llJllliKII t y v t f. >v ' blvi: M n K i i Mm vj-lyii iu;r f li\JJii\ J.. v J L mil 1 ill! iliil I HI T. O'CONOR SLOANE, A.M., E. M. r ; ii i Hi i i Hi i !i Hi HUliiih iiii-i'>': ; ' Hi hi • Hi:!!:!!!!: iiM::::i; !!-i!i!jli!{jh iHiilttHHii il?jH:Jij!H|}j i \i\m\ ^^•'.■ : '':';;.::ir: :;:;-'::''':'.: i!p|i III Class Book • — 1^1 ■« i^ Copyright N°_^L^^/i2. COPYRIGHT DEPOSIT. RUBBERHAND STAMPS AND THE MANIPULATION OF RUBBER A PRACTICAL TREATISE ON THE MANUFACTURE OF INDIA RUBBER HAND STAMPS, SMAW, ARTICLES OF INDIA RUBBER, THE USE OF RUBBER IN SURGERY AND DENTISTRY, RUBBER TIRES, THE HEKTOGRAPH, SPECIAL INKS, CEMENTS AND ALUED SUBJECTS ALSO Giving the Sources of India Rubber and Its History— Its Collection— Properties of Unvulcanized and Vulcanized Rubber— The Manufacture of Masticated Mixed Sheet, and Vulcanized India Rubber— Various Vulcanizing and Curing Processes— The Solution of India Rub- ber — Ebonite — Vulcanite — Gutta Percha, Etc. BY T. O'CONOR SLOANE, A.M., E.M., Ph.D. Author of "Arithmetic of Electricity," "Electricity Simplified, "Standard Electrical Dictionary," etc. REVISED THIRD EDITION FULXY HJ.USTRATED NEW YORK THE NORMAN W. HENLEY PUBLISHING CO. 132 Nassau Street 1912 Copyright, 1890, by NORMAN W. HENI.EY & CO. Copyright, 1912, by THE NORMAN W. HENLEY PUBLISHING CO. U ^m £C!.A316115 *i \JV. PREFACE. The present work hardly needs a preface. The object is to present in the simplest form the subject of the manipulation of india rubber. To mould and cure the mixed gum but few appliances are needed, and these can be made at home. The arti- cles produced are of more than ordinary utility. These two facts give value to the art and furnish a raison d'etre for this book. If its instructions do not prove practical it will have missed its object. For some reason the methods of moulding the material are not generally known. Experiment has taught many the futility of attempting to melt and cast it. While thus intractable by the usual meth- ods, it is the most plastic of materials when prop- erly treated. Its power of reproducing the finest details of a mould, of entering all the intricacies and undercuttings of a design, cause one to feel a peculiar pleasure in working with so responsive a material. It is not saying too much to affirm that to some readers this book will disclose a long hidden secret. To make it more generally useful it is writ- iv PREFACE. ten for such readers, to meet the want of those knowing of the subject. It was felt that in follow- ing this course, and in treating the subject from its first steps, including the simplest as well as most advanced methods, the book would appeal to a larger body of readers. The allied subjects to which some chapters are devoted will be acceptable to many readers. The hektograph is given in several modifications. A substitute for rubber stamps which stands the severe usage of the Post Office has very distinct merits, and the manufacture is accordingly described in detail. Cements and inks embody many special formulae. In the last chapter inter- esting and practical notes will be found. For the use of certain cuts we are under obliga- tions to the Buffalo Dental Manufacturing Co., Messrs. E. & F. N. Spon & Co., and to Mr. L. Spang- enberg. Preface to Third Revised Edition This work has been revised and enlarged by the addition of chapters on the Use of Rubber in Sur- gery and Dentistry and the Construction and Re- pairing of Rubber Tires. The addition of this matter, we believe, will greatly interest the reader. June, 1912. CONTENTS. CHAPTER 1. THE SOURCES OF INDIA KUBBER AND ITS HISTORY. The Trees — The Sap — Caoutchouc — Early Uses by the Indians — First knowledge of it in Europe — Good- year, Day, and Mackintosh CHAPTER II. THE NATURAL HISTORY AND COLLECTION OF INDIA RUBBER. African, East Indian, Central and South American Gums — Different Methods of Collection and Coagula- tion 15 CHAPTER III. PROPERTIES OF UNVULCANIZED AND VULCANIZED IN- DIA RUBBER. Properties of Unvulcanized Rubber; its Cohesion and importance of this property — Analysis of Sap and Caoutchouc — Effects of Heat and Cold — Distillation Products — Vulcanized Rubber, and its Properties 24 CHAPTER IV. THE MANUFACTURE OF MASTICATED, MIXED SHEET AND VULCANIZED INDIA KUBBER. Treatment by the Manufacturer — Washing and Sheet- vi CONTENTS. ing — Masticating — Making Sheeting and Threads — Mix- ing — Curing — Coated Tissues 35 CHAPTER V. INDIA RUBBER STAMP MAKING. Mixed Sheet — Outlines of Moulding — Home-Made Vulcanizing Press — Further Simplifications of Same — Securing Accurate Parallelism of Platen and Bed — Dis- tance Pieces — Wood vs. Iron as Material for Press — Use of Springs on the Home-Made Press — Metal Flask Clamps — Large Gas-Heated Vulcanizing Press — Prepar- ing Type Model — The Matrix — Plaster of Paris and Dental Plaster as Substances for Matrices — Dextrine and Gum Arabic Solutions for Mixing Matrix — How Matrix is made — Shellac Solution for Matrix — Matrix Press and Spring-Chase — How to retard the Setting of Plaster of Paris — Oxychloride of Zinc Matrices — Talc Powder — Moulding and Curing the Stamp — Kerosene Heating Stove — Manipulation of Press — Degree of Heat — Simple Test of Curing — Time Required — Combined Matrix Making and Vulcanizing Apparatus — Chamber Vulcanizers — Object of Steam in Vulcanizers — Temper- ature Corresponding to Different Steam Pressures — Jacketed Vulcanizers — Gas Regulator — Flower Pot Vulcanizer — Fish Kettle Vulcanizer — Making Stamps without any Apparatus Whatever — Notes on Type, Quadrats and Spaces — Autograph Stamps 47 CHAPTER VI. INDIA RUBBER TYPE MAKING. Movable Type Making — Simple Flask and Matrix — Precautions as to Quantity of Rubber — Moulding — Curing — Cutting Type Apart — Special Steel Moulds — Wooden Bodied Type ... 73 CONTENTS. vii CHAPTER VII. THE MAKING OF STAMPS AND TYPE FROM VULCAN- IZED INDIA RUBBER. Eeady Vulcanized Gum as Material for Stamps — Simplicity of the Process of Using It — Advantages and Disadvantages — Availability for Type 77 CHAPTER VIII. VARIOUS TYPE MATRICES FOR RUBBER STAMPS AND TYPES. Electrotype Matrices — Papier Mache — Plong Paste — Flong Matrices — Beating into Model — Drying and Bak- ing — Struck-up Matrices — Chalk Plates 80 CHAPTER IX. THE MAKING OF VARIOUS SMALL ARTICLES OF INDIA RUBBER. Suction Discs — Pencil Tips — Cane and Chair Leg Tips — Corks — Mats — Cord and Tubes — Bulbs and Hol- low Toys ...... o 85 CHAPTER X. THE MANIPULATION OF SHEET RUBBER GOODS. Sheet Rubber Articles — Toy Balloons — Uses of Sheet Rubber in the Laboratory 94 CHAPTER XI. VARIOUS VULCANIZING AND CURING PROCESSES. Liquid Curing Baths — Sulphur Bath — Haloids and Nitric Acid as Vulcanizers — Alkaline Sulphides — Sul- phur Absorption Process — Parke's Process 97 CHAPTER XII. THE SOLUTION OF INDIA RUBBER. Mastication with Solvent — Peculiarities of the Pro- viii CONTENTS. cess — Different Solvents and their Properties — Par- affin — Vulcanized Rubber Solution — Aqueous Solu- tion 103 CHAPTER XIII. EBONITE, VULCANITE AND GUTTA PERCHA. Ebonite and Vulcanite — Manufacture — Manipula- tion — Gutta Percha and its Manipulation 108 CHAPTER XIV. GLUE OR COMPOSITION STAMPS. Substitute for Rubber Stamps — The United States Government Formula — Models and Moulds — Dating — Handles 113 CHAPTER XV. RUBBER IN SURGERY AND DENTISTRY. Rubber in Surgery and Dentistry 121 CHAPTER XVI. RUBBER TIRES. Constructing and Repairing Rubber Vehicle Tires — Rubber Preparations — Chemical or Cold Vulcanizing 127 CHAPTER XVII. THE HEKTOGRAPH. How Made — The French Government Formula — Hektograph Sheets 142 CHAPTER XVIII. CEMENTS. Marine Glue, and other special Cements 1 46 CHAPTER XIX. INKS. Hektograph, Stencil and Marking Inks — White and Metallic Inks 150 CHAPTER XX. MISCELLANEOUS. Preservation and Renovation of India Rubber — Burned Rubber for Artists — India Rubber Substitutes — General Notes of Interest 155 RUBBER HAND STAMP MAKING AND THE MANIPULATION OF RUBBER. CHAPTER I. THE SOURCES OF INDIA RUBBER AND ITS HISTORY. India rubber or caoutchouc is a very peculiar product, which is found in and extracted from the juice of certain trees and shrubs. These are quite numerous and are referred for the most part to the following families: Euphorbiacesed, Urticaceaed, Ar- tocarpeaad, Asclepiadaceaed, and (Jinchonacea?d. It is evident that a considerable number of trees are utilized in commerce for its production, and it is certain that it exists, quite widely distributed, in many cases as a constituent of the juice of plants not recognized as containing it. When an india rubber tree is tapped, which is effected by making incisions in the bark, the sap of the tree exudes. It is a milky substance and is collected in various ways; it may be in vessels of 10 RUBBER HAND STAMP MAKING clay, in shells, or in other receptacles by the india rubber hunters. If this substance is examined it is found to be of very remarkable and characteristic constitution, resembling in its physical features ordinary milk. It is composed of from fifty to ninety per cent, of water, in which is suspended in microscopic globules, like the cream in milk, the desired caoutchouc or india rubber. If the juice is left to stand in vessels, like milk in a creamery, the globules rise to the surface, and a cream of india rubber can be skimmed off from the surface. If the juice is evaporated over a fire, the water escapes and the india rubber remains. By dipping an article repeatedly in the juice and drying it, a thick or thin coating of india rubber can be developed. Before the modern methods for the manipulation of the gum had been developed, and before the inven- tion of vulcanization, this method was adopted for the manufacture of shoes. The original " india rubbers " for protection of the feet in wet weather were made in this manner. A clay last was used, upon which the india rubber was deposited as described. The clay last was then broken out and removed. Great quantities of overshoes were thus made in South America, and many were exported to Europe. When caoutchouc has once been removed from this watery emulsion, which for all practical pur- poses is a solution, it cannot be restored to the former state of liquidity; it remains solid. It will AND THE MANIPULATION OF RUBBER. 11 absorb a considerable quantity of water, but will not enter again into the quasi solution or combina- tion. This property of permanent coagulation, which interferes to a degree with its easy manipula- tion, was early discovered. In the last century quantities of the natural milk were exported to Europe to be used in what may be termed the nat- ural process of manufacture, because once solidified it could not be redissolved, and because the manu- facturers of those days had not the present methods of dealing with the apparently intractable gum. The natives of South America before the advent of Europeans, were familiar with the treatment of the juice by evaporation just described and used to make bottles, shoes and syringes of it for their own use. The name Siphonia applied to several species of rubber tree, and seringa (caoutchouc) and seringari (caoutchouc gatherer) in Spanish recall the old Indian syringes and tubes. The gum is now collected for export in many parts of the world. South and Central America are, as they have always been, the greatest produ- cers. Some is collected in Africa, Java and India. The best comes from Para. However carefully treated a great difference is found in the product from different countries. The Brazilian india rub- ber, known as Para, from the port of shipment, ranks as the best in the market. Its history as far as recorded, does not go back of the last century. Le Oondamine, who explored the 12 RUBBER HAND STAMP MAKING Amazon River, sent from South America in 1736 to the Institute de France, in Paris, the first sample of india rubber ever seen in Europe. He accompanied the sample with a communication. He said that the Indians of that country used the gum in making several domestic objects of utility, such as vessels, bottles, boots, waterproof clothing, etc. He stated that it was attacked and to a certain extent dis- solved by warm nut oil. In 1751 and 1768 other samples were received through MM. Fresnau and Maequer, who sent them to the Academy of Sci- ences, Paris, from Cayenne in Guiana. Although from this period numerous exj^eriments were tried with the new substance little of impor- tance was done with it for many years. Its first use was to rub out pencil marks, whence it derived its name of " india rubber." As late as 1820 this con- tinued to be its principal use. An interesting reminiscence of its early history is given by Joseph Priestley, the great English chemist of the last century, celebrated as the discoverer of oxygen. In 1770 he mentioned the use of the gum for erasing pencil marks, and speaks of its cost being three shillings, about seventy cents, for " a cubical piece of about half an inch." As we have seen, its solubility was early studied. In 1761 Herissant added turpentine, ether and "huile de Dippel " to the list of solvents. In 1793 its solubility was utilized in France by Besson, who made waterproof cloth. In 1797 Johnson intro- AND THE MANIPULATION OF RUBBER. 13 duced for the same manufacture a solution in mixed turpentine and alcohol. The year 1820 is the beginning of the period of its modern use on a more extended scale. Nadier developed the methods of cutting it into sheets and threads and of weaving the latter. Mackintosh in 1823 began the manufacture of waterproof cloth, using the solution of the gum in coal tar naptha, which was caused to deposit by evaporation a layer of the gum upon a piece of cloth which was covered by a second one. This protected the wearer from the gummy and sticky coating of raw india rubber. At the best the original Mackintoshes must have been very disagreeable articles for wear. In 1825 india rubber shoes of raw india rubber were imported from South America and formed for a while an important article of commerce. In 1839 Charles Goodyear, of Massachusetts, in- vented the art of vulcanizing, or combining india rubber with sulphur. It was patented on June 15, 1844, and covers only the manufacture of soft rub- ber. Vulcanite or hard rubber (whalebone rubber) is disputed as to its origin, its invention being assigned by some to Nelson Goodyear and by others to Austin G. Day, of Connecticut. Goodyear how- ever succeeded in obtaining a patent on May 6, 1851. Day obtained a patent on August 10, 1858. Vulcanization is the most important invention ever made in connection with india rubber and may fairlv rank as one of the greatest discoveries of the 14 HUB BEE HAND STAMP MAKING present century. It is claimed by the English, an inventor named Handcock being cited as the rival of Charles Goodyear. The latter inventor had as an associate Nathaniel Hayward, who is probably entitled to some of the credit. By vulcanization india rubber loses susceptibility to heat and cold, becomes non-adherent, and insol- uble in almost all substances. It is converted from a comparatively useless substance into one of wide applicability. The subject of india rubber is so interesting in its theoretical as well as practical bearings that it seems impossible that those who are workers in it should not feel an interest in its natural history. For such readers the chapter on the natural history and collection of india rubber has been written. As it is a product of widely separated lands on both hemispheres, and as it is yielded by an immense number of plants, it is impossible in the limits of a chapter to give a full outline of its natural history. The chapter in question is, therefore, with this apology, inserted where it belongs, near the begin- ning of the book. Those who are entirely practical may pass it over. There is no doubt that the few minutes necessary for its perusal will be bestowed upon it by some. CHAPTER II. THE NATURAL HISTORY AND COLLECTION OF INDIA RUBBER. • African india rubber is mostly exported from the west coast. The belt of country producing it extends nearly across the continent. Those who are familiar with the india rubber plants of our conser- vatories are apt to think of the gum as the product of trees, but in Africa it is largely yielded by climb- ing plants of very numerous varieties, belonging generally to the Landolphia species. It is collected by the natives by careless or desultory methods, probably less advanced than the ways followed by the South Americans. Possibly its marked inferior- ity may be partly attributed to this. It is also sup- posed by many that, were the gathering restricted to the vine producing the best gum, better results would follow. As it is now all gums are mixed indiscriminately. African gum is of very inferior quality. The African india rubber vines grow often in dark moist ravines, where no valuable product other than themselves could be cultivated. They are entirely wild. The vines when cut exude an abun- 16 RUBBER HAND STAMP MAKING dance of sap, which differs from the South Amer- ican product in its quickness of coagulation. As it escapes from the wound it at once solidifies and pre- vents the further escape of juice. The negroes are said to employ the following highly original method of collecting it. They make long gashes in the bark. As fast as the milky juice comes out they wipe it off with their fingers and wipe these in turn on their arms, shoulders, and body. In this way they form a thick covering of inspissated juice or caoutchouc over the upper part of their body. This from time to time is removed by peeling. It is then said to be cut up and boiled in water. This is one account. According to others the natives remove a large piece of bark, so that the juice runs out and is collected in holes in the earth or on leaves. Wooden vessels are said to be used else- where. Sometimes the juice is said to be collected upon the arms, the dried caoutchouc coming off in the shape of tubes. A clew to the inferiority of African india rubber is afforded by the statement that too deep a cut liberates a gum which deterior- ates the regular product if it mixes with it. The drying of the gum is thought to have much to do with its quality and it is highly probable that this affects the African product. Some samples seem to be partly decomposed they are so highly offensive in odor. The South American rubber is often dried in thin layers, one over the other, by a smoky fire, which may have an antiseptic effect upon the newly A XD THE MAN IP UL A TION OF B UBBER. 1 7 coagulated caoutchouc. ISo such process as far as known is used in Africa. The African india rubber appears under different names in commerce. From the Congo region lumps of no particular shape called ei knuckles " ; from Sierra Leone smooth lumps, "negro-heads," and "balls " made up of small scrap ; from the Portu- guese ports "thimbles/' "nuts," and "negro- heads: " from the gaboon (i tongues; " and from Liberia "balls are received.''' It is all character- ized by great adhesiveness and low elasticity. From Assam, Java, Penang, and Rangoon there is considerable gum exported. It is supposed to be the product of trees of the ficus species, in all these places, as it is known to be in Java and Assam. In the latter place rigid restrictions are imposed as far as possible upon the gathering. In the case of wild trees scattered through the forest the carrying out of these restrictions is not practicable. The trees are cut with knives in long incisions through the bark and the juice is collected in holes dug in the ground, or often in leaves wrapped up into a conical form, somewhat as grocers form their wrap- ping paper into cornucopia shape for holding- sugar, etc. It has seemed reasonably certain that the india rubber producing plants might be cultivated with profit, and it is as certainly to be feared that without such cultivation they will become extinct. Efforts have been made in the direction of raisings 18 RUBBER HAND STAMP MAKING them artificially but without much success. In Assam numerous experiments have been made to propagate the india rubber bearing ficus tree. A good instance of the ill effects of carelessness in the original gathering of the crop is afforded by the Bornese collectors. The source of Borneo india rubber is a variety of creepers. These are cut down and divided into short sections from a few inches to a yard in length. The sap oozes out from the ends. To accelerate its escape the pieces are sometimes heated at one end. It is coagulated by salt water. Sometimes a salt called nipa salt, ob- tained by burning a certain plant {nipa fruticans), is used for the purpose. In either case it is coagulated Tree Felled for Collection of India Rubber. into rough balls and masses. These masses are heavily charged with the salt water, often contain- ing as much as fifty per cent., and rarely much less than twenty per cent. Central America and Panama are great producers of the gum. In Panama the custom of felling the AND THE MANIPULATION OF RUBBER. 19 trees is often adopted. In this case grooves are cut around the prostrate trunk, and under each groove as the trunk lies on the ground a vessel is placed to collect the sap. Its coagulation is often effected by leaving it for a couple of weeks standing at rest in a hole, excavated on the surface of the ground, and covered over with leaves. The caoutchouc sepa- rates under these conditions. A quicker method, but one yielding an inferior product, is obtained by adding to the fresh juice some bruised leaves of a plant (iponwa bona nox) which acts something like acid upon milk, in separating the desired solid matter or caoutchouc. A jelly like accretion satu- rated with blackish water is thus obtained. By working it together a blackish liquid is caused to escape, and comparatively pure gum is gradually obtained. As much as one hundred pounds of india rubber may be obtained from a single tree where this destructive system is employed. Fur- ther north, where a better counsel has prevailed, the trees are only tapped, and the india rubber hunter is satisfied if from a tree eighteen inches in diam- eter he obtains twenty gallons of sap, giving fifty pounds of gum. Even where tapping is done the tree is often destroyed by carelessness or ignor- ance. Two systems are followed in Nicaragua. The oper- ator ascends by a ladder if he has one, or in any case climbs as high as he well can and begins to make a long incision. Sometimes he carries one long straight 20 RUBBER HAND STAMP MAKING cut clear down to the ground. This is made the starting point for a number of side cuts, short, and running diagonally into it. This is also one of the Brazilian methods. The Nicaraguan sometimes also makes two spiral incisions, one right-handed and the other left-handed, crossing each other as they descend so as to divide the surface of the tree into roughly outlined diamonds. In either case the juice flows down to an iron spout, placed at the bottom of the tree, which sj)Out leads to an iron pail. The milk is gathered and passed through a sieve, and coagulated in barrels by the ipomcea plant as before mentioned. This gives three grades of rubber. The bulk is obtained from the barrels and is called often meros; the small lump which forms in the spout is rolled into a ball and called cabezza; the dried strips pulled out of the cuts is of very good quality and is called bola or burucha. From Brazil is exported the famous Para iudia rubber. This is of very high quality, and is greatly esteemed by all manufacturers. No process can make a poor gum give a really good product. The system of gathering it varies. Sometimes the tree is cut into by gashes from an axe, such gashes ex- tending in a row all around the trunk. Under each gash a small clay cup is luted fast with some fresh mixed clay. These collect from a tablespoonful of juice upward, which is collected, and the cups are removed on the same day. The next day a second row of cuts is made below the others, and the same AND THE M . i N I P UL A TION OF R UBBEE. 2 1 process is repeated. This is continued until from a point as high as a man can reach, down to the ground the tree is full of cuts. Sometimes a gutter of clay is found partly around the trunk with gashes above it. In other cases a vine is secured ?5^ Tree Tapped for India Rubber. around the tree and a collecting gutter is worked with it for a basis. The juice is coagulated in a smoky fire. A bot- tomless jar is placed over the fire and some palm nuts are mixed with the fuel. The mould, which is often a canoe paddle, is smeared with clay to pre- vent adhesion and is then heated. A cup of juice is poured over it, and after the excess has dropped off it is moved about rapidly over the smoke and 22 RUBBER HAND STAMP MAKING hot air which ascends from the mouth of the jar. This series of operations is repeated until the coat- ing is quite thick; it may be as much as five inches. After solidifying over night it is cut open and the paddle or mould is removed. After a few days dry- Indian Drying and Smoking India Rubber. ing it is sent to market. With all the heating, during which it sweats profusely, it still retains fifteen per cent, of water. India rubber sap may be coagulated by an aqueous solution of alum. The process has been tried in Brazil, and is used to a considerable extent in AND THE MANIPULATION OF RUBBEli. 