630.7 I6b no. 676 cop. 8 UNIVERSITY OF ILLINOIS LIBRARY AT URBANA-CHAMPAIGN AGRICULTURE ^ = u BULLETIN 676 10 -YEAR PAINT WEATHERED GALVANIZED ROOFING By A. J. Muehling and J. O. Curtis UNIVERSITY OF ILLINOIS AGRICULTURAL EXPERIMENT STATION Urbana, Illinois August, 1961 Publications in the Bulletin series report the results of investigations made or sponsored by the Experiment Station ' CONTENTS DESCRIPTION OF TESTS 6 Application of Paints 6 Inspections 13 Criteria for Evaluating Tests 13 TEST RESULTS 15 Performance of Paint Systems 15 Effect of Exposure 20 Effect of Original Condition of Sheet 22 Effect of Wire Brushing Sheets Before Applying Paint 23 SUMMARY 26 LITERATURE CITATIONS. . . .27 COVER PHOTO fhe 150-foot corn crib on which the paint study was conducted (south side after application of first coat of paint). This bulletin was prepared by A. J. Muehling and J. O. Curtis, Assistant Professors of Agricultural Engineering. The research reported here was initiated by R. W. Whitaker, formerly Instructor of Agricultural Engineering, now Director of Agricultural Research, A. O. Smith Cor- poration, Milwaukee, under the direction of D. G. Carter, Professor of Agricultural Engineering. For several years, inspections of the test panels were conducted in the Department by H. L. Wakeland, now Assistant Dean of the College of Engineering, University of Illinois. Funds for this project were provided in part by the American Zinc Institute and the Aluminum Company of America. GALVANIZED METAL SHEETS ARE STEEL SHEETS that have been COated with zinc to prevent the steel from rusting. As this zinc coating deteriorates through weathering, the steel becomes exposed and begins to rust. Besides being unsightly, rusting reduces the life of the roofing. Galvanized metal roofing and siding are used extensively on farm buildings. A 1941-1942 survey (8)* by the American Zinc Institute in 36 states east of the Rocky mountains showed that one-third of all farm buildings had galvanized steel roofs. More than one-fourth of these roofs were rusty. According to a 1944-1954 survey (7), the roofs of about one-half of all Illinois farm buildings were made of galvanized steel. About 50 percent of these roofs showed signs of rust. The application of protective paints is one of the least expensive means of preventing rusting of galvanized metal sheets, provided that the paint is chosen carefully. Painting also makes the building more attractive and can reduce roof temperatures by reflection. Paints vary in their ability to adhere to metals, to withstand ex- posure, and to prevent rusting. Manufacturers' tests indicate the rela- tive ability of paints to protect metal from corrosion. However, the final evaluation of a particular paint can be obtained only by direct exposure to the elements. According to several authorities (5, 10) accelerated laboratory tests do not predict the service life of a paint, and the final trial should be under field conditions. In 1932, the American Zinc Institute established tests of paints on galvanized metal roofs at Donnellson, Illinois. These tests are usually referred to as the Harwood Tests. In 1948, test data covering 16 years were turned over to the Department of Agricultural Engineering at the University of Illinois. The data were analyzed and the results published (3,4). After studying the results of the Harwood Tests and reviewing other technical literature on paint for metal roofs, the University of * This number and similar numbers in parentheses refer to the literature citations on page 27. 