EASY EXPERIMENTS IN PHYSICAL SCIENCE, FOR ORAL INSTRUCTION IN COMMON SCHOOLS, LE ROY C. COOLEY, PH. D, PROFESSOR OF NATURAL SCIENCE IN THE NEW YORK STATE NORMAL SCHOOL. NEW YORK: SCRIBNER, ARMSTRONG & CO., 1876. Entered according to Act of Congress, in the year 1870, BY LE ROY S. COOLEY. In the Office of the Librarian of Congress at Washington. JOHN F. TROW & SON, PRIMNTRS a05-2I3 EAST IXTH ST., Naw YORni PREFACE. IT is coming to be very generally believed by educators that one of the most important aims of primary instruction should be to discipline the child to habits of quick and accurate observation, and to the power of making simple but correct inferences from the facts which his senses reveal. Surely this result can be reached more easily by means of those facts which nature communicates through the senses than by subjects which have no natural dependence upon material forms; and hence the superior adaptation of the simple facts of physical science to the wants of common-school instruction. But the only way to strengthen mind is to make it work. If the senses are to be developed and disciplined, the child must be allowed, and, if need be, compelled, to use his senses for himself. The teacher is to guide him, but not to carry him. His mind is to be directed toward material things, and taught to see their forms and characters as they themselves present them. The instructor is to be his guide, but Nature is herself to be his teacher. The intelligent teachers of common-schools are eagerly asking how can this theory be wrought into practice. Lack of time and lack of material seem to almost forbid Iy PREFACE. the attempt: lack of time, because custom and public opinion demand so much knowledge of books in all the branches which overcrowd the primary course; and lack of material, because apparatus other than a blackboard and a few maps is, in most common-schools, a thing unheard of. It is pleasant to anticipate a time when the higher and theoretical parts of arithmetic and grammar shall be reserved for the high-school course of study, and their places in the common-school left to the more appropriate study of nature. It is pleasant to anticipate the time when every common-school shall be provided with an appropriate set of apparatus, through which Nature may teach her simple truths to children in her own playful and childlike manner. The time is doubtless coming when both these anticipations will be realized, and all the quicker will it come if teachers will only beyiln the work by using the very little time and means already at their disposal. Some have already begun: they find it possible to secure time for a short exercise each day, or at least two or three times a-week, in which they perform simple experiments with such objects and utensils as they find at hand, much to the delight and profit of their schools. Letters from several of these announce their surprise at the interest thus aroused, not only among pupils, but among parents also. Whole neighborhoods are in some instances awakened, and it will not be difficult in such cases to obtain money for the purchase of better means of illustration! Now this little book is offered as an aid to the teachers PREFACE. v who are, or who desire to be, engaged in this work. It is made up of experiments of the simplest kind, which, with few exceptions, can be performed with such apparatus as can be collected anywhere almost without expense. These experiments are arranged in groups, each group teaching some elementary fact or principle of science. They are selected from among those which the writer has long been using in the earliest stages of his instructions to his classes, and which are now being reproduced by young teachers who have gone out into the public-schools of the State, and from whom reports of abundant success are received. There is, therefore, good reason to believe that they are practical and instructive. But there is another purpose which this little book is designed to serve. The best teachers of natural science are unanimously of the opinion that the very best results can be secured only by allowing the student to make experiments for himself. In the study of science in highschools and academies, good text-books are very desirable; a full course of illustrative experiments by the teacher is indispensable; but if, added to these, there can be a course of simple experiments by the pupils themselves, the value of both will be enhanced. Now the experiments described in the following pages are such as intelligent boys and girls can make with little or no assistance. All that the teacher need to give them is encouragement, and it is believed that he would find Vi PREFACE. his own work more productive if, in addition to the textbook and his lectures, this course of simple experiments could be put into the hands of every pupil in his class. Students can not too early begin to acquire the habit and the power of verifying the statements in the science which they study. This they can do in an elementary course of study by experiments of the simplest character made with apparatus the most inexpensive. APPARATUS. THE following list comprises the most important pieces of apparatus needed for the performance of the experiments described in this book. The articles named in the second column may be obtained very cheaply of apparatus dealers: those in the first can be found at home in any district. A great many other things will be used, but they are too common to need even to be na:tled here. Fruit-cans. Glass tubing — lb. ass'd sizes. Ale-glasses. Rubber tubing-2 ft. Bottles. Alcohol lamp. Corks. Flask-glass, 1 pt. Plates. Test tubes- - doz. 6 inch. File. Convex lens. Funnel. Violin string. Tuning-fork. Glass tube-for frictional elec. Shot. Sealing-wax. Besides this apparatus some chemicals are -necessary. All these, except some which are too common to need mentioning, are comprised in the following list. They may also be obtained of the apparatus dealers at very trifling expense. Alcohol. Sulphuric acid. Cochineal. Hydrochloric acid. Litmus. Nitric acid. Sulphur. Ammonia. Copper clippings. EiASY EXPERIMENTS IN NATURAL PHILOSOPHY. "Always bear in mind that the simplest experiments, or those most easily imitated by the pupils, are the best."-Nature. INTRODUCTION. Divisibility. Ex. i.-Take a glass jar, holding half a gallon,-a fruit-can answers the purpose well,-and fill it with water. Next take a little powdered cochineal, as much as will lie upon the end of a penknife-blade, which will not be more than half a grain by weight, and dissolve it in a thimbleful of water. Finally pour the coclineal into the clear water in the jar. Notice the cloud-like masses of colored water slowly making their way downward. After a little time stir the water briskly, and then see that every part of it is distinctly colored. Now it is said that there are as many as 30,000 drops of water in a half-gallon, and that it must take as many as 100 little particles of the cochineal to color a single drop distinctly. In this experiment, then, a single half-grain weight of cochineal has been divided into not less than 3,000,000 pieces. Ex. 2.-Place a goblet on the table and fill it about one half full of water. Take a piece of loaf-sugar as large as a walnut, and by blows break it into small pieces. Put these pieces into tile water and stir them about vigorously. After a little time notice that the sugar has entirely disappeared. In this case the body has been divided into pieces so small that, being colorless, they can not be seen at all. 12 INTRODUCTION. Ex. 3.-Take a small piece of marble, and by pounding it reduce it to the finest powder: the separate grains are almost invisible, and yet each one of them is a piece of the original block. We learn from these experiments that some bodies can be separated into many parts. And when we think of others which we have not just now tried, we remember that they too can be broken or cut into pieces. Now this quality of matter, by virtue of which bodies may be separated into pieces, is called divisibility. REMARKS.-Teachers will notice that the descriptions of the foregoing experiments are minute and clear enough to forbid any failure in the performance of them. But these descriptions only show the work which teachers must do: they do not give the language which they must use. While making an experiment the teacher ought, by skillful questions and appropriate remarks, to keep the attention of the children upon it, so that every part of the apparatus shall be observed and every action definitely seen. Above all tilings ought care to be taken that the final inference is seen to be the natural consequence of the facts observed in the experiments. The tendency will doubtless be for the teacher to do all the talking, while the pupils rest contented with simply repeating what they hear. This should be avoided. The pupils should themselves be made to describe the apparatus while they look at it; to announce the results as they occur; and to interpret them as fully as possible and with as little assistance as may be practicable. No two intelligent teachers will ever work by exactly the same method, but yet the principle just stated ought to be the foundation of every plan and determine the INTRODUCTION. 1 3 detail of every attempt to teach science, in its most elementary form, for which these experiments are designed. The following conversation occurred between a teacler and his class in regard to the experiments just described. It will serve to illustrate the method of making the pupil use his senses to acquire knowledge. TEACHER.-I hlave here three substances about which we want to learn something to-day. One of them-this which you see (holding it up ill view of the class)-is cochineal; another (showing it) is a lump of loaf-sugar; and the third (showing it also) is a piece of marble. I want to show you some things that can be done with these, and I would like to have you to tell me exactly what you see and learn. 1st Experiment.-Now notice (teacher takes a halfgallon jar and fills it with water): what have we here? PUPILS. —-A jar of water. TEACrHER.-I must tell you now that the jar holds one half a gallon; and now think a moment, whether you have not often seen water that looked very unlike this. Tell me, then, what you see before you. A FEW PUPILs.-A half-gallon of clear water in a jar. TEACHER.-Yes; you all can see that the water is not muddy nor colored; it is clear, and you know I told you that the jar holds half a gallon. Now here (dipping up a little cochineal upon his knifeblade) is the cochineal. It was not always as you see it now. It was found in the shape of little balls about as large as large shot, each covered with a grayish coating; but now what do vou say of it? PUPILs.-A reddish powder. TEACHER.-The little balls have been broken into pieces 14 INTRODUCTION. -indeed, crushed into this fine powder. But see what I will do with it. Just the little on my knife-there is not more than the weight of half a grain-remember this, I will use in this way (putting a little water into a goblet and the powder into it, and thoroughly stirring them together). Now, John, come and look at this, and tell your mates whether you can see the powder JOHN.-There is a little at the bottom. TEACHER.-Just a little; but where is all the rest? JOHN.-It looks like red water. TEACHER.-Yes; you do not see the powder in the water, but the water looks red because the little particles of powder are broken up into such very little pieces that John could not see them, and these little pieces are scattered throughout every part of the water. But now look again (pouring the "red water" into the jar): who will tell me what is going on now? SEVERAL PUPILS.-The coclineal is going to the bottom! OTHERS.-It is mixing with the water! TEACHER.-When we have watched these very pretty cloud-like streams of colored water long enough, I will stir the water thoroughly in the jar (doing so after a pause). Now tell me if you see any change made in the water. PUPILS.-It is red now, all through! TEACHER. —But you know there was a whole halgallon of water and only half a grain of cochineal! Now let us see,-how many drops of water do you suppose there are in the jar? Of course you do not know, and I will tell you that it is said that there are not less than 30,000. It is thought, too, that it would need as many, at least, as 100 little pieces of cochineal to color a INTRODUCTION. 15 single drop, perfectly in every part of it. And yet the half-grain has colored the half-gallon! Now who will answer quickly,-If it take 100 pieces of cochineal to color one drop of water, how many pieces will it take to color 30,000 drops? PUPILs. —One hundred times 30,000 are —(after hesitation a few answer correctly) 3,000,000. TEACHER.-That is right. Now look again at this water: it is crimson-colored,-every drop of it. Into how many pieces does this experiment show the halfgrain of cochineal to be divided? MANY PUPILS.-Into 3,000,000 pieces! TEACHER.-Surely it was a very little thing to be broken up into such a multitude of pieces! But now for the 2d Experimenit.-Let us use this little lump of sugar. What have we here? (Placing a goblet on the table and half filling it with water). PUPILS.-A goblet of water. TEACHER.-Now watch the sugar (dropping it into the water and stirring it about a little time). Well, what has happened? PUPILS.-It has fallen to pieces. TEACHER.-I will continue stirring these pieces about in the water (doing so until the sugar is dissolved); and now can you see them? Come and look. (To those who came) Well, where is the sugar? PUPILS.-It is in the water. TEACHER.-But can you see it? PUPILS.-No. TEACHER.-How then do you know that it is in the water? PUPILS.-We saw you put it in there. TEACHER.-Very good: you saw it put there, and it has 16 INTRODUCTION. not been taken out again. But you did see it in the water at first: why can you not see it now? PUPILS.