FMEFAVE^ The favourable reception given by the public, to an Essa^ on the Warming of Mills and other Buildings hy Steam^ which I pub¬ lished in 1807 *, and the many additional facts on the subject, which, since that period, have been determined, and the further application of this agent to drying as well as heating, in various processes in calico-printing and odier manufactures, have induced me to think of publishing an enlarged edition of that Essay. Reflecting on this subject, and consider¬ ing the materials I had collected on other practical applications of heat, it occurred to me, that I might extend my plan to a series of Essays on the Economy of Fuel and Management of Heat. • For an account of this Pamphlet, see Philosophical Magazine, Nicholson’s Philosophical Journal, Monthly Magazine, and various other periodical publications for 1’808. a 8320 PREFACE. iv In order to clear the way for these prac¬ tical inquiries, it seemed proper, to give such a view of some of the principal laws which regulate the phenomena of heat, as would, by the help of references, enable the reader the better to tmderstand the nature of the facts and observations which.-would occur, in the. subsequent parts-bf these in¬ quiries. To this, purpose, I have aceord- ingly devoted the first part of this .Essay. • Originally, I had no intention to make this introductory part’ so large as it now is, but in pursuing the subjects which it contains, it appeared to me, that to em¬ brace the objects of my intention, it could not easily be made less. It would, per¬ haps, not conduce to my credit as a writer, were I to tell the trouble this part has cost me; and, rfter all my labour, I fear it will be thought by many, a mere, compilation. But I -was rnore an^pus to make, a useful than an elegant book, .and, therefore, have attempted, in a small compass, to bring into vievsr, all the practical knowledge that I could find on subjects, which I thought PREFACE. could be beneficial to a valuable class of men, whose time, being otherwise, fully occupied^ have neither' Irisure, opportunity, nor inclination, to search into numerous, and often: costly volumes. If I have suc¬ ceeded in this intention, my labour has not been in vain. Nor will general readers, I trust, deem this part altogether unworthy their notice,' having : endeavoured in it, to give a concise view of the. late .important discoveries made by Professor Leslie and others, respecting, heat. The opportunities which I have had, of conversing and corresponding with several of these writers, as well , as-.with other men of science, .whose pursuits have been more immediately practical, I have endeavoured to turn to the advantage of the. reader. In the “ Additions and Corrections,” I have studied to correct such errors or mistakes as' have occurred in die course of this Essay. The advantages which this island enjoys over other countries, from the abundance PREFACE. vl of coal, are too well known to require to be here enumerated. But in many other things we labour under much disadvantage, which should stimulate us to cherish this superiority which we enjoy over the nations on the Continent of Europe. The economy of fuel becomes a subject of increasing importance, from the' increasing price of labour, which would require exertion to counteract its effects on our commerce and manufactures. Every attempt, therefore, to save fuel, merits attention j and the subject opens a wide and important field for investigadon. It is not the saving only of fuel which merits attention, but its safe^ easy^ and healthful application to the various pur¬ poses of life. .The recent destruction by fire, of St. James’s Palace, and of the two largest Theatres in - the kingdom, has directed much of the public attention to the ren¬ dering of buildings less subject to so dreadful a calamity. In this important respect, no means of heating buildings has yet been devised, so good as that by steam, and from its novelty, none is yet so parr tially known or understood. I have, there¬ fore, been induced to make it the princi¬ pal subject of this Essay. It consists of Three Parts, the first of these I have already mentioned. The Second Part relates to the application of steam to the heating of buildings of vari¬ ous descriptions, such as dwelling-houses, manufactories, arid public buildings. The Third Part treats of the application of this agent to drying of goods, as well as to further naatters relative to heating. Its excellent efiect in preserving, brilliancy of colour, in drying goods, is there proved by strong facts;—a consideration of much importance in many of our manufactures. I must crave the indulgence of the pub¬ lic, for any want of tmity, and other im¬ perfections, which will too readily appear in the whole of this Essay. I have to plead, that it was written at many differ- PREFACE. vili ent and distant intervals, occasioned by interruptions from professional engage¬ ments, as well as from , other and more irksome causes, with a detail of which I shall not trouble die reader. With regard to the subject of heating by steam, I beg leave here further to re¬ peat the Preface to the Publication to which allusion is made at the beginning of this introduction. “ In a country like Britai -., where man¬ ufactures ai'e more generally collected and combined in large establishments, than dispersed through individual dwellings; the production and diffusion of the warmth necessary for the health and comfort of the workmen, as well as for the prosecu¬ tion of the different processes, become objects of the first national importance. “ The excessive expense of insurance, arising from the combustible nature of the materials of the cotton manufacture in par¬ ticular; the great difficulty of retrieving the PR-FBACE; ix injury resulting to a well established busi¬ ness, from the accidental destruction of machinery; and the frequent alarms from fire, in our powder-mills, arsenals, and dock-yards, furnish the strongest economi¬ cal, as well as political recomniendations; for the more general employment of steam for the purpose of warnilhg bitildings; “ The very, limited degree in which steam has yet been applied to this pur¬ pose, might surprise us, did we not recol¬ lect, that the steam-engine itself, although known, perhaps, even before the time of the celebrated Marquis of Worcester, has only, within a very few years, by the ingenious improvements of Mr, Watt, been extensively introduced. The fre-. quent and varioususe, of steam, , to which Mr. Watt’s improvements have given rise, in different departments of manufac¬ ture, have furnished accidental results of great value, which ai'e frequently little known to the merely scientific inquirer. PREFACE. “ THe observations which the Author has been enabled to make, on various con¬ trivances throughout the kingdom, for heating by - steam, modified by his own experience, have led him to believe, that the following remarks on this important subject, would not be altogether undeserv¬ ing the notice of the public. “ He, however, lays no claim to origin¬ ality, nor does he pretend to give informa¬ tion to men of science, his object is merely to make such a collection of facts, as may be useful to those who wish to put in practice the warming of buildings by “ In making this collection, he has been much indebted to the assistance of some friends, without the aid of whose ingenu¬ ity and experience, his readers would have had still more reason to lament its defi¬ ciency. “ Those who are most qualified to esti¬ mate the importance of such investigation, PREFACE. s:i can best appreciate their difficulty, and will, most readily, and candidly, pardon the unavoidable imperfection o£ this at¬ tempt; the chief object of which, is less to satisfy curiosity, than to direct the atten¬ tion of the; public', to the farther prosecu¬ tion of an inquiry, not less curious: than useful.” I shall now proceed to give an account of the origin and progress of this applica^ tion of steam, Jn Acc/omt. of the. Origin and Progress of the. Application of Steam^ to. the purpose of Heatr. ing Bi tidings. In the Philosophical Transactions for the year 1745^ Colonel William Cook suggests the idea of warming rooms by steam. But it does not appear that he ever attempted to reduce it to practice. And although Count Rumford, in the third-number of the Journals of the Royal Institution, men¬ tions, that “ this scheme- has frequently “ been put in practice with success, in this “ country, as well as on the Continent,” b ■ I have not been able to learn, that any thing of importance was done, previously to the use of steam in warming cotton- mills* It is natural to suppose, that Mr. Watt’s attention to other applications of steam, would lead him to the consideration of the particular subject of heating buildings. Such was indeed the case. The period at which he used steam for warming the room in which he commonly wrote, was 1784, or 5, probably the winter between these two years. The room was about 18 feet long, by 14 feet wide, and feet high; and the apparatus consisted of a box, or heater, made of two side-plates of tinned iron, about 3i feet long, by 2i wide, kept at the distance of an inch asunder, by means of stays, and joined round the edges by other tin-plates. This box was placed upon its edge, near the floor of the room, and. furnished with a cock to let out the air, and with , a pipe, proceeding from its A patent for heating By steath tras granted to John Hoyle, dated 7th Wyi 1791; and to Joseph Green, dated 9th December, 179S. PREFACE. XIU lower edge to a boiler in an under apart¬ ment, which pipe served , to convey the steam, and return the water. , The effect produced by ,this apparatus, was less than Mr. Watt had calculated, which, perhaps, may now be .explained by Professor Leslie s experiments .on the heat transmitted by polished surfaces. Mr. Boulton heated a room in his man¬ ufactory by steam, soon after this time; but the very infirm state of his health at this moment, prevents me from obtaining accurate information concerning it He, however, heated his bath by steam, a few years later, I believe about the year 1789, which he continued to do from that period, until a very short time ago. Towards the end of the year 1794, he assisted the late Marquis of Lansdown, to improve an apparatus, erected by a Mr. Green, for warming his library, by means of air heated by steaui; but the use of it was afterwards abandoned, owing, I be- • This w.as written previonriy to Mr. Boulton’s death. 51V PREFACE. -lieve, to some defect ia the pipes or joints. About a twelvemonth later, in the winter of 1795-6, Mr. Boulton directed the erec¬ tion of a similar apparatus, for his friend Dr. Withering’s library, which, in point of;.heating, answered perfectly; but the pipes being ^nade of copper, and soft sol¬ dered in some places, the smell of the solder was rather unpleasant to the Doctor, who was then in an infirm state of health with diseased lungs. The apparatus was, k consequence, removed to Soho, where Mr. Botdton proposed erecting it in his own house, in which he was making al¬ terations about this time, and had it in view, to heat every. room in the house ^by steam. A boiler was put up for that pur¬ pose, m one of the ceUaxs, but some cir- cmnstances occurred, to prevent his con- tinuing the plan. The subject, however, underwent frequent discussions, and the diSerent modes of efiecting it, were amply considered by Messrs. Boulton and Watt, as was known to many of their friends, no secret having been made, either of cal¬ culations of surface, or of the modes of applykg them. PREFACE. XV About the end of the year 1799, Mr. Lee of Manchester, having a large increase of his cbtton-rmill in view, consulted with Messrs. Boulton and Watt, relative to the best mode of heating it by steam; and, in the course of the subsequent year, he erected his present apparatus of cast-iron pipes, acting also as supports to the floor, which answered perfectly, and was, both in'point of the materiais used, and of the construction adopted, as far as I know, the first of the kind.. I may add, that though the construction has been frequently inii- tated by others, I have never heard of any material improvement having been made upon it., from that period, many appara¬ tus were constructed, by them, in some of which, applied to old buildings, the pipes were conducted horizontally through the rooms, with other variations of little im¬ portance. It may not be improper here to add, the vats, &c. of the dye-house of Messrs. Wormauld '& Gott, of Leeds, were heated by steam, under the direction of Messrs, xvi PREFACE. Boulton & Watt, in the year 1799. The apparatus was planned in August of that year, and set to work either in the course of it, or early in the succeeding one. The history of that establishment has been very incorrectly given, in the Journals of the Royal Institution, for iSOl. The merit of the first application of steam, to the heating of buildings in Scot¬ land, belongs to Mr. Snodgrass. He in¬ troduced it* into the cotton-work, which Messrs., Dale & M‘Intosh established on the banks of the Spey f. Soon after this period, Mr. Houldsworth of Glasgow, used it with great success. His example has been followed by several other respectable cotton-spinners. Steam was soon afterwards applied to warm buildings, appropriated to the pur¬ poses of calico-printing. Mr. Richard • In the year 1799, and, there is reason to think, without the know¬ ledge of what had been done in England. + See Philosophical Magazine for March, 1807. PREFACE. xvii Gillespie, in his calico-works at Anderston, was induced very early to use it in his warehouse for finished goods, and has ' since been gradually extending it through other parts of his works*. It has also been adopted by some calico-printers in England. Messrs. W. Stirling & Sons are at present getting steam apparatus fitted up for their extensive calico-printing works at Cordale, In Ireland, Messrs. Orr have introduced it at their works, at Stratford upon Slainy. It is also gradually finding its way into the cotton-mills in that kingdom. Messrs. Oakley & Co. cabinet-makers, London, have heated their premises by Steam; and Messrs. James Ballantyne & Co. have applied it to the heating of their printing-ofiice in Edinburgh. * In the introduction to the Third Part of this Essay, there is a narrative respecting the application of steam to the purpose of drymi. TABLE OF CONTENTS. ,#att jfirst ON THE EFFECTS OF HEAT, MEANS OF MEASURING IT, FUEL, &c. SECTION I. 1. Before proceeding'to the more prac¬ tical parts of the economy of fuel, in order to establish our inquiries on solid grounds, it will be proper here, to take a view of some of the principal laws which regulate the phenomena of heat. . A 2 EFFECTS OF HEAT. The most eminent philosophers of the present age, are not yet agreed respecting the nature of heat, nor can any of them yet give to a plain inquirer a satisfactory an¬ swer to this simple question. What is heat? While some consider it as merely a state or condition of which all bodies are susceptible; others conceive that heat is a material sub¬ stance—raxi elastic fluid, extremely subtile and active. I shall not take up the reader’s time, by attempting to investigate the merits of those opinions, since it is of no consequence to our present purpose, which of the parties is in the right. But although we may not be able to comprehend the nature of heat, we may amve at the knowledge of many of its ^ects, and so classify and arrange these, as to adapt them to many ustful purposes in common life. EFFECTS OF HEAT. OF HEAT. 2. The term Aeai, as used in common language, is ambiguous, being applied to express either a certain sensation.^ or the ex¬ ternal cause which excites that sensation. It is in this last sense only, that we are at present to consider it; and to this meaning of the term heat., the authors of the New' French Chemical Nomenclature, have given the definite name of caloric *. 3. “ When all surrounding bodies are of one temperature, then the heat attached to them is in a quiescent state; the absolute quantities of heat in any two bodies, in this case, are not equal, whether we take • “ The term caloric has been adopted in the New Nomenclature, to avoid that ambiguity and misconception which might, it is said, arise from employing- the same term to express a substance, and the sensa¬ tion produced by the action of that substance. By the same mode of reasoning, all the sutilantha should be changed, in any language that has similar -peril. But suppose the argument, for change, in the pre¬ sent instance, to have full force in some languages, it has little or none with regard to the English, which employs the word loarmth to express the sensation occasioned by heat. I shall, however, use the terms heat and caloric indifferently.” Tilheh's Phileiophieal Magazine, vol. 8. p. 71. 4 EFFECTS OF HEAT. the bodies of equal weights, or of equal bulks. Each kind of matter has its peculiar affinity for heat, by which it requires a certain portion of the fluid, in order to be in equilibrium with other bodies at a cer¬ tain temperature Thus, when the heat of a room is increased, the various bodies contained in it will attract and retain dif¬ ferent quantities of heat. This property seems to indicate the materiality of caloric, since, though in a quiescent state, it exists in bodies in difierent proportions, modified neither by their density nor form, but by some innate and peculiar force of attraction, resembling chemical affinity. To express this faculty, the term capacity for heat was invented, and employed by the British philosophers; the name specific caloric being used for the same purpose, by ^ose on the Continent. However various the capacities of bodies for heat may be, yet, in consequence of the perfect elasticity of this power, it will speedily acquire the same tension in them * Dalton’s Chemical Philosophy, p. 2. EFFECTS OF HEAT. 5 all; or, like a number of tubes of different magnitudes, but narrow apertures, plunged into the same vessel of water, it will soon stand in each at the same height or level, though the absolute quantity in them be very different. Now, it must evidently be a desirable object, with the philosopher, to obtain some means of estimating this tension, or height, or degree of tempera¬ ture, as it is technically termed. • Of Tltermometers. 4. The thermometer was invented early in the 17th century, but, like many other useful contrivances, its real author has never been ascertained. The first form of this instrument was the air thermometer^ The air was confined in a tube by means of some coloured liquor, and the liquor rose or fell in. the tube, accordingly as the air became expanded or condensed. It was found, however, to be very defective. The expansion of spirit of wine was next used, but still thermometers had a great defect; the scale did not commence at any Jixed 6 EFFECTS OF HEAT. point. While they laboured under this disadvantage, they could not be of general use. The subject which next drew the atten¬ tion of philosophers, was to obtain some fixed unalterable points, by which a deter¬ minate scale might be formed, so that all thermometers might be accurately adjusted to one standard. These important points, on which the accuracy and value of the thermometer depends, although previously discovered by Dr. Hooke seem first to have been practically applied by Sir Isaac Newton. He chose, as fixed, those points at which water freezes and bods; the very points which the experiments of succeeding philosophers have determined to be the most fixed and convenient. Sir Isaac Newton used lintseed oil in his thermom¬ eter, which was constructed in 1701. 5. Oil, however, was found to have many imperfections. At length a different • Dr. Robert Hooke discovered the pennaneccy of the temperature of freezing in 1664, and of boiling water in 1684. EFFECTS OF HEAT. fluid was proposed, by which thermometers could be made free from most of the defects alluded to. This fluid was mercury, and seems first to have occurred to Dr. Halley, about the end of the 17th century, but was not adopted by him, on account of its hav¬ ing less expansibility than the other fluids then in use for thermometers. The honour of this invention is commordy given to Fahrenheit of Amsterdam, who presented an account of it to the Royal Society of London, in 1724. 6. Fahrenheit’s thermometer consists of a slender cylindrical tube, and a small bulb. To the side of the tube is annexed a scale which Fahrenheit divided into 600 equal parts,, beginning with that of the severe cold which he had observed in Iceland, in 1709, or that produced by surrounding the bulb of the thermometer with a mix¬ ture of snow with sal-ainoniac, or with sea-salt. The point at which mercury be¬ gins to boil, he made the other limit of his scale. By trials, he found that the mercury stood at 32“ on his scale, when snow or 8 EFFECTS OF HEAT. ice just begins to thaw, which was, there¬ fore, called the freezing point. When the tube was immersed in boiling water, the mercury rose to 212°, which was, therefore, denominated the boiling point.^ and is just 180° above the freezing point. 7. But the present method of making these thermometers, is to immerse the bulb in melting ice or snow, and mark the place where the mercury stands with the num¬ ber 32°, then immerge it in boiling water, and again mark the place where the mer¬ cury, stands in the tube, which indicates the position of 212°. Dividing, therefore, the intermediate space into 180 equal parts, will giye the scale of the thermometer, and which may afterwards be continued upward and downward at pleasure. 8. These fixed points are now universally chosen for adjusting thermometers to a scale, but it is well known that the point at which water boils is not invariable. It varies some degrees, according to the weight and temperature of the atmosphere. EFFECTS OF HEAT. 9. In order, therefore, to insure uni¬ formity in the construction of thermom¬ eters, it is now agreed, that the bulb of the tube be suspended in the steam when the water boils violently, the barom¬ eter* standing at 30 English inches, which is its mean height round London, and the temperature of the atmosphere 55° f. 10. Fahrenheit’s thermometer is now universally used in this kingdom. See Fig.i: The centigrade thermometer, or that of France, since the Revolution, places Zero, or 0, at the freezing point, and divides the range between it and the boiling point into, 100°. This has been long used in • I suppose the reader to he previously acquainted with the doctrine ef the frtssarc of the atmoifihcre, and the construction of the barometn'. If not, as it is necessary to the right understanding of the following parts of this Essay, I beg leave to refer to Gregory’s Mechanics, voL 2. p. 112, or almost any other of the elementary Treatises on Natural Philosophy. f See the Report of the Committee for adjusting Thermometers, Philosophical Transactions, vol. LXVII. B 10 . EFFECTS OF HEAT. Sweden, under the tide of Celsius’s ther¬ mometer. See Fig. 2, 11. Reaumur’s thermometer, which was formerly used in France, divides the space between the freezing and the boiling of water, into 80 degrees, and places the Zero at the freezing point. Fig. 2, 12. Mr. Murray has suggested a scale which, he conceives, wotdd be much more convenient than that of Fahrenheit. He uses, as fixed points, those of the freezing and boiling of mercury, and divides the intermediate space into one thousand parts, or degrees *. See Fig. 3. 13. The expansion which is observed in a mercurial thermometer, is, in reality, only the difierence of expansions of mer¬ cury and of glass. 14. It has long been supposed, that the egual divisions on Fahrenheit’s scale, did Murray’s Chemistry, voL i. p. 15S. EFF-ECTS OF HEAT'.' 11 not point out the real equal increments (or degrees of equal increase) of tempera¬ ture. This circumstance was not over¬ looked by Dr. Black, who illustrates it in the following manner: “ If a string be stretched, by suspending a nioderate weight to it, and we add one pound to that weight, we shall make it a little longer j but by adding a second pound, we shall not add as much more to the length of the string as the first pound added, nor will a third pound produce so much effect as the second pound. In like manner, we can imagine, that when a thermometer receives a series of equal ad¬ ditions to its heat, these may not produce equal increments of expansion; and, there¬ fore, that equal increments of expansion may require for their production, incre¬ ments of heat, very unequal among them¬ selves. This question has been over¬ looked, or little attended to, by some of the principal writers on thermometers. It does not appear to have occurred to Dr. Boerhaave, and Dr. Martin gives very little attention to it. I began to attend to it, 12 EFFECTS OF HEAT. and made an experiment to decide it in the year 1Y60, and did not then know that others' had thought of it; but I soon learned, that Boyle, Renaldini of Padua, Wolfius, Dr.- Halley, Sir Isaac Newton, and Dr. Brook Taylor, had severally given, their opinions or doubts concerning this question*.” The result, however, of. Dr. Black’s inquiry was, “ that equal additions, or abstractions of heat, produced equal varia¬ tions of bulk in the liquor of the thermom¬ eters employed by him, and, therefore, that the scale of expansion was also a scale of heat f, or, at least, that, there was but " a little deviation from the exact propor¬ tion^’ “ M. De Luc,” says Mr. Dalton, “ found that in mixing equal weights of water, at the freezing and boiling temperatures, 32* and 212°, the mixture indicated nearly ■ • Vide Black’s Lectures, vol. i. p. 56 and 57. f Black’s Lectures, vc!. i. Preface, p. axxix. EFFECTS OF HEAT, 13 119® of Fahrenheit’s thermometer, but the numerical mendj. or average, is 122°. If he had mixed equal bulks of water at 32® and 212°, he would have found a mean of 115V’ 15. “ It is not improbable, that the true mean temperature between 32° and 212°, may be as low as 110° of Fahrenheit*”. We are indebted to Mi'. Dalton, for farther investigating this intricate subject, and he has formed a. scale which, he con¬ ceives, will correspond with the increments of heat; and, as this is an important part of our subject, I shall here give some extracts with relation .to it, from his late valuable publication. 