6 BULLETIN NO. 676 Illinois Department of Agricultural Engineering initiated a new series of paint tests in June, 1949. This project was supported in part with funds supplied by the American Zinc Institute and the Aluminum Company of America. The objective of these tests was to expand the knowledge gained from the Harwood Tests. Information was sought concerning (a) the durability of metallic zinc paints for priming and finish coats on rusty galvanized metal roofing; (b) the durability of aluminum paints as finish coats over various primers; and (c) the value of wire brushing the rusty surface before painting. The roof of a 150-foot crib on one of the University-owned Aller- ton farms near Monticello, Illinois, was chosen for the tests (see cover photo). The rural location corresponded to the least severe ordinary exposure condition, according to the classification of atmos- pheric types used by the American Society for Testing Materials (11). The condition of the galvanized sheets on this roof did not vary as much as the condition of the sheets used in the Harwood Tests. Much of the metal was quite rusty. A trace of black asphalt paint remained on most sheets from a previous painting. These surface conditions were as severe as one would be likely to encounter in farm buildings. DESCRIPTION OF TESTS Application of Paints Each panel was composed of corrugated metal sheets approxi- mately 2 feet wide and extending up one side of the crib and down the other. This arrangement gave a north and south exposure for each panel. Before painting, all panels were renailed where needed, and the entire roof was brushed with a broom to remove all loose foreign material. A three-foot strip of roof was wire brushed across the northern exposure of panels 46 through 81 to evaluate the practice of wire brushing a rusty galvanized sheet before painting. Twenty-three paints from 11 manufacturers were hand-sprayed on the test panels in 7 one-coat and 34 two-coat applications. Replications were made of all but two panels (panels 11 and 16). In addition to giving better test data, these replications provided some insurance against a complete loss of record in the event that some of the sheets were blown off the roof. Fig. 1 shows the numbered panels on the crib and lists the paint combinations that were tested. The compositions of the paints as reported by the manufacturers are listed in Table 1. FIRST COAT 1 GRAY MZP (SOYBEAN OIL) 2 GRAY MZP (SOYBEAN OIL) 3 ZINC CHROMATE PRIMER 4 ZINC CHROMATE-IRON OXIDE 5 RED LEAD (LINSEED OIL) 6 WHITE LEAD 7 RED MZP 8 RED MZP 9 IRON OXIDE (RED RUST-RESISTING PAINT) 10 GREEN MZP 11 GREEN MZP 12 GREEN AUTO ENAMEL 13 GRAY MZP (LINSEED OIL) 14 RED LEAD (LINSEED OIL) 15 RED LEAD (SEMI-QUICK-DRYING VEHICLE) 16 ZINC CHROMATE-IRON OXIDE 17 ZINC CHROMATE PRIMER 18 ALUMINUM, GENERAL PURPOSE (I) 19 ALUMINUM, GENERAL PURPOSE (I) 20 GRAY MZP (SOYBEAN OIL) 21 GRAY MZP (SOYBEAN OIL) 22 GRAY MZP (SOYBEAN OIL) 23 GRAY MZP (LINSEED OIL) 24 GRAY MZP PRIMER 25 RED LEAD OXIDE (LINSEED OIL) 26 GRAY MZP PRIMER 27 ALUMINUM (RUST-RESISTING VEHICLE) 28 ALUMINUM (RUST-RESISTING VEHICLE) 29 RED LEAD OXIDE (LINSEED OIL) 30 GRAY MZP (SOYBEAN OIL) 31 GRAY MZP (SOYBEAN OIL) 32 ASPHALT ALUMINUM 33 ASPHALT ALUMINUM 34 ASBESTOS ASPHALT 35 ALUMINUM, FOR METAL & MASONRY (I) 36 