23 Pernambuco. It was proposed by an investigator named Strauss, and the process is still called by his name. One objection is that it gives a very wet product, and apparently one of inferior value to the smoked gum. The feeling that india rubber suffers in the gath- ering has been so much felt that it has been re- cently suggested that if possible the uncoagulated juice should be exported to Europe there to be worked up from the beginning. CHAPTER III. PROPERTIES OF UNVULCANIZED AND VULCANIZED INDIA RUBBER. There are two broad divisions to which all varie- ties of india rubber can be assigned — nnvulcanized and vulcanized rubber. Speaking with a certain amount of license it may be said that more proper- ties characterize the former than the latter. The vulcanized article is very slightly affected by ordi- nary changes of temperature, cannot to any consid- erable extent be changed by heat short of absolute destruction or decomposition, cannot be united or moulded except in simple forms, is highly elastic, and is insoluble in almost every solvent for ordinary caoutchouc. Unvulcanized caoutchouc possesses very interest- ing and peculiar properties. The first part of the present chapter is devoted to this substance. Those who have never seen the crude gum as imported are familiar with the article almost pure in the form of sheet rubber and black rubber articles generally. These are of nearly pure caoutchouc, though recently the tendency is to vulcanize them to a considerable degree. AND THE MANIPULATION OF RUBBER. 25 A piece of pure gum containing no combined sulphur, iodine, or other vulcanizing constituent will be found to exhibit a very striking peculiarity. Two freshly cut surfaces when placed in contact will adhere. This is not in consequence of any viscous or sticky coating. When india rubber is cut the surface is perfectly dry and non-adherent except to itself. The writer once had this property of adhesion brought strongly to his attention. In some analyt- ical investigations of coal gas he had proposed to use finely divided india rubber as an absorbent of sulphur. This constituent it absorbs from gas. and it seemed that a basis for a quantitative determina- tion of sulphur might be found in such property. Accordingly some raw india rubber was procured and with some trouble was cut up into little pieces which were put into a bottle. A day or two after- wards the pieces united wherever they were in con- tact, and an irregular cavernous lump was the result. This involved no melting or softening or change of shape. Each little piece was there intact and distinct but firmly attached to its neighbors. The analogy of this action is seen in lead. Two fresh surfaces brought together, preferably with a twisting or wrenching pressure, adhere quite firmly. The adherence of india rubber and of lead each to itself is often exhibited by physical lecturers as an illustration of cohesion. The cohesion of india rubber is however far more perfect than that of 26 RUBBER HAND STAMP MAKING lead, probably because of its comparatively great resistance to oxidation, and because, owing to its elasticity larger areas can be brought in contact. Comparatively great though this resistance to oxi- dation is, oxygen, especially in the allotropic modi- fication known as ozone, may act quite powerfully on the gum. Sunlight also can affect it injuri- ously. A more familiar illustration of the uniting of two pieces of the same material is seen in the welding of iron. The blacksmith heats two pieces of iron until they are nearly white hot and are pasty in consistency. On placing them in contact and ham- mering to force them together they unite so firmly as to be practically one. It is necessary that the surfaces of clean metal should be brought together. If the pressure induced by the hammering is insuf- ficient to bring this about, a flux is added which dissolves the oxide and causes the metal to come in contact with metal and to weld. The analogy with india rubber in its cohesive action is evident. Sur- faces long exposed or which are dusty do not cohere. The regelation of ice is similar in effect. The cohesion of india rubber is important and should be thoroughly appreciated. It is not saying too much to assert that the entire treatment of the raw gum depends upon this interesting property. The great lumps of gum are torn to pieces and washed free from gravel and dirt without going to powder, because owing to their elasticity they yield AND THE MANIPULATION OF BUBBER. 27 and as fast as torn apart the pieces tend to reunite. Again india rubber is mixed with pigments and vul- canizing reagents by a method practically one of grinding or masticating, but the material while it changes its shape, and by the admixture of the. va- rious ingredients becomes less strong or easier torn, still remains intact, as it welds together or coheres as fast as disintegrated. As regards its chemical constitution the sap of a Para rubber tree has been analyzed with the follow- ing general results: (Faraday). Caoutchouc 80.70 Albuminous, extractive, and saline matter, etc 12.93 Water 56.37 100.00 Its specific gravity is 1.012. Caoutchouc itself or raw india rubber is a mixture of several hydrocarbons of the following composi- tion in general: Carbon 87.5 Hydrogen 12.5 100.0 Its specific gravity is from .912 to .942. The hydrocarbons composing it are isomeric or polymeric with turpentine. This fact brings it well within the range of familiar vegetable products. As will be seen the products of its distillation fall among the same polymers and isomers. 28 RUBBER HANB STAMP MAKING When pure it is nearly colorless, the dark color being due to impurities. In thin sheets it is almost or quite transparent. It burns readily, and with a very luminous, smoky flame, as might have been anticipated from its composition. The action of heat and cold on it is dependent on the degree of the temperature. At ordinary temperature it is elastic and firm. It can be stretched and will re- turn almost to its original size when released from tension. Yet the return to its shape is so liable to be incomplete, especially after long sustained stretching, that pure unvulcanized india rubber is considered imperfectly elastic. Any elasticity it possesses is principally elasticity of shape as distinguished from elasticity of volume. In other words when pressed or stretched it may change shape to a great extent but hardly change its volume at all. A cube of 2^ inches under a weight of 200 tons lost 1-10 of its volume only. This is largely due to the fact that it represents an approximately solid body, or one destitute of consid- erable physical pores. Solids and liquids are very slightly compressible. Whatever degree of com- pressibility caoutchouc possesses is due principally to its minute pores. If the temperature is reduced to the freezing point of water a piece of raw india rubber becomes rigid and stiff. On application of heat it returns to its former pliable condition. The same return to flexibility may be brought about by stretching it AND THE MANIPULATION OF RUBBER. 29 mechanically. This may be rather a fallacy. Stretching india rubber warms it, so that in this mechanically imparted rise of temperature we may find at least a probable cause of the softening. If the temperature is raised several effects are produced, according to circumstances. A piece which has been stretched and held stretched, has its tension increased by a degree of heat considerably less than that of boiling water. Some offer the theory that it contains air enclosed in its pores which, expanding, produces this effect. As the boiling point is reached the material softens and becomes somewhat plastic, so that it can be moulded into shape to a considerable extent and stretched to threads of great fineness. Its elasticity also disap- pears as the heat is maintained. These effects in- crease in extent up to a heat of 248° F. (120 3 C). The return to its original state is not immediate however. Some time is required before the reduc- tion of temperature will have full effect. If now a still higher degree of heat is applied, 392° F. (200° C.) the india rubber softens to a viscous body, or melts. From this state it cannot be restored. It remains permanently "burned" or melted whatever is done to it. Some attempt at hardening may be made by the use of vulcanizing chemicals, but the result will be very imperfect. A further increase of heat brings about a destruc- tive distillation. India rubber treated in a retort to a heat exceeding 400° F. (204° C.) evolves volatile BO EUBBEli HAND STAMP MAKING hydrocarbons of oily consistency, and it distills almost completely, a small residue of gummy mat- ter or of coke if the final heat has been pushed far enough being left. The distillate is called caout- choucin. According to Mr. Greville Williams it con- sists of two polymeric hydrocarbons : one, caout- chin C 10 H 16 , boiling point 340° F. (171° C); the other, isoprene C 5 H 8 (in formula equal to one-half of caoutchin), boiling point 99° F. (37° C). The mixture has a strong naptha-like odor and has won considerable reputation as being the best solvent for india rubber. How far it deserves its reputation is a matter open to discussion. The solution of india rubber like its fusion is a vexed point. There is little question that it can be dissolved by proper treatment. Usually naptha, carbon disulphide or benzole are used as solvents, the choice being guided by motives of cheapness and efficiency. It is worthy of remark that the formula given for caoutchoucin is the same as that of the principal constituent of oil of turpentine, and that the latter is often recommended as a solvent. Turpentine is slightly more volatile than caoutchoucin, its boiling point being 322° F. (161° C.) Other hydrocarbons have been recognized in the distillate by Bou- chardat, Himly and G-. Williams, varying in boiling point from 32° F. (0° C.) to 599° F. (315° C), and in specific gravity from 0.630 to 0.921. Although it has been spoken of as approximately AND THE MANIPULATION OF RUBBER. 31 solid it does possess microscopic pores, to which its limited amount of elasticity of volume is mostly due. Thus it is found to absorb water, in which it is quite insoluble. As it does this it acts like a dry sponge and increases in volume a little, owing to dilation of these minute pores. The water absorbed may be as much as 18.7 to 26.4 per cent, with an in- crease of volume of the gum of i&h> to T Mo. When it has once absorbed water it is very hard to get rid of it. Although the minute surface orifices commu- nicate with the entire system of capillary vessels and pores, the surface pores on drying contract and seal up the absorbed water within the mass. This is a clew to the impracticability of the gatherer ship- ping dry rubber, and to the great difficulty the manufacturer experiences in drying his washed and sheeted stock before working it up by masticating or mixing and curing. By proper manipulation caoutchouc may be made inelastic. This can be done by the freezing process or by keeping it stretched for two or three weeks. In this way threads can be made to extend and to remain extended to seven or eight times their orig- inal length. They can then be woven into a fabric. On gentle heating their original elasticity reappears and they contract. In this way fluted braids can be made which will have a high capacity for stretch- ing. The solution of caoutchouc is difficult often to bring about. We have seen that in water it swells 32 RUBBER HANI) STAMP MAKING a little without dissolving. In benzole it does the same, but swells to a greater extent, to 125 times its original volume or even more. Some authorities ( Watts) go so far as to assert that no solvent com- pletely dissolves it. Acting on it repeatedly with benzole or other solvent and taking care not to break up the swelled mass, from 49 to 60 per cent, of soluble matter can be extracted. On evaporation this is deposited as a ductile adherent film. The swelled up residue which remains undissolved is assumed to be the constituent giving strength and elasticity, and is only sparingly soluble. If the gum is masticated or kneaded at the temperature of boiling water a change occurs not well understood, by which its solubility is greatly increased. As solvents many liquids have been named. Oil of turpentine, caoutchoucin, coal-tar, naptha, benzole, petroleum-naptha, coal-tar-naptha, anhydrous ether, many essential oils, chloroform, bisulphide of car- bon, pure, or mixed with seven or eight per cent, of alcohol, are among the solvents recommended. A mixture of fifty parts ot benzole and seventy parts of rectified turpentine has been given as a solvent for twenty-six parts of the gum. Mastication be- fore or after immersion in the solvent is to be advised. More will be said on this subject in a succeeding chapter. Vulcanized india rubber is unaffected by changes of temperature within ordinary range. It softens a little on heating. Even hard vulcanite when heated AND THE MANIPULATION OF RUBBER. 33 can be bent and will retain the bend on cooling. It is exceedingly elastic with elasticity of shape but far less compressible as regards absolute change of volume than the raw gum. It melts at 392° F. (200° C.) It cannot be made to cohere, and no cement has yet been discovered that will satisfac- torily unite two surfaces. It is unaffected by light, by ordinary acids and rubber solvents. In contact with the latter solvents it swells sometimes to nine times its original volume, but on heating returns to its original volume and shape. Of water it will absorb no more than four per cent, and often much less. If it is maintained at a high temperature 266° to 302° F. (130° to 150° C.) for a long time it gradually loses its flexibility, especially if in con- tact with metals. Often the escape of sulphuretted hydrogen may be observed under these conditions. A small admixture of coal tar operates to prevent this action. Its composition and specific gravity vary widely as the most varied mixtures are added by the manu- facturer. Its relation of carbon to hydrogen is unaffected by the mixtures added. While it may contain twenty per cent, or more of sulphur it is believed that but a very small quantity is combined with it, although the excess of sulphur or some equivalent, such as sulphide of antimony is essen- tial to vulcanization. The combined sulphur is from one to two per cent. Some or all of the ex- cess of sulphur is mechanically retained, and as the 34 BUB B Eli HAND STAMP MAKING rubber in ordinary use is worked about, keeps escap- ing and forms a whitish dust upon the surface. By treatment with alkali some of the excess of sulphur can be removed when the rubber acquires the power of absorbing a little more water, up to six and four- tenths per cent. Boiling oil of turpentine is given as its solvent. CHAPTER IV. THE MANUFACTURE OF MASTICATED, MIXED SHEET, AND VULCANIZED INDIA RUBBER. The manufacture of india rubber relates to the production of two principal products. One is mas- ticated unvulcanized sheet and thread rubber; the other is un masticated mixed and cured rubber, otherwise vulcanized rubber. For the purposes of the rubber-stamp maker an intermediate product is required, namely, unmasticated mixed sheet which is uncured. This is really incompletely vulcanized india rubber. It will be evident from the description to come that it is not advisable for any one without consider- able apparatus to attempt to clean and to wash (" to sheet"), to masticate, or to mix india rubber. These operations are best accomplished in the fac- tories. The partially vulcanized (''mixed sheet") or the pure masticated article are regular articles of commerce. Yet a full insight into the manipula- tion of india rubber can only be obtained by under- standing its treatment from the gum up to the two separate lines of products we have indicated. A third type of product is coated tissue, such as 36 RUBBER HANB STAMP MAKING Mackintosh. This really is a sequence of one of the other two processes and a few words will be said of it in concluding the chapter. As the caoutchouc is received' by the manufac- turer it appears an utterly intractable mass. It occurs in lumps of every size, varying in color and odor, and very tough but elastic. In virtue how- ever of the properties already described, its power of cohering when cut, and its softening when heated, it becomes amenable to treatment. It is to some extent received in such assorted condition as to secure even grades, and then each grade may be washed by itself. It is thrown into water which is in many cases kept at the boiling point by steam-heat and left there for some hours. It absorbs some water and also softens. Some gum is so soft that it will not stand hot water. For such the water is kept cold. The purer gum floats; such pieces as have stones, dirt, iron, etc. in them, per- haps placed there purposely from fraudulent motives, sink and can be picked out for separate treatment. The lumps are next cut up. A revolving circular knife driven by power is often used, and sometimes an ordinary knife is adopted. At this part of the operation there is frequently need for sorting, as the grades received may have inferior pieces mixed witli the good. The cutting is mainly to secure good grading, and to remove concealed impurities. The gum then goes to the washing rollers, called the washer and sheeter. (See cut, p. 37.) AND THE MANIPULATION OF RUBBER. 37 These are heavy corrugated rolls made very short, 9-18 inches in length, to prevent springing. They are grooved or corrugated and have a screw adjust- ment for regulating their distance apart. They are geared together so as to work in corresponding directions, like a clothes wringer or a rolling mill of any kind. The pieces of gum are fed into the Washer and Sheeter. roils and are drawn between and through them. The friction tends to heat the gum. To prevent this and also to effect the washing, a supply of water, either hot or cold, is kept playing upon the mass. This dissolves out all soluble matter and washes away mechanically the chips, dirt, etc. which may be present. The whole operation is one of main force. The caoutchouc is torn and dis- tended and delivered as a rough perforated sheet. It is passed repeatedly through the machine, the rollers being gradually brought closer together, or else different sets of rolls are used, set to different 38 RUBBER HAND STAMP MAKING degrees of fineness. The wash water passes through a screen which catches any small detached frag- ments of gum. Other types of machines have been introduced; the above is a representative form. The rough sheets must now be perfectly dried, as water impairs the final product. This is done in drying rooms by steam heat, generally, at a temper- ature of about 90° F. (32° 0.) The windows, if there are any, are painted to exclude sunlight, which operates to deteriorate raw gum. When absolutely dry the caoutchouc is removed and stacked away for use. Masticating Machine. To prepare pure gum for the manufacture of sheet rubber and as a starting point for many other preparations, the india rubber is " masticated " in AND THE MANIPULATION OF RUBBER. 39 special apparatus. The machine consists of a fixed cylinder within which is a corrugated roller set eccentrically and rotated by power. The perfectly dry sheets in the masticator are pressed and rolled and ground and produce a mass of even consistency. Here the welding or cohering action again appears in its fullest development. The perfect dryness of the mass enables it to keep reuniting as fast as divided. The action is assisted by the heat gener- ated, which is not inconsiderable. Sometimes the caoutchouc is warmed before introduction, and sometimes the roller is heated by passing steam through it. Masticating Machine. The masticating machine the French pictur- esquely term the wolf (Joup) or devil ((liable). It is given from sixty to one hundred turns a minute, and a machine large enough to treat fifty pounds of 40 BUBBEli HAND STAMP MAKING gum in a charge, requires five horse-power to drive- it. In it the sheeted gum is ultimately brought to the state of a perfectly homogeneous dark brown translucent mass. The masticated rubber is peculiarly amenable to mechanical and chemical treatment. It can fee shaped by heat and pressure, and it is the most soluble form and is used for making cement and solution, and is moulded into blocks for the manu- facture of sheet and thread rubber. In the process neutral body pigments, such as oxide of zinc, or sol- uble transparent ones, such as alkanine may be intro- duced; easily decomposed matter cannot be incorpo- rated on account of the heat. In all these machines special provision is made to prevent any oil from getting into the gum. There is no greater enemy to india rubber than oil or fats of any description. The flanges in the mas- ticator that roll just inside the bearing are for this purpose. Sheet rubber is made from the blocks of masti- cated gum by slicing. A machine is used for the purpose which carries a knife which works back and forth in the direction of its length at high speed, making two thousand cuts a minute. The knife is kept wet by a stream of water, and about sixty cuts are made per inch. In many articles made from this sheet the marks of the cuts can be seen as a fine ribbing. The appearance is familiar to many readers. AND THE MANIPULATION OF RUBBER. 41 The sheet is often cut from rectangular blocks, but cylindrical blocks are also used. The latter are rotated in front of the knife edge and a long, con- tinuous sheet can thus be obtained. The sheet rubber can be cut into threads on web- bing and braid. Everyone has noticed that these threads are usually square. The method of prepa- ration accounts for it. Vulcanized sheet is now almost universally used for threads. Round threads however can be made by forcing softened or partly dissolved gum through a die. It is from unvulcanized masticated sheet that toy balloons, tobacco pouches, etc., are made. It is the starting point for india rubber bands. For the usual form of the latter article the sheet is cemented into a long tube which is afterwards cut transversely, giving bands of any desired width. To make any of these articles satisfactory vulcanization is imper- ative. Uu vulcanized rubber for many years was used, but it is "now completely displaced by the vulcanized product. Sheet rubber is made as above; is vulcanized by some of the absorption processes described in the chapter on vulcanization. We now come to the second product: regularly mixed and cured rubber. Its starting point is the washed india rubber from the washer and sheeter. We have seen that the pure gum or caoutchouc is very sensitive to changes of temperature. At the freezing point of water it is hard and rigid, and at 42 EUBBEB HAND STAMP MAKING the boiling point is like putty in consistency. There are several substances which can be made to combine with the gum and which remove from it this susceptibility to change of temperature. The process of effecting this combination is called vul- canization, and the product is called vulcanized india rubber. Sulphur is the agent most generally employed. In the factory the normal vulcanization is carried out in two steps, mixing and curing. The washed sheet india rubber which has not been masticated and which must be perfectly dry is the starting Making Mixed Rubber. point, and the mixing rolls shown in the cuts are the mechanism for carrying out the first step. These are a pair of powerful rollers which are geared so as to work like ordinary rolls, except that one revolves AND THE MANIPULATION OF RUBBER. 43 about three times as fast as the other. They are heated by steam, which is introduced inside of them. The sheet is first passed through them a few times to secure its softness, and then the opera- tive begins to sprinkle sulphur upon it as it enters the rolls. This is continued, the rubber passing and repassing until perfect incorporation is secured. About ten per cent, of sulphur is added, and a work- man can take care of thirty pounds at a time. This material is incompletely vulcanized. It is in its present condition very amenable to hetit and is ready for any moulding process. Generally it is rolled out or " calendered " into sheets of different thickness from which articles are made in moulds by curing. These sheets are of especial interest to the reader as they are the material from which most small arti- cles are made, including rubber stamps. This rolling of the mixed india rubber into sheets of definite thickness is done by special calendering rolls. The product is termed " mixed sheet." In the mixing rolls the incorporation of other material is often brought about. Zinc white, lead sulphide, antimony sulphide, chalk, clay, talc, barium sulphate, plaster of paris, zinc sulphide, lead sulphate, white lead, oxides of lead, magnesia, silica, form a list of ordinary mixing ingredients. These lower the cost of the finished material and are often serious adulterants. For some cases the addi- tion if not carried too far is not injurious, or even 44 RUBBER HAND STAMP MAKING may be beneficial. A proper admixture renders the gum more easily moulded and treated in the shap- ing processes. Mixing Rolls. The next step in the vulcanizing process is the heating of the mass, which step is called " curing. " Up to a temperature in the neighborhood of that of boiling water the mixed rubber can be heated with- out change except as it is softened. But if the heat is increased it begins to get a little more elastic and less doughy, and eventually becomes i( cured " or vulcanized. The temperature for vulcanization is about 284° F. (140° C). The word " about " is used advisedly, for it is not only a question of heat but of time of exposure. After vulcanizing, including the curing, india rubber cannot be moulded to any great extent. In the manufacturing process, there- fore, it is before curing placed in the moulds, AND THE MANIPULATION OF RUBBER. 