K H V +■ . c • r 567 ) E3 >y 1 L REPORT ON FERTILIZATION BY Charles F. Eckart CHAIRMAN OF COMMITTEE SUBMITTED TO THE Hawaiian Sugar Planters' Association NOVEMBER, 1901. HONOLULU: HAWAIIAN GAZETTE CO. 1901 REPORT ON FERTILIZATION BY ^ Charles F. Eckart CHAIRMAN OF COMMITTEE SUBMITTED TO THE Hawaiian Sugar Planters' Association No^yy^^^^ 1 90 1. HONOLULU: Hawaiian Gazette Co. 1 90 1 Committee on Fertilization C V. ECKART, C. M. AValtox, J T. Ckawlby, Geo. Koss, John Watt. 9^\ REPORT ON FERTILIZATION (C. F. ECKART, Chairman of Committee) H(iNOLT Lu, H. T., November IStli, 1001. To THE PkESIDEXT. TRUSTEES, AND MEMBERS OF THE HAWAIIAN" SuoAR Planters' Association, Honolulu, T. H. Gentlemen: — Dnrino- the past year, no less than twenty-five thousand tons of commeroial fertilizers have been added to our Hawaiian soils to satisfy the demands of the suoar in- dustry. The initial cost of this large quantity of fertilizing material, added to the cost of distybution and application, makes the subject of fertilization from all "economic standpoint one of great importance and-- wSrtl^v 'oC't'lose consideration. The comparative cost of the different manurial compounds, their relative efficacy in meeting the requirements of the cane crop, their proportional liability to waste under given climatic con- ditions, combined with a knowledge of the soil to which they are to be applied, must constitute the only basis from which any rational and economical system of fertilization can be derived. The earliest method in use for determining the ability of a soil to furnish the requisite amount of plant food for a giveu fi'O]), involved ]»iactical tests with small field i)lats. On a small area, without fertilization, but with due obscnvance of proper tilth and cnltivation. a crop was started for puri)os<..^s of comjiarison. At the same time other |)lats Avere laid off in the same field and i-eceived alotments of nitroeriments, however, are found to be open to the following objection: Tlie time necessary to determine th(' proper quantity and the best balanced ])ioportion of fiMtiliz ing- ingredients to be added for maximum yields, covtns per- iods of considerable length. The chemist has endeavored to overconu* this objiM-tion, and to reach in the laboratory results thai Inne taken the agricul- turist months to learn from observation in tin/ fi(dd. l>y an examination of the ash of the ])articular plant to be groAvn. he learned the cpiantities and ]>rop(irtions of the various min- eral elements thai had been removed from the soil, and used in the development and elaVolfitum of the ]tlant and its ])ro- ducts. He digested a sniail (juanlity of the soil in hydro- ciiloric acid of a certain sjx'cific gravity, and noted the ]»er- centages of the different eleuu^nts in the resulting soil extract. From thes(^ analyse s. conclusions were drawn as to the fertil- ity of the land in question, and the supply of ]»lant food, from which the cio]) could draw as m^'ded. was su])])osed to have been nu^asui-ed. Unfortunately, (liscrei)ancies soon begin to arise between field results with 1 he growing cro]> and the conclusions reacluMl from chemical analyses, and the chemisi found that liii-' slioi'tt'i- method was not witlimit palpaltlc defects. If an element was lackinredient was i)resent in larointed out, these results do not ajtpear so remarkable, when it is consideivd that the great bulk of matter removed by total (•r(>]»]»ing is found in the wateis of discharge. AVith these data at hand, the next step was to tiiid some acid whose solvent action on the soil would remove the essen- tial elements in proportions a{)proximating those of cro])ping. Many organic acids of different strengths were allowed to act on the soil for varying lengths of time, and it was found that an one per cent solution of aspartic acid, when shaken with the soil at intervals during twenty-four hours, apparently met all requirements. The amounts and proportions of the ele- ments, removed by this acid dui-ing twenty-four hours, were approximately the same as were removed by total cropjjing during a period estimated at twenty years. Dr. Maxwell's conclusions were stated as follows: "An one per cent solu- tion of aspartic acid takes out of Hawaiian soils in twenty- four hours, the same amounts of lime, potash, and prosphoric acid, that are removed during the production of ten crops of cane. Therefore one-tenth of these amounts may be taken a« the i»roi)ortions of lime, ])otash, and phos])horic acid that are available for the iir.mediate cro]) of cane." The Aspartic Acid Method, although not i»erfect, offers a fairly reliable means for determining the amount of available ])lant food in the soil, and is in fact a better guide in the matter of fertilization on these islands than any other known method, as in its concep- tion. Hawaiian conditions intliienced every consideration. 6 Before considering the subject of fertilization in its more re- stricted sense, i. e. the ap|>lication of ditterent niaiuirial com- pounds to tlie soil, itrobably a few words on the average avail- ability of the essential elenn^its in (question might i)i-ove of interest. AvAiLABiLri'Y OF Elkmexts. — ('ousiderable data are at hand to give an ad(Miuate idea of the amounts of lime, potash, phos- phoric acid and nitrogen that are present in the soils of the respective islands, the subjoined table representing average results of about one hundred analvses. ISLAND Lime 380 418 0.395 0.185 Potash Phosphoric APid Nitrogen Oahu Kauai Maui Hawaii 0.342 0.309 357 0.346 207 0.187 0.270 0.513 176 0.227 0.388 0.540 These results wer<^ obtained by the ordinary agricultural method, which was in use at the Experiment Station prioi- to the adoption of aspartic acid as a soil solvent, and although an absolute analysis would give somewhat larger results, these are couiparative to a large extent as showing the pro- portions of lime, potash, phosphoric acid, and nitrogen present in the island soils. The amounts of the mineral ingredients which are found to be available are as follows: ISLAND Lime Potash Phosphoric Acid Oahu Kauai Maui Hawaii Per cent. .01568 .01367 01764 .00789 Per c-ent. .00256 .00249 00312 .00156 Per cent. .00012 .00013 .00012 .00014 or reducing these pei-centages to a more tangible form, we have: ISLAND • Lime Potash Phosphoric 4 2 lbs, 4.5 " 4.2 " 4.9 " Acid Oahu Kauai Maui Hawaii 549 lbs. 478 '• 617 " 276 " 89 lbs. 87 " 109 " 54 " which quantities rei)iesent the amounts of the essential min- eral elements, in one acre of soil to a depth of one foot, that are in a condition to be removed through the several actions of total cropping, during the growth of one crop. It is interesting to note that Kauai stands highest in lime, Maui in potash, and Hawaii in phosphoric acid. The smallest percentage of lime is on Hawaii, while Kauai is lowest in potash and phosphoric acid. If, however, we consider the availability of these elements instead of the actual amounts in the soil, a somewhat modi- fied order presents itself: Maui and Oahu are both higher iu available lime than Kauai, Oahu standing first. INIaui with the highest total content of potash has also more of that element iu an available form than the other islands. The amounts of available phosphoric acid show little variation, notwithstanding a difference between .187 per cent total phos- phoric acid on Kauai, and .51o per cent on Hawaii. This latter ingredient is so closely bound up in iron and aluminic compounds as to be practically insoluble; on Hawaii nine tons of the element per acre scarcely yield five })ouuds in an assim- ilable foi'm. Having considered the metliod in use for gauging the avail- ability of the mineral elements in question, and having noted the amounts in which they are present in the soils of the respective islands, we will next consider the demands of tlu- cro]). Elkmioxts Removed by the Cuoi'. — In the rejxtrt of the Experiment Station for 1!HMI, it was pointed out that where 29,010 lbs. of sugar were produced i)er acre by Lahaina cane, 6,60(> lbs. of mineral matter were extracted from the soil, while with Rose Bamboo, 30,475 lbs. of sugar required 7,662 lbs. of inineral matter. The following t^ible shows the amounts of the various elements includinjj;- nitrogen, which were required to produce one ton of sugar by the respective varieties: Varieties Nitrogen 25.4 lbs. 40 5 " Phosphoric Acid Potash Lime Lahaina Eose Bamboo .... 16.0 lbs. 13.6 " 89.5 lbs. 114.2 ' 28 7 lbs. 34.8 " If we should take live tons of sugar per acre, as the average production for the Hawaiian Islands, and consider for our pur- pose that the amounts of the essential elements required by the croj) for such a yield would be Ihc same as at the Experi- ment Station, we have: Nitrogen, Phosphoric Acid, Potash, and Nitrogen Required bv the Cane to Produce Five Tons of Sugar Varieties Nitrogen Phosphoric Acid Potash Lime Lahaiaa Kcse Bamboo 127.0 lbs. 202.5 " 80 IbB. 68 " 447 5 lbs. 571.0 " 143 5 lbs. 174.0 " x\s it is our present ])urpose to consider crop reijuirements in general, and not the special demands made by particular varieties, we will take the mean of the figures presented above, as representing Lahaina and Rose Bamboo needs, and for future consideration say, that a crop to produce five tons of sugar, would require per acre, about: 1()4.7 lbs. of nitrogen. 