16. “ In the present imperfect mode of estimating temperature, the equable expan-- sion of mercury is adopted as a scale for its measure. This cannot be correct, for two reasons: 1st, The mixture of water of .* Dalton’s Chemical Philosophy, p. 7. 14 EFFECTS OF HEAT. different temperatures, is always below the mean by the mercurial thermometer; for instance, water of 32° and 212° being nuxed, gives 119° by the thermometer; whereas, it appears, from the preceding remarks, that the temperature of such mixture ought to be formd above the mean 120°. 2d, Mercury appears, by the most recent experiments, to expand by the same law as water, namely, as the square of the temperature from the point of greatest density. The apparently equal ex¬ pansion of merctuy, arises from bur taking a small portion of the scale of expansion, and that at some distance from the freez¬ ing point of the liqvsid. 17. “ From what has been remarked, it appears, that we have not yet any mode, easily practicable, for ascertaining what is the true mean between any two tempera¬ tures, as those of freezing and boiling water; nor any thermometer which can be considered as approximating nearly to accuracy. EFFECTS OF HEAT. 15 18. “ Heat is a very important agent in nature; it cannot be doubted, chat so active a principle must be subject to general laws.. If the phenomena indicate otherwise, it is because we do not take a sufficiently com¬ prehensive view of them. Philosophers have sought, but in vain, for a body that should expand uniformly, or in arithmeti¬ cal progression, by equal increments of heat; liquids have been tried, and found to expand unequally; all of them expands ing more in the higher temperatures than in the lower, but no two exactly alike. Mercury has appeared to have the least variation, or approaches nearest to uniform expansion, and on that and other accounts, has been generally preferred, in the con¬ struction of thennometers. 19. “ Some time ago, it occurred to me as probable, that water and mercury, notwithstanding their apparent diversity, actually expand by the same law, and that the quantity of expansion is as the square of the temperadire, from their re¬ spective freezing points. Water very 16 EFFECTS OF HEAT. nearly accords with this law, according to the present scale of temperature, and the Jitde deviation observable, is exactly of the sort that ought to exist, from the knovfs, error of the equal division of the mercurial scale. By prosecuting this in- quifyj I found that the mercuri^ and water scales, divided according to the principle just mentioned, would perfectly accord, as far as they were comparable, and that the law will probably extend to all other pure liquids, but not to hetero¬ genous compounds, as liquid solutions of 20. “ However, it now appears, that the force of steam, in contact with water, in¬ creases ACCURATELY in geometrical pro¬ gression, to equal increments of tempera¬ ture, -provided those increments are mea¬ sured by a thermometer of water or mer¬ cury, the scales of which are divided according to the above-mentioned law. • Dalton’s Chemical Philosophy, p. 8—II. EFFECTS OF HEAT. 17 21. “ The force of steam ha,ving been found to vary by the above law, it was natural to expect that of air to do the same; for, air (meaning any permanently elastic fluid) and steam are essentially the same, difiering only in. certain modifications. Accordingly, it was found upon trial, that air expands in geometrical progression to equal increments of temperature, measured as above. Steam detached from water, by which it is rendered incapable of increase or diminution in quantity, was found, by Gay Lussac, to have tbe same quantity of expansion as the permanently elastic fluids. J had formerly conjectured that air expands as the cube of the temperature from absolute privation, as hinted in the essay above- mentioned; but I am now obliged to abandon that conjecture. 22. “ The union of so many analogies, in favour of the preceding hypothesis of temperature, is almost suflicient to establish it; but one remarkable trait of temperature, derived from experiments on the heating and cooling of bodies, which does not ac- C 18 EFFECTS OF HEAT. cord with the received scale, and which, nevertheless, claims special consideration, is, that a body in cooling loses heat in propor¬ tion to its excess of temperature above that of the cooling medium', or that the temperature descends in geometrical progression in equal moments of time. Thus, if a body were 1000° above the medium; the times in cooling from 1000° to 100, from 100 to 10, and from 10 to 1°, ought all to be the same. This, though nearly, is not accurately true, if we adopt the common scale, as is well known; the times in the lower intervals of temperature are found longer than in the upper; but the new scale proposed, by shortening the lower degrees, and lengthening the higher, is found perfectly according to this remark¬ able law of heat. 23. “ Temperature then will be found to have four most remarkable analogies to support it. “ 1st. All pure homogenous liquids, as water and mercury, expand from the point of their congelation, or greatest density, a EFFECTS OF HEAT. 19 quantity always as the square of the tem¬ perature from that point. “ 2. The force of steam from pure liquids, ‘ias water, ether, &c. constitutes a geometrical progression to increments of temperature in arithmetical progression. “ 3. The expansion of permanent elastic fluids, is in geometrical progression to equal increments of temperature. “ 4. The refrigeration of bodies is in geometrical progression in equal incre¬ ments of time. “ A mercurial thermometer graduated according to this principle, will differ from the ordinary one with equidifferential scale, by having its lower degrees smaller, and the upper ones larger; the mean be¬ tween freezing and boiling water, or 122° on the'new scale, will be found about 110° on the old one.—The following table ex¬ hibits the numerical calculations illustra¬ tive of the principles inculcated above * Ealton’s Chemical Philosophy; p. 11—14. EFFECTS OF HEAT. 21 Explanation of the Tahk. 25. Column I. contains the degrees of temperature, of which there are supposed to be 180, between freezing and boiling water, according to Fahrenheit. By com¬ paring' this column with the II. the cor¬ respondences of Mr. Dalton’s new scale and the common one are perceived; the greatest difference between 32° and 212°, is ob¬ servable at 122° of the new scale, which agrees with 110° of the old, the difference being 12°; but below 32° and above 212* the differences become more remarkable. The first number in the column, —175“ denotes the point at which mercury freezes, hitherto marked -^40°. By vietying column II. along with the I. the quantity of the supposed error in the common iscale may be perceived; and any observations on the old thermometer may be reduced to the new. See Fig. 1. Column II. contains the common Fah¬ renheit’s scale. EFFECTS OF HEAT. CoItitdii ni. contains a series of numbers in geometrical progression, representing the expansion of air, or elastic fluids. Column IV. contains the squares of the arithmetical series, 1,2, 3, &c., representing the expansion of water by equal intervals of temperature. Column V. contains the force of aque¬ ous vapours in contact with water, ex¬ pressed in inches of mercury, at the re¬ spective temperatures. 26. On the construction hitherto de¬ scribed, the thermometer is necessarily very limited in its application. When made with alcohol, or spirit of wine, it maybe said, indeed, to measure the greatest degrees of cold with which we are ac¬ quainted; but even the mercurial ther¬ mometer measures no higher than 400 degrees above boiling water, by Fahren¬ heit’s scale, or about 250 degrees by Mr. Dalton’s new scale, at which temperature mercury boils. This comes short of red EFFECTS OF HEAT. heat, and is far below the highest attain¬ able temperature. To supply this defi¬ ciency, and to measure high temperatures, various methods have been proposed. The instruments thus applied to measure high temperatures, are usually rvaxsxQdipyrometers. That which has come into most genera! use, was invented by the late Mr,, Wedge- wood; but even on this instrument there is still great room for improvement. Wedgewood’s pyrometer consists of cy¬ lindrical pieces of clay, composed in the manner of earthen ware, and slightly baked. When used, one of them is ex¬ posed in a crucible to the heat proposed to be measured, and after cooling, it is found to be contracted in proportion to the heat previously sustained; the quantity of contraction being measured, indicates ■ the temperature. The utility of this instrument, it was obvious, could be increased, by connecting it with the mercurial thermometer, and-sby ascertaining the proportional degrees of EFFECTS OF HEAT. each. This was accordingly done by Mr. Wedgewood. Its scale commences at red heat,, fully visible in day-light. Its whdle range is divided into 240 equal degrees, each of which is calculated to be equal to 130° of Fahrenheit. The lowest, or 0, is found about 1077° of Fahrenheit (suppos¬ ing the . common scale continued above boiling merctuy), and the highest 32277°. In i^ig-. 4, is given a diagram, which may .seiwe farther to illustrate the con¬ nection between the, mercurial thermom¬ eter, and that of Mr. Wedgewood. The following table exhibits some of the more remarkable temperatures in the whole range of Reaumur, Fahrenheit, Cel¬ sius, and Wedgewood’s thermometers. EFFECTS OF HEAT. ,25 27. TABLE of ilie Degrees of different Ther¬ mometers omitting Fractions, at ’which some feniarkahh Chemical Phenomena occur. REAU. EAHR. CENT. 54) 90 ■ 68 Greatest artificial cold ob¬ served, produced by Mr. Walker. 44 66 55 Nitric acid freezes, Fourcroy. 36 50 44 Cold observed at Hudson’s Bay, M‘Nab. 36 46 43 Ether freezes. ' 34 45 42 Ammonia exists in a liquid 39 39 Mercuiy freezes. 30 36 37 S ulphuric acid freezes, Thomson 28 31 35 Sulphurousacid liquid, Monge. 24 23 30 Cold observed at Glasgow on the surface of snow, 1780. 23 22 30 Acetous acid freezes. 20 .14 25 Cold ob’seived at Glasgow, 1780. 19 11 24 Two parts of alcohol and one 18 10 23 Cold observed on the snow at Kendal, 1791. 17 7‘ 14 Brandy freezes. 14 0 IS Cold, produced by mixing equal parts of snow and muriate of soda. 7 16 9 Oil of turpentine freezes. Margueron did not freeze at—18 ilW//. 5 20 6 Strong wines freeze. 4 23 5 Fluoric acid freezes. Priestly. Oil of bergamot and cin¬ namon freezes, Marg. ■ 3 25 4 Human blood freezes. 2 28 2.5 Vinegar freezes’ 1 39 1.25 Milk freezes. 0 32 0. Oxymuriatic acid melts, 77;om- son. Water freezes. 26 EFFECTS OF HEAT- HEAtJ. FAHK. CENT. 2 36 2.5 Olive oil freezes. 3 39 4 Meat of hedgehogs and mar- 4 40 s 5 Oxyrauriatic acid boils, '1 'horn- son, Equal parts of phos¬ phorus and sulphur melt, Pelktier. 5 43 6 Phosphorus bums slowly. 6 45 Sulphuric acid, Sp. gr. 1.78, freezes, Keir. 10 55 to 66 12 Putrid fermentation, Jioarcroy. 12 59 15 Vinous fermentation begins, Fourcroij, 14 64 17 Oil of anise freezes, 15 66 to 133 18 Animal putrefaction, 70 to panary fermentation. 16 68 20 . Camphor evaporates, Fourcroy 18 74 23 Butter melts. 19 75 24 Summer heat at Edinburgh. 20 77 25 Vinous fermentation rapid, Fourcroy, Acetous ditto begins. 21 80 26 Phosphorus burns in oxygen gas. 104, Goettl'mg. 21 75 to 80 26 Summer heat in England, 21 80 26 Heat of the ocean under the equator. 82 28 The adipocere of muscle melts. 23 88 31 Acetous fermentation ceases, Fourcroy. Phosphorus is ductile. 29 92 to 99 37 Heat of the human body. • 28 97 36 . Axunge melts, Nicholson. 97 36 ' Heat of a swarm of bees. •29 98 36 Ether bods. 30 99 37 ■ Phosphorus rsAs,-Pelletier. 31 100 to 103 39 Heat of domestic quadrupeds. 104 40 Resin of bile melts. 35 lOStolll 44 Heat of Birds. 33 107. 41 Feverish heat. 108 Hens hatch eggs. , '^^34 109 42 Myrtle wax mdts, Cadet. 35 111 •44 • Heat of the air near Senegal. EFFECTS OF HEAT. 27 • REA0. EAHR. CENT. 36 112 45 Spermaceti melts, Bostoci. 40 122 50 Phosphorus hums vividly, Fourcroy. 148, Thomson. 42 127 53 Tallow melts, Nicholson. 44 130 54 Ammonia is separated from 48 140 60 Ammonia boils, Dalton. 49 ■ 142 « 61 Bees-wax melts, Irvine. SO 145 63 Camphor sublimes, Venturi. Ambergriomelts,ia(?rAn^e. 55 155 79 Bleached wax voe\ts,Nicholson. 59 165 74 Albumen coagulates. 156, Black Sulphur evaporates, Kirwan. 61 170 77 64 176 80 Alcohol boils. 174, Blach. 90 235 116 Adipocere of biliary calculi melts, Fourcroy. Water and volatile oils boil. Bismuth 5 parts, tin 3, and lead 2, melt. 80 212 100 83 219 104 Phosphorus begins to distil, Pelletier. 88 230 110 Muriate of lime boils, Dalton. 89 234 111 Sulphur melts, Hojie. 212°, Fourcray. 185°, Kirovan. 93 242 116 Nitrous acid boils. 96 248 120 Nitric acid boils. 103 264 130 Air breathed by the human species, with tolerable ease, Phil. Transac. osol. 65. 112 283 140 White oxide of arsenic su¬ blimes. Alloy of equal parts of tin and bismuth melts. 120 303 150 Sulphur burns slowly, and camphor melts, Venturi. 134 334 168 Alloys, tii: 3 and lead 2, and tin 2 and bismuth 1, melt. 182 442 227 Tin melts, Crichton. 413, Ir¬ vine. 190 460 238 Tin 1, and lead 4, melt. 197 476 248 Bismuth melts. Irvine. 226 540 282 Arsenic sublimes. 232 554 290 Phosphorus boils, Pelletier. EFFECTS OF EEAT. EFFECTS OF HEAT, 11100 14.331 10177 12257 12777 13267 134.27 18627 20577 10320 11414 Working heat of plate glass. Flint glass furnace. Cream coloured ae.ware fired. Welding heat of Worcester china vitrified. Welding heat of iron greatest. Stone ware fired. Chelsea china vitri¬ fied. Derby china. Flint glass furnace Bow china vitrified. Equalpartsof chalk and clay melt. Plate glass furnace strongest heat. Smith’s forge. Cobalt melts. Cast iron melts. Bristol china no vitrification at Nickel melts. Hes¬ sian crucible melt¬ ed. ' Soft iron nails melt¬ ed with the cru- Iron melts. Manganese melts. Air furnace. Platinum, tungsten, molybdenum, ur- nium, melt. Greatest heat ob¬ served. Extremityofwedge- wood’s scale. EFFECTS OF HEAT. N. B. As many of these higher num¬ bers were calculated from Wedgewood’s, by the sliding rule, the two or three first figures only can be depended upon as cor¬ rect. They will be found, however, to be sufficiently accurate for most purposes. For more full information respecting various constructions of tliermometers and pyrometers, I beg leave to refer to Mr. Murray’s System of Chemistry, vol. 1st. I shall, however, when I come to speak of Mr, Leslie’s experiments, give an account of his diferential thermometer. EFFECTS OF HEAT. 31 SECTION n. Of Expansion. 28. Expansion of bodies is an im¬ portant effect of heat. Solids are least expanded, liquids more, and elastic fluids most of all. The law of expansion of all permanently elastic fluids, has already been noticed (Art. 23.), it remains now to notice liquid and solid bodies. 29. Every body receiving heat, with a few exceptions, when accurately measured, is found to be enlarged, or expanded. 30. It may be proper to take notice of some of the exceptions to this law,—^that bodies are expanded by heat. The inost general exception is, that increase of bulk which takes place in several substances in changing from the fluid to the solid state. This is remarkably the case with water, the expansion of which, in freezing, is capable of overcoming a very great resistance, as was proved by Mr. Boyle, by the Floren- EFFECTS OF HEAT. tine academicians, and, more lately, by Major Williams. In one of bis experi¬ ments, by the expansive force of freezing, an iron plug, weighing 21 lbs, was pro- jected to a distance of 415 feet, with a velocity of niore than 20 feet in a second*. Hence the .bursting, during frost, of pipes for conveying water, the raising of pavement,^ the falling of parts of neglected buildings, the splitting of trees, rocks, &c. 31. But a phenomenon still more sin¬ gular is exhibited by water, it expands not only in the instant in which it passes to the solid state, but before it reaches its freezing point. This singular phenom¬ enon appears first to have been observed by Dr. Croune, towards the close of the 17th century. It was afterwai'ds observed by Mairan; but De Luc seems to have been the first who attempted to investigate it with precision. Dr. Hope has since made experiments, from which he infers, that water obtains its maximum density at 40°, • Transactions of Royal Society of Edinburgh, vol. 3. p. 23. EFFECTS OF HEAT. 33 that is, 8° warmer than at the freezing point, or 32°. Mr. Dalton has also inves¬ tigated this subject, and from his experi¬ ments infers, “ that the greatest density of water, is at or near the 36 ° of the old scale, and 37 ° or 38 ° of the new scale; and fur¬ ther, tliat the expansion of thin glass is nearly the saine as that of iron, whilst that of stone ware is f, and brown earthen ware I of the same 32. Permit me to direct the reader’s attention to this very remarkable fact, that . all bodies are condensed by cold without limitation, water only excepted, whict we have just seen is, at its greatest density, at 36° of Fahrenheit’s scale. This exception to one of those general laws-of nature, is a sti'iking proof of contrivance in the arrange¬ ment of the universe. Were it otherwise, all the fresh water within the polar circles must inevitably have been frozen to a very great depth in one winter, and a great portion of what is now the most temper- " Dalton’s Chemical Philosophy, p. 34. E 34 EFFECTS OF HEAT. ate part of the globe, rendered a dreary- waste. To understand this, let us see -what takes place in the freezing of a fresh water lake. When the cold air comes in contact with the particles at the surface, they are cooled, and becoming heavier descend until they are cooled down to the point of greatest density. Were this 32° then the whole water would continue this in- •ternal motion until it arrived at the freez¬ ing point, and being all equally cold, would become all at once solid ice. But the water is heaviest at 36°, of course whenever, it is all cooled down to that point, the internal motion ceases, and the surface becomes gradually. colder un¬ til it arrive at the freezing point, when a thin body of ice forms a covering to the water, and particularly when snow is added, serves to protect it from the influ¬ ence of the colder atmosphere., For a fuller account of this instance of EFFECTS OF HEAT. S5 the beautiful economy of nature as also what relates to the influence of salt water on the temperature of the globe, I may refer the reader to Count Runiford’s seventh Essay. 33. According to Smeaton, “ glass ex¬ pands in length for 180° of temperature, consequently it expands xio in bulk. But water expands or rather more than eighteen and one-half times as much j'.” 34. A knowledge of the comparative expansions of solids, is of much import¬ ance in the arts, and more particularly in the construction of time-pieces, which are much affected by the expansion of metals. This has led to a number of experiments on the subject; those of Mr. Ellicot| appear to have been the first which were made with any degree of ac- cui'acy., He was followed in the same inquiry by Smeaton ||, Roy and Trough- . ton and also by M. Berthoud §. • “ Nature is but a name for an effect, “ U^hose cause is God.”—Ccu’/nr. f.Dalton, page 31, 32. ^ Phil. Trans vol. 39. || Phil. Trans. 48. § Essai sur Horlogerie, 2d edit. Paris, 17SS. 36 EFFECTS OF HEAT. Althougii we perceive sometliing like a relation subsisting between the expansion and fusibility of solids, those which are most , fusible, as antimony, tin, lead, &c. expanding most, yet it must be confessed, that we know but very little with regard to the connection which subsists between the expansibility and other physical pro¬ perties of solids. No general law has hitherto been dis¬ covered, respecting the ratio of expansion of solid bodies; but for all practical pur¬ poses, we may adopt the notion of the equable expansion of solids. Glass, how¬ ever, is an exception, for it has been found to expand in a ratio which increases with the temperature. For measuring the longitudinal expan¬ sion of solids, various instruments, or py¬ rometers, have been invented, accounts of which may be found in most books, on natural philosophy. “ The longitudinal expansion being found, that of the bulk may be derived from it, and will be three EFFECTS OF HEAT. 37 times as much. Thus, if a bar of 1000 expand to 1001 by a certain temperature, then a 1000 cubic inches of the same, will become 1003 by the same temperature 38 EFFECTS OF HEAT. 35 . TABLE of EXPANSIONS, for 180 ” of Fahrenheit*. Solids. Earthen ware. in Bulk. Wedge wood says, that earthen ware made porous by charcorJ, expanded only one-third as much as when solid. .000416 .0012 Dalton. Stone ware. Wood. . .000208 .0012 Do. Much less than glass. Rittenhouse. Glass rods and tubes. .000208 .0025 Dalton. -bulbs tbiu. .001234 .0037 Do. 00077615 .002330 Roy.—Phil. Trails. ■ 1785. He had be¬ fore found a glass tube expand four 50083333 .002502 Smeaton, Philosoph. Transac. 1754. Glass rod. Deal. 00080787 .002426 Roy, the same glass as the tube. Roy, 1777, as glass. Plarina. .000856 .002570 Borda. Platina and glass. .0011 .0033 Berthoud. Regulusof antimony.l .001083 .003253 Smeaton. Cast-iron prism. .0011094 .003332 Roy. Cast-iron. .0011111 .003337 Lavoisier. Steel rod. .0011447 .003438 Roy. Blistered Steel. .001125 .003379 Phil. Trans. 1795, 428. .001150 .003454 Smeaton. Steel. .0011574 .003476 Lavoisier. Hard SteeL .001225 -003679 Smeaton. Annealed Steel. .00122 .00367 Musschenbroefc. Tempered Steel. .00137 .00411 Musschenbroek., • See Dalton’s Chem. PhiL p. 44. and p. 390—3S1. Young’s Nat. Phil. vol. 2. EFFECTS OF HEAT. 39 Solids. in Length in Bulk. Trnn. .001156 .003472 Borda. .001258 .003779 Annealed Iron. .00133 .00400 Hammered Iron. .00139 .00417 Bismuth. .001392 ■ .004180 Annealed gold. .00146 .004.38 Gold. •0015 .0045 , EUicot, by compari- Gold wire. .00167 .00502 Musschcnbroek. Copper hammered. .001700 .005109 Smeaton. Copper. .00191 .00573 Musschenbroek. Brass. .001783 ;005359 Brass scale, supposed .0018554 .005576 Roy. from Hamburgh. Cast Brass. .001875 .005635 Smeaton, English plate brass .0018928 ,005689 Roy. English plate brass .0018949 .005695 Roy. .001933 .005811 Smeaton. Brass. .00216 .00648 Musschenbroek. Copper 8 tin 1. .001817 .005461 Smeaton. Silver. .00189 .005681 Herbert. — .0021 .0063 Ellicott, by com- __ .00212 .00636 Musschenbroek. Brass 16 tin 1. .001908 .005736 Smeaton. Speculum metal. .001933 .005811 Smeaton. Spelter solder brass .002058 .006187 Smeaton. Fine pewter. .002283 .006866 Smeaton. Grain tin. .002483 .007469 Smeaton. Tin. .00284 .00852 Musschenbroek. Soft solder, lead 2 .002508 .007545 Smeaton. Zinc 8 tin 1 a little .002692 .008095 Smeaton. hammered. Lead. .002867 .008625 Smeaton. .00344 .01032 Musschenbroek. Zinc. .002942 .008850 Smeaton. Zinc hammered out .003011 .009061 Smeaton. half aninchperfoot. 40 EFFECTS OF HEAT. laiquids. Expansion in Bulks. Mercury, ... - . . . . Water, Water saturated with salt, ... Sulphuric acid, ....... Muriatic acid, . . - - - - - Oil of turpentine, ...... Ether, . ........ Fixed Oils, ........ Alcohol, Nutiic acid, .. .0200 = -h .0466 = -5rT.T .0500 = ^ .0600 =tIt .0600 = ^ •.0Y00=tV .0700 = .0800=t4-t .0110 = ^ .0110 = I EFFECTS OF HEAT. 41 SECTION III. On the Speckle Heat of Bodies. 36. It was already observed, (Art. 3.) that different bodies at the same tempera¬ ture, and showing the same degree on the thermometer, really contain different quantities of heat. This diversity of the quantity of heat contained in different bodies, is called specific heat] and, accordingly, tables of the specific heat of bodies, showing their com¬ parative attractions for heat, have been formed in a similar manner with tables of specific gravity, which show the compara¬ tive weights of bodies of equal bulks. Sometimes the specific heat of bodies is deduced from equal weights^ and some¬ times from equal hulis, but it seems to be most correct to deduce them from equal bulks » See Dalton’s Chemical Philosophy, p. 2. F 42 EFFECTS OF HEAT. Not being susceptible of measurement by the thermometer, different modes have been contiiyed for estimating it. Lavoisier and Laplace used an ingenious contrivance called a calomiter, for investi¬ gating the specific heat of bodies. It was calculated to , show the quantity of ice, which any body heated to a given tem¬ perature could melt; but, however ingen¬ ious in its construction, this instrument has not been found in practice to be . sufficiently accurate. Meyer attempted to find tlie specific heats of dried woods, by observing the times which equal volumes were in cool¬ ing. These times^ he considered as pro¬ portionate to the capacities, or specific heats hulk for bulk., and when the thnes were divideiLby the.specific gravities, the quotients represented the capacities of equal weights. This method was applied by Mr. Leslie., to liquids, and has been approved of, and followed by Mr. Dalton. EFFECTS_OF HEAT. 43 37. The important fact of the absorption of heat, during the conversion of ice into water, appears to have been first observed, separately and unknown to each other, by De Luc, Black, and Wilkie, about the year 1755. On this experiment. Dr. Black principally founded his doctrine of latent, heat, . Dr, Irvine and Dr. Crawford, ex¬ plained the circumstances somewhat dif¬ ferently, by the theory of a change of capacity for heat. Dr. Black’s theory led to very vague, indistinct, and inaccurate notions on the subject; nor was the word capacity well chosen. The term specific heat,, is that which is more approved by later writers, particularly Dalton and Leslie*. 38. By the method already mentioned, (Art. 38.) making proper allowance for 'the containing glass vessels, Mr. Dalton made his experiments on the specific heats of various bodies^ the results of which will be found in the following Table. It will be sufficient to illucidate the use. of » See Dalton’s Chem. Phil—-Leslie’s Inquiry, p. 529, also Mr. Til- loch’s paper, Phil Mag. 1808, p. 70. 