a^ ALBERT R. MANN LIBRARY New York State Colleges OF Agriculture and Home Economics Cornell University DATE DUE H m^ 0m^^ ^^*- CWLORD PRINTED IN U-S. A. Cornell University Library SB 23S.S84 Sorghum and Its products.An account of r 3 1924 003 377 672 Cornell University Library The original of tiiis book is in the Cornell University Library. There are no known copyright restrictions in the United States on the use of the text. http://www.archive.org/details/cu31924003377672 EVAPORATING RANGE.-Fig. 1. SORGHUM AND ITS PRODUCTS. AN ACCOUNT OF RECENT INYESTIGATI0N8 OONOBKNINQ THB VALUE OF SORGHUM IN SUGAR PRODUCTION, TOGETHER WITH A DBSCmPTION OF FEOM THIS PLANT, ADAPTED TO COMMON USE. BY F. L. STEWART. PHILADELPHIA: J. B. LIPPINCOTT & CO. 1867. Entered, according to Act of Congress, in the year 1867, by F. L. STEWART, In the Clerk's Office of the District Court for the Western District of PennsylTania. s^4 J777 1 TO JOHN" FEASEK, PRESIDENT OF THE AGRICULTURAL COLLEGE OF PENNSYLVANIA, SCftijS Woxk IS EKSPECTPULIiT INSCRIBED BY BIS FRIEND, THE AUTHOR. PREFACE. Recent improvements in the art of making sugar and syrup from Sorghum Oane have created a necessity for the pubhcation of this volume. It is written for the benefit chiefly of Farmers and Planters of the United States, who have fostered this new branch of industry from the outset, and in whose hands it is destined to assume a new importance. The time is past when this pursuit is to be regarded only as an experiment, or as an ephemeral enterprise, persisted in merely because of the paralyzation of industry at the South. Sugar making is an Art, and complete success is not attain- able at a bound, but the attentive reader of these pages will find that it is an art easily learned. The pathway, by which I reached my object in these researches, was beset with obstructions which it was necessary to overcome successively as they presented themselves — wherein much time was spent, but not unprofitably, as the result, I trust, will show. Of the magnitude of these difficulties few have any just apprehension, who have not, in a thorough manner, addressed themselves to the task of discover- ing what is their real nature. One fact, however, rewards the investigation at the start, and was to me a sufficient encouragement ; namely, that the best varieties of this cane contain as large a proportion of crystalliz- able sugar as does ordinarily the sugar cane in Louisiana. This 1* (v) VI PREFACE. truth has not generally been recognized, but the sooner it be- comes known and appreciated the better. In common with all who would obtain accurate information respecting sugar production at the South, I acknowledge my indebtedness to the works of Evans and Dutrone, and to the more recent and very valuable researches of Professor R. S. McOulloh. With the confident expectation that the processes herein recommended will be successful in other hands, as they have been in my own, the work is submitted to the public. P. L. STEWART. April, 1867. CONTENTS. CHAPTER I. STJOAR AHD StTGAK PLANTS. Cane Sugar— Ita Early History— The Period of its Introduc- tion into Europe — Comparatively unknown to the Ancients — Pliny's Observations — Importance of the Sugar Industry at the Present Time — Sources from which Sugar is now de- rived—The Tropical Cane — Its Climatology — Sugar Pro- duction in the United States — Insufficiency of all our Native Sources of Supply — The Cane in Louisiana — The Sugar Maple— The Beet— Grape or Starch Sugar— Its Low Rank — Inapplicable to the most Important Purposes for which Cane Sugar is used — Sorghum Saccharatum, the Northern Cane — Sketch of its History — Its Relations to Soil and Climate — Its True Character and Value 15 CHAPTER IL METHOD OF CriTIVATION. The Method of Cultivation adapted to the Nature and Re- quirements of the Plant — Resemblance to Indian-corn not BO close as has been supposed — Cereal and Saccharine Plants — Importance of adherence to System — Some Considerations of Primary Importance — The Selection of the Seed — Vari- eties of Cane — Chinese and South African — Characteristics of Good Seed — How Germination may be hastened — Physi- ology of the Seed — Planting and Cultivation — Outline of a System defined .......,, 25 CHAPTER III. METHOD or CULTIVATION (CONTINUED). Inequality of Development of the Stem and Roots of the An- nual Grasses during the early Period of Growth— This Pe- culiarity must be recognized in any Rational System of Planting and Culture — All Cultivated Plants divided into two Great Classes, according to their mode of development — Relations to Climate — The Oat Plant — Ahrend's Experi- ments — In what Respects the growth of Sorghum is Analo- gous^The Characteristics of the Plant at different Periods of Growth exhibited — Physiology of the Leaf, Stem, and Root — Treatment which the Plant should receive at each Period . . 30 VUl CONTENTS. CHAPTER IV. METHOD OP CnLTIVATION (cONIINnEI)) — EARIY PLANTING. Early Planting essentially Important, and why — Analogy to Wheat — "Volunteer Cane" — Conditions of growth during the First Period, and Influence of a Low Temperature — This Period falls within the limits of the Meteorological Spring, in the Latitude of Philadelphia — Disadvantages of Planting at a Later Period — Reasons why a System of Early Spring Planting should in all Cases be followed — How the C(ffidi- tions necessary to Success by this System may be obtained — Fall Plowing arid Deep Tillage almost indispensable — Col- lateral Advantages secured thereby 34 CHAPTER V. METHOD OF CnLTITATIOII (CONTINUED) — RIDQINO. Ridging of the Land indispensable when Early Planting is practiced — Mode of Ridging adopted — Enumeration of the Peculiar Benefits due to this Practice — After-culture of the Cane described — Illustration 41 CHAPTER VL MANURES. The Food of the Plant — Special Manures — Influence of Ma- nures rich in Nitrogen at the various stages of the develop- ment of Cane— Analysis of the Ash — Function of the Min- eral Food or Ash-ingredients — The Elements of Sugar, whence derived — Precautions necessary to be observed — By what Means Exhaustion of the Soil by Successive Crops of Cane may be prevented, without practicing a System of Ro- tation of Crops ......... 46 CHAPTER VII. MANTJUES (OONTINTJED). The Begasse or Cane Trash — How it may be disposed of — Uses — Its Composition — How to convert it into a most Valuable Manure — Rationale of the decomposition of the Trash — Waste Products — Their Use as Manures — Mineral Manures, from Artificial Sources, how supplied — Gypsum as a Special Fertilizer — Harris's Experiments — Analogies and Conclusions — Mode of action of Gypsum as applied to Cane — Why most Energetic when applied to Early-planted Cane — Importance of Potash as a Fertilizer . . .54 CONTENTS. iX CHAPTER VIII. THE KEIATITE VALUE OP DIFFERENT SOILS IN BUOAR PRODUCTION The Soil not merely a Repository of the Mineral Food of Plants — Theory alone not a safe Guide in estimating the Value of Soils for different Purposes — Texture and Physical Prop- erties of Soils — The Peculiar Qualities, physical and chem- ical, of Lauds which Experience has proved to be the best adapted to this Cane — The "Bluff Lands" of the Missouri and Mississippi Valleys — Sugar Production in the West and in Louisiana — Soils of the Ohio Terraces . . . .62 CHAPTER IX. THE INFLUENCE OF CLIMATE. The Limits of the Distribution of Species defined by Climate — Sub-tropical Character of the Middle and Western States during the Summer Months — The Limits within which Sor- ghum may be profitably grown defined — The Summer Iso- therm of 70° Fahr. — The Summer Line of 72° Fahr. proba- bly the Northern Limit of the District within which Sugar may be most successfully produced . . . . .68 CHAPTER X. MEANS BT WHICH THE MATURITY OF CANE MAT BE HASTENED. Special Means by which Early Ripening may be secured — In- attention of Planters to this Subject — The Period of Growth may be abbreviated to advantage by the practice of the System of Planting and Culture previously recommended — Selection of the Earliest ripened Seeds from the most Highly- developed Plants — Early Planting — Sprouting of Seed — Drainage of Land — Use of Lime — Upland Soil and Southern Exposure of the Surface — Direction of the Cane Rows — Importance of attention to these Particulars . . .71 CHAPTER XI. THE "tillering" OF SOEQHUM. Influence of the Side Shoots, or "Suckers," upon the Saccha- rine Products of the Plant— Opposite Opinions of experi- enced Planters as to the Nature and Value of the Lateral Shoots harmonized — Their Growth under perfect Control — They are not an Abnormal Growth, but are perfectly analo- gous to the TUlers of Wheat — The Tillering Process common to many of the Grasses, and a wise provision for their In- crease Under what Conditions the Growth of the Sorghum Tillers should be encouraged 75 X CONTENTS. CHAPTER XII. HAETESTINO THE CANE. Preparation of the Cane for the Operation of Crushing, Re- moval of the Blades — Their Proper Function discharged at the Period when the Seed is Ripe, when they should be removed — Their Value as Fodder — The Mode of stripping Cane — How and when to top Cane — Removal of the Cane from the Field — Effect of Frost upon Cane under Different Circumstances ......... 81 CHAPTER XIII. STOEINO THE CANE. The Sugar Factory, what Buildings necessary — Cane Sheds, their Construction and Arrangement — Trash Thatch a Con- venient Material for Roofing, etc. — How used — Conditions essential to the Preservation of Cane— Length of Time during which it may be kept uninjured — ^Experiment — Uniformity of Temperature necessary ....... 85 CHAPTER XIV. PKOCESS or MANUFACTTJEE. Distinctive Features of the Process of Manufacture herein re- commended — Difficulties attendant upon Crystallization from an Impure Solution — Defecating Substances, Requirements to which they must Conform — Advantages of a well-defined System — Errors which have hindered Progress in Sugar Production from Sorghum — -Necessity of a New Mode of Treatment — Disadvantages of the Common Mode — Constitu- ents of Sorghum Juice — Thorough Defecation the great De- sideratum in any Method ....... 91 CHAPTER XV. PROCESS OP MANTJPACTURE (CONTINUED). Description of the Apparatus and the Mode of using it — General Arrangement of the Different Parts — Description of the Evaporating Range, Materials used in its Construction — Tanks, etc. — Details of the Mode of Operation — First Stage — Lime and the Defecating Agent, how employed — -Satura- tion of the Acid — How the Scum is separated without the usual Process of Skimming — Arrangement of Division A — Requisites to secure Success — Precautions — Fuel — Chemical Agents . 97 CONTENTS. CHAPTER XVI. PROCESS OP MANUPACTTTRE (CONTINUED). Second Stage of the Process — Characteristics of a Refined Syrup — Mode of Refining the Syrup — Manner of using the Filtering Drawer — Third Stage — Concentration of the Syrup — The Finishing Pan— Thermometer — The Striking Point as determined by the Temperature — Other Tests of Density — The Finger Test — Indications at Successive Stages of Con- centration — ^False Indications exhibited by Impure Syrups — Precautions necessary in Barreling Syrups . . . 105 CHAPTER XVII. PROCESS OF MANUFACTURE (CONTINUED). Crystallization — Treatment of the Syrup in the Crystallizing- room — Crystallizing Vessels — Dutrone's Crystallizing Box — How Drainage may be secured and Crystallization promoted. Ill CHAPTER XVIII. PROCESS OF MANUFACTURE (CONTINUED). Drainage — In what it consists — Mode of Working — Extent to which the Production of the Higher Grades of Sugar may profitably be carried in Draining Vessels — Sugar Moulds — Description of the Process of Natural Drainage and the Mode of preparing White Sugar — Reboiling and Crystalliza- tion — Summary of Conditions necessary to Success in Liq- uoring Sugars — Separation of the Molasses by Mechanical Pressure and other Means — The Centrifugal Drainer . . 115 CHAPTER XIX. SUGAR MILLS. Composition of Sorghum Cane Juice — Extraction of the Juice Sugar Mills — Per cent, of Juice ordinarily extracted by Mills Loss from Inefficiency of Mills — Obstacles to the complete Removal of the Juice — To what extent they may be overcome — The Common Three Roll Mills at the South — Mean Results of Experiments with these Mills in Guada- loupe British West Indies — Cuba, Java, and Louisiana — Importance of further Improvements — Necessity of Grinding at a low rale of Speed — How the Advantages of the Process of Maceration may be successfully combined with those de- rived from the use of the Mill— Mills with Four Rolls pro- vided with a Pipe for the Injection of Jets of Steam into the Begasse — Value of these Improvements .... 