K: 13 CORNELL UNIVERSITY LIBRARY ENGINEERING LIBRARY' TN 913.G78T9 jg'"^"'*^ '"""•'^ IMPERIAL MINERAL RESOURCES BUREAU. THE MINERAL INDUSTRY OF THE BRITISH EMPIRE AND FOREKiN COUNTRIES. WAR PERIOD. PHOSPHATES. (1913-1919.) LONDON; ruMTBo AND ra>Lisno IT HIS MAJESTY'S STATIWERY OFFICE. To ta aaichued Utrougb anjr BookMlIa' or direcUr faoa U.M. STATIONERY OFFICE at the £olIowiac aMntta: Ihhbul Hoou, KiMsnrAT, Levixm, W.C8, aad SI, ASIMSDOH Stsbct, Lonoom, S.W.li IT. fmn STmUT, HAMcntTU ; t, St, Anowwrn't utucmNT, CMioirr ; U. torn Srurr, EDomnioH; SI (loa BASON k SON, Ltd.. 49 k 41, Lowu Siu:ktiii.e Stk^st, DtmuH. 1921. Price 2s. Od. Net. GOVERNMENT PUBLICATION'S (with the under-mentioned exceptions) ean be purchased in the manner indicated on the first page of this wrappOT. Hydrographieal PublicatioM of the Admiralty are sold by J. D. Potter, 145, Minories, London, E.l. 1, ■ ' Patent Office Publications are sold at the Patent Office, 25, Sonthsropton Buildings; Chancery Lane, London, W.0.2. ^ Ordnance Sumy and Geological Survey Publications can Tie purchased from the Director-General of the Ordnance Survey, Southampton ; from - the Director, Ordnance Survey, Dublin ; or from Agents in most of the , Chief Towns in the United Kingdom. They can also be ordered through any Bookseller. Small ScaTe Maps 4re on sale.at the following branches of ja._M. Stationery Office :— 28, Abing:don Street, S.W.I ; 37, Peter Street, Manchester; 1, St. Andrew's Crescent, Cardiff ; and 23, 'Forth Street, Edinburgh ; and all Railway Bookstalls. The Ministry of the Board of Agriculture is published on the l^t of each month by the Ministry, and is obtainable Irom- 10. Whitehall Place, London, S.W.I. lUnstrated, ^6^pp. Price 6rf. post free. The foBowing is a list of some recent. Official Publications {f^X prices are net, and those in parentheses include postage) i-^ IMPERIAL MINERAL RESOURCES BUREAU. The Mining Laws of the Beitish Empire and of Eobbign counteies.- Volume I. , Nigebia. --Preliminary Matter ; General Analysis; Introductory; Definition of Minerals and Mineral Oils ; Prospecting : Prospecting Rights, Exclusive Prospecting Licences; Mining: Mining Rights, Mining Leases; AndBar^ Licences ; Fees, Reiits, Royalties and Duties ; Transfer and Surrender of Rights ; Explosives ;"Begistratipn^; Machinery for the Se.ttlernent of Disputes ; Employers and Employed ; Penal Glauses ; Note on Ordinances relative to Toand Tenure ; Prospect- ing and Mining for Mineral Oil ; Ordinances, Regulations and Notices; The Minerai Oil& Ordinaiice, 1914, The Mineral Oils - Regulations; The Minerals Ordinance, 191& (as amended by Sec. 2 of IV.); The Minerals l(Amen(ipaeDt> Ordinance, 1918; Regulations made under The Minerals 'Ordinance, 1916 : The General Minerals Regulations, 1916 (as amended by Amending Regulations Nos. 11 and 16 of 1916; Nos. 1, 23, 24, and 36 of 1918; and No. 28 of 1919), The Safe Mining Regulations, 1&17 ; ' The Mica Mining i?,egulations, 1917 ; The Coal Mining Regula- tions, 1918; The Wolfram Royalties Regulations, 1919 ; The Non-Ferrous Metal Industry Ordinance, 1919 ; Regulations' made under The Non-Fen'ous Metal Industry Ordinance, 1919; The 34032 IMPERIAL MINERAL RESOURCES BUREAU. THE MINERAL INDUSTRY OF THE BRITISH EMPIRE AND FOREIGN COUNTRIES. WAR PERIOD. PHOSPHATES. (1913-1919.) LONDON : PRINTED AND PUBLISHED BV HIS MAJESTY'S STATIONERY OFFICE. To -=000 rJ oc lO OtJ — -T re O Ci -+ GC- O C-) ic -c; [^ -M CO ^1 00^ rN CO • ^ 1 lOOOO o ooo Oi C^ ->] -f (M r- rt oooo no O oc cc -t .TT 00 o rt CO 05000 o -* to •:n rjT. -M 1~t Oi o CO th o o CO a> •>* cs 'TO -t i-i Ti CO to rH t^OO (N •rH Ci -t< ■TT' no TO (M X) • (NCOOSCOOOOO CO -^ r-H :" -t- o -r< 1-H — 1 t-COOOIMOOOO <-i o n -M 00 I-- ■^ o 1 QOrHOOtOOOOO 00 -,r> t^ ir rr< r^ O^ 00 »0 ^ CO t- f-t t^ iC CO r-l 00 o o ri 2^ CO tC CO r-( C>J -O _ 00 # 05 rtOJiOOO^O^ ■~ ■N — r — .r "i -- ,- — , -+ OVOOO>0 = 0000 ;5 •a 00 CO — f %D '>4 ov .-1 (M -* 'O O O O O oj -f oc- -f Oi — r L.T -f Ol -* l>- t^ iC t^ 1^ lO C-l o cc ■M -t -f "M .-/■ -M (N ^ O O^ »0 G^ u"7 or -TJ "M CO T-( r-. 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Germany Luxemburg Italy Netherlands Portugal Russia . . . Spain Sweden ... United States of Basic Slag and during 1913. Basic Slag. Quantity (long tons). Ireland 398,000 50,000 644,000 718,000 2,214,000 246,000 48,000 18,059 Superphosphates Superphosphates . Quantity (long tons). 810,000 36,235 390,000 440,000 89,000 1,890,000 1,789,500 956,690 909,874* 124,000 221,000 181,298 3,196.000- * Production during 1914. II It A •A CI. 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A o o o en tZ5 !5 TS PkWPnC/ Phw izj ^ |25 S^'lzii?; :2i!zj;zi^ l^' !zi o ■o 00 (?fl o Tf COCO (NO lOO 00 t^ ■* >o >o a ■* ■* M< CO CO CO COIN CO O) IN ja & H ^ H ^ ^ ^^>' ^^^^ ^ ^ lO VO m t^ to Oi o o ooo T-1COO-* (N t>00 oo oooo ooco 00 OD z M i : : ; ; ■«! o ■i S i s w § : : : : : 1 P3 1 2 o 5 o FI-SM |s i sill 00:3 o I s M O pq n O i o M P3 Ph 14 2" & a < 1 Pieper. A. Grimm. H. Gilbert. S 1 < Ulbricht. Weiss. "Volcker. -apuonj^j nirLp|Bj3 III 1 1 1 1 -aunrj JO aj'Buoqjiso 5-6 3-80 -aonrjjoa^Bqd -soiij oiSBquj, 74-40 25-32 70-38 00 r-i . «3 73-13 60-79 o UO -uaSoj^T^ 0-73 0-13 o 0-11 0-25 1 -pray OTJOiidsoqj; 34-08 11-60 32-24 CO (M 33-5 27-85 CO "EisauSB]^ -emrauiY 1 1 ?^ o f 1 o «3 CO o 2-88 - 5-77 0-25 s J3 oo 00 in 1 14-8 0-75 03 00 -UOJI JO apixQ (M mm panrq -ra'oo ^on arairj 16-98 -aniTrj 30-60 45-26 CO CO T— 1 CO •aoi^traSi no ssor[ 6-46 --ta^'BAi. 11-90 9-83 7-0 O IM 2-7 7-66 9 03 i ■1 Phosphate Phospho- guano. do. o a e6 3 crusts. Coralline phosphate. Phospho- guano. Guano in crusts. Latitude (degreeis) CO ^ (M 18-2N. 18-1 N. 125 as Longitude of Green- wich (degrees) 82-5 W. 74-3 W. CO 75 W. (17-5W. CO CO o go 1 <1 d 12. West Indies. Havana Guanahani VivoriUa 13. Lesser Antilles. (a) Windward Islands. Avalo ... 1 i o £ a o 15 M i ll i ■*» H-f? 1 .SPJ o io > ^ ■6 d3 'd "S O T) ^1 Eh 1 00 .S 1 1 1 1 1 1 1 ■ c 1 1 1 1 1 1 1 1 1 1 O CS r- CO 05 CO lO . 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B iC -:t< -^^ 01 1 1 1 II 1 ■=". '?' a 0^ OS 3 c^ on lO as C^ C^ tO OS •g 1 CO — J t~ OS 1 rt CO (N 1-t lO ri r^ QQ •^ Kh i "s ■a 6 6 d 0-9 3 » ■^ ^ a s 2 ' _§- is & Ph D. f^pq a t-i ^ CO ^ >o -+ 3 rN t— >0 to C- ■* lO w « CO CO 1^ CO CO CO '^ CO oa m H K ^ q^ g H fq pq 10 >o UO H 10 'O CO 00 00 Ol OS CO — < 00 M ta 1 D 1 CO ■S t HEhhSc5H p 18 PEICES. In the year 1913 prices of phosphate had probably reached their lowest point, supply at that period having attained the maximum and having out-stripped the demand. An adequate representation of the prices ruling is exceedingly dif&cult, owing to the consideration that sales of phosphate-rock are made on the basis of percentage content of tri-calcium phosphate. In most of the published statistics of value only the average price obtained is quoted. In regard to land-pebble phosphate for example, which varies from 66 to 79 per cent, tri-calcium phosphate, prices for the higher grade in 1919 were approximately six dollars per ton in excess of the prices ruhng for the 66 per cent, grade. It will, therefore, be clear that the average price is no accurate guide to the market price obtaining for any particular grade, seeing that the average value would depend on the quantity of each grade mined during any particular period. In the year 1913 the value of the standard 70 per cent, grade of land-pebble was aproximately $3.60 per ton, or, at the rate of exchange then ruling, 15s. per ton. By the end of 1919 this price had risen to $7.35 per ton, or almost exactly double the price obtaining in 1918. In the intervening period prices fluctuated considerably. At the outbreak of the war exports of land-pebble to foreign countries fell away rapidly, and prices barely maintained the 1913 level. Owing to the demands which the belligerent countries made upon America for agricultural produce, the exportable surplus of land- pebble was gradually absorbed, and prices tended to rise, but by 1917 the advance was only about one dollar per ton over the 1913 level. After the Armistice, famine conditions obtained ifi the phosphate market, and, consequently, prices rose very rapidly, but, all things considered, the advance in the value of phosphate was not so great as in the case of many other commodities. It is thought that a brief reference to the course of prices of Tunis phosphate will, together with the above remarks as to land-pebble, form a sufficient indication of the effects of the war on the phosphate market. With Tunisian phosphate, as with land-pebble, prices vary with the quality of the rock. The price of the most popular grade, 58 to 63 per cent., had reached its lowest point in 1911, and while there was very little actual difference between prices obtaining in 1911 and 1913, the tendency was for the price to rise. The 1913 value of this grade may be taken at about 15s. M. per ton, the 63 to 68 per cent, grade being approximately 22s. 6d. per ton. In Tunis, as in America, the first effects of war conditions were to weaken prices slightly, .but in this area labour was very rapidly withdrawn from the phosphate mines to fill the fighting ranks, and production fell so speedily that the value of the phosphate commenced to rise at a very much earlier date than in the United States. 19 By 1916 the price of the 58 to 63 per cent, grade had risen to ios. per ton, with a proportionate increase in the price ol the higher grade, and to the end of the war prices rose steadily, if slowly. Immediately after the Armistice there was a very heavy demand for Tunisian phosphate, but owing to the labour position there was very httle improvement in the output during the year 1919. In consequence prices were very much inflated and quotations varied from 87s. to as much as 49s. 6d. per ton for the lower gi'ade. Prices of Egyptian phosphat& rose to an even higher point than those of Tunis, but the Pacific Islands phosphate did not show such a marked advance in price, o^^ing to the fact that the world's principal consumers are so far removed from the source of production, lack of shipping facilities restricting the demand to markets near at hand. THE MANUFACTUEE OF SUPEEPHOSPHATES. The initiation of superphosphate manufacture from mineral phosphate-rock is ascribed to J. B. Lawes, an English agricul- turist. It is behaved that prior to his experiments a method of acidulating ground bones in order to obtain a form of soluble jiliosphate was practised, but it is generally admitted that Lawes was the first chemist to use mineral phosphates for the manu- facture of superphosphates. Lawes took out patents in England, in 1842, covering the acidulation of bones and phosphate-rock. The first superphosphate is said to have been made from Cambridge coprolite by Lawes in 1845, and there can be no doubt that this discovery turned the attention of the world to the discovery of mineral phosphate deposits. Amongst tlie earliest of these discoveries were the Somme deposits in France and the South Carolina and Florida deposits in the United States. In the earliest processes of superphosphate manufactm^e, sul- phuric acid was introduced into a lead-lined tank, the phosphate- rock being poured into the tank and stirred with hoes or rakes until reaction was complete, after which it was removed from the tank and spread out to dry. The phosphate-rock was originally ground in a stone mill, and, in fact, stone mills are still used in many superphosphate factories ; but in a large number of cases these mills have been replaced by ball mills or patent grinding mills of a similar nature. The usual mixture in to-day's product is approximately 105 parts of sulphuric acid (115° Tw. or 6653 per cent. HaSOi) with 100 parts of ground phosphate-rock. These are introduced together into a mixing chamber, where they are mechanically agitated until the reaction is complete. The loss in weight in manufacture is from 10 to 12.] per cent. 20 EXPERIMENTAL WOEK. There have been many attempts to discover a method of render- ing the phosphate content of rock-phosphate soluble by other means than dissolving with acid, but so far no really satisfactory process has been evolved. Many experiments have been conducted vnth the object oi (1) fortifying lovf-grade phosphates, (2) freeing them from ferric oxide and alumma, (3) increasing their solubility. The chief patents taken out for this purpose are given by J • Fritsch in the " Manufacture of Chemical Manures " (London : Scott, Greenwood and Son), from which the foUowmg is abstracted by permission of the publishers : — 1. Dumonceau and Nicolas (French Patents Nos. 201,427, and 201,461) propose to fortify low-grade phosphates, consisting of phosphate of lime and carbonate of lime, by the use of sulphur. The principle of the two methods is as follows :— Phosphatic chalk is calcined so as to produce a mixture of phosphate of lime and quicklime, which is mixed with water and sulphur in iron pans. The insoluble phosphate of lime is separated from the soluble sulphides formed. The strength is thus fortified 20 to 30 per cent. 2. Simpson replaces sulphur by sulphuretted hydrogen (German patent 58,925), and, after calcination of the raw phos- phates, injects it into water, holding the phosphates in suspen- sion. 3. Brochon (French patent 215,577) extracts phosphates rich in carbonate of lime by means of carbonic acid under pressure after crushing and stirring with water. 4. Winsinger, to prepare bi-calcium phosphate free from oxide of iron, completely soluble in citrate of ammonia (German patent No. 51,739), extracts all the phosphoric acid of the phos- phate of lime by sulphuric acid, converts haK the solution into mono-calcium phosphate, by the addition of carbonate of lime and milk of lime, which precipitate the iron ; he adds this precipitate to the other half, and obtains by the addition of sodium sulphate, sodium carbonate and quickUme, phosphate of hme insoluble in water free from oxide of iron, which he finally adds to the solution of mono-calcium phosphate. 5. 0. lahne (German patent 57,295) prepares phosphate of lime free from oxide of iron, alumina, and silica, by acting on phosphates rich in oxide of iron and alumina with sodium bisulphate. The raw phosphates (coprohtes, etc.), in this case carbonate ajid phosphaite of lime, treated with an aqueous solution of sodium bisulphate, dissolve, whilst the silica, iron, and alumina compounds remain insoluble, and may be separated by filtration along with the gypsum. 6. In making superphosphates, Martin proposes to use the acid sulphate from the manufacture of nitric acid. The acid sulphate from the cylinders is dissolved in water, so as to produce 21 a solution of 45° to 50° Baume. The precipitate con- sists of bisulphate, which it is easy to convert into sulphate by re-crystallization, whilst the strongly acid solution is used to dissolve raw phosphates. All the phosphoric acid is dissolved, and the resultant superphosphates have less tendency to retro- grade than those made with sulphuric acid of 50° to 53° Baume. 7. Thonnar and Huxton's Belgian patent No. 96,109, and Eolland's Belgiaji patent 196,190, to eliminate the oxides of iron and alumina, may also be mentioned. 8. Schiuihb proposed to make superphosphates from ferru- ginous phosphate thus : As soluble ferric oxide induces retro- gradation of the phosphoric acid in superphosphates, whilst the ferrous oxide is inactive, and as sulphate of ammonia possesses the property of forming with a ferrous salt double salts very stable in air, Schucht, on such data, proposed to dissolve phos- phates in presence of sulphate of ammonia, then to effect the reduc- tion and so obtain very stable superphosphates of ammonia. With this end in view, the finely ground superphosphates are mixed with sulphate of ammonia. One part FsiO, requires 1'75 parts of that salt to form the double salt FeSd + (NH^ij SO4 + 6H2O. Eeduction can only be effected by weak sulphurous acid which is injected under pressm'e into the diluted mixture of superphosphate heated to 80° to 100°C. 9. Garr's process, dealing with phosphates rich in oxides of iron and alumina is analogous. It consists in calcining the phosphate, grinding it fine and then mixing 1,000 parts with 400 parts of sulphate of aaumonia dissolved in 400 c.c. of hot water, to which is then added 800 parts of sulphuric acid of 53° Baum6. A violent reaction ensues, the mass intumesces and heats to 110° C. After an hour it solidifies and is easily ground; it contains 18 per cent, of phosphoric acid, two-thirds of which is soluble in water. Author s Note. — It is evident that such generahzations are futile. The data given can only have been appHcableto the particular phosphate to which Carr applied it. All phosphates rich in oxides of iron and alumina would not respond to such treat- ment so as to yield the above results. 