Encyclopedia Britannica; O R, A DICTIONARY O F ARTS, SCIENCES, AND MISCELLANEOUS LITERATURE; Conftrufted on a Plan, B Y W H I C H THE DIFFERENT SCIENCES AND ARTS Are digefted into the Form of Diftind T R E A T I S E S o R SYSTEMS, COMPREHENDING The History, Theor y, and P r a c t i c e, of each, according to the Lateft Difcoveries and Improvements; AND FULL EXPLANATIONS GIFEN OF 7HE VARIOUS DETACHED PARTS OF KNOWLEDGE, W H E T 1 1 E R R E L A T I N G T O Natural and Artificial Objeas, or to Matters Ecclesiastical, Civil, Military, Commercial, ^r. Including Elucidations of the moft important Topics relative to Religion, Morals, Manners, and the Oeconomy of Life : TOGETHER WITH A Description of all the Countries, Cities, principal Mountains, Seas, Rivers, 6c. throughout the World; A General History, Ancient and Modern^ of the different Empires, Kingdoms, and States;^ AND An Account of the Lives of the moil Eminent Perfons In every Nation, from the earliefl: ages down to the prefent times. Comtilei from ibf -icriiings of the hjl Authcrs, infe^'Ctal hrgvas^es ; tbf moji approved Diaionarus, as well of general faence as rf tts farti^ cular branches ; the -Lninlaaions, Journals, a„d Mem ir., 0/ learned SocittUj, both at home and abroad : (he MS. LeSures of Eminent Vrof-jfort on digti e-.t fciences ; and a l arktj of Original Materials, furnifced by an Ext<'nfive Correfpondence. THE THIRD EDITION, IN EIGHTEEN VOLUMES, GREATLY IMPROVED. ILLUSTRATED WITH FIVE HUNDRED AND FORTY-TWO COPPERPLATES. VOL. IV. INDOCTl DTSCANT, Er A M B NT M E M I N I S S B PERiri. EDINBURGH. PRINTED FOR A. BELL AND C. MACFARQU HAR» MDCCXCVIL during the fiege of that city, for five Ihekels. CABAL, an apt name currently given to the infa- mous miniftry of Charles II. compofed of five perfons, Clifford, Afiiley, Buckingham, Arlington, and L?.i«f derdale ; the firft letters of whofe names, in this or- der, furnilhed the appellation by which they were di- ftinguifhed. CABALIST, in Trench commerce, afa£lor or per- fon who is concerned in managing the trade of an- other. CABALLARIA, in middle-age writers, lands hel3 by the tenure of furnifhing a horfeman, with fuitable equipage, in time of war, or when the lord had occa- fion for him. CABALLEROS, or Cavalleros, are Spanifh wools, of which there is a pretty confiderable trade at Bayonne in France. CABALLINE, denotes fomething belonging to horfes ; thus caballine aloes is fo called, from its being chiefly ufed for purging horfes; and common brim- ftone is called fulphur caballinum for a like reafon. CABALLINUM (anc. geog), a town of the ^Edui in Gallia Celtica; now Challon fur Saone, which fee. CABALLINUS (anc. geog.), a very clear foun- tain of mount Helicon in Boeotia ; czVa^di Hippocrenchj the Greeks, becaufe opened by Pegafus on flriking the rock with his hoof, and hence called Pegafus. CABALLIO, or Cabf.llio (anc. geog.), a town, of the Cavares in GaUia Narbonnenfis, fituated on the Druentia. One of the Latin colonies, in the -Notitise called Civhas Cabellkorum. Now CavalUoti in Pro- vence.. CABBAGE, In botany. See Brassica; and A- GRicuLTURE, n° 40, and 169. In the Georgical eflaysj . we find this plant greatly recommended as an excellent food for cattle, producing much dung, and being an excellent fubllitute for hay. The author prefers the ■ Scotch kind, as being moft durable, and preferable oir all other accounts. He alfo recommends tiutumn-fowedf plants in preference to thofe fowed in the fpring; the former producing a much more weighty crop than the latter. The expence of raifing an acre of good cab-'' bages he values at 14/. 15 J. and its prodiace at 34/. CABBAGE-Tree, or True- CABSAGE-pALMi See A^ RECA.. Cabbage-bark Tree. SeeGfeoFFRiEA.. CABBALA, according to the Hebrew ftyle, has a very diftindl fignificatiori from that wherein we un- deriland it in our language. The Plebrew cabbala fige nifies tradition; and the Rabbins, who are called Ci7i^- b'aliftsi ft'udy principally the combination of particular words, letters, and numbers, and by this means pretencf to difcover what is to come, and to fee clearly into the fenfe of many difficult palTages of fcripture. There are no fure principles of this knowledge, but it depends upon fome particular traditions of the ancient-s ; for which reafon it is termed cahhala. The cabbalifts have abundance of names which they call facred i thefe they make ufe of in invoking of fpi- riti, and imagine they receive great light from them. They CAB C % ] CAB Cabbala They tell us, that the fecrets of the cabbala were dif- J1 covered to Mofes on mount Sinai; and that thefe have ^" ^' , been delivered to them down from father to fon, with- out interruption, and without any ufe of letters ; for to write them down, is what they are by no means permitted to do. This is likewife termed the oral laivy becaufe it paffed from father to fon, in order to dif- tinguifh it from the written laws. There is another cabbala, called artificial^ which confifts in fearching for abltrufe and mylterious ligni- fications of a word in Scripture, from whence they bor- row certain explanations, by combining the letters which compofe it : this cabbala is divided into three kinds, the gematrie, the notaricon, and the temura or themurah. The lirfl: whereof confilts in taking the letters of a Hebrew word for ciphers or arithmetical numbers, and explaining every word by the arithmeti- cal value of the letters whereof it is compofed. The fecond fort of cabbala, called notaricon, confilts in ta- king every particular letter of a word for an entire diftion; and the third, called themiira, i. e. change, confilts in making different tranfpofitions or changes of letters, placing one for the other, or one before the other. Among the Chriftians, likewife, a certain fort of magic is, by miftake, called cabbala ; which confifts in ufing improperly certain pafTages of Scripture for ma- gic operations, or in forming magic charadlers or fi- gm-es with itars and talifmans. Some vifionaries among the Jews believe, that Jefus Chrift wrought his miracles by virtue of the myfteries of the cabbala. CABBALISTS, the Jewilh dodors who profefs the ftiidy of the cabbala. In the opinion of thefe men, there is not a word, letter, or accent in the law, without fome myfteiy in it. The Jews are divided into two general fe£ls; the karaites, who refufe to receive either tradition or the talmud, or any thing but the pure text of fcripture ; and the rabbiniita, or talmudilts, who, befides this, re- ceive the traditions of the ancients, and follow the talmud. The latter are again divided into two other fedts ; pure rabbinilts, who explain the fcripture in its na- tural fenfe, by grarnmar, hiltory, and tradition ; and cabbalifts, who, to difcover hidden myftical fenfes, which they fuppofe God to have couched therein, make ufe of the cabbala, and the myftical methods above mentioned. CABECA, or Cabesse, a name given to the fineft filks in the Eliit Indies, as thofe from 15 to 20 per cent, inferior to them are called barina. The Indian workmen endeavour to pafs them off one with the o- ther ; for which reafon, the more experienced Euro- pean m.erchants take care to open the bales, and to examine all the flcaines one after another. The Dutch diftinguiih two forts of cabecas; namely, the moor ca- beca, and the common cabeca. The former is fold at Amfterdam for about 2 1 4- fchellinghen Flemilh, and the other for about Cjbfxa de Vide, a fmall fea-port town of Alentejo in Portugal, with good walls, and a ftrong caftle. W. Long. 6. 43. N. Lat. 39. o. CABENDA, a fea-port of Congo in Africa, fi- tuated in E. Long. 12. 2. S. Lat. 4» 5. CABES, or Gabes, a town of Africa, in the king- dom of Tunis, feated on a river near the gulf of the fame name. E. Long. 10. 55. N. Lat. 33. 4.0. CABEZZO, a province of the kingdom of Angola, in Africa; having Oacco on the north, Lubolo on the fouth, the Coanza on the north-eaft, and the Reinba on the fouth-weft. It is populous, and well ftored with cattle, &c. and hath a mine of iron on a moun- tain from thence called the iron mountain, which yields great quantities of that metal ; and this the Portuguefe have taught the natives to manufacture. This pro- vince is watered by a river called Rio Longo, and other fmall rivulets, lakes, &c. The trees here are vaftly large ; and they have one fort not unlike our apple-trees, the bark of which being flaftied with a knife, yields an odoriferous refin of the colour and confiftency of wax, and veiy medicinal in its nature, only a little too hot for Europeans, unlefs qualified by fome cooling drug. CABIDOS, or Cavidos, a long meafure ufed at Goa, and other places of the Eaft Indies belonging to the Portuguefe, to meafure ftuffs, linens, &c. and equal to 4ths of the Paris ell. CABIN, a room or apartment in a Ihip where any of the officers ufually refide. There are many of thefe in a large Ihip ; the principal of which is defigned for the captain or commander. In fliips of the line this chamber is furnifhed with an open gallery in the fhip's ftern, as alfo a little gallery on each quarter. The apartments where the inferior officers or common fail- ors fleep and mefs are ufually called Births ; which fee. The bed-places built up for the failors at the Ihip's fide in merchantmen are alfo called cabins. CABINDA, the chief port of the kingdom of Angoy in Loango in Africa. It is fituated at the mouth of a river of the fame name about five leagues north of Cape Palmerino, on the north fide of the mouth of the river Zaire. The bay is veiy commo- dious for trade, wooding, and watering. CABINET, the moft retired place in the fineft part of a building, fet apart for writing, ftudying, or preferving any thuig that is precious. A complete apartment confifts of a hall, anti-cham- ber, chamber, and cabinet, with a gallery on one fide. Hence we fay, a cabinet of paintings, curiofities, &c. Cabinet, alfo denotes apiece of joiner's workman- fhip, being a kind of prefs or cheft, with feveral doors and drawers. There are common cabinets of oak or of chefnut, varnifhed cabinets of China and Japan, cabinets of in- laid work, and fome of ebony, or the like fcarce and precious woods. Formerly the Dutch and German cabinets were much efteemed in France ; but are now quite out of date, as well as the cabinets of ebony which came from Venice. Cabinet is alfo ufed in fpeaking of the more feledt: and fecret councils of a prince or adminiftration. Thus we fay, the fecrets, the intrigues of the cabinet. To avoid the inconveniences of a niunerous council, the policy of Italy and pradlice of France firft introduced cabinet councils. King Charles I. is charged with firft eftabliftiing this ufage in Engbnd. Befides his privy council, that prince eredted a kind of cabinet council, or junto, under the denomination of a council of ftate ; compofed of archbiftiop Laud, the earl of A 2 Strafford, CAB [ Cabinet StrafFord, and lord Collington, with the fecretaries of {| ftate. Yet fome pretend to find the fubftance of a cabinet council of much greater antiquity, and even 7 * allowed by parliament, who anciently fettled a quo- TOin of perfons moft confided in, without whofe pre- fence no arduous matter was to be determined ; giving them power to aft without confulting the reil of the council. As long fince as the 28th of Henry III. a charter pafled in affirmance of the ancient rights of the kingdom j which provided, that four great men, cho- fen by common confent, who were to be confervators of the kingdom, amon^ other things, {liould fee to the difpofing of monies given by parliament, and appro- priated to particular ufes ; and parliaments were to be fummoned as they fhould advife. But even of thefe £our, any two made a quorum ; and generally the chief juftice of England, and chancellor, were of the num- ber of the confervators. Matth. Par. 28. Hen. III. In the firft of Henry VI. the parllam.ent provides, that the quorum for the privy council be fix, or four at leall; and that in all weighty confiderations, the dukes of Bedford and Glouceller, the king's uncles, fhould be prefent ; which feems to be erecting a cabinet by law. CABIRI, a term in the theology of the ancient Pagans, fignifying great and powerful gods ; being a Bame given to the gods of Samothracia. They were alfo worftiipped in other parts of Greece, as Lemnos and Thebes, where the cabiria were celebrated in ho- nour of them ; thefe gods are faid to be, in number, four, viz. Axieros, Axiocerfa, Axiocerfus, andCafmilus. CABIRIA, feftivals in honour of the Cabiri, cele- brated in Thebes and Lemnos, but efpecially in Samo- thracia, an ifland confecrated to the Cabiri. All who were initiated into the myfteries of thefe gods, were thought to be fecured thereby from ftorms at fea, and all other dangers. The ceremony of initiation was performed by placing the candidate, crowned with o- live branches, and girded about the loins with a purple ribband, on a kind of throne, about which the prieils, and perfons before initiated, danced. CABLE, a thick, large, ftrong rope, commonly of hemp, which ferves to keep a fliip at anchor. There is no merchant-fliip, however weak, but has at leaft three cables ; namely, the chief cable, or cable of the {heet-anchor, a common cable, and a fmaller one. Cable is alfo faid of ropes, which ferve to raife heavy loads, by the help of cranes, pullies, and other engines. The name of cable is ufually given to fuch as have, at leaft, three inches in circumference ; thofe that are lefs are only called ropes, of different names ac- cording to their ufe. Every cable, of whatfoevier thicknefs it be, is com- pofed of three ftrands ; every ftrand of three ropes ; and every rope of three twifts : the twift is made of more or lefs threads, according as the cable is to be thicker or thinner. In the manufacture of cables, after the ropes are made, they ufe fticks, which they pafs firft between the ropes of which they make the ftrands, and after- wards between the ftrands of which they make the icable, to the end that they may all twift the better, and be more regularly wound together ; and alfo, to prevent them from entwining or entangling, they hang, • at the end of each ftrand and of each rope, a weight of kad or of ftone. 4 ] CAB The number of threads each cable is corapofed of is Cable always proportioned to its length and thicknefs; and II it is by this number of threads that its weight and va- lue are afcertained: thus, a cable of three inches cir- cumference, or one inch diameter, ought to confift of 48 ordinary threads, and to weigh 192 pounds; and on this foundation is calculated the following table, very ufeful for all people engaged in marine commerce, who fit out merchantmen for their own account, or freight them for the account of others. ^ table of the number of threads and weight of cables of different circumferences. Circumf. Threads. 3 inches 48 192 pounds. 4 77 308 5 121 484 6 174 696 7 238 952 S 1244 9 393 1572 10 485 1940 X I 598 2392 12 699 2796 13 821 3284 H 952 3808 15 1093 4372 16 1244 4976 17 1404 5616 18 1574 6296 19 1754 7016 20 1943 7772 Sheet-Anchor Cable, is the greateft cable belonging to a fhip. Stream Cable, a hawfer or rope, fomething fmaller than the bowers, and ufed to moor the ftiip in a river, or haven, ftieltered from the wind and fea, &c. Serne or Plate the Cable, is to bind it about with ropes, clouts, &c. to keep it from galling in the hawfe. To fpFice a Cable, is to make two pieces faft toge- ther, by working the feveral threads of the rope the one into the other. Pay more Cable, is to let more out of the fliip. Pay cheap the Cable, is to to hand it out apace. Veer more Cable, is to let more out, &c. Cable's Length, a meafure of 120 fathoms, or of the ufual length of the cable. CABLED, in heraldry, a term applied to a crofs formed of the two ends of a fliip's cable ; fometimes alfo to a crofs covered over with rounds of rope; more properly called a crofs corded. Cabled Flute, in architefture, fuch flutes, as are fil- led up with pieces in the form of a* cable. CABO DE IsTRiA, the capital town of the province of Iftria, in the territory of Venice; and the fee of a biftiop. It is feated on a fmall ifland in the gulf of Venice, and is joined to the main land by draw-bridges. E. Long. 14. 22. N. Lat. 45:. 49. CABOCHED, in heraldry, is when the heads of beafts are borne without any part of the neck, full-faced. . CABOLETTO, in commerce, a coin of the repub- lic of Genoa, worth about 3 d. of our money. CABOT (Sebaftian), the firft difcoverer of the Goa- tinent of America, was the fon of John Cabot a Ve- netian. He was born at Brlftol in 1477; and was taught by his father arithmetic, geometr)^, and cofmo- Cabot, Ca!;'-a CAB [ grapliy. Before he was 20 years of age he made fe- veral voyages. The firft of any confequence feems to have been made with his father, who had a commiffion from Henry VII. for the difcovery of a north-weft paf- fage to India. They failed in the fpring of 1497 ; and proceeding to the north-weft they difcovered land, which for that reafon they called Pr'ima'vijla, or Nc-m- foundland. Another fmaller illand they called St John, from its being difcovered .on the feaft of St John Bap- tift ; after which, they failed along the coaft of Ame- rica as far as Cape Florida, and then returned to Eng- land with a good cargo, and three Indians aboard. Stowe and Speed afcribe thefe difcoveries wholly to Sebaftian, without mentioning his father. It is pro- bable that Sebaftian, after his father's death, made fe- ver?4 voyages to thefe parts, as a map of his difcove- ries, drawn by himfelf, was hung up in the privy gar- den at Whitehall. However, hiftory gives but Uttle account of his Hfe for near 20 years; when he went to Spain, where he was made pilot-major, and intrufted with reviewing all proje£ls for difcoveries, which were then very numerous. His great capacity and approved integrity induced many eminent merchants to treat with him about a voyage by the new found ftraits of Ma- gellan to the Moluccas. He therefore failed in 152-5, lirft to the Canaries ; then to the Cape Verd iflands ; thence to St Auguftine and the iflapd of Patos; when fome of his people beginning to be mutinous, and re- fufing to pafs through the ftraits, he laid afide the de- iign of faihng to the Moluccas ; left fome of the prin- cipal mutineers upon a defart ifland; and, failing up the rivers of Plate and Paraguay, difcovered, and buUt forts in, a large traft of fine countiy, that produced gold, filver, and other rich commodities. He thence dif- patched meffengers to Spain for a fupply of provifions, ammunition, goods for trade, and a recruit of men: but his requeft not being readily complied with, after ftay- ing five years in America, he x-eturned home; where he met with a cold reception, the merchants being dif- pleafed at his not having purfued his voyage to the Moluccas, while his treatment of the mutineers had given umbrage at court. Hence he returned to Eng- land; and being introduced to the Duke of Somerfet, then lord protestor, a new office was erefted for him : he was made governor of the myftery and company of the merchant-adventurers for the difcovery of regions, dominions, iflands, and places unknown; a peufion was granted him, by letters-patent, of 1 661. 13 s. 4d. per annum; and he was confulted in all aff"airs relative to trade. In 1522, by his intereft, the court fitted out fome fhips for the difcovery of the northern parts of the world. This produced the firft voyage the Englifti made to Ruffia, and the beginning of that commerce which has ever fince been carried on between the two aations. The Ruffia company was now founded by a charter grauted by Philip and Mary ; and of this com- pany Sebaftian was appointed governor for life. He is faid to be the firft who took notice of the variation of the needle, and who publiftied a map of the world. The exaft time of his death is not known, but he lived to be above 70 years of age. CABRA, a town of the kingdom of Tombut in Africa. It is a large town, but without walls ; and is feated on the river Niger, about 1 2 miles from Tom- but. The houfes are built in the ftiage of bells ; and 5 1 CAB the walls are made with ftakes or hurdles, plaftered Cabul, with clay, and covered with reeds after the manner of thatch. This place is very much frequented by negroes * who come here by water to trade. The town is very unhealthy, which is probably owing to its low fitua- tion. The colour of the inhabitants is black, and their religion a fort of Mahometanifm. They have plenty of corn, cattle, milk, and butter; but fait is veiy fcarce. The judge who decides controverfies is appointed by the king of Tombut. E. Long. o. 50. N. Lat. 14. 21. CABUL, or Gaboul, a city of Afia, and capital of the province of Cab uliftan. Itlies in E. Long. 68.15. N. Lat. 33. 30. on the frontiers of Great Bukharia, on the fouth fide of the mountains which divide the territories of the Mogul from that part of Great Tar- tary. It is one of the fineft places in that part of the world; large, rich, and very populous. As it is confi- dered as the key of the great Mogul's dominions on that fide, great care is taken to keep its fortifications, in repair, and a numerous garrifon is maintained for its fecurity. It lies on the road between Samarcand and Labor; and is much frequented by the Tartars, Per- fians, and Indians. The Ufbec Tartars drive there a great trade in flaves and horfes, of which it is faid that no fewer are fold than 60,000 annually. The Perfians bring black cattle and ftieep, which rendei's provifions very cheap. They have alfo wine, and plenty of all forts of eatables. The city ftands on a little river whick falls into the- Indus, and thereby affords a ftiort and fpeedy paflage for all the rich commodities in the country behind it, which, when brought to Cabul, are there exchanged for flaves and horfes, and then con- veyed by merchants of different countries to all parts of the world. The inhabitants are moft of them Indian pagans, though the officers of the Mogul and moft of the garrifon are Mahometans.. CABULISTAN, a province of Afia, formerly be- longing to the Great Mogul; but ceded in 1739 to> Kouli Khan, who at that time governed Perfia. It is-. bounded on the north by Bukharia, on the eaft by Cafch- mire, on the weft by Zabuliftan and Candaliar, and on the fouth by Multan. It is 250 miles in length, 240 in breadth, and its chief town is Cabul. This country in general is not very fruitful ; but in the vales they have good pafture-lands. The roads are much infefted with banditti; which obliges the natives to have guards for the fecurity of travellers. The religion of the Ca-- buliftans is pagan ; and their extraordinaiy time of de- votion is the full moon in February, and continues for two days. At this time they are clothed in red, make their off'erings, dance to the found of the trumpet, and- makevifits to their friends in mafquerade dreffes. They fay, their god Crufman killed a giant who was his e- nemy, and that he appeared like a little child ; in me- mory of which, they caufe a child to ftioot at the figure of a giant. Thofe of the fame tribe make bonfires, andl feaft together ia a jovial manner. The moral part of their religion confifts in charity ; for which reafon, they dig wells and build houfes for the accommodation of travellers. They have plenty of provifions, mines of iron», myrobolans, aromatic woods, and drugs of many kinds. They carry on a great trade with the neighbouring ; countries; by which means they are very rich, and are fupphed with plenty of all things. CABURNS, ■'C<^l>urns, ' Cacalia. C A C I CABURNS, on (hip-board, are Tmall lines made of fpun yarn, to bind cables, feize tackles, or the like. CACALIA, in botany ; a genus of the polygamia "aequalia order, belonging to the fyngenelia clafs of •plants. The receptacle is naked ; the pappus hairy ; the calyx- cylindrical, oblong, and caliculated, or having a fmall calyx of vei-y fliort fcaies only at the bafe. Species. I. The fuaveolens, with a herbaceous italk, is a native of North America. It hath a perennial creep- ■ing root which fends out many ftalks, garni(hed with triangular fpear-fhaped leaves fliarply fawed on their •edges, of a pale green on their under fide, but a deep fhining green above, placed alternately. The ftalks rife ■to the height of feven or eight feet, and are terminated by umbels of white 'flowers, which are fucceeded by ob- long feeds covered with down. It flowers in Auguft, and the feeds ripen in Oftober. The ftalks decay in autumn, and new one rifts in the fpring. This plant 'multiplies greatly by its fpreading roots, as alfo by the feeds, which are fpread to a great dittance by the wind, the down which adheres to them being greatly afiifting to their conveyance. Tlie roots which have been caft out of Chelfea garden, being carried by the tide to a great diftance, have fixed themfelves to the banks of the river, and increafed fo much, that in a few years this fpecies may probably appear as a native of Eng- land. 2. The ficoides is a native of the Cape of Good Hope. It rifes with ftrong round ftalks to the height of feven or eight feet, woody at bottom, but foft and fucculent tipward, fending out many irregular branches, garpiflied more than half their length with thick, taper, fucculent leaves, a little comprefled on two fides, end- ing in points, covered with a whitiflr glaucous farina, which comes ofi^ when handled. Thefe, when broken, emit a ftrong odour of turpentine, and are full of a vif- cous juice ; at the extremity of the branches the flowers are produced in fmall umbels ; they are white, tubu- lous, and cut into five parts at the top. The leaves of this plant are pickled by the French, who efteem them much ; and in doing this they have a method of pre- fervmg the white farina upon them, which adds great- ly to the beauty of the pickle when brought to table. ■3. The kleinia, with a compound flirubby ftalk, grows naturally in the Canary illands, but has long been cult i- vated in the Englifh gardens. It rifes with a thick fleftiy ftem divided at certain diftances, as it were, into fo many joints. Each of thefe divifions fwell much larger in the middle than they do at each end ; and the ftalks divide into many irregular branches of the fame ■form, which, toward their extremities, are garnifhed with long, narrow, fpear-fhaped leaves of a glaucous co- lour, ftanding all round the ftalks without order. As they fall off, they leave a fear at the place, which al- ■ways remains on the branches. The flowers are pro- -duced in large clufters at the extremity of the branch- es, which are tubulous, and of a faint carnation colour. They appear in Auguft and September, but continue -great part of Otlober, and are not fucceeded by feeds in this country. There have been ftones and foffils dug up at a very great depth in fome parts of England iiaving very perfeift imprelhons-of this plant iipon them ; from whence Dr Woodward has fuppoftd tjie plants were lodged there at the univerfai -doluge ; and finding the imprelfions of many other plants and ariimals which are natives of thofe iflands, he concludes that the wa- ter flowed hkher from the fouth-welU This plant has C A C been called the cabha^e-tree, from the refemblance whicli the ftalk of it has to the cabbage: others have intitled it carnatiort'treef from the fliape of the leaves and the colour of the flowers. Befides thefe, there are feven other fpecies, viz. the alpina, with kidney-fliaped leaves ; the glabra, with fmooth leaves ; the atriplici- folia, with heart-ftiaped finuated leaves ;. the papillaris, with a flirubby ftalk guarded on every fide with broken rough footftalks ; the ante-euphorbium,with oblong oval leaves ; the fonchifolia, with lyre-fliaped indented leaves'; and the lutea, with leaves divided into five acute parts. Culture. The three fpecies defcribed above are very eafily propagated. The firft will propagate itfelf, as already mentioned, either by roots or feeds. The fe- cond is eafily propagated by cuttings during the fum- mer months: Thefe ftiould be cut from the plants and laid to dry a fortnight, that the wound may be healed over before they are planted. Moft people plunge the pots in which thefe are planted into an hot-bed, to pro- mote their putting out roots ; but if planted in June or July, they will root as well in tlie open air. Even branches broken off" by accident have frequently put out roots when fallen on the ground, without any care. Thefe branches may be kept fix months out of the ground, -and will take root if planted. This fliould have a light fandy earth, and in winter be placed in an airy glafs-cafe, where they may enjoy the fun and air in mild weather, but muft be protected from freft. Du- ring the winter feafon the plants muft have but little water j and in fummer, when they are pilaced in the open air, it fliould not be given to them too often, nor in great quantity. The third is alfo propagated by cuttings, and the plants require the fame culture ; but muft have a dry warm glafs-cafe in winter, and very- little water, being fubje£l to rot with wet. In fummer they muft be placed in the open airin a warm flieltered fituation, and in very dry weather refreflied moderately with water. With this management the plants will flower annually, and grow to the height of eight or ten feet. CACAO. See Theobroma. Cy\CCOONS. See Flf.villea. CACERES, a town of iTpain, in the province of Eftremadura, is feated on the river Saler, and noted for the exceeding fine wool which the flieep bear in the neighbourhood. Between this town and Brocos, there is a wood, where tlie allies defeated the rear-guard of the duke of Berwick, on the 7th of April 1706. E. Long. 6. 47. 1^. Lat. 59. 15. CACHALOT, in "iclithyology. See Physeter. CACHAN, or Cash AN, a confiderable town of Perfia in Irac Agemi, where they carry on an exten- -five trade in filks, filver, and gold brocades, and fine earthen ware. It is fituated in a vail plain, 55 miles from Ifaphan, E. Long. 50. i. N. Lat. 34. 10. CACHAO, a province of the kingdom ofTonquin in Afia, fitnated in the heart of the kingdom, and fur- rounded by the other feven. Its foil is fertile, and in fome places mountainous, abounding with variety of trees, and particularly that of varnifh. Moft of thefe ■provinces carry on fome branch of the filk mannfafture, but this moft of all. It takes its name from the capi- tal, which is alfo the metropolis of the whole kingdont» though in other refpeils hardly comparable to a Chi- nefe one of the third rank. Cachao, a city of the province of that name, in the kingdom of Tonquiu in Afia, fituated in E. Long. Cacalfa Cacha;». GAG [ Cachao. lo^^ 3i« N. Lat. 22. I o. at about 80 leagues diflance V ' from the fea. It is prodigioufly crowded with people, irtfomuch that the ftreets are hardly paffable, efpecially on market days. Thefe vaft crowds, however, come moftly from the neighbouring villages ; upon which account thefe villages have been allowed their halls in particular parts of the city, where they bring and dif- pofe of their wares. The town itfelf, though the me- tropolis of the whole Tonquinefe kingdom, hath nei- ther walls nor fortifications. The principal ftreets are wide and airy, but the reft of them narrow and ill- paved ; and except the palace royal and arfenal, the to\vn hath little elfe v.'orth notice. The houfes are low and mean, moftly built of wood and clay, and not above one ftoiy high. The m.agazines and vvarehoufes belonging to foreigner's are the only edifices built of brick ; and which, though plain, yet, by reafon of their height and more elegant ftruAure, make a confiderable (how among thofe rows of wooden huts. From the combui- tibility of its edifices, this city fuffers frequent and dreadful conflagrations. Thefe fpread with fuch fur- prifing velocity, that feme thoufands of houfes are of- ten laid in aflies before the fire can be extinguiihed. To prevent thefe fad confequences, every houfe hath, either in its yard or even in its centre, fome lovi' build- ing of brick, in form of an oven, into which the inha- bitants on tlie firft alarm convey their moft valuable goods. Befides this precaution, which every family takes to fecure their goods, the government obliges them to keep a ciftern, or fome other capacious veffel, always full of water on the top of their houfe, to be ready on all occafions of this nature ; as likewife a long pole and bucket, to throw water from the kennel upon the houfes. If thefe two expedients fail of fuppreffing the flames, they immediately cut the ftraps which faf- ten the thatch to the walls, and let it fall in and wafte itfelf on the ground. The king's palace ftands in the centre of the city ; and is furrounded with a ftout wall, within whofe cin&ure are feen a great number of apart- ments two ftories high, whofe fronts and portals have fomething of the grand tafte. Thofe of the king and his wives are embellilhed with variety of carvings and gildings after the Indian manner, and all finely var- nifhed. In the outer court are a vaft number of fump- tuous ftables for the king's horfes and elephants. The appearance of the inner courts can only be conjeftured ; for the avenues are not only fliut to all ttrangers, but even to the king's fubjedts, except thofe of the privy council, and the chief minifters of ftate : yet we are told, that there are ftair-cafes by which people may mount up to the top of the walls, which are about 18 or 20 feet high ; from whence they may have a dif- tant view of the royal apartments, and of the fine par- terres and fiih-ponds that are between the cin£ture and them. The front wall hath a large gate well orna- mented, which is never opened but when the king goes in and out j but. at fome diftance.from it on each fide there are two potterns, at which the courtiers and fer- vants may go in and out. This cinfture,. which is of a vaft circumference, is faced with brick within and: without, and the whole ftruAure is terminated by wide fpacious gardens ; which, though ftored with great va- riety of proper ornaments, are deftitute of the gran- deur and elegance obferved in the palaces of European princes. Befides this palace, the ruins of one ftill more magnificent are to be obferved, and are called X/iJ«/wa, 6 Cachrys. 7 ] C A C The circumference is fald to have been betwixt fix and Cachao feven miles : fome arches, porticoes, and other orna- ments, are ftill remaining ; from which, and fome of ; its courts paved with marble, it may be concluded to have been as magnificent a ftrufture as any of the eaft- ern parts can ftiow. The arfenal is likewife a large and noble building, well ftored with ammunition and artillery. The Engllfli fattory is fituated on the north fide of the city, fronting the river Song-koy. It is a handfome low-built houfe, with a fpacious dining-room in the centre ; and on each fide are the apartments of the merchants, faftors, and fervants. At each end of the building are fmaller houfes for other ules, as ftore- houfes, kitchen, &c. which form two wings with the fquare in the middle, and parallel with the river, near the bank of which ftands a long flag-ftaff', on which • they commonly difplay the Englifli colours on Sun- - days and all remarkable days. Adjoining to it, on the fouth fide, is the Danlfli factory, which is neither fo- large nor fo handfome. On the fame fide of the river runs a long dike, whofe timber and ftones are fo firmly faftened together, that no paijt of it can be ftirred wltli- out moving the whole. This work was ralfed on thofe banks to prevent the river, during the time of their vaft rains, from overflowing the city ; and it has hi- therto anfwered its end ; for though the town ftands high enough to be in no. danger from land-floods, it might yet have been otherwife frequently damaged, if' not totally laid under water, by the overflowing of that' river. Some curious obfervations have been commu-' nicated to the royal foclety concerning differences be-- tween the tides of thofe feas and thofe of Europe, viz. that on the Tonquinefe coaft ebbs and flows but once' in 24 hours ; that is, that the tide is rifing during the fpace of 12 hours, and can be eafily perceived during' two of the moon's quarters, but can hardly be obfer- ved during the other two. In the fpring tides, which laft 14 days, the waters begin to rife at the rifing of- the moon ; whereas in the low tides, ■ which continue the fame number of days, the tide begins not till that- planet is got below the horizon. Whilft it is pafling through the fix northern figns, the tides are obferved ' to vary greatly, to rife foraetlmes very high, and fome- tlmes to be veiy low ; but when it Is once got Into the fouthern part of the zodiac, they are then found to be more even and regular. CACHECTIC, fomething partaking of the nature- of, or belonging to, a cachexy. CACHEO, a town of Negroland in Africa, feated on. the river St Domingo. It is fubjeft to the Portu- guefe, who have tjiree forts there, and carry on a great trade in . wax and flaves. W. Long. 14. 55. N. Lat. 12. o. CACHEXY, in medicine, a vicious ftate of the- humours and whole habit. See (the Index fubjolned. to) Medicine. CACHRYS, in botany^: A genus of the digynia order belonging to the pentandria clafs of plants ; and in the natural method ranking under the 45th order,. , Umbellata. The fruit is fubovate, . angled, - and cork-' or fpongy rinded. There are five fpecies, viz^ the trifida, with bipinna-^ ted leaves; the ficula, with double winged leaves ; the. libanotis, with fmooth furrowed feeds ; the linearia, , wath plain channelled fi-uit ; and the hungarica, with a plain, fungous, channelled feed. All thefe are per- enaial* GAG- [8 Caclrunde ennial plants, rifing pretty high, and bearing large um- J' bels of yellow flowers, and may be propagated by feeds ^ which ought to be fown foon after they are ripe ; for * if they are kept out of the ground till the next fpring, they often mifcarry. They mull alfo be fown in a (hady border where they are to remain : for the plants, having long top-roots, will not bear tranfplanting fo well as many others. The Hungarians in the neigh- bourhood of Erlaw, and thofe 'i\^io border on Tran- fylvania, Servia, &c. eat the root of the fifth fpecies in a fcarcity of corn for want of other bread. CACHUNDE, the name of a medicine, highly ce- lebrated among the Chinefe and Indians, and made of feveral aromatic ingredients, the perfumes, medicinal earth, and .precious Hones: they make the whole into a ftiff pafte, and form out of it feveral figures accord- ing to their fancy, which ai-e dried for ufe : thefe are principally tifed in the Eall Indies, but are fometimes brought over to Portugal. • In China, the principal perfons ufually carry a fmall piece in their mouths, which is a <:ontinued cordial, and gives their breath a very fweet fmell. It is a highly valuable medicine alfo, in all nervous complaints ; and is elteemed a prolonger to Ufe, and a provocative to venery, the two great intentions of moil of the medicines in ufe in the Eall. CACOCHYLIA, or CAcbcwyMiA, a vicious ftate of the vital humours, efpecially of the mafs of blood ; arifing either from a diforder of the fecretions or exe- ■cretions, or from external contagion. The word is Greek, compounded of y-xx.®- HI, and ■/C'^'^ juice. CACOPHONIA, in grammar and rhetoric, the meeting of two letters, or fyllables, which yield an un- couth and difagreeable found. The word is compound- ed of y-a-y-og evil, and voice. Ca COP HON I A, in Medicine, denotes a vice or de- privation of the voice or fpeech ; of which there are two fpecies, aphonia and dyfphonia. CACTUS, in botany: A genus of the monagy-nia order, belonging to the icofandria clafs of plants ; and in the natural method ranking under the 13th or- der, SucculenU. The calyx is monophyllous ; fupe- rior, or above the receptacle of the fruit imbricated ; the corolla polypetalous ; the fruit an unilocular, poly- fpermous berry\ To this genus Linnaeus has added the cereus and opuntia. There are 24 fpecies, all na- tives of the Well Indies and Mexico. The ca£li are plants of a Angular ftm£lure, but e- fpecially the larger kinds of them ; which appear Hke a large, flefliy, green melon, with deep ribs, fet all over with ilrong Iharp thorns ; and, when the plants are cut through the middle, their infide is a foft, pale- green, flelhy fubftance, very full of moillure. The fruit of all the fpecies is frequently eaten by the inha- bitants of the Weft Indies. The fruits are about three quarters of an inch in length, of a taper form, drawing to a point at the bottom toward the plant, but blunt at the top where the empalement of the flower was fitua- ted. The tafte is agreeably acid, which in a hot coun- try mufl render the fruit more grateful. The cochineal animals are fupported on a fpecies called caSus cothenillifer. — The flower of the cadlus grandiflora (one of the creeping cereufes) is faid to be as grand and beautiful as any in the vegetable fyllem : It begins to open in the evening about feven o'clock, is in perfedlion about eleven, and fades about four in Ko. 61. ] CAD the morning; lb that the fame flower only continues in perfe£lion about fix hours. The calyx when ex- panded is about a foot in diameter, of a fplendid yel- low within, and a dark brown without ; the petals ar^ many, and of a pure white ; and the great number of, recurved llamina, furrounding the ftyle in the centre of the flower, make a grand appearance, to which may be added the fine fcent, which perfumes the air to a confiderable diilance. It flowers in July. CACUS, in fabulous hiftory, an Italian (hepherd upon ihount Aventine. As Hercules was driving home the herd of king Geryon whom he had flain, Cacus robbed him of fome of his oxen, which he drew backward into his den lefl; they fliould be difcovered, Hercules at lall finding them out by their lowing, or the robbery being difcovered to him, killed Cacus with his club. He was Vulcan's fon, of prodigious bulk, and half man half fatyr. CAD AN, a town of Bohemia, in the circle of Zats, feated on the northern bank of the river Egra, in E. Long. 13. 34. N. Lat. 50. 20. CADARI, or Kadari, a feci of Mahometans, who aflert free-will ; attribute the adlions of men to men alone, not to any fecret power determining the will \ and deny all abfolute decrees, and predeltination. The author of this fc£l was Mabed ben Kaled Al Gihoni, who fulfered martyrdom for it. The woi-d comes from the Arabic, -np, cadara, poiver. Ben Aun calls the Ca- darians the Magi, or Manichees of the ]Mulfi.dmen. CADE, a cag, caflc, or barrel. A cade of her- rings is a veflel containing the quantity of 500 red her- rings, or 1000 fprats. CADE-Lamb, a young lamb weaned, and brought up by hand, in a houfe ; called in the North, pet-lamb. Cjdp.-O//, in the Materia Medica, a nanie given to an oil much in ufe in fome parts of France and Ger- many. The phyficians call it oleum cada, or oleum de cada. This is fuppofed by fome to be the piflelasum of the ancients, but improperly ; it is made of the fruit of the oxycedrus, which is called by the people of thefe places cada. CADE-Worm in zoology, the maggot or worm of a fly called phryganea. it is ufed as u bait in angling. See Phryganka. CADEA, or The league of the house of God, is one of thofe that compofe the republic of the Gri- fons, and the moll powerful and extenfive of them all. It contains the bilhopric of Coire, the great valley of Engadine, and that of Bragail or Pregal. Of the 1 1 great, or 2 1 fmall communities, thei-e are but two that fpeak the German language ; that of the rell is called the Rheiic, and is a dialedt of the Italian. The Pro- teflant religion is moil prevalent in this league, which has been allied to the Swifs cantons ever iince the year 1498. Coire is the capital town. CADENAC, a town of F ranee in Qiierci, on the confines of Rouergue, feated on the river Lot, in E. Long. 2. 12. N. Lat. 44. 36. CADENCE, or Repose, in mufic, (from the La- tin cadere to fall or defcend) ; the termination of an harmonicial phrafe on a repoie, or on a perfedl chord. See Music, art. 73 — 76, and 132 — 137. Cadence, in reading, is a falling of the voice below the key-note at the dole of every period. In reading, whether profe or verfe, a certain tone isalTumed which is called the keynote and in this tone the bulk of the J words Cacus II Cadence CAD . [ words are foundetl ; but this note is generally lowered towards the clofe of every fentence. Cadence, in the manege, an equal meafure or pro- portion, obferved by a horfe in all his motions ; fo that his times have an equal regard to one another, the one does not embrace or take in more ground than the other, and the horfe obferves his ground regu- larly. CADENE, one of the forts of carpets which the Europeans import from the Levant. They are the worfl fort of all, and are fold by the piece from one to two piaftres per carpet. CADENET, a town of France in Provence, and in the Viguirie of Apt. E. Long. 5. 30. N. Lat. 43. 40. CADES, or Kadesh, (anc. geog.) a town in the Wildernefs of Zin, in Arabia Petraea ; the firft en- campment of the Ifraelites, after their departure from Eziongeber ; and from which the Wildernefs of Zin was called Cades ; the burial-place of Miriam, with the rock and water of Meribah in it. Another Cades^ a town of the tribe of Judah, Jofliua xv. 23. Cade/- barnea, called alfo Cades. CADESBARNEA, (anc. geog.) a town of the Wildernefs of Paran, on the confines of Canaan, from which the fpics were fent out ; fometiines fimply called Cadesy but diftinA from the Cades in the Wildernefs of Zin. CADET, the younger fon of a family, is a term naturalized in our language from the French. At Pa- ris, among the citizens, the cadets have an equal patri- mony with the reft. At Caux, in Normandy, the cuftom, as with us, is to leave all to the eldeft, except a fmall portion to the cadets. In Spain, it is ufual for one of the cadets in great families to take the mother's name. Cadet is alfo a military term denoting a young gen- tleman who choofes to carry arms in a marching regi- ment as a private man. His views are, to acquire fome knowledge in the art of war, and to obtain a com- miffion in the army. Cadet differs from volunteer, as the former takes pay, whereas the latter ferves without pay. CADI, or Cadhi, a judge of the civil affairs in the Turkifh empire. It is generally taken for the judge of a town ; judges of provinces being diftinguifhed by the appellation of mollas. We find numerous complaints of the avarice, inl- <[iiity, and extortion, of the Turkifh cadis ; all juftice is here venal ; the people bribe the cadis, the cadis bribe the moulas, the moulas the cadilefchers, and the cadi- lefchers the mufti. Each cadi has his ferjeants, who are to fummon perfons to appear and anfwer complaints. If the party fummoned fails to appear at the hour ap- pointed, fentence is paffed in favour of his adverfary. It is ufually vain to appeal from the fentences of the cadi, fince the affair is never heard anew, but judg- ment is paffed on the cafe as ftated by the cadi. But the cadis are often cafhiered and punifhed for crying in- juftice with the baftinado and mulfts; the law, howr ever, does not allow them to be put to death. Con- ilantinople has had cadis ever fmce the year 1 390, when Bajazet I. obliged John Paleologus, emperor of the Greeks, to receive cadis into the city to judge all con- troverfies happening between the Greeks and the Turks fettled there. In fome countries of Africa, the cadis Vol. IV. Part I. 9 ] . CAD are alfo judges of religious matters. Among the Mdor^, cadis is the denomination of their higlier order of priefts or doAors, anfwering to the rabbins among the Jews. CADIACI, the TurkiHi name of Chalcedon. See Chalcedon. C ADILESCHE R, a capital officer of juftice among- the Turks, anfwering to a chief juftice among us. It is faid, that this authority was originally confined to the foldiery ; but that, at prefent, it extends itfelf to the determination of all kinds of law-fuits ; yet \% neverthelefs fubjeft to appeals. There are but three cadilefchers in all the grand fig- nior's territories : the firft is that of Europe ; the fe- cond, of Natolia ; and the third refides at Grand Cairo. This laft is the moft confiderable : they have their feats in the divan next to the grand vizir. * CADILLAC, a town of France in Guienne, and in Bazadois, near the river Garonne, witla a handfome caftle, fituated in W. Long. o. 15. N. Lat. 44. 37. CADIZ, a city and port-tovirn of Andalufia in Spain, fituated on the ifland of Leon, oppofite to Port St Mary on the continent, about 60 miles fouth-weft of Seville, and 40 north-weft of Gibraltar. W. Long. 6. 40. N. Lat. 36. 30. It occupies the whole furface of the weftern extre- mity of the ifland, which is compofed of two large circular parts, joined together by a very narrow bank of fand, forming altogether the figure of a chain-fhot. At the fouth-eaft end, the ancient bridge of Sua90, th rown over a deep channel or river, affords a commu- nication between the ifland and the continent; a ftrong line of works defends the city from all approaches along the ifthmus ; and, to render them ftill more difficult, all the gardens and little villas on the beach were in 1762 cleared away, and a dreary fandy glacis left in their room, fo that now there is fcarce a tree on the whole ifland. Except the Calk Ancha^ all the ftreets are narrow, ill-paved, and infufferably ftinking. They are all drawn in ftraight lines, and moft of them interfed each other at right angles. The fwarms of rats that in the nights run about the ftreets are innumerable ; whole droves of them pafs and repafs continually, and thcfe their midnight revels are extremely troublefome to fuch as walk late. The houfes are lofty, with each a veftibule, v^hich being left open till night, ferve paffen- gers to retire to; this cuftom, which prevails through- out Spain, renders thefe places exceedingly offenfive. In the middle of the houfe is a court like a deep well, under which is generally a ciftern, the breeding-place of gnats and mofquitos ; the ground-floors are ware- houfes, the firft ftories compting-houfe or kitchen, and the principal apartment up two pair of ftairs. The roofs are flat, covered with an impenetrable cement, and few are without a mirador or turret for the pur- pofe of commanding a view of the fea. Round the parapet-w»ll at top are placed rows of fquare pillars, meant either for ornament according to fome tradi- tional mode of decoration, or to fix awnings to, that fuch as fit there for the benefit of the fea-breeze may be fheltered fj "om the rays of the fun ; but the molt common ufe made of them, is to faften ropes for dry- ing linen upon. High above all thefe pinnacles, which give Cadiz a moft fingular appearance, ftands ■B the 0 CAD [ 10 ] CAD •CaJiz. tlic tower of fignals. Here flags are Kung out on the — v — "' £rft fight of a fall, marking the fize of the fliip, the nation it belongs to, and, if a Spanifh Indiaman, the port of the Indies it conies from. The fhips are ac- quainted with the proper fignals to be made, and thefe are repeated by the watchmen of the tower : as painted lifts are in every honfc, perfons concerned in commerce foon learn the marks. The city is divided into twenty-four quarters, under the infpeclion of as many commiihoners of police; and its population is reckoned at one hundred and foily thoufand inhabitants, of which twelve thoufand are French, and at leafl as many more Itahans. The fquare of Saint Antonio is large, and tolerably hand- fome, and there are a few fmaller openings of no great note. The pubHc walk, or Alameda, isplcafant in the evening : it is fenced off the coach-road by a marble rail. The fea-air prevents the trees from thri- ving, and destroys all hopes of future fhade. From the Alameda, continuing your walk weft- wards, you come to the Campofanto, a large efplanade, the only airing-place for coaches ; it turns round moft part of the well and fouth fides of the ifland, but the buildings are ftraggling and ugly ; the only edifice of any fhow is the new orphan-houfe ; oppofite to it is the fortrefs of St Sebaftian, built on a neck of land running out into the fea. The round tower at the extremity is fuppofed to have faved the city, in the great earthquake of 1755, from being fwept away by the fury of the waves. The building proved fufBcient- ly folid to withftand the fhock, and break the immenfe volume of water that threatened deftrudtion to the whole ifland. In the narrow part of the ifthmus the furge beat over with amazing impetuofity, and bore down all before it ; among the reft, the grandfon of the famous tragic-poet Racine, who ftrove in vain to efcape, by urging his horfe to the utmofl of his fpeed. On St Sebattian's feaft, a kind of wake or fair is held in the fort ; an aftonifhing number of people then palling and repafTmg, on a ftring of wooden bridges laid from rock to rock, makes a very lively moving pifture. From hence to the wooden circus where they exhi- bit the buU-feafls, you keep turning to the left clofe above the fea, which on all this fide dafhes over large ledges of rock ; the fhore feems here abfolutely inac- ceflible. On this fhore ftands the cathedral, a work of great expcnce, but carried on with fo little vigour, that it is difficult to guefs at the term of years it will require to bring it to perfeftion. The vaults are exe- cuted with great folidity. The arches, that fpring from the cluftered pilafters to fupport the roof of the church, are very bold ; the minute fculpture beflowed upon them feems fuperfluons, as all the efFeft will be lofl from their great height, and from the fhade that will be thrown upon them by the filling up of the in- terftices. From the fea, the prefent top of the church refembles the carcafe of fome huge monfter caft upon its fide, rearing its gigantic blanched ribs high above the buildings of the city. The outward cafings are to be of white marble, the bars of the windows of bronze. Next, croffing before the land-gate and barracks, a fuperb edifice for ftrength, convenience, and cleanli- nefs, you come down to the ramparts that defend the city on the fide of the bay. If the profped to the ocean is folemn, that towards the main land is ant- mated in the highefl degree ; the men of war ride in the eaflern bofom of the bay ; lower down the mer- chantmen are fpread far and near ; and clofe to the town an incredible number of barks, of various fhapes and fizcs, cover the furface of the water, fome moored andfbme in motion, carrying goods to and fro. The oppofite fhore of Spain is ftudded with white houfes, and enlivened by the towns of St Mary 's, Port-real, and others, behind which, eaflward, on a ridge of hills, ftands Medina Sidonia, and further back life the moun- tains of Granada. Weftv.ard, Rota doles the hori- zon, near which was anciently the ifland and city of Tarteffus, now covered by the fea, but at low-water fom-; part of the ruins are ftill to be difcerned. la a large baition, jutting out into the bay^ they have built the cuftom-houfe, the fint ftory of which is level with the walk upon the walls. When it was re- folved to ere£t a building fo neceffary to this great em- porium of trade, the marquis di Squillace gave orders that no expence fhould be- fpared, and the moft intelli- gent architefts employed, in order to erett a monument, which by its tafle and magnificence might excite the admiration of pofterity : tiie refult of thefe precautions proved a piey owns him- felf ignorant of the dimenfions to which they grow. The largeft remaining are not above two inches in thicknefs, and eight or nine feet in height. The branches are flender and full of fmall prickles ; the leaves- are pinnated ; the lobes growing oppofite to one ano- ther, bro^d at their ends, with one notch. The flowers are white, papilionaceous, with many ftamina and yel- low apices, growing in a pyramidal fpike, at the end of a long flender ftalk : the pods inclofe feveral fmall round feeds. The colour produced from this wood is greatly improved by folution of tin in aqua regia*. The fe- , cond fort is a native of the fame countries witli the firft, making but is of a larger fize. It fends out many weak irregu- and Dyeing^ lar branches, armed with fliort, ftrong, upright thorns. The leaves branch out in the fame manner as the firft ; but the lobes, or fmall leaves, are oval and entire. The flowers are produced in long fpikes like thofe of the former, but are variegated with red. Thefe plants may be propagated from feeds, which fliould be fov/n in fmaU pots filled with light rich earth early in the fpring, and plunged in a bed of tanner's bark. Being tender, they require to be always kept in the ftove, and to be treated in the fame manner as other exotics of that kind. C^SALPINUS of Arezzo, profeflbr at Pifa, and afterwards phyfician to pope Clement VIII. one of the capital writers in botany. See Botany, p. 419, 420. C-^SAR (Julius), the illuftrious Roman general and hiftorian, was of the family of the Julii, who pre- tended they were defcended from Venus by .^neas. The defcendants of Afcanius fon of iEneas and Creufa, and furnamed 'Julius, lived at Alba till that city was ruined by Tullus Hoftilius king of Rome, who carried them to Rome, where they flourifhed. We do not find that they produced more than two branches. The firit bore the name of Tullus, the other that of defar. The moft ancient of the Caefars were thofe who were in pu- blic employments in the nth year of the firft Punic war. After that time we find there was always fomc of that family who enjoyed public offices in the com- monwealth, till the time of Caius Julius Casfar, the fub- ]tdc of this article. He was born at Rome the 1 2th of the month Quintilis, year of the city 653, and loft his father an. 669. By his valour and eloquence he foon acquired the highett reputation in the field and in the ' fenate. Beloved and refpefted by his fellow-citizens, he enjoyed fucceffively every magifterial and military honour the republic could beftow cDnfulent with its" own free conftitution^ But at length having fubdued Pompey the great rival of his growing pov/er, his boundlefs ambition effaced the glory of his former ac- • tions : for, purfuing his favourite maxim, " that he had rather be the firft man- in a village than the fecond in Rome," he piocured himfelf to be chofen perpetual dictator ; and, not content with this unconftitutional power, his faction had refolved to raife him to the im- perial dignity ; when the friends of the civil liberties of the republic rafhly aflaflinated him in the £ n-te- houfe, where they fhould only have feized him and • , brought him to a legal trial for ufurpation. By this ■ impolitic-" lot C ^ S . I C'jihr. inipolltic meafure they defeated tbeir own purpofe, in- ^"""v"-— volving the city in confternation and terror, which pro- duced general anarchy, and paved the way to the revo- lution they wanted to prevent ; the monarchial govern- ment being abfolutely founded on the murder of Julius Ciefar. He fell in the 56th year of his age, 43 years before the Chriftian aera. His commentaries contain a hlftory pf his principal voyages, battles, and vi£lo- ries. The London edition in 1 7 1 2, in foho, is pre- ferred. The detail of Caefar's tranfaftions (fo far as is con- fiftent with the limits of this work) being given under "the article Rome, we fiiall here only add a portrait of * From thejjijn as drawn by a philofopher*. J'htTro" " ^^^^^ ^^^^ ^^P^*^ centuries, the truth may fhiques of he publl filed without offence, a philofopher might, in M. Oi hel- the following terras, cenfure Casfar without calum- niating him, and applaud him without exciting his blufiies. " Casfar had one predominant paffion : It was the love of glory ; and he pafTed 40 years of his life in feek- ing opportunities to foller and encourage it. His foul, entirely abforbed in ambition, did not open itfelf to other impulfes. He cultivated letters ; but he did not love them with enthuliafm, becaufe he had not leifure to become the firft orator of Rome. He corruptecT the one half of the Roman ladies, but hie heart had no concern in the fiery ardours of his fenfes. In the arms of Cleopatra, he thought of Pompey ; and this fmgu- lar man, who difdained to have a partner in the empire of the world, would have blufhed to have been for one inftant the flave of a woman. " We muft not imagine, that Caefar was born a war- rior, as Sophocles and Milton were born poets. For, if nature had made him a citizen of Sybaris, he would have been the moft voluptuous of men. If in our days he had been born in Penfylvania, he would have been the moft inoffenfive of quakers, and would not have dif- turbed the tranquillity of the new world. " The moderation with which he conduced himfelf after his vlftories, has been highly extolled ; but in this he fhowed his penetration, not the goodnefs of his heart. Is it not obvious, that the difplay of certain vli-tues is necefTary to put in motion the political ma^ chine ? It was rsqulfite that he ftiould have the appear- ance of clemency, if he inclined that Rome fhould for- give him his viftories. But what greatnefs of mind is there in a generofity which follows on the ufurpation of fupreme power ? *' Nature, while it marked Caefar with a fublime cha- rafter, gave him alfo that fpirit of perfeverance which renders.it ufeful. He had no fooner begun to refleft, . than he admired Sylla ; hated him, and yet wifhed to imitate him. At the age of 15, he formed the pro- ject of being diflator. It was thus that the prefident Montefquieu conceived, in his early youth, the idea of the fpirit of laws. *' Phyfical qualities, as well as moral caufes, contri- buted to give ftrength to his charafter. Nature, which had made him for command, had. given him an air of dignity. He had acquired that loft and infinuating eloquence, which is perfeftly fulted to feduce vulgar minds, and has a powerful influence on the moft culti- vated. His love of pleafure was a merit with the fair f x ; and women, who even in a republic can draw to '4 1 C JE S them the fufFrages and attention of men, have the higheft importance in degenerate times. The ladiets • of his age were charmed with the profpeft of ha- ving a diftator whom they might fubdue by their at- traftions. " In vain did the genius of Cato watch for fomee time to fuftain the liberty of his country. It was un - equal to contend with that of Cxfar. Of what availl were the eloquence, the philofophy, and the virtue off this republican, when oppofed by a man who had thte addrefs to debauch the wife of every citizen whofe in"> tereft he meant to engage ; who, poffelEng an enthu- fiafm for glory, wept, becaufe, at the age of 30, h(e had not conquered the world like Alexander ; and who), with the haughty temper of a defpot, was more defu* rous to be the firft man in a village than the fecond im Rome. *' Casfar had the good fortune to exift in times 0)f trouble and civil commotions, when the minds of mem are put into a ferment ; when opportunities of grea-.t aftlons are frequent; when talents are every thing, and thofe who can only boaft of their virtues are nothing;. If he had Hved an hundred years fooner, he would have been no more than an obfcure villain ; and, inftead o)f giving laws to the world, would not have been able t.o produce any confufion in it. " I will here be bold enough to advance an Ideai, which may appear paradoxical to thofe who weakly judge of men from what they atchieve, and not from the principle which leads them to aft. Nature formecd in the fame mould Caefar, Mahomet, Cromwell, antd KouH Khan. They all of them united to genius thait profound policy which renders it fo powerKil. They all of them had an evident fuperiority over thofe vv-Itlh whom they were furrounded ; they were confcious cjf this fuperiority, and they made others confcious of itt. They were all of them born fubjefts, and became for- tunate ufurpers. Had Caefar been placed in Perfia, hie would have made the conqueftof India; in Arabia, hie would have been the founder of a new religion; in Lora- don, he would have tabbed his fovereign, or have pro)- cured his affaffination under the fanftion of the lawss. He reigned with glory over men whom he had reduced to be flaves; and, under one afpeft, he is tobeconfider- ed as a hero; under another, asamonfter. But it v\'0uld be unfortunate, indeed, for fociety, if the pofTelfion of fuperior talents gave individuals a right to trouble it.s repofe. Ufurpers accordingly have flatterers, but n'ith more fecurity through the dominions of the Grand Mogul, and through other countries on the continent of the Eaft Indies. The Caffila differs from a caravan, at leaft in Per- fia : for the caffila belongs properly to fome fovereign, or to fome powerful company in Europe, whereas a caravan is a company of particular merchants, each trading upon his own account. The EngHfii and Dutch have each of them their caffila at Gambrow. There are alfo fuch caffilas, w^hich crofs fome parts of •the defer ts of Africa, particularly that called the fea of fandy \'<'liich lies between the kingdom of Morocco and thofe of Tombut and Gaigo. This is a journey of 400 leagues ; and takes up two months in going, and as .many in coming back ; the caffila travelling only by ■ night, on account of the exceffive heat of that country. The chief merchandize they bring back confifts in gold daft, which they call atibar, and the Europeans t':bh-. Caffila on the coaft of Guzerat or Cambaya, fig- nifies a fmall fleet of micrchant-fhips. CAFFRARIA, the country of the Caffres or Hot- tentots, in the moft foutherly parts of Africa lying in the form of a crefcent about the inland country of Mo- nomopata, between 35° fouth latitude and the tropic of Capricorn : and bounded on the eaft, fouth, and weft, by the Indian and Atlantic oceans. See Hotten- tots. Moft of the fea-coafts of this country are fubjeft to the Dutch, who l^ave built a fort near the moft fouthern promontory, called the Cape of Good-Hope. CAG, or Keg, a barrel or veffel, that contains from four to five gallons. CAGANUS, or Cacanus, an appellation anciently -given by the Huns to their kings. The word appears alfo to have been formerly applied to the princes of Mufcovy, now called c%ar. From the fame alfo, pro- bably, the Tartar title cham or an excellent work entitled AJlronomia fundamcnta no- 'viffimis foils et Jlellarum obfervationibus Jlahilila ; and the moft corredl folar tables that ever appeared. Ha- ving gone through a feven years feries of aftronomi- cal obfervations in his own obfervatory, he formed a projedl of going to obferve the fouthern ftars at the C Cape Caifong, Ca'vlie. C A I [ 1 Caille. Cape of Good Hope. This was highly approved by the » academy, and by the prime minifter Comte de Argen- fon, and very readily agreed to by the Hates of Hol- land. Upon this, he drew up a plan of the method he propofed to purfue in his fouthern obfervations ; fetting forth, that, befides fettling the places of the fixed ftars, he propofed to determine the parallax of the moon. Mars, and Venus. But whereas this required corre- fpondent obfervations to be made in the northern parts of the world, he fent to thofe of his correfpondents who were expert in praftical aftronoray previous no- tice, in print, what obfervations he defigned to make at fuch and fuch times for the faid purpofe. At length, on the 2ift of November 1750, he failed for the Cape, and arrived there on the 19th of April 1751. He forth- with got his inftruments on Ihore ; and, with the affift- *ance of fome Dutch artificers, fet about building an aftronomical obfervatory, in which his apparatus of in- ftruments was properly difpofed of as fooa as it w^as in a fit condition to receive them. The {l<.y at the Cape is generally pure and ferene, imlefs when a fouth-eaft wind blows. But this is of- ten the cafe ; and when it is, it is attended with fome ftrange and terrible effefts. The ftars look bigger, and feem to caper ; the moon has an undulating tremor ; and the planets have a fort of beard like comets. Two hundred and twenty-eight nights did our aftronomer furvey the face of the fouthern heavens ; during which fpace, which is almoft incredible, he obferved more than io,coo ftars ; and whereas the ancients filled the heavens with monfters and old-wives tales, the abbe de la Caille chofe rather to adorn them with the inftru- ments and machines which modern philofophy has * Sfe the m.ade ufe of for the conqueft of nature*. With no Planifpl^ere lefs fuccefs did he attend to the parallax of the moon, Mars, Venus, and the fun. Having thus executed the purpofe of his voyage, and no prefent opportunity of- fering for his return, he thought of employing the va- cant time in another arduous attempt ; no lefs than that of taking the meafure of the earth, as he had al- ready done that of the heavens. This indeed had, through the munificence of the French king, been done before by difl'erent lets of learned men both in Europe and America ; fome determining the quantity of a de- gree under the equator, and others under the arftic circle : but it had not as yet been decided whether in the fouthern parallels of latitude the fame dimenfions (ibtained as in the northern. His labours were re- warded with the fatisfaftion he wiflied for ; having de- termined a diftance of 410,814 feet from a place cal- led Kl'ip-Fontyn to the Cape, by means of a bafe of 38,802 feet, three times aftually meafured : whence he difcovered a new fecret'of nature, namely, that the radii of the parallels in fouth latitude are not the fame as thofe of the correfponding parallels in north lati- tude. About the 23d degree of fouth latitude he found » degree on the meridian to contain 342,222 Paris feet. He returned to Paris the 27th of September 1754 ; ha- ving in his ahiioft four years abfence expended no more than 9144 livres on himfelf and his companion ; and at his coming into port, he refufed a bribe of 100,000 livres, offered by one who thirfted lefs after glory than gain, to be fliarer in his immunity from cuftom-houfe iearches. After receiving the congratulatory vifits of his more 8 J c A r jn his - lum auprale jhll'Jtnint. intimate friends and the aftronomers, he firft of all Caille thought fit to draw up a reply to fome ftriiftures which profeffbr Euler had pubhfhed relative to the meridian, and then he fettled the refults of the comparifon of his own with the obfervations of other aftronomers for the parallaxes. That of the fun. he fixed at 9^:" ; of the moon, at 56' 56 ' ; of Mars in his oppofition, 36" ; of Venus, 38". He alfo fettled the laws whereby aftro- nomical refraftions are varied by the different dcn- fity or rarity of the air, by heat or cold, and drynefs or moifture. And, laftly, he ftiowed an eafy, and by common navigators pradlicable, method of finding the longitude at fea by means of the moon, which he illuf- trated by examples felefted from his own obfervations during his voyages. His fame being now eftabhihed upon fo firm a bafis, the raoft celebrated academies of Europe claimicd him as their own : and he was unani- moufly elefted a member of the royal fociety at I^on- don ; of the inftitute of Bologna ; of the imperial aca- demy at Peterft)urg ; and of the royal academies of Berlin, Stockholm, and Gottingen. In the year 1760, Mr de la Caille was attacked with a fevere fit of the gout ; which, however, did not interrupt the courfe of his ftudies ; for he then planned out a new and immenfe work, no lefs than a hiftory of aftronomy through all ages, with a comparifon of the ancient and modern ob- fervations, and the conftruftion and ufe of the inftru- ments employed in making them. In order to purfue the tafli he had impofed upon himfelf in a fuitable re- tirement, he obtained a grant of apartments in the royal palace of Vincennes ; and whilft his aftronomical apparatus was erefting there, he began printing his Catalogue of the fouthern ftars, and .the third volume of his Ephemerides. The ftate of his health was, to- wards the end of the year 1763, greatly reduced. His blood grew inflamed ; he had pains of the head, ob- ftruftions of the kidneys, lofs of appetite, with an op- pletion of the whole habit. His mind remained un- affefted, and he refolutely perfifted in his ftudies as ufual. In the month of March, medicines were ad- miniftered to him, which rather aggravated than al- leviated his fymptoms ; and he was now fenfible, that the fame diftemper which in Africa, ten years before, yielded to a few fimple remedies, did in his native country bid defiance to the beft phyficians. This in- duced him to fettle his affairs : his manufcripts he com- mitted to the care and difcretion of his efteemed friend M. Maraldi. It was at laft determined that a vein ftiould be opened ; but this brought on an obftinate lethargy, of which he died, aged 49. CAIMACAN.or CAiMACAM,in the Turkifh affairs, a dignity in the Ottoman empire, anfwering to lieute- nant, or rather deputy, amongft us. There are ufually two Caimacans ; one refiding at Conftantinople, as governor thereof ; the other attend- ing the grand vizir in quality of his lieutenant, fecre- tary of ftate, and firft minifter of his council, and gives audience to ambaftadors. Sometimes there is a third caimacan, who attends the fultan ; whom he acquaints with any public difturbances, and receives his orders concerning them. CAIMAN ISLANDS, certain American iflands lying fouth of Cuba, and north-weft of Jamaica, between 81° and 86'^ of weft longitude, and in 21 of north la- titude. They are moft remarkable on account of the 6 fifhery Call II Cains, C A I [ I fifliery of tortoife, which the people of Jamaica catch here, and carry home alive, keeping them in pens -for food, and killing them as they want them. CAIN, eldell fon of Adam and Eve, killed his brother Abel; for which he was condemned by God to banifhment and a vagabond Hate of life. ■Cain retired to the land of Nod, on the eaft of Eden ; and built a city, to which he gave the name of his fon Enoch. CAINITES, a feft of heretics in the zd century, fo called on account of their great refpeft for Cain. They pretended that the virtue which produced Abel was of an order inferior to that which had produced Cain, and that this was the reafon why Cain had the viftory over Abel and killed him; for they admitted a great number of genii, which they called virfi.vs, of different ranks :and orders. They made pfofeflion of honouring thofe who carry in Scripture the moft vifible marks of repro- ibation; as the inhabitants of Sodom, Efau, Korah, Dathan, and Abiram. They had, in particular, a ■very great veneration for the traitor Judas, under pre- ■tence that the death of Jefus Chrift had faved mankind. 'They had a forged gofpel of Judas, to which they paid ^reat refpeft. CAIRNS, or Carnes, the vulgar name of thofe Iheaps of Hones which are to be feen in many places of Britain, particularly Scotland and Wales. — They are compofed of ftones of all dimenfions thrown together 3in a conical form, a flat ftone crowning the apex; (fee Plate CXX VII.). Various caufes have been affigned by the learned for tthefe heaps of ftones. They have fuppofed them to have Ibeen, in times of inauguration, the places where the chief- ttain-eleft ftood to ftiow himfelf to beft advantage to the ipeople ; or the place from whence judgment was pro- nounced ; or to have been ereded on the road-fide in ho- nour of Mercury ; or to have been formed in memory of :fome folemn compaft, particularly where accompanied )by ftanding pillars of ftones ; or for the celebration of «certain religious ceremonies. Such might have been ithe realons, in fome inftances, where the evidences of ftone-chefts and urns are wanting : but thefe are fo generally found, that they feem to determine the mioft ufual purpofe of the piles in queftion to have ibeen for fepulchral monuments. Even this dcftina- tion might render them fuitable to other pui-pofes; iparticularly religiousj to which by their nature they jmight be fuppofed to give additional folemnity. — According to Toland, fires were kindled on the "tops or flat ftones, at certain times of the year, par- 'ticularly on the eves of the ift of May and the ift of November, for the purpofe of facrificing ; at which ■time all the people having extinguiftied their domeftic Ihearths rekindled them from thefacred fires of the cairns. In general, therefore, thefe accumulations appear to have been defigned for the fepulchral protection of 'heroes and jjreat men. The ftone-chefts, the repofi- ^ tory of the urns and afties, are lodged in the earth be- neath: fometimes only one, fometimes more, are found thus depofited; and Mr Pennant mentions an inftance of 1 7 being difcovered under the fame pile. Cairns are of different fizes, fome of them very large. Mr Pennant defcribes o^ne in the ifland of Arran, 114 ■■feet over and of a vaft height. They may juftly be ■.fuppofed to have been proportioned in fize to the rank 0 ] C A I of the perfon, or to his popularity : the people of a Cairo, whole diftrift aftemblcd to fliow their refpeft to the — — v"*-^ deceafed ; and, by an aftive Iionouring of his me- mory, foon accumulated heaps equal to thofe that a- ftonilh us at this time. But thefehonours were notmere- ly thofe of the day ; as long as the memory of the de- ceafed endured, not a paftenger went by without add- ing a ftone to the heap : they fuppofed it would be an honour to the dead, and acceptable to his manes. ^tanquam fejllnasy non ejl mora longa: Viceh'tty ItijeSo ter pulvere, cur r as. To this moment there is a proverbial expreflion a* mong the highlanders allufive to the old praftice : a fuppliant will tell his patron, Curri mi cloch er do charne, *' I will add a ftone to your cairn;" meaning. When you are no more, I will do all poflible honour to your memory. Cairns are to be found in all parts of our iflands, in Cornwal, Wales, and all parts of North Britain ; they were in ufe among the northern nations ; Dahlberg, in his 323d plate, has given the figure of one. In Wales they are called carneddau; but the proverb taken from them there, is not of the complimental kind : Karn ar dy beti, or, " A cairn on your head," is a token of imprecation. CAIRO, or Grand Cairo, the capital of Egypt, fituated in a plain at the foot of a mountain, in E. Long. 32.0. N. Lat. 30. o. It was founded by Jaw- har, a Magrebian general, in the year of the Hegira 358. He had laid the foundations of it under the ho- rofcope of Mai-s; and for that reafon gave his new city the name of Jl Kahirah, or the Fiaorious, an epitbet applied by the Arab aftronomers to that planet. In 362 it became the refidence of the kaliffs of Egypt, and of confequence the capital of that country, and has ever fince continued to be fo. It is divided into the New and Old cities. Old Cairo is on the eafteni fide of the river Nile, and is now almoft uninhabited. The New, which is properly Cairo, is feated in a fandy plain about two miles and a half from the old city. It ftands on the weftern fide of the Nile, from whic]i it is not three quarters of a mile diftant. It is ex'^ tended along the mountain on which the caftle is built, ■for the fake of which it was removed hither, in order, as fome pretend, to be under its proteftion. Plow- ever, the change is much for the worfe, as well with regard to air as water, and the pleafiuitnefs of the pro- fpeft. Bulack may be called the port of Cairo ; for it ftands on the bank of the Nile, about a mile and a half from it, and all the corn and other commodities are knded there before they are brought to the city. Some travellers have made Cairo of a moft enormous magnitude, by taking in the old city Bulack, and the new; the real circumference of it, however, is not above ten miles, but it is extremely populous. The firil thing that ftrikcs a traveller is the narrownefs of the ftreets, and the appearance of the houfcs. Thefe are fo daubed with mud on the outfide, that you would think they were built with nothing elfe. Befides, as the ftreets are unpaved, and always full of people, the walking in them is very inconvenient, efpecially to ftrangers. To remedy this, there are a great number of aftes, which always ftand ready to be hired for a -trifle, that is, a penny a mile. The owners drive C 2 them C A I [ 20 C A I Cairo, them along, and give notice to the crowd to make way. -—r—— And here it may be obferved, that the Chrillians in this, as well as other parts of the Turkifh dominions, are not permitted to ride upon horfes. The number of the inhabitants can only be guefifedat; bat we may conclude it to be very great, becaufc in ioxne. years the plague will caiTy off 200,coo, without their being much miffed. The houfes are from one to two or three ftories high, and flat at the top ; where they take the air, and often lleep all night. The better fort of thefe have a court on the infide like a college. The com- mon run of houfes have very little room, and even a- mong great people it is ufual for 20 or 30 to lie in the fmall hall. Some houfes wall hold 300 perfons of both fexes, among whom are 20 or 30 flaves, and thofe of ordinary rank have generally three or four. There is a canal called Halis, which runs along the city from one end to the other, with houfes on each fide, which make a large ftraight ftreet. Befides this, there are feveral lakes, which are called I'lrks in the language of the country. The principal of thefe, which is near the cattle, is 500 paces in diameter. The mioft elegant houfes in the city are built on its banks ; but w^hat is extraordinary, eight months in the year it con- tains water, and the other four it appears with a charm- ing verdure. When there is water fufficient, it ig al- ways full of gilded boats, barge«, and barks, in which people of condition take their pleafure towards night, at which time there are curious fire -works, and variety of mufic. New. Cairo is furrounded with walls built with ftone^ which are handfome battlements, and at the diftance of every hundred paces there are very fine towers, which have room for a gi-eat number of people. The walls were never very high, and are in many places gone to r^iln. The bafiia lives in the tsaftle, which was built by Saladine feven hundred years ago. It Hands in the middle of the famous mountain Moketan, which ter- minates in this place, after it had accompanied the Nile from Ethiopia hither. Tliis cattle is the only place of defence in Egypt ; and yet the Turks take no notice of its falling, infomuch that in procefs of time it win become a heap of rubbilh. The principal part in it is a magnificent hall, environed with 12 co- lumns of granite, of a prodigious height and thicknefs, which fuftain an op.en dome, under which Saladine diftrlbuted juttice to his fubjcfts. Round this dome there is an infcription in relievo, which determines the date and by whom it was built. From this place the whole city of Cairo may be feen, and above 30 miles along the Nile, with the fruitful plains that lie near it,, us well as the mofques, pyramids, villages, and gaixlens, with Vv'hich thefe fields are covered. Thefe granite pillars were the work of antiquity, for tliey were got out of the ruins of Alexandiia. There are likewife in the mofques and in the principal houfes no lefs than 40,000 more, befides great magazines, where all kinds are to be had at very low rates. A janiffary happened to find five in his garden, as large as thofe in tlie caf- tle; but could not. find any macliine of ftrength fuffi- cient to, move them, and therefore had them fawed in pieces to make mill-ftones. It is believed that there have been 30 or 40,000 of thefe pillars brought from Alexandria, where there are yet many miore to.be.had. The gates of Cairo arc three, which are very fine and magnificent. There are about 300 public mofques in this city, fome of which have fix minarets. The mofque of A- fhar hath feveral buildings adjoining, which were once a famous unlverfity, and 14,000 fcholars and Itudents were maintained on the foundation; but has now not above 1400, and thofe are only taught- to. read and write. AH the mofques are built upon the fame plan,, and differ only in magnitude.. The entrance is thro" the principal gate into a large fquare, open on the top, but well paved. Roinidthis are covered galleries,, fupported by pillars; under which/they fay their pray- ers, in the fhade. On one fide of. the fquare there are particular places with bafons of water, for. the conve- niency of perfox-ming the ablutions injoinedby the Ko- ran. The moft remarkable part of the mofque, befides the minaret, is the dome. This is often bold, well proportioned, and of an aftoniflilng magnitude. The infide ftones are carved like lace, flowers, and melons. They are built fo firm, and with fuch art, that they will laft 600 or. 700 years. Abo at the outward cir- cumference there are large Arabic infcriptions, in re- lievo, which may be read by thofe who ftand below, thoiigh they are fometimes of a wonderful height. The khanes or caravanferas are numerous and large, with a court in the middle, like their houfes. Some are feveral ttorles high, and are always full of people and merchandife. The Nubians, the Abyffinians, and other African nations, which come to Cairo, have one to themfelves, where they always meet with lodging. Hen; thev are feciwe from infults, and their efie6ts are all fafe. Befides thefe, there is a bazar, or market,, where all forts of goods are to be fold. This is in a long broad ftreet ; and yet the crowd Is fo great, you can hardly pafs along. At the end of this ftreet is a- nother fliort one, bat pretty broad, with fiiops -fuU of the bfctt fort of goods, and precious merchandife; At the end of this fhort ftreet there is a great khane, where all forts of white llaves are to be fold. Farther than this is another khane, where a great number of blacks, of both fexes, are expofed to fale. Not far, from the beft market-place is an hofpital, and a mofque for mad • people. They alfo receive and maintain fick people into this hofpital, but they are poorly looked after. Old Cairo has fcarce any thing remarkable but th-e granaries of Jofeph ; which are nothing but . a high wall, lately built, which includes a fquare fpot of ground, where they depofite wheat, barley, and other grain, which is a? tribute to the baflia, paid by the owners .of land. This has no other covering but the heavens, and therefore the birds are alwayvS fure to have their fnare. There is likewife a tolerable hand- fome church, which is made ufe of by the Copts, who., are Chriftlans and the original. inhabitants of Egypt. Jofeph's well is in the cattle, and was made by king. Mohammed about. 700 years ago. It is called Jofeph's. nuell, becaufe they attribute every thing extraordinary^- to that remarkable perfon. It is cut in a rock, and is,. 2.80 feet in depth. The water is drawn up to the top. by means of oxen, placed on platforms, at proper dif- tances, which turn about the machines that . raife it. The defcent is fo Hoping, that, though there are no. fteps, the oien can defcend and afcend with eafe. . C A I [ Cairo The river Nile, to which not only Cairo, but all .^ji^l ^ Egypt is fo much indebted, is now known to have its _^ *" '. rife in Abyflinia. The increafe of the Nile generally begins in May, and in June they commonly proclaim about the city how much it is rifen. Over againll old Cairo the bafha has a houfe, wherein the water enters to a column, which has lines at the diftance of every inch, and marks at every two feet as far as 30. When the water rifes to 22 feet, it is thought to be of a fufficicnt height ; when it rifes much higher, it does a great deal of mifchief. There is much pomp and ceremony ufed in letting the water into the canal, or Lali, above-mentioned. The-bafha gives the firft Itroke towards the removal of the dike or dam. When the water has filled the canal and lakes in the city, and the numerous citterns that are in the mofques and pri- vate houfes, it is let into a vail plain, to the north- eaft ; the extent of which is 50 miles. When the covmtry is covered with water, it is no unpleafant fight to view the towns appearing like little ifiands, and the people palling and repafling in boats. The inhabitants of Cairo are a mixture of Moors, Turks, Jews, Greeks, and Cophts, or Coptis. The only difference between the habit of the Moors and Coptis is their turbans ; thofe of the Moors being white, and of the Coptis white ftriped with blue. The common people generally wear a long black loofe frock, fewed together all down before. The Jews wear a frock of the fame fafliion, made of cloth ; and their caps are like a high crowned hat, v\-ithout brims, covered with the fame cloth, but not fo taper. The Jewilh womens are not very unlike the mens, but more light and long. The Greeks are habited like tlie Turks, only their turbans differ. Provifions of all kinds are exceeding plenty;, for 20 eggs may be bought for a parrah or penny, and bread is fix times as cheap as with »us. They have almott all forts of flefh and fifli ; and in particular have tame buffaloes, which are very ufeful. They bring goats into the flreets in great numbers, to fell their milk. Their gardens are well flocked with fruit-trees of va- rious kinds, as well as toots, herbs, melons, and cu- cumbers. The mofl common f^efh meat is mutton.. The goats are very beautiful, and have ears two feet, in length ; but their flefh is in no great efleem. CAIROAN, or Cairwan, a city of Africa, in the kingdom of Tunis, feated in a fandy barren foil, a- bout five miles from the gulph of Capres. It has neither fpring, well, nor river ; for. which reafon they are obliged to preferve rain-v/ater in-tanks and citterns. It was built by the Aglabites and is the ancient Cy- 3gg rene*, but hath now loft its fplendor. There is fiill, hiry.- however, a very fuperb mofque, and the tombs of the kings of Tunis are yet to be feen. E. Long. 9. 12. N. Lat. 35. 40. CAISSON, in the militar}^ art, a wooden cheft, i-nto which feveral bombs are put, and fometimes filled only with gunpowder : this is buried under foms work whereof the enemy intend to poffefs themfelves, and, when they are matters of it, is fired, in order to blow them up. Caisson is alfo ufed for a wooden frame or cheft ufed in laying the fo.undations of the piers of a bridge. CAITHNESS, otherwife caBed the>>f of Wkk, \i the moft northcriv county of alt Scotland j bounded 21 1 C A I on the eall by the ocean, and by Strafhnaver and Suther- Caithnefs. land on the fouth and fouth-wett : from thefe it is di- v— vided by the mountains Orde, and a continued ridge of hills as far as Knockfin, then by the whole courfe of the river Hallowdide. On the north it is wafhed by the Pentland or Putland frith, which flows between this county and the Orkneys. It extends 35 miles from north to fouth, and about 20 from eatt to weft. The coait is rocky, and remarkable for a number of bays and promontories. Of thefe, the principal are Sand- fide-head to the weft, pointing to the opening of Pent- land frith ; Orcas, now Holborn-head, and Diinnet - head, both pointing northward to the frith. Dunnet- head, is a peninfulu about a mile broad, and feven in compafs; affording feveral lakes, good paiture, excel- lent mill-ttones, and a lead-mine. Scribifter bay, on. the north-weft, is a good harbour, where fhips may ride fecurely. Rice-bay, on the eafl fide, extends three miles in breadth ^ but is of dangerous accefs, on ac- count of fome funk rocks at the entrance. At the bot- tom of this bay appear the ruins of two itrong catties,., the feat of the Earl of Caithnefs, called Cajlk Sinclair, and Gernegp, joined to each other by a draw-bridge. D'uncan'sbay, ot\\er\vi{t cvMtdLDunfoy-hea/l, isthenorth- eaft point of Caithnefs, and the extremeft promontory in Britain. At this place, the breadth of the frith does not exceed 12 miles, and in the neighbourhood is the ordinary ferry to the Orkneys. Here is likewife Clythe- nefs pointing eaft, and Nottiead pointing north-eafl. The fea in tliis place is very im.petuous, being in con-, tinual agitation from violent counter-tides, currents, and vortices. The only ifland belonging to this coun-- ty is that of Stroma, in the Pentland frith, at the di- ftance of two miles from, the main land, extending a- bout a mile in length, and producing good corn. The navigation is here rendered very difficult by conflifting tides and currents, which at both ends of the ifland produce a great agitation in. the fea. At the fouth end, the waves dance fo impetuoufly, that the failors. term them the merry men of May, alluding, to the houfe of one Mr May, on the oppofite fliore of Caithnefs, which ferved them as a land-mark, in tlie'dangerous pafi"age between the ifland and the continent. The pro- perty of this ifland was once difputed between the earls of Orkney and Caithnefs ; but. adjudged to the latter, in confequence of an experiment, by which it appeared, that venomous creatures will live in Stroma, whereas they die immediately if tranfported to the Orkneys. The county of Caithnefs, though chiefly mountainous, flattens towards the fea-coaft, where the ground is a- rable, and produces good harvefts of oats and barley, , fufficient for the natives, and yielding a furplus for exportation. Caithnefs is well watered with fmall rivers,, brooks, lakes, and fountains, and. affords a few woods of birch, but is in general bare of trees; and even thofe the inhabitants plant are ftunted in their growth. Lead is found at Dunnet, copper at Old Urk, and' iron ore at feveral places; but thefe advantages are not improved. The air of Caithnefs is temperate, tho' in the latitude of 58, where the longeft day in fummeris. computed at 18 hours; and when the fun iets, he makes fo fmall an arch of a circle below the horizon, that the people enjoy a twihght until he i-ifes again. The fuel ufed by the inhabitants of Caithnefs confifts of peat and- turf,, which the ground yield*, in great plenty. The. C A I [ 22 C»it'incf». forefts of Mo ravins and Bern" dale afford abundance of *■ red-deer and roe-bucks ; the country is well ilored with hares, rabbits, growfe, heathcocks, plover, and all forts of game, comprehending a bird called fnoiv- fleet, about the fize of a fparrow, exceedingly fat and delicious, that comes hither in large flights about the middle of February, and takes its departure in April* The hills are covered with fheep and black cattle ; fo numerous, that a fat cow has been fold at market for 4s. Sterling. The rocks along the coafts are frequented by eagles, hawks, and all manner of fea-fowl, whofe eggs and young are taken in vaft quantities by the na- tives. The rivers and lakes abound with trout, fal- inon, and eels ; and the fea affords a very advantageous fifhery. Divers obeliflcs and ancient monuments appear in this diitridl, and fevei-al Romifa chapels are ftill Handing. Caithnefe is well peopled with a race of hardy inhabitants, who employ themfelves chiefly in' fifliing, and breeding flieep and black cattle : they are even remarkably induftrious ; for between Wick and Dunbeath, one continued track of rugged rocks, ex- tending 12 miles, they have forced feveral little har- bours for their fifliing boats, and cut artificial fteps from the beach to the top of the rocks, where they have fCrefled houfes, in which they cure and dry the fifh for market. According to Mr Pennant, this county is fuppofed to fend out in fome years about io,ooohead of black cattle, but in bad feafons the farmer kills and falts great num- bers for fale. Great numbers of fvvine are alfo reared here. Thefe are fliort, high-backed, long brillled, fliarp, {lender, and.long-nofed ; have long ere£l; ears, and moil favage looks. Here are neitlier barns nor granaries: the corn is threflied out, and preferved in the chaff in byks ; which are flacks, in the fliape of bee- hives, thatched quite round, where it will keep good for two years. Vaft numbers of falmon are taken at Caftle-hifl, Dunnet, Wick, and Thurfo. A miracu- / lous draugbt at this laft place is ftill talked of, not lefs than 2500 being taken at one tide within the memoiy of man; and Mr Smollet informs us, that, in the neigh- bourhood, above 300 good falmon have been taken at one draught of the net. In the month of November, great numbers of feals are taken in the caverns that o- pen into the fea, and run fome hundreds of yai-ds un- der ground. The entrance of thefe caverns is narrow, but the infide lofty and fpacious. The feal-hunters en- ter thefe in fmall boats with torches, which they light as foon as they land, and then with loud ftiouts alarm the animals, which they kill with clubs as they attempt to pafs. This is a hazardous employment; for fliould the wind blow hard from fea, thefe adventurers are in- evitably loft. Sometimes a large fpecies of feals, 12 •feet long, have been killed on this coaft ; and it is faid the fame kind are found on the rock Hiflcir, one of the weftern iflands. During the fpring, 'great quantities of lump-fifli refort to this coaft, and are the pre)' of the ' feals, as appears from the number of fliins of thofe fiflies which at that feafon float -afliore. At certain times alfo the feals feem lobe vifited .by a great morta- lity; for, at thofe times, multitudes of them are feen dead in the water. Much Jimeftone is found in this country, which when burtit is n.ade into a compoft with turf and fea-plants. The common people are j queen Mary, and in great favour, he obtained a licence; to advance Gonville-hall, -where he had been educated „ into a college; which he endowed with feveral confi- derable eftates, adding an entire new fquare at the ex- pence oi 1834I. Of tjiis college he accepted the ma- fterfhip, which he kept till within a fliort time of hiss death. He was phyfician to Edward VI. queen Mary,, and Queen Ehzabeth. Towards the latter end of his life he retired to his own college at Cambridge ; where„ having refigned the mafterfliip to Dr I^egge of Nor- wich, he fpent the remainder of his life as a fellow- commoner. He died in July 1573, aged 63; and wats buried in the chapel of his own college. Dr Caius wats a learned, aftive, benevolent man. In 1557, he erec - ted a monument in St Paul's to the memory of the fat-- mous Linacre. In 156,3, he obtained a grant for th(e college of phyficians to take the bgdies of two malc- fa(ftoiT3 C A L I 2 . Cake fsTaftors annually for difleftlon ; and he was the inven- II _ tdor of the infignia which diftingulfh the prefident from Calabria |. j^hg reft of the fellows. He wrote, i . Annals of the ccoUege from l55'qtoi572. 2. Tranflation of feveral ot)f Galen's works. Printed at different times abroad. 33. Hippocrates de MedicamenttSj firft difcovered and ppublifhed by our author; alfo De rc^t'nne vl3us, Lov. 1 1556, 8vo. 4. De medendi Methodo. Balil, 1544, Lond. 11556, 8vo. 5. Account of the fweating ficknefs in lEngland. Lond. 1556. 1721. It is entitled De ephe- ^ nmera Britatinica. 6. Hiftory of the univerfity of Cam- bbridge. Lond. 1568, 8vo. 1574, 4to. in Latin. "j.De thherm'is Brilami'ids. Doubtful whether ever printed. 88. Of fome rare plants and animals. Lond. 1570. 99. De canmbus Britannicis, 1 5 70, 1 729. 10. De pro- Titiunc'iattom Gra-ca et Lat'ina Lingute. Lond. 1574. 11. LDelibrh propriis. Lond. 1570. Befides many other vwoxks which never were printed. CAKE, a finer fort of bread, denominated from its flflat round figure. We meet with different compofitions under the name oof cakes ; as feed-cakes, made of flour, butter, cream, fu- ggar, coriander and caraway feeds, mace, and other fjfpices and perfumes baked in the o\tn; plum-cake, made nmuch after the fame manner, only with fewer feeds, aand the addition of currants ; pan-cakes, made of a nmixture of flour, eggs, &:c. fried; cheefe-cakes, made of GCream, eggs, and flour, with or without cheefe-curd, bbutter, almonds, &c. oat-cakes, made of fine oaten flour, nmixed with yett and fometimes without, rolled thin, aand laid on an iron or ftone to bake over a flow fire ; fifugar-cakes, made of fine fugar beaten and fearced with t the fineft flour, adding butter, rofewater, and fpices ; rrofe-cakes, placentae rofacea, are leaves of rofes dried and ppreffed into a mafs, fold in the fliops for epithems. The Hebrews had feveral forts of cakes, which they ooffered in the temple. They were made of the meal e either of wheat or barley ; they were kneaded fome- ttimes with oil and fometimes with honey. Sometimes tthey only rubbed them over with oil when they were bbaked, or fried them with oil in a frying pan upon the fifire. In the ceremony of Aaron's confecration, they f;facrificed a calf and two rams, and offered unleavened bbread, and cakes unleavened, tempered with oil, and vwafers unleavened anointed with oil ; the whole made oof fine wheaten flour. Ex. xxix. i, 2. CAKET, a town of Aiia, in Perfia, in the province oof Gurgiftan near Mount Caucafus. Its trade confifts Gchiefly in filks. E. Long. 46. 15. N. I^at. 43. 32. CALABASH, in commerce, a light kind of veffel f formed of the fhell of a gourd, emptied and dried, fer- vving to put divers kinds of goods in, as pitch, rofin, aand the like. The word is Spanifli, Calahacca, which fifignifies the fame. The Indians alfo, both of the North aand South Sea, put the pearls they have fiflied in ca- Idabafhes, and the negroes on the coaft of Africa do the f fame by their gold-duft. The fmaller calabaflies are aalfo frequently ufed by thefe people as a meafure, by vwhich they fell thefe precious commodities to the Eu- rropeans. The fame veffels likewife ferve for putting iin liquors; and do the office of cups, as well as bottles, ffor foldiers, pilgrims, &c. CALABASH-Tree, in botany. See Crescentia. African CALABASH-Tree. See Adansonia. CALABRIA, a country of Italy, in the kingdom \ I C A L of "Naples, divided into Calabria Ultra, and Calabria Calabi Citra, commonly called Ulterior and Citerior, or Far- ther and Hither Calabria. Calabria Citerior is one of the 1 2 provinces of the kingdom of Naples ; and bound- ed on the fouth by Calabria Ultra, on the north by Bafilicata, and on the weft and eaft by the fea : Co- fenfa i? the capital. Calabria Ultra is wafhed by the Mediterranean fea on the eaft, fouth, and weft, and bounded by Calabria Citra on the north. Reggio is the capital town. This country has been almoft entirely dcfolated by the earthquakes of 1783. The reiterated fliocks ex- tended from Cape Spartivento to Amantea above the gulf of St Eufemia, and alfo affefted that part of Sicily which lies oppofite to the fouthern extremity of Italy. Thofe of the 5th and 7th of February, and of the 28th' of March, were the moft violent, and completed the deftruftion of every building throughout the above- mentioned fpace. Not one ftone was left upon another fouth of the narrow ifthmus of Squillace ; and what is more difaftrous, a very large proportion of the inhabi- tants was killed by the falling of their houfes, near 40,000 lives being loft. Some perfons were dug out alive after remaining a furprifing length of time buried among the rubbifh. Meifma became a mafs of ruins its beautiful palazzata was thrown in upon the town, and its quay cracked into ditches full of water. Reggio almoft deftroyed ; Tropea greatly dama-- ged ; every other place in the province levelled to the ground. Before and during the concuffion the clouds gather- ed, and then hung immoveable and heavy over the earth. At Palmi the atmofphere wore fo fiery an afpeft, that many people thought part of the town was burning. It was afterwai-ds remembered that an un-- ufual heat had affefted the llcin of feveral perfons juft before the fliock ; the rivers affumed a muddy afli- coloured tinge, and a fulphureous fmell was almoft ge- neral. A frigate paffmg between Calabria and Lipari felt fo fevere a fliock, that the fteerfman was thrown from the helm, and the cannons were raifed up on their carriages, while all around the fea- exhaled a ftrong- fmell of brimftone. Stupendous alterations were occafioned in the face" of the country ; rivers choaked up by the falHng in of the hills, were converted into lakes, which if not fpeedily drained by fome future convulfion, or opened by human labour, will fill the air with peftilential vapours, and' deftroy the remnants of population. Whole acres of" ground, with houfes and trees upon them, were broken off from the plains, and waflied many furlongs down' the deep hollows which the courfe of the rivers had' worn; there, to the aftonifliment and terror of behold-- ers, they found a new foundation to fix upon, either in an upright or an inclining pofition. In fliort, every fpecies of phenomenon, incident to thefe deftruAive commotions of the earth, was to be feen in its utmoft extent and variety in thi* ruinated country. Their Sicihan majefties, with the utmoft expedition, dif- patched veffels loaded with every thing that could be thought of on the occafion for the relief and accommc-- dation of the diftreffed Calabrians ; a general officer - went from Naples with engineers and troops to direct*" the operations of the perfons employed in clearings away and rebuilding the houfes, and to defend the- propertyy GAL C n 1 GAL I Calade II property of the fufFerers. The king ordered this offi- cer to take all the money the royal treafures could fup- ply or borrow ; for, rather than it (hould be wanting on this prefling call, he was determined to part with his plate, nay, the very furniture of his palace. A i-nefTenger fent off from a town near Regglo ort the 8th of February, travelled four days without flielter, and without being able to procure a morfel of bread; he fupported nature with a piece of cheefe which he had brought in his pocket, and the vegetables he was lucky enough to find near the road. To add to all their other fufferings, the Calabrlans found themfelves and the miferable wreck of their fortunes expofed to the depredations of robbers and pirates. Villains landed from boats and plundered feveral places, and thieves went even from Naples in fearch of booty : In order to ftrike a greater terror, they dreffed them- felves like Algerines; but were difcovered and driven off. To this accumulated diftrefs fucceeded a mod in- clement feafon, which obftrufted every effort made to alleviate it ; and almoft daily earthquakes kept the in- habitants in continual dread, not of being deftroyed by the fall of houfes, for none were left, but of being Twallowed up by the fplitting of the earth, or buried in the waves by fome fudden inundation. For further particulars concerning this dreadful ca* taftrophe, and the phenomena attending It, fee Earth- QXJAKE. CALADE, in the manege, the defcent or floping declivity of a rifing manege ground, being a fmall emi- nence, upon which we ride down a horfe feveral times, putting him to a (liort gallop, with his fore-hams in the air, to learn him to ply or bend his haunches, and form his flop upon the aids of the calves of the legs, the ftay of the bridle, and the cavefon feafonably given. CALAGORINA, or CalAguris, diftlnguirtied by the furname Naftca (anc. geog.), a city of the Vafcones in the Hither Spain; now Calahorra. CALAHORllA, an epifcopal town of Spain, In Old Caftile, feated in a fertile foil, on the fide of a hill which extends to the hanks of the river Ebro. W. Long. 2. 7. N. Lat. 42. 12. CALAIS, a ftrong town of France, in Lower PI- cardy, with a citadel and a fortified harbour. It is built in the form of a triangle, one fide of which is towards the fea. The citadel is as large as the town, and has but one entrance. It Is a trading place, with handfome ftreets, and feveral churches and monafterles; the num- 'iser of inhabitants is reckoned to be 4000. Calais was taken by Edward III. In 1 347. Hither he marched his vlftorlous army from Crefcy, and invefted the town on the 8th of September. But finding that it could not be taken by force without the deftruftion of great multitudes of his men, he turned the fiege into a blockade ; and having made ftrong entrenchments to fecure his army from the enemy, huts to proteft them from the inclemency of the weather, and ftationed a fleet before the harbour to prevent the IntroduAIon of provlfions, he refolved to wait with patience till the place fell Into his hands by famine. The befieged, difcovcring his intention, turned feventeen hundred wo- men, children, and old people, out of the town, to fave their provlfions ; and Edward had the goodnefs, after entertaining them with a dinner, and giving them two- pence a-plece, to fuffer them to pafs. The garrifon N°6i. and inhabitants of Calais having at length confumed all their provlfions, and even eaten all the horfes, dogs, cats, and vermin, in the place, the governor John de Vienne appeared upon the walls, and ofTered to capitu- late* Edward, greatly incenfed at their obftinate re- . fiftance, which had detained him eleven months under their walls, at an imniettfe expence both of men and money, fent Sir Walter Manny, an Illuftrious knight, to acquaint the governor, that he Would grant them no terms ; but that they muft furrender at difcretion. At length, however, at the fpirited. remonfl:rances of the governor, and the perfuafions of Sir Walter Manny, Edward confented to grant their lives to all the garri- fon and inhabitants, except fix of the principal bur- geffes, who ftiould deliver to him the keys of the city, with ropes about their necks* When tliefe terms were made known to the people of Calais, they were plunged into the deepeft diftrefs ; and after all the miferies they had fuffered, they could not think without horror of giving up fix of their fellow-citizens to cer- tain death. In this extremity, when the whole people were drowned in tears, and uncertain what to do, Euftace de Pierre, one of the richcfu merchants In the place, ftepped forth, and voluntarily offered himfelf to be one of thefe fix devoted viftlms. His noble exam- ple was foon imitated -by other five of the moft wealthy citizens. Thefe true patriots, barefooted and bare- headed, with ropes about their necks, were attended to the gates by the whole Inhabitants, with tears, blef fings, and prayers, for their fafety. When they were brought into Edward's prefence, they laid the keys of the city at his feet, and falling on their knees implored his mercy in fuch moving ftralns, that all the noble fpedtators melted Into tears. The king's refentment was fo ftrong for the many toils and loffes he had fuf- fered in this tedious fiege, that he was in fome danger of forgetting his ufual humanity ; when the queen, falling upon her knees before him, earneftly begged and obtained their lives. This great and good princefs conduced thefe virtuous citizens, whofe lives fhe had faved, to her own apartment, entertained them honour- ably, and difmiffed them with prefentg. Edward took poffeffion of Calais Auguft 4th; and in order to fecure a conqueft of fo great importance, and which had coft him fo dear, he found It neceffary to turn out all the ancient Inhabitants, who had difcovered fo ftrong an attachment to their native prince, and to people it with Englifti. Calais remained in fubjeftlon to England till the reign of queen Mary, when it was retaken by the duke of Guife. This general began the enterprife by ordering the privateers of Normandy and Bretagne to cruize In the channel, more efpecially in the very ftralts of Calais : he then detached the duke of Nevers, with a confiderable army, towards the country of Luxem- burgh ; a motion which drew the attention of the Spaniards that way : when all things were ready, he procured an application from the people of Boulogne, for a body of troops to fecure them agalnft the incur- fions of the Spaniards ; he fent a ftrong detachment at their requeft, which was followed by another, under colour of fupporting them, then repaired thither in perfon, fecure that his officers would follow his in* ftruftions ; and thus, on the firft day of the new year, 1557, Calais was invefted. He immediately at- 3 tacked Calais. C A L Calais, tacked fort St Agatha, which the gamfon quitted, ■~"v~--' and retired into the fort of Nieulai, which, together with the Rifbank, the heiiegers attacked at the fame time, granted good terms to the officer who commanded in the former, but obliged the garrifon of the latter to furrender prifoners of war. By thefc means he opened a communication with the fea ; and having received from on board the iliips an imraenfe quantity of hurdles, his infantry, by the help of them, paffed the morafles that lie round the town. He then made a falfe attack at the water-gate, which drew the atten- tion of the garrifon, who fatigued themfelves exceed- ingly in making entrenchments behind the breach; hut when tliey had finifhed their work, he began to Are upon the caftle, wdiere the walls were very old, and had been negledlcd on account of the breadth of the ditch, which was alfo very deep when the tide was in ; but a great breach being made, the duke caufed it to be attacked in the night, and during the ebb the foldiers paffing almoft up to the (houlders. The place was ealily carried, though the governor made three vi- gorous attacks before the break of day, in order to diflodge them ; but the French, though they loft a confiderable number of men, kept their pofts. The governor then faw that it was impraAicable to de- fend the place any longer, and therefore made the beft terms for himfclf that he could obtain, which, however, were not veiy good : and thus in eight days the duke of Guife recovered a fortrefs which coft the vidtorious Edward III. a whole year's iiege, and which had been now aio yeai-s in the pofTeffion of the Eng- Jifh, without fo much as a /ingle attempt to retake it. There are very different accounts given of this matter; Some Engliih hiilorians fay, that king Philip pene- trated the defign of the French upon this fortrefs, gave notice of it in England, and offered to take the defence of it upon himfelf ; but that this, out of jea- loufy, was refufed, it being believed to be only an ar- tifice to get a place of fuch confequence into his own hands. The truth of the matter feems to be this : The ftrength and, William Sparilow. 26 ] C A L He was after that an aftive member in the affembly of Cabmy. divines, was a fl:renuous oppofer of feftaries, and ufed v — his utmoft endeavours to prevent thofe violences com- mitted after the king was brought from the ifle of Wight. In Cromwell's time he lived privately, but was affiduous in promoting the king's return ; for which he was afterwards offered a bifliopric, but re- fufed it. He was eje£ted for nonconformity in 1662; and died of grief at the fight of the great fire of London. Calamy (Edmund), grandfon to the preceding (by his eldeft fon Mr Edmund Calamy, who was ejefted out of the living of Moxton in Effex on St Bartholomew's day 1662), was born in London, April 5th 1671. Af- ter having learned the languages, and gone through a courfe of natural philofophy and logic at a private academy in England, he lludied philofophy and civilr law at the univerfity of Utrecht, and attended the lec- tures of the learned Grsevius. Whilil he refided here,, an offer of a profeffor's chair in the univerfity of Edin- burgh was made him by Mr Carftairs, principal of that univerfity, fent over on purpofe to find a perfon pro- perly qualified for fuch an office. This he declined j and returned to England in 1691, bringing with him letters from Grsvius to Dr Pocock canon of Chrill- church and regius profeffor of Hebrew, and toDrlBer- nai'd Savilian profeffor of aftronomy, who obtained leave for him to profecute his ftudies in the Bodleian library. Having refolved to make divinity his principal ftudy, he entered into an examination of the contro- verfy between the conformifts and nonconformifts ; which determined him to join the latter : and coming to London in 1692, he was unanimoufly chofen affifl:- ant to Mr Matthew Sylvefter at Blackfriars ; and lit , 1694, he was ordained at Mr Annefly's meetlng- houfe in Little St-Helena, and foon after was invited to become affiftant to Mr Daniel Williams in Hand- AUey. In 1702, he was chofen to be one of the lec- turers in Salter's-hall ; and, in 1703, fucceeded Mr Vincent Alfop as paftor of a great congregation in Weftminfter. He drew up the table of contents to Mr Baxter's lilftory of his life and times, which was fent to the prefs in 1 696 ; made fome remarks on the work itfelf, and added to it an index; and, reflefting on the ufefulnefs of the book, he faw the expediency of con- tinuing it, for Mr Baxter's hiftory came no lower than the year 1684. Accordingly he compofed an abridge- ment of it, with an account of many other minifl;ers who were tjefted after the reftoration of Charles II. ; their apology, containing the grounds of their non^ conformity and praftlce as to ftated and occafional communion with the church of England ; and a con^ tlnuation of their hiftory till the year 1691. This work was publiflied In 1 702. He afterwards publlflied a mode- rate defence of nonconformity, in three trafts, in anfwer to fome trads of Dr Ploadley. In 1709, Mr Calamy made a tour to Scotland; and had the degree of dodlor of divinity conferred on him by the univerlities of Edir.a burgh, Aberdeen, and Glafgow. In 1713, lie publifh- ed a fecond edition of his Abridgement of Mr Bax- ter's hiftory of his life and times ; in which, among other additions, there is a continuation of the hiftory through king William's reign, and queen Anne's, down to the paffmg of the occafional bill ; and in the clofe is fubjoined the reformed liturgy, which was drawa. C A L f Calandre, dravfn up and prefented to the birtiops in 1 66 1, " that Calas. tj^e world may judge (he fays in his preface) how fair- ' ly the ejected minillers have been often reprefented as irreconcileable enemies to all liturgies." In 17 18, he wrote a vindication of his grandfather, and feveral other perfons, againft certain refleftions call upon them by Mr Archdeacon Echard in his Hiftory of England; and in 1728 appeared his Continuation of the account of the minifters, lefturers, mailers, and fellows of colleges, and fchoolmallers, who were ejeiled, after the reftoration in 1660, by or before the aft of uniformity. He died June 3d 1732, great- ly regretted not only by the dilTenters, but alfo by the moderate members of the eftablifhed church, both clergy and laity, v/ith many of whom he lived in great intimacy. Befides the pieces already mention- ed, he publifhed a great many fermons on feveral fub- jefts and occafions. He was twice married, and had 13 children. C ALAND RE, a name given by the French wri- ters to an infeft that does vaft mifchief in granaries. It is properly of the fcarab or beetle clafs ; it has two antennae or horns formed of a great number of round joints, and covered with a foft and fhort down ; from the anterior part of the head there is thruft out a trunk, which is fo formed at the end, that the crea- ture eafily makes way with it through the coat or flcin that covers the grain, and gets at the meal or farina on which it feeds ; the infide of the grains is alfo the place where the female depofits her eggs, that the young pi'ogeny may be born with provifion about them. When the female has pierced a grain of corn for this purpofe, (he depofits in it one egg, or at the utmoft two, but file moil frequently lays them fingle : thefe eggs hatch into fmall worms, which are ufually found with their bodies rolled up in a fpiral form, and after eating till they arrive at their full growth, they are changed into chryfales, and from thefe in about a fortnight comes out the pcrfedl calandre. The fe- male lays a confiderable number of eggs ; and the in- creafe of thefe creatures would be very great : but na- ture has fo ordered it, that while in the egg ftate, and even while in that of the worm, they are fubjedlto be eaten by mites ; thefe little vermin are always very plentiful in granaries, and they deilroy the far greater number of thefe larger animals. CALAS {John), the name of a moll unfortunate Proteftant merchant atThouloufe, inhumanly butchered under forms of law cruelly proftituted to fhelter the fanguinary di£lates of ignorant Popifh zeal. He had lived 40 years at Thouloufe. His wife was an Englifh woman of French extra6lton : and they had five fons ; one of whom, Lewis, had turned Catholic through the perfuafions of a Catholic maid who had lived 30 years in the family. In Oftober 1761, the family confiiled of Calas, his wife, Mark Anthony their fon, Peter their fecond fon, and this maid. Anthony was educated for the bar ; but being of a melancholy turn of mind, was continually dwelling on palTages from authors on the fubjeft of fuicide, and one night in that month hanged himfelf on a bar laid acrofs two folding doors in their (hop. The crowd coUedled by the confufion of the family on fo (hocking a 4ifcovery, l ook it into their heads that he had been ilrangled by the family to prevent his changing his religion, and 27 ] C A L that this was a commdn pra£lice among protellants. The officers of juflice adopted the popular tale, and were fupplied by the mob with what they accepted as evidences of the fadl. The fraternity of white peni- tents got the body, buried it with great ceremony^ and performed a folemn fervice for him as a martyr; the Francifcans did the fame : and after thefe formali- ties no one doubted the guilt of the devoted heretical family. They were all condemned to the torture, to bring them to confeffion: they appealed to the parlia- ment ; who, as weak and as wicked as the fubordinate magiilrates, fentenced the father to the torture ordi- nary and extraordinary, to be broken alive upon the wheel, and then to be burned to aihes. A diabolical decree ! which, to the fhame of humanity, was atlu- ally carried into execution. Peter Calas, the other fon, was baniflied for life ; and the reft were acquitted. The diftrafted widow found fom.e friends, and among the reft M. Voltaire, who laid her cafe before the council of ftate at Verfailles, and the parliament of Thouloufe were ordered to tranfmit the proceedings. Thefe the king and council unanimoufly agreed to an- nul ; the capitoul, or chief magiftrate of Thouloufe, was degi-aded and fined ; old Calas was declared to have been innocent ; and every imputation of guilt was removed from the family, who alfo received from the king and clergy confiderable gratuities. CALA&H.,. or Cales-h, a fmall light kind of cha- riot or chair, with very low wheels, ufed chiefly for taking the air in parks and gardens. The calafh is for the moft part richly decorated, and open on all fides for the conveniency of the air and profpeft, or at moft, inclofed with light mantlets of wax-cloth to be opened and fhut at pleafure. In the Philofophical Tranfac" tions we have a defcription of a new fort of calafti go- ing on two wheels, not hung on traces, yet eafier than the common coaches, over which it has this further advantage, that whereas a common coach will over- turn if one wheel go on a furface a foot and an half higher than the other, this will admit of a difference of 34- feet without danger of overturning. Add, that it would turn over and over ; that is, after the fpokes being fo turned as that they are parallel to the hori- zon, and one wheel flat over the head of him that rides in it, and the other flat under him, it will turn once more, by v/hich the wheels are placed in Jlatu quo, without any diforder to the horfe or rider. CALASIO (Marius), a Francifcan, and profeffbr of the Hebrew language at Rome, of whom there is very little to be faid, but that he publiflied there, in the year 1621, a Concordance of the Bible, which confifted of four great volumes in folio. This work has been highly approved and commended both by Proteftants and Papifts, and is indeed a moft admi- rable work. For befides the Hebrew words in the Bible, which are in the body of the book, with the Latin verfion over againft them ; there are, in the margin, the differences between the feptuagint verfion and the vulgate; fo that at one view may be feen wherein the three Bibles agree, and wherein they dif- fer. Moreover, at the beginning of every article there is a kind of di£lionary, wliich gives the fignification of each Hebrew word ; affords an opportunity of com- paring it with other oriental languages, viz. with the isyriac, Arabic, and Chaldee ; and is extremely ufeful I D 2 for Calafio. C A L [ 2 Calafirls for determining more exaftly the true meaning of the Calauria ■^'^^1"^^ WOrds. 1 ^ CALASIRIS, in antiquity, a linen tunic fringed at the bottom, and worn by tlie Egyptians under a white woollen garment : but this lail they were ob- lig;ed to pull off when they entered the temples, being only allowed to appear there in linen garments. CALATAJUI), a large and handfome town of Spain, in the kingdom of Arragon ; fituated at the confluence of the rivers Xalon and Xlloca, at tlie end of a very fertile valley, with a good caftle on a rock. W. I^ong. 2. 9. N. Lat. 41. 22. CALATHUS, in antiquity, a kind of hand-balket made of light wood or ruflies ; ufed by the women fometinies to gather flcvi'ers, but chiefiy, after the ex- ample of Minerva, to put their work in. The figure of the calathus, as reprefented on ancient monuments, is narrow at the bottom, and widening upwards like that of a top. Pliny compares it to that of a lilv. The Calathus or work-baikct of jNIinerva is no lefs ce- lebrated among the poets than her dillaff. Calathus was alio the name of a cup for wine, ufed in facrinces. CALATOR, in antiquity, a cryer, or officer ap- pointed to publiih fomething aloud, or call the peo- ple together. The word is formed from xkx:^, 'uqco, I call. Such minii^ers the pontifices had, whom they lUed to fend befoi-e them when they went to facrifice on fitia or holidays, to advertife the people to leave off work. The magiftrates alfo ufed calatores, to call the people to the comitia, both curiata and centur'iata. The officers in the army :Jfo had calatores ; as had like- wife many private lamiUes, to invite their guefts to entertainments. CALATRAVA, a city of New Caftile, in Spain, fituated on the river Guadiana, 45 miles foutli of To- ledo. W. Long. 4. 20. N. I^at. 39. o. Knights of CjLATRAyji, a military order in Spain, inftituted under Sancho III. king of Caftile, upon the following occ:»fior>. When that prince took the Itrong fort of Calatrava from the mo*irs of Andalufia, he jrave It to the templars, who, wantmg courage to defend it, returned it him again. Then Don Reymond, of the order of the Ciilercians, accompanied with feveral |)erfons of quality, made an offer to defend the place, which the king thereupon delivered up to them, and inftituted that order. It increafed fo much under the leign of Alphonfus, that the knights defired they might have a grand mafter, which was granted. Fer- dinand and Ifabella afterwards, with the confent of pope Innocent VIII. re-united the grand- mafterfhip of Calatrava to the Spanifh ci-own ; fo that the kings of Spain are now become perpetual adminiftrators there- of. The knights of Calatrava bear a crofs gules, flower- ^elifed with green, &c. Their rule and habit was ©riginally that of the Ciitercians. , CALAURIA (anc. geog.), an ifland of Greece in the Saronic bay, overagainft the port of Troezen, at the diftance of 40 ftadia. Hither Demofthenes went twice into baniihment ; and here he died. Nep- tune was faid to have accepted this ifland from Apollo in exchange for Delos. The city ftood on a high ridge nearly in the middle of the ifland, commanding an extenfive view of the gulf and its coaib. Tli^re 8 ] C A L was his holy temple. The prieftefs was a virgin, who Calcad* was difmiffed when marriageable. Seven of the cities ^ , " . near the ifland held a congrefs at it, and facrificed '""^ jointly to the deity. Athens, ^gina, and Epidaurus were^ of this number, with NaupHa, for which place Argos contributed. The Macedonians, when they had reduced Greece, were afraid to violate the fandluary,, by forcing from it the fugitives, his fuppliants. An- tipater commanded his general to bring away the ora- tors, who had offended him, alive ; but Demofthenes could not be prevailed on to furrender. His monu- ment remained in the fecond century, within the in- clofure of the temple. The city of Calauria has been long abandoned. Traces of buildings, and of ancient walls, appear nearly level with the ground ; and forae ftones, in their places, each with a feat and back, forming a little circle, once perhaps a bath. The tem- ple, which was of the Doric order, and not large, as may be inferred from the fragments, is reduced to an inconfiderable heap of ruins. The ifland is now called Poro. It ftrcfches along before the coaft of the Mo- rea in a lower ridge, and is feparated from it by a canal only four ftadia or half a mile wide. This, which is- called Poro or the Ferry, in ftill weather may be pafled on foot, as the water is not deep. It has given its name to the ifland ; and alfo to the town, which con- fifts of about 200 hcufes, mean and low, with flat roofs ; rifing on the flope of a bare difagreeable rock. CALCADA, or St Dimlngo CAicJJ.DAy a town of Spain, fituated in W. Long. 3. 5. N. Lat. 42. 36. CAJ^CAR, a very ftrong town of Germany, in the circle of Weftphalia, and duchy of Cleves. It belongs to the king of Pruffia, and is feated near the Rhine, in E. Long. 5. 41. N. Lat. 51. 45. Calcar, in glafs-making, the name of a fmall ovcn^ or reverberatory furnace, in which the firlt calcination of fand and fait of potaflies is made for the turning them into what is called frit. This furnace is made in the fafliion of an oven, tea feet long, feven broad in* the wideft part, and two feet deep. On one lidc of it is a trench fix inches fquare, the upper part of which is level with the calcar, and feparated only from it at the mouth by bricks nine inches wide. Into this trenclv they put fea-coal, the flame of which is carried into every part of the furnace, and is reverberated from the roof upon the frit, over the furface of which the fmoke flies very black, and goes out at the mouth of the calcar ; the coals burn on iron-grates, and the afties fall through. » Calcar (John de), a celebrated painter, was the difciple of Titian, and perfe<£led himfclf by ftiidying Raphael. Among other pieces he drew a nativity, re- prefenting thiC angels around the infant Chrift: ; and fo ordered the difpuiicion of his pidture, that the light all proceeds from the child. Pie died at Naples, in, 1546, in the flower of his age. It was he who de- figned the anatomical figures of Vefal, and the por- traits of the painters of Vefari. CALCAREOUS, fomething that partakes of the nature and qualities of calx, or lime. We fay, a cal^ careous earth, calcareous ftone. See CusMiSTKr-Index, CALCEARIUM, in antiquity, a donative or la*- gefs beftowed on Roman foldiers for buying flioes. Itt monafteries, calcearium denoted the daily fervice of ekaning the flioes of the religious. 5 CAL. C A L r 2g ] la CALCEOLARIA, in botany; a genus of the mo- covered nogynia order, belonging to the diandria clafs of plants. The eoroUa is ringent and inflated ; the capfule has two cells, and two valves ; the calyx four parted and equal. CAIXHAS, in fabulous hiftory, a famous di- viner, followed the Greek army to Troy. He foretold that the fiege would laft ten years ; and that the fleet, which was detained in the port of Aulis by contrary C A L over vilth. wax. Their form is ftill feen in forae medals of the Caflian family ; and the manner of calling them into the urns, in the medals of the Lici- nian family. The letters marked upon thefe calculi were U. R. for utt rogas, and A. for antiqm ; the firft of which exprefled an approbation of the law, the lat- ter a rejeclicn of it. Afterwards the judges who fat in capital caufes ufed calculi marked with the letter A. for abfolvo ; C. for condemno ; and N. L. for non liquefy Calcali;; winds, would not fail till Agamemnon's daughter had fignifying that a more full information was required been facrificed to Diana. After the taking of Troy, Culculus is alfo ufed in ancient grammatic writers he retired to Colophon ; whei-c, it is faid, he died of for a kind of weight equal to two grains of cicer. grief, becaufe he could not divine what another of his Some make it equivalent to the fdiqua, \vhich is equal profeflion, called Mopfus, had dilcovered. to three grains of barley. Two calculi made the ce- CALCINATION, in chemiftry, the reducing of ratium. fubitances to a calx by ftre. See CHSMisrRr-Index. dicuius Dtfferentialls is a method of differencing CALCINATO, a town of Italy, in the duchy of quantities, or of finding an infinitely fmall quantity, ^tlantua, remarkabk for a victory gained over the Im- which, being taken infinite times, fliall be equal to a pcrialiils by the French iii 1 706. E. Long. 9. 55. given (quantity : or, it is the arithmetic of the infinite- iS'. Lat. 45. 25. iy fmall differences of variable quantities. CALCULARY cf a Pear, a congeries of little The foundation of this calculus is an infinitely ih-!ing knots difperfed through the whole parenchyma fmall quantity, or an infinitefimal, which is a portion of the fruit. The calculary is molt obferved in rough- of a quantity incomparable to that quantity, or that tarted or choak-pears. The knots lie more continu- is lefs than any afiignable one, and therefore account- oiis and compact together towards the pear where they ed as nothing; the error accruing by omitting it beings fuiTound the acetary. About tlie Italk they Hand lefs than any affignable one. Hence two quantities. more diltant ; but towards the cork, or ftool of the flower, they It ill grow clofer, and there at laft gather into the firmnefs of a plumb-Hone. The calculary is fto vital or effential part of the fruit ; the feveral knots whereof it confiils being only fo many concretions or precipitations out of the fap, as we fee in urines, wines, and other liquors. CALCULATION, the aft of computing feveral films, by adding, fubtrafting, multiplying, or divi- ding. See Arithmetic. Calculation is more particularly ufed to fignify the computations in allronomy and geometry, for ma- king tables of logarithms, ephemerides, finding the time of eclipfes, Sec. See Astronomv, Geometry, and Logarithms. CALCULUS, primarily denotes a little ftone or only differing by an infinitefimal, are reputed equal. Thus, in Aftronomy, the diameter of the earth is an infinitefimal, in refpedt of the diftance of the fixed ftars ; and the fame holds in abftraft quantities. The term, infinitefimal, therefore, is merely refpedlive, and involves a relation to another quantity ; and does not denote any real ens, or being. Now infinitefimals are called differentials, or differential quantities^ when they are coniidered as the differences of two quantities. Sir Ifaac Newton calls them moments ; confidering them as the momentary increments of quantities, v. g. of a line generated by the flux of a point, or of a furfuce by the flux of a fine. The differential calculus, there- fore, and the doftrine of fluxions, are the fame thing under diftcrent names ; the former given by M. Leib- nitz, and the latter bv Sir Ifaac Newton : each of pebble, anciently ufed in making computations^ taking whom lay claim to the difcovery. There is, indeed, 3; of fuffrages, playing at tables, and the like. In after times, pieces of ivory, and counters ftruck of filver» gold, and other matters, were ufed in lieu thereof, but ftill retaining th~e ancient names. Coraputifts were by the lawyers called calculories, when they were either difference in the manner of expreffing the quantities^ refulting from, the different views wherein the two au- thors confider the infinitefimals ; the one as moments,, the otlier as differences : Leibnitz, and moil foreigners, exprefs the differentials ©f quantities by the fame let- /laves or newly freed men ; thofe of a better condition, ters as variable ones, only prefixing the letter d : llms the differential of x is called d x ; and tliat o£ dy : now dx is a pofitive quantity, if .v continually increafe; negatlve,if it d'ecreafe. The Englilh, with Sir Ifaac New- ton, inftead of jc write x (with a dot o\er it ;) {ovdy,yy 6cc. which foreigners objeft againft, on account of that coafufion of points, which they imagine arifes when differentials are again differen'jed ; befides, that the printers ai-e more apt to overlook a point than a letter. Stable quantities being always expreffed by the firft let— ters of the alphabet d a~o, dh'=.Q, dc—o ; wherefore d (.v-f-j — a) zzz d x-\-d y, and d [x — J-f-^^) d x — d y. So that the differencing of quantities is eafily performed, by the addition or fubtraftion of their compounds. To difference quantities, that multiply each, other ; the rule is, firft, multiply the differential, of one fedtcr into the other faftor, the fum of the two faftors is the differential fought : thus, the quantities being x the dif. were named calculutores or numerarii : ordinarily there was one of thefe in each family of diftinftion. The Roman judges anciently gave their opinions by calculi, which were white for abfolution, and black for con- demnation. Hence calculus albus, in ancient writers, denotes a favourable vate, either it» a perfon to be ab- folved and acquitted of a charge, or elected to fome dignity or poft ; as calculus niger did the contraty. This ufage is faid to have been borrowed from the Thraci- ans, who marked their happy or profperous days by uuhite, and their unhappy by blacky pebbles, put each night into an urn. Befides the diverfity of coh)ur, there were fome cal- culi alfo which had figures or characters engraven on them, as thofe which were in ufe in taking the fuffra- ges both in the fenate and at affemblies of the people. Thefe calculi were made of thin wood, poliihtd and C A L C 30 ] GAL tjalcu'ius. differential will be x dy-\-y d Xy i. e. d {^y) z:zx d y-^ry ^■"""V^"^ d X. Secondly, if there be three quantities mutually multiplying each other, the faftum of the two muft then be multiplied into the differential of the third : thus fuppofe vxy, let n) x~t, then 'vxy—ty; confe- quently d [v xy) dy-\-y dt: but d t—v d x-\-x d u. Thefe values, therefore, being fubllituted in the ante- cedent differential, tdy-\-ydt, the refult is, d (vxy) ~v X dy-^-vy d x-\-xy dv. Hence it is eafy to appre- hend how to proceed, where the quantities are more than three. If one variable quantity increafe, while the other J decreafes, it is evident ^/oc — xdywWlhe the differential of xy. To difference quantities that mutually divide each other ; the rule is, firft, multiply the diflFerential of the dlvifor into the dividend ; and, on the contrary, the differential of the dividend into the divifor ; fubtraft the lafl produft from the firfl, and divide the remain- der by the fquare of the divifor ; the quotient is the differential of the quantities mutually dividing each other. See Fluxions. Calculus Exponent talis , is a method of differencing exponential quantities, or of finding and fiimming up the differentials or moments of exponential quan- tities ; or at leafl bringing them to geometrical con- llruftions. By exponential quantity, is here underftood a power, whofe exponent is variable ; v. g. x^ a^. x^. where the exponent x does not denote the fame in all the points of a curve, but in fome ftands for 2, in others for 3, in others for 5, &c. To difference an exponential quantity ; there is no- thing required but to reduce the exponential quantities to logarithmic ones ; which done, the differencing is managed as in logarithmic quantities. — Thus, fuppofe the differential of the exponential quantity x^f re- ■quired, let Then will y I x—I >. ydx / JC « v-l %lx dy\- -'=d 21 That is, Ix dy-\-x^ ' d x~d z. Calculus Integralis, or Summatorius, is a method of integrating, or fumming up moments, or differential quantities ; i. e. from a differential quantity given, to find the quantity from whofe differencing the given differential refults. The integi-al calculus, therefore, is the inverfe of the differential one : whence the Enghfh, who ufually call the differential method fluxions^ give this calculus., which afcends from the fluxions, to the flowing or va- riable quantities : or, as foreigners exprefs it, from the differences to the fums, by the name of the inverfe me- thod of fiuxiotis. Hence, the integration is known to be juflly per- formed, if the quantity found, according to the rules of the differential calculus, being differenced, produce that propofed to be fummed. jSuppofe / the fign of the fum, or integral quantity, then fydx will denote the fum, or integral of the dif- Ca.Icw!tn. ferential ydx. ^r"^ To integrate, or fum tip a differential quantity : It h demonftrated, firft, that fdx-=x; fecondly,y'(r/x-J-i/j') z=.x-\-y : thirdly,/ [x d y-\-y d x)—x y : fourthly, / (w n — m n X™ — ^ dx—xm: fifthly, f (n : m) x dx'=x • fixthly, f {yd X — X dy) : y'^—x :y. Of thefe, the fourth and fifth cafes are the moft frequent, wherein the dif- ferential quantity is integrated, by adding a variable unity to the exponent, and dividing the fum by the new exponent multiplied into the differential of the root; v. g. the fourth cafe, by m — (i + i) dx, i. e. by m d X. If the differential quantity to be integrated doth not come under any of thefe formulas, it mufl either be reduced to an integral finite, or an infinite feries, each of whofe terms may be fummed. It may be here obferved, that, as in the analyfis of finites, any quantity may be raifed to any degree of power ; but "vice verfa, the root cannot be extrafted out of any number required : fo in the analyfis of infinites, any variable or flowing quantity may be dif- ferenced ; but vice verfa, any differential cannot be in- tegrated. And as, in the analyfis of finites, we ai-e not yet arrived at a method of extra£ting the roots of all equations, fo neither has the integral calculus arrived at its perfeftion : and as in the former we are obliged to have recourfe to approximation, fo in the latter we have recourfe to infinite feries, where we cannot at- tain to a perfect integration. Calculus Literalis, or Literal Calculus, is the fame with fpecious arithmetic, or algebra, fo called from its ufing the letters of the alphabet ; in contradiflinAion to numeral arithmetic, which ufes figures. In the li- teral calculus given quantities are expreffed by the firfl letters, abed; and quantities fought by the lafl z &c. Equal quantities are denoted by the fame letters. Calculus Minerva, among the ancient lawyers, de- noted the decifion of a caufe, wherein the judges were equally divided. The expreffion is taken from the hi- ftory of Oreftes, reprefented by ^fchylus and Euripi- des ; at whofe trial, before the Areopagites, for the murder of his mother, the votes being equally divided for and againfl him, Minerva interpofed, and gave the cafting vote or calculus in his behalf. M. Cramer, profeffor at Marpurg, has a difcourfe exprefs, De Calculo Minerva; wherein he maintains, ' that all the effeft an entire equality of voices can have, is to leave the caufe in Jlatu quo. Calculus Tihtirtinus, a fort of figured ilone, formed in great plenty about the cataradls of the Anio, and other rivers in Italy ; of a white colour, and in fhape oblong, round, or echinated. They are a fpecies of the Jlirite lapidcte, and generated like them ; and fo like fugar-plums in the whole, that it is a common jeft at Rome to deceive the unexperienced by ferving them up at deferts. Calculus, in Medicine, the difeafe of the ftone in the bladder, or kidneys. The term is Latin, and fig- nifies a little peBble. The calculus in the bladder is called Uthiafis ; and in the kidneys, nephritis. See Me- dicine and Surgery. Human calculi are commonly farmed of different ftrata C A L ftraita or Incrufiatlons ; fometimes fmooth and heavy ' likie mineral ftones ; hut oftcner rough, fpongy, light, an without water, people were brought to a profufe fwcati In which fenfe, caldarium was the fame with what was otherwife denominated vaporarium, fudatorlum, and laconium; in the Greek baths, hypocaujlum, t^^oxaurov. CALDERINUS (Domltius), a learned critic, born at Calderia near Verona. He read ledlures upon polite literature at Rome with great reputation ; and was the firft who ventured to write upon the moft difficult of the ancient poets. He died very young in 1477. CALDERON, De la Barca, (Dom. Pedro), a Spanifh officer, who, after having fignalized himfelf in the mlHtary profeffion, quitted it for the ecclefiaftical, and then commenced dramatic writer. His dramatic works make 9 vols in 4to, and fome Spanifh authors have compared him to Shakefpeare. He fiourifhed a* bout the year 1640. CALDERWOOD (David), a famous divine of the church of Scotland, and a diftlnguifhed writer i« behalf of the Prefbyterians, was defcended of a good family in that kingdom; and being early defigned for the miniflry, he applied with great diligence to the ftudy of the Scriptures in their original tongues, the works of the fathers, the councils, and the befl wri^ ters on church-hiftory. He was fettled about the year 1604 at Crelling near Jedburgh. King James I. of Great Britain, being defirous of bringing the church of Scotland nearer to a conformity with that of Eng- land, laboured earneftly to reflore the epifcopal autho- rity, and enlarge the powers of the bifhops who were then in Scotknd. This defign was very warmly oppo- fed by many of the minifters, and particularly by Mr David Calderwood ; who, when Mr James Law, hi- fhop of Orkney, came to vifit the prefbyterles of Merfe and Teviotdale, declined his jurifdiftion by a paper under his hand dated May 5th 1 608. But the king ha- ving Its fuccefs much at heart, fent the earl of Dunbar, then high-treafurer of Scotland, with Dr Abbot after- wards archbilhop of Canterbury, and two other divines, into that kingdom, wath inftruftions to employ every method to perfuade both the clergy and laity of his majefty's fincere defire to promote the good of the church, and of his zeal for the Proteftant rehglon. Mr Calderwood did not affill; at the general affembly held at -Glafgow June 8th 1610, in which lord Duh- E bar C A L [ 34 ] C A L Caldcr- bar prefided as commllfioner ; and it appears from his his offence, nor promife conformity for the future, he Caldr wood, writings, that he looked upon every thing tranfaded retired to Holland, where, in 1623, he publifhed his II in it as null and void. In May following, king James celebrated piece entitled Altare Damafcenum. Mr Cal- '^"'"^ went to Scotland ; and 6n the 17th of June held a par- dei-wood having in the year 1624 been afflifted with liament at Edinburgh : at that time the clergy met in a long fit of ficknefs, and nothing having been heard one of the churches, to hear and advife with the bi- of him for fome time, one Mr Patrick Scot, as Cal- fliops ; which kind of affembly, it feems, was contri- derwood himfelf informs us, took it for granted that ved in order to refemble the EngHfh convocation. Mr he was dead ; and thereupon wrote a recantation in his Calderwood was prefent at it, but declared publicly name, as if, before his deceafe, he had changed his- that he did not take any fuch meetings to refemble a fentiments. This impofture being detedled, Scot went convocation ; and being oppoied by Dr Whitford and over to Holland, and ftaid three weeks at Amfterdam, Dr Hamilton, who were friends to the bifhops, he took where he made a diligent fearch for the author of Al- ius leave of them in thefe words : " It is abfurd to fee tare Damafcenum, with a defign to have difpatched men fitting in filks and fattins, and to cry poverty in him. But Calderwood had privately retii-ed into his the kirk, when purity is departing." The parliament ovvn country, where he lived feveral years. Scot gave proceeded in the mean while in the difpatch of bufinefs; out that the kinor had furnifhed him with the matter and Mr Calderwood, with feveral other minifters, be- for the pretended recantation, and that he only put it ing informed that a bill was depending to empower the in order. During his retirement, Mr Calderwood col- king, with the advice of the archbifliops, biihops, and lefttd all the memorials relating to the ecclefiaftical af- fuch a number of the miniftry as his Majefty fhould fairs of Scotland, from the beginning of the reforma- think proper, to confider and conclude as to matters tion there down to the death of king James ; which decent for the external poHcy of the church, not re- colleftioa is ilill preferved in the univerfity library of pugnant to the word of God ; and that fuch conclu- Glafgow ; that which was publifhed under the title of fious fhould have the ttrength and power of ecclefiafti- " The true hiilory of Scotland," is only an extraft cal laws : againft tliis they protefted, for four reafons. from it. In the advertifement prefixed to the lart edi- 1 . Becaufe their church was fo perfed, that, inftead tion of his Altare Damafcenum mention is made of his of needing reformation, it might be a pattern to others, being minifler of Pencaitland near Edinburgh in 1 638 ; 2. General affemblies, as now eftablifhed by law, and but we find nothing faid there, or any where elfe, of his •which ought always to continue, might by this means death. be overthrown. 3. Becaufe it might be a means of CALDRON, a large kitchen iitenfil, commonly- creating fchifm,- and difliirb the tranquillity of the made of copper ; having a moveable iron handle, where- church. 4. Becaufe they had received affurances, that by to hang it on the chimney-hook. The word is no attempts fiiould be made to bring them to a confor- formed from the chaudron^ or rather the Latiij mity with the church of England. They defired there- caldarlum. fore, that, for thefe and other reafons, all thoughts of Boiling In Cjldrons^ (caMariis decoquere ), is a capl- pafllng fuch a lav/ might be laid afide : but in cafe this tal puniihment fpoken of in the middle-age writers, l)e not done, they proteft for themfelves and their bre- decreed to divers foi-ts of criminals, but chiefly to de- thren who fhall adhere to them, that they can yield no bafers of the coin. One of the torments infli6led on obedience to this law when it fhall be enaded, becaufe the ancient Chriilian martyrs, was boiling in caldrons . it is deftruAive of the liberty of the church ; and there- of water, oil, &c. fore fhall fubmit to fuch penalties, and think themfelves CALDWALL (Richard), a learned Englifh phy-- oblige.d to undergo fuch punifliments, as may be inflic- fician, born in StafFordfhire about the year 151 3. He. ted on them for difobeying that law. This proteft iludied phyfic in Brazen-Nofe college Oxford ; and was figned by Mr Archibald Simfon on behalf of the was examined, admitted unto, and made cenfor of, the members who fubfcribed another feparate roll, which college of phyficians at London, all in one day. Six he kept for his juftification. This protefl was prefent- v/eeks after he was chofen one of the elects ; and in the ed to the clerk regifter, who refufed to read it before year 1570, was made prefident of that college. Mr the ilates in parliament. However, though not read, W ood tells us, that he v/rote feveral pieces in his pro-- it had its efFe£l ; for although the bill had the confent fefiion ; but he does not tell iis what they v/cre, only of parliament, yet the king thought fit to caufe it to be that he tranflated a book on the art of furgcry, written laid afide, and not long after called a general affembly by one Huratio More, a Florentine phyfician. We at St Andrew's. Soon after the parliament was dif- learn from Cambden, that Caldwall founded a chirurgi- folved, and Mr Calderwood v/is fummoned to appear cal'lefture in the college of phyficiang, and endovired it before the high-commiiTion court at St Andrew's, on with a handfome falary. He died in 1585. the 8th of July foUov/ing, to anfwer for his muti- CALEA, in botany : A genus of the polygamia nous and fcditlous behaviour. July loth, the king a;quahs order, belonging to the fyngenefia clafs of' came t-o that city in perfon ; when Mr Calderwood, be- plants ; and in the natural method ranking under the ing called upoji, and refufing to comply v/ith what the 49th order, Comprjfiix. The receptacle is paleaceous, king in perfon required of him, was committed to prifon, the pappus hairy, and the calyx imbricated. Afterwards the privy council, according to the power CALEB, one of the deputies fent by the Ifraelites exercifed by them at that time, direded him to ba- to take a view of the land of Canaan. He made a nifh hi nr\fclf out of the king's dominions before Michael- good report of the country, and by this means revived mas next; and not to return without hcence. Having the fpirits of the dejefted people ; on which account, apphed to the king for a prorogation of his fentence he and Jofhua were the only perfons who, after their without fuccefsj becaufe he would neither, acknowledge leaving Egypt, fettled in the land of Canaan. Caleb C A L C 35 ] C A L had, for his fliare, the mountains and the city of He- bron, from which he drove three kings. Othoniel his nephew having taken the city of Debir, Caleb gave him his daughter Achfah in marriage ; and died, aged 1 14. CALEDONIA, the ancient name of Scotland. From the teftimonies of Tacitus, Dio, and Solinus, we find, that the ancient Caledonia comprehended all that country lying to the north of the rivers Forth and Clyde.' In propox-ticn as the "^ilures or Cinibri advan- ced towards the north, the Caledonians, being circum- fcribed within narrower hmits, were forced to tranf- migrate into the idands which crowd the weftern coails of Scotland. It is in this period, probably, we ought to place the firft great migration of the Eriti!h Gael into Ireland ; that kingdom being much nearer to the promontory of Galloway and Cantire, than many of the Scottifh ifles are to the continent of North Bri- tain. To the country which the Caledonians pofleiTed, they gave the name of Cael-doch; which is the only ap- pellation the Scots, who fpeak the Gaelic language, know for their own divifion of Britain. Cael-doch is a compound, made up of Gael or Ca'el, the firft color ny of the ancient Gauls who tranfmigrated into Bri- tain, and doch, a diilrift or divifion of a country. I'he Romans, by tranfpofing the letter / in Cael, and by foftening into a Latin termination the ch of doch, formed the well known name of Caledonia. When the tribes of North Britain were attacked by the Romans, they entered into affociations, tliat, by u- niting their ftrength, they might be more able to re- pel the common enemy. The particular name of that tribe, which either its fuperior power or military repu- tation placed at the head of the affociation, was the general name given by the Romans to all the confede- rates. Hence it is that the Mmata, who with other tribes inhabited the diftrids of Scotland lying fouth- ward of the frith, and the Caledonians, who inhabited the weft and north-weft parts, have engroffed all the glory which belonged in common, though in an infe- rior deq:ree, to all the other nations fettled of old in North Britain. It was for the fame reafon that |the name of Mccata was entirely forgotten by foreign wri- ters after the third century, and that of the Caledonians themifelves but feldom mentioned after the fourth. Britons, Caledonians, Mceattz, Barbarians, are the names conftantly given to the old inhabitants of North Britain, by Tacitus, Herodian, Dio, Spartian, Vopif- cus, and other ancient writers. The fucceifors of thefe Britons, Caledonians, Mceats, and Barbarians, are cal- led Pifts, Scots, and Attacots, by fome Roman wri- ters of the fourth century. I'he origin of the appellation Scot! and Pi8i, intro- Tluced by latter Roman authors, has occafioned much ■controverfy among the antiquarians of thefe days. The difpute feems now to be fully decided by fome learned critics of the prefent century, whofe knowledge of the Gaelic language aflifted their inveftigation. See Scotland, Picts, and Highlanders. Caledonia, the name of a fettlement made by the 'Scots on the weft fide of the gulph of Darien, in 1 698 ; out of which they were ftarved at the requeft of the Eaft-India company : for the Englilh government pro- hibited the other colonies fending them any prOvIfions; Calecioftia. fo they were obliged to leave it in 1 700. * ' " Neiv Calf.vonia, an ifland in the fouth-fea, lately difcovered by captain Cook, and, next to New Hol- land and New Zealand, is the largeft ifland that hath yet been difcovered ii) that fea. It extends from 19* 37. to 22. 30. S. Lat. and from 163. 37. to 167. 14. E. Long. Its length from north-weft to fouth-eaft is about 80 leagues; but its greateft breadth does not ex- ceed ten leagues. This idand is diverfifiedby hills and valleys of various fize and extent. From the hills ifhie abundance of rivulets, wliich contribute to fertilize the plains. Along its nor' h-eaft fhore the land is flat ; and being well watered, ;u.d cultivated by the inhabitants after their manner, i.'^peared to great advantage to cap* tain Cook's people. Was it not, indeed, for thofe fertile fpots on the plains, the whole country might be called a dreary avajie : the mountains and higher parts of the land are in general incapable of cultivation. They confift chiefly of rocks, many of which are full 6f mundic ; the httle foil that is upon them is fcorched and burnt. up by the fun ; it is, however, Covered with coarfe grafs and other plants, and here and there co- vered with trees and fiirubs. The country in general bears a great refemblance to thofe parts of New South Wales wliich lie under the fame parallel of hititude. Several of its natural prod aftions are the fame, and the woods are without underwood as well as in that coun- tiy. The whole coaft feems to be furrounded by - reefs and flaoals, which render all accefs to it extreme- ly dangerous ; but at the fame time guard the coafts againft the attaeks of the wind and fea ; rendering it eafily navigable along the coaft by canoes, and caufin^ it abound with fi{h. Every part of the coaft feems to be inhabited ; the plantations in the plains are laid out with great judgment, and cultivated with much labour. They begin their cultivation by fetting fire to the grafs, &c. with which the ground is covered, but have no notion of preferving its vigour by manure ; they, how- ever, recruit it byletting it lie for fome years untouched. On the beach was found a large irregular mafs of rock, not lefs than a cube of ten feet, confifting of a clofe- grained ftone fpeckled full of granates fomewhat bigger than pins heads, from whence it feems probable that fome valuable minerals may be found on this ifland. It differs from all the other iflands yet difcovered in the South Sea, by being entirely deftitute of volcanic pro- ductions. Several plants of a new fpecies were found hci'e ; and a few young i readfruit trees, not then fuf- ficiently grown to bear fruit, feemed to have come up without culture : plantains and fugar-canes are here in fmall-quantity, and the cocoa-nut trees are fmall and thinly planted. A new fpecies of pafiion-flower was hkewife met with, which was never known to grow wild any where but in America. Several Capuft (jMe- LALEUCA ) trees were alfo found in flower. Mufquetos here are very numerous. A great variety of birds were feen of different clafles, which were for the moft part entirely new ; particularly^ a beautiful fpecies of par- rot before unknown to zoologifts. A new fpecies of fiih, of the genus called by Linnaeus tetraodbn, was caught here ; and its liver, v.-hich was very large, pre- fented at fupper. Several fpecies of this genus being reckoned poifonous, and the prefent fpecies being re- E 2 mark ably C A L C 36 ] C A L Caledonia.^ markably ugly, Meff. Forfters hinted tlieir fufpicions *~"'V"'~^ of its quality ; but the temptation of a fredi meal, and the affurances of captain Cook that he had foi-merly eaten this identical fort of fifli without harm, got the better of tlieir fcruples, and they eat of it. Its oili- nefs, however, though it had no other bad talle than what proceeded from this, prevented them from taking more than a morfel or two. In a few hours after they had retired to reft, they were awakened by very alarm- ing fymptoms, being all feized with an extreme giddi- nefs ; their hands and feet were numbed, fo that they were fcarcely able to crawl ; and a violent langour and opprt'ffion feized them. Emetics -were adminiftered Vv ith fome fuccefs, but fudorifics gave the greatell re- lief. Some dogs who had eaten the remainder of the liver were likewife taken ill ; and a pig which had eaten the entrails died foon after, having fwelled to an un- ufual fize. The effects of this poifon on the gentle- men did not go entirely off in lefs than fix weeks. — • Abundance of turtle was feen here. The natives had not the leaft notion of goats, hogs, dogs, or cats, and had not even a name for any of them. The inhabitants are very flout, tall, and in genei-al well proportioned; their features mild; their beards and hair black, and ftrongly frizzled, fo as to ba fomewhat woolly in fome individuals ; their colour is fwarthy, or a dark chefnut brown. A few were feea who meafured fix feet four inches. They are remark- ably courteous, not at all addifted to pilfering and ftealing ; in which charafter of honefty they are fin- gular, all the other nations in the South Sea being re- markably thievifh. Some wear their hair long, and tie it up to the crown of their heads ; others fufFer only a large lock to grow on each fide, which they tie up in clubs ; many others, as well as all the women, wear it cropt fhort. They make ufe of a kind of comb made of fticks of hard wood, from feven to nine or ten inches long, and about the thicknefs of knitting needles ; a number of thefe, feldom exceeding 20, but generally fewer, are fattened together at one end, parallel to and near one tenth of an inch from each other ; the ends, which are a little pointed, will fpread out or open hke the fticks of a fan. Thefe combs they always wear in their hair on one fide of their head. Some had a kind of concave cylindrical MS black cap, which appeared to be a great ornament among them, and was fuppofed to be worn only by the chiefs and warriors. A large Jheet of ftrong paper, whenever they got one in ex- change,, was commonly appHed to this purpofe. The men go naked ; only tying a ftring round their middle, and another round their neck. A little piece of a brown cloth made of the bark of a fig-tree, fometimes tucked up to the belt, and fometimes pendulous, fcarcely deferves the name of a covering ; nor indeed does it feem at all intended for that purpofe. This piece of cloth is fometimes of fuch a length, that the extremity is faftened to the ftring round the neck ; to this ftring they likewife hang fmall round beads of a pale green nephritic ftone. Coarfe garments were feen among them, made of a fort of matting ; but they feemed never to wear them, except when in their ca- noes and unemployed. The wonjen feemed to be in a fervile ftate : they were the only perfons of the family who had any employment, and feveral of them brought bundles of fticks and fuel on tlieir back : thofe who had children carried them on their backs in a kind of Calefloni*. fatchel. The women alfo were feen to dig up the earth v in order to plant it. They are in general of a dark chefnut, and fometimes mahogany brown ; their fta- ture middle-fized, fome being rather tall, and their whole form rather ftout, and fomewhat clum.fy. Their drefs is the moft disfiguring that can be imagined, and gives them a thick fquat fiiape ; it is a fiiort petticoat or fringe, confifting of filaments or little cords, about eight inches long, wh.ta are fattened to u very long ftring, which they have tied feveral times round their waitt. The filaments, or little ropes, therefore, lie a- bove each other in feveral layers, forming a kind of thick thatch all round the body, but which does not near cover the thigh : thefe filaments were fometimes dyed black ; but frequently thofe on the outfide only were of that colour, the reft being of a dirty grey. There was not a fingle inttance, during the ttiip's ftay in this ifland, of the women permitting any indecent familiarity with an European : they took pleafure in practifing the arts of a jilting coquette, but never be- came abfolute wantons. The general ornam-ents of both fexes are ear-rings o£ tortoife fhells ; necklaces, or amu- lets, made both of ttiells and ftones; and bracelets made of large fliells, which they wear above the elbows. The houies, or huts, in New Caledonia, are circu- lar, fomething like a bee-hive, and full as clofe and warm ; the entrance is by a fmall door, or long fquare hole, juft big enough to admit a man bent double: the fide-walls are about four feet and a half high; but the roof is lofty, and peaked to a point at the top, a- bove which is a pott or ftick of wood, which is gene- rally ornamented either with carving or fliells, or both. The framing is of fmall fpars, reeds, &c. and both fides and roof are thick, and clofe covered with thatch made of coarfe long grafs. In the infide of the houfe are fet up pofts, to which crofs fpars are faften- ed, and platforms made, for the conveniency of laying any thing on. Some houfes have two floors, one above another; the floor is laid with dried grafs, and here and there mats are fpread for the principal people to fit or fleep on. In thefe houfes there was no paflage for the fmoke but through the door; they were intolerably fmoky, and fo hot as to be infupportable to. thofe unaccuftomed to them : probably the fmoke is intend- ed to drive out the mufquetos which fwarm here. They commonly eredt two or three of thefe huts near each other under a clufter of lofty fig-trees, whofe leaves are impervious to the rays of the fun. The canoes ufed here are very heavy clumfy veflels ; they are made of two trees hollowed out, having a raifed gunnel about two inches high, and clofed at each end with a bulk head of the fame height ; fo that the whole is like a long fquare trough about three feet ftiorter than the body of the canoe. Two canoes thus fitted are faftened to each other about three feet afun- der, by means of crofs-fpars, which projed about a foot over each fide. Over thefe is laid a deck or heavy platform made of plank and fmall round fpars, on which they have a fire-hearth, and generally a fire burning ; they are navigated by one or two latteen fails, extended to a fmall latteen yard, the end of which is fixed in a notch or hole in the deck. Notwithftanding the inoffenfive difpofition of the inr habitants of New Caledonia, they are well provided witli. C A L [ 37 ] C A L Caledonia with offenfive weapons ; as clubs, fpears, darts, and „ , fling-s for throwine: ftones. Their clubs are about two ■ ^ I ' feet and an half long, and varioufly formed ; fome like a fcythe, others like a pick-ax ; fome have a head like a hawk, and others have round heads ; but all are neatly made ; many of their darts and fpears are no lefs neat, and ornamented with carvings. The flings are as fimple as polTible ; but tliey take fome pains to form the {tones that they ufe into a proper lhape, which is fomething like an egg, fuppofing both ends to be like the fmall one. They drive the dart by the af- fiftance of fliort cords knobbed at one end and looped at the other, called by the ieamen beckets. Thefe contain a quantity of red wool taken from the vam- pyre, or great Indian bat. -Bows and arrows are wholly unknown among them. Their language bears no affinity to that fpoken in the other South-fea iHands, the word arrekee and one or two more excepted. This is the more extra- ordinaiy, as different dialects of one language were fpoken not only in the eafterly iflands, but at New Zealand. A mufical inflrument, a kind of whiflle, was procu- red here. It was a little pollfhed piece of brown wood about two inches long, fhaped hke a kind of bell, tho' apparently folid, with a rope fixed at the fmall end ; two holes were made in it near the bafe, and another near the infertion of the rope, all which communicated with each other ; and by blowing in the uppermoft, a fhrill found like whiflling was produced : no other in- flrument was feen among them that had the leail re- lation to mufic. Many of the New Caledonians were feen with pro- digioufly thick legs and arms, which feemed to be af- fefted with a kind of leprofy ; the fwelling was found to be extremely hard, but the fliln was not alike harfh and fcaly in all thofe who were afHicled with the difor- der. The preternatural expanfion of the arm or leg did not appear to be a great inconvenience to thofe who fuffered it ; and they feemed to intimate that they very rarely felt any pain in it ; but in fome the diforder began to form blotches, which are marks of a great de- gree of virulence. Here they bury their dead in the ground. The grave of a chief who had been flain in battle here re- fembled a large mole-hill, and was decorated with fpears, darts, paddles, &c. all ftuck upright in the ground round about it. Lieutenant Pickerfgill was^ fhowed a chief whom they named Tea-booma, and fly- led thtir arrekee or king; but nothing further is known of their government, and nothing at all of their reli- gion. CALEFACTION, the produftion of heat in a body from the a£lion of fire, or that impulfe impref- fed by a hot body on others around it. This word is ufed in pharmacy, by way of diilindlion from coiiion, which implies boiling; whereas calefadlion is only heat- ing a thing. CALENBERG, a caftle of Germany, in the duchy of Brunfwic and principality of Calenberg. It is feated on the river Leine, and is 1 5 miles fouth of Hanover. It is fubjeft to the duke of Brunfwic Lunenburg, elec- tor of Hanover, and king of Great Britain. E. Long, y. 43. N. Lat. 52. 20. CalenberG; a principality of Lower Saxony, and Calenders. one of the three parts of the duchy of Brunfwic, is Calendar bounded on the north by the duchy of Verden, on the eafl by the principality of Zell, on the fouth by the principalities of Grubenhagen and Wolfenbuttle, and on the well by Wellphalia. It belongs to the ele£lor of Hanover. CALENDAR, in aftronomy and chronology. See Kalendar. Calendar of prifoners, in law, a lift of all the pri- foners names in the cuilody of each refpeftive fheriff*. • Seethe CALEND ARIUM Flor^, in botany, a calendar article j containing an exa6t regiller of the refpeftive times {ri^'^"^""' ' which the plants of any given province or chmate ger- minate, expand, and fhed their leaves and flowers, or ripen and diiperfe their feeds. For particulars on this curious fubjedl, fee the articles Defoliatio, Efflo- REscENTiA, Frondescentia, Fru cth scenti A, and Germinatio. CALENDER, a machine ufed in manufaftories to prefs certain woollen and filken fluffs and linens, to- make them fmooth, even, and gloffy, or to give them waves, or water them, as may be feen in Mohairs and tabbies. This inflrument is compofed of two thick cylinders or rollers, of very hard and well polifhed wood, round which the fluffs to be calendered are wound : thefe rollers are placed crofs-wife between two vety thick boards, the lower ferving as a fixed bafe, and the upper moveable by means of a thick fcrew with a rope fattened to a fpindle which makes its axis : the uppermoft board is loaded with large ftones weighing 20,ooolb. or more. At J*aris they have an extraordi- nary machine of this kind, called the royal calender^ made by order of M. Colbert. The lower table or plank is made of a block of fmooth marble, and the upper is lined- with a plate of polifhed copper. — The alternate motion of the upper board fometimes one way and'- fometimes another, together with the prodigious weight laid upon it, gives the fluffs their glofs and fmoothnefs or gives them the waves, by making the cylinders on which they are put roll with great force over the un- dermoft board. When they would put a roller from under the calender, they only incline the undermoft board of the machine. The dreffing alone, with the many turns they make the ftuffs and linens undergo in the calender, gives the waves, or waters them, as the workmen call it. Ic is a miftake to think, as fome have afferted, and Mr Chambers among others, that, they ufe rollers with a fhallow indenture or engraving cut into them. CALENDER of Monteith, a diftridl in the fouth-weft corner of Perthfhire in Scotland, from which a branch of the ancient family of Livingften had the title of Earl. The chief feat of the family near Fal- kirk is alfo called Calender.- Both eflate and title were forfeited' for being engaged in the rebellion 1715. CALENDERS, a fort of Mahometan friars, fo call- ed f rom Santon Calender! their founder. This Santon went bare-headed, without a fhirt, and with the flcin of a wild beaft thrown over his fhoulders. He wore a kind of apron before, the ftrings of which were adorn- ed with counterfeit precious ftonesi His difciples are rather a fe£t of Epicureans than a fociety of rcligiousk They honour a tavern as much as they do a mofquc j and think they pay as aeceptable worlhip to God b-jj the. C A L Calends the free ufe of his creatures, as others do by the great- 'I eft aufterities and afts of devotion. They are called, in [ 38 ] C A L Ciilenture. Perfn and Arabia, Ahdals, or AbMlat, i. e. perfons confecvated to the honour and fervice of God. Their garment is a fingle coat, made up cf a variety of pie- ces, and quilted like a rug. They preach in the mar- ket- places, and live upon what their auditors beftovir on them. They are generally very vicious perfons ; for which rcafon they are not admitted into any houfes. CALENDS, in Roman antiquity. See Kalends. CALENDULA, theMARicooo: A genus of;j|[ie polygamia neceffaria order, belonging to the fyngehe- fia clafs of plants ; and in the natural method ranking under the 49th order, Comp'Jifa^. The receptacle is naked, there is no pappus, the calyx is polyphyllous and equal, the feeds of the dilic membranaceous. Of this there are eight fpecies, none of them natives of Europe. The common kirfd is fo wf It knovirn ' as to need no definition ; and none of the others merit any, except the fruticofa, which hath lately been introdu- ced from the Cape of Good Hope. It hath a (lender fhrubby perennial ftalk, which rifes to the height of feven or eight feet, but requires fupport : this fends out a great number of weak branches from the bottom to the top, which hang downward unlefs they are fup- ported : they are garnifhed with oval leaves, having ftrort flat footllalks ; thefe are of a fnining green co- lour on their upper fide, but paler underneath : the flowers come out at the end of the branches, on fnort naked footftalks. This is eafdy propagated by cut- tings; which may be planted at any time in fummer in a fliady border, or otherwife fliaded with mats in the heat of the day : in five or fix weeks thefe will have taken root, when they (hould be feparately taken up, each put in a feparate pot, and placed in the fiiade till they have taken frefh root ; then they may be placed, with other hardy exotic plants, in a fheltered fituation, where they may remain till the froft begins, when the)'- muft; be removed into the green-houfe, placing them near the windows, that they may enjoy the free air ; for this plant only requires protection from froft. The feeds of the common fort maybe fown in March or A- pril, where the plants are to remain ; and will require no other culture but to keep them clear of weeds, and to thin the plants where they are too thick. The flowers of the common marigold are fuppofed to be a- perient and attenuating, as alfo cardiac, alexipharmac, and fudorific ; they are principally celebrated in uterine obftruftions, the jaundice, and for throwing out the fmall-pox. Their fenfible qualities, however, give Httle foundation for thefe virtues: they have fcarce any tafte, and have no confiderable fmell. The leaves of the plant difcover a vifcid fweetiflmefs, accompanied with a more durable faponaccous pungency and warmth ; thefe feem capable of anfwering fome ufeful purpofes as a fiimulating, aperient, and antifcorbutic medicine. CALENTIUS (Ehfius), a Neapohtan poet and profe author. He was preceptor to Frederic the fon of Ferdinand king of Naples, and the earlieil writer on the illegality of putting criminals to death, except for murder. He died in 1503. CALENTURE, a feverifh diforder incident to failors in hot countries ; the principal fymptom of which is their imagining the fea to be green fields : •iience, attempting to walk abroad in thefe imaginary places of delight, they are frequently loft. Vomiting* Cafepia bleeding, a fpare diet, and the neutral falts, are re- commended in this diforder ; a fingle vomit commonly j removing the delirium, and the cooling medicines com- pleting the cure. CALEPIN (Ambrofius), an Auguftin monk of Ca- lepio, Avhence he took his name, in the i6th centur}'. He is author of a dictionary of eight languages, fincc augmented by Pafferat and others. CALES (anc. geog.), a municipal city of fome note in Campania, at no great diftance from Cafili- num. The epithet Calenus is. by Horace and Juvenal applied to a generous wine which the ten-itory pro- duced. CALETES (anc. geog.), a people of Gallia Cehi- ca, on the confines of Belgica, fituated between the fea and the Sequana. Now called le Pah ck Caux, in Noi-mandy. ^ CALETURE, a fort on the ifland of Ceylon, at the mouth of a river of the fame name. The Dutch becilme matters of it in 1655 ; but were afterwards ob- hged to leave it. E. Long. 80. 5 1. N. Lat. 6. 38. CALF, in zoology, the young of the ox kind. There are two ways of breeding calves that ai^ in- tended to be reared. The one is to let the calf run , about with its dam all the year round ; which is the method in the cheap breeding countries, and is gene- rally allowed to make the bell cattle. The other is to take them from the dam after they have fucked about a fortnight : they are then to be taught to drink flat milk, which is to be made but juft warm for them, it being very dangerous to give it them too hot. The bcft time of weaning calves is from January to May : they fliould have milk for 12 weeks after; and a fort- night before that is left off, water fliould be mixed with the milk in larger and larger quantities. When the calf has been fed on milk for about a month, little whifps of liay fiiould be placed all about him in cleft fl:icks to induce him to eat. In the beginning of A- pril they firould be turned out to grafs ; only for a few days they fliould be taken in for the night, and have milk and water given them : the fame may alfo be gi- ven them in a pail fometimes in the field, till they are fo able to feed themfelves that they do not regard it. The grafs they are turned into muft not be too rank, but fliort and fweet, that they may like it, and yet get it wath fome labour. Calves fliould always be weaned at grafs ; for if it be done with hay and water, they of- ten grow big-belly'd on it, and are apt to rot. "When thofe among the males are felefted which are to be kept as bulls, the reft fliould be gelt for oxen : the fooner the better. Between 10 and 20 days is a proper age. About London almoft all the calves are fatted for the butcher. The reafon of this is, that there is a good mar- ket for them ; and the lands there are not fo profitable to breed upon as in cheaper countries. The way to- make calves fat and fine is, the keeping them very clean ; giving them frefli litter every day ; and the hanging a large chalk-ftone in fome corner where they can eafily get at it to lick it, but where it is out of the way of being fouled by their dung and urine. The coops are to be placed fo as not to have too much fun upon them, and fo high above the ground that the u- rine may run off. They alfo bleed them once when they are a month old, and a fecond time before they 3 CalF. C A L [ Ikill them ; which is a great addition to the beauty and iwhitenefs of their fiefh : the bleeding is by fonme re- peated much oftener, but this is fufEcient. Calves are wery apt to be loofe in their bowels ; which waftes and wery much injures them. The remedy is to give them tchalk fcraped among milk, pouring it down witli a Uiorn. If this does not fucceed, they give them bole armenic in large dofes, and ufe the cold bath ev^y nnorning. If a cow will not let a ilrange calf fuck her, Ithe common method is to rub both her nofe and the (calf's with a little brandy ; this generally reconciles ithem after a few fmellings. Golden C.1LF, an idol fet up and worfhipped by the Ifraelites at the foot of Mount Sinai in their paffage thi-ough the wlldernefs to the land of Canaan. Our ^verfion makes Aaron faftiion this calf with a graving !tool after he had caft it in a mould : the Geneva tranf- ilation makes him engrave it firft, and caft it afterwards. 'Others, with more probabihty, render the whole verfe ^thus ; '* And Aaron received them {the golden ear- irings), and tied them up in a bag, and got them caft iinto a molten calf;" w^iich verfion is authorifed by the 'different fenfes of the word tzur, which fignifies to tie up or bind, as well as to fliape or form ; and of the word cherret, which is ufed both for a graving tool and a bag. Some of the ancient fathers bave been of 'Opinion that this idol had only the face of a calf, and •the ftiape of a man from the neck downwards, in imi- ^tation of the Egyptian Ifis. Others have thought it was only the head of an ox without a body. But the unoft general opinion is, that it was an entire calf in jimitation of the Apis worftiipped by the Egyptians ; iamong whom, no doubt, the Ifraelites had acquired ttheir propenfity to idolatry. This calf Mofes is faid to Hiave iurnt with JitSy reduced to powder, and ftrewed Tppon the water which the people were to drink. How Tthis could be accompliihed hath been a queftion. Moft people have thought, that as gold is indeftrudlible, it could only be burnt by the miraculous power of God ; ibut M. Stahl conjeficures that Mofes diflblved it by . jneans of liver of fulphur*. The Rabbins tell us that the people were made to drink of this water in order to diftinguifh the idolaters from the reft ; for that as foon .as they had drunk of it, the beards of the former turn- ted red. The cabbahfts add, that- the calf weighed 1 25 quintals ; which they gather from the Hebrew word maffehah, whofe numerical letters make 125. CjLF-Skms, in the leather manufafture, are prepared and dreffed by the tanners, flfinners, and curriers, who fell them for the ufe of the Ihoe-makers, faddlers, book- hinders, and other artificers, who employ them in their feveral raanufa£lures. CAir-Slln drejjed tn fumnchy denotes the flcin of this animal curried black on the hair fide, and dyed of an orange colour on the flefti fide, by means of fumach, . chiefly ufed in the making of belts. The Englifti calf-flcin is much valued abroad, and the commerce thereof very confiderable in France and other countries; where divers attempts have been made to imitate itj but hitherto in vain. What is Uke to biafBe all endeavours for imitating the Englifh calf in France is, the fmallnefs and weaknefs of the calves about Paris ; w^hich at fifteen days old are not fo big as the Englifh ones when they come into the world. SaarCjir. See Pho,ca, . 39 ] c A L CALI, a town of Popayan in South America, feat* ed in a valley of the fame name on the riveV Cauca. The governor of the province ufually refides there. W. Long. 78. 5. N. Lat. 3. 15. CALIBER, or Caliper, properly denotes the dia- meter of any body ; thus we fay, two columns of the fame caliber, the caliber of the bore of a gun, the cali- ber of a bullet, &c. C ALUiKR-CompaJfcs ■> a fort of compaffes made with arched legs to take the diameter of round or fw^elUng bodies. See Compasses. Caliber-compalTes, are chiefly ufed by gunners, for taking the diameters of the feveral parts of a piece of ordnance, or of bombs, bullets, &c. Their legs are therefore circular ; and move on an arch of brafs, v.'here- on is marked the inches and half inches, to fhow how far the points of the compaffes ai-e opened afunder. Some are alfo made for taking the dianleter of the bore of a gun or mortar. The gangers alfo fometimes ufe calibers, to em- brace the two heads of any caflc, in order to find its . length. The calibers ufed by carpenters and joiners, is a piece of board notched triangular-wife in the middle for the taking of meafure. CALiBER-Rukt or Gunner's Cailipers^ is an inftru- • ment wherein a right line is fo divided as that the firft part being equal to the diameter of an iron or leaden . ball of one pound weighty the other parts are to the firft as the diameters of balls of two, three, four, &c. , pounds are to the diameter of a ball of one pound. The caliber is ufed, by engineers, from the weight of the ball given, to determine its diameter or caliber, or vice verfa. The gunner's callipers conlift of two thin plates of ' brafs joined by a rivet, fo as to move quite round each other : its length from the centre of the -joint is be- tween fix iftches and a foot, and its breadth from one to two inches ; that of; the moft convenient fize is . about nine inches long. Many feales, tables, and pro- portions, &c. may be introduced on this inftrument ; but none are effential to it, except thofe for taking the , calibt-r of fhot and cannon, and for meafuring the mag- nitude of faliant and entering angles. The moft com- . plete callipers is exhibited Plate CXII. the fui'niture and ufe of which we fhall now briefly defcribe. Let the four faces of this inftrument be diftinguiflied by the letters A, B, C, D : A and D confift of a circular head and leg; B and C confift only of a leg. On the circular head adjoining to the leg of the face > -A. are divifior.s denominated Jloot diameters ; which , fhow the diftance in inches and tenths of an inch of the points of the callipers when they are opened ; fo that if a ball not exceeding ten inches be introduced be- tween them, the bevil edge E marks its diameter a- mong thefe divifions. On the circular bevil part E of the face B is a fcale • of divifions diftinguifhed by /b. lueight of irm JJjoL , When the diameter of any ftiot is taken between the points of the caUipers, the inner edge of the leg A fhows its weight in avoirdupoife pounds, provided it he lb. 1, I, 2, 3, 4, 5^, 6, 8, 9, 12, 16, 18, 24, 26, ' 32, 36, or 42 ; the figures neareft the bevil edge an-., iwering to the fhort lines in the fcale, and thofe be- hind them £0 the longer ftrokes. This fcale is con- ,furua<;a.- Call",' Calibef, C A L [ 40 1 C A L ll'oer. ftrucled on tlie following geometrical theorem, viz. "V— that the weights of fpheres are as the cubes of their diameters. On the lower part of the circular head of the face A is a fcale of divifions marked liores of guns ; for the ufe of which, the legs of the callipers are flipped acrofs each other, till the fteel points touch the concave fur- face of the gun in its greateft breadth ; then the bevil edge F of the face B will cut a divifion in the fcale fiiowing the diameter of the bore in inches and tenths. Within the fcales of Jhot and bore diameters on the circular part of A, are divifions marlied pounJers : the inner figures 4, i^, j?, sit 8, 12, 18, 26, 36, corre- fpond to the longeft lines ; and the figures i, 2, 4, 6, 9, 16, 24, 32, 42, "to the fliort ftrokes. When the bore of a gun h taken between the points of the calli- pers, the bevil edge F will either cut or be near orte of t'hefe divifions, and fiiow the weight of iron-fiiot pro- per for that gun. On the upper half of the circular head of the face A are three concentric fcales of degrees ; the outer fcale confining of 180 degrees numbered from right to left, to, 20, &c. the middle numbered the contrary way," and the outer fcale beginning ^t the middle with o, and numbered on each fide to 90 degrees. Thefe fcales ferve to take the quantity of an angle, either entering or faliant. For an entering or internal angle, apply the legs of the callipers fo that its outward edges coincide with the legs of the given angle, the degree cut by the bevil edge F in the outer fcale fhows the meafure of the angle fought : for a faliant or external angle, flip the legs of the callipers acrofs each other, fo that their outward edges may coincide with the legs forming the angle, and the degree marked on the middle fcale by the bevil edge E will (how the meafure of the angle required. The inner fcale will ferve to determine the elevation cf cannon and mortars, or of any oblique plane. Let one end of a thread be fixed into the notch on the plate B, and any weight tied to the other end : apply the ftraight fide of the plate A to the fide of the body whofe inclination is fought ; hold it in this pofition, and move the plate B, till the thread falls upon the line near the centre marked Perp. Then will the bevil edge F cut the degrees on the inner fcale, ftiowing the inclination of that body to the horizon. On the face C near the point of the callipers is a little table flio wing -the proportion of troy and avoirdu- poife weights, by which one kind of weight may be eafily reduced into another. Near the extreme of the face D of the callipers are two tables fhov/ing the proportion between the pounds v/elght of London and Paris, and alfo between the lengths of the foot meafure of England and France. Near the extreme on the face A is a table contain- ing four rules of the circle and fphere ; and geometri- cal figures with numbers annexed to them : the firll is a circle including the proportion in round numbers of y the diameter to its circumference ; the fecond is a cir- cle infcribed in a fquare, and a fquare within that cir- cle, and another circle in the inner fquare : the numbers 28, 22, above this figure exhibit the proportion of the outward fquare to the area of the infcribed circle ; and the numbers 14, it, below it fhow the proportion be- t\veen the area of the infcribed fquare and the area of ks infcribed circle. The third is a cube infcribed in a ,N^6f. fphere ; aud the number 894- fliows that a cube of iron, infcribed in a fphere of 12 inches in diameter, weighs 89-5-. The fourth is a fphere in a cube, and the num- i_ ber 243 exprefTes the weight in pounds of a fphere infcribed in a cube whofe fide is 1 2 inches : the fifth reprefents a cylinder and cone of one foot diameter and height: the number in the cylinder fliows, that an iron cylinder of that diameter and height weighs 364.5 lb. and the number 12 1. 5 in the cone exprefies the weight of a cone, the diameter of whofe bafe is 1 2 inches, and of the fame height: the fixth figure fliows that an iron cube, whofe fide is 1 2 inches, weighs 464 lb. and that a fquare pyramid of iron, whofe bafe is a fquare foot and height 12 inches, weighs 154^ lb. The numbers which have been hitherto fixed to the four laft figures were not ftriftly true ; and therefore they have been correcled in the figure here referred to ; and by thefe the figures on any inflirument of this kind flxould be correfted likewife. On the leg B of the callipers, is a table fl^iowlng the weights of a cubic inch or foot of various bodies in pounds avoirdupoife. On the face D of the circular iisad of the caUipers is a table contained between five concentric fegments of rings : the inner one marked Gmis fliows the nature of the gun or the weight of ball it carries ; the two next rings contain the quantity of powder ufed for proof and fervice to brafs guns, and the two outermoft rings fiiow the quantity for proof and fervice in iron Gannon. On -the face A is a table exhibiting the method of computing the number of jhol or Jhelh in a triangular, fquare, or redlangular pile. Near this is placed a table containing the principal rules relative to the fall of bodies^ exprefled in an algebraic manner : nearer the centre we have another table of rules for raifing water, calculated on the fuppofition, that one horfe is equal in this kind of labour to five men, and that one man will raife a hogfliead of water to eight feet of height in one minute, and work at that rate for fome hours, N. B. Hogflieads are reckoned at fixty gallons. Some of the leading principles in gunnery, relating to Jhoot'mg in cannon and mortars, are exprefled on the face B of the callipers. Befides the articles already enumerated, the fcales ufually marked on the feftor pre laid down on this infl;rument : thus, the line of inches is placed on the edge of the callipers, or on the ftraight borders of the faces C, D : the logarithmic fcales of numbers, fines, verfed fines, and tangents, are placed along thefe faces near the ftraight edges : the line of lines is placed on the fame faces in an an* gular pofition, and marked Lin. The lines of plains or fuperfices are alfo exhibited on the faces C and D, tending towards the centre, and marked Plan. Fi* nally, the lines of folids are laid on the fame faces tending towards the centre, and diftinguiflied by Sol. CALICOULAN, or Quillon, a town of Afia, in the Eaft Indies, on the coaft of Malabar, and in the peninfula on this fide the Ganges, where the Dutch have a faftory. E. Long. 75. 21. N. Lat. 9. 5, CALICUT, a kingdom of India, on this fide the Ganges, upon the coaft of Malabar. It is about 63 miles long, and as much broad. It has many woods, rivers, and marfliea, and is very populous ; but does not produce much corn, abundance of rice being im- 2 ported (1 Cf.iicu'-, c Calicut ported from Canara. ■"al forma fandy, and produces a number of cocoa-trees. '- The higher grounds produce pepper and cardamoms of a very good quality. They have likewife timber for building, white and yellow fanders, caflia lignea, caf- fia fiftula, nux vomica, and cocculus indicus. The •woods abound with parrots and monkeys, as well as different kinds of game. They have alfo plenty of fifti, feveral forts of medicinal drugs, and their moun- tains produce iron. The famorin, or king, of Calicut, was once mailer of all the coaft of Malabar ; but at his death, he left it by will among four of his nephews. He who governs Calicut has a palace of ftone, and there is fome appearance of grandeur about his court. He carries on a confiderable trade, which makes the people of Calicut richer than their neighbours. In former times they had feveral ftrange cultoms, fome of which are ftill kept up; particularly the famorin's wife muft be firft enjoyed by the high prieft, who may have her three nights if he pleafes. The nobles per- mit the other priefts to take the fame liberty, but the lower people cannot have that honour. A woman may marry a number of hufbands ; each of whom has her ten days or more by turns, as they agree among them- felves ; and provides her all things necelTary during that time. When Ihe proves with child, fhe names the father ; who, after the child is weaned, takes care of its education. Thefe people have no pens, ink, or paper ; but write with a bodkin on flags that grow by the fides of the rivers. By this means the letters are in fome fenfe engraved ; and fo tough are the fla^s, that they will laft for a great number of years. This was the firft land difcovered by the Portuguefe in 1498. Calicut, a town of Afia, in the kingdom of that name on the coaft of Malabar. It contains a great number of mean low houfes, each of which has a gar- den. The Englifti had a factory here, but it is remo-. ved to Tillcherry. E. Long. 76.4. N. Lat. 11. 21. CALID^ plantjE (from c^i/or heat) ; plants that are natives of warm climates. Such are thofe of the Eaft Indies, South America, .Egypt, and the Canary Iflands. Thefe plants, fays Linnxnis, will bear a de- gree of heat which is as 40 on a fcale in which the freezing point is o, and 100 the heat of boihng water. In the loth degree of cold they ceafe to grow, lofe their leaves, become barren, are fuffocated, and perifh. CALIDUCT, in antiquity, a kind of pipes or ca- nal difpofed along the walls of houfes or apartments, ufed by the ancients for conveying heat to feveral re- mote parts of the houfe from one common furnace. ^ CALIFORNIA, the moft northerly of all the Spa- nifti dominions on the continent of America, is fome- timos diftinguifhed by the name of Netu Alh'inn, and the IJlas Carab'iras : but the moft ancient appellation is Cai'ijornia ; a word probably owing to fome accident, or to fome words fpoken by the Indians and mifunder- ftood by the Spaniards. For a long time California was thought to be an ifland ; but Father Caino, a Ger- man Jefuit, difcovered it to be a peninfula joining to the coaft of New Mexico and the fouthern parts of Ame- rica. This peninfula extends from Cape St Sebaftian, lying in north latitude 43, 30. to Cape St Lucar which lies in north latitude 22. 32. It is divided from New Mexico by the gulph, or as fome call it the lake, of Vol. IV. Part L A L [ 4' 1 C A L The land along the fea-coaft is California, or VmnlUon Sea, on the eaft ; on the north, California. by that part of the continent of North America which is leaft known ; and on the weft and fouth, by the Pacific Ocean or great South Sea. The coafts, efpe- cially towards the Vermilion Sea, are covered with in- habited iflands, on fome of which the Jefuits have eftabliflied fettlements, fuch as St Clement, Paxaros, St Anne, Cedars (fo called from the great number of thefe trees it produces), St Jofeph, and a multitude of others. But the iflands beft known are three lying oft' Cape St Lucar, towards the Mexican coaft. Thefe are called Les Tres Marias, " the three Maries." They are but fmall, have good wood and water, fait pits, and abundance of game ; therefore the Englifli and French pirates have fometimes wintered there, when bound on cruizes in the South Seas. As California lies altogether within the temperate zone, the natives are neither chilled with cold nor fcorched with heat ; and indeed the improvements in agriculture made by the Jefuits afford ftrong proofs of the excellency of the climate. In fome places the air is extremely hot and dry ; and the earth wild, rugged, and barren. In a countiy ftretching about 800 miles in length, there muft be confiderable variations of foil and climate ; and indeed we find, from good authority, that California produces fome of the moft beautiful lawns, as well as many of the moft inhofpitable defarts, in the univerfe. Upon the whole, although California is ra- ther rough and craggy, we are affured by the Jefuit Vinegas, and other good writers, that with due culture it furniflies every neceffary and conveniency of life j and that, even where the atmofphere is hottell, vapours rifing from the fea, and difperfed by pleafant breezes, render it of a moderate temperature. The peninfula of California is now ftocked with all forts of domeftic animals known in Sapin and Mexico. Horfes, mules, affes, oxen, ftieep, hogs, goats, and all other quadrupeds imported, thrive and increafe in this country. Among the native animals is a fpecies of deer of the fize of a young heifer, and greatly refembhng it in fliape ; the head is like that of a deer, and the horna thick and crooked like thofe of a ram. The hoof of the animal is large, round, and cloven, the flcin fpatted, but the hair thinner and the tail fliarper than thofe of a deer. Its flefli is greatly efteemed. There is another animal peculiar to this country, larger and more bulky than a flieep, but greatly refembling it in figure, and", like it, covered with a fine black or white wool. Tlie flelh of this animal is nourifhing and delicious ; and, happily for the natives, it is fo abundant, that nothing more is required than the trouble of hunting, as thefe animals wander about in droves in the forefts and on the mountains. Father Torquemado defcribes a crea, ture which he calls a fpecies of large bear, fomething Hke a buffalo, of the fize of a fteer, and nearly of the figure of a ftag. Its hair is a quarter of a yard in length, its neck long and aukward, and on its forehead are horns branched like thofe of a ftag. The tail is a yard in length and half a )':ard in breadth ; and the hoofs cloven hke thofe of an ox. With regard to birds, we have but an imperfeft account ; only, in ge- neral, Father Venegas .tells ,us that the coaft is plen- tifully ftored with peacocks, buftards, geefe, cranes, and moft of the birds common in other parts of the world. The quantity .of fifli which refort to thefe F coaiis C A L [ 42 lifornia. coails are incredible. Salmon, turbot, barbel, fkate, ' mackerel, &c. are caught here with very little trou- ble ; together with pearl oytters, common oyfters, lobfters, and a variety of exquifite (hell-fifli. Plen- ty of turtle are alfo caught on the coafts. On the South Sea coails are fome Ihell-fifli pecuHar to it, and perhaps the moll beautiful in the world ; their luftre furpaffing that of the fineft pearl, and darting their rays through a tranfparent varnifh of an elegant vivid blue, hke the lapis lazuli. The fame of Cahfornia for pearls foon drew forth great numbers of adventu- rers, whofearched every part of the gulph, and are ftill employed in that work, notwithftaiiding fafliion has greatly diminiOied the value of this elegant natural pro- duction. Father Torquimado obferves that the lea of California affords very rich pearl fifheries; and that the kojltas, or beds of-oylicrs, may be feen in three or four fathom water, almoft as plain as if they were on the ftirfacc. The extremity of the peninfula towards Cape St Lu- car is more level, temperate, and fertile, than the other parts, and confcquently more woody. In tlie more di- ilant parts, even to the farthell miffions on the eaft coaft, no largo timber hath yet been difcovered. A fpecics of manna is found in tliis country, Avhich, ac- cording to the accounts of the Jefuits,"has all the fwcet- ncfs of refined fugar without its whitcnefs. The natives firmly believe that this juice drops from heaven. The Californians are well made, and very ftrong. They are extremely pufilanimous, inconftant, ftupid, and even infenfible, and feem extremely deferving of the charafter given to the Indians in general, under the article America. Before the Europeans penetra- ted into Cahfornia, the natives had no form of reli- gion. The miflionaries indeed tell us many tales con- cerning them, but they fo evidently bear the marks of forgery as not to be worth repeating. Each nation was then an afiemblage of feveral cottages more or kfs nu- merous, that were all miutually confederated by alli- ances, but without any chief. They were ilrangers even to filial obedience. No kind of drefs was ufed by the men ; but the women made ufe of fome coverings, and were even fond of ornamenting themfelves with pearls and fuch other trinkets as the country afforded. What moftly difplayed their ingenuity was the con- ftruftion of their fifhing nets, which are faid by the Je- fuits to have even exceeded in goodnefs thofe made in Europe. They were made by the women, of a coarfe kind of flax procured from fome plants which grow there. Their houfes were built of branches and leaves of trees : nay, many of them were only inclofures of earth and ftone, raifed half a yard high, without any covering ; and even thefe were fo fmall, that they could not ttretch themfelves at length in them. In winter, they dwelt under ground in caves either natural or ar- tificial. In 1526, Ferdinand Cortez having reduced and fet- tled Mexico, attempted the conqueft of Cahfornia ; but was obliged to return, without even taking a furvey of the country, a report of his death having difpofed the Mexicans to a general infurreftion. Some other attempts were made by the officers of Cortez, but thefe were alfo unfuccefsful ; and this valuable coaft was long neglefted by the Spaniards, whv, to this day, have but one fettlement upon it. In 1595, a galleon ] C A L was fent to make difcoverles on the Californian Ihore ; Califomiaj but the velTel was unfortunately loft. Seven years af- ^'''^g' ^- ter, the count de Monteroy, then viceroy of New " " " Spain, fent Sebaftian Bifcayno on the fame defign with two fliips and a tender ; but he made no difcovery of importance. In 1 684, the marquis de Laguna, alfo viceroy of new Spain, difpatched two (hips with a tender to make difcoveries on the lake of California. He returned with an indifFerent account, but was a- mong the firft that aflerted that California was not an ifland ; which was afterwards confirmed by Father Caino, as already reUted. In 1697, the Spaniards being difcouraged by their loffes and difiippointmentSy the Jefuits folicited and obtained permifilon to under- take the conqueft of Cahfornia. They arrived among the favages with cunofities that might amufe them, corn for their food, and clothes for which they could not but perceive the necefiity. The hatred thefe peo- ple bore the Spaniih name could not fupport itfeif a- gainft thefe demonitrations of benevolence. They tef- tified their acknowledgments as much as their want of fenfibility and their inconftancy would permit them. Thefe faults were partly overcome by the religious in-, ftitutors, who purfued their projed with a degree of warmth and refolution peculiar to the fovicty. They made themfelves carpenters, mafons, weavers, and huf- bandmen ; and by thefe means fuccecded in impai'ting knowledge, and in fome meafure a tafte for the ufeful arts, to this favagc people, who have been all fuccef- fively formed into one body. In 1745, they compo- fed 43 villages, feparated from each other by the bar- rennefs of the foil and the want of water. The inha- bitants of thefe fmall villages fubfift principally on corn and pulfe, which they cultivate ; and on the fruits and domeftic animals of Europe, the breeding of which laft is an objed of continual attention. The Indians have each their field, and the property of what they reap ; but fuch is their want of forefight, that they r would fquander in a day what they had gathered, if the miffionary did not take upon himfelf to dillribute it to them as they ftand in need of it. They manu- fadure fome coarfe ftuffs ; and the neceflaries they are in want of arc purchafed with pearls, and with wine nearly refembhng that of Madeira, which they fell ta the Mexicans and to the galleons, and which experi- ence hath (hown the neceffity of prahibiting in CalK- fornia. A few laws, which are veyy fimple, are fuffi- cient to regulate this rifing ftate. In order to enforce them, the miffionary choofes the moft intelligent per- fon of the village ; who is empowered to- whip and im- prifon ; the only punilhments of which they have any knowledge. In all Cahfornia there are only two gar- rifons, each confifting of 30 men ard a foldier with every miffionary. Thefe troops were chofen by the le- giflators, though they are paid by the government. Were the court of Madrid to pufh their intereft with - half the zeal of the Jefuits, California might become one of the moft; valuable of their acquifitions, on ac- count of the pearls and other valuable articles of com- merce which the country contains. At prefent the httle Spanifh town near Cape St Lucar is made ufe of for no other purpofe than as a place of refrefliment for the Manila fliips, and the head refidence of the miffion- aries. CALIGA, in Roman Antiquity, was the proper fol- C A L CallgatI !i Caliph. foldier's fhoe, made in the fandal fafiuon, without up- per leather to cover the fuperior part of the foot, tho' otherw'.fe reaching to the middle of the leg, and fa- ftened with thongs. The fole of the caliga was of wood, like the fabot of the French peafants, and its bottom ftuck fuU of nails ; which clavi are fuppofed to have been very long in the (hoes of the fcouts and fen- tinels ; whence thefe were called by way of diftinftion, caliga fpeculator'ta ; as if by mounting the wearer to a higher pitch, they gave a greater advantage to the fight : though others will have the caligte fpecvlatorite to have been made foft and woolly, to prevent their making a noife. From thefe cal'iga it was that the emperor Caligula took his name, as having been born in the army, and afterwards bred up in the habit of a common foldier. According to Du Cange, a fort of callgis was alfo worn by monks and bilhops, when they celebrated mafs pontifically. CALIGATI, an appellation given by fome ancient %vriters to the common foldicrs in the Roman armies, by reafon of the caliga which they Avore. The caliga was the badge or fymbol of a foldier ; whence to take aw-*y tlie cahga and belt, imported a difmiffing or cafhierlng. CALIGO, or Caligatio, in Medicine, an opacity, or cloudinefs of the anterior furface of the crytlalline, caufing a dimnefs or fuffwhon of fight. CALIGULA, the Roman emperor and tyrant, A. D. 37, began his reign with every promifing ap- pearance of becoming the real father of his people ; but at the end of eight months he was feized with a fever, which, it is thought, left a frenzy on his mind : for his difpofition totally changed, and he committed the moll atrocious afts of impiety, cruelty, and folly ; fuch as proclaiming his liorfe conful, feeding it at his table, introducing it to the temple in the veftments of the priefts of Jupiter, &c. and caufing facrilices to be ollered to himfelf, his wife, and the horfe. After ha- ving murdered many of his fubjefts with his own hand, and caufed others to be put to death without any juft caufe, he was alTaflinated by a tribune of the people as he came out of the amphitheatre, A. D. 41, in the 29th year of his age, and 4th of his reign. CALIN, a compound metal, whereof the Chinefe make tea-canifters, and the like. The ingredients feem to be lead and tin. CALIPH, or Khalif, the fupreme ecclefiaflical dignity among the Saracens ; or, as it is otherwife de- lined, a fovereign dignity among tlie Mahometans, veil- ed with abfolute authority in all matters relating both to religion and policy. In the Arabic it lignifies fuc- cejfor or mc.ar ; the caliphs bearing the fame relation to Mahomet that the popes pretend they do to Jefus Chrlft or St Peter. It is at this day one of the Grand Signior's titles, as fucceflbr of Mahomet ; and of the Sophi of Perha, as fucceifor of AH. One of the chief funftions of the caliph, in quality of imam or chief prieft of MulTulmanifm, was to begin the public pray- ers eveiy Friday in the chief mofque, and to deliver tlie khothhak or fermon. In after-times, they had af- littants for this latter office ; but the former the caliphs always performed in perfon. The caliph was alfo ob- liged to lead the pilgrims to Mecca in perfon, and to march at the head of the armies of his empire. He [ 43 ] C A L granted Invefliture to princes ; and feat fwords, ftand- ards, gowns, and the like, as prefcnts to princes of the Maliometan religion ; wlio, though they had thrown ofF the yoke of the caliphate, neverthelefs held of it as valfals. The caliphs ufually went to the mofque mounted on mules ; and the fultans felgiucides, thougFj mailers of Bagdad, held their ftirrups, and led their mule by the bridle fome dillance on foot, till fuch time as the caliphs gave thfm the fign to mount on horfo back. At one of the windows of the caliph's palace, there always hung a piece of black velvet 20 cubits long, which reached to the ground, and was called the caliph's Jleeve ; which the grandees of his court never failed to kifs every day, with great rcfpeft. After the dellru6lion of the caliphate by Hulaku, the Ma- hometan princes appointed a particular olFicer, in their refpeftive dominions, who fuflains the faci-ed authority of caliph. In Turky, he goes under the denominatioi* of mufti, and in Perfia under that of fadne. CALIPHATE, the office or dignity of caliph : See the preceding article. The fucceffion of caliphs continued from the death of Mahomet till the 655th year of the Hegira, when the city of Bagdad waa ta- ken by the Tartars. After this, however, there were perlons who claimed the caliphate, as pretending to be of the family of the Abaffides, and to whom the ful- tans of Egypt rendered great honours at Cairo, as the true fucceifors of Mahomet : but this honour wai merely titular, and the rights allowed thsm only in- matters relating to religion ; and though they bore the fovereign title of caliphs, they were neverthelefs fub- jects and dependents of the fultans. In the year of the Hegira 361, a kind of caliphate was erefted by the Fat«mites in Africa, and lailed till it was fuppreffed by Saladdin. Hiftorians alfo fpeak of a third caliphate in Gemen or Arabia Felix, erefted by Come princes of the family of the Jobites. The emperors of Morocco affume the title oS. grand cherifs ; and pretend to be the true caliphs, or fucceflbrs of Mahomet, though under another name. CALIPPIC PERIOD, in chronology, a fcries of feventy-fix years, perpetually recurring ; which elapfed the middle of the new and full moons, as its inventor Calippus, an Athenian, imagined, return to the fame day of the folar year. Meton, an hundred years be- fore, had invented the period, or cycle, of nineteen years; afluming the quantity of the folar year 365 pa:f«, / nvrite. The minutes of a points, difpofed in a triangular form, fo that three of them are always on the ground, and the fourth in the air. They are fcattered over the ground where the enemy's cavalry is to pafs, in order to embarrafs them. CALVARiA, inanatqmy, the hairy fcalp crupper part of the head, which, either by difeafe or old age, grows bald firft. CALVART (Denis), a 'celebrated painter, was born at Antwerp in 1552; and had for his mailers Profpero Fontana and Lorenzo Sabbatini. He open- ed a fchool at Bologna, which became celebrated; and from which proceeded Guidp, Albani, and other great mailers. Calvart was well llcillcd in architefture, per- •fpedlive, and anatomy, v^hich he confidered as necefr fary to a painter, and taught them to his pupils. His .principal works are at Bologna, Rome, and Reggio, He died at Bologna, in 1 6 1 9. CALVARY, a tenti ufed in Catholic countries for 6 a C A L Calvary a kind of qhapel of devotion raifed on a hillock near a Calvin, ^^^y*. "lemory of the place where Jefus Chrift was crucified jiear the city of Jerufalem. The word comes from the Latin Cii/varium; and that from calvus, bald ; ■ in regard the top of that hillock was bare anddeftitute of verdure: which is alfo fignified by the Hebrew word golgotha. Such is the Calvary of St Valerian near Paris ; which is accompanied with feveral little chapels, in each of which is reprefented in fculpture one of the myfleries of the paflion. Calvary, in heraldry, a crofs fo called, becaufe it refembles the crofs on which our Saviour fuffered. It is always fet upon fteps. CALVERT (George), afterwards lord Baltimore, was born at Kipling in Yorkfhire about the year 1582, and educated at Oxford, where he took the' degree of bachelor of arts, and afterwards travelled. At his re- turn, he was made fecretary to Sir Robert Cecil : he was afterwards knighted, and in 161 8 appointed one of the principal fecretaries of ftate. But after he had enjoyed that poll about five years, he willingly refigned it; freely owning to his majefty that he was become a Roman-catholic, fo that he mull either be wanting to his truft, or violate his confcience in difcharging his office. This ingenuous confelfion fo affefted king James, that he continued him privy-counfellor all his reign, and the fame year created him baron of Bal- timore in the kingdom of Ireland. He had be- fore obtained a patent for him and his heirs, for the province of Avelon in Newfoundland : hut that being expofed to the infults of the French, he abandon- ed it, and afterwards obtained the grant of a country on the north part of Virginia from Charles I. who call- ed it Maryland, in honour of his queen : but he died in April 1632 (aged 50), before the patent was made out. It was, however, filled up to his fon Cecil Cal- vert lord Baltimore ; and bears date June 20th 1632. It is held from the crown as part of the manor of Windfor, on one very fingular condition, viz. to pre- fent two Indian arrows yearly, on Eafter Tuefday, at the caftle, where they are kept and fliown to vifitors. His lordlhip wrote, i . A Latin poem on the death of Sir Henry Upton. 2. Speeches in parliament. 3. Va- rious letters of ftate. 4. The anfwerof Tom Tell-truth. 5. The praftice of princes. And, 6. The lamentation of the kirk. ^ CALVI, a town of the province of Lavoro, in the kingdom of Naples, fituated near the fea, about fifteen miles north of the city of Naples." E. Long. 14. 45. N. Lat. 41. 15. Calvi is alfo the name of a fea-port in the ifland of Corfica, fituated on a bay, on the weft fide of the ifland, about 40 miles fouth-weft of Baftia. E. Long. 9. 5. N. Lat. 42. 16. ^ CALVIN (John), the celebrated reformer of the Chriftian church from Romifh fuperftitions and doftri- nal errors, and founder of the fed fince called Cahlnifls, was born in 1509. He was the fon of a cooper of Noyon in Picardy ; aiid his real name was Chawv'm, which he chofe to latinize into Cah'w.tis, ftyling him- felf in the title-page to his firft work (a Commentary on Seneca de dementia), " Lucius Calvinus, Civis Roma- nus;" an early proof of his pride, at about 24 years of age. In 1529, he was redlor of Pont I'Eveque; and in 1534 he threw up this benefice, feparating himfelf Vol. IV. Part L r . a f 49 ] C A L entirely from the Romifli church. The pcffecution CalvJn, againft the Proteftants in France (with whom he was Calviniim. nowaffociated) obliged him to retire to Bafle in Swit- ^^"^ zerland : here he publifhed his famous Inftitutes of the Chriftian religion in 1535. The following year, he was chofen profeffor of divinity, and one of the mini- fters of the church, at Geneva. The next year, viz. 1 5 3 7, he made all the people folemnly fwear to a body of doc- trines; butfinding that religion had not yet had any great influence on the morals of the people, he, aflifted by other minifters, declared, that fince all their admonitions and warnings had proved unfuccefsful, they could not cele- brate the holy facrament as long as thefe diforders reigned ; he alfo declared, that he could not fubmitto fome regulations made by the fynod of Berne. Upon which the Syndics having fummoned the people, it was ordered that Calvin and two other minifters fliould teave the city within two days. Upon this Calvin re- tired to Strafl)urg, where he eftabliflied a French church, of which he was the firft minifter, and was al- fo chofen profeiTor of divinity there. Two years af- ter he was chofen to affift at the diet appointed by the empei-or to meet at Worms and at Ratifton in order to appeafe the troubles occafioned by the difference of religion. He went with Bucer, and entered into a conference with Melanfton. The people of Geneva now entreated him to return ; to which he confented, and arrived at Geneva, September 13th 1541. He began with eftabhfliing a form of ecclefiaftical' difci- phne, _and a confiftorial jurifdiftion, with the power of infliaing all kinds of canonical punifliments. This was greatly difliked by many perfons, who imagined that the papal tyranny would foon be revived. Calvin however, aflerted on all occafions the rights of his confiftory with inflexible ftridnefs ; and he caufed Mi- chael Servetus to be burnt at the ftake for writing a- gainft: the dodrine of the Trinity. But though the rigour of his proceedings fometimes occafioned great tumults in the city, yet nothing could fliake his ftea- dmefs and mflexibihty. Amongft all the difturbances of the commonwealth, he took care of the foreign churches in England, France, Germany, and in Po- land ; and did more by his pen than his prefence, fend- • ing his advice and inftruftions by letter, and writing a great number of books. This great reformer died on the 2 7th of May 1 564, aged 55. His works were pnnted together at Amfterdam in 1671, in nine vo* lumes folio : the principal of which are his Inftitutions, in Latin, the beft edition of which is that of Robert Stephens in 1553, in folio ; and his Commentaries on the Holy Scriptures.— Calvin is univerfally allowed to have had great talents, an excellent genius, and pro. found learning. His ftyle is grave and polite. Inde- pendent of his fpiritual pride, his morals were exem- plary ; for he was pious, fober, chafte, laborious, and difinterefted. But his memory can never be purified from the ftain of burning Servetus : it ill became a reformer to adopt the moft odious pradice of the cor- rupt church of Rome. CALVINISM, the doarine and fentiments of Calvm and his followers. Calvinifm fubfifts in its greateft purity in the city of Geneva; and from thence It was firft propagated into Germany, France, the U- nited Provinces, and England. In France it was abo- Lflied by the revocation of the edia of Nantz in 1685. G It C A L [ 50 1 C A L Calvities. CalvInHii) It has been tKe prevailing religion in the United Pro- f vinces everJince the year 1571. The theological fyf- tem of Calvin was adopted, and made the public rule of faith in England, under the reign of Edward VI. and the church of Scotland was modelled by John Knox, the difciple of Calvin, agreeably to the doc- trine, rites, and form of eccleliaftical government, efta- blifhed at Geneva. In England it has declined fince the time of queen EUzabeth ; though it ftill fubfifts, fome fay a little allayed, in the articles of the eftablifli- ed church ; and in its rigour in Scotland. The diftinguifhing theological tenets of Calvinifm, as the term is now generally applied, refpeft the doc- trines of Predestination, or particular Election and Reprobation, original Sin, particular Redemp- tion, effeftual, or, as fome have called it, irrefiftible Grace in regeneration, Justification by faith, Per- severance, and the Trinity. See each of thefe arti« cles. Befides the doftrinal part of Calvin's fyftem, which, fo far as it differs from that of other reformers of the fame period, principally regarded the abfolute decree of God, whereby the future and eternal condition of the human race was determined out of mere fovereign pleafure and free-will ; it extended Hkewife to the dif- clpline and government of the Chriftian church, the- nature of the Eucharift, and the qualification of thofe who were intitled to the participation of it. Calvin confidered every church as a feparate and independent body, Invefted with the power of legiflation for itfelf. He propofed that it (hould be governed by preftyteries and fynods, compofed of clergy and laity, without biOiops, or any clerical fubordination ; and maintain- ed, that the province of the civil magiftrate extended only to its protection and outward accommodation. In order to facilitate an union with the Lutheran church, he acknowledged a real, though fpiritual, prefence of Chrift, in the Eucharift, that true Chriftians were uni- ted to the man Chrift in this ordinance, and that di- was conferred upon them, and fealed to grace and he confined the them, in the celebration of it privilege of communion to pious and regenerate be- lievers. In France the Calvinifts are diftmguifhed by the name oi Huguenots; and, among the common people, by that of ParpalUots. In Germany they are con- founded with the Lutherans, under the general title ProteJIants ; only fometimes diftinguifhed by the name Reformed. CALVINISTS, in church-hiftory, thofe who fol- low the opinions of Calvin. See the two preceding articles. Crypto-CALvwisTs, a name given to the favourers of Calvinifm in Saxony, on account of, their fecret at- tachment to the Genevan doftrine and difcipHne. Many of them fuffered by the decrees of the convoca- tion of Torgaw, held in 1576. The Calvinifts in their progrefs have divided into various branches, or lelTer feas. CALVISIUS (Seth), a celebrated German chro- nologer in the beginning of the 1 yth century. He wrote Elenchus calendarli Gregortani, et duplex calendarii melioris forma, and other learned works, together with fome excellent treatifes on mufic. He died in 1617, aged 61. CALVITIES, or Calvi.tium, in medicine, bald- nefs, or a want of hair, particularly on the finclput, occafioned by the moifture of the head, which ftiould - feed it, being dried up, by fome difeafe, old age, or the immoderate ufe of powder, &c. See Alo- pecia. , CALLIMET, a fymbolical inftrument of great im- portance among the American Indians. — It is nothing more than a pipe, whofe bowl is generally made of a foft red marble : the tube of a very long reed, orna- mented with the wings and feathers of birds. No af- fair of confequence is tranfaAed without the calumet. It ever appears in meetings of commerce or exchanges ; in congreffes for determining of peace or w^ar ; and even in the very fury of a battle. The acceptance of the calumet is a mark of concurrence with the terms pro- pofed ; as the refufal is a certain mark of rejection. Even in the rage of a conflict this pipe is fometirnes offered ; and if accepted, the weapons of deftruftion inftantly drop from their hands, and a truce enfues. It feems the facrament of the favages ; for no compatt is ever violated which is confirmed by a whiff from this holy reed. When they treat of war, the pipe and all its ornaments are ufually red, or fometimes red on- ly on one fide. The fize and decorations of the calu- met are for the moft part proportioned to the quality of the perfons to whom they are prefented, and to the Importance of the occafion. The calumet of peace is dif- ferent from that of war. They make ufe of the for- mer to feal their alliances and treaties, to travel with fafety, and to receive ftrangers ; but of the latter to proclaim war. It confifts of a red ftone, like marble, formed into a cavity refembfing the head of a tobacco pipe, and fixed to a hollow reed. They adorn it with feathers of various colours ; and name it the calumet of the fun, to which luminary they prefent it, in ex- pedtation of thereby obtaining a change of weather as often as they defire. From the winged ornaments of the calumet, and its conciliating ufes, writers compare it to the caduccus of Mercuiy, which was carried by the caduceatores, or meffengers of peace, with terms to the hoftile ttates. It is fingular, that the moft re- mote nations, and the moft oppofite in their other cuftoms and manners, fliould in fome things have, as it were, a certain confent of thought. The Greeks and the Americans had the fame idea, jn the inven- tion of the caduceus of the one, and the calumet of the other. Dattce of the Calumet, is a folemn rite among the Indians on various' occafions. They dare not wafh themfelves in rivers in the beginning of fummer, nor tafte of the new fruits, without performing it ; and the fame ceremony always confirms a peace or precedes a war. It is performed in the winter-time in their cabins, and in fummer in the open fields. For this purpofe they choofe a fpot among trees to ftiade them from the heat of the fun, and lay in the middle a large mat, as a carpet, fetting upon it the monitor, or god, of the chief of the company. On the right hand of this image they place the calumet, as their great deity, erefting around it a kind of trophy with their arms. Things being thus difpofed, and the hour of dancing come, thofe who are to fing take the moft honourable feats under the fliade of the trees. The company is then ranged round, every one, before he fits down, faluting the monitor, which is done by blowing upon Calumet. amct: , (I alyb'.tess C A L [ 5 upon it the fmokc of tlicir tobacco. Each perfon next re- ceives the cahimet in rotation, and holding it with both hands, dances to the cadence of the vocal mufic, which is accompanied with the beating of a fort of drum. During this exercife, he gives a iignal to one of their M'arriors, who takes a bow, arrow, and axe, from the trophies aheady mentioned, and fights him ; the for- mer defending himfelf with the calumet only, and both of them dancing all the while. This mock engage- ment being over, he who holds the calumet makes a fpeech, in which he gives an account of the battles he has fought, and the prifoners he has taken, and then receives a cloak, or fome other prefent, from the chief of the ball. He then refigns the calumet to an- other, who having afted a fimilar part, dehvers it to a third, who aftervs-ards gives it to his neighbour, till at laft the inilrument returns to the perfon that began the ceremony, who prefents it to the nation invited to the feaft, as a mark of their friendlliip, and a confirmation of their alliance, when this is the occafion of the en- tertainment. CALUMNY, the crime of accufing another falfely, znd knowingly fo, of fome heinous offence. Oath of Calumny, Juramentum (or rather yusju- ranclmn) Calumnla, among civilians and canonifts, was an oath which both parties in a caufe were obliged to take ; the plaintifi" that he did not bring his charge, and the defendant that he did not deny it, with a defign to abufe each other, but becaufe they believed their caufe was jufl: and good ; that they would not deny the truth, nor create unneceflary delays, nor offer the judge or evidence any gifts or bribes. If the plaintiff refiifed this oath, the complaint or libel was difmiffed; Lt the defendant, it was taken pro confejfo. This cuftom was taken from the ancient athletge ; who, before they engaged, were to fwear that they had no malice, nor would ufe any unfair means for overcoming each other. The juramentum calnmnix is much difufed, as a great occafion of perjury. Anciently the advocates and proc- tors alfo took this oath ; but of late it is difpenfed Tvith, and thought. fufhcient that they take it once for all at their firll admilTion to praftice. See alfo Law, Part IIL n° clxxxiv. 7. CALVUS (Cornelius Licinius), a celebrated Ro- man orator, was the friend of Catullus ; and flourifhed 64 B. C. Catullus, Ovid, and Horace, fpeak of him. CALX properly fignifies lime, but is alfo ufed by chcmiils and phyficians for a fine powder remaining after the calcination or corrofion of metals and other mineral fubftances. All metallic calces, at leafl all thofe made by fire, are found to weigh more than the metal from which they were originally produced. See the article Fire. Calx Nat'j-vo, in natural hiilory, a kind of marly earth, of a dead whitifh colour, which, if thrown into water, makes a confiderable bubbling and hiifing noife, and has, without previous burning, the quality of ma- king a cement like lime or plafter of ParLj. Calx Viva, or ^iek~Jime, that whereon no water has been caft, in contradiftinftion to hme which has been fiaked by pouring water on it. CALYBITES, the inhabitant of a cottage, an ap- pellation given to divers faints , on account of their long refidence in fome hut, by way of mortification. I 3 C A L The word is formed from x«\u*»'«, tego, I cover ; whence naxvCw, a little cot. — The Romifh church com- memorates St John the calybites on the 15th of De- cember. CALYCANTHEM^, in botany, an order of plants in the Fragmenta methodi naturalis of Lin- naeus, in which are the following genera, viz. epilo- bium, Oenothera, julTiKa, ludivigia, oldenlandia, ifnar- da, &c. See Botany, feft. vi. 17. CALYCANTHUS, in botany : A genus of the polygynia order, belonging to the icofandria clafs of plants ; and in the natural method claffed with thofe of which the order is doubtfuL The calyx is mono- phyllous, urceolate, or blown up ; fquanofe, or friz- zled with fmall coloured leaves, the corolla confiiling of the leaves on the calyx ; the Hyles are numerous, eacli with a glandular ftigma ; the feeds are many, each with a train, within a fucculent calyx. There are two fpecies; namely, i. The prcecox, which is not quite inured to this cHmate ; and, 2. The floridus, a flower- . ing calycanthue, or Carolina allfpice tree, a native of Carohna. It feldom grows, at leaft with us, to more than five feet high. It divides into many branches irregularly near the ground. They are of a brown colour, and being bruifed emit a moft agreeable odour. The leaves that garnifh this delightful aromatic are of an oval fi- gure, pointed; They are near four inches long, and are at leaft two and a half broad, and are placed oppo- fite by pairs on the branches. At the end of thefe ftand the flowers, of a kind of chocolate-purple colour, and which are poffeffed of the oppofite qualities of the bark on the branches. They iland fingle on their fhort footftalks, come out ui May and June, and are fuc- ceeded by ripe feeds in England. The prapagation of this fhrub is not very difficult ; though more than common care muft be taken, after fmall plants are obtained, to preferve them till they are of a fize to be ventured abroad. The laft year's fhoots, if laid in the ground, the bark efpecially being a little bruifed, will ftrike root within the compafs of twelve months, par- ticularly if the layers are fnaded, and now and then watered in the fummer's drought. In the fpring they fhould be taken off, and planted in pots ; and if thefe are afforded a fmall degree of heat in a bed, they will ftrike fo much the fooner and ftronger. After they^ bavejjeen in this bed a month or fix weeks, they fhould be taken out. In the heat of the fummer they fhould be placed in .the ftiade ; and if the pots are plunged into the natural ground, it will be fo much the better. At the approach of the fucceeding winter's bad wea- ther, the pots fliould be removed into the green-houfe, or fome fiielter, and in the fpring may refmne their old Rations : and this fhould be repeated till they are of a; proper fize and ftrength to be planted out to ftand. If the pots in which they were firft planted were fmall, they rnay be fiiifted into larger a fpring or two after ; and, when they have got to be pretty ftrong plants, they may be turned out, mould and all, into the places where they are to remain. By this care of potting them, and houfing them during the fevere weather in winter, the young crop will be preferved ; otherwife, if they were planted immediately abroad, the firft hard froft the enfuing winter would deftroy them all : Tan- ner's bark about their roots ^will be the moft proper G 2 fecurityi Ca!ycan- themsB, Calycan« thus. C A L Calyciflors fecurlty ; as they are at beft, when tender plants, and muft have the warmell fituation and the drieft foil. CALYCIFLORiE, in botany, the i6th order in Linnaeus's Fragmenta mcthodi naturalis, confifting of Camaieu. plants which, as the title imports, have the ftamina (the flower) inferted into the calyx. This order con- tains the following genera, viz. eleagnus, hippophae, ©fyris, and trophis. See Botany, feft. vi. i6. CALYCISTtE (from cfl/yx the flower-cup), fy He- matic botanifl:s, fo termed by Linnaeus, who have ar- ranged all vegetables- from the different fpecies, ilruc- ture, and other circumftances, of the calyx or flower- cup. The only fyllems of this kind are the Chara8er plantarum novus, a pofthumous work of Magnolius, profeflbr of botany at Montpelier, publifhed in 1720 ; and LinnjEUs's Methodus calyc'ma, publiftied in his Clajfes plantarum^ at Leyden, in 1738. See Botany, p. 425. CALYDON, (anc. geog.)J a town of ./EoHa, fitu- ated feven miles and a half from the fea, and divided by the river Evenus : the country was anciently called Molts, from the TEolians its inhabitants. This country was famous for the ftory of Meleager and tha Calydo- nian boar. CALYPSO, in febulous hiftory, a goddefs, who was the daughter of Oceanus and Tethys, or, as others fay, of Atlas. She was queen of the ifland of Ogygia, which from her was called the ifland of Calypfo. Ac- cording to Homer, Ulyfles fuffered fhipwreck on her coaft, and ftaid with her feveral years. CALYPTRA, among botanifl.s, a thin membrana- c^us involucrum, ufually of a conic figure, which co- vers the parts of fruftification. The capfules of moft of the moffes have calyptrae. CALYX, among botanifl;s, a general term exprcf- fing the cup of a flower, or that part of a plant which furrounds and fupports the other parts of the flower. The cups of flowers are very various in their flruc- ture, and on that account diftinguifhed by feveral names, as perianth'ium, involucrum, fpatha, gluma, &c. See Botany, p. 439. CALZADA, a town of Old Cafl;ile in Spain, feat- €d on the river Leglera. W. Long. 2. 47. N. Lat. 42. 12. CAM-EA, in- natural hiftory, a genus of the femi- pellucid gems approaching to the onyx ftrufture, be- ing compofed of zones, and formed on a cryftaUine balls ; but having their zones very broad and thick, and laid alternately one on another, with no common matter between ; ufually lefs tranfparent, and more debafed with earth, than the onyxes, I. One fpecies of the camaea is th^ dull-looking onyx, with broad black and white zones ; and is the camaea of the moderns, and the Arabian onyx. This fpecies is found in Egypt, Arabia, Perfia, andtheEaft Indies. 2. Another fpecies of the cama»a is the dull broad zoned, green and white camsa, or the jafpi- cameo of the Itahans : it is found in the Eafl Indies, and in fome parts of America. 3. The third is tjie hard cam-cca, with broad white and chefnut coloured veins. 4. The hard camaea, with bhiifh, white, and flefli-co- loured broad veins, being the fardonyx of Pliny's time, cnly brought from the Eaft Indies. CAMAIEU, or Camay eu, a word ufed to exprefs 3. peculiar fort of onyx : aUo by fome to exprefs a [ j2 ] CAM full grown, but ftone, whereon are found various figures, and repre- C.v.n^ fentations of landscapes, &c. formed by a kind of lufus nature ; fo as to exhibit piftures without painting. The word eomes from camehulay a name the Orientals give to the onyx, when they find, in preparing it, a- aicu I rana. nother colour ; as who fliould fay, a fecond Jione, It is of thefe camaieux Pliny is to be underllood when he fpeaks of the manifold pifture of gems, and the party- coloured fpots of precious Hones : Gemmarum piSura tarn multiplex, lapidumque tarn difcolores macuU, Camaieu is alfo applied by others to thofe precious ftones, as onyxes, cornelians, and agates, whereon the lapidaries employ their art to aid nature, and perfect thofe reprefentations. See QA.tiiMk. Camaieu is alfo frequently applied to any kind of gem, whereon figures may be engraven either indent- edly or in relievo. In this fenfe the lapidaries of Pa- ris are called in their ftatutes, cutters of camayeux. A fociety of learned men at Florence undertook t» procure all the cameos or camayeux, and intaglios in the great duke's gallery to be engraven ; and began to draw the heads of divers emperors in cameos. Camaieu is alfo ufed for a painting, wherein there is only one colour ; and where the lights and fliadows are of gold, wrought on a golden or azure ground.^ When the ground is yellow, the French call it cirage ; when grey, grijfaile. This kind of work is chiefly ufed to reprefent baflb relievos : the Greeks call pieces of this fort ,ciOK);,jf a^ara. CAMALDULIANS, Camaldunians, or Ca- MALDOLiTES, an Order of religious, founded by Ro- muald, an Italian fanatic, in 1023, in the horrible defart of Camaldoli, otherwife called Canipo-Malduli, fituate in the itate of Florence, on the Apennines. Their rule is that of St Benedid ; and their houfes, by the ftatutes, are never to be lefs than five leagues from cities. The Camaldulians have not borne that title from the beginning of their order ; till the clofe of the eleventh century they were called Romualdins, from the name of their founder. Till that time, Ca- maldulian was a particular name for thofe of the defart Camaldoli; and D. Grandi obferves, was not given to the whole order, in regard it was in this monaftery that the order commenced, but becaufe the regulation was beft maintained here. Guido Grandi, mathematician of the great duke of Tufcany, and a monk of this order, has publiflied Camaldulian DifTertations, on the origin and eftablifhr ment of it. The Camaldolites were diftinguifhed into two clafTes, of which the one were coenobites, and the other EREMITES. CAMALODUNUM (anc. geog.), a town of the Trinobantes, the firlt Roman colony in Britain, of veterans, under the emperor. From the Itineraries it appears to have flood where now Maiden flands. It continued to be an open place under the Romans ; a place of pleafure rather than ftrength ; yet not un- adorned with fplendid works, as a theatre and a temple of Claudius : which the Britons confidered as badges of flavery, and which gave rife to feveral feditions and commotions. It ftands on a bay of the fea, at the mouth of the Chelmer, in the county of EfTex ; the modern name is curtailed from the ancient. CAM A RANA, an ifland of Arabia, in the Red Sea, whofe inhabitants are little and black. It is the bell CamaiTei II Camhaycs. CAM [53 befl: of all the iflands in this fea, and Htre they fi(h for coral and pearls. N. Lat. 15, o. CAMASSEI, or Camace, (Andrea), painter of hiftory and landfcape, was born at Bevagna, and at firft Icained the principles of defign and colouring from Domenichino ; but afterwards he ftudied in the fchool of Andrea Sacchi, and proved a very great painter. He was employed in St Peter's at Rome, as alfo at John Lateran ; and his works are extremely admired, for the fweetnefs of his colouring, the elegance of his thoughts and defign, and likewife for the delicacy of his pencil. Sandrart laments that the world was deprived of fo promifing a genius, in the very bloom of hfe, when his reputation was daily advancing. He died in 1 657. At St John Lateran are to be feen, the Battle of Con- fta'ntine and Maxentius ; and the Triumph of Con- ftantine ; which are noble and grand compofitions ; and they afford fyfficient proofs of the happinefs of his invention and the correftnefs of his execution. Alfo at Wilton, the feat of the earl of Pembroke, there is a pifture of Venus with the Graces, faid to be by the hand of Camaffei. CAMARCUM, (anc. geog.), the capital of the Nei vii, a people of Gallia Belgica, (Antonine, Peutin- ger) ; before whofe time no mention was made of it. Now Cambray, capital of the Cambrefis, in French Flanders, E. Long. 3. 15. Lat. 50. 15. CAMARINA, (anc. geog.), a city of Sicily, built by the Syracufans on an eminence near the fea, in the fouth of Sicily, to the well of the promontory Pachynum, between two rivers, the Hipparis and Oanus. Of fo famous a city nothing now remains but its name and ancient walls, a mile and a half in com- pals, with the flight remains of houfes : now called Camc3jrana. Camarii^a Pahs, a marfii or lake, near the city Ca- nnarina, and from which it took its name. In a tinne of drought, the llench of the lake produced a peftilence ; upon which the inhabitants confulted the oracle, whether they fhould not quite drain it. The oracle diffuaded them : they notwithitanding drained it, and opened a way for their enemies to come and plunder their city ; hence the proverb, Ne moveas Camarinam, that is, not to remove one evil to bring on a greater. Now Lago di Catnarana, fituate in a beautiful plain, under the very walls of Ca- marina, and of a triangular form. CAMAYEU. See Camaieu. CAMBAIA, or Campay, a tov/n of Afia, in In- dia, and in the peninfula on this fide the Ganges ; ca- pital of a province of the fame name ; but more com- monly called Gvzarat. It is feated at the bottom of a gulph of the fame name, on a fmall river; is a large place with high walls, and has a pretty good trade. The produft and maniifaftures are inferior to few towns in India ; for it abounds in corn, cattle, and filk ; and cornelian and agate ftoncs are found in its ri- vers. The inhabitants are noted for embroidery ; and fome of their quilts have been valued at 40!. It is fubjedl to the Great Mogul. E. Long. 72. 15. N. Lat. 2Z 30. CAMBAYES, in commerce, cotton cloths made at Bengal, Madras, and fc me other places on the coatl are proper of Cororcandcl. They for the trade of Marfeilles, whither the Enghfh at Madras fend great numbers uf them. Many are alfo imported into Holland. I. ] C A M CAMBER, according to our monkifh hlftorians, one of the three fons of Brute, who, upon his father's death, had that part of Britain affigned him for his , fhare, called from him Cambria now Wales. CAMBEK-Beam, among builders, a piece of timber in an edifice cut archwife, or with an obtufe angle in the middle, commonly ufed in platforms, as church- leads, and on other occafions where long and ftrong beams are required. CAMBERED-DECKS, among fiiip-builders. The deck or flooring of a fliip is faid to be cambered, or to lie cambering, when it is higher in the middle of the fhip's length, and droops toward the item and ftern, or the two ends. Alfo when it lies irregular; a circum- ftance which renders the fhip very unfit for war. CAMBERT, a French mufician in the 17th cen- tury, was at firft admired for the manner in which he touched the organ, and became fuperintendant of the mufic to Anne of Auftria the queen-mother. The abbe Perrin affociated him in the privilege he obtained of his majefty, of fetting up an opera in 1669. Cam- ber t fet to mufic two paftorals, one entitled Pomona^ the other /Iriachie, which were the firft operas given in France. He alfo wrote a piece entitled The pains and pleafures of love. Thefe pieces pleafed the public ; yet, in 1672, Lully obtaining the privilege of the opera, Cambert was obliged to come to England, where he became fuperintendant of the mufic to king Charles II. and died there in 1677. CAMBIO, an Italian word which fignifies ^^cf^ijw^^; commonly ufed at Province, and in fome other coun- tries, particularly Holland. CAMBIST, a name given in France to thofe who trade in notes and bills of exchange. The word cam- bift, though a term of antiquity, is even now a technical word, of fome ufe among merchants, traders, and bank- ers. Some derive it from the Latin cambium^ or ra- ther caml'io. CAMBLET, or Chamblet, a ftuff fometimes of wool, fometimes filk, and fometimes hair, efpecially that of goats, with wool or filk : in fome, the warp is filk and wool twifted together, and the woof hair. The true or oriental camblet is made of the pure hair of a fort of goat, frequent about Angora, and which makes the riches of that city, all the inhabitants whereof are employed in the manufafture and com- merce of camblets. It is certain we find mentioned in middle-age writers ftuffs made of camel's hair, un- der the denominations of cameletum and camelinumy whence probably the origin of the term ; but thefe are reprefented as ftrangely coarfe, rough, and prick- ly, and feem to have been chiefly ufed among the monks by w^iy of mortification, as the hair-ihirt of la- ter times. We have no camblets made in Europe of the goats hair alone ; even at BrufTels, they find it neceffary to add a mixture of woollen thread. England, France, Holland, and Flanders, are the chief places of this manufafture. Btuffels exceeds them all in the beauty and quality of Its camblets : thofe of Ensrland are reputed the fecond. Figured Caubl&^s^ are thofe of one colour, whereon are ftampcd various figures, fiowers, foliage, &c. by means of hot ironr, which are a kind of moulds, paffed together with the ftuff, under a prefs. Thefe are chief- Camber II Camblet. CAM C 54 3 CAM II Catnbray. ly brouglit From Amiens and Flaaders : the commerce of thefe was anciently much more conliderable than at prefent. Watered- Camblets, thofc which, after weaving, re- ceive a certain preparation with water ; and are after- wards pafled under a hot-prefs, which gives them a fmoothnefs and luftre. Waved-CAMBLETSf are thofe whereon waves are im- preffed, as on tabbies ; by means of a calender, under which they arc pafled and repafTed feveral times. The manufafturers, &c. of camblets are to take care they do not acquire any falfe and needlefs plaits ; it be- ing almoft impoflible to get them out again. This is notorious, even to a proverb : we fay, a perfon is like camblet, he has taken his plait. CAMBODIA, a kingdam of Afia, in the Eaft In- dies, bounded on the north by the kingdom of Laos, on the «aft by Cochin-China and Chiapa, and on the fouth and weft by the gulph and kingdom of Siam ; divided by a large river called Mecon. The capital ■town is of the fame name, feated on the weftern fhore of the faid river, about 1 50 miles north of its mouth. This country is annually overflowed in the rainy feafon, between June and Oftober ; and Its produc- tions and fruits are much the fame with thofe ufually found between the tropics. E.Long. 104. 15. N. Lat. 12. 40. CAMBODUNUM, (Itinerary ); a town of the Brigantes, in Britain ; now in ruins, near Almonbury, for arms is of an extraordinary largenefs, and capable Cambray of receiving the whole garrifon in order of battle. The H cathedral dedicated to the Virgin Mary is one of the ^ ' finefl in Europe. The body of the church is very large, and there are rich chapels, the pillars of which are a- dorned with marble tombs that are of exquiiite work- manship, and add greatly to the beauty of the place. There are two galleries, one of which is of copper, finely wrought. The door of the choir is of the fame metal, and well carved. The fteeple of this church is very high, and built in the form of a pyramid ; and from its top you have a view of the city, which is one of the fineft and moll agreeable in the Low Coun- tries. There are nine parilhes, four abbeys, and fe- veral convents for both fexes. The citadel is very ad- vantageoufly fitiiated on high ground, and commands the whole city. Cambray is one of the moft opulent and commercial cities in the Low Countries ; and makes every year a great nuniher of pieces of cambric, with which the inhabitants drive a great trade. E. Long. 3. 20. N. Lat. 50. II. Cambray (M. de Fenelon, archbifhop of). See Fenelon. CAMBRESIS, a province of France, in the Nether- lands, about 25 miles in length. It is bounded on the north and eaft by Hainhalt, on the fouth by Picardy, and on the weft by Artois. It is a very fertile and populous country ; and the inhabitants are iuduftrious, a- perior honour to produce the author of the Lufiad. Early in his life the misfortunes of the poet began. In his infancy, Simon Vaz de Camoens, his father, commander of a vefTel, was flilpwrecked at Goa, where, with his life, the greateft part of his fortune was lofl. His mother, however,, Anne de Macedo of Santarene, provided for the education of her fon Louis at the uni- verfity of Colmbra. What he acquired there, his works difcover ; an intimacy with the clafilcs, equal to that of a Scaliger, but diredled by the talte of a Mil- ton or a Pope. When he left the univerfity, he appeared at court. He was handfome ; had fpeaking eyes, it is faid ; and the finefl comj^lexion. Certain it is, however, he was a polifhed fcholar, w-hlch, added to the natural ardour and gay vivacity of his difpofitlon, rendered him an accomplifhed gentleman. Courts are the fcenes of in- trigue ; and intrigue was faflilonable at Lifbon. But the particulars of the amours of Cam.oens reft unknown. This only appears : he had afpired above his rank, for he was banlfhed from the court ; and in feveral of his fonnets he afcribes this misfortune to love. He now retired to his mother's friends at Santarene. Here he rcnev.'ed his ftudies, and began his poem on the difcovery of India. John III. at this time prepared an armament againft Africa. Camoens, tired of his in- aftive obfcure life, went to Ceuta in this expedition, and greatly diftlngulfhcd his valour in feveral rencoun- ters. In a naval engagement with tlie Moors in the ftraits of Gibraltar, in the confllfl of boarding, he was among the foremoft, and loft his right eye. Yet nei- ther hurry of aftual fervice nor the diffipation of the camp could ftifle his genius. He continued his Lnji-' adcis, and feveral of his moft beautiful fonnets were written in Africa, while, as he expreffed it. One hand the pen, and one the fword, employ'd. The fame of his valour had now reached the courts and he obtained permiffion to return to Lifbon. But, while he folicited an eftablifhment which he had merit- ed in the ranks of battle, the malignity of evil tongues, as he calls it in one of his letters, was injurioufly pour- ed upon him. Though the bloom of his early youth was effaced by feveral years refidence under the fcorch- ing heavens of Africa, and though altered by the lofs of an ej'-e, his prefence gave uneafinefs to the gentle- men of fome families of the firft rank where he had formerly vifited. Jealoufy is the charafterlftlc of the Spanifh and Portuguefe ; its refentment knows no bounds, and Camoens now found it prudent to banlfh himfelf from his native country. Accordingly, in ^553» -^^ failed for India, with a refolution n&ver to return. As the fhip left the Tagus, he exclaimed, it* the words of the fepulchral monument of Scipio Afri- canus, Ingrata patria^ non foJfideVis oJ[u meal " Ungrate- ful CAM [ 63 ] CAM #amoenif. ful country, thou (halt not poflefs my bones !'* But he ~Y"— knew not what evils in the Eaft would awake the re- membrance of his native fields. When Camoens arrived in India, an expedition was ready to fail to revenge the king of Cochin on the king of Pimenta. Without any reft on flrore after his long voyage, he joined this armament,, and in the conqueft of the Alagada iflands dilplayed his ufual bravery. In the year following, he attended Manuel de Vaf- concello in an expedition to the Red Sea. Here, fays Faria, as Camoens had no ufe for his fword, he em- ployed his pen. Nor was his aftivity confined in the fleet or camp. He vifited Mount Felex and the adja- cent inhofpitable regions of Africa, which he fo flrongly piftures in the Luliad, and in one of his little pieces where he laments the abfence of his miftrefs. ' When he returned to Goa, he enjoyed a tranquillity which enabled him to bellow his attention on his Epic Poem. But this ferenity was interrupted, perhaps by his own imprudence. He wrote fome fatires which gave oflFence ; and, by order of the viceroy Francifco Barreto, • he was banifhed to China. The accompli diments and manners of Camoens foon found him friends, though under the difgrace of banilh- mcnt. He was appointed commifTary of the defunft in the ifland of Macao, a Portuguefe fettlement in the bay of Canton. Here he continued his Luliad ; and here alfo, after five years refidence, he acquired a fortune, though fmall, yet equal to his wifhe?. Don Conftantine de Braganza was now vicei-oy of India ; and Camoens, defirous to Return to Goa, refigned his charge. In a fliip, freighted by hirafelf, he fet fail ; but was ftiip- wrecked in the gulph near the mouth of the river Me- hon on the coaft of China. All he had acquired was loil in the waves:, his poems, which he held in one hand, while he fwimmed with the other, were all he found himfelf pofleffed of when he flood friendlefs on the unknown fnore. But the natives gave him a raoft humane reception : this he has immortalifed in the pro- phetic fong in the tenth Lufiad ; and in the feventh, he tells us, that here he loft the wealth which fatisfied his wi flies. Agora da efferancia ja adgu'iridii , Isfc, Now bleft wi.h all the wealth fond hope could crave. Soon I beheld that wealth beneath the wave For ever loft ; My life, like Judah's heaven-doom'd king-of yore, by nriracle prolong'd On the banks of the Mehon, he wrote his beautiful paraphrafe of the pfalm, where the Jews, in the fineft llrain of poetry, are reprefented as hanging their harps on the willdws by the rivers of Babylon, and weeping their exile from their native country. Here Camoens continued fome time, till an opportunity offered to carry him to Goa. When he arrived at that city, Don Con- ftantine de Braganza, the viceroy, whofe charadleriftic was politenefs, admitted him into intimate friendfhip, and Camoens was happy till count Redondo affumed the government. Ttiofe who had formerly procured the banifhment of the fatirift, were filent while Con- ftantine was in power ; . but now they exerted all their arts againft him. Redondo, when he entered on office, pretended to be the friend of Camoens; yet, with all that unfeeling indifference with which he made hia moft 3. horrible witticlfm on the Zamorim, he fuffered the in- Camoens. nocent man to be thrown into the common prifon. » ' ' After all the delay of bringing witneffes, Camoens, in a public trial, fully refuted every accufation of his con- dutt while coinraiffary at Macao, and his enemies were loaded with ignominy and reproach. But Camoens had fome creditors; and thefe-detained him in prifon acon- fiderable time, till the gentlemen of Goa began to be afhamed that a man of his fingular merit fhould expe- rience fuch treatment among them. He was fet at li- berty ; and again he affumed the profeffion of arms, and i-eceived the allowance of a gentleman volunteer, a character at this time common in Portuguefe India. Soon after, Pedro Barreto, appointed governor of the - fort at Sofala, by high promifes, allured the poet to attend him thither. The governor of a diftant fort, in a barbarous country, flrares in fome meafure the fate of an exile. Yet, though the only motive of Barreto was, in this unpleafant fituation, to retain the converfation of Camoens at his table, it was his leaft care to render the life of his gueft agreeable. Chagrined with his treatment, and a confiderable time having elapfed in vain dependence upon Barreto, Camoens refolved to re- turn to his native country. A rtiip, on the homeward voyage, at this time touched at Sofala, and feveral gen- tlemen who were on board were defirous that Camoens ■ " fliould accompany them. But this the governor unge- neroufly endeavoured to prevent, and charged him with , a debt for board. Anthony de Cabra, however, and ■ Hedor de Sylveyra, paid the demand ; and Camoens, . fays Faria, and the honour of Barreto, were fold to- gcther. After an abfence of 16 years, Camoens, in 1569, re- turned to Lift)on, unhappy even in his arrival, for the peftilence then raged in that city, and prevented his * publication for three years. At laft, in 1572, he printed his Lufiad, which, in the opening of the firft book, in a moft elegant turn of comphment, he addreffed to his prince, king Sebaftian, then in his i8th year. The king, fays the French tranflator, was fo pleafed with his merit, that he gave the author a penfion of 4000 reals, on condition that he Ihould rcfide at court. But this falary, fays the fame waiter, was withdrawn by car dinal Henry, who fucceeded to the crown of Portugal, , loft by Sebaftian at the battle of Alcazar. Though the great patron of one fpecies of literature, . a fpecies the reverfe of that of Camoens, certain it is, , that the author of the Lufiad was utterly neglefted by Henry, under whofe inglorious reign he died in all the mifery of poverty. By fome, it is faid, he died in an - alms-houfe. It appears, however, that he had not even the certainty of fubfiftence which thefe houfes provide. He had a black fervant, who had gi-own old with him, . and who had long experienced his mafter's humanity. This grateful Indian, a native of Java, who, according to fome writers, faved his mafter's fife in the unhappy fhipwreck where he loft his effefts, begged in the ftreets - of Lifbon for the only man in Portugal on whom God had beftovved thofe talents which have a tendency to ereft the fpirit of a downward age. To the eye of a careful obferver, the fate of Camoens throws great light on that of his country, and will appear ftriftly connec- ted with it. The fame ignorance, the fame degenerated ; fpirit, which fuffered Camoens to depend on his fhare of the alms begged in the ftreets by his old hoary fer- CAM [ Cnmomile, vant, tlie fame fpirit which caufed this, funk the king- ' i ' . ^^"'^' Portugal into the mod abjeft vaflalage ever ex- perienced by a conquered nation. While the grandees of Portugal were blind to the ruin which impended over them, Camoens beheld it with a' pungency of grief which haftened his exit. In one of hi? letters he has thefe remarkable words : £m Jim accaberey a vida, c verram todos que fay efeicoada a minho patria, Iffc "I am ending the courfe of my life, the world will witnefs how I have loved my country. I have returned, not only to die in her bofom, but to die with her." In this unhappy fituation, in 1579, in his 62d year, the year after the fatal defeat of Don Sebaftian, died Louis de Camoens, the grcateft literary genius ever produced by Portugal ; in martial courage and fpirit of honour, nothing inferior to her greateft heroes. And in a manner fuitable to the poverty in which he died, v/as he buried. CAMOMILE, in botany. S ee Anth£mis. CAMP, the ground 00 which an army pitch their tents. It is marked out by the quarter-mafter general, who appoints every regiment their ground. The chief advantages to be minded In chufing a camp for an army, are, to have it near the water, in a coun- try of forage, where the foldiers may find wood for dreffing their victuals ; that it have a free communica- tion with garrifons, and with a country from whence it may be fupplied with provlfions ; and, if polTible, that it be fituated on a rifing ground, in a dry gravelly foil. Befides, the advantages of the ground ought to be confidered, as marfhes, woods, rivers, and inclofurcs; and if the camp be near the enemy, with no river or marfh to cover it, the army ought to be intrenched. An army always encamps fronting the enemy ; and ge- nerally in two lines, running parallel about 500 yards diftance ; the horfe and dragoons, on the wings, and the foot, in the centre : fomctlmes a body of two, three, or four brigades is encamped behind the two lines, and is called the body of referve. The artillery and bread- ivaggons are generally encamped in the rear of the two lines. AJiattalion of foot is allowed 80 or 100 paces for its camp ; and 30 or 40 for an interval betwixt one battalion and another. A fquadron of horfe is allowed 30 for ics camp, and for an Interval, and more if the ground will allow it. Where the grounds are equally dry, thofe camps are always the moft healthful that are pitc led on the banks of large rivers ; becaufe, in the hot feafon, fituations of this kind have a ftream of frefh air from the water, ferving to carry off the molft and putrid exhalations. On the other hand, next to marfhes, the woril encamp- menfs are on Ibw grounds clofe befet with trees ; for then the air is not only molll and huitful in itfelf, but by ^agnating becomes more fufceotible of corruption. However, let the fituation of camps be ever fo good, they are frequently rendered infeftlous by the putrid ef- fluvia of rotten ftraw, and the privies of the army ; more efpeclally if the bloody flux prevails, in which cafe the bert method of preventing a general infeflion, is to leave the ground with the privies, foul ftraw, and other filth of the camp, behind. This mull be frequently done, If confiflent with the military operations : but when thefe render it improper to change the ground often, the pri- vies (hould be made deeoer than ufual, ajid once a-day ..N'62. 64 ] CAM a. thick layer of earth thrown into them till the pits are near full ; and then they are to be well covered, and* fupplied by others. It may alfo be a proper caution to order the pits to be made either in the front or the rear, as the then ftationary winds may beft carry off their effluvia from th« camp. Moreover, it will be ne- ceflary to change the ftraw frequently, as being not only apt to rot, but to retain the infeftlous fteams of the fick. But if frefti ftraw cannot be procured, more cate muft be taken in airing the tents, as well as the old ftraw. The difpofition of the Hebrew encampment was at firft laid out by God himfelf. Their camp was of a quadrangular form, forrounded with an inclofure of the height of 10 hands-breadth. It made a fquare of 12 miles in compafs about the tabernacle ; and within this was another, called the Levitet camp. The Greeks had alfo their camps, fortified with gates and ditches. The Lacedaemonians made their camp of a round figure, looking upon that as the moft perfeA and defenfible of any form : we are not, however, to imagine, that they thought this form fo efTcntial to a camp, as never to be dlfpenfed with^when the circum- ftances of the place require it. Of the reft of the Gre- cian camps, it may be obferved, that the moft vahant of the foldiers were placed at the extremities, the reft in the middle. Thus we learn from Homer, that Achilles and Ajax were pofted at the ends of the camp before Troy, as bulwarks on each fide of the reft of the princes. The figure of the Roman camp was a fquare divided into two principal parts : in the upper parts were the general's pavilion, or praztorium, and the tent of the chief officers ; in the lower, thofe of inferior degree were placed. On one fide of the prjetorlum ftood the quaeftorium, or apartment of the treafurer of the army; and near this the forum, both for a market-place and the aflembling of councils. On the other fide of the prJEtorium were lodged the legati ; and below it the tribunes had their quarters, oppofite to their re- fpeftlve legions. Afide of the tribunes were the pros- fefti of the foreign troops, over agalnft their refpeftlve wings ; and behind thefe were the lodgments of the evocati, then thofe of the extraordinarii and ablefti equitcs, which concluded the higher -part of the camp. Between the two partitions was a fpot of ground called pritjcipia, for the altars and images of the gods, and probably alfo for the chief enfigns. The middle of the lower partition was affignedto the Roman horfe ; next to them were quartered the triarii ; then the princlpes, and clofe by them the haftati ; afterwards the foreign horfe, and laftly the foreign foot. They fortified their camp with a ditch and parapet, which they term- ed fojfj and vallum ; in the latter fome dlftlnguHh two parts, viz. the agger or earth, and the fades or wooden Itakes driven in to fecure it. The camps were fome- times furrounded by walls made of hewn ftone ; and the tents themfelves formed of the fame matter. In the front of the Turkifh camp are quartered the janizaries and other fool, whofe tents encompafs their aga : in the rear are the quarters of the fpahis and other horfemen. The body of the camp is poffeftcd by the ftately tents or pavihons. of the vizer or general, rals effendl or chancellor, kahija or fteward, the tefter- dar baftiaw or Igrd treafurer, and kapiflar kahiafee or mafter Camp. CAM [ Camp mafter of the ceremonies. In the middle of thefe tents II . is a fpacious field, wherein are erecfted a building for Cam paign. j]van, and a hafna or treafury. When the ground is marked out for a camp, all wait for the pitching of the tent /al/ac, the place where the courts of juftice are held ; it being the difpofition of this that is to re- gulate all the reft. The Arabs ftill live in camps, as the ancient Scenites did. The camp of the Affyne Emir, or king of the country about Tadmor, is defcribed by a traveller who viewed it, as fpread over a very large plain, and pof- fefTmg fo vaft a fpace, that though he had the ad- vantage of a rlfmg ground, he could not fee the utmoft extent of it. His own tent was near the mid- dle ; fcarce diftinguiOiable from the reft, except that it was bigger, being made, like the others, of a fort of hair-cloth. Camp, is alfo ufed by the Siamefe, and fome other nations in the Eaft Indies, as the name of the quarters which they afiign to foreigners who come to trade with them. In thefe camps, every nation forms, as it were, a particular town, where they carry on all their trade, not only keeping all their warehoufes and (hops there, but alfo live in thefe camps with their whole families. The Europeans, however, are fo far indulged, that at Siam, and almoft every where elfe, they may live either in the cities or fuburbs, as they fhall judge moft. con- venient. Camv fght, or K^MP fight t in law writers, denotes the trial of a caiife by duel, or a legal combat of two thampions in the field, for decifion of fome contro- verfy. In the trial by camp fight, the accufer was, with the peril of his own body, to prove the accufed guilty; and by offering him his glove, to challenge him to this trial, which the other mull either accept of, or ac- knowledge himfelf guilty of the crime whereof he was accufed. If it were a crime defcrving death, the camp fight was for life and death : if the offence deferved only Imprifonment, the camp fight was accompliihed when one combatant had fubdued ihe other, fo as either to make him yield or take him prifoner. The accufed had liberty to choofe another to fight in his ftead, but the accufer was obliged lo perform it in his own per- fon, and with equality of weapons. No women were permitted to be fpedlators, nor men under the age of thirteen. The pricft and the people who looked on, were engaged filently in prayer, that the viAory might fall to him who had right. None might cry, fiiriek, or give the leaft fign ; which in fome places was exe- cuted with fo much ftriAnefs, that the executioner llood ready with an axe to cut off the right hand or foot of the party that fliould offend herein. He that, being wounded, yielded himfelf, was at the other's mercy cither to be killed or fufi^ered to live. But if life were granted him, he was declared infamous by the judge, and dilabled from ever bearing arms, or ri- ding on horfeback. CAMPAGNA. See Campania. ■CAMPAIGN, in the art of war, denotes the fpace of time that an army keeps the field, or is encamped. — Theb eginning of every campaign is confiderably more unhealthy than if the men were to rerr.ain in quarters. After the firft fortnight or tiiree weeks encampment, Vol. IV. Part. L 65 1 CAM the ficknefs decreafes daily; the moft .infirm being byCapahaccae that time in the hofpitals, and the weather daily grow- J'j^j^jj ing warmer. This healthy ftate continues throughout ^'^f the fummer, unlefs the men get wet clothes or wet beds ; in which cafe, a greater or lefs degree of the dy- fentery will appear in proportion tq the preceding heats. But the moft fickly part of the campaign begins about the middle or end of Auguft, whilft the days are ftill hot, but the nights cool and damp, with fogs and dews : then, and not fooner, the dyfentery prevails ; and though its violence is over by the beginning of Oftober, yet the remitting fever gaining ground, con- tinues throughout the reft of the campaign, and never entirely ceafes, even in winter-quarters, till the frofts begin. At the beginning of a campaign the ficknefs is fo uniform, that the number may be nearly predided ; but for the reft of the feafon, as the difeafes are then of a contagious nature, and depend fo much upon the heats of fummer, it is impoffible to forefee how many- may fall fick from the beginning to the end of autumn. It is alfo obferved, that the laft fortnight of a cam- paign, if protrafted till the beginning of a campaign, is attended with more ficknefs than the firft two months encampment : fo that it is better to take the field a fortnight fooner, in order to return into winter-quar- ters fo much the earlier. As to winter expeditions, though fevere in appearance, they are attended with httle ficknefs, if the men have ftrong ftioes, quarters, fuel, and provifions. Long marches in fummer are not without danger, unlefs made in the night, or fo early in the morning as to be over before the heat of the day. CAMPANACEJ^., in botany, an order ofplantsin* Sce5».^ the Fragmenta jnethodi naturalis of Linnseus, in which are the following genera, viz. convolvulus, ipomasa, polemonium, campanula, roella, viola, &c. * CAMPANELLA (Thomas,) a famous Italian philofopher, born at Siilo in Calabria, in 1 568. He dillinguifhed himfelf by his early proficiency in learning ; for at the age of 13 he was a perfeft mafter of the ancient orators and poets. His peculiar inclina- tion was to philofophy, to which he at laft confined his whole time and fiudy. In order to arrive at truth, he fliook off the yoke of authority : by which means the novelty of fome of his opinions expofed him to many inconveniences ; for at Naples he was thrown into prifon, in which he remained 27 years, and du- ring this confinement wrote his famous work entitled Atheifnius triumphatus. Being at length fet at liberty, he went to Paris, where he was gracioufly received by Louis XIII. and cardinal Richelieu ; the latter pro- cured him a penfion of 2000 livres, and often confulted him on the affairs of Italy. Campanella paffed the re- mainder of his days in a monaftery of Dominicans at Paris, and died in 1639. .CAMPANI (Matthew) of Spoletto, curate at Rome, wrote a curious treatife on the art of cutting' glaffes for fpeftacles, and made feveral improvements in optics, allifted by his brother and pupil Jofeph. He died after 1678. CAMPANIA.a town of Italy, in the kingdom of Naples, and in the farther principato, with a biftiop's fee. E. Long. 15. 30. N. Lat. 4c. 40. Campania or Campagna di Roma, anciently La- tium, a province of Italy, bounded on the weft by the I Tiber CAM [ 66 ] CAM Campania. Tibet" and the fea, on the foutli-weftby tlie fea, on the """^ fouth by Terra di Lavoro, on the eail by Abruzzo, and on the north by Sabina. Though the foil is good, it produces little or nothing, on account of the heavy duties on corn ; and though the waters are good, the air is unwholefome. It is fubjefl to the Pope, and is about 60 miles in length on the Mediterranean fea. It hath been generally thought that the air of this country hath fomething in it pepuliarly noxious du- ring the fummer-time ; but Mr Condamine is of opinion that it is not more unhealthy than any other marfhy country. His account follows. " It was after the in- vafion of the Goths in the fifth and fixth centuries that this corruption of the air began to manifell itfelf. The bed of the Tiber being covered by the accumulated ruins of the edifices of ancient Rome, could not but raife itfelf confiderably. But what permits us not to doubt of this fa6t is, that the ancient and well-preferved pavement of the Pantheon and its portico is overflowed every winter; that the water even rifes there fometimes to the height of eight or ten feet ; and that it is not poflible to fuppofe tliat the ancient Romans fhould have built a temple in a place fo low as to be covered with the waters of the Tiber on the leaft inundation. It is evident, then, that the level of the bed of this river is raifed fevtral feet ; which could not have happened without forming there a kind of dikes or bars. The choaking up of its canal neceffarily occafioned the over- flow and reflux of its waters in fuch places as till then had not been fubjeft to inundations : to thefe over- flowings of the Tiber were added all the waters that efcaped out of the ancient acquedufts, the ruins of which are fl;iU to be feen, and which were entirely broken and dellroyed by Totila. What need, therefore, of any thing more to infeft the air, in a hot climate, than the exhalations of fuch a mafs of fliagnating waters, depri- ved of any difcharge, and become the receptacle of a thoufand impurities, as well as. the grave of feveral mil- lions both of men and animals? The evil could not but increafe from the fame caufes while Rome was expofed to the incurfions and devaftions of the Lombards, the Normans, and the Saracens, which lafted for feveral centuries. The air was become fo infeftious there at the beginning of the 1 3th century, that Pope Inno- cent III. wrote, that few people at Rome arrived to the age of forty years, and that nothing was more uncommon-there than to fee a perfon of fixty. A very fhort time after, the popes transferred the feat of their refidence to Avignon : during the feventy-two years they remained there, Rome became- a defert ; the mo- pafteries in it were converted into llabks ; and Gre- gory XL on his return to Rome, in 1376, hardly counted there 30,.ooo inhabitants. At his death began the troubles of the great fchifm in the wefl;, which con- tinued for upwards of 50 years. Martin V. in whom this fchifm ended' in the year 1429, and his firft fuccef- fors, were able to make but feeble efi^orts againft fo in- veterate an evil. It was not till the beginning of the 16th. century that Leo X. under whom Rome began to relume her wonted fplendor, gave himfelf fume trouble about re-eftablilhing the falubrity of the air : but the city, being ihortly after befieged- twice fucccflively by the emperor Charles V. fiiw itfelf plunged again into all its old calamities; and from 85,000 inhabitants, -.vhich it contained under Leo X, it was reduced under Clement VIII. to 32,000. In rtiort, it is only fmce the Campari- time of Pius V. and Sextus V. at the end of the i6th ^"' "^ century, that the pones have conftantlv employed the 1 neceliary methods tor purirymg the air 01 Rome and -, its environs, by procuring proper dii'charges for the waters, drying up the humid and marlby grounds, and covering the banks of the Tiber and other places repu- ted uninhabitable with fuperb edifices. Since that tinie a perfon may dwell at Rome, and go in or out of it at all feafons of the year. At the beginning, however, of the prefent century, they were ftill afraid to lie out of the city in fummer, when they had refided there ; as they were alfo to return to it, when once they had quitted it. They never ventured to fleep at Rome, even in broad day, in any other houfe than their own.. They are greatly relaxed at prefent from thefe ancient fcruples : I have feen cardinals, in the months of July and Auguft, go from Rome to lie at Frafcati, Tivoli, Albano, &c. and return the next or the following days to the city, without any detriment to their health : I have myfelf tried all thefe experiments, without fufFer- ing the leaft inconvenience from them : we have even feen, in the laft war in Italy, two armies encamped under the walls of Rome at the time when the heatSr were moft violent. Yet, notwithftanding all this, the greater part of the country people dare not ftill ven- ture to lie during that feafon of the year, nor even as much as fleep in a carriage, in any part of the terri- toiy comprehended under the name of the Campagna of Rome." CAMPANIFORM, or Campanulated, an appel- lation given to flowers refembling a bell. CAMPANINI, a name given to an Italian marble dug out of the mountains of Carrara, becaufe, when it is worked, it founds like a bell. CAMPANULA, or bell-flower; A genus of the monogynia order, belonging to the pentandria clafs of plants ; and in the natural method ranking: under the 29th order, Carnpavacea. The corolla i& campanulated, with its fundus clofed up by the valves- that fupport the ftamina; the ftigma is trifid; the cap- fule inferior, or below the receptacle of the flower^ opening and emitting the feeds by lateral pores. Species. Of this genus there are no fewer than 41 fpecies enumerated by botanical writers ; but the fol- lowing are the moft worthy of attention, i . The pyra- midalis hath thick tuberous roots filled with a milky- juice ; it fends out ftrong, fmooth, upright ftalks,. which rife to the height of four feet, garniflied with fmooth oblong leaves a little indented at the edges. The flowers are produced from the fide of the ftalks, and are regularly fet on for more than half their length, forming, a fort of pyramid ; thefe are large, open, and fliaped like a bell. The moft common colour of the flowers is blue, though fome are white, but the former are moft efteemed. 2. The decurrens, or peach-leaved bell-flower, is a native of the northern parts of Lurope z of this there are fome with white, and fome with blue flowers, and fome with double flowers of both colours- Thefe laft have of late been propagated in fuch abun- dance- as to have almoft baniflied from the gardens thofe with fingle flowers. 3. The medium, commonly called Canterbury lell-Jloiver, is a biennial plant, which periflies foon after it has ripened its feeds. It grows ttftturally in . the woods of Italy and Auftria ; but i* cuL CAM C 67 ] CAM Cimpanula, cultivated in the Britilh gardens for the beauty of its ""V"-' flowers, which are blue, purple, white, and llriped, with double flowers of all the colours. This fpecies hath ob- long, rough, hairy, leaves, ferrated on their edges : from the centre of thefe rifes a ftiff, hairy, furrowed Aalk, about two feet high, fending out feveral lateral branches, garnifhed with long, narrow, hairy leaves fawed on their edges. From the fetting on of thefe leaves proceed the footftalks of the flower; thofe which are on the lower part of the flialk and branches diml- niibing gradually in their length upwai'd, and thereby forming a fort of pyramid. The flowers of this kind are very large, fo make a fine appearance. The feeds ripen in September, and the plants decay foon after. 4. The trachelium, with nettle leaves, hath a peren- nial root, which fends up feveral fl;iff" hairy ftalks ha- ving two ribs or angles. Thefe put out a few flaort fide-branches, garniflied with oblong hairy leaves deep- ly fawed on their edges. Toward the upper part of the fl:alks, the flowers come out alternately upon fliort trifid foot-fl;alks having hairy empalements. 1'he colours of the flowers are a deep and a pale blue and white, with double flowers of the fame ; the double- flowered kind only merit a place in gardens. 5, The latifolia, or greatefl: bell-flower, hath a perennial root, compofed of many flefliy fibres that abound with a milky juice. From thefe arife feveral flirong, round fmgle flialks, which never put out branches, but are ^aiTiifhed with oval fpear-fliaped leaves flightly indent- ed on their edges. Towards the upper part of the fl:alk the flowers come out fingly upon fliort foot-fl:alks; their colours are blue, purple, and white. 6. The rapunculus, or rampion, hath roundirti flefliy roots, which are eatable, and much cultivated in France for fallads ; fome years pafl; it was cultivated in the Eng- lifti gardens for the fame purpofe, but is now general- ly neglefted. It is a native of Britain ; but the roots of the wild fort never grow to half the fize of thofe which are cultivated. 7. The fpeculum, with yellow €ye-bright leaves, is an annual plant with flender fl;alks riling a foot high, branching out on every fide, and garniflied with oblong leaves a little curled on their edges ; from the wings of the leaves come out the flowers fitting clofe to the ftalks, which are of a beau- tiful purple inclining to a violet colour. In the even- ing, they contrail and fold into a pentagonal figure ; from whence it is by fome called viola pent agonia, or Jive-cornered violet. 8. The hybrida, or common Venus looking-glafs. This feldom rifes more than fix inches high, with a ftalk branching from the bottom upward, and garniflied with oval leaves fitting clofe to the ftalks, from the bafe of which the branches are pro- duced, which are terminated by flowers very like the former fort. This was formerly cultivated in the gar- dens: but fince the former kind hath been introduced, it hath almoft fupplanted this ; for the other is a much taller plant, and the flowers larger, though of a lefs beautiful colour. 9. The canarienfis, with an orach leaf and tuberous root, is a native of the Canary iflands. It hath a thick flefliy root of an irregular form; fome- times running downward like a parfnip, at other times dividing into feveral knobs near the top ; and when any part of the root is broken, there iflues out a milky juice at the wound. From the head or crown of the root arife one, two, three, or more ftalks, in propor- tion to the fize of the root ; but that in the centre isCampanuU, generally larger, and rifes higher, than the others. * ' ^ Thefe ftalks are very tender, round, and of a pale green; their joints are far diftant from each other; and when the roots are ftrong, the ftalks will rife to ten feet high, fending out feveral lateral branches. At each joint they are garniflied with two, three, or four fpear-fliaped leaves, with a fliarp pointed beard on each fide. They are of a fea-green ; and, when they firft come out, are covered flightly with an afli-coloured pounce. From the joints of the ftalk the flowers are produced, which are of the perfeft bell-fliape, and hang downward ; they are of a flame-colour, marked with ftripes of a brownifli red : the flower is divided into five parts ; at the bottom of each is feated a nec- tariuni, covered with a white tranfparent flcin, much refembling thofe of the crown imperial, but fmaller. The flowers begin to open in the beginning of Ofto- ber, and there is often a fucceflion of them till March. The ftalks decay to the root in June, and new ones fpring up in Auguft. Culture, &c. The firft fort is cultivated to adorn halls, and to place before chininies in the fummer whtn it is in flower, for which purpofe there is no plant m,ore proper ; for when the roots are ftrong, they will fend out four or five ftalks which will rife as many feet high, and are adorned with flowers a great part of their length. When the flowers begin to open, the pots are removed into the rooms, where, being fliaded from the fun and rain, the flowers will continue long in beauty ; and if the pots are every night removed into a more airy fituation, but not expofed to heavy rains, the flowers will be fairer, and continue much longer in beauty. Thofe plants which are thus treated, are fel- dom fit for the purpofe the following feafon ; therefore a fupply of young ones muft be annually railed. The plant may be propagated either by dividing the roots or by feeds, but the latter produce the moft vigorous and beft flowering plants. The feeds muft be fown in autumn in boxes or pots filled with light undunged earth, and placed in the open air till the froft or hard rains come on : then they muft be placed under a hot- bed frame, where they may be ftieltered from both ; but in mild weather the glafles fliould be drawn off every day, that they may enjoy the free air : with this management the plants will come up early in the fpring, and then they muft be removed out of the frame, pla- cing them firft in a warm fituation ; but, when the feafon becomes warm, they fliould be fo placed as to have the morning fun only. In September the leaves of the plants will begin to decay, at which time they fliould be tranfplanted ; therefore there muft be one or two beds prepared, in proportion to the number of plants. Thefe beds muft be in a warm fituation, and the earth light, fandy, and without any mixture of dung. The plants muft then be taken out of the pots or cafes very carefully, fo as not to bruife their roots; for they are very tender, and on being broken the milky juice wiU flow out plentifully, which will greatly weaken them. Thefe fliould be planted at a- bout fix inches diftance each way, with the head or crown of the root half an inch below the furface. If the feafon proves dry, they muft be gently watered three or four days after they are planted ; the beds fliould alfo be covered with mats in the day time, but I 2 which CAM [68 C.imp annla. which fhould be taken off at night to let the dew fall * on the plants. Towards the end of November the beds fhould be covered over with fome old tanners bark to keep out the froft; and where there is not conveniency for covering them with frames, they fhould be arched over with hoops, that in fevere weather they may be covered with macs. In the fpring the mats mull be re- moved, and, the following fummer, the plants kept free from weeds. In autumn the ea^th fliould be ftirred between them, fome frelh earth fprcad over the beds, and the plants covered in winter as before. In thefe beds the plants may remain two years, during vt-hich time they are to be treated in the manner before direc- ted. The roots v/ill now be ftrong enough to flower 5 fo, in September they Ihould be carefully taken up, and fome of the moll promifing carefully planted in pots ; the others may be planted in warm borders, or in a frefh bed, at a greater diftance than before, to allov/ them room to grow. Thofe plants which are potted fliould be fheltercd in winter from great rains and hard frclts, othervvlfe they will be in danger of rotting, or at leaft will be fo weakened as not to flower with any flrength the following fummer; and thofe which are planted in the full ground, fliould have fome old tanners bark laid round them to prevent the froft from getting at the roots. The fecond, third, fourth, and fifth forts are ,fo eafily propagated by parting the roots, or by feeds, that no particular direftions for their culture need be given. The fixth fort, which is cultivated for its efcu- lent roots, may be propagated by feeds, which are to be fown in a fhady border ; and when the plants are a- bout an inch high, the ground fhall be hoed as is praftifed for onions, to cut up the weeds, and thin the plants, to the diilance of three or four inches ; and when the weeds come up again they muft be hoed over to deftroy them : this, if well performed in dry wea- ther, will make the ground clean for a long time ; fo that, being three times repeated, it will keep the plants clean till v.'inter, which is the feafon for eating the roots, when they may be taken up for ufe as wanted. They will continue good till April, at which time they fend out their flalks, when the roots become hard and unfit for ufe. — The feventh and eighth forts are eafily propagated by feeds, which they produce in plen- ty. If thefe, and the Venus navclwort, dwarf lych- nis, candy-tuft, and other low annual flowers, are pro- perly mixed in the border of the flower-garden, and fown at two or three different feafons, fo as to have a fucceffion of them in flower, they will make an agree- able variety. If thefe feeds are fown in autumn, the plants will flower early in the fpring; but if fown in the fpring, they will not. flower till the middle of June ; and If a third fowing is performed about the middle of May, the plants will flower in Auguft; but from thefe, good feeds muft not be expeaed.— The ninth fort is propagated by parting the roots, Avhich muft be done with caution : for if they are broken or wounded, the milky juice will flow out plentifully; and if planted be- fore the wounds are flr grounds, which are well watered, yield excellent grafs, and breed vail numbers of great and fmall cattle. The uncultivated parts are a continued wood, compofed of prodigioufly large and lofty trees, of which there is fuch a variety of fpecies, that even of thofe who have taken moft pains to know them, there is not per- haps one that can tell half the number. Canada pro- duces, among others, two forts of pines, the white and the red ; four forts of firs ; two forts of cedar and oak, the white and the red ; the male and female ma- ple ; three forts of afh-trees, the free, the mungrel) and the baftard ; three forts of walnut-trees, the hard, the foftj and the fmooth; vaft numbers of beech-trees and white wood ; white and red elms, and poplars. The Indians hollow the red elms into canoes, fome of which made out of one piece will contain 20 perfons ; others are made of the bark ; the dLftcrent pieces of which they few together with the inner rind, and daub over the feams with pitch, or rather a bituminous mat- ter refembling pitch, to prevent their leaking ; the ribs of thefe canoes are made of boughs of trees. In the hollow elms, the bears and wild cats take up their lodging from November to April. The country pro- duces alio a vaft variety of other vegetables, particu- larly tobacco, which thrives well. Near Quebec is a fine lead mine, and many excellent ones of iron have been difcovered. It hath alfo been reported that filver is found in fome of the mountains. The rivers are ex- tremely numerous, and many of them very large and deep.^ The principal are, the Oirattauais, St John's, Seguinay, Defpaires, and Trois Rivieres ; but all thefe are fvvallowed up by the great river St Laurence. This river iffues from the lake Ontario ; and, taking its courfe north-eaft> waflies Montreal, where it receives tlie Ouattauais, aud forms many feitile iflands. It con- tinues the fame courfe, and njeets the tide upwards of 400 miles from the fea, where it is navigable for large yefiels ; and below Quebec, 320 miles from the fea, it becomes fo broad and fo deep, that fhips of the line contributed in the laft war to reduce that city. After receiving in its progrcfs innumerable ftreams, it at laft fulls into the ocean at cape Rofiers, where it is 90 miles broady and where the cold is intenfe and the fea boiftcrous. This river is the only one upon which any ftttkments of note are as yet formed ; but it is very probable, that, in time to come, Canada, and thofe vaft regions to tlie weft, may be enabled of them- 76 ] CAN felves to carry on a confiderable trade upon the great Canada lakes cf fredi water vv'hich thefe countries environ. — -y— Here are five lakes, the leaft of which is of greater ex- tent than the frefti-water lakes to be found in any other part of the world : thefe are the lake Ontario, which is not lefs than 200 leagues in circumference ; Erie,, or Ofwego, longer, but not fo broad, is about the fame extent. That of the Huron fpreads greatly in width, and is about 300 leagues in circuit ; as alfo is. that of Maciiigan, though like lake Erie it is rather long, and comparatively narrow. But the lake Su- perior is larger than any of thefe, being not. lefs than 500 leagues in circumference.. AH thefe are navigable by any velfels, and they all comanunicate with each other ; but the paflage between Erie and Ontario is interrupted by a moft. ftupendous fall or cataradt, cdXhd. tht falls of Niagara* . The river St Lawrence, . as already ohferved, is the outlet of thefe lakes, hy agatl.'' ' which they difcharge themfelves into the ocean. Tlie French built forts at thefe feveral ftraits, by which the lakes communicate with one another, and on that where the laft of them communicates with the river. Ey thefe, while the country was in their pofleifion, they effedually fecured to themfelves the trade of the lakes, and p-/eferved an influence over all the Indian nations tlmt lie near them. ^ The moft curious and interefting part of the natural hiftory of Canada is the animals there produced. Thefe are ftags, elks, deer, bears, foxes, martins, wild cats, ferrets, w-eafels, large fquirrels of a greyifh hue, hares and rabbits. The fouthern parts, in particular, breed great numbers of wild bulls, divers forts of roe bucks, goats, wolves, &c. The marfhcs, lakes, and pools, with which this country abounds, fwarm with otters and beavers, of which the white are highly valued, as well as the right black kind. A vaft variety of birds are alio to be found in the woods ; and the river St Lawrence abounds with fuch quantities of lifh, that it is affirmed by fome writers, this would be a more profitable article than even the fur-trade. — There are in Canada a multitude of different Indian tribes : but thefe are obferved to decreafe in number where the, Europeans are moft numerous ; owing chiefly to the immoderate ufe of fpirltuous liquors, of which they are exceffively fond. Their manners and way of liviiio- we have already particularly defcribedi-. The principal ^ ,See jfm towns are Quebec, Trois Rivieres, and Montreal. The w^, N° g commodities inquired by the Canadians fnmi Europe 2o. are, wine, or rather rum ; cloths, chiefly coarie; linen; and wrought iron. The Indian trade requires rum, tobacco, a fort of dufFil blankets, gums, powder, balls, and flints, kettles, hatchets, toys, and trinkets of alL kinds. While the country was in poiTeffion of the' French, the Indians fupplied them with poultry; and. the French had traders, who, like the original inha-- bitants, traverfed the vaft lakes and rivers in canoes, with incredible induftry and patience, carrying their, goods into the remoteft parts of America, and among nations entirely unknown to us. Thefe. again brought, the fmrs, &c. home to them, as the Indians wei-e there- by habituated to trade with them. For this purpofe,. people from all parts, even from the diftance of 1000 miles, came to the French fair at Montreal, which be- gan in June, and fometimes laftcd three months. On- this occafion many folemnities weie obferved, guards. were CAN [ 77 ] G A N mada. vfcrc placed, and the governor affifted to pref^irve order in fo great and various a concourfe of favage nations. But fometlmes great diforders and tumults happened ; and the Indians frequently gave for a dram all that they were polTelTed of. It is remarkable, that many of thefe nations actually palled by the Englilh fettle- ment of Albany in New York, and travelled 200 miles further to Montreal, though they coidd have purchafed the goods they wanted cheaper at the former. Since Britain became pofleffed of Canada, our trade with that country has generally employed 34 (hips and 400 feamen ; their exports, at an average of three years, in ficins, furs, ginfeng, fnake-reot, capillaire, and wheat, amount to 150,00c/. Their imports from Great Britain are computed at nearly the fame fum. It will, however, be always impoffible to overcome cer- tain inconveniences arihng from the violence of the winter. This is fo exceffive from December to April, that the broadeft rivers are frozen over, and the fnow lies commonly from four to fix feet deep on the ground, even in thofe parts of the country which lie three de- grees fouth of London, and in the temperate latitude of Paris. Another inconvenience arifes from the falls in the river St Lawrence below Montreal, which prevent fhlps from penetrating to that emporium of inland com- merce. Our communication therefore with Canada, and the immenfe regions beyond it, will always be in- terrupted during the winter-feafon, until roads are form- ed that can be travelled without danger from the Indians. For thefe favage people often commit hoftilitiesagainll us, without any previous notice; and frequently, v/ith- out any provocation, they commit the inoft liorrid ra- vages for a long time with impunity. Canada was undoubtedly difcovered by Sebaftian Cabot, the famous Italian adventurer, who failed un- der a commiifion from Henry VII. But though the Engliih monarch did not think proper to make any ufe of this difcovery, the French quickly attempted it; we have an account of their fifhing for cod on the banks of Newfoundland, and along the fea-ccaft of Canada, in the beginning of the i6th century. About the year 1506, one Denys, a Frenchman, drew a map of the gulph of St Lawrence ; and two years after, one Au- bort, a fliip-mafter of Dieppe, carried over to France fome of the natives of Canada. As the new country, however, did not promife the fame amazing quantities of gold and filver produced by Mexico and Peru, the French for fome years neglected the difcovery. At laft, in the year 1523, Francis 1. a fenfible and en- terprifmg prince, fent four (hips, under the command of Verazani, a Florentine, to profccute difcoveries in that country. The particulars of this man's firft ex- pedition are not known. All we can learn is, that he i-eturned to France, and next year he undertook a fecond. As he approached the coaft, he met with a vio- lent ftorm; however, he came fo near as to perceive the natives on the fliore, making friendly figns to him to land. This being found impra6licabie by reafon of the furf upon the coail, one of the failors threw himfelf in- to the fea; but, endeavouring to fwirn back to the fliip, a furge threw him on fhore without ligns of life. He was, however, treated by the natives with fuch care and humanity, that he recovered his ftrength, and was allowed to fwim back to tlie fnip, which immediately retunied to, France. This is. all we know of V.erar zani's fecond expedition. He undertook a third, but C.!na:ia. was no more heard of, and it is thought that he and all ~"~>^ — ^ his company perifhed beforefhe could form any colony. In T534, one Jaques Carticrof St Maloes fet fail under a commifiiofi from the French king, and on the loth of May arrived at Cape Bonavifta in Newfoundland. He had with him two fmaU fliips befides the one in which he failed. He cruifed along the coatts of that ifland, on which he difcovereri inhaVntants, probably the Elicimaux. He landed in feveral places along the coaft of the Gulf, and took poffeffion of the country in the king's name. On Iris return, he was again fent out with a commiffion, and a pretty large force; he re- turned in 1535, and palfed the winter at St Croix; but the feafon proved fo levere, that he and his companions, mull have died of the fcurvy, had they not, by the ad- vice of the natives, made ufe of the decoClion of the tops and bark of the white pines. As Cartier, how-- ever, could produce neither gold nor filver, all that he could fay about the utility of the fettlemeiit was difre-- gardcd ; and in 1540, he was obliged to become pilot to one M. Roberval, who was by the French king ap- pointed viceroy of Canada, and who failed from France with five vefftls. Arriving at the gulph of St Lawrence,; they built a fort ; and Cartier was left to command the garrifon in it, while Roberval returned to France for additional recruits to his new fettlement. Atlaft, ha- ving embarked in 1549, with a great number of adven- turers, neither he nor imy of his followers were heard of more. This fatal accident fo greatly difcouraged the court of France, that, for 50 years, no meafure were taken for fupplying with neceiTarles the fettlers that were left. jA-tlalt, Henry IV. appointed the Marquis de la Roche lieutenant-general of Canada and the neighbouring- countries. In 1598 he landed on the ille of Sable,, which he abfurdly thought to be a proper place for a. fettlement, though it was without any port, and with-- out prodaft except briars. Here he left about 40 ma- lefa(Stors, the refufe of the French jails. After cruizing for fome time on the coaft of Nova Scotia, without be- ing able to relieve thefe poor wretches, he returned to France, v,'here he died of a broken heart. His colony muft have periflied, had not a French fliip been wreck- ed on the ifland, and a few fheep driven upon it at the fame time. With the boards of the ftiip they erected huts; and while the fheep lafted they lived on them, feeding afterwards on fifh. Their clothes wearing out, they made coats of feal-llcins; and in this miferable con-- dition they fpent feven years, when Henry ordered them to be brought to France. The king had the cu- riofity to fee them in their feal-fliin dreifes, and was fo; moved with their appearance, that he forgave them all their offences, and gave each of them 50 crowns to be- gin the world anew. In 1600, one Chauvin, a commander in the French navy, attended by a merchant of St Malo, called Pont^ grave, made a voyage to Canada, from whence he re- turned with a very profitable quantity of furs. Next; year he repeated the voyage with.the fame good for- tune, but died while he was preparing for a third. The many fpecimens of profit to be made by the Canadian trade, at laft induced the public to think favourably of it. An armament was equipped, and the command of it given to Pontgrave, , with powers to extend his difco-- verics : C A N [ 7; verles vjp the river St Lawrence. He failed in 1 603, ha- ving in his company Samuel Champlain, who had been a captain in the navy, and was a man of parts and fpi- rit. It was not, however, till the year 1608, that the colony was fully eftabliflred. This was accomplidied by founding the city of Quebec, which from that time commenced the capital of all the fettlements in Canada^ The colony, however, for many years continued in a low way, and was often in danger of being totally ex- terminated by the Indians. As the particulars of thefe wars, however, could neither be entertaining, nor in- deed intelligible, to many of our readers, we choofe to omit them, and in general obferve, that the French not only concluded a permanent peace with the Indians, but fo much ingratiated themfelves with them, that they could with the greateft eafe prevail upon them at any time to murder and fcalp the Englifh in their fettle- ments. Thefe practices had a confiderable fhare in bringing about the laft war with France, when the whole country was conquered by the Britifh in 1761. The moll remarkable tranfa£tion in this conqueft was the fiege of Quebec ; for a particular account of which, fee that article. And for the tranfaftions here during the late American war, fee America (United States of), nO 195, 200 — 207. CANAL of Communication, an artificial cut in the ground, fupplied with water from rivers, fprings, &c. in order to make a navigable communication be- twixt one place and another. The particular operations necefTary for making arti- ficial navigations depend upon a number of circumllan- ces. The fituation of the ground; the vicinity or con- nection with rivers ; the eafe or difficulty with which a proper quantity of water can be obtained ; thefe and many other cnxumftances neceffarily produce great va- riety in the ftruAure of artificial navigations, and aug- ment or diminifh the labour and expence of executing them. When the ground is naturally level, and uncon- nected with rivers, the execution is eafy, and the navi- gation is not liable to be diflurbed by floods: but, when the ground rifes and falls, and cannot be reduced to a level, artificial methods of railing and lowering velTels mull be employed ; which likewife vary according to circumftances. A kind of temporary fluices are fometimes employed for raifing boats over falls or fhoals in rivers by a very liinple operation. Two pofts or pillars of mafon-work, with grooves, are fixed, one on each bank of the I'iver, at fome dillance below the fhoal. The boat having paf- fed thefe pofts, planks are let down acrofs the river by puUies into the grooves, by which the water is dammed up to a proper height for allowing the boat to pafs up the river over the Ihoal. ■The Dutch and Fleemings at this day fometimes, when obftrufted by cafcades, form an inclined plane or rolling-bridge upon dry land, alongft which their vef- feh are drawn from the river below the cafcade into the river above it. This, it is faid, was the only method employed by the ancients, and is Hill ufcd by the Chi- nefe, v\-ho are faid to be entirely ignorant of the nature and utihty of locks. Thefe rolhng-bndges confift of a number of cylindrical rollers which turn eafily on pi- vots, and a mill is commonly built near by, fo that the •fame machineiy may ferve the double purpofe of work- ing the mill and drawing up vefTels. ; ] CAN A Lock Is a bafon placed lengthwife in a river or ca-* nal, lined with walls of mafonry on each fide, and ter- minated by two gates, placed where there is a cafcade or natural fall of the country; and fo conftrufted, that the bafon being filled with water by an Upper fiuice to the level of the waters above, a veffel may afcend thro' the upper gate; or the water in the lock being reduced to the level of the water at the bottom of the cafcade, the veffel may defcend through the lower gate ; fq>f when the waters are brought to a level on either fide, the gate on that fide may be eafily opened. But as the lower gate is ftrained in proportion to the depth of wa- ter it fiipports, when the perpendicular height of the water exceeds 1 2 or 15 feet, more locks than one be- come neceffary. Thus, if the fiill be 17 feet, twa locks are required, each having %\ feet fall ; and if the fall be 26 feet, three locks are necelfaiy, each having 8 feet 8 inches fall. The fide-walls of a lock ought to be very ftrong. Where the natural foun- dation is bad, they fliouid be founded on piles and platforms of wood: they Ihould likewife flope out- wards, in order to refill the preflure of the earth from behind. Plate CXIV. fig. I. A perfpeftive view -of part of a canul: the veflel L, within the lock AC. — Fig. 2. Sedlion of an open lock: the veffel L about to enter. — Fig. 3. Sedion of a lock full of water; the veffel L raifed to a level with the water in the fuperior canal.-^ Fig. 4. Ground feftion of a lock. L, a veffel in the inferior canal. C, the under gate. A, the upper gate. GH, a fubterraneous paflage for letting water from the fuperior canal run into the lock. KF, a fub- terraneous pafTage for water from the lock to the infe- rior canal. X and Y (fig. I.) are the two flood-gates, each of which coniifls of two leaves, refling upon one an- other, fo as to form an obtufe angle, in order the bet- ter to refill the preffure of the water. The firft (X) prevents the water of the fuperior canal from faUing into the lock; and the fecond (Y) dams up and fu- ftains the water in the lock. Thefe flood-gates ought to be very flrong, and to turn freely upon their hinges. In order to make them open and fhut with eafe, each leaf is furnifhed with a long lever Kb, Ab\ Cb, Cb. They flrould be made very tight and clofe, that as httle water as poflible may be lofl. By the fubterraneous paffagc G H (fig. 2, 3, & 4) which defcends obliquely, by opening the fiuice G, the water is let down from the fuperior canal D into the lock, where it is ftopt and retained by the gate C when fhut, till the water on the lock comes to be on a level with the water in the fuperior canal D ; as repre- fented, fig. 3, When, on the other hand, the wa- ter contained by the lock is to be let out, the paffage G H mull be fhut by letting down the fiuice G, the gate A mull be alfo firut, and the paffage K F opened by raifing t-he fiuice K : a free paffage being thus gi- ven to the water, it defcends through K F, into the inferior canal, until the water in the lock is on a level with the water in the inferior canal B ; as reprefented, fig* 2. Now, let it be required to raife the veffel L (fig. 2) from the inferior canal B to the fuperior one D ; if the lock happens to be full of water, the fiuice G mull be fiuit, and alfo the gate A, and the fiuice K opened, 2 fo CAN [79 Caiiul. fo tl-.iat the water in the lock may run out till it is on — ^ a lev/el with the water in the inferior canal B. When the ^water in the lock comes to be on a level with the water at B, the leaves of the gate C are opened by the leveii-s C h, which is ealily performed, the water on each fide of the gate being in equilibrio ; the veffel then fails into the lock. After this the gate C and the fkiice K are (hut, and the fluice G opened, in order to fill the lock, till the water in the lock, and con- feqvuently the veflel, be upon a level with the water in the fuperior canal D ; as is reprefented in fig. 3. The gate: A is thjn opened, and the velfel pailes into the canal D. Again, let it be required to make a veffel defcer.d from the canal D into the inferior canal B. If the lock is empty, as in fig. 2. the gate C and fluice K muft be {hut, and the upper fluice G opened, fo that the water in the lock may rife to a level with the wa- ter iin the upper canal D. Then open the gate A, and let the veffel pafs thro' into the lock. Shut the gate A and the fluice G ; then open the fluice K, till the water in the lock be on a level with the water in the inferior canal ; then the gate C is opened, and the vefl'tel paffes along into the canal B, as was required. It is almoft needlefs to fpend time in enumerating the many advantages which neceffarily refidt from ar- tificial navigations. Their utility is now fo apparent, that moll nations in Europe give the higheft encou- ragement to undertakings of this kind wherever they are prafticable. The advantages of navigable canals did not efcape the obfervation of the ancients. From the moft early accounts of fociety we read of attempts to cut through large ilthmufes, in order to make a communication by water, either betwixt different na- tions, or diftant parts of the fame nation, where land- canriage was long and expeniive. Herodotus relates, that the Cnidians, a people of Caria in Alia Minor, deftgned to cut the ifl-hmus which joins that peninfula to the continent ; but were fuperftitious enough to give up the undertaking, becaufe they were interdifted by an loracle. Several kings of Egypt attempted to join the Red-Sea to the Mediterranean. Cleopatra was exceedingly fond of this projed. Soliman II. empe- ror of the Turks, employed 50,000 men in this great work. This canal was completed under the caliphate of Omar, but was afterwards allowed to fall into difre- pair ; fo that it is now difficult to difcover any traces of it. Both the Greeks and Romans intended to make a canal acrofs the Ifthmus of Corinth, which joins the Morea and Achaia, in order to make a navigable pafTage by the Ionian fea into the Archipelago. De- metrius, Julius Casfar, Caligula, and Nero, made feve- ral unfuccefsful efforts to open this paffage. But, as the ancients were entirely ignorant of the ufe of water- locks, their whole attention was employed in making level cuts, which is probably the principal reafon why they fo often failed in their attempts. Charlemagne for med a defign of joining the Rhine and the Danube, in (Order to make a communication between the ocean and the Black Sea, by a canal from the river Almutz which difcharges itfelf into the Danube, to the Reditz, which falls into the Maine, and this laft falls into the Rhine near Mayence : for this purpofe he employed a prodigious number of workmen ; but. he met with fo ] CAN many obHacles from different quarters, that he was ob- Canal, liged to give up the attempt. - ^— v"" The French at prefent have many fine canals : that of Briare was begun under Henry IV. and finifhed un- der the direftion of cardinal Richelieu in the reign of Louis XIII. This canal makes a communication be- twixt the Loire and the Seine by the river Loing. It extends 1 1 French great leagues from Briare to Mon- targis. It enters the Loire a little above Briare, and terminates in the Loing at Cepoi. There are 42 locks on this canal. The canal of Orleans, for making another commu- nication between the Seine and the Loire, was begun in 1675, and finiflied by Phihp of Orleans, regent of France, during the minority of Louis XV. and is fur- niflied with 20 locks. It goes by the name of the ca- nal of Orleans ; but it begins at the village of Com- bleux, which is a fliort French league from the town of Orleans. But the greateft and moft ufeful work of this kind is the junction of the ocean with the Mediterranean by the canal of Languedoc. It was propofed in the reigns of Francis I. and Henry IV. and was undertaken and finiflied under Louis XIV. It begins with a large re- fervoir 4000 paces in circumference, and 24 feet deep, which receives many fprings from the mountain Noire. This canal is about 64 leagues in length, is fupplied by a niunber of rivulets, and is furniflied with 104 locks, of about eight feet rife each. In fome places it paffes over bridges of vail height ; and in others it cuts thro' fohd rocks for 1000 paces. At one end it joins the river Garonne near Tholoufe, and terminates at the other in the lake Tau, which extends to the port of Cette. It was planned by Francis Riquet in the 1666, and finiflied before his death, which happened in the 1680. In the Dutch, Auftrlan, and French Netherlands, there is a very great number of canals ; that from Bru- ges to Oftend carries veffels of 200 tons. The Chinefe have alfo a great number of canals;, that which runs from Canton to Pekin extends about 825 miles in length, and was executed about 800 years ago. It would be an endlefs taflc to defcribe the number- lefs canals, in Holand, Ruffia, Germany, &c. We fliall- therefore confine ourfelves to thofe that are either al- ready finiflied, or at prefent executing, in our own. country. As the promoting of commerce is the principal in- tention of making canals, it is natural to expect that their frequency in any nation fliould bear fome propor- tion to the trade carried on in it, providing the fitua- tion of the country will admit of them. The prefent ftate of England and Scotland confirms this obferva- tion. Though the Romans made a canal between the. Nyne, a little below Peterborough, and the Witham, three miles below Lincoln, which is now almoJl entire- ly filled up, yet it is not long fince canals were revived in England. They are now however become very nu- merous, particularly in the counties of York, Lincoln, and Chelhire. Moil of the counties betwixt the mouth of the Thames and the Briilol channel are connedled together either by natural or artificial navigations ; thofe upon the Thames and Ifis reaching within about zoo C A N [ 20 miles of thofe upon the Severn. The duke of * Bridgewater's canal in Chefhire runs 27 miles on a per- fe£l level ; but at Barton it is carried by a very high aqueduft bridge over the Irwell, a navigable river ; lo that it is common for vcffels to be pafling at the fame time both under and above the bridge. It is likcwife cut fome miles into the hills, where the Duke's coal- mines are wrought. A navigable canal betwixt the Forth and Clyde in ■Scotland, and which divides the kingdom in two parts, was firft thought of by Charles II, for tranfports and fraall (hips of war ; the expence of which was to have been L. 500,000, a fum far beyond the abilities of his reign. It was again projefted in the year 1722, and a fui-vey made ; but nothing more done till 1 761, when the then Lord Napier, at his own expence, caufed make a furvey, plan, and eftimate on a fraall fcale. In 1764., the truftees for fifheries, &c. in Scotland caufed make another liirvey, plan, and eftimate of a canal five feet deep, which was to coil L. 79,00a. In 1766, a fubfcription was obtained by a number of the moil re- fpeftable merchants in Glafgov>', for making a canal four feet deep and twenty-four feet in breadth ; but when the bill was nearly obtained in Parliament, it was given up on account of the fniallnefs of the fcale, and a new fubfcription fet on foot for a canal feven feet deep, eftimated at L. 150,000. This obtained the fanftion of Parliament ; and the work was begun in 1768 by Mr Smeaton the engineer. The extreme length of the canal from the Forth to the Clyde is 35 miles, beginning at the mouth of the Carron, and end- ing at Dalmure Burnfoot on the Clyde, fix miles be- low Glafgow, rifing and falling 160 feet by means of 39 locks, 20 on the eaft fide of the fummit, and 19 on the weil, as the tide does not ebb fo low in Clyde as in the Forth by nine feet. VefTels drawing eight feet %vater, and not exceeding nineteen feet beam and feven- ty-three feet in length, pafswith eafe, thecsnal having afterwards been deepened to upwards of eight feet. The whole enterprlfe difplays the art of man in a high degree. The carrying the canal through mofs, quick- fand, gravel, and rocks, up precipices and over valleys, was attended with inconceivable difficulties. There are eighteen draw-bridges and fifteen aqueduft bridges of note, befides fmall ones and tunnels. In the firft three miles there are only fix locks ; but in the fourth mile there are no lefs than ten locks, and a very fine Squedud bridge over the great road to the weft of Falkirk. In the next fix miles there are only four locks, which carry you to the fummit. The canal then runs eighteen miles on a level, and terminates a- bout a mile from Glafgow. In. this cotfrfe, for a con- fiderable way the ground is banked about twenty feet high, and the water is fixteen feet deep, and two miles of it is made through a deep mofs. At Kirkintulloch, the canal Is carried over the water of Logie on an aquedudl arch of ninety feet broad. This arch was thrown over in three ftretches, having only a centre of 80 ] CAN the Clyde ; when tlie fubfcription and a fubfequent loan Canannr , being exhaufted, the work was ftopt in 1775. The Canara. city of Glafgow, howevenj by means of a collateral "'"'^'^ branch, opened a communication with the Forth, which has produced a revenue of about L. 6000 annually; and, in order to finilh the remaining fix miles, the go- vernment in 1784 gave L. 50,000 out of the forfeited eftates, the dividends arifing from this fum to be ap- plied to making and repairing roads in the Highlands of Scotland. Accordingly the work has been refum- ed ; and by contra(S, under a high penalty, muft be entirely completed in November 1789. The aqueduft bridge over the Kilven (now finifhed, and fuppofed the greateft of the kind in the world) confifts of four arches, and carries the canal over a valley 65 feet high and 420 in length, exhibiting a very fin- gular effort of human ingenuity and labour. To fupply the canal with water was of itfelf a very great work. There is one refervoir of 50 acres 24 feet deep, and another of 70 acres 22 feet deep, into v^hich many rivers and fprings terminate, which it is thought will afford fufficient fupply of water at all times. This whole undertaking when finifhed will coft about L. 2oa,ooo. It is the greateft of the kind in Britain, and without doubt will he of great national utility ; though it is to be regretted that it had not been exe- " cuted on a ftill larger fcale, the locks being too (hutt for tranfporting large mafts. Canal, in anatomy, a duel or pafTage thi'ough which any of the juices flow. CANANOR, a large maritime town of Afia, on the coaft of Malabar, in a kingdom of the fame name, with a very large and fafe harbour. It formerly be- longed to the Portuguefe, and had a ftrong fort to guard it ; but in 1683, the Dutch, together with the natives, drove them away ; and after they became ma» fters of the town, enlarged the fortifications. They have but a very fmall trade ; but there is a town at the bottom of the bay independent of the Dutch, whofe prince can bring 20,000 men Into the field. The Dutch fort is la'rge, and the governor's lodgings are at a good diftance from the gate ; fo that, when there was a ficirmifti between the faftory and the na- tives, he knew nothing of it till it was over. E. Long. 78. 10. N. Lat. 12. o. Cananor, a fmall kingdom of Afia, on the coaft of Malabar, whofe king can ralfe a confiderable army. The natives are generally Mahometans ; and the coun- try produces pepper, cardamons, ginger, mirobolans, and tamarinds, in which they drive a confiderable trade. CANARA, a kingdom of Afia, on the coaft of Malabar. The inhabitants are Gentoos, or Pagans ; and there is a pagod, or temple, called Ramtnit, which Is vlfited every year by a great number of pilgrims. Here the cuftom of burning the wives with their huf» bands had its beginning, and is praflifed to this day. The country is generally governed by a woman who keeps her court at a town called Baydor, two days thirty feet, which was fiilfted on fmall rollers from one journey from the fea. She may m.airy whom ftie pleafe.>; ftretch to another ; a thing new, and never attempted l)efore with an arch of this fize ; yet the joinings are as fairly equal as any other part, and admired as a very fine piece of mafonry. On each fide there is a very con- fiderable banking over the valley. The work was car- ried on till it came within fix raHes of its junilion with -4: and is not obhged to burn with her huftiand, hke her female fubjedls. They are fo good obfervers of their laws, that a robbery or murder is fcarce ever heard of among them. The Canarans have forts built of earth along the coaft, which are garrifoned with 200 or 300 foldiers, to guard againft the robberies of their neigh- bours. Canary- If- lands. CAN [ Canaria. bours. The lower grounds yield every year two crops of corn or rice ; and the higher produce pepper, betel nuts, fanders wood, iron, and fteel. The Portuguefe clergy here live very loofely, and make no fcruple of procuring women for ftrangers. CANARIA (anc. geog.), one of the Fortunate Iflands, a proof that thefe were what are now called the Canaries. Canaria had its name from its abounding with dogs of an enormous fize, two of which were brought to Juba king of Mauritania. See the following article. Canaria, or the Grand Canary, an ifland in the Atlantic Ocean, about i8o miles from the coall of Africa. It is about loo miles in circumference, and 33 in diameter. It is a fruitful ifland, and famous for the wine that bears its name. It alfo abounds with apples, melons, oranges, citrons, pomegranates, figa, olives, peaches, and plantains. The fir and palm trees are the moft common. The towns are, Canary the capital, Gualdera, and Geria. CANARY, or CiviDAD DE Palmas, is the capital of the ifland of Canaria, with an indifferent caftle, and a biihop's fee. It has alfo a court of inquifitlon, and the fupreme council of the reft of the Canary-iflands ; as alfo four convents, two for men and two for wo- men. The town is about three miles in compafs, and contains 12,000 inhabitants. The houfes are only one ftory high, and flat at the top ; but they are well built. The cathedral is a handfome ftrudture. W. Long. 15. 20. N. Lat. 28. 4. CANjiRr-IJlandsf are fituated in the Atlantic ocean, over againft the empire of Morocco in Africa. They were formerly called the Fortunate IJlands, on ac- count of the temperate healthy air, and excellent fruits. The land is very fruitful, for both wheat and barley produce 1 30 for one. The cattle thrive well, and the woods are full of all forts of game. The Ca- nary finging birds are well known all over Europe. There are here fugar-canes in great abundance ; but the Spaniards firft planted vines liere, from whence we have the Avine called Canary or Sack. Thefe iflands were not entirely unknown to the an- cients ; but they were a long while forgot, till John de Betencouit difcovered them in 1402. It is faid they were firft inhabited by the Phoenicians, or Carthagi- nians, but on no certain foundation; nor could the in- habitants themfelves tell from whence they were deri- ved ; on the contrary, they did hot know there was any other country in the world. Their language, manners, and cuftoms, had no refemblance to thofe of their neighbours. However, they wei-e like the people on the coaft of Barbary in complexion. They had no iron. After the difcovery, the Spaniards foon got pof- feflion of them all, under whofe dominions they are to this day, except Madeira, which belongs to the Portu- guefe. The inhabitants are chiefly Spaniards; though there are fome of the firft people remaining, whom they call Guanchcs^ who are fomewhat civilized by their intercourfe with the Spaniards. They are a hardy, ac- tive, bold people, and live on the mountains. Their chief food is goat's milk. Their complexion is tawny, and their nofes flat. The Spanifti veflels, when they fail for the Weft Indies, always rendezvous at thefe iflands, going and coming. Their number is 12. i. Alegranza ; 2. Canaria; 3. Ferro; 4. Fuerteventura ; 5. Gomera; 6. Gratiofaj 7, Lancerotta ; 8. Madeira; Vol. IV. Part L 81 ] CAN 9. Palma; 10. Rocca ; 11. Salvages; 12. Teneriff. Canary- Weft longitude from 12. to 21. north latitude from ^ 27. 30. to 29. 30. >— V— " CANARY-Bird. See Fringilla. Thefe birds are much admired for their finging, and take their name from the place from whence they originally came, vi%. the Canary-iflands ; but of late years there is a fort of birds brought from Germany, and efpecially from Tirol, and therefore called German birds, which are much better than the others ; though both are fuppofed to have originally come from the fame place. The cocks never grow fat, and by fome country people cannot be diftinguifhed from common green-birds ; though the Canary-birds are miich luftier, have a longer tail, and differ much in the heaving of the paffages of the throat when they fing. Thefe birds being fo much efteemed for their fong, are fometimes fold at a high price, ac- cording to the goodnefs and excellency of their notes ; fo that it will always be advifable to hear one fmg be- fore he is bought. In order to know whether he is in good health, take him out of the ftore-cage, and put him in a clean cage by himfelf ; if he ftand up boldly, without crouching or fhrinking in his feathers, look with a brifl< eye, and is not fubjeft to clap his head under his wing, it is a fign that he is in good health ; but the greateft matter is to obfervehis dunging: if he bolts his tail like a nightingale after he has dunged, it is a fign he is not in good health, or at leait that he will foon be fick ; but if his dung be very thin like water, or of a flimy white without any blacknefs in it, it is a fign of approaching death. When in per- fect health, his dung lies round and hard, w^ith a fine white on the outfide, dark within, and dries quickly ; though a feed-bird feldom dungs fo hard, unlefs he is very young. Canary-birds are fubjeft to many difeafes, particu- larly impofthumes, which affeft the head, caufe them to fall fuJdenly from the perch, and die in a fliort time, if not fpeedily cured. The moft approved me- dicine is an ointment made of freih butter and capon's greafe melted together. With this the top of the bird's head is to be anointed for two or three days, and it will diffolve the impofthume : but if the medi- cine^lias been too long delayed, then, after three or four times anointing, fee whether the place of his head be foft ; and if fo, open it gently, and let out the matter, which will be like the yolk of an egg ; when this is done, anoint theplace, and the bird will be cured. At the fame time he muft have figs with his other food, and in his water a flicc or two of liquorice, with white fugar-candy. Canary-birds are diftinguifhed by different names at different times and ages : fuch as are about three years old are called runts ; thofe above two are named er^/ thofe of the firft year under the care of the old ones, ■are termed hranchers j thofe that are new-flown, and cannot feed themfelves, pujhers ; and thofe brought up by liand, ne^lings. The Canary-birds may be bred with us ; and, if treated with proper care, they will become as vigorous and healthful as in the country from whence they have their name. The cages in which thefe birds are kept are to be made either of walnut-tree or oak, with bars of ware ; becaufe thefe, being woods of itrength, do not require to be ufed in large piece*. L The Canary- birds. C A N [ The common ihape of cages, ivhich is cylindric, is very improper for thefe birds ; for this allows little room to walk, and without that the birds ufually be- come melancholy. The moft proper of all ihapes is the high and long, but narrow. If thefe birds eat too much, they ^ow over-fat, lofe. their (hape, and their fmging is fpolled ; or at leaft they become fo idle, that they will fcarce ever fing. In this cafe their vicluals is to be given them in a much fmaller quantity, and they will by this means be recovered by degrees to all their beauty, and will fmg as at firft. At the time that they are about to build their nefts, there muft be put into their cages fome hay, dried thoroughly in the fun : with this muft be mixed fome mofs dried in the fame manner, and fome ftag's hair ; and great care is to be taken of breeding the young, in the article of food. As foon as the young birds are eight days old, or fomewhat more, and are able to eat and pick up food of themfelves, they are to be taken out of the cage in which they were hatched, and each put feparately into another cage, and hung up in a room where it may never have an opportunity of hearing the voice of any other bird. After they have been kept thus about eight days, they are to be ex- cited to fmg by a bird-pipe ; but this is not to be blowed too much, or in too fln-ill a manner, left they ling themfelves to death. For the firft fifteen days the cages are to be covered with a black cloth,' and for the fifteen days following with a green one. Five lelTons in a day from the pipe are fufiicient for thefe young creatures ; and they muft not be difturbed with feveral founds at the fame- time, left they confound and puzzle them: two lefTons fnould be given them early in the morning, one about the middle of the day, and two more at night. The genius and temper of the feveral birds of this kind are veiy different. The males are almoft always m.elancholy, and will not ling unlefs they are excited to it by hearing others continually finging about them. The male bird of this kind will often kill the female put to him for breeding ; and when there are feveral females together with the males, they will often do the fame to one another from jealoufy. It is therefore not eafy to manage the article of their breeding well- in this particular, unlefs- in this manner: let two female birds be put into one cage, and when they have lived together fome time, they will have contracted a fort of love for one another, which wiU not eafily be diffolved. Put a male bird into the cage with thefe two, and every thing will go well ; their friendftiip will keep them from quarrelling about his favours, and from dan- ger of his mifchievous difpofition ; for if he attacks one of them, in order to kill her, the other will imme- diately take her part ; and after a few of thefe battles, the male will find that they are together an over- match for him at fighting, and will then diftribute his favours to them, and there will not fail of being a voung breed or two, which are to be taken away from their parents, and educated as before directed. Some males watch the time of the female's laying, and de- vour the eggs as faft as Ihe depofits them ; and others take the young ones in their beak as foon as hatched, and crulh them to death againft the fides of the cage, ». and: CAN ^Jandle. and rolled and fmootiied upon a walnut-tree (able, with """y'^ a long fquare inltrumcnt of box, Imootli at the bottom. z. As to the manner of making wax-candles by the hand, they begin to foflcn the wax, by working it fe- \'eral times in hot water, contained in ja narrow but deep caldron. A piece of the wax is then taken out, and difpofed by little and little around the wick, which is hung on a hook in the wall, by the extix'- xnity oppofite to the neck ; fo that they begin with the big end, diminilhing Hill as they defcend towards the neck. In other refpefts the method is nearly the fame as in the former cafe. However, it muft be ob- ferved, that, in the former cafe, water is always ufed to moillen the feveral inftruments, to prevent the wax from fticking; and in the latter, oil of olives, or lard,, for the hands, &c. The cylindrical wax-candles are either made as the former, with a ladle, or drawn. Wax- candles drawn, are fo called, becaufe actually drawn in the manner of wire, by means of two large rollers of wood, turned by a handle, which, tmniing back- wards and forwards feveral times, pal's the wick through melted wax contained in a brafs bafon, and at the fame time through the holes of aninftrument likethat ufed for drawing wire faftened at one fide of the bafon. If any chandlers mix with their wares any thing de- ceitfully, &c. the candles lhall be forfeited. Stat. 23 Eliz. and a tax or duty is granted on candles, by 8 and 9 Anne, cap. 6. made for fale, of one penny a pound, befides the duty upon tallow, by 8 Anne, cap. 9. And by 24 Geo. III. cap. 11. an additional duty of an halfpenny a pound : and by the fame an addition- al duty of an halfpenny a pound is laid upon all candles imported (except thofe of wax and fpermaceti,for ^vhich fee WAX-Candles), fubjeft alfo to the two additional 5 per cents, impofed by 19 and 22 Geo. III. befides the duty of 2g:d. formerly impofed by 2 W. felT. 2. cap. 4. 8 Anne, cap. 9. and 9 Anne, cap. 6. And every maker of candles, other than wax candles, for fale, fhall annually take out a licence at L. i . The maker of candles fhall, in four weeks within the bills, and elfewhere in fix weeks, after entry, clear off the duties on pain of double duty : nor fell any after de- fault in payment on pain of double value ; 8 Anne, cap. 9. The makers of candles are not to ufe melting houfes, without making a true entry, on pain of L. 100, and to give notice of making candles to the excife officer for the duties ; and of the number, &c. or fhall forfeit L. 50, flat. 11. Geo. I. cap. 30. See alfo 23 Geo. II. cap. 21. and 26 Geo. II. cap. 32. No maker of candles for fale fliall begin to make candles, Avithout notice firft given to the officer, unlefs from September 29th to March 25th yearly, between feven in the morning and five in the evening, and from March 25th to September 29th, between five in the morning and feven in the evening, on pain of L. 10, 10 Anne, cap. 26. The penalty of obftrufting the officer is L. 20, and of removing candles before they are furveyed L. 20, 8 Anne, cap. 9. The pe- nalty of privately making candles is the forfeiture of the fame and utenfils, and L. loo, 5 Geo. III. cap. 43. And the penalty of minghng weighed with unweighed candles, of removing them before they are weighed, or of concealing them. Is the forfeiture of L. 100, 11 Geo. cap. 30. Candles, for which the duty hath been paid, may be exported, and the duty drawn back ; but 94 3 C AN no draw-back fhall be allQwed on the exportation of Cttr\(\\«, any foreign candles imported. 8 Ann. cap. 9. 23 Geo. II. cap. 21. The Roman candles were at firft little ftrings dipt In pitch, or furrounded with wax ; though afterwards they made them of the papyrus, covered Hkewife with wax ; and fometimes alfo of rulhes, by ftripping off the outer rind, and only retaining the pith. — For reli- gious offices, wax candles were ufed ;-for vulgar ufes, thofe of tallow. Lord Bacon propofes candles of divers compofitions and ingredients, as alfo of difierent forts of wicks; with experiments of the degrees of duration, and light of each. Good houfewives bury their candles in flour or bran, which it is faid incre^fcs their Uutiag al« inoft half. Experiments to (Jetcrm'ine the real and comparative value of burning Candles of different forts and Jizes. Nuvaib.of}Wei;-ht The time; The timejThe expence Small wick. Large wick. candles in ( lie pound i8| i6i 5i Mould- candles. Si 4 i candle. Oz. Dr 14 5t 8 I o 13 12 o one can- that one lie lalicd pound wili latl. Hr.MIn 15 40 40 27 36 9 15 19 20 3 Hr. Min, 42 i36 26 34 2 24 24 12 o ^5 39 20 I a hours wiieit candles are at bd. per ddzen, which Ifo fliows the proportion cf the expence at any price per di-zen. Farthings and icoth parts. 4.85 5.70 6.54 6.96 7.50 8.94 8.47 9-53 Moiild-candl. at "Js.per doz. 7.87 9.28 N. B. The time that one candle lafled was taken from an average of feveral trials in each fize. It is obfervable. In optics, that the flame of two candles joined, give a much fl;ronger light than both of them feparate. The obfervatlon was fuggefted by Dr Franklin. Probably the union of the two flames produces a greater degree of heat, whereby the vapour is attenuated, and the particles of which light confifts more copioully emitted. Lighting a Candle by a fmall fpark of eleBricity. This method, which Is an Invention of Dr Ingenhoufz, Is recorded In the Phil. Tranf. vol. 68. It Is done by a fmall phial, having eight®or ten Inches of metaUIc coating, or even lefs, charged with eleftriclty, which may be done at any time of the night by a perfon who has an eleftric machine In his room. •* When I have occafion to Hght a candle," fays he, *' I charge a fmall coated phial, whofe knob is bent outwards, fc) as to hang a little over the body of the phial ; then \ wrap fome loofe cotton over the extremity of a long brafs pin or a wire, fo as to fl;Ick moderately fall to Its fubftance. I next roll this extremity of the pin wrapped up with cotton in fome fine powder of refin, (which I always keep In readinefs upon the table for this piu-pofe^ either in a wide-mouthed phial or in a I loofe CAN [ Cr^vAU, loofe paper) ; (his being clone, I apply tlie extremity Candie- (-he pin or wire to the external coating of the char- "'^'ZL^ S^*^ phial, and bring as quickly as poffible the oth^r extremity wrapped round with cotton to the knob : the po\vder of refm takes fire, and communicates its flame to the cotton, and both together burn long e- nough to light a candle. As I do not want more than half a minute to light my candle in this way, I find it a readier method than kindUng it by a flint and fteel, or calhng a''fervant. I have found, that powder of white or yellov\'- rcfin lights eafier than that of brown. The farina lycopodil may be ufed for the fame purpofe : but it is not fo good as the powder of refin, becaufe it does not take fire quite fo readily, requiring a ftronger fpark not to mifs : befides, it is foon burnt away. By dipping the cotton in oil of turpentine, the fame ef- fect may be as readily obtained, if you take a jar fome- what greater in fize. This oil will inflame fo much the readier if you ftrew a few fine particles of brafs upon it. The pin duil is the beft for this purpofe ; but as this oil is fcattered about by the explofion, and when kind- led fills the room with much more fmoke than the powder of refin, I prefer the laft," CANDLE-Bombs, a name given to fmall glafs bubbles, having a neck about an inch long, with a very {lender bore, by means of which a fmall quantity of water is ihttoduced into them, and the orifice afterwards clofed up. This ftalk being put through the wick of a burn- ing candle, the vicinity of the flame foon rarifies the water into fteam, by the elafticity of which the glafs is broken with a loud crack. Candle is alfo a term of medicine, and is reckoned among the infl:ruments of furgery. Thus the candela fumalis, or the candela pro fitffitu odorata, is a mafs of an oblong form, confifting of odoriferous powders, mixed up with a third or more of the charcoal of wil- low or lime tree, and reduced to a proper confiftence with a mucilage of gum tragacanth, labdanum, or tur- pentine. It is intended to excite a grateful fmell with- out any flame, to correA the air, to fortify the brain, and to excite the fpirits. Medicated Candle, the fame with Bougie. Candle. Sale or auftion by inch of candle, is when n fmall piece of candle, being lighted, the byfl;anders are allowed to bid for the merchandize that is felling ; but the moment the candle is out, the commodity is adjudged to the lafl; bidder. There is alfo an excommunication by inch of can- > die ; when the finner is allowed to come to repentance while a candle continues burning ; but after it is con- fumed, he remains excommunicated to all intents and purpofes. RuJ}j- Candles, ufed in different parts of England, are made of the pith of a fort of ruflies, peeled or llrip- ped of the ilcin, except on one fide, and dipped in melt- ed greafe. CANDLE-JVood, flips of pine about the thicknefs of a finger, ufed in New England and other colonies to burn inftead of candles, giving a very good light. The French inhabitants of Tortuga ufe flips of yellow fan- tal-wood for the fame purpofe, and under the fame de- nomination, which yields a clear flame though of a green colour. CANDLEBERRY tree, in botany, the EngHfli liamc of the Myrica.. 95 i CAN CANDLEMAS, a feaft of the church held on the Cand!cma« fecond day of February, in honour of the purification of the Virgin Mary. It is borrowed from the praftice , i , of the ancient Chriftians, who on that day ufed abun- dance of lights both in their churches and proceflions, in memory, as is fuppofed, of our Saviour's being on that day declared by Simon to be a light to lighten the Gentiles." In imitation of this cuft;om, the Roman- catholics on this day confecrate all the tapers and candles which they ufe in their churches during the whole year. At Rome, the Pope performs that ce- remony himfelf ; and dlftributes wax-candles to the cardinals and others, who carry them in procefliou through the great hall of the Pope's palace. This- ceremony was prohibited in England by an order of council in 1548. Candlemas, (2d Feb.) is made one of the four terms of the year for paying and receiving rents or borrowed money, &c. — In the courts of law. Candle- mas terms begin 1 5th January, and ends 3d February. CANDLESTICK, an inltrument to hold a candle, made in different forms, and of all forts of matter. The golden candleltick was one of the facred uten- fils made by Mofes to be placed in the Jewifli taber- nacle. It was made of hammered gold, a talent in weight. It confilted of feven branches fupported by a bafe or foot. Thefe branches were adorned at equal diftances with fix flowers like lilies, and with as many bowls and knobs placed alternately. Upon the ftock and fix branches of the candleliick were the golden lamps, which were immoveable, wlierein were put oil and cotton. Thefe feven lamps were lighted ever}-- evening, and extinguifhed every morning. The lamps had tlieir tongs or fnuffei-s to draw the cotton in s figned their decrees, letters, &c. The word is by fome derived from cants, or caniculus; alluding to the figure of a dog which it reprefented, or rather becaufe it was fup- ported by the figures of dogs. The caniculum was un- der the care of a particular officer of ftate. CANINA, the north part of the ancient Epirus, a province of Greece, which now belongs to the Turks, and lies off the entrance of the gulph of Venice. The principal town is of the fame name, and is feated on the fca-coaft, at the foot of the mountains of Chimera. E. Long. 19. 25. N. Lat. 40. 55. CANINANA, in zoology, the name of a fpecies of ferpent found in America, and efteemtd one of the lefs poifonous kinds. It grows to about two feet long ; and is green on the back, and yellow on the belly. It feeds on egccs and fmall birds; the natives cut off the head and tail, and eat the body as a delicate difti. CANINE, whatever partakes of, or has any relation to, the nature of a dog. Ni A' E ApJ)etiie, amounts to much the fame with Bu !MY. Canine Madnejs. See (the /n JfAr.fubjpihed tcQ Me- »iClN£. Canint, Canis. ] CAN Canine Teeth, are two fliarp edged teeth in each jaw ; oneoneaeh fide, placed between the incifores and molares, CANINI (John Angelo and Marc Anthony,) bro- * ' thers and Romans, celebrated for their love of antiqui- ties. John excelled in defigns for engraving on ftones, particularly heads ; Marc engraved them. They were encouraged by Colbert to publifh a fucccffion of heads of the heroes and great men of antiquity, defigned from medals, antique ftones, and other ancient remains; but John died at Rome foon after the work was begun : Marc Anthony, however, procured affiftance, finiftied and publifhed it in IiaHan in 1669. The cuts of this edition were engraved by Canini, Picard, and Valet ; and a cu- rious explanation is given, which difcovers the flcill of the Canini's in hiftory and mythology. The French edition of Amfterdam, 1731, is fpurious. CANIS, or Dog, in zoology, a genus of quadru- peds, belonging to the order of ferae. The charafters of the dog are thefe : he has fix fore-teeth in the upper jaw, thofe in the fides being longer than the interme- diate ones, which are lobated ; in the under jaw there are likewife fix fore-teeth, thofe on the fides being lo- bated. He has fix grinders in the upper, and feven in • the lower jaw. The teeth called dog-teeth are four, one on each fide, both in the lower and upper jaw ; they are ftiarp-pointed, bent a little inward, and ilaiid at a di- ftance from any of the reft. There are 14 fpecies of this genus, viz. I.TheFAMiLiARis,orDomeftic Dog, is diftinguifhed Domeftic from the other fpecies by having his tail bent to the -^'^S- left fide ; which mark is fo fingular, that perhaps the tail of no other quadruped is bent in this manner. Of See Plate* this fpecies there are a great number of varieties. Lin- p^^J[' nseus enumerates ii, and Buff'on gives figures of cxix ^' lefs than 27. The maftifF is about the fize of a wolf, andcXX. with the fides of the Hps hanging down, and a full ro- buft body. The large Danifti dog differs only from the former in being fuller in the body, and generally of a larger fize. The gre-hour is likewife the fame with the maftiff ; but its make is more flender and de- Hcate. Indeed the difference betwixt thefe three dogs, although perfectly diftinguifliable at firft fight, is not greater than that betwixt a Dutchman, a Frenchman, and an Italian. The fhepherd's dog, the wolf-dog, and what is commonly called the Siberian dog, to which may be joined the Lapland dog, the Canada dog, and, in general, all thofe which have ftraight ears and a pointed fnout, are all one kind, differing only in thicknefs, the roughnefs or fmoothnefs of their flcin, the length of their legs and tails. The hound or beagle, the terrier, the braque or harrier, and the fpaniel, may be Confidered as the fame kind : they have the fame form and the fame inftinfts ; and differ only in the length of their legs, and fize of their ears, which in each of them .are long, foft, and pendulous- The bull-dog, the fmall Danifh dog, the Turklfli dog, and the Iceland dog, may likewife be confidered as the fame kind, all the va- rieties in their appearance taking their rife merely from climate. Foi inftance, the Turkifli dog, which has no hair, is nothing elfe birt the fmall Danifh dog tranf- ported to a warm climate, which makes the hair fall off. A dog of any kind lofes its hair in very warm climates. But this is not the only change which arifes from dif- ference of climate. In fome, countries, the voiceis chan- ged} CAN [ 99 ] CAN Omis.. ged ; in others, dogs become altogether filent. In feme climates they lofe the faculty of barking, and howriike wolves, or yelp like foxes. Warm climates even change their form and inftindts : they turn ill-fhaped, and their ears become ftraight and pointed. It is only in tem- perate climes that dogs preferve their natural courage, ardour, and fagacity. Dr Caius has left, among feveral other trafts relating to natural hillory, one written exprefsly on the fpecies of Britilh dogs ; befides a defcription of the variety of dogs then exifting in this country, he has added a fyftematic table of them; which we fhall here infert, and explain by a brief account of each kind. Synopsis of British Dogs. ' Hounds. C Terrier Harrier C Blood-hound Gaze-hound Gie-hound Leviner, or Lyemmer Tumbler Spaniel Setter. Water-fpaniel, or finder Spaniel gentle, or comforter Shepherd's dog MaftifF, or ban dog. fcuO o E Eh bo o 11 L.3 O ! Wappe Turnfpit Dancer. I . a. The firft variety is the terrar'ius or terrier, which takes its name from its fubterraneous employ ; being a fmall kind of hound ufed to force the fox or other bealts of prey out of their holes : and, in former times, rab- bits out of their burrows into nets. b. The leverariusy or harrier, is a fpecies well known at prefent : it derives its name from its ufe, that of hiinting the hare ; but under this head may be placed the fox hound, whkh is only a llronger and fleeter va- riety, applied to a different chace. c. The fanguinar'ms , blood-hound, or Jleut-hounde of the Scots, was a dog of great ufe, as already noticed under the article Blood-HoujuI. The next fubdivifion of this fpecies of dogs compre- hends thofe that hunt by the eye ; and whofc fuccefs depends either upon the quicknefs of their light, their fwiftnefs, or their fubtilty. d. The agafitus, or gaze-hound, was the firft : it chaced indifferently the fox, hare, or buck. It would feleft from the herd the fatteft and faireft deer; purfue it by the eye ; and, if loil for a time, recover it again by its fingular diftinguiOiing faculty ; nay, ffiould the bcaft rejoin the herd, this dog would fix unerringly on the fame. This fpecies is now loft, or at leaft un- known to us. e. The next kind is the leporarms, or gre -hound. Dr Caius informs us, that it takes its name quod praclpui gradus fit inter canes ^ " the firft in rank among dogs:" that it was formerly efteemed fo, appears from the fo- reft-laws of king Canute, who enafted that no one un- der the degree of a gentleman fliould prefume to keep a gre-hound; and ftill more ftrongly from an old Welfli faying which fignifies, that " you may know a gentle- man by his hawk, his horfe, and his gre-hound." The variety called the Highland gre-hound^ and now become very fcarce, is of very great fize, ftrong, deep- chefted, and covered^ with long rough hair. This kind was much efteemed in former days, and ufed in great numbers by the powerful chieftains in their magnificent hunting- matches. It had as fagacious noftrils as the blood-hound, and was as fierce. f. The third fpecies is the lev'manus, or lorarius,; the leviner or lyemmer : the firft name is derived from the lightnefs of the kind; the other from the old word lyemme, a thong; this fpecies being ufed to be led in a thong, and flipped at the game. Our author fays that this dog was a kind that hunted both by fcent and fight ; and in the form of its body obferved a medium between the hound and the gre-hound. This probably is the kind now known among us by the name of the Iri/h gre-hound, a dog now extremely fcarce in that kingdom, the late king of Poland having procured from them as many as poffible. They were of the kind called by Buffon le grand Danois, and probably imported tliere by the Danes who long poffefled that kingdom. Their uie feems originally to have been for the chace of wolves with which Ireland fwarmed till the latter end of the laft century. As foon as thefe animals were extirpated, the numbers of the dogs decreafed ; for, from that pe- riod, they were kept only for ftate. g. The 'veriagus, or tumbler, is a fourth fpecies ; which took its prey by mere fubtilty, depending nei- ther on the fagacity of its nofe, nor its fwiftnefs : if it came into a warren, it neither barked, nor ran on the rabbits ; but by a feeming negleft of them, or atten- tion to fomething elfe, deceived the objeft till It got within reach, fo as to take it by a fudden fprlng. This dog was lefs than the hound, more fcraggy, had prickt up ears, and by Dr Caius's defcription feems to anfwer to the modern lurcher. The third fubdivlfion of the more generous dogs com- prehends thofe which were ufed In fowling. h. Firft, the Hlfpaniolus\ or fpanlel ; from the name, it may be fuppofed that we were indebted to Spain for this breed. There were two varieties of this kind : the firft ufed to fprlng the game, wjilch are the fame with our ftarters. The other variety was uf^d only for the net, and was called indtx or the fetter; a kind well known at prefent. This kingdom has been long remarkable for producing dogs of this fort, particular care having been taken to preferve the breed in the utmoft puritv. Thev are ftill diftingulflied by the name of Englijlo ' Spaniels; fo that, notwithftanding the derivation of the name, it is probable they are natives of Great Britain. i. The «5r«a/;Vt/j-, or finder, was another fpecies ufed in fowling ; was the fame with our water-fpaniel ; and was ufed to find or recover the game that was fliot- k. The MditteiiSy or fotor, the fpanlel gentle or com- forter of Dr Caius (the modern lap-dog), was the laft of this divlfioii. The Maltefe little dogs were as much efteemed by the fine ladles of paft times as thofe of Bologna are among the modern. Old Holllngnied is rldiculoufly fevere on the fair of his days for their N 2 excefiive Canis. * The reign of Q«eeii jElizabeth, Cynegettcon, CAN [ 100 exceffive paffion for tliefe little animals ; wKlch is fuffi- cient to prove that it was, in his time*, a novelty. 