ALUMINUM, FOR METAL & MASONRY (I) 37 ALUMINUM, SPECIAL 38 GRAY MZP (SOYBEAN OIL) 39 GRAY MZP (SOYBEAN OIL) 40 GRAY MZP (SOYBEAN OIL) 41 SPECIAL RED PRIMER (NORTH ONLY) 42 GRAY MZP (SOYBEAN OIL) 43 GRAY MZP (SOYBEAN OIL) 44 ZINC CHROMATE PRIMER 45 ZINC CHROMATE-IRON OXIDE 46 RED LEAD (LINSEED OIL) 47 WHITE LEAD 48 RED MZP 49 RED MZP 50 IRON OXIDE (RED RUST-RESISTING PAINT) 51 GREEN MZP 52 GREEN MZP 53 GREEN AUTO ENAMEL 54 GREEN MZP (LINSEED OIL) 55 RED LEAD (LINSEED OIL) 56 RED LEAD (SEMI-QUICK-DRYING VEHICLE) 57 SPECIAL RED PRIMER 58 ZINC CHROMATE PRIMER 59 ALUMINUM, GENERAL PURPOSE (I) 60 ALUMINUM, GENERAL PURPOSE (I) 61 GRAY MZP (SOYBEAN OIL) 62 GRAY MZP (SOYBEAN OIL) 63 GRAY MZP (SOYBEAN OIL) 64 GRAY MZP (LINSEED OIL) 65 GRAY MZP PRIMER 66 RED LEAD OXIDE (LINSEED OIL) 67 GRAY MZP PRIMER 68 ALUMINUM (RUST-RESISTING VEHICLE) 69 ALUMINUM (RUST-RESISTING VEHICLE) 70 RED LEAD OXIDE (LINSEED OIL) 71 GRAY MZP (SOYBEAN OIL) 72 GRAY MZP (SOYBEAN OIL) 73 ASPHALT ALUMINUM 74 ASPHALT ALUMINUM 75 ASBESTOS ASPHALT 76 ALUMINUM, FOR METAL & MASONRY (I) 77 ALUMINUM, FOR METAL & MASONRY (I) 78 ALUMINUM, SPECIAL 79 GRAY MZP (SOYBEAN OIL) 80 GRAY MZP (SOYBEAN OIL) 81 GRAY MZP (SOYBEAN OIL) SECOND COAT GRAPHITE RED MZP RED MZP RED MZP RED MZP RED MZP RED MZP NONE IRON OXIDE (RED RUST-RESISTING PAINT) NONE GREEN AUTO ENAMEL GREEN MZP ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) NONE ALUMINUM, GENERAL PURPOSE (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, GENERAL PURPOSE (II) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM, GENERAL PURPOSE (II) NONE ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM, FOR METAL & MASONRY (II) ALUMINUM, FOR METAL & MASONRY (II) ASPHALT ALUMINUM ASPHALT ALUMINUM NONE ASPHALT ALUMINUM NONE ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, SPECIAL ALUMINUM, GENERAL PURPOSE (I) NONE GRAY MZP (SOYBEAN OIL) GRAY MZP (SOYBEAN OIL) (NORTH ONLY) GRAPHITE RED MZP RED MZP RED MZP RED MZP RED MZP RED MZP NONE IRON OXIDE (RED RUST-RESISTING PAINT) NONE GREEN MZP GREEN MZP ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR MFTAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, FOR METAL & MASONRY (I) NONE ALUMINUM, GENERAL PURPOSE (I) ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, GENERAL PURPOSE (II) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM, GENERAL PURPOSE (II) NONE ALUMINUM (RUST-RESISTING VEHICLE) ALUMINUM, FOR METAL & MASONRY (II) ALUMINUM, FOR METAL & MASONRY (II) ASPHALT ALUMINUM ASPHALT ALUMINUM NONE ASPHALT ALUMINUM NONE ALUMINUM, FOR METAL & MASONRY (I) ALUMINUM, SPECIAL ALUMINUM, GENERAL PURPOSE (I) NONE GRAY MZP (SOYBEAN OIL) Paint treatment for each panel of the corn-crib roof used in the tests. (Fig. 1 ) BULLETIN NO. 676 [August, bfl 'C ^ I >, XJ 2 1 I o u C o c $ . o o 10 o _ IN si >^ d s *" 00 00 fN i * 10 ooo V oo oo ooo o ooo oooo e> O> fS *O f) ^, Soa (*5 Soo ro % " 38 _2^ S 10 ^ 8 SB** ss^s 00 S5 - CO i .. 1 * S i JS 73 2 c 652^ ^23 OS j: -.2 8 *G Soybean oil Linseed oil Mineral spirits Pure linseed oil Drier Mineral spirits Vegetable oil (Linseed oil 60 Soybean oil ' Thinner & drie | ! 