10. Glaser proposes to manufacture precipitated phosphates from insoluble phosphates of alumina, by treating the latter with a cold alkaline solution or with a hot concentrated solution of alkaline carbonate. In this operation the phosphate of alumina is dissolved. In using the alkaline solution, the liquid separated from the residues is treated with carbonic acid. If a hot solution of alkaline carbonate be used, it is cooled, and the dis- solved phosphate of alumina is precipitated. 11. Petermann, of Gembloux, recommends treating the raw phosphate at a high temperature to convert the phosphoric acid into a very soluble form. Ba^in has based a British patent No. 15,237 on this principle. He heats phosphates in retorts to a temperature of 1,300° to 1,500° C. 22 12. Hodgkins (American patent No. 423,320, 1890) mixes the phosphate in fine powder, with quicklime, which he then slakes. But it is not apparent how such treatment can render phosphates more soluble. Besides, no field experiments appear to have been made to test the value of the resultant manure. Manufacture of Precipitated Phosphate by Electrolysis. — A new method of manufacture, based on electrolysis, has been in- vented by Prof. W. Palmer, of- Stockholm. It consists in con- verting the raw phosphate by the wet way into a readily assimilable form, at an ordinary or slightly elevated tempera- ture. The raw material is ground apatite, which need not be finely ground. In an apparatus, specially constructed for the purpose, a solution of chlorate or perchlorate of soda is electro- lysed ; this disengages free chloric acid, sometimes even per- chloric acid, in the " anode " cell. The acid " anode " liquid is made to react on the raw phosphate in a battery of wooden cases, fitted with perforated bottoms, so that the solvent first comes in contact with almost exhausted apatite. The alkaline liquid from the " cathode " is added to the saturated solution, in special precipitation vats, taking care to stir, until a slightly acid reaction ensues. There is thus formed a crystalline precipitate of acid phosphate of lime. 'It is freed as completely as possible from the mother liquor by filtration and washing, which is greatly facilitated l^y the physical nature of the phosphates. The yield is very satisfactory, because only about 1 per cent, of the phosphate in the raw material i-emains in the solution. The latter, which contains a third of the amount of lime originally eliminated from the apatite, is mixed with the residual alkaline cathode liquid, when the greater part of the lime is precipitated as hydrate ; finally, a current of carbonic acid gas is injected. Aft-er precipitating the lime the solution is withdrawn and run into the electrolyser. The electrolyte is thus continuously regenerated. The product so obtained generally contains 36 to 38 per cent, of total phosphoric acid (the formula CaHPOi + 2H2O requiring 46-07 per cent, of P2O5). About 95 per cent, of the phosphoric acid in this product is soluble in Petermann's solution of ammoniacal citrate of ammonia. Other alternative methods have all been along the lines of the investigations of Dr. Marloth, who mixed 100 parts of finely ground rock with 40 parts of ground limestone, 20 of common salt and 10 parts of dried sulphate of ammonia. The mixture was briquetted and calcined at red heat in a kiln, after which it was ground to pass a mesh of 100 to the linear inch. A somewhat similar process was evolved in Italy, the resultant product being called " tetra-phosphate. " The Italian process was developed commercially and used to a limited extent during the war period. The advantage of manufacturing the mineral phosphate into superphosphate by admixture of sulphuric acid is that the phosphate of the rock is rendered soluble in water and this make;? it available for crops immediately it is applied to the soil. The extent to which the original phosphate content of the rock is rendered water-soluble depends upon the percentage of ferric oxide and alumina in the mineral used, hence for superphosphate manulacture a mineral which contains more than 4 per cent, of iron oxide and alumina is seldom, if ever, employed. The action of the metallic oxides in the process of dissolving is not very clearly understood, and it will suffice to say that they neutrahze a percentage of the phosphate, which passes over into the finished superphosphate as not soluble in either water or a 2 per cent, solution of citric acid. Another injurious effect of iron oxide and alumina is that they tend to cause reversion from water- soluble to citrate-soluble in the finished superphosphate, due to the interaction of the mono-calcium phosphate and the tri- calcium phosphate, leading to the formation of di-calcium phos- phate, or to the formation of ferric and aluminium phosphates by the action of the mono-calcium phosphate upon the iron and aluminium sulphates. In the latter case sulphuric acid is again set free and this in turn may possibly act upon some of the tri-calcium phosphate. BRITISH EMPIRE. United Kingdom.* Formerly phospliate-rock was obtained at many places in England, more particularly from the Cambridge Upper Green- sand, where the productive bed consists of dark-brown or black nodules of phosphate of lime and is from 8 to 12 inches in thick- ness, and from a bed of phosphatic nodules 12 to 18 inches in thickness in Suffolk- Both these deposits-' produced a considerable output of rock, but the methods employed and the conditions under which mining operations were carried out rendered the cost of production rather high. Following upon the discovery and exploitation of the great American and African deposits of phosphate-rock, phosphate- mining in England ceased to be profitable, as the amount of iron present caused the phosphate to revert to the insoluble form, and veiy little phosphate-rock has been mined in England in recent years. The output of superphosphate in the United Kingdom had gradually grown until at the opening of the war there were upwards of 80 factories engaged in the industry, the total output being approximately 800,000 tons. The development of the United States and African deposits of phosphate-rock, noted above, and the cessation of the working of the English deposits, rendered • Memoirs of the Geol. Surv. Special Reports on the Mineral Resources of Great Britain, 1917, 5, 15-24. Annual Statements of the Trade of the United Kingdom. 24 * the United Kingdom manufacturers dependent upon foreign sources for their supply of raw phosphate-rock, consequently all the factories are to be found either at or in the vicinity of the principal ports. The geographical distribution of the phos- phate works is such that the supplies of superphosphate do not have to be forwarded for any considerable distance. The principal centres of superphosphate majiufacture are as follows : — England. — Mersey, London, Humber, Bristol Channel, Ipswich, Lynn, Plymouth, Newcastle. Scotland. — Glasgow, Leith and district, Aberdeen. /reZand.— Dublin, Belfast, Cork. For the first two years of the war the superphosphate trade was left to obtain its own supplies of raw materials, and on account of the enormous demand for sulphuric acid for the manu- facture of munitions it was found that there was a very consider- able reduction in the superphosphate output. To such a degree had the manufacture fallen that the production for the year 1917 was rather less than half that of 1913, and this occurred at a time when strenuous efforts were being made to combat the submarine menace to our food supply by increasing by every means possible the production of food in the United Kingdom. During the. summer of 1917 the position had become very serious, and the Government decided to take over the whole of the superphosphate industry and to import and provide to the manu- facturers of superphosphate the whole of the raw materials which they required. Under an order issued in accordance with the Defence of the Eealm Regulations the Minister of Munitions took over the whole of the stocks of phosphate-rock and superphosphate in the country. Arrangements were made for an adequate supply of acid to be provided for the manufacture of superphosphate, and shipping was also obtained for phosphate-rock. The result of these efforts is very plainly apparent in the figures of imports which are appended to this section. The imports of phosphate in 1918 amounted to 464,872 tons, us against 276,617 tons in the year 1917. The superphosphate production in the year 1918 was approximately 800,000 tons, as compared with 460,000 tons in 1917. It^ has already been mentioned that the prices of raw phosphate up to the years 1917-18 had not risen very considerably, but, on the other hand, the submarine menace was then at its height and consequently the cost of bringing raw phosphate to this country had risen to ;i very alarming figure. Although the shipping was, in fact, provided by the State, at the same time it was considered necessary to add to the actual cost of the freight a proportion of the very heavy expenses which fell on the State by reason of the frequent total loss of steamers and cargoes. It was not possible, however, for the whole of these expenses to be passed on to the price of superphosphate as this 25 would have rendered the cost per ton of superphosphate to the farmer prohibitive and would thus have tended to discourage the use of fertilizers, which were essential for intensive food produc- tion. The State, therefore, fixed a reasonable price for super- phosphate, and bore a proportion of the cost as a loss in the interest of agriculture. During the year 1918 the demands on shipping for the moving of American troops to the theatre of war were such that for some two months it appeared as though it would not be possible to provide sufficient ships for the transport of phosphates. It was accordingly decided to re-open the Cambridge workings, and some thousands of tons of the so-called coprolites from the Trumpington bed were extracted. This coprolite is, however, of lower grade than that usually used for superphosphate manufacture, and con- sequently it had to be blended with the higher-grade rocks which were imported from outside sources. Later, however, with the change in the fortunes of war during the summer of 1918, the strain on British shipping was to a certain extent reheved. Consequently (the State again returned to foreign sources of supply for raw phosphate, and the Trum- pington workings were closed down. It will be seen by reference to the statistics attached that in the normal pre-war year of 1913 a total of 539,016 tons of rock- phosphate, and superphosphate were imported into the United Kingdom. The official statistics from which these figures are taken do not distinguish between the two materials, but so far as can be estimated from the sources of supply, about 460,000 tons of this quantity would be raw phosphate, and the balance, approximately 79,000 tons, would be in the form of superphos- phate. The demand in the United Kingdom was mainly for super- phosphate containing 26 to 80 per cent, of tri-calcium phosphate, which is manufactured from the grades of phosphate imported from Tunis and Algeria. Some proportion of the high-grade rock-phosphate imported from the United States and the Pacific Islands was, however, used for the manufacture of the lower-grade superphosphate, the usual practice being to blend with the high-grade rock a proportion of the low-grade phosphates obtained from Belgium and France. It will be observed from the statistics which follow that, during the war period, an increasingly large proportion of the supphes for the United Kingdom was taken from Algeria and Tunis, the imports from the United States falUng from 177,330 tons in 1913 to 13,361 tons in 1918. The principal reason for this variation is to be found in the shortage of shipping previously referred to. It will be obvious that in such circumstances it became vitally necessary to secure the major portion of the supplies of phosphate-rock from the nearest possible source. It is of interest to note that in 1919, when the effects of the war were beginning to pass away, the imports from the United 20 States rose to 47,800 tons, and at the same time the imports from Algeria and Tunis fell from 446,500 tons to 292,400 tons. In the pre-war period the United Kingdom was one of the principal superphosphate manufacturing countries. America produced the largest quantity of superphosphate, the second and third places being occupied by France and Germany, with a pro- duction of approximately 1,800,000 tons each, the United Kingdom following with a production of about 800,000 tons. Imports of Superphosphate of Lime and Rock-Phosphate into the United Kingdom. Quantity (long tons) From 1913. 1914. 1915. 1916. 1917. 1918. 1919. Egypt British Paciiio Possessions Other British Possessions ... 15 5,744 2 300 24,807 10,880 2,426 11,111 36 9,412 400 3,941 730 Toi;al from British Poaseg- 5,761 25,107 12,806 11,147 9,412 4,341 730 Belgium Prance Germany Netherlands Algeria Tunis United States Dutch West India Islands... French Pacific Possessions German Pacific Possessions Other Foreign Countries ... 63,969 10,166 14,168 24,347 44,996 189,555 177,330 4,476 2,633 1,615 62,912 6,989 26,248 21,251 40,380 181,107 177,792 3,830 7,415 9.201 ■ 10 300 250 73,492 195,977 81,484 10,330 600 30 602 81,876 174,640 61,828 2,777 21 734 70,812 144,443 44,982 1,930 4,304 666 32,871 413,633 13,361 3,634 208 48,496 243,883 47,807 11,000 Total from Foreign Coun- 533,255 587,135 361,883 322,274 267,205 460,531 355,028 TOTAL 539,016 562,242 374,639 333,421 276,617 464,872 355,758 Value (£). Egypt British Pacific Possessions Other British Possessions ... 30 15,283 5 363 55,975 18,916 3,038 84,885 210 46,340 9,506 16,720 7,260 Total from British Posses- sions 15,318 108,608 12,920 37,990 50,565 66,598 249,732 314,246 8,377 6,582 3,230 66,338 21,948 34,6"95 46,340 26,226 7,250 Belgium France Germany Netherlands Algeria • Tunis United States Dutch West India Islands French Pacific Possessions German Pacific Possessions Other Foreign Countries ... 129,167 11,713 72,181 50,261 61,320 241,822 304,434 7,610 15,851 20,074 66 2,247 888 156,210 305,967 170,052 47,437 1,200 60 4,997 241,016 425,246 116,489 15,186 84 7,335 317,131 684,707 182,156 14,445 20,444 18,449 138,850 1,692,864 72,165 12,089 6,770 188,601 859,720 184,496 84,300 Total from Foreign Coun- tries 858,848 918,999 682,801 804,227 1,126,217 1,922,318 1,334,976 Total 874,166 970,337 704,749 838,822 1,172,567 1,948,543 1,842,226 27 Imports of Guano into the United Kingdom. From Quantity (long tons). 1913. 1914. 1915. 1916. 1917. 1918. 1919. Falkland Islands Seychelles Other British Posses- sions 1,823 2,491 2,966 3,620 8,741 1,975 4,981 469 8,047 81 1,299 — 101 Total from British Possessions 7,280 14,336 5,450 8,128 1,299 — 101 Belgium Argentina Peru Uruguay Other Foreign Coun- tries 401 390 15,187 793 1,497 1,580 17,083 190 6,096 16,479 4,791 9,665 915 • 2,937 1,034 268 — — Total from Foreign Countries 18,268 24,949 21,270 13,517 1,302 — — Total 25,548 39,285 26,720 21,645 2,601 — 101 Value (£). Falkland Islands Seychelles Other British Posses- sions 12,300 7,500 12,268 25,791 27,474 14,436 34,733 3,151 76,826 837 13,291 — 1,250 Total from British Possessions 32,088 67,701 .S7,884 77,663 13,291 — 1,250 Belgium Argentina ... ' ... Peru Uruguay Other Foreign Coun- tries Total from Foreign Countries Total 3,159 2,269 97,502 4,910 9,261 7,921 126,1.30 905 29,429 105,164 105,001 — 5,098 38,957: 30,952 11,374 3,010 — — 117,101 164,385 144,1211141,051 14,384 — — 149,189 232,086 182,005 218,714 27,675' — 1,250 28 Exports of Superphosphates from the United Kingdom (Domestic Produce). Quantity (long tons). To 1913. 