44 EFFECTS OF HEAT. the table, to give water and mercury as examples. “ If the whole quantity of heat in a measure of water of a certain tempera¬ ture be denoted by 1, that in the same measure of mercury will be denoted by .5 nearly: hence the specific heats of water, and mercury, of equal bulks^ may be sig¬ nified by 1 and ,5 respectively. “ If the specific heats, be taken from equal weights of the two liquids; then they will be denoted by 1 and .04 nearly, because we have to divide .5 by 13.6,' die specific gravity of mercury ■ Mr. Dalton has discovered that water increases in its capacity for heat with the increase of temperature, and infers, ■that as much heat is necessary to raise water 5“ in the lower part of Fahrenheit’s scale, as is required to raise it 7° in the higher, and 6° in the middle. ♦ Dalton, p. EFFECTS OF HEAT. 45 39. TABLE of Specific Heats. Hydrogen - Oxygen - - Common air Carbonic acid Aqueous vapo 21.40* 4.75* 1.79* 1.05* .79* 1.55* .002 .006 .002 .002 .001 .001 LIQUIDS. Water .. Arterial blood.. Milk (1.026). Carbonat. of ammonia (1.035) . . . . Carbonat. of pot-ash (1.30) - - - . - Solut. of ammonia (.948) . . . . . Common vinegar (1.02) Venous blood .. Solut. of common salt (1.197) - - - Solut. of sugar (1.17) ....... Nitric acid (1.20). Nitric acid (1.30) .- Nitric acid (1.36) - Nitrate of lime (1.40) Sulphuric acid and water, equal bulks - - Muriatic acid (1.153) ....... Acetic acid (1.056) Sulphuric acid (1.844) - -. Alcohol (.85). Ditto (. 817). Sulphur: ether (.76) Spermaceti oil (.87) Mercury ........... 1.00 1.03* .95 .75 1.03 •78 .77 .76 .68 .35 .76 .70 .52 .04 1.00 1.00 .98 .70 •55 46 EFFECTS OF HEAT. Quicklime . .. Pit^coal (1.27),. Charcoal - Chalk - -. Hydrat. lime - Flint glass (2.87) - Muriate of soda ......... Sulphur ........... Nickel Zinc. Silver ............ Tin ... -. Antimony - Gold. . ............ Bismuth - - - Oxides of the metals surpass the metals themselves, according to Crawford. .30 .28 .26* .27 .25 .13 .11 .11 .10 .10 .08 .07 .06 .05 .04. .04 .36 .67 1.00 ..97 .98 .78 .45 .40 EFFECTS OF HEAT. 47 Bemarhs on the Table. “ The articles marked * are from Crawford. Notwithstanding the ingen¬ uity and address'displayed in his experi¬ ments on the capacities of the elastic fluids, there is reason to believe his results are not very near approximations to the truth; we can never expect accmracy when it depends upon the observation of 1 or 2 tenths of a degree of temperature after a tedious and complicated process. Great merit is undoubtedly due to him for the attempt.—^The difference between arterial and venous blood, on which he has founded the beautiful system of animal heat, is remarkable, and deserves further inquiry!.” For some account of Dr. Craw¬ ford’s theory here alluded to, see Thomson’s Chemistry, vol. iv. p. 72,—also, Adam’s Lect. on Nat. Phil. vol. 1. p. 396. But those who wish fuller iirformation, I woirld refer to Dr. Crawford’s valuable “ Ex¬ periments and observations on Animal Heat.” f Dalton p. 6S'. 48 EFFECTS OF HEAT. 40. “ Water appears to possess the greatest capacity for heat of any pure liquid yet known, whether it be compared with equal bulks or weights; indeed it may be doubted, whether any solid or liquid whatever contains more heat than an equal bulk of water of the same tem¬ perature. The great capacity of water, arises from the strong affinity which both its elements, hydrogen, and oxigen, have for heat. Hence it is that solutions of salts in water, contain generally less heat in a given volume than pure water: for salts increase the volume of water as well as the density, and having mostly a small capacity for heat, they enlarge the volume of the water more than proportional to the heat they contribute 41. It is of importance to obtain the exact specific heat of the elastic fluids, because it has an intimate connection with the phenomena of combustion, and of heat in general. Of these, Mr. Dalton has given a theory, upon the principles of • Dalton, p. 64. EFFECTS OF HEAT. 49 which, he has calculated the following table, respecting which he says, We^shall have the specific heats, of the several elastic fluids, as in the following table. In order to compare them with that of water, we shall further assume the the specific heat of water, to that of steam, as 6 to '7, or as 1 to 1.166.” 42. “ TABLE of the Specific Heats of Elastic - • Fluids. Hydrogen - Azote •- - Oxygen - - Atmos, air - Nitrous gas Nitrous oxide Carbonic acid Ammon, gas . Carb. hydrogen “ Let US now see how far these results will accord with experience. It is remark¬ able, that the heat of common air comes out nearly the same as Crawford found it by experiment; also hydrogen excells all the rest, as he determined, but oxygen is much I''wer, and azote higher. The G - - 9.382 ,, Olefiant gas - . 1.5SS - - 1.866 Nitric acid - . . .491 1.333 Carbonic oxide - - .'ITJ - - 1.759 Sulph. hydrogen - .583 - - .777 I Muriatic acid . . .424 - - .549 I Aqueous vapour - 1.166 - - .491 I Etlier. vapour - . .848 - - 1.555 I Alcohol, vapour - - .586 - - 1333 Water .... I.OOO 50 EFFECTS OF HEAT. principles of Crawford’s doctrine of animal teat, and combustion, however are not at aU afected with the change 43. The phenomenon of animal heat has from the earhest ages been the subject of philosphical discussion, but its cause seems not yet ascertained. Of this, there are various degrees, some animals preserv¬ ing a heat of 100° or more in all tempera¬ tures of the atmosphere; others, particularly the more imperfect, keep only a few degrees warmer than the medium, with which they are surrounded. That of the human body is from 96° to 98°, and it is truely wonder¬ ful that it shotdd remain nearly the same in all climates. Men have lived in cold greater than that at which mercury freezes, (which is at 39° below zero,) and in an at¬ mosphere above the heat of boiling water. Mr. M‘Nab observed cold at Hudson^s Bay 50° below zero. While the human species have, with impunity, breathed air 264° f, none of the inferior animals, seem capable * Dalton, page 75, 74 . t See Phil. Tran. Votes. EFFECTS OF HEAT. SI of sustaining this change of temperature, while to man has been given this wonder¬ ful power of enduring all the variety of climates, which his necessities, or desire of knowledge, could lead him to visit, (Art. 27.) I hope the following quotations, relative to the power of animals to sustain heat, will be acceptable to the reader. “ Air has often been breathed by the human species, with impunity, at 264:°. TUlet mentions its having been respired at 300; and Morantin, one instance, at 325°, and that for die space of five minutes. Sonnerat found fishes, existing in a hot spring at the Manillas at 158° *: and M. Humboldt and M. Bonpland, in travelling through the province of Quito, in South America, perceived other fishes thrown up alive, and apparently in health, from the bottom of a vulcano, in the course of its explosions along with water, and heated • He graduates by Reaumur’s thermometer, and calculates the heat upon this at S9°. 52 EFFECTS OF HEAT. vapour that raised the thermometer to 210°, being only two degrees short of the boiling point*.” “ There are indeed numerous facts, all ■ of which tend to confirm the statement of these intrepid travellers. Dogs have exist¬ ed without apparent inconvenience, in a temperature of 236°, measured by Fah¬ renheit’s thermometer; a heat exceeding that of boiling water, by 24°. A species of toenia has been fotmd alive in a boiled carp; the oven-giirls in some part of Germany, have sustained a heat of 257° for a quarter of an hour; one girl supported it ten minutes, when augmented to 288° without inconvenience, and another, breathed in air, heated to 325° for five minutes f; the incombustible man, described by Dr. Sem- entini, of Naples, would receive boiling oil into his mouth, and bathe his fingers in fused lead without injmy J; and, to cpme nearer home. Sir Joseph ^ Banks, bore a • AaniTersary oration deEvered, March 8, 1808, before the Medical Society of London, by John Mason Good, F. R. S. I Hist. Acad. Scienc. 1764. ; Phil. Mag. vol. mdi. • EFFECTS OF HEAT. 53 heated room, at 211°, while Sir Charles Blagden, has himself given an account * of his sustaining the heat of 260° in the surrounding facticious atmosphere f 44. Bodies by changing their state, also change their specific heat. By a change of stare in bodies, is meant their successive ■passage from solidity to liquidity, and from tills to elastic fluidity, and contrari¬ wise. Thus water may be in the state of ice, of liquid, and of vapour, or steam. A solid body, as ice, on becoming liquid, acquires a great specific heat, even though its bulk be diminished; and a liquid, as water, acquires a greater specific heat, on being converted into an elastic fluid. It was already mentioned, (Art. 89.) that the absorption of heat, during the conver¬ sion of ice into water, was observed by philosophers, about the year 1755; and Dr. Crawford has shown, that by the laws of * Phil Trans, vols, Ixv. and laviii. f Eclectic Rev. March, 1809. 54 EFFECTS OF HEAT. absorption and extrication of heat, resulting from the change of capacity, which takes place in the solid and fluid states of water. Divine Providence, has wisely guarded againk various sudden vicissitudes of heat and cold upon the surface of the earth. A vast quantity of heat is extricated in freezing of large masses, which renders the process very slow, while the great absorp¬ tion of heat from the atmosphere', in thawing, occupies much time, and prevents that terrible devastation, which otherwise would take place from torrents produced by the sudden dissolution of ice and 45. During the conversion of water into steam, a great quantity of heat is absorbed; in consequence of which, when steam is again converted into water, much heat is extricated. Hence the water which results from condensation, forms an accurate compara¬ tive measure of the heat extricated from steam of the same density, and, for this EFFECTS OF HEAT. 55 purpose, it was applied in experiments made by Mr. Houldswortb*, in comparing the effects of steam-tubes of tin-plate with those of cast-iron. The subject of steam will be farther considered, after treating of Ebullition. » See Part II. 36 EFFECTS OF HE 4 T. SECTION IV. Of Combustion. 46. Modem cHemists consider the sources of heat, which are under the control of art to be the following;— Solar rays, electricity and galvanism, condensation, mechanical action between solids, including friction and percussion, and chemical action, to which head com¬ bustion belongs * Our concern at present is with com¬ bustion, but before proceeding to that subject, I shall very shortly notice some of the other sources of heat. 47. It has been long known, that col- otu'ed bodies when exposed to the light of the Sun, have their temperature raised in proportion to the darkness of their colour. —^The simple experiment of touching a white and a black stone exposed to the • Murray’s Chemistry, vol. i. p. 450. EFFECTS OF HEAT, 51 rays of the sun, would be su^cient to giye any one an idea of this truth. To ascertain this point, experiments were made by Dr. Hooke, by Dr, Franklin, and since, with more precision, by Mr, Davy 48. The temperature produced by the direct action of the rays of the sim, seldom exceeds 120°, but when they are concen¬ trated, -they are capable of producing a temperature as great at least, as the most intense and violent fires f. 49. Condensation of volume, it is well known, produces heat. This fact was long ago observed; in condensing air in the air-gun, A curious i application of this principle was, a few years ago, invented in France, and is now coming into use in this country. I allude to an instrument for kindling fungus, used instead, of the tinder-box. It is simply a condenser, which, by compressing the air into a very small space, by a single stroke of the piston, sets fire to the fungus. * Thomson’s Chemistry, vol. i. page 419. f P^ge 416. H 58 EFFECTS-OF HEAT. Mr. Dalton accounts for; the decrease of temperature of the atmosphere as we ascend, by' supposing that the natural . equilibrium of, heat is an equality lU quantity raxhex than, temperature. Air increases in its capacity for heat by rarefaction. The temperature must, therefore, be regulated by the density of each atom of air, in the same perpendictilar column, being pos¬ sessed of the same quantity of heat. Now, it is well known, that the density of the air becomes less as we ascend, and, of course, the heat also decreases 50. Mr. Dalton is likewise < of opinion, that the heat produced by friction and PERCUSSION of solid bodies, results, in both cases, from the same cause, viz. con¬ densation of volume, in the same manner as the condensation of air and other bodies produces'heat f. (See Art. 49.) 51. It was the opinion of Crawford, Lavoisier, and many other modem chemists, 3. t Dalton’s Chemistry, p.I23—I3S. effect's OF HEAT. 59 , that oxygenous gas was the sole or prin- - cipal source of the light and heat produced by combustion. But Mr. Dalton has proved, diat although-this may be,nearly, the case with regard to charcoal and pit- coal, that it is not true with regard to other combustible bodies. He concludes, “ that the heat, and probably the light also, evolved by combustion, must be con¬ ceived to be derived both from the oxygen' and the combustible body, and that each contributes, for ought we know to the contrary, in proportion touts specific heat before the combustion,” ^ .{Art. 43.), Fitel 52. Dr. Black considers the fuels corh- monly used, under five divisions:—“ The first may comprehend the fluid inflam- ablesj to the second we may refer peat or turf; to the third, charcoal of wood; to the fourth, pit-coal charred; and to the fifth, wood or pit-coal in a crude state, and capable of yielding a copious and bright flame.— » Dalton’s Chem. Phil. p. 81~82. EFFECT'S OF HEAT. 53. " 1st, The fiidd injlamables- are con¬ sidered as distinct from the Solid, on this accovmt, that they are capable of burning upon a •wick, and become in this way the most manageable sources of heat; though^ on account of their price, they are never employed for producing it in great quan¬ tity, and are only used when a gentle degree, or a small quantity of heat is suf¬ ficient. The species which belong to this class, are spirit of wine and different oilSi” 54. “ The second kind of fuel men¬ tioned, peat, is so spongy, that compared •with the more solid fuels, it is unfit to be employed for producing very strong heats. —It is too bulky for this.—e cannot put into a furnace, at a time, a quantity that corresponds with the quick consumption that must necessarily go on when the heat is violent. There is no doubt a great dif¬ ference in this respect, among different kinds of this fuel; but this is die general character of it. However, when we desire to produce and keep up, by means of cheap fuel, an extremely nuld gentle heat, EFFECTS OF MEAt. 61 we can hardly use any thing better, than peat. But it is best to have it previously charred^ that isj scorched, of burned to black coal. The advantages gained by charring it, will be presently explained. When prepared for use in that manner, it is capable of being made to burn more slowly and gently, or will bear, without being extinguished altogether, a greater diminution of the quantity of air with which it is supplied, than any other of the solid fuels. Dr. Boerhaave found it ex-, tremely convenient and manageable'in his FurUtis Studiosorumi - 55. “ The next fuel in order, is the charcoal of wood. This is the chief fuel Used by the cheffliks abroad, and has many good properties. It kindles quickly, emits few watery or other vapours while burning, and when consmned, leaves few ashes, and those very light. . They are, therefore, easily blown away, so that the fire continues open^ or pervious to the current of air which must pass through it to keep it burning. This sort of fuel EFFECTS OF HEAT. -too, is capable of producing as intense a heat as' can be obtained by any; but in those violent heats it is quickly consumed, and needs to be frequently supplied. - 55. “ Fossil coals charred^ called cinders or coaks^ have, in many respects, the same properties as charcoal of vsrood; as kin¬ dling more readily in fiirnaces, than when they ai'e not charred, and not emitting watery or other gross smoke while they bum. This, sort of charcoal is even greatly superior to the other in some properties. It is a much stronger fuel, or contains the inflamable matter iii greater quantity, or in a more condensed state. It is, therefore, consumed much more slowly on all occa¬ sions, and particularly when employed for producing intense melting heats. The only inconveniences that attend it are, that when it consmnes, it leaves much more ashes than the other*, and these much' • I do not know that this is tlie case with the finest pit-coal. I have seen some of the fines^Newcastle coals which did not leave one fiftieth part of their weight of ashes, and even these did not seem entirely consumed. EFFECTS OF HEAT. 63 heavier too, which are, therefoi'e, liable to collect in such quantity, as to obstruct the free passage of air through the fire; and farther, that when the heat is very intense, these ashes are disposed to melt or vitrify into a tenacious drossy substance, which ciogs the grate, the sides of the furnace, and the vessels. This last inconvenience is only troublesome, however, when the heat required is very intense. In ordinary heats the ashes do not-melt, and though they are more copious and heavy than those of charcoal of wood, they seldom choke up the fire considerably, unless the bars of the grate be too close together. “ This fuel, therefore, is preferable in most cases, to the charcoal of wood, on account of its burning much longer, or giving much moi'e heat before it is con¬ sumed. T^e heat produced by equal qtian ■ titles^ by weight of pit-coal^ wood^ charcoal, a7td wood itself are nearly in the proportion of 5, 4, and 3. The reason why both these kinds of charcoal are preferred, on most occasions, in experimental chemistry, to tjie crude wgod arid fossil-coal, from which, fhey are produced, is, that the crude fuels are deprived, by charring, of a consider¬ able quantity of water, and some other volatile principles, which are evaporated during the process of charring, in the form of sooty smoke or flame. These volatile parts, while they remain in the fuel, make it unfit (or less fit) for many purposes in chemistry. For, besides ob¬ structing the vents with sooty matter, they require much heat to evaporate them, and, therefore, the heat of the furnace in which they are burned is much dimin¬ ished, and wasted by every addition of fresh fuel, until the fresh fuel is com¬ pletely inflamed, and restores the heat to its former strength. But these great and sudden variations of the heat of a furnace, are quite inconvenient in-most chemical processes. In the greater number of chem¬ ical operations, therefore, it is much more convenient to use chaiTed fuel, than the same fuel in its natural state. EFFECTS OF HEAT; 65 57. “ The last kind of fuel is wood, or fossil coal in their crude state, which it is proper to distinguish from the charcoals of the same substances. The difference consists in their giving a copious ■ and bright flame, when plenty of air is admit¬ ted to them, in consequence of which they must be considered as fuels, very different from charcoal, and adapted to different purposes. “ I had occasion formerly to remark, when treating of inflamation, that flame is produced from those substances only, which are either totally volatile vsfhen heat is applied to them, or which contain a quantity of combustible taatter that is volatile, or easily convertible into vapour by heat; and that flame is nothing else but this vapour set on fire, or which becomes inflamed as fast as it arises from the body which affords it. : “ Of this nature, therefore, is the flame of wood and fossiLcoal, when they are -burned in their crude state. These fuels I EFFECTS OF HEAT. coatam a quantity of, inflamable matter, that is volatile, and which, when a ■moderate and stifled heat is applied to them, evaporates in the form of oily and sooty vapours and smoke, and diminishes the heat instead of increasing it. But if they are exposed to a stronger heat, and air is freely admitted, the sooty vapours are suddenly set on fire, or become flame, and continue afterwards to burn as fast as they arise from the wood or coal, in con¬ sequence of which they produce a great heat. “ These flaming fuels, however, have their particular uses, for which the others are far less proper; for it is a fact, that flame, when produced in great quantity, and made to burn violently, by mixing it with a proper quantity of fresh air, by driving it on the subject, and throwing it into whirls and eddies, which mix the air with every part of the hot vapour, gives a most intense heat. This proceeds from the vaporous nature of flame, and the perfect miscibihty of it with the air. As PFFECTS OF SEAT. 6f the immediate contact and action, of air is necessary to the burning of every corh- bustible body, so the air, when properly applied^ acts with far greater advantage on flame, than on the solid aiid fixed inflam- able bodies, for when air is applied to , these last, it can only act on. their surface or. the particles of them that are outermost; whereas flame being a vapour or elastic fluid, the air by proper contrivances can be intimately mixed with it, and made to act on every part of if, external and inter¬ nal at the same time.—^The great power of flame, which is the consequence of this, does not appear when we try small quan¬ tities of it, and allow it to burn quietly, because the air is not intimately mixed with it, but acts only on the outside, and the quantity of burning matter in the , surface of a small flame, is too small to produce much efiect. But when fiarne is produced in large quantity, and is pro¬ perly mixed and agitated with air, its power to heat bodies is immensely in¬ creased; it is, therefore, peculiarly proper ' for heating large quantities of matter to a 68 EFFECTS OF HEAT. violent degree, especially if the contact of solid fuel with such matter is incon¬ venient. Flaming fuel is used for this reason, in many operations performed on large quantities of metal or metallic min¬ erals, in the m^hiug of glass, and in the baking or burning of all kinds of earthen ware. The potters kiln is a cylindrical cavity, filled from, the bottom to the top ■with columns of ware. The only inter¬ stices are those that are left between the columns; and the flame, when produced in sufficient quantity, proves a torrent of liquid fire, constantly flowing up through the whole of those interstices, and heats the whole pile in an equal manner. Flaming fliel is also proper in many works or manufactories, in which much fuel is consumed, as in breweries, distil¬ leries, and the Uke. In such works it is evidently worth while to contrive the furnaces, so that heat may be obtained from the volatile parts of the fuel, as well as from the fixed; for when this is done, less fuel serves the purpose than would EFFECTS OF HEAT. Otherwise be necessary. But this is little attended to, or ill understood, in many of those manufactories. It is not uncom¬ mon to see vast clouds of black smoke and vapour coming out of their vents. “ This happens in consequence of their throwing too large a quantity of crude fuel into the furnace at once. The heat is not sufficient to inflame it quickly, and the consequence is, a great loss of heat*.” 