\ * : - - REESE LIB'R-ARY UNIVERSITY CALIFORNIA. ired ' ' .''. - PHYSICO-CHEMICAL CONSTANTS. MELTING AND BOILING POINT TABLES. BY THOMAS CARNELLEY, D.Sc. (LOXD.), B.Sc. (Vicrr.), F.C.S., I PROFESSOR OF CHEMISTRY IN UNIVERSITY COLLEGE, DUNDEK. VOL. I. LONDON: PUBLISHED BY HARRISON AND SONS, 59, PALL MALL, ^ookstlkrs to % <$ aitb P.$.|J. % ^riittt of 1885. , i LOS 13 OK : HAKRISON ANI) SOXS, PRINTERS IN ORDINARY TO HEB MA-JUSTY, ST. MARTIN'S T.ANK. THIS WORK is DEDICATED TO SIR HENRY EN FIELD ROSCOE, LL.D., VICE-PRESIDENT OK THK ROYAL SOCIETY AND PROFESSOR OF CHEMISTRY IN THE VICTORIA UNIVERSITY, OWENS COLLEGE, MANCHESTER, BY ONE OF HIS OLD STUDENTS, IN (iKATEb'UL BKMEMBUANCE OF MUCH KINDNESS AND ENCOURAGEMENT RECE1VKI) FKOM HIM ON MANY OCCASIONS DURING A PERIOD OV NEARLY SEVENTEEN YEARS. PREFACE. More than eleven years ago I commenced an investigation with the object of tracing, if possible, any connection there might exist between the chemical composition and the melting and boiling points of inorganic substances. As the data available for this purpose were extremely meagre, the determination of a large number of melting and boiling points of inorganic bodies became necessary, and this again, on account of the high temperatures required, necessitated the invention of new processes for determining these constants. The results of these investigations, together with the theoretical conclusions deduced therefrom, were published (partly in conjunction with Professor Carleton Williams) in the "Journal of the Chemical Society of London," in the " Philosophical Magazine," and other periodicals. The work, however, soon became so extended as to include organic as well as inorganic substances, and it was with the object of obtaining data for as complete an investigation of this subject as possible, that the compilation of the present tables was commenced. This compilation, which has already taken eight years of almost continuous labour, was in great part completed without any intention of publication, and it was only after the work had been on hand for some years that publication was ultimately decided on. As is well known, two of the most characteristic properties of substances are the temperatures at which they melt and boil, and indeed, as regards organic compounds, are those properties by means of which these bodies are most easily recognised and their degree of purity ascertained. They are, therefore, almost always the properties to which the chemist first directs his attention when dealing with a new or unknown compound, and their determination consequently becomes of the greatest importance for both theoretical and practical purposes. It therefore appeared probable that the publication of the enormous mass of data, which had been collected in the Tables, would be a great convenience to chemists, and especially to those working with compounds of carbon. This is more particularly the case, as the data referring to many comparatively rare compounds are extremely difficult to find, whilst those relating to the same substance not unfrequently vary between somewhat wide limits, so that it is very desirable to have all the available data tabulated for comparison, accompanied by references to the original papers. My object in preparing the Tables has been : First. To present as complete a list as possible of all known melting and boiling point data, and at the same time to indicate which of them is probably the most exact when there are several determinations referring to the same substance. Second. To state as fully as possible the constitution of each substance to which the data refer. Third. To adopt such a system of arrangement as would facilitate, as far as possible, the ready finding of the data relating to any given substance. Fourth. To give the authority and reference to vi PREFACE. the original memoir in each case. The Tables thus form a catalogue also of the literature referring to most chemical substances. Fifth. As but comparatively few chemists have sufficiently large libraries of their own, or can conveniently refer to the original papers in all cases, I have thought it desirable to give in addition the reference (if any) to either Watts' " Dictionary of Chemistry," or to the " Journal of the Chemical Society of London," or both. This is a feature of the work which I believe will be found particularly useful, more especially to British and American investigators. Such has been my ideal, and though I have spared no pains to carry it out, I am nevertheless fully conscious of many shortcomings, but I believe that those who have occasion to use the Tables will look on them leniently, in consideration of the great labour which has been expended on the compilation, and the extreme difficulty of attaining perfect completeness and consistency in dealing with such an enormous mass of material. The present is, the first of the two volumes in which the Tables are to be published, and contains nearly 19,000 separate melting and boiling point data. The two volumes together will contain about 50,000 data.* The work is divided into three parts : I. Elements and Inorganic Compounds. II. Organic Compounds. III. A number of miscellaneous data referring to melting and boiling, such as complete tables of vapour tensions at different temperatures, and of boiling points at different pressures for a considerable number of substances ; boiling points of saline solutions ; freezing points of cryohydrates, &c. It will also contain lists of the volumes and corresponding years of issue of the more important chemical and physical periodicals, similar to, but much more extensive than those given in Landolt and Bornstein's Tables. The volume now issued contains Part I. and a portion of Part II., and therefore includes the elements and all inorganic compounds, and those organic compounds which contain not more than three elements. The remaining portion of Part II., including organic compounds of more than three elements, and the whole of Part III. are consequently dealt with in the second volume. A few remarks are necessary as regards the system of Tabulation : The main consideration lias been so to arrange the material as to render the finding of any given substance as simple and as easy as possible, and consequently with little or no reference to general chemical relationships. The arrangement for the most part is therefore strictly empirical, and has been attained chiefly by four operations : * The only other works, so far as I know, which profess to be collections of melting and boiling point data are the following : (1) Clarke's Constants of Nature. These come down to 1875, and contain 3,150 melting and boiling point data. These Tables deal chiefly with specific gravities. (2) Rammelsberg's Handbuch der Krystallographisch-physikmlischen Chernie, 1882. This work relates mainly to crystallography, and contains only 1,150 melting and boiling point data. (3) Landolt and Bornstein's Physikalisch-Chemuche Tabellen, 1883. These are general Tables, and refer only to the more common chemical substances. They contain 2,000 melting and boiling point data. (4) M.M. Eichter's Tabellen der Kohlenstoff- Verbindungen nach deren empiricher Zusammensetzuiig geordnet. These come down to May 1883, and are chiefly Tables of the literature referring to carbon compounds. They contain 15,100 melting and boiling point data. PREFACE. vii (1.) Separation into the two great Departments of Inorganic and Organic substances. (2.) Separation into Divisions, according to the number of elements contained in the substance. (3.) Separation of each Division into Groups, each group containing all those compounds which are composed of the same elements. (4.) Arrangement of the compounds in the same group, the plan adopted in the case of organic compounds being necessarily different from that for inorganic substances. The elements are arranged alphabetically, according to the first letter of their symbol, inorganic compounds of the same group are also alphabetically arranged according to the first letter of the symbol of their most positive element. On the other hand, organic compounds belonging to the same group are tabulated according to the number of C-atoms, whilst those containing the same number of C-atoms are arranged according to the number of the atoms of the element following carbon in the formula, and so on. One important result of this arrangement is, that all bodies isomeric with one another are placed together. Minor points in the tabulation are more fully indicated in the " Explanatory Notes," which with the Table of Contents will doubtless prove a sufficient key to the use of the Tables. By means of the above arrangement any substance can be, readily found in a few seconds. As already stated the Tables were at first compiled without any reference to publication, and originally the great bulk of the data were taken from Watts' " Dictionary of Chemistry " and the " Journal of the Chemical Society." When, however, publication was decided on, all such data were checked, when possible, by direct reference to the original memoirs. A small number of the data which were taken from second-hand sources, however, could not be checked, as the original references were not quoted, so that the authorities and references attached to these data are those from which they were actually taken. The references for a few are also entirely wanting ; they were among the first collected, and I have not since been able to trace them back to their original sources. The present volume brings the data down to the Autumn of 1884. I shall always be greatly obliged to anyone directing my attention to errors or omissions, for I am anxious that the Tables should be as complete and trustworthy as possible. THOS. CAENELLEY. University College, Dundee. June, 188o. L TABLE OF CONTENTS. PAGE Preface v Table of Contents ix Explanatory Notes xiii List of Abbreviations xvii Catalogue of Reference Literature xxi MELTING AND BOILING POINT TABLES. PART I. Elements and Inorganic Compounds. I. Elements PAGE 2 II. Compounds containing /. Fluorides . Two Elements :- . XF . . . . 15 2. Chlorides . . . . XC1 ... 15 3. Bromides . . XBr . . . 20 4. Iodides .... . XI . . . . 22 5. Oxides .... . XO . . . . 23 fi. Sulphides . 7. Selenides . . xs . . . . . XSe . . . 26 26 8. Tellurides . . . . XTe . . . 26 9. Nitrides . . . . XN. . . . 27 Phosphides Arsenides . . XP . XAs . . . 27 27 Silicides . . XSi ... 27 III. Compounds containing 1. Chlorobromides . Three Elements . XClBr. 28 PAGE III. Compounds containing Three Elements (continued) : Chloroiodides . . . XC1I . . 28 Bromoiodides . . . XBrI . . 28 2. Double Fluorides . . XYF . . 28 Double Chlorides . . XYC1 . . 28 Double Bromides . . XTBr . . 29 Double Iodides. . . XYI . . 29 3. Basic Hydroxides . . XHO . . 29 4a. Oxychlorides . . . XC10 . . 29 4b. Chlorates . . . . . . 30 4c. Perchlorates 31 5a. Oxybromides . . . XBrO . . 31 56. Hypobromites and Bromates ... . . 31 6a. Oxyiodide? . . . XIO . . 31 TABLE OF CONTENTS. PART I (continued). Elements and Inorganic Compounds. PAGE III. Compounds containing Three Elements IV. (continued) : 6b. lodates XIO . . 31 6c. Periodafces .... 31 7. Sulphochlorides . . XC1S. . 31 Sulphobromides . XBrS . 32 Sulphoiodides XIS . . 32 8a. Oxysulphides .... xso . . 32 8b. Sulphites 32 Sulphates > 32 V. Anhydrosulphates . 32 VI. 8c. Thiosulphates . ) 33 9 Selenites XSeO 33 Selenates 33 10. Chroraates * XCrO . 33 Bichromates . . . 1 33 //. Borates XBO . . 33 12a. Nitrites XNO. . 34 12b. Nitrates . . . . . 34 13. Hypophosphites . 11 * XPO . . 35 Phosphites 1J 35 Orthophosphates V 35 Pyrophosphates . ii 35 Metaphosphates . . . >i 35 14. Vanadates xvo. . 36 15. Arsenates ..... XAsO . 36 16. Carbonates .... XCO . . 36 17. Silicates XSiO 36 IV. Compounds containing Four Elements : 1 . Double Sulphates XTSO . 37 Double Selenates . xrseO . 37 2. Double Nitrates . XYNO . 37 3. Double Hypophosphites XYPO . 37 Double Phosphates . . ii 37 Double Arsenates XYAsO . 37 4. Compounds containing XHC1S . 38 ?i > XHC1N . 38 >' XHBrN . 38 >i XHOB . 38 iVII. >' XHON T . 38 " XHOSi . 38 PAGE Compounds containing Four Elements (continued) : 5. Compounds containing XClBrO . 38 XClBrS . 38 XC10S . 38 XClOCr . 38 XC10N . 38 XC1OP . 39 XC10V . 39 Compounds containing Five Elements . 39 Metallic Alloys: a. Alloys of Two Metals: (1) Ag and Au 40 (2) Ag and Cu 40 (3) Au and Pt 40 (4) Bi and Cd 41 (5) Bi and Pb 41 (6) Bi and Sn 41 (7) Cd and Sn 41 (8) Cu and Sn 41 (9) Cr and Pb 41 (10) Amalgams 41 (11) Pb and Sb 42 (12) Pb and Sn 42 (13) PbandZn 43 (14) SbandZn 43 (15) Sn and Zn 43 (16) Tl and one other Metal . . 43 b. Alloys of Three Metals: (1) Bi, Cd, and Pb 43 (2) Bi, Cd, and Tl ..... 43 (3) Bi, Pb, and Sn 43 (4) Bi, Pb, and Tl 44 (5) Bi, Sn, and Tl 44 (6) Pb, Sn, and Zn 44 c. Alloys of Four Metals : (1) Bi, Cd, Pb, and Sn . . . 45 (2) Bi, Hg, Pb, and Sn . . . 45 Alloys of Inorganic Compounds: (a) Alloys of Two Compounds . . 46 (i) Alloys of Three Compounds . . 46 TABLE OF CONTENTS. PART II. Organic Compounds* PAGE I. Compounds containing Two Elements: /. CH 48 2. CC1 88 CBr 89 CI 89 3. CO 90 CS 90 4. CN 91 II. Compounds containing Three Elements: 1. CHF 92 2. CHC1 .92 3. CHBr 113 4. CHI 130 .7. CHO 135 n. CHS 309 7. CHSe 314 CHTe 314 8. CHN 314 PAGE II. Compounds containing Three Elements (continued) : 9. CHP 348 10. CHAs 349 CHSb 349 CHBi 349 //. CClBr 350 CC10 350 CC1S 351 CC1N 351 12. CBrI 351 CBrO 351 CBrS. 351 CBrN 352 13. COS ..352 CON 352 CSN 352 CNP . 352 * Organic compounds containing Al, Au, B, Be, Cd, Hg, K, Mg, Na, Pb, Pt, Si, Sn, Ti, XI, W, Zn, &c., i.e., Elements belonging to Groups other than V., VI., and VII. of Mendeljeff's " Table of the Natural Classification of the Elements," will be found under " Compounds containing Special Elements" at the end of Part II., Vol. II. EXPLANATORY NOTES. 1. To find any given substance. If the substance is an element look for it in Part I. under Elements, bearing in mind that the latter are arranged alphabetically according to the first letter, not of the name, but of the symbol. 2. If the substance is a compound look for it in Part I. or Part II. of the Tables, according as it is an inorganic or organic compound. N.B. All compounds containing carbon, except metallic carbonates, are included under organic compounds. 3. Knowing the number and nature of the elements which the compound contains, find the group of compounds containing those elements by reference to the Table of Contents, p. ix. To render this as easy as possible, the elements are first given, then compounds containing two elements, then those containing three, and so on. (a.) Inorganic compounds containing two elements are arranged in groups according to the valency and atomic weight of the negative element, thus, compounds containing a monovalent negative element are placed first, beginning with fluorides, i.e., with the negative monovalent element of lowest atomic weight, then chlorides, next bromides, &c., after which come compounds containing a divalent negative element, beginning with oxides, and following on with sulphides, selentdes, &c., and so on. A similar principle is also adopted in the case of compounds containing more than two elements. (6.) Organic compounds. Carbon being the dominating element always heads a formr.la. Organic compounds containing two elements come first and are arranged in groups according to the valency and atomic weight of the element other than carbon. Thus we begin with those compounds which contain one monovalent element, starting with the compounds of C and H, followed by those of C and Cl, then those of C and Br, C and I ; after which we have compounds containing a divalent element, beginning with that with the least atomic weight, and so on. Organic compounds containing three elements are also arranged on a similar principle. Compounds containing C and H and one other element come first, arranged according to the valency and atomic weight of the third element ; after which we have the compounds of C and Cl with a third element, arranged according to the valency and atomic weight of this third element ; then we have the compounds of C and Br with a third element also arranged in a similar way, and so on. The same system is also adopted in Volume II., which, when published, will embrace carbon compounds containing more than three elements. 4. Having found, by means of the Table of Contents, the group* of compounds to which the substance sought belongs, the latter is easily found, for : (a.) Inorganic compounds in the same group are arranged alphabetically according to the first letter of the symbol of the most positive element. (b.) Organic compounds in the same group are arranged according to the number of carbon atoms. Those compounds containing the same number of carbon atoms are then arranged according to the number of atoms of the element following carbon in the formula, and so on. Example (1). Suppose diacetoxyanthraquinone, C 18 H 13 6 , were required. Being an organic compound containing three elements, we should find by the Table of Contents that it belonged to the Ilnd Division of Part II., and further that it belonged to group 5 of this division, which embraces compounds * i.e., compounds containing the same elements. xiv EXPLANATORY NOTES. containing C, H, and O. This gronp according to the Table of Contents commences on p. 135. Turning to this page we follow, in the column of formulae, the arrangement of the C-atoms until we come to those compounds containing 18 atoms of carbon, after which we follow the order of the H-atoms until we come to those compounds containing 18 atoms of carbon and 12 of hydrogen, and finally by following the arrangement of the O-atoms we reach the isomeric compounds of the formula C 18 H 13 6 , among which the required compound is readily found. Example (2). Suppose hydrogen lithium sulphate, HLiS0 4 , were required. Being an inorganic compound containing four elements, we should find by the Table of Contents that it belonged to Division IV., Part I.; and further, being a double sulphate, it would belong to group 1 of that division, and hence would be found on p. 37, where it would occur under letter H, that being the first letter of the symbol of hydrogen, which alphabetically comes before lithium, the other variable element in the double sulphate. 5. If a substance contains water of crystallization this is not taken into account in reckoning the number of elements in a compound. In all other cases of molecular or additive compounds, such as those containing alcohol or benzene of crystallization, picrates, &c., all the elements present are reckoned. 6. Alloys of metals or of two or more inorganic compounds will be found at the end of Part I., arranged alphabetically by symbols, according to the number of metals or compounds in the alloy. 7. Polymeric compounds, the molecular weights of which are known, are always found under the molecular formulae, and sometimes under both the molecular and empirical formulae. Polymeric compounds, the molecular weights of which are not known, are found under their empirical formulas. 8. Isomeric compounds are usually arranged according to their chemical relationships, generally as follows : (1.) Paraffin series. (2.) Olefine series, &c. (3.) Aromatic compounds. (4.) Those of unknown constitution. Aromatic compounds again are arranged thus: (1.) Those containing only one ring. (2.) Those containing two rings, as diphenyl. (3.) Naphthalene derivatives. (4.) Anthracene derivatives, &c. And finally aromatic compounds belonging to the same general class are arranged according to the number of side chains they contain, those with only one side chain being placed first. 9. When there are several data referring to the same substance, these data are generally arranged in the order of size, and that which is considered to be the most exact is put in italics. 10. All temperatures are represented on the centigrade scale. 11. All numbers representing pressures are placed in brackets, and all numbers placed in I/rackets in tin; boiling point column indicate pressures. All pressures, except when otherwise stated, are in millimetre". Thus 210 (740) in the boiling point column would indicate that the substance boiled at 210 C. under a pressure of 740 m.m., whilst 210 (3 ats.) would mean that the substance boiled at 210 C. under a pressure of 3 atmospheres. 12. As regards nomenclature compounds are usually placed under their scientific name, the popular or other alternative name being frequently placed in brackets. 13. If the nature and number of elements in a compound be unknown it will be found under its name in the General Index at the end of Vol. II. This index will only include root-compounds, so that if the substance sought be a derived compound the formula of its root-compound must be found from the General Index, from which its own formula may be easily deduced, and thence found in the ordinary way. 14. Compounds, the formulae of which have not been determined, but whose elementary composition is known, are placed at the end of their respective groups. 15. In regard to the Reference Columns of the Tables, the page given is usually that upon which a given determination is to be found, but occasionally it is that at which a paper begins. The last column of the Tables gives the reference (if any) to Watts' Dictionary of Chemistry or to the Journal of the Chemical Society of London, and is for the convenience of those who are unable to refer to the original papers. EXPLANATORY NOTES. Remarks on the Notation Employed. 16. As a rule the orientation of the side-chains in benzene derivatives is represented by numerals, which are always used in the order : The term ortho- is always applied to the positions 2 and 6 in relation to position 1. ,, meta- ,, 3 and 5 ,, ,, P^ra- 4 ., ,, 17. In the case of diphenyl the position of the side-chains is indicated as follows: The C-atoms uniting the two rings are each known as 1, the other C-atoms being numbered as in the case of benzene, thus : !/ \! A semicolon (;) is used to show whether the side-chains are in both or in only one ring. Thus C 6 H 4 Br.C c H 4 Br=1.3; 1.4 would indicate the dibromdiphenyl Br whilst C H 5 .C 6 H 3 Br 2 =1.2.4; or C 6 H 3 PhBr 2 = 1.2.4 would indicate the dibromdiphenyl Br ;\ > Br If the complete orientation was undetermined and only the distribution between the two rings known, such a fact would be represented by means of the semicolon. Thus, Cl ; C1 3 would indicate the constitution of a tetrachlordiphenyl, and would mean that one of the chlorine atoms was in one ring and three in the other ring; whilst C1 4 ; would mean that all four chlorine atoms were in the same ring. These facts, however, may also be represented by CgHj and CjHj.CuHCl^. respectively. 18. In the case of naphthalene the positions are represented as follows : /\ If the symbols are followed by a semicolon, thus: a^; it would indicate that the side-chains were in the same ring ; if however the symbols are separated by a semicolon, thus : j ; /3 3 it would indicate that the substitution had occurred in each ring. The following examples will illustrate the use of this notation in the case of the chlor-derivatives of naphthalene : C 1(I H C1 3 =C1; Cl would indicate a di-chlor-derivative in which there was a Cl-atom in each ring, but that their position in the rings was unknown. XVI EXPLANATORY NOTES. C 10 H 6 Clo=Cl 2 ; would indicate that both Cl-atoms were in the same ring, but in unknown positions. C 10 H 6 CI 2 =a 1 /3 ; would indicate tha,t'both Cl-atoms were in the same ring, and also their position in the ring. C 10 H 6 Cl 2 =a 1 ; ft would indicate that there was a Cl-atom in each ring, and that one of these was in the aj-position, whilst the other was in one of the two ^-positions, but which of the two was unknown. C 10 H c C] 3 =/3 would indicate that the constitution was unknown, except in so far as that one Cl-atom was in a /3-position. C 10 H 5 Cl 3 =Cl 3 ;i would indicate that two of the Cl-atoms were in the same ring but in unknown positions, and that the third Cl-atom was in the other ring in the r position. C 10 H 4 C1 4 = Cl ; Cl would indicate that two of the Cl-atoms were in separate rings but in unknown positions. would indicate a trichlornaphthalene in which one Cl-atom was in the ^-position in one ring, the other two Cl-atoms being in the other ring, and that of these one was in one of the /3- positions, whilst the position of the other Cl-atom in the ring was unknown. ^; would indicate a chlornaphthalene tetrachloride, in which all five Cl-atoms were in one ring, two of them being attached to the same C-atom in the ^-position. 19. In the case of anthracene the positions are represented thus : The dihvdroxyanthraquinone C K) H 5 Cl 3 =/3.? ; OH OH would be C 6 H 3 (OH):(CO) 3 :C 6 H 3 (OH)=3.2.1; 1.2.3 or =(1.2.3) 2 . The dihydroxyanthraquinone OH CO CO Y OH would be C 6 H 4 : (C0) 2 : C 6 H 2 (OH) 2 =2.1 ; 1.2.3.6. 20. A di-ortho-compound is indicated by (1.2) 3 and a dipara- by (1.4) 2 , and so on. In indicating the orientation in such a formula as C 6 H 4 .CH(OH).C 6 H 3 (OH).CH 3 =2.1 ; 1.2.3, the side-chains are taken strictly in the order in which they occur on the horizontal line, so that the above would represent the compound /CH(OH)_ HO /\CH, Finally such a formula as C 6 H 4 .CH 3 .C 6 H 3 .COOEt=(1.2) 2 .3 would represent the compound COOEt [ xvii ] LIST OF ABBREVIATIONS. a. = above. When placed before a number it indicates that the substance melts or boils above that temperature. If placed before the symbol of an element or compound it indicates that the substance melts or boils at a higher temperature than that element or compound. abt. = about, and indicates that the temperature to which it is attached is only approximate. Ac. = acetyl = C 2 H 3 0, i.e., CH 3 .CO. a. f . = after fusion, and indicates that the determination has been made with a sample of the substance which has been fused and allowed to solidify. a. s. = after sublimation, and indicates that the determination has been made with some of the substance after sublimation, ats. = atmospheres, and refers to pressures. b. = below, and indicates that the substance melts or boils below the temperature before which it is placed. If placed before the symbol of an element or compound it indicates that the substance melts or boils at a lower temperature than that element or compound. b. p. = boiling point. Bu = butyl = C 4 H 9 , without indicating the constitution of the butyl radicle. Bu = normal butyl = (CH 3 .CH 2 .CH 3 .CH 2 ) - Bu0 = isobutyl = (CH 3 ) 2 .CH.CH2- = benzoyl = C 7 H 5 O = (C 6 H 5 .CO) = corrected, when placed after a number. condenses, when placed before a number in the boiling point column, and indicates that the substance condenses to a liquid at that temperature, calcd. = calculated. cond. = condenses, see c. cor. = corrected. c. p. = critical pressure. cryst. = crystallizes or crystalline, c. t. = critical temperature. A. = decomposes, and when placed after a number indicates that the substance melts or boils at that temperature with decomposition ; but when placed before a number it indicates that the substance decomposes at that temperature, without any reference as to whether it boils or melts. d. a. = decomposes above, and is employed like d. (q.v.). d. b. = decomposes below, ibid. (d. p.) = diminished pressure, and indicates that the boiling point to which it is attached was determined under diminished pressure. xviii LIST OF ABBREVIATIONS. d. w. m. = decomposes without melting, at the temperature before which it is placed. Et = ethyl = C 2 H 5 . f. m. = freezing mixture. Fr. or fr. = from. Ht. or ht. = heal, thus, red ht. = red heat. (i. v.) = in vacua. L. or 1. = liquid, and when placed before a number indicates that the substance remains liquid at hat temperature, thus, 1. 10 means "remains liquid at 10" and not " liquifies at 10." 1. a. = liquid above, and indicates that the substance is a liquid above the temperature before whicli it is placed. 1. f. m. = liquid in a freezing mixture, and indicates that the substance remains liquid when placed in a freezing mixture of salt and ice. m. = meta- m. a. = much above, and when placed before a number indicates that the substance boils or melts much above that temperature. m. b. = much below, and is employed with a similar signification to TO. a. Me = methyl = CH 3 . m. p. = melting point. n. f. = non-fusible, and when placed before a number indicates that the substance is not fusible at that temperature, n. v. = non-volatile. o. = ortho- (o. p.) = ordinary pressure. o. t. = ordinary temperature. p. = para- p. d. = partly decomposed, and when placed after a number indicates that the substance boils or melts at that temperature with partial decomposition ; but when placed before a number it indicates that the substance is partly decomposed at that temperature, without any reference to boiling or melting. Ph = phenyl = C 6 H 5 . Pr = propyl = CgHy, without indicating the constitution of the radicle. Pr = normal propyl = CH 3 .CH 2 .CH 2 PrP = isopropyl = (CH 3 ) 2 CH r. = reduced, and when placed after a number shows that the pressure which that number indicates has been reduced to C. r.s. = resolidifies, s. = solidifies, indicating when placed before a number that the substance solidifies at that temperature. = slightly above, when placed in the boiling point column. ' \ = solidifies above, when placed in the melting point column. f = slightly below, when placed in the boiling point column. ' \ = solidifies below, when placed in the melting point column. ub. = sublimes, and indicates that the substance sublimes at the temperature before which it is placed. 8. d. = slightly decomposed, and indicates that the substance melts or boils at the temperature before which it is placed with slight decomposition, sf. = softens, and indicates that the substance softens at the temperature before which it is placed. a. f. m. = solidifies in a freezing mixture of salt and ice. LIST OF ABBREVIATIONS. TIT s. t. = in a sealed tube, and indicates that the melting point to which it is attached was determined in a sealed tube. w. m. = sublimes without melting, and when placed before a number indicates that the substance sublimes at that temperature without melting. u.c. = ivncorrected. v. = volatile, volatilizes. v. a. = volatile above. v. b. = volatile below. vol. liq. = volatile liquid. v. t. = vapour tension. + placed after a number in the melting point column means that the substance melts slightly above that temperature. [ -f ] or [ ] when placed in either the " name " or " constitution " column indicates that the substance is active towards polarized light. [ + ] that it turns the plane to the right, and [ ] that it turns the plane to the left. e 2 CATALOGUE OF REFERENCE LITERATURE (WITH ABBKEVIATIONS). Two numbers only affixed in either of the reference columns indicate the " Journal of the Chemical Society of London " or " Watts' Dictionary of Chemistry ; " in the latter case the number of the volume is given in Roman type. Thus, vii., 206 would mean p. 206 of the 7th volume of the Dictionary, whilst 25, 310 would mean p. 310 of the 25th volume of the Journal of the Chemical Society. The following abbreviations are employed in other cases : A. . . . . . . Annalen der Chemie und Phannacie. Ed. by Wohler and Liebig; afterwards by Wohler, Liebig, and Kopp, and later by Wohler, Hofmann, Kekule, Erlen- meyer, and Volhard, 1832-84; 226 vols. (Liebig's Annalen.) (Leipzig and Heidelberg.) A. C. . . .. Annales de Chimie et de Physique. Ed. by Chevreul, Dumas, Boussingault, Wurtz, Berthelot, and Pasteur, 1789-1884. 1st series, 96 vols.; 2nd series, 75 vols.; 3rd series, 69 vols.; 4th series, 30 vols.; 5th series, 30 vols. (Paris.) A. C. J. .. .- American Chemical Journal. Ed. by Bemsen, 1879-84; 6 vols. (Baltimore.) A. C. P. . . See A. C. A. I. V AM del E. Institute Venato. A. J. S. . . American Journal of Science and Arts. Ed. by Silliman. An. . . . . . . " Analyst, including the Proceedings of the Society of Public Analysts." Ed. by Wigner and Muter, 1876-84 ; 9 vols. (London.) Ann. Phil. . . . . " Annals of Philosophy, or Magazine of Chemistry, Mineralogy, 8fC." Ed. by Thomson, 1813-20; 16 vols. New series. Ed. by Phillips, 1821-26; 12 vols. (London.) A. P. .. Archiv.fiir Pharmacie. Ed. by Trier, 1844-80 ; 37 vols. (Kjobenhaven.) As. . . . . Supplement to Annalen der Chemie und Pharmacie (q.v.), 1861-72 ; 8 vols. A. S. C. A. . . . . Annales de la Societa Cientifica Argentia. A. S. S. B. . . . . Annales de la Societe Sclentifique de Bruxelles, 1877- B. . . . . . . Berichte der Deutschen Chemischen Gesellschaft zu Berlin, 1868-84 ; 17 vols. B. A. B. . . . . Bulletin de I'Academie Belgique (Brussels). B. A. R. . . . . British Association Reports, 1833-84 (London). B. A. St. P See B. P. B. B. . . . . Bulletins de I'Academie Eoyale de Science de Bruxelles (Brussels). B. C. . . . . . . Biedermann's Central-Blatt. B. J. . . . . Berzelius Jahresbericht, 1822-51 ; 30 vols. (Tiibigen.) B. M. . . . . Berlin Monatschrift (?). XXII CATALOGUE OF REFERENCE LITERATURE. B. P B. S. or B. S. C. C C. C C. C. P C. E. T. C. G. orChem. Gaz... C. N Co. C C. R C. S. M. or C. S. Mem. D. P. . . E. N Erd. J G. A Ger. Pharm. . G. H G. I Gilb. Ann. .. G. J. C. Gm. .. Gm. Kr. G. P. . . G. S. P. G. T. . . Handw. I. D. . . J. J. F. P. J. p. or J. p. C. J. P. or J. Ph. J. p. Ph. J. R. or J. R. C. S. J. Z. or J. Z. N. K. D. M. K. L. . . L. Bulletin de I' Academic Impe'riale des Sciences de St. Petersbourg. Bulletin de la Societe Chimique de Paris, 1859-84 ; 40 vols. II Cimento, glornale di Fisica, Chimica, e Storia Naturale. Chemisches Gentral-Blatt (Leipzig). Chemical Physics. By Josiah Cooke, 1860 (Boston). Clarke's Engineers' Tables. Chemical Gazette. Ed. by Francis, 1842-47 ; 5 vols. (London.) Chemical News. Ed. by Crookes, 1860-84; 50 vols. (London.) Comptes Chimiques. Comptes Rendus hebdomadaires des Seances de V Academic des Sciences, 1835-84: 99 vols. (Paris.) Chemical Society's Memoirs (London). N.B. In the Tables these are generally included in the Journal of the Chemical Society. Polytechnisches Journal. Ed. by Dingier, and afterwards by Zeman and Fischer, 1820-84; 254 vols. (Augsburg.) The Edinburgh New Philosophical Journal. Ed. by Jameson, 1826. Journal fur praktisehe Chemie. Ed. by Erdmann (afterwards by Kolbe) , 1834-69 : 108 vols. (Leipzig.) (See J. p.) See Gilb. Ann. German Pharmacopicea. Text-book of Organic Chemistry. By Strecker-Wislicenus, translated by Green- away and Hodgkinson, 1881 (London). Gazzetta Chimica Ilaliana, 1871-84 (Palermo). Annalen der Physik. Ed. by Gilbert, 1799-1824 ; 76 vols. (Halle and Leipzig.) Jahresbericht uber die Fortschritte der Chemie. Ed. by Fittica (Giessen). N.B. Some few data have been entered by mistake under G. J. C. instead of tinder J. Gmelin's Handbook of Chemistry, translated by Watts (London). Gmelin-Kraut Hand-buch der Chemie. Ganot's Physics, translated by Atkinson, 1881 (London). Giomale di Scienze Nat. ed. econom. di Palermo. Gerhardt's Traite de Chimie (Paris). Handwbrterbuch der Chemie. By (?). Inaugural Dissertation (followed by name of University and date). Jahresbericht uber die Fortschritte der Chemie. By Liebig and Kopp, afterwards by Kopp and Will (Giessen). N.B. Some few data have been entered by mistake tinder J. instead of under G. J. C. See J. p. Journal fiir praktisehe Chemie. Ed. by Kolbe, 1870-84; 30 vols. (Leipzig.) See Erd. J. Journal de Pharmacie et de Chimie (Paris). Jahresbericht fiir Pharmacie. Journal of the Russian Chemical Society. Jenaische Zeitschrift fiir Medicin und Naturwissenschaft, herausg. v. der Medicinisch-Wissenschaftlichen Gesellschaft zu Jena. Commences, 1864. (Leipzig.) Knight's Dictionary of Mechanics (London) . KeJcule's Lehrbuch der Organischen Chemie. The Laboratory, a Weekly Record of Scientific Research, Vol. I., 1867 (London). CATALOGUE OF REFERENCE LITERATURE. xiiii L. B. J. . . . . Leonhard and Brown's Jahrbuch. Lehrb See K. L. L. V. S. or Lw. . . Landswirthschaft Versuchs-Stationen. M. A. A. . . . . Memoirs of the American Academy of Arts and Sciences (Boston). M. A. S. . . . . Memoires de I' Academic des Sciences (Paris). M. C. . . . . . . Wiener Monatshefte, Sitzungsberichte der Mathematisch-naturwissenscliaftlichen Klasse der Academic der Wissenschaft zu Wien. M. C. M. . . . . Mott's Chemists' Manual, 1877 (New York). Mem. A. A See M. A. A. M. P. . . . . . . Proceedings of the Manchester Literary and Philosophical Society (Manchester). N. . . . . . . Nature, a Weekly Journal of Science, 1870-84 (London). N. B. A. .; .. N. Br. Arch. (?). N. C. Nuovo Cimento (?). N. H. C. . . . . Neues Handworterbuch der Chemie (?). N. J. or Ni. J. ,. Journal of Natural Philosophy. Ed. by Nicholson, 1802-13 ; 34 vols. (London.) N. J. P. . . . . Neues Jahresbericht der Pharmacie. N. J. T. . . . . Neues Journal v. Trommsdorff. N. R. P Neues Rep. Pharm. O. O. C. . . . . Odling's Outlines of Chemistry, 1870 (London). P. A. . . . . . . Annalen der Physik und Chemie. Ed. by Poggendorff, 1824-77 (Leipzig). P. A. B. . . See B. P. P. A. eb. . . . . Poggendorff' s Annalen Erganzungsband. See P. A. P. J. or P. J. T. . . Pharmaceutical Journal and Transactions (London). P. M. . . . . . . Philosophical Magazine, 1798-1884 (London). P. R. or P. R. S. . . Proceedings of the Royal Society of London, 1832-84. P. R. S. E. . . . . Proceedings of the Royal Society of Edinburgh. P. T. . . . . . . Philosophical Transactions of the Royal Society of London, 1781-1884. Q. J. S. . . . . Quarterly Journal of Science, 1816-31 (Royal Institution, London). R. .. .. .. Repetoire de Chimie pure. Ed. by Ad. Wurtz, 1859-62 (Paris). R. A. T. . . Atti della R. Academia delle Scienze, Torino, 1865- R. C. P See R. R. K. T. . . . . Richter's Tabellen der Kohlenstoff-Verbindungen, 1884 (Berlin). R. P. . . .. Repertorium fiir die Pharmacie. Ed. by Gehlen, and afterwards by Bnchner. R. S. . . . . . . Revue Scientijlque (Paris). R. T. . . . . . . Recueil des travaux Ckemiques des Pays-Das. S. J. . . . . See A. J. S. Sob. J. or Sw. J. . . Journal fiir Chemie und Physik. Ed. by Schweigger, 1811-33; 69 vols. (Niirn- berg and Halle.) T. C. . . . . Roscoe and Schorlemmer's Treatise on Chemistry (London). T. E. . . . . . . Transactions of the Royal Society of Edinburgh. U. P. . . . . . . L'Union Pharmaceutique (?). V. p. P. . . . . Vierteljahrs pr. Pharmacie (?). W. . . .. .. Annalen der Physik nnd Chemie. Ed. by Wiedemann, 1877-84; 23 vols. (Leipzig.) W. A. . . . . Sitzungsberichte der Ealserlichen Akademie der Wissenschaften zu Wien. Math. Natw. Classe, 1848-84; 90 vols. cf. M. C. W. A. C. P See W. W. A. C. P. B. . . See W. B. W. B. . . . . Beiblatter der Annalen der Physik und Cliemie. Ed. by Wiedemann (Leipzig). xxiv CATALOGUE OF EEFERENCE LITERATURE. Wied. Ann SeeW. Wied. A. B See W. B. W. M. . . . . Wiener Monatshefte fur Chemie. See M. C. 2. A. C. .. v; Zeitsclirifi fur Analytische Chemie. Ed. by Fresenius, 1862-84; 23 vols. (Wiesbaden.) Z. B. . . : ... . . Zeitschrift fur Eiologie. Ed. by Buhl, Pettenkofer, and Voit, 1865-84 ; 20 vols. (Munchen.) Z. C. . . . . . . Zeitschrift fiir Chemie. Ed. by Beilstein, Fittig, and Hiibner (Leipzig). N.B. A few references are entered by mistake under Z. C. instead of under Z. A. C. Z. C. P. ' . .. . . Zeitschrift fiir Chemie und Pharmacie. Ed. by Erlenmeyer and Lewinstein (Erlangen and Heidelberg). Z. g. N. . . . . Zeitschrift fiir die gesammten Wissenschaften (?). Z. P. C. .. .. Zeitschrift fiir Physiologische Chemie. Ed. by Hoppe-Seyler (Strassburg). PART I. ELEMENTS AND INORGANIC COMPOUNDS. I. ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Silver Ag 916 Deville B., 12, 791 916 Becquerel G. J. C., 1863 940 Deville C. R, 90, 773 954 Violle C. R, 85, 543 34 106 954 Erhard & Schertel W. A. P. C. B. V Commercial 960 Ledebur [1879], 348 Wied. Beibl., 5 960 Becquerel A. C. P., 68, 73 977 Pictet P. M. [1879], 446 982 Bloxam " Metals," 10 999 Princeps P. T., 1828, 94 v., 277 1000 Quinck6 P. A. vii., 242 1000 PouiUet v., 277 1000 Person A. C. P. [3], 27, 250 ili., 77 1023 Plattner Paul's Chern. In- ill., 955 1024 Daniell dustry, 562 P. T. [1830], 237 1032 Wilson F. d. P., 8, 425 1034 Guyton-Morveau v., 277 Pure 1040 Kiemsdyk C. N., 20, 32 Vaporizes at Troost and Haute- C. R, 84, 946 32, 273 1400 a. 1570 feulle Meyer B., 12, 1428 1870 calcu- Wiebe B., 12, 791 Aluminium .... Al lated 600 Pictet C. R, 88, 1317 abt. 700 Heeren G. J. C., 1855 850 Van der Weyde K. D. M. a. 891 (?) (?) ffl Non-volatile Between Zn Deville G. J. C., 1854 i., 153 Arsenic As at a white heat Volatilizes at and Ag, but nearer to Zn than Ag Mott M. C. M., 43 Under pressure 180 a. 500 Landolt G. J. C., 1859 Fuses be- Mallet G. J. C., 1872 Sublimes tween the m. p. of Sb and Ag Conechy G. J. G, 1880 Sold Au 449-450 1035 Violle C. R, 89, 702 38, 150 1037 Becquerel G. J. C., 1863 1037 Deville B., 12, 791 1045 Violle C. R., 92, 866 40, 669 1075 C. R, Oct., 1879 1075 Erhard & Schertel W. A. C. P. B. 1092 Becquerel [1879], 348 A. C. P., 68, 73 1093 Bloxam " Metals," 10 1100 Pictet P. M. [1879], 446 1102 Plattner Paul's Chem. In- ill., 954 1102 Van der Weyde dustry, 562 K. D. M. 1144 Daniell P. T. [1830], 237 1200 Pouillet ii., 926 1200 Quinck6 P. A. vii., 242 1200 Kustel C. C. [1882], 783 44, 691 'ure 1240 Eiemsdvk C. N., 20, 23 ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. r ^Watts'Dict. & J. Ch. Soc. Gold . Au 1250 Pouillet Dixon's " Heat " 1250 Van der Weyde 128 K. D. M. 1380 Guyton-Mx>rveau 11., 926 1425 Daniell 2240 calcu- Wiebe B., 12, 791 Boron .... B lated 300 (!) Mott M. C. M. Above a Roscoe and Schor T. C., i. i., 627 Adamantine white heat Not in oxy- lemmer i., 629 hydrogen blowpipe Fuses at an Odlinsr O. O. C. intense hea Fuses in the Depretz G. J. C., 1849 Barium Ba electric arc 450 ill., 936 475 Van der Weyde K. D. M. Frey A., 183, 368 31, 689 and Sr G. J. C., 1876 Less volatile fuse above the melt- ing point of cast iron Mallet 30, 357 than Sr or Ca Non-volatile b. redness 1., 501 Beryllium Be at red heat Melts above Nilson and Pet- C. R, 1878 the point at which NaCl is readily vo- latilized b As terssen Debray G. J. C., 1855 ii., 849 Bismuth Bi 256 Cooke C. C. P., 548 Commercial 260 Ledebur Wied. Beibl., 5 260 Van der Weyde K. D. M. .... .... .... }J .... 262 264 Pouillet C. E. T. i., 591 265 Quinck6 P. A. vii., 242 266'8 Person G. J. C., 1847 268-3 Budberg J., i., 71 268-3 Riemsdyk C. N., 20, 32 270'5 Person A. C. P. [3], 27, 250 ill., 77 Between the Carnelley & Carle- 35, 565 Bromine Br melting points of Cu and Ni, i.e., 1090- 1450 Solidifies at ton Williams Liebi" B., 12, 1424 According to Baumhauer 25 24'5 Baumhauer B., 4, 927 25, 220 the presence of water raises the m. p., and this accounts for the higher numbers of other observers B 2 ELEMENTS. Name. Remarks* Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Bromine Br Solidifies at i., 676 22, and does not remelt at 12 21 Quinck6 P. A. vii., 242 Solidifies at B , 12, 1424 20 Solidifies at Serullas 19 18 Balard B., 4, 927 vii., 210 12-5 Pierre 12 Mott M. C. M. i., 676 7'7 Pierre B., 12, 1424 iii., 93& 38, 21;") 7-32 Regnault 7-3 Gorup Besanez B., 4, 927 According to Philipp the Solidifies at Philipp B., 12, 1424 38, 215 lower numbers obtained by other observers are due to admixed Cl 45 47 7-2 Lowig Balard A. C. P. [2], 32, 337 i., 676 58 Andrews P. A., 75, 335 59'%7 (760) Thorpe 37, 172 59*6 (760) Bolas and Groves 37, 173 60 (760) Regnault M. A. S., 26, 913 iii., 97 63 (760) Pierre A. C. P. [3], 20, r iii., 84 63 (760) Stas G. J. C., 1865 Carbon For theoretical considerations C 10,000 or not Dewar P. M. [4], 44, 464 26, 231) Calcium Ca higher Boils a. zinc Fuses Roscoe and Schor- T. C., ii., 189 Full red heat lemmer C. E. T. Mallet 30, 357 than Sr and Ba Bright red Matthiessen G. J. C., 1855 heat Caron G. J. C., 1860 Cadmium Cd 228 Van der Weyde K. D. M. 307 Nies & Winkelmann P. A. [1881], 13, 68 310-320 Wied. Ann., 13 315 316 B. Wood Watts' Diet. 320-7 Person A. C. P. [3], 27, 250 iii., 77 320 Rudberg J., 1, 71 320 Quinckfi P. A. vii., 242 ,5 ... .... .... .... n 320 325 Riemsdyk Van der Weyde C. N., 20, 32 K. D. M. 326 Nies & Winkelmann P.A.[1881],13,68 720 Becquerel G. J. C., 1863 746'3 A. C. P., 68, 73 38, 60 but con- siderably a. Sb ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Jhlorine Cl 75 Berthelot B S C 29 3 34 263 33-6 (760) J 16 70 M A S ml V\ *ri .... .... 33-6 Liquifies at Jahn 26, 658 M. C., 3, 176 B S C 1850 436 42, 795 vi 436 34 (ord. press.) 50 (ord. press.) i. 901 15-5 (4 ats. Niemann vi. 436 0- (6 ats.) Liquifies at 12-5 (8-5 ats.) Solidifies a lit- Olszewski M C 5 127 46 816 obalt Co at 102 tle b. 102 1371 Knight K. D M 1500 Pictet C R 88 1317 1800 Van der Weyde K. D M C E T highest tempera- ture of forge i., 1041 hromium Cr than Fe, less easily than Au Clarke C. E. T. fuse in the forge, but softens and agglome- rates Deville G J C, 1856 sesium Cs Pt 26 27 B., 15, 526 42, 465 opper Cu 950 Van der AVeyde A., 211, 100 K. D. M a 1000 P. M [5] 13 361 1000 1200 Pouillet G. J. C., 1836 1032 Violle C R , Get , 1879 1050 Pictet P. M. [1879], 446 1054 Violle C. R, 89, 702 38, 150 1088 Bloxam "Metals" 1090 P. A. vii., 242 1091 Daniell P. T. [1830], 237 1093 1100 Knight Erhard & Schertel K. D. M. W. A. P. C. B. Commercial 1100 Ledebur [1879], 348 Wied. Beibl., 5 1132 Daniell 1157 Becquerel G. J. G, 1863 1200 (?) ill., 936 1200 Braun P. A., 154, 161 29, 504 1207 Guyton-Morveau i., 39 1236 Wilson F. d. P., 8, 425 Pure 1330 Rienisdyk C. N., 20, 32 1398 Daniell U., 39 ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. "OiHymiTiTn White, cast )> j H Grey, cast )i Cast Steel j) ,, Cast steel English hammered iron Pure bar Wrought )> J) Pure Tensions n j) Di Fe )> j? )> j) > ) n I? > M i> )) Gl (see Be) Ga )! H )) Hg j ) !> !) )) > 1) !) I) >J )1 M j) ) )) 346-5 349 339-359 350 350 350 355 (734) 356-25 354-3 (720) 355-0 (730) 355-8 (740) 356-5 (750) 357-25 (760) 358-0(770) 358-8 (780) 357-3 360 360 132(2-1) 160 (5-9) 183(11-8) 200 (19-9) 20 C-021 1 Melts higher than Ce or La 1250 1050-1100 1050-1100 1075 1100-1200 1200 1200 1275 1600 1530 1300-1400 1350-1400 1800 1375 1500-1600 1600 1600 1804 2000 2204 Highest heat of forge 1587 29-5 30-15 200 (?) For liquefac- tion of H see 38-50 38-8 39 39-38 39-44 40 40-5 Hillebrand& Norton Van der Weyde Pouillet Gruner Ledebur Pouillet Quinck6 Gruner Ledebur Knight Pouillet Gruner Ledebur Pouillet Pictet Van der Weyde Knight Scheerer Bloxam Clarke ,/ Daniell Boisbaudran j> Pictet Wroblewski and Olszewski Reguault Stewart Person Cavendish Hutchins Quinck6 Pouillet Crichton Dalton Carnelley & Williams Pictet Van der Weyde Eegnault Meier and Crafts Heiurich Eegnault Crafts Dulong and Petit Deville Thorpe ! Hasren G. J. C., 1875 K. D. M. G. J. G, 1836 G. J. G, 1874 Wied.Beibl.,5,65C G. J. C., 1836 P. A. G. J. C., 1874 Wied.Beibl.,1881 K. D. M. G. J. C., 1836 G. J. G, 1874 G. J. C., 1881 C. K., 2 P. M. [1879], 446 K.D. M. J " Metals I: C. E. T. P. T., 1830 C. R, 72, 1076 C. R, 83, 611 1878 C. R, 98, 304 C. R, 98, 365 J., 16, 70 " Heat," p. 88 A. C. P. [3], 27, 250 Gm. Kr. P. A. G. J. C., 1837 P. M., 16, 48 33, 282 P. M. [5], i., 484 K. D. M. B., 13, 866 Sw. J., 1, 214 M. A. S., 26, 522 A. C. P. [5], 14, 409 A., 157, 71 37, 151 J) )) A.C.P.r21.16.610 vii., 242 Hi., 329 v., 427 Hi., 326 Hi., 326 30, 484 31, 48 46, 888 46, 889 Hi., 77 Hi., 884 vii., 242 Hi., 884 31, 163 Hi., 84 Hi., 884 Hi., 135 Hi., 884 vii., 688 46, 385 Iron Olucinum (see Beryllium) .... Gallium Hvdroeren Mercury ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Mercury ,, .... .... Iodine .... Tensions jj Hg M I j) In Ir )) )) n K D )> ) i> La Li Mg ) )) M Mn M ) Mo 20 (-0013) 20 (-00574) 175-180 a. 200 250 Red heat 719-731 b. 1040 Volatilizes abt 1100 A little above Zn Volatilizes at same temp. as Zn Volatile at very high temperature 107 107 b. 110 113-115 s. 113-6 176 1950 2200 2500 Only fusible before oxy- hydrogen blowpipe Melts in vol- taic arc s. 55-43 55 57-8 58 58 58 62-5 Near the same tem- perature as Ce Between Sb and Ag 180 433 abt. 500 750 Moderate red heat Melts at same temp, as Zn 1482 1900 At highest heat of forge Melts above Fe Does not fuse in the forge, but softens and agglo- merates Hertz McLeod Person Gay-Lussac Exner Stas Eegnault Stas Winkler Ditte Violle Van der Weyde Pictet Deville and Debray Children Eegnault Regnault Gay - Lussac and Thenard Pouillet Quinck6 Bunsen Carnelley & Carle- ton Williams Ditmar and Dewar Hillebrand and Norton Bunsen Ditte Van der Weyde Eoscoe and Schor- lemmer Bunsen Deville and Caron Knight Van der Weyde Clarke Jordan Deville Clarke A.C.P.[2],17,19 C. N., 48, 251 A. C. P. [3], 27, 25 A. G P. [I], 91, A. C. P. [2], 15, 43 G. J. C., 1865 G. J. C., 1856 J., 20, 262 C. B., 73 C. R, 89, 702 K. D. M. C. R, 88, 1317 A. C. P. [3] J., 9, 43 Kech. Phys Chim., i., 3 C. E. T. P. A. J., 16, 178 35, 565 C. N., 27, 121 P. A., 156, 466 G. J. C., 1875 J., 8, 324 C. R, 73, 108 K. D. M. T. G, ii., 239 A., 82, 137 A., 101, 359 K. D. M. )) C. E. T., 365 C. R, 86, 1374 G. J. C., 1856 C. E. T., 365 46, 385 JJ Ui., 77 ill., 292 42, 795 24,795 29, 524 iii., 317 > ill., 936 vli., 242 iv., 694 26, 726 viii., 421 iii., 936 24, 795 iii., 751 iii., 802 84,772 Indium Iridium Potassium Lanthanum .... Lithium Magnesium .... Manganese .... Molybdenum ELEMENTS. Name. Remarks. Formula, Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Molybdenum Nitrogen Mo N Does not Non-fusible or incom- pletely so at a white heat Bucholz Wroblewski and C. B , 96, 1140 44, 781 952 condense at 136 (150 ate.) 193-1 (760) Olszewski Wroblewski M. C., 4, 415 C E. 98 982 46 817 Sodium Na 90 Pouillet C. E T 365 90 Gray - Lussac and Eech Phys 90 Thenard Quinck6 Chim., i., Ill P A vii 242 95'6 Bunsen J 16 178 v 330 s. 97'6 Eegnault J , 9 43 861-954 Camelley & Carle- 35 565 Norwegium .... Nff 254 ton Williams Dahll B 12 1732 38 93 350 C E 88 47 36 H<)O Nickel.... Ni 1371 Knight C. N., 40, 25 K D M 1392-1420 Schertel N , 22 543 1450 Pictet C E 88 1317 1600 Van der W^yde K. D M At highest Clarke GET 365 Oxvgen o Condenses heat of forge Pictet C N 36 281 34 IQ under a pressure of 300 ats. at the temp, produced by the rapid evaporation of liquid CO 2 invacuo Condenses at Wroblewski and C. E., 96, 1140 44, 781 -131-6(26-5 ats.), 133-4 (24-8 ats.), 135-8(22-5 ats.) c.p. 50 ats. Olszewski Wroblewski C. E., 97, 309 46, 148 c.t.= 113 c. p. 48'7ats Sarrau C E 97 489 46, 149 c.t. 105-4 113-0 (50 Wroblewski C E 98 982 46 817 * Osmium Os ats.) c. p. ; 129-6 (27-02 ats.), 131-6 (25-85 ate.), 133-4 (24-40 ats.), 134-8 (23-18 ats.), 135-8 (22-20 ats.), 184(1 at.) 2200 2500 Van der Weyde Pictet K. D. M. C E 88 1317 ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Os Only fusible Clarke C. E T 365 Volatile at a before the oxyhydrogen blowpipe Infusible at a Deville & Debray G. J. C 1876 white heat white heat Most infusi- iv., 242 Vellow P ble of all metals 43 Quincke P. A vil., 242 44 Person A C P [3] 27 25 ill., 77 44 KOPD A., 93 129 111., 78 ., H )) T> ) .... 44 s. 44-2 LL-2 Gernez Damien Person C. R., 63, 217 G. J. C., 1881 J., 1 80 vi., 934 ,, ,, i) ?T J5 U 11 230 (514) 218 (359) 200 (266) 180 (204) 165 (120) 44-2 44-2 44-3 44.4 Desains Gernez Schrotter Pisati and De J., 1, 84 C. R., 95, 1278 G. J. C., 1847-48 B., 8, 70 44,546 4 JJ 287-3 (762) 250 44-4-44-5 Franchis Pisati Heinrich G. J. C., 1875 Iv. 503 M H H 288 290 300 Dal ton Pelletier Van der Weyde A., 4, 3 K D M )> iii., 84 360 ( 3'2ats) Troost and Haute C. R 76 76 & 219 26, 600 440 ( 7'5ats.) feuille ,, 494(18'0ats.) 503(21-9ats.) >1 511(26'2ats) Red 255 Odling O. O C 1 Pb 320 Pouillet GET s. 322 Crichton P. M , 16 48 322 Daniell P T [1830] 237 323 Kustel C. C. [1882] 783 44, 691 325 Bloxam " Metals " p 10 325 K D M 326 Rudberg J 1 71 Commercial 326 Wied Beibl 5 326 Riemsdyk 1881 ON 20 32 330 P A vii., ''4:2 325-335 iii., 478 332 J 1 72 iii., 77 334 Plattner iii., 955 334 Kupffer A C P [2] 40 292 iii., 534 334 mercury thermo- meter, 326-2 by air ther- mometer 335 Person Pictet G. J. C., 1848 1849 P M [1879] 446 Pure 330-335 Brieel B , 6, 191 S6, 84(> Lead 10 ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Pb Carnelley & Carle- 35 565 Palladium Pd m. p.'s of Ni and wrought. Fe, i.e., 1450-1600 1360-1380 ton-Williams Becquerel G. J. C., 1863 1500 Violle C R , 87 961 38, 150 1700 Pictet C R 88 1317 1950 Quincke P. A vii., 242 Not fusible Clarke GET 365 Platinum Pt in forge, but softens and agglo- merates 1460-1480 Becquerel G J C 1863 1700 Pictet P M [1879] 446 1775 Erhard & Schertel W A C P B 1775 Violle [1879], 348 C R 1879 38, 150 1779 C R 85 543 36 106 1900 Deville C R 56 195 2000 iii. 74 2000 Pictet C R 88 1317 2000 P A vii., 242 2000 Marshall-Watts P M [4] 45 89 26, 461 b 2100 P M [4] 44 465 26 239 ) 2200 2533 Van der Weyde Mott K. D. M. M C M 2534 Plattner iii., 955 .... .,.. .... .... 51 Begins to melt b. 2950 Only fusible Hoadley Clarke C. N., 47, 171 C E T 365 44, 770 Itubidium . . Kb before oxy- hydrogen blowpipe 38-5 A 125 367 v. 129 Klioi] i ii in ... Rh 3000 Pictet J., 16, 185 C R 88 1317 Only fusible Clarke C E T 365 before oxy- hydrogen blowpipe b Ir v. 101 softens in oxyhydro- gen blow- pipe a Pt G J C 1859 Ruthenium . . Ru v. 135 tory of all metals ex- cept Os 1800 ('') Pictet C R 88 1317 Only fusible v., 135 in hottest part of oxy- hydrogen blowpipe ELEMENTS. 11 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J.Ch. Soc. Ruthenium . Ru Abt. same Deville and Debray G. J. G, 1876 S as Ir 107-2 (1 at.) Hopkins J., 1854, 48 ill., 76 135-2 (520 ats.) 140-5 (793 ats.) 109 Cooke C. C. P., 548 111 Quinck6 P. A. vii., 242 111-5 Marchand &Scheerer J. F. P., 24, 129 .Rhombic 111-114 Spring A. C. P. [5], 22, 170 40, 499 113-113-5 Pisati G. J. C., 1874 113-6 Regnault G. J. C., 1856 114-5 Brodie J. F. P., 62, 336 v., 530 115 Kopp G. J. C., 1855; til., 78 .... 115 115 Person Dufour A. 93, 129 J., 173 A. C. P. [3], 68, 370 ill., 77 ili., 75 Rhombic 115 Spring A. C. P. [5], 22, 170 40, 499 440 Lemoine C. R. 24, 1157 440 Dumas v., 530 ili., 84 440 Deville and Troost 442 Heumann & Kochlin B., 16, 604 & 1628 44, 781 & 1051 440 (760) Troost and Haute- C.R.,76,76&219 26, 601 420 (470) 444.4 feuille V. Meyer B., 13, 408 445 (735-2) Meier and Crafts B., 13, 869 445 (731-4) 446 ?> Ramsay ?> 35, 471 447 Hittorf J., 18, 130 (490 in original paper, a mis- 447 (760) Regnault J., 16, 70 print) 447 Andrews B., 14, 2119 42, 135 447 113-6 Wiebe B., 12, 1762 38,88 448 Carnelley& Williams 33, 282 448-1 Cooke C. N., 44, 255 42,[354 448-4 (760) Regnault M. A. S., 26, 658 ill., 135 444-0 (708) Calculated from 444-5 (713-8) 445-0 (719-6) 445-5 (725-4) 446-0(731-3) 446-5 (737-3) 447-0 (743-2) 447-5 (749-3) 448-0 (755-3) 448-5(761-4) 449-0 (767-5) 449-5 (773-6) 450-0 (779-7) 450 the experiments of Regnault,M.A. S., 26,526; byWein- hold, P. A., 149, 231 Van dei- Weyde K. D. M. Prismatic 120 Brodie J. F. P., 62, 336 v.,530 Amorphous, insol. in CS n a. 120 G. J. G, 1854 a. 114-3 Gernez G. J. G, 1876 Lutimony Sb 425 Van der Weyde K. D. M. .... 425 Fehling Handworterb. I. 427 432 Pouillet 432 Dalton Gmelin, 5 Ed., 2 ,, .... .... Commercial ) 432 432 Ledebur Quinck6 Wied.Beibl.,1881 P. A. vll., 432 440 Pictet C. R., 88, 1317 12 ELEMENTS. Name. Remarks, Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Antimony Sb 450 I., 315 450 Wright and Luff 33, 19 620 Mott M. C. M., 50 621 Bloxam "Metals," 10 Boils between Carnelley & Williams 35, 566 Selenium Amorphous (Vitreous) Amorphous, insol. in CS 2 Se J) ) the m. p.'s of Cu and Ni, i.e., 1090-1450 Semi-fluid at 100, and perfectly fluid a little a. 100 103 104-4 Semi-fluid at 125-130, s. b. 50 217 Berzelius Mott A.T. F. Hittorf Traite de Chim., 2, 190 M. C. M. N., 22, 585 J. 4, 319 P A 159 117 v., 222 31, 677 Crystalline, iiisol. in CS, 217 Hittorf J 4 319 217 Quinck6 P. A. vu., 24:! (Crystalline) 217'2 A T F N 22 585 A C P [3] 46 257 v., v-2-2 ,, II 664-G66 (760) pie tely fluid till a. 250 250 Etard and Moissan Troost B. S. C., 34, 69 C R. 94 1508 40, 18 44, 17 ; 42, j) .... .... .... .... ) )) 676-683 Somewhatb. 700 700 217 Oarnelley& Williams Roscoe and Schor- lemmer Wiebe N., 26, 168; C. R, 95, 30 35, 563 T. C., i., 356 B 12 1762 1159 38, 88 Silicon.... Si Melts b the Roscoe and Schor- T. C. b. p. of zinc Melts be- lenimer Deville G. J. C., 1856 v., 267 tween the m. p.'s of steel and cast iron Troost and Haute- A. C. P. [5], 7, 453 30, 597 (Adamantine) but not b. 800 feuille Deville and Caron A C. P v., 268 Tin Sn the m. p. of cast iron 220 222 Van der Weyde K. D. M. v., 803 226'5 P M. [5], 13 366 226 '5 P A [1881] 13 35 227 '8 Crichton P M., 1803 228 Daniell P T [1830] 9 37 In oil 227'8 Liebermann B., 15, 436 42, 914 In CO, 228 '4 In air 228 '2 228'5 J., 1, 71 2 28 '5 C N 20 32 Commercial 9-?n Wied Beibl 5 230 Pouillet o^f) P A vii., 242 Pure 230 Kuuffer iii., 534 ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference Tin Sn 332-7 Person G. J. C., 1847 235 J., 1, 71 s.238 Crichton P. M., 16, 48 246 Mott M. C. M. .... 1700 Boils e- Van der Weyde Carnelley & Williams K. D. M. 35, 566 tween the m. p.'s of NiandFe, i.e., 1450- 1600 White heat Odliug O. O. C. Strontium .. .... .... Sr Melts at Roscoe and Schor- T. C. jt .... Volatilizes between Ca and Ba moderate red heat Red heat lemmer Mallet Matthiessen 30, 357 G J C 1855 Non-volatile Franz G. J C 1869 Tellurium Te at bright red heat 400 Van der W^eyde K D M 452, 465 Carnelley & Williams 37 125 482 (0 ffi abt. 500 525 Pictet C. R. 88 1317 Between Sb Klaproth b 1390 and Pb Deville and Troost J [1863] 17 b. 1390 C R , 91 83 Thorium Th Almost in- Nilson C. R., 95, 727 Ti fusible Got only as Thallium Tl Bed heat a powder and not fused 288 Crookes G J C 1863 v " "" ,. .... .... )) )) 289 290 293-9 Pictet Lamy Crookes C. R., 88, 1317 J., 15, 180 17, 123 Volatile in Roscoe and Schor- T C U current of H at very high tem- perature 207 (!) lemmer Mott M C M Hi^h tem- perature Bright red Peligot G J C 1868 Vanadium V heat Fusible only Tungsten w before oxy- hydrogen blowpipe Infusible in Clarke C E. T /- forge, but softens and agglome- rates a. Mn Wohler Gm Kr Zinc Zn 342 Daniell 31. 243 Watts' Diet. & J.Ch. Soc. v., 803 iii., 77 v., 803 v., 709 v., 709 38, 848 44, 152 v., 744 14 ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Zinc Zn 360 Pouillet 360 Quincku P. A. vii., 242 375 Van de Weyde K. D. M. 1040 abt. 400 Ditte C. R., 73 24, 795 412 Daniell P. T. [1831], 443 v., 1068 Commercial 412 Ledebur Wied. Beibl., 5 ,, 1042 414 415-3 Wiebe Person B., 12, 1762 G. J. C., 1847 38, 88 38,5 420 Riemsdyk C. N., 20, 32 420 Wright and Luff 33, 19 423 Person J., 1, 73 433-3 G. J. C., 1848 iii., 936 433 A.C.P.[3],27,250 iii., 77 450 Pictet P. M. [1879], 446 450 Boussingault A.C.P.[5],19,464 38, 610 891 Becquerel G. J. C., 1863 929-6 Violle N., 26, 138 ; 930 C. R., 94, 720 N., 25, 500 42, 697 930 Becquerel A. C. P., 68, 73 932 N., 25, 500 42, 697 940 Deville and Troost C. R., 90, 793 38, 606 Commercial 942 Troost C. R., 94, 788 42, 1028 1035 (719) Weinhold P. A., 149, 186 27, 115 1040 Deville and Troost J., 12, 25 iii., 84 ;v., 1008 By hydrogen thermometer 916-925 C. R., 90, 773 38, 526 By air thermometer 929-954 )) >? By COo thermometer 1067-1079 Zr Melts above Troost G. J. C., 1865 v., 1080 Orderof volatility of metals: Cd Zn Bi Pb Sn most volatile least volatile Si Riemsdyk C. N., 20, 23 15 II. COMPOUNDS CONTAINING TWO ELEMENTS. 1. FLUORIDES. XF. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Gh. Soc. Arsenic trifluoride AsF 3 60-4 (760) Thorpe 37, 351 ,, J) 63 Unverdorben P. A., 7, 316 j* M 64-66 .... Mac Ivor C. N., 30, 169 28, 239 Boron trifluoride BF 3 Gas 1., 632 Barium fluoride BaF 2 a 908 Carnelley 33, 280 Bromine fluoride BrF Solid Pelouze and Frenry Traite de Chim. i., 491 Calcium fluoride CaF 2 a. 902 Carnelley 33, 280 Cadmium fluoride CdF, 520 j Cuprous fluoride .... Cu 2 F, a. 908 .... 33, 280 Hydrogen fluoride .... HF Cond.at 20 Fremy ii., 670 jj 29-44 *. b. 34-5 Gore G. J. C., 1869 vi., 617 Mercuric fluoride HgF 2 Solid, d. a Pelouze and Fremy Traite de Chim 130 iii., 1092 Iodine fluoride IF Solid H Traite de Chim i., 491 Potassium fluoride .... KF 789 Carnelley 33, 280 Lithium fluoride LiF 801 ji > Magnesium fluoride .... MgF, Very high Cossa G. J., 7, 212 32, 707 ,, a. 908 Carnelley 33, 280 Sodium fluoride NaF a. 902 ) Phosphorus pentafluoride .... PF 5 Gas .... Thorpe A., 182, 201 29, 46 Rubidium fluoride .... EbF 753 Carnelley 33, 279 Sulphur difluoride SF 2 (?) Vol. liq. Pelouze and Fremy Traite de Chim. i., 576 Antimony trifluoride SbF 3 .... 292 Carnelley 33, 275 Selenium difluoride SeF 2 Solid Pelouze and Fremy Traite de Chim. l i., 585 Silicon tetrafluoride SiF 4 s. 102 and Olszewski M. C., 5, 127 46, 816 evaps. itrith- out fusion ,, ,, .... s. 140 Natterer v., 270 ,, > Gas, con- Faraday denses un- der great pressure Silicon hexafluoride Si 2 F. Volatile Solid Troost and Haute- A. C. P. [5], 7, 453 30, 597 feuille Stannic fluoride SnF 4 .... Pelouze and Fremy Traite de Chim., iii., 807 Strontium fluoride .... SrF 2 a. 902 3arnelley 33, 278 Titanium tetrafluoride .... TiF 4 Jiquid Pelouze and Fremy Traite de Chim., iii., 839 Zinc fluoride ZnF 2 734 Uarnelley 33, 279 Zirconium tetrafluoride .... ZrF 4 White heat Pelouze and Fremy Traite de Chim., ii., 713. 2. CHLORIDES. XC1. Silver chloride AgCl 260 Gmelin iii., 619 v., 296 -, 450 Rodwell G. J. C., 1875 " n 4S1 Carnelley 33, 278 457 29, 496 Aluminium chloride A1 2 C1 6 alt. 180 Fusible in Liebig MM 1 i., 157 large mass V 1 180-185 Hartley 30, 249 ;, ,, .... .... abt. 700 Thorpe " Metals," 240 16 COMPOUNDS CONTAINING TWO ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watt's Diet. & J. Ch. Soc. Arsenic trichloride .... A S C1 3 128 (754) liiquid Haagen P. A., 131, 117 37, 353 .... ?) 130-21 (760) Thorpe 37, 352 .... 5 132 Liquid Dumas J. F. P., 18, 449 IJ 132 Michaelis J. Z., 6, 239 vii., 105 ,, ,, .... .... .... 133 Begnault M. A. S., 26, 913 iii., 97 ,, ,, 133-81 (756-9) Liquid Pierre C. R, 27, 213 A.C.P. [3] 21, 336 ? .... .... J> 134 b. 29 Henry A. S. S. B., 1879 Gold dichloride .... Au 2 ci 4 d. at 250 Solid Thompsen J. p. C. [2], 13,337 30, 485 Boron trichloride .... BC1 3 17 (760) .... Wohler and Deville J., 10, 931 18-23 (760) Regnault M. A. S., 26, 658 iii., 135 ; vi., )> P 358 Barium chloride Baa 2 a. 860 Carnelley Unpublished Beryllium chloride .... Bea 3 v. b. 520 Nilson & Pettersson C. E., 98, 988, B., 46, 821 17, 994. ?i " .... Jl 585-617 Carnelley P. E. S., 1879 37, 126 Bismuth trichloride .... BiCl 3 225-230 Muir 29, 144 ;> )) .... 5) 227 29, 146 .... 230 (?) (?) .... )> 4^7-439 Carnelley & Williams 33, 283 Bromine monochloride .... BrCl 13, d. only .... (?) A., 189, 208 stable b. 10 + X H 2 3 7 .... i., 677 Carbon chlorides .... See Part 11 Calcium chloride .... CaCl 2 .... 710 Carnelley 33, 279 i) .... )> 723 29, 497 ,, +6H,O )1 28 Tilden 45, 268 j , 5 ) )1 28-5 Person A. C. P. [3], 27, iii., 77 250 ji ) )) 29 Kopp J., 8, 44 Cadmium chloride .... CdCl : abt. 700 abt. 400 Henry A. S. S. B., 1879 j .... )J 541 Carnelley 33, 279 II a. 861 .... Carnelley & Williams 33, 283 861-954 !) 35, 564 Cobalt chloride + 4H 2 Coa 2 Decrepitates Bersch W. A., 56, 724 vi., 476 a. 116 with- out fusion +6H 3 O 86-87 Chromic chloride TJ Cr 3 Cl 6 Volatile Solid Henry A. S. S. B., 1879 )) .... 5) d. with libe- .... Carnelley & Wil liams 37, 126 ration oi Cl without fusion Caesium chloride .... Csa 631 jj D 37, 125 Cuprous chloride .... Cu 2 Cl a .... 434 Carnelley 33, 278 .... i) 954-1032 .... Carnelley & William 37, 126 )> .... jj b. 1560 .... Meyer B., 12, 1284 36, 875 Cupric chloride .... CuCl 2 498 Carnelley 33, 278 Didymium trichloride .... DiCl 3 Fusible Boscoe and Schor- T. C., 2, 431 leininer Erbium trichloride .... ErCl 3 j> Humpidge and 35, 115 Burney Ferrous chloride .... FeCl s Volatile Solid Henry A. S. S. B., 1879 Ferric chloride .... Fe 2 Cl, 306-307 c., Carnelley & William 37, 126 in sealed tubes +5H 2 J s., 42 Fritzche J. p. C., 18, 479 iii., 378 +6H S O J 31 Ordway S.A. J.[2],l 1,329 vi., 750 u + 12H 2 O 35-5 V J? Gallium dichloride .... Ga 2 Cl 4 535 164 Boisbaudran C. E., 93, 294, 40, 1103 329, B., 14, 2237 COMPOUNDS CONTAINING TWO ELEMENTS. 17 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Gallium trichloride Ga^Cl, 70-76 Boisbaudran C. R, 86, 578 j, 215-220 75-5 jj C. E., 93, 294, 40, 1103 329 ;B., 14, 2237 Hydrochloric acid HC1 Gas 1. 110 Faraday " 80 Cooke C. C. P., 592 j> v. t.=40ats Mitchell 30, 248 at 10-6 " Condenses a 112-5 Olszewski M. C., 5, 127 46, 816 +2H 2 ); 18 Berthelot C. R, 86, 279 84,363 Mercurous chloride Hg s Cl 2 Sublimes400 Henry A. S. S. B., 1879 500 withou melting Mercuric chloride Commercial HgCl 2 258-3 u.c. Cross and Bevan 41, 112 u u 295 265 ill., 897 j) jj .... 291 u.c. 271 u.c. ' Hannay N., 24, 77 Commercial 269 u.c.= Carnelley 41, 321 277 c. Pure jj 276 u.c.= jj 33,276 288 c. jj jj .... 293 c. jj jj .... 287 c. Williams 33, 275 jj jj JT SOS c. Carnelley& Williams 33, 282 jj u By thermometer 275-278 u.c. Carnelley 29, 501 = 285-288 c !> JJ .... 302 29, 496 JJ JJ .... 307 Hittorf G. J. C., 1865 [odine monochloride .... IC1 101-3 24-2 Thorpe 37, 175 JJ 100-5-101 5 24-7 Hannay 26, 818 vil, 678 ' .... JJ 25 Bornemann B., 10, 121 32, 110 " ., 25 Trapp J. p. C., 63, 108 ill., 293 D jj 100-102 30 Schutzenberger Z. C. P. [1862] 1 trichloride .... IC1, 20-25 Serullas ill., 294 jj u .... 25 d. .... Gm. Kr. jj .j .... n 25 d. in air ; Brenken B., 8, 488 does not melt in Cl .... 100 25-30 A, 189, 185 u jj .... jj 33 Christomanos B., 10, 438 32,164 Indium trichloride .... InCl 3 Sublimes .... (?) (?) (?) without melting far a.440,slow- ly at 530, and quickly at a low red heat Potassium chloride .... KC1 730 Braun P. A., 154, 190 jj 'f .. - at a tem- perature i above the m. p. of glass 18 COMPOUNDS CONTAINING TWO ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Manganous chloride MnCl 2 Easily fusible Bayer J. p. C. [2], 5, 105 vii., 771 at dull red heat ,, ,, +4H 2 >! 106 87-5 John iii., 804 Molybdenum pentachloride.... MoCl 6 170-175 Piutti G. I., 9, 538 38, 220 u i .... 11 185 Debray )> si ji 1) S68 194 i> G. J. C., 1868 vi., 831 Nitrogen trichloride NC1 3 71 Does not s. Pelouze and Fremy Traite de Chim., i., 443 Sodium chloride NaCl 772 Carnelley 33, 280 i 11 .... )1 776 29, 498 n 11 960 Braun P. A., 154, 190 Niobium pentachloride NbCl 5 240-5 194 Deville and Troost C. R., 64 Nickel chloride NiCl, Sublimes Henry A. S. S. B., 1879 wi thout melting Phosphorous trichloride .... PC1 3 73-8 (760) Regnault A. Suppl., 4, 129 ill., 97; iv., 510 i> 1) 75-95 (760) 'Thorpe B., 8, 331 37, 333 11 i 1) 76 (760) Buff A. Suppl., 4, 129 37, 334 11 ) 11 75-5 Pawlewski B., 16, 2633 46, 252 11 i 11 285-5 c.t. )1 )> 11 1> 76-25 c. (768) Thorpe B., 8, 330 28, 731 11 i> .... 11 76-7 (745-9) Haagen P. A., 131, 117 37, 334 it 11 .... 11 78 (763) Dumas A., 96 iv., 510 11 )! 78-34 (751-5) Pierre C. R., 27, 213 or 11 A. C. P. [3], 20, 5 i 11 11 78-5 (760) Andrews G. J. C., 1847, 48 pentachloride .... PC1 5 148 Strecker Lehrbuch i it 11 Under pres- .... .... iv., 512 sure melts at 148 and boils a lit- tle a. 148 Lead chloride PbCl 2 498 Carnelley 33, 278 11 11 .... .... .... .... 11 501 V 29,498 580 Braun P. A., 154, 190 ! 11 a. 861 Carnelley& Will Jams 33, 283 861-954 35, 564 Rubidium chloride .... EbCl 710 Carnelley 33, 279 Sulphur monochloride .... 8,01, 136 (760) Chevrier C. R., 64, 302 v., 533 t ! 136-5-137U.C. .... HUbner & Guerout Z. C. [2], 6, 455 vii., 1129 11 11 .... 11 136-137 Dalzell and Thorpe P. M. [4], 42, 309 24, 1163 11 1> 11 137-7 (761-4) Haagen P. A., 131, 117 37, 356 1) 11 " .... It 138 Dumas A. C. P. [2], 49, )5 204 1 11 '" .... 11 138 Ramsay 35, 471 1 11 .... 11 138 Hermann&Kocb lin B., 15, 417 4?, 927 11 11 139 Ramsay 27, 860 11 11 11 139 Wurtz C. R., 62, 460 vi., 1065 11 11 .... 11 139 Marohand J. F. P., 22, 507 v., 533 tl 11 ! 138-12 (760) Thorpe 37, 356 It .... 11 144 (760) Kopp A., 96 37, 356 Mixture near SC1 2 SC1 2 (?) Variable Marchand J. F. P., 22, 507 ji 11 .... 5 64 Davy v., 533 ti J 64 Dumas A. C. P. [2], 49, 204 11 11 11 64 Marchand ,, Sulphur dichloride .... )t Begins to boil Orystallizable Thorpe and Dalzell 24, 1163 at 50-60 Antimony trichloride .... Sbd 3 198 Davy J. F. P., 18, 449 >i i> H abt. 200 7-2 H t, 318 i ! .... 1) 216 72 Cooke J. [1877], 284 | p COMPOUNDS CONTAINING TWO ELEMENTS. 19 ... .-- . ^vs. CA t P- rt .-. . . i A 'A/ Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference ' 1 Watts' Diet. Ce> ' & J. Ch. Soc. Antimony trichloride SbCl 3 221 Carnelley&William 33, 282 j .... 11 223-5 (760) 73-2 Thorpe Eoy. Soc., 1876 u ) 11 223 (760) 73-2 Kopp A., 1855 or 1856 j u 225 Henry A. S. S. B., 1879 ?) 11 230 72 Capitaiue J. F. P., 18, 449 Jl 5) 160 in vac. Williams 30, 464 pentachloride... SbCl 5 6 Kammerer B., 8, 507 28, 1163 )> " .... vol. into Henry A. S. S. B., 1879 SbCl 3 +Cl s Selenium dichloride .... Se 2 Cl 2 Volatile Liquid Thorpe 'Non-Metals,' 353 tetrachloride .... 3eCl 4 Sublimes Solid 11 11 u ?5 .... u Easily vol. Henry A. S. S. B., 1879 without fusion Silicon trichloride OL>Olg 144-148 s. abt. 1 Friedel and La- A. C. P. [15], 19, 38, 608 denburg 390 )> j, .... 11 146-148 s. 14 Troost and Haute- Z. F. C. 14, 331 24, 999 feuille 11 146-148 s. 1 Friedel C. E., 73, 1011 vii., 1086 tetrachloride .... SiCl 4 50 : 1. 20 ! Serullas J. F. P., 18, 449 v., 268 M )j .... 11 56-81 (760) Eegnault M. A. S., 26, 658 vii., 135 -* .... 57-57 (760) Thorpe 37, 327 5) .... 55-60 Friedel and Lad- B. S. C. [2], 7, 322 vi., 1019 enburg )) Jl 58 (762) Haagen P. A., 131, 117 37, 328 )> 5) .... 59 (760) Pierre P. A., 76, 458; 11 A. C. P. [3], 20, 5 )) )) .... 59 Troost and Haute- C. E., 73, 563 vii., 1086 feuille Stannous chloride .... SnCLj 617-628 249-3 c, Carnelley& Williams 35, 563 ,, ,, .... .... .... 250 Marx Gm. Kr. v., 806 .... b. 619 V. and C. Meyer B., 12, 1196 36, 1014 11 11 +4H 2 50 v., 807 Stannic chloride .... SnCl 4 112 (754-9) Haagen P. A., 131, 117 ., ,i 112-5 (752) Andrews C. N., 25, 61 v., 808 11 11 .... 113-9 (760) Thorpe 37, 331 ,i 114 Regnault M. A. S., 26, 913 iii., 97 115-4 (753-1) Pierre P. A., 76, 458; v., 808 A. C. P. [3], 20, 58 11 11 118-120 .... Watts and Bell 33, 443 11 11 .... 120 (767) Dumas C. N., 25, 61 v., 808 Strontium chloride .... SrCl 3 825 Carnelley 33, 280 11 .i .... 829 11 29, 498 11 11 910 Braun P. A., 154, 190 11 11 +6H 2 O 112 Tilden 45, 268 Tantalum pentachloride TaCl 5 841-6 (753) 211 -3 Deville and Troost C. E., 64, 294 vi., 1079 11 11 .... 221 11 11 B. S. C., 2, 120 v., 662 Tellurium dichloride TeCl 2 327 c. Carnelley & Williams 35, 563 11 11 .... 209 11 11 37, 125 tetrachloride .... TeCl 4 414 11 11 35, 563 11 11 .... 224 c. 11 11 37, 125 Thorium .... ThCl 4 Slightly Eoscoe and Schor- T. C., ii., 274 volatile lemmer 11 11 n.-v. at 440 Solid Chydenius P. A., 119, 43 v., 785 Titanium dichloride .... Ti 2 Cl 4 Solid ; d. on Friedel and Gu6rin A. C. P. [5], 7, 24 31, 170 heating trichloride Ti 2 CI s n.-v. Solid 11 11 31, 169 tetrachloride .... Tia 4 135 1. 25 Duppa P. A., 97, 510 v., 837 11 11 .... 11 135 (763) Dumas and Kopp A., 96 11 11 11 136 (762-3) .... Pierre P. A., 76, 458, 37, 329 A. C. P. [3], 20, 5 11 11 ., 136-41 (760) Thorpe 37, 329 _ 1T 20 COMPOUNDS CONTAINING TWO ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Titanium tetrachloride TiCl 4 1. 25 Friedel and Gu6rin A. C. P. [5], 7, 24 31, 168 Thallium chloride T1C1 a. 260 Crookes 17, 139 v., 747 ,, ,, .... 427 Carnelley 33, 277 ) j> ' 434 ,, 29, 496 )> u 451 Carnelley& Williams ,, In the vapour j) 708-719 )> 33, 284 ,, ,, .... .... In the liquid ) 719-731 51 Uranium tetrachloride TJC1 4 Volatile Henry A. S. S. B., 1879 Vanadium dichloride VC1 2 Solid Koscoe P. T. [1869], 679 ,, trichloride va 3 n.-v. in H ,, i ) tetrachloride VC1 4 154 (760) b. 18 )> Jj vi., 1126 Tungsten pentachloride WC1 5 275-6 248 3 C. N., 25, 61 vii., 1184 hexachloride WC1 6 180 Forcher W. A., 44, 159 v., 899 i J) .... 183 Cahours J) i) ji J) 189 Teclu A., 187, 255 32, 709 D )> J 218 Kiche J., 9, 373 ,, .... )J 346-7 (759) 275 c. Koscoe C. N., 25, 61 vii., 1184 Yttrium trichloride YtCl 3 Fusible Zinc chloride . .. .... .... ZnCl. 262 Braun P. A., 154, 190 29, 504 In the vapour 676-683 Carnelley & Williams 33, 284 In the liquid 708-719 b. 890 Meyer B., 12, 1197 36, 1014 Zirconium tetrachloride .... ZrCl 4 Fusible Henry A. S. S. B., 1879 J, ! b. 440 or 350 Deville and Troost C. R, 45, 821 3. BROMIDES. XBR. Silver bromide AgBr 427 Carnelley 33, 277 434 29, 496 Aluminium bromide )) Al 2 Br 6 265-270 90 Weber J., 10,157; P. A., i., 156 103, 254 ,, .... , 260 93 Deville and Troost J., 12, 26 ,, ,, .... .... 263-3 (747) Mallet P. T., 1880, 1003 Arsenic tribromide .... AsBr 3 220 20-25 Serullaa A. C.P.[2], 38,318 Gold monobromide AuBr .... s. ; d. a. 115 dibromide .... Au 2 Br 4 .... a ; d. 115 Boron tribromide BBi-3 90-5 Wohler & Deville J., 10, 94; A. C. P. i., 629 [3], 52, 89 Barium bromide BaBr 2 .... 812 Carnelley 33, 280 Beryllium bromide BeBr 2 .... 585-617 it P. R. S. 37, 126 Bismuth tribromide .... BiBr 3 454-498 Carnelley & Williams 33, 283 ,, ,, H Dull red heat 198-202 Maclvor C. N., 30, 191 28, 133 ^i 11 200 Weber i., 591 ,, .... ) 200 Serullas A.C.P.[2], 38,318 .... 51 210-215 Muir 29, 144 ,, !> 215 Thorpe " Metals," 216 Carbon bromides See Part II. Calcium bromide .... CaBr 2 676 Carnelley 33, 279 .... 1) 680 29, 497 Cadmium bromide CdBr 2 571 ,, 33, 278 )I 806-812 Carnelley & Williams 37, 126 )1 800-914 Meyer B., 12, 1284 36, 875 Cobalt bromide +6H 2 CoBr 2 .... 100 Hartley vii., 3(i:5 Cuprous bromide CuBr 2 504 Carnelley & Williams 37, 125 ,, .... 1 861-954 u 37, 126 Hydrobromic acid HBr .... s. 87, and Faraday P. T., 1845, 155 melts at 86-7 ,, )) Cond. 69 s. 73 D i., 673 +2H 2 O 11 Berthelot C. B., 86, 279 34, 363 +5H 2 126 Champion & Pellet C. R, 70, 620 vii., 211 COMPOUNDS CONTAINING TWO ELEMENTS. 21 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Mercurous bromide .... Hg 2 Br 3 a. 405 (?) Carnelley 33, 277 Mercuric bromide HgBr 2 222-223 Oppenheini Z. F. C., 13, 155 11 11 By specific heat method 242 Carnelley .... 33, 276 ji 11 By thermometer 244 Williams 33, 275 ' 11 234 u. c. = Carnelley 33, 276 11 11 244 Carnelley& Williams 37, 127 11 n 319 11 11 33, 282 Iodine monobromide IBr 36 A., 189, 203 110-120 43 Maclvor 29, 330 tribromide .... IBr 3 80-82 Potassium bromide KBr 699 Carnelley 33, 279 11 11 703 11 29, 497 Lithium bromide LiBr .... 547 11 33, 278 Magnesium bromide MgBr 2 695 11 33, 279 Nitrogen tribromide NBr 3 Very v. Liquid Pelouze & Fremy Traite de Chemie Sodium bromide NaBr 708 Carnelley 33, 279 1, >! .... )1 712 11 29, 497 Phosphorus tribromide .... PBr 3 167 Baudrimont 11 11 .... 172-9 (760) .... Thorpe 37, 335 ,i 11 .... 1.-12 iv., 509 11 11 11 175-3 (760-2) .... Pierre C. R., 27, 213, or A. C. P. [3], 20, 5 pentabromide PBr 6 .... Moderate ht. Balard iv., 510 Lead bromide .... PbBr 2 .... 499 Carnelley 33, 278 a. 861 Carnelley & Williams 33, 283 Rubidium bromide .... RbBr 683 Carnelley 33, 279 Sulphur monobromide S 2 Br 2 185-200 Muir 28, 847 Antimony tribromide SbBr, 270 94 Serullas A. C. P. [2], 38, 318 ,i 11 .... v. 270 90 i., 317 11 n ... 275-4 (760) 90 Kopp A., 1855 or 1856 11 11 * .... 280 93 Cooke S. [1877], 284 D 11 283 90 Maclvor C. N., 29, 179 Silicon tribromide .... Si 2 Br 6 240 Crystalline Friedel C. R., 73, 101 vii., 1086 11 11 .... Friedel and Laden- A. C.P.[5], 19,390 38,608 burg ,, tetrabromide SiBr 4 148-150 s. 12to 15 Serullas A. C. P. [2], 48, 87 v., 268 ,, 11 IBS- 6(762-3) Pierre C. R., 27, 213 Stannous bromide In the vapour SuBr 2 617-634, 259 c. Harnelley & Williams 35, 564 In the liquid 632-634 259 c. 11 !> Stannic bromide .... SnBr 4 SOI u. c. 30 Carnelley & O'Shea 33, 55 ., 11 203 c. 33 Reiss & Raymann C. C. [1882], 773 44, 424 11 11 .... 39 Bcedeker J., 13, 17 Strontium bromide SrBr 2 630 Carnelley 33, 279 Tellurium dibromide Not quite pure TeBr 2 339 abt. 280 Carnelley & Williams 37, 125 11 11 .... 343 305 Carnelley Unpublished tetrabromide .... TeBr, 414-427 380 Carnelley & Williams 35, 563, & 37, 125 Titanium tetrabromide TiBr 4 230 39 Duppa 3., 9, 365 v., 836 Thallium bromide TIBr 458 Carnelley 33, 278 11 n 1) .... 463 n 29, 496 Tungsten pentabromide .... WBr 5 333 276 Roscoe G. J. C., 1872 Zinc bromide ... .... .... ZnBr., 394 Carnelley 33, 277 11 695-699 Carnelley & Williams 33, 283 11 11 Zirconium tetrabromide ZrBr 4 Easily v. at Roscoe and Schor- T. C. heat of gas lemmer flame 22 COMPOUNDS CONTAINING TWO ELEMENTS. 4. IODIDES. XI. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Silver iodide .. . . Ael 527 Camelley 33, 278 "& 530 29, 497 v. at white ii Vogel N. E. P., 20, 129 vii., 1090 )J heat in closed vessel 450 Eodwell C. N., 31, 46 28, 532 Aluminium iodide .... MI. a. Hg abt. 185 Weber J., 10, 156; P. A., i., 157 107, 264 )> .... i! 350 125 Deville and Troost J., 12, 26 (?) Arsenic triiodide .... AsI 3 146 Carnelley 33, 275 11 11 .... 394 to 414 Carnelley & Williams 33, 283 Bismuth triiodide Bil, d. in air, with b.439 in sealed ii ii 37, 125 evolution tubes of I ; resi- due melts at 462 Bromine iodide .... BrI See Bromides Carbon tetraiodide .... CI 4 See Part II Calcium iodide .-. .... Cal a .... . 631 Carnelley 33, 279 Cadmium iodide Cdl, 404 ii 33, 277 .... ii 708-719 ; d. Carnelley & Williams 37, 126 Chlorine iodides See Chlorides Cuprous iodide Different preparations Cu 2 I 2 601 Carnelley 33, 279 i> 11 u )) 628 Carnelley & O'Shea 45, 409 i> 759-772 Camelley & Williams 37, 126 Ferrous iodide FeI 2 177 Carius & Wanklyn A., 120, 69 Gallium triiodide .... GaI 3 a. I Boisbaudran C. E., 86, 578 Hydriodic acid .... HI -49-5 ; s. at Faraday P. T. [1845], 155 iii., 285 -51 Mercurous iodide .... Hg 2 I 2 310 p. d. 290 Yvon C. E., 76, 1607 26, 1104 Mercuric iodide HgI 2 200 Bodwell P. T. [1882], 1141 36, 498 .... 238 (0 Gm. Kr. 36, 602 ,, .... J> 339-359 238 Carnelley & Williams 33, 283 ,, .... 238 Oppenheim Z. F. C., 13, 155 ,, .... >J 349 241 Carnelley& Williams 36, 602 55 253-254 Kohler B., 12, 608 36, 602 ji .... ?) 358 Hittorf G. J. G, 1865 Potassium iodide .... KI 684 Carnelley 33, 279 11 ii J 639 u 29, 497 ji n .... J) 666 Braun P. A., 154, 190 triiodide .... KI 3 45 Johnson 31, 253 Lithium iodide Lil 440 Carnelley 33, 278 ,, )J 453 ii 29, 496 Sodium iodide Nal 628 11 33, 279 ,, ,, )? 633 11 29, 497 Phosphorous diiodide PI S a, 110 Corenwinder J., 3, 272 triiodide .... PI 3 55 11 )! Lead iodide ... PbL 383 Carnelley 33, 277 861-954 Carnelley & Williams 37, 126 Rubidium iodide ) Rbl 642 Carnelley 33, 279 Sulphur iodide .... SI s orS 2 I..(?) b. 60 Gay-Lussac Gmelin, 2, 267 Antimony triiodide .... SbI 3 164-4 c. Maclvor 29, 328 )) 165-5 u. c. 11 C. N., 29, 255 27, 870 )j 11 .... 1 167 Cooke J. [1877], 285 11 11 )> 401 (760) 11 C. N., 44, 255 42, 354 11 i) .... 400-4-400-9 Bennett n 11 i .... )> 401 11 S. J. [3], 15, 391 ,, .... 5> 414-437 171 Carnelley & Williams 33, 283 pentiodide .... SbI 5 78-79 Pendleton C. N., 48, 97 46, 19 COMPOUNDS CONTAINING TWO ELEMENTS. 23 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. elenium moniodide Sel 70 Schneider P. A., 129, 627 tetriodide SeI 4 75-80 35 11 ilicon triiodide Si 3 I 6 Crystalline 250 d. Friedel& Ladenburg A. C. P. [5], 19, 390 38, (JU8 ; vi., 1022 tetriodide .... SiI 4 290 120-5 Friedel J. F. P., 107,245; vi., 1022 A., 149, 96 tannous iodide Snl s 316 Carnelley & Williams 35, 564 tannic iodide .... SnI 4 295 146 Personne J., 15, 172 v., 815 trontium iodide .... Srlj 507 Carnelley 33, 278 itanium tetraiodide TiI 4 s. a. 360 150 Hautefeuille J., 20, 207 v., 841 hallium iodide Til 439 Carnelley 33, 278 ,, .... 446 33 29, 496 11 11 ." In the liquid 1 806-814 .... Carnelley & Williams 33, 284 ., i, .... .... In the vapour 1 800-806 31 11 13 inc iodide.... ZnL .... 446 Carnelley 33, 278 3) 31 .... 3> 624 Carnelley & Williams 5. OXIDES. XO. Aluminium oxide A1A .... Fuses inoxy- i., 159 hydrogen flame Arsenic trioxide AsA Volatile Fuses under Odling O. O. C. pressure 33 31 .... v. abt. 218 .... i., 373 Boron trioxide BA 577 Carnelley 33, 278 ,, 1300 Quinck6 P. A. vii., 242 Beryllium oxide .... BeO v. without Odling O. O. C. melting in oxyhydro- gen flame Bismuth dioxide BiA Not at 180, Muir 32, 131 but forms r ,, trioxide BiA .... Fusible Odling 0. 0. C. Carbon oxides .... See Part IT. Chlorine monoxide .... C1 2 O 19 to 20 Liquid Pelouze A, 3, 7 trioxide CIA 8-9 (745) Brandan Z. F. C., 13, 47 ,, s. a. Liquid 11 A., 151, 340 vi., 440 tetroxide CIA 76 Faraday G. J. G, 1845 33 33 9-9 (730-9) Schacherl A., 206, 68 40, 346 13 31 9 (730) Pebal A., 178, 1 28, 1158 11 11 From KC1O 3 and H 2 SO 4 20 Millon ,, 33 11 From euchlorine 32 11 oxide ( ? ) 59 Faraday Chromium trioxide CrO 3 190 i., 952 33 31 .... 200 11 11 . .... n abt. 300 Henry A. S. S. B. 33 31 .... .... Melts s. b. Schafarik W. A., 47, 256 vi., 453 the b. p. of strong H 2 S0 4 Cuprous oxide Cu 2 O Red heat Odling O. O. C. Cupric oxide CuO Bright red heat. d. Water H 2 O 100 ^^2 For tables of tensions of aqueous vapour and also for table show- ing in fluence of ' pressure on m. p. see Part III. COMPOUNDS CONTAINING TWO ELEMENTS. Name. R emarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Hydrogen dioxide .... HA 1. 30 Thenard Traite de Chem. iii., 197 4th ed. iv., 2, 41 Iodine trioxide .... IA Solid ; d. at Ogier C. E., 85, 957 34, 11 125-130 Potassium monoxide .... KjO v. at high Eed heat .... iv., 706 temp. 1 T) .... )) .... Infusible if Lupton 30, 577 white ; con- tains higher oxide when yellow Magnesium oxide MgO Infusible Odling O. O. C. Molybdenum trioxide .... MoO 3 .... 759 Carnelley 33, 279 >J " Sublimes Stierlin J. p. C. [2], 14, 464 81, 691 Nitrogen monoxide .... .... N 2 O .... 115 ,, ,, .... i) 100 Faraday G. J. C., 1845 ,, j, .... .... > 92 99 Wills C. N., 28, 170 vii., 853 j .... )> 92 (760) Pictet A.C.P.[5],13,213 ,, i) 88 .... (?) (?) 27, 23 ; iv., 07 87-9 (759) Eegnault M. A. S., 26, 658 ill., 84 dioxide .... NA Cond. 11 .... Cailletet C. E., 85, 1017 34, 11 (104 ate.) and re- mains li- quid at + 8 (270 ate.) trioxide .... NA 18 Thorpe "Non-Metals,"202 is .... b. 0. and per- 1. 30 Hasenbach J. p. C. [2], 4, 1 haps b. 10 ,j .... .... .... cond. +14'4 .... Gaines C. N., 48, 97 46,15 (755) tetroxide .... NO, 28 (760) Dulong Sw. J., 18, 177 .... !! 28 Mitscherlich Sw. J., 63, 109 ,, ,, .... n .... s. 20 Peligot & Friteche Gm. Kr. } , .... !) .... 11-5 to 12 Muller G. J. C., 1862 }J .... > SI -6 (760) Thorpe 37, 224 ,, .... !) 22 .... Goldschmidt A., 205, 372 40, 506 ,, .... )) 22 (?) (?) iv., 76 ,, .... )1 .... s. 10 Deville and Troost C. E., 64, 257 vi., 871 .... 22 9 Peligot Gm. Kr. j, .... 26 Gay-Lussac .... 25-30 Girard and Pabst G. J. C., 1878 pentoxide NA 40-50 29-30 Odet and Vignon C. E., 69, 1142 vi., 874 * .... 45-50 29-30 Deville J., 2, 257 ,, ,, .... ) abt. 45 little a. 30 )> A. C. P. [3], 28, iv., 78 241 ,. ,, .... I! .... abt. 30 Weber P. A., 147, 113 vii., 856 Sodium monoxide .... Na 2 Fusible Odling O. O. C. Osmium tetroxide .. .... OsO 4 abt. 100 Solid Henry A. S. S. B. ,j abt. 100 .... Deville and Debray A. C. P. [3], 56 )j 55 .... H A little above Much b. 100 Glaus A. 67, 375 iv., 246 the m. p. Lead monoxide PbO v. at white Eed heat Henry A. S. S. B. heat Ruthenium dioxide .... EuOj Does not sub- .... Deville and Debray C. E., 83, 926 31, 443 lime at red heat tetroxide .... RuO 4 40 15 C. E., 80, 458 )5 )j .... .... abt. 100 58 Clans J., 12, 262 v., 138 Sulphur dioxide so s 8 (759-2) Pierre J., 1, 63 26, 597 ii .... -10 .... Faraday P. T. [1823], 189 v., 540 COMPOUNDS CONTAINING TWO ELEMENTS. 25 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Sulphur dioxide S0 3 10-1 .... Begnault M. A. S., 26, 658 ill., 135 !> .... 11 10-5 .... Dufour A. C. P. [3], 68, ill., 87 378 )> .... )) -10-5 (744) Bunsen P. A., 46, 97 ill., 84 .... )) 10-3 (741) .... Andreeff G. J. C., 1859 ji .... 1) 9-9 (754) j> ) )! .... 10 (760) ; .... Pictet C. C. [1877], 81 ; 34, 251 ; 35 (not more P. M. [5], 1, 484 31, 163 than 4 ats.) .... . 76 Faraday P. T. [1845], 155 ,) )) .... .... -79 .... v., 540 I> .... }} 80 Mitchell A., 37 )) !> .... J .... 100 Clarke C. E. T. Mixture of sulphur di- and S0 2 +S0j SA (?) 5 .... Schultz-Sellack P. A., 139, 480 Til., 1136 trioxides Sulphur trioxide .... S0 3 46-2 (762) 14-8 Weber P. A., 159, 313 32, 165 J! )) .... .... s. 14-8 ) J. p. G, 25, 218 42,804 .... )) a. 25 Bussy A. C. P. [2], 26, 411 (a) Modification I) 46 (760) 16 Schultz-Sellack P. A., 139, 480 20 (200) ( )! 20 (30-40) Gradually a. vii., 135 50 i) .... )) 46-47 (760) 29-5 Buff A. 4th Suppl. 129 .... .... .... When re- Marignac A., 188, 228 v., 569 cently soli- dified melts abt.!8,but quickly passes into another modifica- tion, whicl does not melt b. 100 but return to the firsl modifica- tion, b. p. =35 Antimony trioxide It Sb 2 O 3 Sublimes Red heat Henry A. S. S. B. .... > b. 1560 .... Meyer B. 12, 1284 Selenium dioxide .*> SeO 2 v. at 300 with Eoscoe and Schor T. C. out meltin lemmer Tellurium dioxide .... Te0 2 a. Te Henry A. S. S. B. trioxide .... Te0 3 Fusible (?) (?) Titanium sesquioxide .... TiA Crystalline, Friedel and Guerin A. C. P. [5], 7, 2 31, 168 forms TiO 2 on heating dioxide Ill TiO 2 Fuses in Odling O. O. C. oxyhydro- gen flame Thallic oxide .... TIA 759 Carnelley & O'Shea 45, 409 Uranium tetroxide .... UO b. red heat c Fairley 31, 127 Vanadium pentoxide .... VA .... 658 Carnelley 33, 279 Tungsten trioxide .... W0 3 .... Ht. of forge Henry A. S. S. B. Zirconium dioxide .... ZrO 2 .... Not in oxy- Odling 0. O. C. hydrogen flame 26 COMPOUNDS CONTAINING TWO ELEMENTS. 6. SULPHIDES. XS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Silver sulphide .... Ag 2 S Fuses Odling 0. 0. C. Aluminium sulphide A1 2 S 3 Melts with Reichel J. p. C. [2], 12, 55 29,43 difficulty .... ... .... .... Fusible Fremy i., 160 Arsenic trisulphide .... As 2 S 3 Easily fusible Odling O. O. C. Boron trisulphide .... B 2 S 3 Volatile Solid 11 II Beryllium trisulphide .... Be 2 S 3 (?) Solid (?) (?) Bismuth trisulphide Bi 2 S 3 .... a. 264 Odling O. O. C. Carbon sulphides .... See Part II Cuprous sulphide .... Cu 2 S .... Fusible 11 IT or cupric sulphide ... .... Cu 2 S or CuS 1035 Becquerel G. P. 813 Hydrogen sulphide .... H 2 S .... S.S5-B Faraday P. T. [1845], 155 .... -61-8 (760) Eegnault M. A. S., 26, 658 iii., 135 11 5, .... )I -73 Cooke C. C. P., 592 Mercuric sulphide .... HgS Sublimes Odling O. O. C. without melting Manganous sulphide .... MnS .... Not at 305 (?) (?) Nitrogen sulphide .... NS Sublimes 135 158 Michaelis G. J. C., 1870 Phosphorus disulphide Molec. wt.=P 3 S 6 PS 2 248-249 Seiler Diss. Gott., 76 ' ! 11 ii 296-298 Eamme B., 12, 940 36, 691 monosulphide .... P 2 S Liquid s.alittleb.O Berzelius Gm., ii., 209 iv, 600 trisulphide P 2 S 3 380 167 Isambert C. E., 96, 1499 44, 901 .... )) 200 Lemoine B. S. C., 1, 407 iv, 602 .... .... )> 290 11 J., 17, 134 pentasulphide .... P& 274-276 Meyer B., 12, 610 38, 579 11 i) ) 527 Andrews B., 14, 2119 42, 135 11 11 j) 530 Hittorf P. A., 126, 196 ii >i .... i 519 (734) Goldschmidt B., 15, 304 42,693 II )! 517 (728-5) 11 II n >! 11 >i 550 (760) .... D (?) ii subsulphide (a) Colourless P 4 S Liquid s. a little b.O Berzelius Gm., ii., 209 iv., 599 11 11 (/3) Bed i Solid 11 11 iv., 600 Tetraphosphorus trisulphide .... P 4 S 3 300-400 142 Lemoine J., 17, 133 iv., 602 i) 11 II 166 Ramme B., 12, 1351 36, 883 Lead sulphide .... PbS Slightly v. Full red ht. Odling 0. 0. C. Antimony trisulphide Sb 2 S 8 Red heat J> )I Selenium monosulphide .... SeS Fusible Ditte C. E., 73, 625 24, 995 disulphide SeS 2 ... Alittlea.100 Berzelius v., 233 trisulphide .... SeS 3 .... Fusible 11 )! Stannous sulphide SnS 11 Odling O. O. C. Stannic sulphide .... SnS 2 d. on heating 11 n 7. SELENIDES. XSe. Cadmium selenide Phosphorus subselenide Hydrogen selenide .... CdSe P 4 Se H 2 Se Gas ; does not cond. at 15 Solid S.-12 Margottet Hahn Uelsmann J. [1877], 269 J. p. C., 93, 430 A., 116, 122 iv., 597 v., 218 Thallium selenide Zinc selenide .... .... .... .... Tl 2 Se ZnSe 340 Solid Kuhlmann Margottet J., 17, 255 J. [1877], 269 v., 756 8. TELLTJBJDES. XTe. Cadmium telluride Potassium telluride .... CdTe 2 KjTe .... Solid b. Te Margottet Berzelius C. E., 84, 1293 32, 570 iv., 708 Zinc telluride .... ZnTe Solid Margottet C. B,, 84, 1293 32, 570 COMPOUNDS CONTAINING TWO ELEMENTS. 9. NITRIDES, PHOSPHIDES, ARSENIDES, AND SILICIDES. XN, XP, XAs, AND XSi. 27 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Aluminum nitride .... A1N )oesnotmelt, Mallet 31, 349 but slowly d. Boron nitride.... .... .... BN Infusible Odling O. O. C. Carbon nitride (cyanogen) .... .... CJX 3 See Part II. Ammonia . .... ... H 3 N 75 Faraday P. T. [1845], 155 i., 183 a 38-5 Kegnault M. A. S., 26, 658 iii., 135 )> 36 Thorpe "Non-Metals" )) 35-7 Loir and Drion B. S. C., 1, 184 i., 102 38-7 (749) Bunsen J vi * i., 183 )> 17-78(2-48 ats.) *) J) (4-44 ats.) j .... .... .... ) 10-8 (6 ats.) .... 5) )5 .... )) 19-44 (7'6 ats.) 5J 28-31 (10 ats.) For table of J) JJ tensions, see Part III. Potassium nitride .... K 3 N d. without Gay-Lussac and .... lv., 695 melting Thenard, Davy Titanium nitride .... TisN, Crystalline d. at red heat Friedel and Guerin A.C.P. [5], 7,24 31, 168 .... Ti 3 N 4 > H ) n )) 55 Hydrogen phosphide H 3 P Gas b. 110 Faraday (?) .... H 4 P 2 1. 20 Thenard A. C. P. [3], 14, 5 111., 202 Zinc phosphide .... Zn 3 P 2 Volatile a. Zn. Hayer C. C. [1876], 585 32, 113 Hydrogen arsenide HjAs 58 Cooke C. C. P. ,, .... .... .... j> Cond. 30 .... (?) (?) 1., 372 ,, .... .... > b. -110 Faraday (?) ,, .... .... 113-5 Olszewski M. C., 5, 127 46, 816 Hydrogen silicide H 4 Si Cond. 11 Ogier C. R, 88, 236 36, 436 (50 ats.) .... ) Cond. 5 (70 ats.) i) i) .... ji Cond. 1 n ) (100 ats.) ,, 11 * i c.t. = abt. .... i> j> )J 28 III. COMPOUNDS CONTAINING THREE ELEMENTS. 1. CHLOROBROMIDES, CHLOROIODIDES, AND BROMOIODIDES. XClBr, XC1I, AND XBrl. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Carbon chlorobromides Ml CCl 3 Br, &c. See Part II. Phosphorus chlorobromide .... PCl 3 Br s d. 35 s. 20 Michaelis B., 5, 9 32, 138; 25, 282 PBr 5 .3ClBr PCl 3 Br 8 b. 90 s. 4-5 Prin vault C. E., 74, 368 vii., 961 )> PCl 3 Br 2 .3Br 2 abt. 25 Michaelis B., 5, 414 J) Silicon chlorobromide SiCl 2 Br 2 abt. 100 Friedel&Ladenburg A.C.P.[4],27,416 26,54 SiCl 3 Br 80 Liquid J., 20, 555 D Tin chlorobromide .... SnClBr 3 181-190 Eeis and Eaymann 0. C., 1882, 773 44,424 ) jj .... .... SnCl 2 Br 2 (?) Begins at Ladenburg A. Suppl., 8, 60 vii., 1158 130, d. Titanium chlorobromide .... TiCl 2 Br 2 180 Friedel and Guerin A. C. P. [5], 7, 24 31, 170 J! TiCl 3 Br 160 .... ft 31, 169 Mercuric chloroiodide HgClI 315 153 Kohler B., 12, 1190 36, 1017 Platinum chloroiodide .... PtCl 2 I 2 .... b. 100 Kammerer A., 148, 329 vi., 952 Mercuric bromoiodide HgBrI 229 Oppenheim Z. F. C., 13, 155 vi., 816 Silicon tribromiodide SiBr 3 I 200 Friedel G. J. C., 1869 2. DOUBLE FLUORIDES, DOUBLE CHLORIDES, DOUBLE BROMIDES, DOUBLE IODIDES. XYF, XYC1, BXYr, XYI. Hydrofluosilicic acid 2HF.SiF 4 .2H 2 O H 2 SiF 6 abt. 19 Kessler C. E., 90, 1285 38, 789 Aluminium sodium chloride Al 2 Cl 6 .2NaCl Al 2 Na2Cl 8 185 Deville J., 7, 332 phosphoric chloride A1 2 C1 6 .2PC1 6 AJ 2 P2C1 1C 400 Solid Baudrimont J., 15, 54 iv., 516 )> less v. than Weber P. A., 107, 375 J) either of component chlorides platinous chloride Al 2 Cl 6 .2PtCl 2 .2lH 2 O AJ 2 Pt 2 Cl 10 100 Nilsoii J. p. C. [2], 15, 260 32, 278 Auro-cerous chloride 2AuCl 3 .3CeCl 2 .20H 2 O Au 2 Ce 3 Cl 12 Much b. 100 Holzmann Z.C.P.[1862],668 vi., 420 Caesium platinous chloride .... 2CsCl.PtCl 2 CsjPtC^ .... Fuses with- Godeffroy A. P. [3], 9, 343 31, 686 out d. Calcium platinous chloride .... CaCl 2 .PtCl 2 .8H 2 CaPtCl 4 .... 100 Nilson J. p. C. [2], 15, 260 32, 277 Ferrico-sodic chloride 4NaCl.Fe.jCle.2H2O Fe 2 Na 4 Cl 10 200 Deville iii., 380 phosphoric chloride.... Fe 2 Cl 6 .2PCl 5 Fe 2 P 2 Cl 1(I a. 280 98 Baudrimont J., 15, 54 iv., 516 Mercuric chloride + hydro- 2HCl.HgCl2.7HjO H 2 HgCl 4 abt. 2 d. Ditte C. E., 92, 353 40, 355 chloric acid Tetra-ammoniacal hydro- HC1.4NH 3 H 13 N 4 C1 .... 7 Troost C. E., 88, 578 36, 501 chloride Hepta-ammoniacal hydro- HC1.7NH 3 H 24 N ? C1 .... 18 )) J) chloride Silicon chloroform HSiCl 3 35-37 Friedel & Ladenburg B. S. C. [2], 7, 322 vi., 1019 Hydrogen silico-chloride 3SiCl 2 .4HCl H 4 Si 5 Cl 10 42 Liquid Buff and Wohler J., 10, 166; A. v., 268 104, 94 Mercuric phosphochloride .... 3HgCl 2 .2PCl 5 Hg 3 P 2 Cl 16 v. abt. 200 Easily Baudrimont C. E., 55, 361 iii., 911; iv., 516 Nitrogen chlorophosphide .... N 3 P 3 C1 6 a. 240 110 Gladstone & Holmes J., 3, 283 iv., 517 )> .... I) 250-260 114 Wichelhaus G. J. C., 1870 Phospho-platinic chloride .... ci. 2 Pt:pci 3 PPtCl 5 170 Schutzenberger B. S. C. [2], 14, 178 vii., 987 Diphospho-platinic chloride.... Cl 2 PtPCl 3 .PCl 3 P.PtCl, 160 M B. S. C. [2] vii., 990 Platinico-phosphoric chloride PtCl 4 .2PCl s P 2 PtCl 14 a. 300 p. d. Solid Baudrimont iv., 516 Phosphoric selenium chloride 2PCl 5 .SeCl 4 P 2 SeCl I4 220 D J., 15, 54 iv., 515 Stannico-phosphoric chloride PCl 5 .SnCl 4 PSnCl, 220 ? Iv., 516 Titano-phosphorous chloride PCl 3 .TiCl 4 FTSO, .... 85-5 Bertrand B. S. C., 33, 565 40, 347 COMPOUNDS CONTAINING THREE ELEMENTS. 29 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Phosphoric zirconium chlo- PCl 5 .2ZrCl 4 PZr 2 Cl, 3 325 240 Paijkull B. S. C. [2], 20, 65 26, 1105 ride Platinous yttrium chloride .... 3PtCl 2 .Yt 2 Cl 6 .24H 2 O Pt 3 Yt 2 Cl 12 100 Nilson J. p. C. [2], 15, 260 32, 278 Auric hydrogen bromide .... HBr.AuBr 3 .5H 2 O AuHBr 4 27 Thomsen J. p. C. [2], 13, 337 30, 485 Mercuric hydrogen bromide HBr.HgBr 2 .4H 2 O HHgBr 3 .... 13 J.F.P.[2], 11,283 Tetra-ammoniacal hydro- HBr.4NH 3 H 13 N 4 Br 6 Trooat C. R., 92, 71 40, 972 bromide Hepta-ammoniacal hydro- HrBr.7NH 3 H^Br .... 20 j) u bromide Hydroplatinic bromide 2HBr.PtBr 4 .9H 2 O H 2 PtBr, .... 100 Topsoe T. [1868], 274 vi., 950 Ammonium thallium bro- NH 4 Br 3 .TlBr 3 .2H 2 O (NH 4 )TlBr 6 .... b. 100 Nickles C. R., 58, 537 v., 747 mide NH 4 Br 3 TlBr 3 .3H 2 O b. 100 1) Tetra-ammoniacal hydriodide HI.4NH 3 H 13 N 4 I abt. -12 Troost C. R., 92, 715 40, 972 Hepta-ammoniacal hydriodide HI.7NH, H^N,! -28 H Silicon iodoform HSiI 3 220 Liquid Friedel A., 149, 96 vi., 1022 3. BASIC HYDROXIDES. XHO. Barium hydrate Ba(OH) 2 .9H 2 O BaH 2 O a 75 Rosenstiehl and Ruhlmann C. C. [1870], 684 vii., 123 Sodium hydrate Ammonium hydrate 2NaH0.7H 2 O Saturated solution NaHO (NH 4 )HO 6 s. -38 to -41 Hermes Fourcroy and Vau- quelin P. A., 119, 170 v., 339 i., 185 4A. OXYCHLOEIDES. XC10. Carbon oxychloride .... See Part II. Chromium oxychloride .... CrO-A 115-9 (760) .... Thorpe 37, 362 jj .... 116-8 (733) 21, 514 vi., 456 >! 1! .... 117 .... Ramsay 35, 471 .... 117-6(753) .... Carstanjen Gm. Kr. Hb. * .... ) 118 (760) Walter A. C. P. [2], 66, 387 vi., 456 !1 .... )I 118 (?) (?) i., 954 Molybdenum oxychloride .... 2MoCl 6 .MoO 3 MoOCl 4 v. b. 100 b. 100 .... ill., 1042 Nitrosyl chloride NOC1 8 Tilden 27, 632 ,, J) -5 Girard and Pabst 1878 5 Miiller A., 205, 372 40, 506 dichloride NOC1 2 -7 .... Gay Lussac iv., 117 ,, J) 7-2 Baudrimont J. F. P., 31, 478 )> 5 Liquid Miiller A., 122, 1 vi., 437 Nitryl chloride NO 2 C1 5 Liquid )) ,, .... J> 5 1. -31 Odet and Vignon C. R., 69, 1 142 vi., 874 Phosphorus oxychloride o:pci 3 POC1 3 107-23 (760) Thorpe B., 8, 329 37, 338 M i> H 110 Cahours J. F. P., 45, 129 j) ii jj 110 ETeumann & Kochlin B., 15, 417 42,927 J J? 110 Wurtz J., 1, 365 iv., 596 j> i) j? )> 110 Wichelhaus J., 20, 149 vi., 935 !! )) ) ) 110(760) Buff A., 4, suppl., 129 )* 1> )) 1-5 Geuther&Michaelis B., 4, 769 24, 1162 )) )! + 2-5 Thorpe 24, 1162 vii., 962 Pyrophosphoric chloride 0=PC1 2 -0-PC1 2 =0 P 2 O 3 C1 4 210-215 1. -18 Geuther&Michaelis B. S. C., 16, 231 ; vii., 963 ; 24, B., 4, 767 1161 Thionyl dichloride a.so.ci soa 2 77 .... Henry A. S. S. B. .... .... 78 (746) Wurtz J. F. P., 99,225; vi., 1065 C. R., 62, 460 j) 78-8 (760) Thorpe 37, 354 j? ? > 82 Schiff J., 10, 105 v., 542 Sulphuryl dichloride Cl.SOj.Cl S0 2 C1 2 69-95 (760) Thorpe 37, 359 Jl !) ) 70 Beckurts and Otto B., 11, 2060 36, 201 30 COMPOUNDS CONTAINING THREE ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Sulphuryl dichloride CLSO-^Cl. SO 2 C1 2 70-71 Gustavson G. J. G, 1873 )J M 70-5 .... Behrend 1877 > j )1 72-73 .... Clausnizer B., 11, 2010 3) J> 77 Liquid Eegnault A. C. P. [2] vi., 576 )J 77 Liquid Williamson P. E. S., 7, 11 J) Sulphur oxychloride S 2 oa 4 60-61 Liquid Ogier C. E., 94, 446 42, 694 oxytetrachloride ... SOC1 3 .O.SOC1 S 2 O 3 C1 4 57 d. Michaelis and B., 6, 998, 27 27, 21, 226 Schifferdecker so 2 a 2 soci 2 jj 73 Liquid Michaelis&Mathias B., 6, 1452 27, 226 Pyrosulphuryl chloride S 2 o 6 ci 2 139-69 (760) .... Thorpe 37, 360 > .... 140-5 .... Ogier C. E., 94, 217 44, 900 i) S0 3 .S0 2 C1 2 or SC1 6 .5SO 3 145 .... Eose P. A, 44, 291 v., 535 >1 ) jj 144-148 Armstrong Z. C. [2], 6, 247 vi., 1070 )> )J )) 145-150 .... Eosensthiel J., 14, 121 v., 571 )! )) ao 2 s.o.so 2 ci jj 146 c. Michaelis Z. C. [2], 7, 149 vii., 1132 i 147 Heumann & Kochlin B., 16, 1630 44, 1051 11 .... j 153 (752) .... Konovaloff C. E., 95, 1284 ; 44, 553, 782, C. E., 96, 1059; 900 B., 16, 1127 Compound of hypochlorous C1 2 0.4SO S S 4 13 C1 2 .... 55 Schutzenberger J. [1861], 142 iii., 238 oxide and sulphur trioxide Antimony oxychloride ..,. .... Sb 3 OCl, 3 85 Williams C. N., 24, 224 25, 122 Sb 3 4 Cl 7 97-5 57 D Selenyl chloride a.seo.a Seoa 2 175-176(735) Clausnizer B., 11, 2010 > )I 179-5 (760) 10 Michaelis Z. F. C., 13, 460 vii., 1079 abt. 220 Liquid Weber J., 12, 91 v., 233 Trichlorosilicic oxide SiCl 3 .O.SiCl 3 Si 2 OCl 6 136-139 Friedel & Ladenburg J. F. P., 107, 247 vi., 1021 j> j) (Si 2 3 Cl 2 ), a. 400 Troost &Hautef euille A C. P. [5], 7, 453 30, 597 ,, ,, Si 4 3 Cl IO 152-154 > C. E., 73, 563 24, 1000 ,, j Si 4 4 Cl 8 198-202 A. C. P. [5], 7, 453 30, 597 i) Si 4 O 7 Cl 2 Not at 440 n ) jj s; 8 o 10 a 12 abt. 300 55 5) Telluryl chloride Cl.TeO.Cl TeOCl 2 Melts Ditte C. R, 83, 336 31, 45 Titanium oxychloride Ti 2 2 OCl 2 Cryst. ; d. on Friedel and Guerin A. C. P. [5], 7, 24 31, 171 heating Vandyl trichloride o:va 3 VOC1 3 126-7 (760) Eoscoe P. T., 168, 1 v., 993 .... .... JJ 127 Schafarik J. F. P., 76, 142 ) J) tt 127-19 (760) Thorpe 637, 349 JJ ) b. 15 Henry A. S. S. B. Tungsten oxychloride WOC1 4 .... 208-210 Schiff and Piretti G. J. C., 1879 I? )) .... ) v. 227-5 210-4 Eoscoe C. N., 25, 61 vii., 1185 .... W0 2 C1 2 v. 265-267 Solid Forcher W. A., 44, 159 v., 899 4B. CHLOKATES. XC10. Silver chlorate AgC10 3 230 Berthelot B. S. C. iarium chlorate Ba(C10 3 ) 3 .... 414 Carnelley 33, 277 ,, .... )) abt. 400 Tilden & Shenstone P. T., 1884 .... .... .... a. 400 Wachter A, 52, 231 .... a. 400 Souchay A., 102, 381 ?ostassium chlorate .... KC1O 3 .... 334 Pohl J., 4, 59 D By calorimeter T 359 Carnelley 33, 277 ,, By air thermometer I) .... abt. 370 Baudrimont J. p. C., 14, 81, 24, 1151 and 161 By calorimeter J .... 372 Carnelley 29, 496 .lithium chlorate 2LiClO 3 .H..O LiC10 3 .... Wachter A, 52, 231 Magnesium chlorate Mg(C10 3 ) 2 .6H 2 Mg(C10 3 ) 2 .... 40 Chenevix, Wachter A., 52, 231 sodium chlorate NaCIO, 302 Carnelley 33, 277 COMPOUNDS CONTAINING THREE ELEMENTS. 4o. PERCHLORATES. XC10. 31 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Silver perchlorate .... AgC10 4 .... 486 Carnelley & O'Shea 45,409 Barium perchlorate .... Ba(C10 4 ) 3 505 jj Hydrogeii perchlorate HC1O 4 .H 2 HC1O 4 .... 50 Eoscoe J., 14, 146 Potassium perchlorate Kcio 4 610 Carnelley & Williams 37, 125 Sodium perchlorate .... NaClO 4 482 Carnelley & O'Shea 45, 409 Thallium perchlorate T1C10 4 .... 501 j) SA. OXYBROMIDES. XBrO. Bismuth oxybromide .... BiOBr ...* Solid, un- Muir 29, 146 altered at red heat Nitrosyl bromide .... NOBr 2 .... Landolt G. J. C., 1860 dibromide .... .... NOBr 2 30-50 Muir 28, 844 tribromide .... NOBr 3 50-53 ) Phosphorus oxybromide .... POBr 3 195 45-46 Eitter J., 8, 301 iv., 596 J> V .... 46 Geuther&Michaelis B., 4, 770 5? .... ii 193 55 Baudrimont Tellurium oxybromide .... TeOBr 2 .... Melts Ditte C. E., 83, 446 30, 607 Vanadyl tribromide .... VOBr 3 v. 130-135 Liquid Roscoe P. T., 1869, 679 vi., 1125 (100) dibromide .... .... VOBr 2 .... d.a.180 with- 24, 25 out melting Tungsten oxybromide .... WOBr 4 327 277 G. J. C., 1872 5s. HYPOBROMITES AND BROMATES. XBrO. Hydrogen hypobromite .... HBrO 50 (50) MM Dancer 15, 447 iii., 237 Potassium bromate KBr0 3 .... a. 350 .... i., 672 ,, .... 434 Carnelley & O'Shea 45, 409 Sodium bromate .... NaBr0 3 381 Carnelley & Will iams 37, 125 6A, B, and c. OXYIODIDES, IODATES, AND PERIOD ATES. XIO. Phosphorus oxyiodide P 8 8 I 140 Burton A. C. J., 3, 280 42, 140 Lead oxyiodide PbI 2 .PbO Pb 2 OI 2 300 p. d. iii., 557 Hydrogen iodate (iodic acid) 2HI0 3 .9H 2 HIO 3 15 Kammerer P. A., 138, 390 vii., 593 Potassium iodate KIO 3 560 Carnelley & Williams 37, 125 Potassium periodate.... .... KI0 4 582 Carnelley & Williams 37, 125 Hydrogen periodate (periodic HIO 4 .2H 2 O HIO 4 ISO Langbois A. C. P. [3], 34, iii., 308 acid) 257; J., 5, 343 ? > .... 130 Lautsch J. p. C., 100, 65 vi., 743 ;j j> )) 130-136 Eammelsberg J.p.C. (?) )J 7. SULPHOCHLORIDES, SULPHOBROMIDES, SULPHOIODIDES. XC1S, XBrS, XIS. Carbon sulphochloride .... CSC1 2 See carbon compounds, Part II. Phosphorus sulphochloride .... PSC1 3 124-25 .... Baudrimont B.S.C.[1861],117 iv., 606 ; )> .... .... 124-5 .... Chevrier Gm. Kr. i> j .... 124-125 Baudrimont J., 14, 115 37, 341 51 )> 125 (760) Thorpe B., 8, 330; C. N., vii., 965; 37, 24, 135 341 )1 .... 126-127 Mitscherlich .... 37, 341 )) J .... .... 126-127 .... Cahours J., 1, 364 iv., 606 )) .... (?) Flemming Z. C. [2], 4, 288 vi., 935 5) .... .... 125-128 .... Henry B., 2, 639 )> 32 COMPOUNDS CONTAINING THREE ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Silicon sulphochloride ..* Si 3 S 2 Cl 8 (?) abt. 100 Liquid Pierre J.F.P.,41, 342; v., 276 or Si 3 S 4 01 8 A., 69, 73 Arsenic sulphobromide AsSBr.SBr 2 AsS 2 Br 3 abt 17 Hannay 33, 291 Phosphorus sulphobromide .... PSBr 3 35 Michaelis B., 4, 777 24, 1162 .... 36-4 Maclvor C. N., 29, 116 )> i> .... 38 Michaelis G. J. C., 1872 vii., 964 )> 215 39 Baudrimont (?) ) PSBr s .H 2 O 35 Michaelia A., 164, 9 vii., 964 > P 2 SBr 6 abt. 205 -5 M ) Phosphorus tribromide and 6PBr 3 .P 3 S 3 P 8 S 3 Br 18 200 Liquid Gladstone P. M. [3], 35, 352 iv., 510 Phosphorus trisulphide Arsenic sulphoiodide AsI 3 .As 2 S 3 As 3 S 3 I 3 Slightly a. 100 Schneider Jp.C. [2], 23, 486 40, 686 8A. OXYSULPHTDES, &c. XOS. (?) I,0,S a.!60-170p.d. Solid Weber J.p.C [2] 25 224 42 803 Nitrosulphuric anhydride .... ONO.SO.j.O.SO.jONO SAtNO,)., N 2 O 9 S 2 360 abt. 360 Solid Crystalline Thorpe and Dyson Michaelis and Schu- 41, 299 B. 7, 1076 28,43 mann Tellurium oxysulphide Te f> 2 S/ Te0 3 S Softens at 30 without melting Divers andShimosfi 43, 325 SB. SULPHITES, SULPHATES, AND ANHYDROSULPHATES. XOS. Hydrogen sulphite (sulphur- ous acid) H 2 SO 3 .8H 2 O H.S0 3 4 Pierre A. C. P., 68, 228 v., 541 Silver sulphate .... Ag 2 S0 4 654 Carnelley 33, 279 Cobalt sulphate CoS0 4 .7H 2 O CoSO 4 96-98 Tilden 45, 267 Ferrous sulphate FeS0 4 .7H 2 O FeS0 4 64 J Ferric sulphate Fe 2 O 3 .2SO 3 .15H 2 O Fe 2 S 2 O 9 110-115 Meister B., 8, 772 29, 681 Hydrogen sulphate (sul- Pure, sp. gr. 1'842 H 2 S0 4 327 s. 35 .... v., 573 phuric acid) .... .... 34-4 Eegnault n .... jj 325 .... lit, 84 .... 338 10-5 Marignac J., 6, 325 vi., 1068 12H 2 SO 4 .H S O N 338 0-5 G. J. C., 1853 )) !> H 2 S0 4 .H 2 O 205-210 s. 8-9 Wackenroder J., 2, 249 v., 574 ) 7-5 Pierre and Puchot G. J. C., 1874 !> I) j) ) .... 8-5 Marignac J., 6, 325 H 2 SO 4 .2H 2 O ) 193 .... (?) , (?) v., 574 )) Sp.gr. 1-671 > .... 1. 20 Lunge B., 14, 2650 42, 362 1-727 >j .... -7'5 )> )> )! JJ J 1-732 .... 8-5 )j ) 1-749 j) +4-5 5 5 5 1-767 )j +6-5 U )i )) !) )> 1-790 +8-0 )) 1-807 >j -6-0 )> n 1-822 .... 1. -20 M (fuming) H 2 SO 4 .S0 3 H 2 S 2 7 s. (?) (?) v., 574 )J .... 35 Marignac G. J. C., 1853 )> )) 35 Schultz-Sellack B., 4, 110 24, 194 ) H 2 S0 4 .3SO 3 H 2 S 4 13 .... s. 8-10 Weber P. A., 159, 313 32, 165 1> For table of b. p.'s of sul- phuric acid of various con- centrations, see Part III. COMPOUNDS CONTAINING THREE ELEMENTS. 33 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Potassium sulphate .... .... K 2 S0 4 a. 861 Carnelley Unpublished disulphate .... K 2 S 2 ? 210 Jacquelain A. C. P., 32, 234 ; v., 609 A. C. P. [1870], 311 5? Considerably Schultz-Sellack G. J. C., 1871; vii., 1140; 24, a. 300 B., 4, 111 194 Potassium quadrisulphate .... K 2 S0 4 .3SO 3 .6H 2 O K 2 S 4 3 .... 61 Lescceur C. R, 78, 1044 27, 870 Lithium sulphate Li 2 SO 4 818 Carnelley 33, 280 !! I) .... 822 29, 498 Magnesium sulphate .... MgS0 4 Bed heat (?) (?) without d. j Mg.SO 4 .7H 2 O a 70 Tilden 45, 267 Manganese sulphate MnSO 4 .5H 2 O MnS0 4 54 Sodium sulphate .... Na 2 SO 4 .... 861 Carnelley 33, 280 ,, .... !> 865 29, 498 .... .... )> .... 1280 Braun P. A., 154, 190 Na 2 S0 4 .10H 2 O )! .... 34 Tilden & Shenstone P. B. S., 35, 345 46, 254 )> 34 Tilden 45, 267 quadrisulphate Na 2 S0 4 .3SO 3 .6H 2 O Na 2 S 4 3 90 Lescceur C. R, 78, 1044 27, 870 Ammonium sulphate .... (NH 4 ) 2 S0 4 d. a. 280 140 Marchand P. A., 42 i., 193 Nickel sulphate NiS0 4 .7H 2 NiS0 4 98-100 Tilden 45, 267 Nitrosyl sulphate .... (N0) 2 S0 4 85-87 i 27, 631 Thallium sulphate .... T1 2 S0 4 632 Carnelley 33, 279 Zinc sulphate.... .... ZnSO 4 .7H 2 O ZnSO 4 50 Tilden 4"i 9fi7 "", 1 M 8c. THIOSULPHATES. XOS. Potassium tlriosulphate .... K 2 S 2 3 d. 550 Berthelot J.Ph. [2], 23, 247 31, 278 Sodium thiosulphate Na 2 S 2 3 .5H 2 Na 2 S 2 O 3 45 Kopp J., 8, 45 iii., 75 M 48-1 Trentinaglia 1876 J5 )J 48-5 Tilden 45, 268 JJ )J j 56 Bottger (?) v., 636 1> )> Dimorphous j) 47-9 Parmentier & Amat C. B., 98, 735 46, 819 )) ) ) ) .... 32 9. SELENITES AND SELENATES. XSeO. Mercurous selenite .... Hg 2 Se0 3 Boils 180 Berzelius and Mus- 2, 52 v., 228 pratt Hydrogen selenate (selenic Most concentrated, not quite 280 .... v., 230 acid) free from H 2 O H 2 Se0 4 10. CHROMATES AND BICHROMATES. XCrO. Potassium dichromate K 2 Cr 2 7 abt. 400 Tilden & Shenstone P. T., 1884 Sodium chromate Na 2 CrO 4 .10H 2 O Na 2 CrO 4 23 Berthelot 45, 268 11. BORATES. XBO. Calcium borate CaH2B 4 O 8 .2H 3 B0 3 = CaB 6 O 10 CaB 6 10 Loses its 450 Ditte C. R, 77, 783 27, 127 4H 2 water at 200 Hydrogen borate By thermometer H 3 B0 3 184 Carnelley 33, 275 .... .... By sp. ht. method ) .... 186 JJ Sodium metaborate NaB0 2 .4H 2 NaBO 2 .... 57 I., 645 borate Na 2 B 4 O ; 561 33, 278 ,, .... .... j) .... 1000 Quincke P. A. vii., 242 (borax) Na 2 B 4 O 7 .10H 2 O D .... 75-5 Tilden 45, 268 COMPOUNDS CONTAINING THREE ELEMENTS. 12A. and B. NITRITES AND NITRATES. XNO. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Gh. Soc. Silver nitrite .... AeNOo Begins abt. Divers 2491 "O 2 134 after p.d. Silver nitrate.. Mercury thermometer AgNO, 198 Pohl. J., 4, 59 "^o 3 ,, Sp. ht. method ll 217 Carnelley 33, 276 Mercury thermometer 211 u. c.= ll SIS c. 219 (?) (?) iv., 104 11 11 By sp. ht. method ll 224 Carnelley 29, 496 Aluminium nitrate A1 2 (NO 3 ) 8 .18H 2 O A1 2 (N0 3 ) 6 134 72-8 Ordway J. 12, 114; A. 76, iv., 89 247 Barium nitrate Ba(NO s ) 2 450 (?) Maumene C. R., 97, 1215 46, 384 593 Carnelley 33, 278 Beryllium nitrate Be(N0 3 ) 2 .3H 2 11 Be(N0 3 ) 2 140-5 60 Ordway J., 12, 114 iv., 92 Calcium nitrate Ca(N0 3 ) 3 561 Carnelley 33, 278 450-500 (?) Maumenfi C. R., 97, 45 46, 3 Ca(NO) 4HO 11 132 44 Ordway J., 12, 115 ; iv., 91 11 S. A. J., 27, 14 Cadmium nitrate Cd(N0 3 ) 2 .4H 2 Cd(N0 3 ) 2 132 59-5 J., 12, 114; iv., 90 S. A. J., 27, 14 Cobalt nitrate Co(N0 3 ) s .6H 2 Co(N0 3 ) 2 b. 100 .... iv., 92 Chromium nitrate Cr 2 (N0 3 ),.18H 2 O Cr 2 (N0 3 ) 6 125-5 37 Ordway J., 12, 115; iv., 91 S. A. J. [2] Copper nitrate Cu(N0 3 ) 2 .3H 2 O Cu(N0 3 ) 2 170 114-5 J., 12, 114 iv., 92 Didymium nitrate Di(NO 3 ) 3 abt. 300 Frerichs B., 7, 800 11 ,, 300 A., 191, 331 34, 647 Ferric nitrate Fe 2 (NO a ) 6 .12H 2 Fe 2 (N0 3 ) 6 ... 35 Hausmam A., 89, 109 iv., 93 FeJNO,'). 18EL.O 125 47-2 Ordway J., 12, 114 J. c 2 ^-L1\y 3 ^g. 10J.J. 2 W 11 Hydrogen nitrate (nitric acid] .... HN0 3 86 Mitscherlich P. A., 18, 152 11 11 11 .... 11 86 .... Millon J. F. P., 29, 337 11 11 .... 11 86 55 .... iv., 80 11 11 !> .... 11 -47 Berthelot B. S. C., 293 34, 263 11 11 11 2HNO 3 .3H 2 O 11 123 Liquid Millon iv., 80 11 11 11 68%.HNO 3 11 120-5(735) Eoscoe G. J. C., 1860 15 11 11 2HN0 3 .N 2 S H 2 N 4 O n .... s. 5 Weber J. F. P., 6, 357 ; vii., 856 P. A., 147, 113 25, 1073 Murcuric nitrate Hg(N0 3 ) 2 .8H 2 Hg(N0 3 ) 2 6-6 Ditten J., 7, 366 iv., 96 Potassium nitrate .... KNO 3 s. 320 Guthrie P. M. [5], 18, 114 .... 11 .... s. 327 Maumen6 C. R., 97, 45 46,3 11 55 '" *"* .... 11 s. 338-3 c. Schaffgotsch P. A., 102, 293 11 11 .... 11 .... 339 Person J.,1,73; A.C.P. iii., 77 [3], 27, 250 11 11 .... 11 .... 339 Carnelley 33, 277 11 11 .... 11 342 Braun P. A., 154, 190 11 11 1) 353 Carnelley 29, 496 Lanthanum nitrate La (N0 3 ) 3 .3H 2 La(N0 3 ) 2 120 40 Ordway J., 12, 114 iv., 94 Lithium nitrate By thermometer LiNO 3 .... Mtf Carnelley 33, 275 By sp. lit. method 267 Magnesium nitrate Mg(N0 3 ) 2 .6H 2 Mg(N0 3 ) 2 143 90 Ordway J., 12, 113 Manganese nitrate Mn(NO 3 ) 2 .6H 2 Mn(NO 3 ) 2 129-5 25-8 Sodium nitrate (Commercial) NaNO 3 .... 286'8 u.c. Cross and Bevan 41, 112 s. 298 Maumene C. R., 97, 45 46, 3 SIO'5 Person J.,1,73; A. C.P. iii., 77; iv., 106 " [3], 27, 250 s. 313-1 c. Schaffgotsch P. A., 102, 293 iv., 106 H 314 Braun P. A., 154, 190 By sp. ht. method M S16 Carnelley 33, 276 " COMPOUNDS CONTAINING THREE ELEMENTS. 35 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Sodium nitrate By thermometer NaNO 3 303 u. c.= Carnelley 33, 276 319 c. ) NaNO 3 .7H 2 O .... 1. a. 15 Ditte B. S. C., 24, 366 )> 15 C. K., 80, 1164 28, 734 Ammonium nitrate .... NH 4 NO S 180 108 (?) (?) i., 192 u )) 145 Frankenheim P. A., 93, 17 ,, .... ) .... abt. 152 Berthelot G. J. C., 1876 > jj .... .... J) 153 Maumen6 C. K., 97, 1215 46, 382 159 Veley 43, 374 ,, ,, n 165-166 Pickering C. N., 38, 267 36,200 Nickel nitrate Ni(N0 3 ) 2 .6H 2 Ni(N0 3 ) 2 136-7 56-7 Ordway J. 12, 114 Lead nitrate .... PbfNO,1 n 450 (1) ]M!aumen6 C. E., 97, 1215 46, 384 * "V ^3/2 -xu\s y.y Strontium nitrate Sr(N0 3 ) 2 .... 645 Carnelley 33, 279 Thallium nitrate .... TlNOg 205 Crookes J., 16, 252 17, 141 Uranium nitrate .... _.. UO 2 (NO 3 ) 2 .6H 2 O UN 2 8 118 59-5 Ordway J., 12, 114 vii., 860 ,, U0 3 (N0 3 ) 2 .3H 2 .... 120 Schultz-Sellack Z. F. C., 13, 646 Ytterbium nitrate Contains water of crystal- (?) 100 Nilson C. R., 91, 56 38, 703 lization Zinc nitrate .... Zn(NO 3 ) 2 .6H 2 O ZnfNO,) 131 36'4 Ordway J., 12, 113 LJU^XI ^^3^2 50 Schindler iv., 107 i )) 13. HYPOPHOSPHITES, PHOSPHITES, ORTHOPHOSPHATES, PYROPHOSPHATES AND METAPHOSPHATES. XPO. Hydrogen hypophosphite H 3 P0 2 17-4 Thomsen B., 7, 994 vii., 965 (hypophosphorous acid) Hydrogen phosphite (phos- H 3 PO, 70-1 Thomsen B., 7, 996 vii., 965 phorous acid) j' j) ) 74 Hurzig & Geuther A.C. P., Ill, 170 iv., 528 Silver phosphate Ag 3 P0 4 a. 849 Carnelley 33, 280 Hydrogen phosphate (phos- H 3 .P0 4 38-6 Thomsen J. F. P. [2], 2, 160 B., 7, 997 phoric acid) jj )) 41-75 Berthelot B. S. C., 1878 34,263 Lithium phosphate Li 3 PO., .... a. 857 Carnelley 33, 280 Sodium phosphate Na 3 PO 4 .12H 2 O Na 3 PO 4 77 C) (?) iv., 580 Silver pyrophosphate Ag 4 P 2 7 585 Carnelley 33, 278 Sodium pyrophosphate .... Na 4 P,,0. a. 888 33,280 Lead pyrophosphate Pb 2 P 2 7 806 Silver metaphosphate AgP0 3 482 Carnelley 33, 278 hexametaphosphate .... Ag 6 P 6 ls Becomes sof l .... iv., 576 and semi- fluid at 102, and melts at higher temp. Sodium metaphosphate NaPO 3 617 Carnelley 33, 279 Lead metaphosphate Pb(P0 3 ) 2 800 33, 280 F 2 36 : -.-*''"'' COMPOUNDS CONTAINING THREE ELEMENTS. 14. VANADATES. XVO. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. Silver orthovanadate 6Ag 2 O.2V 2 O 5 Ag 3 V0 4 Appeared to 403-565 Carnelley 33, 277 soften and then melt pyrovanadate 6Ag,0.3V 2 5 Ag 4 V 2 O r 383 ,j ji octovanadate .... 6Ag 2 O.4V 2 5 Ag, 2 V 8 26 384 Barium pyrovanadate :... 6BaO.3V 2 O 5 Ba.V.,0, a. 863 33, 280 Calcium tetradecavanadate.... 6CaO.12V 2 O 5 CaV 4 O n 637 ,, 33, 279 Sodium orthovanadate 6Na,,O.2V 2 O 6 NajVO 4 .... a. 866 33, 280 pyrovanadate eNa/XSVjOs Na 4 V 2 O 7 654 1, 33, 279 octovanadate 6Na. 2 0.4V 2 O 5 Na 12 V 8 2 , 562 1) 33, 278 ,, metavanadate 6Na 2 O.6V 2 O 6 NaV0 3 562 ,, ,, tetradeeavanadate .... 6NajO.i2V,o s Na 3 V 4 O u .... 581 n Basic lead pyrovanadate 6Pb0.2V 2 O 6 or 2 (Pb 2 V 2 7 ). Pb 6 V 4 15 731 , 33, 279 PbO Lead metavanadate 6PbO.6V 2 O 6 Pb(V0 3 ) 2 .... a. 849 33, 280 Thallium orthovanadate 6T1 2 0.2V 2 5 T1 3 V0 4 566 , 33, 278 pyrovanadate 6T1 2 O.3V 2 O 6 Tl 4 V n 7 454 M octovanadate 6T1 2 0.4V 2 5 T1, 2 V 8 26 392 ,, 33, 277 decavanadate 6TL,O.5V 2 O 5 T1,. 2 V 10 3 , 404 n metavanadate 6T1 2 0.6V 2 6 T1V0 3 424 > tetradecavanadate 6T1 2 O.7V 2 O 5 T1 12 V 14 41 408 > ) 15. ARSENATES. XAsO. Hydrogen arsenate (arsenic acid) Sodium arsenate 2H3A8O4.H.JO Na 3 AsO 4 .12H s O H 3 As0 4 Na 3 AsO 4 .... 100 86 .... .... i., 378 i., 384 16. CARBONATES. XCO. Potassium carbonate K,C0 3 834 Carnelley 33, 280 .... )) 838 , 29, 498 .... J) 1150 Braun P. A., 154, 190 Lithium carbonate .... Li 2 C0 3 695 Carnelley 33, 279 .... ) 699 n 29, 497 Sodium carbonate .... Na 2 CO 3 814 33, 280 .... n 818 29, 498 .... > 920 Braun P. A., 154, 190 33, 280 Na-jCOj+lOHjO j 34 Hammerl M. C., 3, 419 42, 1164 34 Tilden 45, 268 Rubidium carbonate .... Rb 2 C0 3 837 Carnelley & Williams 37, 125 Thallium carbonate .... T1 2 C0 3 269 Williams 33, 275 1! Mercury thermometer >J 861 u. c.= Carnelley )> 272 c. )> Calorimeter }) 273 ,, 17. SILICATES. XSiO. Silico-oxalic acid HjSi 2 O 4 Cryst. ; does Friedel and Laden- A. C. P. [5], 19 38, 608 not melt burg 390 at 100 Sodium silicate Na^iCvSHjO Na 2 Si0 3 45 Ordway S.A. J.[2],40, 186 vi., 1018 UNIVERSn V ] 37 IV. COMPOUNDS CONTAINING FOUR ELEMENTS. 1. DOUBLE SULPHATES AND DOUBLE SELENITES. XYSO AND XYSeO. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. . __ Trihydrogen argentic sul- AgH 3 (S0 4 ) 2 .H 2 AgH 3 (S0 4 ) 2 100-150 Schultz yi., 1073 phate Aluminium caesium sulphate AlCs(SO 4 ) 2 .12H 2 O AlCs(S0 4 ) 2 .... 105-106 Tilden 45, 267 potassium sul- A1K(S0 4 ) 2 .12H 2 A1K(S0 4 ) 2 .... 84-5 J) phate Aluminium sodium sulphate AlNa(SO 4 ) 2 .12H 2 O AlNa(SO 4 ) 2 61 j ammonium sul- A1(NH 4 )(SO 4 ) 2 .12H 2 O A1(NH 4 ) 92 H phate (S0 4 ) 2 Aluminium rubidium sul- AlRb(S0 4 ) 2 .12H,O AlRb(S0 4 ) 2 .... 99 )> phate Hydrogen calcium sulphate.... CaS0 4 .3H 2 S0 4 CaH 6 (S0 4 ) 4 Alittlea.100 Schultz P. A., 133, 137 vi., 1071 Chromium potassium sulphate CrK(SO 4 ) 2 .12H 2 O CrK(SO 4 ) 3 89 Tilden 45, 267 ammonium sul- Cr(NH 4 )(S0 4 ) 2 .12H 2 Cr(NH 4 ) 100 .... v., 588 phate (S0 4 ) 2 Hydrogen potassium sulphate HKSO 4 197 v., 608 > ij 5 .... )> .... 200 Mitscherlich G. J. C., 1830 " 210 Schultz-Sellack B.,4,111 potassium anhy- KHS0 4 .S0 3 HKS 2 O r 168 J> 24, 194 drosulphate Trihydrogen potassium sul- KHS0 4 .H 2 SO 4 H 3 K(S0 4 ) 2 abt. 95 Schultz .... vl., 1073 phate Hydrogen lithium sulphate.... .... HLiSO 4 160 .... vi., 1072 Trihydrogen sodium sulphate H 3 Na(SO 4 ) 2 abt. 100 j> vi., 1073 Indium ammonium sulphate In(NH 4 )(S0 4 ) 2 .12H 2 O In(NH 4 ) 36 Rossler J. p. C. [21 7, 14 vii., 669 (S0 4 ) 2 Trihydrogen lithium selenite LiHSeO 3 .H 2 SeO 3 H 3 LiSe 2 6 100 Crystalline Nilson B.S.C. [2], 21, 253 28, 420 2. DOUBLE NITEATES. XYNO. Auric hydrogen nitrate Au(NO 3 ) 3 .HNO 3 .3H 2 O AuH(N0 3 ) 4 72-73 Schottlander A., 217, 312 44, 855 Cerous magnesium nitrate .... Ce(N0 3 ),..M g (No 3 ), ! .5H 2 CeMg(N0 3 ) 4 200 Lange J. p. C., 82, 129 Iv., 91 Hydrogen potassium nitrate KN0 3 .2HNO 3 H 2 K(N0 3 ) 3 3 Ditte C. R., 89, 576 38, 154 ammonium nitrate (NH 4 )N0 3 .HN0 3 H(NH 4 ) 9 )> it 38, 153 (N0 3 ) 2 )) " 1! (NH 4 )NO 3 .2HN0 3 H 2 (NH 4 ) 18 j) (N0 3 ) 3 3. HYPOPHOSPHITES, DOUBLE PHOSPHATES, AND DOUBLE ARSENATES. XYPO AND XYAsO. Ammonium hypophosphite.... (NH 4 )H 2 P0 2 d. 240 200 (?) (?) iv., 525 Potassium dihydrogen phos- H 2 KP0 4 96 Tilden 45,268 phate Disodiumhydrogen phosphate HNa 2 P0 4 .12H 2 O HNa 2 PO 4 35 Kopp J., 8, 45 )i ) 35 Tilden 45, 268 J 5 .... )) 36-4 Person J., 1, 72 Sodium dihydrogen phosphate H n NaPO 4 204 (?) (?) iv., 579 NaH 2 P0 4 +Na 2 HP0 4 .... H 3 Na 3 (P0 4 ) 2 a. 200 Filhol & Senderens C. R., 94, 649 42, 693 H 3 Na 3 (PO 4 ) 2 .15H 2 O )) 55 5> Tt Thallium dihydrogen phos- H 2 T1P0 4 190 Lamy J., 18, 246 phate Dithallium hydrogen phos- 2HT1 2 P0 4 .H 3 HT1 2 PO 4 145 ) phate Potassio-sodic dimetaphos- KNaP^+HjO KNaP 2 O 6 a. 150 Fleitmann (?) iv., 578 phate Disodium hydrogen arsenate HNa 2 AsO 4 .... a. 200 (?) (?) i., 384 i HNa 2 AsO 4 .12H.,O 28 Tilden 45, 268 38 COMPOUNDS CONTAINING 4. COMPOUNDS CONTAINING XHC1S, XHC1N, FOUR ELEMENTS. XHBrN, XHOB, XHON, AND XHOSi. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. Trichlorsilicon sulphydrate.... SiCl 3 .SH SiHCl 3 S 96 Liquid Friedel & Ladenburg B. S. C. [2], 7,472 vi., 1023 ; vii., 1086 JJ 95-97 .... A. C. P. [4], 27,416 26, 53 Silver ammoniochloride Mercuric ammoniochloride .... AgCl.NH 3 HgCl 2 .NH 3 AgH 3 ClN HgH 3 Cl 2 N 590 38 Solid Faraday Eose .... i., 183 iii., 898 Silver ammoniobromide AgBr.NH 3 AgH 3 BrN 90 Terreil C. E., 98, 1279 46, 890 Fluoboric acid HBO 2 .3HF F 3 H 4 2 B a. 100 Gay - Lussac and Thenard i., 633 Ammonio-silver nitrite ammonium nitrate AgNO 2 .NH 3 2(NH 4 )N0 3 .3NH 3 AgH 3 2 N 2 (NH 4 ) 2 H 9 6 .... 70 22 Eeychler Troost B., 16, 2425 C. E., 94, 789 46, 157 42, 1162 Tetrammonioplatinous oxide Silicotungstic acid Tungstosilicic acid Si0 2 .12WO 3 .4H 2 O SiO 2 .12WO 3 .4H 2 O PtH 12 ON 4 W 12 H 8 42 Si 110 d. 36-53 b. 100 Marignac A. C. P. [4], 3, 5 iv., 675 v., 916 v., 917 5. COMPOUNDS CONTAINING XClBrO, XClBrS, XC10S, XClOCr, XC10N, XC10P, XC10V. Phosphorus oxychlorobromide PCl 2 BrO 135-137 Liquid Menschutkin J. F. P., 98, 485 vi., 935 ) 11 Geuther & Michaelis B., 4, 770 24, 1162 >! )) 137-6 c. (760) .... Thorpe 37, 343 Phosphorus sulphochlorobro- PC'l 2 .SBr PCl 2 BrS Begins to boil .... Michaelis B., 5, 8 vii., 965 mide 150 ; d. Pyrosulphuric chloride HC10S (?) 140-5 c. Ogier C. E., 96, 648 44, 646 Sulphuryl hydroxyl chloride C1.SO 2 .OH HC10 3 S 145 Liquid Williamson P. E. S., 7, 11 v., 576 (chlorosulphuric acid) J) 150-151(726) .... Clausmizier A., 196, 265 ; 36, 691 B., 11, 2008 ? )) 150-7-152-7 c. Beckurts and Otto B., 11,2059 36, 200 H 155-3 c. (760) .... Thorpe 37, 358 j> 158-4 c. Liquid Michaelis Z. C. [2], 7, 150 vii., 1135 Potassium chlorosulphate C1.S0 2 .OK KC10 3 S 190 Miiller B., 6, 231 26, 842 !) )) 300-350 (?) )) ) Phosphorus pentachloride + PC1 6 .SO 2 PC1 5 2 S 100 .... Kremers J., 2, 245 sulphur dioxide Sulphoselenium oxytetra- ClSO 2 .OSeCl 3 SeCl 4 3 S 183d. 165 Clausmizier A., 196, 265 ; B., 36, 691 ; 36, chloride 11, 2007, & 2009 201 Action of SO 3 on SeCl 4 2(SeCl 6 .5S0 3 ).5(SeCl 4 .Se0 2 ) SeCl 4 3 S 187 Crystalline Eose and Berzelius P. A., 44, 315 ; v., 224 or SeCl 4 .SO 3 A. C. P.[2],9, 225 CaCl 2 .2CrO 3 .5H 2 O CaCl.,O 6 Cr 2 56 Pratorius A., 201, 1 CoCl 2 .2CrO 3 .9H 2 O CoCl 2 O 6 Cr 2 40 JT n MgCl,.2CrO 3 .9H 2 O MgCl 2 O 6 Cr 2 66 J >) NiCl 2 .2CrO 3 .9H 2 O NiCl 2 O 6 Cr 2 47 > j) SrClj^CrO^HjO SrCl 2 O 6 Cr 2 72 j) ZnCl 2 .2CrO 3 .9H 2 O ZnC'l 2 O 6 Cr 2 37-5 )> Action of N 2 O 4 on BC1 3 BC1 3 .NOC1 BC1 4 ON 23-24 Geuther J. p. C. [2], 8, 354 27, 540 Hydroxylamine hydrochlo- NH 2 (OH).HC1 H 4 C10N .... 100 Lessen Z. C. [2], 1, 551 vi., 723 ride Hydroxylamine hemihydro- 2NH 2 (OH).HC1 H 7 C10 2 N 2 .... 85 vii., 662 chloride Hydroxylamine sesquihydro- 3NH 2 (OH).2HC1 HnC^N, .... 95 )! chloride COMPOUNDS CONTAINING FOUR ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. A1C1 3 .POC1 3 AlCljOP 165 Casselmann A. iv., 597 As 2 3 -PCl 5 (?) As 2 Cl 8 3 P(?) 110 Person and Bloch J. [1849], 246 vi., 220 BC1 3 .POC1 3 BC1 6 OP 73 in sealed Gustavson B., 4, 975 vlt, 208 tubes MoCl 5 .POCl 3 MoCl 8 OP 170 d. 125-127 Wehrlin & Giraud J. [1877], 278 JJ J> nod. 125-127 Piutti G. I., 9, 538 38, 220 SnCl 4 .POCl 3 SnCl,OP 180 55 Casselmann A. iv., 597 > J 180 66 jj A., 83, 257 v., 809 TiCl 4 .POCl 3 TiCl 7 OP 140 110 Wehrlin & Giraud J. [1877], 278 Vanadinite 3Pb 3 (VO 4 ) 2 .PbCl 2 Pb 5 C10 12 V 3 a. 802 Carnelley 33, 280 V. COMPOUNDS CONTAINING FIVE ELEMENTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Potassium nitrosulphate KjSCVHNO, HK 2 O 7 SN 150 Jacquelain A. C. P., 32, 234 phosphatosul- K 2 S0 4 .H 3 P0 4 H 3 K 2 8 SP .... 240 sj )J phate Cadmium tungstoborate (2CdO.B 2 O 3 .9WO 3 .2H 2 O). H 4 CdA.W. .... 75 Klein B. S. C. [2], 36, 42, 17 16Aq. B 2 205 40 VI. METALLIC ALLOYS. A. ALLOYS OF TWO METALS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. p.c. p.c. Ag. Au. 1. Alloys of Ag and Au Determined with air ther- 100+0 954 Erhard & Schertel W. A. C. P. B. mometer, the general error [1879], 348 being less than 20 C. jj j jj j' 80 + 20 975 jj jj jj jj jj j) J 60 + 40 995 jj u j jj jj jj J> 40 + 60 .... 1020 jj jj jj jj j jj * > 20 + 80 1045 jj jj JJ IT jj jj IJ +100 1075 jj jj JJ JJ p.c. p.c. Ag. Cu. 2. Alloys of Ag and Cu Determined by calorimeter 100-0+ o 1040 W. Roberts A. C. P. [5], 13, 28, 736 jj j )j )j 92-5+ 7'5 .... 931 )J 118 jj > 82-1+ 17-9 886 JJ jj j jj j jj 79-8+ 20-2 887 JJ jj j " jj jj jj 77-4+ 22-6 858 JJ jj jj j jj jj jj ? 75-0+ 25-0 850 J jj jj JJ JJ ) 71-9+ 28-1 870-5 jj jj j> jj JJ JJ ) 63-0+ 37-0 .... 847 > j> jj j; j JJ JJ ) 60-0+ 40-0 857 ?> j jj " jj JJ JJ > ? 57-0+ 43-0 900 j jj jj j) JJ )J ) 54-1+ 45-9 920 )J j> u jj jj JJ JJ > 50-0+ 50-0 941 JJ >j jj jj jj JJ JJ 45-9+ 54-1 961 JJ jj jj jj J JJ "" )> !) 25-0+ 75-0 1114 JJ jj jj j> jj JJ J JJ J) +100-0 1330 ) jj jj jj jj p.c. p.c. Au. Pt. 3. Alloys of Au and Pt Determined with air ther- 100 + .... 1075 Erhard & Schertel W. A. C. P. B. mometer, the general error [1879], 348 being less than 20 C. jj jj jj jj 95+5 .... 1100 jj jj JJ )J j jj jj jj 90 + 10 1130 jj JJ JJ jj j jj 85 + 15 .... 1160 j jj JJ JJ j jj jj jj 80 + 20 1190 jj >? JJ JJ JJ JJ jj jj 75 + 25 .... 1220 jj jj JJ JJ J JJ jj jj 70 + 30 1255 jj jj JJ JJ JJ JJ "" jj jj 65 + 35 .... 1285 jj > JJ JJ JJ JJ jj jj 60 + 40 1320 jj jj JJ JJ )) JJ " jj jj 55 + 45 1350 jj jj JJ JJ )> JJ jj jj 50 + 50 1385 jj jj JJ JJ J )J " jj jj 45 + 55 1420 jj jj JJ JJ JJ JJ jj u 40 + 60 .... 1460 jj . jj JJ JJ JJ JJ jj jj 35 + 65 1495 jj jj JJ JJ JJ JJ jj jj 30 + 70 1535 jj jj JJ JJ JJ JJ jj jj 25 + 75 1570 jj jj JJ JJ JJ JJ jj jj 20 + 80 1610 jj jj JJ JJ J) JJ jj u 15 + 85 1650 jj jj JJ JJ JJ >J jj jj 10 + 90 1690 jj jj JJ JJ JJ J " j u 5 + 95 1730 jj jj JJ JJ J1 JJ jj +100 .... 1775 jj jj JJ JJ METALLIC ALLOTS. 41 Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Gh. Soc. 4. Alloys of Bi mid Cd .... Bi 2 Cd .... 146-3 Kudberg P. A., 71, 460 J., 1, 71 5. Alloys of Bi and Pb BiPb a. 146 .... ill., 533 jj jj . 146 & 125 Wiedemann A. C. P. [2], 20, 228 46,8 jj j * .... BiPb 2 s. 180 & 125 j> jj ts BijPb s. 143 .... Hi., 533 ) > .... *. 140 & 124 Wiedemann A. C. P. [2], 20,228 46,8 jj j .... Bi 2 Pb 3 a. 163-171 ill., 533 jj )> Bi 3 Pb .... 122-4 Person J., 1, 84 u .... Bi 4 Pb s. 200 & 125 Wiedemann A. C. P. [2], 20, 228 46,8 jj .... Bi 4 Pb 3 .... s. 129 .... lit, 533 j .... Bi 8 Pb s. 170 & 120, Wiedemann A. C. P. [2], 20, 228 46,8 also par- tially at 125-130 jj jj Bi 8 Pb, 125-3 Rudberg P. A., 71, 460 J., 1, 71 _ 6. Alloys of Bi and Sn .... BiSn s. 150 and 143 Eudberg P. A., 18, 240 v., 804 jj jj BiSn 2 s. 160 and 143 ) jj j) BiSn 4 s.190 and 143 jj si jj i) Bi 2 Sn s. 190 and 143 j> jj jj jj .... Bi s Sn 3 s. 143 jj I) !! .... 131-137 Dobereiner Kastn. Arch. 3, 90 v., 805 JJ JJ .... Bi 3 Sn,, .... 135-3 Person J., 1, 84 JJ JJ .... M .... s. 170 and US Rudberg P. A., 18, 240 v., 804 JJ JJ .... Bi 4 Sn 3 136-4 M J., 1,71; P. A., 71, 460 JJ 1) .... 1 pt. Bi + .... 199 Lewis .... v., 804 )) )! 8 pts. Sn J JJ . 1 pt. Bi + .... 166 .... jj !) JJ .... 2 pts. Sn J> >J 1 pt. Bi + .... 138 M .... jj JJ JJ 1 pt. Sn 7. .dZfoy o/ Cd and Sn CdSn 2 173-8 Rudberg P. A., 71, 460 v., 805 8. Jifoy of Cu and Sn CuSn abt. 400 Rieffel C. R, 37, 454 v., 805 9. Alloy of Cr and Pb .... 0-25 p.c. Cr .... 150 MM iii., 527 +9975 p.c. Pb 10. Alloys containing Hg Hg 2 Cd .... 75 Sromeyer .... iii., 886 (Amalgams) JJ Potassium amalgam, con- 27 p.c. K .... abt. 75 Merz and Weith B., 14, 1445 40, 881 jj jj taining 3-0 85-95 jj jj jj j 37 .... 160-170 jj jj )) H jj jj j) 47 175-184 jj j> )> U jj 6-5 .... 198-206 jj jj I) ) j) jj )> 9-8 (=H g2 K) 240-245 jj jj )) JJ jj jj i) 18-2 175-185 jj jj )) jj JJ JJ ..* D 24-6 .... 155-170 jj jj ) )) j> 26'0 153-160 jj jj )) >J )) >! ?> 29-8 147-152 jj jj )) jj )> Sodium amalgam, containing 3'0 p.c. Na . 152-160 jj jj JJ jj 7 J) )> 47 .... 305-315 jj jj JJ 1) 9-3 .... 276-299 jj jj )> JJ I) >l 127 .... - 190-209 jj jj )> j) 14-0 .... 170-190 jj *j J ) 1 )) 15-5 175-180 jj jj II JJ 458 METALLIC ALLOTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. 10. A lloys containing Hg Sodium amalgam, containing 24-8 p.c. Na ( = HgNa 3 ) 160-180 Merz and Weith B., 14, 1445 40, 881 (Amalgams) ) si 29-2 175-180 ? j )i j 34-0 168-175 M ji >j 37-9 152-159 ?> J> )) j HgSn a. 100 Regnault Ui., 890 n HgSn 2 a. 100 )) 11. Alloys of Pb and Sb .... These alloys usually melt .... De Jussien C. R, 88, 1321 36, 889 about 355 > ) ) 82 p.c. Pb + 260 Ledebur W. A. C. P. B., 5, 18 p.c. Sb 650 )) 90p.c.Pb + .... 240 )> 10 p.c. Sb 12. Alloys of Pb and Sn .... PbSn 182-2 Thomson J., 1, 1040 ? )j .... J) 235 Pillichody J., 14, 279 .... 241 Kupffer A.C.P. [2], 40, 285 iii., 534 >j .... PbSn 2 182-8 Thomson J., 1, 1040 ? i> )> 196 Kupffer A.C.P. [2], 40, 285 iii., 534 i> .... 11 197 Pillichody J., 14, 279 i PbSn, 181 ) )I ... 182-5 Eudberg J., 1, 71 51 .... ) 182-8 Thomson J., 1, 1040 1 )) .... T 182-8 Person J., 1, 84 j) n )> 186 Kupffer A.C.P.[2],40,285 iii., 534 ) ... PbSn 4 187 Pillichody J., 14, 279 .... )J 189 Kupffer A.C.P.[2],40,285 iii., 534 ... .... 190 Thomson J., 1, 1040 )> j> .... PbSn 5 194 Kupffer A.C.P.[2],40,285 iii., 534 5) .... Pb 2 Sn 270 Pillichody J., 14, 279 i )) .... Pb 2 Sn 3 210 n ? )> MM Pb,Sn 283 Tl ) .... )J 289 Kupffer A.C.P.[2],40,285 iii., 534 >i > .... Pb 3 Sn 2 246 Pillichody J., 14, 279 j) .... Pb 4 Sn 292 ) ?> * .... Pb 4 Sn 3 236 Pohl J., 3, 323 j .... Pb 5 Sn 7 184-5r.s.l81-9 IJ J., 3, 324 i ) .... 1 pt. Sn+25 558 Tomlinson .... iii., 535 pts. Pb .... 1 pt.Sn+10 .... 541 .... pts. Pb 11 )> .... 1 pt. Sn+5 .... 511 .... ! pts. Pb n 1 pt. Sn+3 .... 482 M .... pta. Pb j? .... 1 pt. Sn+2 .... 441 .... J> pts. Pb u i> .... 1 pt. Sn+1 .... 370 .... > pt. Pb .... lipts.Sn+1 .... 334 H 11 pt. Pb i n .... 2 pts. Sn+1 .... 340 >\ .... !J pt. Pb ) V .... 3 pts. Sn+1 .... 356 ij .... pt. Pb ) 4 pts. Sn+1 .... 365 >1 .... )1 pt. Pb ) " 5 pts. Sn + 1 .... 378 ) .... ) pt. Pb J) .... 6 pts. Sn+1 381 .... )l pt. Pb - METALLIC ALLOTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. 13. Alloys of Pb and Zn .... 167 p.c. Pb 205 Ledebur W.A.C.RB.,5, +83'3 p.c. 650 Zn it ..... 30-5 p.c. Pb 190 ? +69'5 p.c. Zn 50'0 p.c. Pb 202 )> +50-0 p.c. Zn 14. Alloys of SI) and Zn 10 p.c. Sb 236 Ledebur W.A.C.P.B.5., + 90p.c.Zn 650 Britannia metal 18 p.c. Sb 250 ji +82p.c.Zn 15. Alloys of Sn and Zn SnZn s. 320 & 204 Eudberg v., 1068 it SnjZn s. 280 & 204 ) i) Sn 3 Zn s. 250 & 204 H ? )) >! Sn 4 Zn s. 203 & 204 ) )) Sn 6 Zn s. 204 * Sn 12 Zn .... s. 210 & 204 J 16. A Hoys ofTland one oth er T1 3 A1 White heat Carstanjen J. p. C., 102, 65 vi., 1083 metal .... .... .... Tl 3 Bi s. 170 ;> !) Tl 2 Cd s. 184 )) )1 j) Tl 2 Cii White heat J> )) II !> Tl 2 Pb s. above 250 }} n 1 n Tl 2 Sn or Difficult J Tl 4 Sn 11 )l Tl 2 Zn .... s. above 360 J 9t M (B.) ALLOYS OF THREE METALS. 1. Alloys ofBi, Cd, and Pb Bi 4 CdPb 3 89-5 Hauer J., 18, 236 Bi s Cd 2 Pb 7 95 " 2. Alloy of Bi, Cd, and Tl 5pts.Bi + lpt. .... s. 134 Carstanjen J. p. C., 102, 65 vi., 1083 Cd+6pts.Tl 3. Alloys of Bi, Pb, and Sn Homberg's fusible metal BiPbSn 122 ill., 536 1) !! >> b. 100 Eose's fusible metal Bi 2 PbSn 93-75 i., 591 !> I) .... 95 ..-. ill., 536 Formed by pressure of ,, , 95 Spring B. B. [2], 39; 42, 921 7500 ats. B., 15, 596 Alloys of Pi, Pb, and Sn 11 95-98 Kopp A, 93, 129 ill., 75 and 78 Bi 2 PbSn s 145 Person J., 1, 73 ii Bi 3 PbSn .... 96 J., 1, 72 D'Arcet's fusible metal Bi.,Pb 2 Sn 2 95 Spring B. B. [2], 39 Krafft's fusible metal Bi 5 Pb 2 Sn 104 .... iii., 536 )! 11 ?' Lichtenberg's fusible metal Bi 5 Pb 3 Sn 2 91-60 i., 591 )) >1 Eose's fusible metal Bi 7 Pb 4 Sn 6 90 Spring A. C. P. [5], 7, 178 30, 592 I! Newton's fusible metal Bi 8 Pb 5 Sn 3 .... 94-44 .... .... iii., 536 11 11 " .... Bi 8 Pb 6 Sn 3 97-78 .... .... n o -i 44 METALLIC ALLOTS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Alloys of Pi, Pb, and Sn .... Bi s Pb 8 Sn 3 109-64 .... iii., 536 jj jj jj 1 Bi 8 Pb 8 Sn 4 112-20 JJ jj i) 1 Bi 8 Pb 8 Sn 6 116-05 .... JJ jj jj jj i Bi 8 Pb s Sn 8 112-10 JJ jj jj 1 Bi 8 Pb 10 Sn 8 127-60 MM JJ jj jj jj H Ifl Bi 8 Pb,,Sn s 130-90 .... )) j> jj jj tt> Bi 8 Pb 16 Sn 8 147-40 JJ )j jj jj S S " Bi s Pb 16 Sn 10 149-60 .... J> jj jj jj .j- Bi 8 Pb 16 Sn 12 141-90 .... JJ jj >j jj o" Bi 8 Pb 16 Sn 14 139-70 .... .... JJ JJ JJ JJ ra Bi 8 Pb 16 Sn 16 140-80 ft JJ JJ JJ l| Bi 8 Pb 16 Sn 18 144-10 JJ JJ JJ JJ 8 J Bi 8 Pb I6 S n20 147-4 JJ JJ JJ JJ 'i * BisPbjsSn^ 152-80 .... JJ JJ JJ JJ .2 Bi 8 Pb 16 Sn 24 154-00 .... JJ JJ JJ JJ s | Bi 8 Pb 18 Sn 24 152-90 .... JJ J> JJ JJ J Bi 3 Pb 20 Sn 24 151-90 JJ JJ JJ JJ l'l BisPb^Sn,, 151-80 .... J) JJ JJ JJ ^J Bi 8 Pb 24 Sn 24 152-90 .... JJ J) J> JJ 3 Bi 8 Pb 26 Sn,, 4 158-40 .... J) J) JJ JJ H g BisPb^Sn,, .... 163-00 .... .... >J ' J> JJ ll Bi 9 Pb 30 Sn 24 170-50 .... M JJ JJ JJ 1 "a Bi 8 Pb 32 Sn 24 176-00 Jj JJ JJ JJ {i; Bi 8 Pb 32 S n28 .... 165-00 .... jj JJ JJ JJ E5 Bi 8 Pb 32 Sn 30 .... 163-90 ..... jj JJ JJ JJ & '> Bi 8 Pb 32 Sn 32 158-40 .... jj JJ 1* JJ P -tT Bi 8 Pb 32 Sn 34 157-30 >J JJ JJ JJ J ' Bi 8 Pb 32 Sn 38 158-40 )j JJ JJ J ^ 60 fl Bi 8 Pb 32 Sn 38 159-50 JJ JJ JJ JJ fl* Bi 8 Pb 32 Sn 40 160-60 .... jj JJ JJ JJ D'Arcet's fusible metal Bi,,Pb 8 Sn 10 abt. 90 Spring A. C. P. [5], 7, 178 30, 592 JJ J .... 36-6 p.c. Bi 108 Hannay P. M. [5], 13, 234 +45 p.c.Pb + 18'3p.e.Sn JJ JJ JJ .... 50 p.c. Bi .... 94 P. M. [5], 13, 230 +25p.c.Pb +25p.c.Sn 4. Alloy of Si, Pb and Tl .... 6pts.Bi+6pts s. 130 Carstanjen J. p. C., 102, 65 vi., 1083 Pb+lpt.Tl 5. Alloy of Bi, Sn, and Tl .... .... 2pts.Bi+lpt. a. 115 !) jj Sn+lptTl Solidifying points. a. b. c. 6. Alloys ofPb, Sn y and Zn.... PbSn 6 Zn 168 171 204 Svanberg J. [1847-48], 72 iii., 538 jj jj jj PbSn 8 Zn .... 168 178 183 M JJ JJ jj jj .... Pb 2 Sn 9 Zn .... 168 j JJ JJ jj ji 168 Eudberg J., 1, 72 jj jj jj .... Pb 2 Sn n Zn 3 .... 168 182 Svanberg J. [1847-48], 72 iii., 538 u jj , Pb 2 Sn, 2 Zn 168 - 178 ii jj jj .... Pb 3 Sn 12 Zn 168 172 > jj jj jj .... Pb 4 Sn, 8 Zn 168 172 178 j )! jj jj jj .... Pb 6 Sn 21 Zn 168 175 jj Pb 10 Sn 33 Zn 168 178 ) > j> METALLIC ALLOTS. (c.) ALLOYS OF FOUK METALS. Name. Remarks. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. 1. Alloys ofBi, Cd, Pb, and Sn .... BijCdPbSn .... 68-5 Hauer J., 18, 236 BijCdPb.jSn.j 68-5 n 11 Wood's fusible metal Bi 4 Cd 2 PbSn 2 .... 80 Spring A. C. P. [5], 7, 178 30, 593 ,, Bi s Cd 3 Pb 4 Sn 4 67-5 Hauer J., 18, 236 .... Bi, Cd 4 Pb 6 Su s .... 