2. The fecond grand divifion of dogs comprehends the rtijlici, or thofe that were ufed in the country. a. The firft fpecies is the paJIoraUs, or fliepherd's €log ; which is the fame that is ufed at prefent, either in guarding our flocks, or in driving herds of cattle. This kind is fo well trained for thefe purpofes as to at- tend to every part of the herd, be it ever fo large ; con fine them to the I'cad; and force in every ilraggler, without doing it the leaft injury. b. The next is the villatkusy or eatenar'ms ; the malliff or ban dog ; a fpecies of great fize and ftrengtli, and a very loud barker. Caius tells us that three of thefe were reckoned a match for a bear; and alteration four for a lion: but from an experiment made in the Tower of London, that noble quadruped was foiind an unequal match to only three. Two of the dogs were difabled in the combat, but the third forced the lion to feek for fafety by flight. The Englifli bull-dog feems to belong to this fpecies ; and probably is tlie dog our author mentions under tlie title of lanlarius. Great Bri- tain was fo noted for its maft;iffs, that the Roman empe- yors appointed an officer in this ifland under the name • of procurator fynegii, whofe fole bufinefs was to breed, and tranfmit from hence to the amphitheatre, fuch as •would prove equal to the combats of the place. Gra- tius fpeaks in high terms of the excellency of the Bjri- tiflr dog. Atque ipfos liieat penetrare Britannos ? Q quanta ejl merces, et quantum hnpend'ia fupra! S'l non ad fpecitm, ment'tturofque dec ores Prot'mus: hac una ejl catulh jatlura Britannis. At magnum cum venit opus, promendaque virtus, Et vocat eSctrenio pra-ceps difcrhnine Mavcrs, Won tunc egreg'ws tantuni adnilrere MolofTos. If Britain's diftant coaft we dare explore, How much beyond the coft the valued ftore ? If lhape and beauty not alone we prize. Which natuj^ to the Brittjh hound denies : But when the mighty toil the huntfman warms. And all the foul is rous'd by fierce alarms. When Mars calls furious to th' enfanguin'd field, Even bold MohJJlans then to thefe mult yield. Strabo tells us that the mallifFs of Britain were trained to war, and were ufed by the Gauls in their battles ; and it is certain a well trained mafliff might be of ufe •in diltreffing fuch half-armed and irregular combatants as the adverfaries of the Gauls feem generally to have "been before the Romans conquered them.. 3. The kft divifion is that of the degencres, or curs. a. The firft of thefe was the ivappe, a name derived from its note ; its only ufe was to alarm the family by barking, if any perfon approached the houfe. b. Of this clafs was the 'verfator, or turn-fpit ; and laftly the Jditator or dancing-dog ; or fuch as was • |aught variety of tricks, and carried about by idle people hs a (hew. Thefe degaiares were of no certain fliape, be- ing mongrels or mixtures of all kinds of dogs. M. de Buffoa has given a genealogical table of all the knovi'n dogs, in which he makes the chien deberger, or flicpherd's dog, the origin of all, becaufe it is na- turally the moft fenfibki This table or tree is intend- ed not only to exhibit the different kiada of dogs, but Canis, ] CAN to give an idea of their varieties as ariflng from a dege- neration in particular climates, and from a commixture of the differ ;nt races. It is conftrufted in the form See Plate of a geographical chart, preferving as much as poffible CXXXI. the pofition of the different climates to which each va- riety naturally belongs. The fhepherd's dog, as already mentioned, is the root of the tree. This dog, when tranfported into Lapland, or other very cold chmates, afliunes an ugly appearance, and flirinks into a fmaller fize ; but, in Ruflia, Iceland, and Siberia, where the climate is lefs rigorous, and the people a little more advanced in civill/ation, he feems to be better accomi pllflied. Thefe changes are occufioned folely by the influence of thofe climates, which produce no great alteration in the figure of this dog ; for, in each of thefe climates, his ears are ere£l, his hair thick and long, his afpeft wild, and he barks lefs frequently, and in a different manner, than in more favourable cli- mates, where he acquires a finer pollih. The Iceland dog is the only one that has not his ears entirely eret beat aud trained to filence. The dog eats envioufly, with oblique eyes ; is an en«my to beggars ; bites at a flone flung at it; is fond of licking wounds; howls at certain notes in mulic, and often urines on hearing them. With regard to the propagation of dogs, the females admit the males before they are 12 months old. They remain in feafon 10, 12, or even 15 days, during which time they w ill admit a variety of males. They comc- ■in feafon generally twice in the year, and more fre- ^qirently in the cold than in the hot months. The male difcovers the condition of the female by the fmell; but (he feldom admits him the firil fix or feven days. One coitut CAN F K Canis. coitus will make her conceive a great number of young ; but, when not reftrained, fhe will admit feveral dogs every day : fhe feems to have no choice or predilec- tion, except in favour of large dogs: from this circum- ftance it fometimes happens, that a fmall female, who has admitted a mallifF, perifhes in bringing forth her young. During the time of copulation, thefe animals cannot feparate themfelves, but remain united fo long as the erection fubiiils. This is owing to the ftrufture of the parts. The dog has not only a bone in his pe- nis,, but in the middle of the corpus cavernofum there is a large hollow, which is blown vip in the time of e- reftton to a confiderable bulk. The female, on the other hand, has a larg-er clitoris than perhaps any other animal : befides, a large firm protuberance rifes in the time of copulation, and remains perhaps longer than that of the male,, and prevents him from retii'ing till it fubfides : accordingly, after the aft of copulation is over, the male turns about in order to reft himfelf on his legs, and remains in that polition till the parts turn flaccid. The female goes with young about, nine weeks. They generally bring forth from fix to twelve puppies. Thofe of a fmall fize bring forth five, four, and fometimes but two. They continue to copulate and bring forth during life, which lafts generally about 14 or 15 years. The whelps are commonly blind, and cannot open their eyes till the loth or 12th day: the males are like the dog, the females like the bitch. In the fourth month, they lofe fome of their teeth, which are foon fucceeded by others. The dog has fuch a ftrong refemblance to the wolf and the fox, that he is commonly fuppofed to be the production of one or other of thefe animals tamed and civiKzed. BufFon informs us, that he kept a young dog and a young wolf together till they were three years of age, without their difcovering the leaft incli- nation to copulate. He made the fame experiment upon a dog and a fox ; but their antipathy was rather increafed when the female was in feafon. From thefe experiments he concludes, that dogs, wolves, and foxes, are perfeftly difl:in£t genera of animals. There has, however, been lately an inftance to the contrary: Mr Brooke, animal-merchant in Holborn, turned a wolf to a Pomeranian bitch in heat ; the congrefs was immediatCj and as ufual between dog and bitch : fhe produced ten puppies. Mr Pennant faw one of them at Gordon Caftle, that had very much the refemblance of a wolf, and alfo much of its nature ; being (lipped at a weak deer, it inftantly caught at the animal's throat and killed it. " I could not learn (fays Mr Pen- nant) whether thi-s mongrel continued its fpecies; but another of the fame lund did, and flocked the neigh- bourhood of Fochabers, in the county of Moray (where it was kept), with a multitude of curs of a moil wolfifh afpe£L — There was lately living a mongrel offspring of this kind. It greatly refembled its wolf pm-ent. It v/^as firft the property of Sir Wolftein !0ixey ; afterwards of Sir Wiilughby Afton. During day it was very tame ; but at night fometimes relapfed into feVocity. It never barked, but rather howled ; when it came into fields where fheep were it would feign lamenefs, but if no, one was prefent would in- ftantly attack them. It had been feen in copulation vvith a bitch, which afterwards pupped : the breed was ifiDaginedto. refemble in many refpe(5ls the fuppofed ^3 ] e A N fire. It died between the age of five and fix.— The Cam's, bitch will alfo breed with the fox. The woodman of — — v— the manor of Mongewell, in Oxfordfhire, has a bitch, which conftantly follows him, the offspring of ff and doing mifchief. I brought up one till the age of 1 8 or 1 9 months, in a court along with fowls, none of which he ever attacked ; but, for his firft eflTay, he killed the whole in one night, withr O out CAN [ 106 ] CAN Canis: out eating any of them. Another, having broken V— his chain, run off, after killing a dog with whom he had lived in great familiarity." Whole countries are fometimes. obliged to arm, in ©rder to deftroy the wolves. Princes have particular equipages for this fpecies of hunting, which is both ufeful and neceflary. Hunters diftinguifh wolves into ymng, old, and very old. They know them by the tracks of their feet. The older the wolf, his feet is the larger. The {he-wolf's feet are longer and more {lender ; her heel is alfo fmaller, and her toes thinner. A good blood-hound is neceflary for hunting the wolf: and, when he falls into the fcent, he mull be coaxed and encouraged; for all dogs have an averfion from the wolf, and proceed with coldnefs in the chace. When the wolf is ralfed, the gre-hounds are let loofe in pairs, and one is kept for diflodging him, if he gets under cover ) the other dogs are led before as a referve. The firft pair are let loofe after the wolf, and are fupported by a man on horfe-back ; then the fecond pair are let loofe at the diftance of feven or eight hundred paces ; and, laftly, the third pair, when the other dogs begin to join and to teaze the wolf. The whole together foon reduce him to the lail extre- mity ; and the hunters complete the bufmefs by ttab- bing him with a dagger. The dogs have fuch a reluc- tance to the wolf's flefh, that it muft be prepared and feafoned before they will eat it. The wolf may alfo be hunted with beagles or hounds ; but as he darts always ftraight forward, and runs for a whole day without Hopping, the chace is irkfome, unlefs the beagles be fupported by grey-hounds, to teaze him, and give the hounds time to come up. Wolves are now fo rare in the populated parts of America, that the inhabitants leave their flieep the whole night unguarded : yet the governments of Pen- fylvania and New Jerfey did fome years ago allow a reward of twenty fhillings, and the laft even thirty fliillings, for the killing of every wolf. Tradition in- formed them what a fcourge thofe animals had been to the colonies ; fo they wifely determined to prevent the like evil. In their infant ftate, wolves came down in multitudes from the mountains, often attracted by t'he fmell of the corpfes of hundreds of Indians who died of the fmall-pox, brought among them by the Europeans : but the animals did not confine their in- fults to the dead, but even devoured in their huts the fick and dying favages. Befides being hunted, wolves are deftroyed by pit- falls, traps, or poifon. A peafant in France who kills a wolf, carries its head from village to village, and col- lefts fome fmall reward from the inhabitants : the Kirghis-Coflacks take the wolves by the help of a large hawk called beriut, which is trained for the diverfion, and will fallen on them and tear out their eyes. Britain, a few centuries ago, was much infefted by them. It was, as appears by Hollingfhed, very noxious to the flocks in Scotland in 1577; nor was it entirely extir- pated till about 1680, when the laft wolf fell by the hand of the famous Sir Ewen Cameron. We may therefore with confidence affert the non-exiftence of thefc animals, notwithftanding M. de Bulion maintains that the Englifh pretend to the contrary* It has been a received opinion, that the other parts of thefe kingdoms were in early times delivered from this peft by the care of king Edgar. . la England he attempted to effeft it, hy commuting the punifhments of certain crimes into the acceptance of a certain number of wolves tongues from each criminal ; and in Wales by con- verting the tax of gold and filver into an annual tax of 300 wolves heads. But, notwithftanding thefe his endeavours, and the affertions of fome authors, his fcheme proved abortive. We find, that fome cen- turies after the reign of that Saxon monarch, thefe animals were again increafed to fuch a degree as to become again the objeft of royal attention : ac- cordingly Edward I. iflued out his royal mandate to Pe- ter Corbet to fuperintend and affift in the deftruc- tion of them in the feveral counties of Gloucefter Worcefter, Hereford, Salop, and Stafford; and in the adjacent county of Derby (as Cambden, p. 902, informs us), certain perfons at Wormhill held their lands by the duty of hunting and taking the wolvea that infefted the country, whence they were fty- led 7 ] CAN mal, formerly but imperfedly known, the following CaftU. account is given by Dr Sparmann in his Voyage to the ^"~nr" Cape. *« The night, or the duflc of the evening only, is the time in which thefe animals feek their prey, after which they are ufed to roam about both feparately and in flocks. But one of the mofl; unfortunate properties of this creature is, that it cannot keep its own coun^ fel. The language of it cannot eafily be taken down upon paper ; however, with a view to make this fpe- cies of wolf better known than it has been hitherto, I ftiall obferve, that it is by means of a found fomething like the following, aaiiae, and fometiraes ooao, yelled out with a tone of defpair {at the interval of fome mi- nutes between each howl), that nature obliges this, the mofl: voracious animal in all Africa, to difcover it- felf, juft as it does the mofl: venomous of all the Ame- rican fei-pents, by the rattle in its tail, itfelf, to warn every one to avoid its mortal bite. This fame rattle ■ fnake would feem, in confequence of thus betraying its own defigns, and of its great inaftivity (to be as it were nature's flep-child), if, according to many credible accounts, it had not the wondrous property of charming its prey by fixing its eye upon it. The like is affirmed alfo of the tiger-wolf. This creature, it is true, is obliged to give information againfl; itfelf; but, on the other hand, is aftually pofTefTed of the pe^ cuKar gift of being enabled, in fome meafure, to imi- tate the cries of other animals ; by which means this arch-deceiver is fometimes lucky enough to beguile and attra6i: calves, foals, lambs, and other animals. Near fome of the larger farms, where there is a great deal of cattle, this ravenous beafl is to be found almofl every night ; and at the fame time frequently from one hour to another betraying itfelf by its howHngs, gives the dogs the alarm. The peafants affured me, that the cunning of the wolves was fo great (adding, that the trick had now and then even fucceeded with fome of them), that a party of them, half flying and half defending themCelves, would decoy the whole pack of dogs to follow them to the difl:ance of a gun-fliot or two from the farm, with a view to give an opportunity to the reft of the wolves to come out from their am- bufcade, and, without meeting with the leaft refift- ance, carry off booty fufficient for themfelves and their fugitive brethren. As the tiger-wolf, though a much larger and ftronger animal, does not venture, without being driven to the utmoft neceffity, to meafure its ftrength with the common dog, this is certainly an evident proof of its cowardice. Neither does this fame voracious beaft dare openly to attack oxen, cows, horfes, or any of the larger animals, while they make the leaft appearance as if they would defend themfelves, or even as long as they do not betray any figns of fear. On the other hand, it has art enough to rufh in upon them fuddenly and unexpectedly, at the fame time fetting up a horrid and ftrange cry, fo as to fet them a running in confequence of the fright, that it may af- terwards keep clofe to their heels with fafety, till it has an opportunity with one bite or ftroke to rip up the belly of its prey (even though it fliould be fo large an animal as a draught-ox), or elfe give it fome dan- gerous bite, and fo at one fingle bout make itfelf mafter of its antagonift. On this account the peafants are cbligejto drive their cattle liome every evening before O 2 it CAN [ ic Canis it is dark, excepting the more confiderable droves of ». draught-oxen, which they let roam about day and night to feek their food unattended, by reafon that they are ufed both to the country and the artifices of the wolves, and can therefore the eafier depend upon and defend each other. " Travellers, on the other hand, who are obliged to keep on in their journey, frequently fuffer great loffes by turning their cattle out at night ; efpecially of the young ones, which are eafiert feared. The Hottentots informed me that it was ftill within the memory of man, that the tiger- wolf was bold enough to fteal upon them and moleft them in their huts, particularly by carrj'ing off their children. This, however, is now no longer the cafe ; a circumftance, perhaps, pi'oceed- ing from the introduCllon of fire-arms into the coun- try, a circumftance which, in thefe latter times, has caufed this, as well as other wild beafts, to ftand in greater awe of man than it did formerly. I have heai'd the following ftory of the tiger-wolf mentioned, as be- ing related in a certain treatife on the Cape, of v>^hich I now cannot exactly remember the title. The tale is laughable enough, though perhaps not quite fo pro- bable. * At a feaft near the Cape one night, a trum- peter who had got his fill Avas carried out of doors, in order that he might cool himfelf, and get fober again. The fcent of him foon drew thither a tiger-wolf, which threw him on his back, and dragged him along with Lim as a corpfe, and confequently a fair prize, up to- wards Table-mountain. During this, however, our drunken mufician waked, enough in his fenfes to know the danger of his fituation, and to found the alarm with his trumpet, which he carried failened to his fide. The wild beait, as may eafily be fappofed, was not lefs frightened in his turn.' Any other befides a trum- peter w^ouid, in fuch circumllances, have undoubtedly been no better than wolf's meat. " In the mean while it is certain, that thefe wolves are to be found alraoil every dark night about the lhambles at the Cape, where they devour the offals of Bones, Ikin, &c. which are thrown out there in great quantities, and drag away with them what they catmot eat. The inhabitants repay thefe good offices of the hyaena with a free and unlimited privilege of accefs and egrefs. The dogs too hereabouts, perfeifly accuftomed to their company, are faid never to throw any impe- diment in their way; fo that the beaft, entertained and fed in the very heart of the town, has been feldom known to do any mjfchief there. It is likewife a well- known faft, that thefe wolves, in different parts of Africa, exhibit different degrees of courage ; this, however, may perhaps proceed from their being of different fpecies in different parts. " Yet in this very greedinefs of the hysena, and its difpofition to confume every thing it can get at, the provident economy of nature is abundantly evinced. The flowery fields at the Cape would certainly foon become hideous and disfigured with carcafes and flcele- tons, the relicks of the great qviantity,of game of all forts which graze and die there in fucceffion, were not the tiger-wolf manifeftly fubfervient to nature in the regulation of her pohce, by clearing her theatre from them ; nay, I had almoft faid the wolf alone : for lions and tigers, for example, never eat bones, and are not very fond of cai'cafes. Thefe are ferviceabie ia )8 ] CAN another way. They make the other animals vigilant Cam's, and attentive to the funftions for which nature has de- figned them ; and befides anfwering feveral other in- tentions of providence, they ferve, in conjunftion with mankind, to keep in a jufl equilibrium the increafe of the animal kingdom ; fo that it may not exceed the fupplies afforded it by the vegetable part of the crea- tion, and by this means prevent the neceffary renewal of the latter by feeds, &c. and thus, by defokting it and laying it wafte, in the end impoverifh and deflroy themfelves, and die moft wretched viAims to want and hunger ; fo that, notwithflanding the immeafe quanti- ties of game exifling in this country, there are very feldom found any bones in the haunts they have left, and never after the tiger, lion, jackal, wild cat, and wild dog. Thefe latter animals, that they may not encumber and litter the ground which nature has or- dained them to clear, never go out of their dens and caverns when they find themfelves iick and difabled ; but there, oppreffed with hunger and difeafe, await the tranfitory moment, when they muil pay obedience to nature's lafl law." IV. The MEXICAN us has a fmooth crooked tail. The Mexi- The body is afli-coloured, variegated withyeUow fpots.canus. It is a native of Mexico, and is called the mountain-cat by Seba. , It agrees with the European wolf ia its manners ; attacks cattle, and fometimes men. V. The VuLPES, or Fox, has a llraight tail, white at The Fos, the point. His body is yellowifh, or rather llraw-co- loured ; his eats are fmall and ereft ; his lips are whi- tifh, and his forefeet black. From the bafe of the tail a Rrong fcent is emitted, which to i'ome people is very fragrant, and to others extremely difagreeable. The fox is a native of ahsiofl every quarter of the globe, and is of fuch a wild and favage nature that it is impoifible fully to tame him. He ia efteemed to be the moft fagacious and the moft crafty of all beafts of prey, I'he former quality he fhows in his method of pro- viding himfelf with an afylum, where he retires from preffing dangers, where he dwells, and where he brings up his young : and his craftinefs is chiefly difcovered by the fchemes he falls upon in order to catch lambs, geefe,hens, and all kinds of fmall birds. The fox fixes his abode on the border of the wood, in the neighbourhood of cottages : he llftens to the crowing of the cocks and the cries of the poultry. Hefcents them at a diftance; he choofes his time with judgment; he conceals his road as well as his defign ; he flips forward with cau- tion, fometimes even traihng his body, and feldom. makes a fruitlefs expedition. If he can leap the wall, or get in underneath, he ravages the court-yard, puts all to death, and then retires foftly with his prey, which he either hides under the herbage, or carries off to his kennel. He returns in a few minutes for an- other, which he carries off, or conceals in the fame manner, but in a different place. In this way he pro- ceeds till the progrefs of the fun, or fome movements- perceived in the houfe, advertife him that it is time to fufpend his operations, and to retire to his den. He plays the fame game with the catchers of thrufhes, wood-cocks, &c. He vifits the nets and bird-lime very early in the morning, carries off fucceffively the birds which are entangled, and lays them in different places, efpecially near the fides of high- ways, in the furrows, under the herbage or bruihwood^ where they fometimes CAN Canis . lie two or three days ; but he knows perftcTlIy where to find them when he is in need. He hunts the young hares in the plains, feizes old ones in their feats, never mifles thofe which are wounded, digs out the rabbits in the warrens, difcovers the nefts of partridges and quails, feizes the mothers on the eggs, and deftroys a va ft quantity of game. The fox is exceedingly vora- cious ; befides fleih of all kinds, he eats, with equ;!l avidity, eggs, milk, cheefe, fruits, and particularlv grapes. When the young hares and partridges fail him, he makes war againft rats, field-mice, ferpents, li- zards, toads, &c. Of thefe he deftroys vafl numbers ; and this is the only fervice he does to mankind. Pie is fo fond of honey, that he attacks the wild bees, wafps, and hornets. They at firft put him to flight by a thoufand ftlngs ; but he retires only for the pur- pofe of rolling himfelf on the ground to crufh them ; and he returns fo often to the charge, that he obliges them to abandon the hive, which he foon uncovers, and devours both the honey and wax. In a word, he eats fifhes, lobfters, grafa-hoppers, &c. The fox is not eafily, and never fully tamed ; he lan- guifhes when deprived of liberty ; and, if kept too long in a domeftic ftate, he dies of chagrin. Foxes produce but once a year ; and the Httcr commonly confift of four or five, feldora fix, and never lefs than three. When the female is full, fhe retires, and feldom goes out of her hole, where fiie prepares a bed for her young. She comes in feafon in the winter ; and young foxes are found in the month of April. When (he perceives that her retreat is difcovered, and that her young have been difturbed, flie carries them off one by one, and goes in fearch of another habitation. The young are brought forth blind; like the dogs, they grow i8 months, or two years, and live 13 or 14 years. — The fox, as well as the congenerous wolf, will produce with the dog-kind, as noticed above. The fenfes of the fox are equally good as thofe of the wolf ; his fentlment is more delicate ; and the or- gans of his voice are more pliant and perfect The wolf fends forth only frightful howKngs ; but the fox barks, yelps, and utters a mournful cry like that of the peacock. He varies his tones according to the differ- ent fentiments with which he is affefted : he has an accent peculiar to the chace, the tone of defire, of com- plaint, and of forrow. He has another cry expreffive of acute pain, which he utters only when he is (hot, or has fome of his members broken ; for he never com- plains of any other wound, and, like the wolf, allows himfelf to be killed with a bludgeon without complain- ing ; but he always defends himfelf to the laft with great courage and bravery. His bite is obltinate and dangerous ; and the fevereft blows will hardly make him quit his hold. His yelping is a fpecies of bark- ing, and confifts of a quick fucccflion of fimilar tones ; at the end of which he generally raifes his voice fim.ilar to the cry of the peacock. In winter, and particukr- ly during froil and Ihow, he yelps perpetually ;,- but, in fummer, he is almoff entirely filent, and, during this feafon, he cafts his hair. He fleeps found, and maybe eafily approached without wakening :. he fleeps in a round form, like the dog ; but, when he only repofes himfelf, he extends his hind legs, and Hes on his belly. It is in this fituation that he fpies the birds along the hedges, and meditates fchemes for their furgrite. The [ 109 ] CAN fox flies when he hears the explofion of a gun, or fmells Canis. gun- powder. He is exeedingly fond of grapes, and does ' v — ''^ much raifchief in vineyards. Various methods are daily employed to dellroy foxes : they are hunted with dogs ; iron traps are frequently fet at their holes ; and their holes are fometimes fmoked to make them rua out, that they may the more readily fall into the fnares or be killed by dogs or fire-arms. * The chace of the fox requires lefs apparatus, and is- more amufing, than that of the wolf. To the latter every dog has great reluftance : but all dogs hunt the fox fpontaneoufly and with pleafure ; for, thouo-h his odour be ftrong, they often prefer him to the ilag or the hare. He may be hunted with terriers, hounds, &c. Whenever he finds himfelf purfued, he runs to his hole ; the terriers with crooked legs, or turnfpits, go in with raoft eafe. Tiiis mode anfwers very well when we want to carry off a whole htter of foxes, both mother and young. While the mother defends' her- fclf againft the terriers, the hunters remove the earth above, and either kill or feize her alive. But, as the holes are often under rocks, the roots of trees, or funk, too deep in the ground, this method is frequently un- fuccefsfuL I he moft certain and moft common me- thod of huntmg foxes, is to begin with fhutting up their holes, to place a man with a gun near the en= trance, and then to fearch about with the dogs. When they fall in with him, he immediately makes for his hole ; but, when he comes up to it, he is met with a difcharge from the gun. If he efcapes the fiiot, he runs with full fpeed, takes a large circuit, and returns again to the hole, where he is fired upon a fecond time • but, finding the entrance ihut, he now endeavours to efcape by darting ftraight forward, with the defian of ' never revifiting his former habitation. He is ''then purfued by the hounds, whom he feldom fails to fa- tigue, becaufe he purpofely paffes through the thick-ft parts of the foreft or places of the moft difficult accefs where the dogs are hardly able to follow him • and' when he take? to the plains, he runs ftraight out,' with' out ftopping or doubling. Of all animals the fox has the moft fignificant eye, by which it expreffes every paffion of love fear, hatred, &c. It is remarkably play{"nl ; but' hke all favage creatures half reclaimed, will on the Icaft offence bite thofe it is moft familiar, with It It a great admirer of its bu/hy tail, with which it frequently amufes and exercifes itfelf, by running- in circles to catch it : and, in cold weather, wraps' It round Its nofe. The fmell of this animal is in gene- ral very ftrong, but that of the urine is remarkably fe- tid. This feems fo offenfive even to itfelf, that it will/ take the trouble of digging a hole in the ground, ftretching its body at full length over it ; and there af- ter depofitmg Its water, cover it over with the earth as the cat does.its dung. The fmell is fo obnoxious, that It has often proved the means of the fox's efcape from the dogs ; who have fo ftrong an averfion at the filthy effluvia, as to avoid encountering the animal it came from. It IS faid that the fox makes ufe of its urine as an expedient to force the cleanly badger from its habita^ tation : whether that is the means, is rather doubtful » but that the fox makes ufe of the badger's hole is cer! ' tain : not through want of ability to form its own re- treat, but to fave itfelf fome trouble ; for after the ex,- pulfioaa 'Cants. CAN [ no ] pUlfion of the firft inhabitant, the fox improves as well as enlarges it confxderably, adding feveral chambers, and providently making feveral entrances to fecure a retreat from every quarter. In warm weather, it will quit its habitation for the fake of baflcing in the fun, or to enjoy the free air ; but then it rarely lies expofed, but choofes fome thick brake, that it may reft fecure from furprize. Crows, magpies, and other birds, who confider the fox as their cofnmon enemy, will often, by their notes of anger, point out its retreat. — The iliin of this animal is furnifhed with a warm foft fur, which in many parts of Europe is ufed to make muffs and to line clothes. Vaft numbers are taken in Le Val- lais, and the Alpine parts of Switzerland. At Lau- fenne there are furriers who are in poifeflion of be- tween 2000 and 3000 llcins, all taken in one winter. Of the fox there are feveral varieties, derived from colour ; as, 1. The field-fox, or alopex of Linnaeus, who makes it a diftindl fpecies ; but it is every way the fame with the common fox, except in the point of the tail, which is black. 2. The crofs-fox, with a black mark pafllng tranf- verfely from (houlder to fiioulder, with another along the back to the tail. It inhabits the coldeft parts of Europe, Afia, and North -America : a valuable fur, thicker and fofter than the common fort; great num- bers of the flcins are imported from Canada. 3. The black fox is the moft cunning of any, and its fldn the moft valuable; a lining of it is, in RufTia, ^ efteemed preferable to the fineft fables : a fingle flcin vill fell for 400 rubles. It inhabits the northern parts of Afia and North- America. The laft is inferior in goodnefs. 4. The brant fox, as defcrlbed by Gefner and Lin- naeus, is of a fiery rednefs ; and called by the firft brand-fuchf, by the laft brandraef ; it is fcarce half the fize of the common fox : the nofe is black, and much lharper ; the fpace round the ears ferruginous ; the forehead, back, (houlders, thighs, and fides black mix- ed with red, afh-colour, and black; the belly yellowifli; the tail black above, red beneath, and cinereous on its fide. It is a native of Penfylvania. 5. The corfac-fox, with upright ears, foft downy hair; tail bufliy ; colour in fummer pale tawney, in winter grey : the bafe and tip of the tail black ; a fmall kind. It inhabits the defarts beyond the Yaik : lives in holes howls and barks : is caught by the Kir- ris Cafl'acks with falcons and gre-hounds; 40 or 50.000 are annually taken, and fold to the Ruffians, at the rate of 40 kopeiks, or 20 pence, each : the former ufe their fldns inftead of money : great numbers are fent into Turky. r , • 1 6. There are three varieties of foxes found in the mountainous parts of Britain, which differ a little in form, but not in colour, from each other. They are diftingulflied in Wales by as many different names. The m'llgh or gre-hound-fox, is the largeft, talleft, and boldeft ; and will attack a grown Iheep or wedder : the maM-fox is lefs, but more ftrongly built : the corgi, or cur-fox is theleaft ; lurks about hedges, out-hou(es, &c. and is the moft pernicious of the three to the fea- thered tribe. The firft of thefe varieties has a white tag or tip to the tail ; the laft a black. When hunted, they never run diredly forward, but make a great raa- CAN ny doublings and tnrnlngs ; and when in danger of be- Cams, ing taken, they emit fuch a fmell from their pofteriors ' v—- ' that the hunters can hardly endure it. VI. The Lagopus, or arftlc fox, with a (harp nofe ; The arftic ftiort rounded ears, alraoft hid in the fur ; long and Fox. foft hair, fomewhat woolly ; (hort legs ; toes covered on all parts, like that of a common hare, with fur ; tail fliorter and more buihy than that of the common fox, of a bluifh grey or afli colour, fometimes white : the young of the grey are black before they come to matu- rity : the hair much longer in winter than fummer, as is ufual with animals of cold climates. It inhabits the countries bordering on the Frozen Sea; Khamfchatka, the ifles between it and America, and the oppofite parts of America difcovered in captain Bering's expedi- tion, 1741 ; is again found in Greenland, Iceland, Spitzbergen, Nova Zembla, and Lapland. _ It bur- rows undergroiind, forms holes many feet in length, and ftrews the bottom with mofs. In Greenland and Spitzbergen it lives in the cliffs of rocks, not being able to burrow, by reafon of the froft : two or three pair inhabit the fame hole. They are in heat about Lady-day ; and during that time, they continue in the open air, but afterwards take to their holes. They go with young nine weeks: like dogs, they continue united in copulation : they bark like that animal, for which reafon the Ruffians call them pefzt'i, or dogs. They have all the cunning of the common fox ; prey on geefe, ducks, and other water-fowl, before they can fly; on groufe of the country, on hares, and the eggs of birds ; and in Greenland (through neceflity) on ber- ries, fliell-fifh, or any thing the fea flings up. But their principal food in the north of Afia and in Lapland is the leming, or Lapland marmot : thofe of the countries' laft mentioned are very migratory, purfuing the leming which is a wandering animal : fometimes thefe foxes will defert the country for three or four years, probably in purfuit of their prey ; for it is well known that the migrations of the leming are very inconftant, it ap- pearing in fome countries only once in feveral years. ^ The people of Jcnefea fufpeft they go to the banks 01 the Oby. Their chief rendezvous is on the banks of the Frozen Sea, and the rivers'^ that flow into it, where they are found in great troops. The Greenlanders take them either in pitfalls dug in the fnow, and baited with the capehn fifh ; or in fprings made with whale- bone, laid over a hole made in the fnow, ftrewedover at bottom with the fame kind of fifti ; or in traps made like little huts, with flat ftones, with a broad One by way of door, which falls down (by means of a ftring baited on the infide with a piece of fiefh) whenever the fox enters and pulls at it. The Geeenlanders pre- ferve the fl rowed with paddles, which are pieces of light wood fomewhat refembhng a corn-fnovel ; and, inftead of rowing with it horizontally like an oar, they ma- nage it perpendicularly. The fmall canoes are very naiTow, having only room for one perfon in breadth, and feven or eight lengthwife. The rowers, who are generally American favages, are very expert in mana- ging their paddles uniformly, and in balancing the ca- »oes viith their bodies ; which would be difficult for a ftranger to do, how well accuftoined foever to the con- Canoni dufting of European boats, becaufc the canoes are ex- — — v— tremety light, and liable to be overturned. The Ame- rican Indians, when they are under the neccffity of landing to avoid a water-fall, or of crolTing the land from one river to another, carry their canucs on their heads, till they arrive at a place where they can launch them again. This is the general conflrudiion of canoes, and method of managing them : but fome na- tions have vefiels going under the name of canoes, which differ confiderably from the above ; as the inha- bitants of Greenland, Hudfon's-bay, Otaheite, &c. CANON, a perfon who poffeffes a prebend, or re- venue allotted for the perfoi-mance of divine fervice, in a cathedral, or collegiate church. Canons are of no great antiquity : Pafchier obferves, that the name canon was not known before Charle- magne ; at kail the firft we hear of are in Gregory de Tours, who mentions a college of canons inftituted by Baldwin XVI. archbilhop of that city, in the time of Clotharius I. The common opinion attributes the inftitution of this order to Chrodegangus, bifiiop of Metz, about the middle of the eighth century. Originally canons were only priefts, or inferior ec- clefiaftics, who lived in community ; refiding by the cathedral church, to aflift the bifliop ; depending en- tirely on his will ; fupported by the revenues of tlie bifhopric ; and living in the fame houfe, as his domef- tics, or counfellors, &c.. They even inherited his moveables, till the year 817, when this was prohibited by the council of Aix-la-Chapelle, and a new rule fub- ftituted in the place of that which had been appointed by Chrodegangus, and which was obferved for the moft part in the weft till the twelfth century. By de- grees, thefe communities of priefts, ftiaking off their dependence, formed feparate bodies ; whereof the bi- fhops, however, were flill heads. In the tenth cen- tur)', there wei'e communities or congregations of tlie fame kind, eftabliilied even in cities where there were no bifhops : thefe were called coUegiates, as they ufed the terms congregation and college indifferently : the name chapter, now given to thefe bodies, being much moje modern. Under the fecond race of the French kings, the canonical, or collegiate life, had fpread It- felf all over the country ; and each cathedral had its chapter, diftinA from the reft of the clergy. They had the name canon from the Greek xa'^v, which fig- nifies three different things ; a rule, a penfion, or fixed revenue to live on, and a catalogue or matricula ; all which are applicable to them. In time, the canons freed themfelves from their rules, the obfervance relaxed, and, at length, they ceafed to live in community : yet they ftill formed bodies ; pre- tending to other funcftions befides the celebration of the common office in the church ; yet affuming the rights of the reft of the clergy ; making themfelves as a neceffary council of the bifhop ; taking upon them the admiiiiftration of a fee during a vacancy, and the eledlion of a biftiop to fupply it. There are even fome chapters exempt from the jurifditf ion of the bi- fiiop, and owning no head but their dean. After the example of cathedral chapters, collegiate ones alfo con- tinued to form bodies, after they had abandoned living in community. Canons are of various kinds j as, Cardinal CAN [ I Canofti. Cardinal Canoks^ which are thofe attached, and, as "~v ' the Latins call it, incard'mati to a church, as a priell h to a parifli. jyomcellary Canons, were young canons, who, not being in orders, had no right in any particular chap- ters. ExpeBati've Canons, wexc fuch as, without having ^ny revenue or prebend, had the title and dignities of canons, a voice in the chapter, and a place in the choir; till fuch time as a prebend (hould fall. Foreign CANONi, were fuch as did not officiate in the canonries to which they belonged. To thefe were op- pofi;d nianrioriaJ7 canons, or canons refidentiary. J.ay or honorary Canons, are fuch among the laity as have been admitted, out of honour and refpect, in- to fome chapter of caiions. Regular Canons, are canons that llill live in coin- rnunity ; and who, like religious, have, in procefs of time, to the practice of their rules, added the folemn profcflion of vows. They are called regulars, to dif- tinguifh them from thofe fecular canons who abandon living in community, and at the fame time the ob- - fervance of the canons made as the rule of the clergy, for the tnaintenance of the ancient difcipline. The canons fubfifted in their fanplicity till the eleventh, fome fay the twelfth century, when fome of them, fe- parating from the community, took with them the name of canons, or acephalous priefts, becaufe they declined to live in community with the bifhop ; and thofe who were left thenceforth acquired the denomi- nation of canons regular, and adopted moft of the pro- feffions of the rule of St Auguftine. This order of re- gular canons of St Augulline was brought into Eng- land by Adelwald, confelTor to Henry I. who erefted a priory at Noftel in Yorkfhire; and obtained for them the church of Carlifle as an epifcopal fee, with the pii- vilege of choofmg their own bifhop* They were fin- gukrly protected and encouraged by Henry I. who gave them the priory of Danftable in 1107, and by queen Maud, who, in the following year, gave them the priory of the Holy Trinity in Lotrdon. It appears, that under the reign of Edward I. they had 53 priories. Tertiary Canons, thofe who had only the third part cf the revenues of the canonlcate. Canon, in an ecclefiaftical fenfe, is a law or rule, either of doctrine or difcipline, enacted efpecially by a oouncilj and confirmed by the authority of the fove- rcign. Canons are properly decifions of matters of religion; or regulations of the policy and difcipline of a church, made by councils, either general, national, or pro- vincial. Such are the canons of the council of Nice, or Trent, &c. There have been various coUedllons of the canons of the Eallern councils ; but four principal ones, each ampler than the preceding. The firfl, according to Ufher, A. D. 3B0, containing only thofe of the firll oecumenical council, and the firlt provincid ones: they were but 1 64 in number. To thefe, Dionyfms Exi- guus, in the year 520, added th-e 50 canons of the apoftles, and thofe of tiie other general councils. The Greek canons in this fecond coileftion end with thofe of the council of Chalcedon ; to which are fubjoined thefe of the council of Sardica, and the African coun- 7 1 CAN cils. Tht fourth and laft collcdlion comes down as Canon, low as the fecond council of Nice ; and it is on this ^— nr-"" that Balfamon and Zonaras have commented. j^poJloUcal Canons, are thofe which have been ufu- ally afcribed to St Clement. Bellannin, Baronius, &c. will have them to be genuine canons of the apoftles : Cotelerius obferves, that they cannot be afcribed to the apoftles or Clement, becaufe they ai'e not received with other books of fcripture, are not quoted by the wri- ters of the firft ages, and contain many things not a- greeable to the apoftolical times : Hincmar, De Mar- ca, Beveridge, &c. take them to be framed , by the bifliops wlio xvere the apoftles difciples in the fecond or third century ; S. Bafnage is of opinion, that they were collefted by an anonymous writer in the fifth century ; but Daille, &c. maintain them to have been forged by fome heretic in the fixth century ; and S. Bafnage conjectures, that fome of them are ancient, and others not older than the feventh century. The Greek church allow only 85 of them, and the Latins only 50 ; though there are 84 in the edition given of them in the Corpus Juris Canonici. Canon is alfo ufed for the authorifed catalogue o£ the facred writings. See Bible. The ancient canon, or catalogue of the books of the Old Teftament, was made by the Jews, and is ordina- rily attributed to Ezra ; who is faid to have diltri- buted them into the law, the prophets, and the ha- glographa, to which our Saviour refers, Luke, chap, xxiv. ver. 44. The fame divifion is alfo mentioned by . Jofephus, cont. Applon. This is the canon allowed to have been followed by the primitive church, till the council of Carthage j and, according to St Jerona, this confifted of no more than 22 books ; anfwering to the number of the He- brew alphabet ; though at prefent they are clafTed Into 24 divlfions, containing Genefis, Exodus, Leviticus, Numbers, Deuteronomy, Joftiua, Judges, Samuel, Kings, Ifaiah, Jeremiah, Ezeklel, the twelve minor prophets, the Pfalms, the Proverbs, Job, Canticles, Ruth, Lamentations, Ecclefialles, Either, Daniel, Ezra, comprehending the book of Nehemiah and the Chronicles. However, this order is not unlverfally obferved either among Jews or Chriftians : nor were all the books above enumerated admitted into the ca- non In Ezra's time. It is moft likely, fays Dr Pry- deaux, that the two books of Chronicles, Ezra, Ne- hemiah, Efther, and Malachi, were added in the time of Simon the Juft, when the canon was completed. But that council enlarged the canon very confiderably, taking Into It the books which we call apocryphal ; which the council of Trent has further enforced, en- joining all thefe to be received as books of Holy Scrip- ture, upon pain of anathema, and being attainted of herefy. The Romanifts, in defence of this canon, fay, that it is the fame with that of the council of Hippo, held In 393 ; and with that of the third council of Carthage, In 397, at which werejirefent 46 biftiops, and, among the reft, St Auguftine ; who declared that they received it from their fathers. Their canon of the New Teftament perfeftly agrees with ours. It confifts of books that are well known ; fome of which have been unlverfally acknowledged fuch are the four Gofpels, the Afts of the Apoftles, thirteen Epiftles of St Paul, one Epiftle of St Ptter, CAN Car.or. and one Epiftle of St Jolin : and others, Goncernin^ ■"""v which doubts were eiitertaincd, but which were after- wards received as genuine ; fuch are the epifde to the Hebrews, that of James, the fccond of Peter, the fe- cond and third of John, that of Jude, and tlie Reve- lation. Thefe books were written at difTerent times, and they are authenticated, not by the decrees of coun- cils, or infalhble authority, but by fuch kind of evi- dence as is thought fufliclent in the cafe of any other ancient writings. They were very extenfively diifufed ; they were read In every Chriftian fociety ; they were valued and preferved wJth care by the firft Chriftians ; they were cited by Chriftian writers of the fecond, third, and fourth century, as by Irenseus, Clement the Alexandrian, TertuUian, Origen, Eufebius, &c. and their genuinenefs is proved by the teftimony of thofe vvlio were contemporary with the apoftles therafelves, and by tradition. The four Gofpels, and moll of the other books of the New Teftament, were coUefted either by one of the apoftles, or fome of their difci- ples and fucceiTors, before the end of the firft century. The catalogue of canonical books furniilied by the more ancient Chriftian writers, as Origen about the year 210, Eufebius and Athanafius in 31,^, Epiphanius in 370, Jerome in 382, Auftin in 394, and many o- thers, agrees with thajt which is now received among Chriftians. For the time of writing the feveral books of the New Teftament, fee the titles of the books themfelves ; as the Gofpel of St Matthew, Mark, &c. Some of the fathers diftinguifti the infpired writings into three claffes ; proto-canonical, deutero-canonioal, and apocryphal. Pajchal Cjnon, a table of the moveable feafts, fliow- ing the day of Eafter, and the other feafts depending on it, for a cycle of 1 9 years. The pafchal canon is fuppofed to be the calculation of Eufebius of Csfarea, and to have been done by or- der of the council of Nice. Canon, in monaftic orders, a book wherein the re- ligious of every convent have a fair tranfcript of the rules of their order, frequently read among them as their local ftatutes. Tliis is alfo called regida, as con- taining the rule and inftitution of their order. The canon differs from the miffale, martyrologium, and necrologium. Canon, again, is ufed for the catalogue of faints acknowledged and canonized in the Roman church. Canon is alfo ufed, by way of exceflence, in the Romifti church, for the fecret words of the mafs, from the preface to the Pater ; in the middle of which the pi-ieft confecrates the hoft. The common opinion is, that the canon of the mafs commences with Te igifur, &c. The people are to be on their knees, hearing the canon ; and are to rehearfe it to themfelves, fo as not to be heard. Canon, in the ancient mufic, is a rule or method of determining the intervals of notes. Ptolemy, rcjefting the Ariftoxeiiian way of meafu- ring the intervals in mufic, by the magnitude of a tone (which was fuppofed to be formed by the difference between a diapente and a diateflaron ) , thought that mufical intervals fhould be diftinguifhed, according to the ratios or proportions which the founds terminating thof(; intervals bear to one anoth-er, when confidered [ 118 1 CAN according to their degree of acutenefs or ^avity ; C^ai-roa. which, before Aiiftoxenus, was the old Pythagorean * ~" way. He therefore made the diapafon confill in a double ratio ; the diapente, in a fefquialterate ; the diateffaron, in a fefquitertian ; and the tohe itfelf, in a fefquioftave ; and all the other intervals, according to the proportion of the founds that terminate them : wherefore taking the canon (as it is called) for a de- terminate Hne of any length, he fhows how this ca- non is to be cut accordingly, fo that it may reprefent the refpeftive intervals : and this method anfwers ex- aftly to experiment, in the different lengths of mufical chords. From this canon, Ptolemy and his followers have been called Canonici ; as thofe of Ariftoxenu« were called Mufici. Can©n, in modern mufic, Is a kind of fugue, which they call a perpetual fugue y becaufe the different parts beginning one after another, repeat inceflantly the fame air Formerly, fays Zarlino, they placed, at the head of perpetual fugues, particular direftions which fhowed how this kind of fugues was to be fung ; and thefe di- reftions being properly the rules by which perpetual fugues were compofed were called canon'r, rules, or ca- nons. From this cuftom, others taking the title for the thing fignified, by a metonimy, termed this kind of compofition canon. Such canons as are compofed with the greateft facility, and of confequence moft gaisrally ufed, begin the fugue either with the oftave or the u- nifon ; that is to fay, that every part repeats in the fame tone the melody of the preceding. In order to form 3 canon of this kind, it is only neceffary for the compo- ler to make an air according to his tafte ; to add in fcore as many parts as he choofes, where the voices in oftave or unifon repeat the fame melody; then formino- a fingle air from all thefe parts fucceflively executed, to try whether this fucceffion may form an entire piece which will give pleafure, as well in the harmony as the melody. In order to execute fuch a canouy he who fings the firft part begins alone, and continues till the air is fi- niflied; then recommences immediately, without any fufpence of found or interruption of time : as foon as he has ended the firft couplet, which ought to ferve for the perpetual fubjeft upon which the whole canon has been compofed^ the fecond part begins and repeats the fame couplet, whilft the firft who had begun pur- fues the fecond : others in fucceffion begiii, and pro- ceed the fame way, as foon as he who precedes, has reached the end of the firft couplet. Thus, by incef- fantly recommencing, an univerfal clofe can never be found, and the canon may be repeated as long as the fingers pleafe. A perpetual fugue may likewife confift of parts which begin with the intervals of a fourth or fifth ; or, in other words, eveiy part may repeat the melody of the firft, a fourth or a fifth higher or lower. It is then neceffary that the whole canon ffiould be' invented di prima in- ten-zloncy as the Italians fay ; and that fliarps or flats ftiould be added to the notes, whofe natural gradations do not anfwer exaftly, by a fourth or fifth, to the me- lody of the preceding part, and produce the fame in- tervals with itfelf. Here the compofer cannot pay the leaft regard to modulation; his only care is, that the melody may be the fame, which renders the formation of CAN [ : Canon, of a canon more difficult ; for at every tune wliea any ' * ■' part rcfumes the fugue, it takes a new key; it changes the tone almoft at every note, and what is ftill worfe, no part is at the fame time found in the fame tone with anotlier ; licnce it is that this kind of canons, in other refpefts far from being eafy to be purfued, never pro- duces a pleafing efteft, however good the harmony may be, and how jver pi'operly it may be fung. There is a thii-d kind of canon, but very fcarce, as well becaufe it is extremely difficult, as becaufe it is for the moft part incapable of giving pleafure, and can boaft no other merit but the pains which have been thrown away in its compofition. This may be called a double canon inveiieJ, as well by the inverfions which are prac- tlfedi in it with I'efpeft to the melody of the parts, as by thofe which are found among the parts themfelves, in finging. There is fuch an artifice in this kind of ca- non, that, whether the parts be fung in their natural order, or whether the paper in which they are fet be turned the contrary w^y, to fing them backward from the end to the beginning, in fuch a manner that the bafs becomes the upper part, and the reft undergo a li- milar change, ftill you have pretty harmony, and ftill a regular canon. The reader may confult RoufTeau's Dictionary in this article, where he is referred to plate D fig. 1 1 . for two examples of canons of this fort extrac- ted from Bontempi, who likewife gives rules foi their compofition. But he adds, that the true principle from which this rule is deduced will be found at the word Sjifieme, in his account of the fyftem of Tartini, to which we muft likewife once more refer the reader; as a quo- tatlcn of fuch length muft have protrafted our article to an enormous extent. To form a canon in which the harmony may be a little varied, it is neceffary that the parts fnould not fol- low each other in a fucceffion too rapid, and that the one fliould only begin a confiuerable time after the o- ther. When they follow one another fo immediately as at the diftance of a feraibreve or a minim, the duration is not fufficlent to admit a great number of chords, and the canon muft of neceffity exhibit a difagreeable mo- notony; but it is a method of compofing, without much difficulty, a canon in as many parts as the compofer choofes. Foe a canon of four bars only, will confift of eight parts if they follow each other at the diftance of half a bar; and by each bar which is added, two parts will conftantly be gained.- The emperor Charles VI. who was a great mwfician, and compofed extremely well, took much pleafure in compofing and finging canons. Italy is ftill replete with moft beautiful canons compofed for this prince, by the beft niafters in that country. To what has been faid by Roufieau, we need only fubjoin, that the Englifa caicli and the Italian canon are much the fame ; as any intelligent reader may perceive, from comparing tlie ftruflure and execution of the Englifli catci with the account of canons which has now been given. Canon, in geometry and algebra, a general rule for the folution cf all cafes of a like nature witli the prefent inquiry. Thus every laft ftep of an equation is a canon ; and, if turned into words, becomes a rule "to folve all queftions of the fame nature with that pro- pofed. CANON-Laiu, a colleftion of ecclefiaftlcal lav/s, fer- ving as, the rule and meafure of church-government. ig ] CAN The power of making laws ^yas exercifed by the Canon church before the Homan empire became Chriftian. The canon-law that obtained throughout the Weft, till , ,' the 1 2th century, was the colleftion of canons made by Uionyfius Exiguus in 520, the capitularies of Charle- magne, and the decrees of the popes from Sircius to Anaftafius. The canon-law, even when papal authority was at its height in England, war, of no force when it was found' to contradi(ft the prerogative of the king, the laws, fta- tutes, and cuftoms of the realm, or the doftrine of the " eftabliflied church. The ecclefiaftical jurifdiftion of the fee of Rome In England was founded on the canon-law ; and this created quarrels between kings and feveral archbiftiops and prelates who adhered to the papal ufurpation. Befides the foreign canons, there were feveral laws and conftitutions made here for the government of the church : but all tliefe received their force from the royal aflent ; and if, at any time, the ecclefiaftical courts did, by their fentence, endeavour to enforce obedience to fuch canons, the courts at common law, upon com- plaints made, would grant prohibition. The autho- rity vefted in the church of England of making canons, was afcertained by a ftatute of Henry "VIII. commonly called tlie ad of the clergy'' s fiibnilffion ; by v.hich they acknowledged, that the convocation had always been: affembled by the king's writ ; fo that though the power of making canons refided in the clergy met in convocation, their force was derived from the au- thority of tlie king's affenting to _and confirming them. The old canons continued in fidl force till the reign of James I. when the clergy being affembled in convo- cation, t)ie king gave them leave to treat and confult upan canons ; which they did, and prefented them to the king, who gave them the royal aflent : thefe were a colleftion out of the feveral preceding canons and in- juaclions. Some of thefe canons are now obfolete. In. the reign of Charles L feveral canons were pafled by the clergy in convocation. CANONESS, in the Romifti church, a woman wha enjoys a prebend, affixed, by the foundation, to maids, without their being obliged to renounce the world or make any vows. CANONICA, in philofophical hiftory, an appella- tion given by Epicurus to his dodlrine of logic. It was called canonlca, as _ confifting of a few canons or rules for diredling the underftanding in the purfuit and. knowledge of truth. Epicurus's caiion'ica is reprefent- ed as a very flight and infufficient logic by feveral of the ancients, who put a great value on his ethics and phyfics. Laertius even affures us, that the Epicureans rejefted logic as a fuperfluous fcience ; and Plutarch complains that Epicurus made an unflcilful and pre- pofterous ufe of fyllogifms. But thefe cenfures feem. too fevere. Epicurus was hot averfe to the ftudy o£ Logic, but even gave better rules in this art than thofe philofophers who aimed at no glory but tlrat of logics. He only feems to have rejedled the dialeftics of the ftoics,,as full of vain fubtleties and deceits, and fitted, rather for parade and difputation.than real ufe. The ftrefs of Epicurus's canon'ica confifts in his doftrine of the criteria of truth. AH queftions in philofophy are either concerning words or things: concerning things,. we- CAN r 1 20 canonical, we feek tlicir truth ; concerning words, their fignifi- ^"""Y--^ cation : things are either natural or moral ; and the former are either perceived by fenfe or by the under- ftanding. Hence, according to Epicurus, ariie three criterions of truth, viz. fenfe, anticipation or prceno- lion, and paffion. The great canon or principle of Epicurus's logic is, that the fenfes are never deceived ; and therefore, that every fenfatlon or perception of an appearance is true. CANONICAL, fomething that belongs to, or par- takes of, the nature of a rule or canon. Canonical Hours-, are certain ftated times of the day, configned, more efpecially by the Romilh church, to the offices of prayer and devotion. Such are matins, lauds, Jixth, ninth, vefpers. In our country the canoni- cal hours are from eight to twelve in the forenoon, be- fore or after which marriage cannot be legally perform- ed in any parifli-church. Canonical Obedience, is that fubmiffion which, by the eccleliaftical laws, the inferior clergy are to pay to their bllhops, and religious to their fuperiors. Canonical Sins, in the ancient church, thofe whicli ivere capital or mortal. Such efpecially were idolatry, murder, adultery, herefy, and fchifm. Canonical Puni/hments, are thofe which the church may infliA ; fuch as excommunication, degradation, and penance, in Roman Catholic countries, alfo fall- ing, alms, whipping, &c. Canonical Life, the method or rule of living pre- fcribed by the ancient clergy who lived in community. The canonical life was a kind of medium between the monaftic and clerical lives. Originally the orders of monks and clerks were entirely dillindl ; but pious per- lons, in procefs of time, inilituted colleges of priefts and canons, where clerks brought up for the miniftry, as well" as others already engaged therein, might live under a fixed rule, which, though fomewhat more eafy than the monaftic, was yet more reftrained than the fe- cular. This was called the canonical life, and thofe who embraced it canons. — Authors are divided about the founder of the canonical life. Some will have it to be founded by the apoftles ; others afcribe it to pope Urban I. about the year 1230, who is faid to have ordered bifbops to provide fuch of their clergy as were willing to live in community, with necelFaries out of the revenues £)f their churches. The genei-ality attri- bute it to St Auguttin ; who, having gathered a num- ber of clerks to devote themlelves to religion, inftitu- ted a monalleiy within his epilcopal palace, where he lived in community with them. Onuphrius Panvinius brings the inftitution fomewhat lower ; according to him, pope Gelafms I. about the year 495, placed the firft regular canons of St Auguftin in the Lateran church. Canonical Letters, in the ancient church, were a fort of teftimonials of the orthodox faith, which the bifhops and clergy fent each other to keep up the ca- tholic communion, and dittinguini orthodox Chriftians from Arians and other heretics. They were denomi- nated canonical, either as being compofed according to a certain rule or form, or becaufe they were given to the canoniciy that is, thofe comprehended in the canon or catalogue of their church. When they had occalion to travel into other diocefes or countries, dimiffory and 1 Can recommendatory letters, ailo letters of peace, he. were fo many fpecies of canonical letters. Canonical is alfo an appellation given to thofe epilUes in the New Teftam.cnt more frequently called catholic or general epiftles. CANONIC UM, in a general fenfe, denotes a tax or tribute. Canonicum is more particularly ufed in the Greek church for a fee paid by the clergy to biihops, arch- bifliops, and metropolitans, for degrees and promo* tions. Canonicum alfo denotes a due of firil-fruits, paid by the Greek laity to their bifhops, or, according to Du-Cange, to their priefts. The canonicum is afTelTed according to the number of houfes or chininies in a place. The emperor Ifaac Comnenus made a conftitution for regulating ■ the canonicum of biihops, which was confirmed by another made in 1086, by his nephew Alexis Comnenus. A village containing thirty fires, was to pay for its canonicum one piece of gold, two of filver, one Iheep, fix bufliels of barley, fix of vvlicat flour, fix meafures of wine, and thirty hens. CANONIST, a perfon fltilled in or who makes pro-' feffion of the ftudy and praftice of the canon law. Ca- noniits and civilians are ufually combined in the fame perfons : and hence the title of doEior juris utriufquc, or legum do8or, ufually expreffed in abbreviature, L. L.D. or J. U.D. CANONIZATION, a ceremony in the Romilli church, by which perfons deceafed are ranked in the catalogue of the faints. It fucceeds beatification. " 'Before a beatified perfon is canonized, the qualifica- tions of the candidate are ftriftly examined into, in fome Gonfiftories held for that purpofe ; after which, one of the confiftorial advocates, in the prefence of the pope and cardinals, makes the panegyric of the perfon who is to be proclaimed a faint, and gives a particular detail of his life and miracles : which done, the holy father decrees his canonization, and appoints the day. On the day of canonization the pope officiates in white, and their eminences are dreft in the fame colour. St Peter's church is hung with rich tapeftry, upon which the arms of the pope, and of the prince or ftatc requiring the canonization, are embroidered in gold and filver. An infinite number of lights blaze all round the church, which is crowded with pious fouls, who wait with devout impatience till the new faint has made his public entry as it were into paradife, that they may offer up their petitions to him without danger of be- ing rejefted. The following maxim with regard to canonization is rtow obferved, though it has not been followed above a century, vi-z. not to enter into the inquiries prior to ca- nonization, till 50 years, atleaft, after the death of the perfon to be canonized. By the ceremony of canoni- zation, it appears that this rite of the modern Romans has fomething in it very like the apotheofis or deifica- tion of the ancient Romans, and, in all probability, takes its rife from it ; at leaft feveral ceremonies of the fame nature are confpicuous in both. CANONRY, the benefice filled by a canon. It dif- fers from a prebend, in that the prebend may fubfiil without CAN [ I without the cationicatc : whereas the canonicate is infe- parable from the prebend: again, the rights of fuffra- ges, and other privileges, are annexed to the canoni- cate, and not to the prebend. CANOPUS, in aftronomy, a ftar of the firft mag- nitude in the rudder of Argo, a conftellation of the fouthern hemifphere. Canopus, in Pagan mythology, one of the deities of the ancient Egyptians, and, according to fome, the god of water. It is faid, that the Chaldeans, who worfliipped fire, carried their fancied deity thro' other countries to try its pov.'er, in order that, if it obtained the viftory over the other gods, it might be acknow- ledged as the true object of worfhip; and it having ea- fily fubdued the gods of wood. Hone, brafs, filver, and gold, its priefts declared, that all gods did it homage. This the priefts of Canopus hearing, and finding that the Chaldeans had brought their god to contend with Canopus, they took a large earthen vefTel, in which they bored feveral holes, which they afterwards ftop- ped with wax, and having filled the veffel with water, ■painted it of feveral colours, and fitting the head of an idol to It, brought it out, in order to contend with the Chaldean deity. The Chaldeans accordingly kindled their fire all around it ; but the heat having melted the wax, the water gufhed out thro' the holes, and extin- guiftied the fire ; and thus Canopus cojiquered the god of the Chaldeans. Canopus, or Canobusy according to Strabo, had been Menelaus's pilot, and had a temple eredled to him in a town called Canopus, near one of the mouths of the Nile. Dionyfius mentions it : Kai Ttf/.ii<^ -mpirvrf'y AjuiiY^oti nio Kc/.vuliv. There ftancU Canobus' ftrnple known to fame ; The pilot who from fair Amytla came. Voflius remarks, on this occafion, the vanity of the Greeks, who, as he conjeftures, hearing of an Egyp- tian deity named Canopus, took from thence an oppor- tunity of deifying the pilot of Menelaus who bore the fame name, and giving out that the Egyptian god Ca- nopus had been a Greek. P. Monfaucon gives feveral reprefentations of this deity. One, in allufion to the vi(?tory above mentioned, throws out water on every iide through little holes. Canopus, or Canolus, (anc. geog.) a town of the Lower Egypt, on the Mediterranean, an hnn dred and twenty ftadia, or fifteen miles to the eaft of Alexandria ; as old as the war of Troy, Canopus, or Canobus, Menelaus's fteerfman, being there buried. Canopaei, the gentilitious name : famous for their luxu- ry and debauchery, (Strabo, Juvenal.) See Aboukir. CANOPY, in architefture and fculpture, a mag- nificent kind of decoration, fcrving to cover and crown an altar, throne, tribunal, pulpit, chair, or the like. The word is formed from the barbarous Latin canopeum^ of y.aiu7nioi^ anefjpnail oDe-r a bed to keep off the guais, from %!^y--^:^y,n gnat, ■ Canopies are alfo botne over the head in procefllons of ftate, after the manner of umbrellas. The canopy ■ef an altar is more peculiarly called Ciborhm, The Roman grandees had their canopies, or fpread Teils, called thenfo'., over their chairs : the like were al- io in temples over the ftatues of the gods. The mo- (2ern cardinals ftill retain the ufe of canopies. CANOSA, a town of Puglia in Italy, occupying Vol. IV. Part. I. 2f ] can" part of the fite of the ancient Canufium. The old Canofa city was founded by Diomede, according to Strabo. It i' afterwards became a Roman colony, and one of the , moft confiderable cities of this part of Italy for extent, ' population, and magnificence in building. The sraof Trajan feems to have been that of its greateft fplen- dour ; but this pomp only ferved to mark it as a capi- tal objeA for the avarice and fury of the Barbarians. Genferic, Totila, and Autharis, treated it with ex- treme cruelty. The deplorable ftate to which this province was reduced in 590 is concifely but ftrongly '^>'ai,sls in painted by Gregory the Great, in thefe terms : " On o " every fide we hear groans ! on every fide we behold ^^^^ "^^ ' *' crowds of mourners, cities burnt, caftles rafed to the " ground, countries laid wafte, provinces .become de- " ferts, fome citizens led away captives, and others in- " humanly maiTacred." No town in Puglia fuffered more than Canofa from the outrages of the Saracens; the contcfts between the Greeks and Normans increa fed the meafure of its woes, which was filled by a con- ' flagratlon that happened when it was ftormed by duke Robert. In 1090, it was affigncd, by agreement, to Bohemund prince of Antioch, who died here in 1 1 1 1. Under the reign of Ferdinand the Third, this eftate belonged to the Grimaldis. On their forfeiture, the Affaititi acquired It, and ftill retain the title of mar- qui's, though the Capeci are the proprietors of the fief. The ancient city ftood in a plain between the hills and the river Ofanto, and covered a large trad of ground. Many brick monuments, though degraded and ftripped of their marble cafing, ftill atteft its ancient grandeur. Among them may be traced the fragments of aqueduds, tombs, amphitheatre baths, military co- lumns, and two triumphal arches, which, by their po- fitlon, feem to have been two city gates. The prefent town ftands above, on the foundations of the old cita- del, and is a moft pitiful remnant of fo great a city, not containing above three hundred houfes. The church of St Sabinus, built, as is faid, In the fixth cen- tury, is now without the inclofure. It is aftoniftiing, that any part of this ancient cathedral fhould have wichftood fo many calamities. Its altars and pave- ments are rich in marbles ; and in a fmall court ad- joining, under an oAagonal cupola. Is the maufoleum of Bohemund, adorned in a minute Gothic ftyle. C ANSO, a fea-port town of Acadia, or Nova Sco- tia, In North America, feated on a narrow ftrait which feparates Nova Scotia from Cape Breton. Near this town is a fine fiftiery for cod. W. Long. 62. N. Lat. 46. CANSTAT, a town of Swabia, in Germany, in the duchy of Wirtemberg, fituated on the river Neckar, in E. Long. 9. 9. N. Lat. 48. 51. CANT, a quaint affeded manner of fpeaking, ad- apted chiefly to the lower fort. Skinner racks his in- vention for the origin of this word ; which he fuccef- fively deduces from the German, Elemifh, and Saxon tongues. According to the general opinion, Cantij originally the proper name of a Cameronlan preacher in Scotland, who by exercife had obtained the faculty of talking in the pulpit in fuch a tone and dialed as was underftood by none but his, own congregation: fincc Andrew Cant's time, the word has been extended to fignify all fudden exclamations, and whining unmufica! tones, efpecially in praying and j)reaching. But thi» origin ing L guage. CAN [ T2 Canr, origin of the word has been dlfputed by others ; and Cantabria. perhaps the true derivation is from the Latin cantare ^"—^^r—^ to fmg." Cant is alfo applied to words and phrafcs affefted by particular perfons or profeflions for low ends, and • SeeCa«/.not authorifed by the eftablifhed language *. The difference between cant d^ni technical feems to be this : the former is reftrained to words introduced out of fol- ly, affeftation, or impofture ; the latter is applied to fuch as are introduced for the fake of clearnefs, preci- fion, and fignificancy. Cant is alfo ufed to denote a fale by auction. The origin of the word in this fenfe is dubious ; it may come, according to feme, from quantum, how much ; according to others, from cantare., to fing or cry aloud; agreeably to which, we fometimcs alfo call it an out- cry. CANT-Timhers, in fhip-building, thofe timbers which are fituated at the two ends of a fhip. They derive their name from being canted, or raifed obliquely from the keel ; in contracliiHnftion from thofe whofe planes are perpendicular to it. The upper ends of thofe on the bow, or fore-part of the fhip, are inclined to the ftern; as thofe in the after, or hind part, incline to the ftern-poft above. See SHip-Buildlng. CANTABRIA, (anc. geog.), a diftrift of Terra - conenfis, on the Oceanus Cantabricus or bay of Bif- cay ; now Biscay. The inhabitants were famous for their warlike charaAer. In conjunftion with the A- t See AJlu- fturians f, they carried on defperate wars with the Ro- tria. mans ; but were fubdued by them about 25 years be- fore Chrift. Being impatient, however, of a foreign yoke, they in a few years revolted. Moft of their youth had been already taken prifoners by the Romans, and fold for flaves to the neighbouring nations : but having found means to break their chains, they cut the throats of their matters : and returning into their own country, attacked the Roman garrifons with in- credible fury. Agrippa marched againft them with great expedition ; but, on his arrival, met with fo vi- gorous a refiftance, that his foldieis began to defpair ©f ever being able to reduce them. As the Cantabrians had waged war with the Romans for upwards of 200 years, they were well acquainted with their manner of fighting, no way inferior to them in courage, and were now become defperate ; well knowing, that if they were conquered, after having fo often attempted to re- cover their liberty, they murt expeft^ the moft fevere tjfage, and cruel flavery. Animated with this refleftion, they fell upon the Romans with a fury hardly to be exprefled, routed them in feveral engagements, and de- fended themfelves when attacked by the enemy with fuch intrepidity, that Agrippa afterwards owned, that he had never, either by fea or land, been engaged in a more dangerous entcrprize. That brave commander was obliged to ufe intreaties, menaces, and to brand fome of his legionaries with ignominy, before he could bring them to enter the lilts with fuch a formidable enemy. But having at laft, with much ado, prevailed vipon them to try the chance of an engagement in the open field, he fo animated them by his example, that, after a moft obftinate difpute, he gained a complete viftory, which indeed coft him dear, but put an end to that deftrudlive war. All the Cantabrians fit to. bear arras were cut in pieces ; their caftles and ftrong holds 2 ] CAN taken and rafed 5 and their women, children, and old Cantabria men (none elfe being left ahve), were obliged to aban. q^J^^^^ don the moimtainous places, and fettle in the plain. ^^„.,. Dr WaUis feems to make the Cantabrian the ancient language of all Spain: which, according to him, like the Gaulifh, gave way to a kind of broken Latin called romance, oxromanjhe; which by degrees was refined into the Caftilian or prefent Spanifli. But we can hardly fuppofe, that fo large a country, inhabited by fuch a variety of people, fpoke all the fame language. The ancient Cantabrian, in clfeft, is ftill found to fubfift in the more barren and mountainous parts of the province of Bifcay, Afturias, and Navarre, as far as Bayonne, much as the Britifti does in Wales ; but the people only talk it : for writing, thty ufe either the Spani(h- or French, as they happen to live under the one 01 the other nation. Some att.ribnte this to a jealoufy of fo- reigners learning the myfteries of their language ; o- thers to a poverty of words and exprefiions. The Cantabrian docs not appear to have any affinity with any other known language, abating that fome Spanifii words have been adopted in it for things whofe ufe the Bifcayens were anciently unacquainted with. Its pro- nunciation is not difagreeable. The Lord's prayer, in the Cantabarian tongue, runs thus : Gure aita cervc- tan a'lcena, fantijica hedi hire Icena, ethor bedl hire refuma, e^uin hedi hire vorondatea cervan becala lurrean ere, dec. CANTABRICA, in botany : A fynonime of a fpecies of Con volvulus. CANTABRUM, in antiquity, a large kind of flag ufed by the Roman emperors, dHlinguidied by its pe- culiar colour, and bearing on it fome words or motto of good omen, to encourage the foldlevs. CANTACUZENUS (Johannes), of Conftantl- nople, a celebrated ilatefman, general, and hiftorian, was born in that city, of a very ancient and noble fami- ly. He was bred to letters and to arms, and admitted to the higheft offices of the ftate. The emperor An- dronicus loaded him with wealth and honour ; made him generaliffimo of his forces; and was defirous of having him join him in the government, but this he refufed. Audronicus dying in 1341, left to Cantacu- zcnus the care of the empire, till his fon John Paleo- logus, who was then but nine vears of age, ihould- be fit to take it upon himfelf. This truft he faithfully difcharged ; till the emprefs dowager and her fadion forming a party againft- him, declared him a traitor.. On this the principal nobihty and the aimy belought him to afcend the throne ; and accordingly he waa crowned on the 21ft of May 1342. This was follow- ed by a civil war, which lafted five years ; when he ad- mitted John a partner with him in the empire, and their union was confirmed by his giving hini his. daughter in marriage. Sufpicions and enmities, however, foon arifing, the war broke out again, and continued till John took Conftantinople in 1355. _ A few days after, Cantacuzenus, unwiUing to continue the effufion of blood, abdicated his ftare of the em- pire, and retiring to a monaftery, took the habit of a monk, and the name of Joajaphas. His wife alfo re- tired to a nunnery, and changed her name of Irene for that of Eugenia. In this retirement he lived till the year 1411, when he was upwards of 100 years of age^ Here he wrote a hiftory of his own times, a Lafin tranflation of which, from the Greek manufcript, was pub- CAN t 123 ] C A N antalivfers pnblifhed by Pontanus at Ingolftadt, in 1603: and a I' . fpltndid edition was printed at Paris in 164^, in three ^ ''^ " volumes folio, of the original Greek, and Pontanus's Latin verfion. He alfo wrote an apology for the Chri- ftlan religion againft that of Mahomet, under the name of Chr'ijlodultis . CANTALIVERS, in architefture, pieces of wood framed into the front or fides of a houfe, to fufpend the mouldings and eyes over it. CANTAR, or Cantaro, an eaftern weight, of different value in different places, equal at Acra in Turky to 603 pounds, at Tunis and Tripoli to 114 pounds. Cantar is alfo an Egyptian weight, which is de- nominated a quintal., and confifts of an hundred or of an hundred and fifty rotolos, according to the goods they ' are to weigh. Cantaro is alfo an Egyptian weight, which at Naples is equivalent to 25 pounds, at Genoa to 150 pounds. At l^eghorn there are three kinds of contaros, one weighing 150 pounds, another 151, and a third 160 pounds. Cantaro is alfo a Spanifh liquid meafure, in ufe efpccially at Alicant, containing three gallons. Cantaro is alfo a meafure of capacity, ufed at Co- chin, containing four rubies, the rubi 32 rotolos. CANTARINI (Simon), a famous painter, called the Fefarefe, from his being born at Pefaro, was the difciple of Guido ; and copied the manner of his ma- fler fo happily, that it is often difficult to diftinguifh between their works. He died at Verona in 1648. CANTATA, in muiic, a fong or compofition, in- termixed with recitatives, airs, and different move- ments, chiefly intended for a fingle voice, with a tho- rough bafs, though fometimes for other inftruments. The cantata, when performed with judgement, has fomething in it very agreeable ; the vaiiety of the movement- not clogging the ear, like other compoli- tions. It was firfl ufed in Italy, then in France, whence it paffcd to us. CANTAZARO, an epifcopal city of Italy, in the kingdom of Naples, and in the territory of Calabria Ulterior. It is the refidence of the governor of the province, and isfeated near the fea, in E.L jng. 17. o. N. Lat. 38. 59. CANTECROIX, a fmall territory of the Nether- lands, in Brabant, and in the quarter of Antwerp, with the title of a principality ; there is a fmall town of the fame name, but Lire is the capital. CANTEMIR (Demetrius), fon of a prince of Mol- davia. Difappointed by not fucceeding his father in that dignity, held under the Ottoman Port, he went over with his araiy to the Czar Peter the great, againft whom he had been fent by the Grand Signior : he flg- nali/ed himfelf in the Czar's fervice ; and in the i-epu- bh'c of letters, by a Latin hiftory of the origin and de- cline of the Ottoman empire, &c. Died in 1723. Can TE MIR (Antiochus), efleemed the founder of the Ruflian poetry, was the youngeft fon of the pre- ceding. Under the moll ingenious profeffors, whom the czar had invited to Peterlburgh, he learned ma- thematics, phyfic, hiftory, moral philofophy, and po- lite llterciture ; without neglefting the fiudy of the Holy Scriptures, to which he had a great inclination. Scarce had he fiiiifhed his academic courfe, when he printed a Concordance to the Pfalms in the Ruflian Cantemir, language, and was elefted member of the academy. Canter- The affairs of ftate in which he was foon after enga- j ged, did not make him negleft his literary purfuitf. In order to make himfelf ufeful to his fellow-citizens, he compofed his fatires, to ridicule certain prejudices which had got footing among them. When but 23 years of age, he was nominated miaifter at the court of Great Britain ; and his dexterity in the management of public affairs was as much admired as his tatte for the fciences. He had the fame reputation in France, whither he went in 1738, in quality of minifter ple- nipotentiary, and foon after was invefted with the charafter of ambaffador extraordinary. The wife and prudent manner in which he conduced himfelf during the different revolutions which happened in Ruffia du- ring his abfence, gained him the confidence and efteeni of three fuccefiive princes. He died of a dropfy, at Paris, in 1744, aged 44. Befides the pieces already mentioned, he wrote, i. Some fables and odes. 2. A tranflation of Horace's epiftles into Ruffian verfe. 3. A profe tranflation of Fontenelle's plurality of worlds ; and, 4. Algarotti's dialogues on fight. The abbe Guafco has written his life in French, and tranflated his fatires into that language. CANTERBURY, a city of England, and capital of the county of Kent, fituated in E. Long. i. i^. N. Lat. 51.16. It had the names of Durovernum and Darvernum given it by the Romans, and Durober- n'la by Bede, which are thought to be derived from Durivhem, fignifying a rapid ftream, fuch as the Stour, on which it flands, is. The Britons call it Gaer-Kent^ i. e. the city of Kent ; and its prefent Englifh nanie is of the fame import, derived from the Saxon. Modern writers in Latin call it Catituaria. Its great antiquity appears not only from Antoninus's itinerary, but from the military way which has been difcovered here, and the caufew^ays leading to Dover and Lymme, befides the coins and other curiolitles found about it. The archlepifcopal and metropolitical dignity feems to have been fettled here very early ; and to prevent lis being removed, an anathema was decreed againft afty who fhould attempt it. After that, the city flourlfiied great- ly ; though it fuffered in common with other towns during the Danilh invafions, and at other times by the cafiialties of fire. The city was given entirely to the bifhops by William Rufus, and was held in the utmoft veneration in the Popifh times, efpecially after the murder of Becket in the reign of Henry II. to whofe flirine fo great was the refort, and fo rich were the offerings, that Erafmus, who was an eye-wltnefs of its wealth, fays the whole church and chapel in which lie was interred glittered with jewels ; and at the diffolu- tion, the plate and jewels filled two great chefts, each of which required eight ftrong men to carry out. Tlie cathedral was granted by Etlieibert, king of Kent, up- on his converfion, to Auftin the monk, together with his palace, and the royalty of the city and its territo- ries. This Auftin founded a monaflery for monks, called from him Aiigvjline. After the cathedral had been feveral times deftroyed by fire and rebuilt, the prefent was begun about the year 1 1 74, and augment- ed and embellifhed by the fucceeding archbifhops, till it was completed in the reign of Henry V. It is a noble Gothic pile, and before the refonnation had 37 0^2 altars CAN [ 124 ] CAN Canter- altars. A great many kings, princes, cardinals, and ^" ""y' arclibilliops, are buried in it. At the diffolution, Henry " VIII. feized all the revenues both of the church and monaftery, except what he allotted for the maintenance of a dean, 1 2- prebendaries, and fix preachers, whom he eftablifhed in place of the monks. During the grand rebellion, it fuffered much ; the ufurper Crom- well having made a ftable of it for his dragoons. Af- ter the reftoration, it was repaired, and made what it now appears. Befides the cathedral and other churches, as well as a monaftery, the city had anciently a caftle on the fouth-fide, and ftrong walls, with tov/ers, a ditch, and rampart ; it had alfo a mint and an exchange. As to its government, it fcems to have been entirely fubjeft to the archbiihop, both in fplrftuals and temporals ; at leaft from the time tliat William Rufus-gave it folely to bifhop Anfelm, till the reformation. It is now a county of itftlf ; and the corporation confifts of a may- or, recorder, 12 aldermen, a fherifF, 24 common-coun- cil-men, a mace-bearer, fvvord-bearer, and four ferjeants at mace. Every Monday a court is held at Guildhall for civil and criminal caufes ; and every other Tucfday for the government of the city. Here were formerly 2000 or 3000 French Proteftants employed in the lilk manufacture ; but this branch is now greatly decayed in the place, fince Spitallields became fo flourifhing. Befides the cathedral, it contains 15 parilh-churches, feven hofpitals, a free-fchool, a houfe of corre£tion, a gaol for criminals, and a fumptuous conduit for fupply- ing the inhabitants with water. It coniirts of four ttreets, difpofed in the form of a crofs, and divided in- to fix w^ards, which are about three miles in circumfe- rence. It is furrounded on all hands with hop-grounds much to its advantage, and is famed for its excellent brawn. The diocefe of Canterbury contains 257 parifhes, befides chapels, in Kent, and about 100 more in other diocefes. Thefe are called Peculiars ; it being an an- cient privilege of this fee, that, wherefoever the arch- bifhops had either manors or advowfons, the place was exempted from the jurifdiftion of the ordinary of the diocefe where it was fituated, and was deemed in the diocefe of Canterbury* This fee is valued in the king's books at L. 2816 : 17 : g^, but is reckoned to produce a clear revenue of L. 8000 a-year. The clergy's tenths come to L. 65 1 : 1 8 : 2^. This fee had many great privileges in the time of Popery, fome of which it ftill retains. The archbilliop is accounted primate and me- tropolitan of all England, and is the firil peer in the realm ; having the precedence of all dukes not of the blood-royal, and all the great officers of Hate. In common fpeech, he is ftyled His Grace, and he writes himfelf Divina Providentia ; whereas other bilhops ftyle themfelves Divina PermiJJione. At coronations, he places the crown on the king's head ; and, where- ever the court may be, the king and queen are the proper domeftic parifhioners of the archbiihop of Can- terbury, The bilhop of London is accounted his pro- vincial deaji, the bifhop of Winchefter liis fub-dean, the bifliop of Lincoln his chancellor, and the bifliop of Rochefter his chaplain. This fee hath yielded to the cliurch I ^ faints ; to. the church of Rome, 9 cardinals ; to, the civil ftate of England 12 lord chancellors, 4 lord treafurers, aad i lord chief juftice j and 9 chan- Cantides. cellors to the Univerfity of Oxford. To this fee be- Canterns longs only one archdeacon, viz. of Canterbury. To the cathedral belongs an archbifhop, a dean, a chan- cellor, an archdeacon, 12 prebends, 6 preachers, 6 minor canons, 6 fubftitutes, 12 lay clerks, 10 chorifters, 2 mailers, 50 fcholars, and 12 almfmen. CANTERRURr-Belly In botany : The Englifh name of a fpecles of Campanula. CANTERUS (WiUiam), an eminent lingulft and philologer, was born at Utrecht, in 1542. He ftudied at Louvain and Paris ; and gave furpriling proofs of his progrefs in Greek and Latin literature. He after- wards vifited the feveral univerfities of Germany and Italy; and died at Louvain, in 1575, aged 33. He underftood fix languages, befides that of his native country ; and, notwithllanding his dying fo young, wrote feveral philological and critical works, among which are, Nota, Scholia, Emendationes , et Explicationes , in Enripidem, Sophoclem, JEfchylum, Ciccronem, Proper- tiiim, Aujonimi, Sec. and many tranflations of Greek authors. CANTHARIDES. See Cantharis and Meloe. CANTHARIS, in zoology, a genus of infefts be- longing to the order of infefta coleoptera. The feel- ers of this genus are fetaceous ; the breaft is margina- ted, and fhorter than the head ; the elytra, or wing- cafes, are flexile ; and the fides of the belly are plated and papillous. Linnaeus enumerates 27 fpecies of the cantharis, moll of them to be found in different parts, of Europe. The cantharis ufed in making blifiering plafters, is ranked under a different genus, viz. the Meloe. CANTHI, in anatomy, cavities at the extremities of the eye-lids, commonly called the corners of the ey^: the greater of them, or the greater canthus, is next the nofe ; the leffer of them, or the little canthus, lies to- wards the temple. CANTICLES, a canonical book of the Old Tefta- ment, otherwife called the Song of Solomon ; by the Jews the Song of Songs, Canticum Canticorum. The book of Canticles is ufually fuppofed to be an epitha- lamium compofed by Solomon, on occafion of his mar- riage with the king of Egypt's daughter. But thofe who penetrate further into the myilery, find in it the marriage of Jefus Chrift with human nature, the church, and good men. On this principle the Canticles is held to be a continued allegory, wherein, under the terms of a common wedding, a divine and fpiritual marriage is expreffed. This fong contains the adventures of feven days and feven nights ; the exail time allowed for the celebration of marriage among the Hebrews. The Jews themfelves, apprehending the book liable to be underflood in a grofs and carnal manner, prohibited the reading of it before the age of 30, and the fame ufage anciently obtained in the ChriiHan church. A- mong the ancients, Theodore Mopfuetanus rejefted the book of Canticles a« not divine. Divers rabbins have alfo queftioned its being written, by infpiration. It is alleged, that the name of God is not once found, in it. Mr Whitton has a difcourfe exprefs to prove that the Canticles is not a facred book of the Old Teftament. He alleges it indeed to have been wnt- ten by king Solomon the fon of David ; but afferts that it was compofed at the time when that prince, bUndcd by his concubines, was iuuk in lull and idola- try.. Cantima- Cantlum. CAN r I try. This he chiefly infers from the general character off vanity and diflblutenefs which reigns thro' the Can- ti'cles ; in which there is not, according to Whirton, one thought that leads the mind towards religion, but all is worldly and carnal, to fay no worfe. For the miyftic fenfe, he afferts it to be without foundation ; and that the book is not cited as canonical by any writer before the deftruAion of Jerufalem. Mr Whif- ton will have it to have been taken into the canon be- tween the years 77 and 128, when allegories came in- to vogue, and the rabbins began to corrupt the text of Scripture. Grotius, Nierembergius, the Dutch di- vines who criticifed F. Simon, Menetrier, Bafnage, and foime others, feem alfo to take the Canticles for a pro- fa.ne compofition, on a footing with the love-pieces of Catullus or Ovid. But this opinion is refuted by Mi- chaeKs, Majus, Witfms, Nat. Alexander, Outrein, Francius, and others. Mr Whifton's arguments have been particularly confidered by Itchener, and alfo by l>r Gill. R. Akiba finds the book of Canticles more divine than the reft : the whole world, according to this rabbin, is not worth that day when the Canticles was given to Ifrael ; for, whereas all the hagiographers are holy, the Canticles is the holy of holies. CANTIMARONS, or Catimarons, a kind of floats or rafts, ufed by the inhabitants of the coaft of Coromandel to go a fifhing in, and to trade along the coaft. They are made of three or four fmall canoes, or trunks of trees dug hollow, and tied together with cacao ropes, with a triangular fail in the middle, made of matts. ' The perfons who manage them are almoft half in the water, there being only a place in the mid- dle a little raifed to hold their merchandize ; which HA particular is only to be underftood of the trading cantimarons, and not of thofe who go fiftiing. CANTIN (Cape), a promontory of the coaft of Morocco in Africa, fituated in W. Long. 10. 2. N. Lat. 33. 9. CANTING, a fea-phrafe, denotes the a£l of turn- ing any thing about. Canting Language or d'lakSi, is a myfterious fort of jargon ufed by gypfies, thieves, and ftrolling beg- gers, to exprefs their fentiments to each other, without being underftood by the reft of mankind. This dia- Ie*fl is not founded on any rules : yet, even out of that irregularity many words feem to retain fomething of fcholarftiip ; as togeman a gown, from toga in the La- tin ; pannam, bread, from pan'is ; cafariy cheefe, from ea/eus, 8cc. It is obfervable, that, even unknown to ourfelves, we have adopted fome of their terms into our vulgar language ; as lite and ll/i, to cheat ; bounce, to vapour ^o'Zty^, ftrong drink; Jilchy to fteal ; ^og, to whip ; rig, game or ridicule ; roajl, to rally ; rlnno, Hioney. From the fame fource proceed the words JJ^am, banter, bubble, bully, JJjarper, cutting, Jljujling, palming,_ 8cc. An anonymous author has given a canting diftionarv, comprehending all the terms ufed by the feveral tribes ©f gypfies, beggars, ftioplifters, high-*-aymen, foot- pads, and other clans of cheats and villains, with a colleftion of fongs in tlie cantHig dialed ; London, 1725, 8vo. CANTIUM, (anc. geog. ). a promontory of Bri- tain, literally denoting a bead land ; giving name to a terrritory called Cantium, now Kent ; and to a peo- ple called Cantii, (C«far) j eoimnended for their great 25 ] CAN humanity and polltenefs. The promontory now the Cantium, North Fore/and. It is fuppofed that this was the firft , ^ diftrift in Britain which received a colony from the * continent ; and that it had frequently changed its ma- fters, by new colonies coming over from time to time, and driving the inhabitants further north. In the midft of all thefe revolutions it ftill retained its ancient name (which was fo agreeable to its ftiape and fituation), and gave the fame name to all the fucceffive tribes by which it was inhabited. Thofe who poflefled it at the time of the firft Roman invafion were evidently of Belgic origin, and had come over fo lately, that they difftred in nothing from their countrymen on the con- tinent. " The inhabitants of Kent (fays Caefar) are the moft civilized of all the Britons, and differ but very little in their manners from the Gauls." This great refemblance between the people of Kent and their neighbours on the continent^ might be partly- owing to the fituation of their country, which be- ing neareft to the continent, was molt frequented by ftrangers from thence. It was this fituation al« fo which expofed them to the firft affaults of the Ro- mans. For Caefar, in both his expeditions into this ifland, landed in Kent ; and therefore we may con- clude, that the Cantii had a great ftiare in the vigo- rous oppofition that was made to his landing, and in the feveral battles and fiiirmifties- which were fought againft him after his landing ; particularly, they made a very bold, but unfuccefsful attempt, upon his naval camp. The Cantii did not make tlie fame vigorous refilfance to the Romans on tlieir next invafion in the reign of Claudius. For Aulus Plautius, the Roman ge- neral in that expedition, traverfed their country without, feeing an enemy ; and as they now fubmitted to the power of Rome without a ftruggle, fo they continued in a ftate of quiet fubmiffion to it to the very laft. The- fituation of Cantium occafioned its being much fre- quented by the Romans,, who generally took their way- through it in their marches to and from tlie continent. Few places in Britain are more frequently mentioned by the Roman writers than Rutupium and Portus Rutupenfis,, moft probably Richborough and Stonar. Rutupium was the fame in thofe times that Dover is in ours ; the ufual place of embarking for, and land- ing from, the continent. Before the final departure of the Romans out of Britain, Portus Dubris, now Do- ver, had become a confiderable place, and a well-fre- - quented harbour, where the third iter of Antoninus ends, and from whence they often embarked for Gaul.- Portus Lemanus, fuppofed to be Lime near Weft: Hythe, was alfo a not(!d fea-port in thefe times, and. the termination of the fourth iter of Antoninus. Du-- robrivae and Durovernum, now Rochefter and Canter- - bury, were both Roman towns and ftations, and are often mentioned in the itinerary and other books.. Befides thefe, there were feveral other Roman ftations,, towns,, and ports in Cantium,, which need' not be par- ticularly enumerated^here. Cantium, in the moft per- fedl ftate of the Roman government, made a part of " the province which was called Ffavia Casfarienfis. CANTO denotes apart or divifion of a poem, an-- fwering to what is otherwife called a booL The word is Itahan, where it properly fignifies fong. Taffo, Ari-- ofto, and feveral other ItaRans,,have divided their longer or heroic poems into cantos. In imitation of them-,„ Scxuxoib CAN 12 Canton. Scarron has alfo divided his Gigantomachta, and Boi- '-—\r^ kau his Lutrin, into chants or fongs. The like ufage has been adopted by fome Englifh writers, as Butler, who divides his Hudibras, and Dr Garth his Difpen- fary, into cantos. A late tranflator of part of Virgil's ^neid has even fubdivided a book of Virgil into feve- ral cantos. Canto, in the Italian mufic, fignifies z fmg: hence canlo fimpllce is where all the notes or figures are equal, and called alfo canto Jcrmo canlo figiiratoy that where the figures are unequal, and expreis difierent motions. Canto alfo fignifies the treble part of a fong : hence catito conccrtante, tlie treble of the little chorus ; canto ripleno, the treble of the grand chorus, or that which hugs only now and then in particular places. Canto fignifies the firft treble, unlefs fome other word be ad- ded to it, as fecondo ; in which cafe it denotes the fe- cond treble. CANTON, in geography, denotes a fmall diftrift or country conftituting a dlllind government : fuch are the cantons of Switzerland. Canton, ^ang-tong, or Koanton, one of the fouth- ern provinces of China; bounded on the north-eatl by I'okicn, on the north by Kiang-fi, oh the weft by •Quang-fi and the kingdom of Tonking, and every where tlfe by the fea. The country is diverfified with hills and plains, and the foil in general fo fertile that it produces two crops annually. Befides many of the fruits of Europe, and thofe common in other parts of the Indies, the province of Canton produces fonie peculiar to itfelf. Abundance of valuable aromatic woods are alfo to be met with in this province, as well as eagle-wood, ebony, &c. ; and in tlie mineral king- dom the province furniftes gold, precious ftones, tin, quickfilver, and copper. Silk and fugar are alfo cul- tivated here, and pearls are fiflied up on the coafts ; fo that every thing which can contribute to the pleafure or convenience of hfe is to be met with in Canton. *' One begins (fays F. Premare) to have an idea of China, on entering the river Canton. Both fides of it prefent large fields of rice which refemble green meadows, and extend beyond the reach of fight. They are inter- fered by an infinite number of fiiiall canals, in fuch a manner that the barks which pafs and repafs in them feem at a dlllance, while the water which carries them is concealed, to glide along the giafs. Farther inland the country appears covered with trees and cultivated along die valleys ; and the wliole fcene is interfperfed \\\t\\ villages, rural feats, and fuch a variety of de- lightful pro(pe£ls, that one is never tired of viewing them, and regrets to be obliged to pafs them, fo quickly. All tlie coafts of this province abound with fifli, and furnilh vail numbers of crabs, oyftcrs, and tortoifes of an immenfe fi/e. - The inhabitants keep a prodigious number of tame ducks, which they hatch in ovens or dunghills, though it does net appear that they bor- rowed tiiis cxiftcm from the Eg\-ptians. The docility of thefe creatures exceeds what we ftiould be apt at firft to imagine. The inhabitants load a junnbcr of , fnall barks with them, and carry them in llocks to feed on the fea-ihore, where they find ftirimps and ■ other animals proper for tlieir nourilhment. But though the ducks from the dliTerent barks are thus unavoidably mixed together in the diy-tiine, they are c. Illy colicclcd by only bealiiig on a bafon,, on vrhkh 6 ] CAN they .immediately colleft themfelves Into different flocks. Canto, and each returns to its proper bark. Canton. In this province the Chinefe have alfo a method of ' ' " * preferving not only the flefli of their ducks in fuch a manner that it lofes nothing of its original flavour, but their eggs alfo. The latter operation is performed by covering the eggs with a coat of clay mixed with fait. When mixed in this' manner, it feems that the fait has the property of penetrating through the pores of the fliell, and thus impregnating the fubftance in the egg, which it could not do by fimple folution of water. Canton, though it fiiffered much in the Chinefe wars, is at prefent one of the moft flourifning provinces of the empire; and being at a great diftance from court, its government is one of the moft important. A great number of fortreffes, many of which are cities provided with numerous garrifons, have been built along the coafts for the fuppreffion of pirates and robbers ; for which purpofe alfo a certain number of troops are kept properly pofted' in diff'erent parts of the province. It is divided into ten diftrids, which contain as many cities of the firft clafs, and 84 of the fecond and third. The air in general is warm but healthy, and the people are very induftrious. They poffefs in an eminent degree the talent of imitation, fo that if they are only ftiown any European work they can execute others Uke it with furprifing exaftnefs. The moft remarkable cities in the province befides Canton the capital are, I. Chao-tcheou-fou, chiefly noted for a monaftery of the bonzes in its neighbourhood, to which the adjacent country belongs, and the origin of which is traced back for 8 or 900 years. It has under its jurifdiftion fix cities of the third clafs ; near one of thefe grows a reed of which feveral inftruments are made, which cannot be diftinguiihed from real ebony. The air of Chao-tcheou-fou, however, is unhealthy ; and great numbers of the inhabitants are carried off annually by contagious dittempers, which prevail from the middle of OAober to the beginning of December. 2. Kao-tcheou-fou, fituated in a delighful and plentiful country. In- the neighbourhood is found a fingular kind of ftone much refeml)li!ig marble, on which are natural reprefentations of rivers, mountains, landfcapea, and trees. Thefe ftjnes arc cut into flabs, and mado into tables, &c. Crabs are alfo caught on the coafts here, which very much refemble thole of Europe; but, fays M. Grofier, they have this fingularity, that wdien taken out of the wattr, they becom.e petrified without lofing any thing of their natural figure. _ 3. Kiun- tcheou-fou, the capilal or th.e il'Iand of Hai-nan. See Hai-nan. , Canton, a large, populous, and wealthy city of China, capital of the province of that nia^e, ftaiitis on the banks of the river Taa, of great river, which, near the city, is wide and fpacious. The wall of the cicy is pretty iiigh, and about fix or feven miles in circum- ference, though not more than one-third of the ground is occupied by buildings, the other parts being appro- priated to pleafure grounds or to fifti ponds. The country is extremely pieafaut, and towards the call hilly, fo as to command a beauiiful piofpe£l of the city and fuburbs, the compafs of which, together, is about ten miles. Tiie buildings of Cmton are in general low, confifting of one ftory and a ground flour, which is covered with earth or red tiki i;i order to keep it cool j but the houfes 6 o£ CAN [ Cantom. of the moft refpe£lable merchants and mancjarins are -"-^ comparatively lofty and well built. In different parts of the city and fuburbs are jofs houfes or temples, in ■which are placed the images worfhipped by the Chi- wefe ; before whom are placed, at particular feafons, a vaft variety of fweetmeats, oranges, great plenty of food ready dreffed, and alfo incenfe, which is kept per- petually burning. The ftreets of Canton are long and narrow, paved with flint ftones, adorned at intervals with triumphal arches, which have a pleafmg efFeft, and much crowded with people. On both fides are (hops as in London, appropriated to the fale of different commodities; and a kind of awning is extended from houfe tohoufe, which prevents the fun's rays from incommoding either inha- bitants or palTengers. At the end of every ftreet is a barrier, which, with the gates of the city, are fhut in the evening. In China Street, which is pretty long and confiderably wider than the reft, refice merchants; whofe trade, fo far as refpeits China, lackered ware, fans. Sec. is wholly confined to Europeans. Moft of them fpeak the foreign languages tolerably well, or at leaft fufncieutly intelligible to tranfaft bufinefs. Be- fides thefe merchants, there is a company of twelve or thirteen, called the Cohong ; who have an exchifive right by appointment from authority to purchafe the cargoes from the different fhips, and alio to fupply them with teas, raw filks, &c. in return. The eda- bliftiment of the Cohong, though injurious to private trade, is admirably well adapted for the fecurity of the different companies with which they traffic ; becaufe each individual becomes a guarantee for the whole; fo that if one fail, the others conlider themfelves as rc- fponlible. .« In Canton there are no carriages ; all burdens are carried by porters acrofs their flioulders on bamboos; as are alfo the principal people in fedan chairs, and the ladies always. The ftreets of Canton may be traverfed from morning till evening without feeing a woman, thofe excepted who are Tartars, and even thefe but ve- ry feldom. On the wharf of the river, which is commodious and pleafant, itand the faftories of the. different European nation.^, viz. the Dutch, French, Swedes, Danes, Eng- lifli, &c. In thofe. refide the fupercargoes belonging to their refpeftive companies, who are appointed to difpofe of the cargoes brought to market ; to fupply the fhips with others for Europe in return ; and, du- ring their abfence, to contraft with the merchants for fuch articles as may be judged neceffary for the next fleet. Between the refidents of the faftories the moft perfect cordiality fubfifts ; in each a common and fplendid table is kept at the company's expence, and vifits are reciprocally exchanged ; fo that nothing is wanting to make refidence at Canton agreeable to an European, but the pkafure naturally refulting from the fociety of women. The fide of the river next the city is covered with beats, which form a kind of town or ftreets, in which live the poorer fort of the Chinefe, or rather the de- fendants cf the Tartars. Some of the men come on ftiore in the morning to their refpeftive employments, and in thofe fampans or boats which are not ftation- ary, the women and alfo the men carry paffengers from place to place ui the fame manner as is done bv 27 J CAN wherries on the Thames. On this river live many thoufand fouls who never were permitted to come on fhore ; whofe only habitation is their boat ; in which they eat, drink, fleep, carry on many occupations, keep ducks, &c. and occafionally a hog. The manufactures of Canton ai'e principally carried on in the fuburbs ; though it has been frequently fup- pofed that they were confined to the city ; and this, by fome writers, has been given as a reafon why Euro- peans are not permitted to enter within the gates. But this is a miftake; and perhaps the true reafon for this very Angular reftraint is, that the houfes in which they keep their women are chiefly within the city. At Wampoa, a large commodious place for anchor- age, and which is about 12 or 14 miles from Canton, the European veffels lie and unload their cargoes, which are tranfmitted by lighters to the fadlories ; and by the fame conveyance receive their refpeftive freights. Between this place and the city are three floppo, or cuftom-houfes, at which the boats pafling and repafiing are obliged to ftop, and undergo with its paffengers an examination, in order to prevent fmiig- ling. The lighters juft mentioned, and alfo the cap- tain's pinnace, are, however, excepted; tlie former having proper officers on board for the purpofe, and the latter being narrowly watched and examined- at the landing. The weather at Canton' Is, in fummer, extremely hot ; and in the months of December, January, and February, cold : the country is neverthelefs pleafant and healthful, abounding with all the neceffaries and delicacies of life, which may be procured on ttr-ms much cheaper than In Europe. The number of inhabitants has been eftimated at one million ; but later calcula- tions have made the number confider-ably lefs. N. Lat. 23. 30. E. Long. 113. 20. Canton (John), an Ingenious natural philofopher, was born at Stroud, in Gloucefterfhire, in 17 18 ; and was placed, when young, under the care of a Mr Da- vis, of the fame place, a very able mathematician, with whom, before he had attained the age of nine years, he had gone through both vulgar and decimal ai-ithmetic. He then proceeded-to the mathematics, and particularly to algebra and aftronomy, wherein he had made a con- fiderable progrefs, when his father took him from fchool, and put him to learrv his own bufinefs, which was that of a broad cloth weaver-. This cir cumftance was not able to damp his zeal for the acquifitlon of knowledge. All his leifui-e time was devoted to the affiduous cultivation of afti-onomical fcience ; and, by the help of the Carohne tables, annexed to " Wing's Aftronomy," he computed eclipfes of the moon and other phenomena. His acquaintance with that fcience he apphed likcwife to the conftrufting of feveral kinds of dials.. Brrt the ftudies of our young philofopher being frequently purfued to very late hours, his father, fearing that they would Injure his health, forbad him the ufe of a candle In his chamber any longer than for the purpofe of going to bed, and would himfelf often fee that his Injunftlon was obeyed. The fon's thirft of knowledge was, however, fo great, that it nmde him attempt to evade the prohibition, and to find means of fccreting his light till the family had retired to reft, . when he rofe to profecute undifturbed his favourite piufuits. It was during this prohibition, and at thefe hoursj. C.mton. "CAN [12 Canton, hours, that he compxited, and cut upon ftone, with no better an inftrument than a common knife, the hnes of a large upriglit fun-dial, on which, befides the hour of the day, wafa fliown the rifing of the fun, his place in the ecliptic, and fome other particulars. When, this Was finilhed, and made known to his father, he permit* ted it to be placed againft the front of his houfe, where it excited the admiration of feveral gentlemen in the neighbourhood, and introduced young Mr Canton to their acquaintance, which was foUowedby the offer of the Hfe of their libraries. In the library of one of thefe gen- tlemen, he found " Maftin's Philofophlcal Grammar," which was the firft book that gave him a taile for na- tural philofopliy. In the poffcfiion of another gentle- tnan, a few miles from Stroud, he lirft faw a pair of globes; an objeft that afforded him uncommon plea- fure, from the great eafe with which he could folve thofe problems he had hitherto been accuffomed to compute. The dial was beautified a few years ago at the expence of the gentlemen at Stroud, feveral of whom had been his fchool-fellows, and who continued ilill to regard it as a very diflinguifhed performance. Among other perfons with whom he became acquaint- ed in early life, was the late reverend and ingenious Dr Henry Miles of Tooting, a learned and refpeftable member of the Royal Society, and of approved emi- nence in natural knowledge. This gentleman, per-* reiving that Mr Canton pofTeffed abilities too promi- fmg to be confined within the narrow limits of a coun- try town, prevailed on his father to permit him to come to London. Accordingly he arrived at the me- tropoHs March 4, 1737, and relided with Dr Miles at Tooting till the 6th of May following ; when he ar- tided himfelf, for the term of five years, as a clerk to Mr Samuel Watkins, mafter of the academy in Spital- fquax-e. In this fituation, his ingenuity, dihgence, and good conduft, were fo well difplayed, that on the expiration of his clerkfhip in May 1742, he was taken into partnerfliip with Mr Watkins for three years ; which gentleman he afterwards fucceeded in Spital- fquare, and there continued during his whole life. In 1 744, he married Penelope, the eldeft daughter of Mr Thomas Colbrooke, and niece to James Culbrooke, Efq; banker in London. Towards the end of 1745, eleftrlcity, which feems early to have engaged Mr Canton's notice, received a very capital improvement by the difcoveiy of the fa- mous I^eyden Phial. This event turned the thoughts of moft of the philofophers of Europe to that branch of natural philofophy ; and our author, who was one of the firft to repeat and to purfue tlie experiment, found his afTiduity and attention rewarded by many capital difcoveries. Towards the end of 1 749, he was concerned with his friend, the late Mr Benjamin Ro- bins, in making experiments in order to determine to •what height rockets may be made to afcend, and at what diflance their light may b'e fcen. In 1750 was read at the Royal Society, Mr Canton's '« Method of making artificial magnets, without the ufe of, and yet far fuperior to, any natural ones." This paper procu- red him the honour of being elected a member of the Society, and the prefent of their gold medal. The ■fame year he was complimented with the degree of M. A. by the univerfity of Aberdeen ; and, in 1751, -was chofen o-ae of the council.of the Royal Society. N°64, & 1 CAN In 1752, our- philofopher was fo fortunate as to he Camtort. the firft perfon in England, who, by attrafting the v eleftric fire from the clouds during a thunder-itorm, verified Dr Franklin's hypothefis of the fimilarity of lightning and eleftricity. Next year, his paper in* titled, " Eledlrical Experiments, with an attempt to account for their feveral Phaenomena," was read at the Royal Society. In the fame paper Mr Canton men- tioned his having difcovered, by a great number of ex- periments, that fome clouds were in a pofitive, and fome in a negative, ftate of ieleftricity. Dr Franklin, much about the fame time, made the Hke difcovery in America. This circumftance, together with our au- thor's conftant defence of the doctor's hypothefis, in- duced that excellent philofopher, immediately on his arrival in England, to pay Mr Canton a vifit, and gave rife to a friendfhip which ever after continued without interruption or dimunition. In the " Lady's Diary for 1756," our author anfwered the prize queflion that had been propofed in the preceding year. The que- ftion was, " How can what we call the fliooting of ftars be bcft accounted for ; what is the fubftance of this phsenomenon; and in what flate of the atmofphere doth it moft frequently ihow itfelf The folution, though anonymous, was fo fatisfaftory to his friend, Mr Thomas Simpfon, who then conducted that work, that he fent Mr Canton the prize, accompanied with a note, in which he faid, he was fure that he was not mif- taken in the author of it, as no one befides, that he knew of, could have anfwered the queftion. Ourphi- lofopher's next communication to the public, was a letter in the " Gentleman's Magazine for September 1759," on the eleftrical properties of the tourmalin, in which the laws of that wonderful ftone are laid down in a very concife and elegant manner. On December 1 3th, in the fame year, was read at the Royal Society, " An attempt to account for the regular diurnal va- riation of the Horizontal Magnetic Needle ; and alio for its iil-egular variation at the time of an Aurora Borealis." A complete year's obfervations of the di- urnal variations of the needle are annexed to the pa- per. On Kov. 5. 1 761, our author communicated to the Royal Society an account of the Tranfit of Ve- nus, June 6. 1 761, obferved in Spital-fquare. Mr Can- ton's next communication to the Society, was a letter addreffed to Dr Benjamin Frankhn, and read Feb. 4. 1762, containing fome remarks on Mr Delaval's elec- trical experiments. On Dec. 16. in the fame year, another curious addition was made by him to philofo- phical knowledge, in a paper, intituled, " Experiments to prove that water is not incomprefTible." Thefe ex- periments are a complete refutation of the famous Florentine experiment, which fo many philofophers have mentioned as a proof of the incompreiTibility of water. On St Andrew's day 1763, our author was the third time elefted one of the council of the Royal Society ; and on Nov. 8. in the following year, were read, before that learned body, his farther " Experi- ments and obfervations on the compreffibility of wai- ter, and fome other fluids." The eftablifliment of this fact, in oppofition to the x'eceived opinion, formed on the hafty decifion of the Florentine academy, was • thought to be deferving of the Society's gold medal. It was accordingly moved for in the council of 1 764 ; and after feveral invidious delays, which terminated ^ mucBi CAN Curiton II Can tyre. much to the honour of Mr Canton, h was prefented to him Nov. 30. 1765. The next communication of our ingenious author to the Royal Society, which we fliall take notice of in this place, was on Dec. 22. J 768, being " An eafy method of making a Phofphorus that will imbibe and emit light like the Bolognian ftone ; with expei-iments and obfervations." When he firft (liowed to Dr Frank- lin the initantaneous light acquired by fome of this phofphorus from the near difcharge of an electrified bottle, the do£lor immediately exclaimed, " And God faid, let there be light, and there was light." The dean and chapter of St Paul's having, in a letter to the prefident, dated March 6. 1 769, requefted the opinion of the Royal Society relative to the bell and moft ef- feftual method of fixing ele£lrical conduftors to pre- ferve that cathedral from damage by lightning, Mr Canton was one of the committee appointed to take the letter into confideration, and to report their opi- nion upon it. The gentlemen joined with him in this bufinefs were, Dr Watfon, Dr Franklin, Mi Delaval, and Mr Wilfon. Their report was made on the 8th of June following ; and the mode recommended by them has*been carried into execution. The lall paper of our author's, which was read before the Royal So- ciety, was on Dec. 21. 1769 ; and C' ntained " Expe- riments to prove that the Luminoufnefsof the Sea arifes from the putrefaction of its animal fubftances." In the account now given of his communications to the public, we have chiefly confined ourfelves to fuch as were the moft important, and which threw new and ught proper to employ him. The fenate in return daughter of Mithrldates the Great, hoping to find in fent him a ftaff, and chair of ivory ; which were pre- that prince a powerful friend to fupport him agalnft Ni- fents ufually beftowed on thofe only whom they looked comedes king of Bithynia, who laid claim to part of upon as attached to their intereft. Not long before Cappadocia. But Mithrldates Inftead of affifting, pro- this, Demetrius Soter king of Syria had offered Aria- cured one Gordius to polfon his unhappy fon-In law ; rathes his fifter in marriage, the widow of Perfeus king and, on his death, feized the kingdom, under pretence of Macedon : but this offer the king of Cappadocia was of maintaining the i-ights of the Cappadoclans agalnft obHged to dechne for fear of offending the Romans ; and NIcomedes, till the children of Ariarathes were in a his jfo 'doing was in the higheft degree acceptable to condition to govern the kingdom. The Cappadoclans •the repubhc, who reckoned him among the chief of her at firft fancied themfelves obliged to their new pro- allies. Demetrius, however, being greatly Incenfed tedlor ; but, finding him unwilling to refign the klng- at the flight put upon his fifter, fet up a pretender to dom to the lawful heir, they rofe up In arms, and, dri- the throne, one Orophernes, a fuppofitltlous, or, as ving out all the garrifons placed by Mithrldates, pla- others call him, a natural fon of the deceafed king, ced on the throne Ariarathes VIII. eldeft fon of their Th^citf- bartcbeejl^. They go in great herds ; few only and are fometimes four feet and a half long meafured are foHtary. They gullop feemin'gly with a heavy in a ftraight line. They are naturally of a duflcy co- pace, yet go fwiftly. Tliey d]-op on their knees tt) lour, and wrinkled ; but are generally brought'over fight like the white-footed antelope or nil-ghau, and highly poKflied. The females arc defiitute (Tf horns, the bofch-bok, nfter-dcfcribed. The flefh is fine grained, In the upper jaw is a hard horny fubflance, difpofed in but dry. — Mr Sparman informs us, that in this animal ridges. The length of the animal is nine feet ; the legs there is a pore one line in diameter,, an inch or an Inch are flender: the general colour is of a reddifli cafl, mixed and a half below and before the internal angle of the with gi-ey ; and from the tail, along the top of the ^eye. From this pore, which is the aperture of a carun- back, to the fliotilders, is a white flripe ; from which cle that lies below, there is fecreted a matter almofl: are feven others, four pointing towards the thighs, like ear-wax, which he obfer^ed tise Hottentots kept and three towards the belly; but they vary in number in a piece of fldn a-s a rare and excellent medicine; of flripes. On the upper' part of the neck is a fhort ■on the dried fkin of the animal, this pore is fcarcely to mane: beneath the neck, from the throat to the breaft, be difcerned. This Mr Sparman fuppofes is the rea- are fome long hairs hanging down. It inhabits the fon why fo great and accurate a zoologift as M. Pallas Cape of Good Plope, where it is called coedoes, and is (who defcrjbes it in his SpicUegia under the denomina- faid to leap to a mofl ailonifhmg height. This fpecies 'tion ^of Anidope luhal'is) makes no mention of this pore, wants \\\^ Jmvs lacrymalis. ^ ;as1ie -rnade his defcriptions chiefly from the dried flcins 9. The bofch-bok, or wood-goat of the Cape, a •of this -animal. The ufe of this pore, which is alfo fpecies of antelope, according to Mr Sparman, un- found -Tn the deer, is for affording freer rcfpiration, a known to all the cultivators of natural hifliory, whether «ircirmflancefoeffential to beafts of chafe. SeeCERvus. ancient or modern, till he defcribed it in the memoirs 7. The fpringer, with flender horns, annulated half of the Swedifti academy for the year 1780, quarter way, and twice contorted. The e-ars veiy long and 3d, by the name of antilope fyhaika. This animal T z has CAP [ t48 ] GAP Capra. Jias obtained the name it goes by, in confequence of " » its being the only one among the gazels in Africa, which may be properly fald to live in the woods and groves. In fize, the bofch-bok is foraewhat above two feet and a half high. The horns are ten inches and a half long ; the ears half the length of the horns, or five inches. — The horns are black, in fome meafure triangular, and at the fame time wreathed, fo that both the iides and angles have fomewhat of a fpiral turn. At bottom they are rather rough, in confe- quence of a fet of almoft innumerable wavy-rings ; which, however, are not elevated much above the fur- face. At top they are conical and fharp-pointed, and in that part as fmooth as though they had been pohfli- ed. The teeth of this animal are like thofe of other antelopes. It has no fore teeth or Incifores except in the lower jaw, where it has eight. — There is no porus cer'tfsrus in this, as there is in fome other antelopes. The hairs on the head are very Ihort and fine ; after- wards they become more rough and rugged, refem- bling goats hair more than that of gazels or harts. Forwards on the neck, breaft, fides, and belly, they are an inch and a half or two inches long. On the ridge of the neck, and fo on all along that of the back, they are three or four inches in length, fo as to form a kind of mane there, terminating in a tail about a finger's breadth long. On the hind part of the thighs and buttocks likewife, the hairs are eight inches long; the legs and feet are flender, and covered with fiiort hairs ; the fetlock -joints are fmall ; the nofe and un- der-lip are decorated with black whilkers about an inch long. The predominant colour in this animal is dark- brown, which occupies the principal part of the fides, the back, the upper part of the tail, the upper part of the cheft and fore-ribs, and the fore-part of the belly. A Hill darker brown, bordering upon black, is difcoverable on the outfide of the fboulders, and fome part of the foi-e-ribs. The fore-part of the nofe, from the eyes to the muzzle, is of a foot colour. The ears are likewife as black as foot on the outfide, but on the infide grey ; and both outwards and inwards covered with hairs ilill fhorter than thofe on the head; excepting half the fore-part of the lower edge, where the hairs are white and half an inch long. Divers fmall white fpots, from nine to twelve in all, are feen on each of the haunches and on the fides near them. A narrow line of long white hairs extends from the neck all along the back and tail, in the midil of the long brown hairs already defcribed. From the chine of the back to the fides run five white parallel Itreaks, which, however, are only difcoverable by a clofe infpedtion. This creature does much mifchief to the vineyards and kitchen-gardens of the Cape colonilts ; and it fhows a great deal of craft and artifice in avoiding the fnares and traps fet for it, as well as the ambufcades of the fportfraen. As the bofch-bok runs but flowly, it fometimes happens that he is caught by dogs. When he fees there is no other refource, he puts him- felf in a pofl;ure of defence ; and when he is going to butt, kneels down, like the white-footed antelope apd the hartbeeft. The colonills are not very fond^ of hunting him in this manner, as the beall on this occa- fion generally fells his Hfe at a very dear rate, by go- ring and killing fome of their beft and moft fpirited hqunds. This creature's horns, which are its chief defence, fometimes alfo prove its bane, by being en- tangled in the bufhes and fmall branches of trees, which thus Itop the beail in its flight. In fome imea- fure to avoid tliis, it carries its nofe horizontally and llraight forward while it runs; fo that its horns lie, as it were, diretlly on its neck : notwithltanding which, their horns are generally worn awa^ a little on the fore part, and thus acquire iome degree of poliib. — This fpecies of antelope is monogamous, or keeps in pairs. It is fwifter in woodlands than the dogs, w hich likewife fooner lofe fcent of him there. The female, which is without horns, and on that account runs about in the foreft more free and unimpeded, dOes-not fuffer herfelf fo eafily to be hunted out of the woods, having there, as well as on the plains, a more certain defence againft the dogs in her legs, than the male has in his horns, efpecially as ihe is not fo bulky and heavy as the male. Her breaft is faid to be very plump and flefiiy, but the flelli in general is not very tender. 10. The leucoryx with the nofe thick and broad, like that of a cow ; the ears fomewhat flouching ; body clumfy and thick : The horns long, very flight- ly incurvated, flender, annulated part of the way; black, pointed. The tail reaching to the firft joint of the legs, and tufted. The colour is in all parts a fnowy. whitenefs, except the middle of the face, fides of the cheeks, and limbs, which are tinged with red. — This fpecies is about the fize of a Welch runt ; and inha- bits Gow Bahrein, an ifle in the gulph of Baffora. 1 1 . The pii2/r6^on. — The proprietor of the veffel appoints the captain or mafter ; and he is to. form the crew, and choofe and hire the pilots, mates, and feamen ; though, when the- proprietor and mafler refide on the. fame fpot, they ge-- nerally ad in concert together. Captain Bajhanv, or Capondan. Bafhauo, in the- polity of tlK: Turks, fignifies the Turkifh high admi-- i-al.» He poffeflts the third office of the empire, and is invefled with the fame power at fea that, the vizir> has on fhore. Soliman II. inftituted this office in fa- vour of the famous Barbaroffa, with abfolute autho- rity over the officers of the marine and arfenal, whom he may punifli, cafhier, or put to death, as foon as he- is without the Dardanelles. He commands in chief in all the maritim.e countries, cities, caflles, &c. and^ at Conflantinople, is the firft magiflrate of police in: the villages on the fide of the Porte, and the canal of tha Black-Sea. The mark of his authority is a large In- dian cane,, which he carries in his hand, both in the arfenftl and with the army. — The captain-bafhaw en- joys tvi^o forts of revenues; the one fixed, the other ca-i fual. The firft arife from a capitation of the iflands in the Archipelago, and certain governments in Nato- lia and .Galipoli. The latter confift in the pay of the men who die during a campaign; in a fifth of all prizes made by the begs ; in the profits accruing from the la-, hour of the flaves, whom he hires as rowers to the grand iignior ; and in the contributions he exads in all pla- ces where he pafTes.. CAPTION, in Scots law, a writ ifTuing under his majefty's ilgnet, in his majefly's name, obtained at the inflance of a creditor in a civil debt, commanding mef- fengers at arms and other offix^ers of the law to appre- hend and imprifon the perfon of the debtor until he pay the debt,: — It is alfo the name. of a writ iffued by the covirt of Seffion againft the agents of the court, to return papers belonging to proceffes or law-fuxts, or atherwife to go to prifon. CAPTIVE, a flave, or a perfon taken from the enemy. Formerly captives in war became the flaves of thofe who took them ; and though flavery, fuch as obtain- ed among the ancients, is now. abolifhed, fome flia- dow of it ftill remains in refped of prifoners of war, , who are accounted the property of their captors, and have no right to. liberty but by conceffion from them. — The. Romans ufed their captives with great feverity ; their necks were expofed to the foldiers to be trampled on, and their perfons aftei-wards fold by public auc- tion. Captives were frequently burnt in the funeral , piles of the aucient,warriors,^as a facrifice. to the in^ fernal GAP [ I activity Vernal gods. Thofe of royal or noble blood had their heads (haven, and their hair fent to Rome to ferve as decoraitions for female toys, &c. They were led in triumph loaded with chains through Rome, in the emper-or's train, at leaft as far as the foot of the Ca- pitolime mount, for they were not permitted to afcend the fatcred hill, but carried thence to prifon. Thofe of the prime quality were honoured with golden chains on their hands and feet, and golden collars on their necks.. If they made their efcape, or killed them- felves, to avoid the ignominy of being carried in tri- umph,, their images or effigies were frequently carried in theiir place. CA-PTIVITY, in a general fenfe, the ftate or con- dition of a captive. Captivity, in facred hiftory, a punirtiment which God i nfliited upon his people for their vices and infi- delitie:6. The firft of thefe captivities is that of Egypt, from which Mofes delivered them ; after which, are reckoned fix during the government of the judges; but the greatell and moft remarkable were thofe of Judah and ICrael, which happened under the kings of each of thefe Ikingdoms. It is generally believed, that the ten tribes of Ifrael never came back again after their dlf- periiom ; and Jofephus and St Jerom are of this opi- nion : neverthelefs, when we examine the writings of the pr ophets, we find the return of Ifrael from capti- vity piointed out in a manner almoft as clear as that of the trilbes of Benjamin and Judah : See Hofea i. lo, 1 1 . Amos, ix. 14. The captivities of Judah are generally reckoned four; the fourth and laft of which fell in the year of the world 3416, under Zedekiah: and from this period begins the 70 years captivity foretold by Jeremiah. Since the deftruftion of the temple by the Romans, the Hebrews boaft that they have always had their heads or particular princes, whom they call J)rinces of the captivity, in the eaft and weft. The princes of the captivity in the eaft governed the Jews that dwelt in Babylon, Affyria, and Perfia; and the princes of the captivity in the weft governed thofe who dwelt in Ju- daea, Egypt, Italy, ana in other parts of the Roman empire. He who refided in Judsa commonly took up his ab'ode at Tiberias, and affumed the name of Rnf- ^hahhoih, " head of the fathers or patriarchs." He prefidces parties du corps que la purete de la langue n'cx- prime point, defquelles ils avoient abufe, et s'en etoient .fervis dans dcs crimes execrables." It feems by this imputation that the Albigeols were accufed by their enemies of fome enormities, probably unjuft, and fi- milar to thofe which religious enmity and prejudice have attributed to the followers of Zinzendoif in the jrefent century. CARCERES, in the ancient Circenfian games, were inclofures in the circus, wherein the horfes were reftrain- ed till the fignal was given for ftarting, when, by an admirable contrivance, they all at once flew open. Vol. IV. PartL CARCHEMISH (anc. ^eog.), a town lying upon Carchemifii the Euphrates, and belonging to the Aflyrians. Necho (' king of Egypt took it from the king of Aflyria, _f!]^f^ 2 Chr. XXXV. 20. Necho left a garrifon in it, which was taken and cut to pieces, in the fourth year of Je- hoiachan king of Judah, by Nebucliadnezzar king of Bdbylon, 2 Kings xxiii. 29. Ifaiah (x. 9.) fpeaks of Carcherairti, and feems to fay, that Tiglath pilefer made a conqueft of it, perhaps from the Egyptians. This is thought to be the fame city with that called Ciitefium by the Greeks and Latins. CARCINOMA, in medicine ; the fame withCAN- CtR. CARD, among artificers, an inftrutnent coafifting of a block of wood, befet with ftiarp teeth, fcrving to arrange the hairs of wool, flax, hemp, and the like-i there are difl^ercnt kinds of them, as hand-cards, ftock- cards, &c. They are made as follows: A piece of thick leather, of the fize intended for the card, is ftrained in a frame for that purpofe ; and then pricked full of holes, into which the teeth or pieces of iron wire are inferted. After which the leather is nailed by the edges to a flat piece of wood, in the form of an ©blong fquare, about a foot in length and half a foot in breadth, with a handle placed in the middle of one of the longer fides. The teeth are made in the following manner. The wire being drawn of the fize intended, a fltain or num- ber of wires are cut into proper lengths by means of a gauge, and then doubled in a tool contrived for that purpofe : after which they are bent into the proper diredlion by means of another tool; and then placed in the leather, as mentioned above. Cards, among gamefters, little pieces of fine thin pafteboard of an oblong figure, of feveral fizes ; but moft commonly, in Britain, three inches and an half long and two and an half broad, on which are painted feveral points and figures. The moulds and blocks for making cards are exa{ September 1575, according to Thuanus. This ac- count might be fufficient to mow the reader that Car- dan was of a very fickle temper; but he will have a much better idea of his Angular and odd turn of mind hy examining what he himfelf has written concerning his own good and bad qualities* He paid himfelf con- gratulatory compliments for not having a friend in this world ; \mt that, in r.^nuittal, he was attended by an aerial fpirit, emaned partly from Saturn and partly from Mercury, who was the conftant guide of his ac- tions, and teacher of every duty to which he was bound. 'He declared, too, that he was fo irregular in his man- ner of walking the ftreets, as induced all beholders to point at him as a fool. Sometimes he walked very Slowly, like a man abforbed in profound meditation ; then all on a fudden quickened his fteps, accompanying them with very abfurd attitudes. In Bologna his de- light was to be drawn about in a mean vehicle with three wheels. When nature did not vifit him with any pain, he would procure to himfelf that difagreeable fenfation by biting his lips fo wantonly, or pulling his fingers to fuch a vehement degree, as fometimes to force the tears from his eyes : and the reafon he affign- cd for fo doing, was to moderate certain impetuous Tallies of the mind, the violence of which was to him by far more infupportable than pain itfelf ; and that the fare confequencc of fuch a fevere difcipline was the enjoying the pleafure of health. He fays elfewhere, that, in his greatell tortures of foul, he ufed to whip his legs with rods, and bite his left arm ; that it was a great relief to him to weep, but that very often he could not i that nothing gave him more pleafure than to talk of things which made the whole company un- eafy ; that he fpoke on all fubjefls, in feafon and out of feafon ; and he was fo fond of games of chance, as to fpend whole days in them, to the great prejudice of his family and reputation, for he even flaked his furni- ture and his wife's jewels. Cardanus makes no fcruple of owning that he was revengeful, envious, treacherous, a dealer in the black art, a backbiter, a calumniator, and addlAed to all the foul and deteftable CKcefTes that can be imagined : yet, notwithilanding (as one would think) fo humbling a declaration, there was never perhaps a vainer mortal, or one that with lefs ceremony exprefled the high opl- pion he had of himfelf, than Cardanirs was known to tlo, as will appear by the following proofs. " I have •been admired by many nations : an infinite number of panegyrics, both in profe and verfe, have been compo- fed to celebrate my fame. I was born to releafc the world from the manifold errojs under which it gr oaned. V/}iat I have found out could not be difcovered either by my predeceffors or my cotemporaries ; and that is the reafon why thofe authors who write any thing wor- thy of being remembered, fcruple not to own that they t 163 1 CAR are indebted to me for it. I have compofed a book Cardan on the dialeftic art, in which there is neither one fu- jj perfluous letter nor one deficient. I finifhed it in feven ^ days, which feems a prodl^^y. Yet where is there a perfon to be found, that can boafl of his having become mafter of its doftrine in a year ? And he that (hall have comprehended it in that time, muft appear to have been inftrufted by a familiar daemon." The fame capricioufnefs obfervable in his outward conduft is to be obferved in the compofition of his works. We have a multitude of his treatifes in which the reader is flopped almoft every moment by the ob- fcurity of his text, or his digreffions from the point in hand. In his arithmetical performances there are feve- ral difcourfes on the motions of the planets, on the creation, and on the tower of Babel. In his dialeftic work, we find his judgment on hiftorians and the wri- ters of epiftles. The only apology which he makes for the frequency of his digreffions is, that they were pur- pofely done for the fooner filling up of his flieet, his bargain with the bookfeller being at fomuch perfheet; and that he worked as much for his daily fupport as for the acquifition of glary. The Lyons edition of his works, printed in 1663, confifts of ten volumes in folio. It was Cardanus who revived in latter times all the fecret philofophy of the Cabbala or Cabbalifts, which filled the world with fpirits ; a likenefs to whom, he aflerted, we might attain by purifying ourfelves with philofophy. He chofe for himfelf, however, notwith- Handing fuch reveries, this fine device, Tempus mea pof- fejfio, tempus mens ager : " Time is my fole pofTelTion, and the only fund I have to improve." In faft, when we confidcr the tranfcendent qualities of Cardan's mind, we cannot deny his having cultiva- ted it with every fpecies of knowledge, and his having made a greater progrefs in philofophy, in the medical art, in aftronomy, in mathematics, &c. than the great- eft part of his cotemporaries who had applied their minds but to one of thofe fciences. Scallger affirms, that Cardan, having fixed the time of his death, abftained from food, that his predidion might be fulfilled, and that his continuance to live might not difcredit his art. Cardan's father, who was a doftor of medicine, and a profeflbr of civil and ca- non law, died in the fame manner, in the year 1524, having abftained from all fuftenance for nine days. His fon tells us, that he had white eyes, and could fee in the night-time. CARDASS, a fort of card, proper for carding flocks of filk, to make cappadine of it. It is alfo the name which the French give to thofe flocks of filk. Carjdasses, Is alfo the name which, in the cloth manufaftories of Languedoc, they give to a fort of large card, which is ufed for carding the dyed wool, defigned for making cloth of mixed colours. CARDERS, in the woolle n manufactory, are per- fons who prepare wool, &c. for fpinning, &c. Carders, fpinners, weavers, fullers, flieermen, and dyers, not performing their duty in their occupations, fiiall yield to the party grieved double damages ; to be committed until payment. One juftice to hear and determine complaints. Carders, combers, forters, fpinners, or weavers, X 2 con- Cardi II Cardigan. CAR [164 conveying away, embezzling, or detaining any wool or yarn, delivered by the clothier, or any other perfon, fhall give the party grieved fuch fatisfaftlon, as two juftices, mayor, &c. /hall think fit : if not able or will- ina to make fatlsfaftion, for the firft offence to be whipped, or fet in the flocks in fome market- town, or in any other town where the offence is committed : the fecond offence to incur the like, orfiich further punifh- ment by whipping, &c. as juftices fliall think proper. GonviAion by one witnefs on oath, or confeffion. CARDI (Ludovico). See Civoli. CARDIAC, in a general fenfe, fignifics all medi- cines beneficial to the heart, whether internally or ex- ternally applied. The word comes from the Greek word cor ; the heart being reputed the imme- diate feat of their operation. Cardiacs, in a more particular fenfe, denote medi- cines which raife the fpirits, and give prefent flrength and cheerfulnefs ; thefe amount to the fame with what are popularly called cordials. Cardiacs are medicines anciently fuppofed to exert themfelves immediately in comforting and ftrengthening the heart : but the mo- dern phyficians rather fuppofe them to produce the ef- feft by putting the blood into a gentle fermentation, whereby the fprings, before decayed, are repaired and invigorated, and the tone and elullicity of the fibres of the veffels reflored ; the confequence of which is a more eafy and brifl< circulation. CARDIALGIA, in medicine, a violent fenfation of heat or acrimony felt towards the upper or left ori- fice of the flomach, though feemingly at the heart ; fometimes accompanied with palpitations of the heart, fainting, and a propenfity to vomit; better known by the name of cardiac pajpon, or heart-burn. See {.Index Jiibjohied ^o^Medicine. CARDIFF, a town of Glamorganfhire, in South Wales, feated on the river Tave, in a rich and fruitful foil. It is a large, compaft, well built town, having a caflle, a wall, and four gates, built by Robert Fitz- Hamon, a Norman, about the year 1100. It is go- verned by the conflable of the caflle, 12 aldermen, 1 2 buigeffes, &c. and fends one member to parhament. Here the affixes and fefflons are held, befides feveral <;ourt9i There is a handfome bridge over the river, to which fmall veffels come to take in their lading. It ha& now only one church, St Mary's having been long fince thrown down by the undermining of the river. The oaftle, though much decayed, makes a grand appear- an(;je even at this time ; and the walls of the town are very Rtong and thick. The church has a fine, towcr- fteeple, and the town-hall is a good ftrufture. The magiflfates are ele£led every year by the majority of the burgeffes. W. Long. 3. 20. Lat. 51. 30. Cardiff gives title of Britifh Baron to the family of Bute in Scotland. CARDIGAN, tlie capital town of Cardiganflttre, in South Wales, is feated near the mouth of the river Tei-vy, on the Irifh channel. It is indifferently large and well-built, containing three wards, one church, and the c»unty-gaol It is governed by a mayor, 1 3 alder- men, 13 common-council-men, &c. Here are the ruins of a caflle which was built by Gilbert de Clare, about the year 1 160. It fends one member to Parliament ; and has two markets, held on Tuefdays and l^tiu day*. W. Long. 4. 38, N. Lat. 52. 15. Ihire \\_ Cardinal. "I GAR CARDIGANSHIRE, a county of South Wales, Cardigan- bounded on the north by Merionethfhire and Morvt- gomeryfhire, on the eaft by RadnorfhiTe and Breck- nockfliire, on the wefl by the Irifh Sea, and on the fouth by Caerraarthenfhire. Its length from north- wefl to fouth-eafl is about 44 miles, and its breadth near 20. The air, as in other parts of Wales, varies with the foil, which in the fouthern and weftern parts is more upon a level than this principality generally is, which renders the air mild and temperate. But as the northern and eaflern parts are mountainous, they are confequently more barren and bleak. However, there are cattle bred in all parts ; but they have nei- ther wood nor coals of their own for fuel ; they have rich lead mines, and fifh in plenty, with fowls both tame and wild. The principal rivers are the Teivy, the Ridol, and the Iflwith. This county hath fxve market-towns, vi%. Cardigan,, Aberiflwith, Llanbad- arnvawn, Llanbedar, and Tregaron, with 77 parifhes ; and was formerly computed to have upward of 300O: houfes, and 520,000 acres of land. It fends two mem- bers to parliament ; one for the county, and one for Cardigan. CARDINAL, in a- general fenfe, an appellation given to things on account of their pre-eminence. The word is foi-med of the Latin cardo, a hinge ; it being on thefe fundamental points that all the reft of the . fame kind are fuppofed to turn. Thus, juflice, pru- dence, temperance, and fortitude, are called the four . cardinal virtues, as being the bafis of all the reft. Cardinal Flower, in botany. See Lobelia. Cardinal Points, in cofmography, are the four in- terfeftions of the horizon with the meridian, and the prime vertical circle. Of thefe, two, viz. the inter- feftions of the horizon and meridian, are called North and South, with regard to the poles they are dire£lcd to. The other two, viz. the interfe£lions of the ho-, rizon, and firfl vertical, are called Eaji and Weji. The cardinal points, therefore, coincide with the fbur cardinal regions of the heavens; and are 90° di-, ftant from each other. The intermediate points arc called collateral points. Cardinal Points ^ in aflrology, are the rifing and x ffctting of the fun, the zenith, and nadir. Cardinal A^;//, in aflronomy, are Aries, Libra, Cancer, and Capricorn. Cardinal Winds, are thofe that blow from the car? - dhial points. Cardinal Numbers, in grammar^ arc the numbers one, two, three, &c. which are indeclinable ; in oppo- fition to the ordinal numbers, firil, fecond, third, fourth, &Ci Cardinal, an ecclefiafticar prince in the Romifh church, being one who has a voice in the conclave at the eleftion of a pope. Some fay the cardinals were fo called from the Latin incardinatio, which fignifies the adoption in any churcb made of a prieft of a fo- reign church, driven thence by misfortune ; and add, that the ufe of the word commenced, at Rome and Ravenna ; the revenues of the churches of which cities being very great, they became the common refuge of the unhappy priefts of all other churches. The cardinals compofe the pope's council or fenate : in the Vatican is a conflitution of pope John, which regulates the rights and titles of the cardinals ; and 4 which. CAR f 1^5 ] CAR Cardinal!. v/h.Ich declares, that as the pope reprefents Mofes, fo the' cardinals reprefent the feventy elders, who, under the' pontifical authority, decide private and particular differences. Cardinals, in their firll inftitution, were only the primcipal priefts, or incumbents of the parifhes of Rome. In the primitive church, the chief prieft of a pariih, who immediately followed the bifhop, was called pref- hytitr cardinalis, to diftinguifli him from the other petty priefts, who had no church nor preferment ; the term wa;8 firft applied to them in the year 150 others fay, under pope Silvefter, in the year 300. Thefe cardi- nal priefts were alone allowed to baptize, and admini- fl;e]r the eucharift. When the cardinal priefts became biflkops, their cardinalate became vacant ; they being then fuppcfed to be raifed to a higher dignity. — Un- der pope Gregory, cardinal priefts, and cardinal dea- cons, were only fuch priefts or deacons as had a church or chapel under their particular care : and this was the ori ginal ufe of the word. Leo IV. in the council of Rome, held ia^ 853, calls them preJI>yteros Jut car dims ; and their churches, parocJnas cardinaler. The cardinrils continued on this footing till the eleventh century : but as the grandeur and ftate of his Lolinefs became then exceedingly augmented, he -w^ould have his council of cardinals make a better figure than the ancient priefts had done. It 13 true, they ftill preferved their ancient title ; but the thing exprefled by it was no more. It was a good while, however, before they had the precedence over biftiops, ^or got the ele(^ion of the pope into their hands : but when they were once poflefled of thofe privileges, they foon had the red hat and purple ; and growing ftill in autho- rity, they became at length fuperior to the bilhops, by the fole quality of being cardinal*. X)u-Cange obferves, that originally there were three kinds of churches : the firft or genuine churches were properly called parijhes ; the fecond, deaconries, which were chapels joined to hofpitals, and ferved by dea- cons ; the third were fimple oratories^ where private maftes were faid, and were difcharged by local and re- fident chaplains.- Htr adds, that, to diftinguifh the principal or parifh churches from the chapels and ora- tories, the name cardinales was given, to them. Ac- cordingly, pari/h churches gave titles to cardinal priefts; and fomtf^rhapek alfo, at length, ^ave the title o£ car- ^nal deacons. Others obferve, that thfe term cardinal was given not only to priefts, but alfo to biftiops and deacons who were attached to certain churches, to diftinguifli them from thofig- wh6 only ferved them en pajfant, and by commiffiofl.. Titular churches, or benefices, were a kind of parifhes, i, e. churches afligned each to a cardi- nal prieft } with fome ftated diftrift , depending on it, and a font for adminifterlng of baptifm, in cafes where the bifhop himfelf dould not adminifter it. Thefe cardinals were fubordinate to the biftiops ; and ac- cordingly, in councils, particularly that held at Rome in 868, fubfcribed after them. It was not, however, only at Rome, that priefts bore this name } for we find there were cardinal priefts in France : thus, the curate of the parifti of St John rfe Vignes is called in old charters the cardinal pricji of that parinik The title of cardinal is alfo given to fome bifliops. Cardinal. quatenus bishops ; e. g. to thofe of Mentz and Milan : — v— ' the archbiftiop of Bourges is alfo, in ancient writings, called cardinal ; and the church of Bourges, a cardinal church. The abbot of Vendome calls himfelf cardinalis natus. The cardinals are divided into three clafies or ordei-sj containing fix biftiops, fifty priefts, and fourteen dea- cons ; making in all feventy: which conftitute what they call the J'acnd college. The cardinal biftiops, who are, as it were, the pope's vicars, bear the titles of the biftiopricks afligned to them ; the reft take fuch titles as are given them : the number of cardinal biftiops has been iixed ; but that of cardinal priefts and dea- cons, and confequently the facred college, itfelf, is al- ways fiuftuating. Till the year 1 125, the college on- ly confifted of fifty-two or fifty -three : the council of Conftance reduced them to twenty-four ; but Sixtus IV. without any regard to that reftridion, raifed them again to fifty-three, and Leo to fixty-five. Thus, as the number of cardinal priefts was anciently fixed to twenty-eight, new titles were to be eftabliftied, in pro- portion as new cardinals were created. As for the cardinal deacons, they were originally no more than feven for the fourteen quarters of Rome ; but they were afterwards increafed to nineteen, aud after that were again diminiftied. According to Onuphn'us, it was pope Pius IV. who firft enaded, in 1562, that the pope ftiould be chofen only by the fenate of cardinals;. whereas, till that time, the eledion was by all the clergy of Rome. Some fay, the eleftion of the pope refted in the cardinals, exclufive of the clergy, in the time of Alexander III. . in n6o. Others go higher ftill, and fay, that Nicho- - las II. having been eleded at Sienna,, in 1058, by the cardinals alone, occafioned the right of election to be taken from the clergy and people of Rome ; only lea- ving them that of confirming him by their confent ; which was at length, however, taken from them. Set- his decree for this purpofe, ifiued in the Roman coun- cil of 1059, in Hardouin's Ada ConciHorum, torn. vi. . pt. i. p. 1 1 65^ Whence it appears, that the cardinals who had the right of fuffrage in the eledion of his fucceffbrs, were divided by this pontiff into cardinal hi/hops and cardinal clerks : meaning by the former the feven bifhops who belonged to the . city and territory of Rome ; and by the latter, the cardnial prejbyters or minifters of the twenty-eight Roman parifhes, or prin- cipal churches. To thefe were added, in procefs 01 time, under Alexander III. and other pontiffs, new - members, in order to appeafe - the tumults occafioned by the edid of Nicholas II. . At the creation of a new cardinalj the pope per- forms the ceremony of opening and fhutting his mouth | which is done in a private confiftory. The fhutting hrs mouth implies the depriving him of the liberty of giving his opinion in. congregations ; and the opening his mouth, which is performed 15 days after, fignifies the taking off this reftraint. However, if the pope happens to die during the time a cardinal's mouth is fhut, he can neither give his voice in the eledion of a new pope, nor be himfelf advanced to that dignity. The drefs of a cardinal is a red foutanne, a rocket, a ftiort purple maatle, and a red hat.. Thc- CAR [ 166 ] CAR Jareening. Cardinal Tlie cardinals began to wear tlie red hat at the council of Lyons, in 1243. The decree of pope Ur- ban VIII. whereby it is appointed, that the cardinals be addrefled under the title of etninence, is of the year 1630 ; till then, they were called tlhjlryjmi. When cardinals are fent to the courts of Princes, it is in quahty of legates a latore; and when they are ap- pointed governors of towns, their government is call- ed by the name of legation. Cardinal has alfo been applied to fecular officers. Thus, the prime minifters in the court of the emperor Theodofuis, are called cardinaks. Caffiodorus, lib. vii. formul. 31. makes mention of the cardinal prince of the city of Rome ; and in the lift «f officers of the duke of Bretagne, in 1447, we meet with one Raoul de Thorel, cardinal of Quillart, chancellor, and fervant -of the vifcount de Rohan : which fhows it to have been an Inferior quality. CARDIOID,in tlTC higher geometry, an algebrai- cal curve, fo called from its refeniblance to an heart. CARDIOSPERMUM,in botany: A genus of the trigynia order, belonging to the oftandila clafs of plants ; and In the natural method ranking under the 39th order, Tr'ihilatjt. The calyx is tetraphyllous, the petals four, the neftarlum tetraphyllous and unequal ; •the capfuies three, grown together, and inflated. Tiiere are two fpecies, both natives of the Eall and Weft In- dies ; but have no great beauty, or any other remark- able property. CARDIUM, or Cockle, in zoology, a genus of infefts belonging to the order of vermes teftaceas. The ihell conlifts of two equal valves, and the fides are e- qual. There are 21 fpecies of this genus. Common on all fandy coafts, lodged a little beneath the fand ; their place marked by a depreffed fpot. They are wholefome and delicious food. CARDONA, a handfome town of Spain, in Cata- lonia, with a ttrong caftle, and the title of a duchy. Near it is an inexhauftible mountain of fait of feveral colours, as red, white, carnation, and green : but when wafhed, it becomes white. There are alfo vineyards which produce excellent wine, and very lofty pine- trees. It Is feated on an eminence, near the river Car- denero. E. Long. i. 2fi. N. Lat. 41. 42. CARDUUS, in botany: A genus of the polyga- mla aequalis order, belonging to the fyngenelia clafs of plants ; and in the natural method ranking under the 49th order, Compnfite. The calyx Is ovate, imbricated ' with pricklv fcales, and the receptacle hairy. Of this genus there are 26 fpecies, ten of which are natives of Britain, and being troublefome weeds require no de- fcrlption. Sume few of the exotic kinds are propaga- ted in gardens for the feke of variety; but even thefe have neither beauty nor any other property to recom- mend them. C/iRDVvs BenecJlcfiis. See Cn ic us. CAREENINCJ, in the fea-languaga, the bringing a flnp to He down on one fide, in order to trim and -caulk the other fide. A flilp is faid to be brought to the careen, when, the .mort of her lading being taken out ; fhe is hulled down on one fide, by a fmall vefTel, aslow as neceflary ; and ,there kept by the weight of the ballaft, tordnance, &c. as well as by ropes, left her mafts fhould 'be ftrained tijo much J in oider that her fides and bottom may be Carew. trimmed, feams caulked, or any thing that is faulty Career under water mended. Hence, when a (hip lies on one fide when fhe fails, fhe is falel. He died in the prime of ■iife, about the year 1639. Carew (Richard), author of the " Survey of Corn- wall," was the eldeft fon of Thomas Carew of Eaft Anthony, and was born in 1551. When very youngs he became a gentleman commoner of Chrift-church college, Oxford ; and at 14 years of age had the ho- nour of dilputing, extempore, with the afterwards fa- mous CAR [ 1 Garew; mou8 Sir Philip Sydney, in the prefence of the earls "V \of Leicefter, Warwick, and other nobility. After fpending three years at the univerfity, he removed to the Middle Temple, where he relided the fame length of time, and then travelled- into foreign part8. Not long after his return to England, he married, in 1577, Juliana Arundel, of Trerice. In 1581, Mr Carew was made juftice of the peace, and in 1586 was appointed high-fheriff of the county of Cornwall ; about which time he was likewife queen's deputy for the miliiia. In 1589, he was elecfted a member of the college of Antiquaries, a diftinftion to which be wss intitled by his literary abilities and purfuits. What particularly engaged his attention was his native county, his '* Sur- vey" of which was publiHied, in 4to, at London, in 1602. It hath been twice reprinted, firft in 1723, and next in 1769. Of this work Cambdcn hath fpo- ken in high terms, and acknowledges his obligations to the author. In ihc prefent improved ftate of topo- graphical knowledge, and fince Dr Borlafe's excellent publications relative to the county of Cornwall, the value of Carew^s " Survey" mud have been greatly di- miniflied. Mr Gough remarks, that the hiftory and monuments of this county were faintly touched by Carew ; but it is added, that he was a perfon extreme- ly capable of defcribing them, if the infancy of thofe ftudles at that time had afforded light and materials. Another work of our author was a tranflatLon from the Italian, intituled, *' The Examination of Men's Wits. In which, by difcovering the variety of natures, is fhowed for what profeffion each one is apt, and how far he (hall profit therein." This was publifhed at London in 1594, and afterwards in 1604; and tho' Richard Carew's name is prefixed to it, hath been principally afcribed by fome perfons to his father. Ac- cording to Wood, Carew wrote alfo, *' The true and ready Way to learn the Latin Tongue," in anfwer to a query, whether the ordinary method of teaching the Latin by the rules of grammar be the befl; mode of inftrufting youths in that language ? This trad^ is in- volved in Mr Hartlib's book upon the fame fubjedl, and with the fame title. It is certain that Carew was a gentleman of confiderable abilities and literature, and that he was held in great eftimation by fome of the moft eminent fcholars of his time. He was particu- larly intimate with Sir Henry Spelman, who extols him for his ingenuity, virtue, and learning. Carew (George), brother to the fubjeft of the laft article, was educated in the univerfity of Oxford, after which he Itudied the law in the inns of court, and then travelled to foreign countries for farther improvement. On his return to his native country, he was called to the bar, and after fome time was appointed fecretary to Sir Chriftopher Hatton loi-d chancellor of England. This was by the efpecial recommendation of queen Elizabeth herfeif, who gave him a prothonotaryfliip in the chancery, and conferred upon him the honour of knighthood. In 1597, Sir George Carew, who was then a mafter in chancery, was fent ambaffador to the king of Poland. In the next reign, he was one of the commlffioners for treating with the Scotch concerning an union between the two kingdoms ; after which he was-appointed ambalfador to the court of France, where he continued from the latter end of the year 1 605 till 67 1 CAR 1609. During his refidencc in that country, he form- Carew, ed an intimacy with Thuanus, to whom he commu. ^ ^^ay- nicated an account of the tranfaftions in Poland whilft " ~ he was employed there, which was of great fervice to that admirable author in drawing up the i2ifl book of his hiftory. After Sir George Carew's return from France, he was advanced to the important poft of ma- iler of 4he court of Wards, which honourable fituation he did not long live to enjoy ; for it appears from a letter written by Thuanus to Cambden in the fpring, of 161 3, that he was then lately deceafed. Sir George Carew mai-rled Thomafine, daughter of Sir PVancis Godolphin, great-grandfather of the lord treafurer Go- dolphin, and had by her two fons and three daughters. When Sir George Carew returned, in 1609, from his French erabaffy, he drew up, and addrplfed to James ** A Relation of the State of France, with the cha- racters of Henry IV. and the principal Perfons of that Court." The charafters are drawn from perfonal knowledge and cl'ofe obfervation, and might be of fer- vice to a general hiftorian of that period. The com- pofition is perfpicuous and manly, and entirely free from the pedantry which prevailed in the reign of - James I. but this in the lefs furprifing, as Sir George- Carew's tafte had been formed in a better sera, that of queen Elizabeth. The valuable traft we are fpeaking of lay for a long time in MS. till happily falling into the hands of the earl of Hardwicke, it was communi- cated by him to Dr Birch, who pubiifrted'it, in 1749, at the end of his " Hiftorical View of the Negocia- tions between the Courts of England, France, and Bruffels, from 1592 to 1617." That intelligent and induftrious writer juftly obferves, that it is a model upon which ambafTadors may form and digeft their no- tions and reprefentations ; and the late celebratf^d poet- Mr Gray hath fpoken of it as an excellent perform- ance. V CAREY (Harry), a man diftinguifhed by both poetry and mufic, but perhaps more fo by a certain facetioufnefe, which made hrm agreeable to every bo- dy. He publifhed in 1 720 a little coUeftion of poems ; and in 1732, fix cantatas, written and compofed by himfelf. He alfo compofed fundry fongs for modern comedies, particularly thofe in the " Provoked Hiif- band :" he wrote a farce called " The Contrivances," in which were feveral little fongs to very pretty airs of his own compofition : he alfo made two or three little dramas for Goodman's- fields theatre, which were very favourably received. In 1729, he publifhed by fub- fcription his poems much enlarged ^ with the addition of one intituled " Namby Pamby," in which Am- brofe Philips is ridiculed. Carey's talent, fays his hi- ftorian, lay in humour and unmaltvolent fatire : to ri- dicule the rant and bombaft of modern tragedies he wrote one, to which he gave the ftrange title of ** Chrbnonhotonthologos," afted in 1734. He alfo wrete a farce called " The Honeft Yorkfhireman." Carey was a thorough Engltfhman, and had an unfur- mountable averfion to the Italian opera and the fingers in it : he wrote a burlefque opera on the fubjeA of the " Dragon of Wantley ;" and afterwards a fequel to it, intituled, " The Dragonefs both which wers eileemed a true burlefque upon the Italian opera. Hij qualities being^of the entertaining kind,, he was led hn CAR [ i68 ] GAR Cargadors to more expences than his fiaances could bear, and weft longitude, and between 1 1 and 1 8 degrees of north Ci»ri1>l>ee They lie in the form of a bow or ftmiciircle, tfla"^' ^ Caribbee Iflands. thus was frequently in diftrefs. His friends however were always ready to alTilt him by their little fubfcrip- tions to his works v and encouraged by thcfe, he re- publlflied, in 1740, all the fongs he hid ever compo- ied, in a coUeftion, intituled, " The Mufical Century, in 100 Englifh Ballads, &c." and, in 1 743, his drama tic works, in a fmall Volume, 410. With ail his mirth and good-humour, he feemg to have been at times deep- ly affedled with the malevolence of fome of his oWn profeffion, who, for reafons that no one can guefs at, were his enemies : and this, with the preffure of his circumftances, is fuppofed to have occafioned his un- timely end ; for, about 1744, In a fit of defperation, he laid violent hands on himfelf, and, at his houfe in Warner-ftreet, Cold-bath Fields, pat a period to a life, which, fays Sir John Hawkins, had been led with- out reproach. It is to be noted, and it is fomewhat fingular in fuch a charadler, that in all his fongs and poems on wine, love, and fuch kind of fubjefts, he ieems to have manifeiled an inviolable regard for de- cency and good manners. CARGADORS, a name which the Dutch g;lve to thofe brokers whofe bufinefs Is to find freight for fliips outward bound, and to give notice to the merchants, who have commodities to fend by fea, of the fhipsthat are ready to fail, and of the places for which they are bound. CARGAPOL, or Kargapol, the capital of a ter- ritory of the fame name, in the province of Dwina,.in 'Mufcovy : E. Long. 36°. N. Lat. 63°. CARGO denotes all the merchandifes and effefts which are laden on board a (hip. Snper-CARGO, a perfon employed by merchants to go a voyage, over fee. the. cargo, and difpofe of it to the beft advantage. CARIA (anc. geog. ), a country of the ^Hither A- . fia ; swhofe hmits are extended by fome, while they are , contrafted by others. Mela, Pliny, extend the mari- time Caria from Jafus and HalicarnalTus, to Calynda, and the borders of Xycia. The Inland CarIa Ptolemy extends to the Meander and beyond. Car, Cariatesy iCarlatisf CarlJJa, and Cans ^ and Ci7iV«, are the genti- litious names ; Carius and Car'cus the epithets. In Care periculunif was a proverbial faying on a thing expo- fed to danger, but of no great value. The Cares being 'the Swifs of thofe'days, were hired and placed in the front latitude. ttretching almoft from the coaft of Florida north, to near the river Oroonoque. Thofe th it lie neareft the eaft have been called the IVindioard IJlandt, the others the Leetuard, on account of the winds blowing gene- rally fiom the eaftern point in thofe quarters. Abb(5 Raynal conjeftures them to be the tops of very high mountains formerly belonpring to the continent, vs'hich have been changed Into iflduds by fome revolution that has laid the flat country under water. The iz, of Carlifle. The fee is valued in the king's books at L. 530 14:1 lir, but is computed to be worth annu- ally L.'zSoo. The clergy's tenth amounts only to L. 161 : J : 7I. To this cathedral belong a bifhop, a dean, a chancellor, an archdeacon, foar prebendaries, Caflock 72 ] CAR eight minor canons, &c. and other inferior officers and fervants. _ rlfcroni The Pi£ts wall, which was built acrofs the country 1 from Newcaftle, terminates near this place. Carlifle was a fortified place, and ftill has its governor and lieutenant-governor, but no garrifon. It was taken by the rebels, Nov. 15. 1745; and was retaken by the duke of Cumberland on the loth of December follow- ing, and deprived of its gates. It is governed by a mayor, twelve aldermen, two bailifFs, &c. and has a confiderable market on Saturdays. The manufaftures of Carlifle are chiefly of printed linens, for which near 3000/. per annum is paid in duties. It is alfo noted for a great manufaAure of whips, in which a great number of children are employed. — Salmons appear in the Eden in numbers, fo early as the mofiths of De- cember and Januarv ; and the London and even New- j caftle markets are fupplled v/ith early fifti from this i river : but it is remarkable, that they do not viiit the Efk in any quantity ' till April ; notwithftanding the mouths of the two rivers are at a fmall diftance from each other. — Carlifle fends two members to parliament, and gives title of Earl to a branch of the How«d family. CARLOCK, in commerce, a foit of ifinglafs, made with the fturgeon's bladder, imported from Archangel. The chief ufe of it Is for clarifying wine, but it is alfo ui'ed by the dyers. The beft carlock comes from Aftra- can, where a great quantity of fturgeon is caught. CARLOSTAD, or Carlstad, a town of Sweden in Wermeiand, featcd on the lake Warmer, In E. Long. , 14. 4. N. Lat. 59. 16. Car-lostad, or Carl/ladt, a town of Hungaiy, ca- pital of Croatia, and the ufual refidence of the gover- nors of the province. It Is feated on the river Kulph, . in E. Long. 16. 5. N. Lat. 45. 34. CARLOWITZ, a fmall town of Hungary, in Scla- vonia, remarkable for a peace Concluded here between the Turks and Chriftians in 1669. It is feated on the weft fide of tke Danube, in E. Long. ig. 5. N. Lat. 45.25. CARLSCRONA, or CarlscroOn, afea-port town in the Baltic, belonging to Sweden. It derives its origin and name from Charles Xl. who firft laid the foundations of a new town in 1680, and removed the fleet from Stockholm to this place, on account of its advantageous fituation in the centre of the Swedifh feas, and the fuperlor fecurity of its harbour. The greateft part of Carlfcrona ftands upon a fmall rocky ifland, which rifes gently in a bay of the Baltic ; the fuburbs extend over another fmall rock, and along the mole clofe to the bafon where the fleet is moored. The way into the town from the main land is carried ovef a dyke to an ifland, and from thence along two long wooden bridges joined by a barren rock. The town is fpacious, and contains about 18,000 inhabltams. It is adorned with one or two handfome churches, and a few tolerable houfes of brick ; but the generality of buildings are of wood. The fuburbs arc fortified to- wards the land by a ftone-wall. The entrance into the harbour, which by nature is extremely difficult from a number of flioals and rocky iflands, is ftill fur- ther fecured from the- attack of an enemy'3 fleet by two ftrong forts built on two iflands, under the batte- ries of which all veiTels muft pafs. Formerly CAR [ I fCarlftadt Formerly vefleh in this port, when Careened and 'i repaired, were laid upon their fides in the open, har- ^^"^^ ' hour, until a dock, according to a plan given by Pol- heim, was hollowed in the foHd rock : it was begun in 17145 and finifhed in but as it was too fmall for the admiffion of men of war, it has Ijitely been enlarged, and is how capable of receiving a (hip of the firft rate. But new docks have been began upon a ftupendous plan worthy of the ancient Romans. According to the original fcheme, it was intended to conftruft 30 docks, for buildiwg and laying up the I'argeft (hips, at the extremity of the harbour. A large bafon, capable of admitting two men of war, is defigned to communicate, by fluices, with two fmaller bafons, froni each of which are to extend, like the radii of a circle, five rows of covered docks : each row is to be feparated bv walls of ftone ; and each dock to be provided with Iluice-gates, fo as to be filled or emptied liy means of pumps. Clofe to the docks, magazines for naval ftores are to be conftrycled, and the whole to be inclofed with a ftone-wall. The pro- jeiSh was begun in 1757; but was much neglefted until the acceffion of his prefent majefty, who warmly pa- tronised the arduous undertaking. At the commence- ment of the works, L. 25,000 were annually expended upon them ; which fum has been leiTened to about •Ij. 6000 per annum, and the number of docks reduced to 20. The firfi; dock was finifhed in 1779, and it was computed that the whole number would be exe- cuted in 20 years. CARLSTADT, a town of Germany, in the circle of Franconia, and bifliopric of Wurtfburg, feated on the river Maine, in E. Long. 9. 51. N. Lat. 50. o. CARLTON, a town in Norfolk held by this te- nure, that they fhall prefent 1000 herrings baked in 14 pies to the king, wherever he fliall be when they firft come in feafon. CARMAGNIOLA, a fortified town of Italy, in Piedmont, with a good caftle. It was taken by the French in 1691, and retaken by prince Eugene the fame year. It Is feated in a country abounding in torYi, flax, and fiik, near the river Po, in E. Long. *f,. 32. Nl Lat 44. 43. ■• CARMANIA (mc. geog.), a country of Afia, to the eaft of Perfia, having Parthia to the north, Ge- drofia to the eaft, to the fouth the Perfian Gulf or Sea in, part, and in part the Indian, called the Carma- ttian Sea, diftinguiflied into Carmania Deferta, and Car- mania Propria ; the former lying to the fouth of Par- thia ; and to the foyth of that, the Propria, quite to the fea. Its name is from the Syriac,. Carma, figni- fying a " vine," for which that country was famous, yielding cluflers three feet long. Now Kerman, or GARiPdANiA, a province of modern Perfia. CARMEL, a high mountain of Paleiline, ftanding ©n the flcirts of the. fea, and forming the moii re- markable headrland on all that coaft. It extends eail- xivard from the fea as far as the plain of Jezreel, and from the city of that name quite to C«farea on the fouth. It feems to have had the name of Carmel from its great fertility ; this word,, according to the He- brew import, fignifying the inne of God, and is ufed in fcripture to denote any fruitful fpot, or any place planted with fruit trees. This mountain, we are af- fured, was very fertile. Mr Sandys acq^uaints us, that, 73 ] GAR when well cultivated, it abounds with olives, vines, CafmeHtes. and variety of fruits and herbs both medicinal and aro- ^ - matic. Others, however, reprefent it as rattier dry and barren ; v/hich perhaps may have happened from the negle6l of agriculture fo common in all parts of the T urkifli empire, efpecially where they are expofed to the incurfions of the Arabs. Carmel is the name of the mountain, and of a city" built on it ; as well as of a heathen deity worfhipped in itj, but without either temple or ftatue : though anciently there mull have been a temple, as we are told that this mountain was a favourite retreat of Pythagoras, who fpent a good deal of time in the temple, without any perfon with him. But what hath rendered mount Carmel moft celebrated and revered both by Jews and Chriftians, is its having been the reljdence of the prophet Elijah, who is fuppofed to. have lived there in a cave (which is there fhown), before he was taken up into heaven. CARMELITES, an order of religious, making one of the four tribes of mendicants or begging friars; and taking its name from mount Carmel, formerly in- habited by Elias, Eliiha, and the children of the pro- phets ; from whom this order pretends to defcend in an uninterrupted fucceffion. The manner in which they make out their antiquity has fomething in, it too ridi- culous to be rehearfed. Some among them pretend tiiey are defcendants of JefusChrilt ; others go further, and make Pythagoras a Carmelite, and the ancient druids regular branches of their order. Phccas, a GrecK monk, fpeaks the moft reafonably. Ht fays, that in his time, 1185, Elias's cave was ftiU extant on the moun- tain ; near which were the remains of a building which intimated that there had been anciently a monaftery ; that, fome years before, an old monk, a prieft of Ca- labria, by revelation, as he pretended, from tHe pro- phet Elias, fixed there, and alTembled ten brothers.— Iti 1209, Albert, patriarch of Jerufalem, gave the foll- tarles a rigid rule, which Papebroch has-fince printed. In 1217, or, according to - mon in the ifle of Anglefey, and were alfo ufed as fepulcliral monuments,, in the manner of tumuli; far Mr Rowland found a curious urn in one of thefe car- nedde. Whence it may be inferred, that the Britons had the cuftom of throwiaig ftones on the deceafed.. From this, cuftom is derived the Welch proverb, Karn urdyhtn, " ill betide tliee." CARNEIA, in antiquity, a feftival in honour of Apollo, furnamed Carneus, held in moft cities of Greece, but efpecially at Sparta, where if was firft in- ftituted. The reafon of the name, as well as the oceafion of 75 ] CAR the inftitution, is controverted. It laflcd nine days, beginning on the 13th of the month Carneus. The ceremonies were an imitation of the method of living and difcipline vifed in camps. CARNEL.— The building of fiiips firft with their timber and beams, and after bringing on their planks, is called carnel-'worky to diftinguifii it from chnch- work. VefTels alfo which go with mizzen-fails inftead of main-fails are by fome called carnels. CARNELIAN, in natural hiftor}--, a precious ftone, of which there are three kinds, diftinguifhed by three colours, a red, a yellow, and a white. The red is very- well known among us ; is found in roundifli or oval mafles, much like our common pebbles ; and is gene- rally met with between an inch and two or three inches in diameter : it is of a fine, compa£t, and clofe tex- ture ; of a glofly furface ; and, in the feveral fpecimens, is of all the degrees of red, from the paleft flefh-co- . lour to the deepeft blood-red. It is generally free from fpots, clouds, or variegations: but fometimes it is yeined very beautifully with an extremely pale red, or with white ; the veins forming concentric cir» cles, or other lefs regular figures, about a nucleus, in the manner of thofe of agatesi Tlie pieces of carne- lian which are all of one colour, and perfectly free from veins, are thofe which our jewellers generally mak^; ufe of for feals, though the variegated ones are much more beautiful. The carnelian is tolerably hard, and capable of a very good polifh : it is not at all affe;£ted by acid menftruums : the fire divefts it of a part of its colour, and leaves it of a pale red ; and a ftrong and long continued heat will reduce it to a pale dirty gray. The fineft carnelians are thofe of the Eaft Indies ; but there are very beautiful ones found in the rivers of Silefia and Bohemia and we have fome not defpicable ones in England. Though the ancients have recommended the carne- lian as aftringent, and attributed a number of fanciful virtues to it, we know of no other ufe of the ftone than the cutting feals on it ; to which purpofe it is excel- lently adapted, as being not too hard for cutting, and yet hard enough not to be liable to accidents, to take a good polifh, and to feparate eafily from the wax. CARNERO, in geography, a name given to that - part of the gulph of Venice which extends from the weftern coaft of Iftria to the ifiand of Groffa and the coaft of Morlachia. Carnero is likewife the name of the cape to th? weft of the mouth of the bay of Gibraltar. CARNIFEX, among the Romans, the common executioner. By reafon of the odioufnefs of his of- fice, the carnifex was ertprefslj" prohibited by the laws from having his dwelling-houfe within the city. In middle age writers carnifex alfo denot-es a butcher. Under tke Anglo-Danifh kings, the carnifex was an - officer of great, dignity ; being ranked with the archbi- fhop of Yoi-k, earl Goodwin, and the lord fteward. Flor. Wigorn. ann. 1040. Rtx Hardecanutus Alfrkiim Ehor, Archlep, GoaditAnum - comitem, lulrkum difp^nfaioreniy Throtid fuum carnifieem, altos magna dignitatis vires Londinuin mifit. CARNIOLA, a duchy of Germany bounded on the fouth by the -Adriatic fea, and that part of Ift-ria poS'tffed Carnel II Caruiola. G A R [ 17 Carniola, poffeffed by the republic of Venice ; on the i>ortli, by Carnival. Cannthia and Stiria ; on the eaft, by Sclavonia and ^ V""*' Croatia ; on the weft, by Friuli, the county of Gorz or * Goritz, and a part of the gulph of Venice ; extending in length about 110 miles, and in breadth about 50. It had its ancient name Carn'ia, as well as the modern one Carn'wla, from its ancient inhabitants the Carnr, a tribe of Scythians, otherwlfe called Japidcs, whence this and the adjacent countries were alfo called ^V"''^"^* Carniola is full of mountains, fome of which are cul- tivated and inhabited, fome covei-ed with wood, others naked and barren, and others continually buried in fnow. The valleys are very fruitful. Here are like- wife mines of iron, lead, and copper ; but fa^t mult be had from the foverelgn's magazines. There are fe- veral rivers, befides many medicinal fprings and in- land lakes. The common people are very hardy, going barefooted in winter through the fnow, with open breafts, and fleeping on a hard bench without bed or bolfter. Their food is alfo very coarfe and mean. In winter, w^ien the fnow lies deep on the ground, the mountaineers bind either fmall baikets, or long thin narrow boards, like the Laplanders, to their feet, on which, with the help of a ilout ftaff or pole, they defcend with great velocity from the mountains. When the fnow is frozen, they make ufe of a fort of irons or llcaits. In different parts of the country the inhabitants, efpecially the common fort, differ greatly in their drefs, language, and manner of living. In Up- per and Lower Carniola they wear long beards. The languages chiefly in ufe are the Sclavonian or Wendifh, and German ; the firft by the commonalty, and the latter by people of fafliion. The duchy is divided in- to the Upper, Lower, Middle, and Inner, Carniola. The principal commodities exported hence are, iron, fteel, lead, quickfilver, white and red wine, oil of olives, cattle, fheep, cheefe, linen, and a kind of woollen ftufF called mahalan, Spanifh leather, honey, walnuts, and timber ; together with all manner of wood-work, as boxes, difhes, &c. — Chriftianlty was firft planted here in the eighth century. — Lutheranifm made a con- fiderable progrefs in it ; but, excepting the Walachians or Uflcokes, who are of the Greek church, and ll;yle themfelves Staraverzi, i. e. old believers, all the inha- bitants at prefent are Ronian Catholics. Carniola was long a marquilate or margravate ; but in the year 1 23 i was ere£led into a duchy. As its proportion towards the maintenance of the army, it pays annually 363,171 flo- rins; but only two regiments of foot are quartered in it. CARNIVAL, or Carnaval, a time of rejoicing, a feafon of mirth, obferved with great folemnity by the Itahans, particularly at Venice, holding from the twelfth day till Lent. The word is formed from the Italian CarnavaUe ; which Mr Du Cange derives from Carn-a-val, by rea- fon the flefli then goes to pot, to make amends for the feafon of abftinence then enfuing. Accordingly, in the corrupt Latin, he obferves, it was called Carneievamen, and Carnifprivium; as the Spaniards ftill denominate it ■carries tollendas. Feafts, balls, operas, concerts of mufic, intrigues, marriages, &c. are chiefly held in carnival time. The -carnival begins at Venice the fecond holiday in Chrift- mas • Then it is they begin to wear maiks, and open 6 ] CAR their play-lioufcs and gaming houfes ; the place of Oar(,ivo« St Mark is filled with mountebanks, jack-puddings, ^^^^.'^Ij^J^pji. pedlars, whores, and fuch like mob, who flock thi- . ^''" ^ ' ther from all parts. There have been no lefs than feven fovereign princes and .3O5OOO foreigners here to partake of thefe diverfions. CARNIVOROUS, an epithet applied to thofe a. nimals which naturally fcek and feed on ficfli. It has been a difpute among naturalifts, whether man is naturally carnivorous. Thofe who take the negative fide of the queftion, infill chiefly on the ftruftureofour teeth, which are moftly incifores or molares ; not fuch as carnivorous animals are fur- nifhed with, and which are proper to tear flefh in pieces : to which it may be added, that, even when we do feed on flefh, it is not without a prepara- tory alteration by boiling, roafting, &c. and even then that it h the hardeft of digeftion of all foods. To thefe argument* Dr Wallis fubjoins another, which in that all quadrupeds which feed on herbs or plants have a long colon, with a ccecum at the upper end of it, or iomewhat equivalent, which conveys the food by a long and large progrefs, from the flomach downwards, in order to its flower pafTage and longer ftay in the inteftinej ; but that, in carnivorous ani- mals, fuch ccecum is wanting, and inftead thereof there is a more fhort and flender gut, and a quicker- paflage through the inteftines. Now, in man, the ccecum is very vifible : a ftrong prefumption that na- ture, who is ftill confiftent with herfelf, did not in- tend him for a carnivorous animal. — It is true, the ccecum is but fmall in adults, and feems of little or no ufe ; but in a fcetus it is much larger in proportion ; And it is probable, our cuftomary change of diet, as we grow up, rfiay occafion this fhrlnking. But to thefe arguments, Dr Tyfon replies, that if man had been by nature defigned not to be carnivorous^ there would doubtlefs have been found, fome where on the globe, people who do not feed on flefh ; which is not the cafe. Neither are carnivorous animals always without a colon and coecum ; nor are all animaii car- nivorous which have thofe parts: the opoffum, for inilance, hath both a colon and ccecum, and yet feeds on poultry and other flefli ; whereas the hedge- hog, which has neither colon nor coecum, and fo ought to be carnivorous, feeds only on vegetables. Add to this, that hogs, which have both, will feed upon flefh; when they can get it ; and rats and mice, which have large ccecums, will feed on bacon as well as bread and cheele. Lallly, the human race are furnifhed with teeth neceffary for the preparation of all kinds of foods; fiom whence it would feem, that nature intended we fliould live on all. And as the alimentary dufk in the human body is fitted for digefting all kinds of food, ought we not rather to conclude, that nature did not intend to deny us any? It is no lefs difputed whether mankind were carni' vorous before the flood. St Jerom, Chryfoftom, The- odoret, and other ancients, maintain, that all animal food was then forbidden ; which opinion is alfo ftre^ nuoufly fupported among the moderns by Curcellceus, and refuted by Heidegger, Danzius, Bockhart, &c. See Antediluvians. CARNOSITY is ufed by fome authors for a little- fiefliy CAR flefliy excrcfcence, tubercle, or wen, formed in the urethra, the neck of the bladder, or yard, which flops the paffage of the urine. — Carnofities are very difficult of cure : they are not eahly known but by introducing a probe into the pafTage, which there meets with re- fiftance. They ufually arife from fome venereal ma- lady ill managed. CARO (Annibal), a celebrated Italian poet, was born at Civita Nuovo in 1507. He became fecretary to the Duke of Parma, and afterwards to Cardinal Farnefe. He was alfo made a knight of Malta. He tranflated Virgil's jEneid into his own language with fuch propriety and elegance of expreffion, that he was allo\Jt^ed by the bed judges tp have equalled the origi- nal. He alfo tranflated Arlllotle's rhetoric, two ora- torios of Gregory Nazianzen, with a difcourfe of Cy- prian. He wrote a comedy ; and a mifcellany of his poems was printed at Venice in 1584. He died at Rome in 1566. CAROLINA, a province of North America, com- prehending the moft wefterly part of Florida, and lying between 29 and 36 degrees of N. Lat. It is bounded on the eaft by the Atlantic, and on the weft by the river Miffifipi, on the north by Virginia, on the fouth by Georgia, and to the fouth of Georgia by the Floridas. This country is feated between the extremities of heat and cold, though the heat is more tro«bIefoine in fummer than the cold in winter ; their winters being very fhort, and the frofty mornings frequently fuc- ceeded by warm days. The air is generally ferene and clear the greateft part of the year ; but in Fe- bruary and March the inhabitants have a ctiftom of burning the woods, which caafes fuch a fmoke as to ftrangers would feem to proceed from a fog or thick- nefs in the air. The fmoke of the tar-kilns hkewife deceives ftrangers, and gives them an ill opinion of the air of Carolina ; to which alfo conduces a cuftom of the Indians of fetting fire to the woods in their hunt- ings, for many miles round. The great rains are in winter, though they are not without heavy fhowers at midfummer ; add to thefe the conftant dews tliJtt fall in the night, which refrefti the ground and f'.jpply the plants with moifture. In North Carolina, the north- weft winds in the V/intcr occafion very pinching wea- ther ; but they are not of long continuance. Wefter- ly winds bring very pleafant weather ; but the fouth- erly are hot and unwholefome, occafioning fevers and other difdrders. But this muft be underftood of fum- mer, for in winter they are very comfortable. The depth of winter is towards the latter end of February, and then the ice is not ftrong enough to bear a man's weight. In Auguft and September there are fome- times great ftorms and fqualls of wind, which are fo violent as to make lanes of 100 feet wide, more or lefs, thro' the woods, tearing up the trees by the roots. Thefe ftorms generally happen- once in about feven years; and are attended with dreadful thunder, lightning, and heavy rains. They commonly happen about the time of the hurricanes which rage fo fatally among the iflands between the tropics ; and feem to be occafioned by them, or. to proceed from the fame caufe : but by the time they reach Carolina, their force is much a- bat€d ; and the farther north they proceed, fo much the more do they decreafe in fury. The foil on the coaft Vol. IV. Tart I. [ ^77 1 CAR is fandy; but farther up, the country is fo fruitful Carolins. that they have not yet been at the trouble to manure ^^"^ their land. The grains moft cultivated are Indian corn and rice, though any fort will thrive well enough ; they have alfo pulfe of feveral forts, little known in England. All kinds of garden ftuff ufual in England are cultiva- ted here, and may be had in great plenty. They export large quantities yearly of rice, pitch, tar, tur- pentine, deer-flfins, and timber for building ; cyprefs, cedar, faffafras, oak, walnut, and pine. Befides thefe they alfo fend out beef, pork, tallow, hides, furs, wheat, peas, potatoes, honey, bees-wax, myrtle-wax, tobacco, fnake-root, cotton, feveral forts of gums and medicinal drugs. Indigo is alfo cultivated in this pro- vince, but of an Inferior quality to that which comes from the Caribbee iflands. It hath been attempted in vain to cultivate vines, and produce filk, in this country ; for though the frofts here do not continue long without intervals of warmer weather, they are fuflicient to check the growth of the vine, as well as olives, dates, oranges, &c. The furs are bought of i7» 77//?. the Indians with vermilion, lead, gunpowder, coarfe"^''^'' cloth, iron, and fpirituous liquors. As yet they have not a fufficient number of handicraftfmen ; which ren- ders labour very dear, and a fupply of clothes from Europe neceffary. The afpe6l of the country is very fine, being adorned with beautiful rivers and creeks., and the woods with lofty timber, which afford dehght- ful and pleafant feats for the planters, and render the fencing their lands very eafy. And as they have plenty of fifh, wild fowl, and venifon, befides other neceffaries which this country produces naturally, they live eafy - and luxurioufly. Their rivers are large, and navigable a great many miles up the country. They rife near the mountains, and abound with delicate fifh, befides water-fowl of different kinds. In fome there are iflands which yield good pafture, without the annoyance of wild beafts. The chief mountains arc the Cherokee or Allegany mountains, which are fituated north and north-weft, five or fix hundred miles diftant from the fea. They are very high ; and abound with trees, plants, ftonea, and minerals, of different kinds. This country is divided into North and South Ca- rolina, and Georgia ; each of which, -before the late revolution, was under a particular governor. The North is fubdivided into four counties, Granville, Col- liton, Berkley, and Craven ; and South CaroHna into two, Clarendon and Albemarle. This laft is alfo di- vided into 14 parlfhes or townfhips, each of which has a brick or timber church. The former Hkewife has the fame number of parlfhes. Charleftown is the capi- tal of the whole country. Carohna was difcovered by Sebaftian Cabot, about the year 1500, in the reign of Henry VII. but the fettling of it being neglefted by the Enghfh, a colony of French Proteilants, by the encouragement of Ad- miral Cohgni, were tranfported thither; and named the place of tlveii- firft fettlement ^rx Carolina, in ho- nour of their prince, Charles IX. of France : but in a fhort time that colony was deftroyed by the Spa- niards ; and no other attempt wa^ made by any Euro- pean power to fettle there till the year 1664, when 800 Enghfli landed at Cape-Fear in North Carolina, and took pofTelfion of the country. In 1670 Cha. II. Z of CAR r 178 1 CAR Carolina; of Britain granted Carolina to the Lords Berkley, """V— ' Clarendon, Albemarle, Craven, and Afhley, Sir George Carteret, Sir William Berkley, and Sir John Colliton. The plan of government for this new colony was drawn up by the famous Mr Locke, who very wifely pro- pofed an univerfal toleration in religious matters. The only reftridlion in this refpeft was, that every perfon claiming the proteftion of that fettlement, ihould, at the age of 17, regifter himfelf in fome particular com- munion. To civil hberty, however, our philofopher was not fo favourable ; the code of Carolina gave to the eight proprietors who founded the colony, and to their heirs, not only all the rights of a monarch, but all the powers of a legiflation. The court, which was compofed of this fovereign body, and called the Pah' tine Court, was invefted with the right of nominating to all employments and dignities, and even of confer- ring nobility; but with new and unprecedented titles. They were, for inftance, to create in each county two caciques, each of whom was to be pofTefied of 24,000 acres of land ; and a landgrave, who was to have 80,000. The perfons on whom thefe honours fhould be beftowed were to compofe the upper houfe, and their polTeflions were made unalienable. They had only the right of farming or letting out a third part of them at the moft for three lives. The lower houfe was compofed of the deputies from the feveral counties and towns. The number of this reprefentative body was to be increafed as the colony grew more populous. No tenant was to pay more than about a (hillingper acre, and even, this rent was redeemable. All the inhabitants, however, both flaves and freemen, were under an ob- ligation to take up arms upon the lirll order from the Palatine court. It was not long before the defefts of this conftitu- tion became apparent. The proprietary lords ufed every endeavour to eftablifh an arbitrary government ; and, on the other hand, the colonifts exerted them- felves with great zeal to avoid fervitude. In confe- quence of this ftruggle, the whole province, diilrafted with tumults and diflentions, became incapable of making any progrefs, though great things had been expected from its particular advantages of fituation. Though a toleration in religious matters was a part of the original conftitution, diffentions arofe likewife on that account. In 1 705, Carteret, now Lord Gran- ville, who, as the oldeft of the proprietors, was fole governor of the colony, formed a defign of obliging all the non-conformifts to embrace the ceremonies of the Church of England ; and this, adt of violence, though difavowed and rejefted by the mother-country, inflamed the minds of the people. In 1720, while this animofity was ftill fubfifting, the province was attacked by feveral bands of favages, driven to defpair by a continued courfe of the moft atrocious violence and jnjuftice. Thefe unfortunate wretches were all put to the fword: but, in 1728, the lords proprietors having refufed to contribute towards the expenees of an ex- pedition, of which they were to (hare the immediate benefits, were deprived of their prerogative, except Ijord Granville, who ftill retained his eighth part. The reft received a recompence of about 24,00011 The colony was taken under the immediate proteAion of the crown, and from that time began to floLiriffi. The divifion into North and South Carolina now took place, and the fettlement of Georgia commenced in 1732. < See Georgia. CAROLINE, See Carline, ^ CAROLiNE-Books, thc uamc of four books, compofed by order of Charlemagne, to refute the fecond council of Nice. Thefe books are couched in very harfli and fevere terms, containing 120 heads of accufation againft the council of Nice, and condemning the worfhip of irnages. CAROLOSTADIANS, or Carlostadians, an ancient fe6l or branch of Lutherans, who denied the real prefence of Chrift in the eucharift. They were thus denominated from their leader An- drew Caroloftadius, who having originally been arch- deacon of Wittemberg, was converted by Luther, and was the firft of all the reformed clergy who took a wife ; but difagreeing afterwards with Luther, chiefly in the point of the facrament, founded a fe6t apart. The Caroloftadians are the fame with what are other- wife denominated Sacramentarians, and agree in moft things with the Zuinglians. CAROIjUS, an ancient Englifti broad piece of gold flruck under Charles I. Its value has of late been at 23 ftiillings Sterling, though at the time it was coined- it is faid to have been rated at 20 ftiillings. Carolus, a fmall copper coin, with a little filver mixed with it, ftruck under Charles VIII. of France. The carolus was worth 1 2 deniers when it ceafed to be current. Thofe which are ftill current in trade in Lorrain, or in fome neighbouring provinces, go under the name of French fols. CAROTIDS, in anatomy, two arteries of the neck, which convey the blood frcfin the aorta to the brain; one called the rights and the other the left,, carotid. CARP, in ichthyology, the Englifli name of a fpe- cies of cyprinus. See Cyprinus ; alfo Carp-Fifing. The carp is the moft valuable of all kinds of fifti for ftocking of ponds. It is very quick in its growth, and brings forth the fpawn three times a-year, fo that the increafe is veiy great. The female does not begin to breed till eight or nine years old ; fo that in breed- ing-ponds a fupply muft be kept of carp of that age. The beft judges aUov/, that, in ftocking a breeding- pond, four males ftiould be allowed to twelve females. The ufual growth of a carp is two or three inches in length in a year ; but, in ponds which receive the fat- tening of common fewers, they have been known tO' grow from five inches to 1 8 in one year. A. feeding- pond of one acre extent will very well feed 300 carp of three years old, 300 of two years, and 400 of one year old. Carp delight greatly in ponds that have marley fides ; they love alfo clay-ponds well fheltered from the winds, and grown with weeds and long grafs at the edges, which they feed on, in the hot months. Carp and tench thrive veiy faft in ponds and rivers near the fea, where the water is a little brackifh ; but they are not fo well tafted as thofe which live in frefh wa- ter. Grains, blood, chicken-guts, and the like, may at times be thrown into carp-ponds, to help to fatten the fifti. To make them grow large and fat, the growth of grafs under the water ftiould by all means poflible be encouraged For this purpofe, as the water de- creafes in the fummer, the fides of the pond left naked, and dry fhould be well raked witih an iron rake, to de-=- 3 ^^^Y: Carp. CAR Carpates ftro>y all the weeds, and cut up the II earth : hay-feed fiiould then be fown plentifully in ^''P^""'^' thefe places ; and more ground prepared in the fame manner, as the water falls more and more away. By this means there will be a fine and plentiful growth of young grafs along the fides of the pond to the water's edg-e ; and when the rains fill up the pond again, this will be all buried under the water, and will make a feeding-place for the fifli, where they will come early in the morning, and will fatten greatly upon what they find there. CARPATES,orALPEsBASTARNiCAE,(anc.geog.) a range of mountains, running out between Poland, Hungaiy, and Tranfylvania. Now called the Carpa- thian Mountains. CARPATHIUM (Mare, Horace, Ovid) ; the fea that wafhes the ifland Carpathus. CARPATHUS, an iiland on tlie coaft of Afia, two hundred ftadia in compafs, and an hundred in length. Its name is faid to be from its fituation on the coaft of Caria. It lies between Rhodes and Crete, in the fea which, from this illand, is called the Carpathian Sea, and has to the north the Ionian, to the fouth the Egyptian, to the weft the Cretan and African feas. It is two hundred furlongs in compafs, and a hundred in length. It had anciently, according to Strabo, four cities; according to Scylax only three. Ptolemy mentions but one, which he calls Pofidiurn. This ifland is now called Scarpanto. CARP-SI A, a kind of dance anciently in ufe among the Athenians and Magnefians, performed by two perfons, the one afting a labourer, the other a robber. The labourer, laying by his arms, goes to ploughing and fowing, ftill looking .'. arily about him as if afraid of being furprifed : the robber at length appears, and the labourer, quitting his plough, betakes himfelf to his arms, and fights in defence of his oxen. The whole was perfonned to the found of flutes, and in cadence. Sometimes the robber was overcome and fometimes the labourer ; the viftor's reward being the oxen and plough. The defign of the exercife was to teach and accuitom the peafants to defend themfelves againft the attacks of ruf&ans. CARPENTER, a perfon who praftifes Carpen- try. The word is formed from the French charpen- tier, which fignifies the fame, formed of charpente, which denotes timber ; or rather from the Latin car- pentariusy a maker of carpenta, or carriages. Carpenter of a Shlpj an officer appointed to exa- mine and keep in order the frame of a fliip, together with her mails, yards, boats, and all other wooden machinery. It is his duty in particular to keep the fhip tight ; for which purpofe he ought frequently to review the decks and fides, and to caulk them when it is neceffary. In the time of battle, he is to exa- mine up and down, with aU poflible attention, in the lower apartments of the ftiip, to ftop any holes that may have been made by fhot, with wooden plugs pro- vided of feveral fizes. CARPENTRAS, an epifcopal town of Provence in France, and capital of Venaiifin. It is fuhjcft to ^he pope ; and is feated on the river Aufon, at the foot of a mountain. E. Long, 5'. 6. N. Lat. 44. 4. CARPENTRY, the art of cutting, framing, and joining large pieces of wood, for the ufes of building. [ 179 ] C A R furface of the It is one of the arts fubfervient to archite£lure, and Is Cafpentuci divided into houfe-carpentry and fltip-carpentry : the il firft is employed in raifing roofing, flooring of houfes, ^-arpi. ^c. and the lecond in the building of fliips *, barges, ^ Sif c. The rules in carpentry are much the fame with i,u^fding, ^ thofe of Joinery ; the only difference is, that car- pentry is ufed in the larger and coarfer work, and joinery in the fmaller and curious. CARPENTUM, in antiquity, a name common to divers forts of vehicles, anfwering to coaches as weU as waggons, or even carts, among us. The carpentum was originally a kind of car or vehicle in which the Roman ladies were carried ; though in after times it was alfo ufed in war. Some derive the word fi-om cnrro ; others from Cannenta the mother of Evander, by a converfion of the m into^. CARPET, a fort of covering of fluff, or other ma- terials, wrought with the needle or on a loom, which is part of the furniture of a houfe, and commonly fpread over tables, or laid upon the floor. Perfian and Turkey carpets are thofe moft; efteem* ed ; though at Paris there is a manufaftory after the manner of l''erfia, where they make them little inferior, not to fay finer than the true Perfian carpets. They are velvety, and perfectly imitate the carpets which come from the Levant. There are alfo carpets of Germany, fome of which are made of woollen fluffs, as fergcs, l5c. and called fquare carpets : others are made of wool alfo, but wrought with the needle, and pretty often embellilhed with filk ; and, laftly, there are fome made of dogs hair. We have likewife car- pets made in Britain, which are ufed either as floor- carpets, or to cover chairs, &c. It is true, we are not arrived at the like perfeftion in this raanufafture with our neighbours the French ; but may not this be ovv'ing to the want of a like public encouragement ? CARPET-Knights, a denomination given to gown-men and others, of peaceable profeffions, who, on account of their birth, office, or merits to the public, or the like, are, by the prince, raifed to the dignity of knight- hood. They take the appellation carpet y becaufe they ufually receive their honours from the king's hands in the court, kneeling on a cai-pet. By which they are di- ftinguiflied from knights created in the camp, or field of battle, on account of their military prowefs. Car- pet-knights poffefs a medium between thofe called truck, or dunghill'knights , who only purchafe or merit the honour by their wealth, and knights-bachelors, wh» are created for their fervices in the war. CARPI, a principality of Modena in Italy, lying about four leagues from that city. It formerly be- longed to the houfe of Pio ; the elder fons of which bore the title of Princes of St Gregory. In the be- ginning of the 14th century Manfroy was the firft prince of Carpi ; but in the i6th, the em.peror Cha. V, gave the principality to Alfonzo duke of Ferrara. This nobleman, in recompence, gave to Albert Pio, to whom the principality of Carpi belonged of right, the town of Saifuolo and forae other lands. Albert was, however, at laft obliged to retire to Paris ; where, being ftrlpped of all his ettates, he died in 1538, with the reputation of being one of the beft and braveft men of his age. The family of Pio is yet in being, and continues attached to the French couit. Some of Z 2 them CAR [ 1 Can i, them liave even been raifed to the purple, and flill Carpiruis. ^ figure in Europe. " Carpi, a town of Italy in the duchy of Modena, and capital of the laft mentioned principality. It has a ftrong caille, and is fituated in E. Long. ii. 12. N. Lat. 44. 45. Carpi, a town of the Veronefe in Italy, memorable for a viftoiy gained by the Imperiahlls over the French in 1 701. It is fubjeft to the Venetians; and is fi- tuated on the river Adige, in E. Long. 11. 39. N. Lat. 45. TO. CARPI (Ugo da), an Italian painter, of no very con- fiderable talents in that art, but remarkable for being the inventorof that fpecies of engraving on wood, diftinguifh- ed by the name of chiaro-fcuro, in imitation of drawing. This is perfonned by ufing more blocks than one ; and Ugo da Carpi ufually had three ; the firft for the outhne and dark fhadows, the fccond for the lighter fhadows, and the third for the half tint. In that manner he Ifruck off prints after feveral dcfigns, and cartons of Raphael ; particularly one of the Sybil, a Defcent from the Crofs, and the Hiftory of Simon the Sorcerer. He died in 1500. This art was brought to a ftill higher degree of perfeftion by Balthafar Pe- ruzzi of Siena, and Parmigiano, who publilhed feveral excellent defigns in that manner. Carpi (Girolamo da), hiftory and portrait painter, was born at Ferrara in 1 50 1, and became a difciple of Garofalo. When he quitted that mafter, he devoted his whole time, thoughts, and attention, to ftudy the works of Correggio, and to copy them with a moft critical care and obfervation ; in which labour he fpent feveral years at Parma, Modena, and other cities of Italy, where the beft works of that exquifite painter were preferved. He acquired fuch an excellence in the imitation of Correggio's ftyle, and copying his pidtures, that many paintings finifhed by him were ta- ken for originals, and not only admired, but were ea- gerly purchafed by the connoiffeurs of that time. Nor is It improbable that feveral of the paintings of Giro- lamo da Carpi pafs at this day for the genuine work of Correggio himfelf. He died in 1556. CARPINUS, the horn-beam, in botany; A ge- nus of the polyandria order, belonging to the monce- cia clafs of plants ; and in the natural method ranking under the 50th order, Amentacete. The calyx of the male is monophyllous and ciliated ; there is no corolla, but 20 ftamina The calyx of the female is monophyl- lous and ciliated ; no corolla ; two germens, with two ftyles on each. The fruit is an egg-lhaped nut. There are two fpecies, viz, 1 . The betulus, or common hornbeam ; a deciduous tree, native of Europe and America. Its leaves are of a darkifh green, and about the the fize of thofe of the beech, but more pointed and deeply ferrated. Its branch- es are long, flexible, and crooked ; yet in their general appearanc-e very much refemble thofe of the beech : in- deed there is fo great a likenefs between thofe two trees, efpecially in the fhrubby and underwood ftate, that it would be difficult to diftinguirti them at the firft glance, were it not for that gloffy varnifh with which the leaves of the beech are ftrongly marked. In the days of Evelyn, when topiary work was the garden- er's idol, the hornbeam might be conhdered as deferving of thofe endearing expreffions which_ that enthufiaftic !o ] CAR writer has been pkafed to lavifii upon it : neverthelefs, Carpintis. «s an ornamental in modern gardening it ftands low ; ^ and its prefent ufes are few. As an undemood it af- fords ftakes and edders, fuel and charco •!. Its timber ranks with that of the beech and the fycamore; and the inner bark is faid to be much ufed in Scandinavia to. dye yellow. The only fuperior excellency of the horn=«- beam lies in its fitnefs for flcreen fences for fheltering gardens, nurferies, and young plantations from the fc- verities of the winter fcafon. It may be trained to almoft any height, and by keeping it trimmed on the fides it becomes thick of branches, and confequently thick of leaves ; which being by their nature retained , upon the plant after they wither, a hornbeam hedge occafions a degree of ftielter nearly equal to that given by a brick wall Indeed, be'ng lefs rcfleilive than that expenfive ilcreen, it affords a more uniform tem^ perature of air to the plants which ftand near it. In this point of view, too, the hornbeam is ufeful to be planted promifcuoufly, or in alternate rows, amongil more tender plants in expofed fituations, in the fame manner as the birch ; to which it has more than one preference : namely, it is warmer in winter, — and Hanbury fays, the hornbeam is peculiarly giateful to hares and rabbits ; confequently it may prevent their injuring its more vahiable neighbours : yet, like Eve- lyn, he feems to be of opinion tliat it is difaffefted by deer. If this be really the cafe, the hornbeam may upon many occafions be introduced into deer-parks with fingular propriety. Of this fpecies there are three varieties : The Eaftern Hornbeam, Flowering Hornbeam, Americaa Hornbeam. The eaftern hornbeam arrives to the leaft height of all the forts : about ten feet is the far- theft of its growth, and it looks pretty enough with trees of the fame growth. The leaves are by no means fo large as the common fort ; and as the branches are always clofer in proportion to the fmallnefs of the leaves, where a low hedge is wanted of the deciduous kind, this would not be an improper tree for the pur- pofe, either to be kept fheered, or fuffered to grow in its natural ftate. The bark of this fort is more fpotted than that of the common. The flowering horn- beam is the moft free fliooter of any of the forts ; and will arrive to be the highett, the common hornbeam only excepted. It will grow to be thirty qr forty feet high. The branches of this tree are lefs fpotted with greyifh fpots than any of the other forts. The leaves are very rough, of a dark-green colour, and are longer than the common fort. The property which the common hornbeam is poflefled of, of retaining its leaves all winter, does not belong to this fort, the leaves of which conftantly fall off" in the autumn with other deciduous trees. American hornbeam is a more elegant tree than any of the former forts. The branches are flender, covered with a brownifh fpeckled bark, "and are more fparingly fent forth than from any of the others. The leaves are oblong, pointed, and of a pahfli green, and are not nearly fo rough as the com- mon hornbeam, though the flowers and fruit are pro- duced in the fame manner. 2. The oftrya, or hop-hornbeam, a native of Italy and of Virginia. This is of taller growth than the eaftern kind. It will arrive to the height of twenty feet, or more. The leaves are -nearly the fize of the commoa CAR [ InuB common fort, and fome people admire this tree on ac- '■ count of the fingular appearance it makes with its feeds, before they begin to fall. There is a variety which grows to thirty feet high, (lioots freely, has long rough leaves like thofe of the elm, and longifh vellow-coloured flowers, called the Virginian Jlo'UJdnng hop-hornbeam. Propagation. The common hornbeam may be pro- pagated either by layering (at almoil any time of the year), or from feeds in the following manner : In the autumn the feeds will be ripe ; when, having gathered a fufficient quantity for the purpofe, let them be fpread upon a mat a few days to dry. After this, they ihould be fowa in the feminary-ground, in beds four feet wide, with an alley of about two feet, and from one to two Inches deep. In this bed they mud remain tiU the fecond fpring before thty make their appearance ; and all the fumincr they lie concealed, the weeds fliould conilantly be plucked up as foon as they peep ; for if tiiey are negletled, they will get fo ilrong, and the fibres of their roots will be fo far ftruck down' among the feeds, as to endanger the drawing many feeds out witlr them, on weeding the ground. After the young plants appear, they fliould conftantly be kept clear of weeds during the next fummer ; and if they were to. be now and then gently i-efreihed with water in dry weather, it would prove ferviceable to them. In the fpring following they may be taken out of thefe beds, and planted in the nurfery, in which fituation they may remain till they are of a fufficient fize to plant out for Itandards. The other forts are to be propagated by layers j for which purpofe a few plants for flools mull be pro- cured. The Itools of the eaftern hornbeam (hould be planted a yard, and the other forts a yard and a half or two yards afunder. After thefe plants have made fome young fhoots, they fliould be layei-ed in. the au- tumn, and by that time twelvemonth they will have llruck root ; at which time, or any time in the winter, or early in the fpring, they fliould be taken off", and planted in the nurfery-way, obfervlng always to brufh up the llool, that it may afford fine young ihoots for frefli layering by the autumn following. The diftance the plants fliould be allowed in the nurfery need be no more than one foot, in rows that are two feet afunder; and here they may ftand, with the ufual nurfery care of weeding and digging the rows in winter, until they are to be finally planted out ; though the Virginian hornbeam will frequently fend forth two flioots, which will feem to ftrive for maftery in tlie lead. When this is obferved, the weakeft fliould always be taken away, otherwife the tree will grow forked. CARPOBALSAM, in the Materia Medica, the fruit of the tree which yields the true oriental balfam. The carpobalfam is ufed in Egypt, according to Prof- per Alpinus, in all the intentions in which the balfam itfelf is applied : but the. only ufe the Europeans make of it is in Venice treacle and mithridiite ; and in thefe not a great deal, for cubebs and juniper-berries are generally fubftituted in its place. CARPOCRATIANS, a branch of the ancient Gnoftics, fo called from Carpocrates^ v/ho in the fe- cond century revived and improved upon the errors of -Simon Magus, Menandtr, Saturninus, and other 8i ] CAR Gnoftics. He owned, with them, one fole principle Carpolithi and father of all things, whofe name as well as nature Q^^jj^j.^ Vv'as unknown. The world, he taught, was created by 'j , angels, vailly inferior to the firfl; principle. He op- pofed the divinity of Jefus Chriil ; making him a mere man, begotten carnally on the body of Mary by Jo- feph, though pofleffed of uncommon gifts which fef him above other creatures. He indicated a commu- nity of women ; and taught, that the foul could not be purified, till it had committed all kinds of abomi- nations, making that a necelTary condition of perfec- feftion. Cx^RPOLITHI, or Fruit-stone Rocks of the Germans, are compofed of a kind of jafper, of the na-' ture of the amygdaloides, or almond-itones. Bertrand aflerts that the latter are thofe which appear to be compofed of elliptical pieces like petrified almonds, though in truth they are only fmall oblong pieces of calcareous Itone rounded by attrition, and fometimes. fmall mufcle-fliells connected by a flony concretion. The name of carpolithi, however, is given in general by writers on foffils to all forts of itony concretions that have any refeniblance to fruit of whatever kind. CARPUS, the wrift. See Anatomy, N° 53. CARR, a. kind of roUing throne, ufed in triumphs, and at the fplendid entries of princes. See Chariot. The word is from the ancient Gaulifli, or Celtic, Carr ; mentioned by Ccefar, in his commentaries, un- der the name Carrus. Plutarch relates,, that Camillus having entered Rome in triumph, mounted on a cari;. drawn by four white horfes, it was looked on as too haughty an innovation. Carr is alfo ufed for a kind of light open chariot. The carr, on medals, drawn either by horfes, liona,- or elephants, ufually fignifies either a triumph or an apotheofis : fometimes a procelfioh of the images of the gods at a folemn fuppHcation, and fometimes of thofe of fome illuilrious family at a funeral. The carr. covered, and drawn by mides, only fignifies a confe- cration, and the honour done any one of having his image carried at the games of the circus. See Con SECRATION, &C. CARRAC, or Carraca, a name given by the Por- tuguefe to the veflels they fend to Brafil and the Eafl;- Indies ; being very large, round built, and fitted for fight as well as bui'den. Their capacity lies in their depth, which is very extraordinary. They are nar- rower above than underneath, and have fometimes fe- ven or eight floors ; they cany about 2000 tons, and are capable of lodging 2000 men ; but of late they are little ufed. Formerly they were alfo ia ufe among the knights of Rhodes,, as well as among the Ge- noefe, and other Itahans. It is a cuilom among the Portuguefe, when the carracs returned from India, not to bring any boat or floop for the fervice of the fliip beyond the ifland of St Helena ; at which place they fink them on purpofe, in order to take from the crew all hopes or poffibihty of faving themfelves, in cafe of fliipwi-eck. CARRARA MARBLE, among our artificers, th^ name of a fpecies of white marble, which is called mar-' mor lunenfe, and Ugujirium by the ancients : it is dif- tinguiflied from the Parian, now called the ftatuary marble, bv being harder and lefs bright, CAE.' € A R T 18 Ca'ravelra CAIIRAVEIRA, a town of Turkey in Europe, „ II. , with a Greek archbifhop's fee. E. Long. 22. 25". N. Carrick. - ^ o > ■ ^ ^ Lat. 40. 27. CARRIAGE, a vehicle ferving to convey perfons, goods, merchandizes, and other things, from one place to another. For the conftroftion and mechanical principles of wheel-carriages, fee Mechanics. Carruge of a cannon, the frame or timber work on which it is mounted, ferving to point it for (hooting, or to carry it from one place to another. It is made of two planks of wood, commonly of one-half the Jength of the -gun, called the cheeks, and joined by three wooden tranfums, ftrengthened with three bolts cf iron. It is mounted on two wheels, but on a march has two fore-wheels with limbers added. The principal parts of a carriage are the cheeks, tranfums, 'bolts, plates, train, bands, bridge, bed, hooks, trun- nion holes, and capfquare. Block-CARRiAGK, a cart made on purpofe for carry- ing mortars and their beds from place to place. 'Truck-CARRiAGE, two fliort planks of wood, fnp- ported on two axle-trees, having four trucks of folid wood for carrying mortars or guns upon battery, where their own carriages cannot go. They are drawn by men. CARRICK, the fouthern divifion of the fhire of Ayr in Scotland. It borders on Galloway ; ftretches 32 miles in length ; and is a hilly counti7 fit for paf- -turage. The chief rivers are the Stench er and Gir- Tcn, both abounding with falmon ; here are alfo feve- ral lakes and forefts ; and the people on the coaft em- ploy themfelves in tlie herring-fifhery, though they have no harbour of any confequence. The only towns of this diftria are Bargeny and Maybole, two incon- - fiderable villages, yet the firft gave the title ( now ex- tinft) of baron to a branch of the Hamilton family. The prince of Wales, as prince of Scotland, is earl of Carrick. Carrick on the Sure, a town of Ireland, in the county of Tipperary and province of Munfter. W. Long. 7. J4. N. Lat. 52. 16. CARRJCK-Fergus, a town of Ireland, in the county of Antrim and province of Ulfter. It is a town and county in itlelf, and fends two members to parliament. It is very rich and populous, with a good harbour ; «nd is governed by a mayor, recorder , and fherifFs. — It has, however, been of far greater confequence than at yrefent, as appears from the mayor having been admi- Tal of a confiderable extent of coaft in the counties of Down and Antrim, and the corporation enjoying the cuftoms paid by all vcfTcls within thefe bounds, the creeks of Belfaft and Bangor excepted. This grant was repurchafed, and the cuftom-houfe transferred to Belfaft. — Here is the fkeleton of a fine houfe built by Lord Chicherter in the reign of James I. an old Go- thic church with many family monuments, and a very large old caftle. The town was formerly walled round, and fome part of the walls is ftill remaining entire. — Carrick-fergus is feated on a bay of the fame name in the Irifli channel ; and is noted for being the landing place of king William in 1690. Here alfo Thurot ir.ade a defcent in 1 759, took pofTeflion of the cattle, and car- tied away hoftages for the ranfom of the town ; but 2 ] GAR being foon after purfued by commodore Elliot, his three d^r r'^* fhips were taken, and he himfelf was killed. '"""^ CARRIER, is a perfon that carries goods for others for hire. A common carrier, having the charge and carriage of goods, is to anfwer for the fame, or the value, to the owner. And where goods are de- livered to a carrier, and he is robbed of them, he fhall be charged and anfwer for them, becaufe of the hire. If a common carrier who is offered his hire, and who has convenience, refufes to carry goods, he is liable to an aAion, in the fame manner as an 4nn -keeper who refufes to entertain a guefl;. See Assumpsit. One brought a box to a carrier, with a large fum oiJaaVt money, and the carrier demanded of the owner what was in it ; he anfwered, that it was filled with filks, and fuch like goods : upon which the carrier took it, and was robbed, and adjudged to make it good ; but a fpecial acceptance, as, provided there is no charge of money, would have excufed the carrier. — A perfon de- livered to a carrier's book-keeper two bags of money fealed up, to be carried from London to Exeter, and told him that it was L. 200, and took his receipt for the fame, with promife of delivery for 10 3. per cent. carriage and rifle : though it be proved that there was L. 400 in the bags, if the carrier be robbed, he fhall anfwer only for L. 20c, becaufe there was a particu- lar undertaking for that fum and no more ; and his re- ward, which makes him anfwerable, extends no farther. If a common carrier lofes goods which he is intrufled to carry, a fpecial aftion on the cafe lies againfl him, on the cuftom of the realm, and not trover ; and fo of a common carrier by boat- An acSlion will lie againtl a porter, carrier, or barge-man, upon his bare receipt of the goods, if they are loft through negligence, Alfo a lighter-man fpoiling goods he is to carry, by letting water come to them, aftion of the cafe liesagainll him, on the common cuftom. CARRiF.R-Pigeon, or courier-pigeon, a fort of .pigeon ufed, when properly trained, to be fent with letters from one place to another. See Columba. Though you carry thefe birds hood- winked, 20, i^o, nay, 60 or 100 miles, they will find their way in a very little time to the place where they were bred. They are trained to this fervice in Turkey and Pcrfia ; and are carried firft, while young, fhort flights of half a mile, afterwards more, till at length they will re- turn from the fartheft part of the kingdom. Every Baftiaw has a bafliet of thefe pigeons bred in the fera- glio, which, upon any emergent occafion, as an infur- reftion, or the like, he difpatches, with letters braced under their wings, to the fcraglio ; which proves a more fpeedy method, as well as a more fafe one, than any other ; he fends out more than one pigeon, however, for fear of accidents. Lithgow affurcs us, that one of thefe birds will carry a letter from Babylon to Aleppo, which is 30 days journey, in 48 hours. This is alio a very ancient pradlice ; Hirtiusand Brutus, at the fiege of Modena, held a correfpondence with one another by means of pigeons. And Ovid tells us, that Tauro- fthenes, by a pigeon ftained with purple, gave notice to his father of his viftory at the Olympic Games, fend- ing it to him at JEgim. In modern times, the moft noted were the pigeons of Aleppo, CAR Carnin. Aleppo, which ferved as courien at Alexandretta and Bagdad. But this ufe of them has been laid afide for the laft 30 or 40 years, becaufe the Curd robbers kill- ed the pigeons. The manner of fending advice by thetn was this : they took, pairs which had young ones, and carried them on horfeback to the place from whence they wifhed them to return, taking care to let them have a full view. When the news arrived, the cor- refpondent tied a billet to the pigeon's foot, and let her Iloofe. The bird, impatient to fee Its young, flew off Like lightning, and arrived at Aleppo in ten hours frons Alexandretta, and in two days from Bagdad. It was not difKcult for them to find thtir way back, lince Aleppo may be difcovered at an immenfe diftance. This pigeon has nothing peculiar in its form, except its noftrils, which, inftead of being fmooth and even, are fwelled and rough. C ARRON, a fmall but remarkable river in Scot- land, rifing about the middle of the Ifthmns between the friths of Forth and Clyde. Both its fource, and the place where it emptieth itfelf into the fea, are witKin the (hire of Stirling, which it divides Into two nearly equal parts. The whole length of its courfe, which is from weft to caft, is not above 14 miles. It falls into the frith of Forth about three miles to the north-eaft of Falkirk. The ftream thereof is but fmall, and fcarce deferves the notice of a traveller; yet there is no river in Scotland, and fewr in the whole ifland of Britain, whofe banks have been the fcene of fo many memorable tranfaftions. When the Roman empire was In all its glory, and had its eaftern "frontiers upon the Euphrates, the banks of Carron were its boundaries upon tbe north-weft ; for See /f/i/o-the wall of Antoninus*, which was raifed to mark the 'nus'sH^all.Vitnhs of that mighty empire, ftood in- the neighbour- hood of this river, and ran parallel to it for feveral miles. Near the middle of its courfe, in a pleafant valley, ftand two beautiful mounts, called the //ills of Duni- pacCf which are taken notice of by moft of the Scot- tifh hiilorians as monuments of great antiquity. The whole ftrudture of thefe mounts is of earth ; but they are not both of the fame form and dimenfions. The more eafterly one is perfectly round, refembllng an oven, and about fifty feet in height : And that this is an artificial work does not admit of the leaft doubt ; but we cannot affirm the lame, with equal certainty, of the other, though it has been generally fuppofed to be fo too. It bears no referablance to the eaftern one either in fhape or fize. At the foundation it is nearly of a triangular form ; but the fuperftrufture is quite irregular ; nor does the height thereof bear any proportion to the extent of its bafe. Thefe moimts are now planted with firs, which, with the parifh- church of Dunipace ftanding in the middle between them, and the river running hard by, give this valley a very romantic appearance. The common account given of thefe mounts is, that they were ere£led as monuments of a peace concluded in that place be- tween the Romans and the Caledonians, and that their name partakes of the language of both people ; Dun fignifying a hill in the old language of this ifland, and Fax " peace" in the language of Rome. The com- pound word, Dunipace, fignifies " the hills of peace." And we find in hiftory, that no lefs than three treaties [ "83 1 CAR of peace were, at different periods, entered Into between the Romans and Caledoniatvs ; the firft, by Severus, *" about the year 210 ; the fecond, foon after, by his fon Caracalla ; and the third, by the ufurper Caraufius, about the year 280 ; but of which of thofe treaties Dunipace is a monument, we do not pretend to deter- mine. If the concurring teftimony of hiftorians and. antiquaries did not agree in giving this original to thefe mounts, we would be tempted to conjefturc that they are fepulchral monuments. Human bones and urns have been difcovered in earthen fabrics of this kind in many parts of this ifland, and the little mounts or barrows, which are fcattered in great numbers about Stonhenge in Saliftury plain are generally fuppofed to have been the fepulchres of the ancient Britons. Sec Barrows. From the valley of Dunipace, the river runs for fome time In a deep and hollow channel, with fteep banks on both fides : here It pafTes by the foundation* of the ancient Roman bridge ; not far from which, as is generally thought, was the fcene of the memo- rable conference betwixt the Scottiih patriot William- Wallace and Robert Bruce, father to the king of that name, which firft opened the eyes of the latter to a juft view, both of his own true intereft and that of his country. After the river has left the village and bridge of Larbert, it foon comes up to another fmall valley, through the midft of which it has now worn out to itfelf a ftraight channel; whereas, in former ages, it had taken a confiderable compafs, as appears by the traft of the old bed, which Is ftill vifible. The high and circling banks upon the fouth-fide, give to this valley the appearance of a fpaclous bay ; and, according to the tradition of the country, there was once an harbour here : nor does the tradition feem altogether groundlefs ; pieces of broken anchors having been found here, and fome of them within the me- mory of people yet alive. The ftream-tides would ftill flow near the place, if they were not kept back by the dam-head built acrofs the river at Stenhoufe y and there is reafon to believe, that the frith flowed confiderably higher in former ages than it does at prefent. In the near neighbourhood of this valley, upon the fouth, ftand the ruins of ancient Camelon ; which, after it was abandoned by the Romans, was probably inhabited, for fome ages, by the natives of the country. Another ancient monument, called Arthur'^ Oven,, once ftood upon the banks of Carron ; but was, with a fpirit truly Gothic, entirely demolifiled about 40 years ago. The ccrner of a fmall inclofure between Stenhoufe and the Carron iron- works. Is pointed out as the place of its fituation. This Is generally fuppo- fed to have been a Roman work ; though it is not eafy to conceive what could be their motive for ereft- ing fuch a fabric, at fo great a diftance from any other of their works, and in a fpot which, at that time, muft have been very remote and unfrequented. The form of it is faid to have been perfe£tly round, and rifing perpendicular for fome yards at firft, but afterwards gradually contrafted, till it terminated in a narrow ori- fice at the top. Antiquaries are not agreed whether it had been a temple, or a trophy, or a raaufoleuai ; but the moft common opinion is, that it had been a temple, and,. Carron. CAR t 1B4 ] CAR Catron, and, Buchanan thinks, a tei)nple of Terminus. Heflor — V "™" ' Boetius fays, that there were benches of ftone all around it, upon the infide ; and that there had been a large Itone for facrificing upon, or an altar, upon the fouth fide. As Carron extends over the half of the ifthmus, and runs fo near the ancient boundaries of the Ro- man empire, the adjacent country fell naturally to be the fcene of many battles and rencounters. Hif- torians mention a bloody battle fought near this river between the Romans and the confederate army of the Scots and Pifts in the beginning of the 5th century. The fcenesof fome of Offian's poems were, in the opi- nion of the tranflator, upon the banks of this river. Here Fingal fought with Caracal, the fon of the king of the world, fuppofed to have been the fame with Caracalla the fon of the Roman emperor Severus. Here alfo young Ofcar, the fon of Offian, performed fome of his heroic exploits. Hereabout was the flream of Crona, celebrated in the ancient compo- litions of the Gaelic bard ; pofiibly that now called the water of Bonny, which runs in the neighbour- hood of the Roman wall, and difchargeth itfelf into Carron at Dunipace. In thofe poems, mention is made of a green vale upon the banks of this river, with a tomb ftanding in the middle of it, where young Ofcar's party and the warriors of Caros met. We only take notice of this as it ftrengthens the conjefture hazarded above, that the mounts of Du- nipace, efpecially the more eafterly of them, were fepulchral monuments. — About the diftance of half a mile from the river, and near the town of Falkirk, lies the field of that battle which was fought by Wil- liam Wallace and the Englifli in the beginning of the 14th century. It goes by the name of Graham's muirf from the valiant John Graham, who fell there, and •whofe grave-ftone is ftill to be feen in the church-yard of Falkirk. The river Carron, though it hath long fince ceafed to roll its ftream amidft the din of arms, ftill preferves its fame, by lending its aid to trade and manufaftures ; (fee the next article. ) — The river is navigable for fome miles near its mouth, and a confiderable trade is carried on upon it by fmall craft ; for tlie convenience of which, its channel has of lat« years been ftraightened and * See the ™uch fliortened, and the great Canal * has its entrance article Ca- from it. nal. Carron- Worh,zhrgc irGn foundery,two miles north from Falkirk in Scotland. They are conveniently fitu- ated on the banks of the Carron, three miles above its entry into the frith of Forth. Above 100 acres of land have been converted into rtfervoirs and pools, for ■water diverted from the river, by magnificent dams built about two miles above the works, which, after turning 1 8 large wheels for the feveral purpofes of the manu- fafture, falls into a tide-navigation that conveys their caftings to the fea. Thefe works are the greateft of the kind in Europe, and were eftabHftied in i 760. At prefent, the build- ings are of vaft extent ; and the machinery, conftruc- ted by Mr Smeaton, is the firft in Britain, both in elegance and correftnefs : there are 1 600 men em- ployed, to whom is paid weekly above 650 1. Sterling ; which has greatly enriched the adjoining country : 65CO tons of iron are fmelted annually from the N° 65. 2 mineral with pit-coal, and caft ifito cannon, cylin- Carrot ders, tffc. — In the founding of cannon, thefe works II have lately arrived at fuch perfedlion, that they make Carrucate. above 5000 pieces a-year, many of which are ex- ported to foreign ftatcs ; and their guns of neiv coti" Jiru8ion are the lighteft and neateft now in ufe, not excepting brafs guns; the 32 pounder ftiip-gun weighing 42 hundred-weight, the 6 pounder 8 hun- dred-weight and one half, and the other calibers in proportion. The prefent proprietors are a chartered company, with a capital of 150,0001. Sterling, a common feal, iffc. but their flock is coHfine- them. The common fable is, that the Pha^niciaas im^ pofed upon the Africans in the following' manner : They defired, for their intended fettlement, only as much ground as an ox's hide would encompafs. Tliis requeft the Africans laughed at : but were furprifed, \vhen, upon their granting it, they faw Ehfa cut the hide into the fmallelt fhreds, by which means it fur- rounded a large territory ; ia which Ihe built the cita- 3 del called B^jvfcu The learned, however, are now un- ^"'^1 L^" animousfa. CAR [ Carthage, animous in exploding this fable ; and it is certain that ^-"•"y-— the Carthaginians for many years paid an annual tri- bute to the Africans for the ground they poffeffed. The new city foon became populous and flourifhing, by the acceffion of the neighbouring Africans, who came thither at firft with a view of traiiic. In a fhort time it became fo confiderable, that Jarias, a neigch- i88 1 e A R ^ Carthaginians entered into a treaty with the Romans. Carthagre. It related chiefly to matters of navigation and com- v— merce. From it we learn, that the whole ifland of p. Sardinia, and part of Sicily, were then fubje£l ^o 1,^^^'^^^*' Carthage ; that they were very well acquainted with Cartilage the coails of Italy, and had made fome attempts up- and Rome^ on them before this time ; and that, even at this early bouring prince, thought of making himfelf mafter of period, a fpirit of jealouiy had taken place between it without any effufion of blood. In order to this, he defired that an embafiy of ten of the moil noble Car- thaginians might be fent him; and, upon their arrival, propofed to them a marriage with Dido, threatening war in cafe of a refufal. The ambaffadors, being afraid to deliver this melfage, told the queen that Jarbas defired fome perfon might be fent him who was capable of civilizing his Africans ; but that there was no pofTibility of finding any of her fubjefts who would leave his relations for the converfation of fuch barbarians. For this they were reprimanded by the queen ; who told them that the)'- ought to be afhamed the two republics. Some time near this period, the Carthaginians had a mind to difcontinue the tribute they had hitherto paid the Africans for the ground on which their city ftood. But, notwithftanding all their power, they were at prefent unfuccefsful j and at lafl; were obfiged to conclude a peace, one of the ar- ticles of which was, that the tribute fliould be conti- nued. By degrees the Carthaginians extended their power -;i^.;iy jpy^^ overall the iflands in the Mediterranean, Sicily ex- ile J by the cepted ; and for the entii-e conquefl: of this, they made CarthagUu- vaft preparations, about 480 years before Chrift. Their ^"^* of refu'fing to live in any manner for the benefit of army confifted of 300,000 men ;^ their fieet^ was com 4 She kills hcrfelf. 5- Spanifh mines of vaft fervice to the Car- thfiginians. their country. Upon this, they informed her of the true nature of their meffage from Jarbas ; and that, according to her own decifion, fhe ought to facrifice herfelf for the good of her country. The unhappy queen, rather than fubmit to be the wife of fuch a barbarian, caufed a funeral pile to be erefted, and put an end to her life with a dagger. This is Juftin's account of the death of Queen Di- do, and is the moll probable ; Virgil's ftory of her amour with jEneas,. being looked upon as fabulous, even in the days of Macrobius, as we are informed by that hiftorian. How long monarchical government continued in Carthage, or what happened to this ilate in its infancy, we are altogether ignorant, by reafon of the Punic Archives being defl;royed by the Romans; fo that there is a chafm in the Carthaginian hiftory for above 300 years. It, however, appears, that from the very beginning, the Carthaginians applied them- felves to maritime affairs, and were formidable by fea in the time of Cyrus and Cambyfes. From Diodorus Siculus and Juftin, it appears, that the principal fiip- port of the Carthaginians were the mines of Spain, in which country they feem to have eftabhfhed themfelves very early. By means of the riches drawn from thefe mines, they were enabled to equip fuch formidable fleets as we are told they fitted out in the time of Cyrus or Cambyfes. Juftin infinuates, that the firft Carthaginian fettlement in Spain happened when th« city of Gades, now Cadis, was but of late ftanding, or even in its infancy. The Spaniards finding this new colony begin to flourifli, attacked it with a numerous army, infcmuch that the inhabitants were obliged to call in the Carthaginians to their aid. The latter pofed of upwards of 2000 men of war, and 3*000 ti-anf- ports ; and with fuch an immenfe armament, they made no doubt of conqueiing the whole ifland in a fingle campaign. In this, however, they found them felves miferably deceived. Hamilcar their general having landed his numerous forces, invefted Himera, a city of confiderable importance. He carried on his attacks with the greateft affiduity ; but was at laft at- tacked in his trenches by Gelon and Theron, the ty- rants of Syracufe and Agrigentum, who gave the Carthaginians one of the greateft overtlu-ows mention- g ed in hiftory. An hundred and fifty thoufand were They are killed in the battle and purfuit, and all the reft taken utterly de-f prifoners ; fo that of fo mighty an army, not a fingle ^royed. perfon efcaped. Of the 2000 fliips of war and 3000 tranfports, of v\'hich the Carthaginian fleet confifted, eight ftiips only, which then happened to be out at fea, made their efcape : thefe immediately fet fail for Carthage ; but were all caft away, and every foid periflied, except a few who were faved in a fmall boat, and at laft reached Carthage with the difmal news of the total lofs of the fleet and army. No words can exprefs the confternation of the Carthaginians upon receiving the news of fo terrible a difafter. Ambaf- . fadors were immediately difpatched to Sicily, with orders to conclude a peace upon any terms. They put to fea without delay ; and landing at Syracufe, threw themfelves at the conqueror's feet. They beg- pg^^.^^!^ ged Gelon, with many tears, to receive their city into eluded, favour, and grant them ^ peace on whatever terms he ftiould choofe to prefcribe. He granted their requeft upon condition that Carthage fiiould pay him 2000 talents of filver to defray the expences of the war ; that very readily granted their requeft, and not only repul- they fliould build two temples, where the articles of fed the Spaniards, but made themfelves maftcrs of al- the treaty fliould be lodged and kept as facred ; and moft the whole province in which their new city ftood. that for the future they fliould abftain from human fa- By this fuccefs, they were encouraged to attempt the crifices. Tliis was not thought a dear purchafe of a conqueft of the whole country: but having to do with peace for which there was fuch occafion ; and to fliow very warUke nations, they could not pufli their con, their gratitude for Gelon's moderation, the Cartha- quefts to any great length at firft; and it appears from ginians-comphmentedhis wife Demarata with a crowa the accounts of Livy and Polybius, that the greateft of gold worth 100 talents. part of Spain remained unfubdued till the times of From this time we find little mention of the Car- Hamilcar, Afdrubal, and Hannibal. thaginians for 70 years. Some time during this pe- About 503 years before the birth of Chrift, the riod, however, they had greatly extended their do-. ■ ' . minions CAR ^ 13, llmporium minions in Africa, and likewife Hiaken off the tribute which gave them fo much uneafinefs. They had warm difputes with the inhabitants of Cyrene the ca- pital of Cyrenaica, about a regulation of the limits of their refpeftive territories. The confequence of thefe difputes was a war, which reduced both nations fo low, that they agreed firft to a ceiTation of arms, and then to a peace. At laft it was agreed, that each ftate fhould appoint two commifTaries, who fhould fet out from their refpeftive cities on the fame day, and that the fpot on which they met fhould be the boundary of both ftates. In confequence of this, two brothers called Ph'iUni were fent out from Car- thage, who advanced with great celerity, while thofe from Cyrene were much more flow in their motions. Whether this proceeded from accident or defign, or perfidy, we are not certainly informed ; but, be this as it will, the Cyrene^ms finding themlelves greatly cutftripped by the Philasni, accufed them of breach of faith, afferting ihat they had fet out before the time appointed, and confequently that the convention between their principals was broken. The Philaeni defired them to propofe fome expedient whereby their differences might be accommodated ; promifing to fubmit to it, whatever it might be. The Cyreneans then propofcd, either that the PhilsenI fhould retire from the place where they were, or that they fhould be buried alive upon the fpot. With this laft condition the brothers immediately complied, and by their death gained a large extent of territory to their country. The Carthaginians ever after celebrated this as a mofl brave and heroic aftion ; paid them divine honours ; and endeavoured to immortalize their names by ereA- ing two altars there, with fuitable infcriptions upon them. About the year before Chrift 412, fome difputes happening between the Egeflines and Selinuntines, inhabitants of two cities in Sicily, the former called in the Carthaginians to their afliflance ; and this occa- fioned a new invafion of Sicily by that nation. Great prepaiations were made for this war ; Hannibal, whom they had appointed general, was empowered to raife an army equal to the undertaking, and equip a fuitable fleet. They alfo appointed certain funds for defraying all the expences of the war, intending to ex- ert their whole force to reduce the ifland under their fubjeftion. The Carthaginian general having landed his forces, 189 ] CAR After the reduftion of Selinus, Hannibal laid fiegc Carthage, to Himera ; that city he defired above all things to be- "v~— ^ come mailer of, that he might revenge the death of 14 nc! Seljrius immediately marched for Selinus. In his way he took Emporium, a town fituated on the river Mazara ; and having arrived at Selinus, he immediately invcfled it. The befieged made a very vigorous defence ; but at lail the city was taken by florm, and the inhabitants were treated with the utmofl cruelty. All were mal- facred by thefavage conquerors, except the women who fled to the temples ; and thefe efcaped, not through the merciful difpofition of the Carthaginians, but becaufe they were afraid, thati f driven to defpair they would fet fire to the temples, and by that means eonfumethe treafure they expedlcd to find in thofe places. Six- teen thoufand were maffacred ; 2250 efcaped to Agii- gentum ; and the women and children, about 5C00 in number, were carried away captives. At the fame time the temples were plundered, and the city raft d to the ground. »5 Agrigcn- his grandfather Hamilcar, who had been flain before it by Gelon. His troops, fiufned with their late fuc- cefs, behaved with undaunted courage ; but finding his battering engines not to anfwer his purpofe fufficient- ly, he undermined the wall, fupporting it with large beams of timber, to which he afterwards fet lire, and thus laid part of it flat on the ground. Notwithftand- ing thig advantage, however, the Carthaginians were feveral times repulfed with great flaughtcr ; but at laft they became mafters of the place, and treated it in the fame manner as they had done Selinus. After this, .. Hannibal, difmiffing his Sicilian and Italian allies, re- turned to Africa. Trie Carthaginians were now fo much elated, that they meditated the reduftion of the whole ifland. But as the age and infirmities of Hannibal rendered him incapable of commanding the forces alone, they joined in commillion with him Imilcar the fon of Hanno, one of the fame family. On the landing of the Carthaginian army, all Sicily was alarmed, and the principal cities put themfelves Into the beft ftate of defence they were able. The Carthaginians im- mediately marched to Agrigentum, and began to bat- turn befie»- ter the walls with great fury. The befieged, how-E^^« ever, defended themfelves with incredible refolution, in a fally burnt all the machines ralfed agalnfl their city, and repulfed the enemy with great flaughter. The Syracuiians in the mean time, being alarmed at the danger of Agrigentum, fent an army to its re- lief. On their approach they were immediately at- tacked by the Carthaginians ; but after a fharp dif- pute the latter were defeated, and forced to fly to the. very walls of Agrigentum, with the lofs of 6000 men. Had the Agrlgentine commanders now fallied out, and fallen upon the fugitives,, in all probability the Car- thaginian army muft have been deftroyed ; but either through fear or corruption, they refufed to flir out of j^, the place, and this occafioned the lofs of it. Immenfe And taken*:, booty was found in the city ; and the Carthaginians behaved with their ufual cruelty, putting ail the inha- bitants to the fword, not excepting even thofe who had fled to the temples. The next attempt of the Carthaginians was defign- ed agalnfl the city of Gela : but the Geleans, being greatly alarmed, implored the protection of Syracufe ; and, at their lequefl, Dionyfius was fent to afliil them with 2000 foot and 400 horfe. The Geleans were' fo well fatisfied with his condudl, that they treated.-, him with the highefl; marks of diilinftlon ; they even, fent ambafladors to Syracufe to return thanks for the^ important fervices done them by fendirig him thi- ther ; and foon after he was appointed generaliflimo of the Syracufian forces and thofe of their allies agalnfl the Carthaginians. In the mean time Imilcar, having rafed the city of Agrigentum, made an incurfion into the territories of Gela and Comarina ; which having ravaged in a dreadful manner, he carried off fuch immenfe quantity of plunder, as filled his whole camp. He then marched agalnfl the city : but thou?rh «^ , V /- ^ , . -i-cc 1 r •(- 1 1 • ^ ° Gela belies - It was but mditierently tortihed, he met with a veryg^;^^ vigorous rcfiflance ; and the place held out for a long time without receiving any affiftance from .its allies, . 4, At. C A R [ 190 ] CAR bitants 19 Peace con eluded. earthage. At lad DIonyfius came to its affiftance with an army of 50,000 foot and 1 ooo hprfe. With thefe he at- tacked the Carthaginian camp, but was repulfed with great lofs ; after which, he called a council of war, the refult of whofedeliberationswas, that fmce theenemy was fo much fnperior to them in ftrength, it would be high- ly imprudent to put all to the iffue of a battle; and therefore, that the inhabitants fhould be perfuaded to abandon the country, as the only means of faving their lives. In confequence of this, a trumpet was fent to Imilcar to defire a ceHation of arms till the next day, in order, as was pretended, to bury the dead, but in jg reality to give the people of Gela an opportunity of Abandoried making their efcapc. Towards the beginning of the hy its ii ha- night the bulk of the citizens left the plate ; and he hi mfelf with the army followed them about midnight. To amufe the enemy, he left 2000 of his light arm- ed troops behind him, commanding them to make fires all night, and fet up loud fliouts as though the army Hill remained in town. At day -break thefe took the fame route as their companions, and purfued their march with great celerity. The Carthaginians finding the city deferted by the greateft part of its inhabitants, immediately entered it, putting to death all who had remained ; after which, Imilcar having thoroughly plundered it, moved towards Camarina. The inhabitants of this city had been like wife drawn oiF by Dionyaus, and it underwent the fame fate with Gcla. Notwiihftanding thefe fuccelTes, however, Imilcar finding his army greatly weakened, partly by the ca- fualties of war, and partly by a plague which broke out in it, fent a herald to Syracufe to offer terms of peace. His unexpeiled arrival was very agreeable to the Syracufians, and a peace was immediately con- cluded upon the following terms, viz. That the Car- thaginians, btfidcs their ancient acquifitions in Sicily, fhould Hill poflefs the countries of the Silicani, the Se- linuntines, the Himereans, and Agrigentlnes ; that the people of Gela and Camarina fiiould be permitted to refide in their refpeftlve cities, which yet (hould be difmantled, upon their paying an annual tribute to the Carthaginians ; that all the other Sicilians fhould preferve their independency except the Syracufians, who (hould continue in fubjedion to DIonyfius. The tyrant of Syracufe, however^, had concluded breaks'the ^^'^ peace with no other view than to gain time, and treaty. to put himfelf in a condition to attack the Cartha- ginian territories with greater force. Having ac- jcomplinied this, he acquainted the Syarcufians with bis dtfign, and they immediately approved of it; upon which, he gave up to the fury of the populace the per- fons and poffcfiions of the Carthaginians who relided in Syracufe, and traded there on the faith of treaties. As there were many ot their fliips at that time in the harbour, laden with cargoes of great value, the people immediately plundered them; and, not content with this, ranfacked all their houfes in a moll outrageous ■manner. This exainple was followed throughout the whole Ifland; and in the mean time' Dionyfius dif- patched a herald to Carthage with a letter to the fe- nate and people, telling them, that if they did not im mediately withdraw tlieir garrifons horn all the Greek cities in Sicily, the people of Syracufe would treat them .as enemies. With this demand, however, he did not al- DIonyfius low them to comply ; for without waiting for any an- cartilages fwer from Carthage, he advanced with his army to — — v"" Mount Eryx, near which flood the city of Motya, a Carthaginian colony of great importance, and this he immediately invcfted. But foon after, leaving his bro- ther Leptines to carry on the attacks, he himfelf went with the greatell part of his forces to reduce the cities In alliance with the Carthaginians. He dellroyed their territories with fire and fvvord, cut down all their trees ; and then he fat down before Egella and Entella, moil of the other towns having opened their gates at his approach i but thefe baffling his utmoft efforts, he returned to Motya, and pulhed on the iiege of that place with the utmoll vigour. The Cartha.ginians, in the mean time, though alarm.- ed at the meffage fent them by Dionyfius, and though reduced to a miferable fituation by the plague which had broke out in their city, did not defpond, but fent officers to Europe, with conliderable fums, to raife troops with the utmoll diligence. Ten gallies were alfo fent from Carthage to dellroy all ih; fiiips that were found ^^.■"^^"H^'f^ in the harbour of Syracufe. The admiral, according fl-^Q^ej^^ to his orders, entered the harbour in the night, with- out being difcerned by the enemy ; and having funk moil of the fliips he found there, returned without the lofs of a man. All this vi'hile the Motyans defended themfelver with , . LM u • • J r ^Motyata-; incredible vigour; while their enemies, defirous orj^^„^ytijQ revenging the cruelties exercifed upon their country- Greeks, men by the Carthaginians, fought like lions. At laft the place was taken by ftorm, and the Greek foldiers began a general maffacre. For feme time Dionyfius was not able to reftrain their fury : but at laft he proclaimed that the Motyans Oiould fly to the Greek temples ; which they accordingly did, and a fiop was put to the llaughter ; but the ioldlers took care tho- roughly toplunder the tov>'n, in which they found a great treafure. The following fpring, Dionyfius Invaded the Cartha- ginian territories, and made an attempt upon Egelle ; but here he was again difappointed. The Carthagi- nians were greatly alarmed at his progrefs ; but, next year, notwithftauding a confiderable lofs fuilalned in a fea-fight with Leptines, Himilco their general land- ed a powerful aimy at Panormus, feized upon Eryx, and then advancing towards Motya, made himfelf ma- tter of it, before Dionyfius could fend any forces to its relief. He next advanced to MelTana, which he iike- wile befieged and took ; after which moil of the Siculi revolted from Dionyfius, Notwithllanding this defection, Dionyfius, hi^di^g Crct^k' de his forces lliU amount to 30,000 foot and 3000 horle, feated at Ita advanced ;igainil tlie enemy. At the fame lime, Eep-by iheCai tines was feut with the Svraculian fleet againll that of '^'-S""^"*' the Carthaginians, but with pofitive orders not to break the line of battle upon any account whatever. But, notwithilanding thefe orders, he thought proper to divide his fleet, and the confequence of this was a total defeat; above 100 of the Syracufian galleys being funk or taken, and[ 20, Ooo of their men killed In the battle or in the purfuit. Dionyfius difheartened bv this , misfortune, returned with his army to Syracufe, being [^^.-j^^^^.j |,y afi aid that the Carthaginian fleet might become ma- thgC'ai thi- Hers of that city, if he ihould advance to fight the land army, Himilco did not fail immediately ;o invell the 6 capital ; CAR [ I ?arthage, capital ; and had certainly become mafter of it, and confequeiuly of the whole ifland, had not a moft ma- lignant pertilence obliged him to defift from all further operations. This dreadful malady made great havock among his forces both by fea and land ; and to com- plete his misfortunes, Dionyfius attacked him unexpec- tedly, totally ruined his fleet, and made himlelf malter of h is camp. H imilco finding hinifclf altogether unable to faflain another attack, was obliged to come to a private agreement with Dionyfius ; who for 300 talents con- fentcd to let him efcape to Africa, with the fliattered remains of his fleet and army. The unfortunate ge- neral arrived at Carthage, clad in mean and fordid attire, whfre he was niet by a great number of peo- ple bewni]ing their fad and inaufpicious fortune. Hi- milco joined them in their lamentations; and being unable to furvive his misfortunes, put an end to his own life. He had left Mago in Sicily, to take care of the Carthaginian interelts in the heft manner he could. Tn order to this, Mago treated all the Sicilians fubjeft to Carthage with the grcateft humanity ; and having received a coufiderable number of foldiers from Africa, he at laft fotmed an army with which he ventured a battle : in this he was defeated, and driven out of the field, with the lofs of 800 men ; which obliged him to defift from farther attempts of that nature. Notwithftanding all thefe terrible difafters, the Car- thaginians could not forbear making new attempts up- on the ifland of Sicily ; and about the year before Chriifl: 392, Maoo landed in it with an army of 80,000 men. This attempt, however, was attended with no better fuccefs than before ; Dionyfius found means to reduce him to fuch llraits for want of provifions, that he was obliged to fue for peace. This continued for nine years, ?.t the end of which the war was renewed with various fuccefs. It continued with little interrup- tion till the year before Chrift 367, when, the Syra- cufian (late being rent by civil diflentions, the Car- thaginians thought it a proper time to exert them- ftlrcs, in order to become mafters of the whole ifland. They fitted out a great fleet, and entered into alliance with Icetas, tyrant of Leontini, wlio pretended to have taken Syracufe under his proteftion. By this treaty, the two powers engaged to affifl: each other, in order to expel Dionyfius II. after which they were to divide racufians the ifland between them. The Syracufians applied for ifted by fuccours to the Corinthians; and they readily fent them a body of troops under the command of Timo- leon an experienced general. By a fl^ratagem, h.^ got his forces landed at Taurominiiim. The whole of them did not exceed 1200 in number: yet with thefe he marched againft Icetas, who was at the head of 5(^00 men ; his army he furprifed at fup- per, put 300 of them- to the fword, and took 600 prifoners. He then marched to Syracufe, and broke into one part of the town before the enemy had any notice of his approach : here he took poft, and defend- ed himfelf with fuch refolution, that he could not be diflodged by the united power of Icetas and the Car- thaginians. In this place he remained for fome time, in expec- ^, ,j. ;j^l_tation of a reinforcement from Corinth; till the arri- i uurairal. val of which, he did i.ot judge it pradticabie to extend 27 -2S iliih can- ( of the 91 ! CAR his Conquefls.—The Carthaginians being apprifed that Carthage the Corinthian fuccours were detained by tempeftuous ^ weather at Thurium, polled a flirong fquadron, under Hanno their admiral, to intercept them in their paf- fage to Sioily. But that commander, not imagining the Corinthians would attempt a paffage to Sicily in fuch a ftormy feafon, left his fl:ation at Thurium, and ordering his feamen to crown themfelves with garlands, and adorn their veflels with bucklers both of the Greek and Carthaginian form, failed to Syracufe in a triumph- ant manner. Upon his arrival there, he gave the troops in the citadel to underftand, that he had taken the fuc- cours Timoleon expefted, thinking by this means to intimidate them to furrender. But, while he thus trifled away his time, the Corinthians marched with great expedition to Rhcgium, and, taking the advan- tage of a gentle breeze, were eafily wafted over into Sicily. Mago, the Carthaginian general, was no fooner Cowardice informed of the arrival of this reinforcement, than he of Mago. was llruck with terror, though the whole Corinthian army did not exceed 4000 men ; and, foon after, fear- ing a revolt of his mercenaries, he weighed anchor, in fpite of all the rcmonftrances of Icetas, and fet fail for Atrica. Here he no fooner arrived, than, overcome with grief and fliame for his unparalleled cowardice, he laid violent hands on himfelf. His body was hung up- on a gallows or crofs, in order to deter fucceeding ge- nerals from forfeiting their honour in fo flagrant a man- ner. _ 30 After the flight of Mago, Timoleon carried all be- Exploits of fore him. He obliged Icetas to renounce his alliance '"i"l<-'o"- with the ftate of Carthage, and even depofed him, and continued his mihtary preparations with the greateft vigour. On the other hand, the Carthaginians pre- pared for the enfuing campaign with the greatefl; ala- crity. An army of 70,000 men was fent over, with a fleet of 200 fliips of war, and 1000 tranfports laden with warlike engines, armed chariots, horfcs, and all other forts of provifions. This immenfe multitude, however, was overthrown on the banks of the Crime- fus by Timoleon : 10,000 were left dead on the field of battle ; and of thefe, above 3000 were native Car- thaginians of the befl families in the city. Above 15,000 were taken prifoners ; rail their baggage and provifions, with 200 chariots, 1000 coats of mail, and 10,000 fliields, fell into Timoleon's hands. The fpoil, which confifl;ed chiefly of gold and filver, was- fo im- menfe, that the whole Sicilian army was three days in collefting it and fliripping the flain. After this fignal victory, he left his mercenary forces upon the frontiers of the enemy, to plunder and ravage the countrv ; while he himfelf returned to Syracufe with the reft; of his army,, where he v/as received with the greateft de- raonftratious of joy. . Soon after, Icetas, grown weary of his private ftation, concluded a new peace with the Carthaginians ; and, having aflerabled an army, ven- - tured an engagement with Timoleon : but in this he M'as utterly defeated ; and himfelf, with Eupolemus his fon, and Euthymus general of his horfe, were brought bound to Timokon by their own foldiers. The two firft were immediately executed as tyrants and traitors, and the laft murdered in cold blood ; Ice- tas's wives and daughters were likewife cruelly put to death after a public trial. In a fliort time after, Ma- mercus, another of the Carthaginian confederates, was CAR [ ] CAR 3» War re- newed. Carthage, overthrown by Timoleon, with the \o(s of 2000 men. ' Thefe misfortunes induced the Carthaginians to con- Pcacc'con- elude a peace on the following terms : That all the eluded. Greek cities (hould be fet free ; that the river Halycus fhould be the boundaiy between the territories of both parties ; that the natives of the cities fubjeft to the Carthaginians fliould be allowed to withdraw, if they pleafed, to Syracufe, or its dependencies, with their families and efFefts ; and laftly, that Carthage ftiould not, for the future, give any affiftance to the remain- ing tyrants againft Syracufe. About 316 years before Chrift, we find the Car- thaginians engaged in another bloody war with the Sicilians, on the following occaiion. Sofiilratus, who had ufurped the fupreme authority at Syracufe, having been forced by Agathocles to raife the fiege of Rhe- gium, retm-ned with his fliattered ti-oops to Sicily. But foon after this unfuccefsful expedition, he was ob- liged to abdicate the fovereignty and quit Syracufe. VVith him were expelled above 600 of the principal citizens, who were fufpefted of having formed a de- fign to overturn the plan of government which then prevailed in the city. As Sofiftratus and the exiles thought themfelves ill treated, they had recourfe to the Carthaginians, who readily efpoufed their caufe. Hereupon the Syracufians having recalled Agathocles, who had before been banifhedby Sofiftratus, appointed him commander in chief of all their forces, principally on account of the known averfion he bore that tyrant. The war, however, did not then continue long ; for Sofiftratus and the exiles were quickly received again into the city, and peace was concluded with Carthage: the people of Syracufe, however, finding that Aga- thocles wanted to make himfelf abfolute, exafted an oath from him, that he would do nothing to the pre- Apathocles judice of the democracy. But, notwithftanding this raifes him- oath, Agathocles purfued his purpcfe, and by a ge- neral maflacre of the principal citizens of Syracufe raifed himfelf to the throne. For fome tim.e he was obliged to keep the peace he had concluded with Car- thage ; hut |at laft finding his authority eftabliflaed, and that his fubjefts were ready to fecond his ambiti- ous defigns, he paid no regard to his treaties, but im- mediately made war on the neighbouring ftates, which he had exprefsly agreed not to do, and then carried his arms into the very heart of the ifland. In thefe expeditions he was attended with fuch fuccefs, that in two years time he brought into-fubjedlion all the Greek part of Sicily. This being accomplifiied, he committed great devaftations in the Carthaginian ter- ritories, their general Hamilcar not offering to give him the leaft difturbance. This perfidious conduft greatly incenfed the people of thofe driftri£ls againft Hamilcar, whom they accufed before the fenate. He died, however, in Sicily ; and Hamilcar the fon of Gifco was appointed to fucceed him In the command of the forces. The laft placQ that held out againft Agathocles was Meffana, whither all the Syracufian exiles had retired. Pafiphllus, Agathocles's general, found means to cajole the inhabitants into a treaty ; which Agathocles, according to cuftom, paid no re- gard to, but, as foon as he wa§ in poffeffion of the town, cut off all thofe who had oppofed his govern- ment. For, as he intended to profecute the war with ■the utmoft vigour againft Carthage, he thought it a N°65. 33 felf to the ■throne of -Syracufe. icis He iBV.idci point of good policy to deftroy as many of his Sicilian Caitiiagai enemies as pofiible. 1 The Carthaginians in the mean time having landed ^^^^^^^^ { a powerful arnvy in Sicil)'-, an engagement foon enfued, in which Agathocles was defeated with the lofs of thaginians, 7000 men. After this defeat he was obhged to fliut and befie- himfelf up in Syracufe, which the Carthaginians im- f^^^^^ mediately invefted, and moft of the Greek ftates in the ifland fubmitted to them. Agathocles feeing himfelf ftrlpped of almoft all his dominions, and his capital itfclf in danger of falling into the hands of the enemy, formed a defign which, were it not attefted by writers of undoubted authority, would feem abfolutely incredible. This was no than to transfer the v/ar into Africa, and lay fiege to /Vfnca. the enemy's capital, at a time when he himfelf was befieged, and only one city left to him in all Sicily. Before he departed, however, he made all the necef- fary pteparations for the defence of the place, and ap- pointed his brother Antandrus governor of it. He alfo gave permiflion to all who were not willing to ftand the fatigues of a fiege to retire out of the city. Many of the pilncipal citizens, Juftin fays 1600, accepted of this offer ; but they were no fooner got out of the place, than they were cut oft by parties pofted on the road for that purpofe. Having feized upon their eftates^ Agathocles raifed a coniiderable fum, which was intended in fome mealuie to defray the expence of the expedition ; however, he carried with him only 50 talents to fupply his prefent wants, being well af- fured that he fhould find in the enemy's country what- ever was neceffary for his fubfiitence. As the Cartha- ginians had a much fuperior fleet, they for fom.e time kept the mouth of the harbour blocked up : but at laft a fair opportunity off"ered ; and Agathocles holft- ing fail, by the activity of his rowers foon got clear both of the port and city of Syracufe. The Cartha- ginians purfued him with ail pofiible expedition ; but, notwithftanding their utmoft efforts, Agathocles got his troops landed with very little oppofition. Soon after his forces were landed, Agathocles burnt He burn! his fleet, probably that his foldlers might behave with his ficet, the greater refolutlon, as they faw no pofiibllity of flying from their danger. He firft advanced to a place called the Great City, This, after a feeble refiftance, he took and plundered. From hence he marched to Tunis, which furrendered on the firft furamons ; and Agathocles levelled both places with the ground. The Carthaginians were at firft thrown into the greateft confternation ; but foon recoveving themfelves, the citizens took up arms with fo much alacrity, that in a few days they had on foot an army of 40,000 foot and 1000 horfe, with 2000 armed chariots. The 37 command of this army they entrufted to Hanno and C^arthagu Bomilcar, two generals between whom there fublifted a great animofity. This occafioned the defeat of their whole army with the lofs of their camp, though all the forces of Agathocles did not exceed 14,000 in number. Among other rich fpoils the conqueror found many chariots of curious workmanfliip, which carried 20,000 pair of fetters and manacles that the enemy had provided for the Sicilian prifoners. After this de- Their m feat, the Carthaginians, fuppofing themfelves to have thod of fallen under the difpleafure of their deities on account ^^^j'^^^"^ of their neglefting to facrifice children of noble fami- ^^^^^ lies GAR [ lies to them, refolved to expiate this guilt. Accord iiijgly 200 children of the firft rank were facrificed to thieir bloody gods, befides 300 other perfons who vo- himtariJy offered themfelves to pacify the wrath of thefe deities. After thefe expiations, Hamilcar was recalled from Siicily. When the picffengers arrived, Hamilcar com- manded them not once to mention the viftory of A- ga.thoclcs ; but, on the contrary, to give out am.ong th e troops that he had been entirely defeated, his forces all cut off, and his fleet deftroyed by the Carthagini- an.s. This threw the Syracufians into the utmoft de- fpair ; however, one Eurymnon, an Etohan, prevailed up)on Antandrus, not to confent to a capitulation, but to Hand a general affault. Hamilcar being informed of this, prepared his battering engines, and made all thie neceffary preparations to ilorm the town without delay. But while matters remamed in this fituation, a galley, which Agathocles had caufed to be built im- mediately after the battle, got into the harbour of Sy- racufe, and acquainted the inhabitants with the cer- tainty of Agathocles's victory. Hamilcar obferving that the garrifon flocked down to the port on this oc- cafion, and expefting to find the walls unguarded, or- dered his foldiers to ere6l fcaling-ladders, and begin the intended affault. The enemy having left the ram- parts quite expofed, the Carthaginians mounted them without being difcerned, and had almoft poffeffed them- felves of an entire part lying between two towers, when the patrol difcovered them. Upon this a warm difpute enfued; but at laft the Carthaginians were repulfed with lofs. Hamilcar, therefore, finding it in vain to continue the fiege after fuch glad tidings had reftored life and foul to the Syracufians, drew off his forces, and fent a detachment of 5000 men to reinforce the troops in Africa. He ftlU entertained hopes, how- ever, that he might oblige Agathocles to quit Africa, and return to the defence of his own dominions. He fpent fome time in making himfelf mafter of fuch ci- ties as fided with the Syracufians ; and after having brought all their allies under fubjeftion, returned again to Syracufe, hoping to furprlfe it by an attack in the night-time. But being attacked while advancing thro' narrow paffes, where his numerous army had not room to afisi he was defeated with great daughter, and him- felf taken prlfoner, carried into Syracufe, and put to death. In the mean time the Agrigentines, finding that the Carthaginians and Syracufians had greatly weak- ened each other by this war, thought it a proper op- portunity to attempt the fovereignty of the whole Ifland. They therefore commenced a war againft both parties ; and profecuted it with fuch fuccefs, that in a {hovt time they wrefted many places of note both •out of the hands of the Syracufians and Carthagi- nians. In Africa the tyrant carried every thing before him. He reduced moft of the places of any note in the territory of Caathage ; and hearing that Elyraas king of Libya had declared agalnll him, he immedi- ately entered Libya Superior, .and in a great battle overthrew that prince, putting to the fword a good part of his troops, and the general who commanded them ; after which he advanced agalnll the Carthagi- nians with fuch expedltio)!, that he furprlfed and de- . Vol. IV. Part 1. 193 1 CAR fcated them, with the lofs of 2O00 killed, and a great Ca:thafre. number taken prlfoners. He next prepared for the — v— fiege of Carthage itfelf; and in order thereto advanced to a poft within five miles of that city. On the other hand, notwithftanding the great loffes they had al- ready fuftalned, the Carthaginians, with a powerful army, encamped between him ahd their capital. In this fituation Agathocles received advice of the defeat of the Carthaginian forces before Syracufe, and the head of Hamilcar their general. Upon this he imme- diately rode up to the enemy's camp, and fliowing thera the head, gave them an account of the total deftruc- tlon of their army before Syracufe. This threw them into fuch confternatlon, that in all human probabiUty Agathocles would have made himfelf mafter of Car- thage, had not an unexpedted mutiny arifen in his camp, which gave the Carthaginians an opportunity of recovering from their terror. The year following an engagement happened, in He make; which neither party gained any great advantage : but a", alliance foon after, the tyrant, notwithftanding all his vido- ^'tJ^Ol'l^e^- rles, found himfelf unable to carry on the war alone ; ' and therefore endeavoured to gain over to his interell Ophelias, one of the captains of Alexander the Great. In this he perfeftly fucceeded ; and, to fuccour his new ally the more effeftually, Ophelias fent to Athens for a body of troops. Having finiftied his military preparations, Ophelias found his army to confift of 10,000 foot and 600 horfe, all regular troops, be- fides 100 chariots, and a body o£ 10,000 men, at- tended by their wives and children, as though he had been going to plant a new colony. At the head of thefe forces he continued his march towards Agatho- cles for 1 8 days ; and then encamped at Automolae, a city about 3000 ftadla dlftant from the capital of his dominions. From thence he advanced through the Reglo Syrtlca ; but found himfelf reduced to fuch ex- tremities, that his army was in danger of perifliing for want of bread, water, and other provifions. They were alfo greatly annoyed by ferpents and wild beafts, with which that defert region abounded. The ferpents made the greateft havock among the troops ; for, be- ing of the fame colour with the earth, and extremely venomous, many foldiers, who trod upon them with- out feeing them, were ftuag to death. At laft, after a very fatiguing march of two months, he approached Agathocles, and encamped at a 'fmall diftance from Jilm, to the no fmall terror of the Carthaginians, who apprehended the moft fatal confequences from this jundioil. Agathocles at firft carcffed him, and ad- whom he vlfed him to take all poffible care of his troops that treacher- Irad undergone fo many fatigues ; but foon after cut ""^5' him off by treachery, and then by fair words and pro- mlfes perfuaded his troops to ferve under himfelf. Agathocles now finding himfelf at the head of a numerous army, . affumed the title of King of Africa, intending foon to complete his conquefts by the re- duftion of Carthage. He began vvlth the fiege of Utica, which was taken by affault. After this he marched againft Hippo Dlarrhytus, the Biferta of the moderns, which was alfo taken by .'ftorni ; and after this moft of the people bordering upon the fea-coafts, and even thofe who inhabited the Inland parts of the country, fubmitted to him. But in the midft of thisjs obli'-ed career of fuccefs, the Sicilians formed an affoclation in to return B b favour ^"nue. Car.hage. 47 Succefs of Archaga- thus. He is red«< ced to the litmofl di- ftrefe. CAR [ 19 favour of liberty ; wliich obliged tbe tyrant to return home, leaving his fon Archagathus to carry on the war in Africa. Archagathus, after his father's departure, greatly extended the African conquefls. He fent Eumachus at the head of a large detachment to invade fome of the neighbouring provinces, wliile he himfelf, with the greateft part of his army, obfefved the motions of the Carthaginians. Eumachus falling into Numi- dia, firft took the great city of Tocas, and conquer- ed feveral of the .Numidian cantons. AfteiAvards he befieged and to«k Phellina ; which was attended with the fubmifiion of the Afphodelodians, a nation, accor- ding to Diodorus, as black as the Ethiopians. He then reduced feveral cities ; and being at lall elated with fuch a run of good fortune, refulved to penetrate iH-to the more remote parts of Africa. Here he at firft met with fuccefs; but hearing that the barbarous nations were advancing in a formidable body to give him battle, he abandoned his conquefts, and retreated with the utmoft precipitation towards the fea-coaits. after having \oi\ abundance of men. This unfortunate expedition made a great altera- tion for the worfe In the affairs of Archagathus. The Carthaginians being informed of Eumachas's bad fuc- cefs, refolved to exert themfelves in an extraordinary manner to repair their former loffes. They divided their forces Into three bodies: one of thefe they fent to the fea-coafts, to keep tlie towns there In awe ; another they difpatched into the Medlteiranean parts, to preferve the allegiance of the Inhabitants there ; and the laft body they ordered to the Upper Africa, to fupport their confederates In that country, Arclia- gathus being apprifed of the motions of the Cartha- ginians, divided his forces hkewlfe Into three bodies. One of thefe he fent to obferve the Carthaginian troops on the fea-coafts, with orders to advance af- terwards into the Upper Africa ; another, under the command of jEfchrlon, one of his generals, he pofted at a proper diftance In the heart of the country, to have an eye both on the enemy there and the barba- rous nations ; and with the Ml, which he led In per- fon, he kept nearer Carthage, preferving a commu- nication with the other two, in order to fend them fuccours, or recal them, as the exigency of affairs fhould require. — The Carthaginian troops fent mto tli€ heart of the country, were commanded by Han- no, a general of great experience, who being inform- ed of the approach of jEfchrion, laid an ambufcade for him, into which he was drawn and cut off with 4000 foot and 200 horfe. Hlmllco, who commanded the Carthaginian forces in Upper Africa, having advice of Eumachus's march, immediately advanced agalnft him. An engagement enfued, in which the Greeks were almoft totally cut off, or perlfhed with thirft af- ter the battle, out of 8000 foot only 30, and of 800 horfe only 40, having the good "fortune to make their efcape. Archagathus receiving the melancholy news of thefe two defeats, immediately called In the detach- ments he had fent out to harafs the enemy, which ■would otherwife have been Inftantly cut off. He was, however, In a fhort time hemmed in on all fides In fuch a manner as to be reduced to the laft extremity for want of prcvifions, and ready every moment to 5 4. ] CAR be fwallowed up by the numerous forces which fur- Caithagc:. rounded him. In this deplorable fituation Agathocles /-— ' received an exprefs from Archagathus, acquainting him of the loffes he had fuftained and the fearclty of provifions he laboured under. Upon this the tyrant, leaving the care of the Sicilian war to one Leptlnes, by a ftratagem got 18 Etrufcan (hips that came to his afllftance out of the harbour ; and then engaging the Carthaginian fquadron v/hich lay in its neighbour- hood, took five of their fhips, and made all their men prifoners. By this means he became mafter of the port, and fecured a pafTage into It for the mer- chants of all nations, which foon reftored plenty to that city, where the famine before had begun to make great havock. Supplying himfelf, therefore, with a fufhclent quantity of neceffarles for the voyage he was going to undertake, he immediately fet fail for Africa. 49 Upon his arrival In this country, Agathocles re- Agathoclej viewed his forces, and found them to confift .of 6000 arrives in Greeks, as many Samnites, Celtes, and Etrufcans ; ^^"ca. befides 10,000 Africans, and 1500 horfe. As he found his troops almoft in a ftate of defpair, he thought this a proper time for offering the enemy battle. The Carthaginians, however, did not think proper to ac- cept the challenge ; efpeclally as by keeping clofe in their camp, Vv^here they had plenty of every thing, they could ftarve the Greeks to a furrender without 50 ftriking a ftroke. Upori this Agathocles attacked the Attacks th Carthaginian camp with great bravery, made a con- <:a™P «W fiderable impreffion upon it, and might perhaps have "^^^^J^^ carried It, had not his mercenaries deferted him almoft fuccefs. at the firfl onfet. By this piece of cowardice he was forced to retire with precipitation to his camp, whither the Carthaginians purfued him veiy clofely, doing great execution In the purfuit. . The next night, tlie Carthagl-nians facrificed all the Difafter prifoners of dlftlnftlon as a grateful acknowledgment in the C ir to the gods for the vlftory they had gained. While J^^P:'^'^'* they were em.ployed in this inhuman work, the wind, fuddenly rifing, carried the flames to the facred ta- bernacle near the altar, which was entirely confumed, as well as the general's tent, and thofc of the princi- pal officers adjoining to It. A dreadful alarm took place through the whole camp, which was heightened by the great progrefs the fire made. For the foldiers tents confifting of very combuftlble materials, and the wind blowing in a moft violent manner, the whole camp was almoft entirely laid in afhes ; and many of the foldiers endeavouring to carry off their arms, arid the rich baggage of their ofiicers, perifhed in the flames. Some of thofe who made their efcape met with a fate equally unhappy : For, after Agathocles had received the lail blow, the Africans deferted him, and were in that inftant coming over in a body to the Carthaginians. Tliefe, the perfons who were flying from the flames took to be the whole Syracufian ar- my advancing In order of battle to attack their cajmp. Upon this a dreadful confufion enfued. Some took to their heels j others fell down in heaps one upon another; and others engaged their comrades, mif- taklng them for the enemy. Five thoufand men lofl their lives in this tumult, and the reft thought proper to take refuge within the walls of Carthage ; nor could the appearance of day-light, for fomc time, dlf- iipats CAR 5* inorher in lat of A- athocles. fipate their terrible apprehenfions. In the mean time, the African deferters, obferving the great con- fufion the Carthaginians- were in, and not knowing the meaning of it, were fo terrified, that they thought proper to return to the place from whence they came. The Syracufians feeing a body of troops advancing towards them in good order, concluded that the ene- my were marching to attack tliem, and therefore im- mediately cried out " To arms." The flames afcend- ing out of the Carthaginian camp into the air, and the lamentable outcries proceeding from thence, con- firmed them in this opinion, and greatly heightened their confufion. The confequence was much the fame as in the Carthaginian camp ; for coming to blows with one another iaftead of the enemy, they fcarce recovered their fenfes upon the return of light, and the inteftine fray was fo bloody, that it coll Aga- thocles 4000 men. This laft difafter fo dilheartened the tyrant, that he immediately fet about conti'iving means for making his efcape privately ; and this he at laft, though with great difliculty, effefted. After his departure, his two fons were immediately put to death by the fol- diers, who, choofing a leader from among themfelves, made peace with the Carthaginians upon the following conditions : i. That the Greeks (hould deliver up all the places they held in Africa, receiving from them 300 talents ; 2. That fuch of them as were willing to ferve in the Carthatginian army fhould be kindly treat- ed, and receive the ufual pay; and, 3. That the reft ftiould be tranfported to Sicily, and have the city of Selinus for their habitation. From this time, to that of their firft war with the Romans, we find nothing remarkable in the hiftory of the Carthaginians. The firfl Punic war, as it is commonly called, happened about 256 years before Chrift. At that time, the Carthaginians were poflef- fed of extenfive dominions in Africa ; they had made confiderable progrefs in Spain ; were mafters of Sar- dinia, Corfica, and all the iflands on the coaft of Italy; and had extended their conquefts to a great part of Sicily. The occafion of the firft rupture between the two rep\jblics was as follows. The Mamertines be- ing vanqiiiihed in battle, and reduced to great ftraits by Hiero king of Syracufe, had refolved to deliver up Meffina, the only city they now poffeffed, to that prince, with whofe mild government and ftri£l pro- bity they were well acquainted. Accordingly, Hiero was advancing at the head of his troops to take pof- feffion of the city, when Hannibal, who at that time commanded the Carthaginian army in Sicily, prevent- ed him by a ftratagem. He came to meet Hiero, as it were to congratulate him on his viilory ; and amufed him, while feme of the Carthaginian troops filed off towards Meffina. Hereupon the Mamer- tines, feeing their city fupported by a new reinforce- ment, >were divided into fcvcral opinions. Some were for accepting the proteftion of Carthage; others were for furrendering to the king of Syracufe ; but the greater part were for calling in the Romans to their affiftance. Deputies were accordingly difpatch- ed to Rome, offering the poffeflion of the city to the Romans, and in the moft moving terms imploring proteftian. This, aftcdition. Tlie hril land they got fight of was Cape Hermea, where the fleet lay at anchor for forae time waiting till the galleys and tranfports came up. From thence thev coafted along till they arrived be- fore Cllupea, a city to the ead of Carthage, where the)' made their firft defcent. No words can exprefs the conllernation of the Car- r 197 ] CAR 66 srthagini- 67 liccefs of Leguius. ){i eat thagin ians, on the arrival of the Romans in Africa, erna- r^^^^ inhabitants of Chipea were fo terrified, that, ac- cording to Zonaras, they abandoned the place, which the Romans immediately took poflellion of. Having left there a ilrong garrifon to fecure their fliipping, and keep the adjacent territory in awe, they moved nearer Carthage, taking a great number of towns ; they likewife plundered a prodigious number of vil- lages, laid valt numbers of noblemens feats in aflies, and took above 20,000 prifoners. In Ihort, having plundered and ravaged the whole country, almofl: to the gates of Carthage, they returned to Clupea loaden with the immenfe booty they had acquired in the ex- pedition. The tenth year, Regulus piiflied on his conquefl;s with great rapidity. To oppofe his progrefs, Hamil- car was recalled from Sicily, and with him Boftar and Afdrubal were joined in command. Hamilcar com- manded an army juil equal to that of Regulus. The other two commanded feparate bodies, which were to join him or aft apart as occafion required. But, before they were in a condition to take the field, Re- gulus, purfuing his conquefls, arrived on the banks of the Bragada, a river which empties itfelf into the fea le kills a fmall diilance from Carthage. Here he had a Knftrous monftrous ferpent to contend with, which, according irj ent. iq the accounts of thofe days, infefted the waters of the river, polfoncd the air, and killed all other ani- mals with its breath alone. When the Romans went to draw water, this huge dragon attacked them ; and, twilling itfelf round their bodies, either fqueezed them to death, or fv/allowed them alive. As its hard and thick fcales were proof againft their darts and arrows, they w^ere forced to have recomfe to the balifl^ae, which they made ufe of in fieges to throw great Hones, and to beat down the walls of befieged cities. Witii thefe they difcharged fliowers of huge ftones againft this new enemy, and had the good luck, with one of them, to break his back-bone ; which dilabled him from twifl:ing and winding lu's immenfe body, and by that means gave the Romans an opportunity of approach- ing and difpatching him with their darts. But his dead body corrupted the air and the water of the ri- ver ; and fpread fo great an infe(?i:ion over the whole country, that the Romans were obliged to decamp. We ai:e told that Regulus fent to Rome the fivin of 68 this monfter, which was 120 feet long; and that it Carthage, was hung up in a temple, where it was preferved to — ^r——^ the time of the Numantine war. 69 Having paffed this river, he befieged Jd'/s, or Adda, Defeats the not far from Carthage, which the enemy attempted ^j^J'^^^^'"'" to reheve ; but as they lay encamped among hills and ' ' rocks, where their elephants, in which the main ilrength of their army confiiled, could be of no ule, R.egulus attacked them in their camp, killed 17,000 of them, and took 5000 prifoners, and 18 elephants. Upon the fame of this viftory, deputations came from all quarters, iufomuch that the conqueror in a fev/ days became mafter of 80 towns ; among which were the 70 city and port of Utica. This increafed the alarm at -'^nd reda- Carthage ; which was reduced to defpair, when Re- ^^^^ gulus laid fiege to Tunis, a great city about nine miles defpalrT from the capital. The place was taken in fight of the Carthaginians, who, from their walls, beheld all the operations of the fiege, without making the leaft at- tempt to relieve it. And to complete their misfor-- tunes, the Numidians, their neighbours, and impla- cable enemies, entered their territories, committing every where the moft dreadful devaftations, which foon occafioned a great fcarcity of provifions in the city. The public magazines were foon exhaufted : and, as the city was full of felfifli merchants, who took ad- vantage of the pubHc diftrefs, to fell- provifions at an exorbitant price, a famine enfued, with all the evils which attend it. ••r In this extremity Regulus advanced to the very His propo* gates of Carthage ; and having encamped under the ^^'^ '^^ walls, fent deputies to treat of a peace with the fe-j^g'^ied/'^* nate. The deputies were received with inexprefiible joy ; but the conditions they propofed were fuch that the fenate couJ^ not hear them without the greatelt indignation. They were, i. That the Carthaginians- fliould rclinquifh all claims to Sardinia, Corfica, and Sicily. 2. That they fliould reftore to the Romans all the prifoners they had taken from them fince the beginning of the war. 3. That if they cared to re- deem any of their own prifoners, they fliould pay fo much a-head for them as Rome fliould judge reafon- able. 4. That they fliould for ever pay the Romans an annual tribute. 5. That for the future they fliould- fit out but one man. of war for their own ufe, and 50 triremes to ferve in the Roman fleet, at the expence of Carthage, when required by any of the future con- fuls. Thefe extravagant demands provoked the fe- nators, who loudly and unanimoufly rejefted them ; the Roman deputies, however, told them that Regu- lus would not alter a fingle letter of the propofals, and that they muft either conquer the Romans or obey them. In this extreme diftrefs, fome mercenaries arrived Xanthipfnia- from Greece, among whom was a Lacedemonian, by appointed name Xanthippus, a man of great valour and experi- ence in war. This man, having informed hinifelf ofQ^^^^f^^^^^^^j,. the circumftances of the late battle, declared pubhcly, an arniy.. that their overthrow was more owing to their own mifconduA than to the fuperiority of the enemy. This difcourfe being fpread abroad, came at laft to the knowledge of the fenate ; and by them, and even by the defire of the Carthaginian generals thcmfelvtfj, Xanthippus was appointed commander in chief of theic forcef!. His firft care was to difcipline his troops in.-i proper CAR I Ortliape. proper Tnanner. He taught them how to march, en- *'~"'V— ' camp, widen and dofc their ranks, and rally after the Lacedemonian manner under their proper colours. He then took the field with 12,000 foot, 4000 horfe, and 100 elephants. The Romans were furprifed at the fudden alteration they obferved in the enemy's conduft ; but Regulus, elated with his lall fuccefs, came and encamped at a fmall diftance from the Car- thaginian army in a vaft plain, where their elephants and horfe had room to aft. The two armies were parted by a river, which Regulus boldly pafTed, by which means he left no room for a retrekt in cafe of any misfortune. The engagement began with great ■ fury ; but ended in the total defeat of the Romans, dus taken. 74 cd by fea %nd land. 73 The Ro. mans utter- ia^Rel'u-' ^'^^^P*^ 2000 that efcaped to Clupea, were all killed or taken prifoners, and among the latter was Recrulus himfelf. The lofs of the Carthaginians fcarce exceeded 800 men, The Carthaginians remained on the field of battle till they had firipped the llain ; and then entered their metropolis, which was ahnoft the only place left them, -He is Jruel- g^^^^ triumph. They treated all their prifoners ly ufcd. with great humanity, except Regulus ; but as for him, he had fo infulted them in his profperity, that they could not forbear fhewing the highell marks of their refentment. According to Zonaras and others, he was thrown into a dungeon, where he had only fufte- nance allowed him barely fufficient to keep him alive. Nay, his cruel mafters, to heighten his other torments, ordered an huge elephant (at the fight of which ani- mal, it feems, he was greatly terrified) to be conftantly placed near him ; which prevented him from enjoying any tranquillity or repofe. 'Carthaglnl- The eleventh year of this war, the Carthaginians, e- ans defeat- Jated with their viftory over Regulus, began to talk in a very high ftrain, threatening Italy itfelf with an in- vafion. To prevent this, the Romans took care to garrifon all their maritime towns, and fitted out a new fleet. In the mean time, the Carthaginians befieged Clupea and Utica in vain, being obHged to abandon their enterprize, upon hearing that the Romans were equipping a fleet of 350 fail. The Carthaginians ha- ving with incredible expedition refitted their old vef- fels, and built a good number of new ones, met the Roman fleet off" Cape Hermea. An engagement en- fued, in which the Carthaginians were utterly defeated; 104 of their fhips being funk, 30 taken, and 15,000 of their foldiers and rowers killed in the aftion. The Romans purfued their courfe to Clupea, where they were no fooner landed, than they found themfelves at- tacked by the Carthaginian army, under the two Hanno's, father and fon. But, as the brave Xanthip- pus no longer commanded their army, notwithftanding the Lacedemonian difcipline he had introduced among them, they were routed at the very firlt onfet, with the lofs of 9000 men, and among them many of their chief lords. Notwithftanding all their viftories, however, the Romans found themfelves now obhged, for want of provifions, to evacuate both Clupea and Utica, and abandon Africa akogether. Being defirous of figna- lizing the end of their confulate by fome important conqueft on Sicily, the confuls fleered for that ifland, contrary to the advice of their pilots, who reprefented their danger, on account of the fcafon being fo far ad- 76 ?lomans vfibliged to abandon Africa. 198 1 CAR vanced. Their obftinacy proved the: deftru£lion of CartliSgci the whole fleet ; for a violent florm arifing, out of 370 veffels, only 80 efcaped fliipwreck, the reft hdng .-^^JJ ^^^J fvvallowed up by the fea, or daflied againft the rocks, totally de- | This was by far the greateft lofs that Rome had ever ftrnyed by | fuftained ; for befides the fliips that were caft away ^ ftorm. |! with their crews, a numerous army was deftroyed, with all the riches of Africa, which had been by Re- gulus amaffed and jlepofited in Qupea, and were now from thence tranfporting to Rome. The whole coall from Pachinum to Camerina was covered with dead bodies and wrecks of fliips ; fo that hiftory can fcarce afford an example of fuch a dreadful difailei-. The twelfth year, the Carthaginians hearing of this misfortune of the Romans, rcHewed the war in Sicily with freffi fury, hoping the whole iiland, which was now left defencelefs, would fall into their hands. Caf- thalo, a Carthaginian commander, befieged and took 78 Agrigentum. The town he laid in alhes and demo- Agrigen liflied the walls, obliging the inhabitants to fly to O- ^^^'^ ^^^'f^^ lympium. Upon the news of this fuccefs, Afdrubal ^royed'by was fent to Sicily with a large reinforcement of troops, the Cartha and 150 elephants. They likewife fitted out a fqua- ginians. dron, with which they retook the ifland of Cofyra, and marched a ftrong body of forces into Mauritania and Numidia, to punifli the people of thofe countries for fliewing a difpofition to join the Romans. In Si- cily the Romans poflefled themfelves of Cephalodium and Panormus, but were obhged by Carthalo to raifc the fiege of Drepanum with great lofs. The 13th year, the Romans fent out a fleet of 260 The Ro galleys, which appeared oft' Lilybaeum in Sicily; but ''^oi finding this place too ftrong, they fteered from thence * to the eailern coaft of Africa, where they made feve- ral defcents, furprifed fome cities, and plundered feve- ral towns and villages. They arrived fafe at Panormus, and in a few days fet fail for Italy, having a fair wind till they came off" Cape PaHnurus, where fo violent a which is ftorm overtook them, that 160 of their galleys and a again de- great number of their tranfports were loft ; upon which ^''"yeii* the Roman fcnate made a decree, that, for the future, no more than 50 vefl"els ftiould be equipped ; and that thefe Ihould be employed only in guarding the coaft of Italy, and tranfporting the troops Into Sicily. The 14th year, the Romans made themfelves ma- fl:ers of Himera and Lipara in Sicily ; and the Car- thaginians conceiving new hopes of conquering that ifland, began to make frelh levies in Gaul and Spain, and to equip a new fleet. But their treafures being exhaufted, they applied to Ptolemy king of Egypt, intreating him to lend them 2000 talenta : but he be- ing refolved to ftand neuter, refufed to comply with their reqxieft ; telling them, that he could not with- out breach of fidelity aflift one friend againft another. However, the republic of Carthage making an effort, equipped a fleet of 200 fail, and raifed an army of 30,000 men, horfe and foot, and 140 elephants, ap- pointing Afdrubal commander in chief both of the fleet and army. The Romans then finding the great They fit advantages of a fleet, refolved to equip one notwith- ftanding all former difafters ; and while the vefl"el3 were building, two confuls were chofen, men of va- lour and experience, to fuperfede the a6tlng ones in Sicily. Metellus, however, one of the former con- fuls, being continued with the title of proconful, found xaczai IS utterly bfeated. 83 .tlybseum CAR ( I hirthage. means to draw Afdrubal into a battle on difadvan- -■r-^ tageous terrr.s near Panormus, and then fallying out _ . . i?pon him, gave him a mod terrible overthrow. I'JiltSv" '^^'^"^y thoiifand of the enen>y were killed, and many elephants. An hundrtd and four elephants were taken with their leaders, and fent to Rome, where they were hunted and put to death in the circus The 15th y^ar, the Romans befieged Lilybasum ; cfieji;cdby and the fiege continued during the reft of the firft Punic war, and was the only thing remarkable that '^^"^* happened during that time*. The Carthaginians, See Lily o„ j;^g f^rft news of its being befieged, fent Regulus with fome deputies to Rome to treat of a peace : but inflead of forwarding the negociation, he hindered it ; and notwithftanding he knew the torments prepared for him at Carthage, could not be prevailed upon to 84 flay at Rome, but returning to his enemies country, hey are was put to a moit cruel death- During this fiege, sfeated at Roman fleet under Claudius Pulcherwas utterly de- artha''i- ^^^^^'^ Adherbal the Carthaginian admiral. Ninety ians. ■ of the Roman galleys were loft in the aftion, 8000 of their men either killed or drowned, and 20,000 taken and fent prifoners to Carthage ; and the Carthaginians gained this fignal viftory without the lofs of a fingle \ Roman fliip, or even a fingle man. Another Roman fleet met leet utterly a ftiU feverer fate. It confifted of 1 20 galleys, i^'a^ftorm tranfports, and was laden with all forts of military ^ ^ ' ftores and provifions. Every one of thefe veffels were loft by a ftorm, vpith all they contained, not a fingle plank being faved that could be ufed again ; fo that the Romans found ihemfelves once more deprived of their whole naval force, amdkar I" the mean time, the Carthaginian foldiery having ircas fent flaown a difpofition to mutiny, the fenate fent over ito Sicily. Hamilcar Barcas, father of the famous Hannibal, to Sicily. He received a chai'te blanche from the fenate to a£t as he thought proper ; and by his excellent conduft and refolution, fhowed himfelf the greateft general of his age. He defended Eryx, which he had taken by furprife, with fuch vigour, that the Romans would never have been able to make themfelves matters of it, had they not fitted out a new fleet at the ex- pence of private citizens, which, having utterly defeat- ed that of the Carthaginians, Hamilcar, notwithftand- ' 87 ing all his valour, was obliged to yield up the place |cace with which he had fo long and fo bravely defended. The following articles of a peace were immediately drawn up between the two commanders, i. The Carthagi- nians fhall evacuate all the places which they have in Sicily, arrd entirely quit that iffand. 2. They fhall, in 20 years, pay the Romans, at equal payments every year, 2200 talents of filver, that is, L. 437,250 Ster- ling. 3» They fhall reftore the Roman captives and dcferters without ranfom, and redeem their own pri- foners with money. 4 They ftiall not make war up- on Hiero king of Syracufe, or his allies. Thefe ar- ticles being agreed to, Hamilcar furrendered Eryx u- pon condition that all his foldiers fhould march out with him upon his paying for each of them 1 8 Roman denarii. Hoft'ages were given on both fides, and deputies were fent to Rome to procure a ratification of the treaty by the fenate. After the fenators had thoroughly informed themfelves of the ftate of affairs, two more articles were added, viz. i. That J 000 talents fhould ke R pans. 99 ) GAR be paid immediately, and the 2200 in the fpace of 10 Carthage; years at equal payments. 2. That the Carthaginians v fhould quit all the little iflands about Italy and Sicily, and never more come near them with fhlps of war, or ralfe mercenaries in thofe places. NecefTity obliged Hamilcar to confent to thefe terms ; but he returned to Carthage with an hatred to the Romans, which he did not even fuffer to die with him, but tranfmitted to his fon the great Hannibal. 88 The Carthaginians were no fooncr got out of this Caufcs of bloody and expenfive war, than they found themfelves ^^51^^^^""^ engaged in another which was like to have proved fa- mercena- tal to them. It is called by ancient hlftorians theZi-ries. byan war, or the luar tvith the mercenaries. The prin- cipal occafion of It was, that when Hamilcar returned to Carthage, he found the republic fo much impover- ifhed, that, far from being able to give thefe troops the largefTes and rewards promlfed them, it could not pay them their ar-reai"s. He had committed the care of tranfporting them to one Gifco, who, being an of- ficer of great penetration, as though he had forefeen what would happen, did not fhip them off all at once, but in fmall and feparate parties, that thofe who came firlt might be paid off and fent home before the arrival of the reft. The Carthaginians at home, however, did not adl with the fame prudence. As the ftate was al- moft entirely exhaufted by the laft war, and the im- menfe fum of money, in confequence of the peace, paid to the Romans, they judged it would be a laudable ac- tion to fave fomething to the public. They did not therefore pay off the mercenaries in pr-oportlon as they arrived, thinking it more proper to wait till they all came together, with a view of obtaining fome remiflion of their arrears. But being foon made fen- fible of their wrong conduct on this occafion, by • the frequent diforders thefe barbarians committed in. the city, they with fome dlfSculty prevailed upon; the officers to take up their quarters at Sicca, and canton their troops in that neighbourhood. To in- duce them to this, however, they gave them a fum of money for their prefent fubfiftence^ and promifed to comply with their pretenfions when the remainder of their troops arrived from Sicily. Here, being whol- ly immerfed in idlenefs, to which they had long been flrangers, a negleft of difcipline enfued, and of courfs a petulant and licentious fpirit immediately took place. They were now determined not to acqulefce in recei- ving their bare pay, but to infift upon the rewards Ha- milcar had promifed them, and even to compel the ftate of Carthage to comply with their demands by j» force of arms. The fenate being informed of the jj^pr^jg^^- mutinous difpofition of the foldiery, difpatched Han-condud of; no, one of the fuffetes,. to pacify them. Upon hisHanno. arrival at Sicca, he expatiated largely upon the po^ verty of the ftate, and the heavy taxes with which the citizens of Carthage were loaded and therefore, inftead of anlwering their high expeftations, he de- fired them to be fatlsfied with receiving part of their pay, and remit the remainder to ferve the preffing exigencies of the republic. The mercenaries being highly provoked, that neither Hamilcar, nor any other of the principal officers- who commanded them in Sicily, and were the beft judges of their meritj made their appearance on this occafion, but only Hanno, a perfon utterly unknown, and above all'' others. CAR 200 ;arthag;c. otliers utterly difagretable to them, immediately had recourfe to arms. Affembling therefore in a body to the number of 20,000, they advanced to Tunis, and immediately encamped before that city. The Carthaginians being greatly alarmed at the approach of fo formidable a body to Tunis, made large conceflions to the mercenaries, in order to bring them back to their duty : but, far from being foften- ed, they grew more infolent upon thefe conceflions, taking them for the efFeAs of fear ; and therefore were altogether averfe to thoughts of accommoda- tion. The Carthaginians, making a virtue of ne- ctfiity, fhowed a difpofition to fatisfy them in all points, and agreed to refer themfelves to the opinion of fome general in Sicily, which they had all along dcfired ; leaving the choice of fuch commander entire- ly to them. Giico was accordingly pitched upon to inediate this affair, the mercenaries believing Hamllcar to have been a principal caufe of the ill treatment they met with, fince he never appeared among them, and, according to the general opinion, had voluntarily re- figned his comraiflion. Gifco foon arrived at Tunis with money to pay the troops ; and after conferring with the officers of the feveral nations apart, he ha- • rangued them in fuch a manner, that a treaty was "Upon the point of being concluded, when Spendius and Mathos, two of the principal mutineers, occafioned a tumult in every part of the camp. Spendius was by nation a Campanian, who had been a flave at Rome, and had fled to the Carthaginians. The apprehen- fions he was under of being delivered to his old maftef, by whom he was fure to be hanged or crucified, prompted him to break off the accom.modation. ~ Ma- thos was an African, and free born ; but as he had been a£live in raifing the rebellion, and vcas well ac- quainted with the implacable difpofition of the Car- thaginians, he knew that a peace mufl; infallibly prove his ruin. He therefore joined with Spendius, and in^ finuated to the Africans the danger of concluding a treaty at that junfture, but which could not leave them fingly expofed to the rage of the Carthaginians. This fo incenfed the Africans, who were much more nu- ■meroua than the troops of any other nation, that they immediately aflembled in a tumultuous manner. The •foreigners foon joined them, being infpircd by Spen- dius with an equal degree of fury. Nothing was now to be heard but the moft horrid oaths and impre- cations againfl; Gifco and the Carthaginians. Who- ever off^ered to make any remonfl:rance, or lend an ear to temperate counfels, was ftoned to death by the en- raged -multitude. Nay, marry perfons loft their lives barely for attempting to fpeak, before it could be known w'liether they were in the inteieil of Spendius or the Carthaginians. In the midft of thefe commotions, Gifco behaved with great firmnefs and intrepidity. He left no me- thods untried to foften the officers and 'calm the minds of the foldiery ; but the torrent of fedltion was now fo ftrong, that there was no pofiibihty of keeping it within bounds. They therefore fcized upon the military cheft, dividing the money among themfelves in part of their arrears, put the perfon of Gifco un- der an arreft, and treated him as well as his attend- ants with the utmoft indignity. Mathos and Spen- dius, to deftroy the reraoteft hopes of an accommo- 1 CAR datlon with Carthage, applauded the courage and re- Carth&.ge| folution of their men, loaded the unhappy Gifco and — | his followers with Irons, and formally declared war , 9° » . , „ , . . \ 11 1 • • f A r • 1 nemerca againlt the Carthaginians. All the cities or Atrica^^j.jgj to whom they had fent deputies to exhort them tOc]arewar.| recover their liberty, foon came over to them, ex- *i cept Utica and Hippo Diarhytus. By this means their army being greatly Increafed, they divided it into two parts, with one of which they moved to- wards Utica, whilft the other marched to Hippo, in order to befiege both places. The Carthaginians, in the mean time, found themfelves ready to fink under the prefliire of their misfortunes. After they had been harafled 24 years by a moft cruel and deftruc- tive foreign war, they entertained fome hopes of en- joying repofe. The citizens of Carthage drew their particular fubfiftence from the rents or revenues of their lands, and the public expences from the tribute paid from Africa ; all which they were not only de- prived of at once, but, what was worfe, had it diretlly turned againft them. They were deftltute of arms and forces either by fea or land ; had made no pre- parations for the fuftaining of a fiege, or the equip- ping of a fleet. They fuffered all the calamities in- cident to the moft ruinous civil war ; and, to com- plete their mifery, had not the leaft profpeft of re- ceiving afiiftance from any foreign friend or ally. Notwithftanding their deplorable fituation, however, they , did not defpond, but purfued all the meafure-s neceflary to put themfelves into a pofture of defence. Hanno was appointed commander in chief of all their forces ; and the moft ftrenuous efforts were made, not only to repel all the attempts of the mutineers, but e* ven to reduce them by force of arms. In the mean time Mathos and Spendius laid fiege to Utica and Hippacra at once ; but as they were carried on by detachments drawn from the army for that purpofe, they remained with the main body of their forces at Tunis, and thereby cut off all commu- nication betwixt Carthage and the continent of Afri- ca. By this means the capital was kept in a kind of blockade. The Africans likewife harafled them by perpetual alarms, advancing to the very walls of Car- thage by day as well as by night, and treating with the utmoft cruelty every Carthaginian that fell into their hands. Hanno was difpatched to the relief of Utica with a They are good body of forces, 100 elephants, and a large ^'^f'^^^^^^ 1 train of battering engines. Having taken a view of ^'^^"'lO' the enemy, he immediately attacked their intrench- ments, and, after an obftinate difpiite, forced them. The mercenaries loil a vaft number of meil ; and con- fequently the advantages gained by Hanno were fo great,, that they might have proved decifive, had he made a proper ufe of them : But becoming fecure af- He is in I ter his viftory, and his ti-oops being every where ofF'"''"deiea their duty, the mercenaries, having rallied their for-^ ces, fell upon him, cut off many of his men, forced the reft to fly into the town, retook and plundered the camp, and feized all the provifions, military ftores, &c. brought to the relief of the befieged. Nor was this the only inftance of Hanno's military incapacity. Notwithftanding he lay encamped in the moft advanta- geous manner near a town called Gorza, at which place he twice overthrew the enemy, and had it in his power 9t Carthage, . 9.1 ^amiicar Jarcas ap- ointed to mrnand .gain ft ihem. le defeats CAR I 20 power to have totally ruined them, he yet neglefted to impirove thofe advantages, and even fuifered the mer- cenaries to poflefs themfelves of the ifthmus which joirjied the peninfula on which Carthage ftood, to the con tinent of Africa* Xhefe repeated miftake? induced the Carthaginians onoe more to place Hamilcar Barcas at the head of theur forces. He marched againft the enemy with 1 0,000 men, horfe and foot ; being all the troops the Carthaginians could then affemble for their defence ; a full proof of the low ftate to which they were at that timie reduced. As Mathos, after he had poflefled himifelf of the ifthmus, had ported proper detachments in two paffes on two hills facing the continent, and guarded the bridge over the Bngrada, which through Hamno's negle£t he had taken, Hamilcar faw little -prolbability of engaging him upon equal terms, or in- dee(d of coming at htm. Obferving, however, that on the blowing of certain winds the mouth of the ri- ver was choaked up wnih fand, fo as to become paf- fable, though with no fmall difficulty, as long as thefe winds continued ; he halted for fome time at the river's mouth, without communicating his defign to any perfon. As foon as the v/ind favoured his intend- ed project, he pafled the river privately by night, and immediately after his paflage he drew up the troops in order of battle, and advancing into the plain where his elephants were capable of acting, moved towards Mathos, who was pofted at the village near the bridge. This daring adlion greatly furprifed and in- timidated the Africans. However, Spendius recei- ving intelligence of the enemy's motions, drew a bo- dy of 10,000 men out of Mathos's camp, with which he attended Hamilcar oh one fide, and ordered 1 5,000 from Utica to obferve him on the other, thinking by this, means to furround the Carthaginians, and cut theiTi all off at one ftroke. By feigning a retreat, Hamilcar found ineans to engage them at a difadvan- fage; and gave them a total overthrow, with the lofs of 6000 killed and 2000 taken prifoners. The reft fled, fome to the town at the bridge, and others to the camp at Utica. He did not give them time to recover from their defeat, but purfued them to the town near the bridge before mentioned ; which he entered without oppofition, the mercenaries flying in great confufion to Tunis ; and upon this many towns fubmitted of their own accord to the Carthaginians, whilft others were reduced by force. Notwithftanding thefe difafters, Mathos pulhed on the fiege of Hippo with great vigour, and appointed Spendius and Autaritus, commanders of the Gauls, with a ftrong body, to obferve the motions of Hamilcar. Thefe two commanders, therefore, at the head of a choice detachment of 6000 men drawn out of the camp at Tunis, and 2000 Gallic horfe, attended the Carthaginian general, approaching him as near as they could with fafety, and keeping clofe to the fkirts of the mountains. At laft Spendius, having received a ftrong reinforcement of Africans and Numidians, ■and poflefling himfelf of all the heights furrounding the plain in which Hamilcar lay encamped, refolved r.ot to let flip fo favourable an opportunity of attack- ing him. Had a battle now enfued, Hamilcar and his army muft in all probability have been cut off; Vou JV. Part 1. I ] CAR but by the defertlon of one Naravafus, a young Nu- Carthag*. midian nobleman, with 2600 men, he found himfelf vr— ' enabled to offer his enemies battle. The fight was - - 95 obftinate and bloody ; but at laft the mercenaries were Mercena- ries agaia entirely overthrown, with the lofs of 1 0,000 men kill- defeated, ed and 4000 taken ptjfoners. All the prifoners that were wiUing to inhft in the Carthaginian fervice, Ha- milcar received among his troops, fupplying them with the arms of the foldiers who had fallen in the engage- ment. To the reft he gave full Hberty to go where they pleafed ; upon condition that they ftiould never for the future bear arm.s againft the Carthaginians; in- forming them at the fame time, however, that as many violators of this agreement as fell into his hands muft expeft to find no mercy. ^5 Mathos and his aflbciates, fearing that this afFefted Tbey put ■ lenity of Hamilcar might occafion a defection among '° ^^^'^^ the troops, thought that the beft expedient would be-g^j^if^ "J^^ to put them upon fome adtion fo execrable in its na-foners. ture that no hopes of reconciliation might remain. By their advice, therefore, Gifco and all the Carthagi- nian prifoners were put to death ; and when Hamil- car fent to demand the remains of his countrymen, he received for anfwer, that whoever prefumed hereafter to come upon that errand, fliould meet with Gifco's fate : after which they came to a refolution to treat with the fame barbarity all fuch Carthaginians as fliould fall into their hands. In return for this enor- mity, Hamilcar threw ah the prifoners that fell into his hands to be devoured by wild beafts ; being con- vinced that compaflion ferved only to make his ene- mies more fierce and untraAable. The war was now carried on generally to the ad- vantage of the Carthaginians; neverthelefs, the male- contents ftill found themfelves in a capacity to take the field with an army of 50,000 men. They watch- ed Hamilcar's motions ; but kept on the hills, care- fully avoiding to come down into the plains, on ac- count of the Numidian horfe and Carthaginian ele- phants. Hamilcar, being much fuperior in flcill to any of their generals, at laft flint them up in a poft fo fituated that it was impoflible to get out of it. Here he kept them ftrictly befieged : and the mercenaries^ not daring to venture a battle, began to fortify their camp, and furround it with ditches and intrenchments. They were foon prefled by famine fo forely, that they They are were obliged to eat one another: but they were driven befieged by defperate by the confcioufnefs of their guilt, and there- fore did not defire any terms of accommodation. At lalt, being reduced to the utmoft extremity of mifery, they infifted that Spendius, Autaritus, and Zarxas, their leaders, fliould in perfon have a .conference with Hamilcar, and make propofals to him. Peace was' accordingly concluded upon the following terms, 'viz. That ten of the ringleaders of the malecontents fliould be left entirely to the mercy of the Carthaginians ; and that the troops fliould all be difarmed, every man re- tiring only in a fingle coat. The treaty was no fooner concluded, than Hamilcar, by virtue of the firft article, feized upon the negociators themfelves, and the army being informed that tJieir chiefs were under arreft, had immediately recourfe to arms, as fufpefting they were -o betrayed ; but Hamilcar, drawing out his army in or- 40,000 oS der of battle, furrounded them, and either cut them to them de- C c pieces, ftroyed. 99 Hannibal taken and GAR [20 Carthage, pieces, or trod them to death with his elephants. The ^-'-~\'-^ number of wretches who perifhed on this occafion a- mounted to above 40,000. After the deftru6lion of this army, Hamilcar in- vefted Tunis, whither Mathos had retired with all his remaining forces. Hamilcar had another general, named Hannibal, joined in the command with him. Hannibal's quarter was on the road leading to Car- thage, and Hamilcar's on the oppofite fide. The army was no fooner encamped, than Hamilcar caufed Spendius, and the reft of the prifoners, to be led out in the view of the befieged, and crucified near the walls. Mathos, however, obferving that Hannibal did not keep fo good a guard as he ought to have done, made a fally, attacked his quarters, killed many of his men, took feveral prifaners, among whom was Hanni- bal himfelf, and pliindered his camp. Taking the crucified by body of Spendius from the crofs, Mathos immediately Mathos. fubftituted Hannibal in its room ; and 30 Carthagi- nian prifoners of diftindlion were crucified around him. Upon this difafter, Hamilcar immediately decamped, and pofted himfelf along the fea-coaft, near the mouth of the river Bagrada. The fenate, though greatly terrified by this unex- pefted blow, omitted no means neceffary for their prefervation. They fent 30 fenators, with Hanno at their head, to confult with Hamilcar about the proper meafures for putting an end to this unnatural war, conjuring, in the moil preffing manner, Hanno to be reconciled to Hamilcar, and to facrifice his pri- vate refentment to the public benefit. This, with fome difficulty, v,'as effedled ; and the two generals came to a full refolution to a£l in concert for the good of the pubHc. The fenate, at the fame time, ordered all the youth capable of bearing arms to be prefTcd into the fervice : by which means a ftrong rein- 100 forcement being fent to Hamilcar, he foon found him- Mathos en-felf in a condition to a£l offenfively. He now defeat- fe^fedl^iid enemy in all rencounters, drew Mathos into fre- taken prl- ambufcades, and gave him one notable over- fcncr. throw near Leptis. This reduced the rebels to the neceffity of hazarding a decifive battle, which proved fatal to them. The mercenaries fled almoft at the firft onfet ; moft of their army fell in the field of battle, and In the purfuit. Mathos, with a few, efcaped to a Reighbouring town, where he was taken alive, carried to Carthage, and executed ; and then, by the reduc- tion of the revolted cities, an end was put to this war, which, from the excelTes of cruelty committed in it, according to Polybius, went among the Greeks by the l»me of the inexpiable tvar. During the Lyblan war, the Romans, upon fome abfurd pretences, wrefted the IfTand of Sardinia from the Carthaginians ; which the latter, not being able to. Hamilcar's refift, were obliged to fubmit to. Hamilcar finding fcheme to feis country not in a coudition to enter into an imme- «qual Car- diate war with Rome, formed a fcheme to put it on a Rome^"*^ level with that haughty republic. This was by making an entire conquell of Spain, by which means the Car- thaginians might have troops capable of coping with tlie Romans. In order to facilitate the execution of this fcheme, he infpired both his fon-in-law Afdrubal, and his fon Hannibal, with an implacable averfion to the Romans, as the great oppofers of his country's grandeur. Having completed all the necelTary prepa- 1 CAR rations, Hamilcar, after having greatly enlarged the Carth'.ge. Carthaginian dominions in Africa, entered Spain, » — ' where he commanded nine years, during which time he fubdued many warlike nations, and amafled an im- menfe quantity of treafure, which he diftributed partly amongft his troops, and partly amongft the great men at Carthage ; by which means he fupported his interefts with thefe two powerful bodies. At laft, he was killed in a battle, and was fucceeded by his fon-in-law His deatli. Afdrubal. This general fully anfvvered the expedla- tions of his countrymen ; greatly enlarged their do- minions in Spain ; and built the city of New Carthage, now Carthagena. He made fuch progrefs In his con- quefts, that the Romans began to grow jealous. They did not, however, choofe at prefent to come to an open rupture, on account of the apprehenfions they were under of an invafion from the Gauls. They judged It moft proper, therefore, to have recourfe to milder methods ; and prevailed upon Afdrubal to conclude a Afdrubal's new treaty with them. The articles of it were, '""^^'y ^itii 1 . That the Carthaginians fiiould not pafs the Iberus. ^^an^'^' 2. That the Saguntines, a colony of Zacynthians, and a city fituated between the Iberus and that part of Spain fubjeft to the Carthaginians, as well as the other Greek colonies there, fhould enjoy their ancient rights and privileges. ^04 Afdrubal, after having governed the Carthaginian He is mur- dominions In Spain for eight years, was treacheroufly '^'^"'^'i* murdered by a Gaul whofe mafter he had put to death. Three years before this happened, he had written to Carthage, to defire that young Hannibal, then twenty- two years of age, might be fent to him. This requeft was complied with, notwithftanding the oppofition of Hanno ; and from the firft arrival of the young man in the camp, he became the darling of the whole army. The great refemblance he bore to Hamilcar, rendered him extremely agreeable to the troops. Every talent and qualification he feemed to poflefs that can con- tribute towards forming a great man. After the death of Afdrubal, he was faluted general by the army with the higheft demonftratlons of joy. He Im- Succeeded mediately put himfelf in motion: and. In the firft by Haimi- campaign, conquered the Olcades, a nation feated near|^^^,^^^J^^^j^ the Iberus. The next year he fubdued the Vaccael, ^.Q^quefts another nation in that neighbourhood. Soon after, in Stjaiiu the Carpa;tani, one of the moft powerful nations in Spain, decJared againft the Carthaginians. Their ar» my^onfifted of 100,000 men, with which they pro^ pofed to attack Hannibal on his return from the Vaccaei j but by a ftratagem they were utterly defeat- ed, and the whole nation obliged to fubmit. Nothing now remained to oppofe the progrefs of the Carthaginian arms but the city of Saguntum. Hannibal, however, for fome time, did not think pro- per to come to a rupture with the Romans by attack- ing that place. At laft he found means to embroil fome of the neighbouring cantops, efpecially the Tur- detani, or, as Applan calls them, the Torboleta^ with He attacks the Saguntines, and thus furnifhed himfelf with a pre Saguntum^ tence to attack their city. Upon the commencement of the fiege, the Roman fenate difpatched two am- baffadors to Hannibal, vrith orders to proceed to Car- thage In cafe tlie general refufed to give them fatisfac— tion. They were fcarce landed, when Hannibal, who< was carrying on the fiege of Saguntunj with great. S vigour,. CAR 107 T08 Jart^age. vigour, fent them word that he had fomething elfe to do) than to give audience to ambafladors. At laft, however, he admitted them ; and, in anfwer to their remonftrances, told them, that the Saguntines had dr awn their misfortunes upon themfelves, by commit- ting hoftilitits againft the allies of Carthage ; and at th e fame time defired the deputies, if they had any co)mplaints to make of him, to carry them to the fe- naite of Carthage. On their arrival in that capital, th.ey demanded that Hannibal might be delivered up tO' the Romans to be puniflied according to his deferts ; anid this not being complied with, war was immedi- ately declared between the two nations. The Saguntines are faid to have defended the- - fe.lves for eight months with incredible braveiy. At Andiakes ^^-^t however, the city was taken, and the inhabitants were treated with the utmoft cruelty. After this con- queft, Hannibal put his African troops into winter- quarters at New Carthage ; but in order to gain their affedlion, he permitted the Spaniards to retire to their rei^eftive homes. The next campaign, having taken the neceffary meafures for fecuring Africa and Spain, he pafTed the Iberus, fubdued all the nations betwixt that river and the Pyrenees, appointed Hanno commander of all the e i'ets out new conquered diftrift, and immediately began his r Italy, miarch for Italy. Upon muftering his forces, after they had been weakened by fieges, defertion, morta- lity, and a detachment of 10,000 foot and icoo horfe left with Hanno to fupport him in his new poft, he fo)und them to amount to 50,000 foot and 9000 horfe, all veteran troops, and the beft in the world. As they had left their heavy baggage with Hanno, and wiere all light armed, Hannibal eafily crofTed the Py- renees ; pafled by Rufcino, a frontier town of the Gauls; and arrived on the banks of the Rhone with- out oppofition. This river he pafTed, notwithftand- ing of fome oppofition from the Gauls ; and was for fome time in doubt whether he (hould advance to en- gage the Romans, who, under Scipio, were bending their march that way, or continue his march for Italy. But to the latter he was foon determined by the ar- rival of Magilus prince of the Boii, who brought rich prefents with him, and offered to condu£t the Cartha- ginian army over the Alps. Nothing could have hap- pened more favourable to Hannibal's affairs than the arrival of this prince, fince there was no room to doubt the fincerity of his intentions. For the Boii bore an innplacable enmity to the Romans, and had even come to an open rupture with them upon the firil news that Italy was threatened with an invafion from the Car- thaginians. It is not known with certainty where Hannibal began to afcend the Alps. As foon as he began his march, the petty kings of the country affembled their forces in great numbers ; and taking poffeflion of the eminences over which the Carthaginians muft neceffa- rily pafs, they continued harafling them, and were no fooner driven from one eminence than they felzed on another, difputing every foot of land with the enemy, and deflroying great numbers of them by the advan- tage they had of the ground. Hannibal, however, having found means to poffefs himfelf of an advanta- geous pofl, defeated and difperfed the enemy ; and foon after took their capital city, where he found the [ J CAR 109 Ffe crofles he Alps. prifoners, horfes, Sec. that had before fallen into the Carthage* han^ds of the enemy, and likewlfe corn fufncient to v— ferve the army for three days. At laft, after a moil fatiguing march of nine days, he arrived at the top of the mountains. Here he encamped, and halted two days, to give his wearied troops fome repofe, and to wait for the ftragglers. As the fnow was lately fallen in great plenty, and covered the ground, this fight ter- rified the Africans and Spaniards, who were much af- fefted with the coldi In order therefore to encourage them, the Carthaginian general led them to the top of the higheft rock on the fide of Italy, and thence gave them a view of the large and fruitful plains of Infu- bria, acquainting them that the Gauls, whofe country they faw, were ready to join them. He ahb pointed out to them the place whereabout Rome ftood, telKngf them, that by climbing the Alps, they had fcaled the walls of that rich metropolis ; and having thus anima- ted his troops, he decamped, and began to defcend the mountains. The difficulties they met with In their defcent were much greater than thofe that had occur- red while they afcended. They had indeed no enemy to contend with, except fome fcattered parties that came to fteal rather than to fight ; but the deep fnows, the mountains of ice, craggy rocks, and frightful preci- pices, proved more terrible than any enemy. After they had for fome days marched through narrow, fleep, and flippery ways, they came at laft to a place which nei- ther elephants, horfes, nor men, could pafs. The way which lay between two precipices was exceeding nar- row ; and the declivity, which v/as very fteep, had be- come more dangerous by the falling away of the earth. Here the guides flopped ; and the whole ar- my being terrified, Hannibal propofed at firft to march round about, and attempt fome other way : but all places round him being covered with fnow, he found himfelf reduced to the neceffity of cutting a way into the rock itfelf, through which his men, horfes, and elephants, might defcend. This work was accom- plifhed with Incredible labour; and then Hannibal^ having fpent nine days in afcending, and fix In de- fcending, the Alps, gained at length Infubria ; and, notwithftanding all the difafters he had met with by the way, entered the country with all the boldnefs of a conqueror. Hannibal, on his entry Into Infubria, reviewed his army, when he found that of the 50,000 foot with whom he fet out from New Carthage five months and 15 days before, he had now but 20,000, and that his 9000 horfe were reduced to 6000. PIIs firft care, after he entered Italy, was to refrefa his troops ; who after fo long a march, and fuch Inexpreffible hard- fhips, looked like as many flceletons raifed from the dead, or favages born in a defert. He did not, how- ever, fuffer them to languifh long In idlenefs ; but, joining the Infubrlans, who were at war with thcTaurinum Taurlnians, laid fiege to Taurlnum, the only city in taken, the country, and in three days time became matter of it, putting all who refifted to the fword. This ftruck the neighbouring barbarians with fuch terror, that of their own accord they fubniltted to the conqueror, and fupplied his army with all forts of provifions. Scipio, the Roman general, In the mean time, who had gone in queft of Hannibal on the banks of the Rhone, was furprlfed to find his antagonift had crof- C c i ed CAR [ 204 ] Caf thagc. fed the Alps and entered Italy. He therefore return- viaory ed with the utmoft expedition. An engagement en- fued near the river Ticinus. in which the Romans were defeated. The immediate confequence was, that Scipio repaired that river, and Hannibal continued his -march to the banks of the Po. IrTere he ftaid two CAR Hannibiil in the mean time kept on, ftiH Carthage.' advancing towards Rome, having Cortona on the left hand, and the lake Thrafymenus on the right ; and at lalt, having drawn Flaminius into an ambu- fcade, entirely defeated him. The general hiinfelf, with 15,000 of his men, fell on the field of battle. days; before he could crofs that river over a bridge of A great number were likewife taken prifoners, and They are a gain defeat ed. boats. He then fent Mago in purfuit of the enemy, who having rallied their fcattered forces, and repafled the Po, were encamped at Placentia. Afterwards having concluded a treaty with feveral of the Gallic cantons, he joined his brother with the reft of the army, and again offered battle to the Romans : but this they thought proper to decline ; and at laft the conful, being intimidated by the defertion of a body of Gauls, abandoned his camp, pafTed the Trebia, and pofted himfelf on an eminence near that river. Here he drew lines round his camp, and waited the arrival of his colleague with the forces from Sicily. Hannibal being apprifed of the conful's departure, fent out the Numidian horfe to harafs him on his march ; himfelf moving with the main body to fup- port them in cafe of need. The Numidians arriving before the rear of the Roman army had quite paf- fed the Trebia, put to the fword or made prifoners all the ftragglers they found there. Soon after, Han- nibal coming up, encamped in fight of the Roman army, on the oppofite bank. Here having learned •the character of the conful Sempronius lately arrived, he foon brought him to an engagement, and entirely a body of 6000 men, who had fled to a town in Etru-- ria, furrendered to Maherbal the next day. Hanni- bal loll only 1 500 men on this occafion, moft of whom were Gauls ; though great numbers, both of his foldiers and of the Romans, died of their wounds.- Being foon after informed that the conful Servilius had A Roman ■ detached a body of 4000, or, according to Appian, ^''^'■^-'I'^tn 8000 horfe from Ariminum, to reinforce his colleague ^j'^^^^^ in Etruria, Hannibal fent out Maherbal, with all the taken, cavalry, and fome of the infantry, to attack him. The Roman detachment confifted of chofen men, and was commanded by Centenius a Patrician. Maher- bal had the good fortune to meet with him, and after a fhort difpute entirely defeated him. Two thoufand of the Romans were laid dead on the fpot ; the reft,, retiring to a neighbouring eminence, were, furround-^ ed by Maherbal's forces, and obliged next day to fur- render at difcretion ; and this difafter, happenings within a few days after the defeat at the lake Thrafy- menus, almoft gave the finifhing ftroke to the Roman affairs. The Carthaginian army was now fo much troubled, with a fcorbutic diforder, owing to the unwholefome defeated him. Ten thoufand of the enemy retired encampments they had been obliged to make, and to Placentia ; but the reft were either killed or taken the moralfes they had pafTed through, that Hanmbal 3x3 They are litter! y de- feated near the lake Thrafyme- nus. found it abfolutely neceffary to repofe them for fome time in the territory of Adria, a moll pkalanl and fertile country. In his various engagements, v/itli the. Romans, he had taken a great number of their arms^ with which he nov/ armed his men after the Roman- manner. Being now Hkewife mafter of that part of the country bordering on the fea, he found means to. fend an exprefs to Carthage with the news of tb?; glo- ■ rious progrcfs of his arras. The citizens received this news with the moft joyful acclamations, at the fame time coming to a refolution to reiirforx;e their ar- mies both in Italy and Spain with a proper number of troops. The Romans- being now in the utmoft confterna- Fahius M- tion, named a dictator, as was their cuftom in times ^'^^'^^.'^-^ of great danger. The pcrfon they-chofe to this of- j.^^.^ fice was Fabius Maximus, furnamed Verrucofus ; a. man as cool and cautious as Sempronius and Flaminius; were warm and impetuous. He fet out with a defign prifoners. The Carthaginians purfued the flying Ro- mans as far as the Trebia, but did not think pro- per to repafs that river on account of the exceffive cold. Hannibal, after this aftion upon the Trebia, or- dered the Numidians, Celtiberians, and Luhtanians, to make ineurfions into the Roman territories, where they committed great dcvaftationsi . During his ftate of inaftion, he endeavoured to win the-affeftions of the Gauls, and Hkewife of the allies of the Romans ; declaring to the Gallic and Itahan prifoners, tliat he had no intention of making war upon them, being determined to reftore them to their liberty, and pro- ted them againft the Romans : and to confirm them in their good opinion of him, he- difmifled them all without ranfom. Next year, having Grofled the Apennines, and pe* netrated intt) Etruria, Hannibal received intelligence that the new conful Flaminius lay encamped with the Roman army under the walls of Arretium. Ha- _ , l. ■ • ving learned the true charader of this general, that not to engage Hannibal, but only to watch his motions, he was of an haughty, fierce, and rafli difpofition, he and cut off his provifions,;which he knew was the moft doubted not of being foon able to bring him to a proper way to deftroy him in a country fo iar from battle. To inflame the impetuous fpirit of Flami- his own. Accordingly he followed him through Urn-; nius, the Carthaginian general took the road to Rome,, bria and Picenum, into the territory ol Adna, and and, leavincr the Roman army behind him, deftroyed then through the territories of the Marrucini and Fren-, all the country through which he pafl'ed with fire and tani into Apulia. When the enemy marched,, he fol-; fword ; and as that part of Italy abounded with all lowed them ; when they encamped, he did the. fame ; the elegancies as well as necefl"ar-ies of life, tiie Ro- but for the moft part on eminence's, and at fome dif-. mans and their allies fuffered an incredible lofs on tance from their camp, watcliing all their motions,, this occafion. The rafh conful was inflamed with cutting off their ftragglers, and keeping them in a con-, the utmoft rage on feeing the ravages committed by tinual alarm. This cautious method of proceeding, the Carthaginians ; and therefore immediately ap- greatly diftreffed the Carthaginians, but at the fama prouched tbem with great temerity, as if certain of time- raifcd difcoiatents in hi& own army. Butiieith^x CAR r th'efe difcontents, nor the ravages committed by Han- nibal, could prevail upon Fabius to alter his meafures. The former, therefore, entered Campania, one of the fineft countries of Italy. The ravages he committed there, raifed fuch complaints in the Roman army, that the diftator, for fear of irritating his foldiers, was obliged to pretend a defire of coming to an engage- ment. Accordingly he followed Hannibal with more expe dition than ufual ; but at the fame time avoided, under various pretences, an engagement with more care than the enemy fought it. Hannibal finding he could not by any means bring the diftator to a battle, refolved to quit Campania, which he found abound- ing more with fruit and wine than corn, and to re- turn to Samnium through the pafs called Eribanus. Fab£us concluding from his march that this was his defi^n, got there before him, and encamped on Mount Callicula, which commanded tlie pafs, after having placed feveral bodies in all the avenues leading to it. Hannibal was for fome time at a lofs what to do ; but at laft contrived the following ftratagem, which Fabius could not foi efee nor guard againft. Being encamped at the foot of Mount Callicula, he ordered Afdrubal to pick out of the cattle taken in the coun- try, 2000 of the ftrongeft and nimbleft oxen, to tie faggots to their horns, and to have them and the herdfmeu ready without the camp. After fupper, when all was quiet, the cattle were brought in good order to the hill, where Fabius had placed fome Ro- man parties in arabufh tcT Hop up the pafs. Upon a. lignal given, the faggots on the horns of the oxen were fet on fire ; and the herdfmen, fuppoited by fome battalions. armed with fmall javelins, drove them on quietly. The Romans feeing the light of the fires, imagined that the Carthaginians were marching by torch-light. However, Fabius kept clofe in his camp, depfending on the troops he had placed in am- bufcade ; but when the oxen, feeling the fire on their heads, began to run, up and down the hills, the Ro- mans in ambuili thinking themfelves furrounded on all fides, and climbing the ways where they faw leall light, returned to their camp leaving the pafs. open to Hannibal. Fabius, though ralHed by his foldiers for being thus over-reached by the Carthaginian, ftill con- tinued to purfue the fame plan, marched direftly after Hannibal, and encamped on fome eminences near him. Soon after this, the diftator was recalled to Rome ; and as Hannibal, notwithltanding the terrible ravages he had committed, had all along fpared the lands of Fabius, the latter was fufpeAed of holding a fecret cor.- rcfpondence with the enemy. In his abfence, Minu- cius, the general of the horfe, gained fome advantages, which greatly tended to increafe the difcontent with the dictator, infomuch that before his return Minur cius was put upon an equal footing with himfelf. The general of the horfe propofed that each Ihould com- mand his day ; but the diftator chofe rather to divide the army, hoping by that means to fave atleaft a part iiiuciusin^^ it. Hannibal foon found means to draw Minucius at dan- to an engagement, and, by his mafterly fliill in laying > '■e- ambufhes, the Roman general was furrounded on tive- )iir^^ ry fide, and would have been cut off with all his troops, had not Fabius. haftened to his aliiftanccj aad relieved 205 ] CAR him. Then the two armies uniting, advanced in good Carthage. order to renew the fight : but Hannibal, not caring ' ' to venture a fecond adion, founded a retreat, and re- tired to his camp ; and Minucius, being afhamed of his rafhnefs, refigned the command of the army to Fabius. 