-Because it is broken up and all scattered through the water. TEACHER.-That is it exactly! And now you can tell me what this experiment shows us about sugar, can you not? PUPILS.-That sugar can be broken up into very little pieces. TEACHER.-Yes; or you might say,-it shows us that sugar can be divided into pieces which are so small that they can not be seen. Now let us see about the marble. 3d Experiment. -George, now I place the marble upon this brick which I have brought here oh purpose; won't you come and strike it with this hammer? (He does so.) There, what have you done to the marble? GEORGE.-I have broken it. TEACE1R.- - NOW take one of the pieces and strike it. (He does so.) There, what have you done to the piece? GEORGE.-Crumbled it all to powder. TEACHER.-But not to very fine powder; but now suppose you strike these little pieces, will they be broken again? Try it, George. (He does so.) Well? GEORGE.-The powder is fine now. TEACHER.-Then you must have broken the little pieces up into still smaller ones. We can hardly see them separately. And now, scholars, tell me: what all this shows about marble. PUPILS.-That marble may be divided into little pieces. TEACHER.-Very good. We have now tried three things,-coclineal, sugar, and marble. We have found that each may be divided into very little parts. They INTRODUCTION. 17 are alike in this respect, even though so very different in most others. This quality of these bodies, which allows them to be broken or separated into parts, is called divisibility. Can you think of other substances which can be divided? (Several things are quickly mentioned ) All these things have the same quality as you lhave seen the cochineal, the sutar, and the marble, to possess. What is that quality called? PUPILS.-Divisibility. TEACHKR. -What, then, does this word,-divisibility,mean? I will write its meaning on the blackboard for you. Divisibility is that quality of bodies which allows them to be cut or broken into parts." Perhaps no other teacher would do just exactly as this one did, in conducting this exercise, but in some respects his example is worthy of careful imitation. 1st. He evidently had a definite plan marked out beforehand. No teacher should attempt a single experiment until he has tried it, studied it, and formed his plan for using it. 2d. His object seemed to be to make tile pupils see clearly what occurred, and to infer correctly from what they saw. Let every teacher lay every plan and work out every detail with direct reference to these two results. 3d. Hence he called upon /,is p''pils to tell him what things were being used and what effects produced, instead of describing them himself. So should every teacher do, telling the pupils only those things which the apparatus does not clearly show. It will be found to be an excellent plan, especially after 18 INTRODUCTION. pupils have had some experience in these exercises, to first, put before them all the apparatus for an experiment ready for use and ask some one pupil to describe it fully, then to make the experiment deliberately and silently, (f'terward calling upon a second pupil to tell you what you did, and upon a third to tell you what changes or effects he saw produced, and upon a fourth to tell you what he thinks the experiment teaches. Repeat the experiment, if need be, to bring out any essential point which the pupils did not at first discover. It will also be well to encourage the pupils to make experiments for themselves. Call upon individuals to help you at times. Especially if; during an exercise, one is seen to be inattentive, nothing can be better than to ask him to help you in the experiment being made. Let him do some part of it which you know he can do well, and take care that he do not fail. His success will do more than any thing else can to secure his attention in the future. The following experiments furnish abundant material for such exercises as have just been indicated. If used at all in common-schools, they can not fail to awaken lively interest among the scholars, and will always leave their minds in better condition to pursue their regular studies to better advantage. If used skillfully by the methods just pointed out, their own educational value will not be surpassed by that of any other branch of study. THE PROPERTIES OF MATTER. Impenetrability. Experiment 4.-A glass jar may be partly filled with water (Fig. 1). Let a block of wood _-~ of convenient size and shape be then pushed down into the water. Nlotice that as the wood enters, the liquid rises in the jar, and that it falls again when the wood is taken out. We see that these two bodies, wood and water, can not be put into the same place at the same time. Ex. 5.-Let an inverted goblet be held Fig. 1. with its mouth on the surface of the water in the jar. Notice that the goblet is full of air. Next, push the goblet down into the water. Notice, that the goblet is still full of air, the water not rising into it. We see, here, that water and air can not be put into the same place at the same time. Ex. 6.-Hold the inverted goblet in the water as before, its mouth being an inch or more under the surface. Having a large cork, fixed upon the end of a bent wire (Fig. 2) for a handle, push it down under the edge of the goblet and then up into the air within. Notice that as the cork Fig.2. goes up into the air some air-bubbles escape through the water. We seo that air and cork can not be put into the same place at the same time. 20 PHYSICAL SCIENCE. What is seen in these experiments is true of all bodies; no two can be put into the same place at the same time. This property of matter, by which no two bodies can occupy the same space at once, is called impenetrability. Indestructibility. Ex.'.-into a small tin cup put a little fine sugar and carefully weigh them. (See Ex. 32, Fig. 7.) Add water enough, afterward, to dissolve the sugar. Notice that the sugar has all disappeared. Next place the cup over a stove or a lamp-flame, and continue the heat until the water is driven away and the cup and its contents are thoroughly dry, taking care that nothing is lost by boiling or flying over. Notice that the sugar is to be seen in the cup again. Finally weigh the cup and its sugar; the weight should be the same as before the sugar was dissolved. We see that sugar may disappear without being destroyed. Whenever any substance disappears from any cause, its form is changed, but the substance is never destroyed. This property of matter, by virtue of which it can not be destroyed, is called indestructibility. Elasticity. Ex. 8.-Take a piece of steel wire and hold one end firmly in one hand. With the other hand take hold of the other end and pull it over to one side. Notice that the wire yields to the force of the hand. Next, let go the end which has been pulled away, and notice that it springs back to its former place. We see that this wire will yield to a force and spring back again when the force is taken away. Ex. 9. —Having a glass hall-an " agate" used by boys in playing "marbles "-drop it upon a stone or other hard surface. Notice that it bounds upward to consider PROPERTIES OF MATTER. 21 able height. Now the ball bounds because it is, for the moment, flattened a little just where it strikes the stone, but at the next instant it springs back to its former shape, and this,sprliningg back throws the ball upward. This being so, we see that even glass will yield to a force and afterward spring back. This property of bodies, shown bv the wire and the glass, by wlich tley spring back to their former position or shape after having yielded to some force, is called elasticity. All bodies are more or less elastic. Ductility. Ex. 10.-Hold the middle of a small glass tube in the flame of an alcohol lamp until about an inch of its length is made red-hot. It will be necessary to roll the tube over in the flame constantly to heat it on all sides alike. When heated to redness, take it from the flame, and at tue same time pull with both hands lengthwise of the tube. Notice that the glass is drawn out into a long and thread-like wire. Many substances, like glass, may be drawn out into wire. Metallic wires are very common. The property of matter by which a body can be drawn into wire is called ductility. Ex. 11.-Taking hold of. the ends of the glass still attached to the wire, use them as handles, and on moving them about, notice how flexible fine threads of glass are. Ex. 12.-Break one handle off, leaving tile fine wire still attached to the other. Put the fine end down deep into a vessel of water and the other end in the mouth. Blow strongly, and notice the bubbles of air coming in a steady stream up through the water, showing that the fine thread is still a glass tube. It can not be drawn so fine as not to be a tube. 22 PHYSICAL SCIENCE. Combustibility. Ex. 13.-Take as much potassic chlorate as may lie upon a penny and mix it with an equal quantity of sugar. Put this mixture upon a piece of card-board resting on the top of a goblet. Add next two or three drops of strong sulphuric acid, and quickly take the hand away from over the mixture. Notice that a violent and surprising combustion immediately follows. Wood, coal, oil, and many other bodies burn freely. This property of matter, by which it is able to burn, is called comnbustibility. Explosibility. Ex. 14.-Let as much potassic chlorate as may lie on the point of a penknife-blade be put into a mortar with the same quantity of sulphur. Larger quantities can not be safely handled. Next rub the mixture with the pestle. Notice a sharp report or perhaps several reports in succession if the rubbing be continued. Gunpowder will explode when touched with a burning match, and some other substances have the same property. This property of substances, by which they may be made to explode, is called explosibility. ATTRACTION. Gravitation. Ex. 15. —Let a ball be dropped from the hand. Its falling toward the earth is an example of what is seen perhaps every day of our lives. All bodies fall toward the earth. But not only is this true; the astronomer finds also that all the heavenly bodies are pulling each other toward themselves. Indeed, all bodies tend to approach each other. The attraction which pulls them toward each other is called gravitation. Cohesion. Ex. 16.-Take a half-sheet of letter-paper and gum each end to a smooth bar of wood longer than the width of the paper, so that each end will project beyond the edge. (Fig. 3.) Let the bars be exactly parallel. Now with the pro-' jecting bars as handles, two persons may try to pull the paper apart. An astonishingy force will be needed to do it when the pull is steady and square. Notice that the parts of the paper are held together very firmly. We see that pig. 3. there is an attraction among its parts. Ex. 17.-An apple being cut into two halves, let their fresh surfaces be pressed together again, and notice how hard it is to pull them apart again afterward. We see that there is attraction between them. 24 PHYSICAL SCIENCE. Ex. 18.-Let two oullets be flattened and then smoothed on one side of each with a knife until they will fit each other closely. Next press the two freshly-cut surfaces firmly together, and afterward let them be pulled apart again. Notice that it needs considerable force to pull them apart. In all these experiments we notice an attraction between parts of one body or of two bodies of the same kind of matter. Now the attraction which holds the parts of a body or of different bodies of the same kind together is called cohesion. Adhesion. Ex. 19.-Having two test-tubes, or even two small cups, put some oil into one and some mercury into the other. Into the oil plunge a rod of wood and into the mercury another. Now taking the wood from the oil, we notice it covered with a film of that substance. Next take the wood from the mercury, and notice not a drop of the liquid upon it. We learn that there is an attraction between wood and oil, while none is shown between wood and mercury. Ex. 20.-Have two cups of water: into one of them plunge a rod of wood, into the other a piece of wax, or even a candle. On taking them out, notice that water clings to the wood, and wets it, but not to the wax or candle. We learn that there is an attraction between wood and water, but apparently none or very little between wax and water. Ex. 21.-Draw a crayon along the surface of the blackboard, and notice its particles clinging thereto. We learn from these experiments that there is, in some cases, an attraction between different kinds of matter which holds their particles together. This attraction, ATTRACTION. 25 which holds particles of different kinds together, is called adhesion. In some cases it is called capillary force. Capillary Force. Ex. 22.-Let some water be colored with ink, or, far better, with cochineal. Take a small glass tube-its diameter not more than 0- of al inch-and put one end of it into the colored liquid. Notice the liquid springing up into the tube quickly and remaining there much higher than it is outside. Ex. 23.-Stand a piece of flat glass in the water, and notice the liquid rising a little way up along its sides. Now the attraction, shown in these experiments, by which a liquid is lifted in small tubes or along the sides of solid bodies, is called capillaryforce. Ex. 24.-Wrap a common bottle in a strip of blottingpaper which is as wide as the bottle is high, and fasten its edges with wax. Next fill the bottle with water made black by ink. Finally, stand the bottle, thus prepared, on a common dinler-plate, and pour water upon the plate to come in contact with the lower edge of the paper on the bottle. Notice that the water will be soon seen slowly rising up the paper, and in a little time it will have climbed to the top of the bottle. Remember, also, that oil rises in a lamp-wick in the same way; that water will wet a piece of cloth throughout in a little time, if only one corner touches the liquid; that ink spreads on blotting-paper, and other similar and familiar facts. In all these cases, as in the experiment, capillary force is causing a liquid to penetrate porous solids. Ex. 25.