45 heated, shaped by pressure, and by exposure to a higher heat in a steam oven called a vulcanizer, is at once cured. To prevent adherence to the moulds they are dusted over with ground soapstone, and the rubber itself is often thus coated. The methods of vulcanization and curing, which may be of special use to the reader, are given in the chapters devoted to that subject (chapter XL), and in the one devoted to rubber stamps. Hard rubber, termed ebonite when black, and vul- canite when of other colors, is simply vulcanized rubber containing a large percentage of sulphur added in the mixing process. The manufacture of coated tissues is effected in several ways. The following is a typical process. A mixture of one part washed and sheeted india rubber with one part zinc white, one fourth part sulphur, and about one third part naptha is mixed into a dough-like mass and is spread upon the cloth by machinery. The latter is simple. It consists of a bare board arranged to move under a scraping bar. The cloth is placed on the board and carried under the bar. The coating mixture is fed on one side of the bar upon the surface of the cloth. As it passes under, a regulated amount, according to the set of the bar, adheres. It is then dried by steam heat and recoated, until ordinarily six coats, each about one one-hundreth of an inch in thickness, have been given. Three coats are given in each direction with 46 RUBBER HAND STAMP MAKING. intermediate drying. The fabric is then cured by heat in vulcanizers. Sometimes the sulphur is omitted from the mix- ture and cold curing, as described later, is adopted. When the goods are made up the seams are secured with rubber cement, a thick solution of masticated gum. Such seams have to be vulcanized. Sometimes two such fabrics before curing or vul- canization, are placed face to face and allowed to adhere and are then cured or vulcanized. Enough has been said in this outline of the man- ufacturer's treatment of india rubber to show that, the first treatment requires machinery. Very little can be done with mortar and pestle, although in making up solution these simple instrumentalities are available. As a starting point for making small articles masticated sheet rubber and mixed sheet rubber are the staple materials. The preceding steps are best accomplished in the factory. CHAPTER V. INDIA RUBBER STAMP MAKING. We have seen that india rubber cannot be cast in moulds. Except in special cases deposition from solution is not available. It has to be shaped by a combination of heat and pressure. When gently heated it softens and can be tressed in a mould. As it cools it retains the shape thus given and is moulded. This applies to all un vulcanized india rubber. If mixed rubber is moulded and heated to a higher temperature without removal from the mould the curing process is brought about and the rubber may be not only moulded but cured and the product is moulded vulcanized india rubber. The mixed sheet whose manufacture is described in chapter IV. (page 42) is the starting point in rub- ber stamp making. It is made for this purpose by the manufacturers. When the material is examined it looks like ordi- nary white india rubber, being firm in texture and quite strong. On heating to 280° F. to 290° F. (137° C. to 143 c 0.) it begins to become "cured/' and if in a thin sheet one to ten minutes are suffi- cient for the process. As the heat is applied the in- 48 RUBBER HAND STAMP MAKING dia rubber first softens and becomes much like putty. It can now be pressed through the smallest . orifice and will fill up the finest details of anything it is pressed against. It is at this point that pressure must be applied to drive it into the interstices of the mould. As the heat continues it begins to lose its doughy or putty-like consistenc}^. This marks the 'reaction of the vulcanizing materials. They gradually com- bine with and change the nature of the caoutchouc. The rubber while still quite soft is elastic. If pressed by the point of a knife it yields, but springs back to its shape when released from pressure. The india rubber is vulcanized. On removal from the mould it will be found to reproduce its smallest detail. The color and ap- pearance have not changed much, but its nature and properties are now those of vulcanized rubber. It is unaffected by heat or cold within ordinary ranges of temperature, and if the india rubber is of good quality and made by a proper formula it will last for years. The first thing to be described is the mould, which includes the arrangements for pressing the sheet of india rubber while heated. A small press is needed for this purpose. It may be of the sim- plest description, and as an example of a home- made but perfectly efficient one the illustration may be referred to. The base of the press is a piece of iron, if heat is to be directly employed. Where a AND THE MANIPULATION OF BIBBER. 40 chamber vulcanizer is used both base and platen may be of wood. But from every point of view iron is the best. It lasts forever, admits of direct heat- ing, and does not split, warp, or char. Through two holes drilled near its opposite sides two or- dinary bolts are thrust. It is best to use flat headed bolts, and to countersink a recess for the Simple Vulcanizing Press for Rubber Stamps. heads in order to keep the bottom level. The heads may need to be filed off so as to reduce their thick- ness, in order to secure this object. The bolts may be soldered in place. One thing should be care- 50 BUB BE H HAND STAMP MAKING fully watched for — the bolts should be set true so as to rise vertically from the plane of the base. The platen is best made of iron, cut of the shape shown. This is an excellent disposition of the screw-bolt slots, as by swinging the right end of the platen back it can be taken off without removing the nuts and lifting it over the ends of the screws. Besides the two nuts fitting the thread of the screws it is well to have half a dozen extra ones larger than the others, which will slip easily over the bolts, so as to act as washers. The object of these is to adapt the press to objects of different thickness. The thread upon an ordinary bolt does not extend clear to the head, but by slipping on some loose nuts the plates can be forced together if desired. This press can be simplified. Both base and platen can be made of wood, the platen being sim- ply bored for the bolts, and the latter driven tightly through the holes in the base so as to retain their place. Even this can be improved on as regards simplicity. Two blocks of wood screwed together by two or more long wood screws may be made to do efficient work. One trouble is apparent with all these devices, and that is the want of parallelism of the opposed planes. The base and platen may be true and parallel or they may not. Perhaps the simplest way of securing this is the best. It consists in placing across the base two distance pieces, which may be slips of wood. These must have perfectly AND THE MANIPULATION OF RUBBER. 51 parallel faces. As the press is screwed up they will be gripped between the platen and base and will not only ensure their parallelism but will keep them at an exact distance apart. Such distance pieces are shown in the same cut. Pieces of printers' "furniture," spaces, or "quads," may be used for this purpose. They should not be fastened in place if there is need to adapt the press to more than one thickness of material and matrix. The above described apparatus is a vulcanizing press. A further improvement in it may be effected by the use of spring pressure. Two strong spiral springs may be dropped over the bolts, the nuts being screwed on above them, or a powerful spring of flat brass or steel ribband bent into the shape of a shallow letter V may intervene between nuts and platen, the centre of the bend bearing against the centre of the platen. As regards the strength of the springs there is this to be said. The distance pieces will prevent a spring that would ordinarily be too powerful from doing any harm. Such distance pieces should be used, as the springs must be based upon giving a pressure of many pounds per square inch of surface to be acted on. They should have a range of an eighth of an inch or more. The greater the range the more evenly will they work. The next cut shows an excellent little screw press, that is made for the purpose of pressing vulcanizing flasks. This is so simple that it will suggest to the 52 BUB BEE HAND STAMP MAKING mechanical reader how lie can make a single-screw press, which is by far the most convenient to use. In the stationery stores very small model cast iron copying presses designed for use as paper weights are sold. They are excellent for a limited amount of small sized work. Vulcanizing Flask Clamp, A large sized gas heated press, such as made for the purpose of manufacturing rubber stamps, is shown in the next cut, p. 53. Its construction is obvious. It is termed by the trade a vulcanizer. Its manipulation will be given further on. Type are generally the object to be copied. These are best set up with high quads and spaces. Naturally rather a large type is chosen, with extra wide spaces between the letters. Some advise rub- bing the type faces full of hard soap, afterwards brushing off the face, leaving the hollows filled. Sometimes wax is recommended for the same pur- A ND THE MAN1P ULA TWN OF li UBBER. 53 pose. This prevents the plaster of the matrix en- tering so deeply into the cavities of the letters. The type forming the model to be reproduced, is locked in a frame. Two pieces of printers' furni- Gas-heated Stamp Vvlcanizer. ture or other wooden strips screwed together by wood screws at their ends will answer for a lockir.g frame for small inscriptions. The model to be copied need not be type, but any desired relief may be used, such as an electrotype, a stereotype, an engraving or another rubber stamp. In any case it is to be placed upon a flat surface, best an "imposing stone" or piece of marble, with 54 BUBBEB HAND STAMP MAKING the inscription upwards. On each side of it dis- tance pieces reaching about one-eighth inch above its upper surface are to be placed. The next shaping appliance is the matrix or mould, or reverse of the model which is to be copied. This in the case of rubber stamps is prop- erly called the matrix. Those who have witnessed the stereotyping of a large daily newspaper have seen the matrices of the type made of paper and paste, the whole mixture being termed " Hong." Such a matrix is required for rubber type, but paper is rather too susceptible to heat although good work can be done with it. It also does not enter as deeply into the cavities of the type as is desirable. As a rule a fine quality of plaster of paris is to be recommended. What is sold as dental plaster is the best, but common plaster can be used. It is mixed with water or with a solution of gum arabic or dextrine in water. For the latter enough gum should be added to make the mixing solution as thick as thin syrup. A piece of iron, perfectly fiat and true, is now to be taken, large enough to more than cover the inscription to be copied. Upon its surface a putty made of the plaster and the liquid used in mixing is to be spread. This should be rather stiff. The surface of the iron should not be too smooth as it is desirable that the plaster should adhere well on setting. The plaster should be smoothly spread to a depth of three-sixteenths or a quarter of an inch. AND THE MANIPULATION OF RUBBER. 55 It is best applied with a palette knife or trowel, although a table knife will answer perfectly. If its surface does not become smooth it can be made so by applying a little of the solution with the knife or trowel. Before this has been done the model must be oiled. Olive oil or other clear oil is applied to all parts of the type faces, and the excess is then wiped off and cleared out of the interstices with a piece of blotting paper. Next the plate with the plaster is inverted and is pressed steadily down upon the model until it strikes the distance pieces. It is left to set. In about ten minutes it can be raised, when it will be found to give a beautiful impression true to the smallest detail of each letter. It has been said that water may be used as the mixing fluid. If this is done it is well to strengthen the mould by saturating it with an alcoholic solu- tion of shellac, after it has dried thoroughly, best for a few hours in an oven. This operates to strengthen the small projections that are liable to crumble or to break off in use. The dealers in rubber stamp supplies sell a lever press for conducting the operation of producing the matrix. The type is locked in a special chase, which is carried on a bed that travels under and out from under the platen of the press upon rollers. From each corner of the chase in which the type model is locked, a pin rises which is encircled by a 56 RUBBER HAND STAMP MAKING spiral spring. A square frame of flat iron with holes at the corners for the pins to pass through, rests upon these springs well above the type. The pins pass through holes in its corners. The matrix plate with its coating of plaster is placed upon this frame, which supports it above and not touching the type. The whole is now rolled under the press and the lever pulled to produce the im- pression. As the pressure is released the frame with the matrix is raised from the type by the action of the springs. This can be done immedi- ately, and before the plaster has set. It is almost impossible to raise it by hand with the requisite steadiness. The same chase with corner pins and springs can be used in a screw press, the one press answering for making the matrix and for moulding and curing the stamps. The plaster matrix can also be made by casting from a thinner mixture of plaster and water. After the type has been set up, or the model has been selected and placed face up and horizontal, a little ridge or projection must be made all around it. Paper can be pasted around it, and wound with thread for this purpose. It is oiled and wiped off as before. The plaster is now mixed with water to the consistency of cream, and is poured upon the model until it lies even with the projecting ledges or paper border. In an hour or less it can be removed. If water is used the mould should before use be treated with shellac solution as already described. The plaster may also be mixed AND THE MANIPULATION OF RUBBER. 57 with gum arabic solution, or with three to ten per cent, of powdered marshmallow root. This in- creases its toughness. What is known as the oxychloride of zinc cement appears to the author to be far preferable to com- mon plaster of paris. It is a trifle more expensive, but it costs so little that it is well worth trying. It is made by mixing oxide of zinc with a solution of zinc chloride. No particular strength of solution or proportions are prescribed; the zinc chloride solu- tion should be a strong one, and the mixture should be of about the consistency of soft putty. Zinc chloride may be bought as a solid substance or in strong solution. The latter answers for the mixing directly. It may also be simply made by dissolving metallic zinc in strong hydrochloric acid. The manipulation is exactly the same as with plaster of paris. The manufacture of papier macho and of other matrices is given in a special chapter. For all ordi- nary purposes the plaster or cement matrices are ample. ^ The stamp is made from the mixed uncured sheet rubber, whose preparation in the factory, including the operation of calendering it into sheets, has already been described. The best advice the reader can be given is not to attempt to make it except as a matter of interest and experiment. It can be purchased especially prepared for stamps from the dealers in india rubber. 58 BUB 11 Eli HAND STAMP MAKING A piece is cut from the sheet large enough to cover the face of the matrix. It should have a perfectly smooth surface, without cloth wrapper marks sometimes found impressed on it. The sheet as received from the maker is about one-eighth of an inch thick. It is thrown into a box of powdered soapstone or talc to secure a coating of the same on both sides. A little is dusted over the matrix and the excess is blown off. The matrix is now placed upon the base of the press, and heat is applied. To carry out the process most simply the press if of metal may be placed upon a support over a gas burner or kerosene lamp, or even on a kitchen range or stove. It will in a few minutes become warm. The sheet of india rubber is now dusted off and is placed in the press upon the matrix. The platen of the press is screwed down upon it. As the india rubber becomes hot it begins to soften and flow. By the action of the screw of the press it must be forced down from time to time as it softens. This drives the putty-like material into all the interstices of the mould. The excess escapes from the sides of the tympan in cases where the latter is of restricted area. The press theoretically should bo heated to the vulcanizing temperature, which is 284° F. (140° 0.). In practice the heat is not determined with a thermometer. The operator learns by experience how much heat to apply. The regulation type of gas heated press or stamp vulcan- izer is shown in the illustration on page 53. AND THE MANIPULATION OF ItVBBER. 59 As some of the india rubber is sure to protrude, the progress of the work can be watched from its action. By pressing the point of a knife against it the period of vulcanization can be told. Before the material is heated it is elastic and resists the Oil Stove for Heating Vulcakizers. pressure of the knife; as heat is applied it becomes soft like putty; as the heat increases it again stiffens and becomes quite elastic. At this point the press can be opened and the sheet and matrix can be taken out or the platen swung aside. On pulling or stripping the sheet from the matrix it will be found to reproduce the model in elastic india rubber to the minutest detail. As regards the minor details there is something 60 11UBBER HAND STAMP MAKING to be said. Distance pieces to gauge the thickness have been recommended for the home-made press, page 48. Cave must be taken to have these low enough to provide for enough excess of material to produce a good impression. For ordinary stamp work they should allow about one-sixteenth of an inch for the " squeeze." It will be seen that by using the distance or gauge pieces both for making the matrix and for moulding and curing the stamp, abso- lute parallelism of surfaces will be secured. The reader will have noticed in the description and will find at once in practice that the press has to be screwed up as the rubber softens. Where heavy iron presses are used the large mass of heated iron comprised in the platen of the press instantly heats the upper surface of the india rubber sheet and the heat immediately penetrates into it, while the heated matrix heats it from below. Thus it softens at once, and the press is directly turned down and the india rubber is driven into the mould and curing at once begins. But where small presses are used this manipulation is not so easy. For such the springs mentioned on page 51, are highly to be recommended. The matrix and india rubber can be put into the cold press, and the tympan with intervening springs can be screwed down so as to compress them. Then on .applying heat the mould- ing takes place automatically. With a hot press and good sheet a period of three to ten minutes is ample for moulding and curing. AND THE MANIPULATION OF HUB BEE. 61 Instead of sprinkling with talc the matrix may be oiled and sprinkled with plumbago and afterwards polished with a brush. This is not so clean a ma- terial as talc and is not to be recommended for general use, especially as oil is a bad substance to bring in contact with rubber. The distance or gauge pieces whose use has been recommended are not necessary where presses work- ing truly parallel as regards their opposing faces are used. But where home-made apparatus is used they will be found a valuable addition. In describing the simple press it was said that it could be made of wood. It is evident that a wooden press could not be used for direct heating. Such a press must be used in a hot chamber or vulcanizer, properly so called. Originally rubber stamps were generally made in chamber vulcanizers. The next cut shows a combined matrix making, moulding and vulcanizing apparatus of very conven- ient and compact form and adapted for rapid work. As the press stands in the cut the matrix press is seen in front. A box or chase is carried under its platen by two trunnions, so as to be free to oscillate to a limited extent. The type model is secured in this box. Above this box or chase is a cross-bar with screw and platen attached, connected at will to two standards or pillars, so as to constitute the matrix press. A matrix plate swings on a hinge joint between the two presses. The hinge-pin is removable. Its 02 RUBBER HAND STAMP MAKING ends can be seen projecting to right and left of the press columns. The hinge is at such a height that when the matrix plate is swung forward over the type box it will rest upon it in a nearly horizontal position. The pivoted box will adjust itself so as to come into parallelism with the plate. Matrix Making, Moulding and Vulcanizing Apparatus. When the matrix plate is swung back it falls upon the base plate of the vulcanizing press seen in the rear. In use the composition used for the matrix is spread upon the matrix plate, which may for this AND THE MANIPULATION OF RUBBER. 63 purpose be removed from the apparatus, It is replaced and the hinge-pin is pushed home. This is done with the composition coated side facing the front of the apparatus as it stands in the cut. The plate is then swung forwards, the platen of the matrix press being turned forward out of the way, anc is pressed down upon the type or other model that rests in the type box. If desired the press is used to force it home. The cross-bars of both the presses are arranged to swing each one on one of the pillars, so that the platens are turned to one side out of the way of the matrix plate as it is swung back and forth. The pressure is released and the platens are turned aside. The matrix plate is swung over to the rear upon the bed-plate of the vulcanizing press. Here it lies with the composition-matrix upwards. A lighted lamp, either alcohol or gas, is placed beneath the bed-plate of the vulcanizing press on which the matrix rests. This quickly dries it and brings it to a good curing temperature. The cross- bar and platen may be swung oyer it during the heating so as to be heated at the same time. The matrix is talced when dry and hot; the mixed sheet itself talced, is placed upon the matrix, the platen is screwed down upon it, and in a minute or two the moulding and curing is completed. A vnlcanizer, properly speaking, is a vessel ar- ranged to heat to a definite degree any desired arti- 64 RUBBEli HAND STAMP MAKING Rubber Stamp Vulcanizes. cies which are to be cured. The favorite type have been the steam vulcanizers. If steam is generated from water at a constant pressure, other things AND THE MANIPULATION OF RUBBER. 