1914. 1915. 1916. 1917. 1918. 1919. Channel Islands 2,743 2,006 1,817 2,221 2,433 2,544 1.013 Cape of Good Hope 1,013 5,635 20,253 8,243 700 — 569 Natal 1,360 2,493 . 6,419 2,494 71 -T- 40 Mauritius and Dependen- 776 1,336 1,907 1,124 — — 198 Australia 7,321 5,934 1,016 _ New Zealand 12,522 13,919 6,096 98 — — Other British Possessions 1,367 2,709 1,043- 121 — 3 445 Total to British Posses- 27,102 34,032 38,551 14,301 3,204 2,547 2,265 Denmark (including 12,040 15,236 24,650 — 4 Faroe Islands) France ... 4,200 5,423 1,376 — . — — — Portugal... 1,783 2,675 1 — — — — Russia ... 4,801 1,878 — — — — — Spain 6,585 2,541 465 — — — 90 Canary Islands . 4,105 2,508 1,792 67 — — 1,456 Other Foreign Countries 2,864 1,758 1,854 — — — 211 Total to Foreign 36,378 32,019 30,128 -67 1,761 Total 63,480 66,061 68,679 14,368 3,204 2,547 4,026 Value (£). Channel Islands 8,588 7,387 5,994 9,869 15,908 16,411 6,799 Cape of Good Hope 2,764 16,397 71,688 40,763 3,853 — 6,090 Natal 5,109 9,671 29,943 14,549 359 420 Mauritius and Dependen- 2,717 5,003 7,863 7,470 — 2,357 Australia 16,347 12,631 2,390 New Zealand 34,531 38,302 16,999 325 Other British Possessions 4,010 8,010 5,751 753 — 10 5,157 Total to British Posses- 74,066 97,401 140,628 73,729 20,120 16,421 20,823 sions Denmark (including 30,635 38,372 66,025 60 Faroe Is ands) France .. 9,474 12,105 3,926 Portugal.. . 4,033 5,724 10 jRussia .. , 10,871 3,804 ' Spain . 16,064 6,153 1,155 945 Canary Islands . 11,864 7,012 6,789 324 14,195 2,558 Other Foreign Countries 9,307 4,878' 5,584 — — Total to Foreign Countries 92,248 78,048 83,489 324 — — 17,758 TOTAI 166,314 175,449 224,117 74,053 20,120 16,421 38,581. 29 Exports of Phosphate of Lime and Rock-Phosphate from the Umted Kingdom (Colonial and Foreign Produce). To Quantity (long tons). 1913. 1914. 1915. 1916. 1917. 1918. 1919. New Zealand Other British PoBseasionB 11,561 50 29,640 400 200 10 — — Total to British Posses- sions 11,611 30,040 200 10 — — Denmark (including Faroe Islands) Sweden Other Foreign Countries 11 6,970 21,995 2,737 — 2,370 — — _ Total to Foreign Countries 11 31,702 — 2,370 — — — Total 11,622 61,742 200 2,380 — — — 31,138 64 Value (£). New Zealand Other British Possessions 79,845 2,000 565 38 — — — Total to British Posses- sions 31,202 81,845 565 38 — 1 — — Denmark (including Faroe Islands) Sweden Other Foreign Countries 22 14,229 47,966 4,227 — 11,850 ! — Total to Foreign Countries 22 66,422 — 11,850 — — — Total 31,224 148,267 565 11,888 — — — 30 Exports of Guano from the United Kingdom (Colonial and Foreign Produce). Quantity (long tons). To 1913. 1914. 1915. 1916. 1917. 1918. 1919 British Guiana Mauritius and Dependen- cies Other British Possessions 450 857 265 150 74 821 265 330 168 130 16 — Total to British Posses- sions 1,072 224 1,086 498 146 — — Belgium Germany Norway United States Other Foreign Countries 468 788 962 25 1,060 2,370 168 2,030 343 301 516 204 — — Total to Foreign Countries 2,243 3,588 2,674 516 204 — — ■ Total 3,315 3,812 3,760 1,014 350 — Val ue (£). British Guiana ... Mauritius and Dependen- cies Other British Possessions 4,450 2,622 1,320 1,750 598 10,707 3,079 4,414 2,220 2,192 238 — Total to British Posses- sions 8,392 2,348 13,786 6,634 2,430 — _ Belgium Germany Norway ... United States Other Foreign Countries 4,964 5,544 5,885 238 6,348 17,732 1,646 16,428 2,385 2,304 5,719 2,225 — 5 Total to Foreign Countries 16,631 25,726 21,117 5,719 2,225 — 5 Total 25,023 28,074 34,903 12,353 4,655 — 5 Egypt.* The known deposits of phosphate of lime in Egypt occur in the Cretaceous system, more particularly in the upper .portion, under conditions closely resembling those in Algeria and Tunis. * The Phosphate Deposits of Egypt, by J. Ball ; Surv. Dept. Paper No. 30 1913. Topography and Geology of the Phosphate District of Safaga (Eastern Desert of Egypt), by J. Ball ; ,Surv. Dept. Paper No. 29, 1913. Annuaire Statistique de I'Egypte. M They consist largely of low-grade phosphorite, averaging only iiboiit 45 per cent, tri-calcium phosphate, and are therefore un- suitable for export ; but high-grade rock containing up to 75 per cent, of tri-calcium phosphate is being mined in increasing quantity from beds outcropping at the Um el Huetat mine, situated about 18 miles south of Port Safaga on the Eed Sea. This mine is connected by railway with Port Safaga, where the rock is loaded into steamers and exported chiefly to Japan and elsewhere in the East. A Uttle to the north-west of Qosir, on the south and wehi; plateau of the Duwi range in the Nakheil district, an occurrence of high-grade rock is reported. Phosphate-bearing beds, from 18 inches to 2 feet in thickness, occur also on the eastern slopes of the Red Sea hills. These exposures cover an area from 150 to 300 feet in width and about 4 miles in length. In 1913 an expedition examined the Red Sea phosphate beds, but, with the exception of the extensive Safaga deposit, the tonnage of high-grade phosphate-rock available was found to be too limited to warrant the acquisition of any property. Extensive beds of phosphate of lime occur in the Nile A'^alley, notably in the Sibaia district, on both sides of the river. The bone beds outcrop at a point about 11 miles south of Esna, where three thin beds occur. Analyses of samples from these beds showed the material to be too poor in phosphoric acid to warrant exploitation. At Sibaia the deposits consist of four beds of phosphate of lime which have a total thickness of about 6 feet. Farther to the north, near the village of Qift, there is an extensive bone bed. about 3 feet in thickness which covers the larger part of the Gebel el Qurn plateau, the area of the deposit being about 2,500 acres. The distance to Qift railway station is from 6 to 12 miles. Chemical examination has shown that these beds have under- gone silicification, with a consequent lowering of the percentage of phosphoric anhydride to the extent of about 7 per cent, in the upper layer of the bed, but there remains an average thickness of about 18 inches of unaltered bone bed. Throughout the whole of this area there is very little overburden above the bone beds, the thickness of cover rarely exceeding 9 feet of loose rubble, while in places the bone beds form the surface. An Italian company has obtained large concessions in this district, and also on an extension of these beds on the west bank of the Nile. The rock quarried from the Gebel el Qurn deposit is transported t)y aerial ropeway to the Nile, and thence by boat to Alexandria, where it is shipped to Europe. Analyses of the phosphate-rock from these districts of the Nile Valley indicate that an average of over 45 per cent tri-calcium phosphate may be expected. Phosphatic beds occur also throughout the Dakhla oasis, the total area of outcrop in this region being about 19 square miles. 32 The Egyptian phosphate beds, with the exception of parts of the Sibaia and Gebel el Qurn deposits and tliose at Safaga and Dakhla, are mostly too poor in quaUty to admit of profitable mining for export. There should, however, be a large denaand for this material for domestic consumption when the Fellahin and small farmers of the Nile Valley have learned the value of phosphate of lime as a fertihzer. So far, the domestic demand for the native insoluble phosphate, of which Egypt possesses a practically inexhaustible supply, has been small. Egyptian Productioi I and Exports of I Phosphates. Year. Production. Exports. Quantity Quantity (long tonfe) . (long tons). 1913 ... 102,771 63,151 1914 70,789 85,181 1915 81,664 32,386 1916 ... 122,999 20,196 1917 ... 113,872 25,499 1918 30,646 9,196 1919 28,893 77,263 etails of the exports for 1918 and 1919 are i as follows : — 1918 1919 (long tons) . (long tons) United Kingdom 395 1,022 Australia and New ZeE iland ... — 9,839 Italy — 31,594 Japan ... 3,031 20,998 Other Countries ... 5,770 13,810 Total . ... 9,196 77,263 Union of South Africa.* So far as is known at present, the only deposits of phosphate- rock of any considerable commercial importance in the Union of South Africa are the aluminous phosphates of Saldanha Bay, on the south-west coast of Cape Province. The rocks of this district consist chiefly of granite and porphyry, which form a succession of isolated hills rising above an arid region of blown sand. The phosphates are found outcropping on the two hills lying north and south of the entrance to Saldaaiha Bay. * Report on the Phosphates of Saldanha Bay, by A. L. Du Toit ; Union of South Afrina Department of Mines and Industries Geol. Surv Memoir No 10 1917. ■ ■' • > Annual Reports of the Grovernment Mining Engineer of the Union of South Africa. Annual Statements of the Trade and Shipping of the Union of South Africa and of Southern and Northern Rhodesia. 33 At the northern locality known as Hoedjes Bay, the rock crops out m the sandy soil at the foot of the hill, and phosphate-rock has been observed extending to the top of the mountain, at an elevation of 364 feet. The depth of this sheet or surface oover- mg is variable, and sufficient prospecting has not yet been done to allow of any estimate of the quantity being made. Where tested, the rock has been found to have a thickness of 4 to 15 feet. Analyses of samples of the phosphates obtained at Hoedjes Bay show from 10 to 23 per cent, of phosphorus pentoxide, from 16 to 77 per cent, of silica, and from 7 to 37 per cent, of iron oxide and alumina. At the southern locality known as Oude Post, the phosphates crop out on the flanks of Constable Hill at a general elevation of 150 feet, and continue to immediately below the bare granite summit, 616 feet above sea level. The material in the Oude Post deposits differs somewhat from that at Hoedjes Bay in carrying a considerable percentage of quartz ; but the percentage of phosphoric acid is somewhat higher, varying from 14'8 per cent, to 32'63 per cent. These deposits have not been opened up, and the probable reserves have not been estimated, although they are stated to be large. Throughout the Saldanha Bay deposits, there is very little phosphate of lime, the phosphoric acid being almost entirely combined with alumina and iron. Before the war there was a small plant at Hoedjes Bay, con- sisting of a mill for grinding phosphate rock. A superphosphate plant was, however, in process of erection, and during the year 1919 an up-to-date plant was being erected at Somerset West, Cape Province. When this plant is finished, South Africa will be in a position to manufacture a considerable proportion of its requirements of phosphate fertilizer. Other districts within the Union where phosphates are known to occur are Weenen, in Natal, where the deposits are of low grade, carrying only about 8 per cent, of phosphorus pentoxide, and Lulukop, in the Zoutpansberg distriqt of the Transvaal. Lulukop is an isolated hill of very pure limestone which carries considerable quantities of apatite and magnetite. The apatite is reported to amount to about 10 per cent, of the rock in places. The deposit lies in a remote and unhealthy district, and it does not seem probable that any considerable supply will be obtainable from this source. Phosphate deposits are known to occur at Cape Cross, north of Swakopmund, South- West Africa ; in the Kuruman district, South Bechuanaland ; in the Kenhardt Division of Cape Province ; and on Bird Island, Algoa Bay. Sufficient development work has not yet been done in any of these locahties to prove their economic value. 34032 B 34 Value of Phosphates produced in Cape Province. Year. Value i£). 1916 1,305 1917 2,875 1918 6,639 1919* — • Operations were suspended during the year 1919. Imports of Raw Phosphates into the Union of South Africa.* Prom Quantity (long tons). 1913. 1914. 1915. 1916. 1917. 1918. 1919. United Kingdom South West Africa Pro- tectorate 140 132 — — — 4,514 5,600 252 Total from British Pos- sessions 140 132 — — — 4,514 5,852 Belgium Germany 55 485 5 200 — — — — — Total from Foreign Countries 540 205 — — — — — Total 680 337 — — — 4,514 5,852 Value (£). United Kingdom Bgypt South West Africa Pro- tectorate 446 739 — — — 6,771 10,000 1,974 Total from British Pos- sessions 446 739 — — — 6,771 11,974 Belgium Germany 126 1,133 12 433 — — — — — Total from Foreign Countries 1,259 445 — — — — — Total 1,705 1,184 ^^ — — 6,771 11,974 * In each of the years 1914 and 1918 phosphates to the value of £1 were imported from St. Helena. " 35 Imports of Superphosphates into the Union of South Africa. From Quantity (long tons). 1913. 1914. 1915. 1916. 1917. 1918. 1919. United Kingdom Australia 2,648 2 5,374 25,465 10,845 601 z 740 Total from British PosseBHi an R 2,650 5,374 25,465 10,845 601 — 740 Belgium Germany Holland Portugal Portuguese East Africa United States Argentina Japan 2,405 6,903 24,383 278 242 3,722 23,551 1,856 200 2,157 600 357 6,673 5,612 3,300 88 2,675 — Total from Foreign OonntTifiH 33,969 27,515 4,813 7,030 5,612 6,063 — Total 36,619 32,889 30,278 17,875 6,213 6,063 740 Val ue (£). United Kingdom Australia 7,731 4 18,080 94,102 59,424 3,521 7,792 Total from British 7,735 18,080 94,102 59,424 3,521 — 7,792 Belgium Germany Holland Portugal Portuguese East Africa United States Argentina Japan 5,619 19,514 61,432 973 1,002 9,300 59,721 5,527 650 7,838 2,026 1,766 28,635 3 26,901 28,854 1,524 47,740 — Total from Foreign Countries Total 87,538 70,023 16,041 30,401 26,904 78,118 — 95,273 88,103 110,143 89,825 30,425 78,118 7,792 Canada."*" Prior to the development of the United States phosphate deposits, Canada produced important quantities of phosphate- rock and exported considerable amounts to the United Kingdom. The material mined was wholly apatite, containing from 31'87 to 41"54 per cent, phosphoric acid. • Economic Minerals and Mining Industries of Canada ; Mines Branch , Deot. of Mines, Ottawa, Canada, 1914, p. 50. Investigation of a Reported Discovery of Phosphate in Alberta, by Hugh S. de Schmid ; Canada Dept. Mines, 1916, Bull. No. 12. Annual Reports on the Mineral Production of Canada. Annual Renorts on the Trade of Canada. 34032 B 2 36 The importation of ciieap phosphate-rock from the Unite' States seriously affected the phosphate-mining industry in Canada and in recent years the only production of apatite in the Dominio: has been an annual output of a few hundred tons obtained durin, thica-mining operations on the extensive mica belt in Ottaw county, Quebec. Throughout the region extending from th Ottawa Eiver on the south, northwards through the township of Buckingham, Templeton, Wakefield, Bowman and Hinckf deposits of apatite occur abundantly over a width of 15 to 2 miles. The deposits in the province of Ontario are less important tha: those of Quebec. The mineral occurs as crystal aggregates in matrix of crystalline limestone. The area within which apatit is found extends southward from the Ottawa Eiver to within few miles of the St. Lawrence, a distance of nearly 100 milee The average width of the belt is from 50 to 75 miles. Analyses of typical Quebec Apatites* McLolland Mine, Scott Mine, Hull. Bainville Mine, High Falls Mine, Blackburi Mine, Hull. Templeton. Bowman. Templetoi Silica 0-48 1-80 0-64 0-06 0-36 Iron oxide ... Alumina i 1-00 1-30 1-30 0-72 8-72 Lime 54-20 53-30 54-40 55-70 55-60 Magnesia ... 0-35 0-28 0-31 0-20 0-33 Soda Potash ") 0-77 0-64 0-88 0-80 0-75 Water 0-32 0-36 0-12 0-28 0-20 Chlorine ... ... 0-44 0-4U 0-67 0-65 0-50 fluorine ... ... 3-30 3-20 3-30 3-10 3-05 Carbon dioxide 0-66 1-75 Phosphorus pent- 39-60 40-15 37-50 39-24 39-39 oxide * Summary Report, Mines Branch, Dept. of Mines, Ottawa, 1917, p. 110. Buckingham township, in Quebec, is the principal seat of th phosphate industry in Canada. Phosphate-rock is there mam factured into fertiUzers, phosphorus and its compounds, but th faw material is ahnost entirely imported from the United States. The only known deposits of phosphate-rock of sedimentai formation in Canada are certain low-grade coprolitic bee bccurriag in Quebec and Nova Scotia, and containing about £ to 44 per cent, tri-calcium phosphate; a thin bone-bed in tb Cretaceous rocks of the Wilson Eiver, Manitoba, carrying aboi 30' 7 per cent. tri-caJcium phosphate; and an extensive regie in Alberta where there is a steeply-inclined bed of low-grade, hai black phosphate, 12 inches in width, lying conformably' wil the bedding-planes of the enclosing Eocky Mountain quartzites. The Alberta deposits were carefully examined in the autum of 1915 by officers of the Canadian Department of Mines, wl 37 reported that the low grade of the material (43" 7 per cent, tri- calcium phosphate) and the high cost- of mining would hardly permit of these deposits being profitably worked. Production of Phosphates in Canada. Quae tity (long tons). Value (£).