74.0 lbs. of phosphoric acid. 509.2 lbs. of potash. 158.7 lbs. of lime. We will next compare the amounts of available elements in the soils of the respective islands, with the amounts of these elements that would be required by a crop producing five tons of sugar. The nitrogen contents of the lands are not given. 9 as at the present time we have no reliable method for deter- ininiiiii its availabilitv. ISLAND Lime in soil Lime required by crop Potash in soil Potash required by crop ".'• A"d ; required m sou y,^ crop Nitrogen required by crop Oahu Kauai Maui Hawsiii Pounds 549 478 617 276 Pounds CD 1— 1 Pounds 89 87 109 54 Pounds o Poi'.nds Pounds 4.2 4.5 ^ 4 2 "^ 4 9 Pounds CO It will be noticed from tht' above figures that lime is the only one of the elements that would appear to be present in sntticient quantity for the needs of the crop. But when we consider the statement previously made, concerning the small proportion of lime that is taken up by the cro]) on some up- land soils as comitariMl with the proportion removed by the other factors involved in total croitping. we may see that the average lime content is not so large but what we must con- sider it very carefully. Maui stands highest in available lime, having r»lT lbs. on an average to the acre, but if only 15^/ of that amount could be utilized by the crop, as in the instance above referred to (which was most likely an extreme case), only !>2.55 would go to the crop where 104.7 lbs. were needed. Even if tlu' cane gets on an average 30 per cent of the lime removed, but small margin would be left on Maui, above actual crop requirements, while on Oahu there would be just enough, and on Kauai and Hawaii a marked deficiency. The i»otash is found to b<' very much too low on all the islands for su])i)lyiiig the wants of the cane, and it is readily seen why it was found necessary, during recent years to in- crease the proportion of that element in fertilizers applied. Concerning i»hos}»horic acid, the dearth of this element in available quantities in our island soils is very a]»])arent, but we are almost convinced that the aspartic acid method for soil analysis would indicate this ingredient to be lower in avail- ability than it really is. In the consideration of the amount of plant food taken from 10 the soil by the growing- crop, iu order to ]>iodiU'e one ton of sngnr, we took an average of the (piaiitities removed by Lahaina and Rose Bamboo varieties, as giving a fair idea of the large demands made by the cane ni)on the soil. However these proportions and amonnts are not to be taken as rejjre- senting the exact requirements of the cane in any locality or under any conditions. At the Exjieriment Station, tlie figures in (juestion were reached in a comjtarative test of thirteen varieties of cane, grown under similar conditions as regards soil, fertilization, and climate, one of the objects being to nott^ their resj)ective drafts on the soil as compared with their value as producers of sugar. MixEi{.\i, Mattku Retuknkd to the Koil in Cane Refuse. — The last table, although it gives an idea of the amount of plant food that would be required for a crop of such size as was under consideration, does not show the quantities of lime, phosphoric acid, potash and nitrogen, that are taken away from the field. If it did, the application of artificial manures from crop to crop would reach much larger proportions than it really does. As a matter of fact, after the cane is cut for the mill, and the trash and dead canes, etc., are burned, as is most generally the case on plantations, a much larger amount of mineral matter is returned to the soil than is generally supi)osed. By burning, of course, all the nitrogen is lost with its corresponding manurial value, l)ut tlie other essential elements remain on the field to be used largely by the succeed- ing crop. The following figures indicate the relative amounts of the elements found in the tops, etc., and in the cane, per ton of sugar grown at the Exj)erinumt Stati(»n. ELEMENTS REMOVED FROM SOIL PER TOS OF SUGAR PRODUCED. ELEMENT rn tops, leaves, and dead canes. In cane Lime Phosphoric Acid Potash 27.9 lbs. 6.5 " 66.5 " 20.2 " 3.7 lbs. 8.2 " 85 3 '• Nitrogen 12 7 " 11 These results sliow tlic lime in tlu^ lojtS'. etc. to be over seven tinu^s tliiit in the cane; the idiosjihoric acid is nu)re evenly balanced; while the tops, etc., have nearly twice as mnch i)()tasli as the <-ane. It is thus seen that if only one- half of the mineral matl<'r in the refuse of the tield is con- served, a nianurial mixture is added to the soil of ])articular value, which would less(ui to a larj;e extent the amount to be apjdied dnriuL', I'ciiular fertilization. In regard to the comparative availability of those elements returned to the soil thronj^h the burning;- of the trasli, and the same added in ordinary fertilization, there is sonu^ ditt'orence in favor of the latter. The potash in the ash is chietly in the form of chloride, with a smaller amount as carbonate and silicate, and the chloride is as assimilable as any that could be addfHl in nianurial mixtures. The phosphoric acid is rt'- turned to the land as iron and aluminic ]>hosi)hates with a much smaller amount as phos|»hate of lime, and i)hos])hate of majiuesia. These ])hos]»hates are nu)re insoluble than those ••enerally added in fertilizers and are not imnuHliately avail- able to the i»lant. The linn^ in the ash is nu)st likely com- bined with silica. ]thosi)horic acid, and sulphuric acid and is only slijihtly soluble. FOKMS IN \\'Hn'H PlOUTlLlZIX*; IX(;UEI)IKX'1'S AUK Al'l'LIKIi. Tlie amount of available jdant food in the soil and the prol>a- ble requirements of the crop to be grown are im]((H'tanl fac- tors. to be considei-ed in any estimation of manurial needs. However, nnlet-s these data are su]tplemeuted by a knowledge of climatic conditions, and a jtroper regard shown f(n- their several intluences, analytical investigations in res])ect to the nature of the soil are often of litth^ value. To the action of the heavy i-ains of the ui)lands in washing away the more soluble ingredients of the soil we have already i(4Vrred. Thf^se rains not only leaeh out material which is gradually being reiulered available for ])lant uchmIs, but also that which is artittcially a]>i»lied in tln^ form of fertilizers. The ei-osiv(^ action on the natural matei-ial of the land cannot be controlled, but with a (Ww consideiation of the ]»hysical and 12 cheiuical piopeities of applied ingredients, we can place in the soil those substances required by \he plant, and in a form least liable to waste. We now come to a consideration of the elements themselves, the relative efficacy of their various combinations, and the conditions that influence their selection as component parts of manurial compounds for different locations. Nitrogen. — This element is applied to the land in three forms, namely as nitrate of soda, sulphate of ammonia, and organic substances. Nitrate of soda is the most soluble of these three forms and besides holds its nitrogen in the most assimilable condition. Solubility and availability are not necessarily synonomous expressions as regards nitrogen compounds, although the lat- ter condition is greatly influenced by the former. The solu- bility of nitrate of soda is influenced by the temperature of the solvent, at 78" Fahr., 300 parts of water dissolve t)(l.:^;{ parts of nitrate. Added to this extreme solubility is an unfortunate disinclination of the acid part of the salt to become fixed in the soil, which causes its use on some lands to be attended by considerable risk on account of the leaching action of the rains. A test was conducted at the Experiment Station in 181)8 to determine the relative liabilities to waste of nitrogen in the form of nitrate of soda, and the same element in the form of sulphate of ammonia. In one instance 200 grams of nitrogen as nitrate of soda and in another the same amount as sulphate of ammonia were added to corresponding soils draining into a lysimeter. Forty-eight hours after the application of these compounds, a copious irrigation was allowed to over-saturate the soil, and the excess of water was collected in a receiver and analyzed. The loss in nitrogen is seen by the following rable: 13 Forms Nitrogen Applied Nitrogen lost in water As Nitrate As Ammonia Nitrate of Soda Sulphate of Ammonia 200 grams 200 " 72. 