65 being equal a constant temperature will be pro- duced. By raising or lowering the pressure the temperature can be made to rise or fall. A steam vulcanizer is a tightly sealed vessel whicli contains water and which is provided with a thermometer or a pressure gauge as well as a safety-valve, safety disc or safety plug. By keeping the gauge at con- stant pressure or by keeping the thermometer con- stant the temperature can be limited and kept steady. The following table gives some pressure in pounds per square inch with temperatures corre- sponding to steam of such pressures: . per square inch. Temp. Fahr. Temp. Cent. 45.512 275° 135° 52.548 284° 140° 60.442 293° 145° 67.408 300.2° 149° The illustration, p. 64, shows a vulcanizer of modern type made for rubber stamp work. In some recent vulcanizers the water and steam are excluded from the vulcanizing chamber, being contained within double walls forming a steam jacket and maintain- ing a constant heat within the chamber. These illustrate a point that has been much misappre- hended, namely that curing is independent of pres- sure or atmosphere. Because vulcanizers have generally been filled witli steam at high pressure many have supposed that the steam or pressure had something to do with their action. The fact is that 66 RUBBER HAND STAMP MAKING it is only the heat due to the steam at such pressure- that is instrumental. Steam is a very powerful radiator and absorber of so called radiant heat. For this reason an atmosphere of steam maintains all Steam Jacket Vttlcanizeb. parts of the vulcanizer at an even temperature and is to that extent advantageous. Its presence and tne pressure it generates are not by any means re- quired for vulcanizing. Its pressure is entirely without effect. To use a steam vulcanizer. water is introduced.. AND THE MANIPULATION OF RUBBER. 67 the article in the press or mould is placed in it, and the top is secured. Heat is then applied, best if on the small scale, from a Bunsen gas burner gas, or oil stove. Either the pressure gauge or thermometer may be watched, and the flame turned up or down to keep it at the proper temperature. Moulding cannot be executed in the ordinary closed chambers. The press must first be heated to the temperature of boiling water or thereabouts and the moulding is then effected by screwing down the mould screw, upon the sheet and matrix. It is then placed in the vulcanizer and cured. The manufacturers supply gas regulators which automatically regulate the gas supply. These are worked by the steam pressure. If any one wishes to study the practical manipulation of small steam vulcanizers he can see them in use at any dentist's office. There is no need of a steam vulcanizer for ordi- nary stamp work. The hot press system already de- scribed answers every purpose and is in use by the most advanced manufacturers for thin sheet work. But if a wooden moulding press is used then it must be heated in a vulcanizer or some kind of oven or hot chamber. A very simple and reasonably satisfactory oven or air bath can be made from a flower pot and a couple of tin plates. A plate larger in diameter than the mouth of the flower pot forms the base of tho ap- paratus. This is supported on a stand over the gas G8 RUBBER HAND STAMP MAKING lamp or other source of heat. A smokeless flame or one depositing no lampblack should be used. Alco- hol or a kerosene oil stove illustrated on page 59 are excellent. On this plate a smaller plate is inverted, which latter must be so small as to be surrounded by the flower pot and to be included within it when the pot is placed over it like an extinguisher. Flower Pot Vulcanizek on Stand. A chemical or round stemmed thermometer is arranged to go through the aperture in the up- turned bottom of the pot. This may be hung from a support or it may be secured by passing through a hole in a cork or block of wood. Its bulb should AND THE MANIPULATION OF BUB BE R. 69 be near the part of the chamber to be occupied by the mould or press. The press with the article to be cured is placed upon the inner plate. The temperature is main- tained at the proper point by regulating the heat, and all the conditions for excellent work are sup- plied. The disposition of the apparatus is shown in the cuts. Interior of Flower Pot Vvlcanizer. Another arrangement equally simple is given in the next cut. An iron kettle has a layer of type metal or lead poured an inch thick cast within it upon its bottom. A thermometer passing through a hole in the cover enters a cup of glycerine that stands upon the bottom. This gives the tempera- ture. The object of having a thick or a double bottom is to prevent excessive radiation of heat from any one part. The essential condition for good opera- 70 RUBBER HAND STAMP MAKING tion is to maintain an even temperature throughout the chamber. Fish Kettle Vulcanizer. The thermometer is not an absolute necessity. By removing the press from time to time and in- specting the overflow of india rubber the progress of the operation can be watched. An extra piece of india rubber may be placed on a piece of wood by the side of or upon the wooden portion of the press, and its condition can be taken as the crite- rion. Pressure with the point of a knife will tell the vulcanizing point. By the press system .of curing, a heat far above the vulcanizing temperature may be made to do good work by a very short application. There is AND THE MANIPULATION OF HUB BEE. 71 however danger of burning the work if left in too long. If the air-bath with thermometer or the steam vulcanizer is used, and the heat is kept down to the proper curing temperature, there is no danger of burning the india rubber even if the curing is considerably prolonged. As the flower pot has often to be lifted off for introduction or removal of the press, and as it gets quite hot, a holder of some kind is requisite. A piece of heavy blotting paper is very convenient for this purpose. The flower pot system with thermometer can be further simplified by being used on a stove or range. A china saucer inverted, or some similar support, should be placed under the pot. A part of the stove at very low heat will suffice. The kettle vul- canizer, can also be placed on a stove so as to dis- pense with gas or oil. Finally ; as the last step in simplifying the work, a stamp can be made without any special apparatus beyond a hot flat iron. The matrix may be placed on a stove where the heat is rather low, the talc- coated mixed rubber sheet placed upon it, and on this a hot flat iron. In a few minutes if the heat is sufficient the stamp will be finished. A few words may be said about the type. High spaces and quads between the letters should be used, such as will come up to the shoulder of the type, as has been said. But a very nice effect is produced by using low quads between words. This leaves 72 RUBBER HAND STAMP MAKING. each word elevated by itself, producing a good appearance. Autograph stamps are made from a model cut in wood by a wood engraver. The autograph is writ- ten in some form of copying ink upon a piece of paper, and is transferred by moistening and. pres- sure to a block of wood. With an engraver's tool the wood is cut away from the lines, as the block is routed after the inscription has been "outlined." The woodcut is used as a model for making a matrix. It is evident that an autograph of fair quality could be obtained from a chalk plate. But in rub- ber stamp work to get good results certain essential parts should be of the best. These parts include the mixed rubber, model and matrix. A departure from excellence in any of these tends to the produc- tion of an inferior stamp. What is known as a "healthy cure" is above all essential to the appear- ance of the product. The stamp thus made is attached to a wooden handle by common glue or by one of the rubber cements given in chapter XVI. CHAPTER VI. INDIA RUBBER TYPE MAKING. India rubber type are often used to set up differ- ent inscriptions in wooden handles, or different date figures in rubber stamps. The latter are in such cases made with slots or recesses to receive them. Rubber type are much shorter than regular type, and as a rule are larger in the body in proportion to the face of the letter. Where only a few are re- quired the following process is the simplest way of making them from mixed rubber sheet. The type which are to be copied are set up on a level base or imposing stone, and quads or spaces are put between them. High quads and spaces should be used; otherwise they should be pushed up until even with the shoulders of the type. After oiling the faces a matrix is produced exactly as described for stamps. Before it has set quite hard the plaster or cement is cut off so that it will just fit within a little " flask" or frame. The latter may be made of tin or wood and may be rectangular or circular, provided it is large enough to include within its area the full working face of the matrix. It should be about half an inch 74 RUBBER HAND STAMP MAKING or five-eighths of an inch deep. Its object is to pre- vent the softened india rubber from spreading, so as to secure the requisite height of the type pro- duced. A piece of wood or metal is cut so as to fit closely within this frame like a plunger. It is provided with shoulders or cross pieces, so as to limit the depth to which it can be inserted. It will be seen that when matrix, flask, and plunger are all put together a complete mould for a block of type is ■1. India Rubber Type Mould. produced, as shown in the illustration, the matrix with its plate forming the bottom of the box. After the flask is placed upon the matrix it is filled with the mixed uncured india rubber sheet. As a matter of preference thick sheet is used, but scraps of all shapes can be employed as it all fuses to- gether. The mould and matrix are of course first well dusted with talc powder. The plunger is put on and the whole is pressed. Heat is next applied in a vulcanizer or hot air chamber, such as the flower pot arrangement, or in boiling water. As the sheet reaches the boiling point 212° F. (100° C.) the flask is removed and the plunger examined. If it A ND THE MA NIP ULA TION OF K UBBER. 75 goes down to its seat without expelling any india rubber more of the latter is required and is accord- ingly inserted, the plunger being taken off for the purpose. The softened gum should ooze out around the sides of the plunger. The whole is again put under pressure, and the platen is screwed down, and if all is right an excess of rubber showing itself, the whole is put in the hot chamber, the heat is raised to 284° F. (140° C), and is maintained there for half an hour. It is almost a necessity to secure the matrix plate to the bottom of the flask. This for a single opera- tion may be done by screws, or ior several operations by hooks or catches. When the curing is complete the mould is re- moved from the vulcanizer, is allowed to cool and is opened. The block of type will come out with per- fect reproduction of the letters upon one side. If all the directions have been followed as regards dis- tance pieces, level imposing surface, etc., both faces will be exactly parallel, and any number of other blocks can be reproduced of exactly the same height, not necessarily from the same matrix, although one good matrix can be used many times. The type have now to be cut apart. This is done with a sharp knife which is kept wet. It is worked with a sawing motion, and if sharp and properly used will cut with regularity, and smoothly. Type with knife marks on the sides are always unmechan- ical in appearance and seem to be " home made/' 76 RUBBER HAND STAMP MAKING. The object of using high quads and spaces or of pushing them up, will now be evident. It secures the evenness of the general face of the block of letters, which otherwise would have a deep depres- sion between each pair of letters. If the quads and leads are properly arranged, the letters will project upwards from a smooth, plane surface. The dealers in rubber stamp maker's supplies sell special steel moulds for the purpose of making them. This does away with all necessity for making matrices, and making up a flask, etc. The general manipulation is that given above. Where many are to be made the regular mould is by all means to be recommended. Sometimes type are made by cementing single letters made by the stamp process upon wooden bodies. CHAPTER VII. THE MAKING OF STAMPS AND TYPE FROM VULCAN- IZED INDIA RUBBER. Although all reference hitherto in the matters of stamps and type has been to their manufacture from uncured india rubber, a good deal can be done with vulcanized and cured gum. The stock that is known in the trade as pure gum, such as is used for bicycle tyres, for steam packing and the like, can be made to yield to moulding to a certain degree. It will not flow and unite as will the uncured gum, but it is evident that in certain cases its stiffness is even an advantage. Thus with it, rubber type can be made without any flask or frame. The material has stiffness enough to support itself. The manipulation is of the simplest. A piece is cut out with a knife so as to be of proper thickness and size. It should be a little thicker than will ultimately be required. The two opposite surfaces should be smooth and parallel. It is talced, and placed in the press with the matrix beneath it, and subjected to pressure by the screws being turned down. It is then placed in the vulcanizing chamber and heated to about 284° F. (140° C). 78 RUBBER HAND STAMP MAKING After it has become hot it softens a little. The press is removed from the hot chamber and is again screwed down as hard as the matrix can stand. This point is largely a matter of judgment. The heat is largely indifferent as long as it is anywhere near the above temperature. By one or two repetitions of the pressing and heating the softened india rubber can be made to take quite a deep impression from a suitable matrix. It is allowed to cool under full pressure. When removed from the press, it will retain the characters. It is evident that impressions in as high relief or as deep and clear as those yielded by uncured india rubber need not be expected. But where the other cannot be had, or where some experimental or tem- porary work only is on hand, this process will be very convenient. The material may be half an inch thick. From such india rubber type can be cut with advantage. Old rubber can be thus used. The writer has ob- tained excellent results from pieces of an old dis- carded bicycle tyre. The great point is to apply a heavy pressure to the hot material. Many other articles can be thus produced extemporaneously. At the same time it must be considered only a makeshift. One who has used the soft, easy flowing uncured gum would never be reconciled to the use of so rigid and diffi- cultly moulded a material, one too that can never be trusted to reproduce intricate moulds of consid- AND THE MANIPULATION OF RUBBER. 79 erable depth. In the slow yielding of the half melted unc tired gum, so amenable to slight pressure, a quality of availability is found that is missed in the other. One is worked by main force where the other readily yields and takes the most complicated shapes. By the above process stamps of such thickness may be made that they can be used without handles. It is also useful for impressing a designation of any kind upon ready cured articles. It suggests a very useful department of manipulation of India rubber. The heating and moulding can be done also in a hot liquid bath such as described in chapter XI. CHAPTER VIII. VARIOUS TYPE MATRICES FOR RUBBER STAMPS AND TYPES. Matrices for stamp moulds can be made by sev- eral of the methods used by stereotypers. Thus an electrotype could be taken directly from the face of the type. There would be little or no utility in doing this where the simpler processes are available. PAPIER MACHE MATRICES. The stereotyper for daily newspaper work uses very generally the papier mache or " flong" process of reproducing the page. This is also available for rubber stamp making. The first requirement is paste. This is made by softening twelve parts of whiting in forty parts of water, letting it soak for an hour or more. Nine parts of wheat flour are added. This is best mixed with a little water before adding to the main mix- ture. It is then brought to the boil and seven parts of glue softened by soaking in twenty-one parts of water, are added. For each gallon of such mixture, one ounce of white crystallized carbolic acid is added if it is to be kept for a long time. A ND THE MAN IP ULA TION OF B UBBEB. 8 1 The "'flong "is made by pasting together, one on top of the other, a sheet of fine hard tissue paper, three sheets of blotting paper (about 23 pounds to the ream), and a heavy sheet of manilla paper. The pasting must be smooth and each layer must be pressed and rubbed down, but not too hard. It is very important to secure perfect smoothness and regularity, and entire absence of air bubbles. Every printing office where the process is used has its own traditions as to the preparation of flong. As a great deal depends on manipulation, it would be well to endeavor to inspect its practical use in a newspaper printing office before making it. Ready prepared flong can also be procured. The form of type must be very clean and there must be no paste on the tissue paper face of the flong. The type are lightly oiled, some powdered talc is dusted over the damp tissue paper face of the flong, and the mass is laid face downward on the type. With a stiff haired brush the paper is now beaten down against the type. Great care must be taken to beat vertically; a slight side action will ruin the resulting matrix. If the brown paper will not stand the beating, a cloth may be spread over it. The progress of the work can be watched by rais- ing up a corner from time to time. When suffi- ciently deep the last touch is given by the printer's planer. This is a block of hard wood. It is placed 82 RUBBER HAND STAMP MAKING upon the back of the flong and is hammered down. The operation is repeated until the entire area has been treated. For much rubber stamp work the area would be so restricted that shifting would be unnecessary. The work is then put into a heated screw press, such as the vulcanizing and matrix press, and is dried for a period varying from some minutes up to half an hour. Some blotting paper is advanta- geously pressed on top of the whole in the press while drying. The press is opened, the flong re- moved, and dried in an oven. It is kept under a piece of wire net while drying to keep it flat. The net may be of wire, .064 inch thick, with six meshes to the inch. This baking is not strictly necessary for rubber stamp work. This gives a matrix which may be used as rub- ber stamp moulds. In use it is recomended to place a piece of smooth tin foil over it. This tends to give a smoother surface to the rubber. STRUCK UP MATRICES. Didot's polytype process may be advantageously used for producing type metal matrices. The fol- lowing is the method of applying it. The type form is firmly locked and is backed up by and secured to a solid block of wood. It is sus- pended in a sort of gallows frame with the face of the type downward and exactly level a few inches above a table. Underneath it a shallow tray is AND THE MANIPULATION OF RUBBER- 83 placed, into which some melted type metal is poured. The melted metal is carefully watched. The block and type are held by a catch so as to be released at will. Just as the type metal is on the point of solidifying, the block is released and drops upon the metal in the tray. The type should be slightly oiled. The force of the blow produces a matrix in the metal, and the form can at once be removed. It is well to have accurately adjusted distance pieces for corresponding striking pieces on the type block to impinge upon. The process is highly spoken of, especially for small forms such as those mostly required for rubber stamps. CHALK PLATES. The base for this form of matrix is a metal plate whose surface is slightly roughened with sand- paper. It is next rubbed over with white of egg, and flooded with the chalk wash made as follows: Flong paste (described under Papier Alache Ma- trices, page 80), six ounces; whiting, twenty-four ounces; water, three pints. The whiting is softened by soaking for an hour or more. The whole must be intimately mixed. It should cover the plate to the depth of one-thirtieth to one-twentieth of an inch. The plate is dried in a perfectly horizontal position. When dry the design or writing, etc., is made with a smooth steel point, the lines being carried 84 RUBBER HAND STAMP MAKING. clear through the white layer to the metal. The mould is now baked at a temperature well above boiling water; as high as 392° F. (200° 0.) may be reached without harm. If the coating seems too thin, an extra coat can be given between the lines especially over the larger areas. This must be done before the baking. A pipette may be used for putting on this coat. This deepening has the bad effect of increasing the chance of the coating stripping from the metal. The matrix thus prepared is used in the press just as is the ordinary plaster matrix. It is suited for reproduction of autographs, scrip, diagrams, etc. CHAPTER IX. THE MAKING OF VARIOUS SMALL ARTICLES OF INDIA RUBBER. India rubber can be so readily shaped in moulds and the latter are so readily made of plaster of paris that any one who is interested in such things will find endless amusement in working out different designs. Before suggesting any specific articles the following are the general points to be kept in mind. The material may be uncured mixed sheet of any thickness. As we have seen this material when heated and pressed runs together. It can be forced into any shape by comparatively slight pressure. 80 exactly does it reproduce the smallest line or mark, that care must be taken to have the moulds very smooth and free from defect. Powdered soap- stone is used to prevent adherence to the mould, but great care must be taken not to mix it among the pieces of the india rubber, where several are used in one article, as it will prevent their coalescing or running together. Another point is to contrive to introduce the proper quantity of rubber. The aim must be to 86 RUBBER HAND STAMP MAKING have a slight excess, but to avoid waste this should be as little as possible. Unless some rubber is squeezed out there is no certainty that the mould has been filled. Any projecting "fins" from the overflow are cut off with a knife or scissors after the article is removed from the mould. Plaster of paris or dental plaster mixed with dex- trine or gum arabic water or the zinc oxvchloride cement, already described, is to be recommended for the moulds. They should be made, if deep, in frames or " flasks " of tin, as plaster if unsupported is liable to split open when the rubber is forced home. For many articles the hot press can be used. Such articles are mats and other thin flat pieces. The rubber stamp sheet is a good material for them. For thicker articles a thicker sheet can be used, and sheet of any gauge can be procured from the maker. Much of what has been said about india rubber type applies to the making of miscellaneous shapes. It will also be understood where wooden moulds are spoken of that plaster, or, still better, metal can be substituted, and is to be recommended for nice work as the grain of the wood is very apt to show where the india rubber comes in contact with it. Suction discs and similar small articles into which an extra thickness of india rubber enters are best cured in a vulcanizer. The flower pot arrangement is excellent for such. The time for curing may be somewhat extended on account of the greater thickness of material to be acted on. AND THE MANIPULATION OF RUBBER. 87 Suction Discs. — For suction discs a mould is required which will produce a shallow cup with the edge feathered or reduced to a very slight thickness. Its outer surface should be raised in the centre so as to give a projection for attachment of the hook. The discs are generally made small, not over an inch in diameter, as they are not reliable for any heavy service. Their principal use is to suspend advertis- ing cards and light articles to the glass of show windows. The following is a method of making a simple mould. A hole to give the outside contour should be bored in a small piece of wood. A marble which will exactly fit the hole is next required. Some plaster of paris is mixed with water and put into the bottom of the hole, and the oiled marble is pressed down until the plaster rises and fills the entire space under the marble. After it has set the marble is removed. The proportions should be so arranged that the plaster will have risen at the sides within an eighth of an inch of the surface of the wood. This gives the exterior mould. For the cup or hollow a marble a shade too large to enter the hole may be used. One or if necessary two thicknesses of mixed sheet rubber cut into disc shape so as to fit the hole are inserted in the block, and the larger marble is placed on top and screwed down by the press. Heat is now applied in the vulcanizer. When the thermometer indicates 212° F. (100° C), or better a 88 RUBBER HAND STAMP MAKING little more, the mould is withdrawn and the screws turned until the rubber is forced down and the excess begins to squeeze out between the marble and the wood, which two should now nearly touch. It is replaced and the heat is brought up to the curing temperature .284° h\ (140° C). It is possible that a second screwing up may be needed. The spring press is in such cases particularly convenient as it avoids the necessity for re- moving the press from the vulcanizing chamber. After half an hour it will be thor- oughly cured. A hole is made through its centre from side to side thereof, but not penetrating the disc, and through this hole a brass nail is thrust and bent into hook form. In the cut the correct shape for the mould and consequently for a suction disc is shown. This can be easily secured where a disc already made is procur- able by casting in plaster, or, with a little ingenuity the template for the mould and the plunger to be used instead of the marble can be whittled out of wood. The lower body of the mould in such a case can be made of plaster of paris. To secure the alignment of the two parts of the mould, dowel pins, indicated in dotted lines, should be placed near the periphery. The gum should be introduced in a lump Mori-D for Suction Discs. AND THE MANIPULATION OF RUBBER. 