fsV * o , *>> V v ^ ;, o V 6* V *© v" ; jP^k M*' *P ^ *°«°° v ^ ++0* ^°<* P* *l!nL'* "> v v • *••- <* '•• 1>- O o, *^V'A V^>' V * y * °* ^u . ^ .& > 0° 4 o •>° 7 ° J*** . V, c ,:^v. °^./ ■* ' x% ^ s Eatstm Spinas ////so ,jAsv/v//«//// Mni LansinaluraA A DISSERTATION ON THE MINERAL WATERS OF SARATOGA. INCLUDING AN ACCOUNT OF THE WATERS OF BALLSTON. Second Edition ...Enlarged. M@«— By VALENTINE SEAMAN, M. D. One of the Surgeons of the Nciv-Yorh HofpitaL " What dire neceflities on every hand, " Our art, our ftrength, our fortitude require ! " Of foes inteftine what a numerous band " Againft this little throb of life confpire ! " Yet Science can elude their fatal ire " Awhile, and cum alid> Heath's Wel'd dart, " Soothe the fharp pang, allay the fever's fire, " And brace the nerves once more, and cheer the heart; ■ ; And yet a few foft nights and balmy days impart." NEW- YORK: Printed and Sold by Collins & Perkins, No. 189 Pearl-ftrca - 1809. Diflria of New-York, /■. B< )E IT REMEMBERED that on the fixth day of July, in the thirty-fourth year of the Independence of the United States of Ame- rica, Collins and Perkins of the faid Diftridt, (L. S.) have depofited in this office the title of a book, the right whereof they claim as proprietors, in the words following, to wit : " A Dif- fertation on the Mineral Waters of Saratoga* Including an account of the Waters of Ballflon. Second Edition.....Enlarged. By Valentine Seaman, J\T. D, OIW of the Surgeons of the New-York Hofpital. " What dire neceflities on every hand u Our art, our ftrength, our fortitude require ! " .Of foes inteftine what a numerous band " Againft this little throb of life confpire ! " Yet Science can elude their fatal ire <{ Awhile, and turn aiide death's level'd dart, " Soothe the fharp pang, allay the fever's fire, " And brace the nerves once more, and cheer the heart, ;c And yet a few foft nights and balmy days impart." IN CONFORMITY to the Adfc of the Congrefs m the United States, entitled, " An A6t for the Encouragement of Learning, by fecuring the Copies of Maps, Charts, and Books, to the Auihura and Proprietors of fuch Copies, du- ring the times therein mentioned ;" and alfo an Aci, enti- tled, " An Act fupplementary to an Act, entitled, An Acl for the Encouragement of Learning, by fecuring the Copies of Maps, Charts, and Books, to the Authors and Proprie- tors of fuch Copies, during the times therein mentioned, and extending the Benefits thereof to the Arts of Defigning, En- graving, and Etching Hiftorical and other Prints." CHARLES CLINTON, Clerk of the Difri® of New-York. JOHN COAKLEY LETTSOM, M. & L. L. D. 8cc. IT is hoped that one whofe life has been fo confpicuoufly devoted to the diffufion of ufefol knowledge, in the promotion of human happi- nefs, and whofe beneficent exertions, unlimited by the boundaries of his own country, have been fo fenfibly extended to this, will not view with indifference, an attempt to invefti- gate the real nature of the moft ce- lebrated of its medicinal w 7 aters. Indeed the lively intereft he has ma- nifefted, as the naturalijf s compani- IV on> in refearches of this kind, is an almofl fure pledge of his approba- tion. Under thefe impreffions, the fol- lowing pages are, with due conside- ration, refpedtfully infcribed, by his friend, THE AUTHOR, New-Tort 9 6 Mo. 1809. INTRODUCTION. IT was a remark of the celebrated Bergman, that " In all ages good Phyficians, defirous of eftablifhing the falutary art, on a firm founda- tion, have confidered it incumbent on them, to fubmit to chemical ana- lysis, fuch waters as were famous for the cure of any difeafe." And indeed it is with juftice expected of every phyfician, that at leaft he will enquire into the virtues of fuch fubitances, as £hall offer themfelves to his obfervation, fiippofed to pof- fefs adtive medicinal qualities : for " The Lord hath created medicines A 2 out of the earth, and he that is wife will not abhor them." And as there ftill remain difeafes, which raife up their reproachful heads, in obflinate defiance of our art, it is more efpe- cially our duty to fearch out means for their deftrudlion : for it is not confident with our ideas of the goodness of the Deity, to fuppofe that he would have permitted the favourites of his creation to be af- flicfled with difeafes, without hav- ing formed remedies for their re- lief: but for them, as for relief from fpiritual evils, we muji feek, and we Jhall JincL What a glorious era will the pre- fent time exhibit in the hiftory of medicine ; for befide the many other late improvements in the Vll practice of phyflck, the fingle eftab- lifhment of Vaccination alone, has afforded more unblemifhed comfort to fuffering humanity, than any other difcovery ever made by the profeffion. For before that period, even where Inoculation for the Small Pox was, not only tolerated, but encouraged, as for inftance in this city, more than one tenth part of all the perfons that died, funk under the immediate effects of that mod loathfome of human mala- dies*. What a flimulus this is to * By a register kept by the Sexton super- intending the large cemetery in Broadway, it appears that during the fifteen years immedi- ately preceding the introduction of Vaccina- tion into New- York, of 5756 persons that were interred in that ground, 610 died with the Small Pox. via a perfeverance in our refearches ; — for who, twenty years ago, could have believed that the fufceptibility to Small Pox, which feemed an im- movable intailment upon human life, would have been fo eafily cor- rected. American phyficians, in particu- lar, from their being fituated in a country, with refpecl to medical re- fearches, almoft unexplored, fliould confider it doubly incumbent on them, to attend to its productions ; for befides the Ipecacuanha, the Snake Root, the Jalap, and many other ufeful remedies, America has alfo already furnifhed a Bark which has removed the fatality of that dif- eafe which in lefs than forty years deprived Britain of two of its mo- IX narchs*. And " Who knows but that at the foot of the Allegany Mountains, there blooms a flower that is an infallible cure for the e- pilepfy ? Perhaps on the Mononga- hela, or the Potomack, there may grow a root, that fhall fupply, by its tonic power, the invigorating effects of the favage or military life, in the cure of confumptions.f" — And why may there not fpring up a water, in fome neglected valley, whofe folvent quality may melt down the torturing ftone, or whofe penetrating influence may wafh a- * The intermittent fever, which is now con- sidered a trivial complaint, was arranged in the class of incurable diseases, till the discove- ry of the Peruvian Bark. James the First, and Oliver Cromwell, both died of this complaint. t Dr. Rush's concluding lecture. Xll when he confiders, that in this work I have adled in the dangerous and toilfome capacity of a pioneer, opening a way to the analyfis of thefe waters, whereby others may follow on, perhaps with more fuc- cefs, at leaft with lefs difficulty*. It has been my intention to ren- der this treatife as generally ufeful as poflible. I have, therefore, in addition to the prefent accurate terms of the new nomenclature, given the more common names of fuch fubftances as have occurred in * No one has heretofore attempted to ana- lyse these waters : all that has been done was a mere enquiry into the air discharged from them : see Dr. Mitchill's experiments, related in the American Museum, Vol. 4. This is the first attempt made to search into their real substance, to ascertain the ingredients of their composition. xai the courfe of the work : and have alfo, in other refpedls, employed as familiar a language as the nature of the fubjedl would admit of; and as in compoiitions of this kind, beau- ty of ftile is of lefs confequence than perfpicuity of expreffion, I doubt not but that the reader will excufe me, if he finds fentences which might have been more ele- gantly expreffed. Whether water, of itfelf confider- ed, is a fimple elementary fubftance, according to the opinion of the an- cients, or a compound, as believed by moft of the moderns (though perhaps well defer ving of attention) is not the bufinefs of this difTerta- tion to determine ; its views being confined, merely to difcover the na- B XIV ture of fueh mineral fubftances as are often diflblved in it, and to which many waters owe their par- ticular medicinal virtues. Such mineral waters have been noticed as far back as the time of Hippocrates. Pliny mentions certain of them, as poflefling medicinal properties ; but we do not find any account of a method to detedl their compolition, till about the middle of the feventeenth century, when Boyle fir ft obferved, that the infu- fion of vegetable blues, was an ac- curate teft for difcovering the pre- fence of uncombined acids or alka- lies, by becoming red with the for- mer, and green with the latter. He afterwards found out many other fubftances for the more full exami- nation of waters. XV During the time that Boyle was employed in thefe refearches, Duclos was bufy in the analyfis of the wa- ters of France, and made feveral improvements, by the addition of galls, and the tin&ure of turnfol, to our flock of reagents. Hierne, Valerius^ Boulduc^ and many other eminent chemifts, continued to ren- der this branch of fcience more per- f e a. In the beginning of the prefent century, Hoffman^ followed by Springsfeld and Venel, paid particu- lar attention to what they called the mineral fpirit of waters, and which fince, by Dr. Prieflly, has been pro- ved to be the carbonic acid gas, or fixed air, as he termed it. The mode of analyfing waters has XVI been continually improving, fince the firft experiments of Boyle , till at length the celebrated Bergman has given the finifliing flroke of its pre- fent perfection. In examining thefe waters, I have proceeded firft by reagents, to afcer- tain the different ingredients in their compofition ; for notwith- flanding fome authors confider thefe as mere amufing experiments, yet I rather fuppofe them very ufeful for that purpofe, particularly when em- ployed in the extenfive way that has been done in this enquiry ; and I fancy every intelligent reader will agree with me, upon a candid pe- rufal of them. It muft be acknow- ledged that we are thereby only en- abled to difcover the different in- XV11 gredients of mineral waters, but not the proportion of each. It be- came, therefore, neceffary to apply to diftillation, to obtain the propor- tions of their aerial, and to evapo- ration and chryftalization, that of their fixed principles. In the prefent edition, belides giv- ing a plan of the furrounding coun- try, and the relative fituation of the Springs at Saratoga and Ballfton, as taken from De Witt's Map of the State, I have alfo exhibited a view of the R ock Spring at Saratoga; ho- ping thereby to aflift in giving it a proper ftation among the extraordi- nary productions of our country. The more we reflecft upon it, the more we muft be convinced of the important place this rock ought to B 2 XV111 hold among the wonderful works of nature. Had it flood upon the bor- ders of the Lago cfagnano, the noted Grotto del cani % (which burdens al- mod every book which