5G grams 3 08 " 0.00 grams 0.44 " The loss of nitroj;eii from nitrate is very large. Of the nitrogen fiom sulphate of auinionia only a minute piopordou was found in the receiver, the major part of this small quan- tity being in the form (ff nitrate, into which state it iia AVe have spoken at some length concerning the unfavorable characteristics of niti-ate of soda Avhen applied to lands of heavy and uncertain rainfall, parriculaily when such lands are deficient in lime. However. notAvithstanding these several draw-backs to its general use in all localities, nitiate of soda has suflficient su]terior qualities when ai>])lied in juoper (pian- tities and under suitable conditions to render its use of the highest advantage. AMien ap])lied in large amounts and under such conditions as to allow of the fullest effects, nitrate has Ix^ni observed in many instances to induce an abnormal and undesirabh^ growth, which retarded the ripening of the cane, and resulted in juices of low purity and low sugai- contenl. On th(^ other 15 band this selfsame stiniulatiii^- property lias been of the greatest service to yellow and "nitrojien-hunjiiy" cane, and with the application of small amounts of this material, won- derful tonic effects have been produced in an extremely short space of time. In rej^ard to the influence of nitrate on tassel ing, Mr. Geo. Renton of Kwix Plantation writes: "My experience in one case with a late application in September of nitrate of soda was that it materially effected tasseling. About one-third only of the stalks flowered. As the application in this instance was made for the express purpose of preventing the tasseling of the cane, these results were gratifying.'' Mr. Kenton fur- ther says: "It is my opinion that either excessive or late ap- plications of nitrate of soda will lower the juice purity. The best juice obtained at this mill was from canes upon which nitrate was put on not later than the latter part of April." The experience of Mr. Olding at Kohala has been that "nitrates prevent tasseling in a very marked degree." It was observed last year at the Experiment Station that nitrogenous fertilizers in general prevented tasseling during the flowering- period, whereas, unfertilized plats, and plats receiving merely IJotassic and phosphoric acid fertilizers flowered without ex- ception. On account of the readily available condition of nitrate of soda we should expect small applications of this material to exert a more potent influence in preventing tas- seling than would be the case with either sulphate of am- monia, or organic nitrogen. Some difference of opinion exists as to the amount of nitrate that can be judiciously added to the soil, and reference will be made to that subject later on. Attention has been called to the fact that where nitrate of soda and chloride of potash are applied to the same land, a chemical reaction might ensue to the detriment of the soil. This supposition is based on the fact that the solium of the nitrate of soda has a strong affinity for chlorine, which forms a part of the chloride of potash, and that the two elements might combine with each other to form common salt. Al- 16 though this icactioii is within the roalm of probability we are without the necessary data for a contirniation of tliis view. However it is better to be on the safe side, and on aeeount of this probable interchange of elements to use potassium sul- phate instead of potassium chloride, where nitrate of soda is being used on the land. Sul])hate of ammonia on account of its ready solubility, and small liability to waste as com})ared with nitrate of soda, is held in much favor as an economical nitrogenous compound. At IS'' C. !.:> parts of water dissolve one i)art of sulphate of ammonia and it is seen that little ditference exists between its solubility and that of nitrate of soda, rendering its diffusion throughout the soil almost as c(mipiete as in the case with the latter substance. However it has one very strong advantage over the nitrate of soda, in its ready ability to beconu^ fixed in the soil, and on that account alone, its })articular suitability for sonu^ locations is very ai)pai'ent. If we refer to the results previously given as to the comi»arativc wasti^ of the two fer- tilizers under similar conditions, a striking contrast is noted. Of 200 grams of this material added to the land in the lysi- meter tests only 3.52 grams of its nitrogen was lost in drain- age Avaters, as comi)ared with 72.5(> grams of nitrogen h)st from an e(}ual amount of nitrate of soda. Of this small loss, 3.08 grams were in the foi-m of nitrate, into which condition it had been converted by the nitrifying bacteria of the soil as previously mentioned. Only .44 gram of nitrogen escai>ed in the f(U'm of sul])hate of ammonia. To show Mr. Oi'awh'y's experience with this salt on "sandy soils," we will gi\e his detei-minations in full, the conditions of his experiuKmts having been described on page 13. 17 Amount of moisture in the original soils.. . . Carbonate of lime in the soil Weight of soil taken. . Time required to pene- trate two feet. . . . Total water passing through Time required for the above water to pass throTigh Water holding power of the soils Moisture in soils after ten days Sulphate of ammonia lost Muriate of potash lost Sulphate of potash lost 3.73 p. ct. 2.03 p. ct. 1.08 p. ct.! 0.61 p. ct. 7ll5p. ct. 77.37p.ct. 81.85 pet. 365 grs. j 407 grs. I 362 grs. 55 min. 320 ce. 335 min. 49 p. ct. 31.5 p. ct. 8 p. ct. None. None. 19 min. 342 cc. 12 min. 345 cc. 180 min. 95 min. 39 p . ct. 43 p. ct. 20.4 p. ct. 18 8 p. ct. 42 44 p. ct. 59 p. ct 56 p. ct. p. ct. p. ct. i 25 p. ct. 91.07 p. ct. 374 grs. 8 min. 355 cc. 95 min. 38 p. ct. 16.6 p. ct. 86 65 28 p. ct. p. ct, p. ct. "Nitrate of sdda practically all was lost, tliore beinosed almost entirely of coral or lime-stone, and that other in<;i-edi(Mits must be present in veiy snuill (piantific^s. As the double silicates in the land are most probably responsible for the tixinji of the ammonia radical, it may b(^ easily understood why the co efficient of tixation will be reduced in propoi-tion as the bulk of the soil is laken up with carbonate of lime, and the silicates excluded. 18 As regards the action of aninionirim sulphate as coiupared with nitrate of soda on the lime of the soil, there is a marked difference in faAor of the former. In the Ivsimeter tests to determine this point, it was found that whereas 20.52 grams of lime were lost through the action of the nitrate of soda aj)- plied. only 5.40 grams were removed through the influence of the sulphate of ammonia. In making these comparisons, attention should be drawn to the amount of lime that was carried from the soil by the application of water alone with- out the addition of the various salts. This amount was 1.72 grams, and shouhl be subtracted from the weights of lime re- moved, as given in the table on page 14, in order to reach the actual amounts of this soil element that were lost through the influence of the several agencies. The action of ammonium sulphate in the soil in furnishing nitrogen to the cane, is considerably different from that of the nitrate. The latter substance is in a suitable condition to be absorbed by the plant roots immediately on going into solu- tion in S'oil water, or in coming in contact with the plant root acids. The ammonia of the ammonium sulphate on the other hand has to be oxidized by soil bacteria and changed into niti-ic acid before it reaches an assimilable state for the cane. This difference in the immediate availability of the two com- pounds will explain to a large extent the several ditferences disjdayed in theii- effects upon the crop. The nitrogen as nitrate is so readily absorbed when applied to the land as to act like a stimulant, while the more slowly acting nitrogen of ammonium sul[»hate is yielded more gradually as a plant food, and forms a longer lasting supply of this material, per given weight of ammonium sulphate added than that from the nitrate of soda. We now come to a consideration of nitrogen as supplied from organic sources. The chief nitrogenous substances of this order as ai)i)lied to Hawaiian soils, are dried blood, tank- age, and fish scrap or "fish-guano." Of these materials dried blood unquestionably ranks first, both in its high content of nitrogen and the ease with which it is rendered available bv 11) the niici'o-oijiaiiisins of the soil. Tii a jterfectly dry state it lias been known to inn as liinh as 14 ])ei' rent of nitrogen. The sain])les of tliis malerial re of about 12 i)er cent., with a small amount of water. Tankage, though containing less nitrogen than the blood, is an organic source of nitrogen of no little value. It is oom- ])osed of scraps and fragments of flesh which have been dried and ground, after the removal of fats by steaming. Tankages have been received at the Experiment Station for analysis which were found to have as high as 10 per cent phosphoric acid in addition to their liberal content of nitrogen, which gives them added