65-5 M .. ). Lipowitz's alloy Bi 1I Cd 4 Pb 6 Sn, abt. 70 Spring A. C. P. [5], 7, 178 30, 593 ,. ,, .. 15 pts. Bi + .... 60-65-5 Hauer J. [1860], 684; 3 pta. Cd [1862], 113 + 8pts.Pb + 4 pts. Sn i) Wood's fusible metal 4 Bi + 1 Cd .... 60-5 Roscoe and Schor- T. C., 2, 334 + 2Pb + lemmer 1 Sn >. 1) 4 Bi + 1 Cd .... 65 Spring B., 15, 596 42,921 + 2Pb + ISn Formed by pressure of ii i) 4 Bi + 1 Cd 70 I) 7500 ats. + 2Pb + 1 Sn Alloys of Bi, Cd, Pb, and Si 4 Bi + 1 Cd .... 65-5-70 Hauer J. [1860], 684; + 2Pb + [1862], 113 1 Sn .. 7 or 8 Bi + 66-71 Wood .... ill., 75 lor2Cd + 4 Pb + 2 Sn 1! )) 55 (?) .... 75 Nencki and Giacosa J. p. C. [2], 20, 34 36, 1046 ,. 16Bi + 2Cd 76-5 Hauer J., 18, 236 + HPb + 3Sn 2. Alloy of Bi,Hg, Pb,andS> D'Arcet's alloy +Hg, Bi 8 Hg, Pb 5 45 iii., 537 Sn 3 46 VII. ALLOYS OF COMPOUNDS. (A.) ALLOYS OF TWO COMPOUNDS. Composition. Remarks. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. AgI+Cu 2 L, 514 Carnelley & O'Shea 45, 410 2AgI+Cu 2 I 2 496 SAgl+CujIj 494 4AgI+Cu 2 I 2 493 ISAgl+CujIj 514 Agl+PbL, 350 AgBr+AgNO, ' s. 182 Schnauss & Kremers J. [1855], 419 iv., 104 Agl+AgNO, 94 J. [1855], 429 iv., 105 AgI+2AgNO 3 105 iv., 165 AgNO 3 +KNO 3 s. 169-121 Maumene C. R., 97, 45 46,3 AgNO 3 +l-68KNO 3 s. 191-131 AgNO 3 +NaNO 3 s. 251-5 AgNO 3 +2NaNO 3 s. 263 Ba(NO 3 ) 2 +2NaNO 3 s. 322-288 C. R., 97, 1215 46, 384 Ca(NO 3 ).,+2NaNO 3 s. 235-216 C. R,, 97, 45 46, 3 100 p.c. KNO 3 + p.c. NaNO 3 90 +10 80 +20 70 +30 60 +40 54-3 +457 SO +50 40 +60 30 +70 20 +80 10 +90 +100 KNO 3 +2NaNO 3 =(KN0 3 +NaN0 3 ) .... s. 338-3 s. 311 s. 280 s. 250 s.230 s. 225-6 s. 229 s. 244 s.262 s. 281 s. 298 s.313 s. 242-224 Schaffgotsch j >i ji j> Maumen6 P. A., 102 J )I n > n > >j ?j 5) )J C. R., 97, 45 46,3 KNO 3 +3NaNO 3 s. 267-237 2KNO 3 +NaNO 3 s. 265-244 3KNO 3 +NaNO 3 s. 265-247 KNO 3 +NH 4 NO 3 . . . s. 230 C. R., 97, 1215 46, 385 53-14 p.c. KNO 3 +46-86Pb(NO 3 ) 2 2NaNO,+Pb(NO 3 ) 2 (or else equal weights) * 207 s. 282 Guthrie Maumen6 P. M. [5], 18, 112 C. R., 97, 1215 46, 384 (B.) ALLOYS OF THREE COMPOUNDS. AgCl+AgBr+AgI 295 Rodwell P. R. S. 331 Carnelley & O'Shea 45, 410 AgCl+AgBr+2AgI 320 Rodwell P. R. S. 826 Carnelley & O'Shea 45, 410 AgCl+AgBr+3AgI 330 Rodwell P. R. S. 35U Carnelley & O'Shea 45, 410 AgCl+AgBr+4AgI 350 Rodwell P. R. S. 380 Carnelley & O'Shea 45, 410 2AgCl + 2AgBr+AgI 330 383 Rodwell Carnelley & O'Shea P. R. S. 45, 410 AgN0 3 +KN0 3 +NaN0 3 NH 4 NO.,+KNO 3 +NaNO 3 .... s. 190-130 136-137 Maumenfi C. R., 97, 45 C. R., 97, 1215 46, 3 46, 384 2KNO 3 +2NaNO 3 +Pb(NO 3 ) 2 (or equal weights ?) .... s. 259 )J 5) PART II. OKGANIC COMPOUNDS. 48 I. COMPOUNDS CONTAINING TWO ELEMENTS. (1.) CH. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Kxcnlite (CH) 108 Trommsdorff A., 21, 126 iii., 448 114 P A., 43 141 Polystyrol 117 Engler and Leist B., 6, 256 26, 901 Rose oil (CH,) (272 275) 32 '5 Fluckiger Z. C. [21 6, 126 vi., 999 Keichenbach's paraffin Scheelerite . .. .... J) /CTL} (?) 280-300 a. 300 abt 100 35 43-44 44-45 85-86 44 Hell and Hermanns Hell Dana A., 7, 155 B., 13, 1716 B., 13, 1710 J. [1847-48], 736 Mineralogy 40, 250 40, 249 v., 204 Acetylene rrr ' f^tr Cond at 18 Cailletet C. E., 85, 851 34, 20 Ethylene (olefiant gas) Etherin CH, : CH 2 C 2 H 4 (83 ate.) 102 to 103 (760) 105 (760) 102 (760) Cond. at 10 (63 ate.) Cond. at 8 (56 ate.) Cond. at 4 (50 ate.) Cond. at 1 (45 ate.) 13 c.t. 260 . b. 110 110 Faraday Wroblewski and Olszewski Olszewski Cailletet C. E., 96, 1140 M. C., 5, 127 C. E., 94, 1224 H 44, 781 46, 816 42, 914 JJ ii., 507 Etherol 280 b. 35 Serullas A.C.P. [2], 39, 178 Paraffin from Boghead coal Idrialite i) Trimethylene . CH 2 .CH 2 .CH 2 (C 3 H 2 ) n CH Gas 80 86 100 Galletly Boedeker C. N., 24, 187 A., 52, 100 J. p. C. [2], 26, 367 24, 1183 iii., 242 Propylene .... .... .... 18 vi., 710 CH 2 :CH.Me. iso- 143 (ric) .... Eeboul C. E., 78, 1773 27, 977 v., 892 Propane 140 25 to 30 Lefebvre J., 21, 329 3 3 Cond 17 A. 150, 209 Crotonylene .... CH 3 .CH:c:cH C.H, 18 Caventou A., 127, 347 ii., 965 18 Butlerow C. C. [1871], 89 24,215 Ethylacetylene Divinyl CH : C.Et 18 abt 20 Pfankuch B., 8, 412 J. P.O. [2], 6, 113 vii.,656 ; 26,363 Caoutchene .... .... .... 233-3 14'5 10 Bouchardat A., 27, 33 i., 736 Butylene 4 8 Cond 40 Puchot C. E., 85, 757 34,20 b Faraday P. T. [1825], 440 v., 738 5 Wurtz A., 152, 21 vi., 377 / Puchot A. C. P. [5], 28, 507 46, 167 CH 3 .CH : CH.CH, 3 Crystallizes De Luyeres v., 738; vi., 710 12-14 b. 18 Chapman J., 20, 581 Isobutylene .... Me n C : CH, 6 Butlerow Z. C. [2], 6, 238 vii., 223 7 to 8 8 (752) : vi., 376 Methylallyl Me.(CH),Me or 15-18 (2 to 2J ate.) 4 to | 8 Wurtz B. S. C. [2], 8, 265 CH 2 \ >CH.Me CH,/ COMPOUNDS CONTAINING TWO ELEMENTS. 49 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Me.(CHo)2Me. C,H lft 1 P K S 16 367 04 QQC\ . ;; *" *" " 5J I 3 (2J ats ) Goldstein B., 12, 690 G H 109 891 36, 766 abt J 16 524 miftl abt j 21 329 1 18 54 v 7^ 5-10 A C P [4] 1 5 Et.Et. 23 ii ^94. (CH 3 ) 2 .CH.CH 3 17 A 144 10 Carbopetrocene Valylene i) .... (?) ,, (?) (C 5 H 2 ) B ! or (C 6 H 2 ) n C 5 H 6 10 45-50 abt. 50 60 200-238 Konovaloff Prunier Reboul j> B. S. C. [2], 34, 33 A. C. P. [5], 17, 5 A., 135, 372 J., 18, 510 B 15 1024 40,400 36, 1027 v., 982 42 983 (ft C H or 119 B 6 255 26 901 CH 2 : CMe.CH : CH 2 C 10 H 12 C H 35 Tilden C N 46 120 44 7 r ^5 XA 8 37 45 413 37-38 P R S 10 516 iii 433 Propylacetylene Isopropylacetylene CPr;CH CPr/ OH )J 48-49 28-29 (751) abt. 35 Liquid Liquid Bruylants Flawitzky&Kriloff B. S. C., 24, 112 B., 8, 411 B., 11, 1939 B 7 760 C. R., 72, 1192 36, 134 27 975 35 Eltekoff B 10 707 Methylethylacetylene Valerylen6 .... .... .... Et.C. i C.Me CMe, I C : CH, 51 44-46 (745) H. Eltekoff Reboul B. S. C. [2], 39, 210 A 131 238 J 34, 563 v., 982 41-42 Buff 17, 506 abt 50 Friedel A C [4] 16 366 vli. 1022 43-47 Bruhl A 200 139 38, 296 45 50 C R 90 1560 38 710 34 Flawitzky & Kriloff B S C [2] 27 347 34, 20 Piperylene CMe 2 : C : CH 2 (?) 28-30 42 Liquid u B 14 665 40, 621 Pentine (from resin spirit) .... (?) (from oil of eri- geron canadense) (?) Oil of poplar buds 1 (WX I) C 5 H 8 (C-H.) 50 103-104 (?) 175-177 245-247 260-261 c. abt. 350 45 Couerbe Tilden Vigier and Cloez Tilden Piccard J. p. C., 18, 165 B., 13, 1605 J. Pharm. [5], 4, 333 B., 13, 1605 B., 6, 890 A 41 39 41, 168 42, 64 26, 1237 v., 707 Propy lethy lene PrCH:CH 2 (?) C 5 H 10 39-40 42 Schorlemmer Kekul6 P. T. [1872], 111 A 179 340 25, 1085 29, 546 35-37 Zeidler A 197 253 36, 908 32-39 Wurtz A 123 202 vi., 117 Isopropy lethy lene PrP.CH : CH 2 i 20-2 (749) 25 Flawitzky B., 11, 992 B 6 562 and 36,37 26, 1013 and 25 1254; A., 179, 340; A., 169, 205 B 8 767 27, 241 ; 29, 545 ; 27, 139 29, 894 S1-1-S1-3 A., 190, 328 ; 32, 420 21-5 Flawitzky B., 10, 406 ; J.R.C.S.,9,198 C. R., 86, 973 34, 717 34 Buff A., 4th Spl., 143 vi., 117 35-38 Etard C. R., 86, 448 34, 393 Ethylmethylethylene M Et.CH : CH.Me 1) )i n 36 (740) 36 G. Wagner and A. Saytzeff Fittig A., 175, 373 A., 200, 30 28, 628 28, 376 50 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylmethylethylene jj Trimethylethylene CMeEt : CH 2 j> Me 2 C : CHMe QjH 10 H Sl-22 25 abt. 33 35 A. Wischnegradsky Wischnegradsky Zeidler Ermolaien A., 190, 354 C. C. [1876], 595 A., 186, 245 Z. A. [2], 7, 275 34, 394 32, 286 32, 421 vii., 64 ; v .. 1) 36 35 Wischnegradsky Flawitzky A., 190, 365 ; C. R., 86, 973 A., 169, 206 24, 1036 34, 394 and 717 27, 139 )> .... .... ... J> 5) 35 35-37 )> Perkin A., 179, 340 45, 448 29, 545 36 (749-7) Flawitzky A., 179, 340 29, 546 Amylene 22-23 Zeidler A., 186, 245 32, 421 39 Balard A. C. P. [3], 12, 321 i., 208 30-35-5 Buff A.,4thSupp.,129 35 Bauer J., 14, 660 vi., 710 j * .... )j 28-30 39-40 Buff Schorlemmer J. 21, 334 A., 148, 349 vii., 63 35 W. Ramsay 35, 469 35, 469 30-40 LeBel C. R., 75, 267 25, 886 35-40 Renard A. C. P. [6], 1,223 46, 843 34-5-35-6 Z., 4, 229 38 u. c. Glaus &Rautenberg B., 14, 623 38, 201 c. t. Pawlewski B., 16, 2633 46, 252 Identical 35 Flawitzky B., 6, 562 ; A., 26, 1014; 29, 35 Frankland 179, 340 A., 4thSupp.,129 546 3, 31 ; 29, 546 35 Mendeljeff A., 179, 340 29, 546 jj ...* .... .... Mixture ? I) 42 35 ' Kekul6 O. and F. Zeidler A.,4thSupp.,129 A., 197, 243 i., 208 36, 908 35 (744) Briihl A., 200, 139 38, 296 28-37 Hartley 39, 154 35-37 A., 165, 7 (?) . (C=H,J n 230 A. Staw C. R., 86, 488 34, 393 (?) . 300 (?) 350 Pentane CH 3 .(CH 2 ) 3 .CH 3 39 Goldstein J. R. C. S., 1882, 42, 374 36, j> 37-39 37 Schorlemmer Lachowicz 45 ; B., 12, 690 P. R. S., 16, 367 , P. T. [1872], 111 A., 220, 188 766 vii., 63, 891; 24, 896, 1026 46, 166 35-37 u. c. Thorpe and Young B., 5, 558 vii., 892 35 Hofmann B., 16, 590 36-36-5 Perkin 45, 445 39-40 Schorlemmer 15, 421 iii., 181 From colophony 35-38 Renard A. C. P. [6], 1,223 46, 843 33-38 C. R., 95, 1386 44, 599 34 Schorlemmer P. R. S., 15, 131 vi., 107 32-35 Cahours& Demar^ay C. R., 80, 1569 Isopentane (Me) 2 .CH.CH !! .Me 29-32 c. Perkin 45, 445 30 A., 74, 55 i., 204 30-5 Goldstein J.R.C.S.[1882],45 42, 374 30 Beilstein and .Kur- B., 14, 1620 28-30 batow Wurtz iii., 181 30 Pelouze & Cahours J., 16, 527 vi., 115; iii., 181 30 Schorlemmer P. R. S., 16 vi., 709 30 Lachowicz A., 220, 188 46, 166 M 30 (7 3 A) Frankland 3, 31 26, 679 ,, .... .... )> 30 31, 194-8 c t Just Pawlewski A., 220, 146 B., 16, 2633 46, 169 46, 252 j) .... .... .... 5J )> 1. -21 G. H., 110 COMPOUNDS CONTAINING TWO ELEMENTS. 51 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Tetramethylmethane (impure 2) Eupione Carbopetrocene (?) Benzene CMe 4 C.(Me) 4 H C HC CH II 1 HC CH CsHjj 1) J) 1) (C 6 H 2 ) n or (C S H 2 ) B (C 6 H 4 ) n C 6 H 6 9-5 9 47 91 80 80'Ji (760) s. 20 1. 30 b. 20 200-238 5-5 Lwow i Ladenburg Reichenbach & Hesse Prunier Church Kopp Z. C., 13, 521; Z. C., 14, 257 Z. C., 14, 257 A., 164, 300 A., 13, 217 ; A., 23, 247 A. C. P. [5], 175 14,76 P. A., 72 ; 1, or vii., 63, 1037 24, 1026 26, 50 U., 608 36, 1027 iv., 415 i., 542 iv., 2 V H 80 W. Ramsay 223 35, 469 39, 64 80 Pictet P M [5] 1 484 32 163 81 P. Jannasch A., 176, 283 28, 889 79-5 (747 r ) Naumann B , 10 1422 34 4g 79-3 (739) Briihl A., 200, 139 38, 296 80'5 Hartley 39, 162 81 Berthelot and Ogier C. R, 91, 781 40, 719 " 80-81 Mansfield J., 1, 711 82 s 3 Freund A 120 81 80 '8 Church P.M. [4], 11,256 80'1 Warren P.M.[4],13,415 J., 17, 531 ; P. M. [4], 18, 522 J., 18, 515 ,, .... .... .... 80-5 80-36 (760) 3 4'45 Jungfleisch Re^nault C. R., 64, 911 G. J. C. [1863] ; s Ladenburrr M. A. S., 26, 658 G. J. C., 1871 80 (764) SchifF G. J. C., 1881 79-2 Schall B., 16, 3012 46, 551 78-8 c B 15 2893 44 315 80 Dumreicher B., 15, 33 42, 606 82 TTftiiry B., 6, 957 86 5-5 P T , 1825, 440 86 7 Mi tscherl i ch A., 9, 43 280'6 c t W A. C P. B 45 138 2917 c t [1879], 741 45, 138 CH i C.(CHo) 2 C : CH B 6 957 vii. 1008 82 86 u c J P C [2] 8 54 26, 1215 27 351 85 c. 85 B 5 456 vii., 49- 25, 687 j .... .... (polymer) ,1 (:>! 234-4 c. t. II -2 52 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diallyl CH 2 ' CH (CH 2 ) 2 CH : CH 2 PTT 59 Oppenheim B., 4, 672 58-59'5 Buff A. 4th Supl., 145 vi., 92 58-60 Wagner & Tollens B., 6, 590 vii.,46;26,1122 58-60 Henry B., 6, 956 59-3 Briihl A., 200, 139 38, 296 58-59'5 Zander A., 214, 148 Hexoylene 76-80 Eeboul & Truchot A., 144, 247 ; J., 80-85 20, 587 A., 135, 127 Hexine (from benzene) .... abt. 80 80 .... Michael Saytzeff A., 139, 251 A., 185, 157 vi., 697 32, 299 (from mannite) Hartite Me.C ! C.Pr" j> 80-83 1. at 20 74 Hecht Kumpf B., 11, 1050 J. P. C., 107, 189 34, 717 vii., 594 74 Haidinger P. A., 54, 261 iii., 14 Hexylene (butylethylene) .... j ) (methylpropylethy- lene) j > j ?) (dimethylethyl- ethylene) Me.(CH 2 ) 3 CH : CH 2 Me.CH:CHPr" I) )) (Me) s C : C.H.Et C' 8 H 15 ) > J JJ 60-70 71 68-70 67 (739-5) 67-8-68(760) 68-70 68-70 68-70 68-70 65-67 64-66 Schorlemmer Williams T. M. Morgan Hecht and Strauss Hecht Wanklyn and Erlenmeyer Carius Pelouze & Cahours Jawein Warren and Storer P. T. [1872], 111 P. T. [1857], 737; A., 108, 385 28, 301 A., 172, 64 B., 11, 1152 J., 16, 52 A., 131, 323 J., 16, 526 B.S.C.[2],30,26 A., 195, 253 J., 21, 331 vii.,645; 25,1085 iii., 147 27, 782 iii., 147 vi., 699 )1 vi., 710 34, 961 (dimethylethyl- ethylene) ?i (tetramethylethylene) 5) )* ) 5> 5) )) M )> Me.CH : C.Me.Et (Et) 2 C:CH 2 orMe.CH:CMeEt Mej-CIC-Me,, ) J (?) (?) (?) ) 69-71 68-72 73 72-73 73 73 60-70 70 72-74 65 66 Jawein Tschaikowsky Bizza (?) A. Pawlow Eltekoff Friedel Friedel and Silva Kaschirsky Heeht B. S.C.,27,30,26 B., 5, 330 J.E.C.S.[1882],99 (?) B., 11, 513 J. E. C. S. [1882], 355; B., 16, 398 Z. C. [2], 5, 485 C. E., 76, 226 B., 11,984; C. C. [1881], 278 A., 165, 146 25, 1087 42, 491 34, 562 44, 567 vi., 946 vii.,982;26,489 36, 46 ; 42, 37 )> 65-66 60-70 Wurtz vi., 699 69'5 71 A., 195, 259 68-70 Wurtz J. [1864], 572 68 71 Geibel and Buff J., 21, 336 ) 67 70 E6nard A. C. P. [6], 1,223 46, 843 67 68 Lieben A., 178, 1 29, 60 Dipropylene .. JJ 70-80 Pmnier C. E., 76, 98; vii., 1016 ; Hexylidine Me (CH ) CH 68 71 A., 145, 72 26, 487 vi., 699 Hexahydrobeiizene From Caucasian petroleum ... Hexylene (condensed) )> Hexane (dipropyl) from various sources ?> )> Me.(CH 2 ) 4 .Me Jl 5 J> )> )) (C 6 H 12 ) i C 8 H 14 ) 69 210-215 193-197 196-199 69-70 69-5 69-70 71-5 Wredeii Beilstein and Kur- batow Jawein j> Schorlemmer )i n A., 187, 163 B., 13 [1820] B. S.C.,27,30,26 P. E. S., 16, 367 , j) 32, 445 40, 159 34, 961 )) vii., 891 ; 24, 896 5J COMPOUNDS CONTAINING TWO ELEMENTS. 53 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Hexane (dipropyl) Me.(CH 2 ) 4 .Me C 6 H 14 70-6 Goldstein J.E.C.S.[1882],45 42, 374 M 69-70 Schorlemmer P. T. [1872], 111 vii., 645 ; 25, 1085 ,, ,) 71-5 n 68-3 Bruhl A., 200, 139 38,296 n 68-70 c. Perkin 45,445 a 68-70 T. M. Morgan 28, 301 ,, .. 68-3-71 Zander A., 214, 165 M JJ 69-71 Schorlemmer A., 161, 275 yy J, .... .... n 68-70 Cahours & Demarc,ay C. E., 80, 1570 , 68, 250-3 c.t. Pawlewski B., 16, 2634 46, 252 i> i) 69-5 Dale J., 17, 381 ,, ,, .... .... 68 Williams J., 10, 418 iii., 153 ,, .. 70 Lachowicz A., 220, 188 46, 166 ,, ,, 67-68 .... Thorpe and Young B., 5, 556 vii., 892 ; 25, 803, 982 Chiefly 70 .... Linnemann W. A. [2 Ab.], 63, 255 ,, n 69 .... Berthelot C. E., 85, 831 34, 48 i) 68 Bouchardat C. E., 76, 809 iii., 153 1, n 68-5-70 .... Wanklyn & Erlen- J., 16, 521 meyer M 68 Pelouze & Cahours J., 15, 410 iii., 181 n 68-5 Warren and Storer J., 21, 331 68-70 Schorlemmer J., 15,386; 15,422 iii., 181 Isohexane (propylisopropyl) CHMe 2 .CH 2 .CH 2 .Me 62 Wurtz A. C. P. [3], 44, 275 ii., 525 H 62 .... Schorlemmer P. E. S., 16 vi., 709 5) n 59-62 Perkin 45, 445 i. 62 Goldstein J. E. C. S. [1882], 42,374 45 (diethylmethyl- CHMeEtj 64 Liquid Wislicenus A., 219, 307 methane) ! 60 .... .... B. S. C., 25, 546 .... 64-66 Eenard A.C.P. [6], 1,223 46, 843 60-64 Wurtz J., 16, 509 iii., 181 61'3 \Varren J., 21, 3,'iO n 60 "8 Rams civ 35, 469 w 60 Lachowicz A., 220, 188 46, 166 (diisopropyl) Me.j.CH.CHMe s 58 Schorlemmer P. E. S., 16, 35 v.,887; vi., 709 ,1 58 Zander A., 214, 167 ,1 !) n 59 Liquid Bouchardat C. E., 76, 809 25, 410 ; vii., 646 Hexane (trimethylethyl- (Me) 3 C.Et 43-48 Liquid Butlerow&Gerainow A., 165, 107 ;B. a vii., 1183; 25, methane) C. [2], 18, 124 1092 n 43-48 Liquid Gerainow B., 5, 479 26, 43 48-52 y- J., 17, 531 i., 573 114 v/DTu'dl Gerhard t A. C. P. [3], 14, 111 i., 573 ; iv., 2 " 11 1,320'S c.t. Pawlewski B., 16, 2634 46, 252 " C"H Ill Xollens and Fittiff A., 131, 304 iv., 486 7 110-3 c. "Warren J. [1865], 525 v., 852 " >: Ill vi., 278 111 Eenard A.C.P. [6],1, 223 46, 843 " M u 110-112 W. Tt. Hoilffkinson 33. 497 and 499 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Toluene C 6 H 5 .Me. )J JJ )J J> )> 5J J) ?> )> ) )? )} > )1 From diallylcarbinolchloride Me 2 .C:C:C.Me 2 CHMe:C:CH.C 3 H 7 Me.(CH 2 ) 4 .C:CH From colophony From resin spirit CMe 3 .CMe : CH 2 Me 2 .CH.CH : CMe 2 or Me 2 .CH 2 .CMe : CH 2 From Me 2 .C.Et 2 From methylethyl propyl- carbinol CMe 2 : CMeEt ) C 7 H 8 ) )> )> J) I >* n )j > )) (C 7 H 8 ).. )> C 7 H 10 C 7 H 12 ) > ;j (C 7 H 12 ) n C 7 H, 4 i) j j i) jj j) j) Ill 110-112 111 108-5 (749-5 r. 110-112 110-112 110-110-1 111 110-9-111-2 u. c. 111-112 108 110-5 111 110 109-2 1037c. (760) 110 106 119-5 108 113 114-115 215-220 280-285 115 105-108 70 103-104 106-108 115-125 103-105 ; 103-106 200-250 70-80 78-80 80 80-85 80-85 80-85 81-83 83-84 91 90-92 90-91 90-95 92-95 (755) 75-80 90-100 Liquid Liquid Liquid in freezing mixture W. Ramsay Tommasi P. Jannasch Naumann G. Ciamician Perkin&Hodgkinson Briihl Ramsay Brown Botsch Deville Noad Wilbrand & Beilstein Schiff Church Wilson Glenard & Bondault Church Pelletier & Walter Ladenburg Merling Ekstrand Schwarz Saytzeff Baeyer Henry Tilden Rubien and Henry Funaro R6nard Tawildarow Anderson Eltekoff Butlerow Kaschirsky Markownikow Pawlow Grimshaw . Schorlemmer D. Pawlow Kaschirsky Pawlow Schiff 27, 313 A., 176, 283 B., 10, 1425 B., 11, 270 37, 725 and 727 A., 200, 139 39, 64 39,211 M. C., 1, 609 J. F. P., 44, 145 A., 128, 257 G. J. C., 1863 G. J. C., 1881 P. M. [4], 9, 257 P. M. [4], 9, 258 J) J., 17, 531 A. C. P. [2], 67, 267 B., 14, 230, 2128 and 2403 B., 15, 289 A., 185, 104 B., 14, 1530 A., 185, 144 A., 155, 271 B., 8, 400 B., 13, 1604 A., 142, 294 ; B., 8, 409 G. J. [1881], 274 AC. P. [6], 1,223; C. R., 91, 419 ; B.S.C.[2],36,215 B., 9, 1442 C. N., 20, 76 A., 180, 245 ; J.R.C.S.[1882], 355 A, 167, 176 C. C. [1881], 278 B. J., 21, 470 A., 25, 284 B. S. C., 5, 307 Z. C. [2], 7, 263 B., 7, 729 A., 166, 167 26, 320 26, 323 A., 187, 104 ; B., 9, 1311 B., 11, 984; C. C. [1881], 278 B.,9,1311; A.,190, 314; 187, 194 Z. C., 6, 75 35, 469 28, 889 34, 48 34, 439 38, 296 42, 210 and 211 41, 167 A., 216, 338 A.,217,117&133 32, 499 32,298 vii., 656 41, 174 vi., 696 40, 1032 46, 843; 42, 04; 38, 893 41, 173 44, 567; B., 1 399 28, 1249 42,37 24, 1028 27, 1076 26, 313 vii., 643 32, 732 ; 31, 58 36, 46 ; 42, 37 31, 58 ; 32, 732 ; 42, 37 vii., 869 Paratoluene .... Retinaphtha .... Tropilidene Action of baryta on dioxy- retistene .... (?) Heptone Toluene dihydride Tetramethylallylene Methylpropylallylene CEnanthylidene Heptylidene .... . . Toluene tetrahydricle (?) Heptylene (methylbutyl- ethyleue) ? ,, (trimethylethyl- ethylene) ') )! COMPOUNDS CONTAINING TWO ELEMENTS. 55 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Heptylene C 7 H, 4 94-97 A., 165, 11 ,, .... .... 11 95 Schorlemmer 16, 219 iii., 147 j, .... .... t. 11 95-100 11 15, 424 ! " *" * From Me 2 CH(CH a ) 3 Me 11 94 11 P. E. S., 14 vi., 696 )> 11 94-1 Warren and Storer J., 21, 331 .... (normal ?) From azelaic acid 11 96 Schorlemmer P. R. S., 14 vi., 696 u j) petroleum 11 96 11 )> 11 98 11 A., 166, 177 11 99 Williams J., 11, 438 iii., 147 CH 3 .(CH 2 ) 4 .CH : CH 2 n 93-95 Schorlemmer A., 136, 267 ,, .... .... J) 11 95-97 11 >J j .... .... ... 1) 11 98-49 n A., 166, 176 26, 322 (methylbutyl- C 4 H 9 .CH : CHMe 11 98-5 Schorlemmer and A., 217, 149 44, 652 ethylene) Thorpe 107 ]\J[endelieff J. R. C. S. [1882], 42, 919 11 230 Toluenehexhydride .... 11 94-100 Wreden A., 187, 161 32, 445 ,, 11 94-100 11 B., 8, 769 20,914 ,. ,, .... 11 95-100 Jeilstein&Kurbatow B., 13, 1818 40, 15.9 11 ,, From colophony 11 95-98 B6nard A. C. P. [6], 1,223 46, 843 ; 42, C. R., 95, 245 1301 Heptane (normal) Me.(CH 2 ) 5 Me C 7 H 16 98-99 Schorlemmer P. R. S., 16, 367 24, 896 ,- )> 11 100-5 .... 11 )> vi., 696 ; 21, 896 11 98-65 Goldstein J.R.C.S.[1882],45 42,374 ,j ,, ) 11 98'4 c. .... Perkin 45, 447 j, ) 11 97-99 .... Thorpe and Young A., 165, 13 ; B. 5, vii., 892 ; 25, 556 803 ,, J) 11 97-5-98 Schorlemmer P. T. [1872], 111 vii., 642 ; 25, 1086 ,, ,, i 11 92-94 Pelouze & Cahours C. R., 56, 505 ; 25, 1086 ; iii., A., 127, 196 147 11 11 .... .... ) 11 98 Schorlemmer 26, 322 j> 11 96-99 .... J. M. Morgan 28, 303 ,, ,, .... .... ?i 11 98 Schorlemmer 16, 216 iii., 147 )* 11 98 Warren J. [1865], 516 vi., 696 11 11 " ' i 11 97-8 Warren and Storer Z. C. [2 4, 231 11 (from Pinus Sa- n 11 98-4 (760) Thorpe and Riicker 45, 166 biniana) 281 c. t. 11 11 n 11 98-4 c. (760) T. E. Thorpe 35, 298 11 11 H 11 98-3 c. (755) ?) )> 11 11 j? 11 97-9 c. (747) 11 ) 11 11 11 11 281 c. t. .... 11 35, 308 11 11 11 11 98-42 c. Thorpe 37, 214 (755-6 r.) 1 1> 11 11 98-43 c. 11 (746-9 r.) (from petroleum) 11 11 98-1-99-1 c. 11 35, 308 (765) ii 11 n 11 98-1-98-6 c. .... 11 11 (750) 11 " 11 11 90 .... 11 11 11 11 11 90-92 .... Schorlemmer A., 136, 257 Heptane (from azelaic acid) .... 11 98-99 Dale 17, 261 38, 30 !> 11 11 91 W. Ramsay 35, 469 11 11 .... 11 96-98 Cahours and De- C. R., 80, 1570 margay !> ') 11 99 jachowicz A., 220, 188 46, 166 '1 .... 11 99 Schorlemmer P. R. S., 16, 367 vii., 891 11 11 11 99 Mendeljeff J. R. C. S. [1882] 42,919 230 56 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Heptane (from azelaic acid) C 7 H 16 95-100 -... Amato G. I., 2, 6 25, 682 From light rosin oil 95-97 Tilden B., 13, 1604 40, 101 (triethylmethane) CHEt, ?) 95-98 Ladenburg B., 5, 752 ; A., vii., 1182 ; 26, 164,300; B. S. 48&50 C., 18, 548 (methylethyl- CHMe.Et.Pr a 91 .... Just A., 220, 146 46, 169 propylmethane) 91-93 .... Berthelot J. [1867], 346, vi., 696 350 90-92 Warren J. [1865], 516 > " .... .... j 90 Schorlemmer P. E. S., 16 > .... 89-91 A., 136, 257 ,, 90-4 Warren 26, 320 a. Isoheptane (ethylamyl) .... Et.CH 2 .CH 2 .CHMe. 2 88 Schorlemmer 16, 428 IT JJ J J) j> 88 Wurtz A. C. P. [3], 44, ii., 525 .... 275 Jt JJ JJ j) 91 .... Schorlemmer P. E. S., 16 vi., 696 & 709 > 71 j; j 88 Wurtz A. C. P. [3], 54, 26, 309 278 5) JJ jj 90 Grimshaw 26, 311 vii., 642 J> JT j> > 90-3 (762-3) Thorpe, T. 37, 216 J JJ JT j) 89-5 (745) .... Purdie 39, 468 t> >J JJ >j 90 Goldstein J. E. C. S. [1882], 42, 374 45 ) ) TJ )> 90-91 .... Schorlemmer A., 136, 257 Heptane (dimethyldiethyl- CMesEta 86-87 Friedel and Laden- A., 142, 310, 318 vi., 398 & 826 methane) burg > 86 Schorlemmer P. E. S., 16 vi., 709 j> )j 89-5-90 H A., 166, 172 vii.,643;26,322 C 6 H 13 .Me 82 .... Wurtz J., 8, 576 i., 97 )> j 85 .... j A. C. P. [3], 44, iii., 1008 275 Phenylacetylene C 6 H 6 .CiCH C 8 H 6 1S9-UO Liquid Glaser A., 154, 156 ; vi., 5 Z. C., 5, 97 ,, ? )) 141-6 .... Weger A., 221, 61 46, 11 ,, J> JJ 140 Piadziszewsky B., 6, 493 26, 1029 Styrolene or cinnamene Ogilg.Oii . t-'Jin C 8 H 9 145 1. 20 E. Kopp Compt.Ch.[1846], i., 981 (phenylethylene) 87 ; C. E., 53, 634 ?T )> j 145-75 Blyth & Hofmann A., 53, 293 JJ JJ l ii )J 146-2 Weger A., 221, 61 46, 11 JT JJ ... JJ 144-150 Emmerling and B., 4, 147 vii., 1101 Engler II >J .... JJ 144-145 Fittig and Binder G. J. C. [1879] JJ .... JJ 144-5 .... Perkin 32, 673 U JJ .... JJ 140 Scharling A., 97, 186 n JJ .... JJ 14S-146 .... Botsch M. C., 1, 609 42, 210 JJ .... ' )J 144 .... Kopp J. F. P., 37, 283 jj JJ 140-147 .... Hatton and Hodg- 39, 320 kinson JJ JJ J> 145 .... Berthelot G. J. C., 1866 ? .... )) 135-160 .... .... vi., 32 lietinol 236-244 Pelletier & Walter A. C. P. [2], 67, 267 41, 167 Metastyrolene (cya,). Very high 300 in retort Botsch M. C., 1, 609 42, 210 Xylene .... Me.Me=1.2 Lyo-tlln 140-141 Fittig and Bieber Z. C. [2], 5, 495 vi., 294 (contained some para-) a^^lo 141-143 c. 1. 22 Jannasch & Hiibner Z. C. [2], 7, 706 ; vii., 1208 ; 25, A., 170, 117 893 ; 27, 257 143-143 c. Jacobsen B., 10, 1013 32, 601 141 Eicard B., 12, 580 36, 655 Me.Me=1.3 137-138 Liquid Fittig, Laubinger Z. C. [2], 3, 577 vi., 293 and Jannasch H H 136-141 Botsch M. C., 1, 609 42, 211 COMPOUNDS CONTAINING TWO ELEMENTS. 57 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Xylene Me.Me=1.3 1 j) M )) Me.Me=1.4 JJ J> jj ) j) ;j )> jj Me.Me= ? J) ) n jj j) i IT )> M ij ) Ph.Et >> ,, (?) ) 11 or (C 3 H 12 ) n OH H^CeH,^ | orH 2 .C 6 H 4 .Me 2 \OH 2 CH 2 .CH 2 =1.2orMe.Me=1.2 or (C 3 H n ) n Me.Me=1.3 C a H 10 > J5 > I) 11 )) )> n )? j> n !) M )> )) M I) l> n i) i) j M J I) )) )> (Cllln). QH 1S (C 8 H 12 ). C 8 H H 1! ) 139-140 139-8 139 135-140 135-141(730 137-138 140-141 136 136-5 (758) 136-137 136-137 136-5 135-140 136-137 139-140 139-140 136-141 126 126-2 c. (760) 136 128-130 132-134 135 132-5-138-5 (752) 135-140 138-139 138-140 142-142-5 139 139 139-140 140 139-141 133 136-5 133 134 134 130-140 134-136 134-140 260-270 134-135 134 260-270 119 128-130 129-132 133-134 10 15 15 15 13-15 15 86 .... Liquid Eommier Warren Gundelach Tilden Ador and Rilliet Fittig and Velguth Wroblewsky Jacobsen Jannasch Schiff Jannasch Fittig and Glinzer Jannasch Meyer Jacobsen Schaumann Glinzer and Fittig Carstangen Botach Church Eeuard Cahours Ramsay Fittig Naumann Ramsay Longuinene Boyes Warren and Storer Beilstein Rommier Muller Witting and Post Tollens and Fittig Weger Fittig and Konig Weidel & Ciamician Goldschmidt . Ciamician Botsch Forchammer Emmert & Friedrich Piccard Emmert & Friedrich Wreden Renard )> C. R, 70, 641 ; B.S.C.[2],19,434 A., 148, 1 ; A., 156, 236 B.S.C.[2],26,43 45, 416 B., 11, 1627 J., 20, 697 A., 207, 91 B., 14, 2111 Z. C.[2],7, 117 G. J. C., 1881 A., 171, 79 G. J. C., 1865 A., 176, 283 B., 3, 753 B., 10, 1010 B., 11, 1537 A., 136, 303 J. P.O. [2], 23, 421 M. C., 1, 609 P. M. [4], 9, 257 A. C. P. [6], 1,223 J., 3, 492 35, 469 B. S. C., 11, 398 B., 10, 1421 A.C.P.[4],11,153 B., 10, 1710 J., 21, 331 A., 133, 37 B.S.C.[2],19,434 J., 17, 424 B., 10, 745 A., 131, 310 A., 221, 61 A., 144, 277 B., 13, 70 B., 15, 1067 W.A.B.[2Ab],346 M. C., 1, 609 J. F. P., 20, 459 B., 15, 1852 B., 11, 2122 B., 12, 578 B., 15, 1852 A., 163, 336 ; A., 187, 171 ; B., 6, 1381 ; Z. C. [2], 7,97 A. C. P. [6], 1,223 ) A., 142, 299 vii., 402 ; 26, 888 v., 1056 30, 513 36, 228 40, 433 42, 187 24, 509 27,468 . 28, 889 32,600 36,51 v., 857 42,612 42, 211 iv., 2 46, 843 38,469 34,48 39,64 vi., 278 34, 143 v., 1056 26, 887 32,611 iv., 484 46,11 v., 1056 40, 247 42,210 iv., 634 44,39 36, 271 36, 655 44,39 25, 896 ; 32, 446 ; 27, 258 ; vii., 236 46, 843 46, 844 i (from coal tar) !> J> Ethyl benzene ) ji * > ,, o n " Phylloretin Action of P 2 O 5 on y-diethyl- oxybutyric acid Action of P 2 O 5 on y-diethyl- oxybutyric acid Xylene tetrahydride Caprylidene . .. .... ORGANIC COMPOUNDS, Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Conylene PTT 120 (738) Wertheim B.C. p. [1863], 45 ii., 965 125 Liquid Hofmann B., 14, 710 40, 746 126 Wertheim A., 123, 157 ; A., Octine..., 129-132 Re'nard 130, 297 C. K., 95, 141 42, 1179 Campholene .... (See also C 9 H 18 ) 122-126 Ballo B., 12, 324 36, 540 (?) From cu-camphorate 105 Moitessier J. [1866], 410 vi., 389 (?) 105 ; 104-107 Wreden B., 6, 1381 ; A., 27, 258 (?) 122-125 Baeyer 187, 168 A., 155, 206 vii., 656 (?) From rosin oil 130 H6nard B. S. C., 36, 215 42, 64 Octylene ,, pelargonic acid 106-110 Cahours C. K., 31,143; J. 115-117 Schorlemmer [1850], 402 J., 15, 386 ; A iv., 172 vi., 116-120 Cahours 125, 113 A., 92, 399 "710 iv., 172 From Me.(CH 2 ) 6 CH.OH Me 118-119 G. H., 293 118-120 Pelouze & Cahours J., 16, 529 iv., 172 b. 120 Wurtz B. S. C., 5, 307 ; 118-124 Cloez A., 128, 230 B., 7, 823 ; C. R, 27, 972 Fr. Me 2 .CH.CH2.CH 2 CHMe 2 From colophony n 122 120-123 .... Williams R6nard 178, 1865 B., 10, 908 C. R., 95, 245 32, 542 42, 1301 120-125 A. Cahours and E C. E., 86, 991 34, 653 122-125 Demar9ay Fittig J., 13, 320 parafin 122 125 A., 165, 14 122'4 Lachowicz A., 220, 168 46, 166 125 (760) Bouis J. 7, 582 ; A. C. iv., 172 125 P. [3], 44, 139 Z C [1868] 230 125'2 Warren and Storer J., 21, 331 125 126 E Nieson 28, 207 125 127 27, 848 126-128 27 847 (normal) (normal) (?) (diisopropylethylene (diisobutylene) > n (?) .... Me.(CH 2 ) 6 .CH : CH 2 Me.(CH 2 ) 5 .CH : CH 2 (?) CHPrP;CHPr3 Me 2 C : CH.CMe 3 ji (See C 8 H 1S ) From anethol 5) J 1 )? (?) 123-6 298-6 c. t. 122-123 116-120 102-53 102-104 102-5 102-104 107-5 270-8 c. t. abt 150 Liquid Liquid Liquid Pawlewski u Fossek Butlerow si Dobbin Konovaloff Pawlewski > B., 16, 2634 A., 185, 53 M. C., 4, 663 C. C. [1877], 2 A., 189, 49 37, 241 B. S.C.[2], 34, 334 B., 16, 2634 C E 82 849 46, 252 46,38 32, 874 34, 122 40, 400 46, 252 30, 79 Xylene hexhydride .-. JI !) 51 )) n 51 .... 11 Metaoctylene Octane (normal), from dif- ferent sources " u " '? Me.Me = 1.3 =1.3 = ! =1.? =1-4 Me.(CH 2 ) 6 .Me )) M> > )) (Q.HJ. C 8 H 18 j) n 11 115-120 115-120 118 120-123 137-6 c. 250 123-124 123-124 123-124 124 .... Wreden tt > Eenard' Schiff Schorlemmer B., 9, 725 B., 6, 1379 Z. G, 14, 99 A., 187, 155 A. C. P. [6], 1, 223 B., 13, 1407; G.I. 10, 317 A., 92, 396 P. E. S., 16, 367 i? P. E. S., 16, 367 ; vii., 891 27, 258 B., 6, 1380 32, 445 46, 843 38, 892 24, 896 It 24, 896 ; vi., 709 and 879 COMPOUNDS CONTAINING TWO ELEMENTS. 59 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. - Watts' Diet. & J. Ch. Soc. Octane (normal) Me.(CH 2 ) 6 .Me C 8 H 18 124 Schorlemmer B., 3, 616 vii., 277 j) it l 123-125 P. T. [1872], 111 vil., 867 ; 25, 1086 ,, )> 123 Hofmann B., 16, 591 ,, ,, *... M 125-46(760-8 Thorpe 37, 217 (iso) - Me.(CH 2 ) 4 CH.(Me) 2 )> 124 Schorlemmer P. R. S., 16, 370 vi., 65 & 877 ,, .... .... 127 Riche J., 13, 248 1? " " .... ) 122-125 Schorlemmer A., 152, 15 vi., 877 ,, .... .... i) 122-125 Thorpe and Young A.,165,1;B.,5,55 vii.,892; 25,803 ,, .... 118-122 .... j) A., 165, 1 ,, .... .... 119-122 Schorlemmer A., 152, 15 vl., 877 ,, .... .... 119-120 ) J., 15, 386 15, 419;iii., 181 j 118-120 Cahours & Demai^ca; C. R., 80, 1571 From acenaphthene 115-120 Berthelot B. S. C. [21, 8, 22 vl., 3 cinnamene 115-120 L JJ ) B. S. C. [21 9 J vi., 741 ; vi., 466 u L J' ) ^ [1867], 449 116-118 Pelouze & Cahours J., 16, 524 iii., 181 115-118 Wurtz J., 16, 509 (diisobutyl) Me 2 CH.(CH 2 ) 2 .CHMe 2 108-108-3 1. -17 W. C. Williams 35, 125 If (745) j 1 108-2 (745) <* n i 11 ) IT 108-5 c.(747'5 Kopp A., 95, 335 35, 125 ,, )> 106 (745) v., 732 ,, M 1) 108 .... Kolbe A., 69, 358 31, 541 u H 108-5 Wurtz A. v., 732 > ) 106 N A.C.P.[3],4,278 31, 541 ,,(?)(SeeC 8 H 16 ) )> ,, (?) 107-5 Pawlewski B., 16, 2634 46, 252 270-8 c.t. )) > i) M 109 Williams B., 10, 908 31,542 j) i ) N 108-53 (760) Thorpe 37, 219 (amylisopropyl) C 5 H u .CHMej 109-110 Schorlemmer P. R. S., 16, 37 , v., 887 ; vi., 105 J., 20, 567 i u 109 .... Kopp vi., 105 (hexaniethylethane) Me 3 C.CMe 3 105-106 96-97 Lwow B. S. C. [2], 35, 169 40, 399 Xylene octohydride .... j> 118-120 Berthelot B. S. C. [1869], 10 Allyl benzene (o-phenylpro- Ph.CH : CH.Me C,H 10 164-5-165-5 .... Eadziszewsky C. R., 78, 1153 27, 798 pylene) (728) )i 11 11 ) >T 165 Eiigheimer A., 172, 129 27, 894 >' j| 165 Tiemann B., 11, 672 11 11 )? H 165-170 Fittig & Kriigener B., 6, 214 )> J) 11 )J jj 170-171 Perkin 32, 673 ) u )) 174-175 1. 15 32, 666 Isoallyl benzene (/3-pkenyl- Ph.CH ? CH : CH 2 )> 155 Liquid Chojnacki C. R., 76, 1413 ; 28, 1029; J., propylene) A., 172, 132 1873, 359 Cannabene 235-240 Personne J. Ph. [3], 31, 46 vi., 391 90-95invac. Trimethyl benzene (mesity- Me.Me.Me=1.3.5 C 9 H 12 158-168 Jacobsen B., 10, 858 lene) 11 u > )t 155-160 Liquid Sofmann 2,104; A., 74, 106 iii., 930 ; i., 29 i) i) 11 158-163-5 (Not quite Ador and Rilliet B., 12, 329 pure) I? i) i* > 162-164 Cahours 3,17 iii., 930 11 11 1) > 163 .... Tittig & Bruckner A., 147, 42 vi., 298 11 > 11 J) )? 164-167 Fittig Z. C. [2], 4, 577 vi., 296 11 II 11 )) )1 i) 165-167 Jommier B. S. C. [2], 19, 26, 887 434 1) J> 11 162-6-163-6 .... BrUhl A., 200, 190 38, 296 (743) )) 1> 63-5-164 iamsay 9,64 12 60 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Trimethyl benzene (pseudo- Me.Me.Me=1.3.4 C 9 H 12 abt. 166 vi., 200 cumene) 11 11 11 n ) n 166 Fittig vi., 296 11 11 11 n i 166 Beilstein & Kogler A., 137, 117 vi., 297 j n 11 11 ii 166 .... Botsch M. C., 1, 609 42, 211 11 11 i) 165-167 Rommier B. S. C. [2], 19, 26, 888 434 11 ?j 11 n n 163-5-167 Not quite Adir and Rilliet B., 12, 329 pure )> J? 11 ii 166 Liquid P. Jannasch A., 176, 286 28, 889 ? > 11 11 u 158-168 Jacobsen B., 10, 856 T) (?) 165-166 Fittig and Ernst A., 139, 186 v., 1058 Trimethyl benzene (hemimel- =1.2.3 i) 168-170 1.-15 Jacobsen B., 15, 1857 44, 53 lithene) Ethylmethyl benzene Et.Me=1.3 i) 158 .... Ciamician B., 11, 270 34, 439 11 11 11 11 ii 158-159 Wroblewsky C. C., 6, 68 B., 7, 1681 ) 11 n ii 160 Ciamiciau B., 12, 1662 ; 38, 39 ; 38, G. I., 9, 304 126 11 =1.4 ii 161-163 Liquid in Jannasch & Dieck- B.,7,1514;C. C. 28, 1189 freezing mans [1875], 21 mixture ?? ji 11 11 ii 162 Mazzara G. I., 10, 256 38,882 IT 1J 11 ii 159-160 Glinzer and Fittig A., 136, 312 v., 857 ; vi., 11 11 11 n 1.-18 G. H., 606 200 Propyl benzene Ph.CH 2 .CH 2 .Me u 157-157-5 Fittig, Scha'ffer, & A., 149, 324 ; vi., 200 and Kb'nig G. J. C., 1869 295 w 11 n 157-5-158-5 .... Wispek and Zuber A., 218, 374 44, 977 ) > * n ll 156-5-158-5c. .... Patern6 and Spica B., 10, 294; G. I., 31, 707 (758) 7,22 r, n ii 157-6-159 c. .... Spica G. I., 8, 406 36, 631 (738) n it 11 ll 167 .... Etard A. C. P. [5], 22, 40, 582 218 Isopropyl benzene (cumene).... Ph.CHMe 2 144-151-4 .... Gerhard & Cahours P.M. [4], 9, 258; ii., 173 ; iv., 2 A. C. P. [3], 1,88 11 )? 11 n 148 .... Abel and Cahours A., 63, 308 ii., 173 ) )> 5J 11 148-4 c. .... Church P. M. [4], 9, 257 19 n 11 11 145-155 Jacobsen B., 8, 1261 y i> 5) 11 151 R6nard A. C. P. [6], 1,223 46, 844 W JJ JJ ?J 11 151 Warren G. J. C., 1865 ; vi., 200 J., 18, 515 11 5) 11 151-151-5 Fittig and Kb'nig G. J. C., 1869 vi., 295 > J) ii 151 .... Gustavson B., 11, 1251 n JT )> 11 153 Gerhardt A. C.P.[3], 14,111 j )j 11 11 150-160 Kachler A., 164, 75 25, 1012 > )) JT 11 11 151-151-5 Paternd and Pisati G. I., 3, 574 36, 633 *> 11 )) 11 150-155 11 11 G. I., 9, 443 38, 166 T> >J > H 11 152-5-153 Liebmann B., 13, 46 38, 384 Yf (', (?) 11 166-167 .... Romier C. R., 70, 641 vii., 402 Cuniene From coal tar 166 Beilstein & Kogler A., 137, 322 ii 169 '8 Warren J., 18, 515 Retinyl (cumene ?) .... 11 ii 150 Pelletier & Walter A. C. P. [2], 67, 41, 167 267 (?) .... ii 150-160 .... A., 100, 354 (?) From phorone 150-160 Schwanert A., 128, 298 vi., 390 (?) camphrene ii 170-175 A., 128, 298 ; 25, vi., 390 ; vii., 11 1012 239 (?) 11 170-175 A., 123, 304 COMPOUNDS CONTAINING TWO ELEMENTS. 01 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethyltoliiene dihydride Et.Me=1.3 C 8 H U 153-5 (748-7] Liquid Weidel&Ciamician B., 13, 73 38, 404 C'arpene 155-157 Oudemanns B., 6, 1126 27,73 Action of BF 3 on acetone . .... 162-165 Landolph B., 8, 1583 ; C. E , 36, 915 89, 173 Branchite .... C 9 H, 6 75 Savi L. B. J. [1842; , i., 652 459 Campholene .... 135-137 .... A., 38, 340 A., 162, 266 Nonine From camphor 135-140 Weyl B., 1, 96 (?) rosin oil abt. 140 E6nard B.S.C.[2],36, 215 42,64 Cumene tetrahydride .... 155 (?) A. C. P. [6], 1, 223 46, 844 Camphin C 9 H 16 or 167-170 Claus J. p. C., 25, 262 ; i., 725 C 10 H 13 Gm., 14, 488 Nnnylene From oleic acid C 9 H 18 110 Fr6my A., 20, 65 iv., 134 camphor 115-118 .... Weyl B., 1, 95 bituminous shale 120-121 A. 25, 285 ,J .... .... .. Action of BF 3 on acetone 130 Landolph C. R, 89, 173; 36, 915 B., 8, 1583 From fusel oil 140 .... Wurtz J., 16, 510 ; iv., 134 ; B. S. C., 5, 307 vi., 710 cenanthol 144-146 Fittig J., 13, 321 A., 117, .78 paraffin 145-148 A., 165, 19 fish brine 153 c. .... Warren and Storer Z.C. [1868], 230 ; vi., 874 J., 21, 331 Cumene hexydride H ( ,C 6 H 6 .CHMe 2 147-150 147-150 Eenard C. R, 95, 245 A.C.P. [6], 1, 223 42, 1301 46,844 Mesitylene Me.Me.Me=1.3.5 135-138 .... Baeyer A., 155, 275 vii., 657 ^ 135-138 Wreden A., 187, 153 32, 445 ii 138 Baeyer Z. C. [2], .5, 320 vi., 298 Nonane (normal) Me.(CH 2 ) ; .Me" C 9 H 20 150-8 39-5 (11) Eichter Krafft E. K. T., 203 B., 15, 1692 42, 1271 5) 86 (100) 5, n 149-5 (760) 51 (0 5J 148 Lachowicz A., 220, 1881 46, 166 147-148 .... Thorpe and Young A., 165, 19 ;B., 5, vii., 892 ; 556 26, 803 138-140 .... Cahours & Dernargay C. R, 80, 1571 136-138 Pelouze & Cahours J., 16, 524 iii., 181 ,5 55 .... .... n 134-137 .... Wurtz A., 128, 225 ; iii., 181 ; B.S.C.[1863],300 iv., 134 (iso-butylisoamyl) .... (methyldiisopropyl- Me 2 .CH.CH 2 .(CH 2 ) 2 .CHMe 2 P^.CHj.CHMePr 8 " 132 130 Silva J., 8, 576 B., 5, 984 v.,732; vi.,709 ethane) Naphthalene .... } = Q Q Q Q OH' 175-180 212 79 Dumas B. S. C., 37, 303 A.C.P.[2], 50, 182 II 1 C=C C C=C 221 Gerhardt A.C.P.[3], 14,111 " 81 Lowe D. P., 201, 250 3) " 79 Baeyer and Perkin B. 17, 451 " " 218 79 H. Kopp iv., 5 " 79-2 Kopp A. 218 Craffts B. S. C., 39, 196, 44,843 and 277 218 100 (v. t. 79-2 Naumann B., 4, 647 84, 879 20-5), 78 (v. t. 9-0), 15 (v. t. 2-0) 62 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Naphthalene c=c c c=c ^10 8 218 Grimshaw and 26, 1075 1 II 1 c=c c c=c Schorlemmer ) )) 217 79-91 Schorlemmer Alluard 28, 209 J., 12, 472 217 80 Schultz B., 9, 549 30, 197 )) 80-07 E. J. Mills P.E.S. [1881], 205 J) 213 u.c. 79-5 Carnelley L J7 37, 706 )> 217 c. j .... J )> 217-218 217 79-25 Vohl Geissler J. p. C., 102, 29 26, 1075 vi., 843 70 Goldschmiedt and W. A., 83 [2], 7 40, 824 J) Schidt Phenyl crotonylene Ph.CH:CH.CH:CH 3 C 10 H 10 185-190 Aronheim A., 171, 230 27, 689 Ethylphenyl acetylene Ph.C = C.Et > 201-203 u.c. Morgan 29, 163 Naphthalene dihydride .... 200-210 Berthelot J. [1867], 709 ; vi., 844 B. S. G, 9, 288 it 199-201 Pechmann B., 16, 517 44,809 > 205 Wreden and C. C., 177, 6 32, 899 Znatovicz (?) .... 210-212 Graebe B., 5, 679 a-Phenyl butylene Ph.CH 2 .CH s .CH:OH., ) 176-178 Liquid Aronheim B., 5, 1069 ; A., vii., 945 ; 171, 227 26, 500 - ) )) 177 Penfield A., 216, 125 44, 474 n > From Ph.OH CH.COOH 1 1 O.CO.CH.Me ^10^12 176-177 .... Fittig B., 14, 1825 42, 190 0- Ph.cn: CH.CH 2 .CH 3 (?) 186 Radziszewsky B., 9, 261 29, 915 P- ,> 184-186 Perkin 35, 139 0- )> )1 183-186 A., 216, 118 0- >! 51 >! 186-187 Liquid Perkin J. [1877], 382 32, 667 Naphthalene tetrahydride .... .... >i 201 Wreden and C. C. [1887], 6 32, 899 Znatovicz (?) .... ,, (?) 190 Berthelot J. [1867], 709 vi., 844 it * .... 5 205 c. C. Graebe B., 5, 678 25, 1008 Paranicene .... 205 365 Graebe and Guyl St. Evre B., 16, 3028 J., 1, 532 46, 608 (?) .... J 201 .... Baeyer A., 155, 266 vii., 657 (?) C.oH^orCsHe 119 Engler and Leist B., 6, 255 26, 901 Tetramethyl benzene (du- C 6 H s Me 4 =1.2.4.5 CioHu 189-191 79-80 Jannasch and Fittig Z. C. [2], 6, 16 vi., 828 rene) i )> ) 193-195 79-80 Ador and Eilliet B., 12, 331 >j 191 80 Jannasch A., 176, 283 28, 889 > 190 110 (sic) Friedel and Crafts C. E., 91, 257 40, 40 )> n (1SO- =1.2.3.5 j) 185-190 L 18 Ador and Eilliet B., 12, 331 36, 527 durene) ? J> ) > 195 c. l.SO Jacobsen B., 15, 1853 44,52 ;? 195 Montgoltier A. C. P. [5], 14, 87 34, 889 ; 46, 43 w j ) 192-194 Liquid in Jannasch B., 8,355; B., 15, freezing 1853 mixture ) ) j> i) 195-197 Bielefeldt A., 198, 380 38,37 )> ) =(?) ., 196 Knublai\ch Tubigen,I.D.,1875 Ethyldimethyl benzene C 6 H 3 .Et.Me 2 =1.3.5 180-182 Jacobsen B., 7, 1433 28, 259 > 185 L 20 Wroblewsky B., 9, 496; A., 30, 406 ; 34, 192, 217 978 )> =1.2.4 )) 183-184 Liquid Fittig and Ernst A., 139, 192 ; Z. v., 1058 ; vi., (lau- rene ?) =1.3.4 )i 189 Armstrong & Miller C. [2], 1, 572 B., 16, 2258 302 46, 44 COMPOUNDS CONTAINING TWO ELEMENTS. 63 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diethyl benzene C c H 4 Et 2 =1.3 C 10 H 14 176-179 Allen & Underwoot B. S. C., 40, 100 46, 587 "=1.4 178-179 Fittig and Konig A., 144, 285 ; Z vi., 301 C. [2], 2, 358 181-182 Liquid in Axhenbrandt B., 12, 1303 ; A. 36, 920; 44,31 8 freezing 216, 211 mixture 183 A. C. J., 4, 197 = (?) 179-185 B. S. C., 31, 540 Methylpropyl benzene (cy- C 6 H 4 .Me.Pr=1.2 181-182 u. c Liquid Glaus and Hausen B., 13, 897 38, 631 mene) = 1.3 176-177-5 Liquid Glaus and Stiisser B., 13, 899 ; J. E 38,632 C. S. [1882], 36 ) = 1.4 173-175 Paternd G. I., 13, 535 46, 427 175-176 Fittica B., 7, 324; A. 27, 684; 28,60 172, 303 ' 173-175 Jahns B., 15, 818 178-179 Fittig, Schaffer, A., 149, 334 vi., 301 & 302 and Konig )! ') 175 J. E. C. S., 11, 8 H 174-176 Etard A. C. P. [5], 22, 21 40, 582 >1 !) 175 Glaus B., 14, 2139 42, 196 ^ 175-175-5 Jacobsen B., 11, 1060 ; B., 34, 731 ; 36, (763) 12, 431 624 175-178 Spica G. I., 12, 482 44,321 ' 174-175 1. 18 Carstanjen J. p. C. [2], 3, 53 24, 353 ; vii., 935 ^ 175 c. Fittica A., 172, 303 28, 59 Methylpropyl benzene (from ] f 175 c. n camphor) ,, 174-175 Kopp Z. C. [2], 4, 194 vi., 278 V ' 176-55(761-4- Pisati and Paternd G. I., 3, 351 vii., 420 ; 27, 761-6) 686 ?' " 175 Beilstein & Kupffer B., 6, 1182 27, 153 )' J) 175-178 u. c. Paternd G. I, 4, 113 27, 688 173 (720) .... Nencki and Ziegler B., 5, 749 26, 64 n j> 173-176 Fittig, Kobrich, A,, 145, 129 26, 696 and Jilke V ?1 175-178 c. Wright 26, 690 ,. ., 172-175 c. Longuinine B., 5, 730 26, 383 ,, 174-175 A. C. P. [4], 11, 453 .. -C 6 H 4 .Me.Pr a =1.4 177-179 Kekule Lehrbuch 26, 696 TJ ) V > All these natural cy- menes on oxidation give first 1.4 toluic acid and then terephthalic and acetic acids )? 175 175-178 180 175-178 177-179 Delalande Longuinine and Lippmann Landolph Pott Longuinine J., 20, 700 ; B. S. C. [2], 7, 374 C. E., 85 Z. C. [2], 5, 200 32, 864 vi., 302 JJ 179 c. Warren J. [1865], 525 Methylpropyl benzene (from j) 177-5 (743-7) Kopp A., 1855 or 1856 ii., 296 cumin oil) 1 1) 175-176 Longuinine J. [1867], 692; vi., 278 & 302 A. C.P.[4], 11,153 * 175-1 (761-4- Pisati and Paterno G. I., 3, 551 vii., 420 ; 27, 761-6) 1686 ?J J 175 Beilstein & Kupffer B., 6, 1181 27, 152 171-5 Noad A., 63, 281 ; P.M 26, 695 ; ii., [31 32, 15 296 V 75-5-177-5 c. Wright 26, 695 175 Gerhard t & Cahours A., 38, 345 i., 296 ORGANIC COMPOUNDS. Name. Constitution. Formula Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylpropyl benzene (from 1 CioH 14 175 Gerhardt A. C. P. [3], 14, 11 cumin oil) 11 11 ii 170-7 .... Church P. M. [4], 9, 256 11 11 11 175-176 11 11 n 11 11 179-5 Warren M. A. A., 9, 154 Methylpropyl benzene (from ji 177-25(761-4 Pisati and Patern G. I., 3, 551 vii., 420; 27, cymyl alcohol) 761-6) 686 11 11 11 174-8 Kraut A., 192, 222 34, 973 Methylpropyl benzene (from 11 176 Wright 27,1 absinthol) i) 11 175-178 11 27, 319 11 11 175-178 11 27, 320 11 . )! 11 175 Beilstein&Kupffe A., 170, 295 ; B 6, 1183 11 11 175 Gladstone c?) 27, 324 Methylpropyl benzene (from 11 175-177 Wright 27, 323 citronellol) 11 5) 11 175-177 .... Wright & Lamber 27, 622 11 )) 11 176-179 Oppenheim B., 5, 629 25, 1010; vii., 419 Methylpropyl benzene (from 11 176-177 c. .... Wright & Lamber 27, 620 cajeputol) 11 11 175-178 Wright 27, 622 Methylpropyl benzene (from C 6 H 4 .Me.Pr a =1.4 11 175-178 11 11 turpentine) 11 11 11 11 '> 11 All these natural cy- menes on oxidation give first 1.4 toluic acid and then terephthalic and acetic acids 11 11 11 11 174-177 c. 176-179 176-179 175-5-178-5 c 11 Barbier Oppenheim 11 26, 691 C. E., 74, 194 B., 5, 629 B., 5, 96 25, 240 25, 1010; vii., 419 25, 393 ; vii., 419 Methylpropyl benzene (from 11 176-177 Wright 27, 622 hesperidene) I) >! 11 175-5-177-5 c .... n 26, 692 Methylpropyl benzene (from 175-176 c. .... Fittica A., 172, 30 ; B., 28,59 ptychotis) 6, 939 Methylpropyl benzene (from i 173-177 c. Wright 26, 690 nutmeg) ii 11 11 176-178 c. 11 26, 694 Methylpropyl benzene (from 11 176-178 c. 11 26, 688 myristicol) 11 11 11 173-177 c. 11 26, 689 Methylpropyl benzene (from 11 175-180 'fietsky A. P. [3], 4, 317 27, 892 dill oil) Methylpropyl benzene (from 11 174-178 lennie 39, 241 kauri gum) Methylpropyl benzene (from 11 75-178 Jecket and Wright 29, 2 peppermint camphor) Methylisopropyl benzene 3 6 H 4 .Me.Pr" =1.3 11 76 rmstrong & Miller B., 16, 2258 6, 44 (isocymene) ii i )J )I 11 74-176 25 elbe A., 210, 1 42, 300 II >! ) 11 73-175 jiquid 11 B., 13, 1159 8,878 11 II ) 11 71-175 jiquid Ziegler and Kelbe B., 13, 1400 ; 1830 Methylisopropyl benzene 11 70-178 jiquid Celbe B., 13, 1158 38, 878 (from rosin oil) Tl II > 11 75-178 ;6nard A. C. P. [6], 1,223 46,844 Methylisopropyl benzene .... > 11 86-188 lelbe B., 14, 1241 ii i) = 1.4 11 71-172(765) SO acobsen B., 12, 431 36, 624 i Methylpropyl benzene J> 3 6 H 4 .Me.(Pr a or Pr 8 ) =1.3 11 11 75-178 73-2-1 74 c. 'aterno and Spica spica G. I., 9, 397 B., 16, 792 38, 107 G. I., 12, 543 Methylpropyl benzene (from ii ii 11 74-175 Weidel & Ciamician B., 13, 74 38,404 animal tar) COMPOUNDS CONTAINING TWO ELEMENTS. 65 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylpropyl benzene (from C 6 H 4 .Me.(Pr or Pr") =1.4 C 10 H 14 174-175 Liquid Homeyer A. P. [3], 5, 293 29, 244 eucalyptus) Methylpropyl benzene (from <> 175 Kallen B., 9, 155 29, 917 inulol) Methylpropyl benzene (from .. 170-175 Bruylants J. P. [4], 26, 393 34, 158 tansol) 175-176 Methylpropyl benzene (from 175 J. P. [4], 29, 508 36, 726 rosemary) Methylpropyl benzene (from 174-1 75; 175- Greebe B., 5, 680 25, 1009 wormseed oil) 176 t >. ,5 172-174 Kraut & Wahlfoss Methylpropyl benzene (from 175-179 Siguiraand Muir 33, 294 sage oil) Methylpropyl benzene (from 175-177 Liquid Febve C. R, 92, 1290 42, 524 wild thyme oil) Methylpropyl benzene (from M 178-180 R6nard C. R, 90, 531 38, 479 terebenthene) Methylpropyl benzene (from 177 Riban C. R, 79, 223 27, 1162 isoterebenthene) Methylpropyl benzene (?) 174-175 Gustavson B. S. C. [2], 26, 340 34,49 175 Ramsay 39, 64 Methylpropyl benzene (from .... 1) 171 Mansfield 1,267 coal naphtha) . n 177-5 .... .... iv., 2 )7 5 179-180 Berthelot B. S. C. [2], 8, 226 vi., 303 Butyl benzene (normal) CsHj.CHj.CHj.CHj.Me n 180 Liquid Radziszewsky B., 9, 261 29, 915 ,. H 179-5-180-5 c. 1. -16 Balbiano G. I., 7, 343 ; B., 34,314 (74*) 10, 296 a-Isobutyl benzene .... C 6 H 6 .CH 2 .CHMe,, jj 167-5 Radziszewsky B., 9, 260 29, 915 "- ,, n H 159-160 Liquid Riess Z.C.[2],7,39;B., 24,221 3,780 <*~- ,, .... .... n 167 Wreden & Znatowicz B., 9, 1606 ; C. C. 32,885 [1877], 6 o- , H 166-168 Goldschmidt B., 15, 1066 ; 1426 175 177-179 b. 39 Bouchardat A., 27, 30 B. S. C. [2], 24, 108 i., 736 29, 86 Carvene 166 Gladstone 17, 18 173 i., 808 175-178 Volckel J., C, 512 Cicutene 166 Van Ankum Z. C. [1869], 248 ; Cinoebene 172 Stenhouse J., 21, 794 P. J. T., 17, 19 v., 1048 172 Hirzel J., 7, 592 Citrene 165 Blanchet and Sell Gm., 14, 303 i., 994 173-174 Oppeuheim B., 5, 628 25, 1009 176 Tilden P. J. T. [3], 9, 654 36, 386 Colophene 315 Gladstone 17,18 Cynene .... >I 172-174 173-175 174-175 .... Kraut & Wahlfoos Volckel Graebe B., 5, 680 A., 89, 358 B., 5, 680 25, 1009 Decone From diamylene 155-160 A., 151, 52 Diisoprene 174-176 Tilden C. N., 46, 120 44, 75 170-180 45, 414 176-181 Bouchardat B.,8,904;B.S.C., Eucalyptene .... 172-175 Oppenheim & Pfaff 24, 112 B., 7, 626 173-174 Faust and Homeyer B., 7, 65 Gaultherilene.... 160 Cahours A., 52, 331 ii., 826 160 Biedermann B., 8, 1677 29, 704 168 Gladstone 17, 18 Geraniene 162-164 Jacobsen A., 157, 239 24, 262 162-172 B., 7, 626 Hesperidene 163 164 Wright 26, 551 From Tujtmpiy 167 Gladstone 16, 1 26, 549 C 8 H 12 : CHMe 174 Wright and Piesse C. N., 24, 147 ; 34, 1186; vi., 877 174-175 Tilden & Sheiistone B. A. R, 1871 31, 558 COMPOUNDS CONTAINING TWO ELEMENTS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Hesperidene . .. .... C H 175-177 Wright and Piease C. N., 24, 147 24, 1187 178 Wright 27, 67 and 622 176-178 Schmild T. E., 22, 360 ; i., 711 ; 14, 63 Isoterebenthene a- a- .... * /- Isoterpene Lsevorotary ii 11 i 176-178 177 175 1 79 '3 c. (762 -6) Berthelot Riban Riban Flawitzky J. [1860], 481 A. C. P. [3], 39, 16 ; J., 6, 523 A. C. P. [5], 6, 216; C. R., 79, 223 A, C. P. [5], 6, 216; C. R., 79, 223 B., 12, 2356 27, 1162 28, 62 38, 403 168-172 C. R., 92, 998 ; Macene 160 Schacht 94, 733 J., 15, 461 Olibene 156-158 Kurbatow Z. C. [21 7, 201 ; 24, 695 ; 28, 90 160 A., 173, 2 J. [1874], 919 vii., 873 Paraterebenthene Phellanthrene From turpentine 11 n abt. 250 103-104 (80) 171-172(766) Berthelot Pesci A. G. I., 13, 496 v., 921 46, 331 Pilocarpene .... .... .... 178 Hardy J. P. [41, 23, 95 32, 325 250 155 157 A 152 88 vi., 1014 Sequoiene Sylvestrene (laevorotary) From pinus pumilio ii 11 155 171-176 173-175 Lunge & Steinkauler Atterberg B., 14, 2204 B., 14, 2531 B , 10 1203 42,208 42, 410 34, 79; 33, 82 Terebangelene a- 0- ii 11 175 (22) 166 156 Liquid Naudin B. S. C., 37, 108 C. R., 96, 1152 44,810 v., 924 156 37, 678 155-156 1 27 Riban C R , 76 1547 26,1137; 33,84 156-25 C R 78 288 27, 580 abt. 160 Deville A. C. P., 15, 37 35, 733 160 Berthelot ,T 15 457 160 17, 18 171 J 4 52 t Terebenthene from ,, .... .... ,, .... .... ,, .... .... ,, .... .... ,, [-] .... 5 )> " )> [+] ..- ) I) " )) J " J) [-] -.. Rosin oil ii ii Turpentine ii n Oil of lemon n Angelica ii Pinus pumilio ii ii n 11 11 11 ii 11 11 ii abt. 150 154-157 171-173 156-25 161 a. 175 165 177 175 (o.p.) 87 (22) 156-160 170-173 Liquid Renard ii ii Riban Flavitzky n ii Naudin n Atterberg Haller B.S.C. [2], 36, 215 A. C. P. [6], 1, 223 ii C. R., 78, 288 B. S. C. [2], 34, 342 B. S.C.[2],34, 171 )> C. R., 93, 1146 JJ B., 14, 2531 C R 94 132 42,64 46, 844 11 27, 580 v., 921 40, 437 ! 11 42,410 11 11 42, 738 ,, Terebilene .... 11 175 134 Flavitzky B. S. C. [2], 33, 296 38, 559 v., 925 Terecamphene Terpene from n .... .... ,, 11 .... .... 11 .... .... 11 ii ii ii H ii ii 11 .... 11 Amber Anethol Angelica seeds Angelica archangelica 11 11 n ii ii ii n ii 11 51 II II II abt. 160 160-170 157-163 166 172-5 158 171-175 176 250 45 Liquid Liquid Landolph Naudin Miiller Beilstein & Wiegand ii 11 11 J. p. G, 26, 79 ; A., 54, 241 ; J. [1850], 494; B. J., 24, 619 C. R., 85 C. R., 96, 1152 B., 14, 2483 B., 15, 1741 B., 15, 1742 ji 11 u 32, 864 44, 810 42, 497 42, 1300 )) ) K 2 68 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Terpene from Animal tar C 10 H 16 172-5 (748-5 Weidel & Ciamician B., 13, 75 38, 404 Anise oil 160 Gladstone 17, 18 Athamanta oreoselinum 163 .... A., 51, 336 jj .... .... jj Bay oil 164 Bias J., 18, 569 171 Gladstone A., 44, 309, 50, 17, 18 ; vi., 608 155 ; J. [1863], 547 Bergamot H 175-176 17, 18 jj .... jj 183 Ohme A., 31, 317 ; 35, 313 Birch bark 171 J. [1863], 547 .... .... Birch tar 156 Sobrero J. P. [3], 2, 207 i., 589 Borneol JT 176-180 Kachler A., 164, 75 vii., 206 Cajeputol 160-166 Schmild 27, 322 .... .... ,, J? 176-178 Calamus 158-159 Kurbatow A, 173, 4 28, 91 jj " ".. jj 250-255 J. [1874], 919 ,i 255-258 Kurbatow B., 6, 1210 ; A., 27, 259 ; 28, 173,1 91 ; vii., 231 ;) 260 Gladstone .... 17, 18 Camphor 160 Montgolfier A. C. P. [5], 14, 5 34, 900 ,, .... .... Caraway jj 176 178 Gladstone 17, 18 42,43 .... .... ,, Carvol 173 Arndt B., 4, 204 ; Z. C. vi., 415 [2], 4, 780 .... .... ,, Cascarilla 172 Gladstone 17, 18 t .... .... ,, 254 jj .... JJ Cedrat 173 .... JJ ,, .... .... Citronellol 168-173 Wright 27, 322 Citrus bigaradia ;) 178 Luca C. R, 45, 904 jj .... .. jj medica 66(1) Berthelot J., 6, 521 Cloves 142 Ettling A. C. P., 60, 68 i., 1029 jj .... *- jj 249 Gladstone 17, 18 jj .... L J jj Colophony 170-173 Eenard C. R, 92, 887 ; 94 40, 738 727 [inactive] u 171-173 C. R, 92, 887 40, 739 Copal oil 160-165 Schibler J., 12, 516 ,, .... .... Coriandum sativum n 178-180 Grosser B., 14, 2492 42, 525 .... [-] Cubebs u 158-163 Schmidt G. I., 5, 467 ; B., 30, 642 8, 1357 jj 160 Oglialoro G. L, 5, 467 .... .... 260 Gladstone 17, 18 .... .... Cumin JT 155-8 Warren J., 18, 515 Diamylene 145-150 .... J. R [1881], 445 Dill oil 155-160 Nietsky A. P. [3], 4, 317 27, 892 v n 175 173 Gladstone J. [1863], 548 17, 18 .... .... Dryabalanops camphora 180-190, 260 Lallemand A. C. P., 57, 404 I., 729 .... .... Elder oil ,, 172 Gladstone 17, 18 .... .... Elemi oil n 166 Stenhouse A., 35, 304 ii., 483 .... ., H 174 Deville J., 2, 448 Erechides 175 Beilstein&Wiegand B., 15, 2854 44, 346 .... ... u 240-310 jj - -. jj Erigeron Canadense n 176 jj jj jj .... .... jj Eucalyptus 150-151 Faust and Homeyer B., 7, 1429 28, 371 150-151 Homeyer A. P. [3], 5, 293 29, 244 ,j .... jj Eucalyp. amygd. 171 Gladstone 17, 18 Fennel B 185-190 A., 41, 75 Galbanum B 160-161 .... Mossner A. P., 99, 257 ; ii., 758 A., 119, 258 jj " jj [llicium relig. 173-176 1. 20 Eykmann B., 14, 1721 40, 918 Joberandi ,, 178 .... Hardy U. P., 16, 365 30, 368 COMPOUNDS CONTAINING TWO ELEMENTS. 09 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Terpene from Juniper C-ioH 16 155 A., 7, 165; 34,32 .... .... ,, 11 160 G. T., 3, 637 iii., 444 .... .... ii )! 163 Z. C. [1867], 509 ,, .... .... Kauri gum 157-158 Eennie 39, 241 .... .... ,, Lavender (?) 162 Bruylauta J. P. [4], 30, 139 38,51 .... .... 11 200-210 11 A., 114, 198 .... .... ,, Lemon oil 166-168 Gladstone J. [1872], 813 25,2 n 11 )) 173 11 17, 18 ,, .... .... ,, 11 )) 173 Blanchet and Sell i., 1004 ,, .... .... ,, 11 ?> 174-8 Eegnault M. A. S., 26, 658 .... .... ,, 11 174-176 Tildeu 35,287 ,, .... .... ,, 11 175 Fittig and Krafft A., 208, 71 42,42 .... .... ,, 11 )) 176 Fittig and Sauer B., 10, 522 32, 432 .... .... j) 176-1 .... Brix i., 1004 ,, .... .... ,, Limes )) 176 u. c. Piesse and Wright 32, 549 .... .... J, Limett oil )> 176 J. [1877], 957 ,, .... .... ,, Linaloes ) 168-172 (765 Liquid Morin C. R, 94, 733 42, 737 ,J .... .... ,, Marjoram 161 Kane A., 32, 285 iii., 854 ,, .... .... JJ ?? ) 160-162 Bruylauts J. P. [4], 30, 139 38, 50 ,, .... .... ,, )) 178 Beilstein & Wieganc B., 15, 2855 44,346 ) " Mastic oil >J 155-160 Jungelaussen R, 14, 2419 ; 42, 208 A.P. [3], 19, 170 )> .... .... Mentha crispa J 168-171 Beyer A. P. [3], 21, 283 46, 331 I) " Menthol 168-6 Atkinson & Yoshida 41, 55 V .... .... Mint 160 Gladstone 17, 18 .... .... J, Myrtle II 163 11 J. [1863], 548 11 ,, .... .... Neroli II 173 11 11 ,, .... .... Nutmeg II 163-164 c. Wright 26, 549, 686 ; 32 vii., 862 ; 27, 67 549 ,, .... .... II 166-167 .... Gladstone A., 131, 211 17, 18 1J .... .... ,) Orange oil 11 178 Piesse and Wright 32, 549 .... .... II 180 .... Soubeiran and Capitaine .... .... t Bitter orange 11 178 Luca C. R, 45, 904 i., 1003 r Sweet orange 11 180 J. [1860], 479 i., 1002 .... .... Orange peel 11 174 Gladstone .... 17, 18 > 11 178 c. Wright J. [1873], 369 26, 552 " .... ) 5 Parsley 11 157-5-158 .... Fittig and Krafft A., 208, 71 42, 43 , 11 160 .... Gladstone 17, 18 .... [-] )> 11 160-164 .... Gerichten B.,9,259; A., 208 30, 78 75; P. A., 46, 53 .... .... Parsnip 11 160-164 11 11 i! .... .... ., Patchouli 11 254 .... Gladstone 17, 18 .... .... Penang 11 257 11 .... .... French )! 260 11 n 11 11 Pepper 11 167-5 .... A., 15, 159 ; 34, 326 11 .... .... ,, Peppermint 11 175 .... Gladstone 17, 18 !! Petit grain 11 174 11 )) 11 Pine oil 11 161 Mikolasch J. [1860], 478 iv., 649 11 11 Pinus abies 11 167 Wohler " ,1 P. ab. reg. amal. 11 156-159 Buckner and Thiel J., 17, 536 vi., 1 " I) Pinus maritima 11 80-100 Berthelot J., 6, 519 ! picea 11 168-173 Fliickiger J., 8, 643 (templiii oil) pumilio 11 161 Buckner J., 13, 479 11 > )) 11 161 Atterberg B., 14, 2532 [-] ..- > >j 11 250 d. 11 B., 14, 2531 42, 410 [-] -.. ) ) 11 172 Fliickiger J. [1856], 642 v., 719 sylvestris 11 155-5-156-5 Flawitzky B.S.C.[2],30,433 36, 168 it .... . .. ,, )> 11 156-159 Tilden 33, 83 " i) )? 11 171 11 .... " i! Poplar oil 1) 260-261 Piccard B., 6, 890 70 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Beference. Watts' Diet. & J. Ch. Soc. Terpene from Ptychotis ajowan C 10 H 16 172 Stenhouse J., 9, 624 v., 792 Resina gardenia lucida 158 A., 200, 315 guaiaci Peruviana it 168 Kopp A. P. [3], 9, 193 31, 716 aromatica v. odorata it .... .... Resin spirit it 160 .... Schiel A., 115, 96 41, 168 11 .... .... 11 Rosemary tt 157-160 Bruylants J. P. [4], 29, 508 36, 725 11 > .... tt 163 Gladstone 17, 18 . Rosewood 11 249 it J. [1863], 549 17, 18; vii., 116 .... .... Sage oil 11 152-156 Muir and Siguira .... 33, 293 11 156 Muir 37, 679 ,, .... .... it 157 11 .... 37, 689 tt 158-160 Tilden & Shenstone 31, 557 n .... .... 11 162-167 Muir and Siguira 33, 293 tt 167 Muir .... 37, 679 it 168-176 Tilden & Shenstone 31, 557 ,. .... .... tt 178-180 .... Jahns B., 15, 819 42, 1065 i> .... .... Sal viol tt abt. 172 .... Muir 37, 683 i .... .... Sandal-wood it 185-200 .... B. S. C., 37, 303 .... .... Essence of savory 11 172-175 Haller C. R, 94, 132 42, 737 , .... .... 11 tt 180-185 .... n 11 tt n .... Spikoil it 175 A, 114, 197 .... ,, Oil of tansy tt 155-160 Bruylants B., 11, 452 34, 512 it .... 11 it 11 160-165 it 11 n .... .... Terebenthene 11 157 Liquid Barbier G. R, 96, 1066 44,809 .... .... tt 11 157 Liquid it t .... ,, tt tt 173 Montgolfier C. R, 87, 840 36, 329 .... .... Thyme oil tt 160 Gladstone 17, 18 11 .... .... it tt 160-165 .... A., 102, 119 [ ] Turpentine tt 155 Flawitzky B., 12, 2357 33, 403 ., .... .... it it abt. 159 .... Wright .... 27, Ci22 it it 160-161 .... Oppenheim B., 5, 628 25, 1009; 32, 549 (laurel) tt 160 Gladstone 17, 18 (Russian) 171 Tilden 33, 81 , : .... .... tt tt 173 Letts B., 13, 796 38, 669 Valerian oil it 155-157 Bruylants J. P. [4], 27, 349 34, 800 ., .... tt tt 155-160 B., 11, 453 ., Wormwood oil it abt. 150 Wright 27, 317 ,, .... .... ,, it it b. 160 .... Beilstein & Kupffer B., 6, 1183 27, 153, 324 (?) 150 B. S. C., 36, 215 (?) tt 158 Stenhouse & Groves 35, 691 (?) tt 159-15 Regnault G. J. G, 1862 (?) tt 160-162 Landolt G. J. C., 1877 (?) ' tt 169-173 B. S. C., 36, 215 Terepentiline .... it b. 180 Berthelot A. v., 921 Terpinene tt 176'5-181'5 Walitzky C. R, 94, 96 42, 411 Terpilene (terpinylene) .... tt tt 176 .... Tilden C. N., 39, 256 36, 944 n .... _ 176-178 11 B., 12, 1132 33, 250 11 it tt abt. 178 .... Armstrong & Tilden B., 11, 1754 35, 758 11 n .... it 176-181 Bouchardat C. R, 80, 1446 28, 1259 Thymene 160-165 Lallmand A. C. P. [3], 49, 135 v., 792 Tolene tt 154-160 Kopp A, 44, 304; 97, 72 v., 851 tt 170 Deville & Scharling A., 64, 372 Turpentine oil .... it tt 155 Pictet P. M. [5], 1, 484 32, 163 .... tt 156 Tilden C. N., 39, 256 36, 943 .... it 159-2 .... Regnault M. A. S., 26, 658 JJ U " " .... it 160 Wright .... 26, 549 .... tt 160 .... Gladstone 17, 18 51 .... .... .... it 160 Thorpe 37, 151 .... tt 165 Blanchet and Sell Xanthoxylene .... tt 162 Stenhouse A., 104, 237 v., 1054 Meta-austraterebenthene .... .... (C 10 H, 6 ). abt. 360 .... v., 924 COMPOUNDS CONTAINING TWO ELEMENTS. 71 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. From borneol cr H i 250-280 Kachler A., 164, 75 vii., 206 From turpentine hydro- chloride Naphthalene decahydride .... Camphenedihydride ,, .... .... ,, is * CjoHipHj u j (Ci H 17 ) B ^lO-^MS J )> )) 157-158 175-180 163 165 159-160 167-170 94 120 140 c. Letts Wreden and Znato- wicz Montgolfier Berthelot Montgolfier Kachler and Spitzer B., 13, 794 C. C. [1877], 6 ; B.S.C.[2],26,449 A. C. P. [5], 19, 145 C. B., 67, 327 C. R, 87, 840 ; A.C.P.[5],19,145 B., 13, 616 J. p. C., 25, 264 38, 669 32, 466, 899 vi., 1111 36, 328 ; 38, 699 38, 669 Menthene 163 Walter A., 32, 288 iii., 880 163 Oppenheim 15, 29 39, 81 164-5 165'5 Becket and Wright 29, 2 162-167 Moriya 39, 81 167-4 c. Liquid Atkinan & Yoshida 41, 53 Rutylene abt. 150 Bauer A., 135, 344 v., 141 156-5158 Harting J. p. C. [21 23, 449 40, 795 Sebucin a. 300 55 Petersen A., 103, 187 v., 214 Decenylene abt. 165 Eeboul and Truch6t B. S. C. [2], 8, 42 vi., 52 Decin .... 154-157 C. R, 94, 727 ; 157-158 152 (!) 95, 245 A.C. P. [5], 19, 148 .... .... .... from Camphor 163 Weyl B., 1, 96 170-175 Berthelot B. S. C. [2], 11, 3 vii., 423 From calamus oil From allyldipropylcarbinol 1 1 From terebenthene Decylene JJ ) ) )) 158-159 158 163 163 158-160 Liquid 127 Liquid Kurbatow Eeformatsky Riche Weyl Montgolfier B., 6, 1210 J. p. C., 27, 389 R C. p. [2], 127 Z. C. [2], 4, 496 C. R, 87, 840 J. [1863] 529 27, 259 44, 1074 v., 213 vi., 387 36, 328 vi., 710 161-5 Lachowicz A., 220, 168 46, 166 165 Berthelot B S C [2] 11,3 vii., 423 170-172 A., 165, 22 from .... .... Diamylene (paramylene) Fish brine Burmese earth oil ) 174-6 175-8 165 165 .... Warren and Storrer Balard Bauer Z. C. [1868], 230 ; J., 21, 332 Z.C. [1868], 231; J., 21, 331 A. C. P. [3], 12, 320 J., 14, 660 iii., 416 vi., 122 165 Etard C R 86 488 34, 393 . Pr0(CH 2 ) 3 .CHMe.CH : CH 2 150-153(721) Schneider A., 157, 208 vii., 64 .... Cymene hexhydride i) Naphthalene duodecahydride Terpilene tetrahydride ) 51 Terpene tetrahydride Action of PH 4 I on turpentine Action of I on turpentine .... )> .From crude terebene Action of HI on camphor .... From carvol Isomers J) )) ji ) !) J) n 153-158 155-160 171-173 155 170-175 170c. 155-160 ; 1CO-162 ; 162-167 160 abt. 160 abt. 170 abt. 170 170-175 176 178 Liquid Wreden Wreden & Znatowicz Kcnard Wreden&Znatowicz Berthelot Montgolfier Orlow Baeyer Armstrong )5 Armstrong & Tilden Weyl Arndt A., 187, 164 B.S.C.[2],26,440 A. C. P. [6], 1, 223 C. C. [1877], 6 C. R, 67, 327 C. R, 89, 102 B., 16, 799 A., 155, 276 B., 12, 1758 ?> Z. C. [2], 4, 496 Z C [2] 4 730 32, 445 32, 466 46, 844 32, 899 vi., Ill 36, 944 vii., 657 38, 125 J> 35, 745 vi., 387 vi., 4i:> Decane 107 (100) 3 & Krafft B 15 1695 42, 1271 > 173 (760) 171 A 184 202 169'5 A 220 168 46, Hit; 72 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Decane 166-168 Thorpe and Young A., 165, 23 162-163 Lachowicz A., 220, 188 46, 166 100 Berthelot B. S. C. [2], 8, 226 vi., 3 158-162 Pelouze & Cahours J., 16, 524 v., 1090 158-160 Cahours & Demaray C. R., 80, 1571 from Boghead naphtha 159 155-162 Berthelot B. S. C. [2], 11, 3 iv., 2 vii., 422 155-160 Cloez C. R, 85, 1003 34, 482 155-157 Wurtz J., 16, 510 v., 1090 152 Lachowicz A., 220, 188 46, 166 Diisoamyl Me 2 CH.(CH 2 ) 4 .CHMe 2 155-159 i., 202 155 (728) Frankland 3,31 26, 679 157-1 Liquid Lachowicz A., 220, 168 46, 166 158 Wurtz A. C. P. [3], 44, 281 32, 260 158-159 Schorlemmer P. R S., 14, 172 159 Williams J., 10, 418 160 (751) Grimshaw 38, 261 Isobutyl hexyl (?) a-Methyl naphthalene Q - >, ,, - a- 0- &- !l Oolophthalin .... C 6 Hi 3 .CH 2 .CHMe 2 )) C 10 H 7 .Me' J JJ i ) >j jj j> CuH 10 j> 11 ?) j )j 155 155-160 155-160 230-232 230-232 230-231 231-232 242 242-243 400 1. 18 a. 18, a. 18 to 20 70 Wurtz Berthelot Ciamician jj Goldschmidt and Schidt Fittig and Remsen Emmedt and Rein- gruber Reingruber J., 8, 576 C. R, 67, 327 Ber., 11, 272 W. A., 83, 346 W. A. [2], 83, 7 A., 155, 114 A., 211, 365 A., 206, 375 J. [1874], 921 i., 97 v., 732 vi., 1111 34, 439 40, 247 40, 824 vi., 849; 4O, 824; 44, 1135 42, 733 40, 436 Pheuyl pentylene .... ^, ,j isopentylene Tolyl butylene Isopropyl cinnamene jj (polymer) Pentamethyl benzene ? Propyldimethyl benzene Propyldimethyl benzene (a- Laurene) Propyldimethyl benzene (|3- Laurene) Propyldimethyl benzene (Laurene) Diethylmethyl benzene Propylethyl benzene Butylmethyl benzene Isobutylmethyl benzene )> )i n Amyl benzene Isoamyl benzene ,, j> jj jj .... .... CH 3 .CH 2 .CHPh.CH : CH 2 Ph.C 5 H 9 C 6 H 4 .Me.(CH 2 .C 3 H 6 )=1.3 Pr".C 6 H 4 .CH:CH, J C 6 H.Me 5 JJ )> C 9 H 3 .Me 2 .Pr=1.3.5 =1.3.4 =1.2.4 = (0 C 6 H 3 .Me.Et 2 =1.3.5 C 6 H 4 .Et.Pr=1.3 C 6 H 4 .Me.C 4 H 9 =1.4 C 6 H 4 .Me.(CH.,,CHMe 2 )=1.3 =1.3 = (?) Ph.(CH 2 ) 4 Me Ph.CH.j.CHj.CHMej M jj ^11^14 ) jj ? j (OnH I4 ) n CnH, 6 u jj jj jj j> (see C 10 H 14 ) )J ) J) JJ J JJ Jt ) )) 173-177 210-215 200-5-201-5 195 195-200 203-204 230 215 225 206-210 190-191 184-186 188 198-200 193-195 176-178 186-188 185 190-195 200-5-201-5 (743) 193 195 193 Liquid Liquid Liquid Solid 8.0 13 50 Liquid Liquid Liquid Dafert Schramm jj Aronheim Perkin jj Ador and Rilliet Friedel and Crafts Jacobsen Reuter j> Fittig, Kobrick, and Jilke Jacobsen R6nard Kelbe and Baur j Effront Goldschmidt Schramm jj Tollens and Fittig Bigot and Fittig M. C., 4, 616 A., 218, 383 B., 9, 1790 B., 12, 332 B. S. C., 28, 147 C. R, 91, 257 B., 8, 1259 B., 16, 627 B., 16, 628 A., 145, 149 B., 7, 1434 C. R., 97,328; A. C. P. [6], 1, 223 B., 16, 2563 B., 14, 1240; 16, 2559 B., 17,419 B., 15, 1067 A., 218, 383 JJ A., 131, 313 A., 141, 160 44, 1094 44, 977 32, 401 32, 663 n 36, 527 40, 40 vi., 304 28, 259 46, 173, 844 46, 300 46, 900 44, 977 j) iv., 476 vi., 303 COMPOUNDS CONTAINING TWO ELEMENTS. 73 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. Amyl benzene 1 " " ) n ) )> ,, From betulin .... Ph.CHEt 2 Ph.CMe2.Et Ph.C 5 H n CgHjg.C .* CH CH 3 (CH 2 ) 9 .CH 3 ,CH C,oH,< II \CH ) C 6 H 6 .C 6 H 5 71 J> ) 1 I> JJ J >1 )> )* 5> ) 1 )) J? CH, *<5 )) )> )> CiiH 16 > ii > >j ^iiH ]8 > CnHoQ CuH^ i) u j> ) C n H M i Ji (C,"H 5 ) n C, 2 H 8 T> (Ci 2 H 8 ). Ci 2 H 10 jj j> j) j) j ) jj > u > j TJ I) n )i n 178-180 178 185-190 185-190 178 182-184 245-250 182 202-203 170-172 198-202 210-215 192-193 193-195 195-8 195-9 195-2 194-5 (760); 127 (100); 108-5 (50); 96-5 (30); 81 (15); 74 (11) 180-184 180-185 178-180 176-178 265-275 p. d. 101-102 240 254 250 243 245-258 238-5 257 285 c. 270-280 267-269 u. c. 277-5 c. Liquid Liquid Liquid 26-5 74 92-93 70-5 69 69 70 70 71 70-73 71-5-74-5 70 70 70 70-71 70 70 70-5 69-6 70 70 a. 100 99-100 94-96 05 Dafert Lippmann and Longuinine Essner Friedel and Crafts Paterno and Spica Weidel & Ciamician 3 Giesecke Warren Warren and Storer ? Krafft Pelouze & Cahours Amato Cloez Cahours & Demarfay Behr and Van Dorp Blumenthal Fittig List and Limpricht Riese Griess Schultz Richter Carnelley Berthelot Smith Merz and Weith Coste and Michaelis Carnelley Ladenburg Bronner Christomanos Goldschmiedt and Schidt Fittig & Ostermeyer Carnelley & Williams Berthelot Gnebe Behr and Van Dorp i* M. C., 4, 153, 616 B. S. C. [2], 8, 426 B.S.C.[2],36,212 C. R, 84, 1392 Z. C. [1867], 674 W. A, 4, 153 G. I., 7, 508 B., 13, 80 B., 13, 81 A, 199, 78 Z. C. [1870], 431 B., 8, 413 Z. C., 6, 431 A., 165, 23 J., 21, 330 Z.C. [1868], 231 ; J., 21, 332 Z. C,[1868], 230 ; J., 21, 332 B.,15,1697&1698 J., 16, 524 G. I., 2, 6' C. R., 85, 1003 C. R., 80, 1571 J. [1856], 889 ; J. [1869], 1248 A, 172, 263 ; B., 6, 753 B., 7, 1092 A. C. P. [5], 17, 43 A., 121, 363 A., 90, 209 G. J. C., 1872 P. T. [1864] [3] 692 A, 174, 201 J. p. C. [2], 28, 273 G. J. G, 1870 B., 10, 755 B., 11, 1884 G. J. C., 1871 G. J. G, 1869 G. I. [1875], 402 W. A., 83 [2], 7 G. J. C., 1879 33, 282 B. S. C. [2], 8, 226 B., 5, 16 B., 6, 60 A., 172, 263 44, 659, 1094 vi., 304 42,46 32, 725 34, 569 38,404 )> vii., 808 42, 127 iii., 181 26, 682 34, 482 27, 1168; 26, 1135 iv., 409 iv., 409 28, 148 46, 325 29, 19 )> 32, 552 32, 603 36, 161 37, 706 37, 760 40, 824 vi., 3 25, 295; vii., 834 26,1167;vii,,834 27, 1167 animal tar ) ?i i> /S-Paracotene .... Butylidene TJndecylene .... Undecane Acetylene naphthalene ) )> Petrocin Diphenyl .... .... :: :: :::: ::: Acenaphthene (etheiie naph- thalene) ) j> ">> 74 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Acenaphthene (ethene naph- CioH6 /j H ' Ci 2 H 10 94 Goldschmiedt and W. A., 83 [2], 7 40, 824 thalene) CH 2 Schidt Dimethyl naphthalene C 10 H 6 .Me 2 C 12 H 12 a. 265 p. d. 1. -18 Giovannozzi G. I. [1882], 147 42,855 ,1 262-264(751) Liquid Cannizzaro and G. I., 12, 393 44,79 Carnelutti isomeric 252-254 .... A., 211, 365 !> I! 260-262 JJ -Ethyl naphthalene C 10 H 7 .Et 250 .... Fittig and Remsen Z. C. [2], 5, 37 vi., 849 ~ it 100 (2-3); Carnelutti B., 13, 1672 40, 280 257-259-5 (757-7) a- 251-252 .... Fittig and Remsen A., 155, 119 40, 824 252-260 .... Goldschmiedt and W. A., 83 [2], 7 Schidt 251 Liquid Marchetti G. I., 11, 439 42, 410 Guajene 97-98 Botsch M. C., 1, 609 42, 211 100-101 Weiser W. A. [2 ab.], 464 40, 813 (?) hydride abt. 270 Berthelot Z. C. [1867], 714 vi., 3 Butenyl cinnamene Ph-CH : CH.C 4 H 7 C 12 H 14 245-248 Perkin .... 35, 142 (?) 5 , abt. 69 Berthelot A.C.P.[3],15,150 36, 376 Isopropyl allybenzene Pr0.C 6 H 4 CH I CH.Me C 12 H 16 229-230 1. 15 Perkin .... 32, 664 (?) ... 222 .... B., 9, 12 Hexamethyl benzene C 6 Me 6 C 13 H 13 230-240 136 (163 ?) Hoffmann B., 5, 721 25, 1024;vii.,59 >. 259-260 150 Le Bel and Greene C. R, 87, 260 36, 50 u 260 150 Ador and Rilliet B., 12, 332 36, 527 ,, >, H 150 .... D. P., 237, 146 38, 864 I! ., 258-260 150 Reichardt B. C. [1880], 559 38, 865 250 160 .... J. R, 13, 392 _ 25S 163 Hoffmann B. 13, 1729 40, 260 ,, M 264 164 Friedel and Crafts C. R, 91, 257 40,40 Triethyl benzene Etj. =1.3.5 ,, 217-220 .... Jacobsen B., 7, 1435 28, 259 214-218 .... Friedel and Balsohn B. S. [2], 34, 635 40, 259 Dipropyl benzene Pr. Pr =1.4 220-222 Liquid Korner B., 11, 1863 36, 142 218-220 Liquid A., 216, 223 44, 321 Propylisopropyl benzene Pr0.Pr0 =1. ? 205-208 Paternd and Spica G. I., 6, 99 31, 77 , =1-4 211-213 c. B., 10, 1746 34, 139 (754) Isoamylmethyl benzene Me.(CH 2 .CH 2 .CHMe.,) =1-2 203-205 u. c. 1. -20 Pabst B., 9, 503 =1-4 213 b. 20 Bigot and Fittig A., 141, 162 vi., 304 Amylmethyl benzene Me.C 6 H n = ? 213-218 .... Etard C. R, 97, 909 46, 312 Isohexyl benzene Ph.(CH 2 ) 3 .CHMe 2 214-215 Aronheim A., 171, 223 27, 689 ^ 212-313 Schramm A., 218, 383 44, 977 Ethyl (or ethylene) cymene C 6 H 3 .Et.Me.Pr. or 185-190 .... Landolph C. R, 86, 1267 34, 721 C 6 H 4 Me(C 2 H 4 .Pr) a-Paracotene .... .... 160 A., 199, 77 Cyneue .... fft 173-175 Volckel A. P., 89, 358 ii., 299 Eucalyptene . .... .... See C 10 H 16 165 Cloez A., 154, 372 vii., 494 Eucalyptolene u a. 300 .... JJ H (?) .... 215 Z. C. [1866], 223 From betulin .... 250-255 Franchiniont and B., 12, 9 36, 469 Wignaan Ethel terpene (eterpene) Ci H 16 .Et. CiaHja 153 u. c. 63-5 Meyer and Spitzer B., 9, 880 30, 515 camphene 197-9-199-9 c. Liquid Spitzer B., 11, 1817 36, 168 (742-1) From acetone H 170-180 .... .... A., 140, 301 allyldimethylcarbinol .... 196-198 1. in i. m. Nikolsky & Saytzeff J. p. C., 27, 380 44, 1074 carbazolin .... jj 225 A., 163, 356 ,, animal oil .... 210 A., 139, 245 Naphthol (?) C H 190 B. J., 21, 473 From diallyldihydriodide .... .... B 190-200 Wurtz B. S., 2, 164 vi., 94 COMPOUNDS CONTAINING TWO ELEMENTS. 75 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. From anethol (Wright) / /CH 2 -CH 2 \ x V CH '\CH 3 -CH/ ~h CuHjj 210-212 208-3-214-6 c. Landolph Warren and Storer C. R, 82, 849 Z. C. [1868], 231 30, 79 212-6 c. Z. C. [2], 4, 230 vi., 547 216'2 Warren J., 21, 330 96 (15) 31 Krafft B., 16, 3018 46, 572 Isomeric (?) 193-197 A., 195, 262 (?) 196-199 Triisobutylene M 173-176 174-176 Butlerow and Gor- gainon Dobbin B., 6, 561 ; A., 169, 196 26, 873; 27, 138 37, 240 177-5-178-5 37, 241 174-178 37, 246 (Me 3 C) 2 C I CMe. 177-5-179 Liquid Butlerow B., 12, 1482 38, 230 (749) 180 Puchot A. C. [5], 28, 507 46, 167 (?) . Duodecane Me.(CH,) 10 .Me j 170 S14-5 (760) ; 12 Brazier & Gossleth Krafft B., 15, 1698 ; B., iv., 177 42, 1271 ; 44, 145-5 (100) ; 126 (50) ; 113-8 (30) ; 98 (15) ; 90-5 (11) 202 Schlorlemmer 16, 1714 P. E. S., 16, 367 1076 24, 896 ; vii., 195-198 Cloez C. R, 1003 891 34, 482 196-200 Pelouze & Cahours J., 16, 524 iii., 181 ; vi., abt. 200 Cahours & Demarjay C. E., 80, 1571 547 201 Schorlemmer A., 161, 277 202 Brazier & Goosleth J., 3, 400 202 Wurtz A. C. [3], 44, 275 iii., 151 ; iv., 202 Schorlemmer P. T. [1872], 111 25, 1085 ; vii., 202 Williams J., 10, 418 645 o-Methylene diphenylene (fluorene) a - r - M )> - P~ 5) V P" )) M- >) IJ ?-Methylene diphenylene (?) y~ v y~ > t- ,, - (?) 8- Benzhydrolene Sequoiene CeH 4 \ i >CH 2 C 6 H/ ) J) )i jj 5T I 11 i ) C 6 H 4X 1 >H 2 C 6 H/ ClS^lO M 1 l, J )) (?) l )) )) (?) )3 )> 300-305 29^-395 290-310 abt. 305 300-305 295 8SO 290-300 u. c. 113-114 113-113 113-114 112-113 113 113 113 118 118 124 199-200 205 u. c. ; 208 c. 209-210 105 Grsebe & Gebhard Fittig and Schmitz Fittig Grsebe Barbier Hodgkinson and Matthews Berthelot Barth and Gold- achmiedt Carnelley Hodgkinson and Matthews Hodgkinsou and Matthews Sfeedel Carnelley Linnemann Luncre & Steinkauler A., 174, 194 A., 193, 134 B., 6, 187 B., 7, 1624 A. C. [5], 7, 472 ; C. R, 77, 442 43, 164 A. C. [4], 12 ; 222 B., 11, 847 37, 708 43, 164 B., 6, 189 37, 710 A., 133, I B., 13, 1657 ; 14, 37, 717 26, 755 28, 455 31, 71 ; 26, 1226 vii., 524 34,734 26, 755 iv., 48(1 40, 98 2203 76 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. From a-Benzopinacolin C, 3 H 10 243-244 Thorner and Zincke B., 11, 1397 34,874 Ca-phthalate 5J 243-244 Miller B., 12, 1489 38, 255 Diphenylmethane (benzyl CH 2 .Ph 2 C J3 H 12 261-262 24-25 Zincke B., 4, 299 24, 508 ; vii., benzene) 183 11 ., 26-4 Jene A., 155, 86 vii., 158 11 ?! TJ w 255-265 Stredel B., 6, 189 26, 755 11 11 261-262 Grsebe B., 7, 1630 28, 454 11 11 260 Friedel and Crafts C. B., 84, 1450 32,864 )1 11 263 26 Stsedel A., 194, 253, 307 36, 318 11 11 261 26 Engler B., 11, 927 11 11 i) 200-300 Fischer A., 194, 242 36, 384 Tolylphenyl (phenyltoluene) C 6 H 4 .Me.Ph =1.2 255-260 Liquid Barbier A. C. [5], 7, 472 31, 74 11 11 11 11 258-260 Liquid 11 B., 7, 1548 29, 13 11 11 =1.4 263-267 u. c. 2 to 3 Carnelley 29, 18 i> 11 11 11 TT 263-268 11 37, 707 Isopropylbutenyl benzene (|3) C 6 H 4 Pr0.C 4 H 7 C 13 H 18 234-235 Perkin .... 35, 141 11 >i 11 JT 242-243 Liquid 11 32, 665 Dipropylmethyl benzene .... C 6 H,.Pr I , 232-7 c. J., 21, 332 Tridecane M fPTI "1 M P TT "?/, I7fin\ Q-2 Krafft B., 15, 1699 42, 1271 lYL6,^\^.tl-2/ll* ^* VI**J8 rZOJf {1 W J 142-5 (50) ; 130 (30) ; 114 (15); 106-5(11) 11 .... 218-220 Pelouze & Cahours J., 16, 524 iii., 181 ;v., 880 .... TT 215-220 .... Cloez C. B., 85, 1003 34, 482 Phenanthrene C 6 H 4 .CH C 14 H 10 Much a. 300 97-99 Fittig & Ostermeyer B., 5, 934 25, 177; vii., 85 C 6 H 4 .CH 339-342 98-99 Schmidt B., 7, 206; 12, 27, 581 1159 11 340 c. 100 Grsebe B., 5, 861 ; 7, 48 26, 175; vii., 85 , t 11 96 Limpricht B., 6, 532 26, 897 11 .... 100 Goldschmiedt and W. A., 83, 7 40, 824 Schidt ^ 11 100 Hayduck G. J. G, 1873 ! 96 11 B., 7, 1090 11 11 96 Ostermeyer 11 n 11 98-100 11 11 11 .... 95-96 Japp 37, 410 11 96 11 .... 11 ,. ..** .... TT 11 96 Japp and Wilcock 37, 664 11 .... 97-5-98 11 i. 37, 670 *> **** *"** V 11 .... 101 Carnelley 37, 711 n N 100 Anschutz & Schultz G. J. C., 1879 / CH \ 6"^4\ 1 / 6^^4 213-3 Anderson 15, 44 iv., 350 .... .... \/"irr/ 11 a. 300 180 Dumas and Laurent A. C. [2], 1, 187 n 210 Fritzche A., 109, 249 11 11 210-212 11 J. [1867], 600 vi., 177 abt. 360 213 Grsebe & Liebermann A. s., vii., 257 i 210-212 Grimm B., 6, 506 26, 1235 339-359 212-5 Carnelley & Williams 33, 283 213 Goldschmiedt and W. A., 83, 7 40, 824 Schidt 208 Henzold J. p. C., 27, 518 44, 1137 COMPOUNDS CONTAINING TWO ELEMENTS. 77 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Anthracene .... CH C 6 H 4 ) J) isomeric OgJrljj.O i O.Og-fclj C H H 10 .H 2 Ph.CH : CHPh. ? J ) ) J U JJ J )J J JJ CH 2 :CPh 2 JJ C 6 H 4 .CH 2 .C 6 H 4 CH., or i " i C H H 10 > jj i) )> )> j> ? j n (C 1 ' 4 H 10 ) n (C 14 H n ) n C 14 H 12 i (?) si ? n H i ) ? jj i j 5> orC^H,, (C 14 Hi 2 ),, C l 4 Hl4 )! )> >! ) 275-300 252-295 a. 360 305 313 abt. 292 265 300-302 306 306-307 277 274-276 abt. 260 260 284 282 208 208 213 212-213 133-5-134-5 247 244 189-195 193 59 60 88 s. f. 65-70 189-190 145 abt. 100 106 107-108 106-108 108 100 + abt. 116 115-118 119-5 ISO 120 120 120 121-122 124 124 124 125 Liquid Liquid Liquid Liquid abt. 90 190 51-5-53-5 48-50 50 52-5-53-5 51-52 52 52 Claus Kireher Perkiu&Hodgkinson Weber and Zincke Schmidt Hanhart Limpricht and Schwanert Rembold >i Honig and Berger Kekuleand Franchi- mont Schlitzenberger Grsebe & Liebermann Liebermann Liebermann & Topf Laurent Perkin&Hodgkinson Wurtz Limpricht Fittig Williams Drehner and Otto Jena and Limpricht Forst and Zincktj Michaelis & Lange Eeimer Paal Howard Klinger Forst Grasbe Hepp Demole Jena and Limpricht Borthelot Baeyer Hepp Camiizaro & Rosse Limpricht and Schwanert Limpricht Goldenberg Wurtz Ekstrand Reimer Breuer and Zinckfi B., 8, 530 B., 17, 1168 B., 7, 1156 B., 5, 931 ; 6, 494 B., 6, 494 A., 191, 298 A. C. [5], 7, 526 ; J. [1868], 404 B., 15, 900 A., 145, 347 B., 8, 1494 B., 8, 1496 M. G, 3, 670 C. R., 75, 1767 Z. F. G, 13,257 A., 212, 5 A. s., 7, 265 ; C. R., 79, 764 B., 9, 1202 R. S., 16, 373 A., 7th Supp., 54 A., 139, 303 A., 139, 178 C. N., 15, 244 G. J. G, 1870 IJ G. J. G, 1876 G. J. G, 1875 B., 14, 1805 B., 15, 1819 G. J. G, 1877 G. J. G, 1875 B., 7, 1629 B., 7, 1409 B., 12, 2245 A., 155, 91 B. S. [2], 9 B., 6, 222 B., 7, 1409 J., 14, 548 A., 145, 380 J., 19, 593 A., 174, 333 A., 7th Supp., 54 B., 9, 855 B., 14, 1805 A., 198, 141 28, 891 37, 726 37, 727 28, 156 26, 176; vii., 85 26, 1234 ; vi., 177 vi., 1099 29, 592 44, 68 26, 172 vii., 1163 vi., 177 42,855 31, 86 v., 432 37, 721 vi., 1107 ,, vii., 169 28, 455 28, 361 38, 158 vii., 16!) 26, 885; vii., 533 28, 361 v., 870 vi., 334, 1107 28, 365 30, 514 38, 118 Isoanthracene ,, Paranthracene Synanthrene (phosene) ,, Tolane From chloroform and naph- thalene (') (?) Anthracene dihydride i> jj Stiibene .... .... (ft * Diphenylethylene (2) (?) From diphenylmethane and methylal (?) Dibenzyl ~ (Ph.CH 2 .C 6 H 4 ) 2 CH 2 Ph.CH 2 .CH 2 .Ph 1) )> ) ) : ... (impure) ; : 78 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Dibenzyl Ph.CH 2 .CH 2 .Ph 52 Hanhart B., 15, 900 52-53 Paal B., 15, 1819 272 Fittisr A., 139, 178 276-277 52-5 Silva C. R., 89, 606 38, 260 Diphenylethane > j> 1) >, Benzyltoluene j ,, ,, j (?) Ditolyl CH 3 .CHPh 2 |) J7 )1 )) C 6 H 4 .Me.CH 2 Ph =1.3 =1-4 15 > > )) " )> = (?) Me C 6 H 4 C 6 H 4 Me (1 4) 2 )> )j >i u > M j Jl 5) ! J 268-271 268-270 264-266 286 150 (16) 275 c. (747) 268-269-5 (725) 277 279-380 c. 275-280 282 285-286 c. 283-286 170 283-288 Liquid Liquid 1. -10 1. -17 1. 17 Liquid Liquid 1. f. m. 121 Goldschmiedt Radziszewsky Thbrner & Zinck6 Haiss Angeblis and An- schutz Senff Ador and fiilliet Zinckfi v. Dorp Behr and v. Dorp Barbier Bertholet Zincke B., 6, 1502 B., 7, 142 B., 11, 1990 B., 15, 1481 B., 17, 165 A., 220, 225 B., 12, 2300 B., 4, 298 A., 161, 93 B., 5, 1071 B., 5, 1070 B., 7, 19 B., 7, 1544 B., 4, 397 27, 370 27, 469 36, 317 42, 1071 46, 753 46, 427 24, 508 vii., 183 vii., 82 26, 500 27, 471 vii., 82 24, 510 ; vii., 117-119 Lononinine B., 4, 515 1179 24, 684 121 Doebner B., 9, 272 29, 914 283-288 119-120 Carnelley 32, 654 ( ? ) 91 Schultz B., 17, 472 46, 903 1.2 ; 1.4 272-280 Liquid Carnelley 37, 707 270-290 Liquid 32, 654 277-282 Liquid Lonsuinine B., 4, 515 24, 685 (1) 283-288 Liquid Zincke B., 4, 399 24, 510 ; vii., BB'ffl 280-285 Barbier C. R., 79, 121 1179 27, 1091 =1.3; l.(?) (?) 280-281 273-278 Liquid Schultz Zinck6 B., 17, 468 B., 4, 400 24, 510; vii., (1'2). 272-277 u. c. Liquid Longuiniue B., 4, 515 1179 24, 685 ; vii., 272 Liquid Fittig A., 139, 178 1164 24, 510 ; vii., (?) 270-280 Grsebe B., 7, 48 1179 27, 471 1.3:1. (?) 270 Schultz B., 17, 471 46, 903 PL C 6 H 3 Me^ 270-280 Barbier A. C. [5], 7, 472 31, 76 ,, .... .... Tetrahydrophenanthrene ... i) From bixin .... si ) 283-286 300-310 abt. 310 270-280 Liquid cryst. b. Liquid Grsebe 5 Etti C. R, 69, 660 A., 167, 131 B., 8, 1056 B., 11, 868 28, 62 26, 896 ; vii., 85 29, 70 34, 739 (?) From dioxyretistene Anthracene hexydride > I'henanthreue octohydride ... Tetrethyl benzene Dihutyl benzene From lactucone o ( Metliylpropylally Iene) 2 Diheptine , . C,H,.Et 4 =1.2.3.5 C C H 4 .(C 4 H 9 ) 2 (C r H 12 ) 2 I> CuH 16 CHH,, C 14 H,,j i )! C 14 H 24 283-286 c. 290 b. 300 251 230-240 247-252 320-330 245-247 235-240 56-57 63 63 Liquid 1. 20 Barbier Ekstrand Grsebe and Lieber- mann Liebermann Grsabe Galle Goldschmiedt Franchimont and Wignann Schiff Morris Renard C. R., 79, 660 A., 185, 75 Z. F. C., 13, 257 A., 212, 25 A., 167, 131 B., 16, 1745 B., 15, 1067 B., 12, 11 Z. C., 6, 75 C. R., 91, 419 28, 62 32, 499 vi., 176 42, 857 26,896; vii., 85 44, 1092 36, 469 vii., 869 41, 174 38, 894 235-240 Tilden 45, 419 fsobutyl camphine C 10 H 15 .C 4 H 9 9 228-229 c. (750-4) Liquid Spitzer B., 11, 1818 36, 168 COMPOUNDS CONTAINING TWO ELEMENTS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. From camphic acid C 14 H 24 215 .... Montgolfier A. C. [5], 14, 5 34, 897 animal oil 240 .... A., 139, 245 (?) .... C 14 H 26 245-260 .... Schiff Z. C., 6, 75- vii., 869 Heat on petroleum Caucasian C^H^ 230-232 Schutzenbergerand C. R., 91, 823 40, 706 245-247 Lin n id lonine Tilden B., 13, 1604 41, 174 Tetradecylene Xetradecane * .... .... Me.(CH 2 ) 12 .Me C 14 H 30 127 (15) 252'5 (760) ; 12 4-5 Krafft B., 16, 3021 B. 15 1700 46, 572 42, 1272 178-5(100); 158 (50) ; 145-5 (30) ; 129-5 (15); 122-5 (11) 236-240 Pelouze & Cahours J., 16, 524 iii., 181 From cast iron " 234-238 S. Cloez C. R. 85 1003 34, 482 Myristyl hydride I 236-240 iii., 1073 (0 240 .... B. S., 8, 239 (?) .... 250 Barbier C. R., 79, 121 27, 1092 Fluoranthene (idryl) C 6 H 4 .CH.CH C 15 H 10 250-251(60); Fittig & Liepmann A., 200, 1 38, 400 1 / II C 6 H 3 CH 217 (30) 33 110 Goldschmiedt B., 10, 2028 34, 155 13 33 a .... 109 Fittig and Gebhard B., 10, 2142 34, 431 3 109 33 3 A., 193, 142 36, 166 From fluoranthene Succisterene .... " 309-311 a. 300 d. Liquid 160 Goldschmiedt W. A., 81, 415 A. C. [3], 9, 96 40, 284 Fluoranthene dihydride C 15 H 12 76 Goldschmiedt M., 1, 225 40, 283 Methylanthracene 178 Sadler & McCarter A. C. J., 1, 30 40, 1129 C 6 H 4 :C 2 H 2 :C 6 H 3 Me a. 360 190 Japp and Schultz B., 10, 1050 32, 624 .... 190 Ciamician B., 11, 273 34, 439 n .... 199-200 Liebermann A., 183, 163 31, 611 200 Fischer B., 7, 1196 ? 198-201 Weiler B., 7, 1186 28, 152 .... 203 Bornstein B., 15, 1822 44, 71 205 Liebermann B., 8, 970 29, 251 . .... 208-210 Wachendorff and B., 10, 1485 34, 232 ZinckS Methanthrene .... a. 360 117 Oudemanns B., 6, 1127 27, 73 Methylauthr.icene dihydride C, 5 H 14 .... 100 Roemer and Link B., 16, 703 44, 1138 Phenyltolylethylene Ph.CH : CH.C 6 H 4 Me = 1.4 117 Mann B., 14, 1646 40, 1035 Diphenyldimethylmethane .... CPh 2 Me 2 (?) C 15 H 16 281-282 .... B. S., 34, 674; 35, 289 Dibenzylmethane CH 2 (CH 2 Ph) 2 31 a. 300 Liquid Plascuda B., 7, 986 28,74 a. 300 1. 20 Merz and Weith B., 10, 760 290-300 1. f. m. Grabe B., 7, 1627 28, 457 ii 33 290-295 Claisen&Claparede B., 14, 2466 42, 512 Diphenylpropane C 3 H 6 Ph 2 277-279 Liquid Silva C. R., 89, 606 38, 259 Phenyltolylethane Ph(CH 2 ) 2 .C 6 H 4 Me - 1.4 278-280 Bandrowsky B., 7, 1016 28, 62 J > 286 27 Mann B., 14, 1646 40, 1034 Ditolylmethane CH 2 (C 6 H 4 Me) 2 .3> 285-5-286-5 22-23 Ador and Rilliet B., 12, 2302 280-285 Liquid Schwarz B., 14, 1530 ,, 289-291 u.c. 1. 15 Weiler B., 7, 1182 28, 151 nzylethyl benzene Ph.CH 2 .C 6 H 4 .Et = 1.4 294-295 c. Liquid Walker B., 5, 686 25, 1004 ; vii., (754 r.) 184 Benzylxylene Ph.CH 2 .C 6 H 3 .Me 2 283 Mixture (?) Blatzbecker B., 9, 1761 31, 469 Me.Me= 1.3 Ph.CH 2 .C 6 H 3 .Me 2 290 Sollcher B., 15, 1682 42, 1292 Me.Me = 1.3 Ph.CH 2 .C 6 H 3 .Me 2 295-296 c. Liquid Zincke B., 5, 799 26, 272 Me.Me = 1.3 Ph.CH 2 .C 6 H 3 .Me 2 293-5-294-5 Liquid Me.Me = 1.4 80 ORGANIC COMPOUNDS. "V. '.'!.;, Name."'"- - '' Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Fluoranthene octohydride .... .... c i 5 Hi 8 309-311 M., 1, 226 a-Amylnaphthalene C 10 H 7 .(CH 2 .CH,CH.Me 2 ) 303 Leone G. I., 12, 209 42, 1210 (3- 304-306 Patern6 G. I., 12, 337 42, 1210 ; 44, 212 (?) 245 B. S., 37, 303 From clove oil .... C 15 H 2a (?) 250-260 Beckett and Wright 29,7 sandal wood oil CloH.,2 248 Chapoteant B. S. [2], 37, 303 44,76 cedar oil JI 248 ;) Jl Sesquiterebene .... 55 250 Berthelot J., 15, 457 v., 924 Metatemplene Cl 5 H24 280 Fluckiger J., 8, 646 Petrolene 280 Boussingault (?) (?) Trivalerylene .... 265-275 Eeboul V / J., 20, 585 \ / vi., 1124 11 240-250 B. S., 33, 24 Patchoulin i) 252-255 c. Montgolfier C. E., 84, 88 31, 478 )i (743) Cedrene .... n 237 .... A., 39, 249; 48, 37 249-260 Gladstone 25, 1 26, 563 250-260 J 26, 972 si 260 Muir 37, 680 Heveene 255-265 Bouchardat B. S. [2], 24, 108 29, 86 Conimene j> 264 Stenhouse& Groves A., 180, 253 29, 175 Para-copaiva oil .... u 252 p. d. Posselt A., 69, 69 J., 2, 455 From copaiva.... 250 Soubeiran & Capi- j taine maracaibo balsam .... 250-260 Strauss J., 21, 795 gurgun balsam .... ji 255 Werner J., 15, 461 ,, drybalanops camphora .... ?j 255-270 .... Lallemand J., 12, 503 cascarilla oil .... ) 254 Gladstone 17,1 patchouli oil .... i 254 >j )j .... i) 257 v )> n j, .... )i 260 IT cubebs oil .... i> 220-250 J. [1870], 190 * .... )) 250-260 .... ii., 172 > )> .... 262-263 B., 8, 1357 !> > " "" .... > 264-265 .... Oglialora G. I., 5, 469 30, 643 .... 250-260 Schmidt B., 10, 189 32, 345 >J J) ,, .... .... .... ) 260 Gladstone 17,1 cedar oil .... M 252 .... 25,6 vitivert oil .... > 255 ) clove oil .... 5) 247-250 u. c. .... Church J. [1876], 398 28, 114; 29, (i 253-9 c. ,, .... 142-143 Ettling Watts' Diet. > .... 249 Gladstone 17,1 V 7> V " " .... 251 .... Williams J., 11, 442 sandal-wood oil .... ) 260 .... Chapoteant B. S. [2], 37, 303 44, 76 rosewood oil )1 249 .... Gladstone 17,1 calamus oil .... 260 ? ) " .... .... 255-258 Kurbatow A., 173, 1 laurus nobilis .... 250 .... Bias J., 18, 569 ,, sage oil.... abt. 260 Muir 37, 679 hemp oil .... ) 256-258 Liquid Valente G. I., 10, 479 40, 284 myrtus pimenta )) 255 .... CEser J., 17, 534 iv., 647 , salviol .... .. . 264-271 Ligiiira and Muir 33, 297 (?) .... J) 249-260 .... Gladstone 25, 6 santonic acid .... Ci6H 2S 110-112 (5) Cannizzaro & Amato B., 7, 1104 28, 163 235-245 ; (o. p.) Quindecone .... 220 A., 147, 255 (?) j) j 248-252 Gal C. E., 68, 408 vi., 902 Pentadecine .... CisHjs 230-240 Liquid Bauer A., 137, 249 vi., 903 COMPOUNDS CONTAINING TWO ELEMENTS. ^> L'NIVEUSITY 81 Name. Constitution. Formula. Boiling Point. Melting Point. \X Authority. SfcQL|fpRNl^> ''watt's Diet. & J. Ch, Soc. Oie-lino 223-228 Bauer and Verson A., 147, 252 ; J., 15"^2S 1,337 Triamylene Oic-tL^/i 245-248 Bauer J., 14, 660 vt., 122 Me.(CH 2 ) 13 .Me la 30 Olt-tLno 270-5 (760) ; 10 Krafft B., 15, 1701 42, 1272 \ i/\& V 15 32 194 (100) ; 173 (50) ; 160 (30) ; 144(15); 137 (11) 255-260 Pelouze & Cahours J. [1863], 530 ill., 181 JJ 258-262 Liquid J., 16, 524 vi., 903 ,, .... From cast iron )> 258 Cloez C. R, 85, 1003 34, 482 Diacetenylphenyl FLO ; c.c ; c.ph 51 Cl 6 H 10 97 Glaser A., 154, 159 Pyrene (phenylenenaphtha- C JO H 6 : C 6 H 4 s. a. 360 142 Greebe Z. C. [2], 7, 22 ; 24, 118, 690 ; lene) A., 158, 285 vii., 1027 )} ., .... .... .... 148-149 Fittig and Gebhard B., 10, 2143 34, 432 .y Jl ' "' .... 149-150 Goldschmiedt and W. A., 83, 7 40, 824 Schidt ,) ?i .... i 148-149 Hintze G. J. C., 1877 11 5> .... .... 147-149 Goldschmiedt and M. C., 4, 237 44, 1003 Wegschneider 51 .... 149 Smith and Davies 37, 413 ) )1 260 (60) Fittig & Liepmann A., 200, 1 38,400 )1 )> .... J .... 170-180 Laurent A. C. [9], 66, 136 iv., 754 (?) .... C 16 H 10 or .... 181-186 Ador and Crafts C. E., 88, 1355 36, 940 C 18 H 12 Phenyl naphthalene C 10 H 7 .Ph Ci 6 H 12 95-96 c. Smith B., 12, 2051 38, 125 tt n 101-102 )) B., 12, 1396 38, 262 ,, 11 tt 101-102 c. Smith & Takamatsu 39, 549 11 11 11 tt a. 340 Grsebe B., 6, 66 it 1} !> 104-105 11 B., 7, 782 27, 989 Pseudophenanthrene .... .... 115 A., 191, 295 From coccinin .... 186-187 Fiirth B., 16, 2170 46,84 carmin .... :> 186 ii B., 16, 2171 Jl carminic acid .... .... j 183-188 Liebermann & v. A., 163, 112 25, 706; vii., Dorp 368 Diphenylbutine PhC . CH 345-346 101-101-5 Breuer and Zinck6 B.,11,1403,1995; 34,890 HC .CPh B., 14, 1896; A., 216, 301 Atronol Crr onr oofi/i 1 IS T^ittifr A 9f)fi "S9 Aft 49 16^14 OZO OZOC. I. lo J? 1 1 LIL^ rl ., ' " >, ' ^tWj '.\J Dimethylanthracene MeC 6 H 3 :C 2 H 3 :C 6 H 3 Me )) abt. 200 Van Dorp B., 5, 676; A., vii., 84; 27, 63; 169, 207 25, 1006 n 210-220 Senff A., 220, 225 46, 427 C 2 H 2 jC 12 H 6 Me 2 !I 224-225 Wachendorff and B., 10, 1482 34, 232 Zinck6 (?) .... t) 280 Sadtler & McCarter A. C. J., 1, 30 40, 1129 Ethylanthracene ^64 " ^2 " " ^64 tt 60-61 Liebermann & Tobias B., 14, 803 40, 737 ,, ij tt .... 60-61 Liebermann A., 212, 109 42, 863 Ditolylacetylene Me.C 6 H 4 .C!C.C 6 H 4 .Me tt .... 136 Goldschmiedt and B., 6, 1505 27, 371 Hepp From isatropio acid .... .... tt 320 Fittig B., 12, 1739 38, 120 acetophenone .... .... tt 49-49-5 Thorner & Zinck6 B., 13, 645 Pyrene hexhydride .... .... Ci 6 H 16 127 Grasbe A., 158, 296 24, 691 ; vii., 1028 Ethylenedibenzyl Ph^H^C^.CHICHj tt 287-295 Bernthsen & Bender B., 15, 1984 Dimethylstilbene .... (1.4) 2 Me.C 6 H 4 .CH : CH.C 6 H 4 Me I! a. 300 176-177 Goldschmiedt and B., 6, 1504 27, 371 Hepp Ethylstilbene PhCH:CH.C 6 H 4 Et = 1.4 II .... 89-90 Sollscher A B., 15, 1681 42, 1292 Ditolylethylene CH 2 :C(C 6 H 4 Me) 2 11 304-305 Liquid Hepp B., 7, 1413 28, 361 Distyrene 310312 Fittiff B., 12, 1743 38, 121 II 11 " 11 s. a. 300 p.d. Liquid Krakau B., 11, 1260 11 .... 11 a. 300 p.d. .... Erlenmeyer A., 135, 122 82 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference, Watts' Diet. & J. Ch. Soc. Ph.CH(CH 2 ) 2 .CHPh (?) CieHlG (?) )> J) ? u C 16 H 18 jj D ) u i j ji Ci 6 H 24 Ci 6 H 26 Ci 6 H 2S ^16^30 C 16 H 32 (?) 5) J) )> >1 n 5) ^16^34 )> I) ) )> ) )) )1 C 17 H 14 i Ci;H 18 C 17 H 20 ? 11 310-312 u.c. 320 c. (o.d.) 291-292 (570) 320-323 296 297-300 295-298 293-295(rS3) abt. 300 293-295 300-303 293-297 290-295 248 260-270 260 280 280-285 250 d. 275 274 275 154-155 (15) 283-285 280 287-5 c.(7 60); 208-5 (100) ; 187-5 (50) ; 174 (30); 157-5(15) ; 151 (11) abt. 280 278 276-280 278 277-279 263 270-280 320-350 330-340 345 315 296-297 308 310 Liquid 117 119 Liquid 178-179 Liquid Liquid Liquid 1. f. m. 127-5-128-5 123-5 124 31 125 1. 20 25 4 41-42 18 21 14 19-20 Liquid 64 58-6 59 55 83-84 60-5 Erdmann Engler aud Leist Radziszewsky Liebermaim and Laudshoff Liebermaim Angeblis and Anschutz VoUrath Friedel & Balsohn Fischer Haiss Groebe Thorner and Zincke Engler and Bethge Radziszewsky Sollscher Louise Jacobsen Oliveri Fittig, Ahrens, and Mattheides Walter Austin Renard Chydenius Bouis Dumas and Peligot Lasareuko Chydenius Krafft Berthelot Krafft Pelouze & Cahours Schorlemmer Cloez Zincke' Eichler Lachowicz u Berthelot Prot6 Miguel Vincent and Roux 11 11 Michael Friedel, Crafts, and Ador A., 216, 187 B., 6, 256 B., 6, 494 B., 14, 457 A., 212, 78 B., 17, 165 Z. C. [2], 2, 489 B. S. [2], 35, 52 B., 7, 1193 B., 15, 1474 B., 7, 1627 B., n, 1990 B., 7, 1127 B., 7, 142 B., 15, 1681 C. R., 95, 1163 B., 14, 2112 G. I. [1882], 158 B. S. [1868], 464 A. C. [3], 1,498 B. S. [2], 32, 12 A. C. [6], 1, 223 A., 139, 246 A., 143, 268 A. C. [2], 624 B., 7, 125 A., 143, 267 B., 16, 3018 A., 136, 265 B. S [2], 9 B., 15, 1702 ; B., 16, 3022 C. R., 57, 62 P. R. S., 16, 367 C. R., 85, 1003 A., 152, 16 B., 12, 1882 A., 220, 168 ) B. S. [2], 9 C. R., 76, 639 B. S. [2], 25, 2 B. S. [2], 40, 163 11 A. C. J., 1, 312 J. [1878], 402 )) C. R., 88, 880 44, 475 40,609 42, 862 46, 753 v., 8(i!) 40, 260 28, 155 42, 1071 28, 457 36, 318 28,65 42, 1292 44, 323 42,188 42, 853; 45, 150 42, 853 i., 818 38, 107 46, 844 vi., 421 iv., 172 i., 838 vi., 421, 710 46, 572 vi., 741 42, 1272 vi., 421 24,896;vii.,891 34, 482 vi., 877 38, 229 46, 166 11 vi., 741 26, 891 30, 407 46, 609 11 40, 1150 36, 713 (?) ... C^C-ftEtrCeH, )) C 6 H 4 .CHMe.C B H 4 .CH.Me Ethylanthradihydiide ,, Dimethylanthracenedihydride Ditolylethane ,, ,, .... .... Dibeiizylethane (?) Diphenylethylmethylme- thane Dimethyldiphenylethane .... 11 Ethyldibenzyl Benzylmesitylene Dixylyl (CH^C^.Me), =1.4 ; 1 3 Me.CH(C 6 H 4 Me),, =(l-4) 2 MeCH(CH.j.Ph) 2 CPh 2 EtMe CHPhMe.CHPhMe )) Ph(CH 2 ) 2 .C 6 H 4 Et=l-4 C 6 H,j.Me 3 .CH 2 Ph =1.3.5.6 (C 6 H 3 Me 2 ) 2 = (1.2.5) 2 = (?-1.3) 2 = (?.1.3) 2 C 6 H n .C 6 H 11 =1.3(?) .... Prom azelaic acid Me.(CH 2 ) 14 .Me 11 11 From cast Pe C 8 H 17 .C 8 H 1? 11 11 Secondary C 10 H 7 .CH 2 Ph C 10 H 7 .CH 2 Ph Pr0C 6 H 4 CH:CHPh C 6 H 3 .Me.Pr.CH 2 Ph ) C 6 H.Me 4 .CH n Ph Cedrene Diisoamyl benzene .... Dioctene From animal oil .... Mn Cetine Metaoctylene ... Cetene Polyethylene .... Hexadecane ,, Benzyliiaphthalene .... a-Benzylnapthalene 0- Isopropyl stilbene Benzylcymene Benzylduryl .... COMPOUNDS CONTAINING TWO ELEMENTS. 83 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Heptadecane .... Me.(CHj) 16 .Me ( i , - 1 [ .... 303 (760) ; 22-5 Krafft B., 15, 1687 42, 1272 V I/ 36 223 (100) ; 201-5 (50); 187-5 (30) ; 170- (15) ; Chrysene 163-5 (11) 275 Schorlenxmer Ch. Garb. Comp. ^13 12 j> a. 360 248-250 248 Liebermann Prunier A., 158, 299 A. C F5l 17 5 24,692 ;vii., 337 36, 1027 Ji 247-248 Adler v* *-r. L"J, A 1 , t/ B., 12, 1891 )) 248 Goldschmiedt and W. A., 83 [2], 7 40, 824 C 10 H 6 .CH : CH.C 6 H 4 245 Schidt Greebe & Bungener B., 12, 1079 36, 807 11 .... 230-235 Laurent A. C. [2], 66, 136 i., 958 Isochrysene (triphenylene) .... (C 6 H 4 ) 3 1> ) a. 360 200 Berthelot B. S. [2], 22, 437 28, 760 i> .... * .... 196 Schultz ft (?) Tl a. 360 122 Burg B., 9, 1208 31,96 c?) .... ^i8Hi 2 (C 16 H 10 ) 181-186 Ador and Crafts B. S., 34, 532 36, 940 Diphenyl benzene C 6 H 4 .Ph 2 =1.4 C 18 H 14 a. 400 205 c. Eiese A., 164, 170 26, 63 , ; I b. 440 201 u.c. n Z. C. [2], 6, 192, vii., 139, 945 =205 c. 735 )? * J' J) )? 205 Abebjanz B., 9, 10 ,, . .. r )) )> a. 360 205 Schultz A., 174, 230 28, 150, 760 ., j, 11 )) a. 360 205 >i B. S. [2], 22, 437 B., 6, 415 i )) ) 206 Earth and Schveder B., 11, 1338 36, 66 j, v > J> 205 Meyer and Rosicki B., 11, 2172 36, 466 5) )) .... .. . ) )) 40.4-427 205-207 u.c. Carnelley 37, 705 212-213 c. -it 1) 206-208 u.c. ,, )) )) 383 (760) 205 Schmidt and Schult A., 203, 124; B., 40, 435; 36, 163 250 (45) 11, 1755 Isodiphenyl benzene C 6 H 4 .(Ph) 2 . =1.2 (?) 360 abt. 85 Schultz B., 6, 416 26, 888 ,, ,, .... .... J) )> abt. 360 85 jj A., 174, 233 28, 151, 760 ,, Retene )) 363 t). p of TTg 85 98-99 Schmidt and Schult Fehlinf? A., 203, 129 A., 106, 388 40, 435 v., 97 ; vi.,f993 ^is-^is 360 J. [1858], 440 vi., 32 390 95 Berthelot J. [1867], 39 vi., 993 > 98-99 Wahlforss Z. C. [2], 5, 73 I) b T) of H 1 "' 95 Fritzche J. p. C., 75, 281 )> n 9S'5 Ekstrand B. S. [2], 24, 55 ; B. 29, 86 ; 32, 497 ; 9,855; A.,185,7. 30, 514 Isobutylanthracene /C(C 4 H 9 ) C H <\JH > C6H4 j ji .... 57 Liebermann and Tobias B., 14, 802 40,737 1 > 57 Liebermann A., 212, 107 42, 863 Tetramethyl stilbene Me 2 .C 6 H 3 CH I CH.CjHaMe, C 18 H 20 105-106 Hepp B., 7, 1416 28, 361 =4.2.1 ; 1.2.4 ,. !, (Me 2 =1.3) 2 335 Liquid )> )) ii , =5.2.1 ; 1.2.5 157 B., 7, 1417 Diethyl stilbene .... (1.4)., Et.C 6 H 4 .CH :CH.C 6 H 4 Et 134-5 B., 7, 1414 28, 361 Isobutylanthracene dikydride C 6 H 4 .CH(C 4 H 9 ).C 6 H 4 .CH 2 .... Liquid Liebermann and B., 14, 462 40, 609 Hexetbyl benzene C 6 Et 6 C-isHao 286 123 Walder Albright, Morgan, C. R, 86, 887 34, 664 and Woolworth )) ;; iphin j> C H 292u.c.;305c. 167-170 126 Galle Claus B., 16, 1747 J. F. P., 25, 269 44, 1092 Hexapropylene ..i . ^is-^so C]8H 36 330-340 Prunier C. R, 76, 98 ; A.. ' ?il.,1016;26,487 145, 72 Octodecene J> 17!> (15) 18 Kiafft B. 16,3024 1 46, 572 tr O M 2 84 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Octodecane Me(CH 2 ) 16 .Me C H 317 (760) ; 28 Krafft B., 15, 1703 42, 1272 236 (100) ; 214-5 (50) ; 200 (30) ; 181-5 (15) ; 174-5 (11) Diphenylenephenyl methane C 12 H 8 :CHPh=1.2; 1.? C, 9 H 14 a. 360 138 Hemilian B., 7, 1208 34, 573 11 11 11 11 145-146 Fischer B., 11, 612 11 11 11 11 144 Schwarz B., 14, 1522 40, 913 11 11 11 11 145-5 Hemilian B., 11, 202 34, 431 11 11 11 11 145-5 11 B., 11, 838 34, 738 i. 11 (?) = (?) 1) 145-5-146 Miller B., 12, 1489 38, 250 (0 C 12 H 8 :CHPh=(?) 145 Kekul6 and Fran- B., 5, 910 chimont 11 11 1> 11 144-146 Behr B., 5, 970 Benzyldiphenyl C 6 H 4 Ph.(CH 2 Ph)=1.2 C 19 H 16 283-287 (650) 54 Goldschmidt M. C., 2, 410 42, 202 11 = 1.4 285-286 (650) 85 11 M. C., 2, 435 Triphenyl methane CH.Ph 3 abt. 355 92-5 Kekule and Fran- B., 5, 906 vii., 948 ; 26, chimont 171 11 11 J) 11 abt. 360 92 Hemilian B., 7, 1204 11 11 358-359 (754) Crafts A. C., 14, 409 42, 62 11 11 92-5 Schwarz B., 14, 1526, 1942 11 11 a. 300 Fischer A., 194, 251 36, 384 92-5 Baeyer A., 202, 36 38, 651 ,, ,, 330 92-5-93 Schwarz B., 14, 1519 40, 913 11 11 11 96 Doebner B., 12, 1468 From tobacco C H abt. 300 94-95 Vohl & Eulenberg A. P. [2], 147, 130 24, 1076 Reduction of C 19 H 14 92 Liebermann and B., 14, 462 40, 60!) Landshoff Iso-amylanthracene C 6 H/? C6Hll)N XH 4 C 19 H 20 (59 Liebermann A., 212, 104 42, 862 \CH / I 59 Liebermann and B., 14, 796 40, 736 i Tobias 157 Liebermann and B., 14, 802 CH(C 5 H n ) x Tobias dihydride C H 4 / yC 6 H 4 CigHss r350p. d. .... Liebermann and B., 14, 457 40, 609 X!H S (o.d.) ; Landshoff J 291-292 Liebermann and 11 1 (570) Landshoff 1 abt. 350 p. d. Liquid Liebermann A, 212, 79 42, 862 Dimesityl methane CH 2 :(C B H 2 Me 3 ) 2 =U.2.4.6) s C 19 H 24 .... 130 Baeyer B., 5, 1098 26, 501 ; vii., 534 Helenene C 19 H 26 285-295 iii., 138 Nonodet-ane Me.(CH 2 ) 17 .Me C 19 H 40 330 c. (760) ; 32 Krafft B., 15, 1704 42, 1272 248 (100) ; 226-5 (50) ; 212 (30) ; 193 (15) ; 185-5 (11) / CPh \ Phenylanthracene C H 4 C 20 H 14 .... 152-153 Schellinger A., 202, 61 38, 652 Dinaphthyl (a-a-) C 10 H 7 : C 10 H 7 s. b. 440 154-155 Smith 35, 225 vii., 844 ., a. b. p. of Hg. 154 Lessen A., 144, 78 24, 1186 ; vi., 855 )) " "' H .... 154 Walder B., 15, 2170 ,, (i; .... ,i (?) 154 Gumeschi G. 1., 7, 24 31, 712 ,, 11 a. 300 133 Otto A., 147, 170 32, 562 )) '"* 11 147 Smith B., 10, 1272, 1603 1) Isodinaphthyl (-|3-/3) n m. a. 440 187 11 35, 226 n 186-187 11 B., 9, 467 30, 33, 393 11 , .... ... 11 a. 300 187 B., 10, 1272, 1603 32, 562 11 11 11 189 Gladstone & Tribe 41, 17 COMPOUNDS CONTAINING TWO ELEMENTS. 85 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Isodinaphthyl (-0-3) C 10 H 7 : C, H r C^H,., a. 360 204 Smith 24, 1186 ; vil., 844 Dinaphthyl (-a-/3) j s. b. (-a-a) 76 35, 226, 227 :1 I> >j a. 300 75 32, 562 ?) (C 20 H I4 ) n 250-255 32, 560 Diphenylenetolyl methane ... C 6 H 4 .C 6 H 4 .CH.C 6 H 4 Me C 2 oHi 6 128 Hemilian B., 11, 203 34, 431 Phenylanthracene dihydride 120-120-5 Schellinger A., 202, 63 38, 652 Benzyl fluorene PhCH 2 .C f H 3 .CH i! .C ? H < 202 or 102 Goldschmidt M. C., 2, 443 42, 202 a-Dibenzyl benzene C 6 H 4 (CH 2 Ph) 2 =(1.4)., C 2 oH 18 56 Ziucke B., 6, 120 ; 9, 31 26, 631 a- ,1 83-84 Baeyer B., 6, 221 ft- j; =(1.2), )) 78 Zincke B., 6, 121 ; 9, 31 26, 631 Tolyldiphenyl methane CHPh 2 .C 6 H 4 Me=1.4 a. 360 71 Fischer A., 194, 263 36, 385 1! =1.3 ) 62 Hemilian & Fischer B., 16, 2360 46, 322 V =1.2 a. 300 59-59-5 Fischer A., 194, 282 36, 386 ,> ji = 1 Liquid Hemilian B., 7, 1208 28, 153 Triphenyl ethane GH 2 Ph.CHPh 2 a. 360 Liquid Waas B., 15, 1128 42, 1209 '" CPh 3 .CH 3 .... 205 Combes C. R, 98, 678 46, 837 From rosaniline m. a. 360 58 . Fischer B., 9, 900 30, 530 Oon-tlfw: a. 360 A., 121, 251 (Me.Pr.C 6 H s ) 2 20^^26 335 Solid s. b. Montgolfier A. C. P. [51, 14, 5 34, 899 L J' J 0) CWHao 254 Mossmer A. Ph., 99, 257 il., 759 From Eesina Guaiaci Peruv. .... 250-270 Kopp A P. [3], 9, 103 aroniat. v. odor. Paracajeputene C 20 H 32 310-316 Schmild T. E., 22 [6], 360 i., 711 Colophene .... J 310-315 Liquid Deville A. C. i., 1086 300 Etard and Moissau B. S. [2], 34, 69 40, 18 315 Gladstone 17, 1 From colophony .... 305-310 Eenard C. E., 92, 887 40, 739 315 Bouchardat A., 37, 30 Metaterebenthene .... abt. 360 Berthelot J., 6, 524 v., 924 310-315 (fl (?) 315-325 v / Hirzel \ / v., 1048 Camphoterpene i; 260-280 Ballo B., 12, 324 36, 540 From copaiba oil )> 250-260 Straus A., 148, 152 vi., 490 balsam .... ) 250-260 Brix M. C., 2, 537 42, 65 11 !! 1) .... ji 252-260 M. C., 2, 512 )) >! )! .... 250 .... A., 7, 157; 34,321 From oil of poplar .... 260 Liquid Piccard B., 7, 1485, and 28, 1191 C. C. [1875], 4 (0 is 255 Werner Z. C. [1862], 588 v., 1046 (?) jj 315 Gladstone 25, 6 Colophene dihydride C 2 oH 32 .H 2 ^20^34 322 .... Montgolfier C. R., 87, 840 36, 328 Dicamphene dihydride ) 321 c. .... A. C. [5], 19, 150 ), )! )> 321-323-6 94 Letts B., 13, 795 38, 669 Dimenthene ^_/nfiJi.i ( > 320 B. S., 31, 530 _l( .1(1 i j^ n H - Q 314-315 Ijippnia.nii find B, 12, 69 36,447 ao^^SS Hawliczek *r*J * 1 "* C H 390-400 Ba/uer J., 14, 660 vi., 123 Eicosaue Me.(CH 2 ) 18 .Me 20 40 205 (15) 36'7 Krafft B., 15, 1718 42, 1273 a-Dinaphthyl methane (Ci H 7 ),jCH 2 20 42 C 21 H 16 \ / a. 360 109 Grabowski B., 7, 1606 28, 456 3- j> n i 92 Kichter B., 13, 1728 40, 282 Benzyl phenanthrene C^^CHfh 155-156 Goldschmidt M. C., 2, 432 42, 202 Methylphenyl anthracene .... Me.CH=1.4 119 Hemilian B., 16, 2367 46, 322 CPh, C 6 H 3 Me/| ^>C 6 H 4 Ditolylpheuyl methane Ph.CH.(C 6 H 4 .Me) n t'siHoo 55-56 Thorner and Zincke B., 11, 70 34,425 Diphenyl-p-xylylmethane .... Ph s CH(C 6 H 3 Me 2 ) .... 91 Hemilian B. S. [2], 34, 326 40, 434 i) j) 92 H B., 16, 2360 46, 321 86 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Dibenzyl toluene Me.CeH^CH^h), ^21^20 392-396(760); Liquid Weber and Zinck6 B., 7, 1153 88, 155 280-285 (30-40) From toluene red Heneicosane .... Me.(CH 2 ) 19 .Me j 360-363 215 (15) 36-40 40'4 Rosenstiehl & Gerber Krafft C. R, 94, 1319 B., 15, 1719 42, 964 42, 1273 Dinaphthyl anthrylene Picene.... CloHgC : C.C 10 H 6 ^21*^44 ^22^12 CL.H,,, 270 337-339 u.c.; Grabowski Burg B., 11, 303 B., 13, 1834 34, 509 40, 179 *-^22 14 518-520 345 c. 330-335 o Grrebe and Walter B., 14, 177 40, 284 Dinaphthyl acetylene C 10 H 7 .C:C.C 10 H 7 j I> a. 360 225 Grabowski B., 11, 302 34, 509 ethylene O]Q-Uy.Oji . G-ti.OjQliy C 22 H 16 360 Liquid Hepp B., 7, 1419 28, 362 Dixylyl benzene C 6 H 4 (C 6 H 3 Me 2 ) 2 ^22^22 392-396 Liquid Senff A., 220, 225 46, 427 Tritolyl methane CH(C 6 H 4 .Me) 3 377 73 Rosenstiehl & Gerber C. R., 94, 1319 42, 965 Dipentenyl benzene ... CH2Me.CHPh.CH.CH., CH 2 Me.CHPh.CH.CH 3 CjjHjg 208-212 .... Dafert M. C., 4, 616 44, 1094 Bidiethyltolyl Dooosane (CHEUCeH^)., Me.(CH 2 ) 20 .Me C^Hao a. 360 224'5 (15) 1.0 44-4 Krafft )> B., 15, 1718 42, 1273 Naphthyldiphenyl methane ... C 10 H 7 .CH.Ph 3 ^22 -"46 C23H 1S 134 ; after Lehne B., 13, 358 38, 478 crystalliza- tion or fusion 149 ) .... 150 Hemilian B., 13, 678; B. S., 40, 434 Tricosane Me.(CH 2 ) 21 .Me 234 (15) 477 Krafft 34, 326 B., 15, 1713 42, 1273 Triphenyl benzene C 6 H 3 Ph 3 ^23*^48 C 24 H 18 167-168 Engler and Heine B., 6, 638 26, 1036; vii., 945 ,, 169-170 Engler and Berthold B., 7, 1124 28, 63 ji 169-5 Engler B., 8, 394 28, 890 J 3) !> )> 172-172-5 .... A., 209, 3 Benzerythrene .... u 307-308 Schultz B., 11, 95 34, 323 ,, Didiphenyl . . .... j> 307-308 187 Schmidt & Schultz Barth and Schreder A., 203, 134 M. C., 3, 815 40, 435 44, 469 From American petroleum.... .... )) 260 Prunier C. R., 88, 316 36, 447 Carbopetrocene .... 268 )i A. C. [5], 17, 28 36, 1027 (?) Tetracosane . . CH,(CH,UCH, ^24^32 C H 215-325 243 (15) 51-1 Krafft B. S., 33, 317 B., 15, 1718 42, 1273 Tetraphenyl methane v>j-M-g^v>-i_i.2/22 ~^3 CPh 4 Vy 24 J - i 50 0*5^20 145 Kekul6 & Franchi- B., 5, 907 26, 27C mont ?j i )> )> .... 145 Behr B., 5, 970 JJ i) M ) a. 360 Solid Friedel and Crafts C. R,, 84, 1450 32, 864 Diphenylphenyl methane .... CH 2 (C 6 H 4 .C 6 H 5 ) 2 ji a. 360 162 u. c. Weiler B., 7, 1181 28, 152 Triphenyl methane + benzene CH.(Ph) 3 .C 6 H 6 CsiHj,, 70 Kekul6 & Franchi- B., 5, 906 26, 171 mont j) Begins 80 76-77 Schwarz B., 14, 1519 40, 913 (?) CasHja 350-360 Fischer B., 7, 1194 From fluorene .... (C 26 H l4 ) n .... 270 Harpe and v. Dorp B., 8, 1049 29, 242 ,, C 6 H 4 .C 6 H 4 .C:C.C 6 H 4 .C^H 4 C 26 H 16 (?) a. 360 182-183 )! 3> 33 29, 24.3 jj C 6 H 4 .C 6 H 4 .CH:CH.C 6 H 4 .C f H 4 C 2 fiH 18 241-242 ?> 31 i) Tetraphenylethylene Ph 2 C : CPh 2 C26H20 321 n. c. Behr B., 3, 752; 5, 27. vii., 1150 ,, J J 221 Stiidel A., 194, 311 36, 318 J> H 220 B., 9, 562 J ) Impure 214 Friedel and Balsohn B. S. [2], 33, 337 38, 558 5> )J II 204 Schwarz B., 14, 1526 40, 913 Dibenzyldiphenyl Ci 2 H 8 (CH 3 .C 6 H 5 ) 3 C 26 H 22 113 Wolf B., 14, 2032 42,62 Tetraphenylethane Ph 2 CH.CHPh 2 >i 209 Zagoumenny A., 184, 177; B. 36, 318 9,277 M 207 Stiidel A., 194, 310 3> V ... .... 206 Grsebe B., 8, 1055 29, 70 j ... .... .... 206 Engler B., 11, 927 ? ... ij .... 207 3 J) COMPOUNDS CONTAINING TWO ELEMENTS. Name. Constitution. Formula Boiling Point. Melting Point. Authority. Reference. <->t ~ Watts' Diet. & J. Ch. Soc. Tetraphenylethane - Ph 3 C.CH 2 Ph C 26 H 22 0) Anschutz B., 16, 2377 46, 326 Cholesterilene a- " 205-206 Thorner and Zincl re B., 11, 67 34, 425 (9- C 2H 42 240 Zwenger A, 66, 7; 69, 3^ 17 t, 925 .... JJ 255 y- H 127 " " |^ " 68 A, 69, 348 it Cholestrone (a) jj 175 ,, A, 69, 349 (?) " 68 .... C. E., 92, 195 Cholesterilene hydride C 26 H 44 80 abt. 90 Walitzky B., 9, 1310 31,58 (0 Cerotene (CH 2 Ph.C 6 H 4 ) 2 CH 2 n TT abt. 90 Bseyer B., 6, 222 JJ 26, 885 (_/(>7.fcl- , 57-58 Brodie A, 67, 210; J. ill., 187 1, 708 Heptacosaue .... M,(CH 2)2 , Me O TT 270 (15) 65-66 59-5 Konig and Kiesew Krafft B., 6, 500 B., 15, 1714 26, 1215 42, 1273 From /3-piuacolin dioxyretistene anthracene O TT CTT 290-310 213-213-5 Thorner Ekstrand B., 9, 1743 B., 17, 695 31, 465 46, 1041 Tetratolylethylene From galbanum oil MeC 6 H 4 ) 2 C:C.(C 6 H 4 Me) 2 28^58 360 215 Berthelot Schwarz B. S. [2], 9 B., 14, 1529 vi., 741 40, 913 C 3 oH 4a 255 Mossner A, 119, 257 24,260 chamoinile oil 255 .... Kachler B., 4, 39 250-255 Melissene .... C TT 62 " JJ Melene GO .... .... Hi., 187 ) 370-380 62 Brodie A, 71, 156 Hi., 868 " 33-5 Ettling A, 2, 259 Hentriacontane From benzene and toluene .... Ditolyldixylybethylene Tetraxylylethylene Pentatriacontane Tetraterebenthene Me.(CH 2 ) 29 .Me (C 7 H 7 ) 2 .C:C(C 8 H 9 ), (C 8 H 9 ) 2 .C:C(C 8 H 9 ) 2 Me-tCH^Me 5> Q) 2 H 23 C 32 H 32 302(15) 404-427 331 (15) 47-8 68-1 244-245 244-245 74-7 Lewy Krafft Carnelley Schwarz Krafft A C. [3], 5, 395 B., 15, 1714 37, 713 B., 14, 1532 B., 14, 1531 B., 15, 1715 1) 42, 1273 87,713 40, 913 42, 1273 Fichtelite .... C 4oH w b. 100 Eiban C. E., 79, 389 28, 61 * H * 46 A, 37,304; 103, a-Abietin 236 (0- C 44H 60 295-303 Z. C. [1866], 35 Dammaryl C H 101 Wurzel P. J. [3J 2, 789 25, 392 Oil of vertivert From chrysoquinone Action of heat on benzene .... Mixture (?) n 280-283 190 200-204 Gladstone Grssbe J. [1847-48], 741 B., 7, 782 25,3 27, 989 266 Schultz A., 174, 201 28, 151 Petrocene Angustura bark oil From rosin oil Mixture (?) .... H 267 196 a. 300 Liquid Hemilian Schlagdenhauffen C. C. [1877], 2 J. Ph., 4,26, 130 JJ 32,867 32, 932 M 94-95 Kelbe B., 11, 2174 36,467 From benzene and toluene ... .... jj .... 86 n n a-Paracotene " 293-316 13 Carnelley 37, 715 0- jj 160 170 Jobet and Hesse A, 199, 17 38, 325 Steraoptene M )! n n Oil of pimento " 33 Baur D. P., 204, 258 25,937 From preparation of dipheuy] 243 .... i C\A Gladstone 25, 2 Metanaphthalin 50K 194 ^)sten B., 7, 170 $7, 581 Leken from ozokerite ^ TT >_' 37 ] J elletier & Walter , i. C. [2], 67, 267 a, 167 From lapachic acid />)\ | 9 1 Beilstein&Wiegand J 3., 16, 1547 W, 1073 Colophanthrene Fellow .... ( 3=93 -2, H= ; 7-0 !50 ; 160 ( 5. C 10 H 8 1 >yst j 'atemb ( I6nard ( 1 I., 22, 337 1 E., 97, 111 4, 212 6,83 rtThite Af\ From tobacco smoke ( ,'=847- 85-5 40 e 7 4-5 I Cissling I !., 16, 2432 JJ 9, 173 I 1=14-6 15-2 88 ORGANIC COMPOUNDS. (2.) CC1, CBr AND CI. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Carbon tetrachloride *> CC1 4 78 Kegnault A. C. [2], 71, 383 ii 78 Goldschmidt B., 14, 928 i> ii ) 77 .... Kolbe A., 54, 146 11 11 .... 78-1 (748-3) Pierre C. K., 27, 213 37, 199 >i .... > 75-77 (724) .... Krafft and Merz B.,8, 1297 & 1300 >i 11 )j 75-76 (721) 11 11 B., 8, 1301 & 1302 i) 11 .... j> 75-76 11 i B., 8, 1303 11 11 .... 77 Eiche .... 37, 199 11 11 .... 76 .... Schutzenberger A. C. [4], 21. 350 11 11 75-5 (739-4) Haageu P. A., 131, 117 11 .... it 77 .... Hofmann 37, 199 11 11 .... >i 76-5 (760) .... Main G. J. C., 1877 11 11 .... 76-5 (760) s. 24-73 Eegnault M. A. S., 26, 658 iii., 135 11 11 ... ) 76 Henry A. S. S. B., 1879 11 11 .... 76-74 c. (760) Thorpe .... 37, 199 11 i N 77 .... i., 765 11 11 .... 77 Plimpton & Graves 43, 123 i) 11 76-6 c. .... Thorpe .... 35, 545 11 11 .... 76-9 c. Perkin 46, 532 11 11 .... 76 .... Bolas and Groves 24, 779 vii., 324 11 11 .... 76-4-76-5u.c. Brown 39, 200 11 11 .... 76-45-76-6u.c. .... 11 39, 211 11 11 MM i) 76-45-76-6 u.c. 11 39, 306 >! 11 .... j 75-4,285'3c.t. Pawlewaki B., 16, 2633 46, 252 Dichloracetylene cci. ; CCL GA 175-200 176-200 i., 768 Tetrachlorethylene CCUCClj C 3 C1 4 122 b. 18 Kegnault A. C. [2], 71, 353 i., 767 11 )1 j) 123-9(761-9) Pierre C. K., 27, 213 ; P. A., 76, 458 ,, i) 116-7 Geuther A., 107, 212 28, 746 11 >1 )j 122 Kuoff B., 9, 1498 11 )j 121 Bourgoin B., 8, 548 ; C. K., 28, 746 80, 971 11 M 118 .... Goldschmidt B., 14, 929 11 5 120 (725) .... Krafft and Merz B., 8, 1297 & 130 i 11 J) 120 .... Bruhl A., 200, 139 38, 296 Hexachlorethane CC1 3 .CC1 8 C 2 C1 6 182 160 i., 766 11 1) 172 162 Eegnault 36, 212 11 J> 11 182-5 u. c. Krafft and Merz B.,8, 1297 & 1300 11 *. .> ) 11 .... 179 c. Geuther 36, 212 11 11 182 Smith and Davis 41, 414 11 *.. 11 .... 182-183 Hubner and Miiller Z. C., 6, 328 vii., 258- i )> 11 .... 181 Kuoff B., 9, 1497 & 1500 11 ) 11 .... 181 11 B., 9, 1498 & 1499 i ) 11 .... 182 11 B., 9, 1490 11 ) 11 180 11 B., 9, 1486 11 "* 11 183-5-184-5 185-186 u.c.; Hahn B., 11, 1737 36, 212 u. c.; 187-51-188-43 187-71-188-75 c. (760) c. i " *** 11 .... 184-5-185u.c.; J) 11 11 186-85-187-4 c. 11 )> 11 .... 153-5 Geuther and Stapff J. Z., 6, 228 vii., 479' i> )} 182 (o. p.) 160 Naumann B., 4, 646 24, 879 ,, .... ... ?> 11 100 (31) .... 11 )> ,, n 11 78 (13-5) ) 11 ) 11 11 15(1) .... j 11 I )1 11 181 .... Stsedel Z. C. [2], 8, 515 25, 394 11 > ) 11 For b. p. table seePartlll. COMPOUNDS CONTAINING TWO ELEMENTS. 89 : Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. tetochlorpropane CC1 3 .CC12.CC1 3 C 3 C1 8 268-269 (734) abt. 160 Krafft and MUller B., 8, 1298 29, 540 ,, .... .... > 280 Liquid Cahours A., 76, 283 ; J., 3, 496 (9 .... c.co, a. 200 Liquid Puchot A. C. [5], 28, 507 46, 167 erchlormesol ... C 4 C1 6 283-284 (733) 39 Krafft B., 10, 804 32, 727 erchlormecylene .... C 6 C1 9 d. 270 39 Ost J. p. C., 27, 294 44, 796 texaoblorbenzene .... 0,01, : 222 Klepl J. p. C., 28, 193 46, 447 ,, .... .... .... II .... 223 Smith and Davis 41, 414 ,, .... .... .... 15 225 Ladenburg B., 5, 789 26, 167 ; vii., 142 ,, .... .... .... I) 225 B., 6, 32 26, 499 ,, .... .... .... II 306-307(721} KS Krafft and Merz B., 8, 1302 & 1303 29, 540 11 .... 310 u.c. (733) Krafft B., 10, 801 32, 727 ,, .... .... .... 326 c. 226 BerthelotandJung- Z. C. [2], 4, 565 : vi., 267 fleisch J., 21, 354 .... II 220 Beilstein and Kuhl- Z. C. [2], 5, 183 berg ,, .... .... .... 1 331 c. 226 Jahn ., .... .... >I 231 c. Basset J., 20, 608 11 .... .... .... II 220 Miiller B., 5, 790 ,, .... I 309 (721-5) 223 Kuoff B., 9, 1485 & 1491 ,, .... .... .... I) 310 (725) 223 B., 9, 1486, 1488, and 1498 1) .... I> 222 5) B., 9, 1487 1, .... .... .... )> 310 (727) 223 :) B., 9, 1490 & 1499 ,, .... .... II 310 (721) 224 n B., 9, 1492 - ., .... .... 51 310 (720) 223 i? B., 1500 11 309 (724-5) 223 ?i B., 9, 1493 & 1494 v .... II 310 (724) 224 B., 9, 1493 & 1495 ,, .... .... 11 309-5 (725) 223 5) B., 9, 1497 JJ .... .... 11 309 (722) 223 B., 9, 1499 ctochlornaphtlialene C 10 C1 8 SOS J) B., 9, 1487 31, 300; 32, 901 ,, .... 11 172 Laurent 5> j, > 403 p. d. 135 Berthelot and Jung A. C. [4], 15, 332 32, 901 ; vi.. fleisch 847 ecachlordiphenyl ci 5 c c .c,A C^Clm not at 270 Euoff B., 9, 1491 31, 300 ilorinated toluene C 21 C1 26 152-153 Smith J., 1877, 420 38, 387 \rbon tetrabromide .... CBr 4 89 Gessner B., 9, 1508 11 11 11 90-1 Hamilton 39,48 *i v 11 91 Bolas and Groves A.,156, 60; 160,171 23, 164 'i 11 .... 11 189-5 (760) 24, 780 vii., 257 11 11 n 189-5 Henry A. C. [5], 30, 266 46, 718 1 I? 92 Hofmann B., 15, 767 .. 11 188-189 92-5 Schaffer B., 4, 369 ') )} for b. p. table see Part III. 3trabromethy lene .... CBr 2 : CBr 2 C^r, .... 50 Lennox J., 14, 653 11 i. 11 50 Limprieht A., 165, 253 26, 625; vii., 828 , 11 .... 50 Lo'wig A., 3, 292 i., 764 ), .... n 11 53 Merz and Weith B., 11, 2240, 2243 36, 302 exabromethane CBr 3 .CBr 3 C 2 B r|i d. 170 Solid Limprieht A., 165, 253 26, 625 exabrombenzene C 6 Br 6 a. 300 Gessuer B., 9, 1049 30, 511 , <1 a. 300 Merz and Weith B., 11, 2240 It 306-308 M., 2, 196 )1 a. 310 Gessner B., 9, 1505 31,300 M 315 J. R, 9, 214 rbon tetraiodide .... o* d. 100 Solid (?) A.,172,173;J.R, 6, 109 90 ORGANIC COMPOUNDS. (3.) CO AND CS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Carbon monoxide CO Gas ., ,, non-cond. Wroblewski and M. C., 4, 415 44, 952 136 (150 Olszewski ats.) .... H 193 Wroblewski C. R, 98, 982 46, 817 Carbon dioxide o:c:o C0 2 73 Thilorier A.C. [2], 60,427 ., 56-5 to 58 Faraday P. T. [1845], 155 ) V .... n 78-2 Berthelot B. S. .... 78-2 (760) Itegnault M. A. S., 26, 658 iii., 84 ,, .... n 78-2 .... Jarolimek M. G, 3, 835 44, 418 ,, .... 80 (760) Pictet 1878 ,1 80 Cook C. C. P., 592 Tl 1 .... n cond. 65 Pictet C. N., 36, 281 34, 10 (4 to 6 ats.) .... 10-6 (60 ats.) Davy and Faraday 30, 248 28'3 (70-39 .... Hartley ats.) vapour tension table " See Part III. Carbon monosulphide CS Solid Sidot C. R, 81, 32; 28, 1236 B., 8, 982 ; Z. C. - [1868], 622 Carbon disulphide s:c:s 08, 46-6 (760) Gay Lussac P. M. [4], 29, 4 37, 364 v 11 46-9 (753) Marx Sw. J., 62, 460 46-2 (769) Andrews P. M. [4], 29, 4 37, 364 ' ti .... 45 Couerbe A. C. [2], 61, 232 n 47-4 (760) Friedburg C. N., 47, 52 44, 535 j) 47-9 (755-8) Pierre C. R, 27, 213 iii., 84 46-2 (760) Regnaull M. A. S., 26, 658 iii., 135 JT 46 (760) Buff A. Sup., 4, 129 37, 364 47-7 (745-5) Haagen P. A., 131, 117 46 Braun C. C. [1875], 810 29, 979 n .... 46-04 c. (760) Thorpe 37, 363 .... .... JJ 20 (298) Brown 39, 209 ,, ., 45-1 (736) ; .... Jones .... 33, 180 45-5(744-5); 46-0 (752) ; 46-1 (760) ; 46-2 (762) 46-8 Cossa vi., 1061 .... 47 (768-6) .... Schiff G. J. G, 1881 .... B 110 Wroblewski and C. R., 96, 1225 44, 781 Olszewski .... 43 Ramsay 35, 471 46-6 .... Berthelot 35, 544 12to-13(?) Wartha B., 3, 80 ; 4, 180, vii., 265 221 46 Pictet P. M. [5], 1, 477 31, 163 H 271-8 c. t. Sajotschewsky Wied. A. B. 45, 139 [1879], 741 b. p. table see Part III. Penta carbon diaulphide C 5 S 2 135 Baale N. R P., 19, 449 vii., 265 COMPOUNDS CONTAINING TWO ELEMENTS. 91 (4.) ON. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. N : C.C : N C,N, 34-4 Faraday P. T. [1845], 155 II., 276 21 Henry B., 6, 737 26, 1129 20 Cooke C. C. P., 592 21 to 40 Hofmann B., 3, 658 vil., 416 Cond. 22 Loir and Drion B. S., 1, 184 ill., 97 Cond. ord. Davy and Faraday P. T. [1823], 19C ii., 275 temp.(4ats.) Cond. 35 s.b. 30 Bunsen P. A., 46, 101 to 40(o. p.) 20-7(760) P. A., 46 >? 12-5 (v. t. Niemann il., 275 vapour tension table 4 ate.) see Part III. ^ N 2 92 II. COMPOUNDS CONTAINING THREE ELEMENTS. CHF. Amyl fluoride Fluobenzene Fluotoluene (impure) (only phenol., see 46, 426) PhF C 6 H 4 .Me.F=1.4 C 5 H U F C 7 H-F 72-92 182-183 85-86 114 40 1. 20 Liquid Young Schmidt and Gehm Patemoand Oliveri J. p. C. [2], 1, 394 G. I., 13, 533 39, 497 24, 369; 42, 615 46, 426 11 11 51 CHC1. Trichlormethane (chloroform) CHC1 3 61 Reguault A.C. [2], 71, 381 i., 919 >. 61-1-61-2 Main G. J. G., 1877 11 (760) J ?1 60-5 Remys A. Ph. [3], 5, 513 28, 439 V 62 Reichardt A. P. [3], 5, 593 29, 363 '1 ) .... ,, 60 Pictet P. M. [5], 1, 477 31, 163 11 11 .... 70 Berthelot B. S. [2], 29 34, 263 11 ? .... ,, 60-5 (743) Haagen G. J. C'., 1867 11 11 n 62-63 Werner A. Ph. [3], 12, 481 34, 821 11 1 .... 11 60-8 Regnault J. Ph. [4], 29, 402 36, 747 11 11 61-2 c. (760) Thorpe 37, 196 11 )! 62 c. Perk in 45, 530 11 11 63-5(772-52); b. 16 Pierre C. R., 27, 213 63 (760) 11 11 ,, 60-65 Goldberg J. p. C. [2], 24, 97 42, 28 11 11 62 Rump C. C., 6, 34 .. i) ,, 60-2 Reguault M. A. S., 26, 658 ! * 11 63 Schiff G. J. C., 1881 M V 11 70 Soubeirau A. C. [2], 48, 139 X 11 60-8 Liebig A., 1, 199 i., 919 1) .... v 61-5 Schall B., 16, 3013 46, 551 11 ! 11 260 c. t. Sajotschewsky Wied. A.. [1879], 45, 138 741 (methylene CH 2 C1., 30-5 Reguault A. C. [2], 71, 378 iii., 988 chloride) > j? 40 1. f. m. iii., 1005 >> i) 30 .... 1) .1 55 40 Sakurai 41, 362 11 .... B 40-4-42 Perkiu 22,260;C.N.,18, vi., 827, 829 106 ) 39-5-^0-5 Butlerow Z. C. [2], 5, 276 vi., 829 51 Jl M 41-6 c. (760) Thorpe .... 37, 194 71 V M 40-41 Butlerow A., Ill, 251 V 51 B 40 Perkin 45, 527 J) 11 15 40-41 Greene C. R., 89, 1077 38, 307 Methyl chloride CH 3 C1 b. 18 Dumas and Peligot A. C., 61, 193 iii., 987 .... 11 -23-7(760) Regnault M. A. S., 26, 658 .... 11 20 to 22 Berthelot J., 8, 599 Trichlorethylene ci 2 c : CHOI C 2 HC1 S 88 Berthelot and Jung- C. R., 69, 542 vi., 33 fleisch 87-90 Fischer Z. C. [1864], 268 vi., 603 M 87-88 Paterno and Pisati G. I., 1, 461 24, 1191 H 88 Liquid Berthelot and Juug- A. C. [4], 26, 472 25,996; vii.,20 fleisch 11 87-38 Paterno & Oglialora G. I., 3, 533 27, 460 ,, 11 87 Saban6eff B. S. [2], 34, 323 40, 399 160-170 J. [1864], 481 COMPOUNDS CONTAINING THREE ELEMENTS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Pentachloretliane CC1 3 .CHC1 2 C 2 HC1 S 146 Regnault A.C. [2], 71, 368 11., 532 ,, .... u > 153 .... 11 Z. F. C., 12, 245 ri.,585;vii.,479 ,, *i i) 158 1. 18 Patenid C. R, 68, 450 vi., 584 11 i) 158 Henry B., 4, 101 24,255 11 2 HC1 5 158 .... Paterno and Pisati G.I., 1,461 24, 1191 ,, .... .... ^t Jfl 158 Stsedel Z. C. [2], 8, 513 26, 94 .... .... 11 1J 158 Patern6 & Oglialoro G. I., 3, 533 27, 460 ,, .... 11 I) 159-1 c. (759-9} Thorpe 37, 192 51 153-8 (763-3) Liquid Pierre C. R, 27, 213 37, 192; 11., 573 ,, .... 1 138-1 (400) Stsedel B.,15,2559;B.,13, 840 ,, .... i) J1 146 (500) 11 11 11 u 1? 152-7 (600) 11 11 ,, .... i 1) 158-5 (700) >i 11 ,, .... 1> 161-7 (760) 11 11 v .... .... 163-8 (800) 11 i) 11 11 168-6 (900) 11 )! ,, .... .... 11 1> 172-9 (1000) 11 11 ,, u 176-1 (1080) .... 11 (?) C 2 C1 6 (?) 1> 180-181 Hubner A., 120, 330 vi., 22, 585 Acetylene dichloride CHC1 ; CHCl C^oCL, 55 Berthelot B. S. [2], 5, 191 vi., 33 ,, ., .... .... Jl M 55 .... Plimpton 41, 397 ii >, I) 11 abt. 55 Berthelot and Juug- A. C. [4], 26, 472 25,996; vii., 19 fleisch ,, j, 11 55 Henry C. R, 98, 741 46, 831 1 Hchloretliylene CHj : cci 2 11 35-40 Kegnault A. C. [2], 69, 155 ii., 573 11 )' 35 .... Henry C. R, 98, 741 46, 831 ,, .... .... i 11 37 Kramer B., 3, 261 vii., 490 ,, .... H )i 36 Baumann A., 163, 308 26, 891 v .... j) >i 35-37 Henry C. R, 97, 1491 ; 46, 571, 719 C. R, 98, 518 jj .... >i 37 Plimpton 41, 397 Acetylene tetrachloride CHC1 2 .CHC1 2 C 2 H 2 C1 4 147 Liquid Berthelot and Jung A. C. [4], 26, 472; si., 33; vii., 20 fleisch C. R., 69, 542 25, 996 ,, ,, .... i 11 124-1 (400) .... Steedel A., 195, 188 u ,, .... 11 11 131-9 (500) .... 11 B.,15,2563; B.,13, 840 ., H 138-2 (600) .... ;i 11 ,, ,, .... 11 143-8 (700) | 11 11 ,, ,, 11 11 146-8 (760) 11 u 1" " i) 148-6 (800) 11 ! 11 153-2 (900) .... 11 11 j) 157-2 (1000) .... 11 11 .. j> i) 160-2 (1080) 11 11 (?) ... (?) 11 146 Geuther Z. C. [2], 7, 147 24, 513 " " 11 147 c. Paternd and Pisati G. I., 1, 461 24, 1191 I j u 147 .... 11 N. C. [2], 4, 401 25, 394 (f\ 11 J! W (?) (?) 153-5 Geuther Z. C. [2], 7, 147 24, 513 Tetrachlorethane CC1 3 .CH 2 C1 n 135 .... Regnault A. C. [2], 69, 162 ii., 573 15 138-6 Pierre C. R, 27, 213 i 11 133-136 Geuther Z. C. [2], 7, 147 24,513; vii.,479 ,, J> 1) 138 Stedel A., 195, 188; A., 80, 130 J> 11 135-1 Jl A., 195, 188 J> 11 108-1 (400) !> B., 15, 2563 44, 303 ? 11 115-7 (500) Jl 11 11 T 11 121-9 (600) 11 11 V 5 M 127-5 (700) .... 11 11 1) 11 11 130-5 (760) 11 11 11 1? 11 11 132-5 (800) 11 11 M 1 11 136-9(900) 11 11 11 ,, M 11 141-0 (1000) : 11 11 'i ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Keference. Watts' Diet. & J. Ch. Soc. Tetrachlorethane CC1 3 .CH 2 C1 C^Cl, 144-1 (1080) Stsedel B., 15, 2563 44, 303 jj 127-5 Z. C. [2], 8, 513 25, 394 jj j j 102 Geuther Z. C. [2], 7, 147 24, 513 V 102 Regnault A. C. [2], 71, 366 25, 393; ii., 532 Chlorethylene CH 2 : CHCl C 2 H 3 C1 -18 to 15 Liquid A., 108, 224 ii, 573 17 to 18 Kekule and Zincke A., 162, 125 ;B., 3, 25, 491 131 H M 17 to 18 Sabaneeff B. S. [2], 34, 323 40, 399 Chloracetene .... Mixture (?) 45 s. Harnitz-Hartnitzky A., Ill, 192 25, 492 " 45 s. Kraut B., 3, 129 Chlorethylene .... (C 2 H 3 Cl) n a. 130 Baumann A., 163, 318 25, 891 Dichlorvinyl chloride C 2 H 3 C1 3 36 vii., 1203 Methyl chloroform CC1 3 .CH 3 C.jH 3 Cl 3 75 Regnault A. C. [2], 71, 364 ii.,532; vii.,47 n 72-75 Geuther Z. C. [2], 7, 128 24, 515 ,, 74-5 Stedel Z. C. [2], 7, 197 24, 696 74 Z. C. [2], 8, 513 25, 394 jj 74-9 Pierre C. R., 27, 213 jj jj jj 75-3-76-3 c. .... Perkin 45, 531 j' jj 54-7 (400) StEedel B., 15, 2563; B., 13, 840 jj jj u 61-3 (500) jj ,, jj 66-6 (600) jj jj jj jj ". 71-5 (700) jj jj jj jj jj 74-1 (760) jj jj jj u 75-8 (800) jj 79-8 (900) jj 83-3 (1000) j) jj 86-1 (1080) Chlorethylene dichloride .... CHClo.CH 2 Cl 115 Regnault A. C. [2], 69, 153 ii., 573 jj jj ,, jj 115 .... Geuther Z. C. [2], 7, 147 24,513; vii., 479- jj jj ,, jj 114-8-115-3 .... Perkin 45, 531 n jj 115 Kramer B., 3, 261 vii., 490 jj jj _j M 115 .... Stedel Z. C. [2], 8, 513 25, 394 jj jj M 114-2 Pierre C. R., 27, 213 j, Jj 114 Tawildaroff B. S. [2], 34, 346 40, 398 JJ u ,, jj 115 Sabaneeff B. S. [2], 34, 323 40, 399 jj jj ., 92-8 (400) Stsedel B., 15,2563; B., 13, 840 JJ JJ ,, 99-7 (500) jj jj jj 105-6 (600) jj JJ jj jj 110-7 (700) jj jj u 113-7 (760) .... ,, jj jj JJ jj 115-6 (800) jj jj j> JJ JJ 119-8 (900) jj jj jj jj 123-6 (1000) jj JJ JJ B 126-5 (1080) Bthylene dichloride CH 2 C1.CH 2 C1 C 2 H 4 C1 2 82-5 (765) Regnault A. C. [2], 58, 307 ii., 572 jj B 85 (770) Dumas A. C. [2], 48, 196 83 (760) Frankland & Dobbin 33, 546 j> jj ,, H 82-5 Geuther J., 15, 421 vii. 471)" n 85 .... Kramer B., 3, 259 vii., 490 jj jj ,, H 85-8 Depretz jj jj * 84 Sta;del Z. C. [2], 8, 513 25, 394 ., a 82 Plimpton & Graves 43, 123 85 Plimpton 41, 397 M 85 ; 283 c. t. Pawlewski B., 16, 2633 46, 252 83'7 c. Perkin 45, 528 u u 5J 85 Lescoeur B. S. [2], 29, 483 34, 718 ,, H 83-5 (753-9) Thorpe 37, 182 82-4 (765) .... Liebig A., 94, 245 n 85 .... A., 10 ., jj 84-92 (761-88) Pierre C. R., 27, 213 COMPOUNDS CONTAINING THREE ELEMENTS. 95 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylene dichloride CH 2 a.CH 2 Cl C 2 H 4 C1 2 85 Haagen P. A., 131, 117 jj 86 Maumenc J., 22, 346 84-5-85 (760) Briihl G. J. C., 1880 jj jj 1) 83-85 Schorlemmer 30, 144 M 84-84-5 Brown 39, 209 j, j. 64-7 (400) Stsedel B., 15, 2563 ; B., 13, 840 ,1 j 71 (500) ,j jj 76-6 (600) JJ JJ 81-5 (700) JJ jj 84-1 (760) JJ 1J 85-7 (800) JJ JJ JJ 89-7 (900) JJ J) jj 93-4 (1000) jj J 95-9 (1080) M Etliyli;lene CH S .CHC1 2 64 .... Regnault A. C. [2], 71, 357 ii., 531; vii., 479 jj 58 Wurtz and Frapolli C. R, 45, 1015 ii., 599 60 .... Geuther A., 105, 323 G3, 546 ; ii., 599 60 Beilstein 24,696; vii.,479 J) 59 Henry C. R., 97, 1491 46, 571 j, jj j. 58 Plimpton 41, 397 jj jj 57-8; Pawlewski B., 16, 2633 46, 252 254-5 c. t. 57-59 Geuther J., 11, 289 24, 696 ,, 57-4-57-6 Briihl G. J. C., 1880 (751) ,j jj jj jj 57-59 Geuther and Stapf J. Z., 6, 228 vii., 479 j, jj 60 .... Kramer B., 3, 259 vii., 4.90 ,, 64 .... Walters J. p. C. [2], 4, 57 24, 923 ,j ,, .... 59 Stcedel Z. C. [2], 8, 513 25, 394 ,, j, 57-5 Buntt- A., 170, 305 27, 354 jj 61 .... Gladstone & Tribe C. N., 29, 212 27,616 j, ,, .... .... 60 Lescceur B. S. [2], 29, 483 34,718 ,, 1; .... .... jj 59-9 (753) Thorpe 37, 183 >j j> jj 57-59 Darling J., 21, 329 JJ jj 57-57-5 Perk in 45, 529 jj jj 64-8 (754-1) .... Pierre C. R., 27, 213 87, 183 jj 62 Steedel Z. C., 14, 197 24,696 jj jj j, 39-6 (400) jj B., 15, 2563 44, 302 jj jj 45-4 (500) B., 13, 840 jj j) u 50-7 (600) jj jj 55 (700) ,, jj j* jj 57-7 (760) .... jj 59-4 (800) .. JJ jj jj 63 (900) jj jj jj jj 66-3 (1000) jj 68-5 (1080) B jj Ethyl chloride CH 3 .CH 2 C1 C 2 H 5 C1 11 (758) b. 29 Pierre C. R, 27, 213 ii., 529 j. 12-18 Linnemaun A., 160, 214, 162, vii., 203 39 11-5 .... Stedel Z. C. [2], 8, 513 25,394 jj 11-12 Schorlemmer J., 17, 467 ,, 12 .... Thenard j> 10 Pictet P. M. [5], 1, 477 31, 163 jj jj u 11-13 Darling J., 21, 328 j. ,j jj 12 .... Denzel A., 195, 210 36, 368 jj jj u 12 Sabaneeft' B. S. [2], 34, 323 40, 399 jj 12-5 (760) .... Reguault M. A. S., 26, 658 j. j. .j jj 182-6 c. t. Sajotschewsky Wied. B. [1879], 45, 138 741 jj -3-6 (400) .... Stredel B., 13, 840 ; B., 15, 2563 96 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. Ethyl chloride CH 3 .CH 5 CI C^Cl + 17 (500) Stadel B., 13, 840 ; B., 15, 2563 i, >, 6-3 (600) u ., ? 10-3 (700) i) T, 1, j 12-5 (760) j ,, ., IJ 13-9 (800) > V .... )) j> 17-1 (900) ) )> ,, )> 20-1 (1000) n n 1, ,, .... 5) 22-3 (1080) 5) > Heptachlorpropane .... .... C 3 HC1 7 260 CaLours A., 76, 283 ; J., 3,496 Dichlorallylene .... C 3 H 2 C1 2 78 Liquid Judsoii Z. C. [2], 7, 40 24, 233 ; vii., 398 CH 2 : c : CGI, 78 .... Kramer and Pinner A., 158, 37 24, 557 Tetrachlorpropylene .... C 3 H.,C1 4 165 .... Borsche and Fittig A., 133, 118 vi., 28 Hexachlorpropane .... C 3 H 3 C1 6 250 Liquid Schorlemmer vi., 958 ,, .... .... ) 240-245 Cahours A., 76, 283; J., 3,496 Propargyl chloride CHic.CH 3 a C 3 H 3 C1 65 .... Henry B., 8, 398 a-Trichlorpropylene .... C 3 H 3 C1 3 115 Borscue and Fittig A., 133, 117 vi., 28 ?- .... J> 120 Pinner B., 8, 960 29,57 *- 138-140 ) B., 5, 207 vii., 1020 /3- .... )J 142 Pfeffer and Fittig A., 135, 361 Pentachlorpropane cci 2 : CjH,cij CACI, 194 Borsche and Fittig A., 133, 116 vi., 28 isomeric Solid !> A., 133, 123 ) ,, .... ) 220-225 Cahours A, 76, 283 ; J., 3, 496 w 03X1^012 79-85 .... Friedel and Silva C. R., 74, 805 25, 399 Allylene dichloride Me.CCl. : CHC1 J) 75 n v C. R., 75, 81 25, 80.') .... J5 J 76 r> C. R., 73, 957 25, 806 J) 75 V C. R., 74, 806 vii.. 1019 ,j .... .... J )J 77 .... Lieben and Zeisel M. C., 4, 531 44, 964 i> ) I> 78 A, 158, 47; 179, 44 AUylidene CHCLCHICH, J) 84-4 Hiibner & Geuthei- A., 114, 37 i., 147 ; vi., 97 ,, .... .... J) 85 Roinborgh B. S. [2], 36, 549 42, 376 ,, ,, 88 Romborgh B. S. [2], 37, 98 42, 590 -Dichlorpropylene .... CH 2 a.cci:cH 2 93 Friedel and Silva C. R., 73, 957 24, 1190 ; vii., 1019 a- u *) 04 ?i w C.R.,74,805;75,81 25, 805 - j> J 91-97 Claus A., 170, 126 25, 399 a- ! 94 Reboul C. R., 95, 993 44, SOS - ' 1 94-96 Henry C. R., 94, 1428 42, 103!) - 1 )> 95 .... n C. R., 95, 849 44, 173 - )J ) 94-95 .... 27, -243 a- 97-98 Henry B., 5, 965 /3- CHjCLCH : CHOI 101-102p.il. Reboul J.; 13, 460 ii., 899 )J n > 102 Geuther Z. C. [1865], 26 vi., 56 ,, n J 101 Berthelot A., 155, 10") vii., 3)9 0- } 105-107 Friedel and Silva C. R., 75, 85 25, 805 ; vii., 1019 18- jj ?> 109 Krestownikoff B., 12, 1487 38, 235 ft- * ?j 1) 109 Liquid Hartenstein J. p. C. [2], 7, 295 26, 1218 ft- ji ) 109-1 10 c. Liquid Roniliorgh B. S. [2], 36, 549 42, 376 y- " (1 abt. 120 Berthelot and Luc;i A. C. [3], 52, 438 1, 894 y- )J 120 Boi-sche and Fittig A, 133 vi., 97 Allylene tetrachloride .... c,H 4 ca 4 150 Pinner B., 10, 1057 32, 587 ,, ,. CH 2 C1.CC1 2 CH S CI ) 153 Borsche and Fittig A., 133, 115 vi., 27, 97 153 Ganswindt I. D., Jena, 1873 ,, CH 2 Cl.CCl 2 .CH 2 a 164-165 Henry C. R., 94, 1428 42, 1039 Tetrachloroglycide > 164 Pfeffer and Fittig J., 18, 504 vii., 1020 (') 164 Borsche and Fittig A., 133, 111 vi., 97 COMPOUNDS CONTAINING THREE ELEMENTS. 97 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. (?) .... C 3 H 4 C1 4 164 Berthelot A., 155, 105 vii., 319 (?) .... )J 161-164 A., 155, 108 j> (?) From acetone J) 165 j Allylidene tetrachloride .... ) 171 Liquid Hartenstein J. p. C. [2], 7, 313 42, 376 ji I) 180 (766-4) Liquid Komborgh B. S. [2], 36, 549 j) H .... )I 179-180 (756-6) Tetrachlorpropane .... )J 179-180 i) (756-6) .... .... 177-178 s. t. Schorlemmer P. R S., 18, 29 vi., 958 .... 180-190 145 Berthelot A., 155, 109 vii., 319 ,, .... 1J 195-200 11 .... .... 5> 195-200 .... Cahours A., 76, 283 ; J., 3,496 -Chlorpropylene CH 2 :CCl.Me C 3 H 6 C1 25-5 Oppenheim A., 140, 204 vi., 91 ; vii., 1019 .... .... I> 25-35 5 1 riedel& Ladenburg A., 142, 310 vi., 826 .... .... )? )) 30 .... Friedel J., 12, 338 )) )> 23 Linnemann A., 138, 125 vi., 967 ? J 23 Oppenheim J., 21, 339 ,, )) 25-28 Friedel and Silva C. R, 74, 955 24, 1190 n 25-30 )) B. S. [2], 17, 532 vii., 1019 >J 23-25 Reboul C. R, 82, 377 29, 894 ,, .... .... j > 23-25 .... jj A. C. [5], 14, 453 36, 128 jj JJ 25 ,, .... .... j) ) 25-30 .... T) )> 36, 131 |3- CHOI : CH.CH 3 5J 33-35 C. R, 82, 377 29, 894 ,, .... .... )! ) 35-36 Liquid )> A. C. [5], 14, 462 36, 128 Allylchloride CH 2 . :CH.CH 2 C1 44-45 Oppenheim A., 140, 206 vi., 9i 45-5-47 Tollens A., 156, 155 44-6 BrUhl A., 200, 179 38, 296 44-5-47 Zander A., 214 45-46 c. Perkin 45, 541 45-5 Pawlewski B., 16, 2633 46, 252 240-7 c. t. Chloracetone dichloride CHjCI.OClj.CH, C 3 H 5 C1 3 122-126 Friedel and Silva C. R, 74, 955 24, 1190 ji v )) 125 i C. R, 74, 806 25, 399; vii., 1018 j 123-127 .... Bielohoubek B., 9, 924 j> ;> 127 Friedel C. R, 59, 294 vii., 1019 loracetone monochloride CHC1 2 .CHC1.CH 3 137 B. S., 34, 129 j )> ) 140-145 Berthelot A., 155, 105 vii., 319 !J ) j? lift Friedel and Silva C. R, 74, 805 25, 399 Isotrichlorhydrin CH 2 C1.CH 2 .CHC1 2 144-148 Krestownikoff B., 12, 1487 38, 234 ,, ) )> 146-148 Romborgh B. S. [2], 37, 98 42,590 Trichlorhydrin CH 2 C1.CHC1.CH 2 C1 j) 155 Berthelot &de Luca J., 10, 477 i., 894 ,, .... .... 5 > 154-157 Linnemann A., 136, 51 vi., 965 J) i> 155 .... Berthelot A., 155, 105 vii., 319 ji .... .... )) 155 Friedel and Silva C. R., 74, 805 25, 399 ,, j> 156-157 u.e.; Perkin 45, 532 157-158 c. >i .... .... 153-157 .... Bielohoubek B., 9, 924 J> 154-157 b. 10 Oppenheim B. S. [2], 2, 97 vi., 91 )> 150-160 Schorlemmer P. R S. vi., 958 Trichlorpropane rrom isopropyliodide ;> 150-160 Berthelot A., 155, 105 vii., 319 5) -... propane j> 150-160 vii., 320 .... 170 ? j? vii., 319 .... i 170 Cahours J., 3, 496 Methylehloracetol CH 3 .CC1 2 .CH 3 (?) CaHjClo 25-35 Friedel and Silva C. R., 74, 806 vii., 1018 Dimethylclichlormethane .... CH 3 .CC1 2 .CH 3 > 66-78 Friedel & Ladenburg A., 142, 315 vi., 826 98 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Dimethy Idichlormethane . . . . CH 2 .CCLCH, 69-70 Eeboul C. ft., 74, 669, 944; vii., 51 ; 25, A.C. [5], 14, 453 393 ; 36, 128 ,, 68-5-69-5 c. Perkin 45, 529 j, u H 69-7-71-8 c. 7) >> ) 69-69 Liunemann A., 161, 67 ,, i ) 69 j A., 138, 125 ,, j> > abt. 70 Friedel and Silva C. B., 73, 1379 25, 134 Ethyldichlormethane CH 3 .QH 2 .CHC1 2 jj 84-87 Eeboul C. E., 76, 1270 26, 1016 > V ) 85-87 C. E., 82, 377 29, 894 D > 85-87 .... A. C. [5], 14, 458 36, 128 (?) .... 90 Friedel and Silva Z. C. [2], 7, 489 25, 296 Propylene dichloride CH 2 CLCHC1.CH 3 N 94-98 .... Schorlemmer P. E. S. vi., 958 jj 1; M )) abt. 96 Friedel and Silva C. E., 73, 1379 25,134;vii.,1018 ,, )) )j 96 >! )) Z. C. [2], 7, 489 25, 296 J n 96-82 c. .... Liunemann A., 161, 43 25, 238 ,, jj 93 .... Jeltekow B., 6, 558 26, 1016 ,, ^ )) > 96-97 Reboul A. C. [5], 14, 453 36, 128 ,, Mixture (?) i> 100-103 .... Eeynolds J., 3, 495 s 104 .... Cahours J., 3, 496 ,, ,j j) 103 .... Wurtz .... v., 893 ,) )> > 104 .... Berthelot A., 155, 105 vii., 319 ,, * CH 2 C1.CH 2 CH 2 C1 117 Eeboul C. E., 76, 1270 26, 1016 D ,, Jt i 119 > A. C. [5], 14, 460 36, 128, 133 1) j 119-5 (740) Liquid .... W. A., 2, 638 (?) .... 200 Berthelot A., 155, 105 vii., 320 Isopropyl chloride CH 3 .CHC1.CH 3 C 3 H 7 C1 37 (741) v., 890 ,, ,, ) 35-38 Zander A, 214, 157 ,, )T 36-38 (741) Linnemaim J., 18, 489 vi., 965 )) v n )) 36 .... Friedel and Silva C. E., 73, 1379 25, 134 u ,. j )> abt. 36 Silva C. E., 93, 739 42, 294 i ) jt )) 36 ) Z. C. [2], 7, 489 25, 296 11 .... )> b. 39 Linnemaim A., 161, 43 25, 236 n j, n J) 36-37 (730) .... >i 25, 238 35 c. Perkin 45, 450 Propyl chloride CHa-CH^CH^Cl )} abt. 40 Berthelot J., 8, 613 44-45 c. Perkin 45, 450 )) 42-46 Schorlemmer P. E. S., 17, 372 vi., 957 J> )) 52 Chancel J., 22, 359 vi., 964 )> > f] J) )> 46-5 Pierre and Puchot A. C. [4], 22, 281 vi.,9li4;vii.,1013 46-5 C.'. E., 7i>, 832 24, 809 J) )) 46-48 Liunemann A., 162, 39 vii., 203 )) J) 46-36 A., 161, 26 25,23r,;vii.,1013 >* 9) AG-AA J) *f^ r ft 44-46'S Zander A., 214, 157 Jt >J 44 Briihl A., 200, 139 38, 296 Tetrach lorcrotonylene J -... < C 4 H 2 C1 4 200 Judson Z. C. [2], 7, 40 24, 234 " )1 130-140 Liquid jj Z. C. [2], 7, 40 vii., 401 Pentachlorobutylene 4 H 3 C1 6 185-188 (460) Liquid Loidl B., 8, 1017 29, 365 Crotonyleue dichloride Me.CH 2 .CCl : CHC1 C 4 H 6 C1 2 125 Liquid Kekule Z. C. [2], 5, 572 vi., 513 )J 5J " )* 1) 125-127 Liquid ) A., 162, 98, 309 vii., 401; 25,616 Butine tetracliloride C 4 H.C1 4 73 B. S., 34, 195 Trichlorbutyl chloride 85 (10) Liquid Thurnlackl A., 213, 372 42, 1279 Chlorisol mty lene Me 2 C:CHCl C 4 H 7 C1 66-70 CEconomides C. R, 92, 884 40, 709 v Ji ) 65-68 40, 710 () ) a. 100 Chancel A. C. [3], 12, 416 i., 689 Ethylmethyl dichlormethane CH 3 .CC1 2 .CH 2 .CH 3 C 4 H S C1 2 95-97 Bruylants B., 8, 412 Isobutylidene dichloride .... 103-105 p. d. (Eeonomides C. E., 92, 884 40, 710 Butylene dichloride .... .... j> 120 .... De Luynes .... v., 736 )> > 122-3 .... Kopp A. v .... >j 123 .... Kolbe A., 69, 275 v., 739 COMPOUNDS CONTAINING THREE ELEMENTS. 99 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. WattsTOict. & J. Ch. Soc. Butylene dichloride .... C 4 H S C1 3 125 Faraday P. T., 182, 440 v., 739 55 55 .... 