-Having two strips of glass-three inches long by an inch in width is a convenient size-put a narrow piece of card-board between their ends, and then 2 26 PHYSICAL SCIENCE. cement them together with a little sealing-wax. The two plates are then parallel and very near togetller-separated only by the thickness of the card-board. Take the sealed end in the hand and bring the other end of the plates down into some colored water. Notice the fluid instantly leaping up to some height, where it remains between the plates. Ex. 26.-Cement two other similar plates of glass so that they shall not be parallel-one edge of the pair being in contact, the other edges being separated perhaps an eighth of an inch. Put the lower end of this pair of plates into the colored water; it will spring up quickly as before. But notice that its surface is in the form of a beautiful curve (Fig. 4), and farther, that the liquid is lifted'highest where the plates are nearest together. Ex. 27.-Select two small glass tubes, one of which shall have a diameter twice as great as the other. Put one end of each into the colored water and it will rise in both. Notice that the fluid rises highest in the smallest tube-just twice as high if one tube is exactly one-half diameter Fig. 4. of the other. (See Cooley'8 Philosophy.) WATER. Mobility. Ex. 28.-Fill three goblets, one with small marbles or large peas, another with fine shot, and a third with water. Invert a dinner-plate as a cover over each. By holding the plate tightly pressed upon the mouth of the goblet with one hand, while the goblet itself is grasped by the other, both may be turned over together without spilling the contents of the glass. Do this with each in turn, and the three goblets will be left standing, full, but bottom upward, on the plates. Next carefully lift the goblet containing the marbles, and notice how they spread out upon the plate, and see that they do so because they are such smooth balls, without force to hold them together. Then lift the goblet containing shot, and notice that they roll out upon the plate in the same way and for the same reason. Finally lift the goblet containing water, and notice it, also, spread itself out upon the plate just as the others did. We may give the same reason: water consists of little, VERY little smooth balls, without force enough among them to hold them together. Because water consists of such very small and smooth bodies, it is able to move about so freely as it does. They roll over and around each other with the greatest ease. This freedom of motion among its molecules is called mobility. (See Cooley's Phil., p. 38.) Pressure. Ex. 29.-Having a lamp-chimney, whose lower end is smooth and even, cut a circle of tin large 28 PHYSICAL SCIENCE. enough to cover it. Make a small hole in the center of the disk and pass a string through it, letting a knot in the lower end prevent the string from coming out. Now run the string through the lamp-chimney, and by means of it hold the tin up tightly against the end of the glass until it is pushed down to the middle of a jar of water. Then let go the string (Fig. 5), and notice that the tin-a heavy metal-does not sink. Notice also that there is nothing but water to hold it up. The experiment teaches that water exerts an upward pressure. Ex. 30.-Take a glass tube, bent in two places at right-angles,* and hold the finger tightly over one end, or close it with a cork. Let some water, colored with ink or cochineal, be poured into the other end; it will fill that arm of the tube and a part of the horizontal portion. (Fig. 6.) Now let the air slowly pass from under the finger or the cork at the closed end, and notice the water moving downward in one arm, sideways through the horizontal part, and upward in the other arm of the tube. By this motion of the water we learn that it is exerting pressure downward, sidewise, and upward, at the same time. Ex. 31.-Place a small block of wood upon the surface * A glass tube held in the flame of an alcohol lamp until it begins to soften may be easily bent into any required shape. Roll it in the flame to heat all sides alike, and when it begins to yield, press it gently into the desired shape. WATER. 29 of water in a jar, and by means of a rod of wood or iron try to push it down to the bottom. Notice its struggles to stay at the top, and also that there is nothing but water to push it up. Ex. 32,-To the middle point of a bar of wood let a cord be tied so that the bar will balance when the string is held in the hand. This bar is a very good scale-beam. From one end hang a stone I about the size of a hen's egg, and from the other end hang a small cup, into which put just sand enough to make it balance the stone. (Fig. 7.) Now let the stone be made Fig. 7. to hang down into a vessel of water. Notice that it is no longer balanced by the cup of sand: it is lighter in the water than out of it. See that it must be the water that helps to hold it up. From these two experiments we learn that water presses upward against bodies immersed in it. Ex. 33. —Fill a pitcher brimful of water. Place a dish under the lip to catch the water soon to run over, and smear the under side of the edge of the lip with tallow to prevent water from running down the side of the pitcher. Lay the block of wood (Ex. 31) carefully upon the surface, and notice that water runs over the lip. Afterward notice that the upward pressure of water just sustains the wood, and hence must just equal the weight of the block. Hang a cup from each end of the scale-beam; make them just balance. Now dry the wood and put it into one cup; take the water that was pushed over the 30 PHYSICAL SCIENCE. lip of the pitcher by it and put it into the other cup. Let all, this work be very carefully done. Then notice that the wood and water just balance. We thus learn that the water displaced by a body which floats, weighs just as lmuch as the body itself. Ex. 34.-Empty the water from the cnp and make the two cups balance each other again. Then tie the stone (Ex. 32) to one end of the'"scale-beam" by a string long enough to let it hang down below the cup, and put sand into the other cup to balance it. Next let the stone hang into the pitcherfiZll of water and catch the liquid displaced. Notice that the stone is lighter now than before. How much lighlter? Another experiment will tell. Ex. 35.-Put the water that was displaced by the stone into the cup above it, and not'ice that the balance is restored, and learn that the weight which this heavy body loses in water is just equal to the weight of water it displaces. AIR. Compressibility. Ex. 36.-Take a glass tube several inches long and pass one end of it tightly through a cork which has been selected to fit the neck of a vial. Push the cork end of this tube into some colored water and close the other end with the finger. Keeping the end closed, lift the cork from the water, and press it tightly into the neck of the vial, at the same time taking the finger from the end of the tube. Notice now that the colored water stands some distance up the tube -the space below being filled with air. (Fig. 8.) Next slip the end of a piece of rubber tubing over the end of the glass tube. Apply the lips to the end of this and gently press the breath into it. Notice that the water in the tube moves toward the vial. But there is no escape for the air, and hence it must be crowded into smaller space than it occupied before. We thus learn that air is compressible. Fig. 8. Expansibility. Ex. 37.-Now apply the lips to the rubber tube again and draw the air out of it. Notice the colored water moving away from the vial, and see that the air now fills more space than before. We thus learn that air is expansible. 32 PHYSICAL SCIENCE. Elasticity. Ex. 38. —Using the same apparatus, let the breath be alternately pressed gently into the tube and then withdrawn, and notice the water alternately moving back and forth in the tube. The air first yields to the foree of the breath; it then springs back when the force is withdrawn. We see tllat it eis te'.ic. Pressure. Ex. 39.-Place one end of a straigllt glass tube in colored water, and with the lips at the other end withdraw the air. The colored water is seen rising in the tube. It is pushed up, but znotiee that there is nothing to push it up but the air that rests upon the surface of the water in the vessel. Ex. 40.-Push a glass jar (a fruit-can) down into a pail of water until it is filled. Take hold of the bottom of the jar and lift it until only thle edge of the mouth of it is under the water in the pail. Notice that the jar is still full of water. Sometlling holds the water up; there is nothing to do it but air outside If a shelf is fastened in one side of the pail just under the surface of the water, as may be very' easily done, the full jar may be left mouth ij downward on the shelf; the water will not run out. Ex. 41.-Fit a long-necked bottle with. a cork through which two tubes pass. Both tubes should reach some distance into the bottle. One should reach some inches outside, the other must be shorter. To the shorter one the end of a rubber tube must be attached. Fig. 9 slows the full arrangement. Now let the lower end Fig. 9. of the longer tube be put into colored AIR. 33 water, the end of the rubber tube in the lips, and let the air be drawn out of the bottle. Then notice a pretty little fountain springing up instantly into the bottle. There is nothing but air to push the water up. These experiments teach us that air resting upon the surface of water, or, indeed, of any body, exerts a downward pressure. Ex. 42.-Take the straight glass tube used in Ex. 39 and push it nearly its whole length under water, and then place the finger over one end to close it. Lift the tube out of the water, open end downward, and notice that the water does not run out of it. There is nothing but air to keep it up in the tube. Ex. 43.-Take a ncarrow-necked bottle, and ihaving immersed it in a vessel of water until it is filled, almost cover it with the finger, turn it mouth downward, and lift it out of the water entirely. Yotice the water refusing to run out, and that there is nothing but air to keep it in. Ex. 44.-Take a wide(-mouthed bottle, or an ale-glass, and proceed as follows: having filled it with water, slip a piece of paper under its mouth and hold it against the glass until the bottle is lifted out of the water. The hand may then be taken away from the paper, when the water will be seen remaining up in the bottle. (Fig. 10.) In these experiments we see that the air is exert- I ing upward pressure. r Ex. 45.-Let the wide-mouthed bottle used in Fig. 10. the last experiment be filled with water and covered with the small piece of paper as before. Hold it in a horizontal position, see that the water does not run out. Turn it around to point in various directions horizon 34 PHYSICAL SCIENCE. tally; the water is still kept in by the air. Hold it obliquely in various directions, and witness the same result. We thus see that air exerts pressure in all these directions. By considering all these experiments on pressure together, we are taught that airi exerts pressure in all directions. The Pump. Ex. 46.-Let a glass tube have one open end in colored water. With the lips applied to the other end, take the air out of the tube above the water, and notice that the pressure of air pushes the water up. Ex. 47.-Next take a wire longer than the tube and wind cotton upon one end until it is so large that it can with some difficulty be drawn into the tube. Pass the wire up throough the tube, and, taking hold of the upper end, pull the cotton into the other end, and then insert it in the colored water. Next pull the cotton upward in the tube, and see the water following it. (Fig. 11.) Notice that the air is here taken out of the tube above the water by lifting the cotton. We thus learn that water will be pushed up in a pipe or tube whenever the air within is by any means lifted out. Tilis is the principle of Fig. 11. the common pump. (Cooley's Philosopihy, p. 31.) The Siphon. Ex. 48.-Repeat Ex. 42, and notice again that the pressure of air sustains the column of water in the tube. (Fig. 12.) Study it further. See that the weight of the water is pressing downwarld that the AIR. 35 air is pressing upward, and that the upward pressure is strongest. Ex. 49.-Take next a glass tube, bent in the form of the letter U, its arms being of exactly equal length, and immerse it in water. When it is completely filled, close one end with the finger and lift the tube from the liquid. Hold it with open end downward; the water does not run out. Close the other end and open the first; the water still remains. Now put the forefinger of one hand exactly Fig. 12 under the middle of the bend so that the tube will balance, and then very carefully take the finger away from the end of the tube. Both ends are now open downward (Fig. 13), but still the water does not run out. Notice that the water in both arms is pressing downward —that the air at both ends is pressing upward. Again, see that the downward pressures, being equal, overcome equal portions of the air pressFig. 18. ures, and thus leave equal upward ress- I ures to keep the water from running out. Ex. 50.-Take next a bent tube, one arm being longer than the other. Use it exactly as the tube was used in the last experiment. The water will not remain in the tube balanced upon the finger; notice it running out of the longer arm only! (Fig. 14.) In this case there is greater pressure of water downward in the long arm than in the other; it overcomes more of the air-pressure. This leaves more of the air-pressure upward against Fig. 14. the water in the short arm. This stronger pressure of 36 PHYSICAL SCIENCE. the air upward against the water in the short arm pushes the water up through it, over the bend and out of the longer arm. Such a bent tube, one arm longer than the other, is called a siphon. It is used to transfer liquids from one vessel into another; let \ another experiment show how it is used, thus: Ex. 51.