AN ENQUIRY CHVMICAL CH.\RACTER AXD PROPERTIES RHODE ISLAND ; bBSERVATIONS ON THE USEFUL APPLICATION OF IT TO THE ARTS AND MANUFACTURES OF THE EASTERN STATES. AN ENQUIRY, &e. The subject of the following pages is so interesting to the inhabitants of this country, that little apology is requisite for intruding it on the publick. Providence has so bountifully distributed its favours over the continent of America, that few ar¬ ticles are required from other countries, which could not be obtained here by proper industry'and research. While the population of America was but limited, and while the forests afforded a sufficient supply of so useful and necessary an article as fuel for the purposes of com¬ mon life, no exertion was .made to discover other substitutes, but as the soil becomes cultivated, and as arts and manufactures in¬ crease, a necessity arises for seeking a sup¬ ply of fuel from other sources than the woods of the country. It is unnecessary to dwell on the advan¬ tages which must result to a country so em¬ inently flourishing as America, from the dis- 4 covery of Coa] Mines : few who are ac¬ quainted with the rapid increase of the arts and manufactures in England, but must at¬ tribute much of their success to the benefit which they derive from their Colliaries. In this respect, I hope to make it appear, that England has no great superiority over this country ; and those who wish well to the manufactures of America, can in no higher degree promote its best interests, than by encouraging researches which so obviously tend to their prosperity. The inhabitants of the eastern States, and of Boston in particular,are much indebt¬ ed to the genius and perseverance of one of their own countrymen, for tlie discovery of a Coal Mine at Rhode Island, so eligibly situated in every respect, that a constant and regular supply can be obtained at all times, without di'tficuln'. My object at present/is, to describe its geological situa¬ tion, to give an accurate analysis of the Coal whicli'has been discovered, and to ex¬ plain some of its most obvious qualities; and I am more particularly induced to this attempt, from observing that much igno¬ rance prevails on the subject, and that ma¬ ny of its properties are either unknown, or misrepresented. 5 In this .description, 1 shall confine my¬ self entirely to that part of the Island where the Coal Mine is at present situated, and where the indications of Coal V7ere sostrong- ly marked, that it is rather surprising it should have so long escaped general obser¬ vation. The fossils which appear on the surface, in the neighbourhood of the Coal Mine, are argillaceous sand stone, abundance of schis- tus, or shale, and white quartz in large de¬ tached masses. When the ground is pene¬ trated a few feet, the appearances are such as to leave no doubt that the stmta consist of what is called the true independant Coal formation. Shale and argillaceous sand stone, abounding with vegetable impres¬ sions,, present themselves first, and immedi¬ ately under the sand stone, Coal is discov¬ ered ; in some places, even wfthin six feet of the surface. The position of the bed is here, as is gen¬ erally the case in the independaot Coal formation, not horizontal or vertical, but forming an angle of about 76 , and the veins of coal appear to be separated from each other by various coloured sand stones, which interpose between theseams. Though all these substances belong to what is called 6 the transition rocks, yet fine specimens of indurated talc and green Asbestos in capella- ry crystals, are also discovered, interspersed through the shale, and immediately covering the Coal. Substances, which it is difficult to account for, as they have been generally supposed peculiar to primitive rocks. The veins of coal run nearly in the direc¬ tion of east and west, and th&^tratum which is worked at present, appears to be about 14 feet wide ; so little change has as yet taken place in the course of the vein, that there is every appearance of its improving, as they proceed farther from the surface : with only fifteen workmen, they can raise at present, from ten to twelve chaldron of coal per dayj besides keeping the mine free from water, from which they suffer little inconvenience. The character of Pihode Island Coal, is as follows : Its colour is black, or greyish black, with a metallick lustre, it soils the fingers ; its fracture is slaty, but its cross fracture is conchoidal, and the sides of its natural divi¬ sions are sometimes covered with a ferrugi¬ nous earth. It burns slowly, producing an intense heat, without smoke, and with a ve¬ ry light lambent flame ; but emits no sul¬ phureous or bituminous vapour, and, when ■7 perfectly burnt, leaves a very small quanli-' ty of grey ashes. The unconsumed particles of it, retain their original colour and lustre. , Specifick gravity from l,4o0 to 1,750 From the above description, little doubt can remain of the true character of this Coal; but in order to ascertain with precision the quantity of ingredients which it contained, I examined it according to the rules so ably laid down by Kirwan, and as my object was principally to determine the proportion of carbon which it contained, as the substance upon which all its good qualities, depend, I repeatedly deflagrated it with certain propor¬ tions of nitre, and uniformly found, when the experiment was made with proper attention, that 100 parts of coal,contained from 90 to 94 of carbon ; and in order to compare it in this respect, with the charcoal in common use here, 1 found that it required