55- 129 Puchot A. C. [5], 28, 507 46, 167 130-135 Wurtz C. R, 97, 473 46, 169 Butyl chloride CH 3 .CH 2 .CH 2 .CH 2 C1 C 4 H 9 C1 77-6 (741-3) Lieben and Rossi A., 158, 137 34, 520; vii., 216 55 55 "" 77-96 c. .... Linnemann A., 162, 39 vii., 203 55 55 77-96 c. 11 A., 161, 197 25, 396 55 55 77-78 Pagliani G. I., 8, 1 34, 654 ,, 72 .... J. p.C. [2], 24, 118 55 55 " " abt. 70 Wurtz A., 93, 113 v., 735 55 55 "' " 70-75 11 J., 7, 572 55 55 70 .... Gerhard A., 122, 363 vi., 108 55 55 "' "' 69 Pierre and Puchot A. C. [4], 22, 310 Isobutyl chloride CHMe 2 .CH 2 Cl 69-6 55 G. J. G, 1872 67-69 Linnemann A., 162, 17 25, 476 68-6 c. .... 51 JJ 55 ;5 j> 68-5-69 c. Perkin 45, 451 j) 65-70 Pelouze & Cahours J., 16, 524 55 55 66-5-69 Freund J. p. G [2], 12, 25 29, 543 55 15 60 (760) Pierre and Puchot C. R, 72, 832 24, 809; vii., 218 Butyl chloride CClMe 3 55 .... Puchot A. G [5], 28, 507 46, 167 55 55 ,, 51-52 c. Perkin 45, 451 . 50-53 Freund J. p. G [2], 12, 25 29, 543 55 50-51 Zalessky B., 5, 480 55 55 46-52 Linnemann A., 162, 18 25,476; vii., 220 Chlornicene C 5 H 5 C1 292-294 St. Evre J., 1, 530 (0 Gj-fcLgGl.i ( f ) C 5 H 6 C1 2 (?) 144-148 Pinner B., 8, 1326 29, 554 Tetrachloramylene C 6 H 6 C1 4 a. 200 Earth A., 119, 216 vi., 108 Trichloramylene .... C 6 H 7 C1 3 abt. 200 Bauer J. [1860], 405 vi., 121 Dichloroamylene C 5 H 6 CL, (?) C 5 H 8 C1 2 (?) 144-148 Pinner B., 8, 1326 29, 554 146 11 B., 10, 1052 Isoprene dichloride .... 145-153 Bouchardat G R, 89, 1117 38, 323 Tetrachlorpentane .... C 6 H 8 C1 4 220-230 Liquid Bauer Z. G [1866], 380, vi., 118, 120 667 55 .... 230-250 d. 51 J. [1860], 405 vi., 120 55 .... 5) 230-240 11 G R, 51, 572 vi., 116 Isoprene hydrochloride .... C 5 H 9 C1 86-91 Bouchardat G R, 89, 1117 38, 323 Chloramylene 90-95 Bauer Z. G [1866], 380, vi., 118 667 55 abt. 95 Friedel A. C. [4], 16, 366 vii., 1022 55 .... )} 87 Bruylants B., 8, 411 - Valerylene hydrochloride .... .... J5 abt. 100 Reboul Z. G [1867], 173 vi., 1123 Trichlorpentane .... c 5 H 9 a 3 160-190 Bauer Z. G [1866], 380, vi., 118 668 55 - 185-190 Buff J., 21, 334 Isoamylidene chloride CHMe 2 .CH,,CHCl 2 C 6 H 10 C1 2 130 Ebersbach A., 106, 265 vi., 120 55 55 is 138-130 Bruylants B., 8, 413 Dichlorpentane Pr.CCl.,Me abt. 140 .... Friedel A. G [4], 16, 366 vii., 1022 55 55 145 .... 55 B., 8, 413 Amylene dichloride .... 145 Bauer Z.G [1866], 380, vii., 118 668 55 55 .... 141-147 Guthrie 14, 128 vii., 120 Pentine dihydrochloride C 5 H 9 .2HC1 145-150 Tilden 45, 414 Valerylene dihydrochloride 55 150-152 Reboul Z. G [1867], 173 vi., 1123 Chloramyl chloride .... 55 155-160 Buff A., 148, 350; J., 21, 333 Amyl chloride Me.(CH 2 ) 3 .CH 2 Cl C 5 H n Cl 106 (740) Lieben and Rossi G. I., 1, 314 vi,, 1137 51 55 a 55 106-6 (740) .... 5) 55 A., 159, 72 24, 1033 .5 55 .... 11 5) 112 Romborgh R. T., 1, 151 44, 303 55 55 ' ' 55 106 Lachowicz A., 220, 188 46, 166 55 55 j; 11 104 55 5, 55 55 55 .." ... CHClEtj 55 103-105 Wagner & Saytzeff A., 179, 321 29, 548 100 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Amyl chloride CHClMePr* C 5 H U C1 103-105 Wagner & Saytzeff A., 179, 321 29, 548 (inactive) CHMejCEUCHjCl j 100-5 Plimpton C. R, 91, 433 40, 33 n 1) 100-5 chiefly H .... 39, 332 )) ,, .... .... 101 Schorlemmer P. E. S., 15, 131 vi., 107 )) 1) 100-9 c. (745-6) Carius and Fries A., 109, 1 vi., 110 ,J J, ) ) 101-75 (752) Pierre J. [1851], 51 )j )i 100-102 Schorlemmer P. T. [1872], 111 vii., 63 ,, 5) " i )) 100 Lachowicz A., 220, 188 46, 166 ,, )j jj 100 Plimpton & Graves 43, 123 ,j ,, .... 102 Cahours J. P., 22, 172 i., 203 ,, ,, PI )j 100-101 Balard A. C. [3], 12, 300 5, ,1 " " 100-6-101 Kopp A., 95, 337 J) 98-103 Pelouze & Cahours J., 16, 524 ,, 11 102 Schorlemmer 28, 308 1) ) TJ 98-9 (733-8) Balbiano G. I., 6, 229 31, 293 ,, ,, )I ) 97-99 c. Perkin 45,452 .... 95-100 Schorlemmer P. T. [1872], 111 vii., 63 11 )) Primary, active i) 97-99 B. S., 25, 546 Iso- )i 90 .... Wurtz J., 16, 516 ,, CHOlMePi^ )> abt. 90 Berthelot C. E., 56, 700 vi., 114 1) ) j 86-87 .... Butlerow B., 10, 408 32, 589 OOEtMe, j) 86 Wischnegradsky B., 10, 405 32, 420 )) J) " )) ) 85-87 A., 190, 336 34, 394 j i 86-87 Liquid Winsgradow A., 191, 131 34, 484 )> 11 85-86-5 Perkin 45, 452 ,, .... j 85-86 Flawitzky B., 6, 562 26, 1014 > )) '" " .... j 85-86 A., 169, 205 27, 139 Pentachlorbenzene ^ .... C 6 HC1 5 275 Jungfleisch B. S. [2], 9, 346 vi., 264 ,, (?) 175-198 (?) .... 26, 167 ,, .... JJ 270 )> Z. C. [2], 4, 484; J., 20, 36 () .... 272 74 j A. C. [2], 15, 186 vi., 266; vii., 141 .... I) .... 85 Otto Z. C. [2], 6, 36 vi., 264 >' .... JJ 85 A., 154, 182 vii., 142 ,, .... JJ 275-277 85-86 Ladeuburg B., 5, 790 26, 167; vii., 142 ,, .... .... )) .... 175 Jungfleisch J. [1868], 357 vi., 266 WO .... (?) 175 ?) A. C. [4], 15, 186 vii., 141 (0)(?) .... .... (?) .... 198-199 Otto A., 154, 182 vii., 141, 142 175 a. f. Tetrachlorbenzene C1 4 = (?) C,H 2 C1 4 245 .... Jungfleisch B. S. [2], 9, 346 vi., 264 i =1.2.4.5 5 240-250 139 Beilstein and Kuhl- Z. C. [2], 5, 529 vi., 284 berg .... ii 240 139 Juugfleisch A. C. [4], 15, 277 vi., 266; vii., 141 ,, .... v J 24S-246 c. 137-138 Beilstein and Kur- B., 9, 579 30, 294 batow " )) 243-246 137-138 i> 15 B., 10, 270 31, 707 ,, .... .... =1.3.4.5 246o. 50-51 B., 9, 579 30, 294 '> Jl 1) 246 c. 50-51 )> 5) B., 10, 273 ; A., 31, 707 192, 237 )J J) } .... 50-51 B., 11, 1862 36, 144 (impure) 1> 253 35 Otto and Ostrop A., 141, 105 vi., 266 11 )5 253 35 Juugfleisch A. C. [4], 15, 186 vii., 141 ., J> )) ... - 33 Otto A. )) 5) )i 245-248 27-28 Ladenburg B., 5, 790 36, 167; vii., 142 =1.2.3.4 J) 254 45 Beilstein and Kur- B., 9, 1688 31, 474 batow 11 -... .... ) ! JJ $6+0. 45-46 > B., 10, 273 ; A., 31, 707 192, 238 COMPOUNDS CONTAINING THREE ELEMENTS. 101 Name. constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Tetrachlorbeuzene C1 4 =1.2.3.4 C 6 H 2 C1 4 42 Benedikt M. C., 4, 232 44,986 Trichlorbenzene C1 3 =1.3.5 C 6 H 3 C1 3 .... 60 Jungfleisch A. C. [4], 15, 264 vi.,266;vii.,141 JJ JJ 63-4 Korner G. I., 4, 305 29, 224 JJ )J 208-2 c.(763-8j 63-5 Beilstein and Kur- B., 8, 1655 29, 713 batow , JJ JJ 208-5 c.(76S-8) 63-5 B., 10, 271 ; A., 31, 706 192, 232 JJ JJ 63-64 Wenghoffer J. p., 2 [16], 448 34, 297 =1.2.3 218-219 53-54 Beilstein and Kur- B., 9, 1688 31, 474 batow )J JJ 218-819 53-54 >! )! B., 10, 272 ; A., 31, 707 192, 234 ., =1.3.4 206 16-17 Jungfleisch A. C. [4], 15, 186 vi.,266;viL,141 JJ 213 c. 16 Beilstein and Kur- B., 8, 693 28, 1037 * batow JJ )J 213 c. 16 11 B., 10, 270 ; A., 31,706 192, 229 = (?) 210 b. Mitscherlich P. A., 35, 372 vi., 266 , = (?) 207 s. b. Heys Z. C. [2], 3, 122 24, 1028 = (?) 51 210 Liquid Laurent A. C. [2], 63, 27 i., 543 ,, = (?) 11 210 .... Jungfleisch B. S. [2], 9, 346 vi., 264 Dichlorbenzene C1 2 =1.4 C,H 4 C1 2 52-821 Mills P.R.S.[1881],205 ,1 i, J) 53-54 Kekule & Barbaglia B., 5, 875 26, 278 11 11 11 J> 172 Muller Z. C. [1864], 401 vi., 265 11 .... 53 Petersen A., 157, 171 24, 249 ii 11 11 JJ 171 53 Jungfleisch A. C. [4], 15, 186 vi.,265;vii.,141 11 J! JJ 173-174 53-54 Kekul6 B., 6, 944 vii., 918 11 11 .... 53 Beilstein and Kur- B., 7, 487 27, 806 batow 11 11 JJ 172 53 B., 7, 1397 28, 363; vii., 905 11 11 172-174 53 Nolting B., 8, 1091 29, 81 11 11 JJ 172 53 B., 8, 819 29, 928 11 11 J) 173-4 (757-6) 56-4 Korner G. I., 4, 305 29, 215 =1.3 172 Beilstein and Kur- B., 7, 1760 28, 450 batow JJ " ,, JJ 172 A., 182, 94 30, 631 11 u 172-173 B. S., 23, 179 JJ 11 1) 172-1 (742-4) Liquid Korner G. I., 4, 305 29, 215 j, M 11 )j 170-171 Witt B., 7, 1602 28, 759 ,,= 1.2 JJ 179 1. 19 Beilstein & Kurba- B., 7, 488 27, 806 tow JJ " JJ 179 c. I. -14 B., 7, 1398 28, 364 ; vii., 906 J JJ JJ 179 B., 7, 1760 28, 450 ,, JJ J) JJ 179 A., 182, 94 30,631 ,, JJ jj 179 Liquid Korner G. I., 4, 305 29, 233 JJ .... .... ,i = (?) J) abt. 175 .... Jungfleisch B. S. [2], 9, 346 vi., 264 =(?) J) 175 b. A. C. [4], 15, 186 vi.,266;vii.,141 hexachloride C 6 H 4 CL,C1 6 C 6 H 4 C1 8 (?) Z. C. [2], 4, 484 vi., 264 u J5 JJ 255-257 Otto Z. C. [2], 6, 36 vi., 264 j) ji J) )J 255-257 Otto and Ostrop A., 141, 105 Chlorbenzene C 6 H 5 .C1 C 6 H 5 C1 137 Riche A,, 121, 357 iv., 415 136 Williamson and 7,238 JJ Scrugham 136 (767) Sokoloff J., 18, 517 vi., 265 )J 132-4-132-6 26, 886 11 (760) 131 40 Jungfleisch A. C. [4], 15, 212 vii., 140 11 " 131-5-131-97 Adrienz B. 6,443 26, 886 11 (760) 102 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Chlorbenzene C 6 H 5 C1 C 6 H 5 C1 1S2-4-132-B8 Adrieuz B., 6, 443 26, 88 (760) ?> )J 131-4-132 .... Briihl A., 200, 139 38, 296 .... i> 5) (744) 134-5-135 Eamsay 39,64 (?) aaa. 218 Kurbatow B., 16, 966 ^6 S^-^a Chlorbenzene hexachloride ... c 6 H 6 ci.ci 8 C 6 H 5 7 (?) 255-257 Otto and Ostrop A., 141, 105 vi., 264 Chloralbin C.H.C1, 190 Solid Laurent R. S., 6, 72 i *} v ^6 J -*-6 vx 2 *.) OOO Benzene hexaehloride .... C 6 H 6 C1 6 288 132 Mitscherlich P. A., 35, 374 i., 543; vii., 132 ,, .... 1) 135-140 Laurent A. C., 63, 27 It .... )) 157 Heys Z. C. [2], 7, 293 )) )> .... ..* J 157 Z. C. [2], 3, 122 24, 1028 .... (C 6 H 6 C1 6 ) .... 300 Meunier C. R, 98, 436 46, 733 Quercite pentachlorhydrin ... .... C 6 H 7 C1 5 102 Prunier C. R, 86, 338 ; 34, 400; 36, 241 A. C. [5], 15, 5 Hexachlorhexane .... C 6 H 8 C1 6 285-290 Pelouze & Cahours J., 16, 525 Mesityl chloride C 6 H 10 C1 3 (?) C 6 H 9 C1 130 Baeyer A., 140, 298 vi., 822 Chlordiallyl 150 Liquid Henry C. R, 87, 171 36, 34 Allylmethylchloracetol C 3 H 6 .CH 2 .C.Cl 2 .Me )) t-'eHioCl, 150 p.d. Liquid )5 ,, Diallylhydrochloride .... C 6 H n Cl 130-140 Wurtz J. [1864], 514 vi., 93 Chlorhexylene .... 122 (768) Liquid Henry C. R, 97, 260 46, 34 MejCC3.CH 2 CH I CH 2 109-114 Michael & Saytzeff A., 185, 156 32, 299 70-71 Liquid Destrem A. C. [5], 27, 5 Rl K 99Q )1 , i ' ', .' Trichlorhexane .... C 6 H U C1 3 215-218 Pelouze & Cahours J., 16, 525 Diallyl dihydrochloride .... C 6 H 12 C1 2 170-180 Wurtz J. [1864], 512 vi., 93 Hexylene dichloride .... )> abt. 160 Friedel Z. C. [2], 5, 485 vi., 946 ,j .... ) 162-165(764) Liquid Henry C. R, 97, 260 46, 34 .... u 180-184 Pelouze & Cahours J. 16, 525 j. Mej.CCl.CCl.Me,, j> 160 Friedel and Silva B., 6, 35 n )) 160 Sohorlemmer A., 144, 187 Hexyl chloride Me.(CH 2 ) 4 CH 2 a c.H 13 a abt. 133 Lieben & Janecek A., 187, 139 32, 881 ?! abt. 130 Freutzel B., 16, 745 44, 1075 ?) ,, j> 125-130 .... Geibel and Buff Z. C. [2], 4, 179 vi., 699 i) ,, j> j> 125-130 Buff Z. C. [2], 4, 730 .... ) 125-128 .... Cahours & De marjay C. R, 80, 1570 i )i .... j) 125-128 Pelouze and Cahours J., 16, 525 .... - 120-130 .... Wanklyn & Erlen- J., 17, 509 16, 221 meyer n " .... >! 126-130 .... Schorlemmer P. T. [1872], 111 vii., 645 i )> .... .... IJ 125-126 55 )> ,, .... .... .... ) 125-126 .... A., 161, 272 ; J., [1864], 509 .... a- .... J> 124-125 .... A., 199, 141 n ,, Me.CHa.(GHJ s Me 124 .... Schorlemmer A., 199, 139 38, 158 i 122-124 .... Morgan 28, 303 > jj .... .... .... I) 123-5 .... M. C., 2, 313 .... 0- .... ) abt. 120 Wanklyn & Erlen- 16, 221 iii., 153 meyer ,, .... From Prf.Prf 1) 124 .... Silva B., 7, 953 JJ )J .... 5 )) 118 .... )i )) )J .... .... )> !) 122 Schorlemmer A., 144, 186 ; J., 20, 567 )) )J .... . . .... J> 122-124 LeBel B., 5, 216 ; B. S. 18, 167 1> ' .... JJ 121-122 .... C. B., 75, 267 25, 886 U 5) .... 116-118 .... Morgan 28, 302 .... fi- ~~ 3) 116-118 A., 177, 305 ll 11 ... .... ..** )> 115-117 LeBel B., 5, 216;B. S., 18, 167 1 .... )I 111-113 53 C. R, 75, 267 25, 886 COMPOUNDS CONTAINING THREE ELEMENTS. 103 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Hexyl chloride CClMe 2 .CHMe 2 C 6 H 13 C1 11^5-114-5 Friedel and Silva C. E., 76, 226 26, 489 ; viL, QQ9 )) ) 3) M 112 Eltekow J.B. [1882], 1,355 VOX B., 16, 399 D u 33 )) abt. 112 s. 2 Kaschirsky B., 11, 984 36, 46 !) ?) 33 )) 110-112 s. 2 C. C. [1881], 278 43, 37 33 ,, .... 33 )> 115 Fernbach B. S. [2], 34, 146 40, 146 ,, )) 112 s. 14 Pawlow B., 11, 513 34,563 ,, CClMeEt 2 j) 110 d. 1. f. m. Butlerow B. S. [2], 5, 24 vi., 698 j) 3J CClMejPr 100 d. 1. f. m. j> M Tetraclilorbenzo- trichloride C 6 HC1 4 .CC1 3 C 7 HC1 7 316 p. d. 104 Beilstein and Kuhl- A., 150, 308 vi., 284 berg Pentachlorbenzylene chl oride CeCls.CHCl., J3 334 110 A., 150, 306 n Pentachlorbenzyl chloride .... C 6 C1 6 .CH 2 C1 C ? H 2 C1 6 abt. 325 108 j j> Z. C. [2], 4, 561 vi., 283 33 )3 325-327 103 *j A., 150, 302 Tetrachlorbenzylene dichlor- C 6 HCL,CHC1 2 306 Liquid ) ii ide 33 33 305-306 D Z. C., 21, 364 ; A. 150, 303 Trichlorbeuzo- trichloride .... cysA-CQ, 33 298 82 Z. C. [2], 4, 561 vi., 283 33 33 33 307-308 82 )? A., 150, 305 Pentachlortoluene C 6 C] 6 .CH 3 C 7 H 3 C1 6 301 218 j) Z. C. [2], 4, 277 vi., 283 Tetrachlorbenzyl chloride .... G 6 HC1 4 .CH 2 C1 )3 296 Liquid )> j A., 150, 299 3> )J )3 296-297 u Z. C., 21, 362 Trichlorbenzylene dichloride C 6 H 2 C1 3 .CHC1 2 285 Liquid Z. C. [2], 4, 277 vi., 283 s 3j 1J 280-281 s. > )) Z. C., 21, 362 ; A., 150, 299 Dichlorbenzo-trichloride C 6 H 3 C1 2 .CC1 3 33 277 Liquid Z. C. [2], 4, 277 vi., 283 33 33 31 JJ 273 j) Z. C., 21, 363 ; A., 150, 300 n J3 )3 273 Aronheim and Die- B., 8, 1403 trich Tetrachlortoluene C C HC1 4 .CH 3 C 7 H 4 C1 4 276 96 Limpricht A. v., 856 ,, 33 )3 276-5 c. 96 Beilstein and Kuhl- A., 150, 287 ; A., berg 139, 287 ,, )3 13 270 92-95 i> )> Z. C., 11, 276 vi., 282 ,, 33 255 Limpricht J., 19, 595 (isomeric) 33 280-290 .... .... A., 142, 305 Trichlorbenzyl chloride C 6 H 2 C1 3 .CH 2 C1 >3 273 Liquid Beilstein and Kuhl- A,, 150, 290 vi., 282 berg o-Dichlorbenzylene dichloride C8H3C12.CHOJ )> 257 Liquid A., 150, 294 Chlorbenzo-trichloride C 6 H 4 C1.CCL=1.4 33 245 Liquid A., 150, 295 M 3? 33 =1-3 )3 250 t,Q Limpricht A., 139, 326 v., 856 33 33 JT 33 31 244-246 A., 134, 58 13 33 33 33 3? 246-248 )) 33 V 33 33 33 (?) Kammerer and A., 131, 158 Carius )1 1) ... 33 J3 33 (?) Caliours As., 2, 254 33 33 =1.2 3) 260 30 Kolbe & Lautemann A., 115, 195 v., 856 Trichlortoluene C 6 HjMeCl 3 =l. 2.4.6 C 7 H 5 C1 3 235 73 Aronheim &Dietrich B., 8, 1405 29, 392 ,, 5f 33 237 75-76 Limpricht A., 139, 326 vi., 282 ,, 3J 51 (?) (?) Beilstein and Kuhl- A., 146, 325 berg ,, =? 237 Liquid Aronheim and B., 8, 1405 29, 392 Dietrich ,, .... =1 227-228 Henry J., 22, 508 Dichlorbenzyl chloride C 6 H 3 C1 2 .CH 2 C1 !! 240p.d.(760); Naquet As., 2, 248 v., 855 135-145 (10) V 33 M )) 241 Beilstein and Kuhl- A., 146, 327 vi., 282 berg 11 J, )3 )J 241 1 .... Limpricht A., 139, 326 :'.:- 104 OKGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Chlorbenzylene dichloride .... C 6 H 4 C1.CHC1 2 =1.4 C,H 6 C1 3 234 .... Beilstein and Kuhl- A., 146, 327 vi., 281 berg 11 i )> 255-260 Hubner and Bente B., 6, 804 11 =1.2 )J 227-230 Henry B., 2, 136 vi., 282 Benzo-trichloride C 6 H 5 .CC1 3 )5 215-218 Liquid v., 856 11 5, 3> J) 213-214 Liquid Beilstein and Kulh- A., 146, 333 vi., 282 berg 1, 1 J> 224 Limpricht A., 135, 80 ; 139 323 ; J., 19, 594 11 51 1J 5) 216-218 i A., 134, 55 ; J., 18, 539 11 .... (?) Schisehkoff & Rosing J. [1858], 279 1) )> (?) .... Cahoura As., 2, 306 D chlortoluene C 8 H 3 MeCl 2 = 1.3.4 C 7 H B C1 3 196 Liquid Beilstein & Geitner A., 139, 341 vi., 281 1 ) 197-199 Liquid Neuhof Z. C. [2], 2, 653 )J >i 11 11 U 196-198 ' .... Aronheim and B., 8, 1402 29, 392 Deitrich ,, = (?) TJ 202 Beilstein J., 13, 412 ,, = (?) J) 195-200 .... Wroblewsky and Z. C. [2], 6, 164 vii., 1167,1177 Pirogow ,, = (?) ^J 206 Wicke A., 102, 356 )i .... .... = (?) II 207 Limpricht J., 19, 593 Chlorbenzyl chloride C 6 H 4 .C1.CH 2 C1 = 1.4 11 29 Jackson and Field B., 11, 904 36,62 11 11 )1 ! 29 Jl 51 A. C. J. [2], 85 40, 803 11 D ) 213-214 29 Beilstein and Kuhl- A., 147, 352 berg = (?) )> .... Liquid Beilstein and Geitner Z. C., 66, 307 40, 806 ji 11 = (?) 11 s. b. 200 Liquid Beilstein A., 116, 336 v., 855 i) >i = (?) >? 212-214 Liquid Neuhof Z. C. [2], 2, 653 vi., 281 Benzylene dichloride CeH^CHC^ >1 206-208 Wicke A., 102, 356 i., 577 >J !> 11 206 Cahoura A. C. [3], 23, 129 v., 855 11 1> )> 11 212-214 c. Hubner and Bente B., 6, 804 Dichlortoluene hexachloride C 6 H 3 MeCl 2 .Cl 6 C;H 6 C1 8 .... 150 A., 142, 305 Chlortoluene C 6 H 4 Me.Cl = 1.4 C,H,Cl 160-5 6-5 Hubner and Ma j ert B., 6, 794 26, 1136 77 158-161 Aronheim and B., 8, 1402 29, 392 )J II Deitrich 157-158 Beilstein & Geitner A., 139, 334 v., 854 J ^^ 1.3 11 156 Wroblewsky A., 168, 199 27, 55 jj = 1.2 11 156 Liouid Z. C. [2], 5, 460 vi., 281 J? ^ J.. 11 11 157 A., 156, 79 )> )> = (?) )! 164 c. Limpricht B.S.[1866],2,467 v., 854 >J ^^ \ / J> il., 107 Benzyl chloride C 6 H 6 .CH 2 C1 Jl 1) 170 Liquid Deville A. C. [3], 3, 178 i., 573 )> n 176 Liquid Cannizzaro A., 88, 129 i., 573; v., 854 i 51 > )? 183 Limpricht A., 139, 307, 337 v., 854 ,, >? ?> 174 (769) Schiff G. J. C., 1881 ,, ji 175 Letts .... 25, 447 ?i i )> 172-180 Frankland & Tomp- 37, 566 kins ,, i> 176 Ramsay .... 39,64 (?) .... 227-230 Spica G. I., 9, 555 38, 241 Diallyl carbinol chloride (CH 2 :CH.CH 2 ) 2 CHC1 C 7 H U C1 140-145 d. Saytzeff A., 185, 141 32, 298 Chlorheptylene From Pr)3.CO.Pr/3 C 7 H 13 C1 116 Liquid Chancel i., 698 ,, 5) >J 11 118-120 Liquid Henry B., 8, 400 ,, Pr.CO.Pr )1 141 Tawildarow B., 9, 1442 ., 11 155 c. Liquid Limpricht A., 103, 83 iii., 148 Heptylene dichloride From Pr*.CO.Pr C 7 H 14 C1 2 181 Tawildarow B., 9, 1442 ii ) 51 190 Schorlemmer 16, 426 "i., 144 1 1 ) 191 c. Limpricht A., 103, 81 iii., 148 Heptyl chloride Me.(CH 2 ) 5 .CH 2 Cl C 7 H 15 C1 159-2 (754) Liquid Cross A., 189, 3 32, 125 ,, .... i 175 Petersen A., 118, 74 iii., 144 COMPOUNDS CONTAINING THREE ELEMENTS. 105 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. -^^c^^* Reference. Watts' Diet. & J. Ch. Soc. Heptyl chloride . C 7 H 16 C1 151-153 Schorlemmer P.E.,14,164&46 vi., 696 ,, ,j .... M 150 11 16, 426 Hi., 144 ,, . 5) 148-152 Pelouze & Cahours J., 15, 386 ,, ) 140-142 Schorlemmer A., 166, 172 )> 149-150 11 26, 323 ,, . )> 149 11 P.R,14,164&46. vi., 696 J 146-148 11 JJ 11 ,, . )) 138-142p.d Morgan 28, 304 ,, >J 135-138(757 1. -15 Kaschirsky C. C. [1881], 278 42,37 ,, J 135-138 11 B., 11, 984 36,46 ,, )) 134-137 Grimshaw 26, 323 Secondary H 98 .... A., 136, 266; 21 7, From CHMe 2 (CH 2 ) 3 .Me 140-150 Grimshaw 152;J.[1863],52J A, 166, 166 26, 312 ,, " j> 144-158 Schorlemmer A., 166, 173 26, 320 ; vii., 643 , .... CHClMeCCH^CH..?^) >J 135-137 Liquid Rohu A., 190, 312 34,486 CClMe 3 .CMe s .... 130 Eltekow J.E. [1882], 1,355 B., 16, 399 ? j> 134 A., 209, 81 ? )) 135 Kaschirsky C. C. [1881], 278 42,37 J 136 Butlerow A., 177, 183 28, 1249 Dichlorstyrolene Ph.CCl : CHCl C 8 H 6 C1 3 SSI 11. c. Liquid Dyckerhoff B., 10, 531 32, 482 1) jj 225-231 Liquid 11 B., 10, 121 a -Chlorstyrolene Ph.CH I CHCl C 8 H 7 C1 (?) Blyth & Hofmann A., 53, 310; J. [1868], 411 0- Ph.CCl : CH., ) 199-204(766 Glaser A., 154, 166 vii., 1101 112 (40) Trichlorxylene C 6 HMe s Cl,=1.3.(?) 3 C 8 H 7 C1 3 254-256 Hollemann J., 18, 557 v., 1057 Dichlorxylene C.H 2 Me J Cl 2 =1.3.(?) s C 8 H 8 C1 2 222 St. of hand 11 11 11 = (?) )J 240-245 100 Lauth andGrimaux A., 145, 115 11 Tolylene dicliloride C 6 H 4 (CH 2 C1) 2 =1.2 ?> .... 54-8 Colson C. R., 98, 1543 46, 1000 = 1.4 240-245 d. 700 Grimaux A. C. [4], 26, 331 25, 817 >J 11 )' )> 230 00 Biedermann B., 5, 702 26, 1013 11 1) 5 )> 225 d. 03 Eaymann B. S., 26, 534 46, 1000 a-Phenylethyl chloride C 6 H 5 .CHC1.CH, OgrigOl 194 p. d. .liquid Engler and Bethge B., 7, 1127 28,65 ,, 11 J J) abt. 194 -liquid Emmerling& Engler B., 6, 1005 vii., 936 8- C 6 H 5 .CH 2 .CH 2 C1 ) 200-204 d. -liquid Fittig A, 156, 246 Tolyl chloride C 6 H 4 Me.CH 2 Cl=1.2 197-199 B.S.,26,534; 27, 498 11 11 =1.3 JJ 195-196 B. S., 26, 43 =1.4 )J 192 Z. C. [1867], 381 11 = (?) 193 Vollrath Z. C. [2], 488 v., 870, 1057 )) I! " I> )> 190-195 .... Lauthand Grimaux A., 145, 115 11 ,, ,. J) 1 192-196 Phillipe & Barbier A. C. [5], 7, 472 31,76 11 ,, ). J) 190-200 .... Van Dorp B., 5, 675 25, 1006 1> JT J) 190-195 Mazzara G. I., 9, 421 38, 161 Chlorxylene C c H 3 Me 2 Cl=1.3.(?) i? 183-184 Z. C. [1866], 488 Octylene dicliloride C 8 H 16 C1 2 abt. 235 d. Thorpe and Young A., 165, 16; B., vii., 892 ; 25, 5, 558 803 .... 206-210 .... Nieson .... 27,847 ,, From caprylene > 197-200 A., 106, 271 11 Me.CO.C 6 H 13 >J 190-200 11 Octyl chloride CH 3 .(CH 2 ) 6 .CH 2 C1 C 8 H 17 C1 l82-5-18S-5c. .... Perkin 45, 453 11 I! u 11 182 .... Cahours& Demar9ay C. R., 80, 1571 11 11 i> 11 179-5-180-5 Zinck6 A., 152, 4 vi., 878 11 11 11 175 Bouis A. C. [3], 64, 128 iv., 170 1> 11 Secondary I> 171-173 c. .... Perkin 45, 453 ,, )! .... 11 170-172 Schorlemmer 15, 419 v., 170 .... II 168-172 Pelouze & Cahours A., 129, 91 1! " 11 162-167 Wurtz J., 16, 509 ) 1) .... 11 168-174 Nieson ' S7, 848 1> CHClMe.C 6 H 13 11 173-176 Schorlemmer P. R., 16, 376 i ri., 879 T> 106 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Octyl chloride CHClEt.C 6 H n C 8 H 1? C1 174-176 Schorlemmer A., 152, 152 vi., 879 11 11 From CHMe 2 .(CH 2 ) 2 .CHMe 2 170-180 P. B. [1876], 34 31, 541 11 11 C 6 H n .Prf 165 11 P. B., 16, 37 vi., 105 CClEtjPra ,, 155 Butlerow B. S. [2], 5, 24 vi., 880 11 11 From CHMe 2 .(CH 2 ) 2 .(;HMe 2 145-150 p. d. A., 189, 52 34, 122 Styryl chloride .... C 9 H,,C1 b. 19 Bamdohr Z. C. [1858], 113 v., 447 Mesitylene trichloride C 6 H 3 .(CH 2 C1) 3 =1.3.5 C 9 H 9 C1 3 170-180 i.v.; Liquid Colson C. B., 97, 177 46,57 277-284 (760) p. d. Trichlormesitylene Me 3 .Cl 3 =1.3.5.2.4.6 204 Fittig&Hoogewerff Z. C. [2], 5, 168 vi., 299 11 > .... 208 Kurbatow B., 16, 966 Dichlorcumene (?) .... C 9 H 1( ,C1 2 265 Lallemand A., 102, 119 v., 795 Mesitylene dichloride Me.(CH 2 Cl) 2 =1.3.5 .... 41-5 Bobinet and Colson C. R, 96, 1863 44, 1095 >i ., 260-265 41-5 Bobinet C. B., 96, 500 44,577 Dichlormesitylene Me 3 .Cl 2 =1.3.5.2.4 243 59 Kahn 11 i, 11 *tt 59 Fittig&Hoogewerff Z. C. [2], 5, 168 vi., 299 Chlormesitylene C 6 H 2 Me,.Cl=1.3.5.6 C 9 H n Cl 205 i. .. 11 11 >i 204-S06 Bobinet C. B., 96, 500 44, 577 Mesityl chloride CTT TUff, rf^ITT f"* 1 !^ 1 Q K cijLo.iyjLeq.wjio^^'^ i.o.o 11 215-220 1 17 11 11 Camphryl chloride .... C 9 H 13 C1 205 Schwanert A., 123, 310 vi., 390 Camphoryl chloride - 175 11 11 Isophoryl chloride ,, 175 Liis-Bodart C. B., 43, 394 i., 733 Chlornonylene C 9 H 17 C1 175-185 Diew B., 16, 961 Nonylene dichloride C 9 H 18 C1 2 240-245 .... A., 165, 21 Nonyl chloride C,H I9 C1 190-198 Thorpe and Young 11 11 11 .... 196 Pelouzeand Cahours J., 16, 529 iv., 134 11 >i " w 150-160 Z. C. [1870], 404 Heptachlornaphthalene C 10 HC1 7 154 Glaus and Lippe B., 16, 1019 44, 921 Hexachlornaphthalene .... C 10 H 2 C1 6 143 Beilstein Org. Chem. iv., 13 a-Pentachloruaphthalene .... a^fr, ; a, C 10 H 3 C1 3 168-5 Grsebe A., 169, 8 vi., 847 a- 168-5 Glaus and Lippe B., 16, 1017 a- .. 168-5 Widmann B. S. [2], 28, 505 32, 901 /3- C1 3 ; C1 2 .... 177 Atterberg and B. S. [2], 27, 513 Widmann P- H B 177 11 11 B., 10, 1843 34, 322 a-Tetrachlomaphthalene .... C 10 H 4 C1 4 106 Laurent iv., 12 b- ,, 125 11 k- B 125 a- C1 2 ; C1 8 11 130 Faust and Saame A., 160, 72 25, 65 ; vi., 847 a- ,, 130 Widmann B. S., 28, 511 32, 901 i- H 141 11 11 ^ 8- 11 H .... 141 Atterberg and B., 10, 1842 34, 322 Widmann e- .... n .. 156-158 Faust and Saame Z. C. [2], 5, 705 vi., 847 6- C1;C1 159-5-160-5 Alen B. S. [2], 36, 433 42, 410 e- .... 11 V .... 170 Laurent iv., 12 y- 176 Widmaun B. S. [2], 28, 512 32, 901 - 180 Grimaux B. S. [2], 18, 205 26, 69 f- .... 180 Widmann B. S. [2], 28, 508 32, 901 11 .... .... 180 Atterberg and B., 10, 1844 34, 322 Widmann /3- M .... 194 Atterberg B., 9, 318 29, 915 3- 11 194 Widmann B. S. [2], 28, 505 32, 901 f-Trichlornaphthalene A V ; & C 10 H 5 C1 3 66 11 B., 12, 962 36, 723 t- 65 Cleve B. S. [2], 29, 500 34, 730 - & 65 B., 12, 1714 \ 38, 47 ac- 66 Laurent iv., 12 g- 69 11 a- ,, 7f> 11 c- 79 a- aft A ; ,, ... 81 Faust and Saame A., ICO, 71 25, 65 ; vi., 847 0- 81 Widmann B. S.,28, 511 36, 723 COMPOUNDS CONTAINING THREE ELEMENTS. 107 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. d-Trichlornaphthalene .... C 10 H 6 C1 3 89 Laurent iv., 12 0- a a. 305 90 Atterberg B., 9, 926 30, 516 0- a JJ 90 Widmann B. S. [2], 28, 505 32, 901 ae- .... 93 Laurent iv., 12 y- jj Cl 2 ;a, abt. 300 103 Atterberg B., 9, 317 29, 915 y- JJ 103 Widmann B. S., [2], 28, 508 32, 901 y- J u 103 n B., 12, 2230 38, 168 8- a^ ; QI 124 Atterberg B., 9, 1187 31,85 8- jj 129 u. c. S- jj 129 u. c. jj jj 8- jj 131 B., 9, 1733 31, 466 8- ?j 131 Widmann B. S. [2], 28, 511 32, 901 jj 140 B., 12, 1714 38,47 ad- 160 Laurent .... iv., 12 a- di- .... C 10 H 6 C1 6 93 Widmann B. S. [2], 28, 505 32, 900 chloride jj jj .... .... 93 Atterberg and B., 10, 1842 34, 322 Widmann 3- 152 Widmann B. S. [2], 28, 507 32, 900 a-Dichlornaphthalene <; 10 H 6 ci 2 Liquid Laurent iv., 11 x- Liquid JJ 280-300 Rimarenko B., 9, 663 30, 298 ad- .... 29 Laurent iv., 11 e- .... 31 JJ a- ft 280-282 35-36 Faust and Saame A, 160, 69 25, 65 ; vi., 846 a ,, 282-5-284 35-36 Krafft and Becker B., 9, 1089 30, 518 (740) o- 35-36 Faust and Saame B. S. [2], 22, 244 31, 207 a- 3 35-36 Widmann B. S. [2], 28, 505 32, 900 a- 38 B., 15, 2160 44, 208 1- 3 .... 48 B. S. [2], 28, 505 32, 901 1- jj (9 .... 48 Cleve B., 12, 1714 38,47 C- 50 Laurent iv., 11 6- 9 jj .... 59 Armstrong B., 15, 205 e- (9 61-5 Cleve B. S., 29, 415 |3-(?) .... 51 Hermann A., 151, 81 vi., 846 0- *i*i 66 Atterberg B., 9, 1187 31, 85 0- JJ 68 Hermann A, 151, 81 vi., 846 0- JJ u 281-283 68 Faust and Saame A., 160, 70 25, 65 ; vi., 846 0- JJ 286-287(740) 68 Krafft and Becker B., 9, 1089 30, 518 0- JJ jj 68 Faust and Saame B. S. [2], 22, 244 31, 207 0- JJ 67-5 Cleve B. S. [2], 26, 242 31, 208 0- JJ jj 67-68 Meldola .... 43, 2 JJ 68 Arnell B. S., 39, 62 44, 595 0- JJ 67-68 Atterberg B., 10, 547 32, 623 p- JJ jj 67 B., 9, 1189 0- JJ jj 67-68 Widmann B. S. [2], 28, 516 32,900 0- JJ jj 67 B., 12, 1714 38, 47 - j. a,; a, jj .... 83 Atterberg B., 9, 1732 31, 466 f- 83 Widmann B. S. [2], 28, 505 32, 901 f- OjJOj jj .... 92 Hermann A., 151, 163 vi., 846 ?- jj jj .... 94 Glaus and Ochler B., 15, 314 42, 737 y- jj 95 Laurent iv., 11 y~ jj jj 101 jj r j, a,; a 3 jj 107 Atterberg B., 9, 1188 31,85 y- jj jj abt. 289 707 B., 9, 317 29, 915 y- jj jj 107 B. S. [2], 22, 244 31, 207 V- / jj jj 107 Widmann B. S. [2], 28. 505 32,900 y- j' 107 Armstrong B., 15, 205 8- 8- Cl; Cl " 114 114 Cleve Widmann B. S. [2], 22, 244 B. S. [2]. 28, 505 31, 207 32, 900 8- JJ 114 Cleve B., 10, 1724 34, 154 108 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. fi-Dichlornaphthalene a; ci Ci H 6 Cl 2 114 A16n B. S. [2], 36, 433 42, 409 i- .... 11 120 Widmann B., 15, 2162 44, 208 t 0;() 11 .... 135 Cleve B. S. [2], 22, 244 31, 207 c- 11 135 Widmann B. S. [2], 28, 505 32, 901 t- 11 135 Cleve B., 10, 1722 34, 154 t- )i 11 285 135 Claus & Zimmerman B., 14, 1483 40, 915 f - 11 135 Alen B. S. [2], 36, 433 42, 409 t- ! 135 Cleve B. S., 25, 244 39, 142 a- ft- tetra- C 10 H 6 C1 6 Liquid Widmann B. S. [2], 28, 506 32, 900 chloride y- ?- I) 85 Widmann & Atter B. S. [2], 27, 513 32, 901 berg y~ 85 Atterberg & Wid- B., 10, 1842 34, 322 manu - r .... ) 141 Laurent iv., 9 - Q - )) 172 Faust and Saame A., 160, 67 25, 64 ; vi., 846 .... )) 172 Widmann B. S. [2], 28, 506; 32, 900 B., 15, 2160 Chlor naphthalene a C 10 H 7 C1 250-252 Liquid Faust and Saame A., 160, 68 25, 64 ; vi., 846 a 254-255 Liquid Atterberg B., 9, 317, 927 29, 915 a )) Liquid Palm B., 9, 499 30, 206 a )> Liquid Lieberniann A., 183, 225 31, 607 ,, a ) Liquid Smith 32, 563 a u 293 Liquid Widmann B. S. [2], 28, 509 32, 900 ) a jj 251-253 Koninck and Mar- B., 5, 11 25, 302 quart a 259-262 Laurent A., 8, 13 a abt. 260 .... Carius A., 114, 146 ,, ^ jj 256'5 cor. 55-5 Cleve and Dannfelt B. S. [2], 25, 256 30, 81 ft 254 53 Cleve B. S. [2], 25, 258 30,82 ft u 61 Palm B., 9, 499 30, 206 253-258 (751 56 Eimarenko B., 9, 663 30, 298 3 j) 61 Liebermann A., 183, 270 31, 607 j 53 11 )> J> ,, ft .... 56 11 n 5 ., ft 56 Smith 32, 563 ft jj .... 55-5-56 Widmann B. S. [2], 28, 505 32, 900 " ' ft .... 53 Cleve B., 10, 1722 34, 154 ,, .... ft 59 Armstrong B., 15, 203 ft- tetra- A C 10 H 7 C1 5 Liquid Widmann B. S. [2], 28, 506 32, 900 shloride ft- 11 11 ft .... 81 11 B., 12, 1714 38, 47 ' 11 .... H 105 Gerhardt iv., 9 ? 11 11 .... >i 121 Fischer B., 11, 741 1 11 11 .... JT 128-130 Faust and Saame A., 160, 67 25, 64 ; vi., 846 - 11 11 n i ) .... 131-5 Widmanu B., 12, 1714 38,47 - n 11 "^i^ift ; ) 182 i) B. S. [2], 28, 506 32, 900 Naphthalene dichloride .... C 10 H 8 C1 2 Liquid Laurent A.C.[1833],52,278 ;i 11 .... Liquid Fischer B., 11, 737 11 11 A ) Liquid Widmann B. S. [2], 28, 505 32, 899 tetrachloride ... C IO H 8 C1 4 .... 160 Laurent A. C. [1883], 52, 278 iv.,8 11 11 182 Schwarzer B., 10, 379 11 11 )) 182 Fischer B., 11, 738 11 11 1) 182 Faust and Saame A., 160, 66 25, 64 ; vi., 846 11 n Tetrachlorisocymene a^ftft, ; MeP/Cl 4 =1.3.(?) 4 . )) CioH 10 Cl 4 182 158-5 Widmann Kelber B. S. [2], 28, 505 B., 16, 617 32, 899 44, 806 Dichlorcymene Dichlorisooymene Me.Pr a .Ca s =1.4.(?) s Me.Pr B .Cl 2 =1.3.(?) 2 C 10 H 12 C1 S > 240-244 280 Gerichten B., 10, 1252 A., 210, 53 34,49 Cumylene chloride )) 255-260 Cahours A. C. [3], 23, 345 ii., 184 11 n .... ." .... 255 p. d. Tiittscheff J. p. C., 75, 370 11 Tetrachlorturpentine .... C 10 H 12 G1 4 110-115 v., 925 COMPOUNDS CONTAINING THREE ELEMENTS. 109 Name. Constitution. Formula Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Chlorcymene Me.PrCl=1.4.6 C 10 H 13 C1 208-211 Gerichteu B., 10, 1249 34,49 ,i H 214 Kekul6 & Fleischer B., 6, 1090 vii., 935; 27, 66 214 Gerichten B., 11, 1091 34, 787 Me.Pr.Cl=1.4.5 208-210 B., 11, 365; J.p. [2], 3, 64 Cymylchloride 225-229 Errera G. I., 13, 421 46, 300 IJ 220-240 J. [1875], 414 (?) II (? abt 225 Spica G. L, 5, 394 20, 582 C 6 H 4 .Pr.CH 2 Cl 230 Paternd and Spica G. I., 9, 397 38, 107 Chlorcamphene C 10 H 15 C1 60 Pfaundler A., 115, 29 i., 728 60 Wright 26, 688 60 Spitzer B., 13, 1046 38, 717 (?) .... 100 Wright 26, 549, 686 vii., 833 Camphene dichloride C 10 H 16 Cl2 70 Pfaundler A., 115, 29 i., 728 ,, .... 155-155-5 Spitzer B., 11, 1819 36, 168 ,, .... ,, 155-155-5 B. 13, 1046 38, 717 Chlorterebene hydrochloride C 10 H 15 C1.HC1 ,, 107 Papasogli G. I., 6, 538 31, 593 Divalerylene hydrochloride.. .... CioH, 7 Cl 115-120(20 B. S., 33, 24 Diisoprene hydrochloride .. 145 .... .... B. S., 24, 112 Geranylchloride .... d. 1.15 Jacobsen A., 157, 232 vii 552 Cajputene hydrochloride .... 11 160 .... i., 713 ii is .... 55 J. [1860], 482 Calamene hydrochloride .... 63 Kurbatow A., 173, 4 28, 91 ,. .... 11 (?) abt. 65 B., 6, 1210 vii., 231 Cetrene hydrochloride .... .... 100 i., 1005 Turpenthie hydrochloride .. .... 165 115 v., 922 !I II ,... ,, b. 10 .... j; Terpene hydrochloride .. From parsley oil 115-116 Gerichten B., 9, 258 30, 78 Terebene hydrochloride C 10 H 9 .HC1 125 Armstrong&Tilden 36, 733 I! 125 Riban B. S. [2], 19, 244 27, 154 Isoterebenthenehydrochlorid 210 .... C. B., 79, 225 Terebenthene hydrochloride .... ii 120 (0-045) Liquid Barbier C. E., 96, 1066 44,809 II !! .... 120 (0-04) Liquid Terpene hydrochloride 3 10 H 6 .HC1 abt. 210 125 Tilden C. N., 39, 256 36, 943 ii 11 127 Beilstein & Wiegand B., 15, 1742 11 11 from pinus sylvestris n 204 p. d. 127 Flawitzky B. S. [2], 30, 433 36, 168 D 11 .... 131-132 Armstrong & Tilden 35, 733 Olebeue hydrochloride C JO H 6 .HC1 127 Kurbatow Z. C. [2], 7, 201 24,695;iii.,873 11 ! 127 A., 173, 3 28,90 Borneol chloride .... 132 Kachler A., 164, 75 vii., 206 ; 26, 1011 147-148 c. B., 11, 460 34, 512 11 11 *. ..* .... 159 c. A., 197, 86 36, 1040 Camphene hydrochloride .... .... 145 Armstrong & Tilden 36, 733 11 11 .... 145 ii 11 35, 744 a- nactive] 45 Montgolfier A. C. [5], 6, 372 13- 47 A. C. [5], 6, 374 n HC1 gas 47 A. C. [5], 14, 5 34, 901 11 n 53 iachler and Spitzer A., 200, 343 38, 324 11 11 .... 56-157 11 ii Terpene hydrochloride rromathamantha oroselinum 90 A., 51, 337 11 11 Muscat nut oil 94 Cloez J., 17, 536 Divalerylene dihydrochliiridc .... C 10 H 18 Cl2 5 B. S., 33, 24 Citrene dihydroehloride h'om lemon oil 42 43-44 Cahours i., 1005 i, 11 n D 62 Blanchet and Sell ,i .. 11 sweet orange Gm., 14, 306 ., 1002 Terpeue dihydrocloride camphor oil 2 Lallemand A. C., 57, 404 .,729 11 11 erigeron canadense .... 7-48 3eilstein & Wiegand B., 15, 2854 44, 346 11 11 ,, colophony 9 Renard C. E., 92, 886 40, 739 11 11 templin oil ,, 5 .... J. [1855], 645 v., 720 n 11 Klden B., 12, 1131 33, 249 11 n 48 _ .... 35, 288 110 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Terpene dihydrocloride QioB-isda .... 48 Tildeu C. N., 39, 256 36, 943 /3-Isoterebenthene dihydro- C 10 H 16 .2HC1 49-5 A. C. [5], 6, 228 chloride Diisoprene dihydrochloride... ji > .... 49 Tilden 45, 414 *> 175-180 49-5 .... B. S., 24, 112 (150) Pilocarpene dihydrochloride n )> 49 '5 Hardy J. Ph. [4], 23, 95 31, 325 Carvene dihydrochloride j) 50-5 .... A., 40, 333 i., 809 Cajputene dihydrochloride ... 5J 55 J. [1860], 482 i., 713 Sylvestrene dihydrochloride n 72-73 Atterberg B., 10, 1206 34,79 )T 72-73 Tilden C. N., 39, 256 36, 943 Copabene dihydrochloride .... IJ TJ 77 ii., 17 Menthyl chloride C 10 H 19 C1 204 .... Walters A., 32, 292 iii., 881 C 10 H 18 hydrochloride From calamene oil abt. 65 Kurbatow B., 6, 1210 27, 259 Chlordiamylene chloride .... C, H 19 C1 3 240-250 Bauer Z. C. [1867], 393 vi., 122 Decyl chloride From isocapryl alcohol C 10 H 21 C1 175-185 .... J. [1864], 338 ,, fusel oil 190-200 Wurtz B.S. [1863], 5, 315 v., 1091 ,, .... petroleum )> 200-204 Pelouze & Cahours J., 16, 530 )J diamyl abt. 200 Schorlemmer 15, 425 iii., 182 Chlorundecylene .... CnH 21 Cl 221-223 Giesecke Z. C., 6, 431 vii., 808 "Dndecylene dichloride QuH^CSi 270 Z. C. [1870], 431 Undecyl chloride CnHjgCl 220-224 J. [1863], 530 Pentachlordiphenyl .... .... Ci 2 H & Cl 6 179 Dcebner B., 9, 130 40, 911 ,, .... .... in. a. 360 179 Schmidt & Schultz A., 207, 342 J5 Trichlordiphenyl (?) .... C 12 H 7 C1 3 (?) 126 j> 5) 40, 910 Dichlordiphenyl C1.C1=4.4' C 12 H 8 C1 2 148 Griess P. T. [1864], 3, 730 iv., 410 u 315 148 Kramers A., 189, 142 32, 898 > jj 148 Schmidt & Schultz A., 207, 339 40, 910 ,, .... .... CeHsClj'CjHs si 179 Doebner B., 9, 129 29, 932 Chlordiphenyl Ph.C 6 H 4 .Cl=1.2 C 12 H 9 C1 S6T-S68 34 Kramers A., 189, 144 32, 898 V .... .... =1.4 ) 75 Schultz B., 7, 52 27, 468 ; vii., 937 " ) .... 75 A., 174, 209 28, 149 )) )> 282 75-5 Kramers A., 189, 145 32, 898 =1.3 J) .... 89 Pfankuch J. p. C. [2] ; G, 106 26, 363 ; vii., 656 Duodecyl chloride .... C 12 H, 5 C1 242-245 .... Pelouze & Cahours J., 16, 530 vi., 547 From pentachlorfluorene .... C 13 H 6 C1 6 (?) 110 Hodgkinson and 43, 171 dichloride Matthews Pentachlorfluorene dichloride See C 13 H 8 C1 2 Ci 3 H 5 Cl, .... 104 s> 43, 170 Trichlorfluorene .... C^HjClj 147 Holm B., 16, 1082 44, 922 Dichlorfluorene c.c:c.c.c:c.c C-iaHsClj 128 Hodgkinson and B., 16, 1103 43, 170 II 1 1 II Matthews cic.c:c C:C.cci Diphenyl dichlormethane .... CCLiPh., C 13 H 10 C1 2 220 (671) ; Liquid Kekule and Franchi- B., 5, 909 ; A., 26, 171 305 p. d. (760) mont 187, 217 chlormethane Ph 2 CHa. CuH.^l 14 Engler and Bethge B., 7, 1128 28, 65 Tridecyl chloride CiaH^Cl 258-260 J. [1863], 530 Octochlorophenanthrene .... C 14 H 2 C1 8 270-280 Zetter B., 11, 168 34, 510 Octochloroanthracene .... n. f. 350 Diehl B., 11, 177 34, 429 Heptachloranthracene .... C H H 3 C1 7 a. 350 B., 11, 176 Hexachlorphenanthrene .... C, 4 H 4 C1 6 249-250 Zetter B.,'11, 168 34, 510 Hexachloranthracene .... a. 330 Bolas C. N., 28, 167 27, 64 ,, 320-330 Diehl B., 11, 175 34, 429 Tetrachlorphenanthrene .... C 14 H 6 C1 4 171-172 Zetter B., 11, 167 34, 510 |3-Tetrachloranthracene .... ji .... 152 Liebermann and B., 13, 1589 40, 100 Lindemann a- .... j) .... 220 Greebe & Liebermann As., 7, 28.3 vi., 179 a- n .... 220 Diehl B., 11, 174 34, 429 Trichloranthracene C 14 H 7 C1 3 .... 162-163 Schwarzer B., 10, 378 32, 494 Dichlorphenanthrene .... C 14 H 8 C1 2 .... low temp. Zetter B., 11, 166 34, 510 COMPOUNDS CONTAINING THREE ELEMENTS. Ill Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dichlorauthracene C 6 H 4 . C 2 C1 2 1 C 6 H 4 C I4 H 8 C1 2 205 Perkin 24, 14 vi., 179 ji C 6 H 2 C1 2 . C 2 H 2 . C 6 Hj ) .... 255 Kireher B., 17, 1167 46, 1040 Dichlordiphenyl dichlorethyl- cci 2 :(c 6 H 4 ci) 2 c 14 H 8 a 4 .... 89 .... B., 7, 1181 ene Dichloranthracene dichloride c 6 H 4 :c 2 ci 4 :c 6 H 4 149-150 Schwarzer B., 10, 377 32, 493 From anthraquinone chloride )> 203-204 Thb'rner and Zinck B., 10, 1480 34,231 Dichlorphenanthrene tetra- Ci4H 8 Cl 2 .Cl 4 C 14 H 8 C1 6 145 Zetter B., 11, 165 34, 510 chloride a-Dichloranthracene tetra- n 5> 141-145 d. Diehl B., 11, 174 34, 429 chloride 0-Dichloranthracene tetra- ) U 205-207 Liebermann and B., 13, 1588 40, 99 chloride Lindemann Monochlorphenaiithrene .... C I4 H 9 C1 .... Liquid Zetter B., 11, 166 34, 510 Monochloranthracene .... J> 103 Perkin C. N., 34, 145 31, 209 Chlortolane dichloride C 14 H 9 d 3 137-145 Limpricht and B., 4, 379 vii., 1162 Schwanert it .... j> 150 )> 24, 511 Pentachlortolylphenylketone Ph.C01 2 .C 6 H 4 .CCl 3 =:1.4 C 14 H 9 CI 5 79-80 Thorner B., 9, 1738 ; A., : 31, 464 ; 34, 68 189, 95 Dichlorphenyltrichlorethane CC1 3 CH.(C 6 H 4 C1)., )> 105 Zeidler B., 7, 1181 28, 148 /3-Tolane dichloride C 6 H 5 .C 2 C1 2 .C 6 H 5 " Ci 4 H 10 Cl2 .... 60 Hanhart B., 15, 900 1 42, 1103 0- }> v 63 Zinin Z. C. [2], 4, 718 ; vii., 157,1162; Z. C. [2], 7, 284 24, 1041 $- ,j i> ) 63 Liebermann and B., 12, 1973 38, 259 Homeyer #- )j )j 63 Limpricht and B., 4, 379 24,511 Schwanert a- )) j ... 140 Hanhart B., 15, 899 42, 1103 o- .. ) .... 143 Liebermann and B., 12, 1973 38, 259 Homeyer - i> >! 1) ) 153 Zinin Z. C. [2], 4, 718 vii., 157, 1162 - ,1 v ) > 153 Z. C. [2], 7, 284 38, 259 - >i 153 Limpricht and B., 4, 379 24, 511 Schwanert Dichlorstilbene C 14 H 10 C1 2 170 Kade J. p. [2], 19, 461 38,46 Diphenyldichlorethylene Ph 2 c : cci 2 80 Baeyer B., 6, 223 Diclilordiphenylethylene CH 2 : C(C 6 H 4 C1) 2 280-285 Liquid Hepp B., 7, 1419 28, 362 Tolane tetrachloride Ph.cci 2 .cx;i 2 ph" ^uH 10 Cl4 163 Liebennann and B., 12, 1971 38, 259 Homeyer ,, )) 163 Hanhart B., 15, 901 Tetrachloranthracene C 6 C1 4 . C 2 H 2 . C 6 H 4 )) 148 Kireher B., 17, 1167 46, 1040 Diphenyltrichloretliane Ph 2 .CH.CCI, CuH^Cl., 64 Baeyer B., 5, 1099 26, 501 Chlorstilbene dichloride ) 85 .... B. J., 25, 620 ?-Stilbene dichloride C(ft. CgHgClg. C 6 H 5 C 14 H 12 C1 2 69-70 Forst and Zinck6 B., 8, 797 S8, 1190 0- . v j) i) 92-93 - it j) 94 Zineke A., 198, 134 38, 115 3- !! )) n 94 Perkin 39, 427 0- ) )) .... 93-94; a.f. Zincke B., 10, 999 32, 622 160-165 J. ' )> )> ) 153 >i A., 198, 134 38, 116 "- >j > 184 Amman Z. C. [2], 7, 83 ;24,385; vii.,171 - >! ) .... 188 )> A., 168, 74 26, 1140 - )I jj )) 190 Forst and Zinek6 B., 8, 797 28, 1190 - 11 j .... 191-192 B., 10, 999 32, 622 - )? 192 Paal B., 16, 638 - i, 192 Perkin 39, 427 - > j .... 191-192; a.f. Zinckfi B., 10, 999 32, 622 160-165 j a- (identical) 5) 192 A., 198, 131 38, 115 - !! J) 1J 192 i> j> Di-chlordibenzyl ClC 6 H 4 (CH a ) 2 .C 6 H 4 Cl=(1.4) !! )1 112 lade J. p. [2], 19, 462 38, 46 112 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. From benzyl chloride C 14 H 13 C1 204-206 p. d. .... Zinck6 B., 7, 278 27, 691 Tetradecyl chloride C 14 H^Cl 280 Pelouze & Oahours J., 16, 530 .Trichloridryl . C H PI a. 300 Goldschmidt W. A., 81, 415 40, 283 Dichlorditolyl methane CH 2 .(C 6 H 4 CH 2 C1) 2 15"^7 3 106-108 Weiler B. 7, 1187 28, 152 Hydrochloride, from cubebs C 15 H 24 .HC1 C 15 H 25 C1 117-118 Oglialoro G. I., 5, 467 30, 64.3 oil Dihydrochloride, from cubebs C 15 H 24 .2HCl C 15 H 26 C1 2 118 B., 8, 1357 oil- 11 ) 11 131 ii., 172 Tetrachlorpyrene C 16 H 6 C1 4 a. 330 Goldschmidt and M. C., 4, 241 44, 1003 Wegschneider Trichlorpyrene .... C^Hydj 256-257 11 11 a-Dichlorpyrene .... C 16 H 8 C1 3 154-156 11 11 M. G, 4, 239 44, 1002 0- n 194-196 11 11 M. C., 4, 240 11 Chlorpyrene ... C 16 H 9 C1 118-119 M. C., 4, 238 44, 1001 Diphenyl trichloroquartene.... C 3 H 2 a 3 .CH.Ph 2 C 16 H 13 C1 3 80 11 11 Hepp B., 7, 1420 28, 362 Ditolyl dichlorethylene (C 6 H 4 Me) 2 C:C01 2 CuH^CL, .... 92 Fischer B., 7, 1191 28, 154 trichlorethane (C 6 H 4 Me) 2 CH : CC1 8 C 16 H 15 C1 3 89 11 11 Cetyl chloride .... C 16 H 3.-)C1 a. 200 Tuttscheff E. C. p. [2], 463 i., 840 11 289 p. d. J., 13, 406 Trichlorchrysene C I8 H 9 C1 3 a. 300 Schmidt J. p. [2], 9, 279 27, 988 Dichlorchrysene C 18 H 10 C1 2 267 J. p. [2], 9, 278 11 Triphenylchlormethane (?) .... Ph 3 OCl (?) Ci 9 H 15 Cl (?) 105-115 B., 7, 1208 ; A., 194, 254 Iso-amylchloranthracene c 6 H 4 : CjjCKCsHu) : c 6 H 4 C 19 H 19 C1 70-71 Liebermann and B., 14, 797 40, 737 Tobias )> i) 11 .... 70-71 Liebermann A., 212, 111 42, 863 a-Heptaehlordinaphthyl .... C^RjClj 70 Widmann B. S. [2], 28, 505 32, 901 p~ ,, ... 164 11 Enneachlordinaphthalene .... .... C 20 H 7 C1 9 156-158 Faust and Saame A., 160, 73 vii.,466;25,65 Heptachlordinaphthalene .... C^HjCly 106 11 13 A., 160, 65 25, 65; vi.,847 .... 100-102 11 11 Tetrachlor-/3/3-dinaphthyl .... .... G, H 10 ci 4 m. b. 100 Smith and Poynting 27, 855 a-Dibenzoylbenzene tetra- C 6 H 4 (CCl 2 Ph) ! C 20 H 14 C1 4 91-92 Wehnen B., 9, 311 chloride Hydrocuminoin dichloride .... C 9 H U .CHC1.CHC1.C 9 H U C^H^Cl,, 184-185 Raab B, 10, 54 32, 894 (?) .... C 20 H 33 C1 abt. 110 Bauer and Verson A., 151,52 vi., 1112 (?) .... 180-200 d. 11 11 A., 151,57 From Minjak Lagam balsam 0^32.41101 CjoH;,/)!., .... 114 Haussner A. P. [3], 21, 241 46, 355 oil of copaiva balsam.... .... 77 .... A., 34, 321 54 .... A., 7, 158 Eikosylene hydrochloride .... .... C 20 H 39 C1 5:25-230 Liquid Lippmann & Hew- B., 12, 71 36, 447 liezek (?) 02,301,, 102 .... J. [1877], 421 a-Dinaphthyldichlorethylene (Cyijjttj^O . l_A^I 2 (i) C^HuClj .... 149-150 Grabowsky B., 11, 299 34, 509 0- (C 10 H 7 )C1.C:CC1(C 10 H 7 ) (?) a. 360 219 B., 11, 300 JJ a-Dinaphthytrichlorethane .... C-sH^CL, .... (?) 11 B., 11, 298 /3- (C 10 H 7 ) 2 CH.CC1 3 (?) ,, .... 156 11 Camphocarbonylchloride .... .... C^H^CIs 45-45-5 Kachlerand Spitzer C. C. [1881], 359 42, 66 Tetrachlor- +trichlorpropane 3C 3 H 4 C1 4 + 5C,H 5 C1 3 ^24 ^37^-% 40 (i. v.) B., 16, 329 Cholesteryl chloride C 26 H 43 C1 100 Planer A., 118,26 vi., 448 97 Lindenmeyer A., 112, 359 Myricyl chloride ... C 30 H 61 C1 .... 64-5 Pieverling A., 183, 348 31, 586 1, 64-5 Canzoneriand Spica G. 1. [1882], 227 42, 1040 Pentaphenylchlorethane CPh 2 Cl.CPh 3 C 32 H 26 C1 a. 340 120-125 J. [1877], 403 Tarcouyl chloride C 50 H; ol Cl or .... 67-68 Canzoneriand Spica G. I. [1882], 227 42, 1040 C 51 H W3 Clor COMPOUNDS CONTAINING THREE ELEMENTS. (3.) CHBr. 113 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Bromoform .... .. CHBr 3 144-146 Bolas and Groves 24, 783 " abt. 145 .... Borodino K L., 2, 145 " 14/-148 Klimenko J. p.C.[2], 13, If 29, 900 " 1 K 1 . 0? ,, fytin Schmidt B., 10, 193 32, 293 " 101 6 C. (iuU ) *. 2-5 Thorpe MM 37, 201 " **** **** ** . 152 .... Cahours J., 1, 501 37, 202 " 120'3 (330) 1 1Q 1 PiA 7 '8 Perkin 45, 533 " 14o 150 1 Fil .O .... Dyson 43, 36 ioi Z Henry A. C. [5], 30, 266 46, 718 Methylene dibromide .... CH 2 Br 2 80-82 9 Herrmann Steiner G. J. C., 1855 B., 7, 507 27, 782 " " .... 98-5 1.-12 Henry A. C. [5], 30, 266 46, 718 .... ,, 96-5-97-5 c. .... Perkin 45, 520 Methyl bromide .... CH 3 Br 13 (759) Pierre and Puchot C. R, 27, 213 iii., 987 .... 4-5 .... Henry A. C. [5], 30, 266 46, 718 " " .... If 5 c. .... Perkin 45, 454 Tribromethylene CBr^CHBr C 2 HBr s b.-17 130 .... Bunsen Lennox 13, 206 iii., 422 ii., 570; 34, 401 " " ,, 162-163 Liquid Sabanejeff A., 178, 123 29,56 " " ,. 162 .... Demole B., 11, 315 34, 401 .... " n 162-5 Anschutz A., 221, 133 46, 33 " MM (C 2 HBr 3 ),, 174 Sabanejeff & Eeboul C. R., 54, 1229 41, 391 ,, Pentabromethane CHBr 2 .CBr 3 C 2 HBr 5 .... 175 48-50 Sabanejeff Jeboul A., 178, 114 A., 124, 268 29, 56 ii., 571 " 1) 50-52 jimpricht A., 165, 253 26, 625; vii., 828 " " ,, .... 51 Orlorsky B. S. [2], 28, 348 34,31 " " 210 (300) 54 )ruzel B., 12, 2208 38, 228 Dibromethylene CH 2 : CBr 2 C 2 H a Br 2 75 56-57 Jurgoin I'ontaine C. R, 80, 325 C. R, 7, 1361 28, 553 vii., 490 " 88 leboul A., 126, 270 " " i. 86-88 .... lenry C. R, 97, 1491 46, 571 " 88-90 .... C. R, 98, 680 46, 831 11 " ., 87-92 & 87-95 .... Deruole B., 11, 316, 1308 " " v 88 .... abauejeff B. S. [2], 34, 323 40, 399 " " i, 90-91 .... fenry C. R, 98, 741 46, 831 " 91 Liquid 'awildarow B., 6, 1459 vii., 479 ; 87, 348 " 91 .... Plimpton 41, 397 " 91-5 Anschutz A., 221, 133 46, 33 CHBr! CHBr 106-109 .... Sabanejeff B., 12, 2075 " " a 109-5 Weger A., 221, 61 46, 11 " ,. 110-111 .... Anschutz A., 221, 133 46, 33 " " 110-111 1. -17 Plimpton 41, 391 " " ,, 110 .... Henry C. K., 98, 741 46, 831 " , 110^111 1. -17 Plimpton 39, 536 ' .... 130 .... Berthelot 41, 391 .... 157 .... Tawildarow A., 176, 23 " .... ,, 161 H B., 6, 1459 vii., 479; 27, 348 (CH^CBr.). (C 2 H 2 Br 2 ) a 220-230 Liquid Demole B. S. [2], 34, 204 10, 142 Tetrabromethane .>.. C 2 H 2 Br 4 206 Liquid Burgoin B. S. [2], 19, 148 26, 621 .... 95-197(300); Denzel B., 12, 2207 38, 228 25-227(732) H 00 : Demole B., 11, 1308 J4, 847 i, .... 90-210 B. S. [2], 34, 201 10, 142 2HBr 2 .CHBr 2 v bt. 200 s ,. f. m. ] jeunox 3,206 i., 570 " 09 p. d. 1 . 20 ?awildarow B., 6, 1459 'ii., 479 ; 27, 1 348 Q 114 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Tetrabromethane CHBr 2 .CHBr a C.HsBr, d. Liquid Sabanejeff A., 178, 113 29, 56 .... 1. 20 Burgoin B. S. [2], 27, 395 32, 443 136-137-2(36) 1. 24 Anschutz B., 12, 2074 38,98 139-139-2(41) 1. 24 B., 12, 2075 .... 200 d. .... A., 216, 255 195-200 .... B. S., 34, 28 .... ,, 114(14) .... Anschutz A., 221, 133 46,33 CH 2 Br.CBr 3 103-5 (14) U abt. 200 p. d. s. 17 Burgoin A. C. [5], 12, 427; 34,30; 32,443 - B. S. [2], 27, 395 150 s. Sell and Sakmann B., 7, 496 \ 200 d. .... .... A., 216, 255 208-211 .... .... A., 176, 24 CHBr 2 .CHBr 2 abt. 42 Berend A., 135, 257 vl., 36 y- jj CH 2 Br.CBr 3 abt. 206 p. d. 54-5 Burgoin C. E., 79, 953 28, 343 54-5 B. S. [2], 27, 395 32, 443 220 52 Kessel B., 10, 1669 34, 128 ,, 206 54-55 Reboul & Burgoin C. E., 84, 556 32, 592 8- u 150-160 Burgoin C. E., 79, 953 28, 343 //"YTT "D * O"D. N ( 1 . rl 2 "" . V^-Dr^ 1^ (C 2 HjBr 4 ) n .... 185 Tawildarow B., 6, 1459 vii., 479; 27, 348 Bromethylene (vinyl bromide) CH 2 :CHBr C 2 H 3 Br ord. temp. .... Regnault ii., 570 jj n n JJ 16 Anschutz A., 221, 133 46, 33 JJ 16 c. .... Perkin 45, 540 JJ 18 Reboul A., 155, 29, 212 vii., 489 n J rt JJ 17-18 C. E., 74, 944 25, 684 JJ 15-16 .... Livoff B. S. [2], 30, 255 34, 963 Tribromethane CHBr 2 :CH.jBr C 2 H 3 Br 3 186-5 .... Wurte A. C. [3], 51, 84 ii., 570 JJ 187-188 Anschutz A., 221, 133 46, 33 ?j 188 Glockner As., 7, 111 vi., 603 n n JJ 187 Caventou C. E, 52, 1330 vi., 594 185-186 Orlowsky C. C. [1877], 3 32, 869 JJ 186 Simpson J., 10, 461 )J 188-5-189-5 c. Perkin 45, 534 > >J 184-185 Demole B., 9, 49 29, 693 JJ 191 Tawildarow A., 176, 21 CBr 3 .CH 3 JJ 187-188 (731) Denzel B., 11, 1735 36, 214 j) " JJ 180 B. S., 34, 28 Ethylidene dibromide CHyCHBr,, C 2 H 4 Br 2 86-88 Michael A. C. J., 5, 192 46, 418 j "' jj 87-92 Demole 38, 158 jj >> 93 Anschutz B., 12, 2073 38, 98 j? j> j> 109 Sabanejeff .... 46, 418 jj j jj B 110 Plimpton 41, 397 j> n 110-5 Anschutz A., 221, 133; B., 46,33; 44,807 16, 622 jj j> jj ft 108-110 c. Perkin 45, 523 jj B 110-112 .... Caventou C. R., 52, 1330 vi., 594 jj j? n 110-112 Reboul Z. G, 13, 200 jj j> jj 110-112 Paterno and Pisati G. I., 1, 596 25, 233; vii., 493 jj j> jj 110 .... Hofmann J., 13, 346 jj jj tj 110 .... Lescoeur B. S. [2], 29, 483 34, 718 u M 109-110 (750) Liquid Denzel B., 11, 1735 36, 214 jj j> j> M 110 A., 195, 210 36, 368 jj jj ^ 110-112 Sabanejeff B. S. [2], 34, 323 40, 399 jj jj jj w " 110 Anschutz B., 12, 2073 38, 98 u u 114-115 Tawildarow A., 176, 12 Ethylene dibromide CH.jBr.CH 2 Br M 129 9 ii., 569 127 Jahn B., 13, 2108 j> B 131-132 Butlerow J., 14, 652 u jj n 127-128 Jahn B., 13, 2115 jj jj 132-5 Hermann COMPOUNDS CONTAINING THREE ELEMENTS. 115 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylene dibromide CH 2 Br.CH 2 Br C 2 H 4 Br 2 129-129-5 Carnelley 28, 525 ) JT Ji j) 137 Lescceur B. S. [2], 29, 483 34, 718 1) )) j> )i 131-6 (760) s. 9 '53 Eegnault J., 16, 70 J> ) T) j 132-6 (756-9) 13-1 Pierre C. R, 27, 213 131-6 (770) Haagen P. A, 131, 117 1 *" ) i 131 Plimpton 41, 397 TJ )> 131 Plimpton & Graves 43, 123 T ) 131-6 Anschutz A., 221, 133 46,33 j) i> 131-5 c. 8-2-8-4 Perkin 45, 521 > D 130-135 Ladenburg B., 15, 1029 5) j> 130 8.0 Cahours J., 3, 402 )i ii " ) 131-45(760) 9' 2 Thorpe 37, 177 J) ) 129-5 s. 12to 15 Eegnault A. C. [2], 59, 358 )> ) ' 129-2-131-4 .... Brown 39, 210 >J 11 130 D'Areet J. P., 5, 28 j 130 Tawildarow B. S. [2], 34, 346 40, 398 > " J) > 130 Denzel A, 195, 210 36, 368 Ethyl bromide CH 3 .CH 2 Br C 2 H 5 Br 40-7 (757) Pierre C. R, 27, 213 U, 528 ) ) 38-78 Linnemann A., 162, 39 vii., 203 ,, 40-2 Haagen P. A., 131, 117 ) 38-5 .... vii., 438 ,, )> 42-44 Eeboul C. R, 92, 1465 ,, )> )j 41 .... Grimshaw 26, 310 ,, H 41 Bonnet , ) ji 38-39 (760) Gladstone and Tribe .... 27, 410 ,, j, .... .... )) 38-5-39-5 ji ii ,j ) >i 38-5-39-5 i) ii ,, 38-37 Eegnault J., 16, 70 ,j j) 39 Denzel A., 195, 210 36,368 ti j, .... .... ) 38-5-38-75 c. Perkin 45, 455 j, n )> 38 Henry C. R, 98, 370 46, 979 ,, 38-4 Anschutz A., 221, 133 46, 33 )) 39 Plimpton & Graves 43, 123 Jl 5> j 39; 236 c.t. Pawlewski B., 16, 2633 46, 252 ,, ,, > ) b. p. tables see Part III. Tribromallylene .... C 3 HBr, 190-195 Liquid Pinner B., 8, 900 28, 1245 Pentabrompropylene C 3 HBr 5 .... Liquid Merz and Weith B., 11, 2242 36, 302 Tetrabrompropylene (?) C 3 H 2 Br 4 (?) 45-46 Eeboul and Burgoin C. R, 84, 556 32, 592 Propargyl bromide CHiC.CH,,Br C 3 H 3 Br 88-90 Liquid Henry B., 6, 728 vii., 1008 ; 26, 1123 ,, ,, )) )) 88-90 Liquid B., 7, 761 27, 977 Bromallylene .... (C 3 H 5 Br). 115-116 Pinner B., 14, 1082 Tribrompropylene .... C 3 H 3 Br 3 183-185 Oppenheim B.S.[2],2,6;4,434 vi., 96 Propargyl tribromide CHBr:CBr.CH 2 Br n. v. Liquid Henry B., 7, 761 vii., 1008 ; 27, 977 Propargyl pentabromide CHBr 2 .CBr 3 .CH 2 Br C 3 H 3 Br 6 n. v. Liquid n ii Peutabrompropane From CH 3 .CHBr.CH.,Br u 255 Cahours A., 76,284; J.,3, 496 ,, n .... 173 A., 179,61; Z.C. [1865], 719 Dibrompropylene C 3 H 4 Br 2 120 .... Oppenheim B.S.[2],26,4,434 vi., 96 Allylene dibromide CH 3 .CBr:CHBr 120 Cahours J., 3, 496 )? 127-131 Linnemann J. 18, 490 vi., 965 ,, ,, ? 133 Oppenheim B.S. [2], 26,4,434 vi., 96 ! 126-138 jj J., 17, 493 ,, ) j) 130-131 .... Borsche and Fittig J., 18, 314 Dibrompropylene CH 2 :CBr.CH 2 Br j) 141 Henry .... vii., 1018 )> 14g C. R, 96, 1233 44,803 ,, 1 145 u A., 154, 371 15 .... .... CHBr : CH.CH 2 Br 151-1,-,.' Eeboul B. S. [2], 14, 50 vii., 1018 .,, .... .... J 152 i., 899 >1 I )) 150-152 Henry A., 154, 363 vii., 210 Q. 2 116 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Dibrompropylene CHBr:CH.CH 2 Br C 3 H 4 Br 3 152 Henry B., 14, 403 40, 507 Allylene dibromide .... (C 3 H 4 Br 2 ) n 37 Berthelot& De Luca A. C. [2], 63, 257 i., 141 Dibrompropylene dibromide C 3 H 4 Br 4 226 Liquid Caliours A., 76, 284 vi., 96 Allylene tetrabromide CH3.CBr 2 .CHBr 2 225-230 d. Lii|uid Oppenheim B. a [212,6; 4, 434 u (760); 110- 130 (10) )> CHsBr.CBr^CHsBr n 195 Hartenstein J. p. [2], 7, 317 26, 1219 Tetrabrom glycide CHBr 3 .CHBr.CH 2 Br j> 250-252 Liquid Keboul As. 1, 232 ii., 899 Tribromisopropyl bromide ... 230-240 d. 69 A., 136, 64 vi., 965 /3-Brompropyleue CH 2 :CBr.CH 3 C 3 H 5 Br 48-49 Liquid Reboul C. R, 74, 669, 944 vii.,51; 25,393 ,, .... jj J> 48 )j C. R., 74, 613 28, 683 ft- 48-49 j B. S. [2], 17, 351 vii., 1017 j, ) 48-49 (710) >) B. S. [2], 16, 50 > * 5) 48 .... u C. R, 79, 317 28, 50 ) * " j ?) 47-48 (742) Liquid s> A. C. [5], 14, 479 36, 130 ~ CHBr:CH.CH 3 )) 54 Vogt vi., 91 ,, 56-58 .... Linnemann A., 136, 55 vi., 965 ,, ) T) 56-5 .... j> A., 138, 122 vi., 967 1 56-59 .... A., 136, 55 J 54 .... Reboul B. S. [2], 14, 50 vii., 1017 ,, )J )) 54 .... Sawitsch C. E., 52, 399 M - >J J) 59-63 c. .... Perk in 45, 542 j ) 57-6 c. (760) .... Linnemann A., 161, 43 vii., 1017 )> 59-5-60 (740) Reboul C. R., 79, 317 ; 28, 50; 36, 130 A. C. [5], 14, 479 ,; J) 62 .... Reynolds vi., 91 Allyl bromide CH 2 :CH,CH,Br 1J 62 .... Cahours J., 3, 496 i., 141 n )J 70 Tol lens & Henninger Z. C., 12, 88 70 Henry Z. C., 13, 575 M 70-71 Hiibner & Muller Z. C., 13, 341 )1 )J 70-71 (753) Tollens A., 156, 153; B.S. vi., 91 [2], 9, 397 .... )I 70 Oppenheim G. J. C., 1869 .... )1 ) 70-77 c. .... Perkin 45, 542 Tribrompropane C 3 H 5 Br 3 175-180 Liquid Berthelot & De Luca A. C. [3], 48, 304 i.,668; vii., 210 n CH 3 .CBr 2 .CH2.Br )) 190 Liquid Reboul B. S. [2], 16, 50 ; vii., 1017; 28, C. R., 79, 317 50 n ft JJ 190-191 c. A. C. [5], 14, 476 36, 130 u From CH 3 .CHBr.CHjBr ) 194-196 .... Linnemann J., 18, 490 vi., 965 it .... )> 192 .... Cahours J., 3, 496 >j V 195 Wurtz J., 10, 462 J9 CH 3 .CHBr.CHBr 2 I) 200-201 c. Reboul C. R, 79, 317 ; 28, 50; 36, 131 A. C. [5], 14, 481 Tribromhydrin CH 2 Br.CHBr.CH 2 Br )1 217-218 16 Wurtz A. C., 3, 60, 84 i., 141 i) 219-221 16-17 Henry A., 154, 370 vii., 209 u J 215-220 Reboul C. R, 92, 1465 j> ?) abt. 240 Perrot J., 11, 395 i) ) J) 216-220 Tollens A., 156, 168 Dibrompropane CH 3 .CBr 2 .CH 3 C 3 H 6 Br 2 113-116 Butlerow A., 145, 271 vi., 967 i> )> )> 114-116 Perkin 45, 524 j 114-115 Liquid Reboul C. R, 74, 669 25,393; vii., 50 ? ) 114 .... C. R, 74, 613 25, 683 j T> 115-118 Linnemann A., 138, 125 vii., 1017 .... J ) 113-116 .... r riedel & Ladenburg B. S., 5, 8 )) it 113-116 .... Gladstone & Tribe 27, 408 > ) )j 115 Reboul C. R, 78, 1773 27, 977 > 5 114-114-5 .... A. C. [5], 14, 465 36, 129 (740) )> 5) 114 M 36, 130 j )) 122 ii Z. C., 13, 200 CH 3 .CH.,.CHBr 2 !> 131-133 A.C. [5], 14, 467 36, 129 jj .... )) 136-139 Gladstone & Tribe .... 41, 11 COMPOUNDS CONTAINING THREE ELEMENTS. 117 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Dibrompropane CH 3 .CHBr.CH 2 Br G 3 H 6 Br a 140-144 .... Wurtz A., 104, 245 v., 893 , 11 11 140-143 Linnemann A., 136, 53 vi., 965 3 j .... 11 11 140-5 A., 138, 123 i 11 )> 141-61 Liquid jj A., 161, 26 25, 235 11 .... .. 11 11 141-143 .... Butlerow A., 145, 271 vi., 967 j )1 143 .... Friedel and Silva C. R., 73, 1379 28, 135 , .... 11 11 141-61 Linnemann A., 161, 43 25, 237 ,, .... 11 11 142-65 .... Erlenmeyer A., 139, 226 j} .... 11 > 143 Reynolds J., 3, 495 vii., 1017 j) .... .. >1 11 142-142-3 c.; .... Perkin 45, 523 121-8-122-5 ' (330) 11 )> 143 .... Reboul C. R., 76, 1270 26, 1016 j, 11 > 143-145 .... j C. R., 74, 613 25, 683 JJ 11 141-143 Friedel & Ladenbur B. S., 5, 8 )> 11 142-143 Jahn B., 13, 983 38, 794 j, JJ 11 142-143 j> B., 13, 2111 11 11 142 .... jj B., 13, 2113 ,j 1 )! 143 B., 13, 2116 ,1 11 11 141-6 .... Zander A., 214, 175 j, 11 11 140-141 .... Friedel & Ladenbur B. S., 5, 8 )) 11 142 Kekute & Fleischer B., 6, 1087 27,66 11 11 141-143 Gladstone & Tribe .... 27,408 jj ! 142-143 .... >! J) .... 11 ;j 51 11 145 Cahours J., 3, 496 ,, 1 11 143 .... Reboul C. R., 78, 1773 27, 977 51 .... .... 1 11 143 .... jj A. C. [5], 14, 453 36, 129 ji JJ 11 141 .... Hartmann J. p. [2], 16, 383 34, 211 )i . 11 11 143-145 Hofmann A., 77, 162 CH^r.CH^CHjBr 11 160-163(719) Liquid Geromont A., 158, 370; B., 4, Iil.,49;42,157; 549 24, 697 11 1} 161-163 Niederist M. G, 3, 838 44, 450 jj 11 !> 165-5-167 c. Perkin 45, 525 (743) 135-5- 136-5c. (330) j .... .... JJ 160-165 Zander A., 214, 176 11 11 11 164-5-165-5 Liquid Freuad M. C. [2], 639 42, 157 (731) ,j JJ 11 162-163 .... Reboul C. R, 76, 1270 26, 1016 jj 1 11 162 .... jj C. R., 74, 613 25, 683 ,, JJ 11 165 .... jj C. R, 78, 1 773 27, 977 jj 11 11 165 c. .... jj C. R, 79, 169 27, 1153 5> Jl 11 164-165 jj A. C. [5], 14, 472 36, 129 jj Mixture ?) Jl 141-161 Linnemann A., 161, 26 vii., 1013 sopropyl bromide CH 3 .CHBr.CH 3 C 3 H 7 Br 60-63 (739) jj A. 161, 57 v.,890; vi., 965 n } j JJ i 60-63 Kekulko & Schrotter B., 12, 2280 n jj )! 60-3 .... Gustavson B. S. [2], 26, 346 34,49 jj jj n > 59-63 Zander A., 214,160 jj jj .... .. ji 59-62 .... Aronstein E. T., 1, 134 44, 173 j) jj .... .... n 60-63 .... jj B., 14, 608 ^ jj 11 59 c. .... Perkin .... 45, 455 ropyl bromide CH 3 .CH.,.CH 2 Br ;> 71-71-5 .... Fittig, Konig, and Z. C. [2], 4, 44 vi., 963 Scha'ffer ' 1 jj i, 1? 70-3-70-8 .... Chapman & Smith 2, 198 >j j T 11 )> 8-72 Linnemann A., 148, 259 vi., 964 j> ,) 11 n 1 .... Kekul6 & Schrotter B., 12, 2280 jj jj .... Jl 1-71-5 Aronstein B., 14, 608 jj ,, )J 0-8-71 c. .... Perkin 45, 455 jj ,, 11 0-71 .... Rossi A., 159, 79 vi., 964 jj >j 11 0-71 (749) -.... jj 1. I., 1, 230 24, 1032 ,j 11 j) 2 .... Pierre and Puchot A. C. [4], 22, 281 vi., 964 j ^ 11 sj 0-72 .... Zander A., 214, 159 118 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Propyl bromide CH 3 .CH2.CH 2 Br C 3 H 7 Br 70-82 .... Linnemann A., 162, 43 vii., 203 ,, 5> ) 70-8 )> A., 161, 26 vii., 1013 JJ 72 Pierre aud Puchot J. Ph. [4], 13, 93 vii., 1013 ; 24, 524 Hexabrombutylene ... C 4 H 2 Br 6 .... 52-53 Merz and Weith B., 11, 2246 36, 303 Hexabromisobutane .... C 4 H 4 Br 6 .... 108-109 >j >> B., 11, 2245 36, 302 Dibrombutylene .... C 4 H 6 Br 2 140-150 .... Caventou A., 127, 96 ; J., 16, 506 Crotonylene dibromide 148-158 .... A., 127, 349 ii., 965 Butine tetrabromide CHB^.CBr.j.CH^Me C 4 H 6 Br 4 113-115 Prunier C. R, 76, 1410 vii., 401 .... 115-116 Caveutou B., 6, 70 ) MM J) 99 .... A., 172, 291 Bromisobutylene CMe 2 :CHBr C 4 H 7 Br 88-92 .... Butlerow Z. C. [2], 6, 524 vii., 224, 401 Brombutylene .... )1 82-92 Caventou A., 127, 96 ; J., 16, 506 0- .... J) 86-88 .... .... A., 195, 126 )> .... 97 p. d. Jaffe A., 135, 301 vi., 158 dibromide .... C 4 H 7 Br 3 208-215 d. Caventou A., 127, 96 ; J., 16, 506 Bromisobutylene dibromide.... Me 2 .CBr.CHBr 2 214-218 Linnemann & Zotta A., 162, 33 25, 479 y-Iso-butylene dibromide .... CMe 2 Br.CH 2 Br C 4 H s Br 2 149 Linnemann A., 161, 178 vil.,216;86,396 )> I) 149-7 c. A., 162, 12 25, 476 I> )) 146-150 Linnemann & Zotta A., 162, 33 25, 478 )) 148-149 Linnemanu A., 162, 36 )> } 148-149 Hofmanu B., 7, 515 27, 792 y- 147-150(760); .... Perkin .... 45, 525 118-120 (313) > )) 146-148 .... Studer B., 14, 2188 149-152 .... Paterno G. I., 12, 337; B., 16, 802 )J 147-148 .... Nevol6 B. S. [2], 24, 122 29, 59 > n 147-148 C. R, 83,65 & 146 30, 621 )> i) 148 Grosheintz B. S. [2], 29, 201 34, 562 > )) )j 148 Le Bel and Greene B. S. [2], 29, 306 34, 773 Butylene dibromide ) 153 Liquid Puchot A. C. [5], 28, 507 46, 167 - CHEtBr.CH 2 Br 158 Wurtz & De Lynea J., 17, 500 v., 739 )J 156-159 (755) .... Wurtz B. S. [2], 8, 268 vi., 376 ,, )) 156-159 Linnemann A., 161, 190 25, 390 (?) 158-160 Chapman 20, 28 25, 397 5) .... .... ) ) 158-159 .... Nevole B. S. [2], 24, 122 29, 59 ,, j, j) 158 Grosheintz B. S. [21, 39, 201 34, 562 .... )) 160 .... Cahours J., 3, 402 ) 156-158 Le Bel and Greene B. S. [2], 29, 306 34, 774 156-160 .... ) 156 34, 773 ,, .... .... 5> C 4 H 7 Br 164-165 .... Nevol6 C. R, 85, 514 32, 868 )1 ) 164-165 .... i> a ~ 1> CHMe.Br.CHMeBr C 4 H 3 Br 2 166 .... Wurtz Z. C. [2], 5, 407 ; vi., 377; 25, A., 152, 23 396 )> 165-5-166 .... > B. S. [2], 8, 265 ; 34, 562 ; vii., J., 22, 365 216 jj ) 166-167 .... Linnemann A., 161, 199 25, 396; vii., 216 J) H .... 164-165 .... Grabowsky and A., 179, 331 29, 542 (757-5) Saytzeff 5> JJ 168 .... Grosheintz B. S. [2], 39, 201 34, 562 JJ jj )) )) 166 .... Le Bel and Greene B. S. [2], 29, 306 34, 773 8- .... (?) 175-195 *.* Grosheintz B. S. [2], 29, 201 34, 562 Butyl bromide CMe 3 Br C 4 H 9 Br 73-74 Liquid Beboul C. R, 93, 69 40, 1025 j> j> 72 .... Roozeboom B., 14, 2396 42, 154 COMPOUNDS CONTAINING THEEE ELEMENTS. 119 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Butyl bromide CMe 3 Br C 4 H 9 Br 70-5-72-5 c. .... Perkin .... 45, 457 Isobutyl bromide CHMe 2 .CH 2 Br 89 Wurtz A., 93, 114 v., 734 ,, ,, JJ 92 Chapman and Smith 22, 153 vi., 373 JJ U 87-88 Eeimer B., 3, 756 ; Z. C. vii., 222; 24, [2], 7, 26 121 ,, 1 11 89 Lieben and Eossi G. J. C., 1872 )> 90-5 .... Pierre and Puchot J. Ph. [4], 139 ; vii., 218 ; 24, A., 163, 278 524 JJ 92-33 c. Linnemann A., 162, 34 25, 476 )J i 91-3-92-3 c. Perkin .... 45, 457 J) ) 92 Williams 31, 541 Butyl bromide CH 2 Me.CH 2 .CH 2 Br 100-4 (744) .... Lieben and Eossi A., 158, 137 24, 520; vii., 216 >j 99-88 c. Linnemann A., 162, 39 vii., 203 jj , ' D J 99-94 5) A., 161, 198 25, 396 ,, u Jl 99-83 c. )) u Bromvalerylene C 5 H 7 Br 125-130 d. Eeboul A., 135, 373 v., 982 Valerylene dibromide .... C 5 H 3 Br 2 166- 172 .... D A., 135, 372 D JJ )I 170-175 u A., 132, 121 laoprene dibromide .... )) 175-180 Bouchardat C. B., 89, 1117 38, 323 Isopropyl acetylene dibromide Pr/3.CBr:CHBr J 175 1. 20 Bruylants B., 8, 407 Propyl Pr.CBr : CHBr 190 .... j> B.,8, 411 Valerylene tetrabromide .... C 5 H 8 Br 4 .... b. 10 Eeboul A., 132, 120 v., 982 Isoprene tetrabromide CH 2 Br.CBrMe.CHBr.CH 2 B 1. -18 Tilden C. N., 46, 120 44, 75 J* j .... .... 1. 20 45, 414 Pentine tetrabromide .... 11 .... 1. -20 jj Isopropyl acetylene tetra- Pr/3.CBr 2 .CHBr 2 )> 275 1. 20 Bruylants B., 8, 407 bromide Propyl acetylene tetrabromide Pr.CBr 2 .CHBr 2 J) 275 1. -15 B., 8, 412 Piperylene tetrabromide CMe 2 Br.CBr 2 .CH 2 Br (?) .... 114-5 Hoffmann B., 14, 665 40, 621 jj jj JJ 114-5 Schotten B., 15, 424 Isoprene hydrobromide .... C 6 H 9 Br 104-105 Bouchardat C. R, 89, 1117 38, 323 Valerylene hydrobromide ... .... J> 112 Eeboul A.&Z.C.[1867],173 v., 982 jj jj .... JJ 115 .... ) C. E., 64, 284 vi., 1123 Bromamylene .... JJ 100-110 Bauer A., 120, 167 vi., 119 symmetrical 110-112 A, 200, 37 JJ 110-115 M. C., 4, 81 JJ 115 Eeboul A. v., 982 )J JJ 115 Bouchardat C. E., 93, 316 40, 1114 .... .... JJ 117-118 Linnemann A., 143, 351 vi., 119 ffl abt. 175 Wurtz A., 123, 202 vi., 117 dibromide JJ \V C & H 9 Br 3 Solid Eeboul C. B., 58, 1058 vi., 120 Amylene dibromide CHMe 2 .CHBr.CH 2 Br QHl0^ r 2 25 Flavitsky & Kriloff B. S. [2], 28, 347 34, 20 ,, ,, .... j 67-70 Niederist A., 196, 349 36, 700 Valerylene dihydrobromide n 170-175 Eeboul A. v., 982 jj jj u 180 p. d. Z. C. [1867], 173 vi., 1123 Amylene dibromide CHEtBr.CHMeBr ii 178 p. d. Wagner & Saytzeff A., 179, 307 20, 547 ,, From iso-amylene u 170-180 Wurtz A. C. [3], 55, 458 vi., 119 D jt CHMe 2 .CHBr.CH 2 Br jj 170-180 Bruylants B., 8, 406 ,, ,, .... 5J 175-180 Bouchardat C. E., 93, 316 40, 1114 j> .... JJ 170-175 Helbing A., 172, 281 j> v CMe 2 Br.CHBr.Me J> 126-127-5 Perkin .... 46, 527 (215) JJ J> .... JJ 184-188 Thorpe and Young B., 5, 556 vii., 892 ; 24, 343 ; 25, 803 Amyl bromide CMe 2 Br.CH 2 .CH., C 5 H n Br 108-109 Wischnegradsky B., 10, 405 32, 420 and Flawitzsky jj ji 108 5 B., 10, 406 n j 107-109 Wischnegradsky A., 190, 328 34, 394 " " CHMe 2 .CHBr.CH, 113 c. \Viirf-7 vi., 113 )> i) 115-116 VV HI \jZi Wischnegradsky B., 10, 406 32, 420 and Flawitzsky 120 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Isoamyl bromide CHMe 2 .CH 2 .CH 2 Br C 5 H n Br 1187 .... Pierre C. E., 27, 213 ,, j> J 118'8 .... Haagen P. A., 131, 117 ?> TT J 1187 .... Mendelejef J. [1860], 7 vi., 110 > ) 121 .... Chapman & Smith 22, 198 n it * 118-124 Grimshaw .... 26, 310 rr ) 119-123 .... 32, 261 )> > JJ 120-4 (745-2 Balbiano G. I., 6, 229 31, 209 )> .... I 120'2-120'7c Perkin 45, 458 n )) )) 117-117-5 .... M. C., 2, 649 Amyl bromide CH 3 (CH 2 VCH 2 Br 128-7 (739-4) .... Lieben and Eossi G. I., 1,314; A., vi., 1137; 24, 159, 73 1034 Pentabrombenzene .... C 6 HBr 5 .... a. 240 .... vi., 263 i .... .... 260 Diehl B., 11, 191 Tetrabroinbenzene Br 4 =1.2.3.5 C 6 H 2 Br 4 .... 95 Korner vi., 263 i> I) 95-96 Losanitsch B., 15, 473 )J 1 .... 98 Mayer A., 13, 7, 218 vi., 263 J n 1> 329 97-2 Korner G. I., 4, 305 29, 212 I> )> 300-320 96, 98, & 99'E Wurster & Nolting B., 7, 1564 29, 389 ?r > )) .... 98'5 Richter B., 8, 1429 29, 390 > J> .... 98-5 Limpricht B., 10, 1540; A. 34, 220, 494 191, 175 Yf T > ; . > .... 98 Silberstein J. p. G, 27, 118 44, 660 Jf *H* .. J) 98-5 u ) 44, 661 J> .... = (?) .... 136-138 M. G, 2, 194 .... J> I ) .... 137-140 Kekule A., 137, 172 vi., 263 > H .... 160 Glaus and Ladl B., 14, 1169 40, 814 W "" )> .... 160 Halberstadt B., 14, 911 J> )> )> .... s. abt. 160 Eiche and Burard A., 133, 51 iv., 414 n 1) )) .... 175 Meyer B., 15, 46 42,607 TVibrombeuzene Br s =1.2.4 C 6 H 3 Br 3 266-280 44 A., 137, 224 vi., 263 , T ... .... J J 44 StUber B., 4, 969 25, 305 T, > )) 268-272 u. c. 43-44 Wurster B., 6, 1490 27, 369 >r "* > .... 43 A., 173, 145 28, 756 T > ) .... 44 Wroblewski B., 7, 10, 61 28, 58 J1 .... .... 44 j A., 192, 196 34, 978 .... j) )? ? 275-276 u. c. 44 Korner G. I., 4, 305 29, 223 )> .... .... > ) > 44 Liuipricht B., 10, 1538 ; A., 34, 220, 493 191, 175 f . =1.2.3 J .... 87-4 Korner] G. I., 4, 305 29, 224 =1.3.5 11 115 Stuber B., 4, 961 25, 305 > " .... 118-5 i) j> ,, > )> )) s. a. 278 u. c. 119-6 Korner G. I., 4, 305 29, 224 n >> 119 Silberstein J. p. C., 27, 104 44, 660 IT n ) .... 119-120 Losanitsch B., 15, 474 42, 955 , ? .... .... 1 .... 118-5 Jackson B., 8, 1172 29, 390 >T .... )> 1 .. 118-5 Eeinke A., 186, 271 32, 466 }, .... i) )i ) .... 118-5 Limpricht B., 10, 1538; A., 34, 220, 494. 191, 206 Dibrombenzene Br.Br=1.3 C 6 H 4 Br,, abt. 215 u.c. 1. 28 Meyer and Stuber B., 4, 958 5,303; vii., 139 11 .... .... > ) 1. -25 Wurster B., 6, 1492 27, 369 11 214-220 1. -27 Wurster and B., 7, 419 27, 691 Grubenmann ), ?> H .... 1. 28 Meyer B., 7, 1560 28, 758 11 .... .... 11 219-4 (754-8) 1. 20 Jorner G. I., 4, 305 29, 214 v j 11 216-4 (?) (?) > .... )> i> 223-224 1. 28 (?) (?) ) .... .... = (?) )! 217 u.c. Liquid )umreicher B., 15, 1867 J1 .... ,, =1.2 )1 213-215 c. 1 liese B., 2, 61 i., 263; 25, 304 T) ) )1 209-211 c. 5> A., 164, 176 u., 1.39; 26,64 1) .... .... ? 11 223-8 (751-6) 1 Corner G. I., 4, 305 89, 214 t) .-.. .... =1.4 ) 219 89 Couper A. C. [3], 52, 309 .,543;iv., 414 COMPOUNDS CONTAINING THREE ELEMENTS. 121 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dibronibeuzeiie Br.Br=1.4 C 6 H 4 Br, 219 89 Eiese B., 2, 61 vi., 263 ,, .... 11 11 11 89 Dumreicber B., 15, 33 42, 606 ,, U 11 215-217 88 u.c. 11 B., 15, 1867 11 l 11 89 Walker and Zincke B., 5, 116 25, 418 11 " 11 219 .... Korner G. I., 1874, 331 vii., 925 ,, .... ... 11 )) 89 Kekule A., 137, 173 218-219 88-5 Meyer A., 156, 281 vii., 925 ,, .... .... )1 > )> 89 Richter B., 6, 373 26, 1133 ,, .... 11 It )) 89 Wurster A., 173, 145 28, 758 ,, .... 11 11 > 220 89 Halberstadt B., 14, 911 ,, >1 > 218-6 c. 89-3 Korner G. I., 4, 305 29, 213 (757-66} 11 .... .... 11 218-3-218-4 c 11 11 i (747-2) V M )i 89 Boras A., 187, 350 32, 768 ,, .... .... 11 11 85-86 Neville & Winther 37, 435 ,, .... .... 11 11 11 .... 89 1) M 11 ,, .... .... 11 11 11 87-035 Mills P.E.S.[1881],205 Octobroiuhexylene .... 6 H 4 Br 8 .... 184 Merz and Weith B., 11, 2249 36, 303 (?) .... C 6 H 4 B ri! 120-125 .... Wahl B., 10, 1234 Brombenzeue ... C.H^Br 150 b. 20 Couper A. C. [3] 52, 309 i., 543 ^-'B 5 153"6 \V^orer 1> 154 Eleutnann & Koclilii B., 16, 1625 44, 1051 1> 154 Ladenburg B., 7, 1685 11 152-154 Fittisr A., 121, 361 iv., 414 1 154'86-155-52 ^0 Adrienz B., 6, 443 26, 886 11 155 Krafft B., 8, 1044 29, 71 11 154-6-155 Briihl A., 200, 139 38, 296 .... ! (742) 155-166 Riche A., 121, 362 11 1565 Meyer A., 137, 220 Octobrouihexane CHBr 2 .(CHBr) 4 .CHBr 2 '1 C^HgBry 135 Merz and Weith B., 11, 2250 36, 303 Dipropargyloctobromide CHBr^CBr,,. (CH 2 ) 2 .CBr 2 . 11 n. v. 140-141 Henry B., 6, 959 ; B., 7, vii., 1008 CHBr 2 22 .... .... .... 140-141 11 J. p. C. [2], 9, 321 27, 456, 1078 Bromdiallylene .... C 6 H 7 Br abt. 150 Liquid 51 B., 14, 400 40, 565 Oibromdiallyl C 3 H 4 Br.C 3 H 4 Br C 6 H 8 Br 2 205-210 ) B., 6, 956 26, 1215 i 51 210 c. 11 J. p. C. [2], 8, 57 27, 351 Dibromdiallyl tetrabromide .... C 6 H 8 Br 6 76-77 11 B., 7,23; J.p. C. 27, 456, 1078 [2], 9, 231 Hexabromhexane CH s Br.(CHBr) 4 .CH,Br 11 152 Merz and Weith B., 11, 2250 36, 303 Hexine dibromide Me.CBr:CBr.(CH 2 ) 2 Me C 6 H 10 Br 2 d. 130 1. 20 Hecht B., 11, 1054 34, 717 Diallyl tetrabromide CH 2 Br.CHBr.(CH 2 ) 2 CHBr. ^6Hi Br 4 .... 62-5-33-5 Wagnerand Tollens B., 6, 589 26, 1122; vii., CH 2 Br 46 11 11 11 60-63-5 11 ! ) 11 Tetrabromhexane .... j> 318 c. 112 A., 139, 251 ,, >i 120 Z. C. [1871], 699 ,, .... .. . From iododipropylene n 142 Bouchardat C. R., 74, 809 25, 410 Bromhexylene C 6 H n Br 99-100 Liquid Destrem A. C. [5], 27, 5 11 From petroleum 1) 138 Reboul and Truchot A., 172, 70 27, 783 i, .... ! 135-140 .... Cuventou 11 11 /3- mannite ) 1U8-141 Hecht and Strauss 11 11 (738-5) /3-bromhexylene dibromide ... C 6 H n Br 3 125-135 c. .... ...* A., 135, 126 Hexylene dibromide CMe 2 Br.CMe 2 Br C 6 Hi 2 Br 2 140 p. d. Pawlow B., 11, 513 34, 563 11 11 )1 11 140 Eltekoff B., 16, 399 > 11 PACHBr.CHBrMe (?) 11 139-140 11 B., 11, 412 34, 482 " 51 CMe 2 Br.CMe 2 Br n 168-169 Eizza J. R. [1882], 99 42, 491 11 11 11 .... 169 Kaschirsky B., 11, 984 36, 46 " 11 11 .... 169-170 11 C. C. [1881], 278 42,37 ' 11 11 180-190 .... Helbing A., 172, 281 11 11 From petroleum n 192-198 .... Pelouze & Cahours J., 16, 526 24,343 122 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Hexylene dibromide i* i >i .... M .... Ifexylidene dibromide llexyl bromide i i i) Pentabroratoluene )> Tetrabrom toluene ,. jj .... .... Tribrom toluene ) .... .... *> .... .... ,, From mannite paraffin C 4 H 9 .CHBr.Me CHMePr.CH 2 Br CH 3 .(CH.,) 4 .CHjBr C fi Br 6 Me Me.Br 4 =1.2.3.4.6 51 =1.2.3.4.5 =1.2.3.5.6 Me.Br 3 =1.3.4.5 =1.2.3.4 =1.2.3.5 =1.2.3.6 =1.2.4.6 =1.2.?.6 13 5 '> C 6 H 12 Br 2 ? )> C 6 Hi 3 Br ) C 7 H 3 B. 5 J 10 C-H 4 Br 4 > J> n C 7 H 5 Br 3 H n 11 11 11 )l 11 11 11 D D M 51 C 7 H 6 Br 2 ** n )> )) n i j u > l > )> )) )> j> ) ' ) u M )1 195-197 195-200 190-200 210-212 210-212 205 143-145 142-145 155'5 (743-87) 260 290 290 130-140(20) 236 237 238-239 246 238-239 237 246 246 238-239 240 239-241 236 240 7J.fi 282-283 282-283 283-285 105-108 106-8-108 111-111-5 116-117 I. 20 44-4-^4-7 52-53 58-59 66 70 70 88-89 110-111-5 111-2-112 112-113-6 111-8-112-8 lll-S-112-8 150 Liquid 1. 15 30 41 (il b. 20 1. 20 1. 20 1. 20 1. 20 Liquid I. -20 Liquid 1. 10 Liquid Liquid 1. 20 Liquid 1. f. m. 1. 20 Liquid 27-4-27-8 27-4-28 39 Hecht and Strauss Thorpe and Young Thorpe and Young Schorlemiuer Lieben and Janeck Gustavson Neville & Winther ) )! > )> Wroblewsky Neville & Wiuther 7> 1 " )) )> Wroblewsky Neville & Winther n )1 J> )) J 1 Pfankuch Michaelson and Lippmann Jackson Jackson and White Jackson Wroblewsky n Neville & Winther Wroblewsky Neville & Winther i ) U Wroblewsky Burghard Neville & Winther Jannasch Wroblewsky Neville & Winther Wroblewsky Neville & Winther ! 5> A., 172, 67 B., 5, 556 A., 128, 228 J. [1862], 411 A.,124,293;165,9 A., 165, 1 P. T., i. [1878] M., 4, 34 A., 187, 137 B. S. [2], 28, 347 B. S. [2], 26, 346 B., 13, 975 j> B., 13, 976 B., 13, 975 A., 168, 194 B., 13, 975 B., 13, 974 B., 13, 975 A., 168, 195 Z. C. [2], 7, 271 B., 13, 974 B., 14, 417 i B., 13, 974 J. p. C. [2], 6, 108 B. S. [2], 4, 251 B., 9, 932 B., 13, 1218 B., 9, 932 B., 9, 931 Z. C. [2], 6, 239 Z. C. [2], 7, 135 A., 168, 147 Z. C. [2], 7, 271 A., 168, 185 A., 168, 191 B., 13, 973 A., 168, 184 B., 8, 560 B., 13, 964 A., 176, 287 A., 168, 185 B., 13, 973 A., 168, 147 B., 13, 965 B., 13, !)(!4 R. 13. flfifi 27, 783 25, 803 ; vii., 892 32, 866 32, 880 34, 48 34, 49 37, 450 37, 44!) 37, 451 n 27, 54 37, 451 11 > 11 27, 54 24, 1062 37, 451 37, 445 37, 451 39, 83 39, 84 11 26, 363 ; vii., 656 vi., 281 30, 512 38, 879 30, 512 11 vi., 280 24, 564 vii., 1165 24, 1062 ; vii., 1165 vii., 1165 j 37, 451 27, 54 37, 439 37, 446 37, 451 37, 440 27, 53 37, 451 28, 889 27, 53 37, 451 27, 53 37, 434 )) 37. 437 13-) 5 j ) ,j ) 11 Benzylene dibromide Brombenzyl bromide i> i j) Dibromtoluene =1.2.4.5 51 11 1 11 *1 = C 6 H 6 .CHBr 2 C 6 H 4 .Br.(CH 2 Br)=1.2 11 =1.3 =1.4 Me.Br 2 =1.2.(3 ?) 11 11 11 =1.3.5 =1.2.4 )> 11 > =1.2.6 1 1) 11 1 =1.2.6 or 1.2.4 =1.3.4 1 J> > =1.2.5 (?) i) =1.2.3 J> )1 , =1.3.5 it ,, 4) .... COMPOUNDS CONTAINING THREE ELEMENTS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Dibromtoluene u .... .... ,, .... .... i Hexbromheptine Dibromtoluene tetrabromide Benzylbromide ,, .... ,, .... .... Me.Br 2 := 1.3.5 =1.2.3 or 5 > =1.3.5 =(?) =1.3.4 C 6 H 5 .CH 2 Br 11 Me.Br=1.2 i 11 11 11 11 11 11 11 11 n 11 11 n 11 11 11 =!.() 11 11 11 ii =1-3 11 11 11 I) 1 1) 11 1 11 11 1 11 =1.4 >1 J1 11 ) 11 ) )1 >5 1> 11 11 1) >1 )1 ) 11 11 )1 CHMeBr.CBivCHPrBr FromCH 3 .(CH 2 ) 4 .C;CH 11630.0^16^. 1 C\H n CHBr.Me CH 3 (CH 2 ) 4 .CHBr.Me Me.(CHj) 5 CH 2 Br C 7 H 6 Br, 1> 11 n i* C 7 H"Br, 11 C 7 H 7 Br 11 JJ 11 1} 1> H 11 11 M 11 i n 11 n i) ii 1) M > ! > > 11 11 11 JJ C 7 H 12 Br 4 C 7 H 13 Br 11 C 7 H 14 Br 2 C 7 H" 5 Br D 249 239 241 abt. 245 245 198-199 Wl-5-202-5 c. 202 181-183 182 182-183 181-182 179-180 180-5-181 180 181-182 182 182-183 179 181 182-5-183 u.c. 185-185-5 c. 182 182-183 181-182 182 183-5 c. 184-184-1 (754-1) 184-3 (758-74) 184 185-2 184-6 (760-74) 181-183 185 185-2 185 abt. 130 165 d. 165-167 165-167 173-5 (750-6) 39 42-5 42-5 60 107-108 107-108 134 134 1. 20 Liquid I. 20 Liquid Liquid Liquid Liquid Liquid 1.-20 1. 20 Liquid 28-8 28-29 25-4 28-2 28-5 28-29 28-29 28 29 29 28-5 Liquid Liquid 150 152 Liquid Neville & Winther Wroblewsky j H Fittig Wroblewsky R6nard Kekule tt Lauth and Grimaux Rosenstiehl and Nikiforoff Wroblewsky Hubuer & Retschy Jannasch & HUbner Longuinine Reyman HUbner and Post Kb'rner Neville & Winther Glinzer and Fittig Lauth and Grimaux Kekule HUbner & Retschy Wroblewsky t Grite Kiirner ?> Neville & Winther Gissmann HUbner & Retschy Korner HUbner & Wallach HUbner and Terry HUbner and Post HUbner and Roos Fittica Beckett and Wright Neville & Winther Morris Cloez Bruylants Thorpe and Young Kaschirsky Schorlemmer Venables Cross B., 13, 966 Z. C. [2], 7, 210 A., 168, 147 Z. C. [2], 7, 202 ; A., 168, 190 A., 147, 41 Z. C. [2] C. R., 91, 419 A.C. [6], 1, 223 A., 137, 190 J., 20, 662 B. S., 7, 108 Z. C. [2], 5, 635 Z. C. [2], 7, 135 A., 168, 171 Z. C., 7, 618 Z. C. [2], 7, 706 ; A., 170, 117 B., 4, 516 B. S. [2], 26, 532 A., 169, I G. I., 4, 305 J., 18, 538 B. S. A., 137, 198 ; J., 20, 663 Z. C. [2], 7, 618 Z. C. [2], 7, 609 A., 168, 155 A., 192, 196 A., 177, 231 G. I., 4, 305 A., 216, 200 Z. C. [2], 7, 618 C. R, 68, 824 G. I., 4, 305 A., 154, 296 Z. C. [2], 7, 232 A., 169, 6 B., 6, 799 A., 172, 303 41, 179 C. R., 78, 1565 B., 8, 409 B., 5, 556 B., 11, 984 C. C. [1881], 275 A., 209, 81 P. T. [1878]. 1 B., 13, 1650 A., 189, 3 37, 437 vii., 1165, 1177 24, 686; 25,698 24, 686; 27, 54; vii., 1165 vi., 280 vii., 1165 38, 893 46, 844 v., 853 vi., 279 v., 853 vi., 280 24, 564 27,53 25,697;vii.,1164 25, 893; 27, 257 24,68o;vii.,1164 31, 459 27, 58 29, 216 37, 451 v., 853 M v.,853;vi., 279 25, 697 25, 698 ; vii., 1164 27, 51 34,977 29, 72 29, 216 !> 37, 451 44, 335 25, 696 ; vii., 1164 vii., 1175 29, 216 vi., 280 25, 1005 27, 56 27, 165 28,60 29, 6 37, 451 27, !)73 25, 80.3 ; vii., 892 36, 46 42,37 32, 866 40,82 32, 12(i R > .... .... . .. ,, Methylpropylallylene tct ra- bromide Bromheptylene ,, .... Heptylene dibromide ) >! ." Heptyl bromide M J) -". ,. ,, .... , V lL>4 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. a-Bromstyrene C 6 H 5 .CH : CBr C 8 H 7 Br d. Liquid G laser A., 154, 168 ; B., 6, 493 ft- n C 6 H 5 .CBr:CH., 117 .... Barisch J. p.C. [2], 20, 173 38,43 ft- 11 219-221 c. .... .... A., 195, 142 n ** *" n 11 150-160 (75) A., 216, 291 ft- ,, 228 Liquid Glaser A., 154, 168 vii., 1101 dibromide C 6 H 6 .CBr 2 .CH 2 Br C 8 H 7 Br 3 37-38 A., 195, 142 Styrolene dibromide C,H 6 .CHBr.CH 2 Br C 8 H s B.- 2 a. 200 67 .... i., 982 i >i 11 11 68-69 Breuer and Zincke B., 11, 1399 34, 885 11 D tt 73 Miller B., 11, 1451 ,. 11 73-5-74 Breuer and Zinckfi B., 11, 1400 J) 1 68-69 Radziszewsky B., 6, 493 26, 1028 > >i 11 74-74-5 A., 216, 288 Dibronixylene Me 2 .Br 2 =1.3.?.? tl 256 69 Fittig, Ahrens, and A., 147, 25 vi., 294 Mattheides =1.3.4.6 H 72 Jacobsen and Wein- B., 11, 1534 36,61 berg =1.3.?.? ., 255-256 72 .... A., 156, 236 i, = (?) 252 .... .... A., 192, 216 = 1.4.2.5 .... 72-73 Fittig, Ahrens, and A., 147, 26 vi., 294 Mattheides 11 7.5-5 Jannasch B., 10, 1357 Tolylene or xylylene di- C 6 H,.(CH 2 Br) 2 =1.2 v .... 93 Baeyer and Perkin B., 17, 122 46, 753 bromide 11 V f It 94-6 Colson C. R., 98, 1543 46, 1000 11 11 (0 240-250 143-143-5 Radziszewsky and B., 15, 1747 42, 1283 Wispek 11 11 = 1.3 '1 240-250 140-141 11 11 B., 15, 1745 11 11 11 = 1.4 11 240-250 140 11 ii B., 15, 1744 11 11 1* 11 11 143 Bildermnnn B., 5, 702 25, 1013 11 >I 11 It 11 .... 145-147 (Jrimaux Z. C. [1870], 394 ; 25, 817, 1013 ; A. C. P. [4], 26, vii., 1209 331 ; C. R., 70, 1363 Bromxylene .... Me.Me.Br =1.4.5 C H Br 199-5-200-5 10 Jannasch A., 171, 82 27, 468 ^S 9 9-10 (jrissmann A., 216, 200 44, 335 11 it tt =1.3.6 205-208 Weinberg B., 11, 1062 34, 724 11 *. = (?) 11 203 Kekulc v., 1057 \ / 11 203-204 Fittig and Ernst J., 18 556 tt \ / = (?) H 207-5 Kekul6 A., 137, 186 tt V 1 / = (?) M 212 Wahlfovss A., 133, 53 v., 1057 tl \'/ 1! 212 Beilstein J., 17, 530 H = 1.3 ? 205-208 Ahrens Z. C. [2], 5, 102 vii., 1175 tt *-/ i =1.3.4 11 203-204 Fittig and Ahrens A., 147, 31 = 1.3.5 204 1. 20 Wroblewsky B., 9, 495 30, 406 1) i.u.v 11 204 Tjiouid A., 192, 215 34, 978 It ll 11 Ethylbrom benzene C 6 H 4 .Br.Et=1.4 ll 199 Liquid Fittig and Konig A., 144, 282 iv.,485; vi.,292 11 ll 200 Fittig A., 133, 226 v., 1057 11 n .. 11 11 204 1. f. m. Aschenbrand A., 216, 222 44, 320 Xylyl bromide C 6 H 4 .Me.CH 2 Br =1.2 it 216-217 (742) Liquid Radziszewsky and B., 15, 1747 42, 1283 Wispek =1.3 ll 215 (735) Liquid 11 11 B., 15, 1745 =1.4 ll 218-220 (740) 31 11 11 B., 15, 1743 n-Phenylethyl bromide Ph.CHBr.CHj ,, 145-150 (30) Hanriot & Guilbert C. R., 98, 525 46, 733 11 11 11 ll d. Liquid Radziszewsky B., 7, 140, 1126 n- 11 ll 148-152 (500) Thorpe Z. C., 1871, 130 a- 1! n 200-210 (?) Liquid Berthelot B. S., 10, 343 ft- Ph.CH 2 .CH,,Br 11 d. in vac. Liquid BernthMtt&Bendei B., 15, 1983 Oaprylidene bromide C 8 H u Br 203-205 A., 142, 300 Tribromoctine .... C 8 H u Br 3 246 Ruiiard C. R., 95, 141 42, 1179 Bromoctylene.... fl TT T> 150 Cloez C. R., 78, 1565 27, 973 '8 15 185 A.. 142, 298 COMPOUNDS CONTAINING THREE ELEMENTS. 125 Name. Constitution. Formula Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Gh. Soc. Bromoctylene . C 8 H 15 Br 185-190 .... Thorpe and Young A., 165, 15 ; B., vii., 892; 26, 5, 558 803 Octylene dibromide .... . C,H 16 Br 2 abt. 200 d. .... Nieson .... 27, 847 Octyl bromide CH^CHj^CHjBr C 8 H 17 Br W3-W4 e. Perkin .... 45, 458 .... J JJ 198-200 Zincke A., 152, 5 vt, 878 )) not at 190 Nieson .... 27, 847 Secondary B 190 d. .... Bouis A. C. [3], 44, 130 iv., 170 ?> 5 188 Lachowicz A., 220, 168 46, 166 Pentabromisopropyl benzene C 6 Br s .CHMe, W8r, 90-100 Meusel Z. C. [2], 3. 322 vi., 297 j ) 97 A., 149, 326 Oinnyl tribromide C 3 H 4 Ph.Br 3 C 9 H 9 Br,, 124 Grimaux B. S., 20, 121 26, 1139 Mesitylene tribromide C 6 H 3 .(CH 2 Br 3 .) =1.3.5 )) 94-5 Colsou C. R, 96, 713; 44, 734 ; 46, 57 C. R., 97, 177 Bromomesitylene dibromide Me.(CH 2 Br).,.Br=1.3.5 (2or4 81-82 C. R, 97, 177 46, 58 Tribromtrimethyl benzene ... Me 3 .Br 3 "= (?) 219 Preis and Raymam B., 12, 219 36, 623 Tribrommesitylene =1.3.5.2.4.6 )) 224 Fittig and Storer A., 147, 11 vi., 298 Tribrompseudocumene =1.3.4.2.5.6 ? 225-226 Fittig & Laubingei Z. C. [2], 4, 578 vi., 297 Tribromhemellithene =1.2.3.4.5.6 .... 245 Jacobsen B., 15, 1858 44,53 Dibrommesitylene Me 3 .Br, =1.3.5.2.4 C,H 10 Br 2 285 60 Fittig and Storer A., 147, 10 vi., 298 v .... .... ' )) .... 60 Eobinet C. R, 96, 500 44, 577 u *i 277-278 64 Sussenguth A., 215, 247 44, 469 ,, )> M > 276-278 64 JJ I ) i) i) )) 278 64 Jannasch & Sussen- Z. C. [2], 7, 454 25,240 guth Dibrompseudocumene =1.3.4 .? .? 277 63 D Mesitylene dibromide C,H 3 .Me.(CH s Br) 2 =1.3.5 )) 178-190 i. v. 66-3 Robinet C. R, 96, 500 44, 577 i) ? " D .... 66-4 Eobinet and Colsou C. R, 96, 1863 44, 1095 it i> 5) .... 66-4 Colson C. R, 96, 713 44, 734 Allylbenzene dibromide Ph.CHBr.CHBr.CH 3 1 60 Radziszewsky B., 7, 143 27, 470 j> ) 65-66 ji C. R, 78, 1153 27, 798 > j> .... 66-5 RiigheimeB A., 172, 131 27, 894 j) - ) .... 67 Perkin .... 32, 667 Brommesitylene Me 3 .Br =1.3.5.6 C 9 H n Br 225 1 Fittig and Storer A., 147, 6 vi., 298 Brompseudocumene =1.3.4.6 72 Jannaach B., 7, 692 27, 987 ,, M ) 30-#40 72 Sussengutli. A., 215, 242 44, 469 i) .... .... >j ) 73 Gissmann A., 216, 200 i 44, 335 Bromtrimethyl benzene = (0 )1 .... 73 Fittig and Ernst Z. C. P. [1865], 572 v., 1058 Mesitylene bromide Me 2 .CH 2 Br =1.3.5 )I 29-231 (740) 37-5-38 Wispek B., 16, 1577 44, 1095 s.d. > 1> 230 38-3 Colson C. R., 96, 713 44, 734 Ethyl bromtoluene C 6 H 3 .Me.Et.Br =1.4.6 ) Liquid Morse and Remsen B., 11, 225 Propyl brombenzene C 8 H 4 .Br.Pr =1.4 )J 220 c. Liquid Meyer and Miiller B., 15, 698 Isopropyl brombenzene C,iH 4 .Br.Pr/3 =1.4 18-220 Liiquid Mensel Z. C. [2], 3, 322 vi., 297 :i 5) ! ) 9tt I. 20 Jacobsen B., 12, 430 ; 36, 624 Phenylpropyl bromide C.H..C!,H a Br 20 jiquid Radziszewsky C. R, 78, 1153 ! 27, 798 Bromnonylene .... C 9 H 17 Br 08-212 Thorpe and Young B., 5, 556; A., 25, 803; vii., 165, 19 892 Nonylene dibromide.... .... C 9 H 18 Br 2 40-200 Wurtz B. S. [1863], 300 iv., 135 Hexabromnaphthalene C 10 H 2 Br 6 245-24G Gessner B., 9, 1511 Tribromnaphtluilene .... c io H 5 Br 3 SO .... iv., 11 "- > J .... 75 Glaser A., 135, 43 vi., 845 0- a,a 2 ; a, H .... 85 Jolin B. S. [2], 28, 5].-) 7- .... JJ .... 86-5 j? 32, 902 ,, a.0,/3, ; ) 13-114 Meldola B., 16, 421 43, 4 ?-Dibromnaphthalene .... C lu H 6 Br,, 59 .... iv., 11 ? .... i> .... 61 Guareschi A., 222, 262 46, 842 a- .... rt .... 60-5-61 Jolin B. S. [3], 28, 514 32, 901 a- .... V 60-5-61 Magatti G. I. [1881], 357 42, 203 "- A; 63 Meldola 43,5 - .. a/3,; 64 D B., 12, 1963 38, 260 - A; ) -. 67-68 Canzonori G. I., 12, 424 44, 67 126 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. a- Dibromnaphthalene C 10 H 6 Br., .... 67-5-68 Guareschi G. I. [1881], 542 ; 42, 734 ; 46, A., 222, 262 842 .... .... 68 G. I. [1881], 542 42, 734 ... a A; .... 68-70 Meldola 43,2 /3 H 70-71 Guareschi B., 10, 294 .... .... 76 G. I. [1881], 542 42, 734 >i isomeric 76 Glaser A., 135, 43 vi., 845 f- ,, a.Hg. 76-77 Darmstadter and A., 152, 304 Wichelhaus P~ 11 *. .... .... 81 Magatti G. I. [1881], 357 42, 203 S- ., .... 81 Glaser A., 135, 49 3 .... .... 81 Jolin B. S. [2], 28, 514 32, 901 0- 0,0.; .... 81 Meldola 43, 1 /3- .... .... 81 Giovannozzi G. I. [1882], 147 42,854 3- a,a 2 ; 310 s. d. 81-62 Guareschi G.I. [1881], 542; 42, 734 ; 46, A., 222, 262 842 a, ; a? .... 81-82 Meldola 43, 4 3- .... 85 Jolin B. S. [2], 28, 514 32, 902 ,, ... Mixture (?) abt. 110 Baumhauer B., 4, 926 25, 137 y- .... .... 120 Magatti G. I. [1881], 357 42, 203 ?- ,, 126-127 Darmstadter and A., 152, 304 vi., 845 Wichelhaus y- ,, 126-127 Guareschi G. I. [1881], 542 42, 734 y- "l? 2 129 Jolin B. S. [2], 28, 514 32, 901 Br; Br 325*5 s. d. 130-131 -5 Guareschi A., 222, 262 46, 842 *- .... 140-5 Jolin B. S. [2], 28, 517 22, 902 <- .... 159-5 a-Bromnaphthalene .... C 4 H 4 .C : C.CjlI.Bi- C 10 H 7 Br 277 Liquid Wahlforss Z. C. [2], 1, 3 vi., 844 o- 276 Merz and Weith B., 10, 757 "' 270-280 .... .. ,, B., 15, 2721 a- ., 285 Glaser A., 135, 41 vi., 844 a ~ 11 277 .... Eother B., 4, 851 25, 82 a- 277-278 .... Otto and Mories A., 147, 175 - Liquid Liebermann A., 153, 225 31, 607 o- Liquid Palm B., 9, 499 30, 206 - ,T Liquid Smith 32, 563 0- n 277 Solid Eother B., 4, 851 vii., 845 0- ., M 55-60 Canzoneri G. I., 12, 424 44, 67 8- M 68 Liebermann A., 183, 268 31, 607 ; 44, 67 ft- 277 68 Palm B., 9, 500 30, 206 ; 44, 67 0- .... 69 M 0- > 69 Smith .... 32, 563 dihydride .... 10 H 9 Br 269-270 Agrestini B., 16, 796; G. I., 12, 495 Brom-/3-butenyl benzene .... .... C 10 H n Br Liquid Perkin .... 35, 139 di- .... O 10 H n Br 3 63-5 .... 35, 140 bromide Tribromdimethylethyl ben- EtMe 2 Br 3 1.3.5.2.4 6 a. 360 21ft Jacobseu B., 7, 1434 28, 259 zene /-Phenylbutylene dibromide From CsHyCHiVCH, CioH ]a Brj Liquid Eadziszewsky B., 9, 261 .... Liquid Fittig B., 14, 1825 ft' '! C 6 H 6 . CH 2 . C 3 H 6 Br j 1. 20 Perkin C. f. A., 216, 125 35, 139 o- 67 ,, C. f. A., 171,229 32, 668 1- From C 6 H 5 (CH 2 ) 3 .CH 3 70-71 Eadziszewsky B., 9, 261 29, 916 Diethylbenzene dibromide .. C 6 H 4 (C 2 H 4 Br) 2 M 200-230 .... Hanriot & Guilbert C. E., 98, 525 46, 733 Uibromcymene CeHj.Me.Pr-.Br, = 1.4.(?) 2 272 u. c. Liquid Wimmel B., 13, 903 Dibromtetramethyl benzene Me 4 .Br 2 = 1.2.4.5.3.6 v .... 200 Ador and Eilliet B., 12, 329 ., = 1.2.3.5.4.6 199 Januasch & Fittig Z. C. [2], 6, 162 vi., 828 .. ,, H 199 Jannasch B., 8, 356 T, 199 Ador and Eilliet B., 12, 329 26, 527 V > ,. 201 Montgolfier A. C. [5], 14, 87 34,899 1, V n .. .... 202-203 .... J. [1879], 372 COMPOUNDS CONTAINING THKEE ELEMENTS. 127 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dibromtetramethyl benzene Me 4 .Br 2 =1.2.3.5.4.6 (J 10 H, 3 Br 209 Jacobsen B., 15, 1853 44, 52 H u 11 11 .... 309 Arm strong & Miller B., 16, 2255 46, 44 (?) > 196-202 .... Z. C. [1867], 689 Bromocymene Me.Pr.Br = 1.4.6 C 10 H 13 Br 233-235 c. Liquid Landolph B., 5, 267 vii.,420;25,473 11 11 )> 228-229 Fittica A., 172, 311 28, 59 ,, = 1.4.? ? 228-229 .... Gerichten B., 11, 1092 34,787 11 It JJ 224-226 B., 11, 1791 36, 230 a-Bromisocymene Me.Pr9.Br = 1.3.6 n 233-235 Liquid Kelbe B., 15, 40 42, 618 - = 1.3.? > 224-225 Liquid > B., 15, 41 42, 619 Bromtetramethyl benzene .... Me 4 .Br= 1.2.4.5.6 61 Gissmann A., 216, 210 44, 335 i) ?! It > US A., 198, 388 n !) = 1.2.3.5.6 ?> 252-254 Crystalline Biedlefelt )) 38, 38 Action of Br on Laurene .... .... (.' 10 H 13 Br 3 (?) .... 125 Montgolfier A. C. [5], 14, 5 34, 899 From camphor .... ( : ioH 14 Br 4 164 S warts B., 15, 1621 Bromterebene hydrobromide C 10 H I5 Br.HBr. ( ; KiH 16 Br., 80 Papasogli G. I., 6, 538 31, 593 Cajputene tetrabromide c; ioH, 6 Br 4 60 Schmild J. [1860], 482 i., 711 Tetrabromide of C 10 H 16 From colophony )> 120 Rfinard C. E., 92, 887 40, 739 Terpene hydrobromide From turpentine Ci H 17 Br 60 Biedermann & Op- B., 5, 628 25, 1009 penheim < > 11 H .... 80 Papasogli B., 10, 84 Borneol bromide j 74-75 Kachler A., 197, 98 36, 1040 Terpene dihydrobromide C 10 H 16 .2IIBr. C 10 H 18 Br 2 42 Oppeuheim A., 129, 149 v., 923 Bromdecylene Ci H, 9 Br abt. 215 Liquid Reboul and Truchot B. S. [2], 8, 422 vi., 542 Phenylpeiityleuedibromide .... Ph.C 6 H 7 Br a C u H 12 Br 2 .... 53-54 Schramm A., 218, 383 44, 977 Plienylisopentylenedibromide 11 )) 128-129 n i) Tribrompropyldimethyl ( ! 6 Br 3 .Me 2 .Pr CuH^Br, .... 125 Fittig, Kolbrich & A., 145, 149 vi., 304; 46, benzene Jilke 43 Tribromisoamyl benzene QftftfcAHn .... 140 Tollens and Fittig A., 131, 303 vi., 303 )> )i J* I) 140 A., 141, 161 Tribromdiethyltoluene Me.Et 2 .Br 3 =1.3.5.2.4.6 Jl .... 206 Jacobsen B., 7, 1435 28, 259 (?) ' 205 Preis and Raymann B., 12, 219 36, 623 Isopropylvinylbenzenedi- C 6 H 4 .Prf.(CHBr.CH s Br) CnH 14 Br 2 71 Perkin J. [1877], 380 32, 664 bromide Amylbenzeaebromide ^uH, 5 Br 1.0 Essner B. S. [2], 36, 212 42, 46 Dibromdiphenyl Br.Br=4 ; 4' C 12 H 9 Br 3 164 Lellmann B., 15, 2837 44, 343 1* ? 104 Strasse and Schultz A., 210, 191 42, 521 .... 164 .... A., 132, 204 iv., 410 jj 11 162 Carnelley C. f. A., 189, 138 37, 706 355-360 (?) Schultz A., 174, 201 28, 149 I >ibromacenaphthene 10 H 6 .CHBr.CHBr > 121-123 Blumenthal B., 7, 1093 Bromdipheuyl C 6 H 4 .Br.Ph=1.2 C 12 H a Br 296-298 Schultz & Strasse B., 14, 612 40, 604 n n 11 u 296-298 S.20 Schultz, Schmidt, & A., 207, 353 40, 912 Strasse 11 * ' =1.4 310 89 Engelhardt& Latch- Z. C. [2], 7, 259 vii., 937 inoff >' j 310 89 Schultz B., 5, 682 25, 1005 i )' V j> .no c. 89 i A., 174, 201 28, 149 Bromacenaphthene Tribromethylnaphthalene .... C 10 H 5 Br.CH.,.CH i i " n C 12 H i) Br 3 52-53 127 Blumenthal Cannizzaro and B., 7, 1095 B., 13, 1517 C 10 H 4 Br 3 Et Carnelutti 11 11 )i 127 Carnelutti B., 13, 1672 Tribromdimethylnaphthalene C 10 H 3 Br 3 Me 3 )! 145-147 Giovanozzi G. I. [1882], 147 42, 855 n JJ )J 228 Cannizzaro and Car- G. I., 12, 393 ; B., 44, 80 nelutti 13, 1517 Dimethylnaphthalene hexa- e io H 6 Me 2 .Br 6 Ci 2 H 12 Br 6 184 Giovanozzi G. I. [1882], 147 42, 5 bromide Hexamethylbenzene hexa- .... (?) 227 Hofmann B., 13, 1732 bromide Phenylhexylene dibromide .... Ph.C,H^r, C.-H^Br, 79-80 Schramm A., 218, 383 44, 977 I )ipropyldibrombenzene Rr r Br,=1.4.(J), C 12 H 1(i Brj 48 Korner A., 216, 227 44, 322 128 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. laopropylallylbenzene dibro- Pfl8.C 6 H 4 .CHBr.CHBr.Me C 12 H 16 Br 2 .... 59 Perkin J. [1877], 380 32, 665 mide Hexabromhexamethyl- C 6 Br 6 Me, (?) C 12 H 18 Br 6 (?) .... 227 Hofmann B., 13, 1732 40, 261 benzene Tribromfluorene .... C 13 H 7 Br 3 161-162 Barbier A. C. [5], 7, 492 31, 72 Dibrom-a-methylenedipheny- .... C 13 H 8 Br 2 162-163 Fittig and Schmitz A., 193, 137 36, 164 lene , -<*- n 153-154 Grsebe A., 174, 194 ~P~ > XC 6 .CHj.C,X 165 Hodgkinson & Mat- B., 16, 1103 43, 165 i 1 thews -a- 166 Holm B., 16, 1081 44, 921 -0- .... .... 166-167 Barbier A. C. [5], 7, 490 31, 71 -y- 162 Carnelley 37, 710 Brom-/3-methylene dipheny- HA.CHj.CeH.Br C 13 H 9 Br .... 101-102 Hodgkinson & Mat- B., 16, 1103 43, 165 lene 1 l thews Diphenylbrommethane CHBr.Ph 2 C 13 H n Br .... 45 Friedel and Balshon B. S. [2], 33, 339 38, 558 Brom-p-tolylpheuyl From Ph.C 6 H 4 .Me=1.4 127-129 Carnelley .... 57, 707 130-131 .... .... Isopropylbutenylbenzene- C 6 H 4 .Pr S .CHBr.CHBr.Et C 13 H 18 Br 2 77 Perkin J. [1877], 381 32, 666 dibromide Octobromanthracene .... C 14 HjBr 8 .... Crystalline Diehl B., 11, 179 34, 429 Heptabromphenanthrene .... .... C, 4 H 3 Br 7 a. 270 Zetter B., 11, 172 34, 510 Heptabromanthracene .... n. f. 350 Diehl B., 11, 178 34, 429 Hexabromphenanthrene .... C 14 H 4 Br. 245 Zetter B., 11, 172 34, 510 Hexabroiuanthracene .... 182 p. d. Anderson iv., 351 a- .... , 310-320 Difhl B., 11, 178 34, 429 I*>- .... n. f. 370 Hanimerschlag B., 10, 1213 34, 76 Pentabromanthracene .... C 14 H.,Br 5 abt. 212 Tetrabromphenanthrene .... C w H 6 Br 4 183-185 Zetter B., 11, 171 34, 510 Tetrabromanthracene .... 238 Anderson 15, 44 vi., 178 .... H .... 354 Graebe and Lieber- As., 7, 257 manu Tetrabroruanthracene tetra- C 14 H 6 Br 4 .Br, C 14 H 6 Br 8 abt. 212 d. Hanimerschlag B., 10, 1213 34, 76 bromide Tribromphenanthrene .... C 14 H 7 Br 3 126 Limpricht B., 6, 533 26, 898 .... n 125-126 Zetter B., 11,171 34, 510 Tribromanthracene .... 169 Greebe and Lieber- As., 7, 279 vi., 178 mann a-Dibromphenanthrene .... C 14 H 8 Br 2 146-148 Zetter B., 11, 170 34, 510 0- .... n 158 y- .... 02 Limpricht B., 6, 533 26, 898 Di broman thraceue .... ,, 182 (?) Anderson vi., 178 .... .... Ktl Grsebe and Lieber- As., 7, 275 mann Isodibromanthracene .... _ .... 190-192 Miller A., 182, 366 31,86 Dibromsynanthrene .... 175 A., 191, 300 Dibromanthracene dibromide C,,H s Br 4 238 p. d. Anderson iv., 351 tetrabrom- .... C 14 H 8 Br 6 170-180 Grsebe and Lieber- As., 7, 277 ide mann .... 1) .... 182 Anderson A., 122, 304 vi., 178 Bromphenanthrene C l4 H 9 Br 63 Limpricht B., 6, 533 26, 897 C,H 4 .CH I CBr.C 6 H, a. 360 Solid (?) Anschutz B., 11, 1218 34, 984 i i Bromanthracene 100 Perkin C. N., 34, 145 31, 209 /3-Tolane dibromide Ph.CjBrj.Ph C 14 H lo Br 2 .... 64 Limpricht and B., 4, 379 24, 511 Schwanert 3- ,, JJ M 64 Jena I. D. vii., 1162 - , 11 200-205 Limpricht and A., 145, 348 ; B., vi., 1099 ; 24, Schwanert 4,379 511; vii., 1162 ,.- It H 207-208 Liebermann and B., 12, 1974 38, 259 Homeyer Diphenyldibromethyltm: .... CPh a :CBr. H a. 300 p. d. 83 Goldschmidt B., 6, 986 27, 151 COMPOUNDS CONTAINING THREE ELEMENTS. 1-20 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. ^ ' ' ' i J Watts' Diet. J. Gh. Soc. Phenanthreue dibrotnide .... .... C l4 H 10 Br 2 .... Solid Fittig and Oster- A., 166, 364 vii., 85 mayer .... 08 d. Limpricht B., 6, 533 26, 897 Diphenylbromethylene CPh 2 .CHBr C w H n Br a. 300 50 Hepp B., 7, 1411 28, 361 Bromstilbene .... 25 A., 145 340; 155 72 Diphenyltribromethane CHPh^CBr., PlAjETji .... 89 Goldschmidt B., 6, 985 27, 150 Bromstilbeuedibvomide .... 100 Limpricht and A., 145, 341 vi., 1107 Sehwanert Tribromdibenzyl .... .... n. f. 170 Stelling and Fittig A., 137, 268 v., 871 1 .... .... .... .... 207-211 .... A., 151, 365 Dibromdibenzyl C 6 H 4 Br(CH 2 ).,C 6 H 4 Br=(1.4) s C 14 H 13 Br 2 .... 114 Stelling and Fittig A., 137, 267 v., 871 j .... .... i> jy .... lllt-115 Leppert B., 9, 17 29, 704 Stilbeue dibromide Ph.CHBr.CHBr.Ph 230-235 Limpricht and A., 145, 336 vi., 1107 Sehwanert ,. ,, .... 233 Forst and Zinek6 B., 7, 1713 28, 454 ,, ,, .... 232 ) )3 1 fi ,, H .... 337 Zinck6 A., 198, 127 38, 115 j .... 237 jj Bromdibenzyl .... C 14 H 13 Br a. 320 s. 0. Stelling and Fittig A., 137, 266 v., 871 Tetrethyldibrombenzene C 6 Et 4 Br 2 =1.2.3.5.4.6 C 14 H 20 Br 2 330 74-5 Galle B., 16, 1744 44, 1092 ,, = (?) 110 n n ji Tetre thy Ibrombenzene C 6 HEt 4 .Br=1.2.3.5.6 284 Liquid j Tribromfluoranthene C,5H,Br a n. f. 345 Goldschmidt W. A., 81, 415 40, 283 Dibromfluoranthene C 15 H 8 Br 2 202 ?j )> ,, .... .... tt .... 204-205 Fittig and Gerhard A., 193, 146 36, 166 Dibrommethylantkracene .... C 15 H 10 Bl 2 156 Fischer B., 7, 1196 28, 155 .... From C 6 H 4 ' C 2 H 2 : C 6 II 3 Me > .... 148 Bornstein B., 15, 1822 44, 71 ) .... 138-140 Liebermann and B., 11, 1606 ; A., Seidler 212, 35 Dibromditolylm ethane CBr 2 (C 6 H 4 Me) 2 C 15 H 14 Br 2 115 Weiler B., 7, 1182 28, 151 Broni- ? C, H Br ? C H Br 112 4 J I fl , TJ. CT? cc I^P;^ 36, 940 ^IS- 1 " 1 -!!- 1 -" * ^is^o- 01 .... -rvcior iiiiii oritits . 1 I., ' . lOUd Dibromdimethylanthracene .... Ci 6 H 12 Br 2 .... 154 Van Dorp A., 169, 213 27, 63 Distyrene dibromide .... C 16Hl6 Br 2 102 Erdmann A., 216, 190 44,475 Dimethylstilbene dibromide.... C 2 H 2 Br 3 (C 6 H 4 Me) 2 .... 207-209 Goldschmidt& Hepp B., 6, 1505 27, 371 Cetyl bromide .... Ci 6 H 33 Br .... 15 Fridau A., 83, 15 i., 840 Dibromchrysene Ci 8 H 1() Br 2 .... 273 Schmidt J. p. C. [2] 9, 275 27, 988 Brom- 2 C 16 H 9 Br ? P TT Tlr 112 Ador ;unl Crafts C. R., 88, 1355 36, 940 Tetrabromretene 18 11 l C 19 H 14 Br 4 210 Ekstrand B., 9, 855 30, 514 ) 210-212 A., 185, 84 32, 497 Ditbromretene .... C 18 H 16 Br 2 .... 180 IT A., 185, 83 n Tribromdiphenylene phenyl- .... Ci 9 HnBr 3 .... 167-171 Behr B., 5, 971 methane Dibromdiphenylene phenyl- .... C 19 H 12 Br 2 .... 181-182 ) methane Triphonylbrommethane CBr.Ph 3 CisH^Br .... 152 Schwarz B., 14, 1520 40, 913 Isoamylbromanthracene C 6 H 4 : C 2 Br(C 5 H n ) : C fl H 4 C 19 H 19 Br 76 Liebermann and B., 14, 797 40, 736 Tobias . ) .... 76 Liebermann A., 212, 111 42,863 Dibrom-aa-dinaphthyl C 20 H 12 Br 2 215 Lessen A., 144, 80 vi., 855 Dibrom-j3-dinaphthylme- .... C 21 H 14 Br 2 164 Eichter B., 13, 1728 40, 282 thane Dibrom-a-dinaphthylme- CH 2 (C 10 H 6 Br) 2 (?) ) .... 193 Grabowski B., 7, 1608 thane Dibrompicene.... H Br oqo one -P B. 13 1837 .... < -'22 J:l 12 OI 2 _ . ' i ^ . - i riurg 1* B. 14 176 . ' f riyij vjrrtcDe and w alter Bromtriphenyl benzene .... C 24 H 17 Br 104 Engler & Berthold B., 7, 1125 28, 63 '(?) .... CoaHi 9 Br 3 273 Schmidt B., 6, 496 26, 1234 130 ORGANIC COMPOUNDS. (4.) CHI. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. lodofonn CHI 3 115-120 Weltzien iii., 311 119 Dafert M. C., 4, 496 44, 978 .... J) 119 Serullas A. C. [21 22, 72 120 Ger. Pharm., 1882 Methylene diiodide CH 2 I 2 2 Butlerow A., 107, 110 ; 109 iii., 1006 242 .... 181 p. d. 5 J., 11,420 .... 180 p. d. 4 Hofmann A., 115, 267 .... M 181 Sakuri 41, 362 .... M 151-153 c. .... Perkin 45, 464 (330) Methyl iodide Mel CH 3 I 41-8 .... Sigel A., 170, 345 40-50 Dumas and Peligot A. C. [2], 58, 30 437 ; 42-5 Haagen P. A., 131, 117 42-2 (752) .... Andrews J., 1,89 iii., 990 43-8 (750) Pierre C. R., 27, 213 n M 42-3 c. Perkin .... 45, 4E9 42-8 .... Jones .... 33, 182 ., 43-44 .... Lieben and Rossi A., 158, 107 24, 344 41-46 .... Linnemann A., 161, 178 vii., 215 ; 25, 395 B 43 Lieben and Paternc G. I., 2, 290 27, 357 Methyliodide hydrate 2MeI.H 2 O 4 .... C. R., 90, 1491 Acetylene diiodide CHI:CHL C 2 H 2 I 2 70 Berthelot B. S. [2], 2, 202 vi., 34 ,, Sublimes 73 SabanejefF A., 178, 118 29,57 ; , 190 Henry C. R., 98, 741 46, 831 , 192 c. 73 Plimpton B., 16, 79 41, 391 Diiodethylene CH 2 :ci 2 197 calcd. 41, 396 (0 .... .... s. b. SabanejefF A., 178, 118 29, 57 lodethylene (vinyliodide) ... CHi:CH 2 C 2 H 3 I 56 SemenofF C. R., 61, 646 vi., 34 ?J 56 .... Gustavson B., 7, 731 27, 1075 M 55-5-56 .... A. C. [5], 2, 397 27, 1153 . , 5J 56 Saban6jeff B. S. [2], 34, 323 40, 399 Acetylene hydriodide .... B 62 .... SemenofF C. R., 61, 646 vi., 34 Ethylidene diiodide CH 3 .CHI 2 C.,H 4 I 2 180 Liquid Berthelot B. S. [2], 2, 202 n 177-179 .... Gustavson B., 7, 731 27, 1075 178-179 .... A. C. [5], 12, 397 27, 1153 , n 180 Friedel B., 7, 823 B 179-180 Plimpton 41,397 Ethylene diiodide CH 2 I.OH 2 I )? .... 70 Kopp J. P., 33, 183 JT 73 Regnault A. C. [2], 59, 368 ,1 n d. Plimpton 41, 397 75 ii., 578 ^ 82 Romburgh R. T.. 1, 151 44, 303 ,, 82 Aronstein & Knimps B., 13, 489 38, 541 Ethyl iodide CH 3 .CH 2 I C 2 H 6 I 64-8 Gay Lussac A. C., 91, 91 . * Marchand J. F. P., 33, 188 " " 71-6-72-2 Frankland 2,263 ii., 534 79 7 1 ? Berthelot A., 115, 114 " " I I O Pierre C. R., 27, 213 ii., 534 " 7O C. R., 74, 224 25, 239 " " 1 V Andrews J., 1, 89 " / 1 (5 72'2 Jones 33, 181 " " 72 Saytzeff J. p. C. [2], 3, 88 24, 525 70-0 79>n p Perkin 45, 460 ) 5 i t tJ 1 jl V d " B 72 Thorpe .... 35, 544 70 Haagen P. A., 131, 117 " I O 79-9 " " t & M Linnemann A., 162, 39 vii., 203 " 51 * COMPOUNDS CONTAINING THREE ELEMENTS. 131 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethyl iodide CH 3 .CH 2 I 11 11 11 )) CI : C.CH 3 CHiC.CH 2 I H Compare B., 17, 1133 CI 2 :CI.CH 3 CHI : CI.CH 2 I CHI : CI.CH 3 C 3 H 4 .HI CH 2 : CH.CH 3 I )1 )> u 11 11 )j u >i CH^-CH^CHJ 11 C 3 H 4 .2HI CH 3 .CHI.CH, >1 >J 1 )) )1 11 > IJ n n i) )5 J) See Part III. CH 3 .CH 2 .CH 2 I )l )1 )> V V Jl 1> )1 u 11 C 2 H 6 I 1> U > 1) C 3 H 3 I 11 (?) ^aHjIj C 3 H 4 I 2 C 3 H 5 I 1) 11 U J< 11 )) 1> 1 11 CjHijLj 11 )> C 3 H 7 I I* > i ) )) ), ? j n > j > ) > 72-27 72 71 72-3 71 70-72 72 98 115 abt. 120 d. 198 82 93-103 101 100-103 70-71'5c.(330) 101 100-102(761) 89-92 97-100 101-102 101-5-102 102-5-102-8 abt. 227 d. 170 (170) 147-148 d. 90 (735) 89 89 93 72-91 88-89 89-90 (735) 88-7-89-5 c. 88-6-89-5 89-90 89-89-5 c. 92-94 89 93 88-6-89 u. c. 90-95 b. p. table 102 (752) 102-103 104-25-104-5 99-101 101 101-5 102-18 102-2 102-25 102-11 102-2 1O9 inj.-.^ Liquid Liquid 48-49 64 40-41 1. 10 Liquid Liimemann n Plimpton and Grave Gladstone and Tribe Sabanejeff Liebermann Henry Liebermann Henry Oppenheim Semenoff Oppenheim Berthelot& DeLuca Saytzell&Kanouikoi] Perkin Aronheim Romburgh Woieikoff Tollens Linnemann Zander Berthelot& De Luca Freund Semenoff Erlenmeyer j> Buff Schipper and Tak Linnemann j) Zander Siersch Perkin Simpson Gladstone & Tribe Wurtz Brown Friedel Rossi Chapman & Smith Pierre and Puchot Chancel Berthelot& DeLuca Linnemann n M M 7Tir]pr A., 148, 251 A., 162, 12 A., 144, 133 A., 160, 204 43, 123 B. S. [2], 34, 323 A., 135, 266 B., 17, 1132 B., 6, 729 B., 8, 399 A., 135, 216 B., 17, 1133 B. S. [2], 4, 434 B. S. [2], 5, 446 B. S. [2], 4, 434 J., 7, 452 B., 9, 1810 B., 7, 1382 R. T., 1, 151 J., 16, 495 A., 156, 156 As., 3, 264 As., 3, 267 A., 214, 145 A., 92, 311 M. C. [2], 640 ) B. S. [2], 5, 446 Z.C.P.[1861],362 A., 126, 309 A., 139, 229 As., 4, 149 Z. C. [2], 4, 520 A., 140, 178 As., 3, 265, 267 A., 161, 43 A., 214, 162 A., 144, 142 A., 129, 128 A., 136, 43 P. R. S., 26, 238 A., 124, 327 G. I., 1, 230 22, 198 G. R., 66, 302 C.R., 68, 656,726 J., 7, 452 A., 168, 251 A., 162, 39 A., 162, 3 A., 161, 43 ; A. 160, 195 A., 161, 18 A., 162, 12 A.. 214, 159 25, 477 vU., 223 30, 361 40, 399 vi., 97 46, 979 vii., 1008 26, 1123 vi., 98 vi., 96 ;j i., 142 45, 460 28, 246 44, 303 v., 893 42, 157 vi., 96 v., 891 vi., 965 25, 236 vii., 1015 45,461 vii., 1015 ; 26, 968 32, 837 4, 1032; vi., 963 vi., 963, 964 vi., 963, 964 vii., 203, 645 vii., 223, 1013 25, 236 25, 234 25, 477 ,, ,, .... . .. ,, ,, .. . .... lodallylene Propargyl iodide ,, lodallylene diiodide Propargyl triiodide Allylene diiodide hydriodide D Allyl iodide ,, ,, .... .... .... Diiodopropane 11 .... .... i .... .... Allylene dihydriodide Iso-propyl iodide ,. t) V 11 ) ,, ,, ,, .... .... t) 5, 1) ,j Jt >1 ,, >1 11 ,, >1 1 >1 Propyl iodide 132 ORGANIC COMPOUNDS. Name. Constitution. "" "" Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Propyl iodide CHa-CHyCH,,! (XH,I 101 Gladstone & Tribe 36, 969 vii., 1015 100-102 Schorlemmer P T [1872] 111 25, 1086 102-10275uc Brown P B S , 26 238 32, 837 100 Mazzara G I [1882] 333 42, 1199 101 Hiortdahl C. E., 88, 584 36, 519 102 103 c Perkin 45, 460 See Part III. b p table (?) -tetriodide Crotyl iodide Butylene diiodide Butbyl iodide CH^CH^CH^CHjI C 4 H 2 I< C 4 H 7 I C 4 H 8 I 3 C 4 H 9 I 131-133 115-120 129-6 (738-2) 127 74 Berend Lieben and Rossi A., 131, 122 M. G, 1, 837 A., 158, 137 C R 68 1561 vi., 34 24, 521 vii., 215; 24,520 vi., 372 129 "65 Linnemann A 161 178 vii., 215 216 129-95 c 25, 395 125-129 129-97 A, 161 196 25, 396 129-65 1^9-81 c A., 162 39 vii., 203 129'9 A., 162, 3 vii., 223 130-4-131-4 Briihl G. J. C., 1880 (745) 130 A and M Saytzeff J p C [2] 3 88 24, 230 525 121 Wurtz A., 93, 112 v., 736 Isobutyl iodide ;i > jt > jt > j n > w >, > ) i> > ? j ,, n it Me 2 CH.CH 2 I n ) j > j > n >j CH 3 CHICHI CH )J )J >I )) )) 1) ) J )J n )> n j M abt 118 120 (715) 121 120 122-5 122-5 120-63 120-57 115-125 120-6 c. 117-5-118 u.c. (715) 119-121 118-119 (734) 118-122 120 c. (760) 120-5 119-4-120-4 (745) 119-121 120-1Z1 c. 83-83-25(250) 119 ISO .... De Luynes Chapman & Smith Wurtz Pierre and Puchot Linnemann > Erlenmeyer & Hill Linnemann & Zotta Demole Brauner Dobbin Bruhl Demar9ay Perkin Lieben J. [1862], 476 G. J. C., 1863 22, 153 A. C. [4], 22, 317 C. E., 74, 224 A., 140, 195 A., 161, 178 A., 162, 12 A., 160, 257 A., 162, 3 A., 162, 7 A., 175, 142 A., 192, 69 G. J. C., 1880 C. E., 197, 360 J , 21, 439 n vi., 373 24, 526 24, 526 ; 25, 239 vii., 218 jj 26, 395 vii., 217 25, 242 25, 475 vii., 217 28, 561 34, 779 37, 236 26, 1227 45, 462 24, 525 ,, ,, .... .... ?> ,, .... .... j) M n (758-3) 115-125 116-120 mils .... Linnemann Saytzeff Kessel A., 161, 178 Z. C. [2], 6, 327 B , 7, 291 vii., 215 vii., 219 27, 677 116-5-118 A., 175, 44 28, 554 119 120 KannonikofT and A., 175, 374 28, 626 ,, .... .... ) 119-120 118-121 .... Saytzeff Wagner Bel and Greene B. S. [2], 25, 396 B. S. [2], 29, 306 30, 395 34, 773 118 121 34, 774 118-121 120 121 Wurtz Z. C. [21 5, 407 vi., 377 116-118 B. S. [2], 8, 265 vi., 376 CIMe, 98 99 p d Butlerow Z. C. [1867], 3G2 vi., 374 97 99 Linnemann A., 161, 178 vii., 215, 223 98-5 A., 162, 12 25, 395, 477 COMPOUNDS CONTAINING THREE ELEMENTS. 133 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Butyl iodide .... OIMe 3 (J.HJ 1 Markownikoff Z. C. [2], 6, 29 100-35 Puchot A. C. [5], 28, 507 46, 167 lodoisopropylacetylene Valerylene hydriodide Pr^.CiCI C 5 H 8 .HI CH 3 (CH 3 ) 8 .CH 2 I C 6 H 7 I C 5 H 9 I <-' 5 H u I 140 140-142 155-4 (739-8) Liquid Reboul Liebeii and Rossi J. R, 9, 225 C. R., 64, 284 G. I., 1,314; A., vi., 1123 vi., 1137 ; 24, )> CHMe 3 .CH 2 .CH 2 I )> 149 148-25 c. Liquid Grimm Perkin 159, 74 J. p. C., 62, 385 1034 vi., Ill 45, 462 > > j> > 148-2 147 (740) .... Kopp A., 95, 344 J. [1853 J, 37 vi., Ill 147-2-147-7 A. 146 Cahours A. C. [2], 70, 81 i., 205 146 Frankland J., 3, 478 146 Gladstone & Tribe 30, 361 26, 679 147 Haacen P. A., 131, 117 primary active 144-145 B. S., 25, 545 .... .... CH3.CH2.CH5.CHI.CH., ?> 146 (763) 147 .... Wurtz Romburgh J., 21, 446 R T., 1, 151 44, 303 143-146 Le Bel C. R, 73, 499 24, 1025 145 C. R, 75, 267 25, 886 144-145 Wagner & Saytzeff A., 179, 318 29, 548 j, CHMej.CHI.CH 3 137-139 137-139 .... Wischnegradsky & Flawitzky Wischnegradsky B., 10, 406 C. R, 86, 973 32, 420 34, 717 130 LeBel C. R., 75, 276 25, 886 130 (760) ; Wurtz C. R, 65, 1182 vi., 115 50-55 L v. 129 vi., 114 127-129 Butlerow B., 10, 407 32, 589 129-130 Flawitzky A., 179, 348 125-127 Ossipoff B., 8, 542 28, 877 125 Etard C. R, 86, 488 34, 393 (CH 3 .CH 2 ),.CHI 145-146 Wagner & Savt7eff A., 179, 317 29, 548 145 Kannonikotf an J A.,175,374;J.p.C. 28, 628 Jy " " " (?) (CHACI.CHj.CIL 144-146 128-129 .... Saytzeff Demareay Wischnegradskv & [2], 23, 465 C. R, 77, 360 B., 10, 405 ; J. R., 26, 1227 32,420 ,, .... .... .... )) 127-129 127-128 .... Flawitzky Wischnegradsky 9, 156 A., 190, 337 C. R, 86, 973 34, 394 34, 717 127-129 Winogradow A., 191, 131 34, 484 b. 125 Ossipoff B., 8, 1243 29, 545 115-120 B., 8, 542 28, 877 Triiodobenzene Diiodobenzene > n 5 )) 1? H ) lodobenzene > ) Dipropargyl tetriodide Diallyl tetriodide hydriodide .... 1.1.1=1.2.4 1.1=1.4 )> n jj 1.1=1.3 )l 1.1=1.2 1.1=1.2 (?) C 6 H 6 .I > CHirCI.tCH^.CKCHI CHjI.CHI^CH^j.CHI.CHJ C 8 H 3 I 3 C fi H 4 I 2 > ; j )> j C 6 H 6 I ) )) (?) C 6 H 6 I 4 C 6 H 10 I, C 6 H n I 250 277 ; 285 c. 284'7 (756.48) s. a. 1-4 & 1-3 185-190 185 188-2 c. 190 260 164-165 76 122 127 127 u. c. 729-4 40-4 36-5 Solid 94 b. 18 113 a. 100 Kekul6 Schiitzenberger Kekul6 Dumreicher Korner Rudolph Korner Schiitzenberger I^adenburg Kekulfi Paterno Scrugham Henry Wurtz A., 137, 165 C. R, 52, 963 ; R, 3, 145; 4, 268 A., 137, 164 B., 15, 1869 G. I., 4, 305 i) B., 11, 81 G. I., 4, 305 C. R, 52, 963 A., 159, 255 J., 19, 554 G. I. [2], 488 7,244 B., 14, 399 A., 100, 363 A. C. [4], 3, 129 vi., 267 vi., 267, 3C vi., 267 vii., 138 29, 239 29, 222 29, 233 vii., 138 vi., 267 26, 757 iv., 415 40, 5G5 vi., 93 134 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. lodohexy lene C 6 H n I 142-145 Bouchardat C. E., 74, 809 25, 410 130-132 Destrem B., 16, 229 ; A. C. Hexyl iodide CH,(CH 2 )..CH 9 I e,H.,i 181-4(746-8) Liebenand Janecek [5], 27, 5 A., 187, 138 32, 880 179-5 (752'u^ > Me2.CH.CH2.CH2.CH3l 179-5 172-175 Franchimont and Zincke Pelouze & Cahours B., 4, 822 ; A., 163, 196 C. R, 54, 1241 25,61;vii.,646 iii., 153 j CH 3 (CH 2 ) 3 CHI.CH 3 ? 168 167 j> Hecht )) A., 165, 147 ; B., iii., 154 165-170 Wurtz 11, 1422 A. C. [41 3, 129 vi., 700 * * T) 167-5 (752) 165 .... Wanklyn & Erleu- meyer J., 16, 518 J., 14, 732 V it CH3.CH2.CHj.CHI.CHj.CHj 5> 1> 125-75-126-5 c. (220) 102 (98) 164-166 Liquid Perkin Krafft Connick B., 9, 1086 C. E., 182, 92 45, 403 29, 694 J> > t> "" From fusel oil 154-160 u. c. 150 100 (70) Lieben and Zeisel M. C., 4, 44 A., 128, 228 A., 178, 18 44, 570 ,, Me 3 C.CHI.CH 3 MejCLCHj-CHj-CH,, )> 140-144 143 J. [1873], 339 A., 195, 254 139-140 A., 209, 84 Me s CI.CHMe, 140 s. 22 Pawlow B., 11, 513 34, 563 abt. 140 s. 3 Kaschirsky B., 11,984 36, 46 140-14%p.d. s. C. C. [1881], 278 42, 37 140-144 Liquid Friedel and Silva C. E., 76, 226 vii.,982;26,489 lodotoluene .... Me.I 1.4 C-H 7 I 211-5 35 Korner Z. C. [2], 5, 636 vi., 284 200-210 20 + Dreher and Otto A., 154, 171 vii., 1166 w Me.I=1.3 j Me.I=1.2 i> 204 205 204 Liquid Liquid Liquid Beilstein and Kuhl- berg u A., 158, 349 Z. C. [2], 3, 102 A., 158, 347 24, 682 vii., 1166 24, 683 Benzyl iodide MethylpropyLJlylene hydrio- dide Heptyl iodide 11 11 * 11 T 1) > * ,, , r .... f? ,, .... ,. , r .... t T J yj .... .... 1J 71 "' Tolylene diiodide Octyl iodide n .... .... 11 i> .. -.. .** , v I C 6 H 5 .CH 2 I Me(CH 2 ) 3 .Cl:CHMeor Me(CH 2 ).,.CH rCI.CHj.Me CH 3 (CH 2 ) 4 .CHjI Pr-vcm Prj.CHI Prf(CH,VCHI.CH, Prf.MeEtCI J> CMe 3 .CMe 2 I )) From CH 3 .(CH 2 ) 5 .CH 3 C,H 4 (CH 2 1), Me 2 CH.(CH 2 ) 4 .CH 2 I > J> C 7 H 13 I it ) C 7 H 15 I )> 11 > > C 8 H 8 I 8 C 3 H 17 I > > 205-205-5 ; 211 c. abt. 240 140-150 d. 201 (754-8} 196 190 192 185 180 p. d. 165-1 75 p. d. 170 145-147 145-147 142 d. 140-1 42 p.d. 98 (50) 220-222 221 218-222 192-194 c. (330) 24-1 Liquid Liquid Liquid 15 Liquid 170 p. d. Kekulo Lieben Morris Cross Wills Schorlemraer Petersen Kurtz Rohu Schorlemmer Kaschirsky i Butlerow Venable Grimaux Zincke Conrad & Bii?ch()fF Miislinger Perkin B., 7, 1007 Z. C. [2], 6, 736 41, 179 A., 189, 4 (i, 311 16, 219 A., 118, 74 J. [186.9], 514 A., 161, 205 A., 190, 313 16, 220 C. C. [1881], 278 B., 11, 985 C. C. [1881], 278 A., 177, 184 B., 13, 1C49 C. E., 70, 1363 ; A. C. [4], 26, 331 A., 152, 5 B., 13, 597 B., 9, 998 28, 64 vii., 179 32, 126 iii., 147 25, 411 ; vii., 1025 34, 486 iii., 14!) 42, 37 36, 46 42, 37 28, 1249 40, 82 vii., 1209; 25, 817 vi., ,H78 38, (!28 30, 393 45, 463 COMPOUNDS CONTAINING THREE ELEMENTS. 135 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Octyl iodide .... C 6 H 13 .CHI.CH, C S H..I 211 d. Bouis A. C. [3] 44, 131 iv., 171 210 J., 8, 526 vi., 880 206-207 Jalm B., 15, 1293 193 Squire 7, 108 iv.,17l- vl. 880 Secondary 120 i. v. Clermont B. S. [2], 12, 212 vi., 880 Propyl iodobenzene .... Pr.I=1.4 C 9 H U I 250 Liquid Louis B., 16, 110 Isopropyl iodobenzene Pr/s.I=1.4 234 Liquid B., 16, 114 /3-Iodonaphthalene C 10 H 7 I 54-5 Jacobsen B., 14, 803 40,736 o- .... JT a. 300 Liquid A., 147, 173 Isobutyl iodobenzene (CH 2 .CHMe 2 ).I=1.4 C^K,,! 255-256 c. Easily Pahl B., 17, 1232 46, 1009 Cajeputene hydriodide C 10 H 16 .HI + liH 2 C 10 H,.I .... 80 J. [1860], 483 Turpentine dihydriodide C 10 H 16 .2HI CioHisIj 48 Oppenheim A., 129, 149 v., 923 Diiododiphenyl C 6 H 4 I.C 6 H 4 I=(1.4) 2 C 12 H 8 Ij 202 Schmidt & Schultz B., 12, 486 36, 652 (?) Cis^I 143-145 (5) Cannizzaro & Amato B., 7, 1103 28, 163 Cetyl iodide C, C H,,I 22 Fridau A 83 9 i. 841 Myricyl iodide C 30 H 6lI .... 67 Maskelyne 22,87 vi., 391 .... 69-5 Pieverling A., 183, 347 31, 586 (5.) CHO Kornnc acid .. H.COOH CH 2 O 98 '5 Tjift MI o* ii., 687 1 100 Person J., 1, 91 100'5 Pettersson and B., 13, 1194 38, 869 Ekstrand lOl'l (758) Roscoe 15, 271 ii., 687 " 105'3 (760) J. [1847-8], 68 100-5 (749) 7-45 Pettersson J. p. T21, 24, 293 42, 3 and 4 101 c. S Perk in " r L J) J +*uu 45, 480 w 8'6 Berthelot C. R., 76, 1433 ; 26, 1099 ; 28, B. S. [2], 22, 440 749 99-8-100-3 Landolt P. A., 117, 353 2 Bannow G. J. C., 1876 99-8-105-4 Lossen A., 214, For tension tables " see Part III. Methylalcohol H.CH 2 .OH CH 4 60-66-5 .... iii., 988 64-8 Vincent and Dela- C. R., 90, 747 38, 525 chanal 65 .... Ostwald J. p. G, 27, 1 44, 575 65-2 Thorpe 35, 544 ,. a 66-66-5 Linnemann Z. C. [2], 4, 284 vi., 827 =67-1 c. 66-67 Lieben and Rossi A., 158, 107 24,344 66-68 Lieben and Paterno G. I., 3, 290 27, 357 ji 66-5 .... Dumas and Peligot A. C. [2], 58, 5 ,, 60 (744) Kane A., 19, 164 66-7 Regnault M. A. S., 26, 658 u 66-3 Pierre A. C. [3J 15, 325 ., 65-5 Kopp P. A., 1847 64-6-65-2(744, .... I! G. J. C., 1855 65-8 .... Andrews J., 1, 89 65-8-66 c. Perkin 45, 465 66-5 Person J., 1, 91 J) 60-5 Delffs J, 7, 26 58-6 Dupru P. A., 148, 236 n 66 Graham G. J. G, 1862 66 (753) Landolt G. J. G, 1864 65-6-66-2 Grodzki & Kramer G. J. G, 1876 (765) Acid from leaves of viscum C,H;0,.OH CH 4 O 4 .... 101-103 Pavlevsky B. S. [2], 34, 348 40, 441 album 136 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Glycollic anhydride CH 2 .O.CO i i C 2 H 2 2 128-130 Thomson and Falil- berg A., 200, 75 ; J. p., 7,335 38, 380 Gllycolide CH2.O.CO.CH 2 .O.CO (?) > 180 Fahlberg J. p. [2], 8, 329 vii., 570 ; 27, 180 Dessaignes A., 89, 342 143 ii., 919 j >' 180 Bo'ttinger B., 14, 729 40, 714 ) J MO Norton& Tcherniak C. R., 86, 1332 ; 34, 773 Oxalic acid COOH.COOH ) C H O^ 212 Richter B. S., 30, 102 Tabellen ^^2 2^^4 200^ 203 Camelley 33, 275 it )j .... .... J > V 186-187 Staub and Smith 45, 304 JT (crystallized) .... (COOH^+SHp abt. 98 iv., 250 >i ) 98-5 Tilden 45, 268 Ethylene oxide CH 2 .O.CH 2 C 2 H 4 13-5 Liquid Wurtz J., 16, 486 ii., 579 .... (C 2 H 4 0) n 56 5) C. R, 83, 1141 ; 31, 291 B., 10, 90 Acetic aldehyde CH 3 .COH C 2 H 4 20-8 (760) Liquid Kopp A., 1855 or 1856 i., 106 ,, ,, .... .... ) )> 21 Cazeneuve J. P. [5], 5, 494 42, 1003 ) 1> n 21-22 c. Perkin 46, 475 ,, .... -rt 21 .... Ramsay 35, 469 11 v * -l ^^ 21-8 Liebig A., 14, 132 ,, .. ji 22 (758-2) Liquid Pierre C. R, 27, 213 ; i., 106 P. A., 76, 458 V .... .... u 23-28 Guckelberger J., 1, 848 ) ,, H 19-8 (734) .... Kopp P. A, 72, - 11 >J " M ) 20-8 (759) Laudolt A., 131, 172 .... (C 2 H 4 0). 81 Liquid Liebig A, 14, 133; 36, 376 i., 109 .... .,.. .... 90 (0 CO 0) ,, Elaldehyde .... 1) ffl 94 94 Liquid + 2 Liebig Fehling A., 27, 319 vii., 32 i 10Q Isomer of aldehyde .... Vv 110 Bauer J., 13, 436 *, i\jy .... i) 280-285 J. [1878], 612 Metaldehyde & Paraldehyde see C 6 H 12 3 Methylic formate H.COOMe C 2 H 4 2 30-4 (712) Liquid Volhard A., 176, 135; 166, 28, 877 128 j M 32-33-5 c. .... Perkin .... 45, 490 n ,, > 5J 31-6-32-4 Kroemer & Grodzky B., 9, 1928 (764-8) ,, 1? ) 32 .... Bardy and Bordet A. C. [5], 16,561; 36, 520 C. R, 88, 183 ,, v H ) 32-3 .... Elsaaser A., 218, 302 44, 967 ) I " )> J 33 Ramsay 35, 469 > V 33-4 (760) Kopp P. A., 72 ,, ji )> 32-9 .... Andrews J., 1, 89 )) 36-38 Liebig .... ii., 695 ,, )> )> 32-3 .... Schiimanu G. J. C., 1881 Acetic acid CH 3 .COOH 5 113 .... Ramsay 35, 469 ,, M )J 1 114 .... Mitscherlich ;* )> )> 1 117-1 .... Pettersson and Ek- B., 13, 1194 38, 869 117 m l (740) I6-g5 strand Pettersson J. p. [2], 24, 293 4.2 *3 )) 16 Lowitz 4 - . O i., 10 B 16 Regnault J. [1863], 74 vii., 6 >J ) 117 (763) 16'45 Oudemans Z. C. [1866], 750 vi 7 j J) 118 16"5 Longuinine B., 6, 564 V A., I 26, 1101 )> J> 118 Landolt P. A., 117, 353 ) f 1) .... .... .... )> ) 5) 117-8 (760) 16-7 Rudorff B.,3,391;P.J.T., vii., 5; 24, 1094 17 .Baeyer [2], 2, 241 B., 10, 1287 34, 4 i ) 116 17 Delffs A. 92. 277 COMPOUNDS CONTAINING THREE ELEMENTS. 137 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. ^Acetic acid CH S .COOH CJLO, 118-1 c. Lhmemaim A 162 39 160 vii., 203 120 Dumas 195 120 Person J., 1, 91 116'9 119 Losseii A 214 154 120 Lw 24 284 38 515 22 '5 Mollerat A C [1] 68 88 L, 10 117-3 (760) KODD P. A, 72 119 Sebille- Auger 118-5; Pawlewski B., 16, 2633 46, 252 321-5 c. t. 118 118'5 c Perkin 45, 481 .... (hydrate) Methylene oxide CH 2 .O.O.CH 2 > H 1 18-118-8 c. 104 s. a. 152 152 Butlerow A., Ill, 242; 120, 1., 11 iii., 1007 Glycollic acid ,, ,, .... .... ,, ,, .... .... * Methyl oxide CH 2 (OH).COOH )) )) * CH,.O.CH, C 3 H 4 3 H }) CJLO begins 100 20 78-79 78-79 76-77 80 Schulze Drechsel Thomson Fahlberg 295 Z.C.P.[1862],606 A., 127, 150 G. J. C., 1879 J. p. [2], 7, 329 ii., 910 vii., 569 ; 7, 143 iii., 990 21 ii., 537 23'65 M A S 26 658 c 30 (760) Tellier A. C. [5], iii , 502 28, 488 c (2'5 ats ) c 30 (6"5ata ) Ethyl alcohol .... .... CH 3 .CH 2 OH 76 P. A., 12 93 77-9 Andrews J., 1, 89 L, 72 77 77-5 J., 21, 413 78'5 Perkin 45, 465 78 35, 469 78-21 Pictet P. M. [51 1, 477 31, 163 78-4 (760) Gay-Lussac i., 73 78'4 (760) Kopp A., 72, 1 78'8 A., 55, 166 26, 1082 78-1-79 Darling 78-3 (760) M. A. S., 26, 658 78-4 Berthelot 35, 544 78-3 Pierre A. C. [3], 15, 325 78 A., 162, 374 79 Pierre and Puchot A. C. [4], 22, 260 78'4 C. E., 90, 747 38, 524 78-4 chanal J., 1, 91 78'53 (760) A., 160, 195 vii., 203 78'25 Delffs J., 7, 26 78'3 78'307 Mendeljeff J., 18, 469 (760) 80'6 P. T. [1847], 249 81 J., 1, 682 78'05 (760) Main G. J. C., 1877 t 1 -V)-") C. K., 96 1225 ; 44, 781 Me n O Olzewski P. J. T. [1884], 814 B., 7, 699; J. Ethylene glycol > ,, ,, ,, )) CH.,OH.CH S OH I) J) C 2 H S 3 H )> i> 193 194 c. 195 197-197-5 196-199 c. Liquid Kriechbaumer Atkinson Zeller and Hufiier Eamsay Wurtz Perkin [1863], 70 P. M. [4], 16, 437 J. p. [2], 10,270 35, 469 A. C. [3], 55, 410 28,442 ii., 575 45, 504 133 ORGANIC COMPOUNDS. Name. Constitution. formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Propargylic acid Mesoxalic acid (see C 3 H 4 O 6 ) CH I C.COOH CO(COOH) 2 CH 3 :cH.CH:o C 3 H 2 3 (C 3 H 2 2 ). C 3 H 2 6 C 3 H 4 140-145 50 6 145 108 Bandrowski >j Bottinger Briihl B., 15, 2701 B., 12, 2215 A. 203, 138 A 200 139 44, 314 38, 160 40, 415 38 296 52 1 45 52-4 Hiibner & Geutlier A 114 35 i., 56 ]Vtetacrolein see CnHio O. Allylene oxide Propargyl alcohol j, ,, Acrylic acid .... * *Ji CHj.C : CH.O 1 1 CH:C.CH 3 OH 11 )> CH 2 :CH.COOH ! > JJ )) 5) C,H 4 O 2 62-63 62-63 114-115 114-115 110-115(762; Liquid Liquid Liquid Carstanjen Berthelot Brulil Henry j J. p. [2], 4, 419 A. C. [4], 23, 212 A., 200, 139 B., 6, 728 B., 5, 569 vii., 50 25, 143 38, 296 vii., 1007 ; 26, 1123 25, 807 i ^7 140-150 s 15 Caspary and Tollens B 5 560 vii 27 * 25 s 7 A 163 95 814 vii 27 25 689 Paracrylic acid ,, jy (?) Pyroracemic acid (pyruvic) i > Malonic acid .... CH 3 .CO.COOH ) JJ COOH.CH 2 COOH (C 3 H 4 2 ) ) C 3 H 4 3 )> )> C\H 4 O 4 155-165 abt. 165 p.d. 165-170 68-69 180-182 96 Liquid Liquid 102 Klimenko Krestowiiikoff Roser Claisen & Shadwell Volckel Wichelhaus Grimaux & Tcher- B. S. [2], 34, 321 B., 10, 410 B., 15, 293 B., 11, 621 J., 6, 426 G. J. C., 1867 B S [2] 31 338 40, 414 32, 442 34, 568 iv., 770 36 783 131 '5 132 niak Jackson and Hill B 11 291 34 402 132 Bischoff B., 15 1110 42, 1188 132 Petrieff B 7 401 27 787 132 Heintzel A., 139 132 29 65 134 B 14 1185 40 800 abt 138 Pinner B., 8, 965 29, 65 139 140 B 11 1714 36 220 140 Dessaines A., 107 251 Hi., 799 Tartronic acid ,, )i ,j -, ,, 1 " fl . 5, .... .... ,, ., ) )J )J "* " (hydrate) .... Mesoxalic acid (see C 3 H 2 O 6 ) j, Propylene oxide ., ,. ,, ,, CH(OH)(COOH) 2 >' 5 )> J >J > C^H.O^H.O C(HO) 2 (COOH) 2 1 CH 2 .O.CHMe ?J CH 2 .CH 2 .O.CH n L | C 3 H 4 5 )) )1 5> J J) C 3 H 4 6 C 3 H 6 )) > s. 110-120 35 35 36 abt. 50 145-147 150-151 155 160 d. abt. 160 170 175 179-185 182 d. 183 185-187 d. 96 115 Liquid Liquid Grimaux Demole Gruber Campani & Bizzarri Brunner Text books Compani & Bizzarri Conrad and Bischoff Bottinger Conrad and Bischoff Eichter Petrieff Deichsel Oser LeBel Belohouljek Reboul B., 10, 903 B., 10, 1789 B., 12, 516 G. L, 10, 489 B., 12, 547 B., 14, 729 G. L, 12, 1 B., 13, 600 B., 14, 729 A., 209, 222 Tabellen B., 7, 404 J. [1864], 640 B. S. [I860], 237 C. E., 92, 532 B., 12, 1872 A. C. [5], 14, 4!)5 34, 34 v., 698 40, 256 40, 714 42, 818 38, 629 40, 714 42, 39 27, 787 vi., 824 vii., 1021 40, 1021 38, 232 36, 133 ,, ), Propionic aldehyde ,, i) ,, ,, ,, -n v CHj.CHj.COH T > (C 3 H 6 0) n C 3 H 6 N > ) > > 160-170 40-45 (740) 46 47-47 '5 48 46-49-5 48-77 c. Liquid T Rossi Pierre and Puchot Berthelot Briihl Lossen Linnemann G. I., i., 230 Z. C., 13, 255 ; A. C. [4], 22, 298 C. R., 83, 413 A., 200, 139 A., 214, 154 A., 161, 20 >i 24, 10.30 vi., 962 30, 474 38, 296 25, 234 COMPOUNDS CONTAINING THREE ELEMENTS. 139 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Propionic aldehyde .... CH 3 .CF 2 .COH C 3 H,0 47-49 c. Perkin 45,476 H 49-5 (740) Rossi C. R, 70, 129 ; vi., 962 A., 159, 79 54-63 Michaelson A., 133, 182 iv., 734 55-65 Guckelberger A., 64, 39 Dimethylketone (acetone) ... CH 3 .CO.CH 3 55-6 Liebig P. A., 72 vi., 767 a 53-3-56-6 Grodzki & Kramer Z. C., 14, 103 n 56-3-56-53 Zander A., 214, 172 55-6-55-9 c. Perkin .... 45,478 57-58 Schrohe, B., 8, 368 57 u. c. Spring B., 14, 759 54-56 .... Pinner B., 14, 1072 ?, 56 1. 15 Dumas i., 26 ) t) u 56 .... Deichmuller A., 209, 22 40, 1162 V ,, 55-56 .... Freund J., 13, 313 >p 56-3 (763) .... Regnault 37, 212 56-3 (763) .... Kopp P. A., 72 31 33 56-53 c. (760 Thorpe .... ,, 56-58 Jahn B., 13, 2110, 211 11 33 56-57 B., 13, 2114 33 56-58 .... Japp and Streatfielc 41, 271 31 33 56-58-5 .... Linnemann A., 161, 59 25, 238 )1 33 56-59 .... 35 33 jj 56-57 A., 143, 349 V 1) 58 .... Cazeneuve J. P. [5], 5, 494 42, 1003 11 33 * u 55-60 Popoff Z. C. [2], 7, 4 24, 126 13 232-8 c. t. .... Sajotschewsky W. B. [1879], 74 45, 139 Propylal /o\ fifi I ji 111) iru'li t & Uslar 24, 386 \*/ w .. Allyl alcohol .... CH 2 : CH.CH.,OH 8889 Linnemann B., 7, 854 27, 1157 )> .... 90-92 s. 54 Tollens & Henniger A., 156, 134 vi., 91 92-95 Hiibner and IVtulle A., 159, 174 M 93-96 Xollens \Veber ant A., 156, 132 U Kempf 33 31 96-4-97-4 Zander A., 214, 172 96'8 c. Perkin 45, 536 " 96-97 Tollens A. 158, 104 viL, 47 ; 24, 340 31 *1 96-97 Henry B., 5, 569 25, 807 33 11 ** 96-97 _A.ron h eim B., 7, 1381 28, 246 96 "5 Briihl A., 200, 139 38, 296 11 96-6 c. (766) Thorpe 37, 210 3) 92-94 Erlenmever J., 17, 489 " " 96'5-96'8 Buff B., 4, 647 24, 905 " 97 Hartlev 39, 154 33 90-100 Hofmann i., 140 " " 103 LIQ uid Jl 31 31 103 3ofinann & Cahouvs J., 9, 583 vi., 91 hydrate C 3 H 6 0+H,0 88-89 I Aronheim B., 7, 1381 28, 246 (?) .... 13 166-168 .... Heintz A., 169, 114 27, 146 Ethylic formate H.COOEt C 3 H 6 2 52-9 (752) Liquid Pierre C. R., 27, 213 P. A., 76, 458 53-4 .... Liebig 3) 53 .... Delffs J., 7, 26 n 54 Liquid Marchand ii., 693 T) 54-4 (760) Schumann G. J. C., 1881 33 3 54-4 .... Elsasser A., 218, 302 44, 967 55-5 .... Lbwig J., 14, 599 54-3 (762) .... Andrews J., 1, 89 ii., 693 54-9 (760) Kopp P. A., 72 55 .... Ramsay 35, 469 ,, 54-57 .... Claisen & Matthews 41, 266 56 Dobereiner P. A., 72 ii., 693 ,, 54-2 c. Perkin 45, 490 J5-7; 238-6 c.t. .... Pawlewski B., 15, 2463 44, 276 T 2 140 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. \ Reference. Watts' Diet. & J. Ch. Soc. Ethylic formate H.COOEt C 3 H 6 2 230 c.t. .... Sajotschewsky W. B. [1879], 741 46, 138 Methylic acetate CH 3 .COOMe 56-2 Lowig A., 96 56-58 Grodski & Kramer Z. G, 14, 103 ?) 55 (762) Liquid Andrews 1,27 i., 23 j? 56-3 (760) Liquid Kopp A., 55, 181 57-5 Elsasser A., 218, 302 44, 967 56-56-5 c. ; .... Perkin .... 48, 493 57-5 c. 58 .... Dumas and Peligot P. A., 36, 117 59-5 Pierre and Puchot C. R, 27, 213 ; P. A., 76, 458 M 58 .... Cahours G. J. C., 1863 ., 57-5 (760) Schumann G. J. G, 1881 229-8 c.t. .... Sajotschewsky W. B. [1879], 741 45, 138 .... 57-l;239-8c.t. .... Pawlewski B., 15, 2463 44, 276 Acetyl carbinol CH 3 .CO.CH 2 OH ,, a. 100 .... Emmerling and A., 204, 27 38, 868 Wagner Propionic acid CH 3 .CH 2 COOH 1. -21 Baeyer B., 10, 1286 34,4 ,, 57 (25) .... Claisen and Moritz 37, 694 139 .... Freuud J. F. P. [2], 5, 446 vii., 1010 W 140 s. o. t. Dumas iv., 731 140 .... M ilaguti & Leblanc J., 1, 551 B 140-66 Linnemann A., 162, 39 vii., 203 u 140-71 c. (760) !. 21 A., 148, 251; 1GO, vii., 1010 195 N 141-6 .... Vincent B. S. [2], 31, 156 36,612 J> 141-5(760) .... Pierre and Puchot A. C. [4], 28, 71 vii., 1010 146-6 (760) .... .. C. R, 75, 250 26,44 ,, 141-142 c. ; Perkin .... 48, 481 141-3 c. 142 Limpricht & Uslar J., 8, 508 ., f 141-6 (760) Kopp A. , j, .... 1 ,, 140 Landolt P. A., 117,353 139 Linnemann J., 21, 433 M 140-1-141-6 .... Lessen A., 214 (755-756) 11 11 n 138-5 ; .... Pawlewski B., 16, 2633 46, 252 339-9 c.t. B For table of .... Kahlbaum B., 16, 2476 46, 141 b. p.'s. at different pressures, *<* seePartlll Glycide (epihydrin alcohol) OT.0$CH 2 OH 157 (760) .... Hanriot C. R., 88, 387 36, 44!) 157-160 d. A. C. [5], 17,112 36, 1032 I! 161-163 Liquid Gegerfelt B. S. [2], 23, 160 28, 879 >t pi 160 Breslauer J. p. [2], 20, 192 38, 29 Bergamot camphor Lactic acid C 2 H 4 (OH)(COOH) (C 3 H 6 2 ). C 3 H 6 O 3 .... 206 b. 24 Mulder A., 31, 70 i., 581 iii., 45(i Dimethyl carbonate .... CO(OMe) 2 .90-6 c. OT) Rose A., 205, 231 40, 25:2 n 91 (730) Schreinev J. p. [2], 22, 357 40, 88 ,, H 92-97 Councler B., 13, 1697 40, 251 Metliylglycollic acid CH(OMe).COOH 198 Heintz J., 12, 359 178 .... Schreiuer B., 12, 179 Methylic glycollate CH 2 (OH).COOMe ,, 151-2 .... B., 12, 179 ; A., 36, 522 197, 6, 21 Glyceric aldehyde CH 2 (OH).CH(OH).COH ,, 130-135 71-72 Runard C. R, 82, 502 30, 04; 42,1308 t| 92 C. R., 81, 188 28, 1250 Trioxymethylene HO.CH.CH(OH).CHOH r 155 Bartoli & Papnsngli G. I., 13, 287 46, 170 H .... 152; Tollens B., 16, 919 a.s.171 172 COMPOUNDS CONTAINING THREE ELEMENTS. 141 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Methylethyloxide CH 3 .O.C 3 H 6 C 3 H 8 11 Williamson J., 4, 511 ii-, 537 >i > 11 11 Wurtz J., 9, 563 Tsopropyl alcohol CH 3 .CH(OH) CH 3 11 80-82 Linnemann W. A., 63, 255 vii., 982 11 11 .... 11 11 81-85 .... 5) B., 10, 1111 32, 729 )* 1J J1 11 82-85 c. (760) )1 A., 161, 26 vii., 1015 11 1 "" .... 11 11 82-85 c. (725) 11 A., 161, 43 25, 236 J> ?1 11 ) 83-84 (739) b. 20 n A., 136, 37 v., 889 11 >! H )1 82 Liquid Begnault & Hardy J. P. [4], 30, 405 38, 456 V >1 ) 11 82-5-83-5 c. .... Perkin .... 46, 467 11 11 "* i) ) 82-81 .... Lessen A., 214, 154 11 11 " > H 83-84 Schepper and Tak Z. C. [2], 4, 124 vL, 965 1 >1 *" > 11 11 11 H 83-85 85 .... Siersch Weidel and Gruber A., 144, 141 B., 10, 1137 32, 780 11 hydrate iw 11 85. .... Rabateau C. K., 87, 501 36, 36 11 11 >i .... (C 3 H 8 0) 2 .H 2 80 Linnemann A., 136, 40 11 " (C 3 H 8 0) 3 .2H 3 78-80 i n i> >i i) (C 3 H 8 O) 3 .H 2 O 81 Propyl alcohol CH 3 .CH 2 .CH 2 OH 3 H S O 84-91 ji A., 148, 251 vi., 963 11 92-96 Schorlemmer A., 150, 159 vi., 957 11 11 .... D )J 96 >? P. E. S., 17, 372 vi., 963 ,, ,, 11 95-96' .... Etard C. R., 86, 488 34, 393 ,, ji 11 96-97 Chancel C. R., 37, 410 v., 889 M 11 1 96 (743)'. Rossi C. R, 70, 129 ; vi., 963; 24, G. I., 1, 230; 1031 1 A., 159, 79 j, IV 1 96 (758) t Saytzeff J. p. [2], 3, 76 ; 24, 229 i Z. C., 13, 107 ,, j, .... N 11 96 ..... Gladstone & Tribe 39, 4 3 , 11 11 9T .... 1 ! : 1 1 ill f f ; M l , C. R., 87, 501 36.36 ,, 11- IV 97 Bruhl A., 200, 139 38, 296 , .... 11- J1 96-98 .... Lessen A., 214, 153 , 11 1 97-3 (700); .... Brown > P. R. S., 26, 238 32, 838 79-3 (370) ; j 56-0 (120) 1 11 11 97-41 .... L!nneiuaim A., .161, 26 ; A., vii., 203, 1013 ; 162, 39 26, 235 ,- ' ,, ;> 11 95-100 .... Fitz B., 13, 36, 1311 38, 372 11 > * 11 11 97-98 Chapman & Smith 7,198 vi., 963 , " 11 11 98 a Perkin : 46, 466 11 1 11 11 97 Bertoni and Truffi G. L, 14, 23 46, 1110 ,, .... ) 11- 96-100 Kramerand Pinner B., 3, 77 11 11 H M 97-98 .... Schorlemmer .... 27, 1030 11 11 11 Ji- 98-5 Pierre and Puchot C. R, 66, 302 30, 4; vi., 963 ,, 11 ll 97-100 Chancel C. R., 68, 659 vi., 963 )1 j> 11 11 97-101 JV A., 151, 302 hydrate Methylal C 3 H 8 O+H 2 O CH,(OMe) 2 C,H S O.,- 87-5 (738) 43 (761) Liquid 11- jVfjilao'uti C. R., 68 A. C. [2], 70, 390 vi., 963 iii., 994 v 'j i - M -8 v ^2 43(236-6 c.t.) Pjiwlewski B. 16 2633 Aft .>-.-) Propylene glycol 11 CH 3 .CH(OH).CH 2 (OH) JJ 185-186 Jeltekow B., 6, 558 ^W, _!_ 26, 1016 ?i 11 1> ;> 187 c. Belohoubek B., 12, 1873 38, 232 ? ?i 11 185-2-188-5 Zander A., 214, 154 ,, M >J 188-189 Wurtz J., 10, 464 v., 892 ,, ,, i ) 188 Han riot C. R., 86, 1139 34, 656 11 11 J) 188 LeBel C. R, 89, 312 36, 1031 ,, .... .. . 11 189 Loobisch and Looss M. C., 2, 789 42,377 11 11 * 11 ?) 185-3 Flawitzky B., 11, 1256 Trimethylene glycol CH 2 (OH).CH 2 .OH 2 (OH) )J 208-218 Liquid Geromont A., 158, 369; B., vii., 49, 1021 ; 4, 548 24, 698 i 11 11 Viscid 30 Niederist M. G, 3, 838 44, 450 11 I? 11 i 215-216 c. .... Reboul A. C. [5], 14, 491 36, 133 11 11 J1 )l 216 .... C. R., 79, 169 42, 156 142 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority! Reference. ^J?'^ & J. Ch. Soc. Trimethyleue glycol !) Glycerol CH,(OH).CH a .CH s (OH) CH 2 (OH).CH(OH).CH 2 (OH) J) 1) C 3 H 4 (OH) 4 (C 4 H 2 2 )"0 CO.CH:CH.CO.O 1 1 C 3 H 8 2 )I C 3 H 8 3 I) 5) )) 5) i) )) M C 3 H S O, C 4 H 2 3 )) 5> V C 4 H 2 4 )J C,H 4 C 4 H 4 Q, )J )) 1 ) I> C 4 H 4 3 J) ) > C 4 H 4 4 C 4 H 4 6 C,H 4 7 C,H 6 )> )) )) C 4 H 6 2 216-217 S16-816-5 c. (736) 179-5 (12-5); 210 (50) 290-08 c. (756-55) 290-290-5 c. 275-280 280 d. 290 c. (759-7) a. 150 176 192-198 196 202 c. 201-202 (o.d.) 82 (14) 80 (11-12) 32 197-205 SOSc. 260-280 d. 250 abt. 1GO 61-62 67 103-104 102-106 104-105 105 103-105 82-8^' 20 17 15-4 7-2 15-5 57 Crystalline 57 53 53-54 175 d. 100 135 Liquid 76 76 76 76-5 76-5 94-6 189 118 119 119-6 120 160 a. w.m.a.300 s. w. m. 200 abt. 130 (129 ?) 110 Liquid Liquid Liquid Reboul Freund Nitsche Solas Henuinger Armstrong Oppenheim & Salz- mann Perkin Kekulc Strecker Mendeljeft' Gladstone Hamel Boos Carius Pelouze Perkin Kekul6 Anschutz Bandrowski >) Arnaudon Limpricht Lagermark Kahlbauui Pinner Friedrich Geuther Friedrich Demar^ay Anschiitz )* Kraut Urech Goldschmidt Duisberg Buchner Conrad Tanatar Henry Henniger Newbury Perkin Kekule Newbury Kekule Tollens, Weber and Kempf C. R., 78, 1773 M. C., 2, 636 G. J. C., 1873 24,84 G. J. C., 1875 G. J. C., 1876 B., 17, 1623 Lehrbuch, 2, 125 Lehrbuch, 448 A., 114, 165 20, 384 A., 134, 71 A. C. [2], 56, 72 B., 14, 2548 As., 2, 87 B., 12, 2281 B., 14, 2791 ) B., 15, 641 B., 15, 2694 B., 10, 838 J. [1858], 264 A., 165, 282 B., 12, 854 B., 12, 2338 B., 14, 1081 B., 15, 218 J. p. [2], 3, 431 A., 219, 322 B. S. [2], 33, 516 B., 10, 1884 B., 10, 326 A., 137, 254 G. J. C., 1880 M. C., 3, 136 B., 15, 1384 A. A., 49, 57 B., 12, 752, 1237 B., 13, 1384 B., 5, 274; B., 5,455 C. R., 98, 149 C. R., 92, 196 43, 89 A., 162, 92, 309 A. C. J., 5, 112 %. C. [2], 5, 572 Z. C. [1866], 518; J., 21, 450 27, 977 42, 156 vii., 563 28, 442 46, 507 vi., 638 29, 651 v., 893 ii., 746 39, 562 iii., 788 44, 313 32, 592 v., 655 26, 624; vii., 1032 36, 782 42, 945 vii., 399; 24, 816 44, 968 38, 626 34, 136 v., 462 42, 602 iii., 784 36, 707 38, 875 vii., 1008 ; 25, 687 46, 897 40, 406 25, 616 46, 295 vi., 513 vi., 621 , Propyl phycite Fumaric anhydride Maleie anhydride > .... )> )! Acetylene dicarboxylic acid (hydrate) Taiguic acid ) )> > COOH.C-C.COOH C 4 H 2 O 4 +2H 2 O CH S .C1C.COOH or CH1C.CHj.COOH > n ) )* CMe-C.COOH OO.CHJ.CH2.CO.O t i Tetraphenol .. Tetrolic acid Succinie anhydride i) !) >! ,, .... V Oxytetrolic acid Fumaric acid .... )9 M ) CH(COOH) 3 COOH.C(OH) 2 .CO.COOH CH 3 .O.C 3 H 3 CH 3 .CH : CH.CHO > ) CH 2 : CH.CH 2 .CHO H.COO(CH 2 .CH : CH 2 ) Maleie acid Formyl tricarbonic acid Trioxymaleic acid Methyl propargyl oxide Dihydrofurfurane u-Crotonic aldehyde - "- ,. - i) - Allylic formate COMPOUNDS CONTAINING THREE ELEMENTS. 143 Name, Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Erythrol anhydride O.CH;,CH.CH.CH 2 .O C 4 H,0 2 138 Liquid Przybytek B., 17, 1092 46, 979 1*11 i Butyrolactone CH 2 .CH 2 .CH 2 .C.O JJ 201-203 Saytzeff A., 171, 266 27, 570 ), M )> 201-203 18 Fittig A., 208,111 42,33 i> ) 203 (753-8) M. C., 3, 702 jj > J) 206 c. Saytzeff J. p. [2], 25, 64 42,497 Trimethylene carboxylic acid CH 2 .CH 2 .CH.COOH H 188-190 Liquid Perkin B., 17, 54 46, 832 1 1 0-Crotonic acid (quartenylic CH 2 : CH-CH^COOH i 171-9 c. 1. 15 Geuther J.Z.,6; J. F.P. 24, 814 ; vil., or isocrotonic acid) [2], 3, 442 ;J. p. 399 ; vi., 509 [2], 3, 431 > J) 172 1. -15 Stacewicz Z. C. [2], 5, 321 vi., 509 i > ) 170-173 Hemilian G. J. C., 1874 i 5) j 172 .... Kramer & Grodsky B., 11, 1359 )1 1J > ij 170 .... Hell & Mullliauser B., 13, 480 Methacrylic acid CH 2 :CMe.COOH )i .... 1.0 Frankland& Duppa 18, 133 vi., 510, 825 ,, j 160-5 Kopp G. J. C., 1879 i 11 T .... 1. 10 Balbiano G. I., 8, 371 36, 616 j )) J) .... 16 Briihl A., 200, 139 38, 296 ,) .... 11 160-5 16 c. Prehn B., 8, 20 28, 632 i )) 11 160-5 16 Fittig A., 187, 42 32, 736 ,, )1 1) 180-181 18-19 Fittig and Eoeder B., 16, 2592 46, 295 o-Grotoiiic acid CH 3 .CH : CH.COOH I .... 70 Perkin 43,89 j, jj .... J) .... 70-5-71-5, Balbiano G. I., 8, 90 34, 658 jj )> .... 71 Lagermarck and B., 10, 639 32,583 Eltekoff , ,, i )) M .... 71-72 Rhine and Tollens Z. C. [2], 7, 251 vu., 49 ; 25, 1021 )) i) 180-181 71-72 Kekule B., 3, 606 vii., 396 u j) P n 182; 184-7 c. 71-72 11 A., 162, 112, 315 25, 618 j 1 j> 189 c. 71-72 >i B., 3, 606 vii., 396 j) ,, T) j> 182 72 >' B., 3, 609 11 ;, )> 72 Perkin 43, 89 45, 536 \* )t 1> )> 187-4 c. 71-5 Geuther J. p. [2], 3, 431 24, 815 i) jj i .... 72 Will and Koruer A., 105, 12 vii., 396 u i) 183-8; 187 c. 72 Bulk A., 139, 62 vi., 510; vii., 396 i> 1) i) 181-182 c. 71-72 Wislicenus A., 149, 214 vii., 396 )j ) 72 Sarnow B., 5, 468 25, 689 j .... .... ) )> .... 72 Hemilian R, 7, 297 27, 682 ) i) i 72 Hell and Lauber B., 7, 560 27, 887 v j) )> ) .... 72 Briihl B., 14, 2797 Methylic acrylate 1 CH 2 : CH.COOMe C 4 H 6 0,, 80-85 .... .... A., 167, 247 ,) ,j B I) 80-3 Weger A., 221, 61 46, 11 jj .... (C 4 H 6 2 ). 190 (100) Liquid Kahlbaum B., 13, 2348 40, 250 Acetic anhydride (CH 3 .CO) 2 C 4 H 6 3 130-135 Thorpe 37, 187 ,, i) )> ! 137-138 Cahoura G. J. G, 1873 Jl 136-138 .... Gall and Etard C. R, 82, 457 29, 899 ,, ,, ) ) 137 Boughton J., 18, 300 11 -,-, .... .... ) J) 137 .... Gal C. R., 56, 360 vi., 23 11 J) J 137-8 (757) Kopp A., 96 j> 1 JJ 137-5(750) Liquid Gerhardt J, 5, 451 i., 20 Methylic pyroracemate (pyru- CH 3 .CO.COOMe 134-137 .... Oppenheim B., 5, 1051 26, 377 ; vii., vate) 1034 Propionyl formic acid CH 3 .CH. 2 .CO.COOH jj 74-78 (25) 1. 15 Claisen and Moritz B., 13, 2121 7, 694; 40, 154 Acetyl acetic acid CH 3 .CO.CH 2 .COOH )J d. b. 100 Liquid Ceresole B., 15, 1327, 1873 Oxypropylene carboxylic O.CHMe.CH.COOH ) i 84 Melikoff B., 16, 1268 44,969 acid i i Hydroxytetrolic acid ... ) .... 