-Place an empty jar (fruitcan) or other vessel, beside another Fig. 15. containing water. Fill the siphon with water by immersing it, and close the longer arm by holding the finger over its end, while the end of the shorter arm is being put into the vessel of water. Let the longer arm hang over into the empty vessel, and open its end. (Fig. 15.) The water will continue to run until it stands at the same height in both vessels. (See PAilosophy, p. 73.) The Effect of Heat. Ex. 52.-Take a bottle containing some colored water, and fit to it a cork having a hole in its center. Take the little vial and glass tube used in Ex. 36, and pass the tube through the hole in the cork of the bottle down into the colored water below. (Fig. 16.) Now apply the heat of a lamp-flame yently to the vial, or pour warm water over it, and notice bubbles of air coming out of the tube and up through the water. The vial and tube can no longer hold all the air they did. Ex. 53.-Press a goblet bottom upward down into a vessel of water. See that the goblet is full Fig. 16. of air. Pour warm water over the goblet, and notice AIR. 37 bubbles of air coming out through the water, showing that the air is made larger by the warmth. These experiments teach that the effect of heat upon air is to expand it. Ex. 54.-If the bottle and vial, used in Ex. 52, have now been standing some time since the heat was applied, the air in the vial must have grown cool again. Look at the apparatus, and see the colored water standing far in the tube above the fluid in the bottle. Notice that the air has been cooling and growing smaller at the same time. Ex. 55. —Pour now upon the vial some cold water; see the water mounting still higher, showing again that as the air is cooled it gets smaller. We are thus taught that air contracts when heat is withdrawn from it. Ex. 56.-Place a piece of candle about an inch long — perhaps less-upon a flat block of wood. Light it, and notice the flame burning steadily. Now put a lamp-chimney over the flame, leaving one edge of it projecting over the edge of the block (Fig. 17), and notice that the flame is no longer steady. Its flickering shows that air is coming under the edge of the chimney against it. Ex. 57.-Now let some bits of light cot- ton or feather, hanging at the end of fine thread, be held over the top of the chimney; Fig. 17. they will be blown away, showing that air is coming out of the top of the chimney. We thus learn that heated air is pushed upward by the colder air beside it which flows in at the bottom to take its place. Upon this principle the production of winds may be explained. (Natural Philosophy, p. 141.) 'VIBRATION. The Pendulum. Ex. 58.-Let a ball —it may be a bullet, a ball of wood, or even an apple-be fastened to the end of a cord, the other end of which is to be attached to some fixed support above. This fixed support is easily arranged by nailing a bar of wood to the window-frame, so that it will project out some distance from the wall into the room. A string may be bound around the bar, and the cord of the ball may be tied into this ring. By this means the ball is able to swing freely beneath its support. A body hung so as to be able to swing freely under its support, is a pendulum. Ex. 59.-Lift the ball several inches away to one side and let it go. Notice it swinging back and forth over the same path. Such a motion is called vibration. Ex. 60.-Lift the ball again to several inches; let it go, and catch it with the other hand just as it reaches the point where it would turn to go back; it has swung once over its path. This one motion over its path is called a vibration. Ex. 61.-Take two balls of equal length, one of lead, another of wood, or, such not being convenient, an apple and a potato may be used instead, only let them be as nearly of equal size as possible. Hang them from the VIBRATION. 39 same bar, side by side, with cords of the same length. Take one in each hand; pull them to the same distance, and let them both start at the same moment. Notice that they go over their paths and get back to the hands at the same time, showing that: Pendulums of different materials, other things being equal, vibrate in the same time. Ex. 62,-Take two balls of the same material, two apples, for instance, of different sizes, with cords of equal lengths. Release them at the same moment; notice that they get back to the hand again at the same time, showing that: Pendulums of different sizes, other things being equai, vibrate in equal times. Ex. 63.-Take two balls of the same material and of the same size, but hang them on cords of different lengths. Release them both at once, and notice the short one vibrating faster than the other. Ex. 64.-Change the lengths of the cords, but still have one shorter than the other, and after every change notice that the shortest pendulum vibrates most rapidly. We thus learn that the time of vibration depends upon the length of the pendulum. Ex. 65.-Take now two pendulums, one being just four times the length of the other.* Count the number of vibrations each one makes in one minute by the watch.or clock. Divide 60 by these numbers, to learn how long each one takes to make one vibration. Then notice that * Measure from the point of support to a point a very trifle below the middle of the ball. 40 PHYSICAL SCIENCE. the time for the longer pendulum is just two times as great as for the shorter. Length = 4....... Time of a vibration = 2. Ex. 66.-Let, next, one pendulum be nine times as long as the other. Count and divide as before. Notice that the longer pendulum takes three times as long to vibrate. Length = 9...... Time of a vibration = 3. Now compare the lengths of pendulums and the times of one vibration, and see that: The time of one vibration varies as the square root of the lengths of the pendulum. SOUND. Ex. 67.-Strike the prongs of a tuning-fork gently upon the edge of a table, and then stand the other end upon the table-top. The sound will be distinctly heard. Repeat the operation, and while the sound is heard, bring the edge of a knife-blade carefully alongside of one of the prongs, and notice what a rattle it causes. The prong is found to be in motion, bounding back and forth against the blade. Ex. 68.-Let a bell be struck, and while the sound is heard, touch the bell gently with the finger, andfeel the tremulous motion while its sound is heard. Ex. 69.-If the bell is large, or, better still, if you have a glass bell-jar, make a little pendulum of cork, and hang it so that it touches the lower rim of the bell. When the bell is struck, notice that you not only hear the sound but at the same time see the tremulous motion of the ball caused by the riotion of the bell. Ex. 70.-Take a piece of violin-cord, or of piano-wire, somewhat longer than your table. Fasten one end to a nail in one end of the table, and let the other end of the cord pass over a pulley, or even a projecting piece of board, fastened to the other end of the table, and to this end of the cord hang a heavy weight-a pail or box filled with sand or stones. Let two bridges, like the bridge of a violin, be placed under the cord near the ends of the table. The arrangement is now complete. 42 PHYSICAL SCIENCE. Pull the middle of the cord to one side and let it go again. Notice the sound that is heard, and the motion that is at the same time seen. In all these experiments we find that the sounds of bodies are accompanied by tremulous motions or vibrations, which leads us to infer that: Sounds are produced by vibrations. Ex. 71.-Move one of the bridges toward the other; this shortens the vibrating part of the cord. Make it sound again, and notice that while the cord is shorter, the sound it makes is higher. Shorten it more yet; the sound is still higher. Ex. 72.-Move the bridge gradually back to its first position, thus lengthening the vibrating part of the cord. Make it sound after every change in length, and notice that while the cord is lengthening the sound is gradually getting lower. We thus learn that the height or pitch of sound produced by a cord or wire depends upon its length-the highest sound being caused by the shortest cord. Ex. 73.-Let the bridges remain stationary, and put more and more weight into the box at the end of the cord, to stretch it tighter. Notice the sound after every addition. It will be found to get higher and higher. Ex. 74.-Next take off the weight gradually, so that the cord will be stretched less and less, and notice the sound after each loss of weight; it will be found to be lower and lower. From these experiments we infer that: The pitch of the sound of a cord or wire depends upon the weight or force which stretches it,-the higher sound being produced when the cord is most tightly stretched. SOUND. 43 Ex. 75.-Take two cords of different sizes so that they may be of different weights, and stretch them over the table side by side. Place the bridges under both cords, so that their vibrating parts shall be of equal lengths, and finally hang equal weights at their ends. The lighter cord will invariably give the higher sound. From this we infer that: The pitch of sounds produced by different cords depends upon their weights. Other things being equal, the lightest cord gives the highest sound. LIGHT. FoR experiments with light it is very desirable to darken the class-room and admit a small beam of sunlight with which to work. Choose a window into which the sunlight enters most directly at the time the experiments are to be made, and prepare it as follows: Let some boards be cut of the right length, and let them be of such number and length that when fastened together by cleets they will form a shutter fitting the inside of the window and darkening it completely. At a convenient distance from the bottom of this shutter a hole two or three inches in diameter should be made, through which sunlight may come. For some experiments the direction of the beam of light passing through the room is a matter of importance. An addition easily made to the shutter will help the operator to control the direction and change it at will. Let a shelf be fastened to the outside of the shutter, just under the hole. Upon this shelf a piece of looking-glass may be placed. Now, by propping up the outer end of this glass, and perhaps one side of it also at the same time, it may be given just the right position to receive the sun's rays and throw them through the hole into the room. Any change of position of the glass will change the direction of the light. That the glass may be easily changed at pleasure, have a second hole in the shutter large enough to allow the hand to pass out for LIGHT. 45 the purpose: this hole may be covered with black cloth when not in use. It will not be difficult to darken the other windows in the room by closing shutters, or drawing curtains, or perhaps by hanging shawls over them. With this cheap and easily-constructed arrangement many very beautiful experiments may be made with the greatest ease. A looking-glass, a small concave mirror, a convex mirror, one convex lens and another concave, and a glassprism, are the most important pieces of apparatus. They can be obtained from apparatus dealers at small cost. A little time, a little money, and a little ingenuity spent in putting up and using this apparatus, will be abundantly repaid in beautiful results. Choose a day when the sun shines brightly, and while making experiments keep the lower sash of the window raised above the hole. Ex. 76.-Through the hole in the shutter admit the sunbeanm: sprinkle dust in the path by striking two dustbrushes together in front of its entrance. Notice the path. of the sunbeam shown by the very beautiful bar of illumined dust: it is perfectly straight. Ex. 77.-Change the inclination of the looking-glass a little, and see the change of direction of the sunbeam in the room. But notice that in every position the beam of of light is straight. We thus learn that light travels in straight lines. Ex. 78.-Hold the convex lens in the beam of light entering the room, and see what a curious change: Notice that the light is brought to a point (Fig, 18) at some 46 PHYSICAL SCIENCE. distance from the lens, and that beyond this point it widens out again. A point where light is collected is called a focus. The cone of light going toward the focus is called a pencil of light: the cone going from the focus is also a pencil. In the first case Lp~ ^-M^^^^ the pencil consists of converging rays; in the second the pencil Fig. 1 consists of diverging rays. Ex. 79.-Place a lighted lamp or candle on a table in the darkened room. Hold a flat piece of wood, two or three inches in width, at a convenient distance in front of the flame and catch its shadow upon a white wall or upon a piece of white cloth about as far from the wood as the wood is from the flame. Notice that the shadow is made up of two distinct parts-a dark center and a much lighter fringe on each side. Ex. 80.-Form shadows of other bodies in the same way-it scarcely matters wlhat is chosen for the purpose. The two parts of the shadow will in every case be more or less distinct. Now the dark center is called the umbra and the lighter envelope is called the penumbra. Every shadow is made up of these two parts. Ex. 81.-Place two flames upon the table a little distance apart, and hold the fiat piece of wood in front of them, and notice that two shadows appear upon the wall or screen. Ex. 82.-Then move the wood gradually toward the screen and notice the two shadows drawing nearer to LIGHT. 