89 near the centre, in order that it may sink well down- wards to the bottom of the mould before spreading laterally. Sometimes the tips have a recessed end. This is secured by the use of a mandrel, shown in dotted lines in the axis of the mould. Such discs are sometimes made to be cemented to arrows to be discharged against smooth surfaced targets, to which they adhere on impact by atmos- pheric pressure, giving rise to a very interesting game. Another use of suction discs is as photographic negative holders. They can be fastened to a wooden handle and be attached by suction to the back of a negative under treatment. For this purpose they should be at least two inches in diameter. Pencil Tips. — These are generally little cylinders of india rubber, which fit into a tube that slides over the end of the pencil. They can be thus sim- ply made. A hole is bored in a piece of wood the diameter of and a little more than the depth of the pencil tip. A short cylinder that exactly fits the hole is required for plunger. The gum is put into the hole in little discs, or rolled up into a cylinder, the plunger is placed on top, and the mould put in the press. It is shaped by pressure and cured as described. Sometimes the tips are cup shaped. For these the mould is made in two sections fastened by catches or by pins set in the plaster as shown in the cut. The hole is made larger at bottom than at 90 RUBBER HAND STAMP MAKING top, and at the top is a little smaller than the shaft of the pencil. A plunger that nearly fits the small end is provided. The india rubber is placed in the mould and heated. When soft, the plunger is forced down to the proper distance in the press and the article is cured. Care must be taken to Mould for Pencil Tips. give the plunger a good coating of talc, and it must be made to sit vertically. The arrangement of a cylindrical hole shown in the cut secures this result perfectly. As distance piece a pin is passed through the plunger. Cane and Chair Leg Ttys, etc. — By carrying out the process just described with larger moulds and of slightly different section very convenient tips for chair legs and walking canes can be made. Such tips can be modified in size and thickness to answer as covers for the mouths of bottles, test-tubes, etc. Corks. — These may be made in moulds tapering AND THE MANIPULATION OF RUBBER. 91 from top to bottom. The india rubber must be packed in with great care to secure as solid filling as possible. A plunger is used that enters the larger end and is a very little smaller in diameter, so as to descend a little way into the mould. This distance determines the length of the cork. As the perim- eter of the plunger strikes the walls of the mould it cuts off almost completely the excess of rubber Mould for Rubber Corks. that has squeezed up past it. An excellent modifi- cation of the mould is shown in the cut. The upper part with parallel sides serves as a guide for the plunger. It is a similar extension as the one recommended to be used for the plunger in the hol- low pencil and chair leg tip moulds just spoken of. Mats. — These may generally be made in the hot press. Designs for them in great variety may be found in cut glass and pressed glass dishes. Many X 92 RUBBER HAND STAMP MAKING of these have patterns on their bottoms that can be moulded in plaster to serve as matrices. Cord, Thread and Seamless Tube. — By placing the mixed india rubber in a cylindrical mould fitted with piston and with one or more round holes in the bottom, the material may be softened by heat and forced out of the holes by depressing the piston. This will form cylindrical thread or cord. As it descends it may be received in a box of powdered talc and be afterwards cured. By providing the hole with a mandrel seamless tubing may be thus made. In making such the mandrel usually re- mains in place during the curing. Plenty of powdered talc must be used. Skeletonized Leaves as Models. — These would form interesting models from which matrices could be made in plaster. It would be possible to produce some very pretty stamps or mats from these and similar models. After some experience inspection of any article will show how it was moulded. The fin will indi- cate the joint in the mould, and with this as a clew the mould can be almost certainly constructed like the original. India Ruhbw Bulbs. — Bulbs and hollow articles generally, such as dolls, toys and the like, cannot be made without special high pressure hollow moulds. The general process consists in cutting out gores from mixed sheet as for a balloon. The edges are coated with cement (thick benzole or ear- AND THE MANIPULATION OF RUBBER. 93 bon disulphide india rubber solution) and while the rubber is warm the seams are pressed and knitted together with the fingers. A hole is left in one place through which some pure water or water of ammonia is introduced. The bulb is now blown up with the mouth or otherwise, and while inflated the hole is pressed shut. This is often done with the teeth. Any projections around the seams are cut off with curved scissors. The mould is of iron and in two halves. Powdered talc is applied, and the bulb is placed in and shut up in the mould which it should exactly fill. The mould is clamped together and the whole is put into a vulcanizer, and the rubber is cured. The steam and vapor formed by its liquid contents expand it and press it with great force against the sides of the mould. After curing the mould and bulb are removed from the vulcanizer, cooled by a shower bath of cold water, the mould is opened and the bulb is removed. Often an iron pin is left projecting through the side during the vulcanizing, which pin, when withdrawn, leaves the necessary aperture, or it is perforated. The bulbs are polished by tumbling in a revolving cylinder. Considerable skill and practice are needed to succeed in making hollow bulbs. Great accuracy is needed in cutting out the gores and in joining the seams. CHAPTER X. THE MANIPULATION OF MASTICATED SHEET KUBBER. The manipulation of pure sheet rubber is simple, yet is liable to lead to disappointment. When two pieces are laid face to face and cut across with a sharp knife, or scissors, the edges will adhere with considerable tenacity. This may be increased by applying some thick solution of india rubber in a volatile solvent, and by manipulating the sheets so as to bring the entire surfaces of the cuts together. Finally the material may be charged with sulphur by absorption or by Parkes* process, and cured in a glycerine or calcium chloride bath, all of which are described in chapter XI. The same treat- ment will affect the cement used in making the joint also, bringing about its vulcaniza- tion. Such in a few words is the main process in the treatment of this class of goods. Where it is de- sired to prevent adherence, soapy water or powdered talc is used. Adherence may be produced between the surfaces of the sheets if they are clean, by pressure and a little warmth. The method of making toy balloons THE MAN IP ULA HON OF B UBBEB. 95 will give an example of how the article is dealt with by the manufacturer. A pile of pieces of masticated sheet rubber is made. Every piece has one side coated with pow- dered talc, and two talc-coated sides are placed in contact in each pair. As they are piled up, the outer surfaces of each pair are moistened with water. A steel punch or die, pear shaped in out- line, is used to cut down through the pile, cutting all the pieces into that shape. The pile is then taken apart in pairs. The separa- tion takes place between the wet surfaces, the edges of each pair adhering slightly so as to enclose the talc-coated surfaces. The neck is opened if neces- sary. A rather weak or thin solution of india rub- ber in benzole is now brushed over the freshly cut edges. By pulling out the centre of each piece the edges are brought into contact, and adherence is produced. If the Parkes process of vulcanizing, chapter XL, is employed they are cured to the slight extent nec- essary upon a tray coated with talc. The balloons are then ready for inflation. They are rather delicate articles to make except for immediate use as the thin material is liable to become over vulcanized. In the chemical laboratory sheet rubber can be used for covering the ends of glass stirring rods. These answer very nicely for cleaning out from beakers the last particles of a precipitate. The 96 RUBBER HAND STAMP MAKING. sheet is cut of proper size and is bent around the end of the rod and cut off close with a pair of scis- sors. It adheres where cut. It is then pinched with the fingers to bring the edges into better con- tact and the operation is complete. A slight heat makes it adhere better. To connect glass tubes in setting up laboratory- apparatus the same material was formerly used. It was wrapped around the joint, tied with thread and slightly warmed. At present this form of connec- tion is wholly displaced by ready made rubber tubing. It is interesting to observe in all articles made from this sheet the marks of the original cutting knife. These may be observed in inflated balloons, as parallel lines running all over the surface, and magnified by the expansion due to the inflation. CHAPTER XL VARIOUS VULCANIZING AND CURING METHODS. The regular methods of vulcanizing and curing can be departed from and good results obtained. A few excellent methods differing essentially from the ordinary ones are described which will be of service to workers on the small scale, as they enable one to dispense with vulcanizer and air bath en- tirely. One type of curing process does away with the air or steam vulcanizer, and substitutes, as the curing agency, a hot bath of liquid. For this purpose a fluid is required that will not act injuriously upon the india rubber, and which will give a curing temperature without boiling away. One favorite liquid is glycerine. This can be heated to the nec- essary degree and is an excellent substitute for the expensive apparatus often used. For experimental work it is exceedingly convenient. In use it is placed in a vessel of proper size and a thermometer is suspended so that its bulb dips into the liquid near one side and does not touch the bottom of the vessel. The heat is applied by a gas burner, alcohol lamp or oil stove. Of 98 RUBBER HAND STAMP MAKING course the vessel may be placed on an ordinary cooking stove or range, and the heat may be gradu- ated and adjusted by moving it about until it reaches a part of the stove where the proper heat will be maintained. The mould with its contents is immersed in the glycerine, care being taken to see that it so placed as to assume the mean temperature of the liquid and not to be heated too hot. This might happen if it stood on the bottom of the vessel, so it is well to have it supported or suspended a little above it. It is easy to see that the whole may be so arranged that the screw handle or pressure nuts of the mould will rise above the liquid. In this case the press can be screwed down while the article is heating. Instead of glycerine a strong solution of some salt in water has been recommended. A solution of calcium chloride, or some other salt can be sub- stituted. Either are very cheap and will be quite satisfactory. Another treatment which applies also to the mixing operation is by the sulphur bath. Sulphur is melted in an iron vessel and brought to a temperature of 248° F. (120° C). A piece of unmixed pure caout- chouc immersed in this bath will gradually absorb sulphur. The case is almost parallel with the absorption of water or benzole by the gum. The piece swells and thickens as it is acted on and eventually will contain enough sulphur for vulcani- AND THE MANIPULATION OF RUBBER. 99 zatioa. It may absorb as much as fifty per cent. The point of proper absorption must be settled more or less empirically or by successive trials. After enough has been taken up the piece is re- moved and dipped into cold water, which cracks the adherent sulphur so that it can be brushed or rubbed off. This gives a piece of mixed rubber ready for moulding and curing. It can be heated and moulded and may be cured as desired, in a liquid bath, hot press or vulcanizer. It will be observed that this provides for the ad- mixture of sulphur only; no talc or other solid can be thus introduced. The addition of these solids tends to make the rubber of a more attractive color and their use is not to be deprecated in all cases. Hence the sulphur bath process is not to be consid- ered a perfect one. In the sulphur bath the mixing and curing processes can be combined. If the liquid sulphur is heated to the vulcanizing temperature, 284° F. (140° C), a thin strip of gum immersed in it will be vulcanized completely in a few minutes. A heating of several hours at the lower temperature will effect the same result. The sulphur bath processes must be regarded as unsatisfactory. It is not easy to feel that any de- pendence can be placed upon them as regards re- liability or constancy of product. The sulphur also will mostly effect the surface. Thin pieces may be satisfactorily treated, but the same confidence can- 100 RUBBER HAND STAMP MAKING not be felt as is experienced when specific amounts of ingredients have been mixed in with pure caout- chouc in a regular mixing machine. The sulphur bath is of value to the experimenter, enabling him to do his own mixing without expen- sive apparatus. Bromine, iodine, chlorine and nitric acid are vul- canizers. A piece of sheet rubber dipped into liquid bromine is instantly vulcanized. Iodine and nitric acid have also been used in commercial work. Alkaline or alkaline earth sulphides can be em- ployed in solution under pressure for vulcanizing. At a vulcanizing temperature their solutions will answer for thin sheet very well. Polysulphides of calcium have thus been employed. By simply lying embedded in finely divided sul- phur at a temperature of 233° F. (112° C.) as much as ten per cent, of sulphur may be absorbed by thin sheet rubber. This is one of the processes pecu- liarly suited for work on the small scale. It may be used instead of the Parkes process next to be de- scribed. Chloride of sulphur is an orange red mobile liquid of a peculiar and disagreeable odor. It boils at 276° F. (136° C.). It dissolves both sulphur and chlorine so that it is not easy to obtain it in a pure state. If unmixed india rubber is exposed to its action it will quickly become vulcanized. At ordi- nary temperatures the mixing action takes place, AND THE MANIPULATION OF RUBBER. 101 though it is much accelerated by a slight applica- tion of heat. It is quite possible that this action may be of use to the reader in his manipulation of india rubber. Thin sheet may be vulcanized by being immersed in a solution of this substance in bisulphide of carbon followed by slight heating. The thin layer of caoutchouc left by evaporation of the chloroform solution of india rubber may thus be vulcanized so as to become comparatively strong and elastic. Where the same solution has been used as a cement or for patching overshoes and finishing the patch, a vul- canization can thus be given to it. The process is known as Parkes' cold curing pro- cess. A solution of one part of chloride of sulphur in forty parts of bisulphide of carbon is of good strength for rapid work. A thin article needs but an instant of immersion. It then is placed in a box or tray upon some talc powder and is heated to about 104° F., (40° C). One minute of curing will suf- fice. It is advisable to wash off the articles after- wards in water or in weak lye to remove any traces of acid. Petroleum naptha can be used as the solvent in- stead of bisulphide of carbon. The latter substance has an exceedingly disagreeable odor, and its vapors must be considered rather injurious especially to those who are not accustomed to them. When thick articles are to be cured by this pro- 102 RUBBER HAND STAMP MAKING. cess a much more diluted solution is used. One per cent, or less of the chloride of sulphur is the proportion used. The object of this is to enable a longer immersion to be employed so that the in- terior will be affected before the outer layers become too much charged with the vulcanizing material. In this short description of the Parkes curing process hints for a useful method may be found. The process is beyond doubt by far the simplest known for treatment of india rubber. Exactly what reaction takes place is unknown. Whether the sulphur or the chlorine is the acting vulcanizer has not as yet been determined. Its defect .is that it produces surface action, anal- ogous to casehardening. One method of avoiding this is to remove the articles from the sulphur chloride bath and at once to immerse them in water. This prevents the rapid volatilization of the solvent and an equalizing of the absorption ensues. CHAPTER XII. THE SOLUTION OF INDIA RUBBER. India rubber presents some difficulties in its solution. If a piece of pure gum just as received by the factory is placed in hot water it will swell and whiten after a while, but will not dissolve. If a similar piece is placed in benzole a similar but greatly exaggerated action takes place. The piece if left to soak for a day or more swells enormously, but very little solution is effected. The swollen india rubber can be removed from the benzole in a single piece. It will display all the layers and marks of the original piece which was perhaps of not one hundredth part of its volume. Some parts will be a perfect transparent jelly. It has been found that masticated india rubber dissolves with comparatively little difficulty. If the experimenter will place in a porcelain mortar, the jelly-like mass obtained as above detailed, and will rub it up thoroughly, it will be effectually mas- ticated. This requires a little patience, as the slippery material seems to elude the pestle. Yet eventually it will all be reduced to a perfectly homo- geneous mass. Its action while being rubbed up is 104 RUBBER HAND STAMP MAKING very peculiar. At first no progress seems to be made. After a little the lumps yield to the friction. The rubber then begins to attach itself to the pestle and mortar, and begins to be drawn out into ever changing webs and threads. As the operation ap- proaches completion the material makes a snapping, crackling noise familiar to all rubber workers. When complete there will be no lump left, and the whole will be a uniform pulp. If beuzole or a volatile solvent has been used, the rubber will easily be removed from the mortar with a spatula or palette knife. If turpentine was the solvent it will be impossible to remove the last traces except after long standing or by solution. If replaced in the original solvent it will now come into nearly or quite perfect solution. This is the best way of masticating on the small scale. It is almost impossible to masticate untreated gum in an ordinary mortar. The dealers sell a special india rubber for the manufacture of cement and solutions. This is so treated by mastication that it dissolves with great readiness. It is also said that heating under pres- sure is used to dissolve it in some factories. Many solvents have been used and none work without some difficulty. Benzole, coal tar naptha, petroleum naptha, carbon disulphide, ether and chloroform, oil of turpentine and caoutchoucin are the best known. The naptha best suited for its solution is termed solvent naptha. It has a specific AND THE MANIPULATION OF RUBBER. 105 gravity of .850 at 60° F. (15^° C); it boils at from 240° F. (115#° C.) to 250° F. (121° C.) and on evap- oration should leave no more than ten per cent, of residue at 320° F. (160° C.) Payen recommends a mixture of 95 parts bisulph- ide of carbon with 5 parts of absolute alcohol. Commercial chloroform is apt to be too impure to act as a good solvent. It is apt to contain alcohol mixed with it as a preservative, which impairs its effectiveness. Some of these solutions are better suited than others for the deposition of thin layers by evapora- tion. Turpentine gives a very sticky and unman- ageable solution, which dries very slowly. Payen's solution and the chloroform and the benzole solu- tions may be cited as especially adapted for this purpose. Careful vulcanization by the cold curing method can be applied to articles made by such deposition from evaporation. In the case of all of them some form of mastication for the india rubber is needed. The simple mortar grinding of the gum swelled by the solvent is the only practical treatment without special apparatus. When it is remembered that fixed oils are de- stroyers of vulcanized or unvulcanized india rubber it will be obvious how important it is to use pure solvents. Too great care cannot be taken to pre- serve the liquids pure and free from such matter. A solid hydrocarbon may be used. Thus paraffin wax, such as candles are made of, when melted acts 106 RUBBER HAND STAMP MAKING as a solvent. The resulting liquid solidifies when it cools, retaining an almost greasy feel. Boiling oil of turpentine is recommended by some for the solution of vulcanized india rubber. Phenyle sulphide, it is stated, will soften it so as to render it workable. The latter discovery is credited to Dr. Stenhouse. It is stated that a solution or pasty mixture of one part of caoutchouc in eleven parts of turpentine with one half part of a hot concentrated solution of sulphur (potassium sulphide) gives on evaporation a film neither tacky nor soft, a species of vulcaniza- tion taking place. It is of much interest to note that an aqueous solution of india rubber has been proposed in which the vehicle is a solution of borax in water. This is well known to be a solvent for shellac and other resins. It has been recommended often as a vehicle for rubbing up india ink. The ink made by mixing lampblack with the shellac solution is nearly water- proof. A shellac varnish is given by the plain solu- tion. The experiments upon india rubber were pub- lished in a recent trade paper. One method of making the solution is as follows. A solution of borax two fifths saturated is made by adding to two volumes of saturated solution three volumes of water. To this is added a solution of india rubber in benzole or other hydrocarbon of such strength and in such quantity as to contain AND THE MANIPULATION OF BUBBER. 107 from three and one-half to four and one-half per cent, of india rubber referred to the borax solution. It is now vigorously shaken and heated to 120°-140° F. (49°-60° C.) and the agitation, not too violent, is continued until it cools. Ceara or Madagascar rub- ber answers best; Para is not so good for this for- mula. This may be termed the indirect or emul- sion method. For direct solution from two to three volumes of water may be added to three volumes of saturated borax solution. The india rubber is added in ex- tremely thin shavings and the solution is heated. For weak solutions the boiling point need not be reached. For strong solutions the heating should be done under pressure so as to bring up the pres- sure to one to three atmospheres. Such solutions may contain as much as eight per cent, of the gum. The mixture is liable to coagu- late or gelatinize just at the wrong time, but it may be of value as a vehicle or as a waterproofing agent. It deserves further investigation, which it is to be hoped it will duly receive. Great care is necessary in working with naptha, benzole, carbon disulphide and similar liquids. Their vapor is given off at ordinary temperatures and may travel some distance to a lamp or fire and become ignited and carry the flame back to the ves- sel. Their vapors are also anaesthetic and should be avoided as regards inhalation. CHAPTER XIII. EBONITE, VULCANITE AND GUTTA-PERCHA. Ebonite and Vulcanite. — These two well known substances are india rubber, in which the vulcaniza- tion process has been intensified. From twenty- five to fifty per cent, of sulphur is added in the mixing, and the curing is prolonged to several hours. A temperature of 275° F. (135° C.) for six to ten hours is sometimes recommended, but gener- ally a shorter period at the regular temperature, 284° F. (140° C), may be employed. The mixed sheet is made and sold extensively for dentists' use. It is soft and flexible and very easily moulded. It is treated like the regular mixed sheet in every respect, except that plumbago brushed on the slightly oiled surface of the mould is recom- mended instead of the light colored talc, to prevent adherence. Wax where available is better than oil. Sometimes specimens are built up in sections. About an hour before full vulcanization in the fourth stage, new material can be added and will attach itself to the old. The stages of vulcaniza- tion are thus given by Bolas. AND THE MANIPULATION OF RUBBER. 