111 Demarjay B. S. [2], 33, 575 40, 256 Epicyanhydrin carboxylic O.CH 2 :CH.CH,,COOH )1 225 Pazschke J. p. [2], 1, 100 vii., 466 acid 1 ' Dimethylic oxalate COOMe.COOMe C 4 H 6 4 161 51 Dumas and Peligot A. C. [2], 58, 44 iv., 272 114 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Dimethylic oxalate COOMe.COOMe C 4 H 6 4 163*5 .... Kopp A., 32, 49; 64, 313 .... 1> 164'2 (760) 50-51 Regnault M. A. S., 26, 658 * * 1) 163-5 Delffs G. J. C., 1854 * )? ,, 163-3 Weger A., 221, 61 46, 11 Ethylic oxalate COOH.COOEt T* 117(15) Liquid AnschUtz B., 16, 2413 46, 296 Ethylene glycol diformin .... CH2(O.CHO).CH 2 (O.CHO) ) 174 Liquid Henninger B., 7, 263; B. S., 22, 104 Isosuccinic acid CH3.CH(COOH), 130 Wichelhaus Z. C. [2], 3, 247 vi., 1041 n ... ) T' 130 Zublin B., 12, 1112 Succinic acid . . COGH.CH 2 .CH 2 .COOH 170-180 Wichelhaus Z. C. [2], 3, 247 vi., 1041 ^ i ?' 235 d. 180 v., 455 180 Bischoff B., 15, 1110 42, 1188 v * 180 Harrow 33, 435 ,, t , .... ... 'W -) .... 180 Brunner and Bran- B., 9, 983 30,400 denburg ,, T , .... .... .... T 1 180 Baeyer B., 10, 1286 34, 4 abt. 180 Coppola G. I., 10, 9 38, 382 ,, r, .... .... .... w 1 1 J> 180 Purdie 39, 351 180 Schmidt G. J. C., 1860 >? T "- " ' >J ?J 235 180-5 Carius G. J. C., 1867 180 Urech G. J. G, 1880 Glycollic anhydride (HO.CH 2 .CO) 2 O C 4 H 6 5 128-130 Fahlberg A., 127, 154 ; J. p. vii., 570; 27, [2], 7, 336 143 Malic acid COOH.CH(OH).CH i ,.CO 100 Tanatar B., 13, 159 38, 375 (inactive). TT 7 105-108 Pictet B., 14, 2648 42, 389 r r> v> " y? 112-115 .... A., 82, 330; 117, 126 rr r * " T) >T .... 133 .... A., 130, 24; 174, 368 T r T? 1> 130-135 Bischoff A., 214, 44 44,45 >? <* " _ 132-136 Lloyd A., 192, 80 34, 785 Isomalic aeiiJ .... .... .... COOH.CMe(OH).COOH > 149 Kanimerer A., 139, 257 vi., 759 d. 160 begins 100 Schmoger J. p. [2], 14, 77 30, 507 n .... .... .... jj )* T1 140 J. p. [2], 24, 38 42, 40 Diglycollic acidl COOH.CH 2 .O.CH 2 .COOH ji 250-270 148 Wurtz ii., 913 ) jj .... .... ?) 250 p. d. 148 Heintz A., 128, 129 vi., 641 Methyltartronieaekl CHs(OH).CH(COOH). or > .... 178 d. Bottinger B., 14, 148 40, 254 CH 3 .C(OH)(COOH) 2 " (2) acid i) 155-108 A., 216, 276 Tartaric acid (dextrorotary) COOH(CH.OH) 2 .COOH C 4 H 6 B 135 Schiff G. J. C., 1860 Mesotartaric acid > 140 Dessaignes B. S., 1, 34 v., 688 Tartaric acid 1 70-180 v., 675 Racemic acid .. . t 198 Staedel B., 11, 1752 36, 223 201 JJ Ethylvinyl oxide CH ? :cH.aEt C 4 H 8 .35-5 Liquid Wislicenus A., 192, 106 34, 776 Methylallyl oxide ... ...., CH 3 .O.CH 2 .CH : CH. 46 Liquid Henry B., 5, 455 vii., 50 ; 25, 687 Isobutylene oxide Me.C.CHa-O V 51-52 Liquid Eltekoff J. E. [1884], 355 44, 567 Butylene oxide MeCH.CHMe.O i i 56-57 Liquid >* B., 16, 398 Grotyl alcohol J 117-120 .... M. C., 1, 826 Ethyl-vinyl alcohol .... )* 99 (738) Lieben B. S., 12, 282 32, 868 Methylethylketone CHj.CO.CjH, V 77-80 .... Saytzetf Z. C. [2], 7, 104 vii., 11, 711 T> Jl 75-77 .... Fittig A., 110, 18 i., 31 JJ ) 75-80 Linnemann A., 162, 1 25, 474 ; vii., 219 fj V 77-5-78 .... Freund J., 13, 312 11 )) 77-79 .... Grimm A., 157, 258 24, 386 ,, .... .... ) t 79-82 Ceresole B., 15, 1874 COMPOUNDS CONTAINING THREE ELEMENTS. 145 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylethylketone CH 3 .CO.C 2 H 6 C 4 H 8 79-5-81 Popoff J., 20, 399 44, 990 .... n M 80 .... Kanonikoff and A., 175, 374 28, 627 Saytzeff n J) 80 .... Wagner, B. S. [2], 25, 396 30, 395 V )) 79-81 Demole B., 11, 1710 36, 220 J> " " I) 81 .... Frankland &Duppa J., 18, 309 vi., 767 > 80-85 Kramer & Grodzki B., 9, 1920 32, 291 Isobutyric aldehyde CHMe,,OHO JI 60-62 c. Liquid Linnemann & Zotta A., 162, 36 25, 475; vil., 228 J) ?) 62 .... Pierre and'Puchot A. C. [4], 22, 332; Z..C., 13, 255 ) 61 ..... Pfeiffer B. 5, 699 vii., 228; 26, 1001 V )> 60-64 Lessen A., 214, 154 ) 61-62 .... Barbaglia B., 5, 1052 26, 379 )> )> 60-62 Perkin .... 43, 91 ) ) 63-64 c. .... jt .... 45, 476 )j 1) 60-62 Renard A. C. [6], 1, 223 46, 844 M 63 (741) .... Fossek M. C. [4], 660 46,37 ., ) M 62 .... Urech B., 12, 1744 )> ) 65-70 .... Tilden B., 13, 1604 )) (C 4 H 3 0). 145-155 Liquid Pfeiffer B., 5, 700 vii., 228; 25, 1001 Butyric aldehyde CH 3 .CH 2 .CH 2 .CHO. C 4 H 8 68-75 Liquid Guckelberger A., 64, 52 i., 690 ) 73-74 Michaelson A., 133, 184 vi., 380 M " 5) ) 70-78 !> A., 133, 182 )> ) 73-77 Pierre and Puchot C. R, 70, 434 > abt. 75 .... Lieben and Eossi A., 158, 148 24, 517; vii., 214 Butyral .... 95 (75 ?) Liquid Chancel A. C. [3], 12,416 i., 689 Isopropylic formate H.COO c.fiA 65-67 (44-7) Silva B. S. [2], 17, 97 vii., 1016 ; 26, 367 Propylic formate H.COO.Pr )> 82 .... Chancel C. R, 68 vi., 964 ) n j> 81 Schumann G J. C., 1881 )j 82-5-83 Pierre and Puchot C. E., 66, 302; vi., 964 A.C. [4], 22, 28S ,, n 83-7 !> V C. E., 75, 1594 ; 26, 260 Z. C., 12, 660 ,, ,, 5) ! 81 Elsasser-- A., 218, 302 44, 967 ) )> 80-5-81-5 c. Perkin 45, 491 T) I) 85-1; Pawlewski. B., 15, 2463 44,276 267-4 c. t. Etliylic acetate CH 3 .COOEt )> 72-74 .... Zeidler A., 187, 30 32,437 )) )1 73 .... Pierre and Puchot A. C. [4], 22, 261 ; 26, 260 C. R, 75, 1594 j, .... JT u 74-3 (760) .... Kopp P. A., 72 i., 21 i, ,, 5> )> 76 Liquid , Perkin,and Hodg- 37, 487 kinson )J 77 Linnemann A.,160,209;162,39 vii., 203 jj ? 1) J 71 .... Thenard P. A., 72 j> ) 74 Dumas and Boullay P. A., 12, 430 j jj .... .... )J 74-14 .... Pierre C. R, 27, 213; P. A., 76, 458 it B )J 74-6 Andrews J., 1, 89 j ji . .... j )> 77-1 .... Elsasser A., 218, 302 44,967 ,, )> J) 77-5 .... Becker J., 5, 563 i j) J) 77'5 C. Perkin 45, 492 ,, ,, )> 83 Gossmann J., 5, 563 ,, )> 78-78-5 Marsson J., 6, 501 ,, > 74 (756) Delffs J., 7, 26 i )) 74 .... Leblanc A. C. [3], 10, 198 n j> )i > 77-1 (760) .... Schumann W., 12 146 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylic acetate CHj.COOEt C 4 H 8 S 74-3 .... Schiff G. J. C., 1881 75; 256-5 c.t. Pawlewski B., 15, 2463 44,276 239-8 c. t. Sajotschewsky W. B. [1879], 741 45, 138 Methylic propionate CH 3 .CH 2 .COOMe B 77-81 .... M. C., 2, 681 79-5 .... Kahlbaum B., 12, 344 36, 521 79-9 Schumann .... 44,990 79-9 .... Elsasser A., 218, 302 44, 967 80; 262-7 c.t. .... Pawlewski B., 15, 2463 44, 276 Isobutyric acid CHMej-COOH 153-154 c. ; .... Perkin .... 45, 487 153-153-5 c. 68 (45) .... Moritz .... 39, 14 149-151 u. c. Griiuzweig A., 162, 193 vii., 226; (716) 26, 374 151-153 .... Balbiano G. I., 8, 371 36, 615 153-2 .... Briihl A., 200, 180 38, 296 153-5-154-5 ... Markownikoff A., 138, 361 vi., 378 ,, 150-158 Hodgkinson 33, 500 .... .. 152-157 .... n .... 33, 498 150-160 .... .... 33, 501 153-155 Eenard A. C. [6], 1, 223 46, 844 154-11 c. Linnemann & Zotta A., 162, 9 vii., 226; 25, 475 > " 154-155 .... Hell & Waldbauer B., 10, 448 32, 313 155-5 (760) .... Pierre and Puchot A. C. [4], 28, 366; 26,55,616; C. R, 75, 1006 vii., 226 156 .... Delffs A., 92, 277 vii., 226 ,, 157 (760) b. 20 Kopp P. A., 72 i., 692 155-160 .... Kachler A., 159, 281 24, 1049 n 155-160 Lou- A. C. [5], 18, 125 38, 31 60'5 Gottlieb J. p. [2], 12, 1 29, 562 Butyric acid .... CH CH OH OOOTT 157-160 (716 Griinzweig A., 162, 203 26 '}7*}- 1711 99ft v>J_L 3 .V/iX 2 .V>J_Lg.VyV/Vf J.J. )> MM MWpOJO, VIA., ^2O ,, .... Liquid Eeichardt A. P. [3], 10, 339 32, 518 W 161-163 c. .... Perkin .... 45, 483 * " 100 (82-84) Moritz .... 39, 17 162'32 s. f. ni. Linnemann & Zotta A., 161, 175 25, 402 ; vii., 203, 225 ,, 162-82 c. Linnemann A., 160, 228 )) 162-63 5) A. C. [4], 27, 268 )> .... .... )) 163 Pierre C. E., 27, 213; P. A., 76, 458 162 .... Landolt P. A., 117, 353 ,, 163 (742) .... Eossi G. I., 1, 230 24, 1032 163'2 (749) Liebin and Eossi A., 158, 137 24,516; vii. 214 162-164 .... Cabours& Demarcay C. E., 90, 156 38, 540 156-163 .... Lessen A., 214, 154 )i 163-164 .... Vincent B. S. [2], 31, 156 36, 612 Pelouze and Gelis P. A., 59, 625 vi. 378 )> D .... w 161-5-162-5 .... Briihl A., 203, 19 . abt. 164 Pierre and Puchot A. C. [4], 28, 363 26 616 ** " 164 Person J., 1, 91 " IR^ 12 Bulk J > A., 139, 66 n " i\jij 165 Cahours&Demarcay C. E., 89, 331 36, 1036 A Baeyer B., 10, 1286 34 4 " 204"5-206"5 \J Lossen A., 214, 154 *^i) * For tension table " See Part III. Acraldehyde >.* " 110 Wurtz and Bauer E.C.p.[1860], 244 ii., 575 110 Lion id Bauer E.C. p. [1868], 294 vi., 76 Aldol CH 3 .CH(OH).CH 2 .CHO 51 90-105 (20) Viscid Wurtz C. E., 74, 1165 vii., 38 )j 90 (20) ; 135 C. E., 74, 1361; 25, 808 (760) d. 92, 1438 CO H O 1 170(15); 280 LiQiiid C. E., 97, 1525 46, f)7i) ***" \ < - / 4 xl 8 u 2/ w (760) Paraldol See C 8 H 16 O 4 " '] V COMPOUNDS CONTAINING THREE ELEMENTS. 147 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. CHMelOjICHMe C.H 8 Oo Sublimes Infusible Kekule and Zincke A., 162, 141 vii., 32 Dioxethylene .... (_/2 0.4 . C^-Og li^ ^^-a 3 102 Cryst. 9 Wurtz J., 15, 423 ii., 580 Ethylene ethylidene oxide ... C 2 H 4 O.C 2 H 4 O 11 82-5 Liquid 11 A,, 120, 328 i Butinglycol .... .... ... C 4 H 6 (OH) 2 199-200 Liquid Henniger B., 5, 1059 ; 6, 71 Methylic ethylic carbonate ... CO(OMe)(OEt) C,H S 3 104 (730) Schreiner J. p. [2], 22, 354 40,88 )! )) 11 )) 109-2 c. .... Rose A., 205, 245 40, 252 Ethylic methylic CO(OEt)(OMe) ) 115-5 (730-1) Schreiner J. p. [2], 22, 355 40, 88 Methylic methylglycollate ... CH 2 (OMe).COOMe JJ 127 Folsing B. 17, 486 46, 897 )> 3J 132-5 .... Schreiner B., 12, 179 36, 522 >i 11 J 134-5 .... 11 J. p. [2], 22, 353 40,88 Ethylic glycollate CH 2 (OH).COOEt )) 150 .... Fahlberg J. p. [2], 7, 340 vii., 570; 27, 143 1) 160 .... Schreiner B., 12,179; A., 197, 36, 522 12 Ethyl glycollic acid .... CH 2 .(OEt).COOH ) 199 it 11 !> 11 11 11 )) 1) abt 200 Liquid Heintz P. A., 109, 489 ii., 916 11 11 11 )J ) 206-207 .... Henry B. 2, 276 Methylic lactate CH 3 .CH(OH)COOMe 144-8 Schreiner B.,12,179;A.,197 36, 522 M 12 11 11 11 H 212 75-7 Frankland & Duppa P. R.S. iv., 275 11 ii 11 H .... 78 Tiemann and Fried- R, 14, 1973 42,56 lander 11 11 )J 3) .... 76-77 Pinner B., 15, 591 42, 942 11 !! ) .... , 78-79 Meyer B., 11, 1789 11 11 J > .... 79 Willgerodt B., 15, 2309 11 11 1) )J sb. 74 79 Markownikoff A., 146, 339 vi., 29 11 11 )) J1 b. 50 79 11 A., 153, 228 vii., 884 11 11 1) j .... 79-3 c. Balbiano G. I., 8, 371 36, 615 11 11 n ) sb. b. 100 80 Markownikoff A., 138, 361 vi., 379 11 11 .... 80 Hell & Waldbauer B., 10, 448 32,313 11 11 ) ) 80 Kaschirski C. C. [1881], 278 42, 37 Methoxyacetoxymethane .... CH 2 (OMe)(OAc) ) 117-118 .... Friedel C. R, 84, 247; B., 32, 424 10, 492 Ethylene mouacetate HO.CH 2 .CH 2 .OAc )) 181-182 Atkinson P.M. [4], 16, 433; ii., 566 A., 109, 232 Dambonite .... .... )) sb. 200-210 190 Girard C. R, 77, 820 vi., 541 205 C. R, 77, 995 27, 170 Glycerin monoformin .... C 4 H 8 4 165 i. v. 11 B. S., 11, 395 Die thy 1 oxide ... Et 2 O C,H,nO 20 (433) Brown 39, 209 j) ^^4 Ifl 11 1. 50 Thenard B., 10, 830 32, 425 ,, j 11 .... 1.-99 Mitschell 11 !> ,, .... 11 .... 1. 99 Franchiniont 11 11 ,, .... 11 34-5 .... Ramsay 35, 469 55 11 34-5 Regnault M. A. S., 26, 658 > jj .... .... I) 11 34 .... Dumas and Boullay A. C. [2], 36, 294 ii., 537 11 .... s. 31 Fourcroy ami Van- .... 32, 425 quelin 34'8 (760) Main G. J. C., 1877 1} 35'6 (760) 31 Gay-Lussac ii., 539 )) 11 35 Pictet P. M. [5], 1, 477 31, 163 )J 11 35'5 Naumann B., 7, 206 27, 563 1) 11 34-9 KOT>D P. A., 72 )? 11 3Jt97 (760) rr Regnault G. J. C., 1862 )J 1) u*f vi \i \rwj u 2 148 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diethyl oxide.. Et Q C 4 H 10 O 35'5 Pierre C. R., 27, 213; 34'9 Andrews P. A., 76, 458 J., 1, 89 35-6 Person J., 1, 91 35 Delffs J., 7, 26 34'6 c. Perkin 45, 474 117-4 Olzewski M. C., 5, 127 46, 816 190 c. t. Sajotschewsky W. B. [1879], 741 45 138 195-5 c. t. Ramsay (?) (hydrate) Methylpropyl oxide Butyl alcohol Et 2 O+2H 2 O CH 3 .CH 2 .CH 2 .O.CH 3 CH 3 .CH .CH 2 .CH 2 OH n i 49-52 122 s. 3-5 Tanret Chancel Wislicenus C. R., 86, 765 A., 151, 305 A., 219, 307 34, 565 vi., 964 44, 967 116-117 Fitz B., 9, 1350 117-5-120; Lieben and Ziesel W. A., 82, 960 40 710 96 (50) 116-96 c. I 22 Linnemann A., 161, 190 25 396- vii. 215 116-88 116-88 A., 162, 39 vil., 203 114-116 viscid 17 A., 161, 178 25, 395 110 Liquid Wurtz C. R., 35, 210 v., 733 109 A., 93, 107 115-117-2 Lessen A., 214, 154 116 Liquid Pagliani G. I., 8, 1 34 654 115-116 (758) Saytzeff Z. C., 13, 108 116 (740) Lieben and Hossi A., 158, 137 24 519 ,, Isobutyl alcohol > > > >* (inactive) .... > ) It T> , - n * *- different samples rt > > n > jt .... .... n it > >, > it if Butyl 11 >i >' H > CHMeyCHjOH J > > )> |t J> *> 1> H M H t > > i> > > w ) CH a .CH 2 .CH(OH).CH, i> > > > )j n n T )) J V Jl )) (?) ) N vi ) 1 ) ) M )> n N 113-117 115 108-5 109 109 109 108-109 107-109 108-109 108-39 107 108-109 108-109 108 108 108 108 107-109 107-5 107-5 106-109 108 107 107-6-108-3C. 105-110 106-107 105-110 106-9 106-107 103-105 99 99 99 (739) 98-100 98-5-99 .... I) )! Chapman & Smith Lieben and Rossi Rabateau Regnault & Hardy Gladstone & Tribe Lessen Linnemann > Cahours Etard Hofmann & Reimer Reimer Schorlemmer Munch Demarcay Pierre and Puchot i> Krsemer Schmidt Bertoni and Trufli Perkin Linnemann & Zotta 11 11 Fittig Rabateau Griinzweig Erlenmeyer & Hill Lieben and Bauer Lieben and Rossi Lieben Kanonnikoff and Saytzeff Nevolo > C. R, 68, 1561 22, 153 A., 158, 137 C. R, 87, 501 J. P. [4], 30, 405 39, 6 A., 214, 154 A. C. [4], 27, 268 A., 140, 195 A., 162, 12 C. R., 77, 1403 C. R, 86, 488 B., 3, 756 Z. C. [2], 7, 26 A., 180, 327 C. R., 77, 360 J., 21, 434 )) B., 7, 252 B., 7, 1362 G. I., 14, 23 A., 162, 3 A., 162, 7 B., 10, 515 C. R., 87, 501 A., 162, 193 A., 160, 257 (?) A., 158, 137 A., 150, 114 A., 175, 374 C. R, 85, 514 vii., 215 vi., 372 vi., 373 24, 523 36, 36 38, 456 vii., 217 26, 476 27, 348 34, 393 vii., 222 24, 121 27, 1030 30, 68 26, 1227 46, 1110 45, 468 25, 475; vii., 217 25, 475 32, 429 36, 36 26, 374 25, 242 vi., 374 24, 523 28, 626 32, 868 COMPOUNDS CONTAINING THREE ELEMENTS. 149 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Butyl alcohol CH a .CH 2 .CH(OH).CH 3 C 4 H 10 97-100 .... Saytzeff Z.C.,6, 327 ;J. p. vii., 219 ; 84, [2], 3, 88 526 96-99 Ressel A., 175, 44 28, 554 J5 JJ > n 96-99 Wagner B. S. [2], 25, 396 30, 395 JJ )J i 96-98 Schorlemmer 27, 1030 vii., 868 ,, i> n 95-98 De Luynes A., 128, 330; 132, v., 734 ; vi., 274 ; A. C. [4], 374 2,424 ) JJ H abt. 95 Wurtz Z. C. [2], 5, 407 vi., 377 JJ JJ CMe 3 OH n 82-85 Solid Freund J. p. [2], 12, 25 29, 543 Ji J> i) 81-85 2 Linnemann A., 162, 12 25, 477 ; vii., 222 V JJ JJ i 82-94 c. 23-24 JJ 11 J 80-85 4 n JJ 25, 476 ) 80-5-S3 s. 16 JJ 25, 477 JJ JJ ) b. 82 15 D JJ 25, 476 J> 83 (760) .... Pawlewski B., 15, 3034 44, 565 J > 83 .... Longuinine B. S. [2], 36, 307 42, 356 JJ JJ .... ... n ) 81-5-82 o. .... Perkin .... 45, 468 >j J j > 82-5-83 (745 29 Briihl A., 203, 17 Jt JJ )j 11 82 Solid Butlerow A., 144, 1 vi., 374 > 82-5 (750} 25-25-5 Z. C. [2], 7, 273 ; vii., 221; 24, A., 162, 229 1035; 26, 369 ,, V .... 82-5 25-25-5 Dobbin 37, 238 >J JJ i) vi 82-S2-5 25-5 j> JJ JJ j) > 82 Lieben and Rossi A., 158, 137 24, 523 hydrate .... CMe 3 OH+H 2 O ) 80 Butlerow Z. C., 14, 273 Ethylidene dimethylate CH 3 .CH(OMe) 2 C 4 H U 0, 65 Liquid Wurtz A. C. [3], 48, 374 vi., 4 (dimethyl acetal) j >j > 64-4 i... Alsberg J. Z,, 1, 154 j jj )) M 63-2-64-8 .... Kramer & Grodzki B., 9, 1930 (760) jj jj jj > jj 63-64 Dancer 17, 222 iii., 1002 J5 JJ JJ ) i 65 Bachmann A, 218, 38 44,727 JJ J ) >J 64 c. Perkin .... 45, 506 Ethylidene ethylate CH 3 .CH(OH)(OEt) 88-90 .... Renard A.C. [5], 16,289; 38, 24 ; 28, C. R, 80, 105 440 ,, )J a. b. 50 .... Jacobsen B., 4, 215 vii., 481 Ethylene ethylate OEt.CH 2 .CH 2 .OH > abt. 130 Liquid Wurtz A., 108, 84 ii., 574 j M 134u.c.(721-5) D A. C. [3], 55, 430 ; B., 9, 745 Isobutylene glycol Me 2 C(OH).CH 2 OH n 176-178 Nevol6 C. R.,83, 65, 146 30, 621 jj jj ?) 176-178 Eltekoff J. R. [1882], 355 44, 567 > 178-5 Henniiiger C. R., 95, 94 42, 1249 Butylene glycol C 4 H 8 (OH) 2 183-184 Wurtz A. C. [3], 56, 412 v., 739 jj j, Me.CH(OH).CH(OH)Me ) 183-187 Eltekoff J. R. [1882], 355 44, 567 CH 3 .CHj.CH(OH).CH 2 OH n 192-193 .... Nevolo C. R, 85, 514 32,868 )> 191-192 (747) Grabowski and A., 179, 332 n Saytzeff >? j CH 3 .CH(OH).CH 2 .CH 3 OH ) 201-203 Wurtz C. R., 76, 1165 26, 877; vii., 39 )> u 203-5-204 Kekule A., 162, 3'0; vii., 36, 225 ; B., 5, 56 25, 397 ,, ,, n j> 207-208 (769) .... Wurtz C. R, 97, 473 46, 169 Trimethylic orthoformate .... CH(COMe) 3 C 4 H 10 3 101-102 .... Deutsch B., 12, 117 36, 453 )j n JJ 102 .... Pinner B., 16, 1645 44, 1089 Butenyl glycerol C 4 H 7 (OH) 3 J 172-173 p. d. Liquid (?) M. C., 1, 833 11. c. (27) Diethylene glycol CH 2 OH.CH 2 .O.CH 2 .CH 2 OH jj abt. 245 Liquid Louren^o B. S., 1, 77 ii., 577 j> jj abt. 250 Wurtz A. C. [3], 67, 279 ji J jj 250 .... Demole A., 177, 45 28, 1172 150 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Erytkrite CH 2 .(OH).CH(OH).CH(OH). CH 3 OH JJ JJ C 4 H 3 O.CHO jj > jj jj M C 4 H 2 (OH)(COOH) C 4 H 3 O.COOH Me.C : CH.CO.O.CO | | c 4 H 10 o 4 CAA(I) C 5 H 4 (C 6 H 4 0). C 6 H 4 2 J 1} 5) JJ JJ J C 6 H 4 3 )J )J JJ Jl ) IJ JJ JJ JJ JJ JJ JJ JJ JJ JJ JJ JJ JJ C 6 H 4 4 JJ C 5 H 6 C 6 H 8 2 JJ JJ JJ (CJW C 6 H 6 3 JJ JJ JJ JJ C 5 H 6 4 jj 160 130 162 162 162 162 161-6 162-8-163-3 168 160-180 171-172 sb. b. 100 227-228 225 sb. b. 100 212 d. 122 (43) 213-214 c. 212 210-215 139-140 (30) 210 63-63-5 117-119 121-123 124-125 abt. 170-180 230 244-9 244-9 c. a. 300 282-285 p. d. 112 120 80 98 Liquid Liquid 120-125 121-5 Crystalline 129 130 130 133 132-6-134-3 c. abt. 82 7 Liquid 68 68 68-5 57 154 163 164 Liquid Liquid 175-176 206 Liquid Liquid 56-57 57 abt. 70 Larny Hesse Couerbe Kolbe and Schmitt Piamsay Cahours Hill Fownes Stenhouse Volckel Ihl6e Oat Hirzel Boussingault Stenhouse Schwanert Limpricht Fittig Anschiitz Markownikoff Morris Anschiitz and Petri Anschiitz Markownikoff Conrad & Guthzeit Meilly Beer Meilly Atterberg Bandrowski Briihl Henry Limpricht Bolas and Francis Roser Lebedeef Markownikoff Markownikoff Beer Swarts A. C. [3], 35, 138 A, 117, 327 A., 119, 169 A., 134, 61 35, 469 J., 1,733 B., 10, 937 A. C. J., 3, 33 P. T. [1845], 253 A., 156, 197 P. M. [3], 18, 122, 37, 226 J., 5, 652 A., 74, 284 A., 188, 31 J. p. [2], 19, 181 G. J. C., 1866 G. J. C., 1835 P. R S., 20, 80 ; C. N., 24, 303 V A., 116, 257 A., 165, 298 A., 187, 42 B., 14, 2788 B., 13, 1542 A., 188, 64 B., 13, 1845 37, 12 B., 13, 1540 B., 13, 1542 B., 13, 1845 B., 17, 1185 B., 6, 242 A., 216, 91 A., 171, 153 B., 13, 879 B., 15, 2701 A., 200, 139 B., 6, 729 A., 165, 253 22, 417 B., 15, 293 A., 66, 77 B. S. [2], 25, 395 A., 182, 329 B. S. [2], 28, 349 A, 216, 85 J. [1867], 474 ii., 504 iv.,324; vi.,505 32,747 42, 296 11., 752 ii., 752 iv., 761 34, 34 36, 708 iv., 763 vii., 535, 1033; 25, 298 jj vii., 535 ; 2o, 298 vii., 1032 ; 26, 626 32, 736 42, 829 40, 155 40, 35 40, 155 46, 992 vii., 22 ; 26, 875 44, 458 27, 788 38, 663 44, 314 38, 296 vii., 1008 ; 26, 1123 26, 626 vi., 391 30, 287 31,61 iv., 774 34,30 44, 458 vi., 760 Xanthil Paeonin Polyfurfurol Furfurol jj .... .... .... Fucusol Pyromeconic acid )> !) )> ,, .... /3-Pyromucic acid 0- 0- - ,, - ,, Isopyromucic acid Citraconic anhydride jj j? jj j* j "- Itaconic Trimethylene dicarboxylic anhydride Aconic acid .... JJ JJ JJ JJ CH 3 :C.CO.O.CO.CH 2 JJ /CH.OX CH/ | V> X CH.CCK CO.O.CH : C.CH 2 .COOH 1 1 M C 4 H 3 O.Me " CH i C.COOEt CH i C.CHj.OAc jj Me.CH.CO.O.CO.CH, 1 i Sylvane Ethylic propargylate Propargylic acetate Furfuryl alcohol (?) acid Pyrotartaric anhydride j) u n jj jj Paraconic acid ,5 v !) CH 2 .CH 2 .CO.O.CO.CH 2 CO.O.C 3 H 5 .COOH COMPOUNDS CONTAINING THREE ELEMENTS. 151 Nam , Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Citraconic acid Me.C(COOH) : CH.COOH C 5 H 6 4 80 Gottlieb G. J. C., 1852 1., 992 .... 80 Morawski J. p. [2], 11, 430 28, 1253 .... 88-89 Barbaglia B., 7, 466 Crotaconic acid C,H 4 (COOH)., .... abt. 119 Claus B., 10, 822 32, 593 .... 119 A., 191, 74 34,856 Glutonicacid COOH.CH 2 .CH : CH.COOH .... 133 Conrad & Guthzeit B., 15, 2843 44,312 (?) CH 2 :C 2 H 2 (COOH) 2 ? .... 139 Fittig and Boeder B., 16, 372 44,730 Trimethylene dicarboxylic CH 2 .CH 2 .C(COOH) 2 .... 140-141 Perkin B., 17, 54 46, 832 acid CHj.CH(COOH).CH(COOH 137 Conrad & Guthzeit R, 17, 1185 46,992 Not b. T AP fi 1 CO ill. 704 n . * -. Uv, 1 'I.J 140-145 150 Wirz A lft"i 9'W T) -fl., IV/tJ, _'( n Itaconic acid .... 161 111., 435 161-162 A_nsctiutz Bl > 1 K49 .... )) .... ., i , i i_ 162163 jytarkownikoff B 13 1845 .... Jl .... 160-161 Barbaglia B. 7 466 .... .... 160 Olans and T isphlrp "R ]^ 1AQ9 .... J1 oiaus dim j_jiaciiKt; r>., !*, iuz 161 Fittig P T P 1 ft77 .... )J VJ". w . \j.j Lot i 161-162 .Anscliiitz and J*Gtr Bi q -i K.Af\ .... )J .... ., 1 >, 1 ' 1U Mesaconic acid .... 202 Swarts G. J. C., 1868 .... 202 Barbaglia B., 7, 466 .... IJ .... 200 .... iii., 928 ,. .... 200-5 Aarland J. p. [2], 6, 256 26, 377 ., .. .... 202 Morawski J. p. [2], 11, 430 28, 1254 j, .... 201-203 Bottinger A., 188, 293 34,32 .... 208 Gottlieb G. J. C., 1852 26, 377 Ethenyltricarboxylic acid ... COOH.CH 2 .CH(COOH) 2 CsH.O, 158 Bischoff B., 13, 2162 ; 15 40, 156 1109 ,, - n .... 159 A., 214, 40 44,45 - 159 Conrad B., 12, 752 36, 707 Ethylpropargyloxide CH. : C.CH 2 .OEt C 6 H 8 72 Liquid Liebermann A., 135, 284 vi., 98, 958 D 80 Liquid Liebermann and A., 158, 230 vii., 1007 Kretschner n 81-65 Liquid Henry B., 5, 275, 570 vii., 1007 ; 26, 480, 807 82-84 Briihl A., 200, 139 38, 296 Tiglic aldehyde (guajol) CH 3 .CH:CMe.CHO 118 Liquid Deville C. R, 17, 1143 ; 11., 945 19, 134 n n 118-121 .... Herzig M. C., 3, 118 42,594 ? ketone .... 129-131 .<. Claisen B., 8, 1258 32,291 ? > .... 129-131 .... Pinner B., 15, 594 ? .... 202-207 .... A., 217, 137 Ethylic acrylate CH^CH-COOEt C 5 H 8 2 98-5 Weger A., 221, 161 46, 11 ii 101-102; Liquid Caspary & Tollens B.S., 20,368; B., vii., 27 ; 25, 100-101 5, 560 814 Allylic acetate CH 2 H:CH.C 2 .OAc 98-100 .... Cahours & Hofm ami A., 102, 295 i., 21 n 103-104C734) .... Briihl A., 200, 179 38, 296 ,, n 97-100 .... Hofmann& Cahours J., 9, 585 105 .... Zinin J., 8, 618 Methylic a-crotonate CH 3 .CH : CH.COOMe 1207 Kahlbaum B., 12, 344 36, 521 From pyrotartaric chloride ... 203-205 Liquid Hjelt B., 16, 2624 46, 297 Valerolactone.... .... Me.CH.CH 2 .CH .CO.O 1 1 Q "W~lflP A OAQ 1 A/1 A*> Q.R i "' i 1. lo W OIU 206-207 Liquid Fittig B., 13, 955 38, 799 H 206-207 I 18 Messerschmidt A., 208, 92 42, 35 207 c. 1. 18 Hjelt B., 15, 629 42, 948 CHMe 2 .CH.CO.O 260 d. 121-122 Demargay C. R, 83, 449 30, 507 Valerolactide .... 1 Of* . , . _ , . A -mo 110 . ... )> jS2(j 2QO lob scnmidt & bacutle- .j 1 ,;o, 1 i o > ^ *" ben Allylacetic acid CH 2 :CH.CH 2 .CH.COOH 182 Liquid Zeidler B., 8, 1035 29, 368 152 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Allylacetic acid CH 3 : CH.CH 2 .CH 2 .COOH C 6 H S 2 182 .... Zeidler A., 187, 39 32, 437 )> 184 .... Conrad & Bischoff B., 13, 595 38, 628 M 187-189 1.-18 Messerschmidt A., 208, 92 42,35 Tetramethylene carboxylic CH 2 :(CH 2 ) 2 :CH:cooH M 193-195 Liquid Perkin B., 16, 1795 44, 1084 acid Propylidene acetic acid Angelic acid .... CHEt:CH.COOH 194-198 Liquid Liquid Kommenos Kramer & Grodzki A., 218, 145 B., 11, 1360 46, 423 36, 44 C 4 H 7 .COOH j) 185 45 45 Fittig Biichner B., 9, 1195 A., 42, 226; 106,62 31,97 38, 314 jj 190 45 Meyer and Zenner A., 55, 321 i., 293 1J j) 45 Wright and Luff 33, 348 JJ ?) ) 184-185 45 45 Schmidt A. P. [3], 13, 213 B., 12, 254 36, 222 M 51 185 c. 45-45-5 J) Kopp A., 195, 85 36, 454 Methylcrotonic acid (tiglic CH 3 .CH:CMe.COOH J) 201-1 c. 64 ft: Geuther & Frohlich Z. C. [2], 6, 26 vii., 395 acid) 196-197 u. c. 64 Berendes B., 10, 835 32, 593 J> 196-197 u. c. 64 Schmidt A. P. [3], 13, 213 36, 222 )> )) 196-197 u.c. 64 j> B., 12, 254, 257 jj >i )> H 198-5 c. 64-5 Kopp A., 195, 88 36, 454 198-5 65 Fittig B., 9, 1195 31,97 194-196 61-62 Demarc,ay C. R, 80, 1400 30, 70 JT M V .... 64-5 B., 9, 1933 " )> j 62 Frankland & Duppa 18, 133 vi., 828 V > 62-5 Eiicker B., 10, 1954 34, 292 ) )! 11 j) 64 c. Wright and Luff 33, 348 ? 65 c. " .... )i 65 v. Miller A., 200, 261 38, 315 Dimethylacrylic acid CMe 2 :CH.COOH i> .... 69-5 B., 10, 2036 34, 292 )> .... 69-5 A., 200, 261 38, 314 .... 69-5-70 B., 11, 2216 36, 307 i i >i .... 68-5-69 Semlianitzine and B. S. [2], 31, 199; 36, 618 Saytzeff A. C. [5], 19,428 I? .... 69-5-70 Neubauer A., 106, 163 From leduru camphor Pyroxanthin .... .... 174 101 144 J. [1876], 909 iv., 776 Ethylic pyroracemate CH 3 .CO.COOEt C 6 H 6 S 130 d. Liquid Biittinger B., 14, 317 40, 418 Epihydrin acetate O.CH2.CH.CH2.0AC 168-169 .... Gegerfelt B. S. [2], 23, 160 28, 879 )i )> J) 16^168 Liquid Breslauer J. p. [2], 20, 188 38, 29 !) !> j (C 5 H 8 0,). 258-261 Liquid Acetyl carbinol acetate (pyru- Me.CO.CHj.OAc C 6 H 8 3 169-170 Brandes J. [1866], 305 vi., 829 vic acetate) > J> 172-172-5 Breuer and Zincke B., 13, 638 38, 645 i )J 5 175 (745) Liquid Henry B., 5, 966 vii., 14; 26, 379 Butineglycol formate C 4 H 6 (OH)(O.CHO) JJ 190 Heninger B., 5, 1059 ; 6, 71 Butyrylformie acid CH 3 .CH 2 .CH 2 .CO.COOH 115(82-84); .... Moritz 39, 18 180-185 (760) /9-acetylpropionic acid (levu- CH.,Ac.CH 2 .COOH ) 239 31 Conrad A., 188, 223 34, 137 linic) ii )J 239 .... j> B., 11, 2178 36, 453 JJ 235-255 32-5-33-5 Grote and Tollens B., 10, 1442 32, 882 j? !) ;> 250-260 a, 11 B., 7, 1376 28, 250 !> J) i> 239 31-31-60 Grote, Kehrer, and A., 206, 207 40, 410 Tollens Hydroxypentinic acid .... 94-95 .... A. C. [5], 20, 488 Methoxy-acid . . . . From /3-Chlorisocro tonic acid )> .... 128-5 Friedrich B., 15, 218 42, 945 Oxyangelic acid .... j 270-280 184 Demargay C. K., 83, 449 30, 507 Ethylic methylic oxalate ... COOEt.COOMe C 6 H 8 O 4 160-170 Liquid Chancel Co. C., 1850 iv., 271 COMPOUNDS CONTAINING THREE ELEMENTS. 153 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet & J. Ch. Soc. Dimethylic malonate CH2.(COOMe) 2 C 6 H 8 4 175-180 Liquid Osterland B., 7, 1286 28, 142 u ji 181-5 c. Perkin 45,509 Diacetoxymethane CH 2 (OAc) 2 )> 170 .... .... A., 107, 111; 111, 245 Glutaric acid COOH.(CH 2 ) 3 .COOH abt. 97 Eitthausen J. p. [2], 5, 354 vii., 562 abt. 97 Dittmar J. p. [21 5 344 vii., 423 ; 25, n r L J) > u-x-x 815 j) 11 * ** ) .... 97 Baeyer B., 10, 1286 34,4 96-97 Wislicenus and A., 192, 128 i) Limpach 96 Conrad & Outhzeit B., 15, 2843 j, .... .... .... J i > 215; 30S-304 97-5; 95-5 Markownikoff A., 182, 341 31,62 96-5 Moriya 30, 79 j> 97 39, 80 11 11 .... .... .... > i 291 ; 299 c. 96-5 *> Retool A. C. [5], 14, 501 36, 134 j) ,, .... .... .... ) i) .... 97 11 B. S. [2], 25, 386 30, 287 103-104 Pyrotartaric acid (methyl COOH.CHMe.CH 2 .COOH 11 11 a. 190 a. 100 Arppe 1J A., 66, 73 11 succinic) i 11 i i .... 110-112-5 KekulS As., 1, 338 n i> 180-190 111-112 Pelouze A., 16 i 11 i R .... 112 Moldenhauer G. J. C., 1864 n i 11 11 >i .... 110-112 Clermont B. S. [2], 19, 103 26, 495 11 i )i .... 111-112 Wislicenus A., 149, 220 vii., 1035 11 11 n .... 111-112 Keboul B. S. [2], 25, 386 30, 287 i) 11 i )) u .... 111-5 Kressner A., 192, 135 34,783 11 i 11 n abt 200 112 .... .... iv., 772 11 11 n ! 112 Bischoff B., 15, 1109 42, 1188 11 11 1 1U Markownikoff A., 182, 324 31, 61 11 sj ) 112-5 Bottinger A., 188, 293 34,32 u 11 i > 113 s n J! Ethylmalonic acid COOH.CHEt.COOH )1 111-112 Wislicenus & Urech A., 165, 93 26, 376 ) 11 .... 111-112 Demar^ay B. S. [2], 25, 386 30, 287 ,, .... H 11 111-5 Conrad B., 12, 751 36, 707 11 i ) .... 111-5 Markownikoff A., 182, 329 31, 62 11 Liquid Wislicenus A., 149, 220 vii., 1035 Uvic acid 11 .... 133 Bottinger B., 8, 1584 29, 566 133 B., 9, 838 30, 400 C 5 H 6 4 ? n. f. 140 j* Laurent A. C., 66, 169 iii., 704 Jl 150 Wirz A., 105, 257 Dimethylmalonic acid Me 2 .C(COOH) 2 11 51 >... 165 d. Pinner B., 15, 581 42,942 11 " > 11 s.b. 120 170 d. MarkowuikofF A., 182, 336 31,62 ii 11 )> .... 185 Conrad & Guthzeit B., 14, 1644 j> 11 i) 1 186 p. d. Thome 39,544 (?) From phoronic acid 1) 190 Pinner B., 15, 585 42, 942 Glycerol diformin C 3 H 5 .OH.(O.CHO) 2 C 6 H 3 5 163-166 (20- Komburgh C. R, 93, 847 ; B. 42, 378 30) 16, 393 Itamalic acid CH 2 (OH).CH(COOH).CH 2 . 1) .... 60-65 Swarts B. A. B. [2], 24, 25 vi., 761 COOH )5 11 .... 60-65 Moms 37, 14 a-Hydroxyglutaric acid COOH.CH(OH).CH 2 .CH 2 . n .... 72-73 MarkownikofT A., 182, 347 31, 63 COOH <- >; n .... 72 Lippmann B., 15, 1157 n- ) 73 Bitthausen J. p. [1], 103, 239 Ethyltartronic acid CEt(OH)(COOH) 2 )> 98 Guthzeit A., 209, 233 42, 39 ji .... 98 Conrad B., 14, 618 Methylhydroxysuccinic acid COOH.CMe(OH).CH 2 COOH n 106 Bredt B., 14, 1783 42, 162 ;i I 11 108 Morris 37,8 )) '> T 11 (?) Demar9ay C. K., 82, 1337 C'itramalic acid C 3 H 5 .(OH)(COOH) 2 11 .... a. 100 Morawski J. p. [2], 11, 430 28, 1253 ,, ,, .... )) 11 110 W. A., 76, 670 36, 707 154 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Mesamalic acid C 3 H 6 (OH)(COOH)j C 5 H 8 6 129-130 G. H., 502 |3-Hydroxyglutaric acid COOH.CH2.CH(OH).CH 2 . 133 Simpson A., 157, 34 24, 133 CoOH T) (?) Markownikoff A., 182, 347 31,64 n .... abt. 135 Simpson P. E. S., 13, 44 iv., 315 Citratartaric acid C 6 H 8 6 .... a. 100 Carius A., 129, 164 v., 696 Aposorbic acid C 3 H 6 O a (COOH) 2 C 5 H 9 7 170 p. d. abt. 110 Dessaignes E. C. p., 5, 41 vi., 190 (?) C 3 H 6 .CMe.OH ? C 6 H 9 (?) 110-115 .... Pawlewski B., 5, 331 25, 1093 Methylisocrotyl oxide CMe 2 :CH.OMe C 5 H 10 70-74 Liquid Eltekoff B., 10, 705 Allylethyl oxide Et.O.CH 2 .CH:CH 2 ,, abt. 64 .... Hofmann & Cahours J., 9, 583 1, .... 62-5 .... Berthelot & De Luca J., 9, 590 .... 60-65 .... Henry B., 5, 569 25, 807 66-5 Briihl A., 200, 177 38, 296 , 67-2 ; 245 c. t. Pawlewski B., 16, 2633 46, 252 84 Liquid .... .... i., 142 85 .... Grosheintz B. S. [2], 31, 390 36, 780 Ethylallyl alcohol C,H 4 Et.OH ,, 120 Wurtz 24, 1025 ? ketone .... 76-81 Liquid Bouchardat C. E., 93, 316 40, 1114 ? 90-100 Linnemann Z. C. [21, 4, 57 iv., 959 Methylisopropyl ketone Me.CO.PrP B 92 .... Ceresole ^ J ' L J) J B., 15, 1875 >. .. 93-5 Geuther vi., 768 93-5 Frankland & Duppa J., 18, 309 * 93-94 Miinde B., 7, 1371 28, 247 n n 93-94 .... Munch A., 180, 327 30, 68 93-94 .... Winogradow A., 191, 125 34, 484 94-1 Kachler A., 191, 63 34, 514 94-95 Eltekoff J. R, 82, 355 44, 566 n 95 .... Butlerow A., 144, 1 vi., 969 n (C 5 H, 0). b. 200 .... Kaschirski C. C. [1881], 278 42, 37 Methylpropyl ketone Me.CO.Pr" 95 .... Butlerow B. S. [2], 5, 17 vii., 1022 90-95 .... Fittig A., 110, 18 i., 31 95-105 .... Bruylants B., 8, 411 100-102 .... Kutscheroff B., 14, 1542 r> abt 100 .... Geuther J. Z., 6, 560 vii., 488 )> n - * ~*' : j 101 (760) J., 20, 455 vi., 768 99-101 Liquid Grimm A., 157, 251 vii., 1022 ; 24, 385 v 101 Liquid Frankland & Duppa J., 18, 307 24, 386 100-102 Popoff A., 161, 285 101-103 Wichnegradsky A., 190, 328 34, 394 )> W 102 c. .... Perkin 45, 479 n n T) 103 .... .... vi., 112 n 102-105 Schlorlemmer P. T. [1872], 111 25, 1085 n n 103 .... Wagner & Saytzeff A., 179, 322 29, 548 n 111 .... Friedel .A.C. [4], 16, 366 vii., 1022 ; 24, 386 Diethyl ketone Et.CO.Et 'I 100-101 .... Freund J., 13,313 100-101 .... Schmidt B., 5, 599 25, 892 101 Liquid Chapman & Smith J., 20, 453 iv., 729 ,, 100-105 .... Destrem B., 16, 227; A. C. [5], 27, 5 .... J) 104 .... Wagner & Saytzeff A., 179, 322 29, 548 110 .... Limpricht & Uslar J., 8, 510 24, 386 Pivalic aldehyde CMe 2 ^ abt. 90 Friedel and Silva C. E., 77, 48 26, 1127 Methylethyl acetic aldehyde CHMeEt.CHO 85 Eltekoff B., 10, 706 Iso-valeric aldehyde CHMej.CHj.CHO ,, 90-5-91 .... Erlenmeyer & Hell A., 160, 257 90-92 .... Herzig M. C., 3, 118 42,594 B 92-5-92-9 Lossen A., 214, 154 90 Personne J., 7, 654 " & 92-94 e. .... Perkin 45, 477 COMPOUNDS CONTAINING THREE ELEMENTS. 155 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Iso- valeric aldehyde CHMe2.CH 2 .CHO C S H 10 92-5 .... Pierre and Puckot B. S. [2], 9, 1033 vii., 62 jj jj .... * jj JJ 92-5 C. K., 76, 1332 26, 1017 jj jj J 92-5 (758-2) Schroeder B., 4, 400 24, 559 ; vii., 1195 j, .... > 92-8 (740) Kopp A., 95, 315 v., 972 ,, .... JJ 93-6-93-8 .... A., 97, 370 (760) j, (C 5 H 10 0). JJ 215 .... Wanklyn J., 22, 530 jj .... 83-84 Bruylants B., 8, 415 Valeric aldehyde .... J 96-97 (760) .... Kopp v., 972 JJ 96-98 .... KY'ininl A. C. [6], 1, 223 46, 844 I* .... JJ 97-98 .... Schmidt B., 5, 597 25, 892 CH 3 .(CH 2 ) 3 .CHO JJ 101 ? ? vi., 959 JJ 102 .... Lieben and Rossi G. I., 1, 314 24, 1033 ; vii., 1195 ,, .... I) > abt. 110 .... Chancel J. F. P., 36, 447 >1 jj 110 Limpricht & Uslar J. [1865], 509 vi., 959 ,, ,, J J) 111 .... Friedel A., 108, 122 iii., 1002 ,, (C 5 H 10 0). )J 150-200 .... Parkinson A., 90, 114 v., 972 From colophony JJ 90-95 Bruylants B., 8, 1464 20, 615 Trimethylethylene oxide O.CMe.,.CHMe I T.J JJ 75-76 Eltekoff J. K. [1882], 355 44, 566 Methylethylethylene oxide .... O.CHEt.CHMe i i JJ 80 .... B., 16, 396 >j Isopropylethylene oxide O.CHyCHPi* JJ 82 J) jj 1 1 Amyleae oxide c 6 H 10 :o JJ 95 Liquid Bauer C. R, 51, 500 i., 209 jj jj JJ 95 Niederist A., 196, 349 36,700 Valerylene hydrate .... J 115-120 Reboul C. R, 64, 284 vi., 1124 Isopreiie hydrate (alcohol) JJ 120-130 .... Bouchardat C. R, 89, 1117 38, 323 Butylic formate H.COO.(CH 2 ) 3 .CH, C 6 H 10 2 104-105 M. C., 2, 692 Isobutylic formate H.COO.CH 2 .CHMe 2 abt. 100 Liquid Wurtz A., 93, 121 ii., 695 JJ ji 98-5 Pierre and Puchot A. C. [4], 22, 319 ,, )J > 97-9 (760) .... Schumann G. J. C., 1881 ,, j 97-9 Elsasser A., 218, 302 44, 967 Propylic acetate CH 3 .COOPi- 95-100 .... Hodgkinson .... 37,483 JJ n 99-101 Briihl A., 200, 139 38, 296 J ) 100-101 Eossi C. R, 70, 129 vi., 964 J II 100-101(750) H G. I., 1, 230 24, 1032 )< )J 102 (750) A., 159, 81 vii., 8 .... JJ 100-102 Tollens Z. C. [2], 7, 249 25, 998 > 100-8 Elsasser A., 218, 302 44, 967 J, JJ > 101-98 .... Linnemaun A., 161, 30 vii., 203, 1013; 25, 203 ;j J )) 100-8 (760) .... Schumann G. J. C., 1881 JJ 1) 102 Chancel C.R,68,659,726 vi., 964 diff'. samples JJ )' 103 Pierre and Puchot C. R, 66, 302 vi., 964 JT JJ JJ Jj 105 ii Z. G, 12, 660 vi., 963 J* 1J )J JJ J) )J 103 i) j A. C. [4], 22, 289 JJ JJ " ** JJ 1) 102-103 c. Perkin 45, 494 JJ 100-3; .... Pawlewski B., 15, 2463 44, 276 282-4 c. t. Isopropylic acetate CH 3 .COOPr/s ) 90-93 Friedel A., 124, 327 v., 891 jj JJ 90 Liquid Berthelot i., 24 u j) " 88-91 .... M. C., 2, 686 Ethylic propionate CH 3 .CH 2 .COOEt ) 98-84 ; Linnemann A., 160, 219 vii., 203 98-8 (732) JJ )1 101 Limpricht & Uslar J., 8, 509 jj jj JJ 1 93-2-98 Kopp A., 94, 322 J? J 97-7-97-9 jj A., 95, 316 jj (753) diff. samples 1J )> 100 (760) .... Pierre and Puchot Z. C., 12, 660 11 >j ) JJ 100 (760) .... >i jj A. C. [4], 22, 351 x 2 Io6 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylic propionate CH^CHyCOOEt C.H.A 98-3 (760) .... Schumann G. J. C., 1881 )) >! J) 98-3 Weger A., 221, 61 46, 11 >! ? 98-3 Elsasser A., 218, 302 44, 967 ) 99'5-99'8 c. Perkin .... 45, 496 )> )> j) ;> 98-5; .... Pawlewski B., 15, 2463 44, 276 280-6 c. t. Methylic butyrate CH 3 .CH 2 .CH 2 .COOMe j 101 .... Kahlbaum B., 12, 344 36, 521 j) )i 95-1-103 .... Zander A., 214, 184 (736-742) l> 102 Liquid Atkinson .... i., 696 ,, ) 102-5-10S-5 .... Kramer & Grodzki B., 11, 1358 (760) .... .... 1 ) 102-3 Elsasser A., 218, 313 44, 967 >. J 102-103 c. Perkin 45, 499 j> > j 102-1 Pierre C. E., 27, 213; P. A., 76, 458 n n TJ 5> 95-9 (760) .... Kopp P. A., 72 it 5) 93 Delffs J., 7, 26 !> H )J 93 .... Favre & Silbermann A., 95, 315 isobutyrate CHMe 2 .COOMe 93 (760) Pierre and Puchot C. E., 75, 1006 26,55;vii.,226 JJ J) 92-3 (760) .... Schumann G. J. C., 1881 >* 92-3 Elsasser A., 218, 302 44, 967 n )) )J 89-91 .... .... M. C., 2, 682 ) JJ 91-7; Pawlewski B., 15, 2463 44, 276 273-6 c. t. Valeric acid CH3.(CH 2 ) 3 .COOH 18575 c. Kehrer and Tollens A., 206, 237 40, 411 > " )) 185 .... Lieben and Eossi C. E., 71, 370 vi., 106, 1121 184-185 c. 1. 16 G. I., 1, 239 ; A. 24, 1044 ; vii., j) 1) (736) u j) 159, 58 1197 183-185-75 Lessen A., 214, 154 3> 183-185 Cahours& Demarcay C. E., 89, 331 36, 1036 > 185-2-187'2c. Perkin 45, 484 j 183-185 Kramer & Grodzki B., 11, 1359 183-185 Fitz B., 13, 1309 Isovaleric acid CHMe^CH^COOH 178 .... Pierre and Puchot O. E., 76, 1332 vii., 62 ; 1200 j> i) 1) 178 (760) .... u C. B., 75, 1005 ; 26,55,874,1017 A. C. [4], 29, 228 > " J )J 175-8 (746) .... Kopp A. v., 976 yy )> 175 1. 15 Dumas and Stas A., 35, 145 ,j n 175 1. 15 Person J., 1, 91 j J TJ 175 Lieben and Eossi G. I., 1, 239 24, 1044 ,, )J 195 (?) .... Eamsay 35, 469 .... .... 7> )) abt. 175 Vincent B. S. [2], 31, 156 36, 612 . ,, .... H 175 Personne J., 7, 653 n )> 174-176 .... Popoff B., 5, 39 vii., 712; 25, 408 .... )) 173-176 u.c. Gritnshaw 26, 317 (inactive) .... JI )> 174-1 (723-5) .... Balbiano G. I., 6, 229 31, 293 1) > j) 174 Landolt P. A., 117, 353 J ji 173-2-175-8 .... Lessen A., 214, 154 )> ,, 173-175 .... E6nard A. C. [6], 1, 223 46,844 ,, .... 5> 174 .... A., 204, 151 JI 175-5-176-5 Perkin 45, 488 >: n 5 174-5 .... Delffs A., 92, 277 j 173-2-174-3 .... Erlenmeyer & Hell A., 160, 257 vii., 1199 (718-3) ,, M j 172-6-174-1 c. IT ) n M (722-5) (inactive) j )> 174-5 c. (721) .... )) T> si )> > )> 171-5(721-8) ?> 25, 243 ii 171-172 u. c. )' V 25, 242 (722-5) COMPOUNDS CONTAINING THREE ELEMENTS. 157 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. Isovaleric acid CHMe 2 .CH 2 .COOH C 5 H 10 O 3 174 Conrad & Bischoff B., 13, 596 38, 627 ,, 175 .... Frankland & Duppa J., 20, 396 (inactive) .... 11 175 Pedler 21,74 vi., 1121 u 175 u. c. .... Schmidt and Sach- A., 193, 91 36, 139 (754-8) tleben Methylethylacetic acid CHMeEt.COOH N 173-175 Berendes B., 10, 836 32, 593 i v 173-1 75 u. c. Schmidt B., 12, 257 ; A., 36, 618; 40, 208, 256, 262 1126 ii 11 )> 173 u. c. Saur B., 8, 1037 29, 370 i) ii j> 173u. c. 11 A., 188, 257 34,27 ( in - > 173 Conrad & Bischoff B., 13, 596 38, 628 active) [+1... )> 174 (770) 1. 15 Lescceur B. S. [2], 27, 104 31, 589 [+]..-. Jl jj 172-5-173-5 Erlemneyer& Hell A., 160, 268 vii., 1198 (721) [+]. 11 171-173 ii 11 ii )) (718-3) ,, [+]- N N 172-5-173-5 .... ii 11 11 )) (721) i, [+].. j 173; 174-175 .... Ley B., 6, 1368 27, 351 ii ) )> 170-176 .... Miiller B., 14, 2478 42, 496 [+].. )) 168-171 .... Erleiimeyer & Hell A., 160, 257 25, 243 ; vii., 1199 [+]-. 168-171 c. .... ii ii ii 11 ii (720-8) 11 'I 177 Liquid Pagenstecher A., 195, 118 36, 456 [+]...- )j > 170 .... Pedler 21, 74 vi., 1121 Trimethylacetic acid Me 3 C.COOH n 163-7-163-8 35-3-35-5 Butlerow B., 7, 728; A., 27, 1083 ; 28, (760) 173, 355 248 ,, .... H 163-5 33 ii 11 ii ii n M 161 34-35 ii A., 170, 151 ; B., vii., 221, 1182; 5,478 26, 48; 27, 248 II 1! " j r 160-163 26 Friedel and Silva B., 6, 146 .... )> 163 29-30 ii 11 C. B., 77, 48 26, 1126 Ethylpyruvyl oxide Me.CO.CH 2 .OEt )T 128 Liquid Henry C. E., 93, 421 40, 1121 O.CH 2 .CH.CH 2 .OEt 128-129 Liquid Reboul A. C. [3], 60, 58 ii., 897 ?> Acrolein alcoholate Me.CH(OEt).COH jj 130 d. Faubert J. Z. N., 10, 1 31, 296 Fucuaol .... 171-172 Stenhouse P. M. [3], 18 ii., 718 Diethylic carbonate CO.(OEt) 2 QH 10 3 125-126 Liquid Ettling A., 19, 17 i., 800 ii ii ) 125 Salomon J. p. [2], 6, 433 26, 620 ii 11 5> 11 125 (730) .... Schreiner J. p. [2], 22, 353 40, 88 u 11 ) II 125 Cahours 11 11 11 11 126 ... Clermont J., 7, 561 ii ii 11 11 123-5-125-8 .. Kopp A., 95, 325 (749) ii i) 11 126-126-4 .. BriihL A., 200, 139 (748) Methylic propylic carbonate CO(OMe)OPr 11 130-8 c. .... Eose A., 205, 245 40, 252 Ethylic methylglycollate .... CH 2 (OMe).COOEt 11 131 Folsing B., 17, 486 46, 897 ii ii )> 11 138-6 Schreiner B., 12, 179 36, 522 11 11 11 138-6 ii J. p. [2], 22, 353 40, 88 Methylic ethylglycollate CH 2 (OEt).COOMe 11 142 11 A., 197, 8 J ii 11 11 152 .... 11 B. 12, 179 36, 522 11 ii ) 11 148 Folsing B., 17, 486 46, 897 Propylic glycollate CH 2 (OH)COOPr" II 170 Schreiner B., 12, 179 36, 522 ii ii 11 170-5 ii A., 197, 6 Ethylic a-lactate CH 3 .CH(OH).COOEt 11 154-5 .... ii B., 12, 179 36, 522 11 11 )) II 156 (753) Wurtz and Friedel A. C. [3], 63, 102 iii., 463 Methylic methyllactate CH 3 CH(OMe).COOMe II 135-138 .... Markownikoff and A., 208, 333 40, 1127 Krestownikoff Ethyl-lactic acid CH 3 .CH(OEt).COOH 11 195-198 Wurtz A. C. [3], 59, 174 iii., 464 158 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Methylethyl hydroxyacetic acid j) ?> D )i i Hydroxyisopropylacetic acid Acetoglycerol .... CMeEt(OH).COOH 1 CHPr"(OH).COOH j) C,H 5 (OH)(O 2 : C 2 H 4 ) ^sHio^s j> j) >> j> 190 d. 184-188 68 63 68 80 82 83 86 Frankland & Duppa Booking Miller Fittig and Clark Schmidt and Sacht- leben Lipp Ley and Popoff Harnitzky and P.E.S.; A.,136,9 A., 204, 18 B., 12, 1544 ; A., 200, 282 A., 139, 200 A., 193, 106 A., 205, 28 B., 7, 732 B. S. [2], 3, 253 ; iv., 275 38, 872 38, 35, 315 vi., 894, 1123; 27, 1082 36, 140 40,86 27, 1082 vi., 637 Valerolactone. . . . 207 c. 1. -18 Menschutkin Hjelt A., 136, 126 B., 15, 623 Ethylic glycerate From ethylic orsellinate Propylethyl oxide ,, .... .... Isopropylethyl oxide Aiuyl alcohol CH s (OH).CH(OH).COOEt EtO.Pi* n EtO.Prf n CH, (CH 2 ), CH 2 OH C 6 H 10 4 C 6 H 10 6 C.H^O j j) 230-240 65-S 63-64 68-70 54-55 47^8 137 (744) Liquid 60 Henry Hesse Briihl Chancel Morkownikoff Lieben and Eossi B., 4, 706 A., 117, 297 A., 200, 177 A., 151, 305 C. B., 68 A., 138, 374 C. B., 93, 69 C. B., 71, 370 24, 908 ; vii., 563 iv., 236 38, 296 vi., 964 vi., 106 137 (740) A., 159, 70 ; G. I., vi., 1137 ; 24, ,, .... .... .... > M 137 134-137 Schorlemmer 1, 314 27, 1030 P. T. [1872], 111 1033 ; 26, 1082 vii., 868 vii., 63; 25, 1085 (?) 134 Eieckher J., 1, 698 ( + ) (?) (?) 133-134 133 Bakhoven Kopp P. A. eb., 6, 325 ; B., 9, 358 A., 55, 166 27, 140 (inactive) n 11 11 11 11 Mej.CH.CHj.CHjOH 11 11 )> N Yl 131-4 (747) 131 131-5 c. 128-9-133 .... Balbiano Flavitzky Perkin Lessen G. I., 6, 229 A., 169, 205 A., 214, 154 31, 293 27, 138 45, 470 V .... W ) (741-751) 132-1 ; 306-6 c. t. s. 134 Pawlewski Olzewski B., 16, 2634 M. C., 5, 127 46, 252 46, 816 (inactive) 11 ) n * w ) J) 128-132 129 129-131 Lieben and Eossi Pedler Gladstone & Tribe G. I., 1, 314 A., 147, 249 24, 1034 ; vi., 1137 vi., 106; 21, 74 39, 7 (inactive) 129-130-1 (714-8) 128-132 Erlenmeyer & Hell Bertoni and Truffi A., 160, 257 G. I., 14, 23 25, 243 46, 1110 Me 2 CH CH^CH-jOH or 132 a 22 i., 203 ... .... ... ) .... .... .1. Et.CHMe.CH 2 OH ) 11 . W J) 132 132 132 Cahours Person Thorpe A., 30, 288 J., 1, 91 37, 151 131-8 Pierre J., 1, 52 132 Delffs J., 7, 26 different source. 11 11 11 11 > 11 JJ 1J 132 132 128-131 .... Schorlemmer J! J., 19, 527 28, 308 130-132 J. Eegnault and J. P. [4], 30, 405 38, 456 ,, .... > 129-132 128-132 Hardy Demar9ay Eabateau C. B., 77, 360 C. B., 87, 501 26, 1227 36,36 (active) ,, .... CH 3 .CH 2 .CHMe.CH 2 OH 11 )) )) 130-5-131-5c 130-9-131-6 Perkin Kopp A., 96, 255 45, 469 COMPOUNDS CONTAINING THREE ELEMENTS. 159 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Amyl alcohol (active) (-) (-) ( ) (active) (-) (-) ,, (-) ,, (-) ..- -.. CH 3 .CH 2 .CHMe.CH 2 CH J )> 51 ) )) > )) M (?) (?) CH 3 .CH 2 .CH 2 .CH(OH).CH 3 J> )> ) ) 5) 5 CH 3 .CH 2 .CH(OH).CH 2 .CH 3 JJ Me2.CH.CH(OH).CH 3 )) ji ;> j) ij J) Me 2 .C(OH).CH,.CH 8 ) )) )> 5) 1 5) ) 1) )> i >) CH 3 .CH(OMe)(OEt; CH 2 (OEt) 2 )> C 6 H 12 J JJ )I ) ) 1 )J )) ) J) )J 5) )J ) 1 ? 1 n )> 5 )> )) ) )> )> )7 )J )> )) V ) )) )! n n j> j> ?> n )i C 6 H 13 2 > n 55 131-1 (760) 130-131-5 130-130-2 (760) 130 127-131 128 128 127-128 125-130 128-129 125-126 127 113-121 121 120-123 120-123 120-122 120 (759) 120 118-5-119-5 117-5-119 118-120 118-5 116-120 116-117 116-5 113 112-5 112-5 108 108 108 104-108 105 (768) 105 102-105 102-103 102-104 105-108 103-104 102-3 (761-2) 102-104 100-108 102-104 102-5 102-5 101-5-102 c. 98-5-102 99-100 98-5-100 96-97 95-97 b. 100 85 85 87-88 89 (769) L 33 1. f. m. Liquid 1. 30 1.-30 .IS 12 n b. 17 s. 30 a. 30 a. 21 Kopp Popoff Pierre and Puchot j> Plimpton Pedler Ley Pasteur Erlenmeyer & Hell Etard Herzig LeBel )! )> Friedel Lieben and Rossi Schorlemmer Wurtz Ea bateau Linnemann Wisch negradsky Grimm Wagner & Saytzeff LeBel Wagner & Saytzeff Winogradow Butlerow Wischn egradsky Miinch Munde Kolbe Lieben and Eossi Wurtz LeBel Osipoff Flavitzky Wurtz Flavitzky j) Winogradow Wischnegradsky Perkin Popoff Ermolaien Lieben and Rossi Osipoff T Flavitzky Bachmann Wurtz Pratesi Green P. A., 72 B., 5, 381 A., 163, 253 ; B. S. [2], 9, 1033 C. R., 76, 1332 A., 147, 243 B., 6, 1363 A., 160, 257 C. R., 86, 488 M. C., 3, 118 B., 6, 1315; 9,733 C. R., 73, 499 Z. C., 14, 471 Z. C. [2], 5, 486 G. I., 1, 314 P. T. [1872], 111 Z. C. [2], 4, 490 C. R, 87, 501 B., 9, 925 A., 190, 348 A., 157, 249 A., 179, 313 C. R., 89, 312 A., 175, 351 A., 179, 313 A., 191, 127 B., 10, 407 A., 190,338; B., 10, 405 A., 180, 339 B., 7, 1371 G. I., 1, 314 A. C. [4], 3, 137 B., 5, 216 B., 8, 1240 B., 8, 542 B., 5, 479 A., 125, 114 A., 179, 349 A., 179, 340 A., 165, 157 j A., 191, 125 B., 10, 404 A., 190, 336 A., 145, 292 Z. C., 14, 275 G. L, 1, 314 B., 8., 542 B., 8, 1242 A., 169, 205 A., 218, 38 A. C. [3], 48, 375 G. I., 13, 313 C. R., 89, 1077 vil.,712; 85,408 25, 888; vli., 62 26, 1017 39, 334 vi., 106; 21, 74 27, 350 34,393 42, 594 24, 1025 vi., 112 24, 1034 ; vi., 1137 25, 1085 vi., 112 36, 36 30, 504 34, 394 24, 386 29, 548 36, 1029 28, 628 29, 548 34, 484 32, 589 32,420; 34,393 30,68 vi., 112 24, 1034 ; vi., 1137 vi., 112 29, 545 28, 877 26, 45 34, 394 29, 545 26, 369 vii., 64 34, 484 32, 420 34, 393 45, 471 vi., 115 vi., 1137 ; 24, 1034 28, 877 29, 545 27, 139 44, 727 vi., 4 46, 172 38, 307 ,, (active) ,, .... )> .... ) )> .... .... ,1 Ethylmethylacetal .... Diethoxymethane 160 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Amyleneglycol j .... .... .... > * j .... .... i i) .... .... i j, .... .... jj .... Cantharidin .... CMe 2 (OH).CHMe(OH) n jj CHEt(OH).CHMe(OH) )J )) 1 CHPr(OH).CH 2 (OH) CHPrP(OH).CH 2 (OH) JJ C 5 H 12 2 j jj jj j jj jj jj jj jj jj 176-177 178-179 177 177 187-5 187-188 188-189 185-190 185-3 200-5-201-5 206 jiquid 200 Eltekoff Tlavitzky Wurtz Wagner & Saytzeff Eltekoff Wurtz flavitzky jj jj jj J. R. [1882], 355; B., 16, 396 B., 10, 2240 B., 9, 1600 A. C. [3], 55, 458 A., 179, 308 J.R [1882], 335; B., 16, 397 B., 9, 1600; 11 679 B. S. [2], 30, 22 B., 11, 992 A., 179, 352 44, 566 i., 208 29, 547 44,566 34, 965 34, 965 36,37 i., 736 Ethylic dimethylic orthofor- mate JJ JJ JJ Monethylglycerin Tetraethylic orthocarbonate Phenylene oxide ^ jj .... .... Phenoic acid .... CH(OEt)(OMe) 2 )J CH 2 (OEt).CH(OH).CH,,.OH Et 4 CO 4 c 6 H 4 :o u C 5 H 12 O 3 j C 5 H 20 4 C 6 H 4 JJ CJLCX 115-120 116-120 225-230 158-160 Liquid Liquid 103 156 abt. 60 Pinner jj Reboul Bassett Marcker Limpricht B., 16, 356 B., 16, 1647 As., 1, 239 17, 198 A., 124, 249 44, 731 44, 1089 ii., 883 iv., 237 v., 161 44, 664 iv., 388 Collinic acid .... .... .... C H 3 COOH 100 + Frohde J. p., 80, 344 i., 1083 Quinone CM. "O, 1.4 100 Woskresensky A., 37, 168 v., 27 111 Ador and v. Meyer B, 4, 9 24, 379 jj JJ JJ JJ J jj >j .... 115 115 115-2 JJ >! JJ JJ Hesse JJ A., 159, 1 A., 14, 299 jj 24, 826 v., 27 jj Umbelliferone Raffinose Ethylene tetracarboxylic acic Phenol JJ J (CQOH) 2 C:C(COOH) 2 C H OH jj C 6 H 4 7 (?) C 6 H 4 8 C H O 328 p. d. 178 180 115-7 240 80 s. t. 57 jj Loiseau Conrad Gladstone and Tribe jj C. R., 82, 1058 B., 13, 2161 41, 6 >j v., 939 30, 398 40, 169 180 J Williams C. C. [1873], 167 27, 583 188 190(762 Landolt G. J. C., 1864 183'3 184'1 Adrienz G. J. C., 1873 180 Ramsay 39, 64 181 '5 Dale & Schorlemmer 35, 148 181'5 Schorlemmer 28, 209 182 Allen An. [1878], 319 36, 182 183 Lincke J. p. [2], 8, 43 27, 373 184 Scrugham 7, 232 iv., 389 184 Jones 33, 181 184 42 Dale & Schorlemmei 26, 441 186 Ramsay 36, 469 jj 187 188 34 35 Laurent A. C [3], 3, 195 iv., 389 181 182 Sarauw B 14 2444 42, 507 (from tar) .... -^. (fromparoxybenzoicacid (from salicylic acid).. (from oxybenzoic acid j, .... .... .... . i) .... .... .... J) J1 JJ Jt 1J JJ jj jj n ) j) 51 182-1 182-1 182-1 182 '3-182-5 183 38-40 38^0 39 39-5 41 37-5 36 Ladenburg jj jj jj Schiff Gnebe Zotta B., 7 1687 jj jj jj A., 223, 247 ; G. I., 14, 181 A., 174, 87 46, 1089 180 180 - 5 AO Al TTa.mbp.rg B., 4, 751 186187 Church 16, 76 M 187 s 18 Duclos A., 109, 135 M 187-6 188'1 Kopp A. JJ 1J H (747) 197-5 Runge P. A., 32, 308 COMPOUNDS CONTAINING THREE ELEMENTS. 161 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Phenol For tension table C.H.O See Part III (hydrate) Resorcinol C 6 H 5 .OH+nH,O (C 6 H 5 .OH) 2 .H 2 C 6 H 4 .(OH) 2 =1.3 )J C fi H 6 O 2 266-267 37 16 98-99 Alexejeff Calvert Kopp B. S. [2], 35, 379 18,66 B., 6, 447 40, 723 iv., 389 26, 900 ; via., 1040 271 99 Hlasiwetz & Barth A., 130, 356 iv., 215 99 Petersen B., 6, 378 26, 1133 102 Wurster & N Siting B., 7, 906 270-275 104 Oppenheim & Vogt As. 6, 376 270 Troost G. J. C., 1879 105 Ador and Meyer B., 4, 8 24, 378 105 Cross and Bevan 41, 112 109 Barth and Schredei G. J. C., 1879 110 Schiff A, 223, 247 46, 1089 Pyrocatechol .. .... .... JJ JJ JI 1.2 .... 110 110 118 100 u. c. Fittig and Mager Bantlin Calderon Lautemann B., 7, 1178; G. I., 4, 305 G. J. C., 1878 C. R, 84, 779 A., 120, 311 28, 147; 29, 235 32, 474 100 Miller 41, 399 245 101-102 Beckett and Wright 29, 285, 286 102 Fittig and Remsen A., 159, 129 24,938 102-102-5 Beckett and Wright 29, 303 102-103 Miller 41, 407 " 102 Etti B., 11, 1881 S45-5 104 Fittig and Mager G. J. C., 1875 * 240-245 105 Arata A. S. C. A., 1878 34, 986 240-245 111 Buchner J. p., 96, 1 iv., 316 111-112 A., 159, 129, 24, 938 111-112 Eissfeldt iv., 316 112 Petersen B., 6, 368. , 26, 1133 112 Tiemann B., 7, 6i8, 29, 235 110-115 iv., 316 116 Zwenger A., 37, 327 240-250 Wagner J. p., 52,. 450 1.4 " 160 Prunier A. C. [5], 15, 5 36,240 165 Korner G. J. C., 1866 165 Wichelhaus B., 5, 250 169 TTerrmaTiii G. J. C., 1877 169 Miller 41,405 " 168 169 u c. Hesse A., 200, 232 38, 317 " 169 Hlasiwetz B., 8, 684 28,1191;29,235 " 169 u c A., 177, 339 29, 79 .... 169 u. c. 169 Habermann A., 180, 343 A., 175, 62. 30,83 28, 572 171 Bernheimer M. C., 1, 456 42, 232 " 72 1 71 u r B., 5, 1027 26, 388 i> =177-1- 177-5 c. 177-5 178 A., 110,358; 114, 301 B., 6, 378 iii., 213 26, 1133 Pyrocinchonic anhydride 5) Me.C : CMe.CO.O.CO i 1 M C H ('OH') 121 n 212-215 u. c. 223 91ft 90 94-97 94-2; 95-1 a. s. 06 1 1 z Weidel and Schmidt Hoogewerff and v. Dorp Weidel and Brix Roser B., 12, 1151 B., 13, 63 M. C., 3, 608 B., 15, 293, 1319 An 36, 947 38, 406 42,1304 42, 1114 iv. , 758 " 115 G. J. C., 1871 " 118 Tevthnnks B.. 11. 1882 36, 160 162 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Hydroxyquinol 11 , Querciglucinol Phenolglucinol CEnoglucinol Phloroglucinol ., Dimethylic acetylene dicar- boxylate Methylic aconate i .... Muooiiic acid Acetomalic anhydride Acid from dehydromucic acid ? Acid e 6 H 3 (OH) 3 =1.2.4 > u 3C 6 H 6 O 3 .2H 2 O C 6 H 6 O 3 .2H 2 O C 6 H 3 (OH) 3 =1.3.5 )> i) COOMe.C i C.COOMe CO.O.CH : C.CH.COOMe i i C 9 H 6 3 IT JJ )) )> ) )J C,H 6 4 5> 1) C,H 6 5 J> C 6 H 6 6 )1 )) )) C 6 H 8 C 6 H 8 2 )I ft )J 1) C 6 H S 3 (?) )1 )> > C,H^O, si ; i) j )i )> ? 195-198 160-162 (14) 172 119-124 210 c. Begins 225p.d. abt. 228 221 (755) 130 282-284 s.b. 206 212 imc. 205 c. 250 255 u.c. (757) 131 131-5 131-5 132-133 174 200-5 208-5 206 209 220 85 85 100-125 53-54 146 173 139-141 160 186-187 184 d. 109-110 Solid 10-12 93-96 133-134 134-5 Liquid 170 d. 75 Liquid abt 85 126-6 127 127-127-5 Solid 133 68-70 b. 90 105-107 102 Liquid 107 124-5 m 103 155 d. Etti Stenhouse Stenhouse and Groves Barth and Schredei Ganteer D Barth and Schreder Tiemann and Will Hlasiwetz Bandrowski Meilly i) Limpricht Anschutz Seelig i Hunaus Conrad & Guthzeit Kallen Kekul6 Geisler Mulck Fittigand Barriuger Hofmann j) Herrmann Kobiquet Weidel Wedel Duisberg )3 Kommenos Fehling Bredt Lourengo Anschiitz Henry Conrad and Bischoff Perkin B., 11, 1882 A., 179, 236 M. C., 4, 176 B. S. [2], 33, 583 B. S. [2], 33, 585 B. S. [2], 33, 584 B., 12, 419 B., 14, 954 A., 96, 118 B., 15, 2694 B., 6, 242 A., 171, 163 A., 165, 274 B., 14, 2791 B., 12, 1088 B., 9, 1751 A. C. J., 4, 39 ; C. E., 94, 455 B., 17; 1187 B., 6, 1507 A., 162, 105 A., 167, 250 A., 208, 49 A., 180, 56 A., 161, 307 12,46 12,44 A., 211, 324 A., 211, 322 .7. p. [3], 10, 167, 241 B., 12, 2002 A., 219, 71 B., 16, 134 B., 15, 1383 A., 218, 145 A., 49, 192 A., 208, 63 A., 115,361 ; J. p. [2], 20, 207 J. E., 11, 288 B., 12, 2282 B., 12, 2283 A., 167, 319 B., 7, 755 B., 13, 598 B., 16, 1787 36, 160 28, 705 44, 987 40, 272 j jj 36, 633 36,633; iv.,495 44, 313 vii., 22 ; 26, 875 27, 788 vii., 827; 26, 623 42,831 36, 784 i., 54 46, 992 27, 352 vii., 35 ; 25, 617 42,42 29, 924 vii., 1091 ; 25, 486, 487 v., 352 v., 352 42, 713 i., 148 38, 268 46, 835 42, 1192 46, 422 v., 463 42,34 ii.,582 ; v.,4(!4 iii., 464 25, 978 38, 628 44, 1084 CH(OAc).CH 2 .CO.O.CO CH(COOH) : C(COOH).CH 2 (COOH) C^CC-OH), ) CH(COOH).CH 2 .C(COOH) 2 Aconitic acid Trimethylene tricarboxylic acid Helenin 3Q 2 H 4 O 2H 2 O CH 2 : CH.COO.CHs.CH:CH 2 From pyroterebic acid CH 2 .CH.CH(COOH)CH: CH 2 j identical ; see C 12 H 16 6 ii CHMe:(CH 2 .CO) 2 :0 C 4 H 3 Et0 3 (?) CO-tCH.^COO.tCH^.p From aldehyde Allylic acrylate Terelactone ?-acid Sorbic acid Parasorbic acid From diethylic succinosucei- nate Tetrahydroquinone Aloisol Oxysorbic acid Ethylsuccinosuccinate Ethylic hydroxytetrolate .... Ethylidene diace tic anhydride Ethylsuccinic anhydride (?).... Hydroxyglutariclactone Ethylene succinate Dimethylic fumarate j> Dimethylic maleate Lactide .... .... C 3 H 2 (COOMe) 2 J CH(COOMe) 2 : CH(COOMe) 2 CHMe.CO.O.CHMe.CO.O L r j j) CH 2 : CH.CH 2 .CH(COOH) 2 CH 2 :(CH 2 ) 2 :c(cooH) s Allylmalonic acid Tetramethylene dicarboxylic acid COMPOUNDS CONTAINING THREE ELEMENTS. 163 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Homoitaconic acid CH(COOH).CH 2 . C 6 H 8 4 .... 170-171 Krestownikoff B. S. [2], 35, 558 40,801 CH(COOH).CH 2 | 5) Hydroinuconic acid ,, -Methylethenyltricarboxylic acid j Tricarballylic acid ,, j) ,, Glycuronic anhydride 1 C 4 H (COOH) 2 J> CHMe(COOH).CH(COOH) 2 COOH.CH(CH 2 .COOH) 2 )J 1 ) n C(OH)(CH 2 .CQOH),(COOH JI ) C 6 H"o, I) ?J )J ) J> )> J) C,HO, .... 170-171 195 195 142 d. 146 158 158 158 158-159 158-160 160-6 166 165-168 167 146 147 Markownikoff and Krestownikoff Bode Limpricht Bischoff&Guthzeit Bischoff u Simpson Miehle Glaus Claus and Lischke Lippmann ii Weyr Spiegel Grimaux and Adacu B., 12, 1489 A., 132, 98 A., 165, 262 B., 14, 615 B., 15, 1109 ; A. 214, 53 B., 13, 2161 18, 331 A., 190, 322 B., 5, 361 B., 14, 1090 B., 11, 707 B., 12, 1650 11 B., 15, 1966 C K 90 1252 38, 238 v., 1093 vii., 827 42, 1188; 44, 45 42, 1188 v., 880 34,491 25, 685 38, 802 153 154 G J C 1866 C 6 H S O 7 + H.,O 100 Allyloxide (C 3 H 5 ) 2 O CH, n O 82 A 102 290 i 142 85 87 A C [3] 43 257 i 142 Metacetone .... 83-84 Bendikt A , 162 303 vii., 1107 84 Fremy A., 15 281 jj .... .... ... .... > 84 84-86 Gottlieb Zeidler A., 52, 127 A., 187 30 iii., 932 32, 437 Dumasin 120 P A 44 494 120-125 Fittie A., 110 21 i., 31 ; ii., 351 j 5 ...... .... M 120-125 120 130 Zeidler TTfiint.x A., 187, 30 P A. 68 279 32, 437 Allylacetone .... PR PO f'TT PTT PFT'PTT " )) 128130 Zeidler A., 187, 35 Mesityl oxide (?) j> 1 1) ) 130 120 125-135 Liquid Liquid ii Kane Breuer and Zinck6 B., 8, 1035 P. A., 44, 475 B., 13, 638 *9, ODO 38, 645 MM J) 128-130 Louise C. K., 95, 602 j \ " **** M 130 Liquid Baeyer A., 140, 297 vi., ;& .... 131 c. Fittig ., 110, J4 5, Ethylisocrotonic aldehyde .... Methylethylacrole'in.... 11 CoHMeEtCHO 1) )J JJ ) 131 131-132 137 137-3 136-7 .... Benedikt Zeidler Lieben and Zeisel A., 162, 303 A., 187, 30 B., 12, 571 M. C., 4, 10 M. C., 3, 693 vii., 1107 32, 437 36, 615 Resin from larch agaric Ethylvinylacetate 5, .... Propylic acrylate Ethylic-/J-crotonate Ethylic-a-crotonate .... 11 11 11 11 11 11 Acid from croton oil 11 11 Hydrosorbic acid 11 !! 11 11 From broiucaproic acid OH, : CH.COOPr CH 2 : CH.CH 2 .COOEt Me.CH : CH.COOEt n n )> CH 2 .-CH.CHEt.COOH ii C 5 H 9 .COOH (0 (C,H M OX C 6 H I0 2 i) ii ii >i i> i> >i :i ! I> II II II 110-5-111 111 122-9 136 c. 38-8;326c.t. 139-5-141-5 138-140 c. 142-143 204 208 201 ; 204-205 c. 208-5 208-210 20 90 1. 18 Liquid n. f. 13 10 Masing Nevol6 Lieben Weger Geuther Pawlewski Bruhl Perkin Kramer & Grodzki Berendes Fittig & Barringer Mulck Hjelt 11 A. P. [3], 6, 111 C. E., 85, 514 B. 8., 12, 282 A., 221, 61 J. p. [2], 3, 431 B., 16, 2633 B., 14, 2797 B., 11, 1359 B., 10, 835 A., 191, 121 A., 161, 309 A., 180, 45 B., 15, 618 1! v., 981 29, 612 32, 867 32, 868 46, 11 24, 815 46, 252 42, 827 45, 536 32, 593 vii., 1092 ; 25, 486 29, 924 42, 946 J! T 2 164 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Pyroterebic acid CHMe 2 .CH : CH.COOH C 6 H 10 2 L-15 Geisler A., 208, 37 42,41 11 11 11 )) a. 200 ... Rabourdin A., 52, 395 JJ 207 c. 5-6 Mulck A., 180, 45 29, 924 210 Liquid Chautard J., 8, 652 iv., 776 )) 210 Carleton Williams B., 6, 1095 27, 71 11 11 124-127 (26) Keener & Menozzi G. I., 13, 351 46, 425 Methylethylacrylic acid CHEtlCMe.COOH JJ 213 c. (750) 24-4 Lieben and Zeisel M. C., 4, 47 44,571 Hexylenic acid .... ?) 39 Pinner B., 10, 1054 32, 587 a-Ethylcrotonic acid CHj.CH : CEtCOOH 39-40 Waldschmidt B., 8, 1037 29, 369 )) 39-5 Frankland & Dupp 18, 133 vi., 600 .... 41-5 Geuther B. S. [2], 10, 34 Damaluric acid physical isomers JI .... 39-40 Werner Z. C. [2], 4, 413 vi., 541 n 11 * 11 11 I) 50-53 11 11 a-Methylvalerolactone CH 2 .CHMe.COO.CHMe )) 206 1. -17 Gottstein A., 216, 30 44, 454 /3- (impure) CHMe.CH 2 .COO.CHMe i i 1) 205-212 ,, A., 216, 35 Isocaprolactone CH 2 .CH 2 .COO.CMe 2 J) 206 .... Fittig A., 200, 60 38, 378 11 ) S07 7-8 11 A., 208, 111 42, 33 )J 206-207 .... Bredt B., 13, 749 Caprolactone (normal) CH 2 .CH2.COO.CHEt 5) 220 Liquid Fittig B., 13, 955 38, 799 8- CH 2 .CH 3 .CH 2 .COO.CHMe ) 2SO 230-231 17-19 11 Wolff A., 208, 67, 111 A., 216, 134 42,33 44, 455 i i )> 207-214 Hjelt B., 15, 617 ?-Aldehyde .... " abt. 220 Riban C. R., 75, 98 25, 810 Saccharone Me>C 2 H 4 .CH.O.CO.CH 2 11 203-204 u. c. Liquid Scheibler B., 13, 2217 40, 149 Acropinacone ... 11 160-180 Liquid Linnemann As., 3, 271 vi., 56 Ethylic epihydrincarboxylate O.CH n .CH.CH 2 .COOEt i :j n 145-150 Kelly B., 11, 2226 36, 306 Aldol monacetate CH 8 .CH(OAc).CH 2 .CHO 11 100-110 (20) Liquid Wurtz C. R., 74, 1361 25,809;vii., 39 Propionic anhydride , (CH 3 .CH 2 .CO) 2 11 168-160 Liquid Perkin J. [1875], 520 28,11 , 11 165 Limpricht & Uslar A., 94, 322 11 164-166 Linnemann J., 21, 433 Glyceric ether C* TT I f\ I f~l TT ^3^6 '-'3 C 3 l5 11 169-171 Liquid Silva C. R., 93, 418 40, 1123 11 170-172 Gegerfelt B., 4, 920 25,134;vii.,565 11 11 > 11 169-173 Linnemann &Zotta As., 8, 258 25, 134 ; vii., 565 n 169-172 .... Tollens B., 5, 68 25, 398 11 171-172 Liquid Zotta A., 174, 90 28, 246 11 11 11 11 170-173 .... Tollens and Loe B., 14, 1946 42,31 Methylic methylacetoacetate CHMeAc.COOMe 11 177-4 c. .... Brandes J. Z., 3, 25 vi., 829 Ethylic acetoacetate CHjAc-COOEt 11 179-182 .... Mixter B., 7, 499 27, 785 11 11 .... 11 180-181 Oppenheim and B., 9, 318 30,69 Precht 11 n 11 180-6-181-2 .... Briihl G. J. C., 1880 (754) 11 n - 11 180-6 Liquid Geuther J. [1865], 304 vi., 16 11 11 " .* 11 11 180-182 c. .... Perkin 45, 493 (760) ; 152-5-153-3 c. (330) Methylic /3-acetopropionate.... CHjAc-CH^COOMe 11 191-191-5 .... Grote, Kehrer, and A., 206, 220 40, 410 (743) Tollens /3-aceto-butyric acid CH 3 .CHAc.CH 2 .COOH n 241-242 Bischoff A., 20P, 332 40, 413 n-methyl /3-acetopropionic CH2Ac.CHMe.COOH 11 247-248 Liquid n A., 206, 322 40, 412 acid y-acetobutyric acid CH 2 Ac.CH 2 .CH 2 .COOH 11 274-275 13 Wolff A., 216, 129 44, 455 + H..O 11 36 11 11 #-ethxycrotonic acid n 137 148 J. [1864], 377 vi., 58 " 11 .... .rt.1 ppc 148 Ballo B., 14, 332 " 148 B., 10, 1286 34, 4 M 148-149 W^eidel and Brix M. C., 3, 603 42, 1305 Jl 148-149 Motte B., 12, 1572 38, 36 .... +*H 2 D I 140 Wirz A., 104, 257 i., 58 Mannitol anhydride .... C 6 H 8 2 (OH) 2 74(760)p.d.; 87 Fanconnier C. R., 95, 991 ; 44, 306 ; 46, 176 (30) B.C. [1883], 789 573 (?) acid .... " 143;147-148 Ladenburg B., 15, 1028 166 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethoxysuccinic acid COOH.CH 2 .CH(OEt).COOH C 6 H 10 5 .... 86 Purdie .... 39, 348 .... 86 39, 350 Ethylenesuecinic acid HO.(CH 2 ) 2 .O.CO(CH 2 )j. .... b. 100 Lourengo A., 115, 359 ii., 582 ; v., 464 COOH Ethylic diglycollate COOH.CH 2 .O.CH 2 .COOEt B 240 Liquid Heintz A., 144, 95 vi., 642 Pyruvin CoHJOHUOCoH O ) 242 d. 78 Schla^denliiiuffen B. S. [2], 17, 301 25, 1000 Maltic acid vy 3-^5\ v -^ J - t- /2\ 3~^3 2/ " 95 Cuisnier and K i h in i B. C. [1882], 703 44, 42 Inulin ... .... U a. 100 Brjiconnot iii., 278 J) Inuloid 130-135 PODD Z. C. [2], 7, 88 24, 348 Saccharin From milk sugar 11 1) 142; sf. 135, Kiliani B., 15, 701, 295, 3"; 46, 283 141-142 a.f 16, 2625 CH 2 OH(CH.OH) 2 . 160-161 Scheibler B., 13, 2212 40, 149 CH.CH,.CO.CO 11 i i Levulan ( ) .... 250 Lippmann B., 14, 1512 40, 888 Dimethylic dextrotartrate ( + ) C 2 H 2 (OH) 2 (COOMe) 2 C 6 H I0 6 163 (23) ; 48 Anschlitz & Pictet B., 13, 1176, 1538 38, 876 280 (760) Dimethylicracemate(inactive] 11 J? 282 (760) 85 11 11 B., 13, 1178 11 Ethyltartaric acid C 4 H 8 O 2 (COOH) 2 .... 90 .... A., 22, 238; J.E., 7, 150 Isodiglycolethylenic acid .... 11 .... b. 100 Barth & Hlasiwetz A., 122, 96 iii., 414 Succinopropionic acid .... .- 139 Hermann A., 211, 306 42, 713 Hydrocitric acid .... C 6 H 10 7 100 Kammerer Z. C. [2], 2, 709 vi., 473 Isosaccharic acid .... C 6 H 10 8 .... 185 Tiemann B., 17, 241 46, 725 Isodulcitic acid .... C 6 H 10 9 .... 100 Malin A., 145, 197 vi., 759 Gummic acid .... CTT O -IK(\J ii., 956 .... s^MiMo ... 1OVJ (1. ... Ethylisocrotyl cxide CMe 2 : CH.OEt C 6 H 12 92-94 .... Butlerow C. C. [1871], 89 24, 215 11 92-94 .... Z. C. [2], 6, 524 vii., 401 Hexylenepseudoxide .... 93 .... .... Z. C. [1871], 36 Tetramethylethylene oxide ... CMe 2 CMe 2 .O 95-96 Eltekoff J. B. [1882], 355 44,567 1 | Methylpropylethylene oxide CHPr CHMe.O 11 109-110 H B., 16, 398 11 i i Hexylene oxide (normal) .... c 6 H 12 :o 11 115 .... J. [1864], 516 vi., 700 Diisopropylene oxide .... 11 185 .... .... B. S., 19, 147 Diallyl monohydrate C 6 H 10 .H 2 O 11 92-95 Liquid Wurtz A. C. [4], 3, 172 vi., 93 11 ,, CH 3 .CH(OH).(CH 2 ) 2 .CH:CH 2 133-139 .... Crow 33, 53 C 6 H n OH+H 2 130-140 Liquid Wurtz A. C. [4], 3, 172 vi., 93 u 11 ,, 140 Liquid 11 Dimethylallyl carbinol (CH 2 :CH.CH 2 )CMe 2 .OH 11 119 .. M. and A. Saytzeff B., 9, 33 29, 694 ii ii 11 119-5 c. 11 )! A., 185, 151 32, 298 11 11 (hydrate) > 116-117 .... 11 11 Dimethylisoallyl carbinol .... .... H 110-115 .... J. [1872], 349 Hexylene alcohol 11 137 Liquid Destrem B., 16, 228 Methylpropylacetic aldehyde CHMePr'.CHO B 116 M. C., 4, 24, 40 Isobutylacetic aldehyde CHMe 2 .CH 2 .CH 2 .CHO 121 (743) .... Eossi A., 133, 179 vi., 395 Hexyl aldehyde (ft) C 6 H n .CHO 127 (761-2) Wanklyn and Er- 16, 307, 522 iii., 153 lenmeyer 11 CH 3 .(CH 2 ) 4 .CHO 127-9 (737-6) Liquid Lieben & Janecek A., 187, 130 32, 880 Methylpseudobutyl ketone .... CMe 3 .CO.Me 105-5-106-5 .... Butlerow B., 7, 729 27, 1081 11 11 H 106 A., 174, 127 11 .... 11 11 105 Liquid Fittig A., 114, 57 iv., 647 11 .... 11 11 105-107 .... Kaschirski C. C. [1881], 278 42,37 11 11 11 105-106 Liquid Barbaglia & Gucci B., 13, 1572 Methyl 0-butyl ketone CHMeEt.CO.Me 11 118 Liquid Wislicenus A., 219, 307 44, 966 Methylisobutyl ketone CHMej.CHj.CO.Me 11 114 .... Frankland & Duppa J., 20, 395 11 11 11 114 Schmidt B. S., 18, 321 11 i, 11 120 Liquid Williamson A., 81, 81 v., 974 Methylbutyl ketone CH 3 .CO.CH 2 .CH 2 .CH 2 Me 124-126 .... Morgan 28, 303 11 ii 127 .... Wanklyn and Er- A., 135, 144 vi., 768 lenmeyer " " n 128 .... Friedel A., 108, 125 iii., 1002 COMPOUNDS CONTAINING THREE ELEMENTS. 167 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylbutyl ketone CH3.CO.CH2.CH2.CH.jMe C 6 H 12 126-128 .... Schorlemmer P. T. [1872], 111 vii., 645 ; 25, 1085 Ethylisopropyl ketoue P/.CO.Et 11 115 .... Butlerow A., 144, 1 vi., 969 11 117-119 Pawlow B., 9, 1311 31, 58 Ethylpropyl ketone Pr".CO.Et 122-124 Liquid Coninck C. R., 82, 92 29, 694 ,i n .... 122-124 Volker B., 8, 1019 11 .... n 122-124 .... Oechsner B. S. [2], 24, 99 30,67 ,1 11 .... 11 122-125 Liquid Butlerow B. S. [2], 5, 17 vii., 1022 'i .... 122-125 Popoff A., 161, 289 i, 11 121-124 Morgan 28, 302 Hexylene ketone 125 (753) Liquid Henry C. R., 97, 260 46,34 ? ketone 123-125 Destrem B., 16, 228 Action of CaO on glycerol .... .... 160 .... Tawildaroff B., 12, 1487 38, 235 1 180-185 Fittig J., 13, 319 ? .... 244-245 .... Renesse A, 166, 80 26, 642 ? (C 6 H 12 0). 205 .... M. C., 4, 25 From wax of ficus gumrniflua .... 11 345-354 62 Kessel B,, 11, 2114 36, 262 Diacetonic alcohol CH.Ac.CMe 2 .OH C 6 H 12 O 2 163-5-164-5 Liquid Heintz A, 178, 342 29, 365 Diisoallyl alcohol CH 2 .CHOH.(CH 2 ) 2 . 218-225,p.d. Liquid Hiibner & Miiller A., 159, 186, 384 vii., 48 ; 24, CHOH.CH 2 906 11 11 11 11 11 220-230 .... Glaus and Stein B., 10, 558 Amylic formate H.COO(C 5 H n ) 11 112 Kopp A., 96 ,1 11 n 114 Delffs J., 7, 26 11 11 11 )> 116 Liquid Kopp A, 55, 183 ii., 693 ,i 11 123-3 Elsasser A., 218, 302 44,967 .... (iso) J) 121-8; Pawlewski B., 15, 2463 44, 276 304-6 c.t. Butylic acetate CH 3 .COO.(CH 2 ) 3 Me 125-1 (740) Liquid Lieben and Rossi A, 158, 168 24, 521 ; vii., 216 ,i I. 11 J 124-36 .... Linnemann A., 161, 193 25, 396 ; vii., 203, 216 11 11 5> 123-7 ; .... Pawlewski B., 15, 2463 44, 276 305-9 c.t. Iso-butylic acetate CH 3 .COO.CH s .CHMe, ) 117-5 Chapman & Smith 22, 160 11 11 11 M 116-3 Elsasser A., 218, 302 44,967 11 11 ji 5J 114-6; .... Pawlewski B., 15, 2463 44,276 295-8 c.t. 11 11 11 117 c. .... Perkin 45, 495 i, 11 i. n 116-5 (764) .... Pierre and Puchot C. R., 75, 1594 ; 26, 260 A. C., 22, 322 11 n " 11 114 Liquid Wurtz A., 93, 121 v., 732 11 11 11 113-115(736) .... Linnemann A., 162, 12 25, 475 11 n " 11 113 .... Hodgkinson 37, 485 " 11 116-3 (760) Schumann G. J. C., 1881 11 11 11 11 111-113 Liquid Luynes J., 16, 501 v., 732 Butylic acetate CH 3 .COO.CHMeEt 11 111-112-5 Ressel A., 175, 44 28, 554 i, 11 n 11 110-113 Saytzeff J. p., 3, 88; 6, 327 vii., 219 ; 24, 526 11 11 i' 11 111 .... Lieben J., 21, 443 11 11 11 11 abt. 110 Wurtz Z. C. [2], 5, 407 vi., 377 11 11 CH 3 .COO.CMe 3 11 93-96 .... Butlerow A., 144, 7 vi., 375 Propylic propionate CH 3 .CH 2 .COO.Pr 11 124-3 (760) Liquid Pierre and Puchot J. Ph. [4], 13, 369 vi., 964; 24, 903 ,i 11 11 124-75 .... 11 n C. R., 75, 1594 26, 260 11 11 i) n 123-5-125 .... 11 n A. C. [4], 22, 293 11 11 " 11 122-44 Linnemann A., 161, 31 ; 162, vii., 203, 1013; 39 25, 235 11 11 11 122-2 (760) .... Schumann G. J. C., 1881 11 i> 11 122-2 .... Elsasser A., 218, 302 44, 967 11 11 11 122-3; Pawlewski B., 15, 2463 44,276 304-8 c.t. 11 ji n 122-123 c. ... Perkin .... 45, 497 168 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts Diet. & J. Ch. Soc. Propylic propionate CHyCH., COO.Pr C 6 H 12 2 118-120 .... Chancel C. R, 68 vi., 964 Isopropylic propionate CH 3 .CH 2 .COOPr0 109-5-110-Sc. .... Perkin .... 48, 498 ,> >! 109-111 .... M. C., 2, 688 Ethylic butyrate CH 3 .CH 2 .CH 2 COOEt 121-09 c. Linnemann A., 160, 210 tj 121-07 c. A., 162, 39 vii., 203 n 121-07 c. .... Linnemann & Zotta A., 161, 178 vii., 225 ; 25, 403 121-05 c. .... i. n !) .... 121-7; Pawlewski B., 15, 2463 44,276 304-3 c.t. 119-9 .... Elsasser A., 218, 302 44, 967 114-1-121-1 .... Zander A., 214, 185 121-121-5 c. Perkin .... 45, 499 119 (746-5) Liquid Pierre C. R, 27, 213 ; i., 695 P. A., 76, 458 n n jj 119 Frankland& Duppa J., 18, 306 vi., 378 iso-butyrate CHMe^COOEt 113 (760) Pierre and Puchot A. C. [4], 28, 366 vii., 226 113 Delffs J., 7, 26 n 114-8 (760) Kopp P. A., 72 .... j) 110-1 (760) Schumann G. J. C., 1881 n 110 .... Pelouze A., 96 n 110 .... Lerch A., 96 n 110 Liquid Morkownikoff A., 138, 361 vi., 378 >T "* 110-1 .... Elsasser A., 218, 302 44, 967 108-6 ; .... Pawlewski B., 15, 2463 44, 276 290-4 c. t. 110-110-6 c. Perkin .... 45, 500 Methylic iaovalerate CHMe 2 .CH 2 .COOMe n 114-116 .... .... C. R, 94, 1652 ,, n 117 (763-8) Liquid Schmidt and Sacht- A., 193, 101 36, 139 leben n n 117-5 .... Pierre and Puchot C. R, 76, 1332 vii., 62; 26, 1017 117-25 (755) .... A. C. [4], 20, 234 vii., 1200 C 4 H,.COOMe 116-2 (760) Liquid Kopp P. A., 72; A., v., 979 64, 219 Methylic valerate 114-115 A., 96 116-7(760) Schumann G. J. C., 1881 116-7 .... Elsasser A., 218, 302 44,967 Methylic trimethacetate Me 3 C.COOMe 100-102 1. 20 Butlerow A., 173, 372 28, 250 n 100-102 .... B., 7, 728 27, 1084 Caproic acid CH 3 (CH 2 ) 4 .COOH 202-209 Fehling A., 53, 406 202-209 .... Gmelin 11, 414 i., 743 204-6-205'6 Lieben and Janecek A., 187, 126 32, 879 (759) 205 (746) Lieben A., 170, 89 27, 249 " jj .... a 204-5-205 .... Franchimont and B., 4, 825 vii., 646 ; 25, 61 (761-17 r.) Zinck6 204-5-205 .... Lieben and Eossi G. I., 1,314; A., 24, 1034; vi., (738-5) 159, 75 1137; vii., 250 204-206 (755) Schorlemmer 27, 1029 " jj .... *"* .... .... n 204-5-205 .... Liebeu A., 170, 89 27, 249 (738-5) 204-5-205 Lieben and Janecek A., 187, 126 32, 879 (738-5) (761-%) 203-207 Perkiu 43, 58 " 2 Freund J. p. [3], 232 38, 377 Jr L J" 2 Baeyer B., 10, 1287 34, 4 J' " 202-204 Cahours and De- C. R., 89, 331 36, 1036 " maray 11 goo-son abt. 10 Ziucke A., 152, 20 vi., 395 COMPOUNDS CONTAINING THREE ELEMENTS. 169 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. (/aproic acid .... CH 3 (CH 2 ) 4 .COOH M j ) C 5 H U .COOH M > CHMej.CH3.CH2.COOH 1) M M CHMePr-.COOH J) )) CHEtj.COOH ) CMejEt.COOH CHMe.O.CHMe.O.CHMeO i i C.H 13 2 V > n n > u u 51 ) C 6 H 12 O 3 )> n n M J) 5 1) J) )1 ) ?> ) )) It J) JJ )) 1) )1 Ji ) 204-205 202-205 200-205 200-205 201-204 198 198 198 199 199-199-5 c. 198-6-199-8 199-7 195 (746) 193-194 198 (748 r.) 193-194 194-195 190 (756-5 r.) 195-197 187-198 187 186 103-5-1 03'7c. 124 124 124 123-2-123-5 (744) 123-124 123-125 125 125 143-6 c. a. 150 152 155 158'4 147 178 135-5 166 -168 145-155 150-155 151 c. 167 abt. 220 213-220 1-5 s. 9 1. -18 Liquid Liquid Liquid Liquid Liquid Liquid Liquid S.14 10-12 4 10-5 10-5 12 Liquid s. w. m. 120 s. w. m. 100 .w.m.112-115 Fittig Fehling Grillone Schorlemmer Brazier & Gossleth Wurtz Landolt Mulck Rohn Lieben and Rossi Rossi Liebermann and Scheibler Saytzeff Kelbe and Warth Fittig Saytzeff Schnapp Sticht Wischnegradsky > Perkin Geuther & Cartmell Kekule and Zincke Geuther Bruhl Lieben Perkin Weidenbrusch Kroamer & Pinner Fehling Liebig Kekul6 and Zincke Rose Henry Folsing Norton&Tcherniak Schreiner jj j Silva Duvillier Schreiner Louren^o Pinner G. J. C., 1879 ' } OOj A, 165, 127 P. T. [1872], 111 j J., 3, 398 Gm., 11, 414 J., 10, 351 P. A., 117, 353 A., 180, 57 A., 190, 316 G. I., 1, 314 A, 133, 176 B., 16, 1823 B., 11, 512 B., 15, 308 A., 200, 24 B., 11, 511 B., 10, 1954 J., 21, 522 B., 7, 730 B., 8, 541 A, 112, 16 A., 162, 125 ; B., 3,470 Z. C., 1865, 32 A., 203, 26, 44 As., 1, 114 A., 66, 155 B., 4, 788 A., 27, 319 A., 14, 141, 36, 376 B., 3, 471 A., 205, 245 B., 4, 707 B., 17, 486 C. R., 87, 30 B., 12, 179 ; A., 197, 8, 21 ; J. p. [2], 22, 353 B., 12, 179; A, 197, 8, 21 M B. S.[2], 17,97 C. R., 88, 598 A. C. [5], 17, 557 B., 12, 179 ; A., 136, 12 ; 188, 53 B., 12, 179 ; A., 197, 15,21 A., 114, 123 B., 12, 2058 vil., 251 ; 26, 375 25, 1085 vii., 645 i., 743 vt, 1137 29, 924 34, 486 24, 1034 ; vi., 1137; vil., 250 vi., 395 44, 1078 34, 566 38, 376 34, 566 34, 293 27, 1083 28, 878 45, 480 iv., 349; vii., 32 iv., 349 25, 13, 493, 560 vii., 33 iv., 349 43,89 i., 109 24, 1188 1., 109 40, 252 46, 897 34, 971 36, 522 ; 40, 88 36, 522 n >i vii., 1016 ; 26, 367 36, 523 36, 522 38,99 ,, ,, .... .... ... ,, .... ... Ethyldimethylacetic acid .... j Paraldehyde .... ) H V ) I ) M J1 CO(OMe)(OCH 2 .CHMe 2 ) CH 2 (OEt).COOEt ) 1) CH 2 (OMe).COOPr CH 2 (OPr).COOMe CH 3 .CH(OMe).COOEt CHj.CHOH.COOCHMe 2 CHj-CHjCHtOMe^COOMe Me a C(OH).COOEt CH 3 .CH 2 .CH(OH).COOEt HO.CH 2 .CH 2 .O(C 4 H 7 0) CH 3 .CH(OEt)CHj.COOH Metaldehyde ... ... .... Methylic isobutylic carbonate Ethylic ethylglycollate > Propylic methylglycollate .... Methylic propylglycollate .... Ethylio methyllactate Isopropylic lactate Methylic methoxybutyrate .... !) I> Ethylic hydroxyisobutyrate.... a-hydroxybutyrate .... Ethylene monobutyrate (3-Ethoxybutyric acid 170 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethoxyisobutyric acid Me^qOEtXCOOH C 6 H 12 3 180 (741) Liquid Hell & Waldbauer B., 10, 450 32, 313 Isobutylhydroxyacetic acid .... CHMe 2 .CH 2 .CH(OH).COOH H .... 56 Guthzeit A., 209, 238 42, 40 i) i) i> > .... 54-55 Ley B., 10, 231 82,310 Butylhydroxyacetic acid CH 3 . (CH 2 ) 3 .CH(OH).COOH .... 57 J )) > > n 60-62 .... J. B., 9, 139 ; 12, 367 Diethylhydroxyacetic acid .... CEt 2 (OH).COOH t .... 74 A., 135, 26 ; 200, 21 1! !> 74-5 .... A., 209, 235 >! JJ .... 80 Tiemann & Fried- B., 14, 1974 42, 56 lander 73 Waage A., 118, 295 iii., 575 )) 75 Strieker B., 10, 231 j) b. 100 Thudicum 14, 307 Hi., 578 Glycerinallylin C 3 H 6 (OH) 2 (OC 3 H 6 ) j> )) 225-240 Liquid Tollens A., 156, 149; B., vii., 51, 566 ; 5,69 25, 398 Butyracetic acid C 2 H 4 02.C 4 H 8 O 2 C.H.A 120-160 .... Limpricht & Usler A., 94, 321 i., 688 H 140 Dumas C. R., 25, 781 Dihydroxycaproic acid C 5 H 9 (OH) 2 .COOH >l .... 150-3-151-8 .... M.C.,4,48,66,83 Hexerinic acid Homologue of glyceric acid (?) ? .... 141 Fittig A., 200, 39 38, 376 245-255 Liquid Lourenco C. B,, 52, 359 ii., 895 ? (sugar?) or CuHjA j) abt. 105 * Liebermann & Giesel B., 16, 935 ? .... j) .... 240 J. [1863], 485 Isodulcite (hydrate) C 6 H 1S 0,+H 2 C,H 12 6 .... 105-1 10 d. Hlasiwetz and J. [1864], 564 v., 465 Pfaundler C,H,(OH). a. 220 Bottinger A., 202, 269 ^6 7^/5 > tu Prunier A. C. [5"), 15,5 36, 240 u J> 234 Bottinger L J' f B., 14, 1598 jj J 235 Dessaignes A., 81, 104 v., 6 Lactoglucose C 6 H 7 (OH) 6 c,H,A(?) .... 70 Fudakowski C. C. [1877], 6 32, 877 (dried at 100) J) n .... 132-135 B., 11, 1069 ; B. S. 34, 777; 36, [2], 30, 433 137 .... (air dried) H 70-71 H ! 95 Jungfleisch and C. R 93, 547 42, 158 Lefranc Paraglucose .... (hydrate) C 6 H 12 6 +H 2 )) 100 p. d. Jodin C. R, 53, 1252 v., 473 Galactose .... .... 115 Fudakowski C. C. [1877], 6 32, 877 .... (air dried) .... )) ) 118-120 B. S. [2], 30, 433; 36, 137 ; 34, B., 11, 1069 777 (dried at 100) .... .... 142-144 VI )> Dextroglucose .... .... 146 Schmidt I. D., Gottingen, ii., 858 1861 ; J. 14, 720 .... H .... 141-145 Behr C. N., 2, 179 42, 706 .... n 146 Miiller J. p. [2], 26, 78 42, 1275 (hydrate) C 6 H 12 6 +H 3 jj .... 86 Schmidt G. J. C., 1861 130 Eichter Tabellen [+] .... ) j) .... 160 G. H., 508 Pectin sugar .... 160 Scheibler B., 1, 108 vi., 903 abt. 210 Scherer A.,73,322;81, 37f iii., 275 .... .... ... .... n I 150-160 Vohl A., 99, 125 Dambose , 212 Girard C. R., 77, 995 27, 170 Borne odambose .... 220 ?i J) CLH-.O.+H.O abt. 74 Hesse A., 192, 173 34, 851 Parasjlucose . . ... v> 6-^- M -12 6 I "g jj 100 p. d. Jodin C. R, 53, 1252 ; i., 473 j> "* 55, 750 Dipropyloxide Pr 2 O C,H H 85-86 Chancel C. R., 68 vi., 964 H ? Zander A., 214, 163 ,, 82-86 Linnemann A., 161, 37 vii., 1013 ; 26, 235 Diisopropyloxide Pr3 2 ii 60-62 .... ? A, 126, 306 , } n ? .... Zander A., 214, 164 COMPOUNDS CONTAINING THREE ELEMENTS. J71 Name. Constitution. Formula Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Butyl ethyl oxide j )> Isobutyl ethyl oxide Tertiary butyl ethyloxide .. Isoamyl methyl oxide Hexyl alcohol ji jj .... .... ,, j, .... ,, ,, .... ,, ,, CH3.CH2.CH2.CH2.OEt ii CHMe 2 .CH 2 .O.Et Me 3 C.O.Et CHMe 2 .CH 2 .CH,,O.Me CH 3 .(CH 2 ) 4 .CH 2 OH IJ )) )) )J C 5 H U .CH S OH )> ) CHMe 2 .(CH 2 ) 2 .CH !1 OH CHMePr.CH 2 OH 1) CH 3 .(CH 2 ) 8 .CH(OH).CH 3 )J J> 1) ) J) H ij Pr.CH(OH).Et > CHMeEt.CH(OH).CH 3 CHMe 2 .CH 2 .CH(OHj.CH 3 CMe 3 .CH(OH).CH 3 ? ? ? ? econdary CMeEt 2 (OH) CMe 2 Pr(OH) n CMe2Prf(OH) J> J) > )xklation = acetic acid and acetone CH 3 .CH(OEt) 2 n C 6 H I4 ) PI H > n i j j i> j> i) i> j> jj H j> H ) j > > j) n jj i> j H j> n C C H 14 0, )> ) J) JJ 91-5-92-5 91-7 (747-7) 78-80 68-69 92 ^57-S c. 157-2 (740-8 157 156'6c.(752-5 150-155 150-153 150-152 150 152-153 151-156 150 148-154 146-6 146-9 140-142 140-141 136-140 136 132-137 138 137 (755-5) 135 135 abt 135 34-5-135-5 c. 134 108 120-5 134 Liquid s. 30 MM .liquid jiquid .liquid -liquid 35 b. -25 26 -liquid A. and M. Saytzefl Lieben and Kossi Wurtz Williamson Freutzel Liebeu and Janecel Grimshaw and Schorlemmer Franchimont and Xil.rki' Schorlemmer Cahours & Pelouse Rossi Cobig Buff Faget Saumann Schorlemmer H Morgan jieben Wanklyn and Er- lenmeyer Hecht j) Jechsner Volker Wislicenus Schorlemmer Priedel and Silva Coninck Schorlemmer Morgan Wurtz 'rianicknikow iaschirski iaschirski lizza hdanow )obereiner jiebig Dinner Wurtz J. p. [2], 3, 88 A., 158 167 A., 93, 118 C. K., 93, 69 4, 103, 234 B., 16, 745 A., 187, 126 26, 1081 B., 4, 823 ; C. N., 24, 263 P. T. [1872], 111 j* C. R., 54, 1245; J., 16, 527 A., 133, 178 A., 195, 102 J., 21, 336 J., 6, 504 M. C., 4, 32 M. C., 4, 40 B., 7, 206 A., 161, 272 ; P. T. [1872], 111 P. T. [1878], 1 27, 1030 A., 177, 307 A., 178, 22 16, 221 ;J., 16, 521 A.. 165, 151 B. S. [2], 24, 99 B., 8, 1019 A., 219, 307 J. [1873], 339 ; C. R., 76, 226 C. R., 82, 93 A., 199, 139 ? J. p. [2], 26, 111; Z.C.[1865],615 A., 195, 254; 209, 84 Z. C. [2], 7, 275 B., 11, 984 C. C. [1881], 278 J. R. [1882], 99 B., 5, 479 A., 5, 25 B., 5, 148 C. B., 48, 478 24, 525 24,521;vil.,217 11., 537 i., 205 44, 1075 32, 880 vii., 646; 32, 880 25, 1085 ; vii., 645 vii., 645 ; 25, 1085 iii., 152; vi., 698 vi., 395, 698 36, 455 vi., 64 vi., 698 27, 563 vii., 645 ; 26, 1085 32, 866 vii., 868 28, 303 29,60 iii., 152; vi., 698 30,67 29, 364 44, 966 27, 1030 26, 488 ; vii., 982 38, 158 28, 302 vi., 698 24, 1036 36, 46 42,37 42,491 vii., 18; 26,48 26, 406 i., 3 J) ,, .... .... .... .... )> 51 "' *" "" .... , two samples .... j) .... .... .... ? 5 j .... .... .... ,, jj .... .... 135-140 130-135 125-129 20-130 121-122-5 S2-S-123-5 17-118 12-113 18-119 18-119 (751) 17-120 10-112 5 5-2 03-105 00-105 05 (768) ,, ,, >J Jl "" "" ) j) .... .... .... )l j) Kthylidene diethylate (acetal) ^ j) j> H ) J) 1) ) 172 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylidene diethylate (acetal) CH 3 .CH(OEt) 2 C 6 H 14 S 105 Kramer and Pinner B., 4, 788 24, 1188 M 104-106 .... Stas J., 1, 697 ,, 104 .... Wurtz and Frapolli A., 108, 223 ?) 103-7-104-3 Bruhl A., 203, 25 >. j> 104-104-1 c. Perkin .... 45, 507 B 104 .... Bachmann A., 218, 38 44,727 ;, 104-3 ; .... Pawlewski B., 16, 2633 46, 252 254-4 c. t. Ethylene diethylate OEt.CH,.CHj.OEt 123-5 (758-8) Liquid Wurtz A., 108, 84 ; ii., 574 A. C. [3], 55, 431 Methylpropylacetal CH 3 .CH(OMe)(OPr) 103-105 Bachmann A., 218, 38 44, 727 Hexylene glycol CH 2 (OH).(CH 2 ) 4 .CH 2 OH 203-210 Hecht and Munier B., 11, 1154 34,966 207 Liquid Wurtz A. C. [4], 3, 180 vi., 68 n abt. 207 Liquid J. [1864], 512 vi., 699 CH Me(CH s .OH).CHMe 212-215 Liquid J., 17, 513 vi., 94 (CH 2 .OH) 215 Liquid A. C. [4], 3, 62 vi., 68 ,, 219-220 J. P. [2], 23, 18 CH 3 .(CH 2 ) 3 .CH(OH).CH 2 OH 191-192 Liquid Grabowsky & Sayt- A., 179, 325 29, 542 zeff .... Pr 8 .CH(OH).CH(OH).Me 204-208 s. 0. Fossek M. C., 5, 119 46, 833 Et.CH(OH).C(OH)Me 2 184 Flawitzky A., 179, 340 29, 545 (pinacone) .... Mej.C(OH).C(OH)Me 2 170 c. Perkin 45, 506 ,, j> 171-172(739 S5-SK Linuemanii As., 3, 374 iv., 648 J tt 176-177 below 99 206-207 .... Eltekoff J. E. [1882], 355 44,567 (hydrate) ... + 6H 2 .... 46 .... 46-5 Linnemann As., 3, 374 iv., 648 .... 46-3 Pawlow A., 196, 127 36, 536 Cochlearin . . C H O (1} 45 i., 1062 Ethylmethyl glycerol CHEt(OH).CMe(OH).CH 2 ck'o. 170-176(53) Liquid Lieben and Zeisel M. C., 4, 4 44, 570 (OH) Hexyl glycerol primary and secondary 181 (10) .... J. B. [1881], 353 Trimethylglycerol C 3 H 6 (OMe) 3 J) 148 Liquid Alsberg J. [1864], 495 ; v.,885; vi.,(;3,s A., 131, 123 Glycolacetal .... CH 2 OH.CH(OEt) 2 167 Liquid Pinner B., 5, 150 vii., 1 ; 25, 406 Ethylidene oxymethyl alcoho- CH s .C(OMe) 2 (OEt) J) 126 T Laatsch A., 218, 13 44, 788 late Propylic dimethylic orthofor- CH(OMe) 3 (OPr) 150-155 .... Pinner B., 16, 1647 44, 1089 mate Triethylenic alcohol HO(CH 2 ) 2 0(CH 2 ) 2 C 6 H 14 4 abt. 290 Liquid Wurtz J., 16, 489 ii., 577 (CH 2 ) 2 .OH 285-290 .... Lourenjo J., 13, 443 Diglycerol .... .... .... CH,.O t 220-230 (10) Wurtz A. C. [3], 67, 300 Sorbite C H O +iH O 6 14"6 C 6 H 14 6 110-111 Boussingault C. E., 74, 939 ; 25, 480; vii., 6 ,4 6 A. C. [4], 26, 376 1093 Isodulcite (Bhamnoduleite) .... .... n .... 93-94 Berend B., 11, 1354 36, 40 .... .... .... .... jj 92-93 Liebermann and B., 11, 956 36, 39 Hermann n .... 93 Foerster B., 15, 217 105-1 10 d. Hlasiwetz & Pfaun- J. [1864], 564; v., 465, 1091 dler A., 127, 362 Alii mute CH,,OH.(CH.OH) 4 .CH S OH abt. 200 160-165 Berthelot G. J. C., 1857 iii., 823 165 Boussingault C. E., 74, 939 25,480;vii.,1093 165-166 O Linnemann G. J. C., 1862 166 Kubel J. p., 85, 372 ii., 60G 166 Bechenberg J. p. [2], 22, 223 40, 11 Dulcite 0,H 8 (OH), 182 Kubel J. p., 85, 372 ii., 606 182 Gilmer A., 123, 372 ii., 349 " " 182 Jacquelain Co. C. [1851], 21 182 Boussingault C. B., 74, 939 5,480;vii.,1093 188 Berthelot G. J. C., 1855 COMPOUNDS CONTAINING THREE ELEMENTS. 173 Name. Constitution. Formula. Boiling Point. Melting Point. Authority.. Reference. "Watts' Diet. & J. Ch. Soc. Bulcite C 6 H 8 (OH) 6 i> > C 6 H 4 .CO.O or C 6 H 4 .CO.O.OC.C 6 H 4 .O or C 6 H 14 6 )> J) )J C 6 H" 6 0, (?) c 6 H M o 3 n) C 7 HA C 7 H 4 8 C 7 H 4 6 C 7 H 6 ) C 7 H 6 3 )) ) (C 7 H 6 2 ). C 7 H 6 2 ) j jj i ji > j ) ) >v )V JV )V Jl )< > )) 1) )) 5) )i J) ?1 ) 5! 130 63 174-178 176-6-179 (751-752) 179-1 (751 -3) 180-183 200 p. d. 182-185v 178-2 196-5 ^40 255 255 249 249-2 (740) 250 185 185-5 186 187 188-5 190 Mostly at, 195-200 p.d.; all at 220- 225 118 220 d. Liquid 51 64 67 67 67-68 300 abt. 100 s. 20> 104 111-112: 115-116 115-116 115-116 119 119-120^ 119-120 119-120 120 120; 120 121-4 120-5 120-121 120-5 121 121 121-4 120-5 121-5 121-5 121-121-5 121-4 121-5 121-5 Kiliani Rechenberg Eichler Bouchardat Laurent Bobiquet Weidmann and Schweitzer. Schiff Bender Tilden Lossen Kopp Guckelberger Schmidt Spica Nietzki Eiedel Nolting and Kahn Spica Schunck Ettling Mendeljeff Piria Tiemann & Ludwig Tiemann and Will Bucking Reimer & Tiemann >T Japp & Streatfield Ramsay Hittorf Laubenheimer Hodgkinson ji Perkin Schiff Wright and Luff ) n Busse Rennie Carnelley& Williams Kopp Japp and Wilcock )> )> >' Jones Popoff B., 13, 2306 J. p. [2], 22, 223 R, 2, 103 A. C. [4], 27,68; C. R, 73, 199 ) Co..C. [1850], 364 A., 36, 305 A., 163, 220 B., 13, 697 A. P. J. T. [3], 5, 761 A., 214, - A., 112, 175 J., 1, 850 B., 13, 2343 G. I. [1882], 225 B., 10, 833, 1155 B., 13, 126 B., 17, 366 G. I. [1882], 225 A., 29, 310 J., 13, 20 A., 29, 300; 30,154 B., 15, 2044 B., 14, 969 B., 9, 529 B., 9, 1268 B., 9, 825 39, 64 G. J, C., 1865 A., 164, 289 45, 182, 184 A., 223, 247 B., 9, 832 J., 8, 35 , 5 , 39 B., 4, 721 40, 11 ii., 349 vii.,441; 24,810 ii.. 349 i., 148 vii., 1067 ; 26, 819 40,48 28, 1258 i., 568 40, 248 42, 1066 32, 767 38, 386 46, 902 42, 1065 v., 132 v., 168 v., 168 44, 188 30, 296 31, 84 30, 633 41, 150 26, 65 33, 499 33, 500 j 33, 501 46, 1089 35, 395 33, 333 30, 641 41, 37 33, 282 i., 549 37, 670 37, 663 37, 670 37, 669 33, 181 25, 409 24, 1058 Aloi'sol Mesitene Salicylide (!atechol carbonate ( 'helidonic acid Benzoic aldehyde .... ' .... ,, ,, Furfuracrolein Toluquinone C 6 H 4 .OO.O.C 6 H 4 .COO C 6 H 4 .O.CO.O =.1.2. C 6 H 6 .COH ) C 6 H 3 Me:O 2 =1.2.5 5 ? n C 6 H 4 .OH.COH =1.2: I) )) = 1.3 = 1.4 J) I! C 6 H 6 .COOH jl > > I) > M )1 ) ?) ) B )) ) > U (polymer) Rubiretin Hydroxybenzaldehyde (sali- cylol) ) M j> ,, Benzoic acid .... ,, , T ,, ,, .... .... 174 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Benzole acid C 6 H 5 .COOH .... 123-3 Kachler Z. C. [2], 6, 60 vii., 160 Phenol + CO 2 .... C 7 H 6 3 (?) 37 Klepl J. p., 25, 464 44, 585 Furfuracrylic acid C 4 H 3 O.CH : CH.COOH C 7 H 6 3 135 Baeyer B., 10, 357 32, 444 Methoxy quinone C 6 H 3 .OMe:O 2 =1.2. ? > .... 138 MUhlhauser A., 207, 251 42, 302 Oxytolic acid .... 180 Fittig A., 120, 966 iv., 321 Hydroxybenzoic acid (sali- C 6 H 4 .OH.COOH =1.2 )J 121 Procter J. P. [3], 3, 275 v., 153 cylic) ! I) I ) sb. 200 125 Ettling A., 53, 77 tt V J .... 154 Richter B., 4, 554 24, 824 JJ ? ji J) 155 Wroblevsky Z. C. [2J 7, 6 24, 130 > J1 n .... 155 Liebermann B., 10, 1038 32, 782 l> >J 1) i i 180-190 155 Perkin and Hodg- .... 37, 488 kinson > ) 155-156 Eecheuberg J. p. [2], 22, 223 40, 11 )1 JJ 156 Velden J. p. [2], 15, 151 32, 337 I) > .... 156 Smith, E. F. A. C. J., 2, 338 40, 1035 J r j .... 157 Petersen B., 6, 377 26, 1133 J J > ?) 157-5 Farsky C. C. [1877], 148 34, 225 11 > 158 Cahours A. C. v., 153 l )> )J )) i) 157 Kolbe & Lantemann G. J. C., 1860 l J) J H 155-156 Hiibner G. J. Q, 1872 J> I> .... 157 Vogt & Henninger G. J. C., 1873 )> ) i> > 155-156 Kohler G. J. G, 1879 J> Ji )> )i 156-158 Oliveri G. I., 13, 263 46, 174 11 =1.3 j) 182 Ador & Oppeuheim Z. C. [2], 7, 22 24, 131 1) 1 )> )i .... 189 Kemsen Z. C. [2], 7, 294 24, 1052 (4th) .... ? j) .... 188-190 Fittica B., 11, 1208 34, 980 =1.3 .... 190-195 Oliveri G. I., 13, 263 46, 174 i) J) J) 196-197 Mazzara G. I., 9, 425 38, 164 n ,i I> )> .... 197 Conrad J. p. [2], 15, 241 32, 485 )) n >i .... 198 Oat J. p. [2], 11,385 29, 253 M > j 199 Sarauw B., 15, 43 42, 608 I! n .... 199 Peterseu B., 6, 377 26, 1133 > j 200 Earth G. J. C., 1870 .." M 200 Liebermann B., 10, 1038 32, 782 )> 200 Fischer G. J. C., 1863 ) )> 200 Rechenberg J. p. [2], 22, 223 40, 11 )> )! )> ) .... 201 Fittica B., 11, 1208 34, 980 J> 1 =1.4 .... 210 p. d. Saytzeff A., 127, 129 iv., 353 ) !) )> 210 Earth G. J. C., 1870 ii )) .... 210 Remseu Z. C. [2], 7, 81 24, 369 )) )> >i ? 210 Z. C. [2], 7, 199 24, 704 )) n )> >J ... 210 Petersen B., 6, 377 26, 1133 )) ) 210 Velden J. p. [2], 15, 151 32, 337 ) .... 210 Liebermann B., 10, 1038 32, 782 > J) .... 210 Vogt & Henninger G. J. C., 1873 > )l 210 Jacobsen B., 11, 376 34, 582 !) ? MM 210 Rechenberg J. p. [2], 22, 223 40, 11 " i) i) > 211 Balbiano G. I., 13, 65 44, 1125 Dihydroxybenzaldehyde COH.OH.OH = 1.2.5 )) .... 99 Tiemann and Miiller B., 14, 1986 42,52 (gentisic) 1.2.6 n ... 134-135 Tiemann and Lewy B., 9, 1269 ; 10, 34, 424 (resorcjlic) 2212 >i .... 1.2.4 . 134-135 Tiemann and B., 13, 2379 Parrisius 1.3.4 J) 150 Tiemann and Koppe B., 8, 1123; 9, 42, 54 (protocatechuic) 1269; 14, 2015 " i J .... 150 Remsen and Fittig Z. C. [2], 7, 100 vi., 976 j) i) .... 150 Fittig and Remsen A., 159, 149 24, 939 Acjtylpyromeconic acid C 6 H 3 Oj.OAc C 7 H 6 4 .... 91 Ost J. p. [2], 19, 187 36, 708 COMPOUNDS CONTAINING THREE ELEMENTS. 175 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dihydroxytoluquinone C 6 HMe(OH),, : O 2 C 7 H,0 4 ,,,. 177 Zinck B., 16, 1562 44, 1118 Dihydroxybenzoic acid COOH.OH.OH=1.2.6 H d. 135 140 d. Senhofer and W. A., 80, 504; 40, 266 Brunner 81, 430, 1044 )* .... 148-167 !> 11 R, 13, 2356 41, 410 11 11 ? s. w. m., 170 Leeds B., 14, 482 40, 584 J) !> ) .... abt. 180 Matthiessen and 16, 350 ill., 239 Forster 11 11 ? j .... 180 d. Beckett and Wright 29, 299 11 11 " ? 189 Bemsen Z. C. [2], 7, 294 vii., 1127 )> = 1.2.3 )) 192 d. Miller 41, 400 11 11 11 11 204 d. D B., 16, 81 41,406 ,, (gen- = 1.2.5 .... 183 Liechti As., 7, 144; Z.C. 41, 401 ; vi., tisic) [21 6, 197 1005 11 11 11 ! )J 3> 183 Demole B., 7, 1437 28, 253 11 11 11 )> )> )1 .... 192 Hlasiwetz and A., 175, 66 28, 572 Habermann 11 11 11 ) 193 Lantemann A., 120, 311 iv., 320 ; vi., 1005 11 11 11 )' )) )) 197 Senhofer & Sarlay M. C., 2, 448 40, 1140 11 11 ) .... 195-197 P. Frankland .... 37, 750 11 11 11 n .... 196-197 Hlasiwetz and A., 180, 347 30,83 Habermann 11 11 11 > .... 196-197 Goldberg J. p. [2], 19, 371 36, 929 11 ?! 11 n .... 196-197 Tiemann & Miiller B., 14, 1988 42,52 11 11 11 n )J .... 197 Rakowski & Lepper B., 8, 789 41,409 11 11 11 ) ) 1> .... 200 Miller B., 16, 81 41, 45 11 11 11 = 1.2.4 11 194 Ascher B., 4, 649 ; A., 24, 828, 1055 ; 161,11 26, 240 ; vii., 432 11 n(+3H 2 O) 148 11 > D 11 11 I )J 194 Blomstrand B., 5, 1090 26, 506 15 11 1 .... 194 Fahlberg A. C. J., 2, 181 40, 818 11 11 >J )) .... 194-198 Senhofer & Brunne W. A., 80, 504; 81 40, 265 43, 1044 11 1) ) JJ 200 Tiemann & Eeimer B., 12, 997 11 11 >1 ) .... 204-206 Tiemann & Parrisiu B., 13, 2360, 2378 41,409 11 , (proto- = 1.3.4 194 Earth and Schmidt G. J. C., 1879 catechuic) 11 1! !! 199 Miller 41,399 11 11 11 JJ 199 Malin 41, 410 11 11 !> 51 ) > .... 197 c. Beckett & Wright .... 20, 473 11 11 11 T) )J 1) .... 199 c. D 11 .... 29, 308 11 11 11 I) ?1 > .... 198-199 c. ? ... 29, 287 11 11 11 J 199 Hlasiwetz G. J. C., 1864 11 n 11 7) 199 .... iv., 739 11 11 11 3) J) 199 Fittig and Remsen A., 159, 129 24, 939 11 11 11 > )> T 198 Earth G. J. C., 1870 11 !> 1) 199 Ascher B., 4, 649 vii., 432 Jl >! 1) ) ) 799 Korner G. I., 6, 142 31, 88 11 !> = ? )J .... 207 c. Hesse A., 112, 527 iii., 215 >! =1.3.5 220 Earth & Senhofer B., 4, 632 24, 828 11 11 11 11 )> .... a. 220 11 11 A., 159, 222, 164, vii., 433 109 1) 11 11 11 1 .... S32-2S3 Bottinger B., 8, 375 Gallic acid COOH.(OH) 3 = 1.3.4.5 C 7 H 6 O 5 abt. 200 Pelouze A., 12, 36, 160 220 B., 12, 36 " J? j 225-230 d. 11 Robiffnet [1837] '* I) jj 197-200 IVTatsmoto G. J. C., 1878 JJ TJ ji 210 when Freda G. I., 9, 327 38, 122 J* )) slowly heated 176 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Gallic acid COOH (OH^ 1 345 C H O 240 252 when Freda G I 9 327 38 122 j t y, ... .... ... j) ^7 6^S )) ... quickly heated 222 232 Etti B., 11, 1882 36, 160 240 235 240 Schiff G I 9 1 36 647 240 d R12 ^7 36 466 Methylphenyl oxide (anisol) Benzyl alcohol C 8 H 5 .OCH 3 CjHs.CH.OH C 7 H 8 152 204-5-205-5 (743) 204 Liquid Cahours Bruhi A. C. [3], 2, 274 ; 10,353;&27,439 A., 200, 139 J 7 585 i., 305 38, 296 " "* " ,, )) 205-207 206-5(751-4) 206-2 c Liquid b 18 Laubenheimer Kopp Kraut A., 164, 289 A. A 152 134 vii., 177 ; 26, 65 i., 578 vl., 335 207 vli., 931 Cresol . . . . : * ;, C 6 H Me OH ' Wurtz A C [4] 25 108 vii. 1163 iM abt 197 Allen An [1878] 319 36, 182 200 Liquid Friedel and Crafts C R. 86 884 34, 670 198 Ead J 22 448 203 Liquid Williamson& Fairlie 7, 232 ii., 107; vi.,50") 13 189 190 s 38 Earth Z C 13 624 195-200 1 f m Engelhardt and Z C [1869] 623 vi., 507 196-202 8 14 Latschinoff Gladstone & Tribe 41, 12 abt. 192 Kolbe J. p F21 8 41 27, 373 193 195 Schwarz M C 3 728 44, 205 198-200 Southworth A., 168 268 201 Liquid 20 Oppenheim & Pfaff B., 8, 889 200-204 Liquid Tiemann& Schotten B., 11, 770 201 Tiemann & Hoppe B., 14, 2013 =11.2 185-187 Gerichten & Eossler B., 11, 1587 36, 323 189 1. f. m. Engelhardt and Z. C. [1869], 620 vi., 507 abt. 15 Latschinoff t | I 188 30-31 Ihle J. p. [2], 14, 442 31, 708 29-8-30-.4 Nevile & Whither 37, 631 185-186 31-31-5 Kekute B., 7, 1006 vii., 934; 28,64 186 Tiemann & Hoppe B., 14, 2013 188 30 Tiemann & Shotten B., 11, 769 190 Southworth A., 168, 273 1.4 205 34 Buff B., 4, 378 24, 531 ; vii., 199 Tiemann & Hoppe B., 14, 2013 393, 934 201 '5-202 34-5 Wurtz A.C. [4], 25, 108 vii., 1163 199 202 35 Jacobsen B., 11, 376 34, 582 35 Vogt & Henninger C. R., 94, 650 42, 729 198 35 Fucha Z. C., 13, 171 198-190 36-37 Tiemann & Schotten B., 11, 769 197-198 Southworth A., 168, 273 197-200 Guareschi G. I., 4, 22 27, 584 199-202 Gladstone & Tribe 41, 10 198-200 s. f. m. Engelhardt and Z. C. [1869], 623 vi., 506 197 36 Latschinoff Earth Z. C., 13, 624 198 36 Ihle J. p. [2J 14, 442 31, 708 Methoxyhydroxybenzene .... n (guaiacol) ) OMe.OH=1.3 ) JJ =i.a > C 7 H 8 2 J) 243 843-344 200 200 Liquid ) Tiemann & Parrisius Habermann Beckett & Wright Gratzel B., 13, 2362 B., 10, 868 A. P. [3], 20, 605 40, 270 32, 474 29, 286 44, 393 COMPOUNDS CONTAINING THREE ELEMENTS. 177 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methoxyhydroxybenzene OMe.OH = 1.2 C 7 H 8 2 210 .... J. Williams C. C. [1873], 167 27, 583 (guaiacol) 11 II 11 11 11 205-210 Hlasiwetz A., 106, 366 II 11 11 11 ) 210 Sobrero Watts' Diet. 11 11 1 T 203-205 Volckel J., 7, 610 V II 1> JJ 210 .... ii G. J. C., 1854 V II > )> 1) 200 Gorup G. J. C., 1867 11 V 1) 11 199 11 G. J. C., 1868 > II =1-4 11 abt. Z1& 53 u. c. Hlasiwetz and A, 177, 339 89,79 Habermann 11 11 1 > )) 53 Tiemann & Miiller B., 14, 1989 48,52 Hydroxybenzyl alcohol (CH 2 OH).OH=1.3 1) 300 p. d. 67 Velden J. p. [2], 15, 166 38, 338 i 11 (saligenin) =1.2 )) s. 82 Piria A., 56, 39 v., 173 11 11 n 1 1 11 .... 82 Beilstein A.,117,83; 128,179 ii n ii ^-isoi'cin =1.4 Me.OH.OH= ? > 260 197-5 87 Herzfeld Senhofer B., 10, 1267 A., 164, 132 34,65 vil, 1170; 25, )1 1017 n- (anhydrous) =1-2.4 (?) 11 270 87-88 Blomstrand and B., 5, 1087 Hakansson a- (hydrated) )) 11 )1 95 11 11 11 Dihydroxytoluene (tolu- =1.3.4 1) .... Liquid Miiller C. N., 10, 269 quinol) 11 11 11 .... Liquid Tiemann and Nagai B., 10, 210; 11, 672 11 11 11 1 11 .... Liquid Neville & Wiuther B., 15, 2983 41, 426 11 11 = (0 )) .... 69 Carstanjen J. p. C. [2], 23, 421 42, 612 11 11 =1.2.4 ! .... 103 Knecht B., 15, 301 42, 729 )) 11 11 1) 11 103; 104-105 Wallach B., 15, 2835 II 11 11 11 Jl .... 104-105 Neville & Wiuther R, 15, 2981 41, 423 II " )1 1 11 267-270 .... A., 215, 92 II II 11 11 11 .... 104-105 Vogt & Henninger C. R., 94, 650 42, 729 (orcinol) =1.3.5 11 287-290 Dumas A., 27, 140 ii " > 11 286-290 86 Lamparter A., 134, 243 41, 418 ii ii )J } 103-108 Neville & Winther B., 15, 2988 41, 420 i' ii ) > 11 .... 106-108 11 11 11 41,418 ii ii t )1 )) .... 106-5-108 ii ii ii ii +H 2 )> 1 11 .... abt. 56 11 n ii 11 v ii ii .... 54-56 11 ii ii 41, 420 11 11 I! > ) 11 .... 57-58 Schroder B., 12, 1612 11 11 II 1) 1 57-1 Vogt & Henninger A. C. [4], 27, 129 41, 418 11 II II 11 )J 11 .Ml 58 Hesse G. J. C., 1881 II II 11 ) }> 58 Lamparter A., 134, 243 41, 418 II = 1.2.5 1) 124 Nietzki B., 10, 834 32, 476 11 " ) ) 11 124 ii B., 10, 1157 32, 767 II " > 1 } 124-125 ; Neville & Winther B., 15, 2979 41, 4-25 123-125 11 " ' ) )> ) 125 Nietzki A., 215, 159 44, 467 11 [C 6 H 3 .Me.(OH) 2 ] n (C 7 H d 3 ). .... 204 Spica G. I. [1882], 225 42, 1065 Furfuropropionic acid CH.C x -(CH 2 ).COOH II I >o CH.CH/ C 7 H 8 3 50-51 Baeyer B., 10, 357 32, 445 Ethylic pyromucate C 4 H 3 .COOEt ii 208-210 34 Malaguti A., 25, 276 iv., 765 11 11 )) ii 33-34 Jourdan R, 16, 659 Methyl pyrogallol C 6 H 2 .Me.(OH) 3 =? ii 129 Hermann B., 12, 1371 38, 249 Reduction of quercetiu .... 11 130 J. [1864], 562 v., 5 Uvic acid (pyrotritartaric) ... CH,,.C.(COOH) I CH.CH : n 133 Bottinger A., 172, 242 27, 1159 CH.CHOH 1 11 11 11 ii 11 133 ii B., 6, 893 33, 429 n 11 ii .... ii .... 134-5 Wislicenus and A, 146, 306 vi., 981 Stadnicki 11 11 11 COOH.CHAc.CH : C : CH 2 ii .... 135 Harrow .... 33, 429 2 A 178 OEGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Uvic acid (pyrotritartaric) .... COOH.CHAc.CH : C : CH 2 C 7 HA .... 135-136 Harrow 33, 434 135-136 .... 33, 430 Hydro-hydroxybenzoic acid C 6 H S .COOH.OH .... 273; 274-5 c. Emmerling and B., 9, 326 30,85 Oppenheim Teraconic anhydride 11 (/ 270-280 p. d. .... Geisler A., 208, 37 42, 42 Terebilenic acid CMe.,O.CO.CH : C.COOH C 7 H 8 O 4 .... 169 Roser B., 15, 296 Furonic acid .... C 6 H 6 O(COOH) 2 C ? HA 180 Baeyer B., 10, 695, 1358 32, 744 Diacetomesoxalic acid C(OAc) 2 (COOH) 2 C 7 H 8 S .... 130 Petrieff B., 11, 414 34, 490 Isoallylene tetracarboxylic C(COOH) 2 (CH 2 .COOH) S .... 151 d. Bischoff B., 13, 2164 40, 156 acid From bromamylene dibro- C 5 H 6 .O.Et C 7 H 10 125-130 Liquid Reboul C. R., 58, 1058 vi., 120 mide Tropilene 180-181 ; Ladenbure C. R., 93, 517 ; 42, 216 181-182 O B., 14, 2130 From a-ethyl-/3-acetopro- .... C 7 H,A 219 .... Thorne 39,343 pionic acid Mesitonic lactone CMe 2 :CH.CMe.CO.O 167 24 Pinner B., 15, 579 43, 942 Pimelic anhydride CO.CH 2 .CHPr0.COO i i C.H.A 245-250 Liquid Kachler A., 169, 172 27, 155 .... 245-250 Roser A., 220, 271 46, 423 Acrolein diacetate C 3 H 4 .(OAc) 2 C 7 H 10 4 180 Liquid Hubner & Geuther A., 114, 48 i., 147 ; vi., 217-218 Liquid Amthor A. P. [3], 18, 356 42,46 )j )> j 218 cor. 1. f. m. Fittig and Kraft A., 208, 82 42, 43 jy ) " .... j) .... 72 Samow B., 4, 731 24, 1046 from terpenylic acid 202-204 Amthor A. P. [3], 18, 356 42, 46 202-204 1. 16 42, 45 11 n 210-212 j> j> CHMe.CH 2 .CHEt.CO.O jj 219:5 c. Liquid Young 11 A., 216, 38 11 43, 173 n C 3 H 7 .CH.CH.,.CH 2 .CO.O 220 c. 11 Fittig A., 208, 111 42, 33 " o ,, .. .. .... ... * 220 c. 11 Fittig and Kraft A., 208, 88 42, 43 224-225 Vounff 43, 179 Methylic ethylacetoacetate .... CHEtAc-COOMe C 7 H 12 3 186-8 MM i. 1897 c. Brandes Z. C. [1866], 457 vi., 829 Ethylio a-acetopropiouate .... CH 3 .CHAc.COOEt ) 185-186 Kohrbeck B., 8, 1036 29, 369 11 11 11 ,, 187 Geuther J. [1865], 304 vi., 16 1} >! "" n J 186-8 .... A,, 138, 335 ; 188, vi., 591 231 Ethylic 0-acetopropionate .... CH 2 Ac.CH i! .GOOEt )) 203-205 Liquid Conrad A., 188, 225 34, 137 11 >i " )J .203-205 Grote and Tollens B., 10, 1440 32, 882 11 11 5) 200-210 Conrad B., 11, 2177 36, 453 11 11 200-201 u.c. Grote and Tollena B., 10, 1442 32, 882 (756) ji 200-201(756) .... Grote, Kehrer and A., 206, 221 40, 410 =205-2 c. Tollens a-ethyl /3-acetopropionic acid CH 2 Ac.CHEt.COOH M 250-252 1.-15 Thorne 39, 340 Acetopentylic acid .... J> 210-220 .... Hardtmuth A., 192, 142 34,782 Mesitonic acid CMe 2 : CH.CMe(OH).COOH )J 88 Pinner B., 15, 578, 585 42, 942 ji 11 " n J> 230-240 90 11 B., 14, 1073 40, 796 Hydroxypentinic acid .... J 103-104 .... A. C. [5], 20, 490 Methyl |3-ethoxycrotonic acid .... )J 132 Friedrich A., 219, 322 44,968 Propylene diacetate CH 3 .CH(OAc).CH 2 (OAc) C 7 H 12 4 180-185 .... vi., 965 11 11 M 186 Liquid Wurtz A.C. [3], 55,400; v., 892 ; 27, C. R, 78, 1773 977 11 11 AcO.CHo.CH.j.CHj.OAc 11 203-205(717) .... Geromont B., 4, 550; A., vii., 1021 ; 24, 158, 369 697 11 .... 209-210 c. Eeboul C. R, 79, 169 27, 1153 11 11 * 11 210 C. R, 78, 1773 27, 977 11 11 11 209-210 11 A. C. [5], 14, 491 36, 133 Ethylic acetolactate CH 3 .CH(OAc).COOH !> 177 (733) Liquid Wisliceuus A., 125, 59 iii., 460 ,, propionylglycollate.... CH 2 (OC 3 H 6 O).COOEt 11 200-201 Liquid Senff A., 208, 270 40, 1127 Butyrolactic acid CH 3 .CH(OC 4 H 7 O).COOH 11 208 Wurtz A. C. [3], 59, 177 iii., 4CO From akaline camphorate .... Fusion with KHO 11 .... 114 Hlasiwetz and Gra- Z. C. [2], 4, 508 vi., 389 bowski (3-ethylglutanic acid CHEt(CH 2 .COOH) 2 11 .... 66 Kommenos A., 218, 145 46, 423 a-pimelic acid COOH.(CH 2 ) 5 .COOH 11 100 )ale & Schorlemmer A., 199, 148 35, 686 i- i) 11 )) 11 .... 100 Baeyer B., 10, 1358 34,4 a- i) 11 n 11 ... 103 Schorlemmer & Dale B., 7, 808 27, 936 '- 11 11 11 .... 130 Helms B., 8, 1167 29, 374 Propylsuccinic acid .... .... COOH.CHPr.CH,,COOH 11 91 Waltz A., 214, 59 ; B., 44,46; 42,948 15, 608 Isopropylsucciuic acid COOH.CHPr/i.CH,.COOH ') .... abt. 114 Laurent A. C. [2], 66, 163 iv., 646 (pimelic) 11 11 11 11 114 Kachler A., 169, 168 27, 154 11 11 11 11 114 Mulck A., 180, 45 29, 925 11 11 11 J) 11 .... 114 Hjelt B., 16, 2621 46, 297 180 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Isopropylsuccinic acid (pimelic) ' i Pimelic acid .... COOH.CHPr0.CH 2 .COOH n C 5 H 10 (COOH) 3 COOH.CHEt.CHMe.COOH CHMe 2 .CH 2 CH(COOH) 2 COOH.CEtj.COOH ) COOEt.CH 2 .COOEt COOMe.CH 2 .CH s .COOEt MeO.CH 2 .CH.CH CH.CH. V ' V o o CH,OH EtO.CO.OCH 2 .COOEt C 3 H 5 (OH)(OAc) 3 Me 2 .CH.CH 2 .C(OH).(COOH) 2 EtO.CH : CMeEt C 6 H 13 .COH CH 3 .(CH 2 ) 5 .COH 1 1) )) ') 1 ' isomer Me(CH 2 ) 5 .CH.(OH) Me.(CH 2 ) 4 .CH.CH(OH) Me.(CH 2 ) 4 .CH.CH.(OH) Me.(CH 2 ) 4 .CH.COH * Me.CO.(CH 2 ) 4 .CH 3 ? J* Me.CO.CH 2 .CH 2 .CHMe., 5 TT C 7 H 12 4 i }j *i ?> i ) T ) J) C 7 H 12 5 ,, (?) C 7 H 12 6 5) C 7 H U 5 1) n i M T )) ) ) ? J J1 J) TJ (C ; H U 0) 4 (C ; H 14 0) n C 7 n" 4 o it ) )> n high temp. 195 196 197-7-198-2 c. 208-2 abt. 240 280 250-253 111-114 145 151-152 152 (748-6) 153-154 c. ' 152-154 1SS-S-1SS-2 c. 155-160 154 c. 155 c. 155-156 155-156 155-157 154-2-154-5 (748) 155-158 161-164 230 260 d. 115 260 155-156 150-152 149-152 146-149 144-146 145 144 . 114 114 134 158-160 107 112 121 Liquid 44-45 Liquid 1. -40 110-114 130 155 161-6 c. 161-6 c. Liquid Liquid 5-6 5-6 52-53 51-52 Eoser Waltz Bromeis Young Guthzeit Conrad Finkelstein Bischoff Perkin Weger Faucoimier Heintz Berthelot Guthzeit Arppe Woskresensky Hesse Zwenger & Siebert Eltekotf De Clermont Sbedeler Cross Perkin > Bruylants Grimshaw & Schor- lemmer Tilley Williamson Bouis Neison Briihl Bussy Fittig Bussy Bruylants Perkin Bruylants Borodine Schmidt Schorlemmer Schorlemmer Morgan Mixter Demarcay Popoff B., 15, 295 ; A., 220, 271 B., 15, 609 ; A., 214, 60 A., 35, 104 43, 180 A., 209, 236 B., 12, 749 A., 204, 138 A., 133, 349 B., 15, 1109 A., 221, 61 B. S., 41, 18 A., 154, 264 A. C. [3], 41,278 J. [1876], 343 A., 209, 238 A., 95, 242 A., 24, 257 A., 114, 292 A., 1, 79 B., 10, 706 B. S. [2], 13, 404 J. [1857], 360; J. p., 72, 240 32, 124 B., 15, 2802 B., 8, 415 26, 1075 A., 75, 249; P.M., 33, 81 A., 61, 38 J., 8, 524 A., 200, 102; 203, 28 .1. P. [3], 8, 321 J., 13, 319 J. P. [3], 8, 321 B., 8, 415 B., 16, 1034 B., 8, 415 B. B., 5, 597 A., 161, 279 ; P.T.[1872],111 B., 7, 501 C. R, 86, 1085 Z. C. [1865], 578 42, 717 ; 46, 423 42,948; 44,40 iv., 646 42,39 36, 707 vi., 801 42, 1188 45, 508 46, 11 46, 111 vii., 255 i., 25 42, 40 iv., 319 v., 10 n vii., 868 iv., 175 ; 26, 1075 43,47 43,81 45, 477 26, 1073 ; iv., 175 iv., 175 27, 508 iv., 175 iv., 176 43,80 43,46 vii., 251 vii., (542 ; 25, 1086 26, 322 28, 305 27, 785 34,661 vii., 251 Ethylmethyl succiiiic acid ... Isobutylmalonic acid Diethylmalonic acid )j j* .... Diethylic malonate i > Methylic ethylic succinate .... Methyl isomannide .... Ethylic carboglycollate Glycerin diacetin ,, (isomer) ... Isobutyl tartronic acid Oxypyrolic acid Quinic acid Ethylvaleryl oxide Heptene oxide (Enanthol ' Metoenanthol .... (Enanthol Amylmethyl ketone > ; ,, .... Isoamylmethyl ketone , COMPOUNDS CONTAINING THREE ELEMENTS. 181 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Isoamylmethyl ketone Me.CO.CH 2 .CH 2 .CHMe 2 C 7 H 14 O 143-145 .... Grimshaw 26, 319 vii., 643 ., ,, JI 142-144 u. c. Liquid Rohn A., 190, 305 34, 486 i) i> I n 155-156 .... Schmidt B., 5, 604 Amylmethyl ketone Me.CO.CHj.CMe3 M 125-130 Butlerow A., 189, 78 34, 125 Me.CO.CHEt,, ) 137-5-139 .... Frankland & Duppa A., 138, 212 vl., 768 1 )! 11 135-137 u.c. Ceresole B., 16, 830 (?) .... 5 182-5 .... Geuther J. F. P., 6, 160 It 11 Me.CO.CEtMe 2 )) 131-5-132-5 Wischnegradsky B., 8, 541 ' 28, 878 1) )1 ) ? 142-146 Schorlemmer 26, 319 vii., 643 Butylethyl ketone Et.CO.CH 2 .CHMe 2 * 132-134 Geuther, Frohlich A., 202, 327 38, 623 and Loos Et.CO.CMe, * 125-5-126 Wischnegradsky B., 8, 541 28, 878 Dipropyl ketone Pr.CO.Pr T) 144 Schmidt B., 5, 597 vii., 228; 26, 892 71 144 .... Chancel A., 52, 296; A. C. 25, 410 [3], 12, 146 1) 1 144-145 Jahn B., 13, 2116 11 11 I J 143-146 Grimm A., 157, 249 24, 387 ,, )> r) 144 .... Friedel J., 11, 295 i., 698 i 139-144 Kurtz A., 161, 207 25, 410 ,, (0 175-185 Freund A., 118, 33 vi., 380 Propylisopropyl ketone Pr.CO.Pr0 )> 137-141 Morgan 28, 304 Diisopropyl ketone Prf.CO.Pr/3 n 124-126 Liquid Munch A., 180, 327 30,67 1) 11 ) u 124-126 .... MUnde B., 7, 1370 28, 247 5> n 129-130 Popoff B., 6, 1255 - () (0 M 135-137 .... Markownikoff 11 ..- (?) (?) jj 145-150 Destrem B., 16, 227 Hexylic formate H.COO.(CH s ) s .Me C 7 H 14 2 146 Freutzch B., 16, 745 44, 1075 Amylic acetate CH 3 .(CH 2 ) 4 .OAc 11 148-4 (737) Lieben and Rossi A., 159, 74; G. I., vi., 1137; vii., 1, 314 8 ; 24, 1034 Isoamylic acetate CHMej.CH2.CHj.OAc 11 140 .... Wauklyn 18, 30 vi., 13 11 )! 1> 11 140 Schorlemmer J. [1866], 527; vi., 13 ; 106 P. R.S., 15, 131 ,, inactive J 11 138-6(743-5) Liquid Balbiano G. I., 6, 229 31, 293 is ... H 11 135-137 Conrad A., 186, 228 32, 435 Amylic acetate C 6 H n .OAc 11 138 Friedel and Crafts J. [1864], 460 vl., 13 isomeric )J 11 135-140 .... Schorlemmer P. T. [1872], 111 vii., 63 i' 11 '> n n 135-140 11 u i) !> 11 137-6 Kopp A., 96 ,, IT n 133-3 Liquid 11 i., 21 I) l> ;j 11 133 Delffs J., 7, 26 ., ,, C H 3 .CH 2 .CH,.CHMe.OAc 11 133-135 Liquid Wurtz A. C. [4], 3, 137 ; vi., 113 Z. C., 11, 490 CHEtj.OAc 11 132 .... Wagner & Saytzeff A, 175, 366 28, 628 )) 1! CHMe 2 .CHMe.OAc 11 125 Liquid Wurtz A. C. [4], 3, 137 vi., 1 13 CMe 3 Et.OAc 11 124-125 .... Coninck C. R., 92, 413 40, 444 11 1> 11 11 125 .... Cahours A., 96 1- 1> 11 11 124-5-125-5 .... Menschutkin B., 15, 2512 )1 11 11 n 124-124-5 Flavitsky A., 179, 349 Butylic propionate CH s .CH 2 .COO.(CH !i )3.CH 3 11 145-99 c. .... Linnemann A., 161, 194; A., 25, 396; vii., 203 162, 39 Isobutylic propionate CH 3 .CH 2 .COO.CHj.CHMe 2 11 135-7 (764) Pierre and Puchot Z. C., 12, 660 ; A. C. [4], 22, 324 M 11 136-8 (760) Schumann G. J. C., 1881 11 11 n 136-8 .... Elsasser A., 218, 302 44, 967 11 n 135-8; .... Pawlewski B., 15, 2463 44, 276 318-7 c.t. Propylic butyrate CH 3 .CH 2 .CH 2 .COOPr a 11 144-3 ; n 11 11 326-6 c.t. 11 M n 143-42 Linnemann A., 161, 33 ; 162, vii., 5(i3, 1013 ; 39 25, 235 11 11 )i 11 142-7 .... Elsasser A., 218, 302 44, 967 11 ii >i 11 139-141 .... Chancel C. R., 68 vi., 964 182 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Propylic butyrate CH a .CH 3 .CH 2 .COOPr C ; H 14 3 137-25 (765) .... Pierre and Puchot C. R, 66, 302 vi., 964 isobutyrate CHMeyCOO.Pr* 11 135-25 .... >i C. R, 75, 1594 ; 26, 260 A. C. [4], 22, 29E 11 ) i 1) 133'9 .... Elsasser A., 218, 302 44, 967 i> >i 11 1> 133-4 ; .... Pawlewski B., 15, 2460 44, 276 316-0 c.t. i -11 ji >1 130-133 .... .... M. C., 2, 689 Isopropylic butyrate. .". CH 3 .CH 3 .CH 2 .COOPr $ 1) abt. 130 Berthelot A., 96 v., 890 (inactive 11 11 128 (755) Liquid Silva A., 153, 135 ; vi., 966 Z. C., 12, 508 i) ) 185-5 .... .... A., 163, 272 ; M. C., 2, 690 isobutyrate CHMe^COOPr 3 11 118- 121 .... M. C., 2, 691 Ethylic valerate CH 3 .(CH 2 ) 3 .COOEt 11 144'6c.(736'5 Lieben and Rossi A., 165, 117 26, 368 11 ij 11 H 144-5 .... Kehrer and Tollens A., 206, 239 40, 411 IT i 11 11 144^145 .... Fitz B., 14, 1084 isovallerate CHMe.,.CH 2 .COOEt ! 755-5 (760) .... Pierre and Puchot C. E., 75, 1594 ; vii., 62, 1200 ; 76, 1332 ; A. C. 26, 260, 1017 [4], 20, 234 >, ,, .... 11 11 134-3 .... Elsasser A., 218, 302 44,967 jj .... 11 >I 135-135-25 c .... Perkin .... 46, 501 11 11 11 134-135 .... Frankland & Duppa A., 160, 266 (758-4) i !) 11 118'5 (760) I. SO Butlerow B., 7, 728; A., 173, 27, 1084; 28, 250 372 Methylic caproate CHMe 2 .CH 2 .CH 2 .COOMe n 150 Liquid Fehling A., 53, 410 i., 744 Heptylic acid (oenanthylic) .... CH 3 .(CH 2 ) 5 .COOH 11 I. f. m. Schorlenimer B., 6, 58 26, 617 11 11 11 11 i) 222-224 c. 10-5 B., 6, 59 j> 11 11 11 11 11 %23-2%4(763) W5 Grimshaw & Schor- 26, 1076 vii., 870 lemmer ij 11 ?i 11 11 223-224 -8 Frauchimont B., 5, 786; A., 165, vii., 646, 869 ; (762-7) 237 26, 55 i 11 11 11 n 223-224 Geuther & Frcihlich A., 202, 288 38, 623 > 11 -V 11 n .... 10-5 Baeyer B., 10, 1286 34,4 11 11 11 i) 222-4 (743-4) 10 Lieben & Janecek A. 187, 139 32, 881 11 11 11 ?) )! 221-223 .13 to 14 Cahours & Dernaray C. R, 89, 331 36, 1037 11 11 11 )1 11 221-225 W. H. Perkin, jun. 43,69 >l 51 11 ! 11 220-225 3> B., 15, 2803 43, 48 j) J) )> )> 11 218-228 .... .... 43, 59 11 ?> * 222-5-223-5 c; W. H. Perkin 45, 484 222-222-5 c. l 11 l> 11 11 220-222 .... Krafft B., 11, 1415 34, 853 11 11 11 11 219-222 u. o. .... Schorlemmer P. T. [1862], 121; vii., 642; 26, [1872], 111 318, 1074 ; 25, 1086 l> l i> 1) 11 218-5-220 Landolt P. A., 117, 379 26, 1074 (756-5) 11 l i) 11 11 219 c. abt. 5 Mehlis A., 185, 358 34, 134 11 11 ! 11 H 218 (726) .... Stoedeler J. p., 72,240; J. 26, 1074 ; iv., [1857], 148 177 COMPOUNDS CONTAINING THREE ELEMENTS. 183 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Heptylic acid (oenanthylic).... CHMePrf.CHj.COOH C 7 H 14 2 220 Geuther, Frohlicb, A., 202, 322 38, 623 and Loos 11 i) D ? 212 Strecker Lehrb., 5, 96 iv., 177; 26,1073 11 11 11 CHMe 2 .(CH 2 ) :l .COOH SIS-SIS Liquid Poetsch A., 218, 56 44,729 11 11 11 CHMe 2 .(CH 2 ) 3 .COOH or 210-213 u. c. Liquid Grimshaw A., 166, 168 26,314; vii., CH 3 .(CH 2 ) 3 .CHMe.COOH 642 )! 11 11 " 11 209-213 .... Schorlemmer 26, 320 vii., 643 11 11 11 " CH 3 . (CH 2 ) 3 .CHMe.COOH 211-213 Hecht and Munier B., 11, 1781 36, 140 11 11 J! 11 811 -5 (745-8) viscid 25 Hecht A., 209, 309 42, 40 11 11 11 CEtjMe.COOH , 207-208 .... Idanoff B. S. [2], 26, 450 31, 454 11 11 1) Probably tertiary 202-203 20-25 Menschutkin A. C. [5], 23, 14 40, 886 11 11 ? 11 148 d. Liquid Tilley A., 39, 160 iv., 177 ; vii., 869; 26, 1072 Methylpropylallylene glycol C 3 H-.OH.CH.C(OH):CHMe 11 195-6 c. 89-5 Morris C. N., 20, 76 41, 172 or C 3 H 7 .CH:C(OH).CH(OH)Me 11 11 +H 2 11 106 11 11 11 (hydrate) Acrolemacetal .... 11 140-145 .... As., 3, 184 Ethylic isobutylic carbonate CO(OEt)(O.CH 2 .CHMe 3 ) C 7 H 14 3 160-1 c. .... Rose A., 205, 246 40, 252 Dipropylic carbonate CO(OPr) 2 156-160 Cahours C. R,. 77, 745 27, 38 11 11 OO(OPra) 2 11 160-165 .... Roemer B., 6, 1102 27,39 11 11 11 168-2 Rose A., 205, 231 40, 252 Propylic ethylglycollate CH 2 (OEt).COOPr 11 166 Schreiner B., 12, 179 ; A., 36, 522 197, 8, 21 Ethylic propylglycollate CH 2 (OPr)COOEt 11 184-5 .... 11 11 11 ethyllactate CH 3 .CH(OEt).COOEt 11 .Z56-5 (757) Wurtz A. C. [3], 59, 174 iii., 464 ,, 11 11 155 Schreiner A., 197, 13, 21 ; 36, 522 B., 12, 179 a-methoxybutyrate.... CH,.CH 2 .CH(OMe)COOEt 11 14$ c. n II 11 11 '" 11 J) 11 159-161 Liquid Duvillier C. R., 88, 598; A. 36, 523 C. [5], 17, 553 Methylic diethoxalate CEt,,(OH).COOMe 11 165 Liquid Frankland & Duppa P. T. [1866], 309; iv., 274 A., 135, 27 Ethylic ethomethoxalate CMeEt(OH).COOEt 11 165-5 Liquid )! 11 11 11 iv., 275 Methylic a-ethoxybutyrate.... CH 3 .CH 2 .CH(OEt).COOMe 11 156-158 .... Duvillier A. C. [5], 17, 540 Ethylic a-oxyisovalerate CHMe 2 .CH(OH).COOEt 11 175 p. d. Liquid Schmidt and Sacht- A., 193, 110 36, 140 leben Ethylic /3- Me 2 .C(OH).CH 2 .COOEt 11 180 .... A., 197, 73 Isoamylglycollic acid CH 2 (OC 5 Hu).COOH 235 Liquid Siemens J. [1861], 449 ii., 917 a-Ethoxyisovaleric acid CHMe 2 .CH(OEt).COOH 11 .... 91-92 .... vii., 883 Hydroxyheptylic acid CH 2 (OH).(CH 2 ) 5 .COOH 59-60 Helms B., 8, 1169 29, 374 u 11 CH 3 (CH 2 ) 4 .CH(OH).COOH 11 .... 65 Ley B., 10, 231 32, 310 Hydroxyisoheptylic acid C 5 H U .CH(OH).COOH 11 .... 60-5 Frankland & Duppa Z. C. [1866], 492 iv., 276 Diethylethylenelactic acid .... 11 38-39 .... J. p. [2], 23, 196 0- .... CEt 2 (OH).CH 2 .COOH see J. p. [2], 71-73 (?) Schirokoff B., 12, 2375 38, 382 23, 196 Ethylene monoisovalerate .... CH 2 (OH).CH 2 (O.OC.CH 2 .Prf) 11 abt. 240 .... Lourengo A, 114, 123 Butyringlycerin C 3 H 5 .(OH) 2 .(O.C 4 H 7 O) C 7 H 14 O 4 Liquid 40 Berthelot A. C. [3], 41, 261 i., 696 Bornesite C ? H 14 O 6 175 Girard C. R., 73, 426 24,915; vii., 206 200 C. R., 77, 995 27, 170 11 Methylether of dambose 11 175 .... Z. C. [1871], 335 Amylethyloxide CHMej.CHMe.OEt C 7 H 16 102-103 (742) Liquid Reboul & Truchot C. R, 64, 1243 ; vi., 113 A., 144, 244 Isoamylethyloxide ... CHMe 3 .CH 2 .CH.j.OEt 11 112 Liquid Williamson 4, 103, 234 ; A, i., 205; ii., 537 77,37 11 11 11 111-113 Guthrie A., 81, 79 11 " 11 112 Reboul & Truchot A., 105, 37 vi., 113 11 112 113 Harting J. p. [2], 23, 461 40, 794 184 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Heptyl alcohol CH 3 .(CH 2 ) 5 .CH 2 OH C 7 H 10 179 Wills 6,307 iii., 146 it >J 1) 178-5 .... Petersen A., 117, 69 i) ji )> 19 177-177-5 .... Stadeler J. p., 62, 241 j, .... >J > 175-5-177-5 c. Liquid Grimshaw & Schor- 26, 1081; 27, 1030 vii., 644, 868, (766) lemmer 1025 " > 175-5 (764-1) Liquid Cross .... 32, 125 it > > > 170-178 .... Schorlemmer A., 161, 279 25,411;vii.,229 J> " > ) 174-176 Perkiu .... 43,87 ,, )) 175-177 c. .... .... 45, 472 )> > )) 170-175 .... Schorlemmer P.R.S.[1872], 121 vii., 642 ; 25, 1086; 26,318 CHMe 2 .(CH 2 ) 3 .CH 2 OH or JJ 165-170 .... n 26, 320 vii., 643 CH 3 .(CH 2 ) 3 .CHMe.CH,,OH ) 164 .... )i P. R. S., 14 vi., 696 ,, ,. > >J 165 Grimshaw 26, 313 vii., 642 J ) 165 .... Bouis and Carlet A. C. [3], 44 iii., 146 ,, )J 165 .... > A., 124, 352 26, 1081 ,, U ) 165-5 Schorlemmer P. R. S., 14 vi., 696 ,, > t 164-5 )) vi., 64, 696 (from different ) )) 163-165 ; .... A., 136, 257 sources) 164-167 ; 163-168 ; 164-5 CH 3 .(CH 2 ) 4 .CH(OH).CH 3 )) 160-162 Schorlemmer 26, 319 ; P. T. vii., 229, 642 ; [1872], 111 25, 411,1086 > i I 155-160 .... Faget A., 124, 355 iii., 146 .... .... > >J 155-158 .... Morgan A., 177, 308 28, 305 * 155-157 Schorlemmer P. T. [1878], 1 32, 866 n v H )> 155-5 .... .... 28, 209 ,, ,, CHMe 2 .CH 2 .CH 2 .CH(OH). J 148-154 Purdie .... 39, 467 CH 3 ,, ) )) 148-150 Schorlemmer 26, 320 vii., 643 ji }> .... .... >j > J 148-150 1. - 16 Kohn A., 190, 305 34, 468 ,, .... .... !) II n 146-148 .... Grimshaw A., 166, 169 vii., 642 ; 26, 313 j j) .... .... C 4 Hj.CH(OH).Et 140-141 .... .... A., 177, 308 ; J. p. [2], 26, 109 >, CHMe 2 .CH,,.CH(OH). Et ; 146-148 Wagner B. S. [2], 36, 306 42, 377 T >J Pr.CH(OH).Pr > 149-150 .... Kurtz A., 161, 205 vii., 228, 1025 ; 25, 411 )> )1 Pr.CH(OH).Prf 140-141 Morgan A., 177, 308 28, 304 Prf>.CH(OH).PrS i 131-132 Liquid Munch A., 180, 334 30, 68 ), ) 130-131 Liquid MUnde B., 7, 1370 28, 247 > ) '" ".. CEt,OH j 140-143 1. 20 Nahapetian Z. C. [2], 7, 274 24, 1035 ; vii., 1182 jj 141 Ladenburg A., 164, 300 26, 50 ,, ,, .... .... CHMe 2 .CH 2 .C(OH).Me. 2 139-131 1. 20 Pawlow B., 7, 729 27, 1076 ,, (?) )! 130 .... Markownikoff Z. C. [2], 7, 263 24, 1028 ,, 1) )1 130 .... A., 173, 192 ,, ,, .... .... CHMeEt.C(OH).Me 2 >1 138-140 (750) Liquid Kaschirsky C. C. [1881], 278 42,37 ,, J) 138-140 I. 30 M B., 11, 985 36, 46 ,, ,j .... .... CMe 3 .C(OH).Me 2 )' 131 17 Butlerow A., 177, 176 28, 1249 ,, ,, 11 ) 131-132 17 n B., 8, 166 (hydrate) .... +iH 2 ) .... 83 51 B., 8, 165 i j) )) n )> )t 83 Kaschirsky B., 14, 2065 )) )) D 81 Bogomolez B., 14, 2066 JJ " CPrEtMe(OH) 135-138 Liquid Pawlow B.,9, 1311;C.G, 31, 58 ; 32, 732 76, 770 ; A., 187, 104 11 )) CPrPEtMe(OH) n 124-127 .... n J) )) D tertiary i) 123-132 .... .... Z. C. [1871], 269 1 COMPOUNDS CONTAINING THREE ELEMENTS. 185 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylpropyl acetal CH 3 .CH(OEt)(OPr) C 7 H 16 2 124-126 .... Bachmaun A., 218, 38 44, 727 Methylbutyl acetal CH 3 .CH(OMe)(OC 4 H 9 ) j) 125-127 .... Propylidene acetal Et.CH(OEt) 2 93 Liquid Gramont C. R., 97, 173 46,35 Dimethyl valeral C 4 H 9 .CH(OMe) 2 124 .... Alsberg J., 17, 486 v., 974 Trimethylethyl glycol CM e2 .OH.CMeEtOH 177 Wurtz A., 179, 340 29, 545 Triethylic orthoformate CH(OEt) 3 C 7 H 16 3 145 .... Pinner B., 16, 1643 44, 1089 ,, 144 .... B., 16, 356 1! 1) H 145-146 1. - 18 Williamson & Kay P. R. S., 7, 135 ; vi., 622 A., 92, 347 ,, .. n 146-148 1. - 18 Ladenburg and B. S. [2], 9 ; A., J Wichelhaus 152, 164, 356 , 145-147 .... Deutsch B., 12, 116 36, 453 Diethyl glycerol (diethyline) C 3 H 6 (OH)(OEt) 2 abt. 191 .... Berthelot J., 7, 450 Methylpropylallylene glycol C 7 H 12 (OH) 2 .H 2 O .... 106 d. Morris 41, 172 Phthalic anhydride C 6 H 4 .CO.O.CO=l-2 C 8 H 4 3 105 Laurent A., 19, 42 iv.,631;vi.,944 i __i )> 275 .... Troost G. J. G, 1879 277 .... Gnebe B., 5, 15 25, 295 .... . ji 275 Solid Ador A., 164, 229 vii., 979; 86,00 ., jj 127 A. G [4], 26, 417 26, 393 , n .... 127 Anschiitz B., 10, 326 276 127 H B., 10, 1881 34, 136 ,, ., 1! .... 128 Hermann vi., 944 . .. M 276 128 Lessen A., 144, 47 1! I! 275 127-128 Carius G. J. G, 1868 994 V ) .... 128 A. J. Smith .... 35, 791 ,, ) 11 .... 128 Piccard A., 196, 48 .... .... 129 Graebe and Born .... vi., 944 .... ,. .... 128-5-129-5 Japp and Miller .... 39, 223 Hydroxyphthalic anhydride C 6 H 3 (OH).CO.O.CO=1.2.3 C 8 H 4 4 .... 145 Jacobsen B., 16, 1962 44, 1124 !> )' = 1.3.4 165-166 Miller B., 11, 1193 34,983 >, ,, s. b. 200-210 165-166 Baeyer B., 10, 1082 32, 785 Coumarone C 6 H 4 .CH : CH.O G,H B O 168-5-169-5 1. 18 Fittig and Ebert A., 216, 169 44, 474 I 6 4 1 x -'8'"6 Benzacrylic acid C 6 H 6 .C.COOH C 8 H 6 2 101 Pfankuch J. p. [2], 6, 97 26, 363 Isotoylic aldehyde meta- 199 Liquid Gundelach B. S. [2], 26, 43 30, 514 Hydroxyphenylaeetic lactone C,H 4 .CHj.CO.O=1.2 237 49 Baeyer and Fritsch B., 17, 973 46, 1022 1 t Oxymethylbenzoic anhydride C 6 H 4 .CH 2 .O.CO=1.2 65 Kolbe and Wischin 19, 339 vi., 81, 943 i i n .... 67 i Z. G [2], 2, 315 34, 66 ). !, 5) H .... 73 Hessert B., 10, 1445 ; 11, 238 Isophthalic aldehyde C 6 H 4 (COH) 2 =1.3 n .... 88 Grimaux G R., 83, 825 31, 206 Terephthalic aldehyde =1.4 .... 114-115 .... (C 8 H 6 O a ). .... 170-174 Phenylglyoxylic acid C 6 H 5 .CO.COOH C 8 H 6 3 65-66 Claisen B., 10, 844 32, 616 j) .... 65-66 ,, B., 10, 430 32, 423 Jl .... 111 Hiibner & Buchka B., 10, 479 32, 485 Salicylglycollic anhydride .... C 6 H 4 .CH(OH).COO i i crystalline Ploschl B., 14, 1317 42,515 Piperonal C 6 H 3 (COH).O.CH 2 .O=1.3.4 i i 263 37 Fittig and Mielck A., 152, 36 vi., 948 j3-Hydroxyisophtha!aldehyde C 6 H 3 .OH.(COH) 2 =1.2.6 .... 88 Voswinckel B., 15, 2023 44, 190 "- =1.2.4 108 B., 15, 2022 Phthalic acid .. .... .... C 6 H 4 .(COOH) 2 =1.2 OHO 1 -7Q T ' V, A., 183, 225 31, 601 Vy 8- E1 6 v ^4 .... i . ' i jU ' oei'mann Iftfi P G. J. G, 1868 " " .... 1OJ 1 ". A 1 On Z. C. [2], 4, 705 vi., 941 1! " 1 i \J 1 Ov/ 1 00 T " j T^-n 39, 223 >J .... 1O.6 PP ''I ill .Mil KM JO/ T A., 144, 71 vi., 941 " " " .... 188 B., 6, 377 26, 1133 I) 186 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Phthalic acid (perfect crystals) C 6 H 4 .(COOH) 2 =1.2 C S H 6 4 .... 213 Ador G. J. G, 1872 (ditto powdered) .... 203 Isophthalic acid =1.3 275 Ador & Oppenheim Z. G [2], 7, 22 24, 131 11 11 a, 300 Petersen B., 6, 377 26, 1133 a. 300 Fittig and Velguth Z. C. [2], 3, 526 vi., 942 11 11 a. 300 Meyer A., 156, 265 vii., 134, 978 11 11 .... 310-315 Tilden 45, 46 11 11 11 11 .... a. 320 Korner & Monselise G. I., 6, 133 31, 81 ferephthalic acid =1.4 .... n. f. .... .... v., 725 11 i> 11 11 D .... n. f. MM .... vi., 942 11 11 .... n. f. a. 300 Petersen B., 6, 377 26, 1133 11 11 s. w. m. Carnelley 29, 19 n 11 .... n. f. 11 .... 32, 658 Hydroxyphenylglyoxylic acid O fi H 4 (OH)(CO.COOH)=1.2 43-44 Baeyer and Fritsch B., 17, 974 Piperonylic acid .... C 6 H 3 (COOH).O.CH.,.O=1.3.4 " sb. b. 227 227 Fittig and Remsen 11 11 A., 159, 139 ; Z. C. [2], 7, 289 Z. G [2], 6, 101 vii., 984; 24, 936, 1051 vi., 949 11 11 11 11 n .... 229 Jobst and Hesse B., 11, 1031 34, 733 A Idehydo-hydroxybenzoic COOH.OH.COH=1.3.6 d. Liquid Tiemann and Land- B., 12, 1340 acid shoff 11 n 11 =1.2.3 166 Reimer & Tiemann B., 9, 1273 31, 83 11 11 11 n 179 11 11 B., 10, 1565 ; 12, 34, 227 1341 i 11 n = 1.3.4 .... 234 Tiemann and Land- B., 12, 1335 36, 928 shoff :i 11 11 =1.4.5 243-244 Reimer & Tiemann B., 9, 1274 ; 10, 31, 83 1567 ; 12, 1340 11 11 11 =1.2.5 M.. 248-249 11 11 B., 9, 1271 ; 10, 11 1564 ; 12, 1340 Resorcyl dialdehyde.... (OH) ? .(COH) 2 =1.3.?.? 11 127 Tiemann and Lewy B., 10, 2211 34, 423 Hydroxyphthalic acid (COOH),,.OH=1.2.4 C 8 H 6 6 177-180 Jacobsen B., 14, 42 40, 599 i, 11 11 abt. 180 Baeyer B., 10, 1079 32, 785 11 11 11 11 11 180 Goldsclimidt and M. G, 3, 135 42, 617 Herzig 11 11 11 11 180 d. Miller B., 11, 1193 34, 983 i. 11 11 11 181 Schall B., 12, 833 36, 794 11 ,i =1.2.3 11 .... 200 Jacobsen B., 16, 1962 44, 1124 Hydroxyisophthalic acid .... =1.3.2 239-240 Hesse B., 10, 2195 11 .... 11 11 ,, 239 Schall B., 12, 832 36, 794 11 ,i -. 11 11 11 .... 240-243 Jacobsen B., 11, 902 11 ,i .... 11 11 243-S44 Tiemann & Reimer B., 10, 1570 34, 228 11 i = 1.3.4 270-280 Ost J. p. [2], 14, 103 30, 522 11 .. 11 11 283-285 c. Jacobsen B., 11,378, 898 34, 583 .... 11 11 283-284 Ciamician W. A. ?, 346 40, 247 .i 11 - 11 11 298-299 c. Isles and Remsen B., 11, 580 11 11 - i) 11 >i .... 300 Tiemann & Reimer B., 10, 1572 34, 228 11 11 11 .... 305-306 u.c. Schall B., 12, 833 36, 795 11 11 = 1.3.5 288 Lonnies B., 13, 705 40, 50 i. i, - " 11 284-285 Heine B., 13, 495 38, 549 11 11 - 11 11 280 Goldschmidt and M. G, 3, 131 42, 617 Herzig Hydroxyterephthalic acid ... =1.4.3 H n. f. 280 Schall B., 12, 832 36, 794 11 11 - 11 11 s. w. m. De la Rue and A., 121, 90 ; B., Miiller 12, 1341 11 " 11 11 .... s. w. m. Burkhardt B., 10, 145 11 11 11 11 .... s. w. m. Jacobsen B., 11, 381, & 571 11 i, - 11 11 .... s. w. m. Tiemann and Laud- B., 12, 1336 shoff 11 11 - " 11 B d. 340 Earth and Schreder B., 12, 1260 ... 'i 11 " n. f. a. 300 Schall B., 12, 830 36, 794 COMPOUNDS CONTAINING THREE ELEMENTS. 187 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Hydroxyterephthalic acid ... (COOH) S ,OH=1.4.3 C 8 H 6 5 .... n. f . a. 300 Tiemann B., 12, 1341 i i 11 11 s.w.m. a. 300 Remsen and Hall A. C. J., 2, 50 42, 186 11 D i> 11 IT n. f. 330 Fischli B., 12, 621 36, 639 Noropianic acid COOH.(OH) 3 .COH=1.3.4.? 171 c. Wright J. [1877], 770 32,547 Isonoropianic acid =1.3.4.5 a 240 d. Tiemaun and Men- B., 10, 400 32, 488, 547 delsohn Resorcinoldicarboxylic acid... (OH) 2 .(COOH) 2 =1.3.4.6.(?) C 8 H 8 6 192 d. Tiemann and Lewy B., 10, 2212 p~ i> 11 =1.3.5.! .... 250 p. d. Senhofer& Brunner W. A., 80, 504 ; 40, 266 81, 430, 1044 n- i. 11 = 1.3.4.? 276 11 11 40, 265 ( fallocarboxylic acid (OH) 3 .(COOH) 2 =1.2.3.4.5 C 8 H 6 7 270 d. 11 D M.C.,1,468;4,181 40, 267 Toluic aldehyde C 6 H 4 .Me.COH=1.2 C 8 H 8 200 Liquid Rayman B. S. [2], 27, 498 32, 894 11 11 =1.3 198 .... Etard A. C. [5], 22, 218 40, 582 n 11 11 11 200 Liquid .... vi., 1108 ii 200 Etard C. R., 90, 534 38, 468 11 11 =1.4 S04 Liquid Cannizzaro A., 96, 216 v., 864 11 n 204 .... A., 124, 254 Phenylacetaldehyde C6H5.CHj.COH 192-193 10 Etard A. C. [5], 22, 248 40, 582 D 193-194 .... A., 119, 254 205-207 d. Liquid Radziszewsky B. y 9, 372 30,78 Phenylmethylketone (benzo- phenone) Ph.CO.Me 11 199 Schmidt & Fieberg B., 6, 498 27, 75 11 11 198 Friedel J., 10, 270 11 . 11 199-200 Popoff B., 4, 720 24, 1057 ; 4<, 990 i, 11 abt. 200 16-17 Friedel & Balsohn B. S. [2], 35, 54 40, 279 11 11 ,, .... 20-5 Stsedel and Klein- B., 13, 836 38, 659 schmidt Styrolene a-pinacolin CHPh.O.CH. i i ' n 260 (50) Liquid Breuer and Zinck6 B., 11, 1402; A., 34, 886 216, 301 Phenoxyethylene CH 2 : CH.OPh n 170 Liquid Henry C. R., 96, 1233 44,803 Phenylethylene oxide (polymer) (C 8 H 8 0) n .... 171 Plochl B , 16, 2815 46, 605 Tolylene anhydride 1J a. 275 Grimaux C. R., 73, 1383 25, 136 Condensation product 11 .... 300 A., 155, 343 Furfuroquartenylic acid .... C 8 H 8 2 107 Schmidt B., 14, 575 40, 573 Furfurocrotonic aldehyde .... C 4 H 3 O.CH:CH.CH 2 .COOH(?, 11 .... 121 (111) Kurfui-ylidene acetone C 4 H 3 O.CH : CH.CO.Me 11 135-137 39-40 Claisen B., 14, 2469 ; see 42, 513 (33-34) B., 14, 1459 Phenylic acetate CH 3 COOPh 1) 188 Scrugham J., 7, 605 11 ! 1) 190 Liquid 7,241 i., 24 11 11 * 11 190-194 .... Guareschi G. I., 3, 398 27, 262 51 193 Liquid Perkin&Hodgkinson 37, 467 200 Liquid Broughton 18, 21 vi., 18 Methylic beuzoate C 6 H 5 .COOMe 196 .... Ramsay .... 39,64 198-5 (761) ; Liquid Kopp A., 94, 307 i., 552 199-2 (74G) Liquid 1) 199-2 Buff 44, 990 n 11 1) 198-75 Scharling G. J. C., 1856 D 11 198-5 .... Duinas and Peligot A. C. [2], 58, 50 Benzoyl carbinol C 6 H 5 .CO.CH 2 OH 1) .... 86 Huna'us and Zincke B., 10, 1487 34, 224 11 11 11 (?) 202-203 .... Emmerling& Englei B., 6, 1006 11 11 84 Humiius B., 10, 2010 (hydrate) .... n 11 73-74 .... A., 216, 303 11 11 11 75 Hunnius B., 10, 2010 (i-Toluic acid (phenyl acetic) C 6 H 5 .CH 2 .COOH .... 76-4 Schiff G. I., 14, 181; A., 46, 1089 223, 24 11 11 11 11 ri 76 Zincke B., 2, 738 11 11 11 11 rt 76-5 Slawik B., 7, 1053 - V 1. 11 11 .... 75-5 Barbaglia B., 5, 270 25, 490 11 11 11 11 11 262 u. c.= 76-5 Mbller & Strecker J., 12, 299 v., 863 265-5 c. 2 B 2 188 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. a-Toluic acid (phenyl acetic) i> J> )) ? u TJ ) > JJ JJ ' I> Toluic acid (mixture) > CeHj.CH^COOH > > I) }> C 6 H 4 .Me.COOH=1.3 )> )) =1.2 J > I> J) J> )J )) = 1.3 ) )> ) ) ) J )> 1J > J> )J = 1.4 )> >! !> !> I) ;> 11 )! ) T) !> 11 J) !> !> !> !I " l I) ) ) >' )) > J) C 6 H 4 .OMe.COH=1.2 .) C 8 H 8 2 )> J) T) I) )J J) )) )) )> )) J )) )) )) J J> )> )> >J ) I )J )) J) N )j ?j )) j) 264=275 c. C 8 H 3 2 J JJ )J ) ?J ) 1> 263 274-275 230-233 u. c. 238 75 76 76-76-4 76 76-5 76-77 85 90 90-93 90-93 102 102 102 102 102 102 102-5 104-105 105 105 105 105-106 106 105-106 108-109 109 109-110 109-5 110 110 a. 100 173-176 175-175-5 175 175-176 175-176 176 176 176 176 176 176 176 176 176 176-177 =178-179 c. 177 177 177 177 177 177-178 178 180 Liquid Liquid Salkowski Krant Hodgkinson Radziszewsky Weddige Tawildarow Wurtz Bieber and Fittig Ahrens Bieber and Fittig Ador and Eilliet Ramsay and Fittig Weith Merz and Weith Kekule Jannasch & Hiibner Fittig Etard Bruckner Bottinger & Ramsay Richter n Tilden Bottinger Weith and Landolt Jacobsen Ador and Rilliet Gerichten Kekule Bechler Kekule & Fleischer Merz Fittig Wurtz Landolph Tilden Kekule Jannasch & Hiibner Bottinger & Ramsay Nietzski Bruylants Beckett and Wright Fittica ? Hempel Merz and Weith Weith Gerichten Ador and Craffts Homeyer Fischli Japp & Streatfield Perkin B., 12, 649 B., 12, 701 A., 148, 242 B., 9, 372 J. p. [2], 7, 99 Z. G, 6, 419 C. R., 70, 350 Z. C. [6], 496 Z. C. [2], 5, 102 Z. C. [2], 6, 496 B., 12, 2301 Z. C. [2], 7, 584 A., 168, 242 B., 7, 723 B., 10, 752 B., 7, 1007 Z. C. [2], 7, 706 ; A., 170, 117 B., 5, 954 B., 5, 268 A. C. [5], 22, 218 B., 9, 406 A., 168, 253 B., 5, 426 45, 416 A., 168, 253 B., 8, 720 B., 14, 2347 B., 12, 2300 B., 9, 258 B. S., 2, 46 J. p. [2], 8, 167 B., 6, 1087 Z. C. [2], 4, 33 C. R., 68, 1298 B., 5, 267 B., 6, 437 Z. C. [2], 7, 706 A., 168, 253 A. P. [3], iv., 317 J. Ph. [4], 26, 393 A., 172, 303 ? A., 180, 71 B., 10, 746 B., 6, 421 B., 10, 1251 B., 10, 2176 A. P. [3], v., 293 B., 12, 615 A., 145, 302 36, 814 37, 482 30, 78 26, 1241 25, 692 n vi., 1100 vii., 1175 vi., 1100 25, 491 ; vii., 1174 27,68 32, 602 28,64 vii., 1208 ; 27, 258 26, 277 vii., 1175 40, 582 30, 86 27, 69 25, 692 ? 27,69 42, 185 v., 862 30,78 v., 862 27, 472 27,65 vi., 1100 25, 473; vii., 1175 33, 251 26, 889 vii., 1208 27, 69 27, 892 34, 158 29, 5 28, 60 29, 921 32, 602 34, 49, 787 34, 405 29, 244 36, 638 41, 153 20, 419 ; vi., 1008 > .... .... j> j> .... j> * .... .... (cryst. from water) (sublimed) > >, .... .... 5, ,) jj j> J) .... .... j> .... .... .... j, ,, .... .... .... j, jj .... Methoxybenzaldehyde COMPOUNDS CONTAINING THREE ELEMENTS. 180 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methoxybenzaldehyde C e H 4 .OMe.COH=1.2 C 8 H 8 O 2 .... 35 Voswinckel B., 15, 2024 44, 190 .... =1.3 230 Liquid Tiemann & Ludwig B., 15, 2048 44, 189 =1.4 jj 247-^48 Koasel A., 151, 25 vi., 174 (783-5) ,, .... JJ 11 jj 248 .... Tiemann &Herzf eld B., 10, 63 32, 893 JJ JJ jj 250 u. c. .... Biicking B., 9, 528 3J ) jj 253-255 Liquid Cahours A. C. [3], 14, 484; i., 307 23, 354 Hydroxytoluic' aldehyde Me.OH.COH=? 206-208 Liquid Barbier B. S. [2], 33, 52 38,468 i) =1.2.3 jj 208-209 17 Tiemann & Schotten B., 11, 772 =1.3.4 jj 222-223 54 j> jj B., 11, 773 34, 876 !> )) = 1.4.5 jj 217-218 56 jj jj j) 1) II =1.3.6 j 110 u j> J) )) = 1.2.5 jj 115 jj jj B., 11, 772 JJ )> " =' jj 120 Barbier B. S. [2], 33, 52 38, 468 Xyloquinone (phlorone) C 6 H 2 .Me 2 :O 2 =? j .... 60-62 Boumier & Bouilhon C. R., 55, 214 iv., 496 ; vi., 928 = 1.4.2.5 jj a. 100 Von Had A., 151, 158 vi., 928 I) H )J JJ jj .... 123-5 Carstanjen J. p. [2], 23, 421 42, 612 ;l JJ JJ J> jj .... 125 JRoumier& Bouihlon C. R. [55], 214 iv., 496 !) II JJ ) sb. 125 125 Nietzki B., 13, 472 ; A., 38, 553; 44, 215, 168 467 ? acid C 8 H 10 2 (?) jj 176 Salkowski B., 8, 1462 29, 599 Phenoxyacetic acid CH 2 (OPh).COOH C 8 H a 3 285 p. d. 96 Fritzsche J. p. [2], 20, 267 38, 319 Phenylglycollic acid CHPh(OH).COOH JJ .... Liquid Ploschl B., 14, 1316 42, 515 (man- JJ JJ 115 Miiller A. P. [3], 2, 385, 26, 1038 delic) 389 > jj jj )J JJ .... 115-118 Breur and Zincke B., 13, 635 38, 645 jj jj n JJ JJ .... 117-118 Claisen B., 10, 847 j jj JJ J5 J) 118 Wallach A., 193, 38 )> ) J .... 118 Lewkowitsch B., 16, 1565, 1568 44, 1124 Paramandelic acid .... .. .... JJ .... 132-8 j> D jj Methylic hydroxybenzoate .... C 6 H 4 .OH.COOMe=1.2 JJ 217 .... Ramsay .... 39, 64 jj jj JJ 218 .... Pettigrew P. J. T. [3], 14, 46, 459 167 jj jj * ) Mi Liquid Cahours A. C. [3], 10, 327 ii., 825 ;v., 161 jj jj JJ .... 224 c. .... A. jj =1.4 JJ 283 17 Ladenburg & Fitz A., 141, 250 vi., 898 Hydroxyphenylacetic acid .... C 6 H 4 .OH.(CH 2 .COOH)=1.2 JJ .... 137 Baeyer and Fritsch B., 17, 973 46, 1021 n u JJ .... 144-5. Will and Lauben- A., 199, 158 38, 266 heimer > =1.4 JJ .... 148 Salkowski B., 12, 650, 1438 36, 659 ; 38, 252 i) >i )) .... 148 Baumann B., 13, 281 38, 649 Hydroxymethyl benzoic acid C 6 H 4 .CH 2 OH.COOH=1.2 JJ .... 118 Hessert B., 10, 1446 34, 66 jj jj =1-4 1) .... 176 + Dittmarand Kekule Z. C. [2], 7, 56 24,376 Methoxybenzoic acid C 6 H 4 .OMe.COOH=1.3 JJ .... 95 Korner A., 142, 352 ; vi., 890 B.A.B.[2], 24,155 i) jj JJ 106-107 Oppenheim & Pfaff B., 8, 887 28, 1262 >j =1.2 JJ 98-5 Grsebe A., 136, 137 vi., 1005 jj JJ JJ 223 .... Kopp A., 92, 315 (anisic) =1.4 JJ .... 173-174 Grsebe A., 139, 147 51 JJ JJ JJ 275-280 >.. Richter TabeUen JJ JJ JJ JJ JJ )J .... 175 Laurent A.,108, 240;R.S., i., 300 106 and 362 11 JJ JJ JJ J> JJ .... 175 Ladenburg A., 141, 241 vi., 172 JJ JJ JJ JJ JJ JJ .... 175 Korner & Corbetta B., 7, 1736 28, 458 JJ JJ JJ JJ JJ JJ .... 175 Landolph C. R., 81, 97 29, 246 J) >J )! >J JJ JJ .... 175 ?j B., 13, 146 38, 385 JJ JJ JJ JJ JJ JJ .... 176 Spica G. I., 8, 406 36, 632 JJ JJ JJ JJ J .... 184-2 c. Oppenheim & Pfaff B., 8, 891 28, 1263 190 ORGANIC COMPOUNDS. Name, Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Tetrahydrophthalicanhydride CHj.CH2.C-CO, I' II >0 CH 2 .CHj.C C(X C 8 H S O 3 68 Baeyer B., 3, 61 ; A., 166, 346 vii., 1149 Methoxyhydroxybenz COH.OH.OMe=1.2.3 u 264-268 Liquid Tiemaim & Koppe B., 14, 2021 42, 55 aldehyde J> I> =1.2.r, jj 247-248 4 Tiemann & Miiller B., 14, 1910 42, 52 )t )> =1.2.4 JT .... 62-63 Tiemann & Parrisius B., 13, 2368 40, 271 (vanillin) =1.4.5 1) .... 76 Gobley J. P. [3], 34, 401 v., 994 > .... 80 Beckett & Wright 439, 289 )T 1J .... 79; 81 Scheibler B., 13, 339 38, 467 ) 280 p. d. 80-81 Carles B. S. [2], 17, 12 vii.,1201;25,708 T) 5J 1 > .... 81 Ciemann&Haarmann B., 8, 1119 29, 113 V J )I >J U .... 80-81 u. c. B., 7, 614 27, 895 J) ^l ) > .... 81 Jannasch & Rump B., 11, 1635 36, 245 ) ) > ) .... 82 Stokkebye J. [1864], 612 v., 994 * > )J .... 80 Lippmanii B., 13, 663 T ) > M 1) 285 Tieruann & Koppe B., 14, 2024 J) =1.3.4 .... 116-117 Wegscheid r M. C., 3, 792 44, 191 (isovaiiilliu) = 1.46 J) .... 153 Tiemann & Parrisius B., 13, 2367 40, 271 Hydroxytoluic acid Me.COOH.OH=l.?6 I> .... 114 Engelhardt and Lat- .... vi., 508 ; vii., schinoff 394, 934 ,, .... = ? .... 115-120 Ihle J.p. [2], 14, 442 31, 708 " =1.3.4 1 148 > J.p. [2], 14, 454 ') J> J .... 148 Vogt B. 2, 284 ; Z. C. vi., 508 PI 5, 577 ,, .... .... u )) t .... 147-150 Engelhardt and Lat- Z. C. [1869], 622 vi., 508 ; vii., schinoff 394 ) i* ) .... 149 Jacobsen B., 11, 377 34, 582 ,, ,, .... .... ; " f \ 151 ) A., 195, 283 36, 531 .... > ) w .... 150-151 jj B., 14, 2356 ,, ,, .... .... 41 1 .... 151 Tiemann & Schotten B.ll,778;12, 1340 34, 877 )) .... 151 Schall B. 12, 821 36, 794 ?i Jj n .... 153 Kolbe & Lautemann A., 115, 203 H.,106;vi.,508; vii., 394 i> .... =1.5.6 156-160 Jacobsen B., 11, 902 J .... 159-160 Ihle J. p. [2], 14, 456 31, 708 .... .. i> )J 159-160 Tiemann & Schotten B., 11, 767 ; 12, 34,876 1341 j> ?i i 163-164 Jacobsen B., 14, 2354 ,, ,, .... .... M M M .... 163-164 Kekul6 B., 7, 1006 28, 64 ; vii., !K)4 n ij )J J) 164 Schall B., 12, 818 36, 794 v .... .... > 169-170 u. c. lies and Remsen B., 11, 462 34, 505 ,, .... . " M M .... 168-173 Engelhardt and Z. C. [1869], 623 vi., 508 ; vii., Latschinoff 394 yj " =1.2.3 ) .... 168 Jacobsen B., 16, 1963 44, 1124 =1.2.4 .... 172 B., 17, 163 46, 745 ,, i) ii 172 > B., 14, 41 40, 599 > ,, .... ... =1.3.6 )) .... 172-173 Schall B., 12, 819 36, 794 * ,, 51 ) 171=173c. Jacobsen B., 11, 898 ,, .... .... > .... 174 D B., 14, 2.331 > " 1 ) 172-173 Tiemann & Schotten B., 11, 777 : 12, 34,877 1340 v * > 170-5-171-5 lies and Remsen B., 11, 891, 1327 36, 52 u.c. ; 174- 175 c. >' V )) 174 e. Rflmsen & Kuhara A. C. J., 3, 424 42, 607 ,, ,, .... ... i )J 174-5 Mahon A. C. J., 4, 186 42, 1205 +|H 3 > 1 .... 148-5-149-B c Remsen & Kuhara A. C. J., 3, 424 42, 607 M " ) )) 146-5-147 u.c lies and Remsen B., 11, 892 COMPOUNDS CONTAINING THEEE ELEMENTS. 