• Year Quebec. Ontario. Total. Quebec. Ontario. Total. 1913 344 344 759 759 1914 . 495 357 852 1,016 500 1,516 1915 . 179 15 194 500 21 521 1916 . 170 11 181 488 36 524 1917 . 110 23 133 256 53 309 1918 . 125 125 250 250 1919 . 20 1 21 362 6 368 Imports of Phosphate- Rock and Superphosphate into Canada. (Fiscal years ending March 31.) Phosphate- Bock. Superphosphate. Year Value (£)• Quantity (long tons). Value (£).* From the From the From the Prom the From the United United United United United States. Kingdom. States. Kingdom. States. 1913 5,029 64 800 1,543 15,250 1914 3,379 85 829 1,645 17,127 1915 3,567 67 754 1,323 19,678 1916 3,139 58 906 1,147 23,082 1917 4,517 15 1,299 392 34,270 1918 14,549 6 1,143 139 42,806 1919 18,234 — 1,385 64,144 Exports of Phosphates from Canada. (Fiscal years ending March 31.) Quantity Value* Year (long tons). (£). 1913 . .' ... — — 1914 167 104 1915 54 37 1916 252 709 1917 ... ... 12 42 1918 ... ... — — 1919 . . — — Note.— The whole of the exports were sent to the United States. • Yaluea converted to £ sterling at the rate of 1 dollar ^ 48. 2d. 34032 B 3 38 West Indies. In the Island of Eedonda, Leeward Islands, West Indies, deposits of aluminium phosphate occur as veins in the volcanic rock of which the island is composed. The thickness of the vems varies from a few inches up to 2 feet. Official reports give no statistics of the amount of phosphate exported from the island, but considerable quantities have been shipped to the United States. No shipments were made between 1912 and 1915, although in the latter year a stock of 1,235 tons of phosphate awaited shipment. The Blue Book for 1917-18 states that 80 men were at that time employed on the deposits. . India. Phosphate of hme occurs in the Cretaceous formations of Pondicherry, notably in the neighbourhood of Valudayur, where a bed of black phosphatic nodules was worked some years ago ; but the operations were not successful. The distribution of the phos- phatic nodules within the bed is exceedingly irregular, varying between 27 lb. and 47 lb. per 100 cubic feet of rock. The nodules contain from 56 to 59 per cent, tri-calcium phosphate, with about 15 per cent, carbonate. It has been estimated that the bed contains 8 million tons of phosphatic nodules. The Department of Industries in Madras is now considering the problem of the exploitation and development of the deposits of phosphatic nodules in the Trichinopoli district ; and the estab- lishment of an experimental factory is contemplated at Trichi- nopoli for the production of flour phosphate. Nodules of phosphate of lime and layers of phosphate-rock occur in a band of shale at the base of the chert beds immediately overlying the Mussoorie limestone on the Midlands Estate of the Dehra Dun district. United Provinces. The nodules contain 75 per cent, of tri-calcium phosphate, and the phosphate-rock 66 per cent. Exposures of the deposit have been found at three places in a length of a mile. Apatite occurs abundantly in the mica-pegmatites near Kodarma, in Hazaribagh, but it is discarded during mining operations, and considerable quantities of this mineral he on the waste-dumps. Apatite also occurs near Jothvad, in Bombay, where the mineral constitutes from one-fourth, to one-third of the rock; also at the manganese mines of Garbham, Eamabhadra- puram, and Devada, in Madras. The apatite is apparently not considered of any value, the whole output going to the waste- dumps. Palestine. The important deposit of phosphate situated between Es Salt and Ammon, in the valley of the Jordan, was known and generally prospected prior to the war. Certain workings and test borings had been made, but no organized effort had been brought to bear 39 on inuny of the phosphate beds in the area. It is probable that difficulties of railway communication had mihtated against the commercial development of the deposit. Pre-war references to the deposit describe it as being in an inaccessible position, the nearest railway line being at Jerusalem, which is approximately 30 to 35 miles in a direct Une from Es Salt. As a result of the military operations in Palestine, however, a railway was constructed from Medina |to Haifa. The line runs parallel to the Jordan about 30 milea east of the Jordan vaiiey, and consequently passes very close to the eastern side of the deposit at Es Salt. The railway follows a circuitous route to the sea, the distance traversed betvyeen Ammon aoid Haifa being 151 miles. During 1916 a careful examination of the deposits, made by a German official attached to [the Turkish Army, indicated that they were of greater importance than had originally been suspected. The phosphate beds, of which there are several, are situated on either side of the caravan route from Jerusalem to Ammon, and are reported to be of two types, namely, plateau pliosphates and rich deposits. Plateau Deposits. — Large areas within the plateau phosphate district aj-e covered with fairly thick deposits. At Wadi-el-Kabou and Wadi Siron, there are two phosphate beds, one close to the surface and the other 60 to 70 metres (185 to 215 feet) below the surface. They occur in three aj-eas, namely : (1) Abou Tajrah ; (^) west of Carbet Botin ; (3) north-west of Hirbet Aboutine. On the western side of Abou Tarah there are three phosphate strata, the uppermost of which is 10 metres (32 feet 6 inches) in width, the others being 7 metres (22 feet 9 inches), and 3 metres (9 feet 9 inches) in width respectively. The' outcrop is 150 metres (about 490 feet) in length, and a test caoried along the whole length averaged 51 per cent, of tri-calcium phosphate. The thickness of the strata, the uppermost of which is under a loose cover about 1 to 2 feet deep, ranges from 12 inches to 2 feet, and these deposits are, therefore, unimportant. The plateau west of Carbet Botin flanks the road from Es Salt to Ammon on both sides. At a point about 5 miles from Es Salt a bed of phosphate several metres deep was found, 23 feet below the surface, showing 54" 6 per cent, of tri-caicium phosphate. Various other borings were made, and the average thickness of deposits on this plateau was estimated at 3 metres (9 feet 9 inches) at a depth of a few metres below the surface. The average of all tests made on this plateau showed 541 per cent, of tri-calcium phosphate. The plateau north-west of Hirbet Aboutine is a prolongation, in a north-easterly direction, of that west of Carbet Botin. Here are severaJ deposits of considerable extent, averaging 3 metres (9 feet 9 inches) in thickness, and containing on an average 47 "3 ner cent, of tri-calcium phosphate. 34032 B 4 40 Rich Deposits. — The rich zone extends from Djebel Abou el Bewati on the south up to Hirbet Aboutine on the north, but its continuation beyond Djebel Abou Tarah to the south and Djebel Oum ©1 Kaoub on the north, was not proved. At Abou el Bewati the occurrence of powdery phosphate at 876-5 metres (2,850 feet) above sea-level is regarded as important. The analysis showed 78' 05 tri-calcium phosphate. To the south the powdery phosphate deposit gives place to rock phosphate occurring at about 40 metres (130 feet) below the surface. At its southern hmit the analysis of the powdery phosphate falls to 58/52 per cent. Tests of the rock, however, showed from 63'01 per cent, to 67'17 per cent. No rich phosphate was found to the south of this mountain, but to the north on the Djebel Siron there are a large number of deposits of high-grade material. A shaft was sunk at one point here and a sample gave an analysis of 78'14 per cent. The deposit is apparently very thick (over 20 metres — 65 feet), and 22 analyses showed an average test of 66'1 per c^.nt. The deposit is in layers of varying content rising as high as 80'84 per cent, and falhng at the bottom of the shaft to 59 '3 per cent. South of the shaft the deposit increases in depth from the surface and it appears to lie on an incline of 43° towards the wesit. Here a percenitage content of 82"8 per cent, was estab- lished apparently by boring through the layer. At another excavation some distance away the thickness of the deposit was found to be reduced to 10 metres (32 feet 6 inches), but the analysis was found to be between 83 and 84 per cent. At a third excavation the thickness was found to be less still, but the analysis was 82'4 per cent. North of the shaft, some distance away, the thickness of the layer wa-s found .to decrease from 4 metres to 2 metres (13 feet to 6 feet 6 inches), but the tests were still from 80" 5 to 83" 8 per cent. At Carbet Botin, various tests were made in existing excava- tions and several borings were made. The existence of phosphate beds, some of which were up to 8 metres (26 feet) thick, was established, and test analyses showing from 68"19 to 83'4 per cent, were made. The average of all tests was found to be 72'07 per cent. Again, at Hirbet Aboutine, excavations were made and a bed 6-30 metres (20 feet 6 inches), 5 metres (16 feet 3 inches), and 3 metres (9 feet 9 inches), in thickness at various points was found, analyses at the three points showing 80"1 per cent., 61'8 per cent, and 71 per cent, respectively. It is not clear whether these tests were over only one bed or over three different deposits. At its northern extremity this deposit still shows a thickness of 2'5 metres (8 feet 2 inches). 41 Quantity (long tons) * 149,956 93,703 23,731 44,209* 89,889* 53,370* • Exports. Australia.! Straits Settlements. Chkistmas Island. Christmas Island lies in the Indian Ocean, about 190 miles south of the western extremity of Java. The phosphate deposits are similar to those on Ocean Island. The rock contains on an average about 80 per cent of tri-calcium phosphate. In the year 1912 Christmas Island produced about 300,000 tons of phosphate. Large reserves are available. Production of Phosphate-Rock in Ghristnuis Island. Year. 1913 1914 1915 1916 1917 1918 1919 New South Wales. — Small quantities of phosphate of lime are known to occur in many of the limestone caves found in the State. The deposits are invariably the result of the decomposi- tion of animal remains and, where mined, the rock carries a high percentage of tri-calcium phosphate. The only deposit of any considerable value worked during the period under review was in the Wellington division, which pro- duced the bulk of the phosphate-rock mined in the State. These deposits were exhausted in 1918. Victoria. — Phosphate mining in Victoria is confined to workings situated near Mansfield. The phosphate-rock is obtained by underground mining, the material obtained being picked over at the mine and the selected rock shipped to Melbourne. Queensland. — Deposits of phosphate-rock are being mined on Holbourne Island, which is situated about 20 miles east-north-east of the town of Bowen. The phosphate-rock varies considerably as regards the phosphoric acid content, and it is unsuitable for the manufacture of superphosphate. Including the lowest grades there are about 400,000 tons of phosphate-rock available. f Annual Reports of the Department of Mines, New South Wales. Annual Renorta of the Secretary for Mines, Victoria. Reviews of mining operations in South Australia. Trade and Customs and Excise Revenue of the Common- wealth of Australia (Annual). 42 South ^MsiraHa.*— Phosphate-rock, almost invariably asso- ciated with Cambrian or pre-Cambrian limestone, occurs abun- dantly over wide areas of South Australia. The associated minerals are chiefly limonite and manganese oxide, both occurring sparingly, with silica in the form of chert and quartz. Copper has been noted in the form of copper phosphate in the quarries of the Pekina district, and haematite in veins up to half an inch in thickness has been found traversing the phosphate-rock of the Bendleby deposits. Phosphate-rock is worked at a large number of locaUties, between Willunlga in the south and Carrieton in the north, and between Chnton in the Yorke Peninsula and Bright to the north of Eudunda. The principal producing districts are the Belvedere including Kapunda, and Moorooroo, north of Adelaide ; the Willunga and Noarlunga districts to the south of Adelaide ; and the Tarcowie and Pekina districts north-east of Port Pirie. The phosphate-rock is mined or quarried in the simplest manner, usually by open-quarrying, but sometimes, as in the case of the St. John's and McArthy's quarries, by means of an incline and a rough pillar and stall system. Owing to the erratic nature of the deposits, no attempt is niade to block-out reserves, the only- development work undertaken being the driving of small prospecting levels ahead of the workings. The grade of rock produced averages about 60 per cent. tri-. calcium phosphate in the " firsts " and over 50 per cent, in the " seconds." Eock below 50 per cent, is for the most part unsaleable. Large deposits of aluminium phosphate occur in the Belvedere, Clinton and Orroroo districts, but these occurrences have not beeii worked. Superphosphates are manufactured in Australia chiefly from high-grade imported rock. Before the war high-grade pyrites was imported from Spain for the manufacture of the sulphuric acid required for the production of superphosphate, but during the war it was found impossible to obtain Spanish pyrites, and crude sulphur imported from Sicily and Japan was used for the produc- tion of the acid. One company produces a " Standard " super- brand guaranteed to contain 36 per cent, of tri-calcium phosphate m water-soluble form from the imported rock, and a brand con taming 30 per cent, tri-calcium phosphate. The works are situated at Wallaroo and Port Adelaide and have a capacitv of over 70,000 tons per annum. Other works are situated at Torrensville and Port Adelaide, and have a capacity of 40,000 to 50,000 tons per annum. In addition the metallurgical w^rks at Cockle Creek have erected a large plant for the manufacture of superphosphate, the phosphate-rock being obtained from Ocean * The Phosphate Deposits of South Australia bv R T Ta„t n i o S. Austr. ; Bull. No. 7, 1919. ' ^ " ^- ''^'^'^ ' ^^°^- S"'^- 43 During the period under review, considerable attention was given to the apatite-bearing pegmatite veins of the Boolcoomatta district. Early in 1919 an important discovery of apatite was made near the old Boolcoomatta Station. The mineral was found occurring in lenticular masses of considerable size. The main exposure has a length of 90 feet and an estimated average width of 9 feet, the extension in depth being unknown. Other deposits were found scattered over a considerable area of the Boolcoomatta district. Analyses of various samples of apatite from these areas show insoluble matter ranging from 14'9 to 454 per cent., and phos- phate equivalent to 4870 to 7778 per cent, tri-calcium phosphate. Western Australia* — Coprolite deposits, interbedded with ferruginous sandstones and chalk, have been proved to occur over a distance of 22 miles in the Dandarragan district, which is situated about 20 miles to the west of Moora, on the Midland Railway. The coprolite beds average about 3 feet in thickness, and conjtain from 15'32 to 39"34 per cent, phosphorus pentoxide. No production was reported from this district during the period under review. High-grade phosphate of lime has been obtained from the numerous caves that occur in the limestone hills between Perth and Geraldton. The deposits are hmited in extent, and the pro- duction therefrom is only of local value. The only deposits worked on a commercial scale are the phosphate beds that occur on all the islands from the Ashmore Shoals to the Abroholos Islands. So far as is known, the bulk of the high-grade^ phosphate-rock on these islands has been worked out, but there still remain large quantities of low-grade material which, if ground, could be profitably employed on the wetter farming lands of the State. Production of Phosphatet ■ in Australia. New South Wales. Victoria. Soatb Australia. Year. Quantity Value Quantity Value Quantity Value (long tons). (£). (long tons). (£;. (long tons). {£). 