more charcoal to saturate a given proportion of nitre, than it did of Rhode Island Coal. These exper- imeqts were also confirmed by submitting 100 grains of the Coal loan intense heat in a crucible, which, after five hours, were re¬ duced to six grains of ashes ; those ashes, which consisted, perhaps, of an oxyd of iron and an earth 1 had not leisure to examine; nor was it of much consequence in the main object which 1 had in view, which was, to 8 ascertain the qualities of the coal, as an arti¬ cle of fuel. The follo_wiDg table of the relative pro¬ portion of carbon, which it bears to some other mineral coals,maynot be unacceptable. loo parts of Carbon. Bitumen. Ashes. Sp. Grav. Swansea, 74 22 4 1, 357 SVhitehaven, | 41 2 1, 257 Newcastle, Rhode Island, 58 40 2 1, 71 94 — ' 6 1, 7d0 Kilkenny 1 97 — 3 1, 526 Anthracite 7 I of Hauy 5 j 64 - 36 1, SOO Thus it appears that this coal is nearly a pure natural carbon or charcoal, resembling, in many of its properties,the Anthracite of Ha- and approaching as nearly as possible to the description of Kilkenny Coal, but superi- our to the former, as containing vastly more carbon, and much to be preferred to the lat¬ ter, as it contains neither pyrites or sul¬ phur, substances which render that coal pe¬ culiarly disagreeable fordomestick purposes. Though coal is so profusely distributed in different parts of the earth, yet there is no substance which differs more in its nature and qualities, a knowledge therefore of the ingredients which each species contains, is 9 necessary, in order to appiy it to the pur¬ poses for which it is best adapted.. In such a country as this, where the inhabitants are so, long accustomed to the use of wood for fuel, it is not surprising that much ignorance should prevail on this subject, and that pre¬ judice in favour of what they have been ac¬ customed to, should operate strongly against the introduction of a more oscononiical, and, in many respects, a more convenient substi¬ tute. To point out therefore, in this place, the distinctions between the different spe¬ cies of coals, the various uses for tvhich each of them are designed, and the particu- .lar purposes to which Rhode Island Coal may be applied with advantage, will not, I hope, be generally unacceptable. The two points which are principally to be considered with respect to Pit Coal, are, first the intensity of the heat which it emits, and secondly, the duration of its combus¬ tion. Coals which .abound in bitumen, maltha, or petrolium, such as Whitehar’en, Newcastle, and some of the Virginia Coal, burn quickly and briskly \vitb considerable' flame and smoke. They may generally be distinguished by their low specifick gravity’, and when bitumen or maltha prevails, a sort of semifusion occurs, which causes them to cake and swell, producing a cohesion on 10 their surface ; this interrupts a free circula¬ tion of the air, and renders it necessary that the substance should be broken in order to keep up the combustion. Common bituminous Coal is certainly what is generally used in England. It usu- ally contains from 30 to 40 per cent, of nap¬ tha or bitumen ; but though the presence of these volatile substances does not injure the qualities of the coal for domestick life, yet they render it unfit for use, when in its natural state, for many purposes where sul¬ phureous or bituminous vapour would be injurious, and where its tendency to caking or cohering, would interrupt'the current of air, and create great irregularity in the tem¬ perature of. the fire. I.i order, therefore, to deprive it of these volatile ingredients, it is first charred, and by this means converted into Coak, a substance resembling charcoal in manj' of its properties and in every respect nearly similar to Rhode Island Coal. In this state, Coak gives a ve¬ ry intense and durable heat without flame, and is in general use for blast or wind fur¬ naces ; but it is much less pure than char¬ coal-; it requires a greater draft of air, and is more apt to vitrify; though in one respect, this, as well as Rhode Island Coal is to be 11 preferred ; as it bears the blast better, andj when urged by a strong blast, is not so easi¬ ly blown away, nor does it consume so rap¬ idly. I have thus given a short view of the different species of Coals. It is the business of th?artist or the manufacturer to inform himself of their qualities, before he can adapt them to their different uses. For all general useful purposes, it will appear, that Coals which contain the most carbon, and the least sulphur or bitumen, which burn slowly, and produce an intense heat, leaving but a small residuum, are the most valuable and OBConomical. From the above descrip¬ tion and analysis of Rhode Island Coal, it will be seen, that it comes nearer to the properties of pure carbon or charcoal, than most others, and of course that, for most purposes in which charcoal is used, it is equally applicable, and, for many, it is great¬ ly superiour. I shall now endeavour to point out concisely, and without prejudice or par¬ tiality, the various purposes to which Rhode Island Coal may be applied, as well as those to which it appears to be inapplicable, con¬ cluding with some observations on the most eligible method of using it. The manufacture of iron has become so general and extensive over the continent of America, that it has, perhaps, more than any other circumstance, contributed to raise tlie price of fuel ; and, should it continue to in¬ crease, the woods of the country cannot long afford a sufficient supply, in situations where such works can