118 The year following, the Rom.ans augmented their The Ro- army to 87,000 men,, horfe and foot; and Hannibal m^^"' ^'t'fP" being reduced to the greatell flraits for want of pro- defeated yilions, v^lolved to leave Samnium, and penetrate ' into the heart of Apulia. Accordingly he decamped in the night ; and by leaving fires burning, and tents Handing in his camp, made the . Romans' beHeve for fome time that his retreat was only feigned. V/hen the truth was difcovered, ^milius was againft pur- fuing him : but Terentius, contrary to the opinion of all the officers in the army, except the proconful Ser- vilius, was obftinatcly bent on following the enemy ; and overtook them at Cannae, till tliis time an obfcure' village in Apuha*. A battle enfued in this place, as * See Ca«^ - memorable as any mentioned in hittory ; in which the.'"** Romans, though ahnoft double in number to the Car- thaginians, were put to flight with mofl; terrible llaugh- ter ; at leall 45,000 of them being left dead on the field of battle, and 10,000 taken priloners in the aftion or purfuit. The night was fpent in Hainiibal's camp in feaiting and rejoicings, and next day in ftripping the dead bodies of the uniiappy Romans ; alter which the vidtorious general in vefted .their two camps, where he found 4000 men. The immediate confequence of this vidory, as Han^ConSuen^. nibal had forefeen, was a difpofition of that part of I- ces of th» taly called the Old province, Magna Grecia, Tarcn-viiilory^ tum, and part of the territory of Capua, to fubmit to him. The neighbouring provinces hkewife ^difcovered an incliuation to fhake off the Roman yoke, but want-- ed firft to fee whether Hannibal was able to protctl; them. His firft march was into Samnium, being in- formed that the Hirpini and other neighbouring na- tions were difpofed to enter into an alliance with the Carthaginians. He advanced to Compfa, which opened its gates to him. In this place he left his heavy bag- gage, as well as the immcnfe plunder he had ac quired. After which he ordered his brother Mago with a body of troops deftined for that purpofe to pof- fefs himfelf of all the fortreffes in Campania, the mofl delicious province of Italy. The humanity Hannibal had all along fhown the Italian prifoners, as well as the fame of the complex vidtory he had lately obtain- ed, wrought fo powerfully upon the Lucani, Brutii, and Apuhans, that they expreffed an eager defire of being taken under his procedlion. Nay, even the Campanians themfelves, a nation m.ore obliged to the Romans than any in Italy, except the l.atins, difco- vered an inchnation to -abandon their natural friends. Of this the Carthaginian general receiving intelligence, capuffub»^ he bent his- march towards Capua, not doubting, butmitiito tliat,, by means of the popular fadfion there, he fhould HannibaL- eafiiy make himfelf mafler of it ; which accordingly happened. Soon after this place had made its fub- million, many cities of the Brutii opened their gates to Hannibal, who ordered his brother Mago to take poffefiion of _ them. Mago was then difpatched to Carthage, with the important news of the victory at Canna, and the confcquences attending iL Upor. GAR t 206 1 CAR Oerthage. his arrival there, he acquainted the fenatc, that Hanni- 20,000 foot and 4000 hotfe there. Had this ample CartTiage, bal had defeated fix Roman generals, four of whom fapply been fent with proper expedition, it is by no v '■' were confuls, one diftator, and the other general of means probable that the Romans would have had any horfe to the diftator : that he had engaged fix con- occafion to refleft upon Hannibal's conduft at Capua. That general would undoubtedly have obliged the haughty republic to fubmit to the fupcrior force of hia arms the next campaign. But, notwithftanding the influence of the Barcinian faftion at Carthage, Hanno and his adherents found means not only to retard the march of the fupplies intended, but even to diminirtl fular armies, killed two confuls, wounded one, and driven another out of the field with fcarce 50 men to attend him: that he had routed the general of the horfe, who was of equal power with the confuls ; and that the dictator was edeemed the only general fit to command an army, merely becaufe he had not the courage to engage him ; and as a demonftrative proof their number. Mago, through the artifices of that Hannibal fuperior to every other general mentioned ia hiftory. »i3 Caufe of the decline of his af- fairs. of whAt he advanced, he produced, according to fome authors, three bafliels and an half of gold rings, taken from knights and fenators who had been killed in the various engagements. Hitherto we have feen Hannibal furprifingly vlflo- rious ; and, Indeed, if we confider what he had already done, we (hall find his exploits fuperior to thole of any other general, either ancient or modern. Ocher commanders have been celebrated for viftories gained over barbarous and uncivilized nations. Alexander the Great invaded and over-ran the empire of Perfia ; but that kingdom was then funk in floth and effemi- nacy, fo as to be an eafy conqueft : but had the great commander turned his arms againil the weftern nations, who were of a more martial difpofition, it is more than probable he had not conquered fo eafily. Hannibal, on the other hand, lived at a time when the Romans Vere not only the moll powerful, but the molt warlike nation in the whole wprld. That nation he attacked with an army of only 26,000 men, with- out refourccs either for recruits, money, or provi- Tions, except what he could procure in the enemies country. With thefe he had for three years refilled the Roman armies, which had been hitherto invinci- ble by all other nations. Their armies had been com- manded by generals of dilferent tempers, difpofitions, and abilities : the lofles they fuftained are by the Roman writers Imputed to the faults of the generals themfelves ; but experience had abundantly Ihown, that thefe commanders, with all their faults, were able to conquer the moft warlike nations, when command- ed by another than Hannibal. In the battleb fought with the Romans he had deftroyed 200,000 of their men, and taken 50,000 prifonera; yet from the time of the battle of Cannse, the affairs of this great man totally declined. The reafon of this Is, by the Roman hlftorians, faid to be, that when he put his army into winter-quarters in Capua, he fo enervated himfelf and his army by debaucheries in that place, that he be- came no longer capable of coping with the Roman forces. But this feems by no means to have been the cafe ; for the Roman hlftorians themfelves own, that, after the battle of Cannas, he gave their armies many and terrible defeats, and took a great number of towns in their fight. The true reafon of that reverfe of fortune which Hannibal now experienced, was his not having luf- Eclent refources for recruiting his army. On the firft news, indeed, of his fuccefs at Carthage, a body of 4000 Numidian cavalry, 40 elephants, and loco talents of filver, were granted by the fenate. A large de- tachment of Spanilh forces was alfo appointed to fol- low them ; and that thefe laft might be ready in due time, Mago fet out immediately for Spain to raife infatuated party, could obtain an order for only 12,000 foot and 250c horfe, and even with this incon- fiderable body of troops he was fent Into Spain. Han- nibal being thus deferted by his country, found him- felf obhged to a6l on the defenfive ; his army amount- ing to no more now than 26,000 foot and 9000 horfe. But though obliged to aft in this manner, he was only hindered from conquering ; the utmoft efforts of the whole Roman power not being able to drive this fmall army out of Italy for more than 14 years. j^^- The Romans, though greatly reduced, were not Meafures yet exhaufted. They were able Hill to fend two con- taken by fular armies into the field, fully recruited and in good*^^^ order ; and as neither the Gauls nor Italians were na-"*'^'^*" tural allies of the Carthaginians, they did not fail to abandon them on the firft reverfe of fortune. After the Romans had recovered from the confternatlon in- to which they were thrown by the defeat at Cannae, tliey chofe a dictator, and recalled Marcellus, the con- queror of Syracuie, from Sicily. All the young Ro- mans, above 17 years of age, of what rank foever, were obliged to inlift themfelves ; as were alfo thofe who had already fcrved their legal time. By this means four legions and 1 0,000 horfe were foon raifed in the city. The allies of Rome, the colonics, and the mu- nicipla, furnifhed the contingence as ufual. To thefe were added 8000 of the youngeft and ftrongeft flaves in the city. The republic purchafed them of their matters, but did not oblige them to ferve without their own confent, which they gave, by anfwering F'ohf *• I am willing whence they were called wlones, to ■» dlftlngullh them from the other troops. As the Ro- mans, after the lofs of fo many battles, had no fwords, darts, or bucklers, left In their magazines, the volones were fupplled with the arms which had been formerly taken from the enemy, and hung up in the public temples and porticoes. The finances of Rome were no lefs exhaufted ; but this defeft was fupplled by the liberality of her citizens. The fenators (bowing the ex- ample, were followed firft by the knights, and after- wards by all the tribes ; who ftripping themfelves of all the gold they had, brought it to the public trea- fury. The fenators only referved their rings, and the bulla about their childrens necks. As for the filver coin, it was now, for the firft time, alloyed with cop- per, and increafed in its value. Thus the finances were put into a good condition, and a competent army raifed. This was plainly the laft effort the Romans could make ; and could Hannibal have procured a fufficlent fupply of men and money to enable him to cope with this army, and to break it as he had done the others before, there could have been no more refiftance made oil their part. He began> however, to be in want of money • »f peace. ia6 Afdrubal mans Spain, CAR [2 Carthige. money ; and to procure it, gave the Roman prifoners '> leave to redeem themfelves. Thefe unhappy men a- greed to fend ten of their body to Rome to negociate 125 their redemption ; and Hannibal required no other fe- riiey refufe curit.y for their return but their oath. Carthalo was to treat c^^^f aj- jj^g head of them to make propofals of peace ; but upon the firft news of his arrival, the didlator fent a liftor to him, commanding him immediately to de- part the Roman territory ; and it was refolved not to redeem the captives. Upon this Hannibal fent the moft confiderable of them to Carthage ; and of the reft he made gladiators, obliging them to fight with one another, even relations with relations, for the en- tertainment of his troops. All this time Cjielus and Publius Sclpio had car- defeated by ried on the war in Spain with great fuceefs agalnft the Ro- Carthaginians. Afdrubal had been ordered to en- ter Italy with his army to aflift Hannibal ; but being defeated by the Romans, was prevented. The dila- tor and fenate of Rome, encouraged by this news, carried on the preparations for the next campaign with the greateft vigour, whilft Hannibal remained in- aftive at Capua. This inaflion, however, feems to have proceeded from his expeftatlon of fuccours from Africa, which never came, and which delay occafioned his ruin. The Roman diftator now releafed from prifon all criminals, and perfons confined for debt, who were willing to inlift themfelves. Of thefe he formed a body of 6000 foot, armed with the broad fwords and bucklers formerly taken from the Gauls. Then the Roman army, to the number of about 25,000 men, marched out of the city, under the com- » Hiand of the dlAator ; while Marcellus kept the re- mains of Varro's army, amounting to about 15,000 men, at Cafillnum, in readinefs to march whenever there fhould be occafion. Thus the Roman forces were ftlU fuperlor to thofe of Hannibal ; and as they now faw the neceffity of following the example of Fabius Maximus, no engage- ment of any confequence happened the firft year after the battle of Cannae. Hannibal made a fruitlefs at- 137 tempt upon Nola, expefting it would be delivered up iiTarcellus to him ; h&t this was prevented by Marcellus, who had airi5 an ad- entered that city, and fallying unexpcftedly from three irer Hanrii- S^^^^ "P°" Carthaginians, obhged them to retire lal. in great confufion, with the lofs of 5000 men. This was the firft advantage that had been gained by the Romans where Hannibal had commanded in perfon, and raifed the fpirits of the former not a little. They were, however, greatly dejefted, on hearing that the confol Pofthumlus Alblnus, with his whole army, had been cut off by the Boli, as he was crolTing a foreft. Upon this it was refolved to draw all the Roman for- ces out of Gaul and other countries, and turn them agalnft Hannibal ; fo that the Carthaginian ftood daily more and more in need of thofe fuppHes, which yet never arrived from Carthage. He reduced, however, the cities of Nuceria, Cafillnum, Petelia, Confentla, Croton, Locri, and feveral others in Great Greece, before the Romans gained any advantage over him, ex- cept that before Nola already mentioned. The Cam- panians^ who had efpoufed the Carthaginian intereft, raifed an army of 14,000 of their own nation in fa- vour of Hannibal, and put one Marlus Alfius at the head o£ it ; but he was furgrifed by the conful Sem- 07 ] CAR pronius, who defeated and killed him, with 2000 of C'^rfhage. his men. It was now found, that Hannibal had con- ' eluded a treaty of alliance, ofFenfive and defenfive, with Philip king of Macedon ; but to prevent any diftur- bance from that quarter, a Roman army was fent to ,29 Macedon. Soon after this Marcellus defeated Han- He is f^jj coufuT and ordered to pafs into Africa ; and upon his arrival, the face of affairs was greatly changed. At the time of his entering the port of Utica, 3500 Romans were in great danger of being cut in pieces before Carthage. Thefe had feized Megaha, one of the fuburbs of the city : but as they had not furniihed themfelves with provifions to fubfiil there, and could not retire, being clofely inverted on all fides by the enemy's troops', the prtEtor Mancimis, who commanded this detachment, ieeing the danger into which he had brought himfelf, difpatched a light boat to Utica, to acquaint the Ro- mans theie with his fituation. jEmilianus received this letter a few hours after his landing ; and immediately flew to the relief of the befieged Romans, obliged the Carthaginians to retire within their walls, and fafely conveyed his countrymen to Utica. Having then drawn together all the troops, ^milianus apphed him- felf wholly to the fiege of the capital. His firft attack was upon Megalia ; which he car- ried by aflault, the Carthaginian garrifon retiring into the citadel of Byrfa. Afdrubal, who had comanauded 166 the Cai-thaginian forces in the field, and was now go- Cruelties of vernor of the city, was fo enraged at the lofs of Me- afdrubal. galia, that he caufed all the Roman captives taken in the two years the war lafted, to be brought upon the ramparts, and thrown headlong, in the fight of the Roman army, from tlie top of the wall ; after having, with an excefs of cruelty, commanded their hands and feet to be cut off, and their eyes and tongues to be torn out. He was of a temper remarkably inhuman, and it is faid that he even took pleafure in feeing fome of thefe unhappy men flayed alive, ^milianus, in the mean time, was bufy in drawing lines of circumvalla- tion and contravallation crofs the neck of land which joined the iflhmus on which Carthage ftood to the continent. By this means, all the avenues on the land- Car*ha>re fide of Carthage being ftiut up, the city could receive blocked up no proviJions that way. His next care was to raife a ^ea and mole in the fea, in order to block up the old port, the '^^'^* new one being already ftiut up by the Roman fleet ; and this great work he effefted with immenfe labour. The mole reached from the weftern neck of land, of which the Romans were mafters, to the entrance of the. port ; and was 90 feet broad at the bottom and 80 at the top. The befieged, when the Romans firft began this furprifing work, laughed at the attempt ; but were no^lefs alarmed than furprifed, when they beheld a vaft mole appearing above water, and by that means the port rendered inacceffible to fliips, and quite ufe- lefs. Prompted by defpair, however, the Carthagi- -pf^J^^j^ nians, with incredible and almoft miraculous induftry, ed dia;^'^^ dug a new bafon, and cut a paffage into the fea, by new bafon. which they could receive the provifions that were fent them by their troops in the field. With the fame di- ligence Carthage. ■~v— - 169 rhey fet 'ire to the R.oman ma- hines. fo Vaft fliugli er of the Carthagi- nians. 171 Cotlio ta- ken. CAR [2 Ugence and expedition, they fitted out a fleet of 50 triremes ; which, to the great furpriie of the Romans, appeared fuddenly advancing into the fea through this new canal, and even ventured to give the enemy battle. The adlion lafted the whole day, with little advantage on either fide. The day after, the conful endeavoured to make himfelf mafter of a terrace which covered the city on the fide next the fea ; and on this occafion the befieged fignalized themfelves in a mod remarkable manner. Great numbers of them, naked and unarmed, went into the water in the dead of the night, with un- lighted torches in their hands ; and having, partly by fwimming, partly by wading, got within reach of the Roman engines, they ftruck fire, lighted their torches, and threw them with fury aguinft the machines. The fadden appearance of thefe naked men, who looked like fo many monfters Itarted up out of the fea, fo ter- rified the Romans who guarded the machines, that tliey began to retire in the utrnofl confufion. The conful, who commanded the detachment in perfon, and had continued all night at the foot of the teiTace, endeavoured to Itop his men, and even ordered thole who fled to be killed. But the Carthaginians, per- ceiving the confufion the Romans were in, threw them- felves upon them like fo many wild beafts ; and having put them to flight only with their torchesf^they fet jirc to the machines, and entirely confumed them. This, however, did not difoourage the conful : he re- newed the attack a few days after, carried the terrace by affault, and lodged 4000 men upon it. As this was an important po'l, becaufe it pent in Carthage on thj fea-fide, jEmilianus took care to fortify and fe- cure it againft the failles of the enemy ; and then, winter approaching, he fufpended all further attacks upon the place till the return of good weather. Du- ring the winter feafon, however, the conful was not InaAive. The Carthaginians had a very numerous army under the command of one Diogenes, ftrongly encamped near Nepheris, whence convoys of provifions were fent by fea to the befieged, and brought into the new bafon. To take Nepheris, therefore, was to de- prive Carthage of her chief magazine. This yEmili- anus undertook, and fucceeded in the attempt. He "firft forced the enemy's entrenchments, put 70,000 of them to the fword, and made 10,600 prifoners ; all the inhabitants of the country, who could not retire to Carthage, having taken refuge in this camp. After this, he laid fiege to Nepheris, which was reduced in 22 days. Afdrubal being diflieartened by the defeat of the army, and touched with the mifery of the be- fieged now reduced to the utmoft extremity for want of provifions, offered to fubmit to what conditions the Romans pleafed, provided the city was fpared ; but this was abfolutely refufed. Early in, the fpring, iEmilianus renewed the fiege of Carthage ; and in order to open himfelf a way into the city, he ordered Ltellus to attempt the redudlion of Cotho, a fmall ifland which divided the two ports. iEmilianus himfelf made a falfe attack on tlie'citadel,, in order to draw the enemy thither. This ftratagem had the defired effeft ; for the citadel being a place of the greateft importance, moil of the Carthaginians haftened thither, and made their utmoft efforts to re- pulfe their aggreffors. But in the mean time Laelius liaving, with inctedible expedition, built a wooden 13 ] C A R bridge over tlie channel which divided Cotho from the Cart hage;^ ifthinus, entered the ifland, foaled the walls of the ^'"^ fortrefs which the Carthaginians had built there, and made himfelf mafter of that important poft. The pro- conful, who was engaged before Byrfa, no fooner un- derftood, by the loud fliouts of the troops of LaeHus, that he hud made himfelf mafter of Cotho, thap he ^ abandoned the falfe attack, and unexpeftedly fell on j^^^^;^^ ^^^^ the neighbouring gate of the city, which he broke ter the city, down, notwithftanding the fliowers of darts that were inceflantly difcharged upon his men from the ramparts. As night coming on prevented him from proceeding farther, he made a lodgment within the gate, and waited there for the return of day, with a defign to advance through the city to the citadel, and attack it on that fide which was but indifferently fortified. Pur- fiiant to this defign, at day-break he ordered 4000 frefh troops to be fent from his camp, and, having fo- lemnly devoted to the infernal gods the unhappy Car- thaginians, he began to advance at the head of his men, through the ftreets of the city, in order to at- tack the citadel. Having advanced to the market- place, he found that the way to the citadel lay through, three exceeding fleep ftreets. The houfes on both, fides were very high, and filled with Carthaginians, who overwhelmed the Romans as they advanced with darts and ftones ; fo that they could not proceed till they had cleared them. To this end jEmihanus in perfon, at the head of a detachment, attacked the firft houfe, and made himfelf mafter of it fword in hand. His example was followed by the officers and foldiers, who went on from houfe to houfe, putting all they met with to the fword. As faft as the houfes were cleared on both fides, the Romans advanced in order of battle towards the citadel ; but met v/ith a vigorous re- fiftance from the Carthaginians, who on this occafion behaved with uncommon refolution. From the market- place to the citadel, two bodies of men fought their way every ftep, one above on the roofs of the houfes, the other below in the ftreets. The flaughter was in- expreffibly great and dreadful. The air rung with fhrieks and lamentations. Some were cut in pieces, others threw themfelves down from the tops of the houfes ; fq that the ftreets were filled with dead and mangled bodies. But the deftruftion was yet greater, wi^jc^f when the proconful commanded fire to be fet to that fet on fire^ quarter of the town which lay next to the citadel. Incredible multitudes, who had efcaped the fwords of the enemy, perifhed in the flames, or by the fall of the houfes. After the fire, which lafted fix days, had de- moHlhed a fufficlent number of houfes, jEmilianus or- dered the rubbifh to he removed, and a large area to be made, where all his troops might have room to aft. Then he appeared v/ith his whole army before Byrfa; which, fo terrified the Carthaginians, who had fled thither for refuge, that firft of all 25,000 women, and then 30,000 men, came out of the gates in fuch- a conditit)n as moved pity. They threw themfelves proftrate before the Romair- general, aflcing no favour but life. This was readily granted, not only to them, but to all that were in Byrfa, except the Roman de- ferters, whofe number amounted to 900. Afdrubal's wife earneftly intreated her hufljand to fuffer her toCruebyand join the fuppliants, and carry with her to the pro- cowardic-.. conful her two fons, who v>'ere as yet very young ; ^^j'^^''^'' CAR [ 214 ] Carthage, but tlie barbarian denied her requell, and rejefted her quired ^""^ remonftrances with menaces. The Roman deferters feeing themfelves exchided from mercy, refolved to die f>vord in hand, rather than dchVer themfelves up to the vengeance of their countrymen. Then Afdrubal, find- ing them all refolved to defend themfelves to the lafl breath, committed to their care his wife and children ; after which he, in a moft cowardly and mean-fpirited manner, came and privately threw himfclf at the con- queror's feet. The Carthaginians in the citadel no fooner underftood that their commander had abandoned CAR on fuch occafions : he firft facrlficed to the Carthage, gods, and then caufed a plough to be drawn round the walls of the city. After this, the towers, ramparts, walls, and all the works which the Cnrthagfinians had 175 wife de- llroy= her- felf and two chiidiei'. 176 Ca- tliage, j-'Iiindcred, the place, than they threw open the gates, and put the Romans in pofTeflion of Byrf;'. They had now no enemy to contend with but the 900 deferters ; who, being reduced to defpair, retreated into the temple of JEfculapius, which was as a fecond temple within the firtt. There the proconiul attacked them ; and thefe unhappy wretches, finding there was n * way to efcape, fet fire to the temple. As the flames h.rcad, they re- treated from one part of the building to another, till they got to the roof. There Afdrubal's wife appeared in her bell apparel, and having uttered the moit bitter imprecations againil her hufband, whom flie faw Hand- ing below with yEmiUanus, " Bafe coward (laid ihe), the mean things thou haft done to fave thy life fhall not avail thee : thou fhalt die this inftant, at leaft in thy tvvo children." Having thus fpoken, ^he ftabbed both the infants with a dagger; and while tliey were yet ilruggling for hi^, threw them both from the top of the ten^ple, and then leaped down after them into the flames. jlimihanus dehvered up the city to be plundered, but in t})e manner prefcribed by the Roman military law. Tie foldiers were allowed to appropriate to themfeh-cs all the furniture, utenfils, and brafs money, they fliould find in private houfes : but all the gold and filver, the ftatues, pidures, &c. were referved to be put into the hands of the qujeftors. On this occa- fion the cities of Sicily, which had been often plundered by the Carthaginian armies, recovered a number of ftatues, pitlures, and other valuable monuments : a- inong the reft, the famous brafen bull, which Phalaris had ordered to be caft, and ufed as the chief inftru- ment of his cruelty, was reftored to the inhabitants of Agrigentum. As jEmiliaiuis was greatly incfined to fpare what remained of this ftately metropolis, he wrote to the iVnate on the fubjed, from ^vhom he received the following orders: i. The city of Carthage, w^ith Byrfa, and Megaiia, fliall be entirely deftroyed, and flo traces of them left. 2. Ail the cities that have lent Caithage any affiftance fliall be difmantled. 3. The territories of thofe cities which have declared for the Romans, fliall be enlarged with lands taken from the enemy. 4. All the lands between Hippo and Carthage fliall be divided among the inhabitants of Utica. 5. All the Africans of tlie Carthaginian Hate, both men and women, fliall pay an annual tribute to -the Romans at fo much per head. 6. The v.'hole country, which was fubjedl to the Cartliaginian ftate, fliaU be turned into a Roman province, and be governed by a prffitor, in the fame manner as Sicily. Lalcly, ■Rome flaall fend commifii oners into Africa, there to fettle jointly Avith the proconful the ftate of the new provinre. Before iEmihanus deftroyed the city, he performed thofe religious ceremonies vvhicli were rc- 177 And utter railed in the courie of many ages, and at a vaft ex- ed. pence, were levelled with the ground ; and laftly, fire was let to the edifices of the proud metropolis, which confumed them all, not a fingle houfe efcaping the flames. Though the fire began in all quarters at the fame time, and burnt with incredible fui:y, it con- tinued for 17 days before all the buildings were con- fumed. Thus fell Carthage, about 146 years before the birth of Chrift ; a city whofe deftruftion ought to be attributed more to the intrigues of an abandoned fac- tion, compofed of the moft profligate part of its citi- zens, than to the power of its rival. The treafure ^mihanus carried off, even after the city had been delivered up to be plundered by the foldiers, was im- menie, Pliny making it to amount to 4,470,000 pounds weight of filver. The Romans ordered Carthage ne- ver to be inhabited again, denouncing dreadful im- precations againft thofe who, contrary to this pro- hibition, fliould attempt to rebuild any part of it, e- fpecially Byrfa and Megaiia. Notwithftanding this, however^^about 24 years after, C. Gracchus, tribune Rebuilt, of the people, in order to ingratiate himfelf with them, undertook to rebuild it ; and, to that end, conduced thither a colony of 6000 Roman citizens. The work- men, according to Plutarch, were terrified by many unlucky omens at the time they were tracing the limits and hying the foundations of the new city ; which the fenate being informed of, would have fufpended the attempt. But the tribune, httle affefted with fuch prefages, continued to carry on the work, and finiflied it in a few days. From hence it is probable that only a flight kind of huts were ereft ed ; but, whether Gracchus executed liis defign, or the work was entire- ly difcontinued, it is certain, _that Cai thage was the firft Roman colony ever fent out of Italy. According to fome authors, Carthage was rebuilt by Juhus Ca;far ; and Strabo, who flourifiied in tlie reign of Tiberius, affirms it in his time to have been equal if not fupe- rior to any other city in Africa. It was looked upon as the capital of Africa for feveral centuries after the commencement of the Chrlftian rera. IMaxentius laid it in aflies aboutlhe fixth or feventh year of Conftan- tine's reign. Genferie, king of the Vandals, took it ITttcrl . .3 afterwards it was'-''"y " ' renowned ^^^'^ under Mohammed's hy the A. D. 439 ; but about a century re-annexed to the Roman empire Ikhfarins. At laft the Saracens, fuccelTors, towards the clofe of the feventh century, lo completely dellroyed it, that there are now fcarce any traces remaining. At the conmiencement of the third Punic war, Carthage appears to have been one of the firft cities in ^g^^ the v\".-rld. — It was feated on a peninfula 36oftadia orit^ ancient 45 mile^s in circumference, joined to the continent by grandeur, an ifthmus 23 ftadia or three miles and a furlong in breadth. On the weit fide there projefted from it a long tra£l ox land lialf a ftadium broad ; which flioot- ing out into the fea, feparated it from a lake er mo- rais, and was ftrongly fortified on all fides by recks and a iingle wall, in the mJddle of the city ftood the ci- tadel of Byrfa, having on the top of it a temulf facred to CAR [ 21 Carth?^e. to ^fculapius, feated upon rocks on a very high LllI, ''V~~~' to which the afceat was by 60 fteps. On the fouth fide the city was furrounded by a triple wall, cu- bits high ; flanked all round by parapets and towers, placed at equal ditlances of 480 feet. Every tower had its foundation funk 32 feet deep, . and was four ftories high, though the walls were but two : they were arched ; and, in the lower part, con-efponding in depth with the foundations above mentioned, were ftails large enough to hold 300 elephants with their fodder, &c. Over thefe were flails and other conve- niences for 4000 horfes; and there was likewife room for lodging 20,000 foot and 4000 cavalry, without in the kali incommoding the inhabitants. There were two harbours, fo difpofed as to have a communication with one another. They had one common entrance 70 feet broad, and fhut up with chains. The firil was appropriated to the merchants ; and included in it a vaft number of places of refrefhment, and all kinds of accommodations for feamen. The fecond, as well as the ilJand of Cothon, in the midft of it, was lined with large keys, in which were diftinft receptacles for fecuring and fheltering from the weather 220 iliips of war. Over thefe were magazines of all forts of naval Itores. The entrance into each of thefe receptacles was adorned with two marble pillars of the Ionic or- der ; fo that both the harbour and ifland reprefented on each fide two magnificent galleries. Near this ifland was a tem.ple of Apollo, in which was a ftatue of the god all of mafTy gold; and the inlide of the temple all lined with plates of the fame metal, weighing 1 000 talents. The city was 23 miles in circumference, and at the time we fpeak of contained 700,000 inhabitants. Of their power we may have fome idea, by the quan- tity of arms they delivered up to the Roman confuls. The whole army was aflonifhed at the long train of carts loaded witn them, which were thought fufBcient to have armed all Africa. At leaft it is certain, that on this occafion were put into the hands of the Ro- mans, 2000 catapults, 200,000 complete fuits of ar- mour, with an innumerable quantity of fwords, darts, javelins, arrows, and beams armed with iron which were thrown from the ramparts by the baliftas. The characler tranfmitted of the Carthaginians is extremel)' bad; but we have it only on the authority of the Romans, who being their implacable enemies cannot be much relied upon. As to their religion, manners, &c. being much the fame with the Phoeni- cians of which they were a colony, the reader is re- ferred for an account of thefe things to tke article Phoenicia. On the ruins of Carthage there now Hands only a linall village called Melcha. The few remains of Car- thage conlifl only of fome fragments of walls and 1 7 cifterns for the reception of rain-water. There are three eminences, which are fo many maf- fes of fine marbles pounded together, and were in all probability the lites of temples and other difiinguifh- ed buildings. The prefent ruins are by no means the remains of the ancient city deftroyed by the Romans ; who after taking it entirely erafed it, and ploughed up the very foundations: fo truly they adhered to the well-known advice perpetually inculcated by Cato the Elder, Delenda eft Carthago. It was again rebuilt by the Gracchi family, who conduced a colony to re- people it ; and continually increafing. in fplendour, it si CAR became at length the capital of Africa under the Ro- New-Car- man emperors. It /ublifted near 700 years after its,, '''^S*^' , r n ^ \- • m • • i i ii 11 1 Carthaecnaa nrit demolition, until it was entirely deltroyecl by the ^ ' , Saracens in the beginning of the 7th century. It is a fingular circiimllance that the two cities of Carthage and Rome flrould have been built juft op- pofite one to the other ; the bay of Tunis and the mouth of the Tiber being in a direil line. I/ittora liitoribus corJraria, Jludlbus nnclasy Anna armis. Virg. Mn. i. 4. ARTHAGEf a confiderablc town of Mexico, in the province of Collarica. It is a very rich trading place. W. Long. 86. 7. N. Lat. 9. 5. CARTHAGENA, a province of South America^ and one of the moft confiderable in New Cafiile, oa account of the great trade carried on by the capital ; for the country itfelf is neitlier fertile, rich, nor popu- lous. 1'he capital city, called likewife Cartbagcna, i$ fituated in W. Long. 77. N. Lat. 11. on a fandy ifland, by moil writers called a peninfula ; which, forming a narrow paffage on the fouth-weft, opens a communi- cation with that called Tierra Bomha, as far as Bocca Ch'ica. The little ifland which now joins them was- formerly the entrance of the bay ; but it having been filled up by orders of the court, Bocca Chica became the only entrance : this, how^ever, has been filled up- fince the attempt of Vernon and Wentworth, and the old paffage again opened. On the north fide the land is fo narrow, that, before the wall was begun, the diflance from fea to fea was only 35 toifes ; but afterwards enlarging, it forms another ifland on this fide ; fo that, excepting thefe two places, the whole city is entirely furrounded by falt-water. To the eaft- ward it has a communication, by means of a wooden bridge, with a large fuburb called Xeniarn, built on another ifland, which is alfo Joined to the continent by a bridge of the fam.e materials. The fortifications both of the city and fuburbs are built after the mo- dern manner, and lined with free-ftone ; and, in tfrne of peace, the garrifon conlifls of ten companies of 77 men each, befides militia. The city ar^d fuburbs are well laid out, the ftreets ftraight, broad, imlform, and- well paved. All the houles are built of flone or brick, only one ftor3/ high, well contrived, neat, and furnifh- ed with balconies and lattices of wood, which Is more durable in that climate than iron, the latter being f ioa corroded by the acrimonious quality of the iitmo-- fphere. The climate is exceedingly unhealthy., Tha Europeans are particularly fubjeft to the terrible dif— eafe called the black Vivvit, which fweeps off' multitudes annually on the arrival of the galleons. It feldoni continues above three or four days; in which time the patient is either dead or out of danger,, and if he reco- vers is never fubjeft to a return of the fame diflemper. — This dif cafe has hitherto foiled all the art of th-2- Spanifh phyficians ; as has alfo the ieprofy, which is very common here. At Carthagena, likewife, that painful tumour in the legs, occafioned by the entrance of the Dracvnculus or Guinea-worm, is veiy commoit and troublefome. Another diforder peculiar to this country, and to Peru, is occafioned by a httle infeft called N'lgua, fo extremely minute, as fcarce to be vi- fible to the naked eye. Thisinfedl breeds in the daft, inflnuates itfelf into the foles of the feet and the legs, piercing the Ikin with fuclx fubtilty, that there is no CAR [ 2 Carthag-err. Ijeing aware of" it, before it lias made it s way to tlie Carthannis fl^fli, Jf Jt is perceived in the begianing, it is extrafted ""^^ with little pain ; but having once lodged its head, and pierced the flcin , the patient muft undergo the pain of an incifion, without which a nodus would be formed, and a multitude of infefts ingendered, which would foon overfpread the foot and leg. One fpccies of the ni^ua is venomous ; and when it enters the toe, an inflam- matory fwelling, greatly refem.bling a vencrealbubo, takes place in the groin. CarthactEna, a fea-port town of Spain in the kingdom of Murcia, and capital of a territory of the fame name; built by Afdrubal, a Carthaginian general, and named after Carthage. It has the heft liarbour in all Spain, but nothing elfe very confiderable ; the bifhop's fee being transferred to Toledo. In 1706 iit was taken by Sir John Leak ; but the Duke of J3cnvick retook it afterwards. W.Long. 0.58. N. Lat. 37. 36. CARTHAMUS, in botany : A genus of the or- der of polygamia fpqualis, belonging to the fyngenefia clafs of plants, and in the natural method ranking un- der the 49th order, Compoftte. The calyx is ovate, imbricated with fcales, clofe below, and augmented with Tubovate foliaceous appendices at top. — Of this genus there are nine fpecies ; but the only remarkable one is the tinftorius, with a fafPron-coloured flower. This is a native of Egypt and fome of the warm parts of Afia. It is at prefent cultivated in many parts of Eu- rope, and alfo in the Levant, from whence great quan- tities of it are annually imported into Britain for the purpofes of dyeing and painting. It is an animal plant, and rifes with a ftffF ligneous ftalk, about two feet and a half or three feet in height, dividing up- wards into many branches, garniflied with oval point- ed leaves fitting clofe to the branches. The flowers grow fingle at the extremity of each branch ; the heads of the flowers are large, inclofed in a fcaly empalement; each fcale is broad at the bafe, flat, and formed like a leaf of the plant, terminating in a fharp fpine. 'The lower part of the empalement fpreads open ; but the fcales above clofely embrace the florets, which ai'e of a fine faffron colour, and are the part ufed for tlie purpofes above mentioned. The good quality of tlu's commodity is in the colour, which is of a bright faf- fron hue : and in this the Britifh carthamus veiy oft- en fails ; for if there happens much rain during the time the plants are in flower, the flowers change to a dark or dirty yellow, as they likewife do if the flowei"S are gathered with any moifl:ure remaining upon them. — The plants are propagated by feeds, which fhould be fown in drills, at two feet and a half diilance from one another, in which the feeds fhould be fcat- tered fingly. The plants will appear in lefs than a month ; and in three weeks or a month after, it will be proper to hoe the ground ; at which time the plants fhould be left fix inches diftant : after this they will require a fecond hoeing ; vi'hen they muft be thinned to the diftance at which they are to remain. If after this they are hoed a third time, they will require no farther care till they come to flower ; when, if the fafilower is intended for ufe, the florets fhould be cut off from the flowers as they come to perfeftion : but this muft be performed when they are perfeftly diy ; 5\nd then they flmuld be dried in a kiln with a mode- rate fire, in the fame manner as the true faffron. But N 66. 5 6 ] CAR in thofe flowers which are propagated for feeil?, the CarthuH florets mufl be cut oft", or the feeds will prove abor- tive. — The feeds of carthamus have been celebrated as a cathartic ; but they operate very flowly, and for the moft part diforder the ftomach and bowels, efpecially when given in fubftance : triturated with dillilled aro- matic waters, they form an emulfion lefs offenfive, yet inferior in efficacy to the more common purgatives. They are eaten by a fpecies of Egyptian parrot, which is very fond of them ; to other birds or beafts they would prove a mortal poifon. CARTHUSIANS, a religious order founded in the year 1080, by One Brudo. The Carthufians, fo called from the defert of Chartreiix, the place of their inftitution, are remarkable for the auflei-ity of their rule. They ai-e not to go out of their cells, except ti> church, without leave of their fuperior j nor fpeak to any perfoa without leave. They mufl not keep any portion of their meat or drink till next day ; their beds are of ftraw, covered with a felt ; their cloathing two hair-cloths, two cowls, two pair of hofe, and a cloke, all coarfe. In the refeftory, they are to keep their eyes on the difh, their hands on the table, their atten- tion on the reader, and their hearts fixed on God. Women are not allowed to come into their churches. It is computed that there are 172 houfes of Carthu- fians ; whereof five are of Nuns, who praAife the fame aufterities as the Monks. They are divided into 16 provinces, each of which has two vifitors. There have been feveral canonized faints of this order, four cardi- nals, 70 archbifhops and bifhops, and a great many very learned writers. CARTHusiAN-Poivder, the fame with kennes-mincral. See Kermes. CARTILAGE, in anatomy, a body approaching to the nature of bones ; but lubricous, flexible, and elattic. See Anatomy. CARTILAGINOUS, in ichthyology, a title given to all fifh whofe mufcles are fupported by cartilages Br'it. Zx inftead of bones ; and comprehends the fame genera HI 75. of fifli to which iinnceus has given the name of am- ph'ilia nantcs : but the word amphil'ia ought properly to be confined to fuch aniraals as inhabit both ele- ments ; and can live, without any inconvenience, for a confiderable time, eitlier on land or in water ; fuch as tortoifes, frogs, and feveral fpecies of lizards ; and, among the quadrupeds, hippopotami, <^c. iffc. Many of the cartilaginous fiih are viviparous, being excluded from an egg, which is hatched within them. The egg confifts of a white and a yolk ; and is lodged in a cafe formed of a thick tough fubftance, not unlike foftened horn : fuch are the eggs of the raj and JJoark kinds. Some again differ in this refpeft, and arc ovi- parous ; fuch is the Jlurgeon, and others. They breathe either through certain apertures be- neath, as in the rays ; on their fides, as in the Jharksf \ 8cc. ; or on the top of the head, as in the pipe-Jijlo : for they have not covers to their gills like the bony fifli. CARTMEL, a town of LancaO-iire in England. It is feated among the hills called Carmel-fells, not far from the fea, and near the river Kent ; adorned with a very handfome churcli, built in the form of a crofs like a cathedral. The market is well fupplied with corn, fheep, andfifli. W. Long. 2. 43. N. Lat, 54. 15. CARTON, or Cartoon, in painting,^ a defiga draw a CAR { n Curfon, drawn on flrong paper, to be afterwards calked through, touc e. ^j^j transferred on the frefh plafter of a wall to be painted in frefco. It is alfo ufed for a defign coloured, for working in mofaic, tapeftry, is'c. The word is from the Italian Cartoni, (carta " paper," and oni " large,") denoting many flieets of paper palled on canvas, on which large defigns are made, whether co- loured or with clialks only. Of thefe many are to be feen at Rome, particularly by Domenichino. Thofe by Andrea Mantegna, which are at Hampton Court, were made for paintings in the old ducal palace at Mantua. Eut the moll famous performances of this fort are. The Cartoons of Raphael, fo defervedly applauded throughout Europe by all authors of refined tatte, and all true admirers of the art of defign, for their various and matchlefs merit, particularly with regard to the invention, and to the great and noble expreflion of fuch a variety of charadlers, countenances, and moll exprefilve attitudes, as they are differently affedled and properly engaged, in every compofition. Thefe car- toons are feven in number, and form only a fmall part of the facred lullorical defigns executed by this great artill, while engaged in the chambers of the Vatican under the aufpices of Popes Julius II. and Leo X. When finillied, they were fent to Flanders, to be co- pied in tapeftry, for adorning the pontifical apartments : which tapeftries were not fent to Rome till feveral years after the deceafe of Raphael, and even in all probability were not finifhed and fent there before the terrible fack of that city in the time of Clement VII. when Raphael's fcholars were fled from thence, and none left to enquire after the original Cartoons, which lay negleAed in the ftore-rooms of the manufadlory. The great revolution alfo which followed in the Low Countries prevented their being noticed amidll the en- tire negleft of the works of art. It was therefore a moft fortunate circumllance that thefe feven efcaped the wreck of the others, which were torn in pieces, and remain difperfed as fragments in dilferent collec- tions. Thefe feven were purchafed by Rubens for Charles I. and they have been fo roughly handled '* from the firft, that holes were pricked for the weavers to pounce the outlines, and other parts almoll cut through in tracing alfo. In this ftate perhaps they as fortunately efcaped the fale amongft the royal collec- tion, by the difproportioned appraifement of thefe feven at 300 1. and the nine pieces, being the Triumph of Julius Casfar, by Andrea Mantegna, appraifed at loool. They feem to have been taken fmall notice of till King William built a gallery, purpofely to re- ceive them, at Hampton Court ; whence they were moved, on their fuffering from damps, to the Queen's Palace. They are now at Windfor Caftle, and open to public infpeftion. CARTOUCHE, in architeftufe and fculpture, an ornament reprefenting a fcroll of paper. It is ufually a flat member, with wavings, to reprefent fome in- fcription, device, cipher, or ornament of armoury. They are, in architedlm'e, much the fame as modil- iions ; only thefe are fet under the cornice in wainf- cotting, and thofe under the cornice at the eaves of a houfe. Cartouche, in the military art^ a cafe of wood, ;.bout three inches tlaick at the bottom, girt with mar- lin, holding about four hundred mu fleet-balls, befides VouIVPartL 17 ) GAR fix or eight balls of iron, of a pound weight, to be Cartridge fired out of a hobit, for the defence of a pafs, csf^. Car'ler A cartouche is fometimes made of a globular form, ^ . ' . and filled with a ball of a pound weight ; and fome- times it is made for the guns, being of a ball of half or quarter a pound weight, according to the nature of the gun, tied in form of a bunch of grapes, on a tom- pion of wood, and coated over. Thefe were made in the room of partridge-lhot. CARTRIDGE, in the militaiy art, a cafe of pafte* board or parchment, holding the exa6l charge of a fire-arm. Thofe for muflcets, carabines, and pillols, hold both the powder and ball for the charge ; and thofe of cannon and mortars are ufually in cafes of palleboard or tin, fometimes of wood, half a foot long, adapted to the caliber of the piece. CiRTRiDGE-Boxy a cafc of wood or turned iron, co- vered with leather, holding a dozen muflcet-cartridges. It is wore upon a belt, and hangs a little lower than the right pocket-hole. CARTWRIGHT (WiUiam) an eminent divine and poet, born at Northway, near Tewklbury, in Gloucellerfliire, in September 161 1. He finiflied his education at Oxford ; afterwards went into holy or- ders, and became a moft florid preacher in the univer- fity. In 1642, he had the place of fuccentor in the church of Salilbury ; and, in 1643, was chofen junior pro6lor in the univerfity. He was alfo metaphyfical reader there. Wit, judgment, elocution, a graceful perfon and behaviour, occafioned that encomium of hira from dean Fell, " That -he was the utmoft that " man could come to." He was an expert linguilt ; an excellent orator ; and at the fame time was elteem- ed an admirable poet. There are extant of his, four plays, and fome poems. He died in 1643, aged 33. CARVAGE, car-vagium, the fame with Carru- CAGE. Henry III. is fald to have, taken carvage, that is two marks of filver of every knight's fee, towards the marriage of his fifter Ifabella to the emperor. Car- vage could only be impofed on the tenants in capite. Carvage alfo denotes a privilege whereby a man is exempted from the fervice of carrucage. CARUCATURIUS, in ancient law books, he that held land in foccage, or by plough tenure. CARUCATE. See Carrucate. CARVER, a cutter of figures or other devices in wood. See Carving. Carvers anfwer to what the Romans called fculptoresf who were different from c^elatores, or engravers, as thefe laft wrought in metal. Carver is alfo an officer of the table, whofe bufi- nefs is to cut up the meat, and diftribute it to the guefts. The word is formed from the Latin carptor^ which fignifies the fame^ The Romans alfo called him carpus.^ fometimes fcjjfor^ fcindendi magijler^ and JlruBor. In the great families at Rome, the carver was an officer of fome figure. There were mailers to teach them the art regularly, by means of figures of animals cut in wood. The Greeks alfo had their carvers, cal- led SixTpoi, q. d, deribitores, or dijlribuiors . In the pri- mitive times, the mailer of the feall carved for all his guefts. Thus in Homer, when Agamemnon's ambaf- fadors were entertained at Achilles's table, the hero E e himfeW Carul f( Carum. GAR [21 himfelf carved the meat. Of later times, the fame of- fice on folemn occafions was executed by fomc of the chief men of Sparta. Some derive the cuftom of dif- ttibuting to every gueft his portion, from thofe eaily ages when the Greeks firft left off feeding on acorns, and learned the ufe of corn : The new diet was fo great a delicacy, that to prevent the guells from quar- relling about it, it was found neceffary to make a fair diilribution. In Scotland, the king has a hereditary carver in the family of Anftruther. CARUI, or Carvi, In botany. See Carum. CARVING, in a general fenfe, the art or a£l; of cutting or fafhionlng a hard body, by means of fome lharp inftrument, efpecial'y a chlffel. In this fenfe carving includes ftatuary and engraving, as well as cut- ting in wood. Carving, in a more particular fenfe, is the art of engraving or cutting figures in wood. In this fenfe carvingy according to Pliny, is prior both to ftatuary and painting. To carve a figure or defign, it muft be firft drawn or pafted on the wood ; which done, the reft of the block, not covered by the lines of the defign, are to be cut away with little narrow-pointed knives. The wood fitteft for the ufe is that which is hard, tough> and clofe, as beech, but efpecially box : to prepare it for drawing the defign on, they wafh it over with white- lead tempered in water; which better enables k either to bear ink or the crayon, or even to take the imprelTion by chalking. When the defign is-to be pafted on the wood, this whitening is omitted, and they content themfelves with feeing the wood well planed. Then wiping over the printed fide of the fi- gure with gum tragacanth dlflblvcd in water, they dap it fmooth on the wood, and let it dry ; which done, they wet it flightly over, and fret off the furface of the paper gently, till all the fttokes of the figrure appear diftinftly. This done, they fall to cutting or car- vlrg, as above. CARUM, in botany: A genus of the digynia order, belonging to the pentandria clafs of plants ; and m the natural method ranking under the 45th order, Umlellatte. The fruit is ovate, oblong, and ftriated ; the involucrum monophyllous ; the petals are carinated or keel-ftiaped below, and emarginated by their in- flexion. Species, &c. I. The carui, or caraway of the fhops, grows naturally in many places of Britain. It is a bien- nial plant, which rifes from feeds one year, flowers the next, and perifhes foon after the feeds are ripe. It hath a taper root like a parfnip, but much fmaller, which runs deep into the ground, fending out many fmall fibres, and hath a ftrong aromatic tafte. From the root arifes one or two fmooth, folid, channelled ftalks, about two feet high, garnifhed with winged leaves, having long naked foot-ftalks. 2. The hif- panicum is alfo a biennial, and is a native of Spain. It rifes with a ftronger ftalk than the former, which feldom grows more than a foot and half high ; but is clofely garnifhed with fine narrow leaves like thofe of dill. Both thefe plants are propagated by feeds, which ought to be fown in autumn. Sheep, goata, and fwine, eat this plant ; cows and horfes are not fond of it. Parkinfon fays, the young roots of cara- Gary. 8 ] CAR way are better eating than parfnips. The tender Caruncula leaves may be boiled with pot herbs. The feeds have an aromatic ftnell, and a warm pungent tnfte. They _ are ufed in cakes, incrufttd with Ir.gar, as fweet-medts, and diftilled with fpiritnous liquors, for the fake of the flavour they afford. They are in the number of the four greater hot feeds ; and frequently employed, as :i ftomachic and carminative, in flatulent colics and the hke. CARUNCULA, or caruncle, m anatomy, a term denoting a little piece of fleih, and applied to feveral parts of the human body. Thus, Caruncula Myrtlformes, in anatomy, fleftiy knobs about the fize of a myrtle -berry, fuppofed to owe their* origin to the breaking of the hymen. See Anatomy, n° 108. Carunclks in the urethra, proceeding from a go- norrhoea, or an ulceration of the urethra, may be re- duced by introducing the bougie. CARUS, a fudden deprivation of fenfe and motion, affefting the whole body. See (the Inddx fubjoiued to) Mfdicinf,. Car us (Marcus Aurelius), was raifed from a low ftation, by his great merit, to be emperor of Rome iti 282. He ftiowed himftlf woithy of the empire ; fub- dued its enemies ; and gave the Romans a profped. of happy days, when he waii unfortunately killed by light- ning in 2-84. CARWAR, a town of Afia, on the coaft of Mala- bar in the Eaft Indies, and where the Eaft India com- pany have a faftory, fortified with two baftions. The valleys about it abound in corn and pepper, which laft is the beft in the Eaft Indies. The woods on the mountains abound with quadrupeds, fach as ty- gers, wolves, monkeys, wild hogs, deer, elks, and a fort of beeve:> of a prodigious fize. The religion of the natives is Paganifm ; and they have a great many ftrangs and fuperftitious cuftoms. E. Long. 7^. 7. N. Lat. I 5. o. CARYA-A-E, (Stephanas); Carya, d;rwOT,(Paufanias); a town of Laconia, between Sparta and the borders of Meflcnia : where ftood a temple of Diana, thence call- ed Caryatlsy idis ; whofe annual feftival, called CaryUf orum, was celebrated by Spartan virgins with dances. An inhabitant, Caryates, and Caryatis ; Caryat'is ap'is^ a Laconian bee, (Stephanus.) CARrAF.-artm, (anc. geog. ), a place in Arcadia, to- wards the borders of I^aconia. Whether from this of Arcadia, or that of Lacoaia, the Colmma Carja- ^/V/ifj of Vltruvius and Pliny (which were ftatues of matrons In ftoles or long robes) took the appellation. Is difputed. CARY (Lucius), Lord vlfcount Falkland, was born in Oxfordfliire, about the year 1610 \ a young noble- man of great abilities and accomplifliments. Abou^ . the time of his father's death in 1633, he was made gentleman of the privy chamber to king Charles 1. and afterwards fecretary of ftate. Before the afiem- bling of the long parliament, he had devoted himfelf to literature, and every pleafure which a fine genius, a generous difpofition, and an opulent fortune, could afford : when called into public hfe, he ftood foremoft In all attacks on the high prerogatives of the crown ; but when civil convulfions came to an extremity, and it was neceffary to choofe a fide, he tempered lus zeal. CAR [ zni defended the Itmited powers that remained to mo- narchy. Still anxious however for his country, he feems to have dreaded equally the profperity of the royal party, or that of the parliament ; and among his intimate friends, often fadly reiterated the word peace. This excellent nobleman freely expofed his per- f in for the king in all hazardous enterprizes, and was killed in the 34th year of his age at the battle of New- berry. In Welwood's memoirs we are told, that whilH he was with the king at Oxford, his majefty went one day to fee the public library, where he was fhown a- rnong other books a Virgil, nobly printed, and exqui- fitely bound. The lord Falkland, to divert the king, would have hi* majeily make a trial of his fortune by the Sortes Virgiltanae, an ufiial kind of divination in ages paft, made by opening a Virgil. The king open- ing the book, the palfage which happened to come up, was that part of Dido's imprecation againlt iEneas, iv. 615, &c. which is thus tranflated by Dryden. ** Opprefs'd with numbers in th' unequal field, " His men difcourag'd, and himfelf expell'd ; ** Let him for fuccour fue from place to place, " Torn from his fubjeds and his fon's embrace," &c. King Charles feeming concerned at this accident, the lord FcJkland, who obferved it, would likewife try his own fortune In the fame manner ; hoping he might fall upon fome paffage that could have no relation to his cafe, and thereby divert the king's thoughts from any imprtflion the other might make upon him : but the place lord Falkland ftumbled upon was yet more fuit- ed to his deftiny than the other had been to the king's; being the following exprelTions of Evander, upon the untimely death of his fon Pallas, -/En. xl, 152. *■ O Pallas ! thou haft fail'd thy plighted word. ** To fight with caution, not to tempt the fword, *' I warn'd thee, but In vain : for well I knew *' What perils youthful ardour would purfue ; *' That boiling blood would carry thee too far; " Young as thou wert in dangers, raw to war. " O curft effay of arms, difaft'rous doom, " Prelude of bloody fields and fights to come !" He wrote feveral things, both poetical and political ; and In fome of the king's declarations, fuppofed to be penned by lord Falkland, we find the firft regular de- finition of the Englifh conftitution that occurs in any compofition publifiied by authority. His predeceffor, the firft vifcount Cary, was ennobled for being the firfl who gave king James an account of queen Elizabeth's tieath. Cary (Robert), a learned Enllrti chrnnologer, born in DevonfliIre about the year 1615. On the refto- lation, he was preferred to the archdeaconry of Exe- ter; but on fome pretext was ejefted in 1664, and fpent the re.1 of his days at his reflory of Portle- mouth, where he died In 1688. He pubhfhed Pala- hgia Chronica, a chronology of ancient times, In three parts, didaftical, apodeiftical, and canonical ; and tranflated the hymns of the church into Latin verfe. CARYATES, In antiquity, a fellival In honour of Diana furnamed Caryat'is, held at Caryum, a city of La- conia. The chief ceremony was a certain dance faid lo have been invented by Caflor and P*..'IIux, and per- 19 ] CAR formed by the virgins of the place. During Xerxes's Caf'yatides invafion, the Laconlans not darlncf to appear and cele-\-, " , , , 1 n r 1 • fc> rr , . Carj'ophyl- brate the cultomary iolemnity, to prevent mcurrmg the anger of the goddefs by fuch an intermlffion, the — — y^— j neighbouring fwarns are faid to have alfemhled and fung paftorals or bucollfmiy which is faid to have been the origin of l;ucolic -poetry. CARYATIDES, or Caraites. See Architec- ture, n"^ ^6. CARYL (Jofeph), a divine of the laft century, bred at Oxford, and fome time preacher to the fociety of Lincoln's inn, an employment he filled with much ap- plaufe. He h^cume a frequent preacher before the long parliament, a licenfer of their books, one of the affembly of divines, and one of the triers for the ap- probation of minifters ; In all which capacities he fhowed himfelf a man of conliderable parts and learn- ing, but with great zeal again (l the king's perfon and caufe. On the reftoration of Charles 11. he was filenced by the a£t of uniformity, and lived privately in London, where, befides other works, he diflinguifh- ed himfelf by a laborious Expofit'ion of the Booh of Job; and died in 1672. CARYLL (John), a late Engllfli poet, was of the Roman Catholic perfuafion, being fecretary to queen Mary the wife of James II. and one who followed the fortunes of his abdicating mafter ; who rewarded him, firft with knighthood, and then with the honorary titles of carl Caryll and baron Dartford. How long he continued in that fervlce Is not known ; but he was In England In the reign of queen Anne, and re- commended the fubjeft of the Rape of the Lock" to Mr Pope, who at Its publication addrelTed it to him. He was alfo the intimate friend of Pope's " Unfor- tunate Lady." He was the author of two plays: I. " The Englifh Princefs, or the Death of Richard III. 1667," 4to. ; 2. " Sir Salomon, or the Cautious Coxcomb, 1671," 4to. ; and In 1700, he publiftied ** The Pfalms of David, tranflated fro n the Vulgat," i2mo. In Tonfon's edition of Ovid's EpIftles, that of '< Brlfeis to Achilles" is faid to be by Sir John Caryll ; and in Nichols's Seled CoUeaion of Mif- cellany Poems, vol. 1 1, p. i . the firft Eclogue of Vir- gil is tranflated by the fame ingenious poet. He was hving in 17 17, and at that time mull have been a very old man. See three of his letters in the " Additions to Pope," vol. II. p. 114. CARYOCAR, in botany: A genus of the tetragy- nia order, belonging to the polyandria clafs of plants. The calyx is quinquepartite, the petals five, the ftyles more frequently four. The fruit is a plum, with necleuffes, and four furrows netted. C ARYOPHYLL^I, In botany, the name of a ve- ry numerous family or order in Llnmeu^'s fragments of a natural method: containing, befides the clafs of the fame name in Tournefort, many other plants, which from their general appearance feem pretty nearly al- lied to It. The following are the genera, vi%. Agio- ftema, Cucubalus, Dianthus, Drypis, Gypfophila, Lychnis, Saponaria, Silene, Velazia, Alfine, Arenaria, Bufonia, Ceraftium, Cherleria, Glinus, Holofteum, Loefldngia, Moehringia,Polycarpon, Sagina, Spergula, Stellaria, Minuartia, Mollugo, Ortegia, Pharnaceum, Qixeria. All the plants of this ordc-r are heibaceous, E e 2 and CAR [22 Caryophyl- and moftly annual. Some of the creeping kinds do . ^ . not rife an inch, and the talleil exceed not feven or eight feet. See Botany, fe£l. vl. 22. CARYOPHYLLUS, the pink, in botany. See DiANTHUS. Caryophyllus, the clove-tree, in botany : A genus of the monogynia order, belonging to the poly- andria clafs of plants ; and in the natural method rank- ing under the 1 9th order, Hefpendete. The corolla is tetrapetalous ; the calyx tetraphyllous ; the berry monofpermous below the receptacle of the flower. Of this there is but one fpecies, viz. the aroma- ticus, which is a native of the Molucca iflands, par- ticularly of Amboyna, where it is principally cul- tivated. The clove-tree refembles, in its bark, the olive ; and is about the height of the laurel, which it alfo refembles in its leaves. No verdure is ever feen under it. It has a great number of branches, at the extremities of which are produced vaft quantities of flowers, that are firft white, then green, and at laft pretty red and hard. When they arrive at this de- gree of maturity, they are, properly fpeaking, cloves. As they dry, they afliime a dark yellowifh cafl: ; and, when gathered, become of a deep brown. The fea- fon for gathering the cloves Ts from Oftober to Fe- bruary. The boughs of the trees are then ftrongly fhaken, or the cloves beat down with long reeds. Large cloths are fpread to receive them, and they are afterwards either dried in the fun or in the fmoke of the bamboo-cane. The cloves which efcape the no- tice of thofe who gather them, or are purpofely left upon the tree, continue to grow till they are about an inch in thicknefs ; and thefe falling off, produce new plants, which do not bear in lefs than eight or nine years. I'hofe which are called mother-cloves are infe- rior to the common fort ; but are preferved in fugar by the Dutch ; and, in long voyages, eat after their meals, to promote digeftion. The clove, to be in perfeftion, mud be full fized, heavy, oily, and eafily broken ; of a fine fmell, and of a hot aromatic talte, fo as almoft to burn the throat. It fliould make the fingers fmart when handled, and leave an oily moifture upon them when preflTed. In the Eafl; Indies, and in fome parts of Europe, it is fo much admired as to be thought an indifpenfable ingre- dient in almoft every difh. It is put into their food, liquors, wines, and enters likewife the compofition of their perfumes. Confidered as medicines, cloves are very hot, ftimulating, aromatics ; and pofTefs in an eminent degree the general virtues of fubfl;ances of this clafs. Their pungency refides in their refin ; or raihcr in a combinat?on of refin with eflential oil : for the fpirituous e.xtraft is very pungent ; but if the oil and the refin contained in this extradl are fepa- vated from each other by didtllation, the oil will be very mild ; and any pungency which it does retain, proceeds from fome fmall portion of adhering refin, and the remaining rcfin will be infipid. No plant, or part of any plant, contains fuch a quantity of oil as cloves do. From 16 ounces Newman obtained by di- flillation two ounces and two drams, and Hoffman obtained an ounce and an half of oil from two ounces of the fpice. The oil is fpccifically heavier than wa- ter. Cloves acquire weight by imbibing water ; and this they will do at fome confiderable dillance. The o ] CAS Dutch, who trade in cloves, make a confiderable ad C?.ryo{a vantage by knowing this fccret. They fell them al- , il ways by weight ; and when a bag of cloves is order- ^i^..^" ^"^^ ed, they hang it, for feveral hours before it is fent in, over a vefiel of water, at about two feet diftance froni the furface. This will add many pounds to the weight, which the unwary purchafer pays for on the fpot. This is fometimes praftifed in Europe, as well as in the fpice iflands : but the degree of moiftare muft be more carefully watched in the latter ; for there a bag of cloves will, in one night's time, attraft fo much wa- ter, that' it may be prefled out of them by fqueezlng them with the hand. The plove tree is never cultivated in Europe. At Amboyna the company have allotted the inhabitants 4000 parcels of land, on each of which they were at firft allowed, and about the year 1720 compelled, to plant about 125 trees, amounting in all to 500,000. Each of thefe trees produces annually on an average more than two pounds of cloves ; and confequently the colledtive produce muft weigh more than a mil- lion. The cultivator is paid with the fpecie that is conftantly returned to the company, and receives fome unbleached cottons which are brought from Coromau- deL CARYOTA, in botany: A genus belonging to the natural order of Palrme. The male calyx is common, the carolla tripartite ; the ftamina very numerous : tlie female calyx the fame ; the corolla tripertite ; one peftil, and a difpermous berry. CASA, in ancient and middle-age writers, is ufed to denote a cottage or houfe. Casa Santa, denotes the chapel of the holy virgin at Loretto. — The Santa Cafa is properly the houfe, or rather chamber, in which the bleffed virgin is faid to have been born, where fhe was betrothed to her fpoufe Jofeph, where the angel faluted her, the Holy Gho!l overfhadowed her, and by confequence where the Son of God was conceived or incarnated. Of this building the Catholics tell many wonderful ftories too chi!di(h to tranfcribe. The Santa Cafa or holy chamber con- fifts of one room, forty-four fpaus long, eighteen broad, and twenty-three high. Over the chim.ney, ia a niche, Hands the image called the great Madona or Lady, four feet high, made of cedar, and, as they fay, wrought by St Luke, who was a carver as well as a phyfician. The mantle or robe fhe has on, is covered with innumerable jewels of ineftimable value. She has a crown, given her by Louis XIII. of France, and a little crown for her fon. CASAL, a ftrong town of Italy in Mountferrat,. with a citadel and a bifuop's fee. It was taken by the French from the Spaniards in 1640; and the duke of Mantua fold it to the French in 168 1. In 1695 it was taken by the allies, who deraoliilied the fortifica- tions ; but the French retook it, and fortified it again. The king of Sardinia became mafter of it in 1706, from whom the French took it in 1745 ; how- ever, the king of Sardinia got pofTeffion again in 1746. It is feated on the river Po, in E, Long. 8. 37. N. Lat. 54-7. CASAL-Magg'iore, a fmall ftrong tow^i of Italy, in the duchy of ?/Iilan, feated on the river Po. E. Long, 1 1. 5. N. Lat, 45. 6. C ASA-NOVA (Marc Antony), a Latin poet, born I at GAS [2 at Rome, fuccecded particularly in epigrams. Tlie poems he compofed in honour of the ilkiftrious men of Rome are alfo much cfleemed. He died in 1527. CASAN, a confiderable town of Afia, and capital of a kingdom of the fame name in the Ruffian em- pire, with a ftrong caftle, a citadel, and an archbi- ftiop's fee. The country about it is very fertile in all forts of fruits, corn, and pulfe. It carries on a great trade in furs, and fumifhes wood for the building of Ihips. The kingdom of Cafan is bounded on the north by Peimia, on the cafl by Siberia, on the fouth by the river Wolga, and on the weft by the province of Mof- cov.'. E. Long. 53. 25. N. Lat. 55. 38. CASAS (Bartholomew de las), bifhop of Chiapa, diftinguifhed for his humanity and zeal for the conver- iion of the Indians, was born at Seville in 1474; and went with his father, who failed to America with Chriftopher Columbus in 1493. At his return to Spain he embraced the ftate of an ecclefiattic, and ob- tained a curacy in the ifland of Cuba ; but fome time after quitted his cure in order to procure liberty for the Indians, whom he faw treated by the Spaniards in the moft cruel and barbarous manner, which natu- rally gave them an unconquerable averfion to Chrifti- anity. Bartholomew exerted himfelf with extraor- dinaiy zeal, for 50 years together, in his endeavours to perfuade the Spaniards that they ought to treat the Indians with equity and mildnefs ; for which he dif- fered a number of perfecutions from his countr)''men. At laft the court, moved by his continual remon- ftrances, made laws in favour of the Indians, and gave orders to the governors to obferve them, and fee them executed*. He died at Madrid in 1566, aged 92. He wrote feveral works, which breathe nothing but humanity and virtue. The principal of them are, I. An account of the deftruftion of the Indies. 2. Se- veral treatifes in favour of the Indies, againft Dr Se- pulyeda, who wrote a book to juftify the inhuman bar- barities committed by the Spaniards. 3. A very curi- ous, and now fcarce, work in Latin, on this queftion, " Whether kings or princes can, confiftently with confcience, or in virtue of any right or title, ahenate their fubjeds, and place them under the dominion of another fovereign ?" CASATI (Paul), a learned Jefuit, born at Placentia in 161 7, entered early among the Jefuits ; and, after having taught mathematics and divinity at Rome, was fent into Sweden to queen Chriftina, whom he pre- vailed on to embrace the popifh religion. He wrote, I. V acuum profcriptum. 2. Terra machinis mota. 3. Me- chanicorum, libri oSo. 4. De Igne D'lffertationes ; which is much efteemed. 5. De JugeUs Dlfputatio Theolog. 6. Hydrojlaticx DiJJertat'iones. 7. Optlcde Difputationes : It is remarkable that he wrote this treatife on optics at 88 years of age, and after he was blind. He alfo wrote feveral books in Italian. CASAUBON ( Ifaac) , was born at Geneva in 1559 ; and Henry IV. appointed him his library-keeper in 1603. ^ After this prince's death, he went into Eng. land with Sir Henry Wotton, ambaffador from King Jam^s I. where he was kindly received and engaged in writing againft Baronius's annals : he died not long after this, in 16 14; and was interred in Weftminfter- 21 T CAS abbey, where a monument was eredled to him. He Cafd^iO was greatly Ikilled in the Greek, and in critlcifm ; ^^1-^ pubhllied feveral valuable commentaries ; and recei- . * ved the higheft elogiums from all his cotemporaries. Casaubon (Meric), fon of the preceding, was born at Geneva in 1599. Pie was bred at Oxford, and took the degree of mafter of arts in 1621. The fame year he publiftied a book in defence of his father againft the calumnies of certain Roman Catholics ; which gained him the favour of King James I. and a confi- derable reputation abroad. He was made prebendary of Canterbuiy by archbiftiop Laud. In the beginning, of the civil war he loft all his fpiritual promotions, but ftill continued to pubhfh excellent works. Oliver Crom- well, then lieutenant-general of the parhament's forces, would have employed his pen in writing the hiftory of the late war ; but he declined it, owning, that his fubjeft would oblige him to make fuch reftedlions aj would be ungrateful, if not injurious, to his lordfhip. Notwithftanding this anfwer, Cromwell, fenfible of hio- worth, ordered three or four hundred pounds to be paid him by a bookfeller in London whofe name was Cromwell, on demand, without requiring from him any acknowledgment of his benefaftor. But this offer he rejefted, though his circumftances were then mean. At the fame time it was propofed by his friend Mr Greaves, who belonged to the library at St James's, that, if Cafaubon would gratify Cromwell in the re- queft above mentioned, all his father's books which were then in the royal library, having been purchafed by King James, ftiould be reftored to him, and a pen- fion of 300 /. a-year paid to the family as long as the youngeft fon of Dr Cafaubon ftiould hve; but this alfo was refufed. He hkewife refufed handfome offers from Chriilina queen of Sweden, being determined to fpend the remainder of his life in England. At the rettoration he recovered all his preferments, and con- tinued writing till his death in 1671. He was the au- thor of an EngHfh tranflation of Marcus AureHus An- toninus's meditations, and of Lucius Florus; editions of feveral of the claflics, with notes ; a treatife of ufe and cuftom ; a treatife of enthullafm : with many- other works ; and he left a number of MSS. to the univerfity of Oxford. CASAURINA, in botany : A genus of the mo- nandria order, belonging to the monoecia clafs of plants. The male has the calyx of the amentum ; thi: corolla a bipartite fmall fcale. The female has a caly.-; of the amentum, no corolla ; the ftyle bipartite. CASCADE, a fteep fall of water from a higher in- to a lower plajce. The word is French, formed of the Italian cafcaia, which fignified the fame ; of cafcare^ to fall ; and that from the Lathr caclere. Cafcades are either natural, as that at Tivoli, 8cc. or artificial, i., hofe of Verfaille&, &c. and either fal- hng with gentle defcent, as thofe of Sceaux ; or in form of a buffet, as at Trianon.; or down fteps, in form of a perron, as at St Clou ; or from bafon to • bafon, &c. CASCAIS, a town of Eftremadura in Portugal, fi- tuated at the mouth of the river Tagus, 17 miles eaff of Lifbon. W. Long. 10. 15. N. Lat. 38. 40. CASCARILLA. See Clutia and Croton. CASE, among grammarians, impUes the different Gafe 11 Calhel. GAS [ 22 infleftlons or terminations of nouns, ferving to e:c- prefs the different relations they bear to each other, and to tlie things they reprefent. See Grammar. Case alfo denotes a receptacle for various articles ; as a cafe of knives, of lancets, of pidols, &c. Case, in printing, a large flat oblong frame plv ced aflope, divided into feveral compartments or little fquare cells ; in each of vi hich are lodged a number of types or letters of the fame kind, whence the compoll- tor takes them out, each as he needs it, to compofe his matter. See Printing. Case is alfo ufed for a certain numerous quantity of divers tilings. Thus a cafe of crown-glafs contains ufually 24 tables, each table being nearly circular, and about three feet fix inches diameter;, of Newcaftle glafs, 35 tables; of Normandy glafs, 25. CASF.-Hardm'ing of Iron, is a fuperficial converfion of that metal into Heel, by the ordinary method of converfion, namely by cementation with vegetable or animal coals. This operation is generally praftifed upon fmall pieces of iron wrought into tools and in- ftruments to which a fuperficial converfion isfufficient; and it may be performed conveniently by putting the pieces of iron to be cafe-hardened, together with the cement, into an iron box, which is to be clofelyfliut and expofed to a'red heat during fome hours. By this cementation a certain thicknefs from the farface of •the iron will be converted into fteel, and a proper hard- nefs may be afterwards given by fudden extindlion of the heated pieces of convei-ted iron in a cold fluid. See Steel. CA^F.-Shot, in ihc military art, muflcet-balls, ftones, old iron, &c. put into cafes, and flrot out of great guns. CASEMENT, or Casemate, in architefture, a lioUow moulding, v/hich fome architefts make one- fixth of a circle, and others one-fourth. Casement is alfo ufed in building, for a little moveable window, ufually within a larger, being made to open or turn on hinges. CA.SERN, in fortification, lodgings built in garri- fon-towns, generally near the rampart, or in the wafl:e places of the town, for lodging foldiers of the garrifon. There are ufually two beds in each cafern for fix fol- diers to lie, who mount the guard alternately; the third part being always on duty. CASERTA, an epifcopal town of Italy in the kii j;- dom of Naples, and in tlie Terra di-Lavoro, with the title of a duchy, feated at the foot of a mountain of the fame name, in K. Long, i^, 5. N. Lat. 41.5. CASES (Peter- James), of Paris, the moll eminent painter of the French fchool ; the churches of Paris and of VerfaiUes abound with his works. He died in 1754, aged 79. CASH, in a commercial fiyle, fignifies the flock or ready money which a merchant or other perfon has in Ills prefent difpofal to negociate ; fo called from the French term calfe, 1. e. chejl or coffer for the keeping of money. M. Savaiy fliows, that the management of the cafli of a company is the mofl: confiderable article, and that whereon its good or ill fuccefs chiefly depends. Cash-BooL See Book-keeping. CASHEL, or Cashil, a town of Ireland in the county of Tipperary, and province of Munfter, with 2 1 G A S an archbiikop's fee. The nun? of the old cathedral CaAcl tellify its having been an extenfive as well as handfome !! Gothic fl;rufture, boldly towering on the celebrated ^aflinilre rock of Cafliel, which taken together form a magni- ficent objeft, and bear honoui-able telHmony to the la- bour and ingenuity, as well as the piety and zeal, of its former inhabitants. It is feen at a great diltance, and in many diredions. Adjoining it are the ruins of the chapel of Cormac M'Culinan, at once king and archbiikop of Cafliel, fiippofed to be the firft Itone building in Ireland ; and feems, by its rude imitation of pillars and capitals, to have been copied after the Grecian architedure, and long to have preceded that which is ufually called Gothic, Cormac M'Culinan was a prince greatly celebrated by the Irifii hifliorians for his learning, piety, and valour. He wrote, in his native language, a hiilcry of Ireland, commonly called the Pfalter of Cajhel, which is ftill extant, and contains ' the mofl: authentic account we have of the annals of the country to that period, about the year 90b. On the top of the rock of Cafhel, and adjoining the cathedral, is a lofty round tower, which proudly defied the too fuccefsful attempts of archbifliop Price, who in this century unroofed and thereby demoliflied the ancient cathedral founded by St Patrick. In the choir are the monuments of Myler Magrath, archbiflrop of this fet^ in the reign of queen Elifabeth, and fome other curious remains of antiquity. Cafliel was formerly the royal feat and metropolis of the kings of Munfter ; and on the afcent to the cathedral is a large fl:one on which every new king of Munfl:er was, as the inhabi- tants report from tradition, folemnly proclaimed. Ca- fliel is at prefent but fmall to what we may fuppofe it to have been in ancient days. The ai-chbifliop's pa- '\ lace is a fine building. Here is a very handfome mar- ket houfe, a feflions houfe, the county infirmary, a charter fchool for twenty boys and the fame number of girls, and a very good barrack for two companies of foot. The prefent archbifliop Dr Agar hath finiflied a very elegant church begun by his predeceflbr. W. Long. 7. 36. N. Lat. 52. 16. CASHEW-NUT. See Anacardium. CASHIER, the cafli-keeper ; he who is charged with the receiving and paying the debts of a fociety. — In the generahty of foundations, the cafliier is called tn-afurev. CAstmRs of the Bank, are officers who fign the notes that are iflued out, examine and mark them when re- turned for payment, tff. CASHMIRE, a province of Afia 111 the dominions of the Mogul. It is fituated at the extremity of Hin- doilan, northward of Lahore, and is bounded on the one fide by a ridge of the great Caucafus, and on the other by the little Tartarian Thibet and Moultan. The extent of it is not very confiderable ; but being girt in by a zone of hills, and elevated very confider- ably above an arid plain, which fliretches many miles around it, the fcenes which it exhibits are wild and pifturefque. Rivers, hills, and valleys, charmingly di- verfify the landfcape. Here, Mr Sulhvanf informs us,-|. puu/o. a cafcade ruOies from a foaming precipice; there Aphic.il tranquil fl;ream glides placidly along; the tinkling rill, ^^^Z/"- too, founds amidft the groves ; and the feathered cho-'^'"* rifters fing the fong of love, clofe flieltered in the glade. At CAS Cafamlre At wKat time Cafhm'rc came under the dominion of the Mogul government, and liow long, and in wliat ^ " ^' manner it was independent, before it was annexed to the territories of the houfe of Timur, are points that are beyond our prefent purnofe. Though inconfiderabic as to its revenues, it was uniformly held in the higheit eftimation by the emperors of Hiadoftan. Thither they repaired, in the plenitude of their greatnefs, when the affairs of ftate would admit of their abfence ; and there they diverted tliemfelvcs of form and all the op- preffive ceremony of Hate. The ro^yal manner of tra- velling to Cafhmire was grand, though tedious and un- wieldy, and fhowed, in an eminent degree, the fplcn- dour and magnificence of an eaftern potentate. Au- rungzebe, we are told, feldom began his march to that country'-, for a march certainly it was to be cal- led, without an efcort of 80,000 or 100,000 fighting men, befides the gentlemen of his houfehold, the at- tendants of liis feraglio, and moil of his officers of Jtate. Thefe all continued with him during the time he was on the road, which generally was a month : but no fooner was he arrived at the entrance of thofe aerial regions, than, with a feledl party of friends, he feparated from the rell of his retinue, and with them aicended the defiles which led him to his Eden. The temperature of the air of Cafhmire, elevated as it is fo much above the adjoining country, together with the ttreams which continually pour from its moun- tains, enables the hufbandman to cultivate with fuccefs the foil he appropriates to agriculture ; whilft the gar- dener's labour is amply repaid in the abundant produce of his fruit. In fhort, nature wears her gayefl cloath- ing in this enchanting fpot. The rivers fupply the in- habitants with almoft every fpecies of fifli ; the hills yield fweet herbage for the cattle; the plains are co- vered with grain of different denominations ; and the woods are ilored with variety of game. The Cafli- mireans, according to our author, feem a race diflinft from all others in the Eaft : their perfons are more elegant, and their complexions more delicate and more tinged with red. On the decadence of the Mogul pow«r in Hindo- ftan, Cafhmire felt fame of the ravages of war. It is now however in peace ; and the inhabitants are defi- rous of keeping it fo. They are fprightly and inge- nious ; and have feveral curious manufadlures much valued in India. They are all Mahometans or Idolaters. Cafamire is the capital town. CASIMIR, the name of feveral kings of Poland. See (Hijlory of) Poland. Casimir (Matthias Sorbiewfld), a Polifli Jefuit, born in 1597. He was a mofl excellent poet; and is, fays M. Baillet, an exception to the general rule of Ariilotle and the other ancients, which teaches us "to expert nothing ingenious and delicate from northern climates. His odes, epodes, and epigrams, have been thought not inferior to thofe of the finefl wits of Greece and Rome. Dr Watts has tranflated one or two of his fmall pieces, which are added 10 his J.yric Poems. He died at Warfaw in 1640, aged 43. There have been many editions of his poems, the befl of which is that of Paris, 1759. CASING 0/ TiMBER-v/ORK, among builders, is the plailering the houfe all over the outfide with mor- tar, aud then ftriking it while wet by a ruler, with [ 223 j CAS the corner of a trowel, to make It refemble the joints of free-ftone. Some direct It to be done upon heart- laths, becaufe the mortar would, in a little ^ime, de- cay the fap-laths ; and to lay on the n-idrfaPin two thickneffes, ^'1%. a fecond before the iiril is dry. CASK, a piece of defenlive annoiir wherewitli to cover the head and neck-, otherwife called the head- piece and helmet'^ . The word is French, cafqxie, from ' See cajicum or cafficus^ a diminutive of cajfis a helmet, Le ^'"''^f^-' Gendre obferves, that anciently, in France, the gens d'arms all wore crjhs. The king wore a cafh gilt; the dukes and counts filvered ; gentlemen of extraction polifhed Iteel ; and the reft plain iron. The call-: is frequently feen on ancient medals, where we may obferve great varieties in the form and fafhion thereof; as the Greek faflilon, the Roman fafhion, £ff^, F. Joubert makes it the moft ancient of all the co- verings of the head, as well as the m.oft unlverfal. Kings, emperors, and even gods themfelves, are feen therewith. That which covers the head of Rome has ufually two wings like thofe of Mercury : and that of fome kings Is furnifhed v/ith horns like thofe of Jupiter Ammon; and fometimes barely bidls or rams horns, to exprefs uncommon force. Cask, in heraldry, the fame with helmet. See Heraldry, n"' 45. Cask, a veffel.of capacity, for preferving liquors of divers kinds ; and fbmetimes alfo dry goods, as fugar, almonds, Iffc.—- A. caflc of fugar Is a barrel of that commodity, containing fi-om eight to eleven hundred weight. A cafic of almonds Is about three hundred weight. Ci\JSKET, In a general fenfe, a little coffer or ca- binet. See Cabinet. Cx\SKET.s, in the fea language, are fmall ropes made of finnet, and faftened to gromets, or little rings upon the yarda ; their ufe is to make fait tlie fail to the yard when it is to be fui'led. CASLGN (WiUIam), eminent In an art of the i!?r/V greatefl confequence to literature, the art of letter- ^"'^ founding, was born In 1692, in that part of the t"wn g^'^^^^^. of Hales Owen which is iituated In Shropfhire. Tho' i,y N;_ ' he juftly attained the charafter of being the Coryphas- chols. us in that employment, he was not brought up to the bufinefs ; and: It Is obferved by Mr Mores, that this handy-work is fo concealed among the artificers of ;it, that he could not difcover that any one had taught it to another, but every perfon who had ufed it had' ■ learned It of his own genuine inclination. Mr Cafloa ferved a regular apprenticefliip to an engraver of orna- ments on gun-barrels ; and after the expiration of his ■ term, carried on this trade iu Vine-ltreet, near the Minorles. He did not, however, folely confine his ingenuity to tliat inflrument ; but- employed himfelf likewife in making tools for the book-binders, and fcr the chafing of 'filver plate. Whilft he was engaged in this bufinefs, the elder Mr Bowyer accidentally faw, in a bookfeller's fhop, the lettering of a book uncam- monly neat; and inquiring who the artiil was by whom the letters were made, was hence Induced to feek an acquaintance with Mr Caflon. Not long after, Mr Bowyer took Mr Caflon to Mr James's faundery, in Bartholomew- clofe. Caflon had never before that time feen any part of the bufinefs; and being aflced by his' friend, if he thought he could undertake to cut typefi>. 8 hi- GAS Citflon, [ 1 CAS he requefted a fingle day to coiifider the matter, and then replied that he had no doubt but he could. Upon this anfwer, Mr Bowyer, Mr Bcttenham, and Mr Watts had fufeh^-ft confidence in his abihties, that they lent him 500I. to be^in the undertaking, and he applied himfelf to it with equal affiduity and fuccefs. In 1 720, the fociety for promoting Chriftian knowledge, in con- fequence of a reprefentation from Mr Solomon Negri, a native of Damafcus in Syria, who was well ikilled in the Oriental tongues, and had been profeffor of Ara- bic in places of note, deemed it expedient to print, for the ufe of the Eaflern churches, the New Ttllament and Pfalter in the Arabic language. Thefe were in- tended for the benefit of the poor Chriftians in Palef- tlne, Syria, Mefopotamia, Arabia, and Egypt, the conftitution of which countries did not permit the ex- ercife of the art of printing. Upon this occafion Mr Caflon was pitched upon to cut the fount ; in his fpe- cimens of which he dlftingulflied it by the name of Englifh Arabic. Under the farther encouragement of Mr Bowyer, Mr Beitenham, and Mr Watts, he pro- ceeded with vigour in his employment ; and he arri- ved at length to fuch perfedllon, that he not only ifreed us from the neceffity of importing types from Holland, but in the beauty and elegance of thofe made by him he fo far exceeded the produftions of the beft artificers, that his workmanfiilp was frequently export- ed to the Continent. In fliort, his foundcry became^ in procefs of time, the moft capital one that exifts in this or in foreign countries. Having acquired opu- lence in the courfe of his employment, he was put into the commiflion of the peace for the county of Middle- sex. Towards the latter end of his life, his eldeil fon being In partnerfliip with him, he retired In a great .meafure from the aftlve execution of bufinefs. His death happened in January 1766. CASPIAN SEA, a large lake of falt-water in Afia, bounded by the {irovince of Aftrakan on the north, and by part of Perfia on the fouth, eaft, and weft. It Is upwards of 400 miles long from fouth to north, and 300 broad from eaft to weft. This fea forms fe- veral gulfs, and embraces between Aftrakan and A- ilrabad an incredible number of fmall iflands. Its bot- tom Is mud, but fometlmes mixed with fhells. At the diftance of fome German miles from land it Is 500 fa- thoms deep ; but on approaching the fhore it Is every where fo (hallow, that the fmalleft veflels, If loaded, are obliged to remain at a diftance. When we confider that the Cafpian is inclofed on all fides by land, and that its banks are in the neigh- bourhood of very high mountains, we eafily fee why the navigation In It ftiould be perfectly different from that In every other fea. There are certain winds that domineer over it with fuch abfolute fway, that veflels are often deprived of every refource ; and In the whole extent of it there Is not a port that can truly be called fafe. The north, north eaft, and eaft winds, blow moft frequently, and occafion the moft violent tempefts. A- loFig the eaftern ftiore the eaft winds prevail ; for which reafon veflels bound from Perfia to Aftrakan always di- left their courfe along this fhore. Although the extent of the Cafpian Sea is immenfe, ;fche variety of Its produdlions Is exceedingly fmall. This undoubtedly proceeds from its want of communi- cation with the ocean, whidi cannot impart to it any portion of its Inexliaullible ftores. But the animals Cafpian. which this lake nourifhes multiply to fuch a degree, >— — v-*- that the Ruflians, who alone are In condition to make them turn to account, juftly confider them as a never falling foujce of profit and wealth. It will be under- ftood that we fpeak of the fifti of the Cafpian and of its fifiierles, which make the fole occupation and prin- cipal trade of the people inhabiting the banks of the Wolga and of the Jaik. Tlils bufinefs is dlftingulflied Into the great and lefler fiflierles. The M\ compre- hended under the firft divifion, fuch as the ftiirgeon and others, abound in all pans of the Cafpian as well as in the rivers that communicate with it, and which they afcend at fpawning-time. The fmall fifties, fuch as the falmon and many others, obferve the general law of quitting the fait waters for the frefti, nor Is there an inftance of one of them remaining conftanlly in the fea. ^ Seals are the only quadrupeds that inhabit the Caf- pian; but they are there in fuch numbers as to afford the means of fubfiftence to many people in that coun- try as well as In Greenland. The varieties of the fpe- cles are numerous, diverfified, however, only by the colour. Some are quite black, others quite white ; there are fome whitifli, fome yellowifli, fome of a moufe- colour, and fome ftreaked like a tiger. They crawl by means of their fore-feet upon the iflands, where they become the prey of the fifliermen, Avho kill them with long clubs. As foon as one is difpatched, he Is fuc- ceeded by feveral who come to the afliftance of their unhappy companion, but come only to fliare his fate. They are exceedingly tenacious of life, and endure more than thirty hard blows before they die. They will even live for feveral days after having received many mortal wounds. They arc moft terrified by fire and fmoke ; and as foon as they perceive them, retreat with the utmoft expedition to the fea. Thefe animals grow fo very fat, that they look rather like oil-bags than animals. At Aftrakan is made a fort of grey foap with their fat mixed with pot-afhes, which Is much va- lued for Its property of cleanfing and taking greafe from woollen ftuffs. The greateft numbers of them are killed In fpring and autumn. Many fmall vefTels go from Aftrakan merely to catch feals. If the Cafpian has few quadrupeds, it has in pro- portion ftill fewer of thofe natural produftlons which are looked upon as proper only to the fea. There have never been fousd in it any zoophytes, nor any animal of the order of molufca. The fame may al- moft be faid of fliells; the only ones found being three or four fpecles of cockle, the common mufcle, fome fpecles of fnalls, and one or two others. But to compenfate this fterility. It abounds in birds of different kinds. Of thofe that frequent the fhures there are many fpecles of the goofe and duck kind, of th^ ftork and heron, and many others of the wader tribe. Of birds properly aquatic, it contains the grebe, the crefted diver, the pehcan, the cormorant, and almoft every fpecles of gufl. Crows are fo fond of fifli, that they haunt the fhores of the Cafpian in prodigious multitudes. The waters of this lake are very Impure, the preat number of rivers that run into it, and the nature of Its bottom, aff"eAIng It greatly. It Is true, that In general the waters are fait j but though the whole weftern fliore extends CAS [ 2 Cafpiati. extends from tlie 46th to the 3 jth degree of north lan*- tude, and though one might conclude from analogy that thefe waters would contain a great deaf of fait, yet experiments prove the contrary: and it is certain that the faltnefs of this fea is diminifhed by the north, north-eaft, and north-weft winds ; although we may with equal reafon conclude, that it owes its faltnefs to the mines of fait which lie along its two banks, and which are either already known or will be known to pofterity. The depth of thefe waters alfo diminifhes gradually as you approach the Hiores, and their faltnefs in the fame way grows lefb in proportion to their proxi- mity to the land, the north winds not unfrequently caufmg the rivers to difcharge into it vaft quantities of troubled water impregnated with clay. Thefe varia- tions which the fea is expofed to are more or lefs con- fiderable according to the nature of the winds ; they afPeft the colour of the river waters to a certain dift- ance from the fhore, till thefe mixing with thofe of the fea, which then refume the afcendency, the fine green colour appears, which is natural to the ocean, and to all thofe bodies of water that communicate with it. It is well known, that befides its fait tafte, all fea- water has a fenfible bitternefs, whijh muft be attri- buted not only to the fait itfelf, but to the mixture of different fubftances that unite with it, particularly to different forts of alum, the ordinary effeft of different combinations of acids. Befides this, the waters of the Cafpian have another tafte, bitter too, but quite di- ftinft, which affedts the tongue with an impreflion fimilar to that made by the bile of animals ; a property which is peculiar to this fea, though not equally fen- fible at aU feafons. When the north and north-weft winds have raged for a confiderable time, this bitter tafte is fenfibly felt; but when the wind has been fouth, very imperfedlly. We ftiall endeavour to account for this phenomenon. The Cafpian is furrounded on its weftern fide by the mountains of Caucafus, which extend from Derbent to th^ Black Sea. Thefe mountains make a curve rear Aftrakan, and directing their courfe towards the eaftern fhore of the Cafpian, lofe themfelves near the mouth of the Jaik, where they become fccondary mountains, being difpofed in ftrata. As Caucafus is an inexhauftible mag'^zineof combuftible fubftances, it conf< quently lodges an aftonifhing quantity of metals in its bowels. Accordingly, along the foot of this im- menfe chain of mountains, we fometimes meet with warm fprings, fometimes fprings of naphtha of dif- ferent quality ; fometimes we find native fulphur, mines of vitriol, or lakes heated by internal fires. Now the foot of mount Caucafus forming the immediate weftern fhore of the Cafpian Sea, it is very eafy to imagine that a great quantity of the conftituent parts of the former muft be communicated to the latter : but it is chiefly to the naphtha, which abounds fo much in the countries which furround this fea, that we muft attribute the true caufe of the bitternefs peculiar to its waters ; for it is certain that this bitumen flows from the mountains, fometimes in all its purity, and fometimes mixed with other fubftances which it ac- quires in its paffage through fubterranean channels, from the moft interior parts of thefe mountains to the fea, where it falls to the bottom by its fpecific gravity. It is certain too, that the north and north-vveil winds Vol. IV. Fakt I. 25 ] GAS detach the greatefl quantities of this naphtha ; whence Cifpitn it is evident that the bitter tafte muft be mofl fenfible q.^^^^ when thefe winds prevail. We may alfo comprehend , why this tafte is not fo ftrong at the furface or in the neighbourhood of the fhore, the waters there being lefs impregnated with fait, and the naphtha which is united with the water by the fait, being then either carried to a diftance by the winds or precipitated to the bottom. But it is not a bitter tafte alone that the naphtha communicates to the waters of the Cafpian : thefe wa- ters were analyfed by M. Gmelian, and found to con- tair, befides the common fea- fait, a confiderable pro- , portion of Glauber-falt, intimately united with the former, and which is evidently a produ£lion of the naphtha. As the waters of the Cafpian have no outlet, they are difcharged by fubterranean canals through the , earth, where they depofit beds of fait ; the furface of which correfponds with that of the level of the fea. The two great defarts which extend from it to the eaft and weft are chiefly compofed of a faline earth, in which the fait is formed by efHorefcence into regular cryftals ; for which reafon fait fhowers and dews are exceedinprly common in that neigbourhood. The fait of the marfhes at Aftrakan, and that found in efHore- fcence in the defarts, is by no means pure fea-falt, but much debafed by the bitter Glauber fait we mentioned above. In many places indeed it is found with cryftals of a lozenge fhape, which is peculiar to it, without any cubical appearance, the form peculiar to cryftals of fea-falt. A great deal has been written on the fuccefllve aug- mentation and decreafe of the Cafpian fea, but with little truth. There is indeed to be perceived in it a certain rife and fall of its waters; in which, however, no obfervation has ever difcovered any regularity. Many fuppofe (and there are ftrong prefumptions in favour of the fuppofition), that the fhores of the Caf- pian were much more extenfive in ancient times than they are at prefent, and that it once communicated with the Black Sea. It is probable too, that the level of this laft fea was once much higher than it is at pre- fent. If then it be allowed, t-iat the waters of the Black Sea, before it procured an exit by the Straits of Conftantinople, rofe feveral fathoms above their pre- fent level, which from many concurring circumftances may eafily be admitted ; it wall follow, that all the plains, of the Crimea, of the Kuman, of the Wolga, and of the Jaik, and thofe of Great Tartary beyond the lake of Arat, in ancient times formed but one fea, which embraced the northern extremity of Caucafus by a narrow ftrait of little depth ; the veftiges of which are ftill obvious in the river Mantyfch. CASSADA. SeejATROPHA CASSANA (Nicolu), called Nicoletto, an emi- nent Itahan painter, was born at Venice in 1659, and became a dilciple of his father Giovanni Francefco Caffano, a Genoefe, who had been taught the art of painting by Bernardino Strozzi. He foon diftinguifh- ed himfelf not only by the beauty of his colouring, but by the gracefulnefs of his figures in hiftorical com- pofitions, as well as in portrait. The moft eminent perfonages f -.licited him to enrich their cabinets with fome of his performances ; and were more particularly t f defirous C A. S [ ^: OafTafta; clefirous to obtain their portraits, becaufe in that branch "■"V"" he excelled beyond competition. The Grand Duke of Tufcany, who was an excellent judge of merit in all profeffions, and as liberal an encourager of it, invited Nicoletto to his court ; and he there painted the por- traits of that prince and the princefs Violante his con- tort. Thofe performances procured him uncommon applaufe, as well as a noble gratuity, and he was em- ployed and carefTed by the principal nobility of Flo- rence. Befide feveral hiftorical fubjefts painted by this matter while he relided in that city, one was a very capital defign : The fubjcft of it was the Con/pi- racy of Catiline; it conlifted of nine figures as large as life, down to the knees; and the two principal figiu-es were reprefented as with one hand joined in the pre- fence of their companions, and in their other hand hold- ing a cup of blood. Some of the Eiiglifli nobility on 3, their travels fat to him for their portraits ; which being fent to London, and highly admired, Nicoletto was invited to England, with ftrong afTurances of a ge- nerous reception ; and on his arrival he experienced the kindnefs, the refpeft, and the liberahty, fo peculiar to the natives of that kingdom. He had the honour of being introduced to the prefence of queen Anne, and to paint her portrait ; in which he fucceeded fo happily, that the queen diftinguifhed him by many marks of favour and honour ; but he had not the hap- pinefs to enjoy his good fortune for any length of time, dying in London, univerfally regretted, in the year 1713. Cassana (Giovanni Agoftino), called L' Abate Caf- fana, was brother to the preceding, and born in 1664. He was educated along with him by their fa- ther Franccfco Caffana ; and he finiflied his ftudies at Venice, where his brother Nicolo refidcd for fomc time. Although he compofed and defigned hiftorical fubjefts with expertnefs, and with a correttnefs of outline equal to his brother ; yet from prudence and fraternal aftec- tion, he declined to interfere with him, and chofe therefore to defign and paint all forts of animals and fruits. In that ftyle he arrived at a high degree of excellence, imitating nature with exaftnefs, beauty,, and truth ; expreffing the various plumage of his birds, and the hairs of the different animals with fuch tender- nefs and delicacy as rendered them eftimable to all judges and lovers of the art. His works were admit- ted into the coUeftions of thofe of the firft rank, and' accounted ornaments of thofe repofitories of what is curious or valuable. He alfo painted fruits of thofe kinds which were the moil uncommon, or naturally of odd and fingular colours; and fuch fifties as feemed^ worthy to excite admiration by their unufual form, colour, or appearance. But befides thofe fubjefts, he fometimes painted the portraits of particular perfons of diftiniSlion, Avhich he defigned, coloured, and touch- ed, svith the fame degree of merit that was vifiblein all his other performances. At laft he determined to vifit Genoa, where his family had lived in efteem; and took with him feveral pictures which he had already finifhed. His intention was to difplay his generofity, and to appear as a perlbn of more wealth and of great- er confequence than he really was;- and to fupport.that character, he beftowed his piftures to feveral of the principal nobility of ' that city. Bat, unhappily, he exjjerienced no grateful return for all tliat prodigal 6 ] GAS munificence ; he reduced himfelf by that vain liberality Caffande to the moft; neceifitous circumftances ; was deprived of f' the means to procure for himfelf even the common ne- ceflaries of life ; and wafted away the remainder of his days in the bitternefs of poverty, mifery, and negleft. CASSANDER, king of Macedon after Alexander the Great, was the fon of Antipater. He made fe- veral conquefts in Greece, aboliftied democracy at Athens, and gave the government of that ftate to the orator Demetrius. Olympias, the mother of Alex- ander, having caufed Aridjeus and his wife Euridyce, with others of CaiTander's party, to be put to death ; he befieged Pydne, whither the queen hnd retired, took it by a ftratagem, and caufed her to be put to death. He married Theftalonica the fifter of Alexander the Great ; and killed Roxana and Alexander, the wife and fon of that conqueror. At length he entered into an alliance with Seleucus and Lyfimachus, againft An- tigoBus and -Demetrius ; over whom he obtained a great vitilo'ry near Ipfus in Phiygia, 301 years before the Chriftian sera, and died three years after, in the 19th year of his reign. CASSANDRA, in fabulous hiftory, the daughter of Priam and Hecuba, was beloved of Apollo, who promifed to beftow on her the fpirit of prophccv, pro- vided ftie would confent to his love. Caffandra feemed to accept the propofal ; but had no fooner obtained that gift, than flie laughed at the tempter, and broke her word. Apollo, being enraged, revenged himfelf by caufing no credit be given to her predidlions ; htncc ftie in vain pr6phefied the ruin of Troy. Ajax, the fon of Oileus, having ravithed her in the temple of Minei-va, he was ftruck with thunder. She fell into the hands of Agamemnon, who loved her to diilrac- tion ; but in vain did ftie predict that he would be af- faffinated in his own country. He was killed, with her, by the intrigues of Clytemneftra; but their death was avenged by Oreftes. CASSANO, a town of Italy in the diicliy of Milanj rendered remarkable by an obftinate battle fought theVe between the Germans and French in 1 705. It is fubjefh to the Houfe of Auftria, and is. feated on the river Adda, in E. Long. id. o. N. Lat. 45. 20. CASSANO, a town of Italy in Calabria citerior, in the k'ngdom of Naples, with a biftiop's fee. E. Long.. 16. 30. N. Lat. 39. 55. CASSAVI, or Cassada. See Jatropha. CASSEL, a town of French Flanders^ and capital- of a chatellany of the fame name : It is feated on a mountain, where the terrace of the caftle is ftill to be feen ; and from whence there is one of the finefl: profpefts in the world ; for one may fee no lefs than 32 towns, with a great extent of the fea, from whence it is diftant 1 5 miles. E. Long. 2. 2 7. N. Lat. 50. 48. Cassel, the capital city of the landgravate of Hefle-cafiel, in the circle of the Upper Rhine in Ger- many ; (fee Hesse-cassel). It is divided into the Old, New, and High towns. The New Town is belt built, the houfes being of ftone, and the ftreets broad. . The houfes of the Old Town, which is within the walls, are moftly of timber ; but the ftreets are broad, and the market-places fpacious. The place is ftrongly fortified, but the fortifications are not regular. Ii con- taais about 32,000 inhabitants, of whom a great pro- portion. are French Proteftants. Thefe have eftablifti- € A S [ 22 "CaCia. ed fevcral manufadlories in the place, particularly in ""V"""' the woollen branch. It is featcd on the declivity of a hill near the river Fulva, in E. Long. 9. 20. N. Lat. 51.20. CASSIA, in botany : A genus of the monogynia order, belonging to the decandria clafs of plants ; and in the natural method ranking under the 33d or- der, Lomentacea. The calyx is pentaphyllous ; petals five ; antheras upper, three barren ; lower, three-beaked : a leguminous plant. There are 30 fpecies, all of them natives of warm climates. The moil remarkable are, I. The fiftula or purging cafTia of Alexandria. It is a native of Egypt and both Indies, where it rifcs to the height of 40 or 50 feet, with a large^ trunk, di- viding into many branches, garnilhed with winged leaves, compofed of five pair of fpear-fliaped lobes, which are fmooth, having many tranfverfe nerves from the midrib to the border. The flowers are produced in long fpikes at the end of the branches, each Handing upon a pretty long foot-ftalk ; thefe are compofed^ like the former, of fine yellow concave petals, which are fucceeded by cylindrical pods from one to two feet long, with a dark brown woody fliell, having a longitudinal feam on one fide, divided into many cells by tranfverfe partitions, each containing one or two oval, fmooth, compreffed feeds, lodged in a blackifli pulp, which is ufed in medicine. There are two forts of this drug in the fiiops ; one brought from the Eaft Indies, the other from the Well: the canes or pods of the latter are generally large, rough, thick-rinded, and the pulp naufeous ; thofe of the form.er are lefs, fmoother, the pulp blacker, and of a fweeter tafte ; this fort is preferred to the other. Such pods ftiould be chofen as are weighty, new, and do not make a rattling noife (from tlie feeds being loofe within them) when fhaken. The pulp fliould be of a bright fhining •black colour, and a fweet tafte, not harfh, which hap- pens from the fruit being gathered before it has grown fully ripe, or fourifh, which it is apt to turn upon keep ing: it fliould neither be very dry nor very moift, nor at all mouldy ; which, from its being kept in damp cellars or moiftened, m order to increafe its weight, it is very fubjeft to be. Greateft part of the pulp dif- folves both in water and in redlified fpirit ; and may be extrafted from the cane by either. The fliops em- ploy water, boihng the bruifed pod therein, and after- wards evaporating "the folution to a due confifcence. This pulp is a gentle laxative medicine, and frequently given, in a dofe of fome drams, in coftive habits. Some direft a dofe of two ounces or more as a cathartic, in inflammatory cafes, where the more acrid purgatives have no place ; but in thefe large quantities it gene- rally naufeates the fl:omach, produces flatulencies, and fometimes gripmgs of the bowels, efpecially if the caflia be not of a very good kind : thefe elFeds may be pre- vented by the addition of aromatics, and exhibiting it in a liquid form. Geoffroy fays, it does excellent fer- vice in the painful tenfion of t]^e belly, which fome- times follows the imprudent ufe of antimonials ; and that it may be advantageoufly acuated with the more acrid purgatives, or antimonial emetics, or employed to abate their force. Valhfnieri relates, that the purga- tive virtue of this medicine is remarkably promoted by manna ; that a mixture of four drams 'of cafiia and two of manna, purges as much as twelve drams of caflia 7 ] CAS or thirty-two of manna alone. Sennertus obferves, Caflin, that the urine is apt to be tui-ned of a green colour , by the ufe of caffia : and fometimes, where a large " quantity has been taken, blackifh. This drug gives name to an officinal eleftuary, and is an ingredient alfo - in another. 2. The caffia fenna is a flirubby plant cultivated in Perfia, Syria, and Arabia, for the leaves, which form a confiderable article of commerce. They are of an ob- long figure, fliarp-pointed at the ends, about a quartc't of an hich broad, and not a full inch in length, of a lively yellowiih green colour, a faint not very difagree« ble fmell, and a fubacrid, bitterifli, nauieous tafte. They are brought from the above places, dried and picked from the llalks, to Alexandria in Egypt, and thence imported into Europe. Some inferior forts are brought from TripoH and other places ; thefe may eafily be diftinguifiied by their being either narrower, longer, and fliarper pointed ; or larger, broader, and round pointed, with fmall prominent veins ; or largfe and obtufe, of a irelh green colour, without any yellow caft. Senna is a very ufeful cathartic, operating mild- ly, and yet effeclually ; and, if judicioufly dofed and managed, rarely occafioning the ill confequences which too frequently follow the exhibition of the ftronger purges. The only inconveniences complained of in this drug are, its being apt to gripe, and its naufeous flavour. The griping quality depends upon a refinous fubftance, which, hke the other bodies of this clafs, is naturally difpofed to adhere to the coats of the intef- tines. The more this refin is divided by fuch matters as take off its tenacity, the lefs adhefive, and confe- quently the lefs irritating and griping it will prove j and the lefs it is divided, the more griping : hence fenna given by itfelf, or infufions made in a very fmall quantity of fluid, gripe feverely, and purge lefs than when diluted by a large portion of fuitable menftruum, or divided by mixing the infufion with oily emulfions. The ill flavour of this drug is faid to be abated by the greater water-figwort : but we cannot conceive that this plant, whofe fmell is manifeftly fetid and its tafte naufeous and bitter, can at all improve thofe of feniia i others recommend bohea tea, though neither has this any confiderable effeft. The fmell of fenna refides in its more volatile parts, and may be difcliarged by lightly boiling infufions of it made in water : the li- quor thus freed from the peculiar flavour of the fenna, may be eafily rendered grateful to the tafte, by the addition of any proper aromatic tindlure or diftilled water. The colleges both of London and Edinburgh have given feveral formulae for the exhibition of this article, fuch as thofe of infufion, powder, tincture, and ele£luar}^ The dofe of fenna in fubftance, is from a fcruple to a dram : in infufion, from one to three or four drams. It has been cuftomary to rejc6l the pe- dicles of the leaves of fenna as of little or no ufe: Geoffroy however obferves, that they are not much in- ferior in efficacy to the leaves themfelves. The pods or feed-veffels met with among the fenna brought to us, are by the college of Bruflels preferred to the leaves : they are lefs apt to gripe, but proportionably kfs pur- gative. CjissiA-Lignea. See Laurus. CASSIDA, in botany. Scutellaria. Cassida, in zoology, a genus of infedls belonging Ff2 to C aflim cr II Caffine. Plate CXVI. CAS [2 to the order of coleoptera. The feelers are like threads, but thicker on the outfide; the elytra are marginated; J and the head is hid under the thorax ; from which laft circumftance is derived the name of the genus. Fo- reign countries afford many fine fpecies of them. Thofe we meet with in thefe parts have fomething fmgular. Their larva, by the help of the two prongs which are to be found at its hinder extremity, makes itfelf, with its own excrements, a kind of umbrella, that fhelters it from the fun and rain. When this umbrella grov/s over-dry, it parts with it for a new one. This larva calls its flough feveral times. Thiflles and yerticillated plants are inhabited by thefe infefts. There is one fpecies, of which the remarkable chryfalis re- fcmbles an armorial efcutcheon. It is that which pro- duces our variegated cafTida, and is a very fmgular one. Numbers of them are found on the fide of ponds, up- on the wild elecampane. CASSIMER,orCAs iMER, the name of a thin tweel- cd woollen clotli, much in fiifliion for fummer ufe. CASSIMIRE or Cashmire. See Cashmire. CASSINE, in botany: A genus of the trigynia or- der, belonging to the pentandria clafs of plants ; and in the natural method ranking under the 23d order, DumoJ^. The calyx is quinquepartite ; the petals are five ; and the fruit is a trifpermous berry. There are three fpecies, all of them natives of warm climates. Of thefe the moft remarkable is the yapon^ wliich is a native of the maritime parts of Virginia and Caroli- na. It rifes to the height of ten or twelve feet, fend- ing out branches from the ground upward, garniihed with fpear-fhaped leaves placed alternately, which con- tinue green through the year. The flowers are pro- duced in clofe whorls round the branches, at the foot- ilalks of the leaves ; they are white, and divided into five parts, almoft to the bottom. The berries are of a beautiful red colour, and as they continue moil part of the winter upon the plants without being touched by the birds, we may reafonably conclude that they are pofTeffed of a poifonous. quality ; as few of the whole- fome innocent fruits efcape their depredations. The Indians, however, have a great veneration for this plant, and at certaia fcafons of the year come in great numbers to fetch away the leaves. On fuch occaiions their ufual cuftom, fays Miller, is to make a fire upon the ground, and, putting on it a great kettle full of water, they throw, in a large quantity of yapon leaves; and when tlK: water has boiled fufficiently, they drink large draughts of the decoftion out of the kettle ; which feldom fails to vomit them very feverely. In this manner, however, they continue drinking and vot miting for three days together, until they imagine themfelves fufliciently cleanfed ; they then gather eve- ry one a bundle of the flirub,. and carry it home with them. — In the operation of thefe leaves by vomiting, thofe who have talkd of thsm fay, that- there is no uneafy fenfatlon. or fjain. The matter difcharged comes away in a full ftream by the mouth> without any violence, or fo much as difpofing the patient to reach, or decline his head. The Spaniards who live near the gold m.ines of Peru, are frequently obliged to drink an ihfufion of this herb in order to moilten their breails; without which they are liable to a fort of iuffocation, from >the ilrong metallic exhalations that ase coininually proceeding from the mines. In ^ira- 28 ] CAS guay, the Jefuits make a great revenue by importing CdffinI the leaves of this plant into many countries under the Jl name of Paraguay or South-fea tea, which is there ^'^'"P^'^' drank in the fame manner as that of China or Japan ' is with us. It is with difficulty preferved in England. CASSINI (Johannes Dominicus), a moil excellent" aftronomer, born at Piedmont in 1635. ^^^s early proficiency in aftronomy procured him an invitatioQ to be mathematical profelTor at Bologna when he was no more than 15 years of age: and a comet appear- ing in 1652, he dilcovered that comets were not ac- cidental meteors, but of the fame nature, and proba- bly governed by the fame laws, as the planets. In the fame year he folved a problem given up by Kep- ler and Bullialdus as infolvable, which v/as, to deter- mine geometrically the apogee and eccentricity of a planet from its true and mean place. In 1663, he was appointed infpeftor-general of the fortifications of the caftle of Urbino, and had afterwards the care of all the rivers in the ecclefiailical ftate : he ilill however profecuted his aftronomical ftudies, by difcovering the revolution of Mars round his own axis ; and, in 1 666, publifTied his theory of Jupiter's fatellites. Caffini was invited into France by Louis XIV. in 1 669, where he fettled as the firft profeifor In the royal obferva- tory. In 1677 he demonftrated the line of Jupiter's diurnal rotation ; and in 1 684 difcovered four more fatellites belonging, to Saturn, Pluygens having found •one before. He inhabited the royal obfervatory at Paris more than forty years ; and when he died in 17 1 2, was fucceeded by his only fon James Caffini. CASSIODORUS (M arcus Aurelius), fccrctary of ftate toTheodoric king of the Goths, was born at Squil- lace, in the kingdom of Naples, about the year 470. He was conful in 514, and was in great credit under the. reigns of Athalaric and Vltiges ; but at feventy years of age retired into a monaftery in Calabria, where he amufed himfelf in making fun-dials, water hour- glaffes, and perpetual lamps. He alfo formed a libra- r/ ; and compofed fsveral v;orks, the beft edition of which is that of father Garet, printed at Rouen ia 1679. Thofe moft efteemed are his Divine Inftitu- tions, and his treatife on the Soul. Pie died about the year 562. CASSIOPEIA,, in fitbi ilous hiftorv, wife to Ces- . phcus king of Ethiopia, ' and mother of Andromeda. She thought herfelf more beautiful than the Nereides, who dcfired Neptune to revenge the aftront ; fo that ; he feat a lea-monfter into the country, which did much hariB. To iippeafe the god, her daughter Andi'ome- da was expoled to the monfter, but was refcued by Perfeus ; who obtained of Jupiter, that CaffioiJeia might be placed after his death among the ilars: hence the conttellatlon of that name. Cassiopeia, in aftronomy, one, of the conftellations of the northern hemifphere, fituated next to Cepheus,, In 1572, there appeared a new ftar in this conftella-^ - tion, which at firft furpafted in magnitude and bright- ntis Jupiter himfelf.; but it diminifhed by degrees, and at laft difappeared, at the end of eighteeu months. It alarmed all -the aftronomers of that age, many of whom wrote diffiertation^ on it ; among the reil Tycho Bralie, Kepler, Maurolycus, Lycetus, Gramincus, &c. Beza, the landgrave of Heffc, Rofa, &c. wrote to prove it a CQmct, and the, fa^ne v. hich appeared to the IMagi iit the . CAS [229 C.ffis the birth of Jefns Chrift, and that it came to declare II hia fecond coming : they were anfwered on this fub- Caffumar Tycho. The ftars in the conftellation Caffio- ' » ' peia, in Ptolemy's Catalogue, are thirteen ; in Heve- lius's,thirty-feven; inTycho's, forty-fix; butin the Bri- tannic Catalogue, Mr Flamftead makes them fifty-five. CASSIS, in antiquity, a plated or metalline helmet; different from the galea, which was of leather. CASSITERIA, in the hiftory of foffils, a genus of cr)'llal8, the figures of which are influenced by an admixture of fome particles of tin. ^ The caffiteria are of two kinds ; the whitilh pellu- cid caffiterion, and the brown cafiiterion. The firft is a tolerably bright and pellucid cryllal, and feldom fubjea to the common blemifiies of cryilal : it is of a perfed and regular form, in the figure of a quadrila- teral pvramid ; and is found in Devonfhire and Cornwall principally. The brown caffiterion is like the former in figure : it is of a very fmooth and glolfy furface, and is alfo found in great plenty in Devonftiire and Cornwall. CASSITERIDES (auc. geog.), a duller of illands to the well of the Land's End ; oppofite to Celtiberia, (Pliny) ; famous for their tin, which he calls candidum plumbum ; formerly open to none but the Phoenicians ; who alone carried on this commerce from Gades, con- cealing the navigation from the reft of the world, (Strabo.) The appellation is from Cqffiteros, the name for tin in Greek. Now thought to be the Scil- ly Iflands, or Sorlings, (Camden). CASSIUS (Spurius), a renowned Roman general and conful, whofe enemies accufing him of aipiring to royalty, he was thrown down from the Tarpeian rock, 485 years before Chrift ; after having thrice enjoyed the confiilar dignity, been once general of the horfe \inder the firft diftator that was created at Rome, and twice received the honour of a triumph. Cassius (Longinus), a celebrated Roman law7er, flourifhcd 1 1 3 years before Chrift. He was lo in- flexible a judge, that his tribunal was called the Rock of the impeached. It is from the judicial feverity of this Caffius, that very fevere judges have been caUed Ca/Tiant. , r t v Cassius (Caius), one of the murderers of Julius Cf^far : after his defeat by Mark Anthony at the bat- tle of Philippi, he ordered one of his freed-men to put him to death with his own fword, 41 years before Chrift. See Rome. CASSOCK, or Cassula, a kind of robe or gown, wore over the reft of the habit, particularly by the clergy. The word caffock comes from the French cafaque, an horfeman's coat. CASSONADE, in commerce, caflc fugar, or fugar put into cafks or chefts, after the firft purification, but which has not been refined. It is fold either in pow- der or in lumps ; the-whiteft, and that of which the lumps are largeft, is the belt. Many imagine it to fweetcn more than loaf lugar ; but it is certam that it yields a great deal more fcum. CASSOWARY, in ornithology. See Struthio. CASSUMAR, in the Materia Medica, a root ap- proaching to that of zedoary. It is cardiac and fudorific, and famous in nervous cafes ; it is alfo an ingredient in many compofitions, and is prefcribed in powders, bolufcs, and infufions. Its doXe is from five to fifteen grains. 1 CAS CASSUMBAZAR, a town of India, in Afia, fi- Caffumba^ tuated on the river Ganges, in the province of Bengal: E. Long. 37. and N. Lat. 24. Caftigno. CAST is peculiarly ufed to denote a figure or fmall ^r— J flatue of bronze. See Bronze. Cast, among founders, is applied to tubes of wax fitted in divers parts of a mould of the fame matter ;. by means of which, when the wax of the mould is re- moved, the melted metal is conveyed into all the parta which the wax before poffeffed. Cast, alfo denotes a cylindrical piece of brafs or copper, flit in two, lengthwife, ufed by the founders in fand, to form a canal or conduit in their moulds, whereby the metal may be conveyed to the different pieces intended to be caft. Cast, among plumbers, denotes a little brazen fun- nel at one end of a mould, for cafting pipes without foldering,by means of which the melted metahs pour- ed into the mould. . Cast, or Cap, in fpeaking of the eaftern attairs, denotes a tribe, or number of families, of the fame rank and profefiion. The divifion of a nation ^mto cafts chiefly obtains in the dominions of the Great Mogul, kingdom of Bengal, ifland of Ceylon, and the grea't peninfula oppofite thereto. In each of thefe there are, according to father Martin, four pnncipal cafts, viz. the caft of the bramins, which is the firfl and moft noble ; the caft of the rajcu, or princes, who pretend to be defcended from divers royal families ; the caft of the choutres, which comprehends all the artificers ; and that of the parias, the lovveft and moft contemptible of all : though Henry Lord, it muft be * obferved, divides the Indians about Surat into four cajls, fomewhat diff"ereatly from Martin, vi%. into bramins^ or priefts ; cuttery, or foldiers ; Jhuddery, which we call banians, or merchants ; and ivyfi, the mechanics or artificers. Every art and trade Is confined to its pro- per call, sor is allowed to be exercifed by any but thofe whofe fathers profefTed the fame. So that a taylor's fon can never rife to be a painter, nor a painter's fun fall to be a taylor ; though there are fome employ- ments that are proper to all the cafts, e. g. eveiy body may be a foldier, or a merchant. There are alfo di- vers cafts which are allowed to till the ground, but not all. The caft of parias is held infamous, in fo much that it is a difgrace to have any dealings or _ convcrfa- tion with them ; and there are fome trades m the caft oi choutres, which debafe their profeflbrs almoft to the fame rank. Thus fhoemakers, and all artificers in lea- ther, as alfo fifhermen, and even fhepherds, are reputed no better than parias. CASTAGNO (Andrea Dal), hlftorical pamter, was born at a imall village called Caftagno, belonging to the territory of Tufcany, in 1409 ; and being depri- ved of his parents, was employed by his uncle to at- tend the heids of cattle in the fields ; but, having ac- cidentally feen an ordinary painter at work in the country, he obferved him for fome time with furprife and attention, and afterwards made fuch efforts to imi- tate him, as aftoniflied all who faw his produdions. The extraordinary genius of Andrea became at laft a commen topic of difcourfe in Florence; and fo far excited the curiofity of Bernaidetto de Medici, that he lent for Andrea ; and perceiving tkat he had pro- mifing talents, he placed him under die care cf the ^ f f 3 beit C A S [ 230 ciaalTo"' who were at that ti'me in Florence. An- — ^ - 1 drea diligently purfued his ihidies, devoted himfelf en- tirely to praftice under the Jtreaion of his inftruftors, became particularly eminent in defign, and in a few years made fo great a progrefs, that he found as much tmployment as he could pofTibly execute. Pie painted only in diftemper, and frefco, with a manner of colour- ing that was not very agreeable, being rather dry and hard; till he learned the fecret of painting in oil from Domenico Venetiano, who had derived his knowledge of that new' difcovery from iVntonello da Meffina. An- drea was the firft of the Florentine artitts who painted in oil ; but although he was in the higheft degree in- debted to Domenico for difclofmg the fecret, yet he fecretly envied the merit of the man who taught him the art ; and becaufe his own works feemed to be much lefs admired than thofe of Domenico, he deter- mined to aflaffinate his friend and benefaftor. Ke executed his defign with the utmoft ingratitude and treachery (for Domenico at that time lived with hhn, anri painted in partnerfhip with him), and he ftabbed him at a corner of a ftreet fo fecretly, that he efcaped unobferved, and urifufpefted, to his own houfe, where he compofedly fat down to work ; and thither Dome- nico was foon after conveyed, to die in the arms of his murderer. The real author of fo inhuman a tranfac- tion was never difcovered, till Andrea, through re- morfe of confcience, difclofed it on his death-bed, in 1480. He finifhed feveral confiderable works at Flo- rencei by which he gained great riches, and as great a reputation ; hut when his villanous mifcondudl became public, his memory was ever after held in the utmoil deteftation. The moft noted work of this mafttr is in the hall of juftice at Floience, reprefenting the execution of the confpirators againll the houfe of Medici. CASTALIO (Sebaftian), was born at Chetillon, on the Rhone, in fSie year 15 15. Calvin conceived fuch an e'teem and friendfhip for him, during the ftay he made at Strafburg in 1540 and 1541, that he lodg- ed him foine days at his houfe, and procured him a re- gent's place in the college of Geneva. Caftalio, after continuing in this office near three years, was forced to quit it in the year 1 544, on account of fome parti- Kulai ninions which he held concerning Solomon's fong, aiit' Chrift's defcent into hell. He retired to Bafil, where he was made Greek profelTor, and died in that place in 1564, aged 48. He incurred the high difpleafure of Calvin and Theodore Beza, for differing with them concerning predeftination and the puni/hmeni of heretics. His works are very confi- derable both on account of their quality and number. In 1545, he printed at Bafil four books of dialogues, containing the principal hiftories of the bible in ele- gant Latin ; fo that youth might thereby make a pro- ficiency ill piety and in the Latin tongue at the fame time. But his principal work is a Latin and French trauHation of the fcriptures. He began the Latin tranflation at Geneva in 1542, and finifhed it at Bafil in 1550. It was printed at Bafil in 1551', and dedi- cated by the author to Edward VI. king of England. The French verfion was dedicated to Henry II. of France, and printed at Bafil in 1555. The fault which has been moll generally condemned in his Latin tranf- iation, ia the aifed^ation of ufmg only claffical terms. ] CAS CASTALIUS FONS, (Strabo, Paufanlas) ; Cti/?a- Caftallus /ia, (Pindar, Virgil) : A fountain at the foot of mount II ParnafTus, in Phocis, near the temple of Apollo, or p^^-J^S' near Delphi ; facred to the Mufes, thence called Caja- ^"^'^^ /ides. Its murmurs were thought prophetic, (Nona us, Lucian). CASTANEA, in botany. See Fagus. CASTANETS, Castagnettes, or Castanet- TAs, a kind of mufical inrtrument, wherewith the Moors, Spaniards, and Bohemians, accompany their dances, farabands, and guittars. It confitts of two little round pieces of wood dried, and hollowed in manner of a fpoon, the concavities whereof are placed on one another, fattened to the thumb, and beat from time to time with the middle finger, to direft their motion and cadences. The cajianets may be beat eight or nine times in the fpace of one meafure, or fecond of a minute. CASTANOVITZ, a town of Croatia, fituated on the river Unna, which divides Chrillendom from Turkey. E. Long. 17. 20. N. Lat. 41^. 40. It is fubjeft to the Houfe of Aullria. CASTEL (Lewis Betrand), a learned Jefuit, was born at Montpellier in 1688, and entered among the Jefuits in 1703. He lludied pohte literature in his youth ; and at length applied himfelf entirely to the lludy of mathematics and natural philofophy. He diftinguiflied himfelf by writing on gravity ; the ma- thematics; and on the mufic of colours, a very whim- fical idea, which he took great pains to reduce to practice. His piece on gravity, entitled T raite de la Pejifateur unlverfelk^ was printed at Paris, in 1724. He afterwards - publiflied his Mathematique umverfelle ; which occalioned his being unanimoufiy chofen a fel- low of the Royal Society of London, without the leaft folicitation. He was alfo a member of the aca- demies of Bourdeaux and Rouen but his Clavecin ocidaire made the moft noife ; and he fpent much time and expence in making an harpfichord for the eye, but without fuccefs. He alfo wrote for and a- gainft Sir Ifaac Newton, and pubhfhed feveral other works; the principal of which are, Le Plan du Ma- thematique abregte, and a treatife entitled Optique des Colours. He led a very exemplary life, and died in 1757. CASTELAMARA, a town of Italy, in the king- dom of Naples, and in the hither Principato, with a bifhop's fee and a good harboi^. E. Long. 14. 25. N. Lat. 41 . 40. CASTEL-ARAGONESH, 3 ftrong town of Italy, in the ifland of Sardinia, with a bifhop's fee, and a good harbour. It is feated on the N. W. coaft of the illand, in E. Long. 8. 57. N. Lat. 40. 56. C^&rEL-Branco, a town of Portugal, and capital of the province of Beira; feated on the river Lyra,. 35 miles N. W. of Alcantara. W. Long. 8. o. N. Lat» 39- 35- CASTEL-Franco, a very fmall, but well-fortified fron- tier town of the Bolognefe, in Italy, belonging to the Pope. C AST EL-de- Vide y z' fmall ftrong town of Alentejo. It was taken by Philip V. W. Long. 6. 25. N. Lat. 39- 15- CASTEL-Folit, a town of Spain, in Catalonia, feat- ed on an inacctlTible eminence, between Gironne and Campredonj. C A S [ 231 ] C A S ilel Gun- Campredon, about 15 miles from each, and near the dolpho Fulva. 'aftellatio CASTEL-Gandolphof a town of Italy, in the terri- 'tory of the church, with a caftle, to which the Pope retires in the fummer feafon ; 10 miles S. by E. of Rome. E. Long. 1 2. 46. N. Lat. 41. 44. CASTRL-NovOf a Itrong town of Dalmatia, fubjeft to the Venetians ; feated on the gulph of Cataio, in E. Long. 18. 45. N. Lat. 42. 25. C.isTB.L-RodngOy a town of Portugal, in the pro- vince of Tra-los-Montes, in W. Long. 7. i. N. 41. o. CASTf L-Novo'dc-Carfagnmiaf a town of Italy, in the Modenefe, with a ftrong fortrefs. It is the capital of the valley of Carfagnana ; and feated on the river Ser- chio, 17 miles above Lucca. Caste L del Ovo, a fmall ifland in the Tufcan Sea, in the gulph of Naples, near a town of that name, to which it is joined by a ftone bridge. The fortrefs is called Caftel del Ovo, in which there is always a good garrlfon. Ci^STELBAR, a town of Ireland, in the county of Mayo, and province of Connaught, 35 miles N. of Galway. W. Long. 9. 25. N. Lat. 53. 45-. CASTELL (Edmund) D. D. a learned Englifli di- vine of the 1 7th centuiy, diftinguifhcd by his fldll in tlie eaftern languages. He was educated at Cam- bridge ; where he was mailer of Catharine hall, and Arabic profeffbr ; and was at length canon of Canter- bury. He had the greateil fliare in the Poly glott bible of London ; and v/rote the Heptaglotton pro feptem Or'ien- taUhusy ^c. On this excellent work, which occupied a great part of his life, he beftowed incredible pains and expence, 'even to the breaking of his conftitution, and exhauftlng of his fortune, having expended no lefs than 12,000/, upon that work. At length, when it was printed, the copies remained unfold upon his hands. He died in 1685 ; and lies buried in the church-yard of Higham Gobyon in Bedfordfhire, of which he was reflor. It appears from the infcription on his monument, which he erefted in his hfetime, fcliat he was chaplain to Charles II. He bequeathed all his oriental manufcripts to the univerfity of Cam- bridge, on condition that his name fhould be written on every copy in the colleftion. CASTELLA, a town of the Mantuan, in Italy, about five miles north-eall of the city of Mantua. E. Long. 1 1. 15. N. Lat. 45. '30. CASTELLAN, the name of a dignity or charge in Poland : The caftellans are fenators of the king- ■dom, but fenators only of the lower clafs, who, in diets, fit on low feats, behind the palatines, or great fenators. Tlicy are a kind of lieiitenants of pro\"in- oes, and command a part of the palatinate under the palatine. CASTELLANY, the territory belonging to any oity or town, cliiefly ufed in France and Flanders; Thus we fay, the caftellany of Lifle, Ypres, &c CASTELLARIUS, the keeper, or curator, of a oaftelliim. Gruter gives an ancient fepulchral infcrip- tion in memory of a cojlellarlus. CASTELLATIO, in middle age writers, the aft of building a caftle, or of fortifying a houfe,. and rendering it a caftle. — By the ancient Englifh laws, caftellation was prohibited without the king's efpeciai licence. CASTELLI (Bernard), an Italian painter, was born at Genoa in 1557; and excelled in colouring and- in portraits. He was the intim.ate friend of Tafib, and took upon himfelf the tafk of defigning and etch- ing the figures of his Jerufalem Delivered. He died at Genoa in 1629. Valerio Caftelli, one of his fons, was born at Ge- noa in 1625, and furpafled his father. He particu- larly excelled m painting battles \ whicn he compofed with fpirit, and executed them with fo pleafing a va- ritjty, and fo great freedom of h^nd, as gained him univerfal applaufe. His horfes are admirably drawn, thrown into attitudes that are natural and becoming, full of motion, aftion, and life. In that ftyle of painting he Ihowed all the fire of Tintoretto, united Virith the fine tafte of compofition of Paolo Veronefe. He died in 1659. The works of this mafter are not very frequent ; but they are defervedly held in very high eftt^cm. It is believed that a greater number of his eaftl pictures are In the coUeftions of the nobility and gentry of England, than in any other part of Europe. _ CASTELLORUM operatic, caftle-work, orfer- vice and labour done by inferior tenants for the build- ing and upholding of caftles of defence; toward which forne gave perfonal afliftance, and others paid their contributions. This was one of the three neceflaiy charges to which all lands among the Anglo-Saxons were exprtfsly fubjeft. CASTELVETRO (Lewis), a native of Modena, of the 1 6th century,, famous for his Comment on Ari- Jiotle's Poetics. He was profecuted by the inqulfition for a certain book of Melanfthon, vv'hich he had tranf- lated into Italian. He retired to Bafil, where lie died. CASTIGATION, among the Romans, the puni/h- ment of an offender by blows, or beating with a wand or fwitch. Caftigation was chiefly a military punilli- ment; the power of inflifting which on the foldiery was given to the tribunes. Some make it of two kinds ; one v»-ith a ftick or cane called fujiigailo ; the other with rods, called jlagellatio : the latter was the moll di (honourable. CASTIGATORY for Scolds. A woman indic- ted for being a common fcold, if convifted, fliall be- placed in a certain engine of correftion, called the. treimckety caJI'igaiory y or cuching-Jlool ; which, in the. Saxon language, {\'gxvS\t% xki(t fcold'ing-Jlcol ; though now it is frequently coiTupted into the duchng-Jiool ; be- caufe the refidue of the judgment is, that, when fhe is placed therein, ftie lhall be plunged in water for her puniftiment. CASTIGLIONE (Giovanni Benedetto), a cele« brated painter, was born at Genoa in :6i6. His firft mafter was Gio-Battifta Paggi. Afterwards he ftudied under Andrea Ferrari; andlaftly perfected him- felf from the inftruftions of Anthony Vandyck, who at that time refided at Genoa. He painted portraits, . hiftorical pieces, landfcapes,.and caftles : In the latter of" which he isfaid chiefly to have excelled; asalfo in fairs, markets, and all kinds of rured fcenes. By this mafter we have alfo a great number of etchings, which are all fpirited, free, and full of tafte. The eflfeft is, in general, powerful and pleafing ; and many of them have a more harmonized and finifhed appearance, than is ufual from, ths: CAS [ 232 1 CAS "CalllgHone the point, fo little affifted by the graver. Hia draw- Caftile-de- '^^^ °^ ^^^^ naked figure, though by no means corred, is notwithftanding managed in a ilyle that indicates ^Mxy— the hand of the mafter. His fon, Francefco, was bred under hirafelf, and excelledinthe fame fubjefts; and it is thought that many good paintings which are afcribed to Benedetto, and are frequently feen at fales, or in modern colleftions, are copies after him by his fon Francefco, or perhaps originals of the younger Cafliglione. Castiglione, a fmall, but ftrong town of Italy, in Mantua, with a caftle. It w^as taken by the Ger- mans in 1701, and the French defeated the Im- periaHfls near it iu 1706. E. Long. lo. 29. N. Lat. 43- 23. CASTIGLIONI (Balthazar), an eminent Italian nobleman, defceuded from an illuftrious and ancient •family, and born at his own villa at Cafalico in the duchy of Milan in 1478. He ftudied painting, fculp- ture, and arch'teclure, as appears from a book he wrote in favour of thefe arts ; and excelled fo much in them, that Raphael Urbino, and Buonaroti, though incom.parable artifts, never thought their works com- plete w^ithout the approbation of Count Caftiglioni. When he was 26 years of age, Guido Ubaldo, Duke of Urbino, fent him ambalfador to Pope Julius II. He was fent upon a fecond embaffy to Louis XII, of France, and upon a third to Henry VII. of England. After he had difpatched his bufinefs here, he return- ed, and began his celebrated work intitled the Cour- tier ; which he completed at Rome in 15 16. This work is full of moral and political inftruftion ; and if we feek for the Italian tongue in perfeftion, it is faid •♦o be nowhere better found than in this performance. A verfion of this work, together with the original I- taHan, w^as publ filed at London in 1727, by A. P. Caftiglioni, a gentleman of the fame family, who re- fided there under the patronage of Dr Gibfon biHiop of London. Count Caftiglioni was fent byCIementVII. to the court of the Emperor Charles V. in quality of legate, and died at Toledo in 1529. CASTILE (NEw),orTHE King DOM OF Toledo, a. province of Spain, bounded on the north by Old Caftile, on the eaft by the kingdoms of Arragon and Valencia, on the fouth by that of Murcia and Anda- lufia, and on the weft by the kingdom of Leon. It is divided into three parts ; Argaria to the north, Mancha to the eaft, and Sierra to the fouth. Madrid is the capital. Both thefe provinces are very well wa- tered with rivers, and the air is generally pure and healthy ; but the land is mountainous, dry, and uncul- tivated, through the lazinefs of the inhabitants. The north part produces fruits and wine, and the fouth good paftures and fine wool. Thefe provinces are di- vided by a long chain of mountains, which run from eaft to weft. Castile (OU), a province of Spain, with the title of a kingdom. It is about 192 miles in length, and 115 in breadth ; bounded on the fouth by New Caftile, on the eaft by Arragon and Navarre, on the north by Bifcay and Afturia, and on the weft by the kingdom of Leon. Burgos is the capital town. CASTiLE-de-Oro, a large and fertile country in South America, lying to the weft of Oroonoko. It comprehends eight governmente j viz. Terra Firma, 4 Proper Carthagcna, St Martha, Rio de la Hacha, Veniiuela, New Andalufia,Popayan, and the new king- dom of Granada. CASTILLAN, or Castillane, a gold coin, cur- rent in Spain, and w^orth fourteen rials and fixtecn deniers. Castillan is alfo a weight ufed in Spain for weigh- ing gold. It is the hundredth part of a pound Spa- nifli weight. What they Commonly call a weight of gold in Spain, is always underftood of the caftillan. CASTILLARA, a town of the Mantuan in Italy, fituated fix m.iles north-eaft of the city of Mantua, E. Long. II. 29. N. Lat. 45. 20. CASTILLON, a town of Perigort, in the pro- vince of Guienne in France, fituated on the river Dor- donne, 16 miles eaft of Bourdeaux. W. Long. 2.40, N. Lat. 44. JO. CASTING, in foundery, the running a metal into a mould, prepared for that purpofe. Casting of Metals, of Letters, Bells, is'c. See the article Foundery. Casting in Sand or Earth is the running of metals be- tween tv/o frames, or molds, filled with fand or earth, wherein the figure that the metal is to take has been imprefted en creux, by means of the pattern, Casting, among fculptors, implies the taking of cafts and impreflions of figures, bufts, medals, leaves, &c« The method of taking of cafts of figures and bufts is moft generally by the ufe of plafter of Paris, i. e. alabafter calcined by a gentle heat. The advantage of ufing this fubftance preferably to others, is, that not- withftanding a flight calcination reduces it to a pul- verine ftate, it becomes again a tenaeiousand cohering body, by being moiftened with water, and afterwards fuffered to dry ; by which means either a concave or a convex figure may be given by a proper mold or model to it when wet, and retained by the hardnefs it acquires when dry : and from thefe qualities, it is fitted for the double purpofe of making both cafts, and molds for forming thofe cafts. The particular manner of making cafts depends on the form of the fubjefr hun- dred. The German name for thefe animals is biefem- ralz-e ; the Ruffian, tuychn'z,hoI. 3. The zribethicus, or muHc-rat, with a long, com- preffed, lanceolatcd tail, and the toes of the f^tet fepai- rated from each other. Length from nofe to tail, one foot ; of the tail, nine inches. This fpecies in- habits North America, breeds three or four times ia a year, and brings from three to fix young ones at a time : during fummer the male and female confort together : at the approach of winter they unite ia families, and retire into fmall round edifices covered with a dome, formed of herbs and reeds cemented with CAS [ 240 1 CAS Cartor. .i^.lth clay : at the bottosn are feveral pipes through •""-^r"^ which they pafs in fearch of food; for they do not form magazines like the beavers : during winter tlieir habitations are covered many feet deep with fnow and ice ; but they creep out and feed on the roots be- neath : they quit their old habitations annually, and form new ones: the fur is foft and much efteemed : the whole animal, during funvmer, has a moll exoui- fite fmell of mufk, which it lofes in winter : perhaps the fcent is derived from the calam.us aromaticus, a favourite food of this animal. Lefcarbot fays they arc very good to eat. CASTOR, in aftronomy, a moiety of the conil:eI- lalion Gemini ; called alfo Apollo. Its latitude northwards, for the year 1 700, according to Hevelius, was 10*^4' 23"; and its longitude, of Cancer, 16^ 4' 14". It is alfo called Rafalgenze, Apollo, Aphellan, Avellar, and Anelar. Castor and Pollux, in Pagan mythologv. Jupiter }\zy\0^ an amom* whh Leda, the v/ife of Tyndarua king of Sparta, in the form of a fwan, flie brought forth two eggs, each containing twins. From, that impregnated by Jupiter proceeded Pollux and Helena, who were both immortal ; from the other Caftor and Clytemneftra, who being begot by Tyndarus were both mortal. They were all, however, called by the common name of TynJarid/e. Thefe two brothers en- tered into an inviolable friendfhip : they v/ent with the other noble youths of Greece in the expedition to Colchis, and, on feveral occafions, fignalized them- felves by their courage ; but Caftor being at length killed, Pollux obtained leave to (hare his own immor- tality with him ; fo that they are faid to live and die alternately every day : for, being tranflated into the Ikies, they form the conftellatioii of gemini, one of which ftars rifes as the other fets. A martial dance, called the Pyrrhic or Ctiflonan dance, was invented in honour of thofe deities whom the Cephelenfes placed among the Dii Magni, and of- fered to them white lambs. The Romans alfo paid them particular honours on account of the afii'tance they are faid to have given them in an engagement againft the Latins; in which, appearing mounted on white horfes, they turned the fcale of victory in their favour, for which a temple was erefted to them in the forum. Castor and Pollute, a fiery meteor, which at fea ap- pears fometimes fticking to a part of the fhip, in form of one, two, or even three or four fu-e-balls : when one is feen alone, it is more properly called Helena ; two are denominated Caftor and Pollux, and fometimes Tyndarids. Caftor and Pollux are called by the Spa- niards, San Elmo; by the French, St Elrne, St Ni- cholas, St Clare, St Helene ; by the Italians, Her- mo ; by the Dutch, Vree Vuuren. Caftor and Pollux ai-e commonly judged to portend a ceftation of the ftorm, and a future calm ; being rarely feen till the tempeft is nigh fpent. Helena alone portends ill, and witneffes tlie fevereft part of the ftorm yet behind. When the meteor fticks to the mafts, yards, &c. they conclude, from the air's not having motion enough to diffipate this flame, that a profound calm is at hand ; if it flutter about, it indi- cates a ftorm. N°66. CASTOREUM, in the Materia Medica, CASfOR ; C ifloreum the inguinal glands of the beaver. The ancients had "! a notion that it was lodged in the tefticles ; and that "^"^ the animals, when hard preffed, would bite them ofi", and leave them to its purfuers, as if ctrnfcious of what they wanted to deftroy him for. The beft fort of caiior is what comes from Ruffia. So much is Ruf- fian caftor fuperior to the American, that two gui- neas per Dound is paid for the fortper, and only 8s. 6d, for the Inttcr. 'Ilie Ruffian caftor is in large hard round cods, wliich appear, when cut, full of a brittle, red-, liver-coloured fabftance, interi"perfed with mem- branes and fibres exquifitcly interwoven. An inferior fort is broaglit from Dantzic, and is genei-ally fat and- moill. The American cailor, which is the worft of all, is in longifli thin cods. Ruffia caftor has a ftrong and an acrid, bitterifli, and naufe- extrafts the naufeous part, with difagreeable fmell ; ons tatte. Water little of the iiner bitter; reiSlified fpirit extrafts this lalt without much of the naufeous ; proof-fpirit both : water elevates the whole of its flavour in diftillation ; reftified fpirit brings over nothing. Caftor is looked upon as one of the capital nervine and antihyfteric medicines : fome celebrated pra6litioners, neverthe- lefs, have doubted its virtues ; and Newman and Stahl declare it infignilicant. Experience, however, has fliown that the virtues of caftor are confiderable, tho' lefs than they have been generally fuppofed. CASTRATION, in furgery, the operation or gelding, e. of cutting off the tefticles, and putting a male animal out of a capacity of generation. Caftration is much in ufe in Afia, efpecially am.ong the Turks, ■ who praftife it on their flaves, to prevent any commerce with their v/omen. The Turks often make a general amputation. Caftration alfo obtains in Italy, where it is ufed with a view to preferve the voice for fmging. See Eunuch. The Pcrfiaiis, and other eaftern nations, have di- vers methods of making eunuchs, different fi-om thofe which obtain in Europe : wc fay, of making eunuchs, for it is not always done among them by cutting, or even coUifton. Cicuta and other poifonous herbs do the fame office, as is (hewn by Paulus -ZSgineta. Thofe eunuchifed in this manner are called ihlibia. Befides wliich there is another fort \vi.mc(S. thlafun, in whom the genitals are left entire, and only the veins which ffiould feed them are cut ; by which means the parts do in- deed remain, but fo lax and weak, as to be of no ufe. Caftration was ftn- fome time the pnnifliment of adultery. By the laws of the Vifigoths, fodomitcs underwent the fame jjuniHiment. By the civil law, it is made penal in phyficians and furgeons to caftrate, even with confent of the party, wlio is himfclf included in the fame penalty, and his effefts forfeited. The offence of Mayhem by caftra- tion is, according to all our old writers, felony ; tho* committed upon the higheft provocation. See a re- cord to lIus purpofe of Henry HI. tranfcribed by Sir Edward Coke, 3 Inft. 62. or Blackftone's Com. vol. iv. p. 206. Caftration is fometimes found neceflary on medicinal confiderations, as in moitifications, and fome other difeafes of the tefticles, efpecially the farcocele and vu' r'icocde. Some have alfo ufed it in maniac cafes. 5 Cas- CAS Ciftratlon Castration is alfo in fome fort pradifed on wo- Caftruccio. men. Athenaeus mentions, that king Andramytes "—sf—^ was the firft who caftrated women. Hefychiiis and Suidas fay Gyges did the fame thing. Galen obferves, that women cannot be caftrated without danger of life : and Dalechampius, on the forementioned paffage of Athenaeus, holds, that it is only to be underftood of fimple padlocking. Castration, in refpc£l of brutes, is called Geld- ing and Spaying. Castration alfo denotes the art of retrenching, or cutting away any part of a thing from its whole. — Caf- trating a book, among bookfellers, is the taking out fome leaf, flieet, or the like, which renders it imper- fe£t and unfit for fale. The term is alfo applied to the taking away particular paffages, on account of their obfcenity, too great freedom with refpeft to go- vernment, &c. Castration, among botanifts, a term derived from the fancied analogy betwixt plants and animals. The caftration of plants confifts in cutting off the untheray or tops of the ftamina, before they have attained ma- turity, and difperfed the pollen or fine dull contained within their fubftance. This operation has been fre- quently praftifed by the moderns, with a view to efta- blifli or confute the doftrine of the fexes of plants; the antheraj or tops being confidered by the fexualifts as the male organs of generation. The experiment of caftration fucceeds principally on plants which, like the melon, have their male flowers detached from the female. In fuch as have both male and female flowers contained within the fame covers, this operation can- not be eafily performed without endangering the neigh- bouring organs. The refult of experiments on this fubjedl by Linnaeus, Alfton, and other eminent bota- nifts, may be feen under the article Botany, fedl, iii. CASTREL, a kind of hawk refembling the -lanner in ftiape, but the hobby in fize. The caftrcl is alfo called keftrel, and is of a flow arid cowardly kind ; her game Is the grous, though ihe will kill a partridge. CASTRES, a city of Languedoc in France, about 35 miles eaft of Thouloufe. E Long. 2. and N. Lat. 43. 40. It is a bifliop's fee. CASTRO, the capital of the ifland of Chiloe, on the coaft of Chili in South America. W.Long. 82. 6. Lat. 4'3. Castro Is alfo the capital of a duchy of the fame name in the Pope's territories in Italy, fituated on the confines of Tufcany. E. Long. 12. 35. N, L^t. 42. 30, Castro (Pietro de), a celebrated painter, who flourlHied about the middle of the 17th century. The fubje6ts which this great artift chofe to paint, were what are diftinguiflied by the name offtill Ufe ; vafes, fliells, mufical inftruments, gems, veflels of gold, filver, and Cryftal, books, and rich bracelets ; and in thofe fub- je6ls his choice and difpofition were elegant, and his execution admirable. CASTRUCCIO (Caftracani), a cfelebrated Italian general, was born (nobody knows of whom) at Luc- ca in 'Florence in 1284, and left in a vineyard cover- ed with leaves, where he was found by Dianora a widow lady, the filler of Antonio, a canon of St Mi- chael in Lucca, who was defcendcd from the illuftri- VoL. IV. Part L [ 241 ] CAS ous family of the Caftracani. The lady having tio Caftiiiccl<5» children, they refolved to bring iiim up, and educated — -v— — him as carefully as he had been their own. They in- tended him for a prieft ; but he was fcarcely 14 years old when he began to devote himfelf to military fports, and thofe violent exerclfes which fuited his great ftrength of body. The factions named the Guelfs and Gibelines then flaared all Italy between them ; divided the popes and the emperors ; and engaged in their dif- ferent interefts not only the members of the fame town, but even thofe of the fame family. Francifco, a con- fiderable perfon on the fide of the Gibelines, obfer- vlng Caftruccio's uncommon fpirit and great qualities, prevailed with Antonio to let him turn foldler ; on which Caftruccio foon became acquainted with every thing belonging to that profeflion, and was made a lieutenant of a company of foot by Francifco Guinigi. In his firft campaign he gave fuch proofs of his cou- rage and condudt as fpread his fame all over Lombardy ; and Guinigi, dying foon after, committed to him the care of his fon and the management of his eftate. Still diftingulfliing himfelf by his exploits, he filled his com- mander in chief with fuch jealoufy and envy, that he was imprifoned by ftratagem in order to be put to death. But the people of Lucca foon releafed him, and afterwards chofe him for their fovereign prince. The Gibelines confidered him as the chief of their party ; and thofe who had been baniftied from their country fled to him for prote<9;ion, and unanimoufly promifed, that if he could reftore them to their eftatof , they would ferve him fo effieMijally that the fovereign- ty of their country fliould be \is reward. Flattered by thefe promifes, he entered into a league with the prince of Milan. He kept his army conftantly on foot, employing it as beft fuited his own defigns. For fervices he had done tlie pope, he v/as made fenator of Rome with more than ordinary ceremony ; but while there, received news which obliged him to haften back to Lucca. The Florentines entered into a war with lilm, but Caftruccio fought his way through them ; and the fuprcme authority of Tufcany was ready to fall into his hands, when a period was put to his life. In May 1328, he gained a complete viftory over his enemies, who amounted to 30,000 foot and 10,000 horfe ; in which 22,000 of them wer-^ flain, with the lofs of not quite 16,000 of his own men: but as he was returning from the field of battle, tired with the aftion, and covered with fweat, he halted a Utile, ia order to thank and carefs his foldlers as they pafled ; when, the north wind blowing upon him, he was im- mediately feized with an ague, which he at firft ne- glected, but it carried him off" in a few days, in the 44th year of his age. Machiavel, who has written the life of Caftruccio, fays, that he was not only an extraordinary man iii his own age, but would have been fo in any other. He was of a noble afpeCt, and of the moft winning addrefs. He had all the qualities that make a man great ; was grateful to his friends, juft to his fubje<3:s, terrible to his enem.ies. No man was more forward to encounter dangers ; no man more careful to efcape them. He had an uncommon prefence of mind, and often made rapartees with great fmartnefs. Some of them are rci- corded, which difcover a fingular turn of humour ; H h andj GAS [ 242 Caftruccio and, for a Specimen, we ftiall mention three or four of by „ J." , them. — Faffing one driy through a ftreet where there 1 I ^ , was a houfe of bad fame, he furprifed a young man,^ who wasjuft coming out, and who, upon feeing him, was all over bluihes and confufion : " Friend, you fhould not be afhamed when you come out, but when you go in." — One alking a favour of him with a thou- sand impertinent and fuperfluous words : " Hark you, friend ; when you would have any thing with me for the future, fend another man to aflt it." — Another great talker having tired him with a tedious difcourfe, cxcufed himfelf atlaft, by faying, he was-afraidhe had been troublefome. " No indeed, (replied he), for I did not mind one word you faid." — He was forced to put a citizen of Lucca to death, who had formerly been a great inftrument of his advancement; and being reproached by fomebody for having dealt fo feverely with an old friend, replied, " No, you are miftaken, it was with a new foe." — One of his courtiers, defi- TDUs to regale him, made a ball and invited him to it. Caftruccio came, entertained himfelf among the ladies, danced, and did other things which did not feem to comport with the dignity of hi« rank. One of his firiends intimating that fuch freedoms might diminifti the reverence that ought to be paid him : " 1 thank you for your caution ; but he who is reckoned wife all the day, vnH never be reckoned a fool at night," CASTRUM DOLORis, in middle-aged writers, denotes a c^tafalco, or a lofty tomb of ftate, erefted in honour of fome perfon of eminence, ufually in the church where his body is interred; and decorated with arms, emblems, lights, and the like. Ecclefiaftical writers fpeak of a ceremony of confe- CTViting a cq/irum cloloris ; the edi6ce was to be made to reprefent the body of the deceafed, and the prieft and deacon were to take their pofts, and fay the pray- ers after the fame. manner as if the corpfe were aftually ' prefent. CASTS. See Casting. CASU coNSiMiLi, in law, a writ of entry granted xvhere a tenant, by courtefy or for life, aHens either in fee, in tail, or for the term of another's life- It h brought by him in reverfion agaiaft the perfon to whom fuch tenant does .fo alien to the prejudice of the reverfioner in the tenant's life-time. CAsv-Prov'tfo, in law, a writ of entry founded on the ftatute of Gloucefter, where a tenant in dower aliens the la.ids /he fo holds in fee, or for life ; and lies for the party in reverfion againft the alieuce. CASUAL, fomething that happens fortuitoufly, without any defign, or any meafures taken to bring it to pafs. Casual- Re-venues, ate thofe which arife from for- feitures, confifcations, deaths, attainders, i5c. CASVAL-Theology, di denomination given to, what is more frequently called Casuistry. CASUALTY, in a general fenfe, denotes an acci- dent, or a thing happening by chance, not defign. It is particularly ufed for an accident producing unna- tural death. Casualty, in Scot's few. Cafualtks of a fupsr'ior^ arc thofe duties and emoluments wliich a fuperi- ©r has right to demand out of his and befides the conftant yearly vafTal's eftate, over duties eftabliihed 1 CAT the reddendo of his charter upon certain cafual events. Casualty, in Metallurgy. SeeCAusALTY. CASUIST, a perfon who propofes to refolve cafes of confcience. ECcobar has made a coUeAion of the opinions of all the cafuifts before hira. M. Le Feore, preceptor of Louis XIII. called the books of the ca- fuifts the art of quibbling with God ; which does not feem far from ti'uth, by reafon of the multitude of di- ftinftions and fubtleties they abound withal. Mayer has publiihed a bibliotheca of cafuiits, containing an account of all the writers on cafes of confcience, ran- ged under three heads, the lirft comprehending the Lutheran, the fecond the Calvinift, and the third the Romifh, cafuifts. CASUISTRY, the dodlrine and fcience of con- fcience and its cafes, with the rules and principles of refolving the fame ; drawn partly from natural reafon . or equity ; partly from authority of fcripture, the ca- non law, councils, fathers, i^c. To cafuiftry belongs the decifion of all difficulties arifing about what a man ■ may lawfully do or, not do ; what is fin or not fin ; what things a man is obliged to do in order to dif- charge his duty, and what he may let alone without- breach of it. CASUS AMissiONis, in Scots law, in a&ions pro- ving the tenor of obligations inextinguifliable by the debtors retiring or cancelling them, it is neceffary for the puifuer, before he is allowed a proof of the tenor, to condefcend upon fuch a cafus amijjionts, or accident by which the writing was dellroyed, as (hows it was. , loft while in the writer's pofieffion. ' CAT, in zoology. See Felis. Cat, in fea -affairs, a ftiip employed in the coal- trade, formed from the Norwegian model. It is dif- tinguilhed by a narrow ftern, projefiing quarters, a deep fufa'tfle, and by having ornamental figures on the prow. Tliefe veflels are generally built remarkably ftrong, and carry from four to fix hundred tons, or, in the language of their own mariners, from 20 to 30 keels of coals. Cat, is alfo a fort of ftrong tackle, or combination , of piiUies, to hook and draw the anchor perpendicu- larly up to the cat-head. See C4T-Heads. Cat's Eye, or Sun-JIone of the Turks, a kind of gem found chiefly in Siberia. Cat's-tye is by the Latins called occulus cati, and fometimes onycopahs, as having white zones or rings like the onyx ; and its colours variable like opal, from which laft it differs chiefly by its fuperior hardnefs. It is very hard, and femitranf- . parent, and has different points, from whence the light is refle£led with a kind of yellowifti radiation fome- what fimikr to the eyes of cats, from whence* it had its name.. The beft of them are very fcarce, .and- jewellers cut them round to the greateft advantage. One ©f thefe ftones, an irich in diameter, was in the ppffeffion of the duke of Tufcany. CAT-F'i/hy in ichthyology* See StiUALUS. CAT-Guf, a denomination given to fmall ftrings for fiddles, and other inftruments, made of the inteftines of ftieep or lambs, dried and tv/ifted together, either fingly, or feveral together. Thefe are fometimes co- loured red, fometimes blue, but are commonly left whitifli or browniffi, the natural colour of the gut» They C A t [143 Cat-harp- They are alfo uiTed by watch -mkkers, cutlers, turners, »"g* and other artificers. Great quantities are imported Catacomb England, and other northern countries, from Ly- ons and Italy. CAT-HarplngSy a purchafe of ropes employed to brace in the flirowds of the lower mafts behind their yards, for the double purpofe of making the (hrowds more tight, and of affording room to draw in the yards more obliquely, to trim the fails for a fide- wind, when they are faid to be clofe hauled. CAT-Heads, two ftrong fliort beams of timber, which projedl alraoll horizontally over the fhip's bows on each fide of the bow-fprit ; being like two radii which extend from a centre taken in the direction of the bow-fprit. That part of the cat-head which refts upon the forecaftle, is fecurely bolted to the beams : the other part projects like a crane as above defcribed, and carries in its extremity two or three fmall wheels or Jheaves of brafs or ftrong wood, about which a rope called the cat-fall paffes, and communicates with the cat-block, which alfo contains three fheaves. The machine formed by this combination of puUies is called the Cat, which fei-ves to pull the anchor up to the cat- head, without tearing the fhip's lides with its flukes. The cat-head ajfo ferves to fufpend the anchor clear of the bow, when it is neceffary to let it go : it is fup- ported by a fort of knee, which is generally ornament"- ed with fculpture. See Plate CXXVIII. The cat-block is filled with a large and ftrong hood, which catches the ring of tlie anchor when it is to be tlrawn up. CAT-Mint, See Mentha. CAT-Salt, a name given by our falt-workcrs to a very beautifully granulated kind of common fait. It is formed out of the bittern, or leach-brine, which runs from the fait when taken out of the pan. When they draw -out the common fait from the boiling pans, they put it into long wooden troughs, with holes bored at the bottom for the brine to drain out ; under thefe troughs are placed veflels to receive this biine, and a- rrofs them fmall fticks to which the cat-falt affixes it- felf in very large and beautiful cryftals. This fait contains feme portion of the bitter purging fait, is very fharp and pungent, and is white when powder- rd, though pellucid in the mafs. It is ufed by fome for the table, but the greateft part of what is made lof it is ufed by the makers of hard-foap. CAT-Silver. See MiOA. CATAC AUSTIC curves, in the higher geometry, that fpecies of cauftic curves which are formed by re- fieftlon. See Fluxions. CATACHRESIS, in rhetoric, a trope which bor- tows the name of one thing t.< exprefs another. Thus Milton, defcribing Raphael's defcent from the empy- real heaven to paradife, fays, ** Down thither prone in flight, *' He fpeeds, and through the vaft etherial fl<;y " Sails between worlds and worlds." CATACOMB, a grotto, or fubterraneous place for the burial of the dead. Some derive the word catacomb from the place where I CAT anciently wrote catatumbas. Others fetch the word Gatac ottAs. from the Greek •'■^t^> and r.^n-^®--, a hollow, cavity, or ' ' ' the like. Anciently the word catacomb was only underftood of the tombs of St Peter and St Paul ;• and M. Chafte- laln obferves, that, among the more knowing of the people of Rome, the word catacomb is never applied to the fubterraneous burying-places hereafter mentioned, but only to a chapel in St Sebaftian, one of the feven ftational churches ; where the ancient Roman kalen- dars fay the body of St Peter was depofited> under .the confulate of Tufcus and BafTus, in 258. Catacombs of Italy ; a vafl affemblage of fubter- raneous fepulchres about Rome, chiefly at about three miles from that city in the Via Appia ; fuppofed to be the fepulchres of the martyrs ; and which are vifi- ted accordingly out of devotion, and relics thence ta* ken and difperfed throughout the catholic countries, after having been firft baptized by the pope under the name of fome faint. Thefe catacombs are faid by ma- ny to be caves or cells wherein the primitive Chri- ftians hid and affembledthemfelves together, and where they interred fuch among them as were martyred. Each catacomb is three feet broad, and eight or ten high ; running iii form t)f an alley or gallery, and communicating with others : in many places they ex- tend within a league of Rome. There is no mafomy or vaulting therein, but each fupports itfelf : thg two fides, which we may look on as the parietes or walls, were the places where the dead were depofited ; which were laid lengthwife, three or four rows over one an- other, in the fame catacomb, parallel to the alley. They were commonly clofed with large thick tyles, and fometimes pieces of marble, cemented in a manner in- imitable by the moderns. Sometimes, though very rarely, the name of the deceafed is found on the tyle : frequently a palm is feen, painted or engraven, or the cipher Xp, which is commonly read pro Chrijlo. The opinion held by many Proteftant authors is, that the catacombs are. heathen fepulchres, and the fame with the puticuli mentioned by Feftus Pompeius ; maintaining, that whereas it was the practice of the ancient Ro- mans to burn their dead, the cuftom was, to avoid expence, to throw the bodies of their flaves to rot in holes of the ground ; and that the Roman Chri- ftians, obferving, at length, the great veneration paid to relics, refoJved to have a ftock of their own : enter- ing therefore the catacombs, they added what ciphers and infcriptions they pleafed; and then fhut them up again, to be opened on a favourable occalion. Thofe in the fecret, add they, dying or removing, the con- trivance was forgot, till chance opened them at laft. But this opinion has even lefs of probability than the former. Mr Monro, in the Philojophical Tranfa£lions, fuppofes the catacombs to have been originally the common fe- pulchres of the firft Romans, and dug in confequence of thefe two opinions, w'z. That fliades hate the light; and that they love to hover about the places where the bodies are laid. Though the catacombs of Rome have made the greateft noife of any in the world, there are fuch be- longing to many other cities. Thofe of Naples, ac- jhips are laid up, which the modern Latins and Greeks call cumba. Others fay, that cata was ufed for ad, and cording to bifliop Burnet, are much more noble and f*/tff««i3^c.U and ^f^/^=^, I run), m antiquity, aftixtched floping rope in the theatres, down which the funambuH walked to fhow their fltill. Some have taken the word to fignify the hippodrome or decurforium wherein the Roman knights ufed to exercife themfelves in running and fighting on horfe-r back. But the moft natural meanmg is that of a rope faftened at one end to the top of the theatre, and at the other to the bottom, to walk or run down, which was the highefl. glory of the ancient fchanobates or fu- nambul't. Elephants were alfo taught to run down the catadromus. Suetonius fpeaks of the exploit of a Ro- man knight, who palfed down the catadrmus mounted on an elephant's back. CATAGOGION, a heathen fellival at Ephefus> celebrated on the 22d of January, in which the devo- tees run about the ftreets, drefTed in divers antic and unfeemly manners, with huge cudgels in their hands, and carrying with them the images of their gods ; in which guife they raviflied the wQmen they met with, abufed and often killed the men, and committed many other diforders, to which the religion of the day- gave a fandlion. < CATAGRAPHA, in antiquity, denote oblique figures or views of mens faces; anfwering to what the moderns profiles. Catagrapha are faid to be the invention of Simon CleontEus, who firft taught painters to vary the looks of their figures, and fometimes direft them upwards, fometimes downwards, and fometimes fidewards cw backwards. CATALEPSIS, or Catalepsy, in medicine, a kind CAT [2 'Catalogue, kind of apoplexy or a drowfy difeafe wherein the patient ■~v~— ' is taken fpeechlefs, fenfelefs, and fixed in the fame poflure wherein the difeafe firft feized him ; his eyes open, without feeing or underftanding. See Medi- ci me -/nc/ex. CATALOGUE, a lift or enumeration of the names of feveral books, men, or other things, difpofed ac- cording to a certain order. Catalogues of books are digefted in different man- ners, fome according to the order of the times when the books were printed, as that of Mattaire j others according to their form and fize, as the common book- fellers-catalogues ; others according to the alphabetical order of the authors names, as Hyde's catalogue of the Bodleian library ; others according to the alpha- betical order of matters or fubjedls, which are called real or clafftcal catalogues, zs thofe of Lipeniusand Draudiusj iaftly, others are digelted in a mixed method, partaking of feveral of the former, as de Seine's catalogue of cardi- nal Slufms's library, which is firft divided according to the fubjefts or fciences, and afterwards the books ia each are i-ecited alphabetically. The moft applauded of all catalogues 13 that of Thu- anus's library, in which are united the advantages o£ all the reft. It was firll drawn up by the two Puteani in the alphabetical order, then digefted according to the fciences and fubjedls by Iftm. BuUialdus, and pubhftied by F. Quefnel at Paris in 1679; and re- printed, though incorrectly, at Hamburg, in 1704. The books are here ranged with juftnefs under their feveral fciences and fubjefts, regard being ftill had to> the nation, feA, age, &c. of every writer. Add, that only the beft and choiceft books in every fubjedt are found here, and the moft valuable editions. Yet the catalogue of M. le Telliers archbiftiop of Rheim's library, made by M. Clement, is not inferior to any publifhed in our age, either on account of the number and choice of the books, or the method of its difpo- lition. One advantage peculiar to this catalogue is, the multitude of anonymous and pfeudony mous authors detected in it, fcarce to be met with elfevvhere.^ Some even prefer it to Thuanas's catalogue, as containing a greater variety of claffes and books on particular fuh- jefts. The conditions required iiv a catalogue are, that it indicate at the fame time the order of the authors and of the matters, the form of the book,, the number of volumes, the chronological order of the editions, the language it is written in, and its place in the li- brary ; fo as that allthefe circumftances may appear at once in the fhorteft, cleareft, and exafteft manner pof- fible In this view, all the catalogues yet made will be found to be defedlive. An anonymous French writer has laid down a new plan of a catalogue, which ftiall unite all the advan- tages, and avoid all the inconveniences of the reft. The Jefuits of Antwerp has given us a catalogue of tlie popes; which makes what they call their Propylaum. Catalogue of the Stars, is a lift of the fixed ftars, difpofed in their feveral conftellations ; with the lon- gitudes, latitudes. Sec. of each. The firft who undertook to reduce the fixed ftars into a catalogue was Hipparchus Rhodius, about 120 years before Chrift ; in v.'hich he made ufe of the ob- 45 1 CAT fervations of Timocharis and Ariftyllus for about 180 Cataloguo, years before him. Ptolemy retained Hipparchus's ca- Cacalmna. talogue, containing 1026 fixed ftars ; though he him- ^ - felf made abundance of obfervations, with a view to a new catalogue, A. D. 140. About the year of Chrift 880, Albategni, a Syrian, brought down the fame to his time. Anno 1437, Ulugh Beigh, king of Parthia and India, made a new catalegue of 10Z2 fixed ftars,- fince tranflated out of Perfian into Latin by Dr Hyde.- The third who made a catalogue from his own obfer- vations was Tycho Brahe, who determined the places of 777 ftars for the year 1600, which Kepler from other obfervations of Tycho afterwards increafed to the number of 1000 ia the Rudolphine tables; adding, thofe of Ptolemy omitted by Tycho, and of other au- thors, fo that his catalogue amounts to above 1 160. At the fame time, WilUam landgrave of Heffe, with his mathematicians Chriftopher Rothmannus and Ju- ftus Byrgius, determined the places of 400 fixed ftars by his own obfervations, with- their places reftified for the year 1593 ; which Hevelius prefers, to thofe o£ Tycho's. Ricciolus, in his AJlrmomla Reformata, de- termined the places of loi ftars for the year 1700, from his own obfervations ; for the reft he followed Tycho's catalogue ; altering it where he thought fit. Anno 1667, Dr Halley, in the ifland of St Helena,, obferved 35.0 fouthern ftars not vifible in our horizon. The fame labour was repeated by F. Noel in 17 10, who publifhed a new catalogue of the fame ftars con- ftrufted for tlie year 1687. Bayer, in his Uranometria, pubfifhed a catalogue of I i.6q flars, compiled chiefly from Ptolemy and Tycho, in which every ftar is marked with fome letter of the Greek alphabet ; the biggeft ftar in any conftellation being .denoted by the firft letter, the next by the fe- cond, &c. and if the number exceeds the Greek alpha- bet, the remaining ftars are marked by letters of the Roman alphabet, which letters are preferved by Flam- jftead, and by Senex on his globes. The celebrated Hevehus compofed a catalogue of 1888 ftars, 1553 of which, were obferved by hirafelf ; and their places were computed for the year 1 660. The laft and greateft is the Britannic catalogue, compiled from the obfervations of the accurate Mr Flamftead ; who for a long feries of years devoted himfelf wholly thereto. As there was nothing want- ing either in the obferver or apparatus, we may look on this as a perfedi, work fo far as it goes. It is to be regretted the impreffion had not paffed through- his own hands : that now extant, was publifhed by authority, but without the author's confent : it con- tains 2734 ftars. There was another pubhfhed in 1725, purfuant to his teftament ; containing no lefs than 3Q00 ftars, with their places redlified for the year 1689 : to which is added Mr Sharp's catalogue of the fouthern. ftai-8 not vifible in our hemifphere, adapted to- the year 1726. CATALONIA, a province of Spain, bounded on the north by the Pyrenean mountains, which divide it from France ; by the kingdom of Arragon and Va- lencia on the weft; and by the Mediterranean fea on the fouth and eaft. It is 155 miles in length, and loO in breadth. It is watered by a great number of rivers; the principal of which are the Lgbregat, the Ter, aiid the^ CAT [ 246 ] GAT Catalonia u Catanan- che. tlic Scgra. "The ai'r is temperate and healthy ; but the land is mountainous, except in a few places. It produces, however, corn, wine, oil, pulff, flax, and hemp, fufficient for the inhabitants. The mountains are covered with large fofefls of tall trees, fuch as the oak, the ever-green oak, the beech, the pine, the fir, the chtfmit, and many others; with cork-trees, fln-ubs, and medicinal plants. There, are feveral quarries of marble of alt colours, cr^^ftal, alabafter, amethyfts, and lapis lazuli. Gold dull has been found among the fands of one or two of the rivers ; and there are mines of tin, iron, lead, alum, vitriol, znd fait. They like- wife fifh for coral on the eaflern coaft. The !nha!)i- tants are hardy^ courageous, aftive, vigorous, and good foldiers, but apt to be difcontented. The miquelets are a fort of foldiers which guard the pafles over the mountains, and ought to prote'61 travellers ; but if they are not paid to their minds, 'they feldom fail to pay themfelves. The river Lobregat divides Catalonia in- to two parts, the eaft and weft, according to their fi- tuation. This province comprehends 17 vigueries or territories; two of which are in Roufillon, and'helotig to the French. The reft are fubjeft to the Spaniards. The principal towns are Barcelona the capital, Tarra- gonaj Tortofa, Lerida, Solfonia, Cardo.na Vich, Gi- rona, Seu d'Urgel, Pui Cerda, and Cervera. Cata- lonia was the laft province in Spain which fubmitted to Philip in the fucceffion-war. CATAMENIA, in medicine. See Menses. CATAMITE, a boy kept for fodomitical prac- *tlces. CAT ANA, or Catjna (anc. geog.), a town of Si- cily, fituated oppofite to^tna, to the fouth-eaft ; one t£ the five Roman colonies : anciently built by the people of Naxus feven years after the building of Sy- racufe, 728 years before Chrill. It was the country of •Charondas, the famous lawgiver. The town is ftill called "Catanea. See Cjtakea. CATANANCHE, Candia lions-foot: A genus ©f the polygamia sequalis order, belonging to the fyn- genefia clafs of plants ; and in the natural method tanking under the 49th order, Compnfita. The recep- tacle is paleaceous ; the calyx imbricated ; the pappus furnifhed with awns by a caliculus of five ftiff hairs. There are three fpecies, of which the cerulea is the moft remarkable. This fends out many long, narrow, liairy leaves, which are jagged on their edges like thofe of the buckfhorn plantain, but broader ; the jags are deeper, and at greater diftances : thefe lie flat on the ground, turning their points upwards. Between the leaves com.e out the flower ftalks, which are in num- ber proportionable to the fize of the plants ; for, from an old thriving root, there are frequently eight or ten, while ycung plants do not fend out cibov(r two or three. Thefe ftalks rife near two feet high, dividing into many fmall branches upward, garnifhed with leaves like tbofe below, butfmaller, and v.'ithout jags on their edges ; each of thefe fmaller branches are terminated %>y fingle heads of flowers, of a fine blue colour. This is a. perennial plant, and may be propagated by feeds or flips. The feeds may be fown in the fpring on a i)ed of common earth ; and in the autumn following the plants may be removed to the places where they «ir to iremain. The feeds ripen in Auguft. This 3 pknt is a pretty ornament in gardens, and is eafily Catarca. kept within bounds. . v"^ CATANEA, or Catania, a city of Sicily, feated on a gulph of the fame name, near the foot of Mount -(Etna or Gib*;!. It was founded by the Chalcidians foon after the fettlement of Syracufe, and enjoyed ^reat tranquillity till Hiero I. expelled the whole body of citizens; and after replenifliing the town with a nev/ ftock of inhabitants, gave it the name of Mtna : im- mediately after his deceafe, it regained its ancient name, and its citizens returned to their abodes. Ca- tania fell into the hands of the Romans, among their earheft acquifitlons in Sicily, and became the refideiice of a prnstoi. To make it worthy of fuch an honour, it was adorned with fumptuous buildings of all kinds, and every convenience v/as procured to fupply the na- tural and artificial wants of life. It was deftrbyed by Pompey's fon, but rettored with fuperior magnificence ^ by Augufl;us. The reign of Decius is famous in the hiftory of this city for the martyrdom of its patronefs St Agatha. On every emergency her interceflion is implored. She is pioufly beheved to have preferved Catania from being overwhelmed by torrents of lava, or fliaken to pieces by earthquakes ; yet, its ancient edifices are covered by repeated ftreams of volcanic matter; and almoft every houfe, even her own church, has been thrown to the ground. In the reign of Wil- liam the Good, 20,000 Catanians, with their paftor at their head, were deftroyed before the facred veil could be properly placed to check the flames. In the laft century the eruptions and earthquakes raged with re- doubled violence, and Catania was twice deraoHflied. See .Etna. The prefent prince of Bifcari has been at infinite pains, and fpent a large fum of money, in working down to the ancient town, which on account of the numerous torrents of lava that have flowed out of Mount -(Etna for thefe laft thoufand years, is now to be fought for in dark caverns many feet below the pre- fent furface of the earth. Mr Swinburne informs us that he defcendcd into baths, fepulchres, an amphithe- atre, and a theatre, all very much injured by the va- rious cataftrophes that have befallen them. They were eredted upon old beds of lava, and even built with fquare pieces of the fame fubftance, which in no in* ttance appears to have been fufed by the contad of new lavas : The fciarra or ftones of cold lava, have conftantly proved as ftrong d barrier againft the flow- ing torrent of fire as any_other ftone could have been, though fome authors were of opinion that the hot matter vi'ould melt the old mafs and incorporate with it. This city has been frequently defended from the burning ftreams by the folid mafs of its own ramparts, and by the air comprefled between them and the lava ; as appears by the torrent having ftopt within a fmall diftance of the walls, and taken another direftion. But when the walls were broken or low, the lava col- lefted itfelf till it rofe to a great height, and then poured over in a curve. A fimilar inftana^ is feen at the Torre del Greco near Naples, where the ftr^am of liquid fire from Vefuvius divided itfelf into two branch- es, arid left a church untouched in thcmiddle. There is a well at the foot of the old walls of Catania, where the lava, after running along the parapet, and then falling CAT [ 24 Catanea falling forwards, has produced a very complete lofty II arch over the fpring. , ataphrac- r^^^ church here is a noble fkSrlc, It is accounted ^.—^^l— the largeft in Sicily, though neither a porch nor cu- pola has been eredlcd, from a doubt of the folidity of the foundations, which are no other than the bed of lava that ran out of iEtna in 1669, and is fuppofed to b.e full of cavities. The organ is much efteemed by connoilfeurs in mufical inftruments. ^ Catania, according to Mr Swinburne's account, is reviving with great fplendor. " It has already (he fays) much more the features of a metropolis and royal reiidence than Palermo ; the principal llreets are wide, ftraight, and well paved with lava. An obcliflc of red granite, placed on the back of an antique ele- phant of touchftone Hands in the centre of the great fquare, which is formed by the town-haU, femiwary, and cathedral. The cathedral ere£led by the abbot Angerius in the year 1094, was endowed by<;arl Roger with the territories of Catania and jEtna, for the fmall acknowledgment of a glafs of wine and a loaf of bread offered once a-year. It has fuffered fo much by earthquakes, that little of the original ilrufture re- mains, and the modern parts have hardly any thing ex- cept their materials to recommend them. The other re-- ligious edifices of the city are profufely ornamented, but in a bad tafte. The fpirit of building feems to have feized upon this people, and the prince of Bifcari's example adds frefh vigour. It were natural to fUppofe men would be backward in erefting newhabitations, efpecially with any degree of hixury, on ground f» often (haken to its centre, and fo often buried under the afiies of a volca- no ; but fuch is their attachment to their native foil, and their contempt of dangers they are habituated to, that they rebuild their houfes on the warm cinders of Vefuvius, the quaking plains of Calabria, and the black mountains of Sclarra at Catania; it is however farprifing to fee fuch embellifhrnents lavifhed in fo dangerous a fituation. There is a great deal of aftivity in the difpofition of this people : they know by tradition that their anceflors carried on a flourirning commerce ; and that, before the fiery river filled it up, they had a fpaclous convenient harbour, where they now have fcarce a creek for a felucca : they tliercfore wifh to reftore thofe advantages to Catania, and have often ap- plied to government for affiftance towards forming a mole and port, an undertaking their Itrength alone is unequal to ; but whether the rcfufal originates in the d<;ficiencies of the public-, treafury or the jealoufy of other cities, all their projefts have ended in fruitlefs applications. The number of inhabitants dwelling in Catania amounts to 30,000 ; the Catanians make it double : A confiderable portion of this number apper- tains to the univerfity, the only one in the ifland, and the nurfery of all tlte lawyers." E. Long. 15. 1 9. N. Lat. 37. 30. . CATANZARO, a city in the kingdom of Napksj the capital of Calabria Ulterior, with a bifhop's fee. It is the ufual refidence of the governor of the pro- vince, and is feated on a mountain, in E. Long. 18. 20. N. Lat. 38. 58. CATAPHONiCS, the fcience which coniidersthe properties of reflefted founds. See Acoustics. CATAPHORA, in medicine, the fame as Coma. CATAPHRACTA (from >c«?^, and ?p«^^^, I for- J ] ] GAT tify or arm), in the ancient military art, a piece of Cataphr: heavy defenfive armour, formed of cloth or leathef, *^ fortified with iron fcales or links, wherewith _ fome- Catapla times only the breaft, fometimes the whole body, and m-a. fometimes the horfe too, was covered. It was in ufe ^— — v*" among the Sarmatians, Perfians, and other barbarians. The Romans alfo adopted it early for their foot; aud» according to Vegetius, kept to it till the time of Gra- tlan, when the military difcipline growing remifs, and field exercifes and labour difcontinued, the Roman foot thought the cataphradta as well as the helmet toa. great a load to bear, and therefore threw both hy^ choofing rather to march againit the enemy bare-? breailed ; by which, in the war with the Goths, mul- titudes were dellroyed. Cataphractm Naves, fiilps armed and covered ia. fight, fo that they could not be eafily damaged by ths enemy. They were covered over with boards or planks, on which the foldiers were placed to defencr them ; the rowers fitting underneath,; thus fcreened from the enemy's weapons. CATAPHRACTUS, denotes a thing defended or covered on all fides with armour. , Cataphractus, or Cataphractarlus, more particu- larly denotes a horfeman, or even horfe, armed with cataphrafta. The cotaphraSa equites were a fort of cuiraffiers, not only fortified with armour tliemfelves, but having tlieir horfes guarded with foHd plates of brafs or other metals, ufually lined with flcins and wrought into plumes or other forms. Their ufe was to bear wn all before them, to break in upon the enemies ranks, and fpread terror and havock wherever they came, as being themfelves invulnerable and fecure from danger. But their difadvantage was their un- wieldinefs, by which, if once unhorfed or on the • ground, they were unable to rife» and thus fell a prey to the enemy », CATAPHRYGIANS, a fed in the fecond cen- tury, fo called as beiiig of the country of Phrygia. They were orthodox, in every thing, fetting afide this, that they took Montanus for a prophet, and Piifcilla and Maximiila for true propheteffes, to be confulted in . every thing relating to religion ; as fuppofing the Holy fpirit had abandoned the church. See Montan irt. CATAPLASMA, a poultice ; from xai^tsrA-ac-c-^j, . ilUno, to fpread like a plafter. Gataplafms take their name fometimes from the part. to which they are ap- plied, or efFe&s thfcy produce ; fo are called anacollema, , frontale, ep'icarp'ium., epifpafllcum, vejicatorium ; and when muftard is an ingredient, they are called finapijms. Thefe kind of applications are fofter and more eafy than plafters or ointments. They are formed of fome - vegetable fubllances, and applied of fuch a confiftence as neither to adhere nor run : they are alfo more ufe- ful when the intention is effedled by the perpetuity of the heat or cold which they contain, for they retain- them longer than any other kind of compofition.- When defigned to relax, or to promote fuppura- tion, they fhould be applied warm. Their warmth, moifturc, and the obftruAion they give to perfpira- tion, is the method of their anfwering that end. The proper heat, when applied warm, is no more than to promote a kindly pleafant fenfation ; for great heat prevents the defign for which they are ufed. They ftiould be renewed as often as they cool. For relaxing . and C A T Catapulti. atid fuppurating, none excel the vvhlte-bread poultice, ^ ♦"' made with the crumb of an old loaf, a fufficient quan- tity of milk to boil the bread in until it is foft, and a little oil ; which laft ingredient, befides preventing the poultice from drying and flicking to the fkin, alfo retains the heat longer than the bread and milk alone would do. To preferve the heat longer, the poultice, when applied, may be covered with a ftrong ox's bladder. When defigned to repel, they fhould be applied cold, and ought to be renewed as oft as they become warni. A proper compofrtion for this end is a mixture of oat- meal and vinegar. CATAPULTAj in antiquity, a military engine contrived for the throwing of arrows, darts, and ftones upon the enemy.-^Some of thefe engines were of fuch force that they would throw ftones of an hundred weight. Jofephus takes notice of the furprifmg effefts of thefe engines, and fays, that the ftones thrown out of them beat down the battlements, knocked off the angles of the towers, and would level a whole file of •men from one end to the other, was the phalanx ever fo deep. This was called the Battering Catapulta, and is reprefented on Plate CXXVII. This catapulta is fuppofed to carry a ftone, l^c. of an hundred weight, and therefore a defcription of it will be fufficient to explain the 'do6lrine of all the reft ; for fuch as threw ftoneg of 500 and upwards were conftrudled on the fame prin- ciples. The bafe is compofed of two large beams a, 3. The length of thofe beams is fifteen diameters of the bore •of the capitals 9. At the two extremities of each beam, two double mortifes are cut to receive the eight tenons of two crofs beams, each of them four of the diameters in length. In the centre of each of • the beams of the bafe, and near two thirds of their length, a hole, perfeftly round, and 16 inches in diame- ler, fliould be bored : thefe holeis muft be exadlly opi- |)ofite to each other, and ftiould increafe gradually to the infide of the beams, fo that each of them, being 16 inches on the outfide towards the capitals 9, Ihould be 1 74- at the opening on the infide, and the edges carefully rounded off". The capitals 9 are, in a manner, the foul of the machine, and ferve to twift and ftrain the cordage, which forms its principle or .power of motion. The capitals are either of caft brafs or iron ; each confifting of a wheel with teeth, C 10, of 24- inches thick. The hollow or bore of thefe wheels fliould be 1 1 ^ inches in diameter, perfeftly round, and the edges fmoothed down>> As the fr46lion would be too great, if the capitals rubbed agalnft the beams, by the extreme ftraining of the cordage, which draws them towards thefe beams, that inconvenience is remedied by the means of eight friftion- wheels, or cylinders of brafs, about the 13th of an inch in diameter, and an inch and one fixth in length, placed circularly, and turning upon axes, as reprefented at D 13, B 12. One of thefe frlAIon- wheels at large with its fcrew, by which it Is fattened into the beam, is reprefented at A. Upon this number of cylindrical wheels the capitals g muft be placed in the beams, 2, 3, fo that the cylin- ders do not extend to the teeth of the wheels, which muft receive a ftrong pinion 14. By the means of this K° 67. 2 r 248 ] CAT pinion the wheel of the capital is made to turn fol* Catapto^f<^. ftraining the cordage with the key 15. The capital v wheel has a ftrong catch 1 6, and another of the fame kind may be added to prevent any thing from giving way through the extreme and violent force of the ftralned cordage. The capital-piece of the machine is a nut or crofs- pln of iron, 17, feen at C, and hammered cold into its form. It divides the bore of the capitals exaftly in two equal parts, and fixed in groves about an inch deep. This piece, or nut, ought to be about two in- ches and one-third thick at the top 18, as reprefented in the feftlon at B ; and rounded off and pollfhed as much as poffible, ihat the cords folded over it may not be hurt or cut by the roughnefs «r edges of the iron. Its height ought to be eight inches, decreafing gra- dually in thicknefs to the bottom, where it ought to be only one Inch. It muft be very exa£lly inferted in the capitals. After placing the two capitals in the holes of the two beams in a right line with each other, and fixing the two crofs diametrical nuts or pieces over virhlch the cordage Is to wind, one end of the cord is reeved through a hole in one of the capitals in the bafe, and made faft to a nail within-fide of the beam. The other fide of the Cord is then carried through the hole in the oppofite beam and capital, and fo wound over the crofs pieces of iron in the centre of the two capi- tals, till they are full, the cordage forming a large ilcaln. The tenfion or ftraining of the cordage ought to be exaftly equal, that is, the feveral foldings of the cord over the capital-pieces ftiould be equally ftralned, and fo near each other as not to leave the leaft fpace between them. As foon as the firft folding or fliain cord has filled up one whole fpace or breadth of the capital pieces, another muft be carried over it ; and fo on, always equally ftraining the end till no more will pafs through the capitals, and the llcain of cordage en- tirely fills them, obferving to rub it from time to tlnie with foap. At three or four inches behind the cordage, thus wound over the Capital pieces, two very ftrong upright beams 21 are raifed : thefe are pofts of oak 14 inches thick, croffed over at top by another of the fame foli- dity. The height of the upright beams is 74- diame- ters ; each fupported behind with very ftrong props 25;, fixed at bottom in the extremities of the bafe 2, 3. The crofs beam 24 is fupported in the fame manner by a prop in the centre. The tree, arm, or ftylus 22, fhould be of found afh. Its length is from 15 to 16 diameters of the bore of the capitals. The end at the bottom, or that fixed in the mMdle of the flcain, is 10 inches thick, and 14 broad. To ftrengthen the arm or tree, it fhould be wrapped round with a cloth dipped in ftrong glue like the tree of a faddle, and bound very hard with waxed thread of the fixth of an inch in diameter from the large end at bottom, almoft to the top, as reprefented in the figure. A,t the top of the arm, j lift under the iron-hand or receiver 27, a ftrong cord is faftened, with two loops twifted one within another, for the greater ftrength. Into thefe two loops the hook of a brafs pulley 28 is put. The cord 29 is then reeved through the pulley, and faftened to the roll 30. The cock or trigger 31, which CAT Fig- a- vvhicK ferves as -a ftay, is then brought to it, and made fall by its hook to the extrtmity of the hand 27, in which the body to be difcharged 13 placed. ' The pulley atlhe neck of the arm is then unhooked ; and when the trigger is to let it off, a ftroke muft be given upon it with an iron- bar or crow of about an inch in diameter; on which the arm flies up with a force almoft equal to that of a modern mortar. The aifhion or ftomacher 23, placed exaAly in the middle of the crofs beam 24, fhould be covered with tanned ox-hide, and rtufFed with hair, the arm ftriking againft it with inconceivable force. It is to be obferved, that the tree or arm 22 defcribes an angle of 90 degrees, beginning at the ccck, and ending at the ftomacher or cufhion. Catapvlta for Jrroivs, Spears, or Darts. Some of the fpears, ^c. thrown by thefe engines, are faid to have been 18 feet long, and to have been thrown with fuch velocity as to take fite in their courfe. A B C D is the frame that holds the tkrts or ar- rows, which may be of different numbers, and placed ^n different direftions. E F is a large and ftrong iron fpring, which is bent by a rope that goes over three puUies, I, K, L ; and is drawn by one or feveral men ; this rope may be fattened to a pin- at M. The rope, therefore, being fet at liberty, the fpring muft Itrike the darts with great violence, and fend them, with furprifing velocity, to a great diftance. This in- ftrument differs in fome particulars from the defcription we have of that of the ancients ; principally in the throwing of feveral darts at the fame time, one only being thrown by theirs. CATARACT, in hydrpgraphy, a precipice In the channel of a river, caufed by rocks, or other obftacles, flopping the courfe of the ftream, from whence the water falls with a greater noife and Impetuofity. The word comes from x-aTappxa-au, '< I tumble down with violence compounded of ""tk, «' down," and pac-c-c-, dejicio, " I throw down." — Such are the catarafts of the Nile, the Danube, Rhine, &c. In that of Niagara, the perpendicular fall of the water \^ 137 feet: and in that of Piftlll Rhaladr, yin North Wales, the fall of water is near 240 feet from the mountain to the lower pool. Strabo calls 'that a cataraS which we call a cafcade; and what we call a cataraBy the ancients ufually called a catadupa. 'Herminius has an exprefs differtation, " De admlrandls mundi Cataraftis fupra et fubter- ranels where he ules the word in a new fenfe ; fignifylng, by catarad, any violent motion of the elements. Cataract, in medicine and furgery, a diforder of the humours of the eye, by which the pupllla, that ought to appear tranfparent and black, looks opaque, blue, grey, brown, &c. by which vifion is varioufly impeded, or totally deftroyed. See Sur- gery. CATARO, a town of Dalmatia, and capital of the territory of the fame name, with a ftrong caftle, and a biOiop's fee. It is fubjecSl to Venice, and feated on a gulph of the fame name. E.Long. 19. 19. N. Lat. 42. 25. CATARACTES, m ornithology, the trivial name of a fpecles of Larus. CATARRH, in medicine, a diftillation or defluxlon Vox. IV. Parti. 49 ] ' Gat from the head upon the mouth and afpera arteria, and CataflaCs through them upon the lungs. See (the Index fub- Catcchefis. joined to) Medicine. ; CATASTASIS, In poetry, the third part of the ancient drama ; being that wherein the intrigue, or aftion, fet forth in the epitafis, is fupported, carried on, and heightened, till it be ripe for the unravelling in the cataftrophe. Scaliger defines it, the full growth of the fable, while things are at a ftand in that confufiou to which the poet has brought them. CATASTROPHE, in dramatic ptjctry, the fourth and laft part in the ancient drama ; or that immediate- ly fucceeding the cataftafis : or, according to others, the third only ; the whole drama being divided into protafis, epitafis, and cataftrophe ; or in the terms of Ariftotle, prologue, epilogue, and exode. The cataftrophe cleard up every thing, and Is nothing elfe but the difcovery or winding up of the plot. It has its peculiar place : for it ought entirely to be con- tained, not only In the kil aft, but in the very concla- fion of it; and when the plot is finifhed, the play Ihould be fo alfo. The cataftrophe ought to turn upon a fingle point, orftart up on a fudden. The great art In the cataftrophe is, that the clear» Ing up of all difficulties may appear wonderful, and yet eafy, fimple, and natural. It Is a very prepofterous artifice of fome writers to fhow the cataftrophe in the very title of the play. Mr Dryden thinks that a cataftrophe refulting from a mere change in the fentiments and refolutlons of a perfon, without any other machinery, may be fo managed as to be exceedingly beautiful. It Is a difpute among the critics, whether the cata- ftrophe fhould always fall out favourably on the fide of virtue or not. The reafons on the negative fide feem the ftrongeft. Ariftotle prefers a fhocking cataftrophe to a happy one. — The cataftrophe is either fimple or com- plex. The firft is that In which there is no change in the ftate of the principal perfons, nor any difcovery or unraveUIng, the plot being only a mere paffage out of agitation into quiet repofe. In" the fecond, the principal perfons undergo a change of fortune, in the manner already defined. CATCH, In the mufical feiife of the word, a fugue in the unifon, wherein, to humour fome conceit In the words, the melody is broken, and the fenfe Interrupted in one part, and caught again or fupported by another ; as in the catch in Shakefpeare's play of theTwelfth-night, where there is a catch fung by three perfons, in which the humour Is, that each who fings, calls and Is called hiwue in turn : Or, as defined by Mr Jackfon, ** a catch is a pIece*for three or more voices, one of which leads, and the others follow in the fame notes. It muft be fo contrived, that refts (which are made for thatpurpofe) in the mufic of one line be filled up with a word or two from another hne j thefe form a crofs purpofe, or catch, from whence the name." CATcn-FIy, in botany. See Lychnis. CATCH-Pvky (quafi one that catches by the pole), it term ufed, by way of reproach, for the bailiff's follow- er or afliftant. CATCii-lVord, among printers, that placed it the bot- tom of each page, being always the firft word of the fol- lowing page. CATECHESrS, In a general fenfe, denotes an in- I i " ftruftlon CAT [ 250 ] CAT Catechctic ftruAioa given any perfon in the firft rudiments of an art or fcience ; but more particularly of the Chriftian religion. In the ancient church, catechefis was an inftrudion given viva voce, either to children, or adult heathens, preparatory to their receiving of baptifm. In this fenfe, catechefis {lands contradiftinguiOied from myjlagogica, which were a higher part of inftruftion given to thofe already initiated, and containing the myfteries of faith. Thofe who give fuch inftruftions are called catech'ijls. ; and thofe who receive them, cate- chumens. CATECHETIC, or Catechetical, fomething that relates to oral inftruftion in the rudiments of Chri- ftianity. — Catechetic fchools were bu!ldinj:^s appointed for the office of the catechift, adjoining to the church, and called catechumena : fuch was that in which Origen and many other famous men read catechetical leftures at Alexandria. See Catechumen. CATECHISM, in its primary fenfe, an inftrue- tion, or inilitution, in the principles of the Chriftian religion, delivered viva voce, and fo as to rer|uire fre- quent repetitions, from the difciple or hearer, of what has been faid. The word is formed from y-amx-'^^ a c?ornpound of "^ .^ Zin^L ^x®'-> ({. d. circumfono, alluding to the noife or din made in this fort of exercife, or to the zeal and earneltnefs wherewith things are to be in- culcated over and over on the learners. — Anciently the candidates for baptifm were only to be inftrudled in the fecrets of their religion by tradition viva voce, without writing ; as had alfo been the cafe among the Egyptian priefts, and the Britifli and Gaulifh druids, who only communicated the myfteries of their theo- logy by word of mouth. Catechism is more frequently ufedin modern times for an elementary book, wherein the principal articles ©f rehgion are fummarily delivered in the way of quef- tion and anfwer, tATECHIST, ^ocTix'r»c, catecheta, he that cate- chifes,. i. e^ he that inftrufts novices in the principles of religion.. Catechist more particularly denotes a perfon ap- pointed by the church to inftruft thofe intended for feaptiim, by word of mouth, in the fundamental ar- ticles of the Cliriftian faith. — The catechifts of churches were rainifters ufually diftindl from the bilhops and preft)yters, and had their auditories or catechumena apart. Their bufinefs was to inftruft the catechu- mens, and prepare them for the reception of baptifm. But the catechifts did not conilitute any diftinft or- der of the clergy, but were chofen out of any other order. The biihop himfelf fometimes perfornied the office ; at other times preft)yters, or even readers or deacons, were the catechifts. Origen feems to have had no higher degree in the church than reader, when he was made catechift at Alexandria, being only 1 8 years of age, and confequently incapablt of the deacon- fhip. CATECHU, in the materia medica, the name of a troche confifting of Japan eaith and guai arable, each two ounces, and of fugar of rofes fixteen ounces, beat together with a- little water. It is recommended as a mild rcttringent, &c. CATECHUMEN, a candidate for baptifm, or one ■who prepares himfelf for the receiving thereof. The catechumens, in church-hiftory, were the low- eA order of Chriftians In the primitive. church. They Categorlcali had fome title to the common name of Chriftian, ^si"g Vj^^g ' ^^-^ a degree above pagans and heretics, though not con- j fummated by baptifm.. They were admitted to the ftate of catechumens by the impofition of hands, and. the fign of the crofs.. The children of believing pa- rents were admitted catechumens, as foon as ever they were capable of inftrutlion : but at what age thofe of heathen parents might be admitted, is not fo clear.. As to the time of their continuance in this- ftate, there were no general rules hxed about it ; but the practice varied according to the difference of times and places, and the readinefs and proficiency of the catechumens themfelves. There were four orders or degrees of catechumens;, the firft were thofe inftmfted privately without the church, and kept at a diftance for fome time from the privilege of entering the church, to make them the more eager and defirous of it. The next degree were: the aadientes, fo called from their being admitted to hear fermons, and the fcriptures read in the church,, but v^^ere not allowed to partake of the prayers. The third fort of catechumens were the gemi-Jle3entes , fo^ called becaufe they received impofition of hands kneel'- ing. The fourth order was the competentes ekSi, de*~ noting the immediate candidates for baptifm, or fuch. as were appointed to be baptized the next approach- ing feftival ; before which, ftriil examination was made into their proficiency under the feveral ftages of catehetical exercifes. After examination, they were exercifed for twen- ty days together, and were obhged to fafting and confeffion : fome days before baptifm they went veil- ed ; and it was cuftomary to touch their ears, fay- ing, Ephatha, i. e. Be opened; as alfo to anoint their eyes with clay; both ceremonies being in imitation of our Saviour's practice, and intended to fhadow out to the catechumens their condition both before and after their admiflion into the Chriftian church. CATEGORICAL, in a general fenfe, is applied- to thofe things ranged under a Category. < Categorical alfo imports a thing to be abfolute,. and not relative ; in which fenfe it ftands oppofed to hypothetical. We fay, a categorical propofition, a ra- ft?^onVa/ fyllogifm, ^c, A categorical anfwer denotes, an exprefs and per* tinent anfwer made to any queftion or objeflion pro^^ pofed. CATEGORY, in logic, a feries or order of all the: predicates or attributes contained under any genus. The fchool-philofophers diftribute all the objefts o£ our thoughts and ideas into ctxX.i\n. genera or claffes,. Hot fo much, fay they, to learn what they do not know, as to communicate a diftinft notion of what they do [^know ; and thefe claffes the Greeks called- categories', and the Latins predicaments.^ Ariftotle made ten categories, viz. quantity, qua* lity, relation, aftion, paffion, time, place, fituation, and habit, which are ufually expreffed by the foUoWfi ing technical diftich : Arbor, f ex, firvos, ardore, refrigerat, ttjlosf Rure eras Jlabo, nec tunicatus ero, CATEK. See Bengal, no 15. CATENARIA, in the higher geometry, the name of a curve -line formed by a rope hanging freely from 6 twa CAT Caterpillar two points of fufpenfion, whether the points be hori "'"v^ zontal or not. See Fluxions. CATERPILLAR, in zoology, the name of all winged infefts when in their reptile or worm-ftate. See Eruca. Method of Dejlroying Caterpillars on Trees. — Take a chafing difh with lighted charcoal, and pla- ^ cing it under the branches that are loaded with ca- terpillars, throw fome pinches of brimftone upon the coals. The vapour of the fulphur, which is mortal to thefe infefts, will not only deilroy all that are on the tree, but prevent it from being infefted with them afterwards. A pound of fulphur will clear as many trees as grow on feveral acres. This method has been fuccefsfully tried in France. In the Journal Oecononiique, the following is faid to be infallible a- gainft the caterpillars feeding on cabbage, and per- haps may be equally ferviceable againft thofe that in- feil other vegetables. Sow with hemp all the bor- ders of the ground where you mean to plant your cabbage ; and, although the neighbourhood is infefted with caterpillars, the fpace inclofed by the hemp will be perfedtly free, not one of the vermin will approach it. CATERPjiLAR-Eafersy a name given by fome au- thors to a fpecies of worms bred in the body of the caterpillar, and which eat its flefh : thefe are owing to a certain kind of fly that lodges her eggs in the body of this animal, and they, after their proper changes, become flies like their parents. Mr Reaumur has given us, in his hiftory of infedls, fome very curious particulars in regard to thefe little worms. Every one of them, he obferves, fpins itfelf a very beautiful cafe of a cylindric figure, made of a very ftrong fort of filk ; thefe are the cafes in which this animal fpends its ilate of chryfalis ; and they have a mark by which they may be known from all other animal productions of this kind, which is, that they have always a broad ftripe or band furrounding their middle, which is black when the rcil of the cafe is white, and white when that is black. Mr Reaumur has had the pains and patience to find out the reafon of this Angularity, which is this : the Avhole fliell is fpun of a filk produced out of the creature's body ; this at firft runs all white, and towards the end of the fpinning turns black. The outfide of the cafe muft neceliarily be formed firft, as the creature works from within : confequently this is truly white all over, but it is transparent, and fliows the laft fpun or black filk througli it. It might be fuppofed that the whole infide of the ftiell fliouid be black ; but this is not the cafe : the whole is fafliioned before this black filk comes ; and this is employed by the creature, not to line the whole, but to fortify certain parts only ; and therefore is all applied either to the middle, or to the two ends omitting the middle ; and fo gives either a black band in the middle, or a blacknefs at both ends, leaving the white in tlie middle to appear. It is not unfrequent to find a fort of fmall cafes, lying about garden-walks, which move of themfelves; when thefe are opened, they are found to contain a fmall living worm. This is one of the fpecies of thefe caterpillar- eaters ; which, as foon as it comes out of the body of that animal, fpins itfelf a cafe for its transformation long before that happens, and lives in it without food CAT till that change comes on ; and it becomes a fly like that to which it owed its birth. CATERVA, in ancient military writers, a term ufed in fpeaking of the Gaulifh or Celtiberian armies, denoting a body of 6000 armed men. The word ca~ terva, or catervarius, is alfo frequently ufed by ancient writers to denote a party or corps of foldiers in difor- der or difarray : by which it ftands diftinguilhed from cohort or turma, which were in good order. CATESBiEA, the lily-thorn : A genus of the monogynia order, belonging to the tetrandria clafs of plants ; and in the natural method ranking under the 28th order, Lurida. The corolla is monopetalous, fun- nel-fliaped, very long above the receptacle of the fruit i the ftamina are within its throat ; the fruit a polyfper- mous berry. There is only one fpecies, viz. the fpinofa, which was difcovered in the ifland of Providence by- Mr Catefby, who gathered the feeds, and brought them to England. It rifes to the height of ten or twelve feet, and is covered with a pale ruflfet bark ; the branches come out alternately, and are garniftied with fmall leaves refembling thofe of the box-tree, coming out in clufters all round the branches at cer- tain diftances ; the flowers hang downward, and come out from the fide of the branches : they are tubulous and near fix inches long, very narrow at their bafe, but widening upwards towards the top, w^here it is divided into four parts which fpread open, and are re- flexed backward. They are of a dull yellow colour. This plant is propagated by feeds which muft be pro- cured from the country where it grows. The feeds muft be fown on a hot-bed, and are to be treated ia the fame manner as other tender exotics. CATHjERETICS, in pharmacy, medicines of a cauilic nature, ferving to eat off proud flefti. CATHARINE, Knights of St Catharine of Mount Sinai, an ancient iniHtary order, erefted for the alTift- ance and proteftion of pilgrim.s going to pay their devotions to the body of St Catharine, a virgin of A- lexandria, diftinguiflied for her learning, and faid to have fuffered martyrdom under Maximin. The body of the martyr having been difcovered on mount Sinai, caufed a great concourfe of pilgrims ; and travelling being very dangerous, by reafon of the Arabs, an or- der of knighthood was ei-efted in 1063, on the mo- del of that of the holy fepulchre, and under the pa- tronage of St Catharine : the knights of which ob- liged themfelves by oath to guard the body of the faint, keep the roads fecure, obferve the rule of St Bafil, and obey their grand mafter. Their habit was white, and on it were reprefented the inftruments of martyrdom whereby the faint had fuffered ; viz. a half- wheel anned with fpikes, and traverfed with a fword ftained with blood. Catharine, Fraternity of St Catharine at Sienna, .a, fort of religious fociety inftituted in that city, in honour of St Catharine, a faint famous for her re- velations, and for her marriage with Jefus Chrift, whofe wedding ring is ftill preferred as a valuable re- lick. This fraternity yearly endows a certain num- ber of deftitute virgins, and has tlie privilege of re- deeming annually two criminals condemned for mur- der, and the fame number of debtors, by paying their debts. CATHARTICS, in medicine, remedies which pro- I i 2 mote Caterta II Catharticy, CAT Cathecu 1 Cathetine. [ ] CAT mote evacuation by ftool. See Materia Medica. CATHECU, in botany. SeeARECA. CATHEDRA, in a general fenfe, a chair. — The word is more particularly ufed for a profeflor's chair, and a preacher's pulpit. Cathedra is alfo ufed for the bifhop's fee, or throne, in a church. CATHEDRAL, a church wherein is a bifhop's fee or feat : See Church, and Bishop. The word comes from the Greek x«6£j"^a, '"chair," of y-oc&ilofixi^ fedeOf " I fit." The denomination cathedral feems to have taken its rife from the manner of fitting in the ancient churches, or affemblies of primitive Chriftians : in thefe, the council, i. e. the elders and priefts, was called Prejhyter'wm ; at their head was the bifhop, who held the place of chairman, Cathedralis, or Caihedra- tlcus ; and the prefbyters, who fat on either fide, were alfo called by the ancient fathers, AJfeJfores Ep'ifcoporum. The epifcopal authority did not refide in the bilhop alone ; but in all the prefbyters, whereof the bifliop was prefident. A cathedral .therefore, originally, was different from what it is now ; the Chriftians, till the time of Conftantine, having no liberty to build any temple : by their churches they only meant their affem- blies; and by ea'hedrals, nothing more than confiilories. CATHERINE Parr. See Parr. Catherine I. Emprefs of Rujfia, a moll extraor- dinary perfonage, whofe hiftory deferves to be given in detail. She was the natural daughter of a country girl ; and was born at Ringen, a fmall village upon the lake VirtcherA'C, near Dorpt, in Livonia. The year of her birth is uncertain; but, according to her own account, fiie came into the world on the 5th of April, 1687. Her original name was Martha, which fhe changed for Catherine when flie embraced the Greek religion. Count Rofen, a lieutenant-colonel in the Swedifh fervice, who owned the village of Ringen, fupported, according to the cufl;om of the country, both the mother and the child ; and was, for that rea- fon, fuppofed by many perfons to have been her fa- ther. She loft: her mother when fhe was but three years old ; and, as count Rofen died about the fame time, fhe was left in fo deftitute a fituation, that the parifh-clerk of the village received her into his houfe. Soon afterwards Gluck, Lutheran minifter of Marien- burgh, happening, in a journey through thofe parts, to fee the foundling, took her under his protection, brought her up in his family, and employed her in at- tending his children. In 1 701, and about the 14th year of her age, fhe efpoufed a dragoon of the Swedifli garrifon of Marienburgh. Many different accounts are given of this tranfaftion : one author of great cre- dit affirms that the bride and bridegroom remained to- gether eight days after their marriage ; another, of no lefs authority, aflerts, on the contrary, that on the morning of the nuptials her hufband being fent with a detachment for Riga, the marriage was never con- fummated. Thus much is certain, that the dragoon was abfeat when Marienburgh furrendered to the Ruf- fians } and Catherine, who was referved for a higher fortune, never faw him more. General Bauer, upon the taking of Marienburgh, faw Catherine among the prifoners ; and, being fmit- tcn with her youth and beauty, took her to his houfe, where fhe fuperin tended his domeilic affairs, and was Catherine^ fuppofed to be his miilrefs. Soon afterwards fhe was — v— ^ removed into the family of prince Menzikof, who was no lefs ftruck with the attractions of the fair captive. With hira fhe hvcd until 1704; when, in the 17th year of her age, flie became the miftrefs of Peter the Great, and won fo much upon his affections, that he efpoufed her on the 29th of May 1711. The cere- mony v/as fecretly performed at Jawerof in Poland,, in the prefence of General Bruce ; and on the 20th of February 1712, it was pubUcly folcmnized with great pomp at Peterfburgh. Catherine, by the moil unwearied afiiduity and un- remitted attention, by the foftnefs and complacency of her difpofition, but above all by an extraordinary llvellnefs and gaiety of temper, acquired a vvonderful afcendency over the mind of Peter. The latter was fubjeft to occafional horrors, which at times rendered him. gloomy and fufpicious, and raifed his pafiions to fuch an height as to produce a temporary madnefs. In thefe dreadful moments Catherine was the only per- fon who durft venture to approach him ; and fuch was the kind of fafcination fne had acquired over his fenfes, that her prefence had an inftantaneous effeft, and tlie firft found of her voice compofed his mind and calmed his agonies. From thefe circumftances fhe feemed nc- ceffary, not only to his comfort, but even to his very . exiftence ; fhe became his infeparable companion on his journeys into foreign countries, and even in all his military expeditions. The peace of Pruth, by which the Ruflian army was refcued from certain deftruclion, has been wholly attributed to Catherine, though fhe was little more tlian an inllrument in procuring the confent of Peter. The latter, in his campaign of 1 7 1 1 againll the Turks, . having imprudently led his troops into a difadvantage- ous fituation, took the defperate refolution of cutting, his way through the Turkifh army in the night. With this refolution he retired to his tent in an agony of defpair, and gave pofitive orders that no one ilioukl be admitted under pain of death. In this important juncture the principal officers and the vice-chancellor Shaffirof afTembkd in the prefence of Catherine, and drew up certain preliminaries in order to obtain a truce from the grand vizir. In confequence of this de- termination, plenipotentiaries were immediately dif- patched, without the knowledge of Peter, to the grand vizir, and a peace obtained upon more reafonable conditions than could have been expefted. With thefe conditions Catherine, notwithflanding the orders if- fued by Peter, entered his tent, and prevailed upon him to fign them. Catherine, by her conduct on this occafion, acquired great popularity ; and the emperor particularly fpeclfies her behaviour -at Pruth as one of the reafons which induced him to crown her publicly at Mofcow with his own band. This ceremony was performed in 1724; and although defigned by Peter only as a proof of his aflTeftion,. was the principal caufe of her fubfequent elevation. Her influence continued undiminifhed until a fhort time before the death of the emperor, when foine circura- flances happened which occafioned fuch a coolnefs be- tween them as would probably have ended in a total rup- ture, if his death had not fortunately Intervened. The original CAT [ 253 . ] CAT athevine. original caufe of this mifunderftanding arofe from the which you fhall approve in my name." Baffevitz, find- Catherine. —y——- following difcovery of a fecret conneftion between Ca- ing Menzlkof afleep, awakened and informed him of """"v ' therine and her f.-rll chamberlain, whofe name was the preffing danger which threatened the emprefs and Mons. The emperor, v/ho was fufpicious of this con- her party. As no time remained for long deliberation, reftion, quitted Peterfburgh under pretence of remo- the prince inftantly feized the treafure, fecured the ving to a villa for a few days, but privately returned fortrefs, gained the officers of the guards by bribes- to- his winter palace in the capital. From thence he and promifes, alfo a few of the nobility, and the prin- occafionally fent one of his confidential pages with a cipal clergy. Thefe partizans being convened in the complimentary meffage to the emprefs, as if he had palace, Catherine miade her appearance : fhe claimed been in the country, and with fecret orders to obferve the throne in right of her coronation at Mofcow ; fhe her raotions. From the page's information the em- expoied the ill effc&s of a m.inority ; and promifed, peror, on the third night, furprized Catherine in an that, " fo far from depriving the great-duke of the arbour of the gardsn with her favourite Mons ; while crown, fiie would receive it only as a iacred depofit, his filler, Madame Balke, who was firft lady of the to be reftored to him when flie Ihould be united, in a- bed-chamber to tlie emprefs, was, in company with a nother world, to an adored hufband, whom (he was page, upon the watch without the arbour. now upon the point of lofing." Peter, whofe violent temper was inflamed by this The pathetic manner with which fhe uttered this difcovety, ftruck Catherine with his cane, as well as addreis, and the tears which accompanied it, added to the page, who endeavoured to prevent him from en- the previous diftribution of large fums of money and tering the arbour, and then retired without uttering jewels, produced the defired effcft : at the clofe of this a fingle word either to Mons or his filler. A few days meeting the remainder of the night was employed in after this tranfadlion thefe perfons were taken iiito making the necelTaiy preparations to infure her accef- . cullody, and Mons was carried to the winter palace, fion in cafe of the emperor's death, where no one had admiffion to him but Peter, who Peter at length expired in the morning of the 28th himfelf brought him his provifions. A report was at of January 1725. This event being made known^ . the fame time circulated, that they were imprifoned the fenate, the generals, the principal nobility and for having received bribes, and making their influence clergy, haftened to the palace to proclaim the new fo- over the emprefs fubfervient to their own mercenary vereign. The adherents of the great-duke feemed fe- views. Mons being examined by Peter, in the pre- cure of fuccefs, and the friends of Catherine were fence of major-general Ufchakof, and threatened with avoided as perfons doomed to dellruftion. At this the torture, confeffed the corruption which was laid juncture BalTevitz wliifpered one of the oppofite to his charge. He was beheaded ; his filler received party, *' The emprefs is miftrefs of the treafure five llrokes of the knout, and was baniflied into Sibe- and the fortrefs ; fhe has gained • over the guards and ria ; two of her foiis, who were chamberlains, were the fynod, and many of the chief nobility ; even here alfo degraded, and fent as common foldiers among the fhe has more followers than you imagine ; advife there- Ruihan troops in Perfia. On the day fubfequent to fore your friends to make no opposition as they value tlie execution of the fentence, Peter conveyed Cathe- their heads." This information being rapidly circu- rine in an open carriage under the gallows, to which lated, BafTevitz gave the appointed fignal, and the two was nailed the head of Mons. The emprefs, without regiments of guards, who had been gained by a largefs changing colour at this di-eadful fight, exclaimed, to declare for Catherine, and had already furroundcd " What a pity it is. that there is fo much corruption the palace, beat to arms. " Who has d^ued (ex- among courtiers!" claimed prince Repnin, the commander in chief) to This event happened in the latter end of the year order out the troops without my knov/ledge ?" " 1, ., 1724; and as it was foon followed by Peter's death, (returned general Butterlin), without pretending to and Catherine, upon . her acceffion recalled Madame difpute your authority, in obedience to the commands Balke, it has been fufpe£lcd that fhe fhortened the of my moil gracious miftrefs." This fhort repl)- was days of her hufband by poifon. But notwithftanding followed by a dead filence. In this moment of fuf- the critical iituation for Catherine ia which he died^ pence and anxiety Menzikof entered, .preceding Ca- cmd her fubfequent elevation, this charge is totally de- therine, fupported by the duke of Holftein. She at- flitute of the leall fhadow of proof : for the circum- tempted to fpeak,butwas prevented by fighs and tearv^s ■ ilances of Peter's diforder were too well known, and from giving utterance to her words : at length, reco- • the peculiar fymptoms of his laft illnefs fulficiently ac- vering herfelf, " I come (flie faid)^ notwithftanding count for his death, without the neceflity of recurring the grief which now overwhelms me, to aflfure you, thatj , to poifon. fubmiffive to the will of my departed hufband, whofe While Peter was yet lying in the agonies of death, memory will be ever dear to me, I atn ready to devote feveral oppofite parties were caballing to difpofe of the my days to the paiiiful occupations of government un-- crown. At a confiderable m.eeting of many among til Providence fliallfummon me to follow him." Then,, the principal nobility, it was fecretly determined, on after a fhort paufe, fhe artfully added, " If the great- the moment of his diflblution, to arreft Catherine, and duke will profit by my inftruftions, perhaps I ftialL to place Peter Alexievitch upon the throne. BafTevitz, have the confolation, during my wretched Widowhood, apprized of this refolution, repaired in perfon to the of forming for you an emperor worthy of the blood emprefs, although it was already night. " My grief and and the name of him whom you have now irretrievably confternation," replied Catherine, " render me inca- loft." " As this crifis (rephed Menzikof) is a mo-- pable of afting myfelf: do you and prince Menzikof ment of fuch importance to the good of the empires , confult together, and I will embrace the meafures and requires the moft mature deliberation, your ma- 4 je%/ CAT I 2 Gafherine. jtfty will permit us to confer, without reftraint, that this whole alFair may be tranfafted without reproach, as well in the opinion of the prefent age as' in that of •pofterity." " AAing as I do (anfwered Catherine!, more for the public good than for my own advantage, 1 am not afraid to fubmit all my concerns to the judg- ment of fuch an enlightened aflembly : you have not only my permiflion to confer with freedom ; but I lay my commands upon you all to deliberate maturely on this important fubjeft, and I promife to adopt what- ever may be the refult of your decifions." At the concluilon of thefe words the aflembly retired into another apartment, and the doors were locked. It was previoully fettled by Menzikof and his party -that Catherine fhould be emprefs ; and the guards, ■who furrounded the palace with drums beating and jcoloyrs flyin^^, effeftually vanquilhed all oppofition. The only circumflance, therefore, which remained, ■was to give a jufl colour to her title, by perfuading the alfembly that Peter intended to have named her his fucceflbr. For this purpofe Menzikof* demanded of that emperor's fecretary, whether his late m_aller had left any v^'ritten declaration of his intentions? The fe- cretary replied, " That a httle before his laft journey to Mofcow he had deftroyed a will ; and that he had frequently exprelTed his defign of making another, but had always been prevented by the refledion, that if he thought his people, whom he had raifed from a ftate of barbarifm to an high degree of power and glory, could be ungrateful, he would not expofe his .final inclinations to t^aa infult of a refufal ; and that 'if they recolle£ted what they owed to his labours, they would regulate their condu£l by his intentions, which he had difclofed with more folemnity than could be manifefted by any writing." An altercation now be- gan in the aflembly; and fome of the nobles having the courage to oppofe the acceffion of Catherine, Theophanes archbifhop of Plefcof called to their re- colleftion the oath which they had all taken in 1722 to acknowledge tlie fucceflbr appointed by Peter ; and added, that the ientiments of that emperor delivered by the fecretary were in eSeSt an appointment of Ca- therine. The oppofite party, however, denied thefe fentiments to be fo clear as the fecretary chofe to in- finuate ; and inliittd, that as their late monarch had failed to nominate his heir, the eleftion of the new fovereign Ihould revert to the Hate. Upon this the archbifliop farther teftified, that the evening before the coronation of the emprefs at Mofcow, Peter had declared, in the houfe of an Englilh merchant, that • he Ihould place the crown upon her head with no other -view than to leave her miflirefs of the empire after his deceafe. This atteftation being confirmed by many perfons prefent, Menzikof cried out, " What need have we any teitament ! A refufal to conform to 1 the inclination of our great fovereign, thus authenti- cated, would be both unjuit and criminal. Long live the emprefs Catherine!" Thefe words being inft;an- taneoufly repeated by the greatell part of thofe who were prefent, Menzikof, fjiluting Catherine by the title of emprefs, paid his firil obeifarice by kifiing her hand ; and his example was followed by the whole af- fembly. She next preftnted herfelf.at the window to the guards, and to the people, who fhouted acclama- tions of " Long live Catherine !" while -Menzikof" ;4 ] C A T fcattered ampngft them handfuls of money. Thus Catherine, (fays a contemporary) the emprefs was raifed to the throne by the guards, in the fame manner as the Ro- man emperors by the praetorian cohorts, without ei- ther the appointment of the people or of the legions. The reign of Catherine' may be confidered as the reign of Menzikof, that emprefs having neither incli- nation or abihties to direft the helm of government ; and flie placed the moft; implicit confidence in a man who had been the original author of her good for- tune, and the fole inih ument of her elevation to the throne. During her fliort reign her life was very irregular ; fhe was extremely averfe to bufinefs ; would frequently^ when the weather was fine, 'pafs whole nights in the open air ; and was particularly intemperate in the ufe of tokay-wine. Thefe irregularities, joined to a cancer and a dropfy, haftened her end ; and (he expired oh the 17th of May 1727, a little more than two years after her acceflion to the throne, and in about the 40th year of her age. As the deaths of fovereigns in defpotic countries are feldom imputed to natural caufes, that of Catherine has alfo been attributed to poifon ; as if the diforders which preyed upon her frame were not fufficient to bring her to her grave. Some aflert, that {he was poifoned in a glafs of fpirituous liquor ; others, by a pear given her by general Diever. Sufpicions alfo fell upon prince Menzikof, who, a fhort time before her deceafe, had a trifling mifunderftanding with her, and who was accufed of haftening her deatli, that he might reign with fl:ill more abfolute power during the minority of Peter IL But thefe reports deferve not the lealt credit, and were merely diftated by the fpi- rit of party or by popular rumour. Catherine was in her pcrfon under the middle-fize, and in her youth dehcate and well-foi-med, but incH- ned to corpulency as flie advanced in years. She had a fair complexion, dark eyes, and light hair, which flie was always accuilomed to dye with a black coloui-. She could neither read nor write : her daughter Eli- zabeth ufually figned her name for her, and particu- larly to her Lift will and tefl:ament ; and count Oiler- man generally put her fignature to the public decrees and difpatches. Her abilities have been greatly ex- aggerated by her panegyntts. Gordon, who had fre- quently feen her, feems, of all writers, to have repre- fented her charafter with the greatell juftnefs, whea he fays, " She was a very pretty well-look'd woman, of good fenfe, but not of that fublimity of wit, or rather that quicknefs of imagination, which fome peo- ple have believed. The great reafon. why ihe czar was fo tond of her, was her exceeding good temper ; (he never was feen peevifli or out of humour ; obliging and civil to all, and never forgetful of her former con- dition ; withal, m.ighty grateful." Catherine main- tained the pomp of majeity with an air of eafe and grandeur united ; and Peter ufed frequently to exprefs his admiration at the propriety with which flie fup- ported her high ilation, without forgetting that (he was not born to that dignity. The following anecdotes will prove that flie bore her elevatiou meekly ; and, as Gordon aflerts, was never forgetful of her former condition. When Wurjub., who had been tutor to Gluck's children at the CAT [2 tht time tKat Catherine was a domeftic In that cler- gyman's family, prefented himfelf before her after her marriage with Peter had been publicly folemnized, (he recoUefted and addreffed him with great compla- cency, " What, thou good n>an, art thou Hill alive ! I will provide for thee." And fhe accordingly fettled upon him a penfion. She was no lefs attentive to the family of her benefaftor Gluck, who died a prifoner at Mofcow : fhe penfioned his widow ; made his fon a page ; portioned the two eldeit daughters ; and ad- vanced the youngeft to be one of her maids of honour. If we may believe Weber, fht frequently enquired af- ter her firft hufband ; and, when flie lived with prince Menzikof, ufed fecretly to fend him fmall fums of mo- ney, until, in i 705, he was killed in a ll, c, (fig. 15.) Now ii is remarkable in this apparent bottle, that the water, which, according to all the laws of catop- trics, and all the experiments made on other objedts, fliould appear at a appears on the contrary at h c, and confequently the part a b appears empty. If the bottle be inverted and placed before the mir- ror (as in fig. 16.), its image will appear in its natu- ral, eredt pofition ; and the water; v/hich is in reality at BC, will appear at a h. If while the bottle is inverted it be uncorked, and the water run gently out, it will appear, that while the part BC is. emptying, that oi a h'm the image is fill- ing ; and what is likewife very remarkable, as foon as the bottle is empty the illufion ceafes, the image alfo appearing entirely empty. If the bottlf likewife be quite full there is no illulion. If while the bottle is held inverted, and partly emp- ty, fome drops of water fall from the bottom A to- wards BC, it feems in the image as if there were form- ed at the bottom of the part a /», bubbles of air that rofe from a to ^ ; which is the part that feems full of water. AU thefe phenomena conltantly appear. ^ The remarkable circumftances in this experiment, are, firft, not only to fee an object where it is not, but •alfo where its image is not j and fecondly, that of two P T R I G S. objects which are really in the fame place, as the fur- face of t)ie bottle and the water it contains, the one is ieen at one place, and the other at another ; and to fee the bottle in the place of its image, and the water where neither it nor ifs image are. ^ II. Conttrudl a box AB, of about a foot long, eight n, Appear- inches wide, and fix high ; or what other dimenfion ance i f a you fliall think fit, provided it does not greatly vary ^"uudlefs from thefe proportions. On the infide of this box, and againfl; each of its oppofite ends A and B, place a mirror of the fame fize. Take'uff the quickfilver from the mirror that you place at B, for about an inch and an half, at the part C, where you are to make a hole in the box of the fime fize, by which you may eafily view its infide. Cover the top of the box with a frame, in which muft be placed a tranlparent glafs, covered with gauze, on the lide next the inner part of the box. Let there be two grooves at the parts E and F to receive the two painted fcenes hereafter mentioned. On two pieces of cut palleboard let there be fliilfully painted on both fides (fee fig. 6. and 7.) any lubjedl you think pro- per ; as woods, gardens, bowers, colonades, i^c. and on two other paitcboards, the fame fubjcdts on one fide only ; obferving that there ought to be on one of them fome objedt relative to the fubjeft placed at A, that the mirror placed at D may not refleft the hole at C on the oppofite fide. Place the two boards painted on both fides in the grooves E and F ; and thofe that are painted on one fide only, againft the oppofite mirrors C and D ; and then cover the box with its tranfparent top. This box fhould be placed in a fbong light to have a good effett. When the eye is placed at C, and views the objedls on the infide of the box, of which fome, as we have faid, are painted on both fides, they are fucceflively refledted from one mirror to the other ; and if, for example, the painting confifts of trees, they will ap- pear like a very long vifta, of which the eye cannot difcern the end : for each of the mirrors repeating the - objedls, continually more faintly, contribute greatly to augment the illufion. III. Take a fquare box ABCD, of about fix inch- Qf^ es long, and twelve high ; cover the infide of it with fortificaticni four plane mirrors, which muft be placed perpendicu- of immenfe lar to the bottom of the box CHFD. Place certain objedls in relief on the bottom of this ^' ' box ; fuppofe, for example, a piece of fortification,, (as fig. 9.) with tents, foldiers, ^c. or any other fub- jedt that you judge will produce an agreeable effedl by its difpofition when repeatedly refledied by the mir- rors. On the top of this box place a frame of glafs, in form of the bottom part of a pyramid, whofe bafe AGEB is equal to the fize of the box : its top ILN, muft form a fquare of fix inches, and fhould not be more than four or five inches higher than the box» Cover the four fides of this frame with a gauze, that the infide may not be vifible but at the top ILN, which fftould be covered with a tranfparent glafs. When you Look into this box through the glafs ILN, the mirrors that are diametrically oppofite each other, mutually refiedting the ligures inclofed, the eye beholds a boimdlefs extent, completely covered with thefe CATOPTPvICS. ^5 1 fhefe objeAs ; and if they are properly difpofed, the illufion will occafion no fraall furprize, and afford great entertaiment. Note, The nearer the opening ILN is to the top of the box, the greater will be the apparent extent of the fubjeft. The fame will happen if the four mirrors placed on the fides of the box be more elevated. The objects, by either of thefe difpofitions will appear to be repeated nine, twenty-hve, forty-nine times, ^c. by taking always the fquare of the odd numbers of the arithmetical progreffion 3, 5, 7, 9, is'c. as is very eafy to conceive, if we remember that the fubjeft enclofed in the box is always in the centre of a fquare, corapo- fed of feveral others, equal to that which forms the bottom of the box. Other pieces of the fame kind (that is viewed from above) may be contrived, in which mirrors may be placed perpendicular on a triangular, pentagon, or hexagon, (that is, a three, five, or fix-fided) plane. All thefe different difpofitions, properly direfted, as well with regard to the choice as pofition of the ob- jt£tsy will conftautly produce very remarkable and plealing illufions. If inftead of placing the mirrors perpendicular, they were to incline equally, fo as to form part of a rever- fed pyramid, the fubjeft placed in the box would then have the appearance of a very extenlive globular or many-fided figure. IV. On the hexagonal or fix-fided plane ABCDEF ring muiti- draw fix femi-diameters GA, GB, GC, GD, GE, plication of GF ; and on each of thefe place perpendicularly two |l5je6l:s, . plane mirrors, which mufl join exadtly at the centre ig 10. which placed back to back mufl be as thin as poflible. Decorate the exterior boundary of this piece (which is at the extremity of the angles of the hexa- gon) with fix columns, that at the fame time ferve to ' fupport the mirrors, by grooves formed on their inner fides. (See the profile H). Add to thefe columns their entablatures, and cover the edifice in fuch manner as you fhall think proper. In each one of thefe fix triangular fpaces, contained between two mirrors, place little figures of pafleboard, in relief, reprefenting fuch objecls as when feen in an hexagonal form will produce an agreeable effedl. To thefe add fmall figures of enamel ; and take particular care to conceal, by fome objedl that has relation to the fubjeft, the place where the mirrors join, which, ^ as we have faid before, all meet in the common centre G. When you look into any one of tlie fix openings of this palace, the obje£ls there contained being repeated fix times, will feem entirely to fill up the whole of the building. This illufion will appear very remark- able ; efpeclally if the objecls made choice of are pro- perly adapted to the effecl that is to be produced by the mirrors. Note, if you place between two of thefe mir- rors part of a fortification, as a curtain and two demi- IV. Siirp'i- baftions, you will fee an entire citadel, with its fix ba- flions. Or if you place part of a ball-room, ornament- ed with chandeliers and figures in enamel, all thofe ob- je6ls being here multiplied, will afford a very pleafing profpett. _ _ 5, V. Within the cafe ABCD, place four mirrors, V. Opaque O, P, Q, R, fo difpofed that they may each of them bodies make an angle of forty-five degrees, that is, that they may be half way inclined from the perpendicular, aS(.^-^nfpaj.ejjf^ in the figure. In each of the two extremities AB, lig.n. malce a circular overture, in one of which fix the tube GL, in the other the tube MF, and obferve that in each of thefe is to be inferted another tube, as H and 1(a). Furniih the fiifl of thefe tubes with an obje£l-gIafs at G, and a concave eye-glafs at F. You are to ob- ferve, that in regulating the focus of thefe glaffes, with, regard to the length of the tube, you are to fuppofe it equal to the line G, or vif'ual pointed ray, which entering at the overture G, is refledled by the four mirrors, and goes out at the other overture F, where the ocular glafs is placed. Put any glafs you will inta the two ends of the moveable tubes H and I ; and laflly place the macliine on a fhmd E, moveable at the point S, that it may be elevated or deprefl'cd afe plea"- fure. When the eye is placed at. F, and you look througli the tube, the r^ys of fight that proceed from the objed; T, paffing through the glafs G, are f'ucceffively refleft- ed by the mirrors, O, P, and R, to the eye at F, and there paint the objecl; T, in its proper fituation, and thefe rays appear to proceed direftly from that obje£l. The two moveable tubes H and I, at the extremi- ties of each of which a glafs is placed, ferve only the more to difguife the ilhifion, for they have no commu- nication with the interior part of tiie m:ichine. This inflrument being moveable on the flund E, may be direfted to any objedl ; and if furnifhed with proper glaffes will anfwer the purpofe of a common perfpec- tive. The two moveable tubes H and I beiiig brought together, the machine is direfled toward any objedl, and defiring a perfon to look in at the end F, you aflc him if he fee diflinflly that object. You then fepa- rate the two moveable tubes, and leaving a fpace be- tween them fufiicient to place your hand, or any other folid body, you tell him that the machine has the pow- er of making objefts vifible through the mofl opaque body ; and as a proof you defire him then to look at the fame objedl, when, to his great furprize, he will fee it as diflinft as when there was no folid body placed between the tubes. Note, This experiment is the more extraordinary,, as it is very difficult to. conceive how the effedl is pro- duced. The t\^ o, arms of the cafe appearing to be made to fupport the perfpeftive glafs ; and_ to what- ever object it is dire£led, the effedl is flill the fame. VI. (a) Thefe four tubes mufl terminate in the fubflance of the cafe, and' not enter the infide, that they may not. hinder the effe£l of the mirrors. The fourfold- refleflion of the rays of light from the mirrors, darkens in foraer xiegree the brightnefs of the objeft ; fome light is alfo loft by the magnifying power of the perfpeftive : If,, therefore, inftead of the objeft-glafs at G, and concave eye^-glafs at F, plain glaffes were fubflituted the mag- arifying power of the perfpe^tive will be taken away, and the objedl will appear brighter... lO VI.Vll T •'.-irrors, rij. 13. C A T O P 'VJ. In the partition AB, make two overtures, CD, ,'^^and EF, of a fort high, and ten inches wide, and about a foot dillant from each other. Let them be at the common height of a man's head ; and in each of them place a tranfparent glafs, furrounded with a frame, hke a common mirror. Behind this partition place two mirrors H and I, inclined to it in an angle of forty-five degrees : that is, half-way between a line drawn perpendicular to the ground and its furface : let them be both 1 8 inches fquare : let all the fpace between them be inclofed by boards or pafteboard painted black, and well clofed, that no light may enter: let there be alfo two curtains to ■cover them, which may be drawn afide at pleafure. When a perfon looks into one of thefe fuppofed mirrors, inftead of feeing his own face, he will per- ceive the objeft that is in front of the other : fo tliat if two perfons prefent themfelves at the fame time before thefe mirrors, inftead of each one feeing himfelf, they will reciprocally fee each other. Note, There fliould.be afconce with a candle placed on each fide of the two glalTes in the wainfcot, to en- lighten the faces of the perfons who look in them, otherwife this experiment wiU have no remarkable ef- feft. This experiment may be confiderably improved by placing the two glalfes in the partition in adjoining rooms, and a number of perfons being previoufly pla- ced in one room, when a ttranger enters the other, you may tell him his face is dirty; and defire him to look in the glafs, which he will naturally do ; and on feeing a ftrange face he will draw back : but return- ing to it, and feeing another, another, and another, like the phantom kings in Macbeth, what his furprize will be is more eafy to conceive than exprefs. After this, a real mirror may be privately let down on the back of the glafs ; and if he can be prevailed to look in it once more, he will then, to his further aftonifh- ment, fee his own face ; and may be told, perhaps per- fuaded, that all he thought he faw before was mere imagination. How many tricks, lefs artful than this, have paffed in former times for forcery ; and pafs at this time, in fome countries, for apparitions ? Note, When a man looks in a mirror that is pla- ced perpendicular to another, his face will appear entirely deformed. If the mirror be a little inclined, fo as to make an angle of 80 degrees (that is, one- ninth parts from the perpendicular), he will then fee all the parts of his face, except the nofe and forehead. If it be inclined to 60 degrees (that is, one-third part), he will appear with three nofes and fix eyes : in fhort, the apparent deformity will vary at each degree of in- clination ; and when the glafs comes to 45 degrees (that is, half way down), the face will vanifh. If, in- ftead of placing the two mirrors in this fituation, they are fo difpofed that their junftion may be vertical, their different inclinations will produce other effefts ; as the fituation of the object relative to thefe mirrors is quite different. The effefls of thefe mirrors, though remarkable enough, occafions but little furprife, as there is no method of conceahng the caufe by which they are produced. VII. Make a box of wood, of a cubical figure, TRIG S. fixed on the pede^ P, at the ufual height of a man'« head. In each fide of this box let there be an open- ing of an oval form, of ten inches high, and feven wide. In this box place two mirrors A, D, with their backs againil each other ; let them crois the box in a diagonal Jine, and in a vertical pofition. Decorate the openings in the fides of this box with four ovai frames and tranfparent glaffes, and cover each of tligni with a curtain, fo contrived that they may all draw up together. Place four perfons in front of the four fides, and at equal diftances from the box, and then draw up the curtains that they may fee themfelves in the mirrors ; when each of them, inftead of his own figure, will fee that of tlie perfon who is next him, and wjio, at the fame time, will feem to him to be placed on the oppofite fide. Their confufion will be the greater, as it will be very difficult for them to difcover the mirrors- concealed in the box. The reafon of this ph-jenome- non is evident ; for though the rays of light may be turned afide by a mirror, yet, as we have before faid, they always appear to proceed in right lines. VIII. Provide a box ABCD of about two feet long, V[!I. The 15 inches wide, and 12 inches high. At the end perfpedivc AC place a concave mirror, the focus of whofe paral- "'ifror, lei rays is at 18 inches from the refleding furface. At ^' ^' IL place a pafteboard blacked, in which a hole is cut fuf&ciently large to fee on the mirror H the objed placed at BEFD. Cover the top of the box, from A to I, clofe, that the mirror H may be entirely darkened. The other - part IB, muft be covered with a glafs, under which is placed a gauze. Make an aperture at G, near the top of the fide E B ; beneath which, on the infide, place, in fucceffion, paint- ings of diff'erent fubjcds, as viftas, landicapes, l^c. fo that they may be in fronc of the mirror H. Let the box be fo placed that the objed may be ftrongly illu- minated by the fun, or by wax hghts placed under the enclofed part of the box AI. By this fimple conllrudion the objeds placed at GD will be thrown into their natural perfpedlve ; and if the fubjeds be properly chofen, the appearance will be altogether as pleafing as in optical machines of a much more complicated form. Note, A glafs mirror fiiould be always here ufed, as thofe of metal do not reprefent the objeds with equal vivacity, and are befide fubjed to tarnifh. It is alfo neceflary that the box be fufficiently large, that you may not be obliged 10 ufe a mirror whole focu« is too fhort ; for in that cafe, the right lines near the border of the pidure will appear bent in the mirror, which will have a difagreeable effed, and cannot be avoided. IX. The rays of a luminous body placed in the fo- ^3 cus of a concave mirror being refleded in parallel hues, ^^^.J ^ if a fecond mirror be placed diametrically oppofite the combu;tibIe firft, it will, by coUedlng thofe rays in its focus, fetbody by the fire to a combuftible body. , ^ . u .^woctncavc Place two concave mirrors, A and n, at aoout mirrors, 12 or 15 feet diitance from each other, and letpig. 18. of each of them be in the fame line. In the axis _ the focus C of one of them, place a live coal, and ABCD, of about 1 5 inclies every way. Let it be in the focus D of the other, fome gun-powder. With ' I a C A T O P a pair of double Uellows, which make a continual blaft, keep conftantly blowing the coal, and notwithftanding tlie diftance between them, the powder will prefently take fire. It is not neceffary that thefe mirrors be of metal or brafs, thofe made of wood or paileboard, gild- ed, will produce the explofion, which has fometimes taken effeft at the diftance of 50 feet, when mirrors of 18 inches, or two feet diameter, have been ufed. This experiment fucceeds with more difficulty at great diftances ; which may proceed from the moi- fture in a large quantity of air. It would doubtlefs take effeft more readily, if a tin tube, of an equal dia- meter with the mirrors, were to be placed between them. '4 X. Behind the partition AB, place, in a pofition erealap- fomething oblique, the concave mirror EF, which muft '"9"' be at leall ten inches in diameter, and its diftance from the partition equal to thtee-fourihs of the diftance of its centre. In the partition make an opening of feven or eight Inches, either fquare or circular: it muft face the mir- ror, and be of the fame height with it. Behind this partition place a ftrong light, fo difpofed that it may not be feen at the opening, and may Illumine an ob- jedl placed at C, without throwing any light on the mirror. Beneath the aperture in the partiti? 1 place the ob- Jeft C, that you intend ftiall appear on the outfide of the partition, in an inverted pofition ; and which ^ we will fuppofe to be a flower. Before the partition, and beneath the aperture, place a little flower-pot D, the top of which fliould be even with the bottom of the aperture, that the eye, placed at G, may fee the flower in the fame pofition as if its ftalk came out of the pot. Take care to paint the fpace between the back part of the partition and the muror black, to prevent any refleftions of light from being thown on the mirror ; in a word, fo difpofe the whole that it may be as little tnhghtened as poflible. When a perfon is placed at the point G, he will perceive the flower that is behind the partition, at the top of the pot at D, but on putting out his hand to pluck it, he will find that he attempts to grafp a fha- dow. If in the opening of the partition a large double convex lens of a fliort focus be placed, or, which is not quite fo well, a bottle of clear water, the image of the flower refledted thereon will appear much more vivid and diftinft. 'irvaiicn. The phenomena that may be produced by means of concave mirrors are highly curious and aftonifliing. By their aid, fpeftres of various kinds may be exhi- bited, Suppofe, for example, a perfon with a drawn fword places himfelf before a large concave mirror, but farther from it than its focus ; he will then fee an in- verted image of himfelf in the air, between him and the mirror, of a lefs fize than himfelf. If he fteadily prefent the fwwd towards the centre of the mirror, an image of the fword.vvill come out therefrom towards FRIGS. the fword in his hand, point to point, as it were to fence with him ; and by his pufliing the fword nearer, the image will appear to come nearer him, and alrnoft to touch his breaft, having a fti iking effeft upon him. If the mirror be turned 45 degrees, or one eighth round, the reflefted image will go out perpendicular to the direftion of the fword prefented, and apparently come to another perfon placed in the direction of the motion of the image. If that perfon is unacquainted with the experiment, and does not fee the original fword, he will be much fuiprifed and alarmed. — This experiment may be another way diverfified, by telling any perfon, that at fuch an hour, and in fuch a place, he fliould fee the apparition of an abfent or deceafecf friend (of whofe portrait you are in poflefiion). In order to produce this phantom, inftead of the hole ia the partition AB in the laft figure, there muft be a door which opens into an apartment to which there is a confiderable defcent. Under that door you are to- place the portrait, which muft be inverted and ftrongly illuminated, that it may be lively reflefted by the mir- ror, which muft be large and well poliflied. Then ha- ving introduced the incredulous fpeftator at another door, and placed him in the proper point of vihv, you fuddenly throw open the door at AB, when, to his great aftonifhment, he will immediately fee the appa- rition of his friend. It will be objefted, perhaps, that this is not a per- fcft apparition, becaufe it is only vifible at one point of view, and by one perfon. But it fliould be remem- bered, that it was an eftabliflied maxim in the laft cen- turies, that a fpeftre might be vifible to one perfon and not to others. So Shakefpeare makes both Hamlet and Macbeth fee apparitions that were not vifible to others, prefent at the fame time. It is not unlikely, moreover, that this maxim took its rife from certain ap- paritions of this kind that were raifed by the monks>- to ferve fome purpofes they called i-eligious ; as thty^ alone were in poflefiion of what little learning there then was in the world. Opticians fometimes grind a glafs mirror concave in one direftion only, as it is faid longitudinally ; it is in faft a concave portion of a cylinder, the breadth of which may be confidered tliat of the mirror. A per- fon looking at his face in this mirror, in the dire&ion of its concavity, will fee it curioufly diftorted in a very lengthened appearance ; and by turning the cylin- drical mirror a quarter round, his vifage will appear di- ftorted another way, by an apparent increafe in width only. Another curious and Angular property attends this fort of mirrors : If in a very near fitnation before it, you put your finger on the right-hand fide of your nofe, it will appear the fame in the mirror ; but if in a diftant fituation, fomewhat beyond the centre of concavity, you again look at your face in the mirror, your finger will appear to be removed to the other cr left-hand fide of your nofe. This, though foracthing extraordinary, will in its caufe appear very evident from a fmall confideration of the properties of fpherical con- cave mirrors. CATOPTROMANCY^ Cato; tro- mancy II Cattivel- launi CAT I 2 CATOPTROMANCY, K..ro^Tf.^«vr««, a kind of divination among the ancients ; fo called, becaufe con- fiding in the application of a mirror. The word is formed from y-ccTo^rlpov, Jpgculum, " mirror," and TfRonille, who died in 1740, CATTERTHUN, a remarkable Caledonian poft, a few miles north of the town of Brechin in the county of Angus in Scotland. Mr Pennant defcribes it as of uncommon ftrength. *' It is (fays he) of an oval form, made of a ftupenduous dike of loofe white ftones, whofe convexity, from the bafe ..within to that with- out, is 122 feet. On the outfide a hollow, made by the difpofition of the ftones, furrounds the whole. Round the bafe is a deep ditch, and below that about •100 yards, are veftiges of another, that went round the hill. The area within the ftony mound is flat ; the axis, or length of the oval, is 436 feet, the tranf- verfe diameter 200. Near the eaft fide is the foun- dation of a redSangular building; and on mofl parts are the foundations of others fmall and circular : all which had once their fuperftruftures, the (helter of the poffefTors of the poft : there is alfo a hollow, now al- TOoft filled with ftones, the well of the place." There is another fortification, but of inferior ftrength, in the neighbourhood. It is called the Broivn Catterthun, from the colour of the ramparts which are compoled only of earth. It is of a circular form, and confifts of various concentric dike«. On one fide of this rifejj a fmall rill, which, running down the hill, has formed a deep gully. From the fide of the fortrefs is another rampart, which extends parallel to the rill, and then re- verts, forming an additional poft or retreat. The mean- ing of the word Catter-thun is Camp-toiun ; znd Mr Pennant thinks thefe might pr- bably be the pofts occu- pied by the Caledonians before their engagement at the foot of the Grampian Mountains with the celebrated Agricola. See (Hi/lory of) Scotland. CATTI, a people of Germany, very widely fpread, on the eaft reaching to the river Sala, on the north to Weftphalia ; occupying, befides Heffe, the Wetterau, and part of the traft on the Rhine, and on the banks "of the river Lohne. The Hercynian foreft began and ended in their country. CATTIVELLAUNI, anciently a people of Bri- tain, feated in the country which is now divided into ihe counties of Hertford, Bedford, and Bucks. The ^° 67. 5 64 3 CAT name of this ancient Britifli people is written in feveral different ways by Greek and Roman authors, being fonietimescalled Catti, Caflii, Catticuclani, Cattidudani, Catticliidani, iSc. That they were of Belgic origin cannot be doubted, and it is not improbable, that they derived their name of Catti from the Belgic word Katten, which fignifies illuftrious or noble, and that the addition of Vellauni, which means on the banks of rivers, might be given them after their arrival in Britain, as defcriptive of the fituation of their coun- try. However this may be, the Cattivellauni formed one of the moft brave and warlike of the ancient Bri- tifli natiorhs when Cvefar invaded Britain, and long af- ter. Caflibelanus, tlieir prince, was made commander in chief of the confederated Britons, not only on ac- count of his own perfopal qualities, but alfo becaufe he was at the head of one of their braveftand moft power- ful tribes. In the inverval between the departure of Casfar and the next invafion under Claudius, the Cat- tivellauni had reduced feveral of the neighbouring ftates under their obedience ; and they again took the lead in the oppofition to the Romans at their fecond inva- fion, under their brave but unfortunate prince Carac- tacus. The country of the Cattivellauni was much frequented and improved by the Romans, after it came undertheirobedience. Verulamium, their capital, which flood near where St Alban's now ftands, became a place of great confideration, was honoured with the name and pivileges o^ a municipium or free city, and had magiftrates after the model of the city of Rome." This place was taken and almoft deftroyed by the infurgents under Boadicia ; but it was afterwards rebuilt, reftored to its form.er fplendor, and furrounded with a ftrong wall, fome veftiges of which are ftill remaining. Du- rocobrivae and Magiavintum, in the fecond iter of An- toninus, were probably Dunftable and Fenny-Stracford, at which places there appear to have been Roman ftations. The Salense of Ptolemy, a town in the coun- try of the Cattivellauni, was perhaps fituated at Salndy, in Bedfordfliire, where feveral Roman antiquities have been found. There were, befides thefe, feveral other Roman forts, ftations, and towns in this country, which it would be tedious to enumerate. The territories of the Cattivellauni made a part of the Roman province called Britannia Prima. CATTLE, a coUeftive word, which fignifies the fourfooted animals, which ferve either for tilling the ground, or for food to men. They are diftinguiftied into large, or black cattle ; and into fmall cattle : of the former are horfes, bulls, oxen, cows, and even calves and heifers ; amongfl the latter are rams, ewes, flieep, lambs, goats, kids, ^c. Cattle are the chief ftock of a farm : they who deal in cattle are ftyled graziers. CATULLUS (Cains Valerius), a Latin poet, born at Vorona, in the year of Rome 666. The harmony of his numbers acquired him the efteem and friend- ^ fliip of Cicero, and other great men of his time. Ma- ny of his poems, however, abound with grofs obfceni- ties. He wrote fatlrical verfes againft Cajfar, under the name of Marmoro. He fpent his whole life in a* ftate of poverty ; and died in the flower of his age, and the height of his reputation. Jofeph Scaliger, Paf- ferat, Muret, and Ifaac Vofiius, have written learned notes on this poet. CATZ Cattle Catullus, Catz tl avalcaiite • CAT [ 26:5 ] C A CATZ (James), a great civilian, politician, and fome verfes \vhich are efleemed. Dutch poet, was born at Browerflaaven, in Zealand, V poet , in the year 1577. After having made feveral voy- ages, he fixed at Middleburg ; and acquired by his pleadings fuch reputation, th:it the city of Dort chofe him for its penfionary ; as did alfo, fome time after, that of Middleburg. In 1634, ^^'^ ^"'^^ nominated pen- fionary of Holland and Weil Frielland ; and in 1648, he was eledied keeper of the feal of the fame Hate, and lladtholder of the fiefs : but fome time after, he re- figned thefe employments, to enjoy the repofe which his advanced age demanded. As the poft of grand penfionary had been fatal to almoH all thofe who had enjoyed it, from the beginning of the republic till that time, Catz delivered up his charge on his knees, be- fore the whole alferably of the ftates, weeping for joy, and thanking God for having prefervad him from the inconveniences that feerned attached to the duties of that office. But though he was refolved to fpend the reft of his days in repofe, the love of his country engaged him to comply with the defires of the itate, •who importuned him to go on an embaffy to England, in the delicate conjunfture in which the republic found itfelf during the proteftorate of Cromwell. At his return, he retired to his fine country feat at Sorgvliet, where he lived in tranquillity till the year 1 660, in which he died. He wrote a great nimiber of poems in Dutch ; mofh of which are on moral fubjefts, and fo efteemed, that they have been often printed in all the different fizes ; and next to the Bible, there is no work fo highly valued by the Dutch. CATZENELLIBOGEN, a town of Germany, in the lower part of the upper circle of the Rhine, with a ftrong caftle. It is capital of a county of the fame name. E. Long. 7.38. N. Lat. 50. 20. CAVA, in anatomy, the name of a vein, the lar- geft in the body, terminating in the right ventricle of the heart. See Anatomy, p. 751. col. 2. Cava, a confiderable and populous town of Italy, in the kingdom of Naples, and in the Hither Princi- pato, with a bifliop's fee. It is fituated at the foot of Mount Metclian, in E. Long. 15. 5. N. Lat. 40. 40. CAVAILLAN, a town of France In Contal Ve- naiffin, with a bifliop's fee. It is fituated on the river Durance, in a fertile and pleafant country. E. Long. 4. 17. N. Lat. 43. 52. CAVALCADE, a formal pompous march or pro- celllon of horfemen, equipages, &c. by way of parade, or ceremony, €fs>; wherefore the Italians fettled at Mofcow drive a very great trade "in this coramodity throughout that empire, tbtrc being CaurfineSA MATRIMONII FR^LOCUTi, In common no impulfe. He pities the ignorance of the failor. The law, a writ that lies where a woman gives land to a man effect is produced, fays he, by magnetic effluvia, or in fee to the intent he fliall marry her, and he refufes fubtile matter, which paffes from the magnet to the to do it in a reafonable time, being thereunto required needle, and forces it from its place. He can even by the woman ; and in fuch cafe, for not performing fliow you, in a figure, where thefe magnetic effluvia the condition, the entry of the woman into the lauds iffue from the magnet, what round they take, and again has been adjudged lawful. what way they return home again. And thus he tlilnks The hufband and wife may fue tlils writ againft a- he comprehends perfeftly how, and by what caufe, nether who ought to have married her. the motion of the needle is produced. CAUSALITY, among metaphyficians, the aftlqn A Newtonian philofopher inquires what proof can or power of a caufe in producing its effeft. be offered for the exiftence of magnetic effluvia, and CAUSALTY, among miners, denotes the lighter, can find none. He therefore holds it as a fittion, a fiilphurcous, earthy parts of ores, carried off in the o- hypothefis ; and he has learned that hypothefes ought peration of waflilng. This, in the mines, they throw to have no place in the philofophy of nature. He in heaps upon banks, which 'n fix or feven years they confeffes his ignorance of the real caufe of this motion, find it worth their while to work over again. and thinks that his bufinefs as a philofopher is only CAUSE, that from whence any thing proceeds, or to find from experiment the laws by which it is regu- by virtue of which any thing is done : it Hands oppo- lated in all cafes. fed to effedl. We get the ideas of caufe and effect Thefe three perfons differ much in their fentiments from our obfervatlon of the vicHfitude of things, while with regard to the real caufe of this phenomenon ; and we perceive fome qualities or fubftances begin to exift, the man who knows moil is he who is fenfible that he and that they receive their exiftence from the due ap- knows nothing of the matter. Yet all the three fpeak plication and operation of other beings. That which the fame language, and acknowledge that the caufe produces, is the caufe ; and that which is produced, of this motion is the attrattive or repulfive power of the effeft : thus, fluidity in wax is the effedt of a cer- the magnet. tain degree of heat, which we obferve to be couftantly What has been faid of this, may be applied to every produced by the application of fuch heat. phenomenon that falls within the compafs of natural Jteidonthe Ariftotle, and the fchoolmen after him, diftinguiOi- philofophy. We deceive ourfelves, if we conceive AaivePorc- four kinds of caufes ; the efficient, the material, the that we can point out the real efficient caufe of any trs of Man. f^jrmal, and the final. This, like many of Ariftotle's one of them. diftinitions, is only a diftinftion of the various mean- The grandeft difcoveiy ever made in natural philo- ings of an ambiguous word ; for the efficient, the mat- fophy, was that of the law of gravitation, which opens ter, the form and the end, have nothing common in fuch a view of our planetary fyftem, that it looks like their nature, by which they may be accounted fpecies fomething divine. But the author of this dlfcovery of the fame genus; but the Greek word, which we was perfeftly aware that he difcovered no real caufe, tranflate caufe, had thefe four different meanings in but only the law or rule according to which the un- Ariftotle's days, and we have added other meanings, known caufe operates. We do not indeed call the matter or the form of a Natural philofophers, who think accurately, have a ^ing its caufe ; but we have final caufes, inftruraental precife meaning to the terms they ufe in the fcience ; caufes, occafional caufes, and many others. Thus the and when they pretend to fiiow the caufe of any phe- word caufe \\?L^ been fo hackneyed, and made to have nomenon of nature, they mean by the caufe, a law of fo many different meanings in the writings of phllo- nature of which that phenomenon is a neceffary conr fophcrs, and in the difcourfe of the vulgar, that its fequence. original and proper meaning is loft in the crowd. The whole objeft of natural philofophy, as Newton With regard to the phenomena of nature, the im- exprefsly teaches, is reducible to thefe two heads: firft, yortant end of knowing their caufes, befidea gratifying by juft indudioiv from experiment and obfervation, to 2 difcove* C A Caufe, difcover the laws of nature U [ 271 and then to apply thofe the Caufeway. }aws to the folution of the phenomena of nature. This was all that this great philofopher attempted, and all that he thought attainable. And this indeed he at- tained in a great meafure, with regard to the motions of our planetary fyftem, and with regard to the rays of light. But fuppofing that all the phenomenawhich fall with- in the reach of our fenfes were accounted for from ge- neral laws of nature jultly deduced from experience ; that is, fuppofmg natural philofophy brought to its utmoft perfection ; it does not difcover the efficient caufe of any one phenomenon in nature. The laws of nature are the rules according to which the effedls are produced; but there mull be a caufe which operates according to thefe rules. The rules of navigation never navigated a fliip. The rules of architefture never built a houfe. Natural philofophers, by great attention to the courfe of nature, have difcovered many of her laws, and have very happily applied them to account for many pheno- mena : but they have never difcovered the efficient caufe of any one phenomenon ; nor do thofe who have diftindl notions of the principles of the fcience make any fuch pretence. Upon the theatre of nature we fee innumerable ef- fe61;s, which require an agent endowed with adtive power ; but the agent is behind the fcene. Whether it be the Supreme Caufe alone, or a fubordinate caufe or caufes ; and if fubordinate caufes be employed by the Almighty, what their nature, their number, and their different offices may be ; are things hid, for wife , reafons, without doubt, from the human eye. Cause, among civilians, the fame with a£lion. See Action. Cause, among phyficians. The caufe of a difeafe is defined by Galen to be that during the prefence of which we are ill, and which being removed the difor- der immediately ceafes. The doftrine of the caufes of difeafes is called Etiology. Phyficians divide caufes into procatarftic, antece- dent, and continent. Procatarclk Cause, Tr?oy.xTupy.rtx-,i, called alfo primitive and incipient caufe, is either an occafion which of its own nature does not beget a difeafe, but, hap- pening on a body inclined to difeafes, breeds a fever, gout, IIjc. (fuch as are watching, failing, and the like) ; or an evident and manifeft caufe, which immediately produces the difeafe, as being fufficient thereto, fuch a« is a fword, in refpedl of a wound. Antecedent Causr, -ponyvf/^ivn, a latent difpofition of the body, from whence fome difeafe may arlfe ; fuch as a plethoi-a in refpeft of a fever, a cacochymia in re- fpedt of a fcurvy. Continent, ConjunS, or Proximate Cavsf, that princi- ple in the body, which immediately adheres to the difeafe, and which being prefent, the difeafe is alfo prefent ; or, which being i-emoved, the difeafe is taken away : fuch is the ftone in a nephritic patient. CAUSEWAY, or Causey, a maffive coriftruAion ®f ftone, ftakes, and fafcines ; or an elevation of fat, vifcous earth, well beaten ; ferving either as a road in wet marfliy places, or as a mole to retain the vpaters of a pond, or prevent a river from overflowing the Igwer grounds. See R,OAr>.— The word comes from 1 C A IT French Chaufee, anciently wrote Chavlfce ; and Caufevsraf, that from the Latin Calceata, or Calcata ; according Caufticity, to Somner and Spelman, a calcando. Bergier rather ''"""v—-' takes the word to have had its rife a peditum calceis^ qnihus teruntur. Some derive it from the Latin calx, or French chaux, as fuppofing it primarily to denote a way paved with chalk-ilones. Causeway, cakefum, or calcea, rhore ufually de- notes a common hard raifed way, maintained and re- paired with ftones and rubbifh. Devil's Cavsejvay, a famous work of this kindj which ranges through the county of Northumberland, commonly fuppofed to be Roman, though Mr Horfley fufpefts it to be of later tinfies. Giant^s CAusEfVAT, is a denomination given to a huge pile of llony columns in the diftrift of Colerainc in Ireland. See Giant's Caufeway. CAUSSIN (Nicholas), lurnamed the Juft, a French Jefuit, was born at Troves in Champagne, in the year 1 580 ; and entered into the Jefuits order when he vva.'j 26 years of age. He taught rhetoiic in feveral of their colleges, and afterwards began to preach, by which he gained very great reputation. He increafed this reputation by publifhing books, and in time was preferred to be confeffor to the king. But he did not difcharge this office to the fatisfadion of Cardinal' Richeheu, though he difcharged it to the fatisfadion of-- every honefl man ; and therefore, it is not to be won- dered at that he came at length to be removed. He died in the Jefuits convent at Paris in 165 1. Noneof. his works did him more honour than that which he entitled La Cour Sainte. It has been printed a great many times ; and tianflated into Latin, Italian, Spa- nifh, Portuguefe, German, and Erghfh. He publifh- ed ieveral other books both in Latin and French. CAUSTICITY, a quality belonging to feveral fub- fiances, by the acrimony of which the parts of livings animals may be corroded and deftroyed. Bodies which have this quality, when taken internally, are true poi- fons. The cauilicity of fome of thefe, as of arfenic, is fo deadly, that even their external uCe is profcribed ^ by prudent phyficians. Several others, as nitrous acid, . lapis infernalis or lunar cauflic, common cauftic, butter of antimony, are daily and fuccefsfully ufedto con fume • fungous flefh, to open iffiies, iffc. They fucceed very well when properly employed and fl in the year 1520; and received the rudiments of his education in the grammar-fchool at Grantham. From M ni 2 thence Cecil. C E C [27 thence he was removed to Stamford ; and about the year 1535, '^'^^ entered of St John's College, Cam- bridge. Here he began his ftudies with a degree of enthufiaftic application veryuncommon in young gentle- men of family. At the age of 16 he read a fophif- try ledlure, and at 19 a voluntary Greek leAure, which was the more extraordinary as being at a time when the Greek language was by no means univer- fally underftood. In 1541 he went to London, and became a member of the fociety of Gray's-Inn, with an intention to ftudy the law ; but he had not been long in that fituation, before an accident introduced him to king Henry, and gave a new bias to his pur- fuits. O'Neil, a famous Irifh chief, coming to couil, had brought with him two Irifli chaplains, violent bi- gots to the Romifh faith ; with thefe Mr Cecil, vifit- ing his father, happened to' have a warm difpute in Latia, in which he difplayed uncommon abilities. The king, being informed of it, ordered the young man into his prefence, and was fo pleafed with his converfation, that he commanded his father to had 'a place for him. He accordingly requeiled the rever- iion of the cuf^os hrevium^ which Mr Cecil afterwards poffefled. About this time he married the hiler of Sir John Cheke, by whom he was recommended to the earl of Hertford, afterwards duke of Somerfet and proteftor. Soon after king Edward's acceflion, Mr Cecil came into the pofTeffion of his office of cttjios hre'vium, worth about L. 240 a-year. His firft lady dying in 1543, he married the daughter of Sir Anthony Cook, direc- tor of the king's ftudies. In 1547, he was appointed by the proteftor, mailer of requeits ; and foon after, attended his noble patron on his expedition againft the Scots, and was prefent at the battle of Muffel- burgh. In this battle, which was fought on the loth of September 1 547, Mr Cecil's life was miraculoufl)'- preferved by a friend, who in pufliing him out of the level 'jf a cannon, had his arm lhattered to pieces. The fight and judgment of his friend mull have been as extraordinary as his friendfhip, to perceive the pre- cife direftion of a cannon (hot ; unlefe we fuppofe, that the ball was almoll quite fpent ; , in which cafe the thing is not impoJTibk. The Itory is told in his life by a domeftic. In the year 1548, Mr Cecil was - made fecretary of ftate ; but in the following year, the duke of Northumberland's faftron prevailing, he fuffered in the difgrace of the proteftor Somerfet, and was fent prifoner to the Tower. After three months confinement he was releafed ; in 155 1 refhored to his office ; and foon after knighted, and fworn of the privy council. In 1553 he was made chancellor of the Order of the Garter, with an annual fee of 100 merks. On the death of Edward VI. Mr Cecil prudently refufed to have any concern in Northumberland's at- tempt in favour of the unfortunate Lady Jane Grey; and when queen Mary acceded to the throne, he was gracioufly received at Coirrt ; but, not choofing to change his religion, was difmilTed from his em.ploy- ments. During this reign, he was twice ekfted knight of the fhire for the county of Lincoln; and often fpoke in the houfe of commons, with great freedom and firmnefs, in oppofition tx> the miniftiy. Neverthelefs, though a proteiUiit and a pairht (that is, a coui'tier 6 ] C E C out of place), he had the addrels to ilecr through a Cec very dangerous fea without Hiipwreck. — y- Q^ueen Elizabeth's acceffion in the year 1558 im- mediately difpelled the cloud which had obfcured-his fortunes and minifterial capacity. During the honid reign of Jier fiflier, he had- conftantly correfponded with the princefs Elizabeth. On the very day of her acceffion, he prefented her with a paper containing twelve articles neceffary for her immediate difpatcli ; . and, in a few days after, was fworn of the privy- council, and made fecretary of ftate. His firft advice to the queen was, to call a parliament ; and the firil bufinefs he propofed after it was aticmbled, was the eftablifhment of a national churclu; A plan of refor- mation was accordingly drawn up under his imme- diate infpedtion, and the legal eftablifhment of the church of England was the coufequence. Sir Wil- liam Cecil's next important concern, was to reftore the value of the coin, which had in the preceding reigns been . confiderably debafed. In 1561, he was appointed mafter of the wards; and, in 1571, created baron of Burleigh, as a reward for his fervices, par- ticularly in having lately fti fled a formidable rebellion, in the north.. The following year he was honoured with the garter, and raifed to the office of Lord High Treafurer of England.: From this period we find him the pr'imum mobile of every material traufaftion during the glorious reign of Queen Elizabeth. Notwith- ftanding the temporary influence of other favourites, Lord Burleigh was, in faft, her prime ^iinifter, and the perfon in whom Hie chiefly confided in matters of real importance. Having filled the liigheft and moft im- portant offices of the ftate for 40 years, and guided- the helm of government during the moft glorious pe- riod of Englifli hiftory, he departed this life on the 4Lh of Aiiguft 1593, in the 78th year of his age. His body was removed to Stamford, and there depo- fited in the family vault, where a magnificent tomb was erefted to his memory. — Notwithttanding his long enjoyment of fuch lucrative employments, he left only an eftate of 1^. ^000 per annum, L. 11,000 in money, and elFefts worth about L. 14,000. He lived, . indeed, in a manner fuitable to his high rank and im- portance. He had four places of refidence, viz. his lodgings at court, his houfe in the Strand, his feat at Burleigh-Park near Stamford, and his feat at. Theobalds. The laft of thefe was his favourite place of - retirement, where he frequently entertained the queen at a vail expence. Lord Burleigh was doubtlefs a man of .finguhu* abi- lities and prudence ; amiable in his private charafter, and one of the moft able, upright, and indefatigable minifters ever recorded in the annals of this king- dom. His' principal works are, I. La Complalnle de Vame pechertjfey or the Complaint of a finful Soul, in French verfe, in the king's library. 2. Materials for Patten's Dlarium exped. Scoi'iciz, London 1541, l2mo<. 3. Slanders, and lies malicioully, grofsly, and impu- dently vomited out, in certain traiterous books and pamphlets, againft two counfeUors, Sir Francis Ba-r con and Sir William Cecil. 4. A fpeech in parha- ment, 1562, Strype's Mem. vol. iv. p. 107. 5. Pre- cepts or diredlions for the well ordering of a man's hfe, 1637, HarL Cat. voL ii. p. 755. 6. Meditation* on the death of his lady, Ealltud's Mem. p. 1 84. 7. Meditatioi-s C E C [ 277 ] C E L Meditations on the ftate of England during the reign of queen Elizabeth, manufcript. 8. The execution of juftice in England for the maintenance of public and Chriftian peace, &c. Lond. i^Si, 1583, Somer's trails, 4th colle£t. vol. i. p. 5. 9. Advice to queen Elizabeth in matters of religion and ftate, ib. p. loi. 16. 10. A great number of letters. See Peck's Defiderata Curlofa, Hov^ard's colleftions, &c. li. Several pedigrees, feme of which are preferved in the archbifhop of Canterbury's libi-ary at Lambeth, n° 299, 747- CECILIA (St), the patronofs of mufic, has been honoured as a martyr ever fmce the fifth century. Her ftory as delivered by the notaries of the Roman church, and from them tranfcribed into the Golden Legend and other books of the like kind, fays, that (lie was a Roman lady born of noble parents, about the year 225. That, notwithftanding fhe had been converted to Chrittlanity, her parents married her to a young pagan ncblernan named Valerianus ; who go- ing to bed to her on the wedding night, as the aijlom is, fays the book, was given to underftand by his fpoufe, that fhe was nightly vifited by an angel, and that he mu.ft forbear to approach her, otherwife the angel would deftroy him. Valerianus, fomewhat trou- bled at thefe words, defired that he might fee his ri- val the angel ; but his fpoufe told him that was impof- fible, unlefs he would confent to be baptized and be- come a Chriftian. This he confented to ; after which,, returning to his wife, he found her in her clofet at prayer, and by her fide, in the ftiape of a beautiful young man, the angel clothed witli brightnefs. After fome converfation with the angel, Valerianus told him that he had a brother named Tiburtius, whom he greatly wiftied to fee a partaker of the grace which he himfelf had received. The angel told him that his defire was granted, and that they Oiouldbe both crown- ed with martyrdom ;in a fhort time. Upon this the angel vauiflied, and was not long in ftiowing himfelf as good as his word ; Tiburtius was converted, and both he and his brother Valerianus were beheaded. Cecilia was offered her life upon condition that fhe would facrifice to the deities of the Romans ; but fhe refufed : upon which flie was thrown into a caldron of boIHng water,- and fcalded to death: others fay that fhe was ftifled in a dry bath, i. e. an inclofure, from whence the air was excluded, having a flow fire un- derneath it ; which kind of death was fometimes in- flicted by the Romans upon women of quality whe were criminals. Upon the fpot where her houfe ftood, is a church faid to have been built by pope Urban I. who adminlftered baptifm to her hufband and his bro- ther : it is the church of St Cecilia at Trailevere; within is a moft curious painting of the faint, as alfo a ftately monument with a cumbent ftatue of her with her face downwards. There is a tradition of St Ce- cilia, that fhe excelled in mulic- ; and that the angel vAio was thus enamoured of her, was drawn from the celeftialregions by the charms of her melody : this has been deemed authority fufficient for making her the patronefs of mufic and muficians. The legend of St Cecilia has given frequent occafion to painters and fculptors to exercife their genius in reprefentations of her, playing on the organ, and fometimes on the harp. Raphael has paiated her finging v/ith a re- gal in her hands ; and Domenichino and Mignard, Cecrops linginff and playing on the harp. II CSCROPS, the founder and firft king of Athens, ^f ^"^' about the time of Mofes the lawgiver of the He- brews. He was the firft who eftablillied civil govern- ment, religious rites, and marriage among the Greeks; and died after a reign of 50 years. See Attica, no 4. CEDAR, in botany. See Juniperus andPiNUs. The fpecles of cedar famous for its duration, is that popularly called by us the cedar of Lebanon (Pinuscedrus),by the ancientstWrzw magna, orthe great cedar ; aUb cedrelute, ^i^f-'f^ccrr.. See the article Pin us. CEDRENUS (George), a Gre.:ian monk, lived in the iith age, and wrote " Annals, or an abridged Hiftory, from the Beginning of the A\^orld to the P..eign of Ifaac Comnenus emperor of Conftantinople, who fucceeded Michael IV. in 1057. This work is no - more than an extradl fi-om fcveral hiftorians. There is an edition of it, printed at Paris in 1647, with the Latin verfion of Xylander, and the notes of father Goar a Dominican. CEDRUS, the cedar-tree, mahogany, &c. See Juniperus, Pinus, and Swietenia. CEILING, in archlteclure, the top or roof of a lower room ; or a covering of plafter, over laths nail- ed on the bottom of the joifts that bear the floor of the upper room ; cvr Avhere there is no upper room, on joifts for the purpofe ; hence called ce'ilhig jo'tjis. The word ceiling anfwers pretty accurately to the Latin lacu- nar, " every thing over head." Plaftered ceiling, are much ufed in Britain, more • than in any other country : nor are they without their advantages, as they- make the room lightfome ; are good in cafe of fire ; ftop the pafTage of the duft ; lef- len the noife over head; and, in fummer, make the air cooler. Ceiling, in fea-language, denotes the infide planks of a fhip. CEIMELIA, from iJ'A^a', "to be laid up," In anti- - quity, denotes chuice or precious pieces of furni- ture or ornaments, referred or laid up for extraordi- nary occafions and ufes ; in which fenfe, facred gar- ments, veffels, and the like, are reputed of the cei- melia of a church. Medals, antique ftones, figures, manufcripts, records, &c. . are the ccimelia of men of letters. CEIMELIARCHIUM, the repofitory or place where ceimelia are preferved ^ CEIMELIOPHYLAX, (from ".n/^.-x-.v and ?v^ar7«, . / keep^, the keeper or curator of a eolleftion of ceL- melia ; fometimes alfo denominated ceimetiarcha. The ceimeliarcha, 01 ceimeliophylax, was an officer in the ancient churches or monaftcries, anfwering to what was otherwife denominated chartophylax, and cu/los ar- c.hivorum. CEL^NjE (anc. gcog.), the capital of Phrygia- Magna, fituated on a cognominal mountain, at the common fources of the Mieander and Marfyas. The king of Perfia had a ftrong palace- beneath the citadel, by the fprings of the Marfyas, which rofe in the mar- ket-place, not lefs in fize than the Mteander, and flowed through the city. Cyrus the younger had alfo > a palace there, but by the fprings of the Mccander, , which river paffed Hkewife. tLi-ough the city. He • II Cflaftrus. C F, L [ had, moreover, an extenfivc paradife or park, full of wild beads, which he hunted on horfeback for exer- , cife or amufement ; and watered by the Maeander, which ran through the middle. Xerxes -was faid to have built tliefe palaces and tlie citadel after his return from his expedition into Greece. Antiochus Soter removed the inhabitants of Cehisnoe into a city, which he named from his mother, Apa- mea ; and v/hich became afterwards a mart inferior ©nly to Ephefus. See Apamea. CELANDINE, in botany. See Chelidonium. CELANO, a town of Italy, in the kingdom of Naples, in Farther Abru/z/o. It is feated a mile from the lake Celano, anciently called FuciNus. E. Lon. 15. 39. N. Lat. 41. 56. CEIjARENT, among logicians, a mode of fyllo- gifm, wherein-the niajor and conclufion are univerfal negative propofitions, and the minor an univerfal af- firmative. jE.gr. None whofe underftanding is limited can be omnifcient. !yl Eveiy man's underllanding is limited. rEnt Therefore no man is omnifcient. CELASTRUS, in botany : A gexuis of the mo- nogynia order, belonging to the pentandria clafs of plants ; and in the natural method ranking under the 43d order, Dunwpe. The corolla is pentapetalous and patent ; the capfule quinquangular and trilocular ; the feeds veiled. There are 1 1 fpecies ; two of which are enured to our cli;nate. « 1. The bullutus, an uncertain deciduous fhrub, is a native of Virginia. It is about four feet in growth, rifing from the ground with feveral ilalks, which di- vide into many branches, and are covered with a brownifla bark. The leaves are of a fine green colour, and grow alternately on the branches. They are of an oval figure, and have their edges undivided. The flowers are .produced in July, at the ends of the branches, in loofe fpikes. They are of a white co- lour, and in their riative countries are fuceeeded by very ornamental fcarlet fruit ; but with us this feldom happens. It is eahly propagated from feeds fown, a- bout an inch deep, in beds of good frefli mould made fine. They feldom come up until the fecond, and fometimes not before the third fpring. It is alfo pro- pagated by layers ; vi'hich work mult be performed on the young wood, in the autumn, by a flit at the joint. Thefe layers may be expelled to Itrike root by the autun^n following ; when they may be taken up and planted in the nurfery-ground. This flirub m.ull have a well-flieltered fituation, otherwife the leaves are apt to fall off at the approach of frofty weather. And Milhir fays, that, growing naturally in moiil places, it will not thrive well in a dry foil. 2. The fcandens, or baftard euonymus, with woody, twining Ilalks, rifing by the help of neighbouring trees or buihes to the height of 1 2 feet. Th--: leaves are ob- long, ferrated, of a plealant green col(nir, pale, and veined underneath, andgrow alternately on the branciies. The Howcrs are produced in fmall bunches, from the lides of the branches, near the ends. They are of a greenifh colour, appear in June ; and are fuceeeded by roundifli, red, three-cornered capfules, -containing ripe feeds, in the autumn. This fpecifs is exceeding hardy, and makes a beautiful appearance among other 78 1 C E L trees in the autumn, by their beautiful red berries, Ce!aTlru«, which much refemble thofe of the Spindle-tree, and Celebes, will be produced in vaft profufion on the tops of other '"^ trees, to the heighf of which thef« plants by their twilling property afpire. They fhould not be planted near weak or tender trees, to climb on ; for they em- brace the Ilalks fo clofely as to bring on death to any but the liardieft trees and fhrubs. It is propagated, I. By laying down the yoimg fhoots in the fpring. By the autumn they will have ilruck root, and may then be taken off and fet in the places where they are defigned to remain. • 2. By feeds ; which fliould be foon fown after they are ripe, otherwife they will be two and fometimes three years before they come up» When they make their appearance, nothing more need be done than keeping them clear from weeds all fum- mer and the winter following-; and in the fpring the ftrongeft plants may be drawn out, and fet in the nur- fery for a year, and then removed to the places where they are defigned to remain ; whilit tlie weakeil, be- ing left in tlie feed-bed one year more, may undero-o .the fajne difcipline. In Senegal the negroes life the powder of the root as a fpeclfic againll gonorrhoeas, which it is faid td cure in eight or fometimes in three days. An infu- fion of the bark of a fpecies of ftaff-tree, which grows in tlie Ifle of France, is faid to pofTefs the fame vir- tues. CELEBES, an ifland in the Indian fea, feated under the equator, and called by fome Macafar. The length and breadth has not been accurately computed; but the circumference, at a medium, is about 800 miles; It had formerly fix kingdoms, ^vhich are re- duced to one. The air is hot and moift ; and fubjed to great rains during the north-weft winds, which blow from November to March, at which time the country is overflowed, and for this reafon they build their houfes on piles of wood 10 feet high. The moft heahh- ful time is during the northern monfoons, which fel- dom fail blowing regularly in one part of the year. The chief vegetables are rice and cocoas; but they have ebony, fanders, &c. Their fruits and flowers are much the fame as in the neiglibouring parts of the Indies. They have pepper, fiigar, betel, areca, the fineft cotton, and opium. The natives have bright olive completions, and the women have fliining black hair. They are thought to be very handfome by the Dutch and Chinefe, who often purchafe them for bed- fellows. The men are indultrious, robuft, and make excellent foldiers. Their arms are fabres, and trunks, from whence they blow poifoned darts, which are pointed with the tooth of a fea-fifh. Some likewifc uie poifoned daggers. They were the lail of the In- dian nations that were enflaved by the Dutch, which could not be effefted till after a long war. They teach their children to read and wiite, and their charafters have fome refemblanee of the Arabic. Their religion being h'Lihometan, tlie men indulge themfelves in many wives and concubines. The employment of the wo- men is fpinning, cookery, and making their own and their hiilbands cloaths. The men wear jewels in their ears, and the women gold chains about their necks. The inhabitants in general go half naked, Avithout any thing oil their head, legs, or feet, and fome have no- thing but a cloth about their middle. The ftrcets of ^> the . C E L [ : G-lerps, tHe, town Macaffar are fpacious, and planted witia trees eeleri. every fide. It ftands by the fide of the only hirge ""y" river they have in the ifland. Tlie Dutch have a fort here, mounted with 40 guns, and garrifoned with 700 men. There is only one other town of note, called Jampandam, "where they alfo have a fort. The ifland is not near fo populous as when the Dutch conquered it; the men being hired, for loldiers in moll ot the neighbouring countries. The religion of thefe iflands was formerly idolatry. They worfHipped the fun and moon. They facriiictd to them in the public fqnares, having no materials which they thought valuable enough to be employed in raifing temples. About two centuries ago, fome Chriftians and Mahometans having brought their opi- nions to Celebes, the principal king of the countiy took a diflike to the national worfhip. Having con- vened a general afiembly, he afcended an eminence, when, fpreading out his hands ti^Avards heaven, he told the Deity, that he would acknowledge for truth that do6lrine whofe minillers Ihould iirtt arrive in his dominions, and, as the winds and waves were at his command, the Almighty would have himfelf to blame if he embraced a falfchood. The aifembly broke up, determined to wait the orders of heaven,, and to obey the firft miffipnaries that (liould arrive. The maho- metans were the moft a£live, and their religion ac- cordingly prevailed. CELERES, in Roman antiquity, a regiment of body-guards belonging to the Roman kings, ellablifhed by Romulus, and con;pofed of 300 young men, clio- fen out of the moft illullrious Roman families, and ap- proved by the fuffrages of the curije of the people, each of which furnlihed ten. The name comes from ce/er, " quick, ready and was given them becaufe of their promptnefs to obey the king. The celeres always attended near the king's perfon, to guard him, to be ready to carry his orders, and to execute them. In v/ar, they made the van-guard in the engagement, which they always began lirll ; in retreats, they made the rear-guard. Though the celeres were a body of horfe, yet they ufually difmounti-'d, and fought on foot; their com- mander was called tribune, or prefeft of the celeres. They were divided into three troops, of loo each, commanded by a captain called centurio : their tribune was the fecond perfon in the kingdom. Plutarch fays, Numa broke the celeres ; if this be true, they were foon re-eftabliihed ; for we find them under moft of the fucoeeding kings : witnefs the great Brutus, who expelled the Tarquins, and who was the tribune of the celeres. CELERI, in botany, the Englilli name of a va- riety ofthe Apium Graveolens. The feed of eeleri ftiould be fown at two or three different times, the better to continue it for ufe thro' the whole feafon without running up to feed. The firft fowing fhould be in the beginning of March, up- on a gentle hot-bed ; the fecond may be at the end of the fame montli, which ought to be in an open fpot of light earth, where it may enjoy the benefit of the fun ; the third time of fowing Ihould be in the latter e nd of April, or beginning of May, on a moiil foil ; and if expofed to the morning-fun only, it will be fo much the better, but it Ihould not be under the drip 79 ] GEE of trees. The middle of May, fome of the plants of the firft fowing will be fit to tranfplant for blanch- ing- The manner of tranfplanting it is as fbllows : after having cleared the ground of weeds, you muft dig a trench by a line about 10 inches wide, and 8 or 9 inches deep, loofening the earth- in the bottom, and la) ing it level ; and the earth that comes out of the trench Hiould be equally laid on each fide the trench, to be ready to draw in again to earth the eeleri as it advances in height. Thefe trenches iTiould be made at three feet diftarice from each other ; then plant your plants in tlie middle of the trench, at about four or five inches dillance, in one ftraight row, leaving before trimmed the plants, and cut off the tops of the long leaves ; and as they are planted, you muft obferve. to clofe the earth well to their roots with your feet, and to w ater them plentifully until they have taken new root. As thefe plants advance in height, you mult obferve to draw the earth on each fide clofe to them, being careful not to bury their hearts, nor ever to do it but in dry weather ; otherwife the plants will rot. When your plants have advanced a conliderable height above the tfenches, and all the earth, which was laid on the fides thereof, hath been employed in earthing, them up, you muft then make ufe of a fpade to dig up the earth between the trenches, which muft alfo be made ufe of for the fame purpofe, continuir.g from time to time to earth it up until it is fit fur ufe. Tlie laft crop fliould be planted in a drier foil, to prevent its being rotted with too much wet in the winter. You will do well to cover your ridges of celeii with fome peafe- haulm, or fome fuch light covering,, when the froft is very hard, which will admit the air to tire plants ; for if they are covered too clofe, they will be very fubjetl to rot : by this means you will preferve your eeleri till fpring ; but you nruft remember to take off the covering whenever the weather will permit, otherwife it will be apt to caufe the eeleri to pipe, and run. to feed. The eeleri, when full blanched,, will not continue good above three weeks or a month before it will rot or pipe ; therefore, in order to con- tinue it good, you fliould have, at leaft, fix or feveu different feafons of planting, proportioned to the con- fumption. The otlier fort of eeleri, which is commonly called celeriac, is to be managed in the fiune manner ; ex- cepting that this Ihould be planted on the level ground, or in very fliallow drills ; for this plant feldom grows above eight or ten inches high, fo requires but little earthing up ; the great excellency of this being in the fize of the root, which is often as large as ordinary turnips. The beft method to fave the feed of eeleri, is to make choice of fome long good roots of the upright eeleri, which have not been too much blanched, and plant them out, at about a foot afuuder, in a moifl; foil, early in the fpring ; and when they run up to feed, keep them fupported with flakes, to prevent then being broken down with, the wind : and in July, when the feed begins to be formed, if the feafon fhould. prove very dry, it will be proper to give fome water to the plant, which will greatly help its producing, good feeds. In Auguft thefe feeds will be ripe, at v/hich rime it fliould be cut up, in a dry time, anti;- fpreuil. C E L {2? Ccleri fpread Upon cloths in the fun to dry ; thca beat out Celetes feeds, and preferve it iil bags for ufe. Cf.lf.ri, iv'tid, [Apium nntartlicum), was found in confiderable quantities by Mr Banks and Dr Solander, on the coaft of Terra del Fuego. It is like the garden celeri in the colour and difpoiition of the flowers, but the leaves are of a deeper green. The tafte is between that of celeri and parfley. It is a very ufeful ingre- dient in the foup for feamen, becaui'e of its antiicor- butic quality. CELERITY, in mechanics, the fv/iftnefs of any body in motion. It is alfo defined to be an aftedlion of motion, by which any moveable body runs through a given fpace in a given time. CELESTIN8, a religious order fo called from their founder Peter de Mcuron, afterwards raifed to the pontificate under the name of Celeftin V. This Peter, who was born at Ifernia, a little town in the kingdom of Naples, in the year 12 15, of but mean parents, re- tired, while veiy young, to a folitary m.ountain, in order to dedicate himfelf wholly to prayer and morti- fication. The fame of his piety brought feveral, out of curionty,. to fee him ; fomc of whom, charmed with his virtues, renounced the world to accompany him in his folitude. With thefe he formed a kind of community in the year 1254; which was approved by Pope Ui-ban IV. in 1264, and ere£led into a dlf- tin6l order, called the her?nks of St Damien. Peter de Meuron governed this order till 1286, when his love of folitude and retirement induced him to quit the charge. In July 1 294, the great reputation of his fandlity raifed him, though much againft his will, to the pontificate. He then took the name of Celeftin V. and his order that of Cekjlins from him. By his bull he approved their conftitutlons, and confirmed all their monafteries to the aumber of 20. But he fat too jfliort time in the chair of St Peter to do many great things for his order ; for having governed the church five months and a few days, and confiderlng the great burden he had taken upon him, to which he thought himfelf unequal, he folemnly renounced the pontificate in a confiftory held at Naples. After his death, which happened in 1296, his order made great progrefs not only in Italy, but in France likewife ; whither the then general Peter of Tivoli ,fent 12 religious, at the requeit of king Philip the Fair, who gave them two monafieries ; one in the fo- reft of Orleans, and the otlier in the forell of Com- peigne at mount Chai tres. This order likewife paifed into feveral provinces of Germany. They have about 96 convents in Italy, and 21 in France, under the title of priories. The Celeftins rife two hours after midnight, to fay matins. They eat no flefh at any time, except when they are fick. They fall every Wednefday and I'riday, from Eafter to the feall of the exaltation of the holy crofs ; and, from that feaft to Eafter, every day. As to their habit, it confifts of a white gown, a capuche, and a black fcapulary. In the choir, and when they go out of the m.onaftery, they wear a black cowl with the capuche : their ftiirts are of ferge. CELETES, or Celet^, (from y.-^^s, aracc-hrfe,) in antiquity, denote fingle or faddle-horfes ; by way of contradiftlnaion from thofe yoked or harndied to- gether, caUcd ligariiy quadrigaril, &jc. The fame de- 67. o ) C E L nomination is alfo given to the cavaliers or riders on horfeback ; and hence fome deduce celercs, the name of Romulus's guard. CELEUSMA, or Ce-leuma, in antiquity, the fhout or cry of the feamen, whereby they animated each other in their work of rdw'ing. The word is formed from x;A=uiiv, to call, fo give th^Jlgnal. Celeusma was alfo a kind of fong or formula, re- hearfed or played by the mafter, or others, to direil the ftrokes and movements of the mnrinens, as well as to encourage them to labour. See Celeustes. CELEUSTES, in ancient navigation, the boat- fwain or officer appointed to gi-^ e the rowers the fig- nal, when they were to pull, and when to flop, lit was alfo denominated epopeus, and by the Romans portifcuhs ; fometunes fimply hortator. CELIBACY, the ftate of unmarried perfons. Sca- liger derives the word from the Greek y-'i"-.^ " bed,"" and ^-f'TQ, I'wquo, " I leave ;" others fay it is formed from ctell heatitudo ; q. d. the llrjjediufs of heaven. The ancient Romans ufed all means imaginable to difcourage celibacy. Nothing was m.ore ufual tb.aa for the cenfors to impofe a fine on bachelors. Diony- fius HallcarnalTenfis mentions an ancient conftitutlon whereby all perfons of full age were obliged to marry. But the firft law of that kind, of which we have a;--./ certainty, is that under Auguitus, called lex Julia marhandis ordinibtis. It was afterwards denominated Papia Poppea, and more ufually Julia Papia, in re- gard of fome new fanclion and amendments made to it under the confuls Paplus and Poppsus. By tlus law, divers prerogatives were given to perfons who had many children ; penalties impofed on thofe who lived a fingle life, as that they Ihould be incapable of re- ceiving legacies, and not exceeding a certain pro- portion. CELIBATE, the fame with celibacy ; but it Is chiefly ufed in fpeaklng of the fingle Ufe of the Popllh clergy, or the obhgation they are under to abllain from marriage. In this fenfe we fay the law of celibate. Monks and religious take a vow of ceUbate ; and what is more, of chaftity. The church of Rome impofes an univerfal celibacy on all its clergy, from the pope to the loweft deacon and fubdeacun. The advocates for this ufage pretend, that a vow of perpetual celibacy was required in the ancient church as a condition of ordination, even from the earlieft apoftolic ages. Bat the contrary is evi- dent from numerous examples of bifhops and archbi' Ihops, who lived in a ftate of matrimony, without any prejudice to their ordination or their fundion. It is generally agreed that mo ft of the apoftles were mar- ried. Some fay all of them, except St Paul and St John. Others fay St Paul himfelf was married, be- caufe be writes to hk yoLefeilctv, whom they inter- pret his wife. Be this as it will, in the next ages after the apoftles, we have accounts of divers mar* ried bldiops, prcfoyters, and deacons, without any re- proof or mark of dilhonour fet on them ; e. g. Valens, prcft)yter of Philippi, mentioned by Polycarp ; and Cnfcremon, biftiop of Nilus. Novatus was a married prcihytet of Carthage, as we learn from Cyprian ; who himfelf was alfo a married man, as Pagi confefies ; and fo was Ca;cilius the pi-eioyter who converted him ; and Numidius another prefbyter of Carthage. The 4 ^^p^y CehvSmz li Celibate. Celibate Cell. C E L [281 reply which the Romanifts give to this is, tliat all mar- ried perfons, when they came to be ordained, promi- fed to lived feparate from their wives by confent, which anfwered the vow of celibacy in other perfons. But this is not only faid^withoiit proof, butagainll it. For Novatus prefbyter of Carthage, was certainly allowed to cohabit with his wife after ordination ; as appears from the charge that Cyprian brings agalnll him, that he had ftruck and abufed his wife, and thereby caufcd her to mifcarry. There feems indeed to have been, in fome cafes, a tendency towards the introduAion of fiich a law, by one or two zealots ; but the motion was no fooner made, than it was quafhed by the au- thority of wifer men. Thus Eufebius obferves, that •Pinytus, bifhop of GnofTus in Crete, was for laying the law of celibacy upon his brethren ; but DIonyfius bifhop of Corinth wrote to him, that he fliould confi- der the weaknefs of men, and not impofe that heavy burden on them. In the council of Nice, anno 329, the motion was renewed for a law to obhge the cler- gy to abftain from all conjugal fociety with their wives, whom they had married before their ordination ; but Paphnutius, a famous Egyptian bifhop, and one who himfelf never was married, vigoroufly declaimed a- .gainfl it, upon which it was unanimoufly reje£led. So Socrates and Sodomen tell the llory ; to which all that Valefius, after Bellarmin, has to fay, is, that he fufpefts the truth of it. The council in TruUo, held in 692, made a difference in this refpeft between bi- fliops and prefbyters ; allowing prefbyters, deacons, and all ihe inferior orders, to cohabit with their wives after ordination ; and giving the Roman church a fmart re- buke for the contrary prohibition, but at the fame time laying an injunftion upon bifliops to live feparate from their wives, and appointing the wives to betake them- felves to a monaflic life, or become deaconeffes in the church. And thus was a total celibate eftablifhed in the Greek church, as to bifhops, but not any others In the Latin chuich, the like eftablifhment made, but by flow (teps in many places. For in Africa, even bifhops themfelves cohabited with their wives at the time of the council of Trullo. The celibacy of the clergy, however, appears of an ancient fland- ing, if not of command and neccffity, yet as of coun- fel and choice. But as it is clearly neither of divine nor apodolical inftitution, it is, at firft, hard to con- ceive from what motive the court of Rome perfiited fo very obftinately to impofe this inflitution on the clergy. But we are to obferve that this was a lead- ing flep to the execution of the project formed of making the clergy independent of princes, and ren- dering them a feparate body to be goverened by their own laws. In effcd, while priefls had children, it was very dilhcult to prevent their dependence on princes, whofe favours have luch an influence on private men ; but having no family, they were more at liberty to ad- here to tiie Pope. CELIDOGRAPHIA, the defcription of the fpots which appear on the furfaces of the fun and planets. See Astronomy, n° 5S, &c. CELL, CELLA, in ancient|writers, denotes a place or apartment ulually under ground, and vaulted, in which were ftored up fome fort of neceffaiies, as wine, honey, and the hke ; and according to which it was Vol. IV. Parti. ] • C E L called Cella Vinarlai, Olearla, Mellaria, Sec. The word is formed from the Latin celare, to conceal. Cella was alfo uled for the lodge or habitat on of a common proflitute, as being anciently under ground, hence alfo denominated fornix. 11 Cellar. was alio hermits, Jntravit calidum veleri centone liipanar, Et cellam vacuam. Juv. Sat. vi. ver. 121. On which place an ancient fcholiafl remarks, that the names of the whores were written on the doors ot their feveral cells ; by which we learn the meaning of in- fcripta cella in Martial, lib. xi. ep. 46. Cella was alio applied to the bed-chambers of do- meltics and fervanis ; probably as being low and nar- row. — Cicero, inveighing againfl the luxury of Antony, fays, the beds in the very cellte of his fervants were fpread witli pompous purple coverlets. Cella is alfo applied to the members or apartments of baths. Of thefe there were three principal, called fr'tgi- daria, tepidana, and caldar 'ia ; to which may be added a fourtti, called cella ci/fa, and fometimcs Judatoria. Cella likewifc fignified the adyta, or inmoft and moil retired parts of temples, wherein the irhages of the gods to whom the edifices were confecrated were preferved. In this fenfe we meet vf'ith. cella ^ovis, cella Concordia, &c. Cell is alfo ufed for a lefTer or fubordinate foit of minifler dependent on a great one, by which it was erefted, and continues ftill to be governed. The great abbeys in England had mofl of them cells in places diftant from the mother abbey, to which they were ac- countable, and from which they received their fupe- riors. The alien priories in England were cells to abbeys in Normandy, France, Italy, &c.. The mme cell was alio given to rich and confiderable monafleries not dependent on any other. Cell fignities alfo a little apartment or chamber, fuch as thole wherein the ancient monks, folitaries, and lived in retirement. Some derive the word from the Hebrew x'^a, i. e, " a prifon, or place where any thing is Ihut up." The fame name is flill retained in divers monafleries. The dormitory is frequently divided into fo many cells or lo ges. The Carthufians have each a feparate houfe, which ferves them as a cell. The hall herein the Roman conclave is held, is divided, by partitions, into divers cells, for the feveral cardinals to lodge in. Cell h alfo a name given to the little divifions in honey-combs, which are always regular hexagons. Sec BuE. Cell, in botany, is applied to the hollow places be- tween the partitions in the pods, hufl'p"v,from v^o i^-a^^to ^'Jleep a place fet apart or confecrated for the burial of tlxe dead. Anciently none were buried in churches or cliurch- yards : it was even unlawful to inter in cities, and the ceiBeteries were without the waiis. Among the pri- mitive Chriilians thefe were held in great veneration. It even appears from Eufebius and Tertuiliaii, tliat, in the early ages, they aflembied for diviue worlhip in the cemeteries. Valerian feems to have conlifcated the ce- meteries and other places of divine woilhip, but they were reftored again by GaUienus. As the martyrs were buried in thefe places, the Chriilians chofe them for building churches on, when Conilantine ellabliHied their religion ; and hence fome derive the rule which Hill obtains in the church of Rome, never to confecratc an altar without putting under it the relics of fome faint. The practice oi coniecrating cemeceries is 01 fome antiquity. The bilhop walked round it in pro- ceffion, with the crozier or palloral ftaff in his hand, the holy water-pot being carried before, out of which •• See the foregoing article. ilaiked lime with one of powdered gypfum ; but adds, that it is ufed only in a dry fituation. A mixture of tarras with flaked lime acquires in time a ftoney hard- nefs, and may be ufed for preventing water from en- tering. See Mortar and Stucco. Cement, among engravers, jewellers, iffc. is the fame with the hot cement ufed in building * ; and is ufed for keeping the metals to be engraven firm to the block, and alfo for filling up what is to be chiifeled. Cement, in chemiftry, is ufed to fignify all thofe powders and paftes with which any body is fur- rounded in pots or crucibles, and which are capable by CElSlCflRUS, in botany: A genus of the monoecia order, belonging to the polygamia clafs of plants ; and in the natural method ranking under the 4th ordec, Gramina. The involucrum is iaciniated, and echina- ted, or befet with fmall prickles, and biflorous. The calyx is a biflorous glume, with one floret-male, and the other hermaphrodite. The hermaprodite corolla is a pointlefs glume ; there are three llamina ; one feed : the male corolla a pointlefs glume; with three llamina. CENEGILD, in the Saxon Antiquities, an expia- tory muldl, paid by one who had killed a man, to the kindred of tlie deceafed. The word is compounded of the Saxon cinne, i. e. cognalio, " relation", and giidj the help of fire of producing changes upon that body. They are made of various materials ; and are ufed for J'ohtio, " paym.ent". different purpofes, as for parting gold from filver, con- CENOBITE. See Coenobite. verting iron into ileel, copper into brafs : and by ce- CENOTAPH, in antiquity, an empty tomb, ereft- n^entation more confiderable changes can be efl^efted ed by way of honour to the deceafed. It is diilinguilh- npon bodies, than by applying to them liquids of any ed from a fepulchre, in which a coffin was depolited. • kind ; becaufe the aft ive matters are then in a ilate Of thefe there were two forts; one for thole who of vapour, and aflilled by a very confiderable degree of had, and another for thofe who had not, been honour*- ed with funeral rites in another place. The fign whereby honorary fepulchres were dillin- guillied fi-om others, was commonly the wreck of a loip, to denote the deceafe of the perfon in fome fo- reign country. CENSER, in antiquity, a vafe containing incenfe to .be ufed in facrifices. Cenfer is chiefly ufed in fpeak- i ing heat. Cf.mbnt luhlch quickly hardens in Water. This is de- fcribed in the pofthumous works of Mr Hooke, and is recommended for gilding live craw-fiili, carps, iffc, without injuring the filh. The cement for this pur- poie is prepared, by putting fome Burgundy pitch in- to a new earthen pot, and warming the veflxl till it re- . Cenfor. C E N [ 2 hig of the Jewifh worHiip. Araon ^- ;.!:o Greeks and Romans it is more frequently called tpanbuhm, hti^ccta- , T/c, and acerra. The Jewifli cenfer was a fmall fort of chafing-difh, coveted with a dome, and fufpended by a chain. Jo- fephus tells usi that Solomon made twenty thoufand gold confers for tlie temple of Jerufalerxi, to offer per- fumes in, and £fty thoufand others t .■ cairy fire in. GENSIO, in antiquity, the atl or otnce of the cen- for. - See Census. " Cenfio included both the rating or vahiing a man's eftate, and the impofing multls and penalties. Crnsio ha/iaria^, a punifnment inflidled on a Roman foldier for fome offence, as la/jnefs or luxury, where- by his hqfta o\- fpear was taken from him, and confe- quently hi;-; wnges and hopes of preferment ftopped. CENoITuS, a peifon cenfed, or entered in the cenfual tables. See Census. In an ancient monument found at Ancyra, con- taining the afkions of the emperor 0£lavius, we read, ^uo liiflro civ'ntm Romanorum Cenfita funt capita quadragies Centum millia ^ fexaginta tr 'ia. Censitus is alfo ufed in the civil law for a fervile fort of tenant, who pays capitation to his lord for the land he holds of him, and is entered as fuch in the lord's rent-roll. In which fenfe, the word amounts to the fame with capite cenfus, or capite cenjitiis. See Ca- PiTE Cenft. CENSOR, (from cenfere to " fee" or "perceive"), one of the prime magiilrates in ancient Rome. — Their bufinefs was to regiller the effefts of the Roman citi- zens, to impofe taxes in proportion to what each man poffefTed, and to take cognizance or infpeftion of the manners of the citizens. In confequence of this laft part of their office, they had a power to cenfure vice or immorality by inflifting fome public mark of igno- min}'- on the offender. They had even a power to create iht princeps fenatus, and to expel from the fe- nate fuch as they deemed unworthy of that office. This power they fometimes exercifed without fuffi- cient grounds ; and therefore a law was at length paffed, that no fenator fhould be degraded or difgra- ced in any manner, until he had been formally accu- fed and found guilty by both the cenfoi'S. It was alfo a part of the cenforian jurifdi6tion, to fill up the va- cancies in the fenate, upon any remarkable deficiency in their number ; to let out to farm all the lands, re- venues, and cuftoms, of the republic ; and to contract with artificers for the charge of building and repairing all the public works and edifices both in R ome and the colonies of Italy. In all parts of their office, how- ever, they were fubjeft to the juriidiction of the peo- ple ; and an appeal always lay from the fentence of the eenfors to tlrat of an affembly of the people. The firfl two eenfors were created in the year of Rome 3 J I, upon the fenate's obferving that the con- fuls were fo much taken up with war, as not to have time to look into other matters. The office continued to the time of the emperors, who affumed the cenfo- Tial power, calling themfelves morutn prafeS'i ; though Vefpafian and his fons took the title of eenfors. De- cius, attempted to reftore the dignity to a particular 87 ] C E N raagiftratc. After this we hear no more of' it, till Conftantine's time, who made his brother cenfor, and he feems to have been the lafl that enjoyed the office. The office of cenfor was fo confiderable, that for a long time none afpired to it till they had pafftd all the reft ; fo that it was thought furpriling that Cralfus fhould be admitted cenfor, without having been either conful or praetor. At lirll the eenfors enjoyed their dignity for five years, but in 420 the diilator Mamer- tinus made a law reltraining it to a year and an ha!f> which was afterwards obferved very ftriftly. At firii one of the eenfors was elefted out of a patrician, and the other out of a plebeian family ; and upon the death of either, the other was difcharged from his of- fice, and two new ones ele£ted, but not till the next luftrum. In the year of Rome 622, both eenfors v»'ere chofen from among the plebeians ; and after that time the ofiice was fhared betv^ een the fenate and people. — After their eleiSlion in the Comitia Centurialia, the eenfors proceeded to the capitol, where they took an oatk not to manage either by favour or difafitiStion, but to aft equitably and impartially througliout the whole courfe of their adminiitration. The republic of Venice ftiil has a cenfor of tlie manners of their people, whole office lafts iix months. Censors of Books, are a body of dodtors or others eilabliihed in divers countries, to examine all books before they go to the prefs, and to fee thty contaia nothing contrary to faith and good manners. At Paris, the faculty of theology claim this privi- lege,-as granted to them by the pope ; but, in 1624, new commiflions of four doctors were created, by let- ters-patent, the fole eenfors of all books, and anfwer- able for every thing contained therein. In England, we had formerly an officer of this kind, under the title of licenfer of the prefs : but, linee the revolution, our pi-efs has been laid under no fuch re- ilraint. CENSORINUS, a celebrated writer in the third century, well known by his treatife De Die Natalu This treatife, which was written about the year 238, Gerard Voffius calls a little book of gold ; and de- clares it to be a moll learned work of the higheft ufe and importance to chronologers, fince it connedts and determines, with great exadtnefs, fome of the princi- pal asras in pagan hiftoiy. It was printed at Cam- bridge, with the notes of Lindenbrokius, in 1695. CENSURE, a judgment which condemns fome book, perfon, or a6tion, or, more particularly, a repri-- mand from a fupcrior. Ecclefiaftical cenfures are pe- nalties by which, for fome remarkable mifbehaviour,. Chriftians are deprived of the communion of the church, or prohibited to execute the facerdotal office. CENSUS, in Roman antiquity, an authentic decla- ration made before the eenfors, by the feveral fubjefts of the empire, of their refpedlive names and places of abode. This declaration was regiilered by the een- fors ; and contained an enumeration, in writing, of all the eftates, lands, and inheritances they poffeffed ; their quantity, quality, place, wives, children, domeftics, tenants. Haves. In the provinces the cenfus ferved not only to difcover the fubllance of each perfdn, but where, and in what manner and proportion, taxes - might be beil impofed. The cenfus at Rome is common- I7- C E N I 2 Cenfus, ly tliought to have been held every five years ; but Dr Middleton hath fliown, that both cenfus ahd luftrum were held irregularly and uncertainly at various inter- vals. The cenfus was an excellent expedient for dif- covering the ftrength of the ftate : for l^y it they dif- covered the number of the citizens, how many were fit for war, and how many for oflices of other kinds ; •how much each was able to pay of taxes, &c.^ It went through all ranks of people, though under differ- ent nam.es : that of the common people was called ccn/us ; that of the knights, cefifus, recenfm, rccogn 'itioj that of the fenators, leS'iOy rele&io.—Hence alfo ci-fifus came to fignify a perfon who had made fuch a declara- tion ; in which fenfe it was oppofed to wcenfiis, a per- fon who had not given in his eitate, or name, to be regiftered. The cenfus, according to Salmafms, was peculiar to the city of Rome. That in the provinces was proper- ly called profejfto and "To^pa?.'. But this diflin6tion is not every .where obfervcd by the ancients themfelves. Census was alfo ufed for the book or regifter where- in the profefTions of the people were entered: In which fenfe, the cenfus was frequently cited and appealed to, as evidence in the courts of juflice. Census is alfo ufed to denote a man's whole fub- ftance or ell ate. Census Senatcrius, the patrimony of a fenator, which was limited to a certain value ; being at lirll rated at eight hundred thoufand fefterces, but afterwards, un- der Auguftus, enlarged to twelve hundred thoufand. Census Equcjier, the eftate or patrimony of a knight, rated at four hundred thoufand feilerces, which was required to qualify a perfon for that order, and with- out which no virtue or merit was available. Census was cilfo ufed for a perfon worth an hun- dred thoufand fefterces, or who was entered as fuch in the cenfual tables, on his own declaration. In which fenfe, cenfus amounts to the fame with clajficus, or a rnan of the firft clafs ; though Gellius limits the eitate ofthofe of this clafs to an hundred and twenty-five thoufand affes. By the Voconian law, no cenfus was -allowed to give by his will above a fouith part of what he was worth to a woman. Census was alfo ufed to denote a tax or tribute im- pofed on perfons, and called alfo capitation. See Ca- FiTE Cenfi. Census Dominkattis, in writers of the lower age, denotes a rent due teethe lord. Census DupUcatm, a double rent or tax, paid by vaffals to their lord on extraordinary or urgent occa- fsons; as expeditions to the Holy Land, &c. Census Ecclefia Romano:, was an annual contribution voluntarily paid to the fee of Rome by the fcveral princes of Europe. CENT, fignifies properly an hundred, being an a- bridgement of the word centum ; but is often uled m commerce to exprefs the profit or lofs ariliug from the fale of any commodity : fo that when we fay thei-e is io per cent, profit, or per cent, lofe, upon any mer- chandize that has been fold, it is to be underftood, that the feller has either gained or loft ten pounds on every hundred pounds of the price at which he bought that merchandize ; which is ^ of profit, or tV of lofs, up- on the total of the fale. N"6& 8S 1 C E N CENTAUREA, in botany : A genus of the poly- Centnirfa garaia fruftanea order, belonging to thefyngenefia clafs of plants ; and in the natural method ranking under , . ^ j the 49th order, Compofitx. Tlie receptacle is brillly ; the pappus fimple; the corollulte of the radius funnel- fliaped, longer than thofe of the dilk, and irregular. CENTAUR, in aftronomy, a part or moiety of a fouthern conftellation, in form half-man half-horfe ; ufually joined with the wolf. The word comes from K£VTizup'/ J formed of ■<'~^t=<^ , pi^ngo ; and i-aypof, bull; q. d. buU-pricher. The ftars of this conftellation, in Ptole- my's Catalogue are 37 ; in Tycho's 4; and in the Britannic Catalogue, with Sharp's Appendix, 35. CENTAURS, m mythology, a kind of fabulous monfters, half men and half horfes.— The poets pre- tend that the centaurs were the fons of Ixion and a cloud ; the reafon of which fancy is, that they retired to a caftle called v£p;x«, which lignlfies a *' cloud." — This fable is differently interpreted : fome will have the centaurs to have been a body of ftiepherds and herdfmen, rich in cattle, who inhabited the mountains of Arcadia, and to whom is attributed the invention of bucolic poetry. PalsEphastus, in his book of Incre- dibles, relates, that under the reign of Ixion, king of ThelTaly, a herd of bulls on mount TheiTaly run uiad, and ravaged the wliole country, rendering the moun- tains Iniicceflible ; that fome young men who had found the art of taming and mounting horfes, under- took to clear the mountains of thefe anunals, which they purfued on horfeback, and thence obtained the appellation of Centaurs. This fuccefs rendering them infolent, they infulted the Lapithie, a people of Thef- faly : and becaufe when attacked they fled with great rapidity, it was fuppofed they were half horfes and half men.— The Centaurs in reality were a tribe of Lapithte, who inhabited the city Pelethronium adjoin- ing to mount Pelion, and firft invented the art of breaking horfes, as is intimated by Virgil. CENTAUREA, greater centaury: A genus of the polygamia fruftanea order, belonging to the fyn- genefia clafs of plants ; and in the natural method ranking under the 49th order, Conipcjfitx. The recep- tacle is briftiy, the. pappus fimple, the corolluls of the radius funnel-fhaped, longer than thofe of the diflc, and irregular There are 61 fpecies. The root of one of them called glajlifolia, is an article in the materia inedi- ca. It has a rough, fomewhat acrid tafte, and abounds with a red vifcid juice. Its rough tafte has gained it fome efteem as an aftringent ; its acrimony as an ape- rient ; and its glutinous quality as a vulnerary : but the prefent pradtice takes very little notice of it in any intention. Another of the fpecies is the cyanus-oi: blue bottle, which grows commonly among corn«- The expreffed juice of this flower fiains linen of a beautiful blue colour, but is not permanent. Mr Boyle fays, that the juice of the inner petals, with a little alum, makes a beautiful permanent colour, equal to ultrama- rine. Lefer CENTJURr. See Gentiana. CENTELLA, in botany* A genus of the tetran- dria order, belonging to the moncEcia clafs of plants ; and in the natural method ranking under the i ith or- der, Sarmentacea. The male involucrum is tetraphyl- lous and quinqueflorous, with four petals ; the female GEN [ 289 ] GEN II Centiloqi; um. Oentenari- -Jnvolucrum is diphyllous and uniflorous ; the petals four ; the germen inferior ; two ftyles ; and a bilocu- lar feed-cafe. CENTENARIUS, or Centenario, in the middle age, an officer who had the government or command, with the adminilh-ation of juftice, in a village. The centenarii as well as vicarii were under the jurifdic- tion and command of the court. We find them among the Franks, Germans, Lombards, Goths, &c. Centenarius was alfo ufed for an officer who had the command of 100 men ; moil frequently called a •Centurion. Centenarius, in monafteries, was an officer wht) had the command of 100 monks. CENTENINUM ovum, among naturalills, de- notes a fort of hen's egg much fmaller than ordinary, Vulgarly called a cock^s egg ; from which it has been ■fabuloudy held that the cockatrice or bafiliflc is produ- ced. The name is taken from an opinion, that thefe ■are the laft eggs which hens lay, having laid 100 be- fore ; whence centeni?iutn, q. d. the hundredth egg. — Thefe eggs have no yolks, but in other refpefts dif- fer not from common ones ; having the albumen, cha- lazes, membranes, &c. in common with others. In the place of the yolk is found a little body like a fei- pent coiled up, which doubtlefs gave rife to the fable of the bafiliflc's origin from thence. Their origin is with probability afcribed by Hervey to this, that the yolks in the vitellary of the hen are exhaufted before the albumina. CENTER, or Centre, in a general fenfe, fignifies a point equally diftant from the extremities of a line, figure, or body. The word is formed from the Greek KfvTpovj z point. Center of Gravity, in mechanics, that point about which all the parts of a body do in any fituation ex- aftly balance each other. Center of Motion, that point which remains at reft, while all the other parts of a body move about it. Center of a Sphere^ a point in the middle, from ■which all lines drawn to the furface are equal. Hermes Trifmegiftus defines God an intelleftual fphere, whofe center is every where, and circumference no where. CENTESIMA usura, that wherein the intereft in an hundred months became equal to the principal; i.e. where the money is laid out at ont per cent, per month; anfwering to what in our ftyle would be called 12 per cent, for the Romans reckoned their intereft not by the year, but by the month. CENTESIMATION, a milder kind of mihtary punifhment, in cafes of defertion, mutiny, and the like, when only every hundredth man Is executed. CENTILOQUIUM, denotes a colleaion of 100 ■fentences, opinions, or fayings. The centiloquium of Hermes, contains 1 00 apho- rifms, or aftrological fentences, fuppofed to have been written by, fome Arab, falfely fathered on Hermes Trifmegiftus. It is only extant in Latin, In which It has feveral times been printed. — The centiloquium of Ptolomy is a famous aftrological piece, frequently con- founded with tlie former, confifting likewife of 100 fentences, or doftrlnes, divided Into fhort aphorifms, ifltitkd alfo in Greek as being the fruit or re- VoL. IV. Part J. fult of the former writings of that celebrated aftrono- mer, vh. his quadripartitum and almagejlum ; or rather, by reafon that herein Is (hown the ufe of aftrological calculations. CENTIPES, In zoology. See Scolopenora. CENTIPED WORM, a term ufed for fuch worms as have a great many feet, though the number does not amount to 100, as the term feems to, import. — M. Maloet relates the hiftory of a man, who, for three years, had a violent pain in the lower part of the forehead near the root of the nofe : at length he felt an itching, and afterwards fomething moving with- in his noftril, which he brought away w ith his finger ; it was a worm of the centiped kind, an inch and an half long, which run fwlftly. It lived five or fix days among tobacco. The patient was free [of his pain e- ver after. MrjLittre mentioned a hke cafe in 1708, of a larger centiped voided at the nolfe, after it had thrown the woman, In whofe frontal finus it was, into convulfions, and had almoft deprived her of her rea'- fon. CENTLIVRE (Sufanna), a celebrated cornic wri- ter, was the daughter of Mr Freeman of Holbeach, in Lincolnftiire" ; and had fuch an early turn for poe- try, that it Is faid ftie wrote a fong before fhe was feven years old. Before ftie was twelve years of age, ftie could not only read Moliere In French, but enter Into the fpirit of all the charafters. Her father dying, left her to the care of a ftep-mother; whofe treatment not being agreeable to her, flie determined, though al- moft deilitute of money and every other neceffary, to go up to London to feek a better fortune than what ffie had hitherto experienced. As flie was proceeding on her journey on foot, (he was met by a young gen- tleman from the univerfity of Cambridge, the after- wards well-known Anthony Hammond, Efq; who was fo extremely ftruck with her youth and beauty, that he fell inftantly In love with her ; and inquiring Into the particulars of her ftory, foon prevailed upon her unexperienced innocence to feize on the proteftlon he offered her, and go with him to Cambridge. After fome months cohabitation, he perfuaded her to come to London ; where, in a ffiort time, ftie was married to a nephew of Sir Stephen Fox. But that gentleman not living with her above a twelvemonth, her wit and beauty foon procured her a fecond huftjand, whofe name was Carrol, and who was an officer in the army ; but he having the misfortune to be killed In a duel a- bout a year and an half after their marriage, ftie be- came a fecond time a widow. For the fake of fuppor £ (he now appHed to her pen, and became a votary of the mufes ; and It is under this name of Carrol that fome of her earlier pieces were publiftied. Her firil: attempt was In tragedy, In a play called the Perjured Hujhand; yet her natural vivacity leading her afterwards to comedy, we find but one more attempt In the buf- kin, among i8 dramatic pieces which fhe afterwards wrote. In 1 706, flie wounded the heart of one Mr Jofcpli Centlivre, yeoman of the mouth, or in other words principal cook to her Majefty, who married her ; and, after paffing feveral years happily together, ftie died at his houfe in Spring- Garden, Charlng-Crofs, in De- cember 172]. 