109 " Several distinct stages or steps may be traced during the curing of ebonite; and I wish to call your attention to some specimens illustrating these various stages. "Here, in the first place, is the plain mixture of sulphur and rubber, this being nearly white, and capable of becoming quite plastic or soft by the ap- plication of a gentle heat. " The second specimen illustrates the action of a very moderate degree of heat on the mixed material, this particular sample having been heated to 128° Centigrade for twenty minutes. It is, as you see, somewhat darkened, and has lost a little of its orig- inal softness; while a degree of heat which would have rendered the original mixture plastic, like putty, fails to make much impression upon it. "The third specimen illustrates the effect of a more prolonged heating, this sample having been heated for an hour to 135° Centigrade. It is olive green in color, and has acquired a certain amount of elasticity, resembling that of a rather inferior quality of vulcanized caoutchouc. " The fourth stage of curing is illustrated by this specimen, which you see is brown, and tolerably hard. Ebonite in this state refuses altogether to become plastic by heat, and a temperature of 150° maintained for half an hour or less would suffice to bring it to the fifth stage, or that of finished ebonite. "The fifth stage, or that of properly cured 110 RUBBER HAND STAMP MAKING ebonite, is the goal to be arrived at in manufactur- ing the material. There should be no places where the curing is imperfect, a kind of defect which is likely to happen when articles of unusual thickness are vulcanized, and no portion of the ebonite should be spongy or honeycombed by air bubbles. " The sixth, or spongy state, is generally the result of over-heating, bubbles of gas forming in the material, and converting it into a kind of porous, cinder-like mass. "A specimen will now be handed round, which illustrates the third, fourth, fifth and sixth stages, as already described. The specimen in question was cured on a hot plate, this having probably been heated to 160° or 170° Centigrade; and you will be able to trace all gradations in the curing operation, from the first setting of the plastic material to the destruction of the ebonite by overheating." Cement for uniting pieces of the partially cured material may be made by rubbing up some of the untreated scrap with benzole. At the heat of boiling water, ebonite can be bent to a certain extent, which bend it retains on cooling. When warm an impression of a coin or relief die may be made on it by heavy pressure which it will retain. On heating the image disappears. If before heating the surface is planed off and the piece is heated the image formerly in intaglio will expand into relief. By the exact process of rubber stamp making AND THE MANIPULATION OF RUBBER. Ill excellent stereotype plates may be made of eb- onite. It can be turned at high speed in a lathe and pol- ished with fine 000 emery paper followed by a cloth bob with rotten stone, etc., and water or oil. Blot- ting paper, charged with the above or with tripoli, is excellent for polishing small surfaces by hand. Ebonite is a good connecting material between softer rubber and iron, the whole being vulcanized together ; the iron should be well roughened or cut into rasp-like or file-like projections. Ebonite is properly the name for black hard rub- ber, and vulcanite for the colored products such as used by dentists and others. ■ GUTTA-PERCHA. Gutta-percha is prepared by coagulation from the juice or sap of several trees, among others the Isonandra gutta, of Borneo and the East Indian Archipelago. The product gutta-percha is iden- tical in composition with india rubber. It is hard at all ordinary temperatures. Its manufacture includes purification and masti- cation. It is far more amenable to treatment than is india rubber. Many materials are mixed with it as adulterants or otherwise in the factories. It is more useful in the form of sheets. These when heated to 122° F. (50° C.) become pliable and can be moulded by pressure to any degree. At the 112 RUBBER HAND STAMP M AKIN G temperature of boiling water it becomes pasty and adhesive, and at 266° F. (130° C.) it is so soft that it may be considered as melted. It is an admirable moulding material. Stereo- types and other relief or intaglio images can be made by pressing it while heated. These are often absolutely perfect reproductions of the original. Dishes for photographic purposes, etc., are easily made out of the sheet. By gentle warming they become pliable, and a greater heat makes surfaces capable of adhering by pressure. Tubes can be made by the squirting process, as used for india rubber. Wires are coated with it in a similar manner. It has several defects. It is not durable if ex- posed to the air with consequent changes of temper- ature. It is also too easily softened by heat, as of course no hot liquid can be introduced into a gutta- percha vessel. The Parkes cold curing process can be applied to it, which makes it more indifferent to heat. This is applied by dipping an instant and drying. After several repetitions the period of dip- ping is prolonged and ultimately it is left immersed some time. If left immersed at first it would dis- solve. It is soluble in most caoutchouc solvents, particu- larly in carbon clisulphide. CHAPTER XIV. GLUE OR COMPOSITION STAMPS. Stamps made from a mixture of glue, glycerine, and molasses or from similar mixtures are an excel- lent substitute for iudia rubber stamps. Properly made they possess all the flexibility that character- izes the rubber ones, while for fatty inks such as that used by printers and lithographers, which inks tend to destroy rubber stamps, they are much better. They are adopted by the United States government for making dating stamps for use in the Post Office Department ; by publishers of directories for print- ing advertisements on the edges of their publica- tions, and in many other cases. Our description shall follow as closely as possible the process and methods used in the United States- Post Office. They are there termed "composition blotters." The composition of which they are made is print- er's roller material. Nine and one-half pounds of fine quality glue are soaked in just enough soft water to cover it until it is thoroughly softened. It is then melted. In the Government Department a steam kettle is provided for the purpose. An ordinary glue pot will answer for smaller quantities. 114 RUBBER HAND STAMP MAKING When melted four and one-half pounds of best molas- ses and seven pounds of glycerine are added, and the whole is thoroughly mixed. The formula varies a little according to the prevailing temperature, less molasses being added when the weather is warm, and vice versa. Experience is here the best teacher. When well mixed it is poured out into tin pails whose inner walls or sides and bottom have been Model for Composition Stamp Mould. rubbed over with oil. It solidifies in cooling and becomes a clear brown jelly quite free from any stickiness or superficial moistness. In use it is turned out of the pails to which, owing to the oiling, it does not adhere. It is cut off as wanted, melted by heat and cast in oiled moulds. The latter are made of type metal to which one- third its weight of lead has been added. As model AND THE MANIPULATION OF RUBBER. 115 for the mould or matrix a brass model of the stamp is employed. This represents a sort of oval based cut-off or truncated cone, about an inch high and a little over an inch long on its base. A flange extends outward from its base and a tube is provided to fit this flange. Its smaller end corre- sponds to the face of the stamp, and on it are en- graved in full relief any permanent characters, Composition Stamp Mould. circles or border lines, etc. Through its centre one or more apertures are made. Into these, changeable steel, iron or brass type may be introduced and set fast with plaster of paris. To make the mould, the brass model with its mov- able type set as required is placed upon a flat table or plate, face upward, and surrounded by the tube, as shown in partial section in the cut, page 114. The tube is a strip of sheet iron, which is bent around the flange and is secured in place by a wire twisted around it. The melted alloy (type, metal and lead) is 116 RUBBER HAND STAMP MAKING poured into the space thus formed until it rises a quarter of an inch above the face of the model. In a few minutes it sets and is removed and allowed to cool. This gives a cup with the inscription and design depressed or in intaglio upon its inside base. This is shown in the cut, page 115, partly in section; it will of course be understood that the mould forms a complete cup. To make the stamp the interior surface of the mould is oiled with a stiff brush. It is not material what oil is used. The composition melted by heat is then poured into the cup, and is allowed to solidify. Owing to the conical shape of the mould it is readily removed. The mould must be hot but not too much so. In the Post Office stamps the date requires to be changed frequently. Some of the figures do duty for two or three days each month. Thus the figure 8 is in the designation of three days, the eighth, eighteenth, and twenty-eighth. There are three changes involved therefore in connection with this day numeral. When a stamp mould or matrix is cast the place of numerals that are to be changed is filled with a blank space in the part where the type would otherwise come. A number is stamped in this space when needed, by means of an ordinary steel number-punch. When the number is to be changed the old char- acter is scraped or cut out, leaving a small irregular hollow. A very small piece of soft lead, about one- AND THE MANIPULATION OF RUBBER. 117 sixteenth of an inch on each side, is dropped into the hollow. AVith a fiat faced punch it is flattened out, and on it the new number is impressed by a steel punch. This operation is repeated a great many times before the matrix is worn out. OPEN. Composition Stamp Handle. In the cut, page 115, one number is shown as stamped into the soft lead, and at the other end of the stamp is a blank space ready for a number. The casting of a stamp is so extremely simple that no attempt is made to use movable type, as in permanent rubber dating stamps. While it is obvious that these composition stamps could be attached directly to wooden handles, a spe- 118 BUB BEE HAND STAMP MAKING cial style of handle, shown in the cuts, is employed by the Post Office. A wooden handle carries at its end a brass base, to which is pivotted a swinging piece that is perforated by a conical oval aperture a little larger than the small end of the stamp. The edges of this aperture are slightly rounded. It is swung around as shown in the first figure, and the stamp, previously moistened on its sides, is forced in. If the stamp is properly made it is sur- prising how much force may be used to insert it. If the edges of the brass swinging piece ape not rounded there is danger of the composition being cut. The stamp in its brass frame is then swung back over the brass base, where it is secured by a catch. The stamp is now ready for use, as shown in the second figure of the cut. It is imperative that no aqueous or glycerine ink be employed for continuous work with such stamps. Common printers' ink is perfectly satisfactory, and the work may be nearly or quite as good as that ex- ecuted by an india rubber stamp. The Post Office manufactures a pad for use with printers' ink into whose manufacture the same com- position enters. The ink retainer is a piece of fine felt, one-quarter to one-half an inch thick. This is placed in the bottom of a shallow steel mould, where it enters for half its depth into a recess that it ac- curately fits. The composition from old stamps, melted up, is then poured upon and around it, the mould being previously oiled. When it is full a AND THE MANIPULATION OF RUBBER. 119 piece of strong manilla paper, of the area of the felt only, is placed upon the bottom of the glue pad on its centre, which as it lies in the mould is its upper- most part. The paper adheres strongly as the glue hardens. Eventually it is turned out of the mould, and a pad, shown in the cut, is produced. The dotted lines show the limits of the felt pad. The glue composition underlies, surrounds and extends outwards from the felt portion. It is found that the elasticity of the composition makes the pad Composition Ink Pad. much pleasanter for rapid stamping. The above description gives the clew to making any stamp of this description. The matrix may be of dental plaster, or of oxychloride of zinc cement. The mould may be built up of type of any kind. The composition is so cheap that the stamp can be made quite thick. This gives it a high degree of elasticity and adaptability to uneven surfaces. It may be mounted by adherence upon a flat board or block, provided, if necessary, with handles. If the 120 RUBBEB HAND STAMP MAKING. board or block is placed upon the composition while it is still warm and liquid, as it solidifies the board and composition will adhere with great tenacity. All moulds or surfaces to which it is desired that the melted composition shall not adhere must be oiled. The moulds must not be cold or the comjDosition will not enter the fine divisions. If on the other hand they are too hot the mixture will adhere. Experience will teach the right conditions for suc- cess. Below are given other formulae for roller composi- tion. The formula already given in this chapter is that used by the United States Post Office Depart- ment. I. " Old Home Receipt:" Glue 2 lbs., soaked over night, to New Orleans molasses 1 gallon. Not durable, but excellent while it lasts. II. Glue 10^ lbs., molasses %y 2 gal., Venice tur- pentine 2 oz., glycerine 12 oz.; mix as directed above. CHAPTER XV. RUBBER IN SURGERY AND DENTISTRY. While the preceding chapters of the present work are devoted almost exclusively to a descrip- tion of the method of making rubber stamps and type, yet this is but one of the multitudinous uses to which rubber is adapted under modern manu- facturing conditions. In almost every art and trade rubber plays an important part and each year and month the demand for this valuable natural product increases. The amount of rubber annually consumed is almost unbelievable and yet a large portion of the rubber used up or worn out is actually reclaimed. Quite recently an examination of the dust from streets and parks of cities, disclosed the fact that about 12 per cent of the dust was composed of rubber worn from the rubber tires of vehicles, — an amount well worth reclaiming and which would amply repay the trouble and cost of street cleaning. Perhaps the most valuable and important use to which rubber is put, is the manufacture of 122 RUBBER HAND STAMP MAKING surgical and dental goods. Modern surgery would be practically impossible without rubber and the dentist could hardly succeed at all without the aid of this wonderful gum. Rubber or gutta percha was apparently first used by the medical world in 1822 when a Mr. Montgomerie of Singapore found the natives using it for whips, and at once grasped its possibilities for use in making braces and similar surgical appliances, and in 1842 he recommended the use of rubber for splints, etc., to the medical board of Calcutta. In 1844, the Society of Arts of Lon- don awarded Mr. Montgomerie a gold medal in recognition of his useful discovery and the bene- ficial results from its use in surgery. After this time the use of rubber and gutta percha for surgi- cal appliances and instruments rapidly increased and soon became universal. India rubber has perhaps rendered its greatest service to modern medical practice in the form of drainage tubes. Upon the proper drainage of wounds depends to a great extent their healing. While many other substances have been used as drainage tubes, yet more drainage tubes of rubber are used than of all other substances combined. In the first place its elasticity renders it applica- ble to almost any shaped wound; it is not readily broken; it resists most chemicals; it is cheap AND THE MANIPULATION OF RUBBER. 123 and is easily sterilized. As tourniquets, rubber bandages, ice-caps, water bottles, syringes, sheet- ing, aprons, gloves, instruments, handles, cathe- ters, bougies, and in various other ways India rubber or gutta percha is widely and universally used in medicine and surgery. A very valuable use to which rubber is also put in surgery is in the manufacture of artificial limbs. Many artificial limbs are composed entirely of rubber, while practically all modern artificial limbs have rubber in some form employed in their manufacture. Some of the best limbs made in America are wholly composed of rubber, with a small core of wood, while others use rubber only as buffers at the joints to take up or absorb the jar or concussion in the use of the artificial hands or feet. So excellently made and so well adapted to the purpose are rubber hands, that many wearers of these artificial members can use them to handle small articles and can write almost as well as with the hands provided by nature. Arti- ficial rubber feet defy detection and can be used in riding bicycles, walking, running, dancing and other ways with practically the same security and ease as real feet. The introduction of vulcanized rubber into dentistry marked the greatest epoch in its advance- ment and opened a new field for dental surgery. 124 RUBBER HAND STAMP MAKING While artificial teeth of ivory, bone, wood and metal were actually known and used by the old Egyptians yet the art of dental surgery practically died out until the middle of the 17th century. Even then dentistry was crude and primitive and it was not until the advent of rubber and the discovery of vulcanization that dentistry, as now known, came into existence. Hard rubber as a material for plates for holding artificial teeth has no superior, and even gold, which is far more costly, is no more durable and far less comfortable. Rubber is exceedingly dura- ble and will last for years without suffering injury or change from the secretions of the mouth or foods, and possesses the great advantage of being readily colored to match the real gums while undergoing vulcanization. Another most important point in favor of rubber plates for teeth is its cheapness; thousands of people who could not afford gold plates are rendered happy and able to eat their daily bread in comfort by the use of hard rubber plates for their teeth. Aside from its use in making artificial teeth, rubber is also used by dentists for dams and sheeting while gutta percha is often used in filling teeth. It is estimated that over thirty-five tons of rubber are annually used in the manufacture of artificial teeth alone, and soft rubber has a still AND THE MANIPULATION OF RUBBER. 125 wider field in surgery and medicine, so that the total consumption of the gum in these lines of work is enormous. Practically all rubber articles used in surgery and dentistry are moulded or pressed into shape while the unvulcanized rubber is hot, and are then vulcanized, — much in the same manner as in the manufacture of rubber stamps already described. Plates for teeth are made in plaster moulds, which are in turn made from impressions of the roof of the mouth made by pressing a special form of moulding wax against the flesh. The wax used is readily softened in warm or hot water, and while still warm and plastic, is pressed firmly against the roof of the mouth and from the impression thus obtained a plaster matrix is cast in fine dental plaster. The position of the teeth on the other jaw is obtained by biting firmly into another strip of wax held in a specially designed metal holder. The plaster moulds being ready, the false teeth of porcelain are set in posi- tion, the raw rubber pressed in the mould, the whole clamped firmly together and placed in the vulcanizer until thoroughly ''cured. " The process is very simple and requires no more skill or technical knowledge than in making stamps or similar objects, but to facilitate mat- ters, and render the operations more successful 126 RUBBER HAND STAMP MAKING and certain, forms, moulds, teeth and rubber come prepared in various forms, colors and sizes to suit all variations in the patients' mouths or teeth. CHAPTER XVI. Rubber Tires. constructing and repairing rubber vehicle tires, rubber preparations, chemical or cold vulcanizing. Wide and important as are the uses of rubber in surgery and dentistry, yet of almost equal importance and of far greater volume and cash value is its use in the manufacture of rubber tires for modern vehicles. Automobiles, bicycles, motorcycles, etc., were made practical and pos- sible through the use of rubber as tires for the wheels and the comfort, speed and life of all motor vehicles depend largely upon the quality of the rubber used for tires and the care taken in its manufacture. Rubber tires may be broadly divided into two distinct classes; solid tires and pneumatic tires. In the former, the tire consists of a solid, or hollow, band or rim of rubber strengthened by strips of metal, fiber or wires placed within its mass and the whole cemented or vulcanized on the wheel (Fig. 1). Such tires answer very well for small 128 RUBBER HAND STAMP MAKING vehicles, as baby carriages, velocipedes and invalid chairs, and are also largely used on commercial vehicles, trucks, etc., as well as on many horse- $ot/d T/res 3t* 9 U Tu J>e Dou b/e Tub c( Am /nner tllbe} , Fig. 1. — Sections of Rubber Tires of Various Types. drawn carriages, hacks, cabs and light wagons. The solid tires wear away rather rapidly, are heavy and cost a great deal if made of solid rubber of good quality, and do not possess the resiliency and cushion effect of the pneumatic tires. These consist of a hollow casing, or shoe, of rubber and fabric which is inflated by air and may be readily attached to or detached from the wheel itself. In the early days of rubber tires the pneumatic tires were made in the form known as "single AND THE MANIPULATION OF RUBBER. 129 tube" and were merely an endless tube of rubber and fabric inflated with air. Such tires soon became leaky and were then useless, and conse- quently proved very expensive and unsatisfactory. The system of "double tube" or "inner tube" construction was then invented, and to-day prac- tically all the pneumatic tires in use are of this character of construction. The inner tube, or double tube tire, consists of a heavy casing of rubber and fabric made in semicircular or circular section, with the inner side open. Within the cavity of this casing . a thin rubber tube is placed, and when the whole is attached to the wheel of the vehicle the inner tube is inflated. By this method much longer life is insured than by the single tube system, for in case of wear or injury to either inner tube or the outer casing the tire may be removed and a new tube or a new casing substituted as required. Pneumatic tires were first made in Europe, and were first introduced into the United States by Mr. E. J. Willis of New York in 1889. Since that date the use of the pneumatic tire has spread, and hundreds of factories are now manufacturing these goods throughout the country, while the number annually used runs into millions, — in fact a single factory sold over one million tires during the year of 1911. As the rubber used in 130 RUBBER HAND STAMP MAKING these tires must be of the best grade, and free from reclaimed or "shoddy" stock, each tire made must be built from new rubber and it can there- fore be readily seen what an enormous amount of rubber is annually consumed in this branch of the rubber industry alone. In the details of construction, each maker of tires has his own ideas and system, but in all the process is more jTjg. 2. — Construction of Pneumatic Tire. or less similar. In Fig. 2 is illustrated a section and diagram of a well-made tire, showing how AND THE MANIPULATION OF RUBBER. 