value as fertilizing compounds. Fish scrap, on the average, contains about 8 per cent of nitrogen and 7 per cent of phosphoric acid. It constitutes the ground residue of fish from which the fats and oils have been largely removed, and varies considerably in its value as a manurial substance. Occasionally sam})les are met Avith which contain a large amount of fatty matter, and tliese fats and oils Avhen present in considerable quantity cause the otlier organic matter to decompose with great difficulty in the soil. Some years ago a sample was received at the Experiment Station laboratory which was found on analysis to contain- over 24 per cent of total fats. In the consideration of organic substances as a source of nitrogen, a distinct difference is manifested between them and the soluble chemical salts which have just been discussed. Nitrate of soda and sulphate of ammonia, on account of their solubility in water, may be readily taken up by that medium and distributed throughout the mass of the soil. The organic material on the other hand can only be applied to the land in spots and needs slight covering to depths varying with the nature of the soil and of the substance used, in order that the most suitable conditions will be reached for thorough de- composition and nitrification. Nitrification is believed by many authorities to be accom- plished through the agency of three kinds of soil bacteria. 2(1 One kind chanjies the nitrogenous material into aninioniuni compoundis, another eonA'erts The hitter into nitrons acid, and still another completes the work by a conversion from nitr<»ns into nitric acid. These processes are slow and in the conrse of their ()i>eration a gradual distribution of soluble ammon- ium comi»ounds and nitrates throughout the entire soil veiy probably takes place. For instance as tlie ammonia is formed it may be taken up by the water of the soil and carried som<^ little distance before it becomes fixed, and on being oxidize'' lime from the land. It is seen that nearly nine times as much lime was removed from the land where muriate was added, than resulted from the application of sulphat(\ The influence of }»otassinni chloride is evidently almost as i»ofent as that of the nitrate of soda in its dei)leting- action on the lime content. In ^Ir. Crawley's invest igations with the "sandy soils" pre- viously jeferred to, some very surprising results were reached as ]-egards the disposition of the respective ])otassic com- jiounds to become fixed under similar conditions in soils of a highly calcareous nature. By )-ef erring to the tabulated re- sults on page 17 it will be noticed that none of the chloride or sulphate of ]>otash was lost in the soil containing flie least amount of lime carbonate. In fhe soil with the highest per- centage of lime carbonate. (■»') per cent of the chloride was loK-t and 2S per cent of the sulphate. The absorption of potash by these peculiar soils is intluenced chiefly by their content of lime carbonate for several reasons. The higher the percent- age of lime carbonate the lower must be that of the double silicates in the respective soils, as was pointed out before in considering sulphate of ammonia, and these silicates are par- ticularly instrumental in holding potash. The mechanical condition of the soils is intluenced to a large degree by thi^ quantities of lime carbonate that the}- contain, and as the mechanical condition varies so will the rai)idity with which a solution may filter through them. The time that the solu- tions of potash were in contact with the earth in the pipes in- fluenced in great measure the extent of the resulting chemical changes. In the early rej)orts of the Experiment Station it was point- ed out that in adding chhuide of ]»otasli to lands bordering on the sea and which are sometimes abnormally high in salt, there is a liability of inci*easing the proportion of this deleter- 22 ious substance, and on that account sulphate of potash was advised as the proper form under such conditions. Phosphoric Acid. — This element exists in fertilizers in many combinations with varying degrees of solubility. It is usually classed as water-soluble, citrate-soluble, or insoluble. In considering the availability of what have been called the essential elements of the soil, it was noticed that although the lands of the Hawaiian Islands are usually very high in phos- phoric acid, that very little of it is rendered assimilable dur- ing the growth of the crop. On that account it would seem most natural to apply this element in its most soluble form. The water-soluble phosphoric acid in the form of super or double super:plios})hate is readily taken up by rain or irriga- tion water and distributed more or less throughout the sur- rounding soil and is rather thoroughly tixed. This fixation is brought about by the carbonate of lime and by the hydrated ferric oxide and alumina present. In the first case, a more or less insoluble phosphate of calcium, and in the second case a basic phosphate of iron or alumina is produced. Although there are Hawaiian soils with no inconsiderable amount of lime carbonate, the great bulk are either lacking in that com- pound or else contain it only in very small i)roportions. The ju'edominating bases are those of i''on and alumina, and with them the phosphoric acid is rather quickly united; even where calcic phosphate is formed the indications are that the phos- ])horic acid of this substance is gradually yielded to form com- binations with the former. As nearly all the phosphoric acid in the island soils is already a component part of these basic phosphates, it would seem on first consideration that little or no improvement could be etfected by a further addition to these insoluble compounds. However, when the soluble phos- l)hoi'ic acid is taken up by the water in the soil it is distrib- uted thoroughly and coming in contact with the minute part- icles of iron and alumina, results in compounds which on ac- count of their existence in extremely snuill grains, and on account of their thorough dissemination throughout the soil 28 mass, are in a niiuh iiioic available conditiou than the natural basi<- phosphates of the land. ('itrate-solul)le, or di-calcic }»hosphate. althoujih insoluble in water, is soluble in a solution of citrate of ammonia, and is readily absorbed by the acids of the plant roots. Owing to its insolubility in water, however, it cannot be so thorouj;hly in- corporated with the soil, as the form previously described and is of corresponding less value. By insoluble or tri-calcic jdiosphate is meant that form which exists in natural or untreated phosphate, and is in soluble in water or citrate of ammonia. In the soil it is ren- dered slowly available through the processes of decay or de- composition, which action is influenced by the amount of organic matter with which it is associated, the fineness of its mechanical division, and also by the moisture content, depth, and temperature of the soil in which it lies. Dr. Maxwell has pointed out that the acidity of a soil also assists material- ly in this decomposing action, and attributes the greater effect of bone meal on some of the u])lands to the higher moistur«^ and acid content of those soils as compared with the lands of a lower elevation. Lime. — This element is present in nearly all fertilizers con- taining phosphoric acid, and as calcium phosphate is added in large quantities to Hawaiian soils. In addition to the lime as I)hosphate a considerable quantity is also present as sulphate or gypsum in treated phosphates such as the form designated as water-soluble or citrate-soluble, and on account of its fine mechanical and chemical condition is of high value as a fer- tilizing ingredient. (xround coral and coral sand are also good as well as chea]) sources of this element and are used to a considerable extent on these islands, especially where the content of organic mat- ter is low as well as the lime. The percentages of lime in the various compounds are approximately as follows: (iypsum 32 per cent of lime. Ground coral 45 per cent of lime. Coral sand -19 per cent of lime. 24 The ditterenoe in lime content between coijil sand and jiTonnd coral is due to the admixture of shells in the former, which are c()ii:]»oscd of almost ])ure lime carbonate. Slaked as well as quick lime are used in some htcalities, but owinji to the readiness with which these forms of lime attack the nitro- genous }naterial of the soil, the.v are unsuitable for many lands. Feutili/eks Tsei) ox the Diffekext IsLAXits. — The amount of fertilizer to be added to any land involv(^s a consideration of the available constituents of the soil, and the demands of croppinji;. Tln^ foini in which its iniiiedients should exist is inrtuenced by a consideration of their resi»ective properties and the existini*' clinmtic conditions of the localities in which they are to be applied. On the Island of Oahu, the averaj^e mixed fertilizer con- tains its phosphoric acid in the water-soluble and citrate soluble forms; the potash is in the form of sulphate; and the' nitrogen is applied in three forms, as nitrate of soda, sulphate of ammonia and organic material. On Maui, fertilizers are api)lied to a large extent in the same forms as on Oahu, the water-soluble and the insoluble phosphoric acid being somewhat lower. The three forms of nitrogen are generally used in the same fertilizer, although nitrogen as ammonium sulijhate is in excess of the organic and niti-ic. The total nitrogen is ().