0 o Tlii'5 CentTpc« I. Centlivre. Centner, C E N f 290 1 This lady for many years enjoyed the intimacy aad the fraall weights. efteem of the moil eminent wits of the times, viz. Sir Richard Steele, Mr Rowe, Biidgell, Farqnhar, Dr Sewell, &c. and very few authors received more tokens of efteem and patronage from the great. Wiih regard to her merit as a writer, it muft be allowed that her plays do not abound with wit, and that the language of them is fometimes even poor, enervate, incorreft, puerile ; but then her plots are bufy and well conduc- ted, and her charaflers in general natural and well marked. CENTNER, or Docimastic Hundred, in metal- lurgy and affaying, is a weight divilible, firft into an hundred, and thence into a greater number of other fmaller parts ; but though the word is the fame both with the afTayers and metallurgifts, yet it is to be un- derftood as exprefiing a very different quantity in their different acceptation of it. The weights of the metal- lurgifts are eaflly underftood, as being of the common proportion, but thofe of the aifayers are a thoufand times fmaller than thefe, as the portions of metals or ores examined by the affayers are ufually very fmall. The metallurgifts, who extradl metals out of their ores, life a weight divided into an hundred equal parts, each part a pound ; the whole they call a centner or hundred weight ; the pound is divided into thirty-two parts, or half ounces : and the half ounce into two quarters of ounces, and thefe each into two di*ams. Thefe divifions and denominations of the metallur- gifts are eafily underftood ; but the fame words, tho' they are equally ufed by affayers, with them exprefs very different quantities ; for as the centner of the metallurgifts contains an hundred pounds, the centner of the affayers is really no more than one dram, to which the other parts are proportioned. As the alfayers weights are divided into fuch an ex- treme degree of minutenefs, and are fo very different from all the common weights, the affayers ufually iiiake them themfelves in the following manner, out of fmall filver, or fine folder plates, of fuch a fize, that the mark of their weight, according to the divilion of the dram, which is the docimaftic or affaying centner, may be put upon them. They firft take for a bafis one weight, being about two-thirds of a common dram : this they mark (64/1^.) Then having at hand fome granulated lead, waflied clean, well dried, and fifted very fine, they put as much of it into one of the fmall difhes of a fine balance as will equipoife the (64/^.) as it is called, juft mentioned : then dividing this gra- nulated lead into very nice halves, in the two fcales, after taking out the firft filver weight, they obtain a perfe£l,equirlibrium between the two fcales ; they then, pour the granulated lead: out of one difh of the fcales, and inftead of it put in another filver weight,, which they make exaftly equiponderant with the lead in the other fcale, and mark it (32/^.) If this fecond weight,, when firft put into the fcale, exceed by much the weight of the lead, they take a little from it by a very- fine file; but, when it comes very near, they ufe only a whetftone t() wear oif an extremely fmall portion at a time. When it is brought to be perfeAly even and equal to the lead, they change the fcales to fee that no error has been committed, and then ge on in the fame manner till, they have made all the divifions, aad all C E N Then to have an entire centner or hundred weight, they add to th.z \6j\.lb.) as they call it, a 32/3. and a ^Ib. and weighing againll them one fmall weight, they make it equtil to them, and mark it ( 1 00. ) This is the docimaftical, or affaying centner, and is really one. dram. CENTO, in poetry, a work wholly compofed of verfes or palTages promlfcuoufly taken from other au- thors, only difpofed in a new form and order. — Pro- ba Falconia has written the life of Jefus Chrifl in cen- tos taken from Virgil. Alexander Rofs has done the like in his Chriilrados, and Stephen de Pleure the fame. CENTONARII, in antiquity, certain of the Ro- man army, who provided different forts of ftuff called* centones, made ufe of to quench, the fire which the enemies engines threw into the camp. Thefe centonarii kept with the carpenters and other* officers of artillery. CENTRAL FORCES, the powers which caufe a moving body to tend towards, or recede from, the center of motion. See Mechanics. Cehtral Rule, a rule difcovered by Mr Thomas Baker, whereby to find the centre of a circle defigned to cut the parabola in as many points as an equation to be conftrufted hath real roots. Its principal ufe i^ in the conftrutSlion of equations, and he hath applied it with good fuccefs as far as biquadratics. The central rule is chiefly founded on this property- of the parabola, that, if a line be infcribed in that curve perpendicular to any diameter, a redlangle formed of the ferments of the infcript is equal to the- reftangle of the mtercepted diameter and parameter of the axis. The central rule has the advantage over Cartes and De Latere's methods of conftrufting equations, in that both thefe are fubje£l to the trouble of preparing the equation by taking away the fecond term. CENTRIFUGAL force, that force by which all bodies that move round any other body in a curve en- deavour to fly off from the axis of their motion in a tangent to the periphery of the curve, and that in every part of it. See Mechanics. CENTRifUGAL-Machine, a very curious machinci in- vented by Mr Erflcine, for raifing water by means of a centrifugal force combined with the preifure of the atmofphere. It confifts of a large tube of copper, Iffc. in the form of a crofs, which is placed perpendicular in the water,, and refts at the bottom on a. pivot. At the upper part of the tube is a horizontal cog-wheel, which touches the cogs of another in a vertical pofition ; fo that by the help of a double winch, the whole ma- chine is moved round with very great velocity. , Near the bottom of the perpendicular part of the tube is a valve opening upwards ; and near the two extremities, but on the contrary fides of the arms, or. crofs part of the tube, are two other valves opening outwards. Thefe two valves are, by the afiftftance of fprings,.kept fhut till the machine is put in motion, when the centrifugal velocity of the water forces them open, and difcharges itfelf into a ciftern or refer- voir placed there for that purpofe. Oq the upper part of the arms are two holes, which are Cent© C E N [ 2( Centrifu- are clofed by pieces fcrewing into the metal of the gal. tube. Before the machine can work, thefe holes muft ""■"V""^ be opened, and water poured in through them, till the whole tube be full : by this means all the air will be forced out of the machine, and the water fupport- ed in the tube by means of the valve at the bottom. The tube being thus fiUed with water, and the holes clofed by their fcrew caps, it is turned round by means of the winch, when the water in the arms of the tube acquires a centrifugal force, opens the valves near the extremities of the arms, and flies out with a velocity nearly equal to that of the ex-treniities of the faid arms. The above defcriptlon will be very eafily underftood by the figure we have added on Plate CXXXVI. which is a perfpeftive view of the centrifugal machine, erefted on board a fliip. ABC is the copper tube. D, a horizontal cog-wheel, furniflied with twelve cogs. E, a vertical cpg- wheel, furnifhed with thirty-fix cogs. F, F, the double winch, a, the valve near the bot- tom of the tube, i, by the two pivots on which the machine turns, c, one of the valves in the crofs-piece ; the other at d, cannot be feen in this figure, being on the other fide of the tube. three, and Kjf««vov, head. CERCELE, in heraldiy: a Ci-ofs cercele is a crofs which, opening at the ends, turns round both ways like a ram's horn. See Cross. CERCIS, the Judas-tree : A genus of the mo- nogynia order, belonging to the decandria clafs of plants ; and in the natural method ranking under the 33d order, Lomentacea. The calyx is qinque-- dentated, and gibbous below; the corolla papiliona- ceous, with a fliort vexillum or flag-petal under the wings or fide-petals ; a leguminous plant. There are. only two fpecies, both deciduous. I. The filiquaftrum, common Judas-tree, or Ita- llau cercis, a native of Italy and other parts of the fouth of Europe. — Thefe differ in the height of their growth in different places : In fome they will arrive to be fine trees, of near twenty feet high ; whilfl; in others they will not rife to more than ten or twelve ftet, fending forth young branches irregularly from the vei-y bottom. The ftem of this tree is of a dark- greyifh colour, and the branches, which are few and irregular, have a purplifh caft. The leaves are fmooth, heart-fliaped, and roundifh, of a pleafant green oa their upper furfece, hoary underneath, and grow al- ternately on long footftalks. The flowers are of a fine purple : They come out early in the fpring, in dufters,. from tlie fide of the branches, growing upon fliort footftallcs ; and in fome fituations they are fuc- ch ceeded by long flat pods, containing the feeds, which, v""-^ in very favourable feafons, ri^en in England. Some people are fond of eating thefe flowers in fallads, oa which account alone in fome parts this tree is propa- gated. The varieties of this fpecies are, i. The- Flefli -coloured; 2. The White-flowered ; and, 3. The Broad-podded Judas-tree. 2. The Canadenfis, or Canadian cercis, will grow to the fize of the firft fort in fome places. The branch- es are alfo irregular. The leaves are cordated, downy, , and placed alternately. The flowers ufually are of a palilli red colour, and fliow themfelves likewife in the fpring, before the leaves are grown to their fize. Thtfe too are often eaten in fallads, and afford an ex- cellent pickle. There is a variety of this with deep red, and another with purple flowers. The pleafure which thefe trees will afford in a plantation may be eafily conceived, not only as they exhibit their flowers in cinders, in different colours, eaily in the fpring,, before the leaves are grown to fuch a fize as to hide them; bat from the difference of the upper and lower furface of the leaves ; the one being of a fine green, the other of a hoary caft ; fo that on the fame tree, even in this refpeil, is fhown variety ; an improve- ment whereof is made by the waving winds, which will prefent them alternately to view. Propagation. As thefe fpecies will not take root by layers, they muft be propagated by feeds, which may be had from abroad. They are generally brought us found and good, and may be fown in the months of February or March. Making any particular compoft for their reception is unnecefTary ; common garden mould, of almoft every fort, will do very well: And this being well dug, and cleared of all roots, weeds, &c. lines may be drawn for the beds. The mould be- ing fine, part of it fliould be taken out, and fifted over the feeds, after they are fown, about half an inch thick. Part of the feeds will come up in the fpring, and the others will reuiain until the fpring following ; fo that whoever is deiirous of drawing the feedhngs of a year old to plant out, muft not deftroy the bed, but draw them carefully out, and after that there will be a fucceeding crop. However, be this as it will,., the feeds being come up, they muft be weeded, and encouraged by watering in the dry feafon ; and they will require no farther care during the firft fummer.. In the winter alfo they may be left to themfelves, for they are very hardy ; though not fo much but that the ends of the branches will be killed by the froft, nay, fometimes to the very bottom of the young plant, where it will fhoot out again afrefh in the fpring. Whoever, therefore, is defirous of fecuring his feedling- plants from this evil, fliould have his beds hooped, in: order to throw mats over them during the hard frofts. Toward the latter end of March, or beginning of A- pril, the plants having been in the feed-bed one or • two years, they fliould be taken out, and planted in the nurfery : The diftance of one foot afunder, and tv7o feet in the rows, fhould be given them. Hoeing the weeds down in the fummer muft alfo be allowed, as well as digging between the rows in the winter. Here they m.ay iland until they are to be removed finally ; but they muft be gone over in the winter with the knife, and fuch irregular branches taken oflt" as- C E R t CiTC'ipI- a-s are produced near the root ; by \\-h\ch management ■theci ^j^g j^^j trained up to a reglilar ftem. Such, Cerealia. continues Hanburry, is the culture of the fpecies of y-— cercis ; forts that are not to be omitted where there are any pretenfions to a collection. Beiides, the wood itfelf is of great value ; for it polifhes exceedingly well, and is admirably veined with black and green. CERCOPITHECI, in natural hiilory, the name gi- ven by Mr Ray to monkeys, or the clafs of apes with long tails. See Apk and Simia. CEJUDA (John Lewis de la), a learned jefuit of Toledo, wrote large commentaries on Virgil, which have been much eiteemed ; alfo feveral other works. He died in 1643, aged 80. CERDONIANS, ancient heretics, who maintained moft of the errors of Simon Magus, Saturninus, and the Manichees. They took their name from their leader Cerdon, a Syrian, who came to Rome in the time of pope Hyginus, and there abjured his errors : but in appearance only ; for he was afterwards con- vifted of perfifting in them, and accordingly caft out of the church again. Cerdon aflerted two principles, the one good and the other evil : this laft, according to him, was the creator of the world, and the god that appeared under the old law. The lirft, whom he call- ed unkmivn, was the father of Jefus Chrift ; who, he taught, was incarnate only in appearance, and was not born of a virgin ; nor did he fuffer death but in ap- |)earance. He denied the refurreclion ; and rejefted all the books of the Old Teftament, as coming from an evil principle. Marcion, his difciple, fucceeded him in his errors. CEREALIA, in antiquity, feaftsofCeres, inftituted by Triptolemus, fon of Celeus king of Eleufine in At- tica, in gratitude for his having been inihuAed by Ceres, who was fuppofed to have been his nurfe, in the art of cultivating corn and making bread. There were two fcafts of this kind at Athens; the one called Eleufwia, the other Thefmophoria. See the •article Eleusinia. What both agreed in, and was common to all the cerealia, was, that they were cele- brated with a world of religion and purity ; fo that it was efteemed a great pollution to meddle, on thofe days, in conjugal matters. It was not Ceres alone that was honoured here, but alfo Bacchus. The vic- tims offered were hogs, by reafon of the wafte they make in the produ6l:s of the earth ; whether there was any wine offered or Jiot, is matter of much de- bate among the critics. Plautus and Macrobius feem to countenance the negative fide ; Cato and Virgil the pofitive. Macrobius fays, indeed, they did not offer wine to Ceres, but niulfwn, which was a compofition of wine and honey boiled up together : that the fa- crifice made on the 21 ft of December to that goddefs and Hercules, was a pregnant fow, together with cakes and mulfura ; and that this is what Virgil means by Mill Baccho. The cerealia pafTed from the Greeks to the Romans, who held them for eight days fuccef- fively ; commencing, as generally held, on the fifth of the ides of ApriL It was the women alone who were concerned in the celebration, all dreffed in white; the men, likewife in white, were only fpeftators. They eat nothing till after fun-fet ; in memory of Ceres, who in her fearch after her daughter took no . repaft but in the evening. 68. 96 ] C E R After the battle of Cannae, the defolatlon was fo Cerealia great at Rome, that there were no women to cele- II brate the feaft, by reafon they were all in mourning j ^^'"^"^^^7' fo that it was omitted that year. Cerealia, in botany, filam Ceres the goddefs of corn ; Linnasus's name for the larger efculent feeds of the graffes : thefe are rice, wheat, rye, barley, oats, millet, panic grafs, Indian millet, holcus, zizania, and maize. To this head may be likewife referred darnel, (lolium) 1 which, by preparation, is rendered efculent. CEREBELLUM, the hinder part of the head. See Anatomy, n° 133. CEREBRUM, the brain. Its ftru<5lure and ufc are not fo fully known as fome other parts of the body, and different authors confider it in various man- ners. However, according to the obfervations of thofc moft famed for their accuracy and dexterity in anato- mical inquiries, its general ftrufture is as given in Anatomy, n'' 1 32. Dr Hunter obferves, that the principal parts of the medullary fubftance of the brain in ideots and mad- men, fuch as the thalami nervorum opticorum^ and mc' ditlla oblongata, are found entirely changed from a me- dullary to a hard, tough, dark-coloured fubftance, fometimes refembling white leather. CEREMONIAL ( ceremoniale ) , a book in which is prefcribed the order of the ceremonies to be obferved in certain adlions and occafions of folemnity and pomp. The ceremonial of the Roman church is called ord» Romanus. It was publiflied in 15 16 by the biftiop of Corcyra ; at which the college of cardinals were fo fcandalized, that fome of them voted to have the au- thor as well as book burnt, for his temerity in expofing the facred ceremonies to the eyes of profane people. Ceremonial is alfo ufed for the fet or fyftem of rules and ceremonies which cuftom has introduced for regulating our behaviour, and which perfons praftife towards each other, either out of duty, decency, or ci- vility. Ceremonial, in a more particular fenfe, denotes the manner in which princes and ambaffadors ufe to receive and to treat one another. There are endlefs difputes among fovereigns about the ceremonial: fome endeavouring to be on a level, and others to be fupe- rior ; infomuch that numerous fchemes have been pro- pofed for fettling them. The chief are, i. to accom- modate the difference by ^compromife or alternation, fo that one (hall precede now, the other the next time J or one in one place, and the other in another : 2. By feniority'; fo that an elder prince in years fhall precede a younger, without any other diflinftion. Thefe expedients, however, have not yet been ac- cepted of by any, except fome alternate princes, as they are called, in Germany. Caremonial is more particularly ufed in fpeaking of the laws and regulations given by Mofes relating to the worfhip of God among the ancient Jews. In this fenfe it amounts to much the fame with what is called the Levitical law, and ftands contradiftinguhhed from the moral as well as judicial law. CEREMONY, an afiemblage of feveral aftions, forms, and circumftanccs, ferving to render a thing more magnificent and folemn. In 1646, M. Ponce publifhed a hiftory of ancient ceremonies, tracing the rife, growth, and introduAion 2 of G E R of eacli rite into the church, and its gradual advance- ment to fuperftition therein. Many of them were borrowed from Judaifm; but more feemingly from Pa- ganifm. Dr Middleton has given a line difcourfe on the conformity between the pagan and popifh cere- monies, which he exemplifies in the ufe of incenfe, holy water, lamps, and candles, before the flirines of faints, votive gifts or offerings round the fhrines of the deceafed, &c. In efFeft, the altars, images, croffes, proceffions, miracles, and legends ; nay, even the very hierarchy, pontificate, religious orders, &c. of the pre- fent Romans, he fliows, are all copied from their hea- then anceftors. — e have an ample and magnificent account of the religious ceremonies and cuftoms of all nations in the world, reprefented in figures defigned by Picart, with hiftoricai explanations, and many curious differtations. Maficr of the Cerf.monifs, an officer inttituted by king James I. for the more honourable reception of ambafiadors and ftrangers of quality. He wears about his neck a chain of gold, with a medal under the crown of Great Britain, having on one fide an em- blem of peace, with this motto, Beat'i pac'ific'i ; and on the other, an emblem of war, vvith D'leu et man droit : his falary is 'i^ool, per annum. Ajjijlant Majier of the CEREMONiE.-i, is to execute the employment in all points, whenfoever the matter of the ceremonies is abfent. His falary is 141 A 13J. and j^d. per annum, Marjljall of the Ceremonies is their officer, being [ ] C E R His falary is 100 1, per fub ordinate to them both. annum. CERENZA, a town of Italy In the kingdom of Naples, and in the Hither Calabria, with a bifhop's fee. It is feated on a rock, in E. Long. 1 7. 5. N. Lat. CERES, a Pagan deity, the inventor or goddefs of corn ; in like manner as Bacchus was of wine. According to the poets, fhe was the daughter of Sa- turn and Ops, and the mother of Proferpine, whom file had by Jupiter. Pluto having ftolen away Pro- ferpine, Ceres travelled all over the world in queft of her daughter, by the help of a tor^h, wliich (he had lighted in Mount ^tna. As Ceres was thus travelling In fearch of her daugh- ter, file came to Celeus king of Eleufis, and under- took to bring up his infant fon Triptolemus. Being defirous to render her charge im.mortal, fhe fed him In the day-time with divine milk, and in the night co- vered him with fire. Celeus obferving an unufual Improvement in his fon, refolved to watch his nurfc, to which end he hid himfelf In that part of the houfe where fhe, ufed to cover the child with fire ; but when he faw her put the Infant under the embers, he cried out and difcovered .himfelf. Ceres puniflied the cu- riofity and Indifcretion of the father with death. Af- terwards, fi^e taught the youth the art of fowing corn and other fruits, and mounted him in a chariot drawn by winged dragons, that he might traverfe the world, and teach mankind the ufe of corn and fruits. After this, having difcovered, by means of the nymph Are- :thufa, that Profei-pine was In the infernal regions, fhe applied to Jupiter, and obtained of him that Profer- pine fhould be reftored, on condition that fhe had tafted Tiothing during her ftay In that place • but it beinff Vol. LV. PAar I. difcovered, by the Information of Afcalaphus, that, as Ceret flie was walking in Pluto's orchard, (he had gathered an apple, and had trifled of fome of the feeds, flie was ^^''' "'^"*'^ for ever forbidden to return. Ceres, out of revenge, turned Afcalaphus into an owl. At length, Jupiter, to mitigate her grief, permitted that Proferpine fhould pafs one half of the year In the Infernal regions with Pluto, and the other half with her mother on earth. Cicero fpeaks of a temple of Ceres at Catanea in Sicily, where was a very ancient flatue of that god- defs, but entirely concealed from the fight of men, eveiy thing being performed by matrons and virgins. CERET, a town of France In Rouffillon, with a magnificent bridge of a fingle arch. It Is feated near the river Tec, in E. Long. 2.46. N. Lat.42. 23. CEREUS, In botanv. See Cactus. CERIGO, an Ifiand In the Archipelago, anciently called Cytherea ; noted for being the birth-place of Helen, and, as the poets fay, of Venus. At prefent, there is nothing very delightful in the place ; for the country is mountainous, and the foil dry. It abounds In haref, quails, turtle, and excellent falcons. It is about 50 miles in circumference, and had formerly good towns ; but there Is now none remaining but that which gives name to the Ifland. This Is ftroug both by art and nature, It being feated on a craggy rock. The Inhabitants are Chriftian Greeks, and fub- jedl to the Vtnetians, who keep a governor tliere, whom they change every two years. CERINES, a town in the ifland of Cyprus, with a good cattle, an harbour, and a bifhop's fee. E. Long^ 33.35. N. Lat. 35. 2.2. CERINTHE, honevwoiit: A genus of die mo- nogynia order, belonging to the pentandria clafs of plants; and in the natural method ranking under the 41ft order, ylJperfoHte. The limb of tlie GoroUa Is d. ventrlcofe tube with the throat pervi/ius ; and there are two bilocular feeds. There are three fpecies, na- tives of Germany, Italy, ajid the Alps. They are low annual plants with purple, yellow, and red floweri^, which may be propagated by feed fown In autumn, In a warn^ •fituStion. CERINTHIAN5, ancient heretics, who denied the deity of Jefus Chrifl. — They took their name fi-om Cerinthus, one of the firtt herefiarchs In the ^ church, being cotemporary with St John. See Ce- RINTHUS. They believed that Jefus Chrifl was a mere man, born of Jofeph and Mary; but that, in his baptlfm, a celeftial virtue defcended on him In form, of a dove ; by means whereof he was confecrated by the holy fpirit, and made Chrift. It was by means of this ce- leftial virtue, therefore, that lie wrought fo many mi- racles ; which, as he received it fi-om heaven, quitted him after his pnffion, and returned to the place whence It came ; fo that Jefus, whom they called a pure man, really died and rofe again ; but -that Chrift, who was dillinguifli-ed fn)m Jefus, did not fuffer at all. It was partly to refute this fed, that St John wrote his go- fpel. They received the gofpel of St Matthew, to countenance their doArine of circumcifion, fromChrlft's being circumclfed ; but they omitted the genealogy. They difcarded the epittles of St Paul, becaufe that apottle held circumcifion abolifhed. GEllINTHUS, a herefiarch, cotemporary with the P p apoftles^ Ceropsgia, Certhia. Plate ex XV. C E R [ 298 ] G E R apoftles, afcribed the creation not to God, but to an- 3. The hook-bllled red creeper has the bill fome- gels. He taught that Jefus Chrllt was the fon of Jo- what lefs hooked than the laft fpecles ; the general co feph, and that circumcifion ought to be retained under lour of the plumage is fcarlet ; wings and tail black. Ce the gofpel. He is looked upon as the head of the converted Jews, who raifed in the church of Antioch the tumult of which St Luke has given the hiitory in the 15th chapter of the Afts. Some authors afcribe the book of the apocalypfe toCerinthus; adding, that he put it off under the name of St John, the better to authorife his reveries touching Chrilt's reign vipon earth : and it is even certain that he publifhed fome woi-ks of this kind under the title of ApocaJylfe. See Apocalypse. CEROPEGIA, in botany: A genus of the mono In fome birds the forehead is of a buff-colour; and the parts about the head and neck have both a mixture of buff and dufey black, which are fufpefted to be the birds not yet arrived at their full plumage. 4. The pufiUa, or brown and white creeper, ac- cording to Edwards, is not above half the fize of our European creeper. The upper part 'of the body is brown, with a changeable glofs of copper: tlie under parts ai-e white ; the quills brown, edged with gloffy copper ; the tail blackifh, the outer feather tipped with white. The bird from which Edwards drew his fi- gynia order, belonging to the pentandria clafs of gure had a label tied to it, by the name of Honey- plants ; and in the natural method ranking under the thief. And that they are fond of honey is manifell, 30th order. Contorts. There are two ereft follicles ; from thof^ who keep birds at the Cape of Good Hope the feeds plumofe or covered with. a feathered pappus; having many forts in large cages, and fupplying them the Hmb of the corolla connivent or clofing at top. with only honey and water; but befides this, th-ey CERTHIA, in ornithology, the creeper or ox- catch a great m.any flies, which come within the reach of their confinement ; and thefe two make up their whole fubfiftence ; indeed, it has been attemjSted to tranfport them further, but the want of flies on board a fliip prevented them living more than three weeks \ fo neceiiary are infefls to their fublillence. 5. The Loteni, or. Loten's creeper, has the head, neck, back, rump, fcapulars, and upper tail-coverts^ of green gold ; beneath, from the bread to the vent, of velvet black, which is feparated from the green on the neck by a tranfverfe bright violet band, a line and half in breadth : the leffer wing coverts are of this laft colour ; the middle coverts are green gold ; and the greater coverts are very fine black, edged with grceu gold on the outer edge : the quills are of the lame co- lour, as are alfo the tail feathers. The female differs in having the breafl;, belly, fides, thighs, under wing and tail coverts, of a dirty white, fpotted with black EYE, a genus belonging to the order of picae. The beak is arched, flender, fharp, and triangular ; the tongue is fharp at the point ; and the feet are of the walking kind, /. e. having the toes open and uncon- nefted. Of this genus near 50 fpecies have been enu- merated by ornithologifts ; but Mr Latham fuppofes that many now defcribed as fpecies, will be found hereafter to be mere varieties ; which, he adds, is no wonder, fince many creepers do not gain their full plumage till the tli rd year's moult. The following are a few of the moil remarkable : 1. The familiaris, or common ox-eye, is grey above,, and white underneath, with brown wings and ten white fpots on the ten prime feathers. This bird is found in moil parts of Europe, though it is believed no where fo common as in Britain. It may be thought iiiore fcarce than it really is by the lefs attentive ob- ferver ; for, fuppofing it on the body or branch of and the wings and tail not of fo fine a black. It in- habits Ceylon, and Madagafcar ; and is called Angala- dian. Buffon tells us, that it makes its nefl of the down of plants, in form of a cup, like that of a chaffinch, the female laying generally five or fix eggs ; and that it is fometimes chafed by a fpider as large as itfelf, and very voracious, which feiz.es on the whole brood, and fucks the blood of the young birds. 6. The ccerulea, or blue creeper, has the head of a any tree, the moment it obferves any one, it gets to the cppofite fide, and fo on, let a perfon walk roimd the tree ever fo often. The facility of its nmning on the bark of a tree, in all diredlions, is wonderful : This it does with as much eafe as,a fly on a glafs win- dow. Its food is principally, if not wholly, infefts, which it finds in the chinks and among the mofs of trees.' It builds itS nefl in fome hole of a tree, and lays generally five eggs, very rarely more than feven.: thefe are afh-coloured, marked at the end with fpots mofl elegant blue; but on each fide there is a fl:ripe of " ' ' " " ' black like velvet, in which the eye is placed : the chia. and throat are marked with black in the fame manner; therefl: of the body violet blue. It inhabits Cayenne. Seba fays, that it makes its nefl; with great art. The outfide is compofcd of dry flialks of grafs, orfuchlike; but within of very downy foft materials, in the fhape of a retort, which it fufpends from fome weak twig, at the end of a branch of a tr ee ; the opening or mouth andftreaksof a deeper colour; and the fliell is obferved to be pretty hard. It remains in the places which it frequents during the winter, and builds its nefl early in the fpring. ■ 2. The hook-billed green creeper has a bill an inch and three quarters long, and bent quite in the fliape of a femicircle ; the plumage in general is ohve green, palefl beneath, and fcmtwhat inclined to yellow : the quills and tail are dullcy ; the legs duflty brown ; and downwards, facing the ground : the neck is a foot in See M the feathers juil above the knee, or garter, white. It inhabits the Sandwich Iflands in general, and is one of the birds whofe plumage the natives make ufe of in cOnflrucling their feathered garments ; which, havmg thefe olive-green feathers intermixed with the beautiful fcarlet and yellow ones belonging to the next fpecies, .and yellow-tufted Bee-eater*, make fome of the moil beautiful coverings of thefe iilanders. length, but the real nefl is quite at the top, fo that the bird has to climb up tltis funnel-hke opening to get at the nefl:. Thus it is fecure from every harm ;. neither monkey, fnake, nor lizard, daring to venture- at the end of the branch, as it would not fteadily fupport them. 7. The cardinal creeper, {^Lev. Muf.), has the head, neckj and breafl, of crimfon colour ; down the middle > C E R L 2 Gert'ificate. of the.back is a ftripe of the fame colour to the rump : ^— -v the rell of the body is black ; and the wings and tail are black. It inhabits the cultivated parts of the ifland of Tanna ; is there called Kuyameta, and hves by fucking the neflar of flowers. 8. The mocking creeper is of the_ fize of the lefTer thruOi. On the cheeks is a narrow white fpot : the head, efpecially on the crown, is inclined to violet : the plu- mage in general is olive green, inclining to yellow on the^nder parts: the quills are brown ; the fecondanes edged with olive : the colour of the tail is like that of the fecondaries, and foraewhat forked : the legs are du{] o right ones. 3. Moral certitude is that founded on moral evidence, and is frequently equivalent to a mathematical one ; as that there was formerly fuch an emperor as Julius Casfar, and that he Avrote the com- -mentaries which pafs under his name; becaufe the hif- torians of thefe times have recorded it, and no man has ever difproved it fince : this affords a moral certi- tude, in common fenfe fo great, that one would be thought a fool or a madman for denying it. CERTOSA, a Celebrated Carthufian monaftery, in the ten-itoiy of the Pavefe, in the duchy af Milan, four miles from Pavia ; its park is fiirrounded with a wall 20 miles in circumference ; but there are feveral fmall towns and villages therein. CERVANTES. See SAAviiCRA. CERVERA, a town of Spain, in Catalonia, feated on a fmall river of the fame name, in E. Long. i. 9. N. Lat. 41. 28. CERVIA, a fea-port town of Italy, In Romagna, v/ith a biihop's fee, feated on the gulpii of Venice, in E. Lono;. I 0- N. Lat. 44. 16. CERVICAL NERVES, are feven pair of nerves, fo called, as having their origin in the ceriux, or neck. CKKinrAi. Vejjels, among anatomifts, denote the ar- teries, veins, &c. which pafs through the virw'.ra and mufcles of the neck, up to the fliull. P p 3 CERVIX, Cervix w Ccrvus. C E R I 3 CERVIX, in anatomy, properly denotes the hind part of the neck ; as contradittinguifhed from the ibre part, which is called jugulum, or the throat. Cervix of the Scapula, denotes the head of the fiioulder-blade, or that upper procefs whofe JJrn/s re- ceives the head of the humerus. CERrjx of the Uterus, the neck of the uterus, or that oblong canal, or palTage between the internal and ex- ternal oriiices, which receives and inclofes the penis like a (heath, whence it is alfo called Vagina. CERUMEN, a thick, vifcous, bitter, excremen- titious humour, feparated from the blood b-y proper glands placed in the meatus audhorius, oi outer paffage of the ear. CERUSS. WHiTE-LEADj a fort of calx of lead', made by expofing plates of that metal to the vapour of vinegar. See CHEMisTfty-/«(r/e.v. Cerufs, as a medicine, is ufed externally either mixed in ointments, or by fprinkhng it on old gleeting and watery ulcers, and in miiny difeafes of tlie ikin. If, when it is reduced into a fine powder, it is re*- ceived in with the breath in infpiration, and carried down into the lungs, it caufcs. incurable afthmas. In- ftances of the very pernicious eiTefts of this metal are too often feen among thofe pcrfons who work lead in any form, but particularly among the workers in white-lead.' The painters ufe it fn great quantities ; and that it may be afforded cheap to them,, it is generally adul- terated with common whiting. CERVU8, or Deer, in zoology,, a genus of qua- rxx'x * drupeds belonging to the order of Pecora. The horns and ' ^'^^ brittle, covered with a hairy- Ikin, and CXXXI. growing from the top ; they likewife. fall off and>are renewed annually. There are eight fore-teeth in tlie under jaw, and they have no dog-teeth.. Tlte fpecies of this gerius enumerated by Liimaeus are feven, viz. I. The. Camelopardalis, or Giraffe, with fimple or vmbranched horns, llraight, about fix inciies long, covered with hair, and truncated at the end and tufted ; in the forehead a. tubercle, about two inches high, re>- fembhng a. third horn, Tlie fore legs are not much longer than the hind legs :; but the flioulders are of a vatt length, which' gives- the difpropoitionate height between the fore and bind parts :■ the head is like that of a flag : tlie neck is {lender and elegant, > and on the upper fide is a fhort mane : the ears are large tail is lojig, with.ftrong h-airs at the end : the colour of the whole, animal- a dirty white, marked wiih large broad rufty fpots. This is an uncommon animal, few of them having been ever feen in Europe. It inhabits the fo- refts of Ethiopia,- and other interior parts of Africa, almoff as high as Senegal ; but is not found in Guinea, or any of the. weftern parts nor farther fouth thaa .about lat. 2.8. 10. It is very timid, but not fvvift ; and has been reprefented as liying only by browfing the treeSj being unable from the difproportionate length of its fore legs to graze or feed from the ground. When it would leap, it lifts up its fore legs and then its hind, like a horfe whofe fore legs are tied. It runs -very badly and aukwardly, and is very eafily taken. .The late.ft and beft defcription of this extraordinary quadruped is given in the i6th number of a work en- titled, " A Defcription of the uncommon Animals aiid remarkable Produdions in the Cabinet and Me- 00 ] C E R Plate nagerie of his Serene Highnefs the Prince of Orange ;" Cerv by M. Vofmaer, Direftor of his Highnefs's Collec- r tions of Natural Hiftory. His account of the giraffe, is compofed partly from the notices, of M. Vaillant and Mr Gordon of the Cape of Good Hope, and partly from his own obfervationson the lldns of four of thcfe animals, together with a complete Ikeletou, in the ca-- binet of cuiiofities under his care. , All die accounts we have of the giraffe, agree in ■ reprcfendng its hind quarters as about 2~ feet lower than its withers : but from obfervations made by the late profeffor Camper on the above mendoned ilvele- ton, it would appear that naturalifts have been greatly miftaken in this paTUcular. That its fore legs are. longer than its hind legs, , is indeed true ; but the dif- ference is not more than feven inches, which, in a height of feven feet, is no great matter. It may, however (the profeffor obferves), be rendered appa- rently more coufiderable by the obliquity of the thigh-r bone, with refped to the tibia, when compared with that of the humerus to the radius. The giraffe has always been celebrated for the gentlenefs of its difpofidon. Antonius Conilantius, a writer of the 15th century, in a letter to Galeas Man* fredi. Prince of Faenza, dated Fano, 1 6th December i486, gives an account of a giraffe which he faw there. . He fays it was fo gende, that it would eat bread, hay, or fruit, out of the hand -of a child ; and . that j when led through the ttreet, it would take what- ever food.of this kind was offered to it by the fpeda- tors.at the windows, as it paffed along. This cha- rafter is confirmed by Mr Gordon, who relates, diat. a giraffe, . which he had wounded, fuffered him to ap- proach it as it lay on the ground, without , offering to Itrike with its horns, or (howing any incHnation to rer venge.itfelf ; he even ffroked it over its eyes feveral times, when it only clofed them, . without any figns of: refeotment. Its throat was afterwards cut for tlie fake of its fl even drink .from a river, the furface of which is lower than the bank on which it Hands. . M. Vofmaer ob- ferves, that this account is confirmed by confidering the llrufture of the neck, the vertebrae of which are connefted- with thofe. of the back by a very Itrong , ligament. The giraffe here defcribed, which Mr Gordon, who differed it, fays was the largeft he had ever feen, was 15 feet 4 inches Rhinland meafure (about 15 feet 10. inches Enghlh) from the ground to the top of its head ; the length of the body, from the cheff to the Tump, -R-as 5 feet 7 inches Rhinland meafure. M. Vaillant afferts, that he. has feen feveral which were at leall 1 7 feet high ; and M. Vofmaer declares, . that he has been affured by fome very refpeftable inliabitants of the Cape, that tliey had feen and killed giraffes, whicli, . E ^ [3 Cervus. v?}iIcK, Including tlie horns, were 22 Rhinland feet in height. The giraffe was known to the Romans in early- times. It appears among the figures in the aflemblage of eaftern animals on the celebrated Prseneftine Pave- ment, made by the direftion of Sylla ; and is repre- fented both grazing and browfing, in its natural at- titudes. It was exhibited at Rome by the popular Csfar, among other animals in the Circaean games. 2. The Alces, Elk, or Moofe Deer, has palmated horns, without any proper ilcm, and a flcfhy protu- berance on the throat. The neck is much {horter than the head, with a fhort, thick, upright mane, of a light brown colour. The eyes are fmall ; the ears a foot long, very broad and touching ; noftrils very lafge ; the upper lip fquare, hangs greatly over the lower, and has a deep fulcus in the middle, fo as to appear almoft bifid. This is the bulkieft animal of the deer kind, being fometimes 1 7 liands high, and weigh- ing above 1 200 pounds. The female is lefs than the male, and wants horns. The elks inhabit the ifle of Gape Breton, Nova Scotia, and the weftern fide of the bay of Fundy; Canada, and the country round the great lakes, ahnoll as far fouth as the river Ohio. Theie are its prefent northern and fouthern limits. In all ages it alFefted the cold and woody regions in Eu- rope, Afia, and America. They are found in all the woody trafts of the temperate parts of Ruffia, but not on the Arftic flats, nor yet. in Kamtfchatka. In S't- beria they are of a monftrous fize, particularly among the mountains. The elk and the moi)fe, according to Mr Pennant, are the fame fpecies ; the laft derived from nwfu, which in the Algonkin language fignifies that animah The Engliih ufed to call it the black moofe, to ' diftinguilh it from the ftag, which they named the grey moofe. The French call it I'ong- TUll. Thefe animals refide amidft forefls, for the conve- niency of browfing the boughs of trees, becaufe they are prevented from grazing with any kind of eafe, by reafon of the fliortnefs of their necks and length O'f their legs. They often have recourffe to water-plants, which they can readily get at by wading. M. Saira- fin fays, that they are very fond of the anagyris foe- tida, or ftinking bean trefoil, and will uncover the fnow with their feet in order to get at it. In pafTmg through the woods, they raife their heads to a hori- zontal pofition, to prevent their horns from being en- tangled in the branches. They have a Angular gait : their pace is a= (hambling trot, but they go with great fvviftnefs. In their common walk they lift their feet very high, and will without any difficulty ftep O'ver a gate five feet high. They feed principally in the night. If they graze, it is always againft an afcent ; an advantage they ufe for the reafoa above affigned. They ruminate like the ox. They go to rut in au- tumn ; are at that time very furious, feeking the fe- male by fwimming from ifle to ifle. They bring two }"Oung at a, birth, in. the month of April, which follow the dam a whole year. During the fummer they keep in famines. In deep fnows they coUeft in numbers in the forefts of pines, for proteftion from the incle- mency of the weather under the fhelter of thofe ever- greens. They are very inoffenfive, except in the rut- 4-, Di ] C E R tlng-feafon ; or except they are wounded, when they Cervus. will turn on the aflailant, and attack him with their — horns, or trample him to death beneath their great hoofs. The flefli of the moofe is extremely fweet and nou- rifliing. The Indians fay, that they can travel three times farther after a m.eal of moofe, than after any other animal food. The tongues are excellent; but the nofe is perfeft marrow, and efteemed tlu^ greateit delicacy in Canada. The fliin makes excellent buff ^ being ftrong, foft, and hght. The Indians drefs the- hide, and, after foaking it for fome time, ftretch and render it fupple by a lather of the brains in hot water. They not only make their fnow-flioes of the Ikin, but after a chafe form the canoes with it : they few the flcins neatly together, cover the feams with an unctu- ous earth, and embark in them with their fpoils to return home. The hair ou the neck, withers, and hams of a full-grown elk, is> of much wit in making mattieifes and faddles ; being by its great length well adapted for thofe purpofes. The palmated parts of the horns are farther excavated by the favages, and ' converted into ladles, which will hold a pint. • It is not ftrange that fo ufeful an animal fliould be a principal obj eft of chafe. The favages perform it in ditferent vi'ays. The firft, and the more fimple, is before the lakes or rivers are frozen. Multit-udes af- fcjiible in their canoes, and form with them a vail orefcent, each horn touching the fhore. Another party perform their fliare of the chafe among the - woods ; they furround an extenfive trait, let loofe their dogs, and prefs towards the water with - loud cries Tlie animals, alarmed with the noife, fly lyefore the hunters, and plunge into the lake, where they arc killed by the pei-fons in the canoes, prepared for their reception, with lances or ckbs. The other method is more artful- The favages inclofe a large fpace with ftakes - hedged with branches of trees, forming two fides of a. triangje : the bottom opens into a fecond in- clofure, completely triangular. At the opening are hung numbers of fnares, made of flips of raw hides. The Indians, as before, aflemble in. great, troops, and - with all kinds of noifes drive into the firll inclofure not only the moofes, but the other fpecies of deer which abound in that country : . fome, in forcing their way into the fartheft triangle, are caught in. the fnares by the neck or horns ; and thofe which efcape the fnares, and pafs the httle opening, find their fate from the arrows of the hunters, direi^cd at them from all quarters. They are often killed with the gun. When? they are firit unharboured, they fquat witli their hind parts and make water, at which inftant the fportfinan fires ; if he miifes,. the moofe fets off in a moft rapid trot, making, like the rein-deer, a prodigious rattling with its hoofs, and will run. for 20 or 30 miles before it comes to bay or takes the water. But the ufual time for this diverfian is the winter. The hunters- avoid entering on the chafe till the fun is ftrong enougli ^ ta melt the frozen cruft with which the fnow is co- vered, otherwife the animal can run over the firm fur- face: they . wait till it becomes foft enough to impede the flight of the moofe ; which finks up to the fliould= - ers, flounders, and gets on with great difficulty. The-: fportfraan purfues at his eaCc on hia. broad rackets, ci^- fnoW".' - Ceivus. fnow-flioes, animals. C E R &nd makes a ready prey of the E R clear them of 3 fiilii As weak againft the mountain heaps they pufh Their beating breaft in vain, and piteous bray, He lays them quivering on th' enfanguin'd fnows, And with loud lliouts rejoicing bears them home. Thompson. The opinion of this animal's being fubjecl to the ■epllepfy ieems to have been univerfal, as well as the cure it finds by fcratching its ear with the hind hoof till it draws blood. That hoof has been ufed in Indian medicine for the falling-ficknefs ; they apply it to the heart of the affliiiled, make liim hold it in his left hand, and rub his ear with it. They ufe it alfo in the colic, plcurify, vertigo, and purple fever ; pulverifmg :the hoof, and drinking it in water. The Algonkins pretend that the flefiv imparts the difeafe ; but ii is no- torious that tlie hunters in a manner live on it with impunity. The favages efteem the moofe a beaft of good omen ; and are perfuaded that thofe who dream often of it may flatter themfelves with long life. The elk was known to the Romans by the name of Jke and Machlis : they believed that it had no joints in its legs; and, from the great fize of the upper lip, imagined it could not feed without going backward as it grazed. 3. The Eiainuis, or Stag, with long cylindrical ramified horns bent backwards, and {lender fliarp brow antlers. The colour is generally a reddilh brown with fome black about the face, and a black lift down the hind part of tlie neck and between the Ihoulders. Stags are common to Europe, Barbary, the north of Afia, and America. In fpring, they ihed their horns, which fall off fpontaneoufly, or by rubbing tliem gently againft the branches of trees. It is feldora that both horns fall off at the fame time, the one generally preceding the other a day or two. The old ttags.catt their horns lirll, which happens about the end of Fe- bruary or beginning of March. An aged ftag, or one in his feventh year or upwards, does not call his horns before the middle of March ; a ftag of fix years (beds his horns in April ; young ftags, or thofe from three to^five years old, ihtd their horns in the beginning, and tlioi'e wiiich are in their lecond year, not till the middle or end of May. But in all this there is much variety ; for old ftags fometimes caft their horns fooucT than thofe which are younger. Befides, the ihedding of the horns is advanced by a mild, and re- tarded by a fevere and long winter. As foon as the itags calt their horns, they feparate from each other, the young ones only keeping toge- ther. They no longer haunt the deepeft receffes of the foreft, but advance into the cultivated country, and remain among brullivvood during tlie-fummer, till tlic'r horns are renevred. In this feafon, they walk with tlieir heads knv to prevent their horns from rub- bing againft the branches ; for they continue to have fenjibility till they acquire their full growth. The horns of the oldett ftags are not hdf completed in the middle of May, and acquire their full. lcngth and hard- nefs before the end of July. Thofe of the younger ftags are proportionaliy later both in Ihedding and being renew;.!. But as foon as they have acquired their full dimenfions and foHdity, the ftags rub them [ 302 T i diftreffed againft the trees, in order to with which they are covered. Soon after the ftags have poliihed their horns, they begia to feel the imprefllons of love. Towards the end of Auguft or beginning of September, they leave the coppice, return to the forells, and fearch for the hinds. They cry with a loud voice ; their neck and throat fwell ; they become perfeAly reftlefs, and tra- verfe in open day the fitlds and the fallow grounds ; they ftrike their horns againft trees and hedges ; in a word, they feem to be tranfported with fury, and run from country to country till they find the hinds or females, whom they j>urfue and compel into compli- ance ; for the female at firft avoids and flies from the male, and never fubmits to his embraces till flie be fatigued Avith the purfuit. T4ie old hinds likewifc come in feafon before the younger ones. -When two ftags approach the fame hind, they muft fight before they enjoy. If nearly equal in ftrength, they threaten, paw the ground, fee up terrible cries, and attack each other with fuch fury, J:liat they often inflift mortal Cerviis ds with the ftrokes of their horns. The combat never terminates but in the defeat or flight of one of the rivxls. The conqueror lofes not a moment in en- joying his victory, unlefs another rival approaches, whom he is again obhged to attack and repel. The oldeft ftags are always mafters of the field ; becaufe they are ftronger and more furious than the young ones, v\ ho mull wait patiently till their fuperiors tire, and quit their miftreffes. Sometimes, however, the voung ftags accomplifti their purpofes when the old ones are fighting, and, after a hafty gratification, fly off. The hinds prefer the old ftags, not becaufe they aie moft courageous, but becaufe they are much more ardent. Thty are likewife more inconftant, having often feyeral females at a time ; end when a ftag has but one hind, 'his attachment to her does not conti- nue above a few days : He then leaves her, goes in queft of another, with whom he remains a ttill ihorter time ; and in this manner paifes from one to ano- ther till he is perfectly txhauiced. This ardour of love lafts only three weeks, during which the ftags take very little food, and neither fleep nor reft. Night and day, they are either walking, running, fighting, or enjoying the hinds. Hence, at the end of the rutting feafon, they are fo meagre and exhaufted, that they recover not their ftrengtii for a confiderable time. They generally retire to the bor- ders of the forefts, feed upon the cultivated fields, where they find plenty of nouvifhment, and remain there till their ftrength is re-eftabliftied. The rutting feafon of old ftags commences about the begiiming, and cuds about the 20th day of September. In thofe of fix or fevcn years old, it begins about the 10th of September, and Coududcs in the beginning of October. In young ftags, or tlioic ir. their third, fourth, or fifth year, it 'begins :ii)ui.'i che 20th of September, ard ter- minates about the 5 5th of October ; and at tn : cr.d of October, the rutting is aU over, except ng : iiig the prlchis, or t\v^it wiiich have entered into .neir fecondyear; becaufe they, like the young hinds, are lateft of coming into fealbn. Hence, at the bjgin- • ning of November, the feafon of love is entirely luiiuied ; and" tlie ftags, during tiiis penud of weakneis and laf : fitude, are eafily huntea down, lu feafons when acorns and C E R I 3 Cen'us. and' other nuts are plentiful, the flags foon recover their ftrength, and a fecond rutting frequently hap- pens nt the end of Oftober ; but it is of much fhorter duration than the flrft. In climates warmer than that of France, the rutting time, like the feafons, is more forward. Ariftotle informs us, that, in Greece, it commences in the beginning of Auguft, and terminates about the end of "^September. The hinds go with young eight months and fom.e days, and feldom produce more than one fawn. Tliey bring forth in May or the beginning of June, and fo anxioufly conceal their fawns, that they often expofe themOdves to be chafed, with a view to draw oft' the dogs, and afterwards return to take care of their young. All hinds are not fertile ; for fome of them never conceive. Thefe barren hinds are groffer and favter than thofe which are prolific, and alfo come fooneft in feafon. The young are not called fatvr.s or cahes after the fixth month : The knobs of their horns then begin to appear, and they take the name of knchhers till their horns lengthen {nto [pears, and then they are called brocks or Jlaggards. During the firfl feafon, they never leave their mothers. In winter, the ilaji^s and hinds, of all ages, keep together in flocks, which are ahvays more numerous in proportion to the rigour of the feafon. They feparate in fpring : The hinds retire to bring forth ; and, during this period, tHe flocks confilt only of knolAers and young ftags. In general, the ftags are inclined to affociate, and no- thing but fear or neceffity obliges them to difperfe. The Hfe of the ftag is fpent in alternate plenty and want, vigour and debiUty, health and fickueffi, with- out having any change introduced into his conftitution bv thefe oppolite extremes. He lives as long as other aniir.als which are not fubjefted to fuch viciflitudes. As he grows five or fix years, he lives feven times that number, or from 35 to 40 yearj-. What has been re- ported concerning the longevity of the flag merits no * credit. It is only a popular prejudice which prevailed in the days of Anftotle, and which that philofopher confidered as improbable, becaufe neither the time of geftation, nor of the growth of the young ftag, indi- cated long life. This authority ought to have abolifhed the prejudice ; but it has been renewed, in the ages of ignorance, by a fabulous account of a ftag taken by Charles VI. in the forell of Senlis, with a collar upon which was written this infcription, Cafar hoc me dona- 'vit. The love of the marvellous inchned men to be- lieve that this animal had lived 1000 years, and had his collar from a Roman emperor, rather than to fup- pofe that he came from Germany, vvhere all the em- perors take the name of Cirfnr. The ftag appears to linve a fine eye, an acute fmcll, and an excellent ear. When liftening, he raifes his head, eretts his ears, and hears from a great diftance. When he is going into a coppice, or other half covered place, he ftops to look round him on all fides, and fcents the wind, to difcover if any objeft is near that might dlihn-b him. He is a fimple, and yet a curious and crafty animal. When hifTtd or called to frcra a diftance, he ftops ftiort, and looks ftedfaftly, and with a kind of admiration, at carriages^ cattle, or men ; and if they have neither arms nor dogs, he moves on unconcernedly, and without flying. He appears to fiften, with great tranquillity and delight, to the fnep- Kerd's pipe ; and the hunters foraetiiiies employ this 6 03 1 C E R artifice to encourage and deceive him. In general, he Cervus. is lefs afraid of men than of dogs, and is never fufpi- — —v— clous, or ufes any arts of concealment, but in propor- tion to the difturbances he has received. He eats flow, and has a choice in his aliment ; and after his flo- mach is full, he lies down, and ruminates at leifure. He feems to ruminate with lefs facility than the ox. It is only by violent fhakes that the ftag can make the food rife from his firil ftomach. This difiiculty proceeds from the length and direction of the paffagp through which the aliment has to go. The neck of the ox is fliort and ftraight, but that of the ftag i". long and arched ; and therefore gi eater efforts are n;;-- ceffary to ralfe the food. Theie efforts are made by a kind of hiccup, the movement of which is apparent, and continues during the time of rumination. His voice is ftronger, and more quivering, in proportion as he advances in years. The voice of the hind is fhorter and more feeble. She never bellows from love, but from fear. The flag, during the rutting feafon, bel- lows in a frightful manner : He is then fo tranfported, that nothing diihirbs or terrifies him. He is there- fore eafily furprlfed ; as he is loaded with fit, he cannot keep long before the dogs. But he is dange- ' rous when at bay, and attacks the dogs with a fpecies of fury. He drinks none in wir(ter nor in fpring, the dews and tender herbage being then fufficient to extlnguifh his thirft ; but, during the paixhing heats of fummer, to obtain drink, he frequents the brooks, the marfhes, and the fountains ; and in the feafon of love, he is fo over-heated, that he fearches eveiy wht-re for water, not only to fatisfy his immoderate thirft, but to bathe and refrefli his body. He then fwims eafier than at any other times on account, of his fat- nefs. *He has been obferved croffing very large riversw It has even been alleged, that, attracted by the odour of the hinds, the ftags, in the rutting feafon, throw ihemfelves into the fea, and pafs from one ifland to another at the diftance of feveral leagues. They leap jlill more nimbly than they fvvira ; for, v/lien purfued, they eafily clear a hedge or a pale fence of fix feet high. Their food varies in different feafons. In au-- tumn, after rutting, they fearch for the buds of green flirubs, the flowers of broom or heath, the leaves of brambles, &c. During the fnows of winter, they feed upon the bark, mofs, &c. of trees; and in mild weather, they browfe in the wheat-Helds. In the be- ginning of fpring, they go in queft of the catkins of the trembling poplar, willow, and hazel-trees, the flowers and buds of the cornel tree, &c. In fummer, . when they have great choice, they prefer rye to' all other grain, and the black berry-bearing alder to all other wood. The flefli of the fawn is very good : that of the hind and knobber not abfolutely bad ; but that of the flag has always a ftrong and difagreeable tafte. The fkin and the horns are the moft ufeful parts of this animal. The flcin makes a pliable and very ' durable leather. The horns are ufed by cutlers,, fword-flippers, he. and a volatile fpirit, much em- ployed in medicine, is- extracted from thein by the chymifts. In America, ftags feed eagerly on the broad-leaved kahnia ; yet that plant is a poifon to all other horned, animals : their inteftines are found filled with it du-- ring winter. If their entrails are given to dogs, they become Itupified, and as if drunk, and often 'are. fO' ill' as; C E R Cervus. as hardly to efcape with Kfe. The American ^■""v""" grow very fat : their tallow is much eftecmed for ma- king of candles. The Indians flioot them. As they are very ftiy animals, the natives cover themfelves with a hide, leaving the horns eredt ; under flielter of which they walk v/ithin reach of the herd. De Brie, in the 25th plate of the Hiftory of Florida, gives a very cu- rious reprefentation of this artful method of chafe, when it was vifited by the French in 1564. Their llcins are an article of commerce imported by the Hud- fon's Bay Company ; but brought from the diftant parts far inland by the Indians, who bring them from the neighbourhood of the lakes. In moft parts of North America they are called the grey moofe, and the elk ; this has given occafion to the miftaken no- tion of that great animal being found in Virginia and other fouthern provinces. In Britain the fta::^ is become lefs common than for- merly ; its exceffive vicioufnefs during the rutting fea- fon, and the badnefs of its flefh, induce moft people to part with the fpecies. Stags are flill found wild in the Highlands of Scotland, in herds of four or five hundred together, ranging at full liberty over the vafl h'dh of the north. Formerly the great Highland chieftains ufcd to hunt with the magnificence of an eaftern mo- narch, alTembling four or five thoufand of their clan, who drove the deer into the toils or . to the ftations the lairds had placed themfelves in.: but as this pre- tence was frequently ufed to collect their vafials for rebellious purpofes, an aft .was paffed prohibiting any alTemblies of this nature. Stags are hkewife met with on the moors that border on Cornwal and Devonfhire ; and in Ireland on. the mountains of Kerry, .where they add greatly- to the magnificence of the romantic fee- nery to the:.lake of 'Killarny. The ftags of Jreland during, its uncultivated flate, and while it remained an almgili boundlefs-traft of foreft, had .,an exadl agree- ment in habit with thofc that range at prefent through the wilds of America. They were lefs in body, but very fat ; and their horns of a fize far fu- perior to^thofe of Europe, but. in farm agreed in all points. The chace of the flag has been formed Into an art, and requires a fpecies of knowledge which can only be learned by experience : It implies a royal alTem- blage of men, horfes, and dogs, all fo trained, prac- tifed, and difciplined, that their movements, their re- fearches, and their fldll, mud concur in producing one common, end. The huntfman fliould know the age and the fex of the animal ; he fhould be able to di- flinguiih with precifion, whether the ftag he has har- boured with his hound be a knobber, a young ftag, in his fixth or feventh year, or an old ftag. The chief marks which convey this intelligence is derived from the foot, and the excrement. The foot of the flag Is better formed than that of the hind, or female. Her leg is more grofs and nearer the heel. The impreffions of his feet are rounder, and farther removed from each other. He moves more regularly, and brings the hind foot into the imprefliom made by the fore-foot. But the diftance between the fteps of the hind are Hiorter, and her hind-feet ftrike not fo regularly the track of the fore feet. As foon as the flag acquires his fourth .horns, he is eafily diftinguifhed ; but to know the foot of a youn^ ftag from that cf a hind, requires re- t m ] . C E R flags pcated experience. Stags nf fix, feven, years, are ftill more eafily known;. for tlieir fore-foot is much larger than the hind foot ; the older they are. the fides of their feet are the more worn ; the diftance of their fteps are more regular than thofe of young ftags ; they always place their hind foot exaftly in the track of the fore-foot, excepting, when they flied their horns, the old ftags mifplace, at this feafon, nearly as often as the young ones ; but in this they are more re- gular than the hind or young ftag, placing the hind foot always at the fide of the fore-fof)t, and never beyond or within it. When the huntfman, from the drynefs of the feafon, or other circumftanccs, cannot judge by the foot, he is obliged to trace the animal backwards, and en- deavour to find his dung. .This mark requires, per- haps, greater experience ,than the knowledge of the foot; but without it the huntfman would be unable to give a proper report to the company. After the report of the huntfman, and the dogs are led to the refuge of the ftag, he ought to encourage his hound, and make him reft upon the track of the ftag, till the animal be unharboured. Inftantly the alarm is given to uncouple the dogs, which ought to be enlivened by the voice and the horn of the huntfman. He fiiould alfo diligently obferve the foot of the ftag, in order to dilcover whether the animal has ftarted, and fubftituted another in his place. But it is then the bufinefs of the hunters to feparate alfo, and to recal the dogs which have gone aftray after falfe game. The huntfman ftiould always accompany his dogs, and encourage, without preffing them too hard. He fhould alfill them In detedling all the arts of efcape ufed by the ftag ; for this animal has remarkable addrefs in de- ceiving the dogs. With this view, he often returns twice or thrice upon his former fteps; he endeavours to raife hinds or younger ftags to accompany him, and draw oft' the dogs from the object of their purfuit : he then flies with redoubled fpeed, or fprings off at fide, lies down on his belly, and conceals himftlf. In this cafe, when the dogs have loft his foot, the huntf- men, by going backwards and forwards, alfift them In recovering it. But if they cannot find it, they fup- pofe that he is refting within the circuit they have made, and go In queft of him. But if they are ftill unable to difcover him, there Is no other method left, but, from viewing the country, to conjefture where he may have taken refuge, and repair to the place. As foon as they have recovered his foot, and put the dogs upon the track, they purfue with more advantage, be- caufe they perceive that the ftag Is fatigued. Their ardour augments In proportion to his feeblenefs ; and their fcent becomes more diftin£l as the animal grows warm. Hence they redouble their cries and their fpeed ; and though the ilag praftifes ftill more arts of efcape than formerly, as his fwiftnefs Is diminifhed, his arts and doublings become gradually lefs eftcdlual. He has now no other refource but to fly from the earth which he treads, and get into the waters, in order to cut off the fcent from the dogs. The huntfmen go round thefe waters, and again put the dogs on the track of his foot. The ftag, after taking to the wa- ter, is incapble of running far, and is foon at bay. But he ftill attempts to defend his life, and often wounds the dogs, and even the huntfmen when too for- ward, by blows with his horns, till one of them cute his hams Cervuj. C E R [ 305 ] G E R Oervnu. J^a^s to make him fall, and then puts an end to his raw, dreffed, and dried and fmoked with the fnow Cervut. life by a blow of a hancrer. They now celebrate the lichen. The wearied hunters will drink the raw blood ; death of the ftag by a flour i(h of their horns; the dogs but it is ufuajly dreffed with the berries of the heath : arc allowed to trample upon him, and at laft partake they eagerly devour the contents of the ftomach, but richly of the vidtory by devouring his flefh. ufe the inteftines boiled. They are very fond of the 4. The Tarandus, or Rein-deer, is a native of fat, and will not lofe the leaft bit. The fldn, fome- Lapland, and the northern parts of Eprope, Afia, and times a part of their cloathing, dreffed with the hair America. The horns are large, cylindrical, branched, on, is foft and pliant ; it forms alfo the inner lining and palmated at the tops. Two of the branches hang of their tents, and moll excellent blankets. The ten- over the face. He is about the fize of a buck, of a dons are their bow-ftrings, and when fplit are the dirty whitifh colour ; the hairs of his flfin are thick and threads with which they few their jackets, jftrong. To the Laplasders this animal is the fubftitute The Greenlanders, before they acquired the know- of the horfe, the cow, the goat, and the flieep ; and ledge of the gun, caught them by what was called io their only weahh : the milk affords them cheefe ; the clapper -hunt. The women and children furrounded •the flefli, food; the flcin, cloathing; the tendons, bow- a large fpace, and, where people were wanting, fet up " firings ; and when iplit, thread ; the horns, glue ; poles capped with a turf in certain intervals, to terrify the bones, fpoons. During the winter it fupplies the the animals ; they then with great noife drove the want of a horfe, and draws their fledges with ama- reins into the narrow defiles, where the men lay in wait zing fwiftnefs over the frozen lakes and rivers, or and killed them with harpoons or darts. But they aris over the fnow, which at that time covers the whole now become very fcarce. country. A rich Laplander is poffeffed of a herd of The rein-deers are found In the neighbourhood of 1000 rein deer. In autumn they feek the highefl hills, Hudfon's Bay, in moft amazing numbers, columns' of to avoid the Lapland gad-fly, which at that time de- eight or ten tlioufand are feen annually paffmg frorti pofits its eggs in their flcin ; it is the pell of thefe ani- north to fouth in the months of March and April^ mals, and numbers die that are thus vifited. The driven out of the woods by the muflcetoes, feeking re- moment a fingle fly appears, the whole herd inflantly frefhment on the fhore, and a quiet place to drop their perceives it;' they fling up their heads, tofs about young. They go to rut in September, and the males .their horns, and at once attempt to fly for fhelter foon after flied their horns ; they are at that feafon amidft the (hows of the loftieft Alps. In fummerthey very fat, but fo rank and muflcy as not to be eatable, feed on feveral plants; but during winter on the rein- The females drop their young in June, in the mofl: fc* .liverwort, which lies far. beneath the fnow, which quefliered foots they can find ; and then they likewife they remove with their feet and palmated brow ant- lofe their horns. Beafts of prey follow the herds : ,Iers, in order to get at their beloved food. firft, the wolves, who fingle out the ftragglers (for they The Samoieds, lefs inteUigent than the Laplanders, fear to attack the drove), detach and hunt them down : confider them in no other view than as animals of the foxes attend at a diftance, to pick up the offals left draught, to convey them to the chafe of the wild reins; by the former. In autumn the deer with the fawns re- which they kill for the fake of the flcins, either to migrate northward. The Indians are very attentive clothe themfelves, or to cover their tents. They know to their motions ; for the rein forms the chief part not not the cleanly delicacy of the milk or cheefe ; but only of their drefs but of their food. They often kill prefer for their repaft the inteltines of beafts, or the multitudes for the fake of their tongues only; butge- half.putrld flefh of a horfe, ox, or flieep, which they nerally they feparate the flefli from the bones, and pre- iind dead on the high road. — The Koreki, a nation ferve it by drying it in the fmoke ; they alfo fave thfe of Kamtfchatka, may be placed on a level with the fat, and fell it to the Englifli in bladders, who ufe it Samoieds. They keep immenfe herds of reins ; fome in frying inflead of butter. The flcins are alfo an ar- of the richefl: to the amount of 10 or 20 thoufand ; tide of commerce, and ufed in London by the yet fo fordid aie they as to eat none except fuch as Breeches-makers. The Indians fhoot them in thewinter. they kill for the fake of the flcins ; an article of com- The Enghfli make hedges with flakes and boughs of inerce with their neighbours the Kamtfchatkans ; trees along the woods for five miles in length, leaving otherwife they content themfelves with the flefh of thofe openings at proper intervals befet with fnares, in which which die by difeafe or chance. They train them in multitudes are taken. The Indians alfo kill great the fledge, but negleft them for every domeftic pur- numbers during the feafons of migration, watching in f ofe. Their hiflorian fays, they couple two to each their canoes, and fpcaring them while palling over the carriage ; and that the deer will travel 150 verfts in a rivers of the country, or from Ifland to ifland ; for they day, that is, 112 EngUfli miles. They caftrate the fwim moft admirably well. males by piercing the fpermatic arteries, and tying the 5. The Dama or Fallow-deer, Buck and Doe ; with fcrotum tight with a thong. — The favage and unin- horns branched, compreffcd, and palmated at the top. formed Efklmaux and Grecnlanders, who poffefs, amidft The colour is various ; reddifli, deep brown, white or their fnows, thefe beautiful animals, neglect not only fpotted. This fpecies is not fo univerfal as the flag : the domeftic ufes, but even are Ignorant of their advan- rare in France and Germany. It is found in Greece, tage in the fledge. Their element is properly the wa- the Holy Land, and the north of China. They are ter ; their game the feals. They feem to want powers very numerous in England ; but, except on a few to domefticate any animals except dogs. They are at chafes, confined in parks. None originally In Amc- enmity with all ; confider them as an objeft of chafe, rica. They are eafily tamed ; and their flefli, which and of no utihty till deprived of Hfe. The flefli of the goes by the name of venifon, is in high efteem among rein is the moft coveted part of their food; they eat it the luxurious. During rutting-timc they will contend Vox.. IV. Part I. Qj^ with ' G E R [ 306 1 C E R Ccrvus. wall each other for their miftrefs, but are lefs fierce than in dlfpofition, temperament, manners, and almofl eveiy C'ervas. "-^r-^ the ftag; during that feafon, the male will form a hole natural habit. Inftead of alTociating in herds, they in the ground, make the female lie down in it, and live in feparate families. The father, mother, and then often walk round and fmell at her. Moore fpeaks young, go together, and never mix with ftrangers. of a fpecies found on the banks of the Gambia, in the They are conftant in their amours, and never unfaith- interior parts of Africa, near Bnrracunda, called Ton- ful like the ftag. As the females generally produce cong, which he fays differed not in form from the two fawns, the one male and the other female, thefe Enj'hfh fallow-deer ; only that its fize was equal to young animals, brought up and nouriflied together, ac- that of a fmall horfe, and weighed 300 lb. It had alfo quire fo ftrong a mutual afTeilion, that they never quit on its neck an ereft black mane, four or five inches each other, unlefs one of them meets with a misfortune, long. — Mr White, in his Natural Hiftory of Pelborn, which never ought to feparate lovers. This attach- mentions, as a piece of information to naturalifts, that ment is more than love ; for though always together, if fome curious gentleman would procure the head of they feel the ardour of the rut but once a year, and it a fallow deer, and have it dilTeded, he would find it continues only fifteen days, commencing at the end of furnifhed wiih two^/r^^i^Za, or breathing-places, be- OAober, and ending before the fifteenth day of No- fides the noftrils ; probably analogous to the puni?a vember. They are not then, like the ftag, overloaded /(S-fArywa/irt in the human ht-ad. When deer are thirfty with fat : they have no ftrong fmell, no fury, in a they plunge their nofes, like fome horfes, very deep word, nothing that can change the ftate of their bodies, under water, while in the aft of drinking, and con- During this period, they indeed fufi^er not their fawns tinue them in that fituation for a confiderable time ; to remain with them. The father drives them off, as but, to obviate any inconveniency, they can open two if he meant to oblisre them to yield their place to thofe vents, one at the inner corner of each eye, having a which are to fucceed, and to form new families for communication with the nofe. This feems, as our themfelves. However, after the rutting feafon is paft, author obferves, to be an extraordinary provifion of the fawns return to their mother, and remain with her nature ; for it looks as if thefe creatures could not be fome time ; after which they feparate fur ever, and fufFocated, though their mouths and noftril-3 were both remove to a diftance from the place which gave them ftopped. This curious formation of the head, he far- birth. ther remarks, may be of fingular fervice to bcafts of The female goes with young five months and a half, chafe, by affording them free refpiration ; and no doubt and brings forth about the end of April or beginning thefe additional noftrilsare thrown open when they are of May. She produces two at a time, which ftie is hard run. Mr Pennant has obferved the fame curious obhged to conceal from the buck while very youno-. organization in the antelope. See Capra. In 10 or 12 days they acquire ftiengch fufficient to en- 6. The Capreolus, or Roe-buck, has ereft, cylindri- able them to follow her. When threatened with- cal, branched horns, and forked at the top. His fize danger, flie hides them in a cloie thicket, and, to pre- is only three feet nine inces long, two feet three inches ferve them, prefents herfelf to be chaced. But not- high before, and two feet feven inches high behind : withftanding all her care and anxiety, the young are weight from 50 to 60 lb. Though the leaft of the deer- fometimes carried off by men, dogs, or wolves, kind, his figure is moft elegant and handfome. His Poe-bucks prefer a mountainous woody country to a eyes are more brilliant and animated than thofe of the plain one. They were formerly very common in Wales, flag. His limbs are more nimble, his movements in the north of England, and in Scotland ; but at pre- qntcker, and he bounds, feemingly without effort, with fent the fpecies nowhere exifti in Great Britain except equal vigour and agihty. His coat, or hair, is always in the Scottifti highlands. In France they are more clean, fmooth, and gloffy. He never wallows in the frequent ; they are alfo found in Italy, Sweden, and mire like the ftag. He delights in dry and elevated Norway; and in Afia they are met with in Siberia, fituations, where the air is pureft. He is likewife The firft that are met with in Great Britain are in more crafty, conceals himfelf with greater addrefs, is the woods ©n the fouth fide of Loch-Rannoch, in more difficult to trace, and derives fuperior refources Perthftiire: thelaft in thofeof Longwal,on the fouthern from inftinft : for though he has the misfortune to leave borders of Caithnefs ; but they are moft numerous in behind him a ftronger fcent than the ftag, which re- the beautiful forefts of Invercauld, in the midft of the doubles the ardour and appetite of the dogs, he knows Grampian hills. They are unknown in Ireland. Wild how to withdraw himfelf from their purfult, by the roes, during fummer, feed on grafs ; and are very fond rapidity with which he begins his flight, and by his of the rubus faxatilis, called in the Highlands the roe- numerous doublings. He delays not his arts of defence buck berry ; but in the winter time, when the ground Is tdl his ftrength fails him ; but, as foon as he finds that covered with fnow, they biowfe on the tender branches the firft efforts of arapidchace have been unfuccefsful, of the fir and birch. he repeatedly returns on his former fteps; and after 7. The Guineenfis, about the fize of a cat, is of a confounding, by thefe oppofite movements, the direc- grayifti colour, and black underneath. It is a native tion he has taken, after intermixing the prefent with of Guinea, and the fize and figure of its horns have not the paft emanations from his body, he rifes from the been hitherto defcribed with any precifion. earth by a great bound, and, retiring to a fide, he lies 8. The Axis, or Speckled D^er, has flender trifur- down flat on his belly ; and in this immoveable fitua- cated horns ; the firft branch near the bafe, the fecoixt tion, he allows the whole troop of his deceived enemies near the top, each pointing upwards. This fpecies is to pafs very near him. about the fize of the fallow-deer ; of a light red co- The roe-deer differs from the ftag and fallow-deer lour j the body beautifully marked with white fpots ; along C E R [ 307 1 C E R Cervu*.' along the lower part of the fides, next the belly, is a line of white : the tail long, as that of a fallow-deer ; red above, white beneath. — They are common on the banks of the Ganges, and in theifle of Ceylon. Pliny defcribes them well among the animals of India, and adds that they were facred to Bacchus. They will bear our climate ; and have bred in the prince of Orange's menagery near the Hague. They are very tame, and have the fenfe of fmelling In an exquifite degree. They readily eat bread, but will refufe a piece that has been breathed on : many other animals of this, the antelope and goat kind, will do the fame. 9. The Porcine or Hog Deer, has flender trifurcated horns, 1 3 inches long : His body is thick and clumfy ; his legs are fine and flender : The upper part of the neck, body, and fides, are brown ; belly and rump, of a lighter colour, — They are found in Bengal ; and call- ed, from the thicknefs of their body, hog-deer. The fame fpecles is alfo found in Borneo. They are taken in fquare pit-falls, about four feet deep, covered with fome flight materials. Of their feet, as well as thofe of the lefTer fpecies of muilcs and antelopes, are made tobacco- Itoppers. 10. The Virginiana, or Virginian Deer, has flender horns, bending very much forward ; numerous branches on the interior fides; no brow antlers. It is about the fize of the Englifli fallow-deer ; of a light colour, cinereous brown. A quite diftlnCt fpecles, and pecu- liar to America. It inhabits all the provinces fouth of Canada, but in greateft abundance in the fouthern ; but efpecially the vaft favannas contiguous to the Mif- fjfippl, and the great rivers which flow Into it. They graze. In herds innumerable, along with the flags and buftaloes. This fpecies probably extends to Guiana, and is the ba'ieu of that country, which is fald to be about the fize of a European buck, with fliort horns, bending at their ends. They are capable of being made tame ; and when properly trained, are ufed by the Indians to decoy the wild deer (efpecially in the rutting feafon) within fliot. Both bucks and does herd ^from September to March ; after that they fe- parate, and the does fecrete themfelves to bring forth, and are found with difficulty. The bucks from this time keep fepai ate till the amorous feafon of Septem- ber revolves. The deer begin to feed as foon as night begins;, and fometlmes, In the rainy feafon, in the day; otherwife they feldom or never quit their haunts. An old American fportfman has remarked, that the bucks will keep In the thickets for a year, or even two. Thefe animals are very rcftlcfs, and always In motion, coming and going continually. Thofe which live near the fliores are lean and bad, fubjcct to worms in their heads and throate, geiletated from the eggs de- pofited in thofe parts. Thofe that frequent the hills and favannas are in better cafe, but the venifon is dry. In hard winters they will feed on the long mofa which hangs from the trees in the northern parts. Thefe and other cloven- footed quadrupeds of Ame- rica are very fond of fait, and refort eagerly to the places Impregnated with it. They are always fecn in great numbers in the fpots where the ground has been torn by torrents or other accidents, where they are feen licking the earth. Such fpots are called Ucking-pJaies. The huntfmen are fure of finding the game there; for notwithftanding they are often ditlurbed, the buf- faloes and deer are fo paflionately fond of the favoury regale, as to bid defiance to all danger, and return in droves to thefe favourite haunts. The deer are of the firft importance to the favages. The flflns form the greateft branch of their traffick, by which they procure from the colonifts, by way of exchange, many of the articles of life. To all of them the flefh is the principal food throughout the year ; for drying it over a gentle but clear fire, after cutting it into fmall pieces, it is not only capable of long pre- fervatlon, but is very portable in their fudden excur- fions, efpecially when reduced to powder, which is fre- quently done. Hunting is more than an amufement to thefe people. They give themfelves up to it not only for the fake of fubfillence, but to fit themfelves for war, by habitu- ating themfelves to fatigue. A good huntfman is an able warrior. Thofe who fail in the fports of the field are never fuppofed to be capable of fupporting the hardflilps of a campaign ; they are degraded to ig- noble offices, fuch as drefling the flclns of deer, and other employs allotted only to flaves and women. When a large party meditates a hunting match, which is ufually at the beginning of winter, they agree on a place of rendezvous, often 500 miles diftant from their homes, and a place peiiiaps that many of them had never been at. 1*hey have no other method of fixlna on the fpot than by pointing with their finger. The preference is given to the eldeft, as the moil experienced. When this matter is fettled, they feparate into fmall parties, travel and hunt for fubfiftence all the day, and reft at night ; but the women have no certain refting-places. The favages have their particular hunting countries ; but if they invade the limits of thofe belonging to other na- tions, feuds enfue, fatal as thofe between Percy and Douglas in the famed Chevy Chace. As foon as they arrive on the borders of the hunting coun- try (which they never fail doing to a man, be their refpeAive routes ever fo diftant or fo various), the cap- tain of the band dehneates on the bark of a tree his own figure, with a rattlefnake twined round him with diftended mouth ; and in his hand a bloody tomahawk. By this he implies a deftruftlve menace to any who are bold enough to invade their territories, or to interrupt theirdiverfion. — The chafe is carried on in different ways. Some furprife the deer by ufing the ftale of the head, horns, and hide ; but the general method is performed by the whole body. Several hundreds difperfe in a line, en- compafling a vaft fpace of country, fire the woods, and'- drive the animals into fome ftralt or peninfula, where ■ they become an eafy prey. The deer alone are not the ' objeft ; foxes, raccoons, bears, and all beafts of fur, are * thought worthy of attention, and form articles of com- merce with the Europeans. The number of deer deftroyed in fome parts of America is incredible ; as is pretended, from an abfurd idea which the lavages have, that the more they de- ftroy, the more they fliall find in fuccceding years. Certain it is that multitudes are deftroyed ; the tongues only preferved, and the carcafes left a prey to wild beafts. But the motive is much more political. The Ccrvus. 05 favages G E R I 30 Cervus favages well difcern, that ftiould they overftock the Ceffioii. rnarket, they would certainly be over- reached by the ,„- European dealers, who take care never to produce more goods than are barely fufficient for the demand of the feafon, eftabliflung- their prices according to the quantity of furs brought by the natives. CEgrus Prolans, in natural hlftory, a name given by authors to the ftag-fly, or horned beetle, a very large fpecies of beetle with horns floped, and fomething like ihofe of the liag. CERYX, in antiquity. The ceryces were a fort of public criers appointed to proclaim or publilh things :doud in affemblies. The ceryx among the Greeks an- fwered to the praco among the Romans. Our criers : '• have only a fmall part of their office and authority. There were two kinds of ceryces, chll and facred. The former were thofe appointed to call affemblies and make filence therein ; alfo to go on meffages, and do the office of our lieralds, &c. The facred ceryces were a fort of prielts, whofe office was to proclaim fi- lence in the pubhc games and facrifices, publiih the names of the conquerors, proclaim feafts, and the like. The priefthood of the ceryces was annexed to a parti- cular family, the defcendants of Ceryx, fon of Eumol- phus. To them it alfo belonged to lead folemn vic- tims to flaughter. Before the ceremonies began, they called filence in the affembly, by the formula, Eu?»y.fiTf ) waf (rw XEWf ; anfwering to the favete Unguis oi the Romans. When the fervice was over, they difmiffed the people with this formula, ^=^<^v afia-K^ Ite m'ljfa eft. CESARE, among logicians, one of the modes of the fecond figure of fyllogifms ; the minor propofition of which is an univerfal affirmative, and the other two univerfal negatives : thus, Ce No immoral books ought to be read ; Sa But every obfcene book is immoral ; Re Thei-efore no obfcene books ought to be read. CECENA, a town of Romagna in Italy, with a biffiop's fee, fubjeft to the pope, and feated on the river Savio, in E. Long. 12. 46. N. Lat. 44. 8. CESPITOSjE plants (from cefpes, turf or fod), are thofe plants which produce many Items from one root, and thence form a clofe thick carpet on the fur- face of the earth. CESFirosM Paludes, turf- bogs. CESSATION, the aft of intermitting, difcontinu- ing or interrupting the courfe of any thing, work, ac- tion, or the like. Cessation of Arms, an armiftice or occafional truce. See Truce. When the commander of a place finds things redu- ced to an extremity, fo that he mull either furrender, er facrifiee the garrifon and inhabitants to the mercy of the enemy, he plants a white flag on the breach, or beats the chamade ; on which a ceffation of arms and hoftilities commences, to give room for a capitu- lation. CESSIO BONORUM, in Scots law, the name of that aftion by which an infolvent debtor may apply for li- beration from prifon, upon making over his whole real and perfonal eftate to his creditors. CESSION, in law, an aft by which aperfon funen- ders and tranfmits to another perfon a right which belonged to bimfelfl CelBoa ia.ir;^ore particularly ufed 8 ] C E S in the civil law for a wluntary furrender of a perfon's effects to his creditors, to avoid imprifonmeat. See the article Bankrupt. In feveral places the ceffion carried with it a mark of infamy, and obliged the perfon to wear a green cup or bonnet ; at Lucca, an orange one : to negleft this was to forfeit the privileges of the ctfton. This was originally intended to fignify that the ceffionary was become poor through his own folly. The Italian lawyers defcribe the ceremony of ceffion to confift in ftriking the bare breech three times againft a ftone^ called Lapis Vituperii, in prefence of the judge. For- merly it confifted in giving up the girdles and keys in court : the ancients uling to carry at their girdles tlie chief utenfils wherewith they got their living ; as the fcrivener his efcritoire, the merchant his bag, &c. I'he form of ceffion among the ancient Gauls and Ro* mans was as follows: The ceffionary gathered up dull in his left hand from the four corners of the houfe, and Handing on the threlhold, holding the door-poll in his right hand, threw the dull back over his llioulders ; then ftripping to his Ihirt, and quitting his girdle and bags, he jumped with a pole over a hedge ; hereby letting the world know, that he had nothing left, and that when he jumped aU he was worth Avas in *the air with him. This was the ceffion iii criminal mat- ters. In civil cafes, it was fufficient to lay a broom, a fwitch, or a broken llraw, on the threfliold : this was called chrenecruda per durpillum et fejlticam. Cession, in the ccclefiallical law, is when an ec- clefiallical perfon is created a bilhop, or when a par~ fon of a parilh takes another benefice, without difpen- fation, or being otherwife qualified. In both thefe cafes their fii-ft benefices became void by ceffion, with- out any refignation ; and to thofe livings that the per- fon had, who was created bilhop, the king may pre- fent for that time, whofoever is patron of them ; and in the other cafe the patron may prefent : but by dif- penfation of retainder, a bilhop may retain fome or all": the preferments he was intitled to before he was m.ade bilhop. CESTRUM, ba STARD jasmine: A genus of the monogynia order, belonging to the pentandria clafs of plants ; and in the natural method ranking under the 28th order, Luridts. The corolla is fuimel-lhaped ;., the ftamina each fending out a little tooth about- the middle of the infide. There are fix fpecies, all of them natives of the warmell parts of America ; fo cannof be preferved in this country without artificial heat.. They are flowering Ihrubs, rifing in height from five . to twelve feet, with flov^'crs of a white, herbaceous, or ■ pale yellow colour. The flowers of one fpecies com- monly called Badmington jfafmine, have the property of fending out a Hrong fcent after funfet. They may be propagated either hj feeds or cuttings. CESTUI, a French word, fignifying he or Limy frequently ufed in the Englifli law writings. Thus, . Cijlui qui tntft, a perfon who has lands, &c. commit- ted to him' for the benefit of another ; and if fuch per- fon does not perform his trull, he is compellable to it in chancery. Cejiui qui vie, one for whofe life any lands, &c. are granted. Ce/Iui qui ufe, a perfon to whofe ufe any one is infeoffed of lands or tenements. . Formerly the feoffees to ufes were deemed owners of. tJie il eette» See 'oology' C E S [ 3 the tand, but now the pofleflion is adjudged in ce^ui qui life. CESTUS, among ancient poets, a fine embroidered girdle faid to be worn by Venus, to which Homer afcribes the power of charming and conciliating love. The word is alfo written cejium and cejlon : it comes from v-irot, a girdle, or other thing embroidered or wrought with a needle ; derived, according to Servius, fi'om y.f^Titv, pungn-e ; whence ■^{owcejlus, a term ufed at firft for any indecency by undoing tlie girdle, &c. but now reftrained to that between perfons near akin. See Incest. CI^TACEOUS, an appellation given to the fifhes of the whale kind ; the characters of which are : they have nO gills ; there is an orifice on the top of the head, through which they breathe and eje£l water ; and they have a flat or horizontal tail. Nature on this tribe hath beftowed an internal llruc- ture in all refpcfts agreeing with that of quadrupeds; and in a few others the external parts in both are fi- milar. Cetaceous fifh, hke land animals, breathe by means of lungs, being deftitute of gills. This obliges them to rife frequently on the furface of the water to refpire, to fleep on the furface, as well as to perform feveral other functions. They have the power of ut- tering founds, fuch as bellowing and making other noifes denied to genuine fifh. Like land animals they have warm blood, are furnilbed with organs of geiTera- tion, copulate, bring forth, and fuckle their young, Slowing a ftrong attachment to them. Their bodies beneath the flcin are entirely furrounded with thick layer of fat (blubber), analogous to the lard on hogs. The number of their fins never exceed three, wz. two peftoral fins, and one back fin ; but in fome fpecies the laft. is wanting. Their tails are placed horizon- tally, or flat in refpeft to their bodies ; contrary to the direction of thofe of all other fifh, which have them in a perpendicular fite. This fituation of the tail en- ables them to force themfelves fuddenly to the furface of the water to breathe, which they are fo frequently conftrained to do. Many of thefe circumflances in- duced Linnaeus to place this tribe among his mamma- lia, or what other writers call quadrupeds *. To have preferved the chain of beings entire, he fhould in this cafe have made the genus of phoca or feahy and that of the trichecus or manatl. Immediately precede the whale, thofe being the links that conneft the mammalia or quadrupeds with the fifh : for the feal is, in refpeft to its legs, the moil imperfeft of the former clafs; and in the manati the hind feet coalefce, affuming the form of a broad horizontal tail. Notwithflanding the many parts and properties which cetaceous fifh have in common with land ani- mals, yet there flill remain others which render it more natural to place them, with Ray, in the rank of fifh ; the form of their bodies agrees with that of fifh ; they are entirely naked, or covered only with afmooth llcin ; they live conftantly in the water, and have all the aftions of fifh. CETE, the name of I^innseus's feventh order of mammalia, comprehending the Mb no don, BaljEna, Physeter, and Delphinus. CETERACH, in botany, the trivial name of a fpecies of Asplenium. CETTE, a maritime town of France, in Langue- 09 ] GET doc, feated at the place where the canal of Lsngacdoc begins, between Montpellier and Agde, on the bay of Maguelona in the Mediterranean fea. E. Long. 3.15. N. Lat. 43. 25. CETUS, in aftronomy, the whale ; a large con- ftellation of the fouthern hemifphere, under Pifces, and next the water of Aquarius. The ftars in the conftel- lation Cetus, in Ptolemy's catalogue, are twenty-two ; in Tycho's twenty-one ; in Heveliiis's forty-five ; in the Britannic catalogue ninety-feven. Cetus is reprefented by the poets, as the fea-mou;- fter which Neptune, at the fuit of the nymphs, fent to devour Andromeda for the pride of her mother, and which was killed by Perfeus. In the mandible of ce- tus i« a variable ftar which appears and difappears periodically, palling through the feveral degrees of magnitude both increafing and diminifhing, in about 333 days. See Astronomy, n°45. CEVA, a ftrong town of Piedmont in Italy, feated on the river Tanero, with a fti-ong fort, in E. Long, 8. 8. N. Lat. 44. 20. CEVENNES, mountains of Languedoc in France, remarkable for the frequent meetings of the Prote- ftants there as a place of fecurlty againft the tyranny of their governors. In queen Anne's reign there was an attempt made to afTift them by an Englifh fleet in the Mediterranean; but to no purpofe, for the French had occupied the pafTages. CEUTA, a maritime town of Barbary in Africa, and in the kindom of Fez, feated on the flraits of Gibraltar, oppofite that place, in W. Long 6. 25. N. Lat. 36. 35. John king of Portugal took it from the Moors in 1415, but it now belongs to Spain. In 1697, it fuflalned a vigorous fiege by the Moors. CEYLON, a large ifland in the Eafl Indies, about 250 miles in length and 200 in breadth. It abounds in trees and fhrubs, valuable both on account of their timber and the gums or fpices they produce. Among thefe Mr Ives enumerates the euphorbium, tulip-tree, ebony, red-wood, caffia, cocoa-nut, cotton, lime, man- goe, citron, coffee ; the trees producing balfam of ca- pivi, gum gamboge, lac, and cenqmnomale. This laft is as yet unknown in Europe ; but, according to the in- formation of a Dutch furgeon, an oil or balfam is pro- duced from it by dillillation, which is of great' ufe in paralytic complaints. There is alfo another gum named badukj which has been but lately difcovered, and of which the ufe is as yet unknown. Here is alfo the black and yellow teak, the wood of which is of a mofl beautiful grain, but fo hard that the cutting of it proves very deftruftive to the carpenters tools. ^ But the moft remarkable, as well as the moft ufeful, of the vegetable produftions of Ceylon, is the cinnamon-tree, which grows wild in every wood on the fouih-weft part of the ifland. The very young trees are not fit for rinding, and the old ones are cut down for firewood. The common flowering fhrubs,, of which the whole ifland is full, fend forth a moft agreeable fi-agrance every morn- ing and evening. It abounds with high hills, between which the foil is a fat red earth ; and the valleys are extremely pleafant, having a clear rivulet running thro*' almoft every one of them. Thus the fineft fruits grow in vaft plenty, and may be had at the moft trifling rates ; a pine-apple being bought for lefs than a penny, and fo of the reft. Other provifiouo are almoft equally cheap; C E Y [ 31 Ceylon, clieap ; a dozen of fowls or five ducks being fold for a rupee, not quite half-a-crown of Englifli money. Here the Dutch fhow a polfonous fruit called by them Adam^s apple. In fliape it refembles the quarter of an apple cut out, with the two infides a little convex, and a continued ridge along the outer edges ; and is of a beautiful orange colour. Pepper, ginger, and carda- moms, are alfo produced here ; as well as live kinds of rice, which ripen one after another. Ceylon produces alfo topazes, garnets, rubies, and other precious ftones, which are difcovered by wafhing the foil wherein they grow. It has likewife ores of copper, iron, and probably of tin, with veins of black cryllal. Common deer are found in this ifland in great abun- dance, as well as Guinea-deer; but the horned cattle are botli very fmall and fcarce, fix of them weighed, all together, but 714 pounds, and one of thefe weigh- ed only 70 pounds. They have, however, the largeft and beft elephants in the world ; and their woods are infefted by tygers, the mofh terrible of all ravenous beafts. They abound alfo with fnakes of a monftrous lize, one of which has been known to dcllroy a tyger and dev'our him at one meal. Mr Ives faw one 15 feet long and 30 inches in circumference. Spiders, centipedes, and fcorpions, alfo grow here to an enor- mous fize. Our author faw a fpidcr here as large as a toad, with brown hair upon it, and legs as thick as the fhank of a large tobacco-pipe. A fcorpion, taken out of a piece of wood, was eight inches long, from bead to tail, exclufive of the claws ; the fliell was as hard as that of a crab : and our author killed a centi- pede more than feven inches long. Here the mantis or creeping leaf is met with ; which our author fup- pofes to be a fpecies of grafshopers, having every mem- ber we fee in common infeAs, though in fiiape and ap- pearance it greatly refembles a leaf. It is of a green colour. The fea-coafts abound with fifli, which are to be had very cheap. Neither harp-fliells nor ventle- traps are to be met with here : but there are abun- dance of painted cockles, and others commonly called panama Jhells, ** The natives of this ifland (fays our author) are the ftouteft Indians I ever faw. Mr Knox in lu's hi- ftory reports many ftrange things of their religion and cuftoms, none of which I had any opportunity of fee- ing. He fays ' that they have various ways of treating their dead. Some burn them, which is not uncom- mon in India ; while others throw their limbs up into the forks of trees.' This may be true, becaufe when our wood-cutters were once hewing down a ilick of timber, there fell from it the flcull and many bones of a human body ; and I alfo faw here a human body hanging on a tree. Other hiftorians relate, that the natives of Ceylon feed on human flefh ; nay, that they eat the bodies of their deceafed parents, imagining that no other fepulchre is fo fit for them as their own bowels, fince thereby they think they are changed into their own fubftance, and live again in themfelves. This fliocking cuftom is reported of the ancient Scy- thians, and poffibly might have been ufed by the inha- bitants of Ceylon, but is now in both countries entire- ly aboliihed ; and yet even at this day thefe iflanders are faid to make cups of their parents llcuUs, with a o ] C E Y view, that In midH of their mirth and jollity they may be fare to preferve a refpeilful remembrance of them." The Ceylonefe make ufe of boats hollowed out of the trunks of trees, which are about 12 or 14. feet long, but only as many inches broad witliin. The tree part in the bottom is much larger ; but when the boat, on account of the fize of the tree, is too fmall, they make a trough on the top of it fquare at both ends. Some boats, however, are much larger, being built between two trees ; and with thefe they coall along fiiore ; the others are for filliermen. It lies from E. Long. 78^ to 82°, and from N. Lat. 6^ to 10. The conqueft of this ifland was the firft attempt of Albuquerque the celebrated Portuguefe admiral. He found it well peopled, and inhabited by two different nations, the Bedas inhabiting the northern, and the C'tnglajjes who dwelt in the fouthern parts. The for- mer were very barbarous, but the latter a good deal more poliflied. Befides the advantages already men- tioned, which thefe nations derived from their mines of precious ftones, they carried on the greatefl pearl- lifhery in the Eafl. Thefe nations the Portuguefe con- quered, and tyrannized over in fuch a manner, that they affiiled the Dutch in expelling them from the ifland ; and by their united efforts this was accomplilh- ed in 1658-, after a bloody and obflinate war. All the Portuguefe fettlements fell into the hands of the Dutch Eail India company, who ftill keep pofTeffion of them, excepting a fmall diftrift on the eafteni coall without any port, from whence the fovereign of the country had his fait. Thefe fettlements formed a regular track, extending from two to twelve leagues into the inland parts of the ifland. The company have appropriated all the producStions of the ifland. The feveral articles of trade are, i. Amcthyfls, fap- phires, topazes, and rubies ; the lafl are very fmall, and very indifferent. The Moors who come from the coaft of Coi-omandel buy them, paying a moderate tax : and when they are cut, fell them at a low price in the different countries of India. 2. Pepper, which the company buy for about 4d. /»fr pound ; coffee, for which they only pay 2d. and cardamom, which has no fixed price. Thefe articles are all of an inferior qua- lity, and through the indolence of the inhabitants will never turn to any account. 3. An hundred bales of handkerchiefs, pagnes, and ginghams, of a fine red colour, which are fabricated by the Malabars at Jafra- napatan. 4. A fmall quantity of ivory, and about 50. elephants, which are carried to the coaft of Coroman- deh 5. Areca, which the company buys at about 8 s. 9d. the ammonan, and fells on the fpot at E. ij^ 13 s. t© the merchants of Bengal, Coromandel, and the MaUlives ; who give in return rice, coarfe linen, and cowries. 6. The pearl-fifliery, which was formerly, of great confequence; but is now fo much exhaufted as nut to bring in more than L. 8,750 per annum. 7. After all, the great objeft of the company is cin- namon. They purchafe the greatefl part of their cin- namon of the Indians who are fubje£l to them, and, all expences deducted, it does -not coft them above 6d. per pound. The annual expences of the colony may amount to about L. 96,250 ; their revenues and fmall branches of commerce produce only about L. 87,500. ■—This deficieacy mull be fupplied out of the pro- fits C K M [ 311 1 C H iE Chace fits arifing from the cinnamon trade ; and they are ob- regarded as the author of their royal houfe, and the Chxronsa. liged to provide for the expences of the wars in which high proteftor of their fortune ; and on the other the — — v— • they are frequently engaged with the king of Candy, banks of the Thermodon, a fmall river flowing into ' " the CephifTus, announced by the oracles of Greece as who is at prefent the fole fovereign of the ifland. Thefe are very detrimental to the interefts of the Holland- ers ; for which reafon they endeavoured to engage the good will of this monarch by fiiowing him all ima- ginable civilities. The hanaony, however, has been often interrupted. In a bloody war which terminated on the 14th of February 1766, the Ceylonefe monarch was driven from his capital, fo that the Dutch made a very advantageous treaty. Their fovereignty was acknowledged over all that part of the country they pofTefTed before the troubles broke out ; and that part of the coafts held by the natives was ceded to them. They were allowed to gather cinnamon in all the plains ; and the court was to fell them the beft fort, which is produced in the m.ountains, at the rate of L. I : 16 : I, for 18 /3. The government engaged to have no conneftion with any foreign power; and even to deliver up any Europeans who might happen to ftray into the ifland. In return for fo many concef- fions, the king was to receive annually the value of the produce of the ceded coafts ; and from thence his fubjefts wei-e to be furnifhed gratis with as much lalt as they had occaiion for. The Ceylonefe are in the moil miferable fituation: they are in a ftate of total inaftivity ; live in huts without any furniture ; and the dellined icene of defolation and woe to their un- happy country. The generals of the confederate Greeks had been much lefs careful to avail" themfelves of the powerful fanftlons of fuperftition. Unreflrained by inaufpicious facrifices, the Athenians had left their city at the exhortation of Demofthenes, to wait no other omen but the caufe of their country. Regardlefs of oracles, they afterwards advanced to the ill-fated Ther- modon, accompanied by the Thebans, and the fcanty reinforcements raifed by the iflands and ftates of Pelo- ponnefiis which had joined their alliance. Their army amounted to 30,000 men, animated by the nobleft caufe for which men can fight, but commanded by the Athenians Lyficles and Chares ; the firll but little, and the fecond unfavourably, known ; and by Theagenes the Theban, a perfon llrongly fufpeAcd of treachery : all three creatures of cabal and tools of fadlion, flaves of interell or voluptuoufnefs, whofe charafters (efpe- cially as they had been appointed to command the only ftates whofe fhame, rather than virtue, yet oppofed the public enemy) are alone fufficient to prove that Greece was ripe for ruin. When the day approached for abolifhing the totter- ing independence of thofe turbulent republics, which fubfift upon fi-uits : thofe who are the moft affluent their own internal vices, and the arms and intrigues of have no other covering than a piece of coarfe linen -wrapt about their waifl. CHACE. See Chase. CHACO, a large country of South America fitua- ted between ig^ and 37° S. Lat. It belongs to the Spaniards, by whom it was conquered in 1536. It is not natur-jJly fruitful; but abounds in gold mines, which are fo much the more valuable that thty are eahly worked. The works are carried on by about 8000 blacks, who deliver every day to their maftcrs a cer- tain quantity of gold ; and what they can colledt above this, belongs to themfelves; as weU as what they find on thofe days that are confecrated to religion and reft, upon condition that during the feftival they maintain themfelves. This enables many ef them to purchafe their Hberty ; after which they intermarry with the Spaniards. CHADCHOD, in Jewifh antiquity. Ezekiel men- tions chadchod among the feveral merchandizes which were brought to Tyre. The old interpreters, not very well knowing the meaning of this term, con- tinued it in their tranflation. St Jerom acknowledges that he could not difcover the interpretation of it. The Chaldee interprets it pearls ; others think that the onyx, ruby, carbuncle, cryflal, or diamond is meant bv it. CH^RONEA, (anc. geog.), the laft town, or rather the laft village, of Bocotia, towards Phocis ; the birthplace of Plutarch : famous for the fatal defeat of the confederate Greeks by Philip of Macedon. This place was confidered by Philip as well adapted to the operations of the Macedonian phalanx; and the ground for his encampment, and afterwards the field ol batile, were chofen with equal fagacity : having in view on _ one fide a temple of Hercules, whom the Macedonians Above a thoufand fell,, two thoufard were taken pn- Philip, had been gradually undermining for 22 years, both armies formed in battle array before the rifing of the fun. The right wing of the Macedonians was headed by Philip, who judged proper to oppofe in perfon the dangerous fury of the Athenians. His fon Alexander, only 19 years of age, but fiiiTounded by ■ experienced officers, commanded the left wini?, which faced the Sacred Band of the Thebans. The auxi- liaries of either army were pofttd in the centre. In the beginning of the aftion, the Athenians charged with impetuofity, and repelled the oppofintj divifions of the enemy ; but the youthful ardour of Alexander obliged the Thebans to retire, the Sacred Band being cut down ta a man. The activity of the young prince completed their diforder, and purfucd tire [(Mattered: multitude with his Theflalian cavalry.. Meantime the Athenian generals, too much elated by their firft advantage, loft, the opportUTrity to im- prove it ; for having repelled the centre and right wing of the Macedonians, except the phalanx, which was compofed of chofen men, and immediately commanded by the king, they, inftead of attempting to break this for-midable body by attacking it in flank, prefFed for- ward againft the fugitives, the infolcnt Lyficles ex- claiming in vain triumph, " Pur fue, my brave country- men f let us drive the cowards to Macedon." Philip ob- ferved this rafh folly with contempt ; and faying to thofe around him, *' Our enemies know not how to con- qu'.T," commanded his phalanx, by a rapid evolution, to gain an adjacent eminence, from which they poured down, firm and collefted, on the advancing Athenians, whofe confidence of fuccefs had rendered them totally infenfible to danger. But the irrefiftible fliock of^the Macedonian fpear converted their fury into defpair^ C H if. f 3 ■Toners; the reil efcaped by a precipitate and (hameful flight. Of the Thcbans more were killed than taken. Few of the confederates perifhed, as they had little lhare in the aftion, and as Philip, perceiving his vic- tory to be complete, gave orders to fpare the vanquifh- ed, with a clemency unufual in that jage, and not lefs honourable to his underttanding than his heart ; iuice his humanity thus fubdued the minds, and gained the affections, of his conquered enemies. According to the Grecian cuftom, the battle was Followed by an entertainment, at which the king pre- siding in perfon, received the congratulations of his friends, and the humble fupplications of the Athenian deputies, who craved the bodies of their flain. Their requeft, which ferved as an acknowledgment of their defeat, was readily granted ; but before they availed themfelves of the permiflion to carry off their dead, Philip, who with his natural intemperance had pio- tradlcd the entertainment till morning, iffued forth with his licentious companions to vifit the field of bat- tle ; their heads crowned with fcftive garlands, their rainds intoxicated with the infolence of wine and vic- tory ; yet the fight of the flaughtered Thebans, which firil prefented itlelf to their eyes, and particularly the facred band of friends and lovers, who lay covered with honourable wounds on the fpot where they had been drawn up to fight, brought back thefe infolent fptfta- tors to the fentiments of reafon and humanity. Phihp beheld the awful fcene with a mixture of admiration and pity ; and, after an affeding filence, denounced a folemn curfe againll thofe who bafely fufpefted the friendlhip of uch brave men to be tainted with crimi- nal and infamous paflions. But this ferious temper of mind did not laft long- ; /for having proceeded to that quarter of the field where the Athenians had fought and fallen, the king aban- doned himfelf to all the levity and littlenefs of the moft petulent joy. Inftead of being impreffeJ with a deep lenfe of his recent danger, and with dutiful gratitude to Heaven for the happinefs of his efcape and the im- portance of his viftory, Philip only compared the boaftful pretenfions with the mean performances of his Athenian enemies; and, ftruck by this contraft, re- thearfed, with the infolent mockery of a buffoon, the pompous declaration of war lately drawn up by the ar- dent patriotifm and too fanguine hopes of Demof- henes. It was on this occafion that the orator De- madco at once rebuked the folly, and flattered the am- bition, of Philip, by afl{ money and coinage were regulated j fo called from x^^'-^^^ Irafs, and S'^-n jujlice. Others fay, the money was ftrock in it ; and derive the word from ^ft^i-oi, and oi)tof, houfe. In Vi- truvius, it is ufed for the auditory of a bafihca ; in other of the ancient writers for a hall or apartment where the heathens imagined their gods to eat. CHALCIDICE, (anc. geog.) an eallern diftrift of Macedonia, ftretching northwards between the Sinus ToronjEUs and Singiticus. Formerly a part of Thrace, but invaded by PhiHp of Macedon. Named from the city Chalcis near Olynthus. CHALCIDIUri, a famous platonic philofopher in tlie third century, who wrote a commentary, which ia efteemed, on the Timasus of Plato, This work has been tranflated from the Greek into Latin. CHALCIS, a city of Chalcidice. See Chalcidice. (lanc. geog.) — Another of wEtoha, near the mouth of troj(>/dT defeSum fexus: except when a widow feigns herfelf with child in order to exclude the next heir, and a fuppofititioiis birth is fufpedled to be intended ; then, upon the writ de ventre infpiciendo, a jury of wo- men is to be impanelled to try the queftion whether with child or not. But the principal deficiency is de- feat of eftate fufficient to qualify him to be a juror, which depends upon a variety of ftatutes*. 3. Jurors • See J may be challenged /)r<3^/er etffeSium, for fufpicion h\z% ftone' s Com, or partiality. This may be either a principal chal- 3^*» lenge, or to the favour. A principal challenge is fuch, where the caufe afligned carries with it, prima facie^ evident marks of fufpicion either ;of malice or favour : as, that a juror is of kin to either party within the ninth degree ; that he has an intereft in the caufe; that there is an action depending between him and the par- ty ; that he has taken money for his verdidt, i^c. which, if true, cannot be overruled, for jurors muft be omne exceptione majores. Challenges to the favour, are where the party hath no principal challenge ; but objecils only fome probable circumftances of fufpicion, as acquaint- ance, and the like ; the vahdity of which muft be left to the determination of triors, whofe office is to decide whether the juror be favourable or unfavourable. 4, Challenges /ro/to* deliSlum, are for fome crime or mif- demeanour that affedts the juror's credit, and renders him infamous : As for a conviftion of treafon, felony, perjury, or confpiracy ; or if, for fome infamous of- fence, he hath received judgment of the pilory or the like. II. In criminal cafes, challenges may be made either on the part of the king, or on that of the priloner ; and either to the whole array, or to the feparate polls> for the very fame reafons that they may be in civil caufes. For it is here at leaft as neceffary as there, that the fheriff or returning officer be totally indiffer- ent; that, where an ahen is indidled, the jury fliould be de medietate, or half foreigners, if fo many are found in the place (which does not indeed hold in treafons, aliens being very improper judges of the breach of al- legiance ; nor yet in the cafe of Egyptians under the ftatute 22 Hen. VIII. c. 10.); that on every pannel there fhould be a competent number of hundreders ; and that the particular jurors ftiould be omni exceptione mnjores, not liable to objedlions zilhtr propter honoris re- fpeduWf C H A [3 Challenge, ^^^a^, propter defeBum, propter afeSum, or propter de- Challenges on any of the foregoing accounts are ftyled challenges for caufe; which may be without Hint in both civil and criminal trials. But in criminal cafes, or at leaft in capital ones, there is, in favorem v'tta, allowed to the prifoner an arbitrary and capricious fpecies of challenge to a certain number of juiors, without fhowing any caufe at all ; which is called a peremptory challenge : a provifion full of that tendernefs and humanity to pri- foners for which our laws are juiUy famous. This is grounded on two reafons : T. As every one muft be fenfible what fudden imprefiions and unaccountable pre- judices we are apt to conceive upon the bare looks and geftures of another ; and how neceffary it is, that a prifoner, when put to defend his life, fliould have a {rood opinion of his jury, the want of which might to- tally difconcert him ; the law wills not that he Ihould be tried by any one man againft whom he has concei- ved a prejudice even without being able to affign a rea- fon for fuch his diflike. 2^ Becaufe upon challeages for caufe fliown, if the reafon afiigned prove infuffi- cient to fet afide the juror, perhaps the bare queftion- ing his indifference may fometimes provoke a refent- ment ; to prevent all ill confequences from which, the prifoner is ilill at hberty, if he pleafes, peremptorily to fet him afide. This privilege of peremptory challenges, though granted to the prifoner, is denied to the king by the ftatute 33 Edward I. ftat. 4. which enaAs, that the king fhall challenge no jurors without affigning a caufe certain to be tried and approved by the court. How- ever, it is held that the king need not affign his caufe of challenge till all the panel is gone through, and un- kfs there cannot be a full jury without the perfons fo challenged. And then, and not fooner, the king's counfel muft fliow the caufe : otherwife the juror {hull be fworn. The peremptory challenges of the prifoner muft, however, have fome reafcfnable boundary ; otherwife he might never be tried. This reafonable boundary is fettled by the common law to the number of 35; that is, one under the number of three full juries. For the law judges, that 35 are fully fufficient to allow the moft timorous man to challenge through mere caprice; and that he who peremptorily challenges a greater number, or three full juries, has no intention to be tried at all. And therefore it deals with one who pe- remptorily challenges above ^5, and will not retradl his challenge, as with one who ftands mute or refufes his trial ; by fentencing him to the peine forte et dure in felony, and by attainting him in treafon. And fo the law ftands at this day with regard to treafon of any kind. But by ftatute 22 Hen. VIII. c. 14. (which, with regard to felonies, ftands unrepealed), no perfon arraigned for felony can be admitted to make more than 20 peremptory challenges. CHALLON-sur-Saone, an ancient town of France, in Burgundy, and capital of the Challonnois, with a citadel and bilhop's fee. It is feated on the ri- ver Saone, in E. Long. 5. 7. N. Lat. 46. 47. CHJLLONS-Sur-Marney a large epifcopal town of France, in Champagne. It carries on a confiderable tiade in flialloons, and other woollen ftuffs. It is feated 9 3 c H A between two fine meadows on the rivers Marne, Maii> Ghal oney. and Nau, in E- Long. 4. 37. N. Lat. 48.57. u— n^^— ,1 CHALONER (Sir Thomas), a ftatefman, foldier, and poet, defcended from a good family in Denbigh in Wales, was born at London, about the year 15 15. Having been educated in both univerfities, but chiefly at Cambridge, he was introduced at the court of Hen- ry VIII. who fent him abroad in the retinue of Sir Henry Knevet ambaffador to Charles V. and he had the honour to attend that monarch on his fatal expedi- tion againft Algiers in 1541. Soon after the fleet left that place, he was fliipwrecked on the coaft of Bar- bary in a very dark night : and having exhaufted hia ftrength by fwimming, he chanced to ftrike his head againft a cable, which he had the prefcnce of mind to catch hold of with his teeth ; and, with the lofs of fe- veral of them, was drawn up by , it into the ftiip to which he belonged. Mr Chaloner returned foon after to England, and was appointed firft clerk of the coun- cil, which office he held during the reft of that reign. On the acceffion of Edward VI. he became a favourite of the Duke of Somerfet, whom he attended to Scot- land, and was knighted by thai nobleman after the battle of Muflelburgh, in 1547. The protedor's fall put a ftop to Sir Thomas Chaloner's expeftations, and involved him in difficulties. During the reign of queen Mary, being a determined proteftant, he was in fome danger ; but having many powerful friends, he had the good fortune to efcape. On the acceffion of queen Ehzabeth, he appeared again at Court ; and was fo immediately diftinguiflied by her Majefty, that Ihe ap- pointed him ambaflador to the emperor Ferdinand I. being the firft ambaffador ftie nominated. His com- miffion was of great importance ; and the queen was fo well fatisfied with his conduft, that, foon after his return, ftie fent him in the fame capacity to Spain: but Sir Thomas was by no means fatisfied with this in^ ftance of her majefty's confidence : the courts of Eng- land and Spain being at this time extremely diffatisfied With each other, he forefaw that his fituation would be very difagreeable ; and fo it proved ; but Elizabeth muft be obeyed. He embarked for Spain in 1561, and returned to London in 1564, in conlequence of a requeft to his fovereign, in an elegy written in imita- tion of Ovid. After his return, he refided in a houfe built by himfelf in Clerkenwell-clofe, where he died in the year 1565, and was buried in St Paul's. Sir Wil- liam Cecil allifted as chief mourner at his funeral. So various were the talents of Sir Thomas Chaloner, that he excelled in every thing to which he apphed himfelf. He made a confiderable figure,js a poet. His poetical works were publiftied by William Malim, ma- fter of St Paul's fchool, in 1579. His capital work was that " Of reftoring the Englifti republic, in ten books," which he wrote when he was ambaflador in Spain. It is remarkable, that this gre-at man, who knew how to tranfadl as well as write upon tlie moft important affairs of ttates and kingdoms, could defcend- to compofe a diSionary for children, and to tranflate from the Latin a book Of the off,ce of Servants, merely- for the utility of the fubjefts. Chaloner (Sir Thomas) the younger, though in- confiderable as ua author, deferves to be recorded as .a fliilful naturalift, in an age. wherein natural hiftory was Z very C H A [ ChaloncrJ very little underftood in this or any other counti*}' Cham particularly as the founder of the alum- works in York and in^ (hire, which have fince proved fo exceedingly advan- tageous to the commerce of this kingdom. He was the only fon of Sir Thomas Chaloner mentioned in the laft article, and was born in the year 15^9.'' Being very young at the time of his father's death, the lord treafurer Burleif^h taking charge of his education, fent him to St Paul's fchool, -and afterwards to Magdalen college in Oxford, where, like his father, he difco- vered extraordinary talents for Latin and Engliflr poetry. About the year 1580, he made the tour of Europe, and returned to England before 1584 ; for, in that year, we find him a frequent attendant in the court of queen Elizabeth. About this time he mar- tied the daughter of Sir WilHam Fleetwood, recorder of London. 101591 he was knighted; and, fome time after, difcovered the alum-mines on his eftate at Gifborough, near the river Tees in Yorkfhire ^A). Towards the latter end of the queen's reign. Sir Thomas vifited Scotland ; and returning to England in the retinue of king James I. found fuch favour in the fight of his majelly, that he was immediately appointed governor to prince Henry, whom he conftantly at- tended, and, when his royal pupil vifited Oxford, was honoured with the degree of mafter of arts. How he was employed after the death of the prince is not known. Some years before that event, he married a fecond wife, the daughter of Mr William Blount of London, by whom he had fome children. He died in the year 1615', and was buried at Chifvvick in Middle- fex. His eldeft fon William was created a baronet in the 1 8th of James 1620. The title was extinct in 1681. He wrote, i. Dedication to Lord Burleigh of his father's poetical works, dated 1579. 2. The virtue of nitre, wherein is declared the fundry cures by the fame effected. Loud. 1584, 4to, CHALYBEAT, in medicine, an appellation given to any liquid, as wine or water, impregnated with paitjcles of iron or fteel. See Mineral Waters. CHALYBES (anc. geog.), an ancient people of the Hither Alia. Their fituation is differently aflign- ed ; Strabo placing them in Paphlagonia, to the eaft. of Synope ; ApoUonius Rhodus and Stephanus, on the eaft of the Thermodon, in Pontus ; called ffali- nones by Homer. They either gave their name to, or took it from, their iron manufaftures, (Xenophon, Val. Elaccus), their only fupport, their foil being bar- ren and ungrateful, (Dionyfius Perlegctes). CHAM, or Khan, the title given to the fovereign princes of Tartary. The wqrd, in the Perfian, fignifies mighty lord; in the Sclavonic, emperor. Sperlingins, in his Differta- tion on the Danilh term of Majejly, ioning, ling, thinks the Tartarian cbam may be well derived from it ; add- N° 68. ] G H A that Jn t'hf north they fay im, hnnen, loti^, ion* ningt &c. The term cham is alfo applied, among the Perfians, to the great lords of the court, and the go- vernors of provinces. Cham, in geography, a town of the Bavarian pala- tinate, fituated on a river of the lame name, about 25 miles north-ealtof Ratilhon; E, Long. 13. N. Lat. 49. 1^ CHAMA, in zoology, a gentts of fhell-fifh belong, ing to the order of vermes tellaceas. The fhell is thick, and has two valves; it is an animal of the oyfter kind. Linnasus enumerates i 4 fpecies, principally diftinguirti- ed by the figure of their (hells. CHAMADE, in war, y certain beat of a drum, or found of a trumpet, wb|ich is given the enemy as a fignal to inform them of fome propofition to be made to the commander, either to capitulate, to have leave to bury their dead, make a truce, or the like. — Menage derives the word from the Italian ch'iamata, of clamare to " cry." CHAM.EDRYS, in botany. See Veronica. CHAMiELEON, in zoology, the trivial name of a fpecies of Lacerta. CHAMA-PITYS, in botany. See Teucrium. CHAM^ROPS, in botany : A genus of the na- tural order of palmse. The hermaphrodite calyx is tripartite ; the corolla tripetalous ; there are fix (lami- na, three piftils, and three monofpermOus plums. The male, in a diftinft plant, the fame as the hermaphro- dite. There are two fpecies, the moft remarkable of which is the glabra, a native of the Weft Indies, and warm parts of America, alio of the correfponding la- titudes of Afia and Africa. It never rifes with a tall ftem ; but when the plants are old, their leaves are five or fix feet long, and upwards of two feet broad ; thefe fpread open like a fan, having many foldings, and at the top are deeply divided like the fingers of a hand. This plant the Americans call thatch, from the ufe to which the leaves are applied. — Under the name of pal- metto, however, Mr Adanfon defcribes a fpecies of palm which grows naturally at Senegal, whofe trunk rifes from 50 to 60 feet in height : from the upper end of the trunk ilTues a bundle of leaves,, which, in turn- ing off, form a round head ; each leaf reprefents a fan of five or fix feet in expanfion, fupported by a tail of the fame length. Of thefe trees, fome produce male flowers, which are conlequently barren ; others are fe- male, and loaded with truit, which fucceed each other uninterruptedly almoft the whole year round. The fruit of the large palmettos, Mr Adanfon affirms to be of the bignefs of an ordinary melon, but rounder : it is inveloped in two flcins as tough as leather, and as thick as ftrong parchment ; within the fruit is yellowifh, and full of filaments fattened to three large kernels in the middle. The negroes are very fond of this fruit, which, (a) Sir Thomas, during his refidence in Italy, being particularly fond of natural hiftory, fpent fome time at Puzzoli, where he was very attentive to -the art of producing alum. This attention proved infinitely ferviceable to his country, though of no great benefit to himfelf or his family, his attempt being attended with much dif- ficulty and expence. It was begun about the year t6oo, in the^reign of queen Elizabeth; but was not brought to any degree of perfeftion till fome time in the reign of Charles I. by the affiftance of one Ruflel a Walloon, and two other workmen brought from the alum-works at Rochelle. By one of the arbitrary ads of Charles, it was then deemed a mine-royal, and granted to Sir Paul Pindar. The long parliament adjudged it a mono- poly, and juftly reftored it to the original preprietors. C H A C 321 ] C H A II Chamber Ci amanim which, when baked under the afhcs, is faid to taite like a quince. , The little palmetto may be eafily raifed in this coun- try from feeds brought from America ; but, as the plants are tender, they mull be conllantly kept in a bark-ftove. CHAMANIM, in the Jewifh antiquities, is the Hebrew name for that which the Greeks call Pyrela or Pyraterta; and St Jerom in Leviticus has tranflated Simulachra, in Ifaiah, delubra. Thefe chamanim were, according to Rabbi Solomon, idols expofed to the fun upon the tops of houfes. Abenezoa fays they were portable chapels or temples made in the form of cha- riots, in honour of the fun. What the Greeks call Pyreia, were temples confecrated to the fun and fire, wherein a perpetual fire was kept up. They were built upon eminences ; and were large inclofures with- out covering, where the fun was worfhipped. The Guebres, or worfliippers of fire, in Perfia and the Eaft Indies, have ftill thefe Pyreia. The word chamanim is derived from Chaman, which fignifies to warm, or burn. CHAMARIM, a word which occurs in feveral places of the Hebrew bible, and is generally tranflated the priefis of the ichh, or the pnefts clothed in blacky be- caufe chamar fignifies " black," or " blacknefs." St Jerom, in the fecond book of Kings, renders it aru- fpices. In Hofea and Zephania, he tranflates it adi- tui or church-wardens. But the bell commentators are of opinion, that by this word we are to underftand the priells of the falfe gods, and in particular the wor- fhippers of fire ; becaufe they were, as they fay, dref- fed in black ; or perhaps the Hebrews gave them this name in derifion, becaufe, as they were continually em- ployed in taking care about the fuel, and keeping up the fire, they were always as black as fmiths or colliers. We find priefts, among thofe of Ifis, called melancphor'i ^ that is to fay, that wear black ; but whether this may be by reafon of their dreffing in black, or whether it were becaufe they wore a certain Ihining black veil in the proceiTions of this goddefs, is not certain. Ca- mar, in Arabic, fignifies the " moon." Ifis is the fame deity. Grotius thinks the Roman priefts, called cnmilli, came from the Hebrew chamarim. Thofe a- mong the heathens who facrificed to the infernal gods were dreffed in black. CHAMBER, in building, a member of a lodging, or piece of an apartment, ordinarily intended for lleep- ing in ; and called by the Latins cubicuJum. The word comes from the Latin camera ; and that, accor- ding to Nicod, from the Greek xa,«afa, vault or curve ; the term clamber being originally confined to places arched over. A complete apartment is to confift of a hall, anti- chamber, chamber, and cabinet. Privy-CHJMfiF.R. Gentlemen of the privy -chamber, are fcrvants of the king, who are to wait and attend on him and the queen at court, in their diverfions, ^c. Their number is forty-eight, under the lord-chamber- lain, twelve of whom are in quarterly waiting, and two of thefe lie in the privy-chamber. In the abfence of the lord-chamberlain, or vice-cham- berlain, they execute the king's orders : at corona- tions, two of them perfonate the dukes of Aquitain and Normandy ; and fix of them, appointed by. the Vol. IV. Part L lord-chamberlain, attend am.bafiac ors from crowned Chamber, heads to their audiences, and in public enxries. The — -'v~~-' gentlemen of the privy-chamber were inftituted by Plenry VII. Chamber, in policy, the place where certain af- femblies are held, alfo the affemblies tliemfelves. 0£ thefe fome are eftabliftied for the adminiftration of juf- tice, others for commercial affairs. Of the firft kind are, i. Star-chamber, fo called, becaufe the roof was painted with ftars ; the autho- rity, power, and jurifdi£lion of which, are abfolutely a- bolifhed by the ftatute 17 Car. I. 2. Imperial cham- ber of Spii'e, the fupreme court of judicatory in the em.pire, erefted by Maximilian I. This chamber has a right of judging by appeal ; and fs the laft refort of all civil affairs of the ftates and fubjefts of the empire^ in the fame manner as the aulic council of Vienna. Neverthelefs it is reftrained in feveral cafes : it takea no notice of matrimonial caufes, thefe being left to the pope ; nor of criminal caufes, which either belong to particular princes or towns in their refpe6live terri- tories, or are cognizable by all the ilates of the empire in a diet. By the treaty of Ofnaburg, in 1648, fifty affeffors were appointed for this chamber, whereof 24. were to be Proteftants, and 26 Catholics ; befides five prefidents, two of them Proteftants, and the reft Ca- tholics. 3. Chamber accounts, a fovereign court in France, where accounts are rendered of all the king's revenues, inventories, and avowals thereof regiftered ; oaths of fidelity taken, and other things relating to the finances tranfa£ted. There are nine in France, that of Paris is the chief ; it regifters proclamations, treaties of peace, naturalizations, titles of nobility, i3'r. All the members wear long black gowns of velvet, of fattin, or damaflc, according to their places. 4. Ec- clefiaftical chambers in France, which judge by appeal of differences about coUefting the tythes. 5. Cham- ber of audience, or grand chamber, a jurifdiftion in each parliament of France, the counfellors of which are called j-a^fwrj, or judges, as thofe of the chamber of inquefts are called raporteurs, reporters of proceffes by writing. 6. Chamber of the editt, or miparty, a court eftabliflied by virtue of the edicfh of pacification in favour of thofe of the reformed religion. This chamber is now fuppreffed. 7. Apoftolical chamber of Rome, that wherein affairs relating to the revenues of the church and the pope are tranfaftcd. This council confifts of the cardlnal-camerlingo, the gover- nor of the rota, a treafurer, an auditor, a prefident, one advocate-general, a follcitor-geheral, a commiflary, and 12 clerks. 8. Chamber of London, an apartment in Guildhall, where the city money is depofited. Of the laft fort are, the chambers of commerce; the chambers of affurance ; and the royal or fyndical chamber of bookfellers in France. I . The chamber of commerce is an affembly of mer- chants and traders, where the affairs relating to trade are treated of. . There are feveral eftablifhed in moft of the chief cities of France ; and in our own coun- try, we have lately feen chambers of this kind erefled, particularly in London, Edinburgh, and Glafgow. 2. Chamber of affurance in France, denotes a foclety of merchants and others for carrying on the bufinefs of infuring : but in Holland, it fignifies a court of juf- tice, where caufes relating to infurances are tried. S s 3. Cham- Chamber, Chamber- lain. C H A [32 3. Chamber of bookfellers in Paris, an alTembly con- fifting of a fyndic and affiftants, elefted by four dele- gates from the printers, and twelve from the book- fellers, to vifit the books imported from abroad, and to fearch the houfes of fellers of marbled paper, print- fellers, and dealers in printed paper for hangings, who are prohibited from keeping any letters proper for printing-books. In the vifitation of books, which ought to be performed by three perfons at leaft from among the fyndic and affiftants, all libels againft the honour of God and the welfare of the Hate, and all books printed either within or without the kingdom in breach of their regulations and privileges, are ftopt, even with the merchandifes that may happen to be in the bales with fuch libels or other prohibited books. The days appointed for this chamber to meet, are Tuefdays and Fridays, at two o'clock in the after- noon. Chambkr, in militaiy affairs. i. Powder-cham- ber, or bomb-chamber ; a place funk under ground for holding the powder, or bombs, where they may be out of danger, and fecured from the rain. 2. Cham- ber of a mine ; the place, moft commonly of a cubical form, where the powder is confined. 3. Chamber of a mortar ; that part of the chafe, much narrower than the reft of the cylinder, where the powder lies. It is ©f different forms ; fometimes like a reverfcd cone ; fometimes globular, with a neck for its commu- nication with the cylinder, whence it is called a bot- tled chamber ; but moft commonly cylindrical, that being the form which h found by experience to carry the ball to the greatcft diftauce. CHAMBERLAIN, an officer charged with the management and direftion of a chamber. See Cham- ber, in-psltcy. There are almoft as many kinds of chamberlains as chambers, the principal whereof are as follows. Lord CHAMBERf.AiN of Great Briiain, the fixth great officer of the crown ; to whom belongs livery and lodging in the king's court ; and thete are certain fees due to him from each arclibifhop or biPnop v/hen they perform their homage to the king, and from all peers at their creation or doing their homage. At the coronation of every king, he is to have forty ells of crlmfon velvet for his own robes. This officer, on the coronation-day, is to bring the king his ftiirt, coif, and wearing clothes ; and after the king is drefled, he claims his bed, and all the furniture of his chamber, for his fees: he alfo carries, at the coronation, the coif, gloves, and linen, to be ufed by the king on that occa- fion ; alfo the fword and fcabbard, the gold to be of- fered by the king, and the robes-royal and crown : he dreffes and undreffes the king on that day, waits on him before and after dinner, l5c. To this officer be- longs the care of providing all things in the houfe of lords, in the time of parliament ; to him alfo belongs the government of the palace of Weftminfter : he dif- pofes likewife of the fword of ftate, to, be carried be- fore the king, to what lord he pleafes.. The great chamberlain of Scotland was ranked by King Malcolm as the third great officer of the crown, and was called, Camerarius Domini Regis. Before there v/as a treafurer appointed, it, was his duty to coiledl the revenue of the crown, and he dift)urfed the money HV'Cpffary for the king's expences, and the maintenance 2 ] C H A of the king's houfehold. From, the time that a trea- furer was appointed, his province was limited to the boroughs t)*/ougliout the kingdom, where he was a fort of juftice-general, as he had a power for judging of all crimes committed within the borough, and of the crime of foreftalling. He was to hold chamber- lain-ayres every year. He was fupreme judge ; nor could any of his decrees be queftioned by any inferior judicatory. His fentences were put in execution by the magiftrates of the boroughs. He alfo regulated the prices of provifions within the borough, and the fees of the workmen in the mint-houfe. His falarv was only L. 200 a-year. The fmallnefs of his falan', and his great powers, had no doubt been the caufcs of much oppreffion in this officer, and the chamberlain- ayre was called rather a legal robbery than a court of juftice ; and when the combined lords feized king James VI. Auguft 24, 1582, and carried liim to Ruth- ven Caftle, they iffucd a proclamation in the king's name, difcharging the chamberlain-ayres to be kept. The chamberlain had gi-eat fees ariling from the pro- fits of efcheats, fines, tolb, and cuftoms. This office was granted hei-itably to the family of Stuart, duke of Lenox ; and when their male line failed, king Charles It. conferred it in like manner upon his natu- ral fon, whom he created duke of Monmouth, and on his forfeiture it went to the duke of Lenox ; but that family furrendered the office to the crown in 1703. Lord Chamberlain of the Honfiold, an officer who has the overfight and direftion of all officers belonging to tlie king's chambers, except the preclntl of the king's bed-chamber. He has the overfight of the officers of the v^^irdrobe at all his majefty's houfes, and of the removing ward- robes, or of beds, tents, revels, mufic, comedians, hinit ing, meffengers, iffc. retained in the king's fervice. He moreover has the overfight and direiStion of the fer- jeants at arms, of all phyficians, apothecaries, furgeons, barbers, the king's chaplains, ^c. and adminifters the oath to all officers above ftairs. Other chamberlains are thofe of the king's court of exchequer, of North Wales, of Chefter, of the city of London, &:c. in which cafes this officer is generally the receiver of all rents and revenues belonging to the place whereof he is chamberlain. In the exchequer there are two chamberlains, who keep a controlment of the pells of receipts and exitus, and have certain keys of the treafury, records, i^c. Chambkriain of London keeps the city money, which Is laid up in the chamber of London : he alfo prefidcs over tlie affairs of mafters and apprentices, and makes free of the city, Iffc. His office lafts only a year ; but the cuftom ufually obtains to rc-chufe the fame perfon, unlefs charged with any mifdemeanor in his office. CHAMBERLAYNE (Edward), defcended from an ancient family, was born in Glouceilerfliire 1616., and made the tour of Europe during the diftraftions of the civil war. After the reftoration, he went as fecretary with the. earl of Carlifle, who carried the or- der of the Garter to the king of Sweden ; was apj- pointed tutor to the duke of Grafton, natural fon of Charles II. and was afterwards pitched on to inftruct prince George of Denark in the Englifti tongue. He died in 1703, and was burled in a vault in Chelfea 4. church- Chamher- lain, Chamber- layne. C H A [ 3: Chamber- cKurcli-yard : his monumental infcription mentions ^^y"^ fix books of his writing ; and that he was deiirous of Chamber' doing fcrvice to pofterity, that he ordered fome copies ■ of his books to be covered with wax, and buried with him. That work by which he is beft known, is his AngUa Notiti/ei or the preftnt Jlale of England, which has been often fince printed. Chamberlayne (John), fon to the authors oiThe Prefetit State of Englanciy" and continuator of that ufe- ful work, was admitted into Trinity College, Oxford, 1685; but it doth not appear that he took any degree. Befido the Continuation jutt mentioned, he was author of " Diflertations hiftorical, critical, theological, and moral, on the moll memorable events of the Old and New Teftaments, with Chronological Tables one vol. folio ; and tranflated a variety of works from the French, Dutch, and other languages. He like- wife was F. R. S. and communicated fome pieces, inferted in the Philofophical Tranfa6lions. It was faid of him that he underftood fixteen languages ; but it is certain that he was mafter of the Greek, Latin, French, High and Low Dutch, Portuguefe, and Italian. Though he was qualified for employment, he had none but that of Gentleman-Ufher to George Prince of Denmark. After a ufeful and well-fpent life, he died in the year 1724. He was a very pious and good man, and earnell in promoting the advancement of re- ligion, and the intereft of true Chriflianity ; for which purpofe he kept a large corfefpondence abroad. CHAMBERRY, a confiderable and populous town of Italy, in Savoy, with a caftle. It is capital of the duchy, and well built, but has no fortifications. It is watered by feveral ftreams, which have their fources in )St Martin's-hill, and run through feveral of the ftreets. There are piazzas under mod part of the houfes, where people may walk dry in the worfi: wea- ther. It hath large and handfome fuburbs ; and in the centre of the town is the royal palace. The par- liament meet here, which is compofed of four prefi- dents, and a pretty large number of fenators, being the fupreme tribunal of the whole duchy. The prin- cipal church is St Leger, and the Jefuits college is the moft magnificent of all the monalleries. E. Long. 5. 50. N. Lat. 45. 35. CHAMBERS (David), a Scots hiftorlan, prieft, and lawyer, was born in the (hire of Rofs, about the year 1530, and educated in the univerfity of Aber- their courfe of life, as being in the mercantile way, the import of the name Canaan; and for which their fituation was greatly adapted, they living on the fea; and about Jordan, and thus occupying the greater part of the Land of Promife. CHANCE, a term we apply to events> to denote- that they happen without. any neceffary or foreknown caufe. See Cause. Our aim is, to afcrlbe thofe things to chance, which are not neceffarlly produced as the natural effefts of any proper caufe : but our Ignorance and precipitancy lead us to attribute effefts to chancei, which have a ne- ceffary and determinate caufe. When we fay a thing happens ly chance, we really mean no more than that its caufe is unknown to us : not, as fome vainly imagine, that chance itfelf can be the caufe of any thing. The cafe of the painter, who, unable to exprefs the foam at the mouth of a horfe he- had painted, threw his fponge in defpair at the piece, and, hy chance, , that which he could not before do by de- fign, is an eminent inftance of the force of chance ; yetj it is obvioua, all we here mean by chance, is, that the painter was not aware of the effcft ; or that he did not throw the fponge vvith fuch a view : not but that he aftually did every thing neceffary to produce the . effcd ; infomuch, , that, confidering the direftion whereio- ■. C H A [ 32 wherein he threw his fponge, together with its form, fpecific gravity, the colours wherewith it was fmcared, and the diftance of the hand from the piece, it was im- poflible, on the prefent fyftem of things, the effe£l fhould not follow. Chance is frequently perfonified, and erefted into a chimerical being, whom we conceive as afting arbitra- rily, and producing all the effefts whofe real caufes do not appear to us : in which fenfe the word coincides with the "^^X""^ fortuna, of the ancients. Chance is alfo ufed for the manner of deciding things, the conduftor diredlion whereof is left at large, and not reducible to any determinate rules or meafures; or where there is no ground for preference: as at cards, dice, lotteries, &c. For the Laws of Chance, or the Proportion of Hazard in Gaming, fee Game. The ancient fortilege, or chance, M. Placette obferves, was inftituted by God himfelf ; and in the Old Tefta- ment we find feveral {landing laws and exprefs com- mands which prefcribed its ufe on certain occafions : hence the Scripture fays, " The lot, or chance, fell on Matthias," when it was in queftion who fhould fill Ju- das's place in the apoftolate. Hence alfo arofe the fortes fanSorum; or method of determining things, among the ancient Chrlilians, by opening fome of the facred books, and pitching on the firft verfe they caft their eye on, as a fure prognoftic of what was to befal them. The fortes Homerica, Vir- .giliana, Pranejiintz, ;&c. ufed by the heathens, were with the fame view, and in the fame manner. See SORTES. St Auguftin feems to approve of this method of de- termining things future, and owns that he had pradlifed it himfelf; grounded on this fuppofition, that God pre- fides over chance; and on Prov. xvi. 33. Many among the modern divines hold chance to be conduced in a particular manner by Providence ; and elleem it an extraordinary way which God ufes to dtclare his will, and a kind of immediate revela- tion. Ch AN c.K- Medley, in law, is where one is doing a lawful aft, and a perfon is killed by chance thereby ; for If the aft be unlawful, it is felony. If a perfon caft, not intending harm, a ftone, which happens to hit one, whereof he dies ; or fhoots an arrow in an highway, and another that p-jfleth by is killed there- with ; or if a workman, in throwing down rubbifh from a houfe after warning to take care, kills a perfon ; or a fchoolmafter in correfting his fcholar, a mafter his fervant, or an officer in whipping a criminal in a reafonable manner, happens to occafion his death ; it is chance-medley and mifadventure.. But if a man throw ftones in a highway where perfons ufaally pafs ; or fhoot an arrow, &c. In a market-place among a great many people ; or if a workman caft down rub- bifli from a houfe in cities and towns where people are continually palling ; or a fchoolmafter, &c. corredl his fervant or fcholar. Sec. exceeding the bounds of moderation ; It is manflaughter : and if with an im- proper inftrument of correction, as with a fword or iron bar, or by kicking, ftamping, &c. in a cruel manner, it is murder. If a man whips his horfe in a ftreet to make him gallop, and the horfe runs over a child and killsit, it is manflaughter: but if another whips N° 69. 8 ] G H A the horfe, it Is manflaughter in him, and chance-medley Ch3Rce|, in the rlder.^ And if two are fighting, and a third ^l^j^^'*^^' perfon coming to part them is killed by one of them j without any evil intent, yet this is murder in him, and not manflaughter by chance medley or mifadventure. In chance-medley, the offender forfeits his goods; but hath a pardon of courfe. CHANCEL, Is properly that part of the choir of a church, between the alcar or communion-table and the baluftrade or rail that inclofes it, where the minifter Is placed at the celebration of the communion. The word comes from the Latin canceUus, which in the lower Latin is ufed in the fame fenfe, from cancelli, " lattices or crofs bars," wherewith the chancels were anciently encompaffed, as they now are with rails. The right of a feat and a fepulchre in the chancels is one of the privileges of founders. CHANCELLOR, was at firft. only a chief notary or fcribe under the emperors ; and was called cancellu' rius, becaufe. he fat behind a lattice (in Latin cancel- lus) to avoid being crowded by the people: though fome derive the word from cancellare, " to cancel" (See Chancery). This officer was aftervi^ards inveited with feveral judicial powers, and a general fuperinten- dency over the reft of the officers of the prince. From the Roman empire it pafTed to the Roman church* ever emulous of imperial ftate : and hence every bifliop has to this day his chancellor, the principal judge of his confiftory. And when the modern kingdoms ot Europe were eftabliftied upon the ruins of the empire, almoft every ftate preferved its chancellor with diflFer- ent jurifdiftlons and dignities, according to their dif- ferent conftltutlons. But In all of them he feems to have had the fupervifion of all charters, letters, and fuch other public inftruments of the crown as were authen- ticated in the moft folemn manner : and therefore, when feals came in ufe, he had always the cuftody of the king's great fcal. Lord High Chancellor of Great Britain, or Lord Keeper of the Great Seal, is the higheft honour of the long robe, being created by the mere delivery of the king's great feal into his cuftody ; whereby he be- comes, without writ or patent, an officer of the greatell weight and power of any now fubfifting in the kingdom- He is a privy couniellor by his office ; and, according to Lord Chancellor EUefmere, prolocutor of the houie of lords by prtfcrlption. To him belongs the appoint- ment of all the juftices of the peace throughout the kir.^dom. Being In former times commonly an eccle- fiaftic (for none elle were then capable of an office fo converfant in writing), and prefiding over the royal chapel, he became keeper of the king's confcience ; vifitor, in right of the king, of all hofpitals and col- leges of the king's foundation ; and patron of ail the king's livings under the value of L. 20 per annum in the king'ti books. He is the general guardian of all in- fants, Ideots, and lunatics ; and has the general fupcr- intendanc* of all charitable ufes in the kingdom. And all this over and above the vaft extenfive juriidiction which he exerciies in his judicial capacity in the court of chancery. Pie takes precedence of every temporal lord except the i-oyal family, and of all others except the archbifliop of Canterbury. See Chancery. Chancellor, in Scotland, waa the chief in matters of juttice. In the laws of King Malcolm 11. he is placed C H A [3 • placed before all other officers ; and from thefc it ap- pears, that he had the principal direftion of the Chan- cery, or Chancellary as it is called, which is his proper cfRce. He had the cuftody of the king's feal ; and he was the king's moft intimate counfellor, as appears by' an old law cited by Sir James Balfour : The chan- cellar fall at al tymes aflift the king, in giving him counfall mhir fecretly nor the reft of the nobihty, to quais ordinances all officiarls, als well of the realme as of the kingis hous, fould anfwer and obey. The chan- cellar fall be liidgit neir unto the kingis grace, for keiping of his bodie, and the fcill ; and that he may be readie baith day and nicht at the kingis command." By having the cuftody of the great feal, he had an opportunity of examining the king's grants and other deeds which were to pafs under it, and to cancel them if they appeared againft law, and were obtained fur- reptitioufly or by falfe fuggeftions. King James VI. ordained the chancellor to have the firft place and rank in the nation, ratione officii; by virtue whereof he prellded in the parliament, and in all courts of judicature. After the reiloration of King Charles II. by a particular declaratory law, parliament firft, the lord chancellor was declared, by virtue and right of his office, prefident in all the meetings of parliament, or other public judicatures of the kingdom. Although this a6t was made to declare the cliancellor prefident of the exchequer as well as other courts, yet in 1663 the king declared the treafurer to be prefident of that court. The ofiice of lord chancellor was abolifhed by the Union, there being no farther ufe for the judicial part of this ofRce ; and, to anfwer all the other parts of the chancellor's ofike, a lord keeper of the great feal was erefted, with a falary of L. 3000 a-year. Chancellor of a Cathedral, an officer that hears lelTons and lectures read in the church, either by him- felf or his vicar ; to corre£l and fct right the reader when he reads amifs ; to infpeft fchools ; to hear caufes ; apply the feal ; write and difpatch the letters of the chapter ; keep the books ; take care that there be frequent preachings, both in the church and out of it ; and affign the office of preaching to whom he pleafes. Chancellor of the Duchy of Lancajler, an officer ap- pointed chiefly to determine controvcrlies between the king and his tenants of the duchy-land, and otherwife to dired all the king's affairs belonging to that court. See DucHY-Court. Chancellor of the Exchequer, an officer who prefides in that court, and takes care of the intcreft of the crown. He is always in commiffion with the lord- ireafurer, for the letting of c! own-lands, &c. and has power, with others, to compound for forfeitures of lands upon penal ilatutes. He has alio great authority in managing the royal revenues, and In matters relating to the firft-fruits. Chancellor of the Order of the Garter, and other Mi- litary Orders, is an officer who feals the commifhons and mandates of the chapter and affembly of the knights, keeps the regifter of their proceedings, and delivers ads thereof under the feal of their order. ^ Chancellor of an Univerfity, is he who feals the diplomas, or letters of degrees, proviiion, &c. given in the unlverfity. Vol. IV. Part I. 29 1 C H A The chancellor of Oxford Is ufuallyoneof the prime Chancello nobility, chofen by the ftudents themielves in convo- ^, cation. He is their chief magiftrate ; his office is, durante vita, to govern the imiverfity, preferve and defend its rights and privileges, convoke affemblies, and do juflice among the members under his jurifdic- tion. Under the chancellor is the vice-chancellor, who is chofen annually, being nominated by the chancellor, and eleded by the unlverfity in convocation. He is always the head of fome college, and in holy orders. Hid proper office is to execute the chancellor's power, to govern the univerfity according to her flatutes, to fee that officers and ftudents do their duty, that courts be duly called, &c. When he enters upon his office, he choofes four pro-vice-chancellors out of the heads of the colleges, to execute his power in his abfence. The chancellor of Cambridge is alfo ufually one of the prime nobility, and in moft refpe6ts the fame as that in Oxford; only he does not hold his office duran- te vita, but may be eleded every three years. Under the chancellor there is a commiflary, who^ holds a court of record for all privileged perfons and fcholars under the degree of maftcr of arts, where all caufes are tried and determined by the civil and itacute law, and by the cuftom of the unlverfity. The vice-chancellor of Cambridge is chofen annually by the fenate, out of two perfons nominated by the heads of the feveral colleges and halls. Chancellor's Court. See Unifersity- Courts. CHANCERON, in natural hlft ory, a name given by the French writers to the fmall caterpillar that eats the corn, and does vaft mifchief in their granaries. See the article CoRN-Butterjly. *• CHANCERY, thefiigheft court of juftlce in Britain next to the parliament, and of very ancient inftitution. It has Its name chancery ( canccUaria) from the judge*- who prefides here, the lord chancellor, or caiicellarius ; who, according to Sir Edward Coke, is fo termed a cancellando, from cancelling the king's letters patent when granted contrary to law, which Is the higheft point of his jurlfdidion. In chancery there are two diftindt tribunals : the one ordinary-, being a court of common law ; the other extraordinary, being a court of equity. I. The ordinary legal court holds pleas of recogni- zances acknowledged in the chancery, writs oi fcire facias, for repeal of letters patent, writs of partition, &c. and alfo of all perfonal adions by or againft any officer of the court. Sometimes a fupcrfdeas, or writ Blackji. of privilege, hath been here granted to difcharge a Comment. perfon out of prifon ; one from hence may have a ha> heas corpus prohibition, &c. in the vacation ; and here a fiilpcena may be had to force wltneffes to appear in other courts, when they have no power to call them. But, in profecuting caufes, if the parties defcend to iffue, Ihls court cannot try It by jury; but the lord chancellor dehvers the record Into the king's bench to be tried there ; and after trial had, it is to be remand- ed into the chancery, and there judgment given : tho' if there be a demurrer in law, it fhaU be argued in this court. In this court is alfo kept the ojicina juflitie; out of which all origmal writs that pafs under the great feal, •ail commiffiona of charitable ufes, fewers, bankruptcy, T t idiocy, C H A [ 33 Chancery. Jdlocy, lanacy, and the like, do ilTue ; and for which """T"^ it is always open to the fubjed, who may there at any time demand and have, ex debito jujiitid;, any writ that his occafions may call for. Thefe writs, relating to the bufmefs of the fubjiift, and the returns of them, were, according to the fimphcity of ancient times, originally kept in a hamper, in hanaperio; and the others (rela- ting to fuch matters wherein the crown is mediately or immediately concerned) were preferved in a httle fack or bag, in parva haga: and hence hath arifen the di- ftinftion of the hanaper ©fiice, and the petty-lag of- fice, which both belong to the common law-xourt in chancery. 2. The extraordinary court, or court of equity, pro- ceeds by the rules of equity and confcience ; and mo- derates the rigour of the common law, confidering the intention rather than the luords of the law. It gives relief for and againll infants notwithftanding their mi- nority, and for and againft married women notwith- ftanding their coverture. All frauds and deceits for which there is no redrefs at common law; all breaches of truft and confidence; and accidents, as to relieve obligors, mortgagers, &c. againft penakies and forfei- tures, where the intent was to pay the debt, are here remedied : for in chancery, a forfeiture, &c. fhall not bind, where a thing may be done after or compenfa- tion made for it. Alfo this court will ^ive rehef againft the extremity of unreafonable engagements entered into without confideration ; oblige creditors that are unreafonable to compound with an unfortunate debt- or ; and make executors, &c. give fecurity and pay intereft for money that is to lie long in their hands. This court may confirm title to lands, though one hath loft his writings ; and render conveyances, defeftive through miftake, &c. good and perfeft. In chancery, copy- holders may be relieved againft the ill ufage of their lords ; inclofures of lands that are common be decreed ; and this court may decree money or lands given to charitable ufes, obhge men to account with each other, &c. But in all cafes wliere the plaintiff can have his remedy at law, he ought not to be reheved in chancery; and a thing which may be tried by a jury is not triable in this court. The proceedings in chancery are, firft to file the bill of complaint, figntd by fome counfel, fetting forth the fraud or injury done,- or wrong fuftained, and praying relief: after the bill is filed, procefs oifubpcena iffues to fompel the defendant to appear; and when the defen- dant appears, he puts in his anfwer to the bill of com- plaint, if there be no caufe for the plea to the jurifdic- tion of the court, in difabiHty of the perfon, or in bar, &c. Then the plaintiff brings his rephcation, un- kfs he files exceptions againft the anfwer as infufficient, referring it to a mafter to report whether it be fufficient or not; to which report exceptions may alfo be made. The anfwer, replication, rejoinder, &c. being fettled, and the parties come to ilTue, witnelTes are to be exa- mined upon interrogatories, either in court or by com- miffion in the country, wherein the parties ufually join; and when the plaintiff" and defendant have examined their witnefles, publication is to be made of the de- pofitions, and the caufe is to be fet down for hearing ; after which follows the decree. But it is now ufual to appeal to the houfe of lords ; which appeals are to be figned by two noted counfel, and exhibited by way I o ] C H A of petition ; the petition or appeal is lodged with the ChandJier clerk of the houfe of lords, and read in tlie houfc, () whereon the appellee is ordered to put in his anfwer, ^l^andler. and a day fixed for hearing the caufe; and after coun- ^ fel heard, and evidence given on both fides, the lofds will affirm or reverfe the decree of the chancery, and finally determine the caufe by a majority of votes, &c. CHANDELIER, in fortification, a kind of move- able parapet, confifting of a wooden frame, made of two upright ftakes, about fix feet high, with crofs planks between them ; ferving to fupport faicines lo cover the pioneers. CHANDERNAGORE, a French fettlement in the kingdom of Bengal in the Eaft Indies. It lies on the river Ganges, two leagues and a half above Calcutta. The diftrift is hardly a league in circumference, and has the difadvantage of being fomewhat expofed on the weftern fide ; but its harbour is excellent, and the air is as pure as it can be on the banks of the Ganges. When- ever any building is undertaken that requires ftrength, it muft here, as well as in all other parts of Bengal, be built upon piles ; it being impoffible to dig three or four feet without coming at water. CHANDLER (Mary), diftinguifhed by her talent for poetry, was the daughter of a diffenting miniftcr at Bath ; and was born at Malmfbury in Wiltfhire in 1687. She was bred a milliner ; but from her child- hood had a turn for poetry, and in her riper years ap- plied herfelf to the ftudy of the poets. Her poems, for which ftie was comphmented by Mr Pope, breathe the fpirit of piety and philofophy. She had the mis- fortune to be deformed, which determined her to live fingle ; though flie had great fweetnefs of counte- nance, and was fohcited to marry. She died in 1 745, aged 58. Chandler (Dr Samuel), a learned and refpe£table diffenting minifter, defcended from anceftors lieartily engaged in the caufe of religious liberty, and fufferers for the fake of confcience and nonconformity ; was born at Hungerford in Berks, where his father was a minifler of confiderable worth and abilities. Being by his literary turn deftined to the miniftry, he was firft placed at an academy at Bridgewater, and from thence removed to Gloucefler under Mr Samuel Jones. A- mong the pupils of Mr Jones were Mr Jofeph Butler, afterv^ards bifhop of Durham, and Mr Thomas Seeker, afterwards archbifliop of Canterbury. With thefe emi- nent perfons he contradled a friendlhip that continued to the end of their hves, notwithllanding the different views by which their conduft was afterwards direfted, and the different fituations in which they were placed. Mr Chandler having finifhed his academical ftudics, began to preach about July 1714; and being foon di- ftinguifhed by his talents in the pulpit, he was chofen in 1716 minifter of the Preft)yterian congregation at Peckham near London, in which ftation he continued fome years. Here he entered in the matrimonial ftate, and began to have an increafing family, when, by the fatal South-fea fcheme of 1720, he unfortunately loft: the whole fortune which he had received with his wife. His circumftances being thereby embarraffed, and his income as a minifter being inadequate to his expences, he engaged in the trade of a bookfeller, and kept a' fhop in the Poultry, London, for about two or three yearsj. C H A [ 331 1 C H A Chandler, years, ftill continuing to difcharge the duties of the '~~v~-~ padoral office. He alio officiated as joint preacher with the learned Dr Lardner of a winter weekly evening lefture at the meeting- houfe in the Old Jewry, London : in which meeting he was eftabliflicd affillant preacher about the year 1725, and then as the pallor. Here he miniftered to the religious improvement of a very rcfpeftable congregation for 40 years with the greateft applaufe ; and with what diligence and application he improved the vacancies of time from his paitoral duties, for improving himfelf and benefiting the world, will appear from his many writings on a variety of import- ant fubjefts. While he was thus laudably employed, not only the univerfities of Edinburgh and Aberdeen gave him, without any application, teftlmonies of their eiteem in diplomas, conferring on him the degree of D. D. but he alfo received offers of preferment from fome of the governors of the eftablifiied church, which he nobly declined. He had hkewife the honour of be- ■ing afterwards elected F. R. and A. SS. On the death of George II. in 1760, Dr Chandler publifhed a fermon on that event, in which he compa- red that prince to King David. This gave rife to a pamphlet, which was printed in the year 1761, intitled " The Hiftory of the Man after God's own Heart ;" ■^vherein the author ventured to exhibit King David as an example of perfidy, luft, and cruelty, fit only to be ranked with a Nero or a Caligula ; and complained of the infult that had been offered to the memory of the late Britifh monarch by Dr Chandler's parallel between him and the king of Ifrael. This attack occafioned Dr Chandler to publlfh in the following year " A Re- view of the Hiftory of the Man after God's own Heart; in which the Falfehoods and Mifreprefcntations of the Hiftorian are expofed and corrected." He alfo pre- pared for the prefs a more elaborate work, which was afterwards publifhed in two volumes 8vo, under the fol- lowing title : " A Critical Hiftory of the Life of Da- vid : in which the principal Events are ranged in Or- der of time ; the chief Objeillons of Mr Bayle and others agalnfl the Charafter of this Prince, and the Scripture Account of him, and the Occurrences of his Reign, are examined and refuted ; and the Pfalms which refer to him explained." As this was the laft, it was iikewife one of the beft, of Dr Chandler's produftions. The greateft part of this work was printed off at the time of our author's death, wliich happened May 8th 1766, aged 73. During the laft year of his life, he was vifited with frequent returns of a very painful dlfor- der, which he endured with great refignation and Chri- ftian fortitude. He was interred in the burying-ground at Bunhill-fields on the 1 6th of the month ; and his funeral was very honourably attended by miniflers and other gentlemen. He exprefsly defired, by his laft will, that no delineation of hi«'charafter might be given in his funeral fermon, which was preached by Dr Amory. He had feveral children ; two fons and a daughter who died before him, and three daughters who furvived him ; two of whom are yet living, and both married, one of them to the Rev. Dr Harwood. Dr Chandler was a man of very extenfive learning and eminent abilities ; his apprehenfion was quick and his judgment penetrating ; he had a warm and vigorous ima- gination ; he was a very inftruftive and animated preach- tong. er; and his talents in the pulpit and as a writer procured Chandler, him very great and general eftcem, not only among the ^^"^"8" diffenters, but among large numbers of the eftabllfhed church. He was principally inftruraental in the eflablifh- ment of the fund for relieving the widows and orphans of poor Proteftant dlffenting minifters : the plan of It was firft formed by him ; and it was by his intereft and application to his friends that many of the fubfcripcions for its fupport were procured. In 1768, four volumes of our author's fermons were publifhed by Dr Amory, according to his own direc- tions in his laft will ; to which was prefixed a neat engraving of him, from an excellent portrait by Mr Chamberlin. He alfo expreffed a defire to have fome of his principal pieces reprinted in four volumes 8vo : propofals were accordingly publifhed for that purpofe, but did not meet with.fufficient encouragement. But in 1777, another work of our author was publifhed in one volume 4to, under the following title : " A Para- phrafe and Notes on the Epiftles of St Paul to the Galatlans and Ephefians, with dodlrinal and praftical Obfervations : together with a critical and practical Commentary on the two Epiftles of St Paul to the ThefTalonlans," Dr Chandler alfo left, in his inter- leaved Bible, a large number of critical notes, chiefly in Latin, which are now the property of Dr KIppIs, Mr Farmer, Dr Price, and Dr Savage, and which have been intended to be publifhed ; but the defign has not yet been executed. A complete lift of Dr Chand- ler's works is given in the Biographia Britannica, vol. III. p. 435. CHANG-TONG, a province of China, bounded on the eaft by Petcheli and part of Honan, on the fouth by Kiang-nan, on the eaft by the fea, and on the north by the fea and part of Petcheli. The country is well watered by lakes, ftreams, and rivers ; but Is neverthelefs liable to fuffer from drought, as rain falls here but feldom. The locufts alfo fometimes make great devaftation. However, it abounds greatly iu game ; and ther-e is perhaps no country where quails, parti-Idges, and pheafants, ai-e fold cheaper, the in- habitants of this province being reckoned the keeneft fportfmen in the empire. The province is greatly en- riched by the river Yun, called the Grand Imperial Ca- nal, through which all the barks bound to Pekin mufl pafs in their way thither. The duties on this canal alone amount to more than L. 450,000 annually. The canal itfelf is greatly admii-ed by European travellers on account of its ftrong and long dikes, the banks de- corated with cut ftone, the ingenious mechanifm of its locks, and the great number of natural obftacles which have been overcome in the execution of the work.— . The province produces filk of the ordinary kind ; and, befides this, another from a fort of infeft refembling our caterpillar. It is coarfer than the ordinary filk, but much ftronger and more durable ; fo that the ftuffs made from it have a very extenfive fale throughout the empire. Chang- tong is remarkable for being the birth-place of the celebrated philofopher and lawgiver Confucius. His native city is called Kio-feou, where there are fe- vei-al monuments erefted in honour of this great man. The province is divided into fix diftridls, which con- tain fix cities of the firft clafs, and 114 of the fecond T t 2 and C H A [ 33 and third. Along the coaft, alfo, are 15 or 16 vil- lages of confiderable iinportancc on account of their commerce ; there are likewile a number of fmall iflands, moft of which have harbours very convenient for the Chiuefe junks which pafs from tlience to Corea or Lea- tong. 7.''he mod remarkable cities are, i. Tfi-nan-fou, the capital, which ftands fouth of the river Thr.gho or Tfi. It is large and populous ; but chiefly celebrated for having been the refidence of a long feries of kings, whofe tombs, rifing on the neighbouring mountains, afford 3 beautiful profpeft. 2. Yen-tcheu-fou, the fe- cond city of the province, fituated between two rivers, and in a mild and temperate climate. Great quanti- ties of gold are faid to have been- formerly collefted in its neighbourhood. 3. Lin-i9in-tchen, fituated on the great canal, is much frequented by fhips, and may be called a general magazine for every kind of merchan- dife. Here is an octagonal tower, divided into eieht ftories, the walls of which are covered on the outfide with porcelain loaded with various figures neatly exe- cuted, and encrufted on the inlide witli varioufly co- loured fTiarble. A ilaircale, conftrufted in the wall, condu6^s to all the ilories, from which there are paf- fages that lead into magnificent galleries ornamented with gilt bailuftrades. All the cornices and projefttons of the tower are fyrnlfhed with little bells; which, fays Mr Grofier, when agitated by the wind, form a very agreeable harmony. In the higheit ilory is an idol of gilt copper, to which the tower is dedicated. In the neighbourhood are' fome other temples, the architecture of which is exceedingly beautiful. CHANGER, an officer belonging to the king's mint, who changes money for gold or filver bullion. See Mint. Motiey-CHANGF.R, is a banker who deals in the exchange, receipt, and payment, of moneys. See Banker. CHANGES, in arithmetic, &c. the permutations or variations of any number of quantities ; with regard to their pofition, order, &c. See Combination. To Jind all the pojjible Changes of any Number of ^tantitles, or hoiv oft their Orckr may be varied.^ Sup- pofe two quantities a and b. Since they may be ei- ther wrote a b ox b a, it is evident their changes are 2 = 2.1. Suppofe three qxiantities a b c : their changes will be as in the margin; as is evident by com- c a b bining rfirft with ab, then with ba; and hence acb the number of changes arifes 3. 2. 1—6. If a b c the quantities be 4, each may be combined four ways with each order of the other three ; e b a whence the number of changes arifes 6. 4 = 4. be a 3. 2. I. = 24. Wherefore, if the number of i a 4: quantities be fuppofed n, the number of changes will be n,n — i .n — 2.n~ ^.n — /\..iffc. If the fame quantity occur twice, the changes of two will be found h b; of three, bab, abb, b b c; of four, c bab, be ab, h ab c. And thus the number of changes in the firlt cafe will be 1 1= (2. I ) : 2. ly in thefecond, 3=^ (3. 2. 1) : 2. I : in the third, 1 2 = (4. 3. 2. i ) : 2. i. If a fifth letter be added, in each feries of lour quan- tities, it will beget hve changes, whence the number ©f all the changes will be 60= (5. 4. 3. 2.) i,:2. i. Hence if the number of quantities be «, the number o f changes will be Uim — i,n — 2.« — 3.K. — 4. Siff.): 2. 1. ] C H A II channel. From thefe fpccial formulas may be collefted a general Charge? one, viz. if n be the number of quantities, and m the number which fhows how oft the fame quantity occurs; we fliall have {n.n — i./z — z.n — 3.^ — 4.« — ^.n — 6. n — 7.72 — 8.W — 9. l^cJ): m — \,m — 2.m — T^.m — 4. Sff^:.) the feries being to be continued, till the continual fubtraftion of unity from n and m leave o. After the fame manner we may proceed fuilher, till putting n. for the number of quantities, and /, m., r, &c. for the number that fliows how oft any of them is repeated, we arrive at an univerfal form, [n.n — i.n — i.n — 3. ti — 4.« — ^.n ~6.n — y.w — 8. l^c): (U — 1./—2J — 3. / — 4./ — 5. iffc. m.m — i.m — 2.m — 3. izic. r.r — i.r — 2. r — 3./"-— 4.r — 5". l^c. Suppofe, forinftance, «— 6, r~o. The number of changes will be (6. 5. 4. 3. 2. I.) : (3. 2. i. 3. 2. i.) = (6. 5.4.): (3. 2 = 2. 5. 2 = 20). Hence, luppofe thirteen perfons at a table, if it be required how oft they may change places ; w-e fhall find the number 13. j 2. 11. 10. 9. 8. 7. 6. 5. 4.3.2.1. = 6227020800. In this manner may all the poffible anagrams of any word be found in all languages, and that without any ftudy : iuppofe v. g. it were required to find the ana- grams of the worr, pro- perly fignities a fort of hood or covering of the head anciently worn both by men and women, the nobles and the populace, and afterwards appropriated^to the doftors, and licentiates in colleges, &c. Hence the name paffed to certain little fhields, and other funeral devices, placed on the foreheads of the horfes that drew the hearfcs in pompous funerals, and which are ftill called chaperoons, or Jhafferoons ; becaufe fuch de- vices were originally faftencd on the chaperonnes, or hoods, worn by thofe horfes with their other coverings of ftate. Chaperon of a bit-mouth, in the manege, is only ufed for fcatch-mouths, and all others that are not cannon- mouths, fignifying the end of the bit that joins to the branch juft by the banquet. In fcatch-mouths the chaperon is round, but in others it is oval: and the fame part that in fcatch and other mouths is cal- led chaperon, is in cannon-mouths called fronceau. CHAPITERS, in architedure, the lame with ca- pitals. Chapiters, in law, formerly fignified a fummary of fuch matters as were inquired of, or prefented be- fore juftices in eyre, juftices of affize, or of the peace in their fefllons. Chapiters, at this time, denote fuch articles as are delivered by the mouth of the juflice in his charge to the inqueft. CHAPLAIN properly fignifies a perfon provided with a chapel ; or who difcharges the duty thereof. Chaplain is alfo ufed for an ecclefiaftical perfon, in the houfe of a prince, or a perfon of quality, who officiates in their chapels, &c. In England there are 48 chaplains to the king, who wait four each month, preach in the chapel, read the fervice to the family, and to the king in his private oratory, and fay giace in the abfenee of the clerk of the clofet. While in waiting they have a table, and attendance, but no falarj\ In Scotland the king has fix chaplains, with a falary of L. 50 each, three of them having in addition the deanery of the chapel-royal divided between them, making up above L. 100 to each. Their only duty at pref<;nt is to fay prayers at the eledfion of peers for Scotland to fit in parliament. According to a ftatute of Henry VIII. the perfons veiled with a power of retaining chaplains, together with the number each is allowed to qualify, is as follows : An archblfhop, eight ; a duke or bllhop^ fix ; marquis or earl, five ; vilcount, four ; baron, knight of the gaiter, or lord chancellor, three ; a du- ehefs, marchionefs, countefs, baronefs, the treafurer and comptroller of the king's houle, clerk of the clo- fet, the king's fecretary, dean of the chapel, almoner, and mailer of the rolls, each of them two ; chief juf- tice. of the king's bench, and warden of the cinque?- 335 1 - c H A ports, each one. All thefe chaplains may purchafe a licence or difpenfatlon, and take two benefices ' with cure of fouls. A chaplain mull be retained by letters , teftimonial underhand and feal ; for it is not fufacient that he ferve as chaplain in the family. The firil chaplains are faid to have been thofe inlli- tuted by the ancient kings of France, for preferving the chape, or cape, with the other relics of St Martin, which the kings kept in their palace, and carried out with them to the war. The firft chaplain is faid to have been Giil. de Mefmes, chaplain to St Louis. Chaplain inihe order of Malta, is ufed for the fecond rank, or clafs, in that order ; otherwife called d'laco. The knights make the firfl clafs, and the chaplains the fecond. . Chaplains of the Pope, are the auditors, or judges of caufes in the facred palace ; fo called, becaufe the pope anciently gave audience In his chapel, for the de- clfion of cafes fent from the feveral parts of Chrillen- dom. He hither fummoned as affelfors the moil learn- ed lawyers of his time ; and they hence acquired the appellation of capellani, chaplains. It is from the de- crees formerly given by thefe, that the body of de- cretals is compofed : their number pope SIxtus IV. reduced to twelve. Some fay, the fhrines of relics were covered with a kind of tent, cape, or capella, i. e. little cape ; and that hence the priefts, who had the care of them, were cal- led chaplains. In time thefe relics were repofited in a little church, either contiguous to a larger, or feparate from it ; and the fame name, capella, which was given to the cover, was alfo given to the place where it was lodged : and hence the prieft who fuperintended it came to be called chaplain. CHAPLET, an ancient ornament for the head, like a garland or wreath ; but this word is frequently ufed to fignify the circle of a crown. There are inilances of its being borne in a coat of arms, as well as for crefts ; the paternal arms for Lafcelles are argent, three chaplets, gules. Chaplet alfo denotes a firing of beads ufed by the Roman Cathohcs, to count the number of their pray- ers. The invention of it is afcrlbed to Peter the her- mit, who probably learned it of the Turks, as they owe it to the Eail- Indians. Chaplets are fometlmes c-aWtd. pater-nojers ; and are made of coral, of diamonds, of wood, is'c. The com- mon chaplet contains fifty ave-marias, and five pater- nofters. There is alfo a chaplet of our Saviour, con- fifting of 3 3 beads, in honour of his 33 years living oa earth, inflituted by father Michael the Camaldufian. The Orientals have a kind of chaplets which they call chains, and which they ufe in their prayers, rc- hearfing one of the perfections of God on each link or head. The Great Mogul is faid to have i 8 of thefe chains, all precious flones ; fome diamonds, others ru- bies, peai Is, &c. The- Turks have likewife chaplets,- which they bear in the hand, or hang at the girdle : but father Dandini obferves, they differ from thofe ufed by the Romanlfts, in that they are all of the fame bignefs, and have not that diftinftion into decads ; though they confiil of fix decads, or 60 heads. He adds, that the mufliilmans run over the chaplet almofl in an inflant, the prayers being extremely fhort, as containing only thefe words, <' praife to God," or glory Chaplaiii II Chaplet Chaplet (I Chapter. C H A [ 336 ] C H A " glory to God," for each bead. Befides the com- of the new Toundatlon ; fuch are Canterbury, Wln- mon chaplet they have likewife a larger one confilt- chefter, Ely, Carhfle, &c._ See Dean. ing of 100 beads, where there is fome didinaion, as Chapter, in matters in literature, a divifion in a being divided byhttle threads Into three patts ; on one book for keeping the iubjed treated of more clear and of which they repeat 30 times foubhan Allah, i. e. Chapter " li Charader. God is worthy to be praifed ;" on another, ellamh Allah, " glory be to God ;" and on the third, Allah echcr, " God is great." Thefe thrice thirty times ma- king only 90 ; to complete the number 100, they add diftina. CHAR, in ichthyology, a fpecies of Salmo. CHARA, in botany : A genus of the monandria order, belonging to the moncecia clafs of plants. There is neither male calyx nor corolla ; and the anthera is other prayers for the beginning of the chaplet— He placed under the gerraen. The female calyx is terra- phyllous ; no corolla ; the ftigma quinquefid, with one roundiih feed. CHARABON, a fea-port town on the northern coatl of the ifland of Java in the Eall-Indies ; E. Long. 10. 8. 8. Lat. 6. CHARACENE, the moft fouthern part of Sufiana, a province of Perfia, lying on the Peifian gulph, be- tween the Tigris and the Eulsus. It was fo named from ^the city of Chorax, called lirft Alexandria, from its founder Alexander the Great ; afterwards Antio- chia, from Antlochus V. king of Syria, who repaired and beautified it ; and laftly, Chorax Spafinas, or Pa- finae, that is the Mole of the Spafines, an Arabian king of that name having fecured it agalnft the over- flowing of the Tigris, by a high bank or mole, extend- ing three miles, which fervcd as a fence to all that country. DIonyfius Periegetes, and Ifidorus, author of the Parthica; Manliones, were both natives of this city. The fmall dlftria of Characene was feiztd by Pafines, the fon of Sogdonacus, king of the neighbour- ing Arabs, during the troubles of Syria, and ereded into a kingdom. Lucian calls him Hyfpafines, and ?ierngk7 J)Xw7in\rthree parts, th7 feaions on the adds, that he ruled over the Characeni and the reigh- fides being of different metal or colour from the reft. bouring people : he died m the 85th year of his age. CHAPPEL IN FRITH, a market-town of Derby- The other kings of this country we find mentioned by iliire, about 26 miles north- weft of Derby ; W. Long, the ancients are, Terasus, who died in the 92d year of J CO N Lat C^. 22. his age, and after him Artabazus the icvenih, as l^uciaa * Chappel (Wiil'iam) a learned and pious bifhop of informs us, who was driven from the throne by his own Cork, Cloyne, and Rofs, in Ireland, born in Notting- fubjeas,but reftorcdby the Parthians. And this is all we hamfhire in 1 c82. When the troubles began under find in the ancients relating to the kings ol Characene. Charles I.he was profecuted by the puritan party In par- CHARACTER, in a genera fenfe, fignifies a marK llament, and retired to Derby, where he devoted himfelf or figure, dr^wn on paper, metal, ttone, or other mat- to ftudy until his death in 1649. He wrote Mdhodus ter, with a pen, graver, chiffel, or other inltrument, adds, that the Mahometan chaplet appears to have had its rife from the mea heracoth, or " hundred bs- nediaions-;" which the Jews are obliged to repeat daily, and which we find in their prayer-books ; the Jews and Mahometans having this in common, that they fcarce do any thing without pronouncing fome laud or benediaion. Menage derives the word chaplet from chapeau, ■** hat." The modern Latins call it chapellina, the Ita- lians more frequently corona, Chaplet, or Chapcht, in architeaure, a little moulding, cut, or carved into round beads, peails, olives, or the like. CHAPMAN (George), born in I557» a man \\\^\- ly efleemed in his time for his dramatic and poetic works. He wrote 1 7 plays ; tranflated Homer and fome other ancient poets ; and was thought no mean genius. He died in 16^4 ; and was buried in St Giles's in the fields, where his friend Inlgo Jones ereded a monument to him. CHAPPE', In heraldry, the dividing an efcutcheon by lines drawn from the centre of the upper edge to Concionandi, i. e. " the method of preaching :" and he is one of thofe to whom the Whole Duty of^ Man has been attributed. He left behind him alio his own life written by himfelf in, Latin, which has been twice printed. CHAPTER, In ecclefiaftical polity, a fociety or community of clergymen belonging to the cathedrals and collegiate churches to fignify or denote any thing. The word is Greek, ■^apa.v.rr,p, formed from the verb, x^t^^'^^^-' infculperi', " to ingrave, imprefs," life. The various kinds of charaders may be reduced to three heads, viz. Literal Charaders, Numeral Charac- ters, and Albre'viations. I. Literal CHAiiAcrF.R, is a letter of the alphabet, ferving to indicate fome articulate found, expreffive of It was'in the eighth century that the body of canons fome idea or conception of the mind. See Alphabet. began to be called a chapter. The chapter of the ca- i • TKefe may be divided, with regard to^ their na nons of a cathedral were a ftanding council to the bi- ture and ufe, into Nominal CharaSters, or thofe vve pro- fhop, and, during the vacancy of the fee, had the jiirif diaion of the diocefe. In the earlier ages, the bifhop was head of the chapter ; afterwards abbots and other dignitaries, as deans, provofts, treaCurers, &c. were preferred to this dlflinaion. The deans and chapters had the privilege of choofing the bifhops in England ; but Henry VIII. got this power vefted in the crown : and as the fame prince expelled the monks from the cathedrals, and placed fecular canons in their room, See HiEROGLypHic, Symbol, &c. _ thofe he thus regulated were called deans and chapters 2. Utcral Chakact.k, may be again divided, with N° 69. 5 perly call letters ; which ferve to exprefs the names of things: See Letter. Real CharaBers ; thofe that inftead of names exprefs things and ideas : See Idea, &c. Emllematical ox Symbolical CharaBers : which have this in common with real ones, that they exprefs the things themfelves ; but have this further, that they in fome meafure perlonate them, and exhibit their form : fuch are the hieroglyphics of the ancient Egyptians. 0 !H[ A. Chft^a low as the tranflation of the feat of the empire to Conftantinople : towards the time of Decius the character began to lofe its roundnefs and beauty ; fome time after, it retrieved, and fubfifted tolerably till the time of Juftin, when it degenerated gradually into the Gothic. The rounder, then, and better formed a charafter is upon a medal, the fairer pretence it has to antiquity. IL Numeral CHARAcrERS, or charafters ufed to cxprefs numbers, are either letters or figures. The Arabic charafter, called alfo the common one, becaufe it is ufed almoft throughout Europe in all forts of calculations, confifts of thefe ten digits 1, 2, 3, 4, 5, 6, 7, 8, 9, o. The Roman numeral charafter confifts of feven ma- jufcule letters of the Roman alphabet, vi%. I, V, X, L, C, D, M. The I denotes one, V five, X ten, L fifty, C a hundred, D five hundred, and M a thou- fand. The I repeated twice makes two, II ; thrice, three, III : four is expreffed thus IV, as I before V or X takes an unit from the number expreffed by thefe letters. To exprefs fix, an I is added to a V, VI ; for feven, two, VII ; and for eight, three, VIII. nine is epreifed by an I before X, thus IX. The fame remark may be made of the X before L or C, except that the diminution is by tens ; thus, XL denotes forty, XC ninety, and LX fixty. The C before D or M diminifties each by a hundred. The numbei five hundred is fometimes expreffed by an I before a C inverted, thus, 13 ; and inftead of M, which figni- fies a thoufand, an I is fometimes ufed between two C's, the one direft, and the other inverted, thus CID* The addition of C and 3 before or after raifes CID by tens, thus, CCI33 expreffes ten thoufand, CCCI3DD, a hundred thoufand. Th? Romans alfo expreffed any number of thoufands by a line drawn over any numeral lefs than a thoufand ; thus v denotes five thoufand, or, fixty thoufand: fo likewife M is one million, MM is two millions, &c. The Greeks had three vrays of exprefling numbers : 1. Every letter, according to its place in the alphabet, denoted a number, from «, one, to u, twenty-four. 2. The alphabet was divided into eight units, a. one, ^ two, three, £ff or 5^, the natural note happens to be required, it is de- noted by this character. chara£ler of the treble cliff. 1^1 character of the mean cliff, ^ rj; bafs cliff. ^ , or ^ chara£lers of common duple to be time, fignify- equal to two ing the meafure of two crotchets r.otes, of which four make a femibreve. Q) 5p , charadlers that dilliiiguifh the movements 339 1 C H A of common time, the firfl implying flow quick, and the third very quick. •i-j T» T> 4> ^» chara charadlers of that fpecie* of triple time called the meafure of twelve times. Character, in human life, that which is peculiar in the manners of any perfon, and diflinguifhes him from all others. Good Character is particularly applied to that con- dudl which is regulated by virtue and religion ; in an in- ferior but very common fenfe, it is underflood of mere honefly of dealing between man and man. The importance of a good charadter in the commerce of life feems to be univerfally acknowledged. — To thofe who are to make their own way either to wealth or a good charadter is ufually no lefs necefTaiy than addrefs and abilities. To tranfcribe the obfervatlon of an elegant moralifl : Though human nature is de- generate, and corrupts itfelf Hill more by its own in- ventions ; yet it ufually retains to the laft an efleem for excellence. But even if we are arrived at fuch an extreme degree of depravity as to have lofl our native reverence for virtue ; yet a regard to our own interefl and fafety, which we feldom lofe, will lead us to ap- ply for aid, in all important tranfadlions, to men whofe integrity is unimpeached. When we choofe an afliflant, a partner, a fervant, our firft enquiry is con- cerning his charadler. When we have occafion for a counfellor or attorney, a phyfician or apothecary, whatever we may be ourfelves, we always choofe to trufl our property and perfons to men of the beft cha- radter. When we fix on the tradefmen who are to fiipply us with neceffaries, we are not determined by the fign of the lamb, or the wolf, or the fox ; nor bjr a fhop fitted up in the moft elegant tafle, but by the faireft reputation. Look into a daily newfpaper, and you will fee, from the highell to the lowefl rank, how important the charadlers of the employed appear to the employers. After the advertifement has enume- rated the qualities required in the perfon wanted, there conflantly follows, that none need apply who cannot bring an undeniable charadler. Offer your- felf as a candidate for a feat in parliament, be promo- ted to honour and emolument, or in any lefpedl at- tradl the attention of mankind upon yourfelf, and, if you are vulnerable in your charadler, you will be deep- ly wounded. This is a general teflimony in favour of honefly, which no writings and no pradlices can pof- fibly refute. Young men, therefore, whofe charadlers are yet unfixed, and who, confequcntly, may render them juft fuch as they wifh, ought to pay great attention to the firfl fteps which they take on entrance into life. They sre ufually carelefs and inattentive to thisobjedl. They purfue their own plans with ardour, and negledl the opinions which others entertain of them. By fome thoughtlefs adlion or expreflion, they fuffer a mark to be imprcfl"ed upon them, which fcarcely any fubfequent merit can entirely erafe. Every man v/iil find fome per- il u a fojis, C H A Chaiaiflcr. fonis, who, though they are not profefled enemies, yet ' ' v ' ' '"" view him with an envious or a jealous eye, and who will gladly revive any tale to which truth has given the Jlighteft foundation. In this turbulent and confufed fcene, where our words and actions are often mifunderflood, and of- tener mifreprefented, it is indeed difficult even for in- tiocence and integrity to avoid reproach, abufe, con- tempt, and hatred. Thefe not only hurt our intereft and impede our advancement in life, but forely af- flift the feelings of a tender and delicate mind. It is then the part of wifdom firft to do every thing in our power to preferve an irreproachable character, and then to let our happinefs depend chieHy on the appro- bation of our own confcient es, and on the advance- ment of our interefl in a world v/here liais fhali not be believed, and where flanderers lhali receive countenance from none bat him who, in Greek, is called, by way of eminence, Diabolus, or the calumniator. Character, in poetry, particularly the epopee and drama, is the refult of the manners or peculiarities by which each perfon is diilinguiHied from others. The poetical cha'raAer, fays Mr Boffu, is not pro- perly any parjiicuhlr' virtue or quality, but a compofi- tion of feveral which are mixed together, in a diffe- rent degree, accor Ir*-- tuent parts or elements of that very volatile liquid. But the rnofl extraordinary modern difcovery concerning this fubilance is that of Dr Prieftley, who has found that feveral of the metals may be converted into char- coal by pafling the fl:eam of fpirit of wine over them when red-hot ; and this, by way of diftinftion, he calls the charcoal of metals. This furprifing difcovery was made accidentally, while the Doftor was repeating the experiments by which M. Lavoifier imagined water might be converted into air. Having tranfmitted the fleam of water thro* a copper tube, on which it had no efFeft, he was will- ing to try the effefts of that of other fluids; and for this purpofe made choice of fpirit of wine, having be- fore procured inflammable air by fending the fame fleam through a red-hot tobacco-pipe. No fooner had the vapour of this fluid, however, touched the red-hot copper, than he was aftonifhed at the rapid production of air from it, which refembled the blowing of a pair of bellows ; and before four ounces of the fpirit were expended, the tube was foand to be perforated in two or three places. In a moment afterwards it was fo far deftroyed, that it fell to pieces on attempting to re- move it from the fire; the infide being filled with a black matter refembling lamp-black. Having now re- courfe to earthen tubes, the DoAor found that, by melting copper and other metals in them, and tranf- mitting the vapour of fpirit of wine in contaft with them while in a Itate of ignition, different fubftances were formed according to the metals employed. On fending three ounce-meafures of fpirit of wine over two ounces of copper, the metal loft 28 grains of its weight, and 446 grains of charcoal vvere procured, chiefly in the form of powder, though fome of it was in large flakes feveral inches long ; having feparated at once frcm the furface of the melted metal. Thefe pieces were almoft quite black, and bore handling without any danger of being broken. In another experiment, 508 grains of charcoal were obtained from 19 grains of copper ; but here the metal had been previoufly re- duced C H A [ 345 ] C H A Charcoal, diiced to thin plates, and they were not al! converted into charcoal, being fomething harder, and therefore partially metallic in the middle. Silver was found to be affefted very mnch as copper had been ; but the larger maffes of charcoal procured from this metal were much whiter than thofe fiom copper. Only a fmall quantity of charcoal could be procured from lead. Three ounce-meafures of fplrit of wine and near four ounces of lead, gave only a fmall quantity of whitifli powdery fubftance, though 58 grains of the lead were miffing ; but the infide of the glafs-tube through which the air was tranfmitted be- came very black. The like quantity of fpirit of wine fent over 360 grains of melted tin, and produced 26 grains of black duft,the metal not being diminifhed quite four grains. The vapour of two ounce-meafures of • fpirit of wine, fent over 960 grains of iron-fhavings, diminifhed the m.etal only two grains ; but no charcoal could be colleded, though the air was loaded with black particles. The iron had acquired a dark blue colour. Gold was not fenfibly changed or diminiOied in weight ; and it not only remained unalterable by the procefs itfelf, but effeAually protefttd a tenth-part of its weight of copper from the aftion of the ftcam. Spirit of turpentine was found to anfwer for the produflion of this charcoal, as well as fpirit of wine ; 120 grains of the former being obtained from five of copper by means of the turpentine, notwithftanding a very denfe black fmoke which iffued from the end of the tube during the whole time of the operation. The Doftor obferves, indeed, that in all thofe experiments, where the heat is very great, the minute divifion and volatthty of this charcoal is very extraordinary. See- ing it ifliie from the end of a tube in a denfe black cloud, he endeavoured to collect it in a large glafs re- ceiver ; but after having given the glafs a very thin black coating, not dillinguifliable in appearance from foot, it ilTued from the orifice like denfe fmoke, and appeared to be altogether incoercible, even when feve- ral ad()})ters were connected with the receiver, and a tube, from whence it finally iffued, plunged deep into water. It is obferved, that charcoal of wood, when freHi made, has a ftrong attradtion for air, and will conti- nue to abforb it for a confiderable time ; a property which it has in common with fcveral other fubftances. Dr Pricftley made fome experiments to afcertain the quantity abforbed. For this purpofe, he left in an open dilh, on the fourth of September, fome charcoal fre fion) ; when frefli made inflammable air,, in the fame circumftances, made only 14 explofions, though fkronger ones. In this experiment, however, I over- looked one obvious confi deration,, viz. that water, or any thing foluble in water, might be the bafis -of in- flammable air. All that could be abfolutely inferred from the experiment was, that this bafis could not be any thing that vras capable of fubfifting in the form of air. It will be feen^ that I afterwards made the experiment with air confined by mercury." In this experiment it is to be regretted that the Doftor did not inform us- whether the weight of his calces was on the whole increafed or dimini-fhed by the operation. As it Hands, though, fufficient to over- throw the doftrine of the AntipUogiilians, it is not al^ together fufficient to efi.abHih that of their adverfaries. Mr Higgins, however, though he does not reply to this experiment, gives an account of another from Dr Higgins, which he confiders as abfolutely decilive a- gainll the Phlogilliaus. " Dr. Higgins, (fays he) in- 6 ] C H A troduced feme pieces of well-burned charcoal into a ChiarcoaL- deep crucible, and covered them over an inch deep with, powdered charcoal. Having luted on a cover, he expofed them for two hours to heat fufficient to melt filver ; he then pbiced the crucible in fuch a manner that the powder might remain red hot for fome time after the pieces next the bottom had cooled.' This he had done, as the charcoal mufl; imbibe fomething on cooling, both .to fupply it with inilammable air, and to prevent a communication with. the external air,. which the charcoal would otherwife have imbibed. " One hundred and twent)'- grains of this charcoal quickly powdered, v/ere welh mixed with 7680 grains, of Htharge, which had been prtvioufly fufed to Icpa- rate any uncalcined lead it might contain. Thi.s mix- ture was charged into a coated retort juft large enough - to contain it .j fo that the common air muit have been nearly fecluded'. Being then. placed in a reverberating furaace, and heat duly applied, it yielded by eftima- tion, after cooling to the mean temperature of the at- mofphere, 384 grains, of fixable air, at the rate of 0.57 grains to a cubic inch, 8.704 of phlogilUcated air, and 0.91 1 grains of dephlogifticated air, befides 49 grains of water. On breaking the retort, 3888 grains of revived lead were found, befides fom.e vitrified li- tharge ; but not aa atom of charcoal was left, nor was- there a particle of inflammable air produced. Now, let my reader confider the weight that 3888 grains of lead acquire by its converfion to litharge, and the quan- tity of inflammable air that 120 grains of charcoal will afford (which, according to Dr Prieftley* is about 360 ounce-meafures), and he will find, making allowance for the phlogifticated air^ that theie nearly correipond with the proportion of heavy inflammable air and dephlogiiticated air neceflary to the fonruition of iix- able air by the eleftric fpark... Hence we may con- clude, that not a particle of charcoal entered- into the conftltution- of the revived lead, but muft have been wholly converted into fixable air." To this experiment, however, the Phlogiftians will replv, that fo far from being dcciiive on tlie iubject,. no conclufion whatever can be drawn from it, on ac- cour.t of its enormvus inaccuracy. The quantity of matter put into the retort was 7680+120, or 780a grains, and the whole prx>duce was 3888+38^44-8.704 +0.9.1 i+49=:433o.6i5 grains : a deficiency there- fore of no lefs than 3469.385 grains is to be accounted for ; and of this we hear not one word ; fo that wc are at liberty to fappufe that. the vitrified litharge had perforated the retort in fuch a manner as -to admit the fixed and.phlogiiticated fiir from without, as Dr Priclt- ley found earthen retorts pervious to air from without; . and this, though coated, might by a corrofion of the glafs (if it v/as a glafs one) be reduced to a fimllar lituation. We do not mean that this fliould be reckoned a for » mal anfvwr to. Dr Higgins' s experiment ; all we in- tend ^here, is to ftate the arguments fairly on both fides, fo that the reader who has not an opportimity of making experiments himfelf, may be able to judge on which fide the truth lies. Dr Prieftiey informs us, that in his experiment,- the calx of lead abforbcd a quan- tity- of inflammable air without the extrication of fixed air, or any thing tlfe that could be perceived. Wiie.- ther or not have we reaiun to conclude froia thence, 4. tbat C H A [ 347 ] C H A ins s ■ ■rat. rccal. that the gravit;iting, folid, or cnally, part of the in- fiammable air was received into the calx, arid became part of the revived metal ? In Dr,HiggIns's experi' ment a quantity of elaftic fluid was produced, and a quantity of lead revived ; but we neither know how much of the Calx went to this lead, how much the li- tharge had otiginally attraftcd from the air, nor whe- ther the elaftic fluids were certainly produced ; or indeed whether any of them, the fmall quantity of dephlo- giflicatdd air alone excepted, came from the materials or not. From fuch a ftate of the cafe then, have v/e reafon to conclude, that not a particle of charcoal entered into the conftitution of the lead ?" We fliall next connder an experiment made by Mr Higgins himfelf, and which he likewife confiders as decifive againft the Phlogiftians. " I introduced (fays he) fome iron nails, free from ruft, into ftrong vola- P"*^ tile vitriolic acid ; when it Hood for a few minutes, it acquired a milky appearance, and the folution went on without ebuUition or extrication of air. On ilanding for a few liours, the folution acquired a darkifh co- lour, and a black pov>'der was precipitated. This pow- der, when collefted and wafhed, put on red hot iron, burned partly like fulphur and partly like charcoal dull, and the incombuftible refiduum was of a pur- plifli colour. The filtered folutiun was perfectly neu- tralifed, and free from the leaft fulphureous pungen- cv. Its tafte was ftrongly chalybeate, but not fo dif- agreeable as that .yL the folution of iron in the perfeft vitriolic acid, or in any of the mineral acids. Nitrous acid dropped into the folution inllantly produced a cloudinefs, which immediately difappeared without e- bullitlon, though volatile fulphureous acid was extri- cated in its utmoft degree of pungency. The vitrio- lic, marine, and acetous acids, decompofed this folu- tion, but caufed no turbidnefs, nor was any inflam- mable air produced. " In order to know whether the fulphur was dif- engaged from the volatile fulphureous acid or the iroa, I poured marine acid on the fame nails, when light in- flamm?.ble air and hepatic air were copioufly produ- ced, and likewife fulphur was depofited in its crude ftate. When I ufed vitriolic or the nitrous acid, no fulphur was produced. I tried difi^erent nails, and likewife iron-filings, with the fiime refult. Thefe fadls convinced nie that the fulphur came from the iron ; 'but that all forts of iron contain fulphur is what I can- not pretend to know, as I have not tried ftecl, or va- rieties enough of malleable iron. However, I have •ftrong reafon to fufpeft, that fulphur has more to do 'in the different properties of iron than we are aware of. That iron fliould contain fulphur, notwithftanding the different procefles it muft necefiarily undergo before it acquires malleability, confidering the volatility of ful- phur, points out the force of their attraftion to one another ; and the feparation of this again by volatile fulphureous acid, ftiows hkewife the greater attraftion of iron to fulphur and dephlogifticated air jointly. That volatile fulphureous acid fliould diffolve iron without tiie extrication of inflammable air or phlogi- gifton, is a very ftrong inftance of the fallacy of the phlogiftic doArine. A fmall quantity of inflammable air is produced, but it is fo trilling comparatively to wliat fliould be produced from the quantity of iron dilTolved, that it is hardly worth noticing ; and in my opinion proceeds from a portion of perfeft vitriolic Char coaL^ acid, which is generally infeparable from the volatile ' • acid. If volatile vitriolic acid were a compound of phlogifton, a certain bafis, and dephlogifticated air, a greater quantity of inflammable air fliould have been difengaged during the folution of iron in this aci4 than when the perfeft vitriolic acid is ufed. Let us even fuppofe volatile fulphureous acid to be compofed of the bafis of fulphur, phlogifton, and dephlogifticated air, which is the opinion of all the Phlogiftians, though they differ with refpeft to the modification of thefe three principles ; and likewife iron to be compofed of a certain bafis and phlogifton ; I would aflf the Phlo- giftians, What becomes of the phlogifton of the iron during its folution ?" But however much Mr Higgins may be convinced^ from this experiment, of the fallacy of the phlogiftic doftrine, his adverfarles, Inftead of being filenced, will urge his own experiment againll himfelf. He owny, that during the folution fomething was feparated of a black colour, and whic:h burned like charcoal duit. Unlefs therefore Mr Pliggins fliall prove the contrary, they will fay, that this was the real phlogijion or charcoal which^entered Into the fubftance of the metal ; and that it ajjpeared in its native form, becaufe the volatile vi- triolic acid had not fpecific or latent heat fuflicient to convert it into inflammable air. At any rate, it was incumbent on Mr Higgins to have accounted for the coally part of his refiduum as well as the ful})hureous one ; yet he has been at confiderable pains to deduce the latter from the iron, without fpeaking a word a- bout the foriner. Indeed, whether he deduced this from the iron or the vitriolic acid, it will make equally againft him ; for his principles do not allow that the volatile vitriolic acid contains any charcoal. That the latter really does fo, however, appears from an experi- ment of Dr Prieftley, in which he reduced a calx of lead by means of vitriolic acid air, the fame with the vitriolic or volatile fulphureous acid. It is true, that only a fmall quantity of metal was thus procured; but however fmall this was, the Antiphlogiftians do not pre- tend that metals can be reduced to tlieir metallic ftate in any quantity, except by the mediation of char- coal. Thus It appears, that with regard to metals the dif- pute is as yet far enough from being decided in fa- vour of the Antiphlogiftians. Their caule is equally doubtful with regard to fulphur and phofphorus, both of which Dr Prieftley has produced by heating vitrio- lic and phofphoric acid in inflammable air. Indeed, by fome expei-Iments on fulphur, the matter feems to be decided againft them. " Perhaps (fays Dr Prieftley) as decifive a proof as any^, of the real produftion of fix- ed air from phlogifton and dephlogifticated air, may be drawn from the experiments in which I always found a quantity of it v.-hen I burned fulphur in deplilogifti- cated air. In one of thefe experiments to which I gave more particular attention, fix ounce-meafures and an half of the dephlogifticated air were reduced to about two ounce-meal ures, and one-fifth of this was fixed air." Now, though the Dotlor Infeired from this, that fixed air was compofed of phlogifton and dephlogifti- cated air, on the fuppofition of fulphur containing phlogifton ; yet, admitting from other proofs, that fixed sir is compofed of thefe two principles, theexpe- X X 2 i-iment C H A Charcoal. t 348 ] C H A riment unanfwerably proves, that fulphur coutu'ms phlo- ^"""y—' gilton or charcoal, though indeed in a very fmall quan- tity : but if the fulphur contained none at all, and the dephlogiflicated air as little, as the Antiphlogiftians vould have it, how is it poffible that a compound, of which phlogiiton makes a part, fhould refult from an • See /^fro- union of the two * ? Another experiment equally n° in.decilive, even with regard to metals, is that quoted from Dr Prieftley in the place juft referred to (a), where he obtained pure fixed air from a mixture of red precipitate and iron-filings. Now, according to the antiphlogirtic doftrine, neither of thefc mate>ials con- ' taiiied an atom of charcoal or phlogiilon ; whence then came the phlogifton in the fixed air which iiTued from the mixture ? Thus the Antiphlogiftians feem to be unanfwerably refuted with regard to fulphur and metallic fubftan- ces ; for if the tv/o experiments juft related be accu- rate, it is impofiible to invalidate them by any argu- mentation whatever. Their laft refource therefore is the decompofition of water : and even here it is evi- dent they have little reafon to boafl:. On this fubjeft, however, we are forry to obferve, that the opinions have been fo many, fo various, and fo fluctuating, that it is not only impofiible to fay what are the prevailing ones, but even difficult to afcertain what are the fenti- ments of any individual on the fubjeft. Under the ar- ticle Aerology, n-" 81. we have quoted* Dr Prieft- ley as favouring the doftrine of the decompofition of water ; and in iSlr Higgins's work we find him quoted Cornparatkje^^ oppofing it. " Dr Prieftley (fays he) fuppofes 3. that the water produced by the condenfation of in- flammable and dephlogifticated air, is only what was fu- fpended and attached to them in their elaftic ftate, and that their refpe£live gravitating particles form a diffe- rent compound, namely, the nitrous acid. To afcer- tain this, he confined his mixture of airs with dry fixed alkali over mercury, in order to abitraft from it as much water as pofiible. Having thus prepared his mixture of airs, he found, after exploding them, that the produft of water fell far ffiort of the w^eight of both airs ; and he obferved a denfe vapour after every explofion, which foon condenfed, and adhered in a fo- lid ftate to the fides of the veflel, which he found after- wards to be tJie nitrous acid." To this Mr Higgins anfwers, that the airs ought to have been accurately weighed after abftrafting the water fi-om thern, when (he fuppofes) the weight of water produced would have equalled them. This indeed ought to have been done ; but Mr Higgins, or fome Antiphlogiftian, ought to have done fo before he decided pofitively in favour of the oppofite doclrine. At any rate, it cannot be pretended, that in- any experiment, let the circumftan- ces of it be what they would, the quantity of water produced ever equalled that of the two airs. It is evi- dent therefore, that till this ftiall'fome how or other be cleared up, the matter muft remain uncertain. That the pureft water we can obtain always contains phlo- gifton, is what no Phlogittian denies; that it effentially belongs to it is doubtful, though indeed it mutt be probable, that it do<*8 fo until experiments fhow the Charcoal, contrary. Mr Cavendiih fuppofes that dephJogiJl'icated — 'v-—' air and dephlogijikated -water may be the fame; and in- deed this would fecm to be almoft certain, were it not for a circumftance taken notice of by Mr Higgins, vi/,. that in the firing of iron in dephlogifticated air th« latter appears to be totally abforbed ; though it is cer- tain, that a quantity of undecompofed water enters into its compofition. How far this circumftance throws any obfcurity on the matter the reader muft determine. For a more full inveftigation of the fubjeft, however, we muft refer to the article Water; and in the ir-ean time ftiall difmifs the article with a few obfervations on the compofition of charcoal. From the days of Stahl till very lately, the compo- nent parts of this fubftance have been reckoned a cer- tain kind of earth combined with what was called phlo- gifton. The late experiments of Dr Prieftley have fhown, that this doftrine is eironeous, and that char- coal is wholly diflipable into vapour. " On the whole (fays the tranflator of Wiegleb's Chemiftry), charcoal appears, from the experiments of Lavoifier and Bar- thollet, to be an oil deprived of its inflammable gas. But coal of wood (or common charcoal) likewife con- tains fixed alkah, which the foot (or the coal of oil) does not, but inftead of this exhibits volatile alkali. The fixed alkali of the former proceeds from the plant itfelf, and this, in the cafe of foot, is joined with in- flammable gas, and forms volatile alkali, the earthy part being left behind, as happens when this latter is prepared from fixed alkali. Genuine charcoal, there- fore, confifts of tliis vegetable principle, united with a little fixed alkali and part of the phlogifton that con- ftituted the oil of the plant of which it is made : for fome of this principle is carried oiF, together with the hydrophloge (b), in the form of inflammable gas, if dittil- led in clofe veflels ; but if burned in the open air, the hydrophloge unites with the pure part of the air, and forms water. From thefe confiderations, as well as from the experiments and obfervations of M. Berthol- let, in the Mem. de I'Acad. des Sciences pour 1786, P* 33* fil' appears, that common charcoal con- fii'b of the vegetable principle, fome phlogifton, fixed alkali, and no inflammable gas." On all this, however, we muft obferve, that it is en- tirely dii'proved by the experiments of Dr Prieftley, fo often quoted, in which it was totally dilTipated into in-^ flammable air*. On this occafion indeed he acknow-^^ ^ ledges, that fome very minuce particles of aflies were ob- ferved, which could not have amounted to a fingle grain from many pounds of wood. Even thefe, according to what he obierves in the fame place, may be fuppo- fed to have come from the fmail quantity of air in the receiver ; and it is to be wifhed that the Doftor would repeat the experiment in one of thofe perfect vacuums through which the ele£lric fluid cannot be made to pafs^ From undoubted experiments, however, it ap-^^ pears, that charcoal cannot be decompofed by mere heat; as in vacuo it is diflipated into inflammable air; and.. See A (a) See EncycL Vol. I. p. 169. col. i. where, in lines 18, 19 firom the top, read precipitate iov charcoal. (b) A word u fed by Mr Wieglcb, as far as we can comprehend the author's meaning, for one of tlie comgo- >tnt parts of water. See his General Syftem of Chemiftry, tranilated by Hopfon, p. 39.. C H A r 349 1 C H A •harcnal, and thiR, on prefenutig a proper fubftance to attradi ^"^-y-^ tlie folid part, again difcovera itfelf, by Its blackneffl, to be real charcoal. As liltle does it appear deftruftible by burninjr in the open air ; for thouft'h fome afhes are left, it appears probable that th/.y fur in- cannon whatever was reduced to one-third weight Q{"''"'f"'S ^^'^ the ball, or even lefs, it would be of confiderable ad- I'/'^^^^'f, vantage, not only by faving ammunition, but by keep- ing, ■■Ciiarge H Chariot. C H A ■[ 350 ] ing the guns cooler and quieter, and at the fame time Every chariot move effeftiially injuring the vcfltls of the enemy. With the prefent alK'hich had been pffereti to the fun by the king's predeceilors. This fuperlli- tioUs Chariot. C H A [ 1 Chariot tious cuftom was an imitation of the heathens, and 11. piincipally of the Perlians, who had horfes and cha- Charity. confccrated in honour of the fun. Herodotus, Xenophon, and Quintus Curtius, fpeak of white cha- riots crowned, which were confecrated to the fun, among the Perfians, which in their ceremonies were drawn by white horfes confecrated to the fame hmiinaiy. Triumphal CiiJRioT, was one of the principal orna- ments of the Roman celebration of a vitlory. The Roman triumphal chariot was generally made of ivory, round like a tower, or rather of a cylindri- cal figure ; it was fometimes gilt at the top, and or- namented with crowns ; and to reprefent a vi£tory more naturally, they ufed to ftain it with blood. It was ufually drawn by four white horfes ; but often- times by lions, elephants, tygers, bears, leopards, dogs, &c. CHARISIA, in the heathen theology, a wake, or night- fetlival, inftituted in honour of the graces. It continued the whole night, moll of which time was fpent in dancing ; after which, cakes made of yellow flour mixed with honey, and other fweetmeats, were diftrlbutcd among the aflittants.— Charifia is alfo fome- times ufed to fignify the fweetmeats ufed on fach oc- cafions. CHARISIUS, in the heathen theology,.a furname given to Jupiter. The word is derived from X'^F'-' gi-mtay grace" or " favour he being the God by whofe influence men obtain the favour and affedtion of one another. On which account the Greeks ufed at their meals to . make a libation of a cup to Jupiter Charifius. CHARISTIAj afeftival of the ancient Romans, celebrated in the month of February, wherein the re- lations by blood and marriage met, in order to preferve a good correfpondence ; and that if there happened to be any. difference among them, it might be the more eafdy accommodated, by the good humour and iTiirchr-of the entertainment. OviJ. Fnji. i. 617. CHARISTICARY, commendatory, or donatory, a perfou to whom is given the enjoyment of the reve- nues of a manaftery, hofpital, or benefice. The charifticaries a.mong the Gi-ecks^ were a kind of donatories, or commendatories, who enjoyed all the revenues of hofpitals and monaileiies, without gi- ving an account thereof to any perfon. — The original of this abufe is referred to the Iconoclaftas, particu- larly Conftantine Copronymus, the avowed enemy of the monks, \Yhofe monarteries he gave away to ftrangers. In after times, the emperors and patriarchs gave many to people of quality, not by way of gift, t a reap any temporal advantage fvom them ; but to re- pair, beautify, and patronize them. Ac length avarice crept in, and thofc; in good condition were given away, efpecially . fuch as were rich ; and at laft they were all given away, rich and, poor, thofe of men and of wo- men, and that to laymen and married meh. CHARITY, among divines, one of the three grand theological virtues, confifting in the love of God and of our neighbour, or the habit and difpofition of loving God with all our heart, and our neighbour as ourfclves. Charity is alfo ufed for the effeft of a moral vir- tue, which confifts in fupplying the nectflities of o- thcrs, whether wilhmoney , Qouiifcl, afll llance, or the like. >i T C H A As pecuniary relief is generally the moft efllcaclous, Char!:;,', and at the fame time that from which we are moll apt '~~'V~" to excufe ourfelves, this branch of the duty merits par- ticular illuftration ; and abetter cannot be offered than what is contained in t}\e following extraifls (if we may be permitted 10 make them) from the elegant Moral Sjjitm of Archdeacon Paky, Whether pity be an inlHnft or a habit, it is In fa^l' a property of our nature, which God appointed : and the final caufe for which it was appointed, is to afford to the miferable, in the compaffion of their fellow creatures, a remedy for thofe inequalities and diilrefl'es which God forefaw that many mud be expofcd to, un- der every general rule for the diflribution of property. • Tfie Cfiriftian icriptares are more copious and ex- plicit upon this duty than almoll any other. The de- fcription which Chriil hath left us of the proceedings • of the lafl day, eftabliflies the obligation of bounty be- yond controverfy. " When the Son of man fhallcome in his glory, and all the holy angels with him, then lhall he fit upon the throne of his glory, and before him fhall be gathered all nations ; and he fiiall feparate them, one from another. Then fhall the king fay un- to them on his right hand, Come ye blefled of my fa- ther, iuiierit the kingdom prepared for you from the foundation of the world : For I was an hungered, and ye gave me meat ; I was tliirlly, and ye gave me drink ; I was a ilranger, and ye took me in ; nEiked, and ye clothed me ; I was fick, and ye vifited me ; I was in prilon, and ye came unto me. And inafmuch as ye have done it to one of the leail of thefe my bte- thren, ye have done it unto me." It is not nccelTai y to underftand this paffage as a literal account of what will adlaally pafs on that day. Suppofnig it only a - fcenical defcription of the rules and principles by which the Supreme Arbiter of our defliny will regu- late his dccifions, it conveys the fame lefTon to us ; it equally demonflrates of how great value and import- ance thefe duties in the fight of God are, and what ilrefs will be laid upon them. Tlve apoftles alfo de- fcribe this virtue as propitiating the divine favour in an eminent degree. A-ir^ thefe recommendations have, produced their effect. It does not appear that, before the times of Chriflianity, an infirmary, hofpital, or - public charity of any kind, txifted m the world ; - whereas nuofl countries in Chriltendom have long a- bounded with thefe inftilutions. To which fnay be added, that a fpirit of ptivate liberalitj'- feems to flou-- rifh asr.idil 'the decay of many other virtues : not to mention the legal provifion for the poor, which ob- tains in this country, and which was unknown and.^ unthought of by the moil polifhed nations of anti-. quity. St Paul adds- upon -the fubjefl an excellent direftlon ; . and which is prafticable by all who have auy thing to give^ '* Upon the firfl day of the week (or any other liated time) let every one of you lay by in flore, as God hath profpered hlm." By which the apoflle may . be imderft.ood to recommend what is the very thing wanting with moft men, the being charitahle upqn a plan; . that is, from a dehberate comparifon of our fortunes, with the reafonable expences and expectations of our families, to compute what we can fpare, and to lay by fo much for charitable purpofes, in lome mode or other.. The mode will be a conlideration. afterwards. The ♦ C H A [ 352 J CtiarFfy. 'X'he effc£l, which Chriftiantiy produced upon fome beneficence of its converts, was fuch as mii2;ht be looked for from a divine religion coming with full force and miraculous evidence upon the confciences of mankind. It over- whelmed all worldly confiderations in the expe£lation of a more important exiftence. " And the multitude of them that believed were of one heart and of one foul ; neither faid any of them that aught of the things, which he pofiefTed, was his own ; but they had all things in common. — Neither was there any among them that lacked ; for as^any as were poffeflbrs of lands or houfes fold them, and brought the prices of the things that were fold, and laid them down at the a- poftles' feet ; and diltribution was made unto every man, according -s he had need." Afts iv. 32. Nevertheltfs, this community of goods, however it manifefted the fincere zeal of the primitive Chriftians, is no precedent for our imitation. It was confined to the church at Jerufalem ; continued not long there ; was never enjoined upon any (Afts v. 4. ) ; and, al- though it might fuit with the particular circumilances of a fmall and feledl fociety, is altogether imprafticable in a large and mixed commimity. Tlie conduft of the apollles upon the occafion de- ferves to be noticed. Their followers laid down their fortunes at their feet ; but fo far were they from ta- -king advantage of this unlimited confidence to enrich themfelves or eftablifli their authority, that they foon after got rid of this bufinefs as inconfiRent with the main objeft of their million, and transferred the cufto- dy and management of the public fund to deacons, elected to that office by the people at large. ( Afts vi.) There are three kinds of charity, our author obfei vts, which prefer a claim to attention. 1. The firft, and apparently one of the beft, is to give ftated and confiderable fums, by way of penfion or annuity to individuals or families, with whofe beha- viour and diftrefs we ourfelves are acquainted. In fpeaking of confiderable fums, it is meant only, that live pounds, or any other fum, given at once, or di- vided amongft, five or fewer families, will do more good than the fame fiim diRributed amongil a greater num- ber in fliillings or half crowns ; and that, becaufe it is more likely to be properly applied by the perfons w^ho •receive it. A poor fellow, who can find no better ufe . for a fhlUing than to drink his benefaftor's health, and purchafe half an hour's recreation for himfelf, would hardly break into a guinea for any fuch parpofe, or be fo im.piovident as not to lay it by for an occafion of importance, for his rent, his clothing, fuel, or ftock of winter's provifion. It is a ftill greater recoirmenda- tion of this kind of charity, that penfions and annui- ties, whicu are paid regularly, and can be expedled at the lime, are the only way by which we can prevent one part of a poor man's fufferings, -the dread of want. 2. But as this kind of charity fnppofes that proper objeds of fuch expenfive benefafhions fall within cur private knov/ledge and obfervation, which does not happen to all, a fecond method of doing good, which is in every one's power who has the money to fpare, is by fubfcription to public charities. iPublic charities admit of this argument in their favour, that your mo- ney goes farther towards attaining the end for which it is given, than it can lio by 7.ny private and feparate NO 6.9. 6 C PI A A guinea, for example, contributed to an infirmary, becomes the means of providing one pa- tient, at leatt, with a phyfician, furgeon,. apothecary ; with medicine, diet, lodging, and fuitable attendance ; which is not the tenth part of what the fame affiftance, if it conld be procured at all, would coll to a fick per- fon or family in any other fituation. 3. The lall, and, compared with the former, the loweft exertion of benevolence, is in the relief of beg- gars. Neverthelefs, the indifcriminate rejeftion of ail who implore our alms in this way, is by no means ap- proved. Some may perifli by fuch a conduil. Men are fomctimes overtaken by ditlrefs, for which ail other re- lief would come too late. Befides which, refolutions of this kind compel us to offer inch violence to our humanity, as may go near, in a little while, to fuffo- cate the principle itfelf ; which is a very ferious con- fideration. A good man, if he do not furrender him- felf to his feelings without referve, will at lealt lend aa ear to importunities which come accompanied with outward attellations of diitrefs ; and after a patient hearing of the complaint, will dire(A himfelf by the circumilances and credibility of the account that he receives. There are other fpecies of charity well contrived tar make the money expended go far j fuch as keeping down the price of fuel or provifion in cafe of a mono-, poly or temporary fcarcity, by purchafing the articles at the beft market, and retailing them at prime coft, or at a fmall lofs ; or the adding a bounty to a parti- cular fpecies of labour, when the price is accidentally deprefl'ed. The proprietors of large eilates have it in their power to facilitate the maintenance, and thereby en- courage the eftabllfhrnent of families (which is one of the nobleil purpofes to which the rich and great can convert their endeavours), by building cottages, fpUt-. ting farms, erefting manufaftnres, cultivating waltes, embanking the fea, draining marfhes, and other expe- dients, which the iituation of each eilate points out. If the profits of thefe undertakings do not repay the expence, let the authors of them place the diilcrence to the account of charity. It is true of almoll all fuch projedls, that the public is a gainer by them, whatever the owner be. And where the lofs can be fpared, this coniidcration is lulFicient. It is become a queition of fome importance, Under what circumftances works of charity ought to be done in private, and when they m.ay be made public with- out detradling from the merit of the adllon ; if indeed they ever may, the Author of our religion having de- livered a rule upon this fubjcdl, wiiich feems to enjoin univerfal fecrecy. " Wlien thou doeil alms, let not thy left -hand know what thy right hand doth ; that thy alms may be in fecret, and thy Father which fecih in iecret, himfelf fhall reward thee openly." (Matth. vi. 3, 4.) From the preamble to this prohibition, it is plain, that our Saviour's fole defign was to forbid ojimtation, and all publilhing of good works which pro- ceeds hom that motive. " Take heed that ye do not your alms before men, to be fccn of them ; otherwife ye liave no reward of your Father, which is in heaven : therefore, when thou doeil thine alms, do not found a trumpet before thee, as the hypocrites do, in the fy- nagogues and in the llreets, that they may have glory of men. Charity. C H A C 35.3 1 C H A CIsMity. men. Verily I fay unto thee, tliey have their reward," """"^ V. 2. There are motives for the doing our alms in public btiide thofe of oilentation ; with which there- foi e our Saviour's rule has no concern : fuch as to tef- tify our approbation of lomc particular fpecies of cha- rity, and to recommend it to others ; to take off the prejudice which the want, or, which is the fame thing, the fupprefGon, of our name in the lift of contributors, might excite againft the charity or againft ourfelves. And, fo long as thefe motives are free from any mix- ture of vanity, they arc in no danger of invading our Saviour's prohibition ; tliey rather feem to comply with another diredlion which he has left us : '* Let your light fo fliine before men, that they may fee your good works, and glorify your father which is in heaven." If it be neceffary to propofe a precife diftinclion upon * the fubjeft, there can be none better than the follow- ing : When our bounty is beyond our fortune or fta- tion, that is, when it is more than could be expedled from us, our charity fhould be private, if privacy be practicable ; when it is not more than might be ex- pedled, it may be public : for we cannot hope to in- fluence others to the imitation of extraordinary gene- rofity, and therefore want, in the former cafe, the on- ly juftitiable reafon for making it public. The pretences by which men excufe themfelves from giving to the poor, are various ; as, ' I. '* That they have nothing to fpare i. e. no- thing, for which they have not fome other ufe ; no- thing, which their plan of expence, together with the favings they have refolved to lay by, will not exhauft : never refle£ling whether it be in their power, or that it is their duty, to retrench their expences, and con- traft their plan, " that they may have to give to them that need ;" or rather that this ought to have been part of their plan originally. 2. " That they have families of their own, and that charity begins at home." A father is no doubt bound to adjuft his oeconomy with a view to the reafon- able demands of his family upon his fortune ; and un- til a fufficiency for thefe is acquired, or in due time probably will be acquired (for in human affairs pro- bability is enough), he is juftified in declining expenfi've liberality ; for to take from thofe who want, in order to give to thofe who want, adds nothing to the ftock of public happinefs. Thus far, therefore, and no far- ther, the plea in queftion is an excufe for parfimony, and an anfwer to thofe who folicit our bounty. 3. ** That charity does nqt confift in giving money, but in benevolence, philanthropy, love to all mankind, goodnefs of heart," i^c. Hear St James. " If a brother or filler be naked, and deftitute of daily food, and one of you fay unto them, depart in peace, be ye warmed and filled, notwithftandingj/f ^/-w them not thofe things 'which are needful to the body, what doth it profit?" (James ii. 1 5, 16.) 4. *• That gjving to the poor is not mentioned in St Paul's defcription of charity, in the 13th chap- ter of his firft epiftle to the Corinthians." This is not a defcription of charity, but of good nature ; and it is not neceffary that every duty be mentioned in every place. 5. " That they pay the poor-rates." They might as well allege that they pay their debts : for the poor Vox. IV. Part I. ^ have the fame right to that portion of a man's property, Clianty* which the laws affign them, that the man himfelf has » to the remainder. 6. *' That they employ many poor perfons :" — for their own fake, not the poor's — otherwife it is a good plea. 7. " That the poor do not fuffer fo much as we imagine ; that education and habit have reconciled them to the evils of their condition, and make them eafy under it." Habit can never reconcile human na- ture to the extremities of cold, hunger, and thirft, any more than it can reconcile the hand to the touch of a red-hot iron : befides, the queftion is not, how unhappy any one is, but how much more happy we can raakd' him. 8. << That thefe people, give them what you will, will never thank you, or think of you for it." In the firft place, this is not true : in the fecond place, it was not for the fake oftheirthanks that you relieved them. 9. " That we are fo liable to be impofed upon." If a due enquiry be macje, our motive and merit is the fame : befide that, the diftrefs is generally real, what- ever has been the caufe of it. 10. '* That they fiiould apply to their pariflies." This is not always prafticable : to which we may add, that there are many requifites to a comfortable fub* fiftence, which parifh-relief does not always fupply ; and that there are fome who would fuffer almoft as much from receiving parifh-relief as by the want of it : and laftly, that there are many modes of charity, to which this anfwer does not relate at all. 11. " That giving money encourages idlenefs and vagrancy." This is true only of injudicious and in- difcriminate generofity. 12. *' That we have too many objefts of chai-ity at home to beftow any thing upon ftrangers; or that there are other charities which are more ufeful, or ftand in greater need." The value of this excufe de- pends entirely upon the faB, whether we actually re- lieve thofe neighbouring objeds, and contribute to thofe other charities. Befide all thefe excufes, pride, or prudery, or deli- cacy, or love of eafe, keep one half of the world out of the way of obferving what the other half fuffer. Charity Schools, are fchools erefted and maintained in various parifhes by the voluntary contributions of the inhabitants, for teaching poor children to read, write, and other neceffary parts of education. See School. Brothers of Charity, a fort of religious hofpitallers, founded about the year 1297, fince denominated Bil- letins. They took the third order of St Francis, and the fcapulary, making three ufual vows, but without begging. Brothers of Charity alfo denote an order of hofpi- tallers ftill fubfifting in Romifli countries, whofe bufi- nefs is to attend the fick poor, and minifter to them both fpiritual and temporal fuccour. ^ They are all laymen, except a few priefts, for admi- niftering the facraments to the fick in their hofpitals. The brothers of charity ufually cultivate botany, phar- macy, furgery, and chemiftry, which they praftife with fuccefs. They were firft founded at Granada, by St John de Y'y Dieuj C H A I 354 ] C H A Dieu; and a fecond eftabllfliment was made at Madrid in the year 1553 : the order was confirmed by Gre- gory XIII. in 1572 : Gregory XIV. forbad them to take holy orders; but by leave of PaulV. in 1609, a few of the brothers might be admitted to orders. In 1 61 9 they were exempted from the jurifdiftion of the bifhop. Thofe of Spain are feparated from the reft ; and tucy, as well as fhe brothers of France, Germany, Poland, and Italy, have their diftindl generals, who re- fide at Rome. They were firtt introduced into France by Maiy of Medicis in 1601, and have fmce built a fine hofpital ni the Fauxboiirg St Germain. Charity of St H'lppolttus, a religious congregation founded about the end of the 14th century, by one Bernardin Alvarez, a Mexican, in honour of St Hip- politus the martyr, patron of the city of Mexico ; and approved by Pope Gregory XI 11. CnjRiTr of our Lady, in church-hifiory, a religi- ous order in France, which, though charity was the principal motive of their union, grew in length of time lb diforderly and irregular, that their order dwindled, and at laft became cxtinft. There is ftill at Paris a religious order of women. Called nuns hofpitallers of the chanty of our lady. The religious of this hofpital are by vow obliged to admi- nifter to the neceflities of the poor and the fick, but thofe only women. CHARLATAN, or Charletan, fignifies an em- piric or quack, who retails his medicines on a public fiage, and draws people about him with his buffoone- ries, feats of activity, &c. The word, according to Calepine, comes from the Italian ceretano ; of C/cretunr, a town near Spoletto in Italy, where thefe impoftors are faid to have firft rifen. Menage derives it from clarlaiano, and that from clrcidatortus^ of circulator., a quack. CHARLEMAGNE, or Charles 1. king of France by fucceffion, and emperor of the weft by conqueft in 800, (which laid the foundation of the dynafty of the •weftern Franks, who ruled the empire 472 years till the time of Radolphiis Aufpurgenfis, the founder of the houfe of Auftria). Charlemagne was as illuftrious in the cabinet as in the field ; and, though he could not write his name, was the patron of men of letters, the reftorer of learning, and a wife legifTator: he want- ed only the virtue of humanity to render him the moft accomplifhed of men ; but when we read of his be- heading 4500 Saxons, folely for their loyalty to their prince, in oppofmg his conquefts, we cannot think he merits the extravagant encomiums beftowed on him by fome hiftorians. He died in 814, in the 74th year of his age, and 47th of his reign. France had nine fovereigns of this name, of whom Charles V. merited the title of the ivlfe, (crowned in 1364, died in 1380): and Charles VIII. fignalized himfelf in the field by rapid viftories in Italy ; crown- ed 1483, died in 1498. The reft do not deferve particular mention in this place. See ( Hijlory of) France. CHARLEMONT, a town of the province of Na- mur in the Auftrian Netherlands, about 18 miles fouth of Namur. E. Long- 4. 40. N. Lat. 50. 10. Charlemont is alfo the name of a town of Ire- land, fituated ou the river Blackvvater, in the county Cha of Armagh, and province of Ulfter, about fix miles Charlerojr, fouth-eaft of D-ungannon. W. Long. 6. 50. N. Lat. 50. 16. CHARLEROY, a ftrong town in the province of Namur, in the Auftrian Netherlands, lit-uated on the river Sambre, about 19 miles weft of Namur. E. Long. 4. 20. N. Lat. 50. 30. CHARLES Martel, a renowned conqueror in the early annals of France. He depofed and reftored Chilpei-ic king of France ; and had the entire govern- ment of the kingdom, once with the title of mayor of the palace, and afterwards as duke of France ; but he would not accept the crov^n. He died, regretted, in Charles le Gros, emperor of the weft m 881, king of Italy and Suabia, memorable for his reverfe of for- tune ; being dethroned at a diet held near Mentz, by the French, the Itahans, and the Gcraians, in 887 : after which he was obliged to fubuft on the bounty of the archbifhop of Mentz. He died in 888. Charles V. (emperor and king of Spain), was fos of Philip I. archduke of Auftria, and of Jane queen of Caftile. He was born at Ghent, February 24. 1500, and fucceeded to the crown of Spain in 15 17. Two years afterwards he was chofen emperor at Francfort after the death of Maximilian his grandfather. He was a great warrior and politician ; and his ambitioa was not fatisfied v/ith the many kingdoms and pro- vinces he pofielfed ; for he is fuppofed, with reafon, to have afpired at univerfal empire. He is faid to have fought 60 battles, in moft of which he was vi6torious» He took the king of France (Francis I.) prifoner, and fold him his liberty on very hard terms : yet after- wards, when the people of Ghent revolted, he aflced leave to pafs through his dominions ; and though the generous king thus had him in his power, and had an opportunity of revenging his ill-treatment, y;t he . re- ceived and attended him with all pomp and magni- ficence. He facked Rome, and took the Pope pri- foner ; and the cruelties which his army exercifed there are faid to have exceeded thofe of the northern; barbarians. Yet the pious emperor went into mourn- ing on account of this conqueft : forbad the ringing of bells ; commanded proceflions to be made, and prayers to be offered up for the deliverance of the Pope hia^ prifoner ; yet did not inflift the leaft puniftiment oa thofe who treated the holy father and the holy fee with fuch inhumanity. He is accufed by fome Romlftf writers of favouring the Lutheran principles, which he might eafily have extirpated. But the truth is, he found his account in the divifions which thatfeft oC- cafioned ; and he for ever made his advantage of therti^ fometlmes againft the Pope, fometimes againft France, and at other times againft the empire itfelf. He was a great traveller, and made 50 different journeys into. Germany, Spain, Italy, Flanders, France, England, and Africa. Thotigh he had been fuecefsful in many unjuft enterprizes, yet his laft attempt on Metz, which he befieged with an army of ioO,ooo men, was very juft and very unfuccefsful. Vexed at the reverfe of fortune which feemed to attend his latter days, and op^reffcd by ficknefs, which unfitted him any longer from holding the reins of go- vernment with, fteadinefs, or to guide them with ad- drefsi C H A f 35 drefs, refignej his dominions to his brother Ferdi- nand and his fon PhiHp ; and retreated to the mona. llery of St Juftus near Placentia in Eflramadura. When Charles entered this retreat, he formed fuch a plan of life for himfelf as would have fuited a pri- vate gentleman of moderate fortune. His table was neat, but plain ; his domeftics few ; his intercourfe with them familiar; all the cumberfome and ceremo- nious forms of attendance on his perfon were entirely aboHfhed, as deftruftive of that focial eafe and tran- quillity which he courted in order to footh the remain- der of his days. As the mildnefs of the climate, toge- ther with his deliverence from the burdens and cares of government, procured him at firft a confiderable remiffion from the acute pains of the gout, with which he had been long tormented, he enjoyed perhaps more complete fatisfaftion in this humble folitude than all his grandeur had ever yielded him. The ambitious thoughts and projefts which had fo long engroffed and difquieted him, were quite effaced from his mind. Far from taking any part in the pohtical tranfaftions of the princes of Europe, he reftrained his curiofity even from an inquiry concerning them ; and he feemed to view the bufy fcene which he had abandoned with all the contempt and indifference arifmg from his thorough experience of its vanity, as well as from the pleafing refleftion of having difentangled himfelf from its cares. Other amufements, and other objefts, now occupied him. Sometimes he cultivated the plants in his gai - den with his own hand ; fometimes he rode out to the neighbouring wood on a little herfe, the only one that he kept, attended by a fingle fervant on foot. When his infirmities confined him to his apartment, which often happened, and deprived him of thefe more aftive recreations, he either admitted a few gentlemen who refided near the monaftery to vifit him, and en- tertained them familiarly at his table ; or he employed himfelf in fludying mechanical principles, and in form- ing curious works of mechanifm, of which he had al- ways been remarkably fond, and to which his genius was pecuHarly turned. With this view he had enga- ged Turriano, one of the mofl ingenious artifls of that age, to accompany him in his retreat. He laboured together with him in framing models of the moll ufe- ful machines, as well as in making experiments with regard to their refpe»Slive powers ; and it was not fel- dom that the ideas of the monarch affifted or perfeded the inventions of the artifl. He relieved his mind at intervals with flighter and more fantaftic works of me- chanifm, in fafhioning puppets, which, by the itrufture of internal fprings, mimicked the geilures and aftions of men, to the no fmall aftoniftiment of the ignorant monks, who, beholding movements which they could not comprehend, fometimes diftrufled their own fenfes, and fometimes fufpeftcd Charles and Turriano of be- ing in compaft with invlfible powers. He was parti- cularly curious with regai-d to the contlruiilion of cl:-cks and w atches ; and having found, after repeated trials, that he could not bring any two of them to go exaftly alike, he retltdted, it is faid, with a mixture of fur- prife as well as regret on his own folly, in having be- itowed fo much time and labour in the more vain at- tempt of bringing mankind to a precife uniformity of 5 1 C H A fentiment concerning the intricate and myfterious doc- trines of religion. But in what manner foever Charles difpofed of the reft of his time, he conftantly referved a confiderable portion of it for religious exercifes. . He regularly at- tended divine fervice in the chapel of the monaftery every morning and evening ; he took great pleafure in reading books of devotion, particularly the works of St Auguftine and St Bernard ; and converfed much with his confefTor, and the prior of the monaftery, on pious fubjefts. Thus did Charles pafs the firll year of his retreat in a manner not unbecoming a man perfedly difengaged from the affairs of this pre- fent life, and Handing on the confines of a future world, either in innocent amufements which foothed his pains, and reheved a mind worn out with excef- five application to bufinefs ; or in devout occupations, which he deemed neceffary in preparing for another ftate. But, about fix months before his death, the gout, after a longer intermiffion than ufual, returned with a proportional increafe of violence. His faattered con- ftitution, had not ftrength enough remaining to wlth- ftand fuch a (hock. It enfeebled his mind as much as his body ; and from this period we hardly difcern any traces of that found and mafculine underftanding which diftinguifhed Charles among his cotemporarie. An illiberal and timid fuperftition depreffed his fpirit. He had no relifli for amufements of any kind. He endea- voured to conform, in his manner of hving, to all tlie rigour of monaftic aufterity. He defired no other fociety than that of monks, and Vv'as almoft continu- ally employed in chanting with them the hymns of the miffal. As an expiation for his fins, he gave himfelf the difcipline in fecret with fuch feverity, that the whip of cords which he employed as the inftrument of his puniftiment, was found, after his deceafe, tin- ged with his blood. Nor was he fatisfied with thefe aas of mortification, which, however fevere, were not unexampled. The timorous and diftruftful folici- tude which always accompanies fuperftition, ftill con* tinued to difquiet him, and depreciating all that he had done, prompted him to aim at fomething extraor- dinary, at fome new and fingular ad of piety, that would difplay his zeal, and merit tlie favour of hea- ven. The acl on which he fixed was as wild and uncommon as any that fuperftition ever fuggefted to a difordered fancy. He refoKed to celebrate his own obfequies before his death. He ordered his tomb to be erefted in the chapel of the monaftery. His do- meftics marched thither in funeral procefTion, with black tapers in their hands. He himfelf followed in his ftiroud. He was laid in his coffin with much fo- lemnity. The fervice for the dead was "chanted ; and Charles joined in the prayers which were offered up for the reil of his foul, mingled his tears with thdie which his attendants fhed, as ;f they had been cele- brating A real funeral. The ceremony clofed with fprinkling holy vi^ater on the coffin in the ufual form, and, all the afftftants retiring, the doors of the chapel were fhut. Then Chailts rofe out of the coffin, and withdrew to his apartment, full of thofe aWiul fenti- ments which fuch a fingular folemnity was calculated to infpire. But either the fatiguing length of the ce- Y y 2 remony. C H A I Charles, remony, or the impreffion which this image of death ^ left on his mind, affefted him fo much, that next day- he was feized with a fever. His feeble frame could not long refiil its violence ; and he expired on the 2ift of September, after a life of 58 years fix months and 21 days. Charles I. ■) Kings of Britain. See Britain, CharlesII. i "°49> 254. Charles XII. king of Sweden, was born in 1682. By his father's will, the adminiftration was lodged in the hands of the queen-dowager Eleonora with five fenators, till the young prince was 18: but he was declared major at 15, by the ftates convened at Stock- holm. ■ The beginning of his adminiftration raifed no favourable ideas of him, as he was thought both by Swedes and foreigners to be a perfon of mean capaci- ty. But the difficulties that gathered round him, foon afforded him an opportunity to difplay his real charac- ter. Three powei-ful princes, Frederic king of Den- mark, Auguftus king of Poland and eleftor of Saxony, and Peter the Great czar of Mufcovy, prefuming on his youth, confpired his ruin almoti at the fame in- ftant. Their meafures alarming the council, they were for diverting the florm by negociations ; but Charles, with a grave refolution that aftonifhed them, faid, " I am refolved never to enter upon an unjuft; *' war, nor to put an end to a juft one but by the " deftruftion of my enemies. My refolution is fix- *' ed : I v^'ill attack the firft who fhall declare againft " me ; and when I have conquered him, I may hope to ft.rike a terror into the reft." The old counfel- Jors received his orders with admiration ; and were Hill more furprifed when they faw him on a fudden renounce all the enjoyments of a court, reduce his table to the utmoft frugality, drefs like a common fol- dier, and, full of the ideas of Alexander and Csefar, propofe thofe two conquerors for his models in every thing but their vices. The king of Denmark began by ravaging the territories of the duke of Holftein. Upon this Charles carried the war into the heart of Denmark ; and made fuch a progrefs, that the king of Denmark thought it beft to accept of peace, which was concluded in 1700. He next refolved to ad- vance againft the king of Poland, who had blocked up Riga. He had no fooner given orders for his troops to go into winter-quarters, than he received advice that Narva, where count Horne was governof, was befieged by an army of 100,000 Mufcovites. This made him alter his meafures, and move toward the Czar ; and at Narva he gained a furprifing vifloiy, which coft him not above 2000 men killed and wound- ed. The Mufcovites were forced to retire from the provinces they had invaded. He purfued his con- quefts, till he penetrated as far as where the diet of Poland was fitting ; when he made them declare the throne of Poland vacant, and ele£t Staniflaus their king : then inaking himfelf mafter of Saxony, he ob- liged Auguftus himfelf to renounce the crown of Po- land, and acknowledge Staniflaus by a letter of con- gratulation on his acceflion. All Europe was furpri- fed with the expeditious finiftiing of this great negocia- tion, but more at the difintereftednefs of the king of Sweden, who fatisfied himfelf with the bare reputa- tion of this viftoiy, without demanding an inch of 56 ] C H A ground for enlarging bis dominions. After thus re- ducing the king of Denmark to peace, placing a new king on the throne of Poland, having humbled the emperor of Germany, and protected the Lutheran religion, Charles prepared to penetrate into Mufcovy in order to dethrone the Czar. Pie quickly obliged the Mufcovites to abandon Poland, purfued them into their own country, and won feveral battles over them. The Czar, difpofed to peace, ventured to make fome propofals ; Charles only anfwered, *' I will treat with " the Czar at Mofcow." When this haughty aiifwer was brought to Peter, he faid, " My brother Charks " ftill affefts to ad the Alexander, but I flatter mv- " felf he will not in me find a Darius." The event juftified him : for the Mufcovites, already beaten into difcipline, and under a prince of fuch talents as Peter, entirely deftroyed the Swedifli army at the memo- rable battle of Pultowa, July 8. 1709 ; on which de- cifive day, Charles loft the fruits of nine years labour, and of almoft 100 battles! The king, with a fmall troop, purfued by the Mufcovites, pafled the Borif- thenes to Oczakow in the Turkifti territories : a»id from thence, through defert countries, arrived at Ben- der ; where the Sultan, when informed of his arrival, fent orders for accommodating him in the bett man- ner, and appointed him a guard. Near Bender Charles built a houfe, and intrenched himfelf ; and had with him 1800 men, who were all clothed and fed, with their horfes, at the expence of the Grand Signior. Here he formed a defign of turning the Ottoman arms upon his enemies ; and is faid to have had a pro- mife from the Vizir of being fent into Mufcovy with 200,000 men. While he remained here, he infenfiblv acquired a tafte for books : he read the tragedies of Corneille and Racine, with the works of Defpreaux, whofe fatires he reliflied, but did not much admire his other works. When he read that paflage in whiclr the author reprefents Alexander as a fool and a mad- man, he tore out the leaf. He would fometimes play at chefs : but when he recovered of his wounds, he re- newed his fatigues in exercifing his men ; he tired, three horfes a day ; and thofe who courted his favour were all day in their boots. To difpofe the Ottoman Porte to this war, he detached about 800 Poles and Cofaques of his retinue, with orders to pafs the Neifter, that runs by Bender, and to obferve what paffed on the frontiers of Poland. The Mufcovite troops, difperfed in thofe quarters, fell immediately upon this little company, and purfued them even to the territories of the Grand Signior. This was what the king expefted. His minifters at the Porte ex- cited the Turks to vengeance ; but the Czar's money removed all difficulties, and Charles found himfelf in a manner prifoner among the Tartars. He imagined the Sultan was ignorant of the intrigues of his Grand Vizir. Poniatoflcy undertook to make his complaints to the Grand Signior. The fultan, in anfwer, forae days after, fent Charles five Arabian horfes, one of which was covered with a faddle and houfing of great riches ; with an obliging letter, but conceived in fuch general terms, as gave reafon to fufpeft that the mi- iiifter had done nothing without the fultan's confent : Charles therefore refufed them. Poniatoficy had the courage to form a defign of depofing the Grand Vizir ;.. who. C H A . , ,[ 3 Vv'l'.o accordingly was depi'ived of hi's dignity and v'fcalth, and banifhed. The feul of the empire was ^iven to Numan Ciiproughly r who perfuaded his ma- iler, that the law forbid him to invade the Czar, who had done him no injary ; but to fuccour the king of Swedtn as an unfortunate prince in his dominions. He fcnt his majeity 800 purfes, ever)^ one of which amounted to 500 crowns, and advifed him to return peaceably to his own dominions. Charles ieje£led~ tiiis advice^, threatening to hang up the bafhaws, and fhave the beards of any Janifaries who brought him fxich mefl'agcs ; and fent word that he fhould depend upon the Grand Signior's promife, and hoped to re- enter Poland as a conqueror with ah army of Turks. After various intrigues at the Porte, an order was fent to attack this head of iron, as he was called, and to take him either alive or dead. He ftood a fiege in his houfe, with forty domeilics, againft the Turkifh army; killed no lefs than 20 Janifaries with his own hand ; and performed prodigies of valour on a very unnecefTary and unwarrantable occafion. But the houfe being fet on fire, and himfelf wounded, he was at laft taken prifoner, and fent to Adrianople ; where the Grand Signior gave him audience, and promifed to make good all the damages he had fuftained. At laft, after a ftay of above five years, he left Turkey ; and, having difguifed himfelf, ti-averfed Wallachia, Tranfylvania, Hungary, and Germany, attended on- ly by one perfon : and in 16 days riding, during which time he never went to bed, came to Stralfund at mid- night, November 21. 17 14. His boots were cut from his fwoUen legs, and he was put to bed ; where when he had flept fome hours, the firft thing he did was to review his troops, and examine the ftate of the forti- fications. He fent out orders that very day, to re- new the war with more vigour than ever. But af- fairs were now much changed : Augultus had recover- ed the throne of Poland; Sweden had loft many of its provinces, and was without money, trade, credit, or troops. The kings of Denmark and Pruflia feized the ifland of Rugen ; and befieged him in Stralfund, which furrendered; but Charles efcaped to Carelfcroon. When his countr)'' was threatened with invafion by fo many princes, he, to the furprife of all Europe, inarched into Norway with 20,000 men. A very few Danes might have flopped the Swedifh army ; but fuch a quick invafion they could not forefee. Eu- rope was yet more at a lofs to find the Czar fo quiet, and not making a defcent upon Sweden, as he had before agreed with his alHes. This inaflion was the confequence of one of the greateft defigns, and at the fame time the moft difficult of any that were ever form- ed by the imagination of man. In fiiort, a fcheme was fet on foot for a reconciliation with the Czar ; for re- placing Staniflaus on the throne of Poland; andfetting James the fecond's fon upon that of England, befide reftoring the duke of Holftein to bis dominions. Charles was pleafed with thefe grand ideas, though without building much upon tlitm, and gave his mi- nifter leave to af which is cul- tivated here, and for which the whole country is cover- ed wich mulberry trees. Thefe arc purpoftly check- ed in their growth by the natives, experience having taught them, that the leaves of the fmalleft trees pro- duce the bed filk. The ftuffs made in this province, which are embroidered v>'ith gold and filver, are rec- koned the beft in the empire : and notwithftanding a vaft exportation to the Japan and Philippine iflands, as well as to every part of China, and to Europe, fuch an abundance is left in the province, that a complete fuit of filk may be bought here as cheap as one of the coarfeil woollen in F"rance. * This province is alfo remarkable for a particular fpe- cies of mulhrooms, which is exported to every part of the empire. They are pickled, and then dried ; when they will keep good for a whole year. When ufed they muft be foaked in water, which renders them as frefli as at firft. Here alfo the Lallow tree is met with ; and the province affords excellent hams, and thofe fmall gold fidres with which the ponds are ufually ftocked. Che-kyang contains i i cities of the firft clafs, yz of the third, and i 8 fortreffes, which, in Europe, would be accounted large cities.. The principal of thefe are, 1. Hang-tcheou-fou, the metropolis, accounted by the Chinefe to be the paradife of the earth. It is four leagues in circumference, exclufive of the fuhurbs ; and the number of its inhabitants are computed at more than a million, and io,ooo workmen are fuppofed to be employed within its trails in manufafturing of filk. Its principal beauty is a fmall lake, clofe to the walls on the weftern fide, the water of which is pure and lim-. pid, and the banks almoft every where covered with flowers. Its banks are Hkewift adorned with halls and Chelfea. H E polite, and courteous to Chelidonias ftrangers, but very fuperftitious. CHEILIDONIAS, according to Pliny, an anniver- fary wind, blowing at the appearance of the fwallov^s; otherwife the Favonius, or Zephyrus. CHELIDONIUM, Celandine, and Horned or PRICKLY POPPY : A genus ot the monogynia order,, belonging to the pentandria clafs of plants ; and in the natural method ranking under the zych order, Rhaadea.- The corolla is tetvapetalous, the calyx diphyllous, the filiqua unilocular and linear. There are fix fpecles, none of which are remarkable for their beanty ; but one of them, uiz. the majus, is an article in the materia inedica It grows on old walk, among: rubbifli, and in wafle lhady places. The herb is of a bluilh green colour; the root of a deep red ; and both contain a gold-coloured juice : their fmell Is > difagreeable, the taifcc foniewhat bllteriih, very acrid, burning and biting the mouth ; the I'oot is the moft acrid. The juice takes off warts; cures tetters,, ring-worms, aud the itch; and, diluted with milk,, it confiimes opaque white fpots on the eye. — Horfes, cows, goats, and fwine, refufe to eat the herb. CHELIDONIUS. lapis, in natural hiflory, a flone faid by the ancients to be found in the ftomachs of young fwallows, and greatly ciied up for its virtues in the falling-ficknefs ; but, from their dcfcription, it appears to be only a fpecies of lycodontes, or bufo- nitai. See Lycodontes, and Bufonit.^;. CHELM, a town of Poland, capital of a palatinate of the fame natne. It is fituated in the province of Red Ruffia. E. Eong. 23. 30. N; Lat. 51. 25. CHELMSFORD, the county town of Effex, fitua- ted on the river Chehner, in E. Long. o. 30. N. Lat» 51. 40. It fends two members to parliament. CHELONE, in botany : . A.genus of the ai»g!ofper" mia order, belonging to the didynamia clafs of plants } open galleries fupported by pillars, and paved with and in the natural method ranking under the 40th or large fliig-ftones for the convenience of thofe who are fond of walking ; and the lake itO:'! is interfered with caufeways cafed with cut-ftone, openings covered with bridges being left In them for the pafiage of boats. In the middle are two iflands with a temple and feveral pleafure-houfes, and the emperor has a fmall palace In the neighbourhood. The city is garrlfoned by 3000 Chinefe and as many Tartars, and has under its jurif- diftion feven cities of the third clafs; 2. Hou-tcheou- fou is alfo fituated on a hike, . and manufaftures an in- credible quantity of filk, infomuch, that the tribute of a. city under Its jurifdiftlon amounts to more than 500,000 ounces of filver, 3. Ning-po-fou, by Euro- peans called Llampo, is an excellent port,.oppofite to Jiipan. Eighteen or twenty leagues from it is an ifland called Tcheou-chan, where the £nglilh firft laud- ed on their arrival at China. 4. Ning-po is remarkr able for the filk manufactured there, which is much ciTeemed in foreign countries, efpeclally Japan, where it is exchanged for gold, filver, and copper. 5. Chao- hing-fou, fituated in an extenfive and fertile plain, is re- markable for a tomb about half a league diftant, which Ib faid to be that cf Tu. The people of this province are faid to be the moft verfed in chicanery of any in China. 6. Tchu-tcheou-fou, remarkable for ha- y'nifr in its neighbcurhood pines of an extraordinary fcze, capable of containing 4c raeu lu theix trunks. The 4- der, PerJonaU. The calyx is quinquepartite; the rudi- ment of a fifth filament among the higheft ftamina, the capfule bilocular. There are three fpecies, Wk. the Gla- bra, theHirfuta, and the Penftemon. They are natives of North America ; and are herbaceous flowery perennials, . with upright ftalks two feet high,; decorated with fpear- fhaped leaves, and beautiful fpikes of monopetalous, rin-- gent flowers, red, rofe- coloured-, blue, and purple. They ' flower from September to November, and are fome- times fucceeded by ripe feeds In this country. They are very hardy plants, and may be propagated by feedg fown in any foil or fituation ; but the two firft multi- ply fa faft by their creeping roots^ .that the feeds are ' feldom regarded. CHELSEA, a fine vlllige fituated on the- northern i bank of the river Thames, a mile weftward of Weft- minftjer, remarkable for a magnificent hofpital of In- valids and old decrepit foldiers ; and a, pleafure-houfe, , called Ranelagh, to which a -g^-eat deal of fine com- pany refort in fummer ; and .a noble botanic garden belonging: to the company of apothecaries. The royal ' hofpital of invalids was begun by Charles II. carried on by James II. and finlfhed by king William. It confifls of a vaft range of buildings, that form three- large fquares, in which there is an imconunon air of' neatncfs and elegance obfervcd. It is under the dij- - rediiou of comiuifTionero, who confiit g.enerally of the.: C II E [ Chclfca. officers of ftate and of w ar. There is a governor withi " 500 1. falary, a lieutenant governor with 400I. and f major, with 25:0^ befides inferior officers, ferjeants, coi porals and drums, with about 400 men, vvlio all d( garrifon duty ; and there are above lc,^6o out pen- fioners who receive an annuity of 7'. izs. 6d. each j all which cxpence is defrayed by n poundage dedufted from the army, deficiences being made good by par- liament. — The botanic garden is very extenfive, en- riched with a vail variety of domeftic and exotic plants, the original (tock of which was given to the 'apothecaries of London by Sir Hans Sloane. — At R-anelagh Garden and amphitheatre the enter- tainment is a fine band of mufic, with an organ and 374- ] CHE fome of the beS. voices, ajid the regale is tea and coffee. CHELTENHAM, orCHiLTEvHAM, a market town of Gloucellerihire, fsven miles north-eaftof Gloucefter. W. Long. 2. 10. N. Lat. 51. 50. It is chiefly remark- able for its mineral waters, of the fame kind with thofe of Scarborough. See Scarborough. CHEMISE, in fortification, the wall with which a baflion, or any other bulwark of earth, is lined for its greater fupport and ftrength : or it is the folidity of the wall from the talus to the flone-row. Fire-CnsMisE, a piecd of linen cloth, fteeped in a compolition of oil of petrol, camphor, and other combu- ilible matters, ufed at fea, to fet fire to an ene.ny 's velTel. Chelfert- , ham, Chemife. € HEMISTR Y 'AY be defined. The ftudy of fuch phenomena Definition. \y ]^ properties of bodies as are difcovered by varioufly mixing them together, and by expofing them to different degrees of heat, alone, or in mix- ture, with a view to the enlargement of our know- ledge in nature, and to the improvement of the ufeful arts : or. It is the fludy of the effects of heat and mix- ture upon all bodies, whether natural or artificial, with a view to the improvement of arts and natural know » ledge. Antiquity. The fcience of chemiftry is undoubtedly of very high antiquity; and, like moil other fciences, its origin cannot be traced. In fcripture, Tubal Cain, the 8th from Adam, is mentioned as the father or inllruftor of every artificer in brafs or iron. This, however, does not conftitute him a chemifl, any more than a founder or blackfmith among us has a right to that title. The name of chemifl could only belong to him, whoever he was, who.firft difcovered the method of extrafting metals from their ores ; and this perfon mull neceffarily have lived before Tubal Cain, as eve- ry blackfmith or founder mufl have metals ready pre- pared to his hand. Neverthelefs, as Tubal Cain lived before the flood, and the fcience of chemillry mufl have exifled before his time, fome have con- jeftured, that the metallurgic part, on account of its extreme ufefulnefs to mankind, was revealed to Adam 3 by God himfelf. Science j-^jg Jt vvill, Siphcas, an Egyptian, is confider- loundc . jjy the chemifls as the founder of their fcience. He was known by the Greeks under the name of Hermes, or Mercur'ius Tr'ifmegtjlus ; and is fuppofed to have lived more than 1900 years before the Chri- lllan sera. A numerous liil of this philofopher's works -is given by Clemens Alexandrinus ; but none of them are now to be found, nor do any of them appear to have been written profcfTetlly on chemillry. Two illuflrious Egyptians, of the name of Hermes, are recorded by ancient authors. The elder fuppofed to be the fame with Mi^rahn, the graridfon of Noah, the Hermes of the Greeks, and Mercury of the Ro- mans. The younger Ffermes lived a thoufand years afterwards; and is fuppofed to have rcllored the fci- ences after they had fallen into oblivion, in confe- quence of an inundation of the Nile. No lefs than 36,000 books are fald to have been written under the Bame of Hermes ; but, according to Jamblichus, a cu- ftom prevailed of infcribing all books of fcience with the name of Hermes. Some authors deny the exift- ence of Hermes, and maintain that his hiflory is alle- gorical. As the fcience of chemiftry fs fuppofed to have been Mofelfup- wellknovsn to the Egyptians, Moires, who was'ikilled pofed to be in their wifdom, is thence ranked among the number ^'^'ed in of chemifls ; a proof of whole flcill in this fcience {g ciiemiflry. thought to be, his difTolvIng the golden calf made by the Ifraelites, fo as to render it potable. Of all the Greeks who travelled into Eg\'pt in or- der to acquire knowledge, Dcmocritus alone was ad- mitted into their myfleries. The Egyptian priefts are faid to have taught him many chemical operations ; among which were the art of foftening ivory, of vi-^ trifying flints, and of imitating precious iloncs. Dr Black, however, is of opinion, that Democritus knew nothing more of thefe arts than that tf making a coavfe kind of glafs, as no mention is. particularly made of his imitating any other precious flone thtn the emeal whofe colour is green ; and the coarfer the glais the greener it is. After the time of Democritus, we mav know that confiderable improvements were made in chemiflry, as phyficlans began to make ufe of metallic preparations, as cerufe, verdegrls, litharge, &c. Diofcorides de- fcribes the diftillation of mercury fromcinnabar bymeans of an emhlc, from which, by adding the Arabic Al, Derivation^ comes the term Alembic. The art of diiliUation, how- of the wori ever, at that time, was in a very rude flate ; the ope- Alembic, ration being performed chiefly by feparating the air, and more fubtlc part of tar, from the reft of the matter. This was done by putting the matter to be diftilled in- to a vefTel, the mouth of which was covered with a . ^ wet cloth ; and by this the (Icams of afcendinfr va ^"i^'"^' , ,/,,., r 1 ° , method of pour were condenled, whica were atterwards procured (i,fl^im„g. by wringing out the cloth. No other diftillation, be- fides this kind, is mentioned by Galen, Oiibafius, ^11- an, or Paulus iEgineta. The precife time is not known when the three mine- ral acids were firll difcovered; though, as no mention is made of them by Geber, Avicenna, or Roger Bacon, it isjpiobable that they were not known in the 12th cen- 6 tury. _ 7 Pliny* ilafs-ma- 8 /Ichemy full; men- tioned by Finiiicus Maternus. aiftory. C H E M tury, Raymond LuIIy gives fome hints of his being acquainted with the marine acid ; whence it is pro- bable, that it was difcovered towards the end of the 13th, or beginning of the 14th, century. Several chemical fads are related by Pliny, particu- ountof thelarly the making ofglafs, which he afcribes to the fol- erijjin of lowing accident. *• Some merchants in the Levant, who had nitre on board their fhip, having occafion to land, lighted a fire on the fand in order to prepare their food. To fupport their veflels they took fome of the lumps of nitre with which their ihip was loaded ; and the fire afting on thefe, melted part of them along with the fand, and thus formed the tranfparent fubftance called glafs, to the great furpriTc of the beholders." But it is probable, that the art of glafs-making was known long before ; and it is by no means likely that it took its rife from fuch an accident. The next traces we find of chemiftry are to be ex- trafted from the extravagant p-irfuits of the Alchemijby who imagined it pofiible to convert the bafer metals into gold or filver. The firft mention we find of this ftudy is by Julius Firmicus Maternus, vv-ho lived in the beginning of the fourth century, and fpeaks of it as a well known pujfuit in his time. jEneas Blafius, who lived in the fifth century, likewiie fpeaks of it ; and Suidas explains the term by telling us, that it is the art of making gold and filver. He ttlls us, that Diocle- fian, when perfecuting the Chriftians, forbad all che- mical operations, left, his fubjtfts fliould difcover the art of making gold^ and thus be induced to rebel againft. him. He fnppofes alfo, that the Argonautic expe- rhe fable of dition was only an attempt to procure a f]' where to aiTume a new face. In our ovv-n country, time of*^ i-ord Verulam amufed himfelf at his leifure hours Paracelfus. with forming plans for promoting the fciences in ge- neral, efpecially thofe which related to the ftudy of The fcience ^""P found that chemiftry might turn ftudied by out one of the moft ufeful and comprehenfive branches .Xord Ve- of natural philofophy, and pointed out the means of its ^rulam ; improvement. A number of experiments were propo- fed by him ; but he obfervcd, that the views of che- mifts were as yet only adapted to explain their parti- cular operations on metals ; and he obferved, that, Inftead of the abftrufe and barren philofophy of the times, it was neceflary to r-ake a very large collec- tion of fafts, and to compare them with each other \ery maturely and cautiouiiy, in order to difcover the common caufes and circumitances of conneiSlion up- on which they all depend. He did not, however, make any ooniiderable diicoveriea, and his works are tedious and difagreeable to the reader. *7 A fupcrior genius to Lord Verulam was Mr Boyle, Bo\c^ ■'^^^who v.as born the very day that the former died. His circumftances vi'cre opulent, his manners agreeable ; he was endowed by nature with a goodnefs of heart ; and iiiii inclination led him entirely to tljC ftudy of nature, I S T R y. Hiftory \sluch he wa-8 beft pkafed with cultivating irt the W-iy of experiment. He confidercd the weight, fpring, and quelitie« of the air ; and wrote on hydroftatics and other fubjcfts ; and was poffeifed of that happy pene- •tration and ingenuity fo well fuited to the making of •experiments in philofophy, which ferves to deduce the moil ufeful truths from the moil fimple and feemingly iiiiigniticant fadls. As chemiftry was his favourite fcience, he fpared no pains to procure from chemifts of greateft note the knowledge of curious experiments, and entertained a number of operators conftantly about him. His difcoveries arc related in an eafy ftyle ; and though rather copious, fuited to the tafte of the times in which he lived, and free from that abfurd and my- fterious air which formerly prevailed in chemical wri- tings : nor does he betray a deftgn of concealing any thing except fome particulars which were communica- ted to him under the notion of fecrecy, or the know- ledge of which might do more harm th.m good. It is objected indeed, that he betrays a good deal of cre- dulity with regard to fatls which are given on the faith of others, and which may feem incredible ; but this proceeded from his candour, and his being little difpofed to fufpeft others. He ftiowed the neceftary connetilion between philofophy and the arts; and faid, that by attending the fhop of a workman, he learned more philofophy than he had done in the fchools for a long time. Thus his writings ftiowed an univerfal tafte for the ftudy of nature, which had now made fome advances in the other parts of the world. Agricola is one of the firft and beft authors on the i8 fubjetl of metallurgy. Being born in a village in Mif- Chemiftry nia, a country abounding in mines and metallurgic ^^^^^^^^^^^j^ works, he defcribed them exaftly and copioufly. He fcurity. was a phyfician, and cotemporary with Paracelfus, but of a charafter very diff"cjent. His writings are clear and inftru6live, as thofe of Paracelfus are obfcure and ufelefs. Lazarus Erker, Schinder, Schlutter, PL-nktl, &c. have alfo written on metallurgy, and defcribed the art of aftaying metals. Anthony Neri, l)r Mer- ret, and the famous Kunkel (who difcovered thephof- phorus of urine), have defcribed very fully the arts of making glafs, enamels, imitations of precious ilones, &c. : but their writings, as Vv-ell as thofe cf fucceeding chemifts, are not free from the illufions of alchemy; fo true it is, that an obftinate and inveterate malady ne- ver difappears at once, without leaving traces behind. In a fliort time, however, the alchemical phrenzy was attacked by many powerful antagonills, who contri-i buted to refcue the fcience of chemiftry from an evil which at once difgraced it and retarded its progrefs. Among thefe, the moft diftinguiftied are Kircher a Je» fuit, and Conringius a phyfieian, who wrote with much fuccefs and reputation. About the year 1 650 the Royal Society was form- ^9 ed by a number of gentlemen who were unwilling to^-^^^j^^^ engage in the civil wars ; and being ftruck with the ti^uudcd. extenilve views of Lord Verulam and Mr Boyle, con- tributed to the expence of coftly experiments. This example appeared fo noble, and the deftgn fo good, that it has been followed by all the civihzed ftates of Europe, and has met with the prote6lion of their re- fpedlive fovereigns ; and from thefe chemiftry has re- ceived confiderable improvements. In France, Geof- froy, Lemery, Reaumur, 5cc. came to be diftinguilh- ed; Theory. ed ; and In Germany Margraaf, Pott, and others, have made a confiderable figure .in thofe Ibcieties. Kunc- kel, Begar, Stahl, and Hoffman, &c. have done great fervice to fociety, by introducing new arcs, and the nu- 50 merous improvements they have made. Oftheim- The chemifts who have made a figure in Germany provements j^j^ J France are more in number than thofe whom our different ^^^^^ has produced. In France, the fociety was en- rations ill couraged by the fovereign ; and in It they have diveft- chemiftiy. ed themfelves of that myfterlous air which was afFecl- ed in former ages. In Germany, the riclmefs of the country, and the great variety of mines, by turning the attention of chemifts to tlie metals, have given that alchymiftical air to their writings which we obferve in them. The number of thofe who have applied them- CHEMISTRY. felves to chemiftry is very fmall In England, owing to the great improvements made by Sir Ifaac Newton in the fciences of aftronomy and optics ; which, by turn- ing the general attention that way, has occafioned vs'hat may be called a negleft of chemiftry. But if their number be inconfiderable, they are by no means infe- rior in merit and fame. The name of Boyle has always been held in the higheft efteem, as well as that of Hales, for the analyfis he has made of the air. Sir Ifaac Newton alone has done jnore to the eftabliihing a ra- tional chemical theory than ever was done before. C9 late, the tafte for the ftudy has became more general, and many ufeful books have appeared ; fo that it is to be hoped we fliall foon excel in this branch of fcience^ as we have done in all the reft. 377 Part I. THEORY of CHEMISTRY. 11 Perfedl Theory, what. ObjeCls of Chemiftry, Siippo(it!<>n f)f e'emeiirs the origin of alchtm) . ACCORDING to the definition we have given of this fcience, the theory of it ought to confift in a thorough knowledge of all the phenomena which refult from every poffible combination of its objefts with one another, or from expofing them in all poffible ways to thofe fubftances which chemifts have found to be the moft aftive In producing a change. So various, how- ever, and fo widely extended are the objefts of che-< miftry (comprehending all terreftrlal bodies whatever), tliat a knowledge of this kind is utterly unattainable by man. The utmoft that can be done in this cafe is, to give fome account of the phenomena which accompany the mixtures of particular fubftances, or the appearances they put on when expofed to heat ; and thefe have been already fo well afcertaincd, that, they may now be laid down as rules, whereby we may, with a good deal of certainty, judge of the event of our experiments, even before they are made. Here we muft obferve, that though the obje^^s of chemiftry are as various as there are different fubftan- ces in the v.-hole fyftem of nature, yet they cannot all be examined with equal eafe. Some of thefe fub- ftances a6: upon others with great violence ; and the greater their activity, the more difhcultly are they themfelves fubjefted to a chemical examination. Thus, fire, which is the moft aftlve body in nature, is fo little the fubjeft of examination, that it hath hi- therto baffled the ingenuity of the greateft phllofo- phers to underftand Its compofition. This fubftance, therefore, though it be the principal if not the only agent In chemiftry, is riot properly an objecl of It, be- caufe It cannot be made a fubjeft of any chemical ope- ration. It hath been cuftomary to confider all bodies as com- pofed of certain permanent and unchangeable parts called elements ; and that the end of chemiftry was to refolve bodies into thefe elements, and to recompofe them again by a proper mixture of the elements when fo feparated. Upon this fuppofitlon the alche- mifts went ; who, fuppofing that all bodies were c©m- pofed of fait, fulphur, and mercury, endeavoured to find out thepr^l^ortions in which thefe exifted In gold, and then to form that metal by combining them in a fimilar manner. Had tliey taken care to afcertain the real exiftence of their elements, and, by mixing them together, compofed any one metal v/hatever, though Vol. JV. Part I. but a grain of lead, the leaft valuable of them all ; their pretenfions would have been very rational and well founded ; but as they never afcertained the exift- ence of fuch elementaiy bodies, it is no wonder that their labours were never attended with fuccefs. *4 Another fet of elements which were as generally '^f I'^^y''^ received, and indeed continue to be fo in fome mea- fure to this da)-, are fire, air, earth, and water. — This doftrine of elements was ftrenuoully oppafed by Mr Boyle ; who endeavoured to prove, that fire was not an element />fr fe^ but generated merely from the motion of the particles of terreftrial bodies among one another; that air was generally produced from the fub<- ftance of folid bodies ; and that water, by a great num- ber of diftlUatlons, was converted into earth. His ar- gun-tcnts, however, concerning fire were not at all ccn- clufive ; nor doeB the expulfion of air from fixed bo- dies prove that any of their folid parts were employ- ed in the compofition of that air ; as later difcoveries have fliown that air may be abforbed from the external atmofphere, and fixed in a great number of folid fub- ftances. His afTertion concerning water deferves much confideration, and the experiment is well worth re- peating ; but it does not appear that he, or any other perfon, ought to have relied upon the experiment which was intended to prove this tranfmutatlon. The faft was this. Having defigned to try the pofTiblllty of reducing water to earth by repeated diftlUations, he diftilled an ounce of water three times over himfelf, and found a fmall quantity of earth always remaining. He then gave it to another, who diftilled it 197 times. Th& amount of earth from the whole diftUlatlons was fix drams, or :|:ths of the quantity of water employed ; and tills earth was fixed, white, and infoluble in wa- ter. — Here it is evident, that great fufplcions muft lie agalnft the fidelity of the unknown operator, who no doubt would be weaned out with fuch a number of diftillatlons. The affair might appear trivial to him ; and as he would perhaps know to which fide Mr Boyle's opinion inclined, he might favour It, by mix- ing fome winte earth with the water. Had the ex- periment been tried by Mr Boyle's own hand, his known character would have put the matter beyond a doubt. The decompofitlon of water, however, In another way, by the combination of one part of it with the 3 B phio- 578 C H E M I S T tl y. Theory* 25 phlogiftic, and another with the earthy part of a metal, is now well afcertained, and the experiments which led to the difcovery are treated of under the articles Aerology and Water. JSxiftenceof Even the exiftence of earth as an element appears elements as dubious as that of the others ; for it is certain that is no fpecies of earth whatever, from which we can produce two diflimilar bodies, by adding their o- ther component parts. — Thus, the earth of alum has all the charafters of fimplicity which we can defire in any terreilrial fubftance. It is white, infipid, inodo- rous, and perfeflly fixed in the fire ; neverthelefs, it feems to be only an clement of that particular body called alum ; for though alum is compofed of a pure earth and vitriolic acid joined together, and Epfom fait and felenite are both compofed of a pure earth com- bined with the fame acid ; yet by adding oil of vitriol to the earth of alum, in any poflible way, we (hall ne- vevbe able to form either Epfom fait or felenite. In like manner, though all the imperfeft metals are com- pofed of inflammable matter joined v\'ith an earthy ba- ils ; yet by adding to earth of alum any proportion we pleafe of inflammable matter, we fhall never pro- duce a metal ; and what is fl;ill more mortifying, we can never make the earthy bafis of one metallic firb- Itance produce any other metal than that which it ori- ginally compofed. Elements A little confidcration upon the fubjeft of elements receffarily will convince US, not only that no fuch bodies have ever invilible. been difcovered, but that they never will ; and for this plain reafon, that they muft be in their own nature invifible. — The component parts of any fubfl;ance may with propriety enough be called the elements of that fubflance, as long as we propofe carrying the decom- pofition no farther ; but thefe elements have not the leaft property refembling any fubfl:ance which they compofe. Thus, it is found that the compound fait called fal ammoniac^ is formed by the union of an acid and an alkali : we may therefore properly enough call thefe two the elements of fal ammoniac ; but, taken fe- parately, they have not the leaft refemblance to the \5ompound, which is formed out of them. Both the acid and alkali are by themfelves fo volatile as to be capable of diffipation into an invifible vapour by the heat of one's hand ; whereas, when joined together, they are fo fixed as almoft to endure a red heat with- out going o'S. If, again, we were to feek for the ele- ments of the acid and alkali, we muft not expeft to find them have any properties refembling either an acid or an alkali, but others quite diflferent. Any com- mon element of all bodies muft therefore be a fubftance which has no property fimilar to any other in the whole fyftem of nature, ami confequently muft be impercep ■ tible. * fition above-m.entioned four elements, viz. fire, con«:rn!n2 aii*> earth, and water, a kind oi ffth element has ge- phlogifton. neially been added, but not ufually diftinguiftied by that name, though it has apparently an equal, if not a g"reater, right to the title of an element than any of the others. This fubftance is called the phlogijlon^ or inflammable principle;' on which the ignition of all bodies depends. The exiftence of this element was firft afTerted by Stahl, and from him the opinion has been derived to other chemifts : but of late a new dodlrine was broached by M. jLavoifier, who. denies the exift- ence of phlogifton altogether. Though none of thefe Of the fubftances therefore are properly the objefts of che- ^£ miftry, yet as they have fo much ingroffed the atten- _ , ' ^ j tion of modern chemifts, we lhall here give an ac- count of the moft remarkable theories that have ap- peared concerning them. Sect. I. Of the Element of Fire. The opinions concerning the element of fire may be divided into two general claffes; the one confidering it as an eff"e(5l, the other as a caufe. The former is Two gene- maintained by Lord Bacon, Mr Boyle, and Sir Ifaac j^'g^*^""^"^^ Newton ; whofe refpeftable names for along time gave fuch a fanftion to this theory, that it was generally looked upon as an eftablifhed truth. Some learned men, however, among whom was the great Dr Boer- haave, always diffented, and infifted that fire was a fluid univerfally diffufed, and equally prefent in the frozen regions of Nova Zembla as in a glafs-houfe furnace, only that in the latter its motion made it confpicuous^j and by fetting it in motion in the coldeft parts of the world, its previous exiftence there would be equally demonftrable as in the furnace above-mentioned. 29 Lord Bacon defines heat, which he ufes as a fynony- Lord Ba- mous term with fire, to be an expanfive undulatoi y mo- * tion in the particles of a body, whereby they tend with ° fome rapidity towards the circumference, and alfo a little upwards. Hence, if in any natural body you can excite a motion whereby it fliall expand or dilate itfelf, and can reprefs and direft this motion upon it- felf in fuch a manner that the motion fhall not proceed uniformly, but obtain in fome parts and be checked in others, you will generate heat or fire. ,0 The fame opinion is fupported by Mr Boyle in the Mr Eoyle's' following manner : " The produftion of heat difcovers op'"'"". nothing, either in the agent or patient, but motion, and its natural eff"e£ls. When a fmith brillvly hammers a fmall piece of iron, the metal thereby becomes exceed- ingly hot : yet there is nothing to make it fo, except the motion of the hammer imprefiing a vehement and varloufly determined agitation on the fmall parts of the iron ; which, being a cold body l;efore, grows hot by that fuperinduced motion of its fmall parts : firft, in a more loofe acceptation of the word, with regard to fome other bodies, in comparifon of which it was cold before ; then fenfibly hot, becaufe the motion in the parts of the iron is greater than that in the parts of our fingers ; at the 'fame time that the hammer and an- vil, by which the percufTion is communicated, may, on account of their magnitude, remain cold. It is not neceflary, therefore, that a body fliould itfelf be hot in order to communicate heat to another." 31 The arguments made ufe of by Sir Ifaac Newton Sentimentj- are not intended pofitively to eftabiifti any kind of the- -^^^^^^^^ ory relating to fire, but are to be found in a conjefture, pubUfhed at the end of his Treatife on Optics, con- cerning the nature of the fun and ftars. " Large bo- dies (he obferves ) preferve their heat the loHgeft, their parts heating one another ; and why may not great, denfe, and fixed bodies, when heated beyond a certain degree, emit light fo copioufly, as, by the emiflion and reaftion of it, and the refleftions and itfraftions with- in the pores, to grow continually hotter, till they arrive at fuch a period of heat as is that of the fun ? Their parts Theory. CHEMISTRY. 379 3* Fire now generary allowed to he an ele- <;t fe Z7, Tv- o other theories m- ftituted. 34 In what they dif- fer from the for- mer. 35, General account of Dr Black's and Dr Ir- vine's the- ory. parts may be further prefei-ved from fuming .away, not only by their fixity, but by the vaft weight and denfity of the atmofphere incumbent on them, ftrongly com- prefling them, and condenfing the vapours exhaled from them. Thus we fee, that warm water, in an exhaufted receiver, fhall boil as vehemently as the hotteft water expofed to the air ; the weight of the incumbent atmo- fphere in this latter cafe keeping down the vapours, and hindering the ebullition till it has received its ut- moii degree of heat. Thus alfo a mixture of tin and lead, put on a red hot iron m vacuo, emits a fume and flame ; but the fame mixture in the open air, by i*afon of the incumbent atmofphere, does not emit the leaftfen- fible flame." In confequence of thefe experiments, Sir Ifaac conjedlures, that there is no eflential diilinftion betwixt fire and grofs bodies ; but that they may be converted into one another. " Fire (he fays) is a body heated fo hot as to emit light copioufly ; for what (fays he) is a red hot iron but fire ?" The hypothefes of thefe great men produced long and violent difputes, which were never decifively fet- tled : The difcoveries in eleftricity, however, furnifiied fuch additional ftrength to the followers of Dr Boer- haave, that fire is now believed to be an element and fluid diftindt from all others, by at leaft as many as e- fpoufe the contrary fyfliem; but the queilion is not de- cided. Whether ihe fire itfelf is to be confidered as the agent ? or. Whether its aAion is to be derived from the principles of attraction and repulfion, the na- tural agents fuppofed to influence other material fubftahces ? This has produced two other fyfl:ems of a kind of mixed nature, in which heat or fire is confidered as a fubfl:ance difl;in6l from all others, but which a€ts in other bodies according to its quantity. Thefe fyftems have been promulgated by Dr Black of Edinburgh and Dr Irvine of Glafgow. They differ from the opinions of Mr Boyle, Lord Ba- con, and Sir Ifaac Newton, in fuppofing heat to be a fluid difl:in£t from aU other material fubftances ; and they alfo diflfer from the hypothefis of Dr Boerhaave, Lemery, and others, in fuppofing ditferent terreftrial fubftances to be hot according to the quantity of fluid contained, and not according to the force with which it moves in them. Dr Black is of opinion that heat, which he feems to make fynonymous with fire, exifts in two different ftates ; in one of which it affefts our fenfes and the thermometer, in the other it does not. The former therefore he calls Jenfihk heat, the latter latent heat. On thefe principles he gives the only fatisfadlory explana- tion of the phenomena of evaporation and fluidity that has yet appeared, as fhall afterwards be more fully explained. At prefent we fliall only obferve, that, ac- cording to the theory of Dr Black, heat or fire it- felf feems to be the agent ; but, according to that of Dr Irvine, as far as we can gather it from the treatifes of Dr Crawford and others, the principles of attrac- tion and repulfion are the agents by which heat, as well as other bodies, is influenced. Thus, odi the princi- ples of Dr Black, we fay, that water is converted into vapour by a quantity of heat entering into it in a la- tent ftate, and thereby rendering it fpecifically lighter than the atmofphere : according to the principles of Dr Irvine, we fay, that water is converted into vapour by having its capacity for attradling h^at from the atmofphere increafed. So that, according to the former, Of the the abforption of heat is the caw/s ; according to the ^'^"^p^jf^"' latter, the effect, of its converfion into vapour. ^ Dr Crawford, in his Treatife oa Heat, publlfh- ed in 1788, informs us, that heat, in the philo-Dr Irvine's fophical fenfe of the word, has been ufed to ex- theory^ ex- prefs what is frequently called the element of Jire, in ^^'craw- the abftract, without regard to the peculiar effefts f^ij. which it may produce in relation to other bodies. 37 This, with Dr Irvine, he calls abfolute heat ; and the Abfolute external caufe, as having a relation to the _ eff"e6ls it he^^ de- produces, he calls relative heat. " From this view of ' the matter (fays he), it appears, that abfolute heat ex- prefles, in the abftradl, that power or element which, when it is prefent to 2i certain degree, excites in all ani- 3? mals the fenfation of heat ; and relative heat exprefles Relative the fame power, confidered as having a relation to''"^^^ the effefts by which it is known and meafured. 3^ " The effeAs by which heat is known and meafu- How di- red are three ; and therefore relative heat may admit of ''i^'^'^' three fubdivifions. i. This principle is known by the peculiar fenfations which it excites in animals. Con- fidered as exciting thofe fenfations, it is called fenjihle , heat. 2. It is known by the effeft which it produces upon an inftrument that has been employed to meafurc it, termed a thermometer. This is called the temperature of heat in bodies. 3. It has been found by experiment, that in bodies of different kinds the quantities of ab- folute heat may be unequal, though the temperatures and weights be the fame. When the principle of heat is confidered relatively to the whole quantity of it contained in bodies of different kinds, but which have 40 equal weights and temperatures, I fliall term it com- Comparn- parative heat. If, for example, the temperatures and'^J^,^^^^*^ weights being the fame, the whole quantity of heat in water be four times as great as that of antimony, the comparative heats of thefe fubilances are faid to be as four to one." 41 In order to have a. proper conception of what isExperi- meant by a difference in abfolute heat, when the tern- J^^^n^s peratures are the fame, it will be neceffary to relate gj^^fj^ fome experiments, by which Dr Black was firft led to led to the the difcovery of latent heat. He obferves, that when difcoyery two equal maffes of the fame matter, heated to difFe- ^^g^^*^^""^ rent degrees, are mixed together, the heat of the mix- ture ought to be an arithmetical mean betwixt the two extremes. This, however, only takes place on mixing hot and cold water together ; but if inftead of cold water we take ice, the cafe is remarkably different. Here the temperature of the mixture is much below A quantity the arithmetical mean, and a quantity of heat is appa- ^j^'^f ^^"j^^ rently lofl:. Now we know that the temperature of 1"'^*^^^ ' ice newly frozen is generally 32 degrees of Fahrenheit; fuppofing therefore the temperature of the water which diffolves it to be 1 20=, the arithmetical mean is ' 7 1 ; but if the mixture indicates a temperature only ©f 60°, then we mud fuppofe that the ice contained 1 1"^ of heat lefs than was indicated by the thermometer ; and confequently, that water at 32° contains 1 1° more of abfolute heat than ice at 32 ^. 43 The fame thing is made ftill more evident from the Great condenfation of vapour. The fluid of water is not ca- ^"^"'jj^'^ pable of fuftaining a great degree of heat ; and 212° produce ! of Fahrenheit is the utmoil it can be made to bear, by the con- without an extraordinary degree of preffure, as in Pa- denfation 3B2 pin's ^f^^P""^* 44 Dr Black's method i f calculating it. 4y Mr Watt's experiment on the di- ftillafion of water in •jacuo. Difference of abfolute heat in dif- ferent fluids. 47 Thinneft fluids con- tain tlie greatell ijuantity of heat. 48 Great dlf- fcicnre be- twixt the calculations of Drs Cleg- horn and CiBVvford. 49 Crawford's account of fenfible heat. C H E M pia's digefter, or the admixture of faline fubftances : the temperature of the fteam emiuted by it therefore never can exceed 2 1 2 \ except in the cafes juft men- tioned ; and it is often capable of bearing a great de- gree of cold without being condenfed. When the con- dcnfation takes place at laft, however, 5I very confi- dtrable degree of heat is ahvays produced ; and Dr Black has fuown, that, in the condenfation of fteam by the refrigeratory of a common Itill, as much heat is communicated to the water in the refrigeratory as ■would be fufficient to make the water which comes over as hot as red hot-iron, were it all to exift in a fen- fible ftate. His method of making the calculation is very ealy. For, fuppofmg the refrigeratory to con- tain 100 pounds of water, and that one pound has been diHilled; if the water in the refrigeratory has received 10 degrees of heat, we know that the dillilled pound has parted with 1000. If in paffing through tl-.e worm of the refrigeratory, it has been reduced to the tempera- ture of 50° of Fahrenheit, having been at 212° whe:i it entered it, then it has loft only 1 62° of fenlible heat ; all the rell communicated to the water of the refrrgerato- rj amounting to more than 800^, having been con- tained in a latent ftate, and fuch as could not then af- fect the tliermometer. This experiment was tried by Mr Watt in a manner ftill more ftriking, by a diftilla- tion of water in vacuo. Thus the fteam, freed from the preifure of the atreofphere, could not conceive fuch a degree of lenuble heat as in the common method of di- ftilling. It Came over therefore with a very gentlewarmth, fcarce more than what the haiui cotdd l)ear i neverthe- lefs it had abforbed as much heat as though the di- ft:illatioH had been performed in the common way; for the refrigeratory had 1000 degrees of heat communi- cated to it. The difference of abfolute heat is likewlfe percep- tible betwixt any two bodies of different denfity, water and mercury for inftance : and in comparing thefe, it will always be found that the thinneft fluids contain the greateft quantity of abfolute heat ; as water more than mercury, fpirit of wine more than water, ether more than fpirit of wine, and air more than any of them. Dr Black having brought equal bulks of mercury and water, the former to a temperature of 50 degrees high- er than the latter, found that, on mixture, there was a gain of only 20 degrees above the original; but on rever- fing the experiment, and heating the water 50 degrees above^the mercury, there was a gain of 30 degrees on the whole. " Hence (fays Dr Cleghorji in his thefts de Igne) it appears, that the quantity of heat in water is to that in mercury, when both are of equal tempera- tures, as 3 to 2." Dr Crawford, however, tells us, that " the fame quantity of heat which raifes a pound of water one degree, will raife a pound of mercury 28 degrees ; whence it follows, that the comparative heat of water is t© that of mercury as 28 to i : and confe- quently, the alterations which are produced in the temperatures of bodies by given quantities of abfolute heat, may properly be applied as a meafure of their comparative heats ; the alterations of temperature and the comparative heats being reciprocally proportional to one another. " Senhble heat (continues DrCrawford) dependspart- ly on the ftate of the temperature, and partly on that of I S T R Y. Theory. the organ of feeling; and therefore if a variation be pro- Of the duced in the latter, the fenftble heat w;ll be different, Element though the temperature continue the fame. Thtis water , j at the temperature of 62° of Fahrenheit appears cold to a warm hand immerfed in it; but on the contrary, that fluid will appear warm if a hand be applied to it which has a lower degree of heat than 62"". For this reafon, the thermometer is a much more accurate meafure of heat than the fenfes of animals. As long, however, as the organs remain unchanged, the fenfible heat is in proportion to the temperature ; and therefore thofc term's have generally been confidered as fynonymous. On this fubjeft Dr Reid obferves, that until the ratio Dr Reid*s between one temperature and another be afcertained by obfervati(«i experiment and indudlion, we ought to confider tern- '^"""''"^"S perature as a meafure which admits of degrees, but not [u^j*^'*" of ratios ; and coiifequently ought not to conclude, that the temperature of one body is double or triple to that of anather, unlefs the ratio of different tempera- tures were deterniined. Nor ought we to ufe tlie ex- preffions of a double or triple temperature, thefe being expreffioRS which convey no diftindt meaning until the ratio of difterent temperatures be determined." In making experiments on the com.parative quanti- Difference ties of heat in different bodies, our author chooles ra- betwixt ther to ufe equal iveights than equal bulks of the fub- ^be calcula- ftances to be compared. Thus he found the cempa- 1^""* °^ rative heat of water to be to that of mercury as 28 tOan^^^ack. I by weight, and 2 to i by bulk ; which differs very confiderably from the conclufion of Dr Black, who makes it only as 3 to 2, as has been already men- tioned. From the differences obferved in the quantities of CapfcUics abfolute heat contained in different bodies, our author for contain- concludes, that *' there muft be certain effential diffe-'»g heat rences in the nature of bodies ; in confequence of ^'plained, which, fome have the power of coUeding and retaining that element in greater quantity than others.'' Thefe different powers he calls the capacities for containing heat. Thus, if we find by experiment that a pound of water contains four times as much abfolute heat as diaphoretic antimony, when at the fame temperature, the capacity of water for containing heat is faid to be to that of antimony as 4 to i. " The temperature, the capacity for containing heat, How the and the abfolute heat contained, may be diftinguifhed capacity, from each other in the following manner : tcmpera- " The capacity for containing heat, and the abfo- gJJJjj,'^ lute heat contained, are diftinguifhed as a force diftindthcat, arc from the fubjeft upon which it operates. When we to be di- fpeak of the capacity, we mean a power inherent in itinguilhed, the heated body ; when we fpeak of the abfolute heat, we mean an unknown principle which is retained in the body by the operation of this power ; and when we fpeak of the temperature, we eoufider the Unknowri principle as producing certain effefts upon the ther- mometer. " The capacity for containing heat may continue unchanged, while the abfolute heat is varied without end. If a pound of ice, for example, be fuppofed to retain its fohd form, the quantity of its abfolute heat will be altered by every increafe or diminution of its fenfible heat : but as long as its form continues the fame, its capacity for receiving heat is not affeded by 'heory. G H E M 55 [Fire cor- tained in Voiliesj art !y hy iU attrr.tSion to them. an alteration of temperature, and would remain un- changed though the body were wholly deprived of its heat." In the courfe of his work, Dr Crawford obfervcs, ravvford's that " he has not entered into the inquiry which has 1} inion been fo much agitated among the Englirn, the French, oncernmg ^^^^ ^y^^ German philofophers, Whether heat be a fub- ibiliiid. Ji'i'"^^ or a quality ? In fume places indeed he has ufed expreflions which feem to favour the former opinion ; but his fole motive for adopting thefe was, becaufe the language feemed to be more iimple and natural, and more confonant to the fafts which had been eftablifhed by experiment. At the fame time, he is perfuaded that it would be a very difficult matter to reconcile many of the phenomena with the fuppofition that heat i* a quality. It is not eafy to conceive, upon this hy- pcthefis, how heat can be abforbed in the procefles of fufion, evaporation, combuiHon ; how the quantity of heat in the air can be diminifhed, and that in the blood increafed, by refpiration, though no fenfible heat or cold be produced. *• Whereas, if we adopt the opinion that heat Is a di- flinft fubitance, oran element fui generis y the phenome- na will be found to admit of a fimple and obvious in- terpretation. •* Fire will be confidered as a principle ; which is diilributed in variots proportions throughout the dif- ferent kingdoms of nature. The mode of its union with bodies will refemble that particular fpccies of union, wherein the elements are combined by the joint forces of preffure and attraftion. Of this kind is the combination of fixed air and Avater ; for fixed air is ^Y^ Pfjj|-y^^ retained in water partly by itsattraftion for that fluid, ftf^heex- aiid pai-tly by the prefiure of the external air ; and if tcrnal fluid, either of thefe forces be dimini^died, a portion of the fixed air efcapcs. In like manner, it may be con- ceived that elementary fire is retained in bodies, partly fcy its attraftion to thefe bodies, and partly by the a^lion of the furroanding heat ; and in that cafe a portion of it will be dilengaged, either by diminifhing the attraftive force, or by leffcning the temperature of the circumambient medium. If, however, fire be a fubftance which is fubje6^ to the laws of attraction, the mode of its union with bodies feems to be diffe- rent from that which takes place in chemical combi- nation: for, in chemical combination, the elements ac- quire new properties, and either wholly or in part lofe thofe by which they were formerly charadlerized. But we have no fufficient evidence for belie ving that fire, in confequence of its union with bodies, does, in any inllance, lofe its diftinguiHiing properties." Dr Berkenhout, in his Firft Lines of the Theory and Praftice of Philofophical Chemiftry, informs us, *eii!inf? the that " heat, or the matter of heat, is by Scheele and nature of Bergman fubftituted for fire, which they believe to be the aftion of heat when increafed to a certain degree. Tlie firft of thefe celebrated chemilb believed this mat- ter of heat to be a compound of phlogifton and pure air. He was certainly miftaken. It feems more phi- lofophical to confider heat as an eJeBy of which fire is the fole caufe. " Heat I confider not as a diftinft fubftance, but as ^°"c' ^i'^ ^" effedl of fire, fixed or volatile; in botli which llates^ fire feems to exift in all bodies, folid and fluid. Fixed fire I believe to be a conftituent part of all bodies. 56 Dr Berkei iiout's opi- lleat. €is divi nto fixed i»nd vola aie. I S T R Y. 381 and their fpeclfic heat to depend on the quantity of '^'^ fixed fire in each. This fixed, this latent fire, cannot ^'^^^^^^J^'f be feparated from the other conftituent parts of bo- ' ^ dies but by their decompofition : it then becomes vo- latile and incoercible. If this hypothefis be true, fire exiils, in all natural bodies that contain phlogifton, in three different ftates: i. In that volatile ftate in which it perpetually flucluates between one body and an- other. 2. Combined with an acid, probably in the form of fixed inflammable air or phlogifton. 3. Un- combined and fixed, as a conftituent principle, deter- mining the fpecific heat of bodies. " Pure (or volatile) fire is diftinguiihed by the fol-Pr.re orta lowing properties, i. It is effentially fluid, invifible, Iari!e fre and without weight. 2. It is the immediate caufe of all fluidity. 3. It penetrates and pervades all bodies on the furface of the earth, and as far beneath the fur- face as hath hitherto been explored. Water hath ne- ver been found in a congealed ftate in the deepeft mines. 4. It has a conftant tendency to difi"ufe itfelf equally through all bodies, howfoever different in point of denfity. A marble flab, a plate of iron, a decanter of water, and a lady's muff, at the fame diftance from the fire, and other external circumftances, being equal, poflefs an equal degree of heat, which is precifely that of the atmofphere in which they ftand. 5. It is per- petually in motion from one body to another, and from different parts of the fame body, becaufe external circumftances are continually varying. 6. In fluctu- ating from one body to another, it produces a conftant vibration of their conitituent parts ; for all bodies ex- pand and contradi in proportion to the quantity of fire they contain. 7. Accumulated beyond a certain quantity, it eff'efts the diffolution of bodies, by forcini^ their conftituent parts beyond the fphere of mutual attraction, called the attraction of cohejion^ which is the- caufe of folidity. Hence the fovereign agency of -fire in chemical operations." Dr Crawford, befides the opinions already quoted, -^^ tells us, that fire, in the vulgar acceptation of tlie ^J^^jV'^j^^"* word, expreffes a certain degree of heat accompanied fin ir ion of with light ; and is particularly applied to that heat fire, and light which are produced by the inflammation of combuftible bodies. But as heat, when accumulated in a fufScienl quantity, is conftantly accompanied with light ; or, in other words, as fire is always produced by the increafe of heat, philofophers have generally confidered thefe phenomena as proceeding from the fame caufe : and have therefore ufed the word fire to exprefs that unknown principle, which, when it is pre- fent to a certain degree, excites the fenfation of heat alone ; but, when accumulated to a greater degree, renders itfelf obvious both to the fight ajid touch, or produces heat accompanied with light. In this fenfe, the element of fire fignifies- the fame thing with abfa- lute heat. Having premifed thefe generaJ definitions and re- marks, he gives the properties of lireat in the following words : "I. Heat has a conflant tendency to diffufe itfelf over do all bodies till they arc brought to the fame tempera- * ture. Thus it is found by the thermometer, that ifto'aiff!!? two bodies of different temperatures are mixed toge- itfelf e- ther, or placed contiguous, the heat paffes from the qually over one to the other till their temperatures become equal ; ^odie», aod 6i It is con- tamed in confider- able quan- tity in all bodies. 6z Great de- gree of cold- at Glaf- gow, 6^ . In Siberia, and at Hudfon's bay. 64 Quantity of heat H- nii-ed in all bodies. Bodies uni" verfally ex- panded by iieat. C H E M I and tiiat all inafii'mate bodies, when heated and placed in a cold medium, continually lofe heat, till in proccfs of time they are brought to the ftate of the furiound- ing medium. " From this property of heat it follows, that the va- rious clafltis of bodies throughout the earth, if they were not a£led upon by external caufes, would at length arrive at a common temperature when the heat would become quiefcent ; in like manner as the waters of the ocean, if not prevented by the winds and by the at- tractions of the fun and moon, would come to an equi- librium, and would remain in a ftate of reft. But as caufes continually occur in nature to difturb the balance of heat as well as that of the waters of the ocean, thole elements are kept in a conftant flu£luation. *' II. Heat is contained in confiderable quantities in all bodies when at the common temperature of the at- mofphere. *' From the interefting experiments which were made on cold by Mr Wilfon, we learn, that at Glafgow, in the winter of the year 1780, the thermometer on the furface of fnow funk 25 degrees below the beginning of Fahrenheit's fcale. " We are told by Dr Pallas, that in the deferts of Siberia, during a very intenfe froft, the mercury was found congealed in thermometers expofed to the atmo- fphere, and a quantity of that fluid in an open bowl placed in a fimilar fituation, at the fame time became folid. The decifive experiments of Mr Hutchins at Hudfon's Bay prove, that the freezing point of mer- cury is very nearly 40" below the zero (or 0°) of Fah- renheit. From which it follows, that at the time of Dr Pallas's obfcrvation, the atmofphere in Siberia muft have been cooled to minus 40. By a paper lately tranfmltted to the Royal Society we are informed, that the fpirlt'of-wine thermometer in the open air at Hudfons Bay fell to — 42 in the winter of 1 785 ; and from the fame communication we learn, that by a mixture of fnow and vitriolic acid, the heat was fo much diminiftied, that the fpirit of wine funk to — 80, v/hich is 1 1 2 below the freezing point of water. . " Hence it is manifeft, that heat is contained in confiderable quantities in all bodies when at the com- mon temperature of the atmofphere. It is plain, how- ever, that the quantity Inherent in each individual tody is limited. This, I think, muft be admitted, whatever be the hypothefis which we adopt concerning the nature of heat ; whether we conceive it to be a force or power belonging to bodies, or an elementary- principle contained in them. For thofe who confider heat as an element, will not fuppofe that an unli- mited quantity of It can be contained in a finite body ; and if heat be confidered as a force or power^ the fup- pofition that finite bodies are aftuated by forces or powers which are infinite is equally inadmiflible. " To place this In another light, we know that bo- dies are univerfally expanded by heat, excepting In a very few inftances, which do not afford a juft objedlion to the general faft ; bccaufe. In thofe inftances, by the aAIon of heat a fluid is extricated that previoufly fepa- rated the particles from each other. Since, therefore, heat is found to expand bodies in the temperatures which fall within the reach of our obfervation, we may conclude that the fame thing takes place in all tempe- ^-^tures." S T R Y. Theory. Our author, by a fet of very accurate and laborious Of th& ' ' Elemen' of Fire. experiments, determines that the expanfions in mercury E'ement and feme other fluids are proportionable to the xjuati- tities of heat applied ; " from which (fays he) it is ^5 manifeft, that the quantities of heat in bodies are limi- Expanfu n ted, becaufe an infinite heat would produce an infinite of mercury, expanfion. t^onfftT " it is manifeft, that the number of degrees of fen - ^j^^ decrees fible heat, as meafured by the thermometer, and cfti- of heat, mated from the beginning of the fcale, muft be the fame in all bodies which have a common temperature ; for by the firft general faft It Is proved, that heat ha« a conftant tendency to difFufe itfelf uniformly over bodies till their temperatures become equal. From which It m.ay be inferred, that if a quantity of heat were added to bodies abfolutely cold, the f&me uniform difFufion would take place ; and that if a thermometer, altogether deprived of Its heat, were apphed to fuch bodies, it would be equally expanded by them, the whole of the fenfible heat which they had acquired being in- dicated by that expanfion. -g^ " III. If the parts of the fame homogeneous fub- Homoge- ftance have a common temperatuie, the quantity of "pous bo- abfolute heat will be proportional to the bulk or quan- j:^^" °l ^^'^ r mi^i • riri^u^' lame tem- tity of matter. i hus the quantity or ablolute heat in perature, two pounds of water is double that which is contained contain in one pound when at the fame temperature. quantities " IV. The dilatations and contraaions of the fluid P™* , , . , , 1-1 portionabl?. in the mercurial thermometer arc nearly proportional f^ofe of to the quantities of abfplute heat which are communi- their mat- cated to the fame homogeneous bodies, or feparated ^^c'"' from them, as long as they retain the fame form. Thus the quantity of heat required to raife a body four de- grees in temperature by the mercurial thermometer, is nearly double that which Is required to raife it two degrees, four times that required to raife It one degree, and fo In proportion." Thus we find, that Dr Black, Dr Irvine, Dr Cravv- ford, and Dr Berkenhout, agree in fpeaking of fire or heat as a fluid fubftance diftinft from all other bodies. Mr Klrwan, in his Treatife of Phlogifton, agrees in the jvir Kir- fame opinion. " Some (fays he) have thought,' tha,t wan's opf- I fhould have included the matter of heat, or elemen- ^on- tary fire. In the definition of inflammable air; but 33^^^.^"'"^ fire is contained in all corporeal fubftances, to mention it is perfedlly needleis, except where bodies diff^er from each other in the quantity of It they contain." On Caven the other hand, Mr Cavendifli, Phil. Tranf. Ixxlv. ^^jfj^.g p. I41. tells us, that "he thinks it more likely that nipn that there is no fuch thing as elementary heat :" but, as heit;^^. ""^^ ^ gives n6 reafon for this opinion, it feems probable '^^"^ fubftati^ce the greater part of philofophers either pofitively be- lieve that heat is an elementary fluid diftiniSl from all others, or find themfelves obHged to adopt a language which neceflarily implies it. The only difficulty which Difficulty now remains therefore is, to affix a proper Idea to the in defining , phrafe quanliiy of heat, which we find univerfally made the phrafe ufe of, without any thing to determine our opinions l"^^"'''^' "/ concerning it. That we cannot fpeak of a quantity of fire or heat in 'phis''phr;i{( the fame lenfe as we fpeak of a quantity of water or can.iot be any other fluid is evident, becaule we can take away ufed in the the quantity of water which any fubftance contains, common but cannot do fo with heat- Nay, in many cafes ^6^"^^^^^^'°^ are fure, that a fubftance very cold to the touch does with regan I yet to fire. f the lemenl ; Fire. if Cleg- orn's opi' ion. heory. C H E M yet contain a very confiderable quantity of heat. The vapour of water, for inftance, may be made much colder than the ufual temperature of the atmofpherc without being condenfed, when at the fame time we are certain that it contains a great quantity of heat ; and the fame may be faid of water, which, in the a£l of freezing, throws out a great quantity of heat without becoming colder; and in the a<^ of melting abforbs as much with- out becoming warmer. It is not therefore by the mere prefence or abfence of this fluid that we can determine the real quantity of this fluid ; nor does it appear that the word quantity can be at all accurately applied to the element itfelf, becaufe we have no method of mea- furing it. Dr Cleghorn, in his inaugfural diflertation De Igney throws fome light on this fubjeft, by obferving, that *' the tliermometer fhows only the quantity of heat go- ing out of a body, not that which is really contained in it :" and he alfo infifts, that *' we can neither alTent to the "opinion of Dr Boerhaave, who fuppofed that heat was diftributed among bodies in proportion to their bulks ; nor to the hypothefes of others, who imagined that they were heated in proportion to their denlities." But in what proportion, then, are they heated ; or how are we to meafure the quantity which they really contain, feeing the thermometer informs us only of what they part with? As this point is by no means afcertained, we cannot leat of bo- form a direft idea concerning the abfolute quantity lies cannot jj^^^ contained in any body; and therefore when we fpeak of quantities of this fluid, we muft in faft, if we mean any thing, think of the fenfible quantity flowing out of them ; and though we fliould fuppofe the whole of this fenfible heat to be removed, it would dill be impoflible for us to know how much remained in a la- tent ftate, and could not be diflipated. This difficulty will ftill appear the greater, if with Dr Cleghorn and others we fuppofe the fluid of heat to be fubjedl to the concerning jjjypg Qf attraction and repullion. This gentleman fuppofes, that the particles of heat (like the particles of eleftric fluid according to theFranklinian hypothefis) are repulfive of one another, but attrafted by all other fubftances. " If any body (fays he), heated beyond the common temperature of the air, is expofed to it, the heat flows out from it into the atmofphere, and diffufes itfelf equally all around till the air becomes of the fame temperature with itfelf. The fame happens to bodies fufpended in macuo. Hence it is juftly con- cluded, that there exifts between the particles of heat a repulfive power, by which they mutually recede from each other. Notwithftanding this repulfive power, however, the quantities of heat contained in different fubftances, even of the fame temperature, are found to be altogether diflFerent ; and from Dr Black's experi- ments it now appears, that the quantity of heat is fcarce ever the fame in any two different bodies: and hence we may conclude, that terrefl:rial bodies have a power of attrafting heat, and that this power is dlfler- ent in different fubftances. — From thefe principles it evidently follows, that heat is diftributed among bodies diieftly in proportion to their attrafting powers, and inverfely according to the repulfive power between the Equili- particles of heat themfelves. Sueh is the dlftribution brium of of heat among bodies in the neighbourhood of each heat^de- other, and which is called the equilibrium of heaty, be- rhe latent be meafu' '£d. 74 Cleg- horn's hy- pochefis I S T R Y. 383 caufe the thermometer fhows no difference of tempera- ture among them. For feeing the heat is diftributed ^^'j^j^^'^"' according to the attrafting power of each, the ther- ^ ' j mometer having alfo a proper attraftion cf its own, can fliow no difference in the attracting power of each ; for which reafon all bodies in the neighbourhood of each other are foon reduced to the lame tempera- ture." ~ 76 If we affent to Dr Cleghorn's hypothefis, the quan- The quair- tlty of heat contained in any fuBftance depends, in the 'i*^)' o'^^^j^^^t' firft place, on the attracting power of that fubftance, which is altogether unknown; and, in the fecond by this h)i- place, on the repulfive powers of the particles of heat pothelis. themfelves, which are equally unknown. To deter- mine the quantity, therefore, muft be impofiible. Nei- ther will the mixture of two different fluids, as in Dr Black's experiments, affift us in the leaft ; for though water, heated more than mercury, communicatesagreat- er heat to that fluid than the latter does to water } this only fhows that water more readily parts with fome part of the heat it contains than mercury does, but has not the leaft tendency to difcover the quantity contained in either. Dr Crawford, as we have already feen, calls the de- gree, or, if we may vary the plirafe, the quantity of poiuer or element (fluid, if we may fubftitute a fynony- mous word) exiliing or prcfent in any body, its abfo- lute beat; and lays down a rule for determining the pro- 77 portional quantities of heat in different bodies. ** ItDr Craw- will appear (fays he) from the experiments 1^^, j ^^f^^^ wards recited, that if a pound of water and a pound of diaphoretic antimony have a common temperature, the propor- the quantity of abfolute heat contained in the for- tional quan- mer is nearly four times that contained in the latter." — The manner in which he illuftratcs this is as fol- lows. " If four pounds of diaphoretic antimony at 20 be mixed with one pound of ice at 32, the temperature will be nearly 26 ; the ice will be cooled fix degrees, and the antimony heated fix. If we reverfe the expe- riment, the effeft will be the fame. That is, if we take fix degrees of heat from four pounds of antimony, and add it to a pound of ice, the latter will be heated fix degrees. The fame quantity of heat, therefore, which raifes a pound of Ice fix degrees, will raife four pounds of antimony fix degrees. " If this experiment be made at different tempera- tures, we fhall have a fimllar refult. If, for example, the antimony at 15, or at any given degree below the freezing point, be mixed with the ice at 32, the heat of the mixture will be the arithmetical mean between that of the warmer and colder fubftance. And fince the capacities of bodies are permanent as long as they retain the fame form, we infer, that the refult would be the fame if the antimony were deprived of all its heat, and were mixed with the ice at 32^ But it is evident, that In this cafe the ice would communicate to the antimony the half of its abfolute heat. For if 20G below frofl be conceived to be the point of total privation, the antimony will be wholly deprived of its heat when cooled to 200 degrees below 32, and the heat contained in the ice when at 32 will be 200 degrees. If we now fuppofe them to be mixed toge- ther, the temperature of the m.ixture will be half the excefs of the hotter above the ojlder,, or the ice will CHE be cooled too degrees and the antirxiony heated loo. The one half of the heat, therefore, which was con- tained in the ice previous to the mixture will be cnm- municated to the antimony ; from which it is manifeit, that after the mixture the ice and antimony muft con- tain equal quantities of ahfoluie heat. " To place this in another light, it has been proved, that the fame quantity of heat which raifes a pound of ice lis degrees will raife four pounds of antimony fix degrees. And as the capacities of bodies, while they retain the fame form, are not altered by a change of temperature; it follows, that the fame quantity of heat which raifes the ice 200 degrees, or any given number of degrees, will raife the antimony an equal number of degrees. *« A pound of ice, therefore, and four pounds of antimony, when at the fame temperature, contain vqual quantities of abfolute heat. But it appears from the third general fad (n"=67.), that four pounds of antimony contain four times as much abfolute heat as one pound of antimony ; and hence the quantity of abfolute heat in a pound of ice is to that in a pound of antimony as four to one." y^om this quotation it is evident, that, notwith- iiilufficicnt. {landing all the diftinftions which I) r Crawford has laid down betwixt abfolute heat and temperature, it is only the quantity of the latter that can be meafured ; and all that we can fay concerning the matter is, that when certain bodies are mixed together, fome of them part with a greater quantity of heat than others ; but how much they contain muft remain for ever un- known, unlefs we can fall on fome method of meafu- ring the quantity of heat as we do that of any other M I S T R Y. The or ';8 His method 79 fluid. Nlcho'lfon's Mr Nicolfon, who has coUefted the principal opl- accountof nions on the fubjeft of heat, feems undetermined whe- of hear'"'^^'' *° ^^^'^""^ ^^"^ doaWne of Boyle or of Bocrhaave on the fubjeft. "There are two opinions (fays he) concerning heat. According to one opinion, heat confifts in a vibratory motion of the parts of bodies among each other, whofe greater or lefs intenfity oc- cafions theincreafe or diminution of temperature. Ac- cording to the other opinion, heat is a fubtile fluid that eafily pervades the pores of all bodies, caufing them to expand by means of its elafticily or otherwife. Each of thefe opinions is attended with its peculiar difficul- ties. The phenomena of heat may be accounted for by either of them, provided certain fuppofitions be al- lowed to each refpeftively ; but the want of proof of the truth of fuch fuppofitions renders it very difficult, if not impoffible, to decide as yet whether heat confifts merely in motion or in fome peculiar matter. The word quantity, applied to heat, will therefore denote either motion or matter, according to the opinion made ufe of, and may be ufed indefinitely without de- termining which. Advanta- " The chief advantage which the opinion that heat pc! of the is caufed by mere vibration pofTefles, is its great fimpli- doiarine dty, Jt is highly probable, that all heated bodies is^caufed* ^^'^ ^" inteftine motion, or vibration of their parts ; by vibra- and it is certain that percuffion, friftion, and other tion. methods of agitating the minute parts of bodies, will likewife increafe their temperature. Why, then, it is demanded, ftiould we multiply caufes, by fuppofing the exiftence of an unknown fluid, when the mere vx- N" 70. bration of parts which is knovn to obtain may be ap- <^f ^be plied to explain the phenomena?" of J-T*'"'^ To this the reply is obvious, that the vibration of parts is an e^cSlj for matter will not begin to move of j ilfclf : and if it is an effi a, we muft fuppoie a caufe for AnA^ er tk it ; which, though we fliould not call it a fluid, would MrNiclio be equally unknown and inexplicable with that whofe * exiftence is afferted by thofe who maintain that fire is g'^ a daid pi'r fc. Dr Clcghorn, however, in the difTerta- Dr Ciejr- tion already quoted, ah'erts, that *' heat is occalioned f'orn'sproi by a certain fluid, and not by motion alone, as fome I eminent writers have imagined; becaufe, i. Thofe "^"^"1"^^ who have adopted the hypothefis of motion could never even prove the exiftence of that motion for which they contended ; and though it ftiould be granted, the phenomena could not be explained by it. 2. If heat depended on motion, it would inftati- taneoully pafs through an elaftic body ; but we fee that heat paflts through bodies flowly like a fluid* 3. If heat depended on vibration, it ought to be com- municated from a given vibration in proportion to the quantity of matter ; which is found not to hold true in faft. On the other hand, there are numberlefs argu- ments in favour of the opinion that heat proceeds from elementary fire. i. Mr I^ocke hath obferved, that when we perceive a number of qualities always exifting together, we may gather from thence that there really is fome fubftance which produces thefe qualities. 2. The hypothefis of elementary fire is fimple and agreeable to the phenomena. 3. From fo ne experiments made by Sir Ifaac Newton, it appears, that bodies acquire heat and cold in vacuo, until they become of the fame tem- perature with the atmolphere; fo that heat exifts is the abfence of all other matter, and is therefore a fub- llance by itfelf." But though thefe and ether arguments feem clearly nifficuki' to eftablifh the point that fire or heat is a diftinft fluid, concemiii we are ftill involved in very tjreat difficulties concern- '^^^ 'i'*^"'' ing its nature and properties. If it be fuppofed a jj^^ qI^h fluid, it is impoffible to affign any limits to its extent; and we muft of neceffity likewife fuppofe that it per- vades the whole creation, and confequently conftitutes an abfolute plenum, contrary to a fundamental princi- ple of the received fyftem of natural philofophy. But if this is the cafe, it is vain to talk ot its being abforb- ed, accumulated, colledled, or attrafted by different bodies, fince it is already prefent in all points of fpace; and we can conceive of terreftrial bodies no otherwife than as fponges thrown into the ocean, each of which will be as full of fluid as it can hold. The diff'erent capa- cities will then be fimilar to the dift'erences between bits of wood, fjionge, porcms ftones, &c. for containing water; all of which depend entirely on the ftrudture of the bodies their.felves, and which, unlefs we could fe- parate the water by prefliire, or by evaporation, would be for ever unknown. Suppofing it were impoffible to colleft this water in the manner we fpeak of, we could only judge of the quantity they contained by the degree to which they fwellcd by being immerfcd in it. It is eafy to fee, however, that fuch a method of judging would be very inadequate to the purpofe, as fubftances might contain internal cavities or pores in which water could lodge without augmenting the ex- ternal bulk. This would fuggeft another method of judging of the quantity, namely, the fpecific gra- 5 vlty ; lenient If Fire. :s itfelf heory. C H E M vity ; and we might reafonably fuppofe, that fubftan- ces of the greatcft fpeci'fic gravity would contain the fmalleft quantity of water, though ftill we could by no means determine what quantity they did contain, unlefs we could lay hold of the element itfelf. This feems to be very much the cafe with elemen- tary fire, if we fuppofe it to be a fluid pi:r fe. We judge of its prefence by the degree of expanfion which one heated body com.municates to another ; but this is only fimilar to the calculation of the quantity of moi- fture a fponge or any other body coHtainSj by what it communicates to wood when It comes into contaft with it; which never could be fuppofed to carry the leaft pretenfions to accuracy, though we fhould afcer- taln it with all imagrinable exaftnefs. It is likewifc proibable that the moft denfe bodies contain the fmalleft quantity of fire, as they generally communicate lefs when heated to an equal temperature than thofe which are more rare, though we are far ftom having any per- fedl knowledge in this refpeft. IDifficulty But the greateft difficulty of all will be, on the fup- ftrifingfrom pofition that heat is a fluid, and an omniprefent one i"that (^^^'^^ ^^'^^^ would be fome places eat fliffu- where bodies could not be heated), to anfwer the qucftion, Why are not all bodies of an equal tempera- ture, excepting only the differences arifing from their fpecific denfities, which render fome capable of containing a greater quantity than others ? — The dif- ficulty will not be leffened, though the omniprefence of the flnid fliould be given up, if we fuppofe, as is generally done, that heat has a tendency to difFufe it- felf equably every way. If It has this tendency, w^hat hinders it from doing fo ? Why doth not the heat from the bur ning regions of the torrid zone difFufe It- ftlf equally all over the globe, and reduce the earth to one common temperature ? This indeed might require time; but the experience of all ages has fliown that there is not the leaft advance towards an equality of temperature. The middle regions of the earth con- tinue as hot, and the polar ones as cold, as we have any reafon to believe they were at the creation of the world, or as we have any reafon to believe they will be while the world remains. This indeed is one of the many inftances of the impropriety of eftablifliing gene- ral laws from the trifling experiments we are capable of making, and which hold good only on the narrow fcales on which we can make them, but are utterly in- fufficient to folve the phenomena of the great fyftem of nature, and which can be folved only by obferving other phenomena of the fame fyftem undifturbed by F any manoeuvres of our own. knother Again, fuppofing the objeAIon already made could be got over, and fatisfaftory reafons fliould be given why an equilibrium of temperature in the earth and its S5 nother from the JlJ^PP^f^j'j^g atmofphere fhould never be obtained, it will by no heat. means be eafy to tell what becomes of the heat which is communicated to the earth at certain times of the Pf Craw- y^^''* '^^^^ difficulty, or fomething fimilar, Dr Craw- ford's folu- ford feems to have had in view when treating of the ion. eflefts of the evolution and abforptlon of heat. Thus, fays he, " the Deity has guarded againft fudden viciflTi- tudes of heat and cold upon the furface of the earth. " For if heat were not evolved by the procefs of congelation, all the waters which were expofed to the influence of the external air, whea its temperature was Vol. IV. Part I. I S T R Y. 385 reduced below 32", would fpcedily become fblid } and, Element at the moment of congelation, the progrefs of cooling , woifld be as rapid as it was before the air had arrived " ' at its freezing point. This is manifeft from what was formerly obfervcd refpefting the congelation of difl"crent fluids. It was fliown, that if the velocities of the feparation of heat were equal, the times of the congelation would be in proportion to the quantities of heat which the fluids gave oft" from an internal fource in the freezing pro- cefs. Whence it follows, that if no heal were evolved, the congelation would be inftantaneous- " In the prefeiit ft.ate of things, as foon as the at- mofphere is cooled below 32°, the waters begin to freeze, and at the fame time to evolve heat ; in con- fequence of which, whatever may be the degree of cold in the external air, the freezing mafs remains at 32*, until the whole Is congealed ; and as the quantity of heat extricated in the freezing of water is confiderable, the progrefs of congelation in large mafles Is very flow. — That the abforptlon and extrication of heat in the melting and freezing of bodies has a tendency to retard the progrefs of thefe proo^.flre3, is remarked by Mr Wilkie in his Eflay on Latent Heat. — The fame- doArine is likcwife taught by Dr Black in his lec- tures. " In the northern and fouthern regions, therefore, Severity of upon the approach of winter, a quantity of elementary fire is extricated from the waters, proportional to the^i^^ re- '** degree of cold that prevails in the atmofphere. Thusgions miti^ the feverity of the froft is mitigated, and its progrefs gated by retarded ; and it would feem that, dur!.ng this rctarda- ^^^J'-^'^' e tlon of the cooling procers,.the various tribes of animals and vegetables which inhabit the circumpolor regions gradually acquire power of refifling its influence. gg " On the contrary, if, in the melting of ice, a quan- In'^n 'ations tity of heat were not abforbed, and rendered infen- P''^'^''-""'^'^ fible, that fubftance, when it was expofed to a medium j^^f'^^fc"^^" warmer than 32°, would fpeedily become fluid, and the which con- pi'ocefs of heating would be as rapid as if no alteration K^aled wa- in its form had taken place. If things were thus confti- ter nielt§.^ tuted, the vaft mafles of Ice and fnow which are coUeft- ed in the frigid zones would, upon the approach of fum- mer, fuddenly diflblve, and great inundations would an- nually overflow the regions near to the poles. '* But by the operation of the law of the abforp- tlon of heat when the ice and fnow upon the- return of fpring have arrived at 32% they begin to melt, and at the fame time to imbibe heat : during this procefs, a large quantity of elementary fire becomes infenfible; in confequence of which the earth is flowly heated, and thofe gradual changes are produced which are eflentlal to the prefervaiion of the animal and vegetable kingdoms. " We may remark, in the laft place, that this lawEqufui- not only refifts fudden changes of temperature, butftribution that it like wife contributes to a more equal diftribu- of heat pro* tion of the principle of heat throughout the various parts of the earth, in diff"ereht feafons and climates. J-Qn an?" Thus the diurnal heats are moderated by the evapora- evolution, tion of the waters on the earth's furface, a portion of the fire derived from the fun being abforbed and ex tingulflied by the vapours at the moment of their af- cent. On the approach of night the vapours are again condenfed, and falling in the form of dew, communicate 3C to CHEMISTRY. Theory. 90 Heat of the thus mitr gated. to the air and to the earth the fire which they had im- bibed during the day. '* It was before fliown, that, in the regions near to the poles, when the vernal and fummer heats prevail, provifion is made for tempering the feverity of the win- ter cold, a quantity of elementary fire, upon the dif- folution of the ice and fnow, being abforbed by the waters, and depofited, as it were, in a great magazine for the purpofe of mitigating the intenfity of the cold when the froft returns. " From the experiments of Hales, Halley, and Watfon, torrid zone Jt appears, that vafl; quantities of water are continually converted into vapour by die aftion of the folar rays up- on the portion of the earth's furface which is expofed to the light; and by the celebrated difcovery of Dr Black, it is proved, that, in the procefs of evaporation, much elementary fire is abforbed. It is manifeft, that this caufe will have a powerful influence in mitigating the intenfity of the heat in the torrid zone, and in pro- moting a more equal diffufion of it through the earth. For a confiderable portion of the heat, which is ex- cited by the aftion of the folar rays upon the earth's furface within the tropics, is abforbed by the aqueous vapours, which being coUefted in the form of clouds, are fpread like a canopy over the horizon, to defend the fubjacent regions from the dire£l rays of the fun. A great quantity of elementary fire is thus rendered in- fenfible in the torrid zone, and Is carried by the dif- perfion of the vapours to the north and to the fouth, where it is gradually communicated to the earth when the vapours are condenfed." That all this takes place, as the Doftor has advanced, tion totally cannot be denied ; but, by allowing it, the difficulty is iiifufficient not removed in the fmalleft degree, as will appear from th '^diffic'l ^ confideration of the phenomena which he him- * ' "* 'felf has mentioned. — He owns that the fun communi- cates fire to the earth : the queftion is. What becomes ©f it, feeing the emiffion is continual ? In fummer, the air, the earth, and the water, are heated to a certain degree. On the fun's declining fouthward, the air firft lofes its heat. Whither does it go ? It does not afcend into the higher regions of the atmo- fphere,forthefearecon[lantlyfound colder than the parts below. It does not defcend to the earth and water ; for thefe give out the quantity they had abforbed, as Dr Crawford obferves. Neither does it go laterally to the fouthern regions; for they are conitantly very hot, and ought to impart their heat to thofe farther north, inftead of receiving any from them. How comes it then, that the atmofphere feems pei-petually to receive heat without ever being fatiated ? or if the heat cannot be found going off either upwards, downwards, or fideways, how are we to account for its dlfappear- 91 This fola- -5a Heat moft probably the adlion of an om- nijprefent fluid. This queftion feems to be altogether unanfwerable on the fuppofition that heat is occafioned by the mere prefence of a fluid ; but if we fuppofe it to be only a particular mode of a a very eafy and natural explication of this phenome- Black's the- non. He li^s ftiovvn, that, in the aft of cougelation, 'a- water is not cooled more than it was before, but ra- '"'^"'^ ^^^'* ther grows warmer: that as much heat is difcharged, and pafTes from a latent to a fenfibi^; ftate, as, had it been applied to water in its fluid ftate, would have ,op heated it to 135°. In this procefs the expanfion is The expan- occafioned by a great number of minute bubbles fud-^o" proda- denly produced. Thefe were formerly fuppofed to be g^f^^^^^-^n formed of cold in the abftraft ; and to be fo fubtile, air-bu>- that, infinuating themfelves into the fubftances of thebles. fluid, they augmented its bulk, at the fame time that, by impeding the motion of its particles upon each other, they changed it from a fluid to a folid. Dr Black, however, has demonftrated, that thefe are anly air extricated during the congelation ; and to the ex- trication of this air he very juftly attributes the prodi- gious expanfive force exerted by freezipg water. The 8b1j C H E M General Ef- only queftlon, therefore, which now remains is, By what Heat'*^ means this air comes to be extricated, and to take . up more room than it naturally does in the fluid ? To jjQ. this we can fcarce give any other anfwer, than that This air part of the heat which is difcharged from the freezing extricated water combines with the air in its unelallic flate, and, tlie^heat"^ by reltoring its elafticity, gives it that extraordinary coma^ncd f'^rce, as we fee alfo in the cafe of air fuddenly extri- in the wa- cated in the explofion of gunpowder. Thus expan- tcr, fion, even in the cafe of freezing, is properly an effedl of heat; and mull therefore be confidered as a pheno- menon uniformly and certainly attending the adlion of ji, heat, and in all cafes to be afcribed to it. Capacity of The only way in which the element or fluid of fire a body for can be fuppofed to aA, and the way in which we can containing j^.^^^ ^ rational idea of its being able to produce both lame with heat and cold according to the diverfity of its aftion, the a<5lion has been already explained fo fully, that it is needlefs of heat up- at prefent to enter into any further difcuffion of the CM that bo-^yj^j^^^^ ^viii eafily appear, that the capacity for ^' 'Containing heat is nothing different from the aftion of heat upon that body in expanding, and at lail alter- ing its form in fuch a manner, as either to be able to infmuate itfelf among the particles in much greater quantity than before, ftill retaining its internal ac- tion, though the external one becomes imperceptible ; or fcattering them in fuch a manner, that it breaks forth in great quantity in its pecuhar appearances of fire and light ; in the former cafe producing vapour or fmoke, and in the latter flame, as fliall afterwards be Impombili- ^^^^y explained. It muft likewife appear, that ty of deter- to determine the quantity of heat in any body is mining the altogether impoffible : and with regard to the lowefl; quantity of degree of heat, or a total expulfion of that fluid, fo heat any ^^^^ ^^.^^^ ^^^^ determine what it is, the pro- bability mu'il be, that nature does not admit of any fuch thing ; for if heat confills in the expanfive ac- tion of a certain fluid, and cold in its oppoiite or contraflile aftion, there is very little reafon to fup- pofe that the conftitution of nature will allow any one of thefe adlions entirely to ceafe, as it does not ap- pear by what means it could again be renewed. Cold, as we have already feen, always tends to produce elec- tricity ; and the connexion betwixt that and fire is fo ftrong, that we cannot fuppofe the former to be car- ried to any great extreme without producing the lat- ter. Whatever we may therefore fuppofe concerning the capacities of diff"erent bodies for containing heat, or concerning the point of total privation of heat, mull be altogether void of foundation- A rule, however, has been given by Mr Kirwan for finding the point of total privation, whicli, together with its demonfl:ra- tion, we fliall fubjoin ; and as it is neceffary for the better underftanding of this, to call to remembrance what has been faid concerning the difference between the temperatures and fpecific heats of bodies, we fhall infcrt an epitome of the doftrine from Mr Nicholfon. " If two equal bodies of different kinds and tem- peratures be brought into contaft, the common tem- perature will feldom, if ever, be the mean betwixt the the capaci- original temperatures ; that is to fay, the furplus d?e*s for ° of heat in the hotter body will be unequally divided containing between them, and the proportions of this furplus re- heat, &c. tained by each body will exprefs their refpedlive dif- poiitions, affinities;, or capacities for heat. — If, there- 1 S T R Y. hody con- ■fains. Mr Nichol fon's ac- count of fore, a given fubfiiance, as for example fluid water, beGeneralEf- taken as the ftandard of comparifon, and its capacity ^^^^^"^ for heat be called one, or unity, the refpe£live capa- ■ _ '^-, , ,1 ' cities of their bodies may be determined by experi- ment, and expreffed in numbers in the fame manner a» fpecific gravities ufually are. And becaufe it is eltabhflied as well from reafon as experiment, that th? fame capacity for heat obtains in all temperatures of a given body, fo long as its flate of fohdity, fluidity, or vapour is not changed, it virill follow, that the whole quantities of heat in equal bodies of a given temperauure will be as thofe capacities. And as the refpeftive quantities of matter, in bodies of equal volume, give the proportions of their fpecific gravities, fo the re- fpeflive quantities of heat in bodies of equal weight and temperature give the proportions of their fpecific heatS4 " A greater capacity for heat, or greater fpecific heat, in a given body, anfwers the fame purpofe with refpeft to temperature as an increafe of the mafs ; • or the quantity of heat required to be added or fubdufted, in order to bring a body to a given temperature, will be as its capacity or fpecific heat. The capacities not only differ in various bodies, but alfo in the fame body, according as it is either in a folid, fluid, or vaporous flate. All the experi- ments hitherto made confpire to fhow, that the capa- city, and confequently the fpecific heat, is greatefl in the vaporous, lefs in the fluid, and leafl in the fo- lid flate. l^e quantity of heat that conflitutes the difference between the feveral flates, may be found in degrees of the thermometer. Thus, if equal quantities of water at 162° and ice at 32° of temperature be mixed, the ice melts, and the common temperature becomes 32°} or otherwife, if eqtlal quantities of frozen and fluid wa- ter, both at 23°, be placed in a hke fituation to acquire heat from a fire, the water will become heated to 162°,. whilethe ice melts without acquiring any increafe of tem- perature. In either cafe the ice acquires 130° of heat, which produces no other efFeil than rendering it fluid. Fluid water, therefore, contains not only as much more heat than ice, as is indicated by the thermometer, but alfo 130", that is in fome manner or other em- ployed in giving it fluidity. And as fluid water can- not become ice without parting with 1 30" of heat be- fides what it had above 32'" in its temperature ; fo al- fo fleam cannot become condenfed into water with- out imparting much more heat to the matters it is cooled by, than water at the fame temperature would have done. " The heat employed in maintaining the fluid or vaporous form of a body, has been called latent heat, becaufe it does not affedl the thermometer. 