58. I hope it will not be considered an improper digression, to mention a subject which has lately excited a good deal of the public attention; I allude to the light pro¬ duced from the gas proceeding from the distillation of pit-coal. From the Philo¬ sophical Transactions, it appears that, as far back as the year 1735, it was known as a fact, that coal yields an inflamable gas, but its beneficial application seems to have been reserved for Mr. Murdoch, in the year 1792. The most extensive cot- * Black’s I.e s, vol. i. pages 312—Sl(^ 70 EFFECTS OF HEAT. ton-mill in the kingdom, has been, for several years, lighted np with the gas from coal. The following extract from a peri¬ odical work of extensive circulation % as giving a summary view of this subject, and as containing soine valuable facts respecrii^ fuel, I trust will be acceptable to the reader. But those who wish to pursue tie subject, I would refer to the work alluded to, as well as to Mr. Mur¬ doch’s “ Account of the Application of Gas from Coal to Economical Purposes,” published in the PhUosophicai Transac¬ tions for 1808, and reprinted in Nichol¬ son’s Philosophical Journal, the Philosophi¬ cal Magazine, and the Monthly Magazine for the same year. “ Pit-coal exists in this island in strata, which, as far as concerns the hundredth generation after us, may be pronounced inexhaustible; and is so admirably adapted, both for domestic purposes and the uses of the arts, that it is justly regarded as a »Edinbmgh Review, vol. liii. page 478. EFFECTS OF HEAT. 71 most essential constituent of our national wealth. When exposed to heat, as we see it every day in our grates, it is manifestly composed of a fixed base of carbonaceous matter,; and a variety of evaporable sub¬ stances, which are driven ofFin the form of smoke and flame. But, instead of being con¬ sumed in this open way, the coal may be dis¬ tilled, and these evaporable matters collected in proper vessels, and examined. They are then found to contain, besides a consider¬ able quantity of matter, which is condensed by cold into tar and alkaline liquor, an invisible elastic fluid, or gas, which no cold nor affusion of water can condense or absorb. It is a compound of two highly inflamable gases, which chemists call the light hydrocarbonate, and the heavy hy¬ drocarbonate, or olefiant gas; and this mixture burns with a very brilliant and beautiful light. It is this gas which fur¬ nishes the flame in our conimon. fires “ • There are, in fact, according to Mr. Davy, three inflamable gases g^ven out in our fires;—the' two we have mentioned, and the gaseous oxide of carbon, which is known by its blue flame. They are all distinctly perceptible; the light hydrocarbonate forms the main body «f the flame; the olefiant appears in brilliant jets; and the gaseous effects of heat. but its beauty is there impaired by the unavoidable alloy of smoky vapour. A separation, however, may be effected by the distilling process, which , leaves the pure aerial fluid such as we have described. All the new plans for lighting vtith coal- gas, proceed upon the principle of purify¬ ing this fluid, collecting it in reservoirs, and distributing it in tubes. From the furnace where the coal is distilled, a main pipe may convey all the evaporable matter into a large reservoir or gasometer, where, by various means—chiefly, we believe, by washing with water, it may be freed from impurities, and propagated through the tubes in every direction by its own elas¬ ticity. If nothing confine it, it will issue from the extremities in an equable flow, but still invisible, till a hghted taper be applied, when it bursts into flame, and continues to bum as long as the gas is supplied. Mr. Accxun found, by a com¬ parison of shadows, in the manner sug- oiide is occasionally seen near the root of the flame, or in conuct with, the coaL It is possbie that a small portion of this oxide may mix with prepared gas. EFFECTS OF HEAT. 73 gested, by Count Rumford, that the light of a. gas flame is to that of an equal-sized flame of a candle or lamp, as 3 to 1 or, in other tvords, that to light up a certain space, one gas flame will give as much light as three candles burning with a flame of equal size. The products of the com¬ bustion are, in both cases, the same,-*^ water and carbonic acid gas; but with this material difference, that candles frequently, and lamps always, give out a quantity of smoke and soot; whereas the combustion of the gas is perfect, and leaves no sensible residuum,-—notliing that can soil the most delicate white. Its effects pn the air of a room are,, therefore, less insalubrious than those of a candle, since the only noxious substance it yields is carbonic acid gas; and this it produces in smaller quantity thaa our common iighjts;. From the in- • TVe sliauld have suspected the proportion Ovet-fated, fiad liot the same accurate experimenters assured us, * that 500 cubic inches of gas,, burnt from the orifice of a jet, so as to produce a ilame equal in size to that of an ordinary candle, consumed 1075 cubicinches of oxygen gas in the same time that a candle, kept burning in the best possible manner^ consumed only 279; and we know, that the. intensity of any artificial light depends on the rapidity with which oxygen absorbad.’-^ee Appendix to Report of the Committee, &c. K •74 EFFECTS OF HEAT. flamable properties of the gas, explosions, bursting of tubes, and other dangers might be apprehended. But there is no ground for such fears. On the contrary, nothing can be more simple or easy in the man¬ agement. The gas may be confined by a stop-cock with perfect safety, and issued as occasion requires. When it is exhausted, the flame goes out as quietly as the flame of a candle does, when the tallow is spent. “ Such are the nature and properties of this curious and beautiful substance, when examined in a small way in the laboratory of the chemist. But it frequently happens, that theories perfectly just and elegant iii themselves, and confirmed by experiments on a small scale, with a nice apparatus and skilful management, are yet, when at¬ tempted in the large and wholesale way, utterly incapable of being reduced to prac¬ tice; and thus, many a promising plan has ended with performing nothing. But, in the case before us, there are facts, of the description we want to be collected from different quarters, and furnished by indi- EFFECTS OF HEAT. 75 viduals unconnected with each other, which fully verify the anticipations of theory, arid the conclusions of moi'e limited experi¬ ment. This substance (coke) is the residuum that is found after all the evaporable mat¬ ter has been expelled from the coal by heat. It comes out from the distilling process in large spungy masses, greatly diminished in weight, but increased in bulk nearly one-third. Though somewhat more difficult of ignition than coal, it burns longer, and gives out a steadier and more intense heat. That it should do so, will not appear strange , to . our chemixal readers, (and who is there now, that does not know something of chemistry?) when it is considered that the quantity of mat¬ ter, which, in the combustion of coal, is changed from a solid to a state of elastic fluidity, must necessarily carry off much caloric in a latent state; while the glow of the coke radiates with an intensity un¬ impaired by any demand of this kind. The same respectable chemist we formerly EFFECTS OF HEAT. 76 mentioned, bears testimony to the supe¬ riority of coke, ‘ I have learned,’ says Mr. Accum*, ‘ thai the heat produced by coke^ njohen compared 'with that which can be obtained from coal, is at least as 3 to 2.’ Thus he found, that it required three bushels of coal ro distil a given quantity of -water, and only two of coke. He tried the two sub¬ stances also by combustion, with a certain measure of oxygen gas, by the fusion anti the reduction of metals, &c.; and the same result was obtained,—a result certainly not unimportant, since it proves that, by being forced to yield the material of a beautiful light, coal is actually improved very con¬ siderably in its power of giving heat, “ Before taking leave of Mr. Winsor, we shall present the reader with the results of his analysis of coal, which, we should have been cautious of admitting among authentic facts, had not the Committee declared, that the experiments were repeated in their pre¬ sence, and that they corroborated Winsor’s ' Appendix to Report of the Committee, &c. EFFECTS OF HEAT. 77 printed statement in the most satisfactory- manner. Two pecks of Newcastle cbal^weigking S6 lb., produced three pecks of coke, weighing 24 lb. 2 0 %., about 34 lb. of oily tar, and about 41 of alkaline liquor) and, as the only other product was gas, it is concluded that gas constituted the, remainder of the weight, amounting nearly to four poustdsT 59, ' I shall collect here the effect of se-veral hinds of fuel in producing heat, as given by authorities which have come un¬ der my observation, and afterwards make a comparative abstract of the result. The distillation of water is a simple and satis¬ factory mode of comparing the effects of fuel. 60. Mr. Dalton says, for the sake of those who are more immediately interested in the economy of fuel, that the heat given out by the combustion of 1 lb. of charcoal, and, perhaps, also of pit-coal, is sufficient (if there were no loss) to raise 45 or 50 lbs. of water from the freezing to the boiling temperature} or it is sufficient to convert *78 EFFECTS OF HEAT. 7 or 8 Ihs. of water into steam. If more thaii this weight of coal be used, there is a proportionate quantity of heat lost, which ought, if possible, to be avoided 61. In Dr. Black’s Lectures, vol. i. page 184, we have the following note: “100 pounds weight of the best Newcastle coal, when applied by the most judiciously constructed fur¬ nace, will convert about D wine hogshead f of water into steam that supports the pressure of the atmosphere. 62. By this account, observes Count Rumford, which he (Mr. Kirwan) tells me is founded on experiments made by Mr. Lavoisier, it appears, that equal quantities of water under equal smfaces, may be evaporated, and consequently equal heats produced- By 403 lbs. of coaks, 600 — of pit.coal, 600 — of charcoal, 10S9 — of oak, By 17 of coaks, 10 of pit.coal, 40 of charcoal, 33 of oak • Dalton’s Chemical Philosophy, page 82. t Equal to 12.63 cnhic feet. 1 Rmnford’s Essays, vol. ii. page 134. EFFECTS OF HEAT. 79 “ From tne result of my 20tli experiment, it appeared that 20-iV lbs. of ice-cold water might be heated 180 degrees., or made to boil under the mean pressure of the atmosphere, at the level of the surface of the ocean, with the heat generated in the combustion of \ lb. of pine-wood. Computing from the result of this experiment, and from the relative quan¬ tities of heat producible from pine-wood’ and from pit-coal, it appears that the heat generated in the couibustion of \ lb. of pit-coal, would make 36^ lbs. of ice-cold water boil .— Hence it appears, that pit-coal should heat 36 times its weight of water, from the freezing point to that of boiling; and as it has been found by experiments, made with great care by Mr. Watt, that nearly 5i times as much heat as is sufficient to heat any given quantity of ice-cold water to the boiling point, is required to reduce that same quantity of water, already boiling hot, to steam; according to this estimation, the heat generated in the combustion of \ lb. of coal, shotdd be sufficient to reduce very nearly 7 lbs. of boiling hot water to steam • Count Rumford’s Essays, vol. ii. page 136,137. ^ 80 EFFECTS OF HEAT, Dn Crawford found, by an experiment epnttived with much ingenuity, and whicli appears to have been executed with the utmost care, that the heat generated in the combustion of 30 grains of charcoal raised the temperature of 31 lbs. 7 oz. Troy=f 181.920 grains of water degrees of Fahrenheit’s thermometer, •when none of the heat generated was suffered to escape,. Con¬ sequently, the heat generated in the combus¬ tion of 1 lb, of charcoal, •would be sufficient to heat 57.608 lbs, of ice-cold •water 180 degrees, or to make it both, for 3157.9 grains of char¬ coal are to 181.920 grains of water, as 1 of charcoal to 57.608 lbs. of water, From the result of Mr. Lavoisier’s ex¬ periments, it appeared tKat the quantities of heat generated in the combustion of equal weights of charcoal and dry oak, are as 1089 to 600. Hence we may con¬ clude, that equal quantities of heat are gen¬ erated by 1 lb. of charcoal and 1.815 lbs, of oak; consequently, that the heat gen¬ erated in the combustion of 1.815 lbs. of oak, would heat 57.608 lbs. of ice-cold EFFECTS OF HEAT. 81 water,—or 1 lb. of oak, 31.74 lbs. of ice- cold water 180 degrees, or cause it to boil; were no part of the heat generated in the com- hustion of fuel lost ' 63. “ The comparative examination of the intensity of the heat produced by bursting charcoal and charred turf proves that the heat of the latter is (to that of the former) nearly in the proportion of three to one f. '64. “ Mr. Watt finds, that it requires eight feet surface of boiler to be exposed to fire, to boil oflF one cubic foot of water per hour, and that a bushel or 84 lbs. New¬ castle coal, so applied, will boil off from eight to twelve cubic feet 65. “ The heat expended in boiling olF a cubic foot of water, is about six times as much as would bring it to a boiling heat * Count Rumford’s Essay, vol, li. page 139, 140. f “ Inquiry into the comparative intensity of heat produced by the combustion of charcoal and charred turf,” in the Memoirs of the Acad- f effecting it were amply considered by Messrs. Boulton and Watt, as was known to many of their friends, no secret having been made, either of calcula¬ tions of surface, or of the modes of apply¬ ing them. About the end of the year 1799, IMi-. Lee. of Manchester, having a large increase of his cotton-mill in view, consulted with Messrs. Boulton and Watt, relative to the best mode of heating it by steam ; and, in the course of the subsequent year, he erected his present apparatus of cast-iron pipes, acting also as supports to the floor., which answered perfectly; and was, both in point of the materials used, and of the construction adopted, as far as I know, the first of the kind. From that period, many apparatus were' constructed by them, in some of which, applied to old buildings, the pipes were conducted horizontally through the rooms, with other variations of little importance. PREFACE. It may not be improper here to add, that the vats, &c. of the dye-house of Messrs. Wormauld & Gott, of Leeds, were heated by steam, under the direction of Messrs. Boulton and Watt. The apparatus was planned in August, 1799, and set to work either in the course of that, or early in the following year. The history of that es¬ tablishment has been very incorrectly given in the Journals of the Royal Institution, for 1801. The merit of the first application of steam, to the heating of buildings in Scot¬ land, belongs to Mr. Snodgrass. He in¬ troduced it* into the cotton-work, which Messrs. Dale & M'Intosh established on the banks of the Spey f. Soon after this period, Mr. Hoiildsworth of Glasgow, used it with great success. His example Kas been followed by several other respectable cotton-spinners. • Li&e year 1799, and, there is reason to think, vitliout tlie know¬ ledge of-what bad been done in England. t See Philosophical Magazine, for Jlarch, 1S07. PREFACE. XVll Steam was soon afteiwards applied to warm buildings, appropriated to the pur¬ poses of calico-printing. Mr. Richard Gillespie, in his calico-works at Anderston, was induced, very early, to use it in his warehouse for finished goods; and he has since been gradually extending it through other parts of his works*. It was also soon adopted by calico-printers in En¬ gland and Ireland. Its use for various pur¬ poses, is now daily extending in every part of the United Kingdoms. * In the Introduction to the Tliird Part of this Treatise, there is a nar¬ rative respecting the application of steam to the pilose of drying- TABLE OF CONTENTS. PAGE Prepace,._ ; Account of the Origin and Progress of the Application of Steam to the Heating of Buildings, - - xi PART FIRST.—Effects of Heat—Means of Measuring it—Fuel, die..1 Section I—Of Heat,.1—3 Of Thermometers,.5 Table, -.20 Expianation of the Table,.2l Table of degrees of Thermometers, - . - 25 Section II.—Of Expansion, - - - - 31 Table of Expansions,.38 Liquids,.40 Section III.—On th.-' Specific Heat of Bodies, - - 41 Table of Specific Pleats, . 45 Gases, ib. Liquids, ib. Solids,.- 46 Remarks on tlie Table,'.47 Table of Specific Heats of Elastic Fluids, - - 49 Section IVb—Of Combustion, - - - - 56 Fuel,.59 Section V.—Of the Motion of Heat, - - - 85 Bodies,.89 Equal Bulks, -.90 Equal Weights,.ib. Refrigeration of bodies in various kinds of Elastic Fluids, 128 Section VI.—Boiling, or Ebuliition, - - - 131 Of Steam, or Vapour,., 139 Table of the Force of Steam, &c. . - . . 147 Table of the Expansion of Air, .... 148 Table of the Expansion of Liquids, ... 149 Table of the Expar siou of Water, . . . ib. Section VII_Of Ignition,.150 Description of Plate 1st,.158 PART SECOND_Heating Mills, Dwelling-Houses, and Public Buildings, by Steam, ... Jgg Section I_Of the Proportionate Sire of Boilers, 160 Section II.—Of the Proportion of Steam-Pipe rer quired to heat a given space, .... jgg Section HI.—Of the Substance and Surface .of the. Steam "Pipe,.- 164 Section IV_General Observations respecting the Di¬ rection and Arrangement of the Pipes, ■ ' - 168 XX TABLE OF CONTENTS. Section V.—Of the Method of connecting the Steam- Pipes, .- 173 Section _Description of BoUer for generating Steam, Ac..179 Apparatus for supplying Water, - - . . ib. Apparatus for regulating the Damper, - - 180 Safety Valves,.181 Gauge-Cocks,.182 Contrivance to give Alarm, &c. - - - - ib. Section MI_Syphons,.ISi Section MIL—Description of some Cases of the Direction and Arrangeraenr of Steam-Pipes in ac¬ tual use, .187 Dwelling-Houses, - 194 Baths,.201 General Explanation of Plate 2d, ... 202 PART THIRD.—Drying and heating by Steam, - 203 Introduction,.ib. Section I..210 Section II.—Of the Difference of Temperature, &c. 221 Table of the State of the Thermometer, &-c. - - 222 Section HI.—Of the Proportion between the Surface of Steam-Pipe, and the Heat produced, - - 223 Table showing the Heat, Ac. 229 Section IV.—Miscellaneous Observations, - 230 Note A,.245 Note B.—General Abstract relative to several Buildings which have been warmed by Steam, - - 247 Note C,.248 P.CRT FOURTH.—Miscellaneous Observations, 251 Section I.—On the Phenomena of Heat, &c. - ib. Specific Heat of the Gases, compared with that of Water and with different Solids and Liquids, - - 269 Section II.—On the Heating of Mills, Dwelling-Houses, Baths, and Public Buildings, by Steam, - - 275 Methods of connecting Steam-Pipes, . - . 284 Section HI.—On Heating and Drying by Steam, 305 .APPENDIX.—Miscellaneous Observations on Chimney Fire-Places, particularly those used in Ireland, - 307 On Stoves,..319 Operation of the Stove,.332 Account of the Lime -Kilns at Closcburn, Dumfrics-shire, 338 Gas-Lights,.346 On the' Furnaces and Chimneys used for Rapid Distilla¬ tion, in the Distilleries in Scotland, - - - 356 MISCELLANEOUS OM8EMr^4TIONB ON THE PHENOMENA OF HEAT,-ON THE HEATING OF MILLS, DWELLING HOUSES, BATHS, AND PUBLIC BUILDINGS, BT STEAM.-ON DEYING AND HEATING,BY STEAM, &C. SECTION I. On the Phenomena of Heat, 211, A-BOUT five years have elapsed since the foregoing Parts of this Treatise vvere written. During that period, many im¬ provements of a practical nature on the manner of heating Buildings, &c. by Steam, have been made, of which notice shall be afterward taken; but in regard to dis¬ coveries respecting the laws xchich regulate 252 PHENOMENA OF HEAT. ' the ‘phenomena of heat I am not aware that there is much new information to communi¬ cate. In the Philosophical Transactions for 1812, is inserted an account of Mr. Brodie’s fiirther experiments and observations on the generation of Animal Heat f. “ The near coincidence in the result of these ex¬ periments is sufficient to prove, that we are not yet in possession of a perfect theory of the production of animal temperature; nor do we see any objection to the inference of Mr. B.that the temperature of warm-blooded animals is considerably under the influence of the nervous system. That the function of respiration is one of the sources of animal heat, cunnotbe doubted; perhaps it is. the * See p. 1. f « There is a very interesting paper in tlie Philosophical Transactions (1792, voL 82. p. 199) by Dr. Currie, of Liverpool, on the changes in animal heat occasioned by immersion in cold salt, and fresh water, and by passing repeatedly from the water into air and vice i^ersa. These experi¬ ments have not yet received any attention from chemists and physiologists. They appear to me to subvert every theory of animal heat hitlierto pro¬ posed, not even excepting the theory of Dr. Cla^vfo^d, ingenious and plaiirible as it is. Some very curious experiments by Mr. Brodie, pub¬ lished in the Transactions for 1811, arc equally incompatible with tlic present diemical theory of respirarion. But there is an apparent discor¬ dance between them and Uiose of Dr. Currie, whiclr ought to be cleared up before any attempts can be made to construct a new theory of animal heat.”— Thosison’s Hisiort of the Royal Society, Notc^ p. 129. THENOMENA OF HEAT. 253 primary one, since it prepares the blood for, the various important purposes to which it is subseiwient in the animal economy; but^ as the evolution of heat is an almost con¬ stant effect of chemical action, it is reason¬ able to presume, from analogy, that the various secretions which are constantly going forwards, contribute, in no trifling degree, to maintain the temperature of the animal. We are, at present, veiy far from being able to form any tolerable estimate of the influence of each taken singly; but, as our means of doing this shall increase, we may expect to make a nearer approx¬ imation to a just theory of this most inter¬ esting part of physiology 212. In the year 1813, Leslie pub¬ lished a volume, entitled “ A View of the Facts ascertained concerning Heat, and its relations with Air and Moisture.” “ The object of this short Treatise (to use the Author’s own words) is to convey, in a popular form, a distinct though general ^ See Eclectic Ketiew, December, 1814. p. 603, 60-J. 254 PHENOMENA OF HEAT, conception of the modern doctrine of Heat, disengaged, as inuch as possible, from all hypothetical reasonings. It will trace the progress of experiment, from tlie earlifil* times to the recent discovery of the arti¬ ficial production and conservation of ex¬ treme cold.” 213. In the Journal de Physique is given A Memoir on the Heat of the Surfaces of Bodies, hy M. Ruhland, of Munich. His experiments, though curious, are not so clear and decisive as to merit insertion m a practical work. A few extracts, of a prac¬ tical nature, from ]\Ir. Leslie’s publication above alluded to, will doubtless be accept¬ able to those readers who may not have access to the works of that celebrated Philosopher. 214. “ The increased capacity of rarefied • air is the true cause of the cold which pre¬ vails in the higher regions of the atmo¬ sphere*. * Leslie, p. II. PHENOMENA OF HEAT. 255 215. “ That temperature is hence inverse¬ ly as the capacity of air possessing the rarity due to the given altitude. Having therefore ascertained, hy some delicate experiments, the law which connects the capacity with the rarity of air, it was not very difficult to trace the gradations of cold in the higher atmosphere, and even to mark the precise limit where the reign of peipetual congela¬ tion must commence. Thus, I find that, under the equator, the boundary of the frozen region begins at the altitude of 15207 feet, in the parallel of 45° at 7671 feet, in the latitude of London at 5950, and in that of Stockholm at 3818, while towards the pole it comes to graze along the surface ■ 216. “ A new principle appears to com¬ bine its influence, and the rate of dispersion, in aeriform media, is found to depend chiefly on the nature of the mere heated surface. From a polished metallic surface, heat is feebly emitted; but, from a surface of glass, or stiU better from one of paper, it is discharged with profusion. If two equal PHENOMENA OP HEAT. 256 balls of thin bright silver, one of them en-, tirely uncovered, and the other sheathed in a case of cambric, be filled with water slightly warmed, and then suspended in a close room, the former wiU lose only 11 parts of its heat in the same time that the latter will dissipate 20 parts. Of this ex¬ penditure, 10 parts from each of the balls is communicated in the ordinary way, by the slow recession of the proximate particles of air, as they come to be successively heated. The rest of the heat, consisting of 1 part from the naked matallic surface, and of 10 parts fi.-om the. cased surface, is propagated through the same meclium, but with a cer¬ tain diffusive rapidity, which, in a moment, shoots its influence to a distance, after a mode entirely peculiai; to the gaseous fluids. The very superior propellent energy of a surface of glass or paper in comparison of that of a metallic one, lyes within the com¬ pass even of ordinary observation. If a glass caraffe or a pot of porcelain be filled with boilidg water, on bringing towards it the palm of the hand, an agreeable warmth will be felt at the distance of an inch or two PHENOMENA OP HEAT. ,257 from the heated surface; but if a silver pot be heated in the same way, scarcely any heat is at all perceptible on approaching the surface, till the fingers have almost touched the metal itself. 217. “ It is curious to inquire how such a singular diversity can arise. If the silver ball be covered with the thinnest film of gold-beater’s skin, and which exceeds not the 3000th part of an inch in thickness, the power of dispersioii will be augmented from 1 to 7; if another pellicle be added, there will be a farther increase of this power, from 7 to 9; and so repeatedly growing, till after the application of five coats, when the propellent energy will reach its extreme limit, or the measure of 10. In this case, the metallic surface is precluded from all contact with the air, and it must, therefore, act in consequence of its mere approximation to the external boundary. We may thence infer, that air never coines into actual contact with any surface, but approaches much nearer to glass or paper than to polished metal, from which it is 258 PHENOMENA OP HEAT, separated by an interval of at least the 500th part of an inch. A vitreous surface, firom its closer proximity to the recipient medium, must hence impart its heat more copiously and energetically, than a surface of metal in the same condition; and the mei:al, to a certain extent, can act in re¬ ducing the power of the other. When a pellicle was applied, the metallic surface immediately under it repelled partially the atmospheric boundaiy, and reduced the darting efflux of heat from 10, which would have been thrown by the skin alone, to about 7, or only 6 more than the efficacy of the naked metal. The repelling influence of the-' metallic plate was sensible even imder four coats, or at the distance, of the 750th part-of an inch horn the external 218. “ The very singular and unexpected facts now detailed merit attention, and sug¬ gest a variety of improvements in the prac¬ tical management of heat. A vessel with a bright metallic surface is the best fitted to • Leslie, p. 18—21. PHENOMENA OF HEAT. 259 preserve liquors either long warm, or as a conservatory to keep them cool. A silver pot will emit scarcely half as much heat as one of porcelain; and even the very slightest varnishing of gold, platina, or silver, which communicates to the ware a certain metallic gloss, renders this new kind of manufacture about one-third part more retentive of heat. The addition of a covering of flannel, though indeed a slow conductor, far from checking the dissipa¬ tion of heat, has directly the contrary tendency; for it presents to the atmo¬ sphere a surface of much greater propulsive energy, which it would require a thickness of not fewer than three folds of this loose substance fully to counterbalance. The cylinder of the steam-engine has lately been most advantageously sheathed with polished copper. 