0-|'lu| | Synthetic resin solution Drier Solvent Linseed oil Linseed oil Mineral spirits Drier Raw linseed oil Alkyd resin Drier Penetrating thi Vegetable oil Thinner & drie Drying oil alky 24% Lead napl ate solution 6% Cobalt nap ate solution 6% Manganese thanate solut Petroleum hyd carbon solve o- o a O o o 10 o Ov GO d IO 1O p*5 ^_| j ' o\ IO -0 10 Ov S 10 t- 0000 IO1O ooo. ooooo oo oo O O oooooc oooo rsor^- 2 S*Q (*S OOOO OiOO O O 2$ 3~ o 8 fS tN CN lOtlO^ V 'o^ ly jj V O Zinc dust Zinc oxide Zinc stearate Graphite Inert Zinc dust Zinc oxide Magnesium silical Red iron pigment (87% ferric oxide] Zinc chromate Red lead (95% gr Zinc oxide Iron oxide (85%) Magnesium silical Iron oxide Zinc chromate Magnesium silical calcium carbon; Zinc oxide o (9 H a Basic carbonate o white lead Chemically pure 2 chromate Magnesium silical Iron oxide Aluminum Calcium carbonat Unknown g ^ 3- o M 2-2-0 S P Ess S ^l& o;25S y-c'S u 3^= - z: - = o SE s ^ 2 o acg c'a'S'S lllaijs3 10 -c"* 't 00 00 IO rf ts *25 V V D 01 o IO C C c 10 o" O o tSt^Tl. s c ^^ (N S) fN (N 00 IO oo" o> 10 10 ^5*^ o . ^* 10 >o U-, " " ' 00 "V ^wj^-S 4) . tC o" ** to O ^ IO (N - - . . C oo" 5 g m V 10" VO oC O 13 MZP iybean oil) U a, N II chromate n oxide 'o So p -a a 4) e '3 S 3 C '5 '"'3 0-0-22 OH N c E (0 c u s >, o Q, V cc-2. S 13 gs B-fi oo IE <&c 1 E O o & N N OJ O O *' 10 -d oo o 796J] PAINT TESTS ON GALVANIZED ROOFING E OO OO (N O O O O^O 13 a ; 13 1 cs r (N oO oo cs oo ^ oo r-* oo H-1 a 13 i "o OO O i c -^S 1 V U U en E .0 3 ^ojj*. * ' 'o.S i M M J3 Jj** .S O ~|j*'2'^'C u "tn'^4' K ' S C. 1 JC U "Sg Sfi'S : o= "Sg ' JHQ t*PS2 ; OSt/3 M OSS H Cu H Ptf JScj U M U I - :: oo oooooo o O-HO i ~ 1 1 *O o 3 O-. O t^l lOOoO ") * \r> a g "(3 u B * - 4 OO O OOO OO O OTOO O O OOT|< B 1 "o E 00 O O Q OO O r^ oo O oo Q O O O U bo s 'a iH H E" 1 3 S U 4J -* 1 E-J B rt o 3 4) O 4J (j c *^ Concluded Pigment g I 1 1 1 11 'as 1 1 -8 in 1 1 i in iiiSii i iiiii QJ O M 1 M 05 t_ rt r- SS < 0^ ^ U NN< 0^0eSSu< -<^ O ("^ 1? *0-, (U -^S D Si S g NOO g W5 t^t- g ^ g W5O"t~ (NOO'o O oC ""5 O I-" < B S>0 S 53 S >... 76.0 47 ... 76.0 48 76 49 b ... 76.0 50 . . 76 2.60 13.5 395 51. . 76 52 ... 76.0 2.95 2.95 1.35 1.30 20.9 20.9 8.6 8.6 540 540 485 485 53. . ... 76.0 54. . 76 55>> ... 73.5 A detailed description of the paints is given in Table 1. b The following paints were thinned to obtain better spraying consistency: Panel 5 Red lead (linseed oil) 12 ounces of turpentine added to 9.08 pounds of red lead. Panel 14 Red lead (linseed oil) 2 ounces of turpentine added to 7.70 pounds of red lead. Mixed more thoroughly than for Panel 5. Panels 16 and 45 Zinc chromate-iron oxide 3 ounces of turpentine added to 5.77 pounds of paint. Panels 46 and 55 Red lead (linseed oil) 6yi ounces of turpentine added to 18.5 pounds of paint. About 5 ounces of linseed oil added to paint for Panel 55. Panel 49 Red MZP 1 ounce of turpentine added to 1 cup of paint. c Only the north side of Panel 41 was painted. A new galvanized sheet was placed on the southern exposure before the paint tests started. J96JJ PAINT TESTS ON GALVANIZED ROOFING Table 2. Concluded 13 Panel No. Panel area (square feet) First coat Second coat Paint No. Amount of paint used (pounds) Weight Coverage per (square gallon feet per (pounds) gallon) Amount Paint of paint No. used (pounds) Weight per gallon (pounds) Coverage (scjuaic feet per gallon) 56 . . 66.6 13 23 4 14 14 1 1 1 11 16 18 16 17 17 18 1 1 20 20 21 12 12 22 1 1 1 4.90 1.40 2.55 1 .20 1.20 3.32 3.32 3.32 4.25 4.45 2.65 4.25 1.12 1.12 3.55 3.70 3.34 1.14 1 .26 7 pints 1.30 1 .30 1.00 3.70 3.70 4.00 25.7 8.6 14.4 8.0 8.0 23.5 23.5 23.5 26.7 25.2 13.4 25.7 8.7 8.7 13.7 24.1 24.1 8.6 8.6 unknown 8.5 8.5 8.2 24.6 24.6 24.6 350 415 420 505 505 535 535 535 480 430 385 460 590 590 295 480 480 500 500 85 485 485 625 505 505 505 12 12 12 14 12 15 17 17 17 17 15 17 19 19 20 20 20 12 22 14 1 ' .18 .20 .32 '.45 .25 .50 .29 .29 .29 .29 .30 8.6 8.6 8.6 8.6 8.3 8.3 8.2 8.2 8.2 8.2 9.3 485 485 485 450 500 420 485 485 485 485 540 57 . 