124 Xll CONTENTS. CHAPTER XX. CHEMICAL ACTION Or SUBSTANCES USED IN DEFECATION. Chemical Influence of Lime upon Sorghum Juice — Defecation by Tannic Acid and Albumen — Upon what the Peculiar Ac- tion of these Substances, so combined, depends — Conditions favorable to the Use of this Method — Another Method of Defecation — The Action of the Chemical Compound used — The Composition described and the Advantages to be de- rived from its Use 132 CHAPTER XXI. ANIMAL CARBON, OB, BONEBLACK. Filtration — Animal Charcoal or Boneblaok — Mode of prepar- ing it, and the Condition in which it is employed in this Process — Properties of the Charcoal in this form— Mode of using it — Its Action — Use in removing the Extraotiye Mat- ter and Harsh Flavor — Decolorizes— Promotes Crystalliza- tion — Removes any Excess of Lime, Tannin, etc., etc. — Separates all Soluble Substances mechanically suspended in the Liquid — Mode of restoring the Powers of the Charcoal when exhausted — Different Modes of Keburning — New Method of Revivification — Substitutes for it in Filtration . 140 CHAPTER XXIL THE ACTION OP HEAT. The Influence of Heat upon Cane Juice — Imperfect convection of Heat in deep masses of Syrup — How Heat is economized by this Method, and its Intensity regulated, according to the Effect required at each Stage of the Evaporation — The Tilt Pan — Injurious Effects of a Low but Prolonged Heat — Sou- beiran's Experiments — Open-air boiling indispensable up to a certain point of Concentration — Payen's Experience — Evaporation by a Water-Bath or by Steam at 212° F. — Why injurious — Advantages derived from the use of a Vacuum Finishing Pan — Why it cannot come into general Use 147 CHAPTER XXIII. OTHER METHODS. Description of various Methods of Manufacture heretofore used o / 400 lb*, superphosphate of lime.. I 12000 lbs. unleaohed ashes / "Each plot contained 201 hills, but, as the above table shows, many failed. The seed either rotted ia the ground or was injured by the manure. The last column shows in the plainest manner the relative yield per acre, allowing the same number of hills to have produced on each plot. " The effect of plaster (gypsum, or sulphate of lime) is interesting and instructive. Not only does the plot ma- nured with this show the greatest yield per hill, but with one exception (plot No. 3) the greatest number of hills germinated and grew. These two plots, Nos. 3 and 5, were superior to any others, all through the season. "The superphosphate used was a superior article, made from calcined bones, expressly for the experiment. It should be understood that the best superphosphate con- tains at least 50 per cent, of piaster ; so that if common plaster contains 80 per cent, of sulphate of lime, the 250 lbs. applied to plot No. 5 wouH contain the same quan- tity of real plaster as the 400 ibs. of superphosphate ap- GYPSUM. 69 plied to plot No. 3 ; if 90 per cent., it would get 25 fts. more plaster than plot No. 3. " The plots receiving plaster and superphosphate are the two best of the series. .Plot No. 5. is a little the best, and probably received a little more real plaster than No. 3. One thing is clear : the soluble phosphate of lime in the superphosphate did no good, for on the plot No. 5 we have plaster alone ; and on the other plot (No. 3) we have plaster and soluble phosphate; and yet the crop is no better from the two together than from the plaster alone." Other experiments made since, render it evident that if the augmentation of the yield is less striking in some instances than in the above, the application of gypsum is uniformly in a very high degree beneficial. Its effect is most manifest upon soils not rich in vegetable matter, and especially upon clay lands. Such soils being well adapted to sugar produc- tion from this cane, its eifects are very marked upon them. But it is the direct and peculiar influence which it exerts npon the growth of the plant that is especially noteworthy, and which, when more generally known, is likely to en- hance its value as a manure for the sorghum. This con- sists in the fact that gypsum stimulates some organs of the plant to extraordinary development, while it has no such action upon others,.^it increases greatly the size of the stems, — in a slight degree the quantity of the leaves, while it really diminishes the quantity of flowers and seeds. In the cane, this strong growth of stems is not, as when the plant is encouraged to a luxuriant expansion by animal manures, or a rich vegetable soil, attended by any diminu- tion of the saccharine quality of the juice, but rather an increased richness. Upon clover, it has long been knowa to exert a similar influence. It increases the weight of the stems at the expense of the leaves, flowers, and seeds. In plants, as In animals, special points of excellence may be 60 MANURES. developed, and may be made eventually hereditary by care in keeping the individuals possessing them, through succes- sive generations, under the influence of the agents by which those special forms or qnaliti€s were originally induced. Have we not here, then, in this material, the means of producing, within a single season, an influence which the labors of a century in hybridization directed to the im- provement of the same qualities, might not have effected, and the promise also of rendering permanent, and of im- proving to the highest degree, those qualities when once implanted ? If broom corn is but sorghum with the sac- charine quality undeveloped in it by reason of its subjection to natural influences constantly exerted, may we not appre- hend a slow but sure deterioration of the best varieties of the latter that we have, unless some such powerful agent as this is laid hold of to check the tendency to gradual de- basement ? Snlphate of ammonia has been found to exert an influence very similar to that of the sulphate of lime upon clover. The mode in which the gypsum acts in producing this change is not understood. Liebig, after many years of assiduous research, expresses his inability to answer satis- factorily this question. He regards its action as very complex. He has lately found, however, that it promotes in a remarkable degree the distribution of potash and mag- nesia in the soil, by the substitution of those bases for the lime in the combination with sulphuric acid, thereby mak- ing them soluble, and rendering "nutritive elements ac- cessible to and available for the clover (at least) which were not so before" {Liebig, "Nat. Laws of Husbandry," p. 327). That it also fixes ammonia is certain. Prof. S. W. Johnson estimates that its presence in the juice of plants has the effect of checking undue evaporation from the leaves, thus enabling them to resist drought in a high degree. POTASH. 61 However these or other discoveries may indicate its mode of action, the effect is no less striking and peculiar. G3'psura is best- applied to the cane, sown in the row, before the seed, or afierward used as a top-dressing. As an agent infixing ammonia, chloride of lime is probably more effective, being more soluble. The eflect of gypsum will no doubt be most marked on early planted cane, a larger quantity being dissolved by the rains. On cane late planted, and preceding a drought, it would exert little benefit. Pulaah is observed to be a preponderating ingredient in the ash of all sugar-bearing plants. ]t is, therefore, probably not only beneficial directly applied to the plant in the form of wood ashes, etc., but the sulphate of lime, as above mentioned, seems to effect the conversion of salts of potash existing in the soil in an insoluble form, into one ia which they directly afford nutriment to the plant. CHAPTER YIII. THE RELATIVE VALUE OP DIFFERENT SOILS IN StTQAR PRODUCTION. The Soil not merely a Repository of the Mineral Food of Plants — Theory alone not a safe Guide in estimating the Value of Soila for different Purposes — Texture and Physical Properties of Soils — The Peculiar Qualities, physical and chemical, of Lands which Bxperience has proved to be the best adapted to this Cane — The "Bluff Lands" of the Missouri and Mississippi Valleys — Sugar Production in the West and in Louisiana — Soils of the Ohio Ter- Althocgh it is true that in order to preserve the exist- ence of every plant ia its normal condition, its ash-con- stituents must be found in the soil in which it grows, it would be false to presume that to insure fertility, it will be necessary only to preserve in the soil a constant supply of each ingredient detected by analysis in the ash of the plant. Science, as yet, has given no satisfactory explana- tion of the nature of those transformations by which mineral substances in the soil are made to contribute to the life of vegetation. Within the soil, as well as in the organic struc- ture, many subtle combinations are known to be formed which the chemist is unable to repeat in the laboratory. Unexpected results, incapable of explanation according to any known principles, are often developed, and hence the necessity of admitting no inferences in agriculture as facts which have not been referred to the test of experience for confirmation. The relative value of different soils for (62) PHYSICAL PROPERTIES OF ^OILS. 63 sngar production can only thus be determined. So, too, the specific influence of any fertilizing agent upon the growth or nutrition of the cane, may be regarded as accu- rately fixed only under certain conditions. The texture and other physical properties of soils have generally a uo less important influence upon their fertility than those that are strictly chemical. The former being readily perceptible are well known, and may be pretty clearly defined ; and as they are dependent upon, and, to a certain degree, indicate the chemical composition, they mark the most characteristic points of distinction between diS'erent soils. Correspondent to the quality of the soil, the juice of the cane has been found to undergo, uniformly, various degrees of tnodification, and although much is yet to be learned on this head experimentally, enough is known to enable us to indicate certain soils as peculiarly favorable to the pro- duction of the saccharine matter in the juice of sorghum, almost free from impurities which hinder crystallization, while others are in an equal degree unfavorable in this re- spect. This difference in lands not artificially manured, ap- pears the most broadly marked when we compare a light, friable limestone soil with a wet alluvial one, or one but re- cently cleared, and composed in great part of humus or decay- ing vegetable matter. Upon the last-mentioned variety of soil sorghum grows rank and tall, but its period of growth is inordinately lengthened, the seed fails to mature early, the juices are diluted and mucilaginous, the crystallization of the sugar is accomplished with greater difficulty, and the yield either in sugar or refined syrup is less even than that usually obtained from half worn-out upland soils. The worst possible condition of the juice is attained when the humus is replaced or reinforced by barn-yard or other stimulating ammoniacal manures in large quantity; in sueh 64 soiLa case the cane Reldom ripens, and yields about one gallon to twelve of juice, of a dark, pungent, nncrystallizable synip. Upon such a soil the maize attains to uncommon luxuriance and fruiifulness; and it is this peculiarity which forms one of the most important points of distinction be- tween it and the cane. Upon lands which have ceased to produce remunerative crops of corn, sorghum often thrives well; because, like the pea, clover, etc., it sends its roots down deeply and draws much of its nourishment from the subsoil which is rich in mineral food that the less pen- etrative roots of the corn have failed to extract. But if a light, calcareous loam be selected, which is deep and mellow, either comparatively new land which has been long enough in cultivation to have had its vegetable mat- ter thoroughly incorporated with the deeper layers of soil — or old limestone land which has not been suffered to de- teriorate by injudicious cropping, and to which no more animal manure has been applied than is necessary to give a stimulus to the plant in the early stage of its growth, the cane will attain to a very large size, it will mature its seed and juice in all ordinary seasons in the Middle and Western States, producing an abundance of a light-colored and easily crystallizable sugar, and aline rich syriip. If with these ad- vantages of soil is combined a side-hill exposure to the south, sloping at such an angle as to receive the verti- cal rays of the sun at noon in midsummer, we will tlien have supplied all the natural prerequisites for bringing tlie plant to the highest condition of which it is capable. A good variety of cane, under these circumstances, will sel- dom fail to produce less than one gallon of syrup or live ponnds of sugar, from every live gallons of jnice^ Such soils are abundantly distributed throughout the whole district where sugar production would be profitable, and especially oq the uplands in the Westero States they SOIL OF THE y.ISSOURI "BLUFFS." 