191 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Beference. Watts' Diet. & J. Ch. Soc. Hydroxytoluic acid + JH 2 O MeOOOH.OH=1.3.6 C 8 H 8 3 120 Mahon A. C. J., 4, 186 42, 1205 j) =1.4.5 )) 173 Ihle J. p. [2], 14, 461 31, 708 5, .... .... 1 U 173 Tiemann & Schotten B., 11,777; 12, 34, 877 1341 JJ V )1 ) 173 Ciamician W. A., 81, 346 40, 247 ,, ,, )) JJ V 174 Biedermann and B., 6, 324 vii., 394 ; 26, Pike 904 j, v .... .... J5 J i) .... 174 Jacobsen B., 11, 381 34, 583 ,, ,j .... .... ') )J 5? 174=177 c. u B., 11, 570 ! ,, ,, 1 J> .... 176=177 c. Oppenheim & Pfaff B., 8, 889 (seeB.,11,705) JJ >T 183-184 Fittica B., 7, 928 27, 1167 ,, ,, =1.2.5 JJ .... 177-178 Schall B., 12, 820 38, 794 11 it ii 11 177-178 Tiemann & Schotten B., 11, 778 ; 12, 34,877 1340 , .... IT >! ) 179 Jacobsen B., 17, 62 46, 745 15 11 " " V ! 51 179 n B., 14, 40 40, 599 n 11 .... .... = (1) )) 180 Oglialoro G. I., 8, 440 36, 729 1' 1} ' =1.2.6 )J .... 183 Jacobsen B., 16, 1962 44, 1124 11 11 = 1.4.6 198 n B., 11, 381 34, 583 )1 11 .... ?> IJ 202-203 Flesch B., 6, 481 26, 1030 11 11 n 1> .... 202-204 Gerichten & Bossier B., 11, 706 34, 672 11 )! > ii 203-204 u.c. ; IT 11 B., 11, 1587 36, 323 206-207 c. 11 11 " y) )T .... 205 u. c. Remsen and Hall A. C. J., 2, 50 ; 42, 186 B., 12, 1433 ,1 ,, .... = 1.3.5 ) .... SOS Jacobsen B., 14, 2358 42, 193 Ethylene pyrogallate CsH^OHrOjrCjH, n 267 Liquid Magatti B., 12, 1860 38, 250 Piperonyl alcohol .... HO.CH r C 6 H 3 .O.CH n .O >i .... 51 Fittig and Remsen A., 159, 138 vi., 949 ; 24, i * i 936 =1.3.4 Dihydroxyacetophenone CH 3 .CO.C 6 H 3 (OH) 2 =?.1.3 ji 303-305 142 Nencki and'Sieber J. p. [2], 23, 147 40,591 11 =11.4 )j .... 202 > J. p. [2], 23, 537 40, 812 Orcylaldehyde C 6 H 2 Me(OH) 2 .COH=? )> 177-178 Tiemann and B., 12, 1001 36, 720 Helkenberg Hydroxyisoxyleuequinone .... C 6 HMe 2 (OH) : O 2 =1.3.?.5.? )i .. 103 Fittig and Lieber- A., 180, 27 29, 919 mann Fusion of Sinalbin with KHO r 136 Will Z. C. [2], 7, 89 24,408;vii.,832 Acid from teucrin (C 8 H 8 2 2) i 180 Oglialoro G. I., 13,498; B., 46, 332 12, 296 ? j> .... 109-110 MM M. C., 3, 356 Dehydracetic acid CHjAc.C : OH. C 8 H 8 4 269 108-5 Oppenheim and B., 9, 324, 1101 30,70 1 \ Precht C(OH) : C.COOH 11 .... JJ 269*5 108-6-109 Geuther J. [1865], 303 vi., 543 Terebilic acid.... .C(COOH):CH CMe 2 / / .... 169 Roser B., 15, 293 42, 717 \ o CO Hydrophthalic acid C 6 H 6 .(COOH) 2 =1.2 )r a. 200 A., 142, 334 Hydroxymandelic acid [CH(OH).COOH].OH=1.2 ii Liquid Ploschl B., 14, 1317 i 11 = ? )5 162 Z. C. [1870], 85 11 11 = ? IT ... 167-168 Z. P. C., 6, 192 Methylic dihydroxybenzoate COOMe.(OH) 2 =1.3.4 J> 134-5 Meyer B., 11, 129 34, 501 (protocatechu ate ) Methoxyhydroxybenzoic acid COOH.OH.OMe= 2 n .... 99 Grebe A., 136, 124 v., 186 31 ! =1.2.5 )5 143 Tiemann and Miiller B., 14, 1997 42, 53 >1 11 " !> J* .... 141 Korner and Betoni B., 14, 848 :' 11 = 1.2.4 )> .... 151-5 11 B., 14, 847 11 11 " !> 1) 154 Tiemann and Par- B., 13, 2377 risius (vanillic) =1.4.5 )5 .... 207 Matsmoto B., 11, 124 34, 500 5' 1) " >i n .... 211-212 u. c. Tiemann B., 8, 512 28, 1199 V 11 11 j) 211-212 u. c. Tiemann & Reimer B., 8, 516 29, 303 (isovanillic) = 1.3.4 is 236-238 Wegscheider M. C., 3, 348 42, 1207 192 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methoxyhydroxybenzoic acid COOH.OH.OMe=1.3.4 C 8 H 8 4 .... a. 245 Matthiessen and .... 16, 342 (isovanillic) Forster I! I) 11 .... 249 c. Beckett and Wright 29, 300, 305 11 11 1 11 H 249-250 c. .... 29, 296 11 11 ) IJ .... 250-251 c. .... 29, 304 11 1 11 J I 251 c. .... 29, 296, 302 11 11 11 11 ) .... 250 Matsmato B., 11, 125 34,500 >1 11 J ) .... 250 Tiemann and Will B., 14, 964 Hydroxymethylhydroxy- COOH.OH.CH 2 OH=1.2.3 ) 142 Reiiuer B., 11, 792 ; 12, 34, 881 benzoic acid 1341 n =1.2.5 11 d. 160 crystalline n B., 11, 791 ; 12, n 1341 11 =1.4.5 )J .... n. f. 270 i] B., 11, 792 ; 12 1340 Dihydroxy-alphatoluic acid (CH 2 .COOH).(OH) 2 =1.3.4 J .... 127 Tiemann and Nagai B., 10, 207 32, 340 Dihydroxytoluic acid Me.COOH.(OH) 2 = 2 ) .... 151 p. d. .... M. C., 1, 238 (orsel- > == ? 1) 176 d. .... A., 68, 61 ; 117, linic) 311 ; 139,35 u n =? j) 206-210 p. d. .... M. C., 2, 458 11 11 =1.2.(2) 3 I) .... 245 Jacobsen & Wierss B., 16, 1956 44, 1121 Trihydroxyacetophenone CH 3 .CO.C 6 H 2 (OH), .... 168 .... J. p. [2], 23, 151 538 Oxyvanillic acid ... 11 169 Carles B. S., 17, 13 25,708 ;vii., 1201 Acid from hemipinic acid .... .... > a. 245 Matthiessen and P. T., 1863 iii., 142 Forster Ethylic comenate C 5 H 2 2 (OH).(COOEt) C,HA .... 126-5 Mennel J. p., 26, 453 44, 656 11 11 1 ) 126-5 Reibstein J. p. [2], 24, 277 42, 197 n 11 J) .... 135 How A., 80, 65, 88; 19,177; i.,1106 T. E., 22, 225 Ethylcomenic acid C 5 H 2 2 .(OEt)(COOH 239-240 Mennel J. p., 26, 459 44,656 Carbopyrotritartaric acid .... COOH-CHAc.CH C : CH 2 CO O )? .... 230 Harrow 33, 433 11 11 .... 230-231 i A., 201, 152 33, 432 Ethylic hydroxycomeiiate .... C 5 HO 2 (OH) 2 .COOEt C 8 H 8 6 .... 204 Reibstein J. p. [2], 24, 287 42, 197 Diacetyl racemic anhydride.... CO.(CHOAc) 2 .CO.O i i C 8 H 8 7 .... 122-123 Anschiitz & Pictet B., 13, 1178 38, 876 11 11 11 11 .... 126 Perkin As., 5, 289 20, 149 Diacetyl dextrotartaric anhy- M > .... 125-129 AnschUtz & Pictet B., 13, 1178 38, 876 dride )I 11 !) 11 a. 250 d. 126-127 Perkin As., 5, 289 20,149; v.,689 11 11 )) )i 135 .... J. [1861], 368 Furfurobutylene C 4 H 3 O.CH : CH.CH2.CH3 C 8 H 10 153 Liquid Baeyer and Tonnies B., 10, 1365 32, 746 Ethoxybenzene (pheneto'il) .... C 6 H s .OEt )) 172 Cahours J., 2, 425 iv., 391 11 n 11 )> 175 Baly A., 70, 271 Benzyl methyl oxide C 6 H 5 .CH 2 .OMe 167-168 .... .... A., 161, 334; A.C. [5], 10, 23 Benzyl carbinol C6H5.CH2.CH2.OH 11 212 Liquid Radziszewsky B., 9, 372, 461 30, 78 Phenyl methyl carbinol C 6 H 5 .CH(OH).CH 3 5) Z02-204 Liquid 11 B., 7, 141 27, 469 11 n 11 )J 11 202-203 Liquid Emmerling& Engler B., 6, 1006 27, 74 (polymer ?) Phlorol IJ 11 a. 200 p. d. 220 120 11 11 B., 4, 147 A. 102 166 24, 258 vii., 930 11 .... .... .... J) 1 ') 219-220 Liquid Marasse A., 152, 75 vi., 928 Ethylphenol EtOH = 1.2 11 220 210-212 Liquid Liquid Ciamician Oliver! B., 12, 1661 G. I., 13, 263 38, 39 46, 174 .... .... = ? 11 )5 212 Liquid Beilstein & Kuhl- Z. C. [2], 5, 461 vi., 916 ; vii., berg 930 ,, .... .... .... = ? )1 21078 c. 1. 18 Suida and Plohn W. A., 81, 245 40, 268 ,1 = 220 .... Hentschel J. p., 27, 498 44, 1107 - = ? 11 191-215 Liquid Aner B., 17, 669 46, 1002 0- = 1) 206-208 .... .... A.,156,212;M.C., 1, 175 COMPOUNDS CONTAINING THREE ELEMENTS. 193 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylphenol a- o- Methylcresol .... Et.OH = 1.4 jj j OMe.Me 1.2 C 3 H 10 I 209-210; 211 214r-%15 175 47-48 46 Liquid Fittig and Kiesow Beilstein&Kuhlberg ICornfir Z. C. [2], 5, 333 ; A., 156, 254 Z. C. [2], 5, 461 Z C [2] 4 327 vi., 916 vi., 916; vii., 930 vi., 507 175 176 Liquid Oppenheim & Pfaff B 8 888 j) .... .... .... Phloretol = 1.4 JJ JJ )) Iff 174 190-200 Liquid Liquid Cannizzaro Korner G. I., 2, 65 B. S. [2], 10, 468 ; B. A. B. [2], 24, 154 A 102 166 vii., 79 vi., 172, 506 iv. 493 a 200 J., 10, 329 Tolylcarbinol (xylyl alcohol) jj ) 5) JJ )j JJ JJ JJ Xylenol Me.CH 2 OH = 1.2 = 1.3 (?) = ? = 1-4 Me.Me.OH ? )> J> J I) 210 ^5 (740) abt. 220 217 217 214-3 c 54 Liquid t 18 58-5-59-5 Eadziszewsky and Wispek Laubenheimer Cannizzaro B. S., 27, 498 B., 15, 1747 Z. C. [1866], 489 A, 164, 289 A.,124,255;C.B., 54, 1225 Z C [2] 4 232 42, 1283 v., 869 26, 65; vii., 178 v., 869 vi., 1129 ? 212 Liquid vii., 930 1.3.4 211-5 (759-7) Wurtz J.[1868] 459 A C vi., 1129 25, 211-5 (766) [4], 25, 108 B., 11 24 482 34, 411 208 212 1 20 B 11 2053 1 B 13 1558 jj **** *"* *"* ji *"* *** i) **" **** **"* = 1.3.? JJ = 1-2.4 (?) ( ? ) } )) )> 206-5-208-5 215 220 219 220 Liquid Solid Lako Tiemann& Mendel- sohn A, 182, 30 B., 10, 60 A , 152 57 30, 634 vii., 930 1.2.4 223-225 61 Jacobaen B., 10, 1015 32, 600 225 (757) 61 B. 11 28 34, 412 )j ** * ***" JJ 1) 222-225 61 62'5 B., 12, 437 B., 17, 159 36, 641 46, 737 n **** **** **" = ? 156 J) 213-5 216 75 73 Wurtz J. [1868], 459 ; AC. [4], 25, 108 Z. C. [2] 4 232 vi., 1129 ; 25, 482 vi., 1129 j) .... .... .... ij 1 45 J) 211-212 211-5 (762) 74-5 74'6 Jacobsen B., 11, 26 34,412 ,, 55 JJ H 210-211 m 74-5 C?1 )> B., 10, 1014 G. I. [1882] 161 32,600 42, 837 From oil of arnica Phenylglycol (styrolene alcohol) 1) JJ *) Jl Dimethoxy benzene (veratrol) JJ JJ JJ JJ JJ JJ 1) J JJ JJ JJ JJ jj j ;j ,, ,, ,, ,, ,, Ethoxyhydroxy benzene jj j Methoxy benzalcohol C 6 H 5 .CH(OH).CH 2 OH n polymer (?) C 6 H 4 (OMe) 2 =1.2 55 )J J J> )I J> ) = ? =1.3 ) ) J> =1.4 C 6 H 4 .OEt.OH=1.4 C 6 H 4 .OMe.CH 2 OH=1.2 C 8 H 10 2 ) tt n n j !) J) ) ) l JJ JJ JJ 224-225 272-274. (755) 210-220 210-215 205 205-206 204-206 202-205 210-212 814 214-215 246-247 247-5 c. (765) \'i 67-68 123-126 Liquid Liquid Liquid Liquid s. 15 Liquid Liquid Liquid 55-56 66 66-67 s. in CO 2 & ether Sigel WachendorflF and Zinck6 Breuer and Zinck6 Koalle jj Tiemann & Koppe Marasse Beckett & Wright Merck Coninck Tiemann&Parrisius Habermann Hlasiwetz and Habermann Hantzsck Wichelhaus Cannizzaro & Korner A., 170, 345 B., 10, 1005 A., 216, 294 B., 11, 1399 B., 4, 634 A, 159, 244 B., 14, 2017 A., 152, 74 A, 95, 200 B. S. [2], 34, 150 B., 13, 2365 B., 10, 869 A, 177, 341 J. p. [2], 22, 462 B., 12, 1502 G. I., 2, 65 ; B., 5, 436 27, 378 32, 614 34, 885 24,829; vii.,432 42, 54 29, 284 v., 997 40, 269 40, 270 32,475 29,80 40, 166 vii., 79; 25, 1095 2 c 194 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methoxybenzalcohol (anisic C 6 H 4 .OMe.CH 2 OH=1.4 C 8 H 10 2 258-8 c.(760-3 24-25 Cannizzaro & Korner G. I., 2, 65 ; B., 5, vii., 79; 25,1095 alcohol) 436 ) n 248-250 23 Cannizzaro and A., 98, 190 i., 303 Bertagnini Phthalyl alcohol C 6 H 4 (CH 2 OH) 2 =1.2 j? .... 56-62 Hessert B., 12, 646 36, 634 ,, " ,, (?) i) ) 62 Goldenberg B., 7, 286 27, 694 ,, 64-5 Colson C. R, 98, 1543 46, 1000 Terephthalic alcohol (tolylene =1.4 5> .... 112-113 Grimaux A. C. [4], 26, 331 ; 26, 816; vii., glycol C. B., 70, 1363 1209 Homosalicylic alcohol Creosol OH.Me.CH 2 OH=1.4.6 mixture (?) :j 203 105 Schotten Eeichenbach B., 11, 784 Sw. J., 66, 308 34, 877 (?) jj 202-210 Gorup Besanez J., 8, 653 J7 \ / (?) j> 195 Frisch J., 20, 689 )? .... .... ... J) \ / Me.OMe.OH=1.3.4 ji j) 214-216 219 .... Botsch Gratzel M. C., 1, 616 A. P. [3], 20, 605 42, 211 44, 393 >I " i) 219-220 Hlasiwetz A., 106, 354 ii., 105 ?> jj 220-224 Tiemann & Koppe B., 8, 1136; 10, 42, 55 tj >' >j 206; 14, 2024 Methylorcinol =1.3.5 273 Liquid Tiemann & Streng B., 14, 2001 42, 52 Methy Itoluquinol = ? 240-245 72 Nietzki B., 11, 1279 ; 34,869 A., 215, 166 Xyloquinol (hydrophlorone) C 6 H ! ,Me 2 .(OH) 2 .... 212 Nietzki A., 215, 169; B., 44, 467; 38, 13, 472 553 )) >j .... 208 Carstanjen J. p. [2], 23, 429 42, 612 )5 9} .... 125 Pfaff B., 16, 1135 44,918 ) Betaorcinol )* (?) )) (?) .... 120 n. f. 109 Stenhouse B. S., 28, 345 P. M. [3], 33, 30C iv., 215 JJ \'J )J V 1 / 163 Stenhouse & Groves A., 203, 287 37, 398 Terebentilic acid Caffeol J JJ >J 250 p. d. 195-197 90 Personne Bernheimer A., 100, 253 M. C., 1, 459 v., 723 42, 232 Meconoisin J) 88 T. and H. Smith P. J. T. [3], 8, 981 34, 801 ? phenol C s H a O, (?) 5J 176 Salkowski B., 8, 1462 29, 599 Xeronic anhydride V '8"-8 V 2 \'/ CHj.CMe.CO, 1 1 > CH 2 .CMe.C(K C 8 H I0 3 242 c. 1. -18 Fittig B., 9, 117; A., 187, 42 29, 898; 32, 736 Ethylic carbacetoacetate JI 290-295 Liquid Duisberg B., 15, 1387 ; A., 42, 1193 213, 179 Dimethylpyrogallol C 6 H 3 .OH.(OMe) 2 >J 253 51-52 Hofmann B., 11, 334 34,418 Ethylpyrogallol C 6 H 3 (OH) 2 .OEt ) .... 95 Benedikt B., 9, 125 29, 916 ,, .... 95 Hofmann B., 11, 799 34, 870 Vanillyl alcohol C 6 H 3 .OH.OMe.CH 2 OH ) 103-105 Tiemann B., 8, 1126; 9,415 Trihydroxyisoxylene Me 2 .(OH) 3 =1.3.4.U )T 121-122 Fittig & Lieperm aim A., 180, 37 29, 920 (xH 2 0) >I .... 88-89 Diallylic oxalate (COOC 3 H 6 ) 2 C 8 H 10 4 206-207 Hofmann & Cahours J., 9, 585; A., iv., 268 102, 288, 294 Tetrahydrophthalic acid CH 2 .(CH 2 ) 3 .C(COOH) : C .... 96 Baeyer B., 4, 273 24, 373 (COOH) >i it 96-100 A., 166, 346 vii., 1149 j> I! )) 95 B., 3, 62 Dimethoxy dihydroxy benzene C 6 H 2 .(OMe) 2 .(OH) 2 )> 160 Hofmann B., 8, 67; 11, 332 34, 417 Ketolactonic acid CMe.O.CO II \ C(COOH).CHEt )) 181 Young A., 216, 45 43, 175, 179 Bergenitol Glycuvic acid C 8 H 5 (OH) 5 C 7 H 9 O 4 .COOH C S H 10 6 C H, n O 245-247 130 83 Morelli Bottinger C. E., 93, 646 A., 196, 96 42, 159 36, 524 From glyceric acid C 8 H 6 O 4 .2H 2 O v - / 8 10 6 >J 83 5) B., 10, 266 32, 443 Diformyl isomannide [(CHO).CH 2 .CH.CH.O] 2 M 115 Fauconnier B. S., 41, 18 46, 1111 ? acid .... 139 A., 211, 325 Allyletheny 1 tricarboxylic acid (COOH) 2 .CH.CH 2 (C 3 H 6 ). D 151 d. Hjelt B., 16, 333 44, 656 COOH or COOH.C(C 3 H 6 ).CH 2 .COOH COMPOUNDS CONTAINING THREE ELEMENTS. 195 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Dicarbocaprolac tonic acid ... C 3 H 5 .C(COOH).CH,,.COOH C 8 H 10 6 152-153 Hjelt B., 16, 1258 44, 970 6 CO Erythrol tetraformate C 4 H 6 (O.CHO) 4 C 8 H 10 O, 150 Henninger C. R, 98, 149 46, 897 Umbellol OHO 215-216 Liquid Stillman B., 13, 629 38, 670 Camphrene .... .... a 12 a. 240 Chautard J., 10, 483 Ketone from collidine .... 208-209 Liquid Hantzch A., 215, 50 44,84 Ethylic aorbate C 6 H 7 .COOEt C 3 H 12 2 195-5 .... .... A., 110, 137 Diallylacetic acid (CH 2 : CH.CH 2 ) 2 .CH.COOH 219-220 Conrad and Bischoi B., 13, 598 38, 628 ,, > ?1 221-222 Liquid Wolff B., 10, 1957; A., 34, 293 201, 45 i, 224-226 Liquid Reboul C. R, 84, 1233 32,594 Suberen carboxylic acid C 7 H n .COOH 53-54 Dale & Schorlemme A., 211, 119 39, 541 Dipyrotartracetone .... 230 Liquid Bourgoin C. R, 86, 674 34,488 Lactone from bromdipropyl- .... 235-240 Hjelt B., 15, 627; A., 42, 946 acetolactone 216, 75 Ethylic ethylideneacetacetate CH 3 .CH : CAc.COOEt C 8 H 12 3 210-212 .... Claisen B., 14, 346 40, 405 ,, 810 Liquid Claiseu & Matthew A., 218, 170 46, 443 Ethylic acetyltrimethylene CH 2 .CH 2 .CAc.COOEt 193-195 Liquid Perkin B., 16, 2136 46,64 1 1 carboxylate Diallyl oxalic acid (CH 2 :CH.CH 2 ) 2 .C(OH). j 48-5 Saytzeff A., 185, 183 ; 32, 883; 32, COOH B. S., 27, 446 739 Aldol diacetate CH a .CHOAc.CH 2 .COAc (!) C 8 H 12 4 150-160 (20) Liquid Wurtz C. R, 74, 1361 ; 26, 809; vii., J. [1872], 450 39 Butinglycol diacetate C 4 H 6 (OAc) 2 202-203 Henninger B., 5, 1059 Dimethylic tetrylendicar- C 4 H 6 (COOMe) 2 220 .... A., 208, 338; boxylate J. R, 2, 449 Ethylic pyrocinchonate C^HjOj-COOEt 235-240 .... Roser B., 15, 1319 Diethylic maleate C 2 H 2 .(COOEt) 2 abt. 210 .... Tanatar B., 12, 1563 38, 35 225 c. .... Anschiitz B., 12, 2283 fumarate COOEtCH : CH.COOEt u 213-220 Purdie 39, 346 >! j) 214-216 u. c. > j) 218 c. .... Anschiitz B., 12, 2282 218 B., 14, 2790 42,831 , i u 218 (745-7) Laubenheimer A., 164, 299 26,56 218-5 Anschiitz B., 11, 1644 36, 223 ,, 220-225 .... Claus B., 15, 1848 225 Henry A., 156, 178 ,j 225 Hagen A., 164, 294 26,56 Acetated crotonaldehyde .... C 4 H 6 O+Ac 2 O ,, 205-210 J. R, 11, 79 Suberconic acid .... 165-170 Gantter and Hell B., 15, 149 ; A., 211, 120 Hexahydrophthalic acid C 6 H 10 (COOH) 2 =1.2 203-205 Baeyer B., 4, 273 ; A., 24,373; vii.. 166, 350 1149 )! >I 207 Mizerski B., 4, 558 )! ). Terpenylic acid+H 2 O C 6 H 6 (OH) 2 .Me.COOH .... 89 Amthor A. P. [3], 18, 356 42,44 I) 90 Fittig and Krafft A., 208, 71 42,42 90 Hempel B., 8, 357 28, 762 ., n ) .... 90 A., 180, 79 29, 921 From hydrosuberancarboxylic C 8 H 14 4 (?) 100 }ale& Schorlemmer .... 39, 542 acid Acetyl isomannide O.CH.CH.CH 2 .OAc C 8 H 12 5 185-187 (25) Liquid Fauconnier B. S., 41, 18 46, 1111 O.CH.CH.CH 2 .OH From rottlera tinctoria M .... 191 Leube J. [1860], 563 v., 118 Propylethenyltricarboxylic CPr(COOH) 2 .CH 2 .COOH C 8 H, 2 O 6 148 Waltz B., 15, 608 ; A., 42, 948 ; acid 214, 59 44, 46 Iso-propylethenyltricarboxy- CHPr0(COOH).CH(COOH) 2 .... 160 Boser A., 220, 271 46, 423 lic acid Tartrophthalic acid .... H .... 178-180 d. .> A., 166, 355 Ethenyltriacetate C 2 H 3 (OAc) 3 a. 250 A., 100, 115 Diethylic trioxymaleate COOEt.C(OH) 2 .CO.COOEt C 8 H 12 7 Liquid Tanatar B., 13, 1386 38, 875 2 c 2 196 ORGANIC COMPOUNDS. Name. Constitution, Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diallylcarbinol methyl oxide (CH 2 :CH.CH 2 ) 2 CHOMe C 8 H 14 135 .... Ejabinin J. p. [2], 23, 269 40, 404 I) 1> U J! 135-136 Liquid B., 12, 2374; 38, 372 (763-3 r.) J. R., 11, 395 Isoamyl propargyl f xide ft TT s\ OTT O * OTT 140-145 Liquid Henry Rf> 974. 4.^ IfiQ vii 1 OfIS 2K 6 11 2 Jl , -', Zl t ^t, *UU, UVJi VAA., lyUO j *3O, 687 Diallyl methyl jarbinol (CH 2 : CH.CH 2 ) 2 MeC.OH 157 Sorokin & Saytzeff B., 9, 34 29, 695 >i 11 758-4 c. Sorokin A., 185, 169 32, 299 From methylethyl ketone .. .... 11 163-165 Liquid Schramm B., 16, 1581 44, 1079 Bye-product from preparatio .... 167-168 Liquid Pawlow B.,9, 1312 ;B. S. 31, 58; 32, 311; of ketones [2], 27, 27, 263 32, 733 A., 187, 104 Aldehyde from isobutalde- .... 149-151 Fossek M. C., 2, 618 ; 42, 161 ; 43, 94 hyde M. C., 3, 622 . .... 230-231 Liquid (Economides B. S. [2], 36, 209 42,32 (771-6) Hexylene acetate C 6 H u .OAc C 8 H 14 2 145 Destrem B., 16, 229 AJlyldimethylcarbinol acetat (CH 2 : CH.CH 2 )Me 2 .C.OAc i 136 M. and A. Saytzef B., 9, 33 29, 695 >i n 737-5 c. .... A., 185, 155 32, 298 Methylcrotylcarbinol acetate CH 3 .CHOAc.(CH 2 ) 2 .CH : CH 147-149 .... Crow A., 201, 44 33, 54 11 .... 157-158 J. R. [1881], 353 Diallylic acetate C 6 H n .OAc 150-160 Liquid Wort* A. C. [4], 3, 129 vi., 93 ,, 155-165 .... Tollens Z. C. [2], 7, 249 28, 998 Allylic iso-valerate CHMe 2 .CH 2 .COO.C 3 H 5 162 .... Hofmann&Cahours J.,9,586; A.,102 296 Ethylic ethylcrotonate C 2 H 4 : CEt.COOEt 165 Liquid Frankland & Duppa A., 136, 3 18,133;vi.,601 hydrosorbate EtCH(COOEt).CH : CH 2 166-167 Liquid Fittig & Barringer A., 161, 312; 25, 487 ; vii., Z. C. [1870], 425 1092 a-ethyl-jS-methylvalerolactone CHEt.(CHMe) 2 .CO.O n 226-227 Young A., 216, 43 48, 179 y-diethylbutyrolactone _ 228-233 Emmert&Friedrich B., 15, 1852 44, 39 Dibutyryl (C,H,O), 245-260 Liquid Freund A., 118, 37 vi., 380 \^4 7 /Z Hydrosuberancarboxylic acid C 7 H 13 .COOH ji .... Liquid Dale & Schorlemmer A., 211, 119 39, 541 ? ;Me(C 2 H 3 O)CH],,O C 8 H 14 3 80-84 (C 8 H 18 3 ?) Jacobsen B., 4, 216 24, 513 Butyric anhydride (CH 3 .CH 2 .CH 2 .CO) 2 191-193 Linnemann A., 161, 179 26, 395 190 Liquid Gerhardt A., 68, 127 ; J., i., 695 5, 452 H 190 .... A., 87, 155 vi., 378 190 Markownikoff Z. C. [2], 4, 621 vi., 381 Isobutyric ,, (CHMe 2 .CO) 2 O 180-5 .... Z. C. [2], 5, 501 vi., 378 180-181 .... Markownikoff Z. C. [2], 4, 621 vi., 381 Ethylic dimethylacetoacetate CMe 2 Ac.COOEt 184 .... Frankland & Duppa J., 18, 309 vi., 591 ethylacetoacetate .... CHEtAc.COOEt 192-196 .... Saur A., 188, 257 34,27 190-196 Conrad & Limpach A., 192, 153 34, 781 193-195 .... Wislicenus B., 7, 685 27, 884 11 11 190-200 .... Geuther J. Z., 6, 560, 575 vii., 488 195-196 c. .... Frankland & Duppa A., 138, 214; vi., 16 P. T., 1866 .... .... 198 Geuther A. P. [2], 116, 97 Isobutylic acetoacetate CH 2 Ac.COO.CH 2 .CHMe 2 abt. 203 ; Liquid Emmerling and B., 9, 1097 30, 505 202-206 Oppenheim Ethylic a-methyl /3-acetopro- CH 2 Ac.CHMe.COOEt 206-208 Liquid Bischoff A., 206, 323 40, 412 pionate Ethylic /3-acetobutyrate CH 3 .CHAc.CH 2 .COOEt 204-206 .... A., 206, 334 40,413 Propylic j3-acetopropionate .... CHjAc-CHj-COOPr" u 215-216 u. c. 3rote, Kehrer, and A., 206, 222 40, 410 Tollens Ethylic propionylpropionate CH 3 .CH 2 .CO.(CH 2 ) 2 .COOEt 199 lellon and Oppen- B., 10, 700 heim Suberic aldehyde .... 202 p. d. Liquid Schroder A., 143, 34; J. vi., 1040 [1866], 327 Suberyl glycollic acid C 7 H 12 .OH.COOH r> .... 79-80 )ale & Schorlemmer A., 211, 118 39, 541 COMPOUNDS CONTAINING THREE ELEMENTS. 197 Name. Constitution. Formula. Boiling Point, Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dialdane OH,.CH(OH).CH.CH : CH C a H,.O a 137 (20) 139 Wurtz B. S. [2], 24, 100 30,65 CH(OH).CH 2 .CHO 8 14 3 L JJ J 139-140 C. E., 83, 1259 31, 588 Aldol anhydride (CHO.CH 2 .CHMe) 2 O )T 137 (20) 155 C. E., 74, 1361 vil., 39 ; 25, 809 Ethyl mannitol anhydride ... C 6 H 9 Et0 4 C 8 H 14 4 165 (17) Liquid Fauconnier C. E., 95, 991 ; 44,306 B., 15, 3086 Ethylene dipropionate (C 3 H 6 0)O.CH 2 .CH 2 .0(C 8 H 5 210-5-212 c. .... Perkin 45, 505 Butylene diacetate C 4 H 8 (OAc) 2 )) abt. 200 Liquid Wurtz J., 12, 499 v., 739 Ethlene acetobutyrate .... H 208-215 Simpson A., 113, 117 ; J., 12, 488 Ethylic acetoxybutyrate .... jj 198 .... .... A., 142, 373 isobutyryl glycollate (CHMe 3 .CH 2 )O.CH 2 .COOEt j 197-198 Liquid Banff A., 208, 271 40, 1127 butyryl glycollate ... (CH 3 .CH 2 .CH 2 .CH 2 ).O.CH 2 . 5> 205-207 ... A., 142, 372 ; 208, COOEt 271 Dipropylic oxalate COOPr.COOPr 1) 209-211 .... Cahours C. R, 77, 745; 27,38 B. S., 21, 77 ; B., 9, 1610 Diethylic succinate COOEt.CHj.CHj.COOEt ) 214 .... D'Arcet A. C. [2], 58, 291 v., 463 i )) 215-4 Weger A., 221, 61 46,11 ,, J) 816-5 c. .... Perkin 45, 515 ,, I! J> 214 .... Fehling A., 49, 186 ?i ,, M 217-3 c. (748 .... Kopp A., 95, 327 methylmalonate ... COOEt.CHMe.COOEt j 196-5 c. A., 204, 146 )> 5J " 198-5-199-5 c .... Perkin 45, 510 Tetramethyl succinic acid .... COOH.CMe 2 .CMe 2 .COOH )> 95 Hell and Wittekind B., 7, 321 27, 683 Suberic acid ... C 6 H 12 (COOH) 3 120 Bromeis A., 35, 97 140 Dale A., 130, 208 ; 132, 17, 258 )J l> 244 sb. 150-160 140 Arppe ' A., 120, 291 v., 449 J) ) ? abt. 300 140 rr Gantter and Hell B., 13, 1166 38, 875 ,, .... )) )1 )j 140 )> ji B., 14, 1547 40, 891 COOH.(CH 2 ) 6 .COOH (?) 140 Baeyer B., 10, 1286 34,4 a-Isosuberic acid .... 3 170-180 Hell and Mulhausei B., 13, 475 38, 542 - !! )I .... 184-185 v B., 13, 482 38, 543 ft- .... H 110-125 ji ) B., 13, 475 38, 542 ft- >i .... ) 127 B., 13, 482 38, 543 Methylic homoitaconate (te- C 4 H 8 .(COOMe) 2 n 220 Markownikoff and A., 208, 333 40, 1127 trylene-dicarboxylate) Krestownikoff Dialdanic acid CH 3 .CH(OH).CH 2 .CH : CH. i 198 i. v. 80 Wurtz C. E., 83, 1259 81, 588 CH(OH).CH 2 .COOH >i ;> -* ... I! yi 198 (20) 80 B. S. [2], 24, 100 30, 65 From hydrosuberan carboxy- C 8 H 12 4 (?) )> 100 Dale & Schorlemmer 39, 542 lic acid Diethylene diacetate (AcO.CH 2 .CH 2 ) 2 O C 8 H 14 5 245-255 Wurtz A. C. [3], 69, 335 ; ii., 568 J., 16, 489 Diethylic diglycollate O(CH 2 .COOEt) 2 > 240 d. A., 147, 201 ; 149, 95 Ethylic dilactate .... 235 .... Wurtz and Friedel J., 14, 377 Diethylic malate COOEt.CH 2 .CH(OH).COOEt 128-131 (15) .... Andreoni B., 13, 1394 Oxysuberic acid ) 137 Gantter and Hell B., 15, 149 Terpenylic acid C 8 H 12 4 +H 2 )J .... 57-5-58-5 Amthor A. P. [3], 18, 356 42,44 Diethylic dextrotartrate COOEt.CH(OH).CH(OH). C 8 H 14 6 162 (19); 280 Liquid Anschiitz & Pictet B., 13, 1177 38, 876 COOEt (760) Dimethylic mucate .... C 4 H 8 O 4 (COOMe) 2 C,H I4 8 d. 165 A. C. [2], 63, 92 Hydrogen ethylic mucate .... C 4 H 3 O 4 (COOH)(COOEt) )> 100 d. Limpricht A., 165, 253 vii., 827 Ethylmucic acid C 4 H 7 EtO 4 (COOH) 2 )> .... 190 d. iii., 1059 Allylmethylpropylcarbinol (CH 2 : CH.CH 2 )MePr.COH C 8 H 16 159-160 Liquid Semlianizin B., 12, 2375; J. p. 38, 372; 40, (742-8) [2], 23, 263 402 Allyldiethylcarbinol (CH 2 : CH.CH 2 )Et 2 .COH 156 (736-7) Liquid chirikoff & Saytzeff B. S. [2], 31, 67 36, 448 198 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Caprylic aldehyde .... C 8 H 16 171 (760) Liquid Bouis A. C. [3], 48, 99 i., 746 )> 178 Liquid Limpricht A., 93, 242 J) Methyl butyrone C 7 H 13 MeO )) 180 Liquid 11 A, 108, 184 i., 698 Hexylmethyl ketone Me.CO.(CH 2 ) 6 .CH 3 )) 171-171-5 Liquid Stadeler J. p., 72, 246 lii., 1009 !) )! ) JJ 173 Schorlemmer 27, 1029 11 11 ) )1 172-6-173-1 .... Briihl A, 203, 29 (753) 11 11 1 ) 172-173 .... Neison 27, 507 JI J> 171-172 11 27, 842 11 11 n )) 171-172 .... 11 27, 850 11 1 )) 170-172 11 27, 846 11 11 5> )) 172 (760) .... Petersen A, 118, 75 )) I) Me.CO.C,H 13 ) 163-165 Harting J. p. [2], 23, 476 40, 795 )) 11 Me.CO.C 3 H 6 .CHMe 2 208-210 Liquid Poetsch A., 218, 56 44, 729 Aniylethyl ketone Et.CO.C 5 H n 153-155 Liquid Harting J. p. [2], 23, 449 40, 794 ,, ,, Et.CO.CEtMe 2 H 150-5-151-5 .... Wichnegrodsky B., 8, 541; A, 28, 878 178, 107 n I) 145-150 Liquid Lawrenowitsch B., 8, 768; A., 29, 897; 32, 185, 126; B. S. 306 [2], 27, 265 Isopropyl isobutyl ketone .... CHMe 2 .CO.CH 2 .CHMe 2 5> 159-161 (743) 1.-17 Carleton- Williams 35, 130 Isoamyl allyl oxide CH 3 : CH-CHj-OAH,, I) abt. 120 Berthollet and De A. C. [3], 43, 292 i., 142 Luca Octylene oxide .... )) 145 Liquid De Clermont C. E., 68, 1323; vi., 881 Z. C. [1870], 411 From diisopropyl glycol .... ) 120-122 .... Fossek M. C., 4, 663 46,38 >i i> 11 .... ) 260-262 i) )) ) From C 3 H 16 (OH) 2 From isobutaldehyde )J 122-124 .... i> M. C., 3, 624 42, 1279 H )) 262-264 )! )> j Hexylic acetate CH 3 .(CH 2 ) 5 .OAc C 8 H 16 2 168-7 c. .... Franchitnont and B., 4, 823 vii., 646 ; 25, (760 r.) Zinck6 61 11 11 158-160 .... Schorlemmer P. T. [1872], 111 vii., 645 11 11 Methyl propyl etholacetate ? 162-2 .... .... M. C., 4, 33 CH 3 .(CH 2 ) 3 .CH(OAc).CH 3 i 158-160 Schorlemmer P. T. [1872], 111 vii., 645 i 154-157 .... Lieben A., 178, 20 29,60 11 j 146-150 .... Schorlemmer P. T. [1878], 1 32, 866 -,, -ft .... n 156-157 (787) Liquid Wanklyn and Erlen- J., 16, 522 iii., 152 meyer 11 i> From diisopropyl chloride 155-160 Silva B., 6, 147 )1 11 C 4 H 9 .CH(OAc).CH 3 145-155 .... Morgan .... 28, 303 11 11 .... .... C 3 H 7 .CH(OAc).Et )i 149-151 Liquid Coninck C. E., 82, 92 29, 694 11 11 .... .... > 149-151 .... CEchsner B., 9, 193 ,, -" )j abt. 145 .... Cahours & Pelouze C. E., 54, 1245; iii., 152 ; vii., J., 16, 527 645 11 140-145 Buff J., 21, 336 ,, ,, CHMej.C(OAc).Me 2 140-143 .... Friedel and Silva C. E., 76, 226 vii., 982; 26, 489 Amy lie propionate CHg.CH^.COOC^lin i> 155 .... Wrightson J., 6, 439 ji 160-2 Elsasser A., 218, 302 44, 967 Butylic butyrate OH 3 .(CH 2 ) 2 .COO.(CH 2 ) 3 .CH 3 11 165-5 (735-7) Liquid Lieben and Rossi A., 158, 170 24, 522; vii., 216 )1 11 164-77 Linnemann A., 162, 39 ; A., vii., 203; 25, 161, 195 396 Isobutylic butyrate CH 3 .(CH 2 ) 2 .COO.CH 2 .CHMe 2 >! 156-9 Elsasser A., 218, 302 44, 967 ,, 11 >1 156-9 (760) .... Schumann G. J. C., 1881 H 11 150-155 u. c. .... Griinzweig A., 162, 207 vii., 226 ; 26, (722) 374 Butylic butyrate J 2samp]es 11 \ C 3 H-.COOC 4 rI 9 H 11 11 149-5 (758) 149-5 Liquid Pierre and Puchot 11 11 J. Ph. [4], 13, 369 A. C. [4], 22, 326 24, 903 Isobutylic isobutyrate CHMe 2 .COO.CH 2 .CHMe 2 11 148-150 Balbiano G. I., 8, 371 36, 615 31 11 Me 2 .CH,,.COO.CH,,CHMe 2 11 147-5 .... Schmidt G. J. C., 1874 COMPOUNDS CONTAINING THREE ELEMENTS. 199 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Isobutylic isobutyrate Me 2 .CH 2 .COO.CH 2 .CHMe 3 C 8 H 16 2 146-6 (760) Schumann G. J. C., 1881 n 146-6 .... Elsasser A., 218, 302 44,967 CHMej.COO.CHj.CHMe,, 11 144-145 Griinzweig B. S., 18, 125 11 144-147 (722 .... A., 162, 193 vii.,226;26,374 Propylic isovalerate CHMe 2 .CH 2 .COOPr 11 157 (761) MM Pierre and Puchot C.K.,66,302; 76 vi., 964 ; vU., 1332; Z.C., 12 62 ; 26, 1017 660 ; A. C. P [4], 22, 297 H 11 155-9 .... Elsasser A., 218, 302 44,967 Isopropylic isovalerate CHMe 2 .CH 2 .COOPr0 11 142 (756) Liquid Silva A., 153, 136 ; vi., 966 Z. C., 12, 508 Ethylic caproate CH 3 .(CH 2 ) 4 .COOEt 11 166-9-167-3 .... Lieben & Janecek A., 187, 126; A. 32, 879 (738) 170, 94 5 11 165-5-166 .... 11 ji D (735-8) ,, n 11 164-9-165-9 11 11 A., 187, 126 u ii 11 165-5-166 .... Lieben and Rossi A., 165, 118; G.I. 26, 268 ; vii., (735-8) 1,314 250 ,, ,, .... >i 11 164-9-165-9 .... Franchimont and A., 163, 193 Zinckg ii 11 66-5-168-5 c. .... Perkin .... 45, 501 ,, C 5 H n .COOEt 11 162 Liquid Febling A., 53, 399 i., 744 )J "" CHMe 2 .(CH 2 ) 2 .COOEt 11 160-4c.(737) .... Lieben and Pvossi A., 165, 125 vii.,250;26,268. CHMePr.COOEt ii 150-155 .... Kelbe and Warth B., 15, 309 42,711 ,, i) 151-8 .... M. G, 4, 26 )> )1 ) 11 153 .... Saytzeff B., 11,512; A., 34,566 193, 352 CHEt 2 .COOEt 11 151 .... Schnapp B., 10, 1953 34,293 j, jj ) 11 151 .... Frankland& Duppa J., 18, 308 ,, )> it 151 .... Saytzeff B., 11,511; A., 34,566 193, 352 )) 11 151-5 .... Fittig A., 200, 27 88, 376 ,, , T C 5 H,,.COOEt n 120 Lerch A., 49, 212 Methylic cenanthylate CH 3 .(CH 2 ) 5 .COOMe 11 180 .... .... J. [1866], 323 ji )) 11 172-5-173-5 .... Jahours & Demargay C. R., 89, 331 36, 103T Me 2 .CH(CH 2 ) 3 .COOMe 11 166 Liquid Poetsch A., 218, 56 44, 730 ,, CH 3 .(CH 2 ) 3 .CHMe.COOMe CH 3 .(CH 2 ) 6 .COOH 11 156-157 c. 239-241 L 20 s. 7 Hecht labours &Demarcay A., 209, 324 C. R., 89, 331 42, 41 36, 1037 236-238 15 i., 745 236-237 .6-16'5 ^enesse A., 171, 380 i "^w 27, 1155 (761-7) I! 11 235-238 16-17 11 ii 11 (757-8) ,, ,, .... .... 11 11 230-234 16-17 6-17 Zincko Z. C. [2], 5, 56 A., 152, 9 vi., 395 vi., 878 11 236-240 4-15 11 ^eliling A., 53, 401 11 238 1 "*errot J., 10, 353 )! 13 Tischer A., 118, 315 11 211 (338) 5 45, 485 CHMe 2 . (CH 2 ) 4 .COOH 11 236-237 6 ^anzonen G. L, 13, 514 46, 461 11 235-237 16-17 Jurton A. C. J., 3, 385 42, 600- C 6 H 13 .CH 2 .COOH 11 232-234 jUndahl B., 16, 789 CHMe 2 .(CH 2 ) 2 .CHMe.COOH 218-220 . 17 iurton A. C. J., 3, 385 11 18-220 (767) . 17 Villianis J) 35, 128 CHPr 2 .COOH 11 219-5 jiquid Jurton A. C. J., 3, 385 42, 600 CMe 3 .CH 2 . CHMe.COOH 1) 205-218 p. d. jiquid Jutlerow A., 189, 70 34, 124 CMe 3 .CHMe 2 .COOH (?) 11 215 210-230 A., 202, 315 Oxoctenol (alcohol) CMe 3 .CO.C(OH)Me 2 or 11 11 178-178-5 49-5 Jullerow J. R. [1882], 199 CMe 2 .O.C(OH).CMe 3 Isoamylglycidio ether .... 11 188 .... leboul V. C. [3], 60, 59 i., 897 200 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Isobutaldehyde (polymer) .... see C 12 H 24 O 3 C 8 H 16 2 136-138 (18) .... M. C., 2, 623 Isoamylethylic carbonate .... CO.OEt.[O(OH 2 ) 2 .CHMe 2 ] C 8 H 16 3 182-3 c. Rose A., 205, 246 40, 252 Propylic propylgly collate .... CH 2 .(OPr).COOPr* 192 Schreiner B., 12, 179; A., 36, 522 197, 821 Ethylic a-ethoxybutyrate ... CH 3 .CH 2 .CHOEt.COOEt ? 168-174 Liquid Duvillier C. R., 86, 47 ; A., 34, 489 197, 16, 21 i) j? ji JJ 168-5 Schreiner B., 12, 179 36, 522 ethoxyisobutyrate .... C 3 H 6 (OEt).COOEt 155 i) ji diethoxalate CEtjOH.COOEt )) 175 .... H. C. Jones 33, 183 i) 1> 175 .... Frankland & Duppa P.T. [1866], 309; A., 135, 29 Ethylic leucate CEt 2 (OH).COOEt )7 175 Liquid Frankland P. R. S., 12, 396 iii., 578 J) 175-176 (750) .... Henry B., 5, 949 26, 264 Methylic hydroxycenanthy- CH 2 (OH).(CH 2 ) 5 .COOMe )5 160-165 Liquid Helms B., 8, 1170 29, 374 late Acid from isobutylaldehyde .... 5) 75-80 Fossek M. C., 3, 623 42,1279; 43,92 Hydroxycaprylic acid CH 3 (CH 2 ) 5 .CH(OH).COOH ) .... 69-5 Erlenmeyer & Sigel A., B., 7, 698; A., 37, 981 ; 28, 177, 102 1010 .... )J 92 Fossek M. C., 4, 663 46, 38 )J I! CMe 3 .CH 2 .C(OH)Me.COOH )) 107 (117 ?) Butlerow J. R [1882], 199 42,937 )} Pr 2 .C(OH).COOH ) sb. 50 ' 80-81 Woronzoff J. R., 13, 237 J) Pr/.qOHJ.COOH )) .... 110-111 Markownikoff Z. C., 6, 516 vii., 885 Diallyl hydroacetate C 6 H 10 .H 2 (OH)(OAc) abt. 210 Wurtz A. C. [4], 3, 162 vi.,94 Propylene monovalerate CH 2 .O(C 6 H 9 O).CH 2 .CH 2 OH 260 Liquid Reboul C. R, 79, 169 27, 1154 Isovaleroglycerol c 3 H 5 (OH):o 2 :c 5 H 10 224-228 Liquid Harnitz-Harn itzky A., 136, 127 ; v., 980;vi.,637 & Menschutkin B. S. [2], 3, 253 Dialdane alcohol CH 2 .CH(OH).CH 2 .CH 2 OH n 162-165 (10) sf. 49 ; melts Wurtz C. R, 92, 1371 42,489 CH.CH2.CHMe 53 (?) .... 185-195 (30) .... B. S., 28, 169 Ethylic diethylglyoxylate .... CH(OEt) 2 .COOEt C 8 H 16 4 195-196 .... Pinner and Klein B., 11, 1476 36, 46 51 I) 199-2 .... Schreiber Z. C., 13, 168 Camphoric acid Paraldol CH 2 .CH 2 .CHC 2 H 4 .COOH CHj.CH2.CH.COOH ) 206-215 90-100 L v. sf. 80-90 Kachler Wurtz A., 164, 75 C. R., 83, 255 vii., 949 30, 621 Dimethyl dambose (dam- bonite) .... C 8 H 16 6 190 Z. C. [1869], 67 Octyl alcohol . C 8 H 18 195-195-5 c. 195-196 c. Perkin .... 45, 472 45, 473 CH 3 (CH 2 ) 6 .CH 2 OH i 196-197 Renesse A., 166, 82 26, 1082 > j, .... .... CHMe 2 .(CH 2 ) 1 .CH 2 .OH )) )j 190-192 Liquid Zincke A., 152, 4 ; Z. C., vi., 697, 878 187-192 Franchimont and 12,55 B., 4, 823 CgHn.CHEt.OH 55 182-186 Zinck6 Schorlemmer A., 152, 152 vi., 879 C 6 H 13 .CHMe.OH )) 180-184 Pelouze & Cahours A., 129, 91 ; J., iv., 171 ) 16, 529 ,, ,, )> 11 181-183 178-185 .... Neison .... 27, 845 27, 843 )) 181 28, 208 5) 1 181-182 >j 27, 837 7) 1J 182 Chapman 18, 290 n I? 179-5 c. Perkin 45, 473 u CHMe 2 .(CH 2 ). 3 CHMe.OH J) 181 Schorlemmer P. R. S., 16, 376 vi., 65; 28, 207; 180-182 A., 152, 152 27, 1030 vi.,879;vii.,868 J 179-5 28, 209 ) }) 181 Ramsay 35, 469 ) )j .... .... ... )J ) H )l 181 .... Kullhem A., 173, 319 28, 354 COMPOUNDS CONTAINING THREE ELEMENTS. 201 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Octyl alcohol CHMe 2 .(CH 2 ). 3 CHMe.OH Q 8 H 18 180 (760) .... Bouis C. R, 38, 935; iv., 171 41, 603 ; A. C. [3], 44, 128 .... .... 179 .... Squire .... iv., 171 178 Moschnin J. F. P., 60, 207 177-178 (755) Schorlemmer 27, 1029 vii., 868 ,, ,, J) 177-6-177-8 .... Briihl A., 203, 28 (744) C 6 H 3 .CHMe.OH 174-178 Liquid De Clermont B. S. [2], 12, 212 vi., 880 " " CHMej.CH 2 .CH 2 .CHMe. 179-180 (765) 1. 17 Carleton- Williams 35, 127 CH 3 OH CHEt 2 .CHEt.OH 165-166 Winogradow B., 10, 407 32, 589 _ 1. 80 A., 191, 141 34, 486 C 5 H n .CHEt.OH 163-165 Harti'iicr J. p. [21 23, 467 40, 794 CHMe 2 .CHOH.CH 2 .CHMe., 160-163 (75'.) 1. 17 Carle ton- W^ ill iams Jr L JJ ) w 36, 127 CMe3.CH 2 .CMe 2 .OH 146-5-147-5 8. 20 Butlerow B., 9, 1687 ; C. C. 31, 448 ; 32, [1877], 2; A., 874; 34, 122 189, 53 Pr.CEtj.OH 145-155 Z. C. [1865], 615 Heptylmethyl oxide C 7 H 16 .O.Me ,-, 160-5-161 Liquid Wills J., 6, 510 ill., 149; 6, 314 Hexylethyloxide CH 3 .(CH 2 ) 5 .O.Et abt. 134-137 .... Lieben and Janecek A., 187, 139 32,881 (secondary) C 6 H 13 .O.Et 131-133 .... Schorlemmer Z. C. [1866], 606; 19, 357 A., 144, 241 .... .... 132-134 .... Reboul and Truchot J., 20, 582 Diethylethyloxide C 2 H 3 Et 2 .O.Et 131-1 .... Lieben A., 187, 14 29, 59 Amylpropyloxide C.H^O.Pr- 125-130 .... Chancel C. R,68;A., 151, vi., 964 305 Dibutyloxide (CH 3 .CH 2 .CH 2 .CH 2 ) 2 140-5(741-5) .... Lieben and Eossi A., 165, 110 vii.,217; 26,367 (CHEtMe) 2 O 123 Hanriot A. C.P.[5], 25,219 42, 590 (CHEtMe) 2 O 120-122 Kessel B., 7, 291 27, 677 120-121 Liquid Kessler A., 175, 54 28, 554 (CHMe 2 .CH 2 ) 2 O 100-104; HO A., 175, 55 104 " ii., 537 Octylene glycol C 8 H 16 (OH) 2 C 8 H 18 2 235-240 .... Clermont C. R, 59, 80 ; As., iv., 173;vi., 68 3,254 Methylethylpinacone CMeEt(OH).CMeEt(OH) 200-205 28 Lawrinowitsch B., 8, 767 ; A., 29, 897 ; 32, 428 185, 124 201-203(745) 28-29 Schramm B., 16, 1582 44,1080 Diisopropylglycol CHPr3(OH).CHPr/3(OH) .... 91 Fossek M.C., 4, 663 46,37 90 M.C., 3, 623 42, 1279 Glycol from isobutaldehyde.... C 8 H 16 (OH) 2 222-223 51-5 M.C.,3,623;M.C., 42, 1279; 46, 37 4,663 Diethoxybutane CH 2 (OEt). (CH 2 )j.CH 2 (OEt) 131-4 .... A., 178, 14 Propyl acetal . .. CH 3 .CH(OPr) 2 146148 Girard C. R, 91, 629 40, 35 143 Bachmann A., 218, 38 44,727 Amylmethyl acetal CH 3 .CH(OMe)(OC 6 H 11 ) 141-144 .... >i Isobutyl acetal CHMe 2 .CH(OEt) 2 168-170 Girard C. R, 91, 629 134-136 .01 ... C. R, 92, 886 Ethyloxethyloxide Et.C 2 H 4 .O.C 2 H 4 .OEt 148 Liquid Lieben A., 133, 287 iv.,288;vi.,598 Isoamylglyceric ether (amylin) C 3 H 5 (OH) 2 (6c 5 H n ) C 8 H 18 3 260-262 Reboul J., 13, 464 ii., 884 Amylic dimethylic orthofor- CH(OMe) 2 .(OC 6 H 11 ) 1) 234-240 .... Pinner B., 16, 1643 44, 1089 mate Propylic diethylic orthofor- CH(OEt) 2 .(OPr) 165-170 .... mate Methylic dipropylic orthofor- CH(OPr) 2 .OMe n 180-182 .... ,, mate Diethoxj-ethyloxide (EtO.C 2 H 4 ) 2 M abt. 168 Liquid Lieben A., 133, 287 v.,288;vi., 597 .... (CHMe.OEt) 2 .0 80-84 .... Jacobsen B., 4, 216 vii., 481 Ethylglycol acetal CH 2 OEt.CH(OEt) 2 164 Liquid Pinner B., 5, 150 vii., 1 ; 25, 407 1GS MM A., 146, 196 Triethoxyethane CH 3 .C(OEt) 3 142 Liquid Geuther J.Z. 4,221 ;Z.C. vii., 8; 24, 515 [2], 7, 128 n 202 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference, "Watts' Diet. & J. Ch. Soc. Ethylidene oxethylalcoholate C 4 H 8 (OEt) 2 C 8 H 18 3 153 Liquid Laatsch A., 218, 13 44, 788 Tetraethylene glycol (HO.C 2 H 4 .O.C.,H 4 ) 2 O C 8 H 18 6 a. 300 o.p. .... LourenQO B. S. [1859], 77 ii., 577 230 (25) Dimethyl (or ethyl) mannite .... C 8 H 18 6 230-250 Tollens B., 15, 1633 Ethylperoxide Et 4 O 3 C 8 H 20 3 .... 1. 40 Berthelot A. C. [5], 27, 229 44, 305; 40, 709 C. E., 92, 895 Trimethylcarbinol hydrate .. 2(CMe s .OH)+H,O CsH^O, 80 1. 0. ; s. f. m Butlerow Z. C. [2], 7, 273 24, 1035 ; 26, see C 4 H 10 O A., 162, 228 369; vii., 221 Benzonaphthone (C 9 H 4 0). C 9 H 4 O .... a. 300 .... 39, 220 Trimellitic anhydride C 6 H 3 .(COOH).CO.O.CO C 9 H 4 6 157-158 Baeyer A., 166, 340 vii., 785; 26, 756 i) )> .... 158 Emmerling B., 12, 1446 38, 265 Coumariu .... .... .. .... C 9 H 6 2 270 50 .... ii., 93 .... .... .. .... ) 290-5-S91 67-67-5 Perkin 21, 53; A., 147, 22 vi., 496, 1010 ) " C 6 H 4 .CH : CH.CO.O=1.2 290 .... B., 8, 1599 29, 439 i .... .... .. .... )) 291 .... Briihl B., 9, 1368 31, 165 Phenylpropiolic acid PH.C : C.COOH ) .... 134-137 Paternd G. I., 2, 553 26, 636 .... .. ) 1) .... 136-137 Glaser Z. C. [2], 4, 328 vi., 962 Methylene phthalyl c 6 H 4 :(co) 2 :oH 2 =i.2 .... 217-219-5 Gabriel B., 14, 926 40, 733 Hydroxymethylene phthalyl c 6 H 4 : (co) 2 : CH.OH C,H 6 3 145-146 Gabriel and Michae B., 11, 1012 34, 734 Coumarilic acid C f H 4 .CH : C(COOH).O )> .... 192-193 Perkin 24,46 vi., 498 >1 J) 310-315 s. d. 190-191 Fittig and Ebert A., 216, 162 44,474 Umbelliferone C ? H 3 (OH).CH : CH.CO.O .... 2%S-2%4 Tiemann & Reimer B., 12, 994 36, 720 = 1.2. ? .... )) J> 224 Posen B., 14, 2745 j " MM J> 240 Tiemann and Lewy B., 10, 2218 ft- .... .... d. w. m. 200 Bergapteu .... 1) .... 206-5 A, 31, 70, 320 Methoxyphthalic anhydride C 6 H 3 (OMe) : (C0) 2 : =1.2.3 C 8 H 6 4 .... 87 Jacobseii B., 16, 1964 44, 1124 j> . Ksriilri in .... .... , = 1.3.4 C 9 H 6 O 4 +H 2 O J) d. a. 270 93 a. 270 Schall Zwenger B., 12, 829 A., 90, 68 36, 793 i., 59 C H t O^+iH,O )J a. 250 Daphuetin _ g-I.-M.gV^.J I ^ ^*M CH-(OHXX )) 253-256 u. c jj Stiinkel B., 12, 111 36, 469 Opiuic acid 6"^^5\ "^^/ 3 C 9 H 8 O 5 + 2H 2 O )> C H,O. 148 Liechti Aa., 7, 149 29, 296 Methoxyuorhemipinic anhy- V 9 6^5 )> .... 148 !) As., 7, 153 dride ? Acid 177-197 (sic) Breuer and Zinck6 B., 14, 1897 Benzene tricarboxylic acid .... 6 H 3 (COOH) 3 = 1 C,H 6 6 149-150 p. d Woelz A, 168, 81 26, 1143 Hemimellitic acid =1.2.3 )) 185 d. Baeyer As., 7, 31 vi., 811 Trimellitic acid =1.2.4 )> 916 ;> As., 7, 40 vi., 813 i) )) )J > 216-218 Krinos B., 10, 1495 ,, I =1.3.5 >J 216 a. 300 Hammerschlag Bottinger B., 11, 88 B., 7, 1781 28, 508 )) B. w. m. 300 Ost J. p. [2], 15, 301 32, 486 ?) )) a. 300 Baeyer As., 7, 22 Aldehydo-j3-hydroxyisoph- OH.tCOOH^COH =1.2.6.4 J 237-238 Eeimer B., 11, 795 34, 882 thalic acid Aldehyuo-a-hydroxyisoph- =1.2.4.6 260 d. B., 11, 793 thalic acid Hydroxytrimellitic acid C 6 H 2 .OH(COOH) 3 =1.2.4.5 ^ 9 H 6 7 .... 240-245 d. Jacobsen and Meyer B., 16, 192 44, 590 Hydroxytrimesic =1.2.3.5 )J 270 Reimer B., 11, 796 34, 882 Polyporic acid (C,H,0,). a. 220 Stahlschmidt A., 187, 177 32, 620 Phenylpropargyl oxide PhO.C 3 H 3 C 9 H 8 210 Liquid Henry C. R., 96, 1233 44, 803 Cinnamic aldehyde C 6 H S .CH:CH.CHO 247-248 .... Perkin 31, 403 Action of acetylchloride on .... C 9 H 8 O 2 .... 125-128 Paal B, 15, 1818 44,62 benzaldehyde and Zn. dust 1 [ydrocoumaric anhydride .... 272 25 Zwenger As., 5, 106 vi., 716 Cinnamic acid C 6 H 6 .CH : CH.COOH T 280-290 Jeilstein & Kuhlburg Z. C. [2], 7, 487 25, 300 v > ...< .... JJ 293 )umas and Peligot A. C.. 57, 311 ., 984 ,, ,, j> 300-304 129 Kopp J. F. P., 37, 280 51 )> ); .. . 132 Conrad B., 13, 2160 40, 168 COMPOUNDS CONTAINING THREE ELEMENTS. 203 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Cinnamic acid C 6 H 5 .CH : CH.COOH C,H 8 2 .... 132 Stuart .... 43, 407 JJ JJ 133-4 .... .... vi., 249 JJ JJ .... 133 Basse B., 9, 832 30, 641 JJ Jl 133 Ogilaloro G. I., 8, 429 36, 641 JJ .... 133-3 Kachler Z. C. [2], 6, 60 vii., 160 JJ JJ * JJ JJ .... 132-6-132-8 Kraut G. J. C., 1868 JJ JJ .... 133 Miller G. J. C., 1877 JJ JJ 133 Tiemann & Herzf el B., 10, 69 Atropic acid .... C 6 H 5 .C(COOH) : CH 2 Jl JJ JJ 300 104-106 106-5 Weger Pesci Kraut A, 221, 61 G. I. [1881], 538 A, 133, 93 ; 148 242 46, 11 42,740 vi,, 249 JJ JJ .... 106 Ladenburg and B., 13, 373 38,472 JJ Jl Jl Jl C 6 H 3 (:0 2 :CH 2 )(CHOH.COOH) JJ JJ JJ 202-204 (75) 105-5-107-5 106-5 106-107 106-5 138 152-153 Bugheimer 11 11 Fittig and Wurster Spiegel Schmidt Lorenz B., 13, 2042 A, 195, 147 B., 14, 237 B., 13, 370 A. A, 167, 69 B., 14, 793 36, 379 38,482 Alorcinic anhydride Methylenedioxymandelic acid Isatropic acid.... See C J8 H 18 4 See C 18 H 16 O 4 C 6 H 5 .CO.OAc (C 9 H O 2 ) 2 C 9 H 8 S 120 125-128 Liquid Paal Gerhardt B., 15, 1819 Traite, 3, 319 i., 21 Acetyl benzoate Methylic plenylglyoxylate ... Ph.CO.COOMe JJ 246-248 (760 .... Claisen B., 12, 629 36, 648 Phenylglycidic acid Benzoylacetic acid O.CHPh.CH.COOH i i JJ JJ .... 154-155 d. 103-104 Plochl Perkin B., 16, 2821 46, 605 46, 174 CH 2 Bz.COOH JJ JJ .... 85-90 d. Bayer and Perkin B., 16, 2129 46,63 Acetoxybenzaldehyde .:.. C 6 H 4 .OAc.COH =1.4 JJ 260 Liquid Barbier C. R, 90, 37 ; B. 38, 318, 468 S. [2], 33, 54 JJ JJ 1) 264-265 I. 21 Tiemann& Herzfek B., 10, 64 32, 893 11 =1.2 abt.258p.d. 37 Perkin A, 148, 203 21, 53 ; vi., 1009 JJ JJ JJ 254-256 .... Barbier C. R, 90, 37 38, 318 =1.3 JJ 263 Liquid Tiemann & Ludwig B., 15, 2047 44, 188 Acetylbenzoic acid (aceto- C 6 H 4 .Ac.COOH =1.2 JJ .... 114-115 Gabriel & Michael B., 10, 1554 34, 229 phenone carbonic) 11 11 =1.4 JJ .... 200 E. Meyer B., 12, 1071 36, 795 Toluyl carboxylic acid C 6 H 4 .Me.(CO.COOH) =1.4 JJ abt. 99 Eoser B., 14, 1750 42, 194 Coumaric acid C 6 H 4 .OH(CH : CH.COOH) =? JJ .... 190 .... .... ii., 93 11 11 =1.2 U .... 207-208 d. Tiemann & Herzf eld B., 10, 286 31, 709 11 11 JJ 185 Schotten B., 11, 788 34, 878 11 =1.3 JJ .... 191 Tiemann & Ludwig B., 15, 2040 44, 189 11 11 =1.4 JJ .... 179-180 Hlasiwetz A., 136, 31 vi., 897 11 j 11 Jl .... 198-200 d. Gabriel B., 15, 2301 11 55 " 1J 206 ?iemann & Herzf eld B., 10, 66 32, 893 Hydrocoumarilic acid O.C 6 H 4 .CH 2 . CH.COOH JJ 98-5-300-5 d. 116-5 Fittig and Ebert A, 216, 166 44, 474 Paracumarhydrin .... JJ .... 82-83 A., 199, 36 ,, .... .... .... JJ .... 85 Jobst and Hesse B., 10, 249 32, 201 Acetylbenzoic anhydride ... JJ .... 70 A, 135, 92 , Benzoglycollic acid C 6 H S .CO.O.CH 2 COOH C 9 H 8 4 .... 120 Conrad J. p. [2], 15, 241 32, 484 Benzalmalonic acid Ph.CH : (COOH) 2 JJ .... 193d. Stuart .... 43, 405 Acetylsalicylic acid .... C 6 H 4 .OAc.COOH =1.2 Jl s. 118-118-5 Giliu A., 112, 181 vi., 1007 ? C 6 H 4 .COOH.(CH 2 COOH) JJ s. w. m. 200- Allen & Underwood B. S., 40, 100 46, 587 =1.3 210 Toluene dicarboxylic acid Me.(COOH) 2 =? JJ 180 [160] Hlasiwetz A., 138, 70 vi., 628 (isouvitic) ,i i, (uvitic) =1.3.5 JJ 230 Hall and Eemsen A. C. J., 2, 130 40, 821 n 11 n 11 n JJ .... 287-288 Tittig & Furtenbach Z. C. [2], 4, 1 vi., 821 11 11 15 11 11 JJ 287 i'mck A. 122, 184 v., 770 O r. 9 204 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Toluene dicarboxylic acid Me.(COOH) 2 = 1.3.5 C 9 H 8 4 .... 288 Bottinger B., 8, 1585 29, 566 (uvitic) )! = .... abt. 270 d. Blomstrand and B., 5, 1088 26, 506 ; vii., Hakansson 1171 (xyUdic) =1.2.5 11 280-283 Fittig & Laubinger Z. C. [2], 4, 597 ; vi., 1130 A., 151, 276 T) ) 291 )? M (0- ) =1.2.4 )> 320-330; Jacobsen B., 14, 2112 43, 188 sf. 310 ,, (isoxylidic) =? 315 ; sf. 280 Senhofer A., 164, 135 25, 1018 ; vii., 1171 Ethylene protocatechuic acid 6 H,(COOH):O,:C !I H < =1.3.4 > 133 Fittig and Eemsen Z. C. [2], 7, 289 vii., 1024 H I) J> 133 Fittig & Macalpine Z. C. [2], 7, 291 24, 1051 i> i> J .... 133-5 )! A., 168, 99 26, 1144 Pyrogallol carbonethyl ether C 6 H 3 ; O 3 ! C.OEt =1.2.3 )> 250-280 p.d. 105 Bender B., 13, 698 40, 48 |3-Methylresorcinoldialdehydt OMe.OH.(COH) 2 =1.3. (?) 3 J) 88-89 Tiemann & Parrisius B., 13, 2369 40, 271 a- J) )> )) 179 >! !> a-Orceudialdehyde C 6 HMe(OH) 2 (COH) 2 )I .... 117 Tiemann & Helken- B., 12, 1003 36, 720 berg 3- 168 )> r> B., 12, 1004 jj Metliyl normeconin .... )J 125 c. Beckettand Wright 29, 307 ? acid a, 200 A., 200, 37 Methylene dioxyphenylgly- OH 2 :o 2 :c 6 H 3 .CH(OH). c 9 n"o 5 .'..'. 152-153 Lorenz B., 14, 793 40, 729 collic acid COOH Methoxyphthalic acid (COOH) 2 .OMe =1.2.4 n .... 138-144 Schall B., 12, 829 36, 794 =1.2.3 j> 160 p. d. Jacobsen B., 16, 1962 44, 1124 Methoxyisophthalic acid .... = 1.3.2 )> 216-218 Schall B., 12, 828 36, 794 =1.3.4 )) 245 Jacobsen B., 11, 899 36, 793 H 261 Schall B., 12, 828 36, 794 Methoxyterephthalic acid .... = 1.4.5 274-275 Paterno & Canzoneri G. I., 9, 455 38, 247 ? )J J )> 277-279 Schall B., 12, 828 36, 794 Methylnoropianic acid COOH.OMe.OH.COH =? 154 .... J. p. [2], 24, 368 Aldehydovanillic acid COOH.OMe.OH.COH M 221-222 Tiemann and B., 9, 1280 31, 88 = 1.3.4.5 Mendelsohn Hydroxyuvitic acid (COOH) 2 .OH.Me =1.3.2.5.... > 275 ; Jacobsen B., 13, 2050 ; A., 40, 172 sf. 225-235 d. 195, 287; 206, 196 ,, .... I. D 220 d. Bottinger B., 9, 810 30, 415 ,, ,, =1.3.4.5.... 278 d. B., 13, 1933 40, 172 1) >1 )> 294-295 Hall and Eemsen A. C. J., 2, 137 40, 821 T) )> 290 p. d. Jacobsen A., 206, 188 40, 431 .... 5) i) .... 290 p. d. ; J! B., 13, 2050 40, 172 sf. 280 ,, = 1.3.4.6.... MM d. 290 Oppenheim & Pfaff B., 7, 932 ,, ,, =1.3.5.6 .... )j .... 270 p. d. Jacobsen B., 14, 2115 42, 188 Hydroxyxylidic acid =1.4.2.5 .... ) .... 285-290 Jacobsen and Meyer B., 16, 190 44, 590 Methyhiorhemipinic acid OMe.OH.(COOH) 2 =1.2.4.5 C 9 H 8 6 150-155 d. Beckett and Wright 29, 2.98 i) )! >! MM 153-155 Wegscheider M. C., 3, 372 42, 1207 Ethylic meconate C 6 H0 2 (OH)(COOH)(COOEt) C 9 H 8 7 .... 179 Mennel J. p., 26, 450 44, 656 1 H .... 158-159 A., 83, 358 iii., 861 Ethylmeconic acid .... C 5 HO 2 .OEt.(COOH) 2 ) 200 d. Mennel J. p., 26, 456 44, 656 Hydropolyporic acid (C a H 9 2 ) n 1G2 Stahlschmidt A., 195, 365 36, 383 Ciunamic alcohol (styrone) ... Ph.CH : CH.CH 3 OH C 9 H 10 S3 .... i., 992 5T J> JJ 33 Ken- P. M. [5], 13, 166 1 >1 I) )* U 220 .... Simon A., 31, 274 J) J 1> ) U 230 Scharling A., 115, 90, 183 )) 51 J JJ 1) 248-252 .... Hatton & Hodgkin- 39, 31!) son )) )1 > 250 .... Laubenheimer A., 164, 289 26, 65 1) >5 250 .... Wolff A., 75, 300 I )J J? )> 254 8 Kopp Co. C. [1850], 113 Hydrocinnamic aldehyde ... Ph.CH 2 .CH 2 .COH Jt 208 .... A. C. [5], 22, 254 Allylphenyloxide Ph.O.CH 2 .CH : CH 2 J 192-195 Liquid Henry B., 5, 455 vii., 50; 26,687 COMPOUNDS CONTAINING THREE ELEMENTS. 205 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylphenylketone Ph.CO.Et C 8 H 10 205-209 Liquid Pechmann B., 15, 891 ,, )) 205-210 .... Bechi B., 12, 463 36, 529 ,, .... .... )) 210 Kalle A., 119, 166 ,, .... ) ) 208-210 Liquid Barry B., 6, 1007 27,74 33 ) 208-212 .... Popoff B., 4, 720 24, 1058 33 .... . )1 ) 210 Schmidt & Fieberg B., 6, 498 27,75 ,, .... )) )) 212 Frankland & Louis .... 37, 744 ,, )> 217 Liquid Freund A., 118, 20 vi., 331 Benzylmethylketone C 6 H 5 .CH 2 .CO.Me 1) 215 3) Otto J. p. [2], 1, 144 vii., 940 13 .... )> )) US 33 Radziszewsky B.. 3, 199 .... )J 214-216 .... Popoff B., 5, 500 25, 821 Tolylmethylketone Me.C 6 H 4 .CO.Me )> 217 Liquid Michselis B., 15, 185 42, 970 Allylphenol (anol) C 6 H 4 (C 3 H 5 ).OH =1.4 J) abt. 250 92-5 Ladenburg B., 2, 371 ; As., vi., 175 8,89 C 6 H 4 .OMe.(CH : CH 2 )=1.2 195-200 Perkin B., 11, 515 33, 212 =1.4 201-202 d. 1 to 2 32, 669 7> 204^205 S !> B., 11, 515 33, 215 33 11 J) 204-205 31 32, 673 Mesityl aldehyde C 6 H 3 .Me. ! .COH=1..3.5 Liquid Eobinet C. R., 96, 500 44,577 ,, .... 220-222 .... Etard C. R., 97, 909 46, 312 Epioxyphenylhydrin CH 2 (C 6 H 5 0)(CH.O.CH 2 ) C 9 H 10 2 Solid Lippmann Z. C. [2], 7, 284 24, 1040 Hydratropic acid C 6 H 5 .CHMe.COOH 3) 264-265 1. 20 Fittig and Wurster A., 195, 165 36, 380 /3-Phenylpropiouio acid C 6 H 6 .CH 2 .CH 2 .COOH 46 Conrad and Hodg- B., 10, 255 31, 590 (hydrocinnamic or benzyl- kinson acetic) !! )I )> 270-280 .... Stockly J. p. [2], 24, 17 42, 77 33 33 J 279-8 Weger A., 221, 61 46, 11 33 33 Jl )) 280 47 Merz and Weith B., 10, 758 32, 617 33 33 )> 1) .... 46-5 Fittig Z. C. [1869], 166 vi., 469 33 V 280 c. (754) 47 Erlenmeyer A., 137, 327 ! 33 )i 3) abt. 280 47 Sesemann B., 6, 1086 27,69 33 33 )> 47 Hofmann B., 7, 521 27, 793 S3 )! j 3J .... 47 Oglialoro G. I., 8, 429 36, 641 Benzylic acetate C g H 5 .CH2.OAc 13 210 Liquid Cannizzaro A., 88, 130 i., 21 )? 33 206 .... A., 96, 246 ; 193, 320 Ethylic benzoate C 6 H 6 .COOEt 33 209 .... Dumas and Boullay P. A., 12, 430 ,, 33 208-209- Deville A. C. [3], 3, 188 33 33 207 .... Delffs J., 7, 26 ,, 3r 213 ..... Troost G. J. C., 1879 ,, JJ 33 211 Fittica J. p. [2], 13, 184 36, 153 33 211-16 .... Linnemann A., 162, 39 vii., 203 33 272-05 (753-6) .... Korner G. I., 4, 305 29, 214 3> 212-9 (745-5) .... Kopp A., 94, 309 i., 553 ,, 33 215 .... Busse B., 9, 832 30, 641 Methylic phenylacetate Ph.CH 2 .COOMe 33 220 Liquid Radziszewsky Z. C. [2], 5, 358 ; vi., 1101 B., 2, 208 Ethylbenzoic acid C 6 H 4 .Et.COOH=1.2 33 62 Gabriel & Michael B., 10, 2206 =1.4 33- 110-111 Fittig A., 144, 290 vi., 600 ,, ,, 7) 33 110-111 Thorpe and Kekule B., 2, 421 > 33 ... 11 2-1 IS Aschenbrandt A., 216, 218 44, 319 Cresylic acetate C 6 H 4 .Me.OAc=l. ? 3> 214 Liquid Perkin and Hodg- 37, 489 kinson 33 33 =1.4 33 208-211 .... Fuchs B., 2, 626 Methylic toluate C 6 H 4 .Me.COOMe=1.4 31 217 32 Fischli B., 12, 616 36, 638 Ethylsalicylol C 6 H 4 .OEt.COH=1.2 33 247-249 1.-18 Perkin A., 145, 306 20, 418 ; vi., 1009 )> 33 246-249 Liquid Gottig B., 10, 8 32, 304 Tolylacetic acid C 6 H 4 .Me.(CH 2 .COOH)=l. ? 33 42 Vollrath Z. C. [1866], 489 v., 1062 =1.3 33 53-54 Radziszewsky and B., 15, 1746 Wispek = 1.2 .... 85-5-86 11 33 P., 15, 1747 42, 1283 2C6 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Tolylacetic acid Methoxytoluic aldehyde Hesperetol C 6 H 4 .Me.(CH 2 .COOH)=1.4 OMe.Me.COH=1.46 (CH I CH 2 ).OH.OMe 1.3.4 C 9 H 10 2 254 89 Liquid 57 Radziszewsky and Wispek Schotten Tiemann and Will B., 15, 1744 B., 11, 785 B., 14, 967 42, 1283 34, 878 40, 740 Xylic acid Me.Me.COOH ? Liquid Beilstein & Kogler A., 137, 317 vi., 1130 1.3 2 97-99 Jacobsen B., 11, 21 273 103 Hirzel and Beilstein B. S., 1, 345 v., 1062 =1.3.4 120 Fittig & Laubinger A., 151, 271 ; vi., 1129 122 Kekule Z. C. [2], 4, 597 A., 137, 186 11 125 Schaper Z. C. [2], 5, 545 11 125-126 Jacobsen B., 11, 18 34,410 267 (727) 126 Ador and Meier B., 12, 1968 38, 252 =1.4.3 268 132 Jacobsen B., 14, 2111 42, 187 132 B., 14, 2112 ,, .... .... .... =1.2.4 280 161 163 Meyer Fittig & Laubinger B., 15, 636 A., 151, 275 ; 42, 848 vi., 1130 Mesitylenic acid 11 11 " " Lauroxylic acid Mesitylene quinone Ethylic terebenzate Furfurangelic acid Etliylic phenylic carbonate .... Methylic phenoxyacetate .... phenylglycollic acid 11 j) i> Phenylmethoxyacetic acid .... Phenyl-a-lactic acid 11 11 .... .... Phenyl-/3-lactic acid Atrolactic acid >, .... 11 u .... .... 11 11 .... .... 11 11 .... .... +|H 2 ,, ,, )1 1 a-Phenoxypropionic acid .... Tropic acid .... .... .... =1.3.5 Me 3 :O 3 =1.3.5.2.4 C 4 H 3 O.CH : CH(CH 2 ) 2 .COOH CO(OEt)(OPh) CH 2 (OPh).COOMe Ph.CH(OH).COOMe Ph.CH(OMe).COOH Ph.CH 2 CH(OH).COOH Ph.CH(OH).CH 2 .COOH J) CH 3 .C(OH)Ph.COOH M jy j tt )i CH 3 .CH(OPh).COOH ) CH 2 (OH).CHPh,COOH ).' JJ )) C 9 H" 3 11 11 11 11 u 11 11 11 u D 11 11 11 11 11 11 11 11 i 130 234 245 166 169-170 155 101-102 87-88 Liquid Liquid 47-48 113-114 71-72 97-98 98 93 94 93-94 93-5-94 94-95 93 93-94 80-85 89-91 90-91 91 112-113 112-5 117-118 Fittig Jacobsen Fittig, Kolrich, and Jilke Fittig Caillot Baeyer and Tonnies Fatianoff Fritzsche Breuer and Zinck6 Naquet & Longui- nine Meyer and Boner Erlenmeyer Conrad Erlenmeyer Plochl Spiegel Ladenburg & Rug- heimer Bottinger Tiemann & Kohler Fittig and Wiirster ii 11 Spiegel Bottinger Tiemann & Kohler Saarbach u Spiegel Z. C. [2], 4, 597 A., 141, 144 A., 206, 167 A., 145, 151 B., 6, 1399 A, C. [3], 21, 31 B., 10, 1364 Z. C. P. [1864], 77 J. p. [2], 20, 275 B., 13, 636 A., 139, 301 B., 14, 2392 B., 13, 303 B., 13, 2160 B., 13, 304 B., 16, 2815 B., 14, 1353 B., 13, 374 B., 14, 1239 B., 14, 1980 A., 195, 154 )5 B., 14, 1353 B., 14, 1239 B., 14, 1980 J. p. [2], 19, 175 J. p. [2], 21, 152 B., 14, 238 vi., 823 40, 430 46,43;vi.,775 27, 263 v., 723 32, 746 vi., 413 38, 319 38, 645 11 42, 195 38, 471 40, 168 38, 471 46, 606 42, 520 36, 379 ) 42,520 36, 642 38, 393 117 Fittig and Wiirster A., 195, 147 36, 379 117-118 Ladenburg B., 13, 254 38, 674 117-118 Lessen A., 138, 233 vi., 249 117-118 Ladenburg and B., 13, 379 38, 472 Metbylic methoxybenzoate.... 11 11 11 11 '. 11 u (aiiisate) 11 11 C 6 H 4 .OMe.COOMe= 1 .2 >i >i i) =1.4 ii 11 11 11 11 11 11 228 244-246 (732) 248 255 45-46 abt. 47 Eugbeimer Folsing Schreiner Cahours Ladenburg & Fitz Cahours B., 17, 486 A., 197, 18 C. R., 39, 256 A., 141, 252 A., 56, 311; A. C. [3], 14, 492 46, 897 v., 162 vi., 899 i., 301 COMPOUNDS CONTAINING THREE ELEMENTS. 207 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylic hydroxybenzoate C 6 H 4 .OH.COOEt=1.2 C 9 H 10 S 226-228 Liquid Gottig B., 9, 1473 31, 313 (salicylate) n i) >i 233 (730) Liquid Schreiner A., 197, 17 i =1.3 j 67 Earth A., 148, 30 vi., 890 J) .... 72-74 Greebe & Schultzen A,, 142, 351 i 282 72 A., 153, 336 j =1.4 )> 297-298 112-5 Gnebe A., 139, 146 vi., 899 >! 1) 116 Hartmann J. p. [2], 16, 50 32, 895 Ethoxybenzoic acid C 6 H 4 .OEt.COOH=1.2 M 221 Liquid Delffs J., 7, 26 v., 165 ,, !> ;> )> 225 Cahours A. C. [3], 10, 369 )) 229-5 Baly 2,28 )> )) .... 19-3-19-5 Kraut, Schroder, A., 150, 1 vi., 1006 and Prinzhorn M .... 19-5 Spica G. I., 9, 433 38, 167 JI 19-4 i> A,, 216, 152 (?) =1.3 (?) 115-117 Beilstein and Kuhl- Z. C. [2], 5, 461 vi., 899 berg (?) ,, (0 )> 118-120 ) 5> n (0 M 118-120 A., 156, 213 ,, .... ) 137 Heintz A., 153, 334 )) H )J )> 138 Fittica B., 11, 1209 34, 981 ,, ,, =1.4 n .... 194 Fuchs B., 2, 625 ,, .... ) .... 194-195 Spica A., 216 .152 38, 167 ,, >i N .... 195 Ladenburg & Fitz A., 141, 254 vi., 899 Methoxyphenylacetic acid .... C 6 H 4 .OMe.(CH 2 .COOH)=1.4 3J 85-86 Camiizzaro A., 117, 246 vi., 174 Hydroxybenzylic acetate .... C 6 H 4 .OH.(CH 2 .OAc)=1.3 J 295-302 p. d. 55 Velden J. p. [2], 15, 169 32,339 Oresoxyacetic acid C G H 4 Me.(O.CH 2 .COOH)=1.4 135-136 Gabriel B., 14, 923 Acetoxymethoxybenzene .... C 6 H 4 .OMe.OAc=1.2 > 235-240 Liquid Tiemann & Koppe B., 14, 2020 42,55 =1.3 n 254-256 Liquid Wallach & Wiisten B., 16, 152 Hydrocouruaric acid (meli- OH.(CH 2 .CH 2 .COOH)=1.2 31 .... 82 Zwenger A., 126, 262 ; vi., 715 lotic) As., 5, 100, 121 n J) ) ) .... 82-83 Tiemann & Herzfeld B., 10, 286 31, 709 ,, .... =1.3 111 Tiemann & Ludwig B., 15, 2051 44, 189 .... )) > .... ? Braunstein I. D., Zurich, 1876 j> = 1.4 us Hlasiwetz & Malin A., 142, 358 vi., 716 .... )) n .... 125 Baumanu B., 12, 1452 ,, ,, .... J> J) M 126-127 B., 13, 279 38, 649 .... )> )) .... 125-126 E. & H. Salkowsky B., 13, 191 Phloretic acid > n.f. 128-130 Holm & Keichardt A., 157, 98 24, 149 j C 8 H 8 (OH)(COOH) M .... 128-130 Hlasiwetz Gm. 13, 308 ; A., iv., 489 102, 145 Isophloretic acid OH.(C 2 H 4 .COOH) =1.2 n .... 129 Eochleder Z. C. [2], 4, 741 vi., 927 Dimetlioxybenzaldehyde ... COH.(OMe) 2 =1.3.4 > 285 u. c. 15-20 Tiemann B., 8, 1135 29, 76 ?> n 283 u. c. 41 Beckett & Wright 29, 288 j) =1.2.5 j> 270 51 Tiemann & Muller B., 14, 1992 42,53 )> =1.2.4 jj .... 68-69 Ciemann & Parrisiu^ B., 13, 2370 40, 271 Ethoxyhydroxybenzaldehyde COH.OH.OEt =1.2.5 >r 230 51-5 Hantzsch J. p. [2], 22, 463; 40, 166 B., 13, 2419 Methylic hydroxytoluate .... Me.OH.COOMe =1.3.4 236-237 .... Biedermann & Pike B., 6, 324 26,904; vii., 394 i) =1.3.5 .... 92-93 Jacobsen B., 14, 2359 42, 193 Methoxytoluic acid OMe.Me.COOH =1.4.6 67 Schall B., 12, 825 36, 794 =1.2.6 )) .... 81 B., 12, 824 ,, =1.3.6 u 103-104 D B., 12, 825 j ,, = 1.2.5 >j 156 Gerichten & Rosslei B., 11, 1587 36, 323 ,, ,, =1.3.4 .... 176 Schall B., 12, 825 36, 794 =1.2.4 .... 192-193 i) Ethylhydroxybenzoic acid .... C 6 H 3 .Et.OH.COOH =1.2. ? ji 112 Oliver! G. I., 13, 263 46, 174 Ethylliydroxybenzoic acid or C 6 H 3 .Et.OH.COOH = ? j) .... 127-128 Wright and Eennie 39, 239 dimethylhydroxybenzoic or acid C 6 H 2 .Me 2 .OH.COOH Orcacetophenone C 6 H 3 .Me.OH.OAc ;> .... 146 Easinsky J. p. [2], 26, 60 42, 1289 Orcinyl acetate 284-286 (724) .... J. p. [2], 26, 61 )) 208 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Homomethoxysalicyl- COH.OH.OMe.Me =1.2.3.5 C 9 H 10 3 270-275 Liquid Tiemann & Koppe B., 14, 2026 42, 55 aldehyde Hydroxyxylic acid (para) .... Me 2 .OH.COOH = ? 137 Oliveri G. I. [1882], 161 42, 838 )) I! = ? ) 155 Wroblewsky Z. C. [2], 4, 252 vi., 1129 n Me.Me.OH.COOH =1.2.4.5 j) .... 195 Reuter B., 11, 29 34,413 11 199 Jacobsen B., 12, 434 36, 641 Hydroxymesitylenic acid ... Me 2 .OH.COOH =1.3.4.5 jj 176 Fittig & Hoogewerff Z. C. [2], 5, 169 vi., 824 n ji i) ) M .... 176 Fittig A., 150, 333 36, 530 n 11 )? )) ) .... 179 Jacobsen B., 11, 2055; A., > 195, 274 n =1.3.2.5 B .... 223 11 B., 12, 606 36, 643 Alorcinic acid C 6 H2.Me 2 .OH.COOH+H 2 O n air dried 97; Weselsky A., 167, 65 ; B., 26, 1039 ; vii., over H,jSO 4 115 5, 168 53 Hyoscinic acid C 8 H 9 O.COOH i) 104-105 Holm & Eeichardt A., 157, 98 vi., 726 ; vii., 664; 24, 149 11 11 .... id. Tropic acid, q. v. > .... 116-117 Ladenburg B., 13, 254 38, 674 d. 250 J. p. [2], 26, 76 Usuetic acid (Decarbusnic) .... ItM ) 172 Hesse B., 10, 1326 32, 896 ; 37, 407 Methylic dehydracetate .... C 9 H 1(I O 4 91 Oppenheim & Precht B., 9, 324 30,70 Phenylglyceric acid C 6 H 6 .CH(OH).CH(OH). 117 Auschiitz and Kin- B., 12, 539 36, 645 COOH nicutt Atroglyceric acid CHjOH.CPhOH.COOH j) .... 146 East A., 206, 29 40, 428 Methoxymandelic acid OMe.(CHOH.COOH) =1.4 >i .... 93 Tiemann B., 14, 1977 42,57 Hydroxyphenyllactic acid .... OH.(CH.,CHOH.COOH) j 144 Erlenmeyer & Lipp A., 219, 179 44, 993 =1.4 ,, (?) OH.(CHOH.CHj.COOH) u .... 162-164 Z. P. C., 6, 256 =1.4 Methylic vanillate OMe.OH.COOMe =1.2.5 j 285-287 62-63 Matsmoto B., 11, 128 34, 501 methoxysalicylate.... = 1.3.4 j> 154 Tiemann and Par- B., 13, 2377 40, 271 risius Etliylic dihydroxybenzoate.... COOEt.OH.OH =1.3.6 i> .... 75 Goldberg J. p. [2], 19, 373 36, 929 11 11 =1.?.6 j> .... 78 Liechti Z. C. [2], 6, 197 vi., 1005 11 11 = ' .... b. 100 Barth and Senhofer A., 159, 225 vii., 433 (proto- =1.3.4 133-134 Matsmoto B., 11, 122 34, 501 catechuate) 11 11 l> )j 133-134 Fittig & Macalpine A., 168, 113 26, 1145 i ) )' > j> 134 c. .... A., 114, 295 i) v r> ) )J !! 134 c. Hesse A., 122, 221 iii., 216 Diniethoxybenzoic acid COOH.(OMe) 3 =1.2.5 1) 76 Tiemann & Muller B., 14, 1993 42,53 11 u =1.2.4 J 108 Pechmann and B., 16, 2126 46,67 Duisberg i i> )) )) .... 108 Tiemann and Par- B., 13, 2378; B., risius 15, 2080 11 i =1.3.5 J 175-176 Tiemann & Streng B., 14, 2003 42,52 (vera- =1.3.4 )) 170-171 Kcelle B., 4, 635; A., 24, 829 ; vii., tric acid) 159, 241 432 i 11 *i 1) ) 171 Beckett & Wright 29, 289 i i 11 172-173 15 29,304 M 1) J )1 174 Tiemann and Men- B., 8, 1138 29, 75 delsohn 11 V )1 I> n .... 174-175 Tiemann and Will B., 14, 962 1 11 )1 ? )> 174-175 u.c. Tiemann and Mats- B., 9, 938 moto 11 11 11 )) n 174-175 Matsmoto B., 11, 124 34,500 11 11 11 n > 176-177 Wright and Luff .... 33, 161 11 11 ) ) >i 176-178 c. I! 11 33, 354 1 11 )) T5 51 51 177-178 11 11 33, 161 11 11 11 1 >1 11 179-5 Korner G. I., 6, 142 31,89 > 11 11 11 ) 11 179-5 Church J. [1876], 601, 810 28, 117 n u 11 11 11 .... 179-180 Gra;be & Borgmann A., 158, 282 24, 705 COMPOUNDS CONTAINING THREE ELEMENTS. 209 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. a-Homovanillic acid (CH 2 .COOH).OMe.OH=1.3.4 CjHup., 142-143 Tiemann and Nagai B., 10, 204 32,340 Dihydrohomoisopthalic acid Me.H 2 .(COOH) 2 =1.1.2.3.5 133 Bottinger B., 6, 895 26, 1222 ; vii., 1033 Everninic acid ,/ .... 147; 157 Stenhouse A., 68, 86 ; 117, ii., 612 C 12 H 14 O 6 (?) 199-200 Patern6 & Oglialoro 299 G. I, 6, 531 81, 719 Atranorinic acid 11 100-101 Patern6 G. I. [1882], 231 ; 42, 1084 B., 15, 2242 Ethylic gallate C 6 H 2 (OH) 3 .COOEt =1.2.3.5 .... 141 Etti B., 11, 1882 11 11 11 C,H 10 5 150 Ernst and Zwenger A., 159, 28 vii., 538; 24, 821 C 9 H 7 O.OH.(COOH) 2 O TT O 90 199-200 11 11 Hergt J. p. [2], 8, 382 24,821 27, 457 ? alcohol CH!0(?) 230-244 Laubenheimer * " r L J' 1 A., 164, 289 26, 65 Phenylpropyl alcohol C 6 H 6 .CH 2 .CH 2 .CH 2 .OH 11 235 u. c. 1. 18 Eiigheimer A., 172, 122 vii., 931 ; 27, 894 11 11 11 234-235 .... Fittig & Eiigheimer B., 6, 215 26, 899 Ethylphenyl carbinol C 6 H 5 .CH(OH).CH 2 .CH 3 11 213 .... Briihl A., 200, 139 38, 296 11 11 11 11 212 .... J. p. [2], 26, 110 i, 11 11 11 210-211 Barry B., 6, 1008 27,75 ji 11 11 218 Wagner B. S. [2], 36, 306 42,377 Propyl phenyloxide C 6 H 6 .O.Pra 190-191 Liquid Cahours C. E., 77, 745 ; 27, 38 B. S., 21, 78 laopropylphenyl oxide C 6 H 6 .O.PrP 176 Liquid Silva B. S. [2], 13, 27 vi., 917 Benzylethyl oxide C 6 H 6 .CH 2 .O.Et 185 Liquid Cannizzaro Cimento, 3, 397 i., 579 Methoxylethyl benzene C 6 H 4 Et.OMe =1.2 185 Liquid Oliveri G. 1 , 13, 263 46, 174 11 11 11 190-192 Liquid Ciamician B., 12, 1658 38, 39 Ethoxytoluene C 6 H 4 .Me.OEt =1.2 180-181 u. c. Liquid Steedel B., 14, 898 ; A., 40, 723; 44, 217, 41 585 = 1.3 188-191 Liquid Engelhardt and Z. C. [1869], 623 vi., 507 LatBchinoff 11 11 11 191-192 .... Oppenheim & Pfaff B., 8, 888 11 11 k 186-188 Liquid Engelhardt and Z. C. [1869], 619 vi., 506 Latschinoff 11 11 186-188 ... Fiichs B., 2, 624 Propylphenol C 6 H 4 .Pr".OH =1.2 223-225 1. f. m. Frankland & Turner Spica G. I., 8, 406 ; B., 43, 858 36, 632 ; 43, 11 11 = 1.3 (758-5) 228 c. 26 J acobsen 12, 295 B., 11, 1062 358 34, 732 II 11 =1-"1 227-228 LlQUld Louis B., 16, 109 " 230 1. f. m. Patern6 and Spica G. I., 7, 22 31, 708 11 230'6-232'6 c 1. f. m. Spica G. I., 8,406 ; B., 36, 632; 43, (758-56) 12, 295 358 Isopropylphenol C 6 H 4 .Pris.OH =1.2 213-215 Liquid ., G. I., 10, 246 38, 883 11 11 218-5 c. Liquid ,. G. I., 9, 433 38, 167 (756-18) .... = 1.3 11 abt. 214 8-10 Fileti G. I., 10, 279 38, 883 (753-3) 11 = 1.4 228-2-229-2c 61 Spica G. I., 6, 535 ; 8, 31,593; 36, (758-18) 406 632 11 n 11 61 11 G. I., 9, 433 38, 167 Methylxylenol Me.Me.OMe =1.3.4 11 192 Liquid Jacobsen B., 11, 25 34, 412 11 = 1.4.5 194 c. (772) Liquid B., 11, 28 11 11 11 200 Tiemann and B., 10, 61 Mendelsohn Mesityl alcohol Methylethylphenol C 6 H 3 .Me 2 .CH 2 OH =1.3.5 C 6 H 3 .Me.Et.OH =1.4.? n 218-221 215 Liquid Wispek Mazzara B., 16, 1577 G. I., 10, 256 44, 1096 38, 882 Mesitol Me 3 .OH =1.3.5.6 219-5 c. (768 OS Jacobsen A., 195, 269 36, 529 11 11 11 11 215-220 68-69 Biedermann and B., 8, 57 28, 569 Ledoux B., 8, 250 28, 761 Pseudocumenol Me 3 .OH =1.2.4.5 11 240 69 Renter B., 11.29 34, 413 2 E 210 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Heat on Ca-succinate C 9 H 12 190-200 .... Funaro G. I., 11, 274 40, 1032 u-Phenylmethylgycol Ph.CH(OH).CHMe(OH) C 9 H 12 O 2 .... 52-53 Zinck6 B., 17, 710 46, 1004 0- ,, 1J .... 92-93 )> B., 17, 711 JJ Dimethoxybenzylene C 6 H 6 .CH(OMe) 2 j 208 c. Liquid Wicke A., 102, 363 i., 577 Methoxyethoxybenzene OMe.OEt =1.2 7> 213 Liquid Tiemann & Koppe B., 14, 2018 42,54 Ethoxybenzyl alcohol OEt.(CH 2 OH) =1.2 1) 265 s. 0. Botsch M. C., 2, 621 42, 174 Methoxybenzyl methyloxide OMe.CH 2 OMe =1.4 225*5 (758) Liquid Caunizzaro A., 137, 246 vi., 174 Propyklioxybenzene (OH) 2 .Pr =1.2.? ') .... 56 M. C., 4, 190 Dimethoxytoluene Me(OMe) 2 =1.3.5 )> 244 Liquid Tiemann & Streng B., 14, 2000 42, 51 .... =1.3.4 ,, 214-218 Liquid Tiemann & Mendel- B., 8, 1137 29, 74 sohn ,, )' ) )) 214-218 Tiemann & Koppe B., 14, 2025 ,, = ? J> 214-218 15 Nietzki A., 215, 161 ; B., 34, 868; 44, 11, 1278 467 = 2.1.2 218 .... Goldschmidt M. C., 4, 704 46, 186 Mesitylenic glycol Me.(CH.OH) 2 = 1.3.5 H 190 (20); 280 Liquid Eobinet and Colson C. K., 96, 1863 44, 1095 (750) p.d. Dihydroxytrimethylbenzene Me 3 (OH) 2 = 1.3.5.2.4 M 274-5-275-5 c. 149-150 Knecht B., 15, 1377 ; A., 42, 1200 215, 100 ? .... 5) *.* 148 Kachler A., 169, 183 27, 155 Mptacrolein .... .... ... C.H.,0, b. 132 45-46 Grimaux and Adam B. S. [2], 36, 22 ; 40, 406, 888 ^9 12^3 C. R, 92, 300 50 A., 112, 6 Ethylic pyrotritartrate cooEt.CHAc.cn : c : CH 2 )l )> 205-208 ; Harrow A., 201, 147 33, 428, 430 208-209 Mesitylene glycerol .... C 6 H a .(CH 2 .OH) 3 = 1.3.5 .... Liquid Colson C. R., 97, 177 46, 56 Ethoxyliydroxybenzalcohol OH.OEt.CH 2 OH=1.4.(5or6) U 83-5 Hantzsch J. p. [2], 22, 473 40, 167 Dimethylhomo-pyrogallol .... C 6 H 2 .Me.(OMe) 2 .OH *) 265 36 Hofmann B., 12, 1374 38, 249 Propyl pyrogallol C 8 H 2 .Pr.(OH) 3 ij MM 80 Pastrovich M. C., 4, 184 44, 1005 v .... .... i .... 79-0 Hofmann B., 11, 332 34, 417 Ethylic succinopropionate .... CH 2 .CO.(CIL) 2 .CO.CH. C,H,A *** Liquid Herrmann A., 211, 320; B., 42, 713 1 1 10, 109 COOEt Dilactone (Me.C.COO.CH 3 )C a. 360 105-106 Hjelt B., 15, 626 ; A., 42, 946 )) 216, 67 Diallylmalonic acid (CH 2 : CH.CH 2 ) 2 .C(COOH) 2 )) >.i* 134 Perkin .... 45, 539 .... .... ? .... 133 Conrad and Bischoff B., 13, 598 38, 628 Camphoronic acid + H 2 O .... C,H 12 5 .... 110-115 Kachler A., 159, 286 ; 162, 24, 1049 ; vii., 262 237 Butyrofuronic acid .... COOH.(CH) ;i .CO(CH 2 ) 4 . JJ .... 140-142 Toennies B., 12, 1200 36, 916 COOH Oxycamphoronic acid .... C 9 H 12 6 .... 210 Kachler A., 159, 296 ; J., 24, 1050 ; vii., [1877], 640 238 Isooxycamphoronic acid .... 1) 226 A., 191, 152 34, 513 Trimethyl aconitate C 3 H 3 .(COOMe) 3 270-271 .... Hanaus B., 9, 1750 31, 456 Diallylacetone CH 3 .CO.CH(CH 2 CH : CH 2 ) 2 C 9 H N 174-175 Liquid Wolff B., 10, 1957 ; A., 34, 293 201, 48 Phorone 195-196 28 Louise C. R, 95, 602 44, 176 jt 208 Liquid Schwanert A., 123, 298 vi., 390 [CEt.(CH 2 ) 4 .CH]:CO 1) 208 Kachler A., 164, 79 vii., 238 ; 26, > 1011 .... .... (() .... ) 210-220 .... .... i., 29 218 c. Liquid Schulze B., 15, 64 42, G13 ,. 1 51 209 Fittig A., 110, 32 Hi., 929 Isophorone .... 208-212 Liquid Benedick t A., 162, 303 ; A., 26, 490; vii., 164, 79 1107 Camphorone (phorone) 1 196 20 Baeyer J., 18, 317 )) 208 Liquid Gerhardt Co. C. [1849], 385 i., 733 (camphrene) C 18 H 28 2 (?) 235-238 Schwanert A., 123, 298 vi., 390 Action of HC1 on acetone .... Me 2 C:CH.CMe:CH.CO.Me ; ) 196 .... Kachler A., 164, 75 25, 1012 or Me 2 C : (CH 2 ) 2 : C : (CH 2 ) 2 : From camphic acid .... J) 230-235 Liquid Montgolfier C. R, 88, 915 36, 726 COMPOUNDS CONTAINING THREE ELEMENTS. 211 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diallylcarbinol acetate (CH 2 : CH.CH 2 ) 2 CH.O Ac C 9 H 14 3 169-5 c. Saytzeff A., 185, 136 32, 297 KHO on allyl alcohol .... (?) 230-270 .... Tollens Z. C. [2], 7, 249 25, 999 115-120 Volckel J., 7, 611 59 J. [1878], 958 Ethylic aceto-allylacetate ... C 3 H 5 .CHAc.COOEt C 9 H 14 3 213-214(7W) Perkin 45, 540 11 J) 206 .... Zeidler A., 187, 33 32, 437 Ethylic trimethylene acetoace CH 2 .CH 2 CH 2 .CAc.COOEt 223-225 Liquid Perkin B., 16, 209 tate Eihylic hydroxyheptoate ... C 7 H 9 2 .OEt n 129-130(100) .... Demarjay C. E., 86, 1135 34,662 230-240 (760 Diethylic trimethylene dicar- CH ? CH 2 .C(COOEt) 2 C 9 H 14 4 206-208 (720 Liquid Perkin B., 17, 54 46, 832 boxylate Ethylic itaconate .... 225 Liquid .... iii., 436 .... 230 J. [1873], 579 ,, .... Ml ) 2VT-228 Petri B., 14, 163 40, 1032 ,. ,, .... ... .... >J 228-229 .... Anschiitz B., 14, 2787 mesaconate C 3 H 4 (COOEt) 2 )J 220 Liquid Pebal J.,4,404; A.,78, iii., 928 145 11 .... Jl 223-223-5 Liquid Perkin B., 14, 2543 30, 557 =229 c. 11 15 .... 229 Liquid Petri B., 14, 1634 39, 557; 40, 1032 11 51 " "* .... ) 229 .... Auschiitz B., 14, 2785 citraconate .... .... > 225 Liquid .... .... i., 993 ,, ., ' 226; 231-75 c. Liquid Perkin B., 14, 2542 39, 557 11 11 .... )) 231 Liquid Petri B., 14, 1634 39, 557; 40, 1032 11 11 .... 1J 231 .... Anschiitz B., 14, 2785 terebate CMe 2 .O.CO.CH 2 .CH.COOEt )> 273-276 Roser B., 15, 293 i i acetomalonate COOEt.CHAc.COOEt C 9 H 14 5 238-240 Liquid Ehrlich B., 7, 892 ; B. S., 29, 368 23, 73 Glyceryl triacetate (triacetin) CHOAc(CH 2 OAc) 2 C 9 H 14 6 257-260 .... Schmidt A., 200, 99 38, 312 11 11 ) )) 258-260 Franchimont B., 16, 394 i> 11 * Liquid Berthelot A., 102, 340 i., 25 11 11 11 ) )> 268 .... ... A. C. [3], 41, 282 Hydro-oxy camphoric acid .... ) .Z64-5 Kachler A., 191, 149 34,513 11 i> .... .... 164-5 B., 7, 1730 28,457 i .... )> .... 164-165 !> B., 13, 487 11 .... .... 148 Ballo B., 12, 1597 ; 13, 332 Camphoronic acid + H 2 O .... )) .... 110 Kachler A., 159, 281 24, 1049 Ethylic carbodiglycollate .... CO(OCH 2 .COOEt) 2 CgH^Oy abt. 280 p. d. Liquid Heintz A., 154, 258 vii., 255 TrimethyKc citrate C 3 H 5 0.(COOMe) 3 i) 283-287 78-5-79 Hunaus B., 9, 1749 31, 456 Ethyl diallylcarbinol oxide .... (CH 2 : CH-CH^CHOEt C 9 H 16 143-144 Liquid Ejabinin J. p. [2], 23, 272; 38, 372; 40, (759) B., 12, 2374 404 Diallylethylcarbinol C'(C 3 H 5 ) 2 Et.OH 175-176 Liquid Srnireiisky J. p. [2], 25, 59 42, 488 (743-5) Lycoresin .... .... .... 170 d. A., 100, 303 From Satureja Juliana C 34 H 58 4 (?) 11 11 "" 204-205 Spica G. I., 9, 285 38, 128 Butylic angelate ^4 -tl?' OOOC/.J Hg C9H l( O 2 177-178 .... Fittig B., 10, 513 32,429 Isobutylic angelate C 4 H 7 .COO.CH 2 .CHMe 2 11 177-177-5 .... .... A., 195, 99 Ethylic tetracrylate C 6 H n .C!OOEt 51 189-191 .... Amthor B., 14, 1718; A. P. 42, 46 [3], 18, 356 Phoronic acid.... .... 11 168-169 Montgolfier A. C. [5], 14, 82 34, 898 Amylic acetoacetate CH 2 Ac.COOC 5 H,, C 9 H 16 3 abt. 223 Conrad A., 186, 228 32, 435 Ethylic aceto-methylethyl- CAcMeEt.COOEt i> 198 Liquid Saur B., 8, 1037 29, 370 acetate 11 5i 51 1 98 u.c. 11 A., 187, 257 34, 27 propylacetoacetate .... CHAcPrCOOEt 11 205-210 Liquid Burton A. C. J., 3, 385 42, 599 11 11 ? 11 SIS (750} .... Chancel C. E., 96, 1406 44, 915 isopropylacetoacetate CHAcPrPOOOEt 11 200-202 Liquid Demarc,ay C. E., 83, 449 30, 506 2 E 2 212 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylic isopropylacetoacetate CHAcPr3COOEt C 9 H 16 O 3 SOI Franklaud & Duppa A., 145, 80; J., vi., 591 20, 395 a-ethyl-|8-acetopro- CH 2 Ac.CHEt.COOH 3) 224-226 Liquid Thorne .... 39, 341 pionate mesitonate CMe 2 : CH.CMe(OH).COOEt 210 Liquid Pinner B., 15, 579 42, 941 Valerylene diacetate C 5 H 10 (OAc) 2 C 9 H 16 4 abt. 205 Liquid Reboul C. R., 64, 284 vi., 1124 abt. 195 Kolbe and Guthrie A., 109, 296 v., 974 Amylene a. 200 Liquid Wurtz A. C. [3], 55, 458 i., 208 Ethylene acetoisovalerate .... CH 2 (OAc).CH 2 (O.C 5 H 9 O) abt. 230 Liquid Louren^o A., 114, 125 ii., 568 Ethylic butyrolactate C 2 H 4 0(C 4 H 7 O).COOEt 200-210 Liquid Wurtz C. R., 48, 1092 i., 697 D 208 .... J., 13, 273 ; A., 112, 235 D'ethylic ethylmalonate CHEt(COOEt) 2 208-210 Liquid Conrad B., 12, 751 36, 707 )J 199-201 Liquid Markownikoff A., 182, 334 31,62 n 9 209-5-211'5c.; .... Perkin .... 45, 512 J) 207 .... A., 204, 135 dimethylmalonate CMe 2 (COOEt) 2 196-S-196-7c. .... Perkin .... 45, 511 ! .. 194-196 .... Conrad & Guthzeit B., 14, 1644 H 194-5 Liquid Thorne 39, 544 methylsuccinate COOEt.CHMe.CH 2 .COOEt 33 217-5-218-5c. .... Perkin 45, 516 pyrotartrata C 3 H 6 .(COOEt) 3 13 218 d. Liquid .... A., 25, 274 iv., 774 COOEt.(CH 2 ) 3 .COOEt I) 236-237 Liquid Reboul C. R., 82, 1502 30, 508 236-5-237 c. Liquid A. C. [5], 14, 501 36, 134 3-Hexylmalonic acid C 6 H 13 .CH(COOH) 2 .... 84-86 Lundahl B., 16, 789 Azelaic acid .... C-H 14 .(COOH) 2 106 Gantter and Hell B., 14, 560 40, 578 H 106 B., 14, 1545 40, 891 33 33 jj 106 Dale 17, 261 iii., 572 " 33 106-5 Dale and Schorlem- A., 199, 144 35, 685 D nier 106 Toennies B., 12, 1200 33, 916 33 (anchoic) ji 33 .... 115-124 Wirz A., 104, 265 i., 290 (lepargylic) J) .... 114-116 Buckton 10, 166 iii., 572 COOH. (CH 2 ) ? COOH 117-118 Toennies B., 12, 1202 36, 916 Diethylic hydroxypyrotar- C 3 H 5 (OH)(COOEt) 2 C S H 16 5 295-300 d. Simpson P. R. S., 13, 44 ; iv., 315 trate A., 133, 77 Ethyh'c quinate CjH^EtO, 9 H 16 6 240-250 Liquid Hesse A., 110, 340 v., 13 Isopropylallyl dimethyl car- C 4 H 4 Me 2 Pri3.0H C 9 H 18 174-176 .... Dieff J.p., 27, 364 ; B., 44, 1076 biuol 16, 960 Methylheptyl ketone Me.CO.C 7 H 15 177 Lundahl B., 16, 789 Valerone (C 4 Ha) 2 .CO b. 100 Lowig P. A., 42, 412 25, 892 164-166 Liq uid Ebersbach A., 106, 268 v., 981 " 181-182 Schmidt B., 5, 600 25, 892 Methyl-dipropylmethyl Me.CO.CHPr 2 173-174 Liquid Burton A. C. J., 3, 385, 39 42, 600 ketone Propyhliethylmethyl ketone C3Hj.CO.CHEt, 180-190 .... Geuther, Frohlich, A., 202, 311 38, 623 and Loosa Dimethyl butyrone .,,, 192-195 .... Jalm B., 13, 2116 ? ketone .... 160-170 .... .... J.p. [2], 23, 456 * 180-190 .... Destrem B., 16, 227 ? .... CgHjgOj 179 Geuther J. Z. N., 7, 218 25, 607 Octylic formate H.COO.(CH 2 )-.CH., 195-197 .... Cahours & Demar- C. R., 191, 366 34, 653 Heptylic acetate CH 3 (CH 3 ) 6 .OAc 191-5(758-5) Liquid Cross A., 189, 4 32, 126 C 7 H 15 .OAc 181 Bouis and Carlet A., 124, 352 ; 26, 1081 ; iii., C. R., 55, 140 143 3) M 181 .... Schorlemmer P. R. S., 14 vi., 696 31 180 33 " 179-181 A., 136, 271 iii., 143; 16, 217 COMPOUNDS CONTAINING THREE ELEMENTS. 213 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts Diet. & J. Ch. Soc. Heptylic acetate CH 3 (CH 2 ) 3 .CHMe.CH 2 .OAc ^dH 18 O 2 179 .... Schorlemmer P. R. S., 14 vi., 696 CHMe 2 (CH 2 ) 3 .CH 2 .OAc ,i it 160-175 Grimshaw .... 26, 313 11 1, ' " CH 3 .CH(OAc).CHMe.Pr3 tj 160-185 Schorlemmer 26, 320 vii., 643 Et.CMe 2 .CH(OAc).Me ,, ,, CH 3 .(CH.,) 4 .CH(OAc).CH 3 )> 169-171 .... 11 P. T. [1878], 1 ; 32, 866 A., 188, 254 ,, )) >? 170-174 .... Morgan .... 28, 305 ,, ,, CHMe 2 .CH 2 .CH 2 .CH(OH). H 166-168 Liquid Rohn A., 190, 312 34, 486 CH 3 Ainylic butyrate CH 3 .(CH 2 ) 2 .COO.C 6 H n )> 178-6 Elsasser A., 218, 302 44,967 isobutyrate CHMe2.COO.C5Hn )? 168-8 .... 11 11 Isoamylic butyrate CH 3 (CH 2 ) 2 .COO.(CH 2 ) 2 Pr0 )T 176 Liquid Delffs A., 92, 278 i., 695 isobutyrate CHMe 2 .COO.(CH 2 ) 2 .CHMe 2 )> 170-3 .... Pierre and Puchot C. R.,76, 1332; 26, 1017 ; vii., A. C. [4], 22, 343 62 Isobutylic isovalerate Pr0.CH 2 .COO.CH 2 PrS 173-4 (760) .... 11 !> C. R., 76, 1332 ; 26, 1017 ; vii., A. C. [4], 20, 62, 1200 234 ; 22, 330 ; A., 163, 285 valerate C 4 H 9 .COO.CH 2 Pr0 168-7 .... Elsasser A., 218, 302 44,967 Tertiary butylic (tertiary) CMe 3 .COO.CMe 3 )> 134-135 1. 20 Butlerow B., 7, 728; A., 27, 1084 ; valerate 173, 372 28, 250 Rtliylic oenanthylate CH 3 .(CH 3 ) 5 .COOEt J 189-3 (747-6) Liquid Lieben and Janecek A., 187, 141 32, 881 ,, J 180-187 .... Grimshaw and A., 170, 137 Schorlemmer ,, ,, )> 187-18S 1. -18 Grimshaw & Shor- 26, 1077 vii., 870 lemmer .... )> ! 187-188 (763) 1. 20 ji 11 26, 1076 ) ) 187-188 .... Cahours and De- C. R., 89, 331 36, 1037 inarcay , s > J 186-188 1. -14 Mehlis. A., 185, 358 84, 135 ,. i* 1 187-188 (761) 1. -18 Franchimont B. ; 5, 786 86, 56, 1077 ,, j T 187-188 c.; .... Perkin .... 46, 502 187-5-189-5C. ,, ,, .... M e; ,.CH.(CH 2 ) 3 .COOEt T 182 Liquid Poetsch A., 218, 56 44,730 Me.(CH 2 ) 3 .CHMe.COOEt M 172-173 Hecht A., 209, 324 42,41 (749-5) Methylic caprylate CH 3 .(CH 2 ) 6 .COOMe )) 192-194 s. 48 Cahours and De- C. R., 89, 331 36, 1037 marcay Nonylic acid (pelargonic) .... CH 3 .(CH.,) 7 .COOH 260 10 Cahours J., 3, 401 iv., 370 ,, 11 11 )> n 248-250 7 Giesecke Z. C. [2], 6, 429 vii., 897 i, 11 it )J n 253-234 10; 12-12-5 Franchimont and B.,5, 19; A., 164, vii., 898; 25, (758-8) Zinck6 333 301 11 11 i) J? ) 186 (100) 12-5 Krafft B., 15, 1692 42, 1272 i. 11 11 1? 247-250 u. c. 10-5 Perkin 45, 486 11 11 ! V j) 253 12 Jourdan .... 38, 314 11 11 11 ?) M 255 18 Perrot J., 10, 353 11 11 11 * 55 .... 11-12 Becker B., 11, 1413 34, 85.3 CHMe 2 .(CH 2 ) 3 .CHMe.COOII 244-246 c. LlQUld Kullhem A., 173, 319 vii., 898; 28, )> 354 C 7 H 15 .CH 2 .COOH 232 Licixud Venable B., 13, 1652 40, 82 1J Dibutylic carbonate (CH 3 .CH 2 .CH 2 .CH 2 ) 2 C0 3 C 9 H 1S 3 207 c. (740) .... Lieben and Rossi A., 165, 112 26, 367; vii., 217 Diisobutylic carbonate (CHMe 2 .CH 2 ) 2 CO 3 1> 190-3 c. ...> Rose A., 205, 232 40, 252 11 11 )i 11 190 Liquid Humann and Cler- A. C. [3], 44, 340 : i., 801 mont A., 93, 119 11 11 j 11 190 Wurtz A., 165, 109; J., vii., 217 ; 26, 7,574 367 Isoamylic ethylglycollate .... EtO.CH^COOCsHu 11 180-190 Liquid Siemens J. [1861], 452 il., 917 Ethylic isoamylglycollate .... C & H n .O.CH 2 .COOEt 11 212 Liquid 11 J. [1861], 451 a., ois 214 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diisopropylic lactate r~i~LJ / ^~LTf(~\~D-r* \ (~if~\f\~Dt, V^X3.y.\^JH( \JJTifi J.V^v'Vy-t TB C 9 H 13 O 3 s. a. 168 .... Silva B. S. [2], 17, 97 vii., 1016; 26, 367 Ethylic isoamylhydroxalate.... C 6 H u .CH(OH).COOEt B 203 Liquid Frankland & Duppa P. E. S. ; J., 18, iv., 276 382 Matezodambose ( + ) .... C 9 H 18 9 235 Girard C. R, 77, 995 27,169 Isouyl alcohol .... CjHjoO 205-212 .... .... Z. C. [1870], 404 11 11 "* C 8 H 1; .CH 2 .OH abt. 200 .... Pelouze & Cahours J. [1863], 529 iv., 134 11 11 186-189 .... Lemoine B. S., 41, 161 46, 1107 Heptylethyloxide Et.O.C 7 H ls 177 Liquid Wills 16, 312 iii., 149 Et.O.tCH^.CHj 165 (748-3) Liquid Cross A., 189, 5 32, 127 ,, .... 166-167 (755) Liquid 32, 128 Isobutylisopropylethylene CHBu0(OH).CHPr0(OH) C 9 H 20 O 2 _. 80-81 Foasek M. C., 5, 119 46, 833 glycol Amylidene diethoxide C 5 H 10 (OEt) 2 158-2 Liquid Alsberg J. [1864], 485 v., 974 Ethylic dipropylic ortho- CH(OPr) 2 (OEt) C^R W O 3 185-187 .... Pinner B., 16, 1643 44, 1089 formate Ethoxypropionic acetal EtO.C 3 H 5 .(OEt) 2 11 186 .... .... J. [1864], 495 Triethyl glycerol (triethyline) CH(OEt)(CH r OEt) 2 )! 185 Liquid Eeboul A., 119, 238 11 11 51 180-190 Liquid A. C. [3], 60, 5 ; ii., 884 C. R, 52, 466 11 11 11 186 Liquid Alsberg J, [1865], 495 ; v., 880 ; vi., 638 A., 131, 123 Tetraethylic orthocarbonate C(OEt) 4 C 9 H 20 4 128 .... Ladenburg A., 164, 300 26,50 ,, 158-159 .... Bassett J., 17, 477 Triethylpropyl phycite C 3 H 4 (OH)(OEt) 3 192-8 (758) Carius A., 134, 71 v., 895 C,H fi (OH)rO.C,H v (OH),L C H O 275-285 (10) Liquid Eeboul & Lourenco A. C. [3], 67, 299 ii., 894 Pyromellitic anhydride V ^3^^6\^^"^/L o-^a \ "^^/SJ* C 6 H 2 (C 2 0.,)(C 2 3 ) =1-2.4.5 C,H 2 0, 286 Baeyer As., 7, 37 vi., 812 Prehnitic anhydride .... ' .. =1.2.3.5 .... 239 A., 166, 328 vi., 811 Naphtholdiquinone .... .... C 10 H 4 4 .... 131 .... A. C. J., 2, 283 Furil C,,,H r O 162 E. Fischer A., 211, 214 42, 500 /3-Naphthaquinone m. p. 96 is a misprint ^10 6 .... d. 115-125 Steuhouse & Groves A., 189, 202 ; B., 32,53 14, 1658 ft- Ai d. 115-120 n.f. 110 Liebermann and A., 211, 36, 49 ; 42, 521 Jacobsen B., 14, 1313 - isomeric .... 11 113 Miller B., 14, 1600 40, 1041 *~ .... 119 0- .... 11 120 i, j3- .... a .... 124 n - 11 .... 123-124 Monnet, Eeverdin, B., 12, 2306 and Nolting a- .... ,, 125 11 a- .... ,, .... abt. 125 Groves A., 167, 357 vii., 836 ; 26, 210 a- .... }J 125 Glaus and Ochler B., 15, 312 42, 737 a- 125 Cleve B. S. [2], 26, 241 31, 208 a- .... 125 Plimpton .... 37, 633 a- U l a -2> H .... 125 Liebermann A., 183, 242 31, 601 J) C 10 H 8 .... 238 237-250 264 91 92 Baeyer j) 11 Griesa Eller A., 166, 335 A., 166, 328 A., 80, 281 ; As., 7,37 19, 90 G. J. C., 1869 vi., 811 j) vi., 812 v., 1093 278-S80 94 Schafer Z. C. [2], 5, 395 ; vi., 856 a- 94 Liebermann A., 152, 293 A., 183, 225 31, 607 a- 1 U 94 94 Palm Watson Smith B., 9, 499 30, 206 32, 563 94 Neville & Whither 37, 632 96 Maikopar Z C [2] 5 216 vi., 856 /3- 121-122 Gladstone & Tribe 39, 10 8- 285-290 122 Schafer A., 152, 293 ; vi., 856 B- 122 Calm Z. C. [2], 5, 395 B., 15, 609 42, 972 jS- 121 Walder B., 15, 2169 0- 122 Liebermann A., 183, 268 31,607 & 122 Palm B., 9, 499 30, 206 ft- 285-286 121 Ebert and Merz B., 9, 611 B- 122 Watson Smith 32, 563 B- 122 Meldola 39,41 B- 123 Maikopar Z. C. [2], 5, 215 vi., 856 Decacrylic acid Propionic couniarin Dihydroxynaphthalene (naph- thaquiuol) y- 11 11 11 11 11 11 11 11 11 "- 11 - 11 11 11 11 !) Benzoylacrylic acid 4-xH 2 O... Phenylsuccinic anhydride ... C 6 H 4 .O.CO.C,H 4 =1.2 C 10 H 6 (OH) 2 }) )> f) ) J) )> = 0l ; ^ ora,,; a 2 11 C 10 H fi (OH) 2 one or both (OH)-groups in /3-position BzCH : CH.COOH n CO.CHPh.CH.,.COO i i C 10 H 8 2 J) I) J) i) ) ) > ) )> C 1C H 8 3 I> 292-5 s. b. 160-170 d. b. 200 86 90 60(?) b. ioa 158 173 abt. 176 176 184 186 n. f. 230 Melts when heated on Pt. foil 99 ; 96-97 64 45-50 Siewert Perkin Liebermann Armstrong and Graham Plimpton Groves Cleve Weber Ebert and Merz Darmstadter and Wichelhaus Griess Pechmann 11 Spiegel Z. C. [2], 4, 383 J. [1875], 590 B., 14, 1313 ; A. 211, 58 B. S., 24, 515 26, 210 B. S. [2], 26, 241 B., 14, 2206 B., 9, 609 B., 2, 114 B., 13, 1959 B., 15, 885 ) B., 14, 873 vi., 496 28, 12 ; 36, 439 39, 141 37, 635 vii., 836 31, 208 42, 205 30, 410 vi., 857 39, 141 42, 1074 11 Methoxyphenylpropiolic acid Methoxycoumarin C 6 H 4 .OMe.(C 2 .COOH)=1.2 C 6 H 3 (OMe).CH : CH.CO.O J J> 124-126 d. 103 Perkin Tiemann & Miiller B., 14, 1996 39, 424 42, 53 Methylumbelliferone 0- Furoin.... =1.3.4 C 9 H 5 MeO 3 C 6 H.,(OH).CMe : CH.CO.O C 4 H 3 O.C.JI.,O.,.C 4 H. i O C.nHaO, .... 114 185 135 Tiemann & Eeimer Pechmann and Duisberg Fischer B., 12, 996 B., 16, 2119 B., 13, 1335 38, 721 46, 66 38, 798 135 A., 211, 218 42, 499 Phenylfuraaric acid Benzalmalonic acid .... Cinnamo-carbouic acid 11 11 Benzhydrylacetcarbonic COOH.CPh : CH.COOH CHPhrC(COOH)., COOH.(CH :CH.COOH)=1.2 O.CO.C 6 H 4 .CH.CH. 2 .COOH 1) > 1 i) )) .... 161 195 173-175 173-175 150 Barisch Claisen andCrismer Gabriel & Michael )! 11 11 J. p. [2], 20, 186 A., 218, 129 B., 10, 1551 B., 10, 2203 B., 10, 2201 38, 43 46, 444 34, 230 34, 426 11 anhydride 15 11 =1.2 i) i) 11 .... 150-151 11 11 B., 10, 1558 34,230 216 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet & J. Ch. Soc Methylene caffeic acid CH 2 1 2 1 C 6 H 3 (CH) 2 .COOH C 10 H 8 4 .... 232 Lorenz B., 13, 757 40, 49 Methoxyhydroxycoumarin .... _ .... 184 Tiemann and Will B., 15, 2075 44, 199 (methyloesculetin) Dihydroxymethylcoumarin .... C 6 H 2 (OH) 2 .CMe : CH.COO .... 235 Pechmann and B., 16, 2119 46,67 r i Duisberg Tetrahydroxynaphthalene ... C 10 H 4 (OH) 4 225 A. C. J., 2, 283 Furilic acid .... C(OH)(C 4 H 3 O)j.COOH C nHgOj d. 100 Solid E. Fischer A., 211, 222 42, 500 Phthalylacetic acid +H 3 O ... (COOH). (CO.CH S .COOH) 90 d. Gabriel & Michael B., 10, 1553 U4, 229 =1.2 Hemipinic anhydride C 6 H 2 (OMe) 2 :(CO) 2 :0 166-167 c. Beckett & Wright J. [1876], 807 29, 282 =1.2.4 (3 or 5) v ,, 166-167 ., it 29, 468 D 167 Priuz J. p., 24, 371 42, 403 Dioxynaphthalic acid C 8 H 4 (OH) 2 (COOH) 2 C 10 H 8 O 6 126 Hermann A., 151, 69 vi., 858 Prelmomalic acid .... C 10 H 8 9 210 Baeyer B., 4, 275 ; A., vi., 811 166, 327 From polyporic acid .... (C 10 H 9 0) B *... 156 Stahlschmidt A., 195, 365 36, 382 Methylic polyporate (C 10 H 9 O.,) n .... 187 A., 187, 177 32, 621 Acetocinnamone (benzyl- C 6 H 5 .CH : CH.CO.CH 3 C 10 H 1U O 240-241 Liquid Engler and Leist B., 6, 254 vii., 12; 26,901 idene acetone) 260-262 41-42 Claiseu & Claparede B., 14, 2461 42, 511 From chloranethol .... ^ .... ( ? ) " 240 .... Gladstone 23, 147 vii., 72 (?) .... 240-242 Liquid Ladenburg Z. C. [2], 5, 575 vi., 157 Benzylchloride on phenyl .... 290-300 39 Perkin and Hodg- 37, 722 acetate kinson Allylic benzoate C 6 H f .COO(C 3 H 5 ) CiuH 10 O 2 228 Liquid Hofmann & Cahours A., 102, 297 m 230 . Berthelot and De A. C. [3], 48, 286 Luca ,, ,, .... Sjg .... Ziuin A., 96, 362 Methylic cinnamate C 6 H 5 .CH I CH.COOMe n 241 Liquid Kopp C. R., 21, 1376 i., 986 ^ 241 Liquid A., 60, 269 34,981 n 259-6 .... Weger A., 221, 61 46, 11 263 33-4 Anschiitz and Kin- B., 11, 1220 34,981 nicutt Phenylcrotonic acid C 6 H 6 .CH : CH.CH 2 .COOH 78 Stuart .... 43, 404 n 78 288 .. A., 204, 189 n .... 82 Perkiu .... 31, 392 Iso-pheuylcrotonic acid C 6 H 6 .CH : CMe.COOH () S02 86 Jayne A., 216, 98 44, 472 i) n 83-84 Perkin .... 31, 395 Phenylbutyro-lactone Ph.CH(CHA.COO 305-320 34-35 Pechmann B., 15, 890 42, 1074 i " i " 306 37 Jayne A., 216, 103 44, 472 Benzoyl propylaldehyde CHjBz.CHj.CHO 235 Liquid Burcker C. R.,94,220;B., 42, 730 15, 731 Benzoyl acetone CH 2 Bz.CO.CH 3 t) 58 Fischer and Kuzel B., 16, 2239 46,59 Propenylbenzoic acid C 6 H 4 .C 3 H 5 .COOH=1.4 160-161 Meyer and Rosicki B., 11, 1792 36, 157 Isopropenylbenzoic acid = n 255-260 .. B., 11, 2173 36, 466 Hydrindonaphthalene car- CH 2 .C 6 H 4 .CH 2 .CH.COOH 130 B;eyer and Perkin B., 17, 132 46, 753 V 1 1 i j boxyhc acid Safrol R'*\ 1ft Arzruni N. R. P., 25, 615 32, 202 " "" O *J L\J L 20 Grimaux & Ruotte A., 152, 89 vi., 1014 From sassafras oil C U1 H 10 0, 235 St. Evre A. C. [3], 12, 107 v., 199 Acetylcarbinol benzoate Me.CO.CH.,OBz 189-190 (50- 23-5-24 Breuer and Zincke B., 13, 639 38, 646 60) ; 200- 201 (80- 90) ; 263- 264 (760) ,, 51 H 25 Romburgh R. T., 1, 53 ; B., 44, 63 Hi, 419 Benzoyl carbinol acetate C 6 H 5 .CO.CIL.OAc n .... 40 Hunuius B., 10, 2010 n > .... 270 44 Ghrnbe B., 4, 35 24, 223 COMPOUNDS CONTAINING THREE ELEMENTS. 217 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' D ict. & J. Ch . Soc. Benzoyl carbinol acetate C.jHj.CO.CHj.OAc C 10 H 1( ,0 3 49 Hunseus & Zinck6 B., 10, 1488 34, 224 11 11 n H .... 49-49-5 A., 216, 308 Ethylic benzoyl formate Ph.CO.COOEt 11 250-255 Claisen B., 10, 844 32,616 11 11 11 n 256-257 (760) .... n B., 12, 629 36, 648 ii 11 11 257 .... Gabriel B., 16, 517 44, 920 Benzoyl propionic acid Ph.CO.CH 2 .CH 2 .COOH .... 115-116 Pechmann B., 15, 889 11 11 11 1) 11 .... 116 Burcker B. S. [2J, 35, 17 40, 273 Phenylhydroxycrotonic acid Ph.CH : CH.CH(OH).COOH IT 115 Matsmoto B., 8, 1144 29,80 Metliylic acetylbenzoate C 6 H 4 .Ac.COOMe=1.4 .... 92 Meyer B., 12, 1072 36, 795 Propiophenone carbonic acid C 6 H 4 .(CO.Et).COOH=1.2 91-92 Gabriel & Michael B., 11, 1014 34,735 a-Methoxyphenyl acrylic acic OMe.(CH : CH.COOH)=1.2 .... 88-89 Perkin .... 31, 419 (methylcoumaric) *~ 11 11 11 11 11 .... 178-179 .... 39, 411 P~ n 11 i 11 11 182-183 .... 31, 414 11 11 11 r, 11 ., 182-183 .... 31, 420 ft- ,, 11 11 i' 11 183 n .... 31, 421 p- 11 11 ii T) 183 11 .... 31, 422 11 11 11 =1.3 115 Tiemann & Ludwig B., 16, 2051 44, 189 11 11 11 =1.4 .... abt. 171 Perkin 31, 409 Allylsalicylic acid C 6 H 4 .OC 3 H 5 .COOH=1.2 .... 113 Scichilone G. I., 12, 449 ; B., 44,336 16, 796 11 17 " =1.3 .... 118 11 11 n ,i 11 11 "" =1.4 .... 123 11 11 )J Acetoxytoluic aldehyde COH.Me.OAc=1.3.2 11 267 1. f. m. Barbier C. R., 90, 37 ; 38, 318, 468 B. S., 33, 54 11 n =1.3.4 ,, 275 Liquid II )! 11 J! 11 = 11 ... 39-40 Staats B., 13, 139 38, 385 11 11 = 1.3.6 .... 57 Schotten B., 11, 786 34, 878 Cubebin 125 Weidel W. A., 74, 377 34, 80 Curcuniin " Daube N. R. P., 20, 36 ; 24, 153 ; " egms B., 3, 609 vii., 404 see C 14 H, 4 O 4 178 Jackson B., 14, 485 40, 611 Benzolactic acid C 2 H 4 BzO.COOH C 10 H 10 4 112 Strecker A., 80, 42; 91, i., 561 359 Benzylmalonic acid .... Ph.CH 2 .CH(COOH) 2 ,, .... 117 Conrad B., 12, 752 ; A., 36, 707 204, 175 Phenylsuccinic acid COOH.CHPh.CH 2 .COOH 159-5-162 RUgheimer B., 14, 428 40, 600 n 11 ' .. 167 Spiegel B., 14, 1693 40, 1037 11 11 .... .... 166-167; 166 11 B., 14, 873 Diacetoxy benzene .... C H 4 (OAc), =1.3 378 u. c. I. f. m. Typke B., 16, 551 44,917 isomeric (?) 11 11 273 (708) Nencki and Sieber J. p. [2], 23, 149 ; A., 138, 78 11 11 11 11 11 n 303 72 11 n J. p. [2], 23, 147 40, 591 =1.4 121 Hesse A., 200, 244 38, 317 n 11 11 11 120 Nietzki B., 11, 470 11 11 123-124 Rakowski N. H. G, 2, 560 ; A., 209, 128 Ohnethylic phthalate C 6 H 4 .(COOMe) 3 =1.2 9t 280 c. (734) Grwbe B., 16, 861 Diiuethylic isophthalate =1.3 63-65 Bseyer A., 166, 340 26, 756 11 ii 11 6^-65 Ador and V. Meyer B., 4, 262 24, 367 11 11 .... i. i, 64-65 Meyer A., 156 or 159 vii., 978 terephthalate .... =1.4 .... a. 100 De La Rue and A., 121, 89 v., 727 MUller i, 11 11 11 140 Beilstein A., 132, 269 11 11 .... " ) M .... 140 Grimanx A. C. [4], 26, 331 25, 817 Xylenedicarbonic acid C 6 H 4 (CH 2 .COOH) ;! =1.2 150 Basyer and Pape B., 17, 447 46, 898 11 11 = 1.4 H 2.36 Biedermann B., 5, 703 11 11 11 11 ,, .... 244 Klippert B.,9, 1766 31, 468 Hyd rocinnaraocarbonic acid COOH.(CH 2 .CH 2 .COOH) 165-166 Gabriel and Michael B., 10, 2203 34, 427 = 1.2 2 F 218 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Acetoxymethoxybenzalde- COH.OAc.OMe =1.2.5 C 10 H 10 4 .... 63 Tiemauu & Miiller B., 14, 1995 42, 53 hyde =1.4.5 77 Tiemann and Nagai B., 11, 647 34, 579 =1.4.6 11 86 Tiemann and B., 13, 2374 40, 271 Parrisius Ferulic acid (CH : CH.COOH).OMe.OH 153-154 Hlasiwetz & Earth A., 138, 64 34, 579 ; vi., =1.3.4 227, 616 168-169 Tiemann and Nagai B., 9, 416 ; 11,650 34, 579 JJ )) 168-169 Iscferuiio acid (hesperetic) .... =1.4.5 11 .... 211-212 11 11 B., 11, 654 34, 580 ii 11 11 i> sb. 223 d. 225 E. Hoffmann B., 9, 686 30, 421 11 ii .... MS Tiemann and Will B., 14, 955 40, 740 Methylene hydrocaffeic acid CH 2 : 2 : C 6 H 3 .(CH 2 ) 2 .COOH ii .... 84 Lorenz B., 13, 758 40,49 =4.3.1 Cumidic acid (fromMe 4 = Me,,.(COOH) 2 = ? ,, .... n. f. at a Jannasch Z. C. [2], 6, 449 vi., 828 1.2.4.5) moderately high temp. Isocumidic acid =1.3.4.5 ii .... 278-280 Jacobsen B., 15, 1857 Resacetophenone acetate .... 303 72 .... J. p. [2], 23, 147 Meconin .... C 6 H 2 (OMe) 2 .CH 2 .O.CO 90 Couerbe A., 5, 180 iii., 862 i i =1.2.4. (3 or 5) 98-99 Matthiessen and 16, 349 iii., 862 " Forster n 11 .... 102-102-5 Beckett and Wright B., 9, 73 29, 282 Benzylhydroxymalonic acid Ph.CH 2 C(OH)(COOH) 2 C, H 10 O S 143d. Conrad A., 209, 245 ; B., 40, 168 13, 2159 Acetoxymethoxybenzoic acid COOH.OMe.OAc =1.3.4 .... Ufi Tiemann and Nagai B., 8, 1142 29,78 11 )i .... 142 Matsmoto B., 11, 122 34, 501 ii >i =1.4.5 .... 206-207 B., 11, 130 Dimethylic hydroxytereph- (COOMe) 2 .OH =1.4.5 94 Burkhardt B., 10, 146 32, 337 thalate ii 11 )* J) .... 96 Ost J. p. [2], 15, 301 32, 486 Dimethylichydroxyisophtha- =1.3.4 96 Jacobsen B., 11, 379 34, 583 late =1.3.5 159-160 Heine B., 13, 496 38, 550 Ethoxyterephthalic acid (COOH) 2 .OEt =1.4.5 .... 252-253 Paternd and Can- G. I., 9, 455 38, 247 zoneri i. 253-S54 11 ii M ii Dimethoxybenzoyl carbonic (OMe) 2 .(CO.COOH) =1.2.4 11 .... 138-139 Tiemann and Mata- B., 11, 142 34, 503 acid moto Opianic acid .... COOH.(OMe) 2 COH =1.2.3.6 .... 140 .... .... iv., 205 145 Richter Tabellen 11 11 " "" 150 11 Isopianic acid =1.3.4.5 I) 210-211 Tiemann and B., 10, 397 32, 487 Mendelsohn Methylic aldehydovanillate COOMe.OMe.OH.COH B 134-135 Tiemann and Men- B., 10, 396 32, 487 =1.3.4.5 delsohn Plumieric acid C,H 2 .(CH 2 OH)(C 2 H 2 .COOH) J) 139 Oudemans A., 181, 161 30, 422 (OH), Metacamphretic acid .... M ... 89 Schwanert A., 128, 77 iv., 757 Pyrocinchonic acid C 8 H 8 .OH.(COOH) 2 H .... 95 Weidel A., 173, 76 28, 89 Larixinic acid .... 11 sb. 93 153 Stenhouse P. T. [1863], 53 ; iii., 471 A., 123, 191 Atraric acid .... 140-141 Paterno G. I. [1882], 231 42, 1084 Colein .... .... " .... n. f. 100 Church 31, 260 Ethylic acetylcomenate C 5 H 2 O 2 .OAc.COOEt Clu H 10 6 104 Reibstein J. p. [2], 24, 277 42, 197 Phenylene dioxyacetic acid.... C 6 H 4 (O.CH 2 .COOH) 2 =1.3 .... 193 Gabriel B., 12, 1640 38,33 Hemipinic acid (COOH) 2 .(OMe) 2 =? 165 Schmidt B., 16, 2589 46, 340 = 1.2.3.4 180 .... iii., 142 >i ii ii 180-181 Beckett & Wright .... 29, 469 ii 11 " 11 180-181 d. ii 11 ... 29, 465 COMPOUNDS CONTAINING THREE ELEMENTS. 219 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Hemipinio acid (COOH) 5 .(OMe) 2 =1.2.3.4 CioHicAi 181-182 c. Beckett & Wright .... 29, 282 ii n .... 182-183 11 11 29, 468 Isohemipinic acid 11 i) 11 .... 245-246 Tiemann and Men- B., 10, 398 32,488 delsohn Ethylic quinonehydrodicar- C 6 H 2 H 2 : 2 .COOH.COOEt 11 .... 184 Hermann A., 211, 331 42,714 boxylate Acid from gum ammoniac .... 11 .... 265 d. Goldschmidt B., 11, 851 34,738 resin Ethylic carbogallate (OH) 8 .(COO.COOEt) =1.2.4.5 fc,oH,A(?) .... 116-5 u. c. Drechsel and Moller J. p. [2], 17, 163 34,784 Isohydropyromellitic acid .... .... CioH 10 O 8 .... 220 As., 7, 26 Decylaldehyde CH 3 .(CH, ! ) 9 .CHO C 10 H 12 106 (15) Krafft B., 16, 1714 44, 1075 Propylphenyl ketone C 6 H 5 .CO.Pr" i 218-221 Liquid Popoff B., 6, 560 26, 1037 11 )) )5 JI 220-222 1. 20 Schmidt & Fieberg B., 6, 498 27,75 i) )) )1 0tf)/l 0^5> xf,3l/ */& Liquid Perkin 45, 181 Isopropyphenyl ketone C 6 H 5 .CO.Pr/s n 209-217 Popoff B., 6, 1255 Benzylethyl ketone . C 6 H 5 .CH 2 .CO.Et i 225-226 .... n B., 5, 501 25, 821 Methylphenethyl ketone .... C 6 H 5 .CH 2 .CH 2 .COMe v 225-230 Ceresole B., 15, 1876 , ii ) 233-234 (725) .... Jackson B., 14, 890 40, 742 ii " J) 235 .... Ekrlich B., 7, 683 27, 885 ii ii ) i 285-236 .... A., 187, 16 32, 438 Phenylvinyl ethyl oxide PLCH : OH.O.Et ji 217 Liquid Erlenmeyer B., 14, 1868 42, 191 Ethyl phenylacetylene alcohol CHPh : C(OH)Et or 224-226 Liquid Morgan J. [1876], 398 29, 163 CHEt : C(OH)Ph Butenyl phenol C 6 H 4 .OH.C 4 H 7 =1.2 223-225 Liquid Perkin 35, 143 =1 4 230-235 s f m 35, 145 JJ ~"- 1 -^ i n MM Allyl methoxy benzene C 6 H 4 .(CH : CHMe.)OMe=1.2 ji 222-223 1. f. m. 11 B., 11, 515 33,213 ii ii JT I) v 222-223 11 n 39, 435 (anethol) =1.4 5) 232 11 >! 33,215 ii i> 11 11 )5 226-230 Landolph C. R., 81, 97 29, 246 >i >i " 11 i JI 232 Perkin .... 32, 673 !I JI " 11 11 J> 232 21 Kraut and Schlun Z. C. P. [1863], 359 vi., 156 II " " 11 11 )i 21-3 Schiff A., 223, 247; 46, 1089 G. I., 14, 181 II II n 11 )) 230-240 Solid Perkin 32, 669 II " " Probably (C 10 H 12 O) 2 i 228-230 Solid Landolph C. R., 82, 849 80, 79 (C,,,H,.O), 232-5 IC.i'sut find. Sclilxin Z. C. P. [1863], 359 vi., 156 \^W 12 / a. 300 1JM -p j A., 187, 70 32, 480 Anisoin Jj ) L0B 140-145 _L ci rciioiiu. Riclitcr Tabellen Oumiuic aldehyde (cuminol) I) C 6 H 4 .Pr.COH =1.4 217=222 c. Lippmann& Strecker W. A., 78, 570 38, 251 11 ii >i " )) 222 c. Liquid 11 B., 12, 76 36, 464 11 ii ii ?) )) )j 220 Liquid Gerhardt & Cahoura A. C. [3], 1, 60 ii., 182 ii 11 ii I) 223 u. c. Etard C. R, 90, 534 38, 468 11 11 ii J' )J jj 230 .... Eaab B., 8, 1148 29, 398 11 11 V 7 1 236 Widmann B., 15, 166 42,727 11 II 11 fi n 228u.c.(704'5) .... Meyer B., 10, 150 236-Bc.(760r.) II II 11 Ji )? ) 236-6 (748) Kopp A., 94, 316 ii., 182 Isocuminic aldehyde ... .... abt. 220 80 Etard A. C. [5], 22, 259 40, 582 Terecuminic aldehyde ) 219-220 .... >i it 11 11 )> .... ) 229 .... Kopp 11 i Methylphenylcarbinol acetate C 6 H 6 .CH(OAc).CH, C 10 H 12 2 213-216 Eadziszewsky B., 7, 141 27, 469 11 11 1! 217-220 Z. C. [1871], 132 Benzyl carbinol acetate C B H 5 .CH 2 .CH 2 .OAc 224 Liquid Radziszewsky B., 9, 373 30, 78 Benzylic propionate CH 3 .CH 2 .COO.CH 2 Ph i 219-220 .... A., 193, 312 Propylic benzoate C 6 H 5 .COOPr jj 229-47 Linnemann A., 161, 28; 162, vii., 203, 1013; 39 29, 235 11 11 )) 222-5 .... . M. C., 2, 695 Isopropylic benzoate C 6 II 5 .COOPr0 D 218 (762) Liquid Silva B. S., 12, 225; vi., 966 Z. G, 12, 637 Ethylic phenyl acetate C 6 H 6 .CH,.COOEt 226 Liquid Radziszewsky Z. C. [2], 5, 358 ; vi., 1101 B., 2, 208 11 11 11 11 j) 229 c. Liquid Hodgkiugon .... 37, 481 2 F 2 220 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J . Ch. Soc. Methylic phenyl propionate C 6 H 5 .CH 2 .CH 2 .COOMe CjoHuO., 238-239 Liquid Erlenmeyer A., 137, 334; J., vi., 469 19, 366 jj j jj C 6 H 5 .C 2 H 4 .COOMe JJ 236-6 Wegev A.. 221, 61 46, 11 Methylbenzyl acetic acid ... C 6 H 5 .CH 2 .CHMe.COOH JJ 275 34 Conrad B., 11, 1055 34, 732 jj jj jj JJ JJ 272 37 Conrad and Bischoff B., 13, 595; A., 38, 628 204, 181 Phenylbutyric acid Ph.(CH 2 ) 3 .COOH JJ 290 47-5 Jayne A., 216, 107 44, 473 Xylylic acetate C 6 H 4 .Me.CH 2 OAc JJ 226 Liquid Vollrath A., 144, 262 v., 869 )i =1.3 JJ 226 Liquid Radziszewsky and B., 15, 1747 Wispek Ethylic toluate C 6 H 4 .Me.COOEt=1.2 JJ 219'5 (713) Ador and Rilliet B., 12, 2301 jj j, =1.3 JJ 224-5-226-5 i) 11 (710) jj =1.4 JJ 9*8 Liquid Noad P. M. [3], 32, 25 v., 864 jj ,, JJ JJ JJ 228 .... Wurtz B., 12, 2301 Propylbenzoic acid (iso- C 6 H 4 .Pr.COOH= ? JJ 116-117 51 Etard A. C. [5], 22, 218, 40, 582 cuminic) 287 Propylbenzoic acid (cuminic) C 6 H 4 .Pr".COOH=1.2 JJ .... 58 Gabriel & Michael B., 11, 1014 34, 735 ^ jj C 6 H 4 .Pr.COOH= ? JJ abt. 250 92 Gerhardt & Cahours A. C. [3], 1, 70 ii., 178 jj jj jj C 6 H 4 .Pr0.COOH=1.4 J> 110 Meyer and Mliller B., 15, 496 44,63 jj jj jj JJ JJ JJ 114 Beilstein & Kupffer B., 6, 1184 vii., 403 jj jj jt JJ JJ JJ .... 114-115 Paternd and Spica G. I., 7, 361 34, 296 jj jj jj JJ JJ JJ 114-116 Meyer and Eosicki B., 11, 1791 jj jj jj JJ JJ JJ .... 115 Gerhardt .... vii., 403 j* ?* jj JJ JJ JJ 115 Nencki and Ziegler B., 5, 751 26,64 jj jj jj JJ JJ JJ .... 115 Persoz A., 44, 312 jj jj jj JJ JJ JJ 115 Meyer B., 10, 153 jj jj jj JJ JJ JJ 116-117 Meyer and Mtiller B., 15, 1903 44, 63 jj jj u JJ JJ JJ .... 116-117 !> >! 11 11 jj jj jj JJ JJ JJ .... 116-117 Jacobsen B., 12, 1516 38, 39 jj jj jj C 6 H 4 .Pr.COOH=1.4 JJ .... 137 Francksen B., 17, 1220 46, 1009 jj jj tj JJ JJ JJ 138-139 Paterno and Spica B., 10, 1746 34, 139 jj jj jj JJ JJ JJ 138-139 ii n G. I., 7, 361 34, 296 jj jj * JJ JJ JJ .... HO Korner B., 11, 1866; A., 31, 142 ; 44, 216, 228 322 jj jj jj JJ JJ JJ 140 Meyer and Muller B., 15, 698, 1905 Terecuminic acid JJ .... 128-129 Etard A. C. [5], 22, 218 40, 582 Methylhydrocinnamic acid .... Me. (CH 2 .CH 2 .COOH)= 1 .4 JJ .... 103 Gerichten B., 11, 1719 36, 230 Acetxylenol .... Me.Me.OAc=1.3.4 226 LiQiiid Jacobsen B., 11, 25 34, 412 J "| J- a j *ju =1 45 237 c. (768) Liu iiid B., 11, 28 11 J..-X.U JJ H 11 Dimethylphenyl acetic acid.... Me 2 .(CH 2 .COOH)=1.3.5 JJ 273 (735) 100 Wispek B., 16, 1577 44, 1096 jj jj Jt l JJ JJ .... 97 Eobinet B.,16,965;C.E., 96, 500 Eugenol (eugetic acid) (CH:CHMe).OMe.OH= 1 .4.3 JJ 242 Liquid Stenhouse A., 95, 106 ii., 604 ; jj jj jj !> JJ 243 .... Ettling A., 10, - j* jj jj 11 11 JJ 243 Gladstone 25, 2 jj jj 11 11 JJ 244 u. c. .... Church B., 7, 1551 28, 113 =251-8 c. jj jj jj 11 JJ 247-B (760) Wassermann A., 179, 369 29, 706 u jj jj >1 11 JJ 251 (760) .... Williams Chem.Gaz.[1858], ii., 604 170 jj jj jj !1 11 JJ 251 Gladstone 17, 6 vi., 608 jj jj jj II JJ 252 .... )! 11 11 (CH 2 .CH : CH 2 )(OMe)(OH) 247-249 Tieniann and Kraaz B., 15, 2059 44, 201 Isoeugeuol (CH:CHMe)(OMe)(OH) 1J JJ 258-262 .... 11 )i B., 15, 2065 11 =1.3.4 Eugenol .... (polymer) (C.oH.A). JJ a. 100 Erlenmeyer B., 9, 273 y-Isoduric acid Me 3 .COOH=1.2.4.6 JJ .... 84-85 Jacobsen B., 15, 1856 44, 53 ft' jj jj = 1.3.5.6 JJ 120-123 Bielefeldt A., 198, 387 38, 38 Duric acid =1.2.4.5 140-150 Jannasch Z. C. [1870], 449 vi., 828 JJ 149 Eeuter B., 11, 31 34, 413 i ii ii ii JJ H 11 150 Gissmann A., 216, 206 44, 334 COMPOUNDS CONTAINING THREE ELEMENTS. 221 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. /3-Isoduric acid Me 3 .COOH=l. 3.5.6 C 10 H 12 2 .... 151 Jacobsen B., 15, 1855 44,53 a- = 1.2.3.5 215 Bielefeldt A., 198, 385 38, 38 a- 11 11 .... 215-216 Jacobsen B., 15, 1855 44,53 Thymoquinone .... 11 .... 45-46 Sigel A., 170, 345 27, 378 11 Me.Pi 11 11 11 246-248 (732) Schreiner A., 197, 18 I, 11 11 11 235 .... Folsing B., 17, 486 46, 897 (anisate) =1.4 250-255 Liquid Cahours A. C. [3], 14, 492 i., 301 Methylic ethoxybenzoate .... C 6 H 4 .OEt.COOMe =1.2 265 Kraut, Schroder, & A., 150, 1 vi., 1006 Prinzhorn i. 11 i. 11 256-257 (732) Schreiner A., 197, 18 ,, 11 11 11 245 Folsing B., 17, 486 46, 897 Isopropoxybenzoic acid C 6 H 4 .OPACOOH =1.2 1. 20 Kraut, Schroder, & A., 150, 1 vi., 1006 Prinzhorn Ethylic tolylic carbonate .... C f H 4 Me.(.OCOOEt) =1.2 235-237 Liquid Bender B., 13, 699 40,48 11 ii 11 =1.3 245 Liquid B., 13, 700 J? ii 11 ii =1.4 245-247 Liquid 11 Ethylichydroxyphenylacetate C 6 H 4 .OH.CH 2 COOEt = ? 251 .... Fritsche J. p. [2], 19, 33 36, 322 Hydroxypropylbenzoic acid.... C 6 H 4 .COOH.C 3 H 6 OH =1.4 .... 155-156 Meyer B., 11, 1285 34, 879 11 ii 11 11 155 Meyer and Rosicki B., 11, 1792 ii ii 11 11 n 155 11 11 B., 11, 2172 n 11 11 11 ,, 155 Meyer and MUller B., 15, 699 Methoxyphenylpropionic acid OMe.(CH 2 .CH 2 .COOH) =1.3 51 Tiemann & Ludwig B., 15, 2051 44, 189 n n =1.2 92 Perkin 39, 416 n 11 =1.4 101 11 J. [1877], 792 31,411 11 n OMe.CHMe.COOH =1.4 11 .... 103-4 Kbrner & Corbetta B., 7, 1732 28, 458 (methylphloreticj Ethoxyphenylacetic acid OEt.(CH 2 .COOH) =1.4 88 Salkowski B., 12, 1440 38,252 Coniferyl alcohol (CH : CH.CH 2 OH).OMe.OH 73-74 Tiemann and Haar- B., 7, 612 27, 895 =1.3.4 11IH1IM 11 11 H 74-75 Tiemann B., 8, 1130 29, 77 Ethylvanillin .... COH.OMe.OEt. =1.3.4 KA ft^ B., 8, 1129 29, 76 ,, .... O-* OG ii (K Millar A., 188, 184 34, 159 Methoxyacetoxytoluene ii 11 Me.OMe.OAc =1.3.4 I 245 \J 38-140 .'l 1111:1 n n & Lange B., 13, 1663 40, 276 11 11 11 JI 41-143 Earth B., 11, 1571 36, 158 11 J* i) 43 11 B., 11, 567 34, 574 Isopropylhydroxybenzoic ack COOH.OHPr0 =1.2.4 (?) .... 88 Tacobsen B., 12, 432 36,624 11 11 11 11 .... 93 11 B., 11, 1061 JJ 11 11 n .... 93 11 B., 11, 573 34, 584, 732 11 11 =1.3.4 66-170 11 B., 12, 433 36, 625 Methylic hydroxymesity- COOMe.OH.Me a =1.2.3.5 jj .liquid 11 A., 195, 265 36, 530 lenate 11 11 =1.4.3.5 .... 130 11 B., 12, 608 36, 643 Ethlmethylhydroxybenzoic COOH.OH.Me.Et =1.2.3.5 147-149 11 A., 195, 284 36, 531 acid Hydroxythymoquinone Me.Pr.OH ! O 3 =1.4.2.5.6 1) 165 Zincke B., 14, 97 11 JJ JI 165-166 Carstanjen J. p. [2], 15, 400 11 U JJ 166-167 Schulz B., 16, 901 11 =1-4(1), JJ 169 Ladenburg B., 10, 611 32, 477 .... JJ IJ w .... 169-172 Lfldenburg and B., 10, 1219 Engelbrecht ., = Ji 169-175 Carstanjen J. p. [2], 15, 400 32, 614 11 =1-4(1), 11 .... 173-174 Ladenburg B., 10, 49 32, 891 11 11 IJ H 174-175 Zinck6 B., 14, 97 40, 596 ,, =1.4.2.3.6 u .... 183-185 Liebermann B., 10, 79 11 =1.4(1), Ji .... 187 Ladenburg B., 10, 611 32,477 =1.4.6.2.3 ji 187 uncor. Carstanjen J. p. [2], 3, 50 24, 352 ; vii., 1156 11 =1-4(1), JJ .... 183-221 11 J. p. [2], 15, 400 32, 614 Methylatrolactic acid Nonodilactone xCH^ (CHMe<^ >C) 2 X OOC X jj a. 360 s. d. Crystalline 105 Bottinger Hjelt B., 14, 1598 A., 216, 52 40, 1036 44,456 Ethylic dehydracetate Glycerol monobenzoate CH 2 Ac.C : CH.C(COOH):COH " 320 91-6 nearly s. 40 Oppenheim & Prech Berthelot B., 9, 1100 A. C. [3], 41, 290 i., 559 C 3 H 6 .(OH) 2 (OBz) Isobenzoglycol diacetate C,H 6 (OAc) 2 JT abt. 300 121 Renard C. R, 91, 175 38, 802 Ethylic vanillate COOEt.OH.OMe =1.4.3 291-293 44 Tiemann and Men- B., 10, 59 32, 889 delsohn Methylic dimethoxybenzoate COOMe.(OMe) 2 =1.3.4 B .... 58 Korner G. L, 6, 142; 31,89 J. [1876], 601 11 n H JJ 300 59-60 Matsmoto B., 11, 127 34, 501 11 11 =1.2.3 ;) .... 164-165 Wegscheider M. C., 3, 348 42, 1207 Ethoxymethoxybenzoic acic COOH.OMe.OEt =1.3.4 ( .... 190 Wassermann A., 179, 379 29, 707 11 11 11 11 193-194 Tiemann B., 8, 1130 29, 76 U 11 11 11 .... 195 A. C. J., 4, 77 a-Homoveratric acid (CH 2 .COOH).(OMe) 2 =1.3. +XH..O 98-99 Tiemann & Matsmol B., 11, 143 34,503 Hydroferulic acid (C,H 4 .COOH).OMe.OH .... 89-90 Tiemann and Naga B., 11, 650 34, 580 = 1.3.4 Hydroisoferulie acid =1.4. B 146 11 11 B., 11,656 11 11 11 11 11 * 147 Tiemann and Will B., 14, 965 Hydroxypropyl hydroxyben COOH.(CMe 2 OH).OH=1.4 ,1 173 Widrnann B., 17, 722 46, 1022 zoic acid Ethylic clihydroxytoluic ack COOH.(OH) 2 .Me =1.2(1), 11 97-98 M. C., 2, 463 11 11 11 = (?) 104-5 Kane P. T., 1840 iv., 236 (orsellinate i- 11 11 > JJ 11 .... a. 120 Heeren Schw. J., 59, 34 11 11 11 U JJ u a. 127-5 Hesse A., 117, 314 JJ n 11 11 >' JJ 11 .... 132 Richter Tabellen COMPOUNDS CONTAINING THREE ELEMENTS. 223 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Dihydroxythymoquiuoue ... Me.Pr.(OH) 2 : 3 =1.4 (?) 4 C 10 H,A .... 213 Zinck6 B., 14, 95 40,596 ... 1) 11 .... 220 Ladenburg and B., 10, 1223 34, 60 Engelbrecht Cantharidin .... .... d. 210 218 c. Piccard B., 10, 1504 34, 233 .... 250 Text books Cantharic acid C 6 H 4 .H 4 .CH 2 .O.CO.CH. 278 c. Piccard B., 10, 1505 ; 11, i i COOH 2120 Xanthoxylin .... 80 A., 80, 251 ; 104, 238 Ethylic dehydromucate C 4 H 2 0.(COOEt) 2 C 10 H 12 O 6 46-47 Fittig B., 9, 1198 31, 65 ,, 47 Heinzelmann A., 193, 190 36, 141 carbopyrotritartrate COOEt.CHAc.CH C : CH 2 80-81 ; 81-82 Harrow A., 201, 152 33, 433 CO O Ethylic succinylsuccinate .... CHj.CO.CH.COOEt C 10 H, 3 O 6 98 Hermann A., 211, 319; 32, 319 1 1 B., 10, 109 CHj.CO.CH.COOH i. .... 100 Duisberg B., 16, 135 Oil from nutmeg .... (C^H^O,,). 260-280 Liquid Wright B., 6, 147 vii., 862 ; 26, 549 .... 280-290 Liquid ii ii Disacryl resin .... (C 10 H 13 3 ) a .... 100 Redtenbacher A., 47, 114 ii., 337 Isobutylphenyl oxide C 6 H 6 .O.CH 2 .CHMe 2 C 10 H 14 198 .... Riess Z. C. [2], 7, 39 ; 24, 221 B., 3, 780 Methylphenylcarbinol ethyl C 7 H 6 Me.OEt 185-187 Thorpe Z. C. [1871], 131 22,412 oxide Dimethylbenzyl carbinol .... (C 6 H 6 .CH 2 )Me 2 C.OH ii 220-230 20-22 Popoff B., 8, 768 29, 695 Propylphenyl carbinol C 6 H 6 .CH(OH).Pr ii ? .... .... .... vii., 931 Methylplienethyl carbinol .... Ph.(CH 2 ) 2 .CH(OH).Me 68 Engler and Leist B., 6, 255 Ethyl phlorol C 8 H 9 EtO 215-217 Sieel A., 170, 345 27, 378 Ethoxyethyl benzene C 6 H 4 .Et.OEt Liquid MMW> Auer B., 17, 669 46, 1002 Propyl methoxybenzene C 6 H 4 .Pra.OMe =1.2 u 207-209 c. Spica G. I., 8, 406 ; B., 36, 632 (757-7) 12, 295 ,, =1.4 214-215-5 c. Liquid 11 ii (750-18) i> 11 11 210-215 Paterno and Spica G. I., 7, 21 31, 708 C 6 H 4 .Pr.OMe =1.3 198-199 (751) .... Fileti G. I., 10, 279 38, 883 ii C 6 H 4 .Pr0.OMe =1.4 212-213 c. .... Paterno and Spica G. I., 6, 535 31, 593 (758) Anetholdihydride .... ., 220 .... Landolph B., 13, 145 38, 385 Ethyl xylyl oxide C 6 H 4 .Me.(CH 2 .OEt) =1.3 202 Liquid Radziszewski and B., 15, 1746 42, 1283 Wispek =1.4 203 Liquid 11 11 B., 15, 1745 Isobutyl phenol C 6 H 4 .OH.(CH 2 .CHMe 2 ) =1.? %S6-SS8 97-5-98 Liebermaun B., 14, 1843 42, 171 11 )) ii 231 99 Studer B., 14, 1474 40, 898 Cymylic alcohol C 6 H 4 .Pr.CH 2 OH =1.4 243 Liquid Kraut A., 92, 66 ii., 298; vii., 931 >. !> * ii 238-240 .... Meyer G. J. C., 1877 ,, 51 51 246-6 c. (760} .... Kraut A., 192, 224 Uihydrocunaic aldehyde (?) 190 ... Etard A. C. [5], 22, 218 40, 583 Ethoxyxylene Me.Me.OEt=1.4.5 u 194 .... Canzoneri G. I., 10, 516 40, 269 Isopropyl cresol Prf.Me.OH=1.3.? 231 1. 25 Kelbe A., 210, 40 42, 300 11 II u 227-5-229-5 Liquid Spica G.I.,12,543;B., 44,460 (758) 16, 792 ,, "= i.l.O 225-230 Mazzara G. I. [1882], 167 42, 838 ii 2377 (758) 1. f. m. G. I., 12, 505; B., 44,463 16, 793 Pr*.MeOH U 3 230-235 (734) Li on id G. I. [1882], 333 42, 1199 ii ,, ... .... .... 230-235 G. I. [1882], 167 42,838 (carvacrol) .... =1.4.5 ,, 232 Liquid .... .... i., 809 ., ., _ 231-232 1.-25 Kekule & Fleischer B., 6, 935 26, 1228 ; vii., 421 224 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Propyl cresol (carvacrol) Pr.Me.OH =1.4.5 CioH 14 O 232-232-5 ; .... Kekule & Fleischer B., 6, 1088 vii., 935; 27,65 236-5-237 c. ii i) 11 n 230 .... Kekul6 B., 2, 121 11 i ii 11 !> 232 .... Haller C. R., 94, 132 42, 737 II IT 230-231 s. 20 Beyer A. P. [3], 21, 283 46, 331 ii n >i ,, ,, 233 vii., 930 ,, ,, II II 233-235 Spica G. I., 10, 340 38, 889 i> 11 11 II II 237 3 to Jacobsen B., 11, 1060 34, 732 ii ii ,, 232-233 u.c.; +0-5 to 1 Jahus B., 15, 817 236-237 c. 1-5 to 2 A. P. [3], 15, 1 38, 112 (thymol) =1.4.6 w 209 Gerichten B., 11, 364 34, 570 ii 11 11 11 i> 227-8 (756-7) Paternd &Canzoneri G. I., 9, 455 38, 247 .1 i. 230 .... .... vii., 930 II 71 11 "" 11 ii 232 .... Schiff B., 13, 1407 38, 892 II II 11 "* 11 11 233-235 Liquid Febve C. R., 92, 1292 42, 524 ) 11 II 11 11 235 .... Ramsay .... 39, 64 )) ii 11 233 Paterno and Spica G. J. C., 1879 11 n 230 44 Lallemand A., 102, 119 v., 793 11 11 230 Doveri A., 64, 374 ,, i 11 222; 227 44 Stenhouse J., 9, 624 v., 793 I) ir )> n 11 44 Widmann B., 15, 166 42, 728 11 11 " 11 11 46 Keknl6 & Fleischer B., 6, 1087 27,66 J, 11 II ".' n n 48 Arppe A., 58, 42 v., 793 II J! 49-3 Schiff G. I., 14, 181; A., 46, 1089 223, 247 11 ii .... 51 Andresen J. p. [2], 23, 167 40, 590 11 II ii >i ,, 231 53 Haines v., 793 ,, 226 53 J., 9, 623 II 11 l " 11 11 244-7 .... Pisati and Paterno B.. 8, 71 (cymothymol) .... 245-8 .... 11 11 Pr.Me.OH=1.4. 1 228-234 Patern6 &Cauzoneri G. I., 11, 124 40, 595 230 1. f. m. vi., 303 _ j 232-235 Liquid Grjebe B., 5, 681 25, 1009 Methylmesitol Me 3 .OMe=1.3.5.6 200-203 Liquid Biedermann and B., 8, 60 28, 569 Ledoux Isodurenol Me 4 .OH=1.2.3.5.6 .... 108 Jacobsen B., 15, 1854 44, 52 Carvol 224-5-225 Kekule & Fleischer B., 6, 1088 27, 65 " 227 Gladstone 25, 9 225-230 Volckel J., 6, 512 11 . 228-229 Nietzki A. P. [3], iv., 31 7 27, 892 226'5 (754) Schiff B., 14, 1376 " 250 Liquid J. [1863], 548 i., 808 / C \ 11 Dehydrocamphor CsHl4 \|l/ n .... 160 Schiff B., 14, 1376 42, 528 Stearoptene . .... 48 ArppG A., 58, 41 iii., 1046 Mvristicol .. . .... .... C, n H, f O ? 212-218 Wright 26, 687 vii., 833 ^10 Ifi " 220 ; 224 Gladstone 25, 11 Oil from saffron M 208-210 Liquid Weiss J. p., 101, 65 vi., 1001 ? B 216-218 Liquid Faust and Homeyei B., 7, 1430 28, 371 ? phenol . u 233-235 C. R, 92, 1290 Reduction of anethol \v 220-224 .... Ladenburg As., 8, 87 vii., 72 Triethenylbutyric acid C 3 H 4 (C 2 H 3 ) 3 .COOH C 1U H 14 2 240-260 Geuther, Frohlich, A., 202, 310 38, 623 and Looss Ethylene phenylethyl oxide PhO.CH 2 .CH 2 .OEt B 230 Liquid Henry C. R, 96, 1233 44, 803 Phenylbutylene glycol CHPh(OH).C 2 H 4 .CH 2 (OH) 200 Liquid Burcker C. R.,94, 220; B. 42, 730 15, 731 ]>iethoxy benzene C 6 H 4 (OEt),=1.3 H 250 Liquid Barth and Senhofer A., 164, 109 vii., 434 ; 25, 1016 11 r, n ZS5-236 Liquid Earth B., 11, 1569 =1.4 n 72 N. H. G, 2, 560 COMPOUNDS CONTAINING THREE ELEMENTS. 225 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diethoxybenzene C 6 H 4 (OEt) 2 =1.4 C 10 H 14 O 3 124 .... A., 215, 145 Methoxypropoxybenzene .... C 6 H 4 .OMe.OPr=1.2 240-245 Liquid Cahours C. R, 84, 1195 32, 478 Tolylene glycol monethylate (CH 2 OEt)(CH 2 OH) =1.4 > 250-252 .... Grimaux C. R, 73, 1383 25, 136 j> 11 I) 252 Liquid 11 A. C. [4], 26, 331 25, 817 Isocuminic aldehyde C 10 H 12 0+H 2 Pr.OMe.OH= ? 1.2 > 240-241 80 Liquid Etard Pastrovich C. R, 87, 989 M. C., 4, 188 36, 321 44, 1005 Trimethylorcin Me 2 .(OMe) 2 = ? 1.3.5 Me.Pr.(OH) 2 =l. 4.5.6 i n 250 Liquid 139 Luynes and Lionet Andresen C. R, 65, 213 J. p. [2], 23, 178 vi., 885 40, 591 > 139-140 Kekul6 & Fleischer B., 6, 1090 27, 66 '* U ) 290 139-5 Cars tan jen J. p. [2], 3, 50 24, 351 1> u ? > 145 Lallemand A., 101, 121 ; 102, i> 121 Angelic anhydride (C 5 H 7 0) S C 10 H 14 O S 240-250 1. f. m. Chiozza A. C. [3], 39, 210 i., 293 Ethylic diallyl oxalate (C 3 H 5 ) 2 .C(OH).COOEt 207-209 Liquid Patern6 and Spica B., 9, 344 Diethylpyrogallol C 6 H 3 .OH.(OEt) 2 262 1. -10 Benedikt B., 9, 126 29, 916 J) .... 79 Hofmann B., 11, 799 34, 870 Methyl propylpyrogallol C 6 H 2 Pr.(OH) 2 .OMe 290 c. Liquid Pastrovich M. C., 4, 182 44, 1005 (picamar) Camphoric anhydride C 8 H 14 .CO.O.CO i ..i 213-215 Montgolfier A. C. [5], 14, 86 34, 898 )l ! 216-217 Anschiitz B., 10, 1881 34, 136 11 n ^ u a. 270 217 Malaguti A. C. [2], 64, 160 i., 731 )1 !> > 217 Wreden A., 163, 323 25, 896 >1 11 i 217 Maissen G. I., 10, 280 38, 893 11 11 CH 2 . CH 2 .CH.CO . 1 I >o CHMe.CH 2 .CMe.CO/ j .... 223 Armstrong & Tilden B., 12, 1756 35, 757 Pyrocamphretic acid .... C 10 H 14 O 4 206-210 b. 0. Schwanert A., 128, 77 iv., 757 2 .... 129 Ballo B., 14, 337 40, 415 Hydroxycamphoric anhydride C 8 H 13 (OH).CO.O.CO i i > .... 201 Wreden Z. C. [21 7, 97 24, 549 ii ii j .... 201 ji A., 163,333 25, 896 ii ii 11 .... 201 Kachler Z. C., 72, 264 vii., 236 Diacetyl mannitol anhydride C 6 H 8 4 (OAc) 2 ^ioHi 4 O 8 197-198(28) Liquid Fauconnier C.R.,95, 991;R, 44, 306 15, 3086 Dimethylic diacetyldextrotar- COOMe.(CH.OAc) 2 .COOMe M .... 103 Anschiitz B., 14, 2790 42, 831 tarate ii ii ii )) i .... 103 Pictet B., 2243 Diethylic acetylene tetracar- COOEt.(CH.COOH) 2 COOEt. .... 132-133 d. Guthzeit A., 214, 72 44,46 boxylate .... Oxidation product from oil of C 8 H 13 .CO.Me C 10 H 16 185-186 L -37 Grosser B., 14, 2504 42, 525 fruitof Coriandum sativum Methylic camphoronate .... 225-230 .... A., 123, 311 Camphor (from rosemary) .... 204 176 Bruylants J. P. [4], 29, 508 36, 726 11 .... )> 204 s. 175 174 Landolt Sigiura and IVluir B., 9, 915 30, 373 33, 295 (ordinary) .... )> 1) 204 175 Biot G. J. C., 1852 I., 727 11 ii .... > 205 Lallemann G. J. C., 1860 (from salviol) )? 174 Muir .... 37, 684 (from sage) .... 205 u.c. 174 u.c. n .... 37, 685 (inactive) .... > .... 172-173 162 Armstrong & Tildeu Oppeiiheim B., 5, 631 35,752 25,1010;vii.,233 (from Buch u leaves) .... i) ) 85 Fliickiger P.J.T.[3],iv.,689 27, 494 (from cubebs) .... 11 150 68 Blanchet and Sell A., 6, 294 Ii., 172 (inula) ,, (?) .... 64 Kallen B., 6, 1506 27, 353 (rose) Hydrocarbon (C 2 H 4 ) n (?) ,. O 280-300 35 .... v., 115 11 ii .... 11 187-193 33 1. 17 Baur AVreden D. P., 204, 253 B., 11, 989 25,937 36, 69 11 225-250 IVIylius B., 6, 1053 27, 80 205 Bruhl B., 9, 1375 31, 165 11 Vapour tension tables 11 11 v. Part iii. Laevocamphor .... n .... 175 .... B. S.,24,19; A.C. [5], 14, 29 2o 226 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Laevocamphor .... C 10 H 16 200-220 .... .... i., 729 Anisic camphor (anethol te- .... ) 190-193 Liquid Landolph C.R.,81, 97 ;B., 29, 246 ; 38, trahydride) 13, 145 835 See C 10 H 12 O 4 80 Stenhouae P. J. T. v., 1054 Ericinol M 240-242 Frohde J. F. P., 82, 186 ii., 500 Methyl camphrene C 9 H 13 MeO I) )> 225-230 Liquid Schwanert A., 123, 298 iii.,1003;vi.,390 Myristicol . .. .... See C ln H,.O 265-285 Gladstone 26, 972 ww >_/jg.m...j4 v )) 220 25, 11 vii., 833 212-218 26, 972 U 212-218 Wright 26, 550 vii., 833 J> 212-218 B., 6, 147 26, 687 Absinthol (from oil of worm- ... JJ JJ 217 .... Gladstone 25, 8 wood) 204 Leblanc Gin., 7 27, 324 200-201 c. Wright 200-205 27, 1 .... .... ... .... 195 Beil stein & Kupffer B., 6, 1183 27, 153 Anethenol C lfr H 16 .OH )) 213-5-214-5 Liquid Kobig A., 195, 104 36, 455 200 Liquid Kallen B., 9, 154 29, 917 Alban )1 ^ 140 J. [1852], 644 See (C 10 H 17 0). 230 d. B. J., 24, 588 Eucalyptol .... \ V lir^l7 / ) J n 216-218 Liquid Faust and Homeyer B., 7, 1430 175 A., 154, 372 Citronellol (Penang) .... j> ? 200 Gladstone 25,8 (Ceylon) .... 200 jj Uraone (CaH^OJ ? (?) 190-200 Z. C. [1866], 382 v., 970 Tanacetyl hydride (tansol) ... 195-196 Bruylants B.,1 1,451; J. Ph. 34, 158 [4], 26, 393 Poleyoil .** 182-185 .... Handw. d. Chem., iv., 685 6,615 Xyloretin . .. .... 165 v., 1061 From oil of wormwood .... )> M 200-201 c. Wright .... 27, 318 >i .... n 200-205 .... Leblanc A., 56, 357 citronella .... > 199-205 .... Gladatone 10,7 27, 319 Aldehyde, from oil of tansy .... 195 Liquid Bruylants B., 11, 449 34, 512 Oil from styrax C 10 H 18 0? 170-180 SL 10 Van t'Hoff B. S. [2], 25, 175 31, 478 Oil of mentha pulegium .... i) 182-185 .... A., 32, 286 Oil of pulegium micranthum .... ) 227 Butlerow J., 7, 595 Blue chamomile oil .... v ... 150-168 Kachler B., 4, 37 24, 259 ; vii., 278 .... ( ). 281-289 .... i> B., 4, 36 24, 260 ; vii., 278 .... .... .... 270-300 vii., 278 Blue galbanum oil .... .... > 289-290 .... Mossner A., 119, 263 24, 260; ii., 758; . vii., 278 .... > 281 .... Kachler B., 4, 39 From oil of wormwood .... (C 10 H 16 ) 2 270-300 .... .... A., 170, 292 Ethylic diallylacetate (CH 2 : CH.CH 2 ) 2 .CH.COOEt Ci H, 6 O, 195 Liquid Eeboul C. R, 84, 1233 ; 32, 594 B. S., 29, 228 Diallylmethylcarbinol acetate (CH 3 : CH.CH,,) 2 Me.COAc 177-3 c. Sorokin A., 185, 171 32, 299 Hydroxy camphor C 10 H 15 0(OH) " 248-249 Schrotter M. C., 2, 228 42,66 ,, .... ... )) 258-260 .... Kachler and Spitzer M. C., 3, 217 42, 865 .... 11 i) 258-260 ) 5> B., 15, 2336 44, 215 .... ... )) ji 265 (753-5) .... > M. G, 4, 643 44, 1008 ) i 154-155 Schiff B., 13, 1404 38, 892 ) > 137 Wheeler A., 146, 83; S.J. vi., 387 [2], 45, 48 > .... 59-61 .... A., 200, 358 Ethylic acetisobutylidene C 6 H 8 (C' 4 H S )0 3 CjoH 16 O 3 219-222 Liquid Claisen & Matthews A., 218, 170 46, 443 acetate i) ..* > 219-222 Liquid Matthews .... 43, 201 COMPOUNDS CONTAINING THREE ELEMENTS. 227 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylic diallyloxalate (CH 3 :CH.CH 2 ) 2 .C(OH). c ioH 16 O 3 213-6 Liquid Saytzeff B. 8. [2], 26,454; 31, 455; 88, COOEt A., 185, 183 882 >! 11 210 ) B., 9, 33 29, 697 )> ? ) )j 207-209 Paternd and Spica G. I., 6, 38 31,60 Diethylic allylmalonate (CH 2 : CH.CH 2 ).CH(COOEt) 2 Ci H 16 O 4 220 .... Conrad and Bischoff B., 13, 597 38, 628 > ,) > 219-221 .... A., 204, 168 T %%2-%23 c.; .... Perkin .... 45, 538 193-5-1 94-5 c. (330) tetramethylenedi- CH 2 :(CH 2 ) 2 :c(cooEt), 224 Liquid > B., 16, 1787 44, 1084 carboxylate tetrylenedicarboxy- C 4 H 6 .(COOEt) 3 )) 230 .... A., 208, 338 late dimethylfumarate COOEtCMe. ; CMe.COOEt 235-240 . .. Roser B., 15, 1319 . terpenylate c'H^OH^Me.COOH J) abt. 300 36-38 Hempel A., 180, 84; B., 8, 29, 922; 28, 357 763 Camphoric acid C 8 H 14 (COOH) 2 J) 60 .... .... vii., 235 ,, ,, .... J) 70 .... i., 731 Mesocamphoric acid (inactive) .... 1) .... 113 Wreden Z.C. [2], 7,419; 25, 146 ; 2S, A., 163, 327 895 ,, .... .... )} .... 120 Kachler A., 191, 146 34, 513 Camphoric acid .... n .... 174-176 Meyer B., 3, 117 vii., 235 CH 2 .CMe.COOH > .... 175-178 Ballo B., 14, 338 40, 416 CHj.CPr.COOH 15 ,J )> > .... 176 )> )i .... > 175-178 Fittig and Tollens A., 129, 273 .... j .... 180-7 Kachler G. J. C., 1879 ,> .... j 177-178 Schroeder - 1880 1) II (CH 2 ) 2 .CH.C 2 H 4 .COOH )j .... 186 Muii .... 37, 688 (CH 2 ),,.CH(COOH) i .... 187 Eiban C. E., 76, 1547 35, 757 11 JT '" " j> ! 187 )? C. E., 80, 1381 28, 1192 ,5 ) .... .... ) .... 197 > C. E., 76, 1547 35, 757 (Lsevorotary) .... )1 197-198 j C. E., 80, 1381 28, 1192 ,1 ,, CH 2 .CH 2 .CH.COOH J) .... 202-203 Armstrong and B., 12, 1756 36, 757 CHMe.CH 2 .CMe.COOH Tilden Choleeamphoric acid.... .... || .... n.f. 270 d. Latschinoff B., 12, 1519 38, 56 Diethylic acetosuccinate COOEt.CHAc.CH 2 .COOEt C 10 H 16 O 5 239-240 c. Perkin 45, 517 (330) j H H 254-356 Liquid Conrad A., 188, 219 34, 137 )> ) 260-263 .... n B. 29, 368 Triethylic formyltricarboxy- CH(COOEt) 3 ^10^16^6 254-260 Liquid B., 12, 1236 36, 918 late 51 j 11 250-255 .... B., 12, 752 " l) 200 (140) 29 )i B., 14, 618 !! !> ) I) 253 29 Conrad & Guthzeit A., 214, 31 44,45 >! J5 ) 257 (760) ; .... Bischoff B., 15, 1109 42, 1188 144 (90) Diethylicacetomalate COOEt.CH(OAc).CH 2 . M 258=265-7 Liquid Wislicenus A., 129, 183 vi., 799 COOEt c. (729) I) )> 258 .... Anschiitz B., 14, 2790 42,831 Butenylglyceroltriacetin > 153-155 u. c. Liquid ? M. C., 1, 835 (27); 261-8 (740-2) Glycidic acetate Polymer 51 258-261 .... J. p. [2], 20, 191 Diacetyl glucose C 6 H 10 (OAc) 2 4 ^ioH 16 8 .... b. 100 Schutzenberger C. E., 68, 264 vi., 1045 Atraric acid 140-141 Paternd G. I. [1882], 231 ; >1 B., 15, 2242 Hartin See C 10 H 16 (C, H 17 0). 260 210 Schrotter P. A., 54, 45 ill., 14 2 G 2 228 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diallylpropylcarbinol (CH 2 : CH.CH 2 ) 2 .Pra.COH C 10 H 18 O 194 .... A., 193,362; J.p [2], 26, 111 Diallylisopropylcarbinol (CH 2 : CH.CHjJj.Prf.COH 182-185 Liquid Riobinine & Say tzeff B. S. [2], 31, 199 36, 613 Divalerylene hydrate 2C 5 H 8 .H 2 175-177 Liquid Reboul C. R., 64, 419 vi., 1124 Anhydride of valeric alde- .... j) 190 Ribeau B. S., 13, 24 ; vi., 1123 ; 25, hyde C. R., 75, 98 810 > )> .... u 195 Liquid Borodin B., 5, 481 vii., 37, 1196 ; 26, 58 .... 195 Pott B. S., 18, 244 Anethol hexhydride .... 198 18-19 Landolph B.,13, 146;C.R., 29, 705 ; 38, 82, 226 385 Cajeputol From oil of melaleuca erici- M 173 Gladstone 25, 9 folia From oil of melaleuca linari- 173 folia M ,, .... ..t. ... From oil of eucalyptus j) 171-176 .... .... )J oleoza From oil of cajeputol 174 )> 175-178 Schmidl 14, 63 27, 319 176-179 Wright B., 7, 598 27, 619 Cajeputene hydrate C 10 H 16 .H 2 O ?) j 175 Liquid Schmidl 14, 63 i., 712 Salviol abt. 200 Muir 37, 679 j) 200-201 37, 685 204-205 Liquid Moriya 37, 77 .... jj 206-3 c. Liquid j Atkinson& Yoshida .... 41, 51 Terebenthene hydrate .... 210-214 Liquid R6nard C. R., 90, 531 38, 479 Terpene hydrate ( ) From French turpentine 217-7-220-7 .... Flawitzsky B., 12, 2355 38, 403 (766-3) j, .... .... C 10 H 16 .H 2 O 200-220 .... Deville A, 71, 348 v., 923 205-215 Tilden B., 12, 848 33, 248 *" MM i> H 205-215 > B., 12, 1132 35, 287 Geraniol 232-233 1. -15 Jacobsen A., 157, 234 ; J. 24, 261 ; vii., [1879], 941 552 Borneol (+) 212 197-5-198 Kachler A., 197, 86 36, 1039 <+) I *) 212 197-5 Pelouze A, 37, i., 626 ( ) - 210 35 A., 101, 95; 105, 67 (-) .... ! 220 .... A. C. [5], 14, 21 Camphol (inactive) .... 11 209-210 198-199 Armstrong & Tilden B., 12, 1755 35, 752 From sage camphor 199-200 Muir 37, 686 Ngai borneol .... 1 198 Haller C. R., 98, 578 46, 755 camphor ..* )> 204 Plowman P. J. T.[3],iv.,712 27, 582 Oil from styrax Or C 10 H,,0 )) 170-180 s. 10 Vant'Hoff B. S. [2], 25, 175 31, 478 Ketone (?) 189-191 Liquid Pawlaw A, 187, 134 32, 733 Butyrylchloride on zinc me- .... >! 189-191 Liquid V B. S. [2], 27, 263 32, 311 thide 1 .... b 190 .... Kekule A., 162, 77 vii., 1196 (Propylmethyl ketone) 2 H 2 O i 190-192 .... Pawloff B., 8, 767 29, 895 From oil of osmitopsia asteris- .... j> 178-188 .... Gorup-Besanez J., 7, 596 coides From essence of lemon .... > a. 200 .... Tilden P. J. T. [3], 9, 654 36, 386 From oil of citronella .... )i 210-225 Wright 27, 318 coriander .... >i 150 .... Kawalier J., 5, 624 valerian.... .... i) 205-215 Bruylants B., 11, 454 From likari Canadi .... > 198 (755) C. R., 92, 998 ; 94, 733 worinseed oil .... j> 173-174 Kraut & Erdmann A, 87, 312 .... .... 172-174 .... Kraut &Wahlfross A., 89, 358 1, >> "" ' .... >? 174-175 Grsebe B., 5, 680 ,, ,, .... .... .... .1 173-174 .... Faust and Horneyer B., 7, 1427 From oil of hops .... j 210 J. [1853], 516: [1854], 654 COMPOUNDS CONTAINING THREE ELEMENTS. 229 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Alcohol from oil of tansy ... C 10 H 18 203-205 .... Bruylants B., 11, 452 34, 512 j 11 11 .... )) 205-210 11 J. Ph. [4], 26, 393 34, 158 From menthol ) 204-205 .... J J reduction of valeral ... (C^HwO). 250-290 Liquid Borodin Z. C. P. [1864], 353 v., 973 Isoamylic angelate .... CioHiaQi 200-201 .... A., 195, 100 tiglate .... si 204-205 .... A., 195, 101 Allylacetone pinacone (C(OH)Me.C 3 H 5 ) 2 5J 254-262 Liquid Kablukoff B., 13, 1843 40, 146 Pr0.CH 2 .CO.CO.CH 2 .Pr0 270-280 pd. Liquid Bruhl B., 12, 319 36, 520 5J 210-220 (80-100) Decacrylic acid .... Vi .... 86 Z. C. [1868], 383 Amenylvaleric acid .... C 4 H 8 (C 5 H 9 ).COOH 1) 241-5 c. .... Borodin J. [1870], 680 !> " ij > 235-245 .... Hell and Schoop B., 12, 193 ,, 11 268-270 Liquid Geuther, Frohlich, A., 202, 288 38, 623 and Looss abt. 250 Liquid Hirzel J., 1854 or 1855 v., 1048 Campholic acid .... ) 250 80 Delalande A. C. [3], 1, 120 1., 726 11 )J .... 95 Kachler A., 162, 259 ; B., vii., 232 ; 5, 166 26, 496 11 11 .... .... 98 Montgolfier A. C. [5], 14, 99 34,900 11 11 .... JJ 253-255 u. c 105-106 11 n >! From amylaldehyde .... 187-191 Goss and Hell B., 8, 372 Ethylic diethylacetoaceticacic CEtjAaCOOEt Cu>H 13 O 3 200-215 Geuther J.Z.,6; J.p.[2], vii., 488 ; 3, 431 24,817 11 11 1) M 210-212 Frankland &, Duppa J., 18, 306 i) i) " I 208-211 Wislicenus B., 7, 686 27, 884 )> ii ij 318 .... i) A., 186, 191 32, 433 isobutylacetoacetate CHMe 2 .CH 2 .CHAc.COOEt > 217-218 Liquid Rohn A., 190, 306 34,486 11 i n 200-210 Mixter B., 7, 501 Methylic hydroxyethenyl- CH 2 : C(OH).CH(C 5 H n ). 250 Pcetsch A., 218, 56 44,730 amylacetate COOMe Oxoctenolacetic ether )> 200-202 .... J. B. [1882], 199 Valeric anhydride .... (C 6 H 9 0) 2 i 215 Chiozza A., 84, 107 v., 979 Trimethacetic anhydride .... (CMe 3 .CO) 2 O 190 Butlerow B., 7, 728 27, 1084 ii ii ji j 1. 20 11 A., 173, 374 28, 250 ? .... jj 210-212 Liquid Wanklyn unpublished vi., 17 Hexylene diacetate CH 2 OAc.(CH 2 ) 4 .CH 2 OAc C W H 18 4 207 .... vi., 94 ii ii 11 215-220 Liquid Wurtz A. C. [4], 3, 180 vi., 699 Diallyl diacetate CH 2 OAc.(CHMe) 2 .CH 2 .OAc. 11 225-230 Liquid 11 A. C. [4], 3, 162 vi., 94 Ethylene dibutyrate C 2 H 4 (O.C 4 H 7 0) 2 yi 239-241 Liquid n A. C. [3], 55, 433 i,696 Ethylic butyroxybutyrate .... 215 .... A., 142, 373 Diisobutylio oxalate Pr/3CH 2 .CO.CO.CH 2 Pr0 11 224-226 .... Cahours B. S., 21, 358 ; 27,349 C. R., 77, 1403 Diisopropylic succinate COOPr3.(CH 2 ) 2 .COOPr0 228 (761) Liquid Silva C.R., 69,416; A., vi., 966 154, 255 Diethylic ethylmethylmalo- CMeEt(COOEt), II 207-208 .... Conrad and Bischoff B., 13, 596 ; A., 38, 627 nate 204, 146 Diethylic propylmalonate .... CHPr(COOEt) 2 11 221-224 u.c.; Perkin .... 45, 514 193-5-194-5c. (330) isopropylmalonate CHPrP(COOEt) 2 11 216-5-217-5 .... 11 .... u u. c. (760) ; 188-188-5 c. (330) I, >! )> 213-214 Liquid Conrad and Bischoff B., 13, 596 ; A., 38, 627 204, 146 ethylsuccinate COOH.CHEt.CH 2 .OOOH n 222-225 Huggenberg A., 192, 151 34, 782 diinethylsucciuate COOEt.C 2 H 2 Me. i .COOEt 11 230-235 .... M. C., 2, 546 adipate C.H^COOEtX 11 a. 230 Liquid Malaguti A., 56, 306 i., 58 11 i) 1 11 245 Arppe Z. C. [1865], 302 ; vi., 58 J. [1864], 377 230 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dimethylic suberate C 6 H 12 (COOMe) 2 Ci H, 8 O 4 260 .... Laurent A. C. [2], 66, 162 Ethylic oxytetrolate C 4 H 3 0(OEt) 3 225 Liquid Demarjay B. S. [2], 33, 575 40, 255 homoitaconate C 4 H 8 (COOEt) 2 M 230 Liquid Markownikoff and A., 208, 333 40, 1127 Krestownikoff Heptylmalonic acid C 7 H 15 .CH.(COOH) 2 5) .... 97-98 Venable B., 13, 1651 40, 82 Sebacic acid (ipomoeic) COOH.(CH 2 ) 8 .COOH )1 104 Mayer A., 83, 143 ill., 314 ; v., 214 >> ii jj )j 5 127 Carlet J., 6, 429 v., 213 127 Mayer A., 83, 143 27, 729 126-127 ; Neison and Bayne 27, 730 ?J )i 127-138 Acid .... 184-194 A., 195, 122 Diethylic ethoxysuccinate .... COOEt.CHOEt.CH 2 .COOEt )) CioHi 8 O s a, 225 p. d. Purdie 39,348 (760); 195-200 (250) >> 128-131 (15) Andreoni B., 13, 1394 dilactate .... 235 .... .... A. C. [3], 63, 112 Triethylic ethoxyacetyl- CH 2 (OEt).CO.CH(OEt). abt. 245 .... Courad B., 11, 59 34,403 ethoxyacetate COOEt ? .... j) 251 .... Z. C. [1867], 708 Triethylene diacetate (O.C 2 H 4 .OAc) 2 Ci H 18 O 6 290 .... .... .... ii., 568 i) i) )> n abt. 300 Wurtz J., 16, 489 ; A. C. [3], 69, 336 Dipropylic dextrotartrate .... COOPr.(CH.OH) 2 .COOPra n 181 (23); Liquid Anschiitz and B., 13, 1177 38, 876 303 (760) Pictet Diisopropylic dextrotartrate COOPr3(CHOH) 2 .COOPrf 275 (760) ; Liquid Anschiitz B., 14, 2790 ; 15, 42,831 165 (23) 2242 Anisoic acid abt. 120 Limpricht & Hitter A., 97, 364 1., 304 Diethylic mucate .... C 4 H 8 O 4 (COOEt) 2 jj ^ioH 19 O 8 150 Malaguti A. C. [2], 63, 86 iii., 1059 j, > .... 158 Limpricht A., 165, 254 vii., 827 ; 26, 622 Diethylic isosaccharate C^O^OEt), .... 73 Tiemann B., 17, 249 46, 725 Diacetodulcite C 6 H 8 (OH) 4 (OAc) 2 .... 176 Bouchardat A. C. [4], 27, 147 ; vii., 441 ; 25, C. E., 74, 665 400 Isocaprinic aldehyde .... C 10 H 20 1690. J. [1870], 680 Octylmethylketone .... '. *.'. Me.CO(CH 2 .) 7 Me 214-215 s. f. m. Jourdan A., 200, 106 38, 314 j) .... .... ')) >1 211 (760); 3-5 Kratft B., 15, 1695 42, 1271 142 (100) j) Me.CO.CH 2 .CHM:e(C 6 H 11 ) > 196-198 .... Venable B., 13, 1651 Isopropylhexylketone Prf.CO.C 6 H 13 200-210 .... .... J. R, 7, 334 Dipropylallylcarbinol (CH 2 : CH.CH 2 ).Pra2.COH A 192 (769) A. and P. Saytzeff B., 11, 1939 36, 136 Diisopropylallylcarbinol (CH 2 : CH.CH 2 ).PrP 2 .COH }] 169-171 .... .... J. p. [2], 23, 22 Diamylene oxide .... 51 170-180 Bauer E. C. p. [1863], 3 vi., 122 j) Pr0.(CH 2 ) 3 .CHMe.CH : CH 2 75 180-190 Schneider A., 157, 185 vii., 64 Menthol (menthylic alcohol, C 10 H 19 .OH 225 Gladstone 25, 9 peppermint camphor) " M M 225 .... > > )1 25 Dumas A., 6, 252 iii., 880 ? n 27 Blanchet and Sell A., 6, 293 >i ) 11 34 Walter A., 32, 288 ) 36-5 Gmelin Handbuch,ii.,408 j> u 210 36 Oppenheim A., 120, 351 iii., 880 ; 15, 24 )i ) )? 210-212 37-2-39 Moriya 39,77 >f ) n .... 39 Moss 29, 1 ?' 1 j) n 212 c. 42 Beckett and Wright .... ) )> )) )> 212 c. 4** Atkinson & Yoshida 41, 49 > (artificial) n .... 42-2 i 41, 51 ? Ketone ? )) 190-195 .... J. E., 9, 75; 10, 229 Octylic acetate C 8 H 17 .OAc C 10 H 20 O 2 163-180 De Clermont J., 21, 449 ; Z.C. [1868], 492 COMPOUNDS CONTAINING THREE ELEMENTS. 231 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Octylic acetate Me.CH(OAc).C 6 H la C^HaA, abt. 176 Liquid De Clennont C. R, 66, 1211 vi., 880 ,, C 8 H 1? .OAc 190 Liquid Bouis C. R., 38, 937 i., 24 191-192 Dachauer J., 11, 305 ,, Me.CH(OAc).C 6 H I8 193 .... Bouis J., 8, 526 vi., 880 ,, ,, .... .... C 8 H 17 .OAc Tl 190-195 Pelouze and Cahours J., 16, 529 Et.CH(OAc).C 6 H n 198-202 Schorlemmer A, 152, 152 vi., 879 Me.CH(OAc).(CH 2 ) 3 Pr0 ,, 200-205 Liquid J., 22, 368 ,, ,, .... .... C 7 H ls .CH 2 .OAc 200-212 Liquid Zincke A, 152, 2 vi., 697 CHMe 2 .(CH 2 ) 4 .CH 2 .OAc 206-208 vi., 878 CH 3 .(CH 3 ) 6 .CH 2 .OAc 211-25-212 c. .... Perkin 45, 496 (250) Hexylic butyrate CH 3 .CH 2 .CH 2 .COOC 6 H 13 ,, 201-206 A., 163, 198 Amylic valerate C 4 H 9 .COOC 5 H U 182-184 .... C. R., 94, 1652 187-188 Liquid Kopp A., 96 v., 980 CH 3 .(CH 2 ) 3 .COO.(CH 2 ) 4 .CH 3 190 Liquid Pierre and Puchot J. Ph. [4], 13, 369 24, 902 Isoamylic Pr0.CH 2 .COO(CH 2 ) 2 Pr0 190 .... i) 11 C.R., 76, 1332 26, 1017 ; vii., 62 (inactive) .... 190-3 (748) Balbiano G. I., 6, 229 31, 293 C 4 H 9 .COOC 6 H U 196 Balard A, 52, 311 v., 980 Isopropylic isoheptylate CH 3 . (CH 2 ) 3 .CHMe.COOPrP 177 .... Hecht A., 209, 325 42, 41 Propylic CH 3 (CH 2 ) 3 .CHMe.COOPr a 191-192 .... A., 209, 324 (754-5) Ethylic caprylate C 7 H 15 .COOEt 214 Liquid Fehling A., 53, 405 1., 747 } 11 CH 3 .(CH 2 ) 6 .COOEt 206-208 s.47or 47 ? Cahours & Demarc.ay C. R., 89, 331 36, 1037 204-206 .... Zincke A, 152, 12 ; J., 22, 373 207-208 Liquid Renesse A, 171, 381 27, 1155 (763-2) 207-208 Liquid (753-1) C 6 H, 3 .CH 2 .COOEt 196 .... Lundahl B., 16, 789 i) CHPr 2 .COOEt 183 Liquid Burton A. C. J., 3, 385 42,600 ,, CHMe 2 (CH 2 ) 2 .CHMe.COOEt 175 .... Carleton- Williams .... 35, 129 Methylic nonylate CH,.(CH 2 ) 7 .COOMe ; or 11 213-214 c. Liquid Franchimont and B., 5,20; A., 164, vii., 898 ; 25, CHMe 2 (CH 2 ) 5 .COOMe (756-8) Zincke 338 301 Capric acid C 4 H 8 (C 5 H n ).COOH 11 241-5 L 87 Borodin Z. C., 6, 416 vii., 250 .... tertiary 11 250-253 .... Menschutkin A. C. [5], 23, 14 40, 886 ,, .... .... 27-46 Reichardt A. P. [3], 10, 339 32, 518 .... .... .... s. 30 iso- 11 268-270 p.d. 30 Grimm A., 157, 264 24, 360; vii., 249 .... ?! .... 30 Gorgey A., 66, 295 11 27-2 Rowney A., 79, 236 264 29-5 Fischer A, 118, 312 .... CH 3 .(CH 2 ) 8 COOH 200 (100) 31 -3-31-4 Krafft B., 15, 1696, 1708 42, 1272 1 CMe 2 : CH.O.CH(OEt).Pr0 223 (756-8) CEconimides B. S. [2], 36, 210 42, 32 Terpin hydrate C 10 H 16 .2Aq sb. 150 103 Deville A., 71, 349 v., 923 .... 250 118 .... J. [1855], 643 .... b. 100 1 ? Oil of ash leaves 175 .... Gintl and Reinitzer M. C., 3, 762 44, 219 Ethylic hydroxycaprylate ,., Pr0 2 C(OH).COOEt C 10 H 20 O 3 202-204 c. Liquid Markownikoff Z. C, 6, 516 vii., 885 11 11 C 6 H 13 .CH(OH).COOEt > 229-230(715) Erlenmeyer & Sigel A., 177, 105 28, 1011 Myristicin .... a. 100 .... iv., 145 Matezite .... .... .... p TT r\ 181 Girard B. S., 21, 220 ; 27, 169 C. R, 77, 995 Decyl alcohol ... C 9 H 19 .CH 2 OH C^H^O 155-157 Anitow B., 5, 479 vii., 18; 26, -IS abt. 200 Lemoine B. S., 41, 161 46, 1107 iso- * 203-3 Borodin Z. C. P. [1864], v., 973 353 from diisoamyl 202-203 Grimshaw B., 10, 1602 211-213 yy 225-23. r > Z. C. [18701 404 232 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. CH 3 .(CH 2 ) 8 .CH 2 OH OHO 119 (16) 7 Kraflt B., 16, 1714 44, 1076 Diamylene hydrate ^10^22^ )> \ / 163 Wurtz J., 16, 516 Dianxyl oxide . C 5 H u .O.CHMe.CHMe 2 160-165 Liquid A. C. f4l, 3, 137 vi., 113 aH,,.O.CH 2 .C 4 H a j) 176 jj Williamson *" L JJ J G. J. C., 1852 ii., 537 a 11 '-a* ' J 4-"-"-S) Vv- Xiii.O.Oc.-tlii JT 175-183 Rieckher J., 1, 698 i., 205 (i 80 -) s-^yJ-^lj. WV|*AJ| >5 170-175 Wurtz J., 9, 564 176 G. J. C., 1856 Diisoamyl oxide )J J? J) 172-5-173 c. .... )) Perkin 45, 474 Octyl ethyl oxide C 8 H l7 .O.Et H 177 ? 1 )) 182-184 Liquid Moslinger B., 9, 998 30, 394 Propyl methyl pinacone CMePr(OH).CMePr(OH) C 10 H 22 O 3 220-225 .... Friedel J. [1869], 513 24, 386 V H ) ) 225-230 gentle heat 11 A. C. [4], 16, 366 vii., 1022 1 1 31 )> 225-230 .... Grimm A., 157, 249 24, 386 Diethyl pinacone CEt 2 (OH).CEt 2 (OH) H .... 27-28 Sehramm B., 16, 1584 44, 1080 Diisobutylacetal CH 3 .CH(O.CH 2 PrP) 2 11 168-170 Liquid Gerard C. R., 91, 629 40,35 Cinchocerotic acid .... J' .... 