67.6 58 74.1 59 ... 76.0 60 76.0 61 . 76.0 62 76 63 76.0 64 ... 76.0 65 76 66 76 67 . . 76.0 68 76.0 69 76.0 .45 .30 .26 .74 .74 9.1 8.3 8.3 7.7 7.7 480 485 485 690 690 70 ... 76.0 71 . . 73.6 72 66 6 73. . . 66.4 74. . ... 72.8 75 ... 74.0 .83 1 '.55 .35 .50 7.7 's'.i 8.1 8.1 690 385 455 410 76. . 74.0 77 74 78 ... 76.2 79. . ... 76.2 80 ... 76.2 81 .. 82.6 L10 24.8 500 These panels were painted without using the shield or cleaning the cup after painting each panel. Average values are given for successive panels when the same paint was used. Inspections Inspections were made each year (1950 through 1959, with the exception of 1955) by members of the Farm Structures Division of the Department of Agricultural Engineering. Since most of the in- spectors worked with the project four years in succession, they de- veloped proficiency in judging the panels. The yearly inspections were made by the inspectors viewing each panel from a platform at eave height. A high platform was built over a pickup truck so that it could be moved along the eaves as the inspections were made. Each panel was studied and the percent of film failure was recorded. The north and south exposures were inspected separately. Criteria for Evaluating Tests An important consideration in evaluating paint tests is to select an objective method for determining the life of a paint system. Browne (2) lists people in four categories according to their use of paint as 14 BULLETIN NO. 676 [August, those who (a) paint for appearance; (b) paint when the film shows signs of failing but is not badly deteriorated; (c) paint long after the surface should have been painted; and (d) do not paint at all. Obviously, each of these groups has a different idea of when the "repaint stage" is reached. To evaluate paint tests, the repaint stage must be defined. Singleton (9) states that "To the larger body of technical men who are paint users rather than paint makers, panel tests are only incidental. These men are concerned with the cost and the quality of protection that the paint will give on structures in service. The goal of panel testing should be not merely to compare different paint combinations, but to determine the life of the paint on the struc- ture. The results should be a quantitative figure representing the life of the paint system in months or years to a stage where repainting is necessary." One way to define repaint stage is to compare the condition of a panel with the ASTM photographic standards (12) as adopted in 1943 and reapproved without change in 1958. Numerous authorities (Sin- gleton, Walton, Burgener) have recommended ASTM No. 8 as the stage in the photographic standards when repainting is necessary (Fig. 4). This standard corresponds to a film failure of about 5 per- cent (4). For comparison of paint performance in this test, 5-percent film failure was used as the repaint stage. All panels did not reach 5-percent film failure or repaint stage during the 10-year test period. Photographic reference standard Number 8 type 1, rusting not accompanied by blister- ing. This standard has often been recommended as the "repaint stage." Photo courtesy American