1913 5,950 6,545 1914 700 1,055 — — 6,083 6,691 1915 1,100 — — — 4,614 5,536 1916 2,042 — 400 1,150 5,013 5,839 1917 2,000t 4,500 1,525 1,525 5,101 6,064 1918 460; 1,400 3,384 3,384 8,074 10,773 1919 576 2,016 2,491 2,491 5,950 8,982 • Geol. Surv. Western Australia. Miscellaneous Reports, Series V., No. 61, 1917, Bull. No. 74. f In addition, some 40 to 50 tons of material, said to be rich in phosphates, were raised during prospecting operations. t Including 160 tons of phosphate of lime used in smelting. u Exports of Phosphate-Rock from Australia.* (Fiscal years ending June 30.) Domestic Produce. Foreign Produce. Year. Quantity (long tons). Value Quantity (£). (long tons). Value (£). 1915 1916 1917 1918 1919 1,117 3,742 3,301 3,500 2,200 3,429 10,507 8,464 9,810 6,773 50 188 The whole of these exports went to New Zealand. Exports of Superphosphate from Australia (Domestic Produce.)^ (Fiscal years ending June 30.) To Quantity (long tons). 1915. 1916. 1917. 1918. 1919. New Zealand Fiji 13,963 1,587 40,355 113 23,881 288 34,825 164 17,056 214 Total to British Possessions ... 15,550 40,468 24,169 34,989 17,270 Samoa (German) Java Other Foreign Countries 3 500 9 — 5 Total to Foreign Countriee ... 3 500 9 — 5 Total 15,553 40,968 24,178 34,989 17,275 - Value (£) New Zealand ... Fiji 58,300 5,909 153,517 621 104,063 1,385 178,865 821 94,512 1,086 Total to British Possessions ... 64,209 154,138 105,448 179,686 95,598 Samoa (German) Java Other Foreign Countries 13 2,122 41 — 23 Total to Foreign Countries ... 13 2,122 41 — 23 Total 64,222 156,260 105,489 179,686 95,621 t. In addition, superphosphate to the value of £15 was sent to Norfolk Island during the period 1913-1919. 45 Imports of Phosphate- Rock into Australia. (Fiscal years ending June 30.) From Quantity (long tons). 1915. 1916. 1917. 1918. 1919. India New Zealand Christmas Island Gilbert and EUice Islands Ocean Island 13,724 98,855 3 26,866 96,049 47,885 92,501 1 17,864 112,861 11,938 62,962 Total from British Possessions 112,579 122,918 140,386 130,726 74,900 United States Bismarck Archipelago Makatea Island New Caledonia Pleasant Island Society Islands Tatakotoroa 5,132 300 28,638 17,318 4,300 4,960 17,367 47,704 2,700 6,634 1,190 27,418 2,200 51,426 7,178 58,513; Total from Foreign Countries 60,648 67,771 37,442 51,426 65,691 Total ,173,227 190,689 177,828 182,152 140,591 alue (£). India New Zealand Christmas Island Gilbert and Ellioe Islands Ocean Island 30,771 227,164 12 65,911 222,566 148,553 207,809 3 82,609 239,317 59,094 131,563 Total from British Possessions 257,935 288,489 356,362 321,929 ! 190,657 United States Bismarck Archipelago Makatea Island New Caledonia Pleasant Island... Society Islands Tatakotoroa 9,816 528 65,170 41,713 11,209 10,912 38,209 107,499 6,237 17,564 2,939 63,669 4,450 112,011 15,791 127,588 Total from Foreign Countries 139,348 151,945 88,622 112,011 143,379 Total 397,283 440,434 444,984 433,940 334,036 46 Imports of Superphosphates into Australia. (Fiscal years ending June 30.) From Quantity (long tons). 1915. 1916. 1917. 1918. 1919. United Kingdom New Zealand 6,989 5 5 — — — Total from British Possessions 6,989 10 — — — Belgium Germany Netherlands Japan 100 24 5,905 12,101 2,880 10 — — Total from Foreign Countries 18,130 2,880 10 — — Total 25,119 2,890 10 — — Value (£). United Kingdom New Zealand 16,282 12 • 5 — „ = Total from British Possessions 16,282 17 — — — Belgium Germany Netherlands Japan 958 60 19,032 43,556 10,291 61 — — Total from Foreign Countries 63,606 10,291 61 — — Total 79,889 10,308 61 — — New Zealand.* The known phosphate deposits of New Zealand are of small size, and, with the exception of those in the Clarendon-Milton district of Otago, of httle commercial importance. The phos- phates in the Milton district occur as segregations in Limestones of Miocene age. Parcels of high-grade rock yield 30 to 36-7 per cent, phosphorus pentoxide, equivalent to 65-3 to 80-2 per cent, tri-calcium phosphate. The total iron oxide and alumina varies from 1'4 to 9 per cent. Superphosphate production increased considerably durin<^ the war m New Zealand, which will in the future share the out*' put of Nauru Island with Australia and the United Kingdom Zell^l^Tcfrnuair"" '*^*'"'°*^ ^^°''"^'^- ^^^^^ ^^ Shipping of Ne, 47 Production of Phosphate- Rock in New Zealand. Quantity Year. (long tons). 1913 11.000 1914 1915 1916 1917 1918 1919 Imports of Phosphate-Rock and Guano i 10,743 7,600 5,050 5,000 4,000 nto New Zealand- Quantity (long tons). 1913. 1914. 1915. 1916. 1917. 1918. 1919. United Kingdom 17 16 35 25 ! - 1 20 India — — — — — 1 Seychelles — 5,150 4,350 — — — Straits Settlements ... — 5,779 300 — — — Australia 643 1,638 4,279 6,185 5,362 1,879 3,184 Gilbert and EHice 92 -_i_ 4,000 . Islands Maiden Islands 4,823 5,269 1,885 — — — — Total from British 5,575 17,852 10,849 10,210 5,362 1,880 3,204 Possessions Madagascar 2,848 3,410 . New Caledonia 3,217 — 5,234 2,171 6,124 5,084 7,851 Society Islands — 24 — 545 250 — Tuamotu Archipelago — — 20,026 16,366 24,922 22,901 29,561 Total from Foreign 3,217 2,872 28,670 19,082 31,296 27,985 37,412 Countries Total 8,792 20,724 39,519 29,292 36,658 29,865' 40,616 Value (£). United Kingdom 131 130 656 241 _ 10' 462 India — — — — — 3 - Seychelles — 13,298 13,730 — — — 1 — Straits Settlements ... — 13,257 1,260 — — — i — Australia 2,052 5,877 16,019 21,289 17,937 6,010 10,752 Gilbert and EUice 284 — — 5,720 — — — Islands Maiden Islands 13,311 15,174 4,664 — — — — Total from British Possessions Madagascar 15,778 47,736 36,329 27,250 17,937 6,023 11,214 9,255 11,458 — — — — New Caledonia 7,811 — 12,166 4,042 10.342 10,169 17,435 Society Islands — 74 — 1,009 412 — — Tuamotu Archipelago — — 45,578 22,664 41,271 37,945 65,209 Total from Foreign Countries Total 7,811 9,329 69,202i 27,715 52,025 48,114 82,644 23,589 57,065 105,531 54,965 69,962 54,137 93,858 48 mports of all other Phosphates into New Zealand • From Quantity (long tons). 1914. 1915. 1916. 1917. 1918. 1919. United Kingdom Egypt India Australia 325 1 436 1 10,140 385 11,225 5 50" 120 100 10,000 Total from British Posses- sions 326 436 10,526 11,280 120 10,100 Belgium Germany Netherlands United States 199 424 50 10 80 — — Total from Foreign Coun- tries 683 80 — — — — Total 1,009 516 10,526 11,280 120 10,100 Value (£) United Kingdom Egypt India Australia 1,064 9 9 1,641 21 39,032 1,627 43,217 47 138 383 583 49,500 Total from British Posses- sions 1,073 1,650 40,680 43,402 383 50,083 Belgium Germany Netherlands United States 703 1,474 180 25 239 — — — — Total from Foreign Coun- tries 2,382 239 — — — — Total 3,455 1,889 40,680 43,402 383 50,083 49 Imports of Superphosphates into New Zealand. Vmm Quantity (long tons). 1914. 1915. 1916. 1917. 1918. 1919. United Kingdom Australia 13,923 6,119 5,915 33,603 406 28,055 24,793 33,499 17,604 Total from British Pes- sesBiona 20,042 39,518 28,461 24,793 33,499 17,604 Belgium Germany Netherlands United States Japan 178 18,511 11,077 50 6,283 277 1,196 13,259 5,869 3,954 — — Total from Foreign Countries 36,099 14,732 5,869 3,954 — — Total 56,141 54,250 34,330 28,747 33,499 17,604 Value (£). United Kingdom Australia 48,954 25,428 20,580 136,507 1,444 121,229 120,355 16 174,328 96,638 Total from British Pos- 74,382 157,087 122,673 120,355 174,344 96,638 Belgium Germany Netherlands United States Japan 672 62,267 37,925 163 24,526 885 8,322 51,956 17,417 19,088 1,035 — Total from Foreign Countries 125,553 61,163 17,417 19,088 1,035 — Total 199,935 218,250 140,090 139,443 175,379 96,638 Nauru Island.* Immense deposits of phosphate-rock occur in the island of Nauru, which is situated just south of the equator, in longitude 167° E. The material is easily mined, and shipping facilities are favourable. The reserves on the island are estimated at from 80 to 100 million tons of phosphate-rock carrying 85 to 86 per cent, of tri-calcium phosphate. During the war, this island was captured from the Germans, and, under Article 6 of the Nauru Island Agreement Bill, the title to the phosphate deposits on the island is vested in a Board of Commissioners appointed by the Govern- ments of the United Kingdom, the Commonwealth of Australia, and the Dominion of New Zealand, the arrangement providing • Board of Trade Journal, 1919, Dec. 18, p. 771. The New Zealand Journal of Agriculture, Dec, 1920, p. 297. 50 that 84 per cent, of the output should be divided equally between the United Kingdom and Australia, and that the New Zealand share should be 16 per cent. Formerly these deposits, as well as those on Ocean Island, were owned by the Pacific Phosphate Company of London and Mel- bourne, but under the new arrangement the cdmpany's rights and property were transferred in July, 1920, to the Board of Commissioners. The phosphate occurs in surface deposits which are scattered over the whole interior of Nauru Island. The underlying rock is a hard compact coral limestone which in places has beeni greatly denuded, the harder portions being left standing as pinnacles which may attain a height of 30 feet. The phosphate-rock is found chiefly between these pinnacles and often covers them entirely. Quarrying operations are carried out by pick-and-shovel methods, the excavated material being transported to the tram- ways by cable hoists and subsequently crushed and dried. Ship- ping operations have presented a difficult problem, but this has now been solved by 'putting down mooring-buoys close inshore, in about 1,000 feet of water, at which vessels can load from lighters in fine weather. Phosphate Produced in and Exported from Nauru Island* Year. Eaised Shipped (long tons) . (long tons). 1913 133,000 133,000 1914 72,000 54,000 1915 92,000 85,000 1916 97,000 104,000 1917 98,000 97,000 1918 83,000 80,000 1919 60,000 Ocean Island.! 68,000 Ocean Island is one of the Gilbert Islands, which, with Elhce Islands, form the Gilbert and Elhce Islands Colony. It is administered by a High Commissioner through a Eesident Com- missioner stationed at Ocean Island. The phosphate-rock is found in surface deposits of large size and has a very high degree of purity. The best deposit is on the central tableland, where beds of rock-phosphate extend to a depth of 50 feet. Their origin is attributed to the leaching of guano and the replacement of the underlying limestone by phos- phatic solutions. * Information supplied by the British Phosphate Commissioners, Loudon t N.Z. Journ. Agric, Dec, 1920, p. 312. 51 The phosphate is mined by removing the overburden and breaking out the rock with pick and shovel. The excavated material is run down from the tableland by gravity tramway to driers and bins near the jetty. Owing to the lack of harbour accommodation, vessels are obliged to load at sea. The phosphate is carried by car to the jetty and there loaded into baskets, which are conveyed by boat to the ship. The annual output during the period under review ranged from 215,000 to 53,000 tons of 85 per cent, phosphate. It has been estimated that the reserves of high-grade rock on Ocean Island exceed 50 million tons. As in the case of Nauru Island, the future output of Ocean Island phosphates will be shared by New Zealand, Australia, and the United Kingdom. Phosphate Produced in and Exported from Ocean Island * Year. Eaised Shipped (long tons) . (long tons). 1913 ... '215,000 •205,000 1914 ... 158,000 153,000 1915 ... 126,000 130,000 1916 ... 105,000 93,000 1917 ... 101,000 93,000 1918 70,000 73,000 1919 53,000 64,000 FOREIGN COUNTRIES. Belgium.! Phosphates occur in Belgium, either as beds of phosphatic nodules in a matrix of clay, or as beds of phosphatic chalk in Tertiary and Cretaceous rocks. Before the high-grade American and Pacific Islands deposits were developed, the Belgian phos- phates were of considerable importance, but latterly the oatput has greatly declined, as the average grade of the rock obtainable is only 40 to 45 per cent, tri-calcium phosphate. The principal phosphate-mining region is situated at Ciply and Mesvin, near Mons, in the battle area of Flanders. Before the war Belgium was an important manufacturer of superphosphate. The industry was centred at Antwerp, and there were 33 factories manufacturing superphosphate, six- teen of which made their own acid. Large quantities of high- grade rock were imported from Algeria, Tunis and Florida, while some wa.s obtained from Aruba in the West Indies and also from the Somme district in France. The low-grade domestic rock wa.f mixed with high-grade imported phosphates. Exports of superphosphates were on a large scale, the bulk being shipped to Frajice, Spain, Germany, the Netherlands, Great Britain and Portugal. • Information supplied by The British Phosphate Commissioners, London, ■f Statistique des Industries Extractives et M^tallurgiques en Belgique (Annual). 52 Production of Phosphates in Belgium. Phosphate of Lime. Phosphatic Chalk. Year Quantity (long tons). Value* (£). Quantityf (long tons). Value* (£). 1913 1914 1915 1916 1917 1918 1919 215,894 103,637 16,087 76,491 136,077 60,708 89,508 78,246 41.789 71472 53,356 61,174 60,520 123,180 186,000 188,000 67,000 178,000 61,000 168,000 89,000 12,486 9,747 3,035 9,248 11,400 16,344 20,460 * Values converted to £ sterling at the rate of 25 francs = £1. t Quantity converted to tons assuming 1 cu. yd. of phosphatic chalk=:li ton. Phosphate-minrng in Franc© is cx>nfined to the departments of the Aisne, Ardennes, Meuse, Oise, Pas d© Calais and Somme, all of which were in the war area. In the Aisne, Oise, Pas de Calais and Somme districts, the rock occm"s for the most part as phosphatic chalk beds of Upper Cretaceous age. In the Meuse, Ardennes and Marne districts, the phosphates occur in the Lower Cretaceous Greensands, in narrow bands from 2 to 10 inches in thickness. Before the war the annual output of superphosiphate was approximately 1,890,000 tons, from 75 factories. Imports of high-grade rock were obtained chiefly from Tunis, the United States and Algeria, with smaller quantities from Egypt, the Pacific Islands and Belgium. Formerly the French domestic deposits were of considerable importance, but, as the grades range from 40 to 66 per cent, tri-calcium phosphate, they are now unable to compete with the cheaper high-grade phosphates of Florida and Nortli Africa, and production has consequently declined. In Algeria, Tunis and. Morocco, France possesses large re- sources of phosphate. In her Pacific possessions, particularly on the islands of Tahiti and Makatea, in the Society group, further large reserves of high-grade phosphate are being worked! Phosphate deposits are also mined on the island of Salut, and on the Grand Connetable Island, near the coast of French Guiana. During the war the production of superphosphates in France decreased considerably, chiefly owing to difficulty in obtaining supplies of sulphuric acid, large quantities of which were used for munition purposes. . % Statistique de I'Industrie Min^rale en France et en Alg^rie (1914-1918) 53 French Production, Imports and Exportu of Phosphates and Superphosphates. Quantity (long tons). Year Phosphates. Superphosphates. Production. Imports. Exports. Production. Imports. Exports. 