72 Helms A. P. [3], 21, 279 46, 332 Tripropylic orthoformate .... CH(OPi") s Ci H 22 O 3 192-196 Pinner B., 16, 1646 44, 1089 >i ) > 196-198 Deutsch B., 12, 117 36, 453 Ethylideneoxypropyl alco- C 4 H e (OPr) 2 i 184 Laatsch A., 218, 13 44, 788 holate Diamylene glycol .... > a. 200 .... .... J. [1861], 662 Ethyl isoamylin C,H i (OEt)(OC 6 H I1 )(OH) >j 238-240 Liquid Reboul As., 1,237; J., 13 ii., 884 465 Terpin hydrate Ci H 16 .3H 2 O .... slightly b. 100 List G.J.C.,1847,1848 v., 923 ,, ,, " i) .... 103 Nietzki A. P. [3], iv., 317 27, 892 (identical) )> .... 117-121 Bouchardt C. R., 89, 361 36, 1039 Diisoprene hydrate n .... 117-121 >! j Caoutchene j .... 117-121 I) V ) Cajputene )> 120 Schmidl 14,63 i., 712 Diethyl glycolacetal CH(OEt) 2 .CH(OEt) 2 C 10 H 22 O 4 abt. 180 .... Pinner B., 5, 151 25, 407 ; vii., 2 Pentethylenic glycol .... C 10 H 32 6 281 (25) Lourenco A. C. [3], 67, 280 ; J., 13, 443 Physetoleic acid C 10 H 302 .... 30 Hofstadter A., 91, 177 iv., 634 a-Naphthoic aldehyde C 10 H r COH C U H 8 abt. 280 Liquid Battershall Z. C. [2], 7, 292 24, 1057 ; vii., 839 ft- 1 .... 59-5 i Z. C. [2], 7, 673 vii., 839 ; 25, 699 8-Naphthol aldehyde C 10 H 6 .OH.COH C U H 8 O 3 76 Kaufmann B., 15, 804 42, 1068 ft- )> )> n .... 77 Rousseau A.C. [5], 28, 145; 46, 180 C. R., 95, 39 a-Naphthoic acid C 10 H ? .COOH 139-140 Carstanjen& Schertel J. p. [2], 4, 49 24, ,920 a- J i physical 142-143 Merz and Weith B., 10, 748 32, 603 isomer a- ,j J) H .... 156 Cars tan jen& Schertel J. p. [2], 4, 49 24, 920 a ' 1> 11 ) n 160 Hermann B., 1, 40 ; A., 142, vi., 851 121 a- > > 160 Merz Z. C. [2], 4, 34 "- n physical 160 Merz and Weith B., 10, 748 32, 603 isomer a- M 161 Weith B., 6, 967 a- J H 161 Liebermann A., 183, 225 31, 608 a- !, n > 161 Palm B., 9, 499 30, 200 0- 5! u n 161 Watson Smith .... 32, 563 3- (isonaphthoic) ? i* 181 Liebermann A., 183, 225 31, 608 ft- ) i 181 Palm B., 9, 499 30, 206 ft' >> !) 11 .... 181 Watson Smith 32, 563 ft- JT i a. 300 183=184 c. Merz & Miihlhauser Z. C. [2], 5, 71 vi., 851 ft- >t !> fy )i .... 182 Battershall Z. C. [2], 7, 673 25, 699 ft- 1 " !1 i> .... 182 Vieth A., 180, 305 30,86 ft' IJ 11 w i .... 182 Ciamician B., 11, 272 34, 439 COMPOUNDS CONTAINING THREE ELEMENTS. 233 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Hydroxynaphthoic acid C 10 H 6 .OH.COOH=,3/3 C,,H 8 3 150 d. Kaufmann B., 15, 806 42, 1068 a- ^ 1 ., 185-186 Schaffer A., 152, 291 vi., 852 a- V )J 185-186 Cleve B. S. [2], 26, 241 31, 208 a- 185-186 Stumpf A., 188, 1 34,75 a- n 186-188 Eller A., 152, 277 vi., 852 7- v u ^ =a P t 186-187 Stumpf A., 188, 8 34,74 ;, =<& 210-211 A., 188, 11 )> 11 212-213 Battershall A., 168, 125 vii., 838; 26, 1138 a- =aa ; 234-237 H A., 168, 121 )I 15 a- ,, ., i. 234-237 Stumpf A., 188, 4 34,74 a P- )> ,, =/3; .... 245-247 n A., 188, 6 Acetoxycoumarin C 6 H 3 (OAc).CH I CH.CO.O C n H 8 4 140 Tiemann and Lewy B., 10, 2216 34,424 1) 140 Tiemann & Eeimer B., 12, 995 36, 721 a-Phthalylpropionic acid C,H 4 : (CO) 2 : CH.CH 2 .COOH 245-248 Gabriel & Michael B., 11, 1013 34, 735 =1.2 a-Dioxyquinone C U H 6 (OH) 2 :0 2 .... a. 360 Thorner B., 11, 534 34, 575 Acetyl daphnetin C 9 H 6 .OAc.O 3 C..HA 129-130 Stiinkel B., 12, 112 36, 469 Tetramethylic prehnitate .... C 6 H 2 (COOMe) 4 =1.2.3.5 C n H 8 8 104-108 Baeyer .... vi., 811 Acetyl polyporic acid C 9 H 6 Ac0 2 (C..HA). .... abt. 205 Stahlschmidt A., 187, 177 32, 621 a-Naphthyl-methyl oxide .... C 10 H 7 .O.Me C n H 10 O 258 Liquid Stiidel B., 14, 899 ; A., 40, 724 ; 44, 207, 42 585 a- ,, 5J 263-265 Liquid Hantzsch B., 13, 1347 38, 813 a- 265-266 I. 10 Marchetti G. I., 9, 544 38, 261 /3- .... } , 374 70 (3- .... JJ 72 Stiidel B., 14, 899 ; A., 40, 724; 44, 207, 43 585 Ethylic phenylpropiolate .... Ph.CiC.COOEt C U H 10 O 2 260-270 1.0 Perkin 45, 174 Cinnamylacrylic acid Ph.(CH:CH)j.COOH J) 165-166 J. [1877], 791 31, 404 Butyric coumarin ,CH : CHEt C 6 H/ / =1.2 \O.CO " 296-297 p. d. 70-71 " A., 147, 233; 150, 84 21,53; vi.,500 C 6 H 4 : (co) 2 : c : (CH 3 ) 2 =i.2 299 d. 96 Gabriel & MJchael B., 11, 1683 30, 439 36, 246 Benzoylcrotonic acid Bz.CMe : CH.COOH CuH.oO, 113 Pechmann B., 15, 891 42, 1074 Benzoyltrimethylenecarb- CHj-CHj-CBz-COOH .... 148 Perkin B., 16, 2136 46, 64 oxylic acid 1 ' Toluylacrylic acid C 6 H 4 Me.CO.CH : CH.COOH 138 Pechmann B., 15, 888 42, 1074 Methyl-/3-methylumbelli- C 6 H 3 (OMe)CMe : CH.CO.O a .... 159 Pechmann & Duis- B., 16, 2119 46,66 ferone berg a-$-Diinethylumbelliferone C 6 H 3 (OH).CMe : CMe.CO.O 256 > Tl 1) 46,67 Phenylparaconic acid CH 2 .CO.OCHPh.CH.COOH CnH.O, 100 Fittig B., 14, 1825 42, 190 5) 109 Jayne A., 216, 108 44,473 +iH 2 99 a Aeetylcoumaric acid C 6 H 4 .OAc.(CH : CH.COOH) 146 Tiemann & Herzfeld B., 10, 284 31, 709 =1.2 j u =1.3 151 Tiemann & Ludwig B., 15, 2048 44, 189 >1 I! = 1.4 195 Tiemann & Herzfeld B., 10, 65 32, 893 Acetylbenzoicacetic anhy- C 6 H 4 .Ac(CO.OAc)=1.2 .... 70-5-71 Gabriel B., 14, 920 40, 733 dride Benzhydrylpropiocarbonic anhydride CH.C 2 H 4 .COOH xx>.o " Softens 135; melts 140 Gabriel & Michael B., 11, 1681 36, 246 Hydrindonaphthalene dicar- boxylic acid C 6 H/ 2 \C(COOH) 2 =1.2 X CH/ .... 199 Baeyer and Perkin B., 17, 122 46, 753 Diacetylacetosalicylol C H 4 .OAc.CH(OAc) 2 =1.2 .... 104-105 Barbier C. R., 90, 37 38, 318 Methylene a-homocaffeic acid CH 2 :O 2 :C 6 H 3 .CH:CMe.COOH 192-194 Lorenz B., 13, 759 40, 49 Ethyl cesculetin C 6 H 2 (OH)(OEt).C 2 H 2 .CO.O H 143 Will B.. 16, 2106 46,67 2 H 234 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dimethyl oesculetin C 6 H 2 (OMe) 2 .C 2 H,.CO.O CnHi O 4 .... 144 Tiemann and Will B., 15, 2076 44, 199 i " i Ethyl daphnetin C 9 H 6 O 3 .OEt 11 .... 155 Will and Jung B., 17, 1083 46, 1142 /3-Benzoylisosuccinio acid .... CH 2 Bz.CH(COOH) 2 CnH 10 O a 114 Bischoff B., 16, 1045 44, 912 Phenylcarboxylsuccinic acid .... CnH 10 O 6 191 Spiegel B., 14, 873 Ethylic polyporate C 8 H 6 .COOEt (C n H u 2 ). .... 134 Stahlschmidt A., 187, 177 32, 621 Allylacetophenone Ph.CO.(CH 2 ),,CH : CH 2 C U H 12 235-238 (710) Liquid Perkin .... 45, 187 ,, )) )) 235-238 .... Baeyer and Perkin B., 16, 2132 46, 64 Beuzoyltetramethylene CHBz.CH,.CH,.CH n 258-260 Liquid Perkin B., 16, 1792 44, 1084 i "i Ethylic cinnamate C 6 H 5 .CH:CH.COOEt C U H 12 O 2 262 Herzog A. P. [2], 17, 72 i., 986 ,, JJ V) 263 Liquid Kopp A., 60, 269 34, 981 ,, , .... )) J> 262 .... 11 C. R, 21, 1376 1, , ) J) 265 Basse B., 9, 833 30, 641 ,, ,, -- > n J> 265 .... Plantamour A., 30, 344 11 ,, ?) 260 .... Marchand A., 32, 269 11 11 .... 1 266 c. (760) Kopp J. p. Ph. [3], 11, 72 i., 986 ,, j) I) 271 Liquid Anschiitz and B., 11, 1220 34, 981 Kinnicutt 11 I) j) J> 271 Weger A., 221, 61 46, 11 Phenylangelic acid 81 Fittig and Bieber A., 153, 364 ; Z. C. 31, 393 [1869], 332 n 11 82 .... A., 193, 319 11 11 >" C 6 H 6 .C 3 H 4 .CH 2 .COOH IJ 104 Perkin J. [1877], 789 31, 393 11 ji C 6 H 6 .C 4 H 6 .COOH )) .... 105-106 G. H., 651 Methylic propenylbenzoate .... C 6 H 4 .C 3 H 6 .COOMe=1.4 ?J 254 53 Meyer and Eosicki B., 11, 1792 36, 157 isopropenylbenzoate J .... 83 Meyer B., 12, 1076 36, 795 Salicylol diacetate C 6 H 4 .OH.CH(OAc) 2 =1.2 )J 104-105 Barbier B. S. [2], 33, 52 38, 40!) Acid from Ci 2 H 13 BrO 4 .... )) 112 Fittig B., 14, 1825 ; A., 42, 190 216, 123 Thymotide 187 Naquet B. S., 4, 92 v., 796 Propylic phenylglyoxylate .... Ph.CO.COOPr. 1} CuH 13 O 3 174 (60) Claisen B., 12, 629 36, 648 Ethylic beiizoylacetate CH 2 Bz.COOEt R 265-270 s. d. 1.0 Baeyer and Perkin B., 16, 2129 46,63 11 11 11 )> 365-370 (760) I. Perkin .... 45, 174 230-235(200) Ethylbenzoylacetic acid CHEtBz.COOH .... 111-115 11 45, 180 11 11 JJ .... 112-115 Baeyer and Perkin B., 16, 2130 46, 63 Aeetylphenylpropionic acid.... CH 2 Ac.CHPh.COOH .... 126 Weltner B, 17, 72 46, 746 Ethylic hydroxy cinnamate .... C 6 H 6 .C 2 H(OH).COOEt I 279-5 c. Liquid .... vi., 470 ! 11 J) Jl 273d. .... .... A., 147, 104 Butyryl salicylaldehyde C 6 H 4 .COH(O.C 4 H 7 O)=1.2 260-270 Liquid Perkin A., 150, 82 21, 472; vi., 1010 Methylic allylsalicylate C 6 H 4 .OC 3 H 6 .COOMe= 1 . 2 )) 245 Liquid Scichlone G. I., 12, 449 ;B., 44, 336 16, 796 a-methoxyphenyl- C 6 H 4 .OMe.(C 2 H 2 .COOMe) V 275-S76 Perkin 39, 411 acrylate = 1.2 11 - 11 11 n n 278-280 Liquid 11 31, 418 P- 11 i> )) 293 Liquid 11 .... 39,411 11 0- 11 =1.4 303 89 11 .... 39, 439 Ethylic hydrocoumarilate .... C c H 4 135 Perkin .... 39, 414 3- 11 11 i) 11 > 131-5-133 A., 216, 145 (3-Methoxyphenylcrotonic C 6 H 4 .OMe.(C 3 H 4 .COOH)=l.i j .... 104-105 Perkin J. [1877], 793 31, 416 acid 0- 11 11 11 11 i) .... 107 11 .... 39, 430 "- n 11 11 n i) 118 n .... 39, 430, 449 11 11 =1. l.)4 J. [1877], 792 31, 412 Butyrocoumaric acid C 6 H,.(C 4 H 7 0).COOH=1.2 174 p. d. 11 A., 150, 84 21, 472 ; vi., 501 COMPOUNDS CONTAINING THREE ELEMENTS. 235 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. -Watts'Dict. & J. Gh. Soc. C H 175 Paternd G. I. [1882], 231 ; 42, 1082 ^11-^-12^3 B., 15, 2241 E thy licacetof urf uralacetate . ... C 6 H 8 (C 5 H 4 0)0 3 C n H 12 O 4 188 (30) 62 Claisen & Matthews A., 218, 170 46, 443 i> J> ) 188-189 62-62-5 Matthews .... 43, 204 (29-32) Benzylmethyhnalonic acid ... C 6 H 6 .CH 2 .CHMe(COOH) 2 j 135 Conrad & Bischoff A., 204, 178 ; B., 38, 628 13, 595 Benzylidene diacetate C 6 H 6 .CH(OAc) 2 190-240 36 Wicke A., 102, 368 i., 578 >j )1 45-46 Perkin 20, 590 vi., 328 II II J) ?! 44-45 Hiibner B. S. [2], 8, 459 vi., 24, 328 Ethylio benzoylglycollate .... CH 2 BzO.COOEt 3 286-4-288-4 Andrieff J., 18, 344 i) )J )l 277-279 c. .... .... A., 80, 32; 133,284 Acetoxybenzylic acetate C 6 H 4 .OAc(CH 2 .O Ac) =1.3 3 290 8. 18 Velden J. p. [2], 15, 170 S2, 339 Diacetyl orcinol Me.(OAc) 2 =1.3.5 (?) 1) .... 25 De Luynes Z. C. [2], 4, 703 vi., 885 ii ii >i i> J 280-284 (704) .... Rasinski J. p. [2], 26, 61 42, 1289 Diacetyltoluquinol Me.(OAc) 2 = ? J) 52 Nietzki B., 11, 1279 ; A., 34, 868; 44, 467 215, 160 Acetoxyetlioxysalicyl alde- COH.OAc.OEt=1.2.5 285 p. d. 69 Hantzsch J. p. [2], 22, 468 40, 167 (?) hyde II )J ) 69 Tiemann & Miiller B., 14, 1995 42, 53 Methylic hesperitate (C 2 H,j.COOMe).OH.OMe J .... 79 Tiemann and Will B., 14, 967 40, 740 =1.3.4 Dimethylcaffeie acid (Cocoon). (OMe) 2 = 1 . 3. 4 )> 180 n ii B., 14, 960 ) .... )1 J 180-181 Tiemann and Nagai B., 11, 653 34,580 Dimethylumbellic acid = 1.2.4 N .... 184 Tiemann and Will B., 15, 2080 44, 200 11 ii J5 ) i) 138 Will B., 16, 2116 46,68 Methoxyhydroxymethylcin- (CMe : CH.COOH).OMe.OH H .... 140 d. Pechmann and B., 16, 2119 46,67 namic acid = ? Duisberg Methoxyhydroxymethylcin- (CH : CMe.COOH).OMe.OH )> .... 167-168 Tiemann and Kraaz B., 15, 2064 44,201 namic acid (homoferulic) =1.3.4 Ethylic ethyleneprotocate- C 6 H 3 .(COOEt).O.C 2 H 4 .O ) .... 27-28 Fittig & Macalpine A., 168, 104 26, 1144 i i chuate =1.3.4 Methylene o-homohydro- CH 2 : 2 : C 6 H 3 (CH 2 .CHMe. )j .... 77 Lorenz B., 13, 760 40, 49 caffeic acid COOH) Eugetic acid .... COOH.OH.OMe.C 3 H 5 124 Schench A., 125, 14 ii., 968 =1.2.3.5 n Acetyl alorcinic acid C 6 H i! Me 2 .OAc.COOH ?) MM Begins 125 d. Weselsky B., 5, 168; A., vii., 54 167, 72 Ethylic ? -ate n H n ? 147 Salkowski B., 8, 1461 29, 599 Salicylol and acetic anhydride v ^ll- LI -14 v/ 4 * C 7 H 6 2 +C 4 H 6 3 CnH.A I 103-104 Perkin A., 146, 371 20, 586 ; vi., 1008 Acet-n-homovanillic acid (CH 2 .COOH).OMe.OAc )) .... 140 Tiemann and Nagai B., 10, 202 32, 339 =1.3.4 or 1.4.3 Methylic opianate COOMe.(OMe) 2 .COH I) d. 63 83-85 Wegscheider M. C., 3, 358 42, 1207 =1.2.3.6 isopianate =1.3.4.5 .... 98-99 Tiemann and B., 10, 397 32,487 Mendelsohn Dimethylic hydroxyuvitate.... (COOMe) 2 .Me.OH=1.3.5.2 ) .... 79 Jacobsen A., 195, 289 36, 531 i) )> .... 79 ii B., 13, 2051 40, 172 II >I 1) ? )J .... 79 ii A., 206, 167 40, 431 1) 1! =1.3.4.6 .... 105 ; 108 Oppenheim & Pfaff B., 8, 885 28, 1262 11 II =1.3.5.6 J> 128 Jacobsen B., 13, 2051 40, 172 >! II ii n .-.. IK ii A., 206, 192 40, 431 1) !> ii n .... 129-130 Bottinger B., 13, 2345 40, 278 C' 3 H 10 O.(COOH)., 150-200 Babo & Hirechbruini A., 84, 19 v., 308 Primula camphor si )> a. 200 49 A., 185, 222 Orcyldigylycollic acid C 6 H 3 Me(O.CH,.COOH) 2 C,,H U 0. 216-217 Saarbach J. p. [2], 21, 62 38, 393 a- Methylic hemipinate COOH.COOMe.(OMe) 2 ii 121-122 Wegscheider M. 0., 3, 362 42, 1207 = 1.2.3.4 +H 2 i> ii .... 96-98 ii ) } - =2.1.3.4 n 137-138 n M. C., 3, 366 )J 9. u 2 236 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylic isohemipinate COOH.COOMe.(OMe) 2 =? C,,H 12 O 6 .... 167 u. c. .... B., 10, 398 Ethylic carbocomenate C 4 H 2 O(COOEt)(COO.COOEt) C U H 12 O 7 87 u. c. Drechseland Moller J. p. [2], 17, 164 34, 784 Diethylic meconate .... C 5 H0 2 (OH)(COOEt) 2 1) ... 111-5 Mennel J. p., 26, 453 44, 656 Diethylmeconic acid )1 .... abt. 110 How A., 83, 359 iii., 861 ,, .... 11 110 Drechsel and Moller J. p. [2], 17, 163 34,784 Phenylisobutyl ketone Ph.CO.CH 2 .CHMe 2 C U H 14 215-225 Funaro G. I. [1881], 274 40, 1032 11 )i 225-226 .... Popoff A., 161, 285 ; B., vii., 712; 25, 5, 39 409 Butenyl methoxybenzene .... OMe.(CH :CH.CH 2 Me)=1.2 11 232-234 1. f. m. Perkin B., 11, 515 33, 214 j )) = 1.4 11 17 35, 146 > i 11 51 11 842-345 17 J. [1877], 383 32, 671 ji 11 J) )i 242-245 j) 33, 215 Isobutenyl methoxybenzene OMe.(CH : CMe 2 )=1.4 11 236-237 8-5-9 35, 146 Benzylic butyrate CH,.(CH 2 ) 2 .COO.CH 2 Ph CnH 14 O 2 238-240 .... .... A., 193, 317 isobutyrate CHMe 2 .COOCH 2 Ph 11 228 .... Hodgkinson A., 201, 168 33, 496 Phenylpropylic acetate C 6 H 5 .CH 2 .CH 2 .CH 2 .OAc 11 244-245 1. 18 Riigheimer A., 172, 128 27, 894 Butylic benzoate C 6 H 5 .COO(CH 2 ) 3 CH 3 i) 247-32 c. Linuemann A., 161, 192 ; A., 25, 396 ; vii., 162, 39 203 Propylic phenylacetate C 6 H 5 .CH 2 .COO.Pr 11 238 c. Liquid Hodgkinson 37, 483 Ethylic hydrocinnamate C 8 H 5 .CH 2 .CH 2 .COOEt 11 244-8 (738-2) Bruhl A., 200, 192 38, 296 >* " 11 11 248-1 Weger A., 221, 61 46, 11 j 11 T1 247-249 c. .... Erlenmeyer J., 19, 367 vi., 469 >> 11 11 245-250 Liquid Merz and Weith B., 10, 758 32, 617 ) 1) 11 245-250 Liquid Sesemann I. D. Zurich 28, 74 Pheuylethylpropionic acid .... Ph.CH 2 .CHEt.COOH 11 272 1. f. m. Baeyer and Jackson B., 13, 118 38, 406 Phenylvaleric acid .... Ph.CH 2 .CH 3 .CH 2 .CH. ! . )1 .... 58-59 ;) B., 13, 122 38, 407 COOH Tolyl isobutyric acid (?) Me.(CH 2 .CHMe.COOH) )} .... 91-92 Kelbe B., 16, 620 44, 796 =1.3 Isobutylbenzoic acid C 6 H 4 .C 4 H 9 .COOH=1.4 )) .... 161 Pahl B., 17, 1237 46, 1010 Acetyl propylphenol C 6 H 4 Pr a .OAc=1.4 ?I 242-7-244 c. Liquid Spica B., 12, 295 ; G. I., 36, 632 (760-65) 8,406 isopropylphenol C 6 H 4 .Pr0.0Ac=1.4 1J 244-244-5 .... Paterno and Spica G. I., 6, 535 ; B., 31, 593 (756-27) 10, 84 Mesityl acetate Me 2 .(CH 2 OAc)=1.3.5 11 228-231 (745) Liquid Wispek B., 16, 1577 44, 1095 ,, .... 11 242 i. v. Liquid Eobinet C. R., 96,500;B., 44, 577 16, 965 Ethylic xylate C 6 H 3 .Me 2 .COOEt= ? M 233 Liquid Hirzel and Beilstein B. S., 1, 345 v., 1062 mesitylenate = 1.3.5 11 241 s. 0. Fittig A., 147, 46 vi., 823 Homocuminic acid .... 11 .... 52 Eossi C.R.,52,403; As., iii., 163 ; 38, 1, 139 ; G. I., 9, 163 400 Cyraene carboxylic acid C 6 H 3 Me.Pr.COOH=1.4. ? 51 63 Paterno' and Spica G. I., 9, 400 38, 163 Methyl engenol C 6 H 3 .(OMe) 2 .(CH : CHMe) 11 237-239 Grsebe & Borgmann A., 158, 282 24, 705 ,, .... " 11 237-239 Church B., 7, 1551 28, 116 ,, i) )i 1) 244-245 Matsmoto B., 11, 123 )> )i 255 u. c. Church .... 28, 115 =262-5 c. Thyiuotic aldehyde Pr.Me.OH.CFO=1.3.4.6 11 133 Kobek B., 16, 2096 46, 56 Ethylic phenoxypropionate.... CH 3 .CH(OPh).COOEt C n H 14 O 3 243-244 Liquid Saarbach J. p. [2], 21, 152 38, 393 ,, methylmandelate .... Ph.CH(OMe).COOEt )! 248 .... Meyer and Boner B., 14, 2391 42, 195 Phenylpropylglycollic acid .... CPh(OH).Pr.COOH 11 .... 158 Ploschl B., 14, 1316 42, 515 Phenylhydroxypivalic acid .... CPh(OH).(CMe 2 COOH) 11 134 Fittig and Jayne A., 216, 115 44, 471 Ethyltropic acid Ph.CMe(OEt).COOH 11 59-5-62 Ladenburg and B., 13, 2042 ; 14, 40, 171 Rugheimer 446 a-Benzyl-/3-oxybutyric acid CH 3 .CH(OH).CH(CH 2 .C 6 H S ). 11 152-155 .... Ehrlich B., ; A., 187, 29, 369 ; 32, COOH 26 439 Ethylic ethoxy benzoate C 6 H 4 .OEt.COOEt=1.2 11 25K-S60 (732) A., 197, 18 )) " i) )1 251 Folaing B., 17, 486 46, 897 i) 1) 160-165, sic; 1.-18 Giittig B., 9, 1475 31, 313 (260-265?) ii =1.3 11 263 .... Heintz A., 153, 332 COMPOUNDS CONTAINING THREE ELEMENTS. .237 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylic ethoxybenzoate C 6 H 4 .OEt.COOEt=1.4 ^nH 14 O 3 273-276 Liquid Ladenburgand Fitz A., 141, 253 vi., 899 Methylic isopropoxybenzoate C 6 H 4 .OPACOOMe=1.2 11 250 Liquid Kraut, Schroder, A., 150, 8 vi., 1006 and Prinzhorn Ethylic hydrocoumarate OH.[(CH. ! ) 2 .COOEt]=1.2 273d. 34 Zwenger As., 5, 115 vi., 716 Ethylhydrocoumaric acid .... OEt.[(CH 2 ) 2 .COOH]=1.2 11 80-80-5 .... A., 216, 154 Ethylic phloretate .... OH. (CHMe.COOEt) =1.4 n a. 265 Liquid Hlasiwetz A., 102, 151 iv., 491 Methylic methylphloretate .... OMe.(CHMe.COOMe)=1.4 11 278 38 Korner & Corbetta B., 7, 1733 28, 458 Ethylphloretic acid OEt.(CHMe.COOH)=1.4 H .... 106-5 11 n B., 7, 1734 11 Methoxyphenylbutyric acid OMe.(C 3 H 6 .COOH)=1.2 11 55-56 Perkin 39, 433 Cumophenolglycollic acid .... Pra.(O.CH 2 .COOH)=1.4 51 .... 81 Spica G. I., 10, 246 38, 883 Propylphenylglycollic acid .... Pr.(CHOH.COOH)=1.4 11 .... 158 Raab B., 8, 1149 29, 398 Diethoxybenzaldehyde COH.(OEt) 2 =1.2.5 11 280-285 60 Hantzsch B., 13, 2419; J. p. 29, 167 [2], 22, 469 ii .... =1.2.6 1 71-72 Tiemann and Lewy B., 10, 2215 34, 424 Ethylic hydroxymesitylenate COOEt.Me 2 .OH=1.3.5.4 11 113 Jacobsen B., 12, 608 36, 643 Thymotic acid (carvacrolic).... Pr. Me.OH.COOH= ? 11 118-120 .... C. R, 94, 132 ,, = t M 120 fColbe & Lautemann A., 115, 205 v., 796 11 II 51 =1.4.5. 1 120 Kekule& Fleischer B., 6, 1089 27, 66 ; vii., 935 II II 11 =1.4.2.3 11 123 Kobek B., 16, 2096 46, 56 II II 1' =1.4.5. ? 11 126-127 Spica G. I., 10, 340 38, 889 11 11 11 "" =1.4.5.6 11 .... 133-134 Kekul6& Fleischer B.,6, 1089 ;C.E., 27, 66 ; 94, 132 vii., 935 11 1} 11 = r 11 .... 149-150 Paterno and Spica B., 12, 384 ,. il =1.4.2.5 11 .... 157 Kobek B., 16, 2096 46,56 Photosantonin 11 305 64-65 Sentini B. S. iv., 627 Ethylic dimethoxybenzoate.... COOEt(OMe)j=1.3.4 CnH, 4 O 4 .... 42 Will A., 37, 198 11 11 n 11 11 295-296 43-U Tiemann &Matsmoto B., 9, 942 30, 525 Diethoxybenzoic acid COOH.(OEt) 2 =1.2.3 n .... 87-88 Earth and Senhofer A., 164, 121 25, 1016 ; or =1.3.6 vii., 433 11 11 =1.2.4 M 99 Tiemann and Lewy B., 10, 2215 34, 424 11 ii =1.3.4 i 149 Koelle B., 4, 634; A., 24, 829 ; 159, 245 vii., 432 Dimethoxyphenylpropionic (CH 2 .CH 2 .COOH)(OMe) 2 11 .... 96-97 Tiemann and Nagai B., 11, 653 34, 580 acid =1.3.4 i) 11 =1.2.4 >i .... 97 Tiemann and Will B., 14, 966 n ii 11 11 .... 205 Will B., 16, 2106 46,68 Hydrohomoferulic acid (CH 2 .CHMe.COOH).OMe. )i .... 114-115 Tiemann and Kraaz B., 15, 2070 44, 198 OH=1.3.4 Ethylic everninate Me.OH.OMe.COOH= ? ji .... 56 Stenhouse A., 68, 90 ii., 612 Ethylic ?-ate C U H I2 4 ? u ... 147 Salkowski B., 8, 1459 29, 599 Isoamylphenyl oxide PkCXCH^CHj-CHMe,, C U H 16 224-225 Liquid Cahours A., 78, 227 ;C. R, iv., 391 32,61 Butylphenyl ketone C 4 H 9 .CO.C G H 5 11 225-226 .... Popoff A., 162, 151 Ethoxyisopropylbenzene C 6 H 4 .OEt.Pr0=1.2 n 213 u. c. Liquid Spica G. I., 9, 433 38, 167 11 = 1.4 .. 220 c. (757) Liquid 11 1) 11 51 11 244-245 J. [1876], 455 ; [1879], 760 Methoxybutylbenzene C 9 H 4 .OMe.C 4 H 9 = ? ii 215'5 u. c. Liquid Studer B., 14,2187 42, 176 Aiuyl phenol . .. , ... C 6 H 4 .C 5 H U .OH= ? 248-250 92-93 Liebmann B., 14, 1844 ; B., 42, 171 11 15, 151 247-251 Calm B., 15, 1646 42, 1284 M^uthoxycymene . .. Jl 11 Me.Pr^OMe 1 1 3 11 205 LlQHltl Enffelhardt and Z. C. [2], 5, 43 vi., 1090 11 Latschinoff 11 n ) :i 2167 .... Paterno and Pisati G. I. [1875], 13 ; 28, 638 B., 8, 71 11 11 i 11 abt. 226 (740) Liquid Mazzara G. I., 12, 333; B., 42, 1199 16, 242 11 1 ? 9 ,, 1. . 4 11 216-8 Paterno and Pisati G. I. [1875], 13 , 28, 638 B., 8, 71 Methoxyisocymene Me.Prf.OMe=l.?. 3 11 215-220 Liquid Mazzara B., 16, 793; G. I., 44, 463 12, 505 238 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. From dragon's blood C U H 16 214-215 Jotsch M. C., 1, 613 42, 210 225-228 Randolph C. R, 86, 601 34, 576 allylalcohol C 2 H 3 (C 9 H 13 )O 2 C n H lc 2 195-205 .... Tollens Z. C. [2], 7, 249 25, 998 Benzylidene diethylate C 6 H 5 .CH(OEt) 2 222 c. Liquid Wicke A., 102, 364 i., 578 Phenyl isopropylethylene CHPh(OH).CHPr0.(OH) H .... 81-82 Fossek M. C., 5, 119 46, 833 glycol Diethylorcinol Me(OEt) 2 =1.3.5 (?) 240-250 De Luynes & Lionet C. R, 65, 213 vi., 885 Thymotic alcohol Me.Pr.OH.CH 2 OH=1.4.3.6 120-130 Kobek B., 16, 2096 46,56 Camphocarboxylic acid C 10 H 14 .OH.COOH C n H 16 3 118-119 Baubigny Z. C. [2], 4, 482 vi., 386 and 647 J> j .... 118-119 Santos-e-Silva B., 6, 1092 27, 70 J) 7'J "** ) 1 23-124 u.c. iachler and Spitzer B., 13, 1412 ; 38, 892 ; M. C., 3, 205 42, 865 Propyl dimethylpyrogallol .... Pr.(OMe) 2 .OH 285 Liquid Hofmann B., 8, 67 ; 11, 331 28, 569 Phoronic anhydride .... CMe.CO C U H 16 O 4 138 Pinner B., 14, 1079 40, 797 /\ \ CH 2 O \/ ' \ CMe.CH 2 .CMe 2 .CO Ethylic camphoronate CsH^-COOEt C,iH 16 5 302 Liquid Kachler A., 159, 281 vii., 238 ; 24, 1049 Pyrocholesteric acid 108 Tappeiner A., 194, 221 36, 388 Acrolein and acetyloxide .... C 3 H 4 0.2C 4 H 6 3 C n H 16 O 7 180 Liquid Geuther J. vi., 24 Trimethylic acetylcitrate .... C 3 H 4 .OAc.(COOMe) 3 C n H l6 O s 280-282 Hanaus B., 9, 1750 31, 456 Ethylic diacetomesoxalate .... C(OAc) 2 (COOEt) 2 145 p. d. Petrieff B., 11, 414 34, 490 C H O 78 Liquid Fremy A., 15, 284 41, 167 97 Liquid Schiel A., 115, 96 i., 1087 Diethenylethylisopropylacetic C 4 H 5 .CPrEt.COOH C U H 1S 2 270-280 Geuther, Frohlich, A., 202, 324 38, 623 acid and Looss Undecolic acid C 10 H 17 .COOH 59-5 Krafft B., 11, 1414 34,853 Borneol formate MM 225-230 Bruylants B., 11, 455 97 Liquid Schiel A., 115, 96 41, 168 Ethylic acetisoamylideue C 6 H 9 .CHAc.COOEt CnH 18 O 3 237-241 Liquid Claisen & Matthew A., 218, 170 46, 443 acetate n n n 237-241 Liquid Matthews 43, 202 Rangiformic acid 104-106 Paternd G. I. [1882], 231 , 42, 1084 B., 15, 2242 Methylpropylallylene glycol- Pr(OAc).CH.C(OAc) : CHMe C,,H 18 O 4 .... 68-5 Morris .... 41, 178 diacetate or Pr.CH: C(OAc).CH(OAc)M Ethylic acetylmesitonate .. CMe 2 : CH.CMe(OAc).COOE 205-207 .... Pinner B., 15, 579 42, 941 Methylcamphoric acid .... .... abt. 68 Low A. C., 38, 483 i., 732 Diethylic -methylacetosuc- COOEt.CHAc.CHMe.COOE CnH 18 O a 238 .... Bischoff A., 206, 313 40, 412 cinate 8- 7) ,, 257-259 .... .... A., 188, 227 ; 192 142 a 262-263 .... A., 216, 31 ,, rt ~ ;> J> COOEt.C,H 2 AcMe.COOEt ,, 254-256 A., 206, 329; 216 . 35 a- ij v) 263 Liquid Kressner A., 192, 135 34, 783 acetoglutarate .. COOEt.CHAc.CH 2 .CH 2 . 271-272 .... Wislicenus and A., 192, 128 COOEt Limpach Phoronic acid CMe.COOH S\ .... 184 d. Pinner B., 14, 1078 40, 797 CH 2 v CMe.CH 2 .CMe 2 .COOH Diethylic methylic propenyl CH(COOEt) 2 .CHMe.COOM C,,H 18 6 267 Liquid Bischoff A., 214, 53 44,45 tricarboxylate )) 268 .... Bischoff & Eninier; B., 15, 1107 42, 1191 Triethylic ethenyltricarboxy COOEt.CH 2 .CH(COOEt)., 278 Liquid Bischoff A., 214, 38 44, 45 late i 7) 275-280 ; Liquid Conrad B., 12, 752 36, 707 172 (90) COMPOUNDS CONTAINING THREE ELEMENTS. 230 Name. Constitution, Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diethylic succinolactate EtO.C 3 H 4 O.O.C 4 H 4 2 .OEt CnH 18 O 6 280 Liquid Wurtz and Friedel J., 14, 378 III., 462 Triethylic desoxalate C 2 H 3 O 2 (COOEt) 3 C U H 18 9 85 Lowig J. [1861], 605 v., 41 11 11 .... )J 85 Klein J. p. [2], 20, 146 38,37 Methyl borneol .... CnH. 20 194-5 c. (733) Baubigny Z. C. [1868], 299 Undecylenic acid CnH^Oa 295u.c.(760) 24-5 Becker B., 11, 1412 34, 853 p. d ; 200 (low pres- sure) i> i> 1) 198-200(90) 24-5 Krafft B., 10, 2035 34, 292 Acid from petroleum .... J) 258-261 (741) Hell and Meidinger B., 7, 1217 28, 248 ii ii 250-260 D n B., 10, 451 32, 432 Isoamylic acetoethylacetate.... CHAcEt.COOC 5 H u C n H 29 3 233-236 Liquid Conrad A., 186, 231 32,435 Heptylic acetoacetate CH 2 Ac.COOC ; H 15 250-260 Venable B., 13, 1649 40, 82 Diethylic diethylmalonate .... CEt2(COOEt) 2 C n H 20 4 223 Liquid Conrad A., 204, 138 ; B., 36,707 12, 749 11 )) n 230-230-5 c. .... Perkin .... 45, 513 (760) ; 195- 198 c. (330) isobutylmalonate CHMe 2 .CH 2 .CH(COOEt) 2 si 225 .... Conrad and Bischoff B., 13, 600 38, 628 11 11 IJ 225 .... Guthzeit A., 209, 236 42, 39 pimelate C s H 1(r (COOEt) 5 i 185 Liquid Marsh A., 104, 125 iv., 646 ii 11 > j) 236-240 Liquid Kachler A., 169, 172 27, 155 Dimethylic azeleate C 7 H 14 .(COOMe)., )i 260 d. .... Z. C. [1865], 298 Methylic hydrogensebate .... C 8 H 16 .COOH.COOMe j .... abt. 60 Neison 29, 317 Brassylic acid C 9 H 18 .(COOH) 2 .... 108-5 Haussknecht A., 143, 48 vi., 367 Glycerol dibutyrate C 3 H 5 .(OH)(O.C 4 H.O) 2 C n H 20 O 5 320 b. 40 Berthelot A. C. [3], 41, 264 i., 696 Acetonaloxyisobutyric acid.... CMe 2 (O.CMe 2 .COOH) 2 CnH^O, 192-200 .... Willgerodt B., 15, 2311 Diacetodiethylpropylphycite C 3 H 4 (OEt) 2 (OAc) 2 abt. 210 Carius A., 134, 71 v., 895 Euodic aldehyde C 10 H 21 .COH CnHaO 213 s. 7 Williams P. T. [1858], 1, 99 v., 133 Diamyl ketone (caprone) CO(C 5 H,,) 2 11 165 Liquid Brazier & Gossleth A., 75, 257 i., 744 ii ) J> 11 220-221 .... Schmidt B., 5, 602 vil., 251 ; 26, 892 ii ii ii )) 11 222 s. 12 Limpricht A., 108, 185 i., 698 ii ji ii CO(CH 2 .CH 2 .CH 2 .CH 2 Me) 2 11 226-3 (740) 14-6 Lieben & Janecek A., 187, 134 32, 880 Nonylmethyl ketone Me.CO.C 9 H n( 11 223-224 15-16 Gorup-Besanez and Z. C.,13,290;B., vU., 808; 24, 387 Grimm 3,518; A., 157, 275 ii 11 u 11 224-225 .... i) i 11 11 11 11 V 11 225-226 15 Giesecke Z. C., 6, 429 u 11 11 11 Me.CO.(CH 2 ) 9 .CH 3 n 161 (100) 13 Krafft B., 15, 1709 42, 1272 From oil of wine .... 11 218-219 J. p. [2], 23, 457 Nonylic acetate CHj.COOC^,,, CnH 22 O 2 207-213 Z. C. [1870], 404 ii 11 J> 11 208-212 Liquid Pelouze & Cahours J. [1863], 529 iv., 134 Amylic caproate C 5 H n .COO.G,H n n 211 Liquid Brazier & Gossleth J., 3, 400 i., 744 Isoamylic caproate PA (CHj^COO. (CH 2 ) 2 .PrS ,, 215-220 .... A., 142, 18 Ethylic uonylate CHMe 2 . (CH 2 ) 3 .CHMe.COOEt 11 213-215 c. Liquid Kullhem A., 173, 328 vii.,898;28,354 n 11 C 8 H,-.COOEt 11 216-218 Liquid Cahours J., 3, 401 iv., 371 (pelargonate) JI V 224 .... Delffs J., 7, 26 11 11 " n 11 226-228 c. Perkin 46, 503 11 11 CH 3 .(CH 2 ) 7 .COOEt or 227-228 (757) Liquid Franchimout and A., 164, 338 ; B., vii.,898; 25,301 Pr/s.(CH 2 ) 5 .COOEt Zincke 5, 19 Methylic caprate (iso) G,H 19 .COOMe 11 223-224 Liquid Grimm A., 157, 264 24,300; vii., 249 Uudecylic acid CH 3 .(CH 2 ) 9 .COOH 11 212-5 (100) 28 Krafft B., 15, 1687 42, 1272 11 11 ii II 213 (100) 28-5 11 B., 12, 1664 38, 34 11 ii 11 1; 228 (160) 28-5 11 B., 11, 2219 36, 307 (umbellulk-)... .... II 270-275 u. c. 21-23 Stillmann & O'Noill A. C. J., 4, 206 42, 1186 p. d. (760) ; 208-211 (100) 11 11 (Me 3 C)., : ( 'Mo.COOH II 226 c. 66-70 Butlerow B.,12,1482; J. E., 38, 230 11, 203 240 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diamylic carbonate (CHMej.CHj.CHjkCO, C U H^O. 224-225 Liquid Medlock J., 2, 430 i., 800 ; 1, 368 n JJ "' 1> jj 226 .... Bruce J., 5, 605 6, 132 H )> 228-7 Liquid Eose A., 205, 232 40, 252 Ethylie ethylisomyloxylate .... CE^CjHuXOH^COOEt jj %21r-%25 Liquid Fraukland & Duppa A., 142, 6; P. T. iv., 276 [1866], 309 >J 222-226 .... Z. C. [1866], 491 Isoamylic diethoxalate CEtpH.COO.CsH,, j> 225 Liquid Frankland & Duppa P. T. [1866], 1309; iv., 274 J., 18, 380; A., 142, 15 Hendecatyl alcohol ..., Me.CH(OH).C 9 H 19 C U H 24 228-229 Liquid Giesecke Z. C., 6, 431 vii., 808 1 .... 245-255 .... .... Z. C. [1870], 404 Tetraethylpropylphycite C 3 H 4 (OEt) 4 CnH 24 O 4 150-160 Liquid Carius A., 134, 71 v., 895 From combustion of ether .... .... CnH.Oi, (?) .... 51 Legler A., 217, 385 44, 860 V>lO-tj-j(_)c 137 Hesse iv., 641 Naphthoic anhydride C 10 H 16 .CO.O.CO=/3 1 /3 2 ; 12^^ 4 6 C 12 H 6 3 266 Cleve B. S. [2], 26, 241 31, 208 n ) 266 Behr and Van Dorp A, 172, 267 27, 1168 Diphenylene oxide C 6 H 4 .O.C 6 H 4 =1.2 ; 1.2 C 12 H 8 278-288 Solid Grsebe B., 7, 397, 1629 27,798; 28,455 5) 275 80-81 Hofmeister A., 159, 211 jj JJ J .... 80 Lesimple A., 138, 375 vii., 436 ) 80 Niederhausern B., 15, 1121 jj jj )> > )) .... 80-81 Goldschmidt and M. C., 3, 133 42, 617 Herzig ., ,, ) )> 280-283 u. c. 80-81 Goldschmidt and W. A., 83, 7 40, 824 Schidt j i> =1.4; 1.4 J> 99 Goldschmidt and M. C., 3, 133 42,617 Herzig ? .... C 12 H 8 3 .... 209-211 Gabriel B., 14, 927 40, 733 a-Naphthylglyoxylic acid ... C, H 7 .CO.COOH C 12 H 8 3 113-5 Boessneck B., 16, 640 44, 808 41 E. Fischer A, 211, 229 42, 500 Naphthalene dicarboxylic CwH^OOOH), C 12 H 8 4 n. f. 240 Darmstadter and B., 2, 358; J. vi., 852 ; vii., acid Wichelhaus [1869], 477 428 .... 266 Behr and Van Dorp B., 6, 60 26,632; vii., 842 <* i> jj .... m. a. 300 d. Ebert and Merz B., 9, 607 30, 409 ft- m. a. 300 d. j> jj )) n J> =^1^J J d.lOOforming .... Behr and Van Doip A, 172, 265 27, 1168 anhydride C 10 HO t a. 320 A., 100, 180; ^ J 12 a a Z. C. [1866], 602 Diphenyl oxide (C e H 5 ) 2 CjgHjyO 27-28 Bichter J. p. [2], 28, 273 46, 326 ,, M 246 28 Hoffmeister B., 3, 747; A, vii., 941 159, 200 i 248 28 j Z. C. [2], 7, 24 24, 124 )> )1 249 .... Gladstone & Tribe .... 41,6 > j, )> )1 252-254 28 Merz and Weith B., 14, 188 ,, )1 253 .... Niederhausern B., 15, 1124 Hydroxydiphenyl C 6 H 5 .C 6 H 4 .OH=1. ? ) .... Solid Osten B., 7, 173 27, 581 . =1.4 151-152 .... A., 209, 348 =1.4 (?) JJ 305-308 164-165 Latschinoff B., 6, 194 ; J. R, 26, 750 5, 52 ? 1) 294-296 Liquid Schwarz B., 14, 1524 Dihydroxydiphenyl (di- (C e H 4 .OH) 2 =1.2 ; 1.2 Cj 2 H 10 O 2 .... 98 Hodgkinson and B., 16, 1103 43, 169 phenol) Matthews 0- I) JJ =1.2; 1.? 310-330 (150} 123 Earth and Schreder B., 11, 1334 36, 64 &~ jj jj = 1.2; 1.4 H .... 156-158 Lincke J. p. [2], 8, 46 27, 373 8- j jj )' )) JJ .... 156-158 Griess P. T., 154, 719 29, 932 &" J> 5! )' )> Jl .... 156-158 Herzig B., 13, 2233 ; W. A., 82, 500 &- n u J' JJ .... 156-158 Schmidt & Schultz B., 11, 1754 36, 252 8- JJ )> > JJ 342 161 j; JJ B., 12, 497 36, 651 &- JJ )J )> jj 345 161 JJ JJ B., 12, 498 36, 653 COMPOUNDS CONTAINING THREE ELEMENTS. 241 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. 8-Dihydroxydiphenyl (di- (C 6 H 4 .OH) 2 =1.2 ; 1.4 C 12 H 10 O 2 342 .... Schultz, Schmidt, A., 207, 348 40, 912 phenol) and Strasser 11 V =1.4; 1 11 .... 190 Earth and Schreder B., 11, 1336 36, 66 y- 11 =1.4; 1.4 11 m. a. 360 272 Schmidt & Schultz B., 12, 493 36, 651 y- 11 > 11 11 11 .... 272 11 11 11 36, 653 y- 11 11 1 11 m. a. 360 372 11 11 A., 207, 334 40, 910 y- 11 11 D .... 272 11 11 1) 11 >i 11 = * 340-350 .... Earth Z. C. [2], 7, 18 24, 122 it " C 6 H 3 .C 6 H 3 .(OH) 2 = ? 11 269-270 Dcebner B., 9, 130 29, 932 11 11 = * n 269-270 Engelhardt and Z. C. [1871], 261 Latschinoff 11 11 ? = ? 11 .... 270 Magatti B., 12, 1863 38, 250 a-Acetoxynaphthaleue C 10 H r OAc 11 .... Liquid Schaffer B., 2, 131 ; Z. C. vi., 859 [2], 5, 395 - 11 M H Liquid Liebermann A., 183, 225 31, 607 - 11 11 11 Liquid Watson Smith .... 32, 563 . n- 11 11 44 Schaffer A., 152, 288 - 11 11 n 46 A., 209, 150 ; 208, 248 a- 11 11 11 .... 49 Tassinari B., 13, 2420 ; 40, 280 G. I, 10, 491 0- 11 D .... 60 Schaffer B., 2, 131 ; Z. C. vi., 859 [2], 5, 395 3- 11 11 .... 60 Liebermann A., 183, 225 31, 607 0- 11 i) 60 Watson Smith 32, 563 ft- n 11 70 Schaffer A., 152, 288 ; 209, 150 Methylic 0-naphthoate C 10 H 7 .COOMe 11 abt. 290 77 Vieth A., 180, 319 30,86 a-Napthyl acetic acid C 10 H 7 .CH 2 .COOH 11 .... 131 Bosssneck B., 16, 641 44, 808 Guajenquinone .... 11 121-122 M. C., 1, 605 CHPh(OH).CO.C 4 H 3 O or Cxio-rd-mOt 137-139 E. Fischer B., 13, 1339 ; A., 38, 798; 42, Ph.CO.CH(OH).C 4 H 3 O 12 10 o 211, 228 500 a-Ethoxynaphthoquinone .... C 10 H 5 .OEt:0 2 ^12H 10 O 3 .... 126-127 Baltzer B., 14, 1900 42, 204 /CH 2 .CH.C(X Tetrahydronaphthalene di- carboxylic anhydride C,H/ | >0=1.2 X CH 2 .CH.C(X 11 184 Baeyer and Perkin B., 17, 450 46, 907 ? acid .... 11 .... 114-115 Paal B., 16, 2869 46, 599 ? C 15 H 12 3 ? 11 179 ; 1C9 Weltner B., 17, 70 46, 746 Trihydroxydiphenyl.,.. C 6 H 4 (OH).C 6 H 3 .(OH) 2 11 180 Hodgkinson and B., 16, 1103 43, 167 =1.2 ; 1.2.(4 ?) Matthews = 1.2 ; 1.2.(5 ?) 11 204-205 11 11 11 )1 Benzofurilic acid .... C 12 H 10 O 4 .... 108 E. Fischer A., 211, 231 42, 500 Piperic acid .... CH, : O, : C 6 H,.C,H,.COOH ab. 200 150 Babo and Keller iv., 653 1 1 o 4 4 216-217 ; Fittig and Mielck A., 152, 27 vi., 946 1* n a. f. 212-213 216-217 Lorenz B., 14, 788 40, 728 Acetyl -methylumbelli- 6 H,(OAc)CMe : CH.CO.O 11 51 150 Pechmann and B., 16, 2119 46, 66 i i ferone Duisberg Homoacetoxycoumarin C 6 HoMe(OAe)(CH)j.CO.O 11 .... 126 Tiemann and Hel- B., 12, 1002 36, 720 kenberg Tetrahydroxydiphenyl C 12 H 6 (OH) 4 JJ .... 84 Barth and Schreder B., 11, 1336 36,65 .... [C 6 H 3 (OH).,] 2 =(1.3.5) 2 1? .... n. f. 250 11 11 B., 12, 503 36, 634 Resoquinone ... abt. 90 d. Nietzki B., 12, 1982 38, 247 Sappaiiin > . . )) 201-202 u. c. Barth and Schreder B., 12, 506 1) Baphiin I } abt. 200 Anderson J. [1876], 896 30, 583 Acetyl furo'in C 10 H 7 O 4 .Ac \ 11 / ^12^10^5 75 Fischer B., 13, 1336 38, 798 76-77 E. Fischer A., 211,221 42, 499 From chloral hydrate re- C s H 4 O.(OAc),, 11 11 120 Michael and Comey A. C. J., 5, 349 46, 598 sorcinol Hexahydroxy diphenyl C 12 H,(OH) 6 C, 2 H,,,0 6 .*.. 70 Cobenzl M. C., 1, 670 42, 405 y- 11 11 11 d. 230 Barth&Goldschmidt B., 12, 1249 36, 931 0- 1) 11 d. 250 11 n B., 12, 1244 11 Q i 242 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. a-Hexahydroxy diphenyl .... C 12 H 4 (OH) 6 C 12 H 10 O 6 ? A., 169, 241 a-Ethoxynaphthalene C 10 H 7 .OEt C 12 H 12 .... Liquid Liebermann A., 183, 225 31, 607 a- 270 u. c. .... Jiebermann&Hagen B., 15, 1428 a- yvG) n. ft ** . L.. j 1. -5 Schaffer A., 152, 287 ; vi., 859 280-7 c. Z. C. [2], 5, 395 /3- ,, 33 n 0- 33 Liebermann A, 183, 225 31, 607 0- 11 274-275u.c. 33 Liebermann and B., 15, 1428 Hagen Ethylnaphthol C lu H 6 .Et.OH 98 Marchetti G. L, 11, 439 42, 410 Dimethylnaphthol .... C 10 H 6 Me 2 .OH 134 Connjizzaro G. L, 13, 385 46, 328 135 Cannizzaro and B., 12, 1575 Carnelutti .... 135-136 11 B.,16,428;G.L, 44,79 12, 393 Cinnamenylcrotonic acid C 6 H 5 .CH : CH.q,H 4 .COOH C 12 H 12 O 2 157-158 Perkin J. [1877], 792 31, 406 Valeric coumarin C 6 H 4 .C 5 H S O.CO 11 301 p. d. 54 ,, A., 147, 235 21, 472 ; vi., 501 Dimethoxynaphthalene C 10 H 6 (OMe) 2 134 Weber B., 14, 2209 42, 205 Oxidation of dimethylnaph- MM 104-105 Cannizzaro and G. L, 12, 393 ; 44, 79 thol Carnelutti B., 16, 428 From pyroguajacol .... ., 202 Wieser M. C., 1, 606 40, 813 Allylbenzoylacetic acid CH 2 : CH.CH 2 .CHBz.COOH C 12 H 12 0, 122-125 Baeyer and Perkin B., 16, 2128 46, 64 11 11 ;) H 122-125 Perkin 45, 186 Benzoyltetramethylene carb- CH 2 .(CH 2 ) 2 .CBz.COOH 143 B., 16, 1787 44, 1084 oxylic acid l 1 1 acid C 12 H 10 O 3 ? 179 ; 169 Weltner B., 17, 70 46, 746 Pencedanin (imperatorin) ... C 24 H 24 6 ; or, C 16 H 16 O 4 (?) 75 A., 5, 201 iv., 386 11 .... .... 75 Osann and Wacken- .... 27, 907 roder i> .... 75 Bribe A., 176, 70 28, 772 i .... 76 Heut A, 174, 67 .. .... 78 2 2 81-82 1 1 Phenylhomoparaconic acid ... . COCHPh . C 12 H 12 O 4 177 Fittig B., 14, 1825 42, 190 CO CH.COOH CHMe ji n 11 177 Penfield A., 216, 119 44,473 Acetophenoneacetoacetic acid CH 2 Bz.CHAc.COOH ..A 130-140 Paal B., 16, 2865 46, 599 a-Hydropiperic acid .... .... 63-64 Foster A., 124, 115 15, 19; iv.,65. r > - ii .... .... 70-5-71-5 A., 152, 56; 159, 140 a . .... B 75-76 Lorenz B., 14, 788 40, 728 "- ,< ii .... .... 78 Buri A., 216, 172 44, 485 P~ 11 11 130-131 Methylenedioxyphenylan- CH 2 : o 2 : c fl H 3 .CH : CEt. .... 120-160 Lorenz B., 14, 786 40, 728 gelic acid COOH Tetrahydronaphthalene di- . CH 2 .CH.COOH 199 Baeyer and Perkin B., 17, 450 46, 908 carboxylic acid 4 CH 2 .CH.COOH Phenylacetosuccinic acid COOH.CHAc.CHPh. COOH C 12 H 12 O 5 .... 120-121 Weltner B., 17, 66 46, 746 2 acid C 6 H 2 .(OMe) 2 .(CH : CH.COH) ... 162-163 Wassermann C. R, 88, 1206 36, 790 (COOH) Pyrousnic acid C 9 H 8 4 ? i' 195 p. d. Paternd B., 9, 345 30, 203 .... .... 205 G. I. [1882], 231 42, 1080 197 Salkowski B., 8, 1461 Acetoferulic acid (CH : CH.COOH).OMe.OAc 196-197 Nagai B., 11, 647 34, 579 =1.3.4 Acetoisoferulic acid =1.4.3 11 199 Tiemann and Will B., 14, 963 Murrayetin .... 110 .... Z. C. [1869], 317 Methylic trimellitate C 6 H 3 .(COOMe) 3 .=1.3.5 C 12 H 12 O 6 .... 63-65 Baeyer A., 146, 325 vii., 785 Dimethylic acetoxytereph- C 6 H 3 (COOMe) 2 .OAc=1.4.2 .... 76 Burkhardt B., 10, 147 32, 337 thalate COMPOUNDS CONTAINING THREE ELEMENTS. 243 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diaceto-a-homoprotocate- (CH 2 .COOHXOAc) 3 =1.3.4 Ci 2 H l2 O 6 .... 89-90 Nagai B., 11, 658 34, 579 chuic acid Ethylic diacetoxycomenate... C 5 HO 2 (OAc) 2 COOEt C 12 H 12 O 8 75 Keibsteiu J. p. [2], 24, 287 42, 197 Pliysodin 125 Gerding N.Br. Arch., 87,1 iv., 635 Pyrogalloltriglycollic acid ... C 6 H 3 (OCH 2 .COOH) 3 =1.2.4 C 12 H 12 O 9 .... 198 Giacosa J.p. [2], 19, 396 36, 930 Dimethyldihydronaphthol ... G' 10 H-.Me 2 .OH C 12 H H 113 Cannizzaro G. I., 13, 385 46, 328 Ethylpheiiylacetyleneacetate C 6 H 5 .CH : CEt (OAc) ; or, C 12 H 14 O 2 223-230 Liquid Morgan J. [1876], 398 20, 163 Et.CH I CPh(OAc) Propylic cinnamate .... C 6 H 5 .CH : CH.COOPr jj 283-284 Liquid Anschiitz and Kin- B., 11, 1220 34, 981 nicutt > 285-1 Liquid Weger A., 221, 61 46, 11 Diethylphthalylketone C 6 H 4 .(COEt) 2 =1.2 ) 52 A., 143, 262 Cu inenylacrylic acid C 6 H 4 Pr. CH : CH.COOH > 29 Baeyeraud Jackson B., 13, 115 38, 407 55 55 .... C 6 H 4 Pr.CH : CH.COOH 157-158 Perkin J. [1877], 790 31, 397 Phenolhydrate 2Ph(OH)+H 2 O C 12 H 14 O 3 .... 16 Calvert B. S. [2], 35, 379 40, 723 Isolmtylic benzoylformate .... Ph.CO.COO.CH 2 .CHMe > 170-174(38) Claisen B., 12, 629 36, 648 Etliylic allyloxybenzoic acid C 6 H.,.OC 3 H 6 .COOEt=1.3 ? 283-285 Crystalline Scichilone G. I., 12, 449 ; 44,336 B., 16, 796 55 55 55 =1.4 > 260 109 51 55 55 Methylic a-methoxyphenyl- OMe.(C 3 H 4 .COOMe)=1.2 >5 274-275 Liquid Perkin 39, 430 crotonate >! #- I) 11 J J 286 Liquid 55 39, 435 /3-Ethoxyphenylcrotonic acid OEt.(C 3 H 4 .COOH)=1.2 )) .... 133 55 .... 39, 439 . 55 11 J) 105 55 39, 437 ^ " 11 J) abt. 105 55 J. [1877], 792 31, 417 55 55 = 1.4 > 123-124 55 .... 31, 413 Eugenolacetate (CH : CH.CH 3 )OCH,.OAc M 270 Liquid Tiemann B., 9, 53 29, 711 =1.3.4 ; or 1.4.3 >5 iJ rt 30-31 Tiemann and Nagai B., 10, 202 32, 339 Thymodialdehyde Me.Pr.OH.(CHO) 2 ji 80 Kobek B., 16, 2096 46,57 =1.4.3.6.(2 or 5) Phenylglycol diacetate Ph.CH(OAc).CH.,(OAc) C 12 H 14 O 4 Liquid Wachendorff and B., 10, 1004 32,614 Zincke 55 55 )J 11 274(755); .... .... A., 216, 295 183-185(25) Kthylic acetylmandelate Ph.CH(OAc).COOEt n .... 73-5-74 A., 139, 302 benzolactate CH 3 .CH(OBz).COOEt >) 288 c. Liquid Wislicenus A., 133, 272 vi., 772 1 Methylic phthalate .... (COOEt),, = 1.2 )) 288 u. c. ; Liquid Grsebe and Born J. [1866], 411; vi., 942 295 c. A., 142, 344 55 11 11 i 294 c. (734) Liquid Grabe B., 16, 861 Diethylic isophthalate = 1.3 D 285 s. Storrs and Fittig A., 153, 284 vii., 978 ,, terephthalati- = 1.4 > 44 Beilstein A.,121,89; 132,269 v., 727 51 55 11 11 'i 44 Grimaux A. C. [4], 26, 331 25, 817 Dipropionyl quiiiol .... ^HXO.CO.CaHJ^l^ >i 113 Hesse A., 200, 246 38, 317 Phthalyl diacetate ! 8 H 4 (CH s OAc) 2 =1.2 it 37 Hessert B., 12, 647 36, 634 Terephthalyl diacetate =1.4 11 .... 47 Grimaux A., 155, 342 ; A. C. 26, 817 [4], 26, 331 Uimethylic xylenate C 6 H 4 (CH 2 .COOMe) 2 =:1.4 ) 56-5-57 Klippert B., 9, 17, 68 31, 468 Eugenoxyacetic acid C 6 H 3 (OMeXCH s : CH.CH 2 ) n .... 80-81 Sarrbach J. p. [2], 21, 158 38, 393 (O.CH 2 COOH) Methylic dimethylcaffeate .... C 6 H 3 .(CH:CH.COOMe) 55 .... 64 Tiemann and Will B., 14, 959 40, 740 (OMe) 2 =1.3.4 Methylic dimethoxyumbel- C 6 H 3 (CPT : CH.COOMe) )1 .... 87 55 55 B., 15, 2080 44, 200 late (OMe) 2 =1.2.4 Methylhomoferulic acid C 6 H 3 (CH:CMe.COOH) > 140-141 Tiemann and Kraaz B., 15, 2071 44, 198 (OMe) 2 Diacetoxyxylene C 6 H 2 Me 2 (OAc} 2 45 Pfaff B., 10, 1135 44, 918 Methyleugetic acid C 6 H 2 (OMe) 2 .C 3 H,.COOH M .... 180 Wassermann C. R., 88, 1206 36, 790 Piperhydronic acid ?* 96 Buri A., 216, 178 44, 485 Apiol 300 30 Gerichten B., 9, 1478 31, 326 1) 2 I 2 244 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Diethylic hydroxyisophtha- (COOEt) 2 .OH=1.3.2 C 12 H 14 O 5 Liquid O. Miller A., 208, 247 42, 405 late * TT =1.3.4 52 Jacobsen B., 11, 380 34, 583 IT T) lf 52 Ost J. p. [2], 14, 108 30, 522 = 1.3.5 IT 103 Heine B., 13, 496 38, 550 ii 104 M. C., 1, 439 : J. p. [2], 25, 515 Ethylic opianate C 9 H 9 3 .COOEt 88 Matthiessen & Foster 16, 345 iv., 206 n 92 Wohler A., 44, 126 92-2 A., 50, 5 ; 86, 194 Dimethyl rhamnetiu C.oHA-Me., .... 156-157 Liebermanu and B., 11, 1622 36, 272 Hermann Trimethoxycesculetic acid ... C 6 H,,(CH:CH.COOHXOMe) 3 TT 168 Tiemann and Will B., 15, 2082 44, 200 Methoxybenzaldehyde + ace- Ac 2 O + (C 6 H 4 .OMe.CHO) 75 .... A., 146, 372 tic anhydride =1.2 Picrotoxiu C 9 H 10 O 4 ? 170 Blyth 33, 317 C 15 H 16 O 6 ? 192 Apjohn C. N., 33, 265 30, 533 Io ID o f TT O ? ^30^34^13 199-200 Paterno & Oglialoro G. I., 6, 531 ; B., 31, 719 12, 685 200 B., 14, 539 C H O ? 199-200 Schmidt and Low- B., 14, 818 40, 740 JJ enhardt 201 Barth and Kretsch) W. A., 81, 7 Diethylic phenyldioxycar- C 6 H 4 (O.COOEt) 2 =1.4 J) .... 101 Bender B., 13, 697 40,48 bouate Diethylic quinolhydrodicar- MM .... 133-133-5 Hermann A., 211, 327 42, 714 boxylate .... 133 Duisberg B., 16, 135 n n IT i) 133 Wedel A., 219, 71 46, 834 Monethylic hemipinate 132-2 A., 86, 195 .... 141-142 M. C., 3, 370 Dimethoxydiacetoxybenzene C 6 H 2 .(OMe) 2 (OAc) :: .... 128; 132-133 Hofniaim B., 11, 333 Tetric acid 3C 4 H 4 O 2 .H 2 O |~1 TT f\ 262 189 Pawlow B., 16, 486 44, 730 1 14 , 268-280 189 Demarcay C. E., 88, 126 36, 457 Ethylic carbogallate .... J? 116-5 .... J. p. [2], 17, 164 Oxytetric acid 3(C 4 H 4 3 ).H 2 C 12 H 14 O 10 203-204 Deniargay C. E., 88, 289 36, 458 TJ abt. 280 pd. 203-204 B. S. [2], 33, 575 40, 255 Diethyl acetophenone Ph.CO.CHEtj C 12 H 16 229-231 Liquid Baeyer and Perkin B., 16, 2131 46,63 ,, 229-231(710) I. Perkin .... 45, 185 Amylic benzoate C 6 H 5 .COO(CHMe.CHMe,,) C 12 H 16 O 2 abt. 240 Liquid Wurtz A. C. [4], 3, 137 vi., 113 >, C 6 H 5 .COO(C 6 H n ) 260-7(745-6) Liquid Kopp A., 94, 311 i., 553 252-254 .... Eieckher J., 1, 699 H 261 Troost G. J. C., 1879 Isobutylic phenylacetate C 6 H 5 .CH 2 .COO.CH 2 .CHMe 2 ,, 147 c. Liquid Hodgkinson 37, 485 Propylic phenylpropionate .... Ph.C 2 H 4 .COOPr ,, 262-1 Weger A., 221, 61 46, 11 Butylacetoxybenzene C 6 H 4 .C 4 H 9 .OAc 245 Liquid Studer B., 14, 2187 42, 176 Methylic isobutylbenzoate .... C 6 H 4 .C 4 H 9 .COOMe= 1 .4 247 Palil B., 17, 1232 46, 1010 Ethylic cuminate C 6 .H 4 .Pr.COOEt 240 Liquid Gerhardt & Cahours A., 38, 81 ii., 181 Hydrocumenyl acrylic acid.... C 6 H 4 .Pr.(CH 2 .CH 2 .COOH) 70 Perkin J., 1877, 791 31, 400 Thymol acetate Pr.Me.OAc=? a. 236 Liquid Czumpelik B., 3, 483 vii., 420 ,, f. 1.3 IT 239-241(743) Liquid Mazzara B., 16, 243; G.I. 42, 1199 [1882], 333 ,, )! ' 244-245 Liquid Febve C. E, 92, 1290 42, 524 (natural) .... Pr.Me.OAc= 1 55 244-7 Paternd G.I. [1875], 13; 28, 638 B., 8, 71 (from cymene) 245-8 .... TT Etliylic eugenate (ethyl eu- (CH : CHMe).OMe.OEt=? 240 C'ahours A., 158, 284 ;Z. C. vii., 494; 24, 705 genol) [1866], 466 11 15 11 Tl TT 5) abt. 240 Liquid .... A., 108, 324 ii., 604 251 .... Grsebe & Borgmann A., 158, 282 vii., 4 94; 24, 705 n 251 u.c. Church 28, 116 = 1.3.4; or 1.4.3 252-254 .... Wassermann A., 179, 375 20, 706 COMPOUNDS CONTAINING THREE ELEMENTS. 24.5 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylic eugenate (ethyl eu- polymer C 12 H 16 O 3 125 Wassermann A., 179, 376 29, 706 genuol) Isobutyltoluic acid Me.C 4 H 9 .COOH=l.?.2 140 Effront B., 17, 419 46, 900 Methyl thymotic aldehyde ... C 6 H 2 .Me.Pr.OMe.CHO 270 Liquid Kobek B., 16, 2096 46, 56 =1.4.3.6 Thymoil 235 pd. 48 Lai 1 em and A. C., 49, 160 v., 792 Amylic salicylate OH.(COOC 6 H n )=1.2 C 12 H 16 3 270 Briihl B., 12, 197 36, 499 270 Liquid Drion A., 92, 513 v., 166 Ethylic oxycuminate COOEt.OH.Pr=1.3.4 .... 73-75 Earth B., 11, 1575 36, 158 Ethoxycumiuic acid COOH.OEt.Pr=1.3.4 140 Lipmann & Lange B., 13, 1662 40, 276 Thymol glycollic acid Me.Pr a .(O.CH 2 .COOH) it .... 147-148 Spica G. I., 10, 340 38, 888 =1.4.5 Jl ,, .... 148 Saarbach J. p. [2], 21, 159 38, 393 Carvacrol glycollic acid =1.4.6 149 Spica G. I., 10, 340 38, 889 Methylthymotic acid Me.Pr.OMe.COOH=1.4.3.6 ) 137 Kobek B., 16, 2096 46, 56 Acetocoeruliguol C 9 H 10 .OMe.OAc 265 pd. Crystalline Pastrovich M. C., 4, 191 44, 1006 Asarone .... ,, 296 59 Bizza and Butlerow B., 17, 1159 46, 1159 Ethylic cantharate .... CH 2 .O.CO C 12 H 16 4 abt. 300 Piccard B., 11, 2122 36, 271 1 / H 4 .O 6 H 4 .OH.COOEt Methoxyhydrohomoferulic C 6 H 3 (CH 2 .CHMe.COOH) 58-59 Tiemann and Kraa B., 15, 2072 44, 198 acid (OMe) 2 Amylic gallate C 6 H 2 .(OH) 3 .COOC 5 H U C 12 H 16 O 5 .... 139 Ernst and Zwenger A., 159, 27 vii., 539 ; 24, 822 Diethylic succinylsuccinate CH 2 .CO.CH.COOEt Ci 2 H 16 O 6 .... 1S6-127 Hermann B., 8, 1039 29, 371 1 ' I CH 2 .CO.CH.OOOEt ,, .. .. .... .... 127 Duisberg B., 16, 134 .. i. .. .... T) 128 Remsen B., 8, 1409 29, 564 , 133 FehHng A., 49, 186 >, i. C 6 H 6 2 (COOEt) 2 .... 156 Hermann A., 211, 306 42,713 Plienol glucoside C 6 H (i (OPh)(OH) 4 .CHO 171-172 Michael C. B., 89, 355 36, 1038 Erythrite orsellinate (picro- .... C 12 H 16 7 158 A. erythriii) .... 141-143; 162 Schiff B.. 14, 2561 165-166 G. I., 11, 99 40, 610 " o f 1 fiA i f(f\ " Oi. 1. 1 \JO 1OO 166-167 M B., 14, 304 40, 439 J1 O : CH(CH.OH) 4 .CH 2 O.C 6 H 4 . jj 168 Strecker 44, 347 OH .... 168-169 Michael B., 14, 2099 .... 170 Zwenger and Him- A., 129, 203 vi., 190 " melmann .... .... 187 Schiff B., 15, 1841 44,60 Triacetyl cellulose C 6 H 7 2 (OAc) 3 C 12 H 16 O g 232 Franchimont C. B., 92, 1053 40, 709 Acetyl erythrodextrin C 6 H 7 Ac 3 5 n 180 Herzfeld B., 13, 267 38, 620 achrodextrin.... n 180 n B Diethylic diacetyltrioxyma- COOEt.C(OAc) 2 .CO.COOEt C 12 H 16 O 9 .... 48 Tanatar B., 13, 1387 38, 875 leate Isobutyl ethoxybenzene C 6 H 4 .OEt.(CH 2 .CHMe,) C 12 H 18 234-236 Liebmann B., 14, 1843 42, 171 n 241-342 e. n B., 15, 1991 44, 59 Ethyl thymol ... Me.Pr.OEt= ? 222 Liquid Z. C. [1865], 532; vi., 1090 [1869], 43 = 1.4.6 228 (656-58) Paterno and Can- G. I., 9, 455 38, 247 zoneri . Me.Prf.OEt=1.3.? 227-2-229-2 Liquid Spica G. I., 12, 543; 44, 460 (753-2) B., 16, 792 Xylitone (xylite oil) .... rt 251-252 .... Pinner B., 15, 589 42, 942 ,, .... n a. 200 P. A. ., 29 Dipropyl resorciiiol C,H 4 (OPr) s =1.3 C 12 H, 3 O 2 251 Liquid Kariof B., 13, 1677 40, 269 Thymoilol 290 145 jallemand A. C., 4P, 160 v., 793 Masopin . . .... 155 Genth A., 46, 124 ii., 856; 30, 4 17, 246 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Acetyl camphor Ci 2 H 18 O 2 227-230 Baubigny J., 19, 624 Authemol acetate ...< 5> 234-236 A., 195, 105 Ethylic diallylacetoacetate .... CAc(CH 2 .CH : CH 2 ) 2 .COOEt CtjH w O a 239-241 Liquid Wolff B., 10, 1956 ; A., 34, 293 201, 47 Triethylpyrogallol C 6 H 3 (OEt) 3 =1.2.4 )5 .... 39 Hofmann B., 11. 800 34, 870 j )) )) )1 39 Will and Jung B., 17, 1089 46, 114.3 Oxycamphor acetate J) 273-5 c. 69 Schrotter M. C. [1881], 227 42,66 Ethoxycamphoric anhydride C a H 13 (OEt).CO.O.CO C 12 H 1S O 4 63 Wreden Z. C. [2], 7, 97 ; 24, 549 ; 25, 1 1 A., 163, 335 896 i) 63 Kuehler Z. C., 72, 264 vii., 236 Cascarillin 205 C. and E. Mylius B., 6, 1052 Diethylic diacetosuccinate .... COOEt.CHAc.CHAc.COOEt C 12 H 18 6 77 Euegheimer B., 7, 892 29, 367 78-79 Harrow A., 201, 145 33, 427 Triethylic pheuaconate C 3 H 3 (COOEt) 3 ) 225 Liquid Carius A. vi., 905 aconitate (aeonate) 5> 236 Liquid Crasso A. C. [3], 1, 311; 24, 1047 ; vii., J. [1871], 597 349 t? Jl Jl 236 Liquid Gerhardt A., 34, 59 i., 55 i< 250-253 (250) Conen B., 12, 1655 v D cooEt.cn : c(cooEt)CH 2 . )) 270-275 Liquid Mercadante G. I., 1, 248 24, 1048, vii., COOEt 349 Triethylic trimethylene tri- COOEt.CH.CH 2 .C(COOEt) 2 276 Liquid Conrad & Guthzeit B., 17, 1185 46, 992 carboxylate 1 ' Diethylic diacetotartarate C 2 H 2 (OAc) 2 (COOEt) 2 Ci 2 H 18 O 3 48 Tanatar B., 13, 1387 (inactive) Diethylic diacetoracemate .... u 298 d. 50-5 Perk in As., 5, 286 v., 693, -20, 147 diacetodextro tar- COOEt.CH(OAc).CH(OAc). ii 288-5 c. 63-5 As., 5, 285 ; A., tarate COOEt 129, 188 M )> )J " j 291-292 66-5 Anschutz B., 14, 2790 42,831 >? )* 11 )' jj 291-292 66-5 Pictet B., 15, 2243 ) C 2 H 3 (OAc) 2 (COOEt)., H 294-298 p. d. 67 Perk in As., 5, 286 v., 693; 20,147 Eucalyptol C^H^O 175 Cloez A., 154, 372 ; vii., 493 ; 29, A. P. [3], 5, 293 244 P H O 170-210 Planta-Keichenau A., 155, 145 vii., 20 Ethylcamphor ^24 40 2 C 10 H 15 EtO JJ 226-229 ; Liquid Baubigny Z. C. [1866], 409 ; vi., 388 226-231 [1868] 298 ; J., 19, 624 Matico-camphor 94 Kiigler B., 16, 2841 46, 611 From methylethylketone .... ; 248-253 Liquid Schramm B., 16, 1581 44, 1080 wormseed oil .... )) 174-175 ... Volckel J., 6, 513 mesityloxide n 213-217 A., 180, 8 Acetate of C 10 H 18 O .... From oil of tansy C 1:! H 20 O 2 abt. 220 Bruylants J. Ph. [4], 26, 393 34, 158 Camphylic acetate ! 227 24 Montgoltier A. C. [5], 14, 50 34, 894 Acetate of C 10 H 18 O From coriander oil 1 234 Grosser B., 14, 2493 Acid from poeonia moutan .... ,. (?) 45 Jagi A. P. [3], 13, 335 36, 306 From manufacture of phorone ) 310-320 Pinner B., 15, 590 42, 942 Allylglyceryl ether .... C 3 H 6 (OC 3 H 5 ) 3 c,A o 3 232 Liquid Berthelot and De A. C. [3], 43, 257 ; i., 143 Luca A., 100, 361 Diisobutylic fumarate COO(CH 2 PrP).CH : CH.COO VB**SBM4 265-270(760); Liquid Purdie .... 39, 354 (CH 2 Pr0) 170 (160) Valeral+ benzoic anhydride C 5 H 10 O.C 7 H 10 3 )) 264 111 Kolbe and Guthrie A., 109, 296 v., 974 Ethyl camphoric acid .... 51 196 Malaguti A. C. [2], 64, 164 Ethylic paracamphorate .... 51 270-275 Liquid Chautard C. R., 56, 698 vi., 390 ( 'onylene diacetate .... C 8 H 14 (OAc) 2 15 225 Wertheim W. A. B, 47 [2], vi., 490 491 Diethylic /3-ethylacetosuc- COOEt.CHAc.CHEt. COOEt 12 H 2U 5 262 Liquid Clowes B., 8, 1208 29, 565 cinate > n If H 263 Liquid Thome .... 39, 337 , "- >t COOEt.CAcEt.CH 2 COOEt 1) 263-265 Liquid Huggenberg B., 8, 1209 29, 565 )' U 5) 263-265 Liquid tt A., 192, 146 34, 782 COMPOUNDS CONTAINING THREE ELEMENTS. 247 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diethylic a-/3-dimethylaceto COOEt.CMeAc.CHMe. C, 2 H 20 O 6 270-272 Liquid Hard ninth A., 192, 142 34, 782 succinate COOEt o-methylacetoglu- COOEt(CH 2 ) 2 .CMeAc. 280-281 Wislicenus and A., 192, 133 34, 784 tarate COOEt Limpach Dialdane diacetate .... i 158-160 (20) .... C. R., 92, 1371 Hexylglycerol triacetate CHjOAc.CHOAc.CH2.CH.,. C 12 H 20 6 270-280(760) Liquid Markownikoff B., 13, 1843 40, 146 CH(OAc)Me 192-196(100, (prim. C 6 H u (OAc) 3 280-285 .... J. E. [1881], 353 and sec.] j C s H 3 MeEt(OAc) 3 1) 270 (745-6) ; .... M. C., 4, 42 153*8-155-8 (21) Diacetoxy-butylic acetoxy- CHMe(OAc).CH 2 .COO.CH 3 1> 275 (760) ; Liquid Wurtz C. R, 97, 1525 46,579 butyrate CH 2 .CH(OAc)M 176 (15) Ethylic tricarballylate C 3 .H 6 .(COOEt) 3 > 295-305 Liquid Simpson P. R. S. v., 880 Triethylic propenyltricar- (COOEt) 2 .CH.CHMe.COOE )> 270p.d.(760); Liquid Bischoff B., 13, 2165 ; A. 40, 156 ; 44, 45 boxylate 178-180 (25) 214, 53 Triethylic citrate C 3 H 4 .OH.(COOEt) 3 C 12 H 20 O 7 261 (300) Liquid Conen B., 12, 1653 38, 36 ) u 280 Liquid .... i., 1001 ,, 11 283 .... Malaguti A., 21, 267 ,, ,, C 3 H 4 .OH.(COOEt) 3 11 283 u. c. Glaus B., 8, 867 Hydroxytetric acid 3C 4 H 6 O 3 .H 2 O C 12 H 20 O 10 .... Ill Demar9ay C. R., 88, 289 36, 459 Inuloid 1 *ifl_ 1 *\ r ~\ n .... _ 11 .... loU lo> fopp A., 156, 190 vii., 670 Hexylene oxide (C 6 H U ) 2 Oj2-tt.i 2 ^ 116-118 Destrem B., 16, 229 Di (diallyl) oxide )> 11 180 Liquid Wurte A. C. [4], 3, 129 vi., 93 Mesityl oxide.... abt. 206 T " "A -p Al Af\ ftn^ n > -LjlQUlQ xissyer ., 140, 297 vi., 822 Ethyl borneol .... 11 202-5 .... Baubigny Z. C. [1868], 481 ?-Ketone 917 91O T * 'A Pawrlrkflf RQ *7tiG A 1) *i i zitf -LjlQUlQ i diWlOII , o, 7oo ; A., 29, 895 ; 32, 733 187, 104 From isobutahlehyde .... CuH^ 154-157 Liquid Perkin .... 43, 93 )> ?> >" )> 154 Urech B., 12, 192 36, 520 Dipropylallylcarbinol acetate (CH 2 : CH.CH 2 ).Pr 2 C.OAc )1 210 (751 r.) .... A. and P. Saytzeff A., 196,110; B. 36, 136 11, 1939 Meiithylic acetate C lu H 19 .OAc 1 222-224 Oppenheim A., 120, 351 iii., 881 ; 15, 26 Methyl etherof petroleumacic 1) 236-240 Hill and Medinger B., 7, 1218 Ethylic dipropylaceto acetate CAcPrOyCOOEt CjgH^Og 235-236 Liquid Burton A. C. J., 3, 385 42, 599 /3-hexylacetacetate .... CHAc(C 6 H 13 ).COOEt 1) 247-249 .... Lundahl B., 16, 789 Acid from isobutaldelhyde .... .... 11 245-255 I. -10 Perkin 43, 92 Xylite naphtha )) 110-120 .... Schweizer and J. p., 23, 14 i., 29 Weidmann Terpin acetate C 10 H 18 (OH)(OAc) 11 140-150 (20) .... Oppenheim A., 129, 158 v., 923 Octylene diacetate C 3 H 16 (OAc) 2 CiAi>o4 240-245 Wurtz A., 128, 231 iv., 173 j) .... .... 11 11 245-250 Clermont J., 17, 517 Ethylene diisovalerate .... 11 abt. 255 Loureno A., 114, 124 Diisoamylic oxalate OOOC & xijj).i n 262 Liquid Balard A. C. [3], 12, 311 iv., 268 ? ) )! 260 .... Cahours - 11 !> 265 .... Delffs A., 130, 200 Diisobutylic succinate (CH 2 .COO.CH 2 Prf) 2 )1 264-75- .... Perkin 45, 519 26575 c. Diethylic tetramethyl succin- COOEt.CMe 2 .CMe 2 . COOEt. 11 230-231 u.c. Hell and Wittekind B., 7, 321 27,683 ate diethyl succinate.... COOEt.C 2 H 2 Et 2 .COOEt 1 233-2:15 Hell B., 6, 31 26, 495 suberate C,H 12 .(COOEt) 2 )) 230 Liquid Bromeis A., 35, 89 v., 450 JJ 11 260 .... Laurent A. C. [2], 66, 157 j, .... )1 11 280-282 .... Gautterand Hell B., 13, 1170 38, 875 ,, ,, .... 11 282-286 c. .... Perkin .... 45, 517 (760); 251- 253 c. (320) Dimethylic sebate C 8 H le .(COOMe) 2 )) 285 25-5 Carlt C. R,, 37, 130; J. \ '., 214; 20, 315 [1853], 430 i> 1J 1J 287-289 pd. ; 38 Veison J. [1876], 576 39, 316 288 c. 1 248 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet, & J. Ch. Soc. Ethylic hydrogen sebate C s H 16 .COOEt.COOH C^H^O, s. 10 Neison 29, 320 11 250-253 J. R., 12, 460 Georetinic acid C 24 H 42 O 7 ? ,, 82 J. [1852], 647 1 P TT O 270 Z. C. [1867], 708 Diisobutylic dextrotartarate [CH(OH).COO.CH 2 Prf,,] ^12 22 5 C 12 H 22 O 6 323-325(760); 68 Anschutz & Pictet B., 14, 2790 ; 15, 42, 831 197 (23) 2242 Tetrethylene diacetate (AcO.C 2 H 4 .O.C 2 H 4 ) 2 O C 12 H 22 O 7 a. 300 Liquid Wurtz A. C. [3], 69, 338 ii., 568 ? (sugar) C 6 H 12 4 1 C^H^O,, ? .... 105 Liebermann & Giesel B., 16, 935 Quercite ether (C 6 H 10 4 )(C 6 H 12 5 ) C^HaA 210 Prunier C. R., 84, 184 31, 450 anhydride 228-230 A. C. [5], 15, 5 36, 240 Melezitose +4H 2 O C 12 H 22 O,, b. 140 Berthelot A. C. [3], 55, 282 iii., 868 +H 2 O 140 Villiers B.S.,27,98;C.R., 31, 451 11 84, 35 Saccharose (cane sugar) 11 160 Briason .... v., 470 11 11 .... n 160 Quincke P. A., 138, 141 vii., 243 11 11 160 Berzelins i) 11 .... 11 180 Peligot A., 30, 71 Lactose (milk sugar).... ^ ,'. .... .... 204 Bouchadat C. R., 72, 462 24,915 11 11 .... 203-5 Lieben G. J. C., 1856 Mycose (trehalose) .... .... 100 Mitcherlich A., 106, 15 11 11 +2H 2 O 109 .... .... iii., 1068 .... 120 .... A. C. [3], 55, 272 Decyl methyl ketone Me.CO.(CH 2 X.Me C 12 H 24 246-247(760), 21 Krafft B., 15, 1708 42, 1272 177-5 (100) Methylcaprone C 6 H U .CO.C 6 H 10 .CH 3 144 Popoff B., 5, 597 25, 892 i 152 Schorlemmer Chem.Carb. Oomp. 11 155^166 .... Schmidt B., 5, 597 ,, Laurie aldehyde .... . .... 184-185(100) 44-5 Krafft B., 13, 1414 38, 867 142-143(22) (?) 232 Liquid Williams P. T. [1858], 1, 99 v., 133 From bark of "Bois Piquant ' 11 .... 285 Heckel and Schlag- C. R., 98, 996 46, 848 denhauffen Decylic acetate CH 3 (CH 2 ) 9 .CH 3 .OAc C 12 H 24 O 2 125-126(15) Liquid Krafft B., 16, 1717 44, 1075 11 11 C 10 H 2 ,.OAc 11 228-235 .... Z. C. [1870], 404 11 11 11 219-5 J., 1864, 338 Octylic butyrate C 3 H 7 .COOC 8 H U 244-245 .... .... A.. 166,81 Hexylic caproate CH 3 .(CH 2 ) 4 .COO(CH 2 ) 5 CH. J 245-6 c. Liquid Franchimont and A., 163, 197 ; B., vii., 646; 25, (il (761-17) Zinck6 4,824 CHMePr.COOC 6 H 13 n 223-5 M. C., 4, 36 Ethylic caprate (rutylate) .... C 9 H,,.COOEt v 243-245 Fischer A., 118, 314 11 11 (ISO).... 243 Grimm A., 157, 264 24, 360 11 11 J! .." ., 243 Liquid Fischer & Rowney vii., 249 Methylic undecylate.... CMe(CMe 3 ) 2 .COOMe 11 217-220 u.c. Liquid Butlerow B.,12,1484; J.R., 38, 230 11, 203 (umbel- C 10 H 21 .COOMe n 244-246 Stillmann & O'Neill A. C. J., 4, 206 42, 1186 lulate) Duodecylic acid (lauric) CH 8 (CH 2 ) 10 .COOH 11 2S5 (100) 43-6 Krafft B., 13,1415; 15, 42, 1272 1708 11 11 11 JJ rt 225-5 (100) 43-5 11 B., 12, 1666 38, 34 11 11 11 11 227-5 c. (100); 11 B., 16, 1718 176 c. (15) 11 11 M CnH^COOH ,, .... 43 Oudemans J. P., 81, 367 i., 1063 1 11 11 43-6 Heintz P. A., 92 ; J., 7, 457 iii., 475 11 11 11 ' 11 .... 43 Sthamer A., 53, 393 11 11 11 11 11 42-43 Marsson A., 41, 333 n 11 11 11 11 42-43 Gorgey A., 66, 305 11 11 11 11 11 4'3-8 Schlippe A., 105, 14 11 11 11 11 11 45 Miiller J. p., 58, 469 11 (laurosteric) 11 .... s. 44 Reichardt A. P. [3], 10, 339 32, 518 Acid, from axin .... 11 42 Hoppe J. p., 30, 102 v., 1087 Acid, from coeoa butter cf. B 16, 1104 11 .,.. 57-5 Kirigzett B., 10, 2243 COMPOUNDS CONTAINING THREE ELEMENTS. 249 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference, Watts' Diet. & J. Ch. Soc. Hordeinic acid .... C 12 H 24 O 2 60 .... J. [1855], 513 ? .... ) abt. 200 Lieben A., 178, 1 29, 59 Triisobutyric aldehyde .... C 12 H 24 3 59-60 Barbaglia B., 5, 1052 vii.,228;26,379 .... J .... 60 ? B., 6, 1064 27,47 !) 1> )) 194 59-60 Markownikoff B., 6, 1176 27,144 JI II cf. B 13, 590 )' .... 60 Urech B., 12, 1748 Diisoamyloxalic acid.... C 6 H n ) 2 (OH).COOH ) .... 122 Frankland & Duppa P.R.S.;A.,142,14 iv., 277 Hexyl oxide (/3) (CsIW C 12 H 26 203-5-208-5 Wanklyn and Erl- J., 16, 521 iii., 154 (751) enmeyer Heptylisoamyloxide C 7 C l6 .O.C b H. n JJ 220-221 Wills J., 6, 510 ill., 147; 6, 316 Duodeeyl alcohol CH 3 .(CH,) 10 .CH 2 OH J) 143-5 (15) 24 Krafft B., 16, 1719 44, 1076 .... 1 265-275 .... Z. C. [1870], 404 Diisoamylacetal CH 8 .CH(OC 5 H 11 ) 2 C 12 H 26 O 2 194-196 Backmann A., 218, 38 44,727 H ) 210-8 c. Alsberg J., 17, 485 Isoamylethylvaleral C 4 H 9 .CH(OEt)(OC s H n ) T 200-210 .... Z. C. [1866], 465 Methyl-/3-butyl pinacone ... [CHMeEt.CMe(OH)] 2 ) 248-250 Wislicenus A., 219, 307 44,966 Ethylpropyl pinacone CEt(C 3 H 7 )OH.C(C 3 H 7 )OH )> 252-255 1. 20 Coninck C. B., 82, 92 29, 694 17 > abt. 255 Liquid Oechsner B. S. [2], 24, 99 30,67 11 V 254-255 .... B. S., 25, 10 Pinacolin CMe 2 (OH).CMe 2 .CMe 2 .CMe 2 .... 69 Friedel and Silva C. R., 76, 226 vii., 982 ; 26, OH 489 From reduction of C 12 H 2 . 2 O 2 Alcohol 11 270-275 I. -10 Perkin 43,94 Ethylidene oxyisobutyl alco- C 4 H 8 (OC 4 H 9 ) 2 C 12 H 26 O 3 174 Laatsch A., 218, 13 44, 788 holate Amylic dipropylic ortho- CHtOPr^OC^,) 222-230 .... Pinner B., 16, 1647 44, 1089 formate Propylic dibutylic OH(OC 4 H 9 ) 2 (OPr) 207-208 )5 i> i! ;> )) ) 212-214 Liquid J) Triethyldiglycerol (C 3 H 5 ) 2 0(OEt) 3 (OH) C 12 H 36 O 5 288-290 Liquid Reboul and Lorenzo A., 119, 235; C. il., 894 R., 52, 401 ; A. C. [3], 67, 310 Hexethylene glycol C 12 H 26 O 7 325 (25) Lorenzo A. C. [3], 67, 281 Glyceric aldehyde C 3 H 6 3 or (C 3 H 6 0,) 4 .H 3 ^12^26*^13 130-135 71-72 Kenard C. R., 82, 562 30,64 Sorbite . .... . . 2C 6 H, 4 O 6 +H 2 O P "FT O 102 Boussingault C. R., 74, 939 vii., 1093 ; 25, V ^12 JJ -30 13 480 j3-Picroerythrin C 13 H 6 6 115-116 Lamparter A., 134, 243 iv., 641 Diphenylene ketone C 6 H 4 .C S H 4 .CO= ? C 13 H 8 336-338 .... Grsebe B., 7, 1630 28, 455 )> 1) 81-82 Barbier A. C. [5], 7, 472 ; 31, 72 ; 28, 456 C. R., 79, 1151 =1.2 ; 1.2 > .... 82 Friedlander B., 10, 127 32, 336 ,, i )> )5 .... 82 B., 10, 536 32, 493 >, V )) M .... 83-84 Anschiitz & Schultz B., 9, 1402 31, 210 ,1 ,, = ? I) .... 83-84 Wittenberg and B., 16, 502 44, 804 Meyer ,, =1.2 ; 1.2 ) a. 300 83-5-84 Fittig & Ostmeyer A., 166, 373 vii.,435;26,893 (see = 310-312 99 Salzmann and B., 10, 1400 34, 79 C, 3 H 10 0) Wichelhaus Diphenylene ketone oxide .... C 6 H 4 .O.C 6 H 4 .CO= ? 13 H 8 2 .... 91 Eichter J. p. [2], 23, 350 42, 618 )i =1.2 ; 1.? n 173-174 11 J. p. [2], 28, 273 48, 324 11 11 11 ) 173-5 Perkin B., 16, 340 43,35 5, 11 11 = ? v 173 Niederhausern B., 15, 1124 11 11 11 " 1) J i> 173 Grsebe and Ebrard B., 15. 1679 V ,1 >1 >1 V a. 300 ./73-174 Merz and Weith B., 14, 192 40, 264 11 11 11 )t )) )> .... 170-171 Salzmann and B., 10, !400 34, 79 Wichelhaus )1 >1 >- 5' J 173-174 Behr and V. Dorp B., 7, 399 vii., 902 ; 27, 798 Hydroxydipheuylene ketone L',H,(OH).C 6 H 4 .CO "** 91 Richter J. p. [2], 28, 273 46, 325 250 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. /3-Methylene diphenylene .... C I3 H 8 2 .... 181-182 Barbier A. C. [5], 7, 500 31, 72 quinone (fluorene quinone) a- .... abt. 270 C.-R, 79, 1151 28, 456 8- ,j .... 276-277 u.c. Carnelley .... 37, 711 =288 c. s- .... 277-278 u. c. y~ j> jj jj jj .... 280-281 c. 37, 709 /3-Naphthacoumarin C 10 H 6 .CH : CH.CO.O jj 118 Kauffmann B., 16, 685 44, 1136 1 J Salicyl resorcinol oxide C 6 H 3 (OH).O.C 6 H 4 .CO C 13 H 8 3 146-147 Michael A. C. J., 5, 81 46, 311 Euxanthone .... C 6 H 3 (OH).O.C 6 H 3 (OH).CO C HO 232 Grsebe and Ebrard B., 15, 1675 42, 1301 13 8 4 Dihydroxydiphenylene CTT f\ ff\TT\ ,n ft ~\ I,J I t t~t ,. .... 330 Grsebe B., 16, 863 ketone oxide Hexahydroxydiphenylene C 12 H 2 (OH) 6 :CO C 13 H 8 O 7 d. 250 w. m. Very high Barth and Gold- B., 12, 1248 ketone schmidt Diphenyl ketone (benzo- CO.(C 6 H 5 ) 2 C 13 H 10 .... 26-26-5 Zincke B., 4, 299 24, 508 phenone) jj jj jj 300 26-26-5 B., 4, 577 24, 832 ; vii., . 176 ., m B 300 26-26-5 B., 4, 510 24, 689 jj jj jj H 170 (15) .... Angeblis and An- B., 17, 165 46, 753 schiitz j> j* >j M jj 295 .... Grsebe B., 7, 1630 28, 455 TJ JJ JJ u jj 306 Crafts B. S., 39, 196, 277 44,843 JJ JJ JJ 296-7-297 46 Crafts and Ador B., 10, 1856 u. c. (730) JJ JJ JJ 315 46 .... .... i., 562 ,J J, JJ jj .... 47-48 Goldstein B. S. [2], 35, 108 40, 423 JJ J JJ 295 (741) 48-48-5 Linnemann A., 133, 1 iv., 478 JJ JJ JJ jj .... 48 Behr B., 5, 278 25, 472 JJ JJ JJ j) 300 48-49 Zincke B., 4, 578 24, 832 ; vii., 176 JJ JJ JJ jj 300 49 Grucarevic & Merz B., 6, 1243 JJ JJ JJ j> .... 49 Kollarits and Merz B., 6, 537 (?) jj 280 97 Gladstone & Tribe 41, 7 Methylenediphenylene oxide C 6 H 4 .O.C 6 H 4 .CH,=(1.2) 2 ); 300-301 u.c.; 98-5 Merz and Weith B., 14, 191 40, 264 i i ' 315 c. jj !! JJ jj .. 98-5 Eichter J. p. [2], 28, 273 46, 324 jj j. JJ JJ jj 310-312 99 Salzmann and B., 10, 1400 ; cf. Wichelhaus B., 15, 1676 jj j JJ TJ jj 98-5 Niederhausern B., 15, 1124 Fluorenic alcohol C 6 H 4 .C 6 H 4 .CH(OH) 153 Barbier A. C. [5], 7, 504 ; 31, 73 ; 30, 77 i 1 C. E., 80, 1396 B jj .... 151-152 Friedlander B., 10, 535 32, 493 Phenylic benzoate C 6 H 5 .COOPh C 13 H W O 2 314 c. 68-69 Guareschi G. I., 3, 398 27, 262 jj 65 E. Fischer B., 8, 59Q 28, 1035 jj jj " ... !; 66 List and Limpricht A., 90, 191 i., 553 Benzoyl phenol C 6 H 4 .OH.Bz=1.4 jj 134 Dobner and Stack- B., 9, 1919 ; 10, 32, 327 mann 1970 I! JJ jj 134 Dobner and Weiss B., 14, 1840 42, 177 134 Eennie 41, 228 . .... jj 134 Dobner A., 210, 249 42, 508 Phenylbenzoic acid C 6 H 4 .Ph.COOH=1.2 jj .... 110 Schmitz A., 193, 120 36, 164 jj jj ,, 110-111 Eichter J. p. [2], 28, 273 46, 326 jj 110-111 Fittig B., 6, 167 26, 750 JJ )5 U JJ ,, 110-111 Fittig & Ostmeyer A., 166, 374 26, 893 JJ )J jj =1.3 jj 160 Schmidt & Schultz B., 11, 1756 36, 163 !> 160-161 Barth and Schreder M. C., 3, 808 44, 468 'J 5J " = 1.4 jj 209-211 Carnelley 29, 18 J) J7 ., 208-212 " jj COMPOUNDS CONTAINING THREE ELEMENTS. 251 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Pheuylbenzoic acid C 6 H 4 .Ph.COOH=1.4 C 13 H 10 2 211-213 Camelley .... 20, 18 ,, ,, > M .... 216 u.c. 37, 713 ,, ,, .... .... ) i ) .... 217 ji B., 8, 1467 20,18 ,, w 216-220 37, 707 j 5) >? ... 216-217 Meyer and Rosicki B., 11, 2173 36, 466 v * > V > 216-217 Barth and Schreder M. G, 3, 800 44, 468 ,, ,, .... .... > M )t .... 216-217 Sehultz B., 6, 417 ; A., 20, 888 174, 213 >' 218-219 Dobner A., 172, 112 27, 892 Naphthylacrylic acid C 10 H r CH:CH.COOH D 205-207 Lugli G. I. [1881], 393 42, 206 1 .... > .... 170 Lunge and Stein- B., 14, 2204 kauler Diphenylic carbonate CO(OPh) 2 Ci 3 H w O 3 .... 78 Kemp Z. C. [2], 6, 205 vi., 918 ,, H 88 J. p. [2], 27, 41 ,, , T .... .... n yi 301-302 J. p. [2], 27, 42 Phenoxybenzoic acid C 6 H 4 .OPh.COOH=1.4 > .... 159-5 Klepl J. p. 28, 193 46, 447 Phenylic hydroxybenzoate .... C.H 4 .OH.COOPh=1.4 )> .... 176 (b.p. ?) > 46, 448 y-Dihydroxybenzophenone .... CO(C 6 H 4 .OH) 2 =1.2; 1.4 )) .... 143-144 Michael B., 14, 656 ; 40, 592; 46, A. C. J., 5, 81 311 s- =(1.4), >^ .... 161-162 Stadel and Sauer B., 13, 836 ; A., 38, 646; 44, 218, 339 992 - )< W > ?> 206 Baeyer & Burkhardt B., 11, 1300 34, 886 "- v > i 205-207 Liebermann B., 11, 1435 "- i) r> i j .... 210 Stadel and Gail B., 11, 746 ; A., 34, 672; 44, 218, 339 991 - 1^ M .... 210 Stadel and Sauer B., 11, 1748 36, 242 )J i .... 210 Caro and Greebe B., 11, 1348 "- )) > 210 Gail A., 194, 335 36, 326 Benzoresorcinol C 6 H 3 (OH) 2 .Br=1.3.? ? .... 144 Dobner and Stack- B., 11, 2271 36, 320 mann ? 144 Dobner A., 210, 258 42,508 Benzopyrocatechol = 1.2.? JT 145 11 A., 210, 262 i o-3-Naphthacoumaric acid .... O in H 8 .OH(CH rCH.COOH) 170 Kauffmann B., 16, 686 44, 1136 Trihydroxybenzophenone C 6 H 4 (OH).CO.C 6 H 3 (OH) 2 C 13 H M4 133-134 Michael B., 14, 658 ; 40, 592 ; 46, =1.2 j U.3 A. C. J., 5, 81 311 Dihydroxyphenylbenzoic acid C 6 H 4 (OH).C 6 H 3 (OH)(COOH) >j ..... 270 Schmidt & Sehultz A., 207, 346 40, 911 =1.4; 1.4.6 Morintannic acid (maclurin) .... C 13 H 10 6 .... 200 .... ili., 1049 Diacetylcesculetin C,H 4 4 .Ac,, ) .... 133-134 Liebermann and B., 13, 1591 Knietsch Sordidin (impure) CH 18 ; ? Ci 3 H 10 8 .... 180 Paterno 30, 203 32, 780 210 GT 7 981 "" jj : . 1 - . 1 , ZOl Benzylphenyl oxide Ph.O.CH 2 Ph C 13 H 12 286-287 38-39 Sintenis B., 4, 699 24, 909 V ,1 J * 39 Stadel A., 217, 43 44, 585 Diphenyl carbinol (C 6 H : ,) 2 .CH.OH .... 65 Friedel and Balsohn B. S. [2], 33, 337 38, 559 (benzhydrol) 51 11 ,. .... 68 Zagoitmenny B. S. [2], 26, 452 31, 459 11 H W >T T 297-298 (7J,S) 167-5-1 OS Linnemanu A. 133, 6 iv., 478 Benzylphenol Ph.CH 2 .C 6 H 4 .OH=1.4 5> 314-316 .... Liebmami B., 14, 1844 42, 171 n TI ? 325-330 84 B., 15, 152 42, 727 ,. j J) 320-322 80-81 Perkin and Hodg- .... 37, 723 kinson ,, .... .... ir w * 175-180 84 Paterno B., 5, 288 ; G. I., 26, 702 (4-5) 2,1 )i j* 84 Paterno and Fileti G. I., 3, 121 ,j .... .... " T> J) 84 Rennie .... 41, 34 Pipheuoxymethane CB 2 (OPh) 2 C 13 H,jO 2 294 Liquid Henry A. C. [5], 30, 266 46, 718 Benzyl quinol 6 H 4 .OH.(O.CH 2 Ph) =1.4 n 18* Pellizzari G. I., 13, 501 46, 437 11 1 "" " n ,, .... 121-122-5 Schiff G. 1^ 13, 538 46, 432 BenzhydrylpUenot CHPli(OH).C 6 H 4 .OH=1.4 i? 161 Dobner and Staok- B., 10, 1971 34, 321 mann )T 1 n M Wl Dobner A., 210, 253 42. r>OS 2 K 2 252 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Dihydroxydiphenylmethane CH 2 .(C 6 H 4 .OH) 2 =1.4 ; 1. ? Cj 3 H 12 O 2 .... 158 Beck B., 10, 1838 ; A., 34, 420 ; 36, 194, 318 324 Ethylic a-naphthoate C 10 H 7 .COOEt 309 c. Liquid Hofmann B., 1, 42 vi., 851 ft- n jj 308-309 Heat of hand Vieth A., 180, 320 30,87 Dihydroxybenzhydrol CH(OHXC 6 H 4 .OH) 2 =1.2 ; 1.2 160-165 d. Michael B., 14, 657 40, 592 Ethylic a-naphthylic car- CO(OEtXOC 10 H 7 ) C 13 H 12 O 3 31 Bender B., 13, 702 40, 48 bonate Diacetocaffeic acid (CH : CH.COOHXOAe) 2 C 13 H 12 O 6 .... 190-191 Tiemannand Nagai B., 11, 656 34, 581 =1.3.4 Triacetogallic acid COOH.(OAc) 3 =1.3.4.5 C 13 H ]2 O 8 .... 170 d. A., 163, 210 Benzylidine-mesityl oxide .... CMe 2 1 CH.CO.CH : CHPh C 13 H 14 178-179 (14) Liquid Claisen & Claparede B., 14, 351 40, 422 Methoxy-dimethylnaphtha- C 10 H 5 .Me 2 .OMe ) 68 Cannizzaro and G. I., 12, 393 ; B., 44, 79 lene Carnelutti 12,1575; 16,428 Cinnamenylangelic acid Ph.CH : CH.C 4 H 6 .COOH C )3 H lA 125-127 Perkin J. [1877], 792 31, 408 Ethylic acetobenzylidene Ph.CH : CAc.COOEt Ci 3 H 14 O 3 180-183(17); Claisen B., 14, 347 40, 405 acetate 295-297 (760) p.d. )) ft 295 Crystalline Claisen & Matthews A., 218, 170 46, 443 benzoyltrimethylene CH 2 .CH 2 .CBz.COOEt 280-283 Liquid Perkin B., 16, 2139 4.6, 64 1 1 carboxylate Ethylic phenylparaconate .... CHPhO.CO.CH 2 .CH.COOEt Ci 3 H 14 O 4 a. 360 Erdmann B., 17, 418 46, 906 1 1 Diethyldaphnetin C 9 H 4 2 (OEt) 2 ) .... 72 Will and Jung B., 17, 1084 46, 1142 Diethylcesculetiu C 6 H 2 (OEt) 2 .CH : CH.CO.O ,, .... 109 Will B., 16, 2106 46,67 1 1 Usnetol 179 Paternd G. I. [1882], 231 42, 1080 B., 15, 2241 Diethoxycoumarilic acid C 6 H 2 (OEt) 2 .CH : C(COOH).0 C 1 3 H U O 5 .... 195 Will B., 16, 2119 46,69 1 " 1 Diethyldaphnetilic acid 154 Will and Jung B., 17, 1085 46, 1142 Acetoxybenzylidene diacetate C 6 H 4 .OAc.CH(OAc) 2 =1.2 Ci 3 H 14 O 8 100 Barbier C. R., 90, 37 ; 38, 318, 469 B. S. [2], 33, 53 >i " 11 1 100-101 Perkin A., 148, 205 21, 53, 181 ; vi., 1010 i) " = 1.3 n 76 Tiemann & Ludwig B., 15, 2047 i) =1.4 ) .... 93-94 Tiemauu & Herzfeld B., 10, 65 32, 893 C~H>O. ? P TT O 45 Schulze A. P. [3], 2, 388 vii., 402 ; 26, v - / 28- t - L 32 vy 8 * ^13 14 7 .... 1149 Diethylic hydroxytrimesate OH.(COOEt),.COOH=1.2.4.6 .... 148 Ost J. p. [2], 14, 121 30, 523 Hexylene benzoate C 6 H u .OBz CiaHieOs 275-280 105 Destrem B., 16, 229 Oumenylcrotonic acid C 6 H 4 .Pr.(C 3 H 4 .COOH) 90-91 Perkin 35, 137 .... abt. 90-91 J. [1877], 791 31, 402 Allyl eugenol .. C 3 H 5 .OMe.OC 3 H 3 =1.3.4; or 267-270 Cahours C. R., 84, 151 31, 462 1.4.3 jj Polymer 284-290 )i yj Diethylbenzoylacetic acid .... CEt 2 Bz.COOH CIH M O S .... 128-130 Baeyer and Perkin B., 16, 2128 46, G3 ,i n n j> .... 128-130 Perkin .... 45, 183 Ethylic benzacetyl acetate .... C 13 H 14 4 ? M 276 .... A., 187, 12 ; 204, 180 Isoamylic phenylglyoxylate Ph.CO.COO.(CH 2 ) 2 .Pr/s H 179-182 (40) Claisen B., 12, 630 36, 648 Methylic a-methoxyphenyl OMe(C 4 H 6 .COOMe) =1.2 ) 282 Liquid Perkin 39, 430 angelate 0- 292 Liquid .... 39, 438 Ethylic a-ethoxyphenyl aery- OEt(CH : CH.COOEt) =1.2 51 290-291 Liquid 39, 413 late )) ft' 7! >! J 302-304 Liquid .... 39, 414 Thymoacrylic .... 65-66 Tiemann and Kraaz B., 15, 2070 44, 198 =1.3.4 Ethoxybenzylidene diacetate C 6 H 4 .OEt.CH(OAc) 2 =1.2 Cj 3 H 16 5 .... 88-89 .... A., 146, 372 Methylic trimethoxyoesculate C 6 H 2 (CH : CH.COOMe) 11 .... 109 Tiemann and Will B., 15, 2082 44, 200 (OMe) 2 161 Luck J. [1851], 558 ii., 646 Diethylic ethylmeeonate .... C 5 HO 2 (OEt)(COOEt) 2 Ci 3 H 16 O 7 .... 61 Ost J. p. [2], 23, 439 48, 601 1! 11 11 67 Mennel J. p., 26, 454 44, 656 Heliciu 174 Schiff B., 14, 304 40, 439 175 Piria A. C. [3], 14, 287 iii., 139 11 C 5 H fi (OC fi H,.CHO)(OH) d . 175 Michael C. E., 89, 355 36, 1038 ^5-^j.g^v^gJ-^^.v^J ..._< y^v-u./.J. CHO Phenylic oenanthylate C 6 H 13 .COOPh Ci 3 H 18 o 2 275-280 Liquid Cahours C. E., 38, 257 iv., 178 Hexylic benzoate C 6 H 5 .COO(CH 2 ) 6 .Me J> 272 (770) Freutzch B., 16, 745 44, 1075 Isopropyleugenol C 3 H 5 .OMe.OPr^=1.3.4 ; or )) 252-254 Liquid Cahours C. E., 84, 151 31, 461 1.4.3 Propyleugenol C 3 H 5 .OMe.Pi-= )> 263-265 Liquid 11 11 Isoamylic methoxybenzoate C fi H 4 .OMe.(COOC s H n ) =1.2 Ci 3 H 18 3 a. 300 11 C. E., 39, 256 v., 162 Ethylic tliymylic carbonate C 6 H 3 Me.Pr(O.COOEt) ^ 259-262 Liquid Eichter J. p., 27, 503 44, 1112 Thymolactic acid C 6 H 3 PrMe.(O.CHMe.COOH) j .... 48 Scichlone G. I., 12, 48 42, 849 11 ii 1 74 11 11 Etliylic diethylprotocate- COOEt(OEt) 2 =1.3.4 Ci 3 H ia O 4 56 Herzig M. C., 5, 72 46, 846 chuate Triethoxybenzaldehyde C 6 H 2 (OEt) 3 .CHO 5 .... 95 Will B., 16, 2106 46,68 11 70 Will and Jung B., 17, 1088 46, 1143 Isoamylic orsellinate C 6 H 2 Me(OH) 2 .COOC 5 H n 76 A., 125, 356; 139, 37 Acetyl dimethyl propyl pyro- C 6 H 2 .Pr.(OMe) 2 .OAc )J .... 87 Hofmann B., 11, 331 34,417 gallol Acetyl picamar C n H 15 Ac0 3 J) 80-87 Niederist M. C., 4, 487 44, 1005 Triethoxybenzoic acid C 6 H 2 (OEt) 3 .COOH C 13 H 18 5 134 Will B., 16, 2106 46, 68 11 11 100-5 Will and Jung B., 17, 1088 46, 1143 Syrin^enin .... .... 170-180 Kromayer A. P. v., 652 )> Methyl arbutin Ci 3 Hi 9 7 141-145 Schiff G. I., 11, 99 40, 610 ,, ., )j 168-169 Michael B., 14, 2098 42, 175 .... O : CH(CH.OH) 4 .CH,,0. 168-169 j> A. C. J., 5, 171 42, 174; 44, C 6 H 4 .OMe 347 ; 46, 439 .... i .... 174 Schiff G. I., 13, 538 ; 46, 432; 44. G. I., 12, 460 347 ,, .... ) 175-176 ! B., 15, 1842 11 11 Salicin . . 120 Piria A. C. [3], 14, 257 v., 148 )? 170 Blyth 33, 317 )) 198 Schmidt Gin., 7, 860 (cf. B., 16, 800) C 6 H n O s .OC 6 H 4 .CH 2 OH jj ) SOI Schiff B., 14, 302 40, 439 Iso-amyl ethoxybenzene C 6 H 4 .C 5 H n .OEt C.sH^O 259-261 Liebmann B., 15, 1991 44, 59 Propyl propoxytoluene Me.Pr.OPr a .=l.?.3 )> 235-240 .... Mazzara G. I., 12, 167,333; 42, 838, 110!) B., 16, 243 j> u Me.Prp.OPr0 11 230-235 Liquid i G. I., 12, 505 ; 44, 463 B., 16, 793 Diisopropylcresol C 6 H 2 .Me.Pr0 2 .OH =1.(?) 2 .3 11 251 1. f. m. 11 ! ! J! Dipropylcresol C 6 H 2 .Me.Pr 2 -OH 11 255-260 .... 11 11 11 From dragon's blood 11 256-260 Botsch M. G, 1, 613 42, 210 Ethyltriethenylisovaleric Ci 3 H 20 O 2 280-300 Geuther A., 202, 324 38, 623 acid(>) Triethyl orcin C 7 H 5 Et 3 2 11 265 Liquid Luynes and Lionet C. E., 65, 213 vi., 885 1 195-196 A., 208, 81 11 Benzenyl triethylate C 7 H 5 (OEt) 3 CnHjoOj 220-225 Limpricht A., 135, 88 v., 856 Diethylic diallylmalonate ... (C 3 H 5 ) 2 C(COOEt) 2 Ci 3 H 20 O 4 240 .... Conrad and Bischoff A., 204, 171 ; B., 38, 628 13, 595 254 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diethylic diallylmalonate .... (C 3 H 5 ),C(COOEt) 2 CuHaO, 201-204 c. Perkin .... 45, 538 (225) camphoronate .... C 13 H. 20 O 5 Liquid Hjelt B., 13, 797 38, 669 11 11 67 11 38,670 i) 11 302 Kachler A., 159, 293 Urechitoxin .... Quickly lighted 170-180 Bowrev J. [1878], 974 33 9fil i) "W, iUJL t slowly heated )) 160 Euphorbone .... Hy-x 106-116 Fliickiffer Z. C. [2], 4, 221 vi., 609 .... ui 22 Zeorin.... 230-231 Paterno B., 9, 346 ; G. I., 30, 203 : 32 .... ) 7,281 780 Diethylic trilactate .... C l3 H a O 7 abt. 270 Liquid Wurtz and Friedel A. C., 63, 112 iii., 464 From Angostura bark .... C 13 H 24 a. 266 .... Herzog J., 11, 444 From cajeputol .. 185 .... .... J. [1860], 481 Ethylic salt from petroleum .... C, 3 H 24 O 2 (?) 236-240 u.c. Liquid Hell and Meidinger B., 7, 1218 28, 248 (739) heptylaceto-acetate Me(CH 2 ) 6 CHAc.COOEt C 13 H 24 O 3 271-273 u.e. Liquid Jourdan A., 200, 105 38, 314 ,i (sec) C ? H,,.CHAc.COOEt n 250-260 B. S., 13, 1651 Convolvulinolic acid.... . .... 42-42-5 A., 83, 133 ; 95, 165 Propylene diisovalerate (C 6 H 9 0)0.(CH J ) 3 .0(C,H 9 0) C 13 H 24 4 269-270 c. Keboul A. C. [5], 14, 491 36, 133 ,, divalerate 11 280 Liquid 11 C. R., 79, 169 27, 1154 Ethylic anchoate C 7 H 14 (COOEt)2 325 Liquid Buckton J., 10, 304 i., 290 ; 10, Hi!! 11 i )) d. 260 Wirz A., 104, 265 Diethylic j3-hexylraalonate .... C 6 H 13 .CH(COOEt)., H 251 Lundahl B., 16, 789 Diisovaleryl glycerol C 3 H 6 .(OH)(OC 6 H 9 6) 2 C|sH S4 Os s. 40 Berthelot A. C. [3], 41, 255 v., 980 Undecyl methyl ketone Me.CO.CuHj., C 13 H 26 263 28 Krafft B., 12, 1667 38, 34 11 11 11 CH 3 .(CH 2 ) 10 .CO.Me 191-5 (100) 28 B., 15, 1710 42, 1271 Dihexyl ketone (oenanthone) C 6 H 13 .CO.C 6 H 13 253-254 .... .... A., 117, 81 11 11 11 H 264 30 Uslar and Seekamp A., 108, 182 iv., 178 Octylic isovalerate .... C 4 H,.COO.CH 2 .(CH 2 ) 4 . C 13 H M O, 249-251 .... Zincke A., 152, 6; J., vi., 879 CHMe 2 22, 371 Ethylic undecylate CMe(CMe 3 )j.COOEt 227-230 u.c. Liquid Butlerow B., 12, 1484 38, 230 (umbellulate) .... n 253-255 Stillmann & O'Neill A. C. J., 4, 206 42, 1186 Tridecylie acid CH^CHj^.COOH 236 (100) 40-5 Krafft B., 12, 1669; 15, 38, 34 ; 42, 1706 1272 From seammonin .... C 13 H 2S 40 Keller A. iii., 440 Triisobutylic orthoformate .... CH(O.CH 2 .CHMe 5 ) 3 Cj-jHaA, 220-222 Deutsch B., 12, 118 36, 453 Ethylic diamylic orthofor- CH(O.C 5 H n ) 3 (OEt) n 255 Pinner B., 16, 357 44,731 mate 11 11 11 253-255 11 B., 16, 1647 44, 108!) Diisoamyl glycerol (diamylin) C 3 H 5 (OH)(OC S H H ) 2 272-274 Liquid Eeboul A. C. [3], 60, 5 ii., 884 Propylic orthocarbonate C(OC 3 H 7 ) 4 Cnll a o 4 224-2 c. Rose A., 205, 252 40, 253 Physalin P TT O s. f. 180 Dessai^nes and J. P. [3], 21, 24 iv., 634 CO O 14 6 5 Chautard Ellagic anhydride .... C 6 H ! (OH)/-0-0- N >C 6 H n N) CO/ C 14 H 6 S - 210 Schiff R S. [2], 18, 23 25, 1099 (OH) Isophenanthreiie quiuone .... C 14 H 8 O i . 156 Limpricht B., 6, 533; A., 26, 898 167, 186 Phenanthrene C 6 H 4 .CO.CO.C 6 H. 198 Ostermeyer and B., 5, 934 ; A., 26, 177, 892 i i Fittig 166, 365 11 11 * .... ^ .. 198-200 Japp 37,88 11 i* ... .... w 202 Hayduck and Lim- B., 6, 533 26, 898 pricht " 11 .... w 201 Carnelley 37, 712 11 n .... 203-205 11 i, .... n 204-204-5 Japp .... 37, 85 1? 5J .... C 6 H 4 .C.O 205 Grsebe B., 5, 862 26, 176; vii., 93 i II 1 C 6 H 4 .C.O 1 5, B ... 205 Ja])|> .... 37, 409 JJ )) .... n .... 205-5 37, 663 J j, .... .... 205-206 11 _.. 37, 669 COMPOUNDS CONTAINING THREE ELEMENTS. 1 tNIVEfcfcltl } 255 Name. Constitution. Formula. Boiling Point. Melting Point. X Authority. ^ OW*"^ r Watts' Diet. & J. Ch. Soc. Phenauthrenequinone .... C 14 H 8 3 .... 206 Japp .... 37,85 .... .... 206 B 37, 409 Authraquinone ~) ( .... 270 Goldschmiedt and W. A., 83, 7 40, 824 Schidt 273 Grsebe and Lieber- G. J. C., 1870 vi., 180 i mann f~\f\ / \. M .... 273 Schmidt B., 6, 496 26, 1235 . G J if \ G Q/ G J 5 '* 273-274 C'arnelley .... 37, 712 i i 275 Anschiitz & Schultz G. J. C., 1879 Fittig and Ostmeyer I) 275 Liebermann and v. A., 163, 97 25, 706 Dorp 277 Liebermann B., 8, 972 29, 251 j) .... 276 Auerback 35, 803 j 276 Paul and Cownley C. N., 28, 175 26, 1263 C 6 H 4 -C-0 a. b.p. of Hg Grsebe B., 5, 15 25, 295 XI C 6 H 4 -C-0 Isoanthraquinone c 14 H 8 :o 2 n 211-212 Weber and Zinck6 R, 7, 1156 28, 156 Quiuone from iiitroanthra- .... .... 235 Schmidt B., 6, 496 26, 1234 ceue Diphenylene ketone carbonic C 6 H 4 .CO.C 6 H 3 .COOH C 14 H 8 3 191-192 Fittig and Gebhart B., 10, 2142 ; A., 34, 432; 36, 166 acid 193, 149 Diphenic anhydride C 6 H 4 .CO.O.CO.C 6 H 4 211-212 Anschiitz B., 10, 1884 34,136 i 210-213 B., 10, 326 220 Grsebe and Men- B., 13, 1303 sching Hyd roxy anthraquinone C 6 H 4 : (C0) 2 : C 6 H 3 .OH=2.1 173-180 Baeyer and Caro R, 7, 971 1.2.3 ,. ,, jj 180 Perger J.p. [2], 15, 224 32, 343 > 5? 190 Pechmann B., 12, 2127 38, 323 ., ') n .... 191 Eoemer B., 12, 2128 42, 857 n if ,, u 191 B., 15, 1793 57 11 ,, .... 190 Baeyer and Caro G. J. C., 1874 ., .... 190-191 Liebermann A., 212, 20 42, 856 J >J i) 191 G. J. C., 1876 V ) .) .... 191 Liebermann and B., 10, 611 32, 495 Giessel ,, )l .... 191-193 Liebermann and B., 15, 1804 Hagen 11 H = 1 u .... 202 BOttger & Petersen B., 6,19; J.p. [2], 26, 390 6,367 ., = 1 n .... 268-271 Baeyer and Caro B., 7, 970 28,67 ,, =2.1 ; n.f. 285 Liebermann A., 183, 154, 208 31,609 1.2.4 V " ' B 301 Liebermann and B., 15, 1799 44, 73 Hagen 51 )) n i! M .... SOS Liebermann A., 212, 25, 53 42,857 !' 1) a. 300 ; 323 Claus B., 8, 530 28, 891 ,, .1 302 Simon B., 14, 464 40, 608 ,, .. ,, .... 320 Willgerodt D. P., 217, 238 29, 249 Morindin J5 245 Stein J. p., 97, 234 vi., 838 Acetic anhydride on salicylic .... B 192 Perkin .... 43, 188 acid Diphenylene ketoneoxide car- /co\ C 14 H 8 4 275 .... boxylic acid C,H 4 ^ /C 6 H 3 .COOH Salicylide O.H 14 0, ? 1 95-225 p.d. Schiff A.. 163, 218 25, 819 Dihydroxyanthraquinone C 6 H 3 (OH):(CO) 2 :C 6 H 3 (OH) w .... 191 Liebermann A., 183, 184 31,611 (chrysazin) =3-2-1 ; 1.2-3 or 5 .... 191 Liebermann and. B., 8, 1646 29, 712 Giesel 2-56 ORGAIs T IC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. "" Reference. Watts' Diet. & J. Ch. Soc. Dihydroxyanthraquinone C 6 H 3 (OH) I (CO), I C 6 H 3 (OH) C 14 H 8 4 .... 191-192 Liebermann B., 12, 186 36, 538 (chrysazin) =3.2.1 ; 1.2.3. or 5 (anthrarutin) =3.2.1 ; 1.2.6 .... 280 Schunck & Roemer B., 11, 1176 34,984 , ,, 11 1) H 280 Liebermann & Bolck B., 11, 1616 36, 259 (anthraflavic =4.2.1 ; 1.2.5 a. 330 Schunck & Roemer B., 9, 379 ; B., 30, 89 acid) 11, 971 ,, ,, 11 n.f. 300 Barth and Senhofer A., 170, 103 27, 266 (isoanthraflavic C 14 H 6 (OH) 2 :0 2 .... a. 330 Schunck & Roemer B., 9, 379, 679 30,89 acid) (frangulic acid) n 11 252-254 Faust A., 165, 229 26, 504 ; vii., 534 .1 246-248 Z. C. [21 5, 17 vi., 623 (m-beuzdioxy- 11 291-293 Schunck & Roemer B., 10, 1227 34, 77 anthraquinone) 11 11 .... 291-293 B., 11, 971 36, 68 (qtiinizarin) c 6 H 4 : (co) 2 : c 6 H 2 (OH) a Cryst. from 192-193 u.c. Grimm B., 6, 508 26, 1235 =2.1 ; 1.2.3.6 alcohol - n 1J 11 .... 193-194 Schunck & Roemer B., 10, 555 31, 675 " . ,, after subl. 194-195 u.c. Grimm B., 6, 508 26, 1235 ,, (purpuro- =2.1 ; 1.2.3.5 ,, .... 262-263 Plath B., 9, 1204 31, 87 xanthin) >' 11 IT .... 263 Liebermann and B., 15, 1804 Hagen 11 11 264 Schunck & Roemer B., 10, 173 31, 667 (alizarin) =2.1 ; 1.2.3.4 ,, .... sb. 215 Schunck A., 66, 174 i., 114 ,- n 11 11 11 .... 275-277 0. Fischer B., 8, 676 28, 1021 11 11 11 261(11); Troost C. R., 89, 439 36, 1039 627 (20) . X 11 11 ! .... 275 Liebermann B., 8, 381 11 a. 280 Glaus B., 8, 531 28, 891 11 )1 11 11 289-290 ,, 11 J! B 290 Willgerodt D. P., 217, 238 29, 249 Trihydroxyanthraquinone CTT /f^f\\ * /"") TT//"KTT\ , 1 1 i . IV^V-JJo . V^gXlf \Jlln C 14 H 8 O 5 sb. 150 253 Schuuck & Roemer B., 10, 552 31, 671 ; 32, (purpurin) =2.1 ; 1.2.3.4.6 624 >. . 11 sb. 250 MM Schiitzenberger . 11 ,. 1) .... 251-253 Liebermanu and B., 10, 1619 Plath .. .. .1 M .... 256 Diehl B., 11, 185 (anthragallol) =2.1 ; 1.2.3.4.5 B s.w.in. 290 Seuberlich B., 10, 40 (anthrapurpurin) C 14 H 5 (OH) 3 :0. 2 11 .... a. 330 Schunck & Roemer B., 9, 679 30,300 (flavopurpurin) n ^ a. 330 11 11 11 Tetrahydroxyanthraquinone C I4 H 4 (OH) 4 :0 3 C I4 H 8 6 n.f. 290 Diehl B., 11, 185 34,430 (oxypurpurin) (anthrachrysone) H n.f. 320 Barth and Senhofer A., 164, 113 vii., 86; 25, 101 5 Rufohydroellagic acid .... 1) 300 Rembold B., 8, 1496 29, 592 Ellagic acid .... C 6 H 2 .(COOH)(OH) p TT n Schitf B. S. [2], 18, 23 25, 1099 \\>-CO\ 14 Of~\ /^ J &*-^- i *\\s*-*-/2 ~~~\J / Phenanthrol .... C 14 H 9 .OH CTT f\ 112 Rehs B., 10, 1252 34, 76 Phenanthrone i 14 10 .... 148-149 Lachowicz J. p. [2], 28, 68 46, 82 213 Japp and Streatfield B., 16, 213 43, 33 Anthranol C 6 H 4 : C 2 H(OH) : C 6 H 4 163-170 Liebermann & Topf B., 9, 1201 31, 87 " .... 163-170 Liebermann A., 212, 6 42, 856 Anthrol C 6 H 4 : C 2 H 2 : C 6 H 3 .OH " abt. 200 A., 212, 26, 49 42, 859 '' d 250 w m Linke J D [21 11 227 28, 1197 1) 11 " if* L J' 1 ' 8- Solid Benzostilbene ... " " 244.5 Rochleder A., 41, 93 11 i., 565 cf. C 13 H 10 O " 173 Grgebe and Ebrard B., 15, 1679 Isobeuzil C H 314 Liquid Alexeyeff A., 129, 347 vi., 328 78-81 Ziiicke A., 198, 115 38, 115 11 COMPOUNDS CONTAINING THREE ELEMENTS. 257 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Benzil C 6 H 4 .CHPh.O.CO i i 55 55 5! 55 55 55 55 55 n CH 10 O 3 55 55 55 5, 55 5' 55 55 55 55 14 llA-M 55 346-348 c. 310 360 c. a. 360 sb. 180 90-92 94-95 95 94 92-93 96-97, 95-96 146 155-156 115 220-222 245-246 202-206 p.d. d. at 220 260-270 172 42 127 128 130 85 85-87 93-94 127 127-128 127-128 127-128 127-128 160 160 161 161 194; 194 194 194 194 194-195 194-195 161-102 163 208 140 330 190 130 d. 103-5 Zinin Wittenberg ant Meyer Klinger Limpricht anc Schwaneit Paal Forst and Zincke' Liebermann and Homeyer Brigel Klinger Holering & Zincke Friedlander Fittig & Liepmann Liebermann & Simoi Liebermann Schiller Schroder Gerhardt Anschiitz Ettling Behr and v. Dorp Plascuda & Zinck6 Hemilian Plascuda & Zincke Fittig Dobner 55 Senff Ador Kollarits and Merz Behr and v. Dorp Plascuda & Zincke Ador Kichter Zinck6 Friedlander Roemer Michael loemer& Schwarzer Schnedermann and Winckler ^encki A., 34, 190 B., 16, 502 B., 16, 996 J. [1867], 674; A., 145, 338 B., 16, 638 B., 8, 799 B., 12, 1975 A., 135, 172 B., 16, 996 B., 9, 631 B., 10, 536 A., 200, 15 B., 14, 1264 B., 12, 185 B., 15, 1808 A., 153, 122 B., 12, 1612 A., 87, 73 B., 10, 1882 A., 145, 297 A., 53, 77 A., 145, 299 As., 8, 42 B., 7, 17 B.,6,908; 7,982 B., 11, 838 B., 6, 908 B., 7, 987 B. S. [2], 33, 56 B., 12, 1740 B., 14, 648 A., 210, 277 A., 220, 225 B.,13,320;B.S., [2], 33, 56 B., 6, 539, 540 B., 7, 19 B., 7, 988 B. S. [2], 33, 56 B., 4, 459 B., 4, 510; A., 161, 98 B., 10, 125 B., 10, 534 B., 14, 1259 A. C. J., 5, 81 B., 15, 1040 A., 51, 315 Jp. [2], 25, 283 J. [1863], 315 ; 1870, 686 i., 545 44, 804 44,920 vi., 305, 1107 vi., 333 44, 920 30, 414 32, 493 38, 401 40, 823 36, 537 44,74 i., 557 34, 136 v., 170 27, 471 26, 1225 34, 738 1) 26, 1225 28, 69 38, 470 38, 120 40, 600 42, 508 46, 428 38, 470 27, 471 28,69 38, 470 vii., 177 24, 689 32, 336 32, 492 40, 823 46, 312 42, 975 v., 216 43, 359 Me.c 12 H 7 :c:o 2 C 6 H 5 .CO.CO.C 6 H 5 C 6 H 6 .CO.CO.C 6 H 5 C 6 H 4 .CHPh.O.CO=1.2 i i lsot>euzil Benzhydrylbenzoic anhydridt Fluorenecarbonic acid Fluorenic acid Hydroxyanthrol Dihydroxyanthracene (chrysnzol) (flavol) Oxytolidene .... C 6 H 4 .C 6 H 4 .CH.COOH i i C 6 H 4 .CH 2 .C 6 H 3 .COOH C 6 H 4 :C 2 H(OH):C 6 H 3 .OH C 14 H 3 (OH) 2 Bzp C 6 H 4 .Bz.COOH=1.2(?) = '! =1.2 11 11 =1.3 11 1> = 1.4 '1 11 11 11 C 6 H 4 .C 6 H 4 .C(OH).COOH C 6 H 4 :C 2 H(OH):C 6 H 2 (OH) 2 CO.C c H 4 .O.C 6 H 2 Me.OH Benzoic anhydride .... Benzoylsalicyl aldehyde 1 tlsidicyl aldehyde (parasalicyl) 55 55 55 55 55 55 Benzoj'lbenzoic acid + H 2 O .... 55 55 55 55 55 55 55 . 5) 55 55 55 ,) 55 > 55 55 55 55 55 55 Dipheiiylenegly collie acid .... 55 55 Deoxyalizarin Salicylorcinol oxide .... Desoxyisoanthraflavic acid .... Oreoselone = 1.2 ;(?)., 3 f H 3 (OH).CH s .C 6 H 3 (OH).CO (C H O) O Diphenylic oxalate .... Benzoylhyperoxide (COOPh), 2 L 258 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Gh. Soc. Uiphenic acid (iso-) (C 6 H 4 .COOH) 2 =3.1; 1.? C M H 10 4 193 Schultz B., 17, 469 46, 903 ,, =2.1 ; 1.3 )) 216 Fittig and Gebhanl A., 193, 155 36, 166 ?) =2.1; 1.2 > 226 Fittig & Ostmeyer A., 166, 367 vii., 434 ; 26, 893 ; 32, C59 ,, ,, .... .... )) 228-229 Schultz B., 12, 235 36, 653 =2.1; 1.4 1 n.f. Carnelley 32, 658 ,, =4.1 ; 1.4 d.w.sb. d.w.m. Doebuer B., 9, 272; A., 27, 893 172, 117 ,, J) V n.f. Carnelley .... 32, 658 Dimetoxybenzoid Ci 4 H 10 O 5 130-135 Schiff B., 15, 2588 44, 335 Hydroxybenzoic anhydride,... (HO.C 6 H 4 .CO) 2 0=(1.4) 2 T> abt. 275 Klepl Jp. [2], 25, 525 42, 1294 Hydroxybenzoyl hydroxy- C 6 H 4 (OH).CO.O.C 6 H 4 .COOH )J .... 261 Jp., 28, 193 46, 447 benzoic acid Dihydroxybenzoylbenzoic C 6 H 3 (OH) 2 (CO.C 6 H 4 .COOH) 200 A., 183, 24 acid (resorciuphthalein) =1.3.? Isopinic acid .... p TT f) 148 d. Liechti As., 7, 129 29, 298 Gardenic acid .... ^^It^Hf^i )) 223 p.d. Stenhouse & Groves A., 200, 316 35, 693 ,, ,, .... )> abt. 236 31, 553 Opinic acid OHO 148 Liechti Z. C. [2] 6 196 ; vl., 882 ; .... ^U^^Ifl^S As., 7, 129 29, 296 Tetrahydroellagic acid .... sb. 200-220 d. 230 w.m. Oser and Kalmann W. A., 83, 161 40, 815 Digallic acid .... C 6 H 2 .COOH(OH) 2 .O.CO. C, H, n O Q sf. 110-1 15 d. Schiff A. 170 54 27, 268 C 6 H 2 .(OH) 3 Vy 14 JJ -10 w 9 Diphenylacetic aldehyde CHPh 2 .CHO C 14 H 12 Liquid Zincke B., 9, 1769 31, 460 ) j )J j 315 s. d. Liquid Breuer and Zincke A., 198, 182 38, 118 Isohydrobenzoin anhydride... CHPh.O.CHPh (?) u .... 95 Limpricht and A., 155, 59 ; 160, 25, 138 ; vii., Schwanert 177 172, 174 IJ ) 100-101 Zincke B., 9, 1773 31, 460 > JJ 5> .... 101-102-5 Breuer and Zinck6 A., 198, 159 38, 117 Hydrobenzoin CHPh.O.(CHPh) 2 .O.CHPh(?) M 125 Limpricht and A., 155, 59 : A., 25, 138 ; vii., Schwanert 160, 186 172, 175 1 )) )1 .... 131-132 Zinck6 B., 9, 1773 31, 460 )> )5 .... 131-132 Breuer and Zinck6 A., 198, 158 38, 117 Benzylphenyl ketone (dea- C 6 H 6 .CO.CH 2 .C 6 H 5 )) .... 45 Zinin Z. C. [2], 4, 718 vi., 332 oxybenzoin) j) )J ?) 47 J. p., 33, 35 iii., 185 )) )> )) .... 54-55 Limpricht and A., 155, 59 vii., 172 Schwanert 5J )? JJ )J l 55 Badziszewsky B., 6, 491 ) >I ?) J> ) 310- 315 55 )j B., 8, 757 )> ) 57 Grsebe & Bungener B., 12, 1079 36, 790 > 1) Jl ) )J 58 Limpricht and A., 145, 330 ; J., vi., 332, 1108 Schwanert [1867], 675 Tolylphenyl ketone C 6 H 4 .Me.Bz=l.a 5) .... Liquid Behr and v. Dorp B., 7, 19 27, 471 ,j .... .... j) >1 305-306 u. c. Liquid Plascuda & Zinck6 B., 6, 908 26, 1225 315-316 c. (768) j> )J T) 306-307 1. 18 Ador and Eilliet B., 12, 2301 .... .... )> ) 314-316 c. Liquid Senff A., 220, 225 46, 428 (745) ,, .... =1.3 1) 305-311 Liquid Ador and Eilliet B., 12, 2301 ) = 1.4 1) 307-312 Liquid ZinckS A., 161, 108 ; B., 24, 689 4, 514 ,, )) )) 310-312 Solid Radziszewsky B., 6, 810 27, 470 ,, ,, .... ') )) 313-314 u.c.; Solid Plascuda & Zincko B., 6, 908 26, 1225 326-5 c. )> )) )> ?) 311-312(720) 50 Ador and Rilliet B., 12, 2299 M ,, .... ) J M 318-321 51 J5 1) ,, ,, 5) 54 Plascuda & Zincke B., 7, 982 28, 69 ,, j, J )) II 305-315 56-5-57 Kollarits tand Merz B., 6, 538 26, 1035 > )> J) 57 Behr and v. Dorp B., 7, 19 27, 471 > ) .. )? )> 55 ; 59-60 Richter Tabellen COMPOUNDS CONTAINING THREE ELEMENTS. 259 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts Diet. & J. Ch. Soc. Tolylphenyl ketone C 6 H 4 .Me.Bz=1.4 C 14 H 12 O a. 300 Solid Grucarevic & Merz B., 6, 1244 Dihydroaiithranol C 6 H 4 .CH 2 .C 6 H 4 .CH(OH) 76 Perger J. p. [2], 23, 137 40, 607 ,, >1 jj 80 Roemer B., 15, 224 42, 974 Dipheuylacetic acid CHPh s .COOH C U H 12 O 2 .... 145-146 Symonsand Zinck6 A., 171, 122;B., 27, 162 6, 1189 .... .... u LfiS Jena B., 2, 385; A., vi., 306 ; vii., 155, 84 158 11 ) .... 148 B. S., 33, 59 Benzylic benzoate CjHj.COO.CHj.CJI, ) 300 Busse B., 9, 831 30, 640 ., i) 303-^04 Kraut A., 152, 159 i, 345 20 Canizzaro J,, 7, 585 i., 553 Phenoxyacetophenone Benzoin Ph.CO.CH5.OPh Pliysical isomer 72 98 Mohlau Zincko B., 15, 2498 A., 198, 115 44, 332 38, 115 H 120 i., 559 Constitution not definitely >l 133-134 Linipricht and A., 160, 177 ; B., 26, 138 settled T 135 Schwanert 4, 337 ) 137 ji u )1 137 > Tl Jena and Linipricht 11 A., 155, 89 J) vil., 169 Benzyl salicylaldehyde C e H 4 .OCH,Ph.COH=1.2 >1 a. 360 46 Perkiu A., 148, 24 21, 122; vi., 1009 Methoxybenzophenone C 6 H,.Bz.OMe=1.4 M .... 61-62 Rennie 41, 227 u )) .... 61-62 .... n Uresylic benzoate (benzoyl- C 6 H 4 .Me.OBz=1.2 n Liquid Engelhardt and Z. C. [1869], 621 cresol) Latschinoff )t )1 !' 11 1 ^) Liquid Kekule B., 7, 1007 11 r> >' J) 11 i a. 360 Liquid Buff B., 4, 378 24,531 11 V >J =1.3 290-300 38 Engelhardt and Z. C. [1869], 622 vi., 507 Latschinoff 11 "* = 1.4 70 D n Z. C. [1869], 622 vi., 506 1, 11 1) )J 11 70 Guareschi G. I., 4, 22 27, 584 1, 1) 70-70-5 Buff B., 4, 378 vii.,393;24,f)31 Phenylic toluate C 6 H,.Me.COOPh=1.4 H 71-72 Kraut J. [1858], 406 ; v., 864 I. D. Gottingen, 1854 Benzylbenzoic acid C 6 H 4 .CH,Ph.COOH= 1 .3 M 107-108 Senff A., 220, 225 46, 428 ,, =1.2 ji .... 114 Rotering & Zincke B., 9, 633 30, 414 ' 11 11 =1.4 ., 154-155 Zinck6 B., 4, 513 24, 689 Tolylbenzoic acid Me.C 6 H 4 .C 6 H 4 .COOH > .... 176 Carnelley J. [1877], 385 32, 658 =1.2 ; 1.4 11 i) ?J H 179-180 11 37, 707 ! Jl =1.4; 1.4 i 244 d. J. [1877], 384 32, 658 Diplienol ethylidene CH 2 : C(C 6 H 4 .OH) 2 i .... 280 p.d. ter Meer B., 7, 1203 28, 158 Hydroxyhydranthrauol C 6 H 4 .CH(OH).C 6 H 3 (OH).CH 1 H 99 Liebermann A., 212, 15 42, 856 =2.1; 1.2.3 n )> 5 It 99 Liebermann and B., 10, 609 32, 494 Giessel Diphenylglycollic acid (ben- CPh.(OH).COOH C 14 H, 2 O 3 120 Zinin A., 31,329 i., 546 zilic) 11 >1 n ISO Jena B., 2,384; A., 155, vi., 306; vii., 157 77 Plienylmandelic acid Ph.CH(OPh).COOH 108 Meyer and Boner B., 14, 2393 42, 196 Benzylsalicylic acid .... C 6 H 4 .(OCH 2 Ph).COOH=1.2 ;i 75 Perkin A., 148, 28 21,122;vi..lOO(i Benzhydrylbenzoic acid C 6 H 4 .CHPh(OH).COOH= 1 .4 ;i 164-165 Zincku B., 4, 512; A., 161, 24, 689 102 11 11 = )) 121 Senff A., 220, 225 46, 428 Beiizylhydroxybenzoic acid.... C 6 H 3 .CH 2 Ph.OH.COOH 11 139-140 Patenid and Fileti G. I., 3, 121, 251 27, 372 Dihydroxyphenyltolyl ketone 11 200 .... A., 179, 196 Orcinyl benzoate C 7 H 6 (OHXOBz) 11 88 Rasinski J. p. [2], 26, 53 42, 1289 2 L 2 260 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Tetroxyditolyl anhydride ... Saliretone .C 6 H,.Me.OH o/l XJ 6 H 2 .Me.OH Ci 4 H la O 8 .... 232 121-5 Nietzki Oiacosa A., 215, 125 ; B., 11, 1281 J. p., 21, 221 44, 467 ; 34, 869 38, 716 Dimethylic naphthalate Diacetoxynaphthalene Oroselone C 10 H 6 .(COOMe) 2 =V 2 ; C 10 H 6 (OAc) 2 C 14 H 12 O 4 )? 102-103 129 756' Behr and v. Dorp Weber Heut A., 172, 273 B., 14, 2209 A., 176, 73 27, 1168 48, 205 28, 772 C 6 H 4 (OH)O C 6 H 4 OCH COH 177 Hlaaziwetz and Wei- A., 174, 67 28, 257 190 del Schnedermann and A., 51, 321 Ethylie phthalylaceto-acetate Gardeuin c 6 H 4 :(co) 2 :cAc.cooEt C 14 H 12 5 124 155 Winkler Fischer and Koch Fliickiger B., 16, 651 P. J. [31 7, 589 ; 44, 806 163-164 Stenhouse & Groves A., 98, 316 A., 200, 311 31, 552 ; 35, (590 Dibenzyl oxide Benzyl phenyl carbinol Tolyl phenyl carbinol Benzyl tolyl oxide (benzyl cresyl oxide) u ii 11 '> 11 u " 11 Benzyl methoxybenzene >' 11 11 11 Ditolyl oxide (dicresyl oxide) j j) i Tolyl phenol (C 6 H 6 .CH 2 ) 2 C 6 H 5 .CH 2 .CHPh.OH C 6 H 4 .Me.(CHPh.OH)=1.4 C 6 H 4 .Me.O.CH 2 Ph.=1.2 =1.3 )> > =1.4 C 6 H 5 .GH 2 .C 6 H 4 .OMe C 6 H 6 .CHj.C 6 H 4 .OMe (Me.C 6 H 4 ) 2 =(1.3) 2 =(1.4), HO.C 6 H 4 .CH 2 .C 6 H 4 Me C 14 H 14 5) ) ) )) )) 5) ) 300-315 285-290 300-305 300-305 abt. 305(760) ; 170(10); 155 (4) 304-308 abt. 300 284-288 220-270 250-255 Liquid 62 (42 2 ) 52-53 Liquid 43 43 41 1. very low temp. Liquid 50 Liquid Cannizzaro Limpricht and Schwanert Staedel Orth Staedel Paternd Rennie Paternd Gladstone & Tribe 11 ji Mazzara A., 92, 115 A., 155,62; 174, 332 A., 194, 265 B., 14, 898 ; A., 217, 45 A., 217, 46 B., 15, 1129 B.,14,898;A.,217, 44 G. I., 2, 1 ; J. [1871], 468 ; [1872], 405 G. I., 1, 589 G. I., 9, 421 i., 579 vii., 173 40, 724; 44, 585 44,586 42, 1204 40, 724 ; 44, 585 25, 703 41, 37 25, 241 41, 13 u 38, 161 Benzyl cresol .... C 6 H.,.Me.OH CH Ph. 1 4 ? (8-10) 240 (40) Liquid Pateruo & Mazzara G. I., 8, 303 36, 315 260-265 (40) J. [1878], 591 Isohydrobenzoin .... +aq. 11 -- 11 u 11 .... .... j, .... .... Hydrobenzoin C 14 H 13 (OH) 2 i J Jl JT Ci4H 14 Oj ji u 11 i 11 95-96 96 119 119-5 119-1SO 100 116 Forst and Zincke Limpricht and Schwanert Wallach Ammann Forst and Zinck6 Glaus Hermann A., 182, 279 A., 160, 177 J.p., 25, 262 Z. C. [2], 7, 83 ; A., 168, 75 A., 182, 279 A., 132, 75 30, 636 vii., 172 ; 26, 138 42, 853 24, 385 ; vii., 171 30, 636 vi., 333 112-122 Limpricht and A., 145, 345 vi., 1108 122 Schwauert Z. C. [2], 3, 684 vi., 333 129 Church P. M. [4], 25, 522 a. 300 130 Zinin Z. C. [2], 4, 718 ; vi., 333 ; iii., 132 Limpricht and A., 123, 125 A., 160, 177 185 vii., 172 ; 25, 115-146 Schwanert 138 132 Jena and Limpricht A., 155, 89 vii., 169 132-5 Ammann A., 168,71; Z. C., vii., 171 ; 24, 184 Forst and Zincko [2], 7, 83 A., 182, 273 384 30, 635 134-135 Grimaux B., 2, 281 11 11 138 Paal B., 16, 637 COMPOUNDS CONTAINING THREE ELEMENTS. 261 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diphenoxyethane PhO.CH 2 .CH 2 .OPh C I4 H M O t .... 95 Lippmann C. C. vi., 917 .... 98-5 Burr Z. C. [2], 5, 165 Diphenolethane HO.C 6 H 4 .(CH 2 ) 2 .C 6 H 4 .OH 185 Kade B., 7, 239 CH 3 .CH(C 6 H 4 .OH) 2 122 Fabini B., 11, 283 34, 431 a-Dimethoxydiphenyl C,H 4 (QMe).C 6 H 4 (OMe) ., 310-320 Earth A., 156, 99 24, 123 a- (iso-) .... 146 P- ,, crystalline Barth and Schredei B., 11, 1337 Acetyl dimethyl (or ethyl) C 10 H 6 Me 2 .OAc or C 10 H 6 Et. .... 77-78 Cannizzaro and G. I., 12, 393 ; 44, 79 mtphthol OAc Carnelutti B., 12, 1575 ] )ihydroxytolyl oxide 0(C 6 H 3 .Me.OH) 2 C 14 H 14 O 3 .... 100-110 d. Biedermann B., 6, 327 vii., 394; 26, - 898 Terebenzic acid C 14 H 14 O 4 sb. 100 169 Cailliot A. C. [3], 21, 31 v., 723 Hydro (para) oxybeuzoin ... 222 Herzfeld B., 10, 1268 34, 65 Ethylic piperate CH 2 : O 2 : C 6 H 3 .C 4 H 4 .COOEt 70-72 A., 152, 31 ,, j 77-78 J. [1857], 414 1 acid C,,H, n O r (?) 200 J. [1862], 466 Curcumin 20 20^6 \ / CifiH-ijO. (i) amorphous 140 Gajewsky B., 5, 1103 16 14 4 \ / (C 4 H 4 0) n (?) crystalline 172 B., 3, 625 C H O non. subl. 165 Daube B., 3, 611 C 6 H 3 . (CH.C 6 H 5 .COOH). 177-178 Jackson and ]Venk< B., 14, 487 ; 15, 40, 611 ; 42, OMe.OH =1.3.4 1761 ; A. C. J., 1108 4, 77, 360 a-Salylie acid 2C,H 6 O.,.H 2 O CnH 14 O 5 .... 100-101 Stadeler As., 7, 165 vii., 1073 Dimethyl rhamnetiu 156-157 A., 196, 318 210 Jobst and Hesse A., 199, 44 38, 327 Diphenylic orthoxalate PhO.C(OH) 2 .C(OH) 2 .OPh CuH 14 O a 150-180 p.d. 123-124 Claparede & Smith 43, 360 > .... 126-127 Staub and Smith 45, 301 Pyrousnetic acid .... ,, .... 183-186 Paternd G. I. [1882], 231 ; 42, 1081 B., 15, 2240 Hydrogardenic acid 190 Stenhouse & Groves A., 200, 321 35, 695 Tetramethylic pyromellitate (COOMe) 4 =1.2.4.5 C 14 H 14 3 138 Baeyer A., 166, 339 26, 756 ; vii., 785 prehnitate .... =1.2.3.5 104-108 A., 166, 332 Ethoxydimethylnaphthalene C lu H 5 .Me 2 .OEt C 14 H 16 90 Cannizzaro and G. I., 12, 393; 44, 79 Carnelutti B., 16, 428 v 280 (40) ; Hodgkinson 33, 498 J? 340-350 (760) Diethoxynaphthalene C 1() H 6 .(OEt) 2 C 14 H 16 O 2 104 Liebermann and B., 15, 1428 42, 1212 Hagen Action of KHO on anethol.... 65 Landolph C. R., 81, 97 ; B., 29, 246 ; 38, /^TT 13, 147 385 Ethylic benzoyltetramethyl- /VyJjL 2 \ \/""1TT V'-DZl \J\J\JS-jL )\ /V_/Xlo C' 14 H 10 3 59-60 Perkin B., 16, 1791 44, 1084 ene carboxylate CH 2 From crude butyl glycol tj 160-165 (15) Wurtz C. R., 97, 473 46, 169 Ethylic benzylidene malonate CHPh I C(COOEt), C 14 H 16 4 190-193 (17) Claisen B., 14, 348 40, 405 ., >J 215-217 (30) Liquid Claisen and Crismer A., 218, 129 46, 444 Curcumin dihydride (CH 2 .C 5 H 6 .COOH).OMe.OH .... near 100 Jackson and Menke A. C. J., 4, 360 ; 44,481 =1.3.4 B., 16, 572 (. 'ubebic acid (C H O ?) 45 Schulze A. P. [3], 2, 388 vii., 402 ; 26, j) 1149 1 340-350 A., 201, 171, 180 Ethylic phenylacetosuccinate COOH.CHAc.CHPh.COOEt C, 4 H 16 5 132-5 Weltner B., 17, 72 46, 746 Propiohomoferulic acid C 6 H 3 (CH : CMe.COOH) 128-129 Tiemannand Kraai B., 15, 2060 44, 200 (OMe)(OC 3 H 5 O) =1.3.4 Physalin 180-190 J. [1852], 670 Acetoxytoluic aldehyde + Me.OAc.CH(OAc) 2 =1.4.5 C 14 H 16 6 94 Schotten B., 11, 786 34, 878 acetic anhydride Triacetoxyisoxylene Me 2 .(OAc) 3 =1.3.5.6.2 or 4 99 Fittig and Lieper- A., 180, 41 29, 920 niann Diacetoxythymoquinone C 6 Pr a Me.(OAc) 2 : 0., 81 Zincke B., 14, 95 40, 596 " = 1.4.6. (0, 262 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. A eetoxy methoxybenzalde- OMe.OAc.CH(OAc) 2 =1.4.5. C 14 H 16 7 69-70 'ieinann and Miiller B., 14, 1995 42, 53 hyde -{-acetic anhydride ;. =1.2.4 (or 5) 88-89 Tiemannand Nagai B., 8, 1143 29,78 Ostruthin (C H O ) 115 Gorup Besanez A., 183, 321 ; B., 31, 717 ; 27, 7,564 907 Cumenylangelie acid C 6 H 4 .Pr.(C 4 H 6 .COOH) C 14 H 18 O 2 123 Perkin J. [1877], 791 31, 403 Ethlic methylbenzyl aceto- Ph.CH 2 .CMeAc.COOEt C 14 Hi 8 O 3 287 Liquid Conrad A., 204, 180 ; B., 34,732 acetate 11, 1055 Methylthymoacrylic acid .... Me.Pr.OMe.(CH : CH. 141 Kobek B., 16, 2105 46, 57 COOH) =1.4.3.6 Diethylic benzylmalonate .... C 6 H 5 .CH 2 .CH(COOEt) 2 C 14 H 19 O 4 203 Liquid Conrad B., 12, 752 36, 707 300 A., 204, 175 Dipropylic terephthalate C 6 H 4 (COO.Pr) 2 =1.4 V 31 Berger B., 10, 1742 34, 152 Diisopropylic C 6 H 4 (COO.Pr0) 2 =1.4 H 55-56 Diethylic xylenedicarbonate C 8 H 4 (CH 2 .COOMe) 2 =1.4 57-5-58 Klippert B., 9, 1768 31, 468 Maynos resin.... .... _ abt. 105 Lewy A. C. [3], 10, 380 iii., 85H Benzoylbenzoic anhydride .... (C 6 H 5 .CO.C 6 H 4 .CO) 8 C,,H I3 5 120 Pechmann B., 14, 1866 42, 184 Methoxydiacetoxypropyl ben- C < H 3 .Pr.OMe.(OAc) 2 82-5-83 M. G, 4, 185 zene (picamar diacetate) Filix acid 160 A., 54, 119 ; 143, 279 Olivil +H 2 O 118-120 A., 6, 31 ; 54, 68 iv., 200 .... 119-120 Amato G. I., 8, 83 ; B., 34, 681 11, 1251 Tetramethylic isohydropyro- (COOMe), =1.2.4.5 C 14 H 18 O 3 .... 156 Bseyer A., 166, 339 26, 756 ; vii., mellitate 785 Saccharovanillie aeid C, 4 H 18 O,, .... 211-212 Tiemann & Reimer B., 8, 515 28, 1199 Isoamylic hydroeinnamate ... C < H 5 .CH 2 .CH 3 .COOC 5 II 11 C^H.^ 291-293 c. .... Erlenmeyer A., 137, 335 ; J., vi., 469 19, 367 Phenylic caprylate C 7 H ls .COOPh 300 C. R., 39, 257 Isobutyl eugeuol (Cttj-CH : CH 2 ).OMe.OC 4 H 9 272-274 Liquid Cahours C. R., 84, 151 ; 31, 462 = l.a4 or 1.4.3 J. [1877], 581 Pyrophotosantonie acid 94-5 Sestini and Danesi G. I. [1882], 83 42, 627 Isoamylic phloretate.... C 8 H 8 (OH)(COOC 5 H n ) C 14 H 20 O 3 a. 290 Liquid Hlasiwetz A., 102, 154 iv.,492 Ethylie carvacrol glyollate.... C 6 H 3 Me.Pr.(O.CH 2 .COOEt) 289 s. low temp. Spica G. I., 10, 340 38, 889 =1.46 tbyrool = 1.4.5 ,, 290 1. f. m. V Helleboretin a. 200 Huseniann and A., 135, 60 vi., 695 Marine Autiariii O TT O 220 '6 A., 28, 304 ; Z. C. [1869], 351 Tetraethylie ethylene tetra- (COOEt) 2 .C'.C(COOEt) 2 C 14 H,, O S 210 (90) Conrad B., 13, 2161 42, 11 88 earboxylate ,1 ., ji 325-328 d. 57-58 Conrad & Guthzeit A., 214, 76 44, 46 Methoxydiisopropyl toluene MePr3 5 .OMe =1.(?) 2 .3 C^H^O 242-245 Liquid Mazzara G. I., 12, 505 ; 44, 463 B., 16, 793 Diisobutyl quinol C 6 H 4 (O.CH,.CHMe 2 ) 2 =1.4 C^ILjA 262 crystalline Schubert M. C., 3, 681 44,60 ? 128 Z. C. [1867], 632 Diethylic ?-ate .... CnH,^ 247-250 Ballo B., 14, 336 ? .... 257-260 A., 215, 42 Triethylic allylethenyltri- (COOEt) : ,CH.CH(C 3 H 5 ). c lt a K o t 282-283 .... Hjelt B., 16, 333 44, 656 carboxylate COOEt or (COOEt) 2 .C(C 3 H 5 ).CH 2 . COOEt aeetotriearballylat CAc(CH,.COOEt) 2 .COOEt GtJi^O. 280-300 Liquid Miehle A., 190, 323 34, 491 Oxypeucedanin .... ,, 140 A., 176, 78 ; J. [1849], 476 Triethylic acetylcitrate C 3 H 4 .OAc.(COOEt) 3 C 14 H 2S O 8 288 c. 1. 20 Wislicenus A., 129, 193 vi., 473 Diethylic succino-dilactate .. C 2 H 2 (C 3 H 4 O 2 ) 2 . (COOEt ) 2 250-270 Wurtz and Friedel J. [1861], 378 iii., 462 )i D .... 300-304 (7:><> Wislicenus A., 133, 262 vi., 773 280 1 COMPOUNDS CONTAINING THREE ELEMENTS. 263 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Tetrethylic acetylenetetra- (COOEt)2.CH.CH(COOEt) 2 CuH^Os 305 p. d. 75 Conrad and Bischoff B., 13, 601 38, 629 carboxylate ) >? ! 305 p. d. 76 Conrad and Guthzeit A., 214, 68 ; B., 44, 46 ; 46, 297 16, 2631 Dipropylic diacetyldextrotar- [CHCOAcJ.COOPra].,. >1 313 31 Anschutz B., 14, 2789 42, 831 tarate )! II i 313 31 Pictet B., 15, 2243 Lactucone (see 04011,5503) .... C^O 296 Francuimont and B., 12, 10 36, 469 Wigman O TT O 176 Liquid v., 450 Myristolic acid 14 24^-^2 >I 12 Masino A., 202, 175 ; G. I., 38, 460 10, 72 Lichenstearic acid .... C, 4 H M 3 .... abt. 120 Schnedermann and A., 55, 150 iii., 588 Knop Diethylic camphorate C 8 H 14 (COOEt) 2 C 14 H 244 285-287 Liquid Malaguti A. C., 64, 152 i., 731 paracamphorate ... H )1 270-275 Chautard A., 127, 124; J., 16, 395 Triethylic propylethenyl- CHPr/3(COOEt).G'H(COOEt)., C U H 2 .,O 6 276-278 Liquid Eoser A., 220, 271 46, 423 tricarboxylate i) CH 2 (COOEt).CPr(COOEt) 2 j) 280 p. d. Liquid Waltz B., 15, 608 ; A., 42, 948 ; 44, 46 214, 58 Tetraethylic citrate C 3 H 4 .OEt(C(X>Et^ C 14 H e4 0- 290 d. Liquid Conen B., 12, 1654 38, 36 Hexylpentylacrylic aldehyde Me(CH 2 ) 5 .CH : qCOH). C 14 H 26 O 277-279 ; 1. 20 Perkin B., 15, 2804, 43, 49, 51, 81 (CH 2 ) 4 .Me 276-280 ; 2806 ; 16, 1034 275-280 f ? .... )) 240 .... Z. C. [1870], 76 Hexylpentylacrylic acid Me(CH 2 ) 5 .CH:C(COOH). C U H 26 O 2 275-280(250); Liquid Perkin B., 15, 2803 ; 16, 43, 48, 62 (CH 2 ) r Me 270-290(200) 211 IVfeiithylic butyrate C 3 H 7 .COO(C 10 H 19 ) n 230-240 A., 120, 351 iii., 881 Ethylic diisobutylacetoace- (CHMej-CH^CAc-COOEt C J4 H 26 O 3 250-253 Mixter B., 7, 501 27, 784 tate Ethylic octylacetoacetate .... CHAc(C 8 H J7 ).COOEt ) 280-282 u. c. Liquid Guthzeit A., 204, 2 38, 872 (Enanthylic anhydride [CH 3 .(CH 2 ) 5 .CO] 2 H 268-271 Liquid Mehlis A., 185, 371 34, 135 Diethylic sebate C 8 H 16 (COOEt) 3 C M H 26 O 4 307-308 3-5 Nelson C. N., 32, 298 ; 29, 318 J. [1876], 576 ., ) u 307-308 c. .... Perkin .... 46, 518 ,, .... ... j> 308 Carlet C. R, 37, 129 29, 318 11 15 >1 .... 9 Eedtenbacher A., 35, 193 v., 214 ,, heptylmalonate .... CjH 15 .CH(COOEt).> )> 263-265 Venable B., 13, 1651 Diisoamylic succinate COOC 5 H n (CH 2 ) 2 : COOC 5 H n yj 289-9 c. (728) 1. 16 Guareschi and B., 12, 1699 Debzanna Acetyl diruannitan C^H^AcO.o C l4 H 26 O n 120 Grange C. E., 68, 1326 vi., 806 Hexylpentylacryl alcohol .... Me.(CH 2 ) 6 .CH : qCHs-OH). C 14 H 28 282-290 ; 1. 20 Perkin B., 15, 2810 ; 16, 43, 53, 55, 63, (CH 2 ) 4 Me 280-283 ; 211, 1029 68 280-290 ; 280-283 Myristic aldehyde .... 168-169 (22) ; 52-5 Krafft B., 13, 1415 38, 867 214-215(100) Heptyl pentyl acetaldehyde Me.(CH 2 ) 6 .CH(COH).(CH 2 ) 4 . 266-268 29-5 Perkin B., 16, 1030 43,71 Me Duodecyl methylketone Me.CO.(CH 2 ) n Me i> 205-206 (100) 33-34 Krafft B., 15, 1708 42, 1272 From cenauthylic aldehyde.... .... )i 220 d. Liquid Tilley J., 1, 566; A., 43,46 67, 111 Auiyl valerone 208-209 Frohlieh, Geuther, A., 202, 301 38, 623 and Looss Duodecylic acetate .... CH 3 (CH 2 ) 10 .CEL.OAc CnH^O,, 150-5-151-5 Liquid Krafft B., 16, 1719 44, 1076 (15) Octylic caproate CH 3 .(CH 2 ) 4 .COO.(CH 2 )..CH 3 u 268-271 Zinckti A., 152, 18 vi., 697, 879 264 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Heptylic oenanthylate CH 3 .(CH 2 ) 5 .COO.(CH 2 ) e .CH 3 C 14 H 28 O 2 270-272 (760) Liquid Cross B., 10, 1602 32, 127 276-278 c. .... Perkin 45, 503 Ethylic laurate C n H, 3 .COOEt 264 p. d. s. 10 Gorgey A., 66, 303 iii., 475 269 (750) .... Delffs A., 92, 278 ; J., 7,26 Heptylpentylacetic acid Me.(CH 2 ) 6 .CH(COOH) (CH 2 ). 300-310 Liquid Perkin B., 16, 1031 43, 74 Me Myristic acid .... 49 Reichardt A. P. [3], 10, 339 33, 518 49 Fehlin <* A., 53, 399 i., 1064 52 Fliickiger A. P. [3], 6, 481 30, 644 CH 3 .(CH 2 ) ]2 .COOH " 248 (100) 53'5 Krafft B., 12, 1669 38, 34 ?> 248 (100) 53-8 B., 15, 1707 42, 1272 " 53-54 Masino G. I., 10, 72 38 460 i) 53-54 Heintz 53 '8 Schlippe J., 11, 303 " H 53 Oudemans J., 13, 323 Jl 53-5-54 Marasse B., 2, 361 " 53'8 Playfair A., 37, 152 53'8 A., 53, 399 i., 1064 M o C 13 Ho 7 .COOH 53'8 Heintz P. A. ; J., 7, 456 iii., 1071 " 54 Reichardt A. P. [3], 10, 339 32, 518 " 54 '5 Fliickiger P. J. T. [3], iv., 36 28, 91 Ethylic diisoamoxalate C(C 5 H n ) 2 (OH).COOEt C 14 H 28 3 262 Liquid Frankland & Duppn P.R.S.; A., 142, 9 iv., 276 Hydroxymyristic acid M 51 Miiller B., 14, 2480 42, 497 Isobutylic diisobutylglyoxy- CH(O.CH,,Pr/3) 2 .COOCH 2 Pr0 C 14 H 28 4 250-252 .... Pinner and Klein B., 11, 1478 36,47 late Tetradecyl alcohol CH 3 .(CH 2 ) 12 .CH 2 .OH C 14 H 30 167 (15) 38 Krafft B., 16, 1714 44, 1076 Heptylpentylethyl alcohol .... Me.(CH 2 ) 6 .CH(CH 2 .OH). J) 270-275 s. 10 Perkin B., 15, 2811 ; 16, 43, 56, 76 (CH 2 ) 4 Me 1032 From lactarius piperatus .... Alcohol T) 36-37 Bissinger A. P. [3], 21, 321 46, 480 Diisobutyl pinacone .... [CMe(OH).CH 2 .CH 2 .CHMe 2 ] 1 C 14 H 30 O 2 240-260 1.-13 Rohn A., 190, 311 34, 486 ,1 ,, .... 268 30 Purdie 39, 468 Butyrone CPr 2 (OH).CPr 2 (OH) ,, abt. 260 68 Kurtz A., 161, 215 35,411 ; vii.,229 Ethylidene oxyisoamyl C 4 H 3 (OC 5 H U ) 2 C I4 H 30 O 3 226 Laatsch A., 218, 13 44, 788 alcoholate Amylic dibutylic orthoform- CH(OC 4 H, J ) 2 (OC 5 H 11 ) 230-235 Pinner B., 16, 1647 44, 108.9 ate Pro])ylic diamylic CH(Oq,H n ) 2 (OPr) n 254-255 H Pentamethylethol hydrate .... 2(CMe 3 .CMe 2 OH) + H 2 O C 14 H 34 O 3 see p. 184 75-76 Eltekoff B., 11, 412 34, 482 M begins 100 83 Butlerow A., 177, 176 28, 1248 . ,, .... 83 . Kaschirski C. C. [1881], 278 42,37 Fluorantheue quinone C 6 H 4 .CH.CO=1.2 C, H a O 18S Fittig & Liepmann A., 200, 3 38, 401 1 / 1 C 6 H 3 CO=1.2.3 ,. .... 188 Fittig and Gebhard A., 193, 149 36, 166 ., ^ 189 Goldschmiedt B., 10, 2029 34, 15.') Phenanthrene quinone car- C lj H 4 .CO.CO.C (j H 3 .COOH C I5 H a 4 a. 315 A., 196, 14 boxylic acid /3-Antliraquinone carboxylic G e H 4 :(co) 2 :c 6 H 3 .cooH H 278-280 Ciamician B., 11, 273 34, 43!) acid J' ,, n 280 Liebermann A., 183, 168 31, 610 V )) 280 B., 8, 972 29, 251 V )> jj .... 280 Hammerschlag B., 11, 82 34, 323 . M 282 u. c. Weiler B., 7, 1186 28, 152 V 282-284 Liebermann and B., 8, 248 28, 763 v. Rath V 15 B 283-284 Fischer B., 7, 1196 ,. 285 Liebemiann and B., 13, 49 38, 400 Bischoff Hydroxyanthraquinone car- C 6 H 4 :(CO) 2 :C 6 H 2 .OH.COOH C 15 H S O. 260 Haniinei-sehlag B., 11, 83 34, 323 boxylic acid = 1.2.3.4 (?) COMPOUNDS CONTAINING THREE ELEMENTS. 265 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Purpuroxanthin carboxylic C 14 H 5 (OH) 2 :0 2 .COOH C 16 H 8 6 2S1 Schunck & Roemer B., 10, 173 33, 423 acid (munjistin) ,, > J5 55 231 a a B., 10, 791 32, 788 a 11 n 55 231 a a 31. 667 11 55 5) 225-230 a 11 31, 669 Alizarin carboxylic acid 55 55 305 Hammerschlag B., 11, 86 34, 323 e-Purpurin cf. B., 10, 790, 2166 180 Rosenstiehl C.R.,83,560,827; 31, 209 5 84, 559 Purpurin carboxylic acid C 14 H 4 (OH) 3 : 2 .COOH C 15 H 8 7 218-220 Liebermann & Plath B., 10, 1618 34,77 (pseudopurpurin) Benzylidene phthalyl c 6 H 4 : (CO), : CHPh=i.2 C 15 H 10 O 2 98-99 Gabriel & Michael B., 11, 1017 34,735 Phenylcoumarin C 5 H 4 .CH : CPh.CO.O=1.2 1 1 55 139-140 Oglialoro G. I., 9, 428 ; J. 38, 164 [1879], 731 a-Phenanthrene carboxylic C 6 H 4 .CH . CH.CfiIT 3 .COOH 55 260 Japp and Schultz B., 10, 1661 34,77 acid n- ., 5 .... 266 Japp A., 196, 13 37,83 ft- 11 !> CCT /~( \j\J\JO. },\,>el,4 1 | * 5> .... 250-252 11 37,84 a-Anthracene-carboxylic acid C,H 4 :C 2 H(COOH):C.H 4 51 .... 206 p.d. Grsebe and Lieber- B., 2, 678; A., vi., 180 ; 26, mann 160, 121 139 - ,, C 6 H 4 : C 2 H 2 .C 6 H 3 .COOH 55 .... 260; Liebermann and v. B., 8, 248 28, 763 sf. 220-230 Rath y- a i, 5J abt. 280 Liebermann and B., 13, 49 38, 400 Bischoff y~ a a a 55 55 280 Biirnstein B., 16, 2609 46, 330 Methyl anlhraquinone C 6 H 4 :C 2 2 :C f ,H 3 Me 15 160-162 Wachendorff and B., 10, 1485 34,232 Zincke 11 a 5 M 162-163 O. Fischer B., 8, 675 28, 1021 a 11 w 5 .... 177-179 Wachendorff and B., 10, 1486 Zincke a a J - .... 175-176 Bornstein B., 15, 1820 44, 71 n a 55 M 177 Roemer and Link B., 16, 696 44, 1138 Methanthraquinone (0 55 187 J. p. [2] 9, 421 From Codeine C 6 H 4 .C 2 O.C 6 H 3 .OMe 51 65 Gerichten and B., 15, 1487, 2179 42, 1113 ; 44, " Schrotter 222 Phenoxymethylenephthalyl C 6 H 4 .(CO) 2 :CH.OPh=1.2 C 15 H 10 O 3 .... 142-143-5 Gabriel B., 14, 922 40, 733 /3-Phenylumbelliferone C 6 H 3 (OH).CPh : CH.CO.O .... 244 Pechmann and B., 16, 2119 46,67 Duisberg Hydroxymethylanthra- C 14 H 6 : 2 .Me.OH 55 .... 177-178 Roemer and Link B., 16, 699 44, 1139 quinone n a 55 5> .... 260-262 d. A., 202, 163 Acetyl salicylresorcinol oxide O.C 6 H 4 .CO.C 6 H 3 .OAc = 1.2 ; C 15 H 10 O 4 .... 167-168 Michael A. C. J., 5, 81 46, 312 l_ 1 Benzhydrylisophthalic C 6 H 3 .(COOH).CO.O.CHPh 55 206-207 Blatzbecker B., 9, 1764 31, 469 i j i i i anhydride COOH.CO = 1.3 11 5 55 55 .... 206 Zincke B., 5, 800 26, 272 Methyl quinizarin C 6 H 4 :(CO) 2 :C 6 HMe(OH) 2 ..., 160 Nietzki B., 10, 2012 34, 154 = 1.2.4.3.6 alizarin = 1.2.4.5.6 )5 250-252 O. Fischer B., 8, 676 28, 1021 ,, n a M .... 250-252 Fraude B, 12, 241 36, 635 Chrysophanic acid C 14 H 6 Me(OH) 2 :0 2 15 163 Sadtler & Rowland A. C. J., 3, 22 40, 1042 11 11 >5 .... 162 .... A. i., 959 Chrysin 275 TV 1 B., 6, 884 26, 1236 Benzoyl isophthalic acid C 6 H 3 (COOH) 2 .Bz = 1.3.? C I5 H 10 5 I 278-280 A i ccarct Blatzbecker B., 9, 1762 31, 469 11 11 a 55 .... 278-280 Zincke B., 5, 800 26, 272 Beuzoylterephthalic acid = 1.4.5 55 .... a. 290 J., 1878, 402 n .... !) n n.f. Weber and Zincku B., 7, 1154 Benzophenonedicarbonicacid CO(C 6 H 4 .COOH) ; ,= 1.4 ; 1.4 55 i... a. 300 Ador and Craffts B., 10, 2175 34, 405 Trioxymethylanthraquinone C 14 H 4 .Me.(OH) 3 :0 2 55 .... 245-850 Liebermann A., 183, 161 31, 610 (emodin) >! 11 55 n .... 257 Liebermann and B., 9, 1777 Waldstein 2 M 266 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Apigenin Galangiu .... ... 81 Dobner A., 210, 251 42,508 Desoxybenzoin carboxylic Ph.CH 2 .CO.C 6 H 4 .COOH 74-75 Gabriel and Michael B., 11, 1019 34,735 acid = 1.2 Toluylobenzoic acid CH 3 .C 6 H 4 .CO.C 6 H 4 .COOH 146 Friedel and Kraffts C. E., 92, 833; 40, 732 = 1-4; 1-2 B. S., 35, 505 11 ii + H 2 O ii ii 11 a. 100 + 11 11 ,i ii i' 222 u.c. Weiler B., 7 1184 28, 151 ii ii 11 .... 222 Fischer B., 7, 1195 =1.4; 1.4 ,, .... 228 Ador and Craffts B., 10, 2175 34, 405 Isohydrobenzoin carbonate .... .... 110 Wallach J. p., 25, 262 42, 853 Phenyl p-coumaric acid fr. C 6 H 4 (OH).C 2 H 2 .COOH ,, 219 Oglialoro G. I., 13, 173 46, 176 Stilbous acid = 1.4 Lau rent A. C. [2] 65 193 Pyroxanthiu ... " Hill A. C. J. 3 332 42 307 " .... B. 10 938 32 747 Na on phenylic acetate .... ,, ... 48 Perkin & Hodgkin- o* , i ~ t 37, 488 (?) acid 1 841 fifi son Bemthsen & Bender B. 15 1985 Phenylic acetoxybenzoate .... C 6 H 4 .OAc.COOPh = 1.4 C 15 H 12 4 1O* AOU 84 Klepl J. p., 28, 193 46, 448 Phenoxyacetophenone COOH.C 6 H 4 .CO.CH 2 .OPh .... 110-110-5 Gabriel B., 14, 923 40, 733 carboxylic acid = 1.2 Benzoyl-ethylenepyrogallol.... c 6 H 3 (OBz):o 2 :c 2 H 4 109 Magatti B., 12, 1862 38, 2.50 Benzyl isophthalic acid C 6 H 3 (COOH) 2 (CH 2 Ph)=1.3.? H 242-243 Blatzbecker B., 9, 1765 31, 469 Orcinol-o-carbonate 11 . ... 195 d. Bender B., 13, 700 40,48 Dimethyleuxanthone C 13 H 6 Me 2 4 ,, 130 Grsebe and Ebrard B., 15, 1677 42, 1301 Benzoylvanillic acid COOH.OMe.OBz=1.3.4 C 15 H 12 O 6 178 TiemannandKraaz B., 15, 2068 Diacetyl a-dioxyquinone C n H 6 2 (OAc) 2 C 15 H 12 O 6 238-240 Thorner B., 11, 534 34, 575 Allylene-digallem .... 235 u. c. Wittenberg J. p. [2], 26, 68 42, 128!) Reduction of 23112203 from hydrobenzoin (C 1 ,,H 13 O 2 ) n .... 144-145-5 Breuer and Zincke A., 198, 174; B., 38, US ; 34, 11, 77 321 Dibenzyl ketone CO(CH 2 Ph)., 1D H 14 O 320-321 30 Popoff B., 6, 560 vii., 941 ; 26, 1037 COMPOUNDS CONTAINING THREE ELEMENTS. 267 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Benzyltolyl ketone CH 2 Ph.CO.C 6 H 4 Me=1.4 C 15 H 14 a. 360 107-5 Mann B., 16, 1646 40, 1034 Ditolyl ketone CO(C 6 H 4 .Me) 2 =(1.4) 3 333-33S-5 92 u. c. Ador and Crafts B., 10, 2174 34, 405 u. c. (725) ) J) 95 u. c. Weiler B., 7, 1184 28, 151 M ,, 94 Fischer B., 7, 1195 ,, ,, .... i n 94 Hepp B., 7, 1414 ,, J) M 94 Haiss B., 15, 1476 42, 1071 Phenylxylyl ketone Ph.CO.C 6 H 3 Me 2 =2.1.3 a. 350 Liquid Sollscher B., 15, 1682 42, 1292 Ethyldiphenyl ketone Ph.CO.C B H 4 Et=1.4 u a. 300 Methoxystilbene C 6 H 4 .OMe(CH : CHPh)=1.4 136 Oglialoro G. I., 9, 533; J. 38, 253 [1879], 732 Cynanchol (see C J6 H 24 O) Mixture 135-145 Butlerow A, 180, 349 30, 103 From Al paracresylate .... 307 168 Gladstone & Tribe 41, 9 Al metacresylate 200 41, 14 Octylic beuzoate C 6 H 5 .COOC 8 H 17 C 16 H 14 2 305-306 A., 152, 7 Benzylic phenylacetate Ph.CH 2 .COO.CH 2 Ph s.a. 300; 270 Liquid Hodgkinson 37, 485 (160) ,! S17-S19 Liquid Slawik B., 7, 1056 28, 59 Diphenylcarbinol acetate .... Ph 2 CH.OAc 310 Liquid Friedel and Balsohn B. S. [2], 33, 340 38, 559 ,, 301-302(731) 1. 15 Linnemann A., 133, 20 iv., 479 ,, 300 41-6 Vincent B. S. [2], 35, 304 40, 596 Phenylbenzylacetic acid Ph.CH 2 .CHPli.COOH 84 Wurtz C. R, 70, 350 vii., 427 84 ,, C. R, 68, 1298 36, 641 Diphenylmethylacetic acid .... CPh 2 Me.COOH .... 178; Thorner and Zincke B., 11, 1993 36, 322 a.f. 169-172 5? ! a. 300 171-172 Bottinger B., 14, 1596 Benzylphenol acetate C 6 H 5 .CH 2 .C 6 H 4 .OAc 315-320 Perkin and Hodg- 37, 723 kinson ,, ,, 317 Paternd and Fileti G. I., 3, 121,251; 27, 371 J. [1873], 440 Methylic benzylbenzoate C 6 H 5 .CH s .C 6 H 4 .COOMe=1.2 Liquid Rotering & Zinck6 B., 9, 633 ao, 414 Ethylic phenylbenzoate C 6 H 6 .C 6 H 4 .COOEt=1.2 ,, 300-305 1. 20 Schmitz A, 193, 123 36, 164 =1.4 .... 46 Dcebner A., 172, 114 27, 893 Tolylphenylacetic acid CH 3 .C 6 H 4 .CHPh.COOH=1.4 ,, .... 115 Tanisch B., 10, 996 32, 618 Tetrahydroanthracene car- C 14 H 13 .COOH .... 164-165 Bornstein B., 16, 2612 46, 330 boxylic acid Tolylene alcohol monoben- C 6 H 4 .CH 2 OH.CH 2 OBz= 1.4 C 15 H 14 3 73-74 Grimaux A., 155, 341 ; vii., 120 zoate C. R, 70, 1363 Methylic benzhydrylbenzoate C 6 H 4 .CHPh(OH).COOMe .... 109-110 .... J. [1875], 599 =1.4 benzylsalicylate .... C H 4 .OCH 2 Ph.COOMe=1.2 B , v G. I., 12, 337 ; B., 44, 210 )) .... 1OO j aijerno 16,800 HNO 3 on lapachic acid CO .... 116-117 B 44,213 Diphenylpropionic acid C 2 H 3 Ph 2 .COOH C 15 Hj 4 O 4 .... 268 Bottinger B., 16, 2072 46, 55 Ethylene phenoloxybenzoate PhO.C,,H 4 .O.C 6 H 4 .COOH 196 Wagner Jp. [2], 27, 227 ; 46, 437 28, 199 Benzoyldimethylpyrogallol .... C 6 H 3 (OMe) 2 .OBz .... 118 Hofmann B., 12, 1373 Hydrocoto'in .... .... .... no A., 199, 57 Santaliii (santalic acid) C',7 H 160,, (?) C 15 H U 5 WO 104 Westermanu and A., 74, 226 v., 187 Hiiifely i ftn o. A., 30, 201 iv., 492 " .... 2 M 2 268 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Phloretin C,H,,O (]) r H o 253-255 Schiff B., 14, 302 40, 439 Catechuic acid ^ 15-*-Ml v 6 \ / ^'15^-14^'S C, S H 14 0- 160-165 Lowe Z.A.C.[1874],113 28,75 Dipyrogallopropionie acid ... .... Ci 5 H 14 O g .... 162 Bottinger B., 16, 2405 46, 318 Diphenyl carbinolethyl oxide Ph 2 CH.OEt C 16 H 16 183 (736) Liquid Liimemann A., 133, 17 iv., 479 " J) 288 Liquid Fried el and Balsohii B. S. [2], 33, 337 38, 558 )) J) >) 120 Zagoumeny B. S. [2], 26, 452 31, 460 Tolylbenzylcarbinol CH 2 Ph.CH(OH).C 6 H 4 .Me a. 360 66 Mann B., 14, 1646 40, 1035 =1.4 Ditolylcarbinol (CH 3 .C 6 H 4 ) 2 .CH.OH 69 Weiler B., 7, 1184 28, 151 Dimethoxydiphenylmethane CHj(C,H 4 .OMe) 2 =1.4 ; 'I ^l&Hl62 330-340 49 Beck A., 194, 323 36, 325 ) j > a. 360 52 ter Meer B., 7, 1200 28, 158 Hexhydroaiithracene car- C 14 H 15 .COOH j) 232 Bornstein B., 16, 2613 46, 330 boxylic acid Hydrolapachic acid .... C 15 H 16 3 (?) 100 Patern6 G. I., 22, 337 44, 212 Ethylic cinnamylacetoacetate Ph.CH:CH.CO.CH Ac.COOEt Ci 5 H 16 04 40 Fischer and Kuzel B., 16, 166 44, 588 a-Triethylcesculetic acid C 6 H 2 (OEt) 3 (CH : CH.COOH) 102-103 Will B., 16, 2111 46, 68 ft' >! )) 144 ): B., 16, 2109 Diacetyl usneol C 11 H 10 Ac 2 3 C 15 H 16 5 141-142 Patent G. I. [1882], 231 42, 1082 Decarbusnic acid 175 > B., 9, 345 30, 202 i 198-199 G. I. [1882], 231 42, 1080 Hydrocoeruliguone See C I6 H 18 6 ^isH l6 O 6 190 Liebermann B., 5, 748 26,71 Picrotoxin See C 12 H 14 O 5 201 Barth and Kretschv B., 13, 1243 300-301 Schmidt & Lowen- B., 14, 819 hardt .... ) .... 199-200 Patern6 & Oglialoro B., 10, 83 (polymer) .... u .... 225 Schmidt & Lowen- B., 14, 818 40, 741 hardt Picrotoxid )> .... 310 Patern6 & Oglialoro B., 10, 83 Aloiu .... C 15 H 17 ; C I6 H 18 7 ? C 15 H 16 7 .... 146-148 Schmidt A. P. [3], 6, 496 30, 641 C lr H 18 7 ? 150 Stenhouse +xaq ) 70-80 Schmidt A. P. [3], 6, 496 i> Quercitrin See Ca.HaAo Ci 5 H 16 O 9 130-133 Liiwe Z. A. C., 14, 233 29, 708 (Esculin ... .. . 205 ! Snliiff B., 13, 1952 ^04^-^05 B., 14, 303 40, 439 Daphnin +2H 2 O T )) 100 d. ! A., 115, 1 Aloin .... See C 15 H 16 7 (C 15 H 17 0). Santanol Isomeric P TT O Liquid St. Martin C. R., 75, 1190; 26, 162 ^is-^-is^^ J. [1872], 808 abt 350 135 Ethylic cinnamylethylacetate Ph.CH :CH.CO.CHEt.COOEt is ^'is^is^s 210 (22) Liquid Matthews .... 43, 207 Parasantonide )< .... 110 Nasini B., 14, 1512 )J 110-110-5 Cannizzaro&Valente J. [1878], 826 ; 36, 331 G. I., 8, 309 Santonide 127-127-5 n-Metasantonin I )> J) .... 160-5 Cannizzaro and Car- J. [1878], 828 ; 36, 330 nelutti G. I., 8, 318 ., .... >1 238-%40 (10) 1GO-5 Cannizzaro and B., 7, 1105 28, 163 Amato .... )) 160-5 Carnelutti and B., 13, 2210 40, 181 Nasini ,1 .... 1) 160-5 Cannizzai'o and G. I., 10, 461 40, 285 Carnelutti - ., .... V 136 Carnelutti and B., 13, 2210 40, 181 Nasini ,. .... > 186 Cannizzaro and G. I. 10, 461 ; J. 40, 285 Carnelutti [1878], 828 ,, .... .... r .... 136 v., 189 ., ... )) .... 186 Cannizzaro and G. I., 8, 318 36, 330 Carnelutti J, .... ,, .... 135-13G Trommsdorff A., 11, 190 Isosantonin l 137-138 Cannizzaro J. [1880], 894 COMPOUNDS CONTAINING THREE ELEMENTS. 269 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Santonin ... C 15 H 18 3 170 Cannizzaro and G. L, 3, 241 ; B., 26, 1230 ; vii., Sestini 6, 1201 1074 ,, .... .... .... ., 169-170 Schmidt G. J. C. [1865] .... .... .... .... 170 German Pharma- 1882 copoeia Trieth oxy phenylpropionic C 6 H 2 (OEt) 3 (CH 2 .CH 2 .COOH) C 15 H ]3 4 77 Will B., 16, 2111 46,68 acid Eesin from Eottlera tinctoria * 80 Leube J. [1860], 562 v., 118 Triethylic trimesitate C 6 H 3 (COOEt) 3 =1.3.5 C 15 H 18 O f , 129-133 Ost J. p. [2], 15, 314 32, 486 Diethylic benzoracemate C s H,(OH)(OBz)(COOEt) s C 15 H 1S 7 57 Perkin As., 5, 278 v., 693; 20, 139 benzotartrate I) I) 64 As., 5, 276 Triethylic phenoltricarboxy- C 6 H 2 .OH.(COOEt) 3 =1.2. (i) 3 .... 84 Ost J. p. [2], 14,117 30, 523 late Picrotoxinin (picrotoxin hy- C 15 H 16 6 +H 2 u .... SOO-S01 Schmidt and Low- B., 14, 819 40, 740 drate) enhardt V > .... 201 p.d. Barth and Kretschy W. A., 8, 7 40, 286 1) .... 246-248 d. Paternd & Oglialoro G. L, 7, 193 32,790 Tetracetyl quinide C 7 H 6 Ac 4 O 6 C 15 H 18 O 9 124 Hesse A., 200, 233 38, 317 Alantic anhydride .... C^H^Oj 275 p.d. 66 Kallen B., 9, 155 29, 917 E thy 1 i c ethy Ibenzy lace tace- C 6 H 5 .CH 2 .CEtAc.COOEt C^H^OS 295-298 Liquid Conrad B., 11, 1057 34,732 tate Hydrosantonide 155-156 Cannizzaro&Valente G. L, 8, 309 ; J. 36, 332 [1878], 827 Isosantonous acid 155 Cannizzaro and B., 12, 1575 Carnelutti ,, ,, 51 150-160 (4) 153-155 V 1) G. L, 12, 393 ; 44,77 B., 16, 428 Saiitonous acid .... ., 200-260 (5) 178-179 <> H ,, 178-179 )! >, B., 12, 1574 Pipitzahoinic acid 100 A., 95, 188 Diethylic benzylmethylmalo- Ph.CH 2 .CMe(COOEt) 2 C 15 H 2(J O 4 300 .... Conrad & Bischoff B., 13, 595 ; A., 38, 628 nate 204, 177 Photosantonic acid C 13 H 18 (COOH) 2 153 Sestini G. L, 6, 357 31, 472 +H 2 .... ,, .... 125-130 Cannizzaro G.I. Saiitoiiic acid .... .... .... 161-163 Cannizzaro and G. L, 3, 241 ; B., 26, 1230 ; vii., Sestini 6, 1201 1074 171 Hooslef B., 6, 1471 vii., 1074 Metasantonic acid 161-167 Cannizzaro G. L, 6, 341 31, 471 Triethyldaphnetic acid .... C 15 H 20 O 5 193 Will and Jung B., 17, 1087 46, 1143 Diethylic oreyldiglycollate .... C 6 H 3 Me(O.CH 2 .COOEt) 2 c lb a w o e 107 Saarbach J. p. [2], 21, 167 38, 394 Pentic acid 3C 5 H 6 O 2 -|-H 2 O C 15 H^O. 127-128 Demar^ay C. E., 88, 126 36, 457 128 B. S. [2], 33, 575 40, 255 Uxypentic acid 3C 6 H 6 3 +H,0 C 16 H 20 O, 193 C. E., 88, 289 36, 458 Isoamyleugenol (CH 2 .CH : CH 2 ).OMe. CjjH^Oo 283-285 Cahours C. K., 84, 151 ; 31, 462 OC 5 H U =1.3.4 or 1.4.3 J. [1877], 581 Acetyl diisopropyl cresol .... C c H 2 .Me.Pr0 2 .OAc= 1 . (?) 2 .3 n 255-260 1. f. m. Mazzara G. I., 12, 505; B., 44,463 16, 793 dipropyl cresol C 6 H 3 .Me.Pr 2 .OAc=l.(?) 2 .3 255-260 Liquid r a Cyclamiretin .... 198 A, 185, 218 HC1 on sylvane I 235-245 Atterberg B., 13, 881 38, 663 Alantic acid C 14 H no .OH.COOH P TT O ii() (11 A Ivallen B., 9, 155 29, 917 tf\J if L U. Laserpetin .... .... OHO 118 Kiilz A. P. [3], 21, 161 46, 182 VS|U Oi>V/.J Hydrosantonic acid .... .... n 170 d. Cannizzaro G. I., 6, 341 ; J., 31, 470 [1876], 619 Triethoxypheaylpropionic l' 6 U 2 (OEt) 3 .C 2 H 4 .COOH CuHjjOi 85 Will and Jung B., 17, 1087 46, 1143 acid Tetraethylic propylenetetra- (COOEt) 2 .CH.CH : C C 15 H 22 O S 270-280 Liquid Conrad & Guthzeit B., 15, 2842 44,312 carboxylate (COOEt), CHEt., CO.C 3 H 4 .(C 2 H 3 )., C H O 9KfU'WI Geuther, Frohlich, A., 202, 312 38, 623 15 24 ^oU oUU and Looss Alcoholic KHO on camphor M 238-240 c. Montgolfier A. C. [5], 14, 5 34, 900 Amvlthvmol .., aH,.Me.C,H,.OC,H.. 9aS_9ASn r\ T.imiiH Z. C. fl869l 43 vi., 1090 270 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Euphorbone .... C,JL,,O 113-114 Hesse A., 192, 193 34, 801 From essence of sandal wood 15 24 5) 300 Chapoteaut B.S. [2], 37,303; 44, 76 B., 15, 1197 Santanal .... .... ... 30 Lactucone )> 150-200 j A. 60 83 11 a-Paracatol 220-222 A., 199, 79 Cynanchin .... ... ... 148-149 A. 180 352- 182 .... J 163 ; 192, 182 Cynanchocerin 1) 145-146 .... )> Tetraethylic isoallylenetetra- C(COOEt) 2 (CH 2 .COOEt}. ! C 15 H 24 O 8 199-201(25); Liquid Bottinger B., 13, 2164 ; A., 40, 156 carboxylate 293-296 p. d. 214, 62 (725) Isoamyl camphor C 10 H 16 .OC 5 H U C 15 H 26 277-5 c. (736) Baubigny Z. C. [2], 4, 481 ; vi., 388 272-275 vuc. 7, 299 Cedar camphor .... 282 74 Walter A. C. [3], 1, 498 i., 818 Cubebs camphor .... 19 65 Schmidt B., 10, 189 )> .... )> .... 67 Schaer and Wyss A. P., 206, 316 j> .... .... 68-7-70 Eichter Tabellen Patchouli camphor See CjsHjsO 11 296 54-55 Gal B. S., 28, 414 Sesquiterpene hydrate C 15 H 24 .H, ! O i 200-220 .... Beilstein&Wiegand B., 15, 2855 44, 346 Santalol 310 Chapoteaut B. S. [2], 37, 303 ; 44, 76 j B., 15, 1197 Diamenyl valeric acid C 4 H 7 (C 5 H 9 ) J .COOH C 15 H 26 2 300-306 Geuther, Frolich, A., 202, 304 38, 623 and Looss Borneolisovalerate CHMe 2 .CH 2 .COOC 10 H 17 255-260 Bruylants B., 11,456 Ethylic phoronate CH 2 .CMe 2 .COOEt Ci 5 H 26 O 5 .... 125 Pinner B., 14, 1079 40, 797 CMe.CH 2 .CMe(COOEt).O L I Patchouli camphor See C 16 H 26 C 15 H 29 282-294 Liquid Gal C. E., 68, 406 vi., 902 11 296 54-55 )> j) .... 3 59 Montgolfier C. E., 84, 88 31, 478 Beech nut oil.... C H O 17 Lefort C. E. 35 734 i "S97 Vy 15 J ~ L 2S v ^2 A., tjzt i Oimicic acid .... C 14 H 27 .COOH 43-8-44-2 Carius A., 114 151 i., 964 (?) 11 234-240 u. c. Ga'ss and Hell B., 8, 373 Isoamylic hydrogen sebate .... C 8 H 16 (COOC 5 H n )(COOH) C, 5 H 2S 4 d. 325 a. 10 Neison J. [1876], 577 29, 323 Tridecyl methyl ketone Me.CO.(CH 2 ) 12 .Me C, 5 H 30 294 39 Krafft B., 12, 1669 38, 34 M )) 219 (100) 39 D B., 15, 1708 42, 1272 Diheptyl ketone (caprylone) C 7 H 15 .CO.C 7 H 15 278 40 Guckelberger J. 2, 340; A., 69, 201 (?) ketone .... 163-168 .... Geuther, Frolich, A., 202, 327 38, 623 and Looss From Ficus gummiflua Alcohol >i .... 73 Kessel B., 11, 2114 36, 262 Isoamylic iaocaprate 9 19 ^^'5 11 Ci5H 30 O 2 275-290 d. Liquid Grimm A., 157, 269 24, 360; vii., 249 Pentadecylic acid CH 3 (CH 2 ) I3 .COOH 257 (100) 51 Krafft B., 12, 1671 38, 34 i> U " 5> j 257 (100) 51 ;> B., 15, 1687 42, 1272 Benomargaric acid .... CnH^-COOH it 52-53 Walter C. E., 22, 1143 i., 538 Oetic acid f?') 53-5 Heintz P. A., 84, 232 ; 87, i., 838 )J >1 \V 553 ; J. 5, 505 Isocetic acid )i 1J 55 Bouis C. E., 39, 923 ; iii., 414 J. 7, 463 Acid from oxidation of cholic )> 54 Tappeiner Z. B., 12, 60 31, 213 acid Lactarius piperatus )> )1 69-70 Bissinger A. P. [3], 21, 321 46, 480 Agaricus integer )1 69-5-70 Thorner B., 12, 1631 38, 44 Lycostearone .... 75-76 A. 100 302 ) Diamy valeral C 5 H 10 .(OC 5 H 11 ) 2 ^1511320., 240-255 Liquid Alsberg J., 17, 486 v., 974 a-Phenylenenaphthylene .... CuH s O 3 140 Arx B., 13, 1727 ; A., 40, 282 oxide quinone 209, 143 Diphthalyl CO.C 6 H 4 .CO.CO.C 6 H 4 .CO OHO a. 300 + Ador A. C.[4], 26,417; vii., 979 26, * '16 n 8 < -'4 A., 164, 229 67, 392 =(1.2) 2 COMPOUNDS CONTAINING THREE ELEMENTS. 271 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diphthalyl C B H 4X X C 6 H 4 C 16 H 3 4 334-335 Grsebe and Schmal- B., 15, 1674 42, 1298 COO/ \)OC zigany Diphthalic anhydride yCO.CO N^ C 16 H 8 5 228 Ador A, C. [4], 26, 417 26, 393 Anthraquinone diearboxylic C 14 H 6 : 2 (COOH) 2 C 16 H S 6 a. 300 Wachendorff and B., 10, 1483 34, 232 acid Zinck6 Dioxydiphthalyl ... 11 .... 250 .... A,, 164, 246 a-Naphthalene phenylene C L H 4 .O.C ln H f , C 16 H 10 a. 360 ; 178 Arx A., 209, 141 ; B., 40, 282 oxide 1 1 sb. 280 13, 1726 0- 33 296 A., 209, 145 P~ 33 33 33 300 Grsebe and Knecht A., 202, 15 38, 664 Idryl carboxylic acid C 15 H 9 .COOH C 16 H 10 O.j 165 Goldschmidt W. A., 81, 415 40, 284 Dibenzyldicarbonide.... .... .... 202 Eeimer B., 14, 1806 42, 200 Quinone from ruticoccin 250 Liebermann and V. A., 163, 97 25, 706 ; vii., Dorp 368 Diphenyltetrol quinone of o.o.c : cph.c : cph n ... 109-110 Breuer and Zinek6 B., 11, 1404 34,890 C H ., i 1 (white) ,3-modili cation (C 16 H 10 2 ) n .... S07-5 33 3) B., 13, 634 38, 666 33 !> 211-211-5 B., 11, 1403 34,890 (yellow) a-modification 225-229 33 33 B., 13, 634 38, 666 J> I! .... abt. 240 B., 11, 1403 34, 890 Diphenylmaleic anhydride .... Ph 2 c 2 :(co) 2 :o C 16 H, O 3 Identical 156 Eugheimer B., 15, 1626 42, 1298 Diphenylfumaric CPh:CPh.CO.O.CO 155 Eeimer B., 13, 743 40,47 L 1 Hydroxydiphenyltetrolqui- o.o.c : cph.c : c.c 6 H 4 .OH 143-5-144-5 Breuer and Zinck6 B., 11, 1403,1996 34, 890; 36, none 327 Acid from diphthalylaldehy- .... H .... 200-225 Ador A., 164, 229 vii., 979; 26, dic acid 67 Acetoxyauthraquinone c 6 H 4 : (CO). : c 6 H 3 .OAc Ci 6 H 10 4 .... 158 Liebermanu B., 5, 870 vii., 92 ; 26, =1.2; 1.2.4 276 11 159 Liebermann and B., 12,591; A.,' 36, 654; 42, Hermann 212, 52 859 31 =1.2 ; 1.2.3 13 176-179 Liebermann and B., 15, 1804 Hagen Methylanthraquinone car- 14 H 6 Me.COOH I O 2 33 244-246 Wacheudorff and B., 10, 1483 34, 232 bonic acid Zinck6 V Anhydride .... .... ^ 240 Ador A., 164, 229 vii., 981; 26, 69 Benzoyldaphnetiu t' 9 H 5 Bx0 4 C 16 H 10 O 6 ... 149-150 Stiinkel B., 12, 113 36, 469 Diphthalylaldehydic acid .... CO.C C H 4 .COH =1.2 a. 300 d. Ador A. C. [4], 26, 417 vii., 979; 26, CO.C 6 H 4 .COOH=1.2 A., 164, 233 67, 392 Diphthalic acid CO.C 6 H 4 .COOH=l.i> C 16 H 10 O 6 265 A. C. [4], 26, 417 vii., 980; 26, CO.C 6 H 4 .COOH=1.2 A., 164, 236 67, 393 Acetoxypurpurin .... C 16 H 10 7 (?) a. 240 Diehl B., 11, 186 34, 430 From hydroxynaphthoben- C 16 H 12 .... 108 Walder B., 16, 306 44, 666 zoic acid Acetphenanthrol C H 4 .CH:CH.C 6 H 3 .OAc CisHisOj 117-118 u.c. Eehs B., 10, 1253 34, 77 Acetanthrol .... . . C G H 4 :C,H 2 :C 6 H 3 .OAc 33 .. .. 198 Liebermann and B., 12, 590; A., Hermann 212, 51 Acetanthranol C 6 H 4 : C 2 H(OAc) : C H 4 33 .... 126-131 Liebermann and B., 9, 1202 ; A., 31, 86 ; 42, topf 212,8 856 Dimethylanthraquinone CuH.MvO, 33 .... 153 van Dorp B., 5, 674; A., vii., 84; 25, 169, 207 1007 ; 27, 63 11 31 155 Wachendorff and B., 10, 1482 34, 232 Zinck6 From codethyline 14 H 7 O.OEt 59 Gerichten and B., 15, 2182 44, 222 Schrotter 272 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority, Reference. Watts' Diet. & J. Ch. Soc. Hydroxydiphenyltetrolquinol C(OH) : CPh.C(OH) : C.C 6 H 4 . C 16 H 12 O 3 .... 72-73 Breuer and Zincke B., 11, 1997 S6, 3^7 t J OH Cresoxymethylenephthalyl .... C 6 H 4 : (C0) 2 : CH.OC 6 H 4 Me 11 173-174 Gabriel B., 14, 924 40, 733 =1.2 ; 1.4 Ethoxyanthraquinone c H 4 : (co) 2 : c 6 H 3 .oEt 135 Liebermann &Hagen B., 15, 1798 44,73 Diphenylfumaric acid Ph 2 : c 2 : (coon). C 16 H I2 4 abt. 260 Eugheimer B., 15, 1625 42, 1298 Dibenzoylacetic acid.... CHBz,.COOH JJ 109 Bseyer and Perkin B., 16, 2134 46, 64 Acetylic benzoylbenzoate .... C 6 H 4 .Bz.COOAc=1.2 Jl 112 Pechmann B., 14, 1865 42, 184 Acetylsalicylorcinol oxide .... CO.C 6 H 4 .O.C 6 H 2 Me.OAc 1) 151-152 Michael A. C. J., 5, 81 46, 312 L _| =1.2; ? Methylchrysin (tectochrysin) 130 Piccard B., 6, 891 26, 1238 i) i> C 6 H 3 .Me.OCOPh.OCOMe 163 B., 7, 891 27, 1166 11 ,, 163-164 B., 10, 176 32, 342 Dimethyl xanthopurpurin .... C 6 H 4 :(CO) 2 :C 6 H 2 (OMe) 2 11 178-180 Plath B., 9, 1204 31,87 =2.1 ; 1.2.3.5 ,, anthraflavic acid.... C 6 H 3 (OMe):(CO) 2 :C 6 H 3 ^ 247-248 Schunck & Bcemer B., 9, 383 30,89 (OMe)=4.2.1 ; 1.2.5 Acetoxybenzoylhydroxyben- C 6 H 4 (OAc).COOC 6 H 4 .COOH C 16 H 12 6 216-5 Klepl J .p., 28, 193 46, 448 zoic acid =1.4; 1.4 Campheride .... 221-222 JcillllS B. 14 2386 42, 201 Dimethyltetrahydroxyan- C 14 H 2 Me 2 (OH) 4 :0 2 11 242; Briinner M. C., 2, 466 40, 1142 thraquinone a. 300 a. s. Anthrol ethyl oxide C 6 H 4 :C s H 2 :C 6 H 3 .OEt C 16 H 14 139-140 Liebermann and B., 12, 591 36, 654 Hormann 11 D 11 * 51 139-140 Liebermann A., 212, 51 42, 859 11 11 11 1} 11 145-146 Liebermann and B., 15, 1427 42, 1212 Hagen Benzylic cinnamate C 6 H 5 .CH : CH-COOCHj-CA C J6 H H O 2 305 1. 12 or Plantamour A., 26, 329 ; 30, i., 980 15 241 11 _. 