114 " From the confideration of the fpecific heats of Mr Kir= the fame body in the two ftates of fluidity and ^^^^'^^-^^'^'fj^^""- ty, and the difference between thofe fpecific heats, is finding deduced a method of finding the number of degrees point of ta- which denote the temperature of any body immediate- cal priva- ly after congelation, reckoned from the natural zero, ^'^^^ or abfolute privation of heat. The rule is ; multiply the degrees of heat required to reduce any folid to a fluid flate, by the number exprelTmg the fpecific heat of the fluid : divide this produft by the difference be- tween the numbers expreflTmg the fpecific heat of the body in each flate ; the quotient will be the number Z . o{ heory. and w= r s — / C H E M eneralEf- of degrees of temperature, reckoned from an abfolute ^ privation of heat. « This theorem is Mr Kirwan's, and may be proved thus. Let s reprefent the required temperature of the body juft congealed, / = the number of degrees that exprefs the heat required to reduce it to fluidity, n = the fpecific heat of the folid, and m = the fpecific heat of the fluid. Then s-\-l : s i : m : n. Whence /n j__ : — _ tiie temperature from the natural zero m — K in thermometrlcal degrees of the fluid. But becaufe tlie ailual fall of the thermometer is to be produced by cooling the fohd, muft pay attention to its capa- city. The quantity of heat required to produce a given change of temperature in a body is as its capa- city; and confequently the changes of temperature, when the quantity of heat is given, will be inverfely /« In as the capacities: therefore, n : w ; :-— — -=J'. which is the rule above mentioned. " If the data /, m, and n, be accurately obtained by experiment, in any one infl;ance, and the difference between the zero of Fahrenheit's fcale and the natural zero be thence found in degrees of that fcale, this difference will ferve to reduce all temperatures to the numeration which commences at the natural o. So that s being known in all cafes, if any two of the quantities /, m, or «, be given in any body, the other sm — sn may be likewife had. For/=: sm — //« and nzz . s *♦ To give an example of this curious rule, let it be required to determine how many degrees of refrigera- tion would abfolutely deprive ice of all its heat ? The degrees of heat neceffary to melt ice are 130 ; and the fpecific heats of ice and water are as 9 to 10. The number 130 multiplied by 10, produces 1300, and divided by the difference between 9 and to quotes 1300: therefore if ice were cooled 1300 degrees be- low 32°, or to — 1263 of Fahrenheit's fcale, it would retain no more heat." II. Fluidity is another effeft of heat, and is capable of taking place in all bodies hitherto known, when the fire is carried to a certain pitch. Theories have been invented, by which fluidity was afcribed to the fmoothnefs and round figure of the particles whereof bodies were compofed, and folidity to an angular or irregular figure. It has alfo been afcribed to a ttrong- tr degree of attradlion between the parts of folids 1 -j^/ than of fluids. Dr Black, however, has fhown, that luidity to , ' . , r M e afcril.ed m the cafe 01 meltmg ice, we are certamly to alcnbe ) the ab- the acquired fluidity of the water to the abforption of orption of This was determined by a decifive experiment, ^^'* in which he expofed a Florence-flaflt full of water to the atmofphere In a warm room, vsTien he found that the heat in the air evidently left it, to flow into the ice in the bottle, and reduced it to fluidity. The air thus deprived of its heat, he felt fenfibly defcending like a cold blall from the bottle, and continuing to do £0 as long as any of the ice remained unthawed ; yet after it Vv'as all melted, the temperature of the fluid Wcis no move tlian 32°. Different degrees of heat are requifite for converting different folids into fluids,, for which fee the Tabic of Degrees of Hs^r, I S T R Y. 391 This theory receives an additional confirmation from General Ef- the quantity of heat which is always known to be produ- ^g^^^''^ ced by the converfion of a fluid into a folid. And that , _ , this is really the cafe appears, i . From what happens in , ,5 the congelation of waters, it appears that ice is formed SenGble very flowly, and with feveral circumfliances which fiip- heat produ- port the theory. — Thus, if we expofe equal quantities of water to the air, which is perhaps 10- below froftj^f ^ fluij and add to one of ihefe a fmall quantity of fait or mto a folid. fpirit of wine, and obferve the cooling of each, we fliall find them both grow gradually colder, until they arrive at the temperature of frofl; ; after which the wa- ter containing the fait will continue to grow colder, until it has arrived at the temperature of the air, at tlie fame time that only a fmall quantity of the other water is converted into ice. Yet were the common opinion jufl;, it ought all to have been congealed by this time ; infliead of which, it is fcarce grown a degree colder during the whole time. Its remaining at the fame temperature for fo long time, fliows that it has been communicating heat to the atmofphere ; for it is impoffible that any body can remain in contad with another that is colder, without communicating heat to it. Whence then comes this heat ? There mull be fome fource adding to the fenfible heat of the water, fo as to keep up its temperature to the freezing point : and this . - fource of heat mufl; be very confiderable ; for it will continue to aft for a very long time before the water is changed into ice ; during all which time, even to -the lafl: drop, the water is not a degree colder than 32° of Fahrenheit's thermometer. This, therefore, is the lafenl heat of the water, which had formerly entered into it during its tranfition from ice to a fluid ftate. A fl;ill ilronger argument is derived from the fol- Argument lowing experiment; which evinces that the fluidity of in fupport water really depends upon Its latent heat, and that of the thco- the fenfible heat is only a mean or condition to its ""^ containing the latent heat. This experiment confifl:s ^!;!L^" in expohng water contained in a covered bser-glafs to fluid tho* the air of a cold frofty night; and when the atmo- cooled be- - fphere is at the temperature of perhaps 10° or 12' be- low froft, the water will acquire that temperature without freezing: fo that the fluidity of the water does not altogether depend on the quantity of fen- fible heat contained in it. The congelation, however, . may be brought on by touching it with a bit of ice, with the extremity of a wire, by a fhock upon the board, or otherwife diilurbing It ; and we then find the temperature fuddenly raifed up to 32°, This ftiows plainly, that the water has a difpofition to re- ■ tain the quantity of latent heat, upon which Its flui- dity mufl; immediately and neceffarily depend ; and it retains it with a certain degree of force, fo as to keep the water fluid In a temperature bel nv that in which it ufually parts with the latent heat and congeals. By difturbing It, however, we Infl:antly bring on the con- gelation, which cannot take place without an extri- cation of the latent heat; which then, being changed' into the ordinal^ or moveable heat, raifcs the thermo- meter as ufual. The quantity of heat difcharged from the firft fmall . portion of ice formed in the water is fufficient to prevent anymore latent heat fiomfepa-- rating, and confequently from any more Ice being produced till more of the fenfible heat is abllradlcd. This doftrine extends not only to fuch bodies as are aftually converted from a folid to a fluid, or from; ft ds of Heat. 1x8 Heat the univerfal caufe of fluidity. 39^ G H E M I Genera! Ef. a fluid to a folld ftat^ but to fuch as are m a kind of middle Hate betwixt folidity and fluidity 5 for every degree of foftnefs depends on a certain degree of heat contained in the body. Thus, for inftance, melted wax, allowed to cool flowly, foon becomes opaque and f^7^^^^J?/^J?^confiftent ; but it mull be colder ftiil before it attains bodiiap its utmoft degree of hardnefs. There is there tore a iroachir.fj certain degree of heat below which every body is folid, to auidity. and above which every one is fluid ; the former being called the congealing, and the latter the meltings point of TT9 bodies. Abforption By making experiments upon different fubftances, t)i lieat the T^xi • ji i , . univerfal iJon trie con- i c iv * i r* i ■ » verfion of P^^^e ot calt iron, one end of which was made fenfibly red-hot, they fet upon this fome iron veflels with cir- cular fiat bottoms, of about four inches diameter, and which contained a quantity of water. The tempera- ture of the water was noted, as alfo when it began to boil; and when the whole of it was boiled away, it was found, that when fet on the table its temperature had been 540 ; in four minutes it began to boil, and in that fpace of time received 158° degrees of heat. Had the evaporation, therefore, depended merely on the quan- tity of fenfible heat introduced, it ought to have been diliipated entirely in a fingle minute more. It was, however, iB minutes in dilhpating; and therefore had received 807 degrees of heat before it was all evapo- N° 70. ^ R Y. Theory, 1 this time, therefore, while tbe water con- General Ef- y\y it wa3 receiving a ;;reat quantity of heat, ^^'^^^ J 40 Vapour tson of la t€Ut heat- Ill Experi- ments by Dr Black water into vapour. i T rated. All tinued to boil, ^ - ^ -1— ; which muft have been flowing equally faft out of it ; for the veffel was no hotter, and the iron plate conti- nued equally hot, the whole time. The veffcls were of different (hapes, fome of them cylindrical, fome co- nical, others widening upwards ; one of the deCgns of the experiment being to fliow how far the evaporation was retarded by the particular form of the veflels. By fufpending a thermometer in the mouth of one of the evaporating vefl"els, the heat of the fl;eam was "found to be exaaiy 212°; fo that as the great quantity of heat abforbed was found neither to have remained in the water, nor to have been carried away by the fl:eam in a fenfible manner, we have nothing left to fuppofe, but that it flew off »,s one of the component parts of the fteam in a latent itate. 2. In an experiment to fliow the fixednefs of the boiling point of water, Dr Black inclofed fome of that fluid in a (Irong vial having a therm.ometer in it, and flopped clofe with a cork. By the application of heat he hoped now to be able to raife the- thermometer fome degrees above the boiling point, which would be the natural confequence of the confinement of the fteam. When this was done, he pulled out the cork, and fup- poled that the water would now all fly out in vapour : but in this he was totally difappointed ; a fudden and very tuniultuous boiling enfued, which threw out fome of the water; but though fome quantity of fteam like- wife iiTued, the quantity of water was not confiderably diminiihed. The vial had been heated to 20° above the boiling point, but almoft inftantly cooled down to 212°, when the cork was taken out. 3. Mr Watt, in making fome experiments on the force of il.-am, had occafion to ufe Papin's digefter, with a pipe proceeding from its fide ; the orifice of which. was fliut with a valve prelTed down by one end of a lever. Thus he heated fteam to 400° of Fahren- heit ; after which, having fuddenly ftruck off the lever, a euantiiy of fteam flew out with confiderable noife, and^ with fuch violence as to make an imprefTion on the ceiling of the room ; but this noife gradually diminifli- ed, and after ten minutes ceafed entirely; rnd upon opening the machine, he found the greateft part of the water ftill remaining. 4. The change of fenfible into latent heat in the Boiling formation of vapour, appears flill more evident ia the point of boiling of water in 'vacuo. Mr Boyle took a quantity ^^''"■'f^'' of water which had been previoufly boiled to purge it^^^'^^i^^^ of its air, and put it whilft hot under the receiver of an Mr^ air-pump. In confequence of this it began again to boil, Boyle, and continued boiling till it was only lukewarm, and it foon arrived at this temperature ; fo that in this cafe alfo the heat had difappeared during tke converfion of the fluid into vapour. Others have repeated the ex- And by periment, asBoerhaave, Mufchenbroek ; and Robinfon, l^"" Robin- who ledures on chemiftry in Glafgow, fays that the '^"'^ °^ ^^*^* heat diminiflies very faft till it comes to 90° or 95'',^°*^* which feems to be the boiling point of water in vacuo. As a confiderable part'of the heat thus difappears, and is to be difcovered neither in the water nor in the va- pour, we muft conclude that it enters the latter as part of its compofition. 5. Thus alfo we may underftand fome curious expe- riments made by Dr Cullen upon ether and other vo- latile 124 Theory, C H E M General Ef- latUe fluids. He employed fome perfons to make ex- Heat"^ periments upon the cold produced by evaporation ; and willing to repeat them himfelf in vacuo, he put fome of the moft volatile liquors under the receiver DrCullen'sof an air-pump. One of thefe was ether. It was experiments contained in a glafs, in which there was alfo placed on cold pro- f-Qj^jg water. When the air was extraded, the ether vaporation." began to boil, and to be converted into vapour, till it ' became fo very cold that it froze the water contained in the velTel, though the temperature of the room was about 50°. Here therefore there was a quantity of heat which difappeared all of a fudden ; which it is plain co\ild not be owing to its having any communi- cation with that of the atmofphere or other cold bo- dies, as they could not render it colder than they were themfelves. Ether therefore is to be confidered as a fluid fo volatile, that were it not for the prefTur; of the atmofphere it would be perpetually in the ftate of va- Heat expel- 6. That this heat which enters into the vapour is I led in great not deftroyed, but remains in a latent ftate, is i quantity by eafjiy p^Qygjl . fgr we find that a great quantity of heat is expelled from vapour when it is condenfed again fationotva- T . 1 • r j • • 11 t-u- • pour. to ^orm the body it compoled originally. 1 his is ea- fily afcertained by obferving the quantity of heat com- municated to the water in the refrigeratory of a ftill by any given quantity of liquid which comes over. Thus, if the refrigeratory contain 1 00 pounds of water, and the diftillation be continued till only one pound has come over, fuppofing the water in the refri- geratory to have received 8° of heat ; it is plain, that if the whole of the quantity thus received could be thrown into one pound of water, the latter would be heated to 800'^ ; which is fufficient to make an equal fpace of iron red-hot. But that this quantity of heat is received by the water in the refrigeratory has ap- peared from feveral experiments, which fliow that wa- i ter, by being converted into vapour, abforbs between 126 800° and goC of heat. Mr Watt's On this principle we may explain fome curious expetimei tsgj(.p^j.;^gj,jg made by Mr Watt with regard to the on the «^*-evaporation of fluids in vacuo. That gentleman had fia-ds /« -ya-iormed a dehgn or converting water into Iteam witti -no. lefs txpence of fuel, which he imagined might be done by removing the prefTure of the air from the water, which he thought would thus require a much fmaller quantity of fuel to convert it into vapour. Dr Black, however, perceiving that only the {mall quan- tity of fenfible heat the fteam poffefled could thus be carried off, informed him beforehand that hi.s project would not be found attended with the advantages he imagined. The experiment, however, was made in the following manner: A flill was procured of tinned iron, the body of which refembled that of a retort, with a vefTcl ferving as a condtnfer ; the whole appa- ratus being clofe, exceptintr a little hole in the extre- mity of the condenfing veflel. He firfl exliaulled this vefl'el of air by holding the condenfer over the retort, in which fome boiling wattr was contained, until it was entirely converted into iteam. He then fuddenly ftopped the little hole, and removed the vfflels from the fire ; when, after they were cooled, there was a pretty perfeft vacuum formed by the condenfation of the fteam. The retort was then put on the fire, and turned fo that the pipe and condenfing veflel (hould Vol. IV. Part 1. I S T R Y. 393 hang downward ; and plunging them into cold water, General heat was applied to the ftill till the water boiled, as^^^^"®^ could be known by the noife. It was kept boiling, ' j till a quantity of fteam was pufhed over and condenfed ' with a very gentle heat, the ftill feeling little warmer than his hand. After a certain quantity had been diftilled, the apparatus was removed, and he had noted the heat of the water in the refrigeratory % but though the fteam all along came over with fo gentle a heat^ he found the quantity communicated to the water in the refrigeratory to be furprifingly great, not lefs than 1000'' ; fo that it would have been more than fufficient to heat the quantity of liquor which came over red-hot. , ^ IV. or the caufing bodies to fhine or emit Ignition « " light in the dark. This may be confidered as a fpe- conftant cies of inflammation, and ftiall therefore be explained ^^^^f^ under that head : here we ftiall only obferve, that ig-heat nition is a more fteady and conftant effedt of heat than ug either the produftion of fluidity or vapour ; and ap- A.1I ignite(3 pears not only to be the fame degree with regard to^*"^'^*^" any particular body, but the fame with regard to kinds of matter. Dr Martin imagines, that a red hot piece of iron is hotter than a red hot piece of ftone ; but if you put into a crucible an hundred different kinds of matter, as metals, glafs, &c. that are capable of bearing a red heat, they will all begin to appear luminous about the fame time, and their brightnefs will increafe equal- ly as their heat increafes. But it is difficult to know at what point this begins, as we have no way of afcer- taining the beginning or loweft degree of ignition but by the effett it produces on our fight, and we cannot be fure that we perceive the loweft degree of light ; for we know that other animals fee objefts with fuch light as appears perfedt darknefs to us. Sir Ifaac Newton's method of determining this has been already mentioned. " ^ Dr Boerhaave entertained a notion, that fome Metah may metals, after being once brought into a ftate of fu- become fion, could be made no hotter ; and propofes the pof- ^^^'^ Ability of this as a queftion, " Whether the heat of^^^'^'^'^g metals can be increafed after they are melted ?" There brought in- is not, however, the leaft doubt but that their heat may to fulion. be valtly increafed after they are melted; and we know certainly that fuch as are of eafy fufion may be heated to a vaftly greater degree after being melted ; and why may not thofe requiring ftronger heats be the fame ? We are fure that this is the cafe with filver, wliich, after being melted, may be brought to fuch a heat as to become too dazzling for the eye to bear it. If Boerhaave's opinion were juft, it would be impof- fible to caft any metal into moulds, becaufe it mult lofe a little heat in being removed from the fire and in en- tering the mould ; nor would they receive a proper impreffion if they did not contain a greater quantity 6f heat than was neceffary for their fufion. Ignition appears to be univeifal; and all bodies ca- i,Tnitfon an pable of fupporting it without being converted into an univerfal elaftic vappur that cannot be confined, are affefted ''^'^'^ of the fame way. Water, which in its ordinary ftate feeras very Kttle capable of enduring this heat, may be Water^may confined in ftrong veflels fo as to become capable of be made melting lead, which is more than half way betwixt a Sufficiently red heat and that of boiling water. Experiments with the eollpile fhow alfo that it can be made red-hot for when the fteam pailes through burning fuel, it can. 3 l'> not 394 CHEMISTRY. Theory- General £ffe(ft- of Heat. on. 133 Inflammati on decom- 134 Spirit of" not mlfs of being made red-hot. Dr Black has alfo frequently feen the vapour of water heated by throw- ing ft into the afh-pit of a furnace, fo as to produce a very large and transparent flame in rifing up through the vent. There is reafon therefore to conclude, that ignition is one of the more general effefts of heat, only that fome bodies are incapable of it until they be re- duced to a (late of vapour. V. The laft of the effeds of heat here to be taken notice of is inflammation. It differs from ignition in DifFerence this, that the bodies fubjeft to the latter gradually grow betwixt ig' cooler as foon as they are taken out of the fire, with- iiition and underffoincr any confiderable change; while thofe fubjecT to inflammation become contmually hotter and hotter, communicating a vaft quantity of heat to others, and undergoing a kind of decompofition themfelves, infomuch, that by this means they have been thought to be reduced to their conftituent principles or ele- ments. Some fubftances indeed fcem to be an excep- in ae.com o-^tn air they burn totally away, pounds but without leaving any refiduum or producing any foot, does not de- Thefe are fpirit of wine, fulphur, and efpecially inflam- Itroy bodies mable air ; which laft, by a proper mixture with de- phlogifticated air, may be fo totally confumed, that fcarce a fiftieth part of the two will remain. On a careful examination of thefe fubftances, however, we find that there is by no means a total confumption, or indeed, properly fpeaking, any confumption at all, at leaft if we meafure the quantity of matter by the weight ^ of the fubftance employed. Thus, if we are at pains wine yields to colkft the vapour of burning fpiiit of wine, we will a great ^^^^ aqueous dew is colleded, which fome- wTter by ^''"^^ equals the fpirit of wine itfclf in weight. With being burn- regard to fulphur, the cafe is ftill more evident; for ed» the vapour of this, when colleAed, not only equals but greatly exceeds the weight of the fulphur employ- ed ; and on burning dephlogifticated and inflam- mable air together, as much water is found to be pro- Water pro-duced as nearly equals the weight of both airs. In duced by like manner, when we coUefl the afties, water, foot, the defla- ^nd oil, procured by burning any of the common in- gration of ^^^^^\^\^ fubftances, we will find, that they in gene- catedand ral exceed the weight of the matter employed. 1 he inflamma- great wafte of bodies by fire, therefore, is owing to the ble air. diffipation of the volatile principles they contain, which are carried off and rendered invifible by being mixed with the atmofphere. The procefs of Inflammation has long been explain- ed from the prefence of a fubftance called Phlogijlon in phlogifton. thofe bodies which are fubjeft to it, and which is fup- pofed to be the fame In all bodies belonging to this clafs ; the differences between them arifing from the 137 principles with which it Is combined. This doftrine, Denied by which was firft introduced by Stahl, has given occa- Lavoj- ^jQjj various and difcordant theories, that the exiftence of phlogifton has been lately denied altoge- ther by M. Lavoifier, who brought in a new method of folvirg the phenomena of fire, heat, and ignition, without any alliftance from this principle, aga^nft i" ^ The foundation of M. Lavoifier's doftrlne is the drawn from increafe of weight In metals by calcination. This in- the increa- creafe he finds to be preciftly, or very nearly fo, pro- of^ nTe'tals' P^Ttlonable to the decrtafe of weight in the air In by cakLa- which they are calcined. His theory, therefore, Is, that in the aft of calcination, the pure part of the air, 136 Of the ex- iftence of tion. which he calls the acidifying or oxygenous principle, General unites with the metal, and converts it into a calx. In °^ like manner, in fubftances truly inflammable, the heat ^7 and flame arc fuppofed to proceed from the union of i^^p the pure air, or the oxygenous principle, 'j ith the fab- His theory ftance, and convertings it into thofe principles which f , • r ■ n • rrf i_ • mation. are round to remam alter inflammation, inus the in- creafed weight of the fubftance is cafily accounted for;. while the inflammation, in his opinion, is nothing more than a combination of the inflammable body it- felf with pure air, which has an attraftion for it : and in confirmation of this It is urged, that when com- buftion is perfoimed in empyreal or dephlogifticated. air, the whole of the latter is abforbed ; but in com*- mon atmofpherical air only one fourth, beirvg the quan* tity of pure air contained in it; 140 OthtT arguments in favour of this opinion are, that -^''.iiun''cnt9 the calces of the perfed metals may be reduced without ^'"[^^^ . ^ . . exilfceuce ox addition by the mere emiflion of the oxygenous principle', phi.,j,);irron, (dephlogifticated air) ; by an union with which they al- tioiuthe re- fumc the form of a calx. Thus he evades a very '^"'^^i"" of • ftrong argument ufed by the oppofite party ; who of*^ ^g^fg^ duced, as a proof of the exiftence of phlogifton, thenier'ab^ ufe of charcoal in the redudtion of metals to their pro- w:rhoutad« per form. A difpute indeed took place betwixt M. dicion. Lavoifier and Dr Piicftley concerning the reduflion "fj^jf^yfg ^ the whole of a mercurial calx formed by an nnion ^^^.j^^^ with the nitrous acid without addition ; the Doftor voilier and maintaining, that the whole could not be reduced by l^"eftley. mere heat, but that a very perceptible quantity was always loft : but on a thorough examination of the fnbjeft, the truth Teemed rather to lie on M. Lavoi- fier's fide. See Aerology. Another theory, fomewhat fimilar to that of Lavoi- Dr Lub- fier'y, has been publiftied by Dr Lubbock, in an Inau- bock's theof gural Diftertation in 1784. In this he fuppofes two''5''* kinds of matter to exift in the unlverfe ; one he calls the principium proprhnn, the other the pr'incipium for- bile ; and it is this latter, which, according to our au- thor, is the piinciple of mutability, or which, by be- ing united in various proportions with the other, forms bodies of all the different kinds we fee in nature. It' is this principle, therefore, which he fuppofes to be ab- forbed in the calcination of metals, and not empyreal air, as M. Lavoifier fuppofes ; and he contends, that this fame principle extends throughout the whole fy- ftem of nature, even to the utmoft celeftial bounds* It would exceed the limits of this treatife to give an Difputes account of the various theories which have been invent- concerning ed, and the areurrvents ufed for and aofainft them. ; norP^'"^'^"" . , , . , ° - . , now entire- inueed is there any occahon tor doing io, as late expe- jy riments have reduced the difpute Into a much narrow- er compafs than before, and furnlfhed the moft deci- five arguments in favour of the exiftence, of phlogifton. The greatelt objeftion to the belief of this prin- objedlions ciple was, that it could neither be feen nor felt by ouragainft the fenfes direftly, nor difcover Itftlf indireftly by ^^^^ ^^^'^^^^"^^ weight it communicated to the bodies with which it from*^its'in- was united ; on the contrary, the latter always became vifibility lighter In proportion to the quantity they contained : and fuppo- fo that it was imagined, inftead of being poflefTed oi^*^^ vyant o» any fpecific gravity of its own, to be a principle of po-^"^"^* fitive levity, fuch as that of heat or hght may be rea- fonably fuppofed. This objeftion, however, is now entirely removed ; and fhloglftoii in the abftra£t is found "45 the fame. T46 Decifive proofs of ley. T47 Sfiiit of wire and rnetals con- , Theory. C H E M I General found to be no fubtile principle capable of eluding our EfFtdls of refearches, but one very common, and eafily met with, ' ■ • being no other than common charcoal. In the laft edition of this work, under the article Phlogiston, Common it was fhown, that inflammable air, deprived of its ela- charcoalandfticity, and comVjined with metallic fubflances, is real- phl )^')ftoM jy their phlogillon ; and that in the inflammable bo- dies commonly ufed, what we call their phlogillon, IS really their oil; and that which exifts in charcoal, and cannot be driven off by diftlUation, id part of the em- pyreumatic or burnt oil of the fabjeA which adheres fo obftinately, A fimilar doArine f )on after appeared in the Phil )fophical Tranfailions for 1782, and the iden- tity of phlogiiton and inflam^iable air was clearly pro- ved by Mr Kirwan. Still, however, it was infified by the French phllofophers and others, that no faSs had _ _ been adduced againft M. Lavoifier, nor any decifive ^'i'vef h"^''^ proofs appeared of the exiftencc of phlogifton as a fub- Dr Prieit- ilance ^fr^^. Fafts of this kind, however, have 'now been difcovered by Dr Prieftley, and are related under the articles Aerology, Charcoal, Phlogiston, &c. It is fufficient at prefent to mention, that he has been able to convert the pureft fpirit of wine, and one of the hardell metals, viz. copper, as well as feveral others, into a fubllance eniiirely refcm- ve-tible iti- '^^'"g charcoal ; that by means of the heat of a burn- lo charcoal, ing glafs in vacuo, he has diffipated this metallic char- coal, as well as the common kind, entirely into inflam- Charcnal mable air, with the affiftance only of a little water, entirely dif- which feems necelTary to make it affume the aerial fipated by form, and perhaps is the true folvent of it ; and by a irfkmma- combination with the element of heat, with the aid of bieair^ the cliarcoal, is enabled to refill condenfation in the • See Ela/- '^^^"'O'^^^'^y** 'Phis inflammable air, when abfoi bed by tic Vnpour. "metallic calces, again reduces them to their metallic 149 form ; fo that here is one faft by which the phlogillon Metallic not only appears to our fenft s, but we are able to af- ^^ll^^j^ '"j^^l"" certain its quantity with the utmoft precifion. Nor can flammable ^'^"^^ ''"Y t)bjt(3ion, that the reduced metal is air. lighter than the calx ; for this only proves that the 150 metallic earth, while a calx, is united to a heavy ingre- Wliy metals (the bafis of dephlop-ifticated aii), and in the a!C lighter , ^ , ■ \ 1 1 1 r r - n jj^gjj. latter to a light one, viz. charcoal, the baiis 01 mnam- ta!'.!c than mable air. in their cal- Another cafe in wliith the exiftence of phlogifton cined ftate. jg made equally evident to our fenfes, and where no fuch objection can occur, is related under the article ^ '5^* Aerology, n'^ 112. It is there (hewn, that "by the lofs ticated^air" "^^ grain of ch^arcoal of copper (formed by the union converted of fpirit of wine with the metal), and which like com- int< aerial mon charcoal was confumed without havins: any refi- acid by duum, he reduced four ounce-meafures of dephlogilli- cated air till «nly one-ninth remained unabforbed by water ; and, again, with the lofs of one grain and a half of charcoal, fix and an half meafui-es of dephlogi- flicaled air were reduced till five and an half meafiires were pure fixed air." — Here, then, is an abfolute and vmdeniable evidence, that fixed air is compofed of de- phlogifticated air, and charcoal or pldogillon, and ele- mentary fire. There were no other ingredients pre- fent, and the charcoal nuift either have been annihila- ted or difpofed of in the manner juft mentioned: but the fuperior weight of the fixed air evidently fhows that fome ingredient had been added to the dephlogi- ilicated air; and which increafe was more than we can S T R Y. 39 S charcua!. fuppofe to arife from the condenfation of the dephlo-^^eneral gifticated air during the operation, for this fometimes ^ amounted to no more than one-thirtieth- part. < The ftrongeil objedtion which can be made againft the do£lrine of phlogifton may be drawn from the to-ObjeiStions tal confumption of pure air in certain cafes of corabu- drawn from ftion, for inftance, in that of phofphorus, inflammable '■^^ V"*^^'- air, and iron, it mult be obierved, however, that m^^f ^gp^io. no cafe whatever is the air totally confumed; andgifticated in that of inflammable air water is produced by th^r^ir in fonie union of the bafis of the latter, that is charcoal, '-^^^'* with the bafis of dephlogifticated air, the oxygenous principle of M. Lavoifier, and which appears to be one of the component parts of Water. In the cafe of phofphorus, the latter is converted into an acid ; and in all probability a quantity of water is alfo pro- duced, by which part of it is converted into cryftalline 153 flowers. The cafe of the iron, therefore, alone re-^''"'^ P*^'°* mains to be confidered. Dr Prieftley's experiments 1 • r 1 • n 1 1 1 11 r • 1 P^^hed from on this lubject are related at length under the article iron by he- Aerology, n° 67 et feq. In them the iron burnt ing burnt brilkly in dephlogifticated air, which, according to dephlo- the common theory, fliould have indicated the expul- ^'^'^^^^'^ fion of a great quantity of phlogifton ; yet the whole refiduum, of which the fixed air, produced by the fup- pofed union of the phlogifton or principle of inflamma- bility, was only a part, fcarce amounted fometimes to one-fourteenth of the air originally employed. 1^4 This argument, however, inftead of contradiclingl'heobjec- the exiftence of phlogifton, only Ihows, that in fome '^i^j^g'^''^* cafes the diilipation of a very fmall quantity of phlo- gifton is necefiary to inflammation ; or that the aerial principle may combine with the iron in its metallic ilate. In this cafe only a very little quantity of the phlogifton of the iron was diflipated ; for it was IJ5 not reduced to a calx, but to that kind of fcorije is not which flies oft' in fcales by, beating the metal when^^^'^j^^^jy led-hot with an hammer. A decifive proof of this burning In was had by uniting iron thus combined with the dephlogifti- bafis of dephlogifticated air with inflammable air. ^'^'^^^ By this the metal was indeed reduced to peifeft iron again ; but water was produced at the fame time ^j^^g^j^fj^g from the union of the bafis of the two airs, that of the redudtion inflammable airsbeing capable of furnifliing a fuperflu-of it by in- cus quantity, which united with the other into the form of a fluid. ^"^"157 The exiftence of phlogifton being thus proved, and Heat prq- its nature afcertained, we may now proceed to deter duced in mine the quellion. Whether the great quantity of heat produced by the combuftion of inflammable bodies jj|^gg'°^^^°_ proceeds from the bodies themfelves, or from the air ble bodies which muft be admitted to them in order to make coming them burn ? That the heat in this cafe proceeds from ^"^^"^ the atmofphere is evident ; becaufe in all cafes of ^*'^* combuftion there is a certain diminution undoubted- ly takes place by means of the converfion of the de- phlogifticated part of the atmofphere into fixed air. It is proved, under the article Elastic Vapours^ that elementary fire is the univerfal caufe of elafticity ia fluids. By uniting a certain quantity of it with any fubftance, the latter at length afl"umes an aerial or va- porous form; and it is this vapour alone which is in- flammable*. Different vapours no doubt contain dif- ' See the ferent quantities of thefe ingredients; but in all cafes ^"•'^"^ the bafis of the -dephlogifticated part of the atmofphere'^'"'"'* 3 D 2 muJl 39^ Genera! ESc&i of Heat. 158 Too much phlogifton prevents the heat from being intuiie. CHEMISTRY. Too great a quantity of air has the fame effccSl. 160 Why the fcilar heat ai.d that of eledtricity are lb in- tenfe. 161 Table of the varii us degrees of heat. muft unite with the phlogiftori of the inflammable body, or with fomething elfe, fo that a decompofition may enfue : and it is this decompofition which produces the heat and light ; for then the fire contained in. the atmofphere having no longer any thing to abforb it, mull appear in its proper form. But in thofe cafes where there is a great quantity of phlogifton, and con- fequently much fixed air produced, the latter ablorbs fo much heat in a latent ftate, that the quantity communicated to furrounding bodies muft be greatly diminifhed ; and if by an excefs of this ingredient, not only fixed air, but the phlogiilicated kind and grofs fmoke be alfo produced, this diminifhes the heat ftill farther by the great abforption, and will even deftroy it altogether. The remedy for this is either to dimi- nifli the quantity of phlogifton, or to augment the quantity of air ; which, by furRiihlng a greater quan- tity of dephlogifticated bafis, affords an opportunity for the evolution of a greater quantity of heat. On the other hand, when the quantity of air is too great, the phlogiftic matter cannot combine with the bafis of the pure air in fufficient quantity to efFe£l a decompo- fition ; and therefore the heat is abforbed in a latent ftate, and the fire goes out. From this theory, which is further illuftrated under the articles Fire, FlaIwe, Heat, Phlogiston, &c. we may not only have a rational idea of the manner in which inflammation is generally accomphflied, but fee why a fire may be put out both by too great a quan- tity of fuel, and by too great a quantity of air. We may alfo fee why the folar beams and eleftric fluid, which contain no phlogiftic matter, excite a much more powerful heat than asy we can raife in our hot- teft furnaces. The difference between ignition and inflammation will now likewife appear; fuch bodies as are capable only of ignition containing little or no phlogifton, but inflammable bodies a great deal. The following table ftiows the moft remarkable de- grees of heat from the congelation of mercury to that of Mr Wedgewood's hotteft furnace. Mercury freezes at - - Weak fpirit of wine Brandy at - - - Cold produced by fnow and fait mixed Strong wine freezes at Vinegar freezes at Water freezes at • Temperature of fpring and autumn Ordinary fummer weather ^ - Sultry heat - - . Heat of human blood Feverifli heat Bees wax melts Serum coagulates Spirit of wine boils Water boils Tin melts Bifmuth melts Oil of vitriol boils Oil of turpentine boils Lead melts Quickfilver and linfeed-oil boil Iron begins to fliine in the dark Iron fliines bri/kly in the dark ijroA Ihinfs in. the twilight 40 32 10 o 20 27 32 65 75 97 to 100 108 142 156 174 212 408 460 550 561 585 600 635 750 884 Iron red-hot from a common fire Red heat fully vifible in day light ac- cording to Mr Wedgewood Heat by which his enamel colours are burnt on - - - Brafs melts - - Swedifli copper melts Fine filver melts Fine gold melts Leaft welding heat of iron; Greateft ditto Greateft heat of a common fmith's forge . - Caft iron melts , - Greateft heat of Wedgewood's fmall air-furnace - Extremity of the fcale of his thermo- meter * - - to^O 1077. 1857 3807 4587 4-717 5237 12777 13427 17327 17977 21877 32277 Theory. Attraiftion. V ^■ Sect. II. 0/ the DoElrine of EJeSlive Jttrac- tioriy and of the different OhjeSls of Chemi/iry^ Before we proceed to give a general theory of tlie Chcaiical changes which happen upon the mixtures of difi'srent attradtiun,. bodies together, or expofing them fingly to heat, we mull oblerve,. that all depend on certain qualities in bodies, by which fome of them are apt to join tegether, and to remain united while they have an op- portunity. The caufe of thefe qualities is totally un- known ; and therefore philofophers, after the example of Sir Ifaac Newton, have exprefled the apparent ef- fect of this unknown caufe by the word attradion. From them the word has been adopted by the che- raifts, and is now generally ufed in fpeaking of the phenomena which are obferved in the mixture of dif- ferent fubftances ; but to diftinguifti it from other kinds,, it is ufually called Eka'tve^ This attradlion is not equally ftrong between all fub- ftances ; in Gonfequence of which, if any body is com pounded of two others, and another is prefented to it which has a greater attradion for one of the compo- nent parts than they have for one another, the fub* ftance will be decompounded. A nevK compoimd is thea formed by the union of that third fubftance witli one of the component parts or elements (if we pleafe to call them fo) of the firft. If the attradion between the body fuperadded and either of the component parts o£ the other is not fo ftrong as that between themfelves,- no decompofition will enfue j or if the third fubftance is attrafted by both the others, a new compofition will take place by the union of all the three. jg^ The objefts of chemiftry, as we have already ob- Objedls of fierved, are fo various, that an enumeration of them chemiftry all is impolTible. To eafe the mind, therefore, when fpeaking of them, and render more ufeful any thing that is faid or wrote on chemiftry, it is neceflary to divide them into different claifes, comprehending in each clafs thofe bodies which have the greateft refem- blance to one another, and to which one common rule applies pretty generally. — The divifion formerly ufed,. was that of vegetables, animals, and minerals; but this has been thought improper, as there are many fubftances in each of thofe kingdoms which differ very widely from one another, and which are by no means fubjedi to the fame laws. The moft approved me- thod, i64 Salts. i'65 Theory. C H E M Saks, thod, at prefefit, of arranging the objefts of chemiilry, ■"v— — J 3 into falts, earths, metals, inflammable fubllances, waters, animal and vegetable fubllances. StCT III. Salts. Salts are either fuftlle^ tliat is, capable of abiding the fire, and melting in a ftrong heat, without being difiipated ; or volatile, that is, being difperfed in va- pour with a fmall heat. Their other properties are, that they are fohible in water ; not inflammable, unleis by certain additions ; and give a fenfation of taite when applied to the tongue. The moft general charadleriftic of falts is, that they are all foluble in water, though feme of them with much more difficulty than others. Moll of them have like- wife the property of forming themfelves, in certain circumftances, into folid tranfparent mafles of regular figures, different according to the different fait made ufe of, and which are termed cryjlah of that fait. In this Hate they always contain a quantity of water; and therefore the utmoft degree of purity in which a fait can be procured, is when it has been well cryftallized, and the cryilals are freed of their fuperfluous moitlure by a gentle heat. They generally appear then in the form of a white powder. Phenomena In the folution of falts in water, the firfl thing ob- Mtendj'ng fervable is, that the water parts with the air contain- their folu- . which immediately rifes to the top in the form of bubbles. This, however, is moll remarkable ■^'hen the fait is in the dry form we have jufl now men- tioned, becaufe there is always a quantity of air en- tangled among the interflices of the powder, which ri- fes along with the reft ; and this difcharge of air is fometimes fo great, as to be miftaken for an effervef- cence. From this, however, it is eflentially different. See Effervescence. Another thing obfervable in the folution of falts is, that a confiderable change happens in the temperature of the water in which they are diflblved ; the mixture becoming either a good deal warmer or colder than ei- tlier the fait or the water were before. la general, however, there is an increafe of cold, and fcarce any fait produces heat, except when it has been made very dry, and deprived of that moifture which it na- turally requires ; and thus the heating of falts by be- ing mixed with water may be explained on the fame principle with the heat produced by quicklime. See Quicklime. After fait has been dlffolved in a certain quantity by water, no more of that fait will be taken up unlefs the water is heated ; and as long as the heat continues to increafe, the fait will be diffolved. When the wa- ter boils, at which time it has attained its greateil heat, and will take up no more fait, it is then faid to be faturated with that fait. This, however, does not prevent it from taking up a certain quantity of another fait, and after that perhaps of a third, or fourth, with- out letting go any of the firfl which it had diffolved. How far this property of water extends, has not yet been afcertained by experiments. To the above rule there is only one exception known as yet; namely, common fea-falt: for water difTolves it in the very fame quantity when cold as when boiling hot. It has been faid by fome, that all deliquefcent falts, or thofe which grow moi£ on being 39? Salts I S T R Y. expofed to the air, had the fame property : but this is found to be a miilake. ~'i66~~' This property of folubility, which all the falts pof- Mixture fefs in common, renders them eafily mifcible together; and fepara- and the property by which moft of them ftioot in- tio" of to cryftals, renders thofe eafily feparable again which have no particular attraftion for one another. This is like wife rendered ftill more eafy by their requiring different proportions of water, and different degrees of heat, to fufpend them ; for by this they cryftallizc at different times, and we have not the trouble of picking the cryftals of one out among thofe of the other. _ _ ^ The manner in which the folution of falts in water Hfpothefij is effected, is equally unaccountable with moft of the concenmig other operations of nature. Sir Ifaac Newton fup- pofed that the particles of water got between thofe ° * of the fait, and arranged them all at an equal diftance fiom one another: and from this he alfo accounts for the regular figures they affume on paffing into a cry- ftalline form ; becaufe, having been once arranged in an orderly manner, they could not come together iu diforder, unlefs fomething was to difturb the water in which they were fufpended ; and if any fuch difturb- ance is given, we find the cryftals are by no means fo' regular as otherwife they would have proved. Others have thought that thefe figures depend on a certain ^o- lar'tty in the very fmall particles into which the fait is refolved when in a ftate of folution. Thefe things,, however, are merely conjedlural ; neither is- it a matter of any confequence to a chemift whether they are right or wrong. 168 Though folution is that operation which falts un- S . Its dc-' dergo the moft eafily, and which fhould feem to affe6l j^'^'"^''''^^^- them the leaft of any, a repetition of it proves n<^ver- jc^j^j'^j^jj^^ thelefs very injurious to them, efpecially if it is fol- lowed by quick evaporation ; and the fait, inftead of being cryfi;allized, is dried v/ith a pretty flrong heat. Newman relates, that a pound of fea-falt was reduced, by 1 3 folutions and exficcations, to half an ounce ; and even that was moftly earth. Where folution is requi- red, therefore, it ought always to be done in clofe vef- fels, in which alfo the fubfequent evaporation fliould be perfumed, (fee Evaporation); and in all cafes where cryftallization is prafticable, it ought to be" pre- ferred to violent exficcation. The two great divifions of falts are into acids and alkalies. The former of thefe are known by their pecu- liar tafte, which is> called aeid or four. They are not found in a folid form ; neither are any of them, except the acids of vitriol, of tartar, of phofphorus, and of borax, capable of being reduced to folidity. The o- thers, when highly concentrated, that is, brought to the utmoft degree of ftrength of which they are ca- pable, always become an invifible vapour, permanently elaftic, until it comes in contaft with water, or fome other fubftance with which they are capable of uni- ting. For fuch acids the name oi Jails feems lefs pro- per, as we can fcarcely fay that a vapoury which is al- ready much more fluid than water, &au be dijfolved ia that element. The acids are divided into the mineral, the vege- table, and the animal ; expreffing their different ori- gin, or where they are moft commonly to be found. The mineral acids are commonly reckoned three; the vi. 165^; Acids* 398 Salts. 170 Alkalies. 171 :Diffe;ent acSlion of ..alkalies and .acids. >7» Neutral felts. CHE M I vitriolic, the nitrous, and the marine. To this the acid of borax ought to be added; but its weaknefs makes it much lefs taken notice of as an acid than the others. A Swcdifli chemift, however, Mr Scheele, hath lately added feveral others, which are afterwards taken notice of. The vegetable kingdom affords only two diftinfl fpe- cles of acids, at lead without the affiftance of fome chemical operation. The one appears fluid, and when concentrated to the utmoft degree becomes an iuvilible vapour. This is produced from fermented liquors, under the name of vuiegar. An acid fimilar to this, and which is thought not to be effentially different from it, is extrafted from mofl vegetables by diftillation with a Itrong fire. The other is likewife a confe- quence of fermentation ; and crufts on the bottom and fides of caflcs in which wine is put to depurate itfelf. In its crude ftate it is called tartar; and when afterwards purified, is called the cream, or cryftals, of tartar. As for the various acids produced in the dif- ferent chemical procefTes to be afterwards related, we forbear to mention them at prefent, it being juftly fufpefted that fome of them are artificial. The animal acids, which have hitherto been difco- vered, are only two ; the acid of ants, and that of tirine, which is alfo the acid of phofphorus. The firft of thefe is volatile; and confequently mull be fuppofed a vapour when in its flrongeft flate : the other is ex- ceedingly fixed ; and will rather melt into glafs than rife in vapours. Befides thefe, it is faid an acid is con- tained in. blood, in wafps, bees, &c. : but no experi- ments have as yet been made on thefe to determine this matter with./iny degree of precifion. The alkalies "are of two kinds ; fixed and volatile. The fixed kind are fubdift'ided into two; the vege- table, and minei-al or foflU alkalis The vegetable is fo called, becaufe it is procured from theafhes of burnt vegetables ; the foflile, becaitfe it. is found native in fome places of the earth, and is the bafis of fea-falt, which in fome places is dug out of mines in vail quan- tity. They are called fxed., becaufe they endure a very intenfe degree of heat without being dilfipated in vapour, fo as even to form a part of the compofition of glafs. The volatile alkali is generally obt^ed by diftillation from animal fubflances. In its pure ftate this alkali is perfetlly invifible ; but affefts the fenfe of fmeUing to fuch a degree, as not to.be approached with fafety. The acids and alkalies are generally thought to be entirely oppofite in their natures to one another. Some, however, imagine them to be extremely fimi- lar, and to be as it were parts of one fubftance vio- lently taken from each other. Certain it is, that when feparated, they appear as oppofite. to one another as heat and cold. Their oppofite aftion indeed ver)' much refembles that of heat and cold, even when applied to the tongue ; for the alkali has a hot, bitter, burning tafte,. while the acid, if not confiderably concentrated, always gives a fenfation of coldnefs. In their aftion too upon animal fubftances, the alkali diffolves, and reduces the part to a mucilage ; while the acid, if not very .much concentrated, tends to preferve it uncor- rupted. If an alkaline fait, and moderately ftrong acid in a liquid ftate, be mixed together, they will immediately S T R Y. r ^ Theory. unite ; and, provided the alkali has not been depri- Sal-s. ved of its fixed air, their union will be attended with ' ' a very confiderable effervefcence : (fee Aerology.) If the alkali has been deprived of air, no effervefcence will enfue, but they will quietly mix together; but if a due proportion of each has been added, the li- quor will neither have the properties of an acid nor an alkali, but will be what is called neutral. The bring- ing the liquor into this ftate, is called faturattng the acid or alkali, or combining them to the point of fa- turation. If the liquor after fuch a faturation be gently eva- porated, a fahne mafs will be left, which is neither an acid nor an alkah, but a new compound formed by the union of the two, and which is called a perfect neu- tral fait. The epithet perfeS is given it, to make a diftinftion between the falts formed by the union of an acid and an alkali, and thdfe formed by the union of acids with earthy or metallic fubftances ; for thefe will likewife unite with acids, and fome of the compounds will cryftallize into regular figures ; but,becaufe of their weaker union with thefe fubftances, the falts refulting from combinations of this kind are called hnperfeS. All acids, the volatile fulphureous one excepted, actable change the blue infufions of vegetables, fuch as vio- colours * lets, to a red; and alkalies, as well as fome of the changed by imperfedl neutrals, change them to green. This is the ^<^'^s aud niceft teft of an acid or alkali abounding in any fub- ^'''^^'^s* ftance, and feems the moft proper method of determi- ning whether a folution intended to be neutral really is fo or not. Though between every acid and alkali there is a Differerjces very ftrong attraction, yet this is far from being the in the de- fame in all ; neither is it the fame between the fame g ee.s of at- acid and alkali in different circumftances of the acid, j.'^^^''"'' When the acids are in a liquid Hate, and as free as poffible of inflammable matter, between which and the nitrous and vitriolic acids there is a very ftrong attraAion, the vitriolic will expel any of the rell from an alkaline bafis, and take its place. Thus, if you combine the acid of fea-falt, or marine acid, to the point of faturation, with the foffil alkali, a neu- tral fait will be formed, which has every property of common fait : but, if you pour on a certain propor- tion of the vitrioHc acid, the acid of fea-falt will im- mediately be expelled ; and the liquor, upon being e- vaporated, will contain not the neutral fait formed by an union of the marine acid with the alkali, but ano- ther confining of the vitriolic acid joined with that al- kali, and which has quite different properties from the former. When the acids and alkalies are applied to one ano- ther in a liquid ftate, the vitriolic acid always ftiows itfelf to be the moft powerful ; but when applied in a folid form, and urged with a violent heat, the cafe is ver)' much altered. Tiius, the acid of borax, com- monly c?i\\t^i{>!in. phlogifton the moft powerfully, and feparates it even 195 from the vitriolic. A proof of this may be had by ''"'P-'"y_ de- boiling fulphur flowly In concentrated nitrous acid, j^llj"]^'^'"*^^" At length all its phlogifton may be feparated, and the trous^acij. vitriolic acid will remain, deprived of its principle of inflammability. The extraordinary iolvent powers of this acid, therefore, is conformed to the peculiarity ot its nature in this refpeft. For this menftruum diffolves metals for folution with the greateft eafe, moft com- monly without any affiftance from external heat; which fi^jj^*^ ^ in fome inftances would be hurtful, by feparating too fome metajj much of phlogifton, as appears in the cafe of Iron, tin, prepared by and antimony ; all of which may be fo far dephloglfti- "it' ous a- cated by the nitrous acid, as to be rendered ^^tremcly difficult of folution : for this reafon it Is very often after-* neceifary, as has already bes^u obferved, to temper the wards. aflivitv Theory. C H E M 197 Why the vitrioiic a c!d cannot a eft on lea.l, Cl- rer, &c. without a boiling heat. 198 Why ma- rine acid adts en Jome me Soluti'in aftlvlty of this meiiflruiim by water. The vitriolic ^"t tio-i ' ^'^'^ requires a boiling heat before it can aft upon iil- nj^ ver or mercury. The reafon of this is, that by means of the heat, the watery part of the menftruum is dimi- niflied, its power is thereby increafed, and the connec- tion of the metallic earths with the inflammable prin- ciple diminilhed. Marine acid, which contains phlo- gifton as one of its conftltuent principles, mull necef- farily have little or no efFeft on thofe metals which re- tain their principle of inflarhmability very obftinately. But its watery part being diminilhed by boiling, it afTumes an aerial form, and powei fully attra6is a lar- ger quantity of phlogifton than before ; fo that in a va- porous ftare it will diffolve metals, particularly filver and mercury, which in its liquid form it would fcarce tals and not be brought to touch. When dephlogifticated as much on others, as poffible, it attrafts phlogifton with prodigious avi- dity, diflolving all metals by its attraftion for their phlogifton, and, uniting the inflammable principle to itfelf, refiimes the ordinary form of marine acid. When dephlogifticated by means of nitrous acid in aqua re- gis, it difTolves gold and platina. On the fame prin- ciples may we account for its inferiority in power to the other acids. Why feme It has alread)' been obferved that the metals differ metals are much :n their degrees of folubility, which is owing to hiWe than ^^^^ various degrees of force with which they retain ©thers. pl^logifton. Thofe called perfeft metals effec- tually relift calcination in the dry way. In this opera- tion, the fire on the one hand, the great caufe of the volatility of bodies, ftrenuoufly endeavours to expel the phlogifton ; on the other hand, the bafts of the dephlo- gifticated part of the atmofphere (the acidifying prin- ciple of M. Lavoifier, and the pnnaphim forhile of Dr Lubbock) attrafts the calx ftrongly. Experience, however, fnows, that thefe two forces united, cannot decompofe gold, filver, or platina to any confiderable degree. All the other metals yield to thefe forces when united, but not fingly. Iron and zinc retain their inflammable principle fo flightly, that any acid immediately afts upon them; but if the other metals be properly prepared for folution by being calcined to a certain degree, the acid will immediately take them up. Any further privation, liowevtr, would be injurious, and precipitate what was before diftblved. Thus the precipitates ^^-^ when added to a lolution of tin or anti- ■n folution . . .... )f tin or iT»ony m marine acid, by its extraoroinary attraction mtimony. for phlogifton carries oft" fuch a quantity of it, that t^^e calces of the metals are immediately precipitated. Different kinils of air produ- ced during the dilTo- lutifin of metals. ioa Pure vi- triolic a- cid cannot 200 Why ni- trous acid The various elaftic fluids which refemble air, an5 which are produced in plenty during the difiohition of metals, may be reduced to theiollowing, in-x.. thofe ex- tiicated by the vitriolic, nitrous, and marine acids, fluor acid, vinegar, alkaline faks, and hepar fulphuris. Pure vitriolic acid expofed to a violent heat, is in- deed rtTolved into vapourti, but of fuch a nature, that when the heat is gone, they condenfe again into an a- cid liquor of the fame nature as btfore. But if any l)e reduced fubftance be added which contains phlogifton in a fe- " Tf^ 'm^" P^'^'^^^^ ftate, an elaftic fluid is produced by means of but h'y a w^^'^^' fcarcely condenfible by the moft extreme combina- Cold, unlefs it comes in contaft with water. This is tion with called the volatile fulphureous acid, or vitriolic acid phlogifton. air, which may be totally abforbed by water. In this cafe the bond of union betwixt it and the phlogifton Vol. IV. Part II. I S T R Y. 40E is fo weak, that the latter foon flies off totally, and Solution common vitriolic acid is regenerated. ^".'^ Preci- The nitrous acid undergoes a fimilar change in a more obvious manner. Let a piece of filver, for in- 203 ftance, be put into a dilute nitrous acid, and the fur- N'""o"s a- face of the metal will inftantly be covered with in- numerable bubbles, which arifing to the top of the H-chln^ed^ quor, there burft ; and if coUcfted, are found to be ni- 204 trous air. The nitrous acid faturatcs itfelf with plilo- Why til- gifton more completely than the vitriolic; therefore j""""' fi 1 n- a . . , . does not u- the elaltic fluid produced, or nitrous air, does not unite nj^g ^[.^ vv h water, and fcarce retains any veftige of an acid water, nature. The vitriolic acid, however, differs from the nitrous in this refpeft, that the phlogifton is abforbed by the latter even beyond the point neceffary to obli- terate its acid nature. In proof of this, our author addu ces the decompofition of hepatic by means of ni- trous air. The marine acid exhibits different phenomena. Phenomen* It naturally contains phlogifton, and therefore can ^'^'^'^'"^^ by Its means be refolved into a kind of air fomewhat ^"^l^' fimilar to that produced by the vitriolic acid when ar- tificially united to the fame principle, and whicl^ has the fanie property, wa. that of remaining permanent- ly elaftic as long as it is kept from the contadl of wa- ter. But as the acid we fpeak of naturally contains phlogifton, there is no neceffity of adding more to produce this effeft. In the mean time, the marine as well as nitrous air, when in its expanded ftate, attrafts phlogifton, and that with wonderful avidity. 206 When the marine acid is dephlogifticated, it yields another elaftic fluid of a reddifli brown colour, having ^^P^^J^''^"* an odour like that of warm aqua regia. This does mJ^ne a- not unite with water, or only in very fmall quantity ;cid. and by the addition of a proper proportion of phlogif- ton may be reduced again to common marine acid. It is faid that the marine acid may be dephlogifticated by lead as well as by manganefe, the nitrous acid, and arfenic. The fluor acid abounds with phlogifton, and there- Of th° fluor fore may, without any adventitious matter, be reduced acid, to an elaftic fluid. This air is eafily diftinguiflied from^ all others by its corrofion of glafs whilft hot. 208 Vinegar alfo contains phlogifton ; and for that rea- '^'^V fon, when well dephlegmated, may be reduced without addition into a permanently elaftic fluid, called acetous IfaTwith- , cut addi- , All thefe fluids feem to b? nothing elfe, according ''O"- to Mr Bergman, than the acids themfelves expanded 209 by phlogifton. Perhaps (fays he) the matter ofHeat and heat alfo enters their compofition." The experiments"?'^ r^^'"" lately made on thefe fubjcfts, however, have put it be-^rfn"*!^^ yond all doubt, that the expanfive principle is notof'elafti- phlogifton but heat ; neverthelefs, it ftems highly pro- city, bable, that thefe elaftic fluids do really confift of the acid united to phlogifton, and expanded by heat. This is alfo the cale_ with the cauftic volatile alkali, now called alkaline air. In the hepatic air, it has been ftiown by Mr Berg- Sulphir man, that fulphur exifts which contains phlogifton; andexifts in there is little reafon to doubt that the expanfive Wa"^ power here is the fame as in other cafes. See He pa- TIC Air. The heat generated during the folution of metals is by Mr Bergman fuppofed to be owing to the matter 3 E of 402 Solution and Precl pitatiou. proba!-)!y proceeds from the folvent li- quor. C H E M I of heat which had been fixed in the metals ; but it may with much more reafon be fuppofed to proceed from the acid. Dr Black has demonftrated, that heat is univerfally the principle of fluidity; and all fluids, Heat in fo- whether acid or not, are found to contain a great lution moft quantity of it. It is not probable that folids, even the proba^ilv j^q^ inflammable, contain an equal quantity ; for it is always obferved, that bodies in becoming fluid afaforb heat, and throw it out again on becoming folid. Acids in all probability contain a much greater quantity than what is neceflary to their fluidity ; for we fee that the nitrous acid, when poured upon fnow, parts with us much heat as is neceflary to diflblve the fnow, at the fame time that it fl:ill retains its fluidity. The cafe is not fo with common fait, which is a folid : for though, in a mixture of fait and fnow, the latter abforbs as much heat from the fait as is neceflary for its own li- quefaftion ; yet the fait could not be held in folution by a liquid of this temperature, were it not that an additional quantity is perpetually abforbed from the adjacent bodies, particularly the atmofphere. But were it polfible to prevent this adventitious increafe of heat, there is not the leail reafon to believe that the fait would be diflblved ; for the ftrongeft brine, when reduced to the temperature of o of Fahrenheit, is decompofed, the fait falling to the bottom in pow- der, and the water being converted into ice. Add to this alfo, that the cold produced by fpirit of nitre and fnow is much more intenfe than that produced by com- mon fait and fnow ; which undoubtedly fliows, that a «. s^^t folid does not readily part with as much heat as a fluid, Soild bo- , - , J ,r ri. die? do not and confequently cannot be iuppoled to contam as part with much. The folution of metals in acids alfo demon- ftrates, that the folid fubftance has not parted with heat, but abforbed it ; for as foon as the folution be- comes folid again, i.e. when it cryftalhzes, the tem- perature becomes higher than before. The calces of metals have not that quantity of phlo- gifton that is neceflary for their metallic fl;ate, but yet are not entirely deftitute of it ; therefore, in their fo- lution, fcarce any elaftic fluid is generated, unlefs the Are be continued after exficcation. Such as contain aerial acid, difcharge it immediately in the fame form as they had received it. It is remarkable, that Dr Prieftley mentions a calx of lead, which, with the acid of phofphorus, produced an inflammable air. By means of the nitrous acid and evaporation to drynefs, a pure air is produced. Sometimes a fmall portionjof vitriolic acid air is obtained by means of a proper degree of fire from vitriolic acid, but a far gieater quantity of fo much heat as fluids. "3 •Why little or no ela- ftic fluid is obtained fr6m me- tallic cal- ces. 5lt4 Meraiiic folutions contain a calx of ch? pure air. The folutions made by the menfl:rua above men- tioned, contain a metallic calx intimately united with the acid, the quantity of phlogifton left being va- metal with rious according to the difl"erence of the menllrua and various de- of the temperature; but the performance of the opera- grees of ^[^-^^ either with or without intenfe heat, frequently oc- phlogillon. ^^^^^^^^ ^ remarkable difference. That metals are lefs calcined by the marine than by the nitrous acid, ap- ■oears from pouring concentrated nitrous acid on tin or antimony ; but the diff"erence, if it atlually does take place, is lefs vilible in other metals. Some modern chemilts have denied this calcination of metals by folution. I'hey have infifted, that the perfed metals ought to be excepted, as they do not S T R Y. Theory. yield to the moft intenfe fire. On this fubjec^, how- Solnrfon ever, it may be obferved, i. That during their folu- tion nitrous air is always generated, and that of a very perfeft kind, which cannot happen without phlogi- Hon ; but in this cafe there is nothing prefent which Rearons can yield phlogifl:on except the metals. Therefore, t ^ r belie- 2. The metals, when precipitated from their menllrua ^^^j^'^j'^^'^*^ by fixed alkalis, both with refpeck to their external appearance and internal properties, appear to be cal- phlogifton. cined. Thus the precipitate of gold rcfufes to unite with mei-cury, and may be diflblved by marine acid and other fimple menfl;rua, and that without the prviduc- tion of any elafliic fluid. 3. Glafs may be ftained by thefe calces ; but no metal in its perfcdl ftate can be taken up by glafs. 216 The common objeAion is, that the calces of the Why the perfect metals may be reduced by heat alone without ^^■^'^^^ '^^ ^ the addition of charcoal. Many theories have been ^^llJ^l^ invented to folve this phenomenon. Some have fup- niay be re- pofed, that the matter of heat and light are the fame duce 1 vath- with the phlogifton, and that thus the calces are redu- ".'"^ ced in the fame manner as by charcoal or other fub- ' ftances ufually termed phlogiJHc. But in this cafe we ought to find the calces of the imperfeft metals alfo reduced by a long continuance of heat, as well as the more perfei\ ; which, however, has never yet been known to take place. Some, among whole number is Dr Lewis, have imagined, that the porofity of the veflels, particularly thofe made of earthen ware, may be fuch as to admit the pafliige of phlogiftic vapours through them ; and he inftances the revival of globules of lead in the middle of pieces of glafs upwards of an inch in thicknefs, and that where there was not the leaft appearance of a crack. But from an experiment of Mr Kirwan's, to be afterwards related, it is much more probable that the reduction is efi'efted by means of the phlogifton contained in one part of the calx ar- trafted by another ; by which means the latter is re. duced to a perfetl metal, while the foi'mer becomes fomewhat more dephlogifticated. In confequence of this it appears, that the calx of the perfect metals is never totally reduced : for if the operation be per- formed in a glafs retort, the bottom of it is always ftained ; which indicates the exiftence of a calx, in however little quantity. The following faft, Mr Bergman fays, has been D.fEculty propofcd to him as an inextricable dilemma. " Silver "^"i'lcerning cannot amalgamate with mercury except when in Jts*^*^^ metallic ftate, yet both faUted and nitrated filver are^,£ j^iy',,. taken up by mercury ; it is therefore not calcined by folved by the acids, but adheres to them in its metallic form." iiergman. This, however, may be eafily folved in the following manner. It is well known that the calx of copper, diflblved in the vitriolic acid, is precipitated in its me- tallic form on the addition of iron, and that by means of a double eleftive attraftion ; for the iron, dilTolving in the acid, would form an inflammable air by its phlogifton, were not the copper prefent which takes it up, and thereby becomes iiifoluble as long as it re- tains it ; but mercury has a ftronger attraftion for acids than filver : if therefore falited or nitrated filver be triturated with mercury, the iilver muft be preci- pitated in a metallic ftate, and th^ uitrtury be calcined by being diflblved. This alfo takes place, provided there be raoifture fufiicieat to fuifer the eledive attrac- tions and i-'reci- pit Kin 4l8 Pliio^ifton the caufe of colour in metal- lic folu- tions. Theory. C H E M Solution tioris to operate. The fuperabundant mercury greedi- ly takes up the comminuted filver precipitate ; and the arbo7-es Diana are nothing more than fuch an amalgam cryftalHzed. But although the acids cannot take up any frtetal while it retains ita full proportion of plilo- gifton, various metallic falts are able to effeft that ib- lution. Thus nitrated or falited mercury, boiled in water together with the crude metal, can take up a certain portion of it without dephlogifticati on J and t he latter of thefe falts, even in the via fcca, becomes a mercurius dulcis, which contains at the fame time a crude and a calcined mercury. Perfeft folutions (hould in general be tranfparent ; but fome, as has been already mentioned, nre diftin- guifhed by a peculiar colour. That phlogifton is the chief caufe of colour appears fr«m hence, that the black calx of manganefe tinges vitriolic acid of a red colour ; but on the addition of fugar the tinge is en- tirely deftroyed. Nitrous acid is rendered blue by copper ; but when the metal is added in confiderable quantity, it becomes of a very deep green. The ma- rine acid, which dephlogiilicatcs the copper lefs, is yet made green ; but by dephlegmation may be fp condenfed as to become brown. Mr Bergman has fometimes feen a folution of filver green, without the prefence of the fmalleft particle of copper. This de- pends on the abforption of nitrous air : for let fmoking nitrous acid be diluted, on the addition of a certain quantity of water it will be of a deep green ; by a greater, blue ; and upon a ftill greater, becomes lim- pid. By means of the water, the nitrous air is ex- tended to a greater fpace ; and this attenuation gradu- ally increafed varies the colours. Hence we fee why nitrous acid is made green by a large quantity of copper. Metals dephlogifticated by acid folvents powerfully attraft phlogillon ; nay, nitrated filver and mercury, and falited antimony, corrode animal fubftances, in or- der, as our authoj fuppofes, to extraft it. " This metallic caufticity (fays he), which is only to be mo- derated by phlogifton, ought to be carefully dillin- guifhed from, the acid caufticity, which is reprefled by alkalies, and the alkaline, which is mitigated by acids. Colours vary according to the quantity of phlogifton prefent ; and fome experiments ftiow, that by a fuffi- cient quantity all colour is entirely deftroyed. All metals may be precipitated by alkaline falts ; which, by their fuperior power of attraftion, feparate them from their menftrua ; but their difference with lion of me- regard to their nature and preparation alters the na- tal* by al- xmt of the precipitate. With the cauftic fixed alkali kalme falts. calces fall almoft entirely pure, but loaded with water. The weight is found to be increafed by the water, and perhaps (fays Mr Bergman) by the matter of heat ; but yet lefs than by the aerial acid. With the aerated fixed alkali, by means of a double decom- pofition, the aerial acid unites to moft calces. The vo- ktile alkaH, which naturally contains phlogifton, fome- times phlogifticates the precipitate. It throws down a black or white precipitate of mercury ; nay, it makes the orange-coloured precipitate white. Gold receives its fulminating quantity from this precipitant, as is af- terwards to be explained. The alkali, which is com- monly called phlogyilcakd, generally precipitates metals with an increafe of weight. I ai9 Attradion of phln- gifl-< n the cr.ufe of cwuftjcity. 320 Phenome iia attend injr the precipita- I S T R Y. 403 The acids frequently occafion precipitates, and that Solution for various reafons. By means of elective attraftion, ^I'^ Pf^ci- mercury, filver, and lead, are taken from the nitrous P'^^^^""' ^ acid by the addition of the marine or vitriolic. Thefe acids form with the metals new compounds which are Precipitates difficult of folution in water; they are therefore pre- '«afii>ned cipitated in greater or lelTer quantity according te ^i^"" ^^j^^'^*'. cumftances. The nitrous acid is capable of decom-' pounding falited tin and antimony by dephlogiftica- ting the calx of the metals too much ; for when thefe are too much calcined, they cannot be diflolved In any inenftruum, as has been already obferved. ztx Metallic folutions are fometimes difturbed by the^>' ''^^ P*^'"'! neutral falts formed by an union of alkalies with acids. £■^['^3"'^""^ Thofe which contain the vitriolic or marine acids de- compofe folutions of filver, mercury, or lead, in ni-g,"j'^j j trous acid, and precipitate the meta.ls. By forming a coutinua- triple combination, the vegetable as well as the vola- tiun. tile alkali> though faturated with vitriohc, nitrous, or marine acid, precipitate platina from aqua-regia ; but when the bafis is mineral alkali, the fait has no power .3^4 of this kind. Some metallic falts can decompofe '^^'^^ others, and precipitate their bafes ; which may hap-|i^'^^|,'^J^,'p^fj. pen whether the acid be diff'erent in the two falts or .thtrs. not. Solution of gold affords an example of each of 42.5 thefe cafes. This is precipitated by martial vitriol ; the reafon of which will appear from confidering the^'^j'^ ? nature of the precipitate : for this, when well wafhed cipitated and dried, not only fhows many fliining gold-coloured by Rreen particles, but alfo unites with mercury by trituration, ^^'""^» difTolves in aqua-regia, but not in marine acid alone, to- gether with other circumftances which evince a complete refufcitation of the gold. Martial vitriol, in its ordina- ry ftate, contains phlogifton, but very loofely adhering; fo that the calx of gold may eafily take it from the folution to fupply the lofs it had fultained during the folution. That this is the true foundation of the pro- 326 cefs, appears alfo from the following circumftances, "ot by that the weight of the gold is exaftly recovered, ^"^ivvhen^de that dephlogifticated vitriol will not precipitate thIsphi„gj{iiJ metal. The reafon that the furrounding aqua-regia cated. leaves this precipitate untouched is, that the men- ftruum is diluted and weakened by a large quantity of water ; for upon boiling it gently, fo as to expel part of the water, the menftruum recovers its folvent power, and takes up the precipitate again. It is fomewhat more difficult to explain the reafon why^folu- why the folution of gold in aqua-regia fhould be preci- lution of pitated by a folution of tin in the fame menftruum. " P''^" Here Mr Bergman firft fuppofed that the tin had ^^-'SSnll traded a fuperabundance of acid, and taken it from tin. the gold ; which being therefore deftitute of its pro- per quantity, muft fall to the bottom : but on employ- ing a folution containing a fuperabundant aqua regia, the fame precipitation took place. The caufe is therefore not in the menftruum. On examining the precipitate itfelf, we find nothing like the metallic fplendor of 228 gold, but that it entirely rcfemblcs a calx. It is eafily T!r6 prc- found by its weight, indeed, that It cannot confift en-^P*'.^''^ tlrcly of gold ; and in fadl chemical examination '^""^l'^* c fhows that it confifts partly of tin. It cannot be dif-tin. folved by the marine acid alone, but is eaiily taken up by the addition of a little nitrous acid. It fcarcely unites with mercury by trituration. Thefe properties feem to indicate, that the gold has fo far received phlo- 3 E 2. giftoa 404 Solution and Preci- pitation. 419 Precipita- tion (if me- tals by one another, owing to a double c- leffHve at- rraftion. Variations in the or- ^ Zinc, itedb <— ■■ ■ •ecipit J Antimony Mang. phlogifticated aerated mineral alkali cauflic phlogifticated aerated mineral alkali Yielded dry p: ecip. i8o i6o 140 142 161 495 140 138 138 180 168 150 a6i Difference "t-ctwixt themical attraclion and that of cohe- fion. C162 Geoffroy's phlogifticated aerated mineral alkali cauftic phlogifticated aerated mineral alkali cauftic phlogifticated Kirwan's Kirwan has made a great number of experi- dt finition ments on the attraftive powers of the mineral acids to of chenii- various fubilances, and greatly illuftrated the opera- cal attrac- ^^^^^ \io\}\ of folution and precipitation. Chemical at- traftion, he obferves, " is that power by which the invifible particles of different bodies intermix and u- nite with each other fo inthnately, as to be infeparable by mere mechanical means." Thus itdiff"ers from the attraction of cohefion, as well as from that of mag- netifm and eleftricity, as not afting with the indif- ference obferved to take place in thefe powers, but caufing a body already united to another to quit that and unite with a third ; whence it is called ehalve at- traftion. Hence attraftion of cohefion often takes place betwixt bodies that have no chemical attraftion for each other ; as for inftance, bifmuth and regulus of cobalt, which cannot be made to unite together by fulion, though they cohere with each other fo ftrong- ly, that they cannot be feparated but by the blow of a hammer. To determine the degrees of attradion betwixt dif- rule for ilrf- ferent fubftances, M. Geoffroy laid it down as a gene- Tfirnuning ^^^^ when two fubftances are united, and of dfemU^' either quits the other to unite with a third, that which cal attrac- tluis unites to the third muft be faid to have a greater tion. affinity to it than to the fubftance it has quitted.. In "^^^ many cafes, however, the feemingly fingle decompo- decompo- fiti"" i« ^^"^^1 ^ ^^^^^^^^ when the vi- fitions, tho' trioHc acid expels the air from a fixed alkali, it does feemingly not neceifarily follow, that the acid is more attratled /Jn ^^^^^^ ^""^ ^^^^ though the latter refigns its place to the acid, yet the acid gives out its fire to the air ; whence a decompofition might take place, even though the attraftive powers of both the vitriolic and aerial acid to the alkali were equal. To attain to any certainty in this matter, therefore, it is neceffary to determine the quantity and force of each of the attractive powers, and denote it by num- determined ^^grs. The necefTity of this has been obferved by Mr bcrs""^' I^orveau and Mr Wenzel, who have both propofed ^^^265 methods for aniwering the purpofe ; but Mr Kirwan True me- has fhowed that both are defedlive : and he tells us, thod of in- that the difcovery of the quantity of real acid in each veftigatinj/ ^^j- mineral acid liquors, with the proportion of real ty of at- 3Cid taken up by a given quantity ot each balis at the tradlioii point of faturation, led him unexpedtedly to what each of the feems the true method of inveftigating the quantity of Toflt ^^Tf a'^tradtion which each acid bears to the feveral bafes to f^reiA ba- ^vhich it is capable of uniting : " for it was Impoiriblc fcg. often deu- blc. 364 Force of the attrac- tive \ ow- ers to be 407 Solution and Preci- pitation. I S T R Y. (fays he) not to perceive, i. That the quantity of real acid neceffary to faturate a given weight of each balls is inverfely as the affinity of each bafis to fuch acid. 2. That the quantity of each bafis requifite to faturate a given quantity of each acid is direttly as the affinity of fuch acid to each bafis. Thus 100 grains of each of the acids require for their faturation a greater quantity of fixed alkali than of calcareous earths, more of this earth than of volatile alkali, more of this alkali than of magnefia, and more of magnefia than of earth of alum. *• If an acid be united to lefs of any bafis than is requifite for its faturation, its affinity to the deficient part of its bafis is as the ratio-which that deficient part bears to the whole of what the acid can faturate. Thus, if 100 grains of vitriolic acid, which can faturate no of calcareous earth, be united only to 55, its affinity to t"he deficient 55 parts fiiould be eftiniated one half of its whole affinity ; but its affinity to the retained part is as its whole affinity." 266 To explain the decompofitions in which thefe acids Method of are concerned, we muft confider, firft, the P^^^'^"^^ '^'"^'"^ which refift any decompofition, and tend to keep the portions af- bodies in their prefent ftate ; and, fecondly, the powers fecfted by which tend to effeft a decompofition and new union j acids alone, the former our author calls qulefcent affinities, the latter ^67 divelknt. A decompofition will therefore always take Quiefcent place when the fum of the divellent affinities is greater than the quiefcent ; and, on the contrary, no decom- ^-^^ " pofition will happen when the fum of the quiefcent affinities is greater than that of the divellent. All we have to do therefore is to compare the fums of each of thefe powers. The method our author takes to compare the affinities together is by the following table ; in which the quantity of alkali, earth, &c. fa- tu rated by 1 00 grains of each of the mineral acids, is ftated. Vc'g. fixed Mineral Calcsr aikali. alkali, earth. Vitriolic acid 215 165 1 10 Nitrous acid 215 165 96 Marine acid 215 158 89 Thefe numbers he confiders as adequate expreffions of the quantity of each of the affinities. Thus the af- finity of the vitriolic acid to fixed vegetable alkali Is to the affinity with which it adheres to calcareous earth as 215 to no; and to that which the nitrous ^69 acid bears to calcareous earth as 2 15 to 96, 6cc. Hence Expreffive we fum up the powers of affinity betwixt any number of different fubftances, and account for their decom- pofitions, as in the following example of the double ^^gy have decompofition, which takes place when a folution of for each vitrioluted tartar and folution of Ume or chalk in ni- ^^^'^ trous acid are mixed together. Vol. Map- Earth of Q.liantity alk. neiia alum, f acid ta- Qo 80 7 c "p }'y «„ „ - fTr- various ba- 79 71 55 ^licfceiit uiffinities. Vitriolic acid to vege- table fixed alkali, Nitrous acid to calca- • reous earth, Sum of quiefcent affinities '15 96 311 Divellent j^JJiniiies. Vitriolic acid to calca- reous earth, Nitrous acid to vege- table alkali, bafes. 270 ■ Decompo- firion cf 11 0 vitrlolated tartar by folution oC 2\ Sum of divellent affinities 325 J c ilcaicoua- — earth ex- plained. Hence we fee that a double decompofition muft enfue. The fame will be produoed, if Inflead of vkrlolated tartar wc make ufe of Glauber's fait 5. for the fum of 4o8 C E M I S T R Y. So'iMtioii end V red- pit a tion. 571 Coinci- dence of the above table with fxperience, Miftake of Dr Crell corredlcd. 373. Formation «)f triple and qua- druple falts. 274 Volatile al- Jialies ]iar- ticularly form falts of this kind. ns Vitriolic falts de- compofed by the ni- trous and marine a- cids, 176 Tl*fe de- compofi- tions fup- pofed to a- rife from compound forces. ilae qiuffcent aff.aitles Is 261, of the divellent 275 ; with vitriolic ammoniac the fum of the quiefcent is 186, of the divellent 195, &c. In mixing vitriolated tartar with foliition of magnefia in nitrous or marine acids, a double decompofition takes place though in- vilibly, as the vitriolic Epfom fait is very foluble in wa- ter, and therefore cannot be precipitated hkc felenite. In the former cafe the fum of the quiefcent powers is 290, of the divellent 295 ; in the fecond 286 and 295. Other decompofitions take place in the fame manner; and from all the fafts Avhich our author had occafion to obferve, he concludes, that the quantity of each af- finity, as determined in the above table, coincides ex- actly with experience ; and that thefe decompofiltons are perfeflly confillent with the fuperior affinity which has been hitherto obferved in the vitriolic and nitrous acids with fixed alkahes over the calcareous earths; nor do they infringe in the leall the known laws of affinity, as has been infinuated by fome chemifts. One faft only, mentioned in Dr Crell's Journal, feems to be repugnant to what is here advanced ; and that is, that if folutions of one part of alum and two of com- mon fait be mixed together, evaporated, and fet to cryftallize, a Glauber's fait will be formed ; though, in this cafe, the fum of the quiefcent affinities is 233, and that of the divellent only 223. Mr Kirwan re- peated this experiment without fuccefs ; and Dr Crell himfelf owns that it will njt fucceed but iij the moft intenfe cold. If it does fucceed at all, he fays the de- compofition mult arife from a large excefs of acid in the alum, which a£led upon and decompofed the com- mon fait : and this explanation is confirmed by the fmall proportion of Glauber's fait faid to be obtained by this procefs ; for from 30 lb. of common fait and 16 of alum, only 15 lb. of Glauber's fait were produ- ced ; whereas, if the whole of the alum had been de- compofed, there fiiould have been formed, according to Mr Kirwan's computation of the quantity of acid in the diiferent falts, 29^ lb, or, according to Mr Berg- man's, 22 lb. of Glauber's fait. In fome cafes, the neutral falts have a power of uniting, without any decompofition, or with only a very fmall one, to a third fubftance ; thus forming triple falts, and fometimes quadruple ; which often caufes anomalies that have not yet been fufiiciently in- veftigated. Volatile alkalies in particular are poffefied of the power of uniting with neutral falts in this man- ner. Hence they feem to precipitate magnefia from Epfom fait, even when perfeftly cauftic ; but this is owing to their combination with that fait, and form- ing a triple one, which is infoluble in water. It feems extraordinary that, according to Mr Kir- wan's table, the three mineral acids fliould have the fame affinity to vegetable fixed alkalies, when it is well known that the vitriolic will expel either of the other two from an alkaline bafis. In expHcation of this, Mr Kirwan obferves, that nitre is decompofed by the marine acid ; and that Glauber's fait and vitriolic am- moniac are decompofed by that of nitre ; and that t^iefe falts, as well as cubic nitre and nitrous ammo- niac, are decompofed by the marine acid. Mr Kirwan is of opinion, that thefe decompofitions are the effeft of a double affinity, or at leaft of com- pound forces. He fufpeded that they arofe from the N°7i. Theory. difi'erent capacities of the acids for elementary fire ; Solution and to determine this matter, he made the following ^"^^ Pieci- experiments, in which the decompofitions were not ^"^'^ ''""'^ difcovered by cryttallization, but by teils. 277 1 . Having procured a quantity of each of the three Experi- mlneral acids containing the fame proportion of real"^^"'* ^'^ acid, and reduced them to the temperature of -8^ °f tliL^ll^'the Fahrenhtit, lOO grains of vitriolic acid, containlrg various de- 26.6 of real acid, was projefted upon 480 grains of oil ^rees of of tartar at the fame temperature, by which the ther-^^*^^?"'* momcter was raifed to 128°. "'•*^.„ I ,,,, .J--.. mixtures. 2. An nunareu grains at ipint or nitre, containing alfo 26.6, projedted on 480 grains of oil of tartar, pro- duced only 1 20° of heat. 3. An hundred grains of fpirit of fait, the fpecific gravity of which was 1220, and which contained the ufiial proportion of real acid, raifed the thermometer from 69 to 129. " Hence (fays he) it follows, that the vitriolic acid Vitriolic contains more fpecific fire, or at leaft gives out more ^cid con- by uniting with fixed alkalies, than either the nitrous [(^^'g ^^^""^^ or marine; and therefore when the vitriolic acid comes ^j.'^ous in contact with either nitre or fait of Sylvius, its fire and ma- palTes into thefe acids, which are thereljy rarefied to a great degree, and are thus expelled from their aika- 279 fine bafis, which is then feized on by the vitriolic." — Difftcuitf On this, however, it is obvious to remark, that, ac- ^^'^ cording to Mr Kirwan's explanation, the marine acid, as giving out more fpecific heat, ought to expel the nitrous from an alkaline bafis; which, however, is not the cafe. Something elfe, therefore, befides the mere quantity of fpecific heat, mull here be taken into confi- deration. Mr Kirwan, however, goes on to prove tlie truth of his theoiy by the following experiments. 4. To 400 grains of vitriolic acid, whofe fpecific iiuifxni of gravity was 1.362, fixty grains of nitre were added; on ^l^f "'""ous which the thermometer fell from 68^ to 60°. During "jH'^jyJf the time of this defcent, the nitrous acid was not ex- luted. ' * pelled; for fome filings of copper, put into the mix- ture, were not afted upon in the leaft; but in five minutes afterwards they vifibly effervefced, which fiiowed that the nitrous acid began to be expelled; for tlie vitriolic acid does not ad upon copper but by a boiling heat. _ ' ^g, 5. Sixty grains of nitre were put to 400 of oil ofBythefame vitriol, whofe fpecific gravity was 1.870; the f her- mometer inftantly rofe from 68° to 105=, and the „[. ""''^ted, trous acid was expelled in a vifible fume. — " Thefe experiments (fays Mr Kirwan) prove, i. That neu- tral falts are not decompofed by mere folution in an acid different from their own. 2. That the nitrous acid, being converted into vapour, had imbibed a large quantity of fire. But as the vitriolic acid, in with a both thefe experiments, was ufed in much larger quan- fmall quan- tity than was necefiary to faturate the alkali of the^i'v "fdi- nitre, fixty grains of the latter were put into 64 of j"*^^"^' ^''"'^ tlie above mentioned dilute fpirit of vitriol, which con- ^g^^* tained the fame quantity of real vitriolic acid that the On the ex- 60 grains of nitre did of the nitrous ; Avith the addi- pulfion of tion of 40 grains 'of water and a few copper-filings. ".'^'"'^ ^* In lefs than two hours the copper was adled upon, "In^l'/j,'^^^^ and confequently the nitrous acid was expelled. ted vitrio- 6. To 400 grains of oil of vitriol, of the fpe-iic. clfic gravity of 1.870, 100 grains of common fait were added. An effervefcence immediately enfued, 5 and 2 So On tlie ex- On the de- cern fition of vitnolated taitar by nitrous a- Theory. C H E M Solution, and the marine acid rofc m white vapours. A ther- and Preci- mometer held in the liquor rofe only 4 degrees, but ^ pitat.on. froth it afcended to 10", and fell again upon being replaced in the liquor. Hence Mr Kirwan con- Botb the eludes, that the vitriolic acid gives out its £re to the nitrous and marine ; and that this latter received more than it "^^■""'"^ ^" could abforb even in the ftate of vapour, and therefore ceive fire communicated heat to the contiguous liquor. Tt ap- from the pears to him alfo, that the nitrous and marine acids vitriolic _ receive fire from the vitriolic, and are thrown into a vaporous ftate, or at leaft rarefied to fuch a degree as to be expelled from their alkaline bafis, tliough their affinity with that bafis may be equally llroug with the vitriolic. 7. To afcertain the manner in which vitriolated tartar and Glauber's fait are decompofed by fpirit of nitre, 60 grains of powdered tartar of vitriol were put into 400 of nitrous acid, v/hofe fpecific gravity was i.355> and which contained about 105 grains of real acid. The thermometer was not aiTeiled by the mixture ; but In 24 hours the vitriolic acid was in part difengaged, as appeared by the acid m.ixture afting up- on regulus of antimony, which neither pure vitriolic nor pure nitrous acid will do by themfelves. On put- ting the fame quantity of vitriolated tartar into 4C0 grains of fpirit of nitre whcfe fpecific gravity was 1.478, the thermometer rofe from 67'^ to 79°; the vi- triolated tartar was quickly diffolved, and the regulus of antimony fliowed that the vitriolic acid was dlfen- Acids unite gaged. Hence it appeared, that the nitrous acid, ha- Eo alkalies ying the fame affinity with the bafis of vitriolated tar- tar as the vitttolic, but giving out, during the folu- tion, more fire than was ntceflai-y to perform the folu- tlon, the vitriolic, receiving this fire, was difengaged : for as it cannot unite to alkalies without giving out fire ; fo when it receives back that fire, it muil quit them. The reafon why the nitrous acid, \idiich fpe- cifically contains lefs fire than the vitriolic, gives out fo much is, that its quantity in both thefe experi- ments is far greater than that of the vitriolic ; it be- ing in the firft as 105 to 17, and in the laft as 158 to 8. To 60 grains of fpirit of nitre, whofe fpecific gravity was 1.355, Kirwan added 1000 grains of water; and Into this dilute acid put 60 grains of vitrio- by d'iluted lated tartar, containing exaftly the fame quantity of real nitrous a- ^(^[^ ^j^g f^o grains of nitrous acid did. In eight days the vitriolated tartar was almoft entirely dlflx)lved, and without any fign of its decompofition ; and no nitre v/as found upon evaporating the liquor. Hence he concludes, that the nitrous acid can never decom- pofe vitriolated tartar, without the affift;ance of heat, but when its quantity is fo great that it contains con- liderably more fire, and by the adt of folution is de- termined to give out this fire. This fait is alfo dc- compofed, iti fimilar circumftances, by the marine a- cid ; though ftlU more flowly and with more difficulty than by the nitrous, as appeafs by the following ex- periments. 9. Into 400 grains of fpirit of fait, whofe fpecific gravity was 1.220, were put 60 grains of vitriolated taitar. The thermometer was not affefted in the leaft, and the fait diflblved very flowly. Some pulverized bifmuth was added to try whether the vitriolic acid was difengaged ; and in 1 2 hours part of it was dif- VoL. IV. Part II. aS6 by giving ©ut fire, and qu t tliCm by receivin.' Vitriolated tartar can- iiot be de- compofed cid. a88 Deconi])o- fjtion of vitriolated tartar by marine a- cid. I S T R Y. 409 folved, fo that it could not be precipitated by water. Solution This fhowed, that part of the vitriolic acid was dif- ^"'^j^^jy" ' lodged ; for this femi-metal cannot be kept in folution ^' ' ' « when much diluted with water, excepting by a mix- ture of marine and vitriolic acids. i^g In this experiment the quantity of marine acid was^^^*^'''^^' much arreater than that of the vitriolic ; and therefore r ^, •* ° . . ' . „ ccfs of this it v/as capable or diliodging it. ihis circumltance a- expeti- lone, however, is not fufficient ; the acid mull be dif- mcnt. pofed to give out by folution that quantity of fire which It is neceffary the vitriolic fhould receive in or- der to its quitting the bafis to which it is united ; and therefore when Mr Cornette added two ounces of fpl- 290 rit of fait to half an ounce of vitriolated tartar already \'itno!ated diiTalved in water, no decompofition took place. The|.||^'^j reafon of this w as, that as the vitriolated tartar was al- vvratei can- ready difTolved, no cold nor heat was generated by not be de- the mixture ; and therefore the fpirit of fait could not compcled give out any fire. Glauber's fait is more eafily decompo- ''Jjj^^^^^^ fed by marine acid than vitriolated tartar, on account of Its being more eafily foluble in fpirit of fait ; and likcwife becaufe its alkaline bafis takes up an equal quantity of both acids : confequently the marine gives out more fire In uniting to the bafis of Glauber's fait than on being united to that of vitriolated tartar. Vi- triolic ammoniac is alfo decompofed by means of ma- 291 rine acid ; but in all thefe cafes, the quantity of ma- Dccompo- rine acid muft greatly exceed that of the vitriolic ^'f^o" of contained in the fait to be decompofed; and it muft^'''"''''*: 1 111 T l ie - r -hr '.immoniac be remarked, that according to trie obiervations of Mr^nd Glau- Bergman, the decompofition of Glauber's fait or vi- bar's fait triolic ammoniac by this acid is never complete. hy marine On the fame principles the marine acid decompofes^''^^ never falts which have the nitrous acid for their bafis. Mr^""^^^^''^' Cornette found, that cubic nitre was more eafily de- Nitrous compofed by It than that which has vegetable alkali falts de- for its bafis. Accordingly, during the folution of '^""^1"*^^'^ prifmatic nitre, only three degrees of cold were pro- duced ; but fix by the folution of cubic nitre ; which fhows that the fpirit of fait gave out more fire in the latter cafe than in the former ; and its quantity mull always be greater than that of the nitrous acid con- tained in the mineral alkaline bafis ; becaufe this bafis requires for its faturation more of the marine than of the nitrous acid. The nitrous acid, however, in its Ma'^e turn decompofcs fait of Sylvius and common fait; but falts de- it mufl; always be in greater quantity than the marine compofed to produce that effea:. ^'^^ 10. Sixty grains of common fait being added to ' 400 of colourlefs fpirit of nitre, whofe fpecific gra- vity w^as 1.478, the misture quickly eff'ervefced and grew red, yet the thermometer rofe but two degrees ; which fliowed that the marine acid had aLforbed the greater part of the fire given out by that of nitre ; the decompofition was likewlfe hallened by the fupe- rior affinity of the nitrous acid to the alkaline bafis of the fea-falt : hence the decompofition of fea-falt by means of nitre takes place without any folution ; but fpirit of fait will not decompofe cubic nitre until It has firft diflblved it. This mutual expulfion of the ni- trous and marine acids by each other, is the reafon why aqua-regia may be made by adding nitre or nitrous ammoniac to fpirit of fait, as well as by adding com- mon fait or fal ammoniac to fpirit of rtftre. Selenite cannot be decompofed either by nitrous or 3 F marine 410 Solution and Preci- pitation 494 Selenites cannot be cieci :f, J o- fed by ma- rine acid. 295 Wliy the vitriolic acid af- fumes on evapora- tion the bafes itl had loft. 496 Difficuli ie^ in deter- mining the attradtive powers of the acids to metals. 297 Metallic falts info- luble in water without an excefs of acids. 298 Quantities of the dif- ferent me- tals taken up by a- cid. Metals have a greater af- finity with acids than alkalies. 3©0 Why alka- lies preci- pitate the «ietuls. C H E M marine acid ; becaufe it cannot be dlffolved in either without the affiflance of foreign heat. It muft Uke- wife be obferved, that in all decompofitlons of this kind, when the liquor has been evaporated to a cer- tain degree, the vitriolic acid expels in its turn the ni- trous or marine acid to which it had already yielded its bafis. The reafon of this is, that the free part of the weaker acids being evaporated, tlie neutral falts begin to cryilallize, and then giving out heat, the vi- triolic abforbs it ; and thus reacting upon them, exijels them from the alkali or earth to which they are united. Mr Kirwan found much more difficulty in deter- mining the attractive pov>'ers of the different acids to the metals tlian to aJkalne falts or earths. Some of the difficulties met with in this cafe arofe from the na- ture of metallic fubftances themfelves. Their calces when formed by fire always contain a quantity of air, which cannot be extrafted from them without great difficulty, and is very foon re-abforbed ; and if formed by folution, they as conitantly i^etain a part of their folvent or precipitant; fo that the prtcife weight of the metalline part can fcarce be difcovered. Our author, therefore, and becaufe metallic calces are generally in- foluble in acids, chofe to have the metals in their perfeft ftate : and even here they muft lofe a part of their phlogifton before they can be diifolved in acids, and a confiderable part remains in the folution of the acid and calx ; which laft quantity he endeavoured to determine. A new difficulty now occurred, arifing from the impoffibility of finding the real quantity of acid ne- ceflary to faturate the metal, for all metallic folutions contain an excefs of acid : the reafon of which is, that the falts formed by a due proportion of acid and calx are infoluble in water without a further quantity of acid ; and in fome cafes this quantity, and even its proportion to the aqueous part of the liquor, muft be very confiderable, as in folutions of bifmuth. It was 100 grains of Vitriolic 1 acid J Nitrous / acid ) Marine ] acid \ Though from this table, compared with the former, we might fuppofe that metals, having a greater at- traftion for acids than alkalies, could not be precipi- tated by them, yet Mr Kirwan obferves, that the com- mon tables, which poftpone metallic fubftances to al- kaline falts, are in reality juft, though there can fcarce be any room to doubt that almoft all metaUIc fubftan- ces have a greater affinity with acids than alkalies have. The common tables, he fays, are tables of precipitation rather than of affinity, as far as they relate to metaUIc fubftances. Thefe precipitations, however, are con- ftantly the refult of a double affinity and decompofi- tion; the precipitating metal yielding its phlogifton to the precipitated one, while the precipitated metal yields Its acid to the other. Thus, though copper in Its metallic form precipitates filver and mercury from the nitrous acid, yet the calx will precipitate nei- ther. The fuperior attradion the nitrous acid has to filver Iron. Copper. Tin. Lead. Silver. Merc. Zinc. 270 260 412 390 432 318 255 255 120 375 416 304 265 265 130 400 420 438 312 I S T R Y. Theory. In vain attempted to deprive thofe folutions of their Solution excefs of acid by means of cauftic alkahes and lime- water; for when deprived of only part of it, many of the metals were precipitated, and all of them would fo if deprived of the whole. As the folution of filver, however, can be very much faturated, Mr Kirwan began with it, and found that 657 grains of this folu- tion contained 100 grains of filver, and 31.38 grains of real acid, after making the proper allowance for the quantity diffipated in nitrous air. Nine grains of this folution tinged an equal quantity of folutioa of litmus as red as xo ^ grain of real acid of fpirit of nitre would have done ; whence our author concluded, that 9 grains of his folution of filver contained an ex- cefs of of ^ grain of real filver ; according to which calculation, the whole quantity ought to have contained 5.6 grains; which deduiied from jf.jS, leaves 25.78 grains for the quantity of acid faturated by 100 grains of filver. As the vitriolic folutions of tin, bifmuth, regulus of antimony, nickel, and regulus of arfenic, con- tain a large excefs of acid, Mr Kirwan faturated part of it with cauftic volatile alkali before he tried them with the infufion of litmus ; and the fame me- thod was ufed with folutions of iron, lead, tin, and regulus of antimony in the nitrous and marine acids. The proportion of vitriolic and marine acid taken up by lead, filver, and mercury, were determined by com- puting the quantity of real acid neceffaiy to precipi- tate thefe metals from their folutions in the nitrous a- cid ; which feemed to be the moft exaO: method of determining this point. The refult of all the expe- riments was, that 100 grains of each of thefe acidS take up at the point of faturation of each metallic fub- ftance, dephlogifticated to fuch a degree as is neceflary for its folution in each acid, the quantities marked In the following table. Zinc. Bifmuth. Nickel. Cobalt. Reg. of ant. Reg. ofarfen. 250 310 290 250 320 320 300 275 310 360 200 260 350 194 220 370 198 290 301 rather than fixed alkali, appears from the following ex- Nitrous a- perlment. If a folution of filver in nitrous acid becid attracts poured Into a mixed folution of alkali and fea-falt, ''Iver more the filver will be precipitated by the fea-fak into a luna ^J^^^l'^^*^ cornea, and not by the loofe alkali contained In the liquor. *' Now (fays Mr Kirwan), If the nitrous acid had a greater affinity to the free alkali than to the filver, it is evident that the filver would be preci- pitated pure, and not In the ftate of luna cornea ; but from Its being precipitated In this ftate, It is plain, that the precipitation was not accompHffied by a fingle but by a double affinity. Hence alfo the marine acid appears to have a greater attraftlon to filver than the nitrous has to fixed alkalies. The refult is fimilar when we make ufe of folutions of lead or mercury In the nitrous acid. Mr Bayen has alfo fhown, that vi- triol of lead and corrofive fubllmate mercury cannot be deprived of more than half their acid, even by cau- ftic fixed alkalies. With Theory. Solution CHEMISTRY. With regard to lead, If perfeftly dry fait be projcft and Pi-eci- ^}^ig meta^ heated to ignition, the common fait will ^Illa tion. decompofed, and plumbum corneum formed. Nor can we attribute this to the volatilization of the alkali Sea-falt de- by heat ; for the alkali is as fixed as the lead, and compofed rauft therefore be caufed by the fuperior attraction in various y^r\^[Q\^ xh^ calx of this metal, even when dephlogifti- means^of ^^t^^' ^'^^ marine acid. Mr Scheele informs lead. "s, tliat if a folution of common fait be digelled with litharge, the common fait will be decompofed, and a cauftic alkali produced. It may alfo be decompofed fimply by letting its folution pafs flowly through a fun- nel filled with litharge ; and the fame thing happens to a folution of calcareous earth in mai-ine acid ; which (hows that the decompofition takes place merely by the fuperior degree of attradion betwixt the acid and me- tallic calx (a). That acids have a greater attraftion for metallic earths than volatile alkalies, is flill more evident. Luna cornea is foluble in volatile alkalies; but if this folution be triturated with four times its weight of quick fdver, a tnercurius dulcis, and not fal ammoniac, is formed. The reafon why alkahes and earths precipitate all metallic fo- lutions is, that the metals are held in folution by an ex- cefsof acid. Even if the alkaline and earthy fubftance did no more than abforb this excefs of acid, a precipi- tation muft necelTarily enfue ; but they not only take Up this fuperabundant acid, but alfo the greater part of that which is neceffary to faturate the metalHc earth. This they are enabled to do by means of a double af- finity ; for during the folution of metals, only a fmall part'of the phlogiRon, comparatively fpeaking, efcapes, the remainder being retained by the compound of acid and calx. When therefore an alkali or earth is added to fuch a fdlulion, the phlogifton quits the acid, and joins with the calx, while the greater part of the acid reunites to the precipitate. Notwithftanding this greet affinity, however, of metaUic earths to acids, there are but few inftances of their dtcompofmg thofe falts which have an alkali or an earth for their bafis, by rea- fon of the inability of the acids, while combined with thefe bafes and thereby deprived of a great part of 303 Acids at- traift me- tallic earth more ftrongly , than vola- tile alluli. 304 Why the tnetal'ic ear hs fcl- don-. ■r'e- conip' fc fait- ha- viu'; :'.n 305 I)ecom]io- fition <.if ^iefcent Affinities. Nitrous acid to fdver, 375 Vitriolic acid to ve- 7 ^ ^ getable alkali, 5 ^ Divellent Affinities, Nitrous acid to ve- ^ getable alkali, 5 Vitriolic acid to lilver, 215 605 411 Solution and Preci- pitation. 306 eaithor al- ^j,. ;^ gre, to volatilize the phlogilton combi- their^bafis. ""^^ ^^^^^ metallic earths, which mrift neceffarily be expelled before an acid can combine with them: and as to the metallic calces, they are generally combined w ith fixed air, which muft alfo be partly expelled ; but ammonlacal falts (containing much more fire, for they abforb it during their formation) for that reafon aft much more powerfully on metals. Allowing then the affini- ties ot the mineral acids with metalhc fubftances to be as above, all double decompofitions, in which only faks containing thele acids united to alkaline, terrene, or metalHc bafes, are concerned, admit of an eafy explana- tion ; nay, fays Mr Kirwan, I am bold to fay, they vitrktlated cannot otherw ife be explained. Thus, if a folution tartar hy of tartar vitriolate, and of filver in the nitrous acid, be folution (.f ir.ixed in proper proportion, nitre andvitriol of filver will filver ex- formed: and this latter for the mofl. part precipitated, plained; 590 Thus alfo, if, inftead of a folution of tartar vltrio-And of^ late, that of Glauber's fait, or of vitrioHc fal ^^'^^■^{^^"Jl^Jig^ niac, felenite, Epfom fait, or alum, be ufed, the ba- '^^^^^^^ lance is conftantly in favour of the divellent powers 5 and niac, &c. a precipitation is the confequence, though but flight when felenite or alum are uled. ^07 Solution of filver is alio precipitated by the vitriolic In what ca- folutions of iron, copper, tin, and probably by many folution other folucions of metals in the vitriolic acid ; for t^'SpreclpiTa-* reafon, among others undoubtedly, that they contain ^e.i by fl- an excefs of acid : but if a faturated folution of filver 'her nic- be mixed with a very faturated folution of lead or mer-t^''* cury in the vitriohc acid, the filver will not be preci- pitated ; and in both cafes the balance is in favour of the quiefcent affinities. 308 All the marine neutral falts, whether the bafis be al- ^^^"^'^ kaUne, terrene, or metallic, decompofe the nitrous folu- j-^^ll^^^. tion of filver ; and thefe decompofitions are conftantly rinefalti; indicated by the balance of affinrties already defcribed. The fame thing alfo takes place with folution of filver in the vitrioHc acid, as is indicated alfo by the lame 3°9 table. The nitrous folution of lead is alfo decompo- f^^^lfo fc fed, and the metal for the moft part precipitated, un-j^^^^^ lefs the folution be very dilute in the form of vitriol of lead, by all the neutral falts containing either the vi- triohc or marine acid, excepting only the combination of filver with marine acid, which precipitates it in no other v?ay than by its exdefs of acid. 310 Solution of lead in mariire acid is decompofed by all ^°^^V°" the neutral falts containing the vitriolic acid, excepting ^^'^.j^^" g_ only felenite and folution of nickel in oil of vit: iol. Thefe dd decom- can only precipitate it by virtue of an excefs of acid, pofed by Nitrous folution of mercury is decompofed by all the ^"^'"'^^^'^ neutral falts contaitiing the vitriolic acid, except vitriol ' of lead, which only decompoies it by an exce ls of acid. Alfo ni* All the falts containing marine acid decompofe the trous folu- nitrous folution of mercury, excepting the combina- °^ tions of marine acid with filver and lead, which decom- "^^^^ i ' pofe it by fxcefs of acid. And by Thefe fah s alio decompofe vitriol of mercury, tho'the falts a precipitatioii does not always appear, owing, as Mr '^'^"'.^'"'"5 Kirwan fuppofes, to the facility with which a fmall quan- ^* tity of the marine fait of mercury is foluble in an excefs 313 of acid. Marine lalt of filver, however, decompofes vitriol Vitriol of of mercury only through its excefs of acid. Hence we m' rcury fee why luna cornea can never be reduced by fixed al- fj^i h'^^^j, kalles without lofs; and were it not that the atlion ofnne acid, the alkah is affifted by heat, it never could be reduced 314 by them at all. Why luna When oil of vitriol is mixed with a folution of cor- ^°nn!)t be rofive fublimate, a precipitate falls: but this, as Mr reduced Bergman remarks, does not proceed from a decompo- without 3 F 2 fition '°f« ,t>y alkaline falta. (a) Thefe experiments have been repeated by many other chemlfts without fuccefs : and Mr Wiegleb informs, that none of thofe who have attempted to decompofe fea-falt by means of lead, ever found their me- thods anfwer the purpcfe. 412 So'utlon and Preci- pitation. 315 Precipita- tion of cor- rofive mer- cury by oil of vi- triol ex- plained. 316 Table of the affini- ties to the different metals ex- plained. 317 Of the tjuantity of phloijifton contained in the dif- ferent me- tals. Method of calculating this quan- tity exem- plified in regulus of a.'-fQnjc. 3T9 Tabie i.f_ the quanti- ties of phlo- gifton in differeiit metals,. Exp.ri- mf iit^ e^" plaii'injij the reduc- tion of ftlver per C H E M fitlon of tl»e mercurial fait, but from an abftraftion of the water neceffary to keep the fublimate diffolved. In the foregoing table t«^o different affinities are af- figned to the vitriolic acid with regard to bif- muth and nickel ; one fliowing the affinity which thefe acids bear to the metals when dephlogiilica- ted only by folution in the acids ; the other that which the acids bear to them when more dephlo- gifticatcd, as when they are dilfolved in the nitrous acid. On the other hand, all the acids have lefa affi- nity with the calces of iron, zinc, tin, and antimony, when they are dephlogifticated to a certain degree ; but our author found himfelf unable to give any cer- tain criteria of this dephlogidication. The moft difficult point to be fettled .was the pre- cipitation of metals by each other from the mineral acids. To determine this it was neceffary to find the quantity of phlogifton in each of them, not only in their natural ftate, but according to their various de- grees of deplilogiftication by each of the acids. The fubftance he chofe for determining the abfolute quan- tity of phloglfton in a metallic fubrtance was regulus of arfenic. An hundred grains of this femitnetal diffol- ved in dilute nitrous acid yielded 102.4 cubic inches of nitrous air; vi'hich, according to his calculations on ttiat fubjeft, contain 6.86 grains of phlogifton : and hence he concluded that 100 grains of regulus of arfenic con- tain 6.86 grains of phlogifton. From this experi- ment, three times repeated with the fame fuccefs, our author proceeded to form, by calculation, a table of the abfolute quantity of phlogifton contained in me- tals, the relative quantity having been computed by Mr Bergman, and his calculations adopted by our au- thor. Thefe quantities are as follow. too. grains Gold Copper Cobalt Iron Zinc Nickel Regulus of ) antimony 3 Tin Regulus arfenic SiWcr Mercury Bifmuth Lead ■'1 Rc'ative Abfo'ute (^:antity. Quai:tity. 394- 24.82 312 • 9.65 270 J 7.0 1 233 14.67 I 1.46 156 9.82 1 20 7.56 114 7.18 ■ 109 <).86 ICO 6.30 7+ 4.56 57 3-59 43 2.70 This point he likewlfe endeavoured to afcertain by other experiments. As filver lofts a certain quantity of phlogifton, which efcapcs and feparates from it du- ring its folution in nitrous acid, he concluded, that if the fojuiion was expofed to nothing from which it could reobtain phlogifton, and this was dlftilled to dry- nefs, and entirely feparated from the acid, as much fil- ver fhould remain unreduced as correfpondcd with the quantity of plilogifion loft by it ; and if this quantity correfpondcd with that in the above table, he then had good reafon to conclude that the table was juft. For this purpofe 120 grains of ftandard filver were diffolved in dephlogifticatcd nitrous acid diluted with water, and he obtained from it 24 cubic inches of ni- trous air. This folution was gently evaporated to I S T R Y. Theory. drynefs ; and he found that, during the evaporation, Solution about a quarter of a grain of the filver had been volati- ii''d Preci-j llzed. The dry refiduum was then dlftilled, and kept , an hour in a coated green-glafs retort heated almoft to * ' a white heat. Abundance of nitrous acid paffed off during the operation, and a green and white fublimate rofe into the neck of the retort, fome of it even paf- fing over into the receiver. On breaking the retort, the infide was penetrated with a yellow and red tinge, and partly covered over with an exceedingly fine filver pow- der, which could fcarcely be fcraped off. The re- mainder of the filver was white, and perfedlly free from acid, but not melted into a button. On being collefted, it weighed 94 grains; confequently 26 grains had been loft either by fublimatlon or vitrification ; but of thefe 26 grains 9 were copper ; for 100 grains of ftandard filver contain 7^- of copper, therefore only 1 7 grains of pure filver remained unreduced, being ei- ,j ther volatilized or vitrified. The whole quantity of Quuntity pure filver in 120 grains of ftandard filver amounts to ''f pi'^e mc- 1 1 1 grains ; then if n i grains of pure filver lofe 17 ^''^ by being deprived of its phlogifton, ico grains of the Sn^arci fame fliould lofe 15.3; and hy the above table 15.3 filver. ' grains of filver fhould contain 0.945 of a grain of phlogiflon. Now, 100 grains of pure , filver afford 14 cubic inches of nitrons air, which, according to our author's calculation, contain 0.938 of a grain of phlogifton ; and this differs from 0.945 only by .007 of a grain. ** In this experiment (fays Mr Kirwan) only as much of the filver fublimed as could not regain phlogifton ; the remainder regained it from the nitrous air abforbed by the folution, and by that which remain- ed in the acid and calx. If this were not fo, I do not fee why the whole of the filver would not fublime." Dr Prieftley having feveral times diffolved mercury Exarnina- in the nitrous acid, and revivified it by diftilhng over*'°!^°^ that acid, conilantly found a confiderable portion of it 2^Jcrimen> unreduced. ^ To try whether that proportion corre- coiicerning fponded with his calculation, Mr Kirwan examined the revival Dr Prieftley's experiment, in-z. that having diffolved °^ 17 penny-weights 13 grains (321 grains) of mercury in nitrous acid, 36 grains ren\pined unreduced. Ac- cording to Mr Klrwan's calculation 56 grains ftiould have remained unreduced; for 100 grains of mercury afford 12 cubic inches of nitrous air; of confequence 321 grains ftiould afford 38.52, which contain 2. 5S of phloglftlon : and if, as according to the table, 4.56 grains of phlogiliion be neceflary to metallize 100 grains of mercury, 2.58 grains will be necefHiry to metallize 56 grains of the fame metal ; and our author is fatisfied from his own trials, that more than 50 grains would have remained unreduced, if dephlogifti- catcd nitrous acid had been ufed in diffulving the mer- cury, and the folution performed with heat and a ftrongacid: but that which the Dodor ufed was ofwhy^fo the fmoking kind, and confequently contained a con- much of fiderable quantity of phloglftlon already, which un- ''^^ "^'^'^l doubtedly contributed to revive more of the metal JJ^g"") than would otherwife have been done. It is true, DocftorV^ Dr Prieftley afterwards revived a great part of what experi- had originally remained unreduced ; but this happened ^ents. after it had been fome time expofed to the free air, from which the calces of metals always attraft phlogif- ton ; as Is evident in luna cornea, which blackens on be- ing expofed to the air. By another experiment of Dr Prieftley's, it was found >, Theory. CHEMISTRY. 415 Solution and Preci- \)itation. 324 Of the re- v.val cf lead from nunium by jiiflam- niabie air. 32.? Mr Kir- wan 's re- marks on the expe- rinicnts of Dr i'l ieft- ley. 326 Of the at- found, that nearly five pennyweights of minluin, from whence all its air was extrafted, that is, about Ii8 grains, abforbed 40 ounce-meafures, or 75.8 cubic inches of inflamm?ble air, containing 2.65 grains of phlogi'lon, by which they were reduced. An hundred grains of minium, therefore, require for their reduc- tion nearly 2.25 grains of phlogifton. In another experiment made with more care, he found, that 480 grains of minium abforbed 1 08 ounce-meafures of in- flammable air : fo that, according to this, 100 grains of minium require for their redudlion 1.49 grains of phlogifton ; and in two fucceeding experiments he found the quantity flill lefs. On this Mr Kirwan re- marlcf., i. That the whole of the minium was not de- phlogifticated ; for it is never equally calcined, and befidcs much of it muft have been reduced during the espulfion of its air. 2. The quantity of phlogifton in the inflammable air may have been greater, as this varies wiih its temperature and the weight of the at- mofphere: fo that on the whole thefe experiments con- firm the refults expeffcd in the table. Mr Kirwan next proceeds to confider the attraftion nietalUc calces lo phlogifton. gravity of the diiTe- rent nic- taihc cal- ces. traaion of of metallic calces to phlogifton. Inflammable air, when condenfed into a folid fubftance, he fuppofes not only equal, but much fuperior, to any metallic calx in fpecific gravity ; and therefore, if we could find the fpecific gravity of any calx free both from phlogiffon and fixed air, we would thus know the denfity which phlogifton acquires by its union with fuch calx. It Of fiMd'ng ^35' however, hitherto proved impofiible to procure thefjiecific calccd in fuch a ftate ; as, during their dephlogiftica- tion, they combine with fixed air or fome particles of the menftruum, whence their abfolute weight is in- creafed, and their fpecific gravity diminiflied. Hence it appears, that the^ fpecific gravity of the calces differs much lefs fi-om that of their refpeclive metals, than the fpecific gravity which the phlogifton requires by its union with thofe calces from that which it poffefTes in its uncombined ftate. Hence, inftead of deducing the quantity of afilnity betwixt phlogifton und metallic cal- ces from the following propofition, that " the affinicy of metaUic calces to phlogifton is in a compound ratio ^28 of its quantity and denfity in each metal," he is obliged Whence to deduce it from this other, that " the affinity of me- iheir va- t^iijc calces to phlogifton is direftly as the fpecific ""ees of'af- °^ lefpeAive metals, and inverfcly as the InUy to quantity of calx contained in a given weight of thefe phlogifton metals." This latter propofition is an approximation to the former, founded on this truth, that the larger may be de termined. pitation. the quantity of phlogifton in any metal is, the fmaller Sohuion is the quantity of calx in a given weight of that me- tal;" and, that " the denfity which the pholgifton ac- quires is as the fpecific gravity of the metal." This latter propofition, however, is not flrlftly tru?, -fn* this denfity is much greater; but its defetl is only fen- fible with regard to thofe metals which contain a confiderable quantity of phlogifton, as gold, copper, cobalt, and iron. With regard to the reft, it is of no importance. The fpecific gravity of the different me- tals, then, being as reprefented in the firft column of the following tabic, the affinity of their calces to phlo- gifton will be as in the fecond ; and the third ex- in numbers homogeneous with the affinities of acids with their preffes the affinities thofe which exprcfs bafis. Specific Gravity, H 1 1. 09 1 8.8 9.6 7-7 7-7 } 8.31 7.24 7 6.86 Prcpovtionable Af-initi'js. o 25 C.I 47 O.I I 8 0.1 16 O. ! 09 O.C99 0,092 0.090 0.089 0.0812 0.075 Real Affinities of Tabic of Calx to Phlogift.the pro- 1041 612 491 483 454- 41 2 383 375 370 338 312 308 j-.ortional affinities of metallic calces to phl( giuoniu Gold Mercury Silver Lead Copper Bifmuth Cobalt Iron Regulus of Arienic Zinc Tin Regulus of ^ 6.86 0.074 Antimony 3 From this table we way fee why lead is ufeful in Why'^lead' cupellation ; namely, becaufe it has a greater affinity '■'fefitl in- with phlogifton than the calces of any of the other '^^r^il^'^o'*' imperfe£l metals ; confequently after it has loft its own phlogifton, it attra£ts that of the other metala with which it is mixed, and thus promotes their calci- nation and vitrification. The third point neceffary for the explanation of the Quaiitityoi: phenomena attending the folution of metals, and their J hloglfton precipitation by each other, is to determine the P^O" [^j^ portion of phlogifton which they lofe by folution in calcination each of the acids, and the affinity which their calces bear to the part fo loft. Though our author was not able to determine this by any direft experiment, yet from various confiderations he was led to believe that it was as follows :. By the vitriolic acid By nitrous acid By marine acid Quantity of Phlogifton feparated From Iron, Coiiper, Tin, Lead, Silver, Mercury, Zinc, Bifmuth, Cobalt, Nickel, Reg. (;f Ant. Reg. of Aff. T 100 100 6 To Entire Entire J 00 8J To "o Entire ^Vn -A^o tVtt Entire Entire Entire f 00 3»9 ^ni^^ of "^^^^ affinity of the calces to the deficient part of calces t< "the their phlogifton may now be eafily calculated; for deficient they may be confidered as acids, v/hofe affinity to the deficient part of their bafis is as the ratio which that part bears to the whol'e. Thus the affinity of iron, thoroughly deprived of its phlogifton, being 375, as it lofes two-thirds of its phlogifton by folution in the vitrolic acid, the affinity of iron to thefe is two- thirds of its whole affinity ; that is, two-thirds of 375, cr 250. 6 To Ji J!_4 J 00 Thus we may eafily conftruA a table of the affinities tTfs'^of of the phlogifton of different metals fiar their cal- thefe cal- ces ; and from this and that formerly given, by which culationa the affinities of the acids to the metallic calces was ex- f^^^^^^^^^ prelfed, we may guefs what will happen on putting one j^g ^ metal in the folution of another. Thus if a piece of ori thepi .e^ copper be put into a faturated folution of filver, the ''omena of filver will be precipitated; for the balance is in [fjiQ^*^""^*" vour of the divellent powers, as appears from the fol- lowing calculation.. part of ifieir phi 414- NitrouG acid to filver 375 Calx of copper to phlogifton of the '} 363 354 Of the. ex- cefs of a- cid in fo- lutions pro- per for ma- ting thefc experi- ments. 335 \Vh- the metals are more de- phlogifli- catcd by mutual pre- . cipitatidU that! by di- rect folu- tion. 336 "Why cop- per is '^il- folved by ffilution of filver, mer- cury, or i- Ton. 337 Iron and zinc the only metals difTolved by vitriolic a- cid. 338 Nitn.us a- cid diffolves all metals, though it has lefs af- finity with thorn than the viti io- 11 c or ma- rine. 339 Why if cannot dif- Iblve them when much concentra- ted. 340 In what cafes the marine a- cid can dif- folve me- tals, and when it cajinot. C H E M I D'lveUeiit Affinities. Nitrous acid to copper 255 Calx of filver to ) phlogiilon 5 ' Sum of the divel- ■> ^ lent I Sum of the quief- \ „ cent affinities \ ' ^ In making thefe experiments the folutlons muft be nearly, though not entirely, faturated. If much fu- perfluous acid "be left, a large quantity of the added metal will be difFolved, before any precipitation can be made to appear ; and when the folutlon Is perfeft- ly faturated, the attraftion of the calces for one another begins to appear ; a power which fometimes takes place, and which has not yet been fully inveitigated. In this way the precipitating metals are more de-, phloglfticated than by direft folution in their re- fpeftive menftrua ; and are even difiblved by men- ilrua which would not otherwife alFedl them. The reafon of this id, that their phlogifton is afted upon by two powers inftead of one : and hence, though copper be diredlly foluble in the vitriolic acid only when in its concentrated ftate, and heated to a great degree ; yet if a piece of copper be put into a folution of filver, mercury, or even iron, though dilute and cold, and expofed to the air, It will be difTolved ; a circtimftance which has juftly excited the admiration of feveral emi- nent chemitts, and which Is Inexplicable on any other principles than thofe juft now laid down. From this circumflance we may fee the reafon why vitriol of cop- per, when formed by nature, always contains iron. Mr KIrwan now proceeds to confider the folu- tlons of metallic fubftances in all the different acids. Vitriolic acid, he obferves, dlffolves only iron and zinc of all the metallic fubftances, becaufe its afiinity to their calces is greater than that which they bear to the phlogifton they muft lofe before they can unite with it. Nitrous acid has lefs affinity with all metallic fub- ftances than either the vitriolic or marine ; yet It dlf- folves them all, gold, filver, and platina excepted, though it has even lefs affinity with tliem than they have with that portion of phlogifton which muft be loft before they can diflolve in any acid. The reafon of this Is, that it unites with phlogifton, unlefs when in too diluted a ftate ; and the heat produced by Its union with phlogifton is fufficient to promote the folution of the metal. On the other hand, when very concen- trated, it cannot diffolve them ; becaufe the acid does not then contain fire enough to throw the phlogi- fton into an aerial form, and reduce the folid to a li- quid. The marine acid dephlogifticates metals lefs power- fully than any other. It can make no folution, or at leaft Gjm operate but very flowly, without heat, in thofe cafes where the metallic calx has a ftronger affinity with that portion of the phlogifton which tnuft be loft, than the acid : nor can it operate brifldy even where the attraftlon is ftronger, provided the quantity of acid be fmall ; becaufe fuch a little quantity of acid does not contain fire enough to volatilize the phlogifton : and hence heat is neceflary to affift the marine acid in dlffolving lead. When dephlogiftlcated, it afts more powerfully. It has been obferved, that copper and iron mutual- ly precipitate one another. If a piece of copper be S T R Y. Theory. put Into a faturated folution of iron frefK made, no Solution precipitation will enfue for 1 2 hours, or even longer, ^".^ Preci» if the liquor be kept clofe from the air ; but if the li- ^ quor be expofed to the open air, the addition of vo- ^ ^ latile alkah will fhow, in 24 hours, that fome of the whv cop- copper has been difTolved, or fooner, if heat be ap- per and i- phed, and a calx of iron Is precipitated. The reafon preci- of this will be underftood from the foUowinjr ftate oi^'^^^f '^^'^ rr • • another, tne aranities. Quiefcent. Vitriolic acid to calx of iron - - 270 Copper to its phlogi- fton - - 360 Divelleiit. Vitriolic acid to cop- per - - 260 Calx of iron to phlo- gifton - - 250 630 510 In this cafe no decompofttlon can take place, be- caufe the fum of the divellent affinities is lefs than that of the quiefcent ; but in the fecond, when much of the phlogifton of the iron has efcaped, the affinity of the calx of iron to the acid is greatly diminlfhed, at the fame time that the affinity of the calx to phlogi- fton is augmented. The ftate of the affinities may therefore be fuppofed as follows. Vitriolic acid to calx of iron - 240 Copper to its phlo- gifton - 360 Divellent, Vitriolic acid to cop- per - 260 Calx of iron to phlo- gifton - 370 600 630 The increafe of affinity of the calx of Iron to phlo- gifton is not a mere fuppofition ; for if w^e put lome frefh iron to a folution of the metal fo far dephlogiftl- cated as to refufe to cryftallize, fo much of the phlo- gifton will be regained that the impoverifhed folution will now yield cryftals. The reafon why the increafed quantity of phlogifton does not enable the acid to re- aft upon the metal is, becaufe it is neither fufficiently large, nor attracted with a fufficient degree of force, to which the accefs of air and heat employed contri- bute confiderably. The diminution of attraftion in calces of iron for acids is evident, not only from this but many other experiments ; and particularly from the neceffity of adding more acid to a turbid folution of iron in order to re-eftablifh its tranfparency. A dephlogiftlcated folution of iron is alfo precipita- ted by the calces of copper. The fame thing happens to a folution of Iron in nitrous acid ; only as the acid predominates greatly in this folution, fome of the cop- per is difTolved before any of the iron Is precipitated. Copper precipitates nothing from folution of iron in the marine acid, though expofed to the open air for 24 hours. Solution of copper in the vitriolic acid is inftantly precipitated by Iron ; the reafon of which is plain from the common table of affinities : and hence the foun- dation of the method of extrafting copper, by means of Iron, from fome mineral waters. The precipitated folution affords a vitriol of iron, but of a paler kind than that commonly met with, and lefs fit for dyeing, as being more dephlogiftlcated : the reafon of which is, that copper contains more phlogifton than iron : old iron is alfo ufed which has partly loft its phlo- gifton. 34* Increafe of the attrac- tio I of calx of iron 'o phlogi- ilon rle- monftra- ted. 343 Cake's of copper pie- :il itate de- phlogifti- cat( d folu- tions of i- ron. 344 Martial vl* triol jirocu- rcd by pre* ci.iitation of copper lefs fit for dyeing than the com- mon. Theory. CHEMISTRY. 415 Solution and l*reci- pitation. compoied by cait i- ron. Why turiiteil fi hition of {llv c.n fcarce be precipita- ted by i- ron. gifton. Hence tlie Iron is more dephlogiflicated by precipitating copper than by mere diflblution in the _ vitriolic acid ; and hence caft iron, according to the obfervations of Mr Schlutter, will fcarcely precipitate Solurion of a folution of copper ; becaufe it contains lefs phlo- coppei- gifton than bar-iron, as Mr Bergman has informed us. fcarcely de- ^/^^ Kirwan always found filver eafily precipitated by means of iron from its folution in nitrous acid ; though Bergman had obferved that a faturated folution of filver could not be thus precipitated without great difficulty, even though the folution v/ere diluted and an excefs of acid added to it. What precipitation 346 took place could only be accomplifhed by fome kinds 'y ^. of iron. The reafon of this Mr Kirwan fuppofes to be, that the folution, even after it is faturated, takes up fome of the filver in its metallic form ; which Mr Scheele has alfo obferved to take place in quickfilver. The lall portions of both thefe metals, when diiTolved in ftrong nitrous acid, afford no air, and confequently are not depWog'ftlcated. This compound of calx, therefore, and of filver in its metallic ftate, it may rea- fonably he fuppofed cannot be precipitated by iron, as the filver in itsmetaUIc form prevents the calx from coming into contaft with the iron, and extradling the - phlogifton from it ; and for the fame reafon iron has been obferved not to precipitate a folution of mercury 347 in the nitrous acid. Of the pre- ^inc cannot precipitate iron, as Mr Bergman has zh^rand""^^^^'"' ""^^^ folution of the latter lofes part of its iron by one phlogifton. Hence we may underftand why Newmann another. denied that iron can be precipitated by means of zinc. Mr Kirwan, however, has found, that zinc does not precipitate iron from the nitrous acid ; but on the contrary, that iron precipitates zinc. In a fhort time the acid redifTolves the zinc and lets fall the iron, owing to the calx of iron being too much dephlogifti- cated. Iron, however, will not precipitate zinc either from the vitriolic or marine acids. Moil of the me- tallic fubftances precipitated by iron from the nitrous ac'd are in fome meafure redlToIved fliortly after ; be- caufe the nitrous acid foon dephlogifticates the iron too much, then lets it fall, reafts on the other metals, and diffolves them. Dr Lewis obferves, that filver is fometimes not pre* cipitated by copper from the nitrous acid; which hap- pens either when the acid is fuperfaturated with filver by taking up fome in its metallic form, or when the filver is not much dephlogifticated. In this cafe, the remedy is to heat the folution and add a little more acid, which dephlogifticates it further ; but the nitrous acid always retains a little filver. It has commonly been related by chemical authors, "e'formed'^ ^^^^ blue vitriol will be formed by adding filings by boiling copper to a boiling folution of alum. Mr Kirwan, a folution however, has fhowed this to be an error : for after boiling a folution of alum for 20 hours with copper filings, not a particle of the metal was diflblved ; the liquor ftanding even the teft of the volatile alkah. The alum indeed was precipitated from the liquor, but ftill retained its faline form ; fo that the precipitation was occafioned only by the diflipation of the fuperflu- ous acid. No metal is capable of precipitating tin In its me- tallic form ; the reafon of which, according to Mr Kirwan,, is, becaufe the precipitation is not the effeA 348 Why cop- per feme • times can not preci- pitate fil- ver. 349 Blue vi' of alum "wi'h cop- per filings. 350 Why tin cannot he precipita- ted in ics n:eta!iic form. of a double affinity, but of the fingle greater affinity Solution, of its menftruum to eveiy other metallic earth. Me- ^"5' ^J'^^i- tals precipitated froni the nitrous acid by tin are af- P"^ ^*^"' . terwards rediffolved, becaufe the acid foon quits the ^51 tin by reafon of its becoming too much dephlogi- why me- fticated. \ _ _ f'^^'^^'a u" Lead precipitates metallic folutions in the vitriolic ^ • -ii nil r 1 r r\ • ^^'^ ^""e al- and marine acids but llowly, becaule the hrit portions fg^-^j^. j^ of lead taken up form falts very difficult of folution, rediffwlved, wliich cover its furface, and proteft it from the fur- 3J* ther aftion of the acid ; at the fame time it conta-ins^^^^^^'P"^* fo little phlogifton, that a great quantity of it muft be diffolved before it will difi'blve other metals. A folu- tion of lead very much faturated cannot be precipita- ted by iron but with difficulty, if at all. Mr Kirwan conjc£lures that this may arife from fome of the lead' alfo being taken up in its metallic form, as is the cafe with mercury and filver. Iron will not precipitate lead from marine acid ; for though a precipitate ap- pears., the acid is ftill adhering to tiie metal. On the contrary, iron is precipitated from its folution in this acid by lead, though very flowly. 353 Mercury is quickly precipitated from the vitriolic Precipita*' acid by copper, thouo-h the difference between the fum °^ , _ , ^ fV ^ •!• n re ■ • • -L ^ mercury by of the quiefcent and divellent affinities is but very ^.^pp^j./ fmall. The precipitation, however, takes place, be- caufe the calx of mercury has a ftrong attraftion for phlogifton ; and a very fmall portion of what is con- tained in copper is fufficient to revive it. ^54^ Silver, however, is not able to precipitate mercury It cannot be from the vitriolic acid, unlefs it contains copper ; in 1 recipita- whlch cafe a precipitation will enfue : but on diftilling ^"^^^^ from' filver and turpeth mineral, the mercury will pafs over vitriolic a- in its metallic form ; which fhows that the affinity of cid. the calx of mercury to phlogifton is increafed by heat, though the difi'erence betwixt the divellent and quief- cent powers is very fmall. 355' Mercury appeared to be precipitated by filver from Why nier'. the nitrous acid, though very flowly ; but when the^^"^y^^"'^ folution was made without heat, it was not at all pre- dpTtate'^one cipitated. On the other hand, mercury precipitates another filver from this acid, not by virtue of the fupeviority fiom the of the ufual divellent powers, but by reafon of the at-^V^'""* trafkion of mercury and filver for each other ; for they form partly an amalgam and partly a vegetation, fcarcely any thing of either remaining in the folu- ^ , . . r 1 r 1 CoiTofive Silver does not precipitate mercury from the lolu-fubiimate^ tion of corrofive fublimate ; but, on the contrary, cannot be mercury precipitates filver from the marine acid : and precipita- if a folution of luna cornea in volatile alkali be tritura-^^jj J'^but" ted with mercury, calomel will be formed ; yet on dl- i^na cornea ftiUing calomel and filver together, the mercury will may be de- pafs in its metallic form, and luna cornea will be form- j^o^po^^'l ed. The fame thing happens on diftilling filver and JJ^.^^^''^^^ corrofive fublimate, the affinity of calx of mercury to fublimate phlogifton increafing with heat. by filver, in Bifmuth precipitates nothing from vitriol of copperf'"^ dry in 16 hours ; nor does copper from vitriol of bifmuth. ^''^^'^^ The two metallic fubftances, however, alternately pre- Precirita- cipitate one another from the nitrous acid, which pro-tu^n- of bif- ceed from their difi"erent degrees of dephlogiftication. niuth. Nickel will fcarcely precipitate any metal except it be reduced to powder. A black powder is precipi-preopita- tated by means of zinc from the folution of nickel ted ly iier* Jiu fcTircely precipitare one ai:o- tlier. 360 Precipita- tion of cop per, lead, and bif- muth, by aickel. 361 Zinc can- rot preci- toitate co- balt. 36a 416, G H E M I Solution %i the vitriolic and nitrous acids, which has been ^pita'Io" ^o"*^'" by Bergman to confift of arfenic, nickel, and a little of the 7,1 nc itfelf. The latter, however, precipi- tates nickel from the marine acid. The folutions of iron and nickel in the vitriolic acid mutually a£l upon thefe metals ; but neither of them will precipitate the other in 24 hours, though on re- maining longer at reft iron feems to have the advan- tage. Iron, however, evidently precipitates nickel from the nitrous acid ; and though nickel feems to precipitate iron, yet this arifes only from the gradual dephlogiftication of the iron. Copper is precipitated in its metallic formi from the vitriohc, nitrous, and marine acids, by nickel. The vitriolic and nitrous folutions of lead feem to aft upon it Vvfitjiout any decompcfition, the calces uniting to each other. Lead feems for fome time to be atlcd upon in the fame manner by the vitriolic and nitrous folutions of nickel, bvit at lall nickel feems to have the advantage ; but a black precipitate appears whichever of them is put into the folution of the other. How- ever, nickel readily precipitates vitriolic and nitrous folutions of bifrauth ; but in the marine acid both thefe femimetals are foluble in the folutions of each other : yet nickel precipitates bifmuth very flowly, and only in part ; while bifmuth precipitates a red powder, fuppofed by Mr Kirwan to be ochre, from the folution of nickel. Cobalt is not precipitated by zinc either from the vitriolic or nitrous acids, though it feems to have fome effefl upon it when difTolved in that of fea-falt. Iron precipitates cobalt from all the three acids, • •1^.'^ j^'^" vet much of the femimetal is retained in the vitriolic cipitated by , . r i • r • • 1 t i i iron. '^"d nitrous iolutions or it, particularly the latter ; 363 which, after letting fall the cobalt, takes it up again, Nickel pre- g^jj i^tg fall a depklogifticated calx of iron. Nickel fonitTl^te- though it does not precipitate cobalt itfelf, as rogeneous appears by the remaining rednefs of the folution, yet niatterfroni conftantly precipitates fome heterogeneous matter from it. Solution of cobalt in the marine acid becomes co- ^ ^ lourlefs by the addition of nickel. Bifmuth is foluble fcolutions . • • T 1 • CI- r 1 1 1 of fobah in the vitriolic and nitrous lolutions 01 cobalt, and let fall a throws down a fmail white precipitate, but does not white pow- jiffeft the metallic part. Nor can we attribute thefe der on the f^Qjy^jQjjg Ju vitriolic acid to any excefs in that acid, as addition ot , ... , 1 • i 1 ^r bifmuth cr they are dilute and made without neat. Copper alio precipitates from the folution of cobalt a white powder fuppofed to be arfenic. Precipita- The regulus of antim.ony has no effcifl on folution tions of and of copper in vitriolic acid, nor is precipitated by it of a?^"!"^ from the fame acid ; but it dilfolves flowly in vitriol of antimony. With folution of vitriol of lead it becomes red in 16 hours, but is fcarcely precipitated by lead from the vitriolic acid. Powdered regulus alfo preci- pitates vitriol of mercury very flightly. Bifmuth nei- ther precipitates nor is precipitated by the regulus in 24 hours from the vitriolic acid. Tin precipitates the regulus from the nitrous acid ; but if regulus be put into a folution of tin in the fame acid, neither of the A t'^'^ le r^ctals will be found in the liquid in 16 hours, either fait foimcd by reafon of the dephlogiftication or of the union of the by iron, re- calces to each other. gulusof an Iron dees not precipitate regulus of antimony en- *^'"^'."yi'^"" tirely from the marine acid; but feems to form a marine a- ^^.-^^^p fait, confifting of the acid and both calces. copper, 365 S T R Y. Theory. The regulus may alfo be diflblvcd by marine fait of Solution iron. ^'^'^ Preci- Copper does not precipitate regulufj of antimony 1 't^^ion. ^ from marine acid in 16 hours; and if the regulus be put into marine fait of copper, it will be dilfolved, Another and volatile alkalies will not give a blue, but a yellowilh formed by white precipitate ; fo that here alfo a triple fait is ^ej^ulus of fo,^^^^ ■ mar'nea-' Solution of arfenic in vitriolic acid a£l:s upon iron, p,,^ lead, copper, nickel, and zinc ; but fcarce give any copper, precipitate : neitlier is arfenic precipitated by iron 3^^ from the nitrous acid, thoujxh it is by conoer, and ^"^"^'P'/^" , even filver gives a flight white precipitate. Regulus i^y aif.nic. of arfenic, however, precipitates lilver completely in 1 6 hours : whence the former precipitate feems to be a triple fait. Mercury alfo fl.ightly precipitates arfenic from the nitrous acid, and feems to unite v/ith it, though it is itfelf precipitated by regulus of arfenic in . . . . . . 369 Bifmuth flightly precipitates arfenic from fpirit of Re^julus of nitre, but regulus of arfenic forms a copious precipi- aifcnx pifs- tate in the nitrous folution of bifmuth ; fo that Mr ^^■^^'^^^'^^^j^' '^^ Kirwan is of opinion that the calces unite. It is not i^on^ ^hc precipitated from this acid by nickel, but the calces n'trous a- unite. Though regulus of arfenic produces a copious cid; precipitate in the folution of nickel in nitrous acid, yet the liquor remains green ; fo that the nickel is certainly not precipitated. The white precipitate in this cafe feems to be arfenic flightly dephlogiilicated. Regu- lus of arfenic alfo produces a white precipitate in the nitrous folution of cobalt, but the liquor ftill continues red. .370 Regulus of arfenic is precipitated from the marine And by acid by copper; but the precipitate does not ftrike blue colour with volatile alkali, becaufe the metal „ unites with the arfenic. The arfenic 13 alio precipi- cid. tated by iron. Tin is foluble in marine folution of ar- fenic, but Mr Kirwan could not obfcrve any precipi- tation ; nor does regulus of arfenic precipitate tin. Neither bifmuth nor regulus of arfenic precipitate each other from marine acid in 16 hours. Regulus of an- timony is alfo afted upon by the marine folution of ar- fenic, though it caufes no precipitate, nor does the regulus of arfenic precipitate it. ^2. Of the ^mHU'ies of Ac'ul, Allioli, iffc. contahied in different Salts, ivith the Sfecific Gravity of the In- gredients. It is a problem by which the attention of the beft modern chemifts has been engaged, to determine the quantity of acid exifting in a dry Itate in the various compound falts, refulting from the union of acid with alkaline, earthy, and metallic fubftances. In this way Mr Kirwan has greatly excelled all others, and deter- mined the matter with an accuracy and precifion alto- gether unlooked for. His decifions are founded on the following principles. 1 . That the fpecific gravity of bodies is their weight 37' divided by an equal-bulk of rain or diftilled water; the ^^^"j^f latter being the itandard with which every other body bodies^ how is compared. found. 2. That if bodies fpecifically heavier than water be weighed in air and in water, they lofe in water part of the weight which they were found to have in air ; and Theory. C H E M Contents, and that the weight fo loft is juft the fame as that of Saks'^ ^" equal bulk of water ; and confequently, tliat their . fpecilic gravity is equal to their weight in air, or ab- folute weight divided by their lofs of weight in water. 3. That if a folid, fpecifically heavier than a liquid, be weighed firll in air and then in that liquid, the weight it lofes is equal to the -weight of an equal vo- lunie of that liquid ; and confequently, if fuch folid be v^^eighed fini in air, then in water, and afterwards in any other liquid, the fpecific gravity will be as the weight loft in it by fuch folid, divided by the lofs of weight of the fame foHd in water. This method of finding the fpecific gravity of liquids, our author found more exaft than that by the aerometer, or the compa- rifons of the weights of equal meafures of fuch liquids and water, both of which are fubje£l to feveral inaccu- I S t ft Y. 4*7 racies. ,•»/■» To find 'he 4. That where the fpecific gravity of bodies is al- weighr of ^gady known, we may find the weight of an equal ^"l^'^of ^-a. hidk of water ; it being as the quotient of their abfo- tcr where lute weight divided by their fpecific gravities : and this the fpecific he calls their lofs of weight in water, fnowif Thus where the fpecific gravity and abfolute weight of the Ingredients of any compound are known, the fpecific gravity of fuch compound may eafily be calcu- lated ; as it ought to be intermediate betwixt that of ^ the lighter and that of the heavier, according to their Mathema- feveral proportions : and this Mr Kirvvan calls the ma- ticalfpeci- thematical fpecific' gravity. But in faft the fpecific fic gravify gravity of compounds, found by aftual experiment, explained, f^j^^^^ agrees with that found by calculation ; but is often greater, without any diminution of the lighter Increafed ingredient. Tliis increafe of denfity, then, Mr Kirwan denfity of fuppofes to arife from a clofer union of the component mixtures parts to each other than either had feparatelv with its accounted ^ • . . j ..1 • ^. . £jjj_ own mtegrant parts ; and this more mtimate union miift, he thinks, proceed from the attradlion of thefe parts to each other : for which reafon he fuppofed, that this attrailion might be ettlmated by the increafe of denfity or fpecific gravity, and was proportionabk to it ; but foon found that he was miltaken in this 375 r : Weights of With regard to the abfolute weights of feveral forts diifcreiJt of air, our author adheres to the computations of Mr kindsof air. j?Qji{-ana^ at whofe experiments he was prefent ; the thermometer being at 55°, and the barometer at 294- inchcs, or nearly fo. Thefe weights were as follow : vCubic inch .of icommon air, - 0.385 'fixed air, - o-570 ;inanne acid air, 0.654 nitrous air, - 0.399 vitriolic acid air, 0.778 alkaline air, - 0.2 inflvimmable air, 0.03 *MefVio i of Mr Kirwan begins his inveftigatlons with the marine fin lino- the acId ; endeavouring firft to find the exaft quantity of quantity <^f rinvt acid it contains at any given fpecific jjravitv, and otitaii.edin^"^" oy means of it determining the weight of acid lpi.it of contained in all other acids. For if a given quantity .fait. of pure fixed alkali were faturated, firlt by a certain quantity of fpirit of fait, and then by determined quantities of tlie other acids, he concluded, that each of thefe quantities of acid liquor mull contain the fame quantity of acid ; and this being known, the remaiji- VoL.,IV.PartIL point. der, being the aqueous, part, muft alfo be known. Consents, This coiielufion, however, refted entirely on the fup- '^^'^ pofition that the fame -quantity of all the acids was^^^"' requifite for the faturation of a, given quantity of fixed * alkali ; for if fuch given quantity of fixed alkali mi!>'ht be faturated by a fmaller quantity of one acid than of another, the conclufion fell to the ground. The weight of the neutral falts produced might indeed de- termine this point in fome mcafure ; but ftill a fource of inaccuracy remained ; to obviate which he' ufed the following expedient, i. He fuppofed the quantities' of nitrous and vitriolic acids necelfary to faturate a given quantity of fixed alkali exadly the fame as that of marine acid, whofe quantity he bad determined ; -and to prove the truth of tliis fuppofitiou, he obferved the fpecific gravity of the fpirit of nitre and oil of vi- triol he employed, and in which he fuppofed, from the trial with alkahes, a certain proportion of acid and water. He then added to thefe more acid and water, and calculated what the fpecific gravity ftiould be on the above fupnofition ; and finding the refult agreeable with the fuppofition, he cancluded the latter to be exaft. The following experiments were made on the marine acid. Two bottles were fdled nearly to the top with di- Method of Itilled water, of which they contained in all 1399.9 finding the grains, and fucceffively introduced into two cyHnders filled with marine air ; and the procefs was renewed, "."^ff 9"^' until the water had imbibed, in 18 days, about 794"^ cubic inches of the marine air. The thermometer did not rife all this time above 55°; nor fink, unlefs perhaps at night, above 50° ; the barometer flanding between 29 and 30 inches. This dilute fpirit of fait then \veighed 1920 grains; that is, 520.1 more than before; the weight of the quantity of marine air abforbed. The fpecific gravity of the liquor was found to hz 1.225. Its lofs of weight in water (that is, the weight of an equal bulk of water) lliould then be 1567.346 nearly ; but it contained only, as we have feen, I399'.9 grains of water: fubtraftlng this therefore from 1567.346, the remainder (that is, 167.446^ muff be the lofs of 520.1 grains of marine ac?d ; and confe- quently the fpecific gravity of the pure marine acid, m fuch a condenfed ftate as when it is united to water, muft beT-fi-^jfj., or 3.100. Still, however, it might be fufpeded, that the den- fity of this fpirit did not entirely proceed from the mere denfity of the marine acid, but in part alfo from the attraftion of this acid to water ; and though the length of time requifite to make the water imbibe this quantity of marine acid air, naturally led to the fiippo- iition that the attraftion was not very confiderable, yet the following experiment was more fatisfaaory. He expofed 1440 grains of this fpirit of fait to marine acid air for five days, tlie thermometer being at 50°, or be- low ; and then found that it weighed 1562 grains, and confequently had imbibed 122 grains more. Its fpeci- fic gravity was then 1.253, ^vl"ch was precifdy what It fiiould have been by calculation. Being now fatiafied that the proportion of acid in^ ^'5 x fpirit of fait was difeovered, our author determined to^^ptjfn' hnd it m other acids alfo. For this purpofe he took of pure air ' iho grains of very ftrong oil of tartar per Mquium, and ^" found that it was faturated by 180 grains of fpirit of fait, whofe fpecific gravity was 1.225; and by ,3 ^ -calculafion 4i8 CHEMISTRY. Theory. 379. CJuantiries Contents, calculation it appeared, that i8o grains of this fpirit &r. ofthe contained 48.7 grains of acid, and 131. 3 of water. ^ . Hence he drew up a table of the fpecific gravities of acid liquors containing 48.7 grains of pure acid, with different proportions of water, from 50 to 410 parts ; the hquor with the firft proportion having a fpecific gravity of i.497> and the latter weighing only 1.074. Mr Baume had deternained the fpecific gravity of the ftrongeil fpirit of fait made in the common manner to be 1. 187, and Bergman 1.190; but we are told in the Paris Memoirs for 1700, that Mr Romberg had pro- duced a fpiilt whofe fpecific gravity was 1.300 ; and that made by Dr Prieilley, by faturating water with marine acid air, muft have been about 1.500. The fpirit of fait, therefore, whofe fpecific gravity is 1.261, has but little attraction for water, and therefore at- trafts none from the air ; for which leafon alfo it does not heat the ball of a thermometer, as the vitriolic and nitrous acids do ; though Mr Cavallo found that ■ this alfo had fome effect upon the thermometer. Com- mon fpirit of fait, Mr Kirwan informs us, is always adulterated with vitriohc acid, and therefore unfit for thefe trials. _ Mr Kirwan now fet about inveftigating the quanti- of acid, wa- ^^id, water, and fixed alkaU, in digeftive fait, or kaVi I'n ^ combination of the marine acid with vegetable al- geftive fah. kali. For this purpofe he to,ok 100 grains of a folu- tion of tolerably pure vegetable alkali, that had been three times calcined to whitenefs, the fpecific gravity of which was 1-097 ; diluting alfo the fpirit of fait . with different portions of water ; the fpecific gravity of one fort being 1. 01 5, and of another 1.098. He then found that the above quantity of folution of the vegetable alkali required for its faturation 27 grains of 'that fpirit of fait whofe fpecific gravity was 1.098, and 23.35 grains of that whofe fpecific gravity was 1.115. Now, 27 grains of fpirit of fait, whofe fpe- cific gravity is 1.098, contain 3.55 grains of marine acid, as appears by calculation. The principles on which calculations of this kind are founded, our author gives in the words of Mr Cotes. ,T J " The da^ requifite are the fpecific gravities of the the fpecific mixture and of the two ingredients. Ihen, as the gravities of difference of the fpecific gravities of the mixture and thedifFerent lighter ingredient is to the difference of the fpe- cific gravities of the mixture and the heavier ingredi- ent ; fo is the magnitude of the heavier to the magni- tude of the lighter ingredient. Then, as the magni- tude of the heavier, multiplied into its fpecific gravity, is to the magnitude of the hghter multiplied into its fpecific gravity ; fo is tlie weight of the heavier to the weight of the lighter. Then, as the fum of thefe weights is to the weight of either ingredient ; fo is the weight given to the weight of the ingredient fought." Thus, in the -prefent cafe, 1.098 — i.ooo=.098 is the magnitude of the heavier ingredient, viz. the marine acid, and .098X3.100 = 0.3038 the weight of the ma- rine acid; and on the otherhand,3.ioo — 1.098=12.002, the magnitude of the water; and 2.002X1.000=2.002 its weight ; the fum of thefe weights is 2.3058 : then if 2.3058 parts of fpirit of fait contain 0.3038 parts acid, 27 grains of this fpirit of fait will contain 3.55 acid. In the fame manner it will be found, that 23.35 grains of fpirit of fait, whofe fpecific gravity is J.I 15, contains 3.55 grains acid. Ojir ^Hthor defcrlbes very particularly his method of 6 making the faturation of the alkali with the acid ; Conten.ts, which, as it is always difficult to hit with precifion, we g^jj^^^* Ihall here tranfcribe. " It was performed by putting ."^ ^ the glafs cylinder which contained the alkaline folu- tion on the fcale of a very fenfible balance, and at theMrku-- fame time weighing the acid liquor in another pair ofwan' , me- fcales; when the lofs of weight indicated the efcape [J^l-atinlfhe nearly equal quantities of fixed air contained in the ^^.j^ ^^'^ folution. Then the acid was gradually added by dip- kali wit!i ping a glafs rod in it, to the top of which a fmall drop accuracy, of acid adhered. With this the folution was ftirred, and veiy fmall drops taken up and laid upon bits of paper fl.ained blue with radifh juice. As foon as the paper was in the leaft reddened, the operation was completed ; fo that there was always a very fmall ex- cefs of acid, for which half a grain was conflantly al- lowed ; but no allowance was made for the fixed air, which always remains in the folution. But as on this account only a fmall quantity of the alkaline folution was ufed, this proportion of fixed air mull have been inconfiderable. If an ounce of the folution had been employed, this inappretiable portion of fixed air would be fufficient to caufe a fenfible error; for the quantity of fixed air loft by the difference betwixt the weight added to the 100 grains and the adlual weight of the compound was judged of ; and when this difference amounted to 2.2 grains, the whole of the fixed air was judged to be expelled : and it was found to be fo ; as 100 grains of the alkaline folution, being evaporated to drynefs, in the heat of 300°, left a refiduum which amounted to lo^^ grains, which contained 2.2 grains of fixed air." ^ The refult of this experiment was, that 8.3 grains Q^i^'^fj^y of pure vegetable alkah, freed from fixed air and water, mild and or 10.5 of mild fixed alkah, were faturated by 3.55 cauftic grains of pure marine acid ; and confequently the re- fulting neutral fait fliould, if it contained no water, ^ weigh 11.85 grains: but the falts refulting from this ^iveii union (the folution being evaporated to perfedl dry- weight of nefs in a heat of 160 degrees, kept up for four hours) '^^^j'"* weighed at a medium 12.66 grains. Of this 11.85 grains were acid and alkali ; therefore the remainder, Wz. 0.81 grains, were water. An hundi'cd grains of perfedlly dry digcitive fait contain 28 grains acid, 6.55 of water, and 65.4 of fixed alkali. In his experiments on the nitrous acid, Mr Kirwan made ufe only of the dephlogifticated kind, which ap- pears pure and colourlefs as water. (fays he) cannot be made to exift in the form of air, as^^-jj^ when Dr Prieftley has (hown ; for when it is deprived of pui e, cau- water and phlogifton, and furnifhed with a due pro- " 't be portion of elementary fire, it ceafes to have the pro- ^^^^^j'^^^ perties of an acid, and becomes dephlogifticated air. ^g^j^j f^^^^ Its proportion therefore could not be determined in fpirit of nitre as the marine acid had been in fpirit of fait in the laft experiment." — To determine the mat- ter, the following experiments were made. ^g^ 1. To 1963.25 grains of dephlogifticated fpirit ofHow to de- nitre, whofe fpecific gravity was 1.419, he gradually t^ra^ne added 179.5 grains of diftilled water; and when it^ ^J"^"^*^' cooled, the fpecific gravity of the mixture was found ^^id con-^ to be 1.389. tamed in 2. To 1984.5 of this 178.75 grains of water were^iiitaf then added, and the fpecific gravity of the mixture""'^* found to be 1.362. 3. An hundred grains of a folution of fixed vege- table This pure acid ... ^ - Nitrous Theory. C H E M table alkali, wliofe fpecific gravity was 1.097, tlie fame that had been formerly ufed in the experiments with fpirit of fait, was found to be faturated by 1 1 grains cf the fpirit of nitre, whofe fpecific gravity was 1.4 19, by 1 2 of that whofe fpecific gravity was 1.389, and by I ^.08 of that whofe fpecific gravity was 1.362. Thefe quantities were the medium of five experiments ; and it was found neceffary to dilute the acid with a fmall quantity of water. When this was neglefted, part of the acid was phlogifticated, and flew off with the fixed air. Ten minutes were alfo allowed after each affu- fion foi the matters to unite ; a precaution which was likewife found to be abfolutely neceffary. Upon the fuppofition, therefore, that a given quan- tity of vegetable fixed alkali is faturated by the fame weight of both acids, we fee that 1 1 grains of fpirit of nitre, whofe fpecific gravity is 1. 41 9, contain the fame quantity of acid with 27 grains of fpirit of fait, whofe fpecific gravity is 1.098, or 3.55 grains. The remainder of 1 1 grains, or 7.45 grains, is therefore mere water ; and of confcquence, if the denfity of the acid and water had not been increafed by their union, the fpecific gravity of the pure nitrous acid fliould be To find the 1 1-8729. But the fpecific gravity of the nitrous, as fpecific gra- well as of the vitriolic acid, is augmented by its union vity of the ^.j^h vv^ater ; and therefore the lofs of its weight in P^r^"'""""* water is not exaAly, as it would appear by calculation '387 from the above premifes, according to the rules al- How to de- ready laid down. To determine therefore the real termine the {pacific gravity of the acid in its natwal ftate, the acciucd quantity of accrued denfity mull be found, and fub- mixing' fpi- trafted from the fpecific gravity of the Ipirit ot nitre. Tit of nin e whofe true mathematical fpecific gravity will then with wa- ter. I S T R Y. 419 lofs of the 3.5-5 grains acid ; and confequently th* true Con' cnts, fpecific gravity of the pure and mere nitrous acid is ^^^^^ ^ ° 385. Proportion of acid in fpirit of ni- tre ro that in fpirit of fait. 386 effed appear. This our author endeavoured to by mixing different portions of fpirit of nitre and water, remarking the degree of diminution they fuf- tained by fuch union ; but was never able to attain a fufficient degree of exaftnefs in the experiment. He had recourfe therefore to the following method, as af- fording tnore fatisfaftion, though not altogether accu- rate. Twelve grains of the fpirit of nitre, whofe fpe- cific gravity by obfervation was 1. 389, contained, as our author fuppofed from the former experiment, 3.55 grains of real acid, and 8.45 of water : then if the fpecific gravity of the pure nitrous acid were i i.872,th^t of this compound acid and water fhould be 1.37 1 ; for the lofs of 3-55 fhould be 0.299, and thelofs of thewater 12 8.45, the fum of the loffes 8.749. Now, g-^^m.371: but the fpecific gravity, as already mentioned, was 1.389 ; therefore the accrued denfity was at leaft o.i 8. the difference betwixt i.389 and 1.37 1. This calcu- lation indeed is not altogether exaft ; but our author concludes, that 0.18 is certainly a near approximation to the degree of denfity that accrues to 3.55 grains of acid by their union to 7.45 grains of water : there- fore, fubtraAing this from 1.419, we have nearly the mathematical fp-cific gravity of that proportion of acid and water, namely, 1.401. Again, fince 1 1 grains of this fpirit of nitre contain 3-55 g™ns acid, and 7.45 of water, its lofs of weight fliould be — — — =:7.8ecificgra- fpecific gravities, continuing his mixtures till the '"^"^^I^Qf'^ thematlcal fpecific gravities found by obfervation nearly coincided with thofe made by calculation. luconllruc- this table the fpirit of nitre was mixed with water in ted. various proportions, but after a different manner from that obferved with the fpirit of fait. Nine grains of the fpirit containing 3.55 grains of pure acid were mixed with 5.45 of water ; the accrued denfity of the mixture was found to be nothing, the mathematical fpecific gravity 1-537, and the fpecific gravity by ob- fervation was found the fame. When 10 grains of fpirit were mixed with 6.45 of water, the accrued den- fity was 0.009, the raaihematical fpecific gravity 1.458, and the fpecific gravity by obfervation 1.467. In this manner he proceeded until 38 90 grains of water were mixed with 42. 4 j of fpirit. In tliis cafe the accrued denfity was found to be 0.002, the mathe- matical fpecific gravity 1.080, and the fpecific gravity by obfervation 1.082. The intermediate fpecific gravities, in a table of this kind, may be found by taking an arithmetical mean be- ^ t vvixt the fpecific gravities, by obiervation, betwixt which the defired fpecific gravity lies, and noting how much it exceeds or falls (hort of fuch arithmetical mean ; and then taking alfo an arithmetical mean betwixt the ma- thematical fpecific gravities betwij^t which that fought for muft lie, and a proportionate ^txcefs or defeft. The fpecific gravity of the ftrongeft fpirit of nitre yet made, is, according to Mr Baurae, 1-500, and ac- cording to Mr Bergman 1.586. Our author next proceeded to examine the propor- 3 G a tion 420 G H E MI Mr Kir €?ontcnt«, tJon of aci^, water, and fixed alkali in nitre, in a man- Salts*'^ ner fimilar to what he had already done with digeflive «_ . fait ; and found that lOO grains of perfedlly dry nitre contained 28.48 grains of acid, 5.2 of water, and 66.32 family • f of fixed alkali. acid, water, Some experiments of the fame kind had been made ^nitre de ^■^ refults of which our author com- termiifed.' P^^^^ ^i^'^ thofe, of his own. The fpecific gravity of 39a the fpirit of nitre which M. Homberg made ufe of Homberg's was 1.349; and of this, he fays, one ounce two txpen- drachms and 36 grains, or 621 troy grains, are requi- ^^°j^^*red to faturate one French ounce (472.5 troy) of dry thofe of fait of tartar. According to Mr Kirwan's computa- tion, however, 613 grains are fufiicient ; for the fpeci- fic gravity lies between the fpecific gravities by obfer- vation 1.362 and 1.337, and is nearly an arithmeti- cal' mean between them. The correfponding mathe- matical fpecific gravity lies between the quantities marked in Mr Kirwan's table 1.3 15 and J. 286, being nearly 1.300. Now the proportion of acid and water in this is 2.629 of acid and 7-465 of water ; for 8.765 — 1.300=7.465 of water, and 8.765X.3oo=2.62Q of acid; and the fum of both is 10.044. Now, fince 10.5 grains of mild vegetable alkali require 3.53 grains of acid for their faturation, 472.5 will require 159-7; therefore if 10.044 grains of nitre contain 2.629 grains acid, the quantity of this fpirit of nitre requi- iite to give 159.7 will be 613.2 nearly, and thus the difference with M. Homberg is only about eight grains. M. Homberg fays he found his fait, when evapo- rated to drynefs, to weigh 1 86 grains more than be- fore ; but by Mr Kirwan'? experiment, it ihould weigh but 92.8 grains more than at firfi; ; the caufe of which difference will be mentioned in treating of vi- accounted triolated tartar, as it cannot be entirely attributed to the difference of evaporation. He alfo alferts, that one ounce (472.5 Troy grains) of this fpirit of nitre contains 141 grains of Troy of real acid. According to Mr Kirwan's computation, however, it contains only 123.08 grains of real acid. But this difference evidently proceeds from his neglecEl- ing the quantity of water that certainly enters into the compofition of nitre ; for he proceeds on this ana- logy, 621 : 186.6 :: 472.5 : 141. Our author obferves, that the proportion of fixed alkali afligned by him to nitre is fully confirmed by an perimeiits experiment of Mr Fontana's Infertedln Rozier's Jour- eonfiraied 1 77 8. He decompofed two ounces of nitre by 393 t)lfferent refuhs ©f Homberg snd Kir- wan's ex- i a difference of no confequence in the prefent cafe, and which might arife from the immerfion of the cold glafs-ball filled with mercury in the liquor. In the next cafe the differ- ence is dill lefs, amounting only to -s-pVoo* With another, and fomewhat ftronger fpirit of nitre, the fpecific gravities were as follow : Des^rees Specific (if hfat. gravity. 34 1.4750 49 *-46s3 150 1.3792 Here alfo the expanfions were nearly proportional tc the degrees of heat ; for 116^ of heat, the difference between 34 and 130, produce an expanfion of 0.0958 ; and 15° of heat, the difference between 34 and 49, produce an expanfion of 0.C097 ; and by calculation 0 0123: which laft differs from the truth only by From this experiment we fee, that the ftronger the strong fpj- fpirit of nitre is, the more it is expanded by the fame rit of nitre degree of heat ; for if the fpirit of nitre of the laft ex- "^"''f f^" • ^ 1 J • ^1 r • • paiided by penment were expanded in the fame proportion as in ^^^^ ^^^^^ the former, its dilatation, by 116 degrees of heat, ^eak, and ftiould be 0.0679; whereas it was found to be 0.0958. why. As the dilatation of the fpirit of nitre is far great- er than that of water by the fame degree of heat, and as it confifts only of acid and water; it clearly follows, that its iuperior dilatability muft be owing to the acid part : and hence the more acid that is contained in any quantity of fpiiit of nitre, the greater is its dilata- bility.' We might therefore fuppofe, that the dilata- tion of nitre was intermediate betwixt the quantity of water it contains and that of the acid. But there exifts another power alfo which prevents this fimple re- fult, vix. the attraftion of the acid and water to each other, which makes them occupy lefs fpace than the fum of their joint volumes; and by this coiidenfation our author explains his phrafe of accrued denfitv. Taking Exadl quan»- tlus mto the account, we may conuder the dilatation j^^j^jj^j o£ the fpirit of nitre as equal to thofe of the quan • fpirit of titles of water and acid it contains, minu& the con- nitre, denfatlon they acquire from their mutual attraction; and this rule holds as to all other Heterogeneous com- pounds. 4j6^ To find the quantities of acid and water in fpirit of '-'^ nitre, whofe fpecific gravity was found in degrees temperature different from thofe for which the table.^vjj(_^. c^,^, was conftrufted, viz. 54°, 55°, or 56° of Fahrenheit, camcu m the fureft method is to find how much that fpirit of'i"^"<'i nitre is expanded or contlenfed by a greater or leffer de- gree of bent;, and then, by the rule of proportion, find what its denfity would be at 55°. But if this cannot be done, we {haU approach pretty near the trut,h, if we allow -rh^^ every 1 5° degrees of heat above or below 55° of Fahrenheit, when the fpecific gravity is between 1.400 and 1.500. and -t^tj when the fpe- cific gravity is between 1.400 and 1.500. — The di- latations of oil and fpirit of vitriol were found to be ex- ceedingly irregular, probably by reafon of a white foreign matter, which is more or lefs fufpended or dif^^ folved in it, according to its greater or lefier dilution 5,. 424 Contents, &c. of the Salts. 447 Dilatation of fpli it of fait by va- rious de- greesof heat. and this matter our author did not feparate, as he in- tended to try the acid in the Hate in which it is com- monly ufed. In general he found that 15° of heat caufed a difference of above t^sit in 'ts fpecific gravity, when it exceeds 1.800, and of tttoo when its fpecific gravity ia between 1.400 and 1.300 — The dilatations of fpirit of fait are very nearly proportional to the degrees of heat, as appears by the following table. cDegrees Specific i of Heat. G avity. 33 i.igi6 54 1. 1 860 66 1.1820 128 I 1631 Hence -rtfso niould be added or fubtrafted for every 21° above or below 55*^, in order to reduce it to 55', the degree for which itsproportion of acid and water was calculated. The dilatability of this acid is much greater than that of water, and even than that of the nitrous 418 acid of the fame denfity. f Qiiantiry of Qur author next proceeds to cotifider the quantity of t kci u^M) P"""^ acids taken up at the point of faturation by the vark)'u'iiib-^^''^°"^ fubftances they unite with. — He begins with the glances. mineral alkali. Having rendered a quantityof this cau- 4^9 flic in the ufual manner, and evaporating one ounce Mineral al- cauflic folution to perfect drynefs, he found it prepared contain 20.25 grains of folid matter. He was af- for thefe fured, that the watery part alone exhaled during eva- cxperi- poration, as the quantity of fixed air contained in it ajents. y^j-y fnialj, and to diflipate this a much greater heat would have been requifite than that which he ufed. This dry alkali was diiTolved in twice its weight of water; and faturating it with dilute vitriolic acid, he found it to contain 2.25 grains of fixed air,; that be- ing the weight which the faturatcd folution wanted of being equal to the joint weights of water, alkali, and fpirit of vitriol employed. ■Quantityof The quantity of mere vitriolic acid neccffary to fa- vitriolic titrate 100 grains of pufe mineral alkali was found to acid necef- be 60 or 61 grains; the faturated folution thus form- turatc"it*" heing evaporated to perfeft drynefs weighed 36.5 grains; but of this weight only .28.38 were alkali and acid; .the remainder, that is, 8.12 grains, there- fore, were water. sHence 100 grains of Glauber's Ouantit ' of P^'"^^'^^y "t"'^<^> contained 29.12 of mere vitriolic ingredient^s acid, 48,6 of mere alkah, and 22.28 of water. But in Glau- Glauber's fait cryftallized contains a much larger pro- ber's fait, portion of water ; for 100 grains of thefe cryftals heat- .ed red hot loft 55 grains of their weight; and this lofs Mr .Kirwan fuppofes to arife merely from the evapo- ration of the watery part, and the remaining 45 con- tained alkali, v/ater, and acid, in the fame propor- tion as the 100 grains of Glauber's fait perfeftly dried above mentioned. Then thefe 45 contained 13.19 grains of vitriolic acid, 21.87 of fixed alkali, and 9.94 of water : confequently 100 grains of cryllallized Glau- ber's fait contain 13.19 vitriohc acid, 21.87 of al- kali, and 64.94 of v/ater. O 1 ^I'^'t of faturating the mineral alkali with dephlogifti- nuneralal- cated nitrous acid, it was found that ico grains of the kali taken alkali took up 57 of the pure acid in the experiment up by de- moft depended upon ; though in fome others this P^]"^.'^'*^^* quantity varied by a few grains : lie concludes, there- ted mtrcus i / , . r II 1- . 1 L .1 • -J acid • fore, that the quantity of alkah taken up by this acid nearly tlic fame as that taken up by the vitric- CHEMISTRY. Theory, lie. Suppofing this quantity to be 57 grains, then 100 Contents, grains of cubic nitre, perfectly dry, contain 30 of acid, of the 52.18 of alkah, and 17.82 of water: but cubic nitre ^ cryftaUized contains fomething more water ; for ico * grains of thefe cryflals lofe about four by gentle dry- ing ; therefore 100 grains of the cryftallized fait con- tain 28.8 of acid, 50 09 of alkali, and 21. ti of wa- ter. An hundred grains of mineral alkali require from gy j^^g^j^^ 63 to 66 or 67 grains of pure marine acid to faturate acid, it ; but Mr Kirwan fuppofes that one reafon of this vatiety is, that it is exceeding hard to hit the true point of faturation. Allowing 66 grains to be the quantity required, then 100 grains .of perfeftly dry common fait contain nearly 35 grains of real acid, 53 of alkah, and 13 of water; bat loo grains of the cryftallized fait lofe five by evaporation.: fo that 1 00 grains of thefe cryflals contain 33.3 of acid, 5.0 of al- kali, and 16.7 of water. The proportion of fixed air, alkali, and water, was Propo^jon thus invefligated,: 200 grains of thefe cryttals were of tixed air, difTolved in ,240 of water ; the folution was faturated ^"^^''j and by fuch a quantity of fpiiit of nitre as contained 4° ^^f^ated of pure nitrous acid ; whence it was inferred that i^y this fatU" thefe 200 grains of fait of foda contained 70 of pure latiou. alkahne fait. The faturated folution weighed 40 grains lefs than the fum of its original weight, and that of the fpirit of nitre added to it ; confequently it h)ft 40 grains of fixed air. The remainder of the ori- ginal weight of the cryftals therefore mull have been water, w'z. 90 grains. Conleqiiently 100 grains of thefe cryftals contained 35 of alkali, 20 of fixed air, and 45 of water. This proportion differs confiderably- 43S from that affigned by Mr Bergman and Lavoifier, which ^!|^^''^""' our author imputts to their having made ufe of foda Bertrtran recently cryftallized ; but Mr Kirwan's had been made and Lavoi- for fome months, and probably loll much water and ^i'^'^'^- fixed air by evaporation, which altered theptoportion of ^"^"'^'^ ^"^^^ the whole. According to the calculations of Bergman and Lavoifier, 100 grains of this alkali take up 80 of fixed air. The fpecific gravity of the cryiiallized mineral alkali, weighed in ether, was found to be 1-42 . ... 436 The proportion of the different ingredients in vo- Propor- latile alkalies can only be had from the experiments tion^ of in- lately made by Dr Prieftley concerning alkahne air. gradients He informs us, that i ro «f a meafure of this, and one ^"j^^^ii'^g'^*^ meafure of fixed air, faturate one another. Then, fup- pofing the meafure to contain 100 cubic inches, 185 cubic inches of alkaline air take up 100 of fixed air } but 1 85 cubic inches of alkaline air weigh at a medium 42.55 grains, and 100 cubic inches of fixed air weigh 57 grains ; therefore 100 grains of pure volatile alkali, free from water, take up 134 of fix- ed air. On expelling its aerial acid from a quantity of this volatile alkali in a concrete ftate, and formed by fub- limation, he found, that 53 grains of it were fixed air: according to the preceding calculation, ico giains of it fiiould contain 39.47 of real aJkali, and 7.5^ of water, the reft being fixed air. — On faturating a quan- tity with the vitriolic, nitrous, and marine acids, 100 grains of the mere alkah \vere found to take up io6 of niere vitriolic acid, 115 of the nitrous, and 130 of the marine acid. The fpscific gravity of the volatile alkali 4n Experi- ments on calcareous earth. Quantity ol marine acid fatu- rated by this earth. 439 Proportion •^yater, and earth ; loo grains of it contaii ("lentfin 3^ 34°^ ^^''^^ ^"'^ likewife of earth, and fi natural 3 2 of water. The artificial gypfum conta; Theory. C H Con'ents, alkali weighed in ether (b) was 1.4076. The propor- tion of water in the different amnion iacal falts could not be found on account of their volatility ; but was fup- pofed to be very fmall, as both volatile alkali and fixed air cryftallize without the help of water when in an aerial ftate. In making experiments on calcareous earth, it was firft diflblved in nitrous acid ; and after allowing for the lofs of fixed air and water, 100 grains of the pure earth was found to take up 104 of nitrous acid; but only 91 or 92 of mere vitriolic acid were required to precipitate it from the nitrous folution. Of the marine acid 100 grains of the pure calcare- ous earth require 112 for their folution. The liquor at firft is colourlefs, but acquires a greenifh colour by ftanding. Natural gypfum varies in its proportion of acid, ining from from 26 to 32 ot water, l ive artiftcial gypfum contains 32 of earth, 29.44 of acid, and 38.56 of vv^ater. When w^ll dried, it lofes about 24 of water ; and therefore contains 42 of earth, 39 of acid, and 19 of water, ^sr hundred. Nitrous felenite (folution of calcareous earth in ni- trous acid) carefully dried, contains 33.28 of acid, 32 of earth, and 34.72 of water. The fame quantity of marine felenite (folution of calcareous earth in marine acid), well dried, in fuch a manner as to lofe no part of the acid, contain of the latter 42.56, of earth 38, and of water 19.44. Magnefia, when perfeftly dry and free from fixed air, cannot be diflblved In any of the acids without heat. Even the ftrongeft nitrous acid did not a6t up- acids with on it In 24 hours in the temperature of the atmofpherc ; out heat, but in a heat of 1 80°, the mineral acids, diluted with four, or even fix, times their quantity of water, had a very fenfible effeft upon it : but the quantity of acid diflipated by heat rendered It Impoffible to afcertain how much was neceffary for folution, except by precipi- tation after It had been diffolved. For this purpofe the cauftic vegetable alkali was employed ; by which it appeared that 100 grains of pure magnefia take up 125 of mere vitriolic acid, 132 of the nitrous, and 140 of the marine. All of thefe folutlons appeared to con- tain fomething gelatinous ; but none of them reddened vegetable blues ; and that in the marine acid became greenllh on ftanding for fome time. An hundred grains of perfeftly dry Epfom fait con- tain 45.67 of mere vitriolic acid, 36.54 of pure earth, g"^'^'^"^* and 17.83 of water. Solution of common Epfom fait, lipfon°falt • ^^owever, reddens vegetable blues, and therefoi-e con- 'tains an excefs of acid. A like quantity of nitrous In nit' ous Epfom, well dried, contains 35.64 of acid, 27 of pure Epfom. earth, and 37.36 of water. The folution of marine k= Epfom cannot be tolerably dried without lofinof much Cannot be /, • 1 , m r iomic' in ot its acid together with the water. 1 he Ipecinc gra- marine Ep- vity of this earth is 2.3296. fom. Moft writers on chemlftry have faid that earth of Earth of 'i^"™ contains fcarce any fixed air ; but Mr KIrwan alum con- Vol. IV. Part II. tiiiis a f^reat quan- -— ^ ( B ) The fixed and volatile alkalies were weighed water. E M I S T R Y. 425 nat \gypfum ; 440 In nitrous felenite ; 441 In marine felenite. 444 Calcined magnefia will not diflblve in 443 . Proportion of the in- found that It contained no lefs than lS per cent, though Contents, it had been previoufly kept red-hot for half an hour. °^ It diffolved with a moderate eftervefcence in acids un- ^ til the heat was raifed to 220°; after which the folu- tion was found to have loft weight in the proportion above mentioned. 447 An hundred grains of this earth, deprived of the Quantity fixed air, require 1 3 3 of the pure vitriolic acid to dif- folve them. The folution was made in a very dilute alum! ^* fpirit of vitriol, whofe fpecific gravity was 1.093, ^"'i in which the proportion of acid to the water was near- ly as I to 14. It contained a flight excefs of acid, turning the vegetable blues to a brownifii red ; but It cryftallized when cold, and the cryftals were of the form of alum. Oiu- author, therefore, is of opinion, that this is the true proportion of acid and earth to be ufed In the formation of that fait, though there was 448 not water enough to form large cryftals. Perceiving T^'^i^ fait al- that the liquor contained an excefs of acid, more earth was added; but thus It was found Impoffible ,-2^5 of acU; to prevent It from tinging vegetable blues of a red colour until a precipitation was formed : and even when this was the cafe, though one part of the fait fell In the form juft mentioned, yet the reft would ftill redden vegetable blues as before ; though here our author doubts whether this be a mark of acidity. An hundred grains of alum, when dried, contain 42.74 of acid, 32.14 of earth, and 25.02 of water ; but cryftallized alum lofes per cent, by defic- catlon : therefore 100 grains of it contain 23.94 of acid, and 58.06 of water. An hundred grains of this Proportion pure earth take up, as near as can be judged, 153 of of pure pure nitrous acid. The folution ftill reddened vege- '^^'"''i of table blues ; but after the above quantity of earth was ^^Y^ added, an infoluble fait began to precipitate. The u ou JacJd • folution, when cold, became turbid, and could not be rendered quite clear by 500 times its quantity of wa- ter. An hundred and feventy-three grains of pure By marine marine acid are required for the diffolution of 1 00 acid, grains of earth of alum, but the liquor ftill red^ght g^j^"^ alfo to be as concentrated as poffible ; though, when this is the cafe, it is almofl impofTible to prevent a great quantity from efcaping, as a violent effervefcence takes place for fome time after the mixture. Aqua regia made with common fait or fal ammoniac and fpirit of nitre, is much lefs aqueous than that pro- ceeding from an immediate combination of both acids ; and hence it is the fitteft for producing cn'ftals of gold. Very little air is produced by the folution of this metal, and the operation goes on very flow. It is, however, better promoted by allowing it fufficient time, than by applying heat. An hundred grains of Quantity gold require for their folution 246 grains of real acid, '• the t'.vo acids beincj in the proportion above mentioned. ^ rin irrii- i ifi -n- i • -i- aqua regia. i liough foluble m the dephlogiiticated marine acid, it is only in very fmall quantity, unlefs the acid be in a fiate of vapour; for in its liquid ilate it is too aque- ^g, ous. In vitriolic and nitrous acids it is infoluble, tho' Calces of the calces are fomewhat foluble in the nitrous, m^ore gold foluble eaulyin the marine, but fcarcely at all in the vitriolic acid. Mr Kirwan fays, that gold in its metallic flate maybe diffufed through the concentrated nitrous acid, acTdl! tho' not diffolved in it ; contrary to the opinion of other 484 chcmifls, who have afhrmed that a true diifolution takes '^^'^ pla^^e. iir^'toKir'^' An hundred grains of mercury require for their fo- ^van be dif- lulion 230 grains of real vitriohc acid, whofe propor- fylved in nl- tion to that of water is as i to ^s- A ftrong heat is t^ous acid, alio requifite, and the air produced is vitriolic. Mtrcur - cipitate per fc k ftill lefs foluble. — An hundred grains with'^vi?i io- of vitriol of mercury, produced by precipitation, con- lie acid tain 77 of metal, 19 of acid, and 4 of water. In fpirit of nitre, 100 grains of mercury are diffol- wiih fj.irit ved by 28 of real acid, whofe proportion to the water of nitre, it contains is as i to ItVo* I" this acid the folution takes place without heat ; but it may alfo be diffolved in a m.uch more dilute acid, provided heat be applied. About 12 cubic inches of air are produced when heat is not applied ; but M. Lavoifier found the produce much greater. This, fays Mr Kirwan, v\as evidently caufcd by his ufing red or yellow fpirit of nitre, which already contains much phlogifton. Precipitate is much lefs eafily diFiolved in the nitrous acid, which Mr Kirwan fuppofes to be owing to the attraction of the aerial acid. 2d 486 The marine acid, in its common phlwgifticated Rate, With ma- does not aft on mercurj', at leaft in its ufual Hate of '"'"^ concentration ; though M. Romberg, in the Paris Memoirs for the year 1700, affirms, that he diffolved it by feveral months digeftion in this acid. When de- phlugiflicated, it certainly afts upon it, though very. 3 H 2 wcaklv triolic and nitrous 428 Contents, &c. of the Salts. .487 Zisic with vitriolic ^i(l ; With ni- trous acid. 489 Lefs metal ciiffolved by concen- trated than hy diluted nitrous acid. 490 With ma- tine acid. 491 Bifmuth fcarce fi>- luble in vitriolic acid. 49a Quantity diffolved in fjpirit of riitre. 493 Scarce fo- llble in ma- rine ricids. 2d 493 Nickel Vii'h vi- triolicacid; 494 V/ith ni- li oui acid. C H E M I weakly while in a liquid ftate. Precipitate perfe is alfo foluble in the marine acid with the afliftance of heat. An hundred grains of corrofive fubUinate con- tain 77 of mercury, 1 6 of real acid, and fix of water. The like quantity of mercurius dulcis contains 86 of metal and 14 of acid and water. Zinc requires for its folution an equal quantity of real vitriolic acid, whofe proportion to that of water may be as i to 8, 10, or 12. Heat mull be applied towards the end, when the faturation is almoft com- pleted. By the help of heat alfo this femimetal is fo- luble in the concentrated vitriolic acid, but a fmall quantity of black powder remains in all cafes undif- folved. An hundred cubic inches of inflammable air are produced. An hundred grains of vitriol of zinc contain 20 of zinc, 22 of acid, and 58 of water. The calces of zinc, if not exceedingly dephlogiilicated, are alfo foluble in this acid. An hundred and tv/enty-five grains of real nitrous acid, whofe proportion to water is that of i to 12, are required for the folution of 100 grains of this femi- metal, applying heat flightly from time to time. A concentrated acid diffolves lefs of the metal, as a great quantity of the menftruum efcapes during the effervefcence. No nitrous air can be procured, the acid being partly decompofed during the operation. The calces of zinc, if not too much dephlogiilicated, are likewife diflblved by the nitrous acid. An hundred grains of zinc require for their diflblu- tion 210 grains of real marine acid, the proportion of it to the water being as i to 9. If a more concentra- ted fpirit of fait be made ufe of, a coniiderable part of it will be diffipated during the effervefcence, and confe- quently more will be required for the folution. The calces of zinc are alfo foluble in the marine acid. Only three g^-ains of bifmuth were dilTolved by 200 of oil of vitriol, whofe fpecific gravity was 1.863, though a ftrong heat was ufed at the fame tinae. A greater quantity was indeed flightly dephlogiilicated ; but when the gravity of the acid was reduced to 1.200, only a fingle grain of the metal was diffolved by 400 of it. The calces of this femimetal are much more foluble. Four cubic inches of vitrioHc air were af- forded by the folution of three grains of bifmuth. In fpirit of nitre, 100 grains of real acid are only required to dilTolve 100 grains of the metal. The proportion of water to the acid ought to be as 8 or 9 to I ; in which cafe a gentle heat may be applied.. The folution affords 44 cubic inches of nitrous air. The calces of bifmuth are alfo foluble in this acid. — Only three or four grains of it were diifolved by 400 of marine acid, whofe fpecific gravity was 1.220. About four grains of nickel were diflblved in an hundred of the concentrated vitriolic acid with the alfiftance of a flrong heat ; but its calces are much, more foluble. — An hundred grains of nickel require for their folution 112 of real nitrous acid, whofe pro- portion to water is as i to 1 1 or 12. The produft of nitrous air is 79 inches. The calces are alfo foluble.. A moderate heat is neeeflary for the diflblution of the metal; but a concentrated acid afts fo rapidly that much of it ii diflipated.— Only four or five grains of nickel are diflblved by 2rOO of fpirit of fait whofe fpe- cific gravity was 1.220. An acid of this degree of .trength ads v/ithout the afliftance of heat,, though S T R y. Theory, a weaker acid requires it, and diflblves illll Icfs of the Contencs, metal. The calces of nickel are alfo foluble with dif- ^^:^f ficulty in this acid. ... , ' — ~ ^ -j Four hundred and fifty grains of real vitriolic acid, whofe proportion to water is not lefs than i to t^, With ma- are required for the diflblution of 100 grains of co-nneacid; bait, aflilled by a heat of ^£70° at leail. A folution ^ , 496 _ , . , , ' • ... J ui t^obaitvvith is obtained by pounng warm water on the dephJo- gifticated mafs. — The calces of cobalt, however, are acid ; more foluble ; fo that even a dilute acid will ferve.— In fpirit of nitre, the like quantity of cobalt requires with fpi- 220 grains of real acid, whofe proportion to water is rit of nitre ; as I to 4; giving a heat of 180' towards the end. — The calces of the metal are foluble in the nitrous acid.— ^^g An hundred grains of fpirit of fait, whofe fpecific gra- With fp.Tit vity is 1.178, diflblves, with the affiilance of heat, of fait; two grains and a half of cobalt ; and a greater quanti- ty will be diifolved by an acid more highly concen- trated.— The calces of cobalt are more foluble. An hundred grains of regulus of antimony require Reguh.s of for their folution 725 grains of real vitriohc acid, antnnony whofe proportion to water is as i to t-'o, afliiled by ^^i^^^^''^'.^" a heat of 400 '. A large quantity of regulus fliould ' * be put into the acid; and the refulting fait requires much water to dlflblve it, as the concentrated acid lets fall much when water is added to it. A lefs con- centrated acid will likewife diflblve this femimetal, but in fmaller quantity. The calces of antimony, even diaphoretic antimony, are fomewhat more foluble. Nine wj^jj hundred grains of real nitrous acid are required for the trouiacid. folution of 1 00 grains of regulus ; the proportion of acid to the water of the folvent being as i to 12, and aflifted by an heat of 110°; but the folution becomes turbid in a few days. The calces are miach lefs foluble in this acid. — Only one grain of the regulus is dif- folved by 100 of fpirit of fait, whofe fpecific gravity iuble in the was 1.220, with the aflifliance of a flight heat; and marine that which is only 1.178 dilfolves ftill lefs; but Mr^"*^' Kirwan is of opinion that the concentrated acid would, in a long time, and by the afliftance of a gentle heat, diflblve much more. The calces diflblve more eafily in the marine acid. ^ Eighteen grains of regulus of arfenic are_ diflblved Regulus of in a heat of 250° by 200 grains of real vitriolic acid, arfenie with whofe fpecific gravity is 1.87 1. About feven of thefe ^^^.J^^'c parts cryftalhze on cooling, and are foluble in a large ^'^^ ' quantity of water. The calces of arfenic are more foluble in this acid.— An hundred and forty grains of real nitrous acid are requlfite for the folution of i 00 trous acid 1 grains of regulus of arfenic ; the proportion of acid^ to the water being as i to 11. The folution aff"ords 102 cubic inches of nitrous air, the. barometer being at 30 and the thermometer at 60. Calces of arfenic are likewife foluble in this acid. _ 504 . An hundred grains of fpirit of fait, whofe fpecific With fpirit gravity is 1.220, difl"olve a grain and an half of regu-°^-*^^' lus of arfenic ; but the marine acid, in its common ftate, that is, when its gravity is under 1.17, does not at all afl^eft it. The arfenical calces are lefs foluble in this than in the vitriolic or nitrous acids. § 3. Of the ^antity of Phlog'yhn conialned in dlferent Sulflances. Having gone through all the various bafes with which acida are ufually combined, and afcertained the quantity 5or Scarce fo- 505 Quantity gi'lon con- tuiiied in nl ti ous air. Theory. C H E M Quantity of quantity of difTerent ingredients contained in the com- Phlo^ifton pQui^js refultine: from their union, we ou?ht next to Subftances. g''^'^ account oi our author's experiments on phlo- u— Y— J gifton; but as his fentiments on that fubjeft are taken notice of elfewhere, we fhall content ourfelves with briefly mentioning the very ingenious methods by which he difcovers the quantities of it contained in va- rious kinds of air and in fulphur. Having proved that inflammable air» In its concrete ftate, and phlogifl;on are the fame thing, Mr Kirwan proceeds to eftimate the quantity contained in nitrous air in the following manner. " An hundred grains of filings of iron, diflblved in a fiifficient quantity of very dilute vitriolic acid, pro- duced, with the afliftance of heat gradually applied, 155 cubic inches of inflammable air; the barometer being at 29.5, and the thermometer between 50^ and 60°. Now, inflammable air and phlogifl;on being the fame thing, this quantity of inflammable air a- mounts to 5.42 grains of phlogifton. — Again, 100 grains of iron diflVjlved in dephlogifticated nitrous acid, in a heat gradually apphed and raifed to the utmofl:, afford 83.87 cubic inches of nitrous air. But as this nitrous air contains nearly the whole quantity of phlogiflon which iron will part with (it being more completely dephlogiflicated by this than any other means), it follows, that 83,87 cubic inches of nitrous air contain at leaft 5.42 grains of phlogifton. But it may reafonably be thought, that the whole quantity of phlogifton which iron will part with is not expelled by the vitriolic acid, but that nitrous acid may expel and take up more of it. To try whether this was really the cafe, a quantity of green vitriol was cal- cined until its bafis became quite infipid; after which, two cubic inches of nitrous air were extrafted from 64 grains of this ochre ; and confequently 100 grains would yield 3.12 cubic inches of nitrous air. If 83.87 cubic inches of nitrous air contain 5.42 of phlogifton ; tlicn 3.12 cubic inches of this air contain 0.2 of phlo- gifton. The nitrous acid, therefore, extrafts from 100 grains of iron two-tenths of a grain more phlo- gifton than vitriolic acid does. Therefore 83.87 cubic inches of nitrous air, containing nearly the whole phlogifton of the iron, have 5.62 of this fub- flance. Hence 100 cubic inches of nitrous air contain 6.7 grains of phlogifton." With regard to the quantity of phlogifton in fixed air, after proving at length that it is compofed of 2d J05 cf phlogif- ton in fixed dephlogifticated air united to the principle of inflam- ^5 mability, Mr Kirwan afcertains the quantity of the latter in the following manner : " Dr Prieftley, in the fourth volume of his Obfervations, p. 380, has fatis- fdftorily proved, that nitrous air parts with as much phlogifton to common air, as an equal bulk of inflamma- ble does when fixed in the fame proportion of common air. Now, when inflammable air unites with common air, its whole weight unites to it, as it contains no- thing elfe but pure phlogifton. Since, therefore, ni- trous air phlogifticates common air to the fame de- gree that inflammable air does, it muft part with a quantity of phlogifton, equal to the weight of a vo- liime of inflammable air, fimilar to that of nitious air. But 100 cubic inches of inflammable air weigh three grains and a half ; therefore 100 cubic inches of ni- trous air part with 3.5 grains of phlogifton, when ^.ey communicate their phlogifton to as much common I S T R Y. 429 air as will take it up. In this procefs, however, the Qinntity of nitrous air does not part with the whole of the phlo- p'''"^'^°" gifton it contains, as appears by the red colour it con- subfbn'ce"'^ ftantly alfumes when mixed with common or dephlo- ■ . ^ gifticated air ; which colour belongs to the nitrous acid, combined with the remainder of its phlogifton, whence the acid produced is always volatile. *' One meafure of the pureil dephlogifticated air and two of nitrous air occupy but x| o of one meafure, as Dr Prieftley has obferved. Suppofe one meafure to contain 100 cubic inches, then the whole, very near- ly, of the nitrous air will difappear (its acid uniting to- the water over which the mixture is made), and 97 cubic inches of the dephlogifticated air, which is con- verted into fixed air by its union with the phlogifton of the nitrous air; therefore 97 cubic inches of de- phlogifticated air take up all the phlogifton which- 200 cubic inches of nitrous air will part with ; and this we have found to be feven grains: therefore a weight of fixed air equal to that of 97 cubic inch- es of dephlogifticated air, and 7 of phlogifton, will contain feven grains of the latter. Now, 97 cubic inches of dephlogifticated air weigh 40.74 grains; to which adding 7, we have the whole weight of the fix- ed air, = 47. 74 grains, =: 8 3. 755 cubic inches ; and con- fequently 100 cubic inches of fixed air contain 8.357 grains of phlogifton, the remainder being dephlogifti- cated air. An hundred grains of fixed air therefore, contain 14.661 of phlogifton, and 85.339 of elemen- tary or dephlogifticated air. Hence alfo 100 cubic inches of dephlogifticated air are converted into fixed air by 7.2165 grains of phlogifton, and will be then reduced to the bulk of 86.34 cubic inches* 506 To find the quantity of phlogifton in vitriolic acld^" vitrioiio air, our author purfued the following method. "'^^'^ 1. He found the quantity of nitrous air afforded by a given weight of copper, when dilTolved in the dephlogifticated nitrous acid, and by that means how much phlogifton it parts with» 2. He found the quantity of copper which a given quantity of the dephlogifticated vitriohc acid could dif- folve; and obferved, that it could not entirely fat-urate itfelf with copper without dephlogifticating a further quantity which it does not diffolve. 3. He found how much it dephlogiftlcates what it thoroughly diffolves, and how much it-dephlogifticates what it barely calcines. 4. How much inflammable air a given quantity of copper aflfords when diffoived In the vitriolic acid to the G:reateft advantas^e. 5. He deducts from the whole quantity of phlogi- fton expelled by the vitriolic acid the quantity of it contained in the inflammable air ; the remainder (liows the quantity of it contained in the vitriolic acid air. The conclufion deduced from experiments conduct- ed after this manner is. that 100 cubic inches of vi- triohc air contain 6.6 grains of phlogifton, and 71.3 grains of acid; and 100 cubic inches of this air wcia;h- ing 77.8 grains, 100 of it muft contain 8.48 grains phlogifton, and 91.53 of acid. To find the quantity of phlogifton in fulphur, Mr Quan-i'-- o" Kirwan propofed to eftimate that of the fixed air pro- pblog-iihm duced during its. combuftion. For this purpofe he Sul: htr. firmly tied and cemented to the open top of a glafs- bell a large bladder, deftined to receive the air ex- panded by combuftion, which genendly efcapes when thi* * riiie acid air, 430 C H E M I Qi^^nuty of^i^is precaution is not ufed. Under this bell, con- !n'!M''rctn taining about 30CO cubic inclu-s of air, a CJUidlt- of siiblia' cc's i'ulphur, weighing 347 grains, was placed ; its wick, . i which v/as not conuuned, weighing half a gram. It 508 was fupported by a \ery thin concave plate of tin, to Proper me- prevent the fulphur from running over during the coni- hurnfntn i l^ufiion ; and both were fupported by an iron wire fixed ' "in a flielf in a tub of water. As foon as the fulphur h'egan to burn with a feeble flame, it was covered with the bell, tlie air being fqnee/.ed out of the bladder. 'I'he iiifide of the bell was foon filled v.-ith white fumes, ft' that the flame could not be feen ; but in about an hour after all the fumes were thoroughly fubfided, and 5 he glufs become cold, as much water entered the liell as was equal to 87.2 cubic inches; which fpacc our author conchides to have been occupied by fixed air, and which muft have contained 7.287 grains of phlogifton. The candle of fulphur being weighed was found to have loft 20.75 grains; therefore 20.75 grains of fulphur contain 7.287 of phlogifton, behdes the quantity of phlogifton which remained in the vi- triolic air. ' This air muft have amounted to 20.75 — 7.287=13.463 grains, which, as already fiiown, con- tain 1. 41 grains of phlogifton. Therefore llie whole quantity of phlogifton In 20.75 g^"^'''-^ fulphur is 8.428; of confequence too grains of fulphur contaui 59.39 of vltrlohc acid, and 40.61 of phlogifton. OuStv The quantity of phlogifton contained in marine c^'hlo jf- acid air was found by the following method.— Eight ton in ma- grains of copper diffolved in colourlefs ipint of fait afforded but 4.9 inches of Inflammable air ; but when the experiment was repeated over mercury, 91.28 cu- bic Inches of air were obtained. Of thefe only 4.9 cubic Inches were Inflammable; and confequently the remainder, 86.38 Inches, were marine air, weighnig 56.49 grains.— Now, as fpirit of fait certainly does not dephloglftlcate copper more than the vitriolic acid does. It follows, that thefe 4.9 cubic Inches of inflam- mable air, and 86.38 of marine air, do not contain more phlogifton than would be feparated from the fame quantity of copper by the vitriolic acid ; and fmce 100 grains of copper would yield to the vitriolic acid 4.32 grains of phlogifton, 8.5 grains^of copper would yield 0.367 grains of phlogifton. This there- fore is the whole quantity extrafted by the _ marine acid, and contained In 91.28 cubic inches of air ; and, deduftlng from this the quantity of phlogifton con- tained In 4.9 cubic Inches of inflammable air =:o.i7_i grains, the remalndei*, viz. 0.367 — 0.171=0.196, is all the phlogifton that can be found In 86.38 cubic Inches of marine air. Then 100 cublc_ inches of it contain but 0.227 of a grain of phlogifton, 65.173 grains being acid. — Hence we fee why it ads fo feebly on oils, fpirit ofwIne,£ffc.andwhy it Is not di (lodged from any bafis by uniting with phlogifton, as the vitriolic and nitrous acids are, its affinity to It being inconflderable. § 4. Remarks on the Doarhies of the ^lantity and Jpe- c'tfic Gravity above delivered. •fj, -fr ■ • To this doftrine of the fpecific gravity and quan- cJjeSkln.' tity of acid contained in different fubftances, Mr Keir to K.rwan'shas made feveral objeaions. i. Mr Kirwan fuppofes, doctrines, t^^t marine acid gas Is the pure and folid maiinc acid divefted of all water and other matter. Its apparent drynefs in this refpeft, however, Is no argument that 510 Why ma- rine acid a<5ts fo weakly. ad 5 10 Mr Keir's S T R Y. Theory. it really contains no water; for water icfelf, reduced Remarks to a flute of vapour, poffeffcs no moiftening P'''opfi'ty. ^"l^J^"" Tiieic is great reafon to believe that water is a conlti- t,'j,,g, tuent part of fjme gales, and it is certain that all of v.«— y-— ,»j them are capable of holding it in folulion. As raoift materials, therefore, are employed in the preparation of mui-ineacid air, there feems no reafon to believe, that in any way in which Mr Kirwan c<)uld obtain it, there was reafon to fuppofe it perfedly free of water ; ia wfu'ch cafe the denlity of the acid would be greater, and its quantity fmallerthan lie fuppofes. 2. A confiderable part of the denfity of the acid ab- foi "bed in the experiment, probably arofe from the con- denfation wliich always accompanies the union of a concentrated acid with water. Mr Kirwan allows this to be the cafe with the nitrous and vitrolic acids, but thinks it too inconilderable to deierve notice in the ma- rine. Hii reafoning, however, does not app;;ar fa- tisfaftory, or his experiments on the fubje£t conchi- five. He obfcrves, that the length of tim.e taken up in effecting an union between the marine gas and water, is no argument againll their attrafting one an- other iirongly when once united; and it is certain that part of this acid gas is very quickly abforbed by water. He alfo finds fault with his accuracy in cal- culation; aiid afierts, that if matters are fairly flated, the realdenfiry of the m.arine acid gas will be con- fiderably lefs than Mr Kirwan makes it. 3. A great obltacle even to an approximation to- wards the real denfity of the acid, arifes from the con- dcnfation which the water, as well as the acids, muft fufier in the procefs : and in this cafe, where a ge- neral condenfation takes place, he alks, " How fliall we determine the part of the condenfation that belongs to the water, and the part that the acid iuf- tains This, with other confiderations, makes Mr Keir " doubt of the poffibility of folving the qutftion concerning the adual denfity of pure and folid acids.'' The inveiUgation of the queftion, indeed, he does not confider as a matter of great confequence, as every ufe- ful application may be oljtalned, by Hrfl Inveftigating the comparative ftrengths of different portions of the fame acid rendered more or lefs dilute ; and then by finding out the ftrength of the vitriolic, nurous, and marine acids of known denfities, fo that they may be compared togetlier. " Homberg (fays he) has the me- rit of making the fir!t effay towards this inveftiga- tion. Bergman and Wenzel have fupplied the de- fetl of Homberg, by taking into confideiation the gas united with alkaline fubftances ; and Mr Kirwan, by ufing determinate quantities of acid hquors of known denfiiii'S, has confiderably improvtd the method of Bergman : and whoever lucceeds thefe able cheinifts in this inquiry, may avail himl'elf greatly of their ia- bom-s, particularly thofe of Mr Kirwan." He con- cludes with ftating the refulis of the inquiries made by the chemifts above mentioned; on which he makes the following remarks. •« The difcorJancy of thefe re fults Is very ftriking, Orent dif- and gives but an humiliating reprefentation of the pi-e- fercnces in cifion of our prefent knowledge in chemiftry. A g''^.^*^ [^("jj"' ^'f part of the difference arifes undoubtedly from the dif- j^,ff5,rent ferent views in which thefe authors confidered the dry- authors, ncfs or pvu-Ity of the acids. Mr Kirwan, as we have feen, endeavoured to find their denfity and quantity in 5 » rheorv. C H E M I S T R Y. 431 a ftatc of perfeit drynefs and purity ; which he fup- pofed to exift in the marine ?.cid gas : with which he compared and iiii^crred the dcuuties and quantities of the nitrous and vitriohc acidy, upon the fuppoiition that equal quantities of thefe feveral acids are fatu- rated by a given weight of fixed alkali. Beiides the uncertainty of his principles, from wliich he deduces the denlity and quantity of the marine acid, his appli- cations from thence to deduce the denuties of the pure nitrous and vitriolic acids, being founded on the above fuppofition, muft partake of its defedls. The alkali which he happened to fix on as the ftandard by which he compared the ftrengths of the different acid liquors, in arder to determine the quantity of real acid they contained, and thence to determine their denfity in a folid Hate, was the fixed vegetable. Having found that 100 grain J uf his real marine acid could faturate 215 grains of this alkali, he infers, that tl:t fame pro- jKTrtion is applicable to the other acids : and accord.- ingly we find that 100 grains of each of the pure and real mineral acids are faturated by an equal quantity, 215 grains of this alkali. But if we exaaiinc the other columns of his table, we fhall at once fee, that, in other fubftances ffjluble by acids, this equality docs not exift ; and that every inch lubftance has a ratio peculiar to Itfelf, with refpeil to the proportions of thefe acids neceflary for its faturatlon. It is evident, therefore, that if ^^r Kirwan had fixed on the mineral alkali, the volatile alkali, lime, or any other fub- ftance, as a flandard, inftead of vegetable alkali, his determination of the denllties of the real vitriolic and nitrous acids would have been different ; and as no reafon can be afligned why the vegetable alkali or any other fubftance fnould have the prerogative over the reft, it is obvious that there can be no fuch general ftandard, but that each fubftance pofTeflts fblely the capacity of determining the proportions of the fevei^al acids neceffary for its faturatlon. " The other chemifts were contented to confider as the pure and dry acid, that which aclually remains in the neutral fait, after this has been rendered as dry as p offible by expofure to a red heat : and having made tlieir alkalies as dry as they could, they fuppofed thefe alkalies to retain the fame weight in the dried neutral fait ; and that the augmentation of the weight gained by the alkali during the formation of the neutral fait fhfiwed the weight of the dry acid. The uncertainty which affects this method arifes from the different ca- pacities which difTerent neutral falts may poflefs of re- taining more or lefs water, either as a conflituent part of the diy fait, or merely by the ftrength of adhefion 4)r affinity. Nevertheltfs, this method being founded folely on expeiiment, without any theoretical Induc- tions, feems to furniih fome approximation, not per- haps of the abfolute quantity of the acids in their drleft poITible Itate, but of the acids as they a£fually *xift in thefe falts comparatively with each other. Though the difagreements between Bergman's and Wenzel's refults are little in comparifon of the diffe- rence between them and Kirwan's, yet as their expe- riments were made nearly in the fame manner, and upon the fame grounds, there feems to be fufficient reafon to wifli for a careful repetition of their experi- ments, or of others with the fame view, and lefs liable to objeclions. The only difference in the methods employed by Remarks thefe two celebrated chemifts coulifted in the mode ofo" 'y^^"^' faturatlon. Bergman probably ufed the common me- ^^-^.^^^^ thud, but Wen/.el employed a very pecuhar one. He l— -y— ^ added to his alkali a greater quantity of acid than v.-as ntceffary for the faturatlon ; and after the alkali was dlifolved, he added a lump of zinc, or of oyfter-fliell, ia order to fatuiate completely the fuperfiuous acid. By obferving how much of the zinc or oyftcr-fhcll the acid dlifolved, and knowing- how much of thefe fubftances was foluble in his acid by former experiments, he in- fen-ed the quantity of acid left for the faturatlon of the alkali. Having thus afcertained the quantity ne- ceflary to faturate the alkali, he mixed together the proper proportions of thefe, and formed his neutral fait by evaporating the mixture and drying the fait with a red heat. Perhaps the difference In the refults obtained by thefe two chemifts might arife from their different modes of faturatlon. The common method of afcertalning the point of faturatlon by means of litmus or other blue vegetable juices, appears fuffi- clently exadf. Is fimplei", and therefore preferable to that ufed by Wenzel. " The ftandard for comparing the ftrengths of acids, and likewife of alkalies with one another, may be ei- ther an acid or an alkaline fubftance ; and if we had one of each, the proportion of whole quantities requi- fite for their mutual faturatlon were well afcertained, the convenlency in making the expernnents would be obvious, and the ceilalnty greater. Alkaline, and the earthy fubftances that are foluble In acids, are feldcm pure enough for this purpofe. Tiiey generally con- tain quantities, which are not conftant, of fixed ah-, liliceous earth, magnefia, neutral falts, and inflammable mattei, which render any of thole that are commonly met with unfit for the purpofe without a very lkiifi;l and careful purification. The chemiils v/ho have made experiments to determine the proportions of acids and alkahes requlfite for each other's faturatlon, have fcarce- ly been explicit enough in explaining the means of pu- rifying the alkalies which they employed ; for thofe in commerce are quite uncertain in flrength and purity : and as to the general rules for making allowances for any heterogeneous fubftances they may contain, the j are quite inapplicable to delicate experlTuents. No other method feems proper for afcertalning the pu- rity of alkahes but that of cryftallization ; of whiclv both the vegetable and mineral alkahes are fufceptibl;^, efpecially the latter, which on account of its being more eafily reducible into cryftals, is therefore prefer- able. Thefe alkaline cryftals, however, are not tit to be ufed as a ftandard, becaufe they either are apt to be infufficlently dried, or, upon expofure to air, to lofe a part of the water of their cryftallization, and to fall into powder. Even if they fliould be taken, as is pot- fible with due care, at the exaft ftate of dry but entire cryftals, another uncertainty arifes from a property which feems to be common to them all, namely, that of retaining a greater or fmaller quantity of water- ac- cording to the degree of heat in which they were cryftaUized; the colder the weather the greater quau - tity of water entering into the compofition of the cry-- 4t'i jio Hals. It feems poflible, however, to make a pretty accurate ftandard of mineral alkali in the following "J^/..^";.,^^ manner : Let the alkali be purified by repeated folu-ua alk,il-r e 432 CHEMISTRY. tion raid cryilullizatlon, ufiiig only fuch as are formed firft, and rejofting the remaining liquors. Let the pure cr^'ftals be expofcd to a dry air until they have completely efflorefced or fallen into a di-y white pow- der ; which alteration may be facilitated by bruifing the cryllals, and changing the furface of the powder. Let this powder be then expofed for a certain and de- terminate time to a conftant heat, as that of boihng v/ater for 1 2 hours ; letting the furface expofed be in fome given proportion, fuppofe of a fquare inch to an ounce of the powder of cryllals, and let it be flirred every two hours. When thus dried, let them be put while hot into a bottle, and well flopped. This pow- der I have found to be an uniform and conftant ftand- ard for afcertaining the ftrength of acids ; and alfo, by ■comjjarifon by means of acids, of other alkaline fub- flances." With regard to an acid ftandard, our author re- commends oil of vitriol ; which, he fays, as it comes from the hands of the Britilh manufafturers, is of the fpecific gravity of about 1.846, but foon becomes >\'eaker, unlefs carefully kept from the external air ; and in general he rates it at 1.844. O"*^ P'^''"^ acid mixed with nine of water, is of a very convenient llrength for ufe ; and as every ten grains of the mix- ture contain one of the ftandard acid, the computations m-e thus rendered eafy : and by thefe ftandards, the ftrength of all acids, alkalies, and fubftances foluble in ^th ^To "^'^y meafured and compai-ed together. His method To determine the fpecific gravity of liquors with of iindinjif ciccuracy, our author recommends the method of weigh- the fpecific j^g them in a phial fitted with a glafs-ftopper, which can only enter a certain length into the neck. In this way, he obferves, no other inconvenience can en- fue than the flight one, that the glafs-ftopper, by very frequent ufe, is apt to wear itfelf and the neck of the phial alfo ; fo that after a great number of experiments, it will at laft diminifli, in fome meafure, the capacity of the phial itfelf. This, however, is but very trifling, and may be correfted at any time. Mr Keir has be- fides found, that after fome hundreds of experiments, the error amounted only to one quarter of a grain in loi grains. " The methods hitherto praftifed (fays he) for af- certaining the quantities of acids and alkalies contain- ed in neutral falts, feem to be liable to feveral objec- tions befides thofe above mentioned, arifing from the different proportions of water remaining in a neutral fait, after expofure to a red heat, which heat is alfo very indefinite. In boiling the faturated mixture of acid and alkali to drynefs, and afterwards in expofing this fait to a red heat, it has been fuppofed that nothing but water is expelled ; and fome chemifts, who have given the refults, have alfo determined the weight of the alkali which enters into the neutral mixture, by evaporating to drynefs an equal quantity of the alka- line folution which had been employed in the fatura- t!on, and weighing the dry folution, on the fuppofi- ■fition that nothing is expelled but water. It is cer- tain, however, that in the evaporation both of alkalies and neutral falts, a confiderable portion of the faline matter is elevated towards the end, when the liquor becomes concentrated and acquires a degree of heat coufiderably above that of boiling water. The fol- K°7i. 1 Theory. irravity of riiiFcrenc lowing method appears bell for determining the reia- 'f^emark ^nd it has al- ways appeared to me, that the weight of phlogifton in fulphur is almoft infinitely fmall." His objeftion pro- - ceeds on a maxim which he thinks he has demonftra- ted, viz. that fulphur is compofed, not of the vitriolic acid and phlogifton, but of the 6afe of vitriolic acid and phlogifton. No experiments hitherto made, how- ever, have been able to fhow this bafe diftincL from the acid ; nor have we any reafon to fuppofe that the in- creafe of weight in the vitriolic acid above the fulphur from Theory. G H E M ^ %mh$. ^ from which it « produced, arifes from any thing be- *~''V''*~' fides the acceflion of mere water, which the air parta with during the combuftion. Hence, if the fulphur is burnt in a very moift air, the quantity of acid obtained will be four or five times the weight of the fulphur. Sect. IV. Earths. These are divided into five clafTes : i. Abforbent, alkaline, or calcareous earths : 2. Argillaceous earths or clay: 3. The flinty: 4. The fufible earths : and, 5. The talks. I. The firA clafs comprehends all thofe that are ca- pable of being converted into hme. They are found of various degrees of hardnefs ; but none of them are capable of totally refilling the edge of a knife, or ftriking fire with fteel. They are found to confift of a very friable earth, joined with a large quantity of air and fome water. They effervefce with an acid when poured on them ; by which they are diftinguiflied from all other kinds of earth, except the argillaceous. When calcined by a ftrong fire, they part with the water and air which they contained, and then acquire a great degree of caufticity, lofe their power of ef- fervefcing with acids, and become what is a cal- Quicklime. 9'"'^^^^^^- They are foluble in acids, but not equal- ly fo in all. The vitrioHc and tartareous acids form compounds with them very difficultly foluble ; the fe- leniteSf formed by the vitriolic acid and calcareous earth, requiring, according to Mr Beaumc, an ounce of water to diffblve a fingle grain of it. The folubi- lity of the tartareous felenite hath not yet been de- termined. — With the other mineral acids, the calca- reous earths become eafily foluble ; and by proper ma- nagement form concretes which appear luminous in the dark, and are called p/jo/phori. Argiiiace- 2. The argillaceous earths diiTer from the calca- •u». reous, in not being convertible into quicklime. When mixed into a pafte with water, and expofed to the fire, they (brink remarkably, crack in many places, and become exceflively hard. By being gently dried in the open air before they are turned, they do not crack, and thus may be formed into veffels of any fhape. Of this kind of earth are formed all the brown fort of earthen ware. The pureft kind of argillaceous €arth naturally found, is that whereof tobacco-pipes are made. All the argillaceous earths are foluble in acids. With the vitriolic they diflblve into a gelatinous tough liquor very difficultly cryftaUizable ; but which, on the addi- tion of fome fixed or volatile alkali, may be (hot into cryftals of the fait called alum. With the other acids they form aftringent falts of a fimilar nature. The attraction between the argillaceous earths and acids is very weak, yielding not only to alkaline falts both fixed and volatile, but even to fome metals, par- ticularly iron ; but thefe earths have as yet been but little the fubjeft of chemical examination in this way. They have a remarkable property of abforbing the colouring matter of cochineal, Brafil-wood, life, as have alfo the calces of fome metals. Both the calcareous and argillaeeous, and indeed all earths when pure, refift the utmott violence of fire ; but when mixed together will readily melt, efpecially if In Gontad with the burning fuel. Dr Lew's having Vol. IV. Part II. 433 Earths, I S T R Y. made covers to fome crucibles of clay and chalk mixed together, found that they melted into a yellow glafs, before the mixtures in the crucibles were fufed in the leaft. But though they melted thus readihr when in contaft with the fuel, it was with great difficulty he could bring them to a tranfparent glafs when put into a crucible. The other fpecies of earths, vh. the flinty, fufible, and talky, being no other way the fubjedts of che- miftry than as they are fubfervient to the making of glafs, all that can be faid of them will moft properly come under that article. For their diff"erent fpecies, fee Mineralogy. Befides the above mentioned fpecies of earths, there Anomalous are others which may be called anomalous, as having fome refemblance of the calcareous and argillaceous, and yet being eflentially different from them. Thefe are the white earth called magnefta alba, the earth of burnt vegetables, and that produced from burning a- nimal fubfliances. Magnefia alba was at firft; prepared from the thick Magnefia. hquor remaining after the cryftallization of nitre ; |and is now found to be contained in the Hquor called bit- tern, which is left after the feparation of common fait from fea-water. In the former cafe it was united with the nitrous, in the latter with the vitriolic, acid. It is alfo found naturally in the foft kind of ftone called Jleatites or " foap Hone and in the concrete ufed for taking fpots out of cloaths, called French chalk. It difl'ers from the calcareous earths, In not acquiring any caufticity when deprived of its air, of which it con- tains fo large a quantity as to lofe two-thirds of its weight when calcined. From the argillaceous it dif- fers in not burning hard when mixed with water, nor forming a tough dudile paflie. It is eafily foluble In all the acids, even the vitriolic ; with which it forms the bitter purging fait commonly called Epfom fait, fi-om its being firfl: difcovered in the waters of Epfom. With all the other acids it likewife forms purgative compounds, which are either very difficultly or not at all cryftaUizable. — Like other pure earths, it can- not be melted by itfelf ; but, on proper additions, runs into a beautiful green glafs. The earth of burnt vegetables is thought by Dr Vegetable Lewis to be the fame with magnefia alba ; but on try- ^'"^ animal ing the common wood aflies, they were found to be very different. This kind of earth is fufible, by rea- fon of the alkaline falts contained in it. Animal earth is both very difficult of folution in acids, and impof- fible to be melted in the ftrongeft fire. It diflblves, however, in acid liquors, though flowly; but the na- ture of the compounds formed by fuch an union are as yet unknown. The fofter parts of animals, fuch as blood, flefh, i!fc. are faid to yield a more foluble earth than the others. Animal earth has lately been fup- pofed to be compounded of calcareous earth and phof- phoric acid ; but this opinion is ftiown to be erroneous under the article Bones. The phofphoric acid pro- duced from thefe, is with reafon fuppofed to be only the vitriolic acid changed. Sect.V. Inflammable Subjiances. 516 These comprehend all vegetable, animal, and fome PJ^enomena mineral fubfl;ances. They are diftinguiflied from all ^^"""'"So 3 I others, 434 Inflam- mable Sub- fiances. CHEMISTRY. Theory. 317 On diftilla. tion. 518 Treated with diffe lent acids. 519 Singular produc- tions. others, by emitting a grofs thick fmoke and flame, when a certain degree of heat is applied. To this, however, fpliit of wine and all preparations from it are exceptions. They burn without the leaft fmake ; and if a glafs bell is held over the burning fplrit, no foot is formed, only a quantity of water is found condenfed on its fides. Even the grofler oils, if flowly burnt with a very fmall flame, will yield no foot; and an exceeding great quantity of water, fully equal in weight and bulk to the oil employed, may be obtained from them. We can fcarcely, however, credit, that fo great a quantity of water comes from the oil ; as this would be a real tranf- mutation ; and Ave know that, befides water, the oils contain alfo fome quantity of fixed air, as well as earth. It is probable, therefore, that, as it is Impoflible to fuftain flame without a decompofition of that part of the air which rufhes In to fupport it, part of the water in this cafe comes from the air, which always contains moifture in abundance. Inflammable matters, on being burnt, generally leave behind a fmall quantity of earthy matter called afies ; but to this, fplrit of wine, camphor, the more volatile oils, and the mineral oil called naptha, are exceptions. . Vegetable fuftances, when diftlUed In clofe veffels, give out a quantity of air, fome acid, and an empyrcumatic oil, leaving behind a black fpongy mafs called charcoal. To this too there are a few exceptions, viz. fpirit of wine, and the preparations from It, camphor, and per- haps fome of the more volatile oils, or naphtha. Ani- mal fubftances yield only a very fetid empyreumatic oil, and volatile alkali. In general, all inflammable matters are afted upon with fome violence by the vitriolic and nitrous acids, excepting only camphor and naphtha. With the vi- triolic acid, when In a liquid ftate, they render It vola- tile and fulphureous ; If in 'a dry fl:ate, they form ac- tual fulphur. With the nitrous, they firft Impart a high colour and great degree of volatility to the acid ; then a violent flame enfues, if the matter Is attempted to be dried. With fpirit of wine the effefts are confi- derably different ; and very volatile compounds are formed, which are called ether, on account of their ex- ceeding great difpofitlon to rife in vapour. Similar compounds are likewlfe produced, but with more dif- ficulty, from the marine acid and concentrated vine- gar. The fal fedativus of borax mixes with fplrit of wine, and caufes It burn with a green flame ; but does not feem to produce any other change upon it. How the acid of phofphorus and of ants aft upon fplrit of ■wine, is not exaftly known ; but that of tartar by dl- geftion with It, Is converted Into the acetous acid. With any other inflammable matter, the phofporine acid re- produces phofphorus. There are two fingularltles obferved among the In- flammable fubfl:ances. One Is that bituminous matter called amber, which yields a volatile fait of an acid nature on diftlUation : "When combined with alkalies, this acid is found to yield compounds fimllar to thofe made with the acetous acid and alkali. The other Is, that gum called benzoin, which is ufcd as a perfume, and yields by fubllmatiun a kind of votatlle fait in fine Alin- ing cryftals like fmall needles, and of a molt grateful odour. Thefe diflblve very rtadily in fpirit of wine ; but not at all in water, unlels It Is made very hot ; fo ^t they feeia to contain more oily than faline matter. Neither the nature of thefe flowers, however, nor that Metalline of the fait of amber, is fully known. Subltances. Sect. VI. Metalline Stihjlances. These are diftlngulfhed from all other bodies by their great fpec'^ic gravity, exceeding that of the moft denfe and compaft ftones. Tiie heavleft of the latter do not exceed the fpecific gravity of water in a greater proportion than that of 4 to i ; but tin, the llghteft of all the metals, exceeds the fpecific gravity of water In the proportion of 7 to i. They are alfo the raoft opaque of all known bodies, and reflcd the niys of light mod powerfully. _ Metallic bodies poflTefs the quality of diffolvlng in Metals fo» and uniting with acid falls, in common with earths luble in a- and alkalies ; but, in general, their union Is lefs per- cids. fe£l, and they are more eafily feparable. They ef- fervefce with acids, as well as calcareous earths and alkahes ; but their effervefcence is attended with very different appearances. In the eff"ervefcence of acids with alkalies, or with calcareous earths, there is a dll- charge of the fluid called fxecl air, which is fo far from being Inflammable, that it will immediately extinguifh a candle, or other fmall flame immerfed In it. The mixture alfo is notably dimlnifhed in weight. When a metallic fubftance is dilfolved in an acid, the weight of the mixture is never very much dimlnifhed, and fometimes it Is increafed. Thus, an ounce of quick- filver being flowly dropped Into as much aquafortis as was fufficient to diffolve it, and the folution managed fo as to take up almofl; a whole day, the whole was found to have gained feven grains. There is alfo a re- markable difference between the nature of the vapour difcharged from metals and that fro;n alkalies; the former, in mf)ft cafes, taking fire and exploding with violence ; the latter, as already obferved, extingulililng flame. ' 511 The metallic fubftances, at leafl: fuch as we are able Their com^ to decompound, are all compofed of a certain kind of po^"'""- earth, and the inflammable principle called phlogijlon. The earthy part by itfelf, In whatever way It Is pro- cured, goes by the name of calx. The other principle has already been proved to be the fame with charcoal. When thefe two principles are feparated from one an- other, the metal Is then faid to be calcined. The calx Calcination being mixed with any inflammable fubft:ance, fuch as ^ndjevivi- powdered charcoal, and urged with a ftrong fire, '° melts into metal again ; and It is then faid to be re- duced, or revificated: and this takes place whether the metal has been reduced to a calx by diflblutlon in an acid, or by being expofed to a violent fire. If, how- ever, the calcination by fire has been very violent and long continued, the calx will not then fo readily unite with the phloglfl:on of the charcoal, and the re- dattion will be performed with more difficulty. Whe- ther, by this means, fia. a long continued and violent calcination, metallic earths might entirely lofe their property of combining with phlogifton, and be changed Into thofe of another kind, deferves well to be inquired into. S»3 When a metallic fubfl^ance is difTolved In any kind of Calcination acid, and an alkali or calcareous earth not deprived ^"''J"^^ of its fixed air is added, the alkali will immediately J^,g^„ht"by be atiraded by the acid, at the fame time that the fix- acids. ed M. Lavoi- fier's expe- limcntf. Theory. G H E M I Metalline ed air contained in the alkali is difengaged, and the Subftanccs. ^^■[^ metal, having now no acid to keep it dlf- folved, immediately joins with the fixed air of the al- kali, and falls to the bottom. Something fimilar to this happens when metals arc calcined by lire. In this cafe, there is a continual decompofition of the air which enters the fire ; and the fixed air contained in it, bting, by this decompofition, let loofe, combines with ti\e calx ; whence, in both cafes, there is a confi- derable incrcafe of weight. If the air is excluded from a metal, it cannot be calcined even by the mott vio- lent fire. Reafon of When a raetal is precipitated by a mild alkali, or by the increafe an uncalcined calcareous earth, the i-eafon of the in- of wei|;htin ^^^^fg of ^^v^jg^it {g very evident; namely, the adhe- taices''''^ fion of the fixed air to the metalline calx : but, though- it is not fo much increafed when precipitated by can- flic alkali, or by quicklime, there is neverthelefs a very evident increafe, which is not fo eafily accounted for. M. Lavoifier has mentioned fjme experiments made on mercury and iron dilFolved in aquafortis, which deferve to be taken notice of, as in a great meafure accounting for the phenomenon already mentioned of th^folution of metalline fubftances gaining an addi- tion of weight ; and likewife (how the proportion of increafe of weight with the mild, or calcined calcareous earth. " Exaftly 12 ounces of quickfilver (fays he) were put f^ito a matrafs, and 12 ounces of fpirit of nitre poured on it. Immediately a fpontaneous effervef- cencc enfued, attended with heat. The red vapours of the nitrous acid arofe from the mixture, and the Hquor afTumed a greenifh colour. I did not wait till the fo- lution was entirely accompliflied before I Weighed it ; it had loft one drachm 18 grains. Three hours after, the mercury was nearly all dlffolved: but having again weighed the folation, I was much attonifhed to perceive that it had increafed inftead of being diminifhed in weight ; and that the lofs, which was one drachm 1 8 grains at firft, was now only 54 grains. The next day the folution of the mercury was entirely finlfhed, and the lofs of weight reduced to 1 8 grains ; fo that in 1 2 hours the folution, though confined in a narrow neck- ed matrafs, had acquired an augmentation in weight of one dr-achm. I added fome diftilled water to my fo- lution, to prevent it from. cryftalHzing; the total weight of it was then found to be 48 ounces i drachm and 1 8 grains. " I weighed feparately, in two veflels, 8 ounces 15 grains of the above folution, each of which por- tions, according to the preceding experiment, ought to contain 2 ounces of nitrous acid and 2 ounces of quickfilver. On the other fide, I prepared 6 di-achms 36 grains of chalk, and 4 drachms 36 grains of lime ; thefe proportions having been found by former ex- perim.ents juft neceffary to faturate two ounces of ni- trous acid. I .put the chalk in the one veffel, and the lime in the other. " An effervefcence attended the precipitation by chalk, but without heat ; the meirury pi-ecipitated in a light yellow powder, at the fame time the chalk was diffolved in the niti-ous acid. The precipitation by the lime was efFeCiled without e£Fer%'efcence, but with heat; the mercury was precipitated in a brownifh S T R Y. powder. When the precipitates were well fublided, Metallme I decanted off the liquors from them, and carefully edulcorated them. After which, I caufed them to be " ' dried in a heat nearly equal to that in which mercury boils. " The precipitate by the chalk weighed 2 ounces 2 drachms 45 grains ; that by the lime weighed 2 ounces I diachm 45 grains. *' Sixteen ounces of the nitrous acid, the fame aa employed in the former experiments, were placed in a mati-afs, and fome iron filings gradually added. The effervefcence was brifk, attended with great heat, red vapours, and a very rapid difcharge of elaftic fluid : the quantity of iron neceffary to attain the point of faturation was 2 ounces 4 drachms ; after which, the lofs of weight was found to be 4 dr-achms 19 grains. As the folution was turbid, I added as much diftilled water as made the vv-hole w^eight of the folution to be exaftly 6 pounds. " I took two portions, each weighing i 2 ounces of the above folution, and containing 3 ounces of nitrous acid, and 2 drachms 36 grains of iron filings. I pla* ced them in two feparate veflels. To one were added 6 drachms 36 grains of chalk ; and to the other 4 drachms 36 grains of flaked lime, being the quantities neceffary to faturate the acid. " The precipitation was effefted by the chalk with effervefcence and tumefaftion, that by the lime witJi- out either effervefcence or heat. Each precipitate was a yellow brown ruil of iron. They were wafhed in feveral parcels of diftilled water, and then dried in an heat fomewhat fuperior to that ufed in the laft ex* periment. " The precipitate by the chalk, when dried, was a / greyifh ruft of iron, inclining even to white by veins. It weighed 6 drachms 35 grains. That by the lime was rather yellower, aiid weighed 4 drachms 69 grains. " The refult of thefe experiments (fays M. La- Confequen- voifier) are, I. That iron and mercury diffolved in ces from his the nitrous acid acquire a i-emarkable increafe of^^P^f*- weight, whether they be precipitated by chalk or by ^^'^^^ » lime. 2. That this increafe is greater in refpedl to iron than mercury. 3. That one reafon for thinking that the elaftic fluid contributes to this augmentation is, that it is conftantly greater when an earth is em- ployed faturated with elaftic fluid, fuch as chalk, than when an earth is uftd which has been deprived of it, as lime. 4. That it is probable that the increafe of w^eight which is experienced in the precipitation of lime, although not fo great as that by chalk, proceeds in part from a portion of the elaftic fluid which re^ mains united to the lime, and which could not be fepa- rated by the calcination." But though We are naturally enough inclined to Not well think that the increafe of weight in the precipitates founded, formed by lime proceeded from fome quantity of ela- ftic fluid or fixed air which remained combined with the lime, it is by far too great to be accounted for in this way, even according to the experiments men- tioned by M. Lavoifier himfelf, and which, from thfc manner in which they are told, appear to have been performed with the greateft accui^acy. He found, that I ounce 5 drachms and 36 grains of flaked lime confained 3 drachms and 3 quarters of a grain of water, 3 I 2 and CHEMISTRY. 3 so What me- tal a^-e cal- cinable, & with what degrees of licat. 541 Rufting of metals. 54a Fufibility of metal- lic com- pounds. 543 Rrtat fufi- bility of compounds of tin and l)jfmuth. 544 ©ne fufiblg by the heat •f boiling water. and only 1 6 grains and an half of claftic fluid were fe- parable from it. In the experiments above related, where only 4 drachms and 36 grains were employed, the quantity of elaftic fluid could not exceed 6 or S grains. Yet the calx was increafed in mercury by no lefs than 105 grains, and in iron by 203 grains; a quantity quite unaccountable from the elaftic fluid or fixed air which we can fuppofe to be contained in the \ime made ufe of. It is much more probable, that the increafed weight of metallic precipitates, formed by lime, arifes from an adhefion of part of the acid. Metals are found to be compounded of a kind of earth mixed with the inflammable principle or phlo- gifton ; and, by a difBpation of the latter, all metallic bodies, gold, filver, and platina excepted, are capabk of being reduced to a calx, but very dift"erent degrees of heat are required for calcining them. Lead and tin begin to calcine as foon as th-ey are melted, long be- fore they are made red-hot. The fame happeris to the femimetals bifmuth and zinc ; the latter indeed, being combuftible, cannot bear a greater heat in open veffels than that which is barely fufficient to melt it. Iron and copper require a red heat to calcine them ; though the former may be made partly to calcine by being frequently wetted in a degree of heat confiderably below that which is fufficient to make it red. Moft metals undergo a kind of fpontaneons calcina- tion in the open air, which is called their nifiing; and which has given occafion to various conjeftures. But M. Lavoifier has fliown, that this arifes from the fix- able part of the atmofphere attaching itfelf to their earthy part, and difcharging the phlogifton. Accord- ing to him, no metallic body can ruft but where there is an abforption of air ; and confcquently metals can be but imperfedtly rufted when kept under a re- ceiver. If two metals are mixed together, the compound generally turns out more fufible than either of them was before the mixture. There are indeed great differences in the degrees of heat requifite to melt them. Thus, lead and tin melt below that degree of heat which is required to make quickfilver or hnfeed- oil boil. , Silver requires a full red heat, gold a low white heat, copper a full white, and iron an ex- treme white heat, to make it melt. The feraimetal called bifmuth melts at about 460° of Fahrenheit's thermometer, and tin at about 422". When mixed in equal quantities, the compound melted at 283°. When the tin was double the bifmuth, it required 334" to melt ft ; with eight times more tin than bifmuth, it did not melt under 392°. If to this compound lead is added, which by itfelf m.elts in about 540°, the fu- fibility is furpriiingly increafed. Mr Homberg pro- pofed for an anatomical injection a compound of lead, tin, and bifmuth, in equal parts ; which he tells us keeps in fufton with a heat fo moderate that it will not finge paper. Sir If'ac Newton contrived a mix- ture of the above-me.itioned metallic fubftances, in fuch proportions that it melted and kept fluid in a beat ftill fmaller, not much exceeding that of boiling water. A compound of two parts of lead, three parts of tin, ^nd five of bifonuth, did but juft ftiffen at that very heat, and fo would have melted with very little more ; and when the lead, tin, and bifmuth, were to one ano- ) Theory. ther in the proportions of I, 4, and 5, the compound Metalline melted in 246^. We have feen, however, a piece pf S-ibftances.^ metal compounded of thefe three, the proportions un- * ' "'" "* known, which melted, and even underwent a flight degree of calcination, in boiling water, and barely Itif- fened in a degree of heat fo gentle that the hand could, almoft bear it. 54J A flight degree of calcination feems to give the Solubility acids a greater power over metalline fubftances ; a.^||^ greater makes them lefs foluble ; and if long and vio- [,y'^'j,^j lently calcined, they are not afted upon by acids at t on. all. Of all the acids, the marine has the greateft at- traction for metallic calces, and volatilizes almoft every one of them. Sulphur readily unites with moft rruetals, deftroys ElFe-6lsof their malleability, and even entirely diflblves them.. ^"'p'^"'' On gold and platina, however, it has no effedl, till'"^"^** united with a fixed alkaline fait, when, it forms the compound called hepar fulphur'is ; which is a very pov^'erful folvent, and will make even gold and pla- tina th<;mfelves foluble in, water, fo as to pafs the filter. This preparation is thought to be the means by which Mofes diflblved and gave the Ifi-aelites to drink the golden calf which they had idolati-ouily fct up. ' When a metal is diflblved in an acid, it may be precipitated, not only by means of calcareous earths and alkalies, but alfo .by fome other metals : for acids do not attraft all metals with equal ftrength ; ^d it is remarkable, that when a metal is precipitated by another, the precipitate is not found in a calcined ftate,, but in a metallic one. The reafon of this is, tliat the precipitating metal attrafts the phlogifton which is ex- pelled from that w hich is diflblving, and immediately unites with it, fo as to appear in its proper form. The various degrees of attradliion which acids have for the diff^erent metals is not as yet fully determined. The beft authenticated are mentioned in the Table of Affi- nities or Eleftive Attradlions (Sed. IX.); MetalUne fubftances are divided into metals and fe-Divifion In] mimetals. The metals which are diftihguifhed from to metals the femimetallic fubftances by their malleability or^"^ femi- ftretching under the hammer, are in number fcven;"^^^*' gold, filver, copper, iron, lead., tin,, and platina. To thefe is added quickfilver ; which Mr Bi-own's expe- riments have ftiown to be a real malleable metal, as well as others, but requiring fo little heat to keep it in fufion, that it is always found in a liquid ftate. The femimetals are bifmuth or tin-glafs, zinc, regulus of antimony, and cobalt, nickel, and arfenic. This laft ^^g fubftance is now difcovered to be compounded of an acid Proj erties of a peculiar kind and phlogifton ; and as. the quantity of the latter is gi-eat or fmall, the arfenic afliimes ei- ther a metallic or faline form. It hkewife unites with fidphur, with which it forms a compound of a red or yellow colour, according as more or lefs fulphur is ufed. This compound is eafily fufible ; though the arfenic, by itfelf, is fo volatile as to go all off^ in vapour rather than raelt. In common with the falts, it pof- fefles the properties of diflblving in water, and uniting itfelf to alkalies. Water will diflblve about -rV of its weight of pure arfenic ; but if arfenic is boiled in a ftrong alkaline lixivium, a much greater proportion will be dilfolved. Indeed ftrong alk.aline lixivia v.'ill difr folye Theory. C H E M Waters, &c. folve a part of almofl every metalline fubllance, except gold, filver, and platina ; but, excepting copper, which may be formed into cryftals by means of the vo- latile alkali, none of them wiU affume a cryftalline form when united with alkaUes. Arfenic, on the contrary, unites very readily with fixed alkalies, and {hoots with them into a neutral fait. If it is mixed v.'ith nitre, it unites itfelf to the alkaline bafis of that fait, and expels the acid in very volatile fumes, which are difficultly condenfed into a blue hquor. The rea- fon of this is the great attraftion between the nitrous acid and phlogifton, which are always difpofed to unite when a proper degree of heat is applied. Was the phlogifton contained in large quantity in the arfenic, and the heat fufficiently great, a violent deflagration would enfue ; but as the acid of arfenic attradls the alkaline part of the nitre, at the fame time that the ni- trous acid attrafts the phlogifton, a double decompo- lition enfues, in a lefs degree of heat than would other- wife be neceffary ; and die niti'ous acid arifes in a very volatile ftate, as it always is when combined with phlo- gifton, which is the occafion of the bluenefs in aqua- fortis fo produced. The arfenic is alfo decompofed by being deprived of its proper quantity of phlogifton ; in confequence of which its acid attaches itfelf to the fix- ed alkali of the nitre, and forms a neutral arfenical fait. For the extraftion of metallic fubftances from their ores, and the various methods of refining them, fee Metallurgy. Sect. VII. JVaters. The pure element of water, like that of fire, is lb much an agent in moft chemical operations, as to be it- felf very little the objeS of practical chemiftry. Some late experiments, however, have ftiown that this fluid really confifts, in part at leaft, of phlogifton, and an in- vifible fubftance which forms the bafis of pure air; and confequently water is generated in the deflagration of dephlogifticated air ; but as the bafis of the former cannot be perceived by itfelf, we can as yet fay nothing about it. Waters, therefore, can only be the objedts "Water.howof chemiftry, in confequence of the impurities they far an objedl contain : and as thefe impurities are moft commonly of chemi- ^£ faline kind, it is impoffible that any general theo- ry can be given of waters, diftint5l from that of tlie falts contained in them ; which all depend on the ge- neral properties belonging to falts, and which we have already mentioned. Any thing that can be faid with regard to water*, then, muft be poftponed. to the parti- cular confideration of the properties of each of the fa- line bodies with which water is capable of being adul- terated- W e n^all therefore refer entirely to the article Water in the order of the alphabet, for what caabc faid on thisfubje£t. Sect. VIII. Animal and Vegetable Subjlances. Ch/m?cal The general chemical properties of thefe have been properties, already taken notice of under the name of injlanitnalle fuhjlances. They agree in giving out a very thick fe- tid oil, when diftilled by a ftrong fire ; but in other refpe£ls they differ very confiderably. Moft kinds of Tegetables give out an acid along with the oil ; but all animal fubftf^nces (ants, and perhaps fome other infefts, excepted) yield only a volatUe alkali. Soxne kinds of 3 I S T R Y. 437 vegetables, indeed, as muftaid, afford a volatile alkali Chemical . on diftillation, fimilar to that from animal fubftances ; ^h arajSlers. but inftanccs of this kind are very rare, as well as of ' ^ animals affording an acid. Both animal and vegetable fubftances are fufccptible of a kind of fermentation, called putrefaalon, by which a volatile alkali is produ- ced in great plenty : there is, however, this remark- able difference between them, that many vegetable fubftances undergo two kinds of fermentation be- fore they arrive at the putrefactive ftage. The firft is called the vinous, when the ardent fpirits are produced, which v.-e have already mentioned when fpeaking of inflammable fubftances. This is fucceeded by the ace- tous, wherein the vegetable acid called nmegar is pro- duced in plenty : anS laftly, the putrefafhive ftage fuc- ceeds when a volatile, alkali is only produced ; not the fmalleft veft-ige either of ardent fpirits or of vinegar re- maining. On the other hand, animal fubftances feem fufceptible only of the p.utrefa£tive fermentation ; no inftance having ever occurred where there was the leaft drop, either of ardent fpirit or of vinegar, produced from a putrified an-'mal fubftance. (See Fermenta.- TiON and Putrefaction.) Sect. IX. Of the Chemical CharaBersy and Tables cf Ele£Hve Atira^ion. 55"' The numerous marhs or charaders by which the an- Inventioa cient chemifts ufed to denote many different fubftances, mark* were invented rather from a fuperftitious and fantafti- jjj.j^^'^'^''* cal principle than from any real necelfity ; or, perhaps, like the enigmatical language ufed by the alchemifts, they have tJiereby fought to conceal their myfteries from the vulgar. In contriving thefe marks, they af- fefted a great deal of ingenuity ; intending them as fyrabfjis of the q^ualities poffeffed by each or the diffe- rent fubftances. A circle being fuppofed the moft per fed figure, was therefore ufed to reprefent the moft per- feftmetal in nature, thatisj^o/J. Silver being hkewife a perfeil and indeftruftible metal, is placed next to gold ; but, on account of its inferiority, is expreffed only by a crefcent, as if but half gold. A circle was likewife ufed to denote fait of any kind, as being fome thing elaborate and perfeft. A crofs was ufed to denote acrimony of any kind, and confequently employed for the acrimo- nious falts of vitriol, alkali, &c. Hence all the in- ferior metals have the crofs fome how or other com- bined with the marks defigned to reprefent them. Thus, the mark for quickfilver denotes, that it hath the fplendor of filver, the weight of gold, but its perfeilion is hindered by an acrimony reprefented by the crofs at bottom, &c. Fire is reprefented by an equilateral triangle, having oire of its angles uppermoft. This may be confidered as a rude reprefentation of flame, which is always pointed at top. Water, again, is re- prefented by a triangle, with an angle downwards, ftiowing the way in which that element exerts its ftrength, &c. AH thefe marks, however,, as they were of no real ufe at firft, fo they are now becoming every day more and more negledled. Such of them, however, as may moft readily occur in chemical books are reprefented and explained on Plate CXXXII. The French chemifts have of late attempted to in- New che« troduce a kind of new chemical language ; and by a- "^"^^^ '•'^^ dopting it thcmfelves, may perhaps make it at laft uni- S"*S«*- Tcrfa}, 438 G H E M I Eietllve verfal, as h is now Jmpoffible to underftand their wri- Attradtion. tings without knowing it. See the Table at the end * of this article. Of ^aMes of "^^^^^^ njjinities, or elcBive attraSions, are but of affinities, late invention. They are confequences of an impro- ved ftate of chemiftry, when the different fubrtances were found to a6l upon one another in moft cafes ac- cording to a fixed and fettled rule. The moft appro- ved table of this kind for a long time was that compo- fed by Mr GeofFroy. It was, however, found to be very incomplete, not only as to its extent, but like- wife as heat and fome other circumftances were found to vary the attraftions confiderably, and fometimes •even to reverfe them. Other tables have been conftruc- ted by Mr Gellert, &c. but none hath yet appeared fo complete but that many additions may be made to it. The following is that at prefent exhibited by Dr Black in his courfe of chemittry. 1. Vitriolic Acid. Phlogifton Terra ponderofa Fixed alkali Calcareous earth Zinc Iron Tin Copper Quickfilver Silver Volatile alkali Magnefia Earth of alum. 2. Nitrous Acid. Phlogifton Fixed alkali Calcareous earth Zinc Iron -Lead Tin Copper Quickfilver Silver Volatile alkali. 3. Marine AciB. Fixed alkali Calcareous earth Zinc Iron Ijead Tin Copper Regulus of antimony Quickfilver Silv-T Spirit of wine Volatile oils Gold. 4. Sulphur. Fixed alkali Calcareous earth Iron Nickel Copper Lead Tin Silver Regulus of antimony Quickfilver Arfenic. 5. HepAR SuLPHURlS is partially decompounded by Quickfilver 'Solution of fixed alkali Lime-water Volatile alkali. 6. Fixed Air. Calcareous earth Fixed alkali Magnefia Volatile alkali. 7. Alkaline Salts. Vitriolic acid Nitrous acid Marine acid Acetous acid Volatile vitriolic acid Sedative fait Fixed air Sulphur Exprefled oils. 8. Calcareous Earth. Vitriolic acid Nitrous acid Marine acid Acid of tartar Acetous acid Sulphureous acid and fe- dative fait Sulphur. 9. Metallic Substan- ces, Lead and Regulus of Antimony excepted. Marine acid. S T R Y. Vitriolic acid Nitrous acid Sulphur and acetous acid. 10. Lead. Vitriolic acid Marine acid Nitrous acid Acetous acid Exprefied oils. n. Regulus of Anti- mony. Vitriolic acid Nitrous acid Marine acid Acetous acid. 12. Arsenic^. Zinc Iron Copper Tin Lead Silver Gold. 13. Regulus of Anti- mony with Metals. Iron Copper Tin Lead Silver Gold. 14. QuiCKSILt'ER, Gold Lead and tin Copper Zinc, bifmuth, and regu- lus of antimony. 15. Silver. Lead Copper Iron. 16. Waters Fixed alkali Spirit of wine Milk, alkahne falts, and fome neutrals. 1 7. Spirit of Wine. Water Oils and refins. Theory, Attraction, In confequence of heat, fedatlve fait and the other folid acids decompound vitriolated tartar, nitre, and fea-falt. Double Eleftive Attraflions; which, in fome cafes, may be confidered as exceptions to the foregoing table. I. Thofe which happen In mixtures of watery fub* ftances. 6. C Acids < Calc.eatths, orme- C tallic fubftances C Vitriolic or marine s acids ^Alkalies or earths C Lead ■< Nitrous, marine, or C acetous acids r Silver ■s Vitriolic, nitrous, C or acetous acids 5 Volatile alkali I Acids C Nitrous, marIne,or ■s acetous acids C Calcareous earths Volatile alkali Fixed air. Mercury, filver, or lead. Nitrous or acetous acids. Vitriol acid Alkalies, earths, or M. S. Marine acid Alkaline falts, earths, or M. S. Fixed air Fixed alkali. Volatile alkali, magnefia, or earth of alum Vitriolic acid. 5 Vol. alkali 7 Acids II. Thofe which happen in diftillations or fublima- tions, and require heat. Fixed air Calcareous earths. Nitrous, marine, or ace* tous acids Fixed alkali. Acetous acid Fixed alkali, or abforbent earths. Vol. alkali Vitriol, acid Vol. alkali I Nitrous, marine, or vitriohc acids Theorv, hcmical Jperations. C Reg. of antimon. Sulphur CHE Marine acid Quickfilver. M III. Thofe which happen in mixtures by fullon. I. f Tin Iron l_ Silver Lead. C Copper Sulphur ^' ^Gold Lead. 5 M. S. Sulphur 3- I Gold Reg. of ant. The firft of thefe tables requires very little expla- nation. The names printed in fmall capitals, are thofe of the fubftances which have the affinity with or at- tra£l thofe below them. Thus, vitriolic acid attracts moft powerfully the phlogifton, or inflammable prin- ciple ; next, fixed alkaH ; then, calcareous earth ; and fo on, in the order in which they are marked. — The tables of double eledlive attractions cannot be made quite fo diftinft ; though an explanation of one ex- ample will make this likewife eafy to be underftood. Thus in Table I. the firft cafe is, *' If a combination of acids with calcareous earths or metallic fubftances is mixed with a combination of volatile alkali and fixed air, the acids will unite themfelves to the volatile al- kali, and the fixed air tallic fubftance. to the calcareous earth or me- 5S4 Sect. X. Of the different Operations in Prac- tical Chemiflry, and the proper Injiriimerits for performing each, Operatii-ns The moft remarkable operations in chemiftry, and in chemi- by which the greateft changes are made upon thofe ^•y- bodies which are the objefts of that fcience, may be comprehended under the following names. i . Solu- tion. 2. Filtration. 3. Precipitation, or coagulation. 4. Evaporation. 5. Cryftallization. 6. Diftillatlon. 7. Sublimation. 8. Deflagration. 9. Calcination. 10. Fu- fion. II. Maceration, or digeftion. To which we j.^ may add, X2. Trituration, or levigation. Chemifts, Before we proceed to a particular account of each how divid- of thefe operations, it is neceflary to take notice, that there are two diiferent things propofed by thofe who enter on the praAice of chemiftry. Some have no- thing farther in view than the enlargement of their knowledge,, or making improvements in arts which are to be praftifed by others for their own advantage. Others defign to follow chemiftry as a trade, by which they hope to enrich themfelves, or to get a comfortable livelihood. But the apparatus and utenfils neceffary for performing the very fame op^ations are exceed- ingly different when experiments only are to be made, from what they muft be when thefe operations are performed with a view to profit ; and fo great is this difFcrence, than thofe who purfue chemiftry with a view to advantage, will always find themfelves very confiderable lofers if they follow the plan of an appa- ratus or a laboratory defigned only for making expe- riments. Along with the apparatus, therefore, which is commonly defcribed in chemical books, and proper only for experiments, we fhall alfo give that which is neceflary for preparing great quantities of any chemi- cal article in the way of trade. Glafs vcf- In general, thofe who praAice chemiftry merely fels, when an experimental view, ought, as mucli as pof- 'to be ufed. ^ ' & ' r ^ I S T R Y. 439 fible, to make ufe of glafs veffels, as not being liable Chemical to be corroded by the moft powerful folvents ; and, pperatiom. by their tranfparency, giving an opportunity of ob- ferving what paffes within them during the operation. But by thofe who pradlife chemiftry with a different view, thefe veflcls ought, with equal care, to be a- voided, on account of their expence and brittleuefs. This laft quality, iadeed, is poffefled by glafs in fo eminent a degree, that glafs veflels will fometimes fly to pieces, and that with confiderable violence, when ftanding by themfelves, and nothing touching them. The principal objefts which a chemift ought to have in view, in performing his operations, ought to be to fave time and fuel, efpecially the former; and for this purpofe, he would find himfelf a confiderable gainer, though he fhould be at much greater expence in his apparatus than he would otherwife have occa- fion for. On the fubjeft of chemical veflels Dr Black ob- Dr Black's ferves, that " with regard to the material of which ".^f'^''"'^- thefe are compofed, we are very much at a lofs : and '^i""* . , , , ^ r 1 • 1 • cheniicai indeed there are ao iuch materials in nature as are ca- veflels. pable of anfweriug the purpofes of chemifts in abfo- lute perfe6lion. — The qualities are, i . Tranfparency, to allow us to fee the changes going on; 2. The power of refifting the aftion of acids and corrofive fubftan- ces ; 3, That they bear fudden alterations of heat and cold v^'ithout breaking ; 4. That they be ftrong,, in order to confine elaftic vapours ; and, 5. That they bear very great heat without melting. As thefe qualities, how- ever, are not to be met with united in any one fub- ftance, the chemifts are obliged to have recourfe to different fubftances which poffefs fome of them dif- ferently. Thefe are, glafs , metal, and earthen ware. Good and' Glafs is poflefled of the two firft properties, but has^^at^ quali- the inconvenience of being apt to crack and fly in pieces, on any fudden tranfition from heat to cold, or^i;^! from cold to heat. The beft method of remedying chemical this defeft, is to have the glafs made very thin, and veffels. of a round figure, that it may be all heated as equally as poflible ; as it is the unequal application of the heat which caufes it break. Another requifite in the choice of chemical glaffes, is that they be well annealed. If this is not done, the glafs will either immediately fly Extreme to pieces, or be liable to break on the fmalleft acci- ^'''g'^li'y «f dent. That fuch glafl"es fliould be liable to be broken ^^Uanneal- on every flight occafion, is a phenomenon that has hi- g^. therto received no explanation. If you touch them with a diamond, with a piece of flint, glafs, l^c. or expofe them to the heat of the fun, they break imme- diately. Dr Black has had great veflels of glafs, which broke immediately on his throwing a little fand into them to clean thtm. This manifeftly depends upon the fame principles as the qualities of what are called glafs tears. Glafs when well annealed is univerfally to be pre- ferred, where great and fudden changes of heat, or much ftrength, are not required. Flint -glafs is the beft- ; but the coarfer kinds, as bottle-glafs, are very apt to break. ^ f,o The metals have the third and fourth , qualities ^nd^ \^ perfeftion, but are deficient in all the reft. The j^^*^ 'Ij^'j^^''^'* moft troublefome property is, that they are liable a ^ n^^^^ lobe corroded by acids and other bodies, as is the reriais tit- cafe with iron and copper; though this is in fome.chprnical 440 C H E M 561 Of earthen ware. Chemical meafure remedied by tmnmo; 5 which, though it wants O peratior s. f^j^^^ q£ ^Yie. qualities from its melting too foon, yet " refifts the a£tion of many acrid fubftances without be- ing fo readily injured by them ; but it is not entirely free from this imperfedtion, and is liable to be fome- what corroded and rulled. In nice operat'.ons, there- fore, recourfe is had to filver and even to gold vcf- fels. ■ Earthen ware poffeffes only the fifth quality in per- feftion, viz. that of bearing a violent heat without fu- fion. The bafis of thefe veffels is clay, which, when good, is very convenient for the fonnation of veffels, and it has been ufed from the earlieft ages of chemi- ftry for this purpofe. The requilite quahties are, i. A confiderable degree of toughnefs when mixed with water. 2. A great degree of hardnefs when burnt in the fire with a violent degree of heat. The bell kind of clay thus contrafts a degree of hardnefs fcarce in- ferior to flint, as is the cafe with that of which tobacr co-pipes are made; but moft other kinds, fuch as that of which bricks are conftrufted, are apt to melt with a ftrong heat into a fpongy matter. Clay, however, can feldom be ufed alone; for when burnt to ex- treme hardnefs, the veffels are very hable to crack. This is remedied by mixing fand reduced to a parti- cular degree of finenefs, with the clay of which the veffels are made. For this purpofe both the fineft and the coarfeft particles of the fand muft be thrown away. Black lead Another fubflance known by the name of black a valuable lead, ufed in the making of pencils, refifts the fire ex- -inaterial for ^.g£(]jngiy. This, however, does not contain an ore feme pur- ^£ ^ezd, but fulphur, and fome mineral fubflances ; when mixed with clay, however, it makes it refift the fire furprifingly. But there are fome particular cafes in which neither fand nor black lead can be ufed as a material ; for the fand is eafily corroded by acrid mat- ters, and the black lead would produce other inconve- m'ences. Clay is therefore to be taken in its unbutnt ftate, reducing it to a powder like fand ; then burn- ing this powder with a violent heat, fo as to convert it into fand. Mixing it then with raw clay, it forms a compofition which anfwers very well for making che- mical veffels, and may be employed in thofe particular cafes where fand would not anfwcr. Pott of Berlin has written upon the different kinds of earthen ware proper to be employed in the conflruftion of chemical veffels. There is a French tranflation of it in four or Porcelain ^'^^ volumes. In cafes where the utmofl compaflnefs veffels when of texture is required, porcelain veffels are to be cho- to be ufed. fen ; which is compofed of the finefl clay, mixed with a ftony matter, that has the quality of melting in a violent heat, and gives more compaAnefs to the clay than it is naturally capable of receiving ; but thefe are rather too collly for moft operations. Reaumur has taught a way of converting glafs into porctlaln. We fhall now proceed to a particular defcription of each of the operations above mentioned. ^^^f I. Solution. By this is undtrftood the diffolving a Solution. ^^^.^ fubflance in a fluid, fo as that the fi lid fhall totally difappear, and become part of a tranfpartnt liquor. This operation applies particularly to falts, earths, and metals ; as well as to fevcral undluous and inflammable fubflances. For performing this operaticm in a fmall way, common vials are in many cafes fuflicient. Where N°7i. I S T R Y. Theory the folutton h attended -With efFervefcence and a dif- Chen^ical charge of vapours, the long-necked glafTes called Qpgratior.i vmtrafes, o\- bolt-hecuh, (fig. 5-)» are neccffary. F^^' pj^tc rence flafks are indeed exceedingly well adapted for CXXXIV. this operation, as being of the proper fliape, and ca- pable of bearing heat fo well, thai they may be filled with any fluid, and fet on a common fire hke a me- talHne veffel. Solution is much promoted by agitating the veffel, and by heat. In fome cafes, indeed, it will not take place till the mixture becomes very hot ; and in fuch cafes it will be proper to make the fluid boil- ing hot by itfelf, and then flowly to add the fubflance to be diffolved. When large quantities of fallne matter are to be diffolved, metaUine veffels muft be ufed : but before any are made ufe of for this purpofe, it will be neceffary to make an experiment whether the fait receives any impregnation from the metal of which the veffel in- tended to be made ufe of is formed ; and if this Is found to be the cafe, it muft not be ufed. The me- tals moft liable to be corroded by fallne bodies are iron and copper ; and indeed, unlefs it be for the fingle purpofe of diffolving fixed alkaline falts, iron veffels feem totally unfit for fallne folutlons of any kind. Cop- per veffels are alfo very liable to be corroded, and to communicate very mifchicvous qualities to the liquors which corrode them ; for which reafon, they ought never to be made ufe of for the purpofes of folution. The metal leaft liable to be corroded, next to gold and filver, is lead ; and therefore achemift ought rather to provide himfelf with leaden veffels than thofe of any other metal. But though lead is not apt to be corroded by many kinds of falts, there are fome which are found to a6l upon it, and to form therewith a very dangerous poifon. The vegetable acid of vinegar is particularly apt to receive a dangerous impregnation from this me- tal; and therefore no folution of any fait containing this acid ought to be made in leaden veffels. It appears to be very little affefted by the vitriolic or marine acids; and therefore any fallne fubftance containing either of thefe acids may be fafely enough diffolved in veffels made of lead. In order to fave time in making folutlons, the Vef- fels ought to be as large as poffible ; though even In this there muft be a certain hmii : for two fmall vef- fels filled with water will fooner acquire the neceffary degree of heat than one large one ; and in proportioa as the veffel is made more capacious, the fides and bot- tom muft be thicker, which confiderably increafes the expence. Fifteen or twenty Engllfli gallons is the utmoft capacity of which they ever will be required; and Is rather above what will on molt occafions be neceffary. They ought to be of a conical figure, round at the bottom ; and to have a cover of thick plate-iron all around that part which is expofed to the aftion of the fire, that the lead may not bend on the ap- plication of heat, which It would otherwife be very apt to do. When the folution is to be made, the leaden veffel is firft to be filled up with water fo far as to have room for the quantity of fait Intended to be diffolved : a fire Is then to be applied fo as to make it boil : and then the fait is to be added flowly, fo as fcarcely to hinder the boiling ; for If a great quantity was thrown in at once, fo as to cool the liquor very much, great part af the fait would concrete on the bottom, In fuch a Theary. C H E M Chemical a manner as not only to be very difficultly foluble, but pP^*"^^'"'". even to endanger the melting of the vefTel. It is of fome confequence alfo to avoid the hot fleam which pioceeds from the boiling water, and which ifliies with great force from a narrow-mouthed vefiel fuch as we have been defcribing. That the operator may be out of the reach of this, and likewife dj/Tolve the fait in a regular and gradual manner, without any danger of its concreting on the bottom, it will be proper to have a leaden, or even a wooden, veflel, with a long handle ; which is to be filled with the fubftance to be diflblved, then immerfed in the boiling liquor, and fliaken about in it, till the fait is made into a kind of thick pap, which will be in no danger of concre- ting. It will alfo be proper not to faturate the water perfeftly with fait ; for it will in that cafe be impof- fible to hinder part of it from fettling on the bottom, where it foon acquires fuch a degree of heat as to melt the lead. Before any faline fubftance is put into water for folution, it ought to be pounded and fifted through a hair fieve. Where large quantities of metal are to be dilTolved in acids, efpecially the nitrous acid, glafs veffels are in a manner indifpenfable ; although the common ftone- ware bottles, efpecially thofe made in Holland, will an- fwer the purpofe very well, as not being liable to cor- rofion, and not fo apt to break as the glafs veffels are. They may be got of fuc^ a fize as to hold three or four gallons : but no vefTel in which metalline folutions are made ought ever to be above half full. In folutions of oily and inflammable fubftances, cafl iron vefTels are perhaps the moft proper of any ; though copper ones are generally preferred. The copper is exceflively foluble in oil, efpecially If it is left to cool in fuch a vefTel ; but Iron is not foluble in any inflammable matter except fulphur. Copper has, however, this ad- vantage over iron, that it is fooner cooled, as the vcfTels made of copper are thinner than they can be made of cafl iron : fo that if too great heat is applied to a cop- per vefTjl, it may be eafily remedied by taking it off the fire ; but in a cafl iron vefTel the heat continues fo long as may fometimes produce dangerous confequences, even after the fire is removed. I)r Black obferves, that for the purpofe of folution, if no particular nor uncommon confequence follow the for fofution. application of the two bodies to each other, and if none of them be very volatile, any glafs or porcelain vefTel that can refifl the adlion of the fubflances will an- fwer the purpofe ; but it often happens that they break out into violent ebullition, which produces fleam ; and here a common vefTel is not fo proper, as we would wifh to have the vapour confined or condenfed. We therefore choofe a clofe vefTel that will bear the heat fuddenly produced by the mixture, or the heat that may be neceflary to promote the action of fuch bodies upon one another. Of this kind is the phuda chemica, or matrafs, in which the vapours will have time to cir- culate and to be condenfed again, without being allowed to efcape. Where the matter is in fmall quantity, fmaller vtfTels fom.ewhat of the fame form are ufed, as Florentine flalks, which bear fudden changes of heat and cold remarkably well, on account of their thin- nefs. In order to promote thfe aftlon of bodies, ic is fotnetimes necefTdry to make the Huidii boil^ and for Vol. IV. Part II. .^65 Dr Black's tlirt clions 566 PelkJin. Fig. 6. I S T R Y. this purpofe we mufl have a matrafs with a large neck. Chemical or apply another vefTel to it that will receive thefe Op^ations. fleams, and give them Hill more room for their conden- ^ fation, and diredl them to fall back again, when con- denfed, into the matrafs. This is called circulation. Mac- quer defcribes another vefTel called the pelican, which has been made ufe of for this purpofe ; but it is hard- ly ever employed, on account of its being fo trouble- fome to procure and manage it ; and the advantages arifing from it may be obtained by a more fimple ap- paratus. To this head we mufl refer Papin's digefler, which Papfn's di, is reprefented Fig. 4. It is generally made of cop-gefcer. per, very thick and flrong, open at the top, with , a lid fitted to it, which applies very exaftly. There ai-e ufually two projeftlons on the fide, defigned to make the lid go in a particular manner, but they are unnecefTary. There are other two, to which are fitted the two fides of a crofs bar BB ; in which crofs bar there is a flrong fcrew D, by which the lid can be pi-efTed down very ftrongly. Its ufe is to force wa- ter to bear a flronger heat than it can do under the ordinary prefTure of the atmofphere. It is fometimes furnifhed with an apparatus for letting out the fleam, left it fhould be in danger of burfting the vefTel. A pipe is pafTed through the lid which is fitted with a valve, on which pafTes a lever at a very fmall diftance from its centre of motion ; and this can be made to prefs on the valve with different weights, according to the diftance of thefe weights from the centre. In one conftruded by Dr Black, there was another pipe below, into which a thermometer could be introduced, in order . to mea- fure the degree of heat to which the fteam was raifed. This machine was pretty much employed fome time ago, and its effeds were much admired ; but we find that noft things which can be difTolved in this way, can likewife be difTolved in the ordinary way by boil- ing water, provided it is continued for a longer time, as animal bones, from which the gelatinous parts are indeed extrafted very quickly by this vefTel ; but the fame change is produced by boiling them in watei for a long time in the ordinary degree of heat. II. Filtration. This operation is generally the attendant of folution : very few fubftances, of the faline kind efpecially, are capable of being difTolved without leaving fome impurities, from which they muft be freed ; and the doing of this, fo as to render the folu- tion perfeftly tranfparent, is what is underftood by the word jiltration. For purpofes merely experimental, a glafs funnel and piece of paper are generally fufiiclent. The pa- per Is formed into a conical cap, which being placed iu the funnel with its point downwards, the funnel is then placed in the mouth of a vial ; and the folution or other liquor to be filtered is poured into the paper cap, through which the liquor palTes tranfparent, leaving its impurities on the paper. F'or the purpofe of filtration, paper has come into fuch general ufe, that a particular kind of it is prepared under the name of filtering paper, Tnis is of a reddifh colour; but Dr Lewis prefers the whitirii grey paper which comes from Holland about the pill boxes, as not giving any colour to the folutions which pafs through it. This operation, though apparently fo fi.iiple and 3 K eafy, 568 Filtration. 442 G H E M I CfiemTcal eafy, \s nevertKelefs attended with very troublefome Opera tions, circumftances, on account of the great time it takes Even where very fmall quantities of liquor are to be filtered, merely for experiment's fake, the innpuri- ties frequently fettle on the paper fo foon, and obltnift its pores to fuch a degree, that the operator is often quite wearied out : often, too, the paper breaks ; and thus the whole is fpoiled, and the operation mull be begun over again. To avoid thefe inconveniences, another method of filtration hath been propofed ; namely, to ufe a num- ber of cotton threads, the ends of which are to be im- merfed in the liquor, and the other ends are to hang over the fide of the velfel which contains it, and to hang lower than the furface of the liqour. By this means they will adl as fo many capillary fyphons, (lee Syphon) ; the liquor will arife in them quite pure, and be difcharged from their lower extremities into a v^fTcl placed to received it. That the liquor may flow free- ly into the cotton, it will be proper to wet the threads before they are ufed. In point of efficacy, no doubt, this method excels every other ; and where the operator has abundance of time and patience, may be proper for experiments ; but, in the way of trade, fuch a contrivance is evi- dently ufelefs. For filtering large quantities of liquor, therefore, recourfe has been had to large funnels ; earthen cullenders, or bafons full of holes in the bot- tom, lined with filtering paper; and to conical bags of flannel or canvas. The inconveniences attending funnels, when ufed only in the way of experiment, are much greater when they are employed for filteriiig large quantities of liquor ; and therefore they are generally laid afide. The earthen cullenders, too, do not anfwer any good purpofe; nor indeed does filtration through paper in general fuccced well. The conical flannel or canvas bags are greatly preferable : but they have this in- convenience, that the preffure cf the liquor is direfted chiefly againft one particular point, or a fmall part of the bottom, and therefore the impurities are forcibly driven into that place ; and thus the operation be- comes infufferably tedious. The beft method of obviating the inconveniences cf filtration feems to be the following. Let a wooden frame of about three feet fquare be made, having four holes, one in each corner, about three quarters of an inch in diameter. This frame is to be fupported by four feet, the ends of which muft proje6\ an inch er two through the holes. Thus the whole may be pccafionally fet up and taken down, fo as to go into very little compafs ; for if the feet are properly pla- ced, each with a little projeftion outwards, there wil^ te no danger of its falling. A fquare piece of can- vas muft alfo be procured, fomewhat lefs than the v.'Ooden frame. On each corner of it there muii be a very ftrong loop, which flips on one of ,thc projefl- ing ends of the feet, fo that the canvas may hang a little flack in the middle of the frame. The liquor to be filtered is now poured into the canvas, and a vef- fel placed underneath to receive it. At firfl: it will pafs through very foul ; but being returned two or three times, will become perfeftly tranfparent, and will continue to run with great velocity, if the filter is kept conftaatly full. A filter of the fize juft now S T R Y. Theory, mentioned will contain ten gallons of liquid ; which is Chemical a very great advantage, as the heat of fuch a quan- Operatioii t. tity of liquor is not foon diflipated, and every folution filters much faller when hot than when allowed to cool. The advantages of a filter of this kind above others arife from the pre Jure of the liquor being more equally diffufed over a large fpace, -by which the impurities are not forced fo llrongly into the cloth as to Hop it up entirely. Yet even here, where large quantities of liquor require filtration, the cloth is apt to be flopped' up fo as to make tlie operation not a httie tedious and difagreeable. It will be proper therefore to have feve-- ral cloths, that one may be applied as foon as another is taken ofl".- To promote the operation of filtration, it is very proper to let the liquors to be filtrated fettle for fome< time ; that fo their grofler feculencies may full to the bottom, and thus there will be the fewer to retard the laft part of the operation. Sometimes, however, thefc feculencies refufe to fettle till after a very long time ; and where this happens to be the cafe, a httle pow- dered quicklime thrown into the boiling liquor remark- ably promotes the feparation. This, however, can only be ufed in certain cafes. ^ In fome cafes, the difcovery of a ready way of HI- Schemes for' tering a large quantity of liquor woul i be a matter of Bltenng great confequence ; as where a town is fupplifed with '^'> counted one of the proceffes in chemiftry, is in reali-tion. ty only a natural one, and which the chemift can only prepare for, leaving the operation entirely in the hand? of nature.— By cryftallization is meant the fepara- tion of a fait from the water in which it has been dif- folved, in tranfparent inaffcs regularly figured, and differently formed, according to the different nature of the fahs. This procefs depends upon the conftitution of the atmofphere more than any other ; and therefore if difficult to be perform.ed, nor does it always fucceed equally well ; neither have there yet been laid down any rules whereby beautiful and regular cryftals ca» with certainty be formed at all times. As the different falts affume very different figures when cryftallized, they are not fubjeft to the fame ge- neral rules in cryftalhzation. Nitre, Glauber's fait, vitriol of iron, and many others, cryftallize beft on having their folutions fet in a cold place after proper evaporation. Sal polychreft, and common fait, require the folution to be kept as hot as the hand can bear it during the time of cryftallizing. Soluble tartar too, 3 K 2 and 444 Chemical Operations 574 IViffilla- ?late Cxxxir C H E M and other dell que fee nt falts, require to be kept warm while this operation is going on; and thete are many fiiline fubllances, fuch as the combinations of calca- reous earths and magnefia with acids, which can fcarce- ly be cryrtalHzed at mU. Mr Beaumc lias difcovered, that when two or more falts art difiblved in the lame quantity of water, when one cryftallizts, the cryllals of that fait will not con- tain the leaft quantity of any of the others ; neither, although the liquor was acid or alkaline, will the cry- ftals for that reafon be either acid or alkaline, but will remain perfectly neutral ; and the acid or alkaline li- quor wliicli adheres to the outfide of the cryftals may be abforbed by merely fpreading them on filtering pa- per. — Hence we are furnifhed with a better method of flioottng falts into large and well formed cryftals than merely by diffolving them in water ; namely, by ad- ding to the folutions, when fet to cryftallize, a certain quantity of acid or alkaline liquor, according to the nature of the falts themfelves. Thcfe additions, how- ever, are not equally proper for all falts ; and it is not yet determined what kinds of falts ought to be cry- ilallized In alkaline, and what In acid liquors. — So- luble tartar and Seignette's fait cryftallize beft when the liquor is alkaline. Sal fcdatlvus, fal Glauberl, and fal polychreft, require an acid If cryftalllzed in the cold ; but fal polychreft forms into very fine and large cryftals when the folution Is alkaline, and kept as hot as the hand can eafily bear. The beft general direftlon that can be given with regard to the regular cryftaUIzation of falts is, that they ought to be fet to ci-yftallize In as large a quan- tity at once as poflible ; and this, as far as we have ob- ferved, without any limit ; for by this means, the cr^r- ftals are formed much larger and better figured than they pofrft)ly can be by any other method hitherto known. — Ac- to the form of the veflels In which falts are to be cryftalllzed, little can be fald with certainty. They are generally flat, and wider at top than at the bottom. The only proper material. In the large way, is lead. VI. Distillation. This is a kind of evaporation; only In fuch a manner, that the part of the liquor eva- porated Is not diflipated In the air, but pi-eferved by making the fttam pafs through a fpiral pipe, which goes through a large veftt'l fuU of cold water, or Into cold glafs receivers. ' This Is one of the moft common chemical opera- tions ; and as there are a variety of fubjefts which re- quire to be diftilled, there is confequently a confider- able variety both In the form of the diftilHng veffels to be ufed on different occafions, and llkewife in the materials of which they are made, as well as the mia- nagenient of the fire during the time of the opera- tion. The moft fimple and eafily performed diftillation is that by the common copper ftill, (fig, 3). It con- fills of two paits ; one called the lody, and the other the head. The body is a cylindrical veifel of cop- per, which is fometlmes tinned over in the In fide ; but where diftillation Is performed without any re- gard to the refiduum, the tinning is ufelefs. 7'he up- per part of the body terminates in a kind of arch, in the middle of which is a circular aperture, about one aalf, or fomething lefs, in diameter, of the breadth of I S T R y. Theory, the whole body. — Into this aperture, a round head, Chemical made likewife of copper, is fitted, fo as to be remove- Oper ations. able at pleafure. In the top, or fometimes in the fide " of the head, is inferted a pewter pipe, which commu- nicates with a fpiral one of the fame metal, that pafTes through a large wooden vefTcl, called the refrigeratory ^ filled with csjld water ; each of its ends projefting a little above and below. The ftill is to be filled two thirds full of the fubilance to be diftilled, the head put on, and the junctures well clofed with a mixture of linlfeed meal and water, or common flour or chalk and water will anfwer the fame purpofe. This mixture is called the luiing, or lute. A fire being kindled un- der the flill, the vapours will arlle ; .and, being con- denfed by the cold water through which the fpiral pipe called the worm paffes, will run in a ftream more or lefs ftrong as the fire is more or lefs hattily urged, and Is catched in a receiver fet underneath. This kind of diftilling veflels is proper for procuring the eflential oils of vegetables, vinous Ipirits from fer- mented liquor, and for the leftification of thefe after they arc once diftilled. Even the acetous acid may be very conveniently diftilled in a copper veflel, pro- vided the worm and all the delcending paits of tlic pipe which communicates v/Ith it be of pewter, other- wife a mifchlevous impregnation of copper would bs communicated to the diftilled vinegar. The reaion of this Is, that copper is not diflcjlYed by vinegar, or in very Imall quantity, when that acid is boiled in it ; but if the metal is expofed to the aftion of the acid when cold, or to its vapours, a confiderable dilfolu- lion takes place. For this reafon, too, the ftill mull be waftied out after the operation while it continues hot, and muft be very carefully freed from the leaft remains of acid, otherwife It will be much corroded. Copper-ftills ought to be of as large a fize as pof- fible : but Dr Lewis very juftly oblerves, that, in com- mon ones, the width of the worm is by no means pro- poitionable to the capacity of the ftill: hence the va- pour which iflues from a large fuiface being violently forced through a fmall tube, meets with fo much re- fiftance as fometimes to blow off the ftlll-head. This inconvenience is ridiculoufly endeavoured to be pre- vented by ftrongly tying or otherwife forcing down the head ; by which means. If the worm fliould hap- pen to be choaked up, a terrible explofion would enlue : for no ligatures, or any other obftacle what- ever, have yet been found ftrong enough to refift the elaftic force of fteam ; and the greater obftacle it has to overcome, the greater would the explofion be. — Dangers of this kind might be totally avoided by ha- ving the worm of a proper degree of widenefs. Sometimes, however, matters are to be diftilled, Mineral a- fuch as mineral acid fpirits, which would corrode anycidshow kind of metalline veflels ; and for thefe only earth, or '^'i^iUcd. the clofeft kind of ftone-ware, can be ufed. Thefe are more eafily condenfed than the fleams of aqueous or vinous liquors, and therefore do not require to be pafled through a pipe of fuch a length as is ufed for condenfing the fteams from the common ftill. In thefe cafes, where a violent heat Is not neceffary, and the diftillation is to be performed in glafs veffels, the re- tort is ufed (fig. 4.) When a fluid is to be put into tin's vefftl, the retort muft be laid upon its back on land, or any other foft malter that will fupport it; with- 57« operations. 577 JLutirii; [or Theory. C H E M Chemical without breaking. A fannel muft alfo be procured with a long ftem, and a litile crooked at the extremi- ty, that the h"quor may pafs at once into the belly of the retort, without touching any part of its neck ; otherwife the quantity which adhered to the neck would pafs into the receiver when the retort was pla- ced in a proper fituation for dilHiling, and foul the produce. When the veflTel is properly filled, vhich ought never to be above two thirds, it is to be fct in a fand bath ; that is, in an iron pot, of a proper thick- nefs, and covered over in the bottom, to the depth of one or two inches, with dry fand. When the re- tort is put in, fo as to ftand on its bottom, the pot is to be tilled up with fand, as far as the neck of the retort, A glafs receiver is then to h: applied, which ought to be as large as poffible, and likewife pretty ftrong ; lor which reafon it will be proper not to let the capacity of it be above what is neceffary to hold ten gallons. In the hinder part of it (liould be drilled a fmall hole, which may be occafionally fliut by a fmall wooden peg. The mouth of the receiver ought to be fo wide as to let the nofe of the retort enter to the middle of it, or very near to it ; for if the vapours are difchargfd very near the luting, they will aft upon it much more llrongly than when at a diilance. It is likewife pro- per to have the neck of the retort as wide as maybe; for this has a very great efFeft in the condenfation, by prefenting a larger furface to the condenfing va- pour. The luting for acid fpirits ought to be very diffe- a£id Ipii its. rent from that ufed in other diftillations; for thefe will penetrate the common lutes fo as to make them liquid and fall down into the receiver. Some have ufed re- torts, the necks of which were ground to the recei- vers with emery ; but thefe are very difficult to be procured, and are expenfive, and confequently have never come into general ufe. Various kinds of lutes have been propofed, but the preference feems due to a mixture of clay and fand. We are not to under- Hand, however, that every kind of clay is fit for this purpofe : It muft only be fuch as is not at all, or very little, affefted by acids; and this quality is only poffef- fed by that kind of which tobacco-pipes is made. Trial ought to be made of this before the diftillation is be- gun, by pouring a little nitrous acid on the clay in- tended to be made ufe of. If a violent effervefcence is raifed, we may be fure that the clay is unfit for the purpofe. Finely powdered alabafter would anfwer extremely well, had It the duftllity of clay. As this kind of lute remains foft for a confiderable time, it ought to be farther fecured by a bit of rag fpread with fome ftrong cement, fuch as quicklime mixed with the white of an egg, isfc. M?.tters, however, ought to be managed In fuch a manner, that the luting may give way, rather than the veffels burft ; which would not only occafion a certain lofs of the materials, but might endanger the perfons who were ftanding by. j.g The iron pots commonly ufed for diftillations by the Jtnlnam a- fand-bath, or bahieum aremx, are commonly made very '.r.a, thick V and are to be fold at large founderies, under the name of Jand-pots. The ftiape of thefe, however, is by no means ehgible : for, as they are of a figure nearly cylindrical, if the retort is of fuch a fize as al- moft to fiU their cavity,, it cannot, be put into them I S T R Y. 445 when full, and often pretty heavy, without greit dan- Chemical ger of touching the fides of the pot ; and in this cafe, Qi'^^'^ tiang. touching and breaking are fynonymous expreffions. It " is much better, therefore, to have them in the figure of a punch-bowl ; and the common caft-iron kettles, which may be had much cheaper than the fand-pota ufually fold, anfwer exti emely well. If the dittilliiig veffel is placed in a pot filled with water, the dlltilla- tion is fald to be performed in a water-bath, or bah newn war'ne. When the matter to be condenfcd is very volatile, a number of open receivers with two necks, called adopters (fig. 7.), may be ufed, with a clofe receiver at the end. Each of thtfe adopters muft be luted with , , 1 1 i- 1 • • 1 Adoptersoj? as much care as when only a iingle receiver is uiade aj^jj^i ^ ufe of. Velfels of a fimilar kind were formerly much ufed by chemifts for particular fublimatlons, under the name of aludcls. Formerly, inftead of retorts, a vefTel called a aicurbif, (fig. 5, and 6.) with a head like the common ftill, called an alembic, were ufed ; but the more fimple figure of the retort gives it greatly the preference. It is but {ddom that veflels of this kind are ufeful, which will be taken notice of when defcribing the particular ope- rations : and if at any time an alembic head ftiould be neceffary, its ufe may be fuperfeded by a crooked glafs tube, which will anfwer the purpofe equally well. Sometim.es a very violent fire is required in diftil- lations by the retort. Here, where it is polTible, glafs or earthen velfels fhould be avoided, and iron pots lub- ftltuted in their ttcad. The hardeft and beft caft iron, however, will at lait melt by a vehement heat ; and therefore there is a neceffity for ufing earthenware, or coated glafs. This laft is better than moft kinds- of earthen ware, as being lefs porous ; for when the veffel is urged by a very Intenfe heat, the glafs mtlts, and forms a kind of femivitreous compound with the infide of the coating, fo that its figure is ftill prefer- ved, and the accidental cracks in the luting arc filled "P* 580 For coating of vefTtls, mixtures of colcothar of vi- Cnatmg of triol, fand, iron filings, blood, chopped hair, \jffc. have glafl'es. been recommended. We cannot help thinking, how- ever, that the fimple mixture of tobacco-pipe clay and fand is preferable to any ©tlier; efpecially if, as Dr Black diredts, that part next the gjafs Is mixed with charcoal duft. The proportions recommended by the Dodlor for luting the joints of veffels, are four parts of fand and one of clay ; but for lining the infides of furnaces, and, , we ftiould think, likewife for coating glafs veffels, he direfts 6 or 7 of fand to i of clay ; that the contrac- tion of the clay in drying may thereby be the more effedually prevented. Befides this, he direfts a mix- ture of three parts of charcoal-duft with one of clay to be put next the furnace itfelf, as being more apt to confine the heat ; but poffibly the firil compolltion might be fufficieut for glaffes. The coating of large glafles muft be a very troublc- fome and tedious operation ; and therefore coated, glafs is never ufed but in experiments. When large diftillations are to be performed in the way of trade,., rtcourfe muft be had either to iron pots, or to earthen- 446 C H E M I S T R Y. Chemical Operations 5Sr Sublima- tion. 58a ■Defligra- Cion. ware. Of the tftofl: proper kinds of earthen ware for refifting violent heats, we fhall take notice under the article Fu/ton. In all diftillatlone by the retort, a confiderable quan- tity of air, or other incondenfible vapour, ia eKtrica- ted ; and to this it is abfoluiely neceffary to give vent, or the veflels would be barR, or the receiver thrown off. For this purpofe, Dr Lewis recommends an open pipe to be inferted at the luting, of iuch an height as will not allow any of the vapour to efcape ; but this we cannot approve of, as by that means a conftant communication is formed between the external atmo- fphere and the matters contained in the retort and receiver, which is at all times to be avoided as much as poflible, and in fome cafes, as the diftlUation of phof- phorus, would be very dangerous. The having a fm all hole drilled in the receiver, which is to be now and then opened, muit anfwer the purpofe much bet- ter, although it takes more attendance ; but if the ope- rator is obliged to leave the vefTels for fome time, it will be convenient either to leave the little hole open, or to contrive it fo that the wooden peg may be pulh- ed out with lefs force than is fufficient to break the lute. VII. Sublimation. This, properly fpeaklng, is only the diftillation of a dry fubftance; and therefore, when volatile matters, fuch as fait of hartfliorn, .are to be fublimed, the operation is performed in a glafs retort fet in a fand bath, and the fait pafTes over into the re- ceiver. The cuG.mbit and alembi -> were formerly much in ufe for; this purpofe ; and a blind head, without any fpout, was^applied. Amuch fimpler apparatus,however, is noW:made ufe of. A globe made of very thin glafs, or an ablu-ng veflel of .tlie fame kind, anfwers the more common purpofes of fublimation. For experiments, Florence ilalks are excellent ; as being both very cheap, , and havmg tht neceCary fliape and thinnefs re* quifite for bearing the heat without cracking. The matter to be fublimed muft not, on almoft any occa- fion, take up more than a third part of the fiibliming veffel. It is to be fet in a fand-bath, that the heat may be more equally applied than it could otherwife be. The heat mull be no greater, or very little, than is neceffary for fublimation, or it will be in danger of flying out at the mouth of the fubliming veffel, or of choaking it up fo as to feurft. The upper part of the velTel, too, muft by no means be kept cool, but flightly covered with fand, that the matter may fettle in a kind of half-melted ftate, and thus form a com- pa£l hard cake, which is the appearance fublimates are expedled to have. Hence this operation re- quires a good deal of caution, and is not very eafily performed. VIII. Deflagration. This operation is always per- formed by means of nitre, except in making the flow- ers of zinc. It requires open veflels of earth or ir^on ; the latter are very apt to be corroded, and the former to imbibe part of the matter. To perform this pro- cefs with fafety, and without lofs, the nitre ought to be mixed with whatever matter is to be deflagrated with it, and throvVn, by little and little into the vefl'el previoufly made red-hot. If much is put in at once, a great deal will be thrown out by the violent commo- tion ; and to perform this operation in clofe velFels is in a manjier impoflible, from the prodigious quantity 5S4 FulioBe Theory. of elaftic vapour genei-ated by tli2 nitre. Care muil al- Chemical fo be taken to remove the whole mixture to fome di- '^i'erationio ftance from the fire, and not to bring back ai y fpark * from the quantity deflagrating, with the fpoon which puts it in ; otherwife the whole would irremediably be confumed at once. . IX. Calc iNATiO!^. This is the fubjedting any mat- QjJ^jjjjj^Jjjj^i ter to a heat fo violent as to dilhpate fome part " of it, without melting what remains. It is often praflifed on metallic fubftances, particularly lead, for obtaining the calx of that metal -called minium, or red. lead. This operation, as indeed ail other chemical ones, is beft performed in large quantities, where a particular furnace is conftru6led on-purpofe, and a fire kept chi •day and night without interruption. The flame is made to play over the furface of the metal, and it is conti- nually ftirred fo as to expofe different parcels of it to the adlion of the heat. X. FusiG>f» This is when a folid body is expofed to fuch a degree of heat as makes it pafs from a folid to a fluid ftate ; and as diifcrent fubllances are poffef- fed of very different degrees of fufibihty, the degrees of melting heat are very various. Befides the true fufion, there are fome kinds of falts which retain fo large a proportion of water in their cryftals, as to become entirely fluid upon being expo- fed to a very fmall degree of heat. This is com- monly called the ewib's «>hftrva- eions. CJiemical moifk ; die, when dried and baked, they will not Operations. fufficiently compaft : hence they ought not to be fo moift as to be capable of being turned on a pot- ter's lathe ; but they mufl be formed in brafs or wood- en moulds. On this fubje£l Dr Lewis hath alfo made feveral obfervations ; the principal of which are, i. Pure clay foftened to a due confillence for being worked, not • only coheres together, but fticks to the hands. In drying, it contra&s I inch or more in 12 ; and hence it is very apt to crack, unlefs it is dried exceeding flow- ly. In burning, it is fubjeft to the fame incoHve- nience, unlefs very flowly and gradually heated. "VVnen thoroughly burnt, if it has efcapedthofe imperfeftions, it proves folid and compafi: ; and fo hard as to ftrike fire with fleel. VelTels made of it are not penetrated by any kind of liquid ; and refill falts and glaffes brought into the thinneft fufion, excepting thofe which b>y degrees corrode and diffolve the earth itfelf, as glafs of lead.; and even this penetrating glafs is refift- cd by it better than by almoft any other earth ; but, in counterbalance to tliefe good qualities, they cannot be heated or cooled, but with fuch precautions as can rarely be compHed with in the way of bufinefs, with- out cracking, or flying in pieces. 2. Clay that has been once expofed to any confider- able degrees of heat, and then po-wdered, has no longer any tenacity. Frefli clay, divided by a due propor- tion of this powder, proves lefs tenacious than by it- felf; not fticking to the hands, though cohering fuf- ficiently together. It Ihrinks lefs in drying, is lefs apt to crack, and lefs fufceptible of injury from alte- rations of heat and cold; but at the fame time is lefs fol d and compact. Confiderable differences are ob- ferved in thefe refpefts ; not only according to the quantity of dividing matter, but according as it is in finer or coarfer powder. 3. Veffels m.ade with a moderate proportion of fine powder, as half the weight of the clay, are compaft and fol d, but Hill very apt to crack, from fudden heat or cold : thofe witli a larger proportion, as twice or thrice the quantity of the clay, are free from that imperfection, but fo friable as to crumble between the fingers. Nor does there appear to be any medium be- tween a difpofition to crack and to crumble ; all the compounds siade of clay and fine powders having the one or the other, or both imperfe£lions. Coarfer powders of the fi/.e of middling fand, form, with an equal weight of clay, compounds fufficiently folid, and mucli lefs apt to crack than the mixtures with fine powders. Two parts of coarfc powder, and one of clay, prove moderately folid, and but little difpofed to crack : a mixture of tliree parts and one, tho' heated and cooled fuddenly, does not crack at all, but fuffers very fluid fubftances to tranfude through it ; folidity, anc refiitance to quick viclffitudes of heat and cold, feeming here alfo to be incompatible. 4. Pure clay, mixed with pure clay that has been burnt, is no otlier than one fimple earth ; and is nei- ther to be melted nor foftened, nor made in any de- gree tra,pfparent with the moft intenfe fire?. 5. Mixtures of clay with gypfeous earths burn whiter than clay alone; in certain proportions, as two parts of clay to three of gypfum, they become, in a No 72. Theory. moderate fire, femi-tranfparent, and in a ftrong one Chemical they melt. Operations. 6. Calcareous earths in fmall proportion bake to- " lerably compact and white ; and added to other com- pofitions, feem to improve their compaftnefs. If the quantity of the calcareous earth nearly equals that of the clay, the mixture melts into a yellow glafs ; if it confiderably exceeds, the produdl acquires the quali- ties of quicklime. 7. Veflcis made from clay and fand, in whatever proportion, do not melt in the ftrongeft fire ; but they fometimes bend or foften, fo as to yield to the tongs. Glalfes in thin fufion penetrate them by dlffolving the fand. If gypfeous or calcareous earths are urged In fiich crucibles with a vehement heat, the veffels and their contents run all Into one mafs. In moderate fires, thefe yeflels prove tolerably compact, and retain moft kinds of falts in fufion : but they arc liable to crack, efpcially when large ; and do not long fuftain melted metals, being buril by their weight. Such are the Hefiian crucibles. 8. Mixtures of clay and black-lead, which fee'ms a fpecies of talc, are not liable to crack from alterna- tions of heat and cold ; but are extremely porous. Hence black-lead crucibles anfwer excellently for the melting of metals, and fl;and repeated fufions ; whilft falts flowing thin, tranfude through them almoft as water through a fieve : fulphureous bodies, as antimo- ny, corrode them. 9. Pure clay, foftened with v/ater, and incruftated on earthen veffels, that have been burnt, does not ad- here to them, or fcales off again upon expofure to the fire ; applied to unburnt veffcls, it adheres and in- corporates. Divided clay unites with them in both ftates. Vitreous matters, melted in veffels of pure clay, adhere fo firmly as not to be feparated ; from veffels of divided clay they may be knocked off by a hammer. 10. The faline fluxes which promote the fufion of clay, befides the common ones of all earths, alkali and borax, are chiefly arfenic fixed by nitre, and the fulible fait of urine; both which have little effeft on the other earths though mixed In a large proportion. Nitre, which readily brings the cryftalline earths Into fufion, and fal mirabile and fandirer, powerful fluxes for the calcareous earths, do not perfectly vitrify with clay. Burnt clay does not dlflfer in thefe refpeds from fuch as has not been burnt; nor In that Angular property of vitrifying with gypfeous or calcareous earths, with- out any faline or metallic addition ; the utmoft vehe- mence of fire feeming to deltroy only its dudttlity, or that power by which It coheres when its pans are moiflened with water. But though it feems impoffible to make perfeft veflTels from mixtures of clay in Its two different ftates, of burnt and unburnt, more Is to be hoped from the mixtures which are employed in making porcelain. Ma- nufaftorles of this kind of ware have been atttmptedjvjofe per- In diff"crent countries, (fee Porcelain) ; and in fomefeft -.tflVls placts the qualities requifite for chemical veffels have''" '•'>,'ed been e'ven to It in aT^ery furprifinff degree. Thecount^"'" ^''""^ J T • rr 1 ui J 1 r 1 porcelain, dc lyiuraguais, a rrench nobleman, and member of the :.:::iJ- iny of fciences, has diftinguiflied himfelf in a very eminent manner by attempts of this kind. The 6 traiiflator Theory. C H E M Chemical tranflator of the chemical diftionary afllires us, that he Operations. j^. fj-Qj^ g gentleman of undoubted veracity, that ' * this nobleman having heated a piece of his porcelain red hot, threw it into cold water, without breaking or 59J cracking it, Mr Rcau- The moil ufeful attempt, however, for the purpofes ^lain chemiftry, feems to be the difcovery by Mr Reau- mur of converting common green glafs into porce- lain. This was publifhed as long ago as the year T 739 ; yet we have fcarce heard of any chemift, no not Dr Lewis himfelf, who has made trial of chemical ve/Tels formed of this fort of porcelain, although the very ufe to which Mr Reaumur thought the prepara- tion could be applicable was that of bringing chemical vefFcls to a degree of perfeftion which could not other- wife dc done. The following is the refult of Mr Reau- mur'fr experiments. Green glafs, furrounded with white earthy matters, as white fand, gypfum, or plafter of Paris, ^c. and expofed to a confiderable heat not ftrong enough to alter its figure, as that of a potter's furnace, acquirco different fhades of blue, and by degrees begins to grow white. On breaking the glafs, the white coat appears to be compofcd of fine, white, gloffy, latin- like fibres, running Iranfverfely, and parallel to one ano- ther ; the glafs in the middle being fcarcely altered. On continuing the cementation, the change proceeds further and further, till at length the white fibrous parts from both fides meet in the middle, and no ap- pearance of glafs remains. By this means, entire vef- fels of glafs may be changed into porcelain. The fubliance into which glafs is thus converted, is «paque, compa£l, internally of great whitenefs, equal to that of the fineft china-ware ; but, externally, of a much duller hue. It is confiderably harder than glafs, much lels fufible in the fire, and fuftains alterations of heat and cold without injury. Veffels of it, cold, bear boiling liquors ; and may be placed on the fire at once, without danger of their cracking. " 1 have put a vef- lel of this porcelain (fays the author) into a forge, furrounded it with coals, and kept vehemently blow- ing for near a quarter of an hour ; I have melted glafs in this veffel, without its having fuffered any in- jury in its figure." If means could be found of giving the outfide a whitenels equal to the internal part, glafs veffels might thus be converted into a valuable kind of porcelain, fuperior to all that have hitherto been made. Chemiftry, fays he, may receive from this difcovery, in its prefent flate, fuch veffels as have been long wanted ; veffels which, with the compaftnefs and impenetrability of glafs, are alfo free from its in- conveniences. The common green glafs bottles yield a porcelain of tolerable beauty; window-glaffcs, and drinking- glaffes, a much inferior one ; while the finer kinds of cryftalline glaffes afforded none at all. With re- gard to the cementing materials, he found white fand and gypfum, or rather a mixture of both, to anfwer beft. Coloured earths generally make the external furface of a deeper or lighter brown colour ; foot and charcoal, of a deep black, the internal part being al- ways white. The account of this kind of porcelain given by Mr experi- Reaumur, induced Dr Lewis, who had alfo obfcived raciits. ^jjg {Vj^g changes on the bottom of glafs-retorts ex- VoL. IV. Part IL 593 . Dr Lewis's I S T R Y. 449 pofed to violent heat in a fand-bath, to make further Chemicil experiments on this matter ; an account of which he ^i^'^''^'^'^'"'*' has publifhed in his Philufophlcal Commerce of Arts, ' The refults of his experiments were, i. Green glafs, cemented with white fand, received no change in a heat below ignition. 2. Tn a low red heat, the change proceeded exceeding ilowly ; and in a flrong red heat, approaching to white, the thickeft pieces of glafs bottles were thoroughly converted in the fpace of three hours. 3. By continued heat, the glafs fuffered the following progieflive changes: firft, its furface became blue, its tranfparency was diminifhed, and a yellowifh hue was obfervable when it was held between the eye and the light. Afterwards it was changed a little way on both fides into a white fubftance, exter- nally flill bluifli ; and, as this change advanced liill further and further within the glafs, the colour of the vitreous part in the middle approached nearer to yel- low : the white coat was of a fine fibrous texture, and the fibres were difpofed nearly parallel to one another, and tranfverfe to the thicknefs of the piece : by de- grees the glafs became white and fibrous throughout, the external bluifhnefs at the fame time going off, and beinfir fucceeded by a dull whitifh or dun colour. By a flill longer continuance in the fire, the fibres were changed gradually from the external to the internal part, and converted into grains ; and the texture was then not unlike that of common porcelain. The grains, at firfl fine and fomewhat gloffy, became by degrees larger and duller ; and at lafl the fubftance of the glafs became porous and friable, like a mafs of white fand flightly cohering. 4. Concerning the qualities of this kind of porcelain, Dr Lewis obfervcs, that, while it remained in the fibrous ftate, it was harder than com- mon glafs, and more able to refift the changes of heat and cold than glafs, or even porcelain ; but, in a mo- derate white heat, was fufible into a fubftance not fi- brous, but vitreous and fmooth, like white enamel : that when its texture had become coarfely granulated, it was now much fofter and unfufible : and laflly, that when fome coarfely granulated unfufible pieces, which, with the continuance of a moderate heat, would have become porous and friable, were fuddenly expofed to an intenle fire, they were rendered remarkably more compaft than before ; the folidlty of fome of them being fuperior to that of any other ware. ^.^^ It feems furprifing that tliis able chemift, who on This fub* other occafions had the improvements of the arts fojeftftill much at heart, did not put fome veffels of this kind *"^P'^'^^^*^' of porcelain to other fevere trials, befides attempting to fufe it by icfelf with a violent fire : for though pieces of it were abfolutely unfufible, we are not fure but they might have been corroded by alkaline falts, acids, calcareous earths, or glafs of lead ; nay, it fhould feem very probable that they would have been fo: in which cafe they would not be much fuperior to the veffels made from earthy materials. When a firft- rate chemift publiflies any thing in an imperfeft ftate, inferior ones are difcouraged from attempting to finifh what he has begun ; and thus, notwithflanding that thefe experiments have been fo long publifhed, no- body has yet attempted to inveftigate the properties of this kind of porcelain, by getting chemical veflels made of it, and trying how they anfwer for crucibles, or retorts. 3 ^ Ali 450 . Chemical Operations, CHEMISTRY. Theory, J95 [596] Stone-ware velTels cor- foded. 597 Wtdge- woi d's ware. 598 Macera- tion, 592 , Levigation, All tliat lias been faid concerning the proper mate- rials for crucibles, mud likewife be applicable to the materials for retorts, which are required to ftand a very violent heat. Mr Reaumur's porcelain bids falreft for anfwering the purpofe of retorts, as well as cru- cibles. The great difadvantage of the common earthen ones, is, that they fufFer a quantity of volatile and penetrating vapours to pafs through them. This is very obfervable in the diftillation of phofphorus ; and though this fubflanee has not hitherto been ufed for any purpiofe in medicine, and very little in the arts, its acid only being fometimes ufed as a flux, if vefltls could be made capable of confining all the fl;eams, and at the fame time bearing the heat necelTary for its di- flillation, phofphorus, perhaps, might be obtained in fuch quantity, as to (how that it is a preparation not altogether ufelefs. V/ith regard to flone-ware veffels, and all thofe in which the compofition of fand or flint enters, we fliall only further obferve, that they will be corroded by fixed alkaline falts, efpeclally of the cauttic kind, in a very moderate heat. Dr Black, having evaporated fome cauftic ley in a fl:one-ware bafon, and then melted the dry fait in the fame vefTel, found it (o corroded, as afterwards to be full of fmall holes ; and he found nothing to refift the aAion of this fait fo well as filver. On the fubjeft of chemical veflels, we have now, however, to add the improved earthen ware of Mr Wedgewood ; in which the propei-ties of compaft- nefs, infufibility, and the power of refitting fudden changes of heat and cold, are faid to be united, fo that it promifes to be a very valuable addition to the chemical apparatus, 11. Maceration, or Digestion. This is the mixing two bodies, generally a folid and a fluid, toge- ther, and then expofing them to a moderate degree of heat for a confiderable length of time, that fo they may have the better opportunity of aAing upon one another. Digeftion is ufually performed in the glafles already mentioned, called matrajfes or bolt-heads; and is done in a fand heat. When any of the fubftances are very volatile, as fpirit of wine ; or when the matter requires to be heated fo confiderably that a quantity of vapour will be raifed, the necks of the bolt-heads ought to be pretty long ; or a tin pipe may be infert- ed, q£ fufficient length to prevent the efcape of any part of the fteam. 12. Levigation. This is the reducing any body to a very fine powder, which fliall feel quite foft be- tween the fingers or when put into the mouth. It is performed by grinding the fubftance upon a flat marble fl;one, with fome water, or by rubbing it in a marble mortar. In the large way, levigation is per- formed by mills drawn by horfes, or driven by water ; fome of them are fo fmall as to be turned by the hand. They confift of two fmooth ftonea, generally of black marble, or fome other ftone equally hard, having fe- veral grooves in each, but made to run in contrary di- reftions to one a-nother when the mill is fet in mo- tion. The m.atter being mixed with water, is put in fey a funnel, which is fixed into a hole in the upper ftone, and turhs along with it. The under militone }ias round it a wooden ledge, whereby the levigating Scatter is confined for fome time, and at length dif- charged» by an opening made for that purpofe, wKen Ciien)ical it has accumulated in a certain quantity. • In this operation, when the matters U) be levigated ' '^ are very hard, they wear off a part of the mortar, or Hones on which they are levigated; fo that a fub- ftance perfeftly hard, and which could not be worn by any attrition, is as great a defideratum for the purpofes of levigation, as one which could not be melted is for thofe of fufion. Dr Lewis propofes the porcelain of Mr Rcamur as an improvement for levi- gating planes, mortars, l^c. becaufe, while in its fi- brous ftate, it is confiderably harder than glafs, and confequently much lefs liable to abrafiun by the hard- er powders. In many cafes levigation is very much accelerated by what is called elutriation. This is the method by which many of the painters colours are prepared of the requifite finenefs; and is performed by mixing*ip.ny fubftance, not totally reduced to the neceflliry degree of finenefs, with a fufficient quantity of water, and ftiiring them well together. The finer parts of the.- powder remain fome time fufpended in the water, while the groffer particles fall to the bottom. The reparation is then eafily made, by pouring off" the wa- ter impregnated with thefe fine parts, and commit- ting the reft to the levigating mill, when it may a- gain be waflied ; and this may be repeated till all the- powder is reduced to the utmoft finenefs. Subftanceii; foluble in water cannot be levigated in this manner. Of Chemical Furnaces. The two general divifions we have already men- tioned of thofe who praftife ehemiftry, namely, thefe who have no other view than mere experiment, and thofe who wifti to profit by it, render very differeni: kinds of furnaces neceffaiy. For the firft, thofe fur- naces are neceffary which are capable of afting upon a fmall quantity of matter, yet fufficient for all the changes which fire can produce, from fimple digeftion to the molt perfeA vitrification. For the others, thofe are to be chofen which can produce the fame changes upon very large quantities of matter,, that as much may be done at once as poflible. To avoid the trouble and expence of a number of Portable furnaces, a portable one hath long been a defideratum furnace, among thofe chemifts who are fond of making expe- riments. One of the beft of thofe, if not the very beft, that hath yet appeared, is that defcribed in Shaw's edition of Boerhaave'a ehemiftry, and repre.- fentedfiff, I, ^'^te This furnace is made of earth ; and, as the work- ' manftiip of a furnace requires none of the neatnefs or elegance which is required in making potters veflels, any perfon may eafily make a furnace of this kind for himfelf, who has time and patience for fo doing. With regard to the raott proper materials, all that we have faid concerning crucibles and retorts muft be appli-, cable to the materials for conftrufting a furnace; only here we need not care fo much for the porofity, or difpofition to crumble, as when crucibles or other dif^ tilhng veffels are to be made. Plate-iron is commonly direfted for the outfide of portable furu iccs ; but vvc cannot help thinking this is a very needlefs expence, feeing the coating which. i4> Theory. C H E M I Chemical it necefiarlly requires on the infide may be fuppofed l-uniacee. harden to fiich a degree as foon to fupport itfelf, ^"""V""-' without any afliftance from the plate-iron. This will be the lefs neceflary, if we confider, that, for the thicknefs of the walls of any furnace where a confide- rable heat is wanted, two or three inches are by no means fufficient. When the infide of a furnace is heated, the walls, if very thin, are foon penetrated by the heat, and great part of it by this means difli- pated in the air. If they are of a fufficient thicknefs, the heat cannot penetrate fo eafdy; and thus the inner part of the furnace preferves the heat of the fuel, and communicates it to the contained velfel. In the con- ftruftion of a portable furnace, therefore, it will be convenient to have all parts of it fix inches thick at leaft. This will alfo give it a fufficient degree of ftrength ; and, as it is formed of feveral different pieces, no inconvenience can follow from the weight of each of them taken feparately. In B'jerhaave's chemiftry, this furnace is reprefent- ed as narrower at the bottom than at the top ; but we cannot fuppofe any good reafon for fuch a form, (ee- ing a cylindrical one muft anfwer every purpofe much better, as allowing a larger quantity of air to pafs through the fuel, and likewife not being fo apt to be overturned as it neceflarily muft be where the upper part is confiderably heavier than the lower. We have, therefore, given a reprefentation of it as of a cylindri- cal form. The furnace confifts of five or more parts. C, re- prefents the dome, or top of the furnace, with a fhort earthen funnel E for transmitting the fmoke. B, B, B, are moveable cylinders of earth, each provided with a door D, D, D. In Boerhaave's chemiftry thefe doors are reprefented as having iron hinges and latchets ; but they may be formed to more advantage of fquare pieces of earth, having two holes in the middle, by which they may be occafionally taken out, by intro- ducing an iron fork. In like manner, the domes and cylinders, in Boerhaave's chemiftry, are reprefented with iron handles ; but they may be almoft as eafily taken off by the cheaper contrivance of having four holes in each, two direftly oppofite to one another, into which two (hort forks may be introduced when the parts are to be feparated. In the lowermoft cylinder is to be placed an iron- grate, a little below the door, for fupporting the fire. In the under part is a fmall hole, big enough for introducing the pipe of a pair of good perpe- tual bellows, when the fire is to be violently excited. Dr Lewis prefers the organ-bellows to any. other kind. When the belbws is ufed, the whole muft ftand upon a clofe cyUnder A, that the air may be confined, and made to pafs through the fueh By having more bellows, the fire may be excited to a moft intenfe degree. In this cafe, the pipe of every one of them muft ent r the cylinder B. Each »of the cylinders fhould have, in its upper part, a round hole, oppofite to its door, for carrying off the fmo ke, by means of a pipe inferted into it, when the furnace is ufed for diftillations by the fand-bath. Each cyhnder ought likewife to have a femicircular cut in the oppofite fides, both above and below, that when the under cut of the upper cylinder is brought -dir-e'^lly above the upper cut of the lower one, a per- 45 X Chemical Furnaces. S T R Y. feA circle may be formed. Thefe are for giving a paffage to the necks of retorts, when diftillation by the retort is to be performed. The holes may be ^ occafionally filled with ftopples made of the fame ma- terials with the body of the furnace. The moft convenient fituation for a furnace of this kind would be under a chimney ; the vent of which might be eafily ftopped up by a broad plate ;«f iron, in which a hole ought to be cut for the reception of the earthen tube of the dome. By this means the ule of a long tube, which at any rate muft be very troublefome, might be eafily avoided, and a very ftrong blaft of air would pafs through the fuel. If It 18 found convenient to place the furnace at fome di- ftance from the chimney, a plate-iron pipe muft be procured to fit the earthen pipe of the dome, and carry the fmoke into the chimney. This pipe will alfo be of ufe, when the furnace is ufed for dii illa- tions by the fand-bath ; it muft then be inierttd into the hole oppofite to the door of any of the cyhnders, and will convey away the fmoke, while the mouth of the cylinder is totally covered with a fand-pot. f>ot For portable furnaces, Dr Lewis greatly rccom-^'' ^'^^''^ ^ mends the large black crucibles, marked n° 60, on|°^jj^^.g,^ account of their refitting a violent heat, and being very eafily cut by a knife or faw, fo that doors, iScc. may be formed in them at pleafure. The bottom of one of thefe large ones being cut out, a grate is to be put into the narrow part of it. For grates, the do6lor recommends caft-iron rings, having each three knobs around them. Thefe knobs go into correfpond- ing cavities of the outer rings, and the knobs of the outermoft reft on the crucible, which is to be indented a little to receive them, that fo the grate may reft: the more firmly, and the furnace not be endangered from the fwelling of the iron by heat. When thi« is to be made ufe of as a melting- furnace, and a vio- lent heat to be excited, another crucible muft be in- verted on that which contains the fuel, which ferves inftead of the dome of the laft mentioned furnace : and as whatever is faid of it muft likewife be applicable to the two crucibles when placed above one another, we need give no farther defcription of the docftor'a portable furnace. (^oz No doubt, the great experience of Dr Lewis in olijeftion chemical matters muft give very confiderable weight [" ^'^^g to any thing he advances ; and the warmth with which he recommends thefe furnaces muft convince us, that he has found them abundantly anfwer the purpofes of experiments. We cannot help thinking, however, that where a very great and lafting heat is to be given, the thinnefs, and even the fornix of thefe crucibles, is fome objeftion to their ufe. It is certain that inch a permanent, or, as the workmen call it, a folid heat, can never be given where the walls of a furnace are thin, as when they are of fufficient thicknefs. They are alfo very apt to bur ft with great heat ; and, for this reafon, Dr Lewis defires his hirnace to be ftrengthened with copper hoops. This difpofition to burft proceeds from the inner parts, which are more intenfely heated than the outer, expanding more than thefe do, and confequently burfting them. Hence the dodlor defires his furnace to be ft;rengthened alfo by putting it within another crucible of a larger fize, and the intermediate fpace to be filled up with a mix- 3 L 2 ture 45^ chemical Furnaces ad 602 Dr Black's furnace fchbed. 6c3 ^ How adap' ted to the various o- jierations t)f chemi- C H E M tare of fifted afhes and water. For mod chemical procefles, where only a fmall degree of heat is requi- fite, thefe furnaces anfwer beyond any thing that has liitherto been attempted. The whole is to be fup- ported by an iron ring with three feet. Dr Black has contrived a furnace in which all thefe "inconveniences are avoided. Two thick iron plates, above and bclov/, are joined by a thinner plate, forming the body of the furnace, which is of an oval foim. The upper part is perforated with two holes; the one, A, pretty large, which is the mouth of the furnace, and whicli is of a circular form ; the other behind it, B, of an oval form, and dciigned for fattening the end of the vent which is fcrewed down upon it. The under- moft thick plate has only one large circular opening G near to the middle, but not altogether fo, being nearer to one fide of the ellipfe than the other, where the round hole in the top is placed; fo that a line paf- fing this circular hole has a little obhquity forwards. The afh-pit HH ishkewifc made of an elliptical form, and a very fmall matter widened ; fo that the bottom of the furnace is received within the elhpfe. A little below, there is a border E that receives the bottom of the furnace; and except the holes of the damping-plate DD, the parts are all clofed by means of foft hite, upon which the body of the furnace is prefTed down ; by whicii means the joining of the two parts, and of all the different pieces, are made quite tight ; for the body, fire-place, afh-pit, vent, and grate, are all fepa- rable from one another. As the furnace comes from the workman, the grate is made to apply to the out- fide of the lower part. It confifts of a ring laid on its edge, and then bars likewife laid on their edges : and from, the outer ring proceed four pieces of iron, by means of which it may be fcrewed down ; fo it is kept out of the cavity of the furnace, and preferved from the extremity of the heat. Thus it lafts much longer, and is indeed hardly liable to any decay ; for by be- ing expofed to the cool air, it is kept fo cool, that it is never hurt by the heat of the fuel. The fides, which are made of plate iron, muft be luted within, to confine the heat, and preferve them from its aftion. To adapt this to the various operations of chenii- ftry, we may obferve, that for a melting furnace it is very convenient ; we need only provide a cover for the opening above, which is made the door ; and which, being immediafely over the grate, is convenient for introducing the fubrtances to be afted upon, and for allowing us to look into the vefTel and take it out. This cover may be a piece of tile, or two bricks ren- dered flat and fquare. Dr Black commonly ufes a kind of lid with a rim containing a quantity of lute ; and to augment the heat, we may increafe the height of the vent. It can be employed in moft operations iln the way of effaying ; and the fituation of the door allows us to fee the fubftances very readily. It does cot admit the introdudlion of the muffle ; but can be employed in all thofe operations where the muffle is made ufe of ; and in Cornwall in England fuch a fur- nace is made ufe of for effaying of metals. To pre- ferve the fubftance from the conta6l of the fuel, they cut off about a third part of the length of a brick, and then put it on one end on the middle of the grate. They choofe their fuel of large pieces, that the air znay have free pafTags through it, and open a little of I S T R Y. Theory. the door, which occafions a ftream of air to flow in ; Chemical and this flrikes upon the fubftance and produces the ^"'■"^•ces- effe making glafs; but with little fuccefs, as the glafs wherein it is an ingredient always proves very brittle and apt to crack of itfelf. If, inftead of the vegetable fixed alkali, the vitriolic Glauber's acid is faturated with the foflile one called the fait of^^"^^- Soda, a kind of neutral fait will be produced, having- veiy different properties from the vitrioiated tartar. This compound is called Glauher\ fait. It diffolves eafily in water, flioots into long and beautiful cryflals,- which contain a large quantity of water, in confe quence of which they undergo the aqueous fufion- when expofed to heat. They are alfo more eafily fu- fible than vitrioiated tartar. — This kind of fait was for- merly much recommended as a purgative, and from its- manifold virtues was intitled by its inventor fal mira-^- bile. It is, however, found to pofTefs no virtue diffe- rent from that of other purgative falts ; and its ufe is, in many places, entirely fuperfeded by a fait prepared from the bittern, or liquor which remains after the cry- .ftallization of fea-falt, which fiiall be afterwards de- fcribed. 653 . II. With volatile alkaU. Take any quantity of vo- Giau'^ci 's latile alkaline fpirit ; that prepared with q^iicJ^i™^ ImmoSlV is preferable to the other, on account of its raifing no effervefcence. Drop into this liquor, contained, in a bottle, diluted oil of vitriolj lhaking the bottle after every addition. The. faturation is known to. be complete by the volatile fmell of the alkali being entirely deftroyed. When this happens, fome more- of the fpirit muft be added, that the alkali may predominate a little, becaufe the excefs will fly off during the evaporation. The liquor, on being fil^ tered and evaporated, will flioot into fine fibrous.- plates like feathers. This falt^ when newly pre- pared, has a fulphureous fmell, and a penetrating pungent tafte. It readily diflblves in water, and in- creafes the coldnefs of the liquor ; on ftandiug for a little time, it begins to feparate from the water, and vege. 1 Praaice. Viti iolic A cid 3i:dits Combina- tions. Projiert'C C H E M vegetate, or arlfe in cMorcfcences up the fides of the glafs. It eafily melts in the fire ; penetrates the com- mon crucibles ; and if fublimed in glafs veffels, which requires a very confiderable heat, it always becomes a- cid, however exadly the faturation was performed. This fait has been dignified with the names of Gku- her''s fea-ei fal ammoniac, o\- philofopMc fal ammoniac, from the high opinion which fome chemiils have entertained of its activity upon metals : but from Mr Pott's expe- riments, it appears, that its effeds have been greatly ex- aggerated. It diffolves or corrodes in fome degree all thofe metals which oil of vitriol difTolvcs, but has no efie£l upon thofe on which that acid does not ad by itfelf. Gold is not touched in the leaft, either by the fait of thefaits.|jj fuilon, or by a folution of it: the fait added to a folution of gold in aqua-regia occafions no precipita- tion or change of colour. On melting the falts with inflammable matters, it forms a fulphureous compound, which diffolves gold in fufion, in the fame manner as compofitions of fulphur and fixed alkaUne fait. Melt- ed with filver, it corrodes it into a white calx, w^hich partially diflblves in water : it likewife precipitates fil- ver from its folution iu aquafortis. It a£ts more pow'- erfuUy on copper ; elevates a part of the metal in fub- limation, fo as to acquire a bluifh colour on the fur- face ; and renders the greateft part of the refiduum fo- luble in water. This folution appears colourlefs, fo that it could not be fuppofed to hold any copper ; but readily difcovers that it abounds wath that metal, by the blue colour it acquires on an addition of volatile alkali, and the green calx which fixed alkalies precipi- tate. In evaporation it becomes green without addi- tion. Iron is corroded by this fait in fufion, and dif- folved by boihng in a folution of it. Zinc diffolves more freely and more plentifully. Lead unites wath it, but does not become foluble in water. Tin is cor- roded, and a part of the calx is foluble in boiling wa- ter. Of regulus of antimony a)fo a fmall portion is made foluble. Alkalies precipitate from the folution a bluiili powder. Calcined bifmuth-ore treated with its equal weight of the fak, partly diffolted in water into a pale red liquor, which became green from heat, in the fame manner as tindtures made from that ore by aqua-regia. The undiflolved part yielded ftill, with frit, a blue giafs. On treating manganefe in the fame manner, aluminous cryftals were obtained : the un- diffolved part of the manganefe gave ilill a violet colour to glafs. III. With Calcareous Earth. This combination may be made by faturating diluted oil of vitriol with chalk in fine powder. The mixture ought to be:made in a glafs; the chalk mull be mixed with a pretty large quantity of water, and the acid drop- ped into it. The glafs mufl be well (haken after every addition, and the mixture ought rather to be over faturated with acid ; becaufe the fuperfluous quantity may afterwards be wafhed off ; the felcnite, as it is called, or gypfum,^ having very little folubility in water. This combination of vitriolic acid with chalk or cal- careous earth, is foimd naturally in fuch plenty, that it is leklomor never made, unlefsfor experiment's fake, ♦r by aceideftt. Mr Pott indeed fays, that he found I S T R Y. 459 «35 fome flight differences between the natural and artifi- Y'trioUc A- cial gypfum, but that the former had all the effential g'^^^'^jf^"* properties of the latter. . ^ , ti .ns. The natural gypfums are found in hard, femitran- y— — ' fparent maffes, commonly called alahajler, or plnjler of Paris. (See Alabaster, Gypsum, and Plaster.) By expofure to a moderate heat, they become opaque, and very friable. If they are now reduced to fine powder, and mixed with water, they may be call in- to moulds of any fliape : they very foon harden with- out fhrinking ; and are the materials whereof the com- mon white images are made. This property belongs likewife to the artificial gypfum, if moderately calcined. Mr Beaume has obferved, that gypfum may be dif- Beiumc'* folved in fome meafure by acids ; but is afterwards fe-obferva- parable by cryflallization in the fame ftate in which it^^""®' was before folution, without retaining any part of the acids. This compound, if long expofcd to a pretty flrong heat, lofes great part of its acid, and is con- verted into quicklime. In glafs veffels it gives over no acid with the moft violent fire. It may be fufed by fuddenly applying a very intenfe heat. With clay it foon melts, as we have obferved when fpeaking of the materials for making crucibles. A. like fufion takes place when pure calcareous earth is mixed with clay ; but gypfum bubbles and fwells much more in fufioa with clay than calcareous earth. From natural gypfum we fee that vitriolated tartar may be made, in a manner fimilar to its preparation from green vitriol. If fixed alkaline fait is boiled with any quantity of gypfum, the earth of the latter will be precipitated, and the acid united with the alkali. If a mild volatile alkali is poured on gypfum contained ia a glafs, and the mixture frequently fhaken, the gyp- fum will in like manner be decompofed, and a philoja- phic fal ammoniac will be formed. With the caulHc vo- latile alkaH, or that made with quicklime, no decora- pofition enfues. 6j7 IV. With Argillaceous Earth. The produce of Alum ol this combination is the aftringent fait called much ufed in dyeing and other arts. It has its ^.^.'^^^''^^^.^^ name from the Latin word alumen, called crTUTr»p(a by the Greeks ; though by thefe words the ancients expreffed a ftalaftitic fubftance containing very little alum, and that entirely enveloped in a vitriolic mat- ter. The alum ufed at prefent was firft difcovered in the oriental parts of the world ; though we know not w^lien, or on what occafion. One of the moft an- whence the cieat alum-works of which we have any account was name of that of Roccho, now Edeffa, a city of Syria : and fromf ckah;m this city was derived the appellation of Roch-alutn; an'^ deiivecfc expreffion fohttle underllood by the generahty, that it has been fuppofed to fignify rock alum. From this, and fame works in the neighbourhood of Conllantinuple, as well as at Phocsa Nova, now Foya Nova, near Smyr- na, the Itahans were fupplied till the middle of the 15th century, when they began to fet up works of a fimilar kind in their own country. The firll Italian /^]^,^f alum-work w-as eftabhfhed about 1459 by Bartholo- works fet mew Perdix, or Pernix, a Genoefe merchant, who had up in Italy, difcovered the proper matiix, or ore of alum, in the ifland of Ifchia. Soon after the fame material was difcovered at Tolfa by John de Caftro, who had vifit- ed the alum manufaftories at Conflantinopie. Ha- 3 M a vin^ CHEMI STRY. 640 In Spain, England, and Swe- den. 641 Its compo- nent parts firft d'fco- VitrioUc A- vlng obferved the ilex'aquilifoUiim to grow in the neigh- ""' bourhood of the Turkifh manufaftories, and finding the fame near Tolfa, he concluded that the materials for alum were to be found there alfo ; and was quickly confirmed in his fufpicions by the taite of the itones in the neighbourhood. Thefe alum-works profpered ex- ceedingly, and their fuccefs was augmented by an edldl of Pope Pius II. prohibiting the ufe of foreign alum. In the i6Lh century an alum manufactory was erec- ted at Alamaron, in the neighbourhood of Carthagena, where it ftill continues. Several others were erefted in Germany ; and in the reign of Queen Ehzabeth one was erefted in England by Thomas Chaloner. The preparation of this fait was aot known in Sweden tiU the I yth century. The component principles of this fait were long un- known ; but at laft Meffrs Boulduc and Geoffroy dif- vered b covered, that it confifted of argillaceous earth fuperfa- Meir. Boul- ^^^^ vitriolic acid. This is confirmed by the due and • experiments of other chemifts. It is found to redden Geoffroy. the tinfture and paper of turnfole ; and ou taking away the fuperabundant acid, it lofes its folubiHty and all Miflake of the other properties of alum. Mr Morveau, indeed, Morveau ^ill not admit of a fuperabundance of acid in alum, which he thinks would neceffarily be feparated by wan. edulcoration and cryftallization ; and he is of opinion with Mr Kirwan, that the turning vegetable juices red is not any unequivocal fign of the prefence of an acid. In the prefent cafe, however, we certainly know that there is a fuperabundance of acid, and that a certain portion of the vitriolic acid adheres to the clay Icfs te- nacioufly than the remainder. If we put a piece of iron into a folution of alum, it will attraft this portion of acid; and the vitriolated clay, when deprived of the infoluble in fuperfluous quantity, will fall down to the bottom in an water. infoluble powder. Alum in its ordinary ftate contains a confiderable quantity of water, and cryftallizes by proper manage- ment into oftohedral and perfectly tranfparent and co- lourlefs cryftals. When expofed to a moderate fire, it melts, bubbles, and fwells up ; being gradually changed into a light, fpongy, white mafs, called burnt alum. This, with the addition of fome vitriolic acid, may be cryftallizcd as before. The principles it con- tains, therefore, are water, vitriohc acid, and argilla- Aj4 ceous earth. The proportions may be afcertained in Bergman's following manner, i. The water and fuperfluous method of vitriolic acid may be diflipated by evaporation, or ra- fmding the ther diilillation ; and the lofs of weight fuftained by and*^ dieir'* ^^^'^ quantity of liquid which comes proper- o'*'^'^ ^"^o receiver, Ihows the quantity of aqueous phlegm and unfaturated acid. 2. By combining this with as much cauftic fixed alkali as is fufficient to fa- turate the acid which comes over, we know its propor- tion to the water ; and by redittilling this new com- pound, we have the water by itfelf. 3. The earth may be obtained by precipitation with an alkali in its cau- ifig the pure ftic Itate, either fixed or volatile : but this part of the earth of procefs is attended with confiderable difficulty ; for the alkalies firft abforb the fuperfluous acid, after which the earth combined to faturation with the acid falls to the bottom, and the digeftion with the alkaline fait muft h^e continued for a very cgnfiderable time before the acid is totally feparated. By analyfing alum in •ithis manner, Mr Bergman determined the principles of ^43 Alum de- prived of its fuper- fluous acid tions. 645 Difficulty in obtain alum. Pradlice. alum to be 38 parts of vitriolic acid, 18 of clay, and Vitriolic A- 44 of water, to 1 00 of the cryltallized fait. ^'^^ ^"'1 »u It has been a quellion among cheraifts, whether the 9'^"''^'"*- earth of alum is to be confidered as a pure clay or not. , j The fait was extradted from common clay by Meffrs 646 Hellot and Geoffroy. The experiment was rc])eated P™po'- with fuccefs by Mr Pott; but he feemed to confider it^/""^j rather as the produftion of a new fubltance during the accor^in >■ operation, than a combination of any principle already fo Mr Btr- exiiting with the vitriohc acid. Margraaf, however, from lome veiy accurate experiments, demonftrated, ^J^rJ'^l that all kinds of clay confiit of two principles mecha- tht, ea,.^^^ of nically mixed; one of which conftantly is the pure alum be a earth of alum. This opinion is efpoufed by Bergman ;r"' e day who concludes, that fince an equal quantity of it may - be extraaed from clay by all the acids, it can only be ComMonert mixed with thefe clays ; for if it v/as generated by the parts of all menilrua during the operation, it muft be procured in '"'""^s 'f -by different quantities, if not of different qualiues alfo, ac- j|^^eaigated cording to the difference of the folvents made ufe of. griaf.*'^' Notwithftanding this, the matter feems to be rendered 649 fomewhat obfcure by an experiment of Dr Lewis. J't^wis's «' Powdered tobacco-pipe clay (%s he) being boiled in t*|^d[n'"^"^' a confiderable quantity of oil of vitriol, and the boiling S^o.y^fhat continued to drynefs, the matter when cold difcovers clay under- very httle tafte, or only a flight acidulous one. Ex-!?"es f me pofed to the air for a fev/ days, the greateft part of it was changed into lanuginous efFiorci'cences tafting vertfd*^imo exadtly like alum. The remainder, treated with frelh earth of oil of vitriol, in the fame manner exhibits the fame*^""^* phenomena till nearly the whole of the clay is convert- ed into an aftringent fait." Plence he concludes, that the clay is in fome degree changed before the alumi- nous fait is produced. Without this fuppofition, in- deed, it is difficult to fee why the fait fliould not be pro- duced immediately by the combination of the two principles. An hundred parts of cryltallized alum re- Solubility quires, according to Mr Bergman, in a mean heat of alum in 141 2 parts of diitilled water, but in a boihng heat ^'^'"'V.''"