47 gether. At length the two shadows will lie right beside each other. Carry the wood a little farther, and the two shadows begin to overlap each other, and we may notice. then a single shadow made up of the two, its umbra and penumbra very distinct. The umbra in the last experiment is the part of the shadow which gets no light from either of the flames; the penumbra receives light from one or the other, and is not so dark in consequence. Just so the umbra in a common shadow is the part which gets no light from any part of the flame which casts it, while the penumbra is the part which receives light from some part of the flame, and is not so dark on that account. Ex. 83.-The " dance of the witches " may be shown by cutting fantastic figures out of heavy card-board and hanging them by slender rubber cords from a bar of wood, by which they can be held between the flame and the screen. A dancing motion can be easily given to these figures, and the motion of their shadows will present an amusing spectacle to those sitting in front of the screen. Two or three flames a little distance apart will multiply the shadows and increase the amusement. Ex. 84.-A circular disk of card-board, a triangular piece of wood, a cubical block, a ball, and bodies of other shapes, may be in turn held in front of a flame and their shadows formed. Notice the shapes of the shadows: they will change with every change in the position of the object. The disk, for example, gives a circular shadow when its side is toward the light, but only a dark line when turned edgewise. The ball, however, will give a circular shadow in all positions. The sphere is the only form which will in all positions s8- PHYSICAL SCIENCE. give a circular shadow. The earth's shadow on the.-moon in an eclipse always has a circular outline, showing that the earth is a sphere. Ex. 85.-Let a beam of sunlight into the darkened room and hold a looking-glass obliquely in its path: the light will be instantly thrown from the glass toward the ceiling or wall of the room. (Fig. 19.) If the air is well sprinkled with dust, the bars of light ~ striking the glass and thrown from its surface will be seen distinctly. Ex. 86.-H-old a piece of bright tin or of any polished metal in place of the glass, and notice the same result. Fig. 19. The light which falls upon the surface of a body is called the incident light: that which is thrown off is called reflected light. Ex. 87.-Place a looking-glass upon the floor with its face uppermost, and upon a thick block of wood, or a book on the floor, near one end of the mirror, put a lighted candle. Standing on the other side of the glass, move around until the image of the candle is distinctly seen. Ex. 88.-If the room is not darkened you may stand a goblet partly filled with water upon the face of the looking-glass, and then see the goblet standing upon its image-one goblet seeming to stand erect upon another bottom upward partly full of water. Notice in these experiments that every part of the image is just as far behind the looking-glass as the corresponding part of the object is in front of it, and that the image is just as large as the object. LIGHT. 49 It is the light going from the object to the glass, and being reflected from its surface to our eyes, that enables us to see the image. Ex. 89.-Take two looking-glasses of considerable size and stand them upon their edges at right angles to each other on the table, the room not being darkened. Let a vase of flowers or any other convenient object be placed between the two glasses. Three distinct images of the object will be seen. Ex. 90.-Make the opening between the glasses much less than a right angle, and then put your face halfway between their ends and laugh, as few ever fail to do, at the circle of faces which is seen in the mirrors-a " surprise party,' every member of which will laugh with you. Ex. 91.-Take a bowl or basin in the dark room, and at a little distance from it put a candle-flame, so that its light may pass over the top and strike the opposite side just at the bottom. (a, Fig. 20.) The whole bottom will then be in the shade, and will look much darker \ than the side on which the Fig. 20. b a light shines. Then pour water into the bowl until it is nearly filled. Notice that the light now covers a part of the bottom (a b) of the vessel. We see that in this case the light is bent out of the straight line on entering the water. Such a bending of light always occurs when light passes from one substance into another: it is called refraction. 3 50 PHYSICAL SCIENCE. Ex. 92. —The room being light, put a penny at the bottom of the empty bowl, so that as you look over the edge of the vessel it is / just out of sight (at a, Fig. 21). Now poui water into the bowl carefully, so as not to [7.,'7 ~ disturb the penny. The \ r^' \j / penny will very soon b a Fig. 21. come into view (at b), no change having occurred in the position of the vessel, penny, or eyes. Remember that we see the penny just as we see every thing else, by light that comes from it to our eyes. Without the water, this light, coming up over the edge of the bowl, goes above the eye; for this reason we do not see the penny. But when it has to come up out of water the light is bent where it enters the air, and then, coming over the edge of the bowl, can enter our eyes and enable us to see the penny. Ex. 93.-Let a convex lens-a spectacle glass can be used with success-be placed in the opening in the shutter of the dark room. The hole should be no larger than the lens: it can be made smaller, if need be, by cutting a hole of the right size in a piece of card-board, and then tacking this card over the larger hole in the shutter. Let a screen be made of thin white muslin stretched over a wooden frame. Place this screen near the lens, and move it back and forth until the best effect is found. A beautiful inverted picture in miniature of all things outside the window will be seen upon the screen. A sheet of white paper may be used instead of the muslin screen; the picture will then be best seen on the side toward the lens. HEAT. Production of Heat. Ex. 94.-Rub a metallic button upon a smooth board briskly; it soon will become quite hot. Ex. 95.-Let the finger of the right hand be pressed upon the coat-sleeve of the other arm, or upon a piece of woolen cloth fastened to the desk or table, and then rubbed briskly back and forth. An inconvenient heat is soon felt. We thus learn that heat is produced by friction. Ex. 96.-Let a nail be laid upon some hard surface, a smooth stone, or a flat-iron, for example, and then let it be struck several blows with a hammer in quick succession. On feeling the nail, it will be found to be considerably warmed. Indeed, it call, in this way, be made too hot to be handled conveniently. We thus learn that heat is produced by blows. Ex. 97.-Upon some large fragments of quick-lime lying on a plate, pour some water. After a few minutes, notice the lime swelling and crnmbling to powder, while large volumes of steam are escaping. Let the hand be held in this steam only for an instant, or be laid upon the plate when the action has ceased, and great heat will be discovered. 52 PHYSICAL SCIENCE. The action of the lime and water is called a chemical action, because the nature of these bodies is changed. Ex. 98.-Into a cup put a small quantity of cold water, and then add about one-fourth as much oil of vitriol. The mixture will become intensely hot. There is a chemical action between the two fluids. From these experiments we learn that heat is produced by chemical action. The heat of all our lamp-flames and furnaces is produced by chemical action. Conduction of Heat. Ex. 99. —Take an iron wire and press a bit of wax against one side of it at a distance.... of a few inches from one end. Place this end in the flame of a lamp. (Fig. U D) 22.) After a few minutes the little bit of wax, all this time clinging to Fig. 22. the wire, will fall off. ]Now, the beat must have travelled from the flame gradually along the wire until it reached the wax, and then, by melting it, caused its fall. Ex. 100.-Hold one end of a brass rod, a few inches long, in the lamp-flame. After a little waiting the rod in the fingers at the other end feels warm. In this case the heat has evidently travelled gradually from the flame through the rod to the fingers. When heat travels from particle to particle gradually, as in these experiments, it is said to be conducted. The body in which it travels is called a conductor. Ex. 101.-Take the stem of a tobacco-pipe and a rod of iron as nearly of the same size as possible, and place their ends together, lapping them about an inch, and binding them firmly with small wire. Next fasten a ball of wax to the under side of each of the rods, equally HEAT. 53 distant from the middle point of their junction. Now, if this arrangement is held with the junction in a lamp flame (Fig. 23), it will not be - -. - - long before the ball of wax is melted from the iron, but it will take a long time indeed to melt the ball from the Fig. 23 pipe-stem. We learn thus that the iron conducts heat better than the pipe-stem. Ex. 102.-Take two wires of different metals, brass and copper, for example, of the same size and length. Hold one wire in each hand, the other end of the wire being in the lamp-flame. The heat will be found to reach tlhe fingers through one of the wires quicker than through the other. The two metals teach us that they do not conduct heat alike. Ex. 103.-Let two spoons, one of German silver, the other of silver, be put into the same cup of hot water, with their handles projecting. Feel of the upper ends from time to time, and notice that the silver spoon is heated quickest. From these experiments we learn that all bodies do not conduct heat alike. Convection of Heat.-Ex. 104.-Fill a glass flask two-thirds full of water, and place it upright in a shallow basin of sand standing on a hot stove. Very soon one who looks closely at the water will see delicate currents moving upward from the bottom. Drop a bit of blue litmus into the water. It falls to the bottom and slowly dissolves. Blue clouds appear, which, wafted upward by the currents of water, enable us to see their motion distinctly. These upward currents are of warm water, and 54 PHYSICAL SCIENCE. the heat is being distributed throughout the water in the flask by their motion. When heat travels by means of currents in the body receiving it, the process is called convection. Radiation of Heat.-Ex. 105.-Heat an iron ball or a piece of stone in the stove until nearly or quite redhot. Let it be brought out into tlhe room by means of a pair of tongs. Hold the hand at a little distance above it, on one side of it and on another, and below it. Notice that instcantly, no matter in what direction, the lieat of the ball is felt. The air is a very poor conductor, but we find heat going throug'h it in all directions more swiftly than it can go tllrough the very best conductor. Heat that is thrown through poor conductors in all directions is said to be crdiated, and the process of distributing heat in this way is called radiation. Expansion by Heat. Ex. 106.-Take a bottle having a ground stopper. When the stopper is out, warm the neck of the bottle yentl?/ by wrapping a cloth wet with warmn water around it, and afterward put the stopper in-not too tightly-just so that it fits the neck nicely. Let the neck cool again, and when cold try the stopper. lotice that it is tightly held-perhaps it will not come out at all, because the neck of the bottle is so small as to grasp it too closely. Nlow wrap the neck again in the warm clotl, and after a little try tlle stopper; notice tlat it comes out easily. The heat seems to have made the neck larger, so as to let the stopper out. Ex. 107.-Let a hole be bored throulgh a piece of hard wood, just large enonghl to allow a bullet or other metallic ball to pass through, closely touching its sides. An iron HEAT. 55 rod may be used instead of a ball often more conveniently. Heat the ball or rod, and before it gets hot enough to burn the wood, try to pass it through the hole. If it has been warmed enough you will notice that the hole is no longer large enough to let the body pass. These experiments teach us that heat expands or enlarges solid bodies. Ex. 108.-Fill a bottle with cold water. Pass a piece of glass tube, a few inches long, through a cork fitting the neck of the bottle nicely, and press the cork into the neck. If the bottle was brimfull of water, as it ought to be, the water will stand some distance up in the tube when the cork is inserted (Fig. 24). Tie a string around the tube to mark the height of the water in it. Now plunge the bottle into a vessel of warm water. Notice the water quickly beginning to rise up the tube, and continuing to | do so while the heat is applied. We see that the water is getting larger as it becomes hotter. Fig. 24. Ex. 109.-Another bottle, used in the same way, with some other liquid, as oil or alcohol, will show the same effect; the liquid will get larger as it gets warmer. From these experiments we learn that heat expands ligqid bodies. Ex. 110.-Fit the neck of a bottle with a cork, and through this cork put the end of a glass tube several inches long. Into another bottle put some water, which may be colored with ink, or cochineal, or litmus. Turn the first bottle bottom upward, and put the open end of its tube down into the colored water of the second. i6 PHYSICAL SCIENCE. Notice, before going farther, that the upper bottle and'ts tube are full of air. Next pour warm water upon the upper bottle, and notice numerous bubbles of air escaping through tle fluid from the lower end of the tube. Tile air is expanded by the heat. Ex. 111.-After a little time, the colored water will rise some distance up the tube in the arrangement used in the last experiment. When this is the case, notice that the tube, above the water, and the bottle are full of air. Now pour some warm water again over the bottle, and see the water quickly driven down by the expanding air. We thus learn that heat expands air, and when similar experiments have been made with other gases, the general truth is found that heat expands gaseous bodies. Contraction by Cooling. Ex. 112.