219. “ The progress of cooling is yet more retarded, by surrounding the heated vessel on all sides, at the distance of near an inch, with a case of planished tin; and the ad¬ dition of other cases, following at like in- K k • 260 PHENOMENA OF ffiEAT. tervals, augments continually the effect. With an obstruction of one case, the rate of-refrigeration is 3 times slower, mth two cases it is 5 times slower, with three cases it is 7 times slower, and so forth; as; exr pressed by the succession of the odd num¬ bers. By multiplying the metallic cases, therefore, and disposing them, like a nest, at regular intervals, the innermost could be made to retaia the same temperature, with little variation, for many hours, or even days. Such an apparatus would obviously be well calculated for various culinary and domestic purposes., 220. “ In the conveyance of heat by means of steam, the surface of the conduct¬ ing tubes should have a metallic lustre. On the contrary, if it, be intended by that mode to warm an apartment, they should be coated on the outside with soft paint, to facilitate their discharge of heat. For the same reason, metallic pots are more easdy heated on the fire, after their bottoms have become tarnished or smoked. If a bright surface of metal be slightly furrowed PHENOMENA OF HEAT. . 261 or divided by fine flutings, it will emit heat sensibly faster, because the prominent ridges, thus brought closer to the general atmospheric boundary, will excite the pul¬ sations with augmented energy. 221. “ On the other'hand, a plate of metal, however thin, if only burnished on each side, will form the most efficacious screen. A smooth sheet of pasteboard, gilt over both sides, would answer the same purpose. But a complete and elegant screen might be composed of two parallel sheets of China papei’, placed about an inch asunder, and having their inner surfaces gilt, and their outsides sprinkled with flowers of gold and silver. 222. “ Since, in a still atmosphere, the momentary flow of heat from any vessel, whatever this may contain, depends merely on the condition of its surface, the whole accumulated discharge, during similar de¬ scents of temperature, is evidently propor¬ tional to the time elapsed. Hence, a very simple and accurate method is suggested, 262 PHENOMENA OF HEAT. for ascertaining the capacity of different liquids, or their specific attraction to heat. Into a glass ball, two or more inches in diameter, and blown extremely thin, with a narrow short neck, and having a delicate thermometer inserted through it, the liquid to be examined, which had been previously warmed a few degrees, is carefully intro¬ duced by means of a funnel. The ball is then made to rest against the tapering points of three slender glass rods at the height of several niches above the table, and sheltered &om any irregular agitation of the air of the apartment by a large re¬ ceiver passed over it. The number of seconds which the thermometer now takes to sink firom one given point to another, or to the middle of its distance from the limiting temperature, is noted by help of a stop-watch; and the ball being thoroughly emptied and again successively filled with other liquids, the like obsen^ations are re¬ peated. Tliese several, intervals of time, allowing a slight correction for the matter of the shell itself and of the inserted bulb of the thermometer, will consequently ex- PHENOMENA OP HEAT. 263 press the proportional quantities of heat contained in equal bulks of the successive liquids. But their densities being already- known, it is hence easy to conapute their respective capacities, or the quantities of heat which equal weights of them are cap¬ able of containing. * By a process grounded on the same principles, the capacity of a solid, when broken or reduced to a gross powder, may be determined*.” 223. “ In the regulating of many processes of art, and in directing the purchase and selection of various articles of produce, the application of the hygrometer would render material service. Most warehouses, for in¬ stance, require to be kept at a certain point of dryness, and which is higher or lower according to the purposes for which they are designed. The printing of linen and cotton is carried on in very dry rooms; but the operations of spinning and weaving succeed best in air which rather inclines, to dampness. The manufacturer is at present entirely guided by observing the effects Leslie, p. 26—31. 264 PHENOMENA OF HEAT, produced, and hence the goods are often shriveled, or.otherwise injured, before he can discover any alteration in the state of the medium. But were an hygrometer, even of the most ordinary construction, placed in the room, it would exhibit every successive change in the condition of thle air, and immediately suggest the proper correctiofli The same means could be em¬ ployed most beneficially, in attempering the atmosphere of public hospitals. 224. “ That wool and corn have their weight considerably augmented by the pre¬ sence of moisture, is a fact well known. Without supposing that any fi-audulent practices are used, this difference, owing merely to the -variable state of the air in which the substances are kept, may yet in extreme cases amount to 10 or even 15 per cent. Grain or paper preserved in a damp place, will be found to swell nearly after the same proportion. But the real condition of such commodities might easily be detected, by placing the hygrometer within a small wired cage, and heaping PHENOMENA OP HEAT. ,265. overithiss fora few. minutes, aqxiantity of the wool or grain which is to be examiued*. 225. ‘^ The application of heat constant¬ ly increases the dryness of the air, or its disposition to dissolve moisture. This propGlty is so generally known, that the evaporating power of the medium is very seldom in . practice referred to any other cause. Drying houses, for example, are commonly constructed as if heat were to produce the whole effect; no means being emplo^'ed for aiding the escape of the air, after it has become charged with humidity, and consequently rendered unfit for per-* forming any longer the process of evapora¬ tion. 226. “ The influence of warmth in aug¬ menting the dryness of the air, or its dis¬ position to imbibe moisture, explains most easily a singular fact remarked by some accurate, observers. If two equal surfaces of water be exposed in the same situation, the one in a shallow; and the other in a » Leslie, p. 92—94. 266 PHENOMENA OF HEAT, deep vessel of metal or porcelain; tlie latter is always found, after a certain interval of time, to have sufiered, contrary to what we might expect, more waste by evaporation than the former. This observation was once made the ground, of a very absurd theory, although the real explication of it appears abundantly simple. Amidst all the changes that happen in the condition of the ambient medium, the shallow pan must necessarily receive more completely than the deeper vessel, the chilling impres¬ sions of evaporation, since it exposes a smaller extent of dry surface to be partly heated up again by the contact of the air. The larger mass being, therefore, kept in¬ variably warmer than the other, must in consequence support a more copious ex- 227. Professor Leslie’s new and very curious application of producing cold by evaporation, consists, in placing under the receiver of an air-pump, two vessels, one containing a considerable quantity of con-, PHENOMENA OF HEAT. 267 centrated sulphuric acid, or of muriate of lime, or of any other substance which ab¬ sorbs moisture from the air, and the other vessel holiiing a small portion of water. As soon as the receiver is e’iJiausted, the water begins to boil, though at a common temperature, and when a pretty good va¬ cuum is made, the pumping may be stop¬ ped, and after a while, the water becomes entirely frozen. For this experiment to succeed, the surface of the substance that absorbs the aqueous vapour, should be con¬ siderable, and concentrated sulphuric acid is preferred by Mr. Leslie to any other absorbent of moisture. Tire water to be frozen, must be in small quantity, and con¬ tained in a thin metallic dish*. For further information on the subjects of Mr. Leslie’s inquiries, I beg leave to refer to the work itself. In the “ Annales de Chimie ” for Jan. 1813, vol. Ixxxv, is a “ Memoir on the Determination of the Specific Heat of the * Aikin’a Chemical Dictionary, Supplement, p. 97. PHENOMENA OF HEAT. different G^es. By MM. F. Delaroche, M. D. and E. Berard.” “ This memoir {says Dr. Thomson in his Annals of Philos¬ ophy) gained the prize proposed by the Institute, and deserves particular attention. It overturns the theory of animal heat ad¬ vanced by Crawford, and Lavoisier’s theory of combustion.” From this long paper, I shall make the following short extracts, being the only parts of it which fall under my plan. 228. “ The difficulty of this sort of ex¬ periments has prevented us from determin¬ ing if the change in the capacity for heat by pressure be the same in all gases. This is exceedingly probable, as the increase of density of each from pressure is the same. Hence the opinion ought to be admitted till new experiments demonstrate to the contrary. We have no direct proofs of it, however. The very curious experiments of M. de Saissy*, if they are exact, may * M. de Saissy, a phUosopber of Lyons, has made, experiments, -firom. PHENOMENA OP HEAT. - 269 even induce us to entertain doubts on the subject. “ Specific Heat of the Gases, compared xvith that of Water and with different Solids and Liquids. ;229. “ We cannot make experiments to determine the specific heats of the gases without remarking, that, when equal volumes are considered, they are very small, com¬ pared to the specific heats of liquid and solid bodies. The most careless experi¬ ment is sufficient to prove the justice of this assertion, which a more exact exami^ nation fully confirms. Thus, if we compare the specific heat of an equal volume of olefiant gas (which under the same volume has the greatest specific heat) and of water, we find that the first is only the two thou¬ sandth part of the second. 230. “ If we take the same weight of each, the specific heat of the gases ap¬ proaches much more nearly to that of the solid bodies, as may be seen from the re¬ sult of our experiments, which we here lay before our readers:— 2T0 PHENOMENA.OF.HEAT. . - Specific heat. Water - - - - - - 1.0000^ Air. - - 0.2669 Hydrogen - - - - - 3,2936 Carbonic acid - - - - 0.2210 Oxygen - - - - - 0.2361 Azote - - - _ - - 0.2754 Oxide of azote - - - 0.2369 Olefiant gas - - - - 0.4207 ' Carbonic oxide - - - 0.2884 ' Vapour of water - - - 0.8470 232. “ From this table it appears, that, if we except hydrogen, which has the greatest specific heat of all known bodies, all the gases that we have examined have a smaller specific heat than water, and a greater specific heat than any of the metals. 233. “ The results which we have obtained by comparing the specific heat of the gases witli that of water, enable us to decide whether, as some have thought, , it would be. attended with a saving of fuel, to em¬ ploy the action of dilated air,. instead of steam, in steam-engines. We consider the ■PHENOMENA.OF HEAT. 271 question here under a point of view entirely theoretic, abstracting both the difficulty of constructing. such machines, and the loss of power, which could. not be entirely a- voided. Setting out from the specific heats of water and air contained in the preceding table, we have found that with the same quantity of heat employed in the one case to convert water of 32° into steam, but without raising its temperature higher than 212°, and in the other to bring the tem¬ perature of atmospherical air from 32°,to 212°, the effects produced in the first case would be to those produced in the second case as 1 to 1.285: but the advantage in favour of air would be much greater if the temperature were raised still higher *.. It is obvious, that, from the knowledge which we already possess of the quantity of heat given out by steam when it is condensed^ and from the data furnished by ^our experi¬ ments on the specific heats of the gases, it * “ Thus, if instead of applying the same quantity of heat to raise a mass of air from 32° to 212°, it was employed-to raise the temperature of §■ of . it from 32° to 572°, tlie effect produced in this case would be 3.043, or thrice as great as would be produced by employing the same quantity of was -very possible to arrive at the solution of this question; hut the calculations being somewhat complicated, and requiring, in order to be presented with clearness, details which might appear foreign to the subject proposed by the Institute, we will not give them here*.” 534 " It is necessary, therefore, unless we deceive ourselves, to abandon the hy¬ pothesis which ascribes the evolution of heat in cases of combination to a diminution of the'specific heat in the bodies combined, and admit, with Black, Lavoisier, and Laplace; and many other plulosophers, the existence of caloric in a state of combination in bodies. The knowledge of the specific heat of oxygen alone would be sufiicient to induce us to adopt this opinion: for it is so small that it is almost impossible for US to account for the great quantity of heat disengaged during the combustion of the greatest number of bodies, unless we sup¬ pose that this heat previously existed in a State of combination. Accordingly, wheii * TJiomson’s Annals of Fhflosophy, p. 435, 436. PHENOMENA OF'HEAT, 273 the opposite hypothesis was adopted, philos- opliers were obliged to suppose the specific heat of this gas, fifteen times greater than it is in reality. 235. “We must not supjpose, howeverj that there exists no relation between the specific heat of compounds and that of their constituents. Too many facts prove this relation to make it possible to deny it. Water, in this respect, constitutes the great¬ est deviation which has been observed; yet it does not exceed one-third of the specific heat of this fluid. In general, we may say that the constituents of a body communi¬ cate to it their specific heat. This is very observable in the combinations of hydrogen, which has the highest specific heat of aU known bodies. The compounds which it forms have a much greater specific-heat than other bodies. Hence the great specific heat of water, of olefiant gas, and of animal and vegetable substances 236.1 find, that many of our most eminent chemists, are not yet convinced of the ac- » Thomson's Annals of Philosophy, p. 4-39. 274 PHENOMENA OF HEAT. curacy of Mr. Dalton’s speculations, with regard to the law of the expansion of liquids, and its influence on the construc¬ tion of the thermometer (See Art. 14. 25;) nor are they disposed to admit the alteration in the thermometric scale, which Mr . Dalton proposes. Professor Playfair, however, seems to agree with Mr. Dalton; see'his “ Outlines of Natural Philosophy,” vol. I. p. 223. • Uie cold at Glasgow, in the t^ter of 1814, was very severe, but HEATING OF MILLS, &c. 275 SECTION 11. ON THE HEATING OF MILLS, DWELLING-HOUSES, BATHS,'AND PUBLIC BUILDINGS, BY STEAM. . Chimneys. 237. In consequence of an act of Parlia¬ ment, for regulating the height of chimneys of steam engines, and other works in the city and sub 'irbs of Glasgow, Messrs. Muir, Brown, & C i. erected a chimney 108 feet high, at their works. It is 3 feet square, within, and the flues of their various boilers are conveyed into it. ^^at they did, in compliance with the act of Parliament, merely with a view to prevent the un¬ pleasant effects of smoke, they find a very great saving of fuel, and (what is of equal if not greater importance) also of time. They now use cuhn instead of coal and • ■ * Tliere has never, I believe, been any very accurate comparison of Glasgow coal with tliat of Newcastle. Some are of opinion, that it re¬ quires about double tlie quantity of Glasgow coal to produce tlie same heat as that of Newcastle.' (See Art'67.) From the nature of .die thing; culm must differ much in its effects in producing heat Therefore, we may expect some results very different from that stated in Xrticle '68. ' , M m 276 HEATING OF MILLS, &c. tkey bring water, &c, to the boiling point in mucli less time then formerly. 238. Messrs. Robert Mutrie & Co. have with still greater advantage, erected a very handsome chimney at their works, at Man¬ chester. It is 120 feet high above ground, 3 feet square inside at top, and 11 feet square inside at bottom. See Plate 3, fig. 1. The strength of this chimney was put to a severe trial, by a tremendous gale of wind which took place in the month of December last, (1814.) It was then newly finished, and surrounded with the entire scaffolding, thereby exposing a much greater surface to the violence of the tempest; yet such is the excellence of the principle of its construc¬ tion, that it sustained not the smallest injury. 239. The advantage of liigh chimneys has alsobeenfor a considerable time experienced in Staffordshire, where they are built in the form of cones, They are made very large below, probably for the convenience of the introduction of many flues into one chim¬ ney, as well as for strength. The wideness BY STEAM. 211 bfilow IS of use also, la allowing room for changing the current of the smoke, from a horizontal, to a vertical direction, 240. The following observations on chim¬ neys, furnaces, and boilers, by M. Chaptal, appear to me worthy of the notice of the reader. 241. “ The air of a chimney, dilated by heat, may be considered as a lighter fluid than atmospheric air^ and wliich must necessarily rise with a rapidity proportionate to the difference of gravity, so that a rapid arid incessant current of external air through the fire-place must be established, in order to expel and occupy the place of that which rises. 242. Hence it follows: 1. That the high¬ er the chimney of a fuiuace is, so much the stronger will be the draught, provided the column of air can be heated and rarefied throughout almost the whole length; for otherwise, the circidation will only be im¬ peded. 2. That the draught will be more 278 HEATING OF MILLS, &c. rapid, the thicker are the sides of the chim¬ ney, or the worse conductors of heat are the materials of which it is constructed; because the heat being then retained within the chimney, the column of external air is less dilated by it, and consequently more dense, and better adapted by its excess of weight to expel the rarefied column in the chimney. 3. That the size of the chimney has no kind of influence over the draught; and that, in this respect, the dimensions should be de¬ termined by the volume of the column of air transmitted by the fire-place. 4. That the draught of a chimney may be ascertained by introducing an inflamed body into the interior of ik^.” 243. On the height and construction of chimneys. See. in the West Indies, see Ob¬ servations and Advices for the improvement of the Manufacture of Muscovado Sugar arid Rum, Part L; by Bryan Higgins, M. D. Printed, St. Jago De La Vega, Jamaica, p. 59. * Chaptal’s Chcmistiy, applied to Arts and Manufactures, p. 119, 120. BY STEAM. 279 Furnaces for Boilers. 244. “ The ash-pit should be wide, deep, and protected from too rapid currents of external aii’. It is separated from the fire¬ place by a grate which supports the fuel, the bars of which should be at such a dis¬ tance, that the coal cannot, fall through, but nevertheless not so close as to interrupt the passage of the air. To judge of the draught of the furnace, and to prevent the grate from being choked, you may place a basin full of water on the bottom of the ash-pit; the vivid light of the grate reflected in it shows, every moment, what points are choked, on which you restore the draught, by removing vfrthan iron poker, the matters which obstructed it, and by raking out the 245. For such coal as is used in Glasgow and its neighbourhood, a distance of about five-eighths of an inch, between the grat¬ ing bars, is foimd to answer well with large coal, and a distance of about three-eighths for culm. Bars of two feet in length, should Chajtal’s Chemistry, applied to Arts and Manufactures, p. 142, 14S. 280 HEATING OF MILLS, &c. be about one-and-arhalf inches thicls on their upper edge, and have their sides parallel, for about one inch downward, so as to preserve the same opening, after they have been a considerable time in use, and partly burned away. 246. In many of those manufactories whereboders are used for dyeing, and similar purposes, there is a great waste of fuel and destruction of the furnace-doors, owing to their being placed close to the end of the furnace-bars. In this case, much heat is lost by the doors becoming red hot. They are by that means, soon put out of shape, and no longer answer the purpose of excluding the air. There ought always to be a con¬ siderable space between the finnace-door and the fire. ^Vheh this is done, the doors continue to fit, and prevent air rushing be¬ tween the fire and bottom of the boiler. Boilers. 247. “ The form of boilers has always appeared to me to be an object of little im¬ portance, if the furnaces were but well con- BY-STEAM. 281 struGted. It is, nevertheless, true, that those o£ a circular form are more easily heated than the others, and that they are less liable to injury. I should therefore prefer them for the purposes of Evaporation only; but when it is necessary to work by dipping into the boiler, the manipidations'are ; ren¬ dered more easy by the square form; 'con¬ sequently the nature of the operations must decide with" respect to the form to be adopted. 248. “ The flat bottom of round boilers has always appeared to me to be attended with inconveniencies. 1. It is difiicult to empty the bottom of a boiler which has this form; 2. The impurities which often sully the contents, and are deposited over a large surface, remain exposed to, the tu^ multuous action of the liquid; 3, The liquid bears everywhere with its whole weight on the bottom already weakened by the heat.: 249. “ By making, the bottom of boilers to project inwards, so as to present a, con¬ cave surface externally, all these defects 282 HEATING OF MILLS, &C. may be corrected, and other advantages procured- 1. The fire is applied in a more equal maimer to eveiy point, firom this cir¬ cumstance alone, that the greatest heat rises in the middle. 2. This internally convex form opposes more resistance to the efibrts of the liquid and the action of the heat, 3 . The deposites formed in the bath are thrown to the sides of the boder which rest on the brickwork, where the fire is less active, and consequently where there is less danger of their forming a crust, and interposing between the liquid and the metal, which very often occasions the melt¬ ing of the boiler. 250. “ It has long been a subject of dis¬ pute, what proportions are the most advan¬ tageous to be given to a boiler. From the experiments with which we are acquainted, we may now deduce the following conse¬ quences. The quantity of fuel necessary for evaporation, augments only the volume of the liquid in the same proportion, so that there is an advantage in employing large boilers; but more time is required to bring BY steam; 9M |bke,latter to ebulUtioiL;, and as time is. an element of calculation in. the interest of the manufacturer, it depends, on, himself, to de¬ termine the dimensions of his boilers.- 251. Count Rumford kept boiling, at different times, for an hour, four hundred and forty, and; two hundred and eighty pounds of water. .In the first, instance, eighteen pounds of water were kept boiling by one pound of fuel, and in the second, only" twelve pounds. ;f r252. “ It may be adopted as, a principle, according to Coimt Rumford, that the sav¬ ing of fuel is greater in,proportion to the length of time necessary for producing ebullition . Gauge-Cocks t. . . 253.. Ror. small, boilers, a very good mod e is to Jiave one of the gauge-cocks- and pipes laid horizontally, - at- the highest surface proper for the water. ' "When filling the “ Cbaptal’s Chemistry, applied to Arts and Manufactures, p, 155—158. f See Art, 166. N n • 284 HEATING OF MILLS, &c. boiler, the attendant leaves the cock open, and allows the water to run into the boiler, until it runs over at the cock, which in¬ dicates the proper height. . METHODS OF CONNECTING STEAM-PIPES. Flanches*. 234. It seems now to be perfectly ascer¬ tained, that the best kind of joint for steam- pipes, whether horizontal or vertical, is that of flanclies, (See Art 153,) but they should have a projecting part on the one pipe, which fits into a recess of the other, to pre¬ vent the cement or jointing from getting into the internal part of the pipe when the joint is screwed up, and, by its rough¬ ness, obstructing the passage of the 'water of Spigot and Faucet Joints 255. IVhere spigot and faucet pipes are used, in order to remedy their defect for steam-pipes, drill a hole in the direction of the diameter of the pipe, quite thrbugh on both sides, and fit in an iron pin into it, which may project a little on each side. * See Art 153. BY STEAM. 285 256. The principal defect found.in the common spigot and faucet joint, when used for steam-pipes, is, that owing to the alter¬ nate expansion and contraction of the metal affecting each particular joint, the cement is apt to break, but when secured by an iron pin, as described above, and the pipes have free liberty to move at one end, this defect is remedied. 25Y. It is a good method to make the faucets with an inner part, no larger in di- meter than just to fit the spigot. This supports the pipe, independently mf the cement, and prevents the risk of the joint being hurt by any external stress. This inner faucet is commonly made about two inches deep, and has the spigot inserted one inch into it. The practice of some, is to make the outer faucet, or that which contains the cement, six inches deep, for all pipes above six inches diameter j and to make the faucets of all pipes below six inches, the same depth as the diameter of the pipes. ,286 HEATING OF SIILLS, 8ec. 258. It is usiM’to make the space for the cement, all round* the spigot,- rfiom three-eighths to one-half inch • that -^pidth is required, in order that the cement may be-firmly driven into the joint;. When the space is very narrow, this cannot be done. On the other hand, when too wide, there is a waste of cementy and a risk of injury from unequal expansion. Direction and An'angement of the Pipes *. 