1913 1914 1915 1916 1917 1918 1919 330,000 270,000 25,500 925,671 650,799 320,527 281,311 132,613 229,648 494,562 20,802 10,811 1,767 1,699 617 35 1,889,000 1,574,000 590,000 344,000 239,000 405,000 99,202 57,220 13,812 4,056 1,853 6.071 12,748 142,894 115,347 58,862 12,164 3,789 2,837 Germany. There was probably no country which gave so much careful attention to the use of phosphates in agriculiture in the pre-waj period as Germany, and, while the United Kingdom was the first producer of superphosphate, there is no doubt that German practice was very largely responsible for the rapid development of its use as a fertilizer. The German consumption of raw phosphate in 1913 was approximately one million tons, equivalent to a production of, say, 1,800,000 tons of superphosphate. No deposits of phosphate-rock of commercial importance were at that time known in Germany, and consequently the whole of the rock required was imported, principally from the United States, Tunis, Algeria and Belgium. Before the war Germany possessed very large reserves of high- grade phosphate in the deposits of various Pacific islands, par- ticularly those worked on the Island of Nauru. This island was captured by the Australian Fleet shortly after the outbreak of war, and the phosphate deposits have since been acquired by the Governments of United Kingdom, Australia and New Zealand. The blockade which was instituted against Germany imme- diately on the outbreak of war prevented the importation of phosphates from foreign sources. Superphosphate consequently became very scarce and dear, and its place had to be taken as far as possible by basic-slag. Even with the increased production of basic-slag there was still a very grave shortage of phosphates in Germany, and every effort was made to discover workable deposits within the country. It was not until 1918, however, that a deposit was found close to Amberg, in the vicinity of Nuremberg, Bavaria. This deposit 54 attains a thickness of about ten feet in many places, and is in the form of bi-basic phosphate of hme. In certain workings a product was found conitaining 80 per cent, tri-calcium phosphate. In places, however, the percentage was as low as 30. The deposit as a whole has been estimated to average 35 per cent, tri-calcium phosphate. Holland.* During the period under review, efforts were made to discover deposits of phosphate-rock in Holland. Deposits carrying 25 to 30 per cent, phosphate of lime were found in the Drenthe and Overyssel provinces of north-eastern Holland, and a factory was erected to prepare the material for market. A bed of phosphate- rock, varying in thickness from 7 inches to 3 feet, was found at Ootmarsum, in the Twente district. The rock contains on an average from 15 to 20 per cent, phosphate of hme, but, on account of the irregularity of the bed, it is difficult and expensive to mine, and only about 30 tons are produced daily. Holland produces a large amount of superphosphate and before the war had an exportable surplus. Italy. A deposit of rock-phosphate has been proved to cover an exten- sive area near Donna Lucata, south of Syracuse, in Sicily. The phosphates -occur as nodules, varying in size and containing up to 33 per cent, of tri-calcium phosphate. It is estimated that the deposit contains about 2,000,000 tons of available phosphate- rock. Imports of Phosphates into Italy. Year. 1913 1914 1915 1916 1917 1918 1919 Quantity (long tons) . 521,262 505,737 449,558 427,727 226,460 227,956 442,096 Norway, f At Oedegaarden, near Kragero, in Norway, important deposits of apatite have been mined continuously for many years, the mineral occurring as veins traversing gabbro. Previous to 1914 more than 140,000 tons of mineral had been extracted from the deposits in this district, the yearly output averaging about 740 tons. * American Fertilizer, 1920, 52, No. 5, 138. t Gorges Bergyerksdrift (Annual). Report on the Commerce and Industry f Norway (Department of Overseas Trade, liondonV 55 Production of Apatite in Norway. Year. Quantity Value* (long tons). (£). 1913 ... 745 1,613 1914 ... 738 1.613 1915 ... 1,870 5,108 1916 ... 2,200 7,634 1917 ... 1,803 17,204 1918 ... : 4,489 51,613 1919 ... * Values converted to £ sterling at the rate of 18'6 Kroner = £1. Imports of Phosphate-Bock and Superphosphates into Norway. Year. Phosphate-rock Superphosphates 1913 1914 1915 1916 1917 1918 1919 (long tons). (long tons). 4,322 9,021 2,715 10,964 '. 4,526 36,831 . 22,622 — . 14,687 11,252 . Russia. Phosphate deposits of great importance occur in the Jurassic and Cretaceous rocks in the provinces of Vladimir, Krostrom, Viatka and Yaroslav, in! northern Russia, and in the governments of Podolia and Bessarabia in the south. Before the war, the southern deposits only were worked, chiefly by underground mining operations. The rock, which is said to have averaged about 75 per cent, of tri-calcium phosphate, was transported to Poland for manufacture into superphosphates. The deposits are estimated to contain about 80 million tons of phosphate-rock. The northern deposits have so far not been worked, but careful geological examination has shown that they contain important quantities of phosphate. In addition to ,these two main phosphate-bearing regions, deposits of Cretaceous phosphate>-rock are reported to occur in the governments of Smolensk, Saratoff, Orel, Kazan and else- where in Central Prussia. Production statistics for the period under review are in- complete. The' outputs for 1913 and 1914 are estimated at 25,000 and 15,000 tons respectively. As a result of the revolution, the superphosphate factories of Russia have suffered to a very serious extent, and it was not until 1919 that the Soviet Government made any serious attempt to provide the Russian peasant with supplies of superphosphate. The principal Russian factories were situated at Petrograd, Kineschma and TvTijni Novgorod, and efforts were in the main 56 directed to using phosphate-rock of native production for the manufacture of superphosphate. The extent to which these efforts succeeded is not known. Spain.* The only phosphate deposits extensively worked in Spain are apatite veins at Aldea Moret, in the province of Caceres. Large quantities of phosphate-rock are imported annually, chiefly from Tunis, Algeria and the United States. The high- grade Florida rock imported from the United States is used chiefly in northern Spain and Catalonia for making high-grade superphosphate. In the soujth the demand is for lower-grade superphosphate. The decrease in imports during 1917 aaid 1918 was due to difficulties in procuring freight and export licences from the United States, and not to any diminution in the demand for phosphate. In 1913, about 600,000 tons of superphosphate were consumed in Spain, of which about 37 per cent, was manufactured in that country, the remainder having been imported from England, France, Belgiuni and Holland. Production and Imports of Rock-Phosphate in Spain. Year. 1913 1914 1915 1916 1917 1918 1919 Production, Imports and Consumption of Superphosphates in Spain. Production. Imports. Quantity Quantity (long tons). (long tons) 3,491 250,373 8,178 198,804 8,934 208,676 13,884 283,694 27,696 128,326 42,607 113,196 24,633 115,986 Production. Importsf. Consumption. Tear Quantity Quantity Quantity (long tons). (long tons). (long tons). 1913 221,000 . 147,820 600,000 1914 . 216,000 115,018 , 1915 . 191,037 63,212 469,717 1916 . 310,112 22,686 479,800 1917 . 353,045 11,911 418,222 1918 . 125,434 11 278,281 1919 . 133,348 5,605 * Estadistioa Minera de Espana. Estadistica General del Comercio Exterior de Espana. The American Fertilizer, 1920, 52, No. 5, 142-144. f Including Thomas phosphate. 57 Algeria.* Large deposits of I'ock-phosphate occur in Algeria, in strata of Eocene age. The two moBt important mining districts are situated near the towns of Setif and Tebessa, in the eastern part of the country. lu 1906 a French company obtained a concession over the important deposits situated in the commime of Bordj-Eedir, in the Setif district, where ithe rock is mined either opencast or by tuimels, and is transported 12 miles by ropeway to the railway. In the same district, deposits are being worked in the commune of Tocqueville, where the phosphaite beds vary in thickness from 1 foot to 6 feet. Another French company is working the exten- sive M'Zaita deposit in the commune of Maadids. The reserves of rock-phosphate at this mine have been estimated to amount to 16,500,000 tons. Throughout the Setif district the grade of the phosphate-rock averages between 58 to 63 per cent, of tri-calcium phosphate. The most important deposits in Algeria axe those at Djebel Kouif, neajf Tebessa. The phosphate occurs in a basin-shaped deposit composed of five sepajrate beds, three of which are work- able. The thickness of the beds worked varies from 1| feet to 9 feet. Where the overburden exceeds 24 feet the rock is worked by inclined tunnels, otherwise opencast methods are adopted. A branch railway, 16 miles in length, connects the mine with the railway from Tebessa to the port at Bona, but this railway is only capable of transporting about 330,000 tons of rock annually. The output from the mine is consequently controlled by the rail- way facilities, and not by the potential resources of the deposit. Throughout the Tebessa district the average grade of the phosphate-rock runs from 58 to 68 per cent, tri-calcium phosphate. Superphosphates are manufactured at Bona, Algiers and Oran, by a company which manufactures its own sulphuric acid, and which before the war was the only company producing super- phosphate in Algeria. There are several known deposits of phosphate-rock in Algeria which, up to the present, have not been worked ; the most important of these are Djebel Onk and Maadids. The fonner deposit is one of the largest known, and from the surveys which have been made it is estimated to contain at least 1,000,000,000 tons of high-grade rock containing from 60 to 70 per cent, tri-calcium phosphate. This deposit is situated about 50 miles to the south of Tebessa, in the district bordering on the Sahaxa desert., and is approximately 125 miles from the sea-ooast of Algeria. At present there is no rail connection beyond Tebessa, and the line between Tebessa and Bona is fully ta.xed in conveying the phosphate produced from the mines at Djebel Kouif, referred to above. • atatistique de I'Industrie Min^rale en France et en Alg^rie ("1914-1918). The Conservation of Phosphate- Rock in the United States, by W. C. Phalen, Trans. Amer. Inst. Min. Eng., 1917, 57. 129-130. 58 The Algerian Government has for some time past been study- ing the question of improving the railway connection between Tebessa aind Bona, and making the necessary extension of the line to Djebel Onk, and there appears to be very little doubt that, as soon as the necessary works have been carried through, the Djebel Onk deposit will be exploited. It should be observed that the whole of the district around Tebessa is very rich in minerals, and more especially iron ore. Consequently, in their project for the improvement of the rail- way, the Algerian authorities are looking to the extension of iron- mining in Algeria in addition to the exploitation of the Djebel Onk phosphate deposit. With |the improvement of railway con- nections, Algeria should make a very substantial advance as a phosphate producer. Imports and Exports of Fertilizers into and from Algeria. Exports (long tons). Imports (long tons). Vmi- Phosphates. Superphosphates. Superphosphates.1 ,^ffi*-f ^t. 1913 431,552 7,877 17,872 1914 349,432 3,275 7,139 595 1915 222,261 21,766 1,143 276 1916 382,956 6,776 1,497 1,140 1917 231,051 545 314 171 1918 199,284 13,187 9 129 1919 238,294 14,342 1 Tunis.* Tunis is second only to Florida as a producer of phosphate. In 1913 the Tunisian exports amounted to about 2 million tons. The regency is very rich in phosphate deposits, and, while many of the most important phosphate beds are being worked, there are several of potential commercial importance which have not yet been developed. In generai the deposits are situated in the south of the regency and toward the Algerian border, between the 34th and 36th parallels of N. latitude, and between .the 8th and 9th degrees of E. longitude. The richest deposits occur as lenses of great extent in rocks of Middle Eocene age. The thickness of these lenses varies from a few inches up to 10 feet, but the phosphate obtainable from the lowest Eocene beds is usually of low grade. The principal centre of the phosphate-mining industry in the regency is Gafsa, in the neighbourhood of which are situated the most important deposits of the country. The grade of rock produced varies from 58 to 68 per cent tri- calcmm phosphate; it is very friable, and is one of the types of * Statistique Gen^rale de la Tunisie (Annual). 59 rock most easily converted into superphosphate. Owing to its soft character, it is easily ground and readily worked through superphosphate plants. Practiciully the whole of the output from this region is con- trolled by one mining company, but there is a second company at present engaged on the preliminary work of opening up an im- portant deposit. Tliis deposit is situated about 9J miles south of Ciafsa at Djebel M'Dilla. The next most important deposit is situated at Kalaa Djerda, which is close ito the Algerian border, and is within about 6 miles of the important Algerian deposit of Djebel Kouif . This deposit is worked in conjunction with that of Maknassy — the product of the Kalaa Djerda mine being shipped from Tunis, and that of Maknassy from Sfax. The other deposits in Tunis which are actually being worked are Kalaa,t es Senam, north-west of the KaJaa Djerda deposit, and Kef Eebiba to the north of that deposit. Both these mines ship their phosphate from the port of Tunis. Practiailly the whole of the Tunisian deposits may be divided into two categories — the lower grade, containing from 58 to 63 per cent, tri-calcium phosphate, and the higher grade, from 63 to 68 per cent. The moisture content averages about 4 per cent., and generally speaking, these phosphates con- tain less ithan 2 per cent, of iron oxide and alumina. The Tunisian phosphate mines suffered very severely from the effects of the war, as the appended statistics show, the pro- duction falling from 2,038,476 tons in 1913 to 820,000 tons in 1919. Tunisian Production and Exports of Phosphates. Production of Exports of Exports of PhoBphatea. Phosphates. Superphosphates. Yciir. Quantity Value Quantity Value Quantity Value (long tons). (£).* (long tons). (£).♦ (long tons). (£).* 1913 2,038,476 1,820,889 1,952,9X0 1,984,880 13,235 37,663 1914 1,373,171 1,283,960 1,404,225 1,312,989 3,213 9,141 1915 1,151,196 1,076,400 1,096,164 1,024,943 10,423 i 29,659 1916 1,024,466 1,041,204 1,018,108 951,959 17,304 49,244 1917 665,726 947,234 602,595 563,446 7,343 2U,896 1918 848,632 1,034,993 923,006 863,035 22 62 1919 820,000 1,129,000 1,520,000 • Values converted to £ sterling at the rate of 25 francs ^ £1. Dutch West Indies. Extensive deposits of phosphate occur in Curasao and Aruba, two islands off the coast of Venezuela. In 1913, phosphate-mining was resumed in Cura9ao after a suspension of twenty yeais. The deposits are of exceptional 60 grade, contaming from 80 to^ 85 per ceat. of tri-calcium phosphate, with less than 1 per cent, of combined iron oxide and alumina^ The rock is very hard, however, and difficult to break up. An English company owns the. property, and minmg operations are bemg actively carried on at the Santa Barbara mines. Before the war the bulk of the output was shipped to Germany and England. Exports of Phosphates from Curagao. Quantity (long tons) . 39,000 96,000 Year. 1913 1914 1915 1916 1917 1918 1919 30,805 14,235 3,524 9,890 United States.* The United States is the largest producer in the world of phosphate-rock and manufactured superphosphates. The southern States of Florida, South Carohna and Tennessee, have for many years been the main source of phosphate-rock in the United States, but recent investigations have shown that in addition to these deposits, there are large reserves of phosphate- rock in the States of Arkansas, Wyoming, Utah, Idaho and Montana. In Florida four distinct types of phosphate-rock have been recognized, viz., land-pebble, hard-rock, soft-rock, and river- pebble. Of these the land-pebble deposits are the most important, and the hard-rock next in value, while the river- pebble beds are now no longer worked. The land-pebble and hard-rock varieties are exported largely. The soft-rock is worked for home consumption only. The land-pebble deposits are of Pliocene age, and consist of a conglomerate of sand, clay and pebbles formed by marine action. They cover a large area in Polk and Hillsboro counties, occurring in beds from 8 feet to 20 feet in thickness. From 10 to 25 per cent, of the whole deposit is stated to be composed of phosphatic material. The average tri-calcium phosphate content of the marketed material ranges from 60 to 79 per cent. The deposits are worked by hydraulic methods after the removal of the overburden. The phosphates thus obtained are first * The United States Geol. Siirv. Mineral Resources (Annual). The Mineral Industry (Annual). 