('» per cent higher than on Oahu. On Hawaii on account of the diversity of conditions, fertil- izers are naturally found to vary more in their composition than on the other islands. In the Hilo district owing to the heavy rains, nitrate of soda cannot be used without liability to waste, and potash in the form of chloride is in disfavor owing to its depleting action on the lime content of the soils which are already low in that element. Most of the nitrogen used in the district is derived from organic sources and also in some measure fi'om sulphate of ammonia, although some few fertilizers used during the past year contained nitrate. In Hamakua phosphoric acid is applied mostly in soluble foiins, the uihoiicn as a rule bcinu dciivcd fioin ainuioiiiuui sulphate and the potasli froiu sulidiatc. Oil Kauai, nitrate of soda and snli)harc of ammonia are fav- ored as sources of nitrojicii for mixed fcrtiliz(M's, very little of tliis clement beinj^ ajtplied in an organic form. According to the analyses of the Experiment Station laboratory, Kauai fertilizers are higher in nitrogen as a rule than those from an;.' other island. On aci'ouiit of the wide \aiiaiions in the composition of fer- tilizers and tile limited number at hand for forming an esiti mate, it would be impossil)le to give average formulas for the differeiil islands which would be leliable for juirposes of com- parison. The following table will give an idea of the wide dif- ferences between the lowest and highest ]>ercentages of each element a]t])lied in mixed fertilizers of which we have data. Island. Potash. Phosphoric Acid. Nitrogen. Lowest Highest. Lowest. ! Highest. Lowest. Highest. Maui Kauai Hawaii . . Oahu Per Cent. 4.J3 4.89 4.03 8.50 Per I'ent 17.24 10.10 22.54 14.66 Per Cent 5.10 5.68 5.29 7.01 Per Cent. 14.26 9.39 14.61 15.00 Per Cent. 5.04 6.66 3.25 4.7(1 Per Cent. 9.70 9.91 10 42 7.10 Time and Mkthoks of Aiu'Lvrxc. — Theoretically the various elements should be added to the laud in such ]>r<)portions and at sueh times as Uw cro]) leiiuires them. This would nece^;- sitate repeated applications of small quantities of mixed fer- tilizers with their respective ingredients in ever varying pro- portions, due consideration being given to their individual inclinations to Avaste. It would mean the feeding of the plant according to the needs of its tiuctuating growth and develop- ment, and the multitudinous changes involved in the elabora- tion of its products. Agricultural science has not advanced so far as to make such nice calculations possible, and if it had. the cost of labor would not permit the close application of such theoretical doctrines. 26 Most plantations make two applications of mixed fertilizers during the growth of the crop and the times of these applica- tions vary on different plantations. Some incorporate fertil- izing material with the soil of the seed bed before planting and others make the first application when the cane is six to eight weeks old or after suckering has actually commenced. Where two applications are made, the first is usually at the end of the suckering period and the second in the fall or in the following spring, depending on the time of the planting season. The methods followed in applying fertilizers depends large- ly upon the kind used. Where the ingredients are in soluble forms, on account of labor considerations the practice on many plantations is to merely drop the material in the fur- row beside the cane stalks, without covering. This method should give satisfactory results with any but fertilizers con- taining organic and insoluble forms such as blood, tankage, etc., which latter substances require a slight depth in the soil to meet the proper conditions for nitrification and satisfactory decomposition. Dr. W. C. Stubbs, ("Sugar Cane," Vol, 1) says, in speaking of practices in Louisiana: "Nitrates and salts of ammonia are always best used as a top dressing — at short intervals, in small quantities. Dried blood requires but little depth, pro- vided moisture necessary for conversion into available plant food be present. Tankage, bones, and fish scrap must be sunk to deeper depths to obtain fermentation necessary to their conversion into soluble plant food. None of the above should be turned too low, especially in stiff soils, since air, moisture, and heat are the factors needed in decomposition." It was pointed out in the report of the Experiment Station for 1890, that considerable risk is entailed by applying soluble fertilizers in the furrow under the seed where irrigation is practiced. Under such conditions there is a likelihood of the material being washed down and out of the soil before the young cane is in a condition to appropriate any of it. This would not apply, however, to organic sources of nitrogen or 27 phosplioi'ic- acid which arc so gradually decomposed, and we understand tliat such material is giving good results in one locality when applied in such manner. Mr. Geo. Eoss, member of the Committee on Fertilization, writes a very interesting letter on the practices followed on Hakalau Plantation. He says: "At Hakalau I am u»ing al- most exclusively a high grade fertilizer of the following aver- age composition. Nitrogen (from sulphate of ammonia and organic ammonia of dissolved bones) 5 to 6^; Phosphoric acid (available) to 10 ^: Potash in the form of sulphate of potash, 9 to 10;/. This is applied to the plant cane at the rate of 900 lbs per acre in two applications, the first at time of planting and at the rate of oOO lbs. per acre, scattered by hand in Ihe bottom of the furrow, or seed bed, followed by a cultivator To stir it up with the soil. The second application is at the rate of fiOO lbs. per acre and just prior to 'hilling up,' or when the cane is too high for further cultivation by mule or horse im- plements. At this time it is scattered, also by hand, on both sides of the cane row and covered up by small plows which throw the soil in towards the cane, which is afterwards trimmed up by the hoe. The same grade of fertilizer is applied to all ratoon cane, but usually in one application of about 500 lbs. per acre. It is applied to both si^es of the row as is done in the case of the second application to plant cane, and is covered over i.i the same way by small one horse plows. The usual practice is to apply it to the ratoons as early as possible after the lirst hoeing. We have used a fertilizer of this general composition for several years, and although I have experimented to some ex tent with such special fertilizers as tankage, fish scrap, and bone meal, I have had no results to warrant their continuance. Nitrate of soda on account of its solubility is not adapted to this district, where in the past we have been subject to s'lch heavy rainfall whereby this salt is liable to be lost before be ing taken up by the plant. Lime always gives satisfactory 2S results and this is tnie of all soils in this district. Filter-press cake when passed thi-ough a disintegrator and ai)plied in lib- eral (|nantity gives excellent and lasting lesults. The same, of course, is true of stable manure. I might state that tlie percentage of jjotash in the mixed fertilizer, above refem^d to was increased from 5 to 6''/ uj) to its present strength about three years ago, and with marked i-esults. This was suggest- ed to me frou) obsei-ving the luxuriant growth produced by ashes fier-](liosphate, sul})hate of i)otash, nitrate of soda and sulphalc of annnonia. ^^'e have each held we plant analyzed and vary the ])ro])ortions of the above ingredients to suit the analysis, so that as a rule every held has a ditferent fertilizer to suit its requircnnuits. A\V sometimes use as a si)ecial fi^rtilizer a mixture of nitrate of soda and coral lime in equal (juantities and ai)i)ly about 400 to 500 lbs. ])er acre. We ai)i)ly this as late as July ;u)d August in the same manner as plant cane mixture. The dif[Vrence between our plant cane and ratoon mixture, is. that in the latter we increase the projiortion of nitrate of soda and deci-ease the phosphoric ingredient." Mr. John A\'att of the Committee on Fertilization, in writ- ing concerning the ]>ractices followed at Honokaa. says that it is custonuiry to a])])ly from .500 to SOO ]>ounds of mixed f<'r- tilizer per acie for the croj). "On poor upj)er lands we give- two ap])lications, on lowei- lands wheri^ soil is rich we give only one. AX'ith only one ajtpli cation we distribute the fer- tilizer in the fui-row before the S(vd is put in, mixing with the soil by a subsoiler or small ])]ow. \Miere we give two ai»pli- cations the first is given as above and second is given Avhen the cane has about two months' gi-owth, sometimes a little later dejjending ui)<)n the condition of the cane, by distribut- 21) in^ tho tVitilizei- aloiiii side of Tlic stool and cillicr lioriuy it in or ruiiniiii; a ciiltivatoi- alon^ tli<- fnn-ows.'" This yeai- tlu' jiciicral coniiiosition of niixed fcrlilizei- ap- plied at Hoiiokaa has hcci! as follows: '.) — 1(1;/ I'hosphoric acid. 8f/ Aiinuoiiia fioiii siilphat(\ 5^' ]*()tash from snljdiare. ]\Ir. AVatt says; "The above is the fertilizer which we have used this year and the weather has been so that we cannot tell what results we nuiy have from it. T.ast yeai- we used a ditferent mixture ou the upper lands with veiy ^ood results, the jinalysis of which was as follows: 15;/ Potash fr(»ni sulphate. 