259. After they have been allowed to* cool, it is a great advantage, to be able to fill the pipes speedily with steam. The arrangement for that purpose, best suited in heating a cotton-mUl or large building of 'that kind, where the circumstances will permit, is to have one vertical pipe from the boiler^ from which a horizontal pipe branches off into each story, having liberty to expand at the farther end. Mr. Houlds- worth’s mills at Ahderston, are now heated on this arrangement. There is a stop-cock at each of the branches, where it springs fromthevertical pipe. The pipeshaveliberty • See Art. BY STEAM. 287-' to expand freely at the farther end, without thei ieast: risk- of breaking, or injuring the joints. But one of the greatest improve¬ ments in heating by steam, which has been yet introduced, is that the expansion of the pipes is made to. regulate the blowing of the air and steam, so as to allow.the pipes to: be speedily .filled, while all unnecessary escape of steam is- prevented.. When the pipes; are. cold, the pipes being at the shortest, they are connected with a puppet- valve,j which they keep open, so that upon the admission of the steam, the air freely escapes, at the further end. By the-time that operation is finished, the pipes grad¬ ually expand, and when . suj05ciently warm, shut the valve, so as to prevent all escape of steam.' . On. the common plan, unless there be a continual escape of steam, the pipes soon become cold.., A patent is at present in progress, for this very ingenious invention of Mr. Houldsworth. 260. Since the first three Parts of this Treatise were written, the application of steam, to the heating of cotton-mills, and 288 HEATING QE jnLLS, &c. for various purposes in other branches of the cotton manufacture, has greatly increased. PRINTING-OFFICES. Case I. 261. In December, 1812, I was several timesinMr. Dawson’s printing-office*, which has for a considerable time been heated by steam. That gentleman very politely showed me his apparatus, and communicated to me every required information respecting it. Although convinced that the arrangement oTthe steam-pipes is very far from being so simple as it might have been, yet he was fully satisfied of the advantage of the plan. He '.uses ;an inferior quality of coal, (the Ponlop,] and saves very considerably in the premium for insurance. He has 17,000/. insured. Formerly, when he used stoves, he paid 10s. 6d. per cent., now he pays only 3s. per cent. Case II. 262. In the year 1811, an apparatus was erected for heating, at a very small expense, • White Friars, London. BY STEAM. the Chronicle printing-of&ce, Glasgow, by steam, which continues to give satisfaction. The boiler is placed in the outer writing- room. The. steam-pipes issue thence to the floor of the press-room above, and lye along the middle of the floor. They rise gradually toward the further end, so that the rmter of condensation runs back to the boiler. The joints are of the spigot and faucet ¥indi. Observations. 263. This arrangement is simple, and as water of condensation to the boiler, there is a saving of heat, as well as of trouble, by the boiler requiring to be sel¬ dom fed with additional water, to supply the small waste. 264. The spigot and faucet joints are inferior to jianches, (see Art. 254,) but in this case, they all have answered well, ex¬ cept one, where there is an angle in the pipes, which was not intended, when the arrangement was first planned. This ap¬ paratus v/as constructed at the Port-Dundas Foundery, Glasgow. 290 HEATING OP JHLLS, &C. ■WAUEHOUSES. 1 265. An apparatus has been lately fitted up in the extensive warehouse of Messrs. ■Walkinshaw & Co. Glasgow. The boiler is placed in the sunk story, thence there is a Vertical pipe, from which there are branches into each floor, rising at the farther end, and l}ing for the most part under the counters. The joints are done with bolted fianches. Observations. 266. The bolted flanches are found to answer well. (See Art. 254.) The obser¬ vations relative to the 'H'otev of condenmtion, made on the heating of the Chronicle Office, (see Art. 261,) are applicable to this case. This apparatus also was constructed at the Port-Dundas Foundery, Glasgow, and gives much satisfaction in its use. D\raLLING-HOUSES *. Pitlcellony House. 267. Pitkellony house in Perthshire, hav¬ ing been damp and cold in the passages, ’ See Art 177, 178. 179. Mri Adam had, about the year 1810, an apparatus put up for heating the passages^ stair-case, and some of the rooms, by steam, lire farm-yard and offices are near the house. It is heated by a boiler which stands in the out-house where the potatoes for feeding the cattle are steamed. The pipe conveys steam into three pillars in the pas¬ sages in the lower part of the house, and in the stair-case. In each of the rooms which are heated by steam there is a steam- chest. The steam and air are blown off from a small pipe which passes into the external air. The rooms are seldom heated, but the dampness of the passages and stair¬ case require, during winter, the daily use of steam, which answers perfectly. Counting-Room at Kaidal. 268. Messrs. Braithwait, at Kendal, have for some years had their counting-room heated by steam. It is done in a very pecu¬ liar mode, and on what may be termed a new principle. In the room there is a small rectangular boiler, having its furnace includ¬ ed in a rectanglar cast-iron case, the whole 292 HEATING OF MILLS, &c. having the appearance of a chest standing against the wall. From the boiler a small pipe proceeds to the condenser, a copper vessel 18 inches diameter and 2 feet high, placed under a double writing-desk. The condenser is made on the plan of the im¬ proved cylindrical refrigeratories used by chemists in distillation; a very small quan¬ tity of steam is allowed to escape at the top, but it is condensed against the lid, so that none of it gets into the room. 269. The effect of this: apparatus, is to form a reservoir of heat; for the steam gives out its heat to the water in the condenser, which, when warm, retains the heat for many hours. The fire requires to be kept on only three hours in the morning, and the room remains comfortable the rest of the day and evening. • Ohser'valions. 270. This may be considered as a new application of steam in heating; and might be applied with advantage, in situations where attendance could not be regularly BY STEAM. given to the fire; for instance, in the case of hot-houses. (See Art. 210.) Steam applied in the common wa}^, however, begins to come into use for heating hot-houses. Mr. Rucker’s Blouse. 271. Mr. Rucker has for more than ten years had his house (about eight miles from London, and one of the most magnificent in England) partly heated by steam. It was done with copper steam-pipes, which were incased in other pipes of greater diameter, leaving a space around them, into which the external air was introduced, and which when heated, was conveyed into several apartments; but the apparatus was found defective in the following particulars;—A loud unpleasant noise arose when the pipes were filling with steam;—the 'water of con¬ densation escaped at every joint;—and the heated air was not produced in sufficient quantity to make the rooms comfortably warm. When consulted on the subject, I proposed substituting cast-iron steam-pipes, for those of copper, with several other al¬ terations, which have since been executed, 294 HExVTING. OF MILLS, &c. under tlie direction of Mr. E. Stuart Meikle- ham. Architect, 2, Staple’s Inn, London. Inn at Johnston. 272. The heating of the Inn at Johnston (see Art. 179) has been relinquished, not on account of its not answering the pui'pose, but for the reasons assigned by hlr. Neil Snodgrass *, in his letter to nia of 16th January last. “ Johmton, IQih January^ 1815. “ Dear Sir, , (Extract)—“ The cause of relinquish¬ ing the heating of the Inn of this place, by steam, arose from the change of landlords; Mr. Hodgait the proprietor, had extensive views, (when he began that system,) of a steam-kitchen, a large ball-room, &c. but in ,a short time thereafter, he let the Inn, and relinquished the business, before the plan was completed. The tenant, ignorant of every thing relative to steam, and in limited circumstances, was even afraid of the very * This geatleman Tvas the inventer of the improved scutching machine for cleaning cc-tton. BY STEAM. 295 name of steam-heat, and all at oiAce gaye it up, without a day’s trial, after he came into possession; and thus without the shadow df a reason, it was given up,—1 am, “ Dear Sir, Yours respectfully, «N. SNODGRASS.” Netherly House, 273. T was applied to respecting the heating of a part of Netherly House by steam, but I find from the following letter, from Mr. Ellis, Sir James Graham’s agent, that he was not fortunate in getting the work properly executed, particularly the joints of the pipes. Btish-Fam, Longiom, Jan. 1815. “ Sie, (Extract)—“ I have your letter of the 7th instant.—In answer to it, I beg to inform you, that the passage at Netherly is now heated with steam. The boiler is placed in the wash-house, and it supplies hot water for washing, and for a small bath 296 HEATING OF MILLS, &C. in an adjoining room, through which the ste^-pipes pass a small dressing-room and a water-closet, and then enter the passage, which is about 90 feet long. The passage at the farther end from the boiler, is 18 inches above the level of the lower end, the ceiling and floor falling together without a step, consequently, we were obliged to take ofi* the condensed water at the boiler end, as the situation did not admit of the pipe being lowered at the farther end, and although it was provided with an air-cock, and a pipe with a siphon, to take away any condensed water that might be forced to the end of the pipe, it requires a great force of fire to heat the passage, which is only about 6 feet wide, 8 feet high, and the pipe 4 inches diarrieter. The joints were badly executed, and did not prove drop-tight.— I am, “ Sir, “ Your most obedt-Serv‘- « L. ELLIS.” BY STEAM. 297 PUBLIC BUILDINGS. West Church, Aberdeen. 274. The West Church of Aberdeen has been for some years heated by steam. James Hadden, Esq. then first magistrate of that city, honoured me with the following letter. “ Aberdeen, 6th July, 1811. “Sir, - “ It being found expedient to warm the principal Church in this city, and conceiving the best mode of doing so may be by steam, a plan for the purpose has been made out. As you are conversant in steam-heating, I trouble you with a plan of our Church, and tire mode of heating it proposed, requesting you will give me yoim' opinion of it, as well as the size of a boiler that may be necessary; only you will please have in view, to warm, by the same boiler, another Church about the same size, at the end of the one now laid down. The pipes are proposed to be laid down into the ground with iron plates for coverings, 298 HEATING OP MILLS, &c. in order not to disfigure the Church.—- I am, “ SiK, “With respect,. &c. “ JAMES HADDEN.” 275. I accordingly made such remarks as occurred to me, and took the liberty of suggest^ some alterations on the plan. It has since been executed and has given much satisfaction, as appears from the fol¬ lowing letter from Mr. Alexander Cooper. “ Aberdeen, Febi'uary, 1813. - “ Dear Sir, “ I am favoured with yours of the 21st January, and shall consider it a pleasure to be of any service to you. The plan of heating the West Church with steam has been executed, and gives perfect satisfection. 1 this morning saw Mr. John Smith, the Architect, who executed the work, and who is a man of considerable taste and ingenuity. I have from his in¬ formation subjoined a few particulars in elucidation. ■ BY STEAM. 299 “ The boiler contains above 300 cubic feet, having been intended for heating a neighbouring church also, but even for both it would be too large. It was made much larger than ordered, and placed so high that the condensed steam cannot be returned. The pressure of the steam is measured by a steam-gauge, (^such as is used by Fenton, Murray, Wood, , & Co. Engine-Makers, Leeds,) on which it indicates 6 or 7 de¬ grees, but never more. : “ Consumption of English coals, about one-and-a-half bolls, at each heating, (thirty- six stone, Amsterdam, per boll.) The pipes have 668 feet of surface to 194,022 cubic feet of space; The fire is put to the boiler on Saturday evening, and continues until the congregation meet; in the afternoon. The temperature of the church is from 46" to 48", Fahr. and the presence of the con¬ gregation raises it to 50"—55". The pipe- tunnel being covered with perforated cast- iron plates, the heat ascends with some little difficulty, and to obviate this, a few plates Pp 300 HEATIKG OF MILLS, &c. here and there are removed, imtil the congregation are to meet.—am, “ Dear Sir, “ Yours respectfully, “A. COOPER.” 276. This Church is built of free-stone, with massive square pillars of the same material, in the inside; neither the pillars nor walls are plaistered, nor done with wainscot. Meeting-kouse at Kendal. 277. The Society of Friends at Kendal, had their Meeting-house heated by steam, some years previous to the time I saw it, which was in the . summer of 1811. The apparatus is exceedingly weU arranged, and the workmanship well executed, and it was done at a very small expense. The whole was designed and executed under the eye of Mr. George Braithwait, a member of that respectable Society, who is distinguished for his ingenuity and scientific knowledge. BY STEAM. 301 278. This Chapel is heated by 8 steam- pipes, of 4 inches external diameter. The whole space is about 26,640 cubic feet, 370 cubic feet of space are heated by one foot surface of steam-pipe. The pipes are placed under the back-seats, where no inconven¬ ience is experienced by the sitters, while the rest of the Chapel is comfortably warm. The water of condensation runs back to the boiler, which is placed in an adjoining a- partment, nearly as large as the Chapel. The boiler and flues make this apartment also comfortably warm. The Fortico at Manchester. 279. The Piiblic-Room and Library at Manchester, called the Portico, has ever since its completion been heated by steam. The boiler is placed in the cellar, the steam- pipes are placed within the wooden columns %vhich stand in the large room. The air and steam are blown off by small leaden pipes which descend from the top of the pipes into the cellar. HEATING OF MIILS, &c. BATHS. 280. Various methods have been em¬ ployed for heating the water for baths. ’ In some cases, steam is used to heat the water in the bath. At Sir Arthur Clark’s public baths, Dublin, the water is heated by steam in a separate vessel. At the Leith baths, steam is not used for heating the water, and it is never allowed to be of a higher tem¬ perature than 150°, and is conveyed directly from the boiler to the baths. 281. At Mr. Harley’s baths, Glasgow, it is brought to the boiling point, and mixed with cold water, to have it of the temperature re¬ quired. This last mode, I recommended for theproposedpublic baths at Largs*, as being found to answer well in practice, and as not requiring a boiler nearly so large and ex¬ pensive as the plan adopted at Leith, while it has the fiirther advantage, that the boiler may be employed for generating steam for the vapour-baths, and for heating any part of the building. Besides that advantage. ' On the sca-cnnst of Airsliirci BY STEAM. 303 whatever water goes . off in the form of steam, leaves the remainder stronger, or in other vs^ords, contains more salt than it would otherwise contain. 282. At Mr. Harley’s baths, in each of the rooms of the hot-baths, there is a square vessel, kept full of hot water, by being at¬ tached to, and communicating with, tlie hot water-pipes, which serves to keep the towels dry and warm. 283. Mr. Harley’s baths, taken as a whole, are perhaps the most complete in the king¬ dom. He applies steam very extensively to other parts of his extensive and useful establishments. It is but justice to Mr. Harley, to say, that he has by his exertions greatly improved a formerly unsightly part of the town, and contributed much to the accommodation and health of its inhabitants. 284. In connection with the baths, there is a public washing-house; and adjoining the byre, or cow-houses, already well known for their excellent construction i and coin- 304 HEATING OF MILLS, &C. plete system of cleanliness and manage¬ ment. He uses a steam-engine for driving various kinds of macMnes, for the use of his establishment, and the same boiler serves to steam the potatoes and other kinds of food for the cattle. 285. The application of steam, for pre¬ paring food for cattle, as well as for cooking victuals, has beenlong known and approved; but it is perhaps not so generally known, that tough and gristly meat is much im¬ proved when cooked by steam. Observations, 286. Dr. Kentish, at Clifton, near Bristol, suggested a plan for having their establish¬ ment formed for invalids, in a building to be kept always at a regidar mild temperature, which he intends to call a Madeira-house. See the Philosophical Magazine for 1818, 1814. Steam would certainly be well adapted to the purpose of producing such an artificial mild climate. ■BY STEAM. ' , t05 287. Two of the steam-boats on the Clyde have their cabins heated by steam, which may in some measure serve to show the practicability of heating ships by that agent. Where there is so much combustible matter as in ships of war, it would seem to promise much advantage; but those who are better acquainted with nautical affairs, can better judge how far this safe mode of heating might be applicable to that purpose. See Art. 210, note. SECTION III. ON HEATING AND DRYING BY STEAM. 288. On this branch of the subject I have little to add to what is said in Part III. Messrs. Muir, Brown, & Co. (See Art. 181) have greatly extended their apparatus for heating and drying by steam, a proof of their being convinced of its advantage. The same may be said of almost all the calico printers in the trade. It has also with great benefit been applied to lessen the danger in the manufacture of gun¬ powder. 306 HEATING OF MILLS, &C. BY STEAM. 289. In many of the most improved oil mills, the chaufer-pan ds now heated by steam, instead of charcoal. This mode is found to give proper heat with greater precision, than can be dons with a charcoal fire. ^F^JPEJVBIX. MISCELLANEOUS OBSERVATIONS ON CHIMNEY FIRE¬ PLACES, PARTICULARLY THOSE USED IN IRELAND. 290. It has frequently been a subject of inquiry, whether the ancients were ac¬ quainted with chimneys, or open fire-places. In the houses discovered at Herculaneum and Pompeii, there are no chimneys: they all appear to have been warmed by furnaces and flues. 291. It may be presumed, that, though 6ne or more expressions of ancient authors may appear to allude to a chimney, if the ancients were acquainted with the art of constructing, in mason-work, elevated fun¬ nels for conveying away the smoke, it must Q q APPENDIX. be allowed, when we consider the many proofs that occur to the contrary, that they were, to say the least, extremely rare. 292. It is not known at what time chim¬ neys began to be used. The writers of the 14th century seem either to have been un¬ acquainted with chimneys, or to have con¬ sidered them as the newest invention of luxury. That' there were no chimneys in the 10th, 12th, and 13th centuries, has been presumed from the terms “ ignitegkm ” or “ inprifegium,” the curfew-bell of the Eng¬ lish, and couvr^eu of the French; which seem- to intimate, that the people made fires in their houses in a hole or pit in the centre of the floor, under an opening formed in the roof; and when the fire was bm-ned out, or the family went to bed at night, the hole was shut by a cover of wood. ^ 293. The oldest certain account of chimr neys, is in the year 134'7 *. An inscrip¬ tion at Venice, records that at the above period a great many chimneys (molti ca- * See Beckmann’s History of Inventions, Tok II. p. 103. APPENDIX. mini) were thrown down by an earthquake. The first chimney-sweepers in Germany came from Savoy, Piedmont, and the neigh¬ bouring territories; and these for a long time were the only countries where the cleaning of chimneys was followed as a trade. Hence it is conjectured, that chimneys were in¬ vented in Italy. 294. It may be observed, that in the countries of modern Europe, the use of stoves prevail throughout the north; while in France and Great Britain, open fires are used. In the warm countries of Italy and Spain, there are very few chimneys, and the only method usually practised of tem¬ pering the cold, which is sometimes severely felt, is to burn charcoal in portable brasiers. 295. A chimney consists of a fire-place, in which the fuel is consumed, and a flue to carry off" the smoke and vapour arising from the combustion; thus affording the benefit of the heat of a fire without the in¬ convenience of its smoke. But these ob¬ jects were, and still are, very imperfectly 310 APPENDIX. attained; a large portion of the fuel being wasted without increasing the warmth of the apartment. 296. Dr. Franklin, in 1785, published “ Observations on the Cause and Cure of Smoky Chimneys.” He has very satisfac- tordj- explained all the usual causes of this defect, and shown their remedies. To this pamphlet succeeded the “ Essay ” of Count Rumfprd, in 1796, whose improvements in the construction of fire-places have been very generally adopted, These two works together, form a valuable body pf informa-r tipn. They are well known to the publie, but it is not sp generally known, that ex^ actly a hundred years agp, viz. in the year 1715, Dr. Desagulier published his bopk, entitled “ Fires Improved, being a new method of Building Chimneys, sp as tP pre¬ vent their smoking, &c,” which is a ti’ans^ lation of a stUl older work fi-ona the French of M. Gauger, which shows that the most, if not all, the principles pointed out by Count Rumfordwere understood, and are explained by M. Gauger. He also proposed seven APPENDIX. 311 difFerent constructions of cbimneys,in wHicb there are hollow cavities made by iron plates in the bach jambs and hearth, through which plates the heat passing warms the air in those cavities, which is continually coming into the room fresh and warm. This con¬ struction had many obvious advantages; but the expense and difficulty attending it, at that early period, discouraged the propa¬ gation of the invention. In our own timesj however, similar constructions have been brought forward as new, probably without the knowledge of what had been done so long before, and therefore with all the merit of invention. 297. To determine in what manner a room is heated by an open chimneyffirej it will be necessary to find out under.’wliat /om.theiheat generated in the combustion of the fuel, exists, and then to see howut is communicated to those bodies which are heated by it. ; . 298. In regard to the first of these sub¬ jects of inquiry, it is certain that the heat APPENDIX. 312 which is generated in the combustion of the fuel, exists xmder two perfectly distinct and different forms. One part of it is com- hined with the smoke, vapour, and heated air, which rise from the burning fuel, and goes off with them into the upper regions of the atmosphere, which is termed the mn- bined heat, while the other part which ap¬ pears to be uncombined, or combined only with light, is sent off from the fire in rays, in all directions, and is teiined radiated heat. With respect to the second subject of inquiry, it is highly probable that the combined heat can only be communicated to other bodies by actual contact with the body with which it is combined; and with regard to the rays which are sent off by the burning fuel, it is certain that they com¬ municate or generate heat only when and where they are stopped or absorbed. In passing through air which is transparent, they certainly do not communicate any heat to it; and it seems highly probable that they do not communicate heat to solid bodies by which they are reflected. APPENDIX. .313 299. A question which naturally presents itself here, is, What proportion does the radiant heat bear to the combined heat?— Though that point has not been determined with any considerable precision, it is, how¬ ever, certain, that the quantity of heat which goes olF combined with the smoke, vapour, and heated air, is much more considerable than that which is sent olF from the fire in rays; and yet small as the quantity is of this radiant heat, it is the only part of the heat generated by the combustion of fuel in an open fire-place, which ever is, or indeed ever can be, employed in heating a room. The whole of the combined heat escapes by the chimney,, and is totally lost; and no part of it could ever be brought into a room from an open fire-place, without bringing along with it the smoke, with which it is combined. 300. Many of the diseases proceeding from colds, may be ascribed to strong draw¬ ing chimneys, whereby, in severe weather, people are scorched in one part, while they are frozen in another. These fire-places are APPENDIX. 314 . of little use iii warming a room, because the air around them which is warmed by the direct rays of the fire, does not continue in the room, but is continually collected into the chimney, by the current of cold air coming behind it, and is presently carried off. Besides, the greater part of the fire is often lost, being absorbed by the back jambs and hearth. 