-The hot rod of iron (Ex. 107) was too large to go through the hole in the hard wood, but now that it is cold again, try it, and notice that it goes through easily again. It ]as given off its heat; and at the same time grown smaller. Ex. 113.-Take the bottle and tube with water, used in Ex. 108; mark the height of the water in the tube, and then place the bottle in a vessel of cold water. Notice the water falling in the tube, showing that as the water in the bottle cools it grows smaller. If this does not show distinctly the desired result, then first warm the bottle of water, and afterward put it into the vessel of cold water. Ex. 114.-Take the apparatus used in Ex. 52, the colored water now standing some distance up in the tube, the space in the tube above the water and in the bottle being filled with air. Pour cold water upon the upper bottle, and notice the colored water quickly rising higher HEAT. 5T in the tube. The air is cooled by the water, and we see that it at the same time gets smaller. From these experiments we learn that the withdrawal of heat f'rom bodies causes them to contract. We thus find that the hotter a body is the larger it is, and the contrary-the colder it is, the smaller. Curious effects in Water. Ex. 115.-Into a common bowl or basin put a considerable quantity of snow, or ice shaved fine with a large knife, and add about half as mTuch common salt. Stir the mixture thoroughly; it will become nearly fluid and be intensely cold. It is called afreezing mixture. Fill a thimble with water, or a pipebowl, with the hole in its bottom closed with wax, and stand this little dish in the freezing mixture. The water, after a few minutes, will be frozen. Ex. 116.-Now take the bottle and water (Ex. 108), the fluid standing some distance up the tube, and place it in the freezing-mixture. Notice first, that the fluid sinks in the tube, showing that as the water cools it contracts. Notice next, after a little time the fluid stops sinking, showing that as water goes on cooling more yet the contraction stops. Notice again, that the water begins to rise in the tube again, showing that the cooling water is now expanding. Notice finally, that ice begins to form in the bottle, and that while the water is freezing, the water in the tube continues to rise, showing that water expands while freezing. Ex. 117.-Take now the bottle containing ice from 08 PHYSICAL SCIENCE. the freezing-mixture, and put it into a vessel of water slightly warm. Notice the water sinking in the tube while the ice is melting, showing that heat contracts the ice while it melts it. Notice afterward, that the water continues to sink in the tube for a little time, showing that heat applied to icecold water contracts it. Notice finally, that the water in the tube begins to rise again, showing that after water has reached a certain degree of temperature, heat expands it. (See Natural Philosophy, p. 240.) ELEOTRICITY. THE successful performance of experiments in electricity demands a dry atmosphere and dry material: dampness in either may cause annoyance and even complete failure. The winter season is generally more favorable than the summer, and an unventilated room, in which the air is loaded with moisture from the lungs of many individuals, is to be especially avoided. In a long, cold winter evening, wihen the family are gathered around the cheerful sitting-room fire, electrical experiments are most likely to succeed admirably. And in a school-room, which has been thrown open and well-ventilated during recess, and in which a brisk fire is rapidly heating the atmosphere again, or, better still, in the morning before the pupils have had time to load the air with dampness, electrical experiments may be tried with the best assurance of success. The following experiments are simple enough for a child to perform, and will furnish children not only, but older students as well, with much amusement and instruction. Electricity produced by Friction. Ex. 118.Take a piece of thin and tough brown paper, about an inch wide and six inches long; heat it thoroughly by holding it over a hot stove or the flame of a lamp, and then holding it in one hand by the end, quickly pull it between 60 PHYSICAL SCIENCE. the thumb and fingers of the other hand, thus rubbing it vigorously. After two or three such rubbings bring the paper near to the wall, and it will instantly fly into contact with it, and perhaps if you let go of it you will see it clinging to the wall. It will thus remain sometimes'for several minutes as if pasted. Ex. 119.-Rub the paper a second time, and, holding it by one end in one hand, bring the other hand alongside of it Notice how quickly the paper flies against the fingers, and how strongly it is inclined to stay there. Ex. 120.-Procure a glass tube several inches in length,-a lamp-chimney, if one can be found of convenient shape to rub easily; procure also a piece of flannel cloth. Both should be thoroughly dry. Iolding the glass in one hand, bring it up very near to the face; you will be able to notice no effect. Next rub the glass vigorously with the flannel held in the other hand, and bring it afterward near to the face as before. A sensation will now be felt like what would be caused by drawing spiders' webs over the face. Ex. 121.-Rub the glass again vigorously, and afterward bring it near to the knuckle of your hand; a crackling sound will be heard, and in the dark little sparks of light are often seen. Ex. 122.-Place some very small and light bits of cotton upon the table. Thoroughly rub the glass again, and bring it near to the bits of cotton; notice how quickly they leap up to meet it. Ex. 123.-Let a bit of cotton or downy feather be floating in the air; bring the glass, which has been vigorously rubbed, near to it. The cotton or the feather will instantly dart against the glass through considerable distance. ELECTRICITY. 61 Ex. 124.-Any one of the preceding experiments may be made with a stick of sealing-wax in place of the glass tube. The same effect will be produced. In these experiments we see that by rubbing the paper, the glass, or the sealing-wax, a new power seems to be developed in them. All the effects noticed are due to electricity, and this electricity is in such cases produced by rubbing, or, as it is called, by friction. Attraction and Repulsion. Ex. 125.-Untwist a silk thread, and take one of its fine fibres; tie to the end of this a very small and light piece of cotton. Let another person hold the cotton by taking hold the other end of the thread, while you rub the glass tube vigorously. Then bring the tube near to the bit of cotton. You will see the cotton fly quickly toward the glass, sometimes through a distance of several inches. The cotton is attracted by the glass. Ex. 126.-Rub the glass thoroughly again, and again bring it near the cotton; the cotton will doubtless be attracted as it was before. If so, let it cling to the glass for some time; then rub the tube again and present it to the cotton as before. If the cotton is again attracted, let it stay in contact with the glass for a time, and then go over the same work again. After a few,-sometimes only one of these trials, the cotton will refuse to again come in contact with theglass. As often as the tube is moved toward it, the cotton darts away. Not until it has first touched some other body can the cotton be made to touch the glass. In this experiment we find the cotton driven away from the glass tube; it is said to be repelled. Ex. 127.-Sometimes the electricity may be made so 62 PP tSICAL SCIENCE. strong on the glass that placing it on one side of the suspended cotton and the hand or piece of iron on the other side of it, the little pendulum will fly quickly back and forth between them many times, being first attracted and then repelled by the electrified glass. We learn from these experiments that electricity shows its presence in two ways, viz.: by attraction and repulsion. Ex. 128.-Let a long silk ribbon, warm and dry, be hung over the forefinger of the left hand; the two parts will hang down side by side together. Now put the forefinger of the other hand between the two parts of the ribbon and press them tightly against it with the thumb and other fingers. Pull the ribbon out quickly, rubbing the whole length of its parts between the fingers; repeat this operation three or four times, and then notice that the two parts of the ribbon will no longer be willing to touch each other. They repel each other. Put the hand between them, and both quickly fly toward it; remove the hand, and they as quickly fly back again. Ex. 129.-Let one person rub the ribbon, as in the last experiment, while another rubs the stick of sealingwax with the dry flannel. When both are well electrified, let the sealing-wax be brought between the parts of the ribbon. They will fly still farther apart. The electrified sealing-wax repels the electrified ribbon. Ex. 130.-Now rub a glass tube, a lamp-chimney, if of convenient shape, and bring it between the electrified branches of the ribbon. Both parts instantly fly toward the glass; the electrified glass attracts the electrified ribbon. We see that the ribbon acts differently toward the ELECTRICITY. 63 electrified glass and toward the electrified sealing-wax. It flies toward the first, andfrom the second. Ex. 131.-Hang a little ball of cotton to the end of a silk fibre, as in Ex. 125. Rub the glass, and then bring it in contact with the ball until the latter flies away, being repelled by the electrified glass. Rub the sealing-wa:with flannel, and bring it toward the ball; the ball will quickly fly to meet it, being attracted by it. Again, we see that electrified glass and electrified sealing-wax act in different ways; when the cotton is repelled by glass it is attracted by sealing-wax. Now whenever the electricity is like that produced by rubbing glass it is called positive electricity, and when it is like that produced by rubbing sealing-wax with flannel it is called negative electricity. The Electroscope. Ex. 132.-Rub the glass tube or stick of sealing-wax vigorously, and observe whether any visible change whatever is produced. None: then, without somefarther trial, it is not possible to tell whether electricity has been developed or not. It may be brought near to the face or hand, and the feeling of cobwebs, or a snapping sound, may show that the tube or wax is electrified, or bringing it near to liglht bodies, as cotton, on the table, electricity will show its presence by attracting them. But neither of these ways is always quite convenient. Ex. 133.-Now take a slender rod of some dry wood, several inches long; make a little ball of the dried pith of corn-stalk or elder, of cork, or even of cotton; fasten it to one end of a silk fibre, and tie the other end of the fibre to the other end of the wooden rod. Next place tle rod upon the table, so that the end carrying the ball shall 64 PHYSICAL SCIENCE. project some inches beyond the edge, or, what is better yet, put the wood up on a pile of books, or some other support, above the table, so that the little ball may swing clear. Now notice that whenever the electrified glass tube or sealing-wax is brought near to this little pendulum, the electricity is at once shown by the motions of the ball, which, if the electricity is well developed, will fly toward the tube or wax, and, after a moment's hesitation, will as quickly fly away again. Ex. 134.-Or, take tinfoil, -a piece one-half inch long and one-quarter inch wide, and hang it in place of the ball in the preceding experiment, and it will be found to show the presence of electricity as well as the other. Here then notice these simple and convenient arrangements by which to show the presence of electricity. Any such instrument is called an electroscope. Ex. 135.-Rub the glass tube vigorously, and then bring it in contact with the ball of the electroscope; this ball, remaining in contact only a moment, if the tube is well electrified, flies away again. We have seen this action in former experiments, but what we wish to notice now is that the ball in contact with the glass takes electricity from it, so that it is electrified in the same way as the glass, or in other words, positively, and that when this is the case, the two bodies separate, showing that they repel each other. In this experiment we see that two bodies, electrified with positive electricity, repel each other. Ex. 136.-Next rub the sealing-wax vigorously with flannel, and hold it in contact with the ball of the elec* The thin metallic wrapping found on some kinds of packages at the grocery store. ELECTRICITY. 65 troscope until it flies away, as it will do after one or more trials. Now what we must notice here is that the electricity of the sealing-wax is negative, and that the little ball must have the same kind of negative electricity also inl it when it flies away from the wax. In this experiment we see that both bodies, electrified with negative electricity, repel each other. We see from these two experiments that when bodies are electrified in the same way, they repel each other. Call this the 1st dLaw. Ex. 137.-Rub the glass tube again, and electrify the ball of the electroscope with it. Notice that the little ball is positive, because electrified from glass. Then rub the sealing-wax with flannel, and bring it near to the little ball. The ball darts instantly against the wax. The wax is negative, the ball is positive, and the two attract each other. Here we see that two bodies, electrified with opposite kinds of electricity, attract each other. Call this the 2d Law. Ex. 138.-Repeat the experiment with the silk ribbon (Ex. 128). Notice its two branches repelling each other. Now, are these branches electrified with the same or with op)posite kinds of electricity? (1st Law.) Ex. 139.