Society for Testing Materials. (See literature citation 12.) (Fig. 4) 7967] PAINT TESTS ON GALVANIZED ROOFING 15 TEST RESULTS Performance of Paint Systems The paint-performance data for all paint systems are summarized in Table 3. The average percent film- failure ratings are listed for the 9 inspections (1949 to 1959, with the exception of 1955). The percent film-failure rating is an estimate of the percent of total area of the panel where the paint film failed and rust occurred. The southern and northern exposures of each panel were graded separately. Since the panels had one replication, the film- failure values listed in the table are an average for two panels. For the sake of convenience, any film failure below 1 percent was coded as 0.5 percent. The relative durability of each paint system is shown by the "time to repaint stage." This stage represents the approximate time at which 5 percent of the surface of the test panel was devoid of paint. In the two-coat systems, the degree of failure applied to both coats of paint. A number of paint systems did not have a film failure of 5 percent at the end of 10 years and, therefore, did not reach repaint stage. Table 4 lists the 15 paint systems with the smallest percent of film failure after 10 years' exposure. Since most of the panels did not reach repaint stage in 10 years, the paints were ranked according to the average percent film failure at that time. The last four paint sys- tems reached the repaint stage before the end of 10 years. The aluminum paints used as a second coat over red lead or gray MZP (Metallic Zinc Paint) gave the best overall performance. All of the panels painted a first coat of red lead and a second coat of one of the aluminum paints (other than asphalt aluminum) performed well. A large number of the panels painted with a base coat of gray MZP and a second coat of one of the aluminum paints did not reach repaint stage after 10 years' exposure. The panels with two coats of gray MZP were nearing repaint stage at the end of 10 years. Table 5 summarizes the results of all one-coat paint systems and all paint systems composed of two coats of the same paint. In the one- coat paint systems, the performance of red MZP and gray MZP was about the same. Each gave approximately 5 years' protection before repaint stage. All single-coat paint systems of MZP gave a better performance than single coats of aluminum paint. When two applications of the same paint were used, gray MZP (soybean oil, paint No. 1) gave the best performance over 10 years' protection. The paint system composed of two coats of aluminum (paint No. 12, aluminum for metal and masonry) protected the panel for over 8 years before repaint stage was reached. 16 BULLETIN NO. 676 [August, .5 6'-~ .a es-c Z.Z &z OO OO oooo OOOO OOO O"OQOOOOOOOOOOOOOOOOOO"OO"OOOOO OOO O"OOOOOOOOOOOOOOOOOOOO"0"OO"OO"OO OOO O"OOOOOOOO"OOOOOOOOOOOO"OOOOO"OO "OO CNO "OCN OO OO "OCN "OCN "OCN "0"0 OO OO OO "OO OO OCN CNCN 8O"0 "0 O"OOOO "0"OOOOOO O OO O"OO O O CNO t O OCN O"0 OO OO CNCN "OO OO OO OO "OO O"0 CN"0 OO -< , t CN f5 CN H co --H CN 'i Si/0 "0 O "0 O"OO"OO"OO O OO "0 "0 O "i t OO OO CNO "OO CNO OO "OCN "0 "Ot OO OO O"0 OCN CNO OCN ^H .