treats upon the carbonic acid gas, fince the pe- culiar properties of that air has been known), would have remained an obfcure cleft in a rock, and if no- ticed at all, would never have been heard of beyond the environs of * The carbonic acid gas in this cavern, not- withstanding its being stated by some as form- ing a stratum about knee high, and by others as rising a foot from the surface of the floor, does not in fact, or at lea?t did not when I vi- sited it in 1803, rise above a few inches from the ground ; even so as to make it necessary for the person who attended to shew the expe- riments, to seek out some hollow place to ex- tinguish the torch used upon the occasion, and also for him to force down the nose of his dog verv near the ground, to exhibit its noxious XIX Naples ; while this fountain, in its place, would have been defervedly celebrated in ftory, and fpread upon canvafs, to the admiration of the world, as one of its greatefl curio- lities. As an objecfl of admiration the Grotto del cani can no more bear a comparifon with the Rock at Sara- toga, than the Water Falls of Tivoli could with the Cataract of Niaga- effects upon animal life : nor indeed did the natural situation of the place at that time, ad- mit of its being ^otherwise, for the bottom of it, if not descending from its inner extremity towards its mouth, was at most not more than upon a level, and from its mouth outwards the adjoining ground was very considerably de- scending. Hence we can hardly conceive but that this air, which is about 50 per cent heavi- er than the air of the atmosphere, would ne- cessarily flow out, before it could rise to such a height. XX ra, or the Lake of Avernus (the Tartarus of Virgil) with the ex- panded waters of Ontario. As the burning mountains of Ita- ly command the aftonifhment of mankind, fo the cold boiling Springs of Saratoga ought, I had almofl faid, to demand their adoration. How vaftly different, yet how equally curious are thefe two fubjedts ! while the magnitude of Vefuvius defies any comparifon with the di- minitive fize of the Rock of Sarato- ga, flill the compadl petrified hard- nefs of the latter, equally abhors comparifon with the cineritious crumbling texture of the former : while that occafionally burfts forth in furious flames and torrents of fiery lava, to the terror and oftentimes to XXI the deJlruElion of the furrounding neighbourhood, and requires a blind confidence, in a fuppofed pro- tecting faint, to preferve the inhabi- tants from incejfant apprehenfion, this conjiantly boils up a refrefhing fountain, attended as it were by Hygea herfelf, difpenfing health and binefs to all around. MINERAL WATERS OF SARATOGA, &c. Topographical Description of the Coun- try y and situation of the several Springs. JL HESE Springs are fituated on the fide of a valley, which lies about twelve miles weft of the confluence of Fifh creek with the Hudfon or North river, in the county of Sara- toga and ftate of New-York, and about two hundred miles above that city. This valley, at leafl the part of it where the Springs rife, runs a northerly and foutherly courfe, and appears to have been formed by a 24 The Mineral Waters of branch of the Kayadaroforas river, which flows through the middle of it, and empties itfelf into Owl pond, whence it efFedls a junction with the main ftream, at a fmall diflance from where that terminates in the Saratoga Lake. The high ground that forms the wefterly bank of the valley, whence the waters of thefe fprings, which are fituated at its foot, appears to have been derived, is compofed al- moft entirely of calcarious rocks, whofe furface however, is moftly overfpread with a fand and clayey foil, and covered with tall pines and oaks. There are feveral deep fub- terraneous caverns obferved in it, which open but a fmall diftance from where the declivity commen- Saratoga and Ballston. 25 ces. The bank on the eafterly fide appears almoft entirely fand, with not the leaft veftige of calcareous earth, and is a perfedl pine plain. The caufe of this fudden change of foil, and alfo of the rivers mak- ing its way, at this particular junc- ture, I leave to the fpeculation of the naturalift to determine : a mere knowledge of their exiltence and fituation being all that is neceffary, either as to their affording us an a£- fiftant means for afcertaining the nature of the Mineral Waters in their neighbourhood, or as enabling us to account for the prefence of in- gredients found in them. About four miles weft of thefe fprings, I am informed there is a flrong fcent- ed fulphureous fpring. c 26 The Mineral Waters of The fprings are eight or ten in number, and all are within the fpace of about half a mile. THE ROCK SPRING has particularly attradled the attention of the curious, and is moftly drank of by valetudinarians. It rifes about midway between the others, and is entirely furrounded by a rock of a conical fhape, which is about five feet high, and nine feet in diameter at the bafe ; it has a cir- cular hole in its apex, of near ten inches acrofs, which is the opening of its inner cavity where the water, enlivened by continued ftreams of air-bubbles pafling through it, rifes to within about two feet of its top. This cavity, like the outfide of the rock, enlarges as it defcends. The furface of this rock is of an afh colour, and appears compad; and Saratoga and Ballston. 27 polifhed* ; it has a crack in one fide, which is fuppofed to defcend internally, and form fome vent be- low the furface of the ground, by which the water makes its way out, as it has not been known to over- flow for feveral years paft.f * The general substance of this rock is very different from that of its surface, for instead of being compact and solid, it is of an open and spongv texture. t This circumstance would seem, at first sight, to be a matter of regret ; but when it is considered that we have thereby in the upper chamber, a well contrived reservoir for the collection and preservation of the gas that is constantly accumulating therein, it becomes questionable whether it ought not rather to be considered as a fortunate occurrence, for while the water is not thereby put out of reach, its surface is constantly protected from coming in contact w T ith the atmospheric air, which might deprive it of a portion of its sparkling brisk- ness: it at the same time furnishes the chemi- cal operator with a considerable quantity of the 28 The Mineral Waters of This fra&ure in the rock, is be- lieved to have been produced by the fall of a tree acrofs it ; and the re- mains of the upper part of one which lies in the marfli below, and whofe body is directed immediately towards it, renders this opinion ve- ry probable, fince its fize and filia- tion prove that it muft have flood on the oppofite fide of the fpring. Indeed I am informed by a man of that country, that he very well re- colledls when the tree flood there, and that then the water overflowed pure unmixed air, ready collected to his hand, for making such experiments as he may wish, either to ascertain its nature or to demonstrate its qualities. The specific gravity of this air being greater than that of the- atmosphere, pre- vents it from being readily dislodged from its apartment. Saratoga and Ballston, 29 the rock. Another perfon inform- ed me, that he knew it to overflow in the time of the late revolutionary war. All thefe waters naturally depofit a petrifa6live matter over where they flow, thereby forming to themfelves a barrier againft the in- trufion of foreign fub fiances. How the Rock Spring, in particular, has furrounded itfelf by fuch a regular formed conical mafs, is a fubjedl of curious inveftigation. For my own part, I am difpofed to conjecture, that the main body of it was origi- nally formed below the furface of the earth, by the calcareous fub- ftance which is continually fepara- ting from the water, (in confe- quence of the efcape of the fupera- c 2 30 The Mineral Waters of bundant carbonic acid) insinuating itfelf among, and in fome degree uniting with, the furrounding hete- rogeneous earthy matters : whence the reafon of its fpongy texture. This hardened mafs then refitting the floods of rain, which wafhing down the bank, and gradually car- rying off the loofer earth from a- round it, it neceflarily would, in time, become above the level of the adjacent ground, the natural Situa- tion of this fpring rendering it of more difficult accefs than the others, would fecure it from being tram- pled down by fuch animals as may have reforted there for drink. Since its expofure to the air, perhaps du- ring the courfe of ages, the water has been permitted unmoleftedly to Saratoga and Ballstoji. 31 precipitate particles upon particles of the ftony matter upon its furface, till finally it has become covered with that compacl, folid fubflance, which adds fo much to the beauty of its prefent appearance. . THE BATHING SPRING. This has obtained its name from its furnifhing the waters that are continually conveyed from it into the bathing-tub, which is in a log inclofure juft below it, in the marfli. It is fituated a fmall diftance from the Rock Spring, and has afforded a much greater quantity of the pe- trifactive depofition ; fo much in- deed, as to have formed an irregular rock around itfelf, of upwards of 20 32 The Mineral Waters of feet in diameter ; but by being more eafily come at, its tender layers have been continually trodden down, as they formed, before it could affiime any regular fhape. TheJIony matter of thefe Springs, by calcination, formed quicklime. A piece of it put into fulphuric (vitriolic) acid, caufed a great efFer- vefcence, and formed a felenites, or plaifler of paris, and alfo a fmall por- tion of alum, as was proved by the folution depofiting a cloudy fedi- ment, on paffing volatile alkaline gas through it. This folution alfo con- tained the fulphate of iron (copperas) whence it affumed a beautiful blue colour, bv the addition of lime water faturated with Prujfian blue, and be- came purple by dropping into it the Saratoga arid Ballston. 33 tinclure of galls. Thefe experiments lead to the conclufion that the petri- faction muft be compofed of an argillo calcareous earth and iron*. To this laft is owing the reddifh co- lour with which great part of it is tinged. Having fettled thefe prelimina- ries, we proceed more particularly to enquire into the NATURE OF THE WATERS. I. Of their Phyjical Properties. i ft. Thefe waters, in general, ap- pear nearly tranfparent, yet none of * The circumstance of this petrifaction con- taining argillaceous earth, supports in some de- gree the conjecture respecting the original for- mation of the conical Rock, since this earth could not have been derived from the water it- self, as that does not appear to contain any in its composition, 34 The Mineral Waters of them perfectly fo, excepting that which rifes up in a barrel, which the neighbours have fixed for the purpofe of collecting it, and is call- ed the Barrel Spring. They are co- lourlefs) and emit a great quantity of air by agitation ; even by {landing {till, in an open veffel, it almoft im- mediately forms bubbles around its infide, which foon rife up and are difcharged. The veffel ufed to dip the water out of the rock, and alfb the bathing tub, foon gather an ochery cruji upon their inner furfa- ces. Wherever thefe waters ftag- nate, around the fprings, befides de- politing the ftony matter before mentioned, their furface alfo foon becomes overfpread with an iri<- Saratoga and Ballston. S5 defcent pellicle of a metallic fplen- dour, reflecting variegated colours. 