61 washed to remove a proportion of the sand and clay, and then passed through log-washers. The clean product is dried in kilns and then stored for shipment. Only the hard pebbles are re- covered, practically all the soft phosphate going to the v?aste- dump. The hard-rock phosphate occurs as boulders in a soft matrix of phoaphatic sands and clays, the whole deposit resting on lime- stones of Lower Oligocene age. The principal hard-rock mining region extends in a belt from Suwanee, in the north, to Pasco county, in the south, a distance of over 100 miles. The hard- rock varies from a massive ajid compact structure, to a light and porous material, and ranges in ooloui" from deep bla<;k ito almost white. The phosphate content of the hard-rock deposits varies from 10 per cent, to more than 30 per cent, of the mass. Probably not more than 15 per cent, of the material mined can be con- sidered of marketable value. Practically all the material sold is guaranteed to carry not less than 77 per cent, tri-calcium phos- phate. After the removal of the overburden, usually by hydraulic methods, the phosphate-rock exposed is broken by pick and shovel if the deposit is dry, or by dredging methods if there is much water. The excavated rock is crushed, washed, and dried in kilns preparatory to shipment. During these operations it is estimated that twice as much phosphoric acid is wasted in the material sent to the waste-dump as is contained in the material sold. Three types of phosphate deposits are recognized in Tennessee according as the material is brown, white or blue. The brown phosphate is found abundantly in the south-west of the central Tennessee basin, notably in the vicinity of Mount Pleasant. The deposits occur either as residual products, or as blanket deposits, both of Ordovician age. Mining is carried out opencast by mechanical excavators or by tunnels driven into the hill-side. The broken rock is washed, screened, and sold under a guarantee of from 70 to 80 per cent, of tri-calcium phosphate. The white phosphate is directly associated with Silurian lime- stone. There are three varieties, viz. : (1) stony, carrying less than 50 per cent, of tri-calcium phosphate; (2) brecciated, which consists of large masses of phosphate of Ume cementing fi-agments of chert ; and (3) lamellar, consisting of thin layers of phosphatic material derived from the overlying Devonian rock. Both tlie lamellar and the brecciated deposits carry as much as 85 per cent, tri-calcium phosphate. The blue phosphate occurs in bedded deposits of Devonian age. The thickness of the beds varies from a few inches up to about i feet, but the high-grade rock is rarely more than 28 inches in thickness. After the overburden has been stripped the rock is excavated by mechanical shovels and crushed fine. The phos- phatic content of the beds varies from 30 to 85 per cent, tri- calcium phosphate. 62 In South Carolina the phosphates occur in a belt, about 60 miles m length, between the source of the Wando river and the mouth of the Broad river. The deposits, which are probably of Miocene age, occur in beds from 1 to 3 feet in thickness, over- lain by 3 to 18 feet of greensand marl. The rock is of com- paratively low grade, containing from 55 to 58 per cent, of tn- calcium phosphate. The western phosphate field covers an area of about 2^ million acres in the States of Idaho, Wyoming, Utah and Montana. The phosphate occurs as well-defined beds of exceptional regularity in rocks of Carboniferous age. The beds vary in thickness from 3 to 6 feet, and contain on an average over 65 per cent, of tri- caleium phosphate. The United States Geological Survey is still engaged in examining these extensive deposits. It has been estimated that the reserves amount to more than 5,750,000,000 tons of high- grade rock within a depth of 5,000 feet from surface. In addition to the occurrences in the regions mentioned, there are extensive deposits of phosphate-rock in Independence county, Arkansas, where the mineral occurs in beds from 4J to 6 feet in thickness, in Ordovician rocks. Manganese ore is commonly associated with this phosphate^rock which carries from 56 to 71 per cent, of tri-calcium phosphate. The rock is mined by means of adits and drifts, and the produce is sold locally. Production and Sales of Phosphate-Rock in the United States. Production. Sal es. Tear Quantity Quantity Value* (long tons). (long tons). (£). 1913 3,152,208 3,111,221 2,457,548 1914 . 2,649,174 2,734,043 2,001,675 1915 . 1,935,341 1,835,667 1,127,802 1916 . 2,169,149 1,982,385 1,228,540 1917 . 2,851,886 2,584,287 1,618,976 1918 . 2,284,245 2,490,760 1,711,346 1919 . 1,851.549 2,271,983 2,414,847 Exports of Phosphates from the United States. Quantity (long tons). Total Year Hard Rock. Land Pebble. All Other. Total. Value* (£). 1913 473,533 891,263 1,712 1,366,508 2,082,621 1914 281,806 681,241 1,067 964,114 1,410,761 1916 34,572 218,472 377 253,421 344,136 1916 28,631 214,358 689 243,678 240,915 1917 12,403 138,010 15,945 166,358 173,968 1918 57,771 64,559 21,561 143,891 190,101 1919 215,039 128,860 34,832 378,731 743,330 * Values converted to £ sterling at the rate of 1 dollar=4s. 2d. 63 Exports of Phosphate-Rock (Land-Pebble) from the United States {Domestic Produce). (Fiscal years ending June 30.) Quantity (long tons). To 1914. 1915. 1916. 1917. 1918. 1919.t United Kingdom 159,220 93,112 86,016 39,033 37,215 45,991 Canada Australia 118 3,000 5,132 3,734 4,004 5,545 1,202 Total to British Posses- 159,338 101,244 89,749 43,037 42,760 47,193 sions Austria-Hungary 3,000 _ , Belgium 129,537 11,800 4,769 Denmark 6,200 9,000 — 17,943 France 159,927 6,900 14,537 14,536 10,438 Germany 122,316 5,550 — — Italy 114,601 ' 22,056 2,864 6,069 1,440 Netherlands 124,579 15,084 45,289 28,686 — 26,953 Portugal 4,800 — 3,500 — — Spain 53,928 51,839 76,987 61,897 32,359 16,072 Sweden 34,400 — 23,280 17,867 4,357 12,250 Cuba — "~" — 6,002 14,786 8,449 Japan 88,004 — — — Total to Foreign 841,292 121,228 165,457 135,057 68,149 81,667 Countries Total 1,000,630 222,472 255,206 178,094 110,909 128,860 Value ( £)■• United Kingdom 192,754 112,192 88,192 27,416 31,841 70,022 Canada 117 3,750 4,222 3,173 4,481 1,001 Australia — 5,346 — — — Total to British Posses- sions 192,871 121,288 92,414 30,589 36,322 71,023 Austria-Hungary 3,750 Belgium 159,419 14,021 3,527 — Denmark 7,750 10,000 33,703 France 196,.584 7,375 11,037 8,051 8,703 — Germany 144,614 6,312 — — — — Italy 139,491 25,423 3,580 3,414 900 — Netherlands 152,454 17,481 53,011 27,246 — 38,595 Portugal 6,000 — 4,375 — — — Spain 65,410 64,092 85,972 54,796 31,556 22,613 Sweden 43,000 — 25,627 18,388 5,011 15,618 Cuba — — — 4,443 9,060 6,845 Japan 109,067 — — — Total to Foreign 1,027,539 144,704 183,602 116,338 58,757 117,374 Countries Total 1 1,220,410 265,992 276,016 146.927 95,079 188,397 • Values converted to £ sterling at the rate of 1 dollar=4s. 2d, t Calendar year. 64 Exports of Phosphate-Rock (High-grade Hard-Rock) from the United States (Domestic Produce). (Fiscal years ending June 30.) Quantity (long tons). To 1914. 1915. 1916. 1917. 1918. 1919.t United Kingdom 19,658 6,110 1,860 — British Honduras — — 5 — — — Canada — — 147 300 235 752 Total to British Possessions Austria-Hungary 19,658 6,110 152 300 2,085 752 23,466 — — Belgium 19,405 — — — 16,161 Denmark 19,200 5,302 4,400 — — 80,753 France ... 3,200 — — — — — Germany 241,560 17,838 — — — 28,062 Italy ... 10,210 — — — — — Netherlands 98,623 3,008 — — — 10,702 Norway ... — — — 3,104 8,366 18,517 Portugal 4,800 760 5,663 — — — Spain 20,493 3,421 5,920 — — 18,527 Sweden ... 14,720 9,566 28,195 11,559 13,561 37,106 Switzerland — — — — — 2,575 Mexico ... — — — 10 — Cuba ... — — — — 45 1,884 Total to Foreign 455,677 39,895 44,178 14,663 21,962 214,287 Countries Total 475,335 46,005 44,330 14,963 24,047 215,039 Value ( £).* United Kingdom 40,954 12,729 1,927 British Honduras — — 10 Canada — — 312 751 732 2,957 Total to British 40,954 12,729 322 751 2,659 2,957 "PosRPastirtns Austria-Hungary 48,887 , _ Belgium 40,427 — — — . 33,669 Denmark 40,000 11,046 9,167 — . 172,608 France ... 6,667 — — — Germany 503,250 37,162 — — 62,663 Italy ... 21,271 — — — Netherlands 205,465 6,267 — — . 27,947 Norway ... — — — 6,467 12,752 41,883 Portugal 10,000 1,583 11,798 — — Spain 42,694 7,127 12,333 — — 41,720 Sweden ... 30,667 19,929 55,782 24,137 20,766 78,135 Switzerland — — — — 51,217 Mexico ... — — — — 22 Cuba ... — — — — 128 4,420 Total to Foreign Countries 949,328 83,114 89,080 30,604 33,668 468,262 Total . .. 990,282 95,843 89,402 31,355 36,327 471,219 * Values converted to £ sterling at the rate of 1 dollar = 4s. 2d. t Calendar year. 65 Exports of all other kinds of Phosphate from the United States (Domestic Produce). (Fiscal years ending June 30.) To Quantity (long tons). 1914. 1915. 1916. 1917. 1918. 1919.t United Kingdom British Honduras Canada British West Indies Australia Total to British Posses sions Netherlands Norway ... Mexico Cuba Dutch East Indies Other Foreign Countries Total to Foreign Coun- tries Total United Kingdom British Honduras Canada British West indies Australia Total to British Posses- sions Netherlands Norway ... Mexico ... Cuba Dutch East Indies Other Foreign Countries Total to Foreign Coun- tries Total 1,856 1,856 50 50 1,906 2 885 337 1 2,865 887 337 2,866 13 2,182 1,460 13 3,642 2,500 8,824 298 500 12,122 3,975 1 6,525 1 1 5,303 126 5,431 3,500 2,200 2 4,156 19,543t 10,501 29,401 887 350 6,508 22.623 34,832 Value {£): 1,282 1,282 76 76 1.358 1 1,225 1,226 1,226 619 619 18 18 637 2 5,845 5,847 4,318 3,895 8,213 14,060 2,604 17,426 605 1,250 21,885 4,969 25 14,532 19,526 41,411 1 1 14,783 622 15,407 12,396 3,6G8 15 15,454 36,773t 68,306 83,713 • Values converted to £ sterling at the rate of 1 dollar = 4s. 2d. t Including Belgium, Denmark and Sweden. J Calendar year. French Guiana. Deposits of phosphate-rock on Grand Connetable Island have been worked for many years by an American company. The average annual output for the period 1910 to 19ia, mdusive, was about 6,000 tons. Production has decUned since that date, and the deposit appears to be approaching exhaustion. 340S2 66 Japan.* For maaiy years beds of low-grade phosphate of Ume have been worked in the provinces of Noto, the Bonin Islands, and in Formosa,, but the quantity of phosphate obtamed has been small. Important deposits occur on the island of Ea,sa, one ot the Lu-chu Islands, but examination has shown that these carry a high percentage of iron oxide and alumina, which renders their use for the manufacture of superphosphate difficult and expensive. Japan now controls the important deposits of rock-phosphate on Angaur Island, one of the Pellew group, formerly a German possession. From two to three million tons of high-grade rock are estimated to be contained in the deposits on this island, which are now worked to supply the Japanese fertiUzer factories. The Japanese also possess considerable reserves of rock-phos- phate in the deposits known to occur on several of the Marshall Islands and on Fais Island in the West Caroline group. The Marshall Islands deposits were formerly worked by the Germans, but both these groups of islands passed to Japan under the terms of the Peace Treaty. Japanese Production and Imports of Phosphates. ( Production of Phosphates. Imports of Phosphorite. Tear Quantity (long tons). Valuef (£). Quantity (long tons). 1913 1914 1915 1916 1917 1918 1919 18,737 37,644 56,788 112,965 119,673 189,181 120,893 28,915. 50,818 59,938 125,080 130,545 711,739 477,563 133,666 98,159 153,041 88,186 188,573 t Values c( )nv erted to £ sterling at the rate of 10 1 ren=£l. Production of Phosphates in Formosa. Quantity Year. (long tons) . 1913 5,531 1914 1,317 1915 495 1916 1,476 1917 1918 191S * statistical Reports of the Department of Agrigfllt^re apd Coniinerce Japan (Annual), ' .wcn-o, 67 Production of Phosphate- Rock in AngauT Island. Quantity lear. (long tons). 1913 • • • ... . , ... 88,500 1914 . •' ... ... 69,000" 1915 ... 29,500 1916 ... ... 29.500 1917 ... ... 1918 1919 ... Exports. Makatea. f The Compagnie Fran9aise des Phosphates owns the exclusive mineral rights on the island of Makatea. The phosphates occui- at the surface©, and are broken by pick aad shovel, the excavated material being crushed, dried, and sold on a moisture percentage basis. The rock conitains about 80 per cent, of tri-calcium phosphate, and is now shipped chiefly to New Zealand. Exports of Phosphates from Makatea and New Caledonia. Makatea. New Caledonia. Year. 1 Quantity ValueJ Quantity 1 Valuet (long tons). (£). 1 (long tons). (£). 1913 80,737 66,645 1914 71,753 58,340 2,361 4,800 1915 70,571 57,379 2,755 4,200 1916 38,654 31,428 2,424 5,914 1917 31,741 26,181 5,909 14,414 1918 39,000 1919 39,000 ;{: Values converted to £ sterling at tbe rate of 25 francB=£l, REFERENCES TO TECHNICAL LITERATURE. GENERAL. The Mineral Industry, New York (Annual with bibliography). The origin, mining and preparation of phosphate rock, by E. H. Sellards; Trans. Amer. Inst. Min. Eng., (1914), 50, 901-916. Manufacture of acid phosphate (superphosphate), by W. H. Waggaman; U.S. Dept. Agric, Bur. Soils, Bull. No. 144, 1914, 28 pp. Phosphate rock and methods proposed for its utilization as a fertiliser, by W. H. Waggaman and W. H. Fry; U.S. Dept. Agrit., Bull. No. 312, 1915, 37 pp. Apatite : a substitute for bone ash in the manufacture of bone china, by J. Keele; Mines Branch, Ottawa, Canada, Summ. Rept. for 1916, pp. 108-111. The geologic role of phosphorus, by E. Blackwelder; Amer, Journ. Sci., 1916, 4th ser., 42, 285-298. t The Amer. FertUiier, 1920, 53, No. 2, 73. The use of low-grade phosphates, by J. A. Barr; Trans. Amer. Inst. Min. Eng., (1916), 84, 474-476. v. r a The nature of the phosphates contained in mineral phosphates, by U. o. Robertson; Journ. Agric. Sci., 1916, 8, 16-25. The phosphate deposits of the world, by J. W. Gregory; Lecture at Royal Institution, March, 1917 (" Geology and the War ".). Abstr. Mining Mag., 1917, 16, 265-267. ConTersion of insoluble into "soluble" phosphates, by A. M. Johnston; Journ. Chem. Met. Min. Soc. 8. Afr., 1917, 18, 140-141. A new fertilizer, superphosphate of ammonia, by C. Brioux; C.R. Acad. Agric. France, 1918, 4, 632-638. A new phosphate fertilizer, t«traphosphate of lime, by A. Bruno; O.R. Acad. Agric. France, 1918, 4, 322-324. Reverted phosphate, by C. C. James; Journ. Ind. Eng. Chem., 1918, 10, 33-35. Use of " mine run " phosphates in the manufacture of soluble phosphoric acid, by W. H. Waggaman and C. R. Wagner; Journ. Ind. Eng. Chem., 1918, 10, 353-355. letraphosphate — a special Italian fertilizer; Amer. Fertilizer, 1919, 51, No. 11, 58-59. Economic analysis of the world shortage in phosphate, by L. B. Anderson; Amer. Fertilizer, 1919, 51, No. 7, 47-59. Coral Island phosphates in the making, by F. Danvers Power; Inst. Min. Met., Bull. No. 181, 1919, 10 ppl Phoaphatic coatings for rust proofing iron and steel, by L. E. Eckelmann ; Chem. Met. Eng., 1919, 21, 787-789. The phosphate industry, by J. Hendrick; Journ. Soc. Chem. Ind., 1919, 38, 155R-157R. The distribution and character of the world's phosphate deposits, by R. W. 'Stone; Amer. Fertilizer, 1919, 51, No. 11, 64g-69, 93, 96 and 98. Phosphorites and superphosphates from the point of view of the sulphur industry, by L. Tirelli; Chem. News, 1919, 118, 73-76. La situation de I'industrie des phosphates; L'Echo des Mines, 1920, 48, 262. Investigation on pyrolytic production of phosphoric acid, by W. H. Wagga^ man and T. B. Turley; Chem. Met. Eng., 1920, ^3, 1057-1063. The manufacture of chemical manures, by J. Fritsch; London, 1920. BRITISH EMPIRE. Egypt. Topography and geology of the phosphate district of Safaga (Eastern Desert of Egypt), by J. Ball; Ministry of Finance, Surv. Dept., Cairo, Egypt, Paper No. 29, 1913, 19 pp. A brief note on the phosphate deposits of Egypt, by J. Ball; Ministry of Finance, Surv. Dept., Cairo, Egytit, Paper No. 30, 1913, 6 pp. Phosphate in Egypt, by E. Corte6'e; Trans. Amer. Inst. Min. Eng., 1918, 59, 112-116. Die Phosphatlagerstatten in Agypten; Zeits. f. angew. Chemie 1919 32, No. 57, 461. SoTJTH Africa. E6ca phosphates of Natal, by A. L. du Toit; S. Afr. Journ. Ind., 1918, 1, 404-407. Triplite : a possible source of phosphoric acid, by A. E. V. IZealley; Rhodesia Munition and Resources Committee Report, Bulawayo, 1918, pp. 41-43. Report on the phosphates of Saldanha Bay, by A. L. du Toit; S. Afr. Geol. Stirv., Pretorta, Mem. No. 10, 1917, 31 pp. Fertilizer production and natural fertilizers in the Union, by C. P. Juritz; S. Afr. Journ Ind., 1920, 3, No. 6, 499-507. Utilization of ircin-aluminium phosphates (of Saldanha Bay), by G. H. Stanley; Journ. 