be carried on with the great¬ est advantage. Many of the most valuable mines must therefore be neglected ; in the neighbourhood of Rhode Island in particu¬ lar, this has already been the case; and, though abounding in iroh ore, the scarcity of fuel on the spot has discouraged the man¬ ufacture of it. It therefore requires but little argument to shew the advantage that may be taken of this discovery. The Rhode Island Coal is peculiarly calculated for the smelting of iron ore ; it bears the blast remarkably well, and, having no tendency to vitrify in the furnace, besides producing an intense heat, it may be applied with more oeconomical views to this purpose, than charcoal. And as the arts progress in this country, and iron from "its crude state is manufactured into steel, this coal may be used to advantage, as it seems to possess the peculiar qualities ne¬ cessary for the manufacture of this article. 13 Steel being nothing more than bar iron, im¬ pregnated with a large proportion of carbon, either by fusion or cementation, it naturally follows that this coal, which consists princi¬ pally of carbon, is as well calculated as pos¬ sible, for the conversion of crude iron into so. useful an article. :ror the burning of lime, Rhode Island Coal will also be found an useful substitute for-wood. The steady and uniform heat which it gives, renders it superiour to wood for this purpose, as when properly applied, all parts of the: kiln will receive equal de¬ grees of heat, and the lime will, of course, be burnt equally, without subjecting some parts of it to vitrification, while others are not affected by the heat, which is often the case in the general method of using wood for the purpose. In all those processes which require a slow and uniform degree of temperature, such as evaporation, this species of coal is to be preferred, and I cannot, at present, -point out one to which it is more applicable, than the- manufacture of salt, an article of the.first necessity, and to which, America will, at some future period, find it necessa¬ ry to pay more attention. in general, for every species of furnace but the reverbatory, this Coal is well qualified, ,provided the grates are so constructed as to give a sufficient draft of air, without which it cannot be properly ignited. This, however, with the knowledge which we possess here, of the principles of combustion, is a matter of little difficulty; and the cir¬ cumstance of its never caking, or adhering in cohesive masses, as well as its affording so little ashes to choak the grates, renders it extremely convenient and ceconomical, when once it is perfectly ignited, the fire is more durable than any other coal, and it re¬ quires less attention. With these qualities, it is obvious that it is well calculated for breweries and distil¬ leries ; for the purpose of drying and pre¬ paring malt, no other species of coal will an¬ swer so well, as almost all others contain so much sulphur, or other volatile substances, that they cannot be used without destroy¬ ing its flavour. This fact is so well under¬ stood, that the malsters, even of America, have hitherto found it necessary to import Kilkenny Coal, at a prodigious expense, for no other purpose but the use of the malt iiJn. 15 The smith will find considerable saving when he becomes accustomed to the use of Rhode island Coal. I am perfectly aware that it is not calculated for every purpose of the forge, and that, as it cannot be brought to cake or adhere, it will not answer on those occasions, where what is called by the smith a hollow fire, is required ; but still, for small work, and all the common purpos¬ es of the forge, it will be found sufficiently well adapted, and it has already been used with success by many of the smiths in the neighbourhood. I cannot at the same time omit stating, that the brazier, the bell found¬ er, and those who are engaged in the cast¬ ing of metals, will perceive the great supe¬ riority which this Coal has over others. The intense and durable heat which it affords, renders it an article peculiarly valuable to artists of this description. For the burning of bricks, and the man¬ ufacture of earthen ware and all sorts- of pottery, such Coal as this is particularly convenient. The total absence of all smoke or vapour, renders it an article of conse¬ quence, in particular for the finer kind of ware. But the same circumstances that make it most eligible for such manufactures, ren-. 16 der it unfit for the reverbatory furnace, which is used in refining a variety of metals, as well as for other purposes. No fuel be¬ ing adapted for such furnaces, but those which produce considerable flame and smoke, such as the Virginia Coal, or \vood, as the principles upon Which these furnaces are erected, requires that the flame only should traverse the surface of the metal, without any part of the fuel being in coti- tact with it. Having no doubt myself of the benefit tVhich this country may derive froni the more general use of an article so well adapt¬ ed to the purposes wdiich I have hinted at, I can, without hesitation, recomrnend it to the serious attention of artists and manufac¬ turers, particularly to those vvbo are situat-, ed in the neighbourhood of large cities, where wood is gradually becoming aii arti¬ cle of considerable e.