2d. They diffufe a fubtle pene- trating odour, which is molt parti- cularly experienced by breathing in the orifice of the rock. 3d. When drank, their firft im- preflion on the palate, is agreeably acidulous^ fucceeded by a naufeous /aline taite ; they afterwards give up accfcent emulations •, like fermented liquors, and which are no ways un- pleafant. 4th. The hydrometer ftands at the fame height in thefe, as in fnow- water. 5th. Notwithftanding the dif- charge of air, from thefe waters makes them appear to be in a con- tinued ebullition, yet they are cold. 36 The Mineral Waters of Their temperature, however, is not the fame in all the fprings, but feems to diminifh in proportion to their brilknefs. Thus the Bathing Spring and the Barrel, each of which difcharges about twenty gallons in an hour, lowered Farenheit's ther- mometer from 72 , the heat of the atmofphere, to 52 while in the others, which are much flower, it flood at 56° and 58°,but in the Rock water it remained at 67 . 6th. By the application of a gen- tle beat, thefe waters difcharge a great quantity of air in bubbles : it is upon this property that their ufe in railing bread depends, and for which purpofe they are carried a- way in confiderable quantities dai- ly, even fometimes to eight or ten Saratoga and Ballston. 37 miles diftance ; all that is neceflary being merely to make the dough, with flour and this water alone, and it is immediately ready to be put into the oven. II. Experiments upon the Air. i ft. A lighted candle let down in the crater of the rock, was immediately cxtingnijhed^ both blaze and wick, before it came within a foot of the furface of the water. The air ob- tained by agitating the water of this, as well as of the other fprings, was equally incapable of fupporting combuftion, as was alfo that collect- ed from the bubbles, that were con- tinually difcharging from the dif- ferent fprings. 2d. A chicken being immerfed in this air, expired in three minutes. D 38 The Mineral Waters of A kitten confined in it for one and a half minutes, appeared very flaccid and almoft dead ; yet, on being brought out, into the atmofpheric air, its fleeting life was foon recall- ed, through the medium of violent convulfions. Being again put into the noxious gas, in fourteen mi- nutes it was irrecoverably dead. 3d. The air being made to pafs through lime-water, immediately rendered it very turbid. 4th. A diluted tinclure of turnfol was tinged red by having a portion of this air pafled through it. From the phyfical qualities men- tioned, and from the above experi- ments, we may fafely conclude, that this air is the true carbonic acid gas , the fpiritus mineralis of Hoffman, Saratoga and Ballston. 39 thegasjilve/lre of Van Helmont,the aerial acid of Bergman, the Jixed air of Prieftley, Cavendifti and Black, the cretaceous acid of Fourcroy, and what is generally known with mi- ners by the name of choak damp: it is flmilar to the noxious gas which rifes up to the height of fome inches in the famous grotto del cani in Ita- ly. This cave having received its name from its fatality to dogs, they from carrying their heads below the furface of this ftratum of air, being the animals which are gene- rally fubmitted to experiments, to fatisfy travellers of its deleterious effects. It is this air which is fo plenti- fully given out during the fpiritu- ous fermentation, and is what gives 40 The Mineral Waters of that brifknefs to porter, champagne and other fermented liquors. Be- ing united with the vegetable alka- li, it forms the common potafh of commerce. Hence the reafon why our good houfewives are enabled, any time, at half an hour's warning, to furnifh us with a well raifed cake merely by mixing up the flour with a lbiution of potaih and four milk. Here the acid of the milk, from a greater attraction, joins itfelf to the alkali, while the carbonic acid taking its aerial form upon being fet at li- berty, and affifted by the expanfive power of heat, penetrates and puffs up every particle of the dough. It is this air alfo which conftitutes the difference between quick-lime and chalk or limeflone. Its difcharge is the effecft of their calcination, Saratoga and Ballston. 41 III. The effecls of Re-agents upon the Waters. i ft. The Rock water had a little of the tinclure of tarnfol dropped in- to it, which immediately gave it a reddijh tinge. 2d. The infufion of the blue petals of our common larkfpur* was not changed by it. 3d. In lime-water , it inftantly in- duced a milky turbidnefs^ followed by a depofition of a white powder. 4th. Tinclure of galls rendered it purple^. * The infusion of blue larkspur I have found to be a most accurate test for discover- ing the presence of the smallest quantity of al- kalies and of fixed acids, but not the carbonic. ■\ It has been observed, that notwithstanding this water mixes with gin, without discoloura- tion, yet it will not make grog j for immediate- D 2 42 The Mineral Waters of 5th. Pruffiate of lime produced no change in it. 6th. A folution of potofh (cauftic vegetable alkali) produced a turbid- ?iefs in it. 7th. It was alfo made turbid by carbonate of potafh (aerated vegeta- ble alkali). 8th. Ammonia (cauftic volatile al- kali) forms a cloudinefs in it, yield- ing a white precipitate. 9th. Sulphuric acid (oil of vitriol) dropped into the water, caufed a great ejfervefcence^ and a little tur- bidnefs. ly upon pouring in the spirits, it becomes blackish. This, though unaccountable to ma- ny, is no more than what every chemist would expect, when he considers that from the oak casks in which spirits are kept, it generally be- comes a true tincture, of a vegetable astringent, Saratoga and Ballston. 4S 10th. After fulphuric acid had been dropped in the water, it then became blue by Prujfian lime-water. nth. Nitrate of filver dropped into the water, formed an immedi- ate copious white curdled precipitate ; this, as alfo the water itfelf, foon at fumed a dirty bluiJJj colour. 1 2 th. Nitrate of mercury produced a copious yellowifh precipitate. 13th. Acid of fugar occafioned a cloudinefs which foon fettled down in a white precipitate. 14th. Acetite of lead produced a copious white, but not granulated, precipitate. Molt of thefe experiments were frequently repeated, and with limi- lar refults. The waters of the other fprings 44 The Mineral Waters of exhibited the fame appearances, with the above re-agents, as the Rock water, excepting that of the Bathing Spring, and of the Barrel, both of which ftiewed a deeper pur- ple tinge with tin6ture of galls. By boiling the water, it difcharged a great quantity of air , and formed a pellicle upon its furface, and depojited a white powder. Afterwards it had not that brifk acidulous tafte, as be- fore, but was extremely naufeous : it was not reddened by tindlure of turnfol, nor rendered purple by tindture of galls : with infulion of larkfpur it became green : it ftill precipitated lime-water^ though not fo plentifully as before, and alfo effer- vefced (lightly, with fulphuric acid, but was not made turbid thereby : Saratoga and Ballston. 45 it changed the yellow matter oftur- merick to an orange redox brick colour. Acid of fugar did not induce any turbidnefs in it ; it formed a light cloud upon (landing a little time with the caiiflic vegetable alkali, but was not altered by the aerated vege- table alkali (carbonate of potafh). From the foregoing experiments, I conclude that thefe waters contain , i ft. An uncombined acid, whereby they become red by tincture of turnfol, and that this cannot be a fixed acid, fince it does not redden infufion cf larkfpur, and is evapo- rated by boiling ; for afterwards the water does not change the tinc- ture of turnfol, therefore it mud be the carbonic acid gas, (fixed air) the fame as has been heretofore proved 46 The Mineral Waters of to be continually difcharging from them, in large quantities. It is from the prefence of this, that lime-water becomes fo very turbid, for with lime, unlefs by a fuperfaturation, it forms a compound infoluble in wa- ter. 2d. Iron. — Hence it takes a pur- ple tinge, with tindlure of galls ; and alfo, when previoufly joined with fulphuric acid, becomes blue^ with pruffiate of lime (Pruffian lime water). The iron is not kept in fo- lution by the fulphuric acid, or it would have become blue by this teft before the acid was added to it, but by the carbonic acid. Hence after being boiled, this water is not difcoloured by tindlure of galls. 3d. A quantity of lime held in fo- Saratoga and JSallston. 47 lution by a fuperfaturation with carbonic acid; for notwith (landing lime, as before obferved, is render- ed infoluble by uniting with this acid, yet it is otherwife when fuper- faturated therewith ; for then it is, to the contrary, much more foluble. Hence the caufe of a precipitation^ by the pure potalh and by the am- monia. They, from their affinity to the acid, deprive the lime of its fuperabundance, and permit it to fall down in a white powder. The fulphuric acid, on the contrary, at- tracts the lime, and forms a gypfe- ous depofition, while the carbonic acid flies off in a great effervefcence. The acid of fugar, alfo evinces the prefence of lime, by uniting and forming an infoluble compound 48 The Mineral Waters of with it. Thefe tefts did not exhibit the fame appearances with the water after ebullition. Hence the pellicle and deposition, formed during that procefs, I take to be calcareous earth and iron. 4th. A muriatic acid. — Hence with nitrated filver it forms a fudden, cafeous precipitate, and alfo a preci- pitate with nitrated mercury ; this laft, on being fublimed, afforded corrofive fublimate. 5th. A neutral fait. Since it is evident from the two laft mention- ed experiments, that thefe waters contain a marine acid, and by fome of the previous ones, that this does not exift in them in a feparate ftate, it muft therefore be united either with an earth or an alkali ; and as * Saratoga and Ballston. 49 a carbonated alkali will be fliewn to be prefent in them, it is evident that it mud be joined with the latter, fince alkalies have a greater attrac- tion for acids than earths have. 6 th. A carb 07i cited alkali^ where- by, after the water has been boiled^ it rendered the infufion of larkfpur green, and eftervefced with vitriolic acid : hence alfo the caufe why lime-water was flill preripitated by it ; the carbonic acid qui k die alkali to unite with its more attracting lime, formed therewith, as above mentioned, an infoluble compound. And that the phenomena were pro- duced, at leaft in part by carbonate of an alkali, and not by the carbo- nate of magnefia alone, is evident from its changing the yellow colour t 50 The Mineral Waters of of turmerick to that of a brick red, which could only have been effect- ed by the prefence of an alkali. The reafon why the water did not change the infufion of larkfpur, be- fore it was boiled, muft have been owing to the alkali's being fuperfa- turated with the carbonic acid ; in which cafe, (as I proved by an expe- riment inftituted for that purpofe) it may exift in confiderable quanti- ty in water, without changing ve- getable blues. 