-Can we find out which kind of electricity we have in the silk? Rub the glass tube, and hold it in contact with the ball of the electroscope until it flies away. We know that the ball is positive. Bring the silk ribbon, whose branches are repelling each other, near to the positive ball, and see how quickly the two fly together! The positive ball is 66 PHYSICAL SCIENCE. attracted, and hence (2d Law), the silk must be negative. We see then that our little "electroscope" not only helps us to detect the presence of electricity; it also helps us to tell which kind a body is electrified with. Let us try it. Ex. 140.-Take a piece of thin but strong brown paper; cut from it a strip an inch wide and sixteen or twenty inches long; thoroughly dry and warm it, and then use it just as the silk ribbon was used (Ex. 128). After the branches of the paper have been drawn through the fingers once or twice, they repel each other strongly. Now what kind of electricity have they? Electrify the ball of the electroscope from the sealing-wax rubbed with flannel; the ball is then negative. Bring near the ball the paper, and see how strongly they repel each other, showing (1st Law) that they are in the same condition; the paper is negative. Ex. 141.-Electrify the ball of the electroscope from glass: it is positive. Now rub the sealing-wax withflannel, and notice that it attracts the ball, showing the wax to be negative. Pass the hand over the surface of the sealing-wax to remove the electricity from it, and then rub it vigorously with a piece of silk. Electrify the ball of the electroscope from the glass again; it is positive. Bring the electrified wax near to it, and then notice that it now repels the ball, showing the wax to be positive. It appears that the electricity of sealing-wax, when rubbed with flannel, is positive, but, when rubbed with silk, is negative! Ex. 142.-See whether the electricity of glass is different when the rubber is flannel from that when the rubber ELECTRICITY. 67 is silk. To do this electrify the little ball from the sealing-wax, rubbed with fannel, and bring the electrified glass near to it. Ex. 143.-Take two pieces of brown paper, each about ten inches long by five inches wide; make them quite hot by holding them over a heated stove or the flame of a lamp. Place them on the table, or, still better, on a tea-tray, one above the other, and rub them vigorously with the palm of the hand. If now you take hold of one corner and lift them from the table, you will find them clinging to each other. If you try to separate them you will see how strongly they attract each other, and sometimes you may hear also a crackling sound on pulling them apart. Notice that the upper one only was rubbed but that both are electrified. And more, since they attract each other they are electrified in different ways. Ex. 144.-Take two fiesh sheets of paper, such as described in Ex. 143, and, having heated them thoroughly, put one above the other on a pane of glass. Rub the upper sheet vigorously with the hand. Taking hold of one end, lift them from the glass, and notice that they now repel each other. If Experiments 143 and 144 are repeated, it will be found that the papers whenever rubbed while lying upon the tea-tray will attract, but if rubbed while lying upon the glass they repel each other. Now the upper one only is electrified by the rubbing; the lower one is electrified from the upper one. When they lie upon glass the lower one becomes electrified in the sanme way as the upper one, and lience they repel (1st Law), but when they lie upon the tea-tray the lower one 68 PHYSICAL SCIENCE. becomes electrified in the opposite way, and hence they attract (2d Law). When one electrified body electrifies another body near to it, and puts it into a condition opposite to its own, it is said to act by induction. The upper strip of paper, when they were rubbed on the tea-tray, electrified the lower one by induction. The full explanation of induction, or, as it is now generally called, polarization, may be left for a higher course of study. Ex. 145.-Having electrified the two sheets of paper, show that they are in opposite conditions by testing them with the electroscope. EASY EXPERIMENT$S IN CH1EMISTRY. CHEMISTRY. THE following simple experiments in Chemistry are pretty and instructive, but, as a general thing, the materials needed are not so conveniently obtained as those needed for the experiments in Natural Philosophy. They are not expensive, however, and what cannot be found at the village stores can be sent from dealers in larger towns on application. Chemical Action. Ex. 146.-Put some strong vinegar into a goblet-enough to fill it about one-quarter full. Take some common " baking soda," as much as will lie upon the end of a case-knife blade, and sprinkle it into the vinegar. A violent foaming will occur, continuing for a time, and when it stops the " soda " will have disappeared. Add more "soda," little by little, until the fluid refuses to foam; the "soda" last added will then remain in the bottom. Now notice: the soda has disappeared from view in this action, while the vinegar (touch it with the tongue) is so changed as to be no longer sour. Here then we find a violent action going on between the vinegar and the soda, by which the natures of both these substances are changed. Ex. 147.-Into a common bottle put a few small pieces of copper, and then pour in upon them nitric acid enough to cover them. iYotice that a violent action quickly begins. The fluid appears to boil. Its color be 72 PHYSICAL SCIENCE. comes deep blue. Cherry-red vapors fill the bottle above the fluid, and perhaps run over the top of it into the room. The copper is, in the mean time, being slowly used up: it will finally disappear altogether if there is acid enough used for the purpose; and when the action ceases, there will remain the quiet blue liquid in the bottle, with some of the red vapors remaining in the air above. In this experiment we again find a violent action, by which the nature of the substances used is changed. Ex. 148.-Into one goblet put three or four drops of hydrochloric acid: into another put as much ammonia. Now turn one of these goblets right bottom side up over the mouth of the other. Both will be quickly filled with white fumes. The acid and the ammonia are liquids nearly or quite colorless: they form, when put together, a vapor which is white. Here also we notice an action which changes the nature of substances. Ex. 149.-Mix together a half-teaspoonfull each of sugar and potassic chlorate, both powdered, and put the mixture upon a common card. The card may well be laid upon the top of a goblet for support to keep it off the table. Now put two or three drops of sulphuric acid upon the mixture. A curious combustion will quickly follow, in which tongues of purple flame will shoot up some distance with considerable noise. When the burning is over, look for the sugar and the chlorate: both have disappeared, and nothing but a black coal-like mass remains upon the card instead. We notice that this combustion is an action by which the natures of the burning bodies are changed. Now, all such acticns as have been shown in these ex CHEMISTRY 73 perimrents are called Chemical Actions. We therefore mean by the term chemical action any action among bodies of matter by wlich their natures are changed. Combination and Decomposition. Ex. 150.Into a small vial-a long and narrow one is best for the purpose-put some water, and then add oil enough to cover the water well. Being the lighter liquid, the oil of course floats upon the water. Now pour in a little ammonia and shake the mixture thoroughly. A soapy liquid will appear instead of the oil and water. Indeed, the oil and the ammonia have joined themselves together and made a kind of soap which mixes with the water. Notice that this new substance, the soap, is a very different thing from either the ammonia or the oil which make it. Now, when two or more substances disappear to form a new one different from themselves, they are said to combine. The new substance made is called a compound. The ammonia and the oil have combined to form the soap, which is a compound. Ex. 151.-Add to the soapy liquid just made in Ex. 150, a little strong sulphuric acid. Shake them well together. The soapy liquid will in part or wholly disappear, while the oil will be brought back again and will be seen floating upon the water as before. Now we see that the sulphuric acid must have taken the ammonia away from the oil, for the soapy substance is broken up, the oil in it coming back again. When a substance is separated into the different materials which compose it, as the soap has been in this experiment, it is said to be decomposed. The substances into which it is separated are called its constituents. The 74 PHYSICAL SCIENCE. soap was decomposed; oil is one of its constituents, ammonia is another. Acids. Ex. 152.-Crush one or two small pieces of blue-litmus and put the powder into a goblet of water. The litmus will dissolve and give a deep blue color to the water. Now add a little strong vinegar, and notice the curious change in color: the blue turns to red. Ex. 153.-Into another goblet of water, colored blue with litmus, put a few drops of sulphuric acid: the blue is quickly changed to red. Ex. 154.-Into another solution of blue litmus put a few drops of nitric acid, and notice how quickly the red color appears. Ex. 155.-Take another goblet of litmus, and add hydrochloric acid: the blue instantly gives place to red. We find that there is a class of substances which are able to turn the color of blue litmus to red. Should you taste these substances you would find them all to be sour. They have other characters in common, but the one most conveniently tested is their power to turn the blue color of litmus to red. These substances are called acids. Alkalies. Ex. 156.-Take a goblet containing litmus, the color of which has been changed to red by an acid, and put into it a little ammonia. Notice that the red color changes back again to blue. Ex. 157.-Take a common glass or tin funnel, stop its neck by crowding some unsized paper (blotting paper) into it, and then pack the funnel nearly full of wood-ashes. Pour some warm water upon the ashes, and as it runs through them and out of the stem of the funnel catch it in a bottle, through whose neck the funnel-stem passes CHEMISTRY. 75 and upon whici it rests. (Fig. 25.) When enough of this liquid has been caught, pour it into a goblet of litmus whose color has been changed to red by an acid and notice that the blue color of the litmus is restored. (If too much acid has been added to the litmus it will be difficult to make it blue i again.) We see in these experiments that some sub- | I" stances have the power to bring back the blue color of litmus after it has been turned red by Fg. 20. acids. Now, the most common substances of this kind are called alkalies. Ammonia is an alkali, so are potash and soda. Acid or Alkali? Ex. 158. —Iaving a bottle and a cork which fits its neck, take a wire and run one end of it through the cork, so that when the cork is put into the neck of the bottle the wire will hang down some distance inside. Now take the cork in the hand and hold the other end. of the wire in the fire until it is very hot. Plunge this hot wire into a vessel of sulphur. By this means considerable sulphur will cling to the wire. Now again hold the end of the wire in fire to inflame the sulphur upon it, and then plunge the burning sulphur into the bottle. It will continue to burn for a little while, filling the bottle with white funmes. These whllite fumes are quite different from either the sulphur or the air: a new compound has been fobrmed by the burning sulphur. Remove the cork and wire and pour a little blue-litmus water into the bottle. Shake it well, putting thle hand over the mouth of the bottle to keep the contents from escaping, and notice the change of color. Is the new compound an acid or an alkali 76 PHYSICAL SCIENCE. The name of this new substance is sulphurous acid. The same white fumes are made when a match is lighted. Ex. 159.-Put some water into a goblet, and mix with it just enough blue litmus to give it a distinctly blue color. Then take a glass tube: put one end into the colored water, the other into the mouth, and breathe the air from the lungs out through it in bubbles through the water. After a little while notice the change in the color of the water: it turns to red. This experiment shows that an acid is contained in the breath as it comes from the lungs: it is called carbonic acid. Nitrogen and Oxygen. Ex. 160.-Prepare a bottle, with cork and wire, just as was done in Ex. 158; the bottle may be in this case a large one. Cover the end of the wire with sulphur, and let it burn in the bottle, as in the other experiment. Have a second cork fitting the bottle: take the cork and wire out, putting the other cork quickly in. Cover the wire a second time with sulphur, and burn it in the bottle. Repeat this until the sulphur quite refuses to burn in the bottle. Then turn the bottle cork downward: plunge its neck into a basin of water: take the cork out, being careful to let no air get in, and leave the bottle thus inverted in the water. After some considerable time, notice that the white fumes in the bottle are not as dense as they were. We see that the water is taking them out. Finally, they will all disappear. Notice then that the water has risen in the bottle a ways, and that the air (as it seems to be) above the water is again clear." Now cork the bottle again, and afterward remove it from the water and stand it upon the table. * If the teacher will perform this part of the experiment beforehand, he need not wait for the water to take the fumes out. He can tell the pupils CHEMISTRY. 