^rpense, and I cannot conclude this part of the subject, Without expressing my most decided conviction, that those who will give this Coal a fair tri¬ al for culinary purposes and doraestick use, Will be forced to acknowledge that it has many advantages. ' 1 am perfectly aware, that such a propo¬ sal will meet with many objections. The IT prejudice arising Trom long and eal'ly habits, it takes some time to remove." So deeply- rooted even are these, that 1 have heard it doubted by many, whether it was possible to make such a fire with Coal, as would an¬ swer the purpose of cooking. Such preju¬ dices are not confined to any country ; the Englishman has the same doubts with re¬ spect to the qualities of wood. But as these doubts arise from perfect ignorance of the true mode of using either of diese arti¬ cles, so are they removed, when each party obtains a more correct knowledge of what the other has discovered by experience. Those, who are at length persuaded that this, or any Coal, can be made to burn in common grates, will ne.xt inquire, what are its advantages over wood, before they resign an article to which they are accus¬ tomed, and with which they are perfectly satisfied ; to this 1 shall concisely reply, as follows ; and upon this answer I rest its merits. First: Such Coal as this, when proper¬ ly ignited, gives a more steady, intense and durable heat. Secondly : It is more ceconomicai, pro¬ duces no disagreeable efiluvja, and requires none of that attention to the frequent re- b2 18 newal of the fire, which is so necessary in ihe use of wood ; arid, Thirdly, from its emitting rid sparks, and from the manner in which it burns, produc¬ ing neither flame or smoke, rnany of those accidents arising from fire, to vvhich chim- nies, stores, and dwelling'houses are liable from the general use of wood in large citieS, would by this means be avoided. I shall add but one bifcumstarice more, which should, perhaps, have some weight ih this country, though the fact riVay be re'ceiv- ed with, hesitation by the gehefality of readers,'yet it has been asserted by medical men arid philosophers, that the Use of this article for fuel iri England, has contribute'd to check that tendency to contagious dis¬ eases, which was at one time so prevalent in their large cities; and Dr. Mitchell, a celebrated philosopher and senator of'Ariier- ica, has endeavoured to explain it, ori prin¬ ciples connected with established theories in chymistry. It now only remains for me to rnake a few observations on the best method of us¬ ing this Coal ; and I must confess, that I have heard so many difficulties started on this subject which have no grounds Whatev- 19 Ter, that it is with some hesitatioa I attempt to remove theni. Well informed and enlightened men will easily underStahdi that such coal,as ibis-, when properly ignited, must possess all the qualities of carbon. To such per¬ sons 1 cannot always appeal, and as the dif¬ ficulty of igniting this substance is much greater than that of charcoal, liiany are dis¬ posed to doubt that it has any advaiitage; all, hovVever, that is' required, is, that the furnace or grate should have a strong draft, and that a little niore patience is bestowed in kindling the fire, than is usually afforded by thoSe, who are accustomed to the burning of wood. The coal should be broke into small pieces, and a proportion of charcoal placed under it; when this is set fire to, the draft of the flue should be increased by proper 'management of the door or register of the furnace, or by blowers applied to the chimney. In a Short time the whole is ig¬ nited ; it never requires stirring, and no fur¬ ther trouble is neceseary but to keep the lower bars of the grate free from ashes, or any substance that would interrupt the free circulation of air. A fire made in this man¬ ner, will continue to produce considerable heat for six or eight hours without a renew- £0 al i)i f. , ...,! ■ Gii!y an occasional atten¬ tion to k-'.-;. iij'.'lie draft of the flue. I have tiius bt-en lead into a more de¬ tailed view of thesid>jcct of this Essay, than I originally.intended. Conscious that it af¬ fords a field for a much abler pen, 1 should, perhaps stop here, but my excuse must be found in an anxiety to direct the attention to the encouragement of those manufac¬ tures, for which the present state of this country is peculiarly calculated. I should pay but an ill compliment, indeed, to the American character, were 1 not freely to ac¬ knowledge, that for talents and genius there can be none superiour. The same spirit of enterprise which has led th^m to the suc¬ cessful pursuit of commerce, will naturally induce them, at a proper season, to turn their attention to those arts and manufac¬ tures, which are best suited to the skill of the inhabitants, and are most intimately connected with the necessities of the country. It will readily be allowed, that the dif¬ ferent branches of manufacture which are pointed out in these pages, are objects of the first consequence. The materials are obtained in abundance, and no greater pro¬ portion of labour is required, than in the 21 present state of population can be spared from other pursuits; they have also this ad* vantage, that they have already been tried and succeeded. Premature attempts to divert thechan- nels of commerce, as well as to excite a ri- valship in manufactures, however plausible they may appear in the reasoning of a phi¬ losopher, experience has shown them to be erroneous in theory,, and dangerous in practice. That species of industry, which has.al- ready succeeded, which has contributed to the wealth and prosperity of the country, which encourages a spirit of literature, and pro¬ motes the diffusion of knowledge, should not be rashly abandoned, for speculations, founded on false views of the real interests of the nation.