7th. A flight impregnation of ful- phur, thereby darkening the nitra- ted filver. This is what might be reafonably expected, as within about four miles there is a ftrong fcented fulphureous fpring. The laft mentioned experiment, Saratoga and Bailston. 51 on the waters, previous to ebullition (fee p. 43) proves, by the precipi- tates not appearing granulated, that fulphuric acid does not exift in the waters, either in a fimple or combi- ned ftate. The prefence of a carbonated alka- li in thefe waters, clearly proves that they cannot contain any earthy or metallic falts other than carbonates, fince the alkali, from its fuperior at- traction to acids, would neceffarily prevent their formation. From the above effects of re-agents, it appears that the waters contain Carbonic Acid, Carbonate of Iron, Lime Superfaturated with Carbo- nic Acid, Muriatic Salt, 52 The Mineral Waters of Carbonated Alkali, *3 Carbonated Magnefia, and a Sulphureous Impregnation. The proportion of each of the a- bove ingredients, and the nature of t;he bafe of the neutral fait, and the fpecies of the carbonated alkali yet remained unknown, I therefore pro- ceeded by the more tedious procefles of Diftillation, Evaporation, and Cryftallization, to afcertain thefe points. IV. Diftillation. From the experiments of Berg- man and Henry, it appears that wa- ter is capable of abforbing about equal its bulk of carbonic acid gas, at the temperature of 55°, and pro- portionably lefs as its temperature is increafed. Now, as the bubbles Saratoga and Balkton. 53 of this air are continually palling through the waters under examina- tion, it is clear that they mud be fully faturated with it ; and as they are of the temperature at which wa- ter will retain about equal its bulk, we of courfe conclude, that they contain that proportion. The fol- lowing experiment tends to confirm that opinion. By means of a Florence flafk, with a fyphon properly affixed to it, and the application of heat, I colledled, from a given quantity of this water, upwards of its bulk of aerial fluid, the greater part of which I take to be the above men- tioned acid j the reft perhaps, part- ly azote (atmofpheric mephitis), and partly oxygen gas (vital air). E 2 54 The Mineral Waters of That the water contains this laft, is proved by its precipitating an oche- ry fubflance^ after having had fome fulphate of iron (green vitriol) dif- folved in it, in a well corked vial. V. Evaporation. By evaporating ten pounds of the water of the Rock, in glafs veflels, by the heat of a water bath, I ob- tained an afh -coloured refidue, which when dried weighed 403 grains. This refiduum was put in- to four times its weight of fpirits of wine, which after (landing a consi- derable time, being frequently agi- tated, was filtered and dried, and was found to have loft about 17 grains, which proved to be common fait ; for by evaporating the fpirits, I obtained it in regular cubic cryftals* Saratoga and Balkton* 55 This circumftance of fpirits of wine difTolving a portion of marine fait, I take to be owing to its not be- ing fo highly rectified as it ought to have been, for if perfectly pure it would only have taken up muriate of lime, muriate of magnefia, ni- trate of lime, nitrate of magnefiai and muriate of terra ponderofa ; but when fomewhat diluted, it will, befides thefe falts, alfo take up others. However, as by evapora- tion I obtained nothing but cubic cryflals,Iagain conclude, pofitively, what in fadl was before proved by re-agents, that there are none of the above mentioned earthy falts in thefe waters. I now immerfed the refiduum in 8 oz. of cold water, which after re- 5$ The Mineral Waters of maining feveral hours, being fre- quently agitated, was filtered. The infoluble part, when dried and weighed, was found to have loft 182 grains. This watery folution, by turning the infufion of larkfpur green, appears to contain an alkali uncombined with any of the fixed acids. This folution not changing the colour of the infufion of larkfpur to a red, renders it evident that the muriatic acid before ihewn to be contained in thefe waters, cannot be in an uncombined ftate : and in- deed the prefence of a carbonated alkali in them, proves that it mufl be in combination with a fait of that kind ; for having a greater at- traction for them than the carbonic acid has, it would neceflarily pre- Saratoga and Balhton. 57 vent the exiftence of a carbonate, unlefs it was itfelf previoufly fatu- rated. We may therefore now again conclude that the waters contain a muriatic neutral fait. This folution of a muriatic neu- tral fait and an alkali, I fubmitted to the heat of the fun; whereby, after great part of the water was evapo- rated, fome cubic cryftals appear- ed to form upon its furface, but which were foon difturbed by irre- gular faline concretions. Having afcertained the prefence of a muriatic neutral fait, and an al- kali, but not knowing decidedly, either the fpecies of the alkali, or the bafe of the neutral fait, I made a faturated folution of this mixed fait, and added thereto acid of tar- 58 The Mineral Waters of tar, and no precipitation taking place, I concluded that the alkali could not be of the vegetable kind, or it would have fallen down in the form of cream of tartar : therefore the aerated alkali muft be the mine- ral alkali, (carbonated fbda) and the bafe of the neutral muft be the fame, which with its acid, forms our common fea fait (muriate of foda). To find the proportion of the ma- rine fait and the foda, I difTolved the mixed fait in water, and added diftilled vinegar thereto, until I brought it to the exadl point of fa- turation. I then faturated an equal quantity of diftilled vinegar, with carbonate of foda, for which purpofe it required 26 grains ; whence it appears that ten pounds of this mi- Saratoga and Bathton. 59 neral water contain 26 grains of carbonate of foda ; the remainder, 156 grains, mud be muriate of fo- da, which added to the 1 7 grains diflblved in the fpirits of wine, makes 173 grains, the amount con- tained in that quantity of the water* The remaining 204 grains I ex- pofed to the fun, for feveral weeks, moiftening it frequently with rain water. This was done in order to ruft the iron, fo as to make it folu- ble in diitilled vinegar, in which this refidue was afterwards digefted and filtered. The filtered liquor was then evaporated, and what was left was re-diffolved in fulphuric acid, with which it formed fulphate of lime (gypfum) but no bitter fait. Hence, as there were but about 1 2 60 The Mineral Waters of or 14 grains remaining on the filter, it appears that ten pounds of this water contain 190 grains of lime, but very little if any magnefia. The fubftance remaining on the filter, by being diflblved in vitriolic acid,afforded 81-2 grains of iron, precipitated in form of Pruflian blue, by the Pruffian lime-water. It appears from a review of thefe experiments, that ten pounds of this water muft contain, Carbonic Acid (fixed air) which when extricated inform of gas,mea- fures about 200 cubic inches, Carbonate of Soda 26 grso Muriate of Soda (feafalt) 173 Super-Carbonated Lime, 190 Carbonate of Iron, 8.5. Saratoga and Ballston. 61 Befides the Mineral Waters that have been already noticed, there are others in the county of Saratoga. About three miles below the junc- tion of Fifli creek with the North river, and about two miles weft of the latter, in a hollow immediately back of the dwelling houfe of Wil- liam Barker^ are fevcral Mineral Spring s, the waters of which, both by their fenfible qualities, and by the operation of re-agents, appear to be very fimilar to thofe hereto- fore mentioned. They do not, how- ever, depofit the ftony matter, nor do they in other refpe&s, appear to be fo ftrongly impregnated with Mineral fubftances. They are fituated in a clayey foil, with no appearance of lime-ftone in F 62 The Mineral Waters of their neighbourhood. The land is covered with beach and oak trees. The air which bubbles up in thefe fprings, appears to be the fame acid as is difcharged from the other iprings: it equally extinguifhes flame . and renders lime-water turbid, &c. Aquatic animals cannot fupport life when fubmerfed in this water. A fiflo in two and a half minutes died in it. Iron appears to exift in thefe wa- ters, by their becoming tinged, though flightly, with tinclure of galls ; and it muft be held in folu- tion by means of the carbonic acid 5 as they were not changed by the tincture after they had been boiled. Lime rendered foluble by a fuper- abundance of carbonic acid, was Saratoga and Balls ton. 66 detected in thefe, by the fame means as were ufed with the other waters. They probably contain a carbonat- ed alkali, for after being boiled, they (till effervefced with fulphuric arid* Muriatic acid is proved to exift in them, by the nitrated friver and ni- trated mercury , and it muft be in combination ; thereby forming a neutral fait) whofe bafe, though not fully afcertained, is prefumed from its tafte, and the great fimilarity there is between thefe and the other waters, to be of the mineral kind; therefore the neutral I believe to be fea fait. Beiides thefe afcefcent fprings, there is another in the fame hollow, about a flone's throw diftance from them, which is entirely of a differ- tj4 The Mineral Waters of ent nature, and from its fmelling like the wafhings of a gun-barrel, has obtained the name of Gunpow- der Spring. The water is tranfpa- rent ; its temperature 58 ; it fmells and tqjles like fidphur, or rather hepar fulphuris. By boiling, it lofes both its difagreeable fmell and tafte. The air difcharged from it by boiling, being made to pafs through lime-water, produced no turbidnefs : hence it contains no free carbonic acid. This water is not difcoloured either by tincture of galls or Prujfian lime- water. With nitrated mercury it forms a precipitate. With nitrated filver it alfo forms a precipitate ; which, as well as the Saratoga mid Ballston. 65 water, directly affumes a dark pur- pli/h brown colour. This precipitate is fufpedled to arife from a marine acid, and the dark colour from a hepatic or fulphureous gas. Sulphuric acid produces an effer- vefcence. This muft be owing to the prefence of a carbonated alkali. It alfo rendered lime-water turbid: this might be from the fame caufe. Hence the above-mentioned muria- tic acid muft have been in combina- tion in form of a neutral fait. F2 BALLSTON. jr LACES, like perfons, after hav- ing attained a certain degree of cele- brity, frequently undergo a change in their names. Thus the modeft fontaine de belle eau has become the admired Fontainbleau^ and the once obfcure town of Brighthelmeftone has become the brilliant Brighton. So alfo Ballftown, which afterwards to diftinguifh it from a place of the 68 The Mineral Waters of fame name in the Diftridl of Maine, was called Balltown, has finally, in feeming fubferviency to the ton of the times, affumed the more fafhi- onable title of Ballfton. THE BALLSTON SPRINGS arife about feven miles to the fouth- ward of the Rock Spring at Sarato- ga, and like that, they are fituated in a valley, through which alfo runs a branch of the Kayadaroforas. The foil nearly adjacent to the Spring, is poor and fandy. Upon digging down into it, Dr. Vandervoort fays, it becomes intermixed with clay and with fome ferruginous particles appearing like the ruft of iron ; and in fome places he obferves, large quantities of bog ore are found : one bed in particular, he notices, a Saratoga and Ballston. 