-H CN CNCNfOCNOCNfOiCN ^-i CN O "0 "0 "0 O "0 "0 "0 "0 "0 "0 "0 "0 O "0 "it OO OO t^O CN O OO OO "OCN J^i~- CN t OO OO CNCN OCN O"0 OCN "0 "0 "0 O O "0 "0 "0 O "0 O "0 "0 "0 CN t OO OO CNO "OO OO OO Ot t t "Ot OO OO "OCN OO OCN OCN "0 "0 O "0 "0 OO OO OO OO OO OO OO CNO CNO OCN OO OO CNO OO OO OO CN V V e c _ _ c c ^ ^ rt ~* OO "OO "OO OO "OO "OO OO "OO "OO "OO OO OO OO OO O"0 O"0 O"0 r O CN"0 OO CN"0 CNO "OO O0"0 vOO * "0 OO OO "0"0 O"0 "OCN OCN OOO OO t O OOI OOOO OOOO ^foo OOO OOs f-oo OO t r O r t t t OOO t--oo 796?] PAINT TESTS ON GALVANIZED ROOFING 17 4> C .52] H | o C I aT J3 _E 9) M 2 w - ' < . o .iS^j oct: c.< 3 g o < X W _c J 1 b i J cd f3 "0 oo uo ON UO ON NO "0 UO ON UO ON uo ON ON uo ON j-o"!? J c a 2-oo = i 'c'x >38| en a V in u u OO 4) - ~ i S 8888 U i-*\ oooo 00 ,-\ u u O O O uo 00 1! o o "0 O NO oo NO t^ oooo "0 "0 O "0 oo 000 4> W O "0 O uo uoi^ uo t^ o oo "0 O 00 uo o oo -\ u u 2^- %% O "OO "0 fN "0 o "* o 88 NO OOO O O O r*2 O O O -H ON I So oo "o O "0 i ON <*0 ts CN -l O "0 O "0 "oo NO NO "OOOO tN O O "0 NO UO O tN "0 "0 uo O tN tN tN "0 uo uo * tN O O uoo tN "0 O "0 oo oo m uo in NO r^- tN NO 80 "0 ON!^ oo "OO ^. uo -H UO O "o -K 9 c. *-* d. 2 S IO NO lO** too c8 SJr- co^ __,,-_ o v 10 4) V C/3 C S" * > > u O> ^j O o o X ^ ^ cs ^ I c S to oo o o lOO too 0000 to 10 to to 00 IO IO 80 o o to to o to O O O r^ O O O IO CN 88 W ce fi 5 5 !T "S t ON CN ON ^* ^* r~ CN co to t^. co CO NO t^ CN H CO IO ON IO ^J O co be u S? o ~" CN Tf 00 ON co iOO N CN .S n _ 3 c c , *> in U 'a 5 C a js 00 to O to O O to CN O O OOO O to O 00 to to So o o O to to to to o o CN CN IO to 10 CN 80 10 A " ~ u ON O NO CN 1-1 -i CN -rf to O ** co OO ON CN J^ co CO NO CN O to to i-l CN CO CO -H CN ^ o CN e'u o 3 ^ t3 o E -S Q, u 0> rt C ~- 0. I to 810 O O CN IO O O O to IO O CN oo to to 88 >8 too o o t~ to to O 8 IO CN So to & c c ON 00 NO 00 OO O ~- CN -* f- co CO to -- t-~ i CN O "* -^ t^. ge. V c "~'n CJ o C . co OO OO CN ^10 "*"* -H CN * u w ^s, ~ | NO IO to to O O t^ CN O IO 88 8 00 to to 000 O to to OO OO IO to IO O o to O CN So 10 +**g 3 I E * u. ON r- to oo t~- O tO CN t^ CN co to **~ ^O CN O Tf CN 10 -rt v i5 > ^ co OO OO CN ^^ to ^^ ^* i-l CN - . ^ <*s 2 ^ "* *^ 3 ON to "^ to IO too CNf- CN rt< IO O CO OO ^ 1 C ^ Q X J= CN t"* t^ ^J* ^^ CN Tf Jrj ^ ., , <_ c^ rs E u li-= " Sfu v _ 2 "rt rt "i> > N So 2 co IO ON 8O to to IO t CN 00 to to O O Sto CN O O O to to IO to CN to to to o CN CN t^ IO o 10 O o o S'S A I'^g.e" 5 u -H CN CO t CN IO VO ^H NOO oC^S 2 1;" 1 1> 2 < CN-* -H r* co II jn rt U J3 <*> CN O ON O to o to tO CN IO f- o o oo 00 lOO o o o to IO IO O CN OO O CN oo CNI U * in "u C a ltf|!2 o "^ rt ^ C u o 8 i CN NOO *- d to to >, S CN CN ^"* I 1 CM S ^I^1I IO ON OO O O to to So o oo 88 to to o to CN CN O CN IO OO O CN oo o o w " u Kill! *""' 1-> 1-1 CO IO 00 CO to C <-> 3 *-^3 ^i^^- CN -H r i n B . > O "rt *^- v ec c ^rS CS ^j > * jj^^ pj 8 ON oo oo So to O O IO O to OO O CN oo oo oo s || jSlsslg- ot-^ ON CN CN - 1 ' In u x "--2.s jj H'ji. -> , 2*^ 0) V u !s '" 1 "-S^^'S 3Z &! CN CN 1 S c o CN CN ~H CN 2 o -1 0) '-' "^ ^S Sl*-o|- U N -' o c c c ^ o 60 > .5fS'rt t *"^ 1 -- en en ti C8 C. ^ ^^ qj w J^ c o '" rt li a . v ~ O. .S c> 2^ ~H CN CN CN l t t e co 1- JJ-TIJ oj 2^'J > rt fV ^~< *"^ O CN CN CN n t *-i CN CN U **"* 03 U 2 o A1 S ^ t*H Q o ^ 5 V < J 1 -O S S ^ * 3J .-5 * 3 *C 5 flj C ^* 00 OO too OO oo OO OO oo oo oo O S J2* 2 So'S'v'S'Tg i 'z 3 8 1 TC IO ~* 1/5 ^ OO IO OO CN IO NO O NO OO NO 00 gig NO ~ ^^ CO t^ 00 OO 00 i O to O r^ OO NO OO to O NO 00 8 S B rf c-rl "ss^ilsi ft u c-S"* a'^'S y?-" (U " fcs |S 'El- la^BJ X 3 u ^ c/3Z c/3Z wz C/3Z c^Z WZ C/>Z C7}Z cZ c^ Z Is* giSIlsgs 'S > "*) S^.IC E 1 E li a jj