65 are very largely developed, where the great limestone series of rocks, from which they derive their chief charac- ters, is found. Among these Western soils particular prominence should, however, be given to one of a peculiar character, consisting of an extensive bed of a fine, friable, silicious marl of a buff color, which is found to cover to a great depth those pic- turesque hills on the banks of the Missouri River, and of the Upper Mississippi, called " the Bluffs," from which the de- posit itself derives its name. It is most largely developed along the Valley of the Lower Missouri, and extends over wide areas of the elevated country on either side, forming the surface of the richest of the upland prairies. The ex- traordinary and almost exhaustless fertility of these Bluff Lands, as well as other qualities which distinguish them, will be more readily understood when the nature of the agency to which they evidently owe their origin is con- sidered. There can be no doubt that during a compara- tively recent geological period, the era of the mammoth, the mastodon, and the huge primeval beaver, a large part of th£ Western country, comprising at least the basins of the great rivers, was deeply covered by a fresh water lake of vast dimensions. TJpon the fioor of the lake an exten- sive deposit of fine, rich, marly sediment was gradually formed, the remains of which, after the subsequent changes of level and drainage of the country through its present water-courses, are now to be found capping the highlands along the streams. This sedimentary bed has in some instances been found to be not less than 200 feet deep, and perfectly homogeneous throughout; but its average depth on the Missouri River, where it attains its best development, generally does not exceed 100 feet, and it is often much less. The soil formed from it contains a very large pro- portion of vegetable matter in its natural state, derived 6* 66 SOILS. from the forests which clothe it, where undisturbed, with alin«st tropical luxuriance. Indian-corn, tobacco, or hemp, should be grown upon the recently cleared land, for three or four successive seasons, until the vegetable matter has been completely decomposed and incorporated with the soil, and its tendency to promote too rank a growth of cane subdued. After this preparation, it is difficult to imagine in what respect it could be improved for sugar production from this cane. Its chemical composition, tex- ture, and great depth, its evenly rolling surface, topo- graphical elevation and thorough drainage comprise ad- vantages such as, it may confidently be said, are naturally possessed in the same degree by no other soil in the Union, for this purpose. The drainage of tliis soil is secured by one of the most remarkable natural provisions. The whole mass of the upper portion of the blufif stratum, to a depth of sometimes twenty feet, is permeated in every direction, but more fre- quently downward, by innumerable cylindrical channels, which are evidently cavities formed by the decay of the roots of trees. The green roots not only of the common white oak, but even of the poke-weed {Phylolacca decan- dra), have been found at a perpendicular depth of seven- teen feet below the surl'ace of the blutf soil.* Experiment has proved that from 300 to 400 gallons of syrup to the acre may be made from an average crop of cane on this soil, without the addition of any special manures. The expense of cultivation is but little greater than is necessary for the production of a good crop of corn, and as it is generally conceded that the fodder and seed annu- ally produced amply compensate the cost of cultivation, * Geological Survey of Missouri, First and Sooond Reports (Prof. G. C. Swallow), p 71. OHIO TERRACES. 67 the cost of the production of sugar or syrup will be re- duced to the expense solely of hauling and working up the canes. These will compare favorably with the best results of sugar manufacture from the tropical cane in Louisiana; they much exceed the ordinary profits of cotton growing in j\Iississippi and Carolina, and these facts require only to be known and appreciated in order to insure the permanent establishment of sugar production from sor- ghum throughout a vast central area of the continent. The fact that these lands are always most fully developed along the large Western rivers, and that their products are thus brought within easy reach of market by water car- riage, is an important consideration additional to the ad- vantages above stated. Next to the bluff or an elevated limestone soil of the first quality, the sandy or gravelly terraces of the Ohio Valley deserve a prominent place. These are the best natural soils; the most unsuitable of all others for cane growing are the alluTial bottoms and wet prairies. Intermediate between the best and the worst are many varieties of soils, which by proper tillage and the use of suitable fertilizers, may be brought to the highest standard of productiveness, if the essential requisite of a congenial climate be not wanting. CHAPTER IX. THE INFirENCE OE CLIMATE. The Limits of the Distribution of Species defined by Climate — Sub- tropical Character of the Middle and Western States during the Summer Months — The Limits within which Sorghum may be profitably grown defined — The Summer Isotherm of 70° Fahr. — The Summer Line of 72° Fahr. probably the Northern Limit of the District within which Sugar may be most successfully pro- duced. While the nature of the soil determines in a great de- gree the situation in which each individual plant is found to flourish in a state of nature, climate fixes the wider limits of the distribution of each species. The geographical range within which the cultivation of the sorghum is capa- ble of being successfully extended in this country, may now be regarded as pretty accurately settled, at least as respects those varieties which have proved the most valuable. Tiiis range is very extensive, but within its limits tiie soil and situation define much more narrowly the area within which alone sugar will become a staple article of production. The results of the past eight years, properly interpreted, indicate this clearly. The subtropical character of those regions of the Old World from whence the several varieties of the sorghum were originally derived, might perhaps lead to the inference that, in this country, we are attempting to carry the limits of the sugar growing region' farther north than analogy of climate would support. But such conclu- sions have no foundation in fact, for it should be remem- bered that an extreme, almost tropical temperature is char- acteristic of the middle latitudes of the United States (68) NORTHERN RANGE OF SORaHUM. 69 during three or four months of the year. These months cover the whole period of growth of this cane, and where- ever the high summer temperature is sufficiently protracted, and the requisite conditions of soil and moisture are sup- plied, its cultivation may be successfully carried, although the mean annual temperature of such a region may fall con- siderably below that of tiie native country of the plant. Our common corn, a subtropical plant also, furnishes a good illustration of this unique feature of our summer climate in its capability of being here successfully extended in cultivation up to a latitude unexampled elsewhere. But even Indian-corn may ripen in a climate where the yield is too meager to render it a successful competitor with the hardier grasses, or to reward the toil of the cultivator. The same is true of sorghum. The limit of remunerative production will fall considerable short of the line which marks the northern boundary of its growth. A certain line of equal summer heat quite accurately fixes this limit. So far as temperature is concerued, the growth of any annual plant msiybe successfully carried to any geographi- cal limits within which the specific amount of heat neces- sary to the species is uniformly supplied, during a definite period of time. This period, which measures the whole life of the annual plant from the germination to the ripen- ing of the seed, has been found for the larger varieties of sorghum in those climates where it has uniformly ripened and attained to the fullest perfection, to average from 130 to 140 days. The line of temperature which marks the northern range of the sorghum as a sugar-producing plant on this continent, may be defined to be the summer isotherm of 10° as determined by Blodget in his "Clima- tology of the United States." This line passes from the east through South vvestern Connecticut, the southeastern extremity of New York, Northern New Jersey, Eastern 10 INFLUENCE OF CLIMATE. and Western Pennsylvania, north of Reading and Pitts- burg, through Northern Ohio, touching the shore of Lalse Erie, Southern Michigan, including Northern Indiana and Illinois as it passes around the southern extremity of Lake Michigan, and thence through Southern Wisconsin and Minnesota. North of this line, the cane fails to ripen. South of it, it ripens generally everywhere when planted early, but this is rendered more certain, and the growth of the cane is more vigorous when the summer line of 12° is reached. There it attains its fullest development. The line of 72° crosses the State of Delaware going westward, extends through Central Maryland into Virginia, where it passes up the Shenandoah Valley, being sharply deflected southward by the mountain chains, thence through Western Virginia, Southern Ohio, Central Indiana, Illinois nortk of Springfield, and Southern Iowa. North of this line, the period of growth is necessarily extended, and the summers are gradually shorter and cooler as we approach the line of tO°. There one hundred and thirty days from the time of planting are not sufficient, and the necessary amount of heat which is lacking must be added in September to ripen the plant. Beyond this point, the period of growth is ex- tended to one hundred and fifty or one hundred and sixty days, but before that time has elapsed, the early frosts suddenly intervene, and cut off the crop. Occasionally the same thing occurs far to the southward, but it Is hap- pily quite unfrequent. In the vast extent of country between the line of 72° and the cotton and cane regions of the South, there is certainly no climatic obstacle to the successful growth of sorghum. The future sugar district of the United States, instead of being limited to a narrow border along the Gulf of Mexico, may now be defined to be a great conti- nental belt of irregular outline, having for its northern boundary the'summer line of 72° Pahr. CHAPTER X. MEANS BY wmCH THE MATURITY OF CANE MAY BE HASTENED. Special Means by whicli Early Ripening may be secured — Inatfen- lian of Planters to this Subject — The Period of Growth may be abbreTiated to advantage by the practice of the System of Planting and Culture previously recommended — Selection of the Earliest ripened Seeds from the most Highly-developed Plants — Early Planting — Sprouling of Seed — Drainage of Land — Use of Lime — Upland Soil and Southern Exposure of the Surface — - Direction of the Cane Eows — Importance of attention to these Particulars. To secure for the cane, in whatever latitude it may be grown, the full benefit that it is capable of deriving from the climate and soil, it is important that every part of the work of its cultivation should be done just at the right time, aud especially should every means be used by which its maturity may be hastened without injury to its growth, or to the saccharine matter in the juice. It has already been men- tioned (in Ch. lY.) that the mode of cultivation there rec- ommended for general adoption, is not only such as seems demanded by the constitution of the plant, but also that it conduces, in a marked degree, to its early maturity. In latitudes north of Washington City and St. Louis, at least, it is an important consideration to secure the ripening of the cane sufficiently early to enable it to escape all dauger from frost, and to prevent the annoyance and loss of time resulting from an undue haste in gathering and working up the crop. But Tor the astonishing neglect of the means con- (n) t2 MEANS OF HASTENING MATURITY. ducive to this end, sugar prodaction at the N"orth would now be far in advance of its present condition. Not only would it be found that much time and labor could have been saved, and the crop brought to maturity much earlier in districts where the autumnal frosts are not dreaded, but the richest and best varieties of cane would now be grown in more extreme situations, with as little risk as in climates which now seem so congenial to them. By pursuing the system of planting and cultivation above recommended, and making use of other means spe- cially directed to this end, the ripening of the Chinese cane may be hastened from thirty to fifty days. This result would be more generally appreciated if it were considered that it is equal to the difference in the length of the season of places widely separated in latitude, or to the advantage, in this respect, which the planter in Southern Virginia or Kentucky enjoys over the farmer in Western New York or Central Illinois. This effect is not merely an advancement of the period of growth, but partly also a real abbreviation of it, and is the result of a combination of favorable inQuences, among the most important of which are a proper selection of the seed, early planting (or its imperfect substitute — steeping and sprouting of the seed), drainage of the soil, the ap- plication of lime, or the selection of a limestone soil, and an elevated position with an easy slope southward, the rows of cane running in the same direction. An important advantage is gained at the outset in rigidly observing the rule to plant only the earliest ripened seeds, or those found upon the summit or at the center of the panicle and grown upon the hirgest and best of the earliest ripened canes. Such seed will produce in turn, not only an earlier, but a more healthy and robust, growth of caue than those indiscriminately selected. HOW GROWTH MAT BE ACCELERATED. 