8. Afr. Assoc. Anal. Chem., 1920, 3, 13-21. 69 Canada. lleport on the mineral production of Canada; Mines Branch, Ottawa, Canudii (Annual). Phosphate in Canada, by H. S. Spence; Mines Branch, Ottawa, Canada, No. 396, 1920, 142 pp. and bibliography. Mineral deposits of the Ottawa district : the apatite deposits at the Emerald mine, by J. Stansfield; Geol. Surv., Ottawa, Canada, Guide book No. 3, 1913, pp. 89-93. Mineraiogical exploration of East Templeton district, Quebec, hy A. Ledoux; Geol. Surv., Ottawa, Canada, Summ. Rept. for 1915, p. 167. South-western portion of the Buckingham Map-area, Quebec, by M. E. Wilson; Geol. Surv., Ottawa, Canada, Summ. Rept. for 1915, p. 161. Contributions to the mineralogy of Black Lake area, Quebec, by E. Poitevin and R. P. D. Graham; Geol. Surv., Ottawa, Canada, Museum Bull. No. 27, Geol. Ser. No. 35, 1918, pp. 81-82. Mineral resources of Alberta, by J. A. Allan; First Ann. Rept. on Mineral Resources of Alberta, Edmonton, 1920, p. 82. Investigation of a reported discovery of phosphate in Alberta, by H. S. de Schmid; Mines Branch, Ottawa, Canada, Bull. No. 12, 1916, 38 pp. The phosphate discussion (discovery of phosphate in Alberta), by F. D. Adams; Can. Min. Journ., 1917, 38, 321-322. Origin of the Rocky Mountain phosphate deposits (abstract), by E. Black- welder; Bull. Geol. Soc. Amer., 1915, 26, No. 1, 100-101. Discovery of phosphate of lime in the Rocky Mountains, by F. D. Adams and W. J. Dick; Trans. Can. Min. Inst., 1916, 19, 321-348, also Canada, Commission of Conservation, 1915, 36 pp. A reconnaissance for phosphate in the Rocky Mountains, B.C., by H. 8. de Schmid; Mines Branch, Ottawa, Canada, Summ. Rept. for 1916, pp. '22-34. New zinc phosphates from Salmo, B.C., by A. H. Phillips; Amer. Journ. Sci., 1916, 42, No. 249. Rkdond.v, Leeward Islands. Report on the Island of Redonda, by H. A. Tempany; West. Ind. Bull., 1915, 15, 22-26. India. Quinquennial reviews of the mineral production of India, 1915 and 1921; Geol. Surv., Calcutta, India. ArSIBALIA. Repoi't of the Department of Mines; Sydney, New South Wales (Annual). Phosphate deposits in limestone caverns in New South Wales, by J. E. Came; Ann. Rept. Dept. Mines, N.S.W. for 19i:4, pp. 191-194. Also Appendix 2, N.S.W. Geol. Surv., Mineral Resources No. 25, 1919, pp. 393-399. Notes on the value of the Leadville ore for superphosphate manufacture, by J. E. Carne and E. C. Andrews; Ann. Rept. Dept. Mines, N.S.W. for 1916, pp. 202-204. Phosphate rock, Canowindra, by M. Morrison; Ann. Rept. Dept. Mines, N.S.W. for 1917, p. 169. Also Appendix 2, N.S.W. Geol. Snrv., Mineral Resources No. 25, 1919, pp. 399-400. A new phosphate deposit in the Howqua district, near Mansfield, Victoria, by E. W. Skeate and E. O. Teale; Proc. Austr. Inst. Min. Eng., 1918, new ser. No. 32, pp. 155-175. Phosphate of iron and other minerals, Whitfield district, by A. M. Howitt; Rec. Geol. Surv., Melbourne, Victoria, 1920, 4, Part 2, 147-151. Phosphates at Gore, bv L. C. Ball; Queens. Govt. Min. Journ., Brisbane, 1917, 18, 443-444. R(x;k phosphate deposit on Holbourne Island, near Bowen.tby E. C. Saint- Smith; Queens. Govt. Min. Journ., BrisbaDf 1919, 20, 122-124, 70 The phosphatic deposits of Wegtern Australia, by H. P. Woodward; W. Austr. Geol. Surv., Perth, Bull. No. 74, Misc. Repts., ser. 5, No. 6i, pp. 9-28. The phosphate deposits of South Australia, by R. Lockhart Jack; S. Austr. Dept. Mines, Adelaide, Geol. Surv. BuU. No. 7, 1919, 136 pp. Report on the Mount Burr phosphate and guano mine, by L. J. Winton; S. Austr. Dept. Mines, Adelaide, Min. Rev. No. 32, 1920, pp. 56-58. Phosphate deposits in Tasmania, by W. H. Twelvetrees ; Mineral Resources of Tasmania, Hobart, No. 3, 1917. New Zealand. Mines Statements; WeUington, New Zealand (Annual). A preliminary investigation of phosphate occurrences in North Auck- land and Waikato districts, by P. G. Morgan; Appendix C, N.Z. Geol. Surv. Branch, Wellington, Ninth Ann. Ilept. new ser., 1915, pp. 86-92. Phosphate occurrences in the South Island, by P. G. Morgan; Appendix O, N.Z. Geol. Surv. Branch, Wellington, Ninth Ann. Rept. new ser., 1915, p. 97. Kaipara district. North Auckland, by P. G. Morgan; N.Z. Geol. Surv. Branch, Wellington, Tenth Ann. Rept. new ser., 1916, pp. 11-13. Notes of a visit to Marlborough and North Canterbury, with especial reference to unconformities post-dating the Amuri limestone, by P. G. "Morgan; N.Z. Geol. Surv. Branch, WeUington, Tenth Ann. Rept. new ser., 1916, pp. 17-28. The geology of the Oamaru district. North Otago, by J. Park; N.Z. Geol. Surv., Wellington, Bull. No. 20, new ser., 1918, p. 115. The limestones of Canterbury considered as a possible source of phosphate, by L. J. Wild and R. Speight; N.Z. Journ. Sci. and Techn., 1919, 2, No. 3, 180-192. Pacific Islands. Phosphate reserves, Pacific Islands; Bd. Tr. Journ., 1919, 103, 771. Nauru and other phosphate islands in the Pacific; Report by the Director- General, Dept, of Agriculture, to the New Zealand House of Repre- sentatives, 1919. The use of Nauru Island phosphate, by B. C. Aston; New Zealand Journ. Agric, 1920, 21, No. 6, 345-346. Nauru and Ocean Islands : story of the phosphate discoveries and workings ; by A. F. Ellis; New Zealand Journ. Agric, 1920, 21, No. 6, 297-317. Ocean Island phosphate fields, by A. S. Ridley; Chem. Eng. Min. Rev., Melbourne, 1920, 12, 402-404. The Nauru Island Agreement Bill, 1920. H.M. Stationery Office, Bill 160. The phosphates of Nauru and Ocean Island, by T. Steel; Journ. Soc. Chem. Ind., 1921, 40, 59T-60T. FOREIGN COUNTRIES. Europe. Sopra alcuni giacimenti fosfatiferi della Galizia, della Podolia e della Palestina, by V. Simonelli ; L'ltaUa Agricola, 1919, October 15, 17 pp. Die Phosphorite des Lias von Deutsch-Lothringen, by F. Bernauor; Jahrb. Geol. Landesanst., 1919, Part 1, pp. 110-199. Nouvelles observations sur le gisement de phosphate de chaux, de St. Martin-du-Tertre pres Sens (Yonne), by A. Hure; BuU. Soc. Geol. de Prance, 1918, 18, 110-122. L'industrie des superphosphates mineraux; Ohimie et Industrie 1919 2, No. 2, 123-128. Lahnphosphorit, by Landgraeber; Bergbau, 1919, April 3, pp. 313-315, April 10, pp. 329-332. Guano from Sardinia, by M. Gina; Gazz. Chim. Ital., 1919, 49, ii, 246-249 Le fosferiti di terra d'Otranto, by V. SimoneUi; L'ltalia Agricola, 1919, April 15, 9 pp. 71 InveatigationB into the utilizatibn of phosphorites in Russia, by A. V. EasakoT, N. P. Koblikov and others; Report by D. N. Prianichnikov ; Agronomic Inst. Moscow, 1915, 5, 1-100. Agric. Intell. itfull., 1916, 7, 804-807. Short abstr. Journ. 8dc. Chem. Ind., 1916, .. 86, 1228. ^ IJber russische Phoephorite, by F. Kaunhowen; Zeits. f. prakt. Gfeol., 1919, 27, 71-76, 89-93. Phosphates in Spain and North Africa: Amer. Fertilizer, 1919, 50, No. 2, 58-62. Phosphates in Spain and France; Amer. Fertilizer, 1919, 51, No. 9, 50-51. Die Phosphathohle von Csokloviiia in Siebenburgen, by G. Gotzinger; Mitt. Geogr. Ges. Wien, 1919, 62, No. 7, p. 305. NOETH AfHICA. Su i pretesi giacimenti fosfatiferi di Cirenaica, by V. Simonelli; L'ltalia Agricola, 1920, August 15, 10 pp. La verita sui fosfati' di Cirenaica, by E. Cortese; Rass. Mineraria, 1920, 52, 41-42. The Algerian phosphate industry, by A. C. Frost; U.S. Commerce Repts., 1920, No. 33, 788-789. Sur un gisement de phosphate pliocene dans les environs de Rabat (Maroc), by A. Drives; C. R. Somm. Soc. Gfol. France, 1917, p. 95, 1920, pp. 78-79, and by L. Gentil; C. R. Somm. Soc. Geol. France, 1920, p. 25. Phosphate deposits in Morocco, by P. Jumeau; Amer. Fertilizer, 1920, 53, No. 8, 140, and 53, No. 10, 69. Phosphate rock deposits in Morocco, by J. C. Martin; Amer. Fertilizer, 1920, 53, No. 10, 142-148. Phosphate mining in Tunisia, North Africa, by P. King; Trans. Inst. Min. Eng., 1913-1914, 47, 456-463. Die Mineralschatze Tunisiens, by H. Arlt; Gliickauf, 1913, 49, Nos. 29 and 30, 1129-1134 and 1169-1179. L'industrie minerale de la Tunisie, by A. de Keppen ; Comite Central des Houilleres de France, Paris, 1914.' Mexico. Los criaderos de fosfato de calcio en los alrededores de Monterey, N.L. (Mexico), by T. Flores; Bol. Minero, 1916, 1, No. 5, 132-135; No. 6. 164-165. United States. Mineral resources of the United States; U.S. Geol. Surv., Washington, D.C. (Annual with bibliography). Reserve supply of phosphate rock in the United States, by W. H. Wagga- man; Journ. Ind. Eng. Chem., 1914, 6, 464-465. The phosphate resources of the U.S., by G. R. Mansfield; Proc. Pan- American Sci. Congress, 1917, sec. 7, 8, 729-766. The conservation of phosphate rock in the United States, by W. C. Phalen; Trans. Amer. Inst. Min. Eng. (1917), 57, 99-132. Phosphate deposits of the western United States and Canada, by W. F. Ferrier; Can. Min. Journ., 1917, 38, 209-210. Origin of the western phosphates of the U.S., by G. R. Mansfield; Amer. Journ. Sci., 1918, 4th ser., 46, 591-598. A report on the phosphate fields of South Carolina, by W. H. Waggaman; U.S. Dept. Agric, Bull. No. 18, 1913, 12 pp. Phosphate deposits of South Carolina, by 6. S. Rogers; U.S. Geol. Surv., Bull. 580, 1915, pp. 183-220. The phosphate deposits of Florida, by G. C. Matson; U.S. Geol. Surv., Bull. 604, 1915, 94 pp. and bibliography. The pebble phosphates of Florida, by E. H. Sellards; Florida Geol. Surv., Tallahassee, Seventh Ann. Rept., 1915, pp. 25-116. Geology of the phosphate deposits north-east of Georgetown, Idaho, by R. W. Richards and G. R. Mansfield; U.S. Geol. Surv., Bull. 577*. 1914, 74 pp. n A g^Iqgic r^conhaiSBance for ptosphate and coal in south-eastern Idaho ahd wfestbrh Wyomitigj by A. R. Schultz; U.S. Geol. Surv., Bull. 680, i918, pp. 37-64; Report on the phosphate rocks of central feehtufck^, h^ W; 0= Phalen; Kentucky Geol. Surv.; frdhkfoit, l91S, 80 pi*. The BUiston phosphate field, Montana, by R. W. Stone and C. A. Bonine; U.S. Geol. ^urv.j Buil. 580, 1915, pp., 373-383. The Garrison and Philipsburfe phosphate fields, Montana; by J; T. Pardee j U.S; felebi. Surv., Bull. 640, 1917, pp. 195-228. Phoapiiatic oil shales near Dell and Dillon, Beaverhead oountfc Montana; by C. F. Bowen; U.S. Geol. Surv., Bull. 661, lOiS, pp. 315-320. . Phosphate deposits near Maxville, Granite county, Montana, by J. T. Pardee; U:S. Geol. Surv.,, Bull. 715-^1. Tehnessfe phbsphate practice, by J. A. Barr; Trans; Ainer. Inst. Min. Eng., (1914), 50, 917-935. The brown and blue phosphate rock deposits of south-central Tennessee, by J. S. Hook; Tennessee Geol. Surv., Nashville, Resources of Ten- nessee, 1914, April. The white phosphates of Tennessee, by J. S. Hook; Tennessee Geol. Surv., Resources of Tennessee, 1915, 5, 23-33. Phosphates and dolomites of Johnson county, Tennessee, by O. P. Jenkins; Tennessee Geol. Surv., Resources of Tennessee, 1916, 6, 51-106. The conservation of phosphate rock in Tennessee, by W. C. Phalen; Tennessee Geol. Surv., Resources of Tennessee, 1916, 6, 193-216. The discovery and opening of a new phosphate field in the United States, by C. C. Jones; Trans. Amer. Inst. Min. Eng., (1913), 47, 192-216. A geologic reconnaissance of the Uinta Mountains, northern Utah, with special reference to phosphate, by A. R. Schultz; U.S. Geol. Surv., Bull. 690, 1919, pp. 31-94. Phosphate deposits in south-western Virginia, by G. W. Stose; U.S. Geol. Surv., Bull. 540-L, 1913, 16 pp. A reconnaissance for phosphate in the Salt River Range, Wyoming, by G. R. Mansfield; U.S. G«ol. Surv., Bull. 620, 1916, pp. 331-349. DtJTCH West Inbies. De Santa Barbara fosfaatmijn op het Eiland Curasao. De fosfaat-markt, een technisch-commercieels studio ober de behoefte aan, de productie en waarde von fosfaat, by J. A. Grutterink, Verh. Geol.-Mijnbouwk. Gen. Nederlanden Kolonien, Mijnbouwk. Serie., 1913, Oct., Pt. 50, pp. 91-189. Chile. Los abonos fosfatados i los yacimientos de apatita de Freirina, Chile, by J. Bruggen; Bol. de la Soc. Nac. de Mineria, 1913, Sept. -Oct., pp. 438-447. Asia Minor. Syrien, Arabien und Mesopotamien, Technisch wichtige Vorkommen : " Phosphat, by M. Blanckenhorn ; Handbuch der reg. Geol., 1914, 5, No. 17, 146-147. Japan. The phosphorus industry, Japan; Journ. Soc. Chem. lud., 1920, 39, 273R. FoHEiGN Pacific Possessions. Phosphates in Dutch Indies; Amer. Fertilizer; 1920, 52, No. 8, 92. Phosphate deposits of New Guinea ; Chem. u. Tech. Zeits., 1918, April 1 and 15. Short abstr. Journ. Soc. Chem. Ind., 1918, 37, 280R. Phosphate deposits in the South Pacific; U.S. Commerce Repts., 1918 Sept. 25. Abstr. Journ. Soc. Chem. Ind., 1918, 37, 459R. ' ' Phosphate production in the Society Islands, by H. P. Wittrey US Commerce Repts., 1920, No. 163, p. 233. Imperial Mineral Rasourccs Bareau— ««»«<*««"'/• LiUid r!«>gi0tratioD Ordinance, 1916 (aa amended by the Laod Plegigtration (Amendment) (ji-dinance, 1915, and the Land R^istration (Amendment) Ordinance, 1918); The liand and Native Rigbte Ordinance, 1016 (ae amended by the Land and Native Kighta (Amendment) Odinance, 1&18) ; The Pabhc Lands Acqnisition Ordinance, 191T (excerpts from) ; The Crown Lands Ordinance, 1918 (excerpts from); The ExplosiveB Ordinance, 1915 ; Regulations made undpr the Explosives Ordinance ; Master and Servant Ordinance, 1917 ; Regulations made under the Master and Servant Ordinance, 1917 ; The Arbitration Ordinance, 1914; Government Notice relative to undertaking as to destination <;f tin ore exported; Government Notice prohibiting prospecting for Coal; Index. (19-20.) Price 15». (15s. ^d.). VoiiUMB 11., West Africa (Thb Gold Coast, Ashanti, The NOBTHEBN Thbbitobibs, AND SiEBEA Lbonb). — Preliminary Matter ; Gbnbbal Analxsib of the Law bblatino to the Gold Coast and Ashanti : Introduqtoi-y ; Definition of Minerals, Mine and Mining; Oonceasions; Definitions and Certification of Validity ; Prospecting, Mining, Dredging and Pumping Licences ; Rights and Duties of the Concetssion Holder; Royalties, Rents, Duties and Stamps; Termination, Cancellation, Surrender or Lapse of Concession or Ijicence ; Survey ; Registration ; Explosives : Machinery for Settlement of Disputes ; Dealing in Minerals and Mineral Oils; Employers and Employed; Penal Provisions and Pjenalties; Law relating to the Northern Tbrritoribs ; General Analysis : Licences, Application and Fees ; Prospecting Licence, Prospecting and Mining Options, Mining and Dredging Lioences; Restrictions on Rights Conferred, Inspection and Survey, Boundary Disputes, Penalties; Sierra Lbonb : Introductory, Definition of Minerals and Mineral Oils; Concessions : Definitions and Certification of Validity; Pi-ospect- ing and Mining Licences; Rights and Duties; Royalties, Rents and Stamps; Termination, Cancellation, Surrender or Lapse of Concession or Licence ; Registration ; Machinery for Settlement of ])ispiitfs; Penal Clauses; Siu-vey; Exptosives; Employes and Employed : Indices. (1920.) Price 15s. (15*. 7d.). Volume III., The Transvaal. {In the prtss.) [P.T.O. IMPERIAL MINERAL . RESOURCE^ BUREAU. Ebpobts.on the Mineral Industey of the 'British Empibe and FoREitsN Countries. (Waji Period, 1913-19.) Aluminium aiid Bauxite ... (1921) Prici^ . U. : (lOH) Antimony ... (1921). ft- Is. (Is, lid.) Arsenic ■;.:;> (1920) >> 6i. 0dS ' Asbestos .r<1921) It-- Us. (Is. lid.) Barium Minerals ... (1921) ft U. mid.} Bismuth ....(1920) >» U. ad.)' Borates ... ... ....(1920) ^> U. aoid.) ' Coal. Parti ... (1921)' »» 3s. M. (3s. 8K) Coal. Part n ..." .*. ft (w f^e press) Chrome Ore : Chromium ... (1920) 11 Is. (15. ip.) Cobalt ... (1921) iii ;■ U. (lOid.) Felspar ... (1920) 11 . &d. (m FlUOTBgar ... (1921) >» . 2d. (lOJd.) Fuller's Earth ... (1920) . " ' , ¥■ m.) Iron Ore Resources of the World. Parts I, n and III ... 11 im the press) Iron Pyrites and Sulphur ... 11 ( _c /, ) Magnesite ... (1920) 11 is. 3d; (Is. Aid.) Manganese ... >.. :.. (1921)' It 3s. m. (3s.8J(l.) Mica ... ... ... - ... . ... It {in the press) ^ Monazite ...:(i920) It 6d. (7d.) Nitrates ... (1920) ' '>,^ M. (lop.) Phosphates ... (1921) >» .2s. (2s. ip.) Talc ... ' ... ... (192D it 9d. xim-v' Tungsten ... (1931) It ' 1*. (Is. lid.) Zinc .... (1921) »j 3s:6