301. In such parts of Ireland as I have visited, the chimney fire-places are con¬ structed in a way that appears to me Well calculated to remedy, in some degree, the defects which have been mentioned, and to economise fuel. Probably its high price in many parts of that island, prompted greater attention to the subject than with us, where it is abundant. The grates are wide; the space from back to front is small; so that a great surface of the coals is exposed to send out the radiant heat. The space above the grate is shut in by a piece of stone, about II inch thickj cut out in the form of an arch over the grate. The back is formed into an ehptical niche, leaving only a very- AP^E^fDlX. SIS siittall opefiing fot the smoke to escape up the chimney. Fig. 2,- Plate III, is a sketch of one of these grates, frorii memory; the sketches and dimensions which I took on the spet haiving been unfortunately lost. ABCD represent the grate, ,AEGB is a thin front-plate of stone, AI'IB the arch fei-ming the front of the niche, I the back, iCL the throat; 302. The effect of this construction, is, that the combined heat and part of the radiant heat acting on the curved back, (which should be formed oi fire-brick or fire-stone,) heats it, and like a concave mirror, reflects it into the room, while the narrowness of the throat prevents a great deal of unnecessary escape of heated air up the chimney. 303. When I first observed one of these chimneys at Belfast, I supposed the land¬ lord to be a man of some science, but was' surprised to find, in pursuing my journey from Belfast to Dublin, and even 80 miles more to the south, that this construction R r APPENDIX. 316 prevails, from the lowest inns to the houses of the opulent, the only difference being in the degree of ornament. 304. But a still more perfect method of heating apartments in temperate climates, where we have the cheerful appearance of an open fire, is what we call a stove-grate, of which there are a variety of constructions now in use, some of which were mentioned when speaking of M. Gauger’s work. On some parts of the Continent, it is called chapelle, from its resemblance to the chapels or oratories in great churches. 305. In the great chimney-piece, which in this case may. be made even larger than ordinary, is set a smaller one, fitted up in the same style of ornament, but of a size no greater than is sufficient for holding the fuel. The sides and back of it are made of iron, and are kept at a small distance from the sides and back of the main chimney- piece, and are continued down to the hearth, so, that the ash-pit is also separated. The pipe or chimney of the stove-grate is car- APPENDIX. Sir tied up behind the ornaments of the mantel¬ piece, till it rises above the mantel-piece of the main chimney-piece, and is fitted with a register or damper plate. All the rest of the chimney is covered with iron- plates or brick-work. 306. The effect of this construction is very obvious. The fuel being in immediate contact with die back and sides of the grate, heats them to a high degree, and they heat the air contiguous to them. This heated air cannot get up the chimney, because the passages above these spaces are shut up. It therefore comes out into the room; some of it goes into the real fire-place, and is carried up the chimney, and the rest rises to the ceiling, and is diffused over the room. Less than one-fourth of the fuel consumed in an ordinary fire-place is sufficient; and this with the same cheerful appearance and salutary renewaLof air. 307. Mr. Moser, Ironmonger, of Frith- Street, Soho, London, manufactures stove- grates very nearly on this principle, in an 318 Appproix, ele^nt manner, The air does not eoine in imniediate contact with the iron parts of the stove-grate, but passes through thin boxes or retorts pf earthen-ware, which prevents the airfiropa being contaminated, as it would be by coming into contact with iron in a high temperature. 308. The Church of Christ-Church Hos^ pital, London, is heated by one of Mr. Mg-r ser’s stove-grates, in the middle of the cen-, tre area. Also that much admired structure of Sir Christopher Wren, St. Stephen’s, Walbrook, is heated by two of those stove- grates, placed in opposite sides of the Church *. * See “ Fires Improved, being a new method of building Chimneys so .as to prevent their smoking, in which a small fire shall warm a room better than amncfa larger, made the common way. With the manner of altering snch chimneys as are, already built, so that they shall perform the same effects, ninstraied with Cuts. Written in Fren cb, by Monsieur Gaugee : made English and improved by J. T. Desactoieks, UL A. F. R. S. By whom is a d de d , the manner of making coal fires as useful this new way, as the wood fires proposed by the French author: explained by an additional plate. The whole being suited to the capacity of the meanest “ Observations on the Causes and Cure of Smoky Chimneys, by Dr. Feakklis.” “ Count Kumeoed’s Essays on Chimney Fire-Places.” “ Encyclopedia Britamiica,” article Pneumatics. '• Dr. Sees’ Encyclopedia,” article Chimuey and Pire-Placc. 0 ARPSNBiS, 319 ON STOVES. :809. The construetion of stoves is ex¬ ceedingly various, although their general principles are simple. 310. Stoves, in general, may be defined to be fire-places enclosed on a,11 sides, having only a passage to support the fire, under a tube, for carrying ofP the smoke. The air of the apartment is warmed by coming in contact with the outside of the stove or flue. 311. The effect of a stove, made on this principle, depends much on retaining the air, already heated by it, in the room. This is so remarkably the case, that a small open fire in the same room will be so far from increasing its heat, that it will greatly di¬ minish it, by diwing in the external air. 312. On the Continent of Europe, where fuel is scarce, especially towards the north, much care and ingenuity has been displayed in the construction of stoves, combining APPENDIX. elegance with economy. The air of a room may be equally warmed, either by using a small stove, made very hot, or a much larger stove, more moderately heated. 313. The first kind is chiefly used in Holland, Flanders, and the milder climates of Germany and Poland. The last kind are universally used in the fiozen climates of Russia and Sweden. 314. The first, are generally maide of cast- iron*, and the last, of brick-work, or rather glazed tiles, and are constructed on excellent principlesi The Russian stove is a sort of magazine, in which a great quantity of heat is accumidated, to be afterward slowly com¬ municated to the air of the apartment. It is therefore built extremely massive. Its internal structure is that of a long pipe of flue, returned backward and forward. Tlie * At the Port-Dundas Foundery, Glasgow, a variety of improved iroii- stoyes are mamifartured. One kind is peculiarly convenient^ where a fire is wanted to he kept in all nighk with hardly any consumption of fiieL By means of a roister, at any moment it may he made to bum briskly. These stoves are sold by Mr. Kobert Anderson, Ironmonger, APPENDIX. 321 fire-place is below, and is shut in with a small door, after the fire is consumed. So long as any blue flame appears on the char¬ coal it is kept open, in order that the fuel maybe thoroughly consumed. The manage¬ ment which this requires, is the principal in¬ convenience of the Russian stoves. If it be not reduced to ashes before the door is shut, it exposes people to imminent danger of suffocation, by fixed air, and many fatal accidents have happened from this cause. There are many instances known in which people have lost their lives in this manner. In those countries, the windows in winter are generally double, to increase the effect of the stove. 315. Since the increase of the manufacture of cotton in this island, stoves have been much used in various buildings appropriated to that business. I shall here make some observations upon those which have been used for that purpose. 316. Till of late years, almost all cotton- mills were heated by stoves. Those origi- APMNfilX. nally used, were what are called coakles or round stoves of cast-iron, according to the size of the rooms; one or more of those stoves were used for carrying ojff the smoke, having a horizontal pipe, and communicat¬ ing more heat to the room. 317. This plan, although very effectual in point of warmth, is very defective in the three following respects: 1st. In Cleanlmess. They occasion much ashes and dust in the apartments. ^ In Salubrity. The pipes being red hot, or even only heated to a high degree, contaminate the air, by burning the small particles of dust floating in it, or, as JMr. Dalton supposes, by decomposing the water suspended in the air, by which hydrogen is evolved, and a very disagreeable and op¬ pressive smell produced. 3d. In Safety. It is evident, that stoves so exposed are veiy dangerous in any budd¬ ing, but more particularly so in cotton- jvp^Nflix. .323 miUs, amid a:gpantil;y qf so Idglily-com- ,blisi;ible materials. 318. ,These,i|icpny,eniences , having been -spripusljjfplt,, another plan . w^as tried, viz. •that of placing the stove in a separate ^apartni.ent, enclosing it with brick-work, ;J?avh>g^,J^plpw^ pnlj ..an ppening for . the air, 3yhich,heing,rare%d, passed up a flue, and ..by mpans.pf registers,, was introduced mto .the.yaripus . apartnaents. This plan i^yas in ,s,pnie n’espects a grpat improvement. In many, instances,. Ijpwever, the, principle was ill .applied, „ apd. from. an inj udicious con- .-st^uction, the .air \yas not only rendered . .npjdpus, hut from the. Intense heat of the cpal^e, >niany,accidents ^ happened by fire; .andjit. is ,an ..ascertained.faqt,, that a lai-ge ..pyopprtion.,pf, the aq^dentaf, fires which ..haveJiappened in mills,, originated from ill pply, however, as T; have said, from an injudicious construction, , ihpt these accidents' occurred. The fault prmcipally^.u'as, that the surface of the, iron . cpakle and pipe was too small in propor- ...tipn .to the. area. of building to be heated. APPENDIX. This, of course, required the iron to be made red hot. The surface ought to have been greater, and the heat more moderate; instead of which, the surface was generally small, and the heat intense. But the greatest defect of this kind of stove was, that the air which was heated by it, did not come suf¬ ficiently near to the surface of the iron stove to carry off the heat as fast as it was gen¬ erated. The effect accordingly was, that by this confined heat, the coakle was very soon burned through. The hot air having pre¬ viously rendered the wood very combusti¬ ble, as soon as the fire had burned through the coakle, the timber was very apt to take fire,andoccasion the destruction of the budd¬ ing; and even when this accident did not occur, the atmosphere of the apartments must have been much contaminated by the adust air proceeding from the fire within the coakle. This kind of stove, so long ago used in cotton-mills, and afterwards, for the reasons above stated, abandoned, has lately been brought forward as a new invention, and a patent obtained for it. The new Church in Charlotte-Square, and a number APPENDIX. 325 of other buildings in Edinburgh, have been recently heated on this plan; which cir¬ cumstance shows, that science alone is not sufficient to bring things to that degree of perfection, which is often attained by prac¬ tical men, where they are prompted by their necessities or interests, aided by experience. Wliile the imperfections of those stoves, in many instances, instigated the heating of cotton-miUs and other manufactories by steam, it also led to greater improvement in the stoves themselves. 819. I shall now proceed to mention two other kinds, constructed upon better prin¬ ciples ; the first kind is probably the least expensive, the second more perfect, both in regard to safety and to the economy of fuel. These two stoves are constructed on the same general principles as those already described, but on a superior modi¬ fication of those principles; the air in them being brought to rush in more rapidly on the coakle. The coakle, which is an inverted vessel, (in one case, square; in the other, dome-shaped,) made of iron, 326 ATPENBIX. and having no opening either on the top or on the sides; the smoke being carried off below, receives nihch more liei^t fi*6hi the fire within, than the stoves above described. The advantage of tho air im¬ pinging strongly on the coakle,' isf, fcat the heat is carried off into tlie apartihents nearly as fast as it is genmated. This ntay be illustrated by the case of a boiler. While clean at the bottom, and filled,' at least partly, with water, the water absorbs the Iieat as fast as it is geherated, aiid the fire does no harm to the metal. But if the boiler be empty, the air being a less perfect conductor of heat than ivater, the boiler is soon burned through. Or, if the watei’ be impure, so as to deposit a sediment, thereby increasing the thickness bf the bottom, and this sediment being a less perfect conductor tliaii the water and the metal itself, the latter will soon be burned oiit. Helice the evil of water containing much lime or other im¬ purities, when used for the boiler of a steam-engine. 320. Tlie stove, represented in Plate lit. Fig. 3, Nos. 1 and 2, was erected in the AT^PENDIX. 327 y6ar 1816, under illy direction', in a cotton- iniliv About the same time, I erected two- more for other cotton-mills. All these stoves continue to give satisfaction, a:nd' they have never (so far as is known to' their proprietors) required any repair.- These stoves are still at work in the neighbour¬ hood of Glasgow. 321. The accompanying description of the stove, (that upon the construction of Mr. Strutt oi' Derbjj) represented in Fig. 3, No. 1, is so miniitej that the stove shown in Fig; 4, Nos. 1 and 2, (constructed by Mr. Murray of Leeds,) will be easily coih- prehfehded from inspection. I may, how¬ ever, mention, that No. 2 has the pauj or coaklej made of cast-iron, and that it has been used^ for at least seven years, for heat¬ ing a flax-mill. 322. It should be observed, that in all the cases of heated air-stoves, mentioned above, they have been found defective in as far as i*elates to the heating of the /owesi fiaor, the local situations not permitting the stoves to be placed sufficiently low. APPENDIX. 323. A very great improvement has been lately made, by Mr. WiUiam Strutt of Der¬ by, in those air-stoves, by using a tube, about 100 yards distant from the building, having a funnel turning to the wind by a vane on the top of it, for supplying the air to the stove, (somewhat as ah air-sad is used on ship-board,) and another on the budding, turning in a contrary direction, for carrying off the-air. This apparatus greatly increases the current of air over the stove; and it was not only found, even during the last severe winter, (1814,) to heat the budding (the Infirmary of Derby) quite sufficiently, but it serves,at the sametime,to ventdatethe whole house. In summer, when, of course, there is no fire made in the stove, the air being, in its subterranean passage, cooled, serves to temperate the air of the different apartments. This subten'anean channel, from its depth below the surface, is so near the mean temperature of the earth, that the air of winter is partiady warmed, whdst that of summer is considerably cooled. In the greatest heat of summer, at this place, the temperature of the air is lowered in its pas¬ sage 20“ of Fahrenheit’s scale. APPENDIX. Description of Fig. S, Nos. 1 and 324. DDD represents the stove-coakle, made of plate-iron, one-fourth of an inch thick, having the shape of a dome, the sec¬ tions of which in each direction are semi¬ circular. It is open at bottom, and stands upon the brick-work CC, containing the fire¬ place T. At 6 inches distant from the sides of the stove, aU round is the perforated wall EE, 9 inches thick, which is also continued over the dome, arch-wise, from each of the four sides meeting in the centre. This wall is composed of bricks laid with their ends towards the stove, and in each com’se be¬ tween every two bricks, a tube of thin sheet iron is inserted, reaching to within about three-fourths of an inch of the stove, and having about 2 inches hold in the brick¬ work. The bricks of the second course lye over the tubes of the first course, and so on alternately. The size of the air-tubes is 21 inches deep, and 2 inches wide by 7 inches long, exclusive of wings cut out of the plate, 330 APPENDIX, which being built into the joints of the brick¬ work, serve to steady the tube. They are made of black sheet-iron, aboutjthe thick¬ ness of common tin-plates, with a lapped -joint on the lower side. The hncks for these walls should be 5 inches broad, ,by 2; inches, and 9 inches, which will ,leave more space for the air to ascend betvyeen them. Those Tor the arches, should , he made in the form of a wedge, to, a proper radius, 5 inches broad, and 2? inches thjck at the thin end. The tubes are cemepted into the brick-work, by some fine plaster- lime mortar, but care must be taken to drop none into the space //, in laying the Tricks ■or tubes. The perforated wall is surrounded. by tlie cold air-flues KK, which are 2 feet ,2 inches wide, and 3 inches high, co,n- .taining a certain number of courses, accord¬ ing to the size of the stove of bricks and tubes, of which height they are covered over, all round by the flag-stones -VV, 6 inches thick, and rabbeted in the joints. APPENDIX, 331 ■ The arched dome of the perforated wall will be best explained by the figures. It should have the same number of tubes above the stone division, as the perforated walls below have; because all the air which enters by the tubes, must issue from the tubes above. In forming this dome, after all the sides have been carried up equally to a certain height or inclination, the bricks will require some supports, to prevent then- falling inwards. The mortar in which the bricks of the arches are laid, should be pretty stiflT and fine; and, although the arch may sink a little, the tubfs should be kept a little farther from the stove than those in the perpendicular sides. JJ is the Jire-plnce. A slit (m) formed between tlie iron bar (1) and another which is riveted to the lower edge of the stove, forms the exit for the smoke, which descends by it into the flue (L). This slit is about half an inch wide, being a little more in area than all the slits of the fire-grate, The regulating if on bar (1) has a notch at each end, which drops down APPENDIX. 332 upon a projecting piece, riveted to the stove at each end; and, if the slit proves too wide or too narrow, it can be adjusted by altering the notches at the ends of the bar. In the cliimney are a sliding damper, and a door, made to shut very close; the use of the latter is, to put in some lighted paper or straw, to cause a draught in the chimney at first lighting the fire on the grate, which otherwise may not immediately begin to act. The Operation of the Stove. 325. As soon as the fire is lighted, the smoke passes down by the slit (m) to the flue (L), and fi’om thence to the cliimney the stove gradually becomes warm, and heats the air in the space (h) which sur¬ rounds it, and by means of its becoming lighter, the air passes out by the tubes in the perforated arches, and "more air enters by the tubes in the perforated walls, from the cold air-flues, which being conducted by the tubes, close to the sides of the stove, blows against it like a bellows, and becomes warm in its turn, and ascends as before; but it APPENDIX. cannot pass out by the tubes in the dome, without again coming into contact with the hot stove, which farther increases its heat; and at the same time these ciuTents of air serve to prevent the stove from becoming too hot, if the fire is properly regulated. Air-chimneys should be made in each apartment, to let the air out of each story, otherwise the hot air may not readily enter. They may be made of wood, and should each have a turning valve, which should always be fully opened before any fire is made in the stove. The smoke-slit (m) will be apt to choke with, soot, which must be removed fi'om time to time. This may be done by draw¬ ing along it a crooked poker, having a point downwards fitted to the slit. The thin iron ceiling is shown in the ver¬ tical Section. On the under edge of the joists should be knobs; the use of which is, in some degree, to protect them from the heat, and by that means to lessen their ex- APtEiJbiXi pansibn and contraction^ To these knobs are screwed two sets of thin iron bars, three-eighths by two inches, wliich embrace between them the edges of the thin iron plates which compose the ceiling, and which should meet edge to edge between the bars, with notches in them to free the screws. The plates may be simply laid over one another two inches, where they meet at their ends. The holes in the thin bars must be made easy for the screws, that they may be allowed to expand, and they must not touch each other, where they meet at the ends, for the same reason. The ends of the joists must have a plate of iron laid upon the wall under them. When the joists are laid, and the ceiling screwed up to them, and the joists made good^ the whole is filled with ashes about nine inches deep. These ashes should be from house- fires, and sifted through a fire-sieve. The air-chamber (Y) serves to conduct the cold air from the door at which it enters APPENDIX. 335 to the cold air-flues by means of the open¬ ings (aa). Great care must be taken, in building these flues and their arches, that they may be perfectly smoke-tight, especially where they pass under the cold air-flues * On German and Russian Stoves, see Encyclopedia Britannica, article ’Pneumatics and Stove. APPENDIX. FARTHER DETAILS RESPECTING THE HEATING OF PITKELLONT HOUSE. (ScO Art. 207.) 326. The following letter from Mr. John M'Naught*, who executed the apparatus, came to hand too late for insertion in its proper place. Paisley, March 22c?, 1815. I)ear Sir, (Extract)—“ The steam-apparatus at PitkeUony house, was put up in October, 1811. There had been a boiler in one of the out-houses, for the purpose of steaming potatoes for feeding cattle. As Mr. Adam wished to heat the dweUing-house from the same boiler, a copper pipe was conveyed from the boiler along the lobby, and from that pipe took branches into the adjoining rooms. Tlie heaters were made pretty much in the form of a Rumford chimney without the grate, the front and backs were cast in separate pieces, and joined together with iron cement; the under part projected towards the floor, in the form of an ogee, covering part of the hearth, for the purpose of warming a person’s feet, and also of ex- • Formerly of Johnston, now of Paisley. APPENDIX. ■ 337 tending tlie heated surface, as much as pos¬ sible, on the lower part of the room; the chimney being filled up in the throat, and plastered over, allowed none of the warm air to escape in that direction; the steam was taken into one of the corners of the heater, and a pipe taken from the opposite side, connected it with the next heater, and so on through three rooms in the under flat. The steam, after expelling the air out of the first heater, proceeded to the next; in like manner, thi’ough the whole; and a pipe was tak^n through the wall and put into a box, which being inverted into a gravelly soil and covered over, the water easily found its way without any appearance of steam. The stair-case was heated with a large cast- iron pillar, and a pipe taken from the top, heated, a room up stairs; being a small pipe, it was pretty well concealed below the steps of the stair, and afterwards by the moulding above the floor, and the con¬ densed water carried through the wall, and into the gravelly soil, as the others.—I am, . “ Dear Sir, “ Your most obed'- Serv''- “JOHN M‘NAUGHT.” 338 APPEIfDlX. ACCOUNT OF THE LIJIE-KILNS AT CLOSEBURN, DOMFRIES-SHIRE. 327. The use of lime in building, as well as in agricultiure, is too obvious to require proof, and every improvement in the mode of burning it, whether respecting the qua¬ lity of the Ihne, or the economy of fuel, and stm more when it embraces both, these advantages becomes an object of national importance. In the Valley of Closeburn, on the river Nith, there is a body of excellent lime^stone, which is wrought op a very ex¬ tensive scale by the proprietor, Mr. Mon- teath. It makes an ample return for the labour bestowed; and he has been at much pains to improve the lime-works. Besides his own unwearied labour and experience at home, he has visited every lime-work of reputation in the island, and has selected and combined every thing that appeared to be advantageous, while he has made several improvements of his own. Tlie re- sidt has been, that his kihis are probably the best in the island. APPENDIX; . 339 Instead of the wide and shallow circular kiln, common in the country, Mr. Menteath has found much advantage from making the kUns elliptical and deep. So much with regard to the form of the kilns. Mr.' Menteath has lately added some parts to it, which are found of most important use. The first is a kind of roof or cover. The want' of some contrivance to protect kilns in stormy weather has long been felt j and various attempts have been made to supply this deficiency. Hitherto, we believe, no covering has been found to answer so iveU as that used at'Cldseburn; and which is re¬ presented in the annexed sketch. The next addition, is, that of having castdron doors below at the opening, where , the kiln is drawn. There is a grating, through which the ashes fall while drawing the kiln, which makes that operation a much less disagree¬ able employment than formerly. Thp U u 340 APPENDIX. ashes and small lime thus separated, are excellent for agricultural purposes. There is often a great loss of fuel from allowing lime-kilns to cool, when there is no demand; but in those of Mr. Menteath, when there is no demand, aU that is neces¬ sary to be done, is to shut the cast-iron doors aboye, as well as below, and the dampers in the chimneys. The heat is thus preserved, and fuel saved, by keeping the kiln hot, to be ready for use when wanted. Fig. 1. Plate IV. is a vertical section through the middle of the kiln, wherein AB is the mouth, into which the lime and coal are thrown. It is elliptical, being about 9 feet long, and 4i ivide. The kiln continues of the same width to about 18 feet from Ae bottom, when it begins to taper until it is only 22 inches wide below. CD is one of the three openings below, by which the lime is dravm from the kiln. DEFG is the arched-way by which the lime is removed when taken from the kiln. APPENDIX. 