13 Early planting, as already obsei-yed, not only accelerates the ripening period, but is in accordance with the habits and natural requirements of the plant. Sprouting of the seed by steeping it in warm water, or in stimulating solu- tions of niter, chloride of lime, muriate of ammonia, or sulphate of iron, or by pouring boiling water npon it in a sieve, or by burying it in warm soil, or in a hot-bed, is to be recommended only when planting has been so long de- ferred as to make it necessary, and should never be adopted but in rare exceptional cases. Drainage, it is well known, is highly conducive to the same result. Well-drained soils are comparatively warm ; the snows melt upon them much sooner, and they are in a condition to be tilled two to four weeks earlier in the spring than those uridrained. The soil also is kept in such a condition as to secure to the plant throughout the season the advantages thus gained. The "warmth" or quickening power of soils in which lime is a predominant ingredient, is universally recognized. " It is true of all our cultivated crops, and especially of those of corn," says Johnston, "that their full growth is attained more speedily when the land is limed, and that they are ready for the harvest from ten to fourteen days earlier." Upon sorghum this effect is equally well marked. This property of a limed or naturally calcareous soil is peculiarly noteworthy, inasmuch as it is upon such land that the caue acquires a richer juice and a more full development of its best qualities than upon any other. The importance of an elevated situation in hastening the maturity of sorghum has, doubtless, been made evident to every one who has had the opportunity of comparing cane grown on the uplands with that grown in the valleys. The former will uniformly mature much earlier, besides being generally out of reach of the early frosts. High 7 74 MEANS OP HASTENING MATURITY. lands produce this influence not only because they are better drained, and less charged with vegetable matter than low grounds, but also for the reason that they are more exposed and airy, and are not bathed in the moist atmosphere productive of rank growth so characteristic of the latter. The favorable influence of an upland soil ia quickening growth is much augmented if it declines gently toward the south, and the effect is further heightened if the cane-rows are made to follow the same direction, thus re- ceiving the vertical rays of the sun at noon, and giving them a more free access to the canes, before and after that hour, than could otherwise be obtained. It is a question, however, to be decided in each particular case, whether the benefit derived from running the rows north and south, on a surface inclined in the same direction, is not counter- balanced by the injury likely to be done the land by its greater liability to wash in heavy rains, and the danger of prostration of the cane by violent west winds ; both of which evils would be avoided by marking out the rows in the opposite direction. The observance of these precautions would remove the only objections which, in some seasons, might be urged agaiist the general cultivation of the more slowly maturing but richer varieties of cane, in the vast district included between the summer lines of 70° and 72° as already de- fined. By these means also, in an extraordinarily backward or cold season, such as is sometimes likely to occur in any climate, a crop may be ripened when otherwise it would be impossible. CHAPTER XL THE "tillering" OF SORQUIIM. Influence of the Side Shoots, or "Suckera," upon the Saocharino Products of the Plant — Opposite Opinions of experienced Plant- ers as to the Nature and Value of the Lateral Shoots harmonized — Their Growth under perfect Control — They are not an Abnor- mal Growth, but are perfeutly analogous to the Tillers of Wheat — The Tillering Process common to many of the Grasses, and a wise Provision for their Increase — Under what Conditions the Growth of the Sorghum Tillers should be encouraged. Much diversity of opinion has existed among cultivators as to tlie nature and influence of the side shoots, or "suc]£- ers," which, sometimes to the number of eight or ten, spring up around the base of the central stem. Experiment, it seems, has not hitherto led to the adoption of any well- grounded opinions on this subject. Some planters have been led to believe that these suckers are really what the term, according to the popular interpretation, indicates — a mischievous and abnormal growth, diverting from the main stalk the nutriment which would otherwise have been em- ployed in enlarging the growth and enriching the juice. They advise, therefore, to pull them off whenever they appear. Others have found that these lateral shoots ar- rive at maturity almost as soon as the central one, are equally as rich in saccharine matter, and of scarcely infe- rior size, while they vastly augment the yield. They recom- mend that their growth should be encouraged. So fre- quently have these opposite conclusions been reached, as to (75) 76 THE TILLERING OF SOEGHUM. leave no donbt that in each case they were jastiSed by the results. A carefal study of the circumstances under which these results were produced, however, will show that they are in perfect harmony with each other, that they are under perfect control, when the causes producing them are understood, and that they are in obedience to a com- mon law of growth. The production of side shoots from the base of the cen- tral stem of the grasses, instead of being an unusual effect, is one of the most common and efficient means provided by nature for their increase, and even for preserving their ex- istence in their great contest for life with other plants. By this means the blue grass of the meadows by a compact circle of stems and roots is enabled to occupy the soil and to resist the encroachments of other plants in its vicinity, and to the same cause we owe the fruitfulness of the har- vests. The tillering process of wheat is perfectly analo- gous to the so-called " snckering " of sorghum, and, in offering an explanation of the one, we but reiterate facts well known as affecting the other. For convenience, the mode of development may be designated in each case by the same name. It is to be distinguished, however, from a peculiar ramification of the stalk above ground, to which the sorghum is sometimes subject in wet summers. In oats, true branches spring from the axils of the leaves, and these branches bear grain which ripens very unequally, and to this mode of increase that last mentioned corresponds ; but true " tillering " is an underground process, and it is char- acteristic of cane and wheat in common with many other plants of the same family. The lateral stems in this case spring from underground buds. Although thus connected with the central culm, they derive their nourishment from roots of their own, which increase in number and length TILLERING OP WHEAT. 77 as the necessities of these secondary stems, to which they are the purveyors, seem to require. The external devel- opQieut of a new side shoot is always simultaneous with the issue of a new set of roots springing directly from it, wliile the growth of the proper roots of the central stem is not retarded by t'his process, being more widely extended at that time, and the surrounding earth not being exhausted of nutritive materials. At a later period, however, this exhaustion occurs; but then the widely branching roots seek a fresh supply of food beyond the circle which at first supplied their wants. An increaite of side shoots, there- fore, is always an index of an increased development of the root. Extensive tillering of wheat is always an evi- dence of vigor and hardihood. Where this does not occur, either the ground is too poor to afford nutrition to new roots to sustain new stems, or the weather during the early growth of the plant has been too mild, and the single central stalk has been pushed forward too fast, the natural period of rest before "shooting " not being long enough to allow of the formation of a more widely extended root surface than is necessary for the supply of a single stem, or it is the result of too thick sowing, the development of the roots being similarly restricted. In all those cases where but a single stalk is produced, it grows up sometimes of average size, but oftener weak and thin, and from the same cause, viz. hinderance of root development. On the other hand, when not too thickly sown, and when the soil and season are favorable to its wants, instead of a solitary stalk and a single meager ear, each seed gives to the grasp of the reaper a clump of healthy stems and nodding heads, pro- ducing a hundredfold. Tillering, therefore, is a natural process, conducive in a high degree to the health, and vigor of the plant. Let ns now consider whether the discordant statements 7* 78 THE TILLERING OF SORQHUM. already referred to, as to the effects of this process in the case of the sorghum, may not be easily reconciled, and a rational method of treatment arrived at, adapted to the requirements and true nature of the plant, and to the external conditions of growth to which it is necessarily subject. It is observed that cane does not tiller when planted very thickly in the drill, nor when it is put in thin land, shallowly plowed or badly tilled ; nor generally when late planted. In the first case mentioned, root growth Is checked by too thick planting in the drill ; the result is that not only tillering is prevented, but the stalks grow thin, soft, and fibrous, instead of strong, hard externally and succulent within. In the next ease, where the condition of the soil is at fault on account of natural sterility, or bad tillage, the cane crop is still more a failure. When late planted also, tillering is checked, especially if the season which fol- lows planting is not unusually cool and wet. The cause is plainly due to the fact that the natural period, within which the roots are to be formed, is so ranch abbreviated that sustenance enough can be gathered only to support a single stem. Has not this system of impoverishment, then, a tendency to degradation ? Is it from parentage origin- ally produced by such treatment that we should seek to perpetuate our stock for future use ? Does not the con- currence of these facts lead inevitably to the conclusion that the noblest type of the plant, the healthiest, the rich- est, the most valuable in all respects, is to be sought in a form exhibiting the freest and fullest development of all its organs in the manner best adapted to its nature ? The mode by which such a result may be secured is al- ready indicated in alluding to those influences which con- duce to the opposite. Deep cultiire in a light, mellow- well-drained soil, and early planting in hills or in drills, with DISCORDANT OPINIONS RECONCILED. 