5;/ Ammonia fi-om sul])iiate. 10 — 12;^' IMiosphoric acid. "With the above fertilizer the cane came up very well and nuiintained a vigorous growth until it was clucked by th(^ very dry weather durin<;' the past five months. When we planted this cane we ^ave it an application of 70(1 pounds of the above fertilizer with the seed and about foui- months later w'e gave it 700 ])ounds ])er acre more." For some years ]»ast Mi'. Watt has beiui very careful in regard t(» the })reseiviug (*f all stable manure, which is liber- ally treated with a dressing of sui)erpliosphate to pr(^vent loss of ammonia. Both with this comjtound and with mud-press cakes which have l)een ])assed through a disint(^grator hi^ has obtained si)lendid results. \W are in rect'ij)t of a very interesting letter from Mr. J. T. Crawley, who writes of a method in vogue at Kilun IMantatiou for tlu^ distribution of nitrate of soda. Ou account of its bear- ing so strongly ou the (juestion of labor economy the letter is given in full. 30 Honolulu, T. H., Sept. 24, VM)1. €has. F. Eckart, (Miaii'man, ("oinniittee on Fertilization. I3kau Sik: — I wish to inclnde in tlie lepoit on fertilization a method of applying nitrate of soda devised and used by Manager W. F. Pogue of Kihei Plantation, and eonmiunieated to nie in a letter from him dated July 2(>. ]Mr. I'ogue says: ''Lacking labor suftieient to apply nitrate of soda with ground eoral, I hare just finished fertilizing some (iOO odd acres with nitrate dissolved in water and applied in the irrigation. The form of application was as follows: Dilute one bag of nitrate of soda in one barrel containing 50 gallons of water, one pail of this solution is added to 4 pails of water, or in that pro- portion; in another barrel a hose bibb in the bottom of the last barrel discharges the diluted solution into a tub which is kept filled to a given mark, from the tub the mixture flows in an exact amount all day into the main irrigation ditch. The outlet of the tub is fixed, and cannot be opened or closed by the laborer doing the work. Strainers are used on the tub and diluting barrel. In this way one man can easily apply 100 lbs. per acre of nitrate to 00 acres in six days, two men will do three or four times as much. In applying I have put on 75 lbs. of nitrate to an irrigation, then skip one or two irrigations and apply the same amount again. The fields thus treated have started from short jt)int sticks to very long joint sticks which means a very rank growth. It seems to me that any soluble fertilizers can be applied much more evenly and certainly vei'y much cheaper than in the ordinary method. It also seems to me that if the applications could be made in small doses as the cane needs it, it would be the correc-t method, exactly as we would feed a horse or a cow." Again in a letter of Sept. 20, Mr. l*ogue says that he is applying 50 pounds nitrate per acre. To quote his words: "^^'e have with my method applied 50 i)Ounds to the acre with 31 one pidinary Jap to as high as 26 acres in one day, that is, 5,250 pounds were applied to 105 acres (one field) in four days by one Jap. The cane began showing the eftects on the fiftli day, by the seventh day after application, the cane roots had fully gotten hold of the stimulant, from a greenish yellow the leaves were turned a dark green. We apply 50 lbs. nitrate every other irrigation, or say every IS days. Cane shows the want of stimulant in from 20 to 30 days, according to nature of soil, after first application, and 30 to 40 days after the second application with this amount of 50 lbs. per acre. Later on, I can give aou results of further experiments on these same lines." The idea of dissolving the nitrate of soda in the water of irrigation was suggested by the scarcity of labor, and Mr. Pogue saw the added advantage of applying this very soluble fertilizer in very small quantities and frequently, rather than in one or two large doses. The only objection that I can see to this method is that there will be loss in the ditches through which the water passes before it reaches the rows of cane, and this loss will depend upon the nature of the soil that compose the bottoms and sides of the ditches. Mr. Pogue states that in the red soils where he is using the method the loss of water is very small. Again, if the part of the row where the water is entering takes up more water than the far end it will like- wise take up more nitrate of soda. The main advantage, aside from the labor question, to my mind is the advantage of applying only so much nitrate as the cane needs at the time, and to be able to apply it in small and frequent doses. With as fugitive a substance as nitrate of soda this is a great consideration indeed. \Yhatever of this substance as is not taken up by the cane, can be washed away either by a heavy rain or by a heavy irrigation, and the least amount that is in the soil at any one time the less is the danger of loss. Very truly yours, J. T. Crawley. 32 This method for the distiibntiou of nitiate of soda, as adopted by Mr. Po^ue, apparently has much to commend it, both as regards the saving of hibor and the added advantage of being able to apply small quantities of the mateiial as the cane seems to demand it. As the barrel from which the nitrate solution is discharged into the main ditch is- kept at a constant level, an even pressure and discharge is obtained which would guarantee a regular and unchanging admixture of nitrate solution and ii'rigation water. Mr. Crawley's obser- vation as regards probable loss of nitrate during the passage of the water through the irrigation ditches is well taken, though this loss may probably be small and of little conse- quence as comjjared with the saving of labor and other ad- vantages to be derived from a following of this method. How- ever this loss is a factor which will be considered later on in a special reference to the use of nitrate on plantations. A curious jioint manifests itself in this method of ai)plying nitrate of soda, which would be particularly striking where the cane is jdanted in long rows receiving their water direct from the main ditch, and less so in proportion as lateral trenches are used and the cane rows shortened. In the former instance the ends of the rows next to the ditch necessarily re- ceive more water than the other extremities and consequently they will receive more nitrate. When this material is dis- tributed in the usual way by hand, each part of the field has approximately the same amount applied to it, and loses it in proportion to the amount of water added providing a point above saturation is reached. At the ditch end of the furrow, according to Mr. Pogue's method a larger quantity of nitrate comes in contact with the cane roots, while in the ordinary method that point is marked by the greatest loss. Mr. Pogue sjieaks of the probable advisability of applying all soluble fertilizers in this way on irrigating plantations and the plan certainly presents many favorable points for consid- eration. However, the question would arise whether the sav- ing of labor and the advantage of small and frecpient applica tions would otf-set tli<' loss of soluble high urade fertilizers 35 in tlic iiiij^alioii ditches^ which is inHiieiiced by the area and iiatnie of the exposed soil. This is a point which must be studied out \ery carefully before any radical change in the system of applying fertilizers is introduced, and I believe this point may be fully determined by a method which will shortly be presented for consideration. It has been pointed out that the ends of tlie furrows next the ditches receive more water than other points along tlit cane row. Under ordinary conditions the soil at these furrow ends, where long rows are the rule, will soon become sat- urated and lose a larger (piantity of their available plant food ihan other points, through the