6 9 little to the weftward, and almofl adjoining one of the Springs. The produce of the foil in the im- mediate vicinity of the Springs, is chiefly pines, fcrub oaks, and fome chefnut, together with ferns and mulleins. The temperature of the water of thefe Springs in the fummer, varies from 50 to 58 ', about the fame as the medium temperature of the wa- ters of Saratoga. Thefe waters have air bubbles conftantly pafling up through them ; they fparkle in the glafs, and when drank give an aci- dulous, followed by a f aline tajle^ though not fo naufeous as thofe of Saratoga. They affedt the nofe and palate with a pungent penetrating fliarpnefs, like mead or lively bot- 70 The Mineral Waters of tied cyder, and oftentimes a draught of them is fucceeded by fimilar eradiations. From experiments made upon it, this air appears equal- ly, with that from the waters of the other fprings, to be incapable of fup- porting combuflion or animal life. From the effedls of re-agents and from evaporating this water, and fe- parating the different parts of the refiduum, it appears to be very fi- milar to the water of the Rock Spring, Dr. Vandervoort found it to contain, Muriate of Soda, Carbonate of Lime, Carbonate of Iron, and Carbonic Acid. This account of Dr. Vandervoort's experiments was publiihed in 1795, Saratoga and Ballston. 71 about two years after the publica- tion of the firft edition of my Dif- fertation on the Waters of Saratoga. In the year 1808 there appeared in feveral of our newfpapers, an ac- count of the analyfis of a bottle of the Ballfton water, faid to have been made in France. This account was afterwards treafured up in the form of an article in the Medical Repofi- tory of New- York, and again re- published in the Monthly Antho- logy of Boflon, ftating it, at the fame time, as a public benefit, &c. From this account having thus ob- tained a place in fuch refpedtable publications, and differing as it does, in feveral refpedls, from the analyfis before mentioned, juftice to Dr. Vandervoort and duty to the 72 The Mineral Waters of community require, that we give it fome attention, and that the waters fhould be more particularly exam- ined ; not merely to fettle the dif- ference between the two experi- menters, but for the more important purpofe of afcertaiiiing what, in truth, are their real contents ; efpe- cially as they now have got into fuch general ufe, and are fo fre- quently prefcribed by phyficians. Silence, upon this occafion, would feem to give a fandlion to what it is prefumed the following inveftiga- tion will prove to be highly erro- neous in that account, which is fta- ted to be an accurate analyfis, pub- lilhed under the impofing authority of a perfon, who (though his name is not mentioned) is faid to be one Saratoga and Ballston. 73 of the mod celebrated chemifts of France. The account fays, that a bottle of the water, after having been tranfported to France, contain- ed three times its bulk of carbonic acid gas. Whereas, by a well diredted experiment, Dr. Vandervoort could obtain at moft, not above a third part of that quantity from it, and that when frefh from the fountain. This experiment, related at full length, ought of itfelf to fatisfy us as to his conclufions. But when in addition thereto, we confider that neither Bergman nor Henry could caufe water, at the temperature of the Ballfton Waters, to abforb more than about that proportion, we can no longer doubt that the French ac- count is greatly exaggerated, and in- G 74 The Mineral Waters of ftead of the waters containing tre- ble their quantity, that they have not more than equal their bulk of car- bonic acid gas fixed in their compo- fition. Further, the two accounts differ in refpe(5l to the ftate of the calcari- ous matter held in folution ; for while the French chemift afferts that they contain a quantity of the muriate of lime, Dr. Vandervoort makes no mention of that, as a part of their compofition. To deter- mine this point, having procured fome of the Ballfton water, I evapo- rated it to one fourth part of its ori- ginal quantity, decanted and filter- ed the liquid, and dropped into it a folution of oxalic acid, which pro- duced a flight effervefcence^ but no Saratoga and Ballston* 75 doudinefs or precipitation took place ; whence it is evident that no muriate of lime ex i fled in it. To afcertain flill further what other matters were contained in this water, the evaporated portion of it was fubmitted to the follow- ing experiments, viz. i . A paper flained blue with the petals of the common iris, was changed to a green by being im- merfed in it. 2. Strips of the fame paper, pre- vioufly reddened by a very diluted nitric acid, were by it, firft gradual- ly reftored to their original blue, and then alfo became green. 3. Lime-water rendered it milky ^ and depofited a copious precipitate. 76 The Mineral Waters of 4. Nitric acid dropped into it, produced a difcharge of air bubbles. 5. A folution of potafh produced a flight turbidnefs in it, which by {landing, formed a permanent thick cloud near its furface. This after- wards was diflblved with efFervef- cence, by the addition of a few drops of the fulphuric acid, and the liquid refumed its former trans- parency. 6. The muriate of lime rendered it turbid^ and let fall a denfe and apparently heavy precipitate. 7. Carbonate offoda exhibited no evident effecl^ upon being mixed with it. 8. The carbonate of ammonia ad- ded to it, did not effect its tranfpa- rency. Saratoga and Balls ton. 77 9. This mixture of it with carbo- nate of ammonia^ immediately loft its tranfparency, became turbid and let fall a precipitate by the addition of the phofphate offoda. 1 o. The yellow colouring matter of turmerick was changed to a brick red by being mixed with it. All thefe phenomena, as well as the difcharge of air by the addition of the oxalic acid, in the firft afore- faid experiment, are eafily explain- able, upon the prefumption of the prefence of the carbonate of magne- fia and the carbonate offoda ; and as they feem inexplicable upon any other principle, in my opinion they fully eftablifh the fact of thefe fub- ftances being a part of the compo- fition of thefe waters. If then thefe G 2 78 The Mineral Waters of waters contain the carbonate of fo- da, it is impoffible that the muriate of magnefia (ftated by the afore- mentioned account to be a part of their compofition) fhould exift in them ; for the fuperior attraction of the alkali for the muriatic acid, would utterly prevent the forma- tion of a magnefian muriate. Finally, I think we may fafely conclude that the Mineral Waters of Ballfton hold in folution, Carbonic Acid, Muriate of Soda, Carbonate of Lime, Carbonate of Soda, Carbonate of Iron, and Carbonate of Magnefia. Nor will any experiments yet pub- lifhed, warrant us in concluding that they contain any thing elfe. OF THE USE AND MEDICINAL VIRTUES OF THE WATERS OF SARATOGA AND BALLSTON. E< I VERY local confideration, be- fide the highly medicinal virtues of the waters themfelves, tends to ren- der thefe Springs equal, if not fu- perior, as a place of general refort, to any of the moft diftinguifhed watering places in Europe. The face of the furrounding country ^ diverfified with Lakes and inter- fered with the branches of the 80 The Mineral Waters of Kayadaroforas, the vicinity of the majeftic Hudfon, with its fine hang- ing bridge, on the eaft ; the rich Mohawk, and the roaring cataracft of the Cohoos, on the fouth ; toge- ther with the romantic mountain fcenery on the north and weft, all confpire to make this one of the moft interesting fpots that the ima- gination could conceive. The fportfman here, need never lan- guifh for want of employment : fhould filhing be his favourite a- mufement, he has the lakes and ri- vers at his command : if he de- lights in his gun, here are not want- ing objedls whereupon to try his ikill. To thofe who are fond of riding and of enjoying the fublime and varied fcenery of nature, no Saratoga and Balls ton. 81 country is better calculated than this to gratify their tafle. When to all this, we add the extraordinary accommodations and entertainment furnifhed at Ballfton, equalling the moft unbounded wifh, we cannot be furprifed that thefe, like moft other celebrated Medicated Springs, from having at firft been the re- fuge of fuffering humanity, the comfortable afylum of the afflidled invalid, mould become the feat and empire of luxury and diffipation, the rallying point of parties of plea- fure. "Where one perfon now ap- plies there to repair a difordered conflitution, twenty go, in the gai- ty of health, to fport a found one, againft the enervating influence of revelry and riot. It is hoped, how- 82 The Mineral Waters of ever, that like the faftiionable refort at Spa, the diftant fituation of the different Springs from each other, will aflift in preventing thofe vota- ries of pleafure from finking into that ftate of indolence and ina<5ti- vity, fo apt to prevail at fuch places of public rendezvous. The favourable circumftance of. the relative fituation of the feveral objedls of attention in this neigh- bourhood, taken all together, is cer- tainly matter for congratulation to that clafs of vifitors w hofe chief view is to pafs their time agreeably ; for befides the fources of amufement juft mentioned, other confiderations will, in addition, impofe a kind of neceffity on many of keeping them- felves a&ively engaged. For while Saratoga and Ballston. 