131 it is built up of alternating layers of rubber and fabric. The inner layer A is ITJ^-ounce Sea Island cotton duck or fabric, cut on the bias and placed over a form or mould. This fabric is tho- roughly impregnated with pure rubber and over it is moulded a layer of pure Para rubber, B; C is another layer of cotton duck, with the lap or seam started exactly opposite from the layer A ; D is another layer of rubber, the same as B, and E another layer of duck, while F, G, H, and / are likewise alternating layers of duck and rubber. Each layer of duck has a tensile strength of 450 pounds or more, and each joint in the fabric is opposite that of the layer beneath with a long overlap. Over the last layer of duck a heavy strip of soft, pure rubber is placed, J, and is known as the ''cushion and breaker strip." This serves as a soft cushion to absorb the jar and blows to which the tire is subjected, and also prevents the various layers of cotton and rubber from loosening. Within the soft rubber cushion a strip of loosely-woven cotton fabric of extra strength is placed, and this "breaker strip" serves to bind the cushion rubber together and prevent its tear- ing or separating while in use. Over the whole of the various layers and cushion the binder strip, K, is then placed. This is a layer of specially prepared rubber which forms the outer wall of 132 RUBBER HAND STAMP MAKING the tire on the sides, and which binds all the other parts of the tire together. Over the central part of the binder a heavy "tread" of selected tough rubber is placed, M, and upon the tough- ness, composition and quality of this tread depend in great measure the life and durability of the whole tire. When the tire is completely moulded, or built up, it is thoroughly vulcanized, and in this operation the rubber-impregnated cotton, the rubber between the fabric and the cushion, binder and tread are all thoroughly and firmly united and formed into a solid, uniform mass. Good tires require a great deal of time and labor to construct, to say nothing of the cost of material, and the high prices asked for such tires is therefore not surprising or unreasonable. Of course, many cheap, poorly-constructed tires are made, but such goods wear badly, and when once injured, broken or worn are useless; whereas, a really good tire may be repaired and used over and over until completely worn out. Most reliable makers guarantee their tires for 5,000 miles and many tires are frequently used for from 12,000 to 20,000 miles. The commonest accidents to tires are "blow- outs" and "punctures." Blow-outs are caused by faulty construction, poor inflation, rotting of fabric, overloading or excessive speed, and consist AND THE MANIPULATION OF RUBBER. 133 of a hole or tear blown clear through the casing from the inner side. Blow-outs, if not too large, may be repaired by relining and vulcanizing. Punctures are small holes made by running over nails, sharp stones, glass, etc., and are readily repaired. The greatest enemy to tires is heat, and this is usually caused by excessive speed, owing to the constant friction of the various fibers and threads of the cotton fabric rubbing against one another. More or less heat is also generated by the friction of the tire upon the road itself, but this is seldom sufficient to cause damage. The harder a tire is inflated the less chance there is of friction occurring in the tire itself, and for this reason every tire should be kept properly inflated, according to the directions furnished by the maker. The business of repairing tires has now grown to enormous proportions, and large factories are engaged solely in making appliances and materials for this industry. The usual method of repairing a broken or punctured tube is to place a raw rubber patch over the hole, cement it in place and vulcanize both patch and cement. In the case of outer casings the work is far more difficult and complex, for the casing may require either a new tread or a new lining, according to the 134 RUBBER HAND STAMP MAKING damage to be repaired. In the case of a new tread, the parts are thoroughly cleansed, soft rubber composition spread over the place to be repaired, the mass held in position by a winding of tape or cloth and the whole vulcanized. Where a new inner lining or fabric is required, the webbing, impregnated with rubber, is moulded in the inside of the casing and is then vulcanized. Vulcanizing for repair work is usually accomplished by steam heat, but numerous portable vulcanizing outfits for use with gasoline, alcohol, gas, kerosene or electricity are now made and for sale at most reasonable prices, and with one of these outfits any user of rubber tires can readily make his own repairs. Great advances have been made in the lines of rubber cements, rubber compounds and curing or vulcanizing methods, since the advent of the rubber-tired vehicle. Rubber cements are now on sale which are so easily used and of such excel- lent quality that vulcanization is entirely unneces- sary under ordinary conditions, and by patching the rubber article with a prepared patch and one of the various standard cements, the article repaired will be as good as new. Other patches and materials are made which are coated with strong adhesive rubber prepara- tions requiring no cement, while various com- AND THE MANIPULATION OF RUBBER. 135 positions of rubber for filling holes, cuts, tears, etc., in rubber articles are widely used. Such a great number of these preparations are now on the market that it is hard to know what to use or what is good and what not, but practically any of the various preparations put up by reliable firms will prove satisfactory for the purpose for which they are designed. Among the various preparations the following have all been tested thoroughly by the writer and have been found to fulfill all the claims of the manufacturers and can be recommended most highly. Cements for patching: "Fisk," "Dia- mond," "Goodrich," "Stickfast," "Willis." Cements for patching (to be used with "acid cure"): "Good- rich," "Half and Half," "C.O.T.," "Congo," "M & M," "Pluto," "Hazenoid." Vulcanizing preparations (acid cures): "M & M," "Vulcanoid," "C.O.T." Cement for vulcanized work: "Good- rich," "Hazen-Brown," "M & M." Prepared patches for use without cement: "Wonder- worker," "Victor," "Continental." Filling com- position for cuts in casings: "Phil-Kut," "Gum- Gum," "Plastic," "M & M," "Kneadit," "Rubber- Tread," "Nu-Tread." Portable vulcanizing out- fits, steam: "Shaler," "National." Portable vul- canizing outfits, electric: "Shaler." Portable vulcanizing outfits, alcohol: "Shaler." Portable 136 RUBBER HAND STAMP MAKING vulcanizing outfits, gasoline: "Shaler," "Stitch in Time," "Imperial," "Pig." By merely follow- ing the plain directions furnished with each of these various compositions or vulcanizing outfits, anyone can make satisfactory repairs in either casings or tubes, and aside from saving the cost of having it done outside, the satisfaction of knowing just how your repairs are made and how thoroughly the work is done, is of great importance. Many excellent tires are constantly ruined through neglect of small cuts, bruises, etc., and these should always be cleaned and filled with one of the various plastic fillers mentioned above. In using any preparation of rubber however the greatest care should be taken to do the work thoroughly and properly, for a small neglect in cleansing the material to be repaired or in other small matters will result in a poor and unreliable job which cannot be depended upon. Within the past few years great improvements have been made in methods of vulcanizing or "curing" rubber, especially when in the form of small patches or other repair work. Not only have the small compact and portable vulcanizers been highly perfected but various chemical methods of curing have been invented and brought into general use. These cold, or chemical, methods AND THE MANIPULATION OF RUBBER. 137 are commonly known as "acid cures" and consist of certain chemicals containing some form of sulphur which applied to the raw rubber acts in the same manner as heating with sulphur. The preparations vary considerably in their com- position but usually consist principally of sulphur chloride, benzine, and carbon bisulphide. They are highly inflammable and explosive and great care should be taken not to use them near a flame or in the vicinity of a hot stove or similar object. The preparation is brushed over the raw rubber, and through the action of the sulphur contained in the solution the rubber is quite thoroughly vulcanized. For small work this method is far easier and cheaper than by the heating process and many rubber stamps and similar articles are now vulcanized by one of the various chemical methods. So enormous has the consumption of rubber become that the demand has far exceeded the supply and in the constant search for new rubber- producing plants, various trees, shrubs and vines have been found to furnish rubber or rubber-like gums or sap that are now used extensively as a substitute for rubber or as an adulterant of pure rubber. Among these may be mentioned the Balata rubber from a large forest hardwood 138 RUBBER HAND STAMP MAKING tree of the West Indies and tropical America; Guayule rubber from a Mexican shrub; Sapota rubber from a tropical fruit tree, and Chicle rubber from another common fruit tree of tropical America. Balata rubber is very good and is widely used and for many purposes compares favorably with true Para rubber. Guayule is also extensively used and is produced in large quantities from a plant until quite recently considered worthless. The milky juice of the Sapota tree furnishes the Sapota rubber and Chicle of commerce and the latter is of great value for use in manufactur- ing various confections, such as chewing gums, etc. Rubber articles, when kept in a warm, dry place or in a very cold spot, often grow quite hard and inelastic; and while excessive hardening of rubber goods is usually a sign of inferior quality in the rubber, yet the highest grade goods are at times subject to this trouble. Most rubber articles may be readily softened by treatment with dilute ammonia, — about one part of ammonia to two parts of water. Before treating with this solution the articles should be thoroughly cleansed by scrubbing with a stiff brush and warm water. Place the cleansed articles in the ammonia and let them remain until the ammonia has evaporated, usually from one to two hours. After treatment with ammonia the goods should be rinsed with AND THE MANIPULATION OF RUBBER. 139 a dilute solution of glycerine and water, thoroughly wiped and dried and stored in a cool spot away from the light. Another method for softening hard or brittle rubber goods is to place them in a hot aqueous solution of tannic acid and tartar emetic. Next transfer them to a cold solution of tannic acid and calcium sulphate. Mix the two solutions and heat to boiling point and place the rubber goods in this hot solution. The treatment should be continued for from one to four days, according to the size and nature of the articles. Old rubber stoppers that have become hard and useless may be revived by soaking in a 5 per cent soda lye solution for about ten days at from 85 deg. Fahr. to 104 deg. Fahr., replacing the lye from time to time. The stoppers should then be thoroughly washed and the softened outer surface scraped off with a dull knife until the firm, elastic portion is reached. The stoppers should then be rinsed with warm water and will be found quite soft and flexible. They may be readily trimmed with a sharp knife wet with cold water and soft soap. For many purposes reclaimed rubber is widely used and answers as well as new, pure rubber. The scraps, old rubber, waste, etc., is first boiled in strong caustic soda or in sulphuric and hydro- 140 RUBBER HAND STAMP MAKING chloric acid until all cloth, paint, fillers, etc., are dissolved and separated and the rubber is then ground and pulverized between rollers and pressed into sheets. Other processes include mixing the reclaimed rubber with mineral oil or benzol and steam under hydraulic pressure while an adulterated mixture or composition rubber is formed by adding the reclaimed rubber to hot linseed oil until dissolved, when coal tar or asphalt is added. When thorough- ly combined the mass is heated to a much greater temperature and air is forced through the mass. The resulting compound, when cool, is very tough and flexible and is of great value for insulating electric wires, cables, etc. For many years various attempts have been made to discover or invent a satisfactory artificial rubbers but although various compounds have been made which in a way answer as a substi- tute, yet none fulfills all the requirements. The so-called "Kerite" consists of a mixture of: Cottonseed oil 14 parts Linseed oil 14 Asphalt 8 Coal tar 8 Sulphur 10 Camphor V2 AND THE MANIPULATION OF RUBBER. 141 By combining a mixture of: Cottonseed oil 27 parts Coal tar 30 " Earthy matter 5 with : Rubber 20 parts Litharge 5 Sulphur 1 n a tough, rubber-like mass is formed which is widely used in place of pure rubber for stoppers, bumpers, etc. Recently, also, various experiments have been made with compounds obtained from turpentine and coal tar, and excellent results obtained, but the process is long and complicated and the artificial rubber thus produced has proved more expensive than the genuine article. While these various substitutes have proved valuable for many purposes, yet no one has yet discovered anything that will take the place of Nature's product, and a vast fortune awaits the fortunate discoverer of a true artificial rubber that can be produced as cheaply or cheaper than the real article. CHAPTER XVII. THE HEKTOGRAPH. For obtaining multiple copies of writing, the apparatus called the Hektograph or Papyrograph has been extensively adopted. In general terms it consists of a tray filled with a jelly like composition. Any imprint made upon the surface with aniline ink can be transferred to paper by simple pressure. The tray filled with composition is called the tablet. It is thus prepared. The tray may be made of tin or even of paste- board or paper, and should be about one half an inch deep. It may be of any size, according to the work it is to do. The composition is made from the best gelatine and glycerine. One ounce by weight of gelatine is soaked over night in cold water, and in the morning the water is poured off, leaving the swelled gelatine. Six and one-half fluid ounces of glycerine are now heated to about 200 F. (93 C.) on a water bath preferably, and the gelatine is added thereto. The heating is continued for several hours. This operates to expel the water and to give a clear glycerine solution of gelatine. The composition is then poured into the tray, AND THE MANIPULATION OF RUBBER. 143 which must be perfectly level in order to obtain a a surface nearly even with the edge. It is then covered so as to keep off the dust. The cover of course must not come in contact with the smooth surface. In six hours it will be ready for use. The original copy that is to be reproduced is made upon ordinary paper in aniline ink. One formula for the ink reads as follows: Aniline violet or blue (2KB or 3 B) 1 oz., hot water 7 fluid oz. ; dissolve. After cooling add alcohol 1 fluid oz. and glycerine % fluid oz., a few drops of ether and a drop of carbolic acid. Keep in a corked bottle. Other formulae are given in chapter XVII. The writing is executed with an ordinary steel pen. The lines should be rather heavy so as to show a greenish color by reflected light. The surface of the pad is slightly moistened with a wet sponge and is allowed to become nearly dry. The paper is then laid upon it and smoothed down. This is best done by placing a second sheet over it and rubbing this with the hand. No air bubbles must remain between the copy and the tablet, and the paper must not be shifted. It is allowed to remain for a minute or less and is then raised by one corner and stripped from the gelatine surface. It will have left the reversed copy of its inscription perfectly reproduced upon the tablet. At once a piece of ordinary writing paper of the desired size and quality is laid upon the tablet. 144 RUBBER HAND STAMP MAKING smoothed down, and stripped off, when it will be found to have taken witii it a complete copy of the inscription or writing. This is repeated over The Hektograph. and over again with another sheet of paper, until the ink on the pad is exhausted. Fifty or more good copies can be thus obtained. As soon as the work is completed the remains of the ink should be washed off with a moist sponge AND THE MANIPULATION OF RUBBER. 145 and the tablet, after drying a little, will be ready for a second operation. Some practice is required to ascertain the proper strength of the writing and degree of wetness of the surface. When the gelatine surface becomes im- paired it can be remelted in a water bath if it is not too dark from absorption of ink. French M in istery of Public Work Formula. — Glue 100 parts, glycerine 500 parts, finally powdered kaolin or barium sulphate 25 parts, water 375 parts. Use a little hydrochloric acid in the water for washing off the pad after use. Hektograph Sheets. — Four parts of glue are soaked in five parts of water and three parts of ammonia until soft. It is then heated and there is added to it three parts of sugar and eight parts of glycerine. The mixture is applied to blotting paper. This is saturated with it, and successive coats added until a smooth surface is produced on one side. This is the side for reproduction. It is used like the regular tablet except that it is claimed that sponging off the writing is not necessary. Owing to the capillary action developed by the blotting paper it is sup- posed to be self-cleaning by standing. CHAPTER XVIII. CEMENTS. Before cementing vulcanized rubber the surface should be roughened or still better it may be seared with a red hot iron. For bicycle tyres this is espe- cially to be recommended. Cement for Outs in Bicycle Tyres, Rubber Belts, etc. — Carbon bisulphide, 5 ounces; gutta-percha, 5 ounces; caoutchouc, 10 ounces; fish glue, %y 2 ounces. After it is applied and has dried the excess can be removed with a wet knife. Bad cuts should first be stitched up. Bicycle Tyre Cement to fasten Tyres to Rims. — Equal parts of pitch and gutta-percha are melted together. Sometimes two parts of pitch are pre- scribed. This cement has extended applica- tion. Cement for Paper Boats and for Mending Rubber Goods. — Fuse together equal parts of pitch and gutta-percha, and to this add about 2 parts of lin- seed oil containing 5 parts of litharge. Continue the heat until the ingredients are uniformly com- mingled. Apply warm. Waterproof Cement. — Shellac, 4 oz; borax, 1 oz; AND THE MANIPULATION OF RUBBER. 147 boil in a little water until dissolved, and concentrate by heat to a paste. \ Another.— 10 parts of carbon disulphide and one part of oil of turpentine are mixed, and as much gutta-percha is added as will readily dissolve. Cement for Mending Hard Etcbber.—Fnse together equal parts of gutta-percha and genuine asphaltum; apply hot to the joint, closing the latter immedi- ately with pressure. Glue to Fasten Leather, etc., to Metals.— 1 part crushed nut galls digested 6 hours with 8 parts dis- tilled water and strained. Glue is macerated in its own weight of water for 24 hours, and then dis- solved. The warm infusion of nutgalls is spread on the leather; the glue solution upon the rough- ened surface of the warm metal; the moist leather is then pressed upon it and dried. Marine Glue, Various Formulce.—I. Dissolve 1 part of india rubber in 12 parts of benzole, and to the solution add 20 parts of powdered shellac, heat- ing the mixture cautiously over a fire. There is great danger of conflagration. Apply with a brush. II. Caoutchouc, 1 oz; genuine asphaltum, 2 oz; benzole or naptha, q. s. The caoutchouc is first dis- solved (as described in chapter XII.), and the asphaltum is gradually added. The solution should have about the consistency of molasses. Cement for Vulcanized India Rubber. —Stockholm pitch, 3 parts; American resin, 3 parts; unmixed india rubber, 6 parts; oil of turpentine, 12 parts. 148 RUBBER HAND STAMP MAKING Heat and mix very thoroughly. More oil of turpen- tine may be added as required. Gutta-Percha Cement for Leather. — Soak gutta- percha in boiling water. Soften in benzole after cut- ting up for a day. Heat on a water bath until the greater part of the benzole is expelled. When cool it will solidify. Use by heating. Cement for Rubber Shoes. — (1) Chloroform 280 parts. India rubber (masticated) 10 " (2) India rubber 10 " Resin 4 " Venice turpentine 2 " Oil of turpentine 40 " For first solution dissolve by mastication. For second, melt the finely divided gum with the resin, add the Venice turpentine and finally the oil of tur- pentine. Use heat if necessary. Mix both solu- tions finally. To apply, saturate a piece of linen with the cement and apply to the spot previously coated with the cement. As it dries apply a little more as required. A finishing varnish is given in the last chapter. Parkes* cold curing process may be applied as described in chapter XL Chatterto?i's Compound for uniting sheets of gutta-percha in cable cores and for general work with gutta-percha coated wires. — Stockholm tar, 1 part; resin, 1 part; gutta-percha, 2 parts. Waterproofing for Wooden Battery Cells. — Resin, 4 parts; gutta-percha, 1 part; boiled oil, a little. AND THE MANIPULATION OF RUBBER. 149 Another Formula. — Burgundy pitch, 150 parts; old gutta-percha in fine shreds, 25 parts; ground pumice stone, 75 parts. Melt the gutta-percha and mix with the pumice stone and then add the pitch, melting all together. Apply melted and smooth off with a hot iron. Cement for Celluloid. — Shellac, 1 part is dissolved in spirits of camphor 1 part, with 3 to 4 parts strong alcohol. It is applied warm and the parts united must not be disturbed until the cement is hard. CHAPTER XIX. INKS. KUBBER STAMP INK. Aniline blue soluble, 1 B 3 parts. Distilled water 10 " Acetic acid 10 " Alcohol 10 " Glycerine 70 " For other colors the following aniline colors may be substituted in proportions given: Methyl violet, 3 B (violet) 3 parts. Diamond fuchsin I, (red J 2 " Methyl green yellowish 4 " Vesuvin, B (brown) 5 " Nigrosin, W (blue black) 4 " For very bright red 3 parts of Eosin BBN. are used. In this case the acetic acid must be omitted. In all cases the colors should first be rubbed up with the water in a mortar, and the glycerine should be added gradually. These inks will answer for the hektograph. Hektograph Ink. — Aniline color, 1 part; water, 7 parts; glycerine, 1 part. A little alcohol may be AND THE MANIPULATION OF RUBBER. 151 used with advantage to dissolve the aniline color. It can be expelled by heating if it proves objection- able. Aniline Ink Vehicle. — Prof. E. B. Shuttleworth, of Toronto, Ont., suggests the use of castor oil in place of vaseline and other vehicles for typewriter ink. The aniline colors may first be dissolved in alcohol, and the solution may be added to the oil. They may also be dissolved directly in the oil in which most of them are soluble. Indelible Stamping Inks. — I. Asphaltum, 1 part; oil of turpentine, 4 parts; dissolve and temper with printer's ink. The ink may be omitted, and solid dry color added. II. Sodium carbonate, 22 parts; glycerine, 85 parts; dissolve and rub up in a mortar with gum arabic, 20 parts. In a separate vessel dissolve silver nitrate, 11 parts; in officinal aqua ammonia, 20 parts. Mix the two solutions, and heat to the boil- ing point, 212° F. (100° C). After it darkens, add Venice turpentine, 10 parts. After applying to the cloth, a hot iron should be applied, or it should be exposed to the sun. III. Dr. W. Reissig's formula: Boiled linseed oil varnish 16 parts. Finest lamp black 6 " Ferric chloride (sesquichloride of iron) 2 to 5 " 152 RUBBER HAND STAMP MAKING Dilute a little for use with varnish. After this ink has been removed, no matter how completely it can be detected by dipping the paper into a solution of ammonium sulphide. IV. Aniline black in crystals 1 part. Alcohol 30 f ' Glycerine 30 " Dissolve in the alcohol, and add the glycerine afterwards. Show Card Ink. — Pure asphaltum 16 parts. Venice turpentine 18 " Lamp-black 4 " Oil of turpentine 04 " Dissolve the asphaltum in the turpentine, and thoroughly mix. Stencil Ink. — Shellac, 2 ounces; borax, 2 ounces; water, 25 ounces. Dissolve by heat if necessary, first the borax alone, and then adding the shellac. To the clear solution add gum arabic, 2 ounces. Color with lamp-black, with Venetian red, or with ultramarine, to suit the taste. Another formula gives shellac, 4 parts, borax, 1 part, and omits the gum arabic. Copying Ink (for use without a press by simply pressing and rubbing with the hand), by Prof. Atfc- field, F.R. S. — Use ink of any kind of extra strength. AND THE MANIPULATION OF RUBBER. 153 This in many cases can be made by evaporating common ink down to six tenths of its volume. Then mix with it two thirds of its volume of glycer- ine, so as to restore the original volume. White Ink. — Barium sulphate, or " flake white " is mixed with gum arabic water of sufficient thick- ness to keep it suspended, at least while in use. Starch or magnesium carbonate or other white pow- der may be used instead of the barium sulphate. The powder must be of impalpable fineness. White Ink on Blue Paper. — A solution of oxalic acid in water is used for this purpose. It may be applied with a rubber stamp or with a common pen. A quill or gold pen is the best as a steel pen is soon corroded. The ink bleaches the paper wherever it touches it, giving white lines on a blue ground. Gold Ink. — Gold leaf with honey is ground up in a mortar, best an agate mortar, or on a painters' slab with a muller. It is added to water, and thor- oughly mixed and at once poured off from the first sediments, filtered out, and washed. This is done to secure the impalpably finely ground gold only. The resulting powder is mixed with a suitable vehi' cle, such as white varnish or gum arabic water. Silver Ink. — As above, using silver leaf. Zinc Label Ink. — I. Verdigris, 1 part; ammo- nium chloride, 1 part; lamp-black, \ part; water, 10 parts. II. Platinum bichloride, 1 part; gum arabic, 1 part; water, 10 parts. 