79 the seed so thinl}' distributed as to permit of each forming a stool, are plainly indicated. The proper distance between these stools or hills, in order to produce the heaviest crop of the best quality of cane, will vary somewhat according to the time of planting and the nature of the soil and sea- son. But when the above conditions are complied with, as heavy a crop as the land can ordinarily sustain can be obtained with the stools about 15 inches asunder in the row, and the rows 4 feet apart. No suckers should be re- moved, for, if the proper precautions are observed, no more suckers will be thrown out than the roots are able to sus- tain. It is easy to see that in cases where the growth of side shoots is encouraged for a time by any mode of treatment by which the roots are permitted to extend themselves, and then the development of the latter is suddenly and perma- nently checked, an immature and badly developed stool will be the result, with which (thus produced by a mode of treatment inconsiderately adopted) planters have had good reason to be dissatisfied. When, on the contrary, favor- able influences were secured, especially early planting of the seed, the heavy yield and excellent character of the crop, where the suckers have matured, are sufficient to lead to a very different judgment. It will be evident from what has been already said, that the difference between early and late planted sorghum is similar in kind to that between fall and spring wheat. It is a difference of growth, vigor, and development. Au- tumn-sown wheat, during the milder intervals of winter, when a slow growth is encouraged, acquires a vigorous constitution ; it is allowed sufBcieut time to develop its roots, although the blade may have perished in the frost; and when confirmed mild weather comes, it is ready to put forth a luxuriant clump of blades and stems. Spring wheat 80 THE TILLEEINQ OF SORGHUM. is not permitted the natural period of rest after germina- tion that the wants of the plant seem to require. There is no marked cessation of growth in the blade after it has appeared above ground; it tillers very little, and requires to be more thickly sown than winter wheat. The inferior quality of the grain of such wheat is generally well known ; the plant is less vigorous ; it is not capable of enduring such vicissitudes as the cold-hardened winter wheat ; is more subject to disease and to some insects, and unless very thickly sown, is peculiarly liable to injury from drought in summer. If we should not desire to perpet- uate our stock of wheat from this inferior and unhealthy sort, is it wise to subject to such an ordeal a plant exhibit- ing the same characteristics under similar circumstances, and to expect that, year by year, it will not degenerate ? With the exception that the half dormant period in sorghum is not so extended as in wheat, and that it has not sufficient hardihood to endure the cold of winter, the analogy is perfect. In point of hardihood it seems to occupy a middle place between our spring-sown grains and those sown in the fall. There are some varieties of imphee it is said which do not tiller. If, like that of Indian-corn, this is found to be their natural mode of growth, it would be unwise to at- tempt to interfere with it; but if it is the result of the "cramping" system, as sometimes pursued with the Chinese variety, we may readily account for the feebleness of growth and light yield of many varieties of the African cane. My own observation leads me to believe that the tiller- ing process is natural to all varieties of sorghum. All the common kinds of imphee grown from seed sown in early spring, in the latitude of Pittsburg, were found to conform to it, although the tendency to multiplication in this way seems, in the case of the Chinese cane, to be peculiarly strong. CHAPTER XII. HARVESTING THE CANE. Preparation of the Cane for the Operation of Crushing, Removal of the Blades — Their Proper Function discharged at the Period when the Seed is Ripe, when, they should be removed — Their Value as Fodder — The Mode of stripping Cane — How and when to top Cane — Removal of the Cane from the Field — Effect of Frost upon Cane under Different Circumstances. The preparation of the canes for crushing is best per- formed in the field. The first step is to strip off the leaves. This should not be commenced until the plant has matured. Prom the nature and functions of the leaf, as at present understood, we may infer that direct and permanent injury to the whole organism of the plant would be the result of the removal of the leaves before that period. While they have been compared not inaptly to the lungs of animals, the leaves are known to discharge other com- plicated functions not analogous to those of the organs of respiration. They are the laboratories in which organic products, such as sugar, starch, and albumen, by complex chemical changes, are prepared for the use of the plant, from the ordinary constituents of the air and soil. They are the outward recipients likewise of very remarkable influ- ences derived from the sunbeam ; namely, those excited by light, heat, and the actinic or chemical rays, all of which reach the inner fabric chiefly through the leaves. The leaves of the cane, however, seem to outlive their (81) !?-i HARVESTING THE CANE. office. Unlike what commonly occurs, vitality seems to linger longer in the leaves than in any other organs ; long after the contents of the cells have undergone their final transformation, and the seeds have matured. Oxidation does not occur as early as in the leaves of most plants, and consequently they retain for a time their green color and vigor. The proper time, therefore, to remove the leaves is during the few days immediately subsequent to the ripening of the seed and the full maturity of the juice. The seed is then hard, the husk (glume) has received the full depth of color natural to it (very dark purple or black iu the Chinese cane and Oom-see-a-na, and various shades of purple, red, and yellow in other varieties), the panicles (seed heads) begin to spread and droop, and the stalk is more or less yellow or orange colored, according to the variety. The blades at that period are almost as green as in midsummer, and their nutritive qualities as forage for horses and cattle are then unimpaired, and if properly cured, they are fully equal, ton for ton, to good hay, and are eaten with even more avidity. The blades and seed, if taken care of, will generally repay the whole cost of cultivation. Of the former, half a ton, and of the latter, thirty bushels, is an average yield per acre. In a mature state, the Chinese cane, if not exposed to severe frosts, may be allowed to remain in the field uncut, after being stripped, for a few days without injury. Some of the later ripening imphees, however, will not bear this treatment, and soon become sour ; a condition to which the Chinese cane, when unripe, is subject under similar circum- stances. The importance of stripping off the blades before the cane is cut, will be found to consist chiefly in the saving of a large amount of excellent fodder, and in an economioal MODE OF STRIPPING CANE. 83 nse of' time, by doing a needful part of the work in ad- vance' of the period of cutting, when time could not so eon''euiently be spared. This operation seems to be at- t-aded by no decided inflnence upon the juice of the stalk, although higher crystallizing powers have been claimed by some for the juice of canes so treated, which are supposed to be due to the more free exposure to the sun and air thus afforded. The practice of stripping cane by hand in the field is so slow and troublesome as to be impracticable on large plan- tations, and the labor is still greater after the canes have been cut and piled. Tet this mode has the advantage of securing the preservation of all the fodder in the best con- dition. But by far the most rapid way is to strike off the blades of the standing cane with a kind of woqden sword, double-edged, about three and a half feet long, and in shape like a long scutching knife, used by flax dressers. With this implement a man can readily blade three- fourths of an acre of thickly set cane in a day. A large proportion of the leaves may subsequently be raked together in heaps, and saved, but almost all that fall in the row are left, as they cannot be caught by the rake either among the standing cane or the stubs. Cattle turned into the fields after the cane has been removed, will eat greedily all that remains, and in some cases it may be more economical to leave all the blades on the ground to be consumed in this way. The rapidity with which cane can be stripped in the way last described, ren- ders inexcusable the slovenly and wasteful practice of passing it unbladed through the mill. The two upper joints, with the leaves attached to them, should generally be removed along with the head when the stems are topped, and in the operation of stripping, the two upper leaves should not be stricken off. The best topping instrument Is a carpenter's broad-axe, the heads being cut 84 HARVESTING THE OANE. off on a block at the time the canes are received from the wagon which conveyed them from the field. Topping cane with a corn knife is wearisome work, and when done in the field renders necessary the additional labor of gathering np the fallen tops, and hauling them in separately. When the two upper blades are not removed, they serve as a guide to the eye of the workman who arranges the cane in bundles upon the block, and the topping is then done with the axe with great rapidity and nicety. If this is done in fair weather, the seed is then in a condition to be put under shelter and dried rapidly, a matter always difficult of ac- complishment when the tops have been cut off in the field and thrown upon the ground. The latter, on account of the scanty and impure juice which they contain are valu- able only aj fodder. After being topped, Chinese sorghum canes will average six to eight feet in length. They are then about two feet longer than the stalks of ribbon cane, grown in the Southern States, when prepared for the mill. On some sugar plantations, not more than three or four feet of the stalk of the Southern cane is suitable for being crushed.* The sorghum stalks are more slender, but they may be grown much more densely on the ground. * De Bow's Eesouroea of the Southern and Western States, p. 269. CHAPTER XIII. STOBINa THE CANE. The Sugar Factory, what Buildings necessary — Cane Sheds, their Construction and Arrangement — Trash Thatch u. Convenient Material for Roofing, etc. — How used — Conditions essential to the Preservation of Cane — Length of Time during which it may be kept uninjured — Experiment — Uniformity of Tempera- ture necessary. The cane should be cut and removed from the field if ripe, immediately after the operation of stripping has been finished. If it has been planted early (see Chapter IV.), it will be in a fit condition for removal, ordinarily, before it has been touched by any frost capable of doing it barm. The iraphees in general are more sensitive to cold than the Chinese variety at corresponding periods of their growth, but most of them mature earlier, and are not so much exposed late in the season. The fact that ripened cane will usually endure without injury the earliest autumnal frosts, should not induce any one by a system of late planting to run the risk of ruining his crop by exposure to the often intense cold of October nights, a calamity which, by pursuing a different course, might have been entirely avoided. The damage done to a cane crop by frost is to be meas- ured, however, not by the intensity of the cold, but by the rapidity of the subsequent change of temperature. A com- mon hoar-frost rapidly melting upon cane in the morning sun, does more harm than a ground freeze gradually abated 8 (85) 86 STOKING THE CANE. by cool winds and cloudy skies. In freezing, the delicate cell-walls of the plant are raptured by the expansion of the fluids which they inclose, and the saccharine and nitro- genous principles become intermingled if a thaw suddenly sets in. But if a freeze is succeeded by a gradually in- creasing temperature prolonged through a period of two or three days, the cane remains comparatively uninjured. The ruptures of the cellular organs gradually close up, and catalysis is prevented. We may easily correct the inju- rious effects of sudden extremes of temperature by storing the canes, after cutting, in a proper manner ; but in the field these changes cannot be controlled, and therefore it is indispensable that the crop be taken off the ground and placed under shelter as soon as ripe. As already indicated, the whole process of sugar pro- duction may be conveniently divided into three successive periods. The first of these embraces the period of culti- vation and ends with the harvesting and storing of the cane. The sugar- house or factory, however humble, con- sists essentially of three parts or divisions, correspondent to those periods, and successively used, viz.: 1. A store- house or repository for the