*^ only 7 5 of the fame parts for its folution. The fpeci- fic gravity of alum, when computed from the increafe of bulk in its folution, is 2.071 when the air-bubbles are abftrafbtd ; but if they are fuffered to remain, it is no more than 1.757. Thefe bubbles confift of aerial acid, but cannot be removed by the air-pump, though they fly off on the apphcation of heat. g^j Theores from which alum is preparedfor fale, accord- Bergman's ing toMr Bergman, are of tvf o kinds ; one containing the account of alum already formed, the other its principles united by ^'^^g^^*^*^^ roafting. What he calls the aluminous fchift, is no-^u^.'' thing but an argillaceous fchift impregnated with a dried 63 a petroleum, from whence the oil is eafily extrafted by Compo- diftiUation ; but .by applying proper menfti ua it difco- "f "he^T^^ vers leveral other ingredients, particulariy an argilla- minous ceous martial fubftance, frequently amounting to |. offthift. the whole; a filiceous matter amounting to^ ; and com- monly alfo a fmall proportion of calcareous earth and magnefia ; the reft being all pyritous. By roafting How rhan- this ore the bituminous part is deftroycd and the py- j;edbyrc.ail- rites decompofed ; on which part of the vitriolic acid'"^* adheres to the iron of the pyrites, and the reft to the pure clay of the fchift, forming green vitriol with the former, and alum with the latter. If any calcareous earth or magnefia are prefent, gypfum and Epfom fah will be produced at the fame time. No fait is obtained by Prac>ice» CHEMISTRY. 461 654 The prc- fence of itrioiicA-by lixiviating this fchlft before calcination, though Mr cid and us gergman thinks nothing more Is neceffary for theprcxiuc- tion of the fait but the prefenceof a pyrites. This, he tells us, is generally difperfed through the mafs in form of very miauie particles, though it fometimes appears in fmail nuclei. The goodncfs of the ore, therefore, depends on the proper proportion of the pyrites to the necefSry" ''clay, and its equal diftribution through the wiiole. The for the pro- moil denfe and ponderous is moft efteemed, while that dutStion of which contains fo much pyrites as to be vihble Is rc- aium. je6lcd as having too much iron. The ore which pro- duces lefs than four pounds of alum from 100 of the ore does not pay the expence ot manufafturing in Swe- den. Sometimes this kind of ore produces lalts with- out the application of fire ; but this muft be attributed ^55 to a kind of fpontaneous calcination. Ores con- That fpecies of ore which contains the principles alum ready already united mto alum, accordmg to Mr cergman, is formed, on- to be met with only In volcanic countries ; and of this ly to be met j5_Jn(j tlje principal Italian ores of alum, particu- Vfuh hi vol- ^^^^ employed at Tolfa near CIncelles, for boilir.t^ came coun- , •' r, < \t -mt 1 .^..'^ tiies Koman aium. Mr Monnet, however, is or opinion, that even this ore does not contain alum perfeftly formed, but a combination of nearly equal parts of clay and fulphur, which, by expofure to air during calcination, is conveited into alum. He found a little 6s6 martial earth alfo contained in it, to which he afcribes Aliinmious ^'^^ reddlih colour of that alum. The aluminous ore oieat o- Solfatara In Italy confills of old lava whitened by the phlogifticated vitriolic acid. The clay thus be- comes a component part of the aluminous fait, and the mafs efilorefces In the fame manner, and for the fame reafon, as the mafs left after boiling tobacco-pipe clay in oil of vitriol mentioned by Dr Lev/is. Mr Berg- man, who examined this ore, found, that 100 pounds of it contained eight of puie alum, befides four of pure clay ; and that the remainder was filiceous. I'his pro- poition, however, muft be very variable, according to the quantity of rain which falls upon the ore^ A variety of aluminous ores are to be met with in differsnt parts of the world. In Haflia and Bohemia fatara in Italy. f>S7 Analyzed by Mr Bergman. 658 Aluminous ores in Hallia, Bo heniia, and this fait Is obtained from wood impregnated with bitu- Scania. men. At Hclfingborg in Scania, a turf is found con- fifting of the roots of vegetables mixed with nuts, draw, and leaves, often covered with a thin pyrltous cuticle, which, when elixated, yields alum : Even the fulphu- reous pyrites is generally mixed with an argillaceous matter, which may be feparated by menllrua. In fome places, fulphur, vitriol, and alum are extraftcd from the fame material. The fulphur rifes by diftilla- tion ; the refiduum is expofed to the air till it efflo- refces, after which a green vitriol is obtained by lixl- AlunUlate elation, and alum from the fame liquor, after no more found at vitriol will cryllallize. The alum Jlate, from which this fait is made near York in England, contains a confi- derable quantity of fulphur j and therefore produces alum on the principles already mentioned. Mr Bergman has given very particular dirtftions for the pre- for the preparation of this fait from its ores, and mi- paration of nutely dcfcrlbes the feveral operations which they muft "'"■^'^^ undergo. Thefe are, ^Tfg of K-OA STING. This is abfolutely neceflary in order roafling the to deftroy the pyrites ; for on this the formation of the ore. alum entirely depends ; as the fulphur of the pyrites v.'IU not jiart with its phlogifton without a burning 2 (>S9 Alum ful- phur and vitriol ex tra thus the heap muft be perpetually increafing. ' The haid ores containing bitumen, fuch as thofe of •M^h^A r"^*^^^^' burned upon wood for fome" hours like Inirning the''''^^^""^' ""'^''^ ^^^^ become pervious to water, and hard ores efflorefce. The fire is extinguiflied as foon as the at Tolfii in flame becomes white, and the fmell of fulphure- ^'^^^y- om acid begins to be perceived. When the ore '^cools, thofe patticles which were nearefl to the fire are placed outermolt, and thofe which had been outer- moft widiin, the fire being again lighted. The ore is fufficiently burned when it can be broken with the hands.. It is then heaped up near certain trenches, and uateted five times a-day, particularly when the fun fliines clear ; the operation being deftroyed by a continued rain and cloudy fty. In fome places the ore is firft burned and afterwards elixated ; neither is there any way of knowing the proper methods of ma- naginir it but by experiment. ^ ^ 2. Elixation. This is performed in fome places with burnecfore^'^"^' ^"'^ others with cold, water. At Garphyttan atGarphyt-'fi Sweden, where the latter method is choien, the rc- -tan v/ith ceptacles, in the year 1 772, were of hewn (lone, having ■«ald water, their joints united by fome cement capable of refifting the liquor. Every fet confifted of four fquare recep- tacles difpofed round a fifth, which was deeper than the reft. The firft receptacle is filled with roafted fchift, and the ore lies in water for 24 hours ; the wa- ter is then drawn off by a pipe into the fifth; from thence into the fecond^ containing fchift not yet wafted; from that, in like manner, after 24 hours, through the fifth into the third, and fo into the fourth. The lixi- vium is then conveyed to the fifth, and allowed to ftand in it ; and laftly, is drawn ofF.into a vefl'cl appro- nther me- priated for its reception. — In other places the water thods. pafles over the fchift that has been waftied three times ^"^^ for fix hours; then that which has been twice wafhed, circum- ^^^^ what has been once waflied, and laftly, the ore fiance by which has been newly roafted. Thofe who fuperintend which the the alum man ufaftories are of opinion that the alum be'dcfko^ is deftroyed by paffing the water firft over the newly ^' burnt ore, and then over that which has been previouf- 673 ly elixated. Of the ro- The lixivium, before boiling, ought to be as richly P^'jj^ J. .'• impregnated with alum as poflible, in order to fave viumbefore though this is frequently negleded. In fome boiling. places the tafte is ufed as the only criterion ; but in others the weight of water which fills a fmall glafs bottle is divided into 64 equal parts, each of which is called in Sweden a panning ; and the quantity by which the fame bottle, full of lixivium, exceeds it when filled with water, is fuppofed to indicate the quantity of fait diflblved. — This method may undoubtedly be reckoned fufBciently accurate for work conducted on a large fcale : and though Mr Bergman gives formula by which the m.atter may be determined to a fcrupu- lous exadlnefs, it does not appear that fuch accuracy is either neceffary or indeed prafticable in works con- 4u£ted in a great way. Thofe who manage the alum manufaftories aflert, that the cold lixivium ought to be made no richer than when the weight of the bottle filled with lixivium .exceeds it when filled with water by 4! pannings, I S T R Y. Praaice which /hows "the water to be loaded with i-*t of its Y»»'iolic A weigrht of alum. If the overplus amounts to fix pan- nmgs, which indicates its containing -^ -^ or lalt, cry- ^-^^.^^^ ftalo are then depofited. — Congelation is of no ufe t to concentrate the aluminous lixivium ; for water faturated with alum freezes almoft as readily as pure water. 674 3. Boiling the ley for chrystallization. The Conftruc- ley being firft brought from the pits through canals made for the purpofe, is put into a leaden boiler, at the back ^^^j^j''*'' '*^ of which is a refervoir, out of which the lofs fuftained by evaporation is conftantly fupplied, fo that the furface of that in the boiler continues always nearly at the fame height. Various figns are ufed by diff"erent manufac- turers to know when the ley is properly evaporated t fome determining the matter by the floating of a new laid egg ; others by dropping a fmall quantity on a plate, and obferving whether it cryftallizes on cooling ; and laftly, others weigh the lixivium in the bottle f,j^ above-mentioned. The boiling is fuppofed to be fi- Proper niftied if the increafe of weight be equal to 20 pan- nings ; that is, if the water be loaded with -rrs^ rntedlL^' its own weight. It might, however, take up above -j-quor. of its weight, or nearly 27 pannings ; but as it has to be depurated by ftanding quiet before the cryftals are formed, the liquor muft not be fully faturated with fait. The lixivium, when fufficiently concentrated by Of the firft evaporation, flows through proper channels into coolers, cfy^^-^Uiaa- where it is allowed to reft foi about an hour to free it ' ■ from the grofler fediment ; after which it is put into wooden or fiione receptacles to cryftallize. In eight or ten days the remaining liquor, commonly called ?nother ley, or mag'ijlral ivater, is let off into another vef- fel. A great number of cryftals, generally fmall and impure, adhere to the bottom and fides of the veffel, which are afterwards coUedled and waftied in cold water. ^ _ When a fufBcIent quantity of the fmall cryftals are Depuraticn collefted, they m.uft then be put into the boiler for de- "f the cry- puration. They are now diflblved in as fmall a quan-^^^* tity of water as poflible ; after which the hxivium is poured into a great tub containing as much as the boiler itfelf. In 16 or 18 days the hoops of the tub are loofed, and the aluminous mafs boind with an iron ring ; and in 28 days more the refiduum of the folation is let out through a hole, and coUefted in a trench ; after which the faline~ mafs, which at Gar- phyttan in Sweden amounts to 26 tons, is dried and fold as depurated alum. The boiler emptied for the firft cryftsllization is next filled two-thirds full with the magiftral lixivium ; and as foon as the liquor arrives at the boiling point, the other third is filled with crude lixivium, with which the evaporation is alfo conftantly fupplied. A certain quantity of the aluminous im- purities left by waftiing the falls of the firft cryflalliza- tion in water is then added, and the above defcribed procefs repeated. Only the firft boiling in the fpring is performed with the crude lixivium alone, the reft are all done as juft now related. — Mr Bergman re- Bergman's marks, that the time required for cryftallization may remarks in undoubtedly be fhortened. The refervoirs ufed in the proper Sweden for this purpofe (he fays), are deep, and n^*"' coo^rs^ row at the top ; on which account they are not only long Praaice. C H E M ITitiiolic A- long In cooling, but the evaporation, which is abfo- id and its lutely neceflary for the cryftallization, goes on very i^^,K,,,._ flovvly, excepting in extremely warm weather, at the fame time that the doors and windows are difpofed in fuch a manner as to direft a current of air along the fnrface. In Italy he tells us that conical refervoirs are ufed with the wide part uppermoft. It is remarkable, that pure alum cannot be obtained in very confiderable quantity by merely evaporating I S T R Y. 4^3 ^ombina- ions. 679 ^lum can- aotbeform ^dbymere-^^j ^^^jjj^g Igy^ The reafon of this is, that the and 'lixivium fometimes acquires fuch a confiftence, that it ly evarora- ley Cou the t xcefs »f add. 680 all by pure clay. ooliiigthe both cryftallizes with difficulty, and produces 'im on ac- pm-g cryftals. The caufe was unknown till the time ""^.f-r. of Mr Bergman, who has (hown that it proceeds from an excefs of vitriolic acid. Hence alfo we may fee the reafon why alkaline falts, volatile alkali in its pure ftate, or even putrefied urine, when added to this thick folution, produce good cryftals of alum when This excefs they cannot be obtained otherwife,_ It is remarkable cannot be that this impediment to cryftallization is not re- removed by j^oyeti by mineral alkali, though it is fo by the ve- SiThoJ'^h getable and volatile alkalies, which is a phenomenon it maybe by hitherto unexplained. According to our author, how- ve^etahl'e ever, an addition of pure clay, to abforb the fuper- and volatile abundant acid, is preferable to any other ; and indeed ^"'/J"' it is reafonable to think fo, as the union of vitriolic and belt ot ^^.^ ^^^^^ ^^^^^ ^^j^. jj^fi^ed, which is not the cafe with any of the alkalies. — To afcertain this, he made the following experiments. Experiment ^' He dlffolved 2 15 grains of pure altim in diftilled fliowint^"^ water, in a fmall cucurbit, and evaporated it over the that an ex- fire till the furface of the liquor ftood at two marks^ ceftofvi- ^,i,;ch Indicated,, in a former evaporation, that it was imide^.'^thefit cryftallization, 2. Having poured out this into ciyftalliza- a proper glafs vefl'el, he dilTolved^ other 215 grains, don of a- and added to the folution 24I grains of concentrated lum. vitriolic acid. 3. This folution being likewife poured out, the experiment was repeated a third time, with the addition of 53 grains of vitriolic acid; and the glaffes being at laft fet in a proper place for cryftal- lization, the firft yielded 155-^-, the fecond 130, and the 68^ third loo^- grains of alum. Expe:i-ment This fhows that an excefs of vitriolic acid impedes to deter- cryftallization of the alum ; but to determine how "r'rV'^r far this could be remedied by the addition of clay, far- of adding ther experiments were neceffary. Haying thereiore clay to the employed a magiftral refiduum, in which the excefs ^•^y- of acid was nearly in the proportion already related, he added two drachms of clay in fine powder to- a kanne, or Swedifli cantharus, of the liqnor : he boil- ed the mixture for ten minutes; and on feparating the clay that rems(ined, he found that 294- grains were diffolved, which indicates an increafe of 141 grains of alum. On gently boiling the liquor for half an hour, 75 grains of the clay were diffolved, which indicated an increafe of 416 grains of alum. Advantages The addition of clay muft therefore be much pre- t-f ufingclay ferable to that of alkaline falts, not only as the former rather thanp^Qjy(,gg ^ confiderable increafe of alum, but alfo as alkalies. there is no danger of adding too much j for we have already ftiown, that when the Hquor is entirely de- prived of its fuperabundant acid, the neutralized clay is infoluble in water. The earth itfelf, however, dif- folves . fo flowly, that there is not the leaft danger of the acid belnfr overfaturated by fimplT boiling them Vitriolic A- , ° ' cid and its together. ^ j ' Combina- AUun, as commonly made, though depurated by a tjon,., fecond cryftalHzation, yet is almoft always found con- ' r--^ taminated by deplilogifticated vitriol ; whence it grov/s 684 yellow, and depofits an ochre in folution when old. Alum gen»> This is equally ufeful in fome arts with the purett kind, i,y and is even fo in dyeing where dark colours are re- dephlogiiti- quired ; but where the more lively colours are wanted, cated vi- every thing vitriolic muft be avoided. This is done trio!, by the addition of pure clay, which precipitates the ^j^.^ ^^^^.^^ iron, and produces an alum entirely void of any no- j-g^^g^ji^.^ xious or heterogeneous matter. Nor is this contrary by the ad- to the law^s of chemical attraftion ; for though iron Is diti"" diflblved by a folution of alum, and the earthy bafe of P'^'"'= alum precipitated, and though in a folution- of vitriol and alum the white earth falls firft on an addition oC alkali, and then the ochre; this happens Only in confe- quence of employing phlogifticated ar metallic iron, or- fuch as Is but very little dephlogiftlcated-; for if the- inflammable principle be any further diminlftied, the attraftlon is thereby fo much weakened, that the clay has a greater attraftlon for the vitriolic acid than' the' iron. The truth of this may be proved in many different v;ays. Thus, let a portion of alum be dif- folved in a folution of highly dephloglftlcated vitriol, , and an alkali then added, the ochre of the vitriol will . be firft depofited, and then the clay: and provided there be a fufficient quantity of the latter, the iron will all be precipitated ; and hence we fee that an alu- minous folution mixed only with- one of dephloglftl- cated vitriol may readily be freed from It. 686 But a folution of alum containing perfeft vi- Perfed vj-. triol cannot be freed from it effeftually either by I^J^j^^'^^fy'^J' clay or alkali ; for the former effedls no decompo- ^.^j i^y ^i^j^ fition, and the latter, although it can deftroy the vi- triol, will undoubtedly decompofe the alum In the firft place. As long, therefore, as the folution is rich- in alum, it may be- employed in the common manner ; but when the vitriolic fait begins to predominate, it muft either be cryftallized in its proper form, or be deftroyed in fuch a manner as to produce alum, which maybe accomplifhed in the following manner. Let How the the lixivium be reduced to a tenacious mafs with clay, phlogifton and formed into cakes, which muft be expofed In ^" houfe to the open air. Thus the phlogifton, which ^^.^^^^ ^.j^^ is powerfully attracted by the dephlogilllcatcd part of vitriol, the atmofphere, by degrees feparates. from the Irouj while the clay Is taken up by Its fuperlor attraftion for the acid» The calcination Is accelerated by fire; but It muft he cautioully employed, left the acid Ihould be expelled. ^gg . In the alum manufaftorles in Sv?eden, a confide^ jrpfom fait - rable quantity of vltriolated magnefia, or Epfom fait, may be is mixed with the alum. Mr Bergman direfts this to l"'^*^"'^^^ be feparated by means of an uncalcined calcareous f. 11-1 -ij/i i-i-t_ 1 1- mother earth, which entirely deltroys both the alum and vi.- quor. triol ; falling down to the bottom with the acid in form of a felenitic matter. This muft be added to the boiling liquor gradually, left the effervefcence ftiould caufe the mafs to fw^ell and run. over the top of the veftel. A juft proportion deftroys both the alurai- - nous and vitriolic fait, 'on being properly agitated and Keatcd j neither is there any danger of the Epfom CHEMISTR Y. 689 SupeiHu- ous acid mijjht be advantage- ©wfly dif- tilled. Ejfotn fait, fait being decomposed in this proceis, the iincalcined earth being unable to feparate the mag^efia from the acid. Were this method follow ed in the Swedifh ma- nufaftories, he is of opinion, that as much Epfom fait might be produced from them as would fupply the confumpt of that kingdom. With regard to the quantit)- of fuperfluous acid found in the magiitral lixivium, Mr Bergman informs us, that it amounted to five ounces in one kanne ; fo that in a fingle boiler there is nearly 2501b. But vi- triol, when well dcpl)logifl:icated, retains its acid fo loofely that it may be eafily fcparated by fire. He has ho doubt, therefore, that if the furface of fuch a lixi- vium were firfl increafed in order to let the phlogifton evaporate, the liquor might afterwards be advanta- geoufly committed to dillillation for the fake of its acid. From what has been above delivered, the neceflity will be fufficiently apparent of not continuing the codtion even with pure clay to perfed fatufation of the liquor: and this is further confirmed by M. Beaume, who relates, that having boiled four ounces of earth of alum with two ounces of the fait, in a fuf- ficient quantity of water, the acid became faturated to fuch a degree with earth, that the liquor loft its alu- minous tafte entirely, and alTumed that of hard fpring water. After filtration and evaporation, only a few micaceous cryftals, very difficult of folution, were fonri'^ ed by letting the liquor ftand for fome months, ^- Dr Sieffert informs us, that by boiling half an ounce of alum with half a drachm of flaked lime, cubical cryftals of alum may be obtained. V. With Magnejia. The earthy fubftance called i7ia^- nefia alba is never found by itfelf, and confequently this combination cannot originally take place by art. The vitriolic acid, however, is found combined with magne- fia in great plenty in thebitter hquor which remains af- ter thexryftalhzation of common fait; from whence the magnefia is procured by precipitating with a fixed alkali. If this liquor, which, when the common fait is extrac- ted, appears like clean oil of vitriol, is fet by for fome time in a leaden veffel, a large quantity of fait (hoots, very much refcmbling Glauber's fal mirabile. This fait is in many places fold inftead of the true Glauber's fait ; and is preferred to it, becaufe the true fal mi- rabile calcines in dry air, which the fpurious kind does not. If after the firft crj'ftallization of the bittern, ihe remainder is gently evaporated farther, a frefh quantity of Glauber's fait will ihoot ; and if the liquor is then haftily evaporated, a fait will ftill be cryftal- lized ; but inftead of large regular cryftals, it will concrete into very fmall ones, having fomething of the appearance of fnow when taken out of the liquid. Thcfe falts are effentially the fame, and are all ufed in medicine as purgatives. The fait ftiot into fmall cryftals is termed Epfom fait, from its being firft pro- duced from the purging waters at Epfom in England. The bittern affording this kind of fait in fuch great plenty, thefe waters were foon neglefted, as they yielded it but very fparingly, and the quantity pre- pared from them was infufficient for the demand. Neumann fays, that having infpiffated 100 quarts of Epfom waterj he fcarce obtained half an ounce of fa- No 72. 69^ Pra^llce. line matter. — According to MrScheele's experiments, Vitriolic A* if a folution of Epfora and common fait be mixed to* ^'^^ "* gether, a double decompofition enfues, and the mix- ture contains Glauber's fait and a combination of mag- '.' ^ .^ y nefia with marine acid. From this lixivium the Glau- ber's fait may be cryftallized in winter, but not in fummer ; a great degree of cold being neceffary for this purpofe. From twelve pounds of Epfom fait and fix of Common fait, Mr Sch'eele obtained, in a tempera- ture three degrees below the freezing point, fix pounds of Glauber fait ; but in a degree of cold confiderably greater, the produce was feven pounds and three quarters. yi. IViih Sihet\ Oil of vitriol boiled on half its With ulvef weight of filver-filings, corrodes them into a faline mafs. This fubftance is not ufed in medicine nor in the arts. The only remarkable property of it is, that it has a very ftrong attraftion for mercury ; coagulating and hard- efiing as much quickfilver as the acid weighed at firtt- If the hard concrete be diluted with frefli acid, it melts eafily in the fire, and does not part with the mercury in the greateft heat that glafs veflels can fu- ftain. The vitriolic acid, by itfelf, ftrongly retains mercury, but *iot near fo much as when combined with filver. ^ Silvef thus corroded by the vitriolic acid, or preci- pitated by it from the nitrous, may in great part be diffolved, by cautioufly applying a very httle water at a time ; and more effectually by boihng in frefh oil of vitriol. VII. With Copper. With this metal the vitriolic acid Coppcl-. cannot be combined, unlefs in its concentrated ftate, and ftrongly heated. If pure oil of vitriol is boiled on copper filings, or fmall pieces of the metal, it diffolvea it into a liquor of a deep blue colour, which eafily cryftallizes. The cryftals are of a beautiful blue co- lour, and are fold under the iiame of blue vitriol or Ro' man 'vitriol. , Where fulphur is found in great plenty, however. Blue vitr-of, Roman vitriol is made by ftratifying thin plates of cop- 5^ow made» per-with fulphur; and upon flowly burning the fulphur, its acid corrodes. the copper. The metal is then to be boiled in water, that the faline part may be diffolved. The operation is to be repeated till all the copper is confumed ; and all the faline liquors are to be evapo- rated together to the cryft;dlizing point. By this method, however, a great part of the acid is loft ; and in Britain, where the fulphur muft be imported, we fhould think the pure acid preferable for thofe who prepare blue vitriol. This fait, on being expofed to the fire, firft turns Phenomena white, then of a yellowilh red colour. On urging it on cUftilla- with a ftrong fire, the acid flowly exhales, and a dark ^^ion. red calx of copper remains. The whole of the vi triolic acid cannot be expelled from copper by heat i as much of it ftill remains as to render a part of the metal folubie in water. After this foluble part has been extracted, a little acid is ftill retained, amounting to about ^ of the calx. Vitriol of copper is employed in medicine as a cau- ftic, in which refpeft it is very ufcful ; but when ufed internally, is dangerous, as indeed all the preparations of copper are found to be. It has, neverthelefs, ac^ cording 695 Ufes. Praclke. G H E M I 696 Iron. Vlnrinlic cording to Neitmann, been recommended in all kinds cS!bTna'^'°^ intermittents, and the lepra. The fmalleft por- tioi.s. ' f^ysj occafions a ficknefs and naufea; a fome- w— y-«w what larger, reaching and violent vomitings, accom- panied often with convulfions. If the quantity taken has been confiderable, and is not foon difcharged by vomiting, the ftomach and inteftines are corroded, in- tenfe pains, inflammations, and death, fucceed. VIII. IVit/j Iron. The vitriolic acid does not aft up- on this metal till confiderably diluted. Common oil of vitriol requires to be mixed with ten or twelve times its quantity of water before it will a£l brilldy on the me- tal. In this ftate it effervefces violently with iron fi- lings, or frnall bits of the metal, and a great quantity of inflammable vapour is difcharged (fee Air). The liquor aflumes a fine green colour ; and by evaporation and flow cooling, very beautiful rhomboidal crvftals Salt of Heel. ^O''"^^'^- Thefe are named fait of Jleel, and are ufed in medicine ; but for the fait made with the pure acid and iron, the common copperas, impure acid extrafted from pyrites, 697 ftituted. vitriolic scid. made v/ith the is commonly fub- This is generally efteemed a venial fraud, and no doubt is fo in medicinal refpecls ; but when it is confidered, that, by this fubftitution, common copperas is impofed on the ignorant, at the price 698 of 2 s. per pound, the affair appears in a different light. Precipifa- Pure- vitriol of iron is originally of a much more ti'in of iron, 1 ^1 1 from the beautitul appearance than common copperas, and re- tains its colour much better ; the reafon of which is, that the fait thus prepared has more phlogifton than the copperas. If either of the kinds, however, are expofed to the air for a fufficient length of time, part of the acid is diffipated, and the vitriol becomes yellowifli or brownirti. If the fait is now diflblved in water, a brown precipitate falls, which is part of the iron in a calcined ftate. If the liquor is feparated from this precipitate by filtration, a fimilar one forms in a ftiort time, and by long ftanding a confiderable quantity fubfides. According to Dr Lewis, the pre- cipitation is greatly expedited by a boiling heat ; by which more of the metal feparates in a few minutes than by fl;anding without heat for a twelvemonth. This change takes place in no other metallic folutions. The calx of iron, precipitated by quicklime from fjoufe paint- gi-een vitriol, appears, when dry, of a yellow colour.; Tfelow for jng. 700 Prefei-va- .(five for wood. 70T Til). a!3d is recommended in the Swedifll tranfaftions, in- fl;ead of yellow ochre, as a colour for houfe-painting. Solutions of green vitriol are alfo recommended for preferving wood, particularly the wheels of carriages, from decay. When all the pieces are fit for being joined together, they are direfted to be boiled in a folution of vitriol for three or four hours ; and" then kept in a warm place for fome days to diy. By this preparation, it is faid, wood becomes fo hard, that moifliure cannot penetrate it ; and that iron nails are not fo apt to rufl; in this vltriolated wood as might be expefted., but laft as long as the wood itfelf. IX. tV'ith Tin. This metal cannot be diflblved in the vitriolic acid, but in the fame manner as filver; namely, by boiling concentrated oil of vitriol to drynefs upon filings of the metal. The faline mafs may then be diflblved in water, and the folution will cryftallize. The falt,-however, formed by this union, is not ap- plied to any ufeful purpofe, A fait of tin, indeed. Vol. IV. Part II. 70a Lead. S T R Y. 465 formed by the union of vitriolic acid with this tnetal, Vitriolic has been recommended for fome medical purpofes, and 1^'^^'^,*"'^ procelles are given for it in the difpeniatones ; but„o„s they have never come much into piaflice. - — _j X. With Lead. While lead is in its metallic ftate, the vitriolic acid adb very little upon It, either in a di- luted or concentrated ftate : but if the metal is dlf- folved in any other acid, and oil of vitriol- added, a precipitation immediately enfues, which is occafioned by the combination of vitriolic acid with the lead. This precipitate will be more or lefs white as the metal is more or lefs deprived of Its phlogifton by 70, calcination before folution. If a little ftrong fpirit of ■• beautiful nitre is poured upon litharge, which is lead calcined to "^^''^ the greateft degree poflible without vitrification, the acid unites itfelf to the metal with confiderable ef- fervefcence and heat. Some water being now poured on, and the phial containing the mixture fliaken, a turbid folution of the litharge is made. If a little oil of vitriol is then added, it throws down a beautifully white precipitate ; and the acid of nitre, being left at liberty to aft upon the remaining part of the litharge, begins anew to diflblve it with effervefcence. When it is again faturated, more oil of vitriol Is to be drop- ped in, and a white precipitate is again thrown down. If any of the litharge is ftill undlflblved, the nitrous acid, being fet at liberty a fecond time, attacks it as at firft ; and by continuing to add oil of vitriol, the whole of the litharge may be converted into a mofl; beautiful and durable white. Unfortunately this co- lour cannot be ufed in oil, though in water it feems fuperior to any. If the procefs is well managed, an ounce of fpirit of nitre may be made to convert feveral pounds of litharge into a white of this kind. Quicufl.. XI. With ^ickflver. The diflbliitlon of quickfilver ver.*^ * in vitriolic acid cannot be performed but by a concen- trated oil and ftrong boiling heat. The metal is firft corroded into a white calx, which may afterwards be eafily diflblved by an addition of freih acid. Every time it is diflblved, the mercury becomes more and more fixed and more difficult to dry. If the exficca- tion and dlflolutlon has been repeated feveral times, the matter becomes at laft fo fixed as to bear a degree of red heat. This combination Is the bafis of a medi- cine formerly of fome repute, under the name of tur- bith mineral. The procefs for m.aking turbilh mineral is given by tlie author of the Chemical DIftionary as follows : " Some mercury is poured into a glafs retort, and Turbit}i upon it an equal quantity of concentrated oil of vitriol, mineral, or more, according to the ftrengtli of the acid. Thefe matters are to be dlftlEed together, "in the heat of a fand-bath, till nothing remains in the retort but a dry faline mafs, which is a combination of the vitriolic acid and mercury. The acid which paffes into the re- ceiver is very fuffbcating and fulphureous ; which qua- lities it receives from the phlogifton of the mercuiy. The white fahne mafs which is left at the bottom of the retort is to be put Into a large veflel ; and upon it are to be poured large quantities of hot water at This water weakens the acid, mercury ; which is then pre ® cipitated towards the bottom of the veflel, in form of a very fhining yellow powder. The water with 3 N wliich feveral different times, and takes it from the 466 vitriolic Acid and it' Combiiia- elons. C H E M I S T R Y, Praaice, which It 19 wafhed contains the acid that was united plicnoracna aUo occur In tliia cafe as In making tur- Viti'iolic with the mercury, and llkewife a little mercury ren- bith mineral; a vc^y fufFocating Tulphurcwis acid rif^js; ^^^'^^^.^^^ dtrtd folable by means of the very large quantity of and, as Mr Geoffroy obferves, a trite fulphur fublimeSti,'','^ acid. i"^^ ^^'^ ncxk of the retort ; a white, faline, tumcii^jd, . Moll diemiils have believed, that a portion of vl- mafs remains in the vefTel ; and wlien the veiTels are 706 Dr Lewis's djr^idions. 707 'Zl'nc. White vi- iricl. triohc acid remains united with the turbith mineral, only too httlc to rendtr it foluble in water. But Mr Beaumc, having fx.:unined -this matter, affirms, that turbith mineral contains no acid, when it has been lufficiently wafhed ; and that, by frequently boihng this preparation In a large quantity of diftilled water, not a vcftige of acid will adhere to It." Dr Lewis, who is of opinion that the whole of this mercurial calx is foluble in a very large quantity of water, defires the water with which it is waflied to be impregnated with fome alkaline fait ; which makes the yield of turbith greater than when pure water is \ifcd. The author of the Chemical DiAionary alfo ohferves, that the precipitate remains white till well freed from the acid ; and the more perfectly it i« wafhed, the deeper yellow colour it acquires. XII. P/id'' Zinc. This fcmimet:d is not a£led upon })V the vitriolic acid in its concentrated ftate; but, when diluted, is diffolved by it with effervefcence, and with the extrication of an inflammable vapour in the fame manner as iron. Neumann obferves, that, during the difiblution, a grey and blackiflr fpongy matter fell to the bottom ; but, on (landing for fome days, was ta- ken up, and dilTolved in the liquor, nothing being left but a little yellowifh dull fcarcely worth mentioning. Six parts of oil of vitriol, diluted with an equal quan- tity of water, diffolves one part of zinc. The produft of this combination is tt'hke vitriol ; which is ufed iu medicine us an ophthalmic, and in painting for making oil-cokairs dry quickly : what is ufed f"or this purpofe, however, is not made in Bri- unlute-d, a while fume ifl'ues, as in the fmoking fpirit of libavius. See CombinatioriJ of marine acid nvith tin. Infra. ^ _ XIV. IVirl:) Reguhs of Cobalt. From a combination ofRegulusof the vitriolic acid with cobalt, a red fait. may be obtained, '^ou'iu., To procure It, one part of cobalt, reduced to a very fine powder, may be mixed with two or three of con- centnited acid, diluting the liquor after it has been digefted for 24 hours, and then hltering aiid evapora- ting it. XV. With. Arfenic. Neumann relates, that powdered ^jf^j^j^.^ white arfenic being dilliiled in a retort with oil of vitriol, a tranfparent fublimate like glafs arofe, wliich in a few days loft its tranfparency, and became opaque like the arfenic itfelf. The arfenic remaining in the retort fuilained an open fire without any fcniible alteration. The author of the Chemical Dictionary fays, that if a concentrated vitriol c acid is dilliiled from arfenic, the acid which comes over fmells exactly like marine acid. When the folution is dilliiled till no more acid rifes, tlie retort is then almoft red-hot, and no arfenic is fub- limed ; but it remains fuffd at the bottom of the re- tort ; and, when cold, is found to be an heavy, com- pa£l mafs, brittle and tranfparent as cryftal-glafs. This kind of arfenical glafs, expofed to the air, foon lofes its tranfparency from the moilture it attracts, which dilfolves and partly dehquiates it. This deliquium is extremely acid. — By digeiling one part of arfenic with two of concentrated oil of vitriol, diluting the folutiori with water, and then filtering and evaporating, we ob- tain a yeIlo\\'ifh fait which Ihoots into pyramidal, tran- to tain, but c^mies from Germany. It is made at Goflar fparent, and fliining cryilals. None of the three lail by the following procefs. An ore containing lead and filver, having been prevloufly roafted for the ob- taining of fulphur (fee Metallurgy), Is Hxivia- ted with water, and afterwards evaporated in leaden boilers, as for the preparation of green vitriol : but mentioned combinations have been found applicabl any ufeful purpofe. XVI. With Oil. The produft of this combination is a thick black fubllance, very much refembling baliam of fulphur in colour and confiftence ; to which it is fome- here a regular cryftallization is prevented; for when times fubftituted. If this fubllance is dilliiled with a ihe fait has aflumed any kiud of cryllalllne form, thefe gentle heat, great part of the acid becomes volatile, cryflals are made to undergo the watery fufion In and evaporates in white fumes, having a pungent Imell copper caldrons. It is then kept conftantly ftirring refembhng that of burning fulphur. This goes by the till a coufiderable part of the moifture is evaporated, and the matter has acquired the confiftence of fine fu- gar. White vitriol gtneral'y contains fome ferrugi- nsus matter," froni which it may be entirely freed by {tmie frefh zinc ; for this femimetal precipitates frpm the vitriolic acid ail other metallic fubftances; but not 7TS.; Oii.. 7'.? Volatile 709 Regulus f; aoiimcny, name o{ volatile or fnlphureous vitriolic acid ; and a f'^h j-^j j^^'^^^.^^ was formerly prepared from it by faturation with fixed yg/j, alkali, which was thought to poflcfs great virtues. From Its inventor it was called the fulpJyureous fait of Stahl. The moft finglar property of this volatile acid is, that though the vitrlohc in Its fixed ftate is capable of withftanding this Itrong attraftion, the vitriohc acid is expelling any other acid from Its bafis, the volatile more eafily expelled by diftillation from white than one is expelled by every acid, even that of vmegar. green or blue vitriol. Towards the end of the dl- It is very difficultly condenfible, as we have already filiation ef white vitriol, the acid arlfes exceedingly taken notice ; and, when mixed with_ water, feems concentrated, though fulphureous : fo that, if mixed fcarcely at all acid, but rather to have a bitterlfli tafte. with common oil of vitriol, It will heat It almoft as Several methods have been propofed for procuring 714 much as oil of vitriol heats water. this acid from burning fulphur, which yields it in its How pro- f XIII. JVith Regulus of Antimony. To combine vitriolic greateft degree of volatility, as well as concentration ; . acid with regulus .of antimony, the fiime method muft be but the produce is fo exceedingly fmall, that none ofj^J,/"' ufed, as direfted for uniting it with quickfilver, for them are worth mentioning.^ Dr Prieftley has given making turbith mineral, vm. to employ a very con- very good direftions for obtaining the volatile vitriolic e<:ntrated acid, and to diftil in tlofe vclh !». The fame acid iu the form of air. His method was, to pour, on lom-t: Charcoal. 7t6 Sul; hur prepared from vitrio luted tarur Spirit of wiue. Ether. C H E M fome oil of vitriol contained in a phial, a very fmall quantity of oil olive ; as much as was fufficient to co- ver it. He then apphed the proper apparatus for the re- ception of air in quickfilver (fee Air) ; _and,_ holding a candle to the phial, the volatile vitriolic acid rufhed out in great quantity. Had he received this air in wa- ter, inllead of quickfilver, the confequence would have been, that fome part of it, at leaft, would have been abforbed by the water, and a fulphureous acid liquor produced. This feems indeed almoft the only method of procuring the fulphureous vitriolic acid of any to- lerable ih-ength ; but it is never required in the form of a liquor, except for experimental purpofes. The only iiftful property hitherto difcovered about this kind of acid is, that it is remarkably dellruAive of colours of all kinds ; and hence the fumes of fulphur are em- ployed to whiten wool, &.c. XVII. With Phhg'tjlnn of charcoal. If charcoal is mix- ed with concentrated vitriolic acid, andthe mixturediftil- led, the fame kind of acid isat firftobtained, whichcomes over ^vhen oil is ufed ; and towards the end, when the matter begins to grow dry, a true fulphur fubhmes. The beft way, however, of producing fulphur from the vitrioHc acid is by combining it, when in a per- feftly dry ftate, with the phlogifton. By this means fulphur may very readily be made at any time. _ The procefs is generally direftcd to be performed in the following manner. Reduce to fine powder any quantity of vitriolated tartar. Mingle it carefully with a i6th part of its weight of charcoal-duft. Put the whole into a covered crucible fet in a melting furnace. Give a heat fuffi- cient to melt the fait ; and when thoroughly melted, pour it out on a flat ttone. The vitriolated tartar and charcoal will now be converted into a fulphureous mafs ■ fimilar to a combination of alkahne falts with fulphur. Sec AlkaTme Salts, below. XVIII. IVith Spirit of nvine. The refult of this combi- nation is one of the moft extraordinary phenomena in chemiftry ; being that fluid, which, for its extreme de- gree of volatility, was firft diRinguilhed by the name of ether : and now, fince a liquor of the Kke kind is dif- Qoyered to. be prepaiable from fpirrt of wine by means of other acids, thisfpecies is diiting'uilhed by the name oivitriolic ether. The method of pieparing this fubtle liquor recommended by M. Beaume, feems to be the beft of any hitherto difcovered. Mix together equal parts by weight, _ of highly rec- tified fpirit of wine and concentiated oil of vitriol, or fomewhat more than two meafures of fpirit of wine with one of the acid. The mixture is to be made in a flint glafs retort, the bottom and fides of which are very thin, that it may not break from the heat which is fuddenly generated by the union of thefe two fubftan- ces. The fpirit of wine is firft put into the retort, and then the acid is poured in by a glafs-funnel, fo that the ftream may be dircfted againft the fide of the glafs ; in which cafe it will not exert much of its force on the fpirit, but will He quietly below at the bottom. The retort is now to be very gently fnaken, that the «icid may mingle with it by little and little. When the mixture is completed, very httle more heat will be neceffary to make the hquor boil. This mixture is to be diftilled with as briflc and Ciuick a heat aspulHbie; for which reafon, immediately 6 I S T R Y. 4^7 after the acid and fpirit are mixed, the retort (hould ^'^V^J^'^j^g be put into a fand furnace heated as much as the mix- [^^^^^^^^J ture Is. The diftillation fliould be continued only till jions. about one third of the liquor is come over ; if it is v— continued farther, part of the vitriolic acid rifes in a fulphureous ftate. In the retort a thick, black, acid matter remains, which is fimilar to a combination of oil of vitriol with any inflammable matter, and from which a little fulphur may be obtained. Along with the fulphureous acid, a greenifii oil, called oleum w- trioli clulcis, arifes, which has a fmell compounded of that of the ether and fulphureous acid : and Mr Beaume has fhown that it is compounded of ihefe two ; for if it is reftifted with an alkali, to attraft the acid, it is changed into ether. If, after the diftillation of the ether, fome water be poured into the retort, the li- quor by diftillation may be brought back to the ftate of a pure vitriolic acid. As the tteams of the ethereal liquor are exceedingly volatile, and at the fame time a quick fire is neceffary to the fuccefs of the operation, the receiver muil be carefully kept cool vith very cold water or with fnow. Care muft alfo be taken to prevent any of the fulphureous acid fteams from coming over ; but as it is impolfible to prevent this totally, the liquor re- quires reftificatlon. This is the more neceffary, as a part of the fpirit of wine always rifes unchanged. From this acid the liquor is eafily fet free, by adding a fmall quantity of alkaline fait, and re-diftllling with a very gentle heat ; but as fpirit of wine is hkewife very volatile, the diftillation mutt be performed^ in a very tall glafs. Dr Black recommends a matrafs, or bolt-head, with a tin-pipe adapted to the head, fo as to convey the fteams at a right angle, to be conden- fed in the receiver. When this fluid is to be prepa- red in great quantities, the ether, by proper manage- ment, may be made to equal half the weight of the fpirit of wine employed. Mr DoUfufs has made many important experiments on this fubjpA ; of vi-hich the following is an abftta<£l : i. Two pounds of vitriolic acid were mixed with as much of fpirit of wine, and the mixture diftilled with a very gentle fire. The firft ten ounctfs- that came over confifted of a liquor ftrong- ly impregnated with ether, and of an agreeable odour. This was put by itfelf and marked A. It was follow- ed by a ftronger ethereal liquor, of which a fmall quan- tity only would mix with water. Of this there were 12 ounces, which were alfo put by themfelves, and marked B. By continuing the procefs two ounces more were obtained, which fmelled of fulphur, and were marked C. The diftillation was now cotitinucd with a view to concentrate the vitriolic acid, when three drachms of a thicker kind of ether were found fwimming on a weak fulphureous acid. This thick liquid was not in the Icall volatile, and in confiftence refembled an expreffed oil. 2. Twenty-four ounces of fpirit of wine were now added to the refiduum of the former diftillation, and the procefs recommenced. The firft feven ounces that came over were poured to the dulcified fpirit marked A. Next pafled over ten oun- ces of a tolerably pure ether, which was mixed with the contents of B ; befides two ounces that had a fulphu- reous fmell, which were mixed with C. By a repeat- ed dcphlegmatlon of what remained in the retort were obtained five ounces of a weak fulphureous acid ; and 3 N 2 the 468 C H E M Ac/'land' ^^^'"g ^''t^ ounces of Combina-^'^P'"'' wine, yielded firft fix ounces of the liquor tions, marked A ; then four ounces of pure ether put into y— »i that marked B ; and after that another ounce marked C. By continuing the diiUlIation four ouaces of weak fulphureous acid were obtained, on which floated a little oil of wine. -5. The remainder, which was very thick, and covered with a flight pellicle, was mixed with 20 ounces of fpirit of wine, and yielded five oun- ces of dulcified fpirit marked A ; efght ounces of pure ether marked B ; and at lafl one ounce of the lame, which had rather a fulphureous fmell. This was fol- lowed by a few drops of acid ; but the remainder fro- thed up with fuch violence, that an end was put to the operation, in order to prevent its pafling over into the receiver. By thefe four diftillations there were obtained from fix pounds of fpirit of wine and two of oil of vitriol, 28 ounces of dulcified fpirit of vitriol and 38 of ether; which lafl;, when reftified by diftillation over mangancfe^ yielded 28 ounces of the belt ether. At the end of this diftillation were produced 13 ounces of weak ace- tous acid ; and the Hquor of the laft running marked C, a{Forded, by t edification, four ounces of good ether. The fulphureous acid liquor yielded four oun- ces of weak acetous acid, and tliree drachmsof naphtha refembling a diftilled oil in confidence. By thefe procefFes the vitriolic acid was rendered quite thick and black ; its weight being reduced to 24 ounces. The blacknefs was found to be owing to a powder which floated in the liquid, and could neither be feparated by fubfiding to the bottom nor rifing ta the top. The liquor was therefore diluted with eight ounces of water, and filtered through powdered glafs ; by which means the black fubfl;ance was colle^aed, partly in powder, and partly in grains of different fizes. It felt very foft between the fingers, and left a flain upon paper like Indian ink ; but though waflied with 24 ounces of water, fl:ill tafted acid. Half an ounce of it diftilled in a retort yielded a drachm and an half of weak acetous mixed with ahttlc fulphureous acid ; the refiduum was a black coal, which by calci- nation in an open fire for a quarter of an hour, yielded 25 grains of white alhes, confifting of felenite, calcare- ous earth, and magnefia. A drachm of it digefted with nitrous acid, which was afterwards diftilled from it, and then diluted with diftilled water and filtered, yielded a few cryftals, which appeared to be genuine fait of tartar, an infoluble feknite being left behind. On reftifying the vitriolic acid freed from the black matter and diluted with eight ounces of water, nine ounces of fulphureous acid were firft obtained, after which followed an ounce of acid rather high-coloured, and then the vitriolic acid qu-ite colourlefs. It now weighed only i ounces, and its fpecific gravity was but 1.723, while that of the acid originally empbyed had been 1.989. On repeating the procefs with fix pounds of fpirit ©f wine to two of oil of vitriol, the firft \2 ounces that came over were fpirit of wine almoft totally un-^ changed ; then two ounces fmelling a little of ether ; and afterwards two pounds, of which about one third were ether. When about five pounds had been drawn off, the diftilling liquor began to fmell fulphureous ; and after nine ounces more had been drawn off, the I S T R Y. Pradlce. frothing up of the matter in the retort obliged him to Vitriolic put an end to the operation. The acid was then ^'^'^ filtered through pounded glafs as before, and after- j,-*™ wards committed to diftillation. The three firft ^ f ounces were a weak fulphureous acid ; then followed, an ounce moi'e concentrated, and of a red colour ; then another of a yellowifh' caft ; after which the reft of the acid came over quite colourlefs.. The whole weighed 27 ounces, and the fpecific gravity of it com- pared with diililled water was as 1.667 to -ooo. Ether is the lighteft of all known fluids, except Propertiet air; and is fo volatile, that In Daaw its boiling point is "f ether, 20" below o' of Fahrenheit's thermometer. If a fmall quantity is poured out on the ground, it inftantly eva- porates, diftufing its fragrance all through the rooni, and fcarce perceptibly moiftening the place on which it fell. It difficultly mixes with water, as being of an oily nature : ten parts of water, however, will take up one part of ether. Its great volatility renders it ferviceable in nervous difeafes, and removing pains, when rubbed, on with the hand, and kept from evapo- rating immediately. By fpontaneous evaporation, it produces a great degree of cold. (See Evaporatiokt and Congelation). The moft extraordinary pro- perty, however, is, that if gold is din"olved in aqua- regia (fee Metallic Sub/lances^ below), and ether add>r ed to the folution, the gold wiil leave the acid and perm.anently unite with the ether. The exceeding great volatility of ether renders it very eafily inflam- mable even on the approach of flame ; and therefore it ought never to be dift;illed, or even poured from one veflel to another, by candle-light. If a lefs quan- tity of the vitriolic acid is added to the fpirit of wine than what is fuiiicient to produce ether, the produft is called fpiritus vitrioli dulcis. The following experi- ment made by Wallerius, induced liim and others to think, that the vitriolic acid was convertible into the nitrous.. " Some fait of tartar (fays he) being mixed with Experiment tlie dulcified fpirit of vitriol, or perhaps with the in favour of ether (for the author expreftes himfclf a little ambi- '^^^^ guoufly), the full bottle flopt with a cork, tied over ^j^-^Jl'^^^^^^ With bladder, and laid on its fide ; on ftanding for four to nitrous months, the greateft part of the fpirit was found to acid, have efcaped, and the fait was ftiot into hexangular prifmatic cryftals refembling nitre. It tafted ftrongly of the fpirit, but had no other particular cafte. Laid on a burning coal, it crackled, exploded with a bright flafli, and fl.ew into the air. He afterwards found, that by adding to the fpirit a drop or two of any acid, the fait eryftallizes the fooner ; that in this cafe it has a fourifh taftc, but in other refpefts is the fame with that made without acid. ' This falt-petre (fays the au- thor) promifes, from the violence of its explofion, to make the ftrongeft gun-powder in the' world, but a very dear one. Though the experiment fliould not be applicable to any ufe in this way, it will probably contribute to iiluilrate the generation of nitre : as it palpably fi^ows nitre, that is, the acid or charafterittic part of nitre, produced from the vitriolic acid and phlogifton." We cannot here help again regretting that chemifts j^^^'^^'^^j^ of fuperior abilities ftiould fornetimes leave, very import- f,ve. ant difcoveries only half finifhed, fo that chemills of an inferior rank know not what to make of them. Had V/ alierius, Practice. CHEMISTRY. 469 Wallerlus, who feems more than once to have beeu in poffeffion of this fah, only poured on it a few drops of oil of vitriol, the peculiar colour and fmell of the fumes muft have been a much more convincing proof of the reality of the traiiimutation than that of mere defla- gration } becaufe the latter can be otherwife accounted for. It is certain, that many fuftances, water Itfelf not excepted, will explode with great violence if fuddenly ap "I'cl'tio:- heated beyond what they are able to bear. If fpirit of wine is confined in a clofe veffel, it will alfo by means of heat burft it as elFectuall)' as water ; and as the vapours of this fubilance are inflammable, the ex- plofion will be attended with a flafh if any flame is near. In like manner ether, on the approach of a candle, takes fire, and goes off in a flafh like Hghtning; but this happens, not from any thing nitrous, but from its great volatility and inflammability. If therefore the vapours of the ethereal liquor are confined, and heat is apphed fuddenly to the containing veffel, their great volatility will caufe them make an inftantaneous effort againit the fides of it, which increafing with a fwift- nefs far beyond that of aqueous or fpirituous vapours, will make a much quicker as well as a much ftronger explofion than either of them ; and if a flaming fub- ftance is near, the explofion will be attended with a bright flafh like that of the ether itfelf. In the experiment now before us, the fait tailed ftrongly of the fpirit, or ethei-, from which it was made. The fpirit was therefore confined in the cry- ftals of fait ; and his volatile liquor, which, even under the preffure of the atmofphere, boils with the heat of 100'^ of Fahrenheit, was, in a confined ftate, fubjefted to the heat of a burning coal ; that is, to more than ten times the degree of heat neceffary to convert it into vapour. The confequence of this could be no other, than that the particles of fait, or perhaps the air itfelf, not being capable of giving way foon enough to the forcible expanfion of the ether, a violent ex- plofion would happen, and the fait be thrown about; which accordingly came to pafs, and might very reafon- ably be expefted, without any thing nitrous contained in the fait. Mr Cavallo defcribes an eafy and expeditious method of purifying ether, though a very expenfive one ; as out of a pound of the common kind fcarce three or four ounces will remain of that which is purified. The method of purifying it,, he fays, was communicated to him by Mr Winch chemift in London, and-is to be performed in the following manner. '* Fill about a quarter of a ftrong bottle with common ether, and pour upon it twice as much water ; then ftop the bottle and give it a (hake, fo as to mix the ether for fome time with the water. This done, keep the bottle for fome time without motion, and the mouth of it downwards, till the ether be feparated from the water, and fwims above it ; which it will do in three or four minutes. Tlien opening the bottle with the mouth ftill inverted, let the greatfeft part of.the water run out very gently ; after this, turn the bottle with the mouth upwards ; pour more water upon the ether, /haking and feparating the water as before; Repeat this operation three or four times ; after which the ether will be exceedingly pure, and capable of diffol- ving elaftic gum, though it could not do fo before.'' Gavallo's xneihovi of purifying ether. As great part of the ether undoubtedly remains Ni'ti ous mixed with the water after this procefs, our author p '^'f . , , 11-1 1 Lombina- remarks, that it might be worth while to put the wa- ^-^^^^ ter into a retort and diftil the ether from it, v/hich _ — ^ 1 ■J will come fufficiently pure for common ufe. He ob- ferves alio, that " it is commonly believed that water combines with the pureft part of the ether when the two fluids are kept together; though the contrary feems to be eftabhihed by this procefs. According to Mr Waftrumb, we may obtain from the refiduum of vitriolic ether a refin containing vitriolic acid, vine- gar, Glauber's fait, felenite, calcareous earth, filex, iron, and phofphoric acid. §2. Of the Nitrous yield and its Coml'inaticns. This acid is far from being fij plentiful as the vitriolic. It has been thought to exift in the air ; and the expe- riments of Mr Cavendifh have fliown, that it may be artificially compofed, by taking the eltdtric fpark in a mixture of dephlogitticated and phlogillicated air. See Aerology, n° 77. ir 734 With regard to the preparation of nitre, Dr Black ob- Of the pr€» ferves, that it is made in great plenty in the more fouth- P'-^' ^i^ioa ob- ern parts of Europe ; likewifc in the fouthern parts of "''^'^'^* Perfia, in China, the Eaft Indies, and in North Ame- rica. We have had no accounts of the manner in which it is prepared in the Eaft Indies, no perlon on the fpot having taken particular notice of the manufafture. The general account is, that it is obtained from the foil of certain diftrifts which are called fcdtpelre grounds ; where the foil is very cold, barren, and unhealthy^. The fait is there ready formed by nature. It is only neceffary to gather large quantities of the earth, and to put it into a cavity through which a great quantity of water is poured, which diffolves the nitre 5 - and the lixivium runs into an adjacent pit, out of which it is lifted in order to be evaporated and obtain- ed is the form of cryftals. This account, however, has been thought unfatisfaftory ; becaufe there is hard- ly any pait of Europe in which it is found in this manner. It is difcovered indeed in fome very large oifcovered i dillriths in Poland, particularly in Podolia, where the in fome country is flat and fertile, and had been once very po- ^^^j^^^^n pulous,, but is now in a great meafure deferted. It is pqI^^^ . there obtained from tumuli or hillocks, which are the remains of former habitations ; but thefe are the only places in which it is found in any confiderable quan- , tity. In Spain, it is laid that the inhabitants ex- j^, Spain • traft it from the foil after a crop of corn. It has been md Am««<- foiind in America in hme-ltone grounds, in the floors iica» of pigeon-houfes, tobacco-houfes, or the ruins of old ftablcs, where a number of putrefying vegetables were once collefted. In general, hovTever, it is extracted from artificial compounds or accidental mixtures, where animal and vegetable fubftances have been fuUy putre- fied by being expofcd to the air with any fpongy or. loofe earth, efpecially of the calcareous kind, and open to the north or north-eaft wind, and more or lefs co- j^p^^-^^g^ , vered from the heat or rains. This laft particular is for its for- - abfolutely neceffary to its formation in any quantity ; niation. for the heat, by evaporating the moifture too much, ^ 7*^, , prevents it from being produced, and the rains walh it ^ .'j^jg^j^j^ ' away after it is already made. Cramer, an author of ^^oii ^.dft the greateft credit, informs us in his Docimai'tics, thatfoi making: he made a. little hut expcfcd to the frelh air of the"'^''^' country^ , CHEMISTRY. 729 )'ovv pie- y.a-ed in Hanover. 73" In other parts 'if Germany. 731 In France. 73^1 Dr B ack's conclufions concerning the riatiire of falt- petie. 733 Snppofcd to be the laft rffctft of pu- trcfadlion. couatr)', wuh wliKlows to admit the winda. In this he put a mixture of garden mold, the rubbifli of lime, and putrid animal and vegetable fubilances. This he frequently moifteued with urise ; and in a month or two found his compofition very rich in nitre, yielding at leall one-eighth p:irt of its weight. It is manutadlurcd in Phiropc bv n'.aking artificial compounds v»ith lefs trouble. In Hanover it is got by collcci:Ing the rakings of the Ptreets; which arc built up into mud-walls that are allowed to remain a certain time, when the furface is found covered with a wli'te falinc efflorefcence. A perfon is employed to fcrape this off ; and putting it into a vcfTel, it is wafhed with water to dilTolve the nitre, and the remaining earthy matter is again plaftered on the mud-walls, and frelh matter brought from the ftreets to renew them occa- fionally : and by this fimple method a confiderable quantity is obtained. In Germany the peafants are directed by law to build mud-walls of this kind with the dung and urine of animals, and fome Itraw. After they have Hood for fome time, and the vegetable and animal fubftances are rotten, they aflbrd a confiderable quantity of nitre. In France it is obtained from ac- cidental colleftions of this kind ; as where loofe earth has been long expofed to the contaft of animal fub- Itances, as the ruins of old ftables, pigeon-houfes, &c. Sometimes from the mould upon the ground where dunghills have been lying. A particular fet of people go about in fearch of thefe materials ; and when, by making a fmall effay, they find that they will turn to account, they put the materials into a large tub with a perforated bottom, and another which is water-proof put below it. Some ftraw is interpofed betwixt the two ; and on pouring water upon the materials, it foaks through them, undergoes a kind of filtratioo in pafiing through the ftraw, and is then drawn off by a cock placed in the under-tub, and boiled to a proper confidence for cryftallization. The cryftals are at firil brown and very impure, but by repeated diffolutlon and cryllallization become pure and white. From thefe particulars relating to the hlftory of falt- petre, Dr Black concludes, that It is not properly a fofiil, being produced at the furface of the ground. Margraaf difcovercd a fmall quantity of it in the ana- lyfis of fome of the waters about Berlin, and others have found it In the wells about fome great cities : but no true nitre has ever been found In fprings ; fo that this nitrous fait may be fuppofed to have derived its origin from the quantity of putrid matters with which all cities abound. All rich and fertile foils are found to contain It ; and in the hot countries, where the pro- dufts of nature are numerous, and puti-efaftion carried on vtry fad, they a)f often very rich In nitre. This may happen in fome places from the conflux of wa- ters ; which remaining for fome time on the furface, and afterwards exhaling, left the fallne pailicles be- hind. On the whole, Dr Black concludes, that neither nitre nor Its acid does exift in the air, becaufe it might eafly be dttefted there ; though many have embraced this opinion from Its being ufually found at the furface. of the ground. He Is of opinion, that It is the efFedl of the laft llage of putrcfaifion of animal and vegetable fubftances ; and it is Ecver to be found except where thefe or their eiBu via are prefcnt, and Pradlce. It has -been a Ni'rous never till the putrefadion is complete, matter of difpute, whether it exifted in thofe matters A^'^'^^"'^ 'ts before the procefs of putrefaftlon, or was produced by it. Bat it is pretty certain, fays the Doftor, that ^ , / it originated In them; for the fun-flower, tobacco, and ether plants, are found to contain it before putrefac- tion : and fome have even afferted, that plants placed in the earth, deprived of all its faline fuljftances, will yield it. The compofitlons recommended by Cramer are the fitteft for producing a complete degree of pu- trefadioa, provided they contain a moderate degree of humidity, and that the quantity expofed to the air be defended from too great a heat by the fun, which would dry up its moifture ; and llkevvife from too great a degree of cold, which llkewlfe checks fermentation. The importance of the calcareous earth in fuch a com- pofition would likewlfc favour the conclufions juft now drawn ; for the moft remarkable effed: of this earth is to promote and pcrfeft the putrefafllon of thefe fub- ftances. It would feem, therefore, that the true fe- cret of the produ6tIon of nitre is to mix properly to- gether animal and vegetable fubftances with earth, particularly of the calcareous kind ; expofing them to the air wath a moderate degree of humidity, fufficient to promote their putrefaftion In the moft eftedlual manner ; and when the putrefaftlon is carried to the utmoft height, we may then expert that nitre will be produced. -^^^ The diftlnguifhlng charaderiftic of the nitrous acid Dlftin- is its great difpofition to unite with the phlogifton ; and, when fo united, firft to become exceedingly vo-^.tfj^^of the latile, and at laft to be diffipated in a very white bright nkroas acid, flame : this is called its dttonat'ion ox deflagration. In the ftrongeft ftate in which this acid Is procurable In a liquid form. It is of a reddilh yellow colour, and con- tinually exhales in denfe, red, and very noxious fumes; and in this ftate Is called fmoklng, or, from its inventor, Glauber's, fplrit of nitre. I. To extraft the Nitrous Acid by means of the Vitriolic. Into a glafs retort put two pounds of good fait- Spint^of petre, and pour upon it J 8 ounces of concentrated oilintrc. of vitriol; fet the retort in a fand heat, and lute on a large receiver with the com.pofitlon already recom- mended, for refiiting acid fumes; the mixture will grow very warm, and the retort and receiver will be filled with red vapours. A finall fire is then to be kindled, and cutloully raifed till no more drops will fall from the nofe of the retort. What comes over will be a very ftrong and fmoking fpirit of nitre. . , In this procefft, the nitrous acid Is generally mixed Redtilica- with part of the vitrlohc which comes over along with tioa. it, and from which it muft be freed If defigned for aloe purpofes. This is moft efi'eftually done by dlf- fulviiig in it a fmall quantity of nitre, and rediftilling the mixture. The vitriolic acid which came over in the firft diftillatlon is kept back by the nitre in the fe- cond, combining with its alkaline bafis, and expelling a proportionable quantity of the nitrous acid. We have here direfted the pure vitriolic acid to be Dift-Jreiit ufed, in order to expel the nitrous one ; but for this methous of purpofe any combination of the vitriolic acid with a ^^■^'^'^^"'S* metallic or earthy bafis may be ufed, though not with equal advantage. If calcined vitriol is made ufe of, a4 Pra£llcei Nitrous as much phloglflon is communicated by the calx of Acid and i s Iron contained in that fait as makes the nitrous acid Gombina- exceedingly volatile, fo that great part of it is lofl. If calcined alrim, or felenite, is made ufe of, the vitrio- lic acid in thefe fubftances immediately leaves the earth' with which It was combined, in order to unite with the alkaline bafis of the nitre, _ and expels its acid : but the moment the nitrous acid is expelled from the alkali, it combines with the earth which the vitrio- lic acid had left ; from which it cannot be driven without a violent fire ; and part of it remains obfli- nately fixed, fo as not to be expelled by any degree of heat. Hence the produce of fpirit, when nitre is diftilled with fuch fubltances, always turns out confi- derably lefs than when the pure vitriolic acid is ufed. Alum is preferable to felenite, for the purpofes of diftilling fpirit of nitre ; becaufe the acid does not ad- here fo ftrongly to argillaceous as to calcareous earth. According to Weigleb, the nitrous acid may be ex- pelled not only by clay, gypfum, and other fubftances containing the vitriolic acid, buL even by various kinds of vitrifiable earth. Clean pebbles, quartz in the form of fand, pieces of broken china and Hone ware, powdered glafs, Iffc. mixed with nitre in the proportion of fix to one, always expel the acid, though imperfeftly. In' France the acid is always extrafted by means of clay. ' The reafon of thefe decompofitions is, that the al- kaline bafis of the nitre attrafts the filiceous earth, whofe fixednefs in a vehement fire gives it an advan- tage over the volatile nitrous acid, in the fame manner that the weak acid of phofphorus or arfenic will alfo expel it by Veafon of their fixednefs in the fire. Even fpirit of fait, according to MargraafT's experi- ments, may be ufed for dilliUing the Ipirit of nitre. That celebrated chemift informs us, that on diftilling nitce with eight or nine times its quantity of ftiong marine acid, a fpirit comes over which confifts chiefly of the nitrous acid, but has alfo fome portion of that of fea-falt. The reafon of this is fhown in Mr Kir- wan's experiments on chemical attradions*. In the piefent caie, however, the decompofition may be faci- litated by the ftrong attraction of the nitrons acid for phlogifton ; for it is well known, that on mixing the nitrous and marine acids together, the latter is always dephlogifticated. It leems therefore that in this cafe a double decompofition takes place, the nitrous acid uniting itfelf to the phlogifton of the marine, and the latter attaching itfelf to the alkali of the nitre. Spirit of nitre is very ufeful in the arts of dyeing and refining, where it is known by the name of aqua for- th ; and therefore an eafy and cheap method of pro- curing it is a valuable piece of knowledge. Many difFicuIties, however, occur in this procefs, as well as that for the vitriolic acid. Oil of vitriol, indeed, al- ways expels the nitrous acid with certainty ; and on diftilling the mixture, a fpirit of nitre arifes : but if a glafs retort is ufed for the pnrpofe of diftilling this a- cid, the quantity of refiduum left in diftillation is fo great, and fo infoluble in water, being no other than vitriolated tartar, that the retort muft always be broken in order to get it out ; and the produce of fpirit vs'iil fcarce afford the breaking a retort. If earthen re- torts are made ufe of, they mult certainly be of that kind called iloae-ware, and the price of them will be CHEMISTRY. • Pee 73^ Ulcs. 47^ very little If at all inferior to that of glafs. Iron pots Nitrous ^ are laid to be made ufe of in the diftillation of common Q^jj^ij^'^'^j^' aquafortis in large quantities ; but they have the great ^ions. inconvenience of making a quantity of the acid fo vo- u-— y— latlle, that it not only will not condenfe, but fpteads its fuffocating vapours all around in fuch a manner as to prove very dangerous to thofe who are near it. If an iron vefTcl, therefore, is thought of for the purpofe of diftilling aquafortis, it will be proper at leaft. to at- tempt luting over the infide with a mixture of gyp- feoud earth and fimd, to prevent as much as pofiible the acid from attacking the metal. Dephlogifticated fpirit of nitre is obtained by diftil- ling the fmoking kind with a gentle heat, until what remains is as colourlefs as water. It is diftinguinied by emitting white and not red fumcs like the other kind, when fet in a warm place. It muft be kept- conftantly In the dark, otherwife it will again become phlogifticated, and emit red vapours by the aflion of the light ; the fame thing will alfo take place if it be heated with too violent a fire. II. To procure the Nitrous Acid by means of Arfinic. 739 Pulverife equal quantities of dried nitre and white Blue aijua. cryttalline arfenic ; mix them well together, and diftil fortis. in a glafs- retort with a fire very cautioufly applied ; for the arfenic adls on the nitre with fuch a violence, and the fumes are here fo volatile, that unlefs great care is taken, a moft dangerous explofion will almoll certainly happen. As, in this cafe, the nitrous fumes arife in a perfeAly dry ftate, fome water muft be put into the receiver, with which thty may unite and con-, denfe. The aquafortis fo produced will have a blue colour, owing to the inflammable principle feparated from the arfenic, by which its extreme volatility is likewife occafioned. If this blue aquafortis is expo- fed to the air, its colour foon flies oif. If inftcad of the white arfenic we employ the pure arfenic acid, the diftilled liquor will have no blue colour. Nitrous Acid combined; I. With Vegetable Jixed Mali. This fait, combined ^^,^^^0 with the nitrous acid to the point of faturation, regene- ^ P^'-s» rates nitre. It is obfervable, however, according to Neumann, that there is always fome diffimilarity be- tween the original and regenerated nitre, unlets quick- lime is added. The regenerated fait, he lays, always corrodes tin, which the original nitre docs not; owing probably to a (juantity of pldogifticated acid remaining in it. Boihng with quicklime deprives it of this quality, and makes it exaftly the fame with original nitre. II. W'uh FoJiU alkali. The neutral fait arifing from q^i^-'^.'^j^j^j.^^ a combination of the nitrous acid and follile alkali is fomewhat different from common nitre; being moie difficult to cryftallize, inclining to deliquate in the air, and fliooting into cryllals of a cubical form, whence it gets the name of cubic nitre. Its qualities are found fomewhat inferior to the common nitre ; and therefore it is never made, unlcfs by accident, or for experi- ments. Nitre is one of the moft fufible falts. It is liqnefied Fufibiifp-. in a heal much lefs than what is neceffary to make it red ; and thus remain in tranquil fufion, without fwel- liug. If nicre thus melted be lefc to cool and fix, whe. - : tions. 1A3 Ufes. 472 G H E M I ^kroua whether It has been made red-hot or not in the fufion, Combina- coagulates mto a white, femi-tranfparent, fohd mafs, called mineral cryjlal, having all the properties of nitre itfelf. By this fufion, Mr Beaume obfcrves that nitre lofes ve«y little, if any, of the water contained in its cryftals, fince the weight of mineral cry Hal is nearly the fame with that of the nitie employed. When nitre is kept in fufion with a moderate heat, and at thefame time does not touch anyinflammable mat- ter, nor even flame, it remains in that Itate without fufiering any very fenfible alteration ; but if it is long kept in fufion with a flirong Fire, part of the acid is de- llroyed by the phlogifton which penetrates the crucible; and hence the nitre becomes more and more alka- line. Nitre is of very extenfive ufe in different arts ; be- ing the principal ingredient in gun-powder ; and fer- ving as an excellent flux to other matters ; whence its ufe in glafs making. (See Glass.) It is alfo poffef- fed of a confiderable antlfeptic power ; whence its ufe in preferving meat, to which it communicates a red colour. In medicine, nitre is ufed as a diuretic, feda- tive, and cooler ; but very often fits uneafy on the fl;o- mach. The refemblance of the cryftals of nitre to thofe of Glauber's fait has fometimes been the occa- fion of dangerous miftakes. Dr Alexander mentions a fwelling over the wholi- body of a woman, occafioncd by her taking a folution of nitre inftead of Glauber's fait. Two mift-akes of the fame kind we have alfo known. In one an ounce, and in the other upwards of two onnces, of nitre vrere fwallowed. The fymp- toms occafioned were unlverfal coldnefs and fhivering, extreme debihty and ficknefs at fl:omach, cold fweats, and faintings. Neither of the cafes proved m.ortaL The cure was eflPedled by cordials and corroborants. A.procefs has obtained a place in the difpenfatories for a fuppofed purification of nitre by means of flower of brimftone. A pound of falt-petre is to be melted in a crucible, or fmall iron veflel ; and an ounce of flowers of fulphur thrown upon it, by fmall quantities at a time : a violent deflagration enfues on each addi- tion ; and after the whole is put in, the fait is poured out in moulds, and then called fal prunella. It has been difputed whether the nitre was at all depurated by-this procefs ; Dr Lewis thinks it is not. From our own experience, however, we can affirm, that by this means a fediment falls to the bottom, which car- ries with it any impurities that may have been in the nitre, and leaves the fluid fait clear and tranfparent as water. This precipitate i^i probably no other than a vitriolated tartar formed by the union of the fulphu- reous acid and alkali of the nitre, which being lels fu- fible than the nitre, fubfides in a folid form and clari- fies it. III. With ^oZ3/iZ?./^/ia//. The nitrous acidfeems pecu- liarly adapted to an union with volatile alkali ; fatura- ting as much, or rather more of it than the fl:rongeft vi* triolic acid is capable of doing. The produ£l is a very beautiful fait, called 'volatile nitrey or mtrous fal ammo- niac. It very readily difiblves, not only in water, but in fpirit of wine, which difl:inguifties it from the vitrio- lic and common kind of fal ammoniac. It alfo requires lefs heat for its fublimation : indeed care miufl; be ta- ken not to apply too great a heat for this purpofe, as TRY. Pradlce* the nitrous fal ammoniac has the property of dcfla^ Nitrous grating by itfelf without any addition of inflammable 744 Sal pruneL ia. . 745 Nitrous am moniac. matter ; and this it does more or lefs readily, as the J^"" volatile alkali with which it was made was more or lefs impure and oily. The medical virtues of this kind of nitre have not D'- Ward's been inquired inta. It feems to have made the prln- '"^'^^ cipal ingredient in the famous Dr Ward's white drop, M'hich was celebrated as an antifcorbutic ; with what juftice, thofe who have tried it mufl: determine. ^ IV. With Calcareous Earths. Thefe the nitrous acid Cakareou* diflblves into a tranfparent colourlefs liquor; but for this ""^c. purpofe it mult beveiy much diluted, or the folution will have a gelatinous coHfillence. This compound is not ap- plicable to any ufeful purpofe. It has a very acrid tafte;^ and, if infpiffated, attracts moifture from the air. If it is totally dried, it then refembles an earthy mat- ter, which deflagrates very weakly. By diiHllation in a retort, almoll all the acid may be expelled, and what Httle remains flies off" in an open fire. _Mr Pott, who has particularly examined the com- Nitrous acid bination of nitrous acid with quicklime, fays that the <^econipo- acid fuffered remarkable aherations by diftillation from quicklime, and repeated cohobations upon it. By thefe experiments he obtained a fah more fenfibly fcfceptible of cryfl.aUi2ation and detonation, than what can be obtained by a fingle combination. From his experiments it would feem, that nitrous acid, by this treatment with quickhme, was capable of being en- tirely decompofed. If a folution of chalk in the nitrous acid be evapo- rated to drynefs, and then gently calcined, it acquires the property of fliining in the dark, after having been expofed to the fun's rays, or even to the light of a candle.^ ^ This fubfl:ance, from its inventor, ts called pho?ho» Baldnnn's phofphorus ; or, from its being neceflTary to rus. ^ keep it in a glafs hermetically fealed, phofphorus her- meticus, (See Earths). V. With Jrgillaecous Earths and Magnefia. All that i$ known concerning the combinations of nitrous acid with thefe earths is, that the firlt produce allringent, and the fecond purgative, compounds, fimilar to alum and Epfom fait, and which are not fufccptible of cry- ftallization. ^ VI. With Gold. — Till very lately, it has been the opi- nion of chemiflis, that the nitrous acid fey itfelf was inca- pable of adling upon this metal.— Dr Brandt, how- ever, produced before the Swedifli academy of fcien- ces, a folution of gold in the nitrous acid, obtained in parting, by that acid, a mixture of gold and filver. — The mixed metal was boiled with aquafortis in a glafs body fitted with a head and receiver, the hquor poured oiF, and the Co6tion repeated with frefli parcels of ftronger and fl:ronger nitrous fpirits, till all the fil- ver was judged to be extraded. The laft parcel was boiled down till the matter at the bottom looked like a dry fait ; on boihng this in frefh aquafortis in dole veffels, as before, a part of the gold was diflblved, and the liquor tinged yellow. But though gold is by this means truly foluble in the nitrous acid, the union is extremely flight ; the gold being not only precipi- tated on the addition of filver, but likew ife Jpontane- oufly on expofure to the air.— Dr Lewis very juftly obfcrves, that this folution may liave been often .made .unknown 150 Gold. I'raclice. C H E M I 751 Silver. 75 a Lunar cau- ftic. 753 Colours produced Ly folution wl filver. unknown to the cliemifls who did fo ; and probably occafioned the miftakes which fome have fallen into, who thought that they were in pofleffion of aquafor- tis capable of tranfmuting filver into gold. Notwith- ftanding thefe authorities, Mi- Kirwan is of opinion that the nitrous acid is in no cafe able to difiolve gold ; the metal being only intimately mixed or dif- fufed through it. II. With Siher. — Pui-e fpirit of nitre will dilTolve its own weight of filver ; and Hioots with it into fine white cryftals of a triangular form, confifting of very thin plates joined clofely one upon another. Thefe cryfhals are fomewhat deliquefcent ; of an extremely bitter, pungent, and naufeous tafte; and, if taken internally, are highly coirofive and poifonous. They rnelt in a fmall heat, and form, on cooling, a dark-coloured mafs ilill more corrofive, called lunar cauftic or lapis itifer- na/is. They readily difiolve in water ; and, by the afQftance of warmth, in fpirit of wine. In the yida Natures Ciirioforim, tom.vi. there is a remarkable hi- llory of filver being volatilized by its combination with the nitrous acid. Four ounces of filver being dif- folved in aquafortis, and the folution fet to diilll in an earthen retort, a white tranfparent butter arofe in- to the neck, and nothing remaining behind ; by de- grees the butter liquefied, and pafl'ed down into the phlegm in the receiver. The whole being now pour- ed back into the retort, the filver arofe agftn along with the acid. The volatilization being attributed to the liquor having ftood in a laboratory where charcoal was bringing in, the experiment was repeated with a frefli folution of filver, and a little powdered charcoal, with the fame event. Solution of filver in the nitrous acid ilaii^s hair, bones, and other folid parts of animals, and different kinds of wood, of all the intermediate fhades from a light brown to a deep and lafting black. The liquors commonly fold for fl;aining hair brown or black, are no other than folutions of filver in aquafortis, fo far diluted in water as not fenfibly to corrode the hair. It gives a permanent ftain likewife to fundry ftones ; not only to thofe of the fofter kind, as marble, but to fome of confiderable hardnefs, as agates and jafpers. The folution for this purpofe fliould be fully faturated with the metal ; and the ftone, after the liquor has been applied, expofed for fome time to the fun. M. du Fay obferves (In a paper on this fubjedl in the French memoirs for 172S), that if the folution be repeatedly applied, it will penetrate in the whitifh agate, or chalcedony'', about one-twelfth of an inch : that the tinfture does not prove uniform, on account of the -veins in the ftoite : that the colours, thus com- municated by art, are readily dillinguifhablc from the natural, by difappearing on laying the ftone for a right in aquafortis: that, on expofing it to the fun afterwards for fome days, the colour returns : that the folution gave fomewhat different tinftures to dif- ferent ftones ; to oriental agate, a deeper black than to the common chalcedony ; to an agate fpotted with yellow, a pui-ple ; to the jade ftone, a pale brownifh ; to the common emerald, an opaque black; to common granite, a violet unequally deep ; to ferpentine ftone, an olive ; to marble, a reddlfn, which changed to pur- ple, and fixed in a brown : that on flates, talcs, and .^mlanthus, it had no e£Fe6t. V-OL. IV. Part IL S T R Y. 473 If a folution of filver be diluted with pure water, aNitrous confiderable quantity of pure mercury added, and the ^^'^'^ whole fet by in a cold place ; there will form by de- nations^ grees a precipitation and cryftalllzation refembhng a l— little tree, with its root, trunk, and branches, called 754 arbor Diana: or the philojophic fdvsr tree. Another kind Arbor Dia- of artificial vegetation may be produced by fpreadlag a few drops of folution of filver upon a glafs plate, and placing in the middle a fm.all bit of any of the metals that precipitate filver, particularly iron. The filver quickly concretes into curious Ramifications all over the plate. Like other metalKc folutions, this combination of Solution of the nitrous acid with filver is decompofed by fixed and filler de- volatile alkalies, calcareous earths, and feveral metals, <^'^'"^r°^^'i' (fee the Table of Affinities) ; but v/ith feveral pecu- liar circumftances attending the precipitation. With metals, the filver is readily and copioufiy thrown down at firft, but flowly and difficultly towards the end. The menftruum generally retains fome portion of the filver, as the filver almoft always does of the metal which precipitated it. For recovering the filver from aquafortis after parting, the refiners em.ploy'copper. ' The folution, diluted with water, is put into a cop- per veflel, or into a glafs one with thin plates of cop- per, and fet in a gentle warmth. The filver begins immediately to feparate from the liquor in form of fine grey fcales, or powder ; a part of the copper being diflblved in its place, fo as to tinge the fluid more or lefs of a blulfti green colour. The plates are now and then ftiaken, that fuch part of the filver as is depo- fited upon them may fall off", and fettle to the bottom. The digeftion is continued till a frefti bi-ight plate, kept for fome time in the warm liquor, is no longer obferved to contrafl any powdery matter on the fur- face ; when the liquor is poured off, and the preci- pitate waftied with frefli parcels of boihng water. It is obfervable, that though the acid in this procefs fa- turates Itfelf with the copper, in proportion as it lets go ,the filver, yet the quantity of copper which it takes up Is not near fo great as that of filver which it de- pofits. One drachm of copper will precipitate three of filver, and faturate all the acid that held the three drachms diffolved. ^ Calcareous earths, as chalk or quicklime, throw Charaders down a part of the filver, but leave a very confide- curioufly rable part fufpended In the liquor. If the earth be ' •^'"l^-ed on moiftened with the folution into the confiftence of a '^^ pafte, and expofed to the fun. It changes Its white by means colour to a dark purplifti black ; diftinft charafters of rhe fun's may be exhibited on the matter, by intercepting a''^'^'^' part of the fun's light by threads, flit paper, ijfc. placed on the outfide of the glafs. Culinary fire does not af- feft Its colour : after the mafs has been exficcated by this, it changes as before, on expofure to the fun. Mild volatile alkaline fpirlts, added to a folution of filver, precipitate but little, and cauftic volatile alka- lies none. Pure fixed alkalies, and alkalies rendered cauftic by quicklime, thiow down the whole. Fixed al- kahes Impregnated with inflammable matter by calci- nation with animal coals, occafion at firfl a confide rable precipitation ; but if added to a larger quantity, take up great part of the metal again. Mr Mar- graaff relates, that edulcorated calces of filver totally dilToLve, both in a lixivium of thefe alkahes and in vo- 3 O latile 474 Nitrous Acid and its Combi- nations. 757 Copper. 75S Verditer. Iron. C H E M I latfle fpirits ; and that the marine acid precipitates the filver from the volatile, but not from the fixed, alka- line folution. Kunckel reports, that the calx precipi- tated by volatile fpirits made with quicklime, fulmi- nates or explodes in the fire; and that by infpifiating a folution of pure filver, melting the dry refiduuin, pouring it on fpirit of urine fuperfaturated with fait, and fetting the mixture in a gentle warmth, a blood- red mafs is produced, fo tough as to admit of being wound about the fingers. III. With Cqfper. The nitrous acid very readily dif- folves this metal into a green-coloured and very cauilic li- quor. The folution, if properly evaporated, will cry- flallizc ; but the cryftals are deliquefcent, and there- fore difficult to be preferved. The cnly ufe of this combination is for the preparation of the pigment cal- led verditer. Of this there are two kinds, the blue and green. The blue is by far the brighteft colour, and confequently the moft valuable. It has been faid that this is obtained by precipitating a folution of copper by any calcareous earth ; and therefore is fold by the refiners, who have large quantities of folution of cop- per accidentally made. The folution is faid to be pre- cipitated by chalk, or whiting ; and that the precipitate is the beautiful blue colour called verditer. By this method, however, only the green kind can be obtain- ed. The blue we have found to be ©f a quite different nature, and formed by precipitation with a gentle heat from a folution of copper in volatile alkali. See the article CotouR-MAKiNG. IV. With Iron. On this metal the concentrated nitrous acid afts very violently, and plentifully corrodes, but does not diflblve it; the calx faUing almoft as faft as difiblved ; and when it is once let fall, frefh acid will not take it up again. If the acid was diluted at firft, it takes up a confiderable proportion, provided the metal be leifurely added. If the folution is perform- ed with extreme flownefs, the colour will be green ; but if otherwife, of a dark red. It does not cryftal- lize ; and, if infpiflated to drynefs, deliquates in the aij"- V. With Tin. Concentrated nitrous acid afts upon tm with great force, but only corrodes the metal into a white indilToluble mafs. In order to obtain a perfeft folution of tin in the nirous acid, the metal muft be put in by very little at a time, and a diluted aquafortis made ufe of. This folution has been confiderably ufed in dyeing, and is remarkable for heightening red co- lours of all kinds ; but the folution made with aqua- regis is preferable. VI. With Lead. Proof aquafortis, lowered with an e- qual quantity of water, diffolves about half its weight of lead. On diluting the folution with a large quantity of water, it turns milky, and depofites great part of the metal. The folution ftioots, upon exhaling part of the menftruum, into fmall pyramidal cryftals with fquare bafes, of an auftere fweet tafte. In the memoirs of the French academy for 1733, fuppofed ro ^j^^^.^ jg ^ particular account of an experiment, in which from'lead!'' mercury is faid to have been extraded from lead by diflblving it in the nitrous acid. During the diffolu- tion, there fell a precipitate, which is plainly proved to be mercury, and was looked upon to be one of the canftituent parts of the lead feparated by this fimple procefs : it feems probable^ however, that the mercury S T R Y. Pradice. ?6o Tin. 761 Lead, 764 CJuickfilver in this cafe had been contained in the aquafortis ; ^o"" Nitrous^ pure lead diffolved in pure aquafortis gives no fuch pre- cipitate. ^ nations. The cryftals of lead in the nitrous acid, when J thrown into the fire, do not deflagrate as other com- binations of this acid with metallic or faline bafes ; but crackle violently, and fly around, with great dan- ger to the by-ftanders. If they arc rubbed into very fine powder, they may then be melted without any danger. By repeated diflblutions in frefh aquafortis, they at laft form a thick fluid like oil, which cannot be dried without great difficulty. This compofition Is not adapted to any particular ufe, and is a violent poifon. 76.? VII. With ^ickfiher. Aquafortis, of fuch a degree Qiiickfil- of ftrength as to take up half its weight of filver, dif-^'^''* folves with eafe above equal its weight of mercury in- to a limpid Hquor, inteniely corrofive and poifonous, which fpontant-oufly ftioots into white cryftals. Thefe cryftals, or the folution exficcated, and moderately calcined, afl'unie a fparkling red colour ; and are ufed in medicine as an efcharotic, under the name of ^^^Rg/'^rec'- precipitate. The precipitate has fometimes been gi- piute.'^'^'^^" ven internally, it is faid, in very large quantities ; even a whole drachm at one dofe. But this would feeni incredible ; and the prefent praftice does not countenance the taking of red precipitate inwardly. This folution feems to have been what gave the efficacy to Ward's white drop. When red precipitate is prepared in quantit)', It Is proper to diftil the mercurial folution ; becaufe moft; of the aquafortis may then be faved. It is exceeding- ly pure, if by purity we mean its being free of any ad- mixture of vitriolic ©r marine acid; but is confiderably tainted with the inflammable principle of the mercury extricated during the diffolution. In confequence of this, it is very volatile and fmoking ; which has gene- rally, though improperly, been taken as a fign of ftrength in the nitrous acid. , VIII. WithBifmuth. This femimetal is vei7 readily afted gifmufh, upon by the nitnius acid. Proof aquafortis diffolves about half Its weight of bifmuth. If the metal was ha- ftily added, the folution proves of a greenifli colour; if otherwife, It is colourlefs and tranfparent. Unlefs the acid was diluted with about an equal quantity of water, a part of the bifmuth cryftallizes almofl; as fafl: as it diffolves. The metal is totally precipitated both by fixed and volatile alkalies. The laft, added in greater quantities than are fufficient for precipitation, take it up again. The liquor generally appears greenifh ; by alternate additions of the alkaline fpirit and folution, It becomes bluifh or purple. Fixed alka- lies calcined with inflammable matter likewife diffolve the bifmuth after they have precipitated it. The only ufe of this compound is for the precipi- Magiftery^ tate, which is ufed as a cofmetic, under the name of of bifnautb. magiftery of bifmuth. The common way of preparing this is by diluting the folution veiy largely with water^ upon which it turns milky, and a fine white precipi- tate falls, which is to be well edulcorated with water, and is then employed as a cofmetic both In wafhes and pomatums. Concerning the preparation of this cofmetic, Neu- mann obferves, that there are fundry variations. — " Some (fays he) take aqua-regia for the menfl;ruum ; and for the precipitant a folution of fea-falt, alkalies, ^ fpirit C H E M 767 Zinc. 769 Regulus of cobalt. 770 Regulus of cobalt, how ilifcovered fpint of wine, Sec. Some mix with the folution of bilmuth a folution of benzoin in fpirit of wine, and thus obtain a magiflery compounded of bifmuth and benzoin. Others add a fohition of chalk to the me- talline folution, and precipitate both together by al- kalies. I have made trial .vith a good number of dif- ferent precipitants ; and found, that with common fixed alkali and caullic alkali, with watery and vinous alkahne fpirits, the magiflery was white, and in con- fiderable quantity ; the liquor, after the precipitation with volatile fpirits, appearing blue. That oil of vi- triol threw down a white precipitate very copioufly : but that with fpirit of fait, or fpirit of vitriol, the precipitate was in very fmall quantity, in colour like the foregoing ; diftilled vinegar making no precipita- tion at all. Common rectified fpirit of wine, and tar- tarized fpirit, common water, and lime-water, gave white precipitates. Solutions of nitre, vitriolated tartar, fal mirabile, alum, borax, common fait, fal ammoniac, the combination of marine acid with calcareous earth, and terra foliata tartari, all precipitated the bifmuth white. With a folution of gold in acjua-regia the ma- giflery proved grey ; ,with a folution of the fame metal in aqua-regia made with fpirit of fait, the precipitate was likewife grey, and in fmall quantity ; with folu- tion of copper in aquafortis, white, and in very fmall quantity, the liquor continuing blue ; with folution of "vitriol of copper, white ; with folution of mercury fub- limate, white and plentiful ; with folution of iron in aquafortis, yellowifh ; with folution of lead in aqua- fortis, and of fugar of lead, white ; with folution of zinc in aquafortis there was little precipitate; and with folutions of filver, tin, regulus of antimony, and of mercury, in the fame acid, none at all." IX. With Zinc. Upon this femimetal the nitrous acid a£lswith greaterviolence than any other, and will forfake any other metallic fubflance for it. The whole is very foon difFolved into a tranfparent colourlefs liquor. The calces of flowers of zinc are likewife foluble in the nitrous acid ; but neither the folution of the flowers, nor of the metal itfelf, has been yet found applicable to any ufeful purpofe. Neumann remarks, that on ex- tra£ling with nitrous acid the foluble parts of calamine, which is an ore of zinc, the folution, infpifTated to drynefs, left a reddifh brown mafs, which on digeflion with fpirit of wine exploded and burfl the vefTel. X. With Regulus of Antimony. The nitrous acid rather corrodes than difTolves this femimetal. The corroded powder forms a medicine formerly ufed under the name of bezoar mineral, but now difregarded. XI. With Regulus ofColalt. This femimetal difTolves readily in the nitrous acid, both in its metallic form and when reduced to a calx. The folution is of a red colour. Hence the nitrous acid furnifhcs means of difcovering this femimetal in ores after flrong calci- nation ; very few other calces bfcing foluble in the ni- trous acid, and thofe that are not influencing the colour. XII. With Nickel. This femimetal is eafily diffolved by the nitrous acid into a deep green liquor j but neither this folution, nor indeed the femimetal of which it is made, has hitherto been found of any ufe. XIII. Withylrfenic. This fubflance is readily'difiblved by the nitrous acid ; which abftradls the phlogiflon, I S T R Y. 475 and leaves the pure arfenical add behind. See belovir Nitrous Acid of Arfenic. Acid and XIV. With Expreffed Oils. Thefe, as well as all other fatty or uniluous fubflances, are confiderably thickened ' .. ^ ■ and hardened by their union with the nitrous acid. 771 There is only one preparation where this combination O'ls* is applied to any ufe. It is the unguentum cttrinum of ^7* the (hops. This is made by adding to fome quantity ^^^^j^]^ of melted hog's-lard a folut ion of quickfilver in the num. nitrous acid. The acid, though in a diluted flate, and combined with mercury, neverthelefs afls with fuch force on the lard, as to render the ointment almofl of the coniiflence of tallow. XV. With Finous Spirits. If highly redified fpirit of Spid^tf wine and flrong fpirit of nitre are fuddenly mixed to- wine, gether, the acid inflantly becomes volatile, and is dif- fipated with great heat and effervefcence in highly noxious red fumes. If the acid is cautioufly poured into the fpirit, in the proportion of five, fix, or even ten parts of fpirit to one of acid, and the mixture di- flilled in a glafs retort fet in a water-bath, an exceed- ingly fragrant and volatile fpirit comes over, ufed in medicine as a diuretic and cooler, under the name of fpiritus nitri dulcis. This liquor is not acid ; nor has SpiritHs ni- what remains in the retort any more the charafteriftics rri dulcis. of nitrous acid, which feems to be entirely decompofed in this procefs. (See the following article.) With the nitrous acid and fpirit of wine, may alfo Nitrous be made an exceedingly volatile liquor, called w/Vrowj- ether, to diflinguifh it from the vitriolic above men- tioned. The proportions of nitrous acid and fpirit of wine to each other for nitrous ether, are two of the acid by weight to three of the fpirit. Dr Black's procefs for making it is as follows. Take four ounces of flrong phlogiflicated nitrous acid ; and having cooled it by putting it into a mixture of fait and fnow, or into water cooled very near the freezing point, by put- ting pieces of ice into it, he pHts it into a phial, and pours upon it an equal quantity of water, likewife cooled very low, in fuch a manner that the water may float as much as pofTible on the furface of the fpirit. Six ounces of flrong fpirit of wine are then put in, fo as to float in like manner on the furface of the water ; the phial is placed in a vefTel containing cold water : and fo great is the power of cold in reflraining the ac- tion of bodies, that if the mixture was too cold, no ether would be produced ; but at the temperature jufl mentioned, the ether begins to be formed in a few hours, with fome little efl'ervefcence, and an expulfion of a fmall quantity of nitrous air. We mull provide for the efcape of this elaflic fluid, by having an hole in the cork, or the vefTel would be broken. The whole of the ether will be formed in a few V / \ ^ days, and may be feparated from the rcfl ^ of the hquor by means of a funirel, fhaped J as in the margin. To procure the nitrous ether in large quantities, Wouife's Mr Woulfe recommends the following procefs. Put i roccfs for into a retort four pounds of nitre, then mix together i''"?'^*}'^'"^ four pounds of vitriohc acid, and three pounds five quantit^s, ounces of fpirit of wine. Thefe are poured on the nitre by adding only two ounces at a time : the vi- triolic acid afting on the nitre, produces a fufiiciemt degree of heat j and the acid of the nitre uniting with 3 O 2 the 777 . Inquiry in- to the na- ture of e- ther. nitre. C H E M I the fplrit, forms a nitrous ether, which flies off from the mixture, and is condenfed in a number of veffels placed in cold water. — To obtain good nitrous ether readily, and at one diftillation, Mr Dollfufs advifes to diftil four parts of nitre of manganefe, four of vitriolic a(;id, and tight parts of fpirit of wine. Macquer fuppofes that ether is the moft oily part or quinteffence of fpirit of wine. But it cannot be proved that ether contains any oil. And, befides, if this were the cafe, thofe acids which have the ilrongell attraction for water would produce the greateft quan- tity of ether ; which is found not to be the cafe: audit is moft probable that ether is produced by a combina- tion of fome part of the acid with a portion, particu- larly the inflammable part, of tin? fpirit of wine ; and it has been (hown by chemical experiments, that every kind of ether contains a part of the acid employed. Dr Black himfelf has formed ether without any fpirit at all, by expofing nitrous acid highly phlogifticated for fome months to the light of the fun. This was owing to the attraftion of the principle of inflamma- bility ; which it is well known that light has the power of afFordincr to. bodies that attraft it with force. Nitrous Acid decomposed, 77^ Oils fired !• -By EJfential Otis. If equal quantities ef llrong by fpirit of nitrous acid and oil of cloves are poured into the fame veflel, the mixture infliahtly takes fire ; both acid and oil burning with great fury till only a light fpongy coal remains. Dr Lewis obferves, that this experiment does not always fucceed, and that there are but few oils which can be fired with certainty, without attend- ing to a particular circumfl:ance firfl; difcovered by M. Rouelle, and communicated in the French Memoirs for the year 1747. *' On letting fall into the oil equal its quantity of acid, the mixture effervefces, fwells, and alight fungous coal arifes: a little more of the acid poured upon this coal fets it infl;antly on fire. By this method almoll all the diftilled oils may be fired by fpi- rit of nitre of moderate ftrength. Expreffed oils alfo may be fet on fire by a mixture of the nitrous acid and oil of vitriol ; the uie of which laft feems to be to ab- forb the aqueous humidity of the fpirit of nitre. II. By Charcoal. By this fubftance the nitrous acid cannot be conveniently decompofed, unlefs it is combi- ned with an alkaline or metallic bafe. For the purpofe of decompofing the acid, common faltpetre is moft convenient. The proportions recommended by Dr Lewis for alkalifating nitre, are four ounces of the fait to five drachms of powdered charcoal. If thefe are carefully mixed, and inje6led by little and little into a tubulated retort made red hot, and fitted with a large leceiver and a number of adopters, a violent deflagra- tion will enfue on every addition, attended with a great quantity of air, and fome vapours which will circulate for fome time, and then condenfe in the veflels. This liquor is called cly/fus of nitre. If fulphur is ufed inftead of nitre, the clyfliis is of a different kind, confifting of a mixture of the nitrous and vitriolic acids. The re- fiduum, when charcoal is ufed, is a very ftrong and pure alkali ; with fulphur it is vitriolated tartar. To pre- vent the lofs occafioned by the violent deflagration, when this operation is performed in open veffels, Dr Black recommends to have the materials fomewhatmoifl:. III. By Vinous Spirits. In the piocefs already men- . 779 Uitre alka- lized. 780 Clyffus of aitrc. S T R Y. Praaice. tioned for mdk.\ng fpiritiis nitri Jukis, a total decompo- Marines fition of the acid feems to talce place : for neither the dulcified fpirit itfeif, nor the acid matter left in the re- ji^tiJ^^^"^'' tort, fliow any figns of deflagration with inflammable . __j matters, which is the peculiar chara6leriflic of nitrous . . -8r Mr Pott has given an analyfis of the oleaginous rc- Rgc/j.^,ujjj Cduum of the diftillation. Diftilled by a ftronger fire, of fpiritus it gave over a yellow, acid, Jlightly empyreumatic '^it^ i ciuiris fpirit; which being faturated with fixed alkali, the '''^'''"'-^ ' liquor evaporated, and the dry neutral fait laid on ' ' * burning coals, did not deflagrate. After this fpirit a- role a red empyreumatic oil ; and in the bottom of the retort was left a fliining black mafs like fout; which, burnt in a crucible, left a white fixed earth, convert- ible by a vehement fire into giafs. Ancjther parcel of the above refiduum was evaporated to the cunfift- ence of pitch. In this ftate it gave a yellow tinfture to fpirit of wine, flamed vividly and quietly on burn- ing coals, and at laft fweiied up like bitumen. Ano- ther portion was faturated with alkaline ley, with, which it immediately effervefced, and then evapora- ted as the former. It gave, as before, a yellow colour to redlified fpirit of wine, and a much deeper yellow to dulcified fpirit of nitre ; and in the fire difcovered no footftep of detonation. M. Macquer fuppofes this acid to have been not the nitrous, but the acetous, v/hich. enters into the compofition of the fpirit of wine ; and his conjecture is now confirmed by late experiments. §3' Of t/je Marine ^cicl and its Combinations, . This acid is never, at leaft very rarely, found but in a ftate of faturation with the mineral alkaK ; in which cafe it forms the common fait ufed in food. Al- moft the only exception to this is human urine, and perhaps that of fome other animals ; for there the ma- rine acid is found faUirated, not with the mineral, but the common vegetable, fixed alkali. From being found, in fuch plenty in the waters of the ocean, it has the, name of marine acid. It is commonly thought that this acid is no other, than the vitriolic, fomehow or other difguifed by the. inflammable principle;, to which fome have added ano- ther, called by them a mercurial earth. The reafons given for this fuppofition, however, are but. very flight, confifting chiefly in the refem- blance between the volatile vitriolic acid and the ma- rine, both in the white colour of their vapours, and likewife the great volatility of both. A s to the exift- ence of that principle called a mercurial earth, it hath never been pi-oved ; and, till that time, can never be allowed to be an ingredient in the compofition of any fubftance whatever. As we do not remember to have read of any experiments where the marine acid was direftly produced from that of vitriol, we fliall con- tent ourfelves with relating one very remarkable faft. which happened to fall under our own obfervation. As vitriolated tartar, or Glauber's fait, when fufed with charcoal- duft, is converted into an hepar fui- phuris, attempts have been made on this principle to feparate the pure alkali from the refiduum of Glau- ber's fpirit of nitre and fpirit of fait. In an attempt of this kind, which, by the bye, proved unfuccefsful,, as all others of the fame kiad muft do, 30 or 40 pounds 78a Marine ; acid. 783 Marineja- cid thought: to be the 1 fame with the vitrio- lic. 784 A tranfmu^ Nation. Fraaice. C H E M Msiine pounds of the mafs for Glauber's fait were fufed in a Itrong iron pot, with a fufficient quantity of common coal powdered and fifted. As the quantity of pow- dered coal was pretty large, the mats was thereby hindered from flowing into thin fiifion ; and, that the whole might be perfeftly alkalifated, it was frequent- ly flirred up with an iron ladle, and kept very intenfe- ly heated for fome hours. The mafs was now taken out by means of an iron ladle, and laid on a flat fl:one'; and, as it was but half fluid, every ladlcful concreted into a black irregular faline mafs, which had the ap- pearance of a cinder ; but which, hov.'ever, confifted of an hepar fulphuris mixed with fome coal-duft. As there was a confiderable quantity of this matter, and the ladlefuld were thrown at random above one ano- ther, it fo happened, that between two or three of the pieces, a kind of cliimney was formed, fo that there being a fraall draught of air through the interftices, and the maircs containing a quantity of coal duft, the internal parts were in a hate of ignition, while the cx- letnal were quite cold. From thefe ignited places a white fume-arofe; which being coUefied on the colder mafies, alTumed the form of white flowers. Thefe were found to be genuine fal ammoniac, compofed of a vola- tile alkali and marine acid ; both of which v/e have the greateft reafon to think were produced at that very time, and that a double tranfnuitation took place ; namely, of the vitriolic acid into the marine, and of the fixed alkali into the volatile. Our reafons for be- ing of this opinion are, i. That the matter had been fubjefted to fuch an extreme and long continued heat, that, had any fal ammoniac been pre-exittent in the mixture, it muft have certainly been diflipated, as this fait always fublimes with a degree of heat below ig- nition. 2. Though the matter was taken out of the pot of a very intenfs red heat, fo that the faline part was evidently melted, yet no aminoniacal fume iffued from it at that time, nor till the mafles had been for fome time cxpofed to the air, and were become cool, excepting only thofe inter fl.ices where the air kept up a burning heat, by a fmall draught being formed from the fitua- tion of the faline malTes. 3. In thofe ignited places, when cool, the fixed fait was entirely decompofed,. neither alkaline fait, Glauber's fait, fixed alkali, nor fulphur remaining ; but the whole was confumed to a- kind of ferruginous aflies. We are therefore of opi- nion, that the marine acid and volatile alkali are, in fome cafes, mere creatures of the fire, and mofl: com- monly produced at the fame time, from the flow com- buftion of mineral fubftances. Hence, where heaps of hot cinders are thrown out, fmall quantities of the true fal ammoniac are always formed, when the ignited ones happen to fall in fuch a manner as to occafion a fmall draught of air through them. The marine acid, or fpirit of fait, is weaker than either the vitricdic or nitrous ; though Dr Piieftley ▼ations on hath obferved, that, when concentrated to the utmoft mamca- ^g^^ree, in which flate it was pcrfetlly invifible and elaftic as air, it was then able to feparate the nitrous acid from an alkali. In fome other cafes, too, it ap- pears not only fl;ronger than the nitrous, but even than the vitriolic; of which we fliall take notice in courfe. — Mr Berthollet fays, that he has been able alfo to procure the marine acid in a folid fl:ate, by diftilhng it in Mr Woulfe's^apparatus, kept perfedtly cool with ice. 7S5 Dr Prieft- ley's obfer- I S T R Y. 477 The yellow colour of the marine acid is fometimes Marine owing to iron, which may be precipitated from it by^*^'^ means of an alkali. In certain cafes, however, it is^^^^j^^^^ ^" obfer-ved to have a much darker and neaidy a brown ' colour, without containing the fmalleft particle of this metal. — Mr Dollfufs is of opinion, that the yellow co- lour of the marine acid is owing to a portion of de- phlogifl:icated air which it generally contains. A pretty ftrong pr-oof that it emits this kind of air indeed is, that a candle will biirn longer in a bottle containing fome marine acid, than it wdll in an equal quantity of common air. I. To pi-ocure the Marine Acid by means of the Vi- triolic. 726 Put any quantity of fea-falt into a tubulated glafs- Spirit of retort, to which a large receiver is firmly luted, ha-^^'^"^*^^' ving a quantity of water in it, more or lefs as you want your fpirit of fait to be more or lefs ftrong. Having placed your retort in a fand-bath, take of con- centrated oil of vitriol half as much as you put fait into the retort. Through the aperture in the upper part of the retort, pour a fmall quantity of the vitrio- lic acid ; a violent efi'ervefcence will immediately a- rife, and white vapours will afcend, and come over into the receiver. Thefe vapours are the marine acid in^ its moft concentrated ftate.; and, as they are. very greedy of moifture, they will unite with the water in- a very fliort time, unlefs too much oil of vitriol is put in at once ; in which cafe, part of them will be difli- pated through the fmall hole in the receiver. When you perceive the firft fumes condenfed, add a httle more ^ oil of vitriol, taking care to ftop the aperture of the retort as foon as you drop in the vitriolic acid, that the marine acid may not efcape. Continue this by- intervals,, till your acid is all put in ; and then make a very gentle fire, that the retort may be no warmer tlian the hand can bear. This degree of heat muft be continued a long time, otherwife very much of the acid will be loft. To per-form this operation perfeftly,. no more acid fliould be forced over-, than what the wa- ter in the receiver can take up ; and by this means the operator's patience will be rewarded with a vaftly larger produce of acid than can be procured by hafty diftillatrofti When the vapours become a little more fixed, a greater heat is neceflary, but nothing equal to what the nitrous acid requires. For diftilling fpi- rit of fait, Mr Wiegleb recommends four pounds of. oil of vitriol to fix of common fait. — It may alfo be obtained from the bittern remaining after the cry ftallization of common fait, by adding one pound of oil of vitriol to five of bittern. It may even be ob- tained from this hquid by fimple diftillation without any additional acid; but a violent fire will then be ne- ceflary, and it is almoft impoflible to prevent the li- quor from fwelling and running over the neck of the retort in the beginning of the procefs. The marine acid cannot be procured by means of Why dilliU combinations of the vitriolic acid with metallic and Ration of earthy bafes, as the nitrous is ; for though, by of calcined viti-iol, for inftance, the marine acid is ef-perasdoCs feftually expelled from its alkaline bafis, yet it imme-noc fuc- diately combines with the calx of iron left by the vi-ceed. triolic acid, and not only adheres obftinately, but even fublimes the metal ; fo that what little I'pirit tan be 47^ C H E M I Marine obtained, is never pure. This inconvenience is not its"combi- ^^^^^ ^K^" uncalcined copperas is made ufe of : nations. ^'^^ the marine acid has a very llrong attraction to y—— water ; which partly diffolvcs its union with the me- talline calx. If gypfum is ufed, inllead of calcined vitriol, not a drop of fpirit will be obtained. Alum and fal catharticus amarus anfwer better. S T R Y. Pra(5lice, 788 II. To procure the Marine Acid by means of the A^ua regis. ^ Take equal quantities of fca-falt and Glauber's fpi- rit of nitre ; put the fait into a retort, and pour on it the nitrous acid; let them ftand for 10 or 12 hours; then dillil with a gentle heat; an acid Hquor will come over, which is a compound of the nitrous and marine acids, called aqua-regis.^ When the diilillation is ii- nifhed, and the veffels cooled, pour back the dillilled liquor on the mafs which is left on the retort, and diftil again : the fecond produce will be more of the nature of fpirit of fea-falt than the former. Continue to do this, pouring the diftilled liquor either on the mafs left in the retort, or upon frefh fea-falt, till you ©bferve that no nitrous acid arifes. No experiments have been made on this fpirit of fait, by which we can judge whether it is different from that procured by the vitriolic acid or not. III. To procure the Marine Acid, by diftilling Salt Spirit of fait Put into a retort any quantity of common fait which t''"!^' has not been dried, and dillil in a fand heat till no- thing more wiU come over. In the receiver you will have a liquor confidcrably more acid than vinegar, in weight about the fourth part of the fait employed. On the dry fait left in the retort, pour fome water, fomewhat lefs in quantity than the liquor which came over. Let it ftand till the fait has thoroughly imbi- bed the moifture, and then diilil again. You will again have an acid, but weaker than the former. Repeat this fix or feven times ; after which you will obtain no more marine acid in this way. It has been thought that fea-falt was capable of total decompofition by means of moifture alone ; but that is found to be a miftake. The reafon of any acid being procurable in this way, is the impurity of the common fait, which is always mixed with a quantity of fal cathaiticus ama- rus, and of marine acid combined with magnefia, from which laft it is feparable by moifture. If a pure fait be formed by combining marine acid with fait of foda, no fpirit will be obtained. IV. To dephlogifticate the Marine Acid. The marine acid, when mixed either with that of nitre or with manganefe, lofes that peculiar fmell by which it is ufually difl;inguifhed, and acquires one much more volatile and fuffbcating. When mixed with the former, the compound is called aqua-regia ; when fub- jeiSled to the aftion of manganefe, the produdl is called dephlogijl'tcatecl fpirit of fait. The method of procuring this acid recommended by Mr Scheele is as follows ; Mix common muriatic acid in any quantity with levi- gated manganefe in a glafs retort ; to which lute on with blotting paper a receiver capable of containing about 1 2 ounces of water. Put about two drachms of liquid into it ; and in about a quarter of an hour, or fomewhat more, a quantity of elaftic fluid, which is the 790 Marine a- acid de- phlogifti- cated by that of nitre or by manganefe. 791 Scheek's method of dephl;igiA- yticating it by maKga- true dephlogifticated fpirit of fait, will pafs over, and Marine communicate a yellow colour to the air in the receiver; f^*^'^ after which the latter is to be feparated from the i'*^- nations" tort. If the paper has been clofely applied, a quantity ^ j- of the air will now rufti out with fome violence ; a cork mult therefore inftantly be put into it, and another re- ceiver applied, having in like manner two drachms of water in it, which will alfo be filled in a fliort time ; and thus may feveral phials full of this aerial acid be procured in a ftiort time. Care ftiould be taken, that the retort be placed in fuch a manner as that any drops of liquid which chance to arife may fall down again in- to it. The water put into the receivers feems to con- dcnfe the vaoours of the marine acid ; and it is moil proper to ufe frnall receivers, on account of the great quantity of vapour which is loft at every operation. The effefts of this dephlogifticated marine acid, Prnpmies which can fcarcely be condenfed into a liquid, are, i.ot dephlo- The lute is corroded in diftillation, and the corks be- H^-'^'.'-^'^^ come yellow, as from aquafortis. 2. Paper coloured ^^j'^"' '^^ with lacmus becomes nearly white, as well as all vege- table red, blue, and yellow flowers ; and the fame change is likewlfe produced upon the green colour of vegetables ; nor can any of thefe colours be recovered either by alkalies or acids. 3. Exprefted oils and ani- mal fats, expofed to the vapour, become as tenacious as turpentine. 4. Cinnabar grew white on the fur- face ; and when it was waflied, a pure folutlon of corro- five fubhmate was obtained ; but fulphur was not changed. 5. Green vitriol became red and deliquef- cent ; but white and blue vitriol remained unchanged. 6. Iron filings were diffolved ; and on evaporating the folution to drynefs, comm.on muriatic acid was obtain- ed by diftillation with marine acid. 7. In like man- ner all the metals, even gold itfelf, were diflblved; and by precipitation with volatile alkali, the folution of gold yielded aurum fulmlnans. 8. The cauftic volatile alkali produced a white cloud, and emitted a number of air-bubbles, which on burfting difcharged an elaftic vapour. 9. Fixed alkali was changed into common fait, which decrepitated in the fire. 10. Arfenic be- came dehquefcent, infefts died, and fire was inftanta- neoufly extingulfticd in the vapour. Thefe phenomena pioceed from the ftrong attrac- Miftake c£ tion of dephlogifticated marine acid for the phlogifton Stalil ac- it has loft; and which Is one of the eftential parts of it, counted for. without which it can fcarce at all be condenfed into a liquor. " Perhaps (fays Mr Scheele) Stahl obtained fuch a dephlogifticated muriatic acid by means of iron; and from the yellow colour of the cork was led to fup- ps like the fcales of fifhes ; leaving be- hind a fubftance which confitU of thin, glofly plates, like talc. . ' The folution of iron in fplrit of fait, with the addi- tion of fome fpirit of wine, is ufcd in medicine as a corroborant, under the name of tinchtra martis.^' The fublimate of iron is alfo ufed for the fame purpofe, and called ens veneris, or Jlores mart'utles. It is com- monly direfted to be prepared by fubliraing iron fi- lings and fal ammoniac together. In the procefs, the fal ammoniac is partly decompofed, and a cauftic al- Flores mar- kallne liquor diilils. Then the undecompofed fal am- tiales. moniac, and the martial fublimate above mentioned, arife together. The fublimate has a deeper or lighter yellow colour, according as it contains more or lefs iron. The namef/zj veneris Is improper. It was given by Mr Boyle, who difcovered this medicine. He imagined it to be a preparation of copper, having made ufe of a colco- thar of vitriol containing both iron and copper. A me- ad 808 haftily. When the fubhmate begins to form, the. aflies muft be removed a little, from the fides of the glafs, or the glafs caiitioufly raifed up a Httle from the afties.. (Thislaft, we think, is highly imprudent. ) Laftly, the laboratory muft have a good chimney, ca- pable of carrying off the noxious fumes.^ The above- mentioned quantities commonly yield 360 pounds of fubhmate; the 280 pounds of quickfilver gaining 8a from the 200 pounds, of fea-falt. . The makers of fub- limate CHEMISTR Y. Sir Obferva- limatc in France, he fays, employ, in one 'operation, only 20 pounds of mercury. This they diflblve in aquafortis, evaporate the folution to drynefs, mix the dry matter with 20 pounds of decrepitated fea-falt and 60 of calcined vitriol, and then proceed to fubli- mation. The above proceffes, particularly the lad, are un- with arfe- cic. tions on the exceptionable as to the produftion of a fublimate per- m^h^^d'' ^'^'-^^y corrofive ; but the operation, it is evident, muft be attended with confiderable difficulty, by reafon of the large quantity of matter put into the glafs at once. We muft remember, that always on mixing a volatile fait with a quantity of fixed matter, the fiiblimation of it becomes more difficult than it woiild have been had no fuch matter been mixed with it. It is of confiderable confequence, therefore, in all fublima- tions, tG make the quantity of matter put into the glafs as little as poffible. It would feem more pro- per, inftead of the calcined vitriol ufed in the pro- ceffcs laft mentioned, to diffolve the mercury in the vitriolic acid, as direfted for tuibith mineral, and fublime the dry mafs mixed with nitre and Cea- S.8 fait. Siippofeda- It has been faid, that corrofive fublimate mercury dulteration was frequently adulterated with arfenic ; and means have even been pointed out for dctefting this.fuppo- fed adulteration. Thefe means are, to dilTolve a little of the fufpefted fait in water, and add an alkaline lixivium to precipitate the mercury. If the^precipitate was of a black colour, it was faid to be a certain fign of arfenic. This, however, ifhows nothing at all, but that either the alkali contains fome inflammable mat- ter, which, joining with the precipitate, makes it ap- pear black ; or that the fublimate is not perfeflly cor- rofive , for if a volatile alkali is poured on levigated mercurius dulcisy the place it touches is inftantly turned black. Mercurius dulcis, or calomel, is prepared by mixing equal parts, or at lead three of quickfilver with four of fublimate ; after being thoroughly ground together in a glafs or ftone mortar, they are to be poured through a long funnel into a bolt-head, and then fub- limed. The medicine has been thought to be im- proved by repeated fubllmations, but this is found to be a miftake. Mr Beaume has found that mercu- rius dulcis cannot be united with corrofive fubh'mate in the way of fublimaiion ; the former, by reafon of its fuperior volatility, always rifes to the top of the veffel. XII. With Zinc, This femimetal dllTolves readily in the marine acid into a tranfparent colourlefs liquor. It is volatilized, as well as moft other metallic fubftances, by this combination, as appears from the following procefs delivered by Neumann. *' Equal parts of filings of zinc and powdered fal ammoniac being mixed together, and urged with a gradual fire in a retort ; at firft arofe, in a very gentle heat, an exceffively penetrating volatile fpirit, fo ftrong as to ftrike a man down who fhould inadvertently re- ceive its vapour freely into the nofe. This came over in fubtile vapours, and was followed by a fpirit of fait in denfe white fumes. In an open fire, white flowers fucceeded ; and at length a reddrfh and a black butter. Ib the bottom of the retort was found a portion of the 819 Mercurius elulcig. 820 Zinc vola tilized. zinc in its metalline form, with a little pondcfows and Marine fixed butyraceous matter, which hqiiefied in the air. The lump was far more biittle than zinc ordinarily is; potions of a reddifli colour on the outfide, and blackifli within. The bottom of the retort was variegated with yellow and red colours, and looked extremely beautiful. The remaining zinc was mixed afrcfli with equal its weight of fal ammoniac, and the procefs repeated, A vola- tile alkaline fpirit and marine acid were obtained as at firft ; and in the retort was found only a little black matter. When the zinc was taken at firft in twice the quantity of the fal ammoniac, the part that preferved its metallic form proved lefs brittle than in the forego- ing experiment, and the retort appeared variegated in the fame manner. On endeavouring to reftify the butter, the retort parted in two by the time that one half had diftilled." The nature of this combination is unknown. Xm. With Regulus of Antimony . This femimetal can- Butter of not be united with the marine acid unlefs the latter is^ntimonf, in its moft concentrated ftate. The produce is an exctffively cauftlc thick liquid, called butter of antimo- ny. The procefs for obtaining this butter is fimilar to that for diftilllng the fmoking fpirit of Libii- vius. Either crude antimony, or its regulus, may be ufed : for the fpirit of fait will attack the reguhne part of this mineral without touching the fulphureous. Three parts of corrofive fublimate are to be mixed with one of crude antimony ; the mixture to be di- gefted in a retort fet in a fand heat ; the marine acid in the fublimate will unite with the reguhne part of the antimony. Upon increafing the fire, the regulus arifes, diifolved in the concentrated acid, not into a h- quid form, but that of a thick unftuous fubitance like butter, ^ from whence it takes its name. This fub- ftance Hquefies by heat, and requires the cautious ap- plication of a live coal to melt it down from the neck of the retort. By redification, or expofure to the air, it becomes fluid like oil, but ftill retains the name of butter. If water is added to butter of antimony, cither v/hen in a butyraceous form, or when become fluid by re£tification, the antimony is precipitated in a white power called ponuder of algaroth, and improperly jnercurim vita;. This powder is a violent and very un- fafe emetic. The butter itfelf was formerly ufed as a cauftic ; but it was totally negleded in the prefent pradlice, until lately that it has been recommended as the mcil proper material for preparing emetic tartar. (See below.) Mr Doixufs recommends the fcI:owing method as the beft for making butter of antimony ; viz. two ounces and a quarter of the grey calx of aa^ timony, eigiit ounces of common fait, and fix of acid of vitrioL By dliliUing this mixture, ten ounces of the antimonial cauftic were obtained ; and in order to determine the quantity of metal contained in it, he mixed two ounces of the cauftic with four ounces of water j but thus fuch a ftrong coagulum was formed, that he was not able to pour ofl^ any of the water even after ftanding 24 hours. The precipitate, when care., fully dried, weighed, 50 grains. The refult was much the fame when glafs of antimony was ufed, only that the precipitate was much more confiderable ; half aij ou«ice of the cauftic then yielding 60 grains, though at aBotheif time only 50 grains were obtained. In the re- 3-^2 fiduum 4S4 Marine Acid and its C. mbi- i)ati( ns. CHEMISTRY. Pradlce. 82a tic ink. Oil cf atfe ■ 8a4 Marine ether. fiduum of tlie former experiment he found 30 grains of an earthy fubftance, chiefly a combination of calcare- ous earth with muriatic acid. V/hen the mercurius vitse precipitates, the union be- tween the marine acid and regukis is totally difTolved ; fo that the pov/d'^r, by frequent walhings, becomes per- feftly free from every particle of acid, which unites with the water made ufe of, and is then called, very improperly, phUofoph'ic fplr'it of 'yitriol. XIV. With Regulus of Cobalt. Pure fpirit of folt dif- folves this femimetal into a reddifh yellow liquor, which immediately becomes green from a very gentle warmth. Gn faturating the folution with urinous fpirits, the precipitate appears at firft white, but aftei-wards be- comes blue, and at length yellow. If the nitrous acid is added to folutions of regulus of cobalt, they affume a deep emerald green when moderately heated, and on cooling become red as at firft. Duly evaporated, they yield rofe-coloured cryftals, which change their colour By heat in the fame manner. This folution makes a curious fympathetic iijk, the invention of which is commonly afcribed to M. Hellot, though he himfelf acknowledges that he received the firft hint of it from a German chemift in 1736. Any thing wrote with this folution is invifible when dry and cold ; but af- fumes a fine green colour when warm, and will again difappear on being cooled ; but if the heat has been too violent, the writing ftill appears. M. Hellot ob- ft rves, that if nitre or borax be added to the nitrous folution, the charadlers wrote with it become rofe- culoured when heated ; and if fea-falt is afterwards pafTed over them, they become blue ; tliat with alkali fufficicnt to faturate the acid, they change purple and red with heat. — A blue fympathetic ink may be made from cobalt in the. fol)x)wing manner. Take of an earthy ore of cobalt, as free from iron as pcfTible, one ounce. Bruife it, but not to too fine a powder. Then put it into a cylindrical glafs, with 16 ounces of diftil- led vinegar, and fet the mixture in hot fand for the fpace of fix days, ttirring it frequently ; or elfe boil it direftly till^there remain but four ounces. Filter and evaporate it to one half. If your folution be of a rofe colour, you may be certain that your cobalt is of the right fort. A red brown colour is a fign of the folu- tion containing iron ; in which cafe the procefs fails. To two ounces of the folution thus reduced, add two drachms of common fait. — Set the whole in a warm place to diffolve, and the ink is made. XV. With Regulus of Arfen'jc. This fubftance is foluble in all acids ; but the nature of the compounds form.ed by fuch an union is little known. If half a pound of regulus is diftilled with one pound of corro- five fublimate, a thin fmoking liquor and a butyrace- ©us fubftance will be obtained, as in making the fmo- king liquor of Libavius. By repeated reftifications, this butter may be almoll all converted into fpirit. If equal part-s of the arfenic and fublimate are ufed, a pon- derous black oil comes over along with the fpirit, which cannot be mixed with ,it. By reftificatlon in a clean retort, they will become cl^ar, bnt ftill will not incor- porate. If they are now returned upon the red mafe remaining in the firft retort, and again diftilled, a much more ponderous oil. than tlw; former will be ob- tained. XVI. With Infammabh Suhjhnccj. The acid of fea- falt is very little difpofed to contraft any union with Marine the phlogifton, while in a liquid ftate ; and much lefs?^^"^J^'J|J.^ fo, even in its moft concentrated ftate, than either thi j,^^;^.,,,^^ vitriolic or nitrous. Mr Beaume, however, has found, — y-— J that a fmall quantity of ether, fimilar to that prepared with tlie vitriohc and nitrous acids, may be obtained by caufing the fumes of the marine acid unite with thofe of fpirit of wine. Others, and particularly fome German chemifts, attempted to make this liquor, by employing a marine acid previouOy combined with me- tallic fubilances, fuch as butter of antimony. The fmuking liquor of Libavius fucceeds beft. If equal parts of this liquor and highly reftlfied fpirit of wine are diftilled together, a confiderable quantity of true ether is produced ; but which, hke the vitrio- lic and nitrous ether, muft be reftified in order to its greater purity. The tin contained in the fmoking li- quor is feparated and precipitated in white powder. In this procefs, the acid is probably more difpofed to unite with the fpirit of wine, by having already be- gun to combine with the inflammable principle of the metal.— For marine ether, Mr DoUfufs recommends to put into a retort four ounces of digeftive fait previouf- ly well dried and powdered, and two ounces of maa- ganefe ; pouring upon this a mixture of five ounces of fpirit of wine and two of oil of vitriol ; the firft five ounces and a half of tht diftilled liquor being poured back on the refiduum, and the whole afterwards drawn ofl" by a gentle beat. The fpirit of fait thus obtained had a very penetrating agreeable odour, fomewhat like that of nitrous ether ; and at firft fwam upon the top of water, but at length mixed with it on being agi- tated for a long time. Towards the end of the diftil- lation a little oil was obtained, which did not mix wjlh the water; and by the addition of four ounces more of . fpirit of wine, more of the dulcified acid was obtained. With regard to tltis klfid of ether, however, Mr Weftrumb denies that it can be made by any me- thod hitherto known ; and infifts, that all the liquids as yet produced under the name of marine ether are in reality dulcified fpirit of fait, and not true ether, which will fwim on the top of water. „ Dr Prieftley has obferved, that the pore marine acid, ^^^^^^^;^^ v^hen reduced to an invifible aerial ftate, has a ftrongfor phlogi- affir^Ity with phlogifton-; fo that it decompofes many fton. fubftances that contain it, and forms with them an air permanently inflammable. By giving it more time, it will extradl phlogifton from dry wood, crufts of bread not burnt, dry flefli ; and, what is ftill more extraordi<- nary, from flints. From what has been above related, it appears that the dephloglfticated fpiiit of fait has a very ftrong attraftion for phlogifton. Eflenllal oil of mint abforbtd the marine acid air pretty faft, and prefently became of a deep brown co- lour. When taken out of this air, it was of the con- fiilence of treacle, and funk in water, fmelling different- ly from what it did before; but ftill the fmell of the mint was predominant. Oil of turpentine was alfo much thickened ; and became of-a deep brown colour, by being faturated with aeid air. Ether abfotbed the air very faft ; and became firft of a turbid white, and then of a yellow and brown colour. In one night a confiderable quantity- of ftrongly inflammable- air was produced. Having once faturated a quantity of ether with acid ■air. Praaice. C H E M I Marine air, he admitted bubbles of common air to it, through the quickfilvty by -which it was confined, and ob- ferved tliat white fumes were made in it, at the en- trance of every bubble, for a confiderable time. Ha- ving, at another time, faturated a fmall quantity of ether with this kind of air, and the phial which contain- ed it happening to be overturned, the whole room was iiiiiantly fdlcd with a white cloud, which had very much the fmell of ether, but peculiarly offenfive. Opening the door and window "of the room, this light cloud filled a long paffage and another room. The ether, in the mean time, was leemingly all vanifh- ed : but, fometime after, the fuvface of the quickfil- ver in which the experiment had been made was co- vered with a very acid liquor, arifing probably from the moiliure in the atmofphere, attra^ed by the acid vapour with which the ether had been impregnated. This feems to (how, that, however much difpofcd the marine acid may be to unite with phlogiftic mat- ters wlien in its aerial ftate, the attraftion it has for them is but very flight, and ftill inferior to what it has for water. Camphor was prefently reduced into a fluid ftate' by imbibing this acid air ; but there feemed to be fome- thing of a whitifh fediment in it. After continuing two days in this fituation, water was admitted to it, upon which the camphor immediately refumed its for- mer folid ftate ; and to appearance was the fame fub- ftance that it had been before. Strong concentrated oil of vitriol, being put to ma- jinc acid air, was not at all affefted by it in a day and anight. In order to try whctlier it would not have more power in a condenfcd ftate, it was comprefl"ed with an additional atmofphere ; but, on taking off this, the air expanded again, and was not in the leaft di- minifhed. A quantity of ftrong fpirit of nitie was alfo put to it without any fenfrble efFeft. From thefe laft experiments it appears, that the marine acid is not able to diflodge the other acids from their union with water. Befides the acids already mentioned, Mr Hombcrg defcribes an artificial one generated by mixing two ounces and a half of luna cornea, wift an ounce and a half of tin calcined alone and without addition, by means of fire. The mixture is to be expofed to a- naked fire in a coated retort, of which two thirds ought to be left empty ; when a browniih matter, an ounce and a half in weight, will adhere to the neck of the retort. This matter is tin combined with the marine acid, and the refiduum is filver deprived of the fame acid, which may therefore now be melted together without any lofs. The fublimate^ well powdered and dried, is to be equally divided into two phials, and fublimed ; by. repeating which operation two or three times, a volatile fait, of an acid nature, very white and tranfparent, is obtained. The refiduum of thefe fubli- mations is always calx of tin. f 4. 0/" the Fluor Acid. Fhft dtfco- '^"'^ ^^^^ difovcred fome time ago by Mr Mar- vered by ' graaf, and more fully inveftigated by Mr Scheele. Mr Mar- The experiments by which it was originally produced, g'aaf its properties afccrtaincd, are as follows : How^^re ^ Two ounces of concentrated vitriolic acid were 1 arcd.^' poured upon an equal quantity of fluor, which b^d hten s T R Y. 485 ad8a5 >>'fw ac d difcovcred by Mr H(jiTibe-g. previoufly pounded in a glafs mortar, and then put in- F'-uo'' Acid to a retort, to which a receiver was adapted, and the q^^^^'^jj^j, j infture clofed with grey blotting-paper. On the j^^.'^s, ' application of heat, the mafs began to tfF-rrverce and J fwell, invifible vapours penetrated every where through the joining of the vtfiels, and towards the end of the procefs white vapours arofe, which covered all the in- ternal parts of the receiver with a white powder. — The mafs remaining in the retort was as hard as a - ftone, and could not be taken out without- break- ing the veflel. The lute was quite corroded and friable. IL The procefs was repeated exactly in the fame manner, excepting only that a quantity of diftilled wa- g^g ter was put into the receiver. A white fpot foon be- Forms a gan to form on the futface of the water, juft in the white ear- centre, and immediately under the mouth of the re- ^^^^^j^^^'^g^. , tort. This fpot continually increafed, till at laft it co- ' vered the whole furface of the water, forming a pixtty thick cruft, which prevented the communication of the. water with new vapours that came over. On gently agi- tating the receiver, the cruft broke, and fell to the bot- tom ; foon after whieh a new cruft like the former was produced. At laft the receiver, and foon after the re- tort alfo, became white in the infide. The veflels, when cooled, were found much corroded internally. In the receiver was an acid liquor mixed with much white matter, feparable by filtration. _ III. This white matter when edulcorated and dried, which has firowed itfelf to be filiceous earth, by the foUov/ing the proper- properties. 1. It was rare, friable, and white. 2. '^'"^^ was not fenfibly foluble in acids. 3. It did not make*^^®"^ a tough pafte witli water, but was loofe and incohe- rent after being dried. 4. It diftblved by boiling in lixivium tavtati, and the folution in cooling afl'umed a gelatinous confiftence. 5. In its pure ftate it fuCFered no change in the ftrongeft heat ; but when mixed with alkali, it boiled, frothed up, and formed a glafs in a melting heat- 6. It diffulvcd in borax without fwelHng. _ g p IV. To determine whether this earth was formed Scheelc's during the procefs, he poured vitriolic acid upon pow- experiment d«red fluor contained in a cylinder of brafs which was to deter- clofed exaftly with a cover, after having fufpended "^.-^-^'^^f over the mixture an iron nail and a bit of charcoal, ^^it earth. On opening the veflel two hours afterwards, he found the nail and charcoal unchanged ; but on moiftening them, he found both covered with a white powder in a fliort time. This powder had all the pr operties of IIH- ceous earth; and as in the experiment he had made no ufe of glafs vefi"els, he concluded that it did net pro- ceed from the glafs vefTels, as might have been fufpeft- ed from their being fo much corroded, but was gene- - rated in fome other way. , V. Having recompofed fluor by faturating the a- Artificial cid with calcareous earth, he treated the compound in fluor yicl(?s the fame manner as the natural fluor, with a fimllar ^ ^•f^^''^'' refult ; and repeating the experiment five times over, ^''* he conflantly found the filiceous earth and.acid dimi- nifti confiderably, fo thai at laft fcarce any mark of acidity was left. Thence he concluded, that all the fluor acid united itfelf by degrees with the vapours of the water, and thus formed the filiceous earth. " It may bt objtAed (fays Mr Scheele), that the fluor acidis per- h;ips eadv united by nature with a hut: fiiicroii"- p'.'W- d-.T., 486 G HEM I S T R Y. I^iaaice. ^'l'','^!' /^^'"^ der, which it volatilizes, and carries over in diftillation, Mr Scheele proved by the following experiment. Up- Fluor Acid 832 IVir Scheele's condiifion that the earth pro- but leaves it as foon as it finds water to unite with, juil as muriatic acid parts with the regulus of antimo- ny, when butter of antimony is dropped into water. But if this was the cafe, the fluor acid would leave the whole quantity of filiceou3 earth thus combined ■with it in the firfl diilillation, and therelore fliow no mark of its prefence in the following proceflcs. When I put fpirit of wine into the receiver inftead of water, no filic* MIS earth was pioduced ; but the alcohol be- cause four. When I put an unftuous oil into the re- ceiver, all the fluor acid penetrated through the crevi- ces of the lute, and neither united with the oil, nor produced a filiceous earth. This happened alfo when acid of vitriol was put into the receiver. If therefore the filiceoua earth was not a prcduiSl of each diftillation, biit, being previoufly contained in the acid,wasonly de- ceeds from pofited from it in confequence of the union of the acid an union of with a third fubftance, I think the filiceous earth ought wilhwa ^q^s^^y to appear when alcohol was put into the recei- '^ver, with which it unites, as well as with water ; but as this does not happen, I conclude that not all the fi- •liceous earth which is depofited upon the furface cf water during the diftillation of the lluor acid, was pre- vioufly diflolved in this acid." This opinion of Mr Scheele did not meet with ge- neral approbation. M. BouUanger endeavoured to IJou II anger, fl^O'Jf, that the fluor acid is no other than the muria- Monnec, ^-^^ intimately combined with fome earthy fubftance ; and Mr Monnet maintained that it is the fame with that of vitriol volatilized by fome extraordinary con- nexion with the fluor ; which opinion was alfo maintained by Dr Prieftley. Mr Scheele contefted nionsfliowm thefe opinions, but found much greater dilncajlty in to be erro- f^pporting his own opinions than in overthrowing Mr Schede. thofe of his adverfaries. BouUanger infifted that fluor acid precipitates the folutions of filver and quickfilver, g^j producing luna cornea with the former, and mer- riuor acid curius dulcis with the latter. Mr Scheele owns proved to that fluor acid precipitates both thefe metals, but nm^w"'^^^ precipitate obtained is in very fmall quantity, and the little that is produced arifes only from a fmall quantity of fea-fak with which the fluor, as well as all other calcareous fubftances, is generally mixed. The greateft part of the acid, therefore, will not precipitate the folutions of thefe metals, which it ought to do up- on Mr Boullanger's hypothefts. Mr Scheele then proceeds to fliow a method of feparating this fmall q;j* itity of marine acid from that of fluor. A folu- tion of filver made with nitrous acid is to be precipi- tated with alkali of tartar, and as much acid of fluor poured upon the edulcorated powder as is fufficient to give an excefs of acid ; after which the folution is to be filtered. This folution of filver in fluor acid is then to be dropped into that acid we defire to purify, till no more precipitation enfties; after which the acid is filter- ed through grey paper, and diftilled to drynefs in a glafs retort. The aqueous part comes over firft, but is Joon followed by fluor acid, which covers the infide of both the veflcls, together with the furface of the water in the receiver, with a thick filiceous cruit. The acid, thus reftified, does not precipitate folution of filver in the leaft, nor otherwifc {how the fmalleft fign of muri- atic acid. That the fluor acid is different from that of vitriol, Contefted by Meffrs 834 Their opi- from that of fea-falt, on one ounce of pure levigated fluor with alcohol, he ^'"^ poured three ounces of concentrated oil of vitriol, and ^'^'^^''"'2- diftilled the mixture in a fand-bath, having previoufly j put 12 ounces of diftilled water into the receiver. He 2^6 then took other tlirce ounces of the fame acid diluted And from with 24 ounces of water, to which he afterwards ad- ^''.^^ °^ ded hxivium tartari previoufly weighed, till he at-^"^'"'* tained the exaft point of faturation. After the diftil- lation he weighed the remaining lixivium ; having kept up fuch a degree of heat for eight hours as was not fufficient to raife the vitriolic acid. On breaking the retort, and reducing the mafs to powder, he boiled it in a glafs veflTel with 24 ounces of water for fome mi- nutes ; after which he added jufl; as much lixivium tartari as he had found Ijefore to be requifite for the faturation of three ounces of the vitrioHc acid, and continued the boiling for a few minutes longer. On examining the folution, it was found to contain a vi- triolated tartar perfeftly neutralized, neither acid nor alkali prevailing in any degree ; which fliowed that no vitriolic acid had paffed into the receiver. The faline matter being then extrafted with hot water, the re- maining earth was found to weigh gl- drachms. Two drachms of this diflolved in muriatic acid, excepting only a fmall quantity of matter which feemed to be fluor undecompofed, and which on being dried weigh- ed only nine grains. Into one part of this folution he poured fome acid of fugar, and into another vitriolic acid. The former produced faccharated hme, and the latter gypium. A third part was evaporated to dry-f nefs, and left a deliquefcent fait ; and the remaining part of the earth burned in a crucible, produced a real quicklime. Thus it appeared that the real bafis of fluor is quick- Quicklime lime, and Hkewife that the fluor acid is different from the LaOs ©f that of vitriol, as appears further from the following confiderations : i. Pure fluor acid does not precipitate terra ponderofa, nor folution of lead in nitrous acid. 2. The fame acid, when faturated with alkah of tar- tar, evaporated to drynefs, and afterwards melted with powdered charcoal, does not produce any hepar ful- Phuris. _ _ Mr Monnet, in order to fupport his hypothefis, de- Miftake of nies that fluor contains any calcareous earth. In proof Mr Mon- of which he adduces the following experiment: E- net on this qual quantities of alkali and fluor were melted toge-^^^J^'^* ther, with little or no change on the mineral ; for, af- ter having taken away by lixiviation the alkali em- ployed, he diflolved the fluor remaining on the filter in nitrous acid, adding vitriolic acid to the folution ; and becaufe he obtained no precipitate, concluded at once, that fluor contains no calcareous earth. Mr Scheele, on the contrary, affirms that all folutions of fluor yield a precipitate of gypfum whenever vitriolic acid is added to them. He explains Mr Monnet's failure, by fuppofing that he had diluted his folution with too great a quantity of water. Mr Wiegleb, diflatisfied with the hypothefis of wieaieb's Scheele, as well as others, concerning the fluor acid, experi- beean a new fet of experiments on the mineral. Ha- "^^"ts."^ ving firft accurately repeated thofe made by Mr ^ j^g fjjj^ Scheele, he proceeded to inquire into the origin of ceous eart^, the filiceous earth. In the following manner: Having firft weighed the retort deftined for the experiment in Fraaice. C H E M I Floor Acid an accurate manner, and found that its weight v/as two ounces and five drachms, he put into it two oun- ces of calcined fiuor in powder, adding, by means of a glafs tube, 2~ ounces of oil of vitriol. The retort was then placed on the furnace; and a receiver, which when empty weighed two ounces, two drachms, and 30 grains, and now contained two ounces of diftilled water, was luted to it. The diftilladon was conduft- ed with all poflible care, and at laft pufhed till the re- tort grew red hot ; but it was found impoffible to pre- vent a few vapours from penetrating through the lute. Next day the retort, feparated from the receiver, was found to weigh, together with its contents, five oun- ces, five drachms, and 30 gtains ; and confequently had loft in weight one ounce, three drachms, and 30 grains. The receiver, which, with the water, had originally weighed four ounces, two drachms, and 30 grains, now weighed five ounces and three drachms, and had therefore gained one ounce and 30 grains. This gain, compared with the lofs of the retort, Ihows that the retort loft more by three drachms than the receiver gained ; fo that thefe muft have undoubtedly paffed through the luting in form of vapour. To determ.ine the point in queftion, the' empty vef- fels, with what had been put into them, were accurate- ly weighed; when the weights and lofs upon the whole were found to be as follows ; The empty retort Calcined fliior Oil of vitriol S T R Y. 4S7 Total weight before diftillatjon After it Lofs of retDrt The empty receiver weighed The water put into it Total weight before diftillation Total weight after dittillatiou dr. 2 5. 0 2 0 0 2 4 0 7 I 0 5 5 30 I 3 30 2 2 30 2 0 0 4 2 30 5 3 0 Gain of receiver - i o 30 Deducting this gain of weight in the receiver from the lofs of weight in the retort, we find, that three drachms were wanting on the whole, which muft. un- doubtedly, as already obferved, have been diflipated in vapour. The retort being now broken, and the dry earth both in its neck, and arch feparated as accu- rately as poflible, it was found to weigh three drachms; the refiduum ia the retort weighed three ounces, two drachms, and 40 grains. Now, as the mafs in the re- tort had originally weighed four ounces and four drachms, it appeared, by dedufting the refiduum, to have fuffered, on the whole, a lofs of one ounce, one drachm, and 20 grains. To determine the lofs more accurately, the following calculations were made : • ozi dr. gr. The white earth feparated from, the neck and arch of the retort - 030 Gain of the receiver - - i o 30 Loft in vapour - - - - 630 Total 1 6 30 Here. Mr Wiegleb was furprifed to find, that the 3. matter which came from the retort amounted to more Flunr Acid by five drachms ten grains than the mafs in the retort ^■'^ bad loft of its original weight j to illuftrate which it tioas/""" was 'necelFary to weigh the retort and receiver by * themfelves. The pieces of the retort now weighed on- ly one ounce feven drachms and 50 grains ; v^hereas, before the procefs, the weight of the retort was two ounces five drachms. It appeared, therefore, that it had loft five drachms ten grains, the very quantity which had been gained by the receiver. This laft had loft nothing of its original weight. The flujd in the receiver was next diluted with four ouiices of diftilled water, and the whole poured out on a filter, in order to feparate the earthy matter with which it was mixed, and frefh water poured up- on it. to take out all the acid : after which the earth' was dried, and found to weigh 57 grains. The cleaapt- liquor was then diluted with more diftilled water, and afterwards precipitated with fpirit offal ammoniac pre- pared with fiited alkali. A brifk efFervefcence took place before any precipitate began to fall, but ceafed foou after the precipitation took place. The whole mix- ture became gelatinous ; and the precipitate, when dry, weighed two drachms. The whole quantity of earth, therefore, obtained in this procefs amounted to five drachms 47 grains, which is forty-fcven grains more than the retort had loft in weight. This excefs is, by our author, attributed to part of the acid ftill adhering to it, and to the acceffion of fome moifture from the air ; to deter mine which he heated each of the parcels • of earth red hot feparately, and thus reduced them to four drachms 52 grains, which is lefs by 18 grains than the lofs of the retort, and which, he is of opi- nion, muft have efcaped in the three drachma of va- pour. From this experiment Mr Wiegleb concludes, that The earthy the earth produced in the diftillation of fiuor proceeds cruft pro- neither from the fpar nor from a combination of the "^"^^ acid with water, but from the folution of the glafs by^f ,£ "^^1* the fparry acid. To his opinion alfo Dr Crell ac- diftilla^ cedes. "In diftilling fluor (fays he) with oil of vi-veffels. trio), I have found the retort as well as the receiver very much corroded. I poured the acid obtained by the piocefs into a phial furnifhed with a glafs ftopper,, and obferved after fome time a confiderable depofition. I then poured the liquor into another phial like the former; and that it might neither on the one hand attack the glafs, nor on the other compofe fiHceous earth with the particles of water, according to Mr Scheele's hypothefis, I added highly re£lified fpirit of wine. I faw, however, after fome time, another confi" derable depofition. This feemed alfo to proceed from the glafs that had been before diffolved, which the acid let fall in confequence of the gradual combination with * the fpirit of wine ; otherwilc^we muft fuppofe, what to me appears incredible, that the acid decompofes the fpirit, attracts the water, and forms the earth." This fingular acid has been ftill further examined by p^rMayerV Mr Meyer. He informs us, that, among Mr Scheele's examina- experiments, he was particularly ftruck by one in of the which no earthy cruft was obtained, after putting fpi. fl"or acii- rit of wine into the receiver. Mr Meyer repeated this experiment, hoping, that when but little fpirit was put into the receiver, he might be able to procure a new ^ kindof ether. An ounce of finely powdered fluor, which bad been previoufly heated red hot; was put into a-- glafs 488 C H E M I S T R Y. Pradice." Fluor Acid g\.^{^ retort, td which was fitted a receiver contain- 6ombina- '"^ three ounces of highly rcftified French brandy, tions. The diftillation was continued for three hours with * v "" ^ gentle heat; when the acid, having made its way through the bottom, put an end to the procefs. No crull could be perceived on » the furface of the fpi- rit ; but in the place where it had been in con- taft with the receiver there was a thin ring of tranfpa- rent jelly. The fame mixture of oil of vitriol and fluor was therefore again put into a retort of very ftroRg glafs, and the fame fpirit put into the .receiver. The' diftillation was condufted two hours with a gentle, and afterwards with a (Ironger, heat. When it was half over, the fpirit began to change into a thin jelly ; and at the end of the procefs fome firmer pieces were found at the bottom. Thefe were wafhed with fpirit of limine ; and in order to obtain the fpirit together with the acid in a pure Hate, it was put into a large retort, and again fubjefted to diftillation. As the retort grew warm, the opal-coloured fpirit became clear and fvvell>- ed, what remained becoming again gelatinous ; a good deal of earth remained behind, but did not adhere firmly to the retort, which was fmooth in the infide,- though full of fhallow excoriations. It was alfo evident, that the glafs was a£lually corroded, and that the earthy mat- ter is not a mere cruft adhering to the infide» The jelly being thoroughly edulcorated, as well as the earth that remained in the retort after the rectification, and that which was diiTolved in the water precipitated by fpirit of fal ammoniac, the whole quantity amounted ■to two diachms. That which had fcparattd fpontane- oufly was femitranfparent. " As this earth (fays he) ■ihowed the properties of filiceous earth, and the glafs, ■which was fo mui;h corroded, confifts in great meafure of it, the greateft part of it might couie from the glafs, 841 and the reft of it perhapsbe a conftituent part of the fluor iHow to ^ I'tfelf. In order to afcertain this, it was neceffary to ob- Jcid free ^^^^ fluor acid quite free framfiliceousearth. I there- from filice- f^oJ'S expofed the ley, which I had procured by the pre- jpus earth, cipitation of the earth with fal ammoninc, to a gentle evaporation in a fllghtly covered glafs vcftll. The pro- duft was one drachm 56 grains of an ammoiiiacal fait ; the glafs did not appear to have been attacked. Half a drachm of this fait was fublimed in a fmall retort, which, towards the end of the operation, war, laid on the bare fire. No cruft appeared on the furface of the water in the receiver. At the bottom of the retort lay a little flocculcnt earth of a light grey colour, above - ■ which the internal furface was covered with a white pellicle that reftefted various colours ; and in the neck there was a fublimate. The thin pellicle eafily fepa- ' rated in many places from the glafs, which was fmooth beneath, though not without fome fmall fur- i rows. I poured water both upon the ammoniacal fait and cruft ; in confequence of which it acquired a very four tafte, and coloured the tinfture of turnfole red. The white cruft that was left behind undiffolved weigh- ed five grains, and melted into a green glafs without addition. This was nothing but the glafs that had been corroded by the fluor acid ; but as this acid can he fet loofe only by ftrong heat, it had done no more than corrode the glafs, without pafting over along with it in the form of vapour, and then depofiting it again on the water. For, upon pouring two drachms of oil p{ vitriol upon half a drachm of .this ammoniacal fait, a little moiftened, and placed in a glafs retflrt, a great F'.uo-: Acid foam arofe, and the thick vapours that afcended cover- ^J''^ td the water in the receiver with a white cruft. A fcru- Ij^',",'^'"^' pie of the falc on folution, left behind a grain of earth, > ' j which, as I conjecture, it had taken up during the eva- poration in the glafs veflel." Ta prevent this, our author diftilled half an ounce of iluor with an ounce of oil of vitriol for five hours. The crufts were feparated from the water; they weigh- ed, after being well waftied and dried, eleven grains ; they were white and very flocculent ; thirty-two grains of filiceous earth were precipitated from the filtered water: the ley was- then evaporated in a leaden veftel, o and yielded 80 grains of fait. As glafs veflels were no Expctt longer to be trufted, a piece of a gun-barrel furniihed mentsmada with a cover, and terminated by a bent tube, intended to .""'^^ ferve inftead of the neck of a retort, was afterwards vcflcj ufed ; and with this apparatus the following experi- ments were made: li Haifa drachm of the newly prepared fal-ammo- tiiac was diftilled for two hours with two drachms of oil of vitriol, into a glafs receiver containing an ounce of water. No veftige of a cruft could be perceived on the\vater,TDUt fome earth was perceived in the receiver-, wiiere the vapours having afcended through the tube, came into conta£l with the wet glafs ; and here the furface was become fenfibly rough. On the addition of volatile alkali, a few flocculi of filiceous earth, a- mounting only to one-fourth of a grain, were thrown •down out of the water. 2. A drachm of oil of vitriol v added to a drachra and an half of the fait ; but a leaden receiver was now ufed, containing an ounce of water as before. The Vy-ater acquired an unpleafant fmell, but fhowcd no figns of a ci-uft. On tlie addition of fpirit of fal am- Tuoulac, a little-grey -earth weighing half a grain fell to the bottom. 3. A fcruple of this fait, mixed with an equal quan- j^^^ ^^'^^^q. tity of white fand in fine powder, and diftilled v/lth a formed b/ drachm and an half of oil of vitriol, into an ounce of mixinjr v/ater in the leaden receiver, ftiowed no fign ot a cruft. j^^j^*^^^^''^ ' The water had a putrid fmell, and left on the filter two grains and an half of grey earth, which ran under Huor acid, the blow-pipe into a grain of lead. Volatile alkali precipitated five grains of grey earth, which melted on the addition of a little fait of tartar into a black glo- bule, though the blow-pipe alone made no change in it- ^ 4. To 1 3 grains of the fame ammoniacal fait a drachm Dut a "^reat of oil of vitriol and two fcruples of green glafs, broken ore by into fmall pieces, were added. The iron tube had "''".^ P"^* fcarce become warm, when a great cruft of filiceous '^^'^'^^^ earth was perceived on the furface of the water, and the fame appearance on the moift fides of the veftel. It did not, however, feenr to increafe during the re- mainder of the dUHllatlon. A grain and a quarter of earthy matter remained on the filter, confifting partly- of white films, which ran under the blow-pipe into a greenifti glafs. J. To afcertain this matter ftlll more clearly, a different fptcies of mineral fluor was ufed, which be- ing diftilled with a double quantity of oil of vitriol, and with a drachm of water In the receiver, yielded 5 thin pellicle of the appearance of lead, but no filics.^us cruft. Volatile alkali threw down 2^ grains of grey 4 earth. CHEMISTRY. riuor Acid earth. — A drachm mixed with the fame quantity of CenSna- P"^^^"2ed fand afforded a peUIcle of lead interfperfed tioiis. ^'^^^ ^ few particles of white cruft, which ran into *i— y— glafs under the blow-pipe. Volatile alkali precipitated eight grains. — A drachm, mixed with an equal quan- tity of green glafs reduced to powder, fwelled a good deal, and yielded a thick fiUceous cruft. 6. To a drachm of green fluor that had been heat- ed and powdered were added two drachms of oil of vitriol, ftill employing the iron tube. A piece of wet charcoal was alfo fufpended in the infide, a cover fixed on the tube, and the latter was heated for about 15 minutes in a fand bath. Obferving now that the charcoal was dry, and had no earth upon it, a fcruple of fand in fine powder was added, the charcoal was wetted arid replaced, but nothing appeared. Some bits of green glafs were then thrown into the mixture, which inftantly foamed up and ran over. The char-- coal was not replaced in the tube, nor was it any longer neceffary, as it gained a covering of white powder by being held a very few moments over the g^g orifice. An experi- Mr Scheele, in one of his experiments, obferves, mentof Mr that he obferved the white powder on a piece of char- ex'^lT^ed ^'^^^ ^^^^ moiftened and fufpended over fluor ^ ' to which vitriolic acid was added. As this experi- ment was made in metalHc veffels, Mr Meyer conjec- tures, that the mortar ufed for reducing the fluor to powder was of foft glafs, and that the phenomenon was occafioned by the abrafion of fome particles of glad's- Of the 7* determine whether the acid can carry up quantity of much more of the filiceous earth than is fufficient filiceous to faturate It, an ounce and an half of pure oil of vi- triol was added in a retort of glafs, and three ounces of water put into the receiver. The retort was cor- roded through in an hour's time, and the cruft. on the water weighed ten grains. The liquid being then filtered and divided into two equal parts, one was pre- cipitated with cauftic volatile, and the other with mild fixed vegetable, alkali. The former yielded 25 grains of filiceous earth, and the lattc-r 68 grains of a preci- pitate, which flowed under the blow-pipe, ran into 489 earth car- ried along with fluor ac.d. glafs retort with a drachm and an half of oil of -vitriol, -A-cid produced no filiceous earth on the water in the ''C'combina ceiver, or that with which the earth was edulcorated, tion . The ley of flu orated volatile alkali was mixed with a 1— y mi J folution of chalk in nitrous acid till no more precipi- tation took place. The raixtuie was pafled through nitrous acid, and the precipitate adulcorated. It weigh- ed, when dry, two drachms and 36 grains. I o. Two drachms of oil of vitriol being added to a drachm of this precipitate contained in a glafs retort» the precipitate was attacked in the cold, but no cruft appeared ; the heat, however, was fcarce appUed, when the whole furface of the water was covered, and the fame phenomena exhibited which are produced by the natural fluor. 11. Mr Scheele having obferved that a mixture of Farther fluor as tranfparent as mountain" cryft.al, and oil of pi'oofs thaC vitriol in a metallic cyhnder, produced no appearance o^^^mj^s^'^'^^ filiceous earth on a wet fponge fufpended in the infide. ceeds^ft-ma at Mr Meyer's requeft he made a new experiment, the glafs by adding oil of vitriol to portions of fluor of this veffels. tranfparent kind placed in two tin cylinders; fome filiceous earth was put into one, and a wet fponge fufpended in both. The next morning the fponge that was fufpended over the cylinder which held the filiceous earth, was covered, with the white powder, but no appearance of it was feen on the other The expe- riment vyas repeated by Mr Meyer with the fame re- fult, but the white cruft did not appear till after a night's ttanding. 12. A drachm of fluor, mixed with two of oil of vi- triol, afforded, after a diftillation of two hours, a thin film of lead on the furface of the water in the receiverj but no filiceous earth. The fame mixture was after- wards diftilled with the ufe only of a glafs receiver in- ftead of a lead one. In the beginning of the diftilla- tion a fmall fpot appeared under the neck of the re- tort, and the neck itfelf was covered with white pow- der, but it foon difappeared ; and though the empty part of the receiver was corroded, yet no more thaa half a grain of earth was procured. Thcfe experiments fo cleaily point out the origin of the filiceous cruft on the furface of the fluor acid, the pores of charcoal, and gave ont ftrong vapours of . that its exiiknce as a diftindt acid is now univerfally 848 Violent ac tion of fluor acid u^ion glafs. fluor acid. The reafon of this difference ft) all be ex plained when we come to treat of filiceous earth. 8. To a mixture of half an ounce of fluor and the fame quantity of glafs, in powder, 12 drachms of oil of vitriol were put in a fmall retort, half filled with the mixture. The ingredients afted upon each other fo violently that they rofe up into the neck of the retort; and the operation being intermitted on account of the noxious vapour they --mittcd, the retort was found next day covered with fafciculated cryftals like hoarfroft. — The experiment being repeated in a more capacious retort, and the mixture thoroughly blended by agita- tion, it became a thick mafs, and fwelled like dough in fermeiuation : the bottom of the retort grew vtry hot, and the filiceous ciuft appeared on three ounces of water in the receiver. The diftillation being continu- ed for three hours, 16 grains of fiUceous earth were found on the furface, and the precipitate by volatile alkali weighed 56 grains ; the retort was much lefscor- loded than ufual. 5>. Thirty grains of this precipitate, diftilled in a Vol. JV. Part II. allowed, even by thofe who formerly contended for its being only the vitriolic or fome other acid difguifed. — g Experiments of a fimilar kind were made by Mr Wen- Mr Wcn- zel, who performed his diftillation in a leaden retort, zcl's expe- furniftied with a glafs receiver. The water was covered "menrs in with a variegated cruft, and yielded a gelatinous preci- ton''^*^" pitate with fixed alkali. On examining the receiver, he found its internal furface corroded, fo that it ap- peared as if it had been rubbed with coarfe fand. By fubftitutinga leaden receiver, however, inftead of a glafs one, he obtained the acid entirely free from filiceous matter, and containing only a fmall quantity of iron and aluminous earth. ^ ^ The fluor acid may alfo be procured by the nitrous, pjuor -lud muriatic, and phofphoric acids.— Mr Scheele diftilled procurable one part of the mineral with two of concentrated ni- '^y "itrous, trous acid. One part went over Into the receiver '"^''^' ''''L along with the fluor acid, and a thick cruft was form- pjJoi-ic adds, ed on the water of the receiver. The mafs remaining in the retort was calcareous earth faturatcd with ni-^ trous acid. 3 0^ With 490 Fluor Acid arid its Cuthhina- tiCBS. 3d 850 Appear- ance and p; oj>erties of fluor a- ci.l. 4th 850 Combined •with fixed alkali. 851 'Whh vola- tile alkali. C H E M With an equal quantity of marine acid, that of fluor pafTed over into the receiver with 11 lartre quantity of the muriatic ; the internal furface of the receiver, as well as of the water contained in it, being covered with a while cruft. The refiduum was fixed fal am- moniac. Phofplioric acid digefted with powdered fluor, dif- folved a fjocd deal of it ; and on didilling this folu- tion, the fluor acid went over together with the watery- particles of the mixture ; the remaining mafs in the re- tort had the properties of the aflies of bones. The fluor acid procured in any of thefe ways Is not dlftinguiOiable by the fmell from that of fea-falt : in fome cafes it afta as muriatic acid, in others like that of tartar ; but in moll cafes it fliowd properties pecijiar to itfelf. With fixed alkali the fluor acid forms a gelatinous and almoil infiuid matter, which refufes to ciyftallize. By evaporation a faline mafs was obtained, which was in weight only the fixth part of the fixed alkali dii- folved ; did not change the colour of fyrup of violets, but precipitated lime water, and likevvife the folutions of gypfum and Epfom fait. With mineral alkali the fame phenomena were produced as with the ve- getable. Volatile alkali with fluor acid formed likewlfe a jelly, which when feparated from the liquor appeared to be filiceous earth. The clear liquid tailed like vi- triolic ammoniac, and fhot into very fmall cryftals, which by fublimation yielded firfl. a volatile alkali, and then a kind of acid fal ammoniac. By diftiillation with chalk and water, all the volatile alkali quickly came Lime water inftantly threw down a regenerated I S T R Y. bule of fixed glafs behind. Pradice. Lead was not diflblved, Flu.^r Acid fweet folution with its 85 a With earths. 853 With me- tals. fluor, which was the cafe alfo with folutions of lime in the nitrous and muriatic aci let fall a pov/der, which, before the blow-pipe, re fumed its metallic form, the acid being diffipated, and forming a white fpot on the charcoal round the re- duced filver. Solution of quicklilver in nitrous acid was precipitated, and the powder was entirely volatile in the fire; but a folution of cotrofive fublimate re- mained unchanged. Lead was totally precipitated from nitrous acid ; and a folution of Epfom fait was rendered turbid. Oil of vitriol produced a fluor acid by diftillation, which formed at the fame time a thick crult on the water of the receiver. The regenerated fluor procured either by means of lime water or folu- tions of the earth in acids, was decompofed by fixed, but not by volatile alkali. With lime, magnefia, and earth of alum, this acid became gelatinous. Part of the two lafl were dif- folved. Gold was not toxiched by the fluor acid either alone or mixed with that of nitre. Silver, in its metallic ftate, imderwent no change. Its calx, precipitated by an alkali, was party diflblved; but the remainder formed an infoluble mafs at the bottom. Vitriolic acid expelled the fluor acid in its ufual form. Quick- filver was not diflblved, but its calx preclpitatedtrom the nitrous folution was partially fo. The remaining infoluble part of the calx united with the aci and without effer- Its proper, vefcence. It precipitates from them moft, but not all, metallic fubftances ; along with which a confiderable part of the borax is generally depofited. It does not abforb the marine acid of luna cornea, or of mercury fublimate. It melts upon the furface of the former without uniting, and fuffers the latter to rife unchanged : the borax in both cafes becomes coloured; in the firft,. milky with red ftreaks ; in the latter, amethyft or purple. Mixed with fal ammoniac, it extricates the volatile alkali, and retains the acid ; but mixed with a combination of the marine acid with calcareous earths, it unites with the earth, and extricates the acid. It extricates the acid of nitre v/ithout feeming to unite with the alkaline bafis of that fait ; nor does it mingle in fufion with the common fixed alkalir.e falts, the borax flowing diftinft upon their furface. A mixture of borax with twice its weight of tartar, diffolves in one fixth of the quantity of water that would be ne- ceffary to diffolve them feparately ; the liquor yields, on infpiffation, a vifcous, tenacious mafs like glue ; which refufes to cryftallize, and which deliquates in the air. Borax affords likewife a glutinous compound with the other acids, except the vitriolic ; whence this laft is generally preferred for making the feda- tive fait. It proves moft glutinous with the vegetable, and leaft with the marine. With oils, both expref- fed and diftilled, it forms a milky, femi-faponaceous compound. It partially diffolves in fpirit of wine. In conjun£lIon with any acid, it tinges the flame of burning matters green ; the precipitate thrown down by it from metallic folutions has this effect. It does., not deflagrate with nitre. Fufed with inflammable matters, it yields nothing fulphureous, as tiiofe falts do which Pradice. C H E M i^cetous A- which contain vitriolic acid. By repeatedly moiften- 01 1 and lis -j^g jj. ^y^en confiderably heated, it may be entirely c_,orp !iin&- /•■II* 1 iubhmed. — Y— Borax retains a good quantity of water in its cryftals ; by which it melts and fwells up in a heat infufficient to vitrify it. It is then fpongy and light, like calci- ned alum; but, on increafnig the fire, it flows like wa- ter. § 6. Of the Acetous Acid and its Combinations. How^pro- This acid Is plentifully obtained from all vinous li- cured. quors, by a fermentation of a particular kind, (fee Fermentation, and Vinegar.) It appears firit in the form of an acid liquor, more or lefs deeply co- loured, as the vinegar is more or lefs pure. By di- flillation in a common copper-ftlU, with a pewter head and worm, this acid may be feparated from many of its oily and impure parts. Diftiiled vinegar is a purer but not a Itronger acid than the vinegar itfelf ; for the acid is originally lefs volatile than water, thougl^, by certain operations. It becomes more fo. After vi- negar has been diftiiled to about ~ of Its original bulk, it Is ftlll very acid, but thick and black. This matter continues to yield, by diftlilatlon, a ftrong acid fplrit, but tainted with an empyreumatic oil. If the dillli- . lation is continued, a thick black oil continues to come over ; and at laft fome volatile alkali, as in the diltil- lation of animal fubftances. The caput mortuum left in the diftllling veffel, being calcined In an open fire, ' and afterwards lixiviated, yields fome fixed alkaline fait. Acetous Acid combines, 868 Sal diureti- ^* ^^'^"''^ Vegetable Alkali. The produce of this combi- cus. nation is the terra foliata tartaric or fal diuretlcus of the (hops ; but to prepare this fait of a line white flaky appearance, which is neceffary for fale, Is a matter of fome dItHculty. The belt method of performing this operation is, after having faturated the alkali witli the vinegar, which requires about 1 5 parts of common di- ftiiled vinegar to one of alkali, to evaporate the liquor to drynefs; then melt the fallne mafs which remalHS with a gentle heat ; after which it Is to be diflblved in wa- ter, then filtered, and again evaporated to drynefs. If it is now diflblved in fplrit of wine, and the liquid ab- ftrafted by dlftlllatlon, the remaining mafs being melted a fecond time, will, on cooling, have the flaky appear- ance defired. A good deal of caution is neceflaiy in the firft melt- ing V tor the acetous acid Is eafily diflipable, even when combined with fixed alkali, by fire. It is proper, therefore, that, when tlic fait is melted, a little ihould be occafionally taken out, and put into water ; and, when It readily parts with its blacknefs to the water, mi^ft then be removed from the fire. The fait, when made, has a very ftrong attraction for water, infomuch that it Is not eafily prefervcd, even when put into glafs bottles. To keep It from deliquating, Dr Black, therefore, recommends the corks to be covered with fome bituminous matter ; otherwlle they would tranf- _ , mit moifture enough to make the fait deliqirate. />ifetousK-" l^'^h Fojjlle Alkali. This alkafi, combined with ckI wltli the acetous acid, forms a fait whofe properties ai-e not ff!Iik uika- well known. Dr Lewis affirms, that it is nearly fimllar I S T R Y. 493 to the terra foliata tartari. The author of the Chemical Acet us A . DIftionary, again, maintains it to be quite different : partlculc^ily that it cryftaUizes well, and is not deii<|ue- jjj,,-,^ fcent in the air; whereas the former cannot be cry- — ftalUzed; and even when obtained In a dry form, un- kfs great care Is taken to exclude the air, will prefeiit- ly dcliquate. 870 III. With Volatile Alkali. This combination produces Veijt tahle a fait fo exceedingly dehquefcent, that it cannot be pro- amnv iuac. cured in a dry form without the greateft difficulty. In a liquid ftate, it is well known in medicine, as a fudo- rlfic, by the name of fpiritiis mindereri. It may, how- ever, be procured in a diy form, by mixing equal parts of vitriolic fal ammoniac and terra foliata tartari, and fubllming the mixture with a very gentle heat. When the fait is once procured, the utmoft care Is requifite tQ preferve it from the air. 871 IV. J^dh Earths. Combinations of this kind are but f^j"^"'''^'"^^ little known. With the calcareous and ai"gillaceous earths compounds of an aftrlngent nature aie formed. According to the author of the Chemical Dictionary, the fait refulting from a combination of vinegar with calcareous earth eafily cryftalllzes, and. does not deli- quate. With magnefia the acetous. acid does not cry- ftaUizc ; but, when Infplfl'ated, forms a tough mafs, of which two drachms, or two and a half, are a brilli pur- gative. _ _ _ ^^^^ V. With Copper. Upon this metal the acid of viner Diftiiled . gar does not adl brifldy, until It is partly at leaft calcl- \'erde- ned. If the copper is previoufly diflblved in a mineral si"^^** acid, and then precipitated, the calx will be readily dif- folved by the acetous acid. The folution Is of ^ green colour, and beautiful green ci*yftals may be obtained from it. The folution, however, is much more eafily eftedtcd, by employing verdegris, which is copper al- ready united w-ith a kind of acetous or tartareous acid, and very readily diflblves in-viue^ar. The cryftals ob- tained by this procefs are ufed in painting, under the name of dijulled verdegris. The moft ready, and in all probability the cheapeft, method of preparing the cryftals of verdegris Is that propofed by Mr Wenzel, by mixing together the fo- lutions of fugar of lead and blue vitriol, when an ex- change of bafes takes place ; the lead being inftantly precipitated by the vitriolic acid, and the acetous acid uniting with the copper. From 15 ounces and two drachms of fugar of lead with twelve ounces of blue vitriol, five ounces of the cryftals were obtained. The ■ precipitate of lead, though waflied feveral times with . water, never loft its green colour. It may either be ufed, he fays, in this ftate, as a green pigment, or it may be made perfectly white by digeftlon in dilute ni- trous acid. VI. With Iron. VIncgar,a£ts very readily upon iron,j,.„^ liquor- and diflblves it into a very brown and almoft black 11- for printing quor, which does not eafily cryftallize, but, if infplf- cloth, fated, runs per dellqulum. This liquor is employed in the printing of linens, callicoes, &c. being found to ftrike a finer black with madder, and to. injure the cloth lefs, than folutions of Iron in the other acids. VII. With Lead. The acetous acid diflblves lead in its metallic ftate very fparingly ; but If the metal is. calcined. It adis upon It very ftrongly. Even after lead Is melted into glafs, the acetous acid will receive a ftrong impregnation from it ; and hence it Is dangerous to..i 874. Lead. 494- CHEMISTRY. Pradlce, AceKvis A- to put vlnegfiv into fiiA earthen vefFt'l'! as are glazed cii\ and ICS ^cjjj Yead. In the metallic ilatc, only a drachm of lead can be diffolvcd in cidit ounces of diiliHed viue- ^75 C'cnifs, If lead is expofed to tlie vapours of warm vinegar, it is corroded into a kind of calx, which is ufed in great quantities in painting, and is known by the innne of crruJSf or ivhiie lead. 'I'Jie preparation of this pig- ment has become a diftinft trade, and is pradtifed in fome places of tliis kingdon^ where lead is procurable at the loweft price. The procefs for making cerufs is thus given by the author of the Chemical Didio- nary. " To make cerufs, leaden plates rolled fpirally, fo that the fpace of an inch ihaU be left between each circumvolution, inull be placed vertically in earthen pots of a pi-oper fize, containing fome good vinegar. Thefe leaden rolls ought to be fo fupported in the pots that they do not touch the vinegar, but that the acid vapour may circulate freely betwixt the circumvolu- tions. The pots are to be covered, and placed in a bed of dung, or in a fand-bath, by which a gentle heat may be applied. The acid of vinegar being thus redu- ced into vapour, eafily attaches itfelf to the furface of thefe plates, penetrates them, and Is impregnated with the metal, which it reduces to a beautiful white pow- der, called cerufs. When a fufficient quantity of it is collefted on the plates, the rolls are taken out of the pots, and unfolded ; ,the cerufs is then taken off, and they are again rolled up, that the operation may be repeated. " In this operation, the acid being overcharged with lead, this metal is not properly in a faline ftate ; hence cerufs is not in cryftals, nor is foluble In water : but a faline property would render it unfit for painting, in which it is chiefly employed." Though this procefs may in general be juft, yet tion* on the there are certainly fome particulars necefl'ary to make procefs for cerufs of a proper colour, which this author has omit- '"'"'^ ' ted ; for though we have carefully treated thin plates of lead in the manner he diredts, yet the calx always turned out of a dirty grey colour. It is probable, therefore, that after the lead has been corroded by the fteam of vinegar, it may be wafhed with water flightly impregnated with the vitriolic and nitrous acids. This preparation Is the only white hitherto found fit for painting in oil : but the difcovery of anether would be very defirable, not only from the faults of cerufs as a paint, but alfo from itsinjnring the health of perfons employed in its manufafture, by aflefting them with a fevere colic ; which lead, and all its preparations, fre- quently occafion. If diflilled vinegar is poured on white lead, it will diffolve it in much greater quantity than either the lead in its metallic form, or any of its calces. This folution filtered and evaporated, fhoots into fmall cryllals of an xiuttere fweetifli talle, called fugar of lead. Thefe are ufed in dyeing, and externally in medicines. They have been even given internally for fpltting of blood. This they will very certainly cure ; but at the fame time they as certainly kill the patient by bringing on other difeafes. If thefe cryftals are repeatedly dilTolved in freih acids, and the folutions evapora1;ed, an oily 876 Obferva' 877 Sugar of cernin^ the ■'ubility (it' kind of fubftance will at lad be obtained, which can Acetous A- fcarcely be dried. "^'^ ''''^^ From all the metallic combinations of the acetous acid, it may be recovered In an exceedingly concen- , trated form, by fimple dilliilation, fugar of lead only 878 excepted. If this fubftance is diftillcd in a retort with |-if!a"in'a- a fti'ong heat, it hath been faid that an inflammabk f"^^'^''|"g3j. fpirit, and not an acid, comes o\ cv; but this is denied of lead, by Dr Llack. gj^ VIII. JVifhTiiu The combination of acetous acid Tin. vi'ith tin is fo little known, that many have doubted whe- ther diftilled vinegar is capable of dilTolving tin or not. Dr Lewis obfervcs, " That plates of pure tin put into pp j^jj^is' ' common vinegar begun In a few hours to be corroded, experi- without the application of heat. By degrees a por- I'lei'ts con- tion of the metal was taken up by the acid, but did not feem to be perfectly diffolved, the liquor appear- ing quite opaque and turbid, and depofiting great part of the corroded tin to the bottom, in a whitifti powder. A part of the tin, if not truly diffolved, is exqulfitely divided in the hquor : for, after Handing many days, and after palling through a fdter, fo much remained fulpended as to give a whitifnnefs' and opacity to the fluid. Acid juices of fruits, fubftituted to the vinegar, exhibited the fame phenomena. Thefe experiments are not fully conchifive for the real folubility of tin in thefe acids, with regard to the pnrpofes for which chemifts have wanted fuch a folution : but they prove what is more important ; tha: tin, or tinned veffels, however pure the tin be, will give a metallic impreg- nation to light vegetable acids fuffered to ftand In them for a few hours." With regard to other metallic fubftances, neither the degree of attraftlon which the acetous acid has for them, nor the nature of the compoui>ds formed by the union of It with fnch fubftances, are known ; only, that as much of the reguline part of antimony Is diffolved In this acid as to give it a violent emetic quahty. See Regulus of Antimony. Concentration of the Acetous Acid, 8f?r Common vinegar, as any other weak acid, may be Concentrac advantageoufly concentrated by froft ; as alfo may itstfl vme- fpirit or the diftilled vinegar of the ftiops : but as the S^""- cold, in this country, is I'eldom or never fo Intenie as to freeze vinegar, this method of concentration cannot be made ufe of here. If diftilled vinegar be fet in a water-bath, the moft aqueous part will arife, and leave the more concentrated acid behind. This method, however, is tedious, and no great degree of concentra- tion can be produced, even when the operation is car- ried to its utmoft length. A much more concentra- ted acid may be obtained by diftilling In a retort the cryftals of copper, mentioned (n° 872.) under the name of d'ifltUed verdegris, A very ftrong acid may thus be obtained, which has a very pungent finell, almoft as fuft'ocating as volatile fulphureous acid. The Count de Lauraguais dlfcovered that this fpi- rit, if heated in a wide-mouthed pan, would take fire on the contaft of flaming fubftances, and burn en- tirely away, like fpirit of wine, without any refiduum. The fame nobleman alfo obfervcd, that this fpirit, JRj when well concentrated, eafily cryftallizes without ad- Salt of vi- dition. "^Sar. 5 This Pfaaice. C H E M Acetous A- This may feem to be the mod proper method of ob- cidanl it- ■ • • • ■ ■ " ' Comblua- I s T R y. 495 an 1 its taining the acetous acid in its grcHteft degree of (trength 883 and purity : but as the procefs requires a very ilrong heat to be ufed towards the end of the operation, It is probable that part of the acetous acid may be by that means entirely dccompofed. It would feem preferable, therefore, to decompofe pure terra foliata tartari by means of the vitriolic acid, in the fame manner as nitre or fea-falt are decompofcd for obtaining their acids. In this cafe, indeed, the acetous acid might be a little mixed with the vitriolic ; but that could eafily be fe- parated by a fecond dliVillation. A Itill better iTie- thod of preparing this acid feems to be by diftllling fugar of Jead with oil of vitriol. The proportion ufed^ by M. Lorenzen of Copenhagen, is three ounces of vitriolic acid to eight of the fugar of lead. Mr Doll- fufs recom.mends two parts of fugar of lead to one of vitriolic acid pyreumatic acid muft firfl. be dlftlUed from beech- vfood, Acid of and then reaified by a fecond dilliUalion. Three .[^^JJ^^Jf'J* pounds of this require for their faturacion five ounces nations, of purified alkali, which by evaporation and fufion af- u— «4 fc^rds three ounces and a quarter of terra foliata tartari. From this, one ounce fix drachms of concentrated a- cld are obtained ; and this, on being mixed v/ith an equal quantity of alcohol, yields two ounces one drachm and a half of genuine ether. Priefl Prieftley, who gives us feveral experiments on ky'&expe- the vegetable acid when reduced to the form of air, riments. mentions his being eafily able to expel it from fome exceedingly ftrong concentrated vinegar, by means of heat alone. This feems fomewhat contrary to the count de Lauragnais's obfervation of the difpofition of the fpirit of vcrdegris, as it is commonly called, to cryflaUize ; but a IHU greater difference is, that the vegetable acid air extinguiflied a candle, when, accord- ing to the Count's obfervation, it ought to have been inflammable. The moll curious property obferved by Dr Prieftley is, that the vegetable acid air being Im- bibed by oil olive, the oil was rendered U fs vifcid, and clearer, almojl Uh an ejfcntu.1l oil This is an ufeful hint ; and, if purfued, might lead to important. difco- veries. Acetous acid combined with Jnflammahh Matter. 884 rp^^ ^^jy yet known, of combining acetous ethS! ^ acid with the principle of inflammability, is by mix- ing togtther equal parts of the ftrongly concentra- ted acid called j'pirit of verdegrisy and Ipirit of wine. The refult is, a new kind of ether, fraailar to the vitii- clic, nitrous, and marine. This ether, however, re- tains fome of the acidity and peculiar fmeil of the vinegar. By rectification with fixed alkali, it may be freed from this acidity, and then fmcUs more like true ether, but dill t-etaining fomething of the fniell, liot of the acid, but the inflammable part of the vine- g;ar. In this prccefs a greater quantity of ether is obtain- f d than by employing the vitriolic acid ; which (hows that the vegetable acid is effentially fitter to produce e*her than the vitriolic. For making the acetous ether rtadily, Mr Dollfufs recommends eight ounces of fugar ©f lead dried by a very gentle heat, until it lofes the water of cryftalllzation, when it will weigh five ounce* and fix drachms. It is then to be put into a glafs re- tort, and a mixture of five ounces of vitriolic acid> with eight of fpirit of wine, poured upon it, and the whole diftilled with a very gentle fire. The firft ounce that paffes over will be dulcified acetous acid, the next almoft all ether, and the third ether in its pureil ftate. An ether may alfo be obtained from vinegar of wood. To make it, the moll concentrated acid of thid kind is to be made ufe of. For this purpofe an em- ^7. Of the Jcid of Tartar. 88^ Tartar \& a fubftance thrown off from wine, after Tartan it is put into cat1 that in the management of wines it is necefiary to add certain powdery fubltances which have fome weighty and fall to the bottom readily 'y and which, in falHng, carry down a number of particles that would other- wife float in the liquor for a long time, being fo light that they could hardly be made to fubfide ; but the particles of clay adhering to them increafe their gravi- ty ; and probably it anfwers the fame purpofe in the refinement of tartar. To obtain the pure Acid of Tartar. For a long time the cream or cryftals of tartar Sclieek '3 were confidered as the pureft acid which could be^n^'y^^^t obtained from this fuWlance ; but, in the year 1 770, "^^"^ an analyfis of tartar was publifted in the S-wedifti tranfaAions, by Mr Scheele. His method of de- compofing the fait was, to dlffolve it in a fufficlent quantity of boiling water, then to add chalk in fine powder till the effervefcence ceafed. A copious pre- cipitation enfucd ; and the remaining liquor being eva- poratedj tartar. 49^ C H E M I Acid of porated, afforded a foliible tartar. This proved, that Tartar and-^^„„ ^i- ^ ■ ^ , r r , Its Combi- ^^^^^ °' tartar IS not, as wag commonly fuppofed, an nations. »cid of ^ a peculiar kind, joined with a great deal of ^— ry earthy impurities ; but really a compound fait, con- taining an alkali joined with an acid ; and that the alkali produced from burnt tartar is not generated ia the fire, but pre-exiftent in the fait. The whole fediment obtained in thii experiment, is the calcareous earth combined with the acid of tartar, which may juftly be calkd felm'ites tartareus. If feme diluted vitriolic acid Is poured upon this felenites tar- ' tareus, the vitriolic acid expels the acid of tartar, form- ing a true felenite with the earth, while the liquor contains the pure acid of tartar. By infpIiTatlon this acid may be made ftronger, and even formed into fmail white cryftals, which do not dellquate in the air. A particular fpecles of tartar extraded from forrel hath been fold for taking fpots out of cloths, under the name of ejfetiilal fait of lemons, and which is now difcovered to be the fame with the acid of fugar. This experiment was foon after confirmed by Dr Black ; who farther obferved, that if quickhme was ufed S T R Y. Pra^ice, recompofed from the pure acid and alkali in the fol- ^eid of lowing manner : " Upon fixed vegetable alkali pour Ja^tar afi4 a folution of the acid of tartar. Continue this till the nat^^lig^^^" effervefcence Is over ; the fluid will then be tranfpa- • ^' -f rent ; but if more of the acid Is added. It will become 890 turbid and white, and fmall cryftals like white fand Regenera- wlll be formed in It. Thefe cryftals are a perfeft cream "^''^^"^ of tartar. of tartar. • Effential 'fait of le- 'tnonst Upon thefe principles, another method of decompo- fing cream of tartar might be tried ; namely, adding to it as much oil of vitriol as would faturate the alkali, then diffolving and cryftalllzing the fait: but, by this method, there would be danger of the acid being adul- terated with vitriolated tartar. . ^ ^ II. With FoJJile Alkali. The fait produced from an Selgnette's union of cream of tartar with foflile alkali, has been Rocheile long known under the names of Selgnette's fait, falRu-^^'^' pelleriftsy or Rocheile fait ; but as the cream of tartar is now difcovered to be not a pure acid, but adulterated * with a portion of foluble tartar, poflibly fome differen- ces might be obferved if the pure acid was uted. This fait was firft invented and brought Into vogue inftead of chalk, the whole acid would be abforbed by by one Seignette, an apothecary' at Rocheile, who kept the lime, and the remaining liquor, inftead of being a the compofitlon a fecret as long as he could. Meffrs folution of foluble tartar, would be a cauftic lixivium. Boylduc and Geoffroy afterwards difcovered and pab- The moft ready method, however, of procuring the pure lifhed its cotnpofitloh. acid of tartar feems_ to be that recommended by Mr To prepare this fait, cryftals of mineral alkali are Schiller in the Chemical Annals for 1787. One pound to be diffolved in hot water, and powdered cream of of cream of tartar Is to be boiled in five or fix pounds of water, and a quarter of a pound of oil of vitriol added by little and little, by which means a perfeft folution will be obtained. By continuing the boihng, all the vitriolated tartar is precipitated. When the li- quor is evaporated to one half, it muftbe filtered ; and tartar thrown in as long as any effervefcence arifes. For the better cryftaUIzation of the fait, the alkali ought to prevail. The hquor muft then be filtered and evaporated, and very fine large ciyftals may be obtained by cold, each of which is the half of a poly- gonous prifm cut in tlie direftion of its axis. This if, on the renewal of the boiling, any thing farther is feftlon, which forms a face much laro-er than the reft. Soluble tar tar. precipitated, the filtration is to be repeated. The clear liquor is then to be reduced to the confiftence of a fyrup, and fet in a temperate, or rather a warm place, when very fine cryftals will be formed, and as much acid obtained as is equal in weight to half the cream of tartar employed. • If too fmall a quantity of vitriolic acid has been employed, the undecompofed cream of tartar falls along with the vitriolated tartar. Acid of Tartar combined, I. With Vegetable Alkali. If the pure acid of tartar be combined with this alkali to the point of faturation, a neutral fait is produced, which dellquates In thf air, and Is not eafily cryftalllzed, unlefs the liquor be kept warm, and hkewife be fomewhat alkaline. This fait, called foluble tartar'^ Is ufed In medicine as a purgative; but as its dellquefcence does not admit of Its being kept in a cryftalline form, it is always fold In powder. Hence thofe who prepare foluble tartar, take no fur- ther trouble than merely to rub one part of fixed all-a- llne fait with thiee of cream of tartar, which renders the compound fufficiently neutral, and anfwers all the purpofes of medicine. Dr Black informs us, that in medical prefcrlptlons, where foluble tartar is ordered as a purgative along with a decoftlon of tamarinds, the acid of the latter will decompofe the foluble tartar, and thus the prefcrlption may perhaps be rendered in- effeftual. The fallne mixture ilfdd in fpvers Is nothing but a tartartts lolubillfi in folution. According to Mr Scheele,- cream of tartar may be IS, hke them, a regular reftangle, diftinguifhable from the others, not only by its breadth, but alfo by two diftlndt diagonal lines which interfeft each other in the middle. The following method of preparing Selg- nette's fait, recommended by Mr Scheele, feems pre- ferable to any other on account of Its eafe and cheap- nefs. Thirty fix ounces of cryftals of tartar are to ba fatm-ated with potafh, and eleven ounces of common fait diffolved in the ley. When it Is grown cold, and the vitriolated tartar has fubfided to the bottom, it is filtered and evaporated till a pellicle appears ; the two firft cryftalllzations yield a fine Seignctte's fait ; the third contains fome digeftive fait ; and the fourth is entirely compofed of it. The reafon of this formation of Selgnette's fait Is, that the vegetable alkah has a greater attraftlon for acids than the mineral, and there- fore decompofes the fea-falt, vvhofe bafis is then at li- berty to combine with the acid of tartar ; while the ftronger marine acid takes the vegetable alkali. — A fait of the fame kind will be produced by adding Glau- ber's fait inftead of common fea-falt. III. With V olatile Akali. With regard to this com* Cream of bination, all we know as yet is, that if the alkali is tartar, over-fiiturated with acid, a cream of tartar, aimoft as difficult of folution as that of fixed alkali, will be ob- tained. When the faturation has been pretty exa£l, a beautiful fait, compofed of four fided pyramids, and which does not dellquate In the air, is produced. It is inllantiy decompounded, and emits a pungeut vola- tile fmel on being mixed with fixed alkah. 6 IV. Practice. CHEMIS TRY. Afine green colour. Chalybcat- t'd tartar. 986 Sacchtiri: acid. 897 faccha.-in ■<'.i,id. IV. IVilh Earths. All that Is as yet known con- cerning thefe combinations, is, that with the calcareous earth a compound not eafily foluble in water is form- ed. The other properties of this fubltance, and the nature of combinations of tartareous acid with other earths, are entirely unknown. V. With Copper. In its metallic Rate, cream of tar- tar afts but weakly on this metal, but diflblves ver- degris much more perfeftly than diftilled vinegar can. The folution with cream of tartar, being evaporated, does not cryftallize, but runs into a gummy kind of matter; which, however, does not attradi the moifture of the air. It readily diffolves in water, and makes a beautiful bluilh green on paper, which has the pro- perty of always fhining, as if covered with varnifh. The elFefts of the pure acid on this metal have not yet been tried. VI. Wilh Iron. The efFefts of a combination of iron with the pure acid have not hitherto been tried. Cream of tartar diiTolves tkis metal into a green liquor, which being evaporated runs per cUiquiuni. It has been attempted to fubilitute a folution of this kind to the liquor ufed in printing calicoes formed of iron ai:d four beer; but this gave a very dull brownilh colour with madder. Poffibly, if the pure acid was ufed, the co- lour might be improved. In micdiclne, a combination of cream of tartar with iron is ufed, and probably may be an ufeful chalybeate. VII. With Regulus ofAnt'movy. See Sed. III. ^ 8. Of the Add of Sugar, '^^ That fugar contains an acid, which on diftlUation by a ftrong fire arifes in a liquid form, in common with that of moil other vegetable fubftances, has been ge- nerally known ; but how to obtain this acid in a con- crete form, and to appearance as pure and cryftal- lizable as the acid of tartar, we were entirely ignorant, till the appearance of a treatife intitled, D'ffertatto Che- mka, de acido Sacchari, auBore Johanne Afzelio Arvidf- fon, 4to, Upfalide. Of the method of procuring, and the properties of, this new acid, we have the following account in the Edinburgh Medical Commentaries, vol. iv. " I. To an ounce of the fmeft white fugar In pow- der. In a tubulated retort, add three ounces of ftrong fplrit of nitre. " 2. The folution being finlfhed, and the phloglfton of the fplrit of nitre moftly exhaled, let a receiver be properly fitted to the retort atid luted, and the liquor then made to boil gently. " 3- When the folution bas obtained a brownl/h co- lour, add three ounces more of fplrit of nitre, and let the ebullition be continued till the fumes of the acid are almoft gone. " .4. The liquor .being at length emptied Into a lar- ger veffel, and expofed to a proper degree of cold, qua- drangular prifmatic ciyftals are obferved to form ; which being collefted, and dried on foft paper, are ifound to weigh about 109 grains. 5. The remaining liquor being again boiled In the fame retort, with two ounces of frelh fplrit of nitre, till the red vapours begin to difappear, and being then In the fame manner expofed to cryftallize, about 43 grains of fallne fpiculce are obtained. Vol. IV. Part II. 497 " 6. To the liquid that ftlU remains, about tw^ Acid of S.-.- ounces more of fpirit of nitre being added, and ^^ter-SfJ^'^^.'^ J*^* wards the whole being, loth by boiling and evaporation, reduced to a dry mafs, a brown, faline, gelatinous ^ — ^ kind of fubftance Is produced, which, when thorough- ly dry, is found to weigh about half a drachm. " In the fame manner, a fimllar acid, we are told, may be obtained from different faccharine fubftances, a'A gum-arabic, honey, iffc; but from none in fuch quan- tities, or fo pure, as from line fugar." g^g This fait poffelfcs fome very fmgular properties, of Prefump^ which what appears to us the moft remarkable, and 'i'"'" ' f its which we cannot help reading with fome-degree of '^f'P^'.^"'^,. doubt. Is, that it produces an eftervefcence on being ^^^1!'''^''^ added to fucli alkaline, earthy, or metallie fubflances, as contain the 'vitriolic acid. From this we fhould be apt to think, that this acid was capable of diflodging even the vitriolic acid from its bafis. Acid of fugar, being diftilled In a retort, gives over about t'q of its weight of water. By an interife heat it melts, and is partly fublimed ; leaving In the retort a dark grey mafs, of about the fifth part of the weio-ht of the cryttals made ufe of. The fubhmed fait eafily recovers its cryftalHne form, and feems to have under- gone no further change by fubhraatlon than belnp- ren- dered more pure. During the diftillatlon a great quan- tity of elaftic vapour rufhes out (about 100 cubic in- ches from half an ounce of the cryftals), which, from the diftilled liquor's precipitating lime-water, we may judge to be fixed air. In a fecond fublimatlon, white fumes are fent over, which, when cold, appear to be an acid, glaffy-coloured hquor, but cannot be again cryftalllzed. " Such parts of the falts as adhei^ to the fides and necks of the veffels do not appear to be in the leaft changed In the proccfs." On a third fub- limation, thefe parts produced fuch elaftic vapours as burft the receiver. This fingular fait has a confiderable acid power ; Great acid twenty grains of It giving a very confiderable degree P'^^^^''" of acidity to a large tankard of water. It dlffolves in an equal weight of diftilled water, but concretes on the liquor's growing cool. It is alfo foluble In fplrit of wine ; 100 parts of boiling fpirit of wine diftblving 56 of the faccharine ciyftals, but no more than 40 when cold. The folution In fplrit of wine foon be- comes turbid; and depofites a mucous fediment, in quantity about of the acid made ufe of. When cold, Irregular fcaly ci-yftals are formed, which when dry are perfeftly white. With vegetable alkali, the acid of fugar can fcarcely be formed into cryftals, unlefs either the alkali or acid predominate. With mineral alkali, a fait very diffi- cult of folution Is formed. The quantity of volatile alkali faturated by this acid Is Incredible. ' " Six parts Tncr^edi!)Ie of a pure volatile alkali may be faturated with one of quantity of the acid of fugar. The produce Is a quadrangular X'^'^''''^^^* prifmaric fait. With lime this acid unites fo ftrongly, ted'b^'iT* as to be feparable by no other means than a ftrong * heat. What kind of a fait refults from this combina- tion we are not told; but the author is of opinion, that this ftiows the ufe of lime In the purification o^ iu'i-ar, in order to abforb the fuperfluous acid. Being fatu- rated with fome of the terra pnnderofa, the acid of fu- gar immediately depofits a quantity of pellucid angu- lar cryftals, fcarcely foluble in water. With map-ne- 3 fa 498 CHEMISTRY. Pracf\ice# Acid of Su- paT and its 901 Its effeds fu nietals. <)0% Saccharine ether. 903 Whether this acid is produced IVom the nitrous. ad Q03 The iame with the acid of for- fir. the fatt appears in form of a white powder, fokible neither in water nor fpirit of wine, unlefs the acid prevails. It has a ftronger affinity with magnefia than any of the alkahne faks. With earth of alum, no cryilals are obtained ; but a yellow pellucid mafs, of a fwcetifli and fomewhat aftringent tafte ; which, in a moill air, liquefies, and increafes two-thirds in weight. This acid afts upon all metals, gold, filver, platina, and;quickfilver, not excepted, if they have been pre- vioufly diffolved in an acid, and then precipitated. Iron in its metaUic ftate is diffolved in very large quantity by the faccharine acid ; 45 parts of iron be- ing foluble in 55 of acid. By evaporation, the liquor Ihoots into yellow prifmatic cryftals, which are eafily foluble in water. With cobalt, a quantity of yellow- coloured cryftals are obtained, which being diffolved in water, and fea-falt added to the folution, fornr a fympathetic ink. The eleAive attraftions of this fingular acid are, firft, lime, then the terra ponde- rofa, magnefia, vegetable alkali, mineral alkali, and laftly clays. With fpirit of wine an ether was ob- tained, which cannot eafily be fet on fire unlefs pre- vioufly heated, and burns with a blue inftead of a white flame. Towards the conclufion of his differtation the au- thor obferves, that fome may imagine that the acid of nitre, made ufe of in thefe experiments, may have a confidcrable fliare in the produdion of what he has termed acid of fugar. But though he acknowledges that this acid cannot in any way be obtained but by the affiilance of fpirit of nitre, he is thoroughly convin- ced that it does not, in any degree, enter into ks com- pofition. Wliat occurs to us on this fubj eft is, that if the acid really pre-exifts in the fugar, it muft give fome tokens of its exiftence by mixing the fugar with other fubftan- ces befides fpirit of nitre. The author himfelf thinks thatUme ads upon the acid part of the fiigar : from whence we are apt to conclude, that by mixing lime, in a certain proportion, with fugar, a compound fliould be obtained fomewhat fimilar to what was formed by a direa combination of hme with the pure acid. In this cafe, we might conclude that the nkrous acid pro- duces this fak, by combining wkh the inflammable part of the fugar, becoming thereby volatile, and flying en- tirely off, fo as to leave the acid of the fugar pure. In the difl;Illatioo of dulcified fpirit of nkre, however, we have an Inftance of the nitrous acid itfelf being very much akered. This muft therefore fuggeft a doubt, that the acid fak obtained in the prefent cafe is only the nitrous acid deprived of ks plilogifton, and united with fome earthy particles. , „ . , , In a treatife lately pubhflied by Mr Rigby, how- ever, we are informed that fugar itfelf may be recom- pofed by unk'.ng the acid of fugar with phlogifton ; which affcrtion, if well founded, undoubtedly decides the difoute in favoiu- of the faccharine acid being ori- ginally" contained in the fugar. Late experiments have determined it to be the fame with that of forrel ; for which, as well as many other valuable acquifitions, the fciehce of chemiftry is indebted to Mr Scheele. Having diffolved as much acid of fugar in cold water a§. the^liquor could take up, he added to this folution fome Hxivium of tartar drop by drop, waiting a little ^Vdd of after each drop and found the mixture, during the ^„/P/^''"'"* effervefcence, full of fmall cryftals, which were geiuiine Con,l,h,a- falt of wood-forrcl. M. Klaproth having precipitated tion-. a nitrous folution of quickfilver with fait of wood- ' v^— J forrel, perfeftly neutralized by vegetable alkali, obtain- 3d 903 ed a whke precipitate ; vvhich, when edulcorated andFulmii^a- dried, and gently heated in a tea-fpoon, fulminated ^'j^-^l"^^^ with a noife not inferior to that of ftilminating gold. Acid of fugar perfeftly neutralized with vegetable al- kali, afforded the fame precipitate, and fulminated in the fame manner. ^9. Of the Acid of Phosphorus. 904 This acid was firft difcovered by Romberg mphlogiftic urine ; afterwards by Margraaf in muftard and cruci-acid. ferous plants : M. Bochante difcovered it in wheat ; and laftly, M. Haflenfratz has traced it in the mineral kingdom wkh great attention. — He has found that phofphorated iron is contained in all the PruiTian blues, when not purified ; but that this acid is produced by the coals employed in the procefs, and is no conftitii- ent part of the tinging matter. According to hini it occurs almoft univerfally in the minerals of iron which are found in the flimy ftrata of the earth, as well as thofe which are undoubtedly modern, whether primary or fecondary ; unlefs the iron be fo far of a metallic nature as to be attracted by the magnet, or very near that ftate. It is afforded by the ochry ftrata, and thofe which contain haematites as well as the flimy kind. Into thefe it is fuppofed to have come by the deccmpofition of vegetables; and to inveftigate this matter he examined the hibifcus paluftris, folidago, virga aurea, antirrhinum, lunaria, folanum nigrum, vulgatum, ftachys paluftris, artemifia Zeylandica, ruta graveolens, lycopus Europeus, carex acuta; vinca major, nepeta Pannonica, and noa Abyffma, All thefe plants afforded the acid of wood-forrel and the phofphoric acid. The quantity of the former varied from two ounces two drachms 1 8 grains of acid fait containing fome calcareous earth, to two drachms 24 grains in a pound of each plant ; the quantity of cal- careous phofphoric fait being from one ounce fix drachms 48 grains, to one drachm 12 grains.---M. Haffenfratz alfo obferves, that the phofphoric acid is procurable from all kinds of iron ; though in fome it feems to proceed from that contained in the earth, and , in others from the coals employed in the reduflion. The phofphoric acid is alfo found by Dr Marquart to be contained in the gaftric juice of animals. One pound four ounces of the gaftric juice of oxen gave 10 grains of a lymphatic matter, exaftly like the blood in its qualities ; 1 6 grains and fix-fevenths of phofpho- ric acid, which with a blow-pipe was changed into a very pure and deliquefcent glafs. of phofphorus ; five grains of phofphorated lime, two grains of refin, 14 grains of fal ammoniac, 29 grains of common fait, a very fmall quantity of an extraft whofe nature was difficult to afcertain ; one pound three ounces fix drachms and 67^ grains of water; fo that the folid contents were only 166th part of the bulk. In ftieep, the quantity of gaftric juice was about . eight ounces in. quantity, of a deeper and brighter greea. Praaice, C H E M Acid of green than that of oxen or calves ; but afFording the Phofphorus£gj^g ingredients, though in a different proportion ; though no other acid than that of phofphorus could be difcovered. It was alfo more difpofed to putrefac- tion. Calves furnished from four to fix ounces of gaftric juice, which contained very little lymph, but afforded fome quantity of dry jelly, though the whole was not equal to the proper proportion of lymph. The phofphorated lime was in the ufual quantity, but the difengaged phofphoric acid in a very fmall propor- tion. The laAeal acid was found in great quantity ; to which, along with that of phofphorus, our author fuppofes the property of curdling the milk in the ani- mal's ffomach to be owing. The phofphoric acid has alfo been found in very large quantity in the calcareous ftones of Andalufia ; and Mr Klaproth has found the fame combined with calcareous earth in a kind of beryl, cryftallized in hexa- hedral prifms, called by M. Verner apatit. — Formerly the beft method of obtaining it was from urine, where it is contained in very confiderable quantity in combi- nation with the volatile alkah, and forming a fait call- ed the mtcrocofmk, or ejferit'ial fait of urine. To procure this, a large quantity of urine is to be evaporated to the confiftence of a thin fyrup ; which, I S T R Y. Microcof- mic fait, howprocu- being fet in a cold place, will yield, in three or four red. weeks, foul brown-coloured cryftals, which are the microcofmic fait, mixed with the marine, and other falts of urine. Thefe cryftals are to be diffolved in hot water ; the folution filtered whilft it continues hot, and fet to crj'^llaUize again ; and the folution, filtra*- tion, and cryftallization, repeated till the fait becomes pure and white. In all the cryftallizations the micro- cofmic fait fhoots firft, and is eafily diftinguifhed and feparated from the others. If the urine which re- mains after the firft cryftallization be further evapo- rated, and again fet in the cold, it will yield more cryftals ; but browner and more impure than the form- er ; and therefore requiring to be purified by themfelves. From 20 gallons of urine may be obtained four ounces of pure fait ; a confiderable part being ftill left in the refiduum. In thefe operations the heat ought to be gentle, and the veffels cither of glafs or compaA ftone-ware. Urine being evaporated in a copper veffel, afforded on- ly a green folution of that metal. Concerning the nature of the microcofmic fait ob- , tained by the above procefs, Mr Margraaf gives the following account in the Berlin memoirs for 1 746. " Sixteen ounces of the fait, diftillcd in a glafs re- tort, in a heat gradually raifed, gave over eight oun- ces of a volatile urinous fpirit, refembling that made from fal ammoniac by quicklime. The refiduum was a porous brittle mafs, weighing eight ounces. This, urged with a ftronger fire in a crucible, bubbled and frothed much, and at length funk down into the ap- pearance of glafs, without fe^ming to fuffer any fur- ther diminution of its weight in the moft vehement heat. The vitreous matter diffolved in twice or thrice its quantity of water, into a clear, tranfpai-ent, acid li- •quor, fomewhat thick, not ill refembling in confiftence concentrated oil of vitriol. This liquor totally cor- roded ziiK into a white powder, which, being diluted 906 Mr Mar- graafF's eX' pcriments. with water, appeared in great part to dlffolve, fixed Acid of alkalies occafioning a plentiful precipitation. It afted Pl^o^'l'liorw* po\*erfulIy upon iron, with fome effervefcence ; andjjf^jjfua- changed the metal into a kind of muddy fubftance in- tions. dining to blulfh, in part foluble in water hke the pre- ceding. It diffolved hkewife a portion of regulus of antimony, and extradied a red tindure from cobalt. On lead and tin it had very little aftion. Copper it cor- roded but flighty. On bifmutb, filver, and gold, it had no efieft at all, either by ftrong digeftlon, or a boihng heat. Nor did the adding of a confiderable portion of nitrous acid enable It to ad upon gold. " The vitreous fait In Its diy form, melted with me> talllc bodies with a ftrong fire, ads upon them more powerfully. In each of the following experiments, two drachms of the fait were taken to two fcruples of the metal reduced to fmall parts, (i.) Gold com- municated a purple colour to the vitreous fait; oft weighing the metal, however, its diminution was not confiderable. (2.) Silver loft four grains, or -rV ; and rendered the fait yellowlfti, and moderately opaque. (3.) Copper loft only two grains, or ^V. though the fait was tinged of a deep green colour. It feemed as if a portion of the fait had been retained by the metal^ which, after the fufion, was found to be whiter and more brittle than before. (4.) During the fufion with iron, flafties Uke Hghtning were continually thrown out ; » a phofjphorus being generated from the combination of the acid with the inflammable principle of the irojj. Great part of the mixture rifes up in froth ; which, when cold, appears a vitreous fcoria, covered on the furface with a kind of metallic flcin, which, on being rubbed, changes Its green colour to a yellowllh. Th^, i-eft of the iron remains at the bottom of the crucible, half melted, half vitrified, and fpongy. (5.) Tin loth 18 grains, or nearly one-half its weight, and rendered the fait whitlfti ; the remaining metal being at the fam« time remarkably changed. It was all over leafy and brilliant, very brittle, internally like zinc. Laid on burning coals, it firft began to melt, then burnt like zinc, or phofphorus. (6.) Lead loft 16 grains, and gave the fame whitlfh colour to the fcoriae that tin does. The remaining lead was In Hke manner inflame mable, but burnt lefs vehemently than the tin ; from which it differed alfo in retaining its malleability, (7.) Mercury precipitated from aquafortis, and well edulcorated, being treated with the fait in a glafs re- tort, with a fire raifed to the utmoft, only 1 2 grains of mercury fubllmed ; 28 remaining united with the acid, in a whltifti, femi-opaque mafs. A folution of this mixed In diftllled water, depofited a quantity of a yel- lowlfti powder ; which, by diftillation in a glafs retort, was in great part revived into running mercury. A part alfo remained diffolved in the clear liquor ; for a drop let fall on poHfhed copper inftantly whitened it. (8.) Regulus of antimony melted with the vitreous fait, loft eight or nine grains, (about f ) ; the regulus affumed a fine, brilliant, ftriated appearance ; the fco- riee were fomewhat opaque. (9.) Bifmuth loft eight grains ; the fcoriae were like the preceding, but the bifmuth itfelf fuffercd little change. {10.) Zinc, mix- ed with the fait, and diftllled in a glafs retort, yielded a true phofphorus, which arofe in a very moderate heat. The refiduum was of a grey colour, a little melted at 3 R 2 th€ 500 Acid of Phofiihorus and its Combina- tions, 907 Expels the acids of vi- triolated tartar, t}itre,and iea-falt. C H E M I the bottom, in weight not exceedingtwo drachms; fo that two fcruples had fublimed. This refiduum, urged further in a fmall Heffian crucible to perfeft fufion, emitted an infinity of phofphorine flaflies, with a kind of deto- nation. The matter, grown cold, looked Hke the fco- rice of n:ielted glais. (n.) White arfenic, mixed with this fait, feparated in the fire, greatell part of it fubliming, and only as much remaining behind as in- creafed the weight of the fait eight or nine grains. This compound appeared at firil tranfparent ; but, on being expofed to the air, became moiil, and of an o- paque whitenefs, much rcfembling cryftalline arfenic. (12.) Cinnabar totally fubhmed ; fuffering no change itfelf, and occafioning none in the fait. Sulphur did the fame. (iS-) One part of the fait, mixed with ten of manganefe, and melted in a clofe veffel, gaveafemi- tranfparent mafs, feme parts of Avhicli were bluifh. The crucible was lined with a fine purple glazing, and the edges of the mafs itfelf appeared of the fame co- lour. " The vitreous fait diffolved alfo, in fufion, metal- h'c calces and earths. Chalk, with one third its weight of the fait, formed a femitranfparent vitreous mafs : calcined marble, with the fame proportion, flowed fo thin as to run all through the crucible; gypfum, like- wife, ran moftly through the crucible ; what remain- ed was femitranfparent. Lapis fpecularis ran entire- ly througii the veffel. Spanifli chalk gave a femitran- fparent mafs, which fparkled on breaking; and fine white clay, a fimilar one. Saxon topaz and flint were changed into beautiful opal-coloured maffes; the earth of alum into a femitranfparent mafs, and quicklime into an opaque white one. The mafs with flints im- bibed moifture from the air; the others not. " Oil of vitriol, poured upon one-fourth its weight of this fait in a retort, raifed an effervefcence, acquired a brownifh colour, and afterwards became turbid and white. On raifing the fire, the oil of vitriol diililled, and the matter in the bottom of the retort melted. In the neck was found a little fubhmate, which grew moifl: in the air ; as did likewife the remaining fait, which was opaque and whitirti. Concentrated fpirit of nitre, diftilled with this fait in the above proportion, came over unchanged; no fublimate appeared; the re- fiduum looked like glafs of borax. The diililled fpirit did not ail in the leaft upon gold, even by coftion. Strong fpirit of fea-falt being diililled in the fame man- Rer, no fenfible change was made either in the fpirit or the fait. " Equal parts of the vitrified microcfomic fait and fait of tartar being urged with the ftrongeft fire that a glafs retort could bear, nothing fenfible came over, nor did the mixture appear in thin fufion. Diflblved in water, filtered, and duly evaporated, it afforded, very difficultly, oblong cryftals, fomewhat alkaline ; the quantity of alkali having been more than enough to fa- turate the acid. A whitifh matter remained on the filter, amounting to feven or eight grains, from two drachms of the mixture ; this, after being wafhed and dried, melted before a blow-pipe, as did likewife the cryftals. " This fait feems to extricate, in pai't, the acids of vltriolated tartar, nitre, and fea-falt. (i.) On diftil- ling a mixture of it with an equal quantity of vitrio- lated tartar, there came over feme ponderous^acid drops, S T R Y. Praaice. which, faturated with fixed alkali, formed a neutral fait '^cid of greatly refembling the vitriolated tartar. The refidu- ^n^'/jg^^'^"* um readily dilTolved in water, and difficultly cryllalli- Cotnbina- zed. (2.) Nitre, treated with the fame proportion oft;ons. the fait,' began to emit red vapours. The reliduura ■ — v was of a peach-blofTom coloin-, appeared to have melted lefs perfectly than the preceding, and diflblved more d f- ficultly in water. The folution depofited a little earthy matter ; and, on being flowly evaporated, fhot into cryftals, which did not deflagrate in the fire. (3.) Sea- falt, diftiUed in the fame manner, manifeftly parted witli its acid ; the refiduum was whitiih, readily diiTolved in water, and afforded fome cubical cryftals. (4.) Sal am- moniac fuft'cred no change. (5.) Borax, with an equal quantity of vitreous fait, run all througii the crucibles. " Solutions of this fait precipitated the earthy part of lime-water, of folution of alum, of flint dilTolved in fixed alkali, and the combination of marine acid with chalk or quicklime. The precipitate from this laft liquor is tenacious like glue, and does not diflolve even in boihng water; expofed to a ftrong lire, it froths prodigioufly, and at lall melts into a thick fcoria. " Solutions of this fait precipitate alfo fundry me- tallic folutions ; as butter of antimony, folutions of filver, copper, lead, iron, mercury, and bifmuth, in the nitrous acid; and of tin in aqua regis. The pre- cipitate of iron from fpirit of fait is a tenacious mafs ; that of filver from aquafortis, fometimes a white pow- der, fometimes tenacious. Copper from aquafortis is fometimes thrown down in form of a white powder, and fometimes in that of a green oil, according to the proportions and dilutenefs of the liquor. Silver is not precipitated at all by this acid from its folution in vine- gar, nor gold from aqua regis. " An ounce of the vitreous fait, well mixed with half an ounce of foot, and committed to dillillation, yielded a drachm of fine phofphorus. The black refi- duum, beitig elixated with boiling water, and the li- quor paffed through a filter, there remained upon tlie filter eight fcruples of a black matter j and, on eva- porating and cryftallizing the liquor, about feven drachms were obtainedof oblong cryllals, which did not deliquate in a moift air, but became powdery in a warm one. Thefe cryftals, treated afreih with inflam- mable matter, yielded no phofphorus. Before a blow- pipe ^they melted into a tranfparent globular mafs, which, on coohng, became turbid and opaque. Dif- folved in water, they piecipitated folutions of filver, mercury, copper, and of chalk ; though they did not a&. upon the latter fo powerfully, nor produce with it a gluey mafs, as before they ^had been deprived of their phofphorine acid." Mr Wiegleb informs us, that the phofphoric acid exhibits lefs affinity with calcareous earth, in the moift way, than the vitriohc ; though it cannot be fepara- ted from the idtimate refiduum of the calcareous eartli by that acid. It expels, however, all the liquid acids from their bafis in the dry way. It precipitates iron from a folution in vitriolic acid, of a perfedly whit.c colour. For the ufes of this acid as a flux, fee the ai'ticle BLow-pipe. § \0. Of the yield of J[>rTS. id 907 The acid may be obtained from thefe infeds either How {iro- by raaice. C HEM cid of by diltillation,, or fimplc infufion in water. From (ifphoru? twenty-four ounces of ants, Neumann obtained eleven I S T R Y. ounces and an half of acid as fti-ong as good vinegar, ^11. Of t/je Acid of Amber. by dillillation: in balnea marlac. Of this acid, Mr Mar- graalf gives the following account in the Berlin Me- moirs for I 749. " The acid of ants efiervefces with alkaline falts, both fixed and volatile. AVith volatile alkalies it forms a neutral liquor, which, like that compofed of the fame alkalies and vinegar, yields no concrete fait on ddlilla- tion. With fixed alkalies it concretes, upon proper exhalation, into oblong cryflals, which deliquate in the air. The cryftals, or the faturated neutral li- quor uncryftallized, on being dillilled with a fire increafed till the retort began to melt, yielded a liquor fcarce fenfibly acid, and afterv/ards a fmall quantity of an urinous and partly ammoniacal liquor. The remaining black matter, diffolved in diiliiled water, filtered and evaporated, fiiot into large cryftals vvhicli did not deliquate in the air, though they were in talte llrongly alkaline, effervefced with acids, and had all the other properties by which fixed alkalies are diftinguiihed. " This acid diflblves, with great effervefcence, coral, chalk, and quicklime; and concretes with them all into cryftals which do not deliquate in the air. " It does not precipitate filver, lead, or mercury, from the nitrous acid ; nor quicklime from the ma- rine. Hence it appears to have no analogy to the ma- rine or vitriolic acids ; the firlt of which conftantly precipitates the metaUic folutions, and the other the earthy. " It does not — and Mr Pott is the only chemift who feems to have examined it with accuracy. We fnall therefore give an abftrafi of the principal obfervations and experi- ments he has made on this fait. " Salt of amber requii-es a large quantity of water Mr Pott's for its folution. In the firft cryftalUzation (being experi- much impregnated with the oil, v\'hlch rifes from the amber along with it), it ftioots into fpongy flakes, in colour reiembling brown fugar-candy; the cryftals which fucceed prove darker and darker coloured. On repeating the depuration, the cryftals appear at top of a clear yellow or whitifti colour, in form of long needles or feathers ; at bottom, darker, and more ir- regular, as are likewlfe the cryftals which flroot after- wards. The cryftals neither liquefy nor beconie pow- dery in the air: rubbed, they emit a pungent fmelllike that of radiflies, efpecially if warmed a little ; their tafte is acid, not In the leaft corrofive, but with 3 kind of oily pungency. " This fait, kept in the heat of boiling water, lofes nothing of its weightj and fufl"ers no alteration. In a great heat it melts like oil ; after v/hlch a little oily acid arifes, then oily ftrire appear in the lower part of the retort, and the fait fublimes into the neck, partly in the form of a dark yellow butter, and partly in that of feathers, a black coaly matter remaining at bottom ; fo that, by this procefs, a part of the fait is deftroyed. *' Oil of turpentine has no aftion on this fait. Highly reftified fpirit of wine gains from it a yellow colour in the cold; and, on the application of heat, dllfolves cl confiderable quantity, but depofites great pai-t of it on cooling. The fait thus depofited is fome- what whiter than before, but ftlll continues fenfibly yellow. The dulcified fpirit of fal ammoniac diflblves- it readily, without eff^ervefcencc, into a yellow liquor ; if the fait was foul, the folution proves of a red co- lour ; on burning of the vinous fpirit, a neutral liquor remains. ** A folution of fait of amber in water, faturated with a pure alkaline lixivium, yielded, on infpiflation, a faline matter, which would not cryftallize, and which, when exficcated by heat, dellquated In the air, leaving a confiderable proportion of an earthy, unc- tuous matter. Being again gently infplfleited, it left a brownifli fait, very foluble, weighing one half more than the fait of amber employed. This fait cffervef- ced with the vitriolic and nitrous acids : the vapour, which exhaled, was not acid, but oily and fulphureous. On repeating the experiment, and fully faturating the alkali with the fait of amber, the neutral faltlraade no effervefcence with thefe acids. This fait did not per- feftly melt before a blow-pipe ; continued in the fire for fome time, it cfl^crvefced with aquafortis. In dif- tiilatlon it yielded a bitter, oily, alkalefcent fpirit, much refembling the fpirit of tartar ; and towards the end, an empyreuiuatic oil. The refiduum elixated, yielded the alkaline fait again of a brown colour. " Salt of amber eff^ervefces ftrongly with volatile alkalies ; and, on faturatlon, forms with them an oily am- - CHEMISTRY. Pradlce, acid. ainmoniacal liquor, which, in diftillatlon, totally arifes in a fluid form, except that a fmall portion of a pe- netrating, oily, faline matter, concretes towards the end. " On diflllling fait of amher with an equal quanti- ty of commmon fal ammoniac, a marine acid fplrit fal ammo- '^^^^^ over, of a ftrong fmell, and a brown colour : riac and ni- afterwards, a little white fal ammoniac fublimed ; at trc. length arofe fuddenly a large quantity of a fuliginous or bituminous matter, leaving behind a fmall portion of a like fhining black fubttance. The coaly matter was confiderably more in quantity than the fait of am- ber employed. On treating it with nitre, red va- pours arofe, and the mixture detonated with vio- lence. -A. mixture of it with borax, frothed and fwell- ed up much more than borax by itfelf ; and, on rai- ling the fire, yielded only fome oily drops ; the acid being deftroyed by this fait, as by fixed alkalies and pji quicklime. Purified by " Spirit of fea fait, poured upon one-fourth its the marine weight of fait of amber, made fcarce any folution in the cold : on the application of heat, nearly the whole coagulated into the confiftence of a jelly. In diftilla- tlon, the fpirit of fait arofe firft ; then almofl the whole of the fait of amber, partly like firm butter, partly like long ftriated plumous alum, very pure, and of a fine white colour, its oily matter being changed into a coal at the bottom. The fait, thus purified, makes no precipitation in the folution of filver, and confe- quently retains nothing of the marine acid ; nor does it precipit-ate folution of quicklime made in fpirit of fait, and confequently contains nothing vitriolic. , If any of the mineral acids was contained in this fait, it Gould not here efcape difcovery ; the oil, which in the rjough fait is fuppofed to conceal the acid, being in this procefs feparated. " Aquafortis being poured upon one-fourth its weight of fait of amber, extradled a yellowifh colour from it in the cold, but diffolved little : on the appli- nitre on it. cation of heat, the whole dlffolves into a clear liquor, without any coagulation : if the fait is very oily, the folution proves red. In dillillation, the greateft part a- rifes in a liquid form, with only a very fmall quantity of concrete fait. The fpirit does not aft upon gold, but dlffolves filver, and quickfilver, as at firft ; a proof that it has received no marine acid from the fait of amber. " Oil of vitriol being added to twice its weight of fait of amber diluted with a little water, a moderate fire elevated an acidulous liquor, which appeared to proceed from the fait of amber ; for its making no change in folution of fixed fal ammoniac, fhowed it not to be vitriolic. On continuing the diftillation by a ftronger fire, greateft part of the fait arifes unde- llroyed, and the oil of vitriol along with it ; a black, light, porous earth remaining. " Equal parts of quicklime and fait of amber gave over in diftillation only an acidulous phlegm ; the refi- duum, ehxatv"d with water, yielded a folution of the lime in the acid of amber, , refembling a folution of the fame earth in vegetable acids^ precipitable by alkaline falts, and by the vitriolic acid. Lime, addedto a wa- tery folution of fait of amber, dlffolves with fome ef- fervefceuce j after which, the whole coagulates into 9Ta Efieds of fpirit of Of oil of vitriol. 914 Of quick liivcr. the confiftence of a jelly: this, diluted whh water,AcM of Af proves fimllar to the foregoing folution. Comb na"^' " Solution of fait of amber makes no precipitation ^j^^jj^ in folutlons of filver or quickfilver. It dlffolves zinc, . — ^— — i as all acids do ; fixed alkalies precipitate the zinc: the 915 volatile do not ; and when a fufficlent quantity of the Effe»5ls of volatile has been added, the fixed make no precipita- "^^^^^J tion. It adls exceedingly flowly and difficultly "pon j^^^^^^^^j^ copper; but corrodes calcined copper in afirorter time. It foon corrodes iron, by co£lIon, into a crocus, and dlffolves a part into a liquid form : the folution has little colour ; but alkaline falts readily difcover that It holds iron, by rendering it turbid and whitifh, and throwing down a confiderable quantity of a greenifli calx." - ^^2. Of the Acid of Arsenic. 916 Mr Scheele firft perceived, from fome experiments How firfi. on manganefe, that arfenic contained phlogifton : from '^^^'^'-'vered. whence he was led to an analyfis of this fubftance, which produced an acid of a very fingular kind ; by uniting of which with phlogifton in certain propor- tions, either white arfenic or its regulus may be com- pofed at pleafure. White arfenic maybe decompounded In two ways. Two ways I. Put two ounces of it reduced to fine powder in aofdeo-m- glafs mortar into a retort of the fame material ; pour upon it feven ounces of pure muriatic acid, whofe fpe- ^ clfic gravity is to that of water as 10 to 8 ; and lute on a receiver. The arfenic is quickly diffolved in a boil- ing heat, which muft be brought on as quickly as pof- fible. After the folution is accompliffied, while the By means liquor is ftill warm, three ounces and a half of nitrous "f nitrous acid, of the fame fpecific gravity with the muriatic '^'^^'^* above-mentioned, is to be added, and the liquid which had already gone over into the receiver poured back. The receiver is then to be put on again, but not luted; the mixture foon begins to effervefce, and red vapours go over into the receiver. The diftillation is to be con- tinued till thefe vapours ceafe ; when an ounce of finely powdered arfenic is again to be added, the re- ceiver applied as before, and a gentle ebuUition con- tinued until the fecond quantity of arfenic be diffolved. An ounce and an half of nitrous acid is then to be added, and the mixture diftiiled to drynefs, increafing the fire towards the end, fo as to make the retort red hot. The acid which comes over Into the receiver may ferve again feveral times. The white mafs which re- mains in the retort is the dry acid of arfenic. It may be reduced to a liquid form by pouring upon it, in coarfe powder, twice its weight of diftiiled water, and boiling for a few minutes, pouring back the liquor which comes over, and afterwards filtering the folu- tion through blotting paper, which has been previouily vvaftred in hot water. In this procefs the nitrous acid attacks the phlo- gifton of the arfenic, is volatilized in confequence of its union with it, and leaves the more fixed but lefs powerful acid of arfenic behind. The nitrous acid would alone be fufficient for this purpofe, could it ac- curately come into contaft with the particles of arfe- , nic ; but this cannot be done without folution, and .the nitrous acid is capable of diffolving arfenic only in pro- >ra£llce. CHEMISTRY, 919 ici ' of Ar- proportion to thf v.'nter it contains. Too great a cjuan- Euican 1. it-jjty would therefore be required were this acid to be :ombiiia- ^^r^^ itfelf ; but by the ufe of muriatic acid for tlie ' folution, a fmallcr quantity of fpirit of nitre is admit- ted to intimate contaCl with all the arfenical particles, and has an opportunity of depriving them of their phlo- glfton. Aqua regia might be poured upon the arfenic at once ; but the great effervefcence it excites would throw the mineral up to the top in fuch a manner that the menftruum could not a£t upon it. By the opera- tion of dephlogifticatlon, arfenic lofes a fifth part, which is fuppofed to be pure phlogifton. Sy dephlo- The other method of decompofnig arfenic is, by •illicated means of the dephlogifticated fpirit of fait. For this P!"^ purpofe, take one part of powdered manganefe, and mix it with three of the muriatic acid above-mention- ed. Put it into a retort, of which it may fill one- fourth ; a receiver containing one-fouith of powdered arfenic, with one-eighth of diilllled water, is to be luted on, and the retort put into a fand-bath. The dephlo- gllilcated muriatic acid, going over into the receiver, is inftantly abforbed by the arfenic ; which fome hours afterwards will be diiTolved, and two different liquid ftrata, which cannot be mixed together, will be per- ceived in the receiver. This folution is now to be put into a clean glafs retort, and diftllled to drynefs ; in- creafing the fire at laft to fuch a degree as' to make the whole red hot : and in this procefs alfo two dif- ferent liquids pafs over into the receiver which do not unite togethei'. Here the manganefe attrafts the phlogifton of the muriatic acid ; and as this dephlogifticated acid has a very ftrong attraftion for phlogifton, it deprives the arfenic of its phlogifton, and thus recompofes the or- dinary phlogiflicated muriatic acid. This portion of recompofed acid diftblves part of the arfenic, forming •with it what is called kiiter of arfenic. The other part of the arfenic which has been decompofed, diftblves in the water, and forrrw a liquid fpecifieally lighter than the butter, and therefore iwims above it. On recti- fying the two liquids, the undecompofed portion of the arfenic arifes along with the muriatic acid, and goes over into the receiver in form of an heavy oil, while the acid of arfenic remains behind in the retort. The acid obtained in this way is preclfely the fame with the former, and one would hardly believe that it is an acid, becaufe it has no acid tafte ; but after fome days it grows moift in the air, and at laft deliquates, affuming the appearance of oil of vitriol. As the de- liquefcence, however, is very flow, it is proper to dif- folve it in a certain quantity of water, when a fmall quantity of white powder remains undlfTolved, after preparing it by the firft procefs, which is filiceous earth derived from the retort. This ought to be carefully feparated from the acid by filtration ; and in order to prevent the glue of the blotting-paper from mixing with the acid, it was direfted to wafti the filter with hot water previous to the operation. Acid of ar- The firft experiment M. Scheele tried on this acid sc: ic equal- after he had obtained it, was to difcover if it was as ly j 01(011- noxious to animals as when combined with phlogifton. tbe wh^^e having mixed a little with honey, the flies that eat of ,. which could not be taken ojf. Solu- tions of cobalt m mineral acids are readily precipitated by the arfenical neutral falts. The precipitate is of a rofe-colour, but melts with di£5.culty into a. dark blue fcoria. 35. Nickel, with acid of arfenic, afTumes a dark green colour, and lets fall a green powder containing arfenic in fubilance, which may be feparated from it by a gentle heat. One part of nickel diftilled with two of dry arfenical acid, melted with fome appear- ance of inflammation, yielding fome arfenic at the fame time. The mafs was yellow, with a number of grey elevated ftreaks upon it,, which appeared like ve- getation, and were formed during the diftfflation. On boiling the yellow mafs in water, the acid was diffolved, leaving a yellow powder behind; which, when treated with charcoal-powder, yielded regulus of arfenic, but was not reduced itfelf. The folutions of nickel in acids are not precipitated by arfenical acid, not even that in vinegar, but the neutral arfenical falts throw down a whitifli green powder.. 36. Manganefe in its natural ftate is diffolved only jn fmall part ; but when phlogifticated it diffolves rea- dily and totally ; though, whenever the acid arrives at the point of faturation, the folution coagulates into fmall cryftals. 37. Regulus of arfenic digefted with its own acid foon becomes covered with a white powder, which is arfenic in fubftance. On diftilling one part of the re- gulus with two of the acid, the former fublimed, and the latter melted. If fmall pieces of regulus of arfenic be gradually added to the acid of arfenic in fufion, an inflammation takes place, and arfenic is fublimed. On diftilling a mixture of equal parts of terra folia- ta tartari and arfenic, a limpid liquor like water firft came over, fmelling ftrongly of garlic ; on changing the receiver, n liquor of a brownifti red coJour was col- lefted, which filled the receiver with a thick cloud, . emitting an intolerable fmell of arfenic. On pouring this upon a filter, hardly a few drops had pafied when, a very thick ftinking fmoke fuddenly arofe as high as the ceiling of the room ; an ebullition enfued towards the edge of the filtering-paper, and a fine rofe-colour- ed flame broke out, that lafted for fome momeiits.. $ 13. Of t^e jicld of MOLYSDXN^, We owe this, as well as the fucceeding acids, to the induftry of the late jVTr Scheele. The fubftance from which he extracted it is named by Cronftedt mo- lyhdcena memlranacea miens. — As this fubftance is of a flaky nature, and incapable of pulverization by it- felf, our author mixed feme pieces of vitriolated tar- • tar along with it in a glafs mortar ; by the attrition of whicTi- it was at laft reduced to a fine powdtr, and which was afterwards freed froni.thc. vitriolated tar- Pra{5llce, tar by wafliing with hot. water. He then treated this Acid of powder with all the known acids, but found none of '^^^'i 1 , „ . ' . ^ . ^ . tia and its them to have anyelfect upon it excepting thole ot arienic Combina- and nitre. No fenfible effedl was perceived from the tions. acid of arfenic until the water was evaporated ; after ^— v— > which, by increafing the fire, a Httle yellow orpiment 959 was fublimed in the neck of the retort, and fome ^"1- ^c'^a^]^^^ phureous acid pafled over into the receiver. On pour- arfenic ing two parts of concentrated nitrous acid upon one upon it. part of powdered molybdaena, the mixture was fcarce . ^560 warm in the retort, when it pafled all together into y'"'^"*^ the recipient with great heat, and in the lorm 01 aark j-eufrated red vapours. Had the quantity been larger, he had nitrous no doubt that it would have taken fire j for which rea- ^cid uj^oa fon the experiment was repeated with diluted nitrous j^^'^^^^"^' acid. Six ounces of diluted nitrous acid being poured on an ounce and a half of powdered molybdaena, no efieft was perceptible till the liquor began to boil ; after which a great number of red elaftic vapours began to appear, and the mixture fwelled confiderably. The diftillation being continued to drynefs, the refiduum appeared of a grey colour ; the fame quantity of ni- trous acid was poured on, and the procefs repeated, when the refiduum was whiter ; and on ftill repeating the operation a fourth and fifth time, the remaining^ powder became at laft as white as chalk. This re- fiduum, after being edulcorated witli hot water, was quite taftelefs and infipid when dry. The Hmpid li- quor which ran from it, being evaporated to half an ounce, firft afliimed a fine blue colour, and then grew thick. On being examined, it was found to contain fome iron, and was otherwife chiefly acid of vitrioL The colour difappeared on diluting the acid with water. 961 The white powder juft mentioned is the true acid Acid of of molybdaena, and maybe obtained by the help of molybdse- fire alone. A fmall piece of molybdasna expofcd on a"^ "^^.'^^'.^'^'^ frlver plate to the blow-pipe, makes a beautiful appear- ^J^^"^ ance, when the white vapours attach themfelves to the plate in the form of fmall fliining fcales,. in the direc- tion of the flame. This white fubhmate becomes blue whenever it is in contaft with the blue flame ; but changes to white whenever the point of the flame is direfled againft it. An ounce of powdered molyb- daena was mixed with four ounces of puiificd nitre,, and detonated in a crucible heated thoroughly red hot. The mafs thus obtained was of a reddifli colour. On diflblving it in water, the folution was clear and co- lourlefs. A fmall quantity of red powder fell to the- bottom of the veflel ; which, when dry, weighed i l;^ grains, and fliowed iffelf to be an iron ochre. By- evaporation vitriolated tartar and nitre were obtained ; , but a good deal of lixivium remained, -which rcfufed to cryftallize, though no mark of fuperftuous alkali re- mained. It was then mixed with lome water, to which diluted acid of vitriol was added, until no more pre- cipitate fell. The white powder which precipitated weighed three drachms ; but if too much acid be added, the precipitate will be rediflolved, and the wa- ter itfelf retains a part of it in folution. A precipi- tate is likevvife. obtained by means of nitrous or muri- atic acid. The precipitate thus obtained, like thofe which rcr chcmi- fult from the two former procefies, is the true acid of cal prop'et»'j molybdaena, and has the following chemical properties, ties. I . The raaice. C H E M cid of I. The folutJon reddens lacmus, coagulates a folutioa olybdae- foap, and precipitates hepar fulphuris. 2. If this la aiKi its boiled with the hUngs of any of the im- iol^""" perfeft metals, it affumes a hluifti colour. 3. By the ^ ' addition of a little alkali of tartar, the earth becomes foluble in greater quantity in wafer ; and aftei evapo- ration (hoots into fmall confuftd cryftals. 4. Under the blow-pipe this earth is foon abforbed by charcoal ; but when placed on a filver plate it melts, and evapo- rates with the fame phenomena as molybda^na itfelf. 5. By the addition of alkali, the earth is deprived of its property of being volatilized in the fire. 6. The lo- lution, whilft hot, fliows its acid power more evidently than when cold, and tinges lacmus of a deeper colour. It effervefces with chalk, with magnefia, and with earth of alum ; with all of which it forms lalts very difficult of folution in water. 7. It precipitates, from the nitrous acid, filver, quickfilver, and lead, as alfo lead difiblved in marine acid. Thtfe precipitates are reduced on burning charcoal, and the melted metal runs into the pores. Corrofive fublimate is not pre- cipitated ; neither are the folutions of the other me- tals. 8. Terra ponderofa is alfo precipitated from the nitrous and marine acids ; and the precipitate is foluble in a large quantity of cold water. None of the lolu- tlons of the other earths are precipitated. 9. Fixed air is alfo expelled by this acid from the fixed and vo- latile alkalies, and forms with them neutral fahs which precipitate all other metallic folutions. Gold, corro- five fublimate, zinc, and manganefe, are precipitated in form of a whhe powder ; iron and tin, from their folution in marine acid, of a brown colour ; cobalt of a rofe colour ; copper of a blue ; the folutions of alum and quicklime, white ; and if the ammoniacal fait form- cd by the earth of molybdsena and volatile alkali be diililled, the earth parts with its alkali in a gentle heat, and remains in the retort in form of a grey powder. 10. Concentrated vitriohc acid diflblves a great quan- tity of this earth by means of heat. The folution ac- quires a fine blue colour; which, however, difappears on being heated, or by diluting the acid with water. In a ftronger heat the acid flies off, leaving the earth unaltered behind. This folution becomes thick on coolinfT. 1 1. The nitrous acid has no efFeft upon the earth *of molybdcena. 12. Boiled with the muriatic acid it diflblves in confiderable quantity ; and, on di- ftilHng the mixture to drynefs, a daik-blue. refiduum remains. On increafing the heat, white flowers arife, with a little blue fublimate, and a fmoking muriatic acid is found in the receiver. The refiduutn is of a grey colour. Thefe flowers are only the earth of mo- lybda;na volatilized by means of the muriatic acid, and lher..;Fore manifefts the fame properties. 13. If one part of this earth be diftilled with tvfo parts of vitriolated tartar, a little vitrioHc acid pafles over,_ at leaft when the heat is very ftrong ; and the remaining earth is more foluble in water than before. 1 4. With two paits of nitre it expels, by means of diftillation, a ftrong nitrous acid ; the refiduum diflolved in w^ater is a neutral fait which precipitates all metallic folutions, and is fimilar to that formed by a direft union of the acid and fixed alkali. 15. Diftilled with two parts of pure common fait, the acid is expelled in a fmoking ftate, and white, yellow, and violet- coloured flowers arife, which become moift in the air, and when fprinklcd metals give them a blue colour. Thefe flowers, I S T R Y. 507 as has been already remarked, are only the acid ofAcId of molybdaena volatilized by that of fea-falt. ?^°'l'j1f; , . , -111' \^ ' .-L na ana it* The blue colour acquu-ed by this earth on the con- ^^^j^^^^.^jj^. tad of flame, alfo in the moift way in fome cafes, tions fliows that it is capable of contrafting an union with — --v— the phlogifton. To reduce this to certainty, Mr 963 Scheele diflblved fome of the earth of molybdaei* inJ'f^^PjJJ* boiling water, with the addition of a little alkali. In- ^^ilh" phi*, to this folution he poured fome drops of muriatic acid, ^ifton. and divided it into feveral parts, into each of which he put filings of feveral metals. The folutions foon acquired a bluIOi colour, which grew deeper and deep- er ; and in an hour's time, during which the bottle was now and then fliaken, the hquor afl'umed a fine dark blue. That this colour depends on phlogifton,- he infers from the following circumftances : i. If, in- ftead of the metals themfelves, you take their calces,' no blue colour is produced. 2. If there be dropped into the blue folution a few drops of acid of nitre, and the folution be then put into a warm place, the colour difappears. It is therefore no matter of furprife, that both filver and quickfilver fliould be attacked, fince a double eledive attraftion takes place ; the muriatic acid uniting with the metallic calx, and the earth of molybdcena with the phlogifton of the metals. Gold, however, is not attacked in this way. 3. Too great a quantity of muriatic acid produces not a blue but a yellowHh colour, which at laft turns brown if the mix- ture be digefted ; but on adding this folution to a fo- lution of the earth of molybdjena, a blue colour as u- fual is produced. 4. Lixivium fanguinis, in which the acid prevails, throw;> down the earth of a brown colour, and the infufion of galls of a dark brown. The acid of molybdxna, treated with various fluxes, shows no and with charcoal, fliows no figns of containing any fjjjn of con- metalhc mutter. Moiftened with oil-olive, and com- ^'^Jf mitted to diftillation in a ftrong fire, it did not fub- * lime, but remained in the retort in form of a black powder ; which, on being calcined in a crucible, fub- limed in white flowers as ufual. On inverting another crucible into the former, and luting the jundure, the earth remained unchanged and of a black colour, with- out any fign of fufion. This black powder did not diftblve in boiling water, nor even with alkali, which on other occafions fo readily diflblves it ; but vv-hen mixed with a triple quantity of fait of tartar, a great efi^ervefcence enfued ; tbe produce was a neutral fait refembling that formed by the diredt union of the acid and alkali. 965 Tlie earth of molybdaena, procured by nitre, re- Properties quires much lefs water for its folution ; it does not"^^'^'^^^"^ expel the acid from vitriolated tartar ; is more eafily^j^'^^^'"^ ^ fufed, and does not fublime in an open crucible. When fufed with charcoal-powder, it affords a folution with water, containing a neutral fait, which precipitates all others. The reafon of thefe diff"erences is, that it contains a portion of alkali, though it be ever fo fre- quently purified by folution and cryftallization. That this is the cafe we know from the following experi- ments : 1. If to a folution of the nitrous earth ofmo- lybdsena we add fome nitrous acid, the latter attacks the alkali, and the greateft part of the diflblved earth is precipitated. This, however, does not happen, ex- cept by long boihng. 2. The neutral fait obtained by fufion proves the fame. This neutral fait is pro- duced in the following manner. The earth which con- 3 S 2 tJU*5 5o8 Acid of Molybdse- na and its Combina- tion'^. 966 Molybd»- na recom- pofed by uniting its acid With 967 This lub- ftavce conr fidei ed as a metallic earth by Mr Berg- man. 968 Schcele's method of analyfing it.. C H E M I tains only a fmall quantity of alkali operates as an acid, as appears from its changing the colour of lacmus to red ; but the alkali prevents as np.uch earth from enter- ing into it as is neceflary to its faturation with plilo- 'gifton; for the acid of 'molybdcsna has a greater at- traftion for alkali than for plilogiflon. The charcoal whitih remains after lixiviating the compound of acid of molybdasna and charcoal, yields vapours in an open crucible, and gives a fublimate containing the phlo- gifticated earth of manganefe. This alkali fixes the earth in the ©pen air ; and hence we fee alfo the rea- fon why this earth does not expel the acid from vitri- olated tantar ; for its attradioH for the alkali mult di- minilh in proportion as it comes nearer the point of faturation ; and as the pure earth contains no alkali, it attrafts a little from the vitriolated tartar ; and con- fequently there can appear bnt a flight veilige of vi- triolic acid. This fmall quantity of acid likewife oc- cafions its more eafy fohibility in water. The pure acid of molybdosna recompofes that fub- ftance by being combined with fulphur. Mr Scheele having mixed fome very fine powder of this earth with three parts of fulphur, and committed the mixture to dilliliation in a glafs retort, the receiver was filled with the fnperfl'jous fulphureous vapours, which had alfo the fetid fmell of volatile fpirit of fulphur. In the retort a black powder remained, which on every che- mical trial was found to be a true molybdsena ; fo that there is now no doubt of this fubftance being compo^ fed of a particular kind of acid united to fulphur. § 14- 0/ the Acid of Ly.fis PoNDEkosus., Tungsten,- or IVoLFRAM.. This fubftance has been analyfed both by Mr Scheele and Mr Bergman, though the former has the merit of difcovering the acid contained in it ; which the latter confiders, as well as the earth of molybdsena, not as truly acid, but as metallic earths. Mr Scheele's ex- periments for analyfing this fubftance were as follow ; I.. On one part cf finely powdertd tungftcn were pour- ed two parts of concentrated acid of vitriol. By di- ftiilation the acid pafled over unchanged ; the refidu- um, which was of a- bluifii colour, after being boiled for a (hort time, and the liquor filtered dtpofited fome vitriolated lime or gypfum by ftanding. 2. Twelve fcruples, of common nitrous acid, or pure aquafortis, being poured on two of finely powdered tungften, no eifervefcence enfued ; but on expo- fing the mixture to a ftrong digefting heat, it af- fumed a citron yellow colour. The acid was then poured off into another phial, and the yellow powder edulcorated with water. 3-. On this yellow powder eight fcruples of cauftic volatile alkali were poured, and the phial expofed to heat ;. on which the yel- low colour inftantly vanifticd, and the powder be- came white. This folution was in like manner put into a feparate phial, and the powder edulco- rated ; and as the matter was fenfibly dimijiiftied by thefe operations, they were alternately repeated, till at length the whole was diffolved, exjcepting three grains, which feemed to be filicenus earth. The fame cffefts enfued on treating this fubftance with muriatic acid, only the folution was of a deeper yellow colour. 4. The folutions made in the foregoing manner with aitrous acid being all mixed together, fome drops of S T R Y. Praaice. phloglfticated alkali were added; by which about --^cid of three grains of Pruftian blue were precipitated. 5. The ^'^P*^ ^"""^ mixture was then faturated with cauftic volatile ^fp^'u"*^ alKali ; but as no precipitate appeared, a lolutioa of nations. fixed alkali vas added, wliich threw down two ' \r^--' fcruples and five grains of white earth of a mild calcareous kind. On adding feme nitrous acid to the extraAs made by volatile alkali, a white powder was ptecipitated, which, on edulcoraiion, proved to be the true acid of tungften. 7 On treating tungften with a ftrong heat in the dry Effects of way, the following appearances took place: i. One !^^^' "r°" part of tungften mixed with four of alkali of tartar''" was melted in an iron crucible, and then poured out on an iron plate. Twelve times its weight of boiiing water being then poured upon it, a white powder fub- fided to the bottom, which diffolved in a great meafure in nitrous acid. 2. The undiftblved part of the pow- der was tried ; and being again mixed with four parts of alkali, was melted as before r and the mafo being alfo diffolved in water, and nitrous acid poured on the refiduum, only a very fmall portion of grey pow- der was left undiftblved. 3. The ley being faturated w ith nitrous acid, grew thick by the precipitation of a white powder; which was afterwards waflied with cold water and dried, and then proved to be the fame acid of tungften wath that already defcribed. The folu- tion in nitrous acid precipitated with fixed alkali gave a white precipitate,, which was found to be calcareous earth.. The properties, of the acid of tungften are, i. Un-itschemi- der the blow-pipe it became firft of a reddifli yellow cal proper- ■ colour, then brown, and at laft black. It neither'^"- fmoked nor gave any figns of fufion. 2. With borax it produced a blue, and with microcofmic fait, a fea- green gTafs. 3. Boik-d wirh-a^ fmall portion of the nitrous or marine 6cids, the powdl?r becomes yello^v, and with the acid of vitriol bluifti. 4, On faturating a folution of the acid with fixed alkali^ a neutral fait in very fmall cryft;Us is obtained. 5. With volatile alkali this acid forms an ammoniacal fait fliaped like the, points of fmall pins. On diftillation the alkali fepa- rates in a cauftic ftate, the acid remaining behind in the retort in form of a dry yellow powder. On mix - ture with a folution of lime in fpirit of nitre, a double, elective attradtion takes place, the acid of tungften.; uniting itfelf with the lime, and that of nitre witli the. volatile alkah. 6. With magnelia the acid of tung- ften forms a fait very difficult of folution. 7. It pro- duces no change on folutions of alum or lime, but de- coxnpofes a folution of terra ponderofa in acetous acid,, and the compound is totally infoluble in water.. 8. It' precipitates of a white colour folutions of iron, xinc,. and copper, in the vitriolic acid ; filver, quickiilver,. and lead, in that oi nitre ; and lead in the acid of fea- falt. Tin combined with the fame acid is thrown down of a blue colour ; but corrofive fublimate and folutions of gold undergo no change. 9. On cal- cining the acid of tungften in a crucible, it lofes itS; folubility in water, i o. It turns black by calcinatioa with inflammable matters and with fulpiiur, but ia other refpeds continues unaltered. Ji. Solution of liepar fulphuris is predpitated of a green colour by this- acid, and the phlogifticated alkali white ; the latter precipitate being foluble in water. On the additioa. of a few drops of muriatic a.id to a folution of tlia acid Praclice. Acid of I .apls Poii- der( fiis an^ ICS Cornbi- rations. f 971 Differences lietwixt the acids of tunei'len and mo- lybdana. 97a Berp man's epinion Cunceriiing the nc'uU of tung- ften fipd molybdse- 973 Why he lapp(j(ed tl'.c acids to be me- tallic earths. acid of tungflen In water, and fpreading the liquor on polifhed iron, zinc, or even tin, it acquires a beauti- fid blue colour; and the kave tiling happens when thefe metals are put into the acid. 12. It diftcrs from the acid of molybd'cEna in not being volatile in tliC fire; in having little attraction for phlogiilon or fulphur ; in tvirning lime yellow, and forming an infoluble com- pound with it, as well as with ponderous earth. It has alfo a ftronger attradion for lime than the acid of mo- lybd^na; for if a combination of lime and acid ^f mo- lybdjena be digelled in a folution of the ammoniacal fait formed by uniimg the acid of tungften with vola- tile alkali, the latter expels the former, and produces regenerated tungften. 13. By uniting the acid of tungften to a calcareous earth, a regenerated tungften is conftantly procured. Mr Bergman obferves, that the acid earth of tung- ften is nearly allied to- that of molybdjEna; and both are in a ftate much refembling that of white arfenic. " It is well known (fays he) that arfenic, in its femimetal- lic ftate, is nothing but a peculiar acid faturated with phlogiilon"; and that the white calx is an intermediate ftate between acid and metal, containing juft phlogiilon enough to coagulate the acid, but remaining ftill folu- ble in water, and {howang figns of acidity. If a con- clufion from analogy be admiflible, all the other metals ftiould confift in a combination of the fame nature of the diflFerent radical acids, which with a certain quan- tity of phlogifton are coagvdated to a dry earthy fub- ftance ; and on full faturation are reduced to the ftate of complete metals." The reafons which induced Mr Bergman to fuppofe that the acids tn queftlon are metallic earths, are as follow : 1. They both fliow a ftriking refemblance to white arfenic in form, in producing effefts like acids, and in their difficult folubility in water. 2. Their fpe- cific gravity ; that of arfenic being 3750, the earth of molybdsena 3460, and the acid of tungften 3000. 3. Their precipitation with phlogifticated alkali ; a property hitherto deemed peculiar to metallic calces. Arfenic alfo, properly diflolved in muriatic acid, gives, with the phlogifticated alkali, a precipitate foluble in water, in the fame manner as the acid of tungften. 4. From their property of tinging vitreous matters ; which, aswell as that of precipitating witli the phlogifti- cated alkali, is reckoned to be a peculiar property of metals. The acid of tungften produces by itfelf fome effervefcence with mineral alkali.. With microcofmic fait it produces. a globule atlirft of a light blue ; more of the acid makes it a dark blue; but ftill it remains free from rednefs by refraflion- A further addition makes it brown. Borax acquires a flight tinge of blue, and with more of the acid becomes of a yellowifli brown colour ; but remains tranfparent, provided no fmther addition be made. This idtimate brown co- lour cannot be driven off" either by nitre or the point of the flame urged by a blow-pipe.. Acid of molyb*- dfEna is no lefs powerful; for with mia-ocofnuc falt.it produces a beautifiJ green colour : borax well fatura- ted with it app^sars grey when viewed by the.reflecled rays, but of a dark violet by the rcfracSted. § 15. Of the Acid of Milk. It' is. univerfally known, that In the fummer-time CHEMISTRY. 509 milk grovvTs four and thick in a fev; days, and that thisAcxd of ^ fournefs continues for ft)vne time to increale. It ''^ •(.^'(j ftrongeft after a fortnight has elapfcd ; after which, [j^^^Q.^g, if the wlioy be liltcrcd and evaporated to one half the ^r- — J qiiuitity, a few curds will ftill fettle to the bottom. 974 By faturating the whey with volatile alkali, a fiuaU Milk r.icft quantity of animal earth precipitates ; and the ^'^"^^^cid'at'tei ter tan '.in^ a thing takes place on the addition of lime-water. On the addition of a fmall quantity of acid of tartar, the fortnight, latter foon becomes partially faturated with vegetable alkali, and is converted into tartar. Thus the acid of Component- milk, befides its proper acid part, contains animal earth pr;nciples and vejretable alkali in a loofc ftate, and which is at- of f<'"r trailed by the acid of tartar ; bcfides all thefe, it has ^ alfo a fmall quantity of the fame vvlkali faturated with muriatic acid. It is no eafy matter to feparate thefe fubttances from one another ; becaufe the acid is not fufficiently volatile to rife in diftillation by a gentle heat, nor are its principles fufticiently fixed to bear the aclion of a ftrong fire. With "the one therefore it remains almoft entirely in the retort, and virith the other it is deftroyed. Mr Scheele therefore uied the fol- lowing procefs,. He evaporated four, whey till only one-eighth part Scheele '3 remained; when the cheefy part being totally fepa- "''^^^"^ rated, he ftrained the acid; and in order to obtain the '"^ animal earth, faturated the hquor with lime, dilutmg ^cid »f the fohition with a tripld quantity of water. In or- milk, der to feparate the lime, he employed the acid of fu- gar, w^hich has a ftronger attraAion than any other for lime. This earth therefore being feparated, the mat- ter was evaporated to the coniiftence of honey, and highly re£lified fpirit of wine poured upon it to diflblve the acid part; wiiich being accompalhed, the other faline fubftances were, left by themielves : and, laftly, the acid folution being diluted with pure water, and the fpirit feparated by diftillatioriy the pui-e acid re- mained in the retort. The properties of the acid of milk are, i . Evapo- Prope'rt;ei^ rated to the confiftence of a fyrup, it ^aelds no cryftals ;of this acidJ- and when evaporated to drynefs, it deliquefces. 2. By diftillation it yitlds frrft water, then a weak acid like fpirit of tartar; afterwards fome empyreumatic oil, with more of the fame acid. Irxed air, and inflammable air ; in tlie retort was left a fixed coaL 3. By fatu- ration with fixed vegetable alkali it yields a deliquef- cent fait, foluble in ipirit of wine. 4.. A fait of a fi- milar kind is obtained by combining it with mineral alkali. 5. With volatile alkali a deliquefcent fait is . produced, which by diftillation yields a great deal of its alkali before the acid is deftroyed by heat. 6. It forms deliquefcent falts with terra pOnderofa, lime, and clay ; but with magnelia it forms fmall cryftals, which, however, are again deliquefcent. 7. It has no effeft either by digeilion or boiling on bifmuth, cobalt, re- gulus of antim.ony, tin, quickfilver, or gold. How- ever, after digeilion with tiri, it. precipitated gold from its folution in aqua-regia, in the form of a black pow- der. 8. It diffolves iron and zinc, ..producing inflam- mable air during the folution. The liquor produced by the dilfolution. of. iron was brown, and yielded no cryftals ; but the folution of zinc cr}'ftallizes. 9. Cop- per diffolved in this acid communicates to the liquor, firft a blue, then a green, and then a dark blue colour, , without cr^'•ftaUizing. ic. Lead wa& diffcilved after fcm.e.. 510 /Vcid oi M:lk and it- Combi- Jiations. 978 It feeais to l)e of the acelous 'kind. G H E M 979 ■Milk ca- pable of romplere fermenta- tion. aa9?9 Ci>n-ve:ted into vine- gar. 9 So Acid of fugar of milk how procured. I'orne dixyr, tlii^AVnn ? the folutlon had a fvveet aftriu- gent tafte, and would not cryftallize. A fmall quan- tity of Avhite matter fell to the bottom, which on exa- mination wks found to be .vitriol of lead. " From thefe experiments (fays Mi- Soheelc) it ap- pears, that the acid of milk is of a peculiar kind ; and though it expels the vinegar from the acetated vegeta- ble allvnli, yet it feeras deiHnedjj, if I may fo fpeak, to vbe vinegar ; but from the want of fuch fubftances as, ••during fermentation, produce fomc fpirituous matter, it ■feems not to be volatilized, though a portion of it in- deed arrives at tbis point, and really becomes vinegar: for without a previous fpiritous fermentation, or with- out brandy, there never arifes any vinegar. But that the milk enters intw a complete fermentation though there be no hgn of brandy prefeirt, appears from the following experiment : If a bottle full of frefa milk be inverted into a veffel containing fo much of the fame iiquor that the mouth of the bottle"^ reaches below the furface of the latter, and if you expofe this bottle to a degree of heat a little greater than our fummer, you ■will find, ill the fpace of 24 hours, that the milk is not ■only coagulated, but in part expelled out of the bottle; and that in a couple of days afterwards, the aerial acid extricated from the milk will have expelled the greater part of it. It was faid above, that the acid of milk cannot be converted into vinegar, from the want of fuch fubftances as during fermentation produce brandy ; which appears to be evident from this : If to a kanne of milk you add five fpoonfuls of good brandy, and ex- pofe the velTel, well corked, in fuch a manner, however, that you now and then give vent to the air developed •dui-ing fermentation, you will find in a month, focaer or latter, that the whey will be changed into good vi- negar, which, ftrained through a cloth, may be kept in bottles." The acid of fugar of milk is confiderably different from that juft now defcribed. To procure it, Mr Scheele poured 1 2 ounces of dduted nitrous acid on four ounces of finely powdered fugar of milk con- tained in a glafs retort, to which a receiver was adapted. The retort was placed in a fand-bath, and as foon as the mixture acquired a certain degree of heat, it began to effervefcc violently ; for which rea- fon, the retort and receiver were taken away from the fire. The mixture, however, continued to grow hotter and hotter, with a great emilfion of dark red ■vapours continually increafing, for half an hour. A confiderable quantity of nitrous air and aerial acid were extricated during that time. Care mull be ta- ken, therefore, to have the retort and receiver both of a fufficient fize, and not to make the luting too tight. When the eftervefcence had fubfided, the retort was again placed in the fand bath, and the nitrous acid thus diftilled off till the mafs acquired a yellowifli colour ; on which the retort was immediately taken away from the fire. In two days time the folutlon fcemed to have undergone no remarkable change, nor was there any appearance of cryftals. Eight ounces more of the fame nitrous acid were therefore added, and the whole expofcd to the fame degree of heat as before. "When the mafs grew warm, another effervefcence, though weaker than the former, enfued ; the yellow colour difappeared, and the nitrous acid was again ab- flrafted, till the folution, which had beea rendered I S T R Y. Praaic In diftilling terra fo- Acetous liata tartari in the dry way, the acid of vinegar which Hmo^ enters its compofition is almoft entirely deftroyed,'^''"'^'^ only ^f^-th of pure acid being obtained, the rcfiduumt fi"/^*^ in the retort, an well as the reft of that which comes * over into the receiver, being entirely alkaline; and the ^ fame Pradice. C H E M Identity of fame thing happens to the acid of tartar, the empy- ^^^^^^j^*-^' reumatic acid above mentioned being exti-emely weak. ' Mr Beaume likewife informs us, that if any calcareous earth, egg-fliells, for inftance, be diflblved in vinegar, and the cryftaUized fait be diftilled, we obtain of a red and veiy fieiy inflammable fluid, fmelling like em- pyreumatic acetous ether, which reddens tindture of turnfole, Muft, diftilled before fermentation, yields only an empyreumatic acid refembling fpirit of tartar. The conjefture therefore feems reafonable, that vine- gar and tartar have for their bafis the fame fpecies of acid, which in the cafe of vinegar is combined with a greater proportion of oil, and in tartar with more earth. To bring vinegar therefore nearer the ftate of tartar, we muft deprive it of its fine volatilizing phlo- iiig vinegar gifton, combine it with more fixed matter, and re- ftate^of tar ^^'"^ grofler oil. All this, however, is extremely " difficult to be effefted. Mr Weftrumb, who attempt- ed it, added nitrous acid in various proportions, but could only produce a phlogiftication of the latter, and dephlogiftication of the vinegar ; but as he could not fu"atte*nipt. t'li"^ of any method of feparating the two acids from one another,- he was unable to inveftigate the pro- perties of vinegar thus dephlogifticated. Dr Crell is of opinion, that this might have been done by ve- the poffibi- getable alkali, lime, and terra pcnderofa. The ni- ^trlsni^^ trous acid, with vegetable alkali, would have ftiot in- jjgjj^ ' " to the ordinary hexangular cryftals of nitre : the ace- tous acid would have formed a compound not eafily cryftallized, provided it had remained unchanged ; and, though it had approached the nature of faccharine acid, would ttill have formed a compound difficultly cryftallizable. The effefts of thefe acids, indeed, on lime, are direftly oppofite to what they are on terra ponderofa. With the former, nitrous acid forms a liquor which can fcarce be cryftallized ; with the lat- ter, it produces falts difficult to be diffolved : while the acetous acid, with terra ponderofa, forms deliquef- cent falts ; with lime, fuch as efflorefce in the air. But if the vinegar, by means of the operation already men- tioned, had been made to approach towards the na- ture of acid of fugar, tranfparent cryftals would im- mediately have fallen, by reafon of the ftrong attrac- Method re- of this acid for lime. Dr Crell therefore recom- commendcd mends the following method. Let nitrous acid be fe- by him for veral times diftilled off from vinegar ; and when the fj^p^^''""^ former, upon being newly added, produces no more red vapours, faturate the liquor with lime or terra I S T R Y. fipate fome phloglftic particles. 5^3 Let it then be diffol- Identity of looa Requifites foi brine:- tar, Mr Wef- ti umli's lanfuccefs- 1004 Dr Crell's opinic n of the experi' tnent ponderofa, feparating the ley, which will not fhoot, from the cryftals. The nature of the fait which does not contain nitrous acid, may be determined from the figure of its cryftals, or from the effefts of other falts in confequence of a double eleftive at- traflion. We might likewife add freOi nitrous acid to the feparated fait, or to the whole mixture, with- out any feparation of the nitrous fait, till the earthy fait, which does not contain any nitrous acid, be fatu- rated. The vinegar, if unaltered by the operation, would rife on diftilling the liquor ; and if converted into faccharine acid, would not be diflodged from lime by fpirit of nitre. In like manner, diftilled vinegar fhould be faturated with chalk, the compound redu- ced to cryftals, and then expofed to as ftrong a fire as it can bear without expelling the acid, in order to dif- Vou IV. PartIL ved, filtered, and ciyftallized again; after which it may be treated with nitrous acid as above direfted. ' " Perhaps (fays Dr Crell), the acetous acid may by — — ^ J this combination acquire more fixity ; fo that the ni- trous acid fhall be able to produce a greater change. Should it pafs over again in the form of acetous acid unchanged, let it be combined once more with calca- reous earth ; and let the foregoing experiment be re- peated, in order to try whether fome fenfible change will not enfue. Should this method fail, try the op- pofite ; that is, endeavour to add more grofs phlogi- ftic matter to the vinegar. Try to combine ftrong vinegar, and that which has been diftilled, with unftu- ous oils. Thus we might perhaps bring it nearer to tartar; and, again, by means of nitrous acid, convert it into acid of fugar. 1006 In another diflertation on this fubjeft, Dr Crell His at- undertakes to fliow, that all the vegetable acids may '^•^"^'""^^f® , , . ■ , 1 • . , pT(,\'e that be converted mto one, and that this is contamed in ^j^g the pureft fpirit of wine. The following are adduced getable a- as proofs. cids may 1. If the refiduum of dulcified fpirit of nitre be ['^^ Jj^^""** boiled with a large quantity of nitrous acid, care be- ,gQ^ ing taken at the fame time to condenfe the vapours by From the a proper apparatus ; and if the liquid which has paf- refiduuin of fed over be faturated with vegetable alkah, nitre and j!"/"^'^^"^^ terra foliata tartari will be obtained; and on feparating j,itre. the latter by means of fpirit of wine, the vinegar may be had in the ordinary way of decompofing the fait. 2. On boiling the refiduum over again with nitrous acid, the fame produfts are obtained ; and the more frequently this procefs is repeated, the lefs acid of fu- gar is procured, until at length no veftige of it is to be met with. ,oog 3. Pure acid of fugar, boiled with 12 or 14 times its From the quantity of nitrous acid, is entirely decompofed, and ^^^^ '^'^^^ " the receiver is found to contain phlogifticated nitrous ^^.l^^ '^f^j^^ acid, vinegar, fixed air, and;phlogifticated air, while gar. a little calcareous earth remains in the retort. 4. Acid of fugar is likewife decompofed by boiling with fix times its quantity of vitriolic acid. In the receiver we find vinegar, phlogifticated vitriolic acid, 1009 aerial acid ; while pure vitriolic acid remains in the ^'"'"^ ^ ''^^ retort. Sac-fof" 5. By faturating the refiduum of dulcified fpirit of tartar from nitre with chalk, there is formed an infoluble fait, the rcfi- ' which by treatment with vitriolic acid yields a real ''""'^ °| acid of tartar, conftituting a cream of tartar with ve- f ^j.^^ getable alkali. nitre. 6. On evaporating the liquor from which the tar- 1010 tareous felenite vras obtained, a dark- coloured matter remains, yielding on diftillation an empyreumatic acid of empy- * of tartar, and a fpongy coal. Hence it would feem, reumatic that fpirit of wine confifts of acid of tartar, of water, acid of tsr- and phlogifton ; fo that it is a native dulcified acid : ^^'^ and nitrous acid, on being mixed with it in moderate jnVhich^ quantity, diflodges the acid of tartar. On the addi- tartarous tion of more nitrous acid, the acid of tartar is refol- feleisite is ved into acid of fugar and phlogifton ; and by a ftill ^o'^^d. greater addition, the faccharine acid is changed into prom'the vinegar. _ _ _ folution of 7. On boiling one part of acid of fugar with one manganefe and an half of manganefe and a fufficient quantity of ^7 "'trous 3 J- aitrous^idoffu- gai-. 514 Acicl of Fat, loia From the fcvlution of the fame ■with vitri- olic acid and that of tartar. From the dig-eflion of acid of tar- tar with fpint of wine. 1014 From the folution I f inano^nere with vitri- olic acid and fi irit of wine. 1015 From the diftillation cf fpirit of wine w.th cauflic al- kali. ad 1 015 How pro- cured. 3d 1015 Its eff-as en alkalies &c. 4th I0T5 On nsetals C H E M I nitrous acid, the manganefe wilt be almoft entirely dif- folved, and phlogifticated nitrous acid along with vine- gar W'ill pafs over into the receiver. 8. On boiling together acid of tartar, manganefe, and nitrous acid, we obtain a folution of the manga- nefe, with phlogifticated nitrous acid and vinegar as be- fore 9. If acid of tartar be boiled along with vitriolic acid and manganefe, the latter will be difiolvcd, and vine- gar with vitriolic acid will pafs over into the re- ceiver. 10. On digefting acid of tartar and fpirit of wine for feveral months, the whole is converted into vine- gar ; the air in the vefiel being partly converted into cretaceous 2cid, and partly into phlogifticated air. 1 1. On boiling fpirit of wine with vitriolic acid and manganefe, it will be converted into vinegar and phlo- gifticated air. 12. By diftilling fpirit of wine upwards of 20 times from cauftic alkali. It was changed Into vinegar, and a confiderable quantity of water was obtained. Hence it appears, fays Dr Crell, that the acids of tartar, fugar, and vinegar, are modifications of the fame acid, as It contains more or lefs phloglfton. The acid of tartar has the greateft quantity, the acid of fugar fomewhat lefs, and vinegar the leaft of all. In thefe experiments, however, care muft be taken that neither the nitrous acid nor fixed alkali employed con- tain any marine acid, otherwife the refults will be un- certain. § iS. Of the Add of Fat. This may be obtained from fuet by means of many repeated diftillations. A fmall quantity is fepa- rated at each diftillation ; but by diftilling the empy- reumatlc oil into which the fuet is thus converted over and over, a frcfh quantity is always obtained. The acid of fat in fome relpefts has a refemblance to that of fea-falt ; but in others is much more like the vege- table kind, as being deftruftible in a ftrong fire, form- ing compounds which do not dellquefce with calcare- ous earth, and uniting intimately with oily fubftances. With alkalies it forms falts entirely different from thofe yielded by the other acids ; with the volatile alkali, particularly, it produces a concrete volatile fait. When iaturated with calcareous earth, it yields brown cry- ftals ; and a fait of the fame kind was obtained by Dr Crell from a mixture of quicklime and fuet diftilled to drynefs, and boiling up the refiduum with water. The cryftals were hexagonal, and terminated by a plane furface ; their tafte was acrid and faltllh ; they did not dellquefce in the air, and were eafily and copioufly diffolved in water. With magnefia and earth of alum a gummy mafs is obtained, vrhich refufes to cryftal- lize. With regard to the metals, Dr Crell informs us, that the acid of fat copioufly dilfolves manganefe into a clear and limpid liquor. It diffolves the precipitate of cobalt, but not the regulus. White arfenic is ail- ed upon but fparingly, and nickel not at all, though it forms a green folution with the precipitate from ni- trous acid. Regulus of antimony, by the affiftance ©f heat, is dllfolved Into a clear liquor, which be- came milky in the cold : it cryftalllzed on evaporation, S T R Y. Praaice. and did not dellquate in the air. Zinc readily dif- Pixed Alka- folved, and imparted a peculiar metalHc tafte, falling ^^^^^^ to the bottom in the form of a white powder on the Combma- addition of an alkali. BIfmuth in the metalHc ftate tions. was not dlifolved ; but the precipitate was. It adled - — v ' upon mercury after being twice diftilled from it, and poured afrefh upon the metal. The mercury could not be entirely precipitated by common fait. It atied more vigoroufly upon a precipitate from corrofive fub- limate ; from the folution of which a white fublimate was obtained after the liquor had been drav/n off by diftillation. A gold-coloured folution was obtained from platina by diftilling the acid from it to drynefs, and then pouring It back again ; the prccipiaite of this metal from aqua-regia by fpirit of wine was dif- folved In great abundance. Iron was very eafily dif- folved in it, and exhibited a liquor of an aftringent tafte, which ftiot into needle-like cryftals that did not dellquefce In the air. Lead was corroded, and ren- dered the acid turbid. Minium was converted into a white powder, and then diffolved with greater eafc. The folution has a fweet tafte, and cannot be precipi- tated by fea-falt. Tin was corroded Into a yellow calxj and difiblved but in very fmall quantity. Copper was diifolved, even in the cold, into a green liquor ; but the folution was greatly promoted by heat. On eva- poration it fiiowed fome difpofition to cryftallize, but again attrafted moifture from the air. S.lver-leaf was attacked only In a very fmall degree ; however, fome was precipitated by means of copper, and tlie mar'ne acid rendered the liquor turbid. The calx precipitated from aquafortis w^as diffolved inore copioufly. Silver was precipitated of a white colour from aquafortis by the pure acid itfelf, as well as by Its aramoniacal falt> Half an ounce of the acid diftilled four times almoft to drynefs from fome gold leaves, and at length pour- ed back upon them, the precipitate of a dilute folu- tion of tin obtained by it, gained only a faint colour, rather Inclining to red ; but a mixture of two parts of acid with one of aquafortis, diffolved gold very rea- dily. § iQ' Of Fixed Alkaline Salts. 1016 Of thefe there are two kinds; the vegetable and How pro- mineral. The former Is never found by itfelf, and but cured, rarely in combination with any acid ; but is always prepared from the afhes of burnt vegetables. It is got in the greateft quantity from crude tartar ; from which, if burned with proper care and attention, we may obtain one pound of alkali out of 2^ of the tar- tar. The latter is found native in fome parts of the earth. It is likewifc found in very large quantities combined with the marine acid, in the waters of the ocean, and in the bowels of the earth ; thus forming the common ahmentary fait. It is alfo produced from the afhes of certain fea-plants, and of the plant called kail ; from whence both the mineral and vegetable al- kalies have taken their name. The vegetable alkali difficultly affumes a cryftalline Vegetable form ; neverthelefs. It may be partially united with alkali cry- fome acids in fuch a manner as to cryflallize, and lofc ilallized. its property of deliquating in the air, without, at the fame time, ceafing to be an alkali. Of this we have an example in the acid of ants above mentioned. Some- thing Practice. C H E M T018 Change on the vege- table alkali 1019 Difference between vegetable and mine- ral alkalies 1020 Comi>"fed of a cauftic fa!t and fix- ed air. 1021 Kepar ful- i'hui is. thing of the fame kind we have obferved in treating vegetable fixed alkali with fpirit of wine. A gallon of pretty ftrong fpirit of wine being drawn over from a pound of fait of tartar, a black untluous liquor was left, which fliot into cryilals very much refembli ng vi- triolated tartar, and which did not deliquate in the air, but were neverthelefs ftrongly alkaline. Dr Black, however, informs us, that the vegetable alkali may be fhot into fine cryftals; but which cannot be preferved, on account of their great attraftion for moillure, un- lefs clofely fhut up from the air. They have not fuch a quantity of water as to undergo the aqueous fulion. The mineral alkali in its natural ftate always aflimies a cryftalline form, fomewhat rcfembling that of fal mirabile. It does not deliquate in the air, nor does it feem to have fo ftrong an attraftion for water, even when in its moft cauftic ttate, as the vegetable alkah : hence mineral alkali is preferable to it in making foap, which is always of a firmer confiftence with mineral than with vegetable alkali. If vegetable alkali is com- bined with fpirit of fait, fome change feems to be ' thereby induced upon it ; as the fait produced by ex- pelling the marine acid by means of the vitriohc, and then ciyftalKzing the mafs, cryftallizes differently from vitriolated tartar. Whether the vegetable alkali might by this means be entirely converted into the mineral, deferves a further inquiry. Both mineral and vegetable alkalies, when apphed to the tongue, have a very (harp, pungent, and uri- nous tafte ; but the vegetable confiderably ijrore fo than the mineral. They both unite with acids, and form different neutral falts with them: but the vegetable al- kali feems to have rather a greater attraction for acids than the other; alchoughthis difference is not fo great as that a neutral fait, formed by the union of mineral alkali with any acid, can be perfeftly decompofed by an addition of the vegetable alkali, unlefs in confider able excefs. Both vegetable and mineral alkali appear to be compofed of an exceedingly cauftic fait united with a certain quantity of fixed air This may be increafed To far, as to make the vegetable alkali affume a cryftalline form, and lofe great part cf its alkaHne properties : but as the adhefion of great part of this air is very flight, it eafily feparates by a gentle heat. Some part, however, is obflinately retained ; and the alkali cannot be de- prived of it by the moft violent calcination per fe. The only method of depriving 'it entirely of its fixed air is, by mixing an alkahne folution with quickhme. Fixed Alkalies -COMBINED, 1. IV'ith Sulphur. The produce o^ this is the red fetid compound called hpar fulphurh, or liver of ful- phur. It may be made by melting fulphur with a gentle heat, and ftirring into it, while melted, four times its weight of dry alkaline fait. The whole readily melts and forms a red mais of a veiy fetid fmcU, and which deliquates in the air. If fulphur is boiled in a folution of fixed alkaline fait, a like cora- ,'bination will take place. In this procefs, when the hepar is made either in the dry or the moift way, the fixed air of the alkali is difchargcd, according to Dr Prieftley's obfervation. Neither does a fixed alkali, when combined^ with fixed air, feem capable of uniting with fulphur ; nor will I S T R Y. 5^5 the union be accompliihed without heat, unlefs the al- P'xed Allta- kali is already in a cauftic ftate. Hence a cold folution ''"j f/''*"' of hepar fulphuris may be decompounded, partly at onn^i,;na- Icaft, by fixed air. On adding an acid, however, thetioas. dccompofition takes place much more rapidly; and the /— ^ fulphur is precipitated to the bottom, in form of a j^^^^^^^,^,, white powder. ' fed_ During the precipitation of the fulphur from an al- kali, by means of acids, a thick white fmoke arifes, of a moft fetid fmcll and fufFocating nature. It burns quietly, without explofion, on a candle's being held in it. Calces of filver, lead, iron, or bifmuth, ai-e ren- j^j, dered black by it. Hence, if any thing is wrote with Inflanima- a folution of lead, and a folutu^n of hepar fulphuris ishle vapnur pafTed over it when dry, the writing, formerly inviiible, will immediately appear of a blackilh brown colour, ^j^jj ^fj^^ Silver, in its metallic ftate, is prodigioufly blackened either by the contaft of this vapour, or by being im- merfed in a folution of the hepar fulphuris itfelf. Li- tharge is inftantly reftored to its metallic ftate, on being immerfed even in a cold folution of hepar ful- phuris. _ . . . , 10^4 By being united with an alkali, the acid of fulphur Phi iiT;fton feems very much dlfpofedto quit the phlogifton. If a '^"^P'^'"'" folution of hepar fulphuris is expofed to the air f"^!* '^iflt'^tj^^ fome time, it is fpontaneoufly decompofed ; the phlo- gj-id. gifton of the fulphur flying off, and the acid remaining • united with the alkali into a vitriolated tartar. This dccompofition takes j^lace fo remarkably, when liver of fulplmr is diffolved in water, that, by a fingle eva- poration to drynefs, it will be almofl totally changed into vitriolated tartar. If this fubftance, in a dry ftate, be expofed to a moderate degree of heat, and the mafs kept conftantly ftirring, a like decompofition will fol- low ; the phlogifton of the fulphur will fly off, and the acid unite with the alkali. _ jqj^ Liver of fulphur is a great folvent of metallic mat- Metals and ters ; all of which, except zinc, it attacks, particular- cli^.''c<'aJ iy in fufion. It feems to diffolve gold more effeftu- ally tlian other metals This compound alfo diffolves ^ * ' vegetable coals, even by the humid way ; and thefe folutions, if fuffered to ftand in the open air, always precipitate a black powder, no other than the coal they had diffolved, in proportion to the quantity of hepar fulphuris decompofed. When vegetable coal is thus diffolved by liver of fulphur in fufion, it is of a much deeper red than in its natural ftate. Thcfolu- tion in water is of a green colour. II. With Exprejj'ed Oils. The refult of this combi- nation is foap ; for the preparation of which in large quantities in the way of trade, fee Soap. The foap which is ufed in medicine is prepared without heat, in the following manner, according to the author of the Chemical Ditlionary. *' One part of quicklime, and two parts of good Spanifh foda (the fait prepared from the afhes of the herb kali), are boiled together during a fhort time in an iron caldron. This lixivium is to be filtered, and evaporated by heat, till a phial, capable of containing an ounce of water, fhall contain an ounce and 216 grains of this lixivium. One part of this lixivium is to be mixed with two parts of oil of olives, or of fweet almonds, in a glafs or ftone-ware veffel. The mixture foon becomes thick and white ; and muft be ftirred from time to time with an iron fpatula. The combi- 3 T 2 nation T026 Soap. 5-6 Fixed Alka line Salts and their Corabina- ti( ns. CHEMISTRY. Toa; Starke) ' foap. 30a8 ?h!ogiftica- ted alkalies • nation is gradually completed, and in feven or eight days a very white and firm foap is obtained." In attempting combinations of this kind, it is abfo- lutely neceffary that the alkali be deprived of its fixed air as much as poffible ; otherwife the foap will be quite unftiious and foft: for fixed alkalies have a great- er attraftion for fixed air than for oil, and hence foap is decompounded by blowing fixed air into a folution of it in water. Tt may be made either with tallow, wax, fpermaceti, butter of cocoa, the coarfer refinous fubflances, or animal oils. III. fHth E/jhtt'ial Oils. The volatility of thefe oils m a great meafure hinders them from being afted upon by alkalies : neverthelefs, combinations of this kind have been attempted ; and the compounds fo produced have been called Starkey^s foap, from one Starkey a chemift, who endeavoured to volatilize fait of tartar by combining it with oil of turpentine. His method was to put dry fait of tartar into a matrafs, and pour upon it effential oil of turpentine to the height of two or three fingers breadth. In five or fix months, a part of the alkali and oil were combined into a white fa- ponaceous compound. This muft be feparated from the mixture, and more of it will afterwards be formed by the fame method. Chemifts, imagining this foap to be pofiefled of con- fiderable medical virtues, have endeavoured by various methods to fhorten this tedious procefs. Of thefe one of the mott expeditious is that recommended by Mr Beaume; which confifts in triturating, for a long time, alkaline fait upon a porphyry, and adding oil of tur- pentine during the trituration. According to him, the thick refinovis part of the oil only can cambine with the fait ; and, during the time this combination is ef- fefted, the more fubtile and attenuated parts will fly off. Hence he finds that the operation is confide- rably abridged by the addition of a little turpentine or common foap. The moil expeditious of all, how- ever, is that mentioned by Dr Lewis ; which confifts in heating the alkali red hot, and then throwing it into oil of turpentine, ftirring them well together ; on which they immediately unite into a faponaceous mafs. This kind of foap is fubje6l to great alterations from keeping ; particularly the lofs of its colour, and a kind of decompofition occafioned by the extra&ion of an acid from the oil of turpentine, which unites with the alkali, and cryftallizes not only all over the furface, but in the very fubftance of the foap. The nature of this fait is unknown, but certainly deferves confidera- tion. IV. With Phlogijton^ This combination is effefted; by calcining them with the charcoal either of vege- table or animal matters. The confequence is, that, they are greatly altered in their properties; fometimes fo much as to be enabled to precipitate calcareous earths from their folutions in acids. Metallic folution s pre- cipitated by them in this llat«,afrume different colours. Differences obferved between Fixed Alkalies, obtain-r ed from different Vegetables. Thefe differences we muft conceive to arife from iome proportion of the oily and phlogiitic matter of the vegetable remaining in the alhes from whence the falls are extracted; for when reduced to tlieir utmoft. Pradlice. purity, by repeated calcinations in a ftrong fire, and Fixed Alka, deliquations in the air, all of them, the marine alkali excepted, appear to be the very fame. liomll^na- On this fubjeft Mr Gmelin has given a great num- tions. ber of experiments in the fifth volume of the Com- ^— J* mentaria Petropol'itana ; and found very confiderable «029 differences, not only between the alkaline falts, but ^\ likewife the pure vegetable earths obtained from dif- rime^ts"^* ferent vegetables by burning. The falts of the feveral plants examined were prepared with great care, and all of them exaftly in the fame manner; each vegetable be- ing burnt in a feparate crucible, with the fame degree of fire, till no remains of coaly matter could any longer be perceived ; and the afhes elixated in glafs veffels with cold diftilled water. The falts, thus obtained, were found to pi-oduce different colours on mixture with certain liquors, and to effervefce in very diffe- rent degrees with acids : certain metalhc folutions were by fome precipitated, by others only rendered thicker, by others both precipitated and rendered thick ; whilft fome occafioned neither the one nor the other of thefe changes, but left the fluid clear and tranfparent. Thus, with the vitriolic acid, the falts of fouthernwood and fage ftruck a pale brown colour ; thofe of pine-tops and rue, a yellow ; that of fern, a reddifh yellow; and that of fanicle, a dark leek-green : that of dill yielded a leek-green precipitate, with ele- gant green flakes floating in the liquor. This laft fait alfo gave a greenifh precipitate with the marine acid, and a red one with the nitrous. Solution of corrofive fublimate was changed yellow by fait of fouthernwood ; of a brownifli colour, by that of colt's- foot ; of a deep red, by that of wormwood ; and of a pitch-colour, by that of dill. That of fern threw down an opal-colour; of fage,^ a fulphur-yellow ; of elder flowers, a cit^-o)i yellow ; of fanicle, a faffron colour ; and of milfoil, a deep-red precipitate. From folution of lilver, fait of carduus benedidus threw down a white ; of camomile, a grey ; of hyfop, a brownifh ; of dill, a blackifh brown ; of fcabious, a yellowifli ; and that of pine-tree tops, a fulphur yellow precipitate. Solution, of vitriol of copper was changed by fait of fouthern- wood to a bright fea-green; by that of dill, to an un- fightly green; of agrimony, to a greenifh blue; and by that of milfoil, to a bright Iky-blue : the fait of pen- ny-royal made the liquor thick as well as blue, arid, that of feverfew made it thick and green : the fait of hyffop threw down a green precipitate, that of fcurvy- grafs a blue one, and that of fumitory a greenlfli blue whilft the fait of fern made fcarcely any change either in the colour or confiftency of the liquor. ^19. Of Volatile Alkali. This is a kind of fait obtained from all animal, fome vegetable, fubftances, from foot by diftillar obtained, tion with a ftrong heat, and from all vegetable fub- ftances by putrefaftion. Though a volatile alkali is procurable from all putrid animal fubftances by di- ftillation, yet the putrefaftive procefs does , not feem to prepare volatile alkali in all of thefe. Putrid urine, . indeed, contains a great quantity of alkali ready form-r^ ed, whence its ufe in fcouring, l^c. but the cafe is. not fo with putrid blood or flelh. Thefe afford no al- kali till after the phlegm has arifen 3.. and this they. would; Pradlce. C H E M Volatile would do, tliougli they had not been putrefied. Ac- ^liLil; n4id cording to Mr Vv iegleb, volatile alkali is found in C,)ml)i- lapis fuillus, chalk, marble, coals, turf, jane in water, nor in any of the acids, except the vitriolic, d ffolved in when by long boiling it had become very conceHtrated and almoft red hot. It then appeared perfectly dif- vi"rioh? folved ; but feparated again unchanged on the addi- acid, tion of water. On expofing the vitriolic folution to the atmofphere for fome days, beautiful radiated cry- ftals were formed in it. On adding a folution of m.ild vegetable alkali to this Precipi- vitriolic folution, a precipitate appeared ; but it con- '-''^'^^ filled of marmor metallicum unchanged. An ounce of it in fine powder was then fufed with two of fait of .retable fix- tartar until it ran thin, whfen fix drachms of a refidu- ed alkali, um infoluble in water were left. On the addition of '°^3 nitrous acid, only 52 grains were left, which appeared to be marmor metallicum unchanged. On faturatinginThe'd'ry the alkahne folution with diftilled vinegar, and waftiing way by fait the precipitate, the liquor was found to contain ter- tartar, ra fohata tartar, formed by the union of the acetous acid with part of the alkali ; and of vitriolated tar- tar, formed by that of the alkali with the native acid of the marmor metallicum. ^^g^ The fait formed by the nitrous acid fliot readily in- Nitrous fo- to beautiful permanent cryftals of a rough bitteriih tafte. ^ution Some of the fait deflagrated with nitre and charcoal, J|'°"'^|. left by^^afiiing the terra ponderofa very white, capa- ftals.^""^" ble of being burnt into lime, and again forming art in- foluble compound with vitriolic acid. An hundred grains of aerated terra ponderofii, diflblved in marine acid, and precipitated by the vitriolic, were augment- ed 1 7 grains in weight. Hence it appears, jq^^ I. That the marmor metallicum is compofed of vi- Analyfis trioUc acid and terra ponderofa. 2. That this com- "'^ P''oP^''- pound has very little folubility in water. 3. That it ' '^'^ '^'^'^ can only be dilioived in highly concentrated od of vi- metalli- triol, from which it feparates unchanged on the addi- cum. tion of water. 4. That it cannot be decompofed in the moiil way, by mild fixed alkali, though it may be fo in the dry. 5. That it may be decompofed by the union of inflammable matter to its acid, by which ful- phur is formed, though the aoid cannot be diffipated by mere heat. 6. An hundred parts of this fubftance contain 32.8 of pure vitriohc acid, and 67.2 of terra ponderofa. The marmor metallicum, our author re- marks, may poffibly be ufeful in fome cafes where a pov\^erful flux is wanted ; for having mixed fome of it with the black flux, and given the mixture a ftrong heat in a crucible, it ran entirely through the pores of the veflel. Dr Withering defcribes two other jkinds of thiscauk a fubftance, known by the name of mid, and found in fubftance o£ the mines of Derbyfliire, and otlter places. Thefe '^"s '^'"''x diff"er from the other only in containing a fmallpropor- i/'. tion of iron. On the whole, he concludes, that " the ' ^^"^ teira ponderofa feems to lay claim to a middle place betwixt the earths and metallic calces. Like the for- 3 U m«r 522 Tranfmu- tat'on of Flints into an E:irth fol. ble in Acids. C H E M I mer it cannot be reduced to a metjilUc fi)rm> though like the latter it miiy be precipitated by phlogiftica- ted alkali. In many of its properties it much refcm- bles the calx of lead, and in others the common cal- careous earth. Its moft remarkable properties are its ' decompofing the vitriolic neutral falls, and forming, with the nitrous and marine acids, cryltals which do not deli que fee. § 2. Tranf mutation of Flints Into an Earth foluhle in Acids. T069 Solution of 1070 Solubility This is effected by mixing powdered flints A^ith alkahne fait, and melting the mixture by a firong fire. The melted m.afs deliquates in the air, hke alkaline falt^ ; and if the flint is then precipitated, it becomes, foluble in acids, which it entirely refilled before. In- this procefs the alkali, by its union with the flint, is deprived of its fixed air, and becomes cauftici To this caufticity its folvent power is owing ; and there- fore the flint m.ay be precipitated /rom the alkah, not only by acids, but by any fubftance capable of furnifh- iiig fixed air.; fuch as rnagncfia alba or volatile alkah. The precipitate in both cafes proves the fame ; but the nature of it hath not hitherto been determined. Some have conjettured that the vitriolic acid exifted in- the flint ; in which cafe, the alkah made ufe of in this procefs ought to be partly converted into vitriolated tartar. The above procefs is delivered' on the authority of of this earth former chemift.s ; but Mr Bergman, who has publifhed denied by a dilTertation on this fubjeft, aflerts that it cannot be Mr Berg- dJffolved except by the fluor acid. The vitriohc, ni- trous, or marine acids, have no effe£l upon it, even when newly precipitated from, the liquor of flints waflied and fl;ill wet, and though a thoufand parts of acid be added to one of the earth, and boiled upon it for an hour: but when three parts of alkaline fait are di?m"ftakc^^'t^^ in a crucible with one of quartz, the fait dif- Df'former folyes at the fame time about feven hundredth parts of chemifts. its'own weight of the clay which compofes the crucible ; and the folubihty of this has given occafion to the mif- take above mentioned. If the fufion be performed in an iron veffel, no foluble part will be obtained, except- ing the very fmall portion of clay which the quartz contains ; and when this is once exhauflcd by an acid, Ro more can be procured by any number of funans with alkali. 107a ^ The fluor acid, he obferves, is never obtained en- Gryftalf ^-^^i ^^.^^ ^^^^ filiceous earth, and confequently its daily form- power as a menfliruum mult be weakened m propor- ed by Mr tion to the quantity it contains. In order to obferve Bergmcn. -^^ folvent pov/er, however, our author, in the year 1772, put fome quartz, very finely powdered, into a bottle containing \ of- a kanne of fluor acid. "The bottle v/as then {lightly corked, and fet by in the cor- ner of a room. Two years afterwards it was exa- mined ; and on pouring out the liquor there were found concreted at the bottom of the veflel, befides innume- rable fmall pvifmatic fpiculce, 1.3 cryftals of the fize of fmall peas, but nfoitly of an irregular form. Some of thefe refembled cubes, whofe angles were all truncated, fuch as are often found in the cavities of flints. Thefe were perfeft filiceous cryftals, and very hard, but not comparable, with quartz, though they agreed with it S T R Y. Praaice. in cfTential properties. " Poffibly (fays he) the length Tranfmu- of a century may be neccffary for them to acquire, by j"^^^^ exficcation, a fulhcient degree of hardnefs. . The £arth bottom itfelf, as far as the Hqv,or had i-eaclied, was foluble m found covered v/ith a very thin filiceous pellicle, which ^^-^ was fcarcely vifible, but feparated on breaking the bottle. It was extremely pellucid, flexible, and fliow- ^^^^ ed prifmatic colours. Thefe phenomena fliow, that why the much filiceous matter is diffolved and fufpended" (in fluor acid the fluor acid). "Whether any of the quartz was^i|.'not. taken up m this experiment is uncertain ; but it ap- ji^pjc^iy^ pears probable that little or none was diflblved ; finee, by the help of heat during the diilillaiion, the acid had previoufiy taken up fo much filiceous earth, that upon flow evaporation, it was unable to retain it. Hence appears the origin of the cryflials and the pel- hcle ; and hence appears the caufe which impedes the aftion of fluor acid upon flint ; namely, that the acid obtained in the ordinary way is already faturated with it. . . . • '■°74. The volatile alkah precipitates filiceous earth mofc Siliceous completely from fluor acid : and thus wc find, that one^^''^''^"'''-'^ part of it is contained in 600 of the acid, diluted to^,|.^^V^|^'''^'J^^ fuch a degree, that its fpecific gravity is only 1.064. by volatile/ This precipitate has all the properties of pure flint ; alkali but that precipitated either by vegetable, or mineral ^J.^ 75^^^ fixed alkah does not afford a pure filiceous earth, but £^j,'j"^^'[^^*^ a peculiar kind of triple fait, formed of the earth, precipita- fliior acid, and fixed alkali, which diflblves, though cum with _ with difiiculty, in warm water, efpecially the earth ^''^'^ procured by vegetable alkali, but is eafily decompofed by lime-water, and lets fall the mineral fluor regene- rated. _ 1076 Fixed alkaline falts attack this earth by boiling, but Siliceous not unlefs it be reduced to very fine powder, and "^^"^Y'^ed'b^' ly precipitated from the hquor. Oil of tartar per de-j^'^^j^^g liquium takes up about one-fixth of its weight, and thefoiution o£ hquor becomes gelatinous on cooling, though at firft all-.ali. diluted with 1 6 times its weight of w^ater. This fo- lutiou is efl'efted only by the cauftic part ; for when fully faturated with fixed air, it cannot enter into any union with it. Volatile alkali, even though cauftic,. has no effeft. ^^^^ The attraftlun betwixt filiceous earth and fixed al- Has a re- kali is ^ much m.ore remarkable in the dry way ; for markable thus it melts with one half its weight of alkali into an hard, firm, and tranfparent glafs, the aerial acid and ^""^ ®* water going ofl' in a violent effervefcence. In pro- portion. as the alkali is increafed, the glafs becomes more foft and lax, until at lafl; it diflblves totally in j^^g water, as has been already mentioned. The filiceous is vei y rare matter thus precipitated is of, a very rare and fpongy an 1 fponjry texture, and fo m.uch fwelled by water, that its bulk when wet is at leail twelve times greater than when dry nor does it contra £1 more though fufFered to re- main a long time in the water.. Hence it is eafy to reduce the hquor of flints to . a jelly, by diluting it with four or eight times it weight of w~ater, and ad- ding a fufiicient quantity of precipitate; but if an over- proportion, of water be ufed, for infliance, 24 times. the weight, the hquor will then remain limpid, though why it can we add as much acid as is fufiicient for faturating the not fume- alkali. The reafon of this Mr Bergman fuppofes to '""f^^s | be, that the filiceous particles are removed to fuch aP^"^''"^^^^ diftance from pne another, that tiiey cannot overcome acid with- the out heat. Iry way. C H E M I phofphoric the fridion they muft necefTanly meet with in their " ' pafiage downv.-ards through the fluid ; but if the li- quor be boiled, which at once diminifhes its quantity and tenacity, the filiceous matter is inllantly fepara- ted. Liquor of flints is alfo decompofed by too great a Hints ui;- quantity of water ; for by this the efficacy of the men- b rT^'i'^Teatftru""^ is weakened, and it is alfo partly faturated by a quanfky ' the aerial acid contained in the water. A precipitate of water, alfo falls when the fluor acid is made ufe of ; the rea- andbyfluor f^^^ ^^Jeh is the fame as the precipitation by other acids : in this cafe, however, the alkali makes part of the precipitate, as has hhen already obferved ; and there- fore the matter which falls is fuflble before the blow- pipe, and foluble in a fufRcient quantity of water. § $• Of Phosphoric Earth. BoWnL These are fo called from their property of fhining ftone. ' in the dark. The m.oft celebrated and anciently known of this kind is that called the Bolognlan Jione, from Bologna, a city in Italy, .near which it is found. The difcovery, according to Lemery, was accidentally made by a flioe-makcr called Fincenzo Cafcinrolo, who ufed to make chemical experiments. This man, having been induced to think, from the great weight and luftre ofthefe Hones, that they contained filver, gathered fome, and calcined them ; when carrying them into a dark place, probably by accident, he obferved them ftiining like hot coals. Mr Margraalf defcribes the Bolog-nian fl:one to be an heavy, fofc, friable, and cryftallizcd fubdance, in- capable of efl"ervefcence with acids before calcination in contaa with burning fuel. Thefe properties feem to indicate this Hone to be of a felenitic or gypfeous nature. When thefe ftones are to be rendered phofphoric, fuch of them ought to be chofen as are the cleaneft, befl; cryftaliized, molt friable and heavy ; which ex- foliate when broken, and which contam no heteroge- neous parts. They are to be made red hot in a cru- cible ; and reduced to a very fine powder in a glafs- mortar, or upon a porphyry. Being thus reduced co powder, they are to be formed into a pafte with mu- cilage of gum tragacanth, and divided into thin cakes. Thefe are to be dried with a heat, which at laft is to be made pretty confiderable. An ordinary reverbe- rating furnace is to be filled to three quarters of its height with charcoal, and the fire is to be kindled. Upon this charcoal the flat furfaces of the cakes are to rtfl, and more' charcoal to be placed above them, fo as to fill the furnace. The furnace is_ then to be covered with its dome, the tube of which is tL remain open ; all the coal is to be confumed, and the furnace is to be left to cool ; the cakes are then to be cleanfed from- the aflies by blowing with bellows upon them. When they have been expqfed during fome minutes to light, and afterwards carried to a dark place, they willleeni to fnine like hot coals; particularly if the ^erfon obferving thsm has been fome time in the dark, or have fhnt his eyes, that the pupils may be fufficient- ly expanded. After this calcination through the coals, if the fi:ones be expol'ed to a fl:ronger calcination, du- ring a full half hour, under a rauflle, their phofphoric ^ality wiH be rendered ftronger. How ren- tJcred lu- minous. S T R Y. 523 From attending to the qualities of this ftone, and the requifites for making this phofphorus, we are na- . ^' . turally led to think, that the Bolognlan phofphorus is ^^g^ no other than a compofition of fulphur and quickllnne. Analyfis of The ftone itfelf, in its natural ftate, evidently contains the phof- vitriolic acid, from ics not effervefcing with acids ofphorus. any kind. This acid cannot be expelled from earthy fubllances by almofl. any degree of fire, unlcfs inflam- mable matter is admitted to it. lu this cafe, part of the acid becomes fulphureous, and flies off; while part is converted into fulphur, and combines with the earth. In the above mentioned procefs, the inflammable mat- ter is furnilhed by the coals in contaA with which the cakes are calcined, and by the mucilage of gum tra- gacanth with which the cakes are made up. A true fulphur mufl. therefore be formed by the union of this inflammable matter with' the vitriolic acid contained in the ftone; and part of this fulphur muft remain united to the earth left in a calcareous fl;ate, by the diffipation, or convcrfion into fulphur, of its acid. . In the year 1730, a memoir was pubhflied by Mr All cakare- du Fay ; wherein he affcrts, that all calcareous ftones, ^^^"^1^^ whether they contain vitriohc acid or not, are capa- according ' ble of becoming luminous by calcination; with this to Mr du difference only, that the pure calcareous ftones require Fay^ a ftronger, or more frequently repeated, calcination to convert them into phofphorus ; whereas thofe which contain an acid, as felenites, gypfum, fpars, iifc. be- come phofphoric by a flighter calcination. On the contrary, Mr Margraaff alferts, that no other ftones can be rendered phofphoi ic but thofe which are fatu- rated with an acid ; that purely calcareous ftones, fuch as marble, chalk, llmeftone, ftalaftites, i^c. cannot be rendered luminous, till faturated with an acid previ- oufly to their calcination. We have already taken notice, that the compounds formed by uniting calcareous earths with the nitrous and marine acids become a kind of phofphori ; the former of which emits hght in the dark, after ha- ving been expofed to the fun through the day; and io?j the latter becomes luminous by being itruck. Signior Slgnior Beccaria found, that this phofphoric quality was ca- pable of being given to almoft all fubllances in na- ' ture, meials perhaps excepted. He found that it was widely diffufed among animals, and that even his own hand and arm polfeffed it in a very confiderable 1086 degree. In the year 3775, a treatife on this kind "^^"".^^j"*^ phofphori was publiftied by B. Wilfon, F. R. S. and j.inieau!'*' member of the Royal Academy at Upfal. In this trea- tife he fliows, that oyfter-fhells, by calcination, ac- quire the phofphoric quality in a very great degree, either when combined with the nitrous acid or with- out it. The firft experiment made by our author was the pouring fome aquafortis, previoufly impregnated with copper, on a quantity of calcined oyfter-fhells, fo as to form them into a kind of pafte; he put this pafle into a crucible, which was kept in a pretty hot fire for about 40 minutes. Having taken out the mafs, and waited till it waij cool, he prefented it to the external light. On bringing it back fuddenly into the dark, he was furprifed with the appearance of a variety of co- lours like thofe of the rainbow, but much more vivid. In confequence of this appearance of the prifmatic 3 U 2 colours, 5^4- Vegetable Earth. 1087 Surprifinp phofphoric quality of jLiyfter- fliello. C H E M colours, he repeated the experiment in various ways, conabining the calcined oyfter-fhells with different me- tals and metallic (olutions, with the different acids, al- kaline and neutral falts, as well as with fulphur, char- coal, and other inflammable fubftances ; and by all of thefe he produced phcfphori, which emitted varioufly coloured light. What is more remarkable, he found that oyfler- fhells pofTefTed the phofphoric quality in a furpriling de- gree ; and for this purpofe nothing more was requifite than putting them into a good fea-coal fire, and keep- ing them there for forae time. On fcaling ofi'the in- ternal yellowiih furface of each (liell, they become ex- cellent phofphori, and exhibit the mofl vivid and beau- tiful colours. As we know that neither the vitriolic nor any other acid is contained in oyfler-fhells, we can- not as yet fay any thing fatisfaftory concerning the na- ture of this phofphorus. ^4. Of the Vf.GETABLE Earth. I S T R Y. Praaice or 19,290, to one. For its fufion it requires a lowde Gold. 1088 Dr Lewis's This is produced from vegetables by burning, and, -opinion. when perfeftly pure, by hxiviating the afhes witli wa- ter, to extract the fait ; and then repeatedly calcining them, to burn out all the inflammable matter ; and is perhaps the fame from whatever Tubftance it is ob- tained : in this flate, according to Dr Lewis, it is of the fame nature with magnefia. In the flate, how- ever, in which this earth is procurable by limply burn- ing the plant, and lixiviating' the allies, it is confide- 1089 J"ably different, according to the different plants from Mr Gmc- which it is obtained. The afhes of mugwort, fmall lin's expe- centaury, chervil, and dill, are of a brownifh grey ; nments. goat's beard and lungwort afford white allies ; thofe of fanicle are whitifh ; thofe of Roman wormwood of a greenifh grey ; thofe of rue, agrimony, faxifrage, brown ; thofe of tanfey, of a duflcy green ; thofe of dodder, of a fine green ; eyebright, fouthern-wood, common wormwood, and fcabious, afford them grey ; fcurvy-grafs, of a whitifh grey ; hyffop, yarrow, and fowbane, of a duflcy grey ; melilot, and oak-leaves, as alfo plantain, colts-foot, pine- tops, and fumitory, of a dufl and the compound pafTed every one of the operations already defcribed, without fhow- ing the leaR alteration from the tin. Several other trials were made with different mix- tures of copper, tin, and filver, with gold, even as low as two ounces and a half of copper, with half an ounce of tin, to twelve ounces of gold ; all of which bore hammering and flatting by rollers to the thinnefs 1095 of ftiff paps'"} 3nd aftervvaids working into watch- Malleahili- cafes, cane- heads, &c. with great eafe. They grew ty of gold more hard and harftr indeed in proportion to the quaa- by regu^lus '''^ alloy ; but not one of them had the appear- ofarfenic. ance of what workmen call brittle gold. Mr Alchorne therefore is of opinion, that when brittlenefs has been occafioned by the addition of tin to gold, the former has been adulterated with arfenic ; as he has found, that by adding 12 grains of regulus of arfenic to as many ounces of fine gold, the compound has; been ren- dered altogether unmalleable. When gold is ftruck during a certain time by a hammer, or when violently comprefled, as by the wire- drawers, it becomes more hard, elaftic, and lefs duc- tile ; fo that it is apt to be cracked and torn. Its duc- tility is, however, reftored by the fame means ufed with other metals, namely, heating it red hot, and let- ting it cool ilowI)^ This is called annsalin^ metals ; 1096 S'^^^ feems to be more affefted by this operation Surpiifiiip than any other metal. The tenacity of the parts of tenacity of gold is alfo very furprifing ; for a wire of of 2" Its f arts. jfj dJatneter will fupport a weight of 500 pounds. Gold is unalterable by air or water. It never con- trails ruR like other metals. The aftion of the fier- ceft furnace-fires occafions no alteration in it. Kunc- kel kept gold in a glafs-houfe furnace for a month, and Boyle kept fome expofed to a great heat for a ftiil longer time, without the lofs of a fingle grain. S T 11 Y. It is faid, however, to be diflipable in the focus of a large burning minor. Mr Boyle 1 elates a very curious and extraordinary ^^^^^^ j^,^ experiment, which he thought was fufhcient to prove gj-perl- the total deftruftibility.of gold. About an eighth partments for of a grain of powder, communicated by a ftranger, deftruc- was projevna cr nea redu- ced. Ml- Mar- praaff'b me This, next to gold, is the mofl petft.a:, fixed, and duftile of all the metals. Its ipecific gravity is to that of water nearly as 11 to r. A fingle grain has been drawn into a wire three yards long, and flat- ted into a plate an inch broad. In common fire it fuf- fers no diminution of its weight ; and, kept in the vehe- ment heat of a glafs-houfe for a month, it lofes no more than one fixty-fourih. In the focis of a large burning-glafs, it fmokes for a long while, then con- tracts a greyifh alh on the furface, and at length is to- tally diffipated. Silver is foraewhat harder and more fonorous than gold, and is fufible with a lefs degree of heat. The tenacity of its parts alfo is nearly one half lefs than that of gold ; a filver wire of tV of an incfi diameter being unable to bear more than 270 pounds. Mercuty unites very readily with filver-leaf, or with the calx of filver precipitated by copper ; but does not touch the calces precipitated by alkaline falts. The vapours of fulphiireous fohitions Hain fil- ver yellow or black. Sulphur, melted with filver, debafes its colour to a leaden hue, renders it more eafily fufible than before, and makes it flo At fo thin as to be apt in a little time to penetrate the crucible : in a heat juft bslow fufion, a part of the filv-r fhocts up, all over the furface, into capillary rfHorefcence. Aquafortis does not a<^l upon filver in this com- pound ; but fixed alkaline falls will abfoib the ful- phur, and form a hepar fulphuris, which, however, is capable of again diffulving the metal. If the ful- phurated filver is mixed with mercury fublimate, and expofed to the fire, the mercury of the fublimate will tjnite with the fulphur, and carry it up in ilie form of cirmabar, whilft the marine acid of the fublimate u- nites with the filver into a luna cornea, which re- mains at the bottom of the glafs. Fire ah.ne is fuf- ficient, if continued for fome time, to expel the fulphur from filver. From the bafer metals, filver is purified by cupel- lation with lead. (See Refining ) It always re- tains, however, after that operation, fome fmall por- tion of copper, fiifficient to give a blue colour to vo- latile fpirits, which has been erroneoufly thought to proceed from the filver itftlf. It is purified from this admixture by melting it twice or thrice with nitre ?.nd borax. The fcoria, on the firft fufion, is com.- monly blue ; on the fecond, green ; and on tlie third, white, which is a mark of the purification being com- pleted The moft effcdlual means, however, of purify- ing filver, Is by reviving it from luna cornea ; be- caufe fpirit of fait will not precipitate copper as it does filver. The filver may be recovered from lu- na ccrnca, by fufion with alkaline and inflair m-;ble fluxes ; but, in thefc operations, fome lofs is alwavs occafioned by the difilpation of part of the volatile calx, before the alkali or metal can abforb its acid. Mr Margraaff has difcovered a method of recovering -the filver with little or no lofs; mercury affifttd by volatile falts, imbibing it by trituration without heat. One part of luna cornea, and two of volatile fait, are to be ground together in a glafs- mortar, with fo much Vol. IV. Part II. 1136 water as will rcdr.cc them to the ccnfificnce of a thin palle, for a quarter of a hour, or more; five parts of pure quickfilver are then to be added, with a litth more water, an3 the triture to be continued for fome hours. A fine amalgam will thus be obtained; which 13 to be wafhed with frefli parcels of water, as long as any white powder feparates. Nearly the whole of the filver is contained in the amalgam, and may be obtain- ed pcrfcdliy pure by difliliing off the mercury. The white pov/der holds a f :iall proportion fcparable by • gentle fiblimation ; the matter which fubliraes is near- ly Itmilar to mcrcurius dulcis. The colour of filver is debafed by all the metal?, and its malleability greatly injured by all but gold and copper. The Englifh ftandard filver contains one part of copper to twelve and one-third of pure filver. This metal difcovers in fome circumftances a great at- Atrra i.n tradtion for lead ; though it does not retain any of ttiat^'-'" •^■^'J- metal in cupellation. If a mixture of filver and cop- per be mclttd with lead in certain proportions, and the compound afterwards expofad to a moderate fire, the lead and filver will melt out together, bringing ve- ry little of the copper with them ; by this means fil- ver is often feparated from copper in large works. The effeil does not wholly depend upon the different fuljbility of the metals ; for if tin, which is ftill more fufible than lead, be created in the fame manner with a mixture of filver and copper, the three ingredients are found to attrad one another fo flrongly as to come; all into fufion together. Again, if filver be melted with iron, and lead added to the mixture, the filver will for- fake the iron to unite wich the lead, and the iron will float by itfelf on the furface. ^j,^ Silver is purified and whitened externally by boiling V.^iitenrd in a folntion of tartar and common fait. This is no^'^*""'-'''? • other than an extradion of the cupreous pat tides from the furface of the filver, by the acid of the tartar acu- ated by the common fait. ^^,g M. Berthollet has lately difcovered a method of rulrrina- Imparting to the calx of filver a fulminating property, ^^''g filver, and that much more terrible than fulminating gold it- fdf. His receipt for making it is, « Take cupelled j^^'J^'' filver, and difiblve it in the nitrous acid ; precipitate par ^i.^*^** ' the filver from the folution by lime-vvater, decant the clear liquor, and expofe the precipitate three days to the open air. Mix this dried precipitate with the cauftic volatile alkali, it will turn black ; and when dried in the air, after decanting the clear liquor, is the fulminating powder required." The properties of this powder are faid to he fo ex- traordinary^, that it is impoffible to imagine how any part of it can ever be feparated from the reft after it is once prepared. To make this fulminate, it Teems /i4o no fenfible degree of heat is necefTary, the contaft of J'"'"''"^''^* a cold body anfwering that purpofe as wdl as any other. t(J,ch of a- After It is once made, therefore, it mufl not be touch- ny fub- ed, but remain in the veflJel in which it is dried ; and^*'-<^s " he- fo violent is the explofion, that it is dangerous to at- '^^'''^ tempt it in larger quantities than a grain at a time. °' For the fame reafon it undoubtedly follows, that no 1141 more than a grain ought to be made at a time, or at^^ngeTous leaft in one vefTd, becaufe no part of it could ever af-^^'^" """^^ ter^vards be feparated from the reit. We are told,Irra"n isful- that, " the wind having turned over a paper-contain- ""nated ac ing fome atoms of this powder," ,(we ought to have^'*'^^* .3 been 5P C H E M I S T R Y. Silve" 1141 Fulraina- tine cry- it. been Informed how the atoms came there, confidering what we have juft now related,) " the portion touch- ed by the hand ndminated, and of coiirfe that which fell upon the ground. A drop of water which fell upon this powder caufed It to fulminate. A fmgle grain of ful- minating filver, which was in a glafs cup, reduced the glafs to powder, and pierced feveral doubles of paper. " If the volatile alkali, which has been employed with the above powder, be put into a thin glafs ma- trafs and boiled,. then, on (landing in the cold, fmall cryftals will be found fublimed on the interior Mes of the vefTel, and covering the liquor. On touching one of thefe cryftals the matrafs will be burft with confi- derable explofion. 1143^ "The dangerous properties of this powder fuggefl be ufcTi'n " the neceffity of not preparing it but when the face is covered witli a malk with glafs eyes ; and to avoid the rupture of the glafs cups, it is prudent to dry the ful- minating filver in fmall metalline vefTcls." To this we may add, that as the powder does not fulminate when wet, it may In that ftate be put up in very fmall quantities on paper, to be fulminated afterwards as occafion offers. This will perhaps account for the ap- pearance of the few atoms above mentioned on the paper which the wind overturned. With regard to the caufe of this extraordinary ful- mlnatioa we can fay nothing fatlsfaftory ; the follow- ing curious reafon is aflfigned by the antlphloglftons ; which at once fliows the futUIty of their theory, and fcts in a very ridiculous light the hard words with which they would obfcure the fclence of chemlftry. " The oxygenous principle* (fay they) unites wath the hydrogenous priiiclple f of the volatile alkali, and form water in a vaporous ftate. Tills water (in a va- porous ftate) being inftantaneoufly thrown into a Jlate <-c;a/^)^^r, poft'effing elaftlcity and expanfive force, is the principal caufe of this phenomenon, in which the \ Ph'.oglfti- a%otic % air which is difengaged from the volatile al- cated air, kali, with its whole expanfile power, has a great ftiare." On this, as well as other theories, in which elaftic onThi'''and A'^^^^ alleged to be the caufe of explofions, it Is o!ber' theo- obvious to remark, that ftiould we allow this to be the Ties. cafe, we are utterly at a lofs to find a fource of heat fufficient to rarefy the vapour to fuch a degree as is neceflary for producing the effeA afcribed to it. _ In the prefent cafe, we can fcarcc fuppofe a grain weight of metalline calx, already dry, to contain as much ei- ' ther of fire or water as Is neceflary to produce the ef- feft ; nor can we explain why the touch of any cold body, and which may be fuppofed to contain lefs fire than the calx Itfelf, fhould produce fuch an effeft. As to the oxygenous and hydrogenous principles, they were there before the touch, and ought to have produced their effetts, not to mention that the water produced 1146 by them could not have amounted to the thoufandth The pheno- part of a grain. It Is much more probable, therefore, menon pro- that the whole Is to be confidered as an ettedt ot elec- liably ow- tricity, though we cannot tell how the fluid comes irog to elec-, ' ^ e^-dted In fuch a violent manner, tricity., ii*-i>- ^ ^ 3. Copper, This Is one of thofe metals which, from their de- ftruftlbility by fire, and contraaing ruft In the air, are called hnpcrJeB. Of thefe, howev&r. It Is the moft perfea and indeftruaible. It Is of a reddifli colour when pure j eafily tarnirnes in a moift air, and con- 1144 Abfurd theory of the anti- 1 hlogif- tons. • Dephlo- gifticated air f Inflam- mable air. ^ ^ _ II48 clftern of cold ^uuled'^' In the m:ddle of Pradllce. trafts a green vufc. It Is the moil fonorous of all the Copper, metals, and the hardcic and moft elaftic of all but Iron. ' ^r—^ In fome of Its ftates, copper is as difiicuUly extended f under the hammer as iron, but always proves foftcr to t^r^' ti^j,,^" the file ; ?nd is never found hard enough to ftiike a ,ron. fpark with flint or other ftones ; whence Its ufe for chlfl"els, hammers, hoops, Idc. in the gunpovvdcr works. When broke by oiFten bending backwards and forwards, It appears internally of a dull red colour without any brightntfs, and of a fine granulated texture refenv- bling fome kinds of earthenware. It is confidcral-ly duftile, though lefs fo than either gold or filver ; and may be drawn into wire as fine as ha'r, or beaten into leaves almoft as thin as thofe of filver. The tenacity of its parts is very confiderable ; for a copper wn t of -j'p of an inch diameter v/ill fupport a weight of 299I: pounds witiiout breaking. Tiie fpecific gravity ot tiiis metal, according to Dr Lewis, Is to that of water as 8.830 to I. Copper continues malleable when heated red ; in which refpecl It agrees with ii-on ; but Is not, like iron,, capable of being welded, or having two pieces joined into one. It requires for Its fufion a flronger heat than either gold or filver, though lefs than that requi- fite to melt iron. Wlien in fufion, it is remarkably Impatient of moifture ; the contaft of a little water cecafioning the melted copper to be thrown about with violence, to the great danger of the by-ftanders. It Is, neverthelefs, faid to be granulated in the brafs- works at Briftol, without explofion or danger, by let- ting It fall in little drops, Into a large water covered with a brafs-plate. the j)late is an aperture, in which Is fecured with Stur- bridge clay a fmall veflel, whofe capacity Is not above a fpoonful, perforated with a number of minute holes, through which the melted copper paffes. A ftream of cold water pafles through the clftern. If fuff'ered to grow hot, the copper falls liquid to the bottom, and runs Into plates. Copper, in fufion, appears of a bluifli green colour, nearly like that of melted gold. Kept in fufion for a ' ' long time. It becomes gradually more and more brittle ; but does not fcorify confiJerably, nor lofe much of its weight. It Is much lefs deftruftlble than any of the imperfeft metals, being very difficukly fubdued even by lead or bifmuth. If kept in a heat below fufion, it contrafts on the furface thin powdery fcales ; \vliich, being rubbed off", are fucceeded by others, till the whole quantity of the metal Is thus changed Into a fcoria or calx, of a dark reddi fir colour. This calx ' does not melt In the ftrongeft furnace -fires ; but, in the focus of a large burning mirror, runs eafily into a deep red, and almoft opaque, glafs. A flaming fire, and ftrong draught of air over the furface of the metal, greatly promote its calcination. Tbe flarne being tinged of a green, bluifli, or rainbow colour, Is a mark that the copper burns. ^^^^ This metal is very readily foluble by^ almoft all fa- 3 jiubihtf. line fubftances ; even common water, fuftered to ftand long In copper-veflels, extracts fo much as to gain a coppery tarte. It Is obfervable, that water is much more impregnated with this tafte, on being fufi^ered to ftand In the cold, than if boiled for a longer time in the vefl"el. The fame thing happens in regard to the mild vegetable acids. The confeftioners prepare the moft acid fyrups, even thofe of • lemons and oranges, by Al-ered by combira- tion with vegetable acids. Amalga- mation with mer cwy. 1153. , Tir Lewis's method. Praaice. " G H E M Copper, by boiling in clean coppcr-vefTels, without the prepa- rations receiving any ill taile from the metal ; whereas, either the juices thcmfelves, or the fyrups made from them, if kept cold in copper velTels, foon become im- pregnated with a difagreeable tafte, and with the per- nicious qualities of the copper. By combination v/ith vegetable acids, copper be- comes in fome refpeils remarkably altered. Verdi- gris, which is a combination of copper with a kind of acetous or tartareous acid, is partially foluble in diitilled vinegar ; the rtiiduum, on being melted with borax and liufeet' oil, yields a brittle metallic fub- ftance, of a whitifh colour, not unlike bell-metal. The copper alfo, when revived from the diftilled verdigris, was found by Dr Lewis to be different from the metal before dilTohition ; but neither of thefe changes have yet been fufficiently examined. Copper, in its metallic ftate, is very difficultly amal- gamated with mercury ; but unites with it more eafily if divided by certain admixtures. If mercury and verdigris be triturated together with common fait, vinegar, and water, the copper in the vendigris will be imbibed by the mercury, and form with it, as Boyle obfei-ves, a curious amalgam, at liril fo foft as to re- ceive any impreffion, and which, on Handing, becomes hard like brittle metals. Brafs leaf hkewife gives out its copper to mercury, the other ingredient of the brafs Separating in the form of powder. Eafier methods of amalgamating copper are pubHlli- ed by Dr l^ewis in his notes on Wilfon's Chemiftry, p. 432. His receipts are, — " DifTolve fome fine cop- per in aquafortis : when the menftruum will take up no more of the metal, pour it into an iron mortar, and add fix times the weight of the copper, of mer- cury, and a little common fait : grind the whole well together with an iron peftle ; and, in a little time, the copper will be imbibed by the mercury, and an amalgam formed, which may be rendered bright by wafliing it well with repeated affufions of water. " yinother method. Take the muddy fubftance which is procured in the polifhing of copper plates with a pu- mice Hone, and grind it well with a fuitable portion of mercury, a little common fait, and fome vinegar, in an iron mortar, (a marble one will do, if you make ufe of an iron peRle), till you perceive the mercury has taken up the copper." The copper recovered from thefe amalgams retains its original colour, with- out any tendency to yellow. Even v/hen brafs is luade ufe of for making the amalgam, the recovered metal is pcrfeft red copper ; the ingredient from which the brafs received its yellownefs being, as a- bove obferved, feparated in the amalgamation. Copper is the bafis of feveral metals for mechanic ufes ; as brafs, prince's metal, bell-metal, bath-metal, white copper, cifi:. Brafs is prepared from copper and calamine, with the addition of powdered char- coal, cemented together, and at lafl: brought into fu- fion. The calamine is to be previoufiy prepared by cleanfing it from adhering earth, ftone, or other mat- ters ; by roafting, or calcining it ; and by grinding it ■ into a fine powder. The length of time, and degree of 'heat, requifite for the calcination of the calamine, ■are different according to the qualities of that mineral. The calamine, thus calcined, cleanfed, and ground, is to be mixed vs'ith about a third or fourth. part of char- i'54 Biaft, how pr pared. I S T R Y. coal dufl:, or powdered pit-coal, as i$ don^ in fom3 parts of England. The malleability of the balls is di- minifiied by the ufe of pit-coal, which is therefor;; only employed for the preparation of the coarfer kinds. To this compofition of calamine and coal, fome manufaftiirers add common fait, by which the procefs of making brafs is faid to be haftened. In Collar, where the cadmia adhering to the infides of the furnaces is ufed inilead of the native calamine, a fmall quantity of alum is added, by which they pre- tend the. colour of the brafs is heightened. With this compofition, and with thin plates or grains of copper, the crucibles are to be nearly filled. The pr-oportion of the calamine to the copper varies according to the richnefs of the former, but is generally as thi-ee to two. The copper mull be difperfed throughthecompofitionof calamine and coal ; and the whole mufl be covered with more coal, till the crucibles are full. The crucibles, thus filled, are to be placed in a furnace funk in the gi'oimd, the form of which is that of the frulhun of hi hollow cone. At the bottom of the furnace, or great- er bails of the fruftum, "is a circular grate, or iron- plate. This plate is covered with a coat of clay and hoi-fe-dung, to defend it from the action of the fire ; and pierced with holes, through which the air main- taining the fire pafles. The crucibles Hand upon the clrcidar plate, forming a circular row, with one in the middle. The fuel is placed betwixt the crucibles, and is thrown into the furnace at the upper part of it, or the leffer bafis of the fruftum. To this upper part or mouth of the furnace is fitted a cover made of bricks or clay, kept together with bars of iron, and pierced v/ith holes. This cover ferves as a regiller. When the heat is to be increafed, the cover mull hz partly or entirely taken off, and a free draught is permitted to the external aii-, which pafles along a vault under-ground to the aflr-hole, through the holes in the cii-cular grate or plate, betwixt the crucibles, and through the upper mouth, along with the fmoke and flame, into an area where the workmen Hand, which is covered with a large dome or chimney, through which the fmoke and air afcend. When the heat is to be diminifhed, the mouth of the furnace is clofeJ with the lid ; through the holes of which the air, fmoke, and flame pafs. The crucibles are to be kept red-hot during eight or ten hours ; and in fome places much longer, even feveral days, according to the natui-e of the calamine. During this time, the zinc rifes m vapour fi-om the calamine, unites with the copper, and renders that metal confiderably more fufible than it is by itfclf. To render the metal very fluid, that it may flow into one uniform mafs at the bottom, the fire is to be increafed a little before the crucibles are taken out, for poiu-ing off" the fluid me- tal into molds. From 60 pounds of good calamine, and 40 of copper, 60 pounds of brafs may be obtain- ed, notwithilanding a confiderable quantity of the zinc is diflipated in the operation. The quantity of br-afs obtained has been confidei-ably augmented fiflce the introduftion of the method now commonly praflifed, of granulating the copper ; by which means a larger furface of this metal is expofed to the vapour of zinc, and confequently lefs of that vapour cfcapes. To make the finer and more malleable kinds of brafs, be- fides the choice of pure calamine and pui-e copper, 3-^2 fome 532 Cqpcr. CHEMISTRY. Pradlce. fbrae manuiaSturers cement the brafs ti fecond time ■ with calamine and charcoal ; and lometimes add to it eld brafs, by which the new is faid to be meliorated. Brafs is brittle when hot j but fo duililc when cold, that it may be drawn into very fine wire, and beat into very thin leaves. Its beautiful colour, malleabi- lity, and its fufibility, by which it may be eafily call into moulds, together with its being lefs liable to ruil than copper, render it fit for the fabrication of many utenfils. Although zinc be fixed to a certain degree in brafs, by the adhefion which it contrails with the copper ; yet when brafs is m.elted, and expofed to a violent fire,, dating a certain time, the zinc diffipates in vapours, and even flames away, if the heat be llrong enough ; and if the fire is long enough continued, all the zinc will be evaporatf4 and deilroyed, fo that what remains Id IT 54 is copper. ^nncesme- Prince's metal is made by melting zinc in fubftance ai- with copper ; and all tlie yellow compound metals prepared in imitation of gold are no other than mix- tures of copper with different proportions of that fe- mimetalj taken either in its pure iiate, or in it:i na- tural ore calamine, with an addition fometimes of iron-filings, ^c. Ziric itfelf unites molt eafily with the copper; but calatnine makes the moll dudlile com- pound, and gives the moft yellow colour. I}r Lewis oh- fcrves, that a little of the calamine renders tlie cop- per pale ; that when it has imbibed about -r\- its own weight, the colour inclines to yellow ; tliat the yel- i6wnefs inereafes more and more, till the proportion comes to alinoi! one half; that on further augmenting the calamine, the compound becomes paler and paler, and at lalt white. The crucibles, in which the fufion is performed in large works, are commonly tinged by iji;^ the matter of a deep blue colour. Bell- metal. Bell-metal is a mixture of copper and tia-; and tho' both thefe metals fi.igly are m.aileable, the compound proves extremely brittle. Copper is diflolved by melted tin eafily and intimately, far more fo than by lead. A fmair portion of tin renders this metal dull- coloured, hard, and brittle-. Bell-metal is compofed of about ten parts of copper to one of tin, with the ad^ dition commonly of a little brafs or zinc. A fmall pro- px)rtion of- copper, on the other hand, inxj^roves the colour and confiilency of tin, without, much injuring its du.Q;ility. Pewter is fometimes made from one p-art of copper and tv/enty or more of tin. It has long been obfervcd, that though tin Is fpeci- fically much lighter than copper, yet the gravity of the compound, hell-metal, is greater than that of the *v!ty ">f ^h£ copper itfelf. The fame augmentation of gravity, al- nse:al. fo takes place where the lighter metal is in the greatefl' proportion ; a mix.ture even of one part of tin with two of copper, turning out fpecifically heavier than pure copper. Moft metallic mixtures anfwer to the mean gravity of the ingredients, or fuoh as wouKl rci- fult from a bare appofitioii of partSi Of thofe tried by IDr Lewis, fom.e exceeded the mean, but the greater number fell fhort of it ; tin and copper were the only ones that formed a compound heavier than the heavieil J 157 of the m.etals feparately. A^'nlic cop- White copper is prepared by mixing togethei equal r"- parts of arfenic and nitre, injefting the mixture into a red-hot crucible, which is to ,be kept in a moderate oliJervati- Oiis '"D tht; (pecific gra fire, till they fubfide, and flow like wax. One part •''■■n, of this mixture is injefted upon lour parts of melted " ' '' copper, and the metal, as foon as they appear tho- roughly united together, immediately poured out. The copper, thus whitened, is commonly melted with a confiderable proportion of filver, by which its colour is both im.proved and rendered more permanent. The white copper of China and Japan appears to be no other than a mixture of copper and arfenic. Geoffroy relates, that, on repeated fulions, it exhaled arfenical fumes, and beceim.e red copper, lofing, with its white- nefs,, one feventh of its v\-eight. , ^4. Iron. Iron is a metal of a greyifli colour ; foon tarnifirng in the air into a dulky blackifh hue ; and in a ihort time contracting a yellowiih, or reddilh rail. It is the hardell of all metals; the moftelailic; a;id, except- ing platina,. the moft difficult to be fufed. Next to o£ gold, iron has the greateft tenacity of parts; an iron in parts! ' wire,, the diameter of which is the tenth part of an inch, being capable of fuftaining 450 pounds. Next to tin, it is the lightell of all the metals, lofing between a feventh and eighth part of its weight when Immerfed in water. When very pure, it may be drawn into wire as fine as horfe-hair; biU: is much lefs capable of being beaten into thin leaves than, tlie other metals, except- • iug only lead. Iron grows red-hot much fooner than any other ^ metal; and this,, not only from the apnlication of ac- tual fire, but likewife from ftrong hammering, fric- tion, or other m.echanic violence. It uevertheltl's melts the mtoH difficultly of all metals except manganefe and - platina ; requiring, in its mall fuiible ftate, an in- tenfc, bright, white heat. Wh^w perfedly malleable, it is not fuiible at all by Use heat of furnaces, without tliC addition or the immediate ccntaCl of burning fuel; and, when melted, lofes its malleability : ' all the com- mon operations which communicate one of thefe qua- lities deprive it at the fame tinte of the other ; as if fufibility a!id malleai)ility were in tliis metal incompa- tible. When expolt'd to tlic focus of a large burning mirror, however, it quickly fulied, boiled, and emit- ted an ardent fiune, tiie lower part of which was a ' true flame. At length it was changed into a blackilli, vitrified fcoria. IT59 From, the- great wade occafioned by expofing iron iron a conii to. a red but efpecially to a vvliitc heat, this metal ap-h ''i:We pears to be a combulHble fubilance. This combullion ^'^'-^^•^"cei is maintained, like that of all i other combulliblc fub- ilauces, by conta- poured into it a little lixivium fanguinis ; and next day fi rbed front found, that it threw down from green vitriol a preci-'^'^'^ atnio- pitate entirely foluble in acids. With, other acids he '^P^'^'^' obtain •«* no precipitate. On inverting the expei-iment, and mixing fome ^'74 green vitriol with lixivium fanguinis, the mixture grew HxcdT^'th'' yellow ; and he found this addition capable of fixing a-ldition 0/ the colouring matter fo, that neither the acid of fixed ^"'"e green air nor any other could expel it from the alkali. For ^j^'"',''.