hnuhing action of the excess of water. With that water will go a certain i)ercen1age of the fertilizer in soluti()n it is true, but the dissolv(Ml elements which leave the irrigation watei- to become^ tixed in the soil, would doubth^ss be more than snfticient to i-eplace the same elements that had been remoNed from the soil itself. In other words the largest amount of fertilizing mateiial would be added to the p(»ints sutl'ering most from ordinary iirigation, on account of the resultant leaching action. XITKATE OF SODA. Owing to the differences of opinion held by plantation man- agers concerning the eflicacy of this substance as a fertilizing compound, I wish to give a consideration of this subject some I)rominence in this i-eport on fertilization, as I believe that the reasons for this dirt'ei*ence of opinion can be largely explained. Jn th(^ early re])<)rts of th<^ Experiment Station, the readi- ness with which nitrate of soda is taken u]) by the cane and its corresponding stimulating action on the i»lant were re- ferrt^l to at some length, ^^'e may quote from the Keport of 1805, page 20, where Dr. ^Maxwell says: "Excepting in loca- tions where the water supi)ly is so small as to retard its (piick operation, nitrate of soda is not a safe and normal fertilizer — it is not a good ordinary diet for comparatively slow gro\\ing ])lants. T'nder the average conditions of moisture and warmth, the plant takes it too greedily, and tlu^ result often is 34 abnormal growtli. The results of this abnormal growth in cane are bulk, which includes an excess of water and un- elaborated products of assimilation, and comparatively less sugar, with low purity of the juice. In wheat and oats the result is lots of straw and little grain. In one case where the manager of a i)lantation called my attention to a piece of cane, which he called 'very coarse and rank, and would never get real rij)e,' I found that Ii5() pounds of nitrate had been added all at once, and the weather had been such as to allow of the fullest effects. I do not advise nitrate of soda as a reg- ular diet in any situations excepting those of extremely small water supjjly. I advise nitrate of soda only as a tonic and immediate source of nitrogen in a crisis of a crop, and only in locations of moderate or small rainfall, but never wiiere th(^ rainfall is constant or heavy." The views of Dr. Maxwell on this subject are clearly set forth, and the advices of the Experiment Station in regard to the use of this material have been largely influenced by his practical observations of field effects following the application of nitrate on plantations. During the last few months, my attention has been called to the fact that a number of plantations are applying nitrate far in excess of amounts considered safe by the Experiment Sta- tion for the normal growth and development of the cane, and reports from these plantations indicate that the cane is doing- well. These cases certainly need careful consideration, and a study of the conditions under which nitrate is applied in these instances must necessarily throw considerable light. on this important and apparently perplexing problem. Reference has been made to a case where 350 pounds of nitrate, per applica- tion ]>er acre, were seen to produce a rank and frothy growth on one plantation where conditions allowed its complete ap- propriation by the cane. In other instances of more recent observation it is found that 500 pounds, per application per acre, leaves nothing to be desired, the cane presenting not only a vigorous, but a perfectly sound and healthy growth. This apparent inconsistency, I believe may be fully explained, 85 and the explanation will involve a factor of j^reater econoni jcal significance tlian the nitrate itself, namely that of water sn])pl.v. The properties of nitrate of soda have already been dis- cussed, and its ready solubility and disinclination to become fixed in the soil have received special attention. It was noted in the lysimeter tests referred to on page 13 that the loss of nitrate of soda from over-irrif»ation reached extremely large proportions and thos*^ data will now be of particular value in considering the subject in hand. If a plantation were to use say 500 or (500 lbs. of nitrate, per application per acre, also applying mor<' water to the fields than the soil will hold, the excess of water which drains off is necessarily going to carry from the land, a large ]»ercentage of the nitrate of soda, and tlie nitrate remaining in the soil after irrigation is concluded might be easily reduced to such a quantity that a harmful in- fluence could not be exerted on the crop. In otlier words the cane would not get all of tlie nitrate applied and a large per- centage of this material together with a large anu)unt of water would be going to waste. It is seen that such a condition of affairs is possible, and with the light of further data it will be seen to be probabl(\ Where a plantation is using large amounts of nitrate without any signs of an injurious action, and where the water of irri- gation is practically free from salt, a view that ovei-irrigation is practiced can only be based on the non-deleterious action of the nitrate of soda; at the ]»resent time sut!1ci«Mit data for a thorough confirnuition of this opinion are lacking. But if we take a ])lantation that is using nitrate of soda in large (juan- tities and is irrigating with water of high salt content, suflti- cient evidence is at hand to show that a large part of that nitrate is being wasted, and in i)roportion to the amount of w'ater used over and above w^liat is necessary to saturate the soil. This leads us into a consideration of the salt content of irrigation water and of Hawaiian soils, which subject has a particular beai-ing on the question before us. In Bulletin No. 90, V. S. Department of Agriculture, en- 36 titled "Irrigation in Hawaii," is given a table showing tlie l)er('entages of salt that have been found in Hawaiian soils, and the resulting condition of cane growing on those lands. The tabulated results are given in full. SALT FOUND IN HAWAIIAN SUGAR LANDS, AND ITS EFFECT UPON SUGAR CANE. Sample Soil Location. Salt in Soil. Per Cent. Condition of Cane. 1... Highlands .061 .063 .050 .059 .129 .130 .155 .181 .181 .460 .832 .223 Normal. 2.... Normal. 3.... (( Normal. 4 .. 1. Normal. 5... 6.... Lowlands Not wholly healthy. Not wholly healthy. Quite healthy and normal. Yellow in color. Yellow in color. Small, yellow, stunted. ( 'ane white and dying. Leaves bleached, cane small. 7. . . . (( 8 ... 9.... 10 ... 11... 12 ... It Sea bluff land Another table gives the effect of salt upon the growth of cane, on ''three parts of one field which contained different amounts of salt in the soil, the soil in other respects being- identical." First part, . . Second part Third part. FIELD. Salt in Soil. Per Cent. 0.10 0.45 1.00 Yield of sugar per acre. Ton.-. 6.0 1.5 0.0 It is noticed from the first table that where the salt content of the soil reaches over 0.1 per cent an injurious effect is pro- duced on the cane, soil sample No. 7 with 0.155 per cent being an exception. We will now consider the amount of salt that is found in some of our irrigation waters and take for an example, the 37 water of a plantation which is nsing 1,000 ponnds of nitrate of 8oda per acre, malting two applications of 500 pounds each. The manager of this plantation estimates that he is using about 2,500,000 gallons of water ])er acre for the crop, and this water is found on analysis to contain over 125 grains of salt per U. S. gallon. If 2,500,000 gallons of water are being ap- X)lied to the acre, with it go 41,042 pounds of salt, during the growth of one crop. If the land in question were not irrigated to a point above saturation practically none of this water would drain off and the salt would remain in the soil. The weight of an acre of soil to a depth of 12 inches is approxi- mately 3,500,000 pounds, and 44,642 lbs. of salt are practical- ly 1.27 per cent of this amount. This would mean that at the end of five or six irrigations the cane would likely sicken and turn yellow. A certain amount of salt is taken up by the cane itself without ajjparent bad effects, and the percentage remaining in the soil would consequently be lessened but only to a very small degree and not enough to alter these figures to any appreciable extent. However the cane on this plantation is doing well and the salty water is having no apparent effect, which would indicate that the salt from the water is not reaching a harmful accu- mulation in the soil. An undue concentration of salt could only have been prevented by an occassional very heavy rain or by an excessive amount of water used in irrigation. For instance let us say that only so much water was added during five irrigations as the soil would take up and hold. Then this water would evaporate from the surface of the soil and