cane. 2. A mill-house and evaporating-room. 3. The sugar-house proper or curing and crystallizing-rooms. The business of sugar production from sorghum will not be successfully conducted, and will not assume its true rank as a great national industrial pursuit until convenient and substantial buildings are made to take the place of the mere sheds commonly used only to protect the workmen from the elements. Especially when the work is on a scale of considerable magnitude, ample provision should always be made for carrying it forward in each department inde- pendently, and in a perfect and thorough manner. Neat- ness and adherence to system should rule throughout the STOREHOUSE FOR CANE. 87 whole establishment, even in minute details. The build- ings should be contiguous and sufficiently roomy. The cane-house or barn need be nothing more than a large square structure, eight to ten feet in height at the eaves, inclosed on all sides sufficiently to prevent exposure of the cane to the sun, rain, or snow, and covered with a tight roof; or a square area contiguous to the mill, occu- pied by parallel ranges of long and narrow sheds extending east and west, and screened from the sun at the sides and ends, is a cheap and good substitute. These shed roofs should pitch toward the south, and if they are ranged close together, only the unprotected ends and the south side of the south- ernmost of the series need be closed up. These buildings may be constructed of any materials that will afford suffi- cient protection to the cane. A thatch of begasse, the crushed stalks being received from the mill without entan- glement, and laid aside in small bundles to dry, would an- swer an excellent purpose, and would be cheaper perhaps than any other materials, and equally as durable as others much more costly. The same in many places where lum- ber is difficult to be obtained, as in some parts of our Western country, might be employed in closing up the sides and ends of these buildings just as straw is used in some places for walls of outhouses.* For this purpose the fresh trash will be found preferable to that which has been dried, as it "A convenient way is to set upright poles about eight inches apart, and draw wisps of straw (or trash) round each, so that both ends of each wisp shall be outside. It is b^st to lay these in horizontal courses, and beat down each course as it is laid, keeping it uniform and tight. As the filling in with straw progresses, there may be a split pole woven in once in three feet or so to hold the uprights in place. The straw is finally to be raked down on the outside so as to shed rain well. This makes a tight, warm, and lasting wall. The inner side is quite even, and it may be sprinkled with mud if there is danger of the animals pulling out the straw to eat." — Amer. Agriculturist, vol. xxiii. p. 9. 88 STORING THE OANE. Is more pliable and can be packed more closely. The employment of such materials would be highly objection- able in structures close to the evaporating-room or any parts of the buildiug in which fires are used, but no un- usual risk would be incurred if the cane sheds occupy the proper position, the extremity of the range of buildings farthest removed from the evaporating-room and sugar- house. In such buildings Chinese cane, if not injured by frost previously to being cut, will keep perfectly uninjured until January if necessary. The canes having been previously topped and bladed may be either tied in bundles of forty or fifty stalks together and set in on the butt ends closely under shelter, or they may be laid horizontally in compact piles, and in either case, if screened from the sun and rain, the density of the juice and the bu.'kiness of the stored mass of canes will preserve them, almost unaffected by the sudden fluctuations of temperat^^^e common in early winter,, and even if they are frozen hi protracted and severe cold they will thaw gradually ir/this condition without hurt. But the knowledge of this fiyt should not tempt any one to protract the working up of a crop beyond Christmas. The confirmed cold weather, which in the latitude of the Middle States usually sets in shortly after that time, sus- pends the work. Subsequent evaporation of the juice in the stalk and repeated freezing and thawing render it almost worthless before spring. Evaporation goes on as rapidly in frozen as in unfrozen cane, and is alone a source of great loss. Experiment proves that no mill is capable of ex- pressing all the juice contained in the stalk, and that when the juice has become dense by evaporation, a larger pro- portion of it, and consequently of the saccharine matter, is retained in the stalk than when it is more dilute. Ther-:-; is a loss then of sugar or syrup to the manufacturer from HOW FREEZING MAY BE PREVENTED. 89 this source directly proportionate to the length of time during which the cane is kept stored beyond the short period of "seasoning" when the juice is in the best con- dition. The stalk also becomes more tough and fibrous, and thus affords an additional obstacle. Economy there- fore dictates the utmost diligence until the work is done. These facts lead to the inference that the question as to the length of time within which it is possible to keep sorghum cane in good preserration is of more interest to the carious than practically important. Yet an observa- tion directly illustrating this point seems not out of place here. The preservation of the cane seems to depend chiefly upon a single external condition, the temperature of the surrounding air. I have found that it does not undergo any apparent change during the winter months in a uniformly cool atmosphere. The warm intervals which so frequently and suddenly alternate with the cold in our winter climate, often, however, elevate the temperature of the air in the shade sufficiently to permit fermentation to set in. Any means by which these extremes of climate may be moderated and freezing prevented will preserve the cane with but little alteration in the quality of its juice, until natural evaporation has rendered it worthless. Pur- suing a plan accidentally discovered, I have kept cane In good condition until the month of March. It was fully ripe when cut, and was laid in small heaps across timbers resting upon the cellar floor of an outbuilding. The door of this cellar was allowed to remain open all winter. The drainage was defective, and water had collected upon the floor to the depth of nearly a foot after the cane had been stored. Cold weather coming on, the cane was not worked up, but ] found that the alternate freezing and thawing of this body of water kept the cane above it at a uniform tem- perature, and in an unfrozen state throughout the winter. 8* 90 STORING THE CANE. This effect may be thus explained. Water in freezing, or in being converted into the solid from the liquid state, evolves heat previously latent, causing an elevation of tem- perature in bodies in its immediate neighborhood. The cane from its position, in this case, was the recipient of a portion of this heat, and during the whole of the coldest weather when the congelation of the water on the cellar floor below was gradually going on, it was thus kept above the freezing point. The greater density of the juice as well as the protection afforded by the cellular and woody sub- stance of the stalk within which it was inclosed also con- tributed to this effect. On the other hand, when very mild weather suddenly ensued and the ice on the subjacent water began to melt, it in turn absorbed heat from the cane, but not so rapidly as to reduce it at any time to the freezing point. The surrounding air within the cellar also suffered a depression of temperature in like manner nearly equal to what it had been during the previous cold weather, being thus tempered by the water in the same way that a lake mitigates the extremes of climate on its shores. CHAPTER XIY. PROCESS OF MANUFACTURE. Distinctive Features of the Process of Manufacture herein recom- mended — Difficulties attendant upon Crystallization from an Impure Solution — Defecating Substances, Requirements to which they must conform — Advantages of a well-defined System — Errors which have hindered Progress in Sugar Production from Sorghum — Necessity of a New Mode of Treatment — Disadvant- ages of the Common Mode — Constituents of Sorghum Juice- Thorough Defecation the great Desideratum in any Method. I DESIGN to embody in the following pages the details of a system of manufacturing sugar and syrup from sorghum, adapted to common use. This system is based strictly upon the results of oft-repeated and carefully-con- ducted experiments, and it will be found to embrace some facts not previously known, the application of some former discoveries to new uses, and the incorporation with these, wherever practicable, of any other modes of working that were found upon trial to be of practical value, and worthy of being perpetuated. Among the distinctive features of this process are the following : 1. A method by which the crystallizable sugar in the juice is separated from the impurities which prevent its assuming the crystalline form. This consists in the use of a chemical agent which it is believed has not heretofore been applied for the defecation of sorghum juice. (91) 92 PROCESS OF MANUFACTURE. 2. A new mechanical device to effect the separation of the scum containing the green coloring matter and fecn- lancies without the loss of- time, the labor, and the incon- venience which has hitherto attended this part of the work. 3. A means of depriving the syrup of the harsh vegetable taste common to it without the use of the expensive and inconvenient appliances regularly employed by the refiner. The syrup is thus cheaply refined at once, during the reg- ular progress of the evaporation. 4. The employment of a finishing pan of such construc- tion and form as to permit the evaporation of the syrup to be protracted to any required degree, without danger of carmelizing the sugar, which may be instantly removed from the action of the heat when the proper point of con- centration is reached as indicated by a thermometer, and discharged by dumping it into a cooler — thus affording the means of making readily a pure syrup of perfectly uniform density, or of reducing the syrup to the point of density at which crystallizable sugar may be obtained of the best quality and in the greatest abundance. The above are inseparable- and indispensable parts of this process, and I have found them to be requisite to uni» form success in the manufacture either of sorghum sugar, or of a superior quality of syrup. Other topics also, of scarcely minor importance, demand attention. The whole subject is one which is fraught with interest of a higher character than is indicated by the nature and results of the investigations which have come to the knowledge of the /public. At the first view, it might seem that the art of extracting sugar from a liquid so rich in it as sorghum juice has proved to be, is not a matter involving any pecu- liar difficulties in practice ; but its apparent simplicity vanishes when it is found that this saccharine liquid con- tains, intimately associated with the sugar, a variety of other DIFFICULTIES TO BE OVERCOME. 