*'? having poured the mixture above mentioned Into a fo-^j^*] lution of green vitriol, and afterwards fuperfaturatcd the Cah'oV'iron terwards obtained foluble in lixivit.m fanguinis; 1176 But not Praaice. CHE M I , lion. the lixivium with acid, he obtained a confiderable quan- ~v--— ' tity of blue. To the fame lixivium fanguinis, in which c. fmall quantity of green vitriol was diffolved, he after- wards added of the other acids fomewhat more than was neceffary for its faturation ; and though this was done, a confiderable quantity of Piuliian blue was af- Again, having precipitated a fo- lution of green vitriol with alkali, and boiled the pre- cipitate for fome minutes in lixivium fanguinis, part of it was dilTolved : the filtered lixivium, uaderv.'ent no change when expofed to the open air or to the aerial acid, and precipitated the folution of vitriol of a blue; and tlioiigh the lixivium was fuperfaturated with acid, and fome green vitriol added, a very beautiful PrufTian blue was obtained. This, however, will not hold when ivhenhigl--a perfectly dephlogi (Heated calx of iron is employed, ly dephb- vvhich none can be diffolved by the lixivium fangui- giiiicue ^ ^ ^^^^ ^ .jj ^^^^ Pruflian blue be obtained by precl- j)itating with Hxivlum fanguinis a perfedlly dephiogi- jj,., Itirated folution of iron in nitrous acid. The colour- To determine what had become of the colouring iiii^ matter matter in thofe experiments where it feemed to have taken up j^^en diffipated, fome lixivium fanguinis was poured in- ^'/^'-tllL to a veffel filled with aerial acid. It was kept well airer it nap _ i • 1 j • r lieen expel- corked during the night, and next day a piece or pa- led by a- per dipped in a folution of green vitriol was fixed to ck'.s. {^[jg cork, pencilling it over with two drops of a folu- tion of alkali in water. The paper was thus foon co- vered with precipitated iron ; and on being taken out two hours afterwards, and dipped in muriatic acid, be- came covered with moll beautiful Pruffian blue. The fame thing happened when lixivium fanguinis fuperfa- turated with vitriolic acid was employed ; for in this cafe alfo the air was filled with the colounng matter, capable of being in like manner abforbed by the calx of iron. But though from thefe experiments it is plain tliat acids expel this colouring fubftance from the lixivium, a given quantity of air is only capable of receiving a certain quantity of it ; for the fame mix- ture removed into another veff'el imparts the coloui-ing property to the air it contains according to its quan- tity. On putting perfedlly dephloglilicated calx of Iron upon the papers, no Pruffian blue was formed ; 1 1 78 but the muriatic acid diffolved the calx entirely. Theoilour- Qm- author having now affured himfelf that acids my niattcr j-g^Uy ^ttradl the alkali more than the colouring- mat- expcllea by , , ~. ^ r i-n-ii • tt dit'tillation ter, proceeded to try the eriects 01 diltillation. r±a- with vitrio vlng therefore fuperfaturated forpe lixivium fanguinis lit acid. with viti-Iolic acid, he dittilled the mixture In a glafs retort with a gentle fire. When about one-third had paffed over, he changed the receiver, and continued the operation till one-half was difl.llled. The firft pro- duct had a peculiar tafte and fmell ; the air in the re- ceiver was filled with colouring matter, and the aque- ous ffuid was alfo ftrongly impregnated with it, as ap- })eared by its forming a fine Pruflian blue with phlogi- llicated calx of iron. Pai t of It being expofed to the open air for fome hours, entirely loft its power, and the product of the fecond operation was no other than wa-. J J ter nuxed with a little vitriolic acid. Attem'^its 'i'he next ffep was to procure, if pofiible, the co- to procure louring matter by itfelf ; and this he attempted to the tolnir-^^t fj.;,^ fvQi-n the Pruflian blue, rather than the lixi- inir matt ir 1180 fcy itfclf. vium fanguinis, as he v.'oidd thus not only avoid the troubkfome calcination of . the alkjilj and bljod. but S T R y. obtain the colouring matter In much larger quantity than could be done from the lixivium. On examining ff veral kinds of this pigment, he found in them evi- dent marks of fulpiiur, volatile alkali, vitriolic acid, and volatile fulphureous acid ; all of which fubftances are to be fonnd in the lixivium fanguinis, as well as in that of foot, and adhere to the precipitate in the preparation of Pruffian blue. I'lnding, however, that he could not obtain his purpofe by any kind of analyfis of thefe by fire alone, he had recourfe to a neutral fait ufed by chemifts for difcovering iron in mineral waters. This Neutral is formed by digefting cauffic fixed alkali on Pruflian fah for diC- blue, u'hich effedlually extradls the colour from it ewen':°'^'^'}"S . in the cold, in a very fhort time, and being neutralized, ^^^.^j ^g^ ' may eafily be reduced into a dry form. But it is notters, . entirely to be depended upon for this purpofe ; for it always contains fome iron, which Indeed is the medium of its connexion with the alkali. The lixivium fan- guinis is preferable, though even this contains fome iron, as well as the lixivium of foot ; our atithor's ex- periments, however, were made with the neutral fait, for the reafons already mentioned. 1181 I . An ounce of the fait was diffolved in a glafs re- EffeCls of tort in four ounces of water, afterwards adding three drachms of concentrated vitriolic acid ; and the mix- ^yjj.]^ (,£. ture was dlftlUed with a gentle fire. The mafs grew vitriol, thick as foon as It began to boil; from a great quan- tity of Pruffian blue, a quantity of the colouring mat- ter appeared by the fmell to penetrate the lute ; and part of it was abforbed by the air in the receiver, as in former experiments. The diltillation was continued till about an ounce had paffed into the receiver. The blue mafs remaining In the retort was put into a ftrain- er, and a piece of green vitriol put into the liquid which paffed through ; but by this laft no Pruflian blue was produced. The blue which remained in the filter was again treated with lixivium tartari ; the fo- lution freed from its ochre by filtration, and the clear liquor committed a fecond time to diftillation Vv'ith vi- triolic acid. Pruflian blue was again feparat^ed, though in . hnaller quantity than before, and the colounng matter came over into the receiver. After one third of the matter had paffed over, that which had been obtained by the firft diitillatlon was added to it, the Pruflian blue was feparated from the hxivium in the retort, . and extracted a third time. Some Pruflian blue was formed again, though In much fmaller quantity; whence it is apparent that Pruffian blue may at laft be totally decompofed by means of alkali. Lime, or terra pon- derofa, hkewife extradt the blue colour, and ffiow the fame phenomena as alkali. ji^i With volatile alkali a compound, confifting of the Colouring, alkah, iron, and colouring matter, is formed, which fliows the fame phenomena with that formed with fixed alkali. ' By diftillation per Je after it has been kali. ' diffolved in water, , the liquor grows thick in confe- quence of a feparation of Pruffian blue, and . volatile alkali paffes over into the receiver. This volatile fpi- rit is impregnated with the colouring matter ; it is not precipitated by lime-water ; but green vitriol is precipitated by It ; and on adding an acid, Pruflian bhie is formed. If a piece of paper, dipped in a fo- lution of green vitriol, be expofed to the vapour of this alkah, it is foon decompofed ; and if the fame be pencilled over with muriatic acid, it inftuntly becomes 2- blue,. 53^ ii83 How to free the lute. 1185 n< r alka. line. CHE M Line. On cxpofing tlie liqaor to the open -air, it all evaporates, leaving pure water behind. As in all the operations with vitriolic acid hitherto related, fome fmall quar.tity of it paiies into the re- colouring ceivcr, our author ihovvs how to deprive the colouring matter fer- matter of that vitriolic taint. For this purpofe no- f^^'^^IXj^j^.'" thing more is neceffary than to put a little chalk into taint. matter, and rediftil it with a very gentle heat ; the 1184 acid unites with the chalk,, and the coloviring matter How to goes over in its greateft purity. In oider to hinder, prevent the gg much as pofTible, the efcape of the volatile colour- the colour- '"S matter through the lute, he makes ufe of a fmail ing matter receiver, putting into it a little diftilltd water, and thro* the placing it fo that the greater part (liall be immerfed in cold water during the operation. The water im- pregnated with this colouring matter has a peculiar but not difagreeable fmell, a tafte fomewhat approach- ing to fweet, and warm in the mouth, at the fame time exciting cough. When rectified as above diredl:- Thismat-ered, it appears to be neither acid nor alkaline; for it "'^'J^^^''"'^ neither reddens paper dyed with lactriUS, nor does it re- llore the colour of fuch paper after it has been niade red ; but it renders turbid the folutions of ioap and hepar fulphuris. The fame liquor mixed with fixed alkali, though it contains a fuperabundance of colour- ing m.atter, rcftores thr blue colour of paper reddened by an acid. By diilillation to drynefs, there goes over a part of the colouring matter which difengages itfelf fiom the alkali; the rtfidnum is fohible in water, and has all the properties of the bsil lixivium fa'iu,ui- nis; but, like the true lixivium, it is dccompofed by all the acids, even by that of fixrd air. With cauftic volatile alkali it forms a kind of ammoniacal fait ; kind of am- however, always fmells volatile, though the co- (Ulr"w!th' loi^'iing matter be in ever fo great proportion. By vdlafile al- diflillation the whole inflantly rifes, and nothing but kali. pure water is left in the retort. I1187 Magnelia precipitated from Epfom fait by cauftic volatile alkali, was diflblved in the colouring matter by allowing them to Hand together for feveral days in a warm clofe bottle. On expofure to the open air, the magnefia feparated from it by its fuperior atttaclion for aerial acid, and formed on the furface of the water a pellicle like that of cream of tartar. This folution was likewife dtcompofed by alkalies and lime- n88 water. ^ ?Very little The colouring matter diffolves but a very fmall terra pon- quantity of terra ponderofa, which may be after- wards precipitated by vitriolic and even by aerial acid. Pure clay, or the balis of alum, is not attacked by it. Lime is diffolved in a certain quantity. The fu- perabundant portion (hoiild be feparated by hkration ; and as the liquor contains, befidcs the combined llmt-, the portion which water itfelf is able to take up, in order to free it from this, precifelv the fame quantity of water impregnated with aerial acid is to be added as is requifite for precipitating an equal quantity of lime-water. The coloining m.atter, thus f^-.turated with lime, is to be filtered again, and then to be pre- ferved in a well clofed bottle to prevent the accefs of fixed air. This folution is decompofed by all the acids, and by the pure or cauftic alkalies. By diflilla- ,tion the colouring matter rifes, and nothing but pure lime is left in the retort. — This folution of lime ap- 7.4- A I S T R Y. Pradice. 1.86 Form' a Diffolves niajmefia derofa. T189 Diffolves lime, birt not clay. pe?.rs to our author to be fo perfedtly faturnted, th^t he employed it in preference to any other in the exoer - ments he made on metals, a^ld which we are now about , to rclvJte. !■ on. 1 190 The f<.luri- ... t r lln^e I'rom the tiials made by Mr Scheele, it appears tlic moib that the colouring matter has no effeft upon any me- pi^'Tcr for tal or metallic folution, excepting thofe of filver and quickfilver in nitrous acid, and that of iron in fixed air. The firft is precipitated in a white powder; the ngt fecond in a black one; and the third affumes a fea- S Iver, green colour, which afterwai-ds turns to blue. With 'luitkfilver, metallic calces it produces the following phenomena, precipit-ted 1. Gold precipitated by aerated alkali becomes white, by ihe co- 2. The fixed air is difengaged from a precipitate oflonnng filver with a (lio-ht efFcrvefcence. 3. Calx of mercury '^^'^'^'** is diffolved, and yields cryftals by gentle evaporation, (js/ffj^fts 4. The calx of copper precipitated by aerated alkali on metal- tffervefces, and affumes a faint citron colour. 5. Calx of I c calces; iron precipitated from its folution in the vitriolic acid by the fame alkali, cffervefccs, and affumes a dark blue colour. 6. Pi-ecipitated cobalt fhows fome figns of effervefcence, and changes into a yellowifh brown co- lour. The other calces are not adled upon. The precipitating liquor above mentioned, poured ^^^m into metallic folutions, produces the following appear- jj^. ^^J^. " anres by means of double cledtive attraftion. i. Goldtioas. is pi-ecipitated of a white colour, but by adding a fu- perabundant quantity of the precipitating liquor the calx is rediffolved. The fecond folution is colourlefs as water. 2. Silver is precipitated in form of a white firbftance of the coniiitence of cheefe ; by adding more of the liquor the precipitate is rediffolvcd, and the fo- lution is not decompofed either by fal-ammoniac or marine acid. 3. Corroiive fublimate appai-entlv un- dergoes no change, though it is in reality decom- potinded ; the calx being diffolved in the colouring matter. Meixury diffolved in the nitrous acid without heat, is precipitated in form of a black powder. 4. The folutions of tin and bifmuth are precipitated, but the calx is not afted upon by the colouring matter. 5. The fame eftecls are produced on the folution of butter of antimony, as well as on that of well de- ph.Iogiflicated calx of iron. 6. Blue vitr-iol is preci- pitated of a yellow citron colour : if more of the pre- cipitating liquor be added, the precipitate is redif- folvcd into a colour-lefs liquor ; and a colourk-fs folu- tion of the fame calx is likewife obtained by volatile alkali. On adding mor-e of the folution of blue vi- triol, the folution likewife difappcars, and the liquor alftunes a green colour. Acids diffolve a portion of this precipitate, and the remainder is white. The muriatic acid diffolves the precipitate completely, but lets it fail again on the addition of water. 7. The fo- lution of white vitriol yields a white precipitate, which is not rediffoh'ed by addition of the precipitating li- quor, but is foluble in acids. Thefe folutions fmell like the colouring matter, which may be feparated from them by ddtillation. 8. Gi'een vitriol is preci- pitated, fij-lLof a yellowifn brown colour, which foon changes to green, and then becomes blue on the fur- face. Some hours afterwards the precipitate fublldes to the bottom of the veffels, and then the whole mix- ture turns blue ; but on adding any acid the pi'eci- pitate becomes inflantly blue. \f a very fmall qi:anti- ty of green vitriol be put into the precipitating liquor-, the 1 194 Inveftiga- tion of the conftituent jiart of the col' uring matter. "95 louring matter. Praaice. G H E M I Iron, the precipitate Is entirely dlflblved, and the whole af- * * fumes a yellow colour. 7. vSolution of cobalt lets fall a browniih yellow precipitate, which is not dif- folved by adding more of the precipitating liquor, neither is it foluble in acids. By diftillation the co- louring matter goes over into the receiver. JLallly, our author undertook an inveftigation of the conftituent parts of the colouring matter itfelf ; and in this he fucceeded in fuch a manner as muft do ho- nour to his memory, at the fame time that it promifes to be a real and lafting improvement to fcience, by ftiow- ing a method of preparing this valuable pigment with- out that naufeous and horrid ingredient, blood, which Inflamma- now ufed in great quantities for that purpofe. — His bility of the ^^.^ j^j^^^. concerning this matter feems to have been taken from an obfervation of the air in his receiver accidentally taking fire from the neighbourhood of a candle. It burned without any explofion, and he was able to inflame it feveral times fucceffively. Wifti- ing to know whether any fixed air was contained in the colouring matter, he filled a retort half full of the liquor containing ithe colouring matter, and ap- plying a receiver immediately after, gave the retort a briflc heat. As foon as the receiver was filled with thick vapours of the colouring matter, he disjoined it, and, inflaming the vapour by a little burning fulphur introduced into the cavity, found that the air which remained threw down a precipitate from lime-water. Hence (fays he) it maybe concluded, that the aerial acid (a) and phlogifton exift in this colouring matter." It has been aflerted by feveral chemifts, that Pruf- fian blue by diftillation always yields volatile alkali. — To determine this, Mr Scheele prepared fome exceed- ingly pure from the precipitating liquor above men- volatilcTal- t'on^^ 'I'l^ green vitriol; diftilung it afterwards in a iali by di- glafs retort, to which he adapted a receiver contain- ing a little diitilled water. The operation was con- tinued till the retort became red-hot. In the re- ceiver was found the colouring matter and volatile alkali, but no oil ; the air in the receiver was im- pregnated with aerial acid, and the fame colouring matter ; the refiduum was very black, and obeyed the magnet. On /ubftituting, itiftead of the PrulTian blue, the precipitates of other metallic fubftances preci- pitated by the Prufiian alkali, the refults were : I. The yellowifli brown precipitate of cobalt yield- ed the very fame produdls with Pruflian blue it- felf ; the refiduum in the retort was black. 2. The yellow precipitate of copper took fire, and emitted, from time to time, fparks during the diftillation. It produced little colouring matter, but a greater quan- tity of aerial acid and volatile alkali than had been ob- tained by the former precipitates. A fublimate arofe in the neck of the retort, but in too fmall a quantity to make any experiment ; the refiduum was reduced copper. 3. The precipitate of zinc yielded the fame with Prufliaii blue. 4. That of filver yielded like- wife volatile alkali and fixed air , but chiefly colour- ing matter ; a fublimate containing fome filver arofe into the neck of the retort ; the refiduum was reduced Vol. IV. Part II. IT96 Aerial a- cid and j)hlogifti>n i'uppofed to exift in it. I (97 pruflian tlue vields ■ftiiiation. 1198 Appearan ices o'^ {!i- {Ulling o- ther preci' pitates tkrowii dow n by Pnjflian alkali. S T R y. filver. 5. Calx of mercury cryftallized by means of the colouring matter, yielded fome of that matter, but fcarce any mark of volatile alka'i. Some mercury, with a portion of the original compound, arofe in the neck of the retort. ^ From thefe experiments Mr Scheele concluded, that ingredient! the colouring matter of Pruflian blue was compoledc Jitained of volatile alkali and an oily matter. He was con- j" firmed in this conjedlure, by obtaining Pruflian blue from green vitriol and fpirit of hartfliorn recently di- ftilled on the addition of muriatic acid. The fame produdl was obtained by means of the volatile fpirit drawn from ox's blood ; fo that nothing now remain- ed, but to imitate thefe natural procefles by artificial- ly combining the two ingredients together. For ,25^ this purpofe he diftilled a mixture of volatile fait U)!fucc*fs- and unduous oil; a mixture of the fame alkali with ^"'^"^"^P" animal fat, and with oil of turpentine ; a mixture of ["anifidS quick-lime, fal-ammoniac, and auxunge, with others L^'^ ' of a fimilar kind; but in vain. He began therefore to conclude, that as long as the volatile alkali contained any water, it could not enter into an union fufficiently intimate with the other principles to form the colour- ing matter ; and finding alfo that the coal of blood, mixed with fait of tartar, yielded very good lixivium fanguinis, he concluded that no oily matter was ne- ceflary for the fuccefs of the experiment. Thus was our author led to make the follow- True me- ing decifive trials, which at once accompliflied his thod of pui-pofe, and fliowed the truth of the principles he had f°'*"^"^S afliimed. Three table-fpoonfuls of charcoal powder were mixed with an equal quantity of alkali of tar- tar, and the mixture put into a crucible. A fimilar mixture was put into another crucible, and both put into a fire, and kept red-hot for about a quarter of a« hour. One of them was then taken out, and the contents thrown, while perfeAly red-hot, into eight ounces of water. At the fame time he put into the other quantity an ounce of fal-ammoniac in fmall pieces, agitating the whole brifltly together, and taking care at the fame time to pufli the fal-ammo- niac down towards the bottom of the crucible, which he replaced in the fire. Obferving in two minutes af- ter, that no ammoniacal vapours arofe, the whole mafs was thrown, when red-hot, into eight ounces of water.' The former lixivium, into which no fal- ammoniac had been put, yielded no PruflTian blue; but the latter fliowtd the fame phenomena with the befl; lixivium fanguinis, and produced a great quantity of blue. By mixing plumbago with the alkali inftead of charcoal, a tolerable lixivium was obtained. ^^^^ " From thefe experiments (fays Mr Scheele), it Volatile appears, that the volatile alkali is capable of uniting ^'kali ca- with the carbonaceous matter, after it has been fub- ^^^^^ °^ tihzed by a ftrong heat ; that it thus acquires the re-wkh'phlo- markable property of combining fo firmly with fait ofglCcon and tartar as to be able to fuftain the moft violent degree ^*td alka- of heat; and whea this lixivium is diflblved in water,''' there is obtained lixivium fanguinis, as it is called. — ■^"eat'de* It is now eafy to explain what happens in the diftil-gree of " 3 Y lationhcat. '{a) This reafoning feems not to be fufficiently conclufive ; for late experiments have fliowH that inflamma- tion is generally attended with the produdlion of fixed air, which could -not be proved to have an exifteuce et- in the materials or common atmefphere before^ 538, G H E M I lation of Pruffian blue, as v/ell as in that of the other above mentioned metallic precipitates. — In the dilUl- lation of Prullian blue, for inftance, the calx of iron attracts a portion of phlogifton from the colouring matter. Tlie aerial acid being thus difengaged, muil go over into the receiver with tlie volatile alkali, which is fet free at the fame-inftant ; but as the calx of iron in the heat of this diftillation cannot unite with more phlogiilon, a portion of the colouring matter, not decompofed, inuft likewife arife. If the calx of iron could combine with the whole of the phlogiilon, there would come nothinj.; over into the receiver but aerial acid and volatile alkali. In order to prove this, I dillilled a mixture of fix parts of manganefe finely powdered, and one part of pulverized Pruffian blue, manganefe. and obtained nothing but aerated volatile alkali, with- 1205 out the leaiL mark of colouring matter." kiari*^"" ' Scheele further remarks, that this colouring niattef can ""tatter may probably be obtained in an aerial form, It is alfo S T R Y. Pradice, Iron, Appe: ran- ee? on di- Prufliati blue ac- counted for. 1 104 Colourii g matter kept from I'AiniX by feparate only mer- cury and filver I'l om their fuln- tion in ni- though he had not been able to do fo. 1206 Nitie alka' lized by iron. worth notice, that, excepting the folutions of filver and mercury in nitrous acid, the colouring matter of Pruffian blue is not able to dccompofe any other by a fingle eleftive attraftion. Now, as we know that tiousacid. Pruffian blue is not foluble in acids, it naturally fol- lows, that the colouring matter has a greater affinity with iron than acids have, notwithftanding there is no precipitation perceived when this matter is mixed with the folution of vitriol of iron. " It may not be eafy (fays Mr Scheele) to give a fatisfaftory expla- nation of this phenomenon." Iron deflagrates with nitre, and renders the fait al- kaline and cauftic. A part of the iron is thus render- ed foluble, along with the alkalized fait. A mixture of equal parts of iron filings and nitre, injefted into a ftrongly heated crucible, and, after the detonation, thrown into water, tinges the liquor of a violet or purplifh blue colour. This folution, however, is not permanent. Though the liquor at firft paffiss through a filter, without any feparation of the iron ; yet, on ftanding for a few hours, the metal falls to the bot- tom, in form of a brick-coloured powder. Volatile alkalies inftantly precipitate the iron from this fixed alkahne folution. Iron readily unites with fulphur; and when com- and lull. hurbined with it, proves much eafier of fufion than by take fire itfelf. A mixture of iron filings and fulphur, moiften- ed with water, and preffed down clofe, in a few hours fwells and grows hot j and, if the quantity is large, burits into flame. By cementation with inflammable matters, iron im- bibes a larger quantity of phlogifl:on ; and becomes much harder, lefs malleable, and more fufible. It is then called ^eel. See Metallurgy, and Steel. ^5. Lead, Lead is a pale or livid-white metal, foon lofing its brightnefs in the air, and contrafting a blackifh or greyifh afli-colour. It is the fofteft and mofl; flexible of all metallic bodies ; but not dudile to any great de- ■ 1108 gree., either in the form of wire or leaf ; coming far Has very ^ -^^ ^j^j^ refped, of all other metals. It has alfo little tCIlfcl" • • ^ • city. the leaft tenacity of all metallic bodies ; a leaden wire 1*07 Irnn fiiinc fpo tane- of TTj- of an inch diameter being capable of fupporting Iv'ad. only 29I pounds. Lead has, however, a confiderable fpecific gravity ; lofing, wlien immeiitd in water, be- tween -rV and XT of its weight. It is of all metals the j j^^p moft fufible, excepting on'y tin and bifmuth. Tiie i>hcet-lead. plumbers caftthin fheets of lead upon a table or mould, covered with a v/oollen, and above this with a linen, cloth, without burning or fcorching the cloths. The melted lead is received in a w^ooden cafe without a bottom ; v/hich being drawn down the fiuping table by a man on each fide, leaves a ilieet of its own width, and more or lefs thin according to the greater or lefs celerity of its defcent. For thick plates, the table is covered over with moiftened fand, and the liquid me- tal condutled evenly over it, by a wooden llrlke, which bears on a ledge at each fide. ^^^^ Some have preferred, for mechanic ufes, the milled Advmta- lead, or flatted flieets, to the call:; as being more equal, '^es of iml- fnicjoth, and folid. But whatever advantage of this^*-^ kind the milled fort may appear to have at firft, they P''^*-^' are not found to be very durable. When the lead is ftretched between the rollers, its cavities mull nc- ceflarily be enlarged. The particles of metal that may be fqueezed into them can have no union or ad- hefion witii the contiguous particles ; and, of confe- quence, muft be liable, from bending, blows, jarrs, &c. to ilart out again, and leave the mafs fpongy and perous. 'der^d Lead yields the duUeft and weakeft found of all me- (onorous. tallic bodies. Reaumur obferves, that it is rendered fo- norous by calling a fmall quantity into a fpherical or elliptical fegment, as in the bottom of an iron-laddle ; from hence he conjeftures, that the found of the fo- norous metals might be improved for the bells of clocks, &c. by giving them a fimilar form. Though this metal very foon lofes its luftre, and tar- nifhes in the air, it refills much longer than iron or copper the combined adlion of air and water, before it is decompofed or deftroyed ; and hence it is exceed- ingly ufefui for many purpofes to which thefe metals ^^^^ can by no means be applied. When juft become fluid. Calcined, lead looks bright like quickfilver ; but immediately contrails a varioufly coloured pellicle on the furface. If this is taken off, and the fire continued, a frefh pel- licle will always be formed, tiU the metal is by degrees changed into a dufl.^ preferves its metallic form. On con- tinuing the fire, the lead, fcorifying or calcining, ab- forbs the phlogiftic principle of the iron, and confe- quently promotes the calcination of that metal ; both being at length reduced to calces. The fufible calx of lead eafily unites with the calx of iron, and both melt together into an opaque brown or blackiih glafs. Cop- per does not unite with melted lead till the fire is rai- fed fo high as to make the lead fmoke and boil, and of a bright red heat. Pieces of copper, now thrown in, foon dilTolve and difappear in the lead : the mix- ture, when cold, is brittle, and of a granulated tex- ture. The union of thefe two metals is remarkably flight. If a mixture of copper and lead is expofed to a fire no greater than that in which lead melts, the lead almoft entirely runs off by itfelf ; a fepa- ration of which no other exaihple is known. What little lead is retained in the pores of the copper, may be fcorified, and melted out, by a fire confiderably lefs than is fufficient to fufe copper. If any of the copper is carried off by the lead, it fwiras unmelted on the furface. Gold and filver are both dilTolved by lead in a flight red heat. They are both rendered extremely brittle by the minuteft quantity of this metal; though lead is rendered more duftile by a fmall quantity of either of them. In cupellation, a portion of lead is retained by gold, but filver parts with it all. On the other hand, in its eliquation from copper, if the copper contains any of the precious metals, the filver will totally melt out with the lead, but the gold will not. The attrac- tion of lead to copper, however flight, is greater than that of copper to iron : a mixture of copper and iron being boiled in melted lead, the copper is imbibed by the lead, and the iron thrown up to the top. Silver is in like manner imbibed from iron by lead ; whilft tin, on the contrary, is imbibed from lead by iron. If two mixtures, one of lead and tin, and another of iron and filver, be melted together, the refult will be two new combinations, one of the tin with the iron at the top, the other with the lead and filver at the bot- tom : how carefully foever the matter be ftirred and mixed in fufion, the two compounds, when grown cold, are found diftinft, fo as to be parted with a blow. This metal is foluble in alkaline lixivia and expref- CHEMISTRY. 539 fed oils. Plates of lead boiled in alkalifie lixivia, have Tin. a fmall part diffolved, and a confiderable quantity cor- v™"^ roded : the folution ftains hair black. Lead, fufed ^ 1 bV^' with fixed alkaline falts, is in part corroded into a ^1]^^^);^^^^ ^j^^ dark-coloured fcoria, which partially diffolves in wa- ia oils, ter. Expreffed oils diffolve the calces of lead, by boil- ing, in fuch large quantities as to become thick and confiftent : hence plallers, cements for water-works, paint for preferving nets, &c. Acids have a greater affinity with leads than oils have. If the common pla- fler, compofed of oil and litharge, be boiled in dillil- led vinegar, the litharge will be diffolved, and the oil thrown up to the top. The oil thus recovered, proves foluble like effential oils in fpirit of wine ; a pheno- menon firlt taken notice of by Mr GeofFroy. ^ 6. r IN. The colour of this metal refembles filver, but is foraewhat darker. It is fofter, lefs elaftic, and fo- norous, than any other metal except lead. When bent backwards and forwards, it occalions a crackling- found, as if torn afunder. It is the Hghteft of all the malleable metals, being little more than feven times fpecifically heavier than water. The tenacity of its parts alfo is not very confiderable ; a tin wire of ~ of an inch diameter being able to fupport only 494- pounds. Tin is commonly reckoned the leafl duftile of all Capable of metals except lead ; and certainly is fo, in regard to h^>"g duttility into wire, but not in regard to extenfibiHty ["^^^g^'" into leaves. Thefe two properties feem not to be fo ^ ' much connefted with one another as is generally ima- gined. Iron and fteel may be drawn into very fine wire, but cannot be beat into leaves. Tin, on the other hand, may be beat into very thin leaves, but cannot be drawn into wire : gold and filver poffefs both properties in a very eminent degree ; whilft lead, notwithftanding its flexibility and foftnefs, can- not be drawn into fine wire, or beat into thin leaves. It melts the moft eafily of all the metals ; about the 430th degree of Fahrenheit's thermometer. Heated till almoft ready to melt, it becomes fo brittle that large blocks may be eafily beat to pieces by a blow. The purer fort, from its facility of breaking into long fhining pieces, is called grain-tin. Melted, and nim- bly agitated at the inftant of its beginning to congeal, it is reduced into fmall grains or powder. ^^^^ With, the heat neceffary for fufion, it may alfo be Calcined, calcined ; or at leaft fo far deprived of its phlogifton as to appear in the form of a grey calx, which may be entirely reduced to tin by the addition of inflam- mable matter. The calcjjiation of tin, like that of lead, begins by the melted metal lofing its brightnefs, and contradting a pellicle on its furface. If the fire is railed to a cherry-red, the pellicle fwells and burfts, difcharging a fmall bright flame of an arfenical fmell. By longer continuance in the fire, the metal is con- verted firft into a greyifn, and then into a perfectly white calx, called putty, which is ufed for polifhing glafs and other hard bodies. The calx of tin is the moft refraftory of all others. Even in the focus of a large burning mirror, it only foftens a little, aud forms ciyftalline filaments. With .3 Y 2 glafs 540 Tin. CHEMISTRY. 1x19 Affinity of tin with arfenic. Arfcnic k parable from tin. mi 9r Lewis' vbferva- tion. glafs of bifmutTi, and the fimple and arfenicated gkfles of lead, it forms opaque milky compounds. By thfs property it is fitted for making the bafis of the im- perfeft glafl'es called enamels; (fee Glass and Ena- mel). The author of the Chemical Diftionary re- lates, •* that having expofed very pure tin, fingly, to a fire as ftrong as that of a glafs-houfe furnace, during two hours, under a muffle, in an uncovered teft, and having then examined it, the metal was found covered with an exceedingly white calx, which appeared to have formed a vegetation ; under this matter was a reddifli calx, and an hyacinthine glafs ; and laJUy, at the bottom was a piece of tin unaltered. The expe- riment was feveral times repeated with the fame fuc- cefs." Nitre deflagrates with tin, and hafliens the calcina- tion of this as well as of other imperfect metals. The vapours which rife from tin, by whatever method it is calcined, have generally an arfenical fmell. Tin melted with arfenic falls in great part into a whitifh calx : the part which remains uncalcined proves very brittle, appears of a white colour, and a fparkling pla- ted texture, greatly rcfembhng zinc. The arfenic is ftrongly retained by the tin, fo as fcarcely to be fepa- rable by any degree of fire ; the tin always difcover- ing, by its augmentation in weight, that it holds a por- tion of arfenic, though a very intenfe fire ;has been ufed. Hence, as the tin ores abound in arfenic, the common tin is found alfo to participate of that mi- neral. Heoekel difcovered a method of feparating aftual arfenic from tin ; namely, by flowly diffolving the tin in eight times its quantity of an aqua regia made with fal ammoniac, and fetting the folution to evaporate in a gentle warmth : the arfenic begins to cone ete whilll the hquor continues hot, and more plentifully on its growing cold, into white cryftals. M. Margraaf, in the Berhn Memoirs for 1747, has given a more par- ticular account of this procefs. He obferves, that the white fediment which at firft feparates during the dif- folution, is chiefly arfenical ; that Malacca tin, which is accounted one of the purefl forts, yielded no lefs than ^th its weight of arfenical cryftals; that fome forts yielded more; but that tin extracted from a particular kind of ore, which contained no arfenic, afforded none. That the cryfl:als were truly arfenical, appeared from their being totally volatile ; from their fubliming (a. little fixed alkaline fait being added to abforb the acid) into a colourlefs pellucid concrete ; from the fublimate, laid on a heated copper-plate, exhahng in fumes of a garhc fraell ; from its ftaining the copper white ; and from its forming, with fulphur^ a com- pound fimilar to the yellow or fulphurated arfenic. He found that the arfenic was feparable alfo by means of mercury ; an amalgam of tin being long triturated with water, and the powder which was wafhed off committed to diftillation, a little mercury came over, and bright arfenical fiowers arofe in the neck of the s retort. Dr Lewis obferves, that the crackling noife of tin in bending may poffibly arife from its arfenic } as thofe operations which are faid to feparate arfenic £rom the metal, likewifc deprives it of this property. Tin may be allayed, in any proportion, with all me- tals by fufion: but it abfolutely deltroys their dudility, and renders them brittle, as in bell-metal ; whence this 'Vlercury metal has obtained the name of dtabolus metallorum. fUve^""^''' Iron is dilfolved by tin in a heat far lefs than that in , ^ which iron itfelf melts ; the compound is white and j^,.^ brintle. Iron added to a mixture of lead and tin, takes Ii jurious t» up the tin, leaving the lead at the bottom ; and, in like o-her ms- manner, if lead, tin, and filver, are melted together, the addition of iron will abforb all the tin, and the tin only. Hence an eafy method of purifying filver from tin. Tin, notwithftanding it is, like lead, foon deprived '**^| of its lufl;re by expofure to the air, is neverthelefs j^^'J^^ * much lefs liable to ruft than either iron, copper, or lead ; and hence is advantageoufly ufed for covering over the inlides of other metalline veffels. The amal- gam of mercury and tin is employed to cover one of the furfacts of looking-glafi'es ; by which they are ren- dered capable of reflcfting the rays of light. The ^^^4 amalgam alfo, mixed with fulphur and fal ammoniac, Aurum and let to fublime, yielos a fparkling gold-coloui-ed mofaicun**. fubfl;ance called aurum mofaicum ; which is fometimes ufed as a pigment. This pi-eparation is commonly made from quickfilver and tin, of each two parts, amalgamated together ; and then thoroughly mixed with fulphur and fal ammoniac, of each one part and a half. The mercury and fulphur unite into a cinna- bar, which fubhmes along with the fal ammoniac ; and, after fublimation, the aurum mofaicum remains at the bottom. Sulphur maybe united with tin by fufion; and forms with it a brittle mafs, more difficultly fufible than pure tin. Sulphur has, in this refpe£l, the fame efleft up- on tin as upon lead. The allay of tin leflens the fufi- bihty of thefe very fufible metals ; while it increafes- the iufibility of other difficultly fufible metals, as iro» and copper. § 7. Mercury or ^ucksilfer. Mercury is a fluid metaUic fubfl;ance, of a bright filver colour, refembhng lead or tin. when melted ; en- tirely void of tafte and fmell; extremely divifible ; and congealable only in a degree of cold very difficultly produced, in this country, by art (fee Cold and Con- j gelation). It is the moft ponderous of all fluids,. HeavicT m and of all known bodies, gold and platina excepted ; winter than its ipecific gravity being to that of water nearly as 14'° fummeE* to I . It is found to be fpecificaUy heavier in winter than in fummer by 25 grains in 1 1 ounces. Neither air nor water, nor the united aftion of thefe two, feem to make any impreffion upon mercury : nor is it more fufceptible of rult than the perfed metals. Its furface, neverthelefs, is more quickly tarnifhcd' than gold or fdver ; becaufe the duft which floats in the air, quickly feizes on its furface. The watery va- pours alfo, which float in the air, feem to be attract ted by mercury. From thefe extraneous matters, which only fliehtlv n 'i** adhere to it, mercury may be eafily cleanfed by paf- tion. fing it through a clean new cloth,, and afterwards heating it : but if mixed with any other metal, no fe- paration can be effefted •Ovithout diftillation.. In this procefs, a fmall portion of fome of the metals gene- rally arifee along with the mercury. Thus, t^uickfil- 5 ver Pradice. CHEMISTRY. 54« CJurious mercurius ver diflilled from lead, bifmuth, or tin, appears lefs Mercury bright than before ; ftains paper black ; fometimes ex- or Quick- hJbits a lliin upon the furface ; and does not run freely, or into round globules. Mr Boyle relates, that he lias obferved the weight of mercury fenfibly inert afed by diftillation from lead, and this when even a very moderate fire was made ufe of. By amalgamation with ilellated regulus of antimony, and then being diftiUed after a few hours digeilion, mercury is faid to become, by a few Repetitions of the procefs, more ponderous, and more aftive. The animated, or phi- lofoohic mercuries of fome of the alchemifts, are fup- ly ]3oyle. pofJd to have been mercury thus prepared. By the fame, or fimilar procelTes, feem to have been obtained the curious mercuries which Boyle declared he was pofleffed of, and made himfelf ; which were " confi- derably heavier in fpecie than common quickfilver, — diiTolved gold more readily,— grew hot with gold, fo as to be offenfive to the hand, and elevated gold in diftillation." When quickfilver is to be diftilled, it is proper to mingle it with a quantity of iron-filings ; which have the property of making it much brighter than it can be otherwife obtained, probably by furnifh- ing phlogifton. By digeftion in a ftrong heat for feveral months, mercury undergoes a confiderable alteration, changing into a 'powder, at firft alh-coloured, afterwards yel- low, at length of a bright red colour, and an acrid tafte ; and is then called wercurius precipitatns per fe. precii ita- In this laft ftate it proves fimilar to the red precipi- tus per fe. tate, prepared from a folution of mercury in nitroua acid. This calx proves lefs volatile in the fire than the mercury in its fluid ftate. It fupports for fome time even a degree of red heat. In the focus of a burning mirror, it is faid to melt into glafs when laid upon a piece of charcoal, and to revive into running mercury before it exhales. Evaporated by common fire, it leaves a fmall portion of a light brown powder; which, Boerhaave relates, bore a blaft-heat fwelled into a fpongy mafs ; formed with borax a vi- treous friable fubftance ; but vanifhed in cupellation. 14*9 By a long continued digeftion in a gentle heat, mercury *^T''"abIe fuffers little change. Boerhaave digefted it in low byVgemie degrees of heat, both in open and clofe veffels, for Mercurius preci[ ita- 15 years together, without obtaining any other re- ward for his labour than a fmall quantity of black pow- der ; which, by trituration, was quickly revived into running mercury. Conftant triture, or agitation, pro- duce a change fimilar to this in a fiiort time. Both the black and red powders, hj bare expofure to a hre fufficient to elevate them, return into fluid mercury. The red powder has been revived by fimplj grinding it in a glafs mortar. In like manner, quickfilver remains unchanged by diftillation. Boerhaave had the patience to diftil 18 ounces of mercury upwards of 500 times over, with- out obferving any other change than that its fluidity and fpecific gravity were a little increafed, and that ExSo' fome grains of a fixed matter remained. The vapours by the VH- of mercury, like thofe of all other voktile- bodies, pours of caufe vrolent explofions if confined. Mr HcHot gives mercury. account of his being prefent at an experiment of this kind : a perfon pretending to fix mercury, had inclofed it in an iron box clofcly welded. When the 1430 ©r by di Aiilation. mercury was heated, it burft the box, and diffipated M- r . v . . .L , at Quick- in uivilible vapours. ^ ^ _ _ filver" Mercury diffolves or unites with all metallic bodies, > ., ^ « except three, -viz. iron, arfenic, and nickel : in fome ^^^^ cafes It will abforb metals, particularly gold and filver, Amaiga- fr ;m their folutions In acids or alkahes ; but does not mate-: with adl upon any metal when combined with fulphur, nor fjtj^^^'^j.'g^ on precipitates made by alkalies, nor on calces by fire. Whatever metal it is united with, it conltantly preferves its own white colour. It unites with any proportion of thofe metallic fabftances with which it is capable of being combined ; forming, with diff"erenfe quantities, amalgams of different degrees of confift-- ence. From the fluid ones, greateft part of the quick- filver may be feparated by colature. Bifmuth is fo far attenuated by mercury, as to pafs through leather with it in confiderable quantity. It alfo promotes the aftion of quickfilver upon lead to a great degree; fo- that mercury united with^, or t't its weight of bifmuth, diffolves mafles of lead in a gentle warmth,, without the agitation, triture, comminution, or melt-- ing heat necelfary to unite pure mercury with lead. From thefe propertleSr this folution of bifmuth In mer- cury becomes a pro-per folvent for pieces of lead lod- ged In the human body. 1*1? On triturating or digefting amalgams for a l^ngth^^P^^^^^^^"^ of time, a blackifh or dufl;u!us ea- filymifcible with mer- cury. This femimetal, when pure, and well fufed, is of a white fliining colour, and confills of laniiiias applied to each other. When it has been well melted, and not too haftily cooled, and its furface is not touched by any hard body during the cooling, it exhibits the perie6t figure of a ftar, confiiling of many radii ilfuiug from a centre. This proceeds from the difpofitioa that the parts, of this femimetal have to arrange themfelves in a regular manner, and is fimilar to the cryftallization of falts. Regulus of antimony is moderately hard ; but, like other femimetals, it has no duftility, and breaks in fmall pieces under a hammer. It lofes 4 of its weight in water. The aftion of air and water dellroys its luftre, but does not rull it fo effeftually as iron or cop- per. It is fufible with a heat fufticient to make it red hot ; but when heated to a certain degree, it fumes .continually, and is diffipated In vapours. Thefe fumea form what are called the argentine Jloivcrs of regulus of antimony, and are nothing but the earth of this fe- mimetal deprived of part of its inflammable principle, and capable of being reduced to its reguline ftate by an union with this principle. There are different methods of preparing the regu- lus of antimony ; but all of them confiil merely in fe- parating the fulphar which this mineral contains, and which is united with the regulus. It is plain, there- fure, that regulus of antimony may be made by an ad- dition of any fubllance to crude antimony in fuhon, which has a greater attraftion for fulphur than the re- gulus itfelf has. For this purpofe, alkaline falts have been employed, either previoufly prepared, or extem- poraneoufly produced in the proccfs, by a deflagration of tartar and nitre. By this means, the fulphur was indeed abforbed ; but the hepar fulphuris, formed by the union of tlie fulphur and alkali, immediately dif- folved the regulus, fo that very little, fometimes none at all, was to be obtained diftinft fi-om the fcoria. Me- tals are found to anfwcr better than alkaline falts, but the regulus is feldom or never free from a mixture of the metal employed. The way of obtaining a very pure regulus, and in great quantity, is to calcine the antimony, in order to diffipate its fulphur ; then to mix the calx with inflammable matters, fuch as oil, foft foap, &c. which are capable of refl^oring the principle of inflammability to it. This method was invented by Kunckel. Another, but more expen- five way of procuring a large yield of very pure regu- lus, is, by digefting antimony in aqua regis, which dif- folves the reguline part, leaving the fulphur untouched, precipitating the folution, arid afterwards reviving the precipitate by melting it with Inflammable matters. There are -confiderable differences obfervcd in the regulus. of antimony, according to the different fub- fl^ances made ufe of to abforb the fulphur. When prepared by the common methods, it is found to be very diflicultlyaznalgamated with mercuiy; but Mr Pott has difcovered, that a regulus prepared with two or five parts of iron, four of antimony, and one of chalk, rea- dily unites with mercury into an hard amalgam, by bare trituration with water. Marble and.g^ulcklimc fuc- VaL. IV. PAK.T U.- I S T R Y. ceed equally well with chalk ; but clay, gypfum, or^esrulus of other earths, have no effecl. ' Andm .ny. One earthy fubflance, found in lead-mines, and com- monly called ca-wk, has a very remarkable eflfedf upon Extern antimony. This is found in whitifh, moderately com- rp.ne ius rc- pact, and ponderous mafles; it is commonly fuppofed g"'"'' with a fpar ; but differs from bodies of this kind, in not be- ing adtedupon by acids, (fee n'^ 1068). If a lump of cawk, of an ounce or two, be thrown red hot into 16 ounces af melted antimony, the fufion continued about two minutes, and the fluid matter poured off, " you will have 15 ounces Hke poliflied fteel, and as the mofl refined quickfilver." Phil. Trmif. n°iio. Dr Lev/ia mentions his having repeated this experiment feverai times with fuccefs : but having once varied it by mix- ing the cawk and antimony together at the firfl,apart of the antimony was converted into a very, dark black vitreous matter, and part ftemed to have fuffered little change; on the furface of the mafs fome yellow flowers appeared. Regulus of antimony enters into the compofitions for metallic fpeculums for ttlefcopes, and for printing- types. It is alfo the bafis of number of medicinal prepa- rations; but many of thefe, which were formerly much eiteemed, are found to be either inert, uncertain, or dangerous In their operation. When taken in fub- llance, It is emetic and purgative, but uncertain in itg opei-atlon ; becaufe it only afts in proportion to the quantity of folvent matter it meets with in the ito- mach ; and if it meets with nothing capable of aching upon it there, the regulus will be quite inadflve. For tliefe reafons, the only two preparations of antimony now retained, at leail by flcilful pradtitioners, are the infufion of glafs of antimony in wine and emetic tar- tar. For making the glafs of antimony we have the jj^, following procefs. " I'ake a pound of antimony ; re- Glafs .ir- duce it to tine powder, and fet it over a gentle fire ; tini^ny. calcine it in an unglazed earthen pan, till It comes to be of an afh colour, and ceafes to fume : you muilkeep it continually ilirring; and if it fliould run into hirapa, you muft powder them again, and then proceed to fi- niflithe calcination. When that is done, put the cal- cined antimony into a crucible ; fet it upon a tile in a wind-furnace; put a thin tile on the top; and covtr it all over with coals. When it is brought into fufion, keep it fo in a flirong fire for an hour : then put into it an iron rod; and when the melted antimony, -which adheres to it, is .tranfparent, pour it upon a fmooth, hot, marble ; and when it is cold, piit it ud for ufe. This is nfitrum antimonii, ovJUliuni.''* This preparation is more violent ia its efFecls thaR the pure regulus itfelf ; becaufe it contains lefs phlo- gifton, confequently is fimilar to a regulus partially calcined, and fo more foluble. Hence it is the moft proper for infufion in wine, or for making the tartar emetic. It is obvloufly, liowever, liable to great un- certainties in poiiit of llrength ; for as the antimony is more or lefs ftrongly calcined, the glafs will turn out llronger or weaker in its operation, and confequently all the preparations of it muft be liable to much uncer- 1158 tainty. This uncertainty is very apparent in the Difference ftrength of different parcels of emetic tartar: accord- °^ ingly Mr Geoffroy found by examination of different ["rtars emetic tartars, that an ounce of the weakeil contain- * - 54^ CHEMISTRY. Pradice. Pulvis al- gari.th the nioft; pro- RepuUis of ed from 30 to 90 grains of regulus ; an ounce of mo- Antim ony. (jj;j.jjte ftrength contained about 108 grains ; and an "^"^^ ounce of the llrongell kind contained 154 grains. For thcfe reafons, the author of the Chemical Dic- tionary recomnaends the pulvis algaroth as the moll proper material for making emetic tartar ; being per- feftly foluble, and always of an eqnal degree of ftrength. Emetic tartar, as he juftly obferves, ought to be a metallic fait compofed of cream of tartar fatu- ] er niateri- rated with the regulus of antimony ; and M. Beaume for emc- has Hiown fuch a faturation to be poffible, and that the tiq tartar, neutral fait ci^ftalllzes in the form of pyramids. They are tranfparent while moift ; but by expofure to a dry air, they lofe the water of their cryftallization, and be- come opaque. The preparation of this fait, according ... to M. Baume, confifts in mixing together equal parts of cream of tartar, and levigated glafs of antimony : thefe are to be thrown gradually into boiling water ; and the boiling continued till there is no longer any efFervefcence, and the acid is entirely faturated. The liquor is to be filtered ; and upon the filter is obferved a certain quantity of fulphureous matter, along with fome undiffolved parts of the glafs of antimony. When the filtered liquor is cooled, fine cryftals will be form- ed in it, which are a foluble tartar perfeftly faturated with glafs of antimony. He obferves, that the diffolu- tion is foon over if the glafs is well levigated, but re- quires a long time if It is only groftly pounded. The trouble of levigating glafs of antimony, as well as the uncertainty of difiblving it, would render pul- vis algaroth much preferable, were it not on account of Its price ; which would be a temptation to thofe in ufe to prepare medicines, to fubltitnte a cheaper antlmonial preparation in Its place. This objection, however, Is now In a great meafure removed by Mr of pulvis al- Scheele who demonlirated' that the pulvis algaroth garoth. is no other than regulus of antimony half calcined by the dephlogittlcated marine acid In the corrofive fubli- mate made ufe of for preparing the antimonlal can- flic. If therefore we can fall upon any other method of dephloglfticating the regulus, we lhall then be able to combine the marine add with it; and by feparating them afterwards, may have the powder of algaroth as good as from the butter of antimony itfelf. One of the methods of dephlogifticatlng the regulus Is by nitre. Our author therefore gives the following re- ceipt for the powder in queftion. " Take of powdered crude antimony one pound; for making powdered nitre, one pound and an half ; which, after be- it cheap. j,,g dried and mixed, -are to be detonated in an iron mortar. The hepar obtained In this manner is to be powdered, and a pound of it to be put into a glafs velTel, on which firft a mixture of three pounds of wa- ter and I 5 ounces of vitriolic acid is to be poured, and afterwards 15 ounces of powdered common fait are to be added ; the glafs vefftl is then to be put in a fand bath, and kept in digcftion for 12 hours, during which period the mafs is to be conllantly ftirred. The folution, v/hen cool, Is to be llralned' through linen. On the refiduum one third of the above menftruum Is to be poured, and the mixture digefted and ftrained. From this folatlon, when It is diluted with boiling wa- ter, the pulvis algarothi precipitates, which Is to be well edulcorated and dried." As regulus of antimony, like other raetallic fub- Objedtion S-o its ufe. J46l Scheele's theory of the nature His receipt Arfenic. I z6s Golden ful- phur of avi- timony aii.l kermes xax". iieral. T264 Diaphore- tic antimc*- ny. 1365 Crocus me!» tallorum. ftances. Is foluble in liver of fulphur, It happens, that, on boiling antimony in an alkahne ley, the fait, uniting with the fulphur contained in that mineral, forms an hepar fulphurls, which dilfolves fome of the reguline part. If the liquor is filtered, and faturated with an acid, the regulus and fulphur will fall together in form of a yel- lowllh or reddilli powder, called golden fulphur of antimony > If the ley is fufFered to cool, alike precipitation of a red powder happens. This laft Is called hermes mitieral. Nitre deflagrates violently with antimony, confum- ing not onlylts fulphureous part, but alfo the phlogifton of the regulus :. and thus reduces the whole to an inert calx, called antlmonium d'taphoretkum. If equal parts of nitre and antimony are deflagrated together, the fulphureous part Ifr confumed, as well as part of the inflammable principle of the regulus. The metalline part melts, and forms a femivltreous mafs, of a red- dlfli colour, called crocus metalloruniy or liver of anti- mony. It is a violent emetic, and was formerly ufed for making Infufions in wine fimilar to thofe of glafs of antimony ; but Is now difufed on account of Its un certainty in ftrength. It is ftill ufed by the farriers : but the fubftance fold for it Is prepared with a far lefs proportion of nitre ; and fometimes even without any alkaline fait being added to abforb part of the antimo- nlal fidphur. This crocus is of a dull red colour; and,, when powdered, alTimies a dark purple. ^11. A R s EN 1 r... Tuisfubftance, In Its natural ilate, has no appearance, of a metal, but much more refembles a fait, which, as has been already obferved, it really is when deprived 1266 of its phlogifton. When united to a certain quantity Aifenic of phlogilton, it alTumes a metallic appearance; ^""^ in this ftate it is found, as Mr Bergman informs us* a^^etallic In Bohemia, Hungary, Saxony, Hercynia, and other form, parts ; particularly at Alfatia in the mines called St Marieux. The mafles in which. It is found are frequently ftiapelefs, friable, and powdery ; but fome- times compact, and divided into thick convex lamellas, with a needle-formed OF micaceous furface; It takes a poliflij.but foon lofes It again in the air. When frefh broken, it appears compofed of fmall needle-like grains of a leaden colour, foon becoming yellow, and by de- grees blackifh ; exceeding copper In hardnefs, though as brittle as antimony. - 1267 Reguline arfenic, whether foiuid naturally or pre- Regulus cfjl pared by art, very readily parts with as much of its ^'"'^"^'^ phlogifton as is fufficlent to make it fly off in a white ifj^o'tj^g'^ ^ \ frnoke ; but this ftill retains a very confiderable quan- common licy of phlogiftic matter, as is evident from its producing white klndj nitrous air by the affufion of nitrous acid, and. from the experiments already related of the preparation of the acid of aifenic. This calx indeed Is the form In which arfenic is moft commonly met with. It is lefs volatile than the reguks ; and by fublimation In a glafs veffel : alFumes an opaque cryftalline appearance from be- coming white on the furface ; but that which cryftal- lizes in the bowels of the earth does not apppar to be fubjed to any fuch change. 1268 White arfenic, though a true metalline calx, may be White ar- mixed In fufion with the fame metals which will unite ^'^•'"^ with the regulus. This feems contrary to the general ^it^ other; rule of otbtr calces, which cannot be united with any metals. metal . acid. Ipraaice. C H E M I Arfenic. metal iti its metalline Rate; but it mud be remembered, ^■~"~v~~ that by this operation the arfenical calx is reduced to a regulus by the phlogifton of the metal : whence, in all fu- fions of this kind, fome fcorias rife to the top, confilling of the calcined metal and part of the white arfenic. 7**^^ e Eieht parts of diftilled water diffolve, by means of Solution 01 . *' ' , r 1' • J r • - J u,. arfenic in moderate heat, one part of calcined arienic, and by water, boiling may be made to take,, up 15. The folution changes fyrup of vIolet> green, but the tinfture of turnfole red. It is not changed by neutral falts, but flowly precipitates the folutions of metals, the arfenic united to the metalline calx falling to the bottom. — "It may be aflced (fays Mr Bergman), whether the whole of the arfenic, or only the arfenical acid, unites with the metallic calx, yielding the phlogiUon to the menftruum of the other metal Certainly fuch a mutual commutation of principles does not appear imi- probable, if we confider only thofe cafes in which the menftruum is vitrioHc or nitrous acid : but as iron, for example, united with marine acid (which does not , aitraft the phlof;ifton of white arfenic), as well as when it is joined to the nitrous acid, is precipitated, it would appear that the whole of the arfenic is united, ,J70 at leaft in certain cafes, to the metallic calces. And ;n fpi- One part of arfenic is diffolved by 70 or 80 of boil- rit of wine. J,^g fphit of wine. ^V}.. Arfenic diffolves partially in concentrated vitriolic In vitiiohc ^^jj^ j^y^ concretes in the form of cryftalhne grains on cooling. Thefe diffolve in water with much greater difficuky than the arfenic itfdf. On the blow-pipe they emit a white fmoke, but form into a globule by fufion, which at firft bubbles, bat foon giows quiet, and is but flowly confumed even in a white heat. This fixity is occafioned by the acid carrying off the phlogifton of the arfenic, and thus leaving a greater proportion of its peculiar acid than what it naturally contains; and therefore the more fi-eqnently the ope- ration is 1-epeated, the more fixed the arfenic becomes, though it is fcarce poflible to diffipate the arfenical phlogifton as pcrfeftly wnth this acid as with the ni- trous ; the efFefts of which have been already particu- larly mentioned. The marine acid, which naturally contains phlo- gifton, diffolves about one-third of its Aveight of arfe- nic, a great part of which feparates fpontaneoufly on cooling in a ftate of faturation with the acid. This fait, which may be had in a cryftalhne form, is much more volatile than the former, readily fubliming in a clofe veflel with a moderate heat ; but is foluble with difii- culty in boiling water. It is of a fine yellow colour, and fcarcely differs from butter of arfenic, except in Its degree of concentration. The nature of marine acid prevents it from difengaging the arfenical acid from the plilogifton of the femimetal, as will eafily ap- pear from what has been faid concerning that acid. The arfenical acid, however, is eafily made to appear by the addition of that of nitre, as will be underltood from the direftions given by Mr Scheele for the pre- ^ paratlon of the acid of arfenic. d^Llkali Arfenic is not precipitated from its folution in vi- cannot%re- triolic and nitrous acids by the phlogifticated alkali, cipitate ar- which yet very readily precipitates all other metals, fenic excel t -p^.^^ marine acid, however, it is precipitated by its jiJTaSd." «iea«s of a white colour i but unlefs the folution be vcrj S T R Y. 547 1172 En marine acid. arfenica 147? acid, the addition of mere watef will throw dowii a Arf enic.^ precipitate of the fame colour. ^ ^ Dephlos>-ifticated marine acid deprives arfenic of its _ '^"^ mflammable principle; fo that m the diftiliing vellel f4(.. we find water, acid of arfenic, and marine acid, rege- phlogifti- nerated. ^i- Arfenic is diffolved by its own acid, and forms cry- ""'"^^ ^^'^ ftalline grains with it as well as with that of fiuor and phenomer* borax. Saccharine acid diffolves it hkcwife, and with othsr forms prifmatic cryftals ; and a fimilar fait is alfo acids, formed by the acid of tartar. Vinegar, and the acids of vinegar and phofphorus, form with it cryftalline grains, which are fcarcely foluble in water. ia7<5. Solutions of fixed alkaU diffolve arfenic ; and, when loaded with it, form a brown tenacious mafs, ' called liver of arfenic. The arfenic is partly precipi- tated by mineral acids, though part of it gradually lofes its phlogifton, and adheres more tenacioufly. So- latiun made with volatile alkali feems to eiTect this decompofition more readily, as no precipitation is made by acids. Limpid folution of faline hcpar, drop- ped into a folution of white arfenic, floats upon the furface in form of a grey ttratum, which at length di- fturbu the whole liquor. By the affiftance of heat folutions of arfenic attack Effedts o« fome of the metals, particularly copper, iron, and zinc; nutaU. the folutions of tlie two laft yielding cryftals by eva- poration. No alteration is made on thefe compounds by alkaline falts or by acids : volatile alkali does not difcover the copper by changing the colour of the fo* lution blue ; nor does the phlogifticated alkali throw down any blue precipitate from the folution of iron. The reafon of this is the fuperabundance of phlogifton in the folutions; for the arfenical acid takes up all metals : w hen united with copper, it fliows a blue co- lour with volatile alkali ; and when united with iron, it lets fail a Prufiian blue in the ufual way ; but the quantity of phlogifton which converts the acid into .while arfenic, prevents the ^ippearance of thefe pheno- mena v^'hen the latter is made ufc of. 1178 Arfenic, either in its calcined or reguline ftate, may Unites eafi» be united with fulphur ; in which cafe it appears ^y ^^'i'^^^^^' either of a red or y^ellow colour, according to the ^ quantity of fulphur with which it is united. Thefe compounds are fpontaneoufly produced by nature ; both of them fometimes pellucid and cryftalhne ; with this difference, however, that the yellow feems to af- fect a lamellated, and the red a cryftalhne, form. 1479 Thefe are called red and yellow orpiment, or realgar and Realgarani orpiment; the fpecific gravity of realgar being about 3.225 ; of orpiment, 5.315. Both of thefe fubhme totally with a moderate heat, unlefs when they hap- pen to be mixed with other fubftances. They readily unite with thofe metals which form an union with the arfenic and fulphur of which they are compofed. Sil- ver mineralized by fufibn with orpiment, forms a fub» ftance fimilar to what is called the red ore of that me- tal. Iron, in conjunftion with orpiment, affumes a white, poliflaed, and metahic appearance, fimilar to that of the white or arfenical pyrites ; and by various combinations of thefe fubftances with metals of diffe- rent kinds, many of the natural metalline ores may be produced. . , . 1- . f • , Phenomew* Nitre, when treated with mmeralized arlenic, de- j^;, 3 Z 2 tpnat^s trous aeiAi- riiie acid> S T R Y. Praaice. of dry nitre, well powdered and mixed, when thrown NiclceL into a red-hot crucible, produce fmall fclntillations ; a — "-nt"" portion of the cobalt being converted Into a calx of a red colour, more or lefs deep, and fometimes of a green. Sal ammoniac is not decompofed, by reafon •^y-'J^°^^j of the little attraftion there is between the metal and ammonia muriatic acid. M. Bucquet, who made the experi 1305 ment with great care, could not obtain a particle of W.th ful- volatile alkali. Sulphur does not unite with it but^'"^^" very difficultly, and the combination is promoted by liver of fulphur. Thus a kind of artificial ore may be produced, the grain of which will be finer or clofer, and its colour whiter or yellower, in proportion to the quantity of fulphur in the mixture. M. Beaume ob- ferves, that this compound cannot be decompofed by- acids, and that fire cannot deftroy all the fulphur. ^13. Nickel. This was firfl difcovered to be a femimetal of a pe- Dif'overei culiar kind by Cronftedt, In the years 1 75 1 and 1 754, by Mr who procured It In the form of regulus from its ore, but Cronftedt.. without being able to reduce it to a fufficient degree of purity; which Indeed has not yet been done by any che- mift. M. Bergman has laboured mofl in this way, though even he has not reduced it to the purity of other metallic fubftances. His experiments were made with fome regulus made by M. Ci-onfledt, and whofc fpe- cific gravity was to that of water exaftlyas 7.421 to I. His attempts to purify it were made, I. By Calcination and Scorlfication. Nine ounces of powdered nickel were expofed for rrr'^i*'' e - , . . . „ • 1 ■, i'-iieCts or lix hours, rn icvei-al portions, to a molt violent heat, calcination under the dome of an affay furnace. Thus the arfe- vvith a vjo-, nic was firft diffipated with a fetid fmtll, after which ^^^^^ the odour of fulphur became perceptible ; after this a white fmoke arofe without any fmell of garlic, and which, according to our author, arofe probably from the more dephloglfllcated part of the arfenic which now began to fublime. The heaps (we fuppofe after the matter had been poured out of the difhes, and yet retaining a greatdeal of heat), whenhot, began to fwell, and green vegetations arofe from ail the fui-face, re- fembling fome kinds of mofs, or the filiform lichen; a ferruginous afii-coloured pov.'der remained at bot- tom ; and o.i 3 of the whole were diffipated during the operation. Half an ounce of this calx, fufed in a forge for four minutes, along with three times its weight of black flux, yielded a regulus reticulated oh the furface ; the areola of a hexangular figure, with very fiend er flrlae, diverging fi-om a centre, full of little tubercles; it weighed 0.73 of half an ounce; was obe- dient to the magnet ; and, when fcorlfied with boi-ax, left a blacklfh glafs. By a fecond roafting the regulus again emitted a garlic fmell ; afterwards a vlfible fume without any fmell, with vegetations as before. The I'oafled pow- der, reduced with black flux as before, ftlU emitted a fmell of arfenic ; but, on repeating the fufion with the calx and borax, nothing but fome obfcure figns of co- balt appeared. A third calcination feemed to have much diflipated the arfenic, as It now emitted but little of that kind of fmell ; the vegetations were alfo gone ; and the matter had rather a ferruginous than a grcei ►raaice. C H E M I NickeL green co!«ur. Nearly the fame phenomencxn appeared -'v after reduAion in a fourth operation. On perforniing the reduftion with lime and borax, the regulus, when firft melted, loft much of its ferru- ginous matter, which adhered to the black fcoiia; ; it foon acquired an hyaciBthine colour, without any re- markable mixture of cobalt, was httle obedient to the magnet, and its fpccific gravity was fomewhat diininilh- ed, being now only 7.0828. By a fifth calcination, gradually adding a quantity of powdered charcoal while the matter continued red hot, a prodigious quantity of arfenic, imperceptible be fore, flew off in the form of vapour ; thearfenical acid being thus furnifhed with as much phlogiilon as was necefTary to make it rife in fume. The regulus was ta-eated in this manner until no more arfenical fmoke could be perceived ; it was now of a lamellated and tenacious texture when reduced, but ftill difFufed the arfenical odour on being removed from the fire. The reading was therefore repeated a fixth time, and con- tinued for ten hours ; the addition of powdered char- coal continued to diiTipate the arfenic in invifible va- pours, which yet were perceptible by the fmell ; the colour of the metallic calx was obfcurely ferrugi- nous, with a mixture of green fcarcely vifible. On reducing the regdus with equal parts of white flux, lime, and borax, a femiduAile regulus was obtained, highly magnetic, and foluble in nitrous acid, to which it communicates a deep green colour j a blackifli mafs remained, which afterwards became white, and when laid on a burning coal, flies off without any remarkable arfenical fmell. The regulus being then fix times fu- fed with lime and borax, the fcorise refembled the hya- cinth in colour, and the metallic part was fuiTOunded with a green calx. The regulus, as before, was mag- netic and femi-malleable. Laftly, it was expofed for 14 hours to a very ftrong heat ; when the powdered charcoal was added by degrees without any dlfTipation of arfenic or lofs of weight ; the colour of the roafted - powder was ferruginous, with a very flight tinge of green. On reduAion, a very fmall globule, itill magnetic, was found among the fcorias. II. By Sulphur. i;iicccs or Eight hundred parts of Cronftedt's regulus of nic- folphur and kel, fufed with fulphur and a fmall quantity of borax, iorax, yielded a mineralized mafs of a reddifli yellow, whofe weight amounted to 1 700. On expofmg one half of this to the fire, it began to grow black ; on which the.' heat was augmented until vegetations appeared ; the remaining calx weighed 652. Melting tliis part with borax, and the other which had not been expofed to the fire, a fulphurated regulus of a whitifh yellow co- lour was obtained, weighing 1 102. The fame regulus, calcined for four hours, was firft covered with egeta- tions, and then, on the addition of powdered char- coal, diffufed an arfenical odour ; the metallic calx was green, and weighed 1038. A whitifh yellow regulus was obtained, femiduftile, highly magnetic, and ex- tremely refraftory, weighing 594. By fufion with fulphur a fecond time, it weighed 816; one half of which roafted to greennefs, united by means of fire to the other half ftill fulphurated, weighed 509, and was almoft deprived of its magnetic quahty. A calcina- tion of. four hours, during which phlogiftou was ad- S5^ Nickel. T308 Effeds of S T R Y. ded, difTipated a confidcrable quantity of arfenic ; the powder put on an afh-colour, fomewhat greenifli, was in " weight 569 ; and by redudlion yielded a regulus whofe furface was red, and which, on breaking, appeared of a white afli-eolour, veiy friable, ,and weighing 432 ; the fpecific gravity 7.173. On mineralizing the regulus a third time with ful- phur, adding charcoal as loqg as any veftige of arfenic remained, which required a violent calcination of 1 2 hours, the remaining powder was of an aih-green co- lour, and weighed 364; but the regulus obtained by means of areduftion effededby the moll violent heat in a forge for three quarters of an hour, was fo refrac- tory, that it only adhered imperfectly to the fcoria, which were of a diftinft hyacinthlne colour ; nor could it be reduced to a globule by means of borax, though urged by the fame vehemence of fire. The abfohite gravity of this regulus was 180; its fpecific gravity 8.666. Its magnetic virtue was very remarkable ; for.- it not only adhered ftrongly to the magnet, but to any other piece of iron ; and the fmall pieces of it attrac- ted one another. It had a confiderable duftility, was of a whitifh colour, mixed with a kind of glittering red ; diffolved in volatile alkali, yielding a blue fofu- tion, and a green one in nitrous acid. An hundred parts of the fame regulus, beaten out into thin plates, were covered, by a calcination of four hours, with a cruft apparently martial, having un- der it a green powder, and within it a nucleus con- fifting of reguline particles ftill unchanged ; the weight being increafed by 5. The friable matter, reduced ta powder, put on a brownifh-green colour ; and after a^ calcination of four hours more, concreted at the bot- tom in form of a friable black cruft, ftrongly magne- tic, and weighing 100 : No veftigea of arfenic were difcovered by a fucceeding operation, in which char- coal was added 5 nor was the magnetic power deftroy- ed, but the weight was inereafed to 105, and the co-', lour fomewhat changed. By fufion for an hour with lime and borax, this powder yielded a regulas of an angular itrufture, red, femidudlile, and altogether mag- netic ; the fpecific gravity being 8.875. '^^^ ^^^^ globule, diffolved in aqua-regia, was precipitated by green vitriol, as if it had been loaded with gold ; but the precipitate was readily foluble in nitrous acid. Moft of the reguli fhowed no figns of precipitation with green vitriol. III. With He par Sulpuris. Fifty-eight parts of regulus of nickel, which had EfTeifts of been fulphurated before, being fufed with 1800 parts ''^I'^f of fahne hepai fulphuris, then diffolved in warm v/ater, ^ * filtered through paper, and precipitated by an acid, yielded a powder, which, by calcination till the ful- phur was driven off, appeared of an afh-colour, and weighed 35. The infoluble refiduum, depnved of its, fulphur by means of fire, was likewife of an afh-colour, and weighed 334. On reducing this regulus by meana of the black flux, a friable regulus was obtaiiied, which had a very weak magnetic property ; but, on fufion with borax, this quality was augmented. On mixing , and melting together equal parts of caLx of nickel, . gypfum, colophony, and white flux, a powdery, fqua- mous, and reguline mafs was produced ; which, by^ fufion with borax, afforded a regulus poffeffing the pro- - perties ■ 552- Nickel. ■T3IS i©f nitre. T311 Kitre ca- pable of fepaiating all tlu' CO balr from .Iiickd. C H E M I perties of nickel, but not entirely deftitute of cobalt, which obeyed the magnet, and did not part with its iron even after two folutions in the nitrous acid, and various reductions by fufion with borax ; the ful- phur was alfo retained with great obftinacy. On dilTolving reguKis of nickel by fufion, in hepar fxilphuris made with fixed alkali, adding a quantity of nitre fufiicient only to deftroy a fmall part of the he* par, the regulus which had becii fufpended by it was feparatcd, and fell to the bottom. On examinincf this regulus, it appeared more pure, and generally deprived of cobalt, but Hill containing iron* In like manner nickel is always very diftinftly precipitated by regulus of cobalt, as this latter is attrafted more powerfully by the hepar fulphuris. When dilTolved by fufion with he- par fulphuris, this femimetal may be precipitated by adding iron, copper, tin, or lead, and even by cobjllt : the regulus obtained is indeed fcarcely ever attracted by the magnet ; but we are not from thence to con- clude that it does not contain any iron ; for when the heterogenous m.atters, which impede its aftion, are pro- perly removed, it then acknowledges the power of. the magnet very plainly. .IV. By Nitre. 'One part of Croniledt's regulus was added to twelve of nitre ignited in a crucible, and kept red-hot for about an hour. Some weak fiailies appeared firil,; then a large quantity of arfenic was emitted; and, laftly , the fides were covered with a blue cruft occafioncd by the cobalt, a green mattet rca:aina7g at .bottom. This, fufed again for an hour, with tv/elve parts of nitre, tinged the internal -fides of the veirtsl of a green colour ; and, laftly, a brownilh green mafs, -inuch lefs in quantity than in the former ojx ration, w;i.') left at the bottom. This green matter, treated in .the fame way for two hours a third time, left a grey fcoria at the -bottom,. which yielded no regulus with black -flux. Another portion of the fame regulus, treated in the fame way with nitre, was dilfolved, and became green; yet on being freed by ablution from the alkaline fait, it yielded no regulus with black flux, but only fcoria of an hyacinthine colour mixed with blue, tinging ni- trous acid, of a green colour, com-reting into a jelly, and ,on evaporation leaving a grtsenifli calx behind. Another portion of Croniledt's regulus was kept fome hours in tlie crucible with 16 parts of nitre ; by which means. all the arfenic was firil feparatcd ; then the phlogifticated nitrous acid ; and, lallly, the fides of the veffei were -penetrated by a kind of green effio- refcences. The mafs, after being wafhed with water, was of a dilute green colour, and tinged bofax of a greenilh brown. A green powder was ftill yielded, after treating this in the fame manner with 1 2 parts of .nitre ; and on reducing it with one-half black flux, .one-eighth borax, and as much lime, a yellowhh white regulus, both magnetic and malleable, was ob- tained, poflelTmg all the properties of nickel. Its fpecific gravity was 9.000 ; the phlogiftic ingredient was ufed in fmall quantity, that the iron might, if polhble, enter the fcoria. It having appeared from this and fome other expe- riments, that nitre was capable of difcovering the fmalleft quantity of cobalt contained in nickel, the produfts of the forper operaticne were now fubjcdcd N° .74. S T R Y. Praaice^ to Its aftion. The regulus produced by repeated fco- N.-dieL rification thus became a little blue ; that diffolved in v— — » volatile alkali (to be afterwards particularly mentioned) difcovered a con'iderable quantity of cobalt ; nor was there any one which did not thus.dlfcover more or Icfs of that ingredient by this trial. v. By Sal Ammoniac. A calx of nickel, fo mucli freed from cob-alt that it Hfledl of did not tinge borax in the leaft, mixed with twice ammo- its weight of fal ammoniac, yielded, by fublimation with a llrong red heat, .two kinda ;of flowers ; one, which rofe higher>than the other:, was of an afli colour; the other white. The bottom of the glafs was ftained of a deep hyacinthine colour : the refiduum was divided into two ft rata ; the upper one yellow, fcaly, and fiiining like mofaic gold. With borax it afforded an hyacinthine glafs, but not regulus ; and in a few days liquefied in the air, acquiring a green colour and the eonfiftence-.of butter. The refiduum flrowed the fame properties with calx of nickel ; and the green folntlon fiiowed no veftiges of Iron with galls, but became blue .with volatile alkali ; which was alfo the cafe with the iflowers. The lower ftiatum contained a calx, blackifh .on the tipper part, but of a ferruginous brown in the under, with a friable and fcarctly magnetic regulus, of a reddifh white. The blackifli calx yielded an hya- cintliine glafs with borax. Part of this ftratum fub- hmed Vv'ith twice its quantity of fal amnioniac ; and ■w ith the fame degree of heat as before, yielded flowers of a very fine white, with a refiduum of ferruginous brown, greenifh on the upper part towards the fides of tlie vefl'^il, the bottom being ftained of an hyacinthine colour as btfore. Twenty parts of fal ammoniac being added to a part of the inferior ft ratum -reduced, the whole was fublimed in a retort ; a blackifli powder re- mained, which became green by calcination, and of an hyacinthine colour by fcorification, as did alfo the bottom of the containing vefiel. The fabllmation be- ing twice repeated, ufing a double quantity of fal am- moniac each time, the calx became at length very green, dlffolving with the fame colour in the nitrous acid, and yielding by reduction a white, brittle, and very, little magnetic regulus. In all thefe fubllmations. It Vas obferved, that the volatile alkali rofe firft ; then fal ammoniac ; and, laftly, a part of the marine acid was forced over by the violeiice of the heat. VI. With Nitrous Acid. Having obtained a fait by cryftallizatlon from nickel Eff^Jh^of dllTolved in nitrous acid, part of this was calcined with antimony, charcoal duft in a proper veflel, and during the opera- tion a large quantity of arfenic was dllfipated ; a grey, femlduftile, and magnetic regulus being obtained after reduftion. A brittle regidus was obtained after a fe- cond fulutlon, precipitation, and rtduftion ; but by a third operation It became again femjdudtile and mag- netic. By repeating this procefs a fourth and fifth time, the quantity became fo much dimlnlfhed that it could no longer be tried. In all thefe folution.s, a blacklfti refiduum appeared ; which, when fufi-ered to ren^ain in the acid, grew white by degrees ; but when edulcorated and laid on a burning coal, exhaled a f.il- })hureous fmoke, ^ and left a black powder foluble ia the nitrous acid. VII. B^ Nickel. Volatile alkali. C H E M I VIL By Volatile Alkali. Four hundred and eighty-feven parts of a calx of nickel, produced by diffolving Cronftedt's regulus in nitrous acid, and precipitating the folution by a fixed alkali, being immerfed for 24 hours in a quantity of volatile alkali, yielded a refiduum of fifty, having a blackifh green colour. The folution, which was blue, by filtration and infpilTation yielded a powder of a light blue colour, weighing 282 ; which, reduced with black flux, produced a white, femiduftile, and highly magnetic regulus, weighing 35, whofe fpecific gravity was 7.000. The fcori^ were of a light red ; but when mixed with borax, put on an hyacinthine colour, and yielded a regulus weighing 30. The two re- guli united together proved very refraftory ; fo that the mafs could not be melted by the blow-pipe, even with the addition of borax. It fent forth neither an arfenical nor fulphureous fmell on the addition of char- coal-duil ; but, on a fucceeding reduftion, yielded hy- acinthine fcorise ; and the remaining flocculi, diiTolved in nitrous acid, affording a very green folution, which, on the addition of volatile alkali, yielded -a powder of the fame colour. From 50 parts of the blackidi green refiduum, 13 of a clear white, brittle, fquamous, and litt'e magne- tic regulus, were obtained, the fpecific gravity of which was 9.333. At the bottom of the veffcl was found a fcoria of an obfcurely blue colour, with the upper part hyacinthine. It was eafil}'- fufed ; and tinged boiax, firft blue, then of a hyacinth colour, upon which it became more llrongly magnetic. By the afiiilance of heat it dilTolved in nitrous acid, forming a folution of a beautiful blue colour. A black powder at firll float- ed in the liquor, but became white, and fe^l to the bot- tom. After cdulcoration it was for the moil part dif- fipated, with a fulphureous fmell, on being expofed to the fire ; a little brown-coloured mafs, fo uble in vola- tile alkali, remaining at bottom. This folution was precipit?ted by phlogiilicated alkali, and a powder thrown dov.'n of the colour of calx of nickel, which foon grew blue with volatile alka^i. From all thefe experiments it appears, that nickel Nickel cai; no' Uc oh- cannot be obtained in a ftate of purity by any means hitherto known. From every othei- fubllance, indeed, nty. it may be fcparated, except iron ; but this refifls all the operations hitherto defcribed, and cannot be di- min'Thed beyond certain limits. 'J"he magnet not only readily difn-rjrs its prefence, but fome portions of the regulus it fell becomes m-dgnetic. ; but the ttiiacity and diil^ciilty of fufion, which increafe the more in proportion to the number of operations, plainly (how that there is no hope of feparating the wliulc quantity, unk fs we fuppofe the regulus of nickel itfelf to be at- tradled by the magnet ; and there is certainly a pof- fibility that one other fubftance befides iron may be attracted by the mapnet. The great -difiiculty, or ra- ther iriipoiiibility, of obtaining it in a ftate of purity, rKiturally raifes a fufpicion of its not being a diilindl femimetal, but a mixture of otliers blended together ; and on this fubjeft our author agrees in opinion with thofe who fuppofe it to be a compound of other me- tiit; com;-o- tals. Indeed, Mr Bergman is of opinion, that " nic- fi'ion .'f kel, cobalt, and manganefe, are perhaps no other than nickel. Y^^^ ly^ Paj-t IL n,)iiiio!i ('f S T R Y. . . .SS3 modificat'ons of iron." And in order to afccrtam this, N^ kii. he made the following experiments. ^ ' I. Equal parts of copper, of the gravity of 9.3243, ^ .^J.^^ and iron of 8.3678, united by fufion with black flux, ^^^^'j^j.^ yielded a red mafs, whofe fpecific gravity was 8.5441 ; mn, >ie and which tinged nitrous acid firft blue, then green, nic'* el arti- afterwards yellow, and at laft of an opaque brown, ficialiy. 2. Two parts of copper and one of iron had a fpecific gravity of 8.4634 ; the mixture yielding firft a blue, and then- a green folution. 3. Equal parts of copper and iron, of the fpecific gravities already mentioned, with another part of cobalt whofe gravity was 8.1500, yielded a metal of the gravity of 8.0300, imparting a iirown colour to the folution. 4. Two parts of arfe- nic of 4.000, added to one of copper and another of iron, gave a brittle metal of 8.0468, which formed a blue folution. 5. One part of copper, one of iron, two of cobalt, and two of white arfenic, gave a brittle regulus of 8.4186 ; the folution of which was brownilh, and feparated in part fpontaneoufly. 6. One part of copper, one of iron, four of cobalt, and two of white arfenic, formed a mafs of 8.5714. The folution was fomewhat more red than the former ; and a fimilar effedl took place on repeating the experiment, on- ly that the fpecific gravity of the metal was now 8.2941. 8. One part of iron and four of white arfe- pic formed a metal which diflblved with a yellow co- lour ; and, on the addition of Pruffian alkali, imme- diately let fall a blu,e fediment. 9. One part of cop- per, eight of iron, iixteen of white arfenic, and four of fulphur, united by fire, on the addition of black flux, yielded a mafs which, though frequently calci- ned and reduced, produced nothing but brown or ferruginous calces. It acquired a greennefs with ni- trous acid, but on the addition of phlogifticated al- kali depofited a Pruffian blue. 10. One part of iron was dlffolved in fix of the nitrous acid, and likewifc feparated by one part of copperand one of the calcined ore of cobalt, in the fame quantity of the fame acid. The whole of the folution of iron was then mixed with five parts of the folution of copper, whence a green and faturated nickel colour was produced ; which, however, on the addition of three parts of the folution of cobalt, became evidently obfcured. The alkaline lixivium dropped into this threw down at firft a ferru- ginous brown fediment, the folution ftill lemaining green : afterwards all the blue was precipitated ; by which at firft all colour was deftroyed, but afterwards a red appeared, occafioned by the cobalt diffolved in the alkaline fait. The fediment, when i-educed, yielded a regulus fimilar to copper, and at the fame time duc- tile, which tinged both glafs and nitrous acid of a blue colour. If a faturated iolution of nickel be mixed with half its quantity of folution of cobalt, the green colour is much obfcured; but four parts of the former, on the addition of three of the latter, put off all ap- pearances of nickel. See the article Nickel. § i^. Of Platina. 1318 The properties of this metal have not as yet been -pjjg ^ea- thor-oughly inveftigated by chemlfts, 'and there is there- vieft of all fore fome difagreeraent concerning them. Formerly nictal*. it was fuppofed to be inferior in fpecific gravity to 4 A gold; 554 CHEMISTRY. P'atina. ^3^9 InP:)lubIe except by fticated ma' gold ; but now is generally allowed to be fuperior in tliat refped by little lefs than a fourth part ; being to Wd,ter in the proportion of 23 to i when perfe£lly freed from all heterogeneous matters. Mr Berg- man fays that its colour is that of the pureft fil- ver. The very fmall globules of it are extremely mal- leable; but when many of thefe are coUefted together, they can fcarcely be fo perfectly fufed as to preferv^e the fame degree of malleability. They are not affec- ted by the magnet in the leaft, nor can they be dif- folved in any fimple menftruvmi excepting dephlogi- riiie acid, ^icated marine acid. As it is commonly met with, 1320 however, platina has the form of fmall grains, its Found in_ plates of a bluifh black, whofe colour is intermediate intSmlxed' '^^^^^^^ thofe of filver and iron. Thefc grains arc wlthforeign ™ixed .with many foreign fubftances, as particles of fubftances, gold, mercury, and blackiih ferruginous, fandy grains, which by the magnifier appear fcorified. The grains themfelves, when examined by a magnifying glafs, ap- pear fometimes regular, fometimes round and flat, like a kind of button. When beat on the anvil, moft of them are flattened arjd appear duftile ; fome break in pieces, and on being narrowly examined appear to be hollow, and particles of iron and a white powder have been found within them : and to thefe we mull attribute tlie attraftion of platina by the magnet ; fince, as we have already obferved, pure platina is not attrafted by it. Mr Bergman, who carefully exammed this metal, dliTolved it firll in aqua-regia compofed of the nitrous and marine acid. The folution at firlt exhibits a yellow colour, but on approaching to faturation be- came red, and the rednefs increafes as the liquor be- comes more loaded with metal. Cryftals are produced by evaporation of a deep red colour, generally in fmall angular and irregular grains, whofe true fhape cannot be difcovered. Their appearance is fometimes opaque and fometimes pellucid. After thefe are once formed, they are extremely difficult of folution, re- quiring much more water than even gypfum itfelf for this purpofe. — The folution is not precipitated by ve- getable fixed alkali, nordoes the latter affeft the cryfl:als, except very faintly by digeftion with them in a cauilic ftate. Aerated mineral alkali takes them up and grows yellow, but without depofiting any thing, though it decompofes tfiem at lallby evaporating to drynefs. Gn the addition of a fmall quantity of vegetable fTe'decom-"' fixed alkali, either mild or cauftic, fmall red cryftals pcfed by foluble in water, and fometimes of an oAohedral fi- Platina. Mr Berg- man's expe rimencs on tliis metal. 1312 Cryllals of nJatina may but gure, are depofited. They are decompofed with ble* fixed^l-' 'iiffi'^ulty by the mineral alkali, but not at all by the kali. vegetable. If a larger quantity of fait is added at firft, an infoluble fpongy matter of a yellow colour is precipitated. Cryttalline particles of the fame kind are thrown down by an alkali faturated either with the vitriolic, nitrous, marine, or acetous acids, though all the platina cannot thus be feparated from the men? flruum. Aqua-regia, compofed of nitrous acid and common aq'4a-re,^:a (^\^^ dilTolved the metal with equal faciHty as the for- made \Mi ^^j, onlv the folution was more dilute, and a vel- lutrcus acid / n , 1 r r , ^■ and that of 'ow powder floated on the iurtace, a larger quantity lea-ialt. being found at the bottom. On adding vegetable fix- ed alkali to the clear folution, a copious yellow pow- der./olubk- in.a large quantity of water, was depolitcd. Solution in A powder, of a fimilar kind, was precipitated, tho' more flowly, and more of a cryftalline nature ; but ^~~V— ^ mineral alkali, though ufed in much larger quantity, did not make any alteration. The colletled powder was yellow, and agreed in property with that fepara- ted fpontaneoufly in a former experiment. 1^24 On repeating the experiment with nitre and depu- In a Hquor rated fpirit of fait, inllead of nitrous acid and fea-falt, ^'j'^^P'^^^^^' the platina was diffolved into gold-coloured liquor, afpii-j^Qf greeni/h coloured granulated matter falling to theiuit. bottom, and the finer part of the fame rifing to the top. After faturating the fuperfluous acid, a metal- lic calx, infoluble in water, was thrown dov/n by the vegetable alkali. The green powder is foluble in wa- ter, and is of the fame nature with the precipitate thrown down by tlie vegetable alkali. Platina precipitated from aqua-regia by a fufficient quantity of mineral alkali, the precipitate wafhed and p,^^jgj. diflblved in marine acid, on. the addition of vegetable al- precipitated ka;li immediately lets fall a cryflialline powder, as it d6es|'y ^e^eta- alfo with nitre and other falts, having the vegetable j'^^^^^'^^'^^j* alkali for their bafis. The cafe is the fame with calx ofiution of the platina dilTolved in vitriolic acid. Nitrous ^cid alfocalx in ma- difiblvf^s the calx of platina, but does not yield any rine acid ; diftind faline precipitate without the aifiilance of ^ri^-ijut ji^t rine acid. — The above phenomena are likewife pi'odu- ivon^ ^ j,^; ced by the precipitate thrown down, by the vegetable lution in ni- alkali after the faline powder has been depofited. ^•''^"s acid. From thefe exiieriments our author concludes, .''■'^■^ . i hat the precipitate which is firlt thrown down, on pirate a the addition of vegetable alkali to folutions of platina, kind of trl- is a faline fubfl;ance, and difiicrent from the calx of P^^c f.ilt. the metal. 2, That tliis faiine precipitate is compo- fed of calcined platina, marine acid, and vegetable al- kali. 3. By means of vitriolic acid, a precipitate ana- logous to this may be obtained, compofed of calcined platina, vegetable alkali, and vitriolic acid. 4. The vt'hole folution of platina cannot be precipitated by vegetable alkali in form of a triple fait; but after pafs- ing a certain Hmit, a metallic calx in, the ufual way is produced. As it has been denied by Margraaf and Lewis ihat^^^^'^^ mineral alkali is capable of feparating platina from i^Sj^^j^^^^^^ acid, our author was induced to attend particularly tojc^iican fe- tliis circumftance.. Having therefore tried the com-parate mon folution with mineral alkah, he found that each drop P^^-"\^ ^ ^ excited a violent efi'ervefcence, and at lafl: that a y<^l" veut"'^ ^'^ low fpongy matter, affording a genuine calx of pla- tina, was precipitated: this was more fpeedily efFected by ufing the dry mineral alkali, which had fallen to powder of itfelf. To determine, however, the dif- ference betwixt the two alkalies in a more accurate manner, he divided a very acid folution of platina in- to two equal parts. To one of thefe he added fmall portions of the vegetable, and to the other an equal weight of pieces of mineral alkali, waiting five mi- nutes after eveiy addition, till the effervefcence Tnould fully ceafe. After the firft addition, fmall cryftals ap- peared; in the former partly on the furface, and partly pj|-j^j''_^j^' in the bottom ; but in the latter no precipitate could rmies as be obferved until 56 times the quantity of vegetable ri^uch mi- alkali had been added. The difference, however, was"""! ^'j^'' even greater than what appears from this experiment ; prec.pi-ate* for the vegetable alkali was cryftallized, and therefore platina as of. charged with, the water neceffary to its cryftalHne vegetable form i Platina. form Iffeas of tlic volatile allcali. 1331 latina C H E M whereas tKc mineral alkali was fpontaneoufly calcined : and though, in equal quantities of thefe two alkalies, the purely alkaline parts are as 3 to 2, yet three parts of vegetable alkali faturated only 1.7 1 of this aqua-regia, while two of the mineral alkali took up about 2.6. The volatile alkali firft throws down this metal in a faliue form ; the grains fometimes diftinftly oSto- hedral. Their colour is red when that of the folution is fo, hut yellow when the folution is more dilute. After faturating. the fuperabundant acid, the fame al- kali precipitates the platina truly calcined. This pre- cipitate is dilTolved in water, though with difficulty, and may be reduced to more regular cryftals by eva- poration. Thefe are dilTolved by the mineral alkali; but hardly any figns of decompofition are to be ob- ferved, unlefs the yellow folution, evaporated to dry- nefs, be again diffolved in water ; for then the metal- lic calx rells at the bottom, and the folution is de- prived of its yellow colour. The vegetable alkali has fcarce any e&€t in this way ; for, after repeated ex- ficcation, the folution remains clear and yellow: but here probably the fixed alkali takes the place of the volatile ; for in larger quantities, and efpecially when the cauftic vegetable alkali is made ufe of, the mixture fmells of volatile alkali. The volatile alkali, faturated with any acid, pre- partly pre- cipitates the platina in the fame manner as the vege- cipirared by j.,^^^ alkali in combination with acids: but thefe neu- neutral ■• 1 1 -i • r 1 falts. tral falts precipitate only a determnied quantity 01 pla- tina; for after their effedl has ceafcd, the liquor lets fall a pure calx of platina on the addition of vegetable j^^^ or volatile alkali. Triple falts The calx of platina precipitated by mineral alkali, formed by and then duTolved in any fimple acid, Ihows nearly the tins metal, {^^^ phenomena with volatile alkali as with the vege- table alkali. " Whence (fays Mr Bergman) we may conclude, that platina dllTolved in acids forms at firft, both with the volatile and fixed vegetable alkah, a triple fait,' difficult of folution, and which therefore al- moft always falls to the bottom unlefs the quantity of %vater be very large." Calcareous earth, whether ae- rated or caultic, produces the fame phenomena as the 1333 "liberal alkali, without any cryftalllne appearance. Datnia the Platina has been remarkable ever fince its firft dlf- -tioft iiifu- covery for being the moft ' infufible fubftance in the j.ibie fub- world. MelTrs Macquer and Beaume kept it in the moft violent heat of a glafs-houfe furnace for feveral days without perceiving any other alteration than that its grains adhered flightly to each other ; but the ad- hefion was fo flight that they feparated even by touch- ing. In thefe experiments the colour of the platina became brilHant by a white heat, but acquired a dull grey colour after it had been heated for a long time. They obferved alfo, that its weight was conftantly in- creafed; which undoubtedly arofe from the calcination of the iron it contained. Dr Lewis, after various at- tempts to fufe platina, found himfelf unable to fuc- ceed even in a fire which vitrified bits of glafs-houfe pcto and Heffian crucibles. MelTrs Macquer and Beaume firft melted this refraftory metal with a large burning-glafs, 22 inches diameter and 28 Inches fo- cus. The power of this fpeculum was almoft incre- dible, and far exceeded what is related of the lens of Tfchirnhaufen or the mirror of Villette. Its general I S T R Y. 5SS ■ancein the 1334 Firft melt ed by a burning mlrrsir. e^^eSts are related under the article BuRh'iKG-Glafs. Platina. And as platina refifted this intenfe heat more than fix times as long as the moft unfufible fubftances formerly known, it appears to require a fire as many times ^ ilronger to melt It. It has been found, however, ca- May^ be vl- pable not only of fufion but of vitrification by the e- t: ified by leAric fire ; and that it may alfo be melted by fire ex- electric fire, cited by dephlogiftlcated air : but M. de LIfle was the firft who was able to melt it with the heat of a com- mon forge when expofed to the blaft of a double bel- ppecipl- lows in a double crucible. Thus Its real fpeclfic gra- tate fufible vlty began firft to be known. It muft be obferved, i" a com - however, that this fufion was not performed on com- furgc. mon platina, but on fuch as had been diftblved in aqua- regia and precipitated by means of fal ammoniac. M. Morveau repeated the experiment, and from 72 grains of platina obtained a regulus weighing 504- ; which feemed to have undergone a very imperfect fu- fion ; for it did not adhere to the crucible or take its form, but feemed to be merely platina revived. Its fpe- clfic gravity was alfo found to be no more than 10.045 ; but It was nearly as malleable as filver ; and when it had been fufficlently hammered, its fpeclfic gravity was augmented to no lefs than 20.170, which is more .^337 ^ than that of gold itfelf. M. Morveau found that he '^^'J^ J" could melt the precipitate with different fluxes, fuch gye^ crude as a mixture of white glafs, borax, and charcoal, and platina, fu- a mixture of white glafs and neutral arfenlcal fait : iii^'e by tha and that the recculus thus obtained was more complete- ^^^^^ance of ly fufed, but was not malleable, and obeyed the mag- net ; but the regulus obtained without addition did not fiiow this mark of containing Iron. He alfo found, that by means of the above mentioned flux of white glafs, borax, and charcoal, he could melt crude pla- tina. Since that time the fufion of platina hjis been accompliflied by various chemlfts, and with different fluxes ; and in proportion to the degree of purity to which the metal has been reduced, its fpeclfic gravity has alfo increafed ; fo that it is now fettled at 25, that of fine gold being 1 9. Though Dr_Lewis could not accompllfti the fufion ^^j^-''-^^ of platina by the methods he attempted, he was ne- l^^-^iJ verthelefs able to alloy it with other metals. Equal with other parts of gold and platina may be melted together by metals, a violent fire, and the mixed metal formed into an ingot by pouring it into a mould. It Is whitifli, hard, and may be broken by a violent blow ; but when carefully annealed, is capable of confiderable extenfion under the hammer. Four parts of gold with one of platina form a compound much more fufible than the ^359 former, and llkewife more malleable ; fo that it may ^^^'^^ be extended into very thin plates without being bro- ken or even fpllt at the edges. Dr Lewis remarks alfo, that though In this cafe It be alloyed with fuch a quantity of white metal, It neverthelefs appears no paler than guineas ufually are, which contain only one-twelfth of filver. Equal parts of filver and platina melted together -witiffiiver, with a violent fire, form a much harder and darker- coloured mafs than filver, which has alfo a large grain, though it preferves fome du6tlllty. Seven parts of filver with one of platina form a compound much more refembling filver than the other ; but ftlU coarfer- grained and lefs white. From the experiments made on filver, however, it appears that no perfect union is 4 A 2 formed 556 C H E M Platina formed betwixt the two ; for after the mixture has ^ been kept in fu;..,n for a confiderable time, moll of the platina ftparates and Falls 1o th bottom. Lewis ob- ferved, that filver melted witli platina was thrown up with an explofion agafnfl the fides of the crucible. Silver did not appear to be in any degree meliorated by its union with this metal, excepting by the fuperior hardnefs communicated to it ; but copper fecmed to be confiderably improved. A large proportion of pla- tina. Indeed, as two-thirds or equal parts, produced an hard, brittle, and coa i fe-grained compound; but when a fmaller quantity of platina is added, as from -g-to union with Or even lels, a goklen-colouted copper is produced, platina. very malleable, harder, fufceptible of a finer polilh, fmoother- grained, and much lefs ftibjeft to calcina- 1342. tion and ri'llthan pure copper. Of all metallic matters, ho.'; ever, zinc mod readily unites with pliitira, and is iv.j{\ t-ftvciuafy dilTolved by fufton. When the pioporticn of platina is confider- able, the metal is of a biuifn colour, the grain clolcr, without tarnilliing or changing colour in the air, and they have not even the malleability of the femi- metal. Platina unites readily with the compound metals, brafs formed of copper and zinc, and bronze made of copper and tin. In the latter it was remarkable, that the compound metal took up more platina than both its ingredients feparattly can do. This compound was hard and capable of receiving a fine polilh, but is fubjeft to tarnilh. Equal parts of brafs and platina formed a compound very hard, brittle, capable of receiving a fine polilli, and not fubjedt to tarnifh. It is poffible therefore that proper ma- it might be ufed to advantage as a material for fpecu- terial^for Jums ; all materials for which, hitheito difcovered, ' ' have the great inconvenience of tarniiliing in the air, 1345 and that very quickly. Platina amjalgamates with mercury, but with much greater difficulty than gold, v,liich will alfo ft;par:'te the quickfilver after it has been united with the pla- tina. The amalgamation of platina does not fucceed but by" very long trituration of the metals with water, as for inttance a week ; but if the trituration be per- formed with a mixed metal compofed of gold and platina, the merciuy ftizes the gold, and leaves the platina untouched. Dr Lewis propofes this as a me- thod of feparating gold from platina ; and it is that ufed in Peru, where gold and platina are fometimes naturally mixed in the ore ; but we do not know whe- ther this feparation be quite complete. Mr Morveau fucceeded in uniting iron with platina^ united with though Dr Lewis could not accomplifh this. The «aif iron"*^ latter fucceeded, however, in uniting it with caft iron. ' The compound was much harder and lefs fubjeCl to ruft than pure iron. It was alfo fufceptible of a T348 much finer polifli. And with Platina may be alloyed with tin, lead, or bif- ^^^1^' ""^ muth, but without sny advantage. To lead and tin it gives the property of affuming blue, violet, or pur- ple colours, by being expofed to the atmofphere. Dr Lewis could not fucceed in uniting platiiia with i34t coni^c-er- abh id : V Uiiirc-s nio!l reaciily with zinc : 1343 ^nd ith the com- pound me 1344 The com- pound of brafs and platiii: Can fcarce be united wiih nier- tury. 1346 Mei'-ury leavesplari- na to unite with gold. 1347 May be I S T R Y. Praaice. arfenic ; but M. SchefFer affirms, that if only one- Platina, twentieth of arfenic be added to platina when red hot in a crucible, the two fubftances will be perfectly i^i^i^.^be fufed and united into a brittle grey mats. This cxpe- mcited by riment did not fucceed with Mr Margraaf ; for he, mean, of having expokd to a violent fire during aar hour a mix- -irFenic. ture of an ounce of platin i with a lufible glafs, com- pofed of eight ounces of minium, two ounces of Hints, and one ounce of white arfenic, obtaiiied a regulus of platina well united and fufed, weighing an ounce and 32 grains; the furface of which was fmooth, white, and fliining, and the internaJ parts grey ; but which neverthelefs appeared luiucitully wuite wiiea filed. The experiment lucceeded impcnettly alio in the hands of Dr Lewis; but 1.1. iouicioy Uii^.ims us, that " it has fincc been repeated, and that platina is in facl very fufible with arfenic, but that it rtinains brittle. In proportion as the arfenic .is driven oh' by the continuance of the hc<.t, the metal becomes more ductile ; and by this procels it is that M. .-ichard and M. de Morvtau fucceeded in making crucibles of pla- tina by melting it a fccond time in moulds." (a) ^^^^ M. Fourcroy feems to deny that platina can be p^urcroy united with mercury, contrary to what is mentioned denies that above. — " Platina (fays he) does not unite with rner- p'"*'"* can cury, though triturated for fcveral hours with that ^'l^^''^^^^'^^ mttallic fluid. It is likewife known, that platina re- ^ury. fills the mercury ufed in America to ieparate the gold. Many intermediums, fuch as water, ufed by Lewis and Beaumc, and aqua-regia by Scheffer, have not been found to facihtate the union of thefe two metals. In this refpeft platina feems to refemble iron, to whofe colour and hardnefs it likewife in fome meafure ap- "*proaches." This laft fentence, however, feems very litile to agree with what he himfelf had before told us of M. Macquer's experiment of melting platina. "The 135 1 melted portions (fays he) were of a white brilliant Inco fiftent colour, in the form of a button ; they could be cut to ^" ^^^^ ut'it, pieces with a knife." This furely was a very fmall ap- hardnef». proach to the hardnefs of iron ; and gives us an idea rather of the confiftence of t-.n or lead. " One of thefe malTes was flattened on the anvil, and converted into a thin plate without cracking or breaking, but it became hard under the hammer." In another expe- riment indeed the button of platina was brittle, and fuificiently hard to make deep traces in gold, copper, and even iron ; but this was obtained from precipita- ted platina urged for 35 minutes by a llrong blaft fur- nace. In an experiment of this kind M. Beaume even precipita- fucceeded in melting the precipitate, along with cer- ted platina tain fluxes, into a vitriform iiibilance by two different '^"^'"'fis'^ procelfes. The precipitate of platina, mixed with calcined borax, and a very fufible white glafs, was ex- pofed, for 36 hours, in the hotteft part of a potter's furnace ; and afibrded a greenilh glafs, inclining to yellow, without globules of reduced metal. This glafs, treated a fecond time with cream of tartar, gypfum, and vegetable alkali, was completely melted, and ex- hibited globules of platina diiperfed through its fub- ftance. M. Beaume feparated them by wafhing, and found them dudile. The fame chemiil afterwards, to- gether M Beaume, (a) For a particular account of this procefs fee before no 587. Pra(^ice. Platina. 1353 Pi-ccipitP.ic by fal ani- irionlac fu- Jicat. Macquer ridt to be perfeft. C H E M I ^ether witli M. Macquer, expofed precipitate of pla- tina to the fame burning mirrcrr with which they had fufed the metal : the precipitate exhaled a ver>' thick and l iminous fume, with a ftrong l'^. :!! of aqua-re;rta : it \oil its red colour, refumed that of pl.itlna, and rn It- ed into a perfect brill ant button, which was foiind to be an opaque vitreous fubftancc, of an hyacuitluue co- lour at its furface, and bhickifh within ; and may be confinered as ^ true glafs of platina. It may however ^ be obferved, that the faline matters with which it was * impregnated contributed doubtlefs to its vitrifica- " The orange coloured precipitate obtained by pour- intr a folution of fal ammoniac into a h lution of pla- tina, appears to bt a faline fubftance entirely foluble in water. This ptecipitati; has a valuable pioptrty, d.fcovcred by M. de i'lne, viz. tliat it isiufible without addition iu a i{ood furnace or common f'oi-ge-heat. The platina meUcd by this proccfs is a brilliant, denfe, and - - cU.fe-graiiicd button ; but it is not ma]l. able imlels it 'b^'^^'S^has been expofed to a very llrong heat. Macquer thinks that this fnHon, like that of the grains of 1354 platina alone, expofrd to the adion of a violent fire, This'fufum conf.fts only in the agglutination of the foftened par- fuvpofcd by^j^i^.g . vvhich being exceedingly more divided and mi- nute than the grains of platina, adhere to and touch each other in a greater number of points than the grains ; and in that manner render the texture of the metal much more denfe, though no true fufion may have taken place. It feems, however, that if platina in grains be capable of fufion by the burning-glals, and of becoming': confiderably dudile, the precipitate of this metal formed by fal ammoniac may likewife be fufcd on account of its extreme divifion ; and that its not being as dnftile as the button of platina ftifed by the- folar heat, may perhaps depend on Its retaining a part of the matter it carried down with it in precipi- tation, of which it may be poffible to deprive it by fire." . , . -rir It being fo extremely difficult to bring platina iticlt one of the firft attempts to purify it was by cupellation with lead. Thus the bafer metals would be fcorified ; and, running through the crucible along with the lead, leave the platina in as great puiity as though it had been melted by itfelf. This operation, hov" ever, was fonnd almoft equally difficult with tlje fufion of the metal by .itfelf. Lewis tailed in the ex- periment, though he applied the moR violent heat of the ordinary cupelhng furnacen. The vitrification and abforption of the lead indeed took place as" ufual ; but in a fliott time the platina became fixc-d, and could not by any means be rendered fluid. MclTrs Macquer and Beaume fucceedcd by expofing an ounce of pla- tina with two ounces of lead in the hottell part of a porcelain furnace, where the fire is continued for 50 hours without intermiffion. At the end of the opera- tion the platina was flattened in the cupel ; its upper fill-face was dull and rough, and eafily feparaied ; but its under furface was brilliant, and it was found eahly to extend under the liammer ; and on every chemical trial was found to be perftftly pure, without any mix- ture of lead. M. de Morveau hkewife fucceeded in cupelling a mixture of one drachm of pluina and two drachms of lead in M. Macquer's wind furnace. The operation lafted eleven or twelve hoursj and a button 1355 Attempt^^o.^^^ f^^, y unty 1 w- tinaby cu- j.tllation. S T R Y. of platina wis obtained which did not adhere to the cupel, was unifo-m, though rather rough, and of a colour refciiii'ling tin. Ii weighed exactly one drachm, and was not at ' all naed upon by the magnet. Thus It appears that platina may be obtained in plated or la- niiiiiE, wiiich may be foiged, and confc^^uently may be employed in making very vaiuable utenfils ; and this the more efpecially as Mr Beaume has obferved that different pieces of it may be welded and forged like iron. After having heated two pieces of pure cupel- led platina to whicenefs, he phc.ed them one upon the other, and llriking them bnlkly u.th a hammer, found that they united together a^ quickly and fiimly as two pieces of iron would have done. _ ^^^^ The p-reat fpecific gravity of platina has rendered it of fhe pof- a very defiiable matter tor fuch ao wifli to a.iulterate frnlity of the precious metal, and can procure the platina eafi!} . This, however, can only be done in South Ain< rica, ^^ j^^^y^'^, where platina is met with in plenty. In Europe the na. fcarcity of platina renders it a more valuable objeil 'than even It.e gold itfelf. Fears of this fraud, hmv- ever, have undoubtedly given occafion to the prohibi- tion of exporting^it. There are g-eat differences a- mong chemiils concerning the quantity of platina that can be mixed with gold without dcilroying the colour of the latter. Dr Lewis, as has already been obfer- ved, ififorms us, that four parts of platina may be mixed with one of gold, and yet the mixture be no paler than that for guineas ; while Fourcroy afferts, that it greatly alters the colour of the metal, unlefs its quantity be very fmall i thus, for example, a 47th part of platina, and all the proportions below that, do not greatly affeft the colour of the gold." But whe- ther this be the cafe or not, chemiitry has aftbrded va- rious wa^s of fepaiatin;^- even the fraalleft propor- tion of platina fro :) gold ; fo that there is now no reafon to prohibit the importation of it to Europe, more than that of any other metal with which gold can be alloyed The following are the methods by T35T which the platina may be molt readily discovered : J^^'^J^^^^^^ I. By amalgamating the fufpefted metal with mercury, f^aud and grinding the mixture for a confiderable time with if it (hould water ; by which the platina will be left, and the goldbcpradi- remain united with the quickfilver. 2. By dilTolving i^d. a little of it in aqua regia, and precipitating with al- kaline fidt ; the remaining liquor, in cafe the metal has been adulterated with platina, will be fo yellow, that it is I'uppofed a mixture of one thoufandth pare would thus be found out. 3. By precipitation with fal ammoniac, which throws down the platina but not the gold. If mineral alkali be ufed, the gold will be precipitated, but not the platina, unlets tfie precipitant is in very large quantity. 4. By precipitation with green vitriol, which throws down the gold, and leaves the platina united with the menflruum. j^..,^ All thefe method?, however, are not only attended pktina with a confiderable deal of trouble, but in fome cates, moll eafiljr- for inllance in fufpet^ed coin, it might not be '^I'gi'^le a^'^'f^' by';^ to ufe them. The hydroftatic balance alone affords a^^^.^^^ j-^^^j^ certain method of difcovering mixtures of metals with- fie giavitT, out hurting the texture of their parts. The great fpecific gravity of platina would very readily difcover it if mixed with gold in any niodcrate quantity ; and even in the fmallett, the gravity of the mats could ne- ver be Itfs than that of the pureil gold ; which cir» cumilancc: 55^ C H E M Manganefccumftance atone, as gold is never worked without al- ^ loy, would be fufficient to create a jufl fufpiclon ; af- ter which feme of the methods already mentioned might be tried. It is pofPible, however, that the hard- nefs and duftility of platina might render it more pro- per for alloying gold than even copper or fdver, ufually made ufs of for this purpofe. >359 . New fenii- metal af- forded by niangaiiei'e 1560 Properties of the com- mon man- ganefe trea ted with vitriolic acid. 1361 Entirely diffolved. by phlogiftica- ted vitrio- lic acid. ^15. 0/ Manganese. This fubflance is now difcovered to afford a femi- metal different from all others, and llkewife to pofTefs fome other properties of a very fingular kind. Mr Scheele has invefliigated its nature with the utmoft care; and the refult of his inquiries are as follows : 1. Two drachms of levigated manganefe, digefted for feveral days in a diluted vitriolic acid, did not ap- pear to be diffolved or diminifhed in quantity ; never- thelefs a yellowifli white precipitate was procured by faturating the acid with fixed alkali. The remaining manganefe was not aftcd upon by more of the fame acid, but the addition of another half ounce nearly dellroyed the acidity of the menftruura when boiled upon it. 2. With concentrated vitriolic acid an ounce of manganefe was reduced to a mafs like honey, and then expofed to the fire in a retort till it became red-hot. Some vitriolic acid came over into the receiver ; and after breaking the retort, a mafs was found in it weighing iz^ drachms, hard and white in the in- fide, but red on the outfide. A great part of it dif- ffjlved in diRilled water, on the affufion of which at firft it became very hot. The refiduum after edulco- r^tion weighed a drachm and an half, and was ©f a grey colour. Being calcined in a crucible with con- centrated vitriolic acid till no more vapours arofe, it was all diffolved by water excepting one drachm ; which being again calcined with the fame acid, an in- foluble refiduum of a white colour, and weighing on- ly half a drachm, remained. This white refiduum effervefced with borax, and melted into a tranfparent brown glafs ; it likewife effervefced with fixed alkali, changing into a brown mafs, which yielded an hepatic fmell with acids, and became at the fame time gela- tinous. The folution obtained by calcination was eva- porated and fet to cryflallize. A few fmall cryftals of felenite were firft depofited, and afterwards lome very fine large cryftals of an oblique parallelopiped form, whofe number increafed as long as there was any liquid left. They tailed like Epfom fait, and Mr Weflfeld fuppofes them to be alum ; but according to Mr Scheele, they have no other refemblance to alum than that they contain the yitriolic acid. 3. By phlogifticated vitriolic acid the manganefe was entirely diffolved. To procure this acid in puri- ty, Mr Scheele dipped fome rags in a folution of al- kali of tartar, and after faturating them with the fumes of burning brim/lone, put them into a retort, pouring on them fome diffolved acid of tartar, luting on a receiver which contained levigated manganefe and water. After a warm digeftion of only one day, the liquid of the receiver had become as clear as water, and a little fine powder, confifting principally of lili- ceouG earth, fell to the bottom. 4. Two drachms of levigated manganefe, digefted I S T R Y. Praaicei for feveral days with an ounce of pure colourlcfs acid Manganeft of nitre, did not appear to have deprived the men- v"*— ftruum of its acidity, or to have been affeded by it in any degree. The liquor being diftilled off, and the produd of the diflillation ;poured back on the refi- duum, a fmall quantity of it was diffolved. By a third difi illation, and pouring back the liquor on the refiduum, a complete folution was effefted ; and this quantity of acid appeared capable of diffolving nine "drachms of the pov/der, 5. The folution of manganefe thus faturated, was p,. ^^^-^ filte. ed and divided into two equal portions. Into one and'^cfyftak of thefe fome drops of vitriolic acid were poured, by obtained which a fine white powder was thrown down, which, '^^°"\'^« however, did not fettle to the bottom for fome hours. It was foluble neither in boiling water nor in acids. The limpid folution, b)-^ evaporation, yielded fome fmall cryftals of felenite or gypfum. 6. From the other half of this folution, after eva- poration by a gentle heat, about ten grains of fmall fhining cryftals of a bitter tafte were obtained. On pouring fome drops of vitriolic acid into the folution infpiffated^ by a gentle heat, no precipitation, except- ing of a little felenite, enfued ; but as foon as it was infpiffated to the confiftence of honey, fome fine aci- cular cryftals, verging towards tlie fame centre, began to form, but grew foft, and deliquefced in a few days after. 7. Phlogifticated nitrous acid diffolves manganefe jyia'nl^. r as readily as the phlogifticated vitrioHc. A little le- diffi"ved by vigated manganefe mixed with fome water was put in- I'hlogiftica- to a large receiver, to which a tubulated retort was "itrous luted. Some ounces of common nitrous acid were^"*^* put into the retort, to which fome iron-filings were added, taking care always to clofe the orifice with a glafs ftopple.^ The phlogifticated nitrous acid thus paffed over into the receiver, and diffolved the man- ganefe in a few hours : the folution was as limpid as water, excepting only a little fine filiceous earth. An- other white precipitate, fimilar to that produced by adding vitriolic acid to the folution in pure nitrous acid, now began to fall ; but in other refpefts this fo- lution agreed with the former. 8. An ounce of purified muriatic acid was poured p,„ ^^^^ upon half an ounce of levigated manganefe; which, jtonfj^it after ftanding about an hour, affumed a dark brown of fait, colour. A portion of it was digefted with heat in an open glafs veffel, and fmelled like warm aqua regia. In a quarter of an hour the fmell was gone, and the folution became clear and colourlefs. The reft' of the brown folution being digefted, to fee whether the mu- ' riatic acid would be faturated with manganefe, an ef- fervefcence enfued, with a ftrong fmell of aqua regia, which lafted till next day, when the folution was found to be faturated. Another ounce of acid was poured '3^5 upon the refiduum, which was followed by the fame ^ phenomenon, and the manganefe was entirely diflblved, fjis alid a fmall quantity of filiceous earth only remaining. The folution, which was yellow, being now divided into two portions, fome drops of vitriohc acid were poured into the one, by which it inftantly became white, and a fine powder, infoluble in water, was pre- cipitated. Some fmall cryftals of felenite were form- ed by evaporation, and the refiduum exhibited the fame phenomenon with thofe above mentioned with ni- 3 troH8 radice. CHEMISTRY. 559 [anganefe. trous acid. By evaporating the other half, fome fmall flilning angular cryllals were obtained, fimilar to thofe procured by means of the nitrous acid. 1 o. Very little manganefe was diffolved by fluor acid, arce folu- y ; i , t n- a ^ 4.-^ e in fluor even after feveral days digeftion. A great quantity :id. was required to form a foturated foliition. It liad very little tafte, and gave a fmall quantity of precipitate with fixed alkali. But if a neutral fait, corapofed of fluor acid and fal ammoniac, be added, a double de- compofition takes place, and the manganefe is preci- pitated along with the fluor acid. 10. A drachm of phofphoric acid digefled with as iVr in pliof- much powdered manganefe, diflblved but little of it ; ihoric acid, and, though evaporated to drynefs, the refiduum tailed very acid ; but by adding more manganefe the acid was at laft faturated. On adding microcofmic fait to a folution of manganefe, a decompofition takes place fimilar to that effefted by the combination of fluor acid and volatile alkali. 1 1 . Pure acid of tartar difiblved manganefe partly . , , : . , in the cold, and more cfFeftually by means of heat. If taru^." The whole, however, could not be diffolved, though the acid was at lafl; faturated by adding a great quan- tity of the mineral. On adding a folution of foluble tartar, a double decompofition took place. ,.'^'^9 _ 12. Little was difiblved by diftilled vinegar, though Sy in the^o'^ed on manganefe ; bat a'fter diltilling fpirit of ver- icetous. digris feveral times upon it, the acid at. lafl; became fjiturated. The folution, evaporated to drynefs, left a deliquefcent mafs. Little or none of the remaining manganefe was difiblved by concentrated vinegar, though repeatedly diiliiled upon it. 13. With acid of lemons the whole was difiblved ^ 1368 Partly fo \^7° _^ iffolvedby with effervefcence, excepting only fome white earth. 14. Water impregnated with fixed air like wife dif- folved manganefe, but parted with it on the addi- tion of alkali, or fpontaneoufly by expofure to the air. From thefe experiments Mr Scheele concludes, that manganefe has a ftrong eleftive attradlion for all phlo- giftic fubftances; and that this attraftion becomes a ftrong Stronger, if there be prefentamenfl:ruum which can unite ittradion with the phlogiflicated manganefe. Thus it attrafts phlogifton more powerfully than even the nitrous acid itfelf in the moift way. By faturation with phlogi- fi:on, manganefe has the property of lofing its black colour, and afi'uming a white one, which is unufual, the phlogifton generally ^ communicating a black or dark colour to the fubftances with which it was united. KniL«i:.» That manganefe naturally contains fome phbgifton, ome i hlo- though but in fmall quantity, appears from evapora- jil'Uin 11a- ^ folution of it in vitriolic acid to drynefs, and then diftilling the rnafs in a glafs retort in an open fire. When the retort begins to melt, the acid parts fly off^ from the manganefe in a fulphuieous ftate, leaving the former of its natural black colour. By diftilling the mafs remaining after evaporation of the nitrous folu- tion, a green volatile nitrous acid remains, and the black calx of manganefe remains as before. A folu- tion of this mineral in vitriolic or nitrous acid, preci- iecomesin- P'^^t^'i by fixed alkali, retains its colour ; but when )lub]e in calcined in the open fire, again becomes black, lire acids By lofing its phlogifton, manganefe becomes info- y ^°^!J||^g'^^luble in pure acids j and therefore the refiduum of the ;id of le- 10ns ; 1371 Lnd by- rater im- pregnated pvitii fixed 137* [or p!ilogi- ;on. >373 'ecomes ■hite by itiiration :t}i (hlogiflon. 1374 lontains above mentioned diftillatlons cannot be difiblved by Manga^iefe. adding more of the vitriolic or nirous acids : but if that " ^ which has come over into the receiver be poured back into the retort, a folution will again take place by rea- fon of the manganefe refuming the phlogifton it had parted with to the acid. On t]iis principle our author explains the reafon of p^^j-jf^'ic^ji^j. the partial folutions of this mineral above mentioned. tio;;s of Part of it is difi'olved, for inftance in the vitriolic acid, manganefe while the remainder is found infoluble. This happens "^'i^igp^ij^. (fays he), " becaufethe undifi"olved portion has parted, j,,;^^ with the little phlogifton it naturally poflefled to that portion of manganefe which is taken up by the vitri- olic acid during the firft digeftion ; for without that principle it is infoluble. " Manganefe attrafts phlogifton more ftrongly when combined with fome acid than by itfelf, as appears from the following experiments. 1377 1. Levigated manganefe, digefted or boiled with a SLronj^at- folution of fugar, honey, gum Arabic,_hdrtlhorn, jelly, J^'^^^^^^^^^^^^ &c. remains unchanged ; but on mixing the pounded mineral with diluted vitriolic, or pure nitrous acid, and bi'ieJ with then adding fome of thefe fubftances, the whole is dif- acids for folved, the black colour vaniflies by degrees, and the phlo^aton. folution becomes as limpid as water. So ftrong is the attra£lion of manganefe for phlogifton in thefe circum- ftances, that metals, the noble ones not excepted, ren- ,^^,3 der it foluble in thefe acids in a Hmpid form. Con- WJiy the ccntrated vitriolic acid, indeed, difiblves manganefe to^.ccnira- entirely without any phlogifton. " It would be v^tj.io*i\iif, cult (fays Mr Scheele) to comprehend whence the foi^.g ^^^n*- phlogifton in this cafe fiiould come, if we were notganefe certain that feveral fubftances, which have a great without attraftion for phlogifton, can attraft it in a red heat. Quickfilver andjilver, when diflblved in the pureil ni- trous acid, really lofc their phlogifton, which is a con- ftituent part of thefe metals. This appears from the red vapours in which the acid arifes ; and the dif- folved metallic earth cannot be again reduced to its . metallic form, till it has acquired the loft phlogifton, which is effe£led either by precipitation with complete metals or by heat alone. Thus manganefe can attradl- the quantity of phlogifton neceflary for its folution by means of concentrated vitriolic acid from heat. II; i^i not probable that the ccncentrated acid undergoes a decompofition in this degree of fire ; for if you fatu- rate half an ounce of this acid with alkali of tartar, and afterwards calcine in a retort, with a receiver ap- plied, an ounce and a half of powdered manganefe, with an equal quantity of the fame vitriolic acid, then dilTolve the calcined mafs in diftilled water, and like- wife wafti well the receiver, which contains fome drops of vitriolic acid, which are alfo to be added to the lo- lution, and lallly add the fame quantity of alkali, there will be no mark of fuperabundant acid or alkali. Thence it may be concluded, that the phlogiilon in the vitriolic acid, if there really exifts any in it, con- tributes nothing to the folution. But the manganeie precipitated by alkali contains a confiderable quantity of it; in confequence of which it is afterwards entirely foluble in acids without any addition. " The cfFefts of volatile fulphureous acid on manga- -^j^^^^j^g nefe, clearly prove what has been afTerted. The man- volatile ful= ganefe attracts the phlogifton contained in this acid, 1 hureous which is the caufe of its great volatility, and which ^"^."^ "^i^" renders. 56o C H E M 1380 EfFeds of i;itrpus acid on manga- iiefe ex- |)laincd. Manganefe. j-enders tlie former foluhle in the new pure vitriolic acid. If this fohition be mixed with concentrated vi- triolic acid and diililled, no volatile fulphureous acid is obtained ; and if it be precipitated by means of fix- ed vegetable alkali, vitrioiated tartar is obtained ; which proves that manganefe has a ftronger attraction than vitriolic acid /or phlogifton in the moift way. " The efFefts of nitrous acid on this fubftance are fimilar to thofe of vitriolic acid. Could fpirit of nitre fuftain as great a degree of heat as the concentrated vitriolic acid, it would alfo entirely diflblye the man- ganefe by means of the phlogifton attracted by heat ; but as this is not the cafe, it is necelfary to add phlo- gifton in the manner above mentioned. The manga- nefe decompofes phlogifticated nitrous acid, for the fame reafon that it does the volatile fulphureous acid ; and that the phlogifton of this acid really combines with the manganefe, is manifeft from this, that the af- fufion of vegetable acid produces no fmell of aquafortis by difplacing the phlogifticated acid of nitre. By di- flillation with pure vitriolic acid alfo, the nitrous acid is expelled, not in a fmoking ftate, and of a yellow colour, but pure and colourlefs. *' In the folutlon of manganefe by means of gum ara- bic or fugar, a very confiderable effervefcence takes place, owing to the extrication, or probably rather the production, of fixed air from the mixture ; but with phlogifticated acid of nitre no fuch phenomenon takes place, becaufe the manganefe is combined with pure phlogifton ; and if this (hould be again feparated, there is no caufe for the production of fixed air. This mi- neral is alfo diflblved without effei-vefcence, by uniting it with nitrous aci^ and metals, arfenic or oil of tur- pentine." Ix-Oenceof As muriatic acid dilTolves manganefe without addi- j»hlogifton tion, Mr Scheele is of opinion that this proves the inihcniu- ^xiftence of phlogifton in that acid, as has already natic acid , • r n^-i r i- n ■, ■ been taken notice or. ihe manganele digcited m the cold with fpirit of fait alTumes a dark brown colour ; for it is a property of this fubilance that it cannot be diffolved into a colourlefs liquor without phlogifton, but has always a red or blue colour; but with fpirit of fait the folution is more brown than red, cn account of the fine particles of the manganefe float- ing in the liquid. Here the mineral adheres but loofely to the acid, fo that it may be precipitated by water. The eff"e£ts of acid of tartar and acid of lemons up- on manganefe are likewife explained on the principle already laid down, viz. the extreme attraction this fubftance has for phlogifton. Thus it attraCts part of acid of le- that naturally contained in thefe acids, decompofing snons. pjjj.^. q£ j-j^gffj^ and being diffolved by the other. This deftruCtion of the acid is fimilar to that of the fugar, gum arable, &c. which render it foluble in nitrous acid ; for if a proper quantity of thefe are added, the manganefe will be diffolved, without a pof- fibility of recovering the fmalleft particle of the vege- table fubftances employed ; and if the folution be flow- ly evaporated and cakintd, there will not remain .the fmalleft mark of burned fugar or gum. During this decompcfition, a pungent vapour arifes, which, being collected, appears to be true vinegar. It is obtained in its purcft ftate from diluted vitriolic acid, fugar, and ,38^ manganefe.^ Of fluor Fhioj acid diffolves but very little manganefe, owing to its preelrltating a fait vi^hich envelopes the particles N Joved. 138a Explana- tiou of the adtion >'{ aeid of t?.r tar and I S T R Y. Praaice, of miiigniii fe, and prevents the further acllon of the Manga^iefc. menftruum. In all precipitations of m.inganefe, how- v— — ever, by means of mild fixed alkalies, the full quantity is not procured ; becaufe the fixed air, detached from the mineral, diffolves part of it. ^^g^ Though manganefe decompound? nitre, yet this EfTecls of does not happen till the mixture becomes red-hot. If mantrancfs phlogifticated manganefe be mixed with an equal quan- tity of nitre, and dift lied in a glafs retort, the mix- ture begins to grow black before the retort becomes red-hot, but no nitrous acid goes over. By lixivia- tion, no mark of uncombined alkali is met with ; but phlogifticated nitrous acid is extricated by the appli- cation of tamarinds, or any vegetable acid. Three parts of phlogifticated m.anganefe, mixed with one part of finely pounded nitre, yields no nitrous acid, though the nitre is alkalized as foon as the mixture becomes black in the retort. Mr Scheele proceeds now to another fet of experi- ^^l^f^^ ments upon manganefe united with phlogifton. In niev.t' on order to procure it in this ftate, the bcit method is to n-iantnmcle diffolve in diftilled water, and cryftallize the fait ob- "i'''^'' tained by folution of manganefe in vitriolic acid, and then precipitate it with vegetable fixed alkali. In this ftate it is white like chalk ; but by calcination in an open fire, the fuperfluous phlogifton flies off, and the calx regains its ufual black colour. This change of colour likewife happens when the precipitation is made with cauftic alkalies, whether fixed or volatile. The pre- cipitate, indeed, in this cafe, is white when kept ciofe from the air, but affumes a brown colour when e.xpo- led to it for any time : But when the precipitation is made by mild alkali, the white colour is preferved by the fixed air, which in this cafe it alfo contains. By diluting the folution with a confiderable quantity of water, and precipitating with cauftic alkali, the pre- cipitate is brown fiom the very beginning, owing to the air in the liquid attracting the phlogiilon from the manganefe. I'he precipitate formed by lime-water is alfo brown ; but on adding more of a ftronp- folutioa ot manganefe, and afterwards precipitating \vith cau- ftic alkali, the powder falls' of a white colour ; becaufe the air, being ajeady faturated with phlogifton, ean- not take up any more. The refults of Mr Scheele's experiments on this phlogifticated mdnganefe are, j,g^ 1. An ounce of this fubftance dift died by itfelf By d'-ftilla^ in a glafs retort, with a ftrong fire, yielded a great t»on /f y'' quantity of fixed air with fome drops of water. The refiduuni poured warm out of the retort grew red-hot, and let the paper on fire. 2. On repeating the experiment with only a drachm of phlogifticated manganefe, and tying a bladder to the neck of the retort, three ounce-meafures of air came over : the refiduuni was of a light grey colour ; diffolved in acids without addition of any n>ore phlo- gifton ; and took fire in that degree of heat in which fulphur fmokcs, but does not burn. From thefe expe- riments, fays Mr Scheele, it is evident, that phlogifton does Hot feparate from manganefe if the accefs of air be prevented. 3. One part of finely powdered manganefe boiled i" Boj^'^d with four of oIl-o"ive, effervefced violently, and diffolved oil olive, into a kind of falve. 4. On diftilling a mixture of finely powdered man- B .'^jj^j-iUj. ganefe and charcoal, with an empty bladder tied ta the ; ion with mou'ih of the relort, a quantity of fixed air was extri- '^''arcoal. cated Pradice. C H E M I S T II Y. 1390 By calcina- tion with catcd when tlic retort began to melt and diftended the bladder. The refiduum was moftly foluble in diluted vitriolic acid. 5. On diftilliiig half an ounce of powdered manga- nefe with two drachms of fu'phur, the latter partly rofe into the neck of the retort, and fome volatile acid vapours penetrated tlu-ough tlie hite. The diib'l- lation was continued till the retort began to melt; and, on cooling, the reliduum was found to weigh 54-drachms. It wasof a yellowiih-grey colour; anddiflblved in fpirit of vitriol with cffervefcence, yielded an hepatic fmcll, fome fulphur being alfo precipitated at the (imie time. By calcination in the open air, the fulphur was difii- pated ; but great part of tlie mafs was rendered foluble on account of its having been penetrated by the acid vapour, and fliot into cryftals as though it had been formaliy diffolved in volatile fulphurcous acid; and by repeating the calcination with more fulphur, the whole became at laft entirely foluble, and was reduced to cryftals. Finely powdered manganefe, triturated with nitre, and ftrongly calcined in a rrucible, unites with the alkali of the nitre, while the acid is diffipated in the air. The mafs formed by the union of the manganefe and alkali is of a dark green colour, and foluble in water, communicating alfo a green colour to the liquid ; but in a fhort time a fine yellow powder (an ochre of iron) falls to the bottom, leaving the liquor of a blue colour. By the addition of water, this fohition firft afTumes a violet colour, grows afterwards red, and a precipita- tion of tlve manganefe takes place, which rcfumes its natural colour as foon as it has fallen. The fame pre- cipitation takes place on the addition of a few drops of acid, or by expofure for fome days to the open air. A* for the dark red colour alTumed by the folution when the precipitate is about to fall, Mr Scheele con- jeftures that the particles of manganefe may naturally have a red colour, which becomes vifible when the fub- ftance is difperfed through a menftruum without being perfcftly diffolved. 7. By the addition of finely powdered white arfe* nic to the alkaline mafs^of nitre and manganefe, the green colour difappeais, and the whole becomes white; phlogifticated manganefe being alfo precipitated on the addition of water. This arifes from the more power- ful attradlion of manganefe for the phlogifton of the arfenic than that of the arfenical acid itfelf ; and for the fame reafon, if the mafs be calcined with charcoal, or any otlier phlogillic fubftance, a colourlefs folution will be obtained. 8. Half an ounce of phlogifticated manganefe, di- ftilled in a retort with an equal quantity of powdered fal ammoniac, yielded firft a concrete volatile fait, after which fome fal ammoniac undecompofed arofe in the neck of the retort. Half an ounce of pure dephlogi- fticated manganefe, mixed with two drachms of pow- dered fal ammoniac, yielded a!kali in its cauftic ftate. Both refiduums were foluble in water ; which Ihows that manganefe attracts phlogifton from the volatile alkah. 9. On digefting finely powdered manganefe for fome weeks with pure nitrous acid and fume volatile alkali, a great number of air-bubbles rife to the t(;p, and the volatile alkali is entirely decompofed ; for though the Vol. IV. Part II. 561 mixture be afterwards diftlUed in a retort with the ad- Minga- dition of quicklime, not the leaft urinous fmell can be ^ , perceived. This decompofition is effefted by the man- y^'^j^ ganefe attrading the phlogifton of the volatile alkali ; ^''oliitile for that the nitrous ac'd has no fiure in this, is proved al':;'!' de- by the following? experiment. ftroyed bv 10. An ounce of well triiurated manganefe was di- ajfj-aclino- ftilled with half an ounce of fal ammoniac ; and a li- its ph.lo- quid alkali, fuch as that obtained from fa^ ammoniac gif^o"' and quicklime, was procured. On repeating this ex- periment, with the variation only of a bladder inftead of a receiver, the fame kind of air was obtained as that which rifes to the top of the nitrous mixture. Though th? emifilou of this air indicated a deftrudion of the volatile alka'i, our author explains the reafon of its being ftill obtained in a cauftic ftate by the phlogi- fton taken from the alkaU being more than fufficient to render the alkali foluble in muriatic acid ; in confe- quence of whicji, the fuperfluous quant'ty combines with the manpanefe, and enables it to decompofe the fal ammoniac in the ordinary way. It muft be owned, however, that his reafoning on thl^ fubjeci is not en- tirely fatisfaftory, nor does the account he gives of his experiments feem entire'y confiftent with itfelf. See Schseles Chew. Efuys, Effay V. § xxxix. 139? 11. Powdered manganefe, diftilled with an equal clirWIa- quantity of white arfenic, underwent no change, the J^'^^*^ arfenic flying off in its proper form ; but with a^ equal*" quantity of yellow orpiment, fome volatile fulphureoas acid came over firft, then a yellow fublimate, and at laft a little red fublimate arofe. On augmenting the fire by degrees, the orpiment remained obftinately at- tached to it. Similar effefts enfued on treating m^ n- ganefe wich an equal quantity of antimony; which hkewife yielded- a pungent fu^phureous acid, but no fublimate. By calcination in the open air thtfe com- pounds are decompofed ; and the manganefe, united with vitriolic acid, becomes foluble in water. 12. On diftilling manganefe with an equal quantity vvth cin* of finely pounded cinnabar, a volatile fulphureous acidnabar. came over firft ; then a 'ittle cinnabar was fublimed in- to the neck of the retort ; and at laft the quick filver, which had been the bafis of the cinnabar, began to diftil : the refiduum, being a combination of manga- nefe and fulphur, was fimilar to the compounds al- ready defcribed. . 1^07 13. With an equal quantity of corrofive fublimate, With cor- manganefe underwent no change; but when fublimed """^'ve fub- with an equal quantity of mercurius dulcis, a corrofive fublimate, and then mercurius dulcis, arofe into the neck of the retort. The reafon of this is, that the mercurius dulcis contains a portion of phlogifton ; by being deprived of which it ceafes to be mercurius dul- cis, and becomes corrofive fublimate : but by reafon of the ftroiig attraction of manganefe for phlogifton, the mercurius dulcis parts with that portion Vv^hich is neceffary to keep it in its mild ftate, and thus is con» verted into conofive mercury. Sect. IV. Inflammable Sub/lances. These may he divided into the following claffes : QgJJffj I. Sulphurs. 2. Ardent fpirits. 3. Oils and fats. vifion.^ 4. Refins. 5. Bitumens ; and, 6. Charcoal. § I. SUL' 3ul]>liur, 1400 Cryftaliiza' tson. 1401 Decumpo- fed by a fuperabun- dance of phlogilton. C H E M I § I, Svi.FHURS. I. Cotnmon fulphur. For the extra»^lion of this fuljjlance from its ores, fee Sulphur. The artificial compofition of it we have already related, n"^ 715 ; and have now only to take notice of a very few of its properties, which come more properly under this fec- tion. Sulphur, as commonly vifed in commerce and the arts, is of a pale yellow colour, of a difagreeable and peculiar fmell, which is rendered more fenfible when it is heated or rubbed. By rubbing, it receives very curious eleftricai qualities : (See Electricity.) Its fpecific gravity is confiderably greater than that of water, though lefs than earths or ftones. In clofe vefTcls, fulphur is incapable of receiving any alteration. It melts with a very gentle heat ; and then is fublimed, adhering to the capital in fmall, veiy fine, needle-like cryftals, called Jloivers of fulphur. It may thus be fub- limed many times without alteration. If fulphur is expofed to a heat barely fufiicient to melt it, and very flowly cooled, it cryftallizes in form of many needles crofling one another. Some of thefe pointed cryftals may alfo be obferved in the interior parts of the luir'^is of fulphur which have been meUed, and caft into cy- lindrical moulds, as they are commonly fold; becaufe the centre of thefe cylindrical rolls is more flowly cooled than the furface. Sulphur alfo gives thisneedle- I'kc form to cinnabar, antimony, and many other mi- nerals containing it. Sulphur may be decompofcd in feveral ways. The moft firaple is by burning ; which we have already taken notice of, n° 623. It may alfo be very effeftually decompofed by mixing it with iron filings and water. In this cafe the phlogifton is diffipated, and the acid uniting with the iron forms a green vittipl. It is veVy remarkable, that though fulphur is com- pofed of vitriolic acid and phlogifton, yet the addition of more inflammable matter, fo far from making the union ftronger, weakens it to a great degree : and hence we have another method of decompoflng this fubftance ; namely, by combining it with a large quan- tity of oil, and diftilling the compound. Sulphur is capable of being eafily diflblved in ex- prefled oils, but very difficultly in eflential ones. Thefe compofitions are called balfams of fulphur; and are fometimes employed in medicine, but are found to be of a very heating nature. They are much ufed by farriers. According to Mr Beaume, fulphur cannot be diflblved in oil, without a heat fufiicient to melt it. A larger quantity is kept diflblved when tlie mixture is hot, than when cold ; and confequently the fulphur, efpecially If it has been diflblved in a thin eflential oil, cryftallizes on cooling the mixture. The fulphur, thus fcparated from the oil, is found not to be altered in any refpeft from what it formerly was ; but if the mixture is expofed to a degree of heat capable of en- tirely decompoflng the oil, the fulphur is decompofed along with it, and the fame produfts are obtained by diftiUing thi^ mixture to drynefs, as if a mixture of pure oil of vitriol and oil were diftilled. Thefe pro- idufts are, firft a portion of oil, when an eflential oil was made ufe of in the compofition of the balfam ; ' then fome volatile fulphureous acid, which is at firft l)it: v\ i.-.iVi> 140,-! S T R Praaice. watery, and afterwards becomes ftronger ; along with S^ip hur. ^ this acid more oil arifes, which becomes more and v— more thick towards the end of the diftillation ; and laftly, when the retort has been made red hot, noihiug remains but a fixed coal. In this procefs we find, that both the fulphur and oil are decompofed. The acid of the fulphur feems to attack the watery principle of the oil, while its phlogifton remains confounded with that ol the oil, or is diflipated in vapours. Hence, though the vitriohc acid in fulphur is concentrated to the utmoft degree, and perfe6lly free from water, what rifes in this diftil- lation is very aqueous, byrealbn of the water which it attrafts from the oiL ^ Spirit of wine does not fenfibly a6l upon fulphur la TLr.v its liquid ftate ; but if both the fpirit of wine and ful- phur meet in the ftate of vapour, they will then u- nite, and a perfeft folution will take place. By me- thods of this kind, many combinations might be ef- fected, which have been hitherto thought impoflible. Pure fulphur unites eafily with all metals; gold, Its u-nna platina, and zinc, excepted. The compounds, except ^^'^^ that with mercury, poifefs a metaUic luftre without any ducliHty. The fulphur may be feparated by ex- pofing the mixture to a ftrong fire, (fee Metal- lurgy,) or by diffolving the metalHne part in acids. The fulphur, however, defends feveral of the metals from the aftion of acids ; fo that this diflblution fuc- ceeds but imperfe£lly. The reguline part of antimo- ny is more eafily feparated from fulphur by means of acids than any other metalline fubftance. Alkaline falts will feparate the fulphur from all metals in fufion, but they unite with it themfelves, and form a com- pound equally capable of diflblving the metal. Sulphur united with quickfilver forms the beauti- 1404 ful pigment called cinnabar, or vermilion ; which is fo Vermilion > much ufed in painting, that the making of it is be- come a diftinft trade. Neuman relates, that in the ma- king of cinnabar by the Dutch method, fix or eight parts of quickfilver are made ufe of to one of fulphur. The fulphur is firft melted, and then the quickfilver is ftirred into it ; upon which they unite into a black mafs. In this part of the procefs the mixture is very apt to take fire ; of which it gives notice by fweUing up to a great degree. The veflel muft then be imme- diately covered. The mafs being beaten to powder, is afterwards to be fublimed in large earthen jars al- moft of an equal widenefs from end to end ; thefe are hung in a furnace by a ftrong rim of iron. When the matter is put in, the mouth of the veflel is cover- ed, the fire increafed by degrees, and continued for feveral hours, till aU the cinnabar has fublimed ; care being taken to introduce at times an iron rod to keep the middle clear \ otherwife the cinnabar concreting there, and flopping up the paflage, would infallibly burft the vefl'els. The quantity of fulphur direfted in the common receipts for making cinnabar is greatly larger than .the above ; being no lefs than one-third of the quantity of quickfilver employed : accordingly it has been found, that the fubHmate, wath fuch a large quantity of ful- phur, turned out of a blackifli colour, and required to ' be feveral times fublimed before it became perfeftly red ; but we cannot help thinking, that by one gentle fublimatioa 1405 Pulvis ful- xninans. Praaice. C H E M Sulj^hur. fublirpation the fuperfluous'fulphur might be feparated, ^"^"^ 'and the cinnabar become perfeftly pure the fecond time. Hoffman gives a curious method of making cinnabar without fubhmation : by fliaking or digeft- ing a httk mercury with volatile tinAure of fulphur, the mer,cury readily imbibes the fulphur from the vo- latile fpirit, and forms with it a deep red powder, not inferior in colour to the cinnabar prepared in the com- mon manner. Dr Lewis has found the common folu- tions of fulphur jby alkalies, or quicklime, to have a fimilar effect. This 'cinnab;«f will likevvife be of a darker or lighter colour, according as the folution contains more or lefs fulphur. Sulphur is a principal ingredient in gun-powder, (fee Gun-powder.) It alfo enters the compofition of the pulvis fiilminans. This confifts of three parts cf nitre, two of the dry alkah of tartar, and one part of fulphur, well ground together. If a little quantity of this powder is laid on an iron-fpoon or (hovel, and flowly heated, it will explode, when it arrives at a cer- tain degree of heat, with aftonifliing violence and noife. The mod probable opinion concerning this is, that the fixed air contained in the alkali is, by the acid vapours afting upon and endeavouring to expel it all at once, driven off with fuch force, that a loud explofion is pro- duced. 2. Phofphorus of Urine. This is a very inflammable fubftance, compofed of phlogifton united with a cer- tain acid, the properties of which we have already ta- ken notice of, n"" 904 el fcq. The preparation of it was long a fecret, and only perfedlly difcovered by Mr Margraaff, who publifhed it in the Berlin Me- moirs in 1743. This procefs being by far the beft and moft prafticable, we lhall content ourfelves with infertlng it alone. Two pounds of fal ammoniac are to be accurately mixed with four pounds of minium, and the mixture procefs for dlftilled in a glafs rfetort ; by which means a very pe- making. i^etrating, caullic alkaline fpirit will be obtained. The refiduum, after the diftillation, is a kind of plumbum cor- neum ; n°8T2. This is to be mixed with nine or ten pounds- of extra £1 of urine, evaporated to the con- fiftence of honey. (Seventy or eighty gallons of urine are required to produce this quantity of extraft.) The mixture is to be made flowly in an iron pot fet over the fire, and the matter frequently ftirred. Half a pound of powdered charcoal is then to be added, and the evaporation continued till the whole is reduced to a black powder. This powder is to be put into a retort, and urged with a graduated heat, till it be- comes red hot, in order to expel all the volatile alkali, fetid oil, and ammoniacal fait, that may be contained in the mixture. After the difllllation, a black friable refiduum remains, from which the phofphorus is to be extrafted by a fecond diftillation and a ftronger heat. Before it is fubjedkd to another diftillation, it may be tried by throwing forne of it upon hot coals. If the matter has been well prepared, a fmell of garlic exhales from it, and a blue phcfphorical flame is feen undu- lating along the furface of the coals. The matter is to be put into a good earthen retort, capable of fuftaining a violent fire. Three quarters of the retort are to be filled with the matter which is to yield the phofphorus, and it is to be placed in a fur- nace capable cf giving a itrong heat. Mr I'/IargraafF f 407 ir Mar grasff'i 140?? I S T R Y. divides the matter among fix retorts, fo that if any accident happens to one, the whole matter is not loft. The retorts ought to be well luted to a receiver of a moderate fize, pierced with a fmall hole, and half full of water ; and a fmall wall of bricks muft be raifed between the furnace and receiver, in oi'der to guard this veffel againft heat as much as pofiible. The re- torts are to be heated by flow degrees for an hour and an half ; then the heat is to be increafed. till the veffels are red hot, when the phofphorus afcends in luminous vapours. When the retoi't is heated till between a red and white, the phofphorus paffes in drops, which fall and congeal in the water at the bottom of the re- ceiver-. This degi-ee of heat is to be continued till no more comes over. When a retort contains eight pints or more, this operation continues about five hour's. In the firfl diftillation, phofphorus never pafTes pure, licdfifica- but is always of a blackifh colour, by reafon of its car-t^o'i of rying along with it fome part of the coal. From this,^'^"^^''^''* however, it may be purified by re6lification in a fmall'"** glafs-retort, to Avhich is luted a receiver half full of water. A very gentle heat is fufficient ; becaufe phof- phorus, once formed, is very volatile ; and as the fuli- ginous matter was raifed probably by the fixed air emitted by the chai-coal in the inftant of its union with the phofphorine acid, none of it can arife in a fecond diftillation. The phofphorus is then to be divided into fmall cy- lindrical rolls, which is done by putting it in glafs- tubes immerfed in warm water ; for the phofphorus is almoft as fufible as fuet. It takes the form of the glafs-tubes ; from which it may be taken out, when it is cold and hardened. This muft be done under wa- ter, leaft the phofphorus fhould take- fire. This concrete continually appears luminous in a dark -proctk place ; and by a very flight heat takes fire, and burns fometimes far more vehemently than any other known fubftance. "Jangerous. Hence it is necefTary to be very cautious in the diftil- lation of it ; for if the receiver fiiould happen to break while the phofphorus is diftilling, and a little flaming phofphorus fall upon the operator's legs or hands, it would burn its way to the bone in lefs than three mi- nutes. In this cafe, according to Mr HeUot, riothing but urine will ftop its progrefs. Though phofphorus takes fire very readily by itfelf, it does not inflame at all by grinding it with other in- flammable bodies, as camphor, gun-powder, or efTen- tial oils. In grinding it with nitre, fome luminous flaflies are obferved ; but the mixture never burns, un- lefs the quantity of phofphorus be large in proportion . to the nitre : rubbed pretty hard on a piece of paper or linen, it fets them on fire if they are rough, b'tt not if they are fmooth. It fires written paper more readily than fuch as is white, probably from the former ha- ving more afpei-ities. On grinding with iron-filings, it prefently takes fire. Oils ground wltli phofphorus appear-, like itfelf, j ; ^^^^^ luminous in a temperately warm place ; and thus be- phufpho- come a liquid phofphorus, which may be rubbed on rus. the hands, &c. without dan|jer. Liquid phofphorus is commonly prepared by grmding a little of the folid phofphorus with oil of cloves, or rubbing it firft with camphor, and this mixture with the oil. A luminous amalgam, as it is called, may be obtained, by digcfting 4 B 3 a 564 Sulphur. 1411 Experi- menrs on p!iofpho- ruR w fh fi'iiit of wine. 1412, With effe!> tial oils and acids. H13 Mr Mar- graaff's ex- periments •with me- tals. G H E M I a fcruple of folid phofphorus with half an ounce of oil of lavender, and, when the phofphorus begins to dif- folve and the liquor to boil, adding a drachm of pure quickfilver; then brillcly ftiaking the glafs for five or fix minutes till they unite. Retlilied fpirit of wine, digefted on phofphorus, ex- tracts a part of it, fo as to emit luminous ilafhes on be- ing dVopt into water. It is, computed that one part of phofphorus will communicate this property to 6oo,coo parts of fpirit. The liquor is never obferved to become luminous of itfelf, nor in any other circum- ftance except that above mentioned. By digeilion for feme months, the undilfolved phofphorus is reduced to a tranfparent oil, which neither emits light nor con- cretes in the cold. By wafliing with water, it is in iome meafure revived ; acquiring a thicker confillence, and becoming again luminous, tlvough in a lefs degree than at firft. Daring this digeftion, the glafs is very apt to buril. Phofphorus is partially diffolved by expreffcd oils ; and totally, or alrnoft fo, in effcntial oils and ether. When effential oils are faturated with it by heat, a part of the phofphorus fcparates, on ftanding in the cold, in a cryftalline form. Concentrated fpirit of fait has no aftion on it. In diftillation, the fpirit rifes firft, and the phofijhorus after it unchanged. Spirit of nitre dilfolves it, and the diflblution is attended with great heat and copious red fumes ; fo that great part of the fpirit diftils without the application of any external heat, and the phofphorus at laft takes fire, explodes, and burfts the velfels. Oil of vitriol like- wife dilTolves phofphorus, but not without a heat fufficient to make the acid diftll. The dillilled liquor is white, thick, and turbid ; the refiduum is a whitilh tenacious mafs, which dehquates, but not totally, in the gir. Phofphorus itfelf is refolved into an acid li- quor on being expofed two or three weeks to the air, its inflammable principle feeming by degrees to be dil- fipated. Phofphorus has been reported to produce extraordi- nary effefts in the refolution of metallic bodies : but from the experiments that have been made with this •view, it does not appear to have any remarkable ac- tion on them; at leaft on the precious ones, gold and fdver, for the refolution or fubtflization of which it has been chiefly recommended. The following experi- ments were made by Mr Margraaff^. I. A fcruple of filings of gold were digefted with a drachm of phofphorus for a month, and then com- mitted to diftillation. Part of the phofphorus arofe, and part remained above the gold, in appearance re- fembling glafs : this grew moift on the admiffion of air, and diffolved in water, leaving the gold unaltered. Half a drachm of fine Clver, precipitated by copper, being digefted with a drachm of phofphorus for three hours, and the fire then increafed to diftillation, greateft part of the phofphorus arofe pure, and the fil- ver remained unchanged. Copper filings being treat- ed in the fame manner, and with the fame quantity of phofphorus, the phofphorus fublimed as before ; but the remaining copper was found to have loft its metal- lic brightnefs, and to take fire on the contad of flame. Iron filings fuffered no change. Tin fiHngs run into granules, which appeared to be perfeft tin. Filings of lead did the fame. The red calx of mercury, called S TRY. Praaice precipitate per fe, treated In the fame manner, was to- Sulphur. tally converted into i-unning quickfilver. 2. Regu- — — y— lus of antimony fuffered no change itfelf, but occaiioa- cd a change in the coniiftence of the phofphorus j which, after being diftilled from this femimetai, refu- fed to congeal, and continued, under water, fluid like oil-olive. With bilmuth there was no alteration. A drachm of phofphorus bemg diftilled and cohobated wlih an equal quantity of zinc, greateft part of tlie zinc fublim-..d in form of very light pointed flowers of a rcddifli-ycUow colour.;; th..fe flowers, injcicd into a red hot crucible, took iire, and run into a glafs re- fcmbling that of borax. White arfenic, fublimed with phofphorus, arofe along with it in form of a mixed red fublimate. Sulphur readily unites with phofphorus into a mafs v/hich fmells like hepar fulphuris. This does not eafily take fire on being rubbed ; but expofed to a moderate dry heat, it flames violently, and emits a ftrong fulpliureous fume. If phofphorus is burnt in an open vcffel, a quantity of acid remains behind ; and if a glafs bell is held over it, an acid likewife fublimes ia the form of white flowers. 3. Mr Canton's phofphorus. This is a compofition ■^i^^'q^ of quicklime and common fulphur. The receipt for ton's phof- making it is as follows. " Calcine fome common oy- chorus, fter-ihells, by keeping them in a good coal-fire for half an hour; let the pureft part of the calx be pulverized and lifted. Mix with three parts of this powder one part of flowers of fulphur. L.et this mixture be i^am- med into a crucible of about an inch and a half in depth till it be ahnoft full ; and let it be placed in the middle of the fire, where it mult be kept red hot for an hour at leaft, and then fet by to cool : when cold, turn it out of the crucible ; and cutting or breaking it to pieces, fcrape off, upon trial, the brighteft parts ; which, if good plKjfphcjrus, will be a white powder. This kind of phofphorus iliines on be- ing expofed to the light of the fun, or on receiving an eledlrical ftroke. 4. Phofphorus ff Homlerg. This fubftance, which ^ ^4' •'^ ,^ has the lingular property of kindling fpontaneoufly ^j^^^^p j^''^'^^^ when expofed to the air, was accidentally difcovered or pyr pho by Mr Homberg, as he was endeavouring to diftil a ''us. clear flavourlefs oil from human excrements. Having mixed the excrement with alum, and diftilled over as much as he could with a red heat, he was much fur- prifed at feeing the matters left in the retort take fire upon being expofed to the air, fome days after the di- ftillation was over. This induced him to repeat the operation, in which he met with the fame fuccefs ; and he then publifhed a p;ocefs, wherein he recommended alum and human excrement for the preparation of the phofphorus. Since his time, however, the procefs has been much improved ; and it is difcovered, that almofl: every vitriolic fait may be fubftituted for the alum, and moft other inflammable fubftances for the excrement ; " but though alum is not abfolutely necefiary for the fuccefs, it is one of the vitriohc falts that fuccced bell. The following procefs is recommended in the Chemi- cal Diftionary. Let three parts of alum and one of fugar be mixed ^ {in\ together. This mixture muft be dried in an iron flio- t^od of prc- vel, over a moderate fire, till it be almofl reduced to pari!)g. a blacklfli powder or coal ; during which time it muit be ftirred with an iron fpatula. Any large maffcs mufl be Pracll Sulphur. T417 ts not in- jureil by mere ex- pofure to 1418 Caufe of the accen- fion. ce. C H E M be bruifed into powder ; and then it muft be put into a glafs matrafs, tlic mouth of which is rather ftrait than wide, and feven or eight inches long. This ma- trafs is to be placed in a crucible, or other_ earthen vef- fcl, large enough to contain the belly of the matrafs, witli about a fpace equal to that of a finger all round it. This fpace is to be iilkd with fand, fo that the matrafs fliall not touch the earthen vefTel. The appa- ratus is then to be put into a furnace, and the whole to be made red hot. The fire mull be applied gra- dually, that any oily or fuliginous matter may be ex- pelled ; after which, when the matrafs is made red hot, fulphureous vajiours exhale : this degree of heat is to be continued till a truly lulphureoiis flame, which appears at the end of the operation, has been feen near- ly a quarter of an hour : the fire is then to be extin- guifned, and the matrafs left to cool, without taking it out of the crucible ; when it ceafcs to be red hot, it muft be Hopped with a cork. Before the matrafs is perfeftly cold, it muft be taken out of the crucible, and the powder it contains pouted as quickly as pof- fihle into a very dry glafs phial, with a glafs ftopper. If we would preferve this phofphorus a long time, the bottle containing it muft be opened as feldom as pof- fible. Sometimes it kindles while it is pouring into the glafs phial ; but it may be then extinguiftied by clofing the phial expeditioufly. A fmall quantity of this pyrophorus laid on paper, and expofed to the air, immediately takes fire, becomes red like burning coals, and emits a ftrong fulphureous vapour greatly refenibling that which arifes on decompofing liver of fulphur. It has been generally alleged, that the common black phofphorus is impaired by being expofed to the light; but MrCavallo has difcovered the fallacy of this fuppofition by the following experiment. Some por- tions of the fame pyrophorus were inclofed in three glafs tubes, and immediately fealed up hermetically. On the 20th of May 1779, two of them were fu- fpended from a nail out cf a window, and the third was wrapped up in paper and inclofed in a box, where not the leaft glimmering of light could enter. In this fituation they were left for more thnn a year ; after which one of thofe that had been kept out of the window was broke, along with that which had been kept in the dark, in the prefence of Mr Kirwan ; when the pyrophorus feemed to be equally good in each tube, taking fire in about half a minute after it was taken out of the tubes, and expofed to the air on a piece of paper. There are many different kinds of-pyrophori ; fome of the moft remarkable of which are defcribed under the article Pyrophorus. Many theories have been invented to folve the phenomenon of their accenfion on the contaft of air. This has been thought owing to the converfion of the earth of alum into lime, or to a remainder of the vitriolic acid attracting moifture from the atmofphere ; but the formation of pyrophorus without either alum or vitriolic acid, fliows that nei- ther of thefe opinions can be juft. It is moft probable, therefore, that the heat is occafioned by the total dif- fipation of that aqueous part which is eflcntial to the conftitution of terrcftrial fubftances. In confequence of this, the water contained in the atmofphere is not only attracted with avidity, but decompounded by the I S T R Y. matter reduced to fuch a ttatc of extreme drynefs. By thefe operations it gives out the latent heat contained in it, and this produces the accenfion in queftion. § 2. Ardent Spirits. See Fermentation and Distix-lation. ^ 3. Oils. Oils. I . EJfential Oils. Thofe oils are called ejfenttal which Effential have evidently the fmell of the vegetable from which oils, they are drawn. For the method of procuring them, fee Distillation. Tluy are diftinguiftied from all others by their fuperior volatility, which is fo great as to caufe them rife with the heat of boiling water. All thele have a ftrong aromatic fraell, and an acrid, cau- ftie tafte ; in which refpeft alfo they differ from other oils. This tafte is thought to proceed from a copious Sup']x)*ftd and difeiigaged acid, with which they are all pene- caufe of trated. The prefence of this difengaged acid in effen- '^heir tafte tial oils, appears from the impreflion they make upon" the corks of bottles in which they are kept. Thefe corks are always ftained of a yellow colour, and a little corroded, nearly as they are by nitrous acid. The var pour of thefe oils alfo reddens blue paper, and converts alkalies into neutral falts. This acid is hkewife fuppofed to be the caufe of their 1^^]^^^ folubility in fpirit of wine. They are not all equally iubility'in°' foluble in this menftruum, becaufe they do not all con- fpirit of tain an equal quantity of acid. As this acid is much wine, difengaged, they lofe a great deal of it by repeated di- ftillations, and therefore they become lefs and lefs fo- luble on being frequently diftilled. By evaporation they lofe their moft volatile and thin part, in which the fpecific fmell of the vegetable from which they are txtrafted refides ; by which lofs they become thick, and acquire the finell and confiftence of turpen^ tine, and even of refins. In this ftate they are no longer volatile with the heat of boiling water ; and, if diftilled with a ftronger fire, they give over an oil which has neither fmell nor tafte of the- vegetable whence they were extracted, but is entirely empyreu^- matic, and fimilar to thofe oils procured by diftilling vegetable or animal fubftances with a ftrong fire. See Distillation. To the clafs of effential oils, the volatile concrete ^A''-'^ called camphor feems moft properly to belong. With ^^"''P^-^*'* them it agrees in its properties of inflammability, fo- lubility in fpirit of wine, and a ftrong aromatic fla- vour. The only differences between them are, that camphor is always in a folld ftate, and is incapable of decompofition by any number of fublimations. It has, however, been found poffible to decompofe Decom^io- it by diftillation with certain additions.. By diftiUingfcd'^by^di^. it feveral times along with bole, we obtain a fluid ha- filiation ving the properties of an effential oil, foluble in water, '^''^'^ and feparating again on the addition of i'pirit of wine. ,^2^ On diitilhng it eight times with deplilogifticated ni- With Pe- trous acid, we obtain a fait having the form of a pa- phlogiitica-- rallclopiped, of an acid and bitter tafte, and changing '^'^':'""''^'^*~ the juice of violets and turnfole red. This has the^*^ properties of a true acid ; combines with fixed and vo- latile alkalies into neutral falts capable of being cry- ftalKzcd J diffolves copper, iron, bifmuth, arfeoic, and:. cobalt, ^ V 566 Oils Soluble ill ardent fpl- tits and oil. 14^6 Empyreu- maiic oils. C H E M I dobalt. With manganefe it forms regular cryftals, in ' fome meafure refembling bafaltes. It is diftinguifhed from the acid of fugar by not precipitating lime from its folution in marine acid, and by forming with mag- nefia a white powder foluble in water. According to Neumann, all the camphor made ufe of is the produce of two fpccies of trees ; the one growing in Sumatra and Borneo, the other in Japan. Of thefe, the Japan kind is the only one brought into Europe. The tree is about the fize of a large lime, the flowers white, and the fruit a fmall red berry. -All parts of the tree are impregnated with camphor ; but the roots contain moft, and therefore are chiefly made ufe of for the preparation of this commodity ; though, in want of them, the wood and leaves are fometimes mixed. The camphor is extraAed by diftillation with water in large iron pots filled with earthen heads ftufFed with ftraw ; greateil part of the camphor conci-etes among the llraw, but part palTes down into the receiver among the water. • In this Hate it is found in fm.all bits like gray falt-petre, or common bay-falt ; and requires to be purified either by a fecond fubhmation, or by diffo- lution in fpirit of wine, filtration, and exficcation. If the firft method is followed, there will be fome diffi- culty in giving it the form of a perfedl tranfparent cake. A difficulty of this kind indeed always occurs in fublimations; and the only way is to keep the upper part of the glafs of fuch a degree of heat as may keep the fublimate in a half-melted ilate. Dr Lewis re- commends the depuration of camphor by fpirit of wine, and then melting it into a cake in the bottom of a glafs. Camphor poffefTes confiderable antifeptic virtues ; and is a good diaphoretic, without heating the confti- tution ; with which intention it is often ufed in medi- cine. It is' likewife employed in fire-works and feve- ral other arts, particularly in making varniflies. See Varnish. This fubftance dilTolves eafily and plentifully in vi- nous fpirits and in oils ; four ounces of fpirit of wine will diffolve three of camphor. On diftilling the mix- ture, the fpirit rifes firil, very little camphor coming over with it. This fliows that camphor, however volatile it may feem by its fmell, is very far from ha- ving the volatility of ether, and confequently is impro- perly clalTed Avith fubftances of that kind. 2. Empyreumatic Oils. Under this name are com- prehended all thofe oils, from whatever fubllance ob- tained, which require a greater heat for their diftil- lation than that of boiling water. Thefe are partial- ly foluble in fpirit of wine, and become more and more fo by repeated diftillations. The empyreumatic oils obtained from animal fubftances are at firft more fetid than thofe procured from vegetables ; but by repeated diftillations, they become exceedingly attenuated and volatile, becoming almoft as white, thin, and vola- tile, as ether- They then acquire a property of afting upon the brain and nervous fyftem, and of allaying its irregular movements, which is common to them with all other inflammable matters v/hen highly attenuated and very volatile ; but this kind of oil is particularly recommended in epileptic and convulfive affeftions. It is given from 4 to 10 or 12 drops: but, though prepared with the utmoft care, it is very fufceptible of S T R y. Praaice. lofing its whitenefs, and even its thinnefs, by a fhort <^i^«- expofure to air ; which proceeds from the almoft in- ftantaneous evaporation of its more thin and volatile parts, and from the property which the lefs volatile • remainder has of acquiring colour. To avoid this in- convenience, it muft be put, as foon as it is made, into very clean glafs bottles wi-th glafs ftoppers, and ex- posed to the air as little as poflible. 14^7 The moft important obfervations concerning the How redi- method of making the pure animal oil are, firft to fieJ, change the veflels at each diftillation, or at Icaft to make them perfeftly clean; for a very fmall quantity of the thicker and lefs volatile part is fufficient to fpoil a large quantity of that which is more rectified. In the fecond place, Mr Beaume has obferved, that this operation may be greatly abridged, by taking care to receive none but the moft volatile part in each diftil- lation, and to leave a large refiduum, which is to be neglefted, and only the more volatile part to be fur- ther reftified. By this method a confiderable quan- tity of fine oil may be obtained at three or four diftil- lations, which could not otherwife be obtained at fifty or fixty. _ ^ - 3. Animal Fats. Though thefe dilFer confiderably ^^J^^^j from one another in their external appearance, andf^tg. probably in their medicinal qualities, they afford, on a chemical analyfis, produ£ls firailar in quahty, and dif- fering but inconfiderably in quantity. They all yield a large proportion of oil, and no volatile fait ; in which refpeft they differ from all other animal fubftances. Two ounces of hog's lard yielded, according to Neu- mann, two drachms of an empyreumatic liquor, and one ounce five drachms and 50 grains of a clear brown- coloured oil of a volatile fmell, fomevvhat like horfe- radifh. The caput mortuum was of a fliining black co- lour, and weighed 10 grains. j^^^ Tallow being diftilled in the fame manner, two Tallow, drachms of empyreumatic liquor were obtained from two ounces of it ; of a clear brown oil, fmelling like horfe-radifli, one ounce fix drachms and 12 grains. The remaining coal was of a fliining black colour, and weighed I % grains. A particular kind of acid is now found to be contained in it. 1430 The marrow of bones differs a little from fats, Marrow, when chemically examined. Four ounces of frefli marrow, diftilled in the ufual manner, gave over three drachms and a fcruple of a liquor which fmelled like tallow ; two fcruples and an half of a hquor which had more of an empyreumatic and a fourifli fmell ; two oimces and an half of a yellowifli-brown, butyraceous oil, which fmelled like horfe-radifli ; and fix drachms and an half of a blackifli-brown oil of the fame fmell. The caput mortuum weighed four fcruples. All animal fats, when perfeftly pure, burn totally away without leaving any feces, and have no particu- lar fmell. In the ftate in which we commonly find them, however, they are exceedingly apt to turn ran- , cid, and emit a moft difagreeable and noxious fmell ; ' and to this they are peculiarly liable, when long kept in a gentle degree of heat. In this ftate, too, an inflam- mable vapour ariies from them, which when on fire is capable of producing explofions. Hence, in thofe works where large bellows are ufed, they have been often fuddenly burft by the inflammable vapours ari- fing from the rancid oil employed for foftening the leather. 1431 _ Uancid oils P*\iaice. C H E M Rpfm-a!id leather. The expreHed unftuoits oils of vegetables Balfiims. f.jVjjj;(3. fU.^. f^^j^j^. changes : but from this ranci- dity thfv may all be freed rno/l efFcftiially, by the fim- p)e procciS of a;;i'::>Liiig thera well with water; which is to be dra^v^ ctF, and freili quantities added, till it co;r.csofF at hJi clear and infipid, without any illfmell. The proper inilrument for performing this operation in large ir, a barrel-churn, having in it four rows of narrow fplit deal;:, from the centre to the circumfe- rence, each piece fet at obtufe angles to the other, in order to give different directions to the oil and water as the churn turns round, thereby to mix them more intimately. The churn is to be fwiftly turned round for a few minutes ; and mufk then be left at reft, till the oil and water have fully feparated ; wdiich will be in 15 or 20 iraiiulies, more or lefs, according to the fize of the chu'-n. V/hen this water is drawn off, frefh water is to be put in, and the churn again turned round, and this continued till the oil is perfeftly f weet. If the oil and water are allowed to ftand to- gether for fome days, a gelatinous fubilance is found between them, which is not very eafily mifcible either with oil or water. Chalk, quickhme, and alkahne falts, are found alfo capable of taking off the rancidity from oils and fats ; but have the inconvenience of de- ftroying a part of their fubllance. § 4. R£siNs and Balsams, These are commonly reckoned to be compofed of an elTential oil thickened by an acid ; as the effential oils themfelves are found to be convertible i-nto a fi- milar fubftance, by the exhalation of their more vola- tile parts. True refms are generally tranfparent in a confiderable degree, foluble in fpirit of wine, and pof- 1431 feffed of a confiderable degree of flavour. Whence Refins are originally produced By infpiffating the procured, natural juices which flow from incifions made in the Items of growing vegetables, and are in that flate called balfams. The balfams may be confidered as ef- fential oils thickened by lofmg fome of their odorife- rous principle, and of their finefl and mofb volatile part. There are feveral kinds of balfams, which, how- ever, differ from each other only in the frnell and de- gree of confiftence ; and therefore all yield fimilar produfts on diftillation. An analyfis of turpentine therefore will be fufficient as an example of the analy- j^,^ fis and natural properties of all the reft. Turpentine The true turpentine-tree is found in Spain and the Chio. fouthetn parts of France, as well as in the ifland of Chio and in the Indies. It is a middling-fized ever- green tree, with lea.ves like thofe of the bay, bearing purplifh, imperfeft flowers; and on feparate pedicles hard unCluous berries, like thofe; of juniper. It is ex- tremely refinous ; and unlefs the refui is difcharged, decays, produces fungous excrefcences, fwells, burfbs, and dies ; the prevention of which confifts wholly in plentiful bleeding, both in the trunk and branches. The juice is the Chio or Cyprus turpentine of the fho^. This fort is quite of a thick confiftence, of a greenifh white colour, clear and tranfparent, and of fcarcely 14-^4 ''"y fmell. .nice* The kind now called Venice turpentine, is no other than a mixture of eight parts of common yellow or black rofin with five- parts of oil of turpentine. What 5^7 I S T R Y. was originally Venice turpentine is now unknown. Refins and Neumann relates, that the Venice turpentine fold in Balfa ma. ^ his country was no other than that prepared, from the larix tree, which grows plentifully in fome parts of France, as alfo In Auftria, Tyrol, Italy, Spain, &c. Of this there are two kinds; the young trees yielding a thin limpid juice, refembling balfam of copaiba; the older, a yellower and thicker one. j^-;. The Strajburg turpentine is extrafted from the filvei*- StruiLtur,f , fir. Dr Lewis takes notice that fome of the exotic firs afford balfams, or refins, fuperior to thofe obtained from the native European ones ; as particularly that called halm of Gilead Jir, which is now naturalized to our own climate. A large quantity of an elegant re finous juice may be collected from the cones of this tree : the leaves alfo, when rubbed, emit a fragrant fmell ; and yaeld, with reCtified fpirit, an agreeable re- finous extraft. 14-; 6 The common turpentine is prepared from different Common, forts of the pine ; and is quite thick, white, and opaque. ' Even this is often counterfeited by mixtures of rofin and common expreffed oils. ^^^^ All the turpentines yield a confiderable proportion Phenomena of effential oil. From iixteen ounces of Venice tur- on diftilkv- pentine, N'eumann obtained, by diftillation with wa- ter, four ounces and three drachms of oil. The fame quantity diftilled, without addition, in the heat of a water-bath, gave but two ounces and an half ; and from the reiiduum treated w-ith water, only an ounce could be obtained. The water remaining in the ftill is found to have imbibed nothing from the turpentine; on the contraiy, the turpentine is found to imbibe part of the water ; the reiiduum and the oil amount- ing to a full ounce on the pound more than the tur- pentine employed. When turpentine is diftilled or boiled with water till it becomes folid, it appears yel- lowifh ; when the procefs is further continued, of a reddifh brown colour : in the iirft ftate, it is called boiled turpentine ; and in the latter, colophony, or rofin. On diftilling fixteen ounces of turpentine in a re- tort with an open fire, increafed by degrees, we ob- tain firft four ounces of a limpid colourlefs oil ; then two ounces and two drachms of a yellowifh one ; four ounces and three drachms of a thicker yellow oil; and two ounces and one drachm of a dark brown- ifh red empyreumatic oil, of the confiftence of balfam, and (fommonly called balfam of turpentine. 143^? The limpid effential oil called fpirit of turpentine, is Effential exceedingly difficult of folution in fpirit of wine; tho'oil difficult turpentine itfelf diffolves with great eafe. One part °f solution, of the oil may indeed be diffolved in feven parts of rectified fpirit ; but on ftanding for fome time, the greateft part of the oil fubfides to the bottom, a much greater proportion of fpirit being requifite to keep it diffolved. 2. Benzoin. This is a very brittle brownlfh refin, Benzoin;- of an exceedingly fragrant fmell. The tree which produces benzoin is a native of the Eaft Indies ; par- ticularly of Siam and the ifland of Sumatra. It is ne- ver permitted to exceed the fixth year ; being, after this time, unfit for producing the benzoin., It is then cut down, and its place fupphed by a young tree rai- fed commonly from the fruit. One tree does not yield above three pounds of benzoin. A tree fuppofed to be the fame with that which af^ fords 568 Bitumen CHEMI STRY. Pradicc 1440 Soluble fpirit of wine. 1441 Origin of bitumens. 1441 Kaphtha. 1443 Petroleum *• fords benzoin in the Eafl Indies, is plentiful alfo in Virginia and Carolina ; from whence it has been brought into England, where it grows with vigour in the open ground. TJie bark and the leaves have the fmell of benzoin ; and yield with re£lifled fpirit a re- fin of the fame fmell ; but no refin has been obferved to ifliie from it naturally in this climate ; nor has any benzoin been collcilcd from It in America. Benzoin diffolves totally in fpirit of wine Into a blood-red liquor, leaving only the impurities, which commonly amount t« no more than a fcruple on an ounce. To water, It gives out a portion of faline mat- ter of a peculiar kind, volatile and fublimable In the lire. See (j^^ et feq. The principal ufe of refins Is In the making of lac- vquers, vaniifiies, &c. See Varnish. ^ 5. B I 7 u M F. N s. - The-se are Inflammable mineral bodies,, not fulphu- reous, or only cafaally Impregnated with fvdphur. They are of various degrees of conhftency; and £eem, in the mineral kingdom, to correfpond with the oils and refins In the vegetable. Concerning the origin of bitumens, chemifts are not at all agreed. Some chemical writers, particularly Mr Macquer, imagine bitumens to be no other than vegetable refins altered In a particular manner by the admixture of fome of the mineral acids. In the earth; but Dr Lewis Is of a contrary opinion, for the follow- ing reafons. " Mineral bitumens are very different in their qua- lities from vegetable refins : and, in the minei-al king- dom, we find a fluid oil very different from vegetable oils. The mineral oil Is changed by mineral acids in- to a fubllance greatly refembling bitumens ; and the vegetable oils are changed by the fame acids into fub- ftances greatly refeml-ling the natural refins. *' From bitumens we obtain, by dlililktlon, the mi- neral oil, and from refins the vegetable oil, dillinft in their quahties as at firft. Vegetable oils and refins have been treated with all the knov^n mineral acids ; but have never yielded any thing fim.Ilar to the mine- 'ral bitumens. It feems, therefore, as If the oily pro- dufts of the two kingdoms were effentlally and fpe- cifically different. The laws of chemical inquiries at leaft demand, that we do not look upon them any otherwife, till we are able to produce from one a fub- ftance fimllar to the other. When this fiiall be done, and not before, the prefumption that nature effects the fame change In the bowels of the earth, will be of fome weight." There is a perfectly fluid, thin bitumen, or mine- ral oil, called naphtha, clear and colourlefs as cryftal ; of a ftrong fmell ; extremely fubtlle ; fo light as to fwim on all known liquoi-s, ether perhaps exceptt\l ; fpread- ing to a vafl; furfacc on water, and exhibiting rain- bow colours ; highly Inflansmable : formerly made ufe of In the compofitlon of the fuppofed Incxtingulftiable greek fire. Next to this In confiflence Is the olam petra, or pe- troleum ; which is groffer and thicker than naphtha, «f a ytllowifti, rcddifh, or brownlfli colour ; but very light, fo as to fwim even on fpirit of wine. By di- ftillation, the petroleum becomes thinnei- and more NO 75. fubtlle, a grofs matter being left behind ; It does not, however, eafily arlfe, nor does It totally lofe its colour by this procefs, without particular managements or additions. Both naphtha and petroleum are found plentifully in fome parts of Perfia, trickling through rocks or fvvlmming on the furface of waters. Kempfer gives an account of two fpvings near Baku ; one affording naphtha, which It receives In di'ops from fubtei-rane- ous veins ; the other, a blackifli and more fetid pe- troleum, uhich comes from Mount Caucafus. The naphtha is colle£led' for making varnlihes ; the petro- leum Is colletled In pits, and fent to different places for lamps and torches. Native petrolea are likewife found In many diffe- rent places, but are not to be had In the ffibps ; what Is fold there for petroleum, being generally oil of tur- pentine coloured with alkanet root. The true naph- tha is recommended againft diforders of the nerves, pains, cramps, and contradlions of the limbs, &c. but genuine naphtha Is rarely or never brought to this country. There are fome bitumens, fach as amber, amber- greafe, pit-coal, and jet, perfectly folid; others, fuch as Barbadoes tar, of a middle confiitence between fluid and folld. Turf and peat are likewife thought to be- long to this clafs. 1. Amber. This fubftance melts, and burns in the fire, emitting a ftrong peculiar fmell. Dill died in a ftrong heat, it yields a pldegm, an oil, and a particu- lar fpecles of acid fait. The diftillation Is performed In earthen or glafs retorts, frequently with the addi- tion of fand, fea-falt, coals, &c. which may break the tenacity of the melted mafs, fo as to keep It from fwelling up, which It Is apt to do by itfelf. Thefe additions, however, make a perceptible difference In the produce of the diftillation : with fome the fait proves yellowifii and dry ; with others, brownlfli or blackifli, and undtuous or foft like an extrafl : with fgme, the oil Is throughout of a dark brown colour ; with others, it proves externally green or greeaiili ; with elixated ^iflies, in particular, It is of a fine green. The quantity of oil and phlegm is greateft when coals are ufed, and that of fait when fea-falt Is ufed. The moft advantageous method of diftilling amber, however, is without any addition ; and this is the me- thod ufed in Pruflla, where the greateft quantities of fait and oil of amber are made. At firft a phlegma- tic liquor difllls; then a fluid oil; afterwards one that is thicker and more ponderous ; ar^d laft of all, an oil ftill more ponderous along with the fait. In order to coUeCl the fait more perfeAly, the receiver Is fre- quently changed; and the phlegm, and light oil, which arife at firft, are kept by themlelves. The fait is pu- rified, by being kept fome time on bibulous paper, which abforbs a part of the o\\( and changing the pa- per as long as it receives any oily ftain. For the fur- ther depuration as well as the nature of this fait, fee SuCCINUM. 2. Ambcrgreafe. This concrete, which Is ordy ufed as a perfume, yields, on diftillation, produfts of a fimllar nature to that of amber, excepting that the v(jlatile fait Is In much Itfs quantity. See Amber-* GRKASE. 3. Pit-coal. See the articles Coal and Lithan- THRAX. Bitumens 1444 Amber. 144.? M- (1: ad- v;in! ajre» oufl)' di- ftiliedwiti out addi- tion. 144O Amber- greafe. '44 7 Pit-coul. Peat. Pnenome- ra on diftil lation. Praaice., ^ G H E M Bitumens. thRAx. This fubftance yields by diftillati'on, ac- cording to the tranflator of the Chemical Dictio- nary, t phlegrh, or v/ater ; 2. a very acid liquor; 3. a thin oil, like naphtha ; 4. a thicker oilj relembling petroleum, which falls to the bottonn of the former, and which ri{es with a violent fire ; 5". an acid, con- crete (alt ; 6. (tn unhrflammable earth (we fuppofe he means a piece of charred coal, or cinder) remains in the retort. The fluid oil obtained from coals is faid to be exceedingly inflammable, i"o as to burn upon the fur- face of water like naphtha itfelf. 4. Peat. There are very confiderable differen- ces in this fubftance, proceeding'- probably from the admixture of different minerals : for the fubflance of peat is plainly of vegetable origin ; whence it is found to anfwer for the fmelting of ores, and the re- duAion of metallic calces, nearly in the fame manner as coals of wood. Some forts yield, in bnrnins;-, a very difagreeable fmell, which extends to a great diilance ; whillt others are inclfenfive. Some burn into grey or white, and others into red, ferruginous afhes. The aflies yield, on elixation, a fraall quantity of alkaline, and fome neutral fait. The fmoke of peat does not preferve or harden flefli like that of wood | and the foot into which it condenfes is more apt to liquefy in moift weather. On 'diflilling peat in clofe vcfTcls, there ariles a clear in- fipid phlegm; an acid liqu()r, which is fucceeded by an alkaline one; and a dark-coloiued oil. The oil has a very pungent tafle, and an empyreutratic fmell ; lefs fetid than that of animal fubftances, but more fo than that of mineral bitumens. It congeals, in the cold, into a pitchy mafs, ^which liquefies in a fmall heat i it readily catches fire from a candle; but burns lefs vehe- mently than other oils, and immiediately goes out up^ on removing the external flame. It difTolves almofl totally in rttlified fpirit of wine, into a dark, brownifh- rcd, liquor* § 6. C H AkCOAL, toiffe-cHces This is the form to which all inflammable matters ietweeii ^""^ reducible, by being fubjefted to the mofl vehe- t!ie coai> nian's ius. Praaice. C H E M Calo lus acid, the earth is kept dlflblvcd; and by reafon of this fuperabundant acidfrefli urine communicates a red colour to Iacmu3. By faturation with cauftic volatile alkali a white powder is preciptate^ ; of which three drachms and an half are obtained from four kannes of ■vrine. It is foluble in nitrous acid ; and on adding the vitriolic, fome gypfum is precipitated. On evapo- rating the nitrous acid,' another remained, which pre- cipitated hme- water ; and when mixed with lamp-black, afforded phofphorus by diftillation ; whence it is evi- dent, that the white powder juft mentioned contained lime and phofphoric acid. 15. From thefe experiments Mr Scheele concludes, that all urine contains, befides the fubilances already known (viz. fal ammoniac, common fait, digeftive fait, 'Glauber's fait, microcofmic fait, fal perlatum, and an -oily extraftive matter), a concrete acid, or that of cal- culus, and animal earth. It is alfo remarkable, that the urine of the fick is more acid, and contains more ani- mal earth than that of healthy perfons. With regard to the fal perlatum, it was afterwards difcovered by Mr Scheele not to be a peculiar acid, but only a phofpho- ric acid difguifed by a fmall quantity of folTil alkali united with it. The analyfis is confirmed by fynthe- fis ; for, by combining foffd alkali with phofphoric acid, our author obtained a true perlate acid. 5, , In a fupplement to Mr Scheele's differtation on the account of calculus, Mr Bergman obferves, that he could not fuc- the calcu- ceed in diffolving it entirely either in pure water or in the nitrous acid, though the undiffolved part was the lefs in proportion to the finenefs of the powder to which the calculus was reduced. The undilfolved part appeai-s mod confpicuous, when fmall pieces, or fmall calculi of a few grains weight only, are put into a fu- perabundant quantity of menftruum, and kept in a de- gree of heat very near to that which makes water boil. Here it will be obferved, that the greateft part of the piece is diflTolved ; but that at the fame time fome fmall white fpongy particles remain, which are not af- fefted either by water, fpirit of wine, acids, or cauftic volatile alkali. If the liquor be made fully to boil, thefe particles divide into white rare flocculi, and be- come almoft imperceptible, but without any entire dif- folution. Mr Bergman could not colled a fuflicient quantity of them to determine their nature with accu- racy ; only he obferved, that when expofed to a ftrong heat, they were reduced to a coal which burns flowly to afhes, and is not foluble in diluted nitrous acid. ^ " When calculus veficas (fays he) is diffolved in nitrous acid, no precipitation enfues «n adding the acid ©f fugar ; whence one is readily induced to conclude, that there is no calcareous earth prefent, becaufe this experiment is the fureft way to difcover it. But I have found, in a variety of experiments concerhing eleftive attractions, that the addition of a third fub- ftance, inftead of difuniting two already united, often unites both very clofely. That the fame thing hap- pens here I had the more reafon to believe, becaufe the acid of fugar contains fome ^hlogiftic matter, though of fuch a fubtk nature, that, on being burned, it does not produce any fenfible coal-; and the event of my expe- riment has fhown, thaf I was not miftaken in my con- jefture. In order to afcertain this point, I burned coals of the calculus to afhes, which were quite white, ■and (howed in every refpedl the fame phenomena as lime^ caufed fome effervefcence during their folution I S T R Y. in acids, united with vitriolic acid into gypfum, were Calculus, precipitated by the acid of fugar, and were partly fo- ' ' luble in pure water, &c. Notwithllanding this, there remains about one-hundredth part of the afhes info- luble , in aquafortis ; being the remainder of the fub- ftance ?bove mentioned, which; together with the concrete acid, conftitutes the calculus. If the calculus be diffolved in nitrous acid, the folution filtered and'eva- porated to drynefs, and the dry mafs calcined to white- nefs, a calcareous powder is thus hkewife obtained." 1461 As pure vitriolic acid contains no phlogiflon, our Calcareous author fuppofed, that by dropping it, in its concentra- l^^"" ted ftate, mto a folution of calculus in nitrous acid, the Itlw vitrit calcareous earth, if any exiftedin it, would be difcover- He acid, ed. _ In this he was not difappointed ; for when the folution was faturated, fome fmall cryftals were thus immediately feparated. Thefe, on examination, were lound to be gypfum ; and, after being diffolved in di- ftiUed water, were precipitated by acid of fugar. When the folution of calculus was very much diluted, no change appeared at firll on the addition of oil of vi- triol ; but after a little evaporation, the above men- tioned ciyftals began to appear. Some calculi of the bladder or kidneys at leaft certainly contain hme, but feldom more than one half in an hundred parts, or one in 200 parts. By the affiftance of heat, concentrated vitriolic acid diffolves the calculus with effcrvefcence, and the folu- tion is of a dark brown colour. On adding a little wa- ter, a kind of coagulation takes place ; but by adding m.ore, the liquor again becomes clear, and afl'umes a yellowifh colour. Mr Bergman agrees with Mr Scheele in fuppofing that the muriatic acid has no ef- feft upon the calculus ; but he is in doubt whether it may not extrad fome part of the calcareous earth. j g _ The red colour affumed by the folution of calculus Red toiour in aquafortis is remarkable. A faturated folution dif- of the nir covers no fmell of nitrous acid, and if evaporated by itfclfina large open vefTel, the hquor afTumes at laft '''I^J'] a deep red colour, and fcarcely contains any nitrous for. acid ; for, on the one hand, paper tinged with lac- mus fcarce fhows any rednefs ; and, on the other, the colour is deftroyed irrecoverably by the addition of any acid. By quick evaporation the folution at laft fwells into innumerable bubbles^ the foam growa redder and redder, and at laft becomes dark red after it is quite dry. This dry mafs communicates its co- lour to a much larger quantity of water than before, and diffolves very readily in all acids, even fuch as have no aftion on the calculus ; but they entirely de- ft roy the colour, and that the more quickly in pro- portion to their degree of ftrength; even alum has this effeft on account of the fmall quantity of loofe acid it contains. Cauftic alkalies aho difiblve the colouring matter, and deftroy it, but more flowly. Our author endeavours to account for this red co- lour produced by the nitrous acid, from the pecuKar nature of that acid, and the effeft it has upon phlo- gifton. In order to obtain it, a proportionable quan- tity of acid muft be made ufe of, and it ought to be diluted, that there may be no danger of going be- yond the neccffary Hmit. If too much be ufed, it will not produce the proper effeft ; but, by reafon of its fuperabundance, more or lefs, or even the whole, will be deftroyed in proportion to the quantity. By poar- ing it in an undiluted ftate on powdered calculut, it i« 4 C 2 <;ojg 572 Calculus. 1463 Experi- ments of Mr Hig- gins on this C H E M I converted In a few moments into mere foam. The acid of calculus is the more eafily feparated from the aquafortis by evaporation, as the latter is rendered more volatile by the inflammable' particles of the for- mer : alkali added to them both united does not pro- duce any precipitation ; a circumftance generally ob- ferved where two acids are united. In this cafe both the acids unite with the alkali, according to the dif- ferent laws of their attraftion. The red niafs oblam- ed after deficcation is, however, very different from the concentrated acid, fuch as is contained in the cal- culus ; for it is of a darker eolour, and very deliqiief- cent : the leaft particle gives a rofe colour to a very confulerable quantity of water; but the muriatic and other ftrong acids always certainly deftroy it ; and, in a longer or fliorter time, produce a colourlefs folu- tion. This remarkable change depends, according to our author, more on the aftion of the nitrons acid upon the inflammable part, than upon any thing re- maining behind. — Such red fpots as are produced up- on the flcin by the folution, are likewife produced up- on bones, glafs, paper, and other fubilances ; but more time is required for their becoming vifible, though this too may be a little accelerated by means of heat. The following is an abftrad of Mr Higgins's expe- riments upon this fubjeft. I. Eight hundred and forty grains of dry and well powdered calculus were introduced into a glafs retort. It was taken from a laminated ftone with a fmall nu- cleus, which was likewife laminated. The outward crull: appeared very porous, but increafed In dculity towards the centre. By the application of heat, an elalHc fluid was firfl llowjy extricatetl; and which, on exarnination, appeared to be compofed of equal parts of fixed and phlogifl-icated air. The lail portions came over very faft, and were attended with an urinous fmell ; and, .by continuing tlie diflillation, it became evident that fixed and alkaline air came over together without form- ing any union,, as they ought, on the common prin- ciples of chemillry, to have dune ; though our author is at a lofs to know wliy they did not unite, unlefs they were prevented by the fmall quantity of inflam- mable air which came over along with them. From the beginning of the iQlh meafiirc, a black, eharry, and greafy matter began to line the conical tube and air-veffel adapted to the retort ; and as the procefs went on,, the proportion of alkaline air de- creafed, while that of the inflammable air was aug- mented, until towards the end, when the lafl nine meafures were all inflammable ; after which no more would come over, though the retort was urged with a- white heat. On breaking the dift.illing veflcl, a black powder weighing 9,5 grains was found in it. On digefting this for an hour in ten ounces of diftilltd wa- ter, and then filtering and evaporating it to two oun- ces, a yellowifn powder was precipitated, bnt no cry- ftals were formed after Handing a whole night. This powder was then feparated by filtration, and the liquor evaporated to one ounce; during which time m.ore powder was precipitated^ Jt was then filtered a fe- eond time, and the liquor evaporated to half an ounce; S T R Y. PradJce, dried, amounted only to one grain, had a fhining ap- Calculus, pearance, and felt v.n-y foft, not unlike mica in pow- "v der. It was not changed, but rather looked whiter by expoling it to a fi;;rce heat for ten minutes. Ii diffolved in diililled water without being precipitated by caulllc volatile alk-rli. Mineral alkah', acid of fu- gar, and nitrated terra pondcrofa, rendered the folu- tion turbid; whence our author inferred,. that the pow- der in queftion was felenite. After the feparatir)n of this powder, the remaining, folution was evaporated to drynefs with a gentle heat. During the evaporation it continued to emit fubatid vapours, leaving eleven grains of a powder of a dirty yellow colour, having an aluminous talle. To this powder he added as much diftiiled vvaier as was nearly fuflacient to diffolve it; after which it was fet by for three weeks. At the expiration of this term feveral fmall, tranfparent, and cubical cryilals appeared on the hde of the veifcl above the furface of the folution j and thcfe hkewife had an aluminous tafle. The whole was then diffulvtd In diililled water, and the folatloa filtered. Acid of fugar produced no change in tlie liquor for at leaft five minutes, but an Immediate cloudinefs took place -^n a mixture with volatile alkali j. and on filtering the Uquor it was again rendered turbid by mineral alkali, though the caullic alkaii already predominated. Nitrated terra pondcrofa threw down a copious precipitate, and PruHian alkali difcovercd a frail quantity of iron. Tuis aluminous folution left, a yellow fubilance on the filter ; which, when col- lefted and dried, weighed only half a grain : it dif- folved without eftcrvelcciice In nitrous acid; acid of fugar caufed no precipitation, but cauftic volatile al- kali threw down a precipitate which difTolved in dif- tilled water. Tiils folution was rendered turbid by the acid of fugar and murluted terra pondcrofa, bift no. effe6t was produced by caullic volatile alkali or lime-water. The yellow powder firft depofited by the folution weighed two grains and a half, and by expofure to a flrong heat acquired a deep orange colour. On dl» geillon with diililled water, the iufoluble part w;is re-- duced to three-fourths of a grain, and appeared to be iron ; while the foluble pari was foui^ to be nothing, elfe but gypfum. Our author, however. Is of opinion,, that this iron is Impreguated with a fmall portion of vitriolic acid, though not in fuch quantity as to ren- der it foluble. The charred matter remaining in the. retort was reduced by lixiviatlan with water to 80 gi-ains. Thefe wei-e calcined with a red heat in an open fire, but could, not be reduced to a grey powder in lefs than, three quarters of an hour. Wheii thoroughly cal- cined and cold, it weighed only 21 grains, which com- municated to hot diltilled water a limy tafle, and gave, it the property of turning fy rup: of violets .green. Di- • luted vitriolic acid had no effoA upon it, bvit it was rendered turbid by ae;-ated volatile alkali and acid of fugar. The remainder -^hen well dried weighed 16 grains, which diflblvcd in niti-ous acid at .firlt with a- little effervefcen'je ; and when this ceafed, the folution went on very flowly, until the whole was taken up. -when it began to depofit a white powder, and to em.it Acid of fugar made no change in the hquld, but the a fubaoid allvingent vapour, not unlike that of vitrio- whole'was precipitated by cauflic volatile alkaU. Pruf- iic acid. This white precipitatej. when wafhed and fwu alkali threw, down a grain,, or perhaps more, of blue • / Pra(51ice. C H E M I Cnlculus. blue ; the precipitate digcfted vv'ith diftilled vinegar lofi: ^ ' ♦ ' a grain and an half, which was thrown down by cauilic volatile alkali. The infoluble part being wafhed and digelted in diililled water for half an hour, was partly dilFolved ; the folution was not affc'tled by'cauftic vo- latile alka'i, but acid of fugar and nitrated terrra pon- derofa cauTed an immediate cloudinefs. Seven grains Hi 1464 account ' parts. of its com- and an half of the powder, which was infoluble both in acetous acid and diftilled water, were readily taken up by diluted vitriolic acid, and precipitated by caullic vo- latile alkali: the 16 grains laft treated, therefore, ap- peared to contain, of clay 74- grains ; of felenite, fix grains; magnefia, one and a half; and of iron, one grain. The proportions of the different ingredients in the whole ^Iculus, therefore, according to Mr Higgins, arc as follow: Grains. 1 I 74 8 5 il- 59 Iron Stlenite Clay Alum Pure calcareous earth Aerated magnefia Charry combuftible fubftance In all 94-^ '465 In this experiment, a darkifh yellow fublimate adhe- xpen- ^j^^ neck of the retort ; the inner part next the ments on o i l a r i m r the fubii- retort more compact, but the rcit or a lamellar ipon- mate ari- gy texture. This fubli mate-, when carefully coUedtedj .'^V'" was found to weigh 425 grains, and readily diiTolved «icn' in eight ounces- of liot dillilled water. A coally fab- ftauce was feparated from this folution by filtration, which, when wafhed and dried, weighed ten grdir.;;, and when expofed to a red heat burned with a green- ilh fl:i'me, emitting white fumes, which fmelled like vi- triolic fal ammoniac : the refiduum after calcination weighed half a grain, and was of a whitifh colour ; appearing infoluble in diitilled water, but dilTolving with efFei vefcence in nitrous acid. Acid of fugar cau- fed a very fmall precipitation, which did not take place until the mixture had ftood for fome time ; but cau- ftic volatile alkali inftantly threw down a precipitate, which was taken up, when wafhed, by the acetous a- oid. The quantity was too fmall to be examined with greater accuracy ;. but it feemed to poffefs the proper- ties of magnefia. The faline folution had the colour of fmall beer ; and, when, evaporated to two ounces, did not depofit any fediment, or yield any cryftals. The black matter with which the conical tube and air vef- fel were lined, weighed 28 grains, and adhered fo f.ift ^ to the glafs, that it was impoflible to coUeft the whole from the fragments of the glafs. When diflfolved in diftilled water and filtered, four grains of coals, fimi- lar to that obtained from the former, were procured ; but no figns of cryitallization were obferved after eva- Jjaration to one ounce, and fufFering the liquor to ftand aJl night. By this treatment, the folution acquired the confift- cnce of treacle ; fo that it was plainly not cryftallizable, and therefore its analyfis was plainly to be attempted after a different method. It was now put into a tu- bulated glafs retort, together with fix ounces of di- ftilled water to wafh It down. By diiiillation in a fand- batli three ounces of water were procured, which dif- S T R Y. J73 ft.red in nothing from common diftilled water, but in Calculus, being coloured with a fmall quantity of the folution ' v from the neck of the retort. On changing the recei- ver, about half an ounce of liquor of th^ fame kind came over, after which the diftiUation began to be at- tended with an urinous fmell. This continued barely perceptible for fome time ; but when about an ounce and an half had pafTed over, it became ib very pun- gent, that our author could no longer doubt of its being in a caullic ftate. A fmall quantity of mild al- kali, however, adhered to the lower part of the neck of the retort, fome of wiiich was wafhed down by the d'fliilation ; fo that the proportions betwixt the two could not be afcertained. The volatile alkaline folu- tion in the retort had the colour of fpirit of hartihorn,- and like it becamt darker coloured by the contact of air ; on account of the evaporation of part of the al- kali, and the reft becoming lefs capable of fufpending, the coaly matter mixed with it. After all the liquor had pafTed over, and nothing, remained in the retort but a fmall quantity of black matter, the fire was raifed ;- and, as the heat increafed,. this black fubllance acquired a white colour, with a kind of arrangement on the furface, which was occa- fioned by the heat applied to the bottom of the retort being only fufficient to raife the fait to the top of the matter in the retort ; but as the fand became nearly red-hot, white fumes began to appear, which conden- fcd on the upper part of the retort, and a little way down the neck. The procefs lafted until the matter was nearly red-hot, when the fumes ceafed, and no- thing more paffed over. The fublim.ate, when col- lected, was found to weigh 72 grains, a black porous btittle fubftance remaining on the bottom of the re- tort, which weighed 12. grains. This refiduum, when expofed to a flrong heat, emitted white fumes, with a flight alkaline fmell ; by which procefs it was redu- ced, with very little apj>earance of combuftion, to a grey powder weighing three grains, which was acci- dentally loft. Five grains of this purified fublimate, mixed with as much quicklime, emitted no fmell of volatile alkali; and, when thrown upon a red-hot iron, emitted white fumes. Tue fame efFefh was produced by a mixture of equal quantities of vegetable alkali and fublimate. The remainder, confifling of 62 grains,, was divided into two equal parts ; the one of which was mixed with tv/o ounces of diftilled water, and on the other was poured 60 grains of vilrriolic acid diluted with half an ounce of water. Thefe two mixtures being fuffered to remain for fix weeks, feeined to be but- little ailed upon. That with vitriolic acid was thea put into a fmall matrafs, and boiled on fand for half an hour with two ounces of diftilled water, when the whole was taken up. The folutioa.looked clear, and. depofited nothing on ftanding. Mild mineral alkali, had no effeft upon it ; but mild vegetable alkali threw down a copious fediment in white flocculi, which waa- rediffolved by cauftic alkali, lime-water, and partly by. mild mineral alkali. Ehlogifticated alkali, acid of fu- ^. gar, and acid of tartar, had no effeft upon it. The - * other portion of fublimate, which had been mixed., with diftilled water, was very little difTolved ; but in pouring it into a matrafs fome fmall round lamps were obiervdble on the battora of the glafs. Thefe w ere Experi £id. 574 C H E M I Calculus, fix or fevcn In number, fome weighing a whole grain, others not more than one-half. They were very hard and compafl, with a fmooth furface, and in figure re- fembling the nucleus of the original calculus. The whole was then put into a matrafs with about three ounces of water. On boiling it on fand for three quarters of an hour, about one-half of it was taken up ; the folution pafled the filter very clear whilft hot ; but on cooling became turbid, and at laft de- pofited white flocculi, which were redilTolved on the addition of cauftic volatile alkali and lime-water. It turned fyrup of violets green ; which, however, our author thinks might have been occafioned by its re- taining volatile alkali, though it had not the fmallefl appearance of any fuch impregnation. He has never- thelefs frequently obferved, that fometimes the pureft vegetable alkali contains volatile alkali, notwithltand- ing the various operations and degrees of heat it un- dergoes before it can be brought to the degree of pu- rity at which it is called fait of tartar. On filtering the folution to feparate what had been depofited by cooling, no change was produced in the filtered liquor by mineral alkali ; but mild vegetable alkali produced a cloudinefs, which was inilantly taken up on adding mineral alkali and lime-water. Neither Pruffian alkali, nor the acids of arfenic, tartar, fugar, or borax, nor any of the three mineral acids, had any effe6t upon it. 2. An hundred and twenty grains of the fame cal- ments withculus were put into a tubulated glafs retort, and half nitrous a- ounce of ftrong nitrous acid poured upon it. An elFervefcence immediately cnfued ; and fome part of the extricated aerial fluid being preferved, appeared to be fixed air mixed with a fmall quantity of nitrous air. When the effervefcence ceafed, a quarter of an ounce more of nitrous acid was added. On digefting the mixture upon hot fand for an hour, it emitted nitrous vapour and nitrous air ; but the latter in very fmall proportion. When the folution was completed, the whole was poured into a fmall matrais, and gently boil- ed till the fuperabundant nitrous acid was nearly ex- pelled. The folution was of a deep yellow colour and turbid ; but on adding five ounces more of water, and digefting it for a quarter of an hour longer, it acqui- red the colour and confiftency of dephlogifticated ni- trous acid. On cooling it became fomewhat turbid, and in a few days depofited a darkilh yellow powder ; which, when feparated, wafh^d, and dried, weighed little more than a quarter of a grain, and, on exami- nation, was found to be a calx of iron. Our author being defirous to know what efFeA the on expofure fun would have upon it, placed it in a window where to the fun. jhe fun fhone full upon it for four hours every day. Here a littk moillure feemed daily to exhale from it^ the weather being hot, and the matrafs, which had a /hort wide ne-ck, being only covered with bibulous pa- per to keep out the duft. In this fituation, in the pourfe of a week, a few very fmall .cryftals appeared ■ to float upon the furface. Thefe in time fell to the bottom, where they adhered together fo as to'form a hard concretion, ftill retaining a cryftalline appearance, but fo finall and confufed, that it was impolTible to di- ftinguifli their figure ; and this depofition of cryftals xrontinued for a month, after which it feemed to ceafe. yjie folution vvas then filtered to feparate the fait i af- Cryftallizcs S T R Y. Praaice. ter which one-half of the liquor waa evaporated away, Calculus, and the reft fet in the ufual place for a fortnight long- ^— ^ er, but no more cryftals appeared. The fait, which weighed three grains, was then digefted in four ounces of diftilled water ; but no part feemed to be diffolved. Three ounces of the water were then decanted off, and fix drops of vitriolic acid added to the remainder, which by the help of digeftion feemed to ^ilfolve the fait flowly ; but on adding half an ounce more diftil- led water, the whole was readily taken up. Acid- of fugar had no effedl on this folution ; but lime-water rendered it turbid. The whole was then precipitated with cauftic volatile alkali, and the folution filtered, which likewife threw down the lime from lime-water. The precipitate was then waftied, and diftilled vinegar poured upon it, which did not take it up ; but it was diflcilved by marine acid. Phlogifticated alkali had no eScSt upon it ; and the acid of fugar occafioned very little cloudinefs after ftanding three or four hours ; from which our. author fuppofed that the matter was phofphorated clay. The folution, being now free from iron and phof- phorated clay, had a fubacid tafte, and looked clearer, though ftill retaining a yellow caft. Acid of fugar had no effect upon it ; but nitrated terra pbnderofa threw down a precipitate, as did likewife the cauftic volatile alkali. Mild vegetable alkali caufed no preci- pitation ; which our author attributed to the folution of the manganefe and clay by the fixed air extricated from the alkali. Two- thirds of the folution were then put into a fmall glafs retort, and two ounces di- ftilled ofi^, which had no tafte, but fmelled very agree- ably, and not unlike rofe-water. After all the liquor had palfed over, white fumes appeared in the retort, and thefe were foon followed by an aerial fluid. Oa collecting fome of this, a candle was found to burn in it with an enlarged flame. Nitrous air did not dimi- nifh it in the leaft ; and it feemed to be that fpecies of air into which nitrous ammoniac is convertible. No more than 13 or 14 inches of this kind of air could be obtained ; and as foon as it cealed to come over, cryftals were obferved in the lower part of the neck of the retort. On augmenting the heat, a white fait began to fublime and adiiere to the upper part of the retort | the operation was continued until the re- tort was red-hot ; but, on breaking it, the quantity of fublimate was fo fmall, that very little of it could be collefted ; though, from the fmall quantity obtain- ed , our author was convinced of its heing the fame in quality with what was obtained in the former analyfis. The fait which cryftallized in th« neck of the retort was nitrous ammoniac, as appeared from its detona- tion J)er fe, &c. A grey powder was left in the bot- tom of the retort, which hot diftilled water partly dilfolved : muriated terra ponderofa, acid of fugar, and vegetable alkali, rendered this folution turbid ; but cauftic volatile alkali had no effeft upon it. The re- maining part of the powder which was left by the di- ftilled water, readily diflblved with effervefcence in the marine acid, and was precipitated by cauftic volatile alkali ; the part foluble in diftilled water appearing to be gypfum, and that foluble in marine acid to be mag- nefia. From all thefe experiments, Mr Higgins concludes the compofition of the human calculus to be vaftly dif- 5 fere at for diffol ▼iBg it Pradice. C H E M Calculus, ferent from what cither Mr Scheele or Mr Bergman have fuppofed it to be. *• It appears (fays he), that H'^t'^^' calculus was compofed of the following different account % Compounds blended together ; wa. felenite, alum, the conft-- microcofmic fait, mild volatile alkali, lime, and caullic tutnt parts volatile alkali, combined with oil, fo as to form a fa- ©f calculus, ponaceous m fs; calx of iron, magnefia combined with aerial acid, clay enveloped by a faponaceous and oily matter, and the fubllmate already defcribed." Confi- dering this to be the true ftate of the calculus in the bladder, the fmall proportions of clay, felenite, mag- nefia, and iron, which are the moft infoluble of the ingredients ; the great folubility of microcofmic fait and alum, and the mifcibility of lime, volatile alkali, and oil, in water ; tend to {how, that the fublimate is the ce'mcnting ingredient. Indeed, its infolubility in water, and property of forming nuclei out of the body, as above obferved, leave no room to doubt it. The proportion of the other ingredients, and very likely their prefence, depend upon chance, volatile alkali and oil excepted ; therefore this fublimate fhould be the 1469 obje£t of our inveftigation. Remarkfon Mr Higgins concludes his differtation with fome the reme- praftical remarks concerning the remedies proper for dies proper difTolvingr the ftone, for counteraftins; that difpofition m the body which tends to produce it, and concern- ing the regimen proper for thofe who are to under- go the operation of cutting for it. " The effe£l of mild mineral alkali (fays he) on the fublimate, is well worth the attention of thofe who may have an opportunity of trying its efficacy. Mild mineral al- kali may be taken in large dofes, and continued for a length of time with impunity to the moft deli- cate conftitutions, only obferving a few circumftances; but this alkali, in a caullic ilate, muft veiy often be attended with mifchievous confcquences. Befides, if we cohfider that it muft enter the mafs of blood before any pait can reach the bladder, and the fmall portion of the dofe taken fecreted with the urine, and, laftly, the aftion of cauftic alkali upon animal fubftances ; we fhall be at a lofs to know on what principle cauftic alkalies have been recommended in preference to mild. Soap itfelf might as well be recommended at once ; for foon after cauftic alkali is taken, it muft be in a faponaceous ftate. Fixed vegetable alkali fhould be avoided, and the preference given to the other two al- kalies. As it is evident that alkalies have no real ac- tion on the ftone in the bladder, though their efficacy has been experienced in alleviating the difeafe when timely adminiftered, their mod^ of a6lion is only ex- plicable in the following manner : They either prevent the generation of the fublimate in the fyftem, or elfe keep it in folution in the mafs of fluids ; and being in the utmoft degree of divifibility, its ultimate particles are capable of paffing through the nioft minute emunc- tori'es ; by which means it is carried off by other fecre- tions as well as the urinary. Thus the urine, not be- ing faturated with this matter, a£i:s as a folvent on the &one ; and as the moft foluble parts are firft wafhed away, it falls through time into fragments of irregular furfaces, which by their friilion initate and inflame the bladder, as has been obferved by feveral pracli- tioners» " Allowing that the fublimate is the cementing fub- ftance in the calculus, and judging, from the effedts of 575 Calculus. I S T R Y. alkalies upon it, their modus operandi in the conftitu- tion, it remains now to inquire into the origin of the calculus. Mr Scheele has found this fublimate in the urine of different perfons ; and hence inferred, that it was a common fecretion : but it ftill remains to be af- certained, whether there be a greater quantity of it procured from the urine of patients who labour under this diforder than in thofe who do not ? If this fliould not be the cafe, may not a deficiency of volatile alkali in the conftitution be the caufe of concretions in the kidneys, bladder, &c. ; or, which muft have the fame effeft, too great a proportion of acid, which, uniting with the alkali, may take up that portion which would have kept the fubhmate in folution until conveyed out of the fyltem by the urinary and other fecretions ; and may not this be the phofphoric acid ? If this latter ftiould be the cafe, an increafe of microcofmic fait mufl be found in the urine ; but if the former, a decreafe of the volatile alkali, and no increafe of the neutral fait. The fmall quantity of phofphoric acid found in the calculus proceeds from the folubility of micro- cofmic fait. Do not volatile alkali and phofphoric acid conftitute a great part of the human frame ? and is there not a procefs continually carried on to gene- rate thefe in the fyftem ? and is not this procefs liable to be retarded or checked by intemperance, &c. which may vary their quantities and proportions ? and may not a due proportion of thefe be neccfiaiy to a vigo- rous and found conftitution ? If fo, no wonder that an increafe or deficiency in either or both of thefe fhould be produftiveof feveral diforders." On this fubjedt, however, our author has not had fufficient leifure to make the experiments neceffary for its elucidation. Indeed,, it feems not eafy to do fo y as, in his opinion, at leaft 500 would be required for the purpofe. " That the urinary fublimate is prefent in tubercles found in the lungs of perfons who die ofo /r pulmonary confumptions, and likewife in what are of caiculus^ vulgarly called chalk Jones, is what I have experienced : found In b\it in what proportion, or whether in quantities fuf- c""fump- ficient to caufe the concretion, is what I cannot fay ; ^"'^ for I have had but a few grains of each to examine, pie"*^^ I have every reafon to fufped, that confumptions and fcorbutic complaints very frequently arife from a fu- perabundance of this fubhmate in the fyftem j and that it is chiefly the caufe of the gout and rheumatifm, and folely the caufe of the ftone in the bladder. I make no doubt but thefe diforders generally proceed from- obftrudlions ; and it is probable, that either a preci- pitation of this fubhmate in the fyftem, or elfe a de- ficiency of fome other fecretion, which would. hold it in folution until conveyed out of the body, may be the- chief caufe of thofe obftruaions ;. and likewife, that, different degrees of precipitation may produce different" fymptoms and difordera. " That mineral or volatile alkali and bark have been ufeful in the above diforders, has been affirmed: by experienced phyficlans ; and I know an inftance myfelf of mineral alkali and nitrous ammoniac being-; ferviceable in a pulmonary complaint, of fome ftand- ing. " With refped\ to the ftone, when it acquires a cer- tain magnitude, it is abfurd to attempt to diffolve it in the bladder, it waftes fo very flowly ; and during- this time the patient muft fuffer vaft pain, particularly- whea 576 ^ C H E M Vitriolic when the ftone acquires a rugged furface : therefore cutting for it at once is much pi-eferable. " Mineral alkali taken in the beginning of the com- plaint, and before the ftone accumulates, will no doubt check its progrefs, and may in time change that dif- I S T R Y. Praaicc. poiltion in the habit. Patients' who are ctit for the Nitrouj ftone fliould, I think, take mineral alkali for foine time when the woimd is healed ; but not before, for fear of bringing on a mortilication/' A'--d. R N D I X Containing fuch Discoveries as have appeared fince the Compilation of tlie Article, and which could not be inferted in their proper Places. M7I ■^'arious methods of reftifying vitriolic ether. iWr Hig- giiib's ob- ifetvations. ■1473 Account of its coiifti- tnent parts by M. La- voifier. 1474 By Mr Ca- veiidilh. T. Vitriolic Etkkr^ MPelletier formerly propofed a trtetliod of rec- • tifying this fluid by putting manganefe into the veflcls ; but as the vitriolated manganefe might perhaps comminiicate fome injurious quality, another method is propofed by M. Tingry. After firft draw- ing off the ether, he adds a diluted folution of volatile alkali, and avoids as much as poffible the difiipation of the vapours : the ether is then rediftilled. It may afterwards in this way be wafiied more fafely, and -with lefs lofs. The little proportion of the ether nvhich is feparatcd in the water, mny be again recover- ed, or the water may be again employed for the fame ■purpofe. M. l.unel propofe-R calcined magnefia fot this purpofe, as its fait is net loluble ; though perhaps -pure terra ponderofa might be better. II. Ni TROt' s ^ c I D- On this fubjeft Mr Higgins has fcveral curious and interefting obfeivatioir?. " It is not an eafy matter (fays he), to afcertain exaftly the grsateft quantity of dephlogifticated air, which a given quantity of nitroua acid may contain. I always found nitre to vary, nut only in its produA of phlogifticated and dephlogiiticated air, but likewife in their proportion to one another. The pureft nitre will yield, about the middle of the procefs, dephlogifticated air fo pure as to contain only about ^ of phlogifticated air. In the beginning, and near- ly about the latter end of the ptoceis, air will be pro- duced about tVvice better than common air. On mix- ing the different prcduds of a quantity of pure nitre, it was found that, by cxpofure to hver of fulphur, f part was left unabforbed ; and this was the utmoll purity in which I obtained dephlogifticated air from nitre. " According to M. Lavoifier, ico grains of nitrous acid contain 79^ of dephlogifticated air, and' 204- of phlogifticated air, which is not quite four to one. But his experiments contradift this ; for whatever mode he adopted to dtrcoinpofe nitrous acid, it appeared that the proportion of dephlogifticated air was nearly as five to one of phlogifticated air. «« Mr Cav^ndifti has proved, that nitrous acid may be formed by taking the eledlric fpark in a mixture of three parts of phlogifticated air, and feven of dephlo- gifticated air, which is but ^ more of dephlogifticated air than nitrous air contains ; which may apparently contradI6l M. L?.voif!er's, as well as my own, eftimation of the proportion of the conftituent principles of ni- N'75- trous acid, when in its perfeft ftate. The red nitroxrs vapour contains three parts of nitrous air and one of dephlogifticated air, or one of phlogifticated and three of dephlogifticated air ;. but nitrous vapour may be formed with a lefs proportion of dephlogifticated air J and which, though it may not be lo condenfible as a more perfeft nitroiis vapour, yet will, when in conta£i with pure alkali, unite with it, and f"orm nitre, as was the cafe in the experiment of Mr Cavendilh. The common ftraW-coloured nitrous acid contains more de- phlogifticated air than the red nitrous acid or vapour ; the proportion appears to be about four to one ; but the colourlefs contains about five of dcphlogiRicated to one of phlogifticated air. j^y^ " Having once a charge of nItroUs and vitriolic acidMethoil in a green glafs retort, I put it in a fand pot to di- <'l>tainjng ftil ; but the pot being fmall) the edge came too "^^•"^-m-ous'^^ the retort, about a quarter of an inch or more above the charge ; which, before the procefs ^jommenced, and when it acquired more than the heat of boiling water, cracked It all round in that direftion. Being thus fituated, I was obliged to withdraw the fire, and, before the charge got cold, to ladle It into an earthen pan. On introducing it into a frefti retort, I obtained from it nitrons acid nearly as colourlefs as water. The vitriolic acid iifed in this procefs not being very per- feft, the goodnefs of the nitrous acid Was attributed to the purity of the nitre from whence it was dillilled j but in another procefs, though the fame nitre was ufed with much purer vitriolic acid, the produce was of ati high ftraw colour. On recoUefling the above-men- tioned circumrtancp, the vitriolic acid and nitre were next mingled in due proportion, and expofed in art earthen pan fet in fand, to nearly the heat of boiHng water, for half an hour or more, continually expofing freih furfaces to the air. When the charge was quite cold, I introduced it into a retort, and diililled as co- lourlefs nitrous acid as the former. As no nitrous air was emitted during dlgeftion, it muft have imbibed de- phl.-igifticated air from the atmofphcre." ^ MrProuft found, that ftrong nitrous acid will fet fire i^^J^^^'l^ to charcoal if it be rendered very dry. He hkewife re- . al on marked, that charCoal expofed to the air a few hours fire by after calcination) was unfit for the experiment. Char- »:<^^"s 0 coal, he obferves, attrafts moifture very forcibly. The^ j'^""^' fi;ft efi'eft of the charcoal on the nitrous acid, he ob- ferv:-s, is to withdraw a portion of its water from it ; by which it is rendered highly concentrated, at the fame time that the condenfatlorl of the water heats the charcoal in a fmall degree, but fufficiently to volatilize a nitious vapour ; which, as foon as it reaches that poi tion of dry Ghareoal next the humid part, is con- denfed 1 Pra^l'ice. Nitre. denfed by it, and genecates heat enough to promote '"■""v——-' the decompofit ion of the nitrous acid. Hence we fee why the experiment will not fucceed if the acid be poured on the furface of the charcoal. "Ef^call "^^^^ ^^'^^ nitrous acid on blood,- according to iiiti cu' acidMr Higgins, is very fingukn Two parts of blood -on blood, procured frefh at the butchers, one of ftrong nitrous acid, and about one fifth of the whole of water, were digefted in the heat nearly of boiling water (frefh poitionsof water being occafionally added until the whole of the acid was expelled), when it acquired almoft the colour, and exaftly the tafte, of bile. When mixed with a large quantity of water, it acquired a fine yellow colour ; and, on ftanding, depofited a fub- ftance of a brighter yellow, though the fupernatant liquor ftill retained a yellow colour and bitter tafte, but not fo intenfely as when the precipitate was fu- fpended in it. The different ftages of this procefs were well worthy of obfervation. No nitrous air was produced, and the acid was expelled ia the ftate of a white vapour. The liquor was found to increafe in bitternefs as the acidity vanifhed. About the middle of the piocefs, the folution firft tafted acid, but was quickly fucceeded by a bitter fenfation. It appears that the nitrous acid took dephlogifticated air from the blood ; for though red nitrous acid was ufed, it was expelled in a perfeft ftate. CHEMISTRY. 577 III. Nitre. ^ Though the artificial generation of the nitrous a- cid, froui a mixture of dephlogifticated and phlogifti- tated air, is now fufficiently underftood, yet we do not well know in what manner nature performs the ope- ration. Some chemifts, particularly M. Thouvenal, have found, that putrefadlion favours the produftion of nitrous acid. AH animal lubftances, during theif dccay, give out a vaft quantity of phlogiilicated air ; therefore, if dephlogifticated air be prefent, it will u- nite to the phlogifticated air in its nafcent ftate, and form nitrous acid : but Mr Higgins has obfervod, that 1478 nitrous acid may be generated in plenty where there is ^^it^e gene- putrid procefs going on. " The chemical elabo- rated with-ratory at Oxford (fays he) is near fix feet lower than Fadion ^''^ earth. The walls are Iconftrufted with common lim.eftone, and arched over with the fame ; the floor is alfo paved with ftone. It is a laro-e room, and very lofty. There are feparate rooms for the chemical preparations, fo that nothing is kept in the elaboratoi-y but the neceflary implements for con- dufting experiments. There is an area adjoining it on a level with the floor, which, though not very large, is fufficient to admit a free circulation of air. The afiies and fweepings of -the elaboratofy are depo- fited in it. There is a good fink in the centre of this area, fo that no ftagnated water can lodge there. Not- withfianding all this, the walls of the room afford frefh crops of nitre every three or four monthiSi Dr Wall, who paid particular attention to this circum- ftance, and who told me it contained fixed vegetable alkali, requefted I would analyfe it, and let him know what it contained. I found that two ounces of it con- tained fix drachms of nitrated fiy.ed vege table alkah, and three of calcareous nitre. The nitre firft appears in fmall whitifti filaments as fine as cob-web, which, when thev Vol. IV. Part II. get a httle larger, drop off ; fo that tl.ey never acquire Marine uilhcient growth to diftinguifh their figure to a naked ^cid. eye. On finding that they contained fixed vegetable — ~ alkah, I concluded that it proceeded from minute ve- getation ; but in this I was miftaken ; for I found that they were fohible in water, and that they detona- ted with charcoal at eveiy ftage of their growth. Having fwept this faline eftlorefcence from the waH I dug deep into it, but could not obtain nitre from it' \Vhen a part had been white-waftied, it yielded nitre, but not fo abundantly as a neighbouring foot which had not been treated in the fame manner. " 'Hence it is evident, that nitrous acid maybe formed without the afiiftance of putrefcent proceffes in a ftill damp air, wheie there is a fubftance to atfraft it when -lialf formed, whereby it is in time brought to perfedion. 1 he above fafts moreover prove, that fixed vegetab^ alkah is a compound." IV. Marine ^ c i Mr Higgins informs us, that he has, with a viewUnfSs- to dccompofe fea-fa't, mixed it with manganefe in va- f"' >;ftemptj nous proportions, and expofed them in a reverberatino- ^° '\.com- furnace in a well clofed crucible for three hours, to a heat nearly fufficient to melt caft iron. In the fame man- ner he treated manganefe, faltj and charcoal, as well as clay, fait, and charcoal, and fait and clay alone, with very httle fuccefs. He treated calcined bones, fait, and char» coal,^ and calcined bones and fait, as well as hme and fait, in the fame manner, without effeding any appa- rent change in the fait. He was informed, however, by Mr Robertfon, apothecary in Bifhopsgate-ftreet, that he had partially alkalized it, by expofing it with clay to a fierce heat ; but that foon after it got into con- taft with air, it became neutral again. " If common fait and litharge be fufed (fays Mr Higgins), it is in part decompofed ; the acid fuffers no decompofition, but unites with the lead ; whereby it acquires, when the faline matter is wafhed away, a yellow colour. It is evident (adds he) from thefe fafts, that the bafis of marine acid is a combuftible body, and quite different from light inflammable air, charcoal, or any known inflammable fubftance ; and that it attrads dephlogif- ticated air with greater force than any fubftance hi- therto difcovered. Though charcoal will dccompofe all other acids, except a few, when united to bodies which will fix them until they acquire k fufficient de- gree of heat, yet it has no effeft on marine acid." According to Fourcroy, if alkaline air be confined by mercury, and dephlogifticated marine acid air be added to it (which muft be done quickly, as the acid air would diftblve the mercury), each bubble produces a flight detonation, and furnifties a very amufing fpec- Though in this country the diftiUation of fpirit of m ^f'^ > fait with clay has long been entirely laid afide for theci-:r',iW procefs with oil of vitriol, yet it is ftill praftifed in 'pi it. of other countries, and may be effeded in the following '^^"^ manner r Having previoufly decrepitated the fait, and dried the clay, they are then to be ground, mixed, and fifted together. The mixture is next to be worked with a fpatula, and then with the hands, until it is brought Into a moderately ftiff and uniform mafs. 4 ^ Thi» C H E M This Is to be divided Into balls about the fize of a pl- jreon's egg, fo that they can pafs through the neck of the retort ; but before they are put into the diftilhng veffel, it is proper to dry them thoroughly. The re- torts muft be of ftone ware, and carefully coated, m order to prevent them from breaking with the intenfe heat to wlilch they are expofed. they are to be fil- led two-thirds full of materials, and the diftillation muft be performed in a reverberatory furnace. The receiver at firft is not luted on, becaufe that which rifes in the beginning of the diftillation, being very a- queous, is to be put by itfelf. When tins has come over, another receiver is then to be applied, and ce- mented with fat lute, and covered with a cloth daubed with a mixture of lime and the whites of eggs. The beat is to be raifed until the retort is red-hot, and con- tinued in this degree until the diftillation ceafes. Various proportions of clay and fait have been re- commended for this procefs ; but it feems probable that not lefs than ten parts of clay to one of fait, as Pott has direfted, will be found necefTary. Inftead of the clay, fome direft the u(e of bole ; but this is in- convenient, on account of the iron it contains. Pow- dered talc has alfo been recommended, but this is not always free from iron ; and where a very pure fpirit is wanted, there is a neceffity for having recourfe to oil ©f vitriol, and glafs or ftone-ware velfels. As the marine acid cannot be feparated from the earthy mix- tures above mentioned, but by means of moifture, M. Beaume advifes to moiften the refiduum, and repeat the diftillation, by which more acid will be obtained. As marine acid has very little aftlon upon phlogi- marine acldftic matters, it cannot therefore affeft oils, either ex- lupon phlo- prefled or eflential, in a manner fimilar to the vitriolic gillie mat- njtrous. M. Marges, however, has obferved yellow cryftals refembling amber formed in bottles, containing a mixture of oils and marine acid of moderate ftrength, which had ttood for feveral months. The little effed which the marine acid has upon thefe fubftances was firft fuppofed to be owing to its want of phlogifton in itfelf ; but when it was afterwards found, that, by the application of certain fubftances which have a great attraction for phlogifton, the marine acid was render- ed capable of uniting very readily with inflammable matters, the former theory was abandoned. It was now alferted, that the acid, inftead of containing no phlo- gifton, was naturally endowed with a very confiderable quantity ; and that, in its new ftate, it was dephlo- gifticated by the fubftances applied. On the other hand, the antlphlogiftlans afl'erted, that no change was thus made upon it, farther than adding a quantity of pure air, which they fuppofe to be the bafis of all a- cids. On this fubjea, however, M. Cornette main tains, that the marine acid feems to have fo little ac- tion upon inflammable fubftances, merely becaufe It is weaker than the reft ; and likewife that it is often prevloufly combined with fome inflammable matter, by which its attra^Ion is prevented. He maintains, that if the marine acid be concentrated in fuch a manner as to render its fpecific gravity to that of water as 19 to 16, it will then aft upon oils with heat and effervefcence, reducing them to a black and thick fubftance, and even burning them to a kind of coal Some experiments have been made by Mr HalTe, EffeiV of ters. I S T R Y. Praaice. with a view to Inveftlgate the aaionof the marine M^nne and vitrioKc acids upon balfams and oils ; for which purpofe he mixed two drachms of fmoking fpirit of fait with one of each of the oily fubftances to be tried. The refults were, that Canada balfam gained one fcruple in weight; balfam of capivi 19 grains; fto- rax, and Venice turpentine, each one fcruple ;_ afphal- tum 18 grains; but the effential oils of anife-feed, benzoin, bergamot, coriander, and many others, were not altered in any degree. The aftion of this acid ' upon inflammable matters, however, is augmented by its being reduced into the form of air. GmeUn relates, that, by diftilling a mixture of five parts of fait, twelve of fpirit of v^ine, and four of vitrio- lic acid, to which he had prevloufly added one or two parts of water, he obtained a completely dulcified l^pi- rlt of fait, and an ImperfeAly dulcified fpirit of vitriol, upon reftifying the liquor. 148* Homberg found, that glafs- was corroded by the Glp.fs cor- marine acid: and his obfervation has been confirmed by rodedby it. Dr Prieftley ; who finds that its corrofive power is aug- mented by confining the acid in tubes hermetically fealed. Its power is exerted not only on flint-glafs, but even on common green glafs ; though more power- fully on the former, where It chiefly attacks the red- lead ufed in Its compofition. By inclofing marine acid gas for fome weeks in a glafs tube expofed to heat, an incruftation was formed on the infide, while the air was diminlflied to |- of Its original bulk, one half of which was abforbed by water ; the other was phlogi- ftlcated air. Cauff of The marine acid is generally met with of a yellow or reddifti colour, which by Macquer is given as one ot ^^j^,^^ Its charafterlftlc marks. In general, however, this co- marine lour is thought to proceed from iron ; but Dr Prieftley acid. has found that it may be produced by many different fubftances ; and his obfervations have been confirmed by Scheele and other chemifts. The Doftor is of opi- nion that it is occafioned for the moft part, if not al- ways, by a mixture of earth ; and he was able to com- municate It by means of calcined oyfter-fliells, calcined magnefia, pipe-clay, or pounded glafs ; but not by wood-aflies, from whence the air had been expelled by < heat. It was effeaually difcharged by flowers of zinc, a coal of cream of tartar, and by liver of fulphur ; but he found, that the colour which had been difcharged by liver of fulphur, would return by mere expofure of the acid to the' atmofphere, but not that which had been difcharged by flowers of zinc. Dephloglftlcated Spirit of Salt. When the aftlon of this vapour upon any thing is to be examined, the fubftance muft be put into a bottle In fuch a manner as to remain in contaa with it ; or It may be put Into a glafs tube, which Is fufpetided and fixed to the ftopper, and thus introduced into the bottle. From its property of deftroying all vegetable colours, It promlfes to be of very confiderable ufe in the arts, provided It could be had In fufficient quantity, and cheap. It bleaches yellow wax, and when proper- ly applied to linen, will whiten It fufficiently, and with- out injury, in a few hours. This may be effefted by fteeping the linen for that fpace of time in water im- pregnated with the dephlogiftlcated marine gas. It unites widx this fluid rather more eafily than fixed air.. 1484 Expediti method bleachin linen. I Praaice. C H E M Marine Berthollet, in order to impregnate water with it with- S—^ l-^ out expofing the operator to the fume, which is ex- tremely difagreeable, put the mixture of marine acid and manganefe into a retort. To this he apphed firft an empty bottle, and then feveral others filled with wa- ter, and communicating with each other by means of bent tubes ; furrounding the whole with ice. When the water in the bottles was faturated, the gas became concrete, and fell to the bottom ; but with the fmalleil heat it arofe to the top in bubbles. The fpecific gra- vity of the faturated water was to that of diftilled wa- ter, when the thermometer was only five degrees above the freezing point, as 1003 to 1000. This impreg- nated water is not acid, but has an auftere tafte, and has the fame action as the gas, though in a weaker de- gree. Mr BerthoUet has obferved, that the addition of alkalies does not prevent, but rather promotes, the difcharge of colours ; for which reafon he direfts to add a fixed alkali to the impregnated water in which linen is to be fteeped for bleaching. This is the ex peditious method hinted at under the article Bleach- ing ; but which has not hitherto come into ufe, prin- cipally through the high price of the dephlogifticated gas. The dephlogifticated marine acid does not difcharge all colours with equal eafe. Thofe of htmus and fyrup of violets are entirely deftroyed, and turned white. The colouring matter of Brazil-wood, and fome green parts of plants, retain a yellow tint. The leaves of evergreen plants refift its action for a long time, and at laft only acquire the yellow colour which they affume by long expofure to the air; and in general the changes of colour which vegetable matters fufFer from this gas, are fimilar to thofe which take place on long expofure to the air ; and by this operation the gas is converted j^gj into common marine acid. Effedtofthe Oils and animal fats arc thickened by this gas j and depl],Iogift;- by thefe and other inflammable fubftances it is reduced on phloei- ^^^^ common marine acid. Light is faid to flic matter?, P'^'o verthelefs, as much of the metal is difTolved, as gives a little white precipitate on the addition of fixed alkali ; but volatile alkali does not tiirow down a blue precipitate, nor turn the folution of that co- lour. The folution of borax precipitates all folutions of copper in acids, and then the fedative fait unites with the copper in form of a light green jelly, which, after drying, is of very difficult folution in water. Bergman fays, it is of an agreeable green colour, which it preferves after being dried ; and that, when expofed to the fire, it melts into a dark-red vitreous fubftance. Wenzel afferts, that by long continued trituration of copper fihngs with fedative fait he obtained a folution of the metal, which yielded cryftals on being evaporated. With twice its weight of copper in a covered crucible, an infoluhle vitreous mafs was obtained. 10. Tin is not apparently ailed upon by boiling with fedative fait ; neverthelefs, the folution becomes turbid on the addition of an alkali. By melting the calx with half its weight of fedative fait, we obtain a black mafs like the dark coloured tin ore. By rubbing for a long time filings of tin with fedative fait and water, and afterwards digefting the mixture with heat for one day, an hard, fandy, and irregularly fhaped fait was obtained, which, by difTolution in water, yielded tranfparent, white,, polygonous cryllals ; and a fait of the fame kind was obtained from the flag produ- ced by melting equal parts of fedative fait and tin filings. 1 1. Lead is not afted upon direcftly ; but, on adding a folution of borax to folutions of the metal in vitriolic, nitrous, marine, or acetous acids, the fedative fait unites with the lead. One part of fedative fait with two of minium gives a fine, greenifh-yeilow, tranfparent, and infoluble glafs. 12. With iron. The acid of borax difTolves this metal more eafily than any other. The folution is amber- coloured, and yields an ochry fediment, with clutters of yellow cryllals containing a little iron. The metal is precipitated by borax from its folutions in vitriolic, ni- trous, marine, and acetous acids, and the precipitates are foluble in fedative fait. A folution of iron may alfo be obtained by melting this fait with iron filings, and lixiviating the mafs. 13. Zinc communicates a milky colour by digeftion with folution of fedative fait. By evaporation it affords a confufed faline mafs, and a white earthy powder by precipitation with alkali. Flowers of zinc, melted with fedative fait, form a light green infoluble flag. 1 4. Bifmuth, in its metallic ftate, is not afted upon by Xedative fait, but is precipitated by borax froni a mix- ture of vitriolic and marine acids, in form of a very Acid of Bo- white powder, which keeps its colour when expofed J!^^ to air, and melts in the fire to a white, tranfparent, and tioJ^. permanent glafs. 15. Regulus of antimony is not afted upon direftly, but 'its calx is difTolved when precipitated by borax from a folution in aqua regia. 1 6. White arfenic unites with fedative fait either in the dry or moiil way, and forms a cryftallizable compound, forming either pointed ramifications, or a white, greyifh, and yellowifh faline powder. 16. On regulus of cobalt the acid has no direft aftion ; but borax precipitates it from its folution, and the calx melts with the fait into a flag of a bluiih-grey colour; and this, by,lixiviation and evaporation, affords a fedative fait impregnated with cobalt, of a reddifh white colour, and of a ramified form. 18. Nickel h precipitated from its folution, and the fedative fait unites with it into a faline fubflance diffi- cult of folution. A variety of opinions have been formed concerning the nature of fedative fait. M. Beaume and M. Ca- det particularly have made a great number of experi- ments on the fubjeft ; but as none of thefe have led to any certain conclufion, we forbear to mention them at ,4^^ prefent. Thofe of MtfTrs Exfchaquet and Struve haveExperi- indeed eftablifhed fome kind of relation between the mentsmade acids of borax and phofphorus, and they have made [^j^^^^"" feveral attempts to analize the former, but with little nature of fuccefs. The moft remarkable of thefe experiments the fedative are the following, i. They diflilled, with a ftrongfalt. heat, two parts of phofphoric acid evaporated to the confiflence of honey, one of fedative fait, and two of water. Towards the end of the diftillation a very acid liquor was obtained ; and the refiduum was a white earth, in quantity above three-fourths of the fe- dative fait employed, and which, on examination, was found to be the filiceous earth ; the liquor which paf- fed over into the receiver being found to be the vo- latile phofphoric acid. If, in this experiment, too much phofphoric acid be added, a greafy matter re- mains; and, if too little, a part of • the fedative fait will remain undecompofed. In their attempts to com- pofe borax, they combined phofphoric acid with mi- neral alkali, the refult of which was a compound re- fembling borax in many rcfpedls. When expofed to the fire, it melts into a very fufible glafs, which has a mild tafle, and feems neutral, but, on expofure to the air, becomes moifl and acid. On being faturated with alkali a fecond time and vitrified, it again dell- quefces and becomes acid ; and the more frequently this operation is repeated, the greater is the refem- blance it bears to borax. In this experiment they fup- pofed that the alkah was decompofed, and converted into an earth fimilar to that of fedative fait. With earthy fubflances the refults were very re- markable. With, earth of alum a cryftallizable fait was obtained, which made paper burn with a greea fiame. Fixed alkali added to a folution of this fait precipitates an earth, and the fait then formed by cryftallization refembles borax in feveral pioperties. In the dry way the earth of alum, with the phofpho- ric acid, mehs into a glafs of the fame fufibiliiy as ;that of borax, and hke ii is fixed in the fire. The folution of this glafs did not cryftallize. Common clay , ^ 582 C H E M I Acid of clay digeiled with phofphoric acid produces filky cry- ■ ' ^^^^^ referabh'ng fedative fait. When dried with their * mother-water, thefe give a dear glafs, which, when united with mineral alkali, has the taRe of borax, fmells in the fame manner, and has the fame effeft up- pon metals. With litne, magnefia, and terra ponde- rofa, this acid produces fufible glaffes, infoluble in water, and which communicate a green colour to flame. Earth of bones and felenite mixed with the acid gave a white, hard, fhining glafs, like the bed cryftal, but as fufible as the glafs of borax, and which continued flexible after it had ceafed to be red-hot. Two parts of gypfum, with one of phofphoric acid, gave a milk-white glafs fit for foldering metals and enameling. In thefe experiments, however, it muft be remembered, that unlefs the heat be raifed very quickly, the phofphoric acid will be evaporated before any fufion takes place. VIII. ^ciD of Amber. It was known to Agricola, that a particular kind of fait could be obtained from amber by diftillation ; but neither he, nor any fucceeding chemift for fome time, afcertained its acid properties. On the contrary, fome erred fo far as to imagine that it was a volatile al- kali; but, about the beginning of the prefent century, its acidity began to be generally acknowledged. This property indeed difcovers itfelf by the tafte, which is manifeftly acid and empyreumatic, along with the pe- culiar flavour of amber. According to Scheele, alfo, the aqueous fluid which pafles over in the difl:illation of amber, is an acid refembling vinegar both in tafte and chemical properties ; and which of confequence ought not to be confounded with the true acid of amber, I OA which manlftfts qualities of a very difl'erent kind. Methods The properties of fait of amber ca,n hardly be in- of purifying vefl:igated until it has been purified} for which, of the fdlt of confequence, various methods have been propofed. amber. p^^^. recommends cryft.allIzation, after having filtered the folution through cotton-wool, in order to retain the oil. Cartheufer attempts the purification by dif- folving the inrpur^ fait in fpirit of wine, then dilating with fix times its quantity of water, and cryftallizing the fait. Others recommend fublimation with com- mon fait or^fand, and Bergman with pure clay. The fait of amber din'olves, by the afliftance of heat, in nitrous and marine acids, and in the vitriolic with- out heat. In none of thefe combinations, however, does it either alter the diflblvlng acids, or fufFer any alteration itfelf, except that it becomes whiter; with nitre it detonates and flies ofl^ ; and if the quantity of fait of amber his been greater than that of nitre, the latter is alkalized. Stockar informs us, that it expels the marine acid from fal ammoniac, and fubllmes be- fore thar (alt ; with which it does not form any union. Wi -m fublimed from common fait, it does not alter the latte; in any uthei refpeft than giving it a darker colour. It precipitates calcareous earth from its folution in vine- g:\r; and it decumpoles fugar ofle-ad; but the precipitate difi^ers from plumbum corneum. It does not prevent the folution of lead in the acids fea-falt and nitre; nor does it produce any fulphureous fmell by calcination with charcoal. Hence it appears that it is neither a yitriulic, nitrous, nor marine acid j and M. Bourde- S T R Y. Pradiice. lin mufl; have been miftaken, when he affirms, that, Acid of after detonation of this fait with niti-e, he obtained a^'^^ fP^^ „ , , • 1 n 1 1-1 r 1 1 .Its Comui- refiduum, which taited like common ialt, decrepita- ^j^Jq^s ted in the fire, yielded cryfl;als of a cubical form, pre- y / cipitated filver and mercury from the nitrous acid ; and thence concluded that it was the fame with acid of fea-falt.! It is very dear, as only about half an ounce can be obtained from a pound of amber. Acid of Amber combined, 1 . With Jixed vegetable alkali. By faturating fait of amber with the fixed vegetable alkali, and then flow- ly evaporating the folution, we obtain, according to Wenzcl, a light deliquefcent falinemafs ; but, accord- ing to Stockar, whofe experiments are confirmed by thofe of Mr Keir, the folution above mentioned affords ftiining white tranfparent cryftials of a triangular prif- matlc figure, with the terminating points truncated. Thefe cryftals readily diflblve in water, deliquefce in the air, and have a peculiarly bitter faUne tafte. In the fire they decrepitate, melt, and remain neutral ; though Wenzel has obferved, that with an intenfc heat they are decompofed and become alkaline. Thefe cryftals do not change aquafortis into aqua-regia ; and though they precipitate both the folutions of lead and filver, the precipitates are neither plumbum corneum nor luna cornea. 2. With mineral alkali. This combination produ- ces long three-fided columnar cryftals, intermixed with fome that are foliated. Thefe cryftals do not de- liquefce in the air, and have a faline, bitter, and fmoky tafte. They are lefs' foluble than common fait, and melt with more difficulty than nitre. They do not become alkaline on burning coals, and, in their other properties, referable the former. 3. With 'volatile alkali. This fait ftioots into acicular cryftals, having a fliarp, faline, bitter, and cooling tafte ; when heated in a filver fpoon, they melt and evaporate entirely ; in clofe vtffels they fublime. They do not precipitate folution of filver,^ nor change fpirit of nitre into aqua-regis. A powerful aniifpafmodic remedy is prepared from redlified fpirit of hartfliorn and fait of amber. 4. With lime. This fhoots into oblong pointed cry- ftals, which do not dehquefce in the air, and are fo- luble with difficulty even in boiling water ; nor, ac- cording to Mr Stockar dc Neuforn, can they be de- compofed by diftillation either with acetous or marine acids. They detonate by diftillation with nitrous acid; and are decompofed, either in the moift or dry way, by the vitriolic. When mixed with common fal am- moniac in the dry way, they fufFer a decompofition ; the fuccinated ammoniacal fait flying off, and the com- bination of marine acid with lime remaining behind. 5. With magnejia. This yields a white, gummy, frothy, faline mafs, which acquires a yellowlfli colour when dried by the fire ; and, when cool, deliquates in the air. It is decompofed by alkahes and lime, as well as by the vitriolic acid. 6. With clay. By uniting the acid of amber with an edulcorated precipitate of alum with vegetable al- kah, Wenzel obtained prlfmatlc cryftals, which could not be decompofed by alkalies. 7. With filver. The acid of amber has no effect on fiiver C H E M Acid of {Silver In its metallic flate ; but with its precipitate ioxms thin ob'ong ci yftal<;, radiatird and accumulated natbiis upon one another, fiom which the filver may be fepa- ^ raced by alkalies, by quickfilvtr, and by copper. 8. IVit/} copper. By ar long dis^eition of copper with acid of amber a green folution is obtained, which by mixture with common I'alt is rendered turbid, by vitri- olic acid white, and lets fall a green precipitate on the addition of fixed alkali. Wenzel, however, could not obtain this precipitation by alkalies. His folution yielded groups of green cryllals, gave a cruft of cop- per to zinc, and was precipitated by liver of fulphur. 9. With tron. Wenzel diffolved a precipitate of this metal in acid of amber, and from the folution obtain- ed Imall, brown, tranfparent, and ftellated cryltals. Zinc precipitated the metal, but not alkalie^;. From a nightly coloured folution of metallic iron, Pott ob- tained, by means of alkali, a white precipitate, which foQU became yellow, and at length green, by pouring water upon it. 10. With tin. Acid of amber difToIves tin when precipitated by a fixed alkali ; and the folution yields thin, broad, and foliated tranfparent cryftals. Alka- lies throw down but little from this folution ; liver of ftilphur more ; and lead, iron, or zinc, nothing. 11. With lead. Acid of amber whitens the furface of lead in its metallic Hate, but does not dilfolve it ; neither can lead be precipitated from its folutions in nitrous and marine acids by fait of amber, though this 13 denied by Pott. According to Stockar, however, it forms a white precipitate with fugar of lead. This metal precipitated by an alkah, and diffolved in acid of amber, forms long foliated cryftals lying upon one another ; from the folution of which the lead may be precipitated by alkalies in the form of a grey powder, and by zinc in its metallic Itate, 12. Zinc, in its metallic flate, is readily difiblved by the acid of amber ; and by a combination with the precipitate formed by fixed alkali, we obtain long, flender, foliated cryftals, lying upon one another. The ^ folution lets fall a white precipitate on the addition of fixed alkali ; but this is denied by Stockar, who fays that volatile alkali produces a red precipitate. 13. Bijmvth. By means of heat, Stockar obtained a folution of this femimetal in acid of amber, which was decompofed by alkalies. Wenzel obtairied, from a precipitate of bifmuth prepared by means of fixed alkali, fmall, flender, foliated, and yellow ci7ftals ; which alkalies cannot decompofe, though black pre- cipitates are thrown down by lead and zinc. 14. Regidui of antimony. Little ot none of this fe- mimetal, in its regidine form, is diffolved in the acid of amber ; but it attacks the precipitate made with fixed alkali. This folution is very copioufly precipi- tated by liver of fulp'rut, but not by alkalies. The combinations of this acid with gold, platina, nickel, arfenic, and manganefe, have either been found imprafticable, or not yet attempted \ all thofe above delcribed are non-dehquefcent, and part with their acid when expofed to fire. The eledtive attraftions of this acid, according to Bergman, are fingular, as it adheres more ftrongly, not only to terra ponderofa and lime, but to magnefia, than to fixed alkali. On the origin of fait of amber, Mr Keir remarks, that it deferves to be cor.fidered as a pure and di- I S T R Y. 583 ftinft acid. No proofs have been adduced of its being Acid of a modification either of the marine or vegetable acids, -A™^*^'"^"^ as MrCornette and M. Hermbftadt have fuppofed. n^don" ' The former, having diftilled fpirit of fait with oil of — lavender, obtained an acid which fmcUed like fait of 1495 amber, but on examination was found to retain the On the na- properties of the muriatic acid. He alfo relates, that, ^"ff when purifying a confiderable quantity of the fait of^g).^ amber which he had prepared himfelf, fome fea-falt was feparated, which in the diftillation had arifen along with it. But this obfervation cannot be juftly applied to fliow any refemblance betwixt thefe two, any more than the fmell in the former cafe could {how an analo- gy betwixt it and oil of lavender. This mixture of fea-falt with acid of amber, however, may readily ex- plain the millake of M. Bourdelin already mentioned. M. Weftrumb and M. Hermblladt have both laboured in vain to convert the acid of amber into acids of fu- gar and tartar by frequent diftillations with fpirit of nitre ; and their want of fuccefs confirms the account already given, that the acids of nitre and amber have no ailion upon each other, farther than that the for- mer is phlogifticated or changed into red fumes," and the latter becomes whiter. Neverthelefs, if Mr Scheele'g obfervation of the identity of the acid liquor, which comes over in the diftillation of amber with acetous acid, holds good, we {hall have the beft reafon yet given to afcribe the origin of this acid to the ve^>;etable kingdom ; and when we confider the very different properties that are affumed by the vegetable acids, which, however, are convertible into one another, no reafon can be drawn trom the diyerficy of its pro- perties with thofe of other vegetable acids, againil its having •» common origin with them. Indeed the na- tural hiftory of amber, its fimilarity to gums and re^ fins, and its involved infefts, afford other arguments in favour of the opinion. IX. Acid of Arsenic. M. BerthoUet remarks upon Mr Scheele*s pro- M. PelTe* cefs, that during the operation a great quantity of '^j^r's me- dephlogifticated air is expelled from the acid. M. |.^^fj,'^^ fj^"" Pellctier has found another method of procuring the arfeoKal ^ arfenical acid. He mixes common white arfenic with acid, nitrous ammoniac, and diflils the mixture. At firfl: phlogifticated nitrous acid paffes over, then the vola- tile alkah, and laftly the arfenical acid remains in the retort in form of a vitreous mafs,. which deliquefcea into a very denfe acid liquor, reddening fyrup of vio- lets, and effervefcing with alkalies. M. Macquer had formerly defcribed this procefs, and obferved, that the nitrous acid paffes over firft, and then the volatile al- kali ; but was of opinion that the refiduum was no- thing but arfenic. He mentions a detonation which took place in his experiment ; but nothing of this kind was obferved by M. Pelletier ; he only informs U5,. that the nitrous acid was driven over with gieat vio- lence, while that of arfenic united with the volatile al- kali. M. BerthoUet, who has endeavoured to afcer- tain the weight gained by the converfion of fulphur, phofphorus, and arfenic, into acids, determines that of arfenic to be about one-ninth of the whole. At the fame time he obferves, that this additional weight docssv not difcover the whole weight of the air contained ia 584 G H E M I Acidxf Mn- the arfenic, as it had that neceflary to convert it into lyb and on cooling afforded feathery cryltals. Thefe when edulcorated had a fweet tafte, though lefs ftrong than that of the former fait, which afterwards be- came bitter. Their folution turned blue paper red; was precipitated, and became like ai\ emulfion with fpi- rit of wine ; and the refiduum, which did not diffolve, appeared to be of the fame niiture. The cryftals dif- folved in frefti acetous acid, and communicated a blue colour to the acid ; but this gradually difappeared 0x1 cooHng, and a glutinous matter was depofited on the lides of the veflel, which had the properties of the former fubftance of that fort. If, in place of letting tlie folution cool, it ftiould be kept boiling, the blue colour difappears, and nothing is precipitated. By ad- ding fpirit of wine when the liquor is almoft evapora- ted to drynefs, a white powder is precipitated ; which, after being edulcorated with frefli fpirit of wine, taftes exceedingly bitter, and is very foluble in water. This Jolution, however, does not redden blue paper, nor make a blue with vinegar. With vitriolic acid its lolution is blue ; with vitriol of copper it forms a white precipitate. All thefe falts, by calcination, firft be- come blue, then yellow, and laftly white. 7^ On pouring a quantity of lime-water upon the folution of the precipitate formed by the nitrous acid, as well as on thofe obtained by the acetous acid, white precipi- tates wei-e formed, all of which were a true regenera- ted tungften. Having afterwards impregnated the li- -quors with Hxed air, and boiled them in order to pre- cipitate the lime more completely, they found in the •Vol. IV. Part XL I S T R y. folutions, after they were filtrated and evaporated to Acid of drynefs, neutral falts formed of the precipitating acids, 'I'^^^'g' en. joined with alkaline and calcareous bales. This pro- ved, that both alkali and acid were concerned in the- precipitation. 8. On pouring the vitriohc folutions of iron, copper, and zinc, as well as that of marine mercu- rial fait, alum, and Pruffian alkali, upon the folution of the precipitate formed by the nitrous acid, no pre- cipitation enfues, and the acetous falts of copper and lead give white jxecipltates ; but the Pruflian alkali forms no precipitate with the acetous falts. Hence it appears, that this fait is not a fimple acid, but rather a fait compofed of the yellow matter, fixed alkali, and the precipitating acid; and its compofition appears more fully from the following experiments with the volatile alkali. 1. The yellow powder diffolves entirely in volatile alkali, but without any perfedt faturation taking place ; and the alkali always prevails. 2. The folution being fet in a faud-bath, produced needle-like cryftals, which had a fharp bitter tafte, exciting a difagrceable fen- iation in the throat. Their folution turned the tinc- ture of turnfole red, and the Hquor from which they were cryftallized had the fame properties. 3. Having repeated this operation with different quantities of the fame cryftals, leaving fome longer on the fire than others, folutions were obtained, whofe acidity was In proportion to the time tbey had remained on the fire ; but during the operation they all emitted the fmell of volatile alkali. By calcination this alkali was entirely dlfTipated, and the refiduum wjm a yellow powder, per- fedly fimilar to that with which the operation was be- gun. On making ufe of a retort for the operation, the remaining powder was blue. 4. This fait precipi- tates the vitriolic falts of iron, copper, zinc, and alum, calcareous nitre, marine mercurial fait, the acetous falts of lead and copper ; and with lime-water regene- rates tungften. The vitriohc acid decompounds it, and forms a blue precipitate ; the nitrous and marine acids produce a yellow ; but no precipitate isoccafiou- edby the Pruffian alkali. Having poured nitrous acid upon a portion of the folution with excefs of alkali, a white powder was pre- cipitated, which, after edulcoration, had a tafte at firft fweet, but afterwards fharp and bitter, and its folution turned the tindlure of turnfole red. This, on exami- nation, appeared to be a triple fait formed of the yeUow powder, volatile alkali, and the precipkatlng The following experiments reahze the conjefture of a IdJd'of Bergman, that the acid of tungften is the bafis of a fciiiimetal particular femimetal. procurable 1. " Having kept too grains of the yellow powder 5[°"' '""^'^ (fays M. Luyart) in a Z^mora crucible well covered, and fet the whole in a ftrong fire for half an hour, it became a fpongy mafs of a bluifii black colour, the furface of which was cryftallized into fine points, like plumofe antimony, and the infide compact, and of the * fame colour. It was too hard to be broken in pieces by the fingers ; and, when ground, was reduced to a dark-blue colour. 2. " Having mixed 100 grains of the fame powder with 100 of fulphur, and put the mixture in a Zamo- ra crucible on a ftrong fire for a quarter of an hour, it came out a dark-biue mafs, which was eafily bioke by 4 E the 85 C H E M I Acid of the fingers ; and the Infi^e prefcnted a cryftalHzatbn Tungden. needles as the laft, but tranfparcnt, and of the ^"^"''r^ colour of a dark lapis lazuH. This mafs weighed 42 grains, and when placed on burning coals yielded no fmell of fulphur. _ 3. " Having put another 100 grains of this powder into a Zamora crucible, provided with charcoal, and well covered, and placed it in a ftrong fire, where it remained an hour and a half, we found, on breaking the crucible after it was cool (a), a button, which fell to powder between the fingers. Its colour was dark brown ; and on examining it with a glafs, there was feen a congeries of metallic globules, among which fome were the bignefs of a pin's head, and wheal broke had a metallic appearance at the fradure in colour like Heel. It weighed 60 gr.ilns ; of courfe there was a di- minution of 40. Its fpecific gravity was 17.6. Having calcined part of it, it became yellow, Avith ^^ increafe of wei"-ht. Having put one portion of this fubftance powdered, in digeftion with the vitrioHc acid, and another with the marine acid,, neither of them fufFcred more diminution thaji tIo of their weight;- then de- canting the hquor, and examining the powder with a glafs, the grains were ftill perceived of a metallic a- fpea. Both the acid liquors gave a blue precipitate with the Pruffian alkali, which let us know that the fmall diminution proceeded from a portion of iron which the button had undoubtedly got from the pow- der of the charcoal in which it had been fet. The ni- trous acid, and aqua-regia, extrafted likewife from, two other portions the ferruginous part ; but befides, they converted them into yellow powder, perfedly fimilar to that which we ufed in this operation. 4. " Having put 100 grains of gold and fifty of the yellow powder in a Zamora crucible furniflied with charcoal, and kept it in a ftrong fire for three quarters of an hour, there came out a yellow bvitton, which crumbled in pieces between the fingers ; the infide of which fliowed grains of gold, feparated from others of a dark-brown colour. This demonftrated there had not been a perfed fufion, and likewife that this fubftance was more refraAory with gold, fince the heat which it endured was more than fufficient to have melted it. The button weighed 139 grains; of eouife there was a diminution of n grains. Having put this button with lead in the cupelling furnace, the gold remained pure in the cupel ; but this operation was attended with confiderable difficulty. 5. Having made a mixture of platina and yellow powder in the preceding proportions, and expofed it to a ftrong fire, with the fame circumftances, for an hour and a quarter, it produced a button which crum- bled with eafe between the fingers, and in which the grains of platina were obferved to be more white than ufual, and fome of them, changed fenfibly in their fi- gure. This button weighed 140 grains, and of con- fequence there had been a lofe of 10 grains. When calcined, it took a yellow colour, with very little in- creafe of weight } and after wafliing it to feparate the platina, there remained 1.18 grains of a black colour. S T R Pra«flice. Having placed this portion again to calcine over a ^ Acid of ftrong fire in a muffle, it fuffered no fenfible alteration Tur.gften. ftrong in weight or colour ; for it neither grew yellow, nor took the brown colour of the platina, but kept the fame blacknefs as before it was calcined. It muft be attend- ed to, that in the wafhings there was not fo much care taken to coUedl all the platina as to deprive it o£ the yellow colour, and for this reafon the water car- ried off part of the fine black powder ; and confequent- ly the increafe which the platina preferved, after being, wafhed and calcined the fecond time, ought to be com- puted more than the 1 8 grains which it Ihowed by it«- weight. " Having mixed the yellow powder with other me- tals in the preceding proportions, and treated them in. the fame manner, the refult was as follows : 6. " With filver it formed a button of a whitifh-brown colour, fomething fpongy, which with a few ftrokes of a hammer extended itfelf eafily, but on continuing them fplit in pieces. This button weighed 1 42 grains, and is the moft perfed mixture we have obtained, except that with iron. 7. " With copper it gave a button of a copperifh red, which approached to a dark brown, was fpongy,. and pretiy dudlle, and weighed 133 grains. 8. " With crude or caft-iron, of a white quality, it gives a perfed button, the frafture of which was corn- pad, and of a whitifh brown colour : it was hard^ harfli, and weighed 137 grains. 9. " With lead it formed a button of a dull dark- brown, with very little luftre ; fpongy, very dudile, and fplitting into leaves when hammered: it weighed 127 grains. 10. " The button formed with tin was of a Hghtcr brown than the laft, very fpongy, fomewhat dudile^ and weighed 138 grains. II . " That with antimony was of a dark-brown c«- lour, fliining, fomething fpongy, harfli, and broke in. pieces eafily : it weighed 108 grains. 12. " That of-bifmuth prefented a fradure, which,, when feen in one light, was of a dark-brown colour, with the luftre of a metal J and in another appeared like earth,' without any luftre :. but in both cafes one could diftinguifh an infinity of little holes over the whole mafs. This button was pretty hard, harfli, and weighed 68 grains.. 1 3. " With.manganefe it gave a button of a dark bluifli-brown colour and earthy afped ; and on exa- mining the internal part of it with a lens, it^ refem- bled impure drops of iron: it weighed 107 grains." XI. ^CJD o/Jnts. Etmuller is among the firft authors who mentions the exiftence of this acid,, and fpeaks of obtaining it by diftillation. Nothing of its properties, however,, was known, until Margraaf undertook to examine it ; of whofe experiments we have an account in the Memoirs of the BerHn Academy for 1749. Since his time a number of chemifts have profecuted the fubjed to Ya^ « The firft time we made this experiment, we broke the crucible without letting it cool entirely ; and': as foon as the matter was in-contad with the air, it took fire, and its dark brown colour turned xnftantly yel. Pra<51ce. G H E M I S T R Y. Acid of to a confiderably greater length ; but Mr Keir prefers Ants. ^jjg refearches of Arvidfon, Bucljoltz, and Herrabftadt, to the reft. The acid in queftion is a natural juice which the in- fers difcharge when irritated, and which is very pun- gent to the fmell as well as tafte. Thus it _ may in- ftantly be perceived on turning up an ant-hill in fpring er fummer. The formica rubra of Linnjeus are thofe infefts which have hitherto fuppHed this acid. Mr Ar- methods'of vidfon advifes to colled them in the mouths of June obtaining: and July, by laying feme fmooth fticks upon an ant- this acid. . vvhich being then diilurbed, the ants will run upon the fticks in great numbers, and may then be fwept off into a veflel containing water until it be full. Henubftadt coUefts them in the fame manner, but into a dry bottle, to avoid the evaporation of the fuper- fluous liquid. Bucholtz having moiftened the inlide of a narrow necked glafs bottle with honey and water, funk it into a difturbed ant-hill until the mouth was level with the ground ; on which the infedls, allured by the fmell of the lioney, went into the bottle, and could not get out. For obtaining the acid, Margraaf employed diftd- lation, with the addition of frefh water. Thus he ob- tained, from 24 ounces of frefh ants, 1 1 ounces and two drach-ms of acid, fome volatile alkali, empyreuma- ti« oil, and a refiduum containing earth and fixed fa^t. Arvidfon made ufe of two methods : One confifted in dittilling the ants when dry ; from a pound of which, in this ftate, he obtained eight ounces of acid befidcs the empyreumatic oil. His other method was to in- clofe, in a piece of linen, the ants preyioufly cleaned by waflung in water, then to pour boiling water upon them, and to repeat the operation until it could ex- traft no more acid ; which is then obtained by fqueezlng the linen, mixing all the liquors, and filtering theiii. Thus froni a pound of ants he obtained a quart of acid liqtfor, which tafted like vinegar, but was fpecifically heavier. By diftlUatlon Hermbftadt obtained from a pound of dry ants ten ounces and a half of yellow em- pyreumatic liquor, which did not tafte more ftrongly acid than the fpirit obtained by dIftiUing wood, on which fwam three drachms of a brown fetid oil, in all refpeds like that of hartfhorn. In the retort was left a black refiduum weighing one ounce fix drachms, which exhibited figns of containing volatile alkali. By dlftllling a pound of ants with three of water, according to Mr Margraaf's method, he obtained an acid liquor and fome oil in the receiver ; and from the furface of that which remained undiftlHed, he coUeded a draehm and an half of ftit oil. The fpecific gravity of the acid liquor obtained by Mr Arvidfon 's maceration was i.ooii ; that of the fame liquor, when diftilled, 1.0075; and of the acid concentrated by freezing, 1.0453. _ According to Bucholtz, the acid liquor thus obtained by macera- tioa did not grow in the leaft mouldy in the fpace of iour weeks ; during which it was allowed to reft in order to free itfelf perfedily from the impurities it con- tained. Mr Hermbftadt, however, prefers Margraaf's method of diftillatlon to that of Arvldfon's macera- tions, not only as being a more perfeft analyfis, but as Icfs laborious; though he finds fault alfo with Mar- graaf's method, as diluting the acid too much, and al- tering It fo that it has hoI the fmell of living ants. He totally difapproves of the method of diftlUIng dried ants, as the acid is thus in a great meafure decom- pofed, and the remainder united with much oil. To avoid all thefe inconveniences, he contrived another method, namely, to exprefs the juice of the infedls ; by which means he obtained at once a concentrated liquor fit for diftillatlon. In this way he obtained from two pounds of dried ants 2 1 ounces and two drachms of juice, which had a pungent and highly acid fmell, re- fembling the vapours of fluor acid; In tafte refembling concentrated vinegar and acid of tartar; to which laft it might be compared for ftrength of acidity. By di- ftilling eight ounces of this expreffed liquor, he ob- tained fix ounces and a half of clear acid, equal in ftrength to a very concentrated vinegar. The acid, when thus procured in purity, has a pun- Properties gent, not unplcafant fmell, a fliarp, cauftic tafte, and^t die pure an agreeable acidity. It reddens blue paper, fyrup of **^'^* violets, and litmus ; blackens the vitriolic acid, and converts part of it into a fuiphureous vapour. It is aU fo decompofed by diftillatlon with nitrous acid. Spirit of fait likewife, when dephlogifticated, decompofes it, but not in its ordinary ftate. It does not form fulphur by an union with phlogifton, but produces Inflamma- ble vapours by diffolving iron or zinc. By the af- fiftance of a gentle heat it diffolves foot, but oils with much more difficulty, and powder of charcoal not at all. It does not unite with vitriolic ether ; but in di- ftilling a mixure of this acid with fpirit of wine, Mr Arvidfon faw fome traces of an ether, and .M. Bu- choltz perfeftly fucceeded in making an ether by means of it. It unites with fixed alkah, forming, according to M. Margraaf, a neutral fait, conftfting of oblong de* liquefcent cryftals, from which very Uttle acid could be procured by diftillatlon per fe ; but ofi adding con- centrated oil of vitriol, a very ftrong and pure acid was obtained ; from a mixture of which with fpii lt of wine, M. Bucholtz readily obtained a true ether. With mineral alkali it forms deliquefcent foliated cryftals of a faUne bitter tafte, and foluble in twice their weight of water. With volatile alkali it fonns an ammonia- cal Hquor ; which, according to Arvidfon, cannot be brought Into a dry ftate ; but Mr Arvidfon fays he has obtained cryftals from it, though very thin and deliquefcent. Margraaf obtained dry cryftals by uni- ting this acid with chalk or coral ; and Arvidfon ob- ferves that this fait Is tranfparent, cubical, or rhom- boidal, nondeliquefcent, foluble in eight parts of water, of a bitter tafte, and Infoluble in fpirit of wine. No acid can be obtained from it by diftillatlon per fe. From a folution of magnefia in this acid, Mr Arvidfon ob- tained fome fahne particles by depofition, and after- wards an efflorefcencc of traniparent fait rifing round a faline mafs. This fait had fcarcely any tafte, was foluble in 1 3 parts of water, and infoluble in fpirit of wine. With ponderous earth the acid formed a clu- fter of bitter needle-Uke cryftals, which did not deli* quefce, were foluble in four times their quantity of water infoluble in fpirit of wine, and when burnt gave out a fmell Hke that of burnt fugar, leaving a coal which effervefced with acid. It unites with diffi- culty to the earth of alum, and can fcarcely be faturated with it. It does' not precipitate filver, lead, or mercury, from their folution in nitrous acid ; whence it feems to have no affinity to the ma- 4 E 3 rine 588 C H E M Acid of ni,e acid : and as it does not precipitate lime from the . marine acid, it feems to have as little with the vitriolic. 1504 From his experiments, however, Margraaf conclud ed, Hasan affi- that the acid of ants, in m^ny refpefts, though not in ^thl a ^^^ allj lias a great affinity with the acetous acid. From acid. ^'"^ diftinguifhed by forming different compounds, and likewife by having different afSnities. It dif- lodges the acetous acid alfo in all inilances, and the arfenical acid from cobalt and nickel. It has a great- y^p^ er attradlion for fixed alkalies than for lime. Its effedls ^ folvent it afts but weakly upon copper ; not •II metals, at all, or very little, on filver, lead, tin, regulus of an- timony, or bifmuth, but ftrongly on iron or zinc. It diffolves, however, the calces of copper, filver, zinc, and lead, without affefting thofc of tin, regulus of an- timony, or bifmuth. The calx of quickfilver, accord- ing to Margraaf, is revived by it. According to Ar- vidfon, it eryflallizes with iron, zinc, or lead ; does not aft upon the regulus of antimony, of arfenic, co- balt, or nickel ; though it diffolves, their calces as well as the precipitate of manganefe. Gold, mercury, and the calx of platina, are not affcAed by it ; but it eryflallizes with thofe of copper, filver, lead, bifmuth, and mercury. In its ftrength of attraftion, the acid of ants ex- j^j^g ceeds thofe of vinegar, borax, and the volatile fulphu- Acid pro- reous and nitrous acids. Infefts amied with flings, cured from as bees, wafps, and hornets, are likewife faid to dif- v^ious m- charge a very acid juice when irritated ; and Mr Bon- *' net has obferved a very llrong acid ejefted by a cater- pillar which he diflinguifiies by the name of grande che- nille clu faule a queu fourchtie. None of thefi;, however, have been as yet particularly examined. XII. Acid of Apvles. That the juices of unripe fruits contain fome kind of acid has been univerfally known, and attempts to invefligate the nature of it have been made fome time j^Q^ ago : but it is to Mr Scheele that we owe the difco- Acld of ci- very of the particular acid now treated of. He had troiis how obferved that the juice of citrons contained a particu- procured. j^j- ^^id ; which, by being united with lime, formed a fait very infoluble in water ; and which therefore by means of lime could be readily feparated from the mucilaginous part of the juice. By adding vitriolic acid to this compound of lime with the acid juice, al- moft in the fame manner; in v,'hich he ufed to procure the acid of tartar, the lime was again feparated, and the pure acid of citrons obtained. Proceeding in the fame manner with other fruit, he found that an acid, agreeing in every refpeft with that of citrons, could be procured from the juice of the rihes grojfularia. Examining the juice which' remained after the fe- paration of the former acid from the citrons, he found that it flill contained another acid; which being o faturated with more calcareous earth, formed a fait Another eafily foluble in water, and therefore remained fufpend- acid procu- ed in the juice. To feparate this new fait, he added red from fome fpirit of wine, by which the fait was precipita- the i»ice of ^^^^ finding: that it flill contained much gummy matter, he judged that it v^'ould be proper to attempt a feparation of this gum before he precipitated the fait. For this purpofe he evaporated fome of the juice of the ribes groffulai-ia to the confiflence of honey, diffolving I S T R Y. Practice. the mafs afterwards in fpirit of wine. Thus the acids, -^crd of which are foluble in the fpirit, were eafily feparated , Apples. ^ by filtration from the infoluble gum. He then eva- * porated the fpirit, adding to the remainder twice its quantity of water, with as much chalk as was necef- fary for the faturation. The liquor was next boiled for two minutes ; during which the infoluble fait was precipitated, and the liquor feparated from it by fil- tration contained the folution of chalk in the new acid. To this folution he added fpirit of wine, which again precipitated the fait, while fome faponaceous and faccharine matters remained diffolved in the fpi- Having thus at lafl; obtained the fait in a ftatc of pu-lts proper- rity, he proceeded to examine its nature ; and found, ties. I. Thai fome of it, fpread on his nail, loon dried, and afliimed the appearance of varnifh. 2. It was very foluble in water, and turned litmus red. 3. When the folution had flood fome days expofed to air, it was found to have depofited a number of fmall cryflals, which could only be diffolved by a quantity of boiling water ; and this fait was alfo found to be completely neutralized, fo that it yielded its calcareous earth to a fixed alkali. 4. The fait was decompofed by heat- ing per fe in z. crucible, and left a milcj calcareous earth. 5. The acid was feparated from the earth by adding oil of vitriol diluted with water until gypfum was no longer precipitated, and the new acid was left difengaged, fo that it could be feparated by filtration. 6. By this operation, however, all the lime was not precipitated, fo that the feparation of the acid was not complete. 7. He obferved that the acid had a greater attradiion for lead than for lime ;. and therefore made ufe of the m.ethod he had formerly difcovered for fe- parating the acid of forrel. To the acid he added a folution of fugar of lead;, by which the acid was preci- pitated along with the lead, and the vinegar was left ,^,0 in the liquor. To this precipitate, cleaned from How pro- the acetous aeid by filtration, he added vitriolic acid, cured in which expelled the weaker vegetable one, and thus j.^j''^'^'^^*^ left it quite pure and free from any heterogeneous mixture. The juice of apples, either ripe or utirspe, was found to contain no acid of citrons, but a large quantity of the new acid; which, being thus alone, he could more eafily procure by a fingle operation. The befl method of procuring this he found to be by faturating the juice of the apples with a folution of fixed vegetable alkali, and pouring a folution of fugar of lead to that of the fait jufl mentioned. The effeft of this was a double decompofition, and a preciptate of lead com- bined with the new acid. To the edulcorated pre- cipitate he then added a dilute vitriolic acid till he could no longer perceive any fweet tafle in the liquor ; for the firfl portions of the vitriolic acid diffolve a part of the calx of lead, and impart a fweetlfh tafle to the liquor, which is fenfible, notwithflanding its acidity ; but when the quantity of vitriolic acid is fufficient to faturate the whole of the calx, all the metal falls to the bottom, and the fweetnefs ceafes ; fo that the acid is at once obtained pure. j^jj The acid of apples is poffeffed of the following pro- Properties perties. i. It cannot be cryllalHzed, but always re-^^f 't when mains in a liquid flate ; or, if much evaporated, at- tradls the moillure of the air. 2. With fixed alkalies of api ks. Pradlice. C H E M Produced nitrous a' •id of all kinds it forms dellqiiefcent falts. 3. With cal- careous earth if for s fraail irreajularly fhaped cryftals, which cannot be 'JifTo' /ed but in a large quantity of boiling water ; hat iP the acid is fuperabundant, the fait readily difiolvesin lime-water. 4. It is affefted by ponderous earth in the fame manner as by lime. 5. Earth of alum forms, with the acid of apples, a fait not very foluble in water. 6. Wiih magnefia the acid forms a deliquefcent fait. 7. Iron is diffolved into a brown liquor, which does not eryftallize. 8. The fo- lution of zinc affords fine cryftals. 9. On other me- tals it has no remarkable effefts. From the acid of citrons it differs, i. The acid of citrons fhoots into fine cryftals. 2. The acid of apples can be eafily con- verted into that of fugar, which Mr Scheele could not accomplifli with that of citrons; though Mr Weftrumb has fince done it. 3. The fait formed with the citron acid and lime is almoft infoluble in water ; but that with acid of apples and lime is cafily foluble. 4. Acid, of apples precipitates mercury, lead, and filver, from their folution in nitrous acid, and likewife the folution of gold, when diluted with water ; but the acid of citrons does not alter any of thefe folutions. 5. The acid of citrons feems to have a greater attraillon for lime than that of apples. It is remarkable that this acid is the firfl produced in fi om fufjar the procefs for making fugar. If a diluted acid of b;- means of nitre be drawn off from a quantity of fugar until the mixture becomes a little brown, which is a fign that all the nitrous acid is evaporated, the fyrup will be found to have acquired a fourifh tafle ; and if, by means of lime, we next feparate all the acid of fugar, another will ftill remain, which diffolves the calcareous earth. When this acid is faturattd with chalk, and the folution filtered and mixed with fpirit of wine, a coagulation takes place. On feparating the curdled part by means of a fieve, diffolving it in water, and then adding fome vinegar of lead, the calx of lead will be precipitated ; and if the new acid is then feparated from the metal by means of diluted oil of vitriol, it will be found to poffefs all the properties of the acid of apples, ar>d is indeed the fame. The fpirit of wine, which has been employed to precipitate the calcare- ous fait, leaves on evaporation a refiduum of a bitter tafte, very deliquefcent, and limilar to the faponaceous extraft of the citron. The following are the refults of Mr Scheele's ex- periments with the nitrous acid upon different fub- ftances. i. From gum Arabic he obtained both the Bients with acid of apples and of fngar. 2. The fame products nitrous acid were obtained from manna. 3. From fugar of milk f "Kft*" he obtained not only its own peculiar acid, but thofe ances. ^£ apples and fugar. 4. Gum tragacanth, during its folution in nitrous acids, lets fail a white powder, which was found to be the acid of the fugar of milk. This gum contained alfo the acid of apples and of fu- gar, and a fait formed from lime and the acid of ap- ples. 5. Starch left an undiffolved matter j which be- ing feparated by filtration, and vvafhtd, refemblcd a thick oil like tallow, which, however, was found to be very foluble in fpirit of wine. By dittillation he obtain- ed fron^, this oily matter an acid fimilar to that of vine- gar, and an oil which has the fmell of tallow, and con- geals by cold J and, befides the£e fubltances, he found I S T R Y. 389 that flarch yielded the acids of apples and fugar. Acid of 6. From the root of falep he obtained the acid of ap- , Ap j iles. pies, with a large quantity of calcareous faccharine ^ fait. 7. Extraft of aloes indicated the exiftence of the acids of fugar and apples, and loft the greatcft part of its bitter- tafte. During the digeftion a refi- nou3 matter was feparated, which fmelled like flowers of benzoin, and took fire on being heated in a re- tort. 8. Extraft of cclocynth was converted by ni- trous acid into a refinous fubftance, and fhowed fome figns of containing acid of fugar. 9. The extrafts of Peruvian bark and of the other plants examined by Mr Scheele, gave both the acids of apples and fugar. 10. Thefe two acids were likewife obtained from an infuiron of roafted coffee, evaporated to the confiftencc of a fyrup. 11. The fame produfts were obtained fr-om an extraft of rhubarb, which yielded alfo a refinous matter. 12. Juice of poppies afforded the fame refuhs. 13. Extract of galls did the fame. 14. The effential oils afforded little or none of the acids ; but the oil of parfley feeds feemed to be entirely convei-tible into them. 15. With a very concentrated acid he was able alfo to dtcompofe ani- mal fubftances. From glue he thus obtained fine cryftals of acid of fugar, and afterwards acid of apples. Ifinglafs, whites and yolks of eggs, afforded the fame produfts. From all thefe fubftances, efpecially the laft, a fat matter was feparated : but it was remarkable that the gas, expelled during the procefs, was com- pofed of a little fixed air, a gr eat quantity of phlo- gifticated air, and very little nitrous air ; whereas no phlogifticated air is obtained in the ufual procefs for preparing acid of fugar. He obferved alfo, that in the procefs for this acid, a fmall quantity of vioegar is found in the receiver. He could not obtain the acid of fugar from the faponaceous extraft of ur ine ; but got infttad of it a fait, which, when completely purified, refembled exaftly the flower:s of benzoin. The fame fait is precipitated in abundance by adding \ to the extraft of uririe a little vitriolic or marine acid ; and Mr Scheele had already remar ked that the fame fait is obtained in the diilillation of fugar of milk. From the various experiments which have been made r,c\i^* ... ^ ^ . -K/r rr • i - "J' the na- on thrs acid, it teems, accordrng to Mr Kerr, to be mture uf thi» an intermediate ftate betwixt acid of tartar and acidaciJ. of fugar. This, however, ought not to prevent it from being accounted a feparate and diftinft acid, otherwife we might confound all the vegetable acids with one another. It approaches more nearly to the nature of acid of milk than of any other. From this alfo, however, it is diftinguifhed„ becaufe the fait formed by the union of acid of milk with lime is fo- luble in fpirit of wine, but n6t that from hme and the acid of apples. According to Mr Hermbftadt, if three parts of fmoking nitrous acid be abflrafted from one part of fugar, and if the brawn acid mafs which remains in the retort be diluted with fix times its weight of diftilled water, and faturaced with chalk, two compounds will be formed ; one confifting of the acids of tartar and lime, which will precipitate ; and the other of lime and the acid of apples, which will remain fufpendcd. If the calcareous earth be preci- tated from this latter folution by adding acid of fu^ gar, a pure acid of apples will be left in the liquor £ ondi 590 Acetous A' cid. G H E M I and he further infontis us, that this acid of apples may be changed entirely into thofc of fugar and vinegar, by means of ilrong nitrous acid. 15 » 5 How to cryftallize fpiritus acid com- bined with calcareous earth. XIIT. JcETovi Acid. It is generally believed, that the combination of this acid with volatik -alkali is altogether incapable of cryftallization ; but Scheffer and Morveau informs Mindereri. ti^at Jt may be reduced into fmall needle-(ha- ped cryftalcj, when the fpiritus Mindereri is evapo- rated to the confidence of a fyrup, and left expofecl to the cold. The fah has a very (harp and burn- ing taRe, but a confiderable quantity is loft during the evaporation. Weftendorf, by adding his concen- trated vinegar to volatile alkali, obtained a tranfparent liquor which did not cryftallize. By diftillation it went over entirely into the receiver, leaving a white fpot on the retort. A faline tranfparent mafs, how- ever, appeared in the receiver under the clear fluid. On feparating it from the liquid, and expofing it to a gentle heat, it mehed, threw out white vapours, and in a few minutes fhot into ftiarp cryftals refem- tling nitre. Thefc remained unchanged in the cold ; but when melted with a gentle warmth, fmoked and evaporated. Their tafte was firft fharp and then fweet. yifi The fait formed by uniting acetous acid with cal- the'^acet"ous careous earth has a (harp bitter tafte, and {hoots in- to cryftals fomewhat refembling ears of corn. Thefe do not deliquate in the air, unlefs the acid has been fuperabundant. They are decompofed by diftillation J>er fe, the acid coming over in white inflammable va- pours fmelling Hke acetous ether, fomewhat empy- reumatic, and condenfing into a reddifli brown li- quor. By reftification this liquor becomes very vo- latile and inflammable; on adding water, it acquires a milky appearance, and drops of oil feern to fwim upon the furface; a reddifh brown liquor, with a thick black oil, remain after reftification in the retort. On mix- ing this calcareous fait with that of Glauber, a double decompofition takes place ; we have a gypfum and the mineral alkali combined with acetous acid. By calcination, the mineral alkali may be obtained from thi« fait in a ftate .of purity. This acetous calcareous fait is not foluble in fpirit of wine. On faturating this acid with magnefia, and evapo- rating the liquor, we obtain a vifcid faline mafs hke mucilage of gum arable, which does not fhoot into cryftals, but deliquefces in the air. It has a fweetifh tafte at firft, but is afterwards bitter. It is foluble in fpirit of wine, and parts with Its acid by diftillation without addition. Acetous acid diflblves zinc both in its metallic and calclform ftate, and even when mixed with other me- tals. By concentrated vinegar the zinc Is diflblved with great heat, fulphureous fmell, and exhalation of inflammable matter. By this union we obtain a con- gealed mafs, which on dilution with water flioots into oblong fliarp cryftals at the firft cryftallization, and afterwards into cryftals of a ftellated form. From this liquor indeed cryftals of various forms have been ob- tained by different chemifts. Monnct obtained from it a pearl-coloured fait In friable talky cryftals ; which ^vhen thrown on the coals, fulminated a little at firft, 1517 With mag- neiia. With zinc. S T R Y. Praaice. and gave a bluifli flame, and then melted, letting Its Acetous A» acid efcape, while a yellow calx remained. Hellot . ^I*^' . informs us, that this fait by diftillation J>er fe into wa- * ter, affords an inflammable liquor, and an oil at firft yellow and then green, with white flowers burning with a blue flame. Weftendorf obtained no oil in thia diftillation, but fome acetous acid ; a fweet-tafted em- pyreumatic liquor Impregnated with zinc ; fweet flowers, or fublimate, foluble in water, and burning ■ttrith a green flame. On applying a ftronger heat, the zinc was fublimed in its metallic form, leaving a fpongy coal at the bottom of the retort. The folu- tion gives a green colour to fyrup of violets, lets fall a white precipitate on the addition of alkalies or an infufion of galls. It Is not precipitated by common fait, vitriolated tartar, vitriolic or marine acids, blue vitriol, or corrofive fublimate ; but forms a red pre- cipitate when added to folution of gold ; a white pre- cipitate with folution of filver ; a cryftalline pearly precipitate with folution of mercury; and cryftalline precipitates with folutions of bifmulh and tin. Ac- cording to Bergman, It is decompofed by acid of ar- . . . . Though regulus of arfenic Is not foluble in this its pheno- acid, it^ calx maybe diflblved either In common or mena with diftilled vinegar. M. Cadet obtained a fmoking liquor by diftillation from a mixture of white arfenic and terra foliata tartari. This experiment has been re- peated by the chemifts of Dijon, and attended with the following curious circumftances. '* We digefted (fay they), in a fand-bath, five ounces of diftilled vi- negar on white pulverized arfenic ; the filtrated liquor was covered, during evaporation, with a white faline cruft. Of this fubftance were formed 150 grains; on which fixed alkali appeared to have no eff'efk, and ' which was at firft confidered as pure arfenic. How- ever, a cat, which had fwallowed 72 grains of it, was only affefled with vomitings that day and the next, ^ and afterwards perfeftly recovered. A fimilar dofe vinegar was given to a little dog ; but as he ran away, thefuppofed to eff"e6l it had upon him could ROt be difcovered ; but ^'^ anti- he returned afterwards in good health, and "^v^'^ ^"fg^j^j ^'"^ fhowed any uneafinefs : whence It may be concluded, that vinegar is in fome meafure an antidote againft the pernicious qualities of arfenic. " On redifl()lving this faline cruft in pure water, filtering and mixing it with liquid alkah, an irregu- larly cryftaUized fait was formed in It after a few days ftanding. By this fait a yellow precipitate was thrown down from the nitrous folution of filver ; whereas the folution of arfenic and terra foliata tartari threw down a white one. " Equal parts of terra foliata tartari and arfenic, di- ftilled in a retort, gave firft a fmall quantity of limpid liquor with a penetrating fmell of garHc, and which had the property of reddening fyrup of violets ; while folution of arfenic In water turns that fyrup green. The vinegar which now arofe was not faturated with arfenic, but effervefced ftrongly with fixed alkali, with which it became turbid, but did not let fall any pre- cipitate. Oh changing the receiver, there came over a reddiflr brown liquor, accompanied with thick vapours, diffufing an Intolerable fmell, in which that of arfenic could fcarcely be diftinguiflied. On continuing the operation, a black powder fublimed into the neck of the Praaice. C H E M Acetous A- the retort, togetlier with a little arfenic in its metal- lie form, and a matter which took fire by a lighted candle like fulphur. " The red liqiior ftill preferved Its property of fmo- king though cold ; diiFufing at the fame time its pe- culiar and abominable fetor, from which the apart- ment could fcarcely be freed in feveral days. This liquor does not alter the colour of fyrup of violets, but efFervefces flightly with fixed alkali, letting fall at the fame time a yellow precipitate, which, however, difappeared on an attempt to feparate it by filtration. M. Cadet had obferved, that the fmoking liquor £aa^°"*' of arfenic did not kindle at the approach of a lighted ' candle ; but that, on pouring it from the receiver into another velTel, it had kindled the fat lute with which the junftures had been clofed, and which had been dried during the opeiatlon : but we, being defirous of examining more fully the nature of the red liquor which collefts at the bottom, and has the appearance of oil, having decanted that which fvvlms on the top, and poured the remainder on a filter of paper, before many drops had palled, there arofe a thick fmoke forming a column from the veflel to the ceiling; a flight ebullition was perceived at the fides of the vef- fel, and a beautiful rofe-coloured flame appeared for a few moments. The paper filter was burnt at one fide, but moft of it was only blackened. After the flame was extingulflied, a fat reddlfli matter remained; which, being melted on burning coals, fwelled confiderably, emitting a white flame. It then funk, and left on the coal a black fpot^ which could not be effaced but by the .mofl. vehement fire. " At the time thefe obfervattons were made, the liquor had been diftllted for three weeks, and the bot- tle frequently opened. The inflammability could not proceed from the concentration of the vinegar : for the rofe- colour of the flame, the precipitation of the fublimate, and the fixity of the fpot remaining on the coal, evidently fliowed that the two fubftances were in a ftate of combination ; which is alfo further evinced by the lofs of the inflammable property wlven the li- quor was decompofed by fixed alkali. — The fmell of the liquor, however, though fo intolerably fetid, was attended with no other inconvenience than a difa* greeable fenfation in the throat, which further flirengthens the fufpicion that vinegar is an antidote againit arfenic. " The faline brown; mafs remaln'ng In the retort was partly diflolved by hot water ; and the filtrated lixi- vium was very limpid, but emitted the peculiar fmell of the phofphoric liquor. By evaporation it yielded a fait which did not deliquefce in the air, of an ir- regular ftiape ; and which being put on burning coals, did not fmell fenfibly of arfenic ; loft its water of cry- ftallization ; and became mealy and white without be- ing diffipated by heat. On expofing the refiduum to the air, it was found next day refolved into a liquor; whence it is probable that mofl: of it was compofed of cryitallized alkali, having received from the decompo- fition of the vinegar as much fixed air as was necef- X5ja fary for Its ci-yftallization." IffeiSl of ^ This acid does not a£l upon mercury in Its metal- lie ftate, but diflblves the mercurial calces, as red pre- SQSrcury. eipitate, turbith mineral, and the precipitate formed I S T R. Y . 591 by adding fixed sdkali to a folution of mercury In ni- Acetous A- trous acid ; with all which it forms white, fliining, . fcaly cryftals, like thofe of fedative fait. Vinegar does not adi upon filver in its metallic ftate, q^^^ ^ijygj^ but readily dlfTolves the yellow calces precipitated from its folution in nitrous acid by microcofmic fait and volatile alkali. By the help of a boihng heat al- fo it very coploufly dilTolves the precipitate obtained by means of a fixed alkali. The laft mentioned folu- tion yields Ihlning, oblong, needle-fliaped cryftals, which are changed to a calx by means of feveral acids, efpecially the muriatic. The filver is thrown down In its metaUic form by zinc, iron, tin, copper, and quick- filver. _ , I5'24. Though the acetous acid has no- effed upon gold in On Goid» its metaUic ftate, yet a folution of this metal is de- compofed by crude vinegar, which produces both a metallic precipitate and dark violet-coloured powder. DirtlUed vinegar throws down the gold in its metallic form. The precipitate by fixed alkali digefted with acetous acid is of a purple colour. This, as well as fulminating gold, is dilfolved by Weftendorff"'s con- centrated vinegar ; the fulminating gold very eafily.. The folution is of a yellow colour ; and with volatile alkali affords a yellow precipitate ; with lixivium fan- guinis, a blue one ; both of which fulminate. The dry fait of gold diflblves in the acetous acid, and pro- duces ablong yellow cryftals. ^ This acid has no effeft on fat oils^ farther than that, On inflam*. when diftilled together, foi»e mixture takes place, as mable fub«, the Abbe Rozler has obferved. Neither does diftil- dances* led vinegar aft upon eflfentlal oils, though M. Weften- dorff's diftilled vinegar diflolved about a fixth part of oil of rofemary, and about half its weight of cam- phor. The latter folution was inflammable, and let fall the camphor on the addition of water. The a- cid diflblves all the true gums, and fome of thofe cal- led gum-refins, after being long digefted with them. By long boiling, Boerhaave oblerves, that it diffolves the bones, cartilages, flefli, and ligaments of animals. ^^^g The concentration of this acid may be effeded by Concenrra* combining it with alkalies^ earths, and metals. By tion of the combining it with copper, and then cryftalllzing andac^'^usa- dlftlUIng the compound, we obtain the acid in the'^' * higheft ftate of concentration in which it is ufually met with. To produce this ftrong acid, we have only to diftlll verdegris, or rather its cryftals in a retort. The operation muft be begun by a very gentle fire, which brings over an aqueous liquor. This is to be fet afide, in order to procure the more con- centrated acid, which comes over with a ftronger fire. On changing the receiver, and augmenting the heat,, we obtain a very ftrong acid, which comes over partly in drops, and partly in white vapours. It is called radical vinegar, or fometlmes fpirit of Venus, and has a very pungent fmell, almoft as fuffbcating as that of volatile fulphureous acid. As the laft portions of it adhere pretty ftrongly to the metal, we are obliged to raifc the heat to fuch a degree as to make the retort quite red, in order perfectly to feparate them. Hence fome part of the metal is raifed along with the acid, which, diflblving in the receiver, gives the liquor a greenifli. colour ; but from this it may be eafily freed by a fe- cond diftillation, when it rifes with a very gentle heat^ 3, ^nd: 592 Acetous A cid. Of its cry- ilallization. T5a8 Difference between ra- dical vine- gar aiul common a- cctouii acid CHE M I ■and becomes cxlr; incl\- white. Cryftals of vcrtlegris afford about one r.alf their weight of radical vinegar ; but verdegris ili .If much Icfs, and of a more oily qua- lity. If this acid be heated in a wide-mouthed pan, ami fire applied to it, it will burn entirely away like fpirit of wine. This obfervation we owe to the count de Lauragais, who has likewife obferved, that it is capa- ble of cryftallization. This, how^evcr, takes place only ■with the laft portions which come over, and the cryltals appear in the form of plates or needles. The mar- quis de Courtrivon, who has repeated and confirmed the experin\ent of the count de Lauragais,. fujjpofes this phenomenon to be owing to a fulphiu-like mixture of acetous acid and pldoglfton. Leonhardi fuppofes an analogy between thefe cryftals and the white fait of ■copper expelled at the end of the operation by the count de LafTone. Tliis fait was at firft very white, and fixed on the neck of the retort pretty thick ; but imlefs quickly collected, was foon deftroyed by the lucceeding vapours. When expofed to the air, it attra£ls moifture, and runs into a greenifh liquid. It is uncommonly light, and in fuch fmall quantity, that fcarce five or fix grains can be collecled from a pound of verdegris. Its tafte is acid^ auftere, very un- pleafant, and permanent. It readily and totally dif- lolves in water, and partially in fpirit of wine, leaving a yellow powder totally foluble in volatile alkali, and which burns with a green fiame. From this fait, vola- tile alkali acquires a blue colour, and. litmus a red one ; and thus it difcovers itfelf to be compofed of acetous acid and copper. Experience has (hown that radical vinegar differs confiderably in its properties from the common acid. It has a greater attraction for alkalies, forms with them more pcrfetl combinations, and is lefs volatile. M. BerthoUct obferves, that when vinegar concei*.ra- ted by froll and radical vinegar, are reduced to equal denfitieSjby adding water to the heavier of the two, they differ very much both in fmell and talle. LafTone found, that radical vinegar formed a cryflallizable compound with volatile alkali ; and Berthollet has ob- ferved the fame with regard to fixed vegetable alkali. The cryftals of the latter with radical vinegar were flat, tranfparent, and flexible, flowly deliquefeent in the" air. On comparing the falts formed by the two acids, he found, that the acetous fait rendered the fyrup of violets green ; but its colour remained unaltered with that made with radical vinegar. The latter alfo re- quired a ftronger fire to expel part of its acid; it was alfo whiter, and had a lefs acid taile. On pouring radical vinegar on the acetous fait, the folution afford- ed, by evaporation and cryftallization, a fait perfeAIy fimilar to that procured direftly from radical vinegar and fixed alkali. On diltilling the mixture, the radi- cal vinegar appeared to have expelled the common a- cetous acid, as the liquor which came over eflervefced with vegetable alkali, and formed with it a terra foli- ata tartan. ** It feems probable (fays Mr Keir), that the radi- cal vinegar contains a larger portion of the aerial prin- ciple than the common acetous acid ; by which it un- dergoes a change fimilar to that of marine acid, when brought into that ftate in which it is faid tc be de- cid. S T R y. Praaice. phlogifticated. This air it may acquire from the me- '^cerous A- tallic calx, which being deprived of its air is reduced to its metallic flate. Thofe who believe in the phlo- gifton of metals, may fay that the acid is dcphlogifti- cated by imparting its phlogifton to the metal, which is thereby metallized. It appears, however, to be very diftinft from common acetous acid, and deferves to have its properties and compounds farther invelliga- ted." Concentrated acetous acid, of a great degree of How to ftrength, may alfo be obtained by diftilling terra foha- obtain it ta tartari with vitrioHc acid ; brit Leonhardi obferves, P"'"'' f*"' "* that the acid thus obtained is always more or lefs con- "^"'^ fohi.vA taminated with the volatile acid of fulphur. He ob- '■^'■'^"* ferves alfo, that the method propofed of feparating the fulphureous acid by a fecond diflillation firom fait of tartar is not effeftual, becaufe the fulphureous acid has lefs attraction for alkalies than the acetous. Wef- tendorff recommends the neutral fait formed by ace- tous acid and mineral alkali, inilead of the terra folia- ta tartari. Thus, in the firft place, we readily obtain cryftals free from the inflammable matter of the vine- gar ; and, in confequence of this, though we diftil it afterwards with concenti-ated oil of vitriol, no fulphu- reous taint < a,i be produced. Even fuppoiing this to be tlie cafe (he fays), it may be removed by a fecond diftillation from fome .'uueral alkali. Mr Kcir, how- ever, obferves, tliat " probably all the acids diftilled from acetous falts by means of the vitriolic, partake of the property of tliat procured by diftilling cryftals of verdegris ; and none of them can compare with that from which Mr I^ouitz obtained acetous ether without addition, as a pure concentrated ana unalter- ed vinegar." XIV. JciD of Bf.nzois: The properties of this acid have been inveftigated by j\i Y.xh- M. Lichtenftein, and are as follow, i. Expofed to teniieif 's the heat of a candle in a filver fpbon, it melts as clear acciMint of as water, without burning, though it is deftroyed by '^^^''^i*^'^' contaft of flame. 2. When thrown upon coals, it eva- porates, without refiduum, in a thick white fmoke. ■3. It is not volatile without a confiderable degree of heat. 4. By very flow cooling its aqueous fohition yields large cryftals, long, thin, and of a feathery fhape. 5. It is foluble in the concentrated acids of nitre and vitriol, but feparates from them, without de- compofition, on the addition of water. 6. By the other acidd it cannot be diffolved without heat, and feparates from them alfo without any change, merely by cooling. 7. It is copioufly diffolved by fpirit of wine, and precipitated from it on the addition of wa- ter. 8. W ith alkalies it forms neutral falts, very fo- luble in \\ ater, and of a fharp faline talle. With ve- getable alkali it forms cryftals of a pointed feathery- form ; with mineral alkali it yields larger cryftals, which fall into powder on being expofed to, the air; and with volatile alkali it is difficultly cryftallizable in- to fmall, feathery, and deliquefeent cryftals. It is fe- parable from alkalies by the mineral acids. 9. With calcareous 'earth it forms white, fliining, and pointed cryftals, not eafily foluble, and which have a fweetifla taile without any pungency. 10. With magnefia it Pra<5lice. C H E M I 153 1 Effeds of^ nitrous acid v\^on it. AcettHis A- fmafl feathery cryflals are formed, of a fliarp (zVine tafte, and eafily foluble in water. 11. An aftringent fait is foi-med with earth of alum. AH thefe earthy falts are eafily decompofed by tli€ mineral acids ss well as by alkalies. The acid of ben- zoin itfelf reddens litmus, but has little efFeft upon fy- rup of violets. MefTrs. Hermbftadt and Lichtenftein have both tried the effedls of nitrous acid upon thit of benzoin. In this operation, however, a great obftacle arofe from the volatility of the acid of benzoin, which prevent- ed it from bearing any confxderable heat without paf- fing over into the receiver. By i-epeated diftillations, however, the acid of benzoin, diminiflied in its vola- tility, affumed a darker colour, and acquired a bitter- ifh tafte. A coal was alfo left at the bottom ; and, at the end of the third operation,- when the nitrous acid had been all drawn off, M. Hermbftadt obferved, that fome brown drops came over which had the appear- ance of a dark-coloxnred tranfparent oil, foluble in di- ftilled water, emitting acrid fumes, and having a very cauftic tafte. On diftilling this acid liquor a fecond time, a yellow faline mafs was obtained, which, when diffolved in diftilled water, formed a fluid acid, which precipitated a folution of fugar of lead and lime-water. On examining the charred refiduum left in the retort, he obferved, that, after calcination, fome of the earth had been vitrified, while another was of a foft ceniift- cnce, and had acquired a cauftic tafte. From a mix- ture of the above-mentioned dark-brown acid and fpi- rlt of wine, he obtained an ether, which differed from the nitrous in being much lefs volatile, and fmelling like bitter almonds. From this refiduum Mr Lichtenftein obtained a re- fmous fubftance, to which he afcribes the volatility of the acid of benzoin, as well as the fmell of bitter al- monds already mentioned. Scheele failed in his attempt to obtain ether from flowers of benzoin and fpint of wine ; but, by adding ii little fpirit of fait, he obtained a kind of ether which fell to the bottom. On diffolving this in alkalized fpirit of wine, and drawing off the latter by diftilla- tion, he obtained from it a quantity of flowers of ben- zoin. From Peruvian balfani alfo Lehman obtained a quantity of the acid of benzoI:i. It may alfo be pro- cured from urine, either by precipitation, fi-om the faponaceous extrad (a), or by repeatedly diftilling vian balfani fro"! it fpirit of nitre, as in the preparation of acid •«nd urine, of fugar. In the urine it is found combined with volatile alkali, by which it becomes foluble in fpirit of wine. "XV. Sebaceous Acib. This is And to have been firft difcovered by Mr Gruitzm?.cker, who publiflied an account of it in 1748. It was afterwards more accurately trctated of "by Mr Rhades in 1753. Its properties were invefti- gated hy Meffrs Segner and .Knappe in 1 754 ; and .afterwards more fuUy'by Dr Crell, =of whofe difcove- ries an account is given in the Philofophical Tranf- Vol. IV. Part II. S T U Y. aftions for 1780 and. 1782. 15 3 i Acia of benzoin 595 It is found not oiily in Sebaceous the fat of all animals, but in fpermaceti, the butter of cocoa, and probably in other vegetable oils. In fe- veral refpecls it feems analogous to the marine acid; ^^^-"^ -^33 but in others it is remarkably different, particularly ^^jj^^'p^^py. in precipitating a folution of corrofivo fublimate. It rable from is probable, however, that its principles are the fame various with thofe contained in all other vegetable and ani-^'^'^^^""'' mal acids ; and this opinion is fupported by what hap- pens on treating tallow in the ufual manner for ob^ talning acid of fugar ; for thus, not the febaceous, but »5j4 the faccharine acid is found to be produced, it has aj^j^jj^yj very great ftrength of attraftion, and by means of heat p.j^yei. f the diffi- liated earth ; and Dr Higgins has verified this ^^P'^^^-i^^"'^^"^'^,. ment, and deduced the quantities. From 7680 grains j^jjjg^jfYy^^^ of foliated earth, the Dodlor obtained foliated Cauftic alkali - 3862-994 grains, earci Fixed air Inflammable air Oily matter retained in the re- fiduura. Oil - - Water condenfed Deficiency attributed chiefly to water - - As fixed and inflammable gafes may be obtained from every vegetable fubfl;ance by fire, nothing can be inferred from thefe experiments to, explain particularly the nature of the acetous acid, excepting that it con- tains fome of the inflammable matter common to the vegetable kingdom, and efpecially of the matter com- mon to vegetable acids; all which alfo, when analyfcd, furnilh large quantities of thefe two gafes. " Although we are far (adds our author) from the knowledge requifite to give a complete theory of the acetous fermentation, yet it may be ufeful to explain the ideas that appear mod probable. In all the in- liances that we know of the formation of acids, whe- ther effefted by combuftion, as the acids of fulphur and phofphorus, or by repeated abft;ra6Hons of nitrous acid, as in the procefs for making acid of fugar, a very fen fible quantity of pure air is abforbed. In the cafe o combuiUon we know, from the weight acquired, that , , , - ' . r • ° J • ..1 formation there is a great abforption of air and in the latter ^jj ^^^^^ cafe, of acids being produced by application of nitrous ax;id, as this acid confiils of nitrous acid and pure air and as in thefe operations a quantity of the nitrous gas is expelled, there feems little doubt but that there aUb the pure air of the nitrous acid is united with the fub- fl^ance employed in the formation of the new acid. Hence, from all that we know, the abforption of air takes place in all acidifying proceflis. But it alfo aftually takes place in the acetous fermentation, as has been obferved, particularly by the Abbe Rozler ; and it is generally known, that air is neceflary to the forma- tion of vinegar. The next queftion is, What is the bafis ? And from the experiments already related, . of forming the acetous acid by means of fpirit of wine, it feems probable, either that this fpirit is the bafis of the acetous acid, or that it contains this bafis : and from, the convertibility of the acids of tartar and of fugar «543 In the cafe of Air abforb- Praftice. CHEMISTRY. tiie Vej^e- cids. '544 Inflam- mable fpi- rit produ- ced from Identity of fugar into the acetous acid by the proceffes- above de- fcribed, it feems probable that thefe alfo contain the fame common bafis ; which, being united with a de- termined quantity of pure air, forms acid of tartar ; with a larger quantity, acid of fugar j and with a ftill larger, the acetous acid. " An inflammable fpirit is faid to appear at the end of the diftillation of radical vinegar from verdigris. Now, if the ardent fpirit were contained in the verdi- radical vi- gris, as it is more volatile than the acid, it ought to aegar. come over firft ; but as it appears only towards the end of the dilHUation, it feems to be formed during the operation ; and I imagine, that the metal, when almoft deprived of its acid, attrafts fome of the air of the remaining acid ; and the part or bafis of the acid thus deprived of its air becomes then an inflammable fpirit, and in fome cafes an oil appears. But as the quantity of acid thus decompofed is very fmall, and little air of confequence remains united with the me- tallic part of the verdigris, the copper appears rather m a metallic than calciform fl;ate after the operation. But zinc, during its folution in concentrated vinegar, dec©mpofes the acid as it does the vitriolic and other »545 ftrong acids, and accordingly inflammable vapours are Sulphure- produced ; and what is remarkable, thefe vapous have ous infiam- a fulphureous fmell. Iron always, during its folution pmirs^pro- conccBtrated vinegar, produces an expulfion of in- tluced from flammable vapours ; which, however, do not explode it. like inflammable gas. nf'h*^- V imagine that we arc yet able to ex- fthuent*^"" P}^'" completely what paffes in the acetous fermenta- partsof the^^''"> ^^^^^ the acetous acid is a compound of mere ^r^tf.„o fm'ri'f ^nA ry,,r-^ o,V Befides this combination' of fpirit acetous a- fpirit and pure air. <^'d. and air, it is obferved, that a precipitation always takes place before the fermentation is completed, of fome mucilaginous matter, which difpofes the vinegar to putrefy, and from which it therefore ought to be care- fully feparated. Stahl affirms, that without a depo- fition of fuch fediment, vinegar cannot be made from fugar, wine, or other juice. Befides the matter that is depofited, probably as much remains in the liquor as can be diffolved therein ; for, by diftillation, much ef a fimilar extractive matter is left in the retort. What the nature of this matter is, and how it is form- ed, has not yet been examined. Though diftillation frees the acid from much of this extraftive fubftance, yet we have no reafon to believe that we have ever ob- tained it entirely free from inflammable matter; as it retains it even when combined with alkalies and with metals. When fugar of -lead and other acetous falts are diftilled with a ftrong heat, the fubftances re- maining in the retort have been obferved to poffefs the properties of a pyrophorus ; and this will happen whatever pains have been taken to purify the vinegar employed. See the article Pyrophorus. This faft fliows the exiftence of an inflammable matter in this acid ; and which may perhaps be eficntial in its com- pofition, and neceffary to its properties. Although fermentation is the ufual mode of obtaining acetous acid, yet it appears from the inftances obferved by latter chcmifts, that it is not effential to its formation, nicii pro- but that it is alfo formed in various chemical proceffes ; <;flc3. and the acids obtained by diftillation from woeds, wax, &c. are very analogous to vinegar. It appears alio on treatingthe acid of fugar with nitrous acid, as has I .1547 It is lorna- ed in va- ritsus chc' been obferved both by Weftrumb and Scheele. Tlie Addition- latter further acquaints us, that he obtained it in ana- ^^ lyfinga tallow hke oil, which remained undiffolved f upon digefting ftarch in nitrous acid. As acid of fu- ^^"""^ gar alfo may be obtained from a variety of animal fub- ftances, and as this acid is convertible into the ace- tous, we have ©ne reafon more added to many others, to prove that the matters of vegetable and animal fub- ftances are not capable of any chemical diftinftion." XVIII. Jddition to Se(ft. I. f 20. concerning the Volatility of a Mixture of Mar we and Nitrous Acids. This is much lefs fenfible when the acids are weak than when they are concentrated. On mixing the ,,48 two when moderately fmoking, and which had remain- How to de- ed for a long time feparate without occafioning any P^Y*^ ^q^a- difturbance, a vaftly fmoking aqua-regia has been pro-'''=f duced, which would either drive out the ftopple, or burft the bottle in warm weather. On diftilling a pretty ftrong nitrous acid from fal ammoniac, M. Beaume obferved, that the vapours which came over were fo exceedingly elaftic, that notwithftanding every precaution which could be taken in fuch a cafe, the diftillation could not be continued. By letting this efcape, however, Mr Cornette obferved, that the diftillation of thefe two fubftances may be carried on to the end without any inconvenience^ and the aqua- regia will then be no longer troublefome. XIX. Test for Acids and Alkjlies. The general method recommended for difcovering a fmall quantity of acid or alkah in any liquid, is by trying it with any vegetable blue, fuch as fyrup of violets ; when, if the acid prevails in the liquor, the fyrup will acquire a red colour, more or lefs deep ac- 1^49 eording to the quantity of acid ; or if the alkali pre- Inaccuracy vail, it will change the fyrup green in like proportion. ^'^^^^ "T™* Since the late improvements in chemiftry, however, the ' fyrup has been found deficient in accuracy, and the infufion of turnfole, or of an artificial preparation called litmus, have been fubftituted inftead of it. The infufion of litmus is blue, and, like fyrup of vio- lets, becomes red with acids. It is fo fenfible that it will difcover one grain of oil of vitriol though mixed with 100,000 of water. Unfortunately, however, this infufion does not change its colour on mixture with al- kalies ; it is therefore neceffary to mix it with juft as much vinegar as will turn the infufion red, which will then be reftored to its blue colourby being mixed with any alkaline Hquor. The blue infufion of litmus is al- fo a teft of the prefence of fixed air in water, with which it turns red, as it does with other acids. The great fenfibility of this teft would leave very little reafon to fearch for any other, were it always an exa6l teft of the point of faturation of acids and alka- lies ; but, from the following faft, this appears to Mr Watt to be dubious. A mixture of phlogifticated ni- trous acid with an alkali will appear to be acid by the teft of litmus, when other tefts, fuch as the infufion of the petals of the fcarlet rofe, of the blu^ iris, of vio- lets, and of other flowei-s, will fnow the fame liquor to be alkaline, by turning green k> evidently as to leave no room to doubt. When Mr Watt made difcovery% the fcarlet! ro- 4 F 2 fes, 596 Teft for A- cids andAl kalies. T550 Red cab- bage a«- fwet s the jiurpofe 1S5I How to prepare it for ufe. C H E M I fes, and feveral other flowers, whofe petals change their colour by acids and alkalies, were in flower. Ha- ving ft:ained paper with their juices, he found that it was not affefted by the phlogifticated nitrous acid, ex- cepting in fo far as it afted the part of a neutralizing acid ; but he found alfo, that paper fl:ained in this manner was much lefs eafily efi'edled than litmus was ; and that, in a fliort time, it loft much of the fenflbi- lity which it poflefled at firft ; and having occafion in winter to repeat fome experiments in which the phlo- gifticated nitrous acid was concerned, he found his ftained paper almoft ufelefs. Searching, therefore, for fome other vegetable which might ferve for a teft at all feafons of the year, he found the red cabbage to anfwer his purpofe better than any other; having both more fenfibillty with regard to acids than Htmns, being naturally blue, and turning green with alkalies, and red with acids ; to all which is joined the advan- tage of its being no farther affeftcd by the phlogiftica- ted acid of nitre than as it afts as a real acid. To prepare this teft, Mr Watt recommends to take the freflieft leaves of the cabbage ; to cut out the large ftems, and mince the thin parts of the leaves very fmall ; then to digeft them in water at about the heat of 120 degrees for a few hours, when they will yield a blue liquor ; which, if ufed immediately as a teft, will be found to poffefs great fenfibility : but as in this ftate it is very apt to turn putrid, fome of the follov/- ing methods muft be ufed for preferving it. 1. After having minced the leaves, ipread them on paper, and dry them in a gentle heat ; when perfedly dry, put them up in glafs bottles well corked ; and, when you want to uie them, acidulate fome water with vitriolic acid, and digeft or infufe the diy leaves an it, until they give out their colour; then ftrain the liquor through a cloth, and add to it a quantity of fine whiting or chalk, ftirring it frequently, until it becomes of a true blue colour, neither incl'ning to green nor purple ; when yon perceive that it has ac- quired this colour, filter it immediately ; otherwife it will become greenifh by ftanding longer on the whi- ting. This liquor will depofit a fmall quantity of gypfum, and, by the addition of a httle fpirit of wine, will keep good for fome days ; but will then become fomewhat putrid and reddifii. If too much fpirit is added, it deftroys the colour. If the liquor is wanted to keep longer, it may be neutralized by a fixed alka- li inftead of chalk. 2. As thus the h'quor cannot be long preferved without requiring to be neutralized afrefii juft before it is ufed ; and as the putrid fermentation which it undergoes, and perhaps the alkalies or fpirit of wine mixed with it, feem to leflen its fenfibility ; in order to preferve its virtues while kept in a liquid ftate, fome frefli leaves of the cabbage, minced as above direded, may be infuftd in a mixture of vitriolic acid and wa- ter, of about the degree of acidity of vinegar ; and it may be neutraKzed, as it is wanted, either by means of chalk, or of the fixed or volatile alkali. It muft be obferved, however, that, if the liquor has an ex- cefs of alkalf, it will foon lofe its colour, and become yellow ; from which ftate it cannot be reftored ; care ftould therefore be taken to bring it very exadly to a blue, and not to let it verge towards a green. 3. In this manner, Mr Watt prepared a red infufion Aikali. S T R Y. Praaice* of violets; which, on being neutralized, formed a very Volatile fenfible teft, though he did not know how long thefe properties would be preferved ; but he is of opinion that the coloured infufiofis of other vegetables may be preferred in the fame manner by the antifeptic powep of the vitrioHc acid, in fuch a manner as to lofe little of their original fenfibihty. Paper frefli ftained with thefe teds, in their neutral ftate, has fufficient fen* fibility for many experiments; but the alum and glue which enter Into the preparation of writing paper, feem. In fome degree, to fix the colour ; and paper which is not fized becomes fomewhat tranfparent when wetted ; which renders fmall changes of colour imperceptible. Where accuracy Is required, there- fore, the teft fliould be ufed in a liquid ftate. 4. Our author has found that the infufion of red Various o- cabbage, as well as of various flowers In water, a-therteft=. cidulated by means of vitriolic acid, are apt to turn mouldy in the fummer feafon, and llk^wife that the moulding is prevented by an addition of fpirit of wine. He has not been able to afcertain the quan- tity of fpirit neccflary for this purpofe, but adds it by little and little at a time until the proctfs of mould- ing is ftopped. — Very fenfible tells are afl'orded by the petals of the fcai let rofe, and of the pink coloured lychnio treated in the above-mentioned manner. »55a 155.1 XX. Volatile AiKAir. Mr HtGGiNs claims the firft difcovery of the coji- ftituent parts of volatile alkali, or at leaft of an expe- y_^j --j^ ^^j, riment leading to It. "About the latter end ofj^-gij prepjl March 1785 (fays he), I found that nitrous acid red from poured on tin filings, and Immediately mixed with "ittous a- fixed vegetable alkali, generated volatile alkali iiyCid and uo, great abundance ; fo Angular a fa6t did not fail of deeply imprefiing my mind, though at the time I could not account for It. About a fortnight after, I men- tioned the circumftance to Dr Brocklefljy. He told me he was going to meet fome philofophical gentle- men at Sir Jofeph Banks's, and defired I would ge- nerate fome alkali to exhibit before them : according- ly I did ; and had the pkafure of accompanying hittv, thither. The December following I mcntion^^d the faft to Dr Caulet, and llkewife the copious genera- tion of volatile alkali from Pruflian blue, vegetable alkah, and water ; on which we agreed to make a fet of experiments upon the fubjed. At prefent I ftiail only give an account of the following, which dreWr our particular attention. Into a glafs cylinder, made- for the purpofe, we charged three parts of alkaline 1555 air, and to this added one part of dephloglfticated air } ^^^^''^^^^j^ we pafled the eleftrlcal fpark repeatedly In It, withrl^^.^^ out apparently effeftlng the fmalleft change. Wlien It had received about lOO ftrong fnocks, a fmall quan- tity of moifture appeared on the fide& of the glafs, and the brafs conduftors feemed te be corroded i.. when we had pafled 60 ra,ore fliocks In it, the quan- tity of moifture feemed tp inoreafe,, and acquire a greenifli colour, though at this;time the column of air fufl"ered np diminution. On examining the air, it burned with a languid greenifh flame, from which we Inferred that the dephloglfticated air was total^ coi»- denfed: It ftill retained an alkaline fmeli; and the alka- line part was not readily abforbed by wat^er. " From . on \: Pra(5licc. C H E M I ** From Mi Cavendifh's famous difcovery of the conflitutent parts of \yater we could readily account for the lofs of the depbloglfticatcd air in this exptri- mcnt ; but the quantity of water was more than we could expect from this : therefore water mxift have been precipitated from the decompofed alkali ; for volatile alkali, from its great attraflion to water, muft keep fome in folution, even in its aeriform ftate. From the above circumftances it might be expefted, that a contra(Elion of the column of air fl^ould take True com- place ; but it muft be confidered, that the union took pofition of place gradually in proportion as the alkali was de- volatiie al- compofed ; and tliat, in this cafe, the txpanfion muil; equal the condenfation. During the fpring of 1786, I had often an opportunity of mentioning different h&.s to Dr Auftin relating to volatile alkali, who at that time was too much engaged to pay attention to the fubjeft. In the end of Auguft 1787, he gave me an account of a fet of experiments which he- had made, and which aclually proved, that volatile alkali confuls of light inflammable and phlogifticated airs ; not knowing at that time what MefTrs Houf- man and Berthollet had done. Without depreciating the merit of thefe two gcntl-emen, Dr Auftin has an equal claim to the difcovery, laying afide priority ; as his experiments are as decifive as theirs. Dr Pricftley made the firft ilep towards our knowledge of volatile alkali." XXI. Prussian Blvp... Th e acid of this fubftance, as far as it contains an acid, is fuppofed to be that of phofphorus. Mr Woulfe propofed a teft of this kind for difcovering iron in mi' neral waters, which, he obferved, would not be affefted 155^7 acide ; but the lixivium defcribed by him had the "Woulfe's bad property of letting fall the Pruflian bkie it copr teft for mi- tains in a few weeks. The precipitate 'of copper, tcrs'^ treated again with alkali, retained this pro- perty upwards of nine months. The volatile alkali, he obferves, is dilTolved by the Pruflian acid ; and tlie cryflals depofited are rendered blue by the colouring matter, though the colour at firft is loft by the union of the alkali with the fabftanee already made. The metals were precipitated by this teft of the following xjjg colours : Gold of a brownifh yellow, the precipitate EfFed of it afterwards becoming of a full yellow: platinaof a deep on various blue, but when quite pure, of a yellow colour, turning flightly green. Silver in the nitrous acid was preci- pitated of a whitifii colour ; copper from all the dif- ferent acids was precipitated of a deep broAvn colour, the liquid remaining greenifh ; green vitriol let fall a deep blue powder, leaving a colourlefs lixivium; fugar of lead and muriated tin gave a white powder; nitra- ted mercury a white or yellowifh precipitate ; the Illfeld manganefe a brownifh, but that from Devon- fhire a blue, whiyh firft became afh-coloured and then reddifh. Nitiated bifmuth sfForded a white precipitate, and the lixjivium was flightly green : mu- riated antimony yielded a white precipitate, with a yellowifh lixivium : vitriolatied zinc a whitrfh : co- balt in aqua-regia a reddifli white powder : the pre- cipitate of arfcnic and the different earths was com- monly white- 5- metallic fo iuti'jns. 1 T R Y. XXIII. NRir Chemical Nomenclaturbs. ^LTl no-' I. Of that propofed in I'jS'j l>y Mefrs Morveau, Berthol-^^^^^f^' let, Fourcroy, and Lavo'ifitr. ■ , - i * When this nomenclative Avas firft publiflred, M. La- voifier informs us, that fome blame was thrown upon the authors for changing the language, wliich had re- ceived the fauftion of their matters, and been adopted i559 by them. Inaniwer tothis,howcver,he urges, that Meflr&|^^^''&'"^*"'»^ Bergman andMacquer had expreffed a wifh for fome re- Morveau- formation in the chemical language. Mr Bergman had,, n this lub-.