340-350 .... Deville B., 74, 230 11 11 *. " 11 340-350 .... Frfimy A. C., 70, 189 11 11 1, 11 d. 350 ; 39 Grimaux Z. C. [2], 5, 157 vi., 471 225-235 (?) Dibenzyl glycollic anhydride (C 6 H 6 CH 2 ) 2 .C.CO.O .... 157 Spiegel B., 14, 1689 40, 1036 1 1 Ethylic diphenylene acetate C 6 H 4 .C 6 H 4 .CH.COOEt 165 Friedlander B., 10, 536 32, 493 i i =(l-2) 2 fluorenate C 6 H 4 CH 2 .C 6 H 4 .COOEt 11 .... 53-5 Fittig & Liepmann A, 200, 16 38, 402 L ' =(1.2) 2 .3 Phenanthrol ethyl oxide .... C 6 H 4 .C(OEt) : C(OH).C 6 H 4 80 Japp B., 13, 761 37, 409 =(1.2), D 11 i> >> C 16 H I4 2 +Et.OH 11 d. 73 77 B., 12, 1307 Oxanthrol ethyl oxide C 6 H 4 .CO.C 6 H 4 .CH.OEt 106-107 Liebermann B., 13, 1597 40, 100 i i Ethyloxanthranol C 6 H 4 .CO.C 6 H 4 .CEt.OH 107 A., 212, 70 42, 861 Dioxyretistene 190 Ekstrand A., 185, 98 32, 498 .... n 194-195 Wahlforss Z. C. [2], 5, 74 vi., 994 Acetyl benzoin C, 4 H u AcO 2 C 16 H 14 O 3 b. 100 .... i., 559 11 11 75 A., 104, 120 ; 155, 92 Ethylic benzoyl benzoate .... C 6 H 4 .Bz.COOEt =1.4 .... 52 Plascuda B., 7, 988 28, 75 =1.2 11 58 B., 7, 987 11 11 11 11 .... 11 11 11 .... 58 Plascuda & Zincku B., 6, 90(i 26, 1225 Methoxyphenylcinnamic acid C 6 H 4 .(OMe.)CH : CPh. 188-189 Oglialoro G. L, 9, 533 ; J. 38, 253 COOH=1.4 [1879], 731 Methylic toluyl benzoate .... CH 3 .C 6 H 4 .CO.C 6 H 4 .COOMe 53 Friedel and Crafts C. B., 92, 833 40, 732 = 1.4; 1.2 Ethylic diphenyleneglycollate C 6 H 4 .C 6 H 4 .C(OH).COOEt 11 92 Friedlander B., 10, 534 32, 492 COMPOUNDS CONTAINING THREE ELEMENTS. 273 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Xyloylbenzoic acid C 6 H 3 Me 2 .CO.C 6 H 4 .COOH Ci6H 14 O s .... 161-5 Meyer B., 15, 637 42, 848 =1.2.4; 1.2 )! =1.3.4; 1.2 .... 126 n B., 15, 637 j) " =1.4.5 ; 1.2 easily Acetoxyhydroanthrol (ortlio) C 6 H 4 : (CH 2 ) 2 : C 6 H 2 .OAc.OH .... 136-138 Liebermann and B., 10, 610 32, 494 Giessel )> .... 136-138 Liebermann A., 212, 19 42, 856 Ethylene dibenzoate C 2 H 4 .(OBz) 2 C 16 H 14 4 a. 350 67 Simpson and Wurt A. C. [3], 55, 400 i.,553; ii.,568 Diphenylic succinate COOPh.CH 2 .CH 2 .COOPh )> 380 118 Weselsky B., 2, 519 vi., 1043 )) .... 119 Easinski J. p. [2], 26, 63 42, 1289 Dibenzylic oxalate (COO.CH 2 Ph) 2 J5 .... 80-5 Beilsteinand Kuhl Z. C. [2], 3, 467 ; vi., 336 berg A., 147, 341 Diphenylsuccinic acid COOH.CHPh.CHPh.COOH .... 222 Franchimont B., 5, 1050 26, 391 ) ) .... 222 Eeimer B., 14, 1802 42, 200 +H 2 )J > 183 i !) 5! ') 1) >J .... 182 Franchimont B., 5, 1050 CH.,Ph.CPh(COOH) 2 )> .... 229 Eeimer B., 14, 1802 42, 200 Dipheuylethane dicarboxylic From CH 3 CHPh 2 5J .... 275 Haiss B., 15, 1481 42, 1071 acid Dimethylic diphenate (C 6 H 4 .COOMe) 2 =(1.2), *} .... 73-5 Schultz A., 203, 98 38, 814 isodipbenate =1.2; 1.3 >J .... 69-5 Fittig & Liepmaim A., 200, 10 38, 401 8-Diacetoxy diphenyl (C 6 H 4 .OAc) 2 = ? )) .... 94 Schmidt & Schultz B., 12, 490 36, 652 )1 1) )> ) ) .... 94 Schultz, Schmidt, A., 207, 358 40, 912 and Strasser !! ) )> 1 .... 94 '> jj y- j> =(1.4), )) 159-160 Schmidt & Schultz B., 12, 490 36, 652 II )! ) )J .... 159-160 A., 207, 336 40, 910 Dimethoxybenzil (anisil) .... (MeO.C 6 H 4 .CO) 2 =(1.4) 2 J> .... 133 B5sler B., 14, 327 40, 421 Anisic anhydride (C 6 H 4 .OMe.CO) 2 O =(1.4) 2 C 16 H lA .... 99 Pisani A., 102, 284 i., 303 Acetyl oroselone C 6 H 4 (OAc).O.C 6 H 4 .OCH 2 . J) .... 123 Hlasiwetz & Weide A., 174, 81 28, 257 COH Helenin .... cf. C 6 H 8 O C 21 H 2S 3 (?) )J .... 72 Gerhardt .... iii., 138; vi., 75 Hoyer V. p. P., 13, 544 693 Ethylene salicylate [C 6 H 4 (OH).COO] 2 : C 2 H 4 C 16 H 14 6 .... 83 Gilmer A., 123, 277 H )) v., 166 =(1-2), salicylic acid C 2 H 4 (O.C 6 H 4 COOH) 2 =(1.2), 1) .... 151-152 Weddige J. p. [2], 20, 128 38, 317 Hydropiperoin C-H 5 2 .(CH.OH) 2 .C 7 H 5 O 2 )> 5) )J .... 202 202 Fittig and Eemsen I! Z. C. [2], 6, 97 A., 159, 131 vi., 948 24, 934 Isohydropiperoin .... T) .... 132-135 ) A., 159, 135 247935 ,, Hesperetin CH.COO.C 6 H 3 (OH) 2 =1.3.5 )) .... 138; a.f. 135 223 E. Hoffmann Z. C. [2], 6, 97 B., 9, 687 vi., 948 30, 420 CH.C 6 H 3 (OH)(OMe)=1.3.4 ) 226 d. Tiemann and Will B., 14, 951 40, 739 Hiematoxylin + 3H..O )) See B., 4, 333 )J 100-120 Eichter Tabellen Lecanoric acid .... C 16 H 14 7 .... 153 Hesse A., 139, 24 vi., 778 Diacetyl rhanmetin C 12 H 8 3 .(OAc) 2 n ... 183-185 Liebermann and A., 196, 319 ; B., 36, 271 Hormann 11, 1618 Diphenyl methyl acetone .... Ph 2 MeC.CO.Me C 16 H 16 310-31 1 c. 41-41-5 Thorner and Zincke B., 11, 1989 36, 317 Phenyldimethyl acetophe- C 6 H 5 .CO.CMe 2 Ph (1) 5J 340-345 c. 70 Grebe B., 7, 1626 28,457 none Ethylphenyl acetoj)henone .... Ph.CO.CH 2 .C 6 H 4 .Et ?7 120 Eadziszewsky B., 6,811 Ethyldesoxy benzoin CH 2 Ph.CO.C 6 H 4 .Et=1.4 )> .... 64 Sollscher B., 15, 1680 42, 1292 Dimethyldesoxybenzoin CH 2 Ph.CO.C 6 H 3 .Me, 1> a. 350 92-5- 93 )> B., 15, 1681 5) Benzoylmesitylene C 6 H 2 Me 3 .Bz=1.3.5.6 ) a. 360 29 Louise B., 16, 966 ; C. E., 44,577 96,490 Styrolene alcohol a-pinacolin CHPh.CH 2 .O.CH 2 .CHPh.Oor CieH^O,, 260 (50) .... Jreuer and Zincke B., 11, 1403; A., CHPh.CH 2 .O.CHPh.CH,.O i J i 216, 298 2 x 274 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethyl benzoin CPh 2 (OEt).CO.H or G i6H 16 O 3 .... 95 Limpricht A., 155, 97 vii., 169 CHPh(OEt).CO.Ph Benzylic hydrocinnamate .... Ph.(CH 2 ),,.COO.CH,,Ph a. 300 Conrad and Hodg- B., 10, 254 31, 590 kinson j ) S90-SOO .... A., 193, 301 Ethylic diphenylacetate CHPh 2 .COOEt ) 57-58 A., 171, 129 Dibenzylacetic acid .... (C 6 H 6 .CH 2 ) 2 CH.COOH 85 Sesemann B., 6, 1086 27, 70; 28, 74 . n H .... 85 Merz and Weith B., 10, 759 32, 617 ,, )? )) 85-86 Ehrlich A., 187, 11 32, 439 Methylic tolylphenylacetate Me.C 6 H 4 .CHPh.COOMe=1.4 j Liquid Tanisch B., 10, 997 32, 618 Phenylic cuminate C 6 H 4 .Pr.COOPh u 57-58 Kraut ; Williamson A., 92, 318; J. ii., 181 and Scrugham [1858], 406 Ethylbenzylbenzoic acid (py- C 6 H 6 .CH 2 .C 6 H 3 Et.COOH )) .... 94 Zinin B., 10, 1735 34, 153 roamaric) Ethyl aoetoxydiphenyl AcO.C 6 H 4 .C 6 H 4 Et )} 250 (9) Mazzara G. I., 9, 421 ; J. 38, 161 [1879], 521 Benzyl acetoxytoluene C 6 H 3 Me.OAc.CH 2 Ph ) 245-246 (34) J. [1878], 591 =1.4 )> 245 (40) Liquid Paterno & Mazzara G. I., 8, 303 36, 315 Hydrobenzoiu monacetate ... C 14 H 12 .OH.OAc Cl 6 H 16 O 3 77 Limpricht and A., 160, 190 25, 138 ; vii., Schwanert 172 j )) 84 Forst and Zinckfi B., 7, 1714 ; A., 28, 454; 30, 182, 274 635 Isohydrobenzoin )) 87-88 j> B., 7, 1714 ; A., 28, 454 ; 30, 182, 282 636 Diphenylethoxyacetic acid CPh 2 (OEt).COOH ) Liquid Jena and Limpricht A., 155, 100 vii., 158 (ethylbenzylic) Desoxyanisoin .... )) .... 95 Rossel A., 151,40;Z. C., vi., 175, 543 [2], 5, 562 Dibenzylglycollic acid (oxa- (C 6 H 5 .CH 2 ) 2 .C(OH).COOH j) .... 154 Moller and Streckei A., 113, 69 iv., 287; 40, tolylic) 174 n > H 156-157 Spiegel B., 13, 2219 40, 174 Benzylphenoxy a-propionic CH 2 Ph.C 6 H 4 .O.CHMe.COOH )) 100-102 Mazzara G. I., 1882, 261 ; 42, 1072 acid B., 15, 1758 Methylbenzylphenoxyacetic C 6 H 3 Me.CH 2 Ph.(O.CH 2 . ) .... 109-111 G. I., 11, 437 42,404 acid COOH)=1.4. ? From oxidation of retene ... .... )) 139 Ekstrand A., 185, 109 32, 499 Reduction of anisic aldehyde .... J .... 215 Samosadsky Z. C. [2], 4, 645 vi., 175 Pencedanin (Imperatorin) ... C 6 H 4 (OMe)O.C 6 H 4 .OCH 2 Ac Ci 6 H 16 4 C 12 H 12 3 (?) 81-82 ; Hlasiwetz and A., 174 ; 67 28, 257 a. f. 74-75 Weidel Anisoin n [C(OH).C 6 H 4 .OMe] i >=(1.4)<, i) 78 109-110 Richter Roasel R. K. T. Z. C. [21 5, 562 : vi., 175 i) ^. [ J} ) f V*J J A., 151, 33 ,, . .. .... Benzoyldimethylhomopyvo- ) C 6 H 2 Me(OMe) 2 .OBz j) 113 ' 118-119 Bo'sler Hofmann B., 14, 327 B., 12, 1376 40, 421 38, 249 gallol Oxidation of dimethyltolu- quinol Anisilic acid .... MeO.C.H 5 .O.O.C,H 5 .OMe (Me.O.C 6 H 4 ) 2 .C(OH).COOH n C *H O 153 u. c. 164 Nietzki Bo'sler B., 11, 1280; A., 215, 162 B., 14, 327 34, 868 40, 421 Acetyl pyrousnetic acid C 14 H 13 Ac0 6 v -^16- LL 16 v -'5 Ci 6 H 16 7 .>. 168 Paterno B., 15, 2241 ; 42, 1080 G. I. [1882] 231 Ethylpheuylbenzylcarbinol ... Ph.CH 2 .CH(OH).C 6 H 4 Et C 16 H 18 a. 350 Sollscher B., 15, 1681 42, 1292 Cumiuylphenol .... ) 300 (700) .... .... J. [1875], 438 Acetophenonepinacone CMePh(OH).CMePh(OH) C 16 H 18 2 .... 120 Emmerling & Engler B.,4,147; 6,1005 i .... )> )) 120 Buchka B., 10, 1714 Dicresoxyethylene (CH 2 .O.C 6 H 4 Me) 2 =(1.2) 2 n .... 79 Stadel A., 217, 41 ; B., 44, 585 ; 40, 723 14, 898 )j From anethol.... =(1-4), C,.H,,OfOAc) > OHO 297 134-5 near 40 Fuchs Landolph B., 2, 625 C. R., 82, 226 ; 29, 705 ; 38, 385 14 15 \ / ^16 XJ 18^ B., 13, 148 KHO on anethol ... > .... 87 ) C. R., 81, 97 ; B., 29,246; 38,385 13, 147 COMPOUNDS CONTAINING THREE ELEMENTS. 275 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Isohydranisoin C, 6 H 18 4 110 Saytzeff Z. C. [2], 3, 679 vi., 175 Hydranisoin ... .... " .... 125 168 Samosadsky Saytzeff Z. C. [2], 4, 644 Z. C. [2], 3, 678 172 Samosadsky Z. C. [2], 4, 644 ? quinol 11 173 Nietzki B., 11, 1281 34, 869 Phthalylpinacone [CH(OH).C 6 H 4 .CH 2 OH] 2 197 Hessert B., 10, 1448 34,67 =(1.2) 2 C 16 H 18 O 5 91 Patern6 & Oglialoro G. I., 7, 189 32, 786 abt. 91 Patern6 B., 9, 346 30, 203 Hydroccerulignone [C 8 H 2 (OH)(OMe) 2 ] 2 C 16 H 18 6 190 Liebermann A., 169, 226 ; B., vii.,376; 26,71 5,746 Hydrovanilloin [CH(OH).C 6 H 3 .OH.OMe] 2 222-225 d. Tiemann B., 8, 1125 29, 75 =(1.3.4) 2 or (1.4.3) 2 see C 15 H 16 O 7 O TT O C,,H, n O, 16 18 7 abt. 180 Patern6 B., 9, 346 30, 203 Diethylic diacetoxyphthalic 13-^MO S (COOEt) 2 .(OAc) 2 =1.2.3.6 C 16 H 18 8 .... 150 Wedel A., 219, 71 46, 834 acid C 16 H 18 10 190 Eochleder J. p., 90, 433 iv., 357 Acetylostruthin .... (C 16 H 19 3 )"(?) C 1G H 00 O 220-230 i. v. 78 Gorup-Besanez Oudemanns A., 183, 330 A., 170, 261 ; B., 31, 718 27, 73 1 CujH^Oj 236-240 6, 1126 M. C., 1, 612 KHO on chloranethol 5J \'/ 268-270 1. 35 Landolph C. E., 82, 226; 29,705; 38,385 B., 13, 148 From dragon's blood C^H^O, 236-240 Liquid Botsch M. C., 1, 609 42,210 Diethylic phenylacetosuccin- COOEt.CHAc.CHPh.COOEt C 16 H 20 O 5 .... 75-76 Weltner B, 17, 71 46, 746 ate Diethylic diacetosuccino- (COOEt) 2 .(OAc) 2 .H 2 C^H^OS 168 Wedel A., 219, 71 46, 834 succinate (diacetoxydihy- =1.2.3.6.1.2 or =1.2.3.6.4.5 drophthalate) Methylic santonite C 15 H 19 Me0 3 C 16 H 22 3 81-84 Cannizzaro and B.,16,427;G.I., 44,77 Carnelutti 12, 393 11 11 .... 82 11 11 B., 12, 1574 Dibutylic terephthalate Diisobutylic terephthalate .... C c H 4 (COO.Bua) 2 =1.4 C 6 H 4 (COO.Bu0) 2 =1.4 C, 6 H 2 ,,O 4 Liquid 52-5 Berger B., 10, 1743 11 34, 152 5) Methylic santonate 86-86-5 Cannizzaro G. I., 6, 355 ; J. 31, 470 [1876], 618 ii 11 .... 86-86-5 Cannizzaro and G. I., 8, 309 ; J. 36, 331 Valente [1878], 825 metasantonate .... 101-5-102-5 11 11 11 11 11 parasantonate Bilic acid . . . . .... C 6 H 22 O 6 .... 183-184 1QO 11 11 11 11 B., 12, 1069 36, 332 36, 811 Coniferin cf. B., 16, 44 1*7 V 185 u. c. Tiemann and B., 7, 610 ,6 22 S Haarmann Lactoglucose pentacetate .... C 6 H 7 (OAc) 5 O C^H^O,, 47-51 Fudakowsky B. S. [2], 30, 433 36, 137 ,, 11 51 ; s. f. 47 B., 11, 1071 34, 777 Galactose pentacetate C 6 H 7 (OAc) 5 62-66 B. S. [2], 30, 433 36, 137 11 11 66-67; sf.62 B., 11, 1071 34, 777 Dulcitan pentacetate .... 163 c. A. C. [4], 27, 156 Antiar resin Uexyleugenol . (CHo.CH : CH 2 ).OMe.OC H C 16 H 24 9 9R_300 60 .... C. E., 84, 151 ; i., 310 31, 462 =1.3.4 or 1.4.3 16 24 2 J. [1877], 581 Tetraethylic propargylpenta- CH(COOEt),.C(COOEt).,. C 10 H 24 1(I 275-280 (188) .... Bischoff & Emmert B., 15, 1109 42, 1191 carboxylate Di^italiretin ... (CH 2 .COOH) J. [1858], 529 ii., 330 Diisobutyl diacetyl dextro- (CHOAc.COOBu3) 2 ciXX 322-326 Liquid Anschutz B., 14, 2790 42, 831 tartarate 11 11 ii B 322-324 .... Pictet B., 15, 2243 Tetraethylic ethylidene di- CHMe[CH(COOEt), ! ] :; C 16 H 26 O 10 209 (20) Liquid Kommenos A., 218, 145 46, 422 malonate 2x2 276 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. C,.H,..COOH 1 fi -tLooOn b. 18 Schiller A., 101, 252 iii., 700 Palmitolic acid Ia27 v lo 29 2 )) 42 Schroder A., 143, 27 vi., 895 Palmitoxylic acid .... CieH^O.! 64 55 A., 143, 35 vi., 896 Hexylpentylacrylic acetate ... Me(CH 2 ) 4 .C.CH 2 .OAc. CieH^Og 285-290 ; Liquid Perkin 43, 54, 63, 68 CH(CH 2 ) 5 .Me 280-290 ; 280-285 ?-acid 21 Marasse B., 2, 361 Hypogoeic acid C 16 H 2 ,,.COOH >) T .... 28 5 ,, J) 5) 33 Schroder A., 143, 22 j i> ) )J 34-35 Gossmann& Schevei A., 94, 230 iii., 238 Physetolic J) >5 .... 30 A., 91, 182 38 Caldwell and Goss- A., 99, 307 )) mann 5) 39 Schroder A., 143, 38 vi., 727 Caprylic anhydride (C 8 H 15 0) 2 C 16 H 3() O3 280-290 Liquid Chiozza A., 85, 229 i., 746 Oxyhypogceic acid .... )> 34 Schroder A., 143, 36 vi., 727 Jalapinolic acid .... 5 60-61 Keller A., 104, 63 ; 109, iii., 441 269 ,, .... )) 64-64-5 Meyer A., 95, 149 j> .... s.50 Spirgatis A., 116, 289 Condensation of isobutalde- .... (?) 190-200(100 .... Perkin .... 43, 101 hyde Diacetate of glycol C 12 H 26 O 2 C 12 H 24 (OAc) 2 Ci 6 H 31) O 4 185-190 .... 43, 95 Thapsic acid (dioctylic acid) (C 8 H 15 2 ) 2 ij .... 123-124 Canzoneri G. L, 13, 514 46, 461 Agaricic acid .... OHO 139 Jahns A. P. [3], 21, 260 46, 354 Suberylglycollic acid (C 7 H 12 .OH.COOH) 2 +H 2 O 16 30 5 C J6 H 30 O 7 see C 8 H 14 O 3 50 Dale and Schor- 39, 541 lemrner Diglycerylsebate (Sebacin) ... (C 3 H 5 ) 2 (OH) 4 (0 2 :C 10 H 16 2 ) Ci 6 H 30 O 8 .... 40 Berthelot A. C. [3], 41, 293 v., 214 Cetene oxide .... O TT f) b. 300 b. 30 Carius A., 126, 203 vi., 421 Palmitic aldehyde C 15 H 31 .CHO " V> 16- Li 32 v ^ )*y 192-193 u.c. 58-5 Kraff't B., 13, 1416 38, 867 (22) ; 239- 240 (100) 52 Dollfus J., 17, 518 Cetyl aldehyde )) )) 46-47 )> A, 131, 287 Tetradecyl methylketone ... Me.CO(CH 2 ) 13 .Me ) 230-231 (100) 43-43-5 KrafFt B., 15, 1707 42, 1272 Heptylpentylethylic acetate Me(CH 2 ) 6 .CH(CH 2 .OAc) Ci 6 H 32 O 2 275-280 L 10 Perkin B., 15, 2811 ; 16, 43, 57, 77 (CH 2 ) 4 Me 1032 Tetradecylic acetate CH 3 .(CH 2 ) 12 .CH 2 .OAc 175-5-176-5 12-13 Krafft B., 16, 1720 44, 1076 (15) Isoamylic umbellulate C 10 H 21 .COO(CH 2 ) 2 .CHMe 2 j) abt. 295 Stillmami& O'Neill A. C. J., 4, 206 4S, 1186 Diisobutylic isooctylate CHMe.(CH 2 ) 2 .Pr0 278-281 Carleton-Williams .... 35, 129 COO.CH 2 .CHMe.(CH 2 ) 2 .PrP Octylic caprylate CH 3 .(CH 2 ) 6 .COO(CH 2 ) 5 . jj 297-299 Zincke A., 152, 6 vi., 879 CHMe 2 Diheptylacetie acid .... [Me.(CH 2 ) 6 ] 2 : CH.COOH M 240-250 26-27 Jourdan A., 200, 116 38, 314 (80-90) Palmitic acid .... C,-H,,.COOH s. 55 Eeichardt A. P. [3], 10, 339 32, 518 15"^31 v ^ J) 339-359 ; 60'5 Carnelley and B., 12, 1360 35, 563 V 348 c. Williams ,, .... 5 60 Bernheimer M. C., 1, 466 42, 232 J) j 62 Heintz J., 7, 461 iv., 332 62 Schlippe J., 11, 303 ,, ,, .... .... .... )} ) 62 Fittig 35, 563 61 Duffy J., 5, 511 J) )) 62 Herrmann N. E. P., 20, 283 24, 724 ; vii., 75 5) 469 62 Eeichardt A. P. [3], 10, 339 32, 518 Jl 3) 62 Kerr L J' ' P. M. [5], xiii., 13 )) 165 COMPOUNDS CONTAINING THREE ELEMENTS. 277 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Palmitic acid .... C 15 H 31 .COOH P TT O 268'5 (100) 62 Krafft B. 12 1670 38, 34 16 32 2 215 (15) B. 16 3018 46, 572 .... 11 .... 17 Hexadecylic acid (palmitic) CH 3 .(CH 2 ) 14 .COOH 11 268-5 (100) 62 B., 15, 1687 42, 1272 (Isobutylal) 4 ... C H O (%} 134-136 Li ouid CEconomides C. R. 92 886 40, 711 Turpetholic acid .... .... 87 A., 139, 53 Monobasic abt. 88 Spirgatis J. p., 92, 97 v., 926 Dihydroxypalmitic acid .... 115 Schroder A., 143, 37 vi., 727 Dioctyl oxide.... Me.(CH 2 ) 7 .O.(CH 2 ).Me C H O 280-282 Liquid Moslii er A., 185, 56 ; B. 30, 394 9,998 Cetyl alcohol . ... .... P TT OTT a. 48 OIlCVrGll.1 JicclicrchGS sur 16s i. 841 16 33* "^ )i .... Corps Gras, 171 (ethal) .... s. 49-19-5 Heintz P. A., 84, 232 i., 841 ; v., 430 49 Schorl 6 ni in 6 1* P. R. S., 19, 22 ; vi., 421 ; vii., B., 3, 617 277 3M 50 A., 206, 352 "-T-T 50 Kerr P. M. [5], 13, 160 Triisoamylic orthoformate .... CH(O.CH 2 .CH 2 .CHMe 2 ) :( C 16 H 34 3 260-265 Pinner B., 16, 1647 44, 1089 Triisoamyl J) 265-267 .... Deutsch B., 12, 118 36, 453 Pyrene carboxylic acid C 16 H 9 .COOH C 17 H 10 O 2 .... 267 Goldschmidt and M. C., 4, 257 44, 1004 Wegscheider a-Naphthylphenyl ketone .... C IO H 7 .CO.C 6 H 6 C 17 H 12 .... 75 Grucarevic & Merz B., 6, 60 26, 635 a- )J 75-5 11 D B., 6, 1239 a- ,, .... 75 Liebermann A., 183, 225 31, 608 ; 32, 563 a- .... 75 Vincent and Roux B. S. [2], 40, 163 46, 609 a- 51 .... 77-5 Kollarits and Merz B., 6, 541 vii., 940; 26, 1035 ft- 11 11 .... 81-5 Vincent and Roux B. S. [2], 40, 163 46, 609 ft- ,1 11 82 Grucarevic & Merz B., 6, 1239 ft' !> 11 .... 82 Kollarits and Merz B., 6, 541 vii., 940 ; 26, 1035 ft- 11 1) .... 82 Liebermann A., 183, 225 31, 608 ; 32, 563 Lactone of cornicularic acid CH : cph.coo.c : CHPh i i C 17 H 12 0. : 141 Spiegel B., 15, 1547 42, 1077 a-Naphthylic benzoate C 10 H 7 .OBz .... 56 Maikopar Z. C. [2], 5, 216 vi., 859 p- .... .... 107 From hydroxynaphthoben- .... .... 114 Walder B., 16, 306 44, 666 zoic acid Benzoyl /3-methylumbellife- ( 1 , i H.,(OBz).C 1 Me : CH.CO.O i i C,,H 12 4 .... 159-160 Pechmann and B., 16, 2124 46, 66 rone Duisberg Acetoxymethylanthra- C 14 H 6 :0 2 .Me.OAc .... 177 Roemer and Link B., 16, 702 44, 1139 quinone Acetylsantonic acid C 15 H 9 Ac0 4 C 17 H 12 O 5 .... 139-140 Sestini G. I. [1875], 121 28, 895 Alpinin C H O 179 174. Jahns B., 14, 2810 42, 866 Acetyl emodin C 14 H 4 .Me : O 2 .(OH) 2 .OAc -17 J- .... L i t 1 i * 179-180 Liebermann A., 183, 162 31, 610 ,, ,, 180 B., 8, 971 29, 252 Diacetyl euxanthone p.C r ,H 3 (OAc).CO.C (i H ;i (OAc) ,i .... 185 Salzmann and B., 10, 1402 34, 80 Wichelhaus Dibenzylidene acetone CO.(CH : CHPh), C 17 H 14 .... 112 Claisen & Claparede B., 14, 350 40, 422 i> 11 112 Claisen B., 14, 2470 a-Naphthylphenylcarbiuol .... C U1 H ; .CH(OH).C 6 H, a. 360 86-5 Lehne B., 13, 359 38, 478 a-Naphthyl benzyl oxide C 10 H 7 .O.CH 2 Ph 320 d. Liquid (?) Stwdel A., 217, 48 44, 586 ft- .... 99 Stadel A., 217, 47 ; B., 44, 586 ; 40, 14, 899 724 Hydrocornicularic anhydride CHPh : C.CH,.CHPh.CO.O i " i C,,H M 0. .... 116-117 Spiegel B., 14, 1691 40, 1036 Isodihydrocornicularic anhy- CH.,.CHPh.COO.C : CHPh 102-105 B., 15, 1547 42, 1077 . i " j dride Ethylic anthracene carboxy- C 14 H 9 .COOEt ?J .... 134 Liebermann and B., 13, 49 38, 400 late Bischoff " " " .... 134-135 Bornstein B., 16, 2609 46, 330 278 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Isatronic acid.. . C 1B H,,.COOH C^I-U-I i\Sc> 156-157 Fittig A., 206, 57 ; B., 40, 427 ; 38, Atronic acid .... .... 16^^13 WJ-MI 17^^14 2 164 12, 1741 A., 206, 50 120 40, 426 JJ >J 163 B., 12, 1742 38, 121 From bromcinnamic acid .... )* JJ> )J .... 127 Leuckart B., 15, 20 42, 615 Cornicularic acid OPh(COOH) :CH.CO.CH 2 Ph C 17 H 14 O 3 115 Spiegel B., 15, 1547 42, 1077 Phenanthrene quinacetone ... .... jj .... 89-5-90 ; Japp & Streatfield B., 16, 283 41, 273, 275 88-89-5 Acetoxyphenylcinnamic acid (OAc).(CH:CPh.COOH) =1.2 C 17 H 14 4 d. 170 180 Oglialoro G. I., 9, 428 38, 164 ) =1.4 JJ 170 )> G. I., 13, 173 46, 176 Ethylic benzhydrylisophtha- COO.CHPh.C 6 H 3 .COOEt JJ .... 114-115 Blatzbecker B., 9, 1764 31, 469 late anhydride Ethylchrysin 146 Piccard B., 10, 177 32, 342 Diacetoxybenzophenone CO(C 6 H 4 .OAc) 2 =1.2 ; 1.4 51 C j; H 14 O 5 .... 84-85 Michael A. C. J., 5, 81 46, 311 =1.2 ; 1. ? jj .... 87-88 B., 14, 657 40, 592 =1.?; 1.4 89-90 Stedel A., 218, 339 44, 992 J )J > .... 89-90 Stadel and Sauer B., 13, 836 38, 646 )! )! = (1-4)2 jj 148 Bayer and Burk- B., 11, 1300 34, 886 hardt 1> )) )! jj 152 Gail A., 194, 336 36, 326 Dimethylic benzoylisophtha- C 6 H 3 Bz.(COOMe) 2 =n.3 jj .... 117-118 Blatzbecker B., 9, 1763 31, 469 late benzoylterephtha- =?.1.4 sj .... 100-101 .... J. [1878], 403 late Benzoylcumidic acid Me 2 .Bz.(COOH) 2 =1.2.3.4.5 jj .... 85 J. [1879], 562 Diphenylethanetricarboxylie .... C 17 H 14 O 6 .... 253-255 Haiss B., 15, 1480 42, 1071 acid Ethylic phenylcinnamate .... Ph.CH : CPh.COOEt Cl7H 16 O 2 Liquid Oglialoro G. I., 8, 429 ; J. 36, 640 [1878], 821 Tetrahydrocornicularic anhy- O.CO.CHPh.CH 2 .CH.CH 2 Ph J) 69-71 Spiegel B., 14, 1692 40, 1037 dride Distyrenic acid abt. 50 Erdmann A., 216, 182 44, 475 Hydrocornicularic acid CH 2 Ph.CH(OH).CH 2 .CHPh. C 17 H 16 3 134 Spiegel B., 14, 1690 ; 15, 40, 1036 COOH minus 2H 1548 Ethylictoluylbenzoate Me.C 6 H 4 .CO.C f .H 4 .COOEt .... 68-69 Friedel and Crafts C. B., 92, 833 ; 40, 732 =1.4; 1.2 B. S., 35, 505 Benzoyleugenol (CH 2 .CH : CH 2 ).OMe.OBz j> a. 360 50-55 Cahours A. C. [3], 52, 201 ii., C05 =1.3.4 ,, 15 J j> .... 69-70 Tiemann & Kraaz B., 15, 2067 Benzoylisoeugenol (CH : CHMe).OMe.OBz >j 159-160 i> B., 15, 2068 =1.3.4 Pseudocumene phthaloic acid C 6 H 2 .Me 3 .CO.C 6 H 4 .COOH j 146-5 Meyer B., 15, 638 42, 848 =1.3.4; 1.2 Mesitylene phthaloic acid .... =1.3.5; 1.2 i> 212-212-5 Grisley and Meyer B., 15, 639 42, 848 Propylene dibenzoate CH 3 .CHOBz.CH 2 OBz C 17 H 16 4 240 (12-14) Friedel and Silva C. R, 73, 1379 ; vii., 1021 ; 25, Z. C. [2], 7, 490 135, 296 V J) CH 2 .(OBz).CH 2 .CH 2 .OBz > .... 53 Eeboul C. R, 79, 169 ; 27, 1153 ; 36, \ A. C. [5], 14, 500 133 C 3 H c (OBz) 2 jj vol. a. 300 72 Mayer B. S. [2], 2, 451 vi., 309 Monethylic diphenylsuccinate COOEt.CHPh.CHPh. COOH t> 140 Franchimont B., 5, 1050 26, 391 Diacetoxydiphenylmethane.... CH 2 (C 6 H 4 .OAc) 2 =1.4 ; 1.? j> 69-70 Beck A., 194, 324 36, 325 Benzoic acetone ether .... 5 230-240 (10) 69-71 A., 145, 195; As., 6, 361 Acetyl-lapachic acid C 10 H 4 (C 6 H 9 )(OAc):0 2 > 82-83 Paterno B., 16, 801 ; G. I., 44,211 12, 337 Diethyleuxanthone C 13 H 6 Et 2 4 J) .... 126 Gnebe and Ebrard B., 15, 1678 42, 1301 Acetyl hydrocoto'iu Cubebin C 15 H 13 Ac0 4 C 17 H 16 O 5 0} .... 83 120 Jobst and Hesse Schuck A., 199, 60 N. B. P., 1, 213 38, 328 ii., 171 From orcinol .... C H O 2 )' \'/ 245 Wittenberg J. p. [2], 26, 70 42, 1290 /3-Acetoxynaphthoic aldehyde 31 30 9 C 10 H 6 (OAc).CH(OAc) s C I7 H 15 6 124 Kauffmann B., 16, 684 44, 1136 diacetate =f3, 2 ; or ,<>, COMPOUNDS CONTAINING THREE ELEMENTS. 279 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Santalin See C 15 H 14 5 C 17 H 16 O n .... 104-105 Franehimont and B., 12, 14 36, 470 Sicherer Evernic acid .... C^H.A 164 Stenhouse A., 68, 84 ; it., 611 ; vii., I/ In / P. R. S., 18, 22 496 Cymylphenyl ketone C 6 H 6 .CO.C 8 H 3 MePr C 17 H 1S abt. S40 l.f. m. Kollarits and Merz B., 6, 546 26, 1036 11 abt. 340 .... Grucarevic & Merz B., 6, 1244 vii., 940 Dixylyl ketone CO(C 6 H 3 Me,) 2 340 1. 60 Ador and Rilliet B., 11, 399 34, 498 Durylphenyl ketone C 6 H 5 .CO.C 6 HMe 4 343-343-5 119 J. [1879], 372, 56 Benzyl ic methylbenzy lacetate C 6 H 5 .CH 2 .CHMe.COO. C 17 H 18 O 2 53 (sic) Liquid Conrad B., 11, 1057 34, 732 CH 2 Ph 11 n 320-325 .... A, 193, 313 Ethylic tolylphenylacetate ... CH 3 .C 8 H 4 .CHPh.COOEt .... 34 Tanisch B., 10, 997 32, 618 =1.4 Benzoxyisobutylbenzene ... C 8 H 4 .C 4 H 9 .OBz 335 u.c. 83 Studer B., 14, 2187 ; A, 41, 176 211, 246 u-ditolylpropionic acid (C 6 H 4 Me) 2 .CMe.COOH .... 151-152 Botfcinger B., 14, 1596 40, 1035 11 11 )? .... 151-152 Haiss B., 15, 1474 42, 1071 Benzoxyisocymene C 6 H 3 .Me.Prp.OBz = 1.3.? .... 73 Kelbe A., 210, 42 42, 301 Methylic dibenzylglycollate (C 6 H 5 .CH 2 ) 2 .C(OH).COOMe C 17 H 18 O :l .... 71 Spiegel B., 14, 1687 Diethoxybenzophenone (EtO.C 8 H 4 ) 2 .CO=(1.4) 2 .... 131 Beck B., 10, 1840 34, 421 11 11 11 131 Gail A, 194, 334 36, 326 Benzylraethyl phenoxy Ph.CH 2 .C 6 H 3 Me.O.CHMe. .... 115 Mazzara B., 15, 1758; G.I. 42, 1072 a-propionic acid COOH = ?.1.4 [1882], 261 Ethylic ethylenephenol PhO.C 2 H 4 .O.C 6 H 4 .COOEt C 17 H 18 O 4 .... 81 Wagner J. p. [2], 28, 199 46, 437 p-oxybenzoate Decarbusnein .... C 17 H 18 O 6 175 J. [1875], 613 Acetyl decarbusnic acid C 15 H 15 Ac0 6 .... 147-148 Patern6 G. I. [1882], 231 42, 1080 Resin from dragon's blood .... .... C 17 H 19 O 5 (*zc) .... abt. 100 Dobbie & Hender- P. J. T. [3], 14, 46, 462 son 361 Benzylthymol C 8 H 2 .OH.Me.Pr<'.CH 2 Ph C 17 H 20 O 255 (8) 1. f. m. Mazzara G. L [1881], 346 42, 172 = 1.3.6.? Diethoxydiphenylmethane .... CH 2 (C 6 H 4 .OEt) 2 = (1.4)., CuHsoO, .... 38-39 Beck A, 194, 323 36, 325 Ethylic a-triethoxycinna- C 6 H 2 (OEt) 3 .(CH:CH.COOEt) C 17 H 20 O 4 230 51 Will B., 16, 2110 46, 68 mate 11 "~ 11 360 75 B., 16, 2109 11 Diacetyl fvaxitannic acid .... C 13 H 12 (OH) 2 (OAc) 2 3 C^H^Oj .... 100 + 5intl and Reinitzer M. C., 3, 753 44, 217 Patellaric acid C 17 H 20 10 .... a. 100 d. .... J. [1869], 768 Ethylic cinnamyl diethylace- Ph.CH : CH : CO.CEt 2 .COOEt CuH^Oa 101 Claisen & Matthews A, 218, 170 46, 444 tate 11 11 11 J) 200-205 (3) 101-102 Matthews 43, 205 Podocarpic acid C 8 H 2 .(C 9 H 15 ).Me.OH.COOH d. 330 187-188 Oudemanns A, 170, 213 ; B., 27,72 6, 1123 Acetylhydrosantonide ' .... .... C^HjA .... 204-204-5 I!annizzaro G. I., 6, 341 31, 471 Diethylic benzylacetosucci- COOEt.CH 2 .CAc(CH 2 Ph). C 17 H 22 O 5 310 .... Conrad B., 11, 1058 34, 733 nate COOEt Acetylsantonic acid .... C 15 H 19 Ac0 4 139-140 .... J. [1875], 608 Ilixanthin ^! H O 215 d. 198 Moldenhauer A., 102, 346 ii., 244 Ethylic santonite C 15 H 19 3 .Et " C^'A 117 Cannizzaro and B., 12, 1574 Carnelutti 11 11 .... '> 5J ,, 116-117 11 11 G. L, 12,393; B., 44,77 16, 427 isosantonite .... 125 11 11 n 11 5) 11 .... 117 ? 11 11 J. [1880], 895 Ethylsantonous acid ft 118 11 11 B., 12, 1574 ,i 11 V ., .... 115-5-110 11 11 G. L, 12, 393; B., 44,77 16, 427 Ethylisosantonous acid )> 143 11 11 Diuiethylic photosantonate .... C 17 H 24 4 51-52 Sestini G. L, 6, 357 1,472 11 1! .... 56-5 n 11 Ethylic santonate .... 88-89 11 G. I., 6, 148 1, 90 i, 11 94-95 annizzaro & Valente | T. I., 8, 309 6, 331 280 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylic parasantonate .... C 17 H 24 O 4 .... 172 Cannizzaro & Valente G. I., 8, 309 36, 332 Ethylsantonic acid ( , .... b. 100 Sestini G. I. [1875], 121 28, 895 Acetylaserpetin C 15 H 21 Ac0 4 C 17 H 24 5 .... 113 Kulz A. P. [3], 21, 161 46, 182 Ethylic tetracetylquinate ... C 6 H 7 (OAc) 4 .COOEt C 17 H 24 O 10 135 Hillebrand&Fittig B., 10, 523 ; A., 32, 488 ; 36, 193, 195 159 Phellylalcohol (cerin) .... C 17 H 28 100 Siewert Z. C. [2], 4, 383 vi., 496 Diisoamyl benzylal C 6 H 5 .CH(OC 5 H,,) 2 C I7 H 2S O 2 292 c. .... Wicke A., 102, 364 i., 578 Santalol acetate C 16 H 25 (OAc) 298 Chapoteant B. S., 37, 303 44,76 Stearolic acid C H O 72 Cloez C. R., 82, 501 30, 102 I 17 ,r .... 46 Limpach A., 190, 294 34, 403 Margarolic acid .... ^ .... 48 Cloez C. R., 82, 501 30, 102 Butenyl butylvalerone (?) .... C 17 H 32 (?) 279-285 Geuther, Frblich, A., 202, 288 38, 623 and Looss Ethylic cimicate Cj.H^COOEt C 1? H 32 O 2 .... b. Carius A., 114, 153 i., 964 Diheptylic malonate CH 2 .(COOC 7 H 15 ) 2 C 17 H 32 4 263-265 Liquid Venable B., 13, 1651 40,82 Diamylic pimelate C 5 H 10 (COOC 5 H n ) 2 170-200 .... Marsh A., 104, 125 iv., 647 Roccellic acid C 1S H 30 .(COOH) 2 132 Hesse A., 117, 336 v., 113 Methyl dihepty Icarbin ketone Me.CO.CH[(CH 2 ) 6 Me] 2 C 17 H 34 300-304 Liquid Jourdan A., 200, 115 38, 314 Pentadecyl methyl ketone .... MeCO.C 15 H 31 > 319-320 48 Krafft B., 12, 1671 38, 34 Me.CO.(CH 2 ) 14 Me 242 (100) 48 B., 15, 1710 42, 1272 Ethylic isocetate .... .. C 14 H 29 .COOEt Ci 7 H 34 O 2 .... s. 21 Bouis C. R., 39, 923 iii., 414 Methylic palmitate C 15 H 31 .COOMe n .... 28 Berthelot J., 6, 502 iv., 334 Metamargaric acid C 16 H 33 .COOH 50 Fremy A. C. [2], 65, 121 iii., 976 Margaric acid 52-3 Duffy J., 5, 511 >! 11 i> .... 59 Ebert B., 8, 775 30, 110 277 (100) 59-8 u. c. Krafft B., 12, 1675 38, 34 .... 59'9 u. c. Heintz P. A., 102, 272 iii., 852 ,, .... 60 Chevreul > .... 60 Hanhart J., 11, 301 Hydroxymargaric acid C 16 H 32 (OH).COOH Ci7H 34 O 3 80 Ebert B., 8, 775 30, 110 Isoamylic diisamoxalate CKC 5 H n ) 2 OH.COOC 5 H n 280-290 .... A., 142, 17 Tetraisobutylic orthocar- C(O.CH 2 .CHMe 2 ) 4 C 17 H 36 O 4 244-9 c. Rose A., 205, 253 40, 252 bonate Triglycerol tetraethylin .... C 17 H 36 7 250-260 (10) .... A. C. [3], 67, 31 1 Chrysoquinone C 6 H 4 .CO.CO.C 10 H 6 C 18 H 10 O 2 ... abt. 220 Lieberraann A., 158, 309 vii., 337 ; 24, 1 1 693 .... " .... 235 Schmidt J. p. [2], 9, 284 27, 989 Pulvic anhydride c~: cph.coo.c : CPLCOO C 18 H U) O 4 120-121 Spiegel B., 13, 1630 40, 97 i i Dibenzoylsuccinyl dilactone c:cph.o.co.c:cPh.o.co .... 254-255 Baeyer and Perkin B., 17, 62 46, 839 Diphthalylethylene (C 6 H 4 :(co) 2 :cH) 2 =(i.2) 2 a. 350 Gabriel & Michael B., 10, 1560 34, 230 Dihydroxychrysoquinone .... a .... 305-310 C'laus B., 8, 158 28, 760 (Chrysezarin) Naphthoylbenzoic acid C 10 H..CO.C 6 H 4 .COOH=1.2 C 18 Hi 2 O 3 173-5 Ador and Crafts C. R., 88, 1355 36, 940 Acetoxyquinone of C 16 H ]2 .... C 16 H 9 (OAc):0 2 C 18 H I2 O 4 .... 110-111 Breuer and Zincku B., 11, 1996 36, 327 Dehydrobenzoylacetic acid .... .... 171-172 Baeyer 'and Perkin B., 17, 64 46, 839 Carboxycornicularic acid CH:cph.coo.c:cPh.cooH ;; .... 215 Spiegel B., 15, 1547 42, 1076 i i lac tone Hyd roxy naphthoy Ibenzoic COOH.C 6 H 4 .CO.C 10 H 6 .OH B .... 256 Walder B., 16, 299 44, 666 acid =1.2 ; a, /3 Pulvic acid O.CO.CPh : C(OH).C '. CPh. Ci S H 12 O 6 214-215 Spiegel B., 13, 1631 40, 97 COOH Lactone of dibenzoyl succinic CHBz.COO.CPh : C.COOH .... 230 d. Baeyer and Perkin B., 17, 59 46, 838 1 1 acid CH 2 .CO.C 6 H 4 .CO, Ethylene dibenzoyl dicar- boxylic anhydride 1 )0=(1.2) 2 CH 2 .CO.C 6 H 4 .OK " .... 228-230 Gabriel & Michael B., 10, 2207 34, 427 Calycin 240 u. c. Hesse B., 13, 1817 40, 180 COMPOUNDS CONTAINING THREE ELEMENTS. 281 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diacetoxyanthraquinone c 6 H 4 :(co) 3 :c 6 H 2 (OAc) 3 C 18 H 12 O 6 .... 160 Perkin .... 26, 22 =2.1 ; 1.2.3.4 11 11 11 11 .... 179-183 Baeyer B., 9, 1232 11 =2.1; 1.2.3.5 n .... 183-184 Liebermann A., 183, 215 31, 613 i. 11 11 11 .... 183-184 Liebermann and O. B., 8, 974 29,248 Fischer 11 =1.2; 1.2.3.6 .... 200 Liebermann & Giese B., 8, 1648 11 C 14 H 6 (OAc) 2 :0 2 n .... 184 Faust A., 165, 235 vii., 534; 26, 504 11 AcO.C 6 H 3 : (CO) 2 : C 6 H 3 .OAc .... 175; 180 Perkin .... 29, 854 = ? 11 1' 11 dbt. 195 Schunck & Eoemer B., 9, 382 30,89 11 =5.2.1; 1.2.4 11 .... 199 11 11 B., 11, 972 36,68 =4.2.1; 1.2.5 11 .... 227 B., 9, 382 30, 89 'i 11 n abt. 228 Liebermann and 0. B., 8, 974 29, 248 Fischer 11 11 11 11 228-229 Perkin 26, 21 vii., 87 =3.2.1; 1.2.3 11 .... 226-230 Liebermann A., 183, 145 31, 612 or 4.2.1 ; 1.2.3 11 11 n 226-230 Liebermann & Giese B., 8, 1643 29, 712 11 11 11 .... 227-23% Liebermann B., 12, 186 36, 538 11 =3.2.1; 1.2.6 11 .... 244-245 Liebermann & Boeck B., 11, 1616 36, 258 n 11 11 11 245 d. Schunck & Eoemer B., 11, 1178 34, 985 Dibenzoxysuccinic anhydride CO.(CHOBz) 2 .CO.O C 18 H 12 O 7 .... 174 Anschiitz & Pictet B., 13, 1178 38, 876 i i Diacetylflavopurpurin 11 238 Schunck & Bosmer B., 10, 1822 34,322 Benzyl naphthylketone C S H 5 .CH 2 .CO.C 10 H 7 C 18 H 14 57 Grsebe & Bungener B., 12, 1078 36, 807 From dehydrobenzoylacetic Acid? 145-150 d. Baeyer and Perkin B., 17, 65 46, 839 acid Cinnamic anhydride (Ph.CH : CH.CO) 2 O C 19 H 14 O 3 127 Gerhardt A. C. [3], 37, 285 i., 989 Acid from dehydrobenzoyl- .... .... 112 Baeyer and Perkin B., 17, 59 46, 839 acetic acid Hydroxynaphthyltoluic acid COOH.C 6 H 4 .CH 2 .C 10 H 6 .OH .... 261 Walder B., 16, 304 44, 666 Phenoquinone (cf. B.,12,1981) C 6 H 4 (O.OPh) 2 =1.4 (?) C 18 H 14 4 71 Wichelhaus B., 5, 249, 846 25, 482; vii., 1037 Phenanthranol diacetate C 6 H 4 .C 6 H 4 .C(OAc).C(OAc) C 18 H 18 O 4 202 Grsebe A., 167, 149 26,895; vii., 94 1 1 Diacetoxyanthracene(diacetyl AcO.C 6 H 3 :C 2 H 2 :C 6 H 3 .OAc C 18 H 14 4 .... 184 Liebermann B., 12, 186 36, 537 chrysazol) =3.2.1; 1.2.3 or4.2.1; 1.2.3 (diacetyl =3.2.1; 1.2.6 .... 196-198 Liebermann&Boeck B., 11, 1616 36, 258 rufol) (diacetyl =4.2.1 ; 1.2.5 .... 254-255 Schiiler B., 15, 1809 44,74 flavol) Acetoxyanthranol acetate .... C 6 H 4 : C 2 H(OAc) : C 6 H 3 .OAc 155 Liebermann & Simon B., 14, 1264 40, 823 Pyrenequinol diacetate C 14 H 8 (OAc) 2 ,, .... 166-167 Goldschmidt M. C., 4, 309 44, 870 Ethylene benzhydryl car- (CH,.CH.C fi H 4 .COO) 2 =(1.2) 2 J? .... 208-210 Gabriel & Michael B., 10, 2209 34, 428 i i bonic anhydride Hydrocoxunarin .... 222 Zwenger As., 8, 32 vii., 657 Polyporic acid .... a. 300 .... A., 187, 177 ; 195, 365 Na on phenylic acetate .... .... 138 Perkin and Hodg- .... 37, 489 kinson CH 2 : CH.C(cooH) : CH. 295 Japp & Streatfield B., 16, 279 43, 31 C 6 H 4 .C 6 H 4 .COOH Diacetoxydesoxyanthraqui- AcO.C 6 H 3 : C 2 H 2 I O 6 H 3 OAc C.H.A .... 173 Roemer and Sch- B., 15, 1044 42, 975 none warzer Ethylene diphthaloic acid .... (CH 2 .CO.C 6 H 4 .COOH) 2 C 18 H 14 O 6 .... 165-5-166-5 Gabriel & Michael B., 10, 1561 34, 230 =(1.2) 2 Diacetyl gentisin C 14 H 3 5 Ac 2 C 18 H 14 O 7 .... 196-196-5 Hlasiwetz & Haber- A., 175, 74 28, 572 mann Acetylhiematein C 16 H n (OAc)0 5 (?) (?) .... 216-219 pd. Erdmann & Schulz A., 216, 232 44, 350 2 o 282 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Dibenzoxysuccinic acid COOH.(CHOBz) 2 .COOH C 18 H I4 8 .... 132 Pictet B., 15, 2242 jj jj +Hj,0 JJ .... 90 Pyrogalloquinone C 6 H 4 .[O.O.C 6 H 3 (OH) 2 ] 2 , .... a. 200 Wichelhaus B.,5, 848; A., 163 26, 172 ; vii., 162 1030 JJ jj .... a. 200 Loew J.p. [2], 15, 324 32, 477 Diacetylgardenic acid C 14 H 8 Ac 2 6 abt. 244 d. Stenhouse & Grove 200, 320 35, 694 ? phenol .... C 18 H 16 270-300 (60) .... Hodgkinsou 37, 483 ? .... C 18 H 18 O 2 250 (60) Liquid jj 37, 482 Cinnylic cinnamate (styracin) C 6 H 5 .CH : CH.COO.C 9 H 9 .... 38 Kopp Co. C. [1850], 14 1., 986 jj jj jj jj .... 40-41 Schroder B., 13, 1072 jj jj jj .... 44 Miller E. P., 24, 1 jj jj 11 jj 44 Toel A., 70, 1 i., 986 jj jj jj ji .... 44 Scharling A., 97, 91, 188 )J From oxidation of retene ... .... jj 222 Ekstrand A., 185, 75 32, 499 ? C 16 H 13 Ac0 2 C 18 H I6 3 .... 103 Japp B., 12, 1307 35, 527 Diacetoxy phenylethylene ... CH 2 :C(C 6 H 4 .OAc) 2 C 18 H 16 O 4 213 ter Meer B., 7, 1203 28, 158 j3-Isatropic acid C 16 H 14 .(COOH) 2 206 Fittig A., 206, 38 40, 426 ft- .... .... 205-206 B., 12, 1743 38, 121 O" ,, ,, ., .... 196-198 Pesci G. I. [1881], 538 - !> JJ .... .... 200 Kraut A., 148, 246 vi., 250 - OOOH.^/ \ CH j, .... 237 Fittig B., 12, 1743 38, 121 CPh\_ p /COOH -O 6 J 4 o- C 16 H 14 .(COOH) 2 .... 2S7-S37-5 A., 206, 36 40, 425 o- ,, ,, /riTT \ PHATT /W-^a/aX OTI v^vxV/JJ.. / \^.tL. .... 240 Fittig and Wiirste A., 195, 167 36, 371 CPh\ rT ,. /COOH ^64 Diethoxyanthraquinone (from c 6 H 4 :(co) 3 :c 6 H 2 (OEt) 2 .... Liquid Schiitzenberger B., 15, 1798 alizarin =2.1 ; 1.2.3.4 jj ,. (from =2.1 ; 1.2.3.5 170 Plath B., 9, 1204 31,87 xanthopurpurin) u u (from EtO.C 6 H 3 :(CO) 2 :C 6 H 2 .OEt= ... 193-194 Schunck andEoemer B., 9, 383 30,89 isoanthraflavic acid) jj jj (from =4.2.1 ; 1.2.5 232 u jj n anthraflavic acid) Action of Ca (HO) 2 on phenol .... C 18 H 16 O 5 .... 159 d. Erhart A. P. [3], 8, 481 34, 316 Diacetoxy-o-tolylphenyl .... n .... 148-150 A., 179, 197 ketone Hydrocoumaric anhydride .... [HO.C 6 H 4 .(CH 2 ) 2 .CO] 2 .... 222 As., 8, 36 =(l-2) 3 Mellilotic coumarin .... 128 .... A., 126, 257 Triacetoxydiphenyl C 6 H 4 (OAc).C 6 H 3 .(OAc) 2 C 18 H 16 O 6 100 Hodgkinson and .... 43, 170 = 1.2; 1.2. (42) Matthews Carbnsnetic acid C 19 H 16 O 8 2 Ci S H 16 7 193-195 Salkowski B., 8, 1460 .... 195-4 c. Eichter E. K. T. u 195-197 Spica B., 16, 427 Tetramethyl rufigallic acid .... C I4 H 2 (OMe) 4 (OH) 2 ;(CO) 3 C 18 H 16 8 abt. 220 Klobukowsky B., 10, 885 32, 619 Iso-butyl oxanthrol C 6 H 4 .CO.C 6 H 4 .C(OH)(C 4 H 9 ) C 18 H 18 2 130 Liebermann and B., 14, 462 40, 609 Walder Diethoxyanthracene (diethyl- EtO.C 6 H 3 : C-ft : C c H 3 .OEt 229 Schuler B., 15, 1809 44, 74 flavol) =4.2.1 ; 1.2.5 Diethylcarbobenzoic acid .... .... M .... 100 Limpricht and A., 155, 67 Schwanert .... .... j) ... 102 .... A., 184, 164 jj .... B 132 Limpricht and A., 155, 67 Schwanert Eetenic acid Eksfcrand A.. 185 111 ; B. 9 . . j) .... HUB ' dLt 855 Methylic hydrocornicularate .... C, 8 H 13 3 67-68 Spiegel B., 14, 1691 40, 1036 Pyroguajacol HO.C,oH 10 .O.C 6 H .OH . . 1 ftfl'^ 11 f -ry- W. A. [18811 464 4O 1 9 Jj io\J O U.L. ^Uj OLZ/ Duroyl benzoic acid C 6 HMe 4 .CO.C 6 H 4 .COOH J) .... a. 260, Friedel and Crafts C. E., 92, 833 40, 732 COMPOUNDS CONTAINING THREE ELEMENTS. 283 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Isohydrobenzoin diacetate ... C 14 H 12 (OAc) 2 CisH J8 O 4 .... 113 Limpricht and A 160, 177 26, 137 Schwanert 11 11 J) 11 .... 116 11 > 11 11 JJ i) .... 116 Ammann A, 168, 77 26, 1140 )) 11 11 117-118; 11 Z. C. [21 7, 83 ; 24, 385 ; vii., a.f. 105-106 A., 168, 77 171 '1 )) 11 .... 117-118 Forst and Zinck6 B., 7, 1708 28, 454 ,. 11 .... 120 Limpricht and A., 145, 330 vi., 1108 Schwanert Hydrobenzoin diacetate n .... 133-134 Ammann A., 168, 73 26, 1140 11 >! )> 11 134 Forst and Zinck6 B., 7, 1708 ; A., 28, 454; 30, 182, 275 635 ) 11 135 Limpricht and A., 160, 275 25, 138 ; vii., Schwanert 172 11 ) CHPh(OAc).CHPh(OAc) 11 .... 134-135 Paal B., 16, 637 44, 806 Dibenzylic succinate COOCH 2 Ph.(CH 2 ) 2 .COO 11 .... 41-5-42-5 Zanna & Guareschi B., 14,2242; G.I. CH 2 Ph [1881], 255 Ethylic diphenylsticcinate .... COOEt.CHPh.CHPh.COOH 11 .... 140 Franchimont B., 5, 1050 Dibenzylacetoxyacetic acid.... (C 6 H 5 .CH 2 ) 2 .C(OAc).COOH 11 .... 106 Spiegel B., 14, 1688 40, 1036 Diethylic diphenate (C 6 H 4 .COOEt) 2 =(1.2) 2 .... 42 Hummel A, 193, 128 36, 165 11 11 .... =U-4) 2 11 .... 112 Doabner A, 172, 121 27, 893 Dibenzylethylene dicar- (CH 2 .CH 2 .C 6 H 4 .COOH) 2 n 196-198 Gabriel & Michael B., 10, 2208 34,428 boxylic acid =(1.2) a Hydropolyporic acid .... 11 .... 162-163 .... A., 195, 366 Besin from Draccena 11 .... abt. 80 Dobbie and Hen- P. J. T. [31 14, 46, 463 derson 361 Alorcinic anhydride [C 6 H 2 (OH)Me 2 .CO] 2 O CigHisOs .... 138 Weselsky B., 5, 168; A., vii., 53; 26, 167, 65 1039 Dipropionyl rhamnetin C 12 H 8 O 3 (O.CO.CH 2 .CH 3 ) 2 Ci 8 H 18 O 7 .... 158-162 Liebermann and A, 196, 320 ; B., 36, 272 Hermann 11, 1618 /3-Usnic acid (cladonic acid).... .... 11 175 Hesse A, 117, 346 34, 882 ; v., 970 ; vii., 353 &- 11 ,, .... 11 175 Stenhouse P. R. S., 18, 222 vii., 1194 - )! I) .... 11 195-197 Spica G. I., 12, 431 44,80 "- 11 n .... 11 .... 195-197 Paternd B., 9, 345 30, 202 a- ,1 i> .... 11 195-197 Patern6 & Oglialoro G. I., 7, 189 32, 786 "- ,t .... 11 .... 200 Knop A, 49, 104 v., 970 "- 11 abt. 200 Hesse 34, 882 a- n .... 11 201-8 11 A, 137, 241 vi., 413 - ,. 11 .... 203 n A., 117, 344 v., 970 - )i Catechin n W3 140 Stenhouse Etti P. R. S., 18, 222 M. C., 2, 547 vii., 1194 42, 67 Querciglucin .... . .. *syr*w*l 174 B. S., 33, 585 Hexamethylic mellitate C 6 (COOMe) 6 ^18 18 9 Ci 8 H, 8 O 12 139-140 A, 177, 273 11 11 )) 187 .... J. [1862], 281 Isobutylhydranthraiiol C 6 H 4 .CH 2 .C 6 H 4 .C(OH).C 4 H 9 Ci 8 H 20 O .... 71-72 Liebermann A, 212, 103 42, 862 Ethylic dibenzylacetate (C 6 H 5 CH 2 ) 2 .CH.COOEt ^18^2oO 2 a. 300 Liquid Sesemann I. D., Zurich 28, 74 11 11 )) 11 a. 300 Liquid Merz and Weith B., 10, 759 32, 617 Benzylic dimethylbenzyl- C 6 H 5 .CH 2 .CMe 2 .COOCH 2 Ph 11 200-210(40) ; .... Hodgkinson A, 201, 171 33, 498 acetate 280 -285 p. d. (760) phenylvalerate C 4 H 8 Ph.COOCH 2 Ph 11 330-340 .... A, 193, 318 n n 11 240-250(120) .... Conrad and Hodg- B., 10, 254 31, 590 kinson (?) 11 250 (60) Liquid Hodgkinson 37, 482 Benzylisobutylbenzoic acid.... 11 .... 172 Zinin B., 10, 1737 34, 153 Ethylic dibenzylhydroxy- (C 6 H 5 .CH 2 ) 2 .C(OH).COOEt CigHjoO, .... 45-5 .... A., 113, 73 acetate From Sequoia gigantea .... 11 227-230 Liquid Lunge and Stein- B., 14, 2205 42,208 kauler Alcoholate of C 16 H 14 2 C]6H I4 O 2 .C 2 H 6 O 11 .... 77 Japp B., 12, 1307 35, 527 2 o 2 284 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Benzoxydimethoxypropyl- C 6 H 2 .C 3 H 7 .(OMe) 2 .OBz C 18 H 20 4 .... 91 Hofmann B.. 11, 331 34,417 benzene Diphenylcarbinol amyl oxide Ph^CH-O-CsH,! C 18 H 22 O 310 Liquid Friedel & Balsohn B. S. [2], 33, 340 38, 559 Benzylmethoxycymene C 6 H 2 .CH 2 Ph.Pr.Me.OMe 89-90 G. I., 11, 433 Diethoxyditolyl (C 6 H 3 .Me.OEt) 2 C 18 H 22 2 .... 156 Sclmltz B., 17, 468 46, 903 Hexmethoxydiphenyl C 15 H 4 (OMe) 6 C 18 H 22 O 6 .... 126 Ewald B., 11, 1623 36, 253 Tetraethylic pyi-omellitate .... C 6 H 2 (COOEt) 4 =1.2.4.5 C^H-jjOg 53 Baeyer As., 7, 36 vi., 812 Murrayin C 18 H 22 O, 170 Bias B., 9, 693 30, 421 no Hoffmann A. P. [3], 14, 139 36, 468 Carotin C 18 H 24 O 167-8 Husemann A., 62,380; 117, i., 806 200 Methylic podocarpate C 18 H 24 O 3 174 A., 170, 223 Allylic santonate .... C 18 H 24 O 4 54-55 Carnelutti & Nasini B., 13, 2209 40, 181 Hydrocotone .... C H O 243 48-49 Jobst and Hesse A., 199, 47 38, 327 Waldivin C 1S H 24 O 10 230 d. Tanret B. S. [2], 35, 104 40, 441 Hexmethylic isohydromelli- C 6 H 6 (COOMe) 6 C 18 H 24 O 12 125 Bseyer As., 7, 47 vi., 810 tate Propylic santonate C 14 H 19 O 2 .COOPra C 18 H 26 4 220 (d. p.) Liquid Carnelutti & Nasini B., 13, 2209 40, 181 parasantonate B 113 11 11 Diethylic hydroxydibenzoate C 14 H 16 Et 2 O 5 C 18 H 26 O 5 205-207 Liquid Otto A., 134, 331 vi., 722 Hexic acid 3C 6 H 8 2 +H 2 O C H O 126 Demargay C. R., 88, 126 ; 36, 457 ; 40, * 7 ; . A. C. [5], 20, 468; 255 B. S. [2], 33, 575 Isohexic acid .... 124 Oxyhexic acid 3C 6 H 8 3 +H 2 C 1S H 26 10 173-174 C. R., 88, 289 ; 36, 459 A. C. [5], 20, 489 Isoxyhexic acid ,j B .... 186-187 Diethylic tetracetsaccharate C 4 H 4 (OAc) 4 (COOEt) 2 C 18 H 26 O 12 61 Baltzer A., 149, 242 ; vi., 1000 B. S. [2], 10, 263 tetracetmucate B 177 .... A., 129, 195 Hexacetmannite C 6 H 8 (OAc) 6 abt. 100 Grange C. R., 68, 1326 vi., 806 11 100 Schiitzenberger A., 160, 94; A. C. vii., 774 ; 25, [4], 21, 235 70 n 119 Bouchardat A. C. [5], 6, 107 ; 26,70 C. R., 76, 1550 B ( : .... 120 Franchimont B., 12, 2059 Hexacetdulcite B 171 c. Bouchardat C. R., 74, 665 ; 25, 400 A. C. [4], 27, 150; B. S. [2], 18, 115 vii., 441 Triacetinulin .... C H Ac 100 Ferrouillet and Z. C. [2], 5, 509 vi., 737 C I8 H 26 13 Savigny Desoxyphorone .... 0,^0 108-109 Claison A., 180, 10 29, 896 .... n 108 B., 7, 1168 28, 161 Anthropocholic acid ..** C 18 HjgO 4 .... 145 .... Z. P. C., 3, 304 Pentaethylic propargyl penta- (COOEt) 2 .CH.C(COOEt) 3 . CisH^Oi,, 323 (760) ; .... Bischoff B., 15, 1109, 1111 42, 1188 carboxylate CH 2 (COOEt) 275-280 ' (188) Lactyceryl alcohol .... C 18 H 162 Hesse N. H. C., 4, 8 Sycoceryl alcohol C 18 H 29 .OH B 90 De la Rue and P. T. [1860], 43 v., 645 Miiller Hy drocarotin. . . . 126'5 Brunner N. R. P., 24, 641 29, 940 " 126'8 Husemann A., 117, 206 iii., 191 Stearolic acid.... C, 7 H 31 .COOH C H. O .... Limpach A., 190, 294 34, 403 ocn "" Overbeck J.p., 97, 159 ; A., vi., 1038 " 140, 50 72 Cloez C. R., 82, 501 30, 102 Ricinostearolic acid C 18 H, 2 3 51 Z. C. [1867], 547 Ricinostearoxylic acid .... C^H^Oj 78 Ulrich B. S. [2], 9, 225 vi., 997 Stearoxylic acid 86 Overbeck J.p., 97,159; A., vi., 1038 140, 63 Oleie acid C,-H 33 .COOH f ' H O "Irt j. Gottlieb A., 57, 40 iv., 192 v- 1 j 8 il 34" '> 14 Reichardt A. P. [3], 10, 339 32, 518 COMPOUNDS CONTAINING THREE ELEMENTS. 285 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Stearidic acid.... C,-H,,.COOH 35 Oudemanns J. p., 89 193 v., 422 Elaidio acid .... 44-45 Meyer A , 35 174 ii., 368 From Stearic acid Pelargonic anhydride ,, Ethylic jalapinolate Eicinoleic acid Ricinela'idic acid Hydroxyoleic acid Trihydroxyoleic acid.... Hexadecyl methyl ketone .... Stearic aldehyde Cetylic acetate ,, Hexadecylic acetate Ethylic diheptylacetate palmitate ,, Dioctylacetic acid (isoatearic) >i i) j i Cetylacetic acid Stearic acid . .. fusion with P 2 O 5 (C 9 H 17 0) 2 J) C 17 H 32 (OH).COOH C 17 H 30 (OH) 3 .COOH Me.CO.(CH 2 ) 15 .Me CH 3 .COO.(C 16 H 33 ) JJ CH 3 .COO.(CH 2 ) 15 .Me [Me(CH 2 ) 6 ] 2 .CH.COOEt C )5 H 31 .COOEt CH(C 3 H 17 ),,.OOOH C 16 H 38 .CH 2 .COOH C 17 H 35 .COOH * ^isH 34 O 3 ) i i i 11 Ci 8 H 34 O 5 C I8 H 36 C 18 H 36 2 ) J? )> 1) 11 ) 1) J) 251-252 (100) 212-213 (22) ; 259-261 (100) 222-225 277-278 (190) 199-5-200-5 (15) 308-5-311 270-275 300 287 (100) 54-60 5 5 32-5 (s. 6 to -10) 50 50 50 56-58 64 51-52 63-5 18-5 18-5 18-5 22-23 21-5 24-2 38-5 38-5 39 63-5-64' Erdmann Cahours Chiozza Saalrmiller Bondet Bouis Ulrich Liechti and Suida Krafft M Becker Dollfus Perkin Krafft Jourdau Berthelot Heintz Guthzeit Conrad & Bischoff Guthzeit Ki-afft J. p., 25, 500 A. C. [3], 39, 207 A., 85, 231 A., 116, 314 J., 1, 562 A., 4, 16 A. C. [3], 44, 82 B. S. [2], 9, 225 B., 16, 2455 B., 15, 1707 B., 13, 1417 A., 102, 220 A., 131, 284 B., 16, 1714 A., 200, 114 J., 6, 502 J., 6, 447 A., 206, 351 A., 204, 11, 165 B., 13, 597 A., 206, 355 B., 12, 1672 v., 416 iv., 371 v., 110 v., 109 vi., 997 46, 239 )1 42, 1272 38, 867 i., 840 vi., 14 46,497 44, 1076 38, 314 iv., 335 40,408 38, 872 38, 628 40,408 38, 34 54-4 56'6 P A., 145, 279 26, 238 ,, 1 60-61 61 Heintz Oudemanns 29, 8 36, 569 68 Duffy J., 5, 511 v., 413 ,, ) 1) 69 69 Stenhouse A., 36, 57 J., 11, 303 )) 69 Reichardt A. P. [3], 10, 339 32, 518 359-383 69 Carnelley&W^illiams B., 12, 1360 35, 563 69 '2 Pebal A, 91, 138 v., 413 69"! 69'2 A., 84, 299 38, 872 69 '5 Schiff A., 223, 247- 46, 1089 69 70 G. I, 14, 181 A., 206, 351 40, 408 70 A., 35, 46 70 J., 8, 43 v., 413 70 P. M. [5], 13, 165 70'5 2 232 v., 413 .... .... ) ) .... 70-6 75 Jacobs C. C. [1882], 384 A C. 42, 1147 v., 413 Neurostearic acid Ethylic turpetholate Isodioxy stearic acid ? C^H^OH^COOH > ( ' ! 18H 36 O 4 v C.oH O 84 72 126 50 60 Thudicum Overbeck J. p. [2], 25, 25 A., 139, 59 A., 140, 72 A 157 295 42, 537 vi., 759 24, 363 Cetyl ethyl oxide Octodecyl alcohol From bromcinnamic acid .... ? Paracotoin .... . Et.O.C I6 H 33 CH 3 .(CH 2 ) 16 .CH 2 .OH ^isHasO C 19 H 12 0, j) C H O 210-5 (15) 20 59 a. 260 157 Becker Krafft Leuckart A., 102, 220 B., 16, 1723 B., 15, 18 A., 212, 98 A 199 31 ; B., i., 842 44, 1076 42,615 38, 326 ; 32, Benzoyl diphenyl .... 1 C 6 H 4 .Bz.Ph =1.4 =1.? C 19 H H ) .... 104 106 9(i Goldschmidt Wolf 10, 249 M. C., 2, 437 B., 14, 2032 A., 212, 97 201 42, 202 42,62 286 ORGANIC COMPOUNDS. Name. Constitution. Formula. Spiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Benzoxy diplienyl Ph.C 6 H 4 .OBz C 19 H 14 2 .... 152 Latschinoff B., 6, 194 vii., 938; 26, 750 Benzaurin HO.C 6 H 4 CPh C 6 H 4 O 100 + Dcebner B., 12, 1463 38 239 Ijeucaurine n. f. 130 Dale &Schorlemme 24, 466 ; 25 74 vii 110 VAA.J 11 y Phenylic phenoxybenzoate ... PhO.C 6 H 4 .COOPh =1.4 C 19 H 14 O 3 73-78 Klepl J. p., 28, 193 46, 447 Aurin .... C 6 H 4 .O C(C 6 H 4 OH)., 150 FrcsGnius 25, 75 1 1 " n. f. 200 Dal6& ScliorlerDme M. P., 11 " " n. f. 220 26, 435 vii., 118 Corallin " " n. f. 220 26, 441 Methylic hydroxynaphtho- COOMe.C 6 H 4 .CO.C, H 6 .OH C 19 H 14 4 .... 199 Walder B., 16, 301 44, 666 benzoate =1.2 ; a, /3 Yulpic acid .... C(OH).C : CPh.COOMe C 19 H 14 O 6 a. 100 Strecker & Miiller A., 113, 56 v., 1007 CPh. COO 148 Spiegel B., 13, 1629 40, 97 Isovulpic acid i... j. .... 124 B., 15, 1552 Diacetchrysophanic acid C 14 H 5 Me(OAc) 2 :0 2 C 19 H I4 O 6 .... 202-204 Liebermann A., 183, 225 31, 611 11 !) ?) .... 200 Liebermann and B., 11, 1607 Seidler Diacetmethylquinizarin 185 Nietzki B., 10, 2013 Paracotoic acid .... C 19 H 14 7 108 Jobst and Hesse A., 199, 38 38, 326 Daphnetin C 19 H 14 O 9 a. 250 Zwenger A., 115, 8 ii., 303 Triphenyl oarbinol (C 6 H 5 ) 3 C.OH C 19 H 16 a. 360 157 Hemilian B., 7, 1206 28, 153 ** 157 Schwarz B., 14, 1522 40, 913 .... 159 Baeyer A., 202, 36 38, 651 1 C 19 H 16 O 170 A., 212, 91 Dihydroxytriphenylmethane Ph.CH(C 6 H 4 .OH) 2 .... 161 Doebner B., 12, 1464 Triphenylic orthoformate ... CH(OPh) 3 C I9 H 16 O 3 260-270 71-5 Tiemann B., 15, 2686 44,340 (50-55) From oxidation of retene .... MM a .... 139 Ekstrand B., 9, 855 30, 514 Tetrahydroxytriphenyl- Ph.CH[C 6 H 3 (OH) 2 ] 3 C 19 H 16 O 4 .... 171 Doebner B., 13, 611; A., 38, 644 methane 217, 235 Allylenedigallem diacetate .... C 15 H 10 4 (OAc) 2 C 19 H 16 O 3 176 Wittenberg J. ]). [2], 26, 66 42, 1290 Carbusnic acid See C 18 H 16 7 )) 195-4 Hesse A., 137, 241 vi., 413; 34, 882 Isoamyloxanthranol anhy- C 19 H 13 .... 66 A., 212, 93 dride !) )> .... .... 71-72 .... A., 212, 94 Diethylic benzoylisophthalate C fi H 3 (COOEt) 2 .Bz=1.3.? C 19 H 18 O 5 .... 95 Blatzbecker B., 9, 1763 31, 469 Diethylic benzoyltereph- =1.4.? 100-101 .... J. [1878], 403 thalate Diacetylapachoic acid C 38 H 36 O 10 ,, 131-132 Paterno B.,16,802;G.I., 12, 337 From orcinol .... C 17 H 15 AcO 5 C 19 H, 8 O 6 C 35 H 34 O U 200 Wittenberg J. p. [21, 26, 71 42, 1290 Atranoric acid 190 Paternd & Oglialoro 1 L JJ "*) ' x G. L, 7, 189 32, 786 .... 190-194 Patern6 G. I. [1882], 231 42, 1083 Acid from methyldeoxyben- .... CuHjoOj .... 92-5 Mann B., 14, 1646 40, 1035 zoin Isoamyloxanthranol C f H 4 .CO.C 6 H 4 .C(OH)C 6 H n .... 125 Liebermann A., 212, 73; B., 42, 861 13, 1599 Amylene dibenzoate C 6 H 10 (OBz) 2 C 19 H 20 O 4 .... 123 Meyer C. E., 59, 444-; vi., 120, 309 B. S. [2], 2, 451 Dibenzoyl isovaleral C 4 H 9 .CH(OBz) 2 ,, 264 111 .... A., 109, 299 Isovaleryl oroselone C 6 H 4 (OC 5 H 9 0).O.C 6 H 4 .0. C 19 H 20 O S .... 95-97 Hlasiwetz & Weidel A., 174, 82 28, 257 CH 2 .COH Guajaconic acid .... ,... See C 19 H,jO 3 .... 95-100 J. [1862], 467 ; M. C., 3, 822 Diacetyl decarbusnic acid .... C 15 H 14 Ac 2 5 C.gHoflO; 130-131 Patern6 G. I. [1882], 231 42, 1080 Barbatic acid .... .... 186 Stenhouse & Groves A., 203, 302 37, 407 Diacetyl picrotoxide .... c^io, 245 Paternd & Oglialoro G. L, 9, 57 86, 729 Isoamyl hydranthranol C ? H 4 .CH.,C 6 H 4 .C(OH).C 6 H 11 C^H^O 73-74 Liebermann A., 212, 103 42, 862 COMPOUNDS CONTAINING THREE ELEMENTS. 287 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Ethylic a-ditolylpropionate ... (C 6 H 4 Me),,CMe.COOEt C, 9 H 22 O 2 145 Haiss B., 15, 1476 42, 1071 -a-Diethylphenylpropionicack (C 6 H 4 Et) 2 .CMe.COOH .... 116 Bottinger B., 14, 1597 40, 1035 Benzyl acetoxycyniene C c H 2 .OAc.Me.Pi-.CH 2 Ph 31 245 (8) 1. f. m. Mazzara G. I. [1881], 346 4S, 172 and 433 Guajaconic acid See C 19 H S0 S C 19 H 22 O 3 100 180-5 u. c. Hadelich Wieser J. p., 137, 321 W.A. [1881], 464 ii., 947 40, 812 183 A., 52, 404; 119, 277 Benzyl arbutin+H 2 O C 6 H 11 5 .O.C 6 H 4 .O.CH 2 Ph C 19 H 22 O- ... 161 Schiff G. I., 13, 538 46, 432 Diacetylpicrotoxide hydrate C 15 H 16 7 Ac 3 CTT f\ 19- CL 22 v/ 9 .... 202 Paterno &Oglialoro G. I., 7, 193 32, 790 Acetpodocarpic acid Anamirtin C 16 H 20 (OAc).COOH C' 19 H 36 O 2 and C 46 H 58 24 C, 9 H S4 O 4 .... 152 d. 280 w. m. Earth & Kretschy A., 170, 238 W. A., 81, 7 40, 286 Ethylic podocarpate C 16 H 20 (OH).COOEt OwBdoT 143-146 A., 170, 223 Santonic acetate Turmerol .. .... .... So 285-290 d. ' 126-128 Liquid Jackson and Menke J. [1875], 608 B., 16, 571 ; 44, 482 (760); A. C. J., 4, 368 193-198(60) Ethylie ethylsantouite C 14 Hi 8 EtO.COOEt C I9 H 28 3 .... 31-32 Cannizzaro and G. L, 12,393; B., 44,78 Carnelutti 16, 427 ethylisosantonite .... 54 11 .1 71 11 Isobutylic santonate.... .... C^H^O, 67 Carnelutti & Nasini B., 13, 2209 40, 181 Diethylic photosantonate .... Syrin^in .... C H .... 67-68 185-190 Sestini G. I., 6, 357 A., 40, 320 31, 472 19 Kromayer J. [1862], 484 ; v., 652 Dce< r lic acid 1) 0+ Scharling [1863], 592 J. p., 43, 257 ii., 343 Anamirtin .... See C 19 H, 4 O, 36 2 35-36 Francis A., 42, 254 i., 289 Dioctylmalonic acid .... CCCJH^COOH)., C 19 H 3B 4 75 Conrad and Bischofl A., 204, 164 ; B., 38, 628 13, 595 Cetylmalonic acid CH(C 16 H 33 )(COOH) 2 115-117 u.c. Guthzeit A., 206, 359 40, 408 Dinonylketone (caprinone) .... CO.(C 9 H 19 ) 2 C^H^O a. 350 58 Grimm A., 157, 270 24, 360: vil., 251 Dioctylacetone .... 325-330 A., 204, 10 Heptadecyl methylketone .... Me.CO(CH 2 ) lc .Me 262-5 (100) 55-5 Krafft B., 15, 1707 42, 1272 .. 266-5 (110) 55-5+ B., 12, 1672 Methylic stearate C 7 H 35 .COOMe C 19 H 38 O 2 38 Hanhart C. R, 47, 230 v., 420 ' .... 85 (?) pos- Lassaigne A., 13, 168 sibly 35 Glycerol nionopalmitin C 3 H 6 (OH) 2 (O.C 1C H 31 0) C 19 H 38 O 4 distils i.v. 58 Berthelot A. C. [3], 41, 238; iv., 335 J., 6, 453 j3-Diuaphthylene oxide C 10 H 6 .O.C 1 oH 6 C 20 H 12 154 Dianiii J. E. [1882], 130 42, 623 ft- 155 Knecht & Unzeitig B., 13, 1724 40, 281 ft- 11 ,. .... 157 Walder B., 15, 2172 44, 209 ft- n 159 Niederhausern B., 15, 1122 ft- J! )I .... 161 Merz and Weith B., 14, 200 40, 265 a- 11 .... 180 Knecht & Unzeitig B., 13, 1724 40, 281 a- D .... 182 Merz and Weith B., 14, 196 a- ,, 180 Niederhausern B., 15, 1122 a- 182-184 Phenolphtlialei'n anhydride.... o:(c 6 H 4 ) 2 :c.c 6 H 4 .co.o CjoH.A .... 173-175 Baeyer A., 212, 349 42, 1096 =(U) 2 .1.2 , Quinolephthaleiu c 6 H 4 :(co.c 6 H 3 .OH) 2 :o C 20 H 12 5 .... 226 u. c. Ekstrand B., 11, 714 34,675 ,, 233 Grimm B., 6, 507 u 11 " "! D .... 230-234 u.c. J) 26, 1235 Phloroglucolphthaleln o: [c 6 H 2 (OH) 2 ] 2 :c.c 6 H 4 .coo QsoHuO; d. 240 w. m. Link B., 13, 1652 40,95 /3-Dinaphthyl oxide C 10 H 7 .O.C 10 H 7 C 20 H 14 O a. 300 104 Gladstone and Tribe .... 41, 15 ft- ,, .... 105 Groebe B., 13, 1850 40, 177 ft- .... 105 Merz and Weith B., 14, 199 40, 264 ft- 105 Nietzki B., 15, 306 288 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. a-Dinaphthyloxide C 10 H 7 .O.C 10 H 7 C 20 H 14 .... 109-110 Merz and Weith B., 14, 195 40, 264 Phenyl anthranol c 6 H 4 :c 2 Ph(OH):c 6 H 4 Ca>H 14 O 2 141-144 d. Schellinger A., 202, 54 38, 651 Diphenyl phthalide (phthal- C 6 H 4 .CO.O.CPh 2 i> .... 112 Baeyer A., 202, 50 38, 650 ophenone] 11 11 11 IJ 115 Pechmann B., 14, 1866 Dibenzoylbenzene C 6 H 4 .Bz 2 =1.3 abt. 260 99-5-100 Ador B., 13,321;B. S., 38, 470 [2], 33, 56 ft- 11 =? 145-146 Zinck6 B., 9, 31 29, 703 a- IJ .... 159-160 11 Dinaphthol HO.C 10 H 6 .C 10 H 6 .OH .... 195 Kaufmann B., 15, 807 42, 1068 ft- 217 Walder B., 14, 2345 ft- 11 J) 218 c. 11 B., 15, 2167 ft- 11 ... 218 Dianin B., 6, 1252 27, 262 ; vii., 842 a- .... 300 11 ,, Phenyloxanthrol C,H 4 .CO.C 6 H 4 .CPh(OH) n 208 Schellinger A., 202, 58 38, 651 i i Benzoylphenyl benzoate C 6 H 4 .Bz.OBz=1.4 C 20 H 14 O 3 112-5 Grucarevic & Merz B., 6, 1245 27, 264 ii 11 11 11 ,, .... 112-5 Dobner and Weiss B., 14, 1841 11 11 .... 112-5 Dobner A., 210, 251 42, 508 Hydroxydiphenylphthaleiu... HO.C 6 H 4 .CPh : C 6 H 4 .COO .i .... 155 ; 61-66 Pechmann B., 13, 1613 40, 96 =1.?; 1.2 ? 1 ,i .... 235-237 Gabriel & Michael B., 11, 1680 36, 245 Phenolphthalin anhydride ... O : (C 6 H.) 2 : CH.C 6 H 4 .COOH 214-217 Baeyer A., 212, 350 42, 1097 =(1.?) 2 ; 1.2 Hydroxyphenyloxanthranol C 6 H 4 .CO.C 6 H 4 .C(OH). ;J d. 175 194 Pechmann B., 13, 1618 i i C 6 H 4 .OH Diphenylic phthalate C 6 H 4 (COOPh) 2 =1.2 C 20 H 14 O 4 .... 60 Schreder B., 7, 705 27, 990 11 11 11 11 70 Gerichten B., 13, 419 38, 474 isophthalate =1.3 .... 120 Schreder B., 7, 708 27, 991 terephthalate .... =1.4 .... a. 100 DelaEue&Muller A., 121, 89 v., 727 11 11 .** 191 Schreder B., 7, 707 27, 991 Pyrocatechol dibenzoate C 6 H 4 .(OBz) 2 =1.2 ,, .... 84 Dobner A., 210, 261 42, 508 Eesorcinol dibenzoate ,, =1.3 .... 117 Easinski J. p. [2], 26, 64 42, 1289 n 11 !> 11 .... 117 Dobner and Stack - B., 11, 2270 lll.-IIIM Quinol dibenzoate =1-4 .... 199 Dobner and Wolff B., 12, 661 ; A., 36, 638 210, 263 Dibenzoresorcinol C 6 H 2 (OH) 2 .Bz 2 =1.3.?.? .... 149 Dobner and Stack - B., 11, 2268 36, 320 mann 11 .... .... ii ii ... 149 Dobner A., 210, 259 42, 508 Dibenzoquinol =1.4.?.? ,, .... 207 11 A., 210, 264 " 5> 207 Dobner and Wolff B., 12, 661 36, 638 Phenylresoroinphthalein C 5 H 4 .CO.O.CPh.C 6 H 3 (OH) :J 11 .... 175-176 Pechmann B., 14, 1860 42, 184 Phenol phthalidein CO.C,H 4 .OH .... 212 Baeyer B., 9, 1235 31, 309 C O.C 6 H 4 .OH phthalei'n .... 15 250-253 A., 202, 68 38, 653 fl-Dinaphthyldiquinol C 20 H 10 (OH) 4 176-178 Stenhouse & Groves A., 194 207 33, 420 Quinol phthalin ^OQ-tlj^V/i 202-203 u.c. Ekstrand 1 B., 11, 716 34, 676 Phenylpyrogallophthalei'n .... C 6 H 4 .CO.O.CPh.C 6 H 2 (OH), 5) 189 . f m IMiLln i Pechmann B., 14, 1864 42, 184 i i = 1.2 ; 1.2.4.? Acetoxynaphthobenzoic acid COOH.C 6 H 4 .CO.C 10 H 6 .OAc .... 170 Walder B., 16, 302 44,666 = 1.2; ?.8 Besorcinophthalein (fluo- C 8 H 4 [CO.C 6 H 3 (OH) 2 ] 2 C 20 H U O 6 .... 1. 290 w. in. 3aeyer A., 183, 26 31, 196 resorcei'n) 12* (1 1 3) COMPOUNDS CONTAINING THREE ELEMENTS. ^X. w - 'f j r-Lk 1 i A -df . -cryp,, ,. 289 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Eesorcinoxalem C0\ C 20 H 14 O 7 .... d. 150 Glaus B., 14, 2563 42,399 HO.C 6 H 3 C[C 6 H 3 (OH) 2 ] 2 Triacetoxyanthraquinone c 6 H 4 :(co) 2 :C 6 H(OAc) 3 C 20 H 14 O 8 171-175 Seuberlich B., 10, 40 (fr. anthragallol) =2.1 ; 1.2.3.4.5 (fr. purpurin) =2.1 ; 1.2.3.4.6 .... 190-193 Liebermann and B., 9, 332; A., 30, 90 Giesel 183, 192 I! >! ,, .... 198-200 Schunck & Ecemer B., 11, 553 31, 673; 32, 625 (fr. oxychrysazin) C I4 H 6 (OAc) 3 2 .... 192-193 Liebermann and B., 9, 332 30,90 Giesel .... 192-193 Liebermann A,, 183, 145 31, 612 (fr. flavopurpurin) 195-196 Schunck & Rcemer B., 10, 1822 34, 322 (fr. isopurpurin) ., 220 Eosenstiehl B. S. [2], 29, 405 34,677 >> 11 I) .... 220-222 Perkin 26, 430 ; 30, 90 vii., 90 Luteolm . 320 p. d. iii., 736 Psoronic anhydride C M H 14 O 9 .... 263-264 Spica G. I., 12, 431 44,80 Prehnomalic anhydride [C 6 H 3 (OH)(COOH) 3 .CO] 2 C^H^O,, 210 Baeyer B., 4, 275 Ketone from rosaniline C 20 H 16 O d. 143 148-149 E. and O. Fischer B., 9, 900 30, 530 Triphenylacetic acid CPh 3 .COOH C 20 Hi 6 O 2 260 d. A., 194, 261 Benzhydrylbenzoate CHPh 2 .COBz .... 87-5-89 Linnemanu A., 133, 20 iv., 479 Beuzylphenolbenzoate C 6 H 5 .CH 2 .C 6 H 4 .OBz .... 86 Paterno and Fileti G. I., 3, 121 ; J. 27, 372 [1873], 440 Triphenylmethane carboxylic CHPh 2 .C 6 H 4 .COOH 150 Pechmann B., 14, 1866 acid 11 11 J) 11 155-157 Baeyer A., 202, 52 38, 651 Hydroxytriphenylmethane CPh 2 (OH).C 6 H 4 .COOH=1.2 C 20 1I )6 O 3 150 Fischer A., 194, 242 46, 323 carboxylic acid 11 =1.3 .... 160-162 Hemilian B., 16, 2369 11 !> = 1 11 .... 187 B., 7, 1210 28, 153 11 11 JHPh.(C 6 H 4 .OH)C 6 H 4 .COOH 210 Pechmann B., 13, 1616 40,97 Ethylic a-phenanthroxylene- C 6 H 4 .C=C-CH : CH 2 124 Fapp and Streatfield B., 16, 278 43,30 isocrotonate C 6 H 4 .CO Eosolic acid .... C 6 EU .C 6 H 3 Me(OH) n.f. 270 Grsebe and Caro A., 179, 184 29, 589 / ' X C 6 H 4 .OH ,, (hydrate) .... 15-6 Fresenius .... vii., 1061 Dihydroxy triphenylmethane C 6 H 3 (OH) 2 .CHPh.C G H 4 . C 20 H 16 O 4 184 Pechmann B., 14, 1862 42, 184 carboxylic acid COOH=1.3.?; 1.2 ,1 11 (HO.C 6 H 4 ) 2 .CH.C 6 H 4 .COOH 225 Baeyer A., 202, 80 38,654 (phenol phthalin) Ethylic phenanthroxylene- C 6 H 4 . C=C-CO.Me .... 184-5-185-5 Japp and Streatfield B., 16, 275 43,27 aceto-acetate 1 \n r\ C 6 H 4 -CO Ethylic hydroxynaphthobeu- HO.C 10 H 6 .CO.C 6 H 4 .COOEt .... 206 Walder B., 16, 302 44, 666 zoate =a,/3; 1.2 From rosolic acid C :0 H 18 5 abt. 200 Grsebe and Caro A., 179, 184 29, 589 Dimethylic pulvate C 16 H 9 .OH.(COOMe) 2 C 20 H J6 5 138-139 Spiegel -B., 13, 1634 40, 97 Ethylpulvic acid C 16 H 9 .OEt.(COOH) 2 127-128 Diacetoxyacetanthran ol C 6 H 4 :C 2 H(OH):C 6 H 2 (OH) 2 C 20 H 16 O 6 .... 188 Ecemer B., 14, 1263 40, 823 =2.1 ; 1.2.3.4 Diacetylcampheride C 16 H 10 Ac 2 6 C 20 Hi C O 8 .... 188-189 Jahns B., 14, 2388 42,209 Purpurogallin C 20 H 1B 9 256 Clermout&Chautard C. E., 94, 1362 42, 1065 Tolyldiphenyl carbinol Me.C 6 H 4 .CPh 2 OH=1.4 C 20 H 18 O 150 E. and O. Fischer A., 194, 283 36, 386 Dibenzyl pyrocatechol C 6 H 4 .(O.CHjPh) a =1.2 C 20 H 13 O 2 .... 61 Pellizzari G. I., 13, 501 46, 437 resorcinol =1.3 ,, 79 quinol =1.4 130 D Dibenzhydryl benzene C 6 H 4 .(CHPh.OH) 2 171 Wehneii B., 9, 310 29, 916 ? acid .... 156 .... A., 195, 368 Essence of linaloes 198 (755) Liquid Morin C. E., 92, 998 40, 738 Oxoctenyl acetate C l3 H, 5 Ac0 2 C 20 H 18 O 3 200-202 Liquid Butlerow J. E. [1882], 190 42, 937 2 P 290 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Cn. Soc. Phenolphthalol (HO.C 6 H 4 ) 2 .CH.C 6 H 4 .CH 2 OH C 20 H 18 3 .... 190 Baeyer A., 202, 87 38, 655 Methylic polyporate .... C 20 H 18 O 4 .... 187 .... A., 187, 193 Acetyl compound of ethyl- .... 84 Liebermann A., 212, 92 42, 861 oxanthrol (?) From rosolic acid C 20 H 16 O 4 C 20 H 18 5 .... abt. 200 Grsebe and Caro A., 179, 184 29, 589 Dimethylic dibenzoyl dextro- COOMe(CHOBz) 2 .COOMe C 20 H 18 O 3 d. 132 Anschiitz B., 14, 2790 42, 831 tartarate 11 ... 132 Pictet B., 15, 2243 Ethylic diphenyl fumarate ... COOEtCPh : CPkCOOEt C 20 H 20 O 4 .... 54 Eeimer B., 13, 745 40,48 Diacetonephenauthraquinone C 6 H 4 .C(OH).CH 2 .CO.Me .... 187 d. Japp B., 16, 283 44, 597 1 | C 6 H 4 .C(OH).CH 2 .CO.Me Isoamylchrysin C, 5 H 9 .(C 5 H U )0 4 .... 125 Piccard B., 10, 177 32, 342 Tannic acid (from oak bark) C 20 H 20 9 140 Etti M. C., 4, 512 44, 996 Frangulin . . OHO 225 Faust A., 165, 230 26, 503 20 20 10 " 249 Casselmann A., 104, 77 vii., 534 Luteic acid C H O (?) 273-274 Holm A. P. [2], 140, 218 vii., 495 Dicuminyl (cuminil) (C 6 H 4 Pr.CO) 2 C 2 [H 2 2 2 300 Liquid Chiozza A. C. [3], 39, 246 ii., 182 n 11 a. 300 Liquid Church P. M. [4], 25, 522 vi., 515 n .... 84 Bosler B., 14, 325 40, 421 0-Dipropylcarbobenzonic acid .... 90 Zagoumeny A., 184, 167 32, 194 a- ,, ,, .... .... 139 Dibenzoyldurene C 6 Me 4 Bz 2 ,, 269-270 Friedel, Crafts and C. E., 88, 880 36, 713 Ador Eugenylic cuminate C 6 H 4 Pr.COO(C 10 H n ) C 20 H 22 O 3 a. 400 very easily Cahours A. C. [3], 41, 491 ii., 180 Eugenic anhydride .... (C 10 H n O) 2 )) .... s. 130 Oeser A., 131, 281 vi., 609 Diethylic diphenylsuccinate COOEt.(CHPh) 2 .COOEt C 20 H 22 4 84-85 Eeimer B., 14, 1804 42, 200 diphenylisosucci- CH 2 Ph.CPh(COOEt) 2 .... 136 1, nate Mangostin G, H 22 O 5 190 A., 93, 83 Diethylic ethylene salicylate C 2 H 4 (O.C 6 H 4 .COOEt) 2 =(1.2) 2 C 20 H 22 O 6 96-97 Weddige J.p. [2], 20, 128 38, 317 Populin (benzoyl salicin) .... C 13 H 17 BzO 7 C 20 H 22 O 8 .... 180 A. iv., 689 Hydrocoerulignone diacetate [C 6 H 2 (OMe) 2 .OAc] 2 D .... 216 Liebermann B., 6, 382 vii.,377;26,1033 11 n .... 217-225 .... A., 169, 236 Erythrite diorsellinate .... C 20 H 22 10 .... 137 .... A. ii., 502 (Erythric acid ; Erythrin) Desoxycuminom Pr.C 6 H 4 .CH 2 .CO.C 6 H 4 .Pr C 20 H 24 .... 58 Bosler B., 14, 325 40, 421 Cuminom Pr.C 6 H 4 .CH(OH).CO.C 6 H 4 Pr C n H O 98 B., 14, 324 20 24 2 101 Wi'dmann B., 14, 610 40, 597 .... (isomer) 11 " 138 Eaab B., 10, 55 32, 894 Cuminilic acid (Pr.C 6 H 4 ) 2 .C(OH).COOH C 20 H 24 3 119-120 Bosler B., 14, 326 40, 421 Opoponax resin .... C 20 H 24 O 7 100 iv., 211 Dipropyldiphenylpinacone .... CHPhPr.O.O.CHPhPr C 20 H 26 2 .... 64 Schmidt & Fieberg B., 6, 499 27, 75 Hydrocumino'in [CH(OH).C 6 H 4 .Pr] 2 .... 131 Eaab B., 10, 54 32, 894 135 Bosler B., 14, 324 40, 421 .... .... ,, .... ? Glaus A., 137, 104 Diethoxydiethyldiphenyl .... EtO.Et.C 6 H 3 .C 6 H 3 .Et.OEt .... 120 c. Schultz B., 17, 475 46, 904 /3-Dithymol 154 J. E. [1882], 130 162 J. E., 7, 9 " 165'5 Dianin J. E. [1882], 130 42,624 Eeduction of oil of anise .... ?) 220-224 Liquid Ladenburg B., 2, 372 vi., 157 Guyaquillite .... C 20 H 2 O 70-100 Johnson P. M., 13, 329 ii., 962 Guaiai'etic acid .... f 2 oH 26 O 4 75-80 Ilasitwetz and Gilm A., 119, 266 ii., 948 Pyrolivilic acid 2C 10 H 12 2 .H 2 C 20 H 26 O 5 a. 200 Liquid Sobrero A., 54, 206 iv., 760 Asarone (asarin) || 280 40 Blanchet and Sell ; A., 6, 296 ; 53, i., 414 Schmidt 156 Tetrethoxydibydroxy- [C 6 H 2 (OEt) 2 OH] 3 ^20^26^6 .... 176 d. Hofmann B., 11, 802 34, 871 diphenyl Absinthin C^HjjgC^ 120-125 J. [1861], 745 Elaterin ( 1 TT O 200 Eichter E. K. T., 408 Isocholanic acid ; .... 239 Latchinoff B., 15, 713 42, 874 COMPOUNDS CONTAINING THREE ELEMENTS. 291 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Cholanic acid ,. a. 250 d. Tappeiner A, 194, 231 36, 388 285 Latschinoff B., 15, 713 42, 874 285 B., 13, 1054 Resinein C.v,H, n O a. 250 Fremy A., 15, 284 41, 167 From Besina Guaiaci Peru- viana aromatica v. odorata From essence of sandal wood ? Copaibic acid .... ) ) C 20 H 30 2 285-290 240 289 126-129 129 Kopp Chapoteaut Mossmer Brix Duvernoy A. P. [3], 9, 193 B. S., 37, 303 A., 119, 257 M. C., 2, 537 A., 148, 147 31, 717 44,76 ii., 759 42,66 vii., 379 129-165 Maly A. 145 Richter R. K. T. 152-5 Trommsdorff A., 13, 169 v., 649 162 Sievert J. [1859], 508 Pimaric acid .... (laevorotary) )> V )J 1 )) I) ) ,, ,, .... .... . .. (contains about 0'4 / H 2 O) ) )) j n a. 320 abt. 125 US 143 145 145 149 155 Laurent Cailliot Duvernoy Cailliot Laurent Duvernoy Sievert A. C. B. S. [2], 21, 387 A., 148, 143 B. S. [2], 21, 387 A., 148, 143 J., 12, 510 iv., 645 28,457 vi., 945 28, 458 vi., 945 158; 153 Z. g. N., 14, 311 iv., 645 (dextrorotary) Action of Na on camphor .... Acetyl campherphoron Gentiopicrin .... > C 20 H 30 2 QzAoOg 230-240 a. 200 141 Liquid 120-125 Cailliot Kachler and Spitzer Schwanert B. S. [2], 21, 387 M. C., 4, 494 A., 123, 312 J. [1862], 483 28, 458 44, 1007 vi., 390 Colophene . . CH TO O 318 320 Richter R. K. T., 409 Metaterebenthene Fluavil .... J) a. 360 42 A. C. [3], 39, 19 J. [1859], 518 Ceroxylin a. 100 iv., 337 Caryophyllin .... (LnH,o(X sb 285 Muspratt B., 6, 1053 27, 80 Sycocerylic acetate Lactucerin Carbocamphoric acid Mt'lantliin C 18 H S9 .OAc M C 20 H 32 O 8 CUH^O- (1) 118-120 210 123-124 205 DelaRue&Muller Hesse Greenish P. T. [1860], 43 N. H. C., 4, 8 M. C., 3, 213 P. J. T. [3], 10 ; v.. 646 38, 719 Terpinol CLH,,O 157 Anderson 909, 1013 J., 22, 789 (C 10 H,,U) 167 168 Stillmann B., 13, 630 38, 670 168 List A., 67, 367 33, 247; v., 923- 165 208 Oppenheim A. [1864], 149 33, 247 From Coriandum sativum .... Cajputene hemihydrate I Geranyl oxide Borneol oxide Black cummin oil Quebrachol (C IO H 16 ) 2 .H 2 (C 10 H 17 ) 2 2CJH 16 .H.,0 M ) ) 168-170 170-175 180-190 187-190 285-290 256 Liquid Liquid Liquid 125 u c Grosser Schmidl Jacobsen Bruylants Fliickiger Hesse B., 14, 2488 14,63 Z. C. [1866], 465 A, 157, 238 B., 11, 456 P.J.T.[2],2,161 A, 211, 272 42,525 i., 712 vii., 553 vii., 852 42, 744 157 A. C. [3], 13, 166 iii., 242 Amyrin (C S H S ) 4 +H.O C H O tt\ 177 Buri N. R. P., 25, 193 30, 423 OHO Vy 25 J - l 42 w \'> 210 Schrotter P. A., 59, 45 ? *-'20 ia 34'- / 2 249 d Geuther J. Z. N., 7, 218 ; 25, 607 Axlepione .... .... .... OHO 104 J. p., 6, 160 A., 69, 125 i., 416 Divalerylene divaleric acid.... Pyrolithofellic acid Cyclamin .... V> 20- C1 34 W 3 ?J )> C2oH 34 O 10 r TT o 295 125-5-128-5 205 236 OK QC Greiner Z. C. [1866], 462 A., 44, 290 A, 185, 214 ; B. S., 32, 417 A., 166, 213 ; J. vi., 601 iv., 760 Lithofellic acid Superfused, m.p. =105-110 C 2 oH 36 O 4 )> .... 304-205 199 Roster [1854], 713 B., 12, 1926 ) 2 r 2 292 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Wa its' Diet. & J. Ch. Soc. Lithofellic acid ^2oH 36 O 4 .... 204 Gobel A, 39, 242 v., 1092 .... j> 205 Wohler A, 41, 150 1) .... n 205 c. Eoster G. I., 9, 364 38, 131 Ethylic oleate C^Hja-COOEt C^H^O, 306-308 (307) Perkiu .... 45, 537 elaidate n )) a. 310 Liquid Laurent A. C. [2], 65, 294 ii., 368 )) 370 d. A, 28, 255 From valeral .... C_/ Ctfi rl n 1_7 260-290 Liquid Borodin B., 5, 481 26, 58 ; vii., su^^.lS 3 1196 260-290 Pott B. S., 18, 244 Ethylic diheptylaceto-acetate [Me(CH 2 ) 6 ] 2 .CAc.COOEt 331-333 Liquid Jourdan A, 200, 114 38, 314 Bryoidin 2(C 11 ,H,,).3H,O 135-136 Phoebus N. E. P., 24, 220 29, 615 Ethylic ricinelaidate \ 10^^16/^^^^2 .... 16 B., 60, 324 From isobutaldehyde .... CsoHsgC^ 223-225 Liquid Perkin .... 43,. 96 jj .... ) 230-240 Urech B., 13, 593 Isoamylic sebate C 8 H 16 .(COOC 6 H n ) 2 )) 360-370 10 Neison J. [1876], 577 29, 322 jj i) ) 366 .... C. N., 32, 298 Octodecylic acetate CH 3 .(CH 2 ) 16 .CH .OAc ^20^40^2 222-223 (15) 31 Kraft B., 16, 1722 44, 1076 Cetylic butyrate C 3 H r COO(C 16 H 33 ) ) 260-270 20 Dollfus J., 17, 518 ; A., 131, 285 Ethylic stearate CuHjj.COOEt 11 27 Lassaigne A., 13, 168 v., 420 i) )> )) .... 30-31 Eedtenbacher A., 35, 51 ) J) JJ 31 Hauhart C. E., 47, 230 ji )l .... 32 Francis A., 42, 261 ) ) * .... 32-9 Pebal A., 91, 154 j> j) )> >j .... 33-3 Crowder J. p., 57, 292 jj n )) 224 p.d. 33-7 Duffy 5, 197 ) j) n .... 33-7 Heintz J. p., 66, 1 Ethylic isostearate (C 8 H,,) 2 .CH.COOEt j) 1.0 Guthzeit A., 204, 13 38, 872 Arachidic acid C 19 H 39 .COOH )) .... 73 Fitz B., 4, 444 24, 703 .... J) ?> 73 R6mont J.P. [5], 2, 136, 213 40, 203 ) )> ... 75 Gossmanu A., 89, 1 i., 353 ,, .... 75 Oudemans J. p., 99, 407 vi., 190 i jj >) .... 77 Tassinari G. I., 8, 305 36, 307 Saponificn. of C io H 36 2 (OAc) 2 CK.H.A 217-223 Liquid Perkin 43,99 Fr. ethylic naphthylcarbonate (C 10 H 6 ) 2 C0 3 C 21 H in O 2 .... 240 Bender B., 13, 702 40,48 Dinaphthyl ketone .... (C 10 H.) 2 CO =a(3 C 21 H H "0 .... 125 Merz & Gmcarevic B., 6, 966 26, 1233 >J ) .... 125-5 Grucarevic & Merz B., 6, 1242, 1249 27, 264 =aa J 135 D B., 6, 1241 vii., 940 J) .... 135 Kollaritz and Merz B., 6, 536 26, 1035 = ? )> .... 140 B., 6, 546 j? =fl9 )1 .... 164 Merz & Grucarevic B., 6, 966 26, 1233 j, 31 > .... 164 Hausamann B., 8, 1505 29, 599 ,, ..., J ) 164-164-5 B., 9, 1515 31, 318 > .... 164-5-165 Grucarevic & Merz B., 6, 1242, 1249 27, 2(i4 From dry distillation of Ca .... J .... 300-305 Niederhausen B., 15, 1123 42, 1211 /3-naphthol a-Dibenzoyl benzoic acid .... (CeHsC^a.CeHa.COOH C 21 H 14 4 .... 80-82 Weber and Zincke B.. 7, 1154 28, 156 P~ )> )> MM 210-212 V ) 5) Triphenylmethane-anhydro- COO.CPh5.aH3.COOH 244-246 Hemilian B., 16, 2373 46, 323 carboxylic acid COOH.CO =1.3 Dihydroxybenzoyl hydroxy- C 6 H 4 (OH).COO.C 6 H 4 .COO. C ;] H 14 7 .... 280 Klepl J. p., 28, 193 46, 447 benzoic acid C U H 4 .COOH =(1.4) 3 .... i> .... 275 .... J. p., 25, 525 Benzolone C,,H,.O,, (?) 248 Eochleder A., 41, 94 i., 562 Methylphenylanthranol C 6 H 3 Me:C 2 Ph(OH):C 6 H 4 21*^ Jo 2 \ / C 21 H,,0 .... 156-157 Hemilian B., 16, 2366 46, 322 Me.C(OH) =1.4 Methyl diphenylphthalide .... C ? H 3 Me.COO.CPh 2 =1.4.? C SI H 16 2 sb. 360 179 IT B., 16, 2362 46, 321 Dinaphthoxymethylene CH 3 (O.C 10 H 7 ) 2 =^ )) .... 133-134 Koelle B., 12, 1954 40, 177 COMPOUNDS CONTAINING THREE ELEMENTS. 293 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. 'Watts' Diet. & J. Ch. Soc. Methylphenyloxanthrol C 6 H 3 Me.CO.C 6 H 4 .CPh(OH) C 2 iH 16 O 2 .... 195 Hemilian B., 16, 2366 48,322 ?-Ketone Benzoin benzoate Orein dibenzoate j, Triphenylmethane dicar- boxylic acid Methylic acetylpulvate Triacetylgelangin Triacetyl emodin Tetracetylanhydropyrogallol ketone Tolyldiplienylacetic acid Tolyldiphenylmethane car- boxylic acid Isohydrobenzoin benzoate .... Hydrobenzoin benzoate Tolyldiphenylhydroxy me- thane carboxylic acid Eesocyanin Me.CO =1.4 2 isomers C 14 HuBz0 2 C 7 H 6 (OBz) 2 CHPh 2 .C 6 H 3 (COOH) 2 =?.1.3 C 17 H 10 O 3 Ac.COOMe C 15 H-0 5 Ac 3 C 14 H 4 .Me.(OAc) 3 : 2 co:[c 6 H 2 (OA C ) 2 ] 2 :o Me.C 6 H 4 .CPh 2 .COOH=1.4 CHPh 2 .C 6 H 3 .Me.COOH =5.1.4 C 14 H 12 .(OBz).OH 1 CPh,(OH).C 6 H 3 .Me.COOH a=I.1.3 C 2 iH 16 O 3 C 21 H 16 4 ) )) C 2 lHi 6 O fi C 21 H 16 8 C 21 H 16 O 10 C 21 H 18 2 C 21 H 18 O 3 ) 300-305 (30-40) C^H^O, ? 125 40 88 278-280 156 140-142 190 237 78-83 217 130 160-161 250-255 185 Weber and Zincke Zinin De Luynes Hemilian Spiegel Jahns Liebermann Buchka Thorner Hemilian Forst and Ziuck6 )! Hemilian B., 7, 1156 A., 104, 117 Z. C. [2], 4, 703 J. p. [2], 26, 65 B., 16, 2375 B., 13, 1634 B., 14, 2808 A., 183, 163 ; B., 8,971 A., 209, 271 A., 189, 83 B., 16, 2364 A., 182, 285 A., 182, 277 B., 16, 2371 J. p. [21 i., 560 vi., 885 46, 323 40,97 42, 866 31, 610 ; 29, 252 42, 61 34, 69 46, 322 30, 636 30, 635 46, 323 Oatechin From brown catechu CLiLaOo V. Cn.HonOo 140 Gautier C. R., 85, 342 32, 892 vellow catechu v. C, a H,oO 188-191 Ethoxytriphenylmethane .... Toluquinhydrone Ijeucotin CPh 3 .OEt cf. Co,H,,O, n a^o C 21 H 20 O 6 78 52 97 u. c Hemiliau Nietzki Jobst and Hess B., 7, 1208 B., 10, 835 B., 10, 252 28, 153 32, 476 32, 201 Cotoin ... .... .... .... cf. C.^H 1S O 6 124 Jobst 0. C. [1876], 167; 31, 480 ; 30, Acetone on furfuraldehyde C 8 H 3 O 2 cf. B., 14, 2469 cf. C,.H,,0,, 229 pd. 37-5 133 n c Schmidt Jobst and Hesse N. E. P., 25, 23 B., 14, 1459 B., 10, 251 425 40, 889 32, 201 Catechin cf. B., 13, 694 v H O 217 A. From catechin Resin from rosewood Acetylisoamyloxanthrol (?) Columbin C 2 iH 20 O 10 (C 21 H 21 6 X C^HsA CLHooO- b. 100 95 73 182 Terrell and Wolff Paterno & O ff lialoro B. S., 4, 8 B. S. [2], 33, 435 A., 212, 90 G. I., 9, 64 ; B 38, 559 38, 730 #-Salylic acid Datiscin 3C 7 H 6 O 2 .2H 2 O C 21 H 22 8 CoHooO,, 94-95 180 fjtadeler 12, 685 As., 7, 162 A. 98 167 vii., 1073 ii., 306 O TT 1 OHO 320 P A 107 331 ii., 709 Isophlorizin .... v - / 2? xl 3(r-'i7 Z. C. F21 4 741 vi., 927 Phlorizin .... .... 109 110 Stas Schiff B., 14, 303 iv., 494 40, 439 -Erythrin + H,,O .... Picrotin cf. C,-H, n O, j .... 115-116 240-245 A., 134, 245 ; B. S., 2, 424 B 14 818 40, 471 C. Ho O (i) 928230 hardt G I 8 440 ; B , 36, 728 t cf. C,-H, C O (' H O IfiO 12, 296 A i., 60 Dithymyl carbonate .... Helenin CO(O.C 6 H 3 .Me.Pr), cf. CLHoO '-'SI" 24^13 C 21 H 26 O 3 C H O a. 270 97.% 900 48 79 Eichter J. p., 27, 503 44, 1112 iii., 138 Heptiuic acid Benzomyristic anhydride .... I! !! Beuzoxymyristic acid Athei'osperma resin 3(C 7 H 10 2 )+H 2 C 14 H 27 O.OBz C 14 H, 7 Bz0 3 v -'21- n -28'~'3 C2lH 30 O 6 C 21 H 32 O 3 IJ C 21 H 32 O 4 C 21 H 32 O 5 150-151 36 38 68 114 Demargay Chiozza & Malerba Miiller Zeyer B. S. [2], 33, 575 ; A. C. [5], 20, 471 ; C. R, 86, 1135 A., 91, 104 G. T., 2, 789 B., 14, 2482 J. [1861], 769 34, 661 ; 40, 255 iii., 1073 i., 558 42,497 vi., 231 294 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Hydroxyheptinic acid 3C 7 H 10 3 .H 2 C 21 H 32 O 10 .... 185 Demargay C. E., 86, 1135 34, 662 Borneol carbonate (C IO H 17 ) 2 C0 3 C 2 iH 34 O 3 215 Haller C. E., 94, 86 ; 42, 528 ; 46, 98, 578 755 Menthol carbonate (C 10 H 19 ) 2 CO S CjjjHjgO,, 105 Arth C. E., 94, 872 42, 1213 Aldehyde from cenanthal- Me.(CH 2 ) 6 .CH : C.(CH 2 ) 4 Me CjiH^O 315-317 1. -10 Perkin B., 16, 1030 43, 72 > dehyde CH 2 .CH(COOH)(CH 2 ) 4 Me (300) Cetylic isovalerate C 4 H 9 .COO(C 16 H 33 ) C S1 H 42 3 280-290(202 25 Dollfus A, 131, 286 v., 980 Isoaniylic palmitate Ci 6 H 31 .COO(C 5 H u ) 9 Berthelot J., 6, 503 iv., 335 ,, .... 13-5 Duffy 5, 314 Methylic arachidate C 19 H 39 .COOMe 54-54-5 Caldwell A., 101, 98 ; J., 9, 492 Medullic acid.... C H COOH 72-5 Eylerts A. P. [2] 104, 129 ill., 864 Benzostearic acid " JJ C 22 H 4 A 76 i., 538 Glycerolmonstearate (mono- C 3 H 5 (OH) 3 (O.C 18 H 35 0) C 2 jH 42 O 4 .... 61 Berthelot A. C. [3], 41, 221 v., 422 stearin) Isoamyl cetyl oxide C 6 H 11 .O.C 16 H 33 C 21 H 44 30 Becker A., 102, 220 i., 842 From (cenanthaldehyde),, .... .... C 21 H 44 2 297-300 1. 20 Perkin 43,87 /3-naphthol aldehyde c^H^ro C 22 H 12 198 Eousseau A. C. [5], 28, 145 46, 180 ,, C 22 H 13 .OH C 22 H 14 250 C 10 H 6 .C(OH):C(OH).C 10 H 6 C 21 H 14 2 230 d. C. E., 94 and 95 1 1 Naphthoic anhydride (C 10 H 7 CO) 2 .0. =08 C 22 H I4 3 126 Hausamann B., 9, 1515 31, 318 I! 1! =#3 .... 133-134 31, 317 ,, ,, =aa .... 145 Hofmaun .B., 1, 42 ; A., 142 vi., 852 121 ? C 8 H 4 O(OBz) 2 C 22 H 14 O 5 165 Michael and Comej A. C. J., 5, 349 46, 598 Phenyl anthranolic acetate .... C 6 H 4 : C 2 Ph(OAc) : C 6 H 4 C 22 H 16 2 165-166 Baeyer A., 202, 57 38, 651 Tribenzoyl methane CHBz 3 C 22 H 16 3 .... 224-225 Baeyer and Perkin B., 16, 2135 46,64 Cresol phthalein anhydride.... : (C 6 H 3 Me) 2 : C.C 6 H 4 .COO 246 Drewsen A., 212, 340 42, 1098 =(1.4. ?) 2 ; 1.2 Phenyloxanthranolic acetate C 6 H 4 .CO.C 6 H 4 .CPh.OAc .... 194-196 A, 202, 61 Acetoxydiphenyl phthalein.... AcO.C 6 H 4 .CPh.C 6 H 4 .COO C 22 H 16 O 4 .... 135-136 Pechmann B., 13, 1615 40, 96 i i =1.? ; 1.2 Acetoxyphenyl oxanthranol C 6 H 4 .CO.C 6 H 4 .C(OH).C 6 H 4 . 207-270 sic B., 13, 1617 40,97 1 1 OAc Ethyl fluorescem C 6 H 4 :(CO) 3 :(C 6 H 3 ) 2 (OH) C 22 H 16 O 6 .... 155-156 Baeyer A, 183, 15 31, 197 (OEt):o Dinaphthoxyethane C 10 H 7 0.(CHo) 3 OC 10 H 7 =aa C 22 H 18 O 2 .... 125-126 Koelle B., 13, 1956 40, 178 =(3/3 217 5) B., 13, 1954 Cresol phthalin anhydride .... 0:(C 6 H 3 Me) 2 :CH.C 6 H 4 . C 22 H 18 O 3 .... 210 Drewsen A., 212, 342 42, 1099 COOH =(1.4. 2) 2 ; 1.2 Phenylglycol dibenzoate Ph.CH(OBz).CH 2 .OBz C 22 H 18 O 4 .... 96-97 Wachendorff and B., 10, 1006 ; A., 32, 614 Zincke 216, 295 Acid C 6 H 4 (CHPh.COOH) 2 110 Symons and Zinck6 B., 6, 1188 ; A., 27, 162 )J 171, 124 Cresol pbthale'in C 6 H 4 [CO.C 6 H 3 Me.OH] 2 213-214 Fraude B., 12, 237 ; A., 36, 635 =1.2 ; (1.3.4 or 1.4.3) 2 202; 153 Dibenzoxy dimethoxy benzene C 6 H 2 (OMe) 2 (OBz) 2 C 23 H 18 6 .... 245 Hofmann B., 11, 3,33 34, 418 a-naphthyl orthoxalate C 10 H 7 O.C(OH),,C.(OH) 2 . ,, .... 163 s. d. Staub and Smith .... 45, 304 OC 10 H 7 =oa P" 5, .... = 167 s. d. Diacetpolyporic acid .... .... 205 .... A., 187, 194 Cotoin .... .... ... ... v. C 21 H 20 O 6 130 Jobst and Hesse A., 199, 23 38, 326 Triacetylresacetei'n C 22 H 18 O 7 .... 229 J. p. [2], 26, 59 Benzylic benzylphenylacetate CH 2 Ph.CHPh.COOCH 2 Ph C^HjoOs, 320 (60) Hodgkinson 37, 486 ? .... 335 (50) Liquid 37, 484 Phenyl ditolylacetic acid (C 6 H 4 Me) 2 .CPh.COOH .... 78-83 Thorner A, 189, 124 34,69 =(1.4) 3 Dibenzhydryl benzene acetate Ph.CH(OAc).C 6 H 4 .CH(OH) C 22 H 20 O 3 94-97 Wehnen B.,9, 311 29, 916 Ph COMPOUNDS CONTAINING THREE ELEMENTS. 295 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J.Ch. Soc. o-Cresolphthalin .... C.ajH.,,,0,, 217-218 .... A., 202, 168 Hydrocotoin .... v. C 16 H 14 O 4 C 22 H 20 O 6 98 u. c. Jobst and Hesse B., 10, 252 32, 202 Benzopicrotin .. C 15 H 15 O 6 .OBz 245 Schmidt A., 222, 313 46, 846 From dioxyretistene C 22 H 22 O .... 89-90 Ekstrand A., 185, 103 32, 499 Ethylic polyporate .... C 22 H 22 O 4 134 .... A., 187, 193 Diacetpyroguajacol AcO.C 12 H 10 .O.C 6 H 6 .OAc C 22 H 22 O 5 122 Wieser W. A. [1881], 464 40, 813 Diethylic dibenzoylsuccinate COOEt.CHBz.CHBz.COOEt C 22 H 22 6 125-126 Baeyer and Perkin B., 17, 61 46, 838 dextrotartarate COOEt(CHOBz) 2 .COOEt C^HjjOs d. Liquid Anschiitz B., 14, 2790 42,831 >i d. 1. -17 Pictet B., 15, 2243 Benzoyl picrotoxide hydrate C 16 H 17 6 .OBz abt. 230 Paternd & Oglialoro G. I., 9, 57 36, 729 From Bath-a-barra wood .... (CogH-jA).. (C 22 H 23 O 4 ) n .... 135 Sadtler & Rowland A. C. J., 3, 22 40, 1042 Benzoyl hydrosautonide .... C 22 H 24 O 4 157 Cannizzaro G. I., 6, 341 31, 471 Ethylic a-isatropate .... .... 180-181 Fittig A., 206, 37 40, 426 Tetraethylrutigallic acid C 14 H 4 Et 4 8 C 22 H 24 8 180 + Klobukowsky B., 10, 885 32, 619 Primula camphor .... C 22 H 24 O 10 a. 200 49 Mutschler A., 185, 214 32, 904 Diisobutylcarbobenzonic acid .... C 22 H 26 Oj 148 Zagouinenny A., 184, 169 32, 195 Dithymyl quinonethylene .... CH 2 :c(C 10 H 12 o) 2 : .... 215 Jager B., 7, 1199 31, .263 Cuminoiin acetate C a H 11 .CH(OAc).CO.C 9 H 11 0^0, .... 75 Widman B., 14, 610 40,59 Benzylic santonate .... C 22 H 26 O 4 84-3 c. Panebiancho B., 11, 2032 Dieugenoxyethylene [CH 2 .O.C 6 H 3 (OMe)(C 3 H 5 )] 2 89 Cahours C. R, 84, 151 31,462 ,_ /"I TT f\ V. J_M.UKAV/ia C H O C H O 275 Paternd & Oglialoro B., 12, 865 Hesperidin (heaperetin gluco- 22 50 lo C 10 H U 6 +C,H 12 6 OaH^Oa .... 243-245 Paternd and Briosi B., 9, 250 29, 709 side) ,i abt. 245 Hoffmann B., 9, 690 32, 548 .... 245 E. Hoffmann A. P. [3], 14, 139 36, 468 jj ) > .... 261 Tiemann and Will B., 14, 946 40, 739 Tetracetsaccharovanillic acid C J4 H 14 (OAc) 4 .0 5 C 22 H 26 O 13 181-182 Tiemann and Nagai B., 8, 1141 29,78 Dithymol-ethylidene CH 2 :C(C 10 H 12 .OH) 2 CaH.,0, .... 170-171 Jager B., 7, 1198 31, 263 From campho-carboxylic acid C 22 H 28 4 .... 195-196 Kachler and Spitzer C. C. [1881], 359 42,66 Dicymoxyethaue (CH 2 ) 2 (O.C 6 H 3 MePr<') 2 C 22 H 30 O 2 Liquid Paternd G. I. [1875], 13 28, 638 JJ 99 Dithymolethane CH 3 .CH(C 6 H 3 MePrOH) 2 .... 180 Jager B., 7, 1197 31, 262 j N 185 Steiner B., 11, 287 34, 507 Camphocarboxylic anhydride (C U H 15 2 ) 2 O C 22 H 30 6 .... 265 d. Kachler and Spitzer C. C. [1881], 359 42,66 1 C 22 H 32 O 262-263 .... Fllickiger B., 9, 471 Anacardic acid v. C 44 H 64 7 C 22 H 32 3 .... 26 Stadeler A., 63, 141 Ethylic cholanate C^H^EtOe C 22 H 32 O 6 50-60 Latschinoff B., 13, 1055 38, 723 Camphocarboxylic acid .... 123-124 Kachler and Spitzer C. C. [1881], 359 42,66 Acetylcaryophyllin C 20 H 31 0(OAc) C 22 H 34 O 3 C 24 H 36 O 4 ? 184 Hjelt B., 13, 800 38, 670 Metacopaivic acid C 20 H 32 (COOH) 2 C 22 H 34 O 4 205-206 Strauss A., 148, 153 vi., 490 Gurjunic acid C 20 H 32 .(COOH) 2 260 220 Werner Z. C. [1862], 588 v., 1046 Paradigitaletin C 22 H 34 O 7 n. f. 100 Walz N. J. P., 9, 302 ii., 330 Hexethylic butonhexa- [C(COOEt) 2 .CH 2 .COOEt] 2 C-jsjH^Ojis .... 56 Bischoff B., 16, 1046 44, 912 carboxylate Masopin C H O 155 A., 46, 124 From chlorethylic ethyloxide .... a. 300 .... Lieben A., 178, 1 29,59 Acetylquebrachol .... Cs2H s ,O a 115 u. c. A., 211, 274 Menyanthin . . O TT O ? C 22 H 36 O U 60-115 iii., 881 ^30 46 14 Ethylic divalerylene-divale- .... C 22 H 33 3 250-280 Greiner J., 1865 or 1866 vi., 601 rate From benolic tetrabromide .... C 22 H 40 O 2 33 Haussknecht A., 143, 40 vi., 257 Benolic acid C^H^COOH 57-5 A., 143, 42 Dihydroxybenolic acid C 2 iH 39 O 2 -COOH C 22 H 40 4 90-91 A., 143, 46 From isobutaldehyde acetate C 20 H 37 3 (OAc) Cj.jH.oOs 240-242 Liquid Perkin 43,97 Erucic acid .... C 21 H 41 .COOH C H O 32-33 "Websky J. p., 58, 453 34 Fitz B., 4, 442 D > ^ 34 Darby A., 69, 4 ii., 501 Brassidic acid 56 Fitz B., 4, 444 vii., 470 59-60 Websky J. p., 58, 461 v., 1091; 24, 703 ,, 70 Haussknecht A., 143, 54 vi., 366 Ethylic dioctylacetoacetate .... C(C 8 H 17 ) 2 Ac.COOEt C 22 H 42 O 3 340-342 u. c. Liquid Guthzeit A., 204, 9 38, 872 296 ORGANIC COMPOUNDS. Name. Constitution. Formula Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. -Soc. Acetoarachidic anhydride .. .... C 22 H 42 O 3 60 Tassinari G. I., 8, 305 ; B. 36, 307 11, 2031 Acid from cholic acid .... 11 .... 67 Tappeiner Z. B., 12, 60 31, 213 Cetylid CjjHjjOs 62-65 .... Z. P. C., 3, 334 Pentadecylhexylketone Me(CH 2 ) 14 .CO.(CH 2 ) s Me C^H^O 231 (10) Krafft B., 15, 1718 Ethylic arachidate Cj 9 H 39 .COOEt C 22 H 44 O 2 50 .... A., 97, 261; 101,9 J) 11 .... 52-5 Gossmann A., 89, 1 i., 353 Benostearic acid .... .... 76 Volcker J., 1, 569 i., 538 Behenic acid C 21 H 43 .COOH 78 .... A., 64, 343 Isodihydroxybehenic acid .. C 21 H 41 (OH) 2 .COOH C^H^ .... 127 Haussknecht A., 143, 53 Limonin v. C 22 H 26 7 C^H^OU 124 .... i"., 699 Benzoxyquinone of C 16 H 12 .. C 16 H 9 :0 2 .OBz C^H!^ .... 120-121 Breuer and Zincke B., 11, 1996 36, 327 Acetyldihydroxybenzoylhy- C 6 H 4 .O.CO.C 6 H 4 .OAc droxybenzoic acid 1 =(1-4) COOC 6 H 4 .COOH CsftA .... 185 Klepl J". p., 28, 193 46, 448 Acetoxyhydroxybenzoic an- AcO.C 6 H 4 .COO.CO.C 6 H 4 .OH .... 230 J. p. [2], 25, 526 48, 1294 hydride =(1.4) 2 Ethylic /3-dibenzoylbenzoate (C 6 H 5 .CO) 2 .C,H 3 .COOEt C^H^O, 106-5-107 Weber and Zincke B., 7, 1155 88, 156 Dibenzoylmesitylene Me 3 .Bz 2 =1.3.5.4.6 C^A .... 117 Louise C. R, 98, 151 46, 904 Dihydroxytriphenylcarbinol From (HO.C 6 H 4 ) 2 .CPh(OH) C 23 H 20 O 6 .... 119 Doebner B., 12, 1465 38, 240 diacetate Aurin + acetic anhydride .. (HO.C 6 H 4 ) 2 .C.C 6 H 4 .p+Ac 2 C^H^O, .... 159-160 Caro and Grsebe B., 11, 1122 34, 795 11 11 11 151 11 11 B., 11, 1349 11 11 11 M ,, .... 168 Dale &Schorlemme 35, 154 Xanthorhamnin 0^,0,4 2 C^H^OH .... b. 100 (?) Kane P. M. [3], 23, 3 v., 1053 Aurantiin (Hesperidin) C 23 H 26 O 12 171 E. Hoffmann B., 9, 691 30, 421 Naringin 171 A. P. [3], 14, 139 36, 468 .... 11 11 MM 100 11 11 11 Dieugenoxypropane .... (C 6 H 3 .OMe.C 3 H 6 .0) 2 C 3 H 8 CjjHjA .... 56-58 Cahours C. R, 84, 1195 38, 479 11 (C 6 H 3 .OMe.C 3 H 6 .0) 2 (CH 2 ) 3 ,, 82-5 11 11 Xanthorhamnin C 23 H 24 O 14 1 C" 1 TT r\ V '23 xl 28 v -'l4 .... b. 100 (?) Kane P. M. [3], 23, 3 v., 1053 Ethyloctoethenylisopropyl- C^H^CPr/s.COOH C 23 H M O.! a. 360 Geuther, Frohlich, A., 202, 325 38, 623 acetic acid and Looss Gardenin .... .... ^ v. C 6 H 5 O 2 O TT O 155 Fliickiger P. J. T. [3], 7, 589 38, 501 From dikamali resin C^H 34 ol(?) I b. 100 11 11 11 Cetylicbenzoate CeHs.axxc^H.j C 23 H 3S O 2 .... 30 Becker A., 108, 219 ? ketone .... C 23 H 42 200-210 Geuther, Frohlich, A., 202, 328 38, 623 and Looss Diethylic dioctylrnalonate .... C(C 8 H 17 ) 2 (COOEt) 2 C 23 H 44 4 338 Liquid Conrad and Bischofl B., 13, 597 38, 628 11 11 338-340 .... Conrad A., 204, 163 cetylmalonate CH(C 16 H 33 )(COOEt) 2 300-360 11 A, 206, 357 Laurone (CnH.ACO C H O 69 Krafft B., 15, 1712 48, 1272 \ 11 &/4 23 46^ 66 Overbeck A., 84, 289 iii., 476 Isoamylic stearate C 17 H 3 ' 5 .COO(C 6 H n ) cJEi 46 o 2 25 Hanhart C. R, 47, 230 v., 420 11 i> .... 11 .... 25-5 Duffy A., 88, 293 5, 197 Alcohol from caniiba wax .... .... C 23 H J8 O .... 78 Maskelyne 22,87 vi., 391 Benzeneresorcinphthalem di- (AcO) 2 C 6 H 3 .CPh.C 6 H 4 .COO C 24 H 8 O 6 .... 137 Pechmann B., 14, 1860 acetate Dibenzoxynaphthalene C 10 H 6 .(OBz) 2 C 24 H 16 O 4 138-139 Weber B., 14, 2209 42,205 Diacetyl fluorescein c 6 H 4 :[co.c 6 H 3 .(OAc)] 2 :o ciJX 200 E. Fischer B., 7, 1211 88, 159 11 11 ,, .... 200 Baeyer A., 183, 13 31, 197 quinolphthalein .... C H 4 (CO.C 6 H 3 .OAc) 2 .... 210 u. c. Ekstrand B., 11, 715 34, 675 Quercetin ... O TT O a. 251 v., 4 From /8-naphthol aldehyde .... Cj2Hu.OH.OEt c^niX' .... 144 Sousseau A. C. [5], 28, 145 ; 46, 181 ; 42, C. R, 95, 232 1300 Diacetpseudorosolic acid C 20 H 12 3 (OAc) 2 C2 4 H 18 O 5 .... 100 Zulkowsky B., 11, 1429 34,873 Phenolphthalidei'n diacetate / CO.C 6 H 4 .OAc QB^C 1 1 C 24 H 18 6 .... 109 Jaeyer A., 202, 105 ; B., 9, 1236 31, 309 N CO.C,H 4 .OAc Phenylresorcinphthalem di- C 6 H 3 (OAc) 2 .CPh.C 6 H 4 .COO )1 .... 137 'echmann B., 14, 1861 42, 184 acetate l 1 = 1.3.?; 1.2 COMPOUNDS CONTAINING THREE ELEMENTS. 297 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch.Soc. Phenolphthale'iu diacetate ... C 6 H 4 (CO.C 6 H 4 .OAc) 2 C 24 H 18 O 6 ...* 143 Baeyer B., 9, 1232 ; A., 31, 308 202, 74 Dibenzoresorcinol diacetate... C 6 H 2 (OAc) 2 .Bz 2 =1.3.?.? .... 150 Dobner and Stack- B., 11, 2273 36, 320 maun .... 150 Dobner A., 210, 260 42, 508 (juinolphthalin diacetate CH 18 ; 190-191 u.c. Ekstrand B., 11, 716 34,676 Pheuyl ethaldehyde G^HjoOj .... 102 Erlenmeyer B., 13, 304 38, 472 1 C 24 H 20 O 3 170 Hodgkinson 37, 484 Glyceroltribenzoate (tri- BzO.CH(CH 2 .OBz)j CTT (~l 24 C1 2 3t"i(P J * 1 t \J _ IU Cholic acid OTT f~\ 145-150 Richter R. K. T., 433 '.... 24 "^40 5 C 24 H 42 O 110-120 A., 180, 8 i ' TT o 1. 17 Planta-Reichenan A., 155, 150 vii., 20 24 )2 3 .... 2 Q '298 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Gh. Soc. From isobutaldehyde C 20 H 36 2 (OAc) 3 C 24 H 42 O 8 248-252 Liquid Perkin .... 43,98 Achillea ageratum ... .... C 24 H 44 O S 180-182 1. -18 Luca J. Ph. [4], 23, 105 31, 326 isobutaldehyde .... C 24 H 44 O 4 250-255 .... Perkiu .... 43, 99 Cerosin .... C 24 H 48 O .... 82 Lewy A., 37, 170, 173; i., 836 A. C. [3], 13, 451 Heptadecyl hexyl ketone ... Me(CH 2 ) 16 .CO.(CH 2 ) 6 Me 248 (10) Krafft B., 15, 1718 Octylic palmitate C 15 H 31 .COOC S H 17 C 24 H 48 O 2 .... 8-5 J. [1858], 301 Ethylic benostearate C 21 H 43 .COOEt 11 .... 48-49 VOleker A., 64, 344 i., 538 Gingkoic acid 35 Schwarzenbach J. [1857], 529 v., 174 Paraffinic acid .... .... 45-47 Pouchet B. S., 23, 111 ; 28, 50 C. R., 79, 320 Lignoceric acid C^Hjj.COOH 80-5 Hell and Hermann B., 13, 1713 40, 249 Cerosinic acid .... .... 93-5 Lewy A. C. [3], 13, 451 ? acid .... .... 62 Kessel B., 11, 2115 Diglycerol monostearate C 3 H 6 (OH) (OEt).O.C 3 H,,(OH) 2 C 24 H 43 O 8 30 Hundeshagen J. p. [2], 28, 219 46, 282 Dibenzoxymethyl naphtho- C 10 H 3 Me : O 2 (OBz) 2 C 25 H I6 O 6 285 d. Thoruer B., 12, 1632 38,47 qviinone Diphenylphenyl ketone (C' a H 5 .C 6 H 4 ) 3 CO C 25 H 1S O 226 Weiler B., 7, 1189 28, 152 Diphenylbenzhydrol (C 6 H 5 .C 6 H 4 ) 2 CH.OH C^H^O .... 151 11 11 ,, Triacetylaurin Ph.C(OAc) : (C 6 H 4 .OAc) 2 CaH.,0,; .... 138-139 u.c. Caro and Grsebe B., 11, 1117 34,794 Ethylic dibenzoylphenyl Ph.CH(OBz).CH(OBz). ' .... 109 Anschiitz and Kin- B., 11, 1221 34, 981 glycerate COOEt nicutt .1 ii .... 109 B., 12, 539 36, 645 Triacetoxy tripheny Imethj. ne CH(C 6 H 4 .OAc), H .... 180 Hemilian B., 7, 1205 28, 152 Resocyanin diacetate C 21 H 16 4 (OAc) 2 C 25 H 22 O S 150 .... J. p. [2], 24, 127 Benzylchloride on phenylic .... C 26 H S4 3 255 (i.v.) ; Liquid Perkin&Hodgkinson .... 37, 722 acetate 310-320 (760) 11 .... 318-322 (760) Liquid 11 .... 37, 725 Di-j3-naphthylic diethylic (C 10 H ; 0) 2 C(OEt) i C 35 H 24 4 298-301 .... Bender B., 13, 701 40,48 orthocarbonate Diacetyl catechin C 21 H 13 Ac 3 9 11 Cj S H M O,, MM 129-131 Liebennann and B., 13, 695 40, 53 Tauchert Eupittonic acid .... C 25 H 26 O 9 200 p.d. Hofmann B., 11, 1457 34, 871 Dibenzyl methoxycymene .... C 6 HMe.Pr.OMe.(CH 2 Ph\j CosH^O .... crystalline Mazzara G. I., 11, 433 42, 173 Rutin C 25 H 23 O 15 a. 190 Richter R. K. T. 436 Picrotin C^TIjjO,, 240-245 Schmidt and Lowen- B., 14, 818 hardt of- C 21 H 24 10 11 245; 250-251 Barth and Kretschy W.A.,81,7;B.,13. 40, 286 1243 Robinin CjjHajO,, lQ r Zwen^er & Dronke A q 1 9^7 1 1 ' AS., 1, l Sylvinolic acid .... C 25 H 3(i O 4 .... 130 d. Maly W. A. B. [2], 44, 121 v., 650 Benzostearic anhydride C, s H 33 O.O.Bz C 25 H 40 O 3 70 Chiozza & Malerba A., 91, 104 i., 558 11 11 .... 100 Ohiozza v., 420 Cholestenic acid .... C 25 H 40 O 4 60-70 J. R,, !), Si Oxycholestenic acid C 25 H 40 O 5 80-100 )J Amyrin C 20 H 34 O ? C 26 H 4 . Buri N. R. P. 95 193 SO 49T OV/, ^^O Ledum camphor v."c 5 H 8 2 C 25 H 44 2 101 Hjelt and Colland B., l.j, iT>01 44, 346 Am brain C 26 H 48 O 3M Afi 9 r > -. ' '. ' Valero-arachidic anhydride.... C 19 H M .CO.O.CO.C 4 H 9 C., 5 H 48 O, .... 68 Taasinari G. I., 8, 305 ; B., 36, 307 11, 2031 Isoamylic arachidate C, 9 H 39 .COOC 6 H n C 25 H5o02 .... 44'8-45 Caldwell J., 9, 492 ; A., 101, 91) Methylic lignocerate C 23 H 47 .COOMe ... 56'5-57 Hesse & Hermann B., 13, 1717 40, 250 Hyoenic acid .... C 24 H 49 .COOH " "7Q p AT *^Q 1 fift vi 7O1 11 / / /o V"ll HIM ., 1O.7, 11>O VI., t \J 1 (or else cerotic acid) C. -H 54 (X 7fi_70 Sclnil/c iind A.llrich J. p. [2] 9 321 27, 1080 i \j i tj Fluorenic oxide (C 6 H 4 .C 6 H 4 .CH) 2 G 26 H 13 abt. 290 Barbier A. C. [5], 7, 507 ; 31, 73 ; SO, 78 C. R., 80, 1396 Dibenzoyl-diphenyl C 12 H 3 .Bz 2 O,, 6 H 18 O,, 218 Wolf B., 14, 2031 42, 62 From oxydiphenyl ketone .... .... C 26 H 18 O 3 19!) Richter J. p. [2], ^3, 350 42,618 C 22 H 12 (OAc) 2 ^6H 13 O 4 .... I!)-' .... C. R., 94, 133 COMPOUNDS CONTAINING THREE ELEMENTS. 299 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Rhamuetin dibenzoate C 12 H 8 3 (OBz) 2 C 2 ,H 1S 0. .... 10-212 jiebermann and A., 196, 321 ; B., 36, 272 HOrmann 11, 1620 Bye product of a-benzopina- CHPh 2 .O.CHPh 2 a.H^o .... 07-108 'horner and Zincke B., 11, 1399 34,874 colin a-Benzopinacolin 58-159 ,, B., 11, 66, 68 34, 425 B- CPh 3 .CO.Ph B 78-179 " t, 11 H 11 8- n .... 78-179 )! 51 B., 10, 1475 34, 223 r j 11 204-204-5 11 11 B., 11, 1396 34,874 "- ,. Tetraphenylethylene oxide.... CPh.,.CPh 2 .O L " _J J) 5) 93-194 Behr B., 5, 278 5,472;vii.,1150 Tetroxytetraphenylethylene Benzaldehyde on resorcinol..., Orcinphthaleiin diacetate .... (HO.C 6 H 4 ) 2 .C:C.(C 6 H,.OH) 2 C 26 H 16 (OH) 4 C 26 H 30 O 4 C 26 H 20 7 .... a. 300 330 d. 219-220 219-220 u. c. u Michael Jaeyer S. Fischer 11 A. G. J., 5, 339 A., 183, 66 B., 7, 1211 11 46, 597 31, 205 28, 160 11 11 "" Cresorcinphthaleliii diacetate .... .... 260 d. Snecht B., 15, 1069 ; A., 215, 96 Phenylpyrogallolphthalem- (AcO) 3 .C e H 2 .CPh.C 6 H 4 .COO C 26 H 20 8 .... 231 Pechmann B., 14, 1864 triacetate Di-benzhydrol oxide (CHPh 2 .) 2 C 26 H 22 315 (745) 110 111 Friedel and Balsohn Linnemann B. S. [2], 33, 341 A., 133, 14 38, 559 iv., 478 11 "' 118 A., 133, 17 38, 559 Isobenzopinacone 11 C 26 H 22 2 297-5 (733) b. 15 j A., 133, 27 iv., 649 .... 31 11 11 Benzpinacone .... " 168 170-180 Zoegoumenny Linnemann B. S. [2], 35, 560 A., 133, 27 40, 813 iv., 648 11 " "" 185-186 Thorner and Zinck6 B. S. [2] 35, 560 40, 813 CPh 2 (OH).CPh 2 (OH) .... 185-186 i'i B., 10, 1473 34, 223 Tetrahydroxytetrapheuyl- C*H SO (OH) 4 C 26 H 22 O 4 248 Engler B., 11, 930 36, 69 ethane Cresolphthalein diacetate .... C 6 H 4 (CO.C c H 3 Me.OAc) 2 C 26 H 22 O 6 .... 73-74 .... A., 202, 156 = 1.2; (1.3.4 or 1.4.3) 2 M 73-75 Fraude B., 12, 238 36, 635 Orciuphthaliu diacetate C 6 H 4 : [O : (CH.C 6 H 2 Me. .... 211 Baeyer A., 183, 73 31,206 OAc) 2 ]:O 211 E. Fischer B., 7, 1215 28, 160 Phenolphthalol triacetate .... (AcO.C 6 H 4 ) 2 CH.C 6 H 4 .CH 2 C 26 H 24 O 6 40 Baeyer A., 202, 90 38, 656 OAc Cresolphthalin diacetate Diphenolcresolmethaue tri- acetate (AcO.C 6 H 4 ) 2 CH.C 6 H 3 Me. OAc .... 138-140 148-149 Caro and Grebe A., 202, 169 B., 11, 1116; A. 179, 199 34, 794 Haematoxylin pentacetate ... C 16 H 9 0(OAe) 5 OH"? 1 165-166 abt. 88 Anderson A., 216, 234 J. [1876], 896 30, 585 Dibenzylacetoxycynieiie Rosolic acid C 6 H.OAc.Me.C 3 H 7 .(CH 2 .Ph) C 26 H 28 2 26 H 28 Oi 82-85 156 Mazzara Fresenius G. I., 11, 346 J. p. [2], 5, 184 42, 173 vii., 1061 C 2U H 18 O 4 ? abt. 158 Caro and Wauklyn .... vii., 391 11 11 Diisobutylic dibenzoyl dex- COOC 4 H 9 .(CH.OBz) 2 . C 26 H 30 8 d. Liquid Anschiitz B., 14, 2790 42, 831 trotartrate COOC 4 H 9 d. 1. 17 Pictet B., 15, 2243 11 11 " Limonin v. C 22 H 26 7 C :2 H bo O 13 244 .... 36, 730 245 E. Hoffmann A. P. [3], 14, 139 36, 468 275 Paterno & Oglialoi G. L, 9, 64 36, 730 Action of acetochlorhydroue .... C 26 H 3U 15 184-185 Michsel B., 15, 1922 44, 77 ; 46, 439 AC* T *} 1 7 on sodium salicylate . VA W .j 7H 13 O 3 C 2? H 13 5 I 11 1) 11 1 11 C 27 H 18 6 C 27 H 20 O 4 C 2 ;H 24 O 4 C^A CjyH^Ojo 305-310 38-5-39 - 4-5 55 a. 300 a. 447 214 204 101-102 101-102 181-182 181-182 95 141 141 259-261 156 156-5-157 136 213-5 a. 310 Hanhart Hell and Hermann Gabriel and Micline 51 Grwbe and Ebrard Dianin Stsedel Stoedel and Saur Stedel Gail Dcebner and Stack- mann Gabriel and Michae Beck Mehu Stenliouse & Groves Pateruo & O< r lialoro A., 51, 98; 95, 164 C. R., 47, 230 B., 13, 1715 B., 10, 1557 B., 11, 10C7 B., 15, 1678 B., 7, 125 A., 218, 339 B., 13, 836 A., 218, 339 B., 11, 746 ; A., 194, 335 A., 210, 262 B., 11, 2271 A., 210, 258 B., 11, 1008 A., 194, 325 J. [1876], 620 J. P. [4], 3, 265 G. I. [1882], 23 G I 6 531 v., 420 40, 250 42, 1301 vii., 84-2 44, 990 38, 646 44, 990 34, 672 ; 36, 326 36, 320 34, 734 36, 325 vi., 584 39, 236 31 720 Diraethylic eupittonate Fraxin.... v. C-JLoO,,, Pl^flPi C. II,,0 242 320 Hofmanii Rochleder B., 12, 2219 P A 107 331 38, 165 ii 700 Mesitylene quinhydrone Apiin .. v. Co.H^O,, C 27 H 32 6 (?) 142-143 180 Fittig Planta and Wallace B., 6, 1400 A 74 262 27, 263 328 w c Gerichten B 9 1124 Phillyrin C ,H O 160 A 92 109- 108 iv 487 Acetyl amyrin ] ketone .... .... OpH^O, C H O 240 "60 198 Buri Geuther and Loos 124 N. R. P., 25, 193 A 202 329 30, 423 38 623 Cinchocerotin .. ('HO 130 A P [3] 21 279 46 '}^o Glyceryllaurate(laurostearin) 1 C 2; H 52 5 ? Qi7H 50 O 4 .... abt. 44 44-45 Marsson A , 41 329 iii., 475 Myristone (C,,H,,1CO C H O 76-3 Krafft B 15 1713 42 1 "79 Overbeck P A 86 591 iii 1073 Cerotic acid C 26 H 53 .COOH j CVH O 78 i 837 it jj )) n 78-79 81-82 Brodie Maakelyne A., 67, 180 J 5 525 n j > i MM 78 Gill and Meusel 21, 466 vi., 421 COMPOUNDS CONTAINING THEEE ELEMENTS. 301 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. CjsH^.COOH C^H-.O. 76-79 Schulze and Albrich J. p. [2], 9, 321 27, 1080 *7 a-* 2 81-82 Fliickiger A. P. [3], 7, 8 29, 616 Isoeeryl alcohol C^OH Cvi

t B., 5, 1105 26,489 Oxyisolepidene .... 152-5 J. [1877], 396 11 .... ,, 161 J. [1877], 395 11 .... .... 162 J. [1877], 396 From oxidation of C^ILoOj .... CjaH^O, i... 98 Breuer and Zincke A., 198, 141 38, 117 Dioxylepidene .... 157 Zinin Z. C. [2], 7, 483 Dioxyisolepidene .... 164 B., 8, 696 28, 1005 Tetracetcoerulein C^H^O,,, 256 Buchka A., 209, 276 Tetracethydrogallei'n c 6 n 4 .coo.c:[c 6 H 2 (OAc) 2 ]:o C^H^OH .... 247-248 A., 209, 263 42,60 Diacetquercetin C 24 H 14 8 (OAc) 2 CaH^O,, 196-198 Liebermann and B., 12, 1183 36, 945 Hansburger Dihydroisolepidene .... .... CssHjjO 182 Zinin J. [1877], 394 Hydro-oxylepidene .... CjsHjjO,, 251 B., 8, 696 28, 1005 Oxylepidenic acid .... C^H^Oj .... 196 B., 5, 1104 26, 489 Isoxylepidenic acid .... 166 J. [1877], 397 Benzoin ether .... 11 ... 157 .... A., 155, 94 From hydro and isohydro- .... 11 154-5-155 Breuer and Zincke A., 198, 169; B., 34, 321 ; 38, benzoin 11,76 117 Isohydrobenzoin dibenzoate C 14 H 12 (OBz) 2 CajH-.A .... 153-154 Forst and Zincke B., 7, 1714 28, 454 11 11 .... 155-156 11 !> A., 182, 287 30, 636 Hydrobenzom dibenzoate .... ,,,, 246-247 11 11 B., 7, 1714 28, 454 ,i 11 .... 247 11 11 A., 182, 278 30, 635 11 11 242 Breuer and Zinckfi A., 198, 141 38, 117 Dibenzoxy diphenylethane.... CH 3 .CH(C 6 H 4 .OBz), 11 .... 152 Fabinyi B., 11, 286 34, 431 a-Pyrocressol oxide .... s. 168 Schwarz B., 15, 2204; 44, 206 M. C., 3, 733 - i, .... .... s. 95 11 11 11 11 y- I- .... s. 77 11 11 11 11 Benzilic anhydride C 28 H 22 O 5 196 Jena B., 2, 385 vi., 306 Tetracetylgallin COOH.C 6 H 4 .CH: C^HjjOn 220 Buschka A., 209, 269 42,61 [O fi H 2 (OAc) 2 ] 2 :0 C^ TT O 108 Jena and Limpricht A., 155, 100 vii., 169 Tetrahydroisolepidene 11 .7 132 Zinin J. [1877], 395 /3-Tolylphe.nyl piuacolin C 6 H 4 Me.CPh 2 .CO.C 6 H 4 Me IT 136-157 Thorner A., 189, 108; B., 30, 198 9,485 B- or Bz.CPh(C B H 4 Me) 2 136-137 Thorner and Zinck6 B., 10, 1477 34, 223 a- 1 /CPh.C 6 H 4 .Me \l N CPh.C 6 H 4 .Me " .... 214-315 Thorner A., 189, 108; B., 9, 484 A., 179, 184 34,68; 30,198 29, 589 Triacetylcoto'in CaHaAcyO, 4 0^0* 94 Jobst and Hesse A., 199, 27 38, 326 Tetraacetpupurogallin C 20 H 12 Ac 4 O 9 28 H 24 O 13 ..* 186 Clermont and C. E., 94, 1362 42, 1066 Chautard Tolylphenyl pinacone .... C^H^O., .!.. 164-165 Thorner and Zincke B., 10, 1476 34, 223 302 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Isodesoxybenzo'in pinacone.... CssHjiA, .... 161 Limpricht and A., 155, 98 Schwanert Desoxybenzo'in .... 156 )) 5? A., 155, 62 vii., 173 a-Pyrocressol .... (C.H.Me.aHaMe). : O. >i .... MIS a. 195 Sagunieuny Schwarz B., 5, 1102 M. C., 3,729 ;B., 26, 502 44, 206 \ vy g*~*-4^^ 6"^a^^ /* * 15, 2203 /s- .... s. 124 ) )) M y- j. s. 104-105 )J )J )i Benzoin pinacone CHPh(OH).(CPhOH) 3 . CsftA 208 Goldenberg B., 7, 287 ; A, 27, 694 ; 28, 365 CHPh(OH) 174, 333 Triacetyl leucorosolic acid ... C 6 H 3 .OAc(CH 2 .C 6 H 4 .OAc) 2 CWHjjOj 148 Grsebe and Caro A., 179, 184 29,590 M ) .... 148-149 )J Oxidation of CggH^Og CjijHjoOj 1 C3H 29 O 4 .... 98 Breuer and Zincke A., 198, 141 38, 117 Colouring matter of Beth-a- CjjHjA ? C^H^OS 135 Sadtler & Rowland A., C. J., 3, 22 40, 1042 barra wood Anhydride of curcumin di- (C 14 H 16 4 ) 2 C-aHajOs .... abt. 120 Jackson and Menke A. C. J., 4, 360 44, 481 hydride Erythric acid.... Oixi ttontJl I 137 Hesse A., 117, 304 ii., 502 Bixin .... 28 30 14 t_J 1 n H 1 i ( 'r 175-176 Etti B., 11, 865 34, 739 Cetylic benzoate C 6 H 5 .COO(C 16 H M ) 28^^34 6 CH^ .... 30 Becker A., 102, 219 i., 840 Octacetsaccharose C 12 H 14 (OAc) 8 3 CasHgaO i 9 39-40 Demole B., 12, 1936 ) 78 u. c. Herzfeld B., 13, 267 38, 620 lactose i .... 52 Demole B., 12, 1936 ,, 86 u. c. Herzfeld B., 13, 266 diglucose 5> *j .... 39-40 Demole B., 12, 1936 J ) 100 Franchimont B., 12, 1940; 38, 159 C. R., 89, 713 jj J> u .... 134 Herzfeld B., 13, 266 38, 619 maltose ,, .... 150-155 d. j A., 220, 206 46, 171 i .... 152 u. c. B., 13, 267 38, 620 /3-Paracatol .... ^28^40^*2 236 Jobst and Hesse A., 199, 80 38, 328 y- .... 240-242 )> 3> A., 199, 81 JJ Urechitin .... C 29 H 4 oO 8 b. 260 Bowrey J. [1878], 974 33, 267 Cholesteryl acetate C 26 H 43 .OAc C 23 H 46O 2 .... 92 Loebisch B., 5, 513 vii.,329; 25,808 Isocholesteryl acetate .... > b. 100 Schulze J. p. [2], 7, 174 26, 1219 Resin from Gurjun balsam .. .... ji .... 126-130 Fliickiger A. P. [3], 12, 58 34, 439 Cholesteryl acetic anhydride CjsH^Oa no .... J. [1863], 545 From isobutaldehyde ) 227-229 (100 Liquid Perkin 43, 100 Stearocutic acid .... C 2 8H 48 4 .... 76 Urbain Ann. Agronom., 46, 859 9, 529 Aldehyde from OBiianthalde- hyde Me(CH 2 ) 5 .CH :C.(CH 2 ) 4 .Me CH:C(CH 2 ) 4 .M Me(CH.,) 4 .C(COOH):CH C 8 H 60 O 330-340(350) 330-340(300) 335-340 (350 1. 20 Perkin B., 15,2805,2807; 16, 211 43, 50-64 a-Jalapic acid .... P"*iOu .... b. 80 Mayer A., 95, 158 iii., 437 Myristic anhydride (C 14 H 27 0) 2 C 2 sH H Oj .... b. 54 Chiozza & Malerba G. T., 2,789 iii., 1072 From polymerised cenanth- Me.(CH 2 ) 6 .CH(OH) 330-340 (200 1. 10 Perkin B., 16, 1035 43, 82 aldehyde Me.(CH 3 ) 4 .CH.CH(OH) Me.(CH 2 ) 4 .CH. CH : C(COH).(CH 2 ) 4 M Geoceric acid C i8 H 56 Oj 82 Bruckner J. p., 57, 1 U., 831 Geocerain .... )> 80 )T J. [1852], 649 Dodecylpalmitate C 16 H 81 .COO.(CH 2 ) n Me j .... 41 Krafft B., 16, 3020 46, 572 CEnanthaldehyde (polymer) Me.(CH 2 ) 6 .CH(OH) Me.(CH 2 ) 4 .CH.CH(OH) | C 2 sH 56 O 4 d. 115 52-53 Perkin 43,80 Me.(CH 3 ) 4 .CH.CH(OH) Me.(CH 2 ) 4 .CH.COH Dibenzchrysophanic acid .. .... C 29 H, 8 O, .... 200 .... A., 183, 173; 212, 38 COMPOUNDS CONTAINING THREE ELEMENTS. 303 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. C H O 192 u. c. Hart A. C. J., 5, 39 46, 332 Diacetyl eupittonic acid C^AcA c^LK 265 d. Hofmann B., 12, 2218 38, 165 Diethylic eupittonate .... C 29 H 34 0, 201-202 B., 12, 2220 O TT O 162 J. [1855], 715 Resineon .... .... .... C 29 H 34 O ' 2 148 Liquid Fremy A., 15, 284 41, 167 Diacetoxyhydroxycholesterin C 25 H 40 0(OAc) a C*H 4 6 6 S 77 Latschiuoff B., 11, 1942 36,135 Isoserylic acetate CH 3 .(JOOC 27 H 55 CjgH^Oj 57 Kessel B., 11, 2114 36, 262 Ethylic cerotate C 36 H 53 .COOEt 59-60 Brodie A., 67, 189 i., 837 60-3 Duffy J., 5, 511 i .... C 30 H 20 O, 246 M. C., 1, 234 Dibenzocampheride C 16 H 10 O 6 Bz, C 30 H 20 O 8 185-186 Jahns B., 14, 2388 42, 209 ? C 15 H 12 0? C, H n O 217-218 Bornstein B., 15, 1823 From dioxyretistene.... .... CsoH^O., .... 151-152 Ekstrand B., 17, 693 46, 1041 Pentacetyl coerulin C 6 H 4 .C .C,Hj(OAc)jv C 30 H 22 Ou 256 Buchka A., 209, 249 42, 62 C(OAc).C 6 H(OAc) 2 / Tribenzoylmesitylene .... C 30 H 24 O, 215-216 Louise C. R., 98, 1440 46, 1000 Patchouli camphor v. C 15 H 26 O C, H,, 3 O 2 296 54-55 Gal Z. C., 12, 220 From dioxyretistene .... C 30 H 26 O 2 90-91 Ekstrand B., 17, 693 46, 1041 Diphenylmethylic succinate (OH 2 .COOCHPh 2 ) 2 C 30 H 26 4 141-142 Linnemann A., 133, 23 iv., 479 Etliyldibenzoin CPh 2 (OEt).CO.CO.CPh 2 OH 200 Limpricht and B., 4, 336; A., 24, 536; vii., Schwanert 155, 93 170 Lapaconic anhydride .... C 30 H 26 O 5 155-156 Patern6 B., 16, 803 r 1 TT o 170-178 A., 212, 29 ^"30 26^7 Dibenzoyl hydroccerulignone C 16 H 16 Bz 2 6 C 30 H 26 O 8 .... 244 Liebermann B., 6, 382 ; A., 26, 1033 ; vii., 169, 237 377 Pentacetgallol OH 2 (OAc)C 6 H 4 .CH : C 30 H 26 O n .... 230 Buchka A., 209, 269 42,61 [C 6 H 2 (OAc) 2J2 :0 ? ~.. C 30 H 28 4 abt. 120 Hodgkinson .... 37, 486 (C 10 H 4 .C 5 H ll .OH)," | (Oj) 2 " C H O 116-117 Paternd G. I., 22, 337; B., 44, 213 16, 803 He xamethy Iquercetin C 24 H 10 Me 6 O n C 30 H 2S O n 156-157 Herzig M. C., 5, 72 46, 847 Triopianid \: C 40 H 38 O 19 CjoH^Ou 225-227 M. C., 4, 263 From rottleratinctoria .... C 30 H 30 O 7 100 Anderson E. N., 1, 300 v., 118 ? .... C 30 H 32 O 2 .... 134 Ekstrand B., 17, 694 46, 1041 v C ~EL PRO 235 d. J. [1855], 713 Picrotoxin .. .... .... v. C,,,H,,O. ^30 1 54^13 C HO 200 Paternd & Oglialoro B., 14, 541 12 14 5 C H O 36 40 16 220 Riban Z. C. [1866], 1663 v., 1090 Oymylenethymol (C 6 H 3 .Me.Pr.O) 2 (C 10 H, 2 )" C^0 2 157 Engelhardt and Z. C. [1869], 43 vi., 1090 Latschinoff From oil of monarda .... C 3U H 42 224 Liquid Arppe A., 58, 41 iii, 1046 C'amphrone C_-H. ,O 75 Liquid Fremy A. C. [2], 59, 16 i., 733 From sandal wood I Vy 30 44 280-285 Chapoteaut B. S., 37, 303 44,76 Echiceric acid C 30 H 46 O 4 100 + Jobst and Hesse A., 178,64 29, 277 Echicerin C 30 H 48 O 2 157 A., 178, 61 29, 276 (/ubebene hydrate .... C 30 H 49 +2H 2 C 30 H 52 2 148 67 Schaer and Wyss A. P. [3], 6, 316 29, 942 Lithobilic acid GjgH^.COOH 199 Roster G. I., 9, 462 ; B., 38, 271 12, 1925 C H COOH C H O 88-89 Brodie A., 71, 156 iii., 869 29 59- SO 60 3 88 -5 Pieverling A., 183, 353 31, 587 Action of potash on myricin C 30 H 62 72 Brodie P. T., 1848 iii., 1069 Myricyl alcohol cjHfl.oH )> 85 Pieverling A., 183, 344 31, 586 ., H 85 Brodie A.,71,147;P.T. ; iii., 1069 1848 .... abt. 88 Maskelyne 22,87 vi., 391 Trinaphthylcarbinol (C 10 H 7 ) 3 .COH C,,H^O 278; sf. 180 Elbs B., 16, 1276 44, 1000 Benzoxydibenzylcymene C 6 H.OBz.Me.Pr.(CH.,Ph), C 31 H 30 O 2 .... 75-80 Mazzara G. I. [1881], 346 42, 173 and 433 ? Ci7H 16 O 6 ? C 31 H 30 9 .... 249 . J. p. [-2], 26, 70 Daphnin .... .... O TT O abt. 200 .... it., 304 From quassiin CnHaOj 237 Christensen B., 15, 2624 Kosin ... P TT O 142 J. [1874], 900 304 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. C al H 42 O 9 205 Christensen A. P. [3], 20, 481 ; 42, 1302 B., 15, 2624 Pyrochinovic acid C 31 H 48 O 4 a. 360 216 Liebermann &Giesel B., 16, 937 Convolvulinic acid .... C 31 H 52 17 .... 100-120 A., 51, 90; 83, 126 ; 95, 162 Palmitone . . (C 15 H 31 ),CO C 31 H 62 O 83-8 Krafft B., 15, 1714 42, 1272 \ 15^*11/2 84 Maskelyne 8, 11 iv., 335 Heraclin .... .... ... ti TT n O^JJ.^V'JQ 185 Gutzeit B. C. [1880], 377 G8, 914 C 16 H 9 (OH) 2 .O.C 16 H 9 (OH) 2 C 32 H 22 6 186-187 Breuer and Ziucko B., 13, 633 38, G66 ? .... ( ) a. 300 jj B., 13, 635 () Diresorcinphthalem .... C 32 HjjO 1( , d. 245 w. m. Link B., 13, 1654 40,96 Diresorcinphthalin C^H^OU 238 d. B., 13, 1655 M ? quinone .... C 32 H 26 3 180 Carnelley .... 37, 714 Dibenzoylpyroguaiacol BzO.0 12 H ]0 .O.C 6 H 6 .OH CajH^Oj 179 Wieser W. A. [1881J, 464 40, 813 Benzoinsuccinate (C M H u O a ) 2 -0 4 H 4 2 C 3 ,H 26 6 129 Lukanin A., 155, 92; B., vii., 1103 ; 25, 5,331 1094 Acetylethyldibenzoin CPh 2 OEt.CO.CO.CPh 2 OAc C 32 H 28 O S 145 Limpricht and B., 4, 337 24, 537 Schwaneit Dibenzoyl hydrocotone .... C 32 H 32 8 113 Jobst and Hesse A., 199, 53 38, 327 Glucoside from Cichorium C 3 2H 34 O 19 250-255 Nietzki A. P. [5], 4, 327 31, 477 jutybus - .... 215-220 d. M J. [1876], 852 Echitin C 32 H 5 ,O 2 170 A., 178, 66 Glucoside from Hedera helix 233 Vernet C. R, 92, 360 40, 440 Saponine (senegin) .... C 32 H 54 O 18 n. f. Blyth 33, 317 Cyclamin v. C l( H 34 O 10 236 Mutschler A., 185, 214 32, 904 Palmitic anhydride (C 15 H 31 .CO) 2 C 32 H 62 O a .... 53-8 Kekulu Lehrbuch 64 Villier B., 9, 1932 Jalapinol .... C 3i H 62 O 7 62-62-5 Mayer A., 95, 145 iii., 440 Cetylic palmitate (cetin) CnHu.COO.Cn H 33 C 32 H M 2 .... 49 i., 838 , ,, .... 53-5 A., 80, 297 Ethylic melissate C 29 H 59 .COOEt .... 73 Pieverling A, 183, 355 31, 587 Dicetyl oxide (C, 6 H 33 ) 2 C 32 H M O 300 55 Fi-idau A., 83, 22 i., 842 Metaphloretin C C 9 H S O j Q C 33 H 32 14 .... n.f. 150 Hlasiwetz A., 119, 212 iv., 492 Cholesterylic benzoate C 6 H 6 5 .COO(C 2 H J3 ) C^O., 125-130 Berthelot A. C. [3], 56, 61 i., 926 ,. ,, .... 150-151 Schulze J. p. [2], 7, 171 Paracholesterylic 127-128 Keinke & Eodewald A., 207, 234 42, 303 Isocholesterylic )J . . 190-191 Schulze J. p. [2], 7, 174 26, 1219 Dibenzfluorescem c 6 H 4 :(co.c 6 H 3 .OBz).,:o C 34 H 20 O 7 .... 215 E. Fischer B., 7, 1211 28, 159 .... 215 Baeyer A., 183, 14 31, 197 Di-j3-benzoxydinaphthyl ... BzO.C 10 H 6 .C 10 H 6 .OBz C 34 H 22 O 4 .... 160 Dianin B., 7, 125 vii., 842 a- 254 B., 7, 487 27, 8d2 Dibenzoyldibenzoxy benzene C 6 H 2 .(OBz) 2 .Bz 2 =1.3.?.? C 34 H 22 O 6 .... 151 Doebner and Stack- A., 210, 259 ; B., 36, 320 maun 11, 2272 = 1.4.?.? .... 146 Dcebiier and Wolff B., 12, 662 36, 638 Naphthylphenylpinacoue .... .... C 34 H 26 O 2 (?) 61 Richter R K. T., 454 From lapachic acid 140-141 Patern6 G. I., 12, 337 44, 21 > j C 6 H 4 (CH.OBz.Ph) 2 C 3 ,H, B O. 185-186 Wehnen B., 9, 311 Leucotin v. C 21 H 20 6 34^^26 4 97 A., 199, 40 Oxyleucotin .... v. C^H^Oj f~\ TT /"\ 133-5 A., 199, 48 Diacetylhexamethylquercetin CHO" 167-169 Herzig M. C., 5, 72 46, 847 Dibenzoxydicymene (C 6 Hj.MePr.OBz) 2 C b4 H 34 O 4 .... 215 .... J. R [1882], 130 Nataloin .... .... 2C 17 H 1S 7 .H 2 O P TT O C .H oa O,, 212-222 Fliickiger A. P. [2], 149, 11 vii. 5.3 ^34 38 ^ 15 io 28 11 H .... 180-190 25, 299 Tampicin C H- O 130 Z. C. [1870], 667 Jalapin OHO 150 Mayer A., 95, 129 iii., 439 Turpethin abt. 183 Spirgatis J. p., 92, 97 v Q9K Euosmite .... .... C 34 H 53 2 77 GUmbel J. [1864], 867 V.J ,'^>l vi., 609 From Satureja Juliana C 9 H 16 ? C 34 H 58 O 4 204-205 Spica G. I., 9, 285 38, 128 Jalapic acid .... .... .... v C H O - C H O C l abt. 120 Mayer & Spirgatis A., 95, 136 ; 116 m4"?7 301 ., T*<}/ COMPOUNDS CONTAINING THREE ELEMENTS. 305 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Cetylic stearate Dicetylacetic acid Geomyricin .... ^- / 'i7H 3 5.COO(C 16 H 33 ) CH(C 16 H 33 ) 2 .COOH C^H^O.; .... 55-60 69-70 u. c. 80-83 Berthelot Guthzeit Bruckner J. [1858], 419; A. C. [3], 56, 70 A., 206, 365 J. p., 57, 1 i., 842 ; v., 421 40,409 ii., 831 Acid from beeswax Tribenzanthrapurpurin Phenanthrene benzalquiu .... From orciuol C 14 H 5 2 -(OBz) 3 O.CHPh.[C I CH(C 6 H 4 ) 2 ]j C,,HoaAc 2 O B j QtfH.jdOj, C 35 H 24 O or CiaHmOa 91 183-185 325; 329-5 200 Schalfeieff Perkin Japp and Wilcock Wittenberg B. S. [2], 26, 450 J. [1873], 452 J. p. [21, 26, 71 31, 455 vii.,90;26, 431 37, 662 42, 1290 52 Jobat and Hesse A., 178, 49 29, 277 Elemic acid (C 5 H 8 ) 7 O 4 215 Buri P. J. T. [3], 8, 601 34, 440 From Satureja Juliana Dicetylmalonic acid Glycerol dipalmitate (dipal- mitin) Stearoue C(C 16 H 3 , 1 ) 2 (COOH) 2 C 3 H 5 (OH)(OC 16 H 31 0) 3 (C 17 H 35 ) 2 CO PMBaA OtftteaOft C 35 H 7U .... n.f. 250 86-87 u. c. 59 88-4 87'8 Spica Guthzeit Berthelot Krafft Heintz G. I., 9, 285 A., 206, 364 A. C. [3], 41, 240 B., 15, 1715 P. A., 94 or 96 38, 128 40, 409 iv., 335 48, 1272 v., 425 86 Bussy A., 9, 270 Isoamylic melissate Anamirtic acid Oxide of naphthobenzoic acid Cresolphthale'in dibenzoate Dithymolethane dibenzoate Quercitrin OogHjj.COOCsH,, 0(C 10 H 6 .CO.C 6 H 4 .COOH) 2 =(",/3; 1.2), C 6 H 4 (CO.C 6 H 3 .Me.OBz) 2 =(1.3.4 or 1.4.3) 2 see C,,;H,Oo C 3 dH 70 2 C 35 H 70 4 QtfHjoO, CsfiH^Oj QteHssO., C* TT O .... 69 68 146 195-196 190 160 Pieverling Francis Walder Fraude Steiner Zwenger & Dronke A., 183, 356 A., 42, 251 B., 16, 305 A., 202, 157 ; B., 12, 238 B., 11, 288 As., 1, 266 31, 587 1., 289 44, 666 36, 635 34, 507 v., 7 168 d Richter R K. T. Hexethylquercetin Picrotoxin .... C i4 H 10 Et 6 O n v. C,.,H,A>- QH 40 Ou C,JJ. .O . 120-122 u. c. 199 200 Herzig Paterno & Oglialoro M. C., 5, 72 B., 14, 539 46, 846 201 Barth & Kretschy B., 13, 1243 Helleborin a 250 d A., 135, 61 Betulinamaric anhydride .... Betulinic acid Betulin anhydride a-Storesin ...i C36H 49 O 14 C 36 H 34 6 Qj6H 56 O .... 181=185 c. 195=200 c. 243 160 168 Hausmann Miller A., 182, 375 >, A., 188, 208 31, 95 31, 96 31, 95 34, 160 /3- 140-145 A., 188, 209 Betulin abt 200 i., 583 251 Franchimont and B., 12, 7 36, 469 258 c Wigman A., 182, 368 31, 95 Phyllic acid Betuloretinic acid Gentianose .... QjeH M O 8 C 36 H 66 O 6 170 94 210 Bougarel Meyer B. S., 28, 148 J. P. [3], 26, 197 Z. P. C., 6, 135 32,905 44, 810 P TT 00 POP TT C H O 76'5 J. p. [2], 28, 219 46, 280 Dicetylic succinate .... ? Catecliin tetraanhydride dianhydride Tetra acetclirysarobin From lapachic acid From pichurim oil .... /3-Chinovin +5C. 2 H 6 Ethylene distearate Dibenzoyl eupittonic acid .... Glycerol dioleate (diolein) .... Glycerol diricinela'idate (ricinelaidin) i) (CH 2 .COOC 16 H 33 ) 2 cy^AcoAc), C 2 H 4 (O.C 18 H 35 0) 2 C-aHaBzjO, C 3 H 5 (OHXOC 18 H 33 0) 3 C,H,(OHXOC IB H S1 S ).. ) C 36 H 70 4 C 37 H 36 CfflHjsO,, C 3 sH 32 O 14 C 3 sH 34 Ou CsaHssOio C 38 H 58 O C'sgHesOn cja,f> 4 C 39 H 34 O n QisHjA C 39 H 7a 7 a. 360 v.C 40 H 36 12 260-265 58 n.f. 190 d. 210 w.m. 228-230 131-132 235 d. 70-80 76 232 s. 15 43 45 Tiittscheff Etti i) Liebermann and Seidler Paternd Mliller Liebermann and Giesel Wurtz Hofmann Berthelot Playfair Bouis E.,2,463;J.,13,406 J. p. [2J 4, 448 A., 186, 327 i, B., 11, 1608 ; A., 212, 34 G. I., 12, 337 J. p., 58, 463 B., 16, 930 A. C. [3], 55, 436 ; J., 12, 486 B., 12, 2219 A. C. [3], 41, 250 A., 60, 322 A. C. [3], 44, 82 v., 463 32, 490 36, 327; 42, 858 44,211 iv., 637 il.,582; v., 420 38, 165 iv., 195 v., 109 9 u 306 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Glycerol diricinela'idate (ricinela'idin) Glyceroltrilaurate (lauro- stearin) j> Glycerol distearate (distearin) From canaiiba wax .... Oil from nutmeg .... ' Tri-a-naplitholpyromellitic acid Benzeneresorcinpbthale'in anhydride Einodin C 3 H 6 (OH)(OC 18 H 33 2 ) 2 C 3 H 5 (O.C 12 H 23 0) 3 C 3 H 5 (OH)(O.C 13 H 35 0) 2 C 39 H 72 7 C 39 H 74 O 6 C 3 9H 76 O 5 C 39 H S A C 40 H 16 QoHiA CjoHae ? n n H, n O,,('!') 212-218 62-66 s. 44-45 44-48 58 105 Liquid 245 285 a. 250 Boudet Reichardt ) Berthelot Maskelyne Wright Grabowski Pechmann Warren De la Rue A., 4, 16 A. P. [3], 10, 339 > A. C. [3], 41, 226 22, 87 26, 549 B., 6, 1068 B., 14, 1862 10 304 v., 109 32, 518 j v., 422 vi., 391 vii., 862 42, 184 ii , 485 Octacetyl-quercetin .... Pent-acetcbrysarobin Corallin C 24 H 8 Ac 8 11 C 30 H 21 Ac 5 7 of. C^H-.O, C 4<>H32O,9 C4oH 36 O, 2 v. C 38 H 34 U 189-191 228-230 80 and Miiller Herzig Liebermann Kolbe and Schmidt M. C., 5, 72 A., 212, 33 J p [2] 5 184 46, 847 42, 858 25, 705' vii 391 .... 150 154-155 Fresenius Erhardt J. p. [2], 3, 477 A P [3] 8 481 vii., 118 34, 316 156 Fresenius J p T2l 5 184 25,705' vii. 391 Catechin, from Gambir i * From opiauic acid Eetinic acid .... v. C^H^A, C^HsiAe C^oHssOia c, n H c o .... 163 176-177 204-205 a. 200 120 pd Gautier C. R., 86, 668 > As., 7, 65 34, 516 i v. 98 Unodeca-acet-triglucose Action of P 2 O 6 on galbanum oil Resin C I8 H 21 6 (OAc) n C-ioH^O,.., C 40 H 58 252 212 a 120 Franchimont Missmer C. R., 89, 711 A., 119, 257 38, 159 ii., 759 vii 1040 Absinthin 2C,,,H,,O,.H,O 120 125 Kromayer A P [2] 108 129 vi., 2 From sandal wood Unripe amber (resin) Retinite (Walchovite) From sandal wood From orange peel Betulin diacetate Resin C 4oH 60 O 2 QoHssO C 4oH 62 O 3 C 40 H 64 5 n n A H C O a. 350 340 240-250 a. 300 250 Liquid 223 c. ; 277 75 90 Chapoteant Spirgatis Schrotter Chapoteant Wright and Peisse Hausmann B. S., 37, 303 N. R. P., 20, 321 P. A., 59, 61 B. S., 37, 303 24, 1186 A., 182, 372 44,76 vii., 1039 v., 98 44,76 vii., 877 31,95 vii 1 040 Lactucerin C-BLjO. C.JI^O ? 175 P J T [3] 10 44 36 1041 Lactucone v C^H^O (-?) 150-160 A 59 83 iii 465 Parillin OHO 210 P.T T m S 4-fiS 34 097 Acetone on benzaldehyde .... Acid from cholic acid Resin from Larch agaric Acetyldistearylglycerol Catechin cf. C 17 H 14 C 3 H 5 (OSt) 2 .(OAc) CjiH 34 O 3 C 4 iH 53 O 22 (C 41 H 77 O s ) n C 41 H 7S 6 OHO .... 110 196-198 125 28-30 IfiAlfje; Schmidt Tappeiner Masing H undeshagen B., 14, 1461 Z. B., 12, 60 A. P. [3], 6, 111 J. p. [2], 28, 219 Bs in ^KR 40, 889 31, 213 29, 612 46, 280 v 42- n 34 v -'l6 C H O 188 190 B S 28 146 /3- v '42 J - L 36 l -'l6 C n H M 176 177 B S 30 567 Amarinic acid 2H 2 O H 2 O Octacetyl-? C, c H0-(OAc) u (C 42 H 37 4i ) 2 C 42 H 40 O 6 C H O 155 140 110 111 Zinin Z. C. [2], 7, 127 ji B 15 1923 24, 540 44 77 4ft J.1Q Hexacetylcoriamyrtin Octacetylhelicoidin Echitein (dextrorotary) Cocinin C 42 H 48 0, 6 C42H 50 O 22 C 42 H 70 O 2 C n H O b. 100 80 195 33-5 Jobst and Hesse Duffy A. C. J., 5, 171 Z. C. [1866], 665 A., 154, 29 A., 178, 49 J 5 511 29, 277 Glyceroldiarachate(diarachinJ Cerylic palrnitate Diacetylphenylresorcino- plithale'in anhydride Dicotoin C 3 H 6 (OH)(OC 20 H 39 0) 2 C 15 H 31 .COO(C 27 H S5 ) C 43 H 84 O 5 C 4 3H 86 O 2 C44H 3U O 9 C H O .... 75 79 245 74-77 Berthelot Hesse Pechmann A. C. [3], 47, 358 B., 3, 639 B., 14, 1863 A 199 29 vii., 277 42, 184 38 326 Picrotoxiniu benzoic anhy- dride Ditliymylquinhydronetheue (C 15 H 16 6 ) 2 .Bz 2 [C 10 H 12 O.C(C 10 H 12 .OH):CH 2 1 C 4 4H 4 A 5 044354^4 237-238 214-215 Schmidt Jager A., 222, 313 B., 7, 1199 46, 845 31, 263 COMPOUNDS CONTAINING THKEE ELEMENTS. 307 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. C 44 H 64 O 6 129-144 Maly A., 129, 94 vii., 378 44^^64 5 135 Fliickiger J. [1867], 727 33, 265 139 Emmerling B., 12, 1442 .... 150 Sievert J. [1859], 508 " .... J) 165 Maly A., 132, 249 165 Kelbe B., 13, 888 38, 670 Anacardic acid v. C M H 3 A C 44 H C4 7 26 Stadeler A., 63, 137 i., 209 Action of HC1 on betulin- .... C 44 H 64 O 14 .... 119 c. Hausmann A., 182, 368 31, 96 amaric acid Hydrabietic acid C 44 H 68 O 5 140-145 .... Z. C. [1866], 34 .... C 44 H 68 5 160 Maly A., 129 and 132 vii., 378 Ethylic betulinamarate .... C 44 H 68 O 14 117 Hausmann A., 182, 378 Cholesterylic stearate .... C 44 H 7 A 65 Berthelot A. C. [3], 56, 57 Isocholesterylic stearate 72 Schulze J. p. [21 7, 174 26, 1220 Fluoranthene + fluoranthene C 15 H 8 2 +2C I6 H 10 C 45 H 28 Oj 102 Fittig & Liepmann A., 200, 4 38, 401 quinone ? ketone .... C 45 H 66 O a. 360 .... A., 202, 329 Dammarylic acid .... C 45 H 72 O 3 60 J. [1847-48], 741 +H 2 .... .... 56 Icacin . .... .... C 47 H 78 O ? C H. C H O ? 175 Stenhouse & Groves A., 180, 256 30, 425 Glyeeroltrimyristate C 3 H S (O.C 14 H 27 0) 3 C 4 5 5 H 8 A .... 31 Playfair P. M. [31 18, 103 m., 1072 (myristin) n .... M .... 31 Reichardt A. P. [31 10, 339 32, 518 .... .... 46 is .... 55 Masino G. I., 10, 72 38,460 Amaric anhydride C 46 H 38 O 4 .... 140-5 Zinin B., 10, 1735 34, 152 Amaric acid .. . .... C 46 H 42 O, 140;a.f. 155 Z. C. [2], 7, 538 vii., 55 Icacin .. . C 4 -H- 8 O ? C H. O C 4i H 74 O ? 175 Stenhouse & Groves A., 180, 256 30, 425 Myricylic palmitate(myricin) Jj jo c-a-o, 71-5-72 Brodie A., 71,244 Ui., 1069 Gallem tetrabenzoate C 6 H 4 .COO.C : [C 6 H 2 (OBz) 2 ] 2 : .... 231 Buchka A., 209, 264 42,61 Hexbenzodulcite C 6 H s (OBz) 6 CwH^O,, .... 147 Bouchardat A. C. [4], 27, 68 ; vii., 442; 85, B. S.[2],18, 115 1093 Ononetin .... C 4S H 44 O 13 .... 120 Hlasiwetz J. p., 65, 142 iv., 202 Myroxocarpiu .... C 4S H 70 O 6 115 Stenhouse A., 78, 306 iii., 1075 Theveresin C 48 H 70 O, 7 140 J. [1868], 769 Tetrethylcholanic acid C 40 H 62 Et 4 O 12 C 48 H 72 O 12 130-131 Latschinoff B., 13, 1056 38, 723 Pyromellithin -tetra-a-naph- C M H 26 6 a. 360 Grabowski B., 6, 1066 tholanhydride y-Pyromellitein-tetra-a-naph- .... CjoHssOj .... 265 B., 6, 1067 vii., 840; 27,65 thol hemianhydride P~ > i> .... .... a. 360 "~ 5> *> .... a. 360 i H .... C 60 H 42 O 3 a. 100 Bruckner J. p., 57, 1 il., 830 Isobutylamaric anhydride .... .... C 50 H 46 4 137 Zinin B., 10, 1737 34, 153 acid .... C 50 H 50 O 6 175-179 u Tarconyl alcohol QiHiojO ? C 60 H 10 ,O C 52 H 106 ? 82 ; a. f. 72 Canzoneriaud Spica G. I. [1882], 227 42, 1040 Glycerol tripalmitate (tri- C 3 H 5 (O.C 16 H 31 0)^ C 61 H 98 6 .... 60 Berthelot J., 6, 453 iv., 335 palniitiu) 61 ; s. 46 Eeichardt A. P. [3], 10, 339 32, 518 !> a jj 1st modifi- 46 Duffy J., 5, 519 cation n 2nd 61-7 j> i> 3rd 62-8 u ,. Tarconyl alcohol See C M H 102 C 51 H 104 0; C 52 H 106 .... C 53 H 76 8 125 Maly Z. C. [1866], 33 vii., 379 Oerotinoiie .... C 63 H 106 O .... 62 Bruckner T. p., 57, 17 Thevetin .... .... C 64 H S4 24 170 .... J. [1868], 768 Cerylic cerotate C 26 H 53 .COO(C 27 H 55 ) C 64 H 108 O 2 82-5 Hesse B., 3, 638 vii., 277 .... 82 Brodie A., 67, 213 i., 837 Geoceriuoue C 55 H 110 > 50 Bruckner J. p., 57, 1 ii., 831 2 R 2 308 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Oetoruetoxybenzoid ... ^H^OI? .... 160-165 Schiff B., 15, 2588 44, 335 Cumenyl crotonic acid + i s ~ 4(C 13 H 16 2 )+C 4 H 8 S C 5 6H 72 O 10 .... 80 Perkin .... 35, 137 butyric acid Glycerol trioleate (triolei'n) C 3 H 5 (O.C 13 H 33 0) 3 C 5 7H 104 O 6 s. 9-10 Eeichardt A. P. [3], 10, 339 32, 518 )i J) 100 .... .... iv., 195 triela'idate (tri- H .... 32 Mayer A., 35, 178 ii., 368 ela'idin) ?> 38 .... J. [1852], 511 tristearate (tri- C 3 H 5 (O.C 18 H 35 0) 3 C57H U oO 6 .... s. 44 Chevreul .... v., 423 stearin) 1 i> .... 50 Thoulet C. R, 94, 1047 42,790 V )J u a. 60 Deite D. P., 231, 168 36, 569 JT ) j s. 61 Braconnot A. C. [3], 41, 228 v., 423 >> )) 11 ji s. 60-62 Liebig and Pelouze A., 19, 264 1J il 1* Tl s.62 Lecanu A., 12, 25 )! 1' ! ) *) ij s. 62 Heintz .... > )> V 1 i) .... 62 Reichardt A. P. [3], 10, 339 32, 518 > > J> 11 M 1st modifi- 60 Kopp A., 93, 194 cation i? T t j) 52 Duffy .... 5, 197, 303 n 1) 65; 65-5; 69-7 * J., 5, 510 v., 423 )1 it 2nd 64-2 ; 69-7 j) 6, 197, 303 V ) i ) 3rd 69-7; ! .... H s. 50-5-51-7 J )J i ) 4th Liquid )J J., 5, 510 Onospin OgijHggO^ 162 Hlasiwetz W. A., 15, 142 iv., 203 Copaivaol hydrate 3C 20 H 32 .H 2 CeoH^O 252-260 .... Brix M. G, 2, 537 42,65 Mellisyl mellisate C 3 oH 59 .COO.C 30 H 61 C 6 oH 120 Oj .... 63 Kissling B., 16, 2432 46, 173 Ononin v. C 30 H 34 O 13 C 6 2H 68 O 27 .... 235 Hlasiwetz W. A., 15, 142 iv., 203 Theobromic acid .... C64HmO 2 72-2 Kingzett B., 10, 2243 From dioxyretistene C 30 H 28 (OAc) 2 .C 3 H 23 (OAc).OH C 6 6H 66 O 7 .... 70 Ekstrand B., 17, 694 46, 1041 Jalapic acid .... .... v. C. t .H sn O, s * ( ( s I I 1 1 gvjjj 120 Mayer & Spirgatis A., 95,136; 116, iii., 437 34^^oU 18 301 G7oH 56 4 225 Zinin Z. C. [2], 7, 127 24, 540 ; vii., 129 C H O 246 Papouslk J., 5, 624 Composition unknown C,H y O, 145-7 Fleury J. p. [4], 10, 202 vii., 30 Agaricin .... (alcohol ?) 11 272 Jahna A. P. [3], 21, 260 46, 354 Autherosperma nyxhatum, )) 224 .... Gladstone 25, 12 oil of Apiol, action of KHO on .... 65-4 %C; 5-5 %H ) 53-5 Gerichten B., 9, 1478 31, 326 60-48 %C; 7'4 %H 120 Eijkmann B., 16, 86, 430 44, 215, 349 Atractyligenin Composition unknown 11 .... a. 100 Lefranc C. R., 67 or 76 vii., 117 Beechblight (wax) i |J .... 78-80 Konig L. V. S., 16, 198 26, 1156 .... (alcohol) >' 49-51-5 )1 (acid) > 1 .... 51-5 J? Capnomor i V 185 Reichenbach J. F. P., 1, 6 Ceratophyllin )> 11 147 Hesse A., 119,365 iv., 635 Citraconic acid, from n 232 Prehn B., 8, 20 28, (i32 Columbo root, from j i .... 218-220 Paterno & Oglialoro G. L, 9, 64 ; B., 36, 730 12, 685 Dehydromucic acid, from .... i abt. 140 Fittig B., 9, 1199 31, 65 209 u. c. 165 Tauret J Ph., 26, 320 34, 81 Eucalyptus globulus, from .... 77 %C; 11 %H > acid? 245-247 Hurtzer B., 9, 315 29, 942 Composition unknown 204-204-5 ; Paternu G. I. [1882], 231 42, 1083 200 Guaiaretic acid, from j i' .... 183-185 Herzig M. C., 3, 822 44, 470 Hay, from meadow 73-27 % C ; 12-41 % H j^ 20 Konig and Kiesow L. V. S., 17, 1 27, 597 81-43% C; 13-71 %H ,, 73-74 Konig & Aroiiheim M Lign aloes, oil of Composition unknown i) 200 Gladstone 25, 12 COMPOUNDS CONTAINING THREE ELEMENTS. 309 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Maltodextrin, acetyl deriv Meteceric acid Omphalocarpum procera, from Oxyquiuhydrone of C 16 H 12 .... Composition unknown >! )! H C,H y 2 n acid 98 105-110 32 154-155 160 Herzfeld Arata Naylor Breuer and Zinck6 Quinck6 B., 13, 267 G. I., 7, 366 P. J. [3], 12, 478 B., 11, 1997 PA ns 141 38, 620 34, 325 42, 308 36, 327 vi i ' i'> Pliycic acid .... 150 d. 136 Lam v J 5 675 Pedophylloquercetin Quercite, acid from ,, Quinetum 59-37 % C ; 4'01 % H Composition unknown j i 247-250 102 no 139 Podwissotsky Prunier Blvth B., 15, 378 C. R., 84, 184 42,977 31, 450 > 00 01 "T Quinone-like substance Eosaniline, from acetate of above Rose oil 73 %C; 6-4"% H 68-25% C; 5-21 %H Composition unknown i> 216 66 200 156 Ador and Meyer Liebermann j> A., 159, 1 B., 6, 952 B., 6, 953 24, 826 26, 1242 H QK I Turmeric oil .... 280-290 Gaiewsky B 5 1103 2 ft fSfU Wormseed oil Xylite 75-5 %C; 11-75 %H Composition unknown * 173-174 61 - 5 .... Faustand Homeyer Weidmaun and B., 7, 1427 A 36 305 28, 371 )i Yew tree, from i 61-62 86-87 Schweitzer Volckel Amato &Capparello J., 4, 499 G. I., 10, 349 38,900 6. CHS. Methylene sulphide cf. C 3 H 6 S 3 CH 2 S a. 200 Husemann A., 126, 294 iii., 1007 Methyl sulphhydrate Me.SH CH 4 S 21 Gregory A., 15, 239 iii., 992 Hydrogen carbosesqui- .... CjE^j 100 Loew Z. C. [2], 1, 723 vi., 410 sulphide Ethylidene sulphide CH 3 .CHS C 2 H 4 S 205 95 Crafts J. [1862], 431 vi., 608 Ethylene sulphide .... CH 2 .S.CH 2 200 112 A., 124, 110 ii., 583 disulphide CH 2 .S.S.CH 2 C 2 H 4 S 3 .... b. 100 Lowig & Weidmann P. A., 46, 84 ,, pentasulphide C 2 H 4 S 5 (?) .... b. 100 )( Methyl sulphide (CH 3 ) 2 S C 2 H 6 S 41 Regnault A. C. [2], 71, 391 iii., 991 37-1-37-5 .... J. p. [2], 17, 453 Ethyl sulphhydrate (mercap- Et.SH 62 .... Bunsen .... ii., 547 tane) ' )? > 61-63 Zeise P. A., 31, 389 36-2 .... Liebig A., 11, 17 ?> >) 36-2 36-8 .... Nasini B., 15, 2881 Ethylene disulphhydrate .... HS.CH 2 .CH 2 .SH C 2 H 6 S 2 146 .... Werner J., 15, 424 Methyl disulphide Me.S.S.Me 116-118 .... Cahours A. C. [3], 18, 157 iii., 991 ,, 112-1 .... Pierre C. R., 27, 213 Ethylenic trisulphocarbonate i 2 * i CHS 39-5 Husemann A., 123, 83 v., 502 Allyl sulphhydrate CH 2 ; CH.CH 2 .SH C^HeS 3 90 Hofmann & Cahours A., 102, 292 i., 145 Thiacetone See CHS Dimethylic trithiocarbonate MeS.CS.SMe C 3 H 6 S 3 200-205 .... Cahours A. C. [3], 19, 163 v., 501 !> 1, 204-205 .... B. J., 27, 548 Trimethylene sulphide .... .... a. 200 Husemaun A., 126, 294 iii., 1007 .... 216 Hofmann B., 2, 155 .... sb. 212 2J.6 B., 3, 588 ,. V .... MM 217 Renouf B., 13, 2174 Propylsulphhydrate CH 3 .CH 2 .CH 2 .SH C 3 H 8 S 67-68 .... Roemer B., 6, 784 26, 1118 ; vii., 1014 Isopropyl sulphhydrate (CH 3 ) 2 .CH.SH abt. 45 .... Henry B., 2, 496 vi., 966 n 57-60 .... Claus and Keerl B., 5, 660 vii., 1016 ; 26, 998 Methylethyl sulphide Me.S.Et 58-8-59-5 .... Carius A., 119, 315 ii.,549;vi.,598 (757) )1 65-66 .... Kriiger J. p. [2], 14, 206 31, 187 310 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylethyl sulphide Me.S.Et C 3 H S S 64 .... Clwsson J. p. [3], 15, 174 32, 293 Thiophene CH:CH.S.CH:CH C 4 H 4 S 84 c. Liquid Meyer B., 16, 1471 44, 1091 i i Diethylene disulphide C 4 H 8 S 2 199-200 111-112 Husemann A., 126, 280 vi., 606 Butyl sulphhydrate CH 3 .CH a .CH 2 .CH 2 .SH C 4 H 10 S 97-98 Liquid Grabowsky and A., 171, 251 27, 565 Saytzeff Isobutyl sulphhydrate MejCH.CHj.SH 88 .... Hermann A., 95, 256 v., 736 86-6-87-8 .... Nasini B., 15, 2882 (754) Butyl sulphhydrate CH 3 .CHj.CH(SH).CH g 84-85 Liquid Eeymann B., 7, 1287 28, 141 Ethyl sulphide Et 2 S 73 .... Eegnault A. C. [2], 71, 387 il., 545 ,, ,, _ 81 .... Smith ,j .... _ 91 .... Gaube J. [1867], 542 vi., 598 91 .... Pierre C. E., 27, 213 .... 91-9 (755) .... Beckmann J. p. [2], 17, 451 92-2-93 (754 .... Nasini B., 15, 2882 disulphide .... . m Et.S.S.Et C 4 H 10 S 2 150-151 Otto B., 13, 1289 151 .... Morin P. A., 48, 484 il., 546 .... 151 .... Eamsay .... 28, 688 ... 152-8-153-4 Nasini B., 15, 2882 (759) Dimeththioethane (ethylene MeS.CH 2 .CH 2 .SMe 183 .... Ewerloff B., 4, 716 24, 1189; vii., dithiomethylate) 491 Fusyl disulphide C 10 H 18 S 2 1 C 6 H 9 S (?) 112 1. 18 Guthrie 12, 125 ii., 755 Amylene sulphide C 6 H 10 S 130-150 Liquid Grabowsky A., 138, 169 vi., 1135 .... abt. 200 .... Guthrie A., 121, 115 14,136; vi., 121 Thioisovaleric aldehyde CHMe 2 .CH 2 .CHS C S H 10 S 114-115 Liquid Barbaglia B., 13, 1574 40,34 ,, >. polymer ? .... 69 Schroeder B., 4, 403 24, 560 ; vii., 1195 Diethylie trithiocarbonate .... EtS.CS.SEt C 6 H 10 S 3 240 Husemann J. [1861], 344 v., 501 237-240 Schweitzer J. p., 32, 254 > 237-240 Debus A., 75, 147 240 Salomon J. p. [2], 6, 433 26, 62C Isoamyl sulphhydrate CHMe 2 .CH 2 .CH 2 .SH C 5 H ia S abt. 120 Kreutzsch J. p., 31, 1 i., 205 ., n 125 .... Balard A. C. [3], 12, 305 i> 117 Krutsch J. P., 31, 2 ., 119-8 Kopp A., 95, 346 116-6-118 Nasini B., 15, 2883 (763) Dieththiomethane EtS.CH 2 .SEt C 5 H 12 S 2 184 Claessou J. p. [2], 15, 176 32, 29.3 Phenylene sulphide c 6 H 4 : s" C 6 H 4 S 159 Stenhouse P. E. S., 17, 62 vi., 922 Phenyl sulphhydrate (thio- C 6 H 5 .SH C 6 H 6 S abt. 165 .... Vogt A., 119, 142 iv., 418 phenol) > !> 168-5 Schmidt B., 11, 1174 34, 975 ), 172-5 Liquid Stenhouse P. E. S., 17, 62 ; vi., 919 A., 149, 258 ,, 170-173 Liquid Otto A., 143, 211 ., ,, 170-173 .... Friedel and Crafts C. E., 26, 884 34, 670 Dithioresorciuol C 6 H 4 (SH) 2 =1.3 C 6 H 6 S2 245 27-1 Korner and Mou- G. I., 6, 133; 31, 81 selise J. [1876], 450 i) 243 27 Pazschke J. p. [2], 2, 418 vii., 1156 .... 27 Gabriel B., 10, 184 32, 325 Dithioquinol = 1.4 .... 98 Korner and Mou- G. I., 6, 133; 31, 81 selise B., 9, 584 Allyl sulphide (CH S :CH.CH 2 ) 2 S C 6 H 10 S 140 .... Wertheim A., 51, 295 ; 55, i., 144 297 140 .... Tollens B. S. [2], 11, 397 vi., 91 trisulphide /riTj riTT OTT ^ Q l^V^-tin V>.I1. vy-dj^n^g C 6 H 10 S 3 188 Lowig J., 13, 399 i., 536 Duplothiacetone C 6 H 12 S 2 183=185 c. Liquid Wisliscenus Z. C. [2], 5, 324 vi., 1047 .... 183-185 .... Spring B. S., 40, 66 46, 580 .... 180-185 MM B., 14, 760 .... ,, 165-170 Glaus B., 8, 532 28, 881 COMPOUNDS CONTAINING THREE ELEMENTS. 311 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Trithioacetic aldehyde (a) ... .... QiH,jS, 246-247 101 Klinger B., 11, 1024 34, 720 )) 11 It 11 249 102 B., S.. 38, 129 (3) -. i S45-248 124-125 Klinger B., 11, 1024 34, 720 ,. )- )> .... 11 125-126 B., 9, 1894 32, 305 ,, t! 145-150 (?) 123-124 ! R, 9, 1894 11 Hexylsulphhydrate CH 3 .(CH 2 ) 4 .CH,,SH C 6 H 14 S 145-148 Pelouze & Cahours C. B., 10, 1241 ; iii., 153 A., 124, 291 Secondary JJ 142 c. .... Wanklyn and J., 17, 509 ; A., ill., 154 Erlenmeyer 135, 150 _Propyl sulphide Pr" 2 S It 130-135 Liquid Cahours C. E., 76, 133 26, 365 Isopropyl sulphide Pr3 2 S >1 120-5 .... J. p. [2], 17, 459 11 >! U )J 105 Henry B. [1869], 496 vi., 966 Propyldisulphide Pr.S.S.Pr C 6 H 14 S 2 192-5 Spring and Legros B., 15, 1940 Isopropyldisulphide Pr/s.S.S.Pr^ 174-5 11 11 H Dieththiomethane EtS.CH 2 .CH 2 .SEt j 210-213 .... Ewerlof B., 4, 717 24, 1189 ; vii., 491 y-Thiobenzoic aldehyde = CuHnS 2 ? C 7 H 6 S 64 Cahours A. C. [3], 23, 129 i., 577 ; vi., A., 70, 40 329 7- ,< .. cf. B. 15, 861 )J 68-70 Fleischer A., 140, 234 vi., 329 y- >. >! ) 69-70 Klinger B., 15, 862 y- 11 1) .... 70-71 Bottinger B., 12, 1054 a- d. 80-85 80-95 Klinger B., 15, 861 a- .... ) d. 90-95 78-80 Fleischer A., 140, 234 a- .... l d. 83-85 Klinger B., 9, 1895 a- .... *J .... 90-95 Laurent A. C. [3], 1, 291 i., 571 ft- ( ). .... 224 Bottinger B., 12, 1057 ft- .... 11 .... 225-226 Klinger B., 9, 1896 32, 306 ft- .... )) 225-226 11 B., 10, 1877 ; 15 34, 132 864 Benzyl sulphhydrate C 6 H-.CH 2 .SH C 7 H 8 S 194-195 Miircker A., 136, 75 v., 858 Tolylsulphhydrate(thiocresol) C 6 H 4 .CH 3 .SH = 1.3 (?) n 187-188 b. 10 Hiibner & Wallach Z. C. [2], 5, 500 ii " ) J v 188 abt. 2 ! 11 5) vi., 291 11 C 6 H 4 .CH 3 .SH = 1.2 > 188 15 A., 169, 30 J) " = 1.4 188 43 Marcker A., 136, 79 ) Tolyldisulphhydrate (thio- C 6 H 3 Me(SH) 2 = 1 C 7 H 8 S 2 .... 34-5-35 Gabriel B., 12, 1640 orcinol) Triallylic trithiocarbonate .... (CH 2 1 CH.CH 2 .) 2 CS 3 C 7 H 10 S 3 170-175 .... Husemann A., 126, 297 v., 496 Heptyl sulphhydrate C 7 H 15 .SH C 7 H 16 S 155-158 Schorlemmer 16, 216 iii., 147 Amylethyl sulphide GjHn-S.C,,!!- 132-133-5 c. Liquid Carius A., 119, 315 ii., 548 ; vi., (758) 123, 599 ; 32, 293 11 n 130-140 .... Linnemann .... vi., 123 11 158-159 .... Saytzeff Z. C. [2]), 6, 105 ; vi., 123, 599 A., 139, 361 Triethylic trithiorthoformate CH(SEt) 3 C-H 16 S 3 200-240 d. Liquid Gabriel B., 10, 186 Thioacetophenone .... C 6 H 5 .CS.CH 3 C 8 H H S 119-5 Sngler B., 11, 931 36,61 Xylene sulphhydrate (thioxyl- C 6 H 3 .Me 2 .SH CsHioS 213 .... Scheffer Z. C. [1865], 360 v., 1059 enol) Phenyl ethyl sulphide C 6 H 5 .S.C 2 .H 5 11 204 (743-5) Liquid Seckmann J. p. [2], 17, 457 36, 37 Butyl sulphide (CH 3 .CH 2 .CH 2 .CH 2 ) 2 S C S H 18 S 182 Liquid Grabowsky and A., 171, 253 27, 565 Saytzeff Isobutyl sulphide (CHMe 2 .CH 2 ).,S 11 172-173 Liquid 11 A., 171, 256 1) 11 170-5 .... J. p. [2], 17, 445 Butyl sulphide (CHMeEt) 2 S 11 165 taymaim B., 7, 1288 28, 141 11 11 11 176-185 .... Saytzeff J., 19, 528 Isabutyl disulphide (CHMe,.CH.,) 2 S 2 C 8 H, 8 S 2 220 Spring and Legros B., 15, 1940 Dithienyl methane CH 2 (C 4 H 3 S), " ^1 TT O ^yll^.. 267 43 J eter B., 17, 1345 6, 1001 Mesitylene sulphhydrate Me x SH = 1.3.5.6 C 9 H 1;! S 228-229 .... Holtmeyer Z. C. [1867], 688 vi., 301 (thiomesitol) Pseudocumeue sulphhydrate = 1.2.4.5 .... 85 Radloff B., 11, 32 34, 414 312 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Gh. Soc. Pseudocumene sulphhydrate Me 3 .SH=1.2.4.5 (?) C 9 H 12 S abt. 235 86-87 Beilstein & Kogler A., 137, 322 vi., 298, 515 Benzyl ethyl sulphide C 6 H 5 .CH 2 .S.Et. jj 214-216 Liquid Marcker A., 140, 88 vi., 336, 599 Tolylethyl sulphide C 6 H 4 .Me.SEt = 1.4 j 220-221 Liquid Otto B., 13, 1277 38, 811 Di-isobutylic trithiocarbonate (CHMe 2 .CH 2 ). 