77 Next take a bit of candle; fasten it to the lower end of a wire (which may be bent upward for the purpose) (Fig. 26), and having lighted it, take the cork from the bottle and plunge the candle in. The flame is extinguished as if it had been plunged into water. If it were air in the bottle the candle would continue to burn, so that what seems to be air in the bottle is not. Now, this gas is what is called nitrogen. A From this experiment several things may be learned: First.-The sulphur, burned in air, left only nitro-ig 26. gen: then nitrogen is a constituent of air. Second.-We look at the bottle and see that nitrogen is a gas, colorless, and transparent as air itself. Third.-Nitrogen extinguishes flame as quickly as water would. Fourth.-The burning sulphur took something out of the air of the bottle to leave the nitrogen. This something combined with the sulphur to form the new compound-the white fumes. Now this substance taken out of the air by the burning sulphur is what is called Oxygen. So that we learn: Fifth.-That oxygen is another constituent of the air. The sulphur took the oxygen out of the air while burning; now, it is a fact that when any substance burns in air the oxygen of the air is being used up. If it were not for the oxygen in the air there would be no such thing as fire known upon the earth. Ex. 161.-Now light the candle and again plunge it that he did the same thing with the other bottle, and that now, after standing so long, the fumes are all gone, and then go on with the work. Always let the bottle which they have been using, stand, that they may see the air clear in it also afterward. T8 PHYSICAL SCIENCE. into the bottle which held the nitrogen (Ex. 160), and which has been left, standing open, on the table. Notice that the flame is not quickly extinguished, as it was before. The nitrogen has left the bottle, we see: it must have gone up out of the open bottle into the air of the room. This experiment teaches us that nitrogen is ligh/ter than air. Hydrogen. Ex. 162.-Put some clippings of zinc (sheets of zinc are used under stoves) into a wide-mouth bottle. Let the bottom of the bottle be more than covered with them, and then pour water in to more than cover the zinc. Next pour a little sulphuric acid into the bottle. In a few moments the liquid will begin to foam: if. not, then add a little more acid, for the "boiling" should be violent enough to make the foaming fill the bottle half full. After this violent chemical action has gone on for a few minutes, and while still violent, bring a lighted match to the mouth of the bottle. An explosion will be heard, and a flame will at the same time appear at the mouth of the bottle-sometimes running down into it. We see that a gas is produced in this experiment which is combustible. This combustible gas is called IHydrogen. Ex. 163.-Wrap a towel around a bottle containing zinc and water, as in the last experiment. Pour in the acid as before, but touch the match to the mouth of the bottle very soon after the action begins. The explosion may be more noticeable in this experiment. The object of the cloth is to prevent the glass from flying and causing injury if, as very rarely cccurs, the explosion should be strong enough to break the bottle. Another proper caution is to tie the match to the end of CHEMISTRY. 9 a wire or stick, so that the hand would be at a distance when the explosion occurs. Now notice that in this experiment the hydrogen has not had time to drive the air all out of the bottle, so that there is a mixture of air and the gas when the explosion occurs. We see that hydrogen and air form an explosive mixture. On this account great care should be taken, in all experiments with hydrogen, to expel all air from the apparatus before using the gas. Ex. 164.-Prepare a cork for the bottle in which hydrogen is to be made, by making a hole through the' middle of it and inserting the end of the stem of a tobaccopipe, so that when the cork is put into the neck of tlhe bottle it shall fit air-tight-the pipe-stem reaching above it. The zinc and water being put into the bottle, add enough sulphuric acid, and then quickly insert the cork. Wait until you are sure that the air has been driven out by the hydrogen, and then bring a lighted match to the upper end of the pipe-stem. The hydrogen takes fire as it issues, K and burns with a steady flame (Fig. 27)..L Notice the flame, and you will see that it gives a feeble light, but: Ex. 165.-Insert a small wire in the flame and rig. 2T. you will find it quickly glowing with a red heat. The flame of burning hydrogen is the source of little light, but of very intense heat. Carbonic Acid. Ex. 166.-Cover tle bottom of a glass jar (it may be a common fruit-can) with "baking soda," and pour upon it-a little at a time-some strong SO PHYSICAL SCIENCE. vinegar. Watch the violent boiling, or, as it is properly called, effervescence, which occurs. Take a bit of candle; fasten it to the lower end of a wire, which is bent upward to support it. Light the candle and pass it down into the jar: the flame will be put out as it enters the gas given off by this chemical action. Notice also that the gas in the jar is colorless and transparent. Is it nitrogen? We will see in another experiment. Ex. 167.-Let the jar containing the gas stand for some time open upon the table after the effervescence has stopped. Insert the lighted candle again: it is seen to be again extinguished,-showing that this gas is heavier than air, and hence is not nitrogen. This colorless gas, which extinguishes flame and is heavier than air, is called Carbonic acid. Ex. 168.-Take a piece of candle, an inch in length, and fasten it upon a cork. This may be done by dropping some melted tallow upon the middle of the cork and pressing the lower end of the candle down upon it, until it hardens. Light the candle, and put it into a jar, or very wide-mouthed bottle. Cover the jar with a plate. The candle standing upon the bottom of the jar goes on burning for a little while, but begins to grow dim, and finally expires. Take the plate from the jar. A stiff wire which has been sharpened with a file may now be stuck down into the cork, and by this means the candle may be lifted out. Next pour a little lime-water* into the jar, and notice that on shaking it about it becomes milky. What * Lime-water may be prepared by taking a little slacked lime, putting it into a bottle, filling the bottle with water, and then shaking it thoroughly. Let the lime afterward settle, and then pour off the clear water above into another vessel for use. CHEMISTRY. 81 makes this change? Air will not do it, Nitrogen would not stay in the open jar, so that it cannot be nitrogen; much less can it be hydrogen. The gas which was in the jar, to turn the lime-water milky, was colorless; it put out the flame of the candle, and it was heavier than air. It seems to have been carbonic acid gas. As a matter of fact, this gas is the only one which will turn lime-water milky. But what produced this gas in the jar? It must have been the burning candle. All common flames like this one produces carbonic acid gas. Ex. 169.-Put a little lime-water into a goblet, and, taking a glass tube, or even a straw, put one end into-the water, the other into the mouth, and breathe the breath out through the liquid. After a breath or two, the limewater will be seen to be milky, thus showing the presence of carbonic acid gas. We learn from this experiment that carbonic acid is one of the things given off from the lungs in breathing. Ex. 170.-Breathe into a clean and dry glass jar: its sides are instantly covered with dew. Showing that water-vapor is another thing given off from the lungs in breathing. Carbonic acid and water are constantly being produced in the process of breathing. The first of these is made up of carbon and oxygen: the second of hydrogen and oxygen. The oxygen for both is furnished by the air taken into the lungs: the carbon and the hydrogen are furnished by waste particles or impurities of the system. The oxygen from the lungs enters the blood-vessels, and goes throughout all parts of the circulation, meeting these waste particles in its course. It decomposes them: com 82 PHYSICAL SCIENCE. bines with their carbon and hydrogen, and then, as carbonic acid and water, goes back to the lungs, from which these substances are thrown out into the air. In this way the blood is purified. Flame. Ex. 171.-Spread the wick of an alcohol lamp, so that, lighting it, a large flame may be obtained. Plunge the sulphur end of a match into the dark center of this flame, and notice that while the wood burns in the edge of the flame, the more combustible end of the match does not burn in the center of it. Ex. 172.-Take a long splinter or rod of pine wood, freshly smoothed, that its surface may be white, and lay it horizontally across the alcohol flame, just above the wick. When the stick begins to burn remove it, and notice that it is scorched in two places. The part which was over the center of the flame is unharmed. Ex. 173.-Press a piece of white paper, held horizontally, quickly down into the flame of the alcohol lamp, to a place just above the wick. As soon as the scorching begins to be seen through the paper take it quickly away. The paper will be burned in the shape of a ring. That part which was directly over the wick is unburned. Ex. 174.-The following experiment may be added to this list, provided great care is taken to follow directions: otherwise accident might happen. A common dinner-plate, when inverted, gives us a very shallow dish, the bottom of a plate being, as you will see, surrounded with a slightly elevated rim. Put a plate upon the table, bottom upward, and pour alcohol into the shallow dish thus obtained, being very careful that none of the fluid runs over upon the table or even upon the sides of the plate. Take a cork, about an inch in diameter: put a CHEMISTRY. 83 little gunpowder upon top of it, and stand it right in the center of the alcohol on the plate. Take a lighted match and touch the alcohol at one edge of the plate; it will take fire: the flame will instantly spread all over the top of the plate, and, if no breeze waft it against the cork, the gunpowder will remain some time, in the center of t/e flame, unharmed! These experiments clearly teach us that the interior of the alcohol flame is not in a state of combustion. Tile same experiments, except the last one, may be made with a candle-flame with much the same results. The interior of all ordinary flames are, like that of the alcohol-lamp, not burning. This central part of a flame consists of combustible gas, and is surrounded by the burning envelope. Ex. 175.-Repeat Experiment 164 with apparatus shown in Fig. 27. Having thus obtained a hydrogenflame, remember that it is being produced by the hydrogen from the bottle and the oxygen in the air. Now, hold over this flame a clean and thoroughly dry glass jar. Its sides will be seen to become instantly covered with dew. Now, this water is the result of the action between hydrogen and oxygen in the flame, and hence the experiment teaches that water is made up of the two substances, hydrogen and oxygen. Ex. 176.-Now hold a clean and dry jar in the same way over the flame of the alcohlol-lamp: its sides are soon dimmed with dew also. Let the same thing be done with a candle and with other flames. Water will be, in every case, deposited upon the sides of the jar. But, since water consists of hydrogen and oxygen, these results show that these two substances take part in the 84 PHYSICAL SCIENCE. production of the flames. Water is a product of all ordinary combustion in flames: the oxygen is furnished from the air: the hydrogen from the body burning. Ex. 177.-Press the bottom of a cold dinner-plate down upon the flame of a candle. A moment afterward take the plate from the flame, and notice the black soot which is collected where the flame burned against it. There is something beside hydrogen and oxygen, we see, taking part in the production of this flame. The black soot is carbon. The flame of a burning stick, and indeed almost any common flame, will furnish carbon upon a solid body held in it. And yet no carbon is seen when a flame burns freely. Why? Ex. 178.-Fix a bit of candle upon a cork, by dropping a little of the melted wax or tallow upon its top and pressing the bottom of the candle upon it until cold. Light the candle and stand it on the table, and bring an inverted glass-jar down over it. The candle will burn freely for a little while, but at length it will burn more dimly, and finally go out. Turn the glass-jar right side up and pour into it a little lime-water. After shaking it about a little, the lime-water will become whitish, showing the presence of carbonic acid. Now, carbonic acid consists of oxygen and carbon, and it has been formed in the flame. Its oxygen has been furnished by the air, but its carbon must have come from the candle. And now we see what becomes of the carbon when a flames burns freely. It combines with oxygen of the air, and forms carbonic acid gas, which, being invisible, passes unseen off into the air. We see from these experiments that water and carbonic gas are produced by the combustion in ordinary flames. The hydrogen and the carbon for these are fur CHEMISTRY. 85 nished by the fuel which burns, while the oxygen comes from the air. Combustion in all common instances is nothing but a chemical action between the oxygen of the air and the elements of the fueL 0 0 0 L E Y'S Physical Science Series. FOR GRADED SCHOOLS. Cooley's Easy Experiments in Natural Philosophy and Chemistry - - $.75 Cooley's Elements of Natural Philos'y - 1.00 Cooley's Elements of Chemistry - - 1.00 FOR ACADEMIC CLASSES. Cooley's Natural Philosophy - - $1.50 Cooley's Text-Book of Chemistry - - 1.25 Teachers find in these books the most judicious selection of matter, developed in topical form by the most skillful methods. Sent to teachers for examination, postpaid, on receipt of two-thirds theabove prices. SCRIBNER, ARMSTRONG & CO., PUBLISHERS, New York. __ ________________________-j