83 the fuperior accommodation fixes upon Ballflon as the place of dwell- ing, the Springs of Saratoga will command frequent vifits. For who, making the lead pretenfions to the character of a virtuofo, would iloop to drink of the waters of Ballfton, when a few miles ride would treat him freely with plenteous draughts from the fine ftone vafe y that fu- perb piece of nature's unaflifted workmanfhip. The more power- fully purgative quality of the water of the Congrefs Spring, will fecure it a repeated call from thofe who re- quire its evacuative operations. And as to the Lakes, which are in- terfperfed in different directions a few miles diftant from the Springs, no profeffional man can entertain a 84 The Mineral Waters of doubt that the more detergent properties of their foft waters? will richly reward thofe for their trouble, who may vifit them for the purpofe of Bathing. Duly to attend to all the above enumerated objedls, and to im- prove them to the beft advantage, will require*repeated and varied ex- curfions, all which will occupy time, and they will occupy it to good purpofe ; for hereby, while indulging in a pleafurable exercife, we are gaining, as far as refpe&s our conftitutions, all the advanta- ges of labour, and that beguiled of its toils. " From labour health, from health content- ment springs ; Contentment opes the source of every joy." Saratoga and Ballstoiu 85 This mode of pafling the time, it is true, may chill the mace and paralize the balls of the billiard board, but it will warm the heart, and promote the healthy movement of its blood : it may diminifh the demand for cards, but it will en- hance the value of life. "... ut sit mens sana in cot-pore sano" " A healthy body and a mind at ease." Let us then be upon the alert, and by well directed exertions repel the approaches of difeafe, and keep clear from the favours of the Facul- ty : it is affuredly " Better to hunt the fields for health unbought Than fee the Doctor for a nauseous draught.' Having difpenfed thefe whole- fome admonitions to the well, we H 86 The Mineral Waters of now fhall attend to the more ferious calls of the fick, by noticing The operation of thefe waters , and the difeafes wherein they may be ufeful- ' ly employed, Thefe waters may generally be taken in very large quantities with- out producing any uneafinefs or fenfe of weight in the ftomach ; but in fome inftances they caufe a fenfe of coldnefs, and fometimes, though very rarely, prove emetic. Some perfons will drink feveral quarts within half an hour, without any inconvenience, otherwife than af- fecting the bowels two or three times, and operating very copioufly by the kidneys. They at the fame Saratoga and Ballston. 87 time produce a gentle diaphoresis. They however ac5l more particular- ly upon the two lafl excretions, when taken in fmaller dofes, and often repeated, as from half a pint to a pint, every third or fourth hour. Their operation upon the bowels may pretty certainly be calculated upon, if taken before breakfafh : if not taken till afterwards, they more generally affec5l the other excre- tions. Hence by a little attention to the time, and to the quantity ta- ken, we are enabled to determine their action to fuch parts, as the na- ture of the cafe for which they are diredled, may require. Thefe waters generally exhilarate the fpirits, and fometimes produce 88 The Mineral Waters of a very troublefome vertigo. In fome perfons they are faid to induce a degree of inebriety, fimilar to wine. They not unfrequently caufe drowfinefs. They increafe the appetite, and prove a pleafant ftimulus to the ftomach. Such are the effe&s of thefe wa- ters upon perfons in health; but as the medicinal virtues of mineral wa- ters mud depend upon the different fubftances that they hold in folu- tion, fo their application in the cure of difeafes muft be directed by a knowledge of the qualities of the predominating articles in their compofition. Inattention to thefe confiderations, ftill tends to fup- port what former ignorance, as to their contents, originally eftablifh- Saratoga and Ballston. 89 ed in refpedt to the ufe of them. They had proved efficacious in the cure of fome difeafes, but upon what principle was unknown. — Hence, like mod other remedies which gain a degree of reputation before their real qualities are known, they were looked upon as a kind of panacea, a cure for all dif- eafes : fo that to be unwell was a fufficient reafon for applying to them for relief ; they were indifcri- minately taken in difeafes of diredl- ly oppofite natures : hence inter- mittents and hedlic fevers, pleurify, dropfies, manias, dyfpepfias, 8cc. all equally were found hovering there for help. When at the Springs, I faw a perfon who had come up- wards of three hundred miles to H 2 90 The Mineral Waters of drink the waters for the cure of a fiftula lachrymalis, and no doubt many other poor fufferers have toil- ed through difficulties to get there, who finally, inftead of meeting with a reward for their pains, have, to their coft, experienced not only no alleviation, but in fome inftances an aggravation of their complaints, for an univerfal remedy is a perfecl fole- cifm. It is an unqueflioned law in medicine, that that which poffeffes aclive curative powers in one fet of difeafes is equally detrimental in others* The carbonic acid^ fait and iron are the principles upon which we fhould chiefly ground our calcula- tions in the ufe of thefe waters. The alkali may, in fome cafes, have its effedls, and in others we may ex- Saratoga and Ballston. 91 pedl fome advantage from the car- bonate of lime. In regard to the comparative virtues of the waters of Saratoga and Ballfton, little need now be offered : the former, parti- cularly the Congrefs Spring, is fomewhat the moft purgative, they . however, appear to be compofed of very fimilar materials : it may ge- nerally, perhaps with propriety, of them be faid, that " that which is beft adminiftered is beft." Of the difeafes for which thefe waters are prefcribed, there is pro- bably none which will more cer- tainly fupport their reputation and keep up a round of company, than Dyfpepfia. As long as the pamper- ings of luxury and the love of eafe fhall prevail over fimplicity in diet 92 The Mineral Waters of and an a&ive life, fo long will the Springs be reforted to by a train of invalids. The change of air and ex- ercife neceflarily impofed thereby uponthofe who refide in large cities, the fruitful nurferies of fuch com- plaints, together with the material contents of the waters themfelves, all feem calculated for relieving fuch affedtions. The carbonic acid furnifhes the cordial exhilarating flimulus, the fait promotes digef- tion, while the iron reftores the loft tone of the enervated ftomach : at the fame time the foda corredls the acidity fo often predominating, and the whole compofition, when judi- cioufly managed, obviates that cof- tivenefs, fo frequently an aggrava- ting attendant upon them. Hence Saratoga and Balhton. 93 we have every feafon for counting upon their falutary operation, and experience fully juftifies our calcu- late ons. Calculous complaints are among thofe which apply there in the greatefl proportion for relief, nor do they apply without reafon ; the compolition of the waters being fuch as would lead us, a priori, to look to them as a remedy. From the experiments of Saunders, Perci- val and Falconer, we learn, that cal- culi, immerfed in water impregna- ted with the carbonic acid, were diminifhed. Prieftley, Percival and others have proved that fixed air, as well as alkalies would, when ta- ken into the ftomach, pafs through the circulation and appear unde- 94 The Mineral Waters of compofed in the urine. Hoffman and other German writers fpeak highly of the efficacy of the Spa and other acidulous waters, both in preventing and diflblving the flone. Springsfeld obferved that human calculi were diminifhed by being immerfed in the urine of a perfon who drank of the acidulous waters, while that of a healthy perfon, not drinking of them, added to their bulk. Egan and Murray have again as- certained, that both lime-water and the carbonated alkalies deftroyed and broke down calculous concre- tions out of the body. Ancient authority eflablifhes the practical utility of the former, while it ap- pears by the cafes related by Bed- Saratoga and Balkton. 95 does and other modern practition- ers, that the latter have been fuo cefsfully employed in relieving both gravel and ftone. Here then we have in thefe wa- ters all the remedies that have pro- ved the moll efficacious in fuch af- fedtions, viz. A fuperabundant car- bonic acid, the carbonate of foda and lime. Indeed the benefit experi- enced by thofe who have drank of them, fully anfwers our expecta- tions. A number of cafes have come within my own particular know- ledge, and Dr. Powell, whofe long refidence at the Springs has givei^ him a full opportunity of afcertain- ing the facft, affures me that they are a valuable remedy in gravely and that he has rarely feen a cafe of it^ where relief was not obtained. 96 The Mineral Waters of The powerfully antifeptic quali- ty of the carbonic acid,^ has lately been fuccefsfully employed by means of the yeaft poultice, in the treatment of ill-conditioned Phage- denic and gangrenous ulcers : its effi- cacy in correcting their putrid na- ture, has been fuch in the New- York Hofpital, that the furgical wards which formerly were diftin- guiflied by their peculiar offenfive fmell, have, fince the more general ufe of this remedy, become as fweet and free from noifome fcent as any of the other apartments. Befide correcting the putrid nature of the difcharge from the ulcers, it alfo changes their difpofition, favours the growth of healthy granula- tions, and promotes their healing. Saratoga and Ballston. 97 Now from the eftablifhed falutary operation of this predominating principle in thefe waters, we can have no doubt but that they may be a ufeful remedy in fuch com- plaints ; and indeed the general re- port corroborates that opinion. Dr. Powell fays, that in phagedenic ulcers the mojl happy effecls may be expecled from the ufe of them. In Chronic rheumatifms thefe wa- ters have been faid to be a remedy, particularly when their internal ufe has been accompanied by a judici- ous application of them as a bath. In General relaxations of the fyjlem^ either from intemperance, or from a long refidence in a hot climate, from the effedts of fyphilis, or from long and repeated courfes of mer- 98 The Mineral Waters of cury, their conjoined flimulant and tonic powers promife to be of fer- vice. In Chlorofis and other affections arifing from debility in the uterine fyjiem, fuch mineral waters have been fuccefsfully employed ; nor need we doubt of their ufefulnefs, particularly if their operation is fupported by due attention to exer- cife and a properly regulated diet. From their conjoined purgative, an- tifeptic and tonic qualities, they ap- pear to be properly formed for the cure of Dyfentery. A perfon at the Springs, who was taking them for this complaint while I was there informed me, they had formerly cured him of it. Cutaneous eruptions frequently Saratoga and Ballston. 