154 RUBBER HAND STAMP MAKING Diamond Ink for Etching Glass. — This consists essentially of hydrofluoric acid mixed with barium sulphate to the consistency of cream. The barium sulphate is quite inoperative except as giving a body to prevent the ink from spreading. It is applied with a rubber stamp or pen and allowed to remain for ten minutes or until dry. On removal of the white powder, the design will be found etched on the glass. The following is a formula for it. Saturate hydrofluoric acid with ammonia, add an equal volume of hydrofluoric acid and thicken with barium sulphate in fine powder. CHAPTER XX. MISCELLANEOUS. To Soften and Restore India Rubber Hose, etc. — I. Dip in petroleum and hang up for a couple of days. Repeat process if necessary. II. The above process is applicable to all articles, but is specified for hose. It is stated that old rub- ber that has become hard may be softened by expos- ure first to vapor of carbon disulphide, followed by exposure to the vapor of kerosene. The latter vapor is found to be a general preservative for india rubber. III. Dr. Pol recommends immersion in a solution of water of ammonia, 1 part, and water 2 parts, from a few minutes to an hour. To Prevent Decay of Rubber Tubing.— -The decay of rubber tubing has been attributed to the forma- tion of sulphuric acid from the sulphur mixed with it. M. Ballard has suggested washing with water or weak alkaline solution five or six times in a year. Joints between India Rubber Tubing and Metal. — Where tubing is temporarily slipped over metal gas pipes and similar connections, as in the chemical lab- oratory, it is well to apply glycerine to the metal. 156 RUBBER HAND STAMP MAKING It acts as a lubricant in slipping the tubing on, and assists in its withdrawal. Preserving Vulcanite. — Wash occasionally with a solution of ammonia and rub with a rag slightly moistened with kerosene oil. Effect of Copper upon Rubber. — In a paper read be- fore the recent meeting of the British Association, Sir William Thomson stated that metallic copper, when heated to the temperature of boiling water, in contact with the rubber, exerted a destructive effect upon it. With a view to finding whether this was due to the copper per se, or to its power of conduct- ing heat more rapidly to the rubber, he laid a sheet of rubber on a plate of glass, and on it placed four clean disks, one of copper, one of platinum, one of zinc and one of silver. After a few days in an incu- bator at 150° F., the rubber under the copper had be- come quite hard, that under the platinum had be- come slightly affected and hardened at different parts, while the rubber under the silver and under the zinc was quite hard and elastic. This would warrant the inference that the metallic copper had exerted a great oxidizing effect on the rubber, the platinum had exerted a slight effect, while the zinc and silver respectively had no injurious influence on it. The rubber thus hardened by the copper con- tained, strange enough, no appreciable trace of cop- per; the copper, therefore, presumably sets up the oxidizing action in the rubber without itself perme- ating it. AND THE MANIPULATION OF RUBBER. 157 Gas Tight Tubings. — Fletcher has invented a gas tight rubber tubing in which a layer of tinfoil is in- terposed between two concentric rubber tubes, all vulcanized together. Printing Colors upon India Rubber. — It may some- times be desirable to have a surface of vulcanized in- dia rubber so prepared that it will take colors such as are used for calico printing. This end is simply at- tained by sprinkling the article with farina before vulcanizing. A small quantity attaches itself and forms an excellent base for color printing. Gutta-Percha for Coating Glass. — For focusing glass in photography and for similar purposes where ground glass or a translucent material is required, a solution of gutta-percha in chloroform is highly recommended. This is flowed over or painted on the glass and is allowed to evaporate afterwards. Burned Rubber. — A very soft pure gum sold for artists' use is improperly termed burned rubber. It is used in crayon work for removing and lightening marks by dabbing it against the paper, cleaning the rubber from time to time. It is so soft that it picks up and removes crayon marks without the necessity of friction. Thus the rubbing out or more properly erasing operation can be localized and crayon tints can be lightened in tone without impairment or "smutting." It is a very elegant accessory to the artists' paraphernalia. To make it, pure virgin gum, preferably the best Para, is cut into pieces and soaked for some hours in benzole. A long soaking is ad- 158 RUBBER HAND STAMP MAKING visable. The pieces are then removed from the ben- zole and are ground in a mortar until perfectly hom- ogeneous. The mass is gathered up with a spatula and is pressed into little tin boxes. If desired it may be dried upon a water bath. This is not nec- essary as, if the box is left open, it will rapidly season itself. It should be very soft, should tend to adhere to the fingers, yet should leave them easily, and should strip cleanly from the box. A very little turpentine makes it more adhesive. It may even be softened in turpentine alone. This gives a gum that seasons more slowly and is in some respects pref- erable to the benzole made preparation. It is sold at a high price by the dealers, as the demand for it is limited. Rubier Sponge. — This is also an artist's rubber. It is also used for cleaning kid gloves. It is made by incorporating with the masticated or washed and sheeted gum any material or materials that will give off vapor in the curing process. Damp sawdust and crystallized alum are used as giving off vapor of water or steam, or ammonium carbonate as giving off vapors of ammonia carbonic acid gas and steam. The mixed gum may be cured in moulds, which it will fill by its expansion. Shellac Varnish for India Rubber. — This is made by soaking powdered shellac in ten times its weight of strong aqua ammonia (26° B.). At first no change beyond a coloring of the solution is percep- tible. After many days standing the bottle, which AND THE MANIPULATION OF RUBBER. 159 should have a glass stopper, being tightly closed, the shellac disappears, having entered into solution. It may be a month before complete solution. This forms an excellent varnish for india rubber shoes and similar articles. It may be applied with a rag. It is also a good application for leather in some cases and doubtless many other uses could be made ot it. It would act well as a vehicle for a dark pigment such as lamp-black. It will reju- venate a pair of india rubbers very nicely. The ammonia exercises also a good influence on the rub- ber. It has been recommended as a cement for attaching rubber to metal, but its adhesive powers are not always satisfactory. Simple Substitute for Stamjjs. — A very simple though rough and imperfect substitute may be made by gluing with common carpenter's glue pieces of thick string upon a piece of wood, the string being given the form of the desired letters. Care must be taken to avoid saturating and stiffen- ing the string with the glue. India Rubber Substitutes. — One of these under the name of vulcanized oil is thus described by Bolas: " Vulcanized oil is, perhaps, of more interest, and many oils, such as linseed and others resembling it, may be vulcanized by being heated for some time to 150° Centigrade with twelve to twenty per cent, of sulphur. The product obtained is soft, and some- what resembles very bad india rubber. By increas- 160 RUBBER HAND STAMP MAKING ing the proportion of sulphur very much indeed, say to four times the weight of the oil, and vulcanizing at a higher temperature, a hard substance, resem- bling inferior vulcanite, is obtained. "Soft and hard vulcanized oil have been intro- duced into commerce at various, times and under many names; but these materials never seem to have made very much headway. " Another method of treating the oil consists in mixing it with a solution of chloride of sulphur in carbon disulphide or in naptha. On standing, the volatile solvents escape, leaving a thick mass, which is the substitute. In combinations of aluminum with the fatty acids, forming aluminum soaps, and of these, alu- minum palmitate especially, a substitute for india rubber has been sought but without success. Metallized Caoutchouc. — Unvulcanized gum is mixed with powdered lead, zinc, or antimony. The mixed india rubber is then cured as in the regular process. EMERY WHEELS AND WHETSTONES. Bolas thus describes their manufacture: " When ordinary vulcanized rubber is heated to 230° Centigrade, (446° F.) or until it melts, a per- manently viscous product is obtained, and this sub- stance, if mixed with emery and sulphur to a kind of paste, forms a material out of which the so-called agglomerated emery wheels or grinders may be AND THE MANIPULATION OF RUBBER. 161 formed, the mixed materials being next hardened or cured by the application of a steam heat. Emery wheels and hones made on this principle were intro- duced by Deplanque about twenty-three years ago. " Thirty-five parts of old vulcanized caoutchouc having been placed in a kind of still, heat is applied to melt it, the operation being assisted by the grad- ual addition of about ten parts of heavy coal oil; but this latter is afterward distilled off. The soft- ened caoutchouc is then incorporated with 500 parts of emery of the required degree of fineness and nine parts of sulphur. These materials having been thoroughly mixed, the hones or wheels are manufactured, and afterward cured or baked at a heat of 140° Centigrade, (284° F.) during a period of about eight hours. Grinding wheels, made in the above manner, can be worked at a speed of 2,000 revolutions per minute, and are extremely useful for the working of hardened steel or other obdurate materials." Etching on Metals and Glass. — India rubber stamps can be used for placing the ground upon knife blades and similar articles which are to be etched. The parts untouched by the stamp are attacked by the acid. In the case of glass, diamond ink (page 133) can be put on with a stamp. The acids for metal etching might be thickened with barium sulphate also and applied in the same way. In these cases the inscription of the stamp would be etched. Where ground is put on, whether on glass or 162 RUBBER HAND STAMP MAKING metal, the design for the stamp will be pro- tected. Etching Ground for Metals. — Equal parts of as- phalt, Burgundy pitch and beeswax melted together and mixed thoroughly. It may be softened with mutton suet. Beeswax may be used, dissolved in ether or simply melted. Yellow soap is sufficient for ordinary work. Etching Solutions for Biting %n. — For steel and iron, a. sulphate of copper and common salt in solu- tion, b. sulphate of copper, sulphate of alumina, and common salt, of each two drachms; acetic acid, 1}4 oz. c. sulphuric acid, diluted with five vol- umes of water with a little sulphate of copper. For other metals, except gold and platinum, nitric acid diluted with five volumes of water. Etching Ground for Glass. — Melted beeswax is generally recommended. It can be removed with spirits of turpentine after as much as possible has been scraped off. Etching Glass. — Glass may be conveniently etched by exposing it to the vapor of hydrofluoric acid. A shallow leaden tray, as large as the glass, is re- quired. A quantity of fluorspar is placed in it and is moistened with concentrated sulphuric acid. The glass is placed face downward over the tray. It is supported over the mixture by resting on the edges of the tray or by any simple method, and the whole is covered with a towel. In half an hour or more the etching will be completed. The vapors AND THE MANIPULATION OF RUBBER. 163 must not be allowed to escape into any room con- taining glass or metal articles as they corrode every- thing. Great care should be taken also not to let the mixture touch the hand, as painful ulcers are the result. India Rubber Shoe Blacking. — Raw india rubber is given as a constituent of several shoe blackings. Formulae are given as below for paste and liquid blackings. I. Paste blacking: bone-black, 20 parts; molasses, 15 parts; vinegar, 4 parts; sulphuric acid, 4 parts; caoutchouc oil (as given below), 3 parts. II. Liquid blacking: bone-black, 60 parts; mo- lasses, 45 parts; gum arabic dissolved in water, 1 part: vinegar, 50 parts; sulphuric acid, 24 parts; caoutchouc oil, 9 parts. Caoutchouc oil is made by dissolving or digesting virgin rubber 55 parts in linseed oil 450 parts. Waterproof Composition for Boots. — One ounce of virgin rubber cut into pieces is digested in enough oil of turpentine to form a stiff paste. In applying heat take great care lest the contents of the vessel become ignited. When homogeneous, which con- dition may be brought about by rubbing in a porce- lain mortar, as described in chapter XII., it is mixed with 5-6 ounces of boiled linseed oil. This gives an ointment almost of the consistency of butter. INDEX. TAGE Absorption of sulphur pro- cess 100 Absorption of water by in- dia rubber 31 Africa, ways of collecting rubber sap 15-17 Analysis of sap of india rub- ber tree 27 Apparatus for stamp mak- ing 61-63 Artificial limbs 123 Artificial teeth 124 Artists' burned rubber . 157-158 Balloon? 95 Bands, india rubber 41 Bicycle tire cement 146 Blacking, india rubber 163 Borax and water solution of rubber 106-107 Brazil, ways of collecting sap 20-21 Bromine as vulcanizer 100 Bulbs, how made 92-93 Burned rubber, artists'. 157-158 Calendering 43 Cane tips 90 Caoutchin 30 Caoutchoucin 30 Caoutchouc (see India rubber). Cements 146-149 Clamp for vulcanizing press 52 Cleaning rubber goods 138 Cohesion of rubber, its im- portance to the manufac- turer 26-27 Cold curing 100-102 Composition for stamps and its moulding 1 13-120 Composition inking pad.l 1 8-119 Composition stamp handle . 117-118 PAGE Cord, rubber 92 Corks 90-91 Curing 44 Curing, how to judge of completion of 70 Curing in liquid bath 97 Curing in sulphur bath. ... 99 Curing, temperature of . . . . 58 Central America, ways of collecting rubber 18-19 Chair leg tips 90 Chalk plates 83-84 Chlorine as vulcanizer 100 Chloroform as a solvent .... 105 Coagulation of sap by a plant 19 Coagulation of sap by alum. 22-23 Coagulation of sap by fire 21-22 Coagulation of sap by salt . . 18 Cohesion of pure rubber .... 25 Dating stamps, composi- tion 116-117 Didot's polytype for ma- trices 82-83 Distillation products of in- dia rubber 29-30 Dolls, how made 92-93 Ebonite 108-111 Ebonite, polishing 110-111 Emery wheels and whet- stones 160-161 Emulsion of caoutchouc. ... 10 Etching 140-163 Fins, removal of 86 Flask for type moulding .... 74 Flong matrices 80-82 Flong paste 80 Fluid for mixing with plas- ter for matrices 55 Gas heated steam vulcanizer 53 INDEX. 165 Glue, marine 126 Glue stamps 113-120 Glycerine bath for curing . . 97 Goodyear, Charles 13-14 Gutta-percha 111-112 G u tt a-percha , moulding. 111-112 Gutta-percha, vulcanizing . Ill Hektograph, composition. 142, 143. 144 Hektograph, how made and used 142-144 Hektograph ink (also see inks) 142 Hektograph sheets 145 India Rubber, absorption of water by 31 India rubber, African. . . . 15-17 India rubber, artists' burned 157-158 India rubber, availability for small articles 85 India rubber, cohesion of unvulcanized 25 India rubber, composition of 27 India rubber, discovery of, etc 11-13 India rubber, effects of tem- perature on 28-29 India rubber, elasticity of 28—29 India rubber sap, its coagu- lation 11 India rubber sheet, how made 40 India rubbers, original way of making 10 India rubber stamp making without apparatus 71 India rubber stamps, home- made mould 48-50 India rubber stamps, start- ing point 47 India rubber, trees produc- ing 9 India rubber tree sap, analysis of 27 India rubber type 73 India rubber, vulcanized, general properties of . . . 32-33 India rubber, where col- lected 11 India rubber, nelastic, how made 31 India rubber, its mastica- tion 38-40 India rubber, manufacture of 35-46 India rubber, necessity of drying 38 India rubber, points to be followed in moulding small articles 85 India rubber, preliminary operations in manufac- turing 35-36 India rubber, preserving, etc 155-156 India rubber, properties of . 28 India rubber sap 9-11 India rubber stamp vulcan- izing 58-60 Inelastic state of india rub- ber 31 Inks, special for stamping, etc 150-154 Inner tube 129 Iodine and haloid vulcan- izers 100 Isoprene 30 "Kerite" 140 Leaves, skeletonized as models 92 Liquid bath curing 97 Machine for cutting sheet and threads 40 1G6 INDEX. Machine for making mixed sheet 42-43 Machine for masticating . 38-40 Machine for washing and sheeting 37 Mackintosh 13 Mackintoshes, how made. 45-46 Marshmallow not for mix- ture with plaster 57 Masticated rubber, its easy solution 103-104 Masticating in mortar with benzole 103-104 Mastication of rubber. . . 38-40 Materials mixed with india rubber 43 Matrices, various kinds of, for stamps 80-84 Matrix for stamp-making. 54-55 Matrix making by casting. 56-57 Matrix press 56 Matrix, process of making, for stamps 54-55 Mats 91-92 Metals, welding and cohes- ion of 25-26 Miscellaneous 155-163 Mixed sheet 42-44 Mixed sheet for stamps . . 47-48 Mould, home-made for stamps 48-50 Moulding and curing stamps 58-60 Moulds for composition stamps, temperature of. . 120 Moulds, material for 86 Naphtha and volatile solv- ents, danger of 107 Naphtha, solvent 104-105 Nicaragua, ways of collect- ing sap 19-20 Nitric acid as vulcanizer. . . 100 Oil for composition stamp moulds 119-120 Oil for mould face 55 Oils, fixed, bad effect on solutions 105 Oxychloride of zinc cement for matrices 57 Papier macho matrices . . 80-82 Paraffin and rubber. . . 105-106 Parkes' process 100-102 Payen's solvent 105 Pencil tips, moulds for. . . 89-90 Phenyle sulphide as softener of vulcanized rubber. . . . 106 Plaster dental for matrices . 54 Press for moulding stamps, etc 51-52 Press, gas-heated 52-53 Press, home-made 49 Press, matrix making .... 55-56 Products, general division of 35-36 Repairing tires 133 Rods, stirring for labora- tory 95 Rubber in surgery and dentistry 121 Rubber, origin of name 12 Rubber (see India rubber) . Rubber tires 127 Salt bath for curing 98 Sap of india rubber tree, analysis of 27 Sheeting and washing .... 37-38 Sheet rubber, how made ... 40 Sheet rubber, its joining ... 94 Shellac for strengthening matrix 55 Shoes blacking for 163 Shoes, india rubber, cement for 148 Siphonia, origin of name. . . 11 INDEX. 167 Solution, different views of 31-32 Solution, difficulties of 103 Solvents for rubber .... 104-105 Spring chase for matrices. . . 56 Springs for stamp moulds. . 51 Springs on moulding press. 51 Sponge india rubber 158 Stamp making 47 Stamps, rubber, substitute for 159 Stamps (see India rubber, Composition and general titles). Strauss' method of coagu- lating sap 22-23 Suction discs, regular mould for 88-89 Suction discs, simple mould for 87-88 Sulphides, alkaline as vul- canizers 100 Sulphur, absorption pro- cess 100 Sulphur bath for mixing and curing 98-100 Sulphur chloride process . 100-102 Sulphur, how mixed with gum 43 Sulphur, its escape from vulcanized rubber 33-34 Sunlight excluded from washed sheet rubber 38 Syringes made by Indians . . 11 Test for curing with knife. 48 Thread, rubber, cut 41 Thread, rubber moulded. . . 92 Tire construction 130-132 Tires, rubber 127 Tissues, coated, how made. 45-46 Tubes, connecting glass. ... 96 Tube, seamless 92 Turpentine, a solvent for vulcanized rubber 10Q Turpentine compared with caoutchoucin 30 Turpentine, viscid nature of solution 104-105 Type, india rubber 73 Type moulding flask 74 Type and stamps from vul- canized rubber 77 Type, cutting apart 75 Type, points in moulding. . 75 Type, quads, and spaces for stamp models 71-72 Type, steel moulds for 76 United States composition stamps 113-120 Varnish shellac for india rubber 158-159 Vulcanite 108-111 Vulcanization, its two steps. 42 Vulcanization, steps in pro- cess 47-48 Vulcanized rubber stamps and type 77 Vulcanizer 52-53 Vulcanizer, chamber 63 Vulcanizer, fish kettle as a . 69-70 Vulcanizer, flower pot. . . 68-70 Vulcanizing and moulding stamps 58-60 Washing and sheeting. . 37-38 Water absorbed by india rubber 31 Waterproof composition for shoes 163 Waterproofing for battery cells 148-149 Zinc chloride 57 CATALOGUE OF STANDARD PRACTICAL and SCIENTIFIC BOOKS PUBLISHED AND FOR SALE BY The Norman W.Henley Publishing Go. 132 Nassau St., New York, U. S. A. wm wm a INDEX OF SUBJECTS Brazing and Soldering- 3 Cams n Charts 3 Chemistry 4 Civil Engineering 4 Coke 4 Compressed Air 4 Concrete 5 Dictionaries 5 Dies— Metal Work 6 Drawing— Sketching Paper 6 Electricity 7 Enameling 9 Factory Management, etc 9 Fuel 10 Gas Engines and Gas 10 Gearing and Cams 11 Hydraulics 11 Ice and Refrigeration 11 Inventions— Patents 12 Lathe Practice 12 Liquid Air 12 Locomotive Engineering 12 Machine Shop Practice 14 Manual Training 17 Marine Engineering 17 Metal Work-Dies 6 Mining 17 Miscellaneous 18 Patents and Inventions 12 Pattern Making 18 Perfumery 18 Plumbing 19 Receipt Book 24 Refrigeration and Ice n Rubber 19 Saws 20 Screw Cutting 20 Sheet Metal Work 20 Soldering 3 Steam Engineering J20 Steam Heating and Ventilation 22 Steam Pipes 22 Steel 22 Watch Making 23 Wireless Telephones , 23 J:!f~" Any of these books will be sent prepaid to any part of the world, on receipt of price. REMIT by Draft, Postal Money Order, Express Money Order or by Registered Mail. GOOD, USEFUL BOOKS BRAZING AND SOLDERING BRAZING AND SOLDERING. By James F. Hobart. The only book that shows you just how to handle any job of brazing or soldering that comes along; tells you what mixture to use, how to make a furnace if you need one. Full of kiaks. 4th edition. 25 cents CHARTS BATTLESHIP CHART. An engraving which shows the 'details of a battleship as if the sides were of glass and you could see all the interior. The finest piece of work that has ever been done. So accurate that it is used at Annapolis for instruction purposes. Shows all details and gives correct name of every part. 28 x 42 inches — plate paper. 50 cents BOX CAR CHART. A chart showing the anatomy of a box car, having every part of the car numbered and its proper name given in a reference list. 20 cents GONDOLA CAR CHART. A chart showing the anatomy of a gondola car, having every part of the car numbered and its proper reference name given in a reference list. 20 cents P 4.SSEN GER CAR CHART. A chart showing the anatomy of a passenger car, having every part of the car numbered and its proper name given in a reference list. 20 cents TRACTIVE POWER CHART. A chart whereby you can find the tractive power or drawbar pull of any locomotive, without making a figure. Shows what cylinders are equal, how driving wheels and steam pressure affect the power. What sized engine you need to exert a given drawbar pull or anything you desire in this line. 50 cents WESTINGHOUSE AIR-BRAKE CHARTS. Chart I.— Shows (in colors) the most modern Westinghouse High Speed and Signal Equipment used on Passenger Engines, Passenger Engine Tenders, and Passenger Cars. Chart II. — Shows (in colors) the Standard Westinghouse Equipment for Freight and Switch Engines, Freight and Switch Engine Tenders, and Freight Cars. Price for the set, 50 cents CHEMISTRY HENLEY'S TWENTIETH CENTURY BOOK OP RECEIPTS, FORMULAS AND PROCESSES. Edited by Gardner D. Hiscox. The most valuable Techno-chemical Receipt Book published, including over 10,000 selected scientific chemical, technological, and practical receipts and processes. See page 34 for full description of this book. 83.00 CIVIL ENGINEERING HENLEY'S ENCYCLOPEDIA OF PRACTICAL EN- GINEERING AND ALLIED TRADES. Edited by Joseph G. Horner, A.M. I., M.E. This set of five volumes contains about 2,500 pages with thousands of illustrations, including dia- grammatic and sectional drawings with full explanatory details. It covers the entire practice of Civil and Mechanical Engineering. It tells you all you want to know about engineering and tells it so simply, so clearly, so concisely that one cannot help but understand. 86.00 per volume or 825.00 for complete set of five volumes. COKE COKE— MODERN COKING PRACTICE; INCLUDING THE ANALYSIS OF MATERIALS AND PRODUCTS. By T. H. Byrom, Fellow of the Institute of Chemistry, Fellow of The Chemical Society, etc., and J. E. Christopher, Member of the Society of Chemical Industry, etc. A handbook for those engaged in Coke manufacture and the recovery of By- products. _ Fully illustrated with folding plates. The subject of Coke Manufacture is of rapidly increasing in- terest and significance, embracing as it does the recovery of valuable by-products in which scientific control is of the first " importance. It has been the aim of the authors, in preparing