341 AHIB the roof or cover of the kiln, which is shown on a larger scale in Fig. 2.i Nos. 1 , 2 , 3 , 4 . . Fig. 2. represents the roof, which con¬ sists of a cast-iron frame, upon which the doors k k k k are hung. These doors are opened for the introduction of the lime and fuel. The frame also serves to support the brick arches LMN, upon which are raised the chimneys o o o; and for carrying off the smoke. Fig. 3. is a front view of the arch-way, showing the doors for taking out the lime below. P P P the doors from Avhich the larger burned lime-stone is taken. There is a grat¬ ing, a b, Fig. 1. through which the ashes and smaller lime fall, which is removed from time to time, by the doors QQQ. These last doors are kept shut while removing the larger lime-stone from the doors P P P, and the people are thereby prevented from being annoyed by the dust. APPENDIX. 342 .Since, writing the foregoingj ii have been favoured, with the, annexed letter from Mr. Menteath, which wUl serve more fuUj to elucidate the subject. “ Closebum-Hall, Nov. Isf, 1813. “SlE, “I.received your letter of the ^Ith of last month, wishing me to send you some particular account of the covers, which I have placed upon tlie top of my lime-Mlns. As you have the dimensions of the covers, I have only to state my opin¬ ion of their utility in facilitating the burn¬ ing of lime-stone. I conceive the greatest advantage to be derived from them, is m the Autumn and Winter season, when a kiln is not worked for more than eight or ten hours each day, when the fire remains long at the.top of the kiln during .a .great part of the remaining sixteen or eighteen hours of the twenly-four. "ViTien the work¬ men are not working the kiln, the foe, by means of the cover, is prevented from es¬ caping during the cold and stormy weather at this season. It is likewise of much use APPENDIX. 343 in, preventing tlie escape, of heat, in ease of a kiln being allowed to remain unworked for a day or two, which frequently happens in our country sales, from an irregular demand for .lime. -I am of opinion, that the covers with chimneys in them, increase the. draught of air, through the kiln, by which-means, a given quantity of lime-stone is calcined in a shorter time; but owing to the prejudices of the tacksman and his workmen, it is dif¬ ficult to get at the truth of any thing. The workmen allow, that, owing to the .covers, they put a less quantity of coal into the kiln in the evening, in the winter season, than they would otherwise do, if the kilns had not tops; and also .upon Saturday night, and Monday morning, when an open-topped hiln requires additional coal to make .up fordhe greater loss, or escape, of heat than goes off from a covered kiln. When yon were here, I mentioned to you my having fixed doors to the eyes of the kilns, which are useful, if it be necessary to allow a kiln to stand unworked, (which is frequently necessmy for the reasons I have above mentioned,) by preventing .the lime from APPENDIX. 344 slacking at the bottom; and the doors have the effect of stopping the escape of the heat at the top. “ I last year increased the height of my kilns from 24 feet to 30 and 32 feet, which, I am of opinion, has had a tendency to save fuel in the calcination of the lime-stone; but I was disappointed in my expectation of drawing out a greater quantity of burned stone each day, than I was accustomed to do, when the kilns did not exceed 24 feet in height. “The dimensions of my kilns are now about 10 feet long at bottom, 22 inches wide, and 20 feet high. After spreading gradudly from the bottom, the width is Ai feet, and the remainder ten or twelve feet. The sides of the kiln are perpendicular, and of course, 4i feet wide at top. My Tacks¬ man thinks that he can burn lime in a nar¬ row kiln of those dimensions, with a less quantity of coal than is commonly used in long circular kilns. I think a circular kiln of not more than 5 feet in diameter, and APPENDIX. 345 30 feet high, burns lime with as small a quantity of coal, as the long narrow OVal kiln; hut the objection to it is, the small quantity of burned lime it produces every day.—I am, “ SiK, “ Yours respectfully, « C. G. S. MENTEATH.” Since the foregoing was written, Mr. Menteath has suggested several improve¬ ments on the covers of the kilns, particu¬ larly that of using doors composed of fire¬ bricks, or of fire-tiles, in iron frames, and suspended by chains, similar to those of an air-furnace for melting iron. I am informed that many fatal accidents have happened to ships, owing to the light arising from open lime-kilns. The seamen, in dark and stormy weather, mistaking them for light-houses. In such situations, those covers to lime-kilns might be the means not only of securing property, but also of preserving lives. 346 GAS-LIGHTS. ... 328. Since Art. 58. was printed, I have read the “ Speeches of H. Brougham, be¬ fore the Committee of the House of Com¬ mons, in opposition to the Gas-light and Coke Compan}’^,” where he states many curious and important facts; two of which it will not be improper here to mention. 1st, That six pounds of coal produces light equal to one pound of tallow^ 2d,, That; the London Fire Company * offered’ to insure the works of Messrs. Phillips & Lee, after they were lighted by the coal-gas, at one- half the former premiums The coal-gas gives a peculiarly softj clear, and steady light. It has an advantage over candles and oil-lamps, in requiring no. snuff¬ ing or trimming;; and;* therefore, avoiding one source of danger from fire,; to which cotton-iiiills’are peculiarly exposed. A de-i scription. df a -^s-light apparatus, on the large - scale, is given'by Mr. Tj Clegg, , in the Phil. Jdum. voL 'XXIII. p. 86. He es¬ timates the cost of a complete apparatus, APPENDIX. . 347 capable of supporting forty lamps for four hours, each lamp affording light equal to ten candles, of eight in the pound, to be about 250?. * Mr. B. Cook, of Birmingham, has given the results, of his experience in the employ¬ ment of coal-gas-light, in the Phil. Journ. voL XXL p. 293. Among other advan¬ tages, it is particularly convenient for that hind of soldering which is commonly per¬ formed with the oil-lamp, for the gas-light gives a sharper flame, and is also ready at the instant; while, with oil and cotton, the workman is always obliged to wait for his lamp being sufficiently kindled to do his work f. For several years, coal-gas has been more or less employed for lighting the streets of London; but last winter its use was greatlj'^ extended. Westminster Bridge was, for the first time, illuminated with gas, and made a most brilliant and splendid appearance. * For lighting large cotton-mills, one guinea for each cockspui-light has been estimated as suSicieiit to erect tliu whole apparatus. f See Appendix to Aiken's Dictionary of Chemistry, p. 93. X X APPENDIX. 348 Both Houses of Parliament, and several of the streets in their vicinity, are now lighted by gas *. Nearly the entire range of shops, in the line of streets from Shoreditch Chm-ch, by St. Paul’s, to Westminster Abbey, a length of more than three miles, is either provided with pipes, and lighted by gas, or is in course of preparation f. Lord Grey has his house, in Perthshire, lighted in an elegant manner by gas. The street all roimd the Admiralty at Petersburgh, being the finest walk in that beautiful city, was lighted, for the first time, by gas, (produced from wood,) in the win¬ ter of 1812—1813. The use of gas-light there was introduced by Messrs. Sobo- leffsky. I am indebted to Messrs. Hart, of this place, for the following communication, reT ^ Christian Observer, Oct. 1814. f See Monthly Magazine, Nov. 1814. APPENDIX. 349 specting the mode of , lighting their dwell¬ ing-house and bake-house by coal-gas. « SiH, Glasgow, Vlth March, 1815. “ It is rather more than four years since we first attempted to use the gas in lighting our house. Our first plan was a four inch pipe, laid along the back of the common grate, which we charged by the one end, and conveyed off the gas by the other. By taking out a fire tile, we allowed the fire to come upon the pipe, when we wished to make gas. This was a very troublesome method; as our gasometer only contained about one cubic foot, if we applied the fire too soon, we were obliged to light earlier than necessary; if too late, we had to light candles, as the water in the gasometer pit soon got impregnated with tar; when the gasometer was rising, the water evaporating from its sides produced a very disagreeable smell; besides, it was very difficult to keep the luting of the re¬ tort tight, as we then made it pass through about a foot of water, by way of washing it. S50 APPENDIX. “ As we had, however, a spare piece of ground at the back of the house, we re-r solved to try it on a larger scale, and to get rid of the defects we experienced in the other; we, therefore, built a gasometer 3 feet cube, which was as large as the place would contain, otherwise we should have made it much larger. The retort is about 2 feet long, by 1 foot in breadth, and 6 inches in height, rounded off at the corners, nearly in the form of those used on the great scale, and the furnace likewise built in the same manner. The gas, after leaving the retort, is conveyed into a vessel (immersed in the water of tlie gasometer-pit) about 12 inches deep by 10 inches in width, where it deposits its tar. It enters by the top of the vessel, and passes out about half way down, from whence it is conveyed down the side, and along the bottom of the gasometer pit, into a small vessel, about 8 inches deep by 6 inches in width. The end of the pipe is immersed about 1 inch below the surface of the water., in this little box, by way of water^valve, to prevent the return of the gas, when the mouth of the - APPENDIX, 351 retort is taken ofF. A pipe from the bottom of this box is raised to the height at which the water should stand, and tlien carried out level; by this means the water can never rise above its proper height, and any tar that- may condense in the pipes, likewise passes' out this way. A pipe rises from the top of this box, above the surface of the water, in the gasometer-pit, by which the gas passes into the gasometer, without any other obstruction. It is, therefore, very easy to keep the mouth of the retort tight; it needs no other luting than a little clayey sand. Another pipe, likewise, descends at the side of this, from the bottom of which passes a smaller pipe through the top of the box into the water, to carry off the tar or water that might condense in it. It then passes along the bottom, and up the side, of the gasometer-pit, to convey the gas to the house. .After it enters the house, there is a stopcock to shut off the gas, should any of the pipes be injured. The burners are all furnished with flexible joints, so that they can be turned in any direction wanted. The joints are formed, by fitting a conical APPENBIX. 352 pipe into the end of the stopcock, to which is soldered a circular plate, about one inch diameter, through which a hole is drilled, into the pipe; it has two concentric grooves, upon which are placed two rings of leather, rubbed fiiU of bees-wax and lintseed oil of the consistence of honey. The use of the two concentric grooves, is, to keep the rings of leather in their places. Another plate of the same dimensions, with a hole in it, to which a branch is attached, is fitted upon it with a screw in the centre. The rings of leather keep the plate so far asimder, as to admit a firee passage for the gas between them, at the same time, keep¬ ing the joints tight. By means of these two joints, the branch can be moved in any direction. When the branch is very long, it is hung by a small counterpoise, a slight spring presses on a wire, soldered to the end of the conical pipe, to hold it steady when the branch is moved up or down. Some;of these joints we have used for three years, without requiring to be taken asunder or repaired. By means of these circular joints, we have a lustre suspended from APPENDIX. 353 the roof; the upper joint is formed of a piece of leather sewed round a spiral wire, and rubbed full of the wax and oil. We use only one erect flame on each burner, as it seems to give more light when erect, than when inclined, as may be seen by raising or depressing one of the branches, or in what is commonly called the cockspur light. By shutting oflT one of the side flames, and trying whether the vertical or inclined flame gives the deeper shadow, the erect flame will be found to give the deeper shadow, both apertures being equal. The cockspur burner must be well formed, otherwise, the horizontal flame deteriorat¬ ing the air, will cause the under part of the vertical flame to appear of a reddish colour, greatly impairing the intensity of its light. “ Fig. 1. No. L is an oblique view of the retort and gasometer. A, the retort, as built in the furnace; B, the pipe by which the gas is conveyed to the condenser; C, the con¬ denser; E, the water-valve; F, the pipe to convey the waste water into a common- sewer; G G, the pipe by which the gas is 354 APPENDIX. conveyed into the house; H, a small pump to empty the condenser; I, the gasometer. “ Fig. 1. No. 2. is apian of the gasometer, in which the same letters refer to the same parts as Fig. 1. No. 1. . “Fig. 2. Conical and circular joint. G, the circular joint; D, the conical joint; 111, rings of leather; Bj the end of the stop-cock; E, the branch. “ Fig. 3i The manner of suspending a lustre. KKK, circular brass joints; L, joints formed of spiral wire, covered with leather. “ Fig. 4:. The flexible branch. ' “ It takes from twelve to fourteen pounds of coal to charge the retort. This (if the coal be good) wiU produce rather more light than two pounds of candles. The coke we esteem of more value than the coal, before the gas was extracted. The only loss, therefore, is in the fuel used in APPENDIX. 355 the furnace to heat the retort. As our re¬ tort is only heated once a-week, upon an average^ it requires rather more fuel to pro¬ duce the same quantity of gas, than if the furnace was always kept hot. We find, however, from fourteen to twenty pounds of coal always sufficient to extract the gas for that night, and to leave the gasometer full, which is sufficient for the rest of the week—^We remain, « SiK, “ Your most obed*- Serv*"' “J, & R. HART.” 356 ABPENDIX. ON THE FURNACES AND CHIMNEYS u'SED:EOR RAPID DISTnXATION, IN-TBffi p^STILLEREES IN . SCOT¬ LAND. : 329. The rapidity of distillation in the Scotch; distilleries has been so great as to appear incredible to those wlio have not witnessed the process. ^ A still of 80 gah Ions was filled with- cold liquor ; that liquor was heated, arid completely distilled ofij and the still again emptied and ready for a new operation, in. the astonishingly short space of 3 to 3" minutes, and those of 44 gallons in migutes. A change having taken place in the Excise laws, it was suggested to me by some gen¬ tlemen, interested in chemical pursuits upon a very extensive scale, that it might be of great practical utility to collect, ar¬ range, and record the facts relative to the construction and dimensions of the furnaces producing those surprising elFscts, while they could be obtained; otherwise, fi’om the changes in the laws above alluded to, the results of many important experiments might, in a short time, be entirely and APPENDIX. S5% irrecoverably lost to the public. For these reasons, I now offer the following result of my inquiries on that subject, which I be¬ lieve to be accurate, and hope will be ac¬ ceptable to all who are interested in the economy of fuel and the management of heat,. The stills, in their most improved state, were made to hold from 44 to 80 gallons. They were wide and very shallow. Those of 44 gallons were about 44 inches diameter, and only about 5 inches deep. Those of 80 gallons were from 52 to 54 inches diameter, and about 8 inches deep. Those stills, perfectly flat in the bottom, and about three-eighths of an inch thick, were. supported by resting an inch and a half on the, brick-work, all round the bilge. The furnace, which was quite level, was placed at the distance of 15 inches below the bottom.. • The inner end of the grating bars was placed 15 inches within a line, falling vertically from the part of support of the bilge of the still. The bars were in APPENDIX. 358 two lengths; the inner length was 21 inches, the outer, 30 inches, supported by a cross bar between them, 4 inches square. In front of the, bars was a dumb-plate, 10 inches broad. The bottom of the ash-pit was 3 feet below the grating-bars, and on a level with the floor of the distillery. For the larger stiUs,' the grating-bars oc¬ cupied-4 feet in width; for the lesser, 3 feet 6 inchesi The bars were 2 inches thick, 3 inches deep, and three-fourths of an inch apart The brick-work extended 21 inches beyond the dumb-plate, and was 4 feet wide, and 4 inches higher outside than at the bilge of the stiU. The furnace-doors were 30 inches wide. The coal generally used at Glasgow, for the purpose of rapid distillation, is the best large flaming coal, from the Monkland col- The bottom of the furnace, beyond the grating-bars, was lined with fire-brick, 9 inches deep, and passed level backward into the chimney. APPENDIX. 359 The chimney was 60 feet high, 4 feet square within from top to bottom, and con¬ sisted of a double wall. The inner wall, of fire-bricks, was 9 inches thick. The outer wall Was placed at 3 inches distance on all sides: froni the inner wall, and the space is left open at top. The outer wall was 18 inches thick at bottom, battering regularly on the outside, until reduced to 9 inches at top. -The two walls were tied together, at certain distances, by long fire-bricks. The still was placed at 3 feet distance from the outside of the chimney, and a flue 3 feet wide and 2 feet li inches high, where it entered the chimney, formed the con¬ nection with the furnace. The whole was lined with 9 inches of fire-brick. The above dimensions, with the excep¬ tions mentioned, served all sizes of stills used. - Various dimensions of chimneys were tried, but those specified were found to combine most advantages. APirENPIX. When only 36 to , 40 feet high, the draught was not sufficient . When higher than 60 feet, the, flame did not act. properly, and burned the bottom of the stiU. When less, than 4 feet square within, it did not take away the flame sufficiently quick. When 4i feet square, the draught was too great, and the flame burned the bottom of the still. For a long time, the walls of the chim¬ neys were built solid, and much trouble w^ experienced from the chimneys giving way, by the intensity of the heat; but an effectual remedy w^ found by leaving the space of 3 inches, as aL;eady described, between the inner wall of fire-brick and the outer waU, composed of common bricks. The walls being thus, in a great measure, unconnected, not only gave liberty for the un¬ equal expansion of the parts, but also saved heat by lessening their conducting power * lllie fizr^ing relates to distilleries in thdr most improved state, Jo the year 1815. In the “ Report of the Committee of the House of Commons,-on tihe Distilleries of Scotland, for il799,” will be found zmicix CQrioQ5 information on dze subject of distillation. In the same R^ort, xrill be found some infonnation on the use of peat^ as fuel. Dr. Jetfay (Appendis to the Report, p. 436) gives it as his opinion, that a APPENDIX. 361 IMPKOVED BOILERS FOR EVAPORATING LIQUIDS; 330. Ah important improvement lias lately been introduced at some of the alum- works in Yorkshire, in the boilers for e- vapdrating the alum liquor, by means of which, there ai’ises not only a; great saving of fiiel,^ but the process is much facilitated^ and its rapidity greatly increased. The boiler is, as usual, made of leadj but, like those generally used for steam-engines^ is covered with an arch-formed top. For; the purpose of filling and feeding the boiler^; there ik a pipe in the middle of the top distiller may distil as fast with peat as with coal; but experiments seem yet wanting to. ascertain the comparative strengft, as fuel, of peat and coal. (See Art J4.) In some parts of Scotland, where coal is dear, peat is used in the lime-kilns, and- answers very well, provided the lime-stone be broken into very small pieces. The largest lump should not weigh more than S lb. It requires, at least, a bulk of peat equal to the bulk of lime in the kiln; but ranch must depehd-6n tire quality of the peat Peat as fuel for distilleries and other similar furnaces, wants some of the inconveniences of most kinds of coal. In almost all coal there is matter,- which, by strong heat turns into slag or coarse glass, and adheres to the bars of the grate, thereby interrupting the passage of tile air to the fuel. See Report, p. 434. Silversmiths in Scotland smelt silver and gold with peat not because peat raises more heat than coal, but because coal contains gases which injure tliose metals. See Report p. 455. APPENDIX. which reaches nearly to the bottom. The top has some inches of saw-dust over it, to serve in some degree as a non-conductor of heat. The process of evaporation is performed by means of a communication between the surface of the liquor and the chimney, (immediately behind the fire,) which having a strong draught, answers the double pur¬ pose of lessening the pressure of the atmos¬ phere, and carrying off the steam as fast as it rises to the surface, and thereby render¬ ing the process much more rapid and eco¬ nomical than it was in the mode formerly in use. Another advantage of this mode of evap¬ oration, is, that when the fiimes are dis¬ agreeable or unwholesome, they are carried off, without affecting the salubrity of the air *. ♦ See “ Repertory of Arts and Manufactures,'* toL II. p. 37, where a furnace, constructed with a view to the attainment of this object, is de- APPENDIX. 363 This principle is put in practice in the following simple manner. Within the boiler on each side, nearly over the back part of the fire-place, is a pipe of 4 inches bore, having its open mouth a few inches above the surface of the liquid. This pipe descends nearly to the bottoni of the boiler, where it passes out of the side, into a short flue, through which the steam is drawn into the flame of the fire, and thence, of course, into the chimney. Does not this mode of evaporation sug¬ gest an important improvement. on the manufacture of common salt, and, indeed, on almost all manufactoes depending upon evaporation of fluids, by means of culinary fire? ERRATA. Page 63, line far wood, charcoal, read wood-charcoal. . 173, Iast line,/or Bdidores Arch. Hjdraulique, read Architecture Hydraulique, par M,-Belidore, tom. iii. 158,/r Keaumenr, read Keaumur. 174, lines 4, 7, 9, and 11,/ir &cet read faucetT ITS, — S and 16, for facet read faucet . ISl, — 19, for the valve a, read the valve e. 182, — 4, 5, and 14, for guage-coct read gauge-cock. 192, — 15, for new read next 223, — 22, for 112 read 212. 295,_ 8,10, and 20, for Netherly read Netherby House. 544, 15 —19 ,/r “Thedimensions,” &C. read “The dimensions of my kilns are now 9 or 10 feet long at bottom, and 22 inches wide, and about 50 feet high. After spreading gradually fiom the bottom, they arc 4j feet wide, at 18 or 20 feet ftom the bottom, and the remaiiMg 10 or 12 feet is perpendicidar at the same width, and, of course, 4f feet wide at top. A44, — 23, for long read large. JJVB JE X AmucMON, - - 103,107 Aberdeen, "West Church, 297 Accum, Mr. - - • - 72 Adelphi cotton-mill, - 165, 247 Air, - - - - 103 brcatlied by the human species, SO circulation of, - - 217 condensed, - - - 129 pump, - - - 131 rarefaction of, - - 232 rarefied, - - - 129 stratum of, - - - 123 Air chimney, - - - 277 Alcohol, - - - - 133 Anderston tambouring-mill, 247 Annales de Chenue, - - 267 Apparatus, feeding, - - 235 Arrangement, - 187, 190, 192 Arrangement of tlie pipes, - 986 Atmosphere, defended from, 236 external, - - 120 Attrition, - - . - 155 Barometer, - - - 22S standing, - - 9 Bars, - - - - 279 Baths, Mr. Harley’s, - - 302 Black, Dr. 11, 43, 78, 141, 143 Block-printing shops, 208,218 Blow-pipe, ... 154 Bodies, - . - - 55 coloured, - 56 lieated, - . .102 soUd ice, - . 53 their condensation, - S3 tlieir specific heats, . S3 Boerhaavc, Dr. - - - 11 Boiler, .... 241 descriptfon of, - .179 surface exposed to fire, 81 for generadng steam, 179 proportionate size of, 160 Boilers, ... 280 Boiling, ... 1,31, 137 during the day, . 216 point, . 8, 9, 10, 134 Branning, dyeing, &c. - . 218 Brass, expansion of, . 168 Breweries, ... 68 Brick flues, ... 244 conductors, , . .88 work, . . 196, 238 Bro^^Mr.^’ - - - 232 Brook Taylor, Dr. . . 12 Building, .... 245 nature of, - . 163 Bush Farm, ... 295 Butterly Iron-Works, . 177 Calomclcr, - Caloric, - of die term, . Candle, wax, cylindiic.al, internal, - p.ainted, tinned iron, - Carbonic acid gas. Cast-iron, Catrine, Centigrade, - Chaptal’s Chemistry, - 208 - 91 98 279, 285 77, 80 INDEX- SUk-conductor, - « - Silver, quick, boils, - - 1 Sliding spy-glass, - - 2 Solid, . _ - - Solii, their expansion, to measure tlieir expan- Specifically lighter, - - 1 Spigot and faucet join^ 1V4,214,2 pipes, - . 1 Steam, 78, 135, 136, 137, 241, 243 black-bull inn heated by, 197 conductor,^ SlTBUck, drying and heating by, 203 drjing dyed and bleached dwclUnghousesheatedby, effect of, engine^ - ■ - general abstract of build¬ ings warmed by, - its combination, substance and su face of, - arrangement of, 168,171 - 95, 240, 242 i comparative of fuels, of liquid?, their expan¬ sion in bulks, , its explanation. 21 of boiling points, > 132 of conductors, - - 89 of expansion of air, .148 liquids, 149 for 180 degrees of Fahrenheit, , 149 of thermometers, - 25 relative to BIr. Dalton’s, 20 Tar, oily, - - - - 77 Toniporntiiro 18,57,102,194,140,151 Centigrade, - 9 differential, - 99 Fahrenheiti?, 9,13,225 mercurial, 14,19,97 Murray’s, - 10 Reaumur’s, - lo ’ IVedgewood’s, 152 Tbimble joint, . 174,214 Thin copper drums, - - 169 Thin musli,us dried, - 211 Tliomson’s Annals of Philoso¬ phy, - - - 272,275 Tin, expansion of, . - 169 Tin-plate, - - . 154 INDEX. V^KJur, elastic^ ; - iSS.j Chimneys Belfast, Vdod^,'^ " . “ " ■ 102 Chinmey-sw^ers, -of radiant heat, - 94 Church, Christy -