- even written to M. Morveau on the fubjed in the fol- lowing terms. " Show no favour to any improper denomination : Thofe who are already poffeffcd of knowledge, cannot be deprived of it by new terms ; thofe who have their knowledge to acquire, v/ill be enabled by your improvement on the language of the fcience to acquire it fooner." The following is M. Lavoifier's explanation of the principles on which his new language is compofed. " Acids confift of two fubftances, belonging to that ^^g^. order which con^jjrehends fuch as appear to us 10 be Lavoiiier'a fimple fubflances. The one of thefe is the principle exphnation; of acidity, and common to all acids ; from it therefore °' '^"^ "^^^ fhould the name of ths clafs and genus be borrowed : The other, which is peculiar to each acid, and diftin- guiflies them from one another, fhould fupply the fpe- cific name. But in moft of the acids, the two coniti- tuent principles, the acidifying and the acidified, may exift in different proportion, forming different degrees of equilibrium or faturation j this is obierved of the fulphiaic and fulphurecus acid. Thefe two ftates of the fame acid we have expreffed by- varying the termina- tion of the fpeclfic name. " Metallic fubftances, after being expofed to the compound aftion of air and fire, lofe their metallic luftre, gain an increafe of weight, and alfume an earthy appearance. In this flate tliey are, like acids, com- pound bodies, confifting of one principle common to them all, and another peculiar to each of them. We have therefore in like manner claffed-them under a. generic name, derived from the principle which is common to them aU, • The name Avhich we have adopt- ed is Oxuk : The peculiar names of the metals from which they are formed, ferre. to diftinguifli thcie ' compounds from one another. " Combuftlble fubftances, which, in.'acids and me- tallic oxides, exift as fpecffic and peculiar principles,^ are capable of becoming, in their turn, the common principle of a great number of fubftances. Combina*- tions of fulphur were long the only compounds of this fort known : but of late the experiments of Meffrs Vandermonde, Monge, and Berthollet, have fhown that coal combines with iron and perhaps with various o- ther metak ; and that the refults of its combination ■ with iron are, according to the proportions, fteel, plum- bago, i!Sc. It is alfo known from the experiments of M. Pelletier, that phofphorus combines with many metallic fubftances. We have therefore arranged thefe difl'ei-ent combinations together under generic names, formed from the name of the common fubftance, with a termination indicating this analogy ; and have dlC" tinguiflied them from each other by fpeclfic names dep- rived from the names of the pecuHar fubftances. CHEMISTRY. Pra(f^ice« " It was found lomewhat more difliciilt to form a no- menclature for the compounds of thofe three fimple fubftances ; becaufe they are fo very numerous, and fllU more, becaufe it is impoflible to exprefs the na- ture of their conllituent principles, witkout ufmg more compound names. In bodies belonging to this clafs, fuch as neutral falts for inftance, we had to confider, i. the acidifying principle common to them all; 2. the acidifiable principle which peculiarizes the acid ; 3. the faline, earthy, or metallic bafe, which determines the particular fpecies of the fait. We have derived the name of each clafs of falts from that of the acidifiable principle, common to all the individuals of the clafs ; and have then diftinguifhed each fpecies by the name of the Jaime, earthy, or metallic bafe peculiar to it. " As fait, confifting of any three principles, may, Vv ithout lofing any of thefe principles, pafs through dif- ferent ftates by the variation of their proportions; 6ur nomenclature would have been defeftive without expreffions for thefe differeat ftates. We have expref- fed them chiefly by a change of termination, making all names of falts in the fame ftate to end with thte ■fame termination.'* 2. Nomenclature by M. Wteglel. Mr Wieg- In Wiegleb's General Syftem of Chemillry tranfla- niencla " Hopfon, we have another nomenclature formed ture ' different principles. In this he gives to fixed ve- getable alkali the name of Spodium, from the Greek word o-jraS®- ( ajhes ). The mineral alkali he calls natrmriy the name by which it was anciently diftinguifhed ; and the volatile alkali ammonium, from fal ammoniac which contains it in great quantity. The compound falts may be diftinguifhed into double, triple, and quadru- ple ; though, in the fcheme given in the work, the firtt divifion is omitted, as tending only to create confufion. The irregular falts, confifting of thofe which are triple and quadruple, are admitted. Such as are imperfeft by reafon of an excefs of acid, he fays, are bcft deno- minated by converting the adjedlive, expreffive of the bafe, into a participle ; a praftice which, on many oc- cafions, though countenancedby the authority of a late eminent writer, feems aukw;ard and ftiff. The excefs of acid is denominated by the word hypero-xys, and a defe£l of it T>y hypoxys. Hence his denominations are * formed in the following manner. Salts with excefs of acid. Cream of tartar, or tarta- rm fpodatus, or tartaroxys fpodicus. Acid vitriolated tartar, or vitriolum fpfldatum, •vitrioloxys fpodicus. The falts ivhich are imperfeft from a defeil of acid have their denominations by mentioning the bafebefore New Che- the acid, and expreffing the former fubftantively, the latter adje / 2. Biftputh, or tin-glafs. A white, ponderous, hard, brittle, and fonorous body, of a plated texture ; eaflly fufed and vitrified. It is only reduced to an ore by arfenic. Its appearance much the fame with regulus of antimony. 3. Antimony. A blackifli fubftance, of a fibrous needle-like texture ; hard, brittle, and of a confiderable weight ; not difficult of fufion, and eafily convertible into glafs. Its only ore is with fulphur, which is the crude antimony. 4. Arfenic. A bright, fparkling, whitifli-coloured femimetal ; of a plated texture ; very brittle, and extremely volatile. It is ee- neraUy found in the ores, of other metals. ° 5. Cobalt. A brittle femimetal fufible in a moderate heat, and eafily convertible into a beautiful blue o-lafs caUed fmalt. It is always obtained from an arfenical ore, likewife called cobalt. ^ §. Nickel. A reddilh white fubftance, of a clofe texture, and very bright ; eafily melted, but very diflicult to vitrify. IV. INFLAMMABLE SUBSTANCES, Are tbofe which continue to burn of themfelves when once fet on fire. They are divided into oils, fulphur or brimflone, alcshot ®r ardent fpints, and charcoal. '' ' ^ j atlc air. Produced from the decompofition of liver of fulphur by acids, or in the common atmofphere. It 13 inflammable, but does not burn with explofion. , , • , i-r 1 J I Jtwvperkal air. Compofed of dephlogifticated and phlogifticated air ; and thus fupports both animal life and vegetation. TABLE fliowing the feveral Combinations that the simple chemical elementary bodies: admit' of with one another; the Compound refivlting from that Mixture; and the Manner in which the Union is effeded : With fome Account of the principal Ufes to which thele are ap- plied in Arts or Manufactures. N. B. This mark*, put above any word, denotes that there is fome difficulty in the procefs, or that the union is not very complete. ACIDS. ALKALIES. EARTHS. But thefe mlx- VIT R 10 L I C JC I D may be combined with the folh'wlng Suhjlances, viz. f Nitrous Acid. A mixture vv^hich readily inflames oils. By folution, generating heat, "i Muriatic, Vegetable, and all other Acids yet known. By folution, generating heat tures are applied to no particular ufe In medicine or arts. c Fltrlolated tartar. By folution and cryftalllzation, or double ekaive attradion from a great variety of bodies. . . Vegetable.-! iV/Vr«w vltrlolatum. A vltrlolated tartar, obtained by diftlUing from nitre with the -ntriohc acid. 1 t • J r • Sal polychrefum. By deflagrating nitre with fulphur. There are many other kinds of vi- trlolated tartar, known formerly by different names, and fuppofed to be poffeffed cf parti- cular properties, but they are now neglefted- FossiLE. Glauber's fab. By folution and cryftalllzation. Much ufed In medicine as a gentle purgatne. i_VoLATiLE. Secret ammoniac. By folution. Formerly fuppofed a moft powerful menftruura for metals, &c but without any juft foundation. , ., fA corroded calx. By fimple corrofion. This when perfeftly edulcorated wath water is found to bea true gypfum. Seknltes. By precipitation from, a very dilute folution of chalk In the nitrous acid, hr means of the vitriolic acid. Terra pondtrofa. With this It unites In preference to alkalies, forming a very heavy and in- foluble fubftance called fpathum ponderojum. Gypfum or Parls-plajler. Often found in a native ftatc. May be_ artificially formed by preci- I I pitating from a folution of chalk in a very concentrated nitrous acid. Ufed as a ce- 1 i ment; for taking Impreffions from medals, &c. I ITalc, ajbejos, iffc. A native produftlon which cannot be perfeftly Imitated by art. Ufed for holding objefts in microfcopes, making Incombuftible cloth, &c. , or magnefta Glauber's fait. By folution r.nd cry ftailizatlon. ivludi ufed CCalcareous 1 Earths. Magnesia. Epfom \^ the fame purpofcs as real Glauber's fait. In medicine for EARTHS. Table, EARTHS. METALS. SEMIMETALS. i «ILS. i5ULPfIUR ALCOHOL WATER. ACIDS. ALKALIES. EARTm. CHEMISTRY. 603 TEarth of Alum. ^lum. By folution, cryftallization, &c. Ufed by dyers as a preparatory for takino- on j the colours, papermakcrs, goldfmiths. &c. [ Earth of Animals, Osteocella, &c. By folution. The mixtures of thefe are not applied to any I particular ufe. . Clay* ^hm. By digefting pure clay for fome time in this acid, and expofing it for fom: time to the air, j an alum is produced; and if the clay is precipitated from this aluminous concrete, it is found to be a pure earth of alum, foluble in all acids. (_Flint. a thickiih coagulum. By digefting the liquor filices in the vitriolic acid. fGoLD*. Imperfeftly. By a particular procefs after being feparated from aqua-regia. Silver*. By folution, after it has been precipitated from the nitrous acid by alkahes. The fumes which arife in this folution are inflammable. Copper. Blue vitriol. This is fometimes a native produftion, but in this way it is never pure. It is arti- ficially prepared by folution in a very concentrated acid, and cr^-ftallizing it. 'Green vitriol or copperas. Obtained at large by particular procefs from pyrites ; or by folution, &c. in a diluted acid. This is the bafis of all black dyes, ink, &c. as it itrikes a black colour with Iron.-! vegetable aftringents. Salt of fteel. By calcining the cryftals of green vitriol till they are converted into a white powder. \Colcothar of vitriol. By continuing the calcination till it affumes a brown colour. Lead S^^^"^"'" A folution In a boiling heat, but is again precipitated when cold. * cAn Indiffoluble concrete. By precipitation from the nitrous aeid. Tin. Jupiter corrofivus. By a boiling heat in a concentrated acid. ^Ignis Geheme^ or infernalis of Paracelfus. By a boiling heat, and repeated codions with frefh Mercury. \ acid when it is evaporated. l^Turpeth mineral, ox mercuiius precipitatus flavus. By evaporating to drynefs, and then wafliing with water. f Antimony*. A metallic fait. By eledtive attraction from butter of antimony. I Zinc. White vitriol. Often found in its native ftate. Artificially made by folution and cryftallization in a diluted acid. Ufed by' painters for drying. Bismuth. A corroded calx. By folution in a concentrated acid. I Arsenic - - - By ditto. LCoBALT. A rofe-coloUred mixture. By folution. If this is precipitated by a fixed alkali, and again dif- folved, the liquor appears of a beautiful red. fExPREssED. A blackifh gummy-like mafs. By folution, generating a confiderable heat. Natl [ fuppofed to owe their origin to a mixture of this kind. Essential. A dark-coloured rcfinous mafs. A great heat and violeflt efFervefcence being produced by this mixture. Native refins fuppofed the fame. I Empyreumatic. Little known. By folution. LFossile. a fubftance refembling amber. By folution. Here there is no proper union of fubftaTices ; but if fulphur is boiled in this acid, it becomes lefs inflammable and more fixed than any oi'dinary fulphur. f Vitriolic ether. By careful folution and diftillatioll, the ether being feparated by the addition of watef. I Spiritus vitrioU dulcis. By Solution and diftlUation. Oleum didce. By continuing the heat after the ether has arifen. Okum anodynum minerale. By rediftlHIng the refiduum of the laft with alcohol. A medicine much cele- I bratcd by Hoffman. {.Sulphur. By pufliing the heat after the oil comes over. It Is to be obferved that this is produced in every combination of this acid with inflammables or metals. An acidulated water. Sometimes ticular ufe. N I T R 0 U S ACID may he combined ivith tlx following Sub/lances, viz. Vitriolic, as above. Muriatic. Aqua regia. By folution. This Is the only proper menftruum for gold ; and it is a folution of tin in this menflruum which is the bafis of the fcarlet dye. Vegetable, and all others. By ditto. Thefc compounds have no particular names, nor are applied to any particular ufes in medicine or arts. Vegetable. Common nitre. A native pi-oduftion. Made artificially by folution and cryftallization. deflagrates with oily or metallic bodies, and Is the foundation of gun-powder. FossiLE. Cubic nitre. By folution. Volatile. Nitrous arriKojuac. By folution. This dllxers from all the other foluble in alcohol. CilCar^ous S-^^^'^Q^d}'^^^ '■''xIJ'^'^' " By ditto and cryftallization. ' LBaldivin^s phofphorus. By ditto and evaporating to dr)'nefs. By folution. The compounds have no names tive gums are though feldom, found Iflulng along with native fprings. Applied to no par- Thi ammonlacal falts, by being C .... ^ Earth of Alum, and all other ahforbent earths. fj ^ remarkable properties hitherto difcovered. Crystalline Earths*. By folution after precipitation from the liquor fihces, 4 G 2 any METALS. CHEMISTRY. Table. Silver. METALS. EARTHS. Mercury. SEMIMETALS. Antimony. OILS-. ALCOHOL. •WATER.. ACIDS>. ALKALIES. <[ 'Gold*. Slightly Impregnated. By a boiling heat in clofe veflels, after the ordniary method of fcparating filver from gold by the nitrous acid. It fpontaneoully fublides in the air. j AJltdd fohition. By folution. This when diluted with water ftains hair and bones black ; a».alfo marble, agate, jafper, &c. of different colours. Sal metallorum. By folution and cryftallization. y Cathart'icum lunare, lunar cauji'ic^ or lapis infernalis. By infpifTating the folution to drynefs. Copper. A green-coloured folution. By folution. Iron. A greenirti folution, if a diluted acid is employed ; if otherwife, it is of a yellowlfh l'tquQr, By boHing a calx of gold (In whatever way obtained) in this acid. It does not act upon It in its metallic llate. ^ C^/wW/c//«//o«. By diffolvlng the ore of filver in this acid. It does not aft upon pure me* biLVER*. ■< talhc filver. ^ ^ C Luna cornea. By eleftive attraftion from the nitrous acid. Platina*. Afluid folution. With difficulty efFeded, after having been precipitated from aqua regia by alkalies. i t> Copper. A green deliquef cent hiflammahh fait. By folution and infpiiTating to drynefs. Iron. TinBura martis aurca. By folution. The iron is in fome meafure rendered volatile by this operation. METALS. ^ l^^^-o. 5 ^ ^'""^P^^ folution. By a boiling heat, and frequent cohobations with freib acid. I Cornea Saturni. By precipitation from the nitrous acid. Tin*. J ^^'■'^O'i^^ pow^^i"' By fimpie corrofion. (_ Butter of tin. By diftilling from corrofive fublimate. ' A colourlefs cryllaUine mafs, extremely acrid. By corrofion, employing the fumes of a very concentrated aid. ^ Mercur. corrofv. alius. By precipitation from the nitrous acid. Mercury N<| Corrofive fublimate. By fubliming from fal ammoniac, common fait, or many other bodies. 1 Mercurius dulcls. By refubliming corrofive fubhmate with more quickfilver. j Mercurial panacea. By fubliming corr, fub. nine times, and digeftln? for "fome time in fni- l_ rit of wine. o & r Bismuth*. A folution very flightly impregnated. By employing a very concentrated acid. I Zinc.' A folution of a very flight yellow colour. dPTVrmTTTATcj J^^^^^!^*- Butter of arfenlc. By diftiUing corrofive fublimate witli arfenic ; the arfenic uniting 'v^'ith tl«5 br^MlMil- 1 AL,b. 1 acid, and leavmg the mercury. ° j Cobalt. reddifh folution. By the ordinary means. It becomes green by a gentle heat. ^Nickel. A green folution. By the ordinary means. OILS *. By folution. The union here is but Imperfeft, nor have they any particular name. ;^<'/r/V«j/a& dulcls. By digeftion, and afterwards dllliUing. The acid here Is never totally dulci'ned. WAiLiv. Acidulated nvater. Generating heat by mixture. ACIDS. ALKALIES. EARTHS. V I hi EGA R may be combined ivltJ) the folloivlng Subjances^ viz. Vitriolic, Nitrous, and Muriatic, as in the above table. It llkewife unites with aU other acids, gene- rating heat ; but the properties or ufes of thefe are not known. {Vegetable. Regenerated tartar. By folution and cryftallizatlon. FossiLE. Polychrejl of Rochelle. By dllto. Volatile. Spirit us Minder erl. By folution. t Calcareous Earths. Earthy falts. Not known In medicine or arts. i Magnesia. _ Dr Black's purging fait. By folution. It unites with all the other abforbent earths ; but tile properties of thefe mixts are unknown. f^^^o'f'the^r?^'''' ^""^ cryftallizatlon ; or at large, by ftratifying copper plates with the huflcs. , Iron. Sahnartls aperlens. By folution and cryftallizatlon. j Lead. \ ^''''f- expofing, in certain circumftances, thin plates of lead to the fumes of vinejr-r. 1 ( bacckarum Saturnt. By folution and cryftallizatlon. ^'"^ *io\2on P''°P'*"^y moh^^ ; but the acid is evidently Impregnated. By the ordinary means of Mercury*. \ ^f'^'^ffijutlon. By employing a precipitate of mercury from the nitrous acid by alkalies. I A red calx. By long digeftion with fluid mercury. fZiNC, A colourlefs folution of a fweetifti tafte. By digefting for fome time j Antim<.ny*. Vlmm benediSum. This is not a proper folution of the metal, but the acid is impregnated <; with an emetic quality. * ° I Arsenic. Vlnum arfenlcum. By ditto. A curious phofphoric liquor. I Bismuth. An auftere ftyptic liquor. By ftrona coftion. A T7?r^ir/-.T ^^'"^ imperfea, nor have any of them obtained particular names.. Al^L-UilUi.. A mixture much ufed for anolntinji fpralns. Sec. WATER. Acidulated 'water^ ^ ^ ' METALS. &EMIMETALS. ALKALIES. ALKALIES. ACID QF^ TAR TAR may be combined iiAth the folloiulng Subjlances, v% Vegetable. ' FossiLE. ^Volatile. 5 Cream of tartar with excefs of acid. C Soluble tartar, when completely faturated. Rochelle fait, 5 A fait very difficult of folution with excefs of acid: vi^ beautiful aod foluble fait when perfectly faturated.. 1 EAJRXii 6o6 EARTH. METALS. SEMIMETAL. C -II E M I 1 Calcareous. An indiflbluble felenite. (Copper. A fine green colour for painting. I Iron. A green altringent liquid. Chalybeatcd tartar. Regulus of Antimony. Emelicj^tartar. T R Y, Table. alkall J C ID OF URINE may hs combined tvith the jllloiving SulfuinccSy viz. ACIDS of all kinds. The nature of thefe not known. f Fixed Vegetable. A fait not eafily cryftalHzed, the nature of which is not known. Fossile. a fine cr}-ftallized fait ufed in medicine. Volatile. A glafs-like faline fubftance called mkrocofmk fait. The acid is always found in this flate I evaporating urine. VITRESCENT EARTHS. Glafs of different forts. By fufion. fLEAD. An inflammable malleable mafs. By calcining the dry fait with lead. I Tin. a mafs refem.bling zinc ; and inflammable. By ditto. 1 , C A true phofphorus. By ditto. \ -'■^ON. ^ ^ i^j^jj^ folution. By employing a watery folution of the acid. ] Copper. A corroded powder, or green folution. By a boiling heat in a watery folution of the acid, t Mercury. A femi- opaque mafs. By fufion with the acid in its folid ftirm. ' c A corroded powder, fcluble in water. By folution in the acid in a watery fituuticn. Zinc. } ^ x.\yx>i phofphorus. By fufion with the dry acid. (A folution in the ordinary way.. Antimony. ^ ^ brilliant ftrlated mafs. By fufion with the dry acid. Bismuth. A mixture but little changed in appearance from ordinary bifmuth. By fufion- i Arsenic. A whitifli femitranfparent dellquefcent mafs. By fufion. (^Cobalt. A reddifh tinfture. By folution. METALS. SEMIMETALS. \ OILS. BaU'win's phofphorus. By diftilling with fubllances that contain oils or inflammable matters. VIZ. Great part ALKALIES. EARTHS. METALS. FLUOR ylCID may Is combined with the following Subjlancs, Fixed Vegetable. A gelatinous faline mafs which cannot be cryftallized pated by evaporation to drynefs. iFossiLE. A fubftance fimilar to the foregoing. Volatile. Lets fall a quantity of filiceous earth, and forms a cryftallizabls ammoniacal fait Lime. 1 IMagnesia. > A gelatinous matter. (Earth of Alum, j Siliceous Earth. After long ftanding, cryftals of _ quartz. of it is alfo diflii Silver. I The calces of thefe metals partially diflblved ; bnt the properties of the folution im Quicksilver. ^ known. Copper. The calx eafily foluble, and affording blue cryftals ; the metal only partially fo. Iron. Diffolved with violence with the emiflion of inflammable vapours into an uncryltallizable liquor. ACID OF SUGAR may be combined luilh the following Subjlances, viz. f Fixed Vegetable. A fait fcarce capable of cryftallization when perft^ly neutral. ALKALIES. 4 Fossile. A fait difficultly fokible in water. (.Volatile. An anunoniacal fait fliooting into quadrangular pnfms. r Lime. A kind of felenite from which the acid cannot be feparated but by a burning lic.it. Sterra Ponderosa. a fait formed into angular cryftals, fcarce foluble in water. EARTHS. jMagnesia. A white powder infoluble without an excefs of acid. CEarth of Alum. A yellow pellucid mafs incapable of cryftallization, and liquefying In the air. ["Gold. T 1 Silver. ( rp,^^ c^zc^ of all thefe metals diffolved, but the nature of the folutions unknown. METALS. \ Platina. r i Quicksilver. J -r • r i n r 1 t_i • LIron. Diffolvtd in gieut quantity, and forming a yellow pnfmatic fait eafily loluble in water. on. After precipitating it from acids ; if the alkali is in too large proportions, it then diholves it, efpecially if the alkali has been calcined in contad with the flame. rZiNC*. By folution, after having precipitated it from the nitrous acid. Bismuth *. By folution, after having precipitated it from the nitrous acid. CKennc-s mineral. By diffolvlng antimony in an alkaline lixivium, filtering, and allowing It to I Itand in a cool place till it precipitates. Golden Julphur of antimony. By diflblving a crude antimony in an alkaline lixivium, and preclpi- tating by an acid. ,j Hepar antimonii. By deflagrating crude antimony with nitre. Crocus mstallorum. Is hepar antimonii pulverifed and edulcarated with water. Diaphoretic antimony. By deflagrating regulus of antimony with nitre. ^ntimoniated nitre. By diffolvlng diaphoretic antimony in water, and allowing it to cryftallize. Magijhry of antimony. By precipitating a folution of diaphoretic antimony by adding vinegar. \^Regulus antmonn medicinalis. By fufing crude antimony with alkali. This is not properly a compound of alkah and antimony, but of another kind. But as it is a term much ufed. It was proper to explain it. A metallic arfenical fait. By a particular ekaive attraaion from regulus of antimony and nitre. iyoap. The beil hard foap is made of olive-oil and foffiie alkali. The ordinary white foap of j this country is made of tallow and potafh ; black foap with whale-oil and potafli. j Essential. Saponaceous mafs. Beft made by pouring fpirit of wine upon cauilic alkali and then oil, diVeft- 1 ing and lhaking. ° Empyreumai ic. This mixture diffolves gold when precipitated from aqua regla ; and is the bafis of the fine coloui cajitd Prufpan Llue ; and has various other properties, as yet but little known. LFossiLE. This has no name, nor are the properties well known ; but from fome obfervations that have been made on nat ive foapy waters, it is probable that It would keep linen much longer white than any other kind of foap. ^Hepar Julphuns. By injeding alkalies upon melted fulphur. LLdc fulphuris. By diflLlving fulphur in an alkaline hxivium, and precipitating by an acid. Alhalme lixivium, when cauftic, or even the ordinary folution of mild alkali, is a fluid of great power in wafhin?. blacking, &c. or 6» Fixed. Mild alkali. This is the general flate in which alkalies are found ; but if they are rendered cauftic by means ot quick-hme or otherwife, they again abforb it from the air, or from many other bodies, by ckaivc attraction. When perfedly mild, this alkali may be made to alfume a cryflalline form. PTT^c /LKALI, or SPIRIT OF SAL AMMONIAC, can be united r^ith thefe Bodies, viz. ^UlJJb: Vitriolic, Nitrous, Muriatic, Vegetable; of Urine, of Amber, of Ants, &c. as above. ^ Gold *. 5 ^'^rum fulminam . A powder obtained by precipitating it from aqua regia by volatile alkalies. ^ A liquid folution. By adding a large proportion of alkali after it has been precipitated from aqua regia. This depofites the gold when long expofed to the air. The curious vegetation called arior DianlLKALI : Fixed*, as above. ' ( Gold, Silver*, Lead*, Tin, and Copper, as above. ( Platina. The compound refulting from this mixture is not known, f Zinc An amalgam. Soft or hard, according to the proportions employed. I Antimony. By melting the regulus, and pouring it upon boiling mercury. By frequently diftilling from- 'EMIMETALS \ amalgam, the mercury is rendered much more pure, and is then called animated mercury. p * j Bismuth. A filverizing for iron.. By putting this amalgam upon iron, and evaporating the mercury. It I has much the appearance of filver. vOobalt. By mixing firll with nickel, and then adding mercury. ULPHUR, as above. ZINC nay be combined -with the folloiuing Subftances, viz. CIDS :• Vitriolic, Nitrous, Muriatic, Vegetable, of Urine, of Amber, of Ants, as above, r Gold, Silver, Lead, Tin, Copper, and Iron, as above. fcvIETALS. •< Platina. A hard fubftance. I C Mercury, as above. , <, fANTiMONV. This mixture Is applied to no particular ufe. SEMIMETALS. ^ Arsenic. A black and friable mafs. l^CoBALT. The particular nature and properties of.thls mixt is not known» DIL : Exprelfed*, as above. SULPHUR*, as above. JlN T I MONT may be combined 'with the foUotving Stdijlances^ viz. \CIDS : Vitriolic*, Nitrous, Vegetable*, and Urinous. With the phenomena, and by the meaiu above defcribed. Alkalies : Fixed and Volatile, as above. I^ITREOUS EARTHS. A thin penetrating glafs ; which is a powerful flux of metals. Gold, Silver, Lead, Tin*, Copper, and Iron, as above. Platina. A hard mafs. Mercury, and Zinc, as above. Bismuth. A mafs refembling regulus of Antimony. Arsenic. The nature and qualities of this mixt are not known. Nature unknown. Ditto. PETALS. IEMIMETALS. Cobalt. Nickel. JULPHUR, as above. B IS MUTH may be combined tuith the follonving SubflanceSf viz. \CIDS : Vitriolic, Nitrous, Muriatic, Vegetable, and Urinous ; with the phenomena, i^c. above defcribed. \LKALIES : Fixed*, and Volatile*, as above. /TTREOUS matters, a yellow glafs. The ore of Bifmuth affords with thefe a blue glafs ; but this is probably owing to fome mixture of Cobalt with it. C Gold, Silver, Lead, Tin, Copper, and Iron, as above. ilE TALS. "S Platina. This mixture changes its colour much on being expofed to the air* CMercury, as above. S Antimony, as above. Arsenic Nature not known. t.MiiVii:.JL-^^-i-.o. -aCobalt*. By mJxing firft with nickel or regulus of antimony, and then adding cobalt ; but it cannotJse" / united by itfelf. NiCKEL. This mixt is not known. . LfLPHUR, as above. jARSENIC may be combined ivith the folloiuing Subjlances, viz. CIDS : Vitriolic, Muriatic*, Vegetable*, and Urinous ; v^-Ith the phenomena, ^c. above mentionedv 4 ALKALIES i: 6^4 CHEMISTRY, Table, ALKALIES : Fixed, and Volatile ; with the phenomena, and by the means mentioned above. VITREOUS MATTERS. A gkfs which greatly promotes the fufion of other fubilances. The arfenic mult firft te prepared by diffolving and precipitating from alkalies. ,-nrr A T c ^ Gold, Silver, Lead, Tin, Copper, and Iron, as above. ^ METALb. J^Platina. f Zinc, Antimony, and Bifmuth, as above. SEMIMETALS. < Cobalt. . , i ,r ^ (Nickel. The phenomena attending thefe mixtures have not been as yet particiuarly oblerved. SULPHUR, as above. T LAT INA may le comhhied iv'ith the fvUoiv'mg Suhjlarxcs, viz. .ACIDS: Muriatic*; with tke phenomena, fiff. mentioned above. ALKALI : Volatile, as above. METALS : Gold, Silver, Mercury, Tin, Copper, and Iron, as above, f Zinc, Bifmuth, and Arfenic, as above SEMIMETALS {Zinc, Bii Cobalt. Nickel. The phenomena attending tliefe mixtures not yet ei>ferved. COBAL T may le combined unth the foUoiving Suhftances, viz. ACIDS.-: Vitriolic, Nitrous, Muriatic, and Urinous; with the phenomena, ^c. as above defcribed. ALKALI : Volatile, as above. , . „. , -n ■ ^ • -l ^Safre. By mixing calcined cobalt with calx of flint, and moiftening them with water, wiu EARTHS. Calx of Flint. ^ preffing them clofe in wooden tubs.^ I Smalt. By vitrifying thefe with the addition of a little potafh. METALS : Gold, Silver, Platlna, Mercury *, Lead, Tin, Copper, and Iron^ as above. ^ . ^ „ CZiNC, Antimony, Bifmuth*, and Arfenic, as above. SEMIMETALS. ijsjj^^jjEL. The properties of this compound not known. . NICKEL may le combined unth the foUoiving Std/flances, viz. ACIDS : Nitrous, and Muriatic ; with the phenomena, ^c. as mentioned above. ALKALI : Volatile, as above. METALS : Gold, Platlna, Lead, Tin, Copper, and Iron, as above. SEMIMETALS : Antimony, Bifmuth, Arfenic, and C&balt, as above. SULPHUR, as above. ABSORBENT EARTHS may le comblv.ed with the follo'wmg Suhftances, viz. ACIDS : Vitriolic, Nitrous, Muriatic, and Vegetable ; with the phenomena, and by the affiftances above mentioned. ALKALIES : Fixed as above. ^ r -l i .i. r ^ u*^ r Crystalline. By this mixture they are both much eafier melted into glafs than by themielves, but not EARTHS. \ without the addition of fom€ alkali. CArgillaceous. This mixture eafily runs into a glafs without any addition. WATER Lime-ivater. By folution. It is fometimes found flowing out of the earth in fpnngs ; and as it alv%'ays quits ' the water when expofed to the air, it is there depofed on the banks of the ftreams, forming the iton^ incruftations called petrifications : And filtering through the pores of the earth, and dropping through the roofs of fubterraneous caves, it forms the curious incruftations found hanging from the root oi iucU places ; fometlmes afTuming forms ftupenduoufly magnificent. _ , • • i • r ATR FixT. Lime-ftonc. It is from the quality that quick-lime lias of abforbing its air, and again with it relu niing its ftony confiftcnce, that it is fitted for a cement in building ; and the great hardnefs of ttf cements in old buildings is owing to the air being more perfeSly united with theft than m new^ works. CRTSTALLINE ar VITRESCENT EARTHS may le combined M the fsJIswing Suljances y yiz. ACIDS : Vitriolic*, and Nitrous* ; with the phenomena, ^c. as above mentioned. ALKALI : Fixed, as above. ABSORBENT EARTHS : as above. ARGILLACEOUS EARTHS. A mafs running into gkfs in a moderate beat. METALS : Lead, Tin, Copper, and Iron, as above. . . u-^ c „ WATER. Although this is not fdluble in water by any operation that we are acquainted with ; _ yet, from -its cryfxalhne fom it is probable that it has been once fufpended ; and certainly it is fo at this day in thofe petrifying fprmgs vvhofe mcruilatiOE are of the cryfl;alline fort. •SEMIMETALS : Antimony, Bifmuth, Arfenic, and Cobalt, as above, ,JR GIL LA CEO US EAR TH may le combined mth Abforbent and Cryftalline Earths, as above. Wixh water it only utiites int a pafte of a mechanical nature. I N D E 3 Index. H E M I S T R Y. 6iS N D E X. Absolute heat, defined, n« 37. Difference of the abfylure heat ot different fluids, 46. _ Abrorption of heat the univerfal caufe of lauidity, i'9- Vapour formed by the abfo! ption of latent heat, of H.>mberg*s pyrophorus explained, 1418. Acetous acid, its fpecific gravity, 400. Thi-i acid and its combmat:ons j.ar- ticulavly treats,-^ of, 867. Procu- red by a particular kind of fermen- tation, ib. Of its coiv.b.nation with alkabe5,868. With earths, 8 7X etfeg. With metallic fubftiuces.ib. Whether tin be Coiuble in it 879- Of its o.ncentrati' n, ^Hf. M^>y^be crvftalli/.ed in forri of a fait, 882,. May be reducc.l into an aerial form, 88.V - combination vvith inflammable bodies, 884. Prodii- ces a greater qi.antit) of etbe._ than the x^trlotic acid, ib. Acd of milk fcems to be of the acet us kind, 9-3 Whey n-.ay be con- verted into an acetous acid^ 979; May be almoft entirely deftroyed by fire, icoi. Requifite. for bringing it nearer to the ftate of ta-tar 1002 Weftrumb s unfuc- cefsful attempt to do fo, 1003. Dr Creil's opinion of the pollibiiry ot this tranfrautation, 1004. Method recommended by him for trymg the experiment, 1005. His expe- riments proving that all the vege- table acids may be reduced to the acetous, .co6, 15"/^. Manga- nefe foluMe with difficulty m it, 1^60 Procurable from the reli- d^luni of vit irdic eth deicded by Mr Kirviran, 642. This excels necef- fary to render alum foluble in wa- ter, 643. Too great an excefs- prevcnts the cryftaUiza: ion of the lalt, 681. Tills excefs beil reme- died by the addition i.i pu. c clay- to the liquor, 6S2, etfiq. I he fu- - periiuous acid might be advanta- geoufly.diftibed, 6S9. Nitrous a- ■ cid and its eombi:;atii»ns,722,£."/y^^. . See Nitrous. Experiment <'n the tranfmutation of vitriolic into ni- ■ trous acid, 721. Incunclufr- e, 722. Marine acid and its r. m!iinations, 7-82, et fi'q.; Tins acid m ly be de- phlogiitlcated by fpirit of nitre or manganefe, 790. Mr Scheele's method of doing it- by ineans of manganefe, 791. l^ropercies of deplilin, 984, ct fcq. See Flavers and Ben- zsifi. Whe'her the acid of fugar ■ or of tartar- is the balis of the an."'- malous veg"et;iMe r.cids, 996. Dr CrcU's method of crytlalli/iny; the acid of lemot-s, 997. The cvyllai- lized Calt cannot be converted into acid of fugar, 999. Product of the acid of tartar by dry diitillatioii, 1000. Acetous acid alaioH entirc'ly tleftrudtible by lire, looi. Of the ■tranfmutation of the vegetable a- cids into the acetous acid, 1002 — 1015. See Acetous. Phenomena re- fulting from the mixture of acid .fpirits with one another, 1040. Solution of falts promoted by vi- triolic acid, 1048. Terra ponde- ruh ufually found in a ftate of combination with this acid, 1049. Eficdls of marine acid aerated terra ponderofa, 1053. See Terra Pomkrofa. White matter coi;tain(>d in the vitriolic acid fliown to b.j pypfum, IC59. Vitriolic acid ea- fily difcoverable byfolution of terra ponderofa, 105S. Marmor metal- liciim foluble in very concentrated vitriolic acid, 1063. Whythefliior Ecid will not dilToIve flint: diredlv, 1073. Why the filiceousearth 1'. . Butter of arfenic can fcarce be made to unite with marine acid, 1282. Reguius 7i. Unite with alkalies into neutral falls, fome- times with, and fc-metimes with- out, flFervefcence, 172, Change the blue coh ur of vegetables t^> red, 173. DiTeient degrees of their attradioii to alkalies, 174. The vitriolic ftrongeft in a liquid fta'e, ib. Marine acid Arongctl: in a flate of vapour, \h. 'I'he fixed acids llrongetl when the fubjedls are urged with a vioK-nt heat, ib. Attiadion of the cUfTerent acids for pldrgifioi], (75. The acids are caijabie of formiiig an union with metals or earths, i;6. Will leave a meral to uiiite with an earth, 176, 177. And an ec.rth to unite v/iih a ndid vobitile alkali, ih. Will leave a volatile, to unite with a fixed alkali, ib. Some will Icive i'lxed alkali to unite v\itii phlo- A. gillon, 175, 178. Exceptions to thefe rules, 179, Why precipi- tates are fomctimes thrown down by them, Exnkaation of the S T R Y. df compolitlons efLded l)y acid, lone, 266. Quantities of the dif- ferent acids taken up by v.irious bafes, 268» I'his quaiitity exprcf- five of the quantity of attradion they have for each of thefe bafes, 267. Vitriolic falts decompound- ed by the nitrous and marine acids, 275. Acids tmite with alkalies l y giving out iire , and qiut them by i e- ceivingit,286. Theattradivei-i.w- ers of acids to metals diflicidt to be de- termined, 296. Proprrcions of the differdnt metallic fubftances taken up by the different acids. 298.. .Me- tals have a greater affinity with a- cids than alkalies, 1()<),Z'^^. Ex- planation of the table of the affi- nities to the different metallic fub- flances, 316. An equal quantity of all the mineral acids taken up by vegetable fixed alkali, 402. Quantity of this alkali recpiifite to faturate the feveral acids, 403. A- cids can never totally dephlogi'di- cate metallic eartlis, 407. Con- centrated acids phi igrllicated by alkahes, 4C9. Of the time re- qidred by mixtures of the mine al acids with wa'.er to attain their ut- mort der.fity, 422. Of the altera- tii-ms of their denfities by various dcjjrees of iieat, 423. Acids can- not difi' l^e calc i;ed ma-nefia Without heat, 442. P'lenome- na of d'.tferent acids with in- fl?.mmable fubftance-, 518. Me- tals folulde in acids, 520. Calci- nation and incieafe of their weight by acids, 523. H-.w to diHil the mineral acids, 5 75. Vitriolic, phof- phoric, and acetous, acids, found in tbe refm extradcd fiom the le- fieiuum of vitriolic ether, 2d 722, Ni'ruiis, marine, and phofphorlc acids, capable of expeilintr the fluor acid, 2d 850. Atids of fal amnno- niac and nitre expelled by fait of amber, 910. Of the anomalous ve- getable acids, and the rcfemblmce which vegetable acids in gei.cral hear to one another, 984, et fe/, EIovv the anomalous vegetable a- cids are d.lvided, 993. Of the cf- iential acids, 994, Empyrtuma- tic acid«, 995. Whether the acid of fugar or of tartar be the bafis of the vegetable acid'^,vy96. D/Creli's proofs that all the vegetable acids may be reduced to one, wliich is contained in the purelt i'j.irit of wine, ioc6. Phenomena attend- ing the d ffolution of vitriolic falts in nitious or marine acirper un- dergoes a change by combination with vegetable acids, lijl. Co- loiirin',r matter of Pi-uffiun blue e.x- pelled by acids, and then taken up , by the atmofpheie, 1177. Pheno- mena of arfenic with different a- cids, 1275. Manganefe becomes in- foluble in puie acids, by lofing its phi 'gillon, 1375^ See /lciJs,Vitri(i- l':c, 'Slarir.e, Vegetable, l3'c. eiJs and Aliif/ies- inaccuracy of the common teds for trying them, 15.-J9. Mr Watt's experim.cnts ..)n this fuiijeift, ib. His method of p iparlnga tell from .cabbage and c_^her plai-its, 1550, etfeq. Abforb ?.ir d•c.ri.^g their fouuation, 1543. Adopters, or Aliideh, defcribed, 5 79. Aerated terra ponderofa, analized \ff Dr Witheriiitr, --0^ 7. Aerial acid: the converiion c f dej hlo- giflicaied air irto it by means of charcoal, a proof of the identity of phlogiiton and charcoal, rjr. De- fcription of the terra ponderofa combined with the aerial acid, 1051. Aerial acid and phlogiilofl fuppofed to e.xiLt in the colouring matter of Pruffian h ue, 1196. Sec Fixed Air. ■4jU^ni.ties,Q\Atkt\',t and divcllent, de- fcribed,'267. Table of the affini- ties cf the three nihieral acids fo the different metals, 298. Expla- nativ-n of this table, 316. Table of the proportlon.-.l affinities of the nict.illic calces to phlogillon, -530, - Dr Black's general table of affmi- tje-S 553- AJjhiity of the different metals to ph!oj;ifton, how determined, 318. Ager.ts in chemiilry.howdiflirguifli- ed from the obieds of It, 22. Air fnpjiiies inflamm.-ble bodies with the heut rhey em't during contbu- flion,. 137. Tor. irreut a quantity of air will diminifh the heat of a lire, or even put it out entirely, and why, 159. O.dy a fmall quan- tity of air can be cbta'ned from metals when calcined, r9i. Dif- fe:ent kinds of it produced during the diffolution of n etals, jor. Spe- cific gravity i f the diffarent kin. Is of air according to Fontana, 375. Expofure of alun.inous ores to the air fome'imes has the fame effcdt with roalbng them, 663. Vitriol deprived of its phi, .gift on by expo- furcto the air, 687. Lixivium fan- gidnis lofes its colouring matter by expofure to tl-.e air, 1172. This colouring matter taken up by the air after It has been expelled by a- cids, IT77. Ab '"orbed during the formation of acids, 1543. Air-L:bbles j)r(,duced in water du- ring the ad of congelaticm, occa- fion its expai.fion and prodigious force, 109. Tliey are extricated by a part ( f the latent heat dif- charged from ihe water at that time, no. Alchcmifis : their labours were of fome advantage to chemiftr) , 13. Alchemy firft mentioned by Julius Ficmdcus Maternus, a writer of the 4th centin y, 8. Suppofed tobe firit derived from the Arabians, JO. The j.rcteHders to it very nunaerous in the beginning of the 1 6th century, n. Alchirnfs experiments on the efftd,s of mixing tin with gold, 109J, etfeq, Alemhic, derivation of that word, 5. Alembrotb Jul, made by fuliliming e- qual quantities of corrofive fubli- mate and fal ammor.iac, 1047. Said to diffolve all the metals, ib. Convertible by rep-ated didilla- tions into a fluid that cannot be raifed into vapours by the ffrongefl heat, ib. A'g.iruth po-zvder, prepared by preci- pitatmg butter of an'imoiiy with • wate.-, Szi. Tiie nioli pro] er ma- terial Index. terial for the preparatinn of eme- tic tartar, 1459. Shown by Mr Si;hct-)e to be a regulus Jialf calci- neil by deplilr^gifticated marine a- ci ', i2ti. His receipt for prepa- ring it cheap, T l6l. Ali'Ui k'fs attracSVed by nitrous acid than filver, 301. Adecailic earths more P:i (ngly attracted by acids than volnrile alkali, ,^03. Why the T'CtaMic f-arths frldom decnnTjX'f'e thofe f< Its that have an alkal- for their hafi«, ^o/^- Quantity of alka- li, acid, and water, contained in d.geftive fait, 379. M Kirwan's tneth:;d of fatiirating an alkali ex- adtlv wit!-, an acid, 381. (>nantity of mild and cauftic vegetable fix- ed aikali futurated by a given weijjht of marine acid, 382. Quan- tity of alkali, water, a:,d acid, in nitre, 391 Of the fame ingre- dients in vitriolated f.rtar, 398. i Vegetable fixed alkah takes up an equal quantity of all (he mineral acids, 402. .Sj)ecific gravity of the •vegetaMe alkali detej miped, 411. Quancit) of earth contained in this alka'i, 413. Of the quantity of fixed air contained iti oil i f tar- tar ai d dry vegetable alkali, 414. i^antinci of fixed air contained in impure vegetable alkali deter- ji'iined by M- Cavendiih, 417. Ex- a(5l quantity of acid takeij up by n ild fixed alkali, 418. iM'neral al- kali how prepared by Mr Kirwan for his experiments, 429. Of the quantity of yitriolic acid neccf- fary to faturate 100 grains nf it, 430. Quantity of dephlogiilica- ted nitrous acid taken up by it, 432. Of the marine acid, 433. Proportion of pure alkali, water, and fixed air, in crjftdliized mii.e- ral alkali, 434. Excels of acid in aluminous liquor cannot be remo- ved, by mineral aikali, though it may be !>y the vegetable and vo- Jat:le kinds, 680. Vitriolic acid combined with fixed alkali, O28, 629. With volatile alkali, 633. Nitrou" acid combined with vege- table fixed alkali, 740. With fof- filf alkali, 741. With volatile al- kali 745 Marine acid combined with vegetable alkali, 794. With mineral aikali, lb. Wi,h volatile alkali, 795 Fluor acid combined with fixe ! alkali, 4th 850. With volatile alkaK, i . Glafs cor- roded by the fait foimed from the union of faior acid and volatile al- kali, 854. Sedative fait combined with the vegetable a kaii, 862. With the miner?.! alkali, 863. A- cetocs acid combined with vei e- table alkaii, 868. Wi:h mineral lalkali, 869. With volatile alkali, 870. Acid of tartar co)rJ)iiied with vegetable alkali, 889. With fofli! alkali, 891. With volatile alkaii, 892. Acid of f;.gar with vegetable alkali, 899. W:th fclfil • alkali, i!\ Incredible quantity of volatile alkalifaturated by it, 900. Phc fphoric acid v\itb. fix,:d alkali, 906. With volatile al!:a!i, 904. Acid of ants combine i with lixtd and volatile sikali, 908. Acid < f aBiber with fixed alkalies, oog. Vol. IV. Part II. G H E M I With Volatile alkali, ib. Aci ! of arfenic with vegetable fixed alkali, 92^. With mineral aikali, 927, With volatile alkali, 928. Vege- table alkali capable of being re- duced into cryflals by means of fpi- rit of wine, ior7. Without any addition into ('eliq';efcent cryflals, ib. Mineral al!:ali always affumcs a ciyttalline f. rni, ib. t.'haiige on the vegetaMe alkali by being united with fpirit of fait, 1018. Difference betwixt the vegetable and mineral alkali, 1019. The for- njcr has a greater attratftion for a- cids, ib. Both of them compofed of a cauflic fait and fixed air, 1020. Of the volatile alkali, 1030. Of the method ofdi{l;illingit,i03l. Of its reclilication,i032. Combined with fixed air, 1033. Combined wi'h merals, 1034. With inflammable fubft.mces 1055. With expreffed oils, ih. With eflential oils and fpirit of wine, 1036, 1037. With fulphur, 1038. Solutions of cal- careous earth decompofed by n^ild volatile alkah, J046. Cauftic fix- ed alkali throws down an infoluble precipitate from folution of terra ponder ofa, 1056. Vegetable al- kali precipitates marnior nietalli- cum unchanged from c )ncentra- ted vitriolic acid, 1064. Volatile alkali precij itates filiceous earth more completely than any other, 1074. A tri; le fait formed by pre- cipit.'.tiiig this earth with fixed al- kali, 1075. Siliceous earth diffol- ved by boiling in folution of alka- li, 1076. A remarkable atrraiftion betwixt fixed alkali and fihceous earth in the dry way, 1077. The ufe of volatile alkali only lately known in the prepara- tion of aurtim fulminans, (106. This alkali the caufe of the explofion, 1121. It exhibits a flalh when thrown into a crucible by itfelf, 1122. Ufed in the prepa- ration of fulminatin? filver, 1139. Plilogifticated alkali lofes its pe- culiar properties, 1 168. Colouring matter ©f Fruflian blue ui;iies with volatile alkali, 1182. Forms a kind of ammoniacal fait with it, 11 86. Volatile alkali produced by difliil- liiig Fruflian blue, 1197. Pheno- mena on diflrilling metallic preci))i- tates thrown down by Fruflian alka- li, 1 198. Volatile alkali capable of uriting with fixed alkali and phlo- giflon foas to be capaliJe of fulb n- ing a great d;'gree of heat, 120a. Phl.igiflicated alkali cannot preci- pitate arfenic except from marine acid, 1273. EflTeciis of volatile al- kali on nickel, 1314. Mineral alkali capable of drcompofing c: y- ftals (pf platina, but not the vege- table alkali, 1322. Cr ftallinc powder j recipitated from folu- tion of calx < f platii.a in marine arid, by means of vegetable alka- li, 1325. But Hi t from the fokiti n in nitro«'< acid, 1326. Whether mine; al alkali can decoaipofe folu- tii.ns of platina, 1328. Fifty-fix times HS much of it required for thi--- purpo'e as of vegetable alkali, ^.3*9. £ifcds of the volatile alkali S T R y. on folut'ons of pb.thia, 1330. Vo- latile alkali deltroycd by manga- nefe attradling its phlogifton, i3i;4. See Alkalies. Wiegleb's account of the phenomena attending the diffolutlon of copper in it, 1035. I's elfe^son dejihlf giilicated Ipirit of fait, 1485. Higgins firft d fco- vercd its conflituent parts, 1553. Procured if fr(mi nitrous acid and tin,ib. Effedl of Jie cledricfpai k on a mixture of it and dej hlogifri- cated air, 1555. True compofi- tion of it, 1556. Alkalks ; one of the general clafTes of falts, 169. Divided into fixed and volatile, 170. The former fubdi- vided into vesjetable and mineral, ib. Difference between their a (Slion andthatof acids, i-i. Neutral falts foi m them by being united with acids, 172. Vegetable blues chan- ged green by them, 173. Diflerent degrees of attraction betwixt them and acids, 174. Phenomena at- tending the precipitation of me- tals by them, 220. Vula ile alka- lies particularly apt to form trij le falts, 274. Why they precipitate the metals, 300. Metals have a greater affinity with acids than al- kalies, though the latter fepaiate them from acids, 299. Why luna cornea cannot be reduced without lofs by alkaline falts, 314. Alka- lies phlogifl;icare concentrated a- cids, 409. Proportions of the dif- ferent ingredients in volatile alka- lies, 436. Stone-ware veflels cor- roded by cauftic fixed alkalie?,595, 596. Advantages of ufing ch.y ra- ther than alkalies for abforbing the fuperfluoHs aci 1 in aluminous liquor, 083. Solution of filver de- compofed with difTu ulty by alka- lies, 756. How the alkalies are jirocured, ioi6. Differences be- tween the vegetable ai)d mineral alkalies, 1019. Combinatiojis of them w ith fulphur, 1021. With exijefled oils, 1026. With eflen- tial oils, 1027. With phloj;iiion, 1028. Diflfercnces between the fixed alkalies obtained from diffe- rent vegetables, ib. Solution of terra ponderofa in marine acid P'ecipitated by ail the alkalies, whether mild o;- cauflic, 1054. Alkalies difTolve lead by boiling, 1216. Effccfls of arfenic on alkalies, 1290 Teit for them and acids, 1549. See AUali, Acid, and Acids, Alkaline falts. See Alkali and Alia- lits. Alkaline ley improper for extradlitig the flowers of ben- zoin, 989. Aljlon-Moir '\\\ Cumberland, a kind of aerated terra poni^erofa found near that place, loji. Aludels, or Adopters, defcribed, 579. Alum : cannot form Glauber's fait by being difl" Ived in water along with comm n fait, 274. Miftake ol Dr Ciell on th s fubje(il cor- redlcd, ib. Nor blue vitriol by boiling it with coj per filings, 349. Why its precipitate retain- pan of the acid, 408. Its earth contains 26 J>er cent, of fixed air, 446. Pro- portions (/f the ingredieiits in it, 447. The fait always Ct^ntains.an 4 I 61 i exc.fj of add, 443. Proportion of the earih of alum taken up by ni- trous acid, 449. By m.arine acid, 450. Alum of the ancients diffe- rent from ours, 637. The name Roch-alitm derived from J?c«o, a city of Syria, 6_,8. Fi'-(t made ia Europe in the middle of the 15th century, in Italy, 639. Made in Spain in the 1 6th century, 640. In iEiigland and Swedisn in the 17 th, ib. I'S component parts firfl difco- vered by Boulduc and Geoffroy, 641. Found to contain an excefs of acid, ib. This ilenied by Mr Morveau, 642. His miftake dif- covered by Mr Kirwan, ib. Info- luble in water when deprived of its fuperfluous acid, 643/' Eafily calcinable in the fire; after which it is cal'ed burnt alum, ib. Bergman's method of (inding the proportion of the i igredients it contains, 644. Difficulty of obtaining the earth of alum in a pure fl;ate, 645. Mr Bergman's account of the propor- tion of the ingredients, 646. Whe- ther earth of alum be a pure clay or not, 647. Dr Lewis's experi- ment, tending to fliow that clay undergoes fume change by being converted into earth of alum, 649. Quantities of alum foluble in wa-m and in cold water, 650. Bergman's account of the Swedifli ores of alum, 651. Component parts of the aluminous fchill, 65a. How changed by roafling, 653. Prefence of pyrites the onlyrequi- fitf for the prndudtion of alum, '654. Ores containing alum ready formed only to be met with in volcanic countrirs, 655. Ores of alum at Solfatara in Italy, 656. Analyfed by Mr Bergman, 657. Heffian, Bohemian, and Scanian, ores, 63 8. Alum, fulphur, and vi- triol, extra(fled from the fanre ore, 6;;9. Ah m Hate foimd at York in England, 660. Bergman's direc- tions for the preparation of alum, 661. Ufes of roafl;ing the ore, 66z. Expofure to the air fometimes has the fame effedl wi h roafl:ing, 66% Earthy ores unfit for either pur- p'jfe,_664. Method of roafting the ore in Sweden, 665. How often the operation is to be repeated, 666. Danger of increafing the heac too much, 667. Rinman's method « f roafting the ore at Garphyttan, 668. Method of burning the hard ores at Tolfa in Italy, 669. Me- thod of elixating the burned ore at Garphyrtan, 670. Heat and cold water ufed f( r this jiurpofe in dif- ferent j.laces, ib. Differer.t me- tbo Is of elixation, 671. Singular circumftance by which the alum is faid to be deftrwyed, 67a. Of the proper ftrength of the lixivium be- fore It is c mmitted to evaj ora- tion, 673. Conflrudion of t e e- vaporating veff.'!, 6-4. He vv far the liquor ou'^ht to be evaporatetl, 67J. Of the lin. cry;:;,niz:,.t;on, 670. D puiation of the cryflals, 6; 7- Beigman's remarks v.n the proper fi^rm of the c;..,icr5, 678. They ought to be of a conical Ihape, lb. Aluminous ley contains to 6iS fo much acid tliat 5c f annct be cry- ftallized without abftradcing part of the excefs, 679. Which m'.y be d me by tlie addition of vej^e- table fixed alkali, or volatile alka- li, but not by the mineral alkali, (>io. Experiments in proof of the excefs of acid preventing the cry- ftallization of alum, 681 . Another, Ihowing the ut ility of adding clay to the a'uniinousley, 68i. Advan- tage of ufing it in preference to the alkalies, 683. Alum general- ly contamir.ated by dephl'^gifli- cated vitriol, 684. Thi^ defetfl: re- medied by the addition of pure day, 685. Perfedt vitriol cannot be deftroyed by clay, 686. How the phlogifton of vitriol may be diffipated, 687. Epfom fait fup- pnfed to be producible from the mother liquor of alum, 688. Su- perfluous acid of this liquor might be advantageoufly (^iftilled, 689. Combination of arfenical acid with earth of alum, 938. How to make it fhoot into cubical cryftals, 689. J^lum JIate. See yllum. Alum ivorh, when firft fet up in I- taly, 639. In Spain, England, and Sweden, 640. Aluminous ores. See Alum. Amalgamation of filver : a difficulty concerning it fulve l by Mr Berg- man, 217. Of copper with mer- cury, 115a. Dr Lewis's methods, 1153. Amalgamation of mercury with different metals, 1132 Amber, acid of, 908. Mr Pott's ex- peiiments on it, 909. Requires a large quantity of water for its fo- lution, ib. Rendered fomewhat purer by cryftallization, ib. Part- ly deftroyed by fublimation, ib. Forms a neutral faline liquor with fixed alkalies which does not cry- flallize, ib. Forms an oily fluid with volatile alkali, ib. Extri- cates the acids of fal ammoniac and liitre, 910. Purified by marine a- cid, 911. Doet not contain any mineral acid, ib. Converted al- moft entirely into a liquid by di- flillation with fpirit of nitre, 912. Moft of it rifes in a folid form by diflilling with oil of vitriol, 913. Forms a folution of quicklime, moftlyrefembling the fame, in ve- getable acids, 914' Its effefls on the metals, 91J. Amber, by di- flillation, yields an acid fait and oil, 1444. Difference in the produdl by certain additionsfometimes ufed in the diftillation, ib. Addition of fea-falt produces the greateft yi^ld of fait of amber, ib. Greateft quantities of amber diflilied in PruiFia, 1445. Diftiiledthere with- out any addition, ib The fak ) u- rificd by bcin;^ kept on bibulous paper to abforb the oil, ib. Cry- llals refembling it formed by the nnion of marine acid with phlogi- ftic matters, 1481. Methods of purifying its fait, i494- An acid of another kind paffes over in di- AiUing this fubfiance, i493- Com- bination of the fait with alkalies, earths, and metals, ib. Mr Keir's remarks on the nature of fait of amber, 1495- G H E M I Amh?tfgreafe yields a produ6l on di- ftillation fimilar to that of am- ber, 1446. America : method of making nitre there, 726. Ammoniac, vitriolic, decompofed by folution of filver, 306. How to prepare this kind of fal ammo- niac, 633. Erroneoufly faid to hav.! powi rful effefts on the difib- lution of metals, ib. Mr Pott's experiments on it, ili. Nitrous am- moniac, how prejiared, 745. Is fo- luble in fpirit of wine, ib. Defla- grates without any addition, ib- The principal ingredient in Ward's white drop, 746. Common fal ammoniac prepared from marine acid and volatile alkali, 795. Dif- folves refins according to Mr Gel- lert, ib. Its volatility diminilhed by repeated fiiblimations, ib. A fmall quantity producible by di- ftilling fea-falt with charcoal, &c. ib. Originally prepared in E- gypt. 796. A method of making it defcribcd, ib. Vegetable ammo- niac formed of the acetous acid and volatile alkali, 870. Can fcarcebe procured in a dry ftate, ib. Acid of common fal ammoniac extrica- ted by acid of amber, 910. And by the arfenical acid, 932. Vola- tile fal ammoniac, how prepared, 1E33. Common fal ammoniac nr)t decompofed by regulus of cobalt, 1304. Effects of it on nickel, 1312. Solution of it precipitates a folution of platina, 1352. 'I'he precij)itate fufible by a ftrong foi ge heat, 1353- This fufion fuppofed by Macqutr not to be perfedl, 1354. Effedts of manganefe on it, 1392. Ammoiiiacal fait, formed by the union of the colouring matter of Pruf- fian alkali with volatile alkali, 11 86, Animal earth, very infoluble in acids, and infufible in the fire, 515. Earth of the foft parts more fo- iuble than that of the hard, ib. This earth erroneoufly fiippofed to contain phofphoric acid, ib. Ani- mal fats analyfed, 1428. Yield a great quantity of oil by diftilla- tion, ib. A particular kind of a- cid produced from tallow, 1429. How to redflify the empyreumatic oil of animals, 1417. Of animal and vegetable fubftances, 145 1. Anomalous earths, 513. Anomalous vegetable acids, how divided, 993. Antimony : why nitrous acid precipi- tates a folution of it, 500. Preci- pitates of it by common and phlo- gifticated alkalies, 246. Of its pi e- cipitates with other metals, 365. A triple fait formed by regulus of antimony, marine acid, and iron, 366. Another with the regulus, marine acid, and copper, 367, Of the folution of the regulus in vi- triolic acid, 499. Of its combina- tion with that acid, 709. Corrod- ed by the nitrous aeid, 768. Re- gulus of antimony combined with marine acid, 821. Of the amal- gamation of it with mercury,! 237. Renders bifmuth capable of unit- ing with cobalt, 1251. The re- gulus particularly treated of, 1232, S T R Y. et feq. Has the appearav.ce of a ftar OH its furface when well made, 1252. Sublimable into flowers, , 1253. Different methods of pre- paring the regulus, 1254. Confi- derable differences in the regulus, according to the difftxent fubftan- ces ufed to ahforb the fulphur, 125J. Of the regulus made with cawk, 1256. This femiiuetal ea- fily mifcible with mercury, 1255. Enters into the comjufition of fpeculumsandjirinting types, 1256. Was the bafis of many medicinal preparations, now difufcd on ac- count of their uncertain operation, ib. Glafs of antitnony, how pre- pared, 1257. More violent in i's effedts than the regulus itfelf, ib. Pi eparation of emetic tartar from glafs of antimony a:)d pulvis alea- roth, \%$%,et feq. See Tartar and Algaroth. Preparation of golden fulj^hur of antimony and kermes mineral, 1263. Diaphoretic anti- mony, 1264. Crocus metallo- rum, 1265. Butter of, Mr Dol- fus's method of preparing it, 821, Antiphlogijlians : their abfurd way of explaining the explofion of fulmi- nating filver, II44. Ants yield an acid by diftillation or infufion in water, 2d 907. Its na- ture and properties, 908. Ants, acid of, cr.mpo.'"es an ammo- niacal liquor with volatile alkali which cannot be reduced to a dry fait, 908. Cryftallizes with fixed alkalies, ib. And with coral chalk or quicldime, ib. Diffolves cal- cined copper, and forms beautiful cryftals with it, ib. Makes a pe- culiar kind of faccharum fatunii with minium, ib. Its effedls on other metals, ib. Different me- thods of procuring their acid, 1502. Properties of the pure acid, 1503. Has an affinity with the acetous, 1304. Its effedts on me- tals, 1505. Apples, th«ir acid treated of, 1506, Its properties, 1509,1511. How prfflcured in perfedt purity, 15 10. Produced from fugar by means of nitrous acid, 1512. Mr Keir's opi- nion concerning its nature, 1514- Aquafortis, procured by means of ar- fenic of a blue colour, 7^9. Aqua-regia, beft kind of it for diffol- ving gold, 481. Quantity of gold taken up by it, 482. How pre- pared from nitrous acid and com- mon fait, 788. Of the folution of gold in aqua-regia, 1099. Solu- tion of platina in an aqua-regia compofed of niti ous and marine a- cids, 1323. In one made *ith marine acid and nitre, 1324. Va- rious methods of preparing if, 1488. Differences between the li- quors prepared by thefc methods, 1489. How to deprive it of its volatility, 1548. Aquila alba, a name for mercurius dul- cis, 814. Arabians, the firft broachers of alche- my, 10. Arbor Z);i7n«, how made, 754. Ardent fpirits, diffolve camphor in great quantity, 1425. Argqnd'i lamps, ufed_for Ump-furna- Index. ces 6ir. Doubtful whether they be preferable for this purpofe to Lewis's or not, ib. Argentine fotvers , formed of regulus of antimony, 1253. Argillciceous earth, in what it differs from the calcareous, 5 12, Tobac- co-pipe clay the pure'l earth of this kin 1, ib. Abfor]) colours, ib. Refift the utmoft violence of fire by fhemfelves, but melt by a mix- ture with chalk, ib. Combina- tion of the aririllaceous earth with vitriolic acid, 637, &c. See Alum. Argonauts, origin of the fable of them, (>. Arfenic : Of its diffolutioii and preci- pitation, 243, 36H. Calculation of the quantity if pld' gillon contain- ed in regulus of aifonic, 318. Pi e- cipi.tatcd by bifmuth from the ni- trous acid, 369. yVnd by copper from the marine, 370. Quantity of vitriolic acid taken uji by regu- lus of arfenic, 501. Of nitrous acid, 503. Of marine acid, 504. Compounded of a particular kind of acid and phlogifton, 548. U- nites with fulphur, ib. Is foluble in water, ib. Expels the acid of nitre, ib. Reafon of this decom- pofition, ib. Phenomena on di- Itillation with the virriolic acid, 711. Dephlogilticated by the ni- trous acid, 770. Of the adultera- tion of eorrofive fublimate by ar- fenic, 818. Oil and butter of ar- fenic, 823. Foi meJ by fubliming arfenic with corroilve fublimate, ib. Of the arfenical acid, 916, et feq. See Arfenic, acid of. A fingle grain of regulus of arfenic dellroys the malleability of an ounce of gold, 1095. Has a great affinity with tin, 1219. Methods of fe- parating arfenic from tin, 1220. The crackling noife of tin in bending fuppofed to arifa from ar- fenic, 1 22 1. Arfenic found in f ime places of Germany in a me- tallic form, 1266. The regulus eafily convertible into cemmon white arfenic by diifipating part of its phlogifton, 1267. Why the ar- fenical calx may be mixed with other metals which will unite with it in its reguline ftate, 1268. Of the folution of the calx in water, 1169. In fpirit of wine, 1270. Forms a very infoluble and fixed fait with vitriolic acid, 1271. Dif- folves in large quantity in the. ma- rine acid, and forms a more vola- tile fait with it, though difficultly foluble in water, 1272. Refem- blance of this folution to butter of arfenic, ib. Phlogifticated alkali precipitates arfenic from marine a- cid, and from that only, 1273. Ar- fenic decompofed by dephlogifti- cated marine acid, 1274. Pheno- mena exhibited by it with other acids, 1275. Liver of arfenic formed by combining it with fix- ed alkali, 1276. Arfenic unites with fome metals, and cryftallizes with iion and zinc, 1277. Unites readily with fulphur, 1278. Com- pounds thence refulting, ib. 1279. Phenomena exhibited by minera- lized arfenic with nitre, 1280. Butter CHEMISTRY. Index. Butter (){ arfenic, laRi, Thi? fub- ftanre can fcarce be made tducea change on mercury hy keeping it long in a gentle heat, and by re- peated diililiations, without fuc- cefs XiK), 1130. 'Bohemia. : Bergman*^s account of the aluminousores in that country, 65 8 . Jioilipg-point of water in vacuo de- termined by Mr Boyle, 122. And by Mr Robinfun of Glafgow, 123. Bale: camphor converted into an cflen- tial oil by diiUlIation with it, 1423. Bolognian Jione, a kind of native phof- pkorus, 1081. How firft difca- vcred, ib. Margraaf's account cf the appearance of this flone, ib. How rendered lumujous, I082. Seems to be of a gypfeous nature, 1081,1083. Analyfis of it, and reafon of its fliining in the dark, ib. Borax, compofed of a peculiar kind of acid and mineral all^li, 863. How prepared in the Ea(l Indies, lb. Of its flate when firft im- ported from thence, 864. Hww refined, ib. .Said to be adultera- ted during this operation, ib. This denied by Dr Black, ib. Simple dilTolution and filtration all that is rieceffary, according to him, for the purification, ib. Its purification ac- cording to others, 1490. Has a glu- tinous quality, by which it gives a glofi to iiiks, ib. Us properi ies with C H E M I acids and various falts, 865. jBor7,v,acid ofjfound in akind(^f m:ne- ral-n Geimany , 838. Procured from the fait either by fulilimation or cryfta!!iza;ion, 858. Is fixed in the fire, and melts into a kind of glafs by a violent heat, 860. Dif- folves in f;.'!' it of wir.e, ib. Makes no change on the colour of vege- tabls juices, ib. Mr Bourdelin's experiments on its nature, 861. Mr Cadet's experiments, 86a. M. Beaume's opinion that it is produ- ced by rancid oils unfatisfadlory, ib. Of its combination with al- kalies, ib. Forms an unknown fait T/ith veget.ihle alkali, ib. And bo ax with the mineral alkali, 863. . Its efre(5ls on cobalt, T303. Beau- mc's obfervanons on the method of preparing the fedative fait from it, 1491. Properties of tlie fait, 1492. It* cnmbinatio!T^ with vo- latile alkali, earths, and metals, ib. Experiments with a view to deter- mine the nature uf the acid, 1493.- Boulduc, M. with GeofFioy, difco- vers the component parts of alum,. 641 . Boiillangert. opi'-von that the flnor acid is no other than the niarine combined with an earthy iub- ftance, 833. Shovstn to be error neous by Mr Scheele, 834. Bourdelin's experiments on the na:ure of the acid of borax, 861. Boyle, Mr, improve? the fcience of chemiftry, 17. His ojiinion con- cerning the mimber and nature of the elements, 24. Attempts to pros'e that fire is not an element, ib. I'hat the folid fubftance of bo- dies is converted into.air, ib. That water is converted into earth, ib. His arguments inconclufive, ib. His account of the produdtion of heat, 30. Determines the boiling point of water in vacuo, 122. His experiment fhowing the deftrudli- bility of gold, 1098. Curious kinds of mercury prepared by him, 142 7. Brafs, how prepared from copper and calamine, 1154. May be re- duced to copper again by a long continued atid violent heat difiipa- ting the zinc, ib. A compound of brafs and platina, a proper mate- rial for fpeculums, 1344. Burning : phenomena of it, 5 16. A great quantity of water produced from oil by burning, ib. Part of this probably from the atmor fphere, ib. Butter of antimony compofed of re- gulus of antimony and marine a- cid, 821. Becomes fluid by recti- fication or expofure to the air, ib. Lets fall the pulvis algaroth by the diredl afFufion of water, ib. For- merly ufed as a cauftic, ib. M. Dollfufs's method of preparing it, ib. Batter of arfenic, prepared from re- gains of arfenic and cerrofivc fub- limate, 823. Becomes fluid by re- peated redlifications, ib. Is not obtained from white arfenic and corrofive fublimed together, 946. May be pre] ared alfo byfubliming orpiment and conolive fublimate, isSi. Qan fcarcely he made to S T R y. unite with marine acid, 1282. CABBAGE, an excellent tell for aclc!* or alkalies prepared from it, T550, Cadet' % ex^ieriments on the nature of the acid of berax, 862,.. Calcareous tartbs. Deconipofition. of vitriolated tartar hr their folu'-iv)ns explained, 270. Mr Kirwan's ex- periments on tltem, 437. Forrti- gyjifum with vitriolic acid, 635. DilFoivein the nitrous acid into an acrid liquor which ca: mot be cry- ftalHzed, 747. De^ompofes this acid hy frequent difl;illations, 784. Are convertiJile by it into a kind of phofphoriis, 749. Fonii like- wife a phofphoi u< with the marine acid, 797. Their cffeJls on the folution of^ ftlver, 756. Form ar ftringent compounds with tlie ace- tous acid, 871. Decompnfe cream of lar.ar, 887. Have a grrat at- traftion for facchariite acid, 90c. Compofe fluor fpar by being com- bined wich its acid, 831. And- tungftau with tlie acid extradted from it, 971. Cakes of metals; arguments againft the exiflence of phlogiftoii from the reduelion of thofe of the per- feifl metals without additi on, 140. Redudlion of metallic calcc? hy in- flammable air, 149. Diffeientco- 1 urs exhibited by them, 19a. Thofe of fume n etals, when pre- pared by nitrous asid, almoft to- tally infoluble ever afterwards, 1 96. M''hy little or no e'aftic fluid is produced from t hem , 2 1 3 . Of i heir attrartion to i.hlo^ift(]n,3a6. How to find the frecific gravity of the different metallic calces, 327. Whence their vai-ious degrees of afiinity to phlogifton may he de- termined, 328. Calces of cojiper precipitate dephlogiilicated foiu- tions of iron, 343. Solutions of the dephlogifticated calces of iron re- fufes to cryftallize, 457. Calces of iron precipit.ated of a re Idilh co- lour from fpirit of fait, 463. C:d- ces of gold foluhle in the vitriolic and nitrous acids, 483. Reafon of the increafe of weight in metalline calces, 524. Beignian's opinion concerning the fulmination of me- tallic calces, 1 1 26. Erroneous, ib. Effedts of the colouring matter of Pi uflian blue on metallic calces, 1193. Calcination : quantity of philogifton loft by metals during that ojiera- tion, 332. Of the affinity of their calces to the deficient part, 332. Calcination of metals by fire de- fcribed, 52a. Of their calcination and increafe of weight by acids, 523. Reafon of this increafe,j24. Solubility of metals increafed by calcination, 545. How to perform the operation of calcination, 383. Why a flight calcination deftroys the explofive prope-ty of auruni fulminans, 1124. Effedls of vio- lent calcination on nick<;l, 1307. Calcined metals. See Calcination , Cal- ces, Calx, and Metal. Calculus, human ; Schcele's experi- ments on it, 1455. His conclu- fions concerning its coirtpofition, i4j6. Is found uuivtrfaiiy iii u- rilie, 1457. Bergman's experi- i.-.eiits on it, 1460. Calcareoui e;'.rth contained in it feparatcd hy means of the vitriolic acid, 1462. Rcvl colour of the folu<'ion in ni- trons acid accounted for, 1460. Mr Higgins's experiments, 1463. H's account of its component [iaif, 1465, 1468. Exjieriments on the fuhlimate arifing from it on diftil- lation, 1465. Experiments with nitrons acid, 1466. Cryftailiza- tion of the nitreus folution by ex- pofu' e to the fun, 1467. Remarks on the remedies proper for dilE li- ving the flone, 1469. Suhliaiate of calculus met with in C{)nfnmp- tive and gouty perfons. 1470. Dif- fi lutioii ought not to be attempted whf n the flone is large, ib. CjIcuIi/s: of the acid obtained from It, 982. All the calculi jiroduced in the human body of the fame na- ture, ib. Diflblved by concentra- ted vitriolic, and by the nitrous acid, but not by the marine acid, iS. The acid of calculus produces deep red f] ots on the ikin, 983. Afl"umes a blood-red colour by eva- poration, ib. Calomel, a name given to mercurius dulcis I'cveral times fublimed, 8t4. Repetited fublimation no improvc- men"- on the meiiphur,-i. volatile fubftance belong- ing to the clafs of cflential oiU, 1422. Converted into a true effen- tial oil by repeatedly diftilling it with bole,'i423. Into an acid hdt by diftilling it feveral times with de- phlogiftica'^ed fpirit of nitre, IA24. Effedts of this faJt on alkalies and metals, ib. How-diftinguiflied from acid of fugar, ib. Account of the method of extradling it from the trees which produce it, its.ufes, &c. ib. Canton's phofphoriis, how prepared, 1414. Becomes luminous by ex- pofure to the fun, or the light, of an eledlrical flafla, ib. Cnpacities of bodies for containing heat : that phrafe exjilained, 52. How they arc to be diilinguifhed from the temperature and abfolute heat of bodies, 53. The capacity of a body for containing heat the fame with the aftion of heat on the body, c r i . Nicholfon's account of the capacities of bodies for con- taining heat,. 113. Cajt-iron fcarcelv decompofcs the fo- lution of copper, 345. Canalio's method of purifying ether, 2d 722. Shows that pyroj>horus is not injured hy expofure to light, 1418. Cai'cndijh, fup]iofes heat not to he a diftindl fubftance, 69. His calcu- lation of chc t^uantity of lixed air INDEX. contained in impure vegetable fix- ed alkalies, 417. Shows tliat ni- trous acid m ay be artificially pro- duced ft-om pper and cream of tar- tar, 894. How to reflore tlie co- lour ofgoid, 1 130, Of fiiverj 1137. a: 621 Colouring mafter of Pnifllan blue in- velHga-ed by Mr Scheele, 1171. This matter flies off from the lixi- vium fangulnii when expofed to the air, 1172. This effedt fuppo- pofed to be owing to fixed air in the atmnfjihere, 1173. The co- louring matter fixed by the addi- tion of fome green vitriol to the lixivium, 1 174. Calx of iron fo- luble ill the lixivium, 1175. But not when highly dcph'ogifticated, 1 1 76. The colouring matter ta- l;en up by the air after it has been expel ed by acid-i, 1177. Effefts of diftilling the lixivium with vi- triolic acid, 1178. Attempts to procure the colouring matter by itfelf, H79. Neutral fait formed by it for difcovering iron in mine- ral waters, 1 180. Effeds of di- llilling this fait with oil of vitriol, 1181. The colouring matter u- nites with volatile alkali, 1182, How to free it perfedtly from any vitriulic taint, 11 83. To prevent its efcape through the lute during diftillation, 11 84. The colouring matter neither acid nor alkaline, 1 1 8 5 . Forms a kind of ammoni- acal fult with volatile alkali, 11 85. Diffolves magnefia alba, 11 87,. Very little terra ponderofa, 11S8, Diffolves lime, but not clay, 1189. This folution moft proper for ma- king experiments on metals, 1190, Precipitates the folutions of filver and quickfilver in nitrous acid, and of iron in fixed air, 1191. Its ef- fecls on the metallic calces, 1192. On metallic folutions, H93. Its. conftituent parts inveftigated by experiment, 1194. Is of an in- flammable nature, 1195. Suppo- fed to contain aerial acid and phlogjfton, 1 1 96. Ingredients in its compofitioii, 1199. Unfuc— cefsful attempts to 2)roduce it by volatile alkalies in a liquid ftatc,, 1200. Succefsful method with fid ammoniac, fait of tartar, and charcoal, 1201. Its volatility de- ftroyedby manganefe, 1204. Can feparate »nly mercury and filver from their folution in nitrous acid, 1205. Colours of vegetables changed by a- cids and alkalies, 173. Different colours of metallic calces, 192. Colours imparted to various kinds of ftoiies by folution of filver, 753, Colours of various kinds dcftroyed by dephlogifticated fpirit of fait, 1484. Ge/Jiparutiw heat of bodiea defined, 40. Compojii artificial, of Cramer for ma- king nitre, 728. Compounds of two metals fbmetimcs lieavier than either of the ingre- dients, 1 1 56. More fufible than , either of them fmgly, 542. Great fufibility of thofe of tin and bif- muth, 543. Fufibility of . thefe aAigmented by the addition of lead, ih. _ One fufible in the heat of boiling water, 544. Platina-unites readily with compound metals, 1343- Cnncentrated acids phlogifticated by alkalies, 409. Conceatrated ni-= traa s . 62 2 trous acid dlffolves lefs metal than vhen diluted, 489. How to ob- tain a very concentrated acetous ■ acid, 881. Violent adtion of the concentrated nitrous acid upon molybdaena, 960. Marmor me- talliciim foluble in concentrated vitriolic acid, 1063. Precipitated from it unchanged by vegetable fixed alkali, 1064. W'hy the concentrated vitriolic acid dif- ft-lvesmanganefe without addition, 1378. Condenfation of vapour produces a great quantity of heat, 43, 125. Dr Black's method of calculating it, 44. Congealed zuater, the difficulty with which it melts, a mean of pre- venting inundatioils in countries vdiere fnow and ice abounds, 88. Copper: of its precipitate^, 238. Why it is diffolved by folutions of filver, mercury, and iron, 335. Why iron and copper precipitate one aiiother, 341. Dephloyifticated folutions of iron precipitated by calces of copper, 343. Dephlogi- fticates the iron which precipitates it, 344. Its folution fcarcely de- compofed by caft iron, 345. Why it fometimes cannot precipitate filver, 348. Precij>!tations of mer- cury by it, 353. Precipitations of copper by nickel, 360. Copper throw? down a white powder from folutions of cobalt, 364. Forms a triple fait with rcgulut. of antimo- ny and marine acid, 367. Preci- pitates regubis uf arfenic from the murine acid, 370. Proportion of it diffolved by the vitriolic acid, 464. Inflammable and vitriolic air produced from its folution in this acid, 465. Quantity ©f the metal diffolved by nitrous acid, 468. }jy marine acid, 469. Forms blue vitriol with the vitrielic acid, 693. Of its folution in nitrous a- cid, 757. In the marine acid, 804. Forms a beautiful green fait with acetous acid, 872. And with cream of tartar, 894. Combina- tion of arfenical acid with it, 947. Forms a moft beautiful blue fait ivith cauftic vobitlle alkali, 1035. Does not greatly diminifh the duc- tility of gold though previoufly alloyed witl; tin, 1094. Its nature partic ularly confidered, 1146. Al- *vays f iler ihan iron, 1147. Will not Itrike fire with flint ; and there- fore of ufe to make hoops, &c. for grnpowder calks, ih. Its ducftility, te :acity, and f ecific gravity, ib. Exv'Sode.' viukn'iy by ihe contadb of n oifl, re whe. in fulion, 1148. How granulateoes fi»me change by co!:li:natio with vegeiatile acids, II- How amabjaii ated with mercury, ^152. A curious amal- gam formed by mercury aid ver- digris, li Vi- Dr Lewis's methods of amalgamation, 11 53. Forms C H E M brafs, prince's metal, &c, by the addition of calamine or zinc, 1 1 54. Crucibles in which thefe operations are performed tinged of a deep blue colour, ib. Forms bcll-metal with a mixture of tin, 1155. Lewis's obfervations on the fpeci- fic gravity of this and other me- tallic compounds, 1156. White copper made by fufion with aa e- qual part of arfenic, 1 157. A fine gold- coloured metal formed by a mixture of copper and platina, 1 341. Phenomena attending the diffolution of it in volatile alkali, 1035- Copperas. See F'itriol. Corrofive fublimate precipitated with- out any decompoli:ion by oil of vitriol, 315. May be decompofed by filver in the dry, but not in the moilf way, 356. Of its prepara- tion from quickfilver, 814, et feq. Differences of iis quality according to the different methods by which it is prepared, 816. Reafon of thefe differences, ib. Method of making itatAmfl:erdam,ib. Obfer- vations on the different methods, 817. Of its adulteration with ar- fenic, 818. Yields no butter of arfenic by fublimation with that fubftance, 945, 946. Its ufe in the preparation of butter of antimony, 821. Of its fublimation with manganefe, 1397. Cramer i artificial compoft for ma- king nitre, 728. Craivford, Dr, his explanation of Ir- vine's theory of heat, 36. Dif- fers jrreatly in his calculations from Dr Clcghorn, 48. His account of fenfible heat, 49. Differs from Dr Black, 51. His opinion con- cerning heat in the abflrad:, 54. His definition of fire, 59. His method of determining the pro- porti(jnal quantities of heat in bodies, 77. Infufficiency of his method, 78. His folution of a difficulty concerning the feeming dilappearance of heat, 86. Infuf- ficieiit, 91. Cream of tartar, how prepared, 886. Analyfcd by Mr Scheele, 887. Regenerated, 890. Crell, Dr, a miftake of his concern- ing the produdion of Glauber's fait from alum and common fait corredfed, 272. His method of cryflallizing the acid of lemons. 997. His attempts to bring vine- gar nearer to the ftate of tartar, 1004. His proofs that all vege- table acids are to be derived from one origin, 1006. Crocas metallorum, how prepared, 1265. Cronjlcdt difcovers the new femlmetal called nickel, 1306. Crucibles: of the mod j^ropcrmaterials for them, 585. Achard's method of making them from calx of pla- tina, 587. Mr Pott's diredlions for making them, 5S8. Dr Lewis's oblisrvations on their conftrudlion, 589. Porcelain probably the fitteft material for veffels of this kind, 591. Of Reaumur's porcelain as a material for crucibles, 592. Cruji produced by the fluor acid on : s T R y. the furface of water, 828. Found to be of the nature of liliceous earth, S29. Scheele's experiments to determine the nature of this earth, 830. The fame cruft pro- duced from artificial riuor, 831. Scheele's opinion that the earth is formed by the union of the acid and water, 832. Contefted by I Meffrs BouUaiiger, Monnet, &c. 833. Their opinions Ihown to be erroneous by Air Scheele, S34. Wiegleb's experimeni s oh the ori- gin of it, 839. Found to proceed froni the corrofion of the glafs- didilling vcffel, 840. How to procure the acid free from it, 842. None formed by mixing fand with a fait containing fluor acid, 844. But a great quantity by adding powdered green glafs, 845- Cryjiallme. pmtvder thrown down from folution of calx of platina by ve- getalde fixed alkab, 1325. Cryjlallixation, in chemillry : how to perform chat operation, 573. Cr) Itallization of alum impeded bj' vitriolic acid, 681. Cryjhils of one kind of fait contain none of any other, 573. Fulmi- nating cryfiaii, 1142. Cryflals of platina decompofed by the mineral, but not by the vegetable, fixed al- kali, 1322. Cullen, Dr, his experiments on the produdion of cold by evaporation, 124. Cupellation : why lead Is ufeful in that operation, 331 . Attempts to refine platina by cupellation, 1355. Cuprum ammoniacale, how prepared, 1034. Decompositions, chemical, are often double, though apparently fingle, 263. Explanation of thofe effected by acids alone, 266. De- compofitions of vitriolic falts fup- pofed to arife from compound for- ces, 276. Why decompofitions are fometimes incomj)lete, 405, 406. Deflagration, an operation in chemi- llry, how performed, 582. De>?wcritus taught chemifiry by the Egyptian priefts, 4. Said to be able to imitate the precious ftones, particularly the emerald, ib. Was probably only acquainted with the method of making green glafs, ib. Denjity of mixtures, its increafe ac- counted for, 374. How to deter- mine the accrued denfity of fpirit of nitre mixed with water, 387. Increafe of it in compound fubftan- ces, 404. DepMogiJlicated air converted into a- erialacid by charcoal, 151. Ob- jedion to the exiflence of phlogi- flon from the total combuftion of it in fomc cafes, 152. Little phlogi- flon confumed by the combuftion of iron in this kind of air, 153. Of the dephlogiflicated marine acid, 206, 790, rfjQj'. 14^4. Dephlogifticated green vitriol eann it, recipitate folu- tion of gold, 226. Quantity of mine- ral alkali taken up by dej)hlogift;i- cated nitrous acid, 432. Solution uf dephlogillicated cal« of irun cannot be cryftallizcd, 457. . phlogifticated green vitriol decooj pofed by clay, 684. DephiogiJ cated air a material for the nitrJ acid, 2d 722. How to prepare tl dephlogifticated fpirit of fait, 79( 791. Can fcarcely be coiidei.it into a liquid, 79a. Its other pn perties, ib. Acid of arfenic pn cured by its means, 919, 127 The only fblvent of platina, 131 Dephlcgifticated fpirit of nitre J compofes cam}>hor, 1424. Dephlugijii cated fpirit of fdt: exped tious method of bleaching linen i: means of it, 1484. EffeiS; of it f phlogiflic matters, 1485. Fffcrvt ces with cauftic volatile alkab, 140 Forms marine ether with fpirit wine, i486. Diflblvcs pholj : rus, ib. Method of procuring detonating fait in quantity from i 1487. Diabolus mctallortm, a name for ti: on account of its bad effects c other metals, Diaphoretic antimony, how preparei 1264. Di-^ejler, Papin's, defcribed, 567. E feds of it producible by long boi iiig, ib. Digefiion, in chemiflry, how perforni ed,s6s. Digefiivefalt : Quantity of ingredien in it, 379, 421. Prepared froi vegetable alkali and mai-ine aci( 794-, Diffolution of metals: heat produce by that operation, 190. Difiillation : liow that operation wj originally performed, 6. M Watt's experiments on the difti: lation of water in -oacuo, 45. Pre per method of performing th operation of diftillation, 574. Ph< nomena on dil'tiUation of inflani mablefubftances,5 17. Boerhaave experiments on tlie diftillation c mercury, 1230. ^ Diftilled verdigris, how preparec 872. Divellent ajfnities explained, 467. Dollfufs, Mr, his method of prepa ring butter of antimony, 821. Hi procefs for muriatic ether, 82-^ For acetous ether, 884. Du Fay fuppofcs all calcareous flone to be phofphoric, 1084. Dyeing: the vitriol formed by precl pitating copper with iron lefs pro per for this purpofe than that mad after the common method. 344, Earth: water fuppofed tobe^c'. V:'- retsble eai th fupj 1 ])y Lewis o be the fame wmIi inap-iiefia, fo8S. Mr GiT.elin's experiments bn it, 1089. irihs how div'dcd,*^!!-! 510. Vifrio- iic acid combined witli dilTerent eartbs, 633, ftfcq- Nitrous acid toirbinedwith them, 746. Soluti'in bf filver deccmpofed by calcareous earths, 755. Charaders curiouily narked by the fun's lioht on the precipitate, 756. Marine acid combined with earths, 797. Fluor acid with tliem, 8~a. Acetous Bcid, 871. Acid of tartar, 893. Of phofphoric earths, 108I. Eat ths do not attratft the colouring mat- ter of Pruflian blue, 1169. \rthen ivare : of its properties as a material for chemical veffels, 561, irthy crttfl. See Crujl. ■tjl Indies: of the method of pre- paring nitre there, 724. 2u de luce, how prej ared, 1037. fci-cejceiice attends the folutiou of metals, 188. hlcoration, a chemical operation, how performed, 571. iinbtirgh: a kind of ponderous fpar, or niarmor metallicum, found near that city, 1061. laJVic jluids extricated during the fo- lutiou of metals, 189. Gteat quantity of elaftic fluid generated "by the explofion of aurum fulmi- nans, 1123. laftidty occafioned by heat, and not phlogifton, 239. ieilive attraiiions, in chemiftry, de- fined, 177. Preci] itation of me- tals by one another cs^ing to a double one, 229. icBr'tc fuid, in winter, the faire v^'ith the heat fent down from the lun in fummer, 99. XeBrk fpari produces nitrous acid in a mixture of dephlogifticated rand phlogifticateil air, 2d 72a. Its eifedt on a mixture of alkaline and dephlogifticated air, If 5 r. hBrical heat, why fo much ftronger than tliat of furnaces, 160. Ca- pable of viti ifying platina, 1335. kBricity : proofs of the identity of its fluid with fire and light, 96. Connexion betwixt it aii(l fire or heat, 97. ExceflTive eledlricity of tlie polar regions, 98. Eledtricity, heat, light, and cold, are to be looked upon a? the eflefts of one univerfal fluid, loi. Expiofion of fulminating lilvcr probably ow- ing to it, 1 146. lements; the fuppofition of them the origin of alchemy, 23. Mr Boyle's opinion of them, 24. Are in their own nature invifible, 26. metic tartars : difierent degrees of their ftrength as commonly jirepa- rcd, 1258. Pulvis algaioth the ;inol1 proper material for their pre- paration, I2J9- v/fyreimatic acids produced by dry 'f its mifchievous effieds, 1112. Its force is not entirely directed downwards, II 13. Of the explo- fion of moifl: aurum fulminans, 1 1 14. Not occafioned by a faline principle, 1115, tii6. Nor by fixed air, 11 18. Mr Bergman's tlieory of its caufe, 1120. Occa.- . fioned by volatile alkali, iiai. Expiofion by the vapours of mer- cury, 1231. Explofions, violent, occafioned by heat fuddenly applied, 722. Fat, acid of; how procured from fuet, ad 1 015. Salts formed by combining it with alkali«s, 3d 1015. With earths, ib. With metals, 4th 1015. Fats of animals analyfed, 1428. Fermentation : milk cap able of a com- plete one, 979. Filings of iron grow hot and take fire fpontaneoufly with fulphur, 1207. Firmietis Maternus the firft writer on alchemy, 8. Filtering large quantities of water, a fcheme for, 569. Filtration : how to perform that operation in chemift;ry, j68. Fire fuppofed by Mr Boyle not to be an element per fe, 24. The contrary opinion now generally embraced, 3a. Two general the- ories of it in eflieem at prelent, 33. In what tliey differ from the theo- ry of Boyle and Newton, 34. Fire detained in bodies partly by attrac- tion and partly by the preflure of the furrounding fluid, 55. Berken- hout's divifion of I'ire into fixed and volatile, 57. Pure or volatile fire defcribed, 58. Dr Crawford's de- finition of fire, 59. Mr Kii'wan's ojiinion, 68. Mr Cavendifh's oi)inion that it is not a diftindl lubftance, 69. Seems deftitute of gravity and vis inertia, 93. Proofs of its identity with light and elec- tricity, 96. Conneia, 482. Its calces foluhle in the vitriolic and nitrous acids, 483. Kirwan's o] inion that thii r^etal cannot in any quantity be difl'olved in the nitrous acid, 484. Dr Brandt's experiment-, fliowing that it may be f> i!i clofc veflel s, 750. Lewis's obfervation on this experiment, ib. Solution (f its cakes in fpirit of fait, 799. Sublimes along with the acid, ib. 'I'he fubliraate faid to he the material iifed for the blood of St Januarius, 800. Is not alfeilcd in any way by the arfeni- Inde; ca\ acid, 941. Its nature and pi perties particularly treated 1089. Unit! s readii} with all t metals, 1090. Its colour debaf by all the metals except copper, Said to lole its malleability markably with tin, J091. 1 Lewis's account of the bad eStt of this metal up f tin, 1093. Nor 1 the additioti of the metal itftlf . fmall quantities, ib. Nor wit the addition of copper, xo^\ Malleability of gold entirely i' ftroyed by a fmail quantiiy of gulus of arfe;:ic, 1095. Surr fing tenacity of its parrs, 1096, notHable to ruft, 1097. Mr Boy! experiment to fliowits dcflrudiib lity, 109S. Of its f .lution in aqi regia, 1009. This folution of corrofive nature, iioo. May \ cryitallized, ib. Of the precip tation of the metal from it, no Separated from other metals b green vitriol, iioa, Explodi with prodigious force in forr cafes, 1 103 — 1126. See Aurum ft minans. Solution of g(ildby htp^ fulphuris, 1 127. Medical virtu< of gold entirely imaginary, ii2j Solution ;n eflential oils not pel manent, 1128. Difli.lved per.nj nently in ether, and cfyfl;a]li2ab] by its means, 1 1 29. Revived froi its folution in aqua regia by mil ing it with fpirit of wine, ib. method thus afforded of purifyin it frum other metals, ib. lloi to reftore its colour when lof 1 130. Mercury fixed by amalgi mation with gold, 1234. Wht ther it be pofiible to adulterat gold with platina, 1356. How t detedl this fraud if it fliould b pradtifed, 1357. Golden calf: its diffblution adduce as an inftance of Mcifes's ikill i chemiflry, 4. Golden julphur cf antimony, how pre pared, 1263. Golden vefj'els recommended for keep ing the fluor acid, 856. Granulation of copper, how performec II48. Gra-uity ■ the element of fire fcem to be dt fUtutc of it, 93. Of find ing the fpecific gravity of the dif ferent metallic calces, 327. Hov to find the fpecific gravity of bo dies, 371. Of the fpecific gravit; of fpirit of fait, 377. How tl find that of the ingredients in di geftive fait, 380. Of the pure ni trous acid, 386. Of its mathcma tical fpecific gravity, 388. Hov to coniti u(5l a table of the fpecifii gravities of fpirits of nitre of dif ferent ftrength, 390. How tt fiitd the fpecific gravity of puri vitriohc acid, 397. Of the ace tous acid, 400. Of ftrong vinegar 401. Of fixed air, 411. Ol tixe< vegetable alkali, 412. Mr Wad foil's account of the fpecific gra vi y of fait of tartar, 415. D; Lewis's obfervations on the fpeci fic gravity of bell-metal and othe: metallic compounds, 11 56. J Gree. ■Creen colour produced from verdigrig arid cream of tarrar, 894.. Gun-ponvder : 4|R expic.five fierce vaflly inferior to that of aurum fulmi- naiis, 1 108. Gypfum: prop >rt ion of iii;^red;eats In the natural kiml, 439. Formed of the vitriolic aci 1 aiid calcare ms eari-h, 635. Some diffei ences be- twixt the natural and artificial kinds, ib. Is fohible in fome de- gree by acids, (136. Convertib e into quicklime by a Oroni;, heat, ib. Fufcd by a very violent and fudden heat, a:^d likewife by the addition of clay or ca'carenus earth, ib. Decom]iorod by fixed and mild volutile alkalies^ ib. And by the ?.cidof arfenic, 933. Found in the concentrated vitriolic acid, 1059. HANovt. r: method of making ni- trr there, 729. HaJJi I : of the alurninous ore^s found in that country, 6-58. Heat, two general theories of, iS. JLord Bacru's , definition of it, 29. Mr Boyle's opinion, 30. Senti- mcnt> of Sir Ifaac Newton on tl e fubjeA, 31. Fire or beat general- ly allowed to be an elemeii-jt^r fe, 32. Two other theories inftitiited, 33. In what they difler from the f irmer, 34. General account of Dr Bl ic'- 's and Dr I'-vn-e's tiu^rry, 35. Dr Irviiif's theory ex plained by Dr C- awford, 36. Abfolute heat defined, 37. Great quanti'y of heat produced by the condenfa- tion of vapour, 43, 125. DifTcr- cnce of the abfolute heat of differ- ent fluids, 46. Thiniieft fluids contain the greateft quantity of it, 47. Crawford's account of fen- fible heat, 49. Capacities for c;ion of the fun, 94. How heat Vol. IV. Part II. C H E M Is produced by his rays, 95. Cnn- nccijHon between heat and eledri- city, 97. Heat in fummer becomes eleiftric fluid in winter, 99. Solu- tion of the phenomena of heat, 102. Wr Kirwaii's tht-oreni for fintlingilie poii:t of total privation of hear, ri4. Hoat the cat fe of the foftnelli of bodies a] proac hing to fluidity, II S. Abforption of heat the un.iverfal caufe of fluidity, 1 20. Heat p odncedin the burning of inflammable l;odic8 comes from the air, 157. Too much phlogiflion prevents the heat ( f burning liodies from being intei fe, 158. Wi y the folar heat and that of eledlri- city are fo intcnfe, 160. Table of the various degrees of heat, 161. Heat ]iroduced during the diflblu- tio:i of mccals, 190. Heat and not phlogifton the caufe of elafti- city, 209. Heat produced in fo- lution moft probably proceed- from the folvent liquor, 211. Argu- ment in favour of the weight of precipitates being augmented by tli.e matter of heat, 249. Experi- ment^ to dcteimiine the caufe of fomecliemicaldeconip lltionsfrom the degrees of heat ])roiiuced by various mixture^, 277. Alteration of the denfity of acii's by various degrees of heat, 423. Strong fpi- rit of nitre move expanded by heat than weak, and why, 424. Dila- tation of fpirit of fait by various degiees of heat, 417. What me- t:>.Is are caii-inablej and by what degrees of heat. 530. Violent ex- pioli .ns from the fudden applica- tion of heat, 722. Effcdsofheat on lapis pontlerofus, 969. Mercu- ry unalterable !;y being kept 15 y ?ais in a gentle heat, 1229. Hdlot [ rocures from flowers of zinc an oil capable of diflijlving gold and filvcr leaf, 1244. Hepar fulphiiris formed by a conibi- nati>..n of fixed alkalies an.l ful^;hu^, lozi. Maybe made either in tJie moift ord yway, 1021. Partly decompofed by fixed aii-, i!). En- tirely by acids, 1022. Eflcdl.=: of the inflammable vapour arifing duriiig its decompofition, ib. 1023. Its ] hi ogiilon very much difpofed to fly off, 1024. Diflblves many metals, and chaicoal, 1025. Solu- tion of gold by its means, 1127. It.s effecfis of it upon nickel. 1309. Hepatic air contain.s fuljihur. 210. Hermes Trifmegijlus, the fame with Siphoas, an Egyptian, the founder of chemifiiry, 3. Hig.r'ins, Mr, his experiments on hu- mao calcuius, 1463, et jeq. His ob- fer vations on tlie nitrous acid, 14 72 . Mefho 1 of obtaining it quite co- It. uiief, 1475. Difcovers tiie true con:po(:tion of volaf ilealkali, 1553. Horidrrgh exj eriments on fpecific gravities comparrd v ith thofe of Kirwan. 392. Diflferent refults of them accounted for, 393, 399. An 0;) obtained by Horaberg fuppofed to come from the flowers of zinc, 1243. The mi; ake difcovered by Neumann, 1243. How he difco- vered his pyrophorus, 141 5. Bell nie-hod of preparing it, 1416. See I S T R Y. Pyrophorus. Difcovers that ftia- rine acid corrodes glafs, 1482. Houfe-pdintiiig : a yellow colour for that 1 urpofe, 699. J.iNif ARIL'S, St, afublimateof ma- rine acid and gold fliown for his blood, 800. Ice: a quantity of heat loft in the melting of it, 42. Jelly, the mucilage of animal fubftan- ces, 1454. All of them reducible to this by long boiling, ih.^ Is the only true animal fubftaTO^j ib. Forms a very ftrong cement, ib. Ignited ladies all equally hot, 128. Ignition an univerfal eff"c.- nietallic ci-lces re- duced I7 it, 149. Revival of lead from nrinium by it, 324. Quan- tify of inflam.muble air produced from i on. 454. Why none is produced from the nitrous folution of iron, 400. Ciiarcoal entirely C()■ the flownefs with wliich coiigealed water melts, 88. Iron: objeclion to tlic exiftencc 'of j'hiogifton fi-om the total ccnfump- tion of dei)hl(.'g!fticated air in burn- ing it, I J 2. Little phlogifton ex- pelled from it by this means, 153. The objcdion inconciufive, 154. This me!al not reduced to a calx by burning in dephlogiflicated air, I55. Water pn duced in the re- du61ion of it by inflammable air, 156 Of it", precipitate.^ by dilTer- cnt fubftances, 239. Is not an of- ienriai IngredicHt in platina, 254. Nor regulus of nickel, 255. Nor cobalt or manganefe, 256. Why Ibhuions of iion diffolve copper, 336. Iron and zinc the otily me- tals diffolved by vitriolic acid, 337. Why copper and iron preei;>itatc one another, 341. Increafe of the attradion of calx of iron to phlo- glfton demonftrated, 342. De- phlogifllcaredfointir'ns of iron pre- cipitated by calces of copper, 343. Why a ftiiurated folution of filvcr cati fcarce be precipi'ated by iron, 346- _ Of the precij'itation of zinc and iron b\' one another, 347. Iroi: and nickel will fcarcely pre- ci] itate one another, 359. Cobalt precipitated by iron, 362. A triple fidt formed by iron, rec.ulus of an- timony,^ and marine acid, 365. Proportion of iron taken up by the vitriolic acid, 453. Why vi- triolic ai!- is produced by dlfr)lving iron in concenrrated vitriolic acid, 455- Solution of the calces of iron in vitriolic acid, 456. That of the dephloginicated calces re- fufes to cryftallize, 457. Propor- tion of iron difl'olved in ni'troua acid, 458. In the marine acid, 4('2 Calces of iron afiume a red cdourwhen precipitatedfrom their fohition in the marine acid, 463. Produces green vitriol by combi- nation with virriolic acid, 696, 697. Precipitaies fpontaneoiifly from the vitriolic acid, 69B. li'on con- tained in the refin jiroduced from the rcfi.luum of vitriolic ether, ad 722, Cannot be diffolved by concentrated, though it will by- diluted, nitrous acid, 7 = 9. Dif. fijives and produces inflammable aij- with mat ine acid, 805. Volatili- zed by this acid, So(5. Its folution nfed in medicine, 807. Combined with acetous acid, 873. With acid of tartar, 895. With the acid of arh nic, 948. Its nature and pro- ptrties particularly treated of, 1 1 57. Has great tenacity of parts, 1158. Is a combuftible fubftance, 1159 Is the only metal capable of being welded, 1 160. Cor.tradh in fi^fion, and expands again on becon-.ing cold, 1 161. Is (lifl'olved by all metals except lea{l and mer- cury, 1162. Becomes brittle by being immeifed for fome time in that fluid, 1102. Can fcarce be unite.l to zinc, ib. Has a ftrong atrradion for arfeitic, ib. Is the bafis of Prnflian blue, 116^, et feq. See PruJJiutt blue. Calx of iron fo- I ihlein lixivium fanguinis, 1171;. Neutral fair for difcovering it in mntcial waters, 1180. Precipita- te 1 bt the co;t)uring matter o£ Pruliian bhie from \t' folution by aenai acid, 1191. Nitre alkalized by It, i2o5. Its filings take fire fjx ntaneoufly with fulphur, 1207. Unites with platina, 1347, ■on liquor for printing "cloth, how prepared, 873. ■■vir.e. Dr : general account of his and Dr Black's tlieory of heat, 35. Bis theory explained by Dr Craw- ford, 36, Italy: of the firft a!un>works fet up there, 639. 4 K ^ui(4» 626 yince, gaflrlcj yields phofphoiic acid, 904. 3Ceir, Mr, his ebje6lions to the doc- trines of Mr Kirvvan, 2d 5 10. His method of prepaiing an alkaline llandard, 4rh 510. Of finding the fpccific j^ravity of differerit liquors, 5 th ^10. His objeftions to the opinions concerning the identity of the vegetable acids, 1540. Kermes mineral, how prepared, JCetley, in Shropfhire : a kind of fjja- thum ponder ofum found there, 1060. JCilfatrict-hills, near Glafgow : fpa- thum ponderofum found there, 1060. Kir-wan s opinion concerning fire, 6S. His theoi em fcir finding the point of total privation of heat, 1 14. His remarks on feme expe- riments of Dr Prieftlcy, 325. His experiments compared with thofe of Homberg, 392. Different le- fults of their experiments account- ed for, 393, 399. Kirwnn's expe- riments confirmed by one of Fon- tana, 394. Differences with Mr Bergman and Lavoifier accounted for, 435. Is of opinion that gold cannot be diffolved in nitrous acid, 484. Miflake of Morveau con- cerning a I'liperabuir.Iance of acid in alum accounted for, 642. Objec- tions to his doflrine concerning the fpecific gravity, &c. of differ- ent fubftances, 2d 5 10, et feq. To lus calculation of the quantity of phlogifton in fulphur, 6th 510. Kunckel pre})ares a fulminating cak of filver, 756. Lamp- FURNACE : Dr Lewis's de- fcribed, 6ti. Is not capable of giving a greater heat than 450° of Fahrenheit, ib. Language: fpecinien of a new chemi- cal one, 552. Itsflrange appear- ance in attempting to account for the phenomenon of fulminating iilver, 1144- Lapis ponderofus confidered as a me- tallic earth by Mr Bergman, 967. See Tungjien. Latent beat: experiments by which Dr Black was led to the difcovery of it, 41. iThis heat cannot be meafured, 73. Expanfion of wa- ter in freezing explained by the theory of latent heat, 108. Air feubbles in ice produced by part of the latent heat of the water, 110. Va))Our formed by the abforption of heat into a latent flate, 120. Lawifier denies the exillence of phlogifton, 137. His arj.niments drawn from the increafed weight of metals by calcination, 138. His theory of inflammation, 139. His - arguments fiom the redudlion of the calces of perfed metals with- out addition, 140. Difpute be- twixt him and Prieftley, 141. His differences with Kirwan accounted for, 435. Account of fome of iiis experiments on the increafed weight of metallic folutions. 525. Confequences deduced by him from thefe experiments, 526. Not v eil fuundcd, J 2 7. Account of the C H E M I conftituent parts of the nitrous acid, 1473. His nev^ nomencla- ture, 1560. Lead: quickfi'iver produced from it in certain cafes, 12, 762. Water may be made fufficiently hot to melt lead, 131. Why tiie vitrio- lic acid cannot ac^ upon it v/ith- out a bo-Hng l eat, 197. Pre- cipitates of lead, 237. Sea-falt decomp /fed in various ways by inea||p of it, 302. In what cafes folution of lead is precijutated by other metals, 309. The folution in marine acid decomi'oled by vi- triolic fa! ts, 310. Revival of lead from muiium by inflammable air, 324. Why it is ufeful in cujielh- tion, 331. Precipitation of it by nickel", ' 360. Veffeh cap;;l-le of refining the glafs of lead, 5S9. Lead vefl'els mofl: proper for the preparation of oil of vitriol, 627. Cannot he diffolved in the vitriolic acid, 702. A beautiful wliite for painting in water pre[ ared from litharge, nitrous and vitriolic acids, 703. Diffolvcs and ciyflallizes with the nit'ous acid, 761. This fait decrepitates witli great violence in the fire, 762. Becomes fluid like oil by repeated difTolutions in aquafortis, 762. Combination of lead with marine acid, 811. Plum- bum corneum. Si 2. Combined with acetous acid, 874. White lead the refult of this preparation, 875. Oblervations on the procefs for making it, 876. Sugar of lead prepared freni acetous acid and vvhite lead, S 77. Inflammable fpirit procured By diftlUing this fait, 878. Combination of lead with the acid of arfenic, 949. Great attra/'V//'o/2.'/'6™,howprepared,i4TO. Litharge prepared in the refiiMng of fiher with lead, 1214- Alrnoft always contains fome lead in a metallic Itate, ib. Bifinu;h con- vertible into a fubllance of this kind, 1250. Lithyiac acid. See Calculus, acid of. Lixivium fu-iguiuis lufes its culoui ing matter by expofure to the air, 1172. Calx of iron foluble in it. Liver If arfenic {ormcd of alkali and arfenic boiled together, 1 276. Lubbock, Dr, his theory of heat, &c, 142. Luna cornea, why it cannot be redu- ced wiihoat lofs by alkabne f-ilts, 314. May be decompofcd by mercury, 356. How j>reparcd, 80Z. It-i properties gave rife to the notion of malleable glafs, 803. How reduced, ii34' Lunar caufic, how prepared, 75 proper for hning furnaces, 605. Luting foi acid fpirits,'577. Maceration, in chemifl;ry : how to perform that operation, 598. Macjueri. theory of. Pruffian blue, Index. 1 1 67. Suppofes the fufion of calx of platina l)y the methods recom- mended tabe imperfc<51:, 1354. Magnejta combined with viuiolic acid, 690. With acid c f arfenic, 937. Diffolved by the colouring matter of Prwflian blue, 1 187. Will rot diffolve in acids after cal- cination without lieat, 442. Its preparation and properties, 514. Combined with the nitrous acid, 749- ^ , Magi/lery oj bifmuth, 766. Manganefe: how to dephiogiflicate fpirit "of fait by it for tlie decom- pofition of arfenic, 919. Combi- ned with the arfenical acid, 956. Identity of vegetable acids proved iVc/m the folution of manganefe by tlie niti ous acid with the additi'in of acid of lugar, iCii. Fi omits fo- lution by.meaiiaof viti io.ic acidand fj.irit of Wine, 1x14. K^eps the colouring matter of Pruflian blue from rifjng, 1204. Anew femi- metal afforded, 1359- Common niangauei'c treated with v'triolic acid, 136c. Is entirely diffolved || by phiogilHcated vitriolic acid, i 1361. Precipitate ai d cry llals ob- tamed from rhe f'olurion, 1362, ; Difl'oive 1 by ph'Ogiiiicated iiitruus acid, 1363. £fieliraate of iron, and fal ammo- niac named Jlores martiahs, 808, Solution i;f tin, 809. Of great ufe in dyeing, ib. Volatilizes the me- t il, and forms with it tlie fmoking liquor of Libavius, 810. With lead, 811. Forms with it plum- bum corneum, 8li. With qiiick- fiiver, 813. Forms with it corro- hve fuldiraate, 814, et fcq. See Corro/l-ve. Volatilizes zinc, 830. With regulus of antimony, 8ji. See Butter. F'orms a fine fympa- thec!c ink wit)-, regulus of cobalt, 812. Combined with infiamiv.abie fubilances, 824. Marine ether, 824. Of its attracftion for phlogi- fton, 823. Is not the fame with fluor acid, 83J . Expels the fluor acid, id 850. Purifies fait of am- ber, 911. Phenomena on dilTol- ving vitriolic falts in marine acid, 1041. On mixing them with fo- lutions of calcareous earth in ma- rine acid, 1042. Of the folution of terra ponderofa m it, 1053. Is not neceffary for the preparation of aiirum fulminans, 1117. So- lution of cobalt in marine acid, 1302. Effeds of manganefe upon it, 1364. Exiftence of phlogilton in it proved, 1381. Can fcarcely unite with butter of arfenic, 1282. Dephloglllicated marine acid the only folvent of platnia, 1319. U- fed for diftillation of fpirit of ni- tre, 737. Various methods of ma- king marine ether, 824. Method of diflilling the acid with clay, 1480. EfFe6l of it upon phb giftic matters, 1481. Glafs corroded by it, 148a. Caufe of its yellow colour, 1483. EfFed; of tlie de- phlojjifticated acid upon phlcgillic matters, I485. How to make ma- rine ether fral ileitis . Sc'e y'ciJs. Mineral -waters: Mr W' ulfe's tefb for them, 1557. See lV.,ters. Mi/fiiciel, a natural rcgtdus of arfe- nic, 1286. Mixti'res : the attradtive powers of acids determined by the various degrees of heat excited by them, 277. Increafed denfity of mix- tures accounted for, 374. Time required by mineral acids and wa- ter to acquire their utmoft denfity, 422. Phenomena refulting from mixtures of the diiferent acids, al- kalies, and neutral falts, with one a:iother, 1040, ef feq. Molybdcsna, acid of, examined, 957. How to reduce the fubftance to powder, 958, EfFedlsi of the acid of arfenic upon it, 9^9. Violent acSlion of the concentrated nitrous acid upon this fubftance, 960. A- cid of niulybdana )irocurable by fire alnne, 961. Its chemic;il pro- perties, 96*. Is capable of ujiic- ing with phlogifton, 963. Shows no figii of containing atiy metal, 964. Properties of (he acid ob- tained by nitre, 965. Molybda;- na recompofed by uniting- iis acid wi'h fulphur, 966. Differ ences be- twixt the acids of tungflen and molybdaena, 971. M. Pelletier's cxjierimcnts on this acid, 1497. iWo«/ eif's opinions concerning the fluor acid, 833. Shown to be erroneous by Mr Scheele, 834. Miftake of Mr Monnet concerning the bafis of fluor fpar, 838. Morveau's niillake concerning the preparation of Glauber's fait from alum deteded by Mr Kirwan, 642. iVfe/'« fuppofed to be well Ikilled in chemiftry, 4. Mucilage of Vegetables confidered, 145 s. Of animals the fume with jeliy or giue, 1454. Muriatic. See Marine. Naphtha, a fine kind of mineral oil defcribed, 1442. Neumann's obfervations on the pre- paration of the magiftery- of bif- muth, 766. Neutral falts compoffd of an acid and alkali, 172. One for difcovering iron in mineral vvaters,ii8o. Pla- tina m,iy be partly precipitated by fome neutral falts, 1331. Nexuton, Sir Ifaac, his fentiments con- cerning heat, 31. Nicholjons account of the theories of heat, 79. Anfwer to his argu- ment: concerning vibration as the caufe of heat, 81. His account of the capacities of bodies for con- taining heat, &c. 113. Nickel, a kind of fcmimetal, of its folution and precipitation, 242. Is precipitated by zinc, 3j8. Iron : S T R Y. and nickel will fcarcely precipi'fate one another, 359. Nickel preci- pitates copper, Icfid., and bifuiurh, 360. 7'iu ows down fome hetero- geneous matter from cobalt, 363. Of^ It', folution in vitriolic acid, 493. hi the nitroas acid, 770. Ef- feA^ of acid ofaifenic u)'on it, 955. The femimetal particularly treat- ed of, 13C6. Difc'ivered by Mr Cronftcdt, ib. Effefls of calcina- tion with a violent heat u])on it, 1307. Of fulphur and borax, 13C8, Gf hepar fulj huris, 1 309. Of mtre, 13 ic. 1 his fait feparates all the co'ialt in the femimetal, 131 1. Eft( (f.s. of fal ammoniac upon it, 131a. Of nitrous acid, 13 I 3. Of volatile alkali, 1314. Nickel can- not be obtained in a flate of pui i- ty, 1 3 15. Bergman's opinion of its compofition, 1316. Exr eri- meius to cumpofe it artificially. Nitre: quantity of acid, water, and alkali in it, di-tei mined, 391. Why it is fo much lighter than vitrio- lated tartar, 416. The ingre- dients of which it is compoled, 420. Of the preparation of nitre, 724, et feq. Difcovcred in fome places in Podolia in Poland, 725. In Spain and America, 726. Re- quifites for its formation, 727. Cramer's artificial comport for ma- king ]t, 728. How prepared in Hanover, 729. In other parts of Germany, 730. In France, 731. Dr Black's conclufioii coi'.cerning its ntiture, 732 Suppofed to be the laft effedl of putrefadion, 733. How to procure the fpirit of nitre by means of viiriolic acid, 735. Of its r( difieation, 736. Different methods of diilillinti:, 737. Its ufes, 738. Prepared from the ni- trous acid and. vegetable fixed al- kali, 740. Cubic nitre formed fnim this acid and mineral alkali, 741. Enumeration of its proper- ties and ules, 742, 743. JQanger of fwallowing large quantities of iit, ib. Is purified by throwing a little fulphur on its liirface wliile melted, 744. Calcareous nitre, 747. How alkalized by charcoal, 779. Clyffus of nitre, 780. Its acid expelled by that of phofpho- rus, 907. And by that of amber, . 910. And by the acid of arfenic, 930. Properties of the acid of molybdsena obtained by nitre, 955. Alkalized by iron, 1 206. And by the flowers of zmc, 1249. Effedls of regulus of arfenic on nitre, 1290. Effecfts of it on cobalt, 1303. On nickel, 1310. Is ca- pable of feparating all the cobalt from nickel, 13 11,. Effeds of manganefe on nitre, 1384. Of phlogilHcated manganefe upon it, 1390. M. Berthollet's new fait refembling it, 2d 793. Method of miking it in quantity, 1487. Genejated in fome cafes without, putrefaction, 1478. Nitrous acid, the moft-violcnt of any in its operations, 181. Renders the calces of metals almoft info- luble, 196. Why it precipitates a folution of tin ot, autiiaony, 400. I* more obvioufly changed than vitriolic by the addition of phlo- gifton, 203. Vitriolic falt^decom- pofed by if, 275. Contains lefa fire than the vitridic acid, 278, . On the expiilfio'.i of it by the vitrio- lic acid, 280. By a linali quantity of ddute vitriolic acid, 282. Re- ceives fire from the vitriolic during its expulfu n, 284. Of the decom- pofition of vitrialated tartar by it, 285. Vitriolated tartar cannot be decomjiol'ed by dilute nitrous acid, 287. Nitrous lalts dccompofed by marine acid, 292. Marine falts by the nitrous acid, 293. Ni- trous acid attradls filver more than fixed alkali, 301. Nitrous fok- tis^ns of mercury decompofed by vitriolic falts, 31 r. Nitrous acid diffolvesall metals, though it has lefs affinity with tJiem than the vitriolic or marine, 338, Why mercury and filver precipitate one aiiotlier from the nitrous acid, 355. Regulus of arienic precipitated by bilhuith from the nitrous acid, 369. This acid, when pure, cannot be made to exift in an aerial form, 383. To find the Ipecific gravity of pure nitrous acid, 386. Quan- tity of mineral alkali taken up by dephlogifticated nitrous acid, 432. Quantity cf ingredients in nitrous feleuite, 440. In nitrous Epfom, 444. Of pure earth of akun taken up by it, 449. Of iron diffolvci by it, 4^58. Quantity of nitrous air obtained from this f lution^ 459. Nitrous acid cannot up- on iron in fuch a dilute ftate as the vitriolic, 4(11. Of copper diffol- ved by the nitrous acid, 468. Tin difl'olved by it, 472. Ofleaddif- folved in nitrous acid, 476. Sil- ver wnh nitrous acid, 479. Calces of gold foluble by it, 483. Can- not diffolve gold according to Mr Kirwan, 484. Zinc with nitrous acid, 488. Lefs metal diffolvcd by concentrated than by diluted nitrous acid, 489. Effed-; of this acid on nickel, 494. On regulus of antimony, 3 00. On regulus of ai,fenic,303. Effcrvefcence between nitious and fulphureous fumes, 626. Experiment relating to the converfion of the vitriolic into the nitrous acid, 720. Inconclufive, 721. Of its origin, ad 722. At- traiftion for phlogifton, its diftin- guifliiiig charaiSteriftic, 734. How to e.xtra(5l it by means of the vi- triolic, 735. How to purify it- from any vitriolic taint, 736. Of diftiiiing it with different fubftan- ces containing the vitriolic acid,. 737. Of its ufes, and the method of diftiiiing it in the large way, 738. Procured of a blue colour by, means of arfenic, 739. Of its combination with alkaline falts,.. 740. Forms common nitre with the vegetable alkali, ib. Cubic nitre with the mineral, 741. Ni- trous ammoniac with volatile al- kali, 745. Of its cornbination with ear ths, 747 . Forms calcareous nitre With quicklime or chalk, 747. Is decompofed by quickhme, 748, Forms Jiald win's phofphorus with •Index. if, 749. Produces aftriiigent e«m^ pounds with earth nf alum, and jurgatlve ones with mafnefia, ib. Of its ctimhira'ion with me-, tola, 750. Is capable of diiFulving gold in fonie cafes, 750. DifTolves and cryllallize< vv.th filver, 751. Forms lunar cauflic with it, 752. PifTolvesand cryll allizes with top- per, 757. Corn des, and ad;s vio- lently upon iron, l-ut fcarcely dif- fulves it, 759. Difirlves tin in very fniall quantity, 760. Forms a- violently decrepitatirg fdt with lead, 761. Difiblvss qiiickfilver in great quan-ity, 763. Purified hy diilillati'^n from this metal, from vitriolic or marir.c acids, 764. Readily diffolves bifmiirh, 705. And zinc, 767. Corrodes regulus of antimony, 768. Dif- folves cobalt, nickel, and arfenic, 769, 770. Affords a nie.hod of difcovering cobalt in ore-, 770. Thickens expreffed oils, 77 r, Forms ether with fpirit of wine,. 773, etfeq. Of its decompofition tjy, phlogiftoii, 778. Takes fire with f'.ime effontia! oils, ib. How to procure iftarire acid by its means, 788. Dephlogilticates this acid, 790. Fluor acid procured by its means, 2d 850. Effec&s of it on fait of amber, 91a. Arfciiic decompounded by it, 918. Vio- lent aiStiiin of it on molybda:na, 950. Effedts of diffolving vitrio- lic falts in it, 1040, 1042. Forms fine cryftals with terra pondei ofa, 1066. Is nnt r.eceffary fur the preparation of aurum fulminans, III 7. EfFedls of it on arfenic mineralized by fulphur, 1280. Re- gulus of cobalt cor.i'iined with it, 1301. Its effefls on nickel, 1313. Explanation of its cffedlis on man- ganefe, 1380. Of digefting.ph'o- gifticated manganefe with pure ni- trous acid, 1393. Camphor de- compofed by it, 1424. Procurable by means of fpirit of fait, '737. • How to procure the deplilogilH- cated kind, 738, 1475. JLavoifier's account of the conftituent parts of nitrous acid, 1473. Mr Caven- difh's account, 1474. How to fet charcoal on fire by means of if, 1476. Remarkable effe6ts of it on blood, 1477. Mr Scheclc's ex- periments witli it on various liib- ftances, 1513. Volatile alkali pre- pared from nitrous acid and ci:!, »553- Some late experiments of Dr ' rieftley iiave Ihown, that though rous acid is produced fri m the de- ompofition of dephloglfticated and phlogiflicated air, by taking the elec- tric fpark in the mixture, it is iike- wife produced by the more rapid decfimpofif ion of combuftion, when inflammable air i^ made ufe of in- ftead of' the phlogifticated Vmi. In this cafe, tht)ugh } hlogifticaied air Ihould happen to exill in the mix- ture, it is not in the leall; affeded by the procefs, but remains after the combuition of the others juft as it ■was ; nay, the Dv dtor obfcrves, that by the addition of phlogifticated air, the quantif y of niu ous acid p.rodu- C H E M ced is fo far from heit!^ augmented, that it !■* much diminilhed. The a- cid in thefe protefle^ always appears to he extremely volatile, infcmuth that forns par t of it conifantlv efcapes. No liquor at all was condenfed when tlie expldfions v\'e e made in quick fuccefiinn, even though the veflei ne- ver becai-.ie ht t'er than the hand. In another procefs, the atmofph?ric air was perfectly excluded, while the ]iure'l dephiogii'ticated air was pro- duced from o: e of the materials em- ploye,!, viz. precipitate per fe. In this experiment he found, that a c^n- Cderable quantity of lixed air was pr.iduced, and that rbe water be- came acid by the abforprion of it. He co.'!ciud;!s, therefore, on the whole, that a mixture of dephlogl- fticated and inflammable air always produces an acid by combuftion ; but that, when they are in their .nafeent ftate, the ae- ial acid is generated ; when both are completely formed previous to the experiment, the ni- trous acid appears. Nitrous air : Why it does not unite with water, 204. Qiiantify of it produced by f lution of iron in ni- trous acid, 459. C^antity of phlo- gifton contained in it, 505. Objects of chemiftry, h!>w diftin- guiilted from the agent--, la. How clafled, 163. Oil of vitriol precipiiates corrofive fubliniate f oni water, and why, 3 15. Kirwan's experiments on it, 395. Why the dilution of it is necelTary in thefe experiments, 395. Quantity of iixed air in oil of tartar, 414. Why oil of vitriol and iroii produce vitri(j]ic air, 4 55, Combination of oil of vitriol witii comruon oil, 712. Oil of arfenic, how prepared, 823. Effeds of oil of vitriol on fait of am.ber, 913. Effcfts of mixing oi! of turpentine with arfenical acid, 923. Of oil of vitriol by diftlllation wich the fait comj.ofed of alkali and the co- louring matter of Prufllan blue, II91. Oil fuppofed by Honiberg to be obtained from flowers of zinc, 1243. The miftake difco- vered by Neumann, ib. Another capable of diffolving gold and fil- ver leaf by Mr Hellot, 1244, Ef- fe6ts of oil olive on manganefe, 1387. Camphor foiuhle in oil, 1 425. Quanti*y of efl"ential oil obtained frojn tuipentine, 1437. This oil very difficult of folution, 1438 Oils ey.prej[id, thickened by nitrrus acid, 771. Effential, fired i)y fpi- rit of nitre, 778. Fixed alkalies combine t With exprelTedoih, 1026. Wiih effential oils, 1027. Lead foluble in oils, 1216. Of the com- bination of phofj)hf»rus with effen- tial oi's, 141 2. Chemical proper- ties of oils treated of, 1419, et feq. Effential oils, ib. Empyreumatic oils, 1426. How to purify ran- cid oils, 1431. Opcr.itions in chcmiftry defcribed, with directions how to perform them, J j 4, et feq. Ores: Bergman's account of the a- luminous ores in Sweden, 6j,i. r S T R Y. Alum, f ilphur, and vitriol, ex- tracSled from the fa:vc,6y9. How to d fcover cobalt in ores Ly means of the nitrons acid, 770. Orpimtnt formed ef I'ulphur and ar- fenic, I 479. Oyjlerjhdls, of rheir phofphoric qua- lity, 1087. Pa pin's digefter defcribed <;67. Paracelfus, account of iiim, 14. Hi- ftory of thenriltry fiacc his time, IS- ■Pent analyfed. 1440. PelL-iio, M. hi, method of rjaify- ir.g ether, I471. His experiments on molybdaeiia, 1407. Pelican, an obfolete chemical vtllel delcribrd, 566. Pentland Hills, marmor metallicuiu found near the;n, 1060. P erf eSl metals. See Metals. Peruvian balfim, yields acid of ben- zoin, 1552. Fetroleuniy or rock oil, account of it, 1443- Phiiojophic fal ammoniac, compofed of vitriolic acid and volatile alkali, 633- Phlogijfic matters : eftedl of marine acid upon them, 1481. Phlo^ijiicatcd alkali, quantity of pre- cijiitate obtained from manganefe by if,Z57. Phlogifticated air an in- gredientin the nitrous acid,2d72i. How prej ared, 1028. Lofes its alkaline properties, 1168. Cannot precipitate a fenic excep't from ma- rine acid, 1273 Phlogifticated ni- trous acid diffolves manganefe, Phhgijlon : Of its exiftence, 27, 136 Denied by M. Lavoifier, 137. Arguments again 11; it from the increafed weight of n.etals by cal- cination, 138. From tliC reduc- tion of the calces of perfedt metals without addition, 140. The dif- putes on this fubject muft fo^n be entiiely decided, 143, Objedbions from its invifibility and fuppofed want of gravity, 144. Commonchar- coal and phlogifton the fame, 145. Dec ifive proofs of its identity from Prieftley's experiments, 146. Too much phlogifton prevents the heat of a fire from being intenfe, 158-. Soluti(,n fometimes promoted by abftradfing part of the phlogi- fton, 186. But totally prevented by taking away too much, as ex- emplified in masiganefe, 187. Hindered by too great a quantity of phlogifton, 194. Is the caufe of colour in metallic folutions, 218. Attradlion of phlogiftun fu):pofed to be the caufe of caufti- city, 219. Metals contain diffe- rent quantities of it, 258. Of the phlogifton contained in the diffe- rent metals, 317. Method of cal- culating this quantity exemplified in regulus of arfenic, 318. Table of the quantities of phlogifton in different metals, 319. Of the at- tradiion of metallic calces to phlo- gifton, 326. Whence their va- rious deg-'ees of affinity to phlogi- fton may be determined, 328. Table of their proportional affini- ties to phlogifton, 329. Quantity of It lolt by them during calcina- 629 tiop, 3?T. Thcif affinity to the deficient part of their })hlog!fton, 332. Increafe of the attraction of the calx of iron to phlogifton de- niohftrated, 342. Quantity of phlo'gifton contained m nitro;;g ^'•■j 505- 1" fi>;t^d air, 2d 505. In vitriolic acid air, jo6. In fulphur, 507. Inmari !eacidair,5C9. Attrac- tion of marine acid for plilo^ifton, 825. Union of phlogifton witha- cid cf molybda;na, 963. Is re- markaMy difpofed to ft}- off from hcpar fulphurif, 1024, Combined with fixed alkalies, I0i8. Suppo- fed to exift in the colouring matter ofPrufuan blue, 1 196, Is ftrong. ly attraiiled by manganefe, 1372, Gives a white colour to manga- nefe, 1373. Some phlogifton na- turally contained hi this fubftance, 1374. Proof of its exiftence in tho muriatic acid, 1381. Sulphur de- compofed by a fuperabundance of phlogifton, 1 40 1, Phofphoric acid, found in the refiduum of ether, 2d 722. Expels tlv.it of fluor, 2d 850. This acid particu- larly treated of, 904, et feq. Ex- pels the acids of vitriolated tartar, nitre, and fea-faU,907. Can fcarce- ly dilfolve manganefe, I367. Of phofphoric eai thg, \o%i, etfeq. Sur- priling phofphoric quality of oyfter- ftielh, 1087. By whom difcover- ed, 904. Found in vaft quanti- ties in the mineral kingdom, ib. In vegetables and the gaffric juice of anima's, ib. Phofphoric liquor, curious one from aTenic and vinegar, 2d 957,1521. Pbofphoriii of Baldwin prepared from nitrous acid and calcareous earth, . 749. Phofphorus fcintillans, of marine acid and calcareous earth, 797. Boiognian phofphorus, jo8r. How rendered luminous, 1082. Analyfed, 1083. Phofphorus of urine, 1406. Mr Margraaf's pro- cefs f)r making it, 1407. Redi- ■ fication of this phofphorus, 1408. The procefs for making it fume- times daiigerous, 1409. Liquid phofphorus, how prepared, 1410. Experiments with- phofphorus on ■ fpirit of wine, 1411. With effen- tial oils and acids, 141 2. Mr Mar- graaf 's experiments witLit on me- talf, 1413. Canton's phofphorus, 414. Homberg's phofphorus, 1415,. et feq. See Vyrophorus. M. Pelletier has now difcovered a- method of unitintr phofphoi us, with- out any decomj ofition, with all the metalsj though lie cautions againft the danger with which the procefs is attended. Gold is phofphorated by. mixing half an ounce of itsoalx with anounce of phofphoric.glafsand about a grain of powdei ed charcoal ; the whole is then put into a crucible, the- compofition covered with a little powdered charcoal, and a degree of heat fufiicient to fufe the gold ap- plied. A great many phofphoric va- pours arife, but part are detained,, and unite with the gold which, is left . at the bottom of the crucible. The . metal by this operation lofes its co- lour, becomes whitifh, breaks under ■ the hammer, and has a cryftalUne appiar, . 630 appearance. By continuing the fii C a long time the Jshofphorus wou d I'C entirely diflipated. The quantity of phofphoric glafs and chaixoal juft mentioned is fufficient to phofphorate a whole ounce of platina. Hy an hour's calcination in a crucible, the metal is converted into a bkckilh mafs refembling fiiver, weighing up- wards of an ounce, and of which the lower part confifts of cubica! cry- ftals. Notvvithflandinjir this change, however, the quantity <;f phofpho- rus united with the platina is very inconfiderahle ; for from 12 ounces of the metal, and as much phofphin- ric glafs, only ii ounces and five grains of the phofphorated metallic mafs was obtained. It was very brittle, but of confiderable hardnefs; was not attratfted by the n-agnet, and by expofure to a ftrong fire parted with the phofphorus it had been com- bined with. He obft-rves, that all the metals lofe their malleahiiity l)y combination with phofphorus, ex- cepting tin and lead ; and the refi- duum of the matter which has once ; phofphorated.a metal, wil'i ferve again for the fame purpofe. The fait formed by a combination • of the phofphoric acid with mineral alkali is found to be an ufefiil purga- tive, and as fuch is now brought into practice Meffrs Struve and Marquart are faid to have difcovered, that the ga- ftric juice of animals is comp led (.f the phofphoric acid and volatile alka- li; and Mr Sci uve has compofed a li- quid from thefe twe ingredients which ads in a fmular manner on a- limentary matters. ?ifoa/analyfed, 1447. Platina not partly compofed of iron, aj4. An excellent material for chemical velfels, 587. MrAchard's; method of making crucibles of its calx, 587. EiFe 1 ive:i, 638. Roc.-M-he formed of cream of tartar and irouoi al alkali, 891. Scheelc's method of preparing it, 89X. Roy 1 1 Society, when founded, 19. '1 his and othe.- focicties of the kind has been of great advantage ; to chemillry, ib. Muf'tng Index. Rulfing of metals explained, 541. Tin lefs liable to this dcfeca than iron or copper, ■L^Z3■ .. Saccharine Acrn, how prepared, 896 Sacchcrine ether, 90a. Is not eafily fe^- ou fire, and burns with a bUie flame, ib. Saccharum falurni. lis frtl'-.tion dc- ftroysihafof '^recn vitriol, 1044. and folution of tin, 1045. How prepared from lead, 877. An in- llammable fj irit jirocirable from it by diftillation, 878. A parti- cular kind of it obrainable by means of acid of ants, or fpirit of verdigris, 908 Sal aUmhroth, corapofed of fal am- moniac ?.nd corrofive fublin.ate. See ^.lembrotb. Sal amnioniac. See Ammenwc. Sal digejlhiii. See Dig^f i-ve Salt. Sal ditiretkus, bow prepared from acetous acid and vej;etable fixed alkali, 868. 5.;/ prunella, prepared from nitre and fulphur, 744- , Why the l itre is thus purified, ib. Sal riipellenjis . See Rochelh Salt. Sal fedati-vus. See Borax-, acid of. Sal ■volatile oleofam, a prepar.ition of volatile alkali, fpirit of wine, and cfiential oils, T036. Sali>!s m'lxfvre prefcribed in fevers, tlie fame with a folution of foluble tar- tar, 889. Salt of vinegar, formed f. om fpint of verdigris, 88l. Eleential fait of lemon's, a kind of tartar extratSled from forrel fold for it, 888. True fait of lemons cannot be converted into acid of fogar, 999. Neutral fait for difcoverinti; iron in mineral waters, I180. Watfon's account of the fpecific gravity of fait of. tartar, 4i5' Saltpetre. See 'KHre. Salts: their general properties con-- fidered, 164, et feq. are either fu- fible or volatile, ib. Soluble in water and cr^ ftallizable, ib. Their folution attended with an emiflion of air-bubbles fometimes mlRaken for an effervefcence, 165. Gene- rally foluble ill greater quantity in hot than in cold ^^ater, ib. _ Sea- falt an exception to this rule, ib. Of their mixture and fepai ation, 166. Hypothefes concerning their fo- lution, 167. Are deftru<5)-ible_ by repeated folution and exficcation, 168. Divided into acids and alka- lies, 169. See AciJ and Alkali. Neutral falts formed by the com- bination of thefe two, 17a. Per- fedl and imperfeft neutral falts de- fined, ib. Why the acids and al- kalies generally eflervefce on mix- ture, ib. Metallic folurions fome- times diflurbed by neutral falts, 222. Triple and quadruple falts, how formed, 2.7.1- Vitriolic falts dcconipofed by tlie nitrous and marine acids, &c. See Vitriolic. Nitrous falts decompofed by the marine acid, &c. Sec Nitrous. Why the metallic calces feMom decompofe the perfedl neutrals, 304. Anomalous falts formed fi om the acetaus acid and earths, 871. Of fixed alkaline falt=, See: Jlikalies. Neutral falts partly pre- cipitate platlna, 1531. C H E M Sand mixed wi;h fluor acid, ju-odu- ces no earthy cruil by diibliation, 844. S an i-pots, fills, &c. how tofet them in furnaces, 616. Ecani.t, of th^alumin ius ores found in thai co'intry, 658. * ScheeWi metliod of dephlogifiicating fpirit of fait, 791. Difcovers the fluor acid, 826. His opinion tliat the earthy cruft f )rmed by this acid proceeds from an union oi' it with water, 8.U- Df teds the er- lors i)f Boullanger and Monreton this fiibjedl, 834. Explanation of one of his experiments concerning this cruft, 846. His method of analyfing cream of tartar and ex- tradting its acid pure, 887. Dif- covers the acid of arfenic, 916. His method of analyfing mol) b- dsena, 959. Tungften, 968. His method of j rocuriiig the pure acid of milk, 976. His receipt for pre- paring the llowers of benzoin, 991. Fi)]- preparing the pulvis algaroth, 1262. Difcovers the nature of the colouring matter of Pruffian blue, II 71 Method of preparing Ro- chelle fait, 801. Sthiller's nierhod of preparing the a- cid of tartar, 838. Schif, aluminous, component parts of it, 65a. Sea-fdt, decompofed in various ways with lead, 302. Why the diftil- lation of it dees not fucceed with copperas, 7S7. It> acid not the fame wi'h that of fluor, 835. Its acid expelled by that of-pbofjiho- rus, 907. And by acid of arfenic, 931. Whitens filver, 1 137. Un- fuccefsful attempts to decompofe it, 1479. Method of diftilling its acid with clay, 1480. Effe(5is of the fpirit upon phlogiftic matters, 1481. Sebaceous acid, procured from a va- riety of fu! ftances, 1533. Has a remarkalde f-rce of attradlion, 1534. Its tffeds on tin,i535. On other fubiiancts, 1536. Secret fal ammoniuc, Glauber's. See Glauber and Amrr.oniac. Sedative fait. See Borax, acid of. Seignette's fait. See Rocbelle fali. Selenite. See Cypfuvi. Found in the refiduum of vitriolic ether, 2d 722. Why it cannot be decompofed by marine acid, 294. Quantity of ingredients in nitrous felenite, 440. In marine felenite, 441. Selenites tartareuj, conipofed of acid of tartar and caicareousearth.887, 893. The liquor from which it has been extraftcd affords an em- pyreumaric acid of tartar, loio. Semlmetal, a new one procui-ablc from tungften, 1501. Semimetdls, one of the general claffes of metallic fubftances, 547. Senfible he.it^ Cra^^ ford'a account of it, 49- Sleet-lead, how made, 1209. The advantages of milled lead over it very dubious, 1210. Silex, found in the refiduum of vi- triolic ether, 2d 722. Siliceous far//5, produces a cruft on the water into which fluor acid is di- ftilled, 829. See Cruf. Of ti e quantity of fiticeous earth tarried [ S T R Y. along with this acid, 847. Moft completely precijiitated from its foivents by vt^latile alkali, 1074. Dilf lived by boiling in fixed alka- linr ley, 1076. Silver: Why the vitriolic acid cannot adl upon it without a boiling heat, 197. Difficulty concerning its a- m-dgamation fo'ved by Mr Berg- man, 2x7. Precipitates of it, 235. Is attradled more than fixed alkali by nitrous acid, 301. Explanation of the decomi ofition of vitriolated tartar by folution of filver, 305. Of other vitriolic falts, 306. Its folution always decompofed by marine falts, 308. Experiment explaining the reduiSlion of itscal- ce^per fe, 320. Why co] per isdif- folved by folution o{ filver, 336. Why a faturated f dbtion of filver can fcarce be precipit;»ted by iron, 346. Why cop])er fometimes can- not precipitate filver, 348. Can- not precipitate coj'per from vi- triolic acid, 354. Why it preci- pitates mercury from the nitrous acid, 355. Cannot decomi ofe cor- rofive fublimate except in the dry way, 356. Of its folution in vi- triolic acid, 478. In marine acid, 480, 801. Of its combination with vitriolic acid, 691. Has a ftrong attradion for mercury in this ftate, ib. Combination with the nitrous acid, 731, Volitihzed by uniting w ith this acid, ib. Co- lours ptoduced by this folution, 7^3- Tlic folutiiai decompofed, 755. Is not adled on by tiie arfe- ni^al acid, 043. The metal par- ticularly treated of, 11 31. Its duc- tility inferior to that ef gold, ib. Its colour and dudtillty deftroyed by fulphur, 1 132. Purified by cu^ pellation with lead, 1133. Redu- ced from its combination with ma- rine acid, 1134, 1135- Has a great attirailioir for lead, 1136. Whiten- ed externally by common fait and cream of tartar, 1137. Fulmina- ting filver difcovered by Kunckel, 756. 13/ M. Berthollet, 1138. How prepared, 1139. Fulmin ;tcs by the touch of any fubftance, whether cold or hot, 1140. Dan- gerous to fulminate more than a grain at a ti-T'e, 1141. Cryftals formed by evaporating the liquor after the precipitation of the calx explode violently by a touch,! 142. Cautions to be ufed in preparing it, 1 143 . Abfurd theory by which the antiphlogiftians attempt to ac- count for this pheiu.menon, 1144. Remarks on it and others, 1 145. Eledlricity probably the caufe of this phenomenon. 1146. Silver ]irecipitated from its folution in ni- trous acid by the celouring matter of Pruflian blue, 1191 120S- Conv binatioii of it with platina, 1340. Siphoas, an Egyptian, the founder of chemiftiy, 3. Smalt produced from the calx of co- balt and flints, 129,5. Smoking liquor of Libavius prepared from corrofive fublimate and tin, 810. Scap, common, prepared by com- bining fixed alkalies with exprefl"- ed oils, 1C35, Starkey's foap, by 631 combining them with effential oils, 1017. This combination difficult to be effe(iled, ib. M. Beaume's method by leng trituration of the ingijgdients, ib. Dr Lewis's, by heating the alkali red hot, and nii.ting it with the oil in that ft ate, ib. Tliis foap naturally fub- jccl to a dccompofition by the ef- florefcence of a fait, ib. Sof/nefs, of bodies, approaching to fluidity cau'ed by heat, 118. Solar Le it, why fo much more in- tenfe than that of cjmmon fires, 160. Solfatarct, aluminous ores found there ai alyfed by Mr Bergman, 656. Solid bodies do not part with fo much heat as fluids, 212. Soh'.bility of different metals, various degrees of it, 1 85 . Their folubi- lity increafed by calcination, 545. Soluble tart.:r, prepared by com- bining cream of tartar with vege-- table fixed alkali, 889. The fame with the faline mixture prefcribed in fevers, ib. So&jtion of falts in water, p^henomena attending it, 165. Hypothefis concerning it, 167. Salts deflruc- tible by repeated folutions, 168. Phenomena attcndit;g the folution' of metah, 180. Sometimes pro- moted by abfti acSting a portion of phloj-ifton, 186. Totally prevent- ed by taking away too much, 187. Solution of metals attended with effervefcence, 188. And the ex- trication of varioui kinds of elaftic fluids, 1 89. Bergman's account of the caufe of chemical folution, 193. Solution impeded by too great a quantity of phfigifton, 194. Heat produced in folution mofl probably proceeds frtjm the folvent liquor, 211. Reafons for believing that metals are calcined by folution, 215. Why folution of gold is precipitated by folution of tin, 227. Why f ilution of cal- careous earth deconiiiofes vitrio- lated tartar, 270. Dccompofition of vitriolated tartar by folution of filver cx] lained, 30J. This folu- tion always decompofed by marine falts, 308. As alfo folution of lead, 309. Solution of lead in marine acid decompofed by vitrio- hc falt«, 310. And nitrous folu- tion of mercury, 311. Solution of copper fcarcely decomp( fed by. caft iron, 345. Why a faturated fo- lution of filver. can fcarce be pre- cipitated by iron, 346. Of the fo- lution of calces of iron in vitriolic acid, 456. That of the deplogiftl- cated calces refufes to cryftaliize, 457. Solution of tin in vitriolic Bcid yields inflammable air, 471. How to ]ierf(>rm the chemical ope- ration of fblLtion, 564. Solution . of filver in nitrous acid, 751. Shoots into a corrofive fait, ib. Its cryftals form lunar cauilic, 752. Stains hair, liones, &c. of a brown or bia-rk colour, 753. Imparts va- rious colours to ftones, 753. Cu- rious vegetations produced fi'om it, 754. Sevei-ai curi.;u=i cii cumflances attending its dccompofition, 755, 756. Solution of calces of gold in marine acid, 799. Of tin in aqua . rcgia- . CHEMISTRY. 632 regia, S09. This f^lutlon ufeful in dyeing, ib. Is decoinj cfed by faccharum faturiii, 1045. Calci- rec'ii^ foliitions by mild volatile al- Itab, ib. Solution of falts prcujioted hy vitridb'c acid, 1048. Solution of terra pondtrofi a teil of ihe vi- triolic acid, 1058. Solution of flint, 1069. Solution of alkali dif- folvc's fiHcemis earth, 1076. Solu- tion of gold IT) aeju i rp;^ia, 1099. et feq. Ill hepar fulpliuri?, 1 127. In vitriolic e'her. 11Z9. So'iition of lime by the colouririir matter of Pruffian blue, (he moft j)roper for makinjT experiments cn mctais, 1190. Effcdts of this matter oa >nietallic f I tions, 1I93. How to attain a pc fefftly faturated folu- "tion of q'iicklilver, 1 239. Of rhe fbhition of arfer.Ic in water, 1269. r.ffeds of legulus of arfenic on me- tallic folutions, 1293. :Sorrel, a kind of tartar extracTced from it fold fur effential fait of le- mons, 888. Si?e Sugar. Sfain : when alum v/a^ firft made there, 640. Nin-e, how prepared in that country, 726. S/y/tr, fionJerotis, account of Dr Wi- thering*? experiments on it, 1057. Specijic gra'jliy . Ste Gravity. Specula, riiateriaU proper for them : propofed by Mr Heilot fiom a ■mixture of gold and zinc, 1246. A mixture of lirafs and platina propofed by others, 1314. Spirit of nitre: how to determine tbe quantity of pure acid contained in it, 384. Propoi tion of it to that in fpirit of fvlt, 385. How to de- termine the accrued denfity on mixing fpirit of nii re vvirh water, 387. Experiment to determine the real quaiitit}- of acid in fpirit of nitre, 389. Mow to conftrucfl a table of fpecific gravities for fpi- rit of nitre, 390. Stron;>- fj^irit of nitre more expanded by heat than Weak, and why, 42 1. ExaA quantity of dilalation of fpirit of nitre, 425. Sohition of m.erciiiy ■with fpirit of nitre, 426. Quan- tity of bifmurh dilTolved by it, 49^2. Of cobalt, 497. Of rcguius of ai- lenic, 304. How to prepare this ipirit ay means of oil of vitriol, 735. By means of arfenic, 739. Oils fired by it, 778. Effedh of it on fait of amber, 9r2. Spirit of fait: method of findin;>: the quantity of pure acid contained in it, 376. Of finding its fpecilic gravity, 377. Proportion of -acid in fpirit of fait to that in fpirit ( f nitre, 385. Dilatation of i\ \\\t of fait by various degrees of heat, 427. EfFecfts of it i;i the way of folution in cohalt, 498. How pro- cured by me,ins of vitriolic acid, 786. By nitrous aciil, 788. By diftillation of common fait without addition, 789. DilTolves and vo- latilizes the calces of gold, 799. Arfenic deconipof^d by dephlogi- fticated fjurit of fair, 919. Spirit of ivine yields a great quantify of water by being imrned, 134. Convertible intti charcoal, 147. Ether produced by its combination with vitriolic acid, 717. Its com- bination with nitrous acid produ- Cr-s fpiritUR nitri dulcis and ether, 773, &c. Ethtr with the marii c acid, 824. With the vegetable a' id, 884. And with the Ticcha- nne acid, 902. Convcrt.'d into acetous acid by di.ueflicn with the acid of tar tar, 1013. Enables vi- triolic acid to diifnlve mangancfe, 1014. Yields a great' qnan city of ■water by diftillation v^ith caufi-ic alkali, 1015. DilTolves a fmall . proportion of arfenic, 13 70. How it may be made to diiTolve fui- phiir, 1402. DifToIves efiential oils, 1421. Spir'itus Mindcreri : how to cryfial^ize Spiritus nitri dulcit, how pi'epnred, 7 74. Analyfis of i-s reliduufi by Mr Pott, 781. Affords a^e^ous acid, IC07. Anrl acid of tartar, 1009. Spiritus -i clatiiis fuccinatus. See Fmu df luce. Stiihl: a miftake of hi.= cencernirg tlie convcrfion of marine into ni- trous acid dete6le.l, 793. Stan Jar J filver : quantity of pure me- tal contained in it, 321. Star formed on the furface of regulus of antimony, 1252. Steel, fait of, the fame with green vitri 1, 697. How prep.ared from iron, 1207. Stills, how to fet them, 610. Stune ivare Corroded by cauflic alka- lies, 59S. Strafbiirg turpentine defci ibed, 143^. Sublimation, in chemiflry, how I'tr- formed, 581. Sublimate. See Corroftve. Sugar, acid of, the fame with that offorrel, 2d 903. Acid of apples procured f;om fugar hy means of the nitrous acid, 1512. l"he acid procurable from this fub- ftance by means of the nitrous, re- fembles that of tartar, in beirg ca- pable i-.f fuperfaturatii'.g- tl.e vegt ta!>!e alkali, and forming with it an acid fait refembling crude tartar. This is found naturally cxlfting in fi.rrel and fome other plants. There is, ho-u'ever, another acid obtained from fugar along with an empyreiimatic oil by dry diftillation, which has been put ified and txamined by Mr Schrikel. Eight ounc^ s and f ur fcruples of liquid vvere obtained in this manner from t6 of fine fugar. About fix drachms of water came over firft ; after which the acid paf- fed in white vapoui s, which conden- fed in unAuous ftrias on the fides of the receiver. It had a pungent and agreeable f)i:ell, and tafled empyreu- matic. By repeated diftiliations from pure clay, its fmell became mild, arid it acquired an, appareiit incrcafe of acidity. With vegetable alkali, it formed a f^lt tufting like that of Syl- vius, and ftioo-ing into needle- like cryftals,- filuble with difticulty in cold water, but not at a 1 in fj irit of wine. It did not deliquate in the air ; but decrejvtated in the fire, and did not melt on be t coals. With the mineral alkali yellow cryftals were iormed •■efenibling Rochelle fait in tafte, eafilyfolubie in water, and not deliquating in the air. Volatile al- kali gave a fiiarp falinc liquor, which couJd not be crj ftaliized, but left a 3 faline raafj on evaporation ; and afimi- lar faline mafs was produced by uni- ting it with calcareous earth. Mag- uefia aiid earth of alum formed gum- my comp. und". Wh,°!i concentrated, it diffolved the calx of gold, and even gold-leaf; but had r;o effed on fil- ver, mercury, or their calces With minium it gave a )'ellow folution, whicii fliot into oblong white cryftais of an aflringent tafle. A blood-red folution, whicii ll'ioc into green cry- ftals, was obtained from iron. Co})per was diir Ived into a green liquid, which did not cryfta lize. Regulus of antimony was alfo dilfolved, and the folution was of a grecnifli col(;ur. Zinc was partly iliffolved into a green liquor, and partly corroded. The precij)itates were remarkable. The cryi;tals of iron gave a green precipitate with alkalies, a black or dark blue one with Pruffian alkali, and a white one with marine acid. Solution of regulus let fall a yellow precipitate with fixed alkali ; with volatile alkali, a powder foluble aijahi i:i the precipitant ; vitriolic and ma- rine acids, and an infufion of galls, threvii (?o-vvn a white powder, but no preciiiitate eniue 1 on adding nitrous acid. Sobatlon of zinc gave a white precipitate^with infufion of galls, al- kalies of ail kinds whether fixed, vo- latile, or phlogifticated, as well as by the vitriolic acid. Tin was partially diffoiviid, and the fo'-ition precipita- ted by alkalies, and an infufion of galls, but not by any of the mineral acids, L.ead was precipitated <y 'boil- ing with fomc of the finer kinds of clay, 886. Scheele's analyfis of cream of tartar, and method of procuring the pure acid, 887. So- luble tartar formed by uniting the vegetable fixed alkali with cream . f tartar, 889. Cream of tartar, liow regenerated, 890. Seignette's or Rochelle fait formed by com- bi;;i:;g the mineral alkali with cream of ta tar, 891. Sait formed by the union of cream of tartar with volatile ali:ali, 892. Combi- nation of the acid of tartar with earths, 893. With metallic fub- ftances. {594. Foi ms a fine green colour with copper, 894. Chaly- beated tartar with iro . 89^. Whether this acid or that of fugar is the bafis of vegetable acids, 995. Piodudt of acid of tartar by dry diftillation, 1000. Requifite.* for bringing vinegar nearer the ftate of tartar, 1002.- Weftrumb's nn- fuccefsful attempt for this purpofe, 1003. Dr Crell's opinion of the ■Index. poffibility of the tranfmvitat'ion, 1004. Method recommended ly him for artemptintf the experi- ment, 1005. Ari^urnent in favour «)f tlie identity of vejjetinile aci^is frdm tl'e prnduifliqii of an empy- JXiimaric nciri if tartar from the liquor in wliicii tartareous felenite is boiled, 1010. From tlie fo'.u- tion uf ina!i^a!iefe in a mixture of yitrioiicand tartareous acids, 1012. Silver whitened by cream of tar- tar and common fait, 1137. Of the preparation of emetic tirtar, X 1257, I25S, I't feq. See Emetic. Manganefe f>luhlein acid of car- tar, 1368. Explanation of its ac- ti< 11 upi n mar4;anefc, 13S2. Schil- ler's metl^od of procuring- its acid, £88. Tliough the ac>d of tartar has been ■commonly fuppofed a j!;odu61: of ti,e ■vinous fermentation yet lare exj^e- riments have fliowri tliat tlii-, i,% i;ot the cafe. It has been fmrn \ not on!y in the juice of the grape, hut in that ■of tamarinds, rlie be rie-- of the rbus ioriiir/a, ai:d the leave- i-f the riimcx ■acdofn. In tl'.efe it is ),enerai!y com- bined vvith the vi--get:d-i!e fixed a'Jca- !i, or wi'h calcnri cus e^'.rth. H^rm.b- fladt has found it combined with cal- careous earth in the j dee of he 101 ts of the triticum re/>ens . the L'vntoJoii-tiix- ar.icum, and CfAita'bark. By the afiift- ance of nitrons acid he obtained it alfo from the juice of grapes, mul- 1-erries, aiijdes. pears, oranii;es, ftraw- fierries, and plums; alfo from ]\ Tie)', fuoar, gum araliic, manna, fpirit of wine, b ech-wood, anil tlie root of black liellebore. In th: fe cafes, where the nitr^insacid is made , life of, however, ir may juftly be fiippofed that the acid < f tai tar is j)artly at Teall iTi -duccd from i'. hi Schecle's procefs for prijcuring the pure acid of tartar by mr: n- of cal- careous earth, it is a Ivifab'e 10 J:iake ufe of qnicklimr ratl^er fl an -clialk, as by this double the quajitity '^f tanar will he (!econ-])ofed. An hundred parts iiata fart;'.ri, the liquor beg-Ui to change t! e f. rup of violets v^recn i:: two :ronth-, and in four the de- compoiition leemed to be romjijete. At the end of a year he fil ered and evaporated the liquor U> drynels, by which procefs he olitained 432 grains of fixed alr.ali. 'J he fame quantity of terra fobata tartari rocefs. It is alfo worth notice, that in conibinitig acid of.ta' tar with lixed alkalies the lalt fuperfaturatcd with acid or cream of tartar is alwny-^ form.ed in frefe-enre to the other c-^'ltAfjluhU tarlar. Thus, if tQ a fann-ated folution of alkali w ith cream of tartar we add another of pure tartai eou s acid^ a w J lite fpongy mr.tter will be precij.itaie J to the b itlom ; winch, on examination, is found to be a true tartar. Any other acid added to the folution of tartari- fed tartar will in like manner pro- duce a prccipitatiiou of tartar, by en- ^ngitig a part of the iilkali with which rt was rnmbined ; arid if the acid of tariar be added tri a folution of any neutral fair containing the vegetable fixed alkali, as vitriola ed tai:ar, fait of .Sylvius, and nitre, a fimilar i>rec:pitati<3n of tartar will cnfue. iJlence the acid of tartar may be employed as a teO to difcover the prefeiice of the ve-etable fixed alka- li, aud to dift.ing.uini it ft oni the nn- I S T R Y. neral, wliirh has not that tffef water into vapour, 121. Heat ex- pelled in great quantit)' by its con- denfation, 125. Vegetable colours changed by acids and alkalies, 173, Of vegetable earths, 515, 1089. Suppnfed by Dr Lewis to be the fame with in:\gnefia, 1089. Dr Gmelin's exj'cjiir.ep.ts, 634 CHEMISTRY. experiments, !b. Vegetable ammo- niac, 870. Vegetable ether, 884. Vegetable acids produce a remark- able change on copper, 1151. Ve- getable fubftauces in general confi- (lered, 1451. folloivlng h a lijl of the Vegetables from ivbich the indujlry of tik vioilern chemijis has procured diff'cr^nt acids, •zvith tie names of the difcuverers. 1. Agave Ameruanet. 'J he juice exfuding fi on the calyx of this plant yields acid of tartar and apples. Mr Hoffman of IV eimar. 2. Aloes. Acid of fugar £Mid ap- ples. Mr Schede. 3. /ipples. A peculiar acid called by the name cf the fruit. By ni- trous acid tliat of tartar is .prccu- red. Mr ?,c.heeU and Mr Hermlf.idt. 4. liarberry. Ac:d i f apj.lc- , and of tartar. By trea'rnent with ni- trous acid it yield*- acid of fugar. jSehcele and Hern:ljiuJt. — HofTnian de- nies that it contains any native acid of tLirtar. By treating it with fpirit of wine and raangancfe he obtained an ether. 5. Bilberry {J^.ieriiiim/i tKyrtillus). .Eqi;al ;'arts of the acids of cii rons and app'cs. Sci'u'ele. 6. Bramble {Ri!b::s chamamoriis') . The fame with theforegoin.^. Scheele. 1 C. inpLor. A peculiar kind of Gryllallizahle acid. M. Kofeyarten. 3. CLerrics. Equal parts cf acids of citrons and a; pies. Saccharine acid by treatment with I'pirit of nitre. ' Scheelc, Herr>7hfiadt, ai;d We- fnnnb.' — Hcrmbftadt fays that he found acid of tartar alfo. 9. Citrons and lemons. A particular kind of cryllallizable acid. Scheele. 10. Coffee. The infufion evapo- rated and treated with fpiiit of nitre. Acids of fugar and apples. Scheele. 11. Corls. A yellow acid by re- peated abftraiftions of fpirit of nitre. With fome of the alkalie's and earths this acid forms ciyftallizable falts which do not deliquate, though others do. That with fixed vegetable alka- li forms needle-like cryfials, foluble in water, virrioKc, nitrous, or ma- rine acids, but not in vinegar or fpi- rit of v/ine. liike the facchatine a- cid it has a Ikong affinity to calca- reous earth, which it feparates from lime-water, and forms a grcyifli fa- hne powJer, foluble in marine acid, but not in water, nor even in its t,wn acid. It exhibits fome appear- ances with metals, wiiich deferve far- ther examination. BrugnatelH. I a. Craiibsriy. {Vaccinitim oxy- (occos). Acid of citrons. Scheele. 13. Currants, red a^id ivhite. Acids (i citrov.s and apples. Wijlrumb. Hernibftadtfays that they contain a- culof tartar. 14. Elderberries. Acii of apples. Seheele. 15. Galls. A peculiar k-.nd cf a- cid. Scheele ~-^'r Keir obferves, that from other aflrin.'ci.t matters, efpe- cially thoff ufed i'.. dyeing, _it is pro- bable that fimi'- r c.cids might be ob- tained. Mr !\T'-.'-vcau has obtained from galls a lei:'' which he fuppofes ro b« their uciiliubic bcife; and which, along with pure air, forms the acid of galls. When purified, this acid is faid t» make a fine and durable ink. 16. Geranium acidum. Small acid cryftals. Cartheufer. Said by Hermb- fladt to be the acid of fugar. 17. Goofi-berries. Acid of ap)>les. -HermbHadt fays that they contain the acid of t; rtar alio. 18. Grafes. Their juiceweil known to contain the acid < f tartar par- tially combined with fixed alkali. 19. Grafs-roots. Saline cryftals from the extracft of the juice after three months {landing. Thcfe were foluble in water, and >iave an earthy precipitate on mixture with fixed al- kali. 0\¥ abtlradling the nitrous a- cid from them, and adding a folu- tion of calcareous earth in vine^iar, a precipitate fell, which was found to con lilt of acid of tartar faturated with lime. Hermlfladt. ao. Gum Arabic. Acid of fugar and a] pies. Scheele. 21. Gum tragacantb. Aclds of fu- gar of milk, apples, and fugar. 22. Haw {Cr.ittegus aria). Equal parts of acids of citrons and apples. ^ 23. Honey. An acid liquor by di- flillatiiin; and with fpirit of nitre, the acid of fugar. The diftilled acid has been faid to diffolve gold. 24. Lemons. An acid the fame with that of citrous. 25. Leoiitodon taraxacum. Acid of tartar by treatment with fpirit of nitre. 26. Manna. Acid of fugar by treatment with fpirit of nitre. 27. Mulberries. Acid of tartar. Hermbfladt. A cryflallizable acid fait by evaporating the juice. Angelus Sala. 28. Oil of olives. A fait which fubhmed and cryftallized, by re- peated and copious abftradlions of the nitrous acid. IVifrumb. 29. Peruvian bark. Acid of aj'ples and fugar, by treating the extradt with nitrous acid. Scheele. 30. Prunus fpinofa et dtmejlica, A- cid of apples. Scleele. 31. Prunus padus. Acid of ci- trons. Scheele. 32. Peppy. Acids of fugar and apples, by treating the juice with nitrous acid. Scheele. 33. Rajpberries. Acids of apples and citrons. Scheele. Acid of tar- tar by faturating the juice with chalk, and then feparating the earthy bafis by means of vitriolic acid. Hermbfladt. 34. Rh.ipontic. Acid of tartar ^ly cryflallizing the juice ; of fugar by treating it whh nitrous acid. Bind- heim. 35. Rhubarb. Acids of fugar and apples by treating the infufion with nhroiis acid. If a pound of Indian rhubarb be infufed in hot water, a powder fubfides, which by wafhmg becomes white, weighing then about nine drachms, and is found to con- fift of calcareous earth united with the acid of f igar. SJjeele, 36. Ribes cynofhati. Acid of citrons or lemons. Scheele. 37. Salep. Acids of fugar and apples by treatment with nitrous a- cld. Scheele. 38. Service (Sorbus aucuparia). A- cid of apples. Scheele. 39 Solanum dulcamira. Acid of citrons. Scheele. 40. Sorrel (Rumex acetofa). Cryfials of tartar by evaporating and cryflal- lizing the juice; and pure acid of tar- tar byf iturathig the acid with chalk, and then expelli:-.g it by means of the vitriolic. Hermlf.idt. Other che- mills, however, have certainly found it to contain the acid of fugar partly neutralized with alkaii, and which is capable of being cryflallized. I'his is jrer.erally known under the name oi' fait of uooJ-forrel, and is manufac- tured in confiderable quantities in Tliuringia, Suabia, Switzerland, and the riartz. It is prepared from this )>lant as Avell as the oxalis acettfella. The plants are bruifed in flone or wooden mortars; the juice is fquee- zcd through Unen; and when cleared by fettling, is to be boiled to a pro- per confiflencc, and clarified with the whites of eggs, or with blood. It is to be fliraiiifd whilft hot, and then kept in a cold cellar. In a few weeks cryftals will be formed, from which the remaining liquor muft be poured olF, and by further evapora- tion will yield more fait. Savary obtained only two oiuices and a half of fait from 25 pounds of the juice. 41. StrazL'berries. Equal jiarts of the acids of apples and citrons. Scheele. 42. Sugar. See the article. 43. Sumach [Rhus coriaria). Cry- fials of tartar. Profcflor Tromfdorf and Son. 44. Tamarinds. Acid of tartar, tartar itfelf,wi=h a mucilaginous and faccharine matter. Weflrumb. 45. Vaccihium vitis idwa. Acid of citrons. Scheele. 46. Wood and bark of the birch tree. From 55 ounces of the wood we're obtained 1 7 Ounces of retflificd acid, which when freed from an araber- coloured oil was to the fpecific gra- vity of water as 49 48, and of fuch flrcngth that one ounce of it re- quired 23 of lime-water f ir its fatu- ration. Chemijis of Dijon.— 'By allow- ing the acid diftlUed from the bark to remain at reft for three months, much of its oil was feparaied; by fatura- tion with fixed alkali a dark- coloured neutral fait was obtained, which was purified by fufion and fubfequent fil- tration and evaporation. On fub- jedling the ptirified fait to diltiUa- tion, an acid arofe, wliich had no longer an emj-.yreumatic fmell, but rather a flavour of garlic. Coettling. Vegetations, curious, produced from folution of filver, 754. Venice turpentine. See Turpentine. Verdigris, how prepared, 87a. Di- flilled, ib. Verdigris diftiiled, beft method of making It, 872. Vsrditer, a preparation of copper, 758. Method of making blue verditer generally unluiown, ib. Vermilion made by fubiiming fulphiir and mercury together, 1404. Dif- ficulty in adjufling the proportions of the ingredients, ib. May be made without fubliraation from Index-. quickfilver and the volatile tinc- tni e of fulphur, ib. Or with the folution of^fulpimr by fixed alkali or quicklime, ib. Is darker or lighter accordmg to the quantity of fulphur, ib. Veridam, Lord, ftudies and revives tbe fcience of chemiftry, 16. flis opinions concerning heat, 29. Veffels, cb.emical : of the proper ones to be ufed, 357, et fq. Or Black's ojunion, i!). Of glafs, 558. Of mctil, 560. See Chemical, GLifs, Metal, Earthen ivare, and Porce- lain. Vibr^ii.en: Nicholfon's account of the advantages attending the fuppofi- tion that heat is occafi. ned by it, 80. Anfwcredj 81. Vineg.ir: fpe ilic gravity of it when j flrongiv conceiitr.ited, lOi. Why : It may be reduced into air without ■ addition, 208. Procurable from; the reiiduum of vitriolic ether, 2d 722. Lewi-'s experiments on the folubility of tin in this acid, 880. Whey convertible into vii.egar.i 979. Requifites for brhiging it i\ nearer the Hate of tartar, 1002. Weftrumb's attempts for thi» pur- pofe, 1003. Dr Crell's opinion 1, of the poflibility of the tranfmu- ji tation, 1004. Method recom- il mended by him for attempting tha ]' experiment, 1005. Suppofed to be i an antidore againfb arfcnic, 1520. | Difference between radical vir.egar r and comuKUi acetous acll, is'^'i- Vis inertia: fire feems to be deftitutc of it, 93. Vitriol: why folution of gold is pre- cipitated by the green kind, 225. But not by this fait when dephlq- gifticatcd, 226. That procured by precipitation of copper with iron lefs fit for dyeing than the common, 344. Blue vitriol can- v not be formed by boiling aluml and copi er filings, 349. Propor- tion of ingredients in blue vitriol, 467. How to extradl green vi- triol from pyrites, and to diftil the acid from it, 620, et feq. Extrac- ted from the fame ore with ful- phur and alum, 659. Alum is generally contaminated by dephlo- giilicated vitriol, 684. PerfeA green vitriol cannot be deftroyed by clay, 686. How to abftiacl the phlogifton from it, 687. How to prepare blue vitriol, 693. Parts with its acid with more difTicuity than the green kind, 694- 'ts ufes, 69J. White vitriol, how prepared, 708. Why the diftiUa- tion of fea-falt with copperas does not fucceed, 787. Green vitricd decompefed by faccharuni faturni,, 1044. Fixe'; the colouring m.^ttep of Pruifian blue, if74- How af- feded by dephiogifticated marine gas, 1485. Vitriol, acid of. See Vitriolic acid. Vitriolic acid: why It cannot a6l on lead, filver, &c. without a boil- ing heat, 197. Cannot be redu- ced into an aerial form but by ^ combination with phlogifton, 202.I On the expulfion of the nitrous acid by the vitriolic diluted, 280. Uy tlic fame in a ccncentraceu ftate. CHEMISTRY. Index. ftate, a8i. With a final! quan- tify of vitriolic acid diluted, 282. On the expulfion of the ma« rine acid by the concentrated vi- triolic, 283. Decompofitlt'n of vitriolic ammoniac by.marine acid never complete, 29I. Why tlie vitriolic acid refumes on evapora- tion the bafes it had left, 285. Deconipofition of vlniolic animo- niac by folutionof filver ex-dained, 306. Of CQrrofive mercury by concentrated vitriolic acid, 315. Can diffctlve no other metals than iron and zinc, 337. Kirwan's ex- periments on the fpecific gravity of oil of vitriol, 385. Why it is necelTary to dilute the acid in thefe experiments, 396. To find " it^ fpecific gravity, 397. Quan- tity of acid neceffary to faturace pure mineral alkali, 430. Why vitriolic air is produced by diflbl- ving iron in concentrated vitriolic acid, 45 5. Solution of the calces «f iron in vitriolic acid, 456. It adts on iron in a much more di- lute ftate than the nitrous, 461. Proportion of cojiper diffolvcd by vitriolic acid, 464. Vitriolic air ©btained from this folution, 4^)^. Why this metal cannot be a61ed upon by diluted vitriolic acid, 466. AS- With argillaceous earth, 637. With magnelia, 690. With metals, 691. With Inflammable fubftances, 712. Bergman's ex- periments to (how that an cxcefs of this acid impedes tlie cryftalli- aation of alum, 681. Procured from the refidnum of vitriolic ether, ad 722. Of its tranfmuta- tion into the nitrous acid, 720. How to cxtrad the nitrous acid by its means, 734. Whether the marine acid be the fame with it, 783. Experiment feenjing to prove the tranfmutatlon, 784. Expelled by acid of fugar, 898. EfF<^(5ts of it on fait of amber, 913. Dilfolvcs manganefe in conjunc- tion with the acid of tartar, 1012. Or with fpirit of wine, 1014. Expelled hy the nitrous and ma- rine acids, 1041. Promotes the foiubility of falts, 1048. Terra ponderofa ufually found united with the vitriolic acid, 1049. Unites with this fuhftance more readily than witli alkalies, I055. Its prefence readily difcovered by terra j)onderofa, 1058. The oil of vitriol ufually fold . contains gypfum, 1059. Effe(Sls of it on arfenic, 1271. Converts the re- gulus into white arfenic, 1292. On regulus of cobalt, 1300. Vitriolated tartar : its decomprfition by calcareous earth explaiised, 270. On its deconipofition by nitrous acid, 28?. Canaot be decompo- fed by diluted nitrous acid, 287. Decompofed by marine acid, 288. Requifite-i for the fuccefs of this experiment, 289. Cannot be de- compofed in a ftate of folution by this acid, 290. Explanation of its deconipofition by folution of fil- ver, 305. Why it is fo much heavier than nitre, 416. Of the quantity of ingredients in it, 419. How prepared, 628, 629. Its ufes, 631. Decompofed and ful- phur procured from it hy calcina- tion with charcoal, 716. Its acid expelled by that of phofphorus, 907. And by the arfenicai acid, 929. Volatile alkali lefs ftrongly attradled than metallic earihs by acids,303. May be ufed to remove the exccfs of acid in aluminous ley, 680. Fiirms Glauber's fal ammoniac with vitriolic acid, 633. Nitrous aramoniac with the nitrous, 745. Common fal ammoniac with the marine, 795. Vegetable ammo- niac with the acetous, 870. A fait forming into elegant cryftals with the acid of tartar, 892. Its combination with fluor acid, 851. Glafs corroded by this fair, 854. A great quantity of k fatu- rated by acid of fugar, 900. Forms microcofmic fait with the phofphoric acid, 905. Combined with acid of arfenic, 928. In its mild ftate decompofes calcareous folutions, 1046. Precipitates fili- ceous eart-h completely, 1074. Its preparation particularly treated of, io^p,etfeq. Obtained from various fubftances, ib. Proper way of diftil- liiigit, 1031. How purified, 103a. Volatile fal ammoniac, how prepa- pared, 1033. Volatile alkali com- bined with metaJs, 1034. With cffential oils and fjiirit of wine, 1036,1037. With fulphur, 1038. Volatile tiniSlure of fulphur, 1038. Ttsufe in the preparation of aurum fulminans but lately known, 1 106. The caufe of its explofion, iiai. Unites with the colouring matter of Pruffian blue, 1182. Obtained by diftillation from Pruffian bhie, 1197. May be united with phlo- gifton and fixed alkali, fo as ta fu- fiaia a great degree of heat, 1202. Effei5ls of it on nickel, 1314. On folution of plarina, 1330. Why the volatile fulphureous acid dif- folves manganefe, 1579. Volatile alkali deftroyed by manganefe at- tradtiiig its phlogifton, 1394. Volcanic countries only afford ores containing alum ready made, 63 5. Ungiientum citrinuvi, how prepared, 772. Urine, how the microcofmic fait is procured from it, 905. Always contains a calculous matter, 1457. Why frefti urine reddens lacmus, 1458. Different falts contained in it, 1459. Affords the acid of ben- zoin, 1532. Ward's drop : Nitrous ammoniac the principal ingredient in it, 746. Water : Its flownefs in melting when congealed, a preventative of in- undations, 88. Prodigious force exerted by it in freezing, 106. Remains fometimes fluid though cooled below 32 degrees, 117. Dr Black's experiments on the converfion of water into fteam, 121. Its boiling point in vacuo determined by Mr Boyle, 122. And by Mr Robiiifon of Glafgow, 123. May be made fufficicntly hot to melt lead, 131. A great quanti- ty of water yielded by burning fpirit of wine, 134. Produced fjom the deflagration of dephlo- gifticated and inflammable air, 135. In the redudlion of iron by inflammable air, 156. Why it does not unite with nitrous air, 204. Cannot diffolve metallic falts without an excefs of acid, 297. Quantity of it in digeftive fait, 379 Innitre,39l. In vitriolated tartar, 398. In fpirit of nitre, 426. How far it is an objedt of chemiftry, 549. Scheme for fil- tering large quantities of it, 569. Earthy cruft formed on it by fluor acid, 833. See Cruji. Neutral fait for difcovering iron in mineral waters, 11 So. Mercury fuppofcd convertible into it, 1235. The miftake difcovered by Lewis, 1 236 . Waters, mineral, Mr WouJfe's teft for them, IJ57. Wattes experiments on the diftilla- tion of water in'ii,!-cuo, 45. On the evaporation of fluids in vacuo, 126. His teft for udids and alka- lies, 1549. et feq. WeJ^eivoodh improvement of the ^^35 thermometer, 1 04. His ftonc-wafe an improvement in chemical vef- fels, 597- Weight of mctah increafed by calci- nation, ^23, et feq. Wenzel's experiments on fluor acid, 850. Method of preparing cry- ftals of verdigris, 872. W i-j1rumh\ analy fis of the refiduum of vitriolic ether, 2d 721. His at- tempt to reduce vinegar nearer t» the ftate of tartar, 1003. Whey : chemical properties of it, 9 70, Convertible into vinegar, 979. White : a beautiful white colour from lead, 703. White drop of Ward, 746. White copper, how pre- pared, 1157. Wiegleb'i experiments on fluor acid, 839. Account of the diftidurion of nitrous acid by clay, &c. 737, His new chemical nomenclature, Wil/on's experiments on phofphori, 1086. Winch's method of purifying ether, 2d 722. Wine8,how purified, 886. Withering'^ experiments on terra ponderofa, 1050. Wolfram. See 'Tungjten. Wood, prefervatives for, 52r,''7oo, IVoodivarf^ receipt for making Pruf - fian blue, 1 164. Woulfe% method of procuring nitrous ether in large quantity, 776. Teft: for mineral waters, 1557. Yellow colour for houfe-painting, 699. Yorh, account of the aluminous ore found near that place, 660. Zaffre, a c:dx of cobalt, defcribed, 1294. Zinc and iron, the only metals dif- folved by vitriolic acid, 537. Of their precipitation by one another, 347. Precipitates nickel, 3^8, Cannot precipitate cobalt, 361. Forms white vitriol with the vi- triolic acid, 707. Combined with the nitrous acid, 767. With the marine acid, 820. Volatilized by it, ib. With acid of arfenic, 951. Cannot eafily he combined with iron, 1 162. Its combination with copper, 1154. Tha metal parti- cularly treated of, 1240. Defla- grates violently in a ftrong heat, ib. Sublimes into flov/ers, 1141. Dr Lewis's method of reducing them, 1242. Oil fuppofed to be obtained from them by Homberg, 1243. The nilftake difcovered by- Neumann, ib. Another oil by Mr Hellot, capable of diiTolving gold and filver leaf, 1244. Combina- tion of zinc with other metals, 1245. Its combination with gold a pn^per material for fpecula, 1 246, Its deflagration with other metals, 1247. Cannot be uni'cd with fulphur, 1248. Nitre alica- lyfed by its iloweis, 1249. Unitts readily with platiua, 1342. 4La CHEMNITZ, « ChetnpJtz II Clienopo- dium. CHE. [ 636 ] C II E CHEMNITZ (Martin), a famous Lutheran divine, leaves become hard and unfit for the table; but that Chepelib- the difciple of Melandhon, was born at Britzen in nourilhment is then found in its root, which ferves as a Brandenburg, in 1522. He was employed in feveral rcfource in times of famine and fcarclty. ' When the ^'^^j important negociations by the princes of the fame belvidere has attained to its natural fize, the Chinefe communion ; and died in 1589. His principal work feparate its_ prindpal ftalk froin the rei^, and put it is the Examen of the Council of Trent, in Latin. into a lye of afhes, which cleans and foftens it, and CHEMOSH. See C H AMos. frees it from all impurities of the bark. After this CHEMOSIS, a difeafe of the eyes, proceeding from bath, it is expofed to the fun; and, when dry, it is an inflammation ; wherein the white of the eye fwells baked and feafoned. With regard to the root, which above the black, and overtops it to fucli a degree, has fomet-hing of a violet- colour, they ftrip off the llcia that there appears a fort of gap between them. Others by filaments, which may be boiled and eaten : but define it to be an elevation of the membrane which what is particularly fought after, is the root itfelf ; of furrounds the eye, and is called the ivhite ; being an which, when reduced to powder, they colled only affeftion of the eye, hke white-fleih. what remains in the bottom of the veflel„ and form it CI-IENOPODIUM, GoosE-FooT, or IVlld Oraeh : into finall loa\'es, that are baked by being held over the fteam of boiling water. People of a delicate talle will fcarcely be tempted to admit this difli at their tables ; but is it not ufeful to point out to the poor peafants, that, in cafes of neceffity, they may always have recourfe, without danger, to this ruilic food ? In. fuch cafes, they will be indebted to the Chinefe for having made the firft trial, which, fortlie mo-il part, is- dangerous. The Chinefe Herbal cites the example of four mountaineers, who having lived on nothing but the leaves, roots, and ftallcs, of the belvidere. With which their country abounded, had neverthelefs en- A genus of the digynia order, belonging to the pen tandria clafs of plants ; and in the natural method ranking under the \ 2ti\ or(^cy, Jloloracda'. The calyx is pentaphyllous and pentagonal ; no corolla ; one feed lenticular, fuperior. There are 18 fpecies, 13 of which are natives of Britain. The moll remarkable are the follov»'ing; i. The bonus henricus, or common En- ghili mercury, foiind growing naturally in fhady laaes in many places in Britain. It iias large triangidar, ar^ row-pointed, entire leaves ; upiight, thick, Itriated italks, garnifhed with triangular leaves, and terminated by clofe fpikes of apetalous yellowilh-green flowers joyed perfed health to a very great age. in June auJ July, which are fucceeded by ripe feeds CHEPELIO, an ifiand in the bay of Panama and in Auguit. 2. The fcoparia, belvidere, or annual province of Darien, in South America, fituated about Hiock-cyprefs, which is of a beautiful pyramidal three leagues from the city of Panama, which it fup- form, refcmbhng a young cyprefs-iree. 3. The bo- plies with provifions. W. Long. 8 1. N. Lat. 9. trys, or oak of Jerufakm. 4. The ambrofoides, or oak of Cappadt)cia. All thefe are very eafily pro- pagated from feeds ; and will thrive beft in a rich light earth. Moft of the fpecies have an aromatic fraell. A fpecies which grows near the Mediter- ranean is ufed by the Egyptians in fallads, on ac- count of its faltiih aromatic talte. From- the fame plant kelp is made in other countries. — The firft fpe- cies, or Englilh mercury, was formerly ufed as ipi CHEPSTOW, a market town of Monraouthfliire in England, feated on the river Wye near its mouthy, in W. Long. 2. 40. N. Lat. 51. 40. CHEQ^or Cherif, the prince of Mecca, who is^ as it were, high prieft of the- law, and fovereign pon- tiff of aU the Mahometans of whatever fetl or countrjt they be. See Calipk. The grand fignior, fophis, moguls, khans of Tarta- rf, &.C. fend him yearly prefents, efpeclally tapeftry to nach ; but is now difufed, as being greatly inferior cover Mahomet's tomb withal, together with a fump to that herb. As an article of the materia medica, it tuous tent for himfelf, and vail fums of money to pro- is ranked among the emollient herbs, but rarely made vide for all the pilgrims during thsri? days of ^leir ufe of in praftiee. The leaves are applied by the devotion. common people for heahng flight wounds, cleanfing CHERASCO, a ftrong and confiderable town of old ulcers, and other like purpofcs. The roota are Italy, in Piedmont, and capital of ^ territory of the given to flicep that have a cough. Goats and flieep fame name, with a (Irong citadel belonging to the are not fond of the herb; cows, horfes, and fwine, king of Sardinia, where he retired in 1706, during vefufe it. — The fecond fpecies, or belvidere, is a plant the fiege of Turin. It is fedted at the confluence of Miuch efteemed in China. The following are the the rivers Sturia and Tanaro, upon a mountain. E.. properties attributed to it in the Chinefe Herbal. Long. 7. 55. N. Lat. 44. 35.. After having faid that it is about the end of March or CHERBURG, a fea-port town of France, in Nor- beginning of April that the belvidere fprings up from mandy, with a harbour and Auguftine abbey. It is the earth ;. that its fuckers or flioots rife to the height remarkable for the fea-fight between the EngHfli and- of eight or nine inches, in fhape of a child's fift half French fleets in 1692, when the latter were beat, and ihut ; that it afterwards extends itfelf, and fends forth upwards of twenty of their men of war burnt near a number of branches loaded with leaves like thofe of Cape la Hogue. The Britifh landed here in Augufl- llax ; and thai, as it grows> its branches arrange them- 1758, and took the town, with the fhips in the bafon,, felves naturally in the form of a beautiful pyramid ; demoliflied the fortifications, and ruined^ the other it adds, that its leaves, yet tender, abound with juice, wcjrks which had been long carried on for enlarging and have a very agreeable talte ; that it may be eaten the harb-our and rendering it more fafe and conveni- as a fallad with vinegar, to which a Little ginger has ent. Within thefe fev/ years it has been attempted been added ; that being prepared like other leguminous again to improve the harbour, and rebuild the works;, plants, and baked with meat, it gives it an agreeable but after confiderable progrefs had been made, a great and pkafing flavour ; that, when in its full beauty, its part of them fuddenly g ave way, and the enterprife it 5 w CHE Chcreni II Cherniei. is thmiglit will not be again refumcd. E. Long. 1.38. N. Lat. 49. 33. CHEREM, among the Jews, is ufed to fignify a fpecies of annihilation. See Annihilation. The Hebrew word cherem.., fignifies properly to de- Jlroy, exterinimie, devote, or anathemat'ife. Cherem is likewife fometimes taken for that which is confecrated, vowed, or offered to the Lord, fo that it may no longer be employed in common or profane tifes. No devoted thing that a man fliall devote uuto the Lord, of all that he hath of man and beaft, and of the field of his polfefiion, fhall be fold or redeemed ; every devoted thing is mo ft holy to the Lord : none devoted, which fhall be devoted of men, ihall be re- deemed, but fliall furely be put "to death. There are fome who alfert that the perfons thus devoted were put to death ; whereof Jephtha's daughter is a me- moral:I>; example. Judges xi. 29. ^c. Cherem is alfo ufed for a kind of excommunicatio-n in ufe among the Jews. See Nionui. CHERESOUL, or Chakrzul, a town of Turkey in Aha, capital of Curdillan, and the feat of a begler- beg. E. Long. 45. 15. N. Lat. 36. o. CHERILUS, of Samos, a Greek poet, flouriflied 479 j-ears before Chriit. He fung the viflory gained by the Athenians over Xerxes, and was rewarded with a piece of gold for every verfe. His poem had afterwards the honour of beirtg rehearfed yearly with the woi-ks of Homer. CHERLERIA, in botany: A genus of the tri- gynia order, belonging to the decandriaclafs of plants; and in the natural method ranking under the 22d or- der, Caryophyllex. The calyx is pentaphyllous ; there are five nedlaria, bifid, and petal-hke ; the anthers al- ternately barren ; the capfule is trilocular and three- valved. CHERLESQLJIOR, In Turkifh affairs, denotes a lieutenant general of the grand lignior's armies. CHERMES, in zoology, a genus of infefts belong- ing to the order of infedfa hemiptera. The rollru;Ti is fituated on the breatt ; the feelers are longer than the thorax ; the four wings are defledted ; the thorax is gibbous ; and the feet are of the jumping kind. There are 1 7 fpecies ; and the trivial names are taken from, the plants which they frequent, as the chermes gra- minis, or grafs-bug ; the chermes ulmi, or elm-bug, ficc. The chei'ines ficus, or fig-tree bug, one of the lar- geft of the genus, is brown above andgreenlfli beneath. The antenna, likewife brown, are large, hairy, and one third longer than the thorax, 'i he feet are yel- lowifti ; the wings large, twice the length of the ab- domen. They are placed fo as to ioxm together an acute roof. l he membrane of which they confifi: is thin and very tranfparent ; but they have brown veins,, ftrongly marked, efpecially towards the extremity. The roftrum of this chermes is black, and takes its rile fi-om the lower part of the thorax, between the firft and fecond pair of feet. It is an infect to be met with in great numbers upon the fig-tree. The larva has fix feet. It is like the infeft, when pro- fldod with wings. Its form is oblong, and its mo- tion flow. I'he chryfalis differs from it by two flat buds that fpring from the thorax and inclofe the wings, r 637 ] CHE plates of their thorax give them a broad uncouth ap- pearance, and a heavy look. When the little chryfa- Itds are going to be metamorphofed, they remain ino- tionlefs under fome leaves which they fix themfelves upon. Their flcin then divides upon the head and tlujrax, and the perfe6l infeft comes forth with his. wings, leaving the fpoil of his chryfalis open and rent anteriorly upon the leaf. Thefe kind of floughs are often found beneath the leaves of the fig-tree. l"he perfetl infect is furniHied with four wings, large in proportion to its body, veined, and placed in the form of a roof; and with them it flies, it has, more- over, the faculty of leaping pretty brifkly, by means of its hinder-legs, which play like a fpring. When it is attempted to catch the chermes, it makes its efcapc rather by leaping than flying. Some of thofe infe»it* have a mancEuvre worthy of notice. Several fpecies- are provided at tlie extremity of their body with a fmall fiiarp-pointtd implement, but which lies con- cealed, and that they draw out in order to depofit tlieir eggs, by making a puncture in the plant that fuits them. By this method the fir-tree chermes pro- duces that enormous fcaly protuberance that is to be found at the fummit of the branches of that tree, and which is formed by the cxtravafatlon c^f the juices oc- cafioned by the punftures. The young larvre fiielter themfelves in cells contained in the tumor. The white down, under which the larva of the pine-chermes is found, feems to b& produced much in the fame manner.- That of the box -tree chermes produces no tuberculi like thofe ; but its punttures make the leaves of that tree bend and grov/ hollow In the (liape of a cap, which by the union of thofe inflefted leaves produces at the extremity of the branches a kind of knobs, in which the larva; of that Infect find fiielter. The box-chermes,. as well as fome others, has yet another peculiarity, wliich is, that the larva and Its chryfalis eject at the anus a white fweet-tafted matter, that foftens under the touch, and Is not unlike manna. This fubftance is- found in fmall white grains within the balls formed by the box-leaves, and a firing of the fame matter is often' feen depending from the anus of the infedt. Chermes Mineral. Sea Kermes. CHERRY -ISLAND, an ifland in the northern ocean,^ lying, between Norway and Greenland, in E^Long,- 20. 5. N. Lat. 75. o. CHERRr-Trce, in botany. See Prunus, CHERSO, an ifland in the gulph of Venice, wlth- a town of the fame name near Croatia, belonging ta tlxe Venetians. The air is good, but the foil fi;ony however, it abounds in wine, cattle, oil, and excel-- lent honey. E. Long. 15. 5. N. Lat. 45. 8. CHERSONESUS, aniong modern geographers^ tlie fame with a penlnfula ; or a continent almoft en- compafied round with the fea, only joining to the mala land by a narrow neckv or iilhinus. The word is- Greek, ,:tE/'o-ov»(r@' ; of x^P'^°^'' land, and vra-or, ifland which fignifies the fame. In ancient geography^ it was applied to feveral penlnfula*; as the Cherfo^ nefus-Aurea, CImbrIca, Taurica, and Thracia, now thought to be Malacca, Jutland, Crim Tartary, and-; Romania. CHERT, Pet ROsiLEx, Lapis Corneus, the Horn- afterwards feen in the perfeit infedt. Thefe chryfa- Jle'in of the Germans ; a fpecies of ftone claffed by lids are frequently met with on plants ; and the two Cronftedt among the fxlic^ous eartliS. Itisofacoar- CHE [ 638 1 CHE Chert II Cherub. fer texture than the common flint, as well as fofter ; for which reafons it is not capable of fuch a fine po- ; lifli. It is femitranfparent at the edges, or when bro- ken into veiy thin pieces. It is found of different colours, viz. white, wnitifii-yellow, flefh-coloured, and greenifli. According to Mr Kirwan, it runs in veins through rocks, from whence its name is derived ; its fpecitic gravity being from 2590 to 2700. In the fire it whitens and decrepitates like filex, but is generally fufible jf)er fe. Mineral alkali does not totally diffolve it in the dry way, but borax and microcofmic fait do fo without effervefcence. Its appearance is duller and lefs tranfparent than common flint. The reddifli pe- trofilex, ufed in the count de Lauragais's porcelain manufaftory, and there called feld-fpat, contained 72 per cent, of lilex, 22 of argill, and 6 of calcareous earth. Cronlledt obferves that there are not as yet any certain charafters known by which the cherts and jafpers may be dillinguiflied from one another, though they can eafily be fo by fight ; the cherts appearing of a fine fparkHng texture when broken ; but the jaf- pcr being grained, dull, and opaque, and having the appearance of a dry clay. The chert is alfo found forming larger or fmaller veins, or in nodules like ker- nels in rocks ; whereas the jafper, on the contrary, fometimes conilitutes the principal part of the high- eft and mofl: extended mountains. The chert is like- wife found plentifully in the neighbourhood of fcaly limeft(^e, as flints are in the llrata of chalk. The connexion between thefe bodies is not yet dif- covcred ; but it is impolTible to eftablifh any eflential difference between them, from the circumftance of flints and agates being generally found in fmgle, loofe, and irregular nodules, and hardly in rocks like the chert : for near Conitantinople the agate ftone runs in a vein acrofs the rock, of the fame hardnefs, and as fine and tranfparent, as thofe agates found in round nodules at Deux Fonts. CHERTZEY, a market town of Surrey in England, about feven miles weft from Kingfton upon Thames. W. Long. 30'. N. Lat. 51. 25. CHERUB, (plural, Cherubim) ; a celoftial fpirlt, which in the hierarchy is placed next to the feraphim. See Hierarchy. The term cheruhy in Hebrew, is fometimes taken for a calf or ox. Ezekiel fets down the face of a cherub as fynonyraous to the face of an ox. The word cheruhy ill Syriac and Chaldee, fignifies to till or plonvy which is the proper work of oxen. Cherub alfo fignifies Jirong and powerful. Grotius fays, that the Cheru- bim were figures much like that of a calf. Bochart thinks likewife, that the cherubim were more like to the figure of an ox than to any thing befides ; and Spencer is of the fame opinion. Laftly, St John, in the Revelations, calls cherubim beajls. Jofephus fays the cherubim wei'e extraordinary creatures, of a figure unknown to mankind. Clemens of Alexandria be- lieves, that the Egyptians imitated the cherubim of the Hebrews in the reprefentations of their fphinxes and their hieroglyphical animals. All the feveral de- fcriptions which the fcripture gives us of cherubim difler from one another ; but all agree in reprelenting them as a figure compofcd of various creatures, as a aiian, an ox, an eagle, and a hon. Such were the tlicrubim dtfbi-ibed by EzekieL Thofc whidi Ifaiah faw, and are called feraphim by him, had the figure Chervil of a man with fix wings ; with tvp© whereof they I' covered their faces, with two more they covered their Chefelden. feet, and with the two others they flew. Thofe which Solomon placed in the temple of Jerufalem are fuppofed to have been nearly of the fame form. Thofe which St John defcribes in the Revelations were all eyes before and behind, and had each fix wings. The firft was in the form of a lion, the fecond in that of a calf, the third of a man, and the fourth of an eagle. The figure of the cherubim was not always uniform, fince they are differently defcribed in the fhapes of men, eagles, oxen, lions, and in a compofition of all thefe figures put together. Mofes likewife calls thefe fym- bolical or hiereglyphical reprefentations, which were embioidered on the veils of the tabernacle, cherubim of coftly work. Such were the fymbolical figures which the Egyptians placed at the gates of their temples and the images of the generality of their gods, which were commonly nothing but ftatues compofed of men and animals. CHERVIL, in botany. See CHiEROPHYLLUM. CHESAPEAK, in America, one of the largeft bays in the known world. Its entrance is between Cape Charles and Cape Henry in Virginia, 12 miles wide ; and it extends 270 miles to the northward, dividing Virginia and Maryland. Through this ex- tent it is from 7 to 18 miles broad, and generally about 9 fathoms deep ; affording many commodious har- bours, and a fafe and eafy navigation. It receives the waters of the Sufquehannah, Patomak, Rappahan- nock, York, and James rivers, which are all large and navigable. CHESELDEN (William), an eminent anatomlfl and furgeon, was born at Burrow on the Hill, in the county of Leicefler, defcended from an ancient family in the county of Rutland, whofe arms and pedigree are in Wright's " Hiftory of Rutland." He received the rudiments of his profeffiona! flls. CHE [640 iCheft. lofe his moves : but above all, the game Hiould be well arranged before the queen is played out. Ufelefs checks fliould alfo be avoided, unlefs fome. advantage is to be gained by them, becaufe the move may be loll, if the adverfary can either take or drive the piece away- 2. If the game is crowded, the player will meet with obftrudtions in moving his pieces; for which reafon he Should exchange pieces or pawns, and caiUe (a) his king as foon as it is convenient, endeavouring at the fame time to crowd the adverfary's game, wlilch may be done by attacking his pieces with the pawns, if the adverfary fliouW move his pieces out too foon. 3. The men {hould be fo guarded by one another, that if a man faould be loll, the player may have it in his power to take one of the adversary's in return ; and if he can take a fupenor piece in lieu of that which he loft, it would be an advantage, and dillrcfs the adverfary. 4. Tlie adverfaiy's king fliould never be attacked without a force futFicient ; and if the player's king fhould be attacked without having it in ^lis pov/er to attack the adverfary's, he fhould offer to make an ex- change of pieces, which may caufe the adverfary to lofe a move. 5. The board fhould be looked over with attention, and the men reconnoitred, fo as to be aware of any flroke tlrat the adverfary might attempt in confcqucnce of his laft move. If, by counting as many moves for- ward as poflible, the player has a profpeft of fuccefs, he fhould not fail doing it, and even facrifice a piece or two to accomplifli his end. 6. No man fhould be played till the board is tho- roughly examined, tliat the player might defend him- felf againft any move the adverfary has in view ; nei- ther fhould any attack be made till the confequcnces of the adverfary's- next move are confidered ; and when an attack may with fafety be made, it Oiould be pur- fued without catching at any bait that might be thrown out in order for the adverfary to gain a move, and thereby caufe the dcfign to mifcarry. 7. The queen fhould never ftand in fuch a manner before the king, that the adverfarjs by bringing a rook Or bifhop, could check the king if fhe were not there ; as it might be the lofs of the queen. 8. The adverfaiy's knight fhould never be fufxcrcd to check the king and queen, or king and rook, or queen and rook, or the two rooks at the fame time ; efpc- cially if the knTght is properly guarded: becaufe, in the two firfl cafes, the king being forced to go out of ♦heck, the queen or the rook mufl be lofl ; and in the two laft cafes a rook muft be lolt at leaft for a worfe piece. 9. The player fliould take care that no guarded pawn of the adverfary's fork two of his pieces. 10. As foon as the kings have caftled on different fides of the board, the pawns on that fide of the board fliould be advanced upon the adverfary's king, and the pieces, efpeciajly the queen and rook, fhould be brought ] C H E to fupport them ; and the three pawns belonging to the king that is caftled mufl not be moved. 11. The more; moves a player can have as it were in anibufcatle, the better; that is to fay, the queen, bifhop, or rook, is to be placed behind a pawn or a piece, in fuch a pofition as that upon playing vliat pawn or piece a check is difcovered upon the adverfaiy's king, by wliich means a piece or fome advantage is often gained. 12. An inferior piece fhould never be guarded with a fuperior, when a pawn would anfwer the fame purpofe ; for this reafon, the fuperior piece may re- main out of play ; neither Ihould a pawn \it guarded with a piece when a pawn would do as well. 13. A well fupported pawn that is paffed often cofts the adverfary a piece ; and when a pawn or any other advantage is gained without endangering the lofs of the move, the pkiyer fliould make as frequent exchanges of pieces as he can. The advantage of a paffed pawn is this: for example, if the player and his adverfary have each three pawns upon the board, and no piece, and the player has one of his pawns on one fide of tlie board, and the other two on the other fide, and the adverfary's three pawns are oppofite to the player's two pawns, he fhould march with his king as foon as he can, and take the adverfary's pawns: If the ad- verfary goes with his king to fupport ihem, the play- er fhiould go on to queen with his fmgle pawns; and then if the adverfary goes to hinder him, he fliould take the adverfary's pawns, and move the others to queen (b). 14. When the game is near finllhed, each party having only three or four pawns on each fide of the board, the kings muft ende~avour to gain the move in order to win the game. For inftance, when the play- er brings his king oppofite to the adverfarj-'s with on- ly one fquare between, lie will gain the move. 15. If the adverfaiy has his king and one pawn on the board, and tlie player has only his king, he cannot lofe the game, provided he brings his king oppofite to the adverfaiy's, when the adverfar)'- Is directly before or on one fide of his pawn, and there is only one fquare between the kings. 16. If the adverfaiy has a blfliop and one pawn on the rook's line, and this bUhop is not of the colour that commands the corner fquare the pawn i;^ going to, and the player Iras only his king, if he can get into that corner, he cannot lofe ; but, on the contrary, may win by a Ptale (c). 17. If the pl-ayer has greatly the difadvantag* of the game, having only his queen left in play, and his king happens to be in a poficion to win, "as above mention- ed, he fhould keep giving check to the adverfary's king, always taking care not to check him where he can interpofe any of his pieces that make the ftale ; bv fo doing he will at laft force the adverfary to take his queen, and then he will win the game by being in a ftale-mate. 18. The Cb (a) Ca/lle his Mng, is to cover the king with a caftle ; which is done by a certain move which each player has a right to whenever he thinks proper. (b) T^o queen, is to make a queen ; that is, to move a pawn into the adverfary's back row, which is the rule at this game when the original one is loft. (c) When the king is blocked up fo as to have no move at all. G H Chefs. i8. The pk'/er (hould ""V""* piece that a pawn puflied upon it may take, for fear of getting only the pawn in exchange for the piece. 19. A player fiiould never crowd his adverfary up with pieces, for fear of giving a ftale-mate inadver- tently, but always fhould leave room for his king to move. By way of corroborating what has been already faid with refpeft to this game, it is neceffary to warn a player againft playing a timid game. He Ihould never be too much afraid of lofing a rook for an inferior piece ; becaufe although a rook is a better piece than any other except the queen, it feldom comes into play to be of any great ufe till at the end of the game ; for which reafon it is often better to have an inferior piece in play, than a fuperior one to lland ftill, or moving to no great purpofe. If a piece is moved, and is imme- diately drove away by a pawn, it may be reckoned a bad move, becaufe the adverfary gains a double ad- vantage over the player, in advancing at the fame time the other is made to retire ; although the fiift move may not feem of confequence between equal players, yet a move or two more loil after the firft makes the game fcarcely to be recovered. There never wants for variety at this game, pro- vided the pieces have been brought out regular ; but if otherwife, it often happens that a player has fcarce any thing to play. Many indifferent players think nothing of the pawns, whereas three pawns together are l^rong ; but four, which conilitute a fquare, with the affiftance of other piecesj well managed, make an invincible-ftrength, and in all probability may produce a queen when very much wanted. It is true, that two pawns with a fpace be- tween are no better than one ; and if there fhould be three over each, other in a line, the game cannot be in a worfe way. This ihows that the pawns are of great confequence, provided they are kept clofe together. Some middling players are very apt to rilk loling the ^3.me in order to recover apiece; this is a mifl-ake; for it is much better to give up a piece and attack the enemy in another qnar'.cr ; by fo doing, the player has a chance of 1 Hatching a pawn or two from, or gaining fome advantage over, the adverfary, whiKt his attention is taken up in purfuing this piece. If the queen and another piece are attacked at the fame time, and that by removing the queen the piece mull be loft ; provided two pieces can be gained in -exchange for the queen, the queen faould be given up, ■ it being the difference of three pieces, and confequently more than the value of the queen By lofuig the queen, the game is not thrown into that diforder which it would otherwile have been : in this cafe it would be judicious to ^ive the queen for even a piece, or a pawn or two ; it beiag well known among good players, that he who bcgviis the attack, and cannot maintain it, being obliged to ret re, generally lofes the game. A player fhonld never be fond of changing without reafon, becaufe the adverfary, if he is a good player, will ruin his fituation, ana gain a coniiderable advan- tage over him. But rather than lofe a move, when a j)layer is llronger than the adverfary, it is good play to change, for he thereby increafes his ftrength. "When the g>i.De is almoil drawn to a conclufion, the player fhould recoUeit that his king is a capital Vol. IV. Part II. E [ 641 ] C H }l never cover a check with a piece,, and confequently fhould keep him in motion by fo doing he generally gets the move, and often the game. As the queen, rook, and bifhop, operate at a di~ ftance, it is not always neceffary in the attack to have them near the adveifary's king. If a man can be taken with different pieces, the player faould take his time, and confider which of tliofe pieces is the beft to take it with. If a piece can be taken almofl at any time, the player fliould not be in a hurry about it, 'but try to make a good move elfewhere before he takes it. A player fliould be cautious how he takes his ad- verfary's pawn with his king, as it often happens to be a fafe -guard to it. After all that has been faid, it is flill neceffary for us to advife thofe who would play well at this game, to be very cool and. attentive to the matter in queflion; for it is impoffible that any perfon in the univerfe can be capable of playing at chefs if their thoughts arc employed elfewhere. The laws at this game are, 1. If a player touches his man, he muft play it, and if he quits it, he cannot recal it. 2. If by miftake or otherwife a falfe move is played, and the adverfary takes bo notice of it till he hath played his next move, it cannot be recalled by eitlier of the parties. 3. If a player mifplaces the men, and he plays twa moves, it is at the option of the adverfary to permit him to begin the game or not. 4. If the adverfary plays or difcovers a check to a player's king, and gives no notice of it, the plaver may let him fland ftill till he does. 5. After the king is moved, a player cannot cafde. ^ Sarafin has an exprefs treatife on the different opi- nions of the origin ef the Latin fchacchi^ whence the French ethecs, and our chefs, is formed. Menage is alfo very full on the fame head. LeuncUvius takes it to come frem Ufcoches, famous Turkifh robbers : P. Sirmond, from the German fcachhe, " theft;" and that from calculus. He takes chefs to be the fame witli the Indus latrunculonim of the Romans, but miflakenly. Ihis opinion is countenanced by VofTuis and Salma- fius, who derive the word from calculus^ as ufed for latrunculus. G. Tolofanus derives it from the Hebrew, fcach, vallaDit et mat mortinis ; whence check and che:k- maie. Fabricius fays, a celebrated Perfian aftronomer, one Schatrenfcha, invented the game of chefs ; and gave it his own name, which it ftill beai-s in that country. Nicod derives it from fchccgue, or xeque, a Moorifh word for lord, king, and prince. Bochart adds,^ that fcach is originally Perfian ; and that fcach- mat, in that language, fignifies the king is dead. - The opinion of Nicod and Bochart, which is likewife that of Scriverius, appears the moft probable. Mr Twifs mentions a fmall treatife on chefs, written, as he fuppofes, about 400 years ago ; at the which is a-reprefentation of a round chefs-board, direftions for placing the men upon it. In thi knight can cover the 64 fquares on the boani many moves. The board is divided into thefe 64 by four concentric circles, having an empty fpat. the middle; and each of thefe is divided into 16 parts. Number i is placed in the outermofl circle ; number 2 in the third circle counting inwards, in the divifion to 4M "the of •ith ihe . as rrts in 'CHE [64 the right hand of the former ; number 3 is placed in the outermoft circle, in the divifion to the right hand of 2 ; 4 in the third circle counting inwards to the right hand of three ; and thus alternately from the firll to the third, and from the third to the firft circle, till the round is completed by 16 on the third <:ircle to the left hand of i. Number 17 is then placed on the divilion of the innermoft circle to the right hand of i ; 18 on the fecond circle counting inwards, to the right hand of 17; and thus alternately from the fourth to the fecond, and from the fecond to the fourth circles, until the round is completed by 32, direftly below number i. Numl^er 33 then is placed on the third circle direftly to the right hand of number 2 ; 34 on the fourth circle, to the right hand of 4 ; and thus al- ternately between the third and fourth circles, until the round is again completed by 48 on the fourth cir- cle, direftly below number 33. The numbers are now placed in a retrograde fafhion ; 50 on the outer circle in that divilion immediately to the right hand of 1 ; 51 on the third circle, to the left hand of 2, and di- reclly below number 32 ; 52 is then placed on the outer circle, immediately on the left hand of i : 53 on the third circle direftly to the left hand of 16 ; and thus alternately on the firll: and third circles, until the lafl round is completed by 64 between the numbers 3 and 5. On this round chefs-board, fuppofmg the black king to be placed in number 48 on the fourth circle, the queen ftands on number 17 at his left hand ; the bi- fliops in 33 and' 2 ; the knights 18 and 47 ; the callles in 3 and 50 ; the pawns on 19, 4, 49, 64, and 46, 51, 32, I. The white king will then lland in 25, oppofite to the black queen ; the white qileen in ^ o oppoGte to the black king, and fo on. In playing on a board of this kind, it will be found, that the power of the callk is double to that in the common game, and that of the bifliop only one half ; the former having 16 fquares to range in, and the laft only four. The king can caftle only one way ; and it is very difficult to bring the game to a conclufion. With regard to the origin of the game at chefs, we are much in the dark; Thoughj, it came to us from the Saracens, it is by no means probable that they were the original inventors of it. According to fome, it was invented by the celebrate^ Grecian hero Dio- medes. Others fay,that two G recian brothers, Ledo and Tyrrheno, were the inventors; and that being much preifed with hunger, they fought to alleviate the pain by this amufement. It is certain, however, that it is a game of very ancient ftanding, and in former ages has been ▼ei-y fafhionable in every part of Europe ; though in this country it is not now very common, probably on account of the intenfe application of thought required to play at it. It has long been a favourite of the Icelanders and other northern people. There is little difference between their game and ours. The game of chefs has been generally praftifed by the greateft warriors and generals; and fome have even fuppofed that it was necefiary for a military man to be well fl^ Kuthar at the time when Al Mamun's forces were car- rv'lng on the fiege of that city with fo much vigour that it was on the point of being carried by affault. Dr Hyde quotes an Arabic hiftory of the Saracens, In which the khalif is fald to have cried out when warned of his danger. Let me alone, for I fee checkmate agalnlt Kuthar ! We are told that Charles I. was at chefs- when news were brought of the final intention of the Scots to fell him to the EngHlh ; but fo little wa3 he difcompofed by this alarming intelligence, that he continued his game with the utmoll compofure ; fo. that no perfon could havt^ known that the letter he received had given him information of any thing re^ markable. King John was playing at chefs when the deputies from Rouen came to acquaint him that their, city was befieged by Philip Auguftus ; but he would- not hear them until he had finlflied his game. The following remarkable anecdote we have from Dr Robertfon in his Hiftory of Charles. V. John. Frederic, eleftor of Saxony, having been tiiken pri- foner by Charles, w?.s condemned to death. The decree was intimated to him while at chefs with Erneft. of Brunfwic, his felloW-prifoner. After a. Ihort paufe, and making fome refledtions on the irregulai-ity and Injuftice of the emperor's proceed- ings, he turned to his antagonift, w'hom he challen- ged to finlfh the game. He played with his ufual in- genuity and attention; and having beat Erneft, expref- fed all the fatlsfaftlon that is commonly felt on gain- ing fuch viftorles. He was not, however, put to death,., but fet at liberty after five years confinement. In the Chronicle of the Moorlfli kings of Granada w& find it related, that In 1 396, Mehemed Balba felzed up- on the crown in prejudice of his elder brother, and pafTed his life in one continual round of difafters. His wars with Caftile w^ere invariably unfuccefsful ; and hl& death was occafioned by a poifoned veft. Finding his cafe defperate, he difpatched an officer to the fort of Salobrena to put his brother Juzaf to death, left that prince's adherents fhould form any obftacle to his fon's fucceflion. The alca,yde found the prince playing at chefs with an alfaqui or prieft. Juzaf begged hard for two hours refpite, which was denied him ; at laft with great reludlance the officer permitted him to finifh the game ; but before it was finifhed a meflenger arrived with the news of the death of Mehemed, and the un- animous eleftion of Juzaf to the crown. We have a curicus anecdote of Ferrand count of, Flanders; who having been accuftomed to amufe him- felf at chefs with his wife, and being conftantly beaten by her, a mutual hatred took place; which came to fuch an height, that v^hen the count was . taken pri- foner at the battle of Bovines, (he fuffered him to re- main a long time in prifon though ^e could eafily. have procured his releafe. The game of chefs has undergone confiderable vari- ations fince it was firft invented. We have it on good, authority, that . among the eaftern . nations, the pieces now called the queen was formerly called the vizir or- king's minifter, and that the powers of the queen her- felf were but very fmall. The chefs-boards ufed by, Tamerlane were larger, and contained many more- fquares,,. CHE Cliefs, Cheft. fquares, tlian thofe at prefent in ufe. Carrera invented ^ two new pieces to be added to the eight commonly in ufe. One of thefe, which he calls Campiotie, is placed between the king's knight and caftle; the other, named Centaury between the queen's knight and caftle, has the move of the bifhop and knight united. This in- vention, however, did not furvive its author. In an- other of this kind, the two additional pieces are called the centurion and c/ecurion the former, fituated between the king and his biihop, in its move the fame with that of the queen, but only for two fquares; the latter moves as the bifhop, but only one' fquare at a time. This, like the former, died with its inventor. The chefs-board of Tamerlane was a parallelogram, having eleven fquares one way and twelve the other. In the Memoirs of the late Marlhal Keith, we find it related, that he invented an amufement fomething fimilar to that of chefs, with which the king of PiufTia was highly entertained. Several thoufand fmall flatues were call by a founder ; and thefe wei-e ranged oppo- fite to each other as if they had been drawn up in an army ; making the different movements with them as in real fervice in the field. A very complicated kind of game at chefs was in- vented by the late duke of Rutland. At this the board has 14 fquares in breadth and 10 in heio-ht, which make in all 140 lioufes; and there are 14 pawns on each fide, whicli may move either one, two, or three fquares the firfl time. The other pieces were the king, queen, two bifliops, two knights, a crowned caftle uniting the move of the king and caftle, and a com- mon caftle. On tlie other fide of the king was a con- cnbine, whofe move united that of the caftle and knight, two bifliops, a fingle knight, a crowned caftle, and a common one. In this game the pawns are of very little ufe; and by the extent of the board, the knights lofe much of their value, which confequently i-enders the game more defeftive and lefs interetting than the common one. There is an amufing variety at the game of chefs, in which the king with eight pawns engages the whole fet, by being allowed to make two moves for every one o£ his adverfary. In this he is almoft certain of coming off viftorious ; as he can make his firfl move into check, and the fecond out of it. Thus he can take the queen when fhe flands immediately before her king, and then retreat ; for he cannot remain in check. He cannot be check-mated unlefs hjs adver- fary has preferved his queen and both caftles. CHf:sS'Tn'es, taqxtcts d'aniure; two pieces of wood bolted perpendicularly, one on the flarboard, and an- other on the larboard, fide of the fhip. They are ufed to confine the clue, or lower corners of the main-fail ; for which purpofe thei-e is a hole in the upper part, through which the rope paifes that ufually extends the clue of the fail to windward. See Tack. The chefs-trees are commonly placed as far before the main-maft as the length of.the main-beam. CHEST, in commerce, a kind of meafure, contain- ing an uncertain quantity of feveral commodities. A cheft of fugar, v. g. contains from ten to fifteen hundred weight ; a clieil of glafs, from two hundred to three hundred feet ; of Caftile foap, from two and an half to three hundred weight; of indigo, from one [ ^43 ] CHE and an half to two hundred weight, five fcore to the hundred. Chest, or Thorax. See Anatomy, Part IV. ^ CHESTER, commonly called Wejl-Chcjlcr, to dif- tinguifli it from many other Chefters in the kingdom ; the capital of Chefhire, in England. It is a very an- cient city, fuppofed to have been founded by the Ro- mans; and plainly appears to have been a Roman fta- tion by the many antiquities which have been and are ftiil difcovered in and about the town. It was among the laft places the Romans quitted ; and here the Bri- tons maintained their liberty long after the Saxons had got poffeffion of the reft of their country. At prefent it is a large well-built wealthy city, and carries on a confiderable trade. Mr Pennant calls it a city without parallel, on account of the fingular ftruaure of the four principal ftreets. They are as if excavated out of the earth, and funk many feet beneath the fiirfacc : the carriages drive far beneath the level of the kitchens on a line with ranges of fiiops. The houfes are moftly of wood, with galleries, piazzas, and covered walls before them ; by which not only the fiiops, but thofe who are walking about the town, are fo hid, that one would imagine there were fcarce any inhabitants in it, though it is very populous. But though by this con- tnvance fuch as walk the ftreets are fcreened from ram, &c. yet the fliops are thereby rendered dark and inconvenient. The back courts of all the houfes are on a level with the ground ; but to go into any of the four prmcipal ftreets, it is neceffary to defcend a flight of feveral fteps. Chcttcr is a bifiiop's fee. It was anciently part of the diocefe of Litchfield; one of whofe bifhops removnig the feat of his fee hither in the year 1075, occafioned his fucceffors to be frequently fl;yled bl/l:ops of Chejer. But it was not erefted in- to a ddtinft bifiioprick until the general diffolutioa of monaftenes, when king Henry VIII. in the year 1541, raifed it to this dignity, and allotted the church of the abbey of St Werburg for the cathedral, ftyhng It the cathedral church 'of Chnft and the hkjfed V irgui; adqmg the bifhoprick to the'province of Can- terbury : but foon after he disjoined it from Canter- bury, and added it to the province of York. When this abbey was diffblved, its revenues were valued at L. 1003 :5 : II. This diocefe contains the entire counties of Chelter and-Lancafter, part of the counties of Weftmoreland, Cumberland, and Yorkfhire, two chapelnes in Denbyfhire, and five pariHies in Flint- flure; amounting in all to 256 parifiies, of which loi are impropriations. This biihoprick is valued in the king's books at L.420 : i : 8, and is computed to be worth annually L.2700; the clergy's tenth amounting to L.435 : 12 : o. To this, cathedral belong a dean, two archdeacons, a chancellor, a treafurer, fix pre- bendaries, and other inferior officers and fervants. W. Long. 3. o. N. Lat. 53. 12. CHESTER-le-Street, the Cuneacejre of the Saxons ; a fmall thoroughfare town between Newcaflle and Dur- ham, with a good church and fine fpire. In the Saxon times this place was greatly refpefted on ac- count of the relics of St Cuthbert, depofited here by biftiop Eardulf, for fear of the Danes, who at that time ^about 884) ravaged the country. His fiirine 4 M 2 became Cheft, Chefter, CHE New-Chef- became afterwards an objeft of great devotion. Cheviot Athelfton, on liis expedition to Scotland, paid it a vifit, to obtain, by interceflion of the faint, fuccefs on his arms; beltowed a multitude of gifts on the church; and direfted, in cafe he died in his enterprize, that his body fnould be interred there. At the fame time that this place was honoured with the remains of St Cuth- bert, the biflioprick of Lindesfarn w^as removed here, and endowed with all the lands between the Tyne and the Were, the prefent county of Durham. It was ftyled St Cut/jicri's patrimony. The inhabitants had great privileges, and always thought themfclves exempt from all military duty, except that of defending the body of their faint. Chefter-le-Street may be con- fidered as the parent of the fee of Durham ; for when the relics were removed there, the fee in 995 followed them. Tanner fays, that probably a chapter of monk^, or rather fecular canons, attended the body at t its place from its firft arrival : but bifliop Beke, in 1286,, in honour of the faint, made the church collegiate,, and eftablifhed here a dean and fuitable ecclefiaftics ; and, among other privileges, gives the dean a right of filhing on the Were, and the tythe of iiih. New Chester, a town of Pennfylvania in America, and capital of a county of that name. It is feated on the Delawar ; and has a tine capacious harbour, ad- mitting veffels of any burden.. W. Long. 74. 7. N. Lat. 40. 15. CHESTERFIELD, a market town of Derby flilrc in England, pleafantly fituated on a hill between two fmall rivers. It has the title of an earldom; and a confiderable market for corn, lead, and other country commodities.. The houfes are, for the molt part, built of rough Hone, and covered with flate. W. Long. 1.25. N. Lat. 53. 20. Chesterfiei.d (Earl of). See Stanhope. CHEVAL c/e Frise, a large piece of timber pier- ced, and traverfed with wooden fpikes, armed or pointed with iron, five or fix feet long. See Plate GXXXVL. The term is French, and properly fignlfies a Frief- land horfe; as having been firft Invented in that coun- try. — It is alfo called a Tiimplhe or Tiirniquet. Its ufe is to defend a paffage, ftop a breach, or make a retrenchment .to ftop the cavalry. It, Is fometimes alfo mounted on wheels, with artificial fires, to roU down in an alTault. Errard obferves, that the prince of Orange ufed to inclofe his camp with Chevaux de Frtfe, placing them one over another. CHEVALER, In the manege, is fald of a horfe, when, in pafTaglng upon a walk or trot, his off fore- leg crolTes or overlaps the near fore-leg every fecond motion. CHEVALIER,a French term, ordinarily fignifying a Knight. The word is formed of the French, che- val, *' horfe ;" and the barbarous Latin cavallus. It is ufed, in heraldry, to fignify any cavalier y or horfeman armed at all points; by the Romans called cataphraBus eques : now out of ufe, and only to be feen in coat-armour. CHEVAUX ^£ Frise. See Cheval de Frifc. CHE V IN, a name ufed in fome parts of England for the Chub. CHEVIOT (orTivior) HILLS, run from north to ip-uth through Cumberland i and were, forperfy the [ 644 1 CHE King borders or boundaries between England and Scotland, Cbevifance- where many a bloody battle has been fought between ^j^jy,,^^ the two nations ; one of which I3 recorded in the bal- _ lad of Chevy cLife. Thefe hills are the firft land dif- covered by fallors in coming from the eaft into Scot- land. CHEVISANCE, la law, denotes an agreement or compofitlon, as an end or order fet down between a creditor and his debtor, Cffc. In the ftatutes, this word is moft commonly ufed for an unlawful bargaih- or contract, CHEVREAU (Urban), a learned writer, born at Lundun In 1 61 3. He diftingulflied himfelf in his youth by his knowledge of the bellts lettres ; and became fe- cretary of ftate to queen Chriftlna of Sweden. Seve- ral German princes invited him to their courts ; and' Charles-Lewis, the eleftor palatine, retained him un- der the title of couafellor. After the death of that, prince, he returned to France, and became preceptor to the duke of Maine. At length retiring to Lundun,.. he died there in 1701, aged 88. He was the author of feveral books ; and amougft others, of an Univerfal Hiftory, which has been often reprinted. CHEVRON,, or Cheyeron, in heraldry. See Heraldry.' CHEWING-BALLS, a kind of balls made of afafce- tida, liver of antimony, bay-wood, juniper- wood, and pellitory of Spain ; which being dried in the fun, and wrapped in a linen cloth, are tied to the bit of the bridle for the horfe to chew ; they create an appetite; and It Is fald, that balls of Venice-treacle may be ufed in the fame manner v,^ith good fuccefs. CHEYKS. See EckGAL, n° 17. CHEYNE (Dr George), a phyficlan of great learn- ing and abilities, born In Scotland In 1671, and edu- cated at Edinburgh under -the great Di Pitcairn. He paffed his youth in clofe ftudy, and with great tem- perance : but coming to fettle at Loudon, when about 30, and finding the younger gentry and free-livers to be the moft eafy of accefs and moft fufceptible of. frlendflrlp, he changed on a fudden his former manner of living In order to force a trade, having obferved this method to fucceed with fome others. The con- fequence was, that he grew daily in bulk, and in in- timacy with his gay acquaintance; fwelling to fuchan enormous fize, that he exceeded 32 ftone weight; and he was forced to have the whole fide of his chariot made open to receive him into it ; he grew fiiort- breathed, lethargic, nervous, and fcorbutic ; fo that his life became an intolerable burden. In this deplo- rable condition, after having tried all the power of medicine in vain, he refolved to try a milk and vege- table diet ; the good effefts of which quickly appear- • ed. His fize was reduced almoft a third ; and he re- covered his ftrength, a&ivity, and cheer fulnefs, with the perfeft ufe of all his faculties. In fhort, by a re- gular adherence to this regimen, he lived to a mature' period, dying at Bath in 1742, aged 72. He wrote fe- veral treatlfes that w^ere well received ; particularly, « An Effay on Health and Long Life ;" and " The Englifii Malady, or a Treatlfe of Nervous Difeafes ;" both the refult of his own experience. In fiiort, he liad grKit i-eputation in his own time, both as a prac- titioner and as a writer ; and moft of his pieces palTed thro' ffiveral editions. He is to be ranked among thofe phyficians C H I [ 645 ] C H I medicines and the morbid alterations which take place in the human bodjr upon mechanical principles. A fpirit of piety and of benevolence, and an ardent zeal for the interefts of virtue, are predominant throughout his writings. An amiable candour and ingenuoufnefs are alfo difcernible, and which led him to retraft with readinefs whatever appeared to him to be cenfurable in what he had formerly advanced. Some of the meta- physeal notions which he has introduced into his books, may, perhaps, juftly be thought fanciful and ill- grounded ; but there is an agreeable vivacity in his produ6lIons, together with much opennefs and frank- nefs, and in general grc-at peripieuity. CHIABRERA (Gabriel), etteemed the Pindar of Italv, was born at Savona in 1552, and went to ftudy at Rome. The Italian princes, and Urban VIII. gave him public marks of their elleem. He wrote a great number of poems ; but his lyric verfes are moll admi- red. He died at Savona in 1 638, aged 86. CHI AN EARTH, in pharmacy, one of the medici- nal earths of the ancients, the name of which is pre- ferved in the catalogues of the materia medica, but of which nothing more than the name has been known for many ages in the (liops. It is a very denfe and compaft earth ; and is fent hither in fmall flat pieces from the ifland of Chios, in which it is found in great plenty at this time. It ftands recommended to us as an aitringent. They tell us, it is the greateft of all cofmetics; and that it gives a whitenefs and fmoothnefs to the fliin, and prevents wrinkltB, beyond any of the other fubilances that have been celebrated for the fame purpofes. CHIAOUS, a word in the original Turkifli, fignify- ing " envoys," are ofiicersto the numbe'r of five or fix hundred in the grand fignior's court, under the com- mand of a chiaous bafchi. They frequently meet in the grand vifir's palace, that they may be in readi- nefs to execute his orders, and carry his dlfpatches in- to all the provinces of the empire. The chiaous baf- chi affifts at the divan, and introduces thofe who have bufmefs there. CHIAPA, the capital of a province of the fame name in Mexico, fituated abort 300 miles eail of A- capulco. W. Long. 98. o. N. Lat. 16. 30. Chupa el Real, a town of Mexico, in a province of the fame name, wath a biihop's fee. Its principal trade confiils in chocolate-nuts, cotton,, and fugar. W. Long. 98. 35. Lat. 16. 20. Chiapas de los Indos, a large and rich town of North Americaj in Mexico, and in a province of riie fame name. The governor and moft of the in- habitants are originally Americans. W. Long. 98. 5. N. Lat. 15. 6. CHIARI(Jofeph), a celebrated Italian painter, was tiie difciple of Carlo Maratti ; and adorned the churches and palaces of Rome with a great number of fine paintings. He died of an apoplexy in 1 727, aged 73. Chiar.1, a town of Italy, in the province of Brtfcia, and territory of Venice, 7 miles weft of Brefcia, and 27 eaft of Milan. Here the Imperialifts. gained a vic- tory over the French in 1701. E. Long. 18. 18. K. Lat 45. 30. CHIARO-scuRO. See CiARo-Ohfcuro^ GHIAVLNNA, a haudfomc^ populous, and large Chtabim phyficians who have accounted for the operations of town of SwUfeiland, in the country of the Grifons. . (I *^ ^ • - ^ . 1 ' T. _ . .J- -r_. J Chiav ;in-i. . , , , , — A fi'ults. The governor's palace and the churches are very magnificent, and the inhabitants are Roman Ca- tholics. It is fcated near the lake Como. E- Long. 9. 29. N. Lat. 46. 15. CHL'\USI, among the Turks, officers employed in executing the vizirs, bafliaws, and other great men : the ordeis for doing this, the grand fignior fends them wrapped up in a black cloth ; on the receptioa of which, they immediately perform their ofiice. CHICANE, or Chicanery, in law, an abufe of judiciary proceeding, .tending to delay the caufe, to puzzle the judge, or impofe upon the parties. Chicane, in the fchools, is applied to vain fo- phifms, diftinftions, and fubtleties, which protraft dif- putes, and obfcure the truth. CHICHESTER, the capital city of the county of Sufiex, was built by Ciffa, the 2d king of the South' Saxons, and by him called ClffciJi Caejier. It is fur- rounded with a wall, which has four gates, anfwering to the four cardinal points ;. from which run two ftreets, that crofs one another in the middle and form a fquare, where the market is kept, and where there is a fine ftone piazza built by biOiop Read. The fpace between the weft and fouth gates is taken up with the cathedral church and the bifhop's palace. It has five parlfli-churches ; and is feated on the little river La- vant, which w^afhes it on all fides except -the north. This city would h?.ve been in a much more flourifhing condition if it had been built by the fea-fide ; how-- ever, the inhabitants have endeavoured to fupply this defe£t in fome meafure, by cutting a canal from the city down into the bay. The principal manufadlures- of tile town are malt and needles. The market of Chi- chefter is noted for fifli, wheat, barley, malt, and oats: the fineft lobfters in England are bred in the Lavant and it is obfcrvable, that this river, luihke moft others, is very low in winter, but in fummer often overflows its banks. Chichefter is a city and county of itfelf ; it is governed by a mayor, recorder, aldermen, common- council without limitation, and four juftlces of the peace chofen out of the aldermen ; and it fends two members to parliament. It is a bifiiop's fee. The cathedral church was anciently dedicated to St Peter,.. It was new built by Radulph, the twenty-fifth bi- ftiop ; but being defti'oyed by fire, it was again built by Seffridus II. the twenty-ninth bifaop. This fee hath yielded to tlie church two faints, and to the na- tion three lord chancellors, two almoners, and one chancellor to the univerfity of Oxford. Anciently the bifliops of Chichefter were confeffors to the queens of England. This diocefe contains the whole of the county of SufTex (excepting 22 parifhes, peculiars of the archbilhop of Canterbury), wherein are 250 pa- rifties, whereof 112 are impropriated. It hath two archdeacons, viz. of Chichefter and Lewes ; is valued in the king's books at L. 677 11:3, and is computed to be worth annually L 2600. The tenths of the whole clergy is L. 287:2: c'^. To the cathedral be- long a biftiop, a dean, two archdeacons, a treafurer, a chancellor, thirty-two prebendaries, a chanter, twelve vicars-coral, and other officers. W. Long 50. N. Lat. 5c. 50. CHICK, or Chicken, in zoology, denotes the young Chlaiifi Chick. C H I C'liick- vveeJ li •ChiuJ. [ 646 J C H I young of the gallinaceous order of blrtlsj efpecially the common hen. See Phasianus. CniCK-V/edd, in botany. See A l. sine. J Chjcken-Pox. See f Index fubjoineJ to) "blzr^i el's u. CHICKLING-PEA, in botany, a name given to the L.ATHYRUS. CHICUITOS, a province of South America, in the government of Santo-Cruz de la Sierra. The chief riches coniift of honey and wax ; and the original in- habitants are very voluptuous, yet very warlike. They rriaintaintd bloody wars with the Spaniards till 1690 ; fince which, fome of them have become Chriftians It is bounded by la Plata on the N. E. and by Chili on the W. CHIDLEY, or Chimley, a market-town of De- vonfhire, fituated in W. Long. 4. o. N. Lat. 51. o. CHIEF, a term fignifying the head or principal part of a thing or perfon. Thus we lay, the chief of a party, the chief of a family, ^ n- n rr i , .^wv.,. cixl^i, ndviuw ^Lwiupauiea tne JLorcl "T r , ' ^" .^^r^^^^^J-'ge ^^everal tnings ranged Hopton, general of the kind's forces in the weft to by thoufands. I'he word is formed of the Greek niiliey a ihouland. CHILIAGON, in geometry-, a regular plain figure of 100 lules and angles. Though the imagina'tion cannot form tlie idea of fuch a figure, yet we may Arundel caftle in SufTex, he was there taken prifoner by the parliamentary forces under the command of Sir William Waller, who obliged the caftle to furrender. But his illoefs increafing, he obtained leave to be conveyed to Chichefter, where he was lodged at the bi- have a very clear notion of it in the mmd, and can fhop's palace ; and, after a fhort ficknefs, died in 1644. eali y demonffrate that the fum of ail its angles is e- He hath left feveral excellent works behind him ^ual to 1996 right ones: for the internal angles of CHILMINAR. See Persepolis every plane figure a.-e equal to twice as many right CHILD, one of the feven fages of Greece, and of ones as the figure hath fides, except thofe four which the ephori of Sparta the place of his birth, flourilTied %?L.1v PaTiT ^'""^ ""^''"^ ^^f^'-^ Chrift. He was ^ccuftomed 4 N to C H I [ 65 Chiloe il Chimaera to fay, that there were three things very difficult " To keep a fecret ; to know how beft to employ , c-ur time ; and to fufFer injuries without murmur- ing." According to Pliny, it was he who caufed the (hort fentence, Knoiv thyftlf, to be written in let- ters of gold in the temple of Delphos. It is faid that he died with joy, while embracing his fon, who had been crowned at the Olympic games. CHILOE, an ifland lying near the coaft of Chili, in South America, under the 43d degree of fouth la- titude. It is the chief of an archipelago of 40 iflands, and its principal town is Caftro. It rains here almofl all the year, infomuch that nothing but Indian corn, or fome fuch grain, that requires but little heat to ri- pen it, can ever come to perfedlion. They have ex- cellent fliell-fifh, very good wild-fowl, hogs, iheep, and beeves ; as alfo a great deal of honey and wax. They curry on a trade with Peru and Chili ; whither they fend boards of cedar, of which they have vaft forettr.. CIIILTENHAM, a town in Gloucellerfhire, fix miles from Gloucefter ; noted for its purgative chaly- Beat fpring, which has rendered it of late years a place of fafhionable refort. This wa,ter, which operates with great eafe, is deemed excellent in fcorbutic comxpkints, and has been ufed with fuccefs in the gravel. CHILTERN, a chain of chalky hills forming the fouthern part of BuckinghamOiire, the northern part of the county being diftingulflied by the name of the Vide. The air on thefe heights is extremely health- ful : The foil, though ftoney, produces good crops of wheat and barley ; and in many places it is covered with thick woods, among which are great quantities of beach.— C/j/'&ra is alfo applied to the hilly parts of Berkfhire, and it is believed has the fame meaning in fome other counties. Hence the Hundreds lying in thofe parts are called the Chiltern Hundreds. Chiltern Hundreds {Steivards of.) Of the Hundreds into which many of theEnglilTi counties were diylded by Kino- Alfred for the better government, the jurifdidion V. as originally veiled in peculiar courts ; but came after- wards to be devolved to the county courts, and fo re- mains at prefent ; excepting with regard to fome, as the chlkerns, which have been by privilege annexed to the crown. Thefe having Itill their own courts, a Steward of thofe courts is appointed by the chancellor of the exchequer, with a falary of 20s. and all fees, &c. be- longing to the office : And this is deemed an appoint- ment of fuch profit, as to vacate a feat in parliament. CHlMuERx^, a port-town of Turkey in Europe, filuated at the entrance of the gulph of Venice, in the -province of Epirus, about 32 miles north of the city Corfu, near v/hich are the mountains of Chimera, which divide Epirus from ThelTaly. E. Long. 20. 40. N. Lat. 40. 20. , , J Chimera, in fabulous hiftory, a celebrated mon- fter, fprung from Echidna arid Typhon. It had three heads ; that of a lion, a goat, and a dragon ; and con- tinually vomited flames. The forepart* of its body were thofe of a lion, the middle was that of a goat, and the hinder parts were thofe of a dragon. It ge- nerally Hved in Lycia, about the reign of Jobates, by whofe orders Bellerophon, mounted on the horfe Pe- gafus, overcame it. This fabulous tradition is explain- ed by the recolleftion that there was a burning moun- tain in Lycia, whofc top was the refort of lions on 4 o 1 CHI account of its defolate wildernefs ; the middle, which ^ Chimes, was fruitful, was covered with goats; ar\d at the hot- torn the marfhy ground abounded with ferpents. Bel- lerophon is faid to have conquered the Cliimsra, be- caufe he deftroyed the v/ild beafts on that mountain, and rendered it habitable. Plutarch fays that it was the captain of fome pirates who adorned their fhip with the images of a Hon, a goat, and a dragon. By a ch'micra, among the philofophers, is under- ilood a^ere creature of the imagination, compofed of fuch contvadlftions and abfurdities as cannot pof- fibly any where exill but in thought. CHIMES of a Clock, a kind of periodical muiic, produced at equal intervals of time, by means of a particular apparatus added to a clock. In-order to calculate numbers for the chimes, and adapt the chime-barrel, it mull be obferved, that the barrel muft turn round in the fame time that the Lime it is to play requires in fmging. As for the ciiime- barrel, it may be made up of certain bars that run athwart it, with a convenient number of holes punch- ed in them to put in the pins that are to dr v, \:\\. hamm.er : and thefe pins, in order to play tlie : - of the tune rightly, mull; Hand upriglit, or huiig down. from the bar, fome more, fome lefs. To place the pins rightly, you may proceed by the way of changes on bells, viz. i, 2, 3, 4; or rather make ufe of the mufical notes. Obfeive what is. the compafs of yom-. tune, and divide the barrel accordingly from end to end. Thus, in the examples on Plate CXXXVII. each of the tunes is eight notes in com.pafs ; and accor- dingly the barrel is divided into eight parts. Thefe diviiions are ftruck round the barrel; oppofitc to- which are the hammer-tails. We fpeak here as if there were only one hammer to each bell, that it may be more clearly apprehend- ed ; but when two notes of tlie fame found come to- gether in a tune, there mud be tv.'o hammers to the bell to Ih-ike it : fo that if in all the tunes you intend to chime of eight notes compafs, there {hould happen to be fuch double notes on every bell, inflead of eight yon mull have fixteen hammers ; and accordingly you muft divide the barrel, and llrikc fixteen ftrokes round ^ it, oppofite to each hammer-tail : then you are to di- vide it round about into as many divifions as there are mufical bars, lemibreves, minims, .'cc. in the tune. Thus the hundredth-pfalm tune has 20 femibreves, and each divifion of it is a femibreve: the firft note of it alfo is a femibreve ; and, therefore, on the chime- barrel muft be a whole divifion, from five to five ; as you may underftand plainly, if you conceive the fur- face of a chime-barrel to be reprefented by the above figures, as if the cylindrical fuperficies of the barrel were ftretched out at length, or extended on a plane : and then fuch a table, fo divided, if it were to be wrapped roiyid the barrel, would fhow the places where all the pins are to ftand in the barrel ; for the dots running about the- table are the places of the pins that play the tune. Indeed, if the chimes are to be complete, you ought to have a fet of bells to the gamut notes ; fo as that each bell having the true found of fol, ^^h nd, fa, you may play any tune with its flats and iharps : nay, you may by this means play both the bafs and treble with one barrel : and by fettlng the names of year bells at the C H I [ 651 ] CHI Cliiinney., the head of any tune, that tune may eafily be tranf- ' " V " ferred to the chime-barrel, without any Ikill in mufic : but it mult be obferved, that each line in the mufic is three notes diftant ; that is, there is a note between each line, as well as upon it. CHIMNEY, in architefture, a particular part of a houfe, where the fire is made, having a tube or funnel ,to cany off the fmoke. The word chimney comes from the French cheminee ; and that from the Latin caminata, " a chamber wherein is a chimney :" cam'mata, again, comes from cam'mus ; and that from the Greek xa^.iv(^, «< a chimney ;" of uro " I bum." Chimneys are ufually fuppofed a modern invention; the ancients only making ufe of ftoves : but Oftavio Ferrari endeavours to prove chimneys in ufe among the ancients. To this end, he cites tlie authority of Virgil, Et jam fumma proful vUlarum culmina fummt : and that of Appian, who fays, " That of thofe per- fons profcribed by the triumvirate, fome hid them- felves in wells and common fewcrs, and fome on the tops of houfes and chimneys ;" for fo he under- Rands ^ '^"^^^li ^^"po^i^Cjfumarla fub teilo pofila. Add, that Ariftophanes, in one of his comedies, introduces his old man, Polycleon, (hut up in a chamber, whence he endeavours to make his efcape by the chimney. However, the few inftances remaining among the an- cients, together with the obfcurity of the rules of Vi- truvius on this head, make us rather conclude the ufe of ftoves, whereof the ancients had entire apartments, induced them to negleft this part of building which the coldnefs of our climates obliges us to have a prin- cipal regard to. Method of Building Cvimnf.ys that nvill not fmoke. V/ orkmen have difterent methods of drawing up the funnels of chimneys, generally accprding to their own fancies and judgments, and fometimcs according to the cuftoms of places. They are feldom diretled by found and rational principles. It will be found for the molt part, that the fmoking of chimneys is owing to their being carried up narrower near the top than below, or zig-zag, all in angles : in fome cafes, indeed, it is Owing to accidental caufes ; but, for the moil part, to thofe two above mentioned. Where they are car- ried up in the pyramid or tapering form, efpecially if the houfe be of a confiderable height, it is ten to one but they fometimes fi:\oke. The air in the rooms, being rarined, is forced into the funnel cf the chim- jiey, and receives from the fire an additional force to carry up the fmoke. Now it is evident, that the fur- ther up the fmoke flies, the lefs is the force that drives it, the flower it muft move, and confequently the more room in proportion it fhould have to move in ; whereas in the ufual way it has lefs, by the fides of the chimney being gathered clofer and clofer toge- ther. The method here propofed of carrying up chim- neys will be obje£led to by fome thus ; The wider a chimney is at the top, fay they, the more liberty has the wind to blow down. Very true ; but is it not re- fifted in going down, both by the form of tlie chim- ney and other evident caufes, fo that it mult return again ? In the other way, when the wind blows down, the refiltance being lefs, the wind and fmoke are, if we may ufe the exprefiion, imprifoned, and make the fmoke puff out below. This method has proved eft. Chimney feAual after all others had failed ; and that in a houfe [I placed in the worft fituation poffibly, namely, und^r a , high mountain to the fouthward, from which ftrong blafts blow down upon it. A vent was carried tip without angles, as perpendicular as poffible ; and was made about three or four inches wider at top than at the bottom : the funnel was gathered in a throat di- rectly above the fire-place, and fo widening upwards. Since that time the houfe has not only ceafed to fmoke^ but, when the doors ftand open, the draught is fo ftrong that it will carry a piece of paper out at the chimney-head. See more on this fubjcdt under the article Smoke. Ch iMNEY-Money, otherwife called Hearth-money ^ a duty to the crown on houfes. By ftat. i^. Char. 11. cap. 2. every fire-hearth, and ftove of every dwelling or other houfe, within England and Wales (except fuch as pay not to church and poor), was chargeable with 2 s. per annum, payable at Michaelmas and Lady- day to the king and his heirs axid fucceffors, l^c. ; which payment was commonly called chimney -money. This tax, being much complained of as burdenfome to the people, has been fince taken off, and others impofed in its ftead ; among which that on win- dows has by fome been elleemed almoft equally grie- vous. CHIMPANZEE, in natural hiftory. See SiMiA, ' CHINA, a country of Afia, fituated on the moft E^^^f.^'j."'' eaftarly part of that continent. It is bounded on the ' north by Tartary ; from which it is divided, partly by a prodigious wall of 1500 miles in length, and partly by high, craggy, and inacceffible mountains. On the eaft. It is bounded by the ocean ; on the weft, by part of the Mogul's empire, and India beyond the Ganges, from which it is parted by other ridges of high moun- tains and fandy deferts. On the fouth, it is^'bounded partly by the kingdoms of Lao, Tonquin, Ava, and Cochin-China, and paitly by the fouthern or Indian fea, which flows between it and the Philippine iflands. There are feveral ways of computing its length and breadth. According to fome of thefe, it is reckoned 1269, 1600, or 1800 miles in length, and as much in breadth : however, by the beft and lateft accounts, this vaft country is fomewhat of an oval form, the breadth being lefs than the length by little more ^ than a fourth-part. It contains 15 provinces, exclu- Divifion in- five of that of Lyau-tong, which is fituated without the provin- great wall, though under the fame dominion. Their names are, i. Shenfi ; 2. Shanfi ; 3. Pecheli: which are fituated on the north fide, along the wall. 4. Slian- tong ; 5. Kyan-nang; 6. Che-kyang ; 7. Fo-kyen : which are fituated along the caftern ocean. 8. Quang- tong; 9. Quangfi ; 10. Yu-nan ; 11. Se-chuen : which Itretch themfelves towards the fouth and fouth-weft. And, 12. Ho-nan ; 13. Hu-quand ; 14. Quey-chew ; 15. Kyang-fi : which take up the middle part. For a particular defcription of all thefe, fee their proper articles. The origin of all nations is involved in obfcurity 5 and fable any other but that of the Chlntfe much more fo than ^^^'^^^^ _ Every nation is inchned to affume too ['o^nl'km?' high an aniquity to itfelf, but the Chinefe carry theirs ty. beyond all bounds. Indeed, though no people on earth are more exaft in keeping records of every me- 4 N 2 morable C H I t 652 ] G H I china. Why their Julcury 1 fo uncer tain. Pabulous hiftory of China. moraWe traafa£lton, yet fuch is the genius of the Chi- ncfe for fuperilition and fitble, that the firil part of their hiilory is defervedly contemned by every ratio- nal perfon. What contributes more to the uncertain- ty of the Chinefe hiitory is, that neither we, nor they themfelves, have any thing but fragments of their an- cient hiftorical books ; for about 213 years before Chriit, the reigning emperor of Si-whang-ti caufed all the books in the empire to be burned, e>:cept thofe writ- ten by lawyers and phyficians. Nay, the more ei- fetlally to deftroy the memory of every thing con- tained in them, Jie commanded a great number of learned men to be buried alive, left, from their me- mories, they ftiould commit to writing fomething of the tnie memoirs of the empire. The inaccuracy of the Chinefe annals is complained of even by their moil refpetted author, Confucius himftlf ; wlxo alio affirms, that, before his time, many of the oldell ma- terials for wiiting fuch annals had been dellroyed. According to the Ciiinefe hillories, the lirll monarch of the whole univerfe (that is, of China), was called Puon-lu, or Fuen-cu. This, according to feme, was the hrlt man ; but according to Bayer and Mcnze- lius, two of the greateil critics in Chinefe litera- ture that have hitherto appeared, the word iignifies the hlgheji mtiqu'iiy. Puon-ku was fucceeded by Tiene- hoang, which fignifies the emperor of heaven. They call him alfo the intelligent heaven, t'le fupreme king of the middle heaven, ijc. According to fome of their hillorians, he was the inventor of letters, and oi the Cy- clic characlers by which they determ.ine the place of the year, iffc. Tieue-h6ang was fucceeded by Ti-hoang (the emperor of the earth), who divided the day and tiight, appointing 30 darys to make one moon, and fix- ed the winter folilice to the iithmoon. Ti-hoang was fucceeded by Gine-hoang (fovereign of men), who with his nine brothers lhared the government a- mong them. They built cities-, and furrounded them ■with walls ; made a dillin^tion between the fovereign and fubjjfts ; inltituted marriage, Sfft. The reigns of thefe four emperors make up one of what the Chinefe called ki, " ages," or " periods," of which there were nine before Fo-hi, whom their moil fenhble people acknowledge as the founder of their empire. The liiftory of the fecond k'l contradifts almoft eve- ry thing faid of the firH ; for though we have but jull HOW been told that Gine-hoang and his brethren built cities furrounded with walls ; yet, in the fuCceeding age, the people dwelt in caves, or perched upon trees as it were in nefts. Of the third ki we hear nothing ; ^md in the fourth, it feems matters had been ttill worfe, as we are told that men were then only taught to re- tire into the lioUows of rocks. Of the fifth and fixth we have no accounts. Thefe fix periods, according to fome writers, contained 90,000 years ; according to others, 1,100,750. In the feventh and eighth k'l, they tell us over again •what they had faid of the firft ; namely, that men be- gan to leave their caves and dwell in houfes, and were taught to prepare clothes, i^c. Tchine-fang, tlie firil monarch of the eighth kl, taught his fubjefts to take off the hair from ilcins with rollers of wood, and co- ver themfelves with the fldns fo prepared. He taught them alfo to make a kind of web of their hair, to ferve Chin*; as a. covering to their heads againft rain. They obeyed — — v"""* his orders with joy,' and he called his {\}b]tQi!, people clothed ivith Jk'ins. His reign lafted 350 years ; that of one of his fucceffors, alfo, named Yeou-tfao-chi, lafted more than 300 ; and his family continued for 12 or 185OOO years. But what is very furprifing, all thefe thoufands and millions ofyears had elapfed with- out mankind^s having any knowledge of fire. This was not difcovered till towards the clofe of this period^ by one Souigine. After fo ufeful a difcovery, he taught the people to drefs their viftuals ; whereas be- fore, they had devoured the fieih of animals quite raw, d;ank tlieir blood, and fwallowed even their hair and feathers. He is alfo faid to have been the inventor of fifliing, letters, l^c. In the ninth period we find the invei'tlon, or at leaft the oiigin of letters, attributed to one Tfang-hic, wTiO received them from a divine tortoife that carried-" them on his fhell, and delivered tlicm into the handa of Tfang-hie. During this pei-iod alfo, muiic, money, carriages, merchandize, and commer-je, l3c. were in- vented. There are various calculations of the length of thefe hi or periods. Some make the time from Puan-ku to Confucius, who flouriihed about 479 years before Chriit, to contain 279,000 years; others, 2,276,000; fome, 2,759,860 years; others, 3,276,000^ and fome no lefs than 96,96-1,740 years. 6 Thefe extravagant accounts are by fome thought ffbulou* to contain obfcure and imperfeft hints concerning the cofniogony and creation of the world, £5" c. Puon-ku, ^ the firlt emperor, they think, i-eprefents eternity pre- ceding the duration of the world. Tiie fucceeding ones, '^llene-hoang, Ti-hoang, and Gine-hoang, they imagine, iignify the creation of the heavens and earth, and the formation of man. The ten or ages, nine of which preceded Fo-hi, mean the ten generations preceding Noah. Tliis may very pofSbly be the cafe j for about 300 years before Chrill, fome Jews travelled- into China, who might have made the Mofaic writings known there. What we have now related, contains the fubftance of that part of the Chinefe hiilory which is entirely fabulous. After the nine hi or " ages" already taken- notice of, the ten-th commenced with Fo-hi ; and the hiilory, though Hill very dark, obfcure, and fabulous, begins to grow fomewhat more confiflent and intel- ^ ligible. Fo-hi was born in the province of Shenfi.. Rgitcn of His mother walking upon the bank of a lake in that Fo-hi. province, faw a very large prinX of a man's foot in. the fand there ; and, being furrounded by an iris or rainbow, became impregnated- The child was named Fo-hi; and, when he grew up, was by his country- men elefted king on account of his fuperior merit, and ilyled Tyent-tfe, that is " the fon of heaven." He invented the eight qua, or fymbor^, con filling of three hnes each, which,, differently combined, formed 64cha- radlers tliat were made ufe of to exprefs eveiy thing. To give thefe the greater credit, he pretended that he hiid feen them infcribed on the back of a dragon- horfe (an animal fli aped like a horfe, with the wings- and fcales of a dragon), which arofe from the bottom of a lake. Having gained great reputation among hii countrymen by this prodigy, he is faid to have created' niauda.- CHI [ 653 ] C H I Ch'na. mandarins or officers, under the name of dragons. ^"""V— ^ Hence we may affign a reafon why the emperors of China always carry a dragon in their banners. He alfo inltituted marriage, invented mufic, iSc. Having ella- blilhed a prime miniller, he divided the government of his dominions among four mandarins, and died af- g ter a reign of 1 1 5 years. MiiRculous After Fo-hi followed a fucceffion of emperors, of foliiice. whom nothing remarkable is recorded, except that in the reign of I'm, tlie feventh after Fo-hi, the fun did 9 not fet for ten days, fo that the Chinefe were afraid of Hypothefis a general conflagration. This event the compilers of concerniiig theUniverfal Hiilorytake to be the fame with that meu- and Fo-hi" in the book of Jofliua, when the fun and moon °' ftood iiiil for about the fpace of a day. F^i, they will have to be the fame with Noah. They miagine, that after the deluge, this patriarch remained fume time with his defcendeuts ; but on their wicked combina- tion to build the tower ©f Babel, he feparated himfelf fV(*m them with as many as he could perfuade to go along with him j and that, Hill travelling eailward, he at laft entered the fertile toiiulvy of China, and laid the foundation of that vali empire. — But, lea- \ing thefe fabulous and conjeftural times, we lhall pro- ceed to give fome account of that part of the Chinefe liiftory, which may be more cejtairJy depended on. As the Chinefe, contrary to the practice of al- moft all nations, have never fought to conquer other countries, but rather to improve and content them- felves with their own, their hiltory for many ages farnifhes nothing remarkable. The whole of their emperors, abftrading from thofe who are faid to have reigned in the fabulous times, are comprehend- ed in 22 dynailies, mentioned in the following table. 1. HyOy containing 2. S/jang, or Irig, 3. Che-Wy 4. 7>«, 5. Han, 6. Hetu-hany 7. Tfm, 8. Songy 9- rjty to. Ijyangy 1 1 . Chin, 1 2 . Siv i, rj. Tivavgy. 14. Htw-lyangy 15. Heiv-tangy 16. Heiv-tfiny 17. Hew-hun, 18. Heiv-cbe-Wy 19. Song, 20. Liven, 2 1. Mingy 2 2. Tfng, This table is formed according to the accounts of the Jefuit Du Haldc, and is commonly reckoned to be the moft authentic ; but according to the above men Empe- ors. Before Chrift. 17 2207. 28 1766. 35 J I 22-. 4 248. 25 206. After Chrift. 2 220. 15 465- 8 220. 5 479- 4 502. 4 557- ^ 3 20 618. 2 907- 4 923- 2- 936. 2 947- 3 951. t8 960. 9 1280. J. 6 1368. 1645. dynafty of Hya 'did not commence till the year before Ciiuia. Chriil 1357 ; and to accommodate the hiftory to their ' ^r-**-' hypothefij, great alterations muft be made in the dura- ^ tion of the dynallies. _ _ tj,;. -j-.^.. The moll interefting particulars of the Chinefe hi- tara. ftory relate only to the incurfions of the Tartars, who at laft conquered the whole empire, and who ilill con- tinue to hold the fovereignty ; though by transfer- ring the feat of the empire to Peking, and adopting the Chinefe language, manners, i^c. Tartary would feem rather to have been conquered by China, than China by Tartary. Thefe incurilons are faid to have begun very early ; even in the time (if the emperor Shun, fucceffor to Yau above mentioned, in whofe reign the miraculous foliiice happened. At this time, the Tartars were repulfed, and obHged to re- tire into their own. territories. From time to time,, however, they continued to threaten the empire with invafions, and the northern provinces were often ac- tually ravaged by the Tartars in the neighbourhood. About the year before Chrift 2 1 3, Shi-whang-ti, ha- ving fully fubdued all the princes, or kings as they were called, of the different provinces, became em- peror of China with unlimited power. He divided the whole empire into 36 provinces ;. and finding the northern part of his domiincns much incommoded by the invafions of the neighbouring barbnrians, he feat a formidable army againft them, which drove them j r fai- beyond the boundaries of China. To prevent Great wa^! their return, he built the fp.mous wall already men- tioned, which feparates China from Tartary. After this, being elated with, his own exploits, he formed U; defign ef making pofterity believe that he himfelf had been the firft Chinefe emperor that ever fat on thc- throne. For this purpofe, he ordered all the hi'lo- rical writings to be burnt, and caufed many ot the learned to be put to death, as already men- tioned. What effeft the great wall for fome time had in preventing the invafions of the Tartars, we are not told ; but in the tenth century of the Chridian ara, thofe of Kitan or Lyau got a. footing in China. The Kitan Tav=. Kitan were a people of eaftern. Tartary, who dwelt to tars (l-trl.j the north and north-eaft of the province of Peclieli in Chir-i*. China, particularly in that of Layu-tong lying without tlie great wall. Thefe people having fubdued tlie country between Korea and Kafligar, became much more troublefome to the Chinefe than all the other Tartars. Their empire commenced about the year 916, in the fourth year of Mo-ti-kyan-ti, fecond empe- ror of the 14th Chinefe dynafty called Hxw lyang. in 946, Mingt-fong, fecond emperor of the 15th dy'na- fty, being dead, Sheking-tang, his fon-in-law,. rebelled againft Mingt-fong, his fon and fucceffor, whom he de. prived of his crown and life. Tiiis he accomplifhed by means of an army of 50,000 men furniflied by the Kitan. Fi-ti, the fon of Mingt-fong, being unable to relift the ufurper, fled to the city Ghey-chew ; where, ftiutting himfelf up with his family and all his valuable, effefts, he fet fire to the palace and was burnt to- afties. On his death, Sheking-tang affumed the title of emperor; founded the 1 6th dynafty; and changed «£ioned hypothefis of the compilers of the Univerfal his name to that of Kaul-fu. But the Kitan general^ Hiftory, who make Tau cotemporary with Jolhua, the refufing to acknowledge him, lie was obliged to pur- C H I china. chafe a peace by yielding up to the Tartars i6 cities in the province of Pecheli^ bclides a yearly prefent of 300,000 pieces of filk. This fubmiffion ferved only to inflame the avarice and ambition of the Kitan. In 959, they broke the treaty when lead expeiSlcd, and invaded the empire afrefh. Tfi-vang, the emperor at that time, oppofed them with a formidable army ; but through the treach- ery of his general Lyew-chi-ywen, the Tartars were allowed to take him prifoner. On this, Tli-vang was glad to recover his liberty by accepting of a fmall principality ; while the traitor became emperor of all China, and, changing his name to Kaut-fu, founded the 17th dynaily. The Tartars, in the mean time, ravaged all the northern provinces without oppofition, and then marched into the foulhern. But being here flopped by fome bodies of Chinefe troops, the gene- ral thought proper to retire with his booty Into Tar- tary. In 962, Kaut-fu dying, was fucceeded by his fon In-ti. The youth of this prince gave an opportu- nity to the eunuchs to raife commotions ; efpecially as the army was employed at a diftance in repelling the invafions of the Tartars. This army was com- manded by Ko-ghey, who defeated the enemy in fe- -veral battles, and thus reftored peace to the northern provinces. In the mean time, In-ti was flain by his eunuchs, and the emprefs placed his brother on the throne: but Ko-ghey, returning in triumph, was fa- luted emperor by his viftorious army, and the em- prefs being unable to fupport the rights of her fon, was obhged to fubmit, while Ko ghey, afRimiug the name of Tay-tfti, founded the i8th dynady. Ninp years after this, however, the grandees of the empire, fet- ting afide Kong-ti, the third in fucceffion from Tay- tfu, on account of his non-age, proclaimed his guar- dian, named Chau-qiiang-yu, emperor ; who, alfum- ing the name of Kau-tfu, founded the 19th dynafly, . called Song,) or Tfotig. Under this monarch the empire began to recover itfelf ; but the Kitan ftill continued their incurfions. The fucceffors of Kau-tfu oppofed them with various fuccefs ; but at laft, in 978, the barbarians became fo flrong as to lay fiege to a confiderable cicy. Tay- tfong, fuccefTor to Kau-tfu, detached 300 foldieri, each carrying a light in his hand, againft them in the night-time, with orders to approach as near as pof- lible to the Tartar camp. The barbarian?, imagining, by the number of lights, that the whole Chinefe ar- my was at hand, immediately fled, and, falling into the ambufcades laid for them by the Cliinefe general, were almoft all cut to pieces. This check, however, did not long put a fl;op to the ravages of the Kitan. In die year 999, they laid liege to a city in the province of Peche-li ; but Ching- tfoug, fuccefTor to Tay-tfong, came upon them with his army fo fuddenly, that they betook themfelves to flight. The emperor was advifcd to take advantage of their confternatlon, and recover the country which had been yielded to them ; but inilead of purfuing his viftory, he bought a peace, by confenting to pay an- nually 100,000 tael (about L. 34,000), and 200,000 pieces of filk. The youth and pacific difpofition of Jin-tfong, fucceflcir to Chlng-tfong, revived the cou- rage of the Kitan : and, in 1035, war would have C 654 ] C H T been renewed, had not the emperor condefcended to Chiria as fhameful a treaty as that concluded by his father. ^— v"--^ Two years after, the Tartars demanded reflltutlon of ten cities in the province of Peche-li, which had been taken by Ko-ghey founder of the i8th dynalfy ; upon which Jin-tfong engaged to pay them an annual tri- bute of 200,000 taels of filvcr, and 300,000 pieces of filk in lieu of thefe chics. 13 From this time, the Kitan remained in peaceable K'tan "^""i- pofieflion of their Chinefe dominions till the.year 1 117. ^'j^" eaflerii. Whey-tfong, at that time emperor, being able nti- Xii-urs. ther to bear their ravages, nor by himfeif to put a flop to them, refolved upon a remedy which at laft proved worfe than the difeafe. This was to call in the Niitfhe, Nyu-che, or Eaftern Tartars, to deftroy the kingdom of the Kitan. 'From this he was diffua- ded by the king of Korea, and mod of his own mini- llers ; but, difregarding their falutary advice, he join- ed his forces to thofe of the Nu-che. The Kitan were then every where defeated ; and at lad reduced to fuch extremity, that thofe who remained were forced to leave their country, and fly to the mountains of the wed. _ 14 Thus the empire of the Kitan w-as totally deftroyed, Who but nothing to the advantage of the Chinefe ; for the Tartar general, elated with his conqued, gave ^^^^^^^&i\d name of Kin to his new dominion, aifumed the title ofjnvaJeChi* emperor, and began to think of aggrandizing him- na. felf and enlarging his empire. For this purpofe, he immediately broke the treaties concluded with the Chinefe emperor ; and, invading the provinces of Pe- che-li and Shen-fi, made himfeif mader of the greater part of them. Whey-tfong, finding himfeif In danger of lofmg his dominions, made feveral advantageous propofals to the Tartar ; who, feeming to comply with them, invited him to come and fettle matters by a perfonal conference. The Chinefe monarch com- plied : but, on his return, the terms agreed on feemed intolerable to his miniders ; fo that they told him the treaty could not fubfid, and that the mod cruel war was preferable to fuch an ignominious peace. Tne Kin monarch, being informed of all that pafl"<;d, had recourfe to arms, and took feveral cities. Whey- tfong was weak enough to go in perfon to hold a fe- cond conference ; but, on his arrival, was immediate- ly fcized by the Tartar. He was kept prifoner un- They take der a llrong guard during the remaining part of his the cmpe- hfe ; and ended his days in 11 26, in the defert of '""'^ P^'^^'^* Shamo, having nominated his elded fon Kin-tfong to^''* fucceed him. Kin-tfong began his reign with putting to death fix miniders of ftate, who had betrayed his father into the hands of the Kin Tartars. The barbarians in the mean time purfued their conquefts without oppo- fition. Tliey croffed the Whang-ho, or Ycllov/ River, which an handful of troops might have prevented ; and marching direftiy towards the imperial city, took and i.-jiperial d- plundered it. Then f^ilzlng the em.peror and his con- ty and &no- fort, they carried them away captives : but many of '^itr empe» the principal lords, and feveral of the minliters, prefer- ring death to fuch an ig*ominIou': bondage, killed them- felves. Tne Kin being informed by the emprefs Meng that die had been divorced, they left her be- hind. This proved th? meaa^ of favlng the empire ; for CHI [6 eiiina. for by her wifdom and prudence llie got the crown placed on the head of Kau-tfong, ninth fou of the em- peror Whey- tfong by his divorced emprefs. Kau-tfong fixed his court at Nauking the capital of Kyaiig-nan ; but foon after was obliged to remove it to Kang-chew in Che-kyang. He made feveral ef- forts to recover fome of his provincs from the Kin, but without effeft. lU tfong the Kin monarch, in the mean time, endeavoured to gain the efteem of hid Chinefe fubjtfts by paying a regard to their learning and learned men, and honouring the memory of Con- fucius. Some time after, he advanced to Nanking, from whence Kau-tfong liad retired, and took it : but, receiving advice that Yo-fi, general of the Song, or fouthern Chinefe, was advancing by long marches to I? the relief of that city, they fet fire to the palace, and ^''"^^F^® retired northward. However, Yo-li arrived time checked. enough to fall upon their rear-guard, which fufiFered very much ; and from this time the Kin never dared to crofs the river Kyang. In a few years afterwards the Chinefe emperor fubmitted to become tributary to the Kin, and concluded a peace with them upon very ^ diihonourable terms. This fubmiffion, however, was of little avail: for, in 1163, the Tartars broke the peace ; and, in^'adir^g the fouthern province with a for- midable army, took the city of Yang-chew. The king, having approached the river Kyang, near ils mouth, where it is widelt as well as moft rapid, com- manded his troops to crofs it, threatening with his drawn fword to kill thofe who refufed. On recei- ving fuch an unreafonable command, the whole ar- my mutinied; and the king being killed in the be- ginning of the tumiJt, the army -immediately reti- 18 They are From this time to the year 1 2 ro, nothing remark- et tacked by able occurs in the Chinefe hiilory ; but this year, Tenghiz- Jenghiz-khan, chief of the weftern Tartars, Moguls, the "kl "^'^of ^^^S^^') quarrelled with Yong-tfi emperor of the Hya. ^ K'" ; 3nd at- the fame time the king of Hya, difgufted at being refufed affiftance againft Jenghiz-khan, threat- ened him with an invafion on the welt fide. Yong-tfi prepared for his defence ; but in 121 i, receiving news that Jenghiz-khan was advancing fouthward with his whole army, he was feized with fear, and made pro- pofals of peact, which were rejected. In T212, the Great w?.ll Mogul generals forced the great wall ; or, according to forcedby {^^^ writers, had one of the gates treacheroufly open- kh-m ^'^ them, to the north of Shanfi ; and made incur- I * fions as far as Peking the capital of the Kin empire. At the fame time the province of Lyau-tong was al- moft totally reduced by feverah KItan lords who had joined Jenghiz-khan ; feveral ftrong places were ta- ken, and an army of 300,000 Kin defeated by the Mo- guls. In autumn they laid fiege to the city of Tay. tong-fu ; where, although the governor Hujaku fled, yet Jenghiz-khan met with confiderable refiftance. Having loft a vaft number of men, and being himfelf wounded by an arrow, he was obhged to raife the fiege and retire intoTartary; after which the Kin re- took feveral cities. The next year, however, Jeng- hiz-khan re-entered China ; retook the cities which the Kin had reduced the year before ; and overthrew their armies in two bloody battles, in one of which the ground was ftrewcd with dead bodies for upwards cf fo.ur leagues. J) J China. 20 ] CHI The fame year Yong-tfi was flain by his general Hujaku ; and Sun, a prince of the blood, advanced in his room. After this the Moguls, attacking the empire with four armies at once, laid waile the provinces of Shanfi, Honan, Pecheli, and Shantong. In 12 14 Jeng- hiz-khan fat down before Peking ; but inftead of af- faulting the city, offered terms of peace, which were accepted, and the, Moguls retired into Tartary. After their departure, the emperor, leaving his fon at Pe- king, removed his court to Py*?n-lyang near Kay- fong-fu, the capital of Honan. At this Jenghiz-khan being offended, immediately fent troops to befiege Pe- king. The city held out to the fifth month of the year^^^^^^^ 1215, and then furrendcred. At the fame time the Moguls finilhed the conqueft of Lyau-tong ; and the Song refufed to pay the ufual tribute to the Kin. In 1216, Jenghiz-khan returned to purfue his con- quefis in the weft of Afia, .where he ftaid feven years; during which time his general Muhuli made great progrefs in China againft the Kin emperor. He was ai greatly aflifted by the motions of Ning-tfong ^'^P^*"°^^'^|j"|^gfg"j^g of the Song, or fouthern China; who, incenfed by the^iJ^^ frequent perfidies of the Kin, had declared war againft a^ainll the them, and would hearken to no terms of peace, though Kin. very advantageous propofals were made. Notwith- ftanding this, however, in 1220, the Kin, exerting tliemfelves, raifed two great armies, one in Shenfi, and the other in Shang-ton. The former bafHed the attempts of the Song and king of Hya, who had united ' againft them ; but the latter, though no fewer than 200,000, were entirely defeated by Muhuh. In 1221, that officer pafTed the Whang-ho, and died after con- quering feveral cities. j2 ■ In 1224, the Kin emperor died ; and was fucceeded Jcnghiz- by his fon Shew, who made peace with the king of U^an de- Hya : but next year, that kingdom was entirely de- j^-"^"^,},,^^^ r ftroyed fby Jenghiz-khan. In 1226, Oktay fon to j^ya ; Jenghiz-Khan marched into Honan, and befieged Kay- Song-fu, capital of the Kin empire ; but was obliged to withdr aw into Shenfi, where he took feveral cities, and cut in pieces an army of 30,000 men. ' In 1227 Jeng- hiz-khan died, after having delired his fons to demaml And dies, a paffage for their army through the dominions of the Song, without which he faid they could not eafily van- qulfh the Kin. After the death of that great conqueror, the war was carried on with variouB fuccefs ; but though the Moguls took above 60 important pods in the province of Shenfi, they found it impoffible to force Tong-quan, which it behoved them to do in order to penetrate effec- tually into Honan. In April 1 23 i they took the capi- tal of Shenfi, and defeated the Kin army which came to its relief. Here one of the officers dcfired prince Toley to demand a paffage from the Song through the country of Han chong-fn. This- propofal Toley communicated to hie brother Oktay, who approved of it a& being conformable to the dying advice of Jeng- hiz-khan. Hereupon Toley, having afTtmbled all his forces, fent a meffenger to the Song generals to de- jylyguu maud a paflage through their territories. This, how- quarrel ever, they not only refufed, but put the meffenger to ^'f^^ *^^<^ death; which fo enraged Toley that he fvrore to^°'*^' make them repent of it, and was foon as good as his 25 word. He decamped in Angufl 1231 ; and having for- ced th^; p&fTagej, p'lt to the fword the iahabitauts of " Wha. C'l-,ina. 16 Capital of the Kin em pire be- fieged. CHI [65 \^'Tia-yang and Fong-chew, two cities in tVe di{lri£l of Han-chong fii. Then having cut down rocks to fill up deep abylTes, and made roads through places almoll inaccefilble, he came and bdleged the city of Han-ehong-fii itfelf. The miferable inhabicants fled to the mountains on his approach, and more than J 00, coo of them periflied. After this, Tclcy divided his forces, confiiling of 30,000 horfe, into two bodies. One of thei'e went v/ellwaid to Mycn-chew : from thence, after opening the paffages of the mountains, they arrived at the river Kyaling, which runs into the great Kyang. This they rroffed on rafts made of the wood of demoIiChed houfes ; and then, march- ing along its banks, feized many important pods. Ac lad, having deflroyed more than 140 cities, towns, or fortreffcs, thuy returned to the army. Tlie fecond detachment feized an important pod in the mountain?, called Ttiutong, fix or feven leagues to the eaftward of Han-chong-fu. On the other fide Oktay advanced, in Oftober, towards Pu-chew a city of Shan-fi ; which being taken after a vigorous defence, he prepared to pafs the Whang-ho. Toley, after furmounting incre- dible difficulties, arrived in December on the borders of Honan, and made a fliew as if he defigned to at- tack the capital of the Kin empire.' On his firll ap- pearance in Honan through a pafTagc fo little fufpeft- ed, every body was filled with terror and adonifh- ment, fo that he proceeded for fome time without oppofition. At lad the emperor ordered his generals, Hota, Ilapua, and others, tp march againft the enemy. Toley boldly attacked them ; but was obliged to retire, ■which he did in good order. Hota was for purfuing him, faying that the Mogul arm.y did not exceed 30,000 men, and that they feemed not to have eaten any thing for two or three days. Ilapua, however, was of opinion that there was no occafion for being fo hafty, as the Moguls were inclofed between the rivers Han and Whang-ho, fo that they could not efcape. This negligence they foon had occafion to re- pent of ; for Toley, by a ftratagem, made himfelf rnafler of their teavy baggage; which accident ob- liged them to retire to Tang chew. From thence they fent a meffenger to acquaint the emperor that they had gained the battle, but concealed the lofs of their baggage. This good news filled the court with joy ; and the people who had retired into the capital for its defence, left it again, and went into the coun- try : but, in a few days after, the vanguard of the Mo- guls, who had been fent by the emperor Oktay, appear- ed in the field, and carried off a great number of thofe that had quitted the city. In January 1232, Oktay paffing the Whang-ho, en- ^mped in the didrift of Kay fong-fn, capital of the ICin empire, and fsnt his general Suputay to befiege the city. At that time the place was near 30 miles in circumference : but having only 40,000 foldiers to defend it, as many more fronj the neighbouring cities, and 20,000 peafants, were ordered into it ; while the emperor publifhed an affefting declaration, animating the people to defend it to the lad: extremity. Oktay, having heard with joy of Toley's entrance into Ho- nan, ordered him to fend fuccours to Supniay. On the other hand, the Kin generals advanced with 150,000 men to relieve the city ; but being obliged to divide their forces in order to avoid in part the great road 6 ] * C H I which Toley had obflrufted with trees, they were China. attacked by that prince at a difadvantage, and, after v— «^ a faint rtfiitance, defeated witli great flaugliter, and the lofs of both their generals, one killed and the other taken. The emoeror now ordered ihe army at Tong-quan and other fortified places to march to the relief of Kay-fong-fu, They affembled accordingly," to the number of 110,000 foot and 15,000 liorie ; and were followed by vad numbers of people wlio expeftcd by their means to be protected from the enemy. But many of thefe troops having deferted, and the red being enfeebled by the fatigues of their march, they difperfed on the approach of their pur- fuers, v.'ho killed all they found in the highways. Af- ter this the Moguls took Tong-quan and fome other confiderable pods ; but were obliged to raife the fieges of Quey-te-fu and Loyang, by the bravery of the go- vernors. Kyang-fliin, governor of Loyang, had only 3 or 4000 ioldiers under him, while his enemies were 30,000 ilrong. He placed his word foldiers on the walls, putting himfelf at the head of 400 brave men ; whom he ordered to go naked, and whom he led to all dangerous attacks. He invented engines to call large doned, which required but few hands to play them, and aimed fo true as to hit at 100 pace.? dif- tance. When their arrows failed, he cut thofe fliot by the enemy into four pieces ; pointed them with pieciis of brafs coin; and difcharged them from wooden tubes with as much force as bullets are from a muflcet. Thus he haraffid the Moguls for three months fo gvie- voufly, .that they were obliged, notwithdanding. their numbers, to abandon the enterprize. Oktay, at lad, notwithflanding his fuccedls, refol- B-avcry of ved to return to Tartary ; and offei-ed the Kin empe- the belieg. ror peace, provided he became tributary, and deli- vered up to him 27 families which he named. Thefe offers were very agreeable to the emperor; but Suputay, taking no notice of the treaty, puflied on the fiegc of the capital with more vigour than ever. By the help of the Chinefe flaves in his army, the Mogul general foon filled the ditch ; but all his effrrts fecmcd only to infpire the beficged with new vigour. The Mogul.; at that time made ufe of artillery, but were unable to make the lead irupreffion upon the city walls. Thty raifed walls round thofe they befiegcd, which they fortified with ditches, towers, and battlements. They proceeded alfo to fap the walls of the city ; but were very much annoyed by the artillery of the befiegcd, efpecially by their bombs, which finking into the gal- leries, and burding under ground, made great havock among the miners. For 16 days and nights the at- tacks continued without intermiffion ; during which time an incredible number of men periflud on both fides r at length, Suputay, finding that he could a8 not take the city, withdrew his troops, under pretence P^a^^^e con- of conferences being on foot. Soon after, the plat^ue » bi^gan in Kay-fong-fu ; and raged with fuch violence, that, in 50 days, 900,000 biers were carried out, be- fides a valt multitude of the poorer fort who could not afford any. In a fhort time, two unlucky accidents occafioned a And bro- renewal of the war ; which now put an end to the^^"' empire of the Kin. Gan-yong, a young Mogul lord, having afliimed the government of fome cities in Kyang-nan, and killed the officer fent to take poffef- fjon China, L 6 «g«in 1 c- ficged, C II I fion of them, declared for ilie Kin. The emperor unwarily took Gan-yong into his fervice, and gave him the title of P, irujc. Upon this Oktay feiit an en- voy, attended by oiher perfons, to in((uire into the affair; hut the Kin cfacer,-i -killed them al', without being puniflied by the emperor. Suputay, having in- formed hh mailer of all thefe proceedings, was or- dered to continue the war in Honan. Shew- fa now commanded his officers to unite their troops for the defence of the capital ; but before his orders could be obeyed, they were attacked and defeated, one after another, by the Moguls. This obliged him to raife foldiers from among the peafants, for whofe fubfill- ence the people were taxed ,V of the rice they pof- fefled. The city began now to be diftreffed for want of prov^ifions ; and as it was but in a bad pollure of deftncc, the emperor marched with an army againll the Moguls. His expedition proved unfortunate ; for, fending part of his army to befiege a city called Why- chew, it was totally cut in pieces, and Suputay a fe- cond time fat down before the capital. On hearing this bad news, the emperor repaffed And taken the Whang-ho, and retired to Quey-te-fu. Here he had not been long before the capital was delivered up by treachery, and Suputay put all the males of the imperial race to death ; but, by the exprefs command of Oktay, fpared the inhabitants, who are faid to have amounted to 1,400,000 famihes. After this difaiter 3Z the unhappy monarch left his troops at Quey-te-fu, lumne fu ^"'^ J^^''"'^^ Juning-fu, a city in the fouthern part -» 6 • of Honan, attended only by 400 perfons. Here the dilla nee of the Moguls made him think of living at eafe ; but while he flattered himfelf with thefe vain hopes, the enemy's aimy arrived before the city and invefted it. The garrifon were terrified at their ap- ptoach ; but were encouraged by the emperor, and his brave general Flu-fye-hu, to hold out to the lait. As there were not in the city a fufficient number of men, the women, di-efhd in mens clothes, were emph>yed to carry wood, iiones, and other necefiary materials to the walls. AH their efforts, however, were ineffec- tual. They were reduced to fuch extremities, that for three months they fed on human flcfh 5 kilhng the old and feeble, as well as many prifoners, for food. This being known to the Moguls, they made a general aifault in January 1234. The attack continued from monnng till night; but at laft the affailancs were re- pulfed. _ In this action, however, the Xin loft all their belt ofiicers ; upon which the emperor rel:gned the crown to Cheng-hn a. prince of the blood. Next morn- ing, while the ceremony of inveiling the new em- peror was performifig, the enemy mounted the fouth vvdils, which were defended only by 2oo men 5 and the iouth gate befng at the fame time abandoned, the whole army broke in. They were oppofcd, how- ever, by Hu-fj'c-hu ; who, with 1000 foldiers, conti- rued to light with amazing intiepidity. In the mean time Shew fu, feeing every thing irreparably loil, lodged tlie feal of the empire in a houle ; and then cauting fiieaves of llraw to be fet round it, ordered it to be fet on fire as foon as he was dead. After giving this order be hanged himfelf, and his commands were e-xecuted by h.s domeftics. Hu-fye-hu, who flill con- tinued fighting with great bravery, no fooner heard of the tragical death of the emperor, than he drowu- VoL. IV. Pan IT, ?Tiihappy fate of the cnjperor. 57 ] , CHI ed himfelf in the river Ju ; as'did alfo 500 of Iiis mofl China. refolute foldieis. The fame day the new emperor, ^— —* Cheng-lin, was flaiu in a tumult ; and thus an end was ^ put to the domini vn of the Kin Tartars in China. of theTu The empire of China was now to he fiiared between empire, the Song, or fouthern Chiuefe, and the Moguls. It had been agreed upon,, that the province of Honan fiiould be dchvered up to the Songas foon as the war was finiflied. But they, without waiting for the expira- tion of the term, or giving Oktay notice of their pro- ceedings, introduced their troops into Kay-fong-fu, 35^ Lo-yang, and other confiderable cities. On this the '^^'^^ '^e- Mogul general refolved to attack them; and repaffing J,'^"" ^''^ the Whang-ho, cut in pieces part of the garrifon of th" Ylo- Lo-yang, while they were out in fearch of provilions. guls. The garrifon of Kay-fong-fu likewife abandoned that place ; and the Song emperor degraded the olHcers who had been guilty of thofe irregularities, fending ambafTadors to Oktay, at the fame time, to defire a continuance of the peace. What Oktay's anfwer was we are not told, but the event fhowed that he was not well pleafed; for, in 1235, he ordered his fecond fon prince_ Kotovan, and his general Chahay, to attack the Song in Se-chwen, while others marched towards the borders of Kyang-nan. In 1236, the Moguls made great progrefs in the province of Huquang, where they took feveral cities^ and put vail numbers to the fword. This year they introduced paper or fi!k money, which had -formerly been ufed by Chang-tfong, fixth empSror of the Kin. Prince Kotovan forced the paffages into the dillrift of Hang-chong-fu in the province of Shenfi, whicli he 56 entered with an army of 500,000 men. Here a ter- Dreadful riBIe battle was fought between the vaft army of che Moguls and the Chinefe troops, who had been driven ■ from the paffages they defended. The latter con- filled only of 10,000 horfe and foot, who were almoit entirely cut off ; and the Moguls loft fuch a number of men, that the blood is faid to have run for two leagues together. After this viftory the Moguls en- tered Sechwen, which they almoil entirely reduced, committing fuch barbarities, that, in one city, 40,000 people chofe rather to put an end to their own lives ■than fubmit to fuch cruel conquerors. In 1237, the Moguls received a confiderable check before the city of Gantong in Kyang-nan, the fiege of which they were obliged to raife with lofs. In 1238 they befieged Lu-chcw, another city in the fame pro- vince. They furroundcd it with a rampart of eaith and a double ditch ; but the Chinefe general ordered Iheir intrenchments to be filled with immenfe quan* titles of herbs lleeped in oil, and then fet on fire while he fhot ftones upon them from a tower feven ftories high. At the fame time a vigorous fally was made ; and the Mogul army being thrown into the utmoll diiorder, were obliged finally to abandon the liege, and retire nortlmards. . In 1239, thefe barbaritins were oppofed by a o-e neral called Meng-kong, with great luccefs; who, this and the following year, gained great honour by his exploits. While he hved, the Moguls were never able to make any confiderable progrefs; but his death^ in I 246, proved of the greateit detriment to the Chi- nefe afiairs : and foon after, the Tartars renewed the war with more vigour and fuccefs than ever. In 4 O ChJn*. 37 Siege of Ho-chew. Moguls de- fcdtcd, and tJjeir enipe. Eor killed. 39 Treachery of a Chi- «efe mini- iler. CHI [ 658 ] 1255, tliey re-entered the province of Se-chwen ; but fail to prcdvice a ftill met with vigorous oppoTition in this quarter, be- caufe the Chincfe took care to have Se-chwen funiifla- ed with good troops and generals. Though they were always beaten, being greatly inferior in number to their enemies, yet they generally retook the cities the Moguls had reduced, as the latter were commonly obliged to withdraw for want of provifions and fo- rage. In 1 259 they undertook the fifge of Ho-chew, a ftrong city to the \yeft of Peking, defended by Vang- kyen, a very able "officer, who commanded a nume- rous garrifon. The fiege continued from the month of February till Auguft ; during which time the Mo- guls loft an immenfe number of men. On the loth of Auguft they made a general affault in the night. They mounted the walls before the governor had in- telligence ; but were foon attacked by him with the utmoft fury. The Mogul emperor, Meng-ko, him- felf came to the fcalade ; but his prefence was not fufficient to overcome the valour of Vang-kyen. At " the fame time the fcaling-ladders of the Moguls were blown down by a ftorm ; upon which a terrible flaugh- " ter enfued, and amongft the reft fell the emperor him- felf. Upon this difafter the Mogul generals agreed to raife the fiege, and retire towards Shen-fi. On the death of Meng-ko, Hupilay, orKublay Khan, who fucceeded him, laid fiege to Vu-chang-fu, a city not far diftant from the capital of the Song empire. At this the emperor being greatly alarmed, diftribu- ted immenfe fums among his. troops; and, having raifed a formidable army, marched to the relief of Vu-chang-fu. Unfortunately the command of this army was com- mitted to the care of Kya-tfe-tau, a man without either courage or experience in war. He was befides very vain and vindiftive in his temper; often ufmg the beft officers ill, and entirely overlooking their me- rit, which caufed many of them to go over to the Moguls. The fiege of Vu-chang-fu was commenced, aud'had continued a confiderable time, when Kya-tfe- tau, afraid of its being loft, and at the fame time not daring to take any eftedual ftep for its rehef, made propofals of peace. A treaty was accordingly con- cluded, by which Kya-tfe-tau engaged to pay an an- nual tribute of about L. 50,000 in filver, and as much in filk; acknowledging Hkewife the fovereignty of the Moguls over the Song empire. In confequence o{ this treaty, the Moguls retreated after the boundaries of the two empires had been fixed, and repaifed the Kyang ; but 1 70 of them having ftaid on the other fide of the river, were put to death by Kya-tfe-tau. This wacked minifter totally concealed from the emperor his having made fuch a fhameful treaty with the Moguls ; and the 170 foldiers maffacred by his order, gave occafion to a report that the enemy had been defeated ; fo that the Song court believed that they had been compelled to retreat by the fuperior valour and wifdom of Kya-tfe-tau. This proved the ruin of the empire ; for, in 1260, the Mogul empe- ror fent H^uking to the Chinefe court to execute the treaty according to the terms agreed on with Kya- tfe-tau. The minifter, dreading the arrival of this envoy, imprifoned him near Nanking ; and took all poffihle care that neither Hupilay, iwr Li-tfong the Chinefe emperor, ftiould ever hear any thing of him. It was impoflible fuch unparalleled condu*^ conld China. 4* C H I r V ar. Hupilay's covutfers in- ceffantly preffed him to revenge himfelf on the Song for their treacherous behaviour ; and he foon pubhlh- ed a manifetlo againft them, which was followed by a renewal of hoftihties in 1268. The Mogul army amounted to 300,000 men; but notwithftanding their numbers, httle progrefs was made till the year 1271. Syan-yang and Fan-ching, cities in the province of Se- chew, had been befieged for a long time ineffectually ; but this year an Igur lord advifed Hupilay to fend for feveval of thofe engineers out of the weft, who knew how to caft ftones of 150 pounds weight out of their engines, which made holes of feven or eight feet wide in the ftrongett walls. Two of thefe engineers were accordingly fent for ; and after giving a fpecimen of their art before Hupilay, were fent to the army ia 1272. In the beginning of 1273 they planted their engines againft the city of Fan-ching, and prefently made a breach in the walls. After a bloody conflict the fuburbs were taken ; and foon after the Moguls made themfelves mafters of the walls and gates of the city. Neverthelefs, a Chinefe officer, with only 100 foldiers, refolved to fight from ftreet to ftreet. /rhis ^^JP^^^^"*' he did for a long time with the greateft obftinacy, killing vaft numbers of the Moguls ; and both parties are faid to have been fo much overcome with thirft, that they drank human blood to quench it. The Chi- nefe fet fire to the houfes, that the great beams, fal- hng down, might embarrafs the way of their purfuers ; but at laft being quite wearied out, and filled with de- fpair, they put an end to theli own lives. After the taking of Fan-ching, all the materials which had fer- ved at the fiege were tranfported to Seyen-yang. The two engineers pofted themfelves againft a wood- en retrenchment raifed on the ramparts. This they quickly demolifhed ; and the befieged were fo inti- midated by the noife and havock made by the ftones caft from thcfe terrible engines, that they immediate- ly furrendered. In 1274, Pe-yen, an officer of great valour, and en- dowed with many other good qualities, was promoted to the command of the Mogul army. His firft ex- ploits were the taking of two ftrong cities ; after which he pafled the great river Ky-ang, defeated the Song army, and laid fiege to Vu-chang-fu. This city was foon intimidated into a furrender; and Pe-yen, by reftraining the barbarity of his foldiers, whom he would not allow to hurt any body, foon gained the hearts of the Chinefe fo much, that feveral cities fur- rendered to him on the firft fummons. In the mean time the treacherous Kya-tfe-tau, who was fent to op- pofe Pe-yen, was not alhamed to propofe peace on the terms he had formerly concluded with Hupilay ; but thefe being rejeded, he was obliged at length to come to an engagement. In this he _ was defeated, and Pe-yen continued his conquefts with great rapi- dity. Having taken the city of Nanking, and fome others, he marched towards Hang-chew-fu, the capi- tal of the Song empire. Peace was now again pro- pofed, but rejeded by the Mogul general; and at laft Chinefe the emprefs was conftrained to put herfelf, with ^^r Emprefe fon, then an infant, into the hands of Pe-yen, who im- " mediately fent them to Hupilay. The fubmiffion of the emprefs did not yet put an tnd to the war. Many of the chief officers fwore to d© C H T [ 659 ] c H r 4a ^Diffolution of the Song ten'itories empire 4.'? 'Reign of Hupilay. do their vtmoft to refcue her from the hands of her enemies. In confequence of this refolution they dif- tributed their money among the foldiers, and foon got together an army of 40,000 men. This army at- tacked the city where tJae young emperor Kong- tfong was lodged, but without fuccefs ; after which, and feveral other vain attempts, they raifed one of his brothers to the throne, who then took upon him the name of Twon-tfong. He was but nine years of age when he was raifed to the imperial dignity, and enjoyed it but a very fhort time. In 1277 he was in great danger of peri filing, by reafon of the fhip on board which he then was being call away. The poor prince fell into the water, and was taken up half dead with the fright. A great part of his troops pe- rifhed at that time, and he foon after made offers of fubmilTion to Hupilay. Thefe, however, were not accepted; for, in 1278, the unhappy Twon-tfong was obliged to retire into a little defertilland on the coaftof Quang-tong, where'he died in the 1 1 th year of his age. Notwithitanding the progrefs of the Moguls, vail ftill remained to be fubdued before they could become matters of ail the Chinefe empire. On the death of Twon-tfong, therefore, the mandarins raifed to the throne his brother, named Te-ping, at that time but eight years of age. His ai-my confifted of no fewer than 200,000 men ; but being utterly void of difcipline, and entirely ignorant of the art of war, they were defeated by 20,000 Mogul troops. Nor was the fleet more fuccefsful ; for being put in con- fufion by that of the Moguls, and the emperor in dan- ger of falling into their hands, one of the officers ta- king him on his flioulders, jumped with him into the fea, where they were both drowned. Moft of the mandarins followed this example, as did alfo the em- prefs and miniffer, all the ladies and maids of honour, and multitudes of others, infomuch that 100,000 people are thought to have perifhed on that day Thus end- ed the Chinefe race of emperors ; and the Mogul dy- nafty, known by the name of Twen, commenced. Though no race of men that ever exifted were more remarkable for cruelty and barbarity than the Moguls ; yet it doth not appear that the emperors of the Ywen dynafty were in any refpeft worfe than their predeceffors. On the contrary, Hupilay, by the Chinefe called S/n-tfu, found the way of reconciling the people to his government, and even of endearing himfelf to them fo much, that the reign of his family is to this day ftyled by the Ch.\n&{& the wife govern- ment. This he accompllffied by keeping as clofe as poflible to their ancient laws and cuffoms, by his mild and juft government, and by his regard for their learned men. He was indeed afhamed of the igno- rance and barbarity of his Mogul fubjedls, when com- pared with the Chinefe. The whole knowledge of the former was fummed up in their ikill in managing their arms and horfes, being perfeftly deftitute of every art or fcience, or even of the knowledge of betters. In 1269, he had caufed the Mogul charac- ters to be contrived. In 1280, he caufed fome mathe- maticians fearch for the fource of the river Whang-ho, which at that time was unknown to the Chinefe them- felves. In four months time they arrived in the cou^itry where it rifes, and made a map of it, which X they prefented to his majefty. The fame year a trea- China, tife on aflronomy was publifhed by his order ; and, in 1282, he ordered the learned men to repair from all parts of the empire to examine the ftate of literature, and take mealures for its advancement. At his firtt acceffion to the crown he fixed his refi- fidence at Tay-ywen-fu, the capital of Shen-fi ; but thought proper afterwards to remove it to Peking. Here, being informed that the barks which brought to court the tribute of the fouthem provinces, or car- ried on the trade of the empire, were obliged to come by fea, and often fuffered Ihipwreck, he caufed that celebrated canal to be made, which is at prefcnt one of the wonders of the Chinefe empire, being 300 leagues in length. By this canal above 9000 imperial barks tranfport with eafe, and at fmall expence, the tri- bute of grain, rice, filks, iffc. which is annually paid to the court. In the third year of his reign Shi-tfu formed a defign of reducing the iflands of Japan, and the kingdoms of Tonkquin and Cochin-china. Beth thefe enterprifes ended unfortunately, but the iiril remarkably fo ; for of 100,000 perfons employed in it, only four or five efcaped with the melancholy news of the deilruftion of the reft, who all perirtied by (hip- wreck. Shi-tfu reigned 15 years, died in the 80th year 44 of his age, and was fucceeded by his grandfon. The Moguls dri- throne continued in the Ywen family till the year 1367, ^"^"^ when Shun-ti, the laft of that dynafty, was driven out by a Chinefe named Chu. During this period the Tartars had become enervated by long profperity ; and the Chinefe had been roufed into valour by their fubjeftion. Shun-ti, the reigning prince, was quite funk in floth and debauchery ; and the empire, befides, was oppreffed by a wicked minifter named Ama. In Expioits of June 1355, Chu, a Chinefe of mean extraction, and Chu. head of a fmaU party, fet out from How-chew, paffed the Kyang, and took Tay-ping. He then affociated himfelf with fome other malcontents, at the head of whom he reduced the town of Tu-chew, in Kyano-- nan. Soon after he made himfelf mafter of Nanking, having defeated the Moguls who came to its relief. In December 1356, he was able to raife 100,000 men, at the head of whom he took the city of U-chew, in the eaft borders of Quang-fi ; and here, affembling his generals, it was refoived neither to commit Haughters nor to plunder. The moft formidable enemy he had to deal with was Cben-yeiv-lyangy ftyled " emperor of the Han." This man being grieved at the progrefs made by Chu, equipped a fleet, and raifed a formi- dable army, in order to reduce Nan-chang-fu, a city of Kyang-fi, which, his antagonift had made himfelf mafter of. The governor, however, found means ' to inform Chu of his danger ; upon which that chief caufed a fleet to be fitted out at Nanking, in which he embarked 200,000 foldiers. As foon as Chen-yew- lyang was informed of his enemy's approach, he raifed the fiege of Nan-chang-fu, and gave orders for at- tacking Chu's naval force. An engagement enfued between a part of the fleets, in which Chu proved viftorious ; and next day, all the fquadrons having joined in order to come to a general engagement, Chu gained a fecond viftory, and burnt 100 of the enemy's veffels. A third and fourth engagement hap- pened, in both which Chu gained the viftory ; and iii z the CHI China. 46 He is pru- c.P.imetl kins of U. [ 660 ] C H I 47 Becomes empeio; of China. 48 Moguls driven be- yend the defert. 49 China a- gain con- quered by the Tartars the laft, Chen-yew-lyang himfelf was killed, his fon taken prifoner, and his generals obliged to furrender themfelves, with all their forces and veffels. In January 1364, Cliu's generals propofed to have him proclaimed emperor ; but this he declined, and at firll contented himfelf with the title of king of U. In February he made himfelf mailer of Vu-chang-fu, capital of Hu-quang ; where, with bis ufual humanity, he relieved thofe in dillrefs, encouTaged the literati, and would allow his troops neither to plunder nor de- ftroy. This wife conduft procured him an eafy con- queft both of Kyang-fi and Hu-quang. The Chinefe fubmitted to him in crowds, and profelfed the greateft veneration and refpeft for his perfon and govern- ment. All this time Shun-ti, with an unaccountable negli- gence, never thought of exerting himfelf againft Chu, but continued to employ his forces againft the rebels w^ho had taken up arms in various parts of the empire ; fo that Chu found himfelf in a condition to affume the title of emperor. This he chofe to do at Nanking on the hrft day of the year 1368. After this his troops entered the province of Honan, which they prefently reduced. In the third month, Chu, who had now taken the title of Hong-uu., or Tay tfu, reduced the fortrefs of Tong-quan ; after which his troops entered Pecheli from Honan on the one fide, and Shan-tong on the otlier. Here his generals defeated and killed one of Shun-ti's officers; after which they took the city of Tong-chew, and then prepared to attack the capi- tal, from which they were now but 12 miles diftant. On their approach the empei-or fled with all his family beyond the great wall, and thus put an end to the dy- nalty of YvsTcn. In 1370 he died, and was fucceeded by his fon, whom the fucceffor of Hong-vu drove be- yond the Kobi or Great Defert, which feparates China from Tartary. They continued their incurfions, how- ever, for many years ; nor did they ceafe their at- tempts till 1583, when vaft numbers of them were cut in pieces by the Chinefe troops. The 2 1 It dynafty of Chinefe emperors, founded in 1368 by Chu, continued till the year 1644, when they were again expelled* by the Tartars. The laft Chinefe emperor was named Whay-tfong, and afcended the throne in 1628. He was a great lover of the fciences, and a favourer of the Chriftians ; though much addifted to the fuperftitions of the Bonzes. He found himfelf engaged in a war with the Tartars, and a pum.ber of rebels in different provinces. That he inight more efFeAually fupprcfs the latter, he refolved to make peace with the former ; and for that end fent one of his generals, named Tweny into Tartary, at the head of an army, with full power to negociate a peace ; but that traitor made one upon fuch fhameful terms, that the emperor refufed to ratify it. Ywen, in order to oblige his mafter to comply with the terms made by himfelf, poifoned his beft and molt faithful general, named Mau-ven-long ; and then dcfired the Tartars to march diredlly to Peking, by a road dif- ferent from that which he took with his army. This they accordingly did, and laid fiege to the capital. Ywen was ordered to come to its relief ; but, on his arrival, was put to the torture and ftrangled; of which the Tartars were no fooner informed, than they raifed the fiege, and returned to their own country. In 163 6, the rebels above-mentioned compofed four great ar- China, mies, commanded by as many generals ; which, how- -v— ever, were foon reduced to two, commanded by Li and Chang. Thefe agreed to divide the empire be- tween them ; Chang taking the weftern provinces, and Li the eaftern ones. The latter feized on part of Shen-fi, and then of Honan, whofe capital, named Kay-fong-fu, he laid fiege to, but was repulfed with, lois. He renewed- it fix months after, but without fuccefs; thebefieged choofing rather to feed on human flefii than furrender. The Imperial forces coming foon after to its affiftance, the general made no doubt of being able to deftroy the rebels at once, by break- ing down the banks of the Ytllow kiver ; but unfor- tunately the rebels efcaped to the mountains, while the city was quite overflowed, and 300,000 of the in- habitants peril'hed. After this difaftar, Li marched into the provinces of Shen-fi and Honan ; where he put to death all the naandarins, exaded great fums from the oflicers in place, and fliowcd no favour to any but the populace, whom he freed from all taxes: by this means he drew fo many to hisinterert, that he thought himfelf ftrong enough to afllime the title of emi)eror. He next ad- vanced towards the capital, which, though well gar- rifoned, was divided into fattions^ Li had taken care to introduce before-hand a number of his men in dif- guife ; and by thefe the gates were opened to him the third day after his arrival. He entered the city in Unhappy triumph at the head of 300,000 men ; whilft the eirv- fate of the- peror kept himfelf Ihut up in his palace, buficd only emperor with his fuperftitions. It was not long, however, be- ^".'.^ '^'^ fore he found himfelf betrayed : and, under the great- eft confternation, made an effort to get out of the pa- lace, attended by about 600 of his guards. He was ftill more furprifed to fee himfelf treacheroufly aban- doned by them, and deprived of all hopes of efcaping the infults of his fubjefts. Upon this, preferring death to the difgrace of falhng alive into their hands, he im- mediately retired with his em>prefs, whom he tenderly loved, and the princefs her daughter, into a private part of the garden. His grief was fo great that he was not able to utter a word ; but fhe foon underftood his meaning-, and, after a few filent embraces, hanged herfelf on a tree in a filken ftring. Her hufband liaid only to write thefe words on the border of his veil : *' I have been bafely deferted by my fubjefts ; do what you will with me, but fpare my people." He then cut off the young princefs's head with one ftroke of his fcymitar, and hanged himfelf on another tree, in the 1 7th year of his reign, and 36th of his age. His^ prime minifter, queens, and eunuchs, followed his exam- ple ; and thus ended the Chinele monarchy, to give place to that of the Tartars, which hath continued ever lince. ^ It was fome time before the body of the unfortu- nate monarch was found. At laft it was brought be- fore the rebel Li, and by him ufed with the utmoft indignity ; after which he caufed two of Whey-tfong's. fons, and all his minifters, to be beheaded ; but his eldeft fon happily efcaped by flight. The whole empire- fubmitted peaceably to the ufurper, except prince U- fan-ghey, who commanded the imperial forces in the province of Lyau-tong. This^ brave prince, finding liimfelf unable to cope with the ufurper, invited the Tartars Ihlna. China. 53 Climate, SI np;e to Liy rcdu- CHI [ 66i ] CHI Tartars to his affiRance, and Tfong-te their king Im- The cllmalc as well as the foil of this extenfive em- mediately joined him with an army of 8o,ooo men. pire is very duTcrent in different parts ; fevere cold be- Upon this the ufurper marched directly to Peking; but ing often felt In the northern provinces, whuc tlie in- not thinking himfelf fafe there, plundered and burnt habitants of the foulhern ones are fcarce abie to bear foil, and the palace, and then fled with the Immenfe treafure the heat. In general, however, the air is accounted produce, he had got. What became of him afterwards we are wholefome, and the Inhabitants hve to a great age.— not told"; but the youn-r Tartar monarch was imme- The northern and wcftern provinces have many diately declared enipero'r of China, his father Tfong- mountains, which In the latter are cultivated,^ but te having died abnoit as foon as he fet his foot In that in the noith are barren, rocky, and incapable oi im- p.j -j-e. provement. On the mountains of Chcnfi, Honan, Caa- * The'new emperor, named Shun-cJA, or Xun-cl/i, be- ton, and Foklen, arc many forefts, abounding with tall, gan his reign with i 'w arding U-fan-ghey, by con- ftralght trees, of different kinds, fit for building, and fcrring upon hini the title of King ; and affigned him particularly adapted for mafts and fhlp-timbcr. Thefe the city of Si-guan-fu, capital of Shen-fi, for his refl- are ufed by the emperor in his private buildings ; and dence. This, however, did not hinder U-fan-ghey from thefe forefts enormous trunks are fometimer fi-om repenting of his error In calling In the Tartars, or, tranfported to the diftance of more than 300 leagues, as he himfelf ufed to phrafe It, " in fending for lions to Qthcr mountains contain quickfilver, iron, tin, copper,, drive away dogs." In 1674, he formed a very ftrong gold, and filver. Formerly thefe laft were not allowed alliance agalnfl them, and had probably prevailed if to be opened, left the people fhould thereby^ be in- Ms allies had been faithful ; but they treacheroufly duced to negleit the natural riches of the foil ; and dcfcrted him one after another:' whlcli fo affecled him, it is certain, that, in the 15th century, the emperor that he died foon after. In 1681 Ilong-wha, fon to caufed a mine of precious ftones to be fhut, which had U-fan-ghev, who continued his efforts againft the been opened by a private pcrfon. Of late, however, Tartars, was reduced to fuch ftralts that he put an the Chinefe are lefs fcrupulous, and a great 'trade m- end to Ills own life. gol-y The bafis of all the civil laws of the Chiriefe is fi- the bafis ofjj^j pj(,ty. Every mandarin, who is a governor either ^'1,?"*" of a province or city, muft Inftrud the people afTem- bled round him twice a-month, and recommend to them the obfervance of certain falut$iry rules, which are fummcd up in a few fliort fentences, and fuch as no perfon can ever be fuppofcd capable of forget- The Chinefe are allowed only to have one wife, whole rank and age muft be nearly equal to that of their huf- bands; but they are a'lowed to have feveral concubines, whom they mayadm.it into their houfes without any for- mality, after paying the parents a fum of money, and en- tering into a ivrltten engagement to ufe their daugh- ^rs well. Thefe concubines, however, are all in. fub- jeaion to the lawful wife ; their children are confider- ed as hers ; they addrefs her as mother, and can give this title to her only.. A ptrfon that has once been married, whether man or woman, may lawfully marry again, but it is then no longer neceffary to itudy e- quality of age or condition. A man may chooie his fecond wife from among his concubines; and, in all cafes, this new marriage requires very few formalities. A widow is abfolute miftrefs of herfelf, and can nei- ther be compelled by her parents to many again, nor to continue in a ftate of widowhood, contrary to her own inclination. Thofe of moderate rank, hovyever, who have no children, do not enjoy the fame privilege ; as the parents of the former hulband can difpoft of her in marriage, not only without her coufent, but without her knowledge. The law authorifes the dif- pofal of them in this manner, in order to indemnify the relations of the deceafed -hufband for the money they may have coft him. If the wife is left big with child, this cannot take place, until (lie is de- livered ; nor can it be done at all if fhe brings forth a fon. There »re like^^"?^^e two ex-ceptions ; i. when the parents of the widow affign her a proper mainte- nance ; and, 2. if the widow embraces a rehgious life, and becomes a bonzeffc. * Divorces are allowed in China in cafes of adultery, mutual diflike, incompatibility of tempers, jealoufy, &c. No huiband, however, can put away or fell his wife until a divorce is legally obtained ; and if this re- gulation be not ftriftly obferved, the buyer and ftUer become equally culpable. If a wife, lawfully married, privately withdraws herfelf from he« hufband, he may 3 C 667 1 CHI Divorces, unlawful marriases &c. ^ immediately commence an a<^lion at law ; by the fen- tence of which fhe becomes his flavc, and he is at li- berty to fell her to whom he pleafes. On the other hand, if an hufband leaves his wife for three years, flie is at liberty, after laying her cafe before the manda- rins, to take another hufband ; but if fhe were to an- ticipate their confent, fhe would be hable to a fevere punifliment. Marriage is deemed illegal in China in the follow- ing cafes. I. If a young woman lias been betrothed to a young man, and prefents have been given and re- ceived by the parents of the intended hufband and - wife. 2. If in the room of a beautiful young wo- man another b^ fubflituted of a difagreeable figure ; or if the daughter of a free man marry his flave ; or if any one give his flave to a free woman, pretending to her parents thp.t he is his fon or relation. In all thefe cafes the marriage is null and void ; and all thofe who have had any fnare in making up the n\atch are feverely punifhed. 3. Any mandarin of letters is forbidden to form an alliance wii h any family rdfiding in the province or city of which he is governor. 4. No Chintfe youth can enter into a ftate of mar- riage daring the time of mourning for his father or mother ; and if promifes have been made before, they ceafe immediately on that event taking place. After the ufua) time of mourning is expired, however, tke parents of the intended bride are obliged to write to thofe of the young man, putting him in mind of his engagement. 5. Marriage is alfo fufpended when a family expe- riences any fevere misfortune, and even if a near rela- tion were thrown into prifon ; though this may be (et afide, provided the unfortunate perfon give his confent. 6. Two brothers cannot marry two fitters ; nor is a widower at liberty to marry his fon to the daughter of a widow whom he choofes for his own wife. A man is alfo forbidden to marry any of his own relations, however diilant the degree of confanguinity may be between them. In China every father of a family is refponfible for the conduft of his children, and even of his dome- ftics ; all thofe . faults being imputed to him which it was his duty to have prevented. Every father has the power of felling his fon, " provided (fays the law) the fon has a right of felling himfelf." This cuftom, however, is barely tolerated among the iniddling and inferior ranks ; and all are forbidden to fell them to comedians, or people of infamous charafter, or veiy mean ftations. In China a fon remains a minor during the whole lifetime, and is even liable for the debts contrafled by his father, thofe from gaming only excepted. Adop- tion is authorifed by law, and the adopted child imme- diately enters into all the rights of a lawful fon ; only the law gives a right to the father of making a few difpofitions in favour of his real .children. The chil- dren, however, whether adopted or not, cannot fuc- ceed to the dignity or titles of their father, though they may to his eilate. The emperor alone can con- fer honours; and even then they muft be reiigned when the perfon attains the age of 70 ; though this refignation is confidered as an advice rather than -a 4 P 2 law. - China. C H I [ 668 I C H I 7* Criminal laws in China. '3 , Method of infli(fling the bafti- nado. law. The will of a father cannot be fet afide in Chi- na on account of any informality ; nor can any mo- ther in this empire make a will. Though the Chinefe laws authorlfe flavery, yet the power of the raafter extends only to thofe matters which concern his own fervice ; and he would be pu- nifhed with death for taking advantage of his power to debauch the wife of his flave. By the laws of China hufbandmen are exempt from the payment of taxes after he has begun to till the earth to the beginning of harveft. In criminal matters every perfon accufed muft be examined before five or fix tribunals ; and whofe en- quiries are diredled not only againft him, but againft his accufer, and the witnelfes that appear in the caufe. He is, however, obliged to remain in prifon during the procefs : " but (fays M. Grolier) the Chinefe prifons are not horrible dungeons like thofe of fo ma- ny other nations ; they are fpacious, and have even a degree of convenience. One of the mandarins is ob- liged to Infpedl them frequently ; and this he does with the greater punftuality-, as he mull anfwer for thofe who are fick. He is obliged to fee them pro- perly treated, to fend for phyficlans, and to fupply them with medicines at the emperor's expence. If any of them dies, he muft inform the emperor, who perhaps will order fome of the higher mandarins to examine whether the former has difcharged his duty faithfully or not. The flighteft punifhment In China is th^ baftinado; and the number of blows Is to be determined by the degree of the offender's guilt. Twenty is the loweft mimber; and In this cafe the ptmlfhrneut is confider- ed as having nothing Infamous In it, but being only a- fimple paternal corredlion. In this way the emperor fometlmes orders it to be Inflifted on his corn-tiers ; which does not prevent them from being afterwards received into favour, and as much refpefted as before. Every mandarin may inflift the baftinado when any one forgets to falute him, or when he fits in judgment in public. The inftrument of correftion is called pan-ffee, and Is a piece of bamboo a little flat- ted, broad at the bottom, and pollfhed at the upper extremity, in order to manage it more eafily with the hand; When the puniftiment Is to be Inflifted, the Hiagiftrate fits gravely behind a table, having on It a bag filled with fmall fticks, while a number of petty officers ftand around him, each furnllhcd with thefe fan-tfeeSf and waiting only for his fignal to make ufe of them. The mandarin then takes out one of the little fticks contained in the bag, and throws It into the hall of audience. On this the culprit Is felzed and ftretch- ed out with his belly towards the ground ; his breech- es are pulled down to his heels, and an athletic do- meftic applies five fmart blows with his pan-tfee. If the judge draws another fmall ftick from the bag, ano- ther officer fucceeds, and beftows five more blows ; and fo on until the judge makes no more fignals. When the punifliment is over, the criminal muft throw himfelf on his knees, incline his body three times to the earth, and thank the judge for the care he takes of his education. For faults of a higher nature, the canying of a wooden collar, called by the Portuguefe the. caaguey Is infiifted. This macliine Is compofed of two pieces of CJu'd^k wood hollowed out in the middle, which, when put v— ' together, leave fufficient room for the neck. Thefe 74 are laid upon the fhoulders of the criminal, and join- ^ '^""§1'' . 1 • ,- 1 11 ■ I n '■^^ wooden ed together in luch a manner, that he can neither fee coUav. his feet nor put his hands to his mouth ; fo that he is incapable of eating without the afliftance of another. This difagreeable burden he Is obliged to carry day and night ; its weight Is from 50 to 200 pounds, ac- cording to the enormity of tlie crime, to which the time of canying it Is alfo proportioned. For rob- bery, breaking the peace, or diiturbing a family, or being a notorious gambler, It is generally carried three • months. During all this time, the criminal Is not al^ lowed to take llielter in his. own houfe, but Is ftationed for a certain fpace of time, either in fome public fquare, the gate of a city or temple, or perhaps even of the tri- bunal where he was condemned. On the expiration of his term of punilhment, he is again brought be- fore the judge, who exhorts him in a friendly manner to amend ; and after giving him 20 found blows dif- charges him. 75 Banifliment Is infliiled for crimes of a nature inferior Bamlh- to homicide, and the duration is often for life, if the criminals be fent into Tartary. Some culprits are condemned to drag the royal barks for three years, or to be branded in the checks with a hot iron, indi- cating the nature of their tranfgreffions. Robbery be- tween relations la more fevtrely puulflied than any other; and that is accounted the m.oft atrocious where younger brothers or nephews appropriate to themfelves beforehand any part of the fucceliion in which they have a right to (hare with their elder brothers or nephews. ^g.,. Information cigainft a father or mother, grandfather P inlfh-- or grandmother, uncle or eldeft brother, even though mtnt of the accufation be juft. Is punifhed with 100 blows of the pan-tfee, and three years banifliment. If the. ac- ^g^l" ^l' cufatlon be falfe, it is puniihed with death. Deficit ' ency in proper filial refped to a father, mother, grand- father, or grandmother, is punifhed with 100 blows of the pan-tfee ; abufive language to thefe relations is death by ftrangling ; to itrike them is punifhed by beheading; aud if any one prefumccs to luirt or mahn them, his flelh is torn from his bones with red hot pincers, and he is cut into 1000 pieces. Abufing an elder brother is punifhed with 100 blows of the pan- tfee; ftriking him, witli the puniihraent of exile. ^7 Homicide, even though accidental, is puniflred with Capital pu- death in China. A rope about fix or feven feet in "iihnnents, length, with a running noofe, is thrown over the cri- minal's head ; and a couple of domeftics belonging to the tribunal pull it ilrongly in different direftions^ They then fuddenly quit It, and in a few moments give a fecoud pull ; a third is feldom neceifary to fi- nifli the bufinefs. Beheading is accounted in China the moft diflionourable of all punlfliments, . and is re- fcrved only for defperate afraffius, or thofe who com- mit fome crime equally atrocious with murder. To be cut in a thoufand pieces Is a punifhment inflitled only uponftate criminals orrebclliousfiibjetts. It is performed by tying the criminal to a poll, fcalping the ikin from the head, and pulling it over the eyes. The. execu- tioner then tears the flefli from dificrent parts of the.*-; CHI [6 €h!iia. unhappy wretch's body ; and never quits this horrible ^ V employment till mere fatigue obliges liim to give over: the remains of the body are then left to the barbarous fpeftators, who finifli what he has begun. Though this punifhment, however, has been inflifted by fome emperors with all the dreadful circumftances juft men- tioned, the law orders Qnly the criminal's belly to be opened, his body to be cut into f^veral pieces, and then thrown into a ditch or'river. The torture, both ordinary and extraordinary, is ufed in China. The former is applied to the hands of feet : for the hands, fmall pieces of weod are ap- plied diagonally between the fingers of the criminal ; his fingers are then tied clofe with cords, and he is left for fome time in that painful fituation. I'he tor- ture for the feet is ftill worfe. An inftrument, con- fiding of three crofs pieces of wood, is provided, that in the middle being fixed, the others moveable. The feet of the criminal are then put into this machine, which fqueezes them fo clofe that the ancle bones be- come flat. The extraordinary torture confiils in making fmall gafiies in the body, and then tearing off the Ikin like thongs. I*t is never applied but for fome great crime, luch as treafon, or where the crimi- nal's guilt has been clearly proved, and it is necelTary to make him difcover his accomplices. Notwithltanding thefe dreadful punidiments, M. Grofier is at great pains to prove that the laws of the ^8 Chinefe, with regard to criminal matters, are extreme- M. Gro- ly mild. " One law (fays he) will no doubt appear fier's gene- exceedingly fevere and rig-orous ; it inflicts the punilh- tJie Chinefe "^"^"^ of death on thofe who ufe pearls. Thofe who lawf. read the hiftory of China will be apt to fall into cer- tain rniliakcs refpcAing the penal laws of that na- tion. Some of its fovereigns have indulged them- felves in gratifying fanguinary caprices which were not authorifed by the laws, and which have often been confounded with them ; but thefe princes are even yet ranked among tlie number of tyrants, and their names are ttill abhorred and dt;tefted throughout the whole empire. The Chinefe, in their criminal procedure, have a great advantage over all otlier nations : it is almoft impolTible that an innocent man-fhould ever be- come a viflim to a falfe accufation ; in fuch cafes the accufer and witnefTes are expofed to too much danger. The flownefs of the procefs, and the numberlefs re- vrfions it undergoes, are another fafcguard for the ac- cufed. In fliort, no fentence of death is ever carried into execution until it has been approved and con- firmed by the emperor. A fair copy of the whole procefs is laid before him ; a number of other copies are alio made out, both in the Chinefe and Tartar languages, which the emperor fubmits to the exami- nation of a like number of doAors, either Tartars or Chinefe. When the crime is of great enormity, and clearly proved, the emperor writes with his own hand at the bottom of the fentence, " When you receive this order, let it be executed without delay." In cafes where the crime, though punifhable by death according to law, is ranked only in the ordinary clafs, the emperor writes at the bottom of the fentence, '* Let the criminal be detained in prifon, and exe- cuted in autumn ;" that being the feafon in which they are generally executed, and all on the fame day. The emperor of China never figns an order for the )9 ] CHI execution of a criminal till he has prepared himfelf by China. failmg. Like other monarchs he has the power of ' ^ ' ' giving pardons ; but in this refped is much more li- Q^fjf^^ mited tban any other. The only cafes in which the which Chinefe monarch can remit the punifliment inflidledciimes may by law are, i . To the fon of a widow who has not pardon- married again ; 2-. To the heir of an ancient family y'^' 3. The defcendents of great men or citizens who have deferved well of their country; and, 4. lailiy. The fons ■ or grandfons of a mandarin, who has become illullri- ous, and diftinguifhe'd himfelf by faithfully difchar- ging the duties of his office. Neither a child, nor a man of very advanced age, can be cited before a tribu- nal. The fon of a very aged father and mother is pardoned, if private property or the pubhc peace be not hurt by giving him a pardon ; and if the fons of fuch a" father and mother be all guilty, or accom- plices in the fame crime, the youngell is pardoned in order to comfort his parents. In China the accufed are always treated with, ten- dernefs and lenity, being accounted innocent until their guilt be clearly proved ; and even then, liberty excepted, they are fcarce allowed to want for any thing. A jailor is p'unifhed who behaves rigoroufly towards his priloners ; and the judges mutt hkevvife aniwer at their peril for any additions to the feverity of the law ; de- pofition being the llightell punifhment infiided upon them. Subftitution is. fometimes allowed by the laws of China ; fo that the near relation of a guilty per- fon may put himfelf in the criminal's place, pro- vided, however, that the chaftifement be flight, and the accufed his ancient friend. The fons, grand- fons, wife, and brothers of a baniflned Chinefe, are ~al-- lowed to follow him into exile; and the relations of all perfons are permitted to vifit them in prifon, and to give them every aflillance in their power ; to do which good ofiices they are even encouraged, inllead of being prevented. ^ Every city in China is divided into different quar-Qf the ci- ters, each of which is fubjetled to the infpeftion of ties and a certain officer, who is anfwerable for whatever paffes ^^eir go- in the places under his jurifdidion. Fathers of fami- lies, as we have already obferved, are anfwerable for the condud of their children and domeitics. Neigh- bours are even obliged to anfwer for one another, , and are bound to give every help and alMance in cafes of robbery, fiie, or any accident, efpecially in the night-time. Ail the cities are furnifhed with • gates, which are barricaded on the commencement of night- Centinels are alfo pofled at certain di- llances throughout the llreets, who flop, all who walkv in the night, and a number of horfemen go round the ramparts for, the fame purpofe; lo that it is almoll impoflible to elude their vigiltnce by favour of the daikntfs. A llridt watch is alfo kept during the day- time; and ail thofe who give any fufpicien by their looks, accent, or behaviour, are immediatly carried be- fore a mandarin, and fometimes even detained until the pleafure of the governor be known. Private quarrels do not often happen in. China, and it is rare that they are attended with a fatal iffue. The champions fometimes decide the quarrel with their fifls, but moil frequently refer the cafe to a man- darin, who very often orders them both a found drub- bing, ' C H I I 67 CVuna. Si Borrowing cf money. Of the Chi pcfc roads. bJng. None but nulitary peopk are permitted to wear arms in public ; and this privilege is extended even to them only during the time of war, or wheu they accompany a mandarin, mount guard, or attend a re view. Proftitutes are not allowed to remain vvitliin the walls of a city, or to keep a houfe of their o\ni , even in the fuburbs. They may, however, lodge in the houfe of anotlier ; but that other is accountable for every diHuibance which may happen on their ac- count. In all the Chinefe cities, and even in foma of their ordinary towns, there is an oifice where money may be borrowed upon pledges at the common rate of the country ; which, however, is no lefs than 30 per cent. Everv pledge is marked with a number when left at the office, and mult be produced wdien demanded ; but it becomes the property of the office if left there a finale day longer than the term agreed upon for the payment of the money. The whole tranlatlion re- mains an inviolable fecret ; not even the name of the perfon who leaves the pledge being inquired after. ' Great attention is paid by the adminiftration of China to the conveniency of travellers. The roads are generally very broad, all of them paved in the fouthern provinces, and fome in the northern ; but neither horfes nor carriages are allowed to pafs, along thefe. In many places val eys have been fdled up, and Tbcks and mountains cat through, for the purpofe of TOaklng commodious high ways, and to prefcrve them as nearly ar, poffible on a level. They are generally bordered with very lofty trees, and in fome places ^v;th walls eight or ten feet high, to prevent travellers from going into the fields ; but openings are left in p-roper places, which give a pafTage into crofs roads that lead to different villages. Covertd feats are tt-efted on all the great roads, wdierc travellers may fhelter theinfelves from the inclemency of the '\yea- ther; temples and pagods are alfo frequent, into which travellers are admitted without fcruple in the day-time, but often meet with a refufal in the night. In thefe the mandarins only have a right to reft them- felves as long as they think proper. There is, how- ever, no \vant of inns on the great roads, or even the crofs ones, in China ; but they are ill fupplicd with provifions'; and thofe who frequent them are even obli- ged to carry beds along with them to lleep on, or elfe •take up with a plain mat. Towers are erefted on all the roads _of this great empire, with watch-boxes on the top, with flag-ftafFs, for the convenience "of fignals in cafe of any alarm, Thefe towers are fquare, and generally conftrufted of brick, but feldom exceed twelve feet in height. They cWe buih, however, in fight of one another, and are guarded by foldiers, who run with great fpecd from ■one to another, carrying letters which concern the ■eiftperor. Intelligence of any remarkable event is alfo ■conveyed 'by. fignals ; and thus the court is informed with furprifing qnicknefs of any important matter. Thofe which are built on any of the roads conducting to court, are furni/hed with battlements, and have alfo o ] CHI very large bells of cafl iron. According to law thefe Ohini. towers {hould be only five lys, about half a French v league, diftant from one another. There is no pubhc poft-office in China, though fe- Method ©f veral private ones have been eitabiifhed ; but the cou- cnnvey- riers and officers charged with difpatches for the em- pire have only a right to m!ike ufe of tliem. This inconvenience, however, excepted, travellers find con- veyance very eafy from one part of China to ano- ther. Great numbers of porters are employed in every city, all of whom are alTociated. under the conduct of a chief, w^ho regulates all their engagements, fixes the price of their labour, receives their hire, and is refpon- fible for every thing they carry. When porters are wanted, he furnilhes as many as may be neceffary, and gives the fam.e number of tickets to the traveller ; who returns one to each porter when they have conveyed their loads to an appointed place. Thefe tickets arc carried back to the chief, who immediately pays them from the money he received in advance. On all the great roads in China there are feveral offices of this kind, which have a fettled correfpondence with others; the travellers therefore have only to carry to one of thefe offices a lift of fuch things as they wifli to have tranfported : this is immediately written down in a book ; and though there fhould be occafion for two, three, or four hundred porters, they are inftantly fur- niffied. Every thing is weighed before the eyes of their chief, and the hire is five pence per hundred weight for one day's carriage. An exa£l regifter of every thing is kept in the office ; the traveller pays the money in advance, after which he has no occafion to give himfelf any farther trouble : on his arrival at the city he defigns, his baggage is found at the cor- refponding office, and every thing is delivered to him with the moft fcrapulous exa^tnefs. The cuftom-houfes are here regulated by the gene- (n^jj^.^,^. ral police of the country ; and according to M. Gro- houfes. fier's account, thefe cuftom-houfe officers are the moft civil in the world. They have no concern with any clafs of people but the merchants, whom they take care not to diftrefs by any rigorous exa6tions ; nei- ther, though they have authority to do fo, do they ftop travellers till their baggage is examined, nor do they ever require the fmalleft fee from them. Duties are paid either by the piece or the load ; and in the former cafe credit is given to the merchant's book without aflcing any queftions. A mandariri is ap- pointed by tire viceroy of each province to infpetft the cuftom-houfes of the whole diftridt ; and the man- darins have alfo the care of the poft offices. 85 In former times the only money ufed in China was Money of made of fmall ftiells, but now both filver and copper ^^'^ empire, coin are met with. The latter confifts of round pieces about nihe-tenths of an inch (a) in diameter, with a fmall fquare hole in the middle, infcribed with two Chinefe words on one fide, and two Tartar ones on the other. The filver pieces are valued only by their weight. For the convenience of commerce the metal is'therefore caft into plates of different fizes ; and for want of fmall coin, a Chinefe always carries about \a) The Chinefe foot is longer by one hundredth part tiian tlie French, and the Inch is divided Into ten parts. \ CHI [ 671 CHI eh'ina. 86 Of the Chi nefe coiii- about him his fcales, weights, and a pair of fcifTars to cut the metal. This operation is performed by put- ting the filver between the fciffars, and then knocicin;^ them againft a Itone till the pieces drop ofL la gi- ving of change, however, people have no rigiit to va- lue filver by the numerical value of copper, this be- ing entirely regulated by the iutrinfic value of the me- tals. Thus, an ounce of filver will fometimes be worth 1000 copper pieces, and fometimes only 800 ; and thus the copper money of China may frequently be fold for more than it would pafs for in commerce. The emperor would lofe much by this recoinage, were he not thf fole proprietor of all the copper mines in China. It is, hov/ever, exprefsly forbidden to employ copper coin in any manufa£ture where it mi^ht be employed as plain copper, and it is alfo forbidden to be fold for the purpofe of melting : but, if the price of the metal has not fallen, the infraftion" of this law is riot ver^' feverely punifhed. On the other hand, if the value of unwrought copper exceeds .'hat of the coin, a quantity of the latter is iffued out to re- ftore the equilibrium. To keep up a conftant circulation of all the coin in the empire^ the Chinefe government are attentive to preferve an equihbrium between the propoitional value of the gold and filver ; that is, to regulate the intrinfic value of each in fuch a nnianner that the pof- feffor of filver may not be afraid to exchange it for copper, nor the poffeflbr of copper for filver. The method ufed for tl'-is purpofe is, when filver becomes f(:arce, to make all the payments for fome time in filver; but if copper, to make them all for fome time in that metal only. The commerce of China is under the infpeftion of the tribunal of finances ; but ftn this fubjedt the Chi- nefe entertain an opinion quite different from that of the Europeans. Commerce, according to them, is only ufeful as far as it eafes the people of their fuper- fluities, and procures them neceflaries. For this rea- fon they confider even that which is carried on at Canton as prejudicial to the interell of the eihpire. They take from us (fay the Chinefe) our filks, teas, and porcelain : the price of thefe articles is raifed through all the provinces : fuch a trade therefore can- not be benefic ial. The money brought us by Euro- peans, and the high-priced baubles that accompany it, are mere fuperfluities to fuch a ftate as ours. We have no occafion for more bullion than what may be neceffary to anfwer the exigencies of government, and to fupply the relative wants of individuals. It was faid by Kouan-tfe, two thoufand years ago. That the money introduced does not enrich a kingdom in any other way than as it is introduced by commerce. No commerce can be advantageous long, but that which confifts in a mutual exchange of things neceffary or ufeful. That trade, whether carried on by barter or money, which has for its objeft the importing of ar- ticles that tend to the gratification of pride, luxury, or curiofity, always fuppoles the exiftence of. luxury : But luxury, which is an abundance of fuperfluities among certain clalfes of people, fuppofes the want of neceffavies among a great many others. The mere horfes the rich put to their carriages, the greater will be the number of thofe who are obliged to walk on foot I tlte larger and more magnificent their houfes 8r are, fo much the more confined and ivYctched muft China; thofe of the poor be ; and the more their tables are sovered with a variety of difhes, the more mull the number of thofe iucreafe who are reduced to the ne- ccffity of feeding upon plain rice. Men, united by fociety in a large and populous kingdom, can employ- their induftry, talents, and economy, to no better pur- pofe than to provide necelTarics for all, and procure convenience for fome." The only commerce confidered by the Chinefe as Hiftory of advantageous to their empire, is that with RuflTia and tl.etnacic Tartary ; by which they are fupplied with thofe furs withRuffia, fo necelfary in the northern provinces. The difputes concerning the limits of the refpeftive empires of Ruifia and China feem to have paved the way to thia commerce. Thefe difputes were fettled by treaty on the 27th of Auguft 1689, under the reign of Ivaa and Peter Alexiowit/. The chief of the embaffy oa the pait of Ruffia wss Golovin gove-rnor of Siberia j and two Jefuits were deputed on the part of the em- pei'or of China ; and the conferences were held in Latin, with a German in the Ruffian ambalTador's train, who was acquainted with that language. By this treaty the Ruffians obtained a regular and per- manent trade with China, which they had long de- ' fired ; but in return they yielded up a large territory,, befides the navigation of the river Amour. The firft intercourfe had taken place in the beginning of the 1 7th century ; at which time a fmall quantity of Chi- nefe merchandize was procured by fome Ruffian mer- chants from the Kalmuck Tartars. The rapid anU profitable fale of thefe commodities encouraged cer- tain Siberian Wayvodes to attempt a dirc61: and open communication with China. For this purpofe fe- veral deputations were fent to the emperor; and though they failed of obtaining the grant of a regular com- merce, their attempts were attended with fome confequences of importance. Thus the Ruffian merchants were tempted to fend traders occafionally to Peking ; by which means a faint connexion was • preferved with that metropolis. This commerce, how- ever, was at lail interrupted by the commencement of hottilities on the river Amour ; but after the conclu- fion of the treaty in i68g, was refiuued with uncom- mon alacrity on the part of the Ruffians: and the ad- vantages thence arifing were found to be fo confide- rable, that a defign of enlarging it was formed by Pe- ter the Great, ifbrand Ides, a native of the duchy of Holftein, then in the Ruffian fervice, was therefore difpatched to Peking in 1692; by whofe means the liberty of trade, before confined to individuals, was now extended to caravans. In the mean time, pri- vate merchants continued to trade as before, not only with the Chinefe, but alfo at the head quar- ters of the Mogul Tartars. The camp of thefe ro- ving Tartars, which was generally ftationed near the confluence of the Orhon and Toula rivers between the fouthern frontiers of Siberia and the Mogul defert, thus became the feat of an annual fair. Complaints, however, were foon made of the diforderly behaviour of the Ruffians; on which the- Chinefe monarch threatened to expel them from his dominions entirely, and to allow them neither to trade with the Chinefe nor Moguls. This produced another embafTy to Pe- king in 17 1 9, when matters were again adjuiled ta the CHI [ 672 1 C H I .China. Emperor's revenue. tlie fatisfaftion of both parties. The reconciliation, was of no long duration; for the Ruffians having foon renewed their diforderly behaviour, an order for their expulfion was iffued in 1722, and all intercourfe between the two nationsforbidden. The differences were once more made up in 1727, and a caravan allowed to go to Peking once in three yekrs, provided it con- fifted of no more than 100 perfons ; and that during their ftay their expences Ihould not, as formerly, be defrayed by the emperor of China. The Ruffians at the fame time obtained permiffion to build a church within the precinfta of the caravanfary; and that four priefts were allowed to refide at Peking for the celebration of divine fervice ; the fame indulgence being granted to fome Ruffian fcholars, for the pur- pofe of learning the Chinefe language, and qualify- ing themfelves for being interpreters between the two nations. This intercourfe continued till the year 1 755 ; fince which time no more caravans have been fent to China. It was firll interrupted by a mifun- derftandlng betwixt the two courts ; and though that difference was afterwards made up, no caravans have been fent ever fmce. The emprefs of Ruffia, fenfible that the monopoly of the fur trade (whleh was entire- ly confined to the caravans belonging -to the crown, and prohibited to individuals) was prejudicial to com- merce, gave it up in favour of her fubjedls in 1762; and the centre of commerce betwixt tiie two nations is now at Kiatka. Here the trade is entirely carried on by barter. The Ruffians are prohibited from ex- porting their own coin ; finding it more advantageous to take goods in exchange than to receive bullion at the Chinefe flandard. The principal exports from Ruffia are furs of different kinds ; the moll valuable of which.are thofe of fca-otters, beavers, wolves, foxes, .martin?, fables, and ermines ; the greater part of :which are brought from Siberia and the newly difco- vered 'tflands ; but as they cannot fupply ilie demand, "there is a neceffity for importing foreign furs to Pe- terfburg, which are afterwards fent to Kiatka. Vari- ous kinds of cloth are likewife fent to China, as well as hardware, and live cattle, fuch as horfes, camels, &c. The exports from China are, raw and manufac- tured filk, cotton, porcelain, rliubarb, muflc, &c. The government of Ruffia likewife refetves to itfclf the exclufive privilege of purchafing rhubarb. It is brought to Kiatka by fome Bukharian merchants, who have entered into a contravSi to fupply the crown with it in exchange for furs : the exportation of the befl rhubarb Is forbidden under fevere penalties, but yet is procured m fufficient quantities, fometimes by clan- deflinely mixing it with inferior roots, and fometimes by fmugghng it direftly. Great part of Europe is fupplied with rhubarb from Ruffia. The revenue of the emperor of China amounts to more than 41 millions Iterling ; and might eafdy be increafed, did the fovereign incline to burden his fub- jeils with new impofitions. The annual expences of government are indeed Immenfe, but they are regulated in fuch a manner as never to be augmented but in cafes of the utmoft neceffity ; it even happens very of- ten that adminiflration makes greater favings every year. When this happens to be the cafe, the furplus ferves to Increafe the general trcafure of the empire, andpvevents the neceffity of new impofitions in time of war, or other public Calamities. The greater part Chiaa, of the taxes are paid in kind ; thofe, for inftance, * ' who breed filk worms, pay their taxes in filk, the hufbandmen in grain, the gardeners in fruits, &c. This method, at the fame time that it is exceedingly convenient for the fubjedf, is no way detrimental to the public intcrefl. There are numbers of people every where in the fervice of government, who ai'C thus furnifh- ed with food and clothing ; fo that the commoditicsi coi- lefted as taxes are almoil; confumed in the provinces where they are levied ; what remains is fold for the behoof of the emperor, and the money depofited iji the imperial treafury. The taxes paid in money arife principally from the cufloms and fale of fait (which belongs entirely to the emperor), from the duties paid by velfels entering any port, and from other im- ports on various branches of manufactures. Excepting thefe, the trader fcarcely contributes any thing to the exigencies of the flate, and the mechanic nothing at all; the whole burden of taxation thus falling upon the hufbandman. This burden is regulated in proportion to the extent and fertility of his lands; and the great- eil care has been taken to manage matters fo, that he may neither be overcharged -in the impofition nor haraffed in the levying of the duties. " The regiflering of lands (fays M. Grofier),fo often and ro no purpofe proje£led in France, has been long praftifed in this empire, notwithflanding its prodigious extent." The levying of taxes in China is as fimple as the Of the nature of the thing will admit of. The duties levied ^'-^'^'^^ " from towns and villages are carried to cities of the third clafs ; then they are condudled to thofe of the fecond ; then to thofe of the firfl ; and at lafl to the capital. The levying and impofition of taxes Is fub- mitted to the tribunal of finances ; and matters are fo managed, that befides the confumption in each diflrift for difcharging the ordinary expences of government, fomething is left by way of referve for anfwering ac- cidental demands, and to be ready in cafes of neceffity. Tin's fum becomes gradually lefs from the capital to cities of the firfl, fecond, and third clafs. A proper flatement of what is paid in the provinces, of what is referved in the different cities, or contained in the dif- ferent treafuries of the empire, is fubjefted to the ex- amination of the grand tribunal of finances. This re- vifes the whole, and keeps an exaft account of what is confumed, and of whatever furplus may be . . . . 90 Lending money upon intereft has been in ufe in Of lending| China for about 2000 years. It has often been abolifh- mo- ey. and ed, and as often eftabliflied. The intereft, as has been deficiencies already hinted, Is no Icfs than 30 J)er cent, and the year -"[£^£^^1^ is only lunar. A tenth part of this Intereft is paid montUy ; and concerning negleiSls of payment, the fol- lowing laws have been cnafted. " However much the debt may have accumulated by months or years, the principal and intereft fhall remain always the fame. Wlioever Infringes tliis law fhall receive 40 blows of a pan-tjee ; or an hundred, if he ufes any artifice to add the principal and intereft together." This law is ex- plained by the foLowing. " Whoever fhall be con- vl£f;ed before a mandarin of not having paid a montli's intereft, fliall receive ten blows ; twenty for two months, and thirty for three ; and in this manner as far as lixty ; that is to fay, to the fixth month. Thej 4 debtor y •China- e H r r 673 ] c h i debtor is then obhged to pay principal and intereft ; five kinds of feeds already mentioned but thofe who obtain payment by uling violence and force, are condemned to receive 24 blov^'S. Many Chinefe writers have endeavoured unfuccefs- fuUy to fhow why government fliould allow fuch ex- orbitant intereft to be taken for money ; but the moil fatisfasScory and rational account feems to be, that the lally, four pieces of cotton-cloth, proper for making drefles, are diftributed to each of the labourers, who aflift in yok- ing the oxen and preparing the feeds*; and the fame prefents are made to 40 other pcrfons who have only been fpedators of the ceremony. " We muft not ffavs M. Chins . ^ . , . , _ (%s M. Grofier) judge of the Of the pea. great intereft of money prevents the ricli from pur- Chinefe psafants from thofe of Europe, efpecially in^""^*- chafing much land ; as landed eftates would only em- what relates to the hghts acquired by education. Free 9^ Agricul banafs and impoverlfti them, their produce being fo much inferior to that of money. The patrimony of a family in China is feldom divided ; and it never hap- pens there, as in almoft eveiy other country, that wealth and riches are engroffed by one part of the na- tion, while the other poffefTes nothing. Agriculture is by the Chinefe confidered as the firft fchools are very numerous in every province of China, and even fome of the villages are not deftitute of this advantage. The fons of the poor are there received as readily as thofe of the rich ; their duties and their ftudies are the fame ; the attention of the mafters is equally divided between tliem ; and from this obfcure fource talents often fpring, which afterwards make a ■Hire great- and moft honourable of all profeffions ; fo that in this confpicuous figure on the erand ftag-e of life. No ly encou- Taged. empire the hufbandman enjoys many and great privi- leges, while the merchant and mechanic are much lefs efteemed. Part of the crop is allowed to be ufed in diftillation ; but if the harvett happens to be bad, this operation is prohibited. In China, the tillage of the earth is not only encouraged by law, but alfo by the perortilling .example of the emperor, who annually tills the earth ly if he be endowed with genius, find himfcTf fully com- wfth^his "'^^^^ "^^^ beginning of fpring in petent for his new employment." [own hajKls. ^^^'"^ '"s alv^-^js reckoned to be in the month of Fe- ^ The Chinefe have been greatly reproached with theorofiet' bruary ; but it belongs to the tribunal of mathematics * ^ ^' " ' ' 9* Cereniony of the em- thing is more common in China than to fee the foit of a peafant governor of that province in which his father had long toiled in cultivating only a few- acres. The father himfelf, if taken from his plough, and elevated to a fuperior fphere, might, by reviving the inftruilion he received in his youth, and efoecial- ;f u„ u„ 1 1 '.1 • ^ ,^ „ .. inhuman praftice of murdering their children; but defence of though our author cannot deny that they are guilty ''^'^ Cbincfe of this practice, he excufes them by faying, that " the crime when committed in China is comitionly owing murderi!i'ith him ; the field fet apart for this pur- pofe being at a fmall diftance-from the mount. Forty . na, where the people, blinded by idolatry, are the dupes of prejudice, fanaticifm, and fuperftition. — It often hap- pens alfo, that the bodies of thofe children which are feen floating on the water have not been thrown into it till after their death ; and this is likewife the cafe with thofe which are found in the ftreets, or lying near the public roads. The poverty oflthe parents fuggefts this_ difmal refource, becaufe their children are then buried at the expence of the pubhc, Ex- pofing of children in public places is a cuftom tole- rated in China ; and government employs as much vi- gilance to have them carried away in the morning, as it beftows care, on their education. This is certainly giving people intimation to expofe their children in ice; thofe labourers are ftlei-.. n:^i,^^ii- fo,.u ^^rr,rr.:n-^A K,r o phans, iffc. but in all this never departs from the moft exaft rules of economy ; fo that the mandarins in this refpedl are much lietter than the relations of the fo- vereign himfelf. With regard to the ancieht religion of China, F. A- p. Ambt's miot informs us, that, after making every poffible re- account of ty which hurt the interefts of the people ; for which fearch, comparing and reafoning upon his obferva ■ ^^j^. reafon they feldom fall a facrifice to that clafs of petty tions, he at laft concluded, that " the Chinefe are a chinT" ^ tyrants who in other countries prey upon and devour diftind people, who have Itiil preferved the charafteri- them. Every fuperior mandarin is obliged to inform ftic marks of their firft origin; a people whofe primitive ' ' " ' doftrine will be found, by thofe who take the trouble and half Tartars. The Highteil fault committed by a Tartar mandarin is always feverely punifhed ; but the punifhment of the greateft is often mitigated if the delinquent be a Chinefe ; and the fame feverity is exer- cifed towards thofe of the miUtary department. Thofe faults, however, are punifhed with the greateft feveri- ^ . 59 trrivileges «f princes, &;c. in Chi himfelf of the faults of his inferiors, and expofe theni ; nay, he would be punifhed for them himfelf if he did not. Very little regard, as we have already had occafion to obferve, is paid to hereditary right in China. Even -the princes of the. blood enjoy no other privilege by birth but that of wearing a yellow girdle ; and the names of their children, with the exadt time of their birth, are infcribed in a yellow book appropriated to that purpofe. Collateral princes are dillinguifhed by an orange girdle, and their qhildren are marked in a book of a red colour. The furnames of the princes of invefligating it thoroughly, to agree in its efTential parts with the dodrine of the chofen people, before Mofes, by the command of God himfelf, had configned the explanation of it to the facred records ; a people, in a word, whofe traditional knowledge, when freed from whatever the ignorance or fuperftition of later ages has added to it, may be traced back from age to age, and from epocha to epocha, without interruption, for the fpace of 4000 years, even to the renewal of the human race by the grandlbn of Noah." The im^, or canonical books of the Chinefe, every where of the reigning family are determined by the empe- inculcate the belief of a Supreme Being, the author and •■ ' " ' ^ preferver of all things. Under him they mention the names of Tien, or Heaven ; Chang-tien, or Supreme Hea- ven ; Chang-ti, or Supreme Lord ; and of Hoang-chan-ti, Sovereign and Supreme Lord : " Names (fays M. Gro- fier) correfponding to thofe which we ufe when we ror alone ; the reft not being allowed to afTume any name that too much referables thofe of the Moguls or Chinefe. The rank even of the emperor's fons diminifhes one degree every generation^ fo that, at the feventh, only the eldeft branch has a title to wear the yellow girdle, the reft being funk into the fpeak of God, the Lord, the Almighty, the Moft rank of plain citizens. An hereditary fovereignty. High " however, palTes from one eldeft fon to another ; and this title cannolr be forfeited, unlefs the pofTeffor be guilty of fome crime. In this cafe the emperor ap- points to the fucceffion either one of his younger bro- thers or a coufm ; but thefe muft be always chofen from the fame branch, as the lawful branch cannot be de- prived of its right without the condemnation of all who compofe it. The only hereditary authority of the other princes exifts among thofe troops called the According to the Chinefe books, the Supreme Be- ing is the principle of every thing that exiits, and the father of all living ; he is eternal, immoveable, and independent ; his power knows no bounds ; his fight equally comprehends the paft, piefent, and the future, penetrating even into the inmoil receffes of the heart. Heaven and earth are under his government ; all events, all revolutions, are the confequences of his will ; he is pure, holy, and impartial-; wickedueXs offends his Tartar bands. There they enjoy, without oppofition, fight ; but he beholds with an eye of complacency the that rank which they derive from their birth, but in ' every thing elfe are on a level with others. They are fubjefted to a military examination at ftated periods, and are always promoted or degraded according to the degree of llfill they exhibit. The fame trial is un- dergone by the heir apparent and his fons ; the only indulgence fliown tliem being, that fchools are ap- pointed for their particular ufe. The princes are likewife indulged with a tribunal appropriated on pur- pofe for them, and before which alone they cap be amend, tried. An infult offered to a prince decorated with The performance of religious worfhip at the pro- t