93 substances of very different chemical properties and rela- tions, some of which are yet but imperfectly understood. Most of these substances, uncrystallizable themselves, pre- vent, by their presence, the sugar from assuming the crys- talline form — the only form in which it can be obtained pure. In order that we may make sugar, therefore, it is necessary to remove first these extraneous substances from the saccharine solution. But the means used for this pur- pose must be well chosen. They must be adequate ; they must be of such a kind as to be adapted to ordinary use on the large scale ; the defecating agents must be harmless to health if inadvertently added in excess to the juice, and must leave no harmful compounds in any product which is afterward to be used as an article of diet; they must be suSiciently convenient in form, and low in price, and they must not exert an injurious influence upon the constitution of the sugar. We find ourselves at once confronted by a delicate chemical problem. Here nothing good can be accomplished by hap-hazard. We must have a clear view of the nature of the material to be acted upon ; means must be employed commensurate to clearly defined ends ; the best methods of usiug such means must be understood, and a certain degree of dexterity in their use must be ac- quired. And here, as in all other industrial pursuits when successfully prosecuted, if a strict adherence to system is observed, and if the relations of the successive parts of the process to each other are well understood, the different operations will be performed with precision and facility, and what may have caused much perplexity at first, will soon appear perfectly simple. Much time would have been gained, and many errors in practice would have been avoided, if some important truths had been earlier recognized. One of these is that the juices of these new canes exhibit properties which are dif- 94 PROCESS OP MANUFACTURE. ferent from those of any other plants from which sugar has beeQ extracted. Hence the necessity for a new and special mode of treatment adapted to these peculiarities. Many persons also have been slow to accept the fact that the saccharine matter in ripe sorghum consists almost exclu- siyely of cane or crystallizable sugar, and that previous to the maturity of the plant, this kind of sugar is present, if at all, only in very small quantity — grape or fruit sugar (practi- cally uncrystallizable, and of lower grade) being abundant. The nature of the other constituents of the juice has also been misunderstood. Lack of information upon these and other points, has led some persons whom a little investiga- tion would have taught better, to adopt expensive methods borrowed from the beet and cane sugar manufacture in France and Louisiana, which, in the end, they have been compelled to abandon after much disappointment and loss. The want of success which has attended these experiments, has repressed investigation, and the popular mind, except when excited by some accidental example of a successful crystallization, seems to have gradually adopted the con- clusion that the production of sugar requires the use of some incomprehensible and extraordinary means too ab- struse and difficult for ordinary practice. And the extreme facility with which a tolerably palatable article of syrup can be prepared for domestic purposes, has increased this apathy, and perhaps more than anything else, checked the progress of discovery. The inventive genius of the country responding to a temporary want, yet not rising above it, has produced a score of evaporators, adapted in a greater or less degree to the production of crude syrup ; but these, in the main, embracing only various modifications of a single idea, can serve no higher purpose than that for which they were originally designed. Rapid evaporation, and the constant removal of the scum by skimming, constitute EREORS — COMPOSITION OP CAljrE JUICE. 95 almost solely the basis upon which their efBciencyis alleged to rest in making syrap by the ordinary mode; but any one that has made himself acquainted with the nature of sorghum juice is well aware that boiling and skimming, unassisted by other means, cannot be relied upon to pro- duce sugar. The fact that sugar has, in some few in- stances, been produced by such means, is no disproof of this assertion ; for sometimes samples of cane may be selected, the juice in the lower joints of which is almost a pure solution of sugar, and consequently it needs no defeca- tion ; but such samples of cane are very rare, and the in- stances in which sugar has been produced even from them by the use simply of " pan and skimmer" are still more so. I have alluded to these particulars here for the reason that I believe them to embrace the most prominent errors in theory and practice now in vogue among planters of the Northern cane ; and in order that the established facts upon which success in the production of sugar from sor- ghum will be found to be based, may not be confounded with them or misunderstood. Ripe sorghum juice, as it flows from the mill, is an im- pure solution of cane sugar. It commonly contains a small proportion of grape or fruit sugar also. Other substances also, in less quantity, are either dissolved or mechanically suspended in the liquid. The chief of these are chloro- phyll (or the green coloring matter), starch, dextrine (the gummy matter), vegetable tissue, pectine or vegetable jelly, vegetable albumen, gluten, and casein (the last three containing nitrogen), acids, salts, and extractive matter. Other modifications of these are found in syrup, and are secondary products, and are not contained in the raw juice. Liquid sugar is an example. It is a degraded form of cane sugar, perfectly unerystallizable, and is produced by the action of heat and imperfect processes of manufacture. 96 PROCESS OF MANUrAOTURB. The cane sugar cannot be induced to crystallize while any considerable quantity of the substances with which it is thus associated is present in the solution. To break this alliance is, then, the great desideratum, and, as already stated, the merits of the system of manufacture hereafter to be described, will be found to consist mainly in the high degree of completeness, ease, and economy with which .this is done. The means used, both chemical and mechanical, have been studiously adapted to each other and to the end in view. CHAPTER XV. PROCESS OF MANUFACTURE (CONTINUED^. Description of the Apparatus and the Mode of using it — General Arrangement of the Different Parts — Description of the Evapo- rating Range, Materials used in its Construction — Tanks, etc. — Details of the Mode of Operation — First Stage — Lime and the Defecating Agent, how employed — Saturation of the Acid — How the Scum is separated without the usual Process of Skimming — Arrangement of Division A — Requisites to secure Success — Pre- cautions — Fuel — Chemical Agents. If the reader will refer to the engraving (Frontispiece), and will examine carefully the representation of the evap- orating range there given, much unnecessary description of the apparatus which I recommend to be used will be avoided. The relative positions of the crushing mill and the evaporating train may be varied according to circum- stances. It is necessary only that the mill be placed upon such an elevation, natural or artificial, that the juice, as it is received from it, may flow into the tank (M), and thence through the descending range of pans into the cooler (F). The pipe (P) which supplies the tank (M) with juice from the mill, may be cheaply constructed of common chain-pump tubing, except when mills of the largest size are used. This pipe when made (as shown in Fig. 5, Oh. XXX.), consists of a number of lengths of this tubing united together and laid in a trench, extending from the mill to the tank, with two upright pieces of the same mate- 9 (97) 98 PROCESS or manufacture. rial jointed to it at the opposite ends. One of these np- right arms is about a foot longer than the other, and its upper end is fitted into the bottom of a tight box or large backet, containing a coarse wire strainer, which is so placed as to receive the juice as it flows fron the mill. The other arm carries a spout at one side, projecting over the side of the juice tank. The ends of the main tube which support these uprights are closed, the one next the mill permanently ; in the other a molasses gate, or movable plug, is fitted, so that the pipe which should incline slightly toward this end, may be completely, emptied at any time. This should al- ways be done at the close of each day's work. The pipe should be painted, the joints cemented with white-lead, and the upright pieces securely braced, and when it is placed in position, the bucket on the one arm of the tube should be about a foot above the level of the spout on the other.* The juice tank M may be made of one and a half inch pine plank. The joints are cemented with white-lead, and it is divided into two compartments by a water-tight par- tition. The depth of this tank should not exceed three feet, but its other dimensions may be extended to conform . to any required capacity. It is most convenient, however, to have each half of it of such size as to contain as much juice as is discharged from the mill in one hour. It should be thoroughly painted inside and out, with red-lead or iron minium, and well dried before being used. The evaporating apparatus consists of four sections, A, * This is necessary to prevent the overflow of the buclset. A column of juice largely commingled with foam, just as it comes from the mill, is lighter than a column of equal height in the vertical tube at the oppo- site end from which the foam has separated. The equilibrium is main- tained only by the liquid rising to a higher level in the one arm than in the other. If the bucket stands but slightly higher than the discharging spout it will overflow. EVAPORATING RANGE. 99 B, C, D, placed in a descending range, the pan A being the highest in the series. The first three are stationary ; the fourth, D, is movable on a horizontal axis. They are constructed of sheet copper, or iron with wooden sides. When of the last-mentioned materials, both surfaces are protected by a heavy coating of iron paint.* Pans with bottoms of galvanized iron are furnished to order, bat the zinc coating is not preferable in any respect to either the plain or the painted iron surface, and is more expensive. The furnace should be of brick- work, of a uniform inside width throughout, corresponding to the width of the space between the abutments in division A. Each pan of the series is set perfectly level, but no two of them are in the same horizontal plane. The fall from B to C in a range of medium length should not be less than ten inches ; from A to B and from C to D, two inches each.f The furnace is snffi- * The advantages of this paint, iron minium, or brownish-red oxide of iron, "are its solidity, durability, cheapness, and above all, its prop- erty of preserving the iron completely from oxidation, and of harden- ing the wood. . . . It is destined to supplant red-lead (lead minium) and other pigments that have been used until now for coating wood, iron, and other metals. It forms a smooth and stripeless coat upon the iron, varnishing as it were the metal and preventing the atmospheric influences upon the paint. . . . Iron minium mixes readily with other colors, such as black, yellow, green, etc., and by so doing a variety of colors is obtained to the convenience of persons who would not like the dark-brown of the iron minium paint. It has been proved by exper- iments that the iron minium paint lasts twice, and even three times as long as red-lead paint. ... It resists generally the strongest heat. . . . It is to be applied in several layers : the first ought to be thin, the second a little thicker. It is employed the same as other paints, with boiled or unboiled linseed oil. If unboiled oil is used, litharge or any good siccative may be added, but not turpentine." — [Condensed from London Practical Mechcvnics' Journal in Scientific American, vol. xi. p. 3sr.) f Printed directions for setting up the apparatus are given on another page. 100 PROCESS OP MANUFACTURB. eiently deep at the mouth to give it a slight inclination np- ward from the level of the grate bars, thus securing a good draught, and throwing the flame closely against the bottoms of the more depressed pans, C and D, at the after part of the range. A great saving of fuel and a more uniform distribution of the heat is thereby secured. The division of the evaporating surface into three separate sections, which is indispensable according to this arrangement, is a security against its being warped by heat, which always occurs when a long unbroken surface is used, and the sep- arate sections may be' packed for transportation in small space and carried without injury. The cooler is simply a large shallow wooden box of the shape represented in the drawing, and made impervious to liquids by iron paint. It may be mounted upon a track, and at the close of each day's boiling may be run along a tram-way into the draining-room, and emptied of its con- tents. The evaporating train, tanks, etc. being arranged as de- scribed, the freshly expressed juice passes into the pipe through the wire strainer, which separates all the coarser fragments of cane pith, etc., and flows directly into the tank. The outlet of the conducting pipe should be close to the partition in the tank, so that by means of a short, movable gutter or T-shaped spout, the current of juice may be turned into either division of the tank at pleasure. Each division, as already stated, should be ca- pacious enough to hold as much juice to within six inches of the top as the mill is capable of expressing in about one hour. Two cocks or molasses gates (one for each division) must be inserted in the side of the tank within about four inches of the bottom.* The tank should be made of such * Only one of these is represented in the engraving. PROCESS OF DEFECATION. 