be dis- sipated into the air through the leaves of the cane, leaving the salt behind, and in quantities sufficient to weaken the growth of the cane. If, however, for the sixth irrigation, •double the amount should be used as w^as applied during any of the previous irrigations, the accumulation of salt would be dissolved up and removed in large measure in the drainage from the land. The soil would then be freed from its injurious amount of 38 salt and ajiain be suitable for the growth of the cane. This occasional flushing of the land to such an extent is not likely to occur, however, on an irrigating plantation; the chances are in favor of an excess being applied at each watering, and that the amount that drains off from the land during every irrigation is what keeps the salt down below a harmful pro- portion. The manager of this plantation did not feel that he was using an excess of water, because if he decreased the amount applied, the cane soon showed it. Now on cutting that water down did the cane suffer from too little water or too much salt? To my mind it was more likely the salt which I)roduced the sickening of the cane, because conditions were then made more favorable for an accumulation of that ma- terial. If a soil were irrigated with saline water below a point of saturation, for a number of times, it has been pointed out that the salt solution in the soil necessarily becomes more concen- trated and contains a higher percentage of salt than the irri- gation water. Providing that the drainage from the land is good and an excess of water can find an outlet through under- ground or other channels, the more water that is put on in excess of the amount that the soil will hold, the more dilute will become the salt solution in the soil, until a point is reached in which the solution in the soil is practically of the same density as the irrigation water. The more dilute this salt solution is rendered, naturally the more suitable it is for the growth of the cane. But as soils have a high absorptive power for water varying on these islands between 30 and 87 per cent., it is readily seen that after any irrigation where there is m.uch salt in the water, a considerable quantity of that material must necessarily be left behind in the land no matter how much water is applied. When the next applica tion of water is made, the concentrated solution of the soil is added in large measure to the irrigation applied, and the salt percentage of the latter is increased as it passes into the soil, until an amount is added sufficient to leach through the soil and drain off, when the dilution will set in according to the 39 excess of water applied after that \Hnut is reached. It can readily be seen what may happen when the irrigation is cut down in some instjinces and jtarticnlarly when it is cut down to such a degree as to allow of no di'ain from the laud what- ever. If the supply of water were decreased gradually it is not too much to suppose that before a point is reached at which the cane will suffer from too little water, it will suffer from too much salt. It has been established as a principle in soil physics that if a continuous and rather heavy rain falls evenly upon the sur- face of a homogeneous soil, a column of water is formed in the soil which will as it descends displace a salty solu^^ion without mixing with it to an appreciable extent. If the drain- age of the laud were good, the salt solution would be forced out of the soil into the natural outlet. In irrigation as prac- ticed on these islands, however, I believe that the ditt'usive or diluting action of the applied water would be a more potent factor in removing salt from the land, if the soil were deep and of high absorptive power, than that of mere pressure. This is caused by the water having to be distributed through- out the soil from fewer points of application as compared with rain water, and also by the fact that the salt or salt solution in the hills between the furrows where it is carried by capil- larity, could not be forced out by any column of water descending from the cane furrow. However, the question of pressure cannot be omitted entirely in a consideration of the manner in which salt is removed from the lands of irrigating l»lantations, as its importance will increase with the shallow- •ness of the soil and its inability to hold much water. We have now seen that a plantation which is using very salty water for irrigation purposes must have a well drained soil, and irrigate quite frequently above saturation, in order that the cane may pi-oduce a healthy and normal growth, and we now come to the point upon which this question of irriga- tion bears from a fertilizing standpoint. Under such condi- tions what becomes of the nitrate of soda that is applied in such large quantities to the land? As nitrate of soda is an 40 exti-einely soluble material and is but slightly fixed in the soil, large amounts mu^f be leached from the land and lost through the excess of irrigation water used under the existing conditions, and it is not unreasonable to suppose that the amount of nitrate remaining in the soil is decreased to such an extent, that the effects of this material on the crop do not correspond with the effects of the same material added in like quantities, but under conditions where the cane may appro- priate the full amount. These points in regard to the use of salty water on our cane lands open up a new field for investigation along the line of irrigation, but a consideration of that matter must neces- sarily be left out of a report of this nature. On a plantation where nitrate of soda is being added to the land in considerable quantities at each application, and where the irrigation water contains in solution only a very small amount of salt, we cannot say positively that over-irrigation is practiced, as at the present time data are lacking to sub- stantiate such a view. The fact that such land is able to stand more nitrate than other lands where irrigation is not practiced, but where the full effects of the nitrate are unques- tionably obtained, points to the conclusion that an excess of water may in large measure account for this apparent incon- sistency. The original nitrogen content of the soils and the size of the crop are naturally factors to be taken into consid- eration, but they are not sufiicient to account for such varia- tions in the behavior of nitrate as we have found in some instances. Unfortunately over-irrigation is not always man- ifested in a visible drainage from the land. An excess of water in some instances can sink down into a deep soil below a point from which capillarity can raise it, and find an outlet into an underground reservoir, or along impervious strata into the sea. The necessity of determining the probable loss of nitrate on a plantation such as we have just described would seem to be of more importance than in the case which has already been considered. Not onlv is there a likelihood of so much nitrate 41 being" lost, but with it is bound up the question of water which, economically, is a matter of greater concern. Where irrigation with brackish water is practiced, more water would necessarily have to be used, than would be the case if tin? water were '"sweet," as an occasional over-irrigation is re- quired. However, in both instances a loss of nitrate and a cori'esponding loss of water are conditions capable of amel- ioration, although the degree of conservation of brackish water would vary with its [lercentage of salt. On one plantation where nitrate is used in large amounts, the manager informs me that directions are always given to use less water for the first irrigation following an application of nitrate of soda, and this certainly is a good precaution to observe, as in a measure it constitutes a safe guard against the immediate loss of the nitrate. But if we look into this matter more closely, it can be seen that this practice does not insure completely against a considerable loss of this soluble material, although a certain saving would take place, provid- ing of course, that we assume that over-irrigation is the rule, wdiich still remains to be proven. For instance, let us say that 500 pounds of nitrate are applied, and one-half of the water ordinarily used, is applied at the first irrigation following. Then we may feel reasonably certain that none of the nitrate is lost from the land during that irrigation; but the (luestion arises: Can the cane appropriate all of that 500 pounds of nitrate between the time it is applied and the second irrigation following? Such a period we might say would probably cover ten or twelve days at the most, and we may feel sure that all the nitrate could not possibly be assimilated by the cane in that time. What is not assimilated is then liable to waste during the second irrigation and those following. Although this report is concerned primarily with fertiliz