99 prove obftinate of cure ; they are confequently found in great plenty at thefe Springs"; and I am happy to add, that they have generally dif- appeared by the ufe of the waters : for this purpofe they muft be ufed externally as well as internally. We need not be furprifed that thefe waters are fo very ufeful in fuch complaints ; (ince they are gently diaphoretic, and their ap- plication in bathing, befides keep- ing the fkin moift, alfo furnifh- es an alterative ftimulns by means of the fea fait, carbonic acid and the fulphureous impregnation with which they abound, well cal- culated for the purpofe*. The car- * I am told that during the Revolutionary 100 The Mineral Waters of bonic acid itfelf, when applied in another form, I have repeatedly- found an effectual remedy in fome obftinate herpetic affections, as the pforiafis d'iffufa and in the palmata y or what is commonly called the fait rheum; a fimple folution of fait has alfo fometimes effected a cure. Their ufe in hypochondria/is and other nervous affeclions^ arifing from the indolence and luxury of a city life, and confequently a confidera- ble diftance from the Springs, per- haps depends in a great degree, up- on the amufing fcenes, more fimple food and conftant exercife, which War, while the troops lay at Saratoga, many of them were affected with the itch^and were sent off in companies to these Springs, bv which they were all cured. Saratoga and Ballst on. 101 are unavoidably connected with a long journey : and if any advan- tage is gained in co?ifumptions from their ufe, I rather fuppofe it owing to the fame circumftances ; fince fixed air has, by thofe who have made experiments thereon, general- ly been found injurious in fuch af- fections. In fad, the common re- port condemns thefe waters as pre- judicial in phthifical complaints, and individual obfervations fup- port the popular opinion. Thefe waters have alfo been in repute for the cure of Dropfy^ and from their pofTefling fuch a con- joined ftimulating and evacuative quality as already mentioned, it ap- pears no way improbable but that, particularly in the early ftages of I 2 102 The Mineral Waters of the diforder, they may promote the abforption of the fluid in the cavi- ties of the human body, and carry it entirely out of the fyftem. There are likewife very fatisfac- tory accounts of Paralytic affections having been cured, or at leaft con- iiderably relieved, by the inward and outward ufe of the Mineral Waters. It has alfo been related, upon un- doubted teflimony, that fevers and agues, or Intermit tents, have fre- quently been cured by them. It is however faid, to attain that effect, that they muft, befide being drank, alfb be ufed as a cold bath juft be- fore the expected paroxyfm. Among the difeafes in which the waters may be ufefully employed? Saratoga and Ballston. 103 perhaps there is none of more im- portance than Scrofula. It is re- markable of this difeafe, that moft of the remedies which have gained any celebrity in its cure, have been compofed in part of the muriatic acid. Salt water and fea bathing have been recommended from the earliefl times, and ftill fupport a de- ferving reputation ; of later date, the muriate of barytes and the mu- riate of lime have had their advo- cates ; and perhaps no remedy, as an external application, has been found more ufeful than the muri- ate of mercury ; and as an internal remedy, I may fafely fay that I have not witnefled any other prepara- tion of mercury of more or equal efficacy. 104 The Mineral Waters of Befides thefe remedies, general flimulants and tonics, as barks and chalybeates have very properly been prefcribed. Whether the car- bonic acid of itfelf, has ever been adminiftered, I am not able to fay* Marchard however (Dijfcrt. dePyr- mont) fays that " the mineral waters of Pyrmont) which much abound with it, and whence their chief vir- tue is probably derived, are employ- ed infcrofula with much advantaged In the firft edition of this work, not then having known thefe waters to have been ufed for that purpofe, I ventured to fuggeft a trial of them in this complaint, confidering that from their containing the muriate of foda (fea fait) and from their ge- neral flimulating and tonic opera- Saratoga and Balls ton, 105 tion upon the fyftem at large ; from their promoting the different excre- tions, and from their acting parti- cularly upon the glandular fyftem, they were calculated to be a reme- dy. I now have the pleafure to add, from the friendly communica- tion of Dr. Powell, that " in fcro- fula their ufefulnefs is perhaps more uniform and extenfive than in any other difeafe 'whatever ; and fo nume- rous are the injlances he has witneffed of their happy effecl therein, that he is inclined to believe a well direcled courfe of drinking and bathing, in thofe who are young, will totally era- dicate its taint from the fyjlem" Of the ufe of thefe waters in the removal of Worms, little, from expe- rience, can be faid. Sulphureous 106 The Mineral Waters of waters have long fupported a repu- tation as anthelmintics, particu- larly in cafes of afcarides ; but I do not know that the acidulous waters, fuch as thofe under confideration, have ever had a trial as a vermi- fuge. Were we, however, to rea- fon from the known deleterious ef- fects of the carbonic acid upon ani- mal life, when applied io as to af- fect the organs of refpiration, we fliould naturally conclude them to be a moil powerful remedy for that purpofe. From the experiment related in page 62, it appears that nfh can live but a very little time in thefe wa- ters. To determine their efFedls more particularly upon the life of worms, the common earth worms Saratoga and Ballston. 107 were fubje&ed to the following ex- periments : fome were fufpended in carbonic acid gas, which produ- ced immediate agitation and con- tortion of their bodies ; this foon fubfided, and in the courfe of from two to three minutes they became perfectly relaxed and motionlefs. Others were immerfed in water ^ impregnated with the carbonic acid, they inftantly moved about very brifkly, but in two minutes became entirely motionlefs and ap- parently dead. Thefe experiments were frequently repeated, and with fimilar refults. Other worms were immerfed in an Artificial Saratoga Mineral Water, with like effedls. Now as thefe worms are fo fimi- lar to thofe that molt generally exift 108 The Mineral Waters of, in the human ftomach, it is no more than fair to conclude, that they alfo would be equally affe&ed by the fame means. Hence then, as the whole alimen- tary canal may be fafely inundated with thefe waters, is it not highly probable that they will prove a complete remedy in fuch affec- tions ? It muft be obferved, how- ever, that in thefe experiments, the worms when fubje&ed for fo fhort a time only, to the operation of this deleterious acid, recovered in a few minutes after being reftored to the atmofpheric air : but a reftoration to pure air could not be effected in the bowels ; particularly when un- der the free ufe of thefe waters ; for then they muft be conftantly expo- Saratoga and Ballston. 109 fed to the carbonic acid, until they would be diflodged and carried out of the body. With this view then the waters fhould be taken in large draughts and upon an empty ftomach, to fecure their purgative operation. Notwitliftanding worms will re- vive after having been expofed for only a few minutes to the operation of the carbonic acid, either in its gafeous flate or when united with water, (till it will, upon a longer expofure, effectually kill them. By fufpending fome of them in the air, ^nd by immerfing others in the water impregnated with it, they di- ed irrecoverably in lefs than two hours. Should thefe waters not ad: fuf- K 110 The Mineral Waters of ficiently upon the bowels, they may be accompanied with fome aloetic or other fuitable purgative medi- cine. I have known an inftance where the Mineral Water of Bed- ford, in Pennfylvania, diflodged and brought away a confiderable portion of a tinea or tape worm : its expulfion was finally completed by taking the male fern and purga- tives. Would not injections of Ample carbonated acidulous water, con- joined with a little laudanum to fe- cure their retention for a time in the bowels, route the peftering little af- carides or thread worms from the rectum, where they fo often obfli- nately refill almofl every means ufually employed to remove them ? Saratoga and Balfston. Ill I have frequently prefcribed decoc- tions of the fpigelia, ( Carolina pink) in that manner, in fuch in- ftances with fuccefs. The acidu- lous waters are certainly much more immediately deftrudlive to the living power of worms. All thefe obfervations apply par- ticularly to the acidulous Springs. The fulphur water ', I imagine, may be more ufefully applied in cutane- ous eruptions^ particularly the itch ; however I do not know of any trials having yet been made with it in any complaint. A conjeclure upon the mariner of the natural formation of thefe Waters, The manner by which thefe wa- 112 The Mineral Waters of ters become charged with their iron, lime, fait, and alkali, hardly needs an explanation. As all thefe fubftances exift ready formed in the bowels of the earth, and water af- ter being loaded with the carbonic acid, cannot pafs over them without taking up a part ; but the manner in which it gains this aerial impreg- nation, as the carbonic acid does not naturally exift in an uncombi- ned ftate in the earth, is not fo eafi- ly accounted for. The carbonic acid is extricated from its combina- tions, in the large way, by three dif- ferent procefles, viz. by fermenta- tion, by the adlion of a ftronger acid, and by heat : the firft method cannot operate in this inftance, the fecond may have its effects : let us Saratoga and Ballston. 113 try how far it will explain the fub- jedt in queflion. Suppofe this water firft contain- ing a marine acid, mould have paffi- ed over a quantity of carbonate of foda ; here the acid contained in ten pounds of it, would unite with 73 grs. of pure alkali, which con- tained and accordingly would dis- charge 58 grs. equal 116 fquare inches of this acid. Now the wa- ter is fuppofed to contain at lead as much as twice that quantity ; hence we fee the mofl favourable ftate- ment of this mode, will not account even for the quantity of air actual- ly exifting as a component part of the water, much lefs for the grea t fuper-abundance which continuaL ly bubbles up through it, and is K 2 114 The Mineral Waters of difcharged. We can hardly fup- pofe the fulphuric acid to act on calcarious earth, and difcharge this air, whereby the water might be- come impregnated before it was charged with fea fait and alkali ; or elfe we mould have detedled fome glauber fait, (fulphate of foda) in the waters, as they would at the time they received their air, alfb unavoidably become faturated with gypfum, which upon coming in contacl with the alkali, would have been decompofed thereby, and for- med this fait. We therefore conclude, that this air is produced by fubterranean heat acting on calcarious earth or lime-flone, thereby fetting it at li- berty in this great profulion ; iri- Saratoga and Ballston. 115 deed the deep caverns opening on the lime-flone bank before men- tioned, gives fome plaufibility to this opinion, for it clearly evinces that fome considerable operations mufl be going forward in the earth below. The coldnefs of the waters may be objected againft this con- jecture ; but this may be obviated by considering, that even if they do not come any great diftance after their aerial impregnation, yet they may have afterwards met with their falts, which, as is the cafe with all fub fiances going from the folid to the fluid ftate,would abforb a confl- derable quantity of heat, during their difTolution, and thereby pro- duce the coldnefs in queftion. — Should any one fuppofe that this 116 The Mineral Waters of caufe is not adequate to the pro- duction of the coldnefs of thefe wa- ters, they are at liberty to confider them as having been aerated at a greater diftance from the Springs than is fuggefled. The above ob- fervations, however, will not per- mit them to fufpe6t but that the air they contain mufl moft probably have been evolved from its combi- nation by fubterranean fire. The temperature of the Waters of New Lebanon*, which is within about 50 miles, proves the exiflence of * From my own experiments and observa- tions, and from those of my friends Professors Mitchill, Waterhouse and Post, all of whom have visited and made experiments upon the Water of this Pool, it appears to be a pure Thermal Water, very similar to those of Mat- lock and Buxton, in England; only that its temperature, which is 72° by Farenheit's scale, Saratoga and Ballston. 