2 CS 3 C 9 H 18 S 3 285-289 Mylius B., 6, 315 26, 873 Thio-a-naphthol C 10 Hj.SH. C 10 H 8 S 285 Liquid Schertel A., 132, 91 v., 1093 ii .... Liquid Liebermann A., 183, 225 31, 608 Thio-j3-naphthol 11 M 75 Billeter B., 8, 463 11 11 = C 20 H 14 S 2 I .... 136 Maikopar Z. C. [1869], 710 j .... 137 Liebermann A., 183, 225 31, 608 Cymene sulphhydrate (thio- Pr-.Me.SH. = 1.4.5 CioS^S 235-236 Liquid Eaderburg B., 6, 669 vii., 421 carvacrol) 11 11 11 1) 235-236 Liquid Flesch B., 6, 479 26, 1029 11 1* I/ )> ) It) 233-235 Liquid Fittica B., 6, 935 26, 1227 11 11 11 J )> J) 235 .... Wright .... 27, 2 ,, .... .... > i) 233-240 .... Wright .... 27, 321 ,, ,, )> 233 .... Bechler J. p. [2], 8, 168 27, 472 ,, (thiothymol) = 1.4.6 J 230-231 1. 20 Fittica A., 172, 303 28, 59, 60 Fusyl disulphide .... C 10 H 13 S 2 (?) 112 1. 18 Guthrie A., 113, 287 12, 125; ii., 755 Tetraeththioethylene C 2 .(SEt) 4 CloH2oS 4 54 Claesson J. p. [2], 15, 213 32, 296 Isoamyl sulphide CsHn.S.CjH,, C^HjjS 216 .... Balard A. C. [3], 12, 248 i., 205 11 11 11 214-2-215 .... Nasini B., 15, 2883 n (754) diaulphide CsH u .S.S.C 5 H|, CmHjjSj 240-260 .... Henry A. 0. [3], 25, 249 11 11 11 250 .... Spring and Legros B., 15, 1940 Phenylthienylmethane CH 2 Ph(C 4 H i S) C|]Hi S 265 c. Liquid Peter B., 17, 1346 46, 1002 Meththiocymene C 6 H,.Pr.Me.SMe CnH 16 S 244 .... Bechler J. p. [2], 8, 167 27, 473 Diisoarnylic trithiocarbonate (C^Hn^CS., CnH^Sj 245-248 Hiiseniann A., 126, 297 v., 497 Diphenylene sulphide C 6 H 4 .S.C 6 H 4 C 12 H 8 S .... 94 Stenhouse A., 156, 333 1 1 11 ii H 11 332-333 o. 97 Grcebe B., 7, 51, 1630 ; 27, 469 ; A., 174, 185 28, 275, 455 disulphide C 6 H 4 .S.S.C 6 H 4 ! 1 C 12 H 3 S 2 abt. 360 153 11 B., 7, 52 27, 469 ii 11 abt. 360 154-155 11 A., 179, 178 29, 578 ii ii j ii 156-157 Schmidt B., 11, 1174 34, 975 Phenyl sulphide C 6 H 5 .S.C 6 H 5 C 12 H 10 S 288 .... Friedel and Crafts C. E., 86, 884 34, 670 ii ii i 11 290 .... Krafft B., 7, 385 11 ii n 11 291 .... Graebe and Mann B., 15, 1683 42, 12S5 11 ii 11 292-5 .... Stenhouse P. E. S., 14, 351 iv., 417 ,l .... 11 292-5 .... Grsebe A., 174, 185 28, 454 II v 11 293 Schmidt B., 11, 1174 34, 975 Diphenyl sulphhydrate C 6 H 5 .C 6 H 4 . SH 11 .... 110-111 Gabriel and Deutsch B., 13, 386 38, 476 Phenyl disulphide C 6 H..S.S.C 6 H 5 C 12 H 10 S 2 .... 59-60 Otto B., 15, 129 ii ii ? 11 .... 60 Vogt A., 119, 142 iv., 418 ji ii t 11 .... 60 Dreher and Otto A., 154, 178 vii., 942 ii ii i i 60-61 Schmidt B., 11, 1174 34, 975 ii 11 n 11 ... 61 Stenhouse P. E. S., 17, 62 vi., 919 11 11 ) 11 61 Gabriel B., 10, 185 32, 311 11 11 *i 11 310 Bichter E. K. T. Diphenyl disulphhydrate .... C 13 H g (SH) 2 11 .... 176 Gabriel and Deutsch B., 13, 390 38, 477 Hexylene sulphide .... .... C 12 H 22 S 168-170 Destrem B., 16, 229 Hexyl (a) .... C 6 H J3 .S.C 6 Hi 3 C I2 H 26 S 230 .... Pelouze & Cahours A., 124, 291 ; iii., 153 C. E., 10, 1241 Diamthioethane ;. (C 6 H U )S.CH 2 .CH 2 .S(C 5 H H ) Ci 2 H 26 S 2 245-255 .... Ewerlof B., 4, 717 24,1189;vii.,491 H 2 S on ethylidene sulphide .... C 12 H 26 S 7 180 Weidenbusch A., 66, 346 vi., 608 Thiobenzophenone .... C 6 H 5 .CS.C 6 H 5 Ci 3 H 10 S 152-153 Behr B., 5, 970 26, 276 11 )j 11 .... 146-5 Engler B., 11,924 36, 61 Tolallyl sulphide .... C 14 H 6 S 208 Limpricht A., 167, 188 Tolallyldisulphide .... GM&A .... 208 11 A., 167, 187 ; B., 26, 1032 6, 534 Tolallyl hydrosulphide (C 7 H 5 ),S. C] 4 H 10 S 144 Miircker A., 136, 75 v., 851 11 11 .... 11 .... 143-144 Limpricht B., 6, 534; A., 26, 1033 167, 192 COMPOUNDS CONTAINING THREE ELEMENTS. 313 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Tolallyl hydrosulphide (CjH^ C 14 H 10 S 143-145 Forst A., 178, 370 29, 394 350-360 172-173 B -_ Stilbene sulphide Ph.CH.CHPh.S i i C 14 H 12 S 168-169 Barbier A. C. [5], 7, 472 31,77 Benzyl sulphide (C 6 H 5 .CH 2 ) 2 S CiH 14 S .... 49-50 Marcker A., 136, 75 v., 859 49-50 Otto and Liiders B., 13, 1284 Tolyl sulphide (CH 3 .C 6 H 4 ) 2 S=(1.4) 2 a. 300 56-67 Otto B., 12, 1176 36, 926 )J ?> .... 42 Otto and Gruber A., 149, 101 Benzyl sulphide (C 6 H 5 .CH 2 ) 2 S .... 49 Marcker and Forst A., 136, 88 ; 140, 87; A., 178,371 disulphide (C 6 H 6 .CH 2 ) 2 S 2 C 14 H 14 S 2 cf. C 7 H 6 S 66-67 Marcker A., 136, 86 v., 859 ,, 66-67 Otto and Liiders B., 13, 1284 >, i 67 Bb'ttinger B., 12, 1055 )i " 69-70 Klinger B., 15, 863 Tolyl disulphide (Me.C 6 H 4 ) 2 S 2 =(1.4) 2 41 Marcker A., 136, 88 v., 859 1, >! IJ 43 Beckurts and Otto B., 11, 2066 36, 230 ,, .... =(1.3), abt. 150 d. 1.-12 Hiibner and Post A., 16!), 51 vli.,1170;27,60 ,. ,, !) abt. 150 p.d. Liquid Hiibner & Muller Z. C. [2], 7, 14 24, 121 Dipheuthioethane 1 PhS.CH^CHj-SPh C, B H,.S 65 150-151 Ewerlof B., 4, 717 A., 216, 328 vil., 491 Distyroleue sulphide .... 16 14 .... 150-151 .... J. [1880], 404 Cetyl sulphhydrate C 16 H 33 .SH C 16 H 34 S 50-5 Fridau A., 83, 18 i., 842 Octyl sulphide (C 8 H 17 ) 2 S ,, a. 310 d. Liquid Moslinger R, 9, 1003 ; A., 30, 394 185, 59 Phenyldiphenylene sulphide Ph.C 6 H 3 .S.C f H 4 C 1S H 12 S .... 97 Grsebe A., 174, 177 28, 275 Mesityl disulphide (Me 3 .C 6 H 2 ) 3 S 2 =(1.3.5.6) 2 ClgH^S-i 125 Holtmeyer Z. C. [1867], 688 vi., 301 Pseudocumyl disulphide =(1.3.4.?), 115 Rudloff B., 11, 32 34, 414 Triphenylic orthothioformate CH.(SPh) 3 C 19 H 16 S 3 39-5 Gabriel B., 10, 185 32, 311 a-Naphthyl sulphide (C l() H 7 ) 2 S C 20 H 14 S abt. 100 Armstrong R, 7, 407 vii., 844; 27, 803 13- n a. 100 J) H a-Naphthyl disulphide (C 10 H 7 .) 2 S 2 CjoHuS., 85 Schertel A., 132, 94 v., 1093 p- ,, .... 132 Billeter B., 8, 463 p- .... 136 Maikopar Z. C. [18691 711 Tribeuzylic orthothioformate CH(S.CH 2 Ph) 3 CjjH^,, .... 98 Dennstedt B., 11, 2265 36, 318 Diphenyl sulphide (Ph.C 6 H 4 ) 2 S C 24 H 18 S .... 171-172 Gabriel & Deutsch B., 13, 387 38, 476 disulphide (Ph.C 6 H 4 ) 2 S 2 C 24 H, 8 S 2 .... 148-150 . 38, 477 Diphenylmethane disulphide (Ph 2 CH) 2 S 2 CjsH-sSj .... 151 Engler B., 11, 925 36,61 Thionessal (thiolepidene) ... CPLCPh : CPh.CPh.S i i C^H^S .... 178 Laurent A. C. [3], 1, 292 v., 779 # 180 Marcker and Forst A., 136, 94 ; A., v., 85 178, 376 1! J1 180 Fleischer A., 164, 192 vl., 1087 Ditolallyl disulphide (dithio- .... CjgHjoSj 350-360 172-173 A. lepidene) Mericyl sulphhydrate C 30 H 61 .SH Q, H 62 S 94-5 Pieverling A., 183, 349 31,586 Cetyl sulphide (CMlS C 3! H 66 S .... 57-5 Fridau A., 83, 16 i., 842 2 s 314 ORGANIC COMPOUNDS. 7. CHSe AND CHTe. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethyl selenhydrate C 2 H 6 .SeH CjHjSe m.a. 100 Wb'hler & Siemens A., 61, 360 ii., 543 Methyl selenide .... *. (CH 3 ) s Se )J 58-2 Liquid Jackson B.,8,109;A.,179,1 28, 553 Ethyl selenide (qjsj& C 4 H 10 Se 108 Liquid Pieverling B., 9, 1470 ; A., 31, 290; 34, 130 185, 331 .... .... n 107-108 .... Eathke A., 152, 210 ; Z. 0., 12, 724 Ethyl diselenide (CfU&, C 4 H 10 Se 2 186 .... n }J vi., 1015 Selenio-isovaleric aldehyde .... CHMe 2 .CHj.CHSe C 6 H 10 Se .... 56-5 Schroeder B., 4, 403 24, 560 Seleniobenzaldehyde C 6 H 5 .CHSe C 7 H 6 Se .... 70 Cole B., 8, 1165 29, 397 Benzyl selenide (Cf^CB^ff C 14 H 14 Se 45-5 Jackson B.,8,111;A.,179,8 28, 553 diselenide (C 6 H 5 .CH 3 ) 2 Se 2 C 14 H 14 Se s .... 90 > B., 7, 1277 ; A., 28, 154; 89, 580 179, 11 Methyl telluride (CH 3 ) 2 Te C 2 H 6 Te 82 .... Wohler and Dean A., 93, 233 iii., 992 Ethyl telluride (C 2 H 6 ) 2 Te C 4 H IO Te b. 100 Wohler A., 35, 111 ii., 550 !) I) J) 98 .... A., 79, 223; 84,69 Isoamyltelluride (C 5 H n ) 3 Te C^Te abt. 198 .... Wohler and Dean A., 97, 2 i., 206 8. CHN. Hydrocyanic acid H.CIN CHN 26-5 s. 15 Gay Lussac A. C., 95, 136 Cyanamide .... .... N : C.NH 2 CH,N,, 40 ii., 188 Param .... ^ij.^ 1 2 100 Beilstein & Geuther A., 108, 88 iv., 349 Ammonium cyanide.... NH 4 .CN )) CH 4 N 2 36 Crystalline ? ii., 203 Methylamine .... CH 3 .NH 2 CH 5 N 8. b. Wurtz iii., 995 53 Fisenberg A., 205, 139 40, 83 Methyl carbamine (methylic CH 3 .NC C 2 H 3 N 58-59 1. 45 Gauthier J., 20, 367 vi., 528 isocyanide) )) !> H :> 59-6 .... A., 152, 222 Acetonitril (methylic cyanide) CH 3 .CN 70-9-72-1 .... Kopp A.. 133, 137 (745) > > .... it 77-78 .... Buckton & Hof mann J., 9, 508 !) 1) .... * 77-78 .... Siersch J., 21, 681 *, )) CH 3 .CN j 77 .... Dumas J., 1, 592 ii., 257 )) JJ > n 77-78 .... Frankland and .... >1 Hofmann >! M 76-5-77-5 Liquid Engler J., 18, 310 vi., 523 =77-6 c. I, )) )) tt 81-82 Liquid Gunthier B. S. [21, 9, 2 ?, )) )) )) H 81-6 Vincent and Dela- C. R., 90, 747 38, 525 chanal Dicyanodiamide .... C 2 H 4 N 4 .... 204 Hofmann B., 2, 606 vi., 1118 i) .... )) .... 205 Haag A., 122, 22 Acetylamine (?] .... C 2 H 6 N (?) 218 .... Natanson J., 9, 527 Dimethylamine NH(CH 3 ) 2 C S H 7 N 8-9 .... Hofmann A., 102, 317 iii., 998 )1 -10 to 15 ... Petersen J., 10, 382 NH 2 .C 2 H 5 18'7 Wurtz J., 3 116 ii P* 1 ^ i> )) JJ ) 18-7 .... Liunemann A., 162, 12 n*) >>') vil., 223; 25, 477 Ramsay qo >T OW, D/ Ethylene diamine C 2 H 4 (NH 2 ) 2 C 2 H 8 N 2 117 .... ii., 586 ,, n ) 116-5 8-5 Ehoussopolos and A., 212, 251 42, 940 Meyer Dimethyl hydrazine NMe 2 .NH 2 ) 62-5 (717) Liquid Reuouf B., 13, 2171 40, 152 Ethylhydrazine NHEt.NH 2 J) 99-5 .... A., 199, 287 Trihydrocyanic acid NH 2 .CH(CN) 2 C 3 H 3 N 3 MM abt. 180 Wippermann B., 7, 767 27, 1085 Glyoxaline (cf. B., 15, 2706) CH:N.CH 2 .N:CH 2 C 3 H 4 N 2 266 c. 86-88 Lubawin B., 10, 1366 COMPOUNDS CONTAINING THREE ELEMENTS. 315 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Gloxaline (cf. B., 15, 2410) CH : CH.NH.CH : N C 3 H 4 N 2 255 Goldschmidt B., 14, 1845 i i (c/B.,16,534,747) > 263 89-90 Wallach B., 15, 645 ...i ...* NH : CH.CH.CH : N (?) ) 255 u. c. 88-89 Wyss B., 9, 1543 31, 299 1 1 Propionitril (ethylic cyanide) C 2 H 5 .CN C 8 H 5 N 88-6 .... Gautier A., 150, 189 vi., 524 11 11 11 )J JJ 967 .... i) J., 21, 631 11 11 11 7> 97 .... Eamsay .... 35, 472 u J) 1) 97-08 c. Liquid Thorpe _.. 37,205 (751-6) 11 11 JJ 97-98 Limpricht J., 9, 514 ) 1) 98-1 c. .... Engler A., 133, 153 11 11 )1 97-6-98 .... 11 A., 142, 65 37, 205 !) 11 98 .... Grimm !! 11 )) )) 96 Frankland and .... 37, 741 Graham Ethyl carbamine (ethylic C 2 H 5 .NC )J 78-79; 1. 68 Gautier J., 20, 367 vi., 529 isocyanide, 78-80 u 11 ) 82 Pelouze A., 10, 249 U., 211 1! 11 11 ) 88 .... Frankland & Kolbe J., 1, 552 )) C,H 5 N 5 265 u. c. Nencki B., 7, 1584 ;C.C. 28, 1202 V 3**5'*- 1 a [1875], 51 Formoguanamine ) .... n. f. 350 11 11 28, 755 Allylamine CH 2 :CH.CH 2 .NH 2 C,H 7 N 58 Oeser A., 134, 9 vi., 95 ^s- 1 -- 1 -? 60 Liebermann & Paal B., 16, 530 Trimethylamine N(CH 3 ) 3 " C 3 H 9 N 9 Hofmann 4,304 iii., 998 11 > n 8 Liquid Vincent B. S. [2], 27, 150 32,380 Propylamine .... .... .... CH 3 .CH 2 .CH 2 .NH 2 49-50 (761) Silva Z. C. [2], 5, 638 vi., 966 11 H ? 49 Linnemann A., 162, 3 vit, 223 46-46-5 A., 161, 44 25, 236, 477 i = 49 c. 11 j) j) 49-7 Mendius A., 121, 136 v., 891 >j 47-48 Hofmann B., 15, 769 Isopvopylamine j) (CH 3 ) 2 CH.NH 2 j? SI- 5-32-5 Gautier C. E., 67, 723 vi. r 966 11 j) 31-5 (743) .... Siersch Z. C. [2], 5, 145 vi., 967 11 " ) 31-32 .... Hofmann B., 15, 769 Propylene diamine C 3 H 6 (NH 2 ) 2 C 3 H 10 N 2 119-120 i) B., 6, 308 26, 881 ; vii., 1021 Ethylenic dicyanide NC.CHj.CHj.CN C 4 H 4 N 2 .... 37 Simpson P. E. S., 10, 574 11 11 51 .... 37'8 Moore B., 4, 521 ; A. J. 24, 701 ; 25, S. [3], 3, 177 485 ; vii., 10 11 ii )5 ) .... 50 Geuther A., 120, 268 ii., 212 11 11 }) 140-160 54'5 Nevol6 and Tscher- C. E., 86, 1411 ; 34,964 (4 to 5) niack B. S., 30, 101 !1 11 )) 158-160 (SO) .... Pinner B., 16, 360 Allylic cyanide (a-croton- CH 2 : CH.CH 2 .CN C 4 H 6 N 96-106 Lieke A., 112, 316 ii., 203 isonitril) (a-croton- CH 3 .CH : CH.CN 11 115-117 .... Kekul6 and Einne B., 6, 388 nitril) 11 11 11 112-120 .... Pinner B., 12, 2054 11 11 11 )) 11 118 c. Will and Korner J., 16, 499; A., iii., 1075; vi., 118-7-119-2 c. 125, 273 525 11 11 11 )) n 116-118 .... Rinne and Tollens Z. C. [2], 7, 251 vii.,49,25,1021 Pyrroline (pyrrol) CH ! CH.CH : CH.NH 1 1 n 126-2 (746-5) .... Weidel & Ciamician B., 13, 70 38, 404 11 11 )J 11 127 11 11 W. A., 81, 572 40, 295 11 11 11 133 .... Anderson J., 10, 399 iv., 783 11 133 .... Eamsay .... 35, 472' i) 11 11 133 .... Niederstadt C. C. [1873], 154 27, 499 11 i) n 133 Bell B., 10, 1810, 1868 36, 525 11 11 11 133 .... Weidel & Ciami9ian B., 13, 70 38, 404 2 s 2 316 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Pyrroline (pyrrol) cf. B. 6H.CH : CH.CH.NH i i C 4 H 5 N 133 .... Schiff B., 10, 1501 34, 216 , HoO Methylglyoxaline (oxal- MeN : C.CH 2 .N : OH i i C 4 H 6 N 2 195 Liquid Goldschmidt B., 14, 1846 42, 166 methyline) ii " 11 Paramethylglyoxaline (glyoxalethyline) * )> N : CH.C : NEt NH : aCHj-CHs-N : CH or * )) 197-198 197^199 267 Liquid Liquid 186 136 Wallach & Schulze Wallach Wallach & Schulze Wallach B., 14, 422 B., 15, 644 B., 14, 425-427 B., 15, 644 ; A., 40, 572 42, 821 40, 572 44, 49 NH : C.OHMe.N : CH i i 214, 297 CH : N.CHMe.N : CH i i >J > 266-268 136 137 j Kadziszewsky B., 16, 542 B., 15, 2707 44,308 1) !' Allylcyanamide (sinamine) .... C 12 H 19 N 6 ?" CH 3 CH 2 .CH 2 .CN H ) C H 7 N 260-270 118-5 Crystalline 100 j> Dumas B., 16, 487 A., 52, 15 A., 64, 334 44, 728 i., 698 116'3 Rossi C. E., 70, 129 vi., 964 115 117 (744) Linnemann & Zotta A., 162, 12 vii.,222;25,47r. Isobutyro-nitril j> Isopropyl carbamine (iso- . cynanide) Hydropyrroline Me 2 CH.CN Me 2 CH.NC C 4 H 6 '.NH MeCH CMe : N H ) t> j) )> 107-108 80 80 87 90-91 c. IRQ 1. 68 Liquid 88 Letts Markownikoff Erleiinieyer Gautier Ciamician and Dennstedt Gutknecht B., 5, 671 B. S. [1866], 53 C. R., 67, 723 B., 15, 1172 ; 15, 1831 ; 16, 1536 B., 13, 1116 vi., 525 v., 890 vi., 530 42, 1214; 44, 82, 1142 38, 712 i i > Acetoguanamine CH.,NH.(C : NH) 3 .NH (?) C 4 H 7 N 5 265 u. c. Nencki B., 7, 775, 1585 Ethyldicyandiamide C H 7 NH C 4 H 8 N 4 C H N 300 71 sn .... Cloez andCannizzaro A., 78, 228; 90, 96 B , 12, 992 ii., 190 36, 712 Diethylene diarnine Diethylamine j, ,, Butylamine (C 2 H 4 ) 2 N 2 H S NHEtj i Me(CH ) NH C 4 H 10 N 2 C 4 H U N ) . . 1* )> 170 55-5 (759) 57 v.t. 10 (120) 220 c. t. (387 ats.) 320 c. t. Oudemans Hermann Isambert Bewar Dewar and Scott B., 16, 390 J., 4, 489 C. R., 96, 708 C. N., 51, 29 P. R, S., 35, 347 A 158 172 ii., 586 ii., 559 44,727 45, 139 vii., 222 24 .... .... .... )j .... ... Isobutylamine ,, ,, .... ... 5, .... ... ,, Butylamine .... i MejCH-CHyNHs V J 1 ) ) )> CH 3 CH 2 CHMe NH > )) T> ) 11 1 5 )J 76-5 76-77 69-70 67-5 65-8-68-3 (743) 65-67 65-5 62-65 62-65 Linnemann Linnemann & Zotta Wurtz Linnemann Hofniann Eeimer Hofmann & Eeimer A., 162, 3 A., 162, 12 A., 93, 124 A., 162, 3 A., 162, 12 B., 15, 769 B., 7, 511 Z. C. [2], 7, 26 B., 3, 756 B 7 510 522 vii., 223 25, 475 ; vii., 222 v., 737 vii., 223 25, 477; 34, 849 ; vii., 222 42, 1054 27, 792 24, 121 vii., 222 27 792 " B 7 1289 28 141 Me C NH 2 1) A 162 19 vii., 223 -25 477 r ) A 192 65 34 779 i) RiirlnpflF B 11 988 36 40 ? .... .... ... )i >t 44-5(745'7 r) Liquid > B., 12, 1023 B S [ 9 ] 33 297 36, 713 38 545 Petinine Diethylhydrazine NEt 2 .NH, )i C 4 H 12 N 2 70-5 96-99 ) Anderson A. A., 199, 308 v., 737 COMPOUNDS CONTAINING THREE ELEMENTS. 317 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. . "Watts' Diet. & J. Ch. Soc. Butylene diamine C 4 H 8 (NH 2 ) 2 C 4 H 12 N 2 a. 140 Fairlie As., 3, 372. v., 739 ; 17, 362 Tetramethyl tetrazone Me 2 N.N : N.N.Me., C 4 H I2 N 4 abt. 130 Eenouf B., 13, 2173 40, 152 Diethylene triamine NH:(C 2 H 4 .NH 2 ).;~ C 4 H 13 N 3 208 Hofmann P. R. S., 10, 224 ii., 589 Butyline C 4 H 7 .(NH 2 ) 3 a. 150 .... Fairlie As., 3, 373 v., 740; vii., 415 ; 16, 362 Ethenyl tricyanide C 2 H 3 .(ON) 3 C 6 H 3 N 3 42 Orlovsky B. S. [2], 28, 348 34, 31 Pyridine +3H 2 O C 5 H S N 92-93 Goldschinidt and B., 16, 2977 46,611 Constam CH : CH.CH : CH.CH : N 115 l\ 1 -^s! 1 11 Lf D. P. 244 234 42 1254 i i )J .... 115 Richard B. S. [2], 32, 486 38, 480 115 Tbenius J., 14, 502 116 Orimaux C. R. 95 85 42 191ft 11 ^**, i i " 116-5 Church and Owen J., 13, 359 115-116 Vohl & Eulenberg A. P. [2], 147 130 24 1 077 '* j> I) *^i L\J ^ i 116-7 -Anderson A., 96, 200 117 iv., 755 11 117 Ramsay 35, 472 115-122 Weidel A. 165 328 26, 508 n 120 Weidel and Hazara M. C., 3, 770 44, 223 *j 130 Hantzsch A., 215, 1 44, 85 11 -Propylene dicyanide CH 3 .CH(CN).CH 2 .CN C 5 H,N 2 252-254 12 Pinner B., 12, 2054 38,99 11 i 11 1) 255-263 c. .... .... A., 121, 160 ; 182, 327 i* )> )) 1) 277-290 .... Simpson .... v., 893 Methyl pyrroline CH I CH.CH : CH.NMe i i C 5 H 7 N 112-113 Liquid Bell B., 10, 1866 36, 525 a-Homopyrroline C 4 H 3 Me : NH 145-5 (742-8) Liquid Weidel & Ciamician B., 13, 77 38, 404 a- 1) )1 145 .... >5 I) W. A., 81, 512 40, 295 a- n 11 147-148(750} Ciamician R, 14, 1057 0- n 142-143 .... >5 (742-7) Paramethyl-methylglyoxaline C 4 H 5 MeN 2 C 5 H 8 N 2 205-206 Liquid Radziszewski B., 16, 488 44,729 (oxalmethylethyline) Ethylglyoxaline C 3 H 3 N : NEt 209-210 Liquid Wallach B., 16, 535 44, 910 Paraethylglyoxaline (glyoxal- C 3 H 2 EtN : NH 11 .... 76-77 H B., 16, 543 44,911 propyline) 55 n ii 11 268 79-80 Radziszewski B., 16, 490 44, 729 Butylic cyanide (valeronitril) Me.(CH a ),.CN C 5 H 9 N 140-4(739-3) Lieben and Rossi A., 158, 171 24, 522 ; vii., 216 Isobutylic cyanide (isovalero- CHMe 2 .CHj.CN 11 126-128 (714) Erlenmeyer & Hill A., 160, 257 25, 242 nitril) 15 11 11 1 )) 125-128 .... Gluckeberger A., 64, 77 ii., 273 11 11 11 11 11 125 .... Schlieper A., 59, 15 n 11 11 51 1 125-128 Letts B., 5, 673 vii., 1200 Trimethyl acetonitril CMe 3 .CN 11 105-106 15-16 Butlerow A., 170, 156 27, 247 11 11 11 begins 105 .... Dobbin 37, 238 11 ji 11 H abt. 103 .... Butlerow B., 5, 478 vii., 221 ; 26, 48, 1020 ! )l > > 11 11 abt. 103 Butlerow and B. S. [2], 18, 124 25, 1092 Gerainow Isobutylic isocyanide (iso- CHMe 2 .CHj.NC ) 114-117 pasty 60 Gautier A., 152, 221 vi., 530 butylcarbamine) Dietbylcyanamide NEt 2 .CN C 5 H 10 N 2 190 .... Cloez & Cannizzaro A., 78, 228 ii., 190 u >J 1 186 u. c. .... Fileti and Sehiff B., 10, 428 32, 307 Ethylallylamine NHEt.C 3 Hj C S H U N 83-85 Rinne A., 168, 261 27, 50 51 ! 84-86 Liebermann & Paal B., 16, 526 44, 909 51 11 81-88 Konigs B., 12, 2344 "- ,: ,, 15 85 .... Gal C. R., 76, 1354 26, 1026 Piperidine CH,,(CH 2 ) 4 .NH 106 Cahours A. C. [3], 38, 78 iv., 656 106 Gal C. R., 76, 1354 26, 1026 , 318 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Piperidine .... .... .... CH 2 .(CH 2 ) 4 .NH C s H n N 106 Rinne A., 168, 261 27, 50 Tetramethylammonium cya- NMe 4 .CN C 5 H 13 N 2 v. 225-230 295 Claus and Merck B., 16, 2743 46, 338 nide w. m. .. v. 225-227 Thompson B., 16, 2338 46, 286 w. m. Piperyl hydrazine C 6 H 10 :N.NH 2 145 Liquid Knorr B., 15, 859 42, 1115 11 146 Liquid A., 221, 297 46, 467 Amylamine .... CH 3 .(CH 2 ) 4 .NH 2 C H N 103 Liquid Hofmann B., 15, 770 42, 1054 Isoamylamine CHMej.CHj.CH2.NHj 11 95-96 B., 15, 771 95-96 Wurtz A. C. [3], 30, 447 11 95 .... Silva C. R., 64, 209 94 .... i., 207 93 Brazier and Gosleth A., 75, 253 11 92-93 Custer 40,33 92-93 Gautier and Etard C. R., 97, 263 46,90 (inactive) 96-97 (766) .... Plimpton C. R., 91, 433 39, 332 (active) .... 96-97 n 39, 334 Pseudo isoamylamine CHMe 2 .CHMe.NH 2 78-5 .... Wurtz B. S. [2], 7, 243 vi., 116 > 11 n 78 Rudneff B. S. [2], 33, 297 38, 546 Cespitine Amvlamine ? 95 Church and Owen J. [1860 & 1868] v., 1088 Cyanpyridine.... C 6 H 4 N.CN C 6 H 4 N 2 48-49 Fischer B., 15, 63 42, 627 o-Amidazophenylene H 2 N.C 6 H 3 .N I N C 6 H 5 N 3 ".'. 98-5 Ladenburg B., 9, 222 29, 933 L 1 1 1 11 C 6 H 4 .N.NH.N =1.2 .... 100 Griess B., 15, 2195 1 f Phenylamine (aniline) C 6 H 5 NH 2 C 6 H 7 N 185 iii., 421 11 n Jl 182 b. 20 Hofmann A., 47, 50 iv., 421 11 11 183 .... Ramsay 35, 472 11 11 11 185-186 Schiff A., 159, 158 24, 958 11 11 182 Hofmann & Martius B., 4, 743 24, 1060 11 n 11 184 Heumann & Kochlin B., 16, 603 44,781 11 11 11 180 Heutschel J. p., 27, 498 44, 1108 11 11 182-183 8 Lucius B., 5, 154 vii.,942; 25,502 ,1 11 185 Bruhl B., 12, 204 36, 499 11 n 182-5 .... 11 A., 200, 139 38, 296 11 11 183 Thorpe .... 37, 151 11 11 a 183-7 'c. (733-2) 37, 221 11 ,, 184-8 (737-2) .... Kopp A. 11 11 i, 184-5 .... Stredler and Arndt J., 17, 425 11 11 183-5-184-5 .... Frankland .... 37, 561 a-Picoline (methylpyridine) C 5 H 4 MeN 1SS-5 (760) Thorpe 37, 223 - 11 n 133-135 ...* Anderson A., 60, 93 iv., 638 "- ,, ., ,, 11 134 .... Thenius J., 14, 502 a ~ 11 n 134 .... Ramsay .... 35, 472 "- 11 11 133-9 u. c. Weidel B., 12, 2008 38, 269 a ' n 11 11 134-135 .... Vohl and Eu lenberg A. P. [2], 147, 130 24, 1077 a ~ 11 n ,, 135 Churoh and Owen J., 13, 359 iii., 421 "" 11 11 135 .... Hantzsch A., 215, 61 44,85 "- n n ,i 11 135 .... Baeyer a- ,i 135 .... Richard B. S. [2], 32, 486 38, 480 a ~ 11 11 135 Kissling D. P., 244, 234 42, 1254 P~ 11 11 11 140-1 Weidel B., 12, 2010 38, 269 ft- 11 11 11 11 144-146 .... Zanoni B., 15, 528 y- 11 11 11 132-150 .... Richter Tabellen Parapicoline .... .... OfJA 01 K Anderson J., 10, 396 From propaldehyde ammonia n 11 ,; 267 HO Hofmann P. R. S., 12, 639 iv., 481 it n 11 11 ,1 .... 140 Meyer and Stuber A., 163, 161 26, 507 .. .... 140 Griess B., 11, 1731 36, 247 COMPOUNDS CONTAINING THREE ELEMENTS. 319 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Diamidobenzene (phenylene C 6 H 4 (NH 2 ) 2 =1.4 C 6 H 8 N 2 140 Stover B., 7, 463 27,806 diamine) 11 11 1) 11 .... 140 11 B., 7, 1315 28, 271 >! 11 1 .... 140 Binne and Zinck6 B., 7, 871 27, 1163 1! 11 11 1 .... 140 Wurster A., 173, 145 28, 758 !> 11 11 11 .... 140 Hiibner A., 208, 296 40, 1130 .1 >1 11 71 1> .... 140 Nietzki B., 11, 1098 11 !I 11 11 .... 140 Griess B., 7, 12, 1224 11 11 11 11 .... 140 11 B., 5, 201 1! 11 11 11 11 .... 140 Hobrecker B., 5, 920 11 11 11 11 .... 140 Korner G. L, 4, 305 29, 234 11 >! 11 11 .... 139 Merz and Weith B., 10, 762 32,603 11 11 11 11 139 Fleischer & Nemes B., 10, 1298 32, 886 11 11 = 1.2 11 Mixture ? 120 HUbner A., 208, 278 40, 1131 11 }> i 11 .... 102-103 A., 171, 63 ; 209, 360 >! 11 M 11 11 102 Stover B., 7, 1315 28, 271 11 n 11 11 11 ... 99 Salkowski A., 173, 58 vii.,925;28,72 11 11 i 1 250 99 11 B., 5, 724 25, 1024 11 11 'i 11 11 .... 99 Wurster A., 173, 145 28, 757 11 11 ) Ji 1} 99 Korner G. I., 4, 305 29, 234 11 " 11 11 1 .... 99 Ladenburg B., 9, 221 29, 933 11 11 11 11 J> .... 99 Zincke and Sintenis B., 6, 123 26, 640 11 11 i 11 abt. 252 99 Griess B., 5, 202, 855 ; 24, 562 ; 26, P. RS., 20, 168; 499; 26, 178; J.p. [2], 3, 143 vii., 137, 947, 1188 11 11 11 i 1 99 Kommier B. S. [2], 18, 70 25, 1004 !! " >i 1 Mixture ? 86-87 Korner G. I., 4, 305 29, 207 11 " =1-3 1 276-277 c. 61-62 Zinckfi and Sintenis B., 5, 792 (760) 1 " 1 1) 276 63 11 11 ! 11 11 > 11 270-276 63-64 Wurster B., 7, 150 1 1) 11 1 .... 64 11 A., 173, 145 28, 757 11 11 11 ! > 268-276 62-63 Wurster & Ambiihl B., 7, 214 27, 588 11 . 11 11 > 287 63 Hofmann P. E. S., 12, 163 ; iv., 481 ; vii., J. [1861], 512 137, 947; 84, [1863], 422 562 1! 11 11 11 11 .... 63 Salkowski A., 173, 39 28, 72 11 11 11 63 Griess B., 7, 1225 28, 263 1) 1 Jl .... 63 11 B., 11, 625 34, 605 11 11 11 M 1) 63 Korner G. I., 4, 305 29, 234 11 11 11 1 11 .... 60 Limpricht B., 8, 290 28, 766 11 >! 1 11 11 60 Hiibner A., 222, 67 46, 315 Phenyl hydrazine NHPh.NH 2 11 233-234 23 Fischer A., 190, 71 34, 303 170 (760) Schichlone and G. I., 12, 416 ; 44, 51 Denaro B., 16, 426 Ketine .... 11 170-180 .... Treadwell & Steiger B., 15, 1060 Methylhydropyridine OH : CH.CH : CH.CHj.NMe C 6 H 9 N 129 .... Hofmann B., 14, 1499 40, 921 Ethylpyroline CH : CH.CH : CH.NEt 1 1 11 131 Liquid Bell B., 9, 936 30, 630 11 11 11 131 .... 11 B., 10, 1862 36, 525 i' 11 11 151 .... 11 B., 11, 1811 11 11 > 155-175 .... Lubavin Z. C. [2], 5, 399 ; 36, 525 ; vi., B., 2, 201 982 Dimethylpyrroline C 4 H 2 Me 2 :NH 11 165 (752) Liquid Weidel & Ciamisian B., 13, 78 38, 404 11 11 160-170 .... 11 11 W. A., 81, 512 40, 295 a-Imidopropionitril .... .... C 6 H 9 N 3 .... 67-68 Urech B., 6, 1115 27, 148 " 11 11 .... 68 Passavant A., 200, 126 38, 313 Triamidobenzene C 6 H 3 (NH 2 ) 3 =1.3.5 11 ... .... .... A., 215, 349 320 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Triamidobeuzene .... ... C 6 H 3 (NH 2 ) 3 =1.2.3 C 6 H,N 3 336 c. 103 Salkowski A., 163, 23 25,715;vii.,147 11 15 abt. 300 103-104 B., 5, 23 25, 303 =1.2.4 n 340 .... A., 174, 265 28, 367 : 11 15 340 .... B., 6, 140 26, 639 55 15 330 a 11 Kyanmethine.... sb. 180-181 Bayer B., 2, 322 Paramethylethylglyoxaline C 3 H 2 MeN:NEt C 6 H 10 N 2 212-213 Liquid Wallach & Strieker B., 13, 512 ; A., 38, 546 (oxalethyline) 214, 298 it 11 51 212 Liquid Radziszewski B., 16, 489 44, 729 11 11 212-213 .... Wallach B., 15, 644 42, 821 11 11 11 212-5 B., 14, 424 Propylglyoxaline C 3 H 3 N:NPr 219-223 Liquid B., 15, 650 ; A., 214, 321 Paraisopropylglyoxaline C 3 H 2 Pr0N I NH 15 240-265 129 Radziszewski B., 16, 747 44, 1086 (glyoxalisobutyline) Ethylallylcyanamide (ethyl- NEt(C 3 H s ).CN .... 100 .... A., 83, 348 v., 307 sinamine) Isoamylic cyanide (capro- CHMe 2 .CH2.CH 2 .CN C 6 H n N 155 .... A., 106, 284 nitril) ii 11 US .... Frankland&Kolbe A., 65, 288 ; J., ii., 203 1, 559 Ethyldimethylacetonitril .... CEtMe 2 .CN 130 s. f. m. Wischnegrodsky B., 7, 730 27, 1083 128-130 .... A., 174, 56 Isoamylic isocyanide.... CHMe 2 .CH 2 .CH 2 .NC 137 Liquid Hofmann A., 146, 109 vi., 530 Diallylamine .... NH(C H ) 111 Ladenburg B., 14, 1879 Propylene guanamine Me.CH 2 .CH:C 3 N s H 5 C 6 H U N 5 sb. 210 230 Nencki B., 9, 231 30, 187 Triethylenediamine .... (C S H 4 ) 3 .N, C 6 H 13 N 2 abt. 210 Hofmann P. R. S., 9, 154 ; ii., 586 J. [1858], 343 Hexamethylentetramine .... C 6 H 12 N 4 .... 120-125 Bartoli & Papasogli G. I., 13, 287 46, 170 11 .... sb. 100 .... A., 115, 324 Propylallylamine NHPr.C 3 H 5 C 6 H 13 N 110-114 Liebermann & Paal B., 16, 526 44, 909 Methyl piperidine C S H 10 1 NMe 107 Hofmann B., 14, 659 40, 621 .... 118 Cahours A. C. [3], 38, 92 iv., 657 11 i) C 5 H 9 Me . NH 122 Ladenburg C. R., 98, 516 46, 760 ,, 121-124 .... B., 17, 388 46, 1054 Ethenyldiethylamidine NHEtCMe : NEt C 6 H 14 N 2 165-168 Liquid Wallach and Hof- A., 184, 116 32, 189 mann Triethylamine NEt 3 C 6 H I5 N 89 .... .... J. [1862], 331 ; Z.C. [1866], 513 89-2 .... Briihl A., 200, 185 38, 296 90-1 ; Pawlewski B., 16, 2633 46, 252 267-1 c. t. 90-91 .... Dewar and Scott P. R. S., 35, 348 46, 258 Diisopropylamine NHPr/ 83-5-84 (743) .... Siersch Z. C. [2], 5, 145 ; vi., 967 A., 148, 265 Hexylamine . .. .... CH (CH ) NH 128-130 Hofmann B., 15, 771 42, 1054 '3 25' 2 " 191 19ft Pelouze & Cahours A., 124, 295 ; J., 1 1 IZiO 16, 527 CH 3 .(CH 2 ) 3 .CHMe.NHo 116 Uppenkamp B., 8, 56 28, 552 114-117 Jahn B., 15, 1292 CMeEt 2 .NH a " 108-110 A., 185, 123 Triethylene triamine 55 216 L Hofmann P. R. S., 10, 224 ; ii., 589 J. [1861], 520 i-Diazobenzonitrilimide C 6 H 3 (CN)N 2 : NH C 7 H 4 N 4 .... 57 Griess B., 2, 370 vii., 427 Phenyl isocyanide Ph.N : C C 7 H 5 N 160 pd. Liquid Hofmann .... vi., 530 Benzonitril (phenylic cya- C 6 H 6 .CN 190-6 (733) Liquid Kopp A. i., 563 nide) 11 11 11 190-191 Fehliug A., 49, 91 11 11 11 192 Ramsay .... 35, 472 15 15 11 191 Weith B., 6, 212-213 11 11 51 H 191 .... Merz and Weith B., 10, 747 32, 602 11 11 55 51 .... -17 Hofmann G. J. C., 1862 COMPOUNDS CONTAINING THREE ELEMENTS. 321 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts Diet. & J. Ch. Soc. Benzonitril (phenylic cyanide) 6 H 5 .CN 7 H 5 N 191 .... Henke G. J. C., 1856 >J a 190 Limpricht A., 106, 284 Phenylcarbamiue (phenylic 6 H 5 .NC jj 767 .... .... A., 144, 117 isocyanide) )! 9) 150-182 .... Weith B., 6, 211 .... (C 7 H 5 N) .... 229-230 A., 214, 211 Cyauanilide (phenylcyan- C 6 H 5 .NH.CN C 7 H 6 N 2 36 Cahours and Cloez A., 90, 91 aniide) .... )) .... 36-37 Hofmann B., 3, 267-268 Methenyl phenylenedianiine C 6 H 4 .NH.CH : N=1.2 1J abt. 360 167 Wundt B., 11, 827 34,667 I 1 Amidobenzonitril C 6 H 4 .NHj.CN=1.3 11 288-290 52 Hofmann Z. C. [2], 4, 726 ; vi., 527 B., 1, 196 j, 11 11 )? 52-53 Fricke B., 7, 1321 11 )1 11 3J 53 Griesa Z. C. [2], 4, 725 ; 31 B., 1, 191 )i " ) 51 1> .... 54 ! B., 8, 861 5) = 1.4 (?) 11 74 Engler A., 149, 302 11 J} 1> .... 86 Griess B., 7, 861 29, 267 J1 =1.2 )1 103 Hiibner B., 10, 1714 34, 140 11 .... .... =1.4 )1 .... 110 Fricke B., 7, 1322 28, 272 aH 4 .CH.NH.N or 1> .... 146-5 Fischer and Kuzel A., 221, 261 46,441 C 6 H 4 .CH : N.NH 1 1 Anliydroformaldehydaniline Ph.N:CH 3 C 7 H 7 N .... d.w.m. Tollens B., 17, 653 46, 988 , Parazotolueue (polymer) .... See CjsHajN, (C 7 H 7 N) n 244-245 Barsilowsky B., 6, 1209 27, 274 11 9) )> 244 A., 207, 105, 118 40, 432 Amidazotoluylene (cf. B., 15, Me.NH 2 .C 6 H 2 .N:N C 7 H 7 N 3 323 83 Ladenburg B., 9, 220 29, 933 1880) Benzimidoamide Ph.C(NH a .) ; NH C 7 H 8 N 2 .... 75-80 Pinner and Klein B, 11, 6 34,491 Benzylamine C 6 H 5 .CH 2 .NH 2 C 7 H 9 N 182-183 Liquid Cannizzaro A., 134, 128 v., 867 U JJ 182-18V5 .... Mendius A., 121, 144 3> 1) 183 Limpricht A., 144, 318 vi., 337 ,, Jl )) 185 .... Strakosch B., 5, 693 vii., 181 1 J) 185 .... Rudolph B., 12, 1297 36, 921 ,, .... .... Methyl aniline C 6 H 5 .NHMe j; 193 Hofmann A., 74, 150 iv., 452 11 i! 11 51 193 i) B., 10, 593 ,j n )> i) 190-191 .... ! B., 7, 523 27, 807 11 "" 11 n 190-192 Nolting & Boasson B., 10, 795 32, 755 11 11 11 )! 192 Monnet, Riverdin, B., 11,2278 36, 310 and Nolting 11 11 .... i) 193 Michler and Zim- B., 12, 1165 36, 935 merman ,, JI 11 192 (754) .... Reinhardt&Staedel B., 16, 29 44, 578 (cf. B., 10, 597) ) )) 200 Spiller P. R. S., 21, 209 vii., 73; 26, 759 Amidotoluene (pseudotolu- CH 3 .NH 2 =1.2 11 196-198 .... Korner .... vi., 1103 idine) i> J ) )> 199 1 199 I Different / Beilstein and Kuhl- Z. C. [2], 5, 521 vi., 235 i) i) ' )> 1) 199 [ samples \ berg 11 )' H 197 1. -13 i> 11 Z. C. [2], 6, 102 vi., 1103 11 ) 11 198 .... Rosenstiehl B. S. [2], 10, 192 j> 11 )) 1) ) 196 1. -21 vi., 280 1, 1) 1 )5 5) 202 c. (741) 1. 20 Rosens tiehl A. C. [4], 26, 189 25, 822 ,, !> 1 Liquid Grete A., 177, 231 29, 74 11 1> )J 11 )) 197-198 1. 16 HoogewerfF and B., 11, 1203 34,973 v. Dorp 1 !! 1* ) 11 198-4 ... Briihl A., 200, 139 38, 290 11 11 )1 11 197 .... Ramsay .... 35, 472 11 1 5) 11 197 .... Tiemanu & Schotten G. J. C., 1878 2 T 322 ORGANIC COMPOUNDS. Name. Constitution, Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Gh. Soc. Amidotoluene (toluidine) .... CH 3 .NH 2 =1.3 C 7 H 9 N 197 .... Schad B., 6, 1362 27, 377 ) JJ M 197 .... Lorenz C. N., 30, 166 vii., 1176 j J> H 197 Liquid Wroblewsky B., 8, 574 28, 886 i > " 1 ) 197 .... A., 192, 196 34, 977 j > 197 Beilstein and Kuhl- G. J. G, 1870 berg ) j> JJ )) 199-5 .... Konier G. I., 4, 305 29, 216 (747-14) IT " > )) 197-200 Widman B., 13, 677 38, 635 ) =1.4 )) 198 40 Muspratt and Hof- A., 54, 1 1, 575 mann J) > > .... 42-89 Mills P.E.S. [1881], 205 i> ; > 200 45 Beilstein and Kuhl- Z. C. [2], 5, 521 vi., 285 berg > " ) 198 J> )! G. J. G, 1869 i J " ii 205-206 45 Staedler J. p., 96, 63 v., 865 (730) > > j> ) .... 45 Staedler and Arndt G. J. G, 1864 j) ) 45 Bindschedler B., 6, 448 26, 911 ?j )* )j .... 45 Eosenstiehl A. C. [4], 26, 189 25, 823 V > ) .... 45 Hofmann B., 5, 721 25,1024; vii.,59 > > H .... 45 Wallack A., 173, 274 28, 350 j > " > > 46 Grete A., 177, 231 29, 73 Lutidine 110-130 C. E., 92, 413 n- , 145 Scichilone and G. I., 12, 444 44, 99 ) Magnamini 153-154 Ladenbure C. E., 98, 516 46, 759 C 5 Me 2 H 3 N )) 15U D Hantzsch A., 215, 56 44, 85 j) **T 154 Thenius J., 14, 502 "i., 737 - D >i i 154 .... Williams J., 17, 437 154 Eamsay 35, 472 - *.*. *> 154-5 .... Anderson J., 10, 397 "- .... > 155 Vohl and Eulenberg Z.A.G[2],147,130 24, 1077 a- .... 156-5 .... Kichard B. S. [2], 32, 486 38, 480 155 Kissling D. P., 244, 234 42, 1254 155-5 o Coninck C. E., 91, 296 40, 56 > 150-160 B. S. [2], 35, 299 40, 612 ft- (ethylpyridine) C 5 H 4 EtN )i ) 163-168 Williams J., 17, 437 iii., 737 ft- )j 163-168 .... Scichilone and G. I., 12, 444 44,99 Magnamini fl- > ij 165 Liquid Coninck C. E., 91, 296 40,56 0- >i )i 165 .... )! C. E., 92, 413 40, 443 ft- !) ji )) 166 )1 C. E., 95, 298 42, 1302 ft' I) u 166 .... )! B. S. [2], 35, 303 40, 612 0- 165 )' 11 ft- 11 I) j n 165-166 11 E. T., 1, 132 44, 220 0- i) 161-164 Weidel and Hazara M. G, 3, 781 44, 223 ft- 1, n j 166 Ladenburg C. E., 98, 516 46, 759 0- j I) 166 Butlerow and B., 11, 1253 38, 269 Wischnegradsky T i! n 152 Liquid Ladenburg B., 16, 2060 44, 1151 >- .... )i 173 Scichilone and G. I., 12, 444 44, 99 Magnamini Allylpyroline C 4 H 4 :N.C 3 H 5 105 (48) .... Ciamician and B., 15, 2581 44, 350 Dennstedt ? 177-183 Williams J., 7, 494 ? 183-187 Mendius A., 121, 129 iv., 413 Diamidotoluene (tolylene C 6 H 3 .Me(NH 2 ) 2 =1.3.r) 1) C 7 H 10 N 2 285 Liquid Stsedel A., 217, 200 44, 865 diamine) >i 11 1 9 *\ >> * 1 abt. 280 64 Nietzky B., 10, 832 32, 475 11 11 ti )* M 273-274 64 ji B., 10, 1157 32, 768 11 11 )) l) .... 64 ji B., 12, 2237 38, 162 COMPOUNDS CONTAINING THREE ELEMENTS. 323 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diamidotoluene (tolylene 6 H 3 .Me(NH 2 )= 1.2.5 C.H 10 N 2 * 65 Ladenburg B., 11, 1652 diamine) )! =1.2.3 1) 270 abt. 80 Beilstein & Kuhlberg Z. C. [2], 7, 134 ; 24, 565 ; 684 ; A., 158, 352 vii., 1180 1 " )i i !> .... 80 Biedermann B., 10, 1165 32, 784 )) =1.3.4 y 365 88-5 3eilstein& Kuhlberg Z. C. [2], 7, 134 ; 24, 565, 683; A., 158, 351 vii., 1180 )> )) )l 11 .... 89 Ladenburg B., 10, 1123 32, 752 )I 11 11 11 .... 89 B., 9, 220 29, 933 )> = 1.2.4 abt. 280 99 Hofmann P. R. S., 11, 518; 26, 683; v., J. [1861], 513 872 ; vii., 1180 !1 11 1 i) 283-285 99 Hell and Schoop B., 12, 723 36, 715 !) 11 11 i) 99 Ladenburg B., 8, 1209 29, 401 )1 " i )) V 11 99 Bernthsen and B., 11, 1758 Trompetter )) 11 11 > .... 99 Biedermann B., 10, 1160 32,783 >! 11 11 1) .... 99 Wallach R, 15, 2826 44, 584 Methylphenyl hydrazine .... N 2 H 2 PhMe !1 222-224 (715) 1.-17 Fischer A., 190, 150 34, 312 Tolylhydrazine C 6 H 4 .Me(NH.NH 2 )=1.2 1> .... 56 Bosler A,, 212, 338 42, 1062 j =1.4 n 240-244 p.d. 61 Fischer B., 9, 890 Ethylhydropyridene C 5 H 4 H 2 EtN C 7 H U N 148 .... Hofmann B., 14, 1500 40, 921 Trimetliylpyrroliue CMe.CH:CMe!cMe.NH i _J .... 180-195 Liquid Ciamician and B., 14, 1338 Oxalethylpropyline C 5 H-EtN 2 C ; H 12 N, 219-220 Liquid Dennstedt Radziszewsky B., 16, 490 44,729 Oxalpropylethyline (J,H 5 PrN 2 )) 224-225 Liquid B., 16, 489 jj Oxalpropyliue C 3 H a MeN : NPr rj 229-234 .... Wallach B., 16, 543 44, 911 Glyoxalisoainyline 11 250-270 120-121 Radziszewsky B., 16, 747 44, 1086 (Enanthonitril Me.(CH 2 ) c .CN C 7 H 13 N 175-178 Liquid Mehlis A., 185, 368 34, 135 Dimethyl piperide'in .... 1> 137-140 Liquid Ladenburg B., 14, 1347 Butylene guanamine N.C( : NH).CHPr0 \ I NH:C.NH.C:NH C 7 H 1S N 5 172-173 u.c. Bandrowski B., 9, 240 30, 190 Diethylallylamiue C 3 H 5 .NEt 2 C 7 H la N 100-103 Rinne A., 168, 205 27, 50 .... ! 110-113 .... Liebermann & Paal B., 16, 526 44, 909 Dimethyl piperidine C 5 H 9 Me : NMe 1 118 Hofmann B., 14, 661 40, 621 >J 11 118 Liquid Ladenburg B., 14, 1346 42, 535 Ethyl piperidine C,H 9 Et:NH 1) 122 Rinne A., 168, 261 27,50 ,, .... .... 1) 128 Hofmann B., 14, 660 ,, ,, 11 128 Cahours A. C. [3], 38, 96 iv., 657 .... 11 126-128 .... Ladenburg B., 14, 1343 42,534 y- C 5 H lo :NEt 1} 143 C. R., 98, 516 46, 760 /3-Lutidine hexhydride CH,(CH.) B .NH 9 )1 C 7 Hi 7 N 155-160 153155 Liouid Coninck JJof mann C. R,, 98, 1438 B., 15, 772 46, 1047 42, 1054 v ^- M - M -3\'-^- M - m -2/fi ~^2 C 7 H 15 .NH 2 145-147 Schoi'Iemmer 16, 221 iii., 147 i> 144-148 ^elouze and Oahour^ A C T4l 1 5 Dicyanobenzene (isophthalo- )) C 6 H 4 (CN) 2 =1.3 C 8 H 4 N 2 156 Korner & Monselist *-* v ^ l_^J1 * 1 " G. I., 6, 133 31,81 nitril) 11 11 ?> 11 .... 150-160 Wollz A., 168, 81 26, 1143 11 11 J )5 11 .... 158-159 Earth and Senhofei A., 174, 236 28, 365 11 n ) 160-161 !) B., 8, 1481 29, 585 11 11 )) 5> 11 .... 156 Beyer J.p. [2], 22, 352 40,96 (terephthalo- =1.4 11 n.v. 195 Solid Wislicenus and B., 4, 984 vii., 152 uitril) Brunners j 11 11 )) 11 a. 200 Barth and Senhofer A., 174, 235 28, 366 i> >i )1 )> 11 .... 215 Limpricht A., 180, 89 29, 931 :i 11 11 Jl 11 >. ) &iG& Korner & Monselisi G. I., 6, 133 31, 81 i> 11 11 11 C 6 H 4 .N : CH.CH : N=l-2 11 CJL,N, contains T3 220-223 205-216 27 Egli Huisl^cr*^ B., 8, 818 B., 17, 318 29, 932 46, 1052 ' s 1 I ,; , ' ^ 2 T 2 324 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Dk & J. Ch. Sc Diazobenzene cyanide Ph.N:N.CN+HCN C 8 H 6 N 4 69 Gabriel B., 12, 1638 38, 41 Benzyl cyanide (a-toluicnitril) C 6 H 6 .CH 2 .CN C.H r N 226=231-9 c. Liquid Hofmann B., 7, 519 27, 793 !) 226'5=231-5c. Liquid B., 7, 1294 n 229 .... Radziszewsky B., 3, 198 37, 567 Tolylcyanide (toluic nitril) .... C 6 H 4 .Me.CN=1.2 i) 203-204 c. Liquid Weith B.,6, 419 =1.4 217'8c.(761-8) 28-5 Patern6 and Spica G. I. [1875], 25 ; 28, 642 B., 8, 441 Indole .... C 6 H 4 .CH : CH.NH=1.2 52 Li "" B., 17, 1067 46, 1030 i i " 245-246 p.d. 52 Nencki B., 8, 1517 vi., 733 Isoindole Ph.C : N.CH 2 (?) n .... 194-195 Stsedel B., 10, 1832 34, 420 194-195 S tst?d el an d Riiff - B., 9, 563 30, 297 heimer =C 16 H 14 N 2 (B., 16, 342) 194-195 Stccdel and .K.lein- B., 13, 838 " schmidt Phenylamidoacetonitril Ph.CH(NH 2 ).CN C S H 8 N .... Crystalline Tiemann & Fried- B., 14, 1967 42, 56 lander Benzylcyanamide C 6 H 5 CH 2 .NH.CN C 8 H 8 N 2 33 Strakosch B., 5, 692 vii.,182;25,l Methenyl tolylene diamine.... Me.C 6 H 3 .N : CH.NH .... 98-101 Ladenburg B., 10, 1124 32, 752 Ethenyl phenylene diamine C 6 H 4 .N : CMe.NH 170 Hiibner A., 209, 353, 357 42, 180 1 j f n JI H 175 Ladenburg B., 8, 677 28, 1036 Amidobenzyl cyanide C 6 H 4 .NH 2 .CH 2 CN=1.4 .... 43-5-44-5 Gabriel B., 15, 835 42, 1070 11 11 11 312 46 Friedlauder and B., 16, 1023 44, 918 Mahley Phenyl dicyanhydrazine Ph.N.C : NH 1 II C 8 H 8 N 4 160 pd. Fischer A., 190, 140 34, 310 HN.C : NH Phthalidine .... C S H 7 : NH 2 P TT 1ST 9 __ abt. 22 Dusart A. C., 45, 335 iv., 632 Amidostyrolene C 6 H 4 .NH 2 .C 2 H 3 =1.4 V 76-81 Bernthsen & Bender B., 15, 1982 44, 70 From formorthotoluide B .... 153 Ladenburg B., 10, 1130 32, 754 Phenylacetamidine .... .... C 9 H 10 N 2 .... 116-117-5 .... A., 184, 327 Phenylacetamimide Ph.CH 2 .C(NH,,) I NH M ...* 83-89 Bernthsen B., 9, 429 30, 95 Azophenylethyl Ph.N : N.Et p, 175-185 p.d. MM Fischer & Ehrhard A., 199, 328 38, 243 Phenethylamine (of. B., 12, Ph.CH 2 .CH 2 .NH 2 C 8 H n N Carbonate ? 87-88 Bernthsen A., 184, 306 31, 617 1308, 1700) 11 n 11 M 87-88 Erlenmeyer & Lipp A., 219, 179 44, 993 .... Liquid Fileti G. I., 8, 446 ; 36, 719 B., 12, 297, 1308 193c. (757-8) Liquid Spica G. I., 9, 555 38, 242 Dimethylaniline C 6 H & .NM.ej 190 .... Ramsay 35, 472 n . 192 .... Briihl B., 9, 1368 31, 165 B 192 c. s. 0-5 Brunner and Bran- B., 11, 700 denburg j^ ... M 191-192 .... Hofmann B., 7, 523 27, 807 > 192-193 ... B., 10, 593 11 n 192 t. 0-5 C. N., 27, 1 ,, .... 192 a. b. Monnet, Reverdin, B., 11, 2278 36, 310 and Nolting B 192 .... Glaus and Howitz B., 17, 1324 46, 1006 M 192 .... Reinliardt & Stoedel B., 16, 29 44, 578 193 .... Kiirner G. I. [1881], 548; 42, 739 B., 15, 529 ,, 202 .... Lauth B. S. [2], 7, 448 Ethylaniline .... .... ... G 6 H 5 .NHEt Reinhardt & Staede: B., 16, 30 44, 578 " 1 1 of niann J., 2, 398 iv., 450 " !f 4 B., 7, 527 27, 807 " 205-210 Spiller P. R. S., 21, 204 vii.,73;26, Ethylamidobenzene 0,H 4 Et.NH,=1.2 210-211 .... Beilstein&Kuhlberg A., 156, 209 ; vi., 292, IK Z. C. [2], 5, 525 .... =1-4 M 213-214 ... *i 11 M i 11 212-216 Hofmann B., 7, 527 COMPOUNDS CONTAINING THREE ELEMENTS. 325 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methyltoluidine .... ,, .... .... ,, .... .... u .... .... C 6 H,.Me.NHMe=1.2 =1.3 = 1.4 C 6 H 4 Me(CH 2 .NH 2 ) 1.2 9 H U N )J 1) 1* 11 51 207-208 207 206-207 206-207 208 207-208 196 Liquid Liquid Liquid Monnet, Keverdin, and Nolting Eeinhardt& Sbedel Monnet, Eeverdin, and Nolting s Thomsen Glaus and Steinberg B., 11, 2279 B., 16, 30 B., 11, 2279 B., 11, 2281 B., 10, 1584 B., 16, 914 A 151 132 36, 310 44, 578 36, 311 H 34, 218 vl 113' Amidoxylene (xylidine) v 11 11 i) 11 55 11 V )5 11 U 11 51 V 11 51 11 11 *" 1 1J "" H '1 " 5 11 11 11 11 11 11 )1 11 15 11 11 )1 1 )1 Collidine .... (y-isopropylpyridine) (y-propylpyridme).... (a-isopropylpyridine) (propylpyridine) .... C 6 H 3 Me,.NH 2 = 1.2.4 M 11 =1.3.4 1' 71 11 11 " 11 > .)' 11 (0 (?) 11 1 =1.3.5 " )> = 1.3.2 = 1.4.3 11 11 = 11 1) 5' 11 )1 Jl 11 )! 11 Jl C 6 H 4 N.Pr0 C 5 H 4 N.Pr C 5 H 4 N.Pr0 C d H 4 N. Pi- 51 1 1) 11 11 11 ) t) 11 11 )1 11 Jl n 11 51 15 )5 11 )1 Jl H 11 15 11 U V 215 00 213-214 214-216 216 212 u. c. $1$ 212 212 212 204 ; 212 220-221 220-221 c. 216 c. G>fi)(\ ^991 &%\J &tZ-L 220-221 198-210 202-204 210-214 212-216 216 215-220 115-180 158 163 167 170 170 1. 20 49 Liquid ( isomeric? j 1. f. m. Liquid 1. 20 Liquid Liquid Wroblewsky Jacobsen Church Deumelandt Tawildarow Schmidt Wroblewsky Hofmann j> ilofmann & Martins Glaus Wroblewsky j Schmidt Schaumann Wroblewsky Hiibner Rosenstiehl Wallach Hofmann Hiibner Gahours and Etard Ladenburg and Schreder Ladenburg Ladenburg and Schreder Cahours and Etard A., 207, 98 ; B., 12, 1227 B. 17, 159 P. M. [4], 9, 455 Z. C. [1866], 22 Z. C., 13, 418 A., 193, 177 A., 207, 91 B., 9, 1295 B., 2, 378 B., 2, 412 B., 15, 318 B., 10, 1248 A. 207,95 A., 193, 179 B., 11, 1537 A., 207, 91 B., 10, 1710 A., 208, 321 A. C. [4], 26, 189 A., 173, 274 B.,5,714;P.K.S., 21,47 A., 210, 328 C. E., 92, 1079 B., 17, 1121 C. E., 98, 516 B., 17, 1122 C. E., 92, 1079 J., 14, 502 3d, 919 46, 737 v., 1059 vii., 1210 36, 157 40, 434 31,92 vii., 1209 j 34, 55 40, 433 36, 157 36, 52 40, 434 34, 143 85, 826 28, 350 25, 1023 ; vii., 58 42,504 46, 1048 46, 759 46, 1048 40, 826 y ,, y- 11 11 171 171 172 .... Kissling D. P., 244, 234 A., 215, 32 42, 1254 44, 83 y ,, 171-5 Vohl and Eulenberg A. P. [2], 147, 130 24, 1077 7. 15 \. 11 173 174 Ramsay Ladenburg C. E., 98, 516 35, 472 46, 759 177 179 (763) Wurtz C. E., 88, 940 36, 704 178 A., 215, 32 44, 83 178-180 Baeyer Z. C., 12, 689 179 J., 7, 490 i., 1082 179 Williams Chem. Gaz., 13, 179 180 309 B. S. [2], 32, 488 38, 481 180 Ghurch and Owen J., 13, 359 180 Coninck C. E., 91, 296 ; 40, 56, 612 180 Anderson B. S. [2], 35, 296 J., 10, 397 180-182 Kramer Z. C. [2], 6, 568 vii., 378, 478 178-183 Wurtz C. E., 95, 263 42, 1303 180 183 Coninck C. E., 95, 298 42, 1302 181 Tawildarow B., 6, 1459 27, 348 326 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. 0-G'ollidine .... C 8 H U N 195 Liquid Coninck C. E., 91, 296 ; 40, 56, 612 jS- 195-196 B. S. [2], 35, 296 R. T., 1, 132 ; 42, 1302 ; 44, J1 A. C., 5, 433 ; 220, 739 C. R., 95, 298 Aldehydocollidine (alde- .... JJ 175 .... Ador and Baeyer Z. C. [2], 14, 724 vi., 82 hydine) .... )) 179-180 Richard B. S. [2], 32, 488 38, 481 ?j Paracollidine .... .... J 179-182 220-230 .... Wurtz C. R., 95, 263 A., 155, 307 42, 1303 ? J> 198-208 Klinger B., 16, 946 Dimethylketine (Me.C.N : C.Me), C 8 H" 2 N 3 87 Treadwell B., 14, 1469 40, 895 J> "" """ i) J) 189 88 Gutkneeht B., 13, 1116 Dimethylphenylene diamine C 6 H 4 .NH 2 .NMe 2 =1.4 I) 257 c. 41 Wurster B., 12, 524 36, 627 JJ J J) 257 38-39 B., 12, 536 Diamidoxylene CeHjMe^NH^l.SAe J) .... 74-75 Hofmann B., 9, 1298 31, 93 = )) 99 Biedermann B., 9, 1670 31, 474 =1.4.2.5 JJ .... ISO Nietzky B., 13, 471 38, 553 JJ 152 Fittig and Ahrens A., 147, 15 vi., 1133 ] Base JJ C,H,,N 180-230 162 Liquid Schrotter Ladenburg B., 12, 1432 B., 12, 944 36, 733 ^S 13* 160-165 B., 13, 252 Hydrocollidine .... JJ jj SOS Liquid Cahours and Etard C. R., 92, 1079 40, 825 .... n 205 Etard C. R., 97, 1218 46, 4C4 .... jj 175-180 Liquid Hantzsch A., 215, 44 44,84 Alkaloid from putrefaction.... .... JJ 110 .... Gautier and Etard C. R., 94, 1598 44, 225 Ethenyldipropionimidine .... CEt:N.CMe.N:CEt.N i i C 8 H 13 N 3 .... 204 Pinner B., 16, 1661 44, 1099 Dimethyltriamidobenzene .... NMe 2 .NH 2 .NH 2 =1.3.4 JJ 298 42-44 Wurster & Sendtner B., 12, 1806 38, 110 Oxalpropy line C 3 H 2 EtN : NPr C 8 H 14 N 2 229-230 Liquid Wallach & Schulze B., 14, 423 40, 572 ,, .... .... JJ M 329-230 .... Wallach B., 15, 651 42, 821 j> 11 11 229-234 .... ?> B., 16, 543 Amyl glyoxaline C 3 H 3 N:NC 5 H n i> 240-245 .... u B., 15, 651 Heptylic cyanide C 7 H 16 .CN C 9 H I5 N 194-196 Liquid Felletan Z. C. [2], 4, C65 vi., 395, 525 (caprylonitril) Coniine (paraconiine) SeeC 9 H 17 N ) 163-5 (739) Wertheim A., 123, 157 ii., 964 (artificial) Et.CH : CH.N I CHPr- JJ 168-170 Schiff A., 166, 88 vii., 380 jj j JJ )> 168 B., 5, 43 25, 416 ,, MM J 168-169 160-180 Liquid Schorm Michael B., 14, 1767 B., 14, 2105 .... J) 187-5 .... Geijer ii., 3 JJ 189 212 Christison Ortiiora A., 42, 313 Base from conine .... JJ 158 J Hofmann B., 16, 559 ,, 44, 789 .... *> 173 .... JJ )J Hydrotropidine C 6 H 7 NMeEt JJ 167-169 .... Ladenburg B., 16, 1409 44, 1155 Isobutenylbutylidene amine 5J 145-147 Liquid Lipp B., 14, 1748 42, 165 Amylene guananime PrP.CH 2 .CH.C : NH C 3 H 15 N 5 .... 177-178 u. c. Bandrowski B., 9, 244 30, 191 C( : NH).NH.C( : NH)NH Amidocaprilonitril Coniine C 7 H 14 (NH 2 )CN See C 8 H 16 N C 8 H 16 N 2 CH,,N 168-171 Erlenmeyer & Sigel Blyth A., 177, 124 1, 345 28, 1014 ii., 3 ^^o-*- 1 -!? 170 J Petit G. J. C., 1877 Aldehydocollidine hexhydrid .... jj 165 Liquid Durkopf B., 17, 1131 46, 1054 jS-Collidine hexhydride C 6 H 8 MeEt.NH JJ 175-180 Coninck C. R., 98, 1438 46, 1048 Propyl piperidine C 6 H 10 N.Pr- JJ 149-150 .... Ladenburg B., 14, 1348 42, 535 JJ jj 147-151 j> B., 15, 1147 Iso- C 6 H 10 N.Prf JJ 149-150 ) B., 15, 1348 ?> Isoamylallylamine .... C 3 H 5 .NH.C S H J1 J) 148-153 Liebermann & Paal B., 16, 531 44, 909 Octylainine CH 3 .(CH 2 ) 7 .NH 2 C 8 H 19 N 185-187 .... Eichler B., 12, 1886 .... JJ M 175 172-175 Bouis Cahours A. C. [3], 44, 139 A., 92, 399 iv., 172 M COMPOUNDS CONTAINING THREE ELEMENTS. 327 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. C 8 H 19 N 171-174 Hofmann B., 15, 73 42, 1054 168-172 Pelouze & Cahours J. [1863], 529 iv., 172 Secondary 165 Jahn B., 8, 805 28, 1188 " 164 Squire 7, 108 iv., 172 u 162-5 Jahn B., 15, 1293 Dibutylamine .N .UfO.ti.oirr'On abt. 160 .... Lieben and Rossi A., 158, 175 24,523; vii., 222 Diisobutylamine NH.(CH 2 Pr) 2 120-122 .... Reimer Z. C. [2], 7, 26 24, 122 11 n 120-122 Hofmann B., 3, 757 vii., 222 11 135-137 u. c. .... Ladenburg B., 12, 949 36, 704 Methylethyl isoamylamine .... NMe.Et(C 5 H n ) 135 .... Hofmann 4, 317 ill., 1001 Diethyldiethylene diamiue .... (C 3 H 4 ) 2 :N 2 H 2 Et 2 C 8 H !0 N 2 185 .... J. [1859], 389 ii., 588 Tetrethyl tetrazone Et 2 N.N : N.N.Et 2 C 8 H 20 N 4 d. 135-140 1. -17 E. Fischer B., 11, 2209 36, 451 Tricyanobenzene (?) C 6 H 3 (CN) 3 C 9 H 3 N 3 (?) .... abt. 112 Woelz A., 168, 81 26, 1143 Cinnamonitril C,H 6 .CH:CH.CN C 9 H 7 N 254-255 11 Rossumo Z. C. [2], 2, 362 vi., 471 Quinoline (chinoline) .... 238 b. 20 Bromeis .... i., 870 n 11 .... 243 Butlerow and B. S. [2], 30, 26 34,988 Wischnegradsky 11 11 .... 227-228 u. c. Konigs B., 12, 98 36, 471 (710) I* 11 .... 229. Japp and Graham .... 39, 174 i. 11 227-230 u. c. .... Skraup W. A., 81, 593 40, 288 n 11 .... 233 Wischnegradsky B. S. [2], 34, 339 40, 444 n- .... 11 234-235 u.c.; Kretschy W. A., 83, 171 40,829 240-37- 241-33 c. (750-1) n 11 CH:CH.C.CH:CH 236-237(775) Coninck A. C., 5, 433; 44,739; 44,89 1 II 1 CH : CH.C.N : CH B.S.[2],37, 208 11 11 .... 236-237(775) 11 11 11 n 11 11 11 .... *i 228-230 42, 414 a- .... 238-25- .... Hoogewerff and v. R. T., 1, 1, 107 ; 44,89 239-25 Dorp B., 16, 425 ft- i. 11 (Leucoline) 239-25- .... 11 11 11 11 240-25(761) ft- 11 11 11 11 239 Hofmann A., 47, 79 n 11 .... n 233-237 Weidel and Hazara M. C., 3, 770 44, 223 - ,i ! .... 11 238-243 Williams J., 9, 533 a- 11 .... 11 237-1 (746-8) Skraup W. M., 1881 ! 11 .... 232-233 Baeyer and Skraup .... 42,414 11 11 .... 235-240 Jacobsen & Reimer B., 16, 1082 44, 922 11 11 .... 238-240 .... Wurtz C. R., 95, 263 42, 1303 a- .... 235-65 c. Friese B., 14, 2805 42,868 11 11 .... 228 Baeyer and Skraup .... 42, 414 11 >! .... 235-240 Hartley 41,47 Toluquinoxaline C ? H 3 Me.N:CH.CH:N= 1.3.4 C 9 H 8 N 2 243-244 u. c. L 10 Hinsberg B., 17, 321 46, 1053 o-Amidoquinoline C.ftN.NH., .... 66-67 Bedall and Fischer B., 14, 2573 o- .... 71-74 Konigs B., 12, 451 in- .... 109-110 B., 16, 725 P- >i 114 Coste B., 16, 671 44,811 Diazotoluene cyanide C 6 H 4 MeN : N.CN+HCN C 9 H 8 N 4 .... 77-5 Gabriel B., 12, 1639 38, 41 =1.4 Phenylpropionitril C 6 H 5 .CH 2 .CH 2 .CN C 9 H 9 N 253-5; 261 c. Liquid Hofmann B., 7, 520 27, 793 Methyl ketole NH Ce> H " .... 59 Baeyer and Jackson B., 13, 187 38, 395 11 11 " 11 MM 59 Jackson B., 14, 879 40, 734 Skatole 93-95 Briefer B., 10, 1030 34, 438 .... 11 11 93 n B., 12, 1985 38, 259 92-93 Salkowski B., 12, 652 11 11 .... 93-94 Baeyer B., 13, 2340 93 Fischer and German B., 16, 711 328 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Dihydroquinoline C 9 H 9 N 161 Hoffmann & Konigs B., 16, 728 44, 1143 u-Phenamidopropionitril NHPh.CHMe.CN C 9 H 10 N 2 .... 92 Tiemann & Stephan B., 15, 2034 44, 199 Ethylcyananilide Ph.NEt.CN (?) )I 271 .... .... A., 90, 94 Tolylamidoacetonitril C 6 H 4 Me.(NH.CH 2 .CN)=1.4 .... 126 Meyer B., 8, 1163 29, 402 Propenyl pheuylene diamine aH 4 NHC 3 H 6 :N=1.2 a. 360 168-5-169 Wundt B., 11, 829 34, 668 Ethenyltoluylene diamine ... C 6 H 3 Me.N : CMe.NH=1.2.4 5J .... 196-198 Ladenburg B., 8, 677 28, 1036 i) ji ) )> )> .... 198-199 Ladenburg and B., 12, 954 36, 716 Rugheirner .... 203 Hobrecker B., 5, 921 28, 1036 Auiliue + acetone Me 2 C:NPh C 9 H U N 200-220 Engler and Heine B., 6, 642 26, 1037 ,, Allyl aniline .... )> 11 220-230 208-209 .... Kramer & Grodzky Schiff B., 13, 1009 As., 3, 364 38, 802 Vinyl toluidine C 6 H 3 .Me.C 2 H 3 .NH 3 )> 189-191 Wurtz C. R., 68, 1504 vi., 1105 Tetrahydroquinoline .... )J 241-242 u. c. Friedliinder and B., 15, 335 Ostermaier .... 244 u. c. .... Konigs B., 14, 101 )i .... ) '244-246 (724) s. very low Hoffmann & Kouigs B., 16, 729 44, 1143 temp. j " .... )) 244 Liquid Coninck C. R., 94, 87 42, 414 .... ) 244 .... Wischnegradsky B. S., [2], 34, 339 40, 444 ) "* .... )) 210-215 Liquid Coninck C. B., 94, 87 42, 414 ) .... )J 212-213 Liquid jj > )j Acetonephenyl hydrazine ... Ph.N 2 H : CMe 2 C 9 H 12 N 2 165 (91) Liquid Reiseneggir B., 16, 662 Ethenyltolylamidine C 6 H 4 Me.NH.CMe : NH=1.4 .... 95-5-96 Bernthsen and B., 11, 1757 36, 147 Trompeter Ethenyldiamidotoluene C 6 H 3 Me.NH.C 2 H 4 .NH i i I) .... 203 Hobrecker B., 5, 921 26, 174 Tetrahydroquinoline hydra- C 9 H 10 N : NH 2 > 255 p. d. 55-56 Hoffmann & Konigs B., 16, 730 44, 1143 zine ? cf. M.C. 3, 705 c 16 n ls N 4 ? )) 266 Lippmann & Lange B., 13, 2137 40, 161 Hydrocyanaldine N.(CH.Me.CN)s C H 12 N 4 .... 115 Passavant A., 200, 132 38, 313 Parahydrocyanaldine .... (C 9 H 12 N 4 ). .... 230-232 A., 200, 135 >i Propylaniline C 6 H 5 .NHPr C 9 H 13 N 213-214 Liquid Claua and Eoquea B., 16, 912 Methylethylaniline 6 H 5 .NMeEt )> 201 u. c. Liquid Claus and Howitz B., 17, 1325 46, 1005 Dimethyltoluidine C 6 H 4 Me.NMe 2 =1.2 51 183 Liquid Thomsen B., 10, 1587 34, 218 )> )) I 183 .... Keinhardt&Stfedel B., 16, 30 44, 578 )> n 182-18^ .... Mounet Riverdin, B., 11, 2279 36,311 aud Nolting ,, .... .... > jj 186 L 10 Hofmann B., 5, 711 vii.,58;25,1022 =1.3 j> 205 L 10 B., 5, 710 ) > )> 206-208 .... Monnet, Biverdin, B., 11, 2280 36, 311 and Nolting ,, M jj 215 Wurster aud Riede' B., 12, 1797 11 = 1.4 206-208 Monnet, Riverdin, B., 11, 2281 36, 311 and Nolting ,, .... 11 j) 207-208 L 10 Hofmann B., 5, 707 25,1022; vii., 58 j> .... )> n 208 Thomsen B., 10, 1586 34, 218 it j j) 208 Beinhardt & Stsedel B., 16, 31 44, 578 209 ; 205 7 210 Claus and Steinberg B., 16, 915 ) ' j> 210 .... Hofmann B., 5, 707 25,1022; vii., 58 Ethyltoluidine C 6 H 4 Me.NHEt=1.2 > 213-214 Reinhardt&Stedel B., 16, 31 44, 578 .... =1.3 158-159 Liquid Wroblewsky B., 7, 1681 28, 455 j .... ... =1.4 j 217 .... Morly and Abel 7,68 i,, 576 Araidopropyl benzene C 6 H 4 Pr.NH 2 =1.4 2%4-326 Liquid Louis B., 16, 107 >i ,, (?) j> 225-226 .... Hofmann B., 13, 1730 Amidoisopropyl benzene C 6 H 4 .PANH 2 =1.4 216-218 Liquid Louis B., 16, 111 (cumidine) = i) 225 .... Nicholson A., 65, 58 1, 2; ii., 174 Amidoethyltoluene C 6 H 3 .NH 2 .Me.Et=1.2 ? 229-230 Liquid Benz B., 15, 1650 42, 1284 Amidotrimethyl benzene C 6 H 3 .Me 3 .NH 2 =1.3.4.6 )) .... 62 Schaper Z. C. [2], 3, 12 (pseudocumidiue) COMPOUNDS CONTAINING THREE ELEMENTS. 329 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. . Watts' Diet. & J. Ch. Soc. Auiidotrimethyl benzene (pseudocumidiue) H (mesidine) ,j )> 1! " " 11 C 6 H 3 .Me 3 .NH 2 =1.3.4.6 =1.3.5.6 )> n ! )) C,H U N H ) ' ) ' )) 234-235 226-237 227 225-227 225-227 187 188 63 1.15 Liquid b. Hofmann Ladenburg Biedermann and Ledoux Fittig aiid Storer Hofmann Eisenberg Vohl & Eulenberg B., 15, 2895 B., 7, 1136 B., 8, 58 A., 147, 3 B., 5, 704 ; 8, 61 B., 15, 1 A P [2] 147 130 44,324 28,64 28, 569 vi., 300 25,1023; vii.,58 24, 1077 188 J 14 502 ii- (from Dippel's oil) .... n 188 188 .... Coninck C. R, 91, 296 D P 244, 234 40,56, 42, 1254 188 M. C , 4, 708 46, 172 (?) L u 193-195 c. 198 200 M. C., 3, 695 M C 4 708 44, 39 46, 172 (3- (from ciiichouine) Trimethyldiamidobenzene .... Dimethyldiamidotoluene .... Diamidocuruene Diamidomesitylene C 6 H 4 .NMe 2 .NHMe=1.4 C 6 H s Me.NMe 2 .NH 2 =1.3.? C 6 H 3 Pr0.(NH 2 ) 2 M%.(NBy*i:lA5.4.fl C 9 H U N 2 ) )) ) 220 265 . 204-205 Liquid 28 47 90 jj Coninck Wurster & Schobig Wurster & Riedel Hofmann Fittig C. R, 91, 296 B., 12, 1810 B., 12, 1801 C. R, 55, 781 A., 141, 134 J p [2] 26 338 46, 56 38, 111 38, 109 vi., 516 vi., 300 44, 352 204-205 J p [2] 22 280 40, 55 Dehydrotriacetonamine (CH S ' CH CH 2 ) 3 N 9 H 16 N 158 \ 150 151 A., 174, 166 ; 183, 276 B 12 2054 38, 99 155 A 214 151 44, 13 Isoamylpyrroline Trimethyltriamidobenzene .... C^NAH,, C 6 H 3 .NMe 2 .NHMe.NH 2 C 9 S 15 N 3 180-184 294 280 p d 90 190 Bell Wurster & Schobig Frankland & Kolbe B., 10, 1866 B., 12, 1813 A 65 281 36, 525 38, 111 ii., 189 )l IflO J p [2] 2 261 40 54 Glyoxalisocenanthyline Oxalethylisoamyline Pelargono-nitril Iso Dipropylallylamine Ethylhexhydroethylpyridine Nonylamine C 3 H 2 (C 6 H 13 )N:MH CfSnEtN, C 8 H 17 .CN n NPr 2 .C 3 H 5 C 5 H 9 Et I NEt C 9 H 19 NH 2 C 9 H 16 N 2 C 9 H 17 N J) 9 H 19 N J) C H N 224-225 (743) 214-216 206 145-150 175 195 84 Liquid Liquid Liquid Eadziszewsky Pvadziszewsky & Szul Eichler Felletas Liebermann & Paal Wischnegradsky B., 16, 748 B., 17, 1294 B., 12, 1888 Z. C. [2], 4, 665 ; J., 21, 634 B., 16, 527 B. S. [2], 34, 339 ; B., 13, 2401 B 15 773 44, 1087 46, 986 38, 230 vi., 525 44, 909 40, 444 42, 1054 190 192 J , 16, 529 iv., 134 Tripropylamine Diethylisoamylamine Cyanoquinoline )> .... .... ji * Xylyldicyanide j, Dicyanoxylene Dipvridvl NPr 3 NEt 2 (C 5 H n ) C,H 6 N.CN=1.2 =1.3 = 1.4 C 6 H 4 .(CH 2 .CN) 2 =1.2 = 1.4 C 6 H,Me s .(CN) 3 =1.4.?.? see C, n H,JSL j C 10 H 6 N 2 )) )1 10 H 8 N 2 )1 ) 144-146 156-5 154 360 149 '5 Liquid Liquid Liquid 87-88 131 59-60 88-90 98 Koemer Zander Hofmann Coste Bedall and Fischer Bedall& O.Fischer Fischer &Willmacli Baeyer and Pape Biedermann Klippert Skraup & Vortmann B., 6, 1101 A., 214, 171 4, 315 B., 15, 196 B., 15, 684, 1980 B., 14, 2574 B., 17, 440 B., 17, 447 B., 5, 703 B., 9, 1767 M. C., 3, 370 27,39 ii., 560 48, 413 46, 1051 46, 898 25, 1013 31, 468 44, 88 287 289 u c M. C., 3, 599 304'8c (760)- 114 u c Weidel and liusso M. C., 3, 856 44, 483 7- +2H 2 a-Naphthylamine j) .... C 10 H 7 .NH S ) J 1 )J C 10 U 9 N 2 i> )i 293 (743) abt. 800 300 73 49 49-5 49-50 00 50 50 !! Jacobsen Liebermann Mainzer Benz Zinin Bechamp Ballo B., 14, 1793 A., 183, 265 B., 15, 1415 B., 16, 14 A., 44, 283 A., 92, 402 B., 3, 675 31, 600 iv., 20 330 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. n-Naphthylamine .... C 10 H 9 N .... 50 Palm B., 9, 499 30, 206 .... )) 50 Smith .... 32, 563 /3- .... .... 112 Calm B., 15, 610 42, 972 ,> .... n .... 112 Liebermann A., 183, 264 31, 606 >i .... .... 112 Benz B., 16, 9 .... si 112 Liebermann and B., 8, 1110 20, 403 Schieding .... .... .... .... 112 Merz and Weith B., 13, 1301 w * .... .... ) .... 112 Cosiner B., 14, 58 TJ .... .... .... 11 .... 112 Smith .... 32, 563 ? 294 .... Eiehter Tabellen Phenylpyrroline CH : CH.CH : CH.NPh 1 1 ^ .... 62 Kottnitz J. p. [2], 6, 148 26, 164 Lepidine jj 266-271 .... Williams J., 9, 536 iii., 572 > .... > 256-258 .... Hooge werff & v. Dorp B., 13, 1639 40, 110 Idrioline .... 252-257 .... J. [1856], 536; iii., 572 [1863], 431 o-Methylquinoline (chinal- C 9 H 6 MeN ) 236 .... Skraup B., 15, 897 42, 1111 dine) >? 238-239 (716) Liquid Drebner and Miller B., 14, 2814 42, 868 ?. ji t) abt. 240 .... Korner G. I. [1881], 548 42, 739 >. n )i 240 Liquid .... D. P., 250, 533 46, 756 o- ,, .. J 240 .... Meister and Lucius B., 16, 982 1. D 240 Liquid Drewsen B., 16, 1955 44, 1149 ?. n j 240-241 .... Jacobsen & Eeimer B., 16, 1084 P- ,> 1 ii 245 .... Skraup B., 15, 897 42, 1111 J. n 246-247 Wallach & Wiisten B., 16, 2008 44, 1097 o- (toluquino- jj 247-S-248-3c. .... Skraup M. G, 3, 381 4S, 1217 Hne) (751-3) o- i. ) i) 248 Liquid W. A., 83, 434 40, 920 m - ,. ,, > 252 .... n B., 15, 893 42, 1111 m- )T 259-7 c. (747) Liquid j M. C., 3, 381 42, 1217 P- V ) 257-258 j> W. A., 83, 434 40, 920 P- >, 1> > S5r-4-258-6 j) M. G, 3, 381 42, 1217 (745) Cincholepidine .... |j 258-6 c. Weidel M. G, 3, 76 42, 533 Benzylglyoxaline .... .... C 3 H 3 N : N.CH 2 Ph C 10 H 10 N 2 310 70-71 Wallach B., 16, 539 44, 911 Carboallylphenylamide .... .... 105 .... J. [1861], 498 Diamidonaphthalene C 10 H 6 (NH 2 ) 2 = ai ; a. M 189-5 Aguiar B., 7, 306 27, 699 )5 > .... 186 Lellmann B., 17, 110 46, 751 = ? ) .... 175 Hollemann Z. C. [2], 1, 556 vi., 863 > j .... 160 Zinin J. p., 33, 29 v., 233 ^a^ ; )j .... 120 Griess B., 15, 2192 44, 183 !) =a,0, ; l .... 95 j B., 15, 2193 >j =aj ; a ; See C 10 H 8 N 2 1 .... 66-5 108 Aiguar Anderson B., 7, 309 A., 154, 274 27, 699; 44, 183 vi., 977 i 286-290 u. c. M. G, 3, 880 Tsodipyridine .... 1* >1 295-305 ; 1. f. m. Ramsay P. M. [5], 6, 29 36, 264 145-155(i.v.) 274-275 1. 20 Cahours and Etard C. R., 90, 275 38, 672 Ainidolepidine )j )) 71-74 Kosnigs B., 12, 451 36, 540 Propylbenzonitril C 6 H 4 .Pr.CN =1.4 1 227 Liquid Francksen B., 17, 1229 46, 1(109 Isopropylbenzonitril (cumo- C 6 H 4 .Pr/.CN =1.4 C 10 H n N 239 .... Hermann J., 1, 595 ii., 181 nitril) Base from nicotine .... ii 250-270 .... Laiblin A., 196, 179 36, 809 a-Phenamidoisobutyronitril NHPh.CMe 2 .CN ^ioH 12 N 2 93-94 Tiemann B., 15, 2040 44, 199 d-Toluamidopropionitril Me.(NH.CHMe.CK) =1.2 ji .... 72-73 Tiemann & Stepfan B., 15, 2038 5> a- =1.4 MM 81-82 ) B., 15, 2037 5 Amidocumonitril C 6 H 3 .Pr.NH 2 .CN M abt. 305 abt. 45 Czumpelik B., 2, 184 ; Z. C. vi., 516 [2], 5, 437 COMPOUNDS CONTAINING THREE ELEMENTS. 331 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Ethylquinazole CH : CH.C.CH.CH 2 C 10 H 12 N 2 234-235 30 Fischer and Kuzel B., 16, 655 44,812 1 B \ 1 (741) CH : CH.C.NEtN Tetrahydromethyl quinoline C 6 H 4 .(CH 2 ),.CHMe.NH i " " i C 10 H 13 N 243-246 Liquid Jackson B., 14, 889 40, 742 11 11 11 H 246-S4S Liquid Doebner and Miller R, 16, 2467 46, 183 (709) 11 u 11 242-244 Liquid Hoffmann & Konigs B., 16, 732 44, 1144 (720) Acetophenone dimethylhy- Me^CPhMe C 10 H 14 N 2 165 (190) Liquid Eeisenegger B., 16, 663 44,798 drazine Camphoric nitril C 8 H 14 (CN) 2 u sb. 125-130 Solid Ballo B., 12, 328 36, 540 250 1. 10 Barral iv., 45 .... " Landolt G. J. C., 1877 (745) 240-242 u. c. .... Lieblin B., 10, 2136 84,432 244 Etard C. R., 97, 1218 46, 464 '.'.". 11 242 I Kissling D. P., 244, 234 42, 1254 Isonicotine . .. .... _ a. 360 78 u. c. Weidel and Eusso M. C., 3, 867 DiethylaniHne C 6 H 6 .NEt 2 C ]0 H 15 N 211-211-5 .... Reinhardt & Stsedel B., 16, 30 44,578 (745-4) 213-5 .... Hofmann A., 74, 135 iv., 451 Isobutylaniline C 6 H 5 .NH(CH 2 .CHMe 2 ) 242 Liquid Giannetti G.I. [1882], 266; 42, 1059 B., 15, 1759 Amidoisobutyl benzene C 6 H 4 .C 4 H 9 .NH 2 280 Liquid Studer B., 14, 1472 40,898 11 11 230-232 Liquid Louis B., 16, 115 Dimethylxylidine C,H 3 Me 2 .NMe 2 = i 11 196 .... Hofmann B., 5, 712 vii., 58 ; 25, 1022 11 = * ( , 203 .... B., 5, 714 11 11 =1.2. ? 200-202 Liquid Baur and Stsedel B., 16, 32 44, 579 ,, = 1.3.4 203-205 Liquid 11 11 11 )) H MM 87 Sesemann B., 6, 446 26, 912 Amido-cymene (cymidine) .... C 6 H 3 .Me.Pr.NH 2 = 1 280 p. d. Eossi C. R.,51, 270 ii., 298 11 yj 250 .... Barton P. M. [4], 10, 454 ii., 297 11 11 = 1.3. ? 11 232 Liquid Kelbe and Warth A, 22J, 157 46, 46 Methylpseudocumidine Me :1 .NHMe =1.3.4.6 a 237 44 Hofmaun B., 1:5, 2896 44,324 Camphoroxime anhydride .... C 9 H 15 : c : N i i 216-218 Liquid Na'geli B., 16j 2982 46,610 Coridine n 211 Thenius J., 14, 502 .... 11 211 .... Kissling D. P., 244, 234 42, 1254 211 Vohl & Eulenberg A. P. [2], 147, 130 24, 1077 '1 Base H 210-215 .... Klinger B., 16, 946 Tetramethyl diamidobenzene C 6 H 4 (NMe 2 ) 2 =1.3 C 10 H 16 N 2 256 c. Liquid Wurster and Morley B., 12, 1814 38, 111 11 u =1.4 M 260 c. 51 Wurster B., 12, 526 36, 627 Amidodiethyl aniline C 6 H 4 NH 2 .NEt 2 =1.4 260-262 u. c. Liquid Lippmann and B., 16, 1425 ; 44, 869, 1100 Fleissner M. C., 4, 284 Diethylketine .... i! 215-217 c. Liquid Treadwell B., 14, 1463 40, 895 Hydronicotine ; , 263-264 Liquid Etard C. R., 97, 1218 46, 464 Amylhydropyridine C ln H, ; N 201-203 Hofmaun B., 14, 1501 40, 921 Imidoisovaleronitril NH(CHPr0.CN) 2 C 10 H,X .... 52 Lipp A., 205, 23 ; B., 40,85 13, 907 Methylcyanthine C 6 H 3 .NMe,(NH)(NHMe) i; 257-258 74 Meyer J. p. [2], 26, 343 44, 352 Oxalpropylisoamyline C-HnPraNij C 10 H 18 N 2 239-242 (738) Liquid Eadziszewsky & Szul B., 17, 1295 46, 986 Dipiperyl tetrazone C 5 H 10 N.N:N.NC 5 H 10 C 10 H 20 N 4 45 Knorr B., 15, 861 42, 1115 11 11 \*) .... 58 Schotten B., 15, 425 Dimethylconine C 8 H 15 Me : NMe C 10 H 21 N 182 Liquid Hofmann B., 14, 709 40, 745 Isoamyl piperidine CVH^IN.CsH,, 186 .... Cahours A. C. [3], 38, 99 iv., 657 u 11 188 .... Schotten B., 15, 421 42,982 From menthol C 10 H 19 .NH., _ 185-190 Moriya .... 39, 78 Diamylamine (C 5 H U ) 2 NH C^H^N abt. 176 Hofman P. T. [1851], 357 i., 207 JJ 11 178-180 .... Silva Z. C., 10, 157 " 11 180 Cuter B., 12, 1333 36, 914 2 u 2 332 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diamylamine (active) (C 5 H n ) 2 NH C^H^N 182-184 u. c. .... Plimpton C. R., 92, 882 39, 335 > 1) 185 .... 11 C. R., 91, 433 40, 34 (inactive) )1 1) 185-186 u. c. 11 .... 40, 332 i ) 11 186-187 .... u 40, 335 185-187 Bell B., 10, 1867 11 ) 187 Ouster B., 12, 1333 36, 914 Diethylenetriethyltriamine.... (0 2 H 4 ) 2 N 3 H. ) Et 3 C 10 iN 3 220-250 Hofmann J. [1861], 517 ii., 591 a-Naphthylcyanide (naph- C 10 H 7 .CN C,,H 7 N 296-5 c. 35-5 Hofmann B., 1, 39 vi., 528 thonitril) 11 11 ") 297-298 c. -37-5 Merz & Muhlhausei Z. C. [2], 5, 71 vi., 847 a- i )> )1 37 Liebennann A., 183, 225 31, C07 11 11 >1 1> 280-290 Mixture Graeff B., 14, 1062 10, r-2-2 11 11 T* 1) 804-305 c. 66-5 Merz & Muhlhauser Z. C. [2], 570 i 259-261 55 Jacobsen & Eeimer B., 16, 2603 46, 335 P- 11 ii ') J .... 59-60 D. P., 250, 533 46, 757 P- ,. >i 1 1> 266-267 60 Doebner and Miller B., 16, 2470 46, 184 m- 11 11 1 264-265 61 11 11 B.. 16, 2471 11 Cryptidine .... .... .... 270 Jjiquid Leeds B., 16, 289 44, 669 274 J. [1856], 537 Dispoline i 282-304 ^V^illiams Laboratory, 109 vi., 546 Menaphthylamine C U H 9 .NH 2 V 290-293 I Hofmann B.. 1, 100 vi., 814 Dimethylamidoquinoliue C 9 H 6 N.NMe 2 = 0l ; /3 ; C,,H 12 N 3 335 54-56 Coste B., 16, 672 44, 811 Isobutylbenzonitril C 6 H 4 .C 4 H 9 .CN =1.4 " C U H 13 N 238 1. -15 Pahl B., 17, 1237 46, 1010 Ethenylethyltoluylenamidine .... C U H 14 N S .... 93 c. .... A., 210, 351 Amylidene aniline , Ph.N:o 5 H 10 C U H 15 N 97 d. Lipmann & Strecker B., 12, 74 36, 462 ii 11 .,,. 11 )) 97 U i! W. A., 78, 247 36, 714 Ethyl allyl aniline Ph.NEt.C 3 H 5 220-225 Schiff As., 3, 365 iv., 452 Pheuylangelamide .... .... > .... 128 Perkin 31, 394 Methyl hydroquinaldine C 10 H 12 MeN 245-248 (708) Liquid Doebner and Miller B., 16, 2468 46, 184 Hydro-o-methyl quinaldine > 1) 260-262 Liquid t! 11 11 11 -p* )> 11 11 11 267 Liquid 11 11 11 11 Ethyltetrahydroquinoline .... C 9 H 10 EtN 11 255 Liquid Wischnegradsky B., 13, 2400 )> 1 11 254-258 p.d. Liquid Claus and Stegelitz B., 17, 1329 46, 1051 Diazobenzene piperidine Ph.N : N.N : c 5 H 10 C,,H 15 N 3 .... 41 Baeyer and Jaeger B., 8, 893 20, 273 Benzyldiethylamine PhCH 2 .NEt 2 C U H 17 N 211-212 c. Meyer B., 10, 310 32, 190 it ) 11 209 Liquid Ladenburg & Struve B., 10, 47 Isoamylaniline C 6 H 5 .NH.C 5 H,, 1 258 Liquid Hofmann A., 74, 153 iv., 450 ; 3, 21)7 Amidoisoamylbenzene C 6 H 4 .C 5 H,,.NH 2 il 255-258 .... Calm B., 15, 1643 ,, )) i abt. 260 Liquid Merz and Weith B., 14, 2346 I* 11 Tl 260-265 Liquid Hofmann B., 7, 529 27, 807 Diethyltoluidine C 6 H 4 .Me.NEt 2 =1.2 1) 208-209 (755) Reinhardt & Stsedel B., 16, 31 44, 578 = 1.4 )1 229 Morley and Abel A., 93, 315 i., 576 ii .... .... !) 1> 227-228 Eeinhardt & Stsedel B., 16, 31 Dimethylamidopropyl ben- C 6 H 4 .Pr.NMe :: =1.4 11 230 u. c. Liquid Claus and Howitz B., 17, 1327 46, 1006 zene Dimethylmesidine Me 3 .NMe 2 =1.3.5.6 11 213-214 Hofmann B., 5, 718 vii., 58 11 i> ii 11 225-245 Hofmann & Martins B., 5, 747 25, 1023 Dimethyl pseudocumidine .... =1.3.4.6 ,, 222 Liquid Hofmann B., 15, 2895 44, 324 9fUl Thenius J., 14, 502 v., 127 1) rSOIS 90A Kissling D. P., 244, 234 42, 1254 1) Zow 7*?n Vohl & Euleuberg A.P. [2], 147, 130 24, 1077 Tetramethyldiaraidotoluene C f H 3 Me(NMe 2 ) 2 C n H 13 N 2 BvV 260 Liquid Wursterand Iliedel B., 12, 1802 38, 109 Ethylcyanethine C 6 H 3 .NMe 3 .(NH)(NHEt) CnH 19 N 3 259-261 45 Meyer J. p. [-2], 26, 345 44, 353 Oxalisobutylisoamyline C 7 H n Bu0N 2 C u H io N 2 238-242 (742) Liquid lladzisze\vsky& Szul B., 17, 1295 46, 986 COMPOUNDS CONTAINING THREE ELEMENTS. 333 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J.Ch. Soc. Methylisoamyl pipeiidine ... C 5 H 9 MeN.C 6 H u CnH^N 190-193 Liquid Schotten B., 15, 422- 42, 982 -Dieyanonaphthalene .... C 12 H 6 N 2 170 Darmstadter and Z. C. [2], 5, 571 vi., 848 Wichelhaus y- .... 204 )! t! 8-. i .... 236 n 17- i, .... .... 262 )> )! n 0- ,1 .... ) .... 267-268 Ebert and Merz B., 9, 604 30, 409 /3- .... >i .... 296-297 i ) _ | Azophenylene C 6 H 4 .N.C 6 H 4 .N C 12 H 8 N 2 .... 170-171 Glaus and Basenack B., 5, 367 vii., 121 , i H 1 171 Claus and Pfeifer B., 5, 611 25, 694, 896 i .... ... n a. 360 171 Glaus & Heusinger B., 8, 39, 600 28, 647 i *" 172-174 Skraup B., 15, 896 42, 1112 11 .... 171 Claus B., 15, 2332 Phenauthroline C:N.C:C.O.N:C m. a. 360 78-78-5 Skraup & Vortmann M. C., 3, 570 44, 86 1 ^ II 1 c:cc:c.c.c:c "" i m. a. 360 79 Skraup B., 15, 895 42, 1111 + 2H,0 .... 11 >i 65-5 Skraup & Vortmann M. C., 3, 570 44,86 * > 11 11 .... 66 Skraup B., 15, 895 42, 1111 Tetrazodiphenylimide .... C 12 H 3 N 6 127 Griess P. T. [1864], 719 iv., 412 Diphenylimide (carbazole) .... C 6 H 4 .NH.C 6 H 4 C )2 H 9 N 8S8 238 Grsebe and Glaser B., 5, 13 vii., 254; 25, 30^ !> 1J 11 238 Braun and Greiff B., 5, 277 25, 502 11 11 354 .... Grabe B., 7, 1630 28, 455 a-Naphthylacetonitril C 10 H 7 .CH 2 .CN 11 a. 300 Liquid Bnessneek B., 16, 642 44,808 Acridine (cf. B., 13, 102) .... CH:CH.C. N:CH 11 a. 360 107 Grsebe and Caro A., 157, 159 24, 145, 708 1 II 1 CH:C. c. C:CH / I CH.CH:CH a. 360 107 A. 158 265 vii., 24 ,, .... V 11 110-111 1 5 Fischer and Korner B., 17, 102 46, 748 From ciuchonine .... 1 .... 192 Konigs B., 12, 99 36, 472 C.H.N : N O.H, C, ,H, n N, 293 65 P. W. Hofmann A., 115, 364 i., 478 v> 6 5 >v 6 5 **U TB* 1 2 293 65 Mitcherlich A 9 , T 11 65 Kerr -" m P. M. [5], 13, 255 * 11 66 Leeds B., 14, 1384 42, 502 1i 66'5 Glaser G. J. C., 1867 11 293 Ramsay 35, 472 ji j) 68 Griess B., 9, 134 29, 933 68 Schmidt & Schultz B., 12, 486 36, 631 Diphenylamine (phenylani- NHPlu C, 2 H H N 310 45 Hofmann A., 132, 164 iv., 453 line) 11 *> 11 1 53 Grsebe B., 7, 49 27, 481 ,, i 11 11 54 Merz and Weith B., 6, 1511 vii., 944; 26, 74 11 " 11 11 297-298 u.c. 54 i B., 13, 1298 >' 1> 1 310 54 Weith B., 7, 849 27, 1171 11 .... ...- 11 11 54 Kerr P. M. [5], 13, 255 ., .... .... H 11 .... 55 Witt B., 10, 1309 34, 54 11 11 310 Solid De Laire, Girard, B. S. [2], 7, 360 vi., 922 and Chapoteaut n 1) 11 310 .... Ramsay , 35,472 Amidodiphenyl C 6 H 5 .C 6 H 4 .NH 2 =l-2 11 44-45 Luddens B., 8, 872 28, 1258 )) a. 320 45 Hofmann P. R. S., 12, 389 v., 1054 ,, = 1.4 11 48-49 Osten B., 7, 171 vii., 937; 27, 580 )> )1 49 Luddens B., 8, 872 28, 1258 ,, .... .... )T .... 49-50 Schultz B., 7, 53 vii., 937; 27,4(58 v .... J 11 1) 322 .... Richter Tabellen Diazoamidobenzene ,. Ph.N : N.NHPh C 13 H n N 3 .... 91 Griess A., 121, 258 iv., 460 Amidoazobenzene Ph.N:N.C 6 H 4 .NH 2 =1.4 11 a. 360 123 .... A., 127, 346 ,, .... .... *> 11 .... 125-126 Witt and Thomas B., 16, 1102 43, 114 ,, .... )) 11 127 Sarauw B., 14, :>443 42, 507 11 ' )> 1 11 a. 350 107-4 Schmidt Z. C. [2], 5,417 vi., 271 334 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Amidoazobenzene .... Ph.N : N.C 6 H 4 .NH 2 =1.4 C 12 H U N 3 .... 130 Martius and Griess Z. C. [2], 1, 132 vi., 271 Hydrazobenzene .... ' { ''. C 6 H 5 .NH.NH.C 6 H S C 12 H 13 N 2 .... 131 Schmidt & Schultz B., 12, 486 36, 631 n .... 131 Hofmann P. R. S. 12, 176 vi.,271 Diphenyl hydrazine N 2 H 2 Ph 2 ii 1. 17 Fischer A., 190, 174 34, 313 Amidodiphenylamine Ph.NH.C 6 H 4 .NH 2 =1.4 61 Nietzki and Witt B., 12, 1401 a-Diamidodiphenyl (benzi- NH 2 .C 6 H 4 .C 6 H 4 .NH i =(l .4),, 122 Wald B., 10, 139 32, 341 dine) " 11 11 ii 11 n far a. 360 ttf Schmidt & Schultz B., 12, 487 36, 652 " 11 11 .... 118 Fittig A., 124, 275 iv.,411 11 11 11 11 u 118 Zinin A., 85, 328 i., 545 i- (dipheny- ,, l.^jl.- .... 53 Schultz B., 9, 548 30, 197 line) 8 ' 11 ii ii ii 11 363 45 Schmidt & Schultz B., 11, 1754 36, 252 *" n ii ii ii ii 363 45 ii B., 12, 487 36, 652 11 n 11 ii 363 45 Schmidt, Schultz, A., 207, 354 and Strasser /3-Diamidodipheuyl C 1S H 8 .(NH 2 ) 2 =? 363 Liquid Schmidt & Schultz A., 207, 320 40,910 P~ j, .... .... ii 11 i a. 360 Liquid Strasser & Schultz A., 210, 193 42, 521 Ethenyl-a-naphthylamidine Me.C(NH).NHC 10 H 7 .... s. 15 Bernthsen and B., 11, 1758 36, 147 Trompetter Diamidoazobenzene (chryso'i- PH.N : N.C 6 H 3 (NH 3 ) 2 =1.2.4 C 12 H 12 N 4 .... 110 Hofmaun B., 10, 213, 388 32, 326 dine) 11 1> J .... 117-5 Witt B., 10, 656 32, 457 (azoani- NH 2 .C 6 H 4 .N 2 .C C H 4 .NH 2 235-240 Mixter A. C. J., 5, 282 46, 666 line) =(1.4), Dimethyl-a-naphtbylamine.... C IO H 7 .NMe 2 C 12 H 13 N 267 Liquid Landshoff B., 11, 643 34, 587 n -- ii 1) 267 .... Hantzsch B., 13, 1348 )) "/"" )J B 305 46 B., 13, 2054 40, 177 Hydrocarbazol .... J? 325-330 120 A., 163, 358 Dimethylquinaldine , C 10 H 7 Me 2 N .... 69-70 Bereud B., 17, 653 46, 1053 Diaraidodiphenylamine NH(C 6 H 4 .NH 2 ) 2 =(1.4) 2 C^H^N, 155 Nietzki B., 11, 1098 34, 792 ii .... i> 158 Nietzki and Witt B., 12, 1402 11 ii 11 .. 158 Nietzki B., 16, 474 Triamidoazobenzene N 2 :C 12 H 7 (NH 2 ) 3 C 12 H 18 N 5 .... 137 .... Z. C. [1867], 278 Paraniline C 12 H 14 N 2 192 J. [1862], 343 Dipicoline (parapicoline) C 6 H 7 N.C 6 H 7 N (?) 260-315 .... Anderson A., 60, 86 iv., 354, 63!) 11 ii .... 310-320 ; Liquid Ramsay P. M. [5], 6, 31 36, 265 165-175(i.v.) Hydrazoaniline NH 2 .C 6 H < .(NH) 2 .C 6 H 4 .NH 2 U 12 H 14 N 4 .... 140+ .... A., 135, 162 vi., 703 145 Lermontotf B., 5, 233 Diallylamine .... NH(C H ) C 12 H r N "" Zander A., 214, 149 44, 13 Carbazoline .... 6 7 1 286 96 Greebe and Glaser B., 5, 14 vii., 254 ; 25 " 302 .... .... 296-297 c. 99 .... A., 163, 352 Anhydrovaleryl diamido- C 6 H 3 Me.N : C(C 4 H 9 )NH i j C 12 H 16 N 2 .... 145-146 u. c. Friederici R, 11, 1974 36, 312 toluene 11 ii 11 M 145 Hiibner A., 209, 365 48, 180 Benzylidene piperylhydrazine C 6 H 10 N 2 .CHPh n .... 2 a. 150 Lipp B., 14, 1747 Ethylene dipiperidyldiamine (C 5 H 10 ) 2 .C 2 H 4 .N 2 ft 263 4 Briihl B., 4, 739 24, 1063 Tricrotonylenamine (C 4 H 6 ) 3 N 2 H 6 C 12 H 24 N, 190 (40) Wurtz C. E., 88, 1154 36, 780 Tributylamine N(CH 2 .CH 2 .CH 2 .Me) 3 C^H^N 211-215 c. .... Lieben and Eossi A., 165, 113 vii., 222; 26, (740) 367 .... .... abt. 208 .... 34, 849 Triisobutylamine N(CH 2 .CHMe 2 ) 3 184-186 u. c. Liquid Sachtleben B., 11, 734 180-186 Ladenburg B., 12, 950 36, 704 abt. 183 Lieben and Eossi A., 165, 109 vii., 222 ; 26, 367 177-180 .... Eeimer Z. C. [2], 7, 26 24, 122 177-180 Hofmann B., 3, 757 vii., 222 Triethylene-triethyltriamine Et3(C 2 H 4 ) 3 N 3 C 12 H 27 Nj 220-250 J. [1861], 517 ii., 591 Cyanodiphenyl Ph.C 6 H 4 .CN=1.4 C 13 H 9 N 84-85 Dcebner A., 172, 111 27, 892 Benzophenylnitril C 6 H 4 .CPh I N ,. .... 118 Dobner and Weiss B., 14, 1841 42, 177 .... 118 Dobner A., 210, 276 42, 508 a-Naphthoquinoline .... 251 (747) 50 .... M. C., 2, 162 p- .... c:c.c.c:c.c:c .... 90 Skraup & Cobenzl B., 15, 896 ; 44, 1011 1 I/I M. C., 4, 436 C:C.C.C:C.N:C Carbodiphenylimide Ph.N : C : N.Ph C 13 H 10 N 2 330-331 c. .... Weith B., 7, 1307 polymer 168-170 . ' B., 7, 11 27, 481 Diphenylcyanamide .... 292 B., 7, 848 27, 1171 Benzenylphenyleneamidine.... C 6 H 4 .N : CPh.NH B .... 250 Hiibner A., 208, 302 40, 1131 i i Base from nitrobenzanilide.... a. 240 Hiibner & Eetschy B., 6, 1128 27,78 Benzylidene aniline NPh I CHPh C 13 H U N 48-49 Tiemann and Piest B., 15, 2029 44, 198 .... 42 Cech B., 11, 248 Amidofluorene C |6 H 3 (NH 2 ).CH 2 .C 6 H 4 124-126 Strasburger B., 17, 107 46, 754 =1...4;U 123 B., 16, 2347 46, 329 Methyl carbazole (C 6 H 4 ) 2 N.Me " ^ .... 187 Grsebe & Aldnikron A., 202, 23 38, 660 Benzenylamidophenylenami- C 6 H 3 (NH 2 ).N:CPh.NH C 13 H,,N S 245 Stover B., 7, 1317 28, 271 L J dine 340 Hiibner A., 208, 309 40, 1131 Methenyldiphenyldiamine .... NPh:CH.NHPh C 13 H 12 N 2 a. 250 135-136 Weith B., 9, 454 30, 205 n 136-137 Wallach B., 15, 208 .... 137 Lellmann B., 14, 2512 42, 503 11 n .... 137 Tobias B., 15, 2449 .... 137-138 Wallach A., 214, 233 44,49 11 .... 138-139 Wallach & WUsten B., 16, 146 .I .... 140 Pinner B., 16, 358 Benzylidinephenylhydrazine Ph.NH.N : CHPh ,, 152-5 Fischer A., 190, 134 34,309 Benzenylphenylamidine NH;CPh.NHPh .... 111-112 .... A., 184, 350 ; 192, 31 .... 114-5-115 Bernthsen and B., 13, 919 Szymanski Phenylazotoluene Ph.N 2 .C 6 H 4 Me=1.4 ji 63 c. Schxiltz B., 17, 466 46, 903 Diamidofluorene .... B .... 155-157 u.c. Struve B., 10, 76 32, 902 n .... JT 155-157 Schultz B., 12, 236 36, 653 n n .... 157 A., 203, 99 38, 814 Methyldiphenylamine NPh 2 Me C 13 H 13 N 270 (528) .... Girard and Vogt C. E., 73, 627 24, 1060 11 290 Liquid Bardy C. E., 72, 751 24, 1197 ! 290-295 .... Briihl B., 12, 198 36, 499 B 282 .... A., 174, 181 Benzylaniliue.... Ph.NH.CH 2 Ph 310; 32 Fleischer A., 138, 226 v., 868 200-220 (50) 336 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Benzylaniline Ph.NH.CH 2 Ph C 13 H 13 N 33 Bernthsen , and B., 11, 1760. Trompetter Benzhydrylamine NH 2 .CHPh 2 295 Crystalline Friedel & Balsohn B. S. [2], 33, 587 40, 279 Phenyltoluidine C 6 H 4 Me.NHPh=1.2 JJ 297-299 41 Girard and Willen B. S. [2], 25, 248 30, 99 5, f 330 .... De Laire, Girard, B. S. [1866], 2, v., 866 and Chapoteaut 360 =1.4 334 87 Hofmann A., 132, 292 iv., 454 H 307-308 87-88 Girard and Willen B. S. [2], 25, 248 30, 98 n !! B 87 Buch B., 14, ,2345. Amidodiphenyhnethaue C 6 H 4 .NH 2 .CH 2 Ph=1.3 n 46 Becker B., 15, 2092 44, 203 =1.4 >) 34-35 Easier B., 16, 2718 46, 310 Amido-p-phenyltolyl ' C 12 H 8 .Me.NH 2 93-97 Carnelley J. [1876], 419 29, 21 Base from aniline tailings .... .... 46-5-47-5 Jackson B., 10, 960 32, 606 Diphenylguanidine . "., NH:C(NHPh) 2 C 13 H 13 N 3 147 . Weith & Schroeder B., 7, 937 28,86 n B .... 147 !> n ., 146 Steiner B., 7, 1246 28, 165 ' .... 147 Forster A., 175, 36 . . 28, 465 ,, H 147 Hofmann B., 2, 688 ,, .... 131 28, 86 Amidobenzene azotoluene .... C 6 H 4 Me.N 2 .C 6 H 4 .NH 2 .... 147 Nietzky B., 10, 666 32, 454 = 1.4; 1.? Diamidodiphenylmethane .... C 1S H 10 (NH S ), C 13 H 14 N 2 .... 85 Doer B., 5, 796 vii., 948; 26, 170 .... 85 Praetorius A., 196, 338 36,319 Amidobenzylaniline .... NH 2 .C 6 H 4 .CH 2 .NHPh. 88 Strakosch B., 6, 1063 27, 80 Benzylidene phenyldiamine NHPh.CHPh.NHj .... 115 Bernthsen and B., 13, 918 38, 639 Szymansky Diethyl dihydroquinoline .... C 9 H 7 Et 2 N C 13 H 17 N 255 Wisch negradsky B. S. [2], 34, 339 40, 444 Tetramidodiphenylmethane CH 2 .C 12 H 6 (NH 2 ) 4 C 13 H 16 N 4 .... 161 Stedel A., 218, 339 44, 991 Octohydroacridine .... C 13 H 17 N 320 (760) 84 Grtebe B., 16, 2831 46, 608 Methylbenzylpiperidine C 6 H 9 N.Me.CH 2 Ph C 13 H 19 N 245 Liquid Schotten B., 15, 424 42, 982 Phenylhydrazine on oanan- PhN 2 H.C 7 H M C 13 H 20 N 2 240 (77) 1.-20 Reisenegger B., 16, 663 44, 798 th aldehyde Ethylisoamylaniline Ph.NEt.C 5 H n C 13 H 21 N 262 Hofmann A., 74, 156 iv., 452 Propylene dipipei idiiie C 13 H 26 N 2 300-315 Liquid Ladenburg B., 15, 1148 42, 1194 Dicyanodiphenyl CN.C 6 H 4 .C 6 H 4 .CN C 14 H 8 N 2 234 Doebner A., 172, 116 27, 893 Benzilam .... =C 42 H 32 O 2 N 2 q. v. C 1 H N 105 Laurent R. S., 19, 443 i., 546 Phenauthrenediimide .... C 14 H 10 N 2 a. 285 .... M. C., 1, 146 Anhydroxalanilide .... (C 6 H 4 .N:C.NH) 2 =(1.2) 2 C I4 H 10 N 4 n.f. 300 Hiibner A., 209, 370 4S, 181 1 1 From diphenylamine C U H U N 92-94 Besthorn & Fischer B., 16, 74, 768 44, 600 Phenyl isoindole Ph.C:CH.NPh >* 185 Mohlau B., 14, 174 1 1 Methylphenanthridine C 6 H 3 Me.N I CH.C e H 4 H a. 360 170 Etard C. R., 95, 730 44, 180 i i Me.N=1.2 Anthramine (antracylamine) / CH \ C 6 H 4 <| >C 6 H 3 .NH 2 " 236-237 Liebermann and Bollert B., 15, 227 J? i 236-237 Liebermann A., 212, 56 42, 860 238 Roemer B., 15, 224 42,974 Hydrocyaucarbodiphenyl- NPh:C(CN).NHPh. C 14 H U N 3 137 u.c. Laubenheimer and B., 13, 2155 40, 163 imide Goring Phenylphenamidoacetonitril NHPh.CHPh.CN C 14 H 12 N 2 82 Cech B., 11, 247 34, 408 H 85 Tiemann and Piest B., 15, 2028 44, 198 Benzenyl-o-tolylenediarnine C 6 H 3 Me.N : CPh.NH 232-233 Hiibner and Kelbe B., 8, 875 ! | n 238-240 Hiibner A., 208, 316 40, 1131 ,, 238-240 Meyer I.D.Hanover,1878 240 Ladenburg and B., 12, 952 36, 716 Rughehner COMPOUNDS CONTAINING THREE ELEMENTS. 337 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Tolylphenylene amidine i) u Benzylene toluidiue Benzylidene Ethyl carbazole Anthramiue dihydride (?) Dibenzenylimidoimide Benze nylamidotoluy lene- C 6 H 4 Me.C:N.C 6 H 4 .NH i 1 =1.4 ; 1.2 )1 C 6 H 4 .Me.(N:CHPh)=1.2 C 12 H 8 EtN C 6 H 4 :C 2 H 4 :C 6 H S .NH 2 Base NH:CPh.NH.CPh:NH C 6 H 2 Me(NH 2 ).N : CPh.NH C 14 H 12 N 2 )) C 14 H 13 N )J )) )J C 14 H,,N 3 ) 314 u.c. 268 268 268 b. 100 67-68 b. 100 120-125 108-109 182-183 Hubnerand Hane- mann Stoddard Bruckner Etard Schiff Grsebe & Alderskrou Liebermann and Bollert Schiff Pinner and Klein Kelbe B., 10, 1712 B., 11, 294 A., 205, 116 C. E., 95, 730 A., 140, 96 ; J. [1880], 566 A., 202, 24 B., 15, 583 A,, 140, 96 ; J. [1880], 566 B., 11, 8 B., 8, 877 34, 144 34,504 40, 93 44, 180 38, 660 34, 492 amidine V )1 =1.3.5.4 CLH 3 Me.N : C(C,H 4 .NH 2 ).NH v.C l4 H 15 ON 3 227-229 HUbner A., 210, 336 J Acetophenone phenylhydra- zine Phenyl-phenylacetamidine .... )> Ethenyldiphenylamidine .... j s Ethenylisodiphenylamidine.... Tolylbenzenylamidine Diamidostilbene Azotoluene =1.3.4; 1.3 Ph.N 2 .CHPhMe Ph.CH 2 .C(NH 2 ):NPh ) NPh : CMe.NHPh ) )) NH:CMe.NPh 2 C 6 H 4 Me.N : CPh.NH 2 =1.4 C 14 H 10 (NH 2 ) 2 Me.C 6 H 4 .N 2 .C 6 H 4 Me (1.3) n C 14 H 14 N 2 ) H )i H )) n )j M .... SS8 105 128-129 129-134 131-132 131-132 132 137 62-63 99-99-5 170 51 Hiibner and Schack Keisenegger Bernthsen Biedermann Lippmaoun Bernthsen Hofmann Bernthsen Strakosch B., 10, 1712 B., 16, 662 B., 9, 429 A., 184, 343 B., 7, 540 B., 7, 542 A.,. 192, 1 C. E., 62, 729 ; B. S. [2], 6, 162 A., 192, 25 B., 9, 429; A., 184, 355 B., 6, 330 B 11 1625 34, 144 44, 798 30, 96 27, 808 34, 789 vi., 585 34,789 30,97 26, 891 36, 236 D 54 B 10 2098 34, 300 54-55 A 207 114 40, 432 ,, ... .... .... =(1.2), )> )i 55 55 J HoogewerfF and v. Dorp Schultz B., 11, 1203 B 17 467 34,973 46, 903 (1\ \VT B 10 2097 34, 300, 973 (?) 137 B P 8 170 , (?) B P 8 310 ? 137 37, 553 (I 4V 137 B 3 550 141 B 16 1048 142 142 143 * ft 143 37, 554 M3 144 B 14, 1384 42, 502 144 B 6 1209 27, 273 n .... .... i )) 144 144 ?) B., 10, 2097 A 207, 103 34, 300 40, 432 ,, .... .... (polymer) ? 11 ) 1 Base 11 .... 144-145 244-245 71 u Petriew Barsylowsky B., 6, 556 B., 10, 2097 B 2 649 26, 1027 34, 300 vi., 258 Cyananiline . C H N 210-220 A 66 129 ; 73 1, 160; 2, 300- Ethyldiphenylamine Beuzyltoluidine Ditolylamine .... NEtPh 2 C 6 H,Me.NH.CH,,Ph NH(C 6 H 4 Me) s 1 2-1? ^14 Xi 14 il 4 C 14 H 15 N j) 295-297 355-360 304 308 1 f m )> Girard De Laire, Girard, and Chapoteant 180 B S., 23, 3 B. S. [1866], 360 B. S., 25, 251 iv., 442 v., 866 (I 3), 319 320 B 13, 1088 38, 714 2 x 338 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. NH(C 6 H 4 Me) 2 =1.4 ; 1.? C,,H..N 355-360 79 Gerber B., 6, 446 .. ^IT j 14^"^15 323 u. c. 82 Girard and Willin B. S. [2], 25, 250 30, 99 7) 145 Girard and Vogt B. S. [2], 18, 67 25, 1026 Phenylxylidine C 6 H 3 Me 2 .NHPh *) )) 278-282 52 I! B. S. [2], 18, 69 vii., 1210 ; 26, (485) ; 1025 173 (15) Dimetliamidoazobenzene Ph.N 2 .C 6 H 4 .NMe 2 = ? CMH^N, .... 115 Griess B., 10, 528 82, 456 Amidotolylbeiizenylamidine Ph.C( I NH).NH.C,H 3 Me. .... 211-5-212 Bernthsen & Trom- B., 11, 1758 36, 147 NH 2 petter Amidoazotoluene .... ,. Me.C 6 H 4 .N 2 .C 6 H 3 Me.NH 2 i 80 Nietzki B., 10, 1155 32, 767 =1.3 ; 1.3.4 =1.2 ; 1.3.4 j .... 100 Schultz B., 17, 470 ... j .... 100 Nietzki B., 10, 663 34,54 =1.4 ; 1.?.? )i .... 115-5-116 Witt B., 10, 1309 34, 53 ) 7J 116-5 j ** =1.3 ; 1.3.6 118-5 Nolting and Witt B., 17, 79 46, 742 .... =1.4; 1.2.4 ) .... 127 Nietzki B., 10, 1156 32, 767 ,, .... .... =1.4 ; 1.3.4 M .... 127-128 B., 10, 665 32, 454 Ethylene diphenyldiamiue .... NHPh.CH 2 .CH 2 .NHPh C 14 H 16 N 2 59 Hofmann P. E. S., 9, 277 iv., 455 ?j .... 63 Morley B., 12, 1794 38, 112 Ethylidene CH 3 .CH(NHPh) 2 )i .... 130 Hofmann P. E. S. iv., 457 Hydrazotoluene Me.C 6 H 4 (NH)j.C 6 H 4 Me J> 124 Melms B., 3, 553 vii., 1163 =1.4; 1. ? > 77 ) 124 Barsylowsky A., 207, 104 11 =(l-8)i > 146 Schultz B., 17, 467 46, 903 ,, .... .... =1.2 ; 1. ? > .... 165 Petriew B., 6, 556 26, 1028 .... =1.4; 1.4 170-172 Barsylowsky B., 8, 695 28, 1037 )> 1 C 23 H 30 N 4 (?) 171-172 A., 207, 107 40, 432 Ditolylhydrazine NS 2 .N(C 6 H 4 Me) 2 =(1.4) 2 )) .... 171-172 Lehne B., 13, 1546 40,41 Diamido-dibenzyl (CH 2 .C 6 H 4 .NH 2 ) 2 =(1.4) 2 > 132 Stelling and Fittig A., 137, 257 v., 870 Amidophenylamidotolyl- N H 2 .C 6 H 4 .CH 2 .C 6 H 3 Me.NH 2 ) 227-228 Klinger B., 16, 943 methane p-Tolidine P. NH 2 .C,H 6 .C 7 H 6 .NH 2 > .... low temp. 103 Goldschmidt Melms B., 11, 1624 B., 3, 554 vii., 1164 o- J 112 Petriew B., 6, 557 26, 1028 )j 1 112 Schultz B., 17, 467 46, 903 9. .... .. )) 128-129 Petriew Z. C. [2], 6, 265 vii., 156, 1164 ? .... 122 Miiller & Limpricht A., Ill, 140 vi., 329 Dimethyldiphenyltetrazone.... N : N.N 2 Me 2 Ph 2 i i C 14 H 16 N 4 133d. Fischer A., 190, 172 34, 312 Amidobenzene azodimethyl- NH 2 .C 6 H 4 .N 2 .C 6 H 4 .NMe 2 )J 182-183 Meldola .... 45, 107 auiline =1.4; 1.4 Amidobenzene azoamido- NH 2 .C 6 H 4 .N 2 .C 6 H 2 Me 2 .NH 2 J) 163 .... 43, 432 xylene =1.4; 2.1.3.? Diamidoazotoluene N, : (C 6 H 3 Me.NH,) 2 =(U.l)., ) 159 Buckney B., 11, 1453 34, 864 ,, N 2 :C 12 H 6 Me 2 (NH 2 ) 2 .... 183 Hofmann B., 10, 218 32, 326 l)iethylnaphthylaniine C 10 H 7 .NEt 2 C 14 H 17 N 290 u. c. Liquid B. E. Smith 41, 181 Di(amidobeiizyl)amine (NH 2 .C 6 H 4 .CH 2 ) 2 NH CuH 17 N :! ..A 106 Strakosch B., 6, 1060 27, 79 Hydrazotoluidiue N n H 2 1 (C 6 H 3 Me.NH,) 2 C 14 H 18 N 4 180 Buckney B., 11, 1453 34, 864 =(U.1) 2 Diisobutylaniline C 6 H 4 .C 4 H 9 .NH0 4 H !) C 14 H 23 N 268-271 Studer A., 211, 240 .... i) 250-270 .... i B., 14, 2186 Tetraethyldiamidobenzene .... C 6 H 4 (NEt 2 ),=1.4 C 14 H 24 N 2 280 u. c. 52 Lippmann and M. C., 4, 284; 44, 869, 1100 Myristonitril . . C^Hnj.CN C H n ,N 226'5 (100) 19 Fleissner Krafft and Stauffer B., 16, 1421 B., 15, 1730 42, 1274 Phenyl quinoline C f H 3 Ph.CH : CH.CH : N ^M 1 "^? 11 C ls H a N 108-109 Coste B., 15, 562 42, 980 =1.3.4 , ,, > C f H 4 .CIi:CPh.CH:N=1.2 T .... 93 Friedlander and B., 15, 557 >* ., ,, .... .... C,H 4 .CPh : CH.OH : N=1.2 >J 84 Gohring Grimaux C. E., 96, 584 44, 668 )j .... .... C 6 H 4 .CH : CH.cpii : N )> a. 300 83 Dcobuer and Miller B., 16, 1664 44, 1150 COMPOUNDS CONTAINING THREE ELEMENTS. 339 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Base from phthalimide C 15 H U N 99-100 Gabriel B., 13, 1685 40, 263 Benzoylazotide Ph.CH I N.CHPh.CN C 15 H 12 N 2 164 Plochl B., 14, 1141 40, 820 Tetrolcyauuramide (C 5 H 4 N 2 ) 3 C 15 H 12 N 6 .... 210 Ciamician and B., 16, 65 44, 599 Dennstedt Cinnamic anilide .... .... C,H 9 : NPh C 15 H 13 N .... 109 Drebner and Miller B., 16, 1665 44, 1150 Diphenylguanidine cyanide .... C 15 H 13 N 6 .... 154 Hofmann A., 67, 160; 74,1 Cyandibenzylamine (PhCH 2 ) 2 N.CN C 15 H 14 N 2 .... 53-54 Limpricht A., 144, 318 vi., 337 o-C'arboditolylimide a. 300 .... Will & Bielschowsky B., 15, 1317 P- .... .... ^ 60 n B., 15, 1310 P- ., a. 230 60 Will B., 14, 1487 a-Benzenylxylene amidine .... C 6 H 2 Me 2 .NH.CPh:N=1.3.4.5 .... 195 Hiibner B., 10, 1711 34,143 a- ... 195 A., 208, 320 40, 1132 0- " \') .... 215 A., 208, 323 Amidomethylanthracene di- C 14 H 10 Me.NH 2 C 15 H 15 N sb. 130-140 78-79 Roemer B., 16, 1633 44, 1137 hydride p.d. Tolylphenylacetamidine Ph.CH 2 .C(NH. 2 ) : N.C 6 H 4 Me C 1S H 16 N 2 .... 118-119 Bernthsen B., 9, 432 30,96 =1.4 Ph.KH.CMe:N.C 6 H 4 Me=1.4 . ... 76 Wallach A., 214, 207 Ethenylphenyltolylamidine NHPh.CMe : N.C 6 H 4 Me=1.4 .... 86-88 _ B., 9, 1214 31,91 Methenyl ditolyldiamine Me.C 6 H 4 .N : CH.NH.C 6 H 4 Me 11 .._ 150 Ladenburg B., 10, 1261 34, 54 =(1.2), Methyl ditolylamine NMe(C 6 H 4 Me) 2 =(1.4) 2 CiiH 17 N 235-240 (20) Liquid Girard B. S. [2], 24, 120 29, 264 Tolylxylidine C 6 H 3 Me 2 .NH.C 6 H 4 Me=? 298-300 (487) 70 Girard and Vogt B. S. [2], 18, 69 26, 1025 ; vii., 194 (L v.) 1210 =(%; !* Yf .... 137 Biickner A., 205, 113 40, 94 Dimethylamidodiphenyl me- .... 330-340 .... Fischer A., 206, 113 40, 588 thane (?) Dibenzyl guanidiue NH:C(NH.CH,Ph)j C 15 H 17 N 3 .... 100 Strakosch B., 5, 695 vii., 182, 582 ; 26, 1027 Ditolyl guanidine NH:C(NH.e 6 H 4 .Me) 2 =(1.4) 2 .... 168 Hofmann B., 7, 1739 28, 466 i. ? 168 C. C. [1877], 738 34, 301 ,, 1! .... 168 Steiner B., 8, 520 )> i> =(1.2), .... 179 u. c. Berger B., 12, 1855 38, 244 Tripropyl aniline C 6 H 4 Pr 3 N C^HjsN 156-5 .... Zander A., 214, 138 44, 14 C -Ho N QQQ T " 'A r*. t A. 78 20 ftfifl .... ~* JUMJUlU ocennouse V., OJO 180-181 (20) Bernheimer G. 1^ 13, 451 46, 337 Valeritrine C,-H N 9"H 9fif> T p 'A T V, B., 6, 565 26 1023 .... _ fU _! M .' J_jlOlllCl i j u Davin NH 3 on propaldehyde .... C^H^Nj .... 74 Waage M. C., 3, 694 44, 39 Triamylamine (active) N(C 5 H,,) 3 CisH-j-jN 230-237 u. c. Plimpton-. C. R, 92, 882 39, 335 Triisoamylamine (inactive) .... N(CH 2 .CH 2 .CHMe 2 ) s 237 u. c. C. R, 91, 433 40,34 j M 237 u. c. Liquid C. R, 92, 882 39, 332 abt. 257 i.i. Hofmann J., 4, 493 i., 207 Dicyanostilbene CN.PhC:CPh.CN C.eH^N, .... 158 Reimer B., 13, 743 40, 47 Isodicyanostilbene .... ,, 242 71 B., 14, 1801 42, 170 Amidopyrene . P TT "XT ^, . i , j. M. C. 2 580 42 9fi7 . vjfOictscnmieciL ^***, ''i Amarone .... 233 Laurent R. S., 18, 207 i., 162 Phenylnaphthyl carbazole .... .... 440-450 330 Grsebe and Knechi; A., 200, 1 38,663 Dicyanodibenzyl CN.CHPh.CHPh.CN C 16 H 12 N 2 ... 214 Reimer B., 14, 1799 42, 170 j .... 218 Diamidodiphenyldiacetylene (C:C.C 6 H 4 .NH 2 ) 2 =(1.2) 2 _ MM 128 Baeyer & Landsberg B., 15, 60 42, 623 Phenyl-a-naplithylamine .... Ph.C 10 Hj.NH. C^H^N .... 42 Streiff B., 13, 1852 40, 176 -a- 335 (528) ; 58 Girard and Vogt B. S. [2], 18, 68 25, 102o ; vii., 226 (15) 846 -a- 315 (528) 60 >' C. R, 73, 628 24, 1059 -a- .... 60 Friedlander B., 16, 2078, 2086 46,80 -p- .... w _ .... 108 n B., 16, 2085, 2087 n -I 3 ' .... 108 Merz and Weith B., 13, 1300 38, 813 Flavoline .... . . p TT pill- fTTf'Ph'V 1 9 ,.,. GA KP. Fisclicr & Entlolpli B., 15, 1503 42 IfMiT M \J~t~ W Tt*', 1 \JV 1 1 1 Flavaniline .CMe I CH.C C 16 H 14 N. 97 B., 15, 1500 42, 1066 C.H 4 / =(1.2). .N:C 6 H 4 .NH 2 9 Y 9 340 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Indole (from indigo) See C 8 H 7 N C 16 H 14 N 2 .... 52 Engler and Janecke B., 9, 1416 31, 322 52 Baeyer As., 7, 59 28, 773 52 Nencki B., 8, 337 28, 1039 (from albumen) V n J) ) .... 85-86 Engler and Janecke B., 9, 1416 31, 322 " ) Jl " >1 89-91 Kiihne B., 9, 1416 Indoline (diindole) .... 1 245 Schiitzeuberger C. R., 85, 147 32, 898 NH 2 Me on phenanthrene- C 14 H 8 (NMe) 2 ) 185-186 Zinck6 B., 12, 1644 38, 48 quiuone From dicyanostilbene .... JJ .... 208 Eeimer B., 13, 747 40,48 Anhydroxalyldiamidotoluene (C 6 H 3 Me.N : C.NH)., C 16 H 14 N 4 .... abt. 193 Hiibner A., 209, 373 42, 181 ji )) 193 Hubner & Rudolph B., 8, 474 Amidobenzeneazoamido-a- NH 2 .C 6 H 4 .N,,C 10 H 6 .NH 2 .... 159-160 Meldola 43, 432 naphthalene =(1.4) 2 Dimethylanthramine C 14 H 9 .NMe 2 C 16 H 15 N 155 Bollert B., 16, 1638 44, 1140 Auhydrodiamidotoluyl- C 6 H.Me.C : N.C,H 2 Me 2 .NH C 16 H 16 N 2 .. 217 Fricke B., 10, 1713 34, 144 i i xylene =1.4; (?) 4 )> n .... 217 . Buckner A., 205, 125 40,94 D 51 > ) .... 217 Hubner A., 210, 333 42, 504 Azoethylbenzene N 2 :(C 6 H 4 Et) 2 =(1.2) 2 C lt H l8 N 2 47 Schultz B., 15, 1540 42, 1062 ,, .... .... ) )> J> .... 46-B c. >T B., 17, 473 46, 904 =(l.4) 2 j) .... 62 J" B., 15, 1540 .... ... >1 1 a. 340 63 c. V B., 17, 475 j> Azoxylene .... ' No ' CCH,Meo')o= ? 120 AV^erifo Z. C. [1865], 315 v., 1058 2 \^^6 3 2/2^^ 7 =(2 1.3). 126 c. Schultz B., 17, 476 }j yj *.v/2 11 = 3 128 Samaiioff J. R. [1882], 327 44, 180 Diethylene diphenyldiamine (CjH^N-.Ph, JJ 1 300 148 ; 157 (?) Hofmann P. R. S., 9, 277 ; iv., 456 ^N.C,H 4 .Me 10, 104 Ethenyl ditolylamidine Me.Cf JT Impure ? 69 (0 Wallach A., 214, 208 ; B., 44,48 N NH.C 6 H 4 .Me 16, 148 =(l-2) 2 *i 11 =(l-4) 2 .... 117-118 11 B., 9, 1214 31,92 I* 11 1 119'5-120'5 A., 214, 203 11 11 )! J) .... ISO r A., 214, 208 ; B., 44,48 16, 148 11 11 ". " I! >1 121-121-5 A., 184, 364 It 11 =1.4; 1.2 >J .... 140 ii A., 214, 208 ; B., ! 16, 148 11 11 =1.2; 1.4 )> 14S-143 )! M JT I 11 11 =(1.2), )) .... 134; 136 >! 11 1> J 11 >1 .... 140-5 Ladeuburg B., 10, 1262 34,54 Cyanbenzylamiue (C 6 H d .CH 2 .NH 3 ) 2 (CN) 2 C 16 H 18 N 4 .... 140 Strakoscli B., 5, 693 vii., 181 ; 25, 1026 Dimethylaniline azyline (.N:C 6 H 3 .NMe 2 ) 2 1 .... 266 Lippmann and B., 15, 2138 ; 44, 55, 185 Fleissner M. C., 3, 705 11 11 fl .... 266 Lippmaiin & Lauge B., 13, 2137 Diphenethylamine (Ph.CH 2 .CH 2 .) 2 NH 16 H 19 N 335-337(603) S])ica G. I., 9, 555 38, 242 Diethylamidodiphenyl Ph.C 6 H 4 .NEt 2 =1.4 (?) 1J b. 100 Hofmann P. R. S., 12, 389 v., 1055 Ethylditolylamine (Me.C 6 H 4 ) 2 NEt=(1.4) 2 (?) ) 255-260 (20) Girard B. S. [2], 24, 120 29, 264 Dixylylamine (C G H 3 Me 2 ) 2 NH )' d. 210 Liquid Pieper A., 151, 131 vi., 1133 11 .... .... >) 11 305-315 ; Liquid Girard and Vogt B. S. [2], 18, 69 25, 1025 ; vii., 205 (i. v.) 1210 )5 11 305-315 ; 162 ) V ) 205 (i. v.) Amidoazoxylene C 6 H 3 Me 2 .N 2 .C 6 H 2 Me 2 .NH 2 C 16 H 19 N 3 215 Nietzki B., 13, 471 38, 553 Base 215 IVTohlau B., 16, 2729 46, 306 C,,H a Me,N n r H N 173 \Viclielliaus B., 14, 1953 42, 58 12 8 4 2 ^le-^ao 1 ^ 2 .... Tetramethylbenzidine (C 6 H 4 .NMe 2 ) 2 =(1.4) !! ) a. 360 19.') Micliler& Pattinson B., 14, 2162 42, 199 Diethylbenzidine .... .... (C 6 H 4 ) 2 N 2 H 2 Et 2 =(1.4) 2 65 Hofmann A., 115, 365 Ethylene ditolyldiamine C 2 H 4 (NH.C fi H 4 Me) 2 =(1.4) :! 5) 97-5 Gretillat J. [1873], 698 Dietliylphenyl tetrazone PhEtN.N : N.NEtPh C.eH^N, 108 d. Fischer and Erhard A., 199, 327 ' 38, 243 COMPOUNDS CONTAINING THREE ELEMENTS. 341 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Diethylene diphenylenetetr- NH^CeH.^.-^^^:^ C.sHjoN, 221 Morley B., 12, 1796 38, 112 amine C 6 H 4 NH 2 Tetramethyl diamidodi- NH(C 6 H 4 .NMe 2 ) 2 =1.4; 1.? C 16 H 21 N 3 .... 119 u. c. Bindschedler B., 16, 866 phenylamine Tetramethyl diphenyldiamin PhMe.jNIN.MejPh. C 16 H 22 N 2 .... 173 Lippmann & Lang B., 13, 2139 40, 161 Diamidotetramethylbenzidin C 12 H 6 (NMe 2 ) 2 (NH 2 ) 2 C 16 H 22 N 4 168 Michler & Pattinso B., 14, 2164 42, 200 Tetrahydrodicollidine C 16 H 26 N 2 255-260 .... Hantzsch A., 215, 46 44, 84 Diisoamylaniline Ph.N(C 5 H n ) 2 C 16 H 27 N 275-280 Hofmann A., 74, 156 iv., 450 Paradiconiine .... 5 210 .... Schiff A., 166, 100 25, 417 210 B., 5, 42 vil., 381 Imidocaprilonitril [C 6 H 13 .CH(CN)] 2 NH C 16 H 29 N 3 a. 5-6 Erlenmeyer & Siege A., 177, 134 28, 1017 Palmonitril C 15 H 31 .CN C 16 H 81 N 251-5 (100) 31 Krafft and Stauffer B., 15, 1730 42, 1274 Dioctylamine NH(C 8 H 17 ) 2 CujH^N a. 220 .... Schiff (?) A., 166, 87 ,, 11 270-280 Liquid Merz and Gasio- B., 17, 636 46, 984 rowsld NH[(CH 2 ) 7 .CH 3 ] 2 297-298 36-5 B., 17, 631 Cyanopyrene C I6 H 9 .CN C 1? H 9 N 149-150 Goldschmidt anc M. C., 4, 253 Wegscheider Anthraquinoline c 6 H 4 :c 2 H 2 :c 6 H 2 .N: C 17 H n N 446 (728) 170 Gnebe B., 12, 1418 ; 38, 262 1 CH.(CH) 2 A., 201, 344 Benzenyl-p'-naphthylamidine C 10 H 6 .N : CPh.NH C 17 H 12 N 2 .... 210 Ebell B., 7, 1319 28, 272 !) 11 H .... 020 Hubner A., 208, 328 40, 1132 Benzylidine quinaldine C 9 H 6 N.CH : OHPh C 17 H 13 N .... 99-100 Jacobsen & Reimer B., 16, 2606 46, 336 )1 100 Wallach & Wiisten B., 16, 2008 44, 1097 Benzenylnaphthylamidine ... C, H 7 .NH.CPh : NH C 17 H I4 N 2 141 Bernthsen and B., 11, 1757 36, 147 Trompetter Benzyl-a-naphthylamine ... C 10 H 7 .NH.CH 2 Ph C 17 H 15 N 66-67 .... B. S., 20, 68 Tolyl-a-naphthylamine C 10 H 7 .NH.C 6 H 4 Me =1.4 11 290 (528); 79 Girard and Vogt C. R., 73, 627 vil., 846; 26, 236 (15) 1025 -a- 11 )1 360 (528); 78 55 B. S. [2], 18, 68 25, 1025 236 (15) B., 14, 2344 -a- V 78-5-79 Friedlander B., 16, 2091 46,80 -a- = 1.2 .... 9^-95 -|3- J) 11 ,5 95-96 -p- ,, = 1.4 11 .... 102-103 Merz and Weith B., 14, 2345 42, 179 -P- !> 102-103 Friedlander B., 16, 2090 46, 80 Azotoluene naphthylamine.... NH 2 .C 10 H 6 .N 2 .C 6 H 4 Me =1.4 C 17 H 15 N 3 .... 145 Weselsky&Benedik B., 12, 229 Dicyanoditolylguanidine .... NH i C(NH.C 6 H 4 Me) +2 CN n TT T^- .... 173-5-174-5 Berger B., 12, 1855 38, 244 =(l-2) 2 u. c. Pentenyl diphenyl diamine.... N 2 HPh 2 (C 5 H 9 )" C 17 H 20 N 2 Ill Hofmann P. R. S., 15, 55 vi. f 922 Isoamyldiphenylamine NPh 2 (C 5 H u ) C 17 H 21 N 330-340 Girard B. S., 23, 3 Dixylylguanidine NH : C(NH.C 6 H 3 Me 2 ) 2 C 1? H 21 N 3 .... 156-158 Hofmann B., 9, 1296 31,92 =(1.2.4) 2 Tetramethyhliamidodiphenyl CH 2 .(C 6 H 4 .NMe 2 ) 2 C!,.H S2 N 2 .... 91 Michler and Moro B., 12, 1170 36, 921 ; 38, 40 methane 5) 5t 91 Michler & Salath6 B., 12, 1789 5> 55 1) 90 Ooebner B., 12,811 36, 787 55 >' 11 .... 90 Tischer A., 206, 95 40, 587 5! " 11 88 ilanhart B., 12, 680 Benzaldipiperyl CHPh(C 5 H 10 N) 2 C 17 H 2B N 2 80-81 jaun R, 17, 679 46, 1011 Cetvl cyanide ... C -H. ,N jiquid Jeintz J. [1857], 445 C 16 H 33 .CN 53(?) iohler J. [1856], 580 i., 841 Dicyanopyrene C 16 H 8 '(CN) 2 C 18 H 8 N 2 a. 300 Solid Goldschmidt and M. G, 4, 255 44, 1004 Wegschneider a-Diquinolyline .... C 18 H 12 N 2 i. 400 75'5 u. c. ; Weidel M. G, 2, 491 42, 69 .sb. 176-1 77 #_ n .... 11 .... 91 app and Graham 30, 174 o 92-5 u. c. Weidel M. G, 2, 501 42,70 Diquinoliue . .... .... C 18 H 14 N 2 14 Claus B., 14, 1940 42, 215 NPh.C,,H 4 .NPh (?) .... 50 Griess R, 9, 132 39, 932 342 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Triphenylamine (C 6 H 6 ) 3 N C 19 H 15 N 140-150 Liquid Gossmann A., 100, 57 iv., 453 n )) 126-127 Merz and Weith B., 5, 646 vii., 945 ; 86, 73 1ST B., 6, 1514 27, 377 Phenyl amidoazobenzene ... Ph.N : N.C 6 H 4 .NHPh C^H^N, 82 Witt B., 12, 259 35, 186 Azobenzene + benzene C 12 H 10 N 2 + C 6 H 6 C 18 H 16 N 3 38 in sealed Schmidt B., 5, 1107 vii., 148; 26, tube 499 Diphenyl diamidobenzene ... C 6 H 4 (NHPh) 2 =1.3 * .... 95 Calm B., 16, 2796 46, 591 =1.4 )> 152 n B., 16, 2806 1! Amidobenzene azodiphenyl- NH 2 .C 6 H 4 . N 8 .C 6 H 4 .NHPh C 18 H 16 N 4 .... 90-91 Meldola .... 43, 441 amine Azodibenzene phenylenedi- PhN : N.C 6 H 4 .N : N. 18 H 16 N 6 ... 185 Griess B., 16, 2034 44, 1103 amine C 6 H 3 (NH 2 ) 2 Azobenzene phenylene di- PhN : N.C 6 H 2 (NH 2 ) 2 . ) .... 250 i) B., 16, 2029 44, 1102 amine benzene N : NPh =?.1.3.? Xylyl-a-naphthylamine C 10 H 7 .NH.C 6 H3Me s C 18 H 17 N 243-245 (15) Liquid Girard and Vogt B. S. [2], 18, 68 vii., 846, 1210; 25, 1025 Propyl piperidine * n 149-150 Ladenburg B., 14, 1348 Isopropyl piperidine .... n 149-150 .... 5) Phenyl-a-imidopropionitril .... NH(CH 2 Ph.CH.CN) 3 C 18 H 1; N 3 .... 105 Erlenmeyer & Lipp A., 219, 179 44, 992 ,, -a- J .... 108 j> u 11 Triaraidodiphenyl benzene (?) C 18 H n (NH 2 ) 3 (?) 169-5 Schmidt & Schultz A., 203, 118 40, 435 Aeetamide on phenyl-cyan- .... CisH 17 N 5 .... 232-234 Berger B., 14, 1257 40, 810 amide Hydrodiquinoline C 18 H 18 N, .... 161-162 Konigs B., 14, 100 Benzenylisoamyl phenylene- C 6 H 4 .N : CPh.N.C 5 H n Ci 8 H 30 N 2 .... 270 HUbner and Senne- B., 9, 776 30, 310 amidine Tetrahydroquinolinetetr- C 9 H 9 N.N 3 .NC 9 H 9 C.sH^N, 160 wald Hoffmann & Konigs B., 16, 731 44, 1144 azone Diethylenedi-p-tolyldiamine C 6 H 4 Me.N.(CH 2 ) 2 . C 18 H 22 N 2 360 189-190 Demote A., 173, 139; As., N(C 8 H 4 Me).(CH 2 ) 2 =(1.4) 2 7, 94 ])iethylidinedi-p-tolyldi- .... P .... 60 Schiff A., 140, 95 amine Azomesitylene Me 3 .C 6 H 2 .N 2 .C 6 H 2 Me 3 )" .... 75 c. Schultz B., 17, 477 46, 904 =1.3.5.6; 6.5.3.1 Diamidotetramethyl benzi- C 12 H 6 (NH 3 ) 2 (NMe 8 ) 2 C 18 H 22 N 4 .... 168 Michler & Pattinson B., 17, 118 46, 748 dine Ethylene diphenyl diethyl- (C 2 H 4 )"Ph 2 Et 2 N 2 18 H 24 N 2 70 Hofmann J. [1859], 389 iv., 455 diamine Tetramethyldiamidodiphenyl- (CH 2 .C 6 H 4 .NMe 2 ) 2 1) a, 300 50 Schoop B., 13, 2197 40, 160 ethane Tetramethyldiamidoditolyl .... (C 6 H 3 Me.NMe 2 ) 2 =(1.4) 2 J) .... 57 Michler& Pattinson B., 14, 2167 =(1-8), J .... 80 Michler & Sampaio B., 14, 2172 42, 178 " Alkaloid (?) )J C, H,,N .... 190 70 n B., 14, 2170 ,T. B., 13, 507 42, 177 ^^IS-^-'-HS-'- 1 5 61-62 Strecker A., 130, 220 Stearonitril . . .... ... *H, CN J> C, H, E N 374-5 c. (100) 41 Krafftand Stauifer B., 15, 1730 42, 1274 Trihexylamine v/ 17 J - t 35' v> - 1 -^ N(C 6 H J3 ) 3 ^^IS^^Sa- 1 - 1 C 18 H 39 N 260 Petersen and Goss- A., 101, 311; 102, mann 312 Phenylacridine ,CPh C,H/ I \C,H 4 X N T C 19 H 13 N a. 360 181 Bernthsen & Bender B., 16, 1810 44, 1133 ) .... 182-183 Bernthsen B., 15, 3012 44, 580 tt )J ... 182-183 M A., 192, 19; B., 32, 886 ; 34, 10, 1235 789 Benzenyl diphenylene ami- Ph.C6Hs.NH.CPh : N C 19 H 14 N 2 .... 197-198 LUddens B., 8, 873 28, 1258 dine =1.4.? Diphenyl methylene aniline Ph 2 C : N.Ph C 19 H 15 N a. 360 109 u. c. Pauly A., 187, 201 32, 614 Benzylidene diphenylhydr- NPl. 2 .N:CHPh C 19 H 16 N 2 .... 122 Fischer A., 190, 179 34,313 azine Benzenyl isodiphenyl amidine NPh,,.CPh : NH ii .... 111-5-112 Bernthsen B., 10, 1236 32, 886 ji )> 11 ) .... 112 JT A., 192, 4 34, 788 COMPOUNDS CONTAINING THREE ELEMENTS. 343 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Benzenyl diphenyl amidine... NHPh.CPh : NPh C 19 H 16 N 2 .... 144 Wallach and Hoff- B., 8, 313 as, 1031 mann " 11 H .... 144 Doebner B., 15, 233 42, 957 Triphenyl amidomethane ... NH 2 .CPh 3 C 19 H 17 N .... 102 Nauen B., 17, 442 46, 899 11 i> d. 103 Hemilian & Silber- B., 17, 742 46, 1032 stein u 11 J> .... 105 Elbs B., 16, 1277 44, 1000 Benzyl diphenylamine NPh.CH 2 Ph )) .... 86-5-87 Bernthsen & Trom- B., 11, 1761 36, 157 petter 11 11 ) .... 87 Meldola B., 14, 1385 42, 502 51 11 H )) 240 (i.v.) 95 Willm and Girard B., 8, 1194 Amidoti-iphenyl methane .... CHPh 2 .C 6 H 4 .NH 2 .... 83-84 Fischer and Koser B., 13, 675 ; A., 38, 661 206, 155 Phenylamidodiphenyl- CH 2 Ph.C 9 H 4 .NHPh. )J .... abt. 89 Meldola .... 41, 199 methane u-Triphenyl guanidine NPh : C(NHPh) 2 C 19 H 1; N 3 141 Hofmann B., 2, 456 - u J .... 142 Merz and Weith Z.C.[2],4,513,60 "- ,1 *j 142-143 u B., 2, 621 vi., 656 - .. ) 145 Bnff B., 2, 499 vii., 583 - 11 It j 143 Land grebe B., 11, 973 a- ,, ,, )I 143 Forster A., 175, 33 28, 465 - u 143 Weith B., 7, 13 - 11 >. ) 143 B., 10, 358 32, 448 #- NH:C(NHPh).NPh 2 131 Weith & Schrceder B., 8, 294 28, 771 Carbotriphenyltriamine NPh : C(NHPh).C 6 H 4 .NH 2 )) 193 Michler and Waldei B., 14, 2174 =1.4 11 V 5) 195 Weith B., 10, 358 32,448 11 .... I) V )) 198 B., 12, 104 36, 462 Diamidotriphenyl methane.... BteH(C,H 4 .NH^, C,,H 18 N 2 124-125 Bottinger B., 11, 841 11 5) JJ 139 O. Fischer B., 13, 668 ; A., 38, 662 206, 147 1? 11 5 n ... 139 Doebner B., 15, 236 11 11 +C 6 H 6 ,, 104-105 Bottinger B., 12, 977 36, 716 11 11 ji 106 O. Fischer B., 13, 669 38, 662 11 11 " > 105-106 Doebner B., 15, 236 5) 11 +aq. r .... abt. 67 Bottinger B., 11, 276, 840 34, 506 Benzenyldiphenylazidiue .... NHPh.NH.CPh I N.NHPh C 19 H 18 N 4 170 Pinner B., 17, 184 46, 743 a-Azobenzene phenyleue di- Ph.N 2 .C 6 H 2 (NH 2 ) 2 .N 2 .C 6 H 4 Ci 9 Hj 8 N 6 .... 192 Griess B., 16, 2030 44, 1102 aminetolueue l ' Me=l.(?) 3 ; 1.4 y~ 11 11 !) !) > 214 j> 44, 1103 &- 11 )> ... 225 j D 44, 1102 Triamidotriphenyl methane CH(C 6 H 4 .NH 2 ) 2 =1.3 ; (?) s CpHifMj 148 0. Fischer B., 15, 678 (pseudoleucaniline) 11 >i >' ii M 150 Fischer and Ziegler B., 13, 673 38, 662 11 D J) )J )) + C 6 H 6 145 )1 i, .... CH(C 6 H 4 NH 2 ) 3 =1.2 ; (?) 2 ) 165 Renouf B., 16, 1305 44,981 (pseudoleucaniliue) = 1.4 ; (?), )) 180 Graebe B., 12, 2242 Cinchen C 1 H N 123-125 Coenigs B., 14, 1854 42, 224 Carbodipropyl phenylimide C(:N.C 6 H 4 Pra) 2 =(1.4) 2 19 20 2 C 19 H 22 N 2 168 Francksen B., 17, 1228 46, 1009 Isoamyl ditolylamine C 5 H n .N:(C 6 H 4 Me) z =(1.4) a C 19 H 55 N 290-300(15) .... Girard B. S. [2], 24, 120 20, 264 Dimesityl guanidine NH : C(NH.C 6 H 2 .Me :) ) 2 C 19 H 25 N 3 218 Eiseuberg B., 15, 1014 42,956 = (1.3.5) s Dipropyl phenyl guanidine.... NH:C(NH.C 6 H 4 Pi*)., =(1.4) 2 J) 113 Traucksen B., 17, 1226 46, 1008 Tetramethyldiamidodimethyl, CMe 2 (C 6 H 4 .NMe 2 ) 2 C 19 H S6 N 2 83 lofmaun & Martins B., 6, 346 diplienylmethane >i 11 J) .... 83 Doebner B., 12, 83 (8-Dinaphthylenamine C, H 6 .NH.C 10 H 6 C 20 H, 3 N 157 ; 159 c. Walder B., 15, 2174 4,209 Azonaphthalene C 10 H 7 .N:N.C 10 H 7 C 20 H 14 N 2 275 ilobukowsky B., 10, 573 2, 623 ,, .... .... Q 11 .... 278 u. c. Doer B., 10, 772 )1 ,, > )) 980 i> B., 3, 291 344 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Meltmg Point. Authority. Reference. Watts'Dict. & J. Ch. Soc. Triphenyl acetonitril CPh s .CN C.H 16 N 137 E. and O. Fischer B., 11, 1599 36, 326 .... 127-5 A., 194, 260 36, 385 )> ,, Polymer 210 a-/3-Dinaphthylamine NH(C 10 H 7 ) 2 110-111 Benz B., 16, 18 44, 594 a- .... 111 Calm B., 15, 615 42, 972 a- 111 u. c. Landshoff B., 11, 639 - ,, 1) 310-315 (15) 113 Girard and Vogt B. S. [2], 18, 68 vii., 846 ; 25, 1025 0- 11 .... 170-5 Merz and Weith B., 13, 1300 38, 813 0- .... 170-171 Benz B., 16, 19 P- ,, J) .... 170-5 Calm B., 15, 611 42, 972 0- 170-171 Jacobsen B., 14, 1791 Diazoainidonaphthalene C 10 H 6 .N 2 .C 10 H..NH 2 C 20 H 15 N 3 100 Martius Z. C. [2], 2, 137 vi., 848 Azodinaphthyl diamine (C 10 H 7 ) 2 NH.N : .... 130 Perkin and Church 16, 207 iv., 23 i) 51 .... 136 Martins Z. C. [2], 2, 138 vi., 849 n .... 173-175 Lecco B., 7, 1291 28, 169 Dibenzylidene p-phenylene .... C 20 H 1C N 2 .... 138-140 Ladenburg B., 11, 599 34, 573 diamine Phenyl benzaldehydine C 6 H 4 (N:CHPh) 2 = 1.2 .... 133-134 Ladenburg and B., 11, 1653 36, 234 Engelbrecht Amidoazonaphthalene NH 2 .C 10 H 6 .N 2 .C 10 H 6 .NH 2 (?) C 20 H 16 N 4 C,, H 15 N 3 (?) 183 c. Schultz B., 17, 477 Diphenylmethylene-m-tolui- C 20 H,.N a. 360 Liquid Pauly A., 187, 214 dine Methylhydrophenylacridine C 6 H 4 .CHPh.C 6 H 4 .NMe a 104 Bernthsen and B., 16, 1802 44, 1134 Bender Triphenmethylmethylamine CPh a .NHMe C 20 H 19 N .... 73 Hemilian & Silber- B., 17,741 46, 1033 stein Triphenethylamine CPh 3 .CH,,NH 2 116 Elbs B., 17, 700 46, 1031 Acetylenetriphenyltriamine NHPh.CH.NPh.CH.NHPh CaHuN, .... 190 Sabanejeff A., 178, 125 29, 56 Triamidodiphenyltolyl- .... C ao H 21 N 3 .... 100 Hofmann J. [1862], 349 methane (leucaniline) Azocymene (C 6 H 3 MePr>0 2 : N 2 =(1.4. ?), C H N 86 Weriso Z. C. Ph. [1864], vi., 303 v o 721 Diethylaniline azyline NEt 2 .C 6 H 3 : N.N : C 6 H 3 NEt 2 C 20 H 26 N 4 170 Lippmann and M. C., 3, 710 ; B., 44,55,185 ...* Fleissner 15, 2139 Dicymylamine (MePrC 6 H 3 ) 2 NH 20 H 27 N a. 300 d. .... Rossi C. R., 51, 570 ii., 298 Tetrethyl benzidine Et 2 N.C 6 H,C 6 H 4 .NEt 2 =(1.4) 2 CjoHsgNj 83 P. W. Hofmann A., 115, 366 i., 545 i j> 85 Michler & Pattinson B., 14, 2166 42, 200 Diamyline lepidine(lepamiue) .... C 20 H 32 N 2 175 Williams 16, 375 iii., 573 a-Compound Base C 2 ,H 10 N 2 .... 100 Kuhn A., 122, 321 8- 190 A., 122, 322 0- " 200 Ekman A., 112, 170 Diphenylenetoluquinoxaline C 6 H 3 Me.N : C.(C 6 H 4 ) 2 .C : N C 21 H 14 N 2 .... 212-213 Hinsberg B., 17, 323 46, 1053 = 1.3.4; (1.2) s Cyaphenine (cf. B., 15, 1494) Ph.C . N . C.Ph C 2I H 15 N 3 .... 331 , Pinner and Klein B., 11, 764 34, 864 II 1 II N CPh N 231 B., 11, 5 34, 491 1) 229 Frankland & Evans ) J 37, 563 ** s. a. 350 224 Cloez A., 115, 27 iii., 449 Diphenyltoluquinoxaline .... C.H 3 Me.N : CPh.CPh : N ) Distils 111 Hinsberg B., 17, 323 46, 1053 = 1.3.4 Lophine 170 Kuhn C.C. [1861], 237; iii., 184, 734 A., 122, 314 230 " 266 Ran B., 14, 444 260-270 Bruuner A., 151, 135 vi., 793 (cf. B., 15, 2421) NH.CPh : CPh.N I CPh 267-270 Jappaud Robinson B., 15, 1269 41, 328 i i (cf. B., 13, 711 ; 15, CPh : N.CHPh.N : CPh 275 Radziszewsky B., 10, 71 32, 887 i i 1494) COMPOUNDS CONTAINING THREE ELEMENTS. 345 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. o-Dinaphthylguaiiidine .... C 21 H 17 N 3 .... 200 Perkin A., 98, 239 Dicyautriphenylguanidiue ... C 21 H 17 N 5 172-5 Landgrebe B., 10, 1595 34,217 .... .... 172-173 B., 11, 974 Amarine (cf. B., 15, 1270, NELCPh : CPh.NH.CHPh i i C 21 H J8 N 2 700 Fownes A. 54, 365 1., 161 2410) (cf. B., 15, 1495, CHPh.NH.CHPh.N : CPh i i .... 113 Bahrmann J. p., 27, 297 44,799 2333) Hydrobenzamide (cf. B., 15, CHPh(N I CHPh) 2 (?) ,, cf. B, 15, 110 Laurent A. 21, 131 iii., 183 1495) 1270 p-Tolylbenzyltolyleneamidine C 6 H 4 Me.N.C 6 H 3 Me.N : CPh MM 165-166 ; Lellmann B., 15, 833 42, 1061 L 1 =1.4; 1.4.2 or 3 a. f. 160 Dibenzylidene-m-toluylen- .... ...* 122-128 Schiff A., 140, 98 diamine Dibenzylidenetolylene dia- C 6 H 8 Me(N : CHPh) 2 =?.1.2 188-191 Ladenburg B., 10, 1126 32, 753 miue 11 .... 195-5 B., 11, 591 34, 572 Triphenylmelamiue C 3 H 3 Ph 3 N 6 C 21 H 1S N 6 162-163 Hofmann B., 3, 267 Benzenylditolylamidine C 6 H 4 Me.NH.CPh : N.C 6 H 4 . C 21 H 20 N 2 .... 131-132 Bernthsen B., 9, 434 30,97 Me=(1.4) 2 % o-Compound (v., C 21 H 10 N 2 ) Base .... 100 Kuhn A., 122, 321 iii., 184 P~ )> ii 190 A., 122, 322 ft- 11 .... 200 Ekman A., 112, 170 Dibenzyltoluidine (Ph.CH 2 ) 2 N.C 6 H 4 Me CMH..N 55 Cannizzaro As., 4, 80 v., 866 Tribeuzylamine (C 6 H 5 :CH 2 ) 3 N 360 p.d. 91 ,. C., 3, 397 i., 576 a abt. 93 As., 4, 80 v., 866 11 91-3 Lfmpricht A., 144, 307 vi., 337 11 91 Schoeller B., 7, 1276 28, 258 11 11 92 Lieben Z. C. [2], 6, 736 vii., 179 11 92 Frankland and 37, 567 Tompkins Tritolylamine (?) N(C 6 H 4 .Me) 3 =(1.4) 3 (2) 165 Merz and Weith B., 14, 2345 Triphenmethyldimethyl- CPh 3 .NMe 2 .... 97 Hemilian and Sil- B., 17, 746 46, 1033 amine berstein Di ruethy lamidotriphenyl- CHPh 2 .C 6 H 4 .NMe 2 .... 132-133 Fischer B., 11, 750 36, 53 methaue 132 A., 206, 114 40, 588 Phenyldi-p-tolylguanidine ... .... C S1 H 21 N 3 73 Will&Bielschowski B., 15, 1310 Tri-p-tolylenetriamine .. 2 16-220 d. Perkins .... 37, 548 51 ~P~ 11 .... i... 244-245 J. R., 13, 450 Tri-(amidobeiizyl)amine (NH,C 6 H 4 .CH 2 ) 3 N C 21 H 24 N 4 ..... 136 Strakosch B., 6, 1061 27,79 Carbodiisobutylphenylimide C(:N.C 6 H 4 .C 4 H 9 ) 2 =(1.4) 2 CnH^N, .... 189 Pahl B., 17, 1243 46, 1010 Diisobutylphenylguanidine .... NH : C(NH.C 6 H 4 .C 4 H 9 )j C^HjsNj .** 173 B., 17, 1240 =(1.4), Dianhydrolupinine .... C 21 H 3(i Nj 220 Liquid Baumert A., 214, 372 44, 100 Triheptylidine diamine (C 7 H 14 ) 3 N 2 21 H 42 N 2 a. 400 .... Schiff As., 3, 367 vi., 697 Metliylamarine CjjHjjN, 172-174 Glaus and Elbs B., 13, 1418 38, 882 Ethylene-a-dinaphthyldi- C 2 H 4 (NH.C 10 H 7 ) 2 11 ..*. 127 Reuter B., 8, 23 28, 649 amine Tritolylguanidine Me.C 6 H 4 .N : C(NH.C 6 H 4 Me) 2 CjjHjjN, .... 100+ Girard B., 6, 445 26, 912 =(1.2) 3 11 11 11 .... 130-131 Berger B., 12, 1857 38, 244 =(l-4) 3 ji 123 VIerz and Weith Z. C. [1868], 610 vi., 657 1! 11 .... 125 Buff B., 2, 500 C 1B H 33 .NHPh CjjHjjN J.9 T? '^1 A.. 83, 29 v., 450 a-Naphthylmethenyldi- C 10 H 7 .C(NHPh) : NPh C^H 1S N 2 KB 183-5 . nciau 3cessneck B., 16, 642 44, 808 phenyldiamiue Naphthyldiphenyl guanidine C 1(1 H 7 .N : C(NHPh) 2 CjjHuNj .... 155 Tiemann B., 3, 7 vii., 583 Dicyanohydrobenzamide .... CHPh(NH.CHPh.CN) 2 C 23 H 20 N 4 .... 55 Ploehl B., 13, 2119 40, 168 Aribine .... 11 .... 229 Rieth . D. Gottingen, 1861 2 T 346 ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authprity. Reference. "Watts' Diet. & J. Ch. Soc. L)imetbylamarine .... .<. OHPh.NMe.CPh : NMe : CPh i i C 23 H 22 N 2 /.B., 15, 2334 146 Claus and Elbs B., 13, 1419 38, 882 Tetramethyldiamidotri- CHPh(C 6 H 4 .NMe 2 ) s C 23 H 2I! N 2 .... 102 E. and O. Fischer B., 12, 798 36, 787 phenyl methane H ) .... 101 Doebner B., 13, 2228 40, 166 ii ii 11 71 .... 101 H B., 11, 2277 36, 787 > 11 H .... 97-98 u.c. >1 B., 11, 1239 34, 874 11 ji i .... 93-94 E. and O. Fischer B., 12, 798 36, 788 J .... b. 93 1 M >i H i .... 92-93 Fischer B., 10, 1625 34, 52 Tetramethyltriamidotri- NH 2 .C 6 H 4 .CH(C 6 H 4 .NMe 2 ) 2 CaH^N, 130 E. and O. Fischer B., 12, 803 36, 788 phenylmethane =1.3 ; (l.?) 2 j) =1.2 ; (1.1), ... 126 Fischer B., 15, 683 43, 834 =1.4 ; (1.?), )> 151-152 B., 14, 2527 Heptylidene diethyldiphenyl (C 7 H u )"Et 2 Ph 2 N 2 CpH^N, 215-220 p.d. .... Hofmann As., 3, 3C3 iv., 459 diaiuiue Azodiphenyl C 6 H 4 .NPh : NPh.C 6 H.=(1.4), C 24 H 18 N 2 .... 249-250 Zimmermann B., 13, 1962 40, 175 i i Acetophenonine CPh:N.CH 2 .cPh:cH.cph:cH C M H 19 N .... 130 Engler and Heine B., 6, 639 vii., 940 ; 26, 1036 Hydrazodiphenyl (C 6 H 4 .NHPh) 2 =(1.4) 2 CHH..N, .... 247 Zimmermann B., 13, 1961 40, 17. r ) o-Naphthylethenyldiphenyl- C 10 H 7 .CH 2 .C( : NPh)(NHPh) 11 .... 130-5 Bcessneck B., 16, 642 44, 808 diamine Hydroacridine ,,,. ) .... 169 Grsebe and Caro A., 158, 278 vii., 20; 24, 711 Tetraphenyltetrazone NPh 2 .N : N.NPh s C 24 H 30 N 4 .... 123d. Fischer A., 190, 182 34, 313 a-Naphthyltolyl phenylguani C 10 H 7 .N : C(NHPh) C 24 H : ,N, .... b. 60 Tiemann B., 3, 7 vii., 583 dine (N.C.H 4 Me) Cyanbenzine (C 8 H.N) 3 )> .... 170-171 Frankland and .... 37, 568 Tompkins |3-Dicyanotri-p-tolyl guani- -C 6 H 4 Me.N:C(NHC 6 H 4 Me) 2 C^H^N, .... 184 Landgrebe B., 11, 976 36, 54 dine + 2CN a-Dicyanotri-o-tolylguanidine 1 )1 .... 141 Berper B., 12, 1857 38, 244 Tricyantribenzyltriamine ... (eH 2 Ph) 3 (HN) 3 (CN) 3 C 24 H 24 N 6 m.a. 33 Strakosch B., 5, 695 vii., 182 Triphenethylamine (PliCHjCH^N C M H 27 N .... Liquid Spica G. I., 9, 555 38, 242 Pentamethyl-leucaniline .... 0HN. 173 E. and O. Fischer B., 12, 799; 16, 707 and German Pentamethyl paraleucaniline ) .... 115-116 Fischer and Korner B., 16, 2907 46, 607 Dipropylaniline azyline NPr 2 .C 6 H 3 : N.N : C 6 H 3 .NPr 2 C 24 H M N 4 .... 90 Lippmann & Fleiss- B., 15, 2140 ; 44, 55, IS,'. uer M. C., 3, 711 Trioctylamine N(C 8 H 17 ) 3 C 24 H S1 N abt. 370 Liquid Merz and Gasio- B., 17, 636 46, 984 rowski NIYCH ) CH 1 365-307 Crvstcil 1 1 11 G B. 17 633 " ^ L\ 2/7 ajs ) Triphenmethyl aniline Ph.NH.CPh 3 C 25 H 21 N .... 144-5 Hemilian and Sil- B., 17, 747 46, 1033 berstein > ) )> 146 Elbs B., 17, 703 46, 1031 Tetraphenyl guanidine NH : C(NPh 2 ) 3 25 H 21 N 8 .... 130-131 Weith B., 7, 843 27, 1170 Diamidotriphenylmethane CHPh(C 6 H 4 .NH.,) 2 +C 6 H 6 CBH^N. ... 106 d. Fischer B., 13, 668 38, 662 -(-benzene Tri-amidotriphenylmethane C 19 H 1B N 3 +C,H, C.H.N, 145 p.d. Fischer and Ziegler B., 13, 673 V + benzene Diethylamarine C 21 H 16 Et 2 N r 1 TT TJ V^j'Hl" 2 110-115 Borodine A., 110, 83 i., 162 Carboamidotetraimidobenzen (NH 2 .C 6 H 4 .NH) 4 C=(1.4) 4 C 25 H 28 N S .... 138 Hiibner B., 10, 1718 34, 143 Tetramethyldiarnidoditolyl- CHPh(C 6 H 3 Me.NMe.,). 2 C 25 H 30 N 2 .... 109 Fischer B., 13, 809 38, 63(i phenylmethane =(?.1.3) 2 Hexamethyl-leucaniline CH(C 6 H 4 .NMe 2 ) 3 C K H 31 N, ... 250 E. and O. Fischer B., 11, 2097 36, 236 Hexamethylparaleucaniline .... ) .... 173 Fischer and Korner B., 16, 2904 46, 6d(> Dinaphthylene-phenylamiue C 10 H 8 .NPh.C 10 H 6 C 26 H 1? N .... 144 ; a.f. 80 Walder B., 15, 2176 44, 209 i i /3-Dinaphthy 1 diarnidobenzen C,H 4 .(NH.C 10 H.) 2 =1.3 C 26 H M N 2 i... 126 Ruhemann B., 14, 2654 43,391 Dibenzylidene benzidine (C 6 H 4 .N:CHPh) 2 =1.4 ) .... 231-232 Schiff B., 11, 832 Bi-diphenmethylamine (CHPh 2 ) 2 NH C 26 H 23 N 136 Friedel & Balsohn B. S. [2], 33, 587 40, 279 Benzyltriphenmethylaniine.. Ph.CH,NH.CPh 3 .... 110 Elbs B., 17,703 46, 1031 Triphenmethyltoluidiue C 6 H 4 Me(NH.CPh 3 )=1.2 .... 142 Wittich B., 17, 705 46, 1032 COMPOUNDS CONTAINING THREE ELEMENTS. 347 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Triphenmethyltoluidine C 6 H 4 Me(NH.CPh 3 )=1.4 C^H^N .... 177 Wittich B., 17, 706 46, 1032 Benzylphenylamidodiphenyl - CH 2 Ph.C 6 H 4 .N Ph.CH 2 Ph .... not definite Meldola 41, 199 methane Methyldiphenylamineazyline (PhMeN.C 6 H 4 ) 2 : N 2 CAN, .... 150 Lippmann & Fleiss- M. C., 4, 788 46, 180 ner Tetramethyl diamido-propyl- C 6 H 4 Pr.CH(C 6 H 4 .NMe 2 ) 2 C 26 H 32 N 2 .... 118-119 O. Fischer B., 12, 1689 ; 38,40 triphenylmethane A., 206, 139 (Enanthylideue benzidine .... (C 6 H 4 .N:CH.C 6 H U ) 2 =(1.4) 3 )> .... 113-115 Schiff B., 11, 832 (!holesterylamine C 26 H 4: ,NH 2 C 26 H 46 N .... 104 Loebisch B., 5, 514 vU., 329; 25, 808 Tetraphenylmelamine C 2 H 3 Ph 4 N 8 C 27 H 22 N 6 .... or Hofmann B., 7, 1738 28, 466 ) J) 217 Weith and Ebert B., 8, 914 34, 301 Triethylene-p-tritolyltria- C^H^N, .... 186 Gretillat J. [1873], 698 mine Tetraethyl diamidotriphenyl Ph.CH(C 6 H 4 .NEt 2 ) 2 C^N, .... 62 Doebner A., 217, 264 44,861 methane Diphenanthrenazotide .... C 2S H 16 N 2 a. 440 Sommaruga M. C., 1, 159 Dianthramine ? (C 14 H 9 ) 2 .NH C 28 H 19 N sb. 300 n.f. 320 crystalline Bollert Miiller B., 16, 1636 A., Ill, 153 44, 1139 ^28 21-^3 Diphenyl diisoiudole CPh.NPh.CH.CPh.NPh.CH C^H^N, a. 360 181 Mohlau B., 15, 2482 44,342 Polydehydro-p-azotoluene .... (C-H 6 N:NC 7 H 7 ) 2 C 28 H 28 N 4 see C 7 H-N 244-245 Barsilowsky B., 11, 2153 36, 237 Tolyltri-p-tolylene triamine (C ; H 6 ) 3 "(C 7 H 7 )H 2 N 3 CjgHjjrN,, .... abt 175 d. Perkin .... 37, 552 Parahydrazotoluene .... C 28 H 30 N 4 C 14 H 16 N 2 (?) 171-172 Barsilowsky A., 207, 108 40, 432 Tetraethyldiamidodinaphthy] Et 2 N.C 10 H (! .C 10 H 6 .]SIEt 2 CaH^N, a. 360 190 B. E. Smith .... 41, 183 Trimesitylguanidine .... C 6 H 2 Me 3 .N:C(NH.C 6 H 2 Me 3 ) 2 *^28"35^3 .... 225 Eisenberg B., 15, 1014 =(6.1.3.5) 3 Dibutylaniline azyline Bu 2 N.C 6 H 3 : N.N :C 6 H 3 .NBu 2 Qi8H 42 N 4 .... 158 Lippmann and M.C.,3, 713 ;B., 44, 55, 185 Fleissner 15, 2142 Sucoinic chloride on acet- .... C M H 28 N 4 .... 132-133 Hiibner B., 10, 2165 34, 407 anilide Trinaphthalene diamine .... C M H 18 N 2 .... d. 180 Saltzmann and B., 9, 1107 30, 528 Wichelhaua ? base .... C 30 H 36 N 2 205 Borodin B., 6, 1253 27, 273 Tricymylamiue (C 6 H 3 MePra) 3 N C 30 H 3 ,N .... 81-82 Rossi As., 1, 143 ii., 298 Diphenyldiamidotriphenyl- CHPh(C 6 H 4 .NHPh) 2 C 31 H 26 N 2 .... 170,-sf. m.b. Meldola .... 41, 192 methane =1.4; 1.4 170 Triisobuty Ipheny Ignanidin e Bu/s.C 6 H 4 .N:C(NH.C 6 H 4 . C 31 H 41 N 3 .... 163-164 Pahl B., 17, 1241 46, 1010 Bu0) 2 =(1.4) 3 Myricylcyanide C 3() H 61 .CN C 31 H 61 N 75 Pieverling A., 183, 357 31, 587 Hydra zoindole C 16 H 13 N.NH.NH.C 16 H 13 N C 32 H 28 N 4 140 Nencki B., 8, 725 28, 1206 Cholesteryl aniline Ph.NH.C 26 H 43 C 32 H 49 N 187 Walitzky B., 11, 1937 36, 135, 376 Diamylaniline azyline [.N:C 6 H 3 .N(C 5 H U ) 2 ] S C 32 H 50 N 4 .... 115 Lippmann and M. C., 3, 713 ; B., 44,55 Fleissner 15, 2142 Hydroisonaphthalamide (C 10 H 7 .CH) 3 N 2 C 33 H 24 N 2 .... 146-150 Battershall Z. C. [2], 7, 673 25, 699 Tetraphenyltoluylene di- C 6 H 3 Me[.N:C(NHPh) 2 ] 2 C^H^N. 76 Tiemann B., 3, 8 vii., 583 guanidine Cliolesteryltoluidine .... C 6 H 4 Me.NH.C 26 H 43 Ca3H 51 N 172 Walitzky B., 11, 1937 36, 135, 376 Octomethyltetramido tetra- [CH(C H 4 .NMe 2 ) 2 ] 2 C 34 H 42 N 4 300 90 Schoop B., 13, 2199 40, 160 phenyl ethane Dibenzylamarine C 21 H 16 N 2 (CH 2 Ph) 2 C^H^N, 139-140 Claus and Elbs B., 13, 1420 38, 882 ,, )T )) .... 140 C'laus and Lupp B., 15, 2330 Azophenine (cf. B., 8, 1028) NPh 2 ) 2 : N.C 6 H 4 .N: NPh=1.4 C 36 H 29 N 6 .... 236; 237 236 Witt B., 10, 1311 B., 16, 1102 Cholesteryl a-naphthylamine C 10 H 7 .NH.C 26 H 43 C 36 H 61 N 202 Walitzky B., 11, 1937: B.S 36, 135, 376 [2], 30, 535 Naphthoquinoline C 39 H 27 N 3 251 (?) 50 Skraup W. A., 83, 434 40, 920 Dinaphthylenamide C^UNH^C^H,, C 40 H 2 ,N 2 .... 157 ; 159 c. \Valder B., 15, 2174 44, 209 ? Base C 42 H 36 N 4 .... 217 Hiibner & Frerichs B., 10, 1720 Tricetylamine (C 16 H 33 ) 3 N C 4S H 99 N .... 39 Fridau A., 83, 25 i., 843 1 ^sHiogNjs .... 260 d. Niederist M. C., 3, 845 Dimyricylaniine (C. io H fil ) 2 NH C6oH 123 N .... 78 Pieverling A., 183, 351 2 Y 2 348 ORGANIC COMPOUNDS. 9. CHP. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Methylphosphine PH 2 Me CH 5 P 14 (758-5) .... Hofmann B., 4, 608 24, 835 ; vii., 954 .... )1 )) c. (1-75 .... ? )! ats.) ,, J )) c. 10 (2-3-4 .... >! J) ats.) ) .... ... )> I c. 20 (4-4-5 )1 )) ats.) Dimethylphosphide .... ... PMe 2 C 2 H 6 P 250 Cahours & Hofmann A., 104, 1 Dimethylphosphine .... , .... PHMe 2 C 2 H 7 P 25 Liquid Hofmann B.,4, 610 Ethyl phosphine PH 2 Et )> 25 Liquid jj B., 4, 430 24, 715 ; vii., 953 Trimethyl phosphine PMe 3 C 3 H 9 P 40-42 Hofmann & Cahours P. T. [1857], 583 iv., 608 Isopropyl phosphine PHjPi^ JJ 41 Liquid Hofmann B., 6,' 294 vii., 955 ; 26, 882 Diethyl phosphine PHEt 2 C 4 H n P 85 Liquid jj B., 4, 433 24, 715 ; vii., 953 Methylisopropyl phosphine.... PHMePrU j 78-80 Liquid B., 6, 299 vii., 955 ; 26, 883 Isobutyl phosphine PH 2 .(CH 2 .CHMe 2 ) )5 62 Liquid B., 6, 296 )J Isoamyl phosphine .... PH 2 .(CH 2 .CH 2 .CHMe 2 ) C 5 H 13 P 106-107 Liquid j B., 6, 297 26, 882 Phenyl phosphine C 6 H 5 .PH 2 C 6 H-P 160 Micheelis& Ananoff B., 8, 499 28, 1205 M J1 J) 160-161 Liquid Kohler & Michselis B., 10, 808 32, 450 Triethyl phosphine PEt 3 C 6 H J5 P 127-6 Liquid Hofmann & Cahours P. T. [1857], 583 iv., 610 *, ,, .... J > 128 Hofmann B., 4, 207 , , .... .... 1) 128 )5 Z. C., 14, 364 Diisopropyl phosphine PHPr3 2 )j 118 Liquid || B., 6, 294 vii., 955 ; 26, 882 Benzyl phosphine PH,,CH 2 Ph C 7 H 9 P 180 Liquid B., 5, 101 25, 422; vii., 955 Tolyl phosphine C 6 H 4 .Me.PH 2 =1.4 )) 178 4 Micluelis & Paneck A., 212, 233 42, 963 Isopropylisobutyl phosphine PHPr0(CH 2 .CHMe 2 ) C 7 H 17 P 139-140 Liquid Hofmann B., 6, 300 26, 883 ; vii., 955 Dimethylphenyl phosphine.... C 6 H 5 .PMe 2 C S H U P 190 .... Czimatis B., 15, 2016 44,58 J5 '' > J 192 c. Liquid Michoelis& Ananoff B., 8, 498 ; A., 28, 1204 181, 359 Octyl phosphine PH 2 .(CH 2 ) 7 .Me *^sH l9 P 184-187 Liquid Moslinger B., 9, 1006 30, 394 Diisobutyl phosphine PH(CH 2 .CHMe 2 ) 2 11 153 Liquid Hofmann B., 6, 296 vii., 955 ; 26, 882 Dimethyltolyl phosphine .... C 6 H 4 .Me.PMe 2 =1.4 C 9 H 13 P 210 1. -10 Czimatis B., 15, 2014 44, 57 Triisopropyl phosphine P(CHMe 2 ) 3 C 9 H 21 P Liquid Hofmann B., 6, 295 vii., 955 Ethylisopropylisobutyl phos- PEtPr0(CH 2 .CHMe.,) abt. 190 ?> B., 6, 300 vii., 955 ; 26, phine 883 Diethylphenyl phosphine .... Ph.PEt 2 Ci H 15 P 220 Czimatis B., 15, 2016 44, 58 > 216-220 Liquid Mich;elis & Ananoff B., 7, 1693 28, 468 J) ,, 220=2eZ'9e. Liquid 5) B., 8, 4.94 28, 1204 Dimethylxylyl phosphine .... C 6 H. t Me 2 .PMe 2 i) 230 Liquid Czimatis B., 15, 2016 44, 58 Diisoamyl phosphine PH.(CH 2 .CH 2 .CHMeA, t-'uiH 2: ,P 210-215 Liquid Hofmann B., 6, 298 26, 882 ; vii., 955 Diethyltolyl phosphine C 6 H 4 .Me.PEt 2 =1.4 C,,H 17 P 240 Liquid Czimatis B., 15, 2016 44, 58 Phosphobenzene (diphos- Ph.P : P.Ph C^HmP., > 145-150 Kohler & Micluelis B., 10, 813 32, 451 phenyl) Diphenyl phosphine PHPh 2 C 12 H n P 280 Liquid Michielis & Gleich- B., 15, 801 42, 1062 mann Diethylxylyl phosphine C 6 H. t Me 2 .PEt 2 C 12 H 19 P 260 Liquid Czimatis B., 15, 2016 44, 58 Triisobutyl phosphine P(CH 2 .CHMe 2 ) 3 C 12 H 27 P 215 Liquid Hofmann B., 6, 296 vii., 955 ; 26, 882 Dipheuylmethyl phosphine.... PPh 2 Me t''i:|H, : ,P 284 Liquid Michselis and Link A., 207, 210 42, 306 Isobenzylphenyl phosphine.... PHPh.CH,Ph (?) )) ^A-iPs O 169-170 ; Michrelis and B., 15, 1962 44, 186 170-171 Gleichmann COMPOUNDS CONTAINING THREE ELEMENTS. 349 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. ^ference. Watts' Diet. & J. Ch. Soc. Diphenylethyl phospliine .... Dibenzyl phosphine PPh 2 Et PH(CH 2 Ph) 2 C 14 H 15 P M 293 205 Michselis and Link Hofmann A., 207, 214 B., 5, 103 42,306 25, 423 ; vii, 956 Isotolylbenzyl phosphine .... PH(CHi,Ph)(C 6 H 4 Me) > C^H-sPj (?) 187 Michselis and B., 15, 1963 44, 186 ' Gleichmann Diethylnaphthyl phosphine Tri-isoamyl phospliine PEtj.C 10 H 7 P(CH 2 .CH 2 .CHMe 2 ) 3 P a. 360 p. d. abt. 300 Liquid Liquid Kelbe Hofmann B., 11, 1501 B., 6, 298 36, 68 26, 882 ; vii., 955 Triphenyl phosphine PPh s C 18 H 15 P a. 360inCO s 75-76 Michselis and B., 15, 802 42, 1062 Gleichmann Isobenzylphenyl phosphine.... Isotolyl benzyl phosphiue ... CaffjjP (?) C 14 H 15 P (?) C 2S H 24 P 2 .... 170-171 187 11 11 B., 15, 1962 B., 15, 1963 44, 186 10. CHAs, CHSb, and CHBi. Trimethylarsine AsMe 3 C 3 H 9 Aa b. 100 Liquid Cahours C. R, 49, 87 i., 410 ,, .... 11 )) 120 .... Schorlemmer Carb. compounds, 98 Dimethylarsine (cacodyl) ... Me a As.AsMe 2 C 4 H 12 As 2 170 s. 6 Bunsen A., 42, 14 i., 403 Triethylarsine AsEt 3 C 6 H 15 As 140-180 p. d Landolt J., 6, 492 ; A. 89 i., 398 (736) 322 Phenyldimethylaraine Ph.AsMe 2 C 8 H,,As 200 Michselis and Link A., 207, 205 42, 305 Diethylarsine (ethylcacodyl) Et 2 As.AsEtj {jt&lfiAMj 185-190 Landolt J., 6, 491 ; A., 89 319 ; 92, 365 Phenyldiethylarsine Ph.AsEt 2 C, H 15 As 240 Liquid Michselis B., 10, 626 ; A., 32, 452 201, 212 Areenobenzene Ph.As:As.Ph C 1! H 10 As 2 .... 196 Michselis & Schulte B., 14, 912 40, 723 Diphenylmethylarsine AsPh 2 Me C 13 H 13 As 306 Michselis and Link A., 207, 199 42,305 Dipheylethylarsine AsPh 2 Et 14 H 15 As 320 in C"0 2 11 11 A., 207, 196 11 11 11 1 305 Liquid La Coste & Michaslis B., 11, 1886 36, 162 Triphenylarsine AsPh 3 C 18 H 15 As .... 58 11 11 A., 201, 237 38,397 11 T ) a. 360 in CO 2 58-59 11 11 B., 11, 1887 36, 162 Arsenoiiaphthalene C ln H 7 .As : As.C 10 H 7 ^2tt' : '-14-^ 8 2 221 Michselis & Schulte B., 15, 1954 44, 187 Tvitolylarsine As(C 6 H 4 Me) 3 =(1.4) 3 C 21 H 2l As 129-130 La Coste & Michselis B., 11, 1889 36, 163 11 >l 130 11 11 A., 201, 252 38, 397 11 J1 )> it 145 La Coste A., 208, 26 40, 905 Diphenylarsine (phenyl- Ph^s-AsPlu C 2 4H 20 As 2 135 Michselis & Schulte B., 15, 1954 44, 187 cacodyl) Trimethylstibine SbMe 3 C 3 H 9 Sb .... Liquid Landolt A., 78, 91 i., 344 11 ) > 80-6 .... 11 J., 14, 569 Tetraiiiethylstibiue SbMe 4 C,H 12 Sb (?) 86-96 C 4 H 12 Sb 2 (?) Buckton J. [1860], 374 13, 120 Peiitamethylstibine .... SbMe 6 C 5 H 15 Sb 96-100 .... 11 11 Triethylstibine SbEt 3 C 6 H, 5 Sb 158-5 1.29 Lowig & Schweitzer J., 3, 471 i., 341 Pentaethylstibine SbEt 5 C 10 H 25 Sb 96-100 .... Buckton J. [1860], 374 13, 120 Triisoaniylstibine Sb(CH s .CH 2 .CHMe J ) 3 Oj5rirj- 1 ob Liquid Berle J. p., 65, 385 i., 340 Tnphenylstibine SbPh 3 c 18 H; 5 sb 48 Michselis and Reese B., 15, 2876 44, 327 Diisoamylstibine (C 5 H n ). 2 Sb.Sb(C 5 H u ) ; Cjo^S b 2 Liquid Berle J. p., 65, 385 i., 340 Triethylbiamuthine BiEt 3 C,H 15 Bi d. 50-60 Liquid Breed ; Diinhaupt A., 82, 106 ; 92, 372 350 ORGANIC COMPOUNDS. 11. CClBr, CC10, CC1S, and CC1N. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. "Watts' Diet. & J. Ch. Soc. Tribromchlormethane CClBr, II. 1 70 Bolas and Groves 24, 779 vii., 324 Trichlorbrommethaue ... CCl 3 Br 104-3 (757-9) Liquid Paternd G. I., 1, 593 25, 232 ; vii., 258 5) .... JJ 104 .... ft B., 5, 289 .... )> 104 .... Friedel and Silva J. F. P., 5, 99 26, 888 ,, .... .... I) 104 B. S. [2], 17, 538 ,, .... J 104-07 (760) Liquid Thorpe .... 37, 203 Chlortribromethylene CBr 2 :CBrCl C 2 ClBr 3 203-205(734) 34 Denzel B., 12, 2208 38, 228 Chlorpentabromethane CBr 3 .CBr 2 Cl C 2 ClBr 5 170 d. B., 12, 2207 a-Dichlordibromethylene .... CBr 3 : CC1 2 C 3 CljBrj a. 160 ; abt. s. 20 B., 11, 1741 36, 214 194 IJ J) .... s. 16 Burgoin C. R, 81, 48 28, 1246 ? )) 143-160 .... Patern6 J. [1871], 512 a-Dichlortetrabromethane .... CBr 3 .CBrC'l 2 C 2 01 2 Br 4 .... 180 d. Denzel B., 12, 2207 38, 228 Tetrachlordibromethane CCl 3 .CClBr 2 OgOl^lirg solid Paterno G. I, 1, 593 vii., 258 CCl 2 Br.CCl 2 Br .... .... Burgoin B. S., 24, 114 Carbon oxy chloride (car- CO : C1 2 CC1 2 O 8'2 c. (756-5) Emmerling and B., 2, 547 ; Z. C., bonyl chloride, phosgene) Lengyel 13, 189 ) i) ) )J 8-0 Henry A. S. S. B. Trichloracetyl chloride CC1 3 .COC1 C 2 C1 4 118 .... Gal C. R, 76, 1019 26, 746 ; vii., 19 > > ) 118 c. (758) .... Thorpe 37, 189 I> 118 Friederici B., 11, 1971 )j )J )> 118 .... Hiibner J. [1861], 437 vi., 22 )i >> )) 116-118 .... Bergomoletz B. S. [2], 34, 330 40, 401 J5 118 Malaguti A. C. [3], 16, 57 i., 883 Tetrachlormethylic formate C1.COO.CC1 3 C 2 C1 4 2 180-185 .... Cahours J., 1, 676; A., ii., 695 64, 315 Hexachlormethyl oxide CC1 3 .O.CC1 3 C 2 C1 6 a. 100 .... Begnault A. C. [2], 71, 403 Hexachloracetone CC1 3 .CO.CC1 3 cf. C 5 C1 10 2 C 3 C1 6 200-201 .... Plantamour B. J., 26, 428 i., 30 .... .... 204 .... Cloez A., 122, 120 i., 996 Hexachlorethylic formate .... .... C 3 a 6 o 2 200 !> A. C. [3], 17, 299 i., 24 i) .... j> 200 3) A. C. [3], 17,312 ) Hexachlormethylic carbonate (CC1 3 ) 2 C0 3 C 3 C1 6 3 78-79 Councler B., 13, 1698 40, 251 Dichlormaleic anhydride C 3 ci 2 : (CO). : o C 4 C1 2 O 3 119-5 Kander J. p. [2], 28, 191 46, 40 PC1 5 on succinic chloride .... .... C 4 C1 6 199-215 Liquid M Chloroxethose .... JJ 210 .... Malaguti A. C. [3], 16, 20 i., 924 Hexachloracetic anhydride .... (CC1 3 .CO) 2 O C 4 C1 6 3 223 Liquid Clermont C. R, 86, 337 34, 402 >i )> 2%2-224 Liquid Buckney & Thomson B., 10, 699 Octochlorethylic acetate CC1 3 .COO.CC1 2 .CC1 3 C 4 C1 8 2 245 Leblanc A. C. [3], 10, 202 i., 22 Decachlorethyl oxide (CC1 3 .CC1 2 ) 2 C 4 C1 10 abt. 300 69 Regnanlt A. C. [2], 71, 394 ii., 541 )> >* J) 300 d. 09 Malaguti A. C. [3] 16, 14 From sodium citrate C 5 C1 10 2 190 ' ... .... i., 996 ? see C 3 C1 6 and C 8 C1 16 3 (?) 200-201 .... Plantamour B. J., 26, 428 ) Decachlorethylic carbonate.... (CC1 3 .CC1 2 ) 2 CO S C 5 C1 10 3 .... 85-86 ; 86-88 Malaguti A., 47,294;B. J., i., 800 26, 759 Perchlorphenylene oxide .... .... c 6 a 4 o C 12 C1 S O 2 ? abt. 320 Merz and Weith B., 5, 461 25, 702 Hexachlorphenol c c a 6 .oci C f .Cl 6 .... 46 Benedikt&Schmidt M. C., 4, 604 44, n )) .... 106 Langer B., 15, 1331 3) dichloride C 6 C1 5 .OC1+C1 2 C 6 C1 8 102 Benedikt&Schmidt M. C., 4, 604 Decachlorethylic oxalate COO(C 2 C1 5 ).COO(C 2 C1 5 ) C 6 C1 10 4 .... 144 d. Malaguti A. C. [2], 74, 299 iv., 270 Tetrachlorphthalic anhydride C,C1 4 .CO.O.CO=1.2 C 8 C1 4 3 .... 245 Grsebe A., 149, 20 Chloroxethide C 8 C1 10 7 200 Malaguti A. C. [2], 74, 308 iv., 271 Tetradecaehlorethylic suc- COO(C 2 C1 6 ).(CC1 2 ) 2 .COO C 8 C1 14 4 MM 116-120 Cahours (?) A., 47, 297 (?) cinate (PA) 1 see C 3 C1,O C 8 C1 16 3 (?) 200-201 Plantamour B. J., 26, 428 i., 996 1 COMPOUNDS CONTAINING THREE ELEMENTS. 351 Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Mellityl hexachloride C 6 (CO.C1), C 12 C1 6 0, sb. 240 190 Claus and Poppe B., 10, 561 Octochlorphenylene oxide .... C 6 C1 4 :0 2 :C 6 C1 4 C 12 C S 2 (?) a. Hg abt. 320 Merz and Weith B., 5, 461 25, 702 ; vii., 906 Carbonsulphochloride (thio- cs:ci 2 CC1 2 S 70 .... Kolbe A., 45, 45 I., 778 carbonyl chloride) >t >1 ) 71-74 .... Bathke A. 167, 204 u * ( X .... 112-5 A., 167, 206 Tetrachlormethylmercaptane CC1 3 .SC1 CC1 4 S 146-147 c. j B., 3, 859 vii., 266 )) M 146-5-148 c. .... A., 167, 200 Chlorothioform .... 0,01,83 abt. 250 Hartley 20, 23 vi., 446 Hexachlormethyl sulphide .... CC1 3 .S.CC1 3 3 C1 6 S 156-160 Eiche A. C. [3], 43, 288 ; A., 92, 355 Hexachlormethyl trisulphide CC1 3 .S 3 .CC1 3 ) 57-4 Eathke A., 167, 209 Cyanogen chloride N : c.ci CC1N c. 12 to 15 s. 18 ii., 279 )> )1 (4 ats.) ii., 278 H ) 12-66 (760) s. 7'4 Regnault M. A. S., 26, 658 ; vi., 538 J. [1863], 70, 74 . )) )i || 15-5 Salet B. S. [2], 4, 105 26, 1129 dichloride .... C 2 C1 2 N 2 15-5 e. 5-6 Wurtz A., 64, 308; 79, 280 ii., 280 Trickloracetonitril CC1 3 .CN C 2 C1 3 N 81 Dumas and Leblanc J., 1, 593 i., 33 )1 83-84 Bisschopiuck B., 6, 732 ; B. S., 26, 1128 20, 450 .... .... ( ) 91-92 Weddiger J. p. [2], 28, 188 46,35 Cyanuric chloride .... C/3L.N, 190 140 Serullas A. C. [3], 35, 291 ii., 280 11 .... ) 140 Gauthier B. S. [2], 5, 403 vi., 538 Pentachlor-benzonitril C 6 C1 5 .CN C 7 C1 5 N 210 Moe and Mayer B., 16, 2886 46, 589 ? C, C1 22 N 4 abt. 85 Bouis A. C. (31 20, 446 ii., 282 Perchlortriphenylamine (0 6 C1 5 ) 3 N II) ZJ 4 C I8 C1 15 N n. f. 270 Euoff " v L JJ "J n B., 9, 1494 31, 300 12. CBrI, CBrO, CBrS, and CBrN. I C 4 Br 3 I 3 .... 100 Berend A., 135, 260 vi., 34 Uarborioxybromide (carbonyl CO : Br 2 CBr 2 O 12-30 Liquid Emmerling B., 13, 874 38,627 bromide) Tribromacetyl bromide CBi 3 .CO.Br C 2 Br 4 O 220-225 Gal B. S., 5, 172 ; A., vi., 21 129, 56 Hexabromacetone CBr 3 .CO.CBr 3 C 3 Br 6 107-109 Weidel and Gruber B., 10, 1146 32, 779 n H 108-109 Herzig M. C., 3, 831 44, 464 Tribrommethylic tribromace- CBr 3 .COOCBr, CJBrA 86-87 Steiner B., 7, 505 27, 886 tate Dibromfumaric anhydride .... CO.CBr.CBr.CO.O i i C 4 Br 2 O 3 .... 95-120 Limpricht A., 165, 253 vii., 828 ; 26, 625 Tetrabromfurfurane .... C 4 Br 4 O 63 Hill B., 16, 1132 44, 912 Tetrabromquinone (bromanil) .... C,Br 4 0, sb. a. 250 Losanitach B., 15, 474 .... 51 sb. 270 .... A. Hexabromphenol C 6 Br 5 .OBr C 6 Br 6 128 Benedikt M. C., 1, 3(i3 Hexabromresorcinol C 6 Br 4 (OBr) 2 =1.3 C 6 Br 6 0, 136 ,, M. C, 1, 366 Pentabromethylic pentabrom CBr 3 .CO.CBr 2 .COO(C 2 Br,,) C 6 Br 10 3 .... 79-80 Wedel A., 219, 71 46, 835 acetoacetate Oarbotrithiohexabromide .... C 2 Br 6 S 3 125 Hell and Ureeh B., 15, 276, 987 ; 42, 706; 44, 16, 1144 907 Tetrabromthiophene CBi-:CBr.S.CBr:CBr C,Br 4 S 326 c. 112 Meyer and Keia B., 16, 2172 46, 45 i i | 352 .,. ORGANIC COMPOUNDS. Name. Constitution. Formula. Boiling Point. Melting Point. Authority. Reference. Watts' Diet. & J. Ch. Soc. Cyanogen bromide .... ' ^ *, NICBr CBrN a. 40 4 16 Lowig Serullas Bineau B. J., 8, 94 A. C. [2], 34, 100 A. C. [2], 68, 425 ii., 277 Cyanuric bromide .... C 3 Br 3 N 3 a. 300 Eghis Z. C. [2], 5, 376 ; B., 2, 160 vi., 538 Pentabrombenzonitril C 6 Br 6 .CN C 7 Br 6 N a. 300 Merz and Weith B., 16, 2892 46, 588 13. COS, CON, CSN, and CNP. Carbou oxysulphide COS c.0(12'5ate.) .... Ilosvay B. S. [2], 37, 294 44, 43 .... H c.3-8(15-ate.) .... c. 107 .... (17-5 ate.) .... c. 12 .... (19-6 ate.) n c. 17 .... ,, (21-5 ate.) .... c. 39-8 .... (44- ate.) .... .... .... c. 41-2 n (45- ate.) ., .... c. 63 (59- ate.) .... n ,, ,, .... .... .... c.69 (65- ate.) .... .... c. 74-6 .... ,, (74 ate.) ,, .... c. 85 (80 ate.) 5> .... c.t. 105 " Tetranitromethane C(N0 2 ) 4 C0 8 N 4 126 13 Schischkoff A., 119, 247 iv., 110 Trinitroacetonitril C(N0 2 ) 3 .CN C 2 6 N 4 60 in current 41-5 A. C. [3], 49, 310 ; iv., Ill of air; d. 220 A., 101, 213 Cyanogen sulphide .. SCy 2 C 2 SN 2 .... 60 Linnemann A., 120, 36 Phosphorus tricyanide PC y 3 C 3 N 3 P 200-203 Wehrhane& Hubner A., 128, 254 ; 132, iv., 517 279 UARKI.SON AND SONS, PRINTERS IN ORDINARY TO HER MAJESTY, ST. MARTIN S LANE, LONDON. I > Selection from jTarri^on ' publication^, Chemical Effect of the Spectrum (The). By Dr. J. M. EDER. 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