117 iubterranean heat about this coun- try. By the waters running over a bed of fulphur, their alkali may form a is about 4 degrees higher than that at Matlock, but not quite as warm as the Buxton Waters. The Water of this Pool is transparent. It has a constant ebullition of air bubbles pass- ing through it. This air appears to be the common azotie gas. It will neither burn itself nor support the combustion of inflammable substances. It does not render lime-water turbid, by being made to pass through it : nor does it communi- cate any effect to water, unfavourable to the life of animals immersed in it : frogs are found voluntarily swimming in the pool. The water, when drank, produces no other effect than that of common spring or river wa- ter. It contains no iron or lime nor any other metallic or earthy matter : hence its transpa- rency is not affected either by Prussian alkali, tincture of galls, carbonated alkali, or the acid of sugar. It does not effervesce with the sul- phuric acid, nor does it change the colour of gold, silver, copper or lead. It neither curdles milk nor soap : it lathers and washes well. 118 The Mineral Waters of hepar with this mineral, the gas difcharged from which, gives them their fulphureous impregnation. This water, however, precipitates the solution of corrosive sublimate (the muriate of mercu- ry) of a yellow colour : it forms also a white precipitate with the acetite of lead : hence it probably contains a small proportion of some alkaline matter, but in such a very small quan- tity as not to unfit it for culinary purposes. Let it not be inferred from these observa- tions, that this water can be of no use in a me- dical point of view. No one can doubt but that free ablutions with pure warm water, both internally and in bathing, may produce saluta- ry effects; particularly in cutaneous eruptions, and in cases where the system has been loaded with peccant humours, and also where irregu- lar action in an irritable habit, has been aggra- vated by draughts of a more stimulating na-- ture. Saratoga and Ballston. 119 A method of making an Artificial Mi- neral Water ', refembling in every re- fpecl that of Saratoga. One great advantage refulting from the analyfis of Mineral Wa- ters is, the being enabled thereby to make Artificial Waters fimilar to them, whence all their virtues may be obtained at pleafure, and at any place, without the inconvenience or expence of attending at the Springs. There are fome mineral waters, that from the fixed nature of their in- gredients, may be kept for a confi- derable time and tranfported from place to place, without fuffering much, if any, alteration in their na- ture : as for inflance, thofe of Ep- fom, Richmond, Swanfey, and the 120 The Mineral Waters of like ; while others, as thofe of Pyr- mont, Seltzer, Saratoga, &c. not- withftanding our greatefl care, can be kept but a fhort time, and con- fequently cannot be conveyed to any great diftance, without loling in a confiderable degree their me- dicinal qualities : for befides the cretaceous acid, which from its vo- latile nature flies off, the iron that was kept in folution thereby, is al- fo depofited ; whence they muft lofe the moft a&ive and eflential parts of their compofition. There- fore if any one would have thefe waters at a diftance from the fprings, it is art alone that can fup- ply him. The manner in which I prepared a water refembling the Saratoga waters, was as follows : — ■ Saratoga and Ballston.* 121 To a gallon of fimple water in Nooth's apparatus, I added fome pieces of marble, (carbonate of lime) 138.4 grs. common fait, and 20.8 of carbonated foda; that quan- tity being juft the proportion ob- tained from the Mineral Water. I alfo fufpended in it fome rufl of iron, tied up in a linen rag. I then caufed the air that was difcharged from powdered lime-flone, by a di- luted vitriolic acid, to pafs through the water above mentioned, till it appeared to be fully faturated. To this water was added fome coarfely powdered fulphur, which after flanding awhile was decanted ofE This liquor was now acknow- ledged by feveral perfons who had 122 The Mineral Waters of, &c. drank of the Saratoga Waters, per- fectly to refemble them in tafle. Moll of the re-agents ufed on the natural waters, were repeated on thefe, and with like effedts. Here then is a clear proof of the fuccefs of the analyfis ; for fynthefis, or the re-compofition of a fubftance, with fimilar ingredients to what were obtained from it, is the fureft evi- dence of the correcflnefs of an ana- lyfis. Notwithftanding I have not had an opportunity of trying the effedls of this water in many difeafes, yet it being compofed of the fame in- gredients as the natural waters, leaves no doubt but that it mud po-flefs the fame medicinal virtues. CONSIDERATIONS UPON THE USE OF ARTIFICIAL MINERAL WATERS AS PREPARED IN THIS CITY : Both as a Remedy in Diseases and as an Ordinary Drink. SlNCE the firft publication of this account of the Waters of Saratoga, and of making Artificial Waters fi- milar to them, a number of Artifi- cial Fountains have been eftablifh- ed in this city, furnifhing a plenti- ful fupply of thefe and feveral other Mineral Waters ; and they appear, as far as the tafte can difcover, (for 124 The Mineral Waters of I have not analyfed them) to be to- lerably well imitated. As a Remedy in Diseases can we calculate as much upon them as upon the Natural Waters at the Springs ? In calculous complaints I fee no reafon why we may'not ; indeed upon fome confiderations I mould prefer them : our citizens may take them without being expofed to the injurious jolting of a jaunt to Sara- toga ; they may be accommodated comfortably in the quiet of home, in the bofom of their friends, and may have the different materials in the waters varied, as their com- plaints may require*. As a vermi- * It is presumed however, that if any vari- ation should be made in the composition of the water, so as to meet the particular complaints Saratoga and Balhton. 125 fuge we may look for as much ad- vantage from the artificial as from the natural mineral waters 5 and as in this inftance it is upon the car- bonic acid in them, that we chiefly reft our hopes, perhaps the artificial waters may here alfo be entitled to a preference. Certainly, by means of pf effure, a much greater propor- tion of this acid may be made to combine with water, than the natu- ral mineral waters contain. In fome other complaints they may be of equal efficacy with the of individuals, that that variation will be made known to those who may take it. It would be an unwarrantable imposition to dispense an Artificial Mineral Water, under the name of an Established Natural Water, unless it be as nearlv like it, as the composer's art would en- able him to make. L 2 126 The Mineral Waters of natural waters ; but in cafes where general bathing in them becomes neceflary, the artificial waters muft be out of the queftion. That they may be ufefully taken in Dyfpepfia there can be but little doubt ; but we fhould recollect what has been before obferved un- der that article, that the adv ■} A tage to be gained, depends in confidera- ble degree upon the exercife and change of air, incumbent upon a vi- fit to the Springs. Hence then this clafs of invalids ought not to be difappointed, if they mould not be as much benefited by the artificial, as they may have had reafon to be- lieve that they would be, by the na- tural waters at Saratoga. In Scrofulous affeclions, bathing and Saratoga and Ballston. 127 the exercife, change of air, &c. at- tendant upon an excurfion to Ballf- ton, are of material confequence : drinking the waters, of itfelf, will have its ufe ; but Scrofula is not a trifling complaint, eafily to be managed ; it requires the united operation of a variety of means to remove it. As an Ordinary Drink, thefe waters hav? become very fafhion- able, and as 44 Fashion in every thing bears solemn sway, And founts and public haunts have each their day," fo they mofl probably will, for a time, continue to be the favourite beverage of the feafon ; but whe- ther judicioufly fo, or not, remains to be determined. 128 The Mineral Waters of From obfervations delivered in the foregoing pages, it would ap- pear that the Waters of Saratoga and Ballfton poffefs adiive medicinal qualities, oftentimes very ufefully employed, not for them that be whole who need not a phyfician^ (no medi- cines) but for them that are fick. If they are adlive medicines, they muft be unfit, as an ordinary drink, for perfons in health. Ncverthe- lefs, if from a multitude of evils we were forced to make a choice, I fhould not hefitate in giving them a preference to many of the beve- rages too frequently indulged in during the heat of fummer, in this city, as brandy and water, lemon- ade, lime punch, &c. I believe the carbonic acid to be much more Saratoga and Ballston. 129 grateful and bracing to the ftomach than the citric. Were I to recom- mend any Mineral Water as a com- mon drink, it would not be the Ballfton, the Soda nor the Seltzer* but the fimply carbonated^ i. e. wa- ter impregnated with fixed air alone, uncombined with any faline, earthy or metallic matter whatever. We can hardly believe that that which the ftomach loathes, and the palate rejects with difguft, can be proper for perfons in health : all alkalies are naufeous, and it is not improbable but that they may in- tercept, by their decompounding chemical powers, the important procefs of digeftion. It is very true that the alkaline tafte of the foda water is very much covered by itfi 130 The Mineral Waters of fuperfaturation with the carbonic acid, and becomes thereby recon- ciled to the palate , and thus pafles by this garde-du-corps, unexamin- ed, into the ftomach : but an ene- my in the citadel, is none the lefs fo for having gained admittance in difguife. Sweetening a potion does not deftroy its power. The carbonic acid, however, feems free from all thefe objec- tions : it is found in greater or lefs proportions in moft of the ordinary fpring and well waters, and is what chiefly conftitutes their life and brifknefs : water faturated with it, is grateful to the palate and pleafant upon the ftomach : the weaknefs of its chemical affinities, leaves not much to apprehend from its de- Saratoga and Balls ton. 131 ranging the affimilating operations of digeftion : it is cordial, antifep- tic and exhilarating. There is, however, a clafs of the community, for whom I feel a near fympathifing intereft, who cannot too cautioufly avoid having any thing to do with this or either of the other of thefe waters : I mean thofe of weak lungs, thofe who are confumptively difpofed : the uni- form opinion of phyficians, con- curring with general obfervations, has been fully confirmed by my own perfonal experience, that fuch drinks are highly prejudicial to per- fons of this defcription. 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