101 dimensions that, with a partition one and a half inches thick, dividiQg it in the center in the direction of its least diameter, each half will contain just 100 gallons, between the level of a mark made "on its side six inches from the top, and the level of the exit cock near its bot- tom. This is a convenient measure of juice, and can be finished to the "striking" point on one of the larger evap- orators in one hour. Begin by filling one compartment of the tank up to the mark, and then turn the flow of juice into the other. Have ready a tin dipper or measure which will hold about half a gill, mix in a bucket this measure of milk of lime with two or three quarts of juice from the division of the tank already filled, return the mixture to the tank and stir it thoroughly. The lime should be added in sufficient quantity at this time not only to neutralize the small quantity of free acid found in ripe sorghum juice of the best quality, but also to im- part to it the very feeble alkalinity which, for a reason to be hereafter mentioned, it should possess at this stage of the evaporation. Juice of a nearly neutral character is seldom obtained in large quantity, and lime will always be needed. To ascertain whether any more lime should be added, dip into the juice already mixed with the milk of lime a small slip of red litmus-paper, or yellow turmeric- paper. No more tempering will be required if the color of the litmus is changed to a tint in which the blue slightly predominates over the red, or the turmeric yellow deepens to a faint shade of brown. But if no such change of color is indicated, more milk of lime must be added grad- ually until the test paper takes the required tint. Then add to each 100 gallons of the juice one pint of the clarify- ing solution, and stir thoroughly. The juice is then ready to be admitted into the evaporator. This should be done 9* 102 PROCESS OF MANUPACTTJKE. while the other division of the tank is receiving its charge of juice. Water should previously have been turned into the evap- orating range to start vrith, and a strong fire of dry wood kindled in the furnace. When the water has begun to boil in the lower pans, admit the tempered juice from the tank in a continuous stream. The conduit L will convey it to the head of the pan A. At the same time open partially the gate P. The simple and effective manner in which the clarification is accomplished, and in which the boiling juice itself is made to do the work of skimming, may then be seen at a glance. The successful working of this part of the apparatus, however, is limited by certain conditions which should here be noted. From the rear of the pan A, two abutments or ledges S S extend along its bottom for about two-thirds of its length, toward the front. This pan projects over the sides and front of the furnace wall, and the abutments must be so placed as to stand directly over the inner face of the side walls, and terminate just over the end wall of the furnace. That portion of this pan, there- fore, which is situated between the abutments is ex- posed to the full heat of the fire, while the remainder is comparatively cool. The flow of juice into the pan must always be duly regulated by the rapidity with which it is heated, defecated, and finally discharged through the gate P into the next division or pan B. The bed of juice in the pan A should be kept at a uniform depth of about half an inch, and then a sheet of rapidly boiling juice will overspread the whole central space between the abutments. The sur- face of the boiling liquid throughout this space is conse- quently much elevated, while toward the front of the pan, and within the bays or scum receptacles R R at the sides, it is not heated. A surface current is created which carries EVAPORATION, HOW CONDUCTED. 103 the seum rapidly forward and down into the recesses R R, where it lodges, and, as it cools, it becomes densely com- pacted and displaces any unclarified juice that may have collected there at the commencement of the operation. At the same time that the scum is being separated and carried forward, an under-current of cold jaice is continually pass- ing onward in the opposite direction and becoming rapidly heated. At a certain point (A) as it advances, it is sud- denly thrown into ebullition, when it parts company with the scum, and impelled onward by the colder current be- hind it, it escapes by the gate P into B. The gates P P, the openings of which are protected by wire gauze, afford at any time a convenient exit also into B, for any clarified juice which may be thrown into the bays when they are not packed with scum. Ordinarily, however, these gates are not used as outlets for any considerable quantity of the juice into B, as there is sometimes danger of unclarified juice passing through them. They should be closed at the commencement of boiling, and afterward opened only just enough to allow the small proportion of boiled juice upon which the scum has floated into the bays, to slowly filter through them. A return current is thus prevented, and the scum is forced back into the head of the bays and re- mains there. At convenient intervals, once every half hour or more, this dense mass of scum is lifted out bodily by means of a large flat dipper or shovel of such width as to slide closely inside the bays. A strong heat must be uniformly maintained in the fur- nace. Feed the fire with regularity, and do not add so much fresh wood at once as at any time to check the boil- ing in the front pan. If at any time this should occur, close the entrance gate into B, and stop the flow of juice from the tank until vigorous boiling is resumed. When coal can be had, it may be used in small quantity along 104 PROCESS OP MANUFACTURE. with the wood ; a shovelful thrown in now and then is very useful in quickening the fire, but care must be taken to keep the grate bars from becoming clogged with cin- ders. The part played by the chemical agents in this clarifica- tion has not been adverted to. It will be noticed on a subsequent page. The most important advantages result- ing from their use are not all made apparent at once to the eye; but the visible evidences of purity — transparency, brightness, and lightness of color — are not produced to an equal extent by the use of any other means which I have been able to discover, or that I believe may be innocently employed. When these clarifying agents cannot be obtained, lime may be substituted for them, but it is far less effieleht. A quantity of the cream of lime should be prepared before- hand (Chap. XXX.), of uniform consistence and strength. The exact measure of it which is necessary to be added to a given measure of the juice to cause it to exhibit the faint alkaline reaction required, should be ascertained and noted. Successive batches of the fresh juice may after- ward be tempered with the same proportion of lime pre- viously used when it is certain that there is no variation in the quality of the juice. But much caution is here neces- sary to avoid error, for the degree of acidity is not constant even in the juices of canes taken from the same field, and the means of readily detecting these differences must be at hand, and frequently used. The sense of taste may in- deed acquire an acuteness in detecting minute differences of quality in the juice, scarcely inferior to that of chemical reagents ; bat until it has acquired this delicacy, we must rely upon the test paper alone. CHAPTER XVI. PROCESS OP MANUrACTUEE (CONTINUED). ' Second Stage of the Process — Characteristics of a Refined Syrup — Mode of Refining the Syrup — Manner of using the Filtering Drawer — Third Stage — Concentration of the Syrup — The Finish- ing Pan — Thermometer — The Striliing Point as determined by the Temperature — Other Tests of Density — The Finger Test — Indications at Successive Stages of Concentration — False Indica- tions exhibited by Impure Syrups — Precautions necessary in Barreling Syrups. The entrance of the clarified juice into division B, marljs the commencement of the second stage of the process during which the syrup is further refined. In B, the evaporation progresses with great rapidity. The boiling juice at the back part of this pan should uniformly indicate a density of about 15° Beaume's saccharometer. An adjustable gate or register R both regulates the con- centration to the required degree in this compartment, and the discharge of the syrup into B, — a shallow cistern or filtering drawer containing animal charcoal, prepared ex- pressly for this use. Through this filter the hot syrap passes into C, — the third pan of the series. The effect of this filtration is the removal of any remaining impurities which hinder crystallization, and of the extractive matter not previously separated, which imparts to unrefined sorghum syrup its peculiar flavor. A syrup prepared by this mode is strictly a refined syrup of the first quality ; (105) 106 PEOCESB OP MANOPACTURE. m at this stage it is perfectly clear, and of the finest color and flavor. The only attention specially required daring this part of the operation is to properly regulate the flow of syrup iato the filter E by means of the adjustable gate. It should not be allowed to pass so rapidly as to drain too much the pan B, in which the depth of juice should be at least twice as great as in any other, or before the proper degree of density has been reached. Nor should it be unduly re- tarded. In either case the filtration will be imperfect The filter should be refilled with fresh or revivified bone- black before the beginning of each day's work. If reburnt bone-black is used, the dust should first be sifted out. Take a piece of thin flannel or canvas of an open texture, wet it, and spread it smoothly upon the slatted bottom of the filtering-box. Then fill in the bone-black gradually, packing it down tightly so as to leave no crevices. When it is filled to the proper level, draw a little of the coal from the central parts toward the sides so as to leave the surface slightly elevated at the sides. Cover with a cloth of the same kind as that which lines the bottom, and confine it closely at the edges by means of the wooden frame. Fill the empty space above the cloth with hot water, taking care not to disturb the surface of the bone-black. The stream of water, in pouring it, should be received upon a piece of board or tin plate resting on the cloth. Another mode of filling the filter is to fasten down the cloth on the bottom of the box, close the outlet, and pour in hot water until it is about half full. Then add the bone-black. When this mode is adopted, the bottom cloth must be confiued very securely at the sides, or the small fragments of the charcoal will find their way under it into the chamber below. It is convenient to have a movable stand of the height CONCENTRATION IN THE FINISHING PAN. lOT of the pan C set close alongside of it upon which to place the filtering-box while it is being filled, and from which it may be readily shifted to its proper position. The pan B should be so placed that the register R, at the back end of it may project its whole breadth over the filter and the for- ward end of C. The water should be retained upon the filter until the juice is ready to be let in; then remore the stopper and allow the water to pass out of the filter as the juice enters it. This and the water used in C andD to start with, must be passed out ahead of the juice. At the close of boiling in the evening before the exhausted filter is re- moved, it should be washed by pouring water upon it through the register-box until the liquid ceases to pass out sweet. Nothing now remains but to concentrate the syrup to the "striking point." But this must be so done as to preserve the qualities which characterize the syrup after filtration unimpaired to the close of the operation. The subsequent evaporation must be rapid, and the syrup must instantly be removed from the fire when the proper degree of concentration is reached. The pan C and the finishing pan D fully accomplish these ends. After being reduced by boiling in C, it is then passed through a gate into D at intervals, and not in a continuous stream as into the other divisions. The finishing pan is shallow, with a long beak or lip, and may easily be turned upon its axis by means of a lever or cord and pulley as at F, and successive batches of syrup, upon arriving at the proper point of density, are dumped into a shallow tank or cooler at the side of the range. When the pan D is tipped to discharge the con- centrated syrup, a damper is drawn which shuts off the flame until the pan is replaced and a fresh portion of syrup admitted. 108 PROCESS OF MANUFACTURE. A standard thermometer, the bulb of which is continually kept immersed in the boiling syrup, indicates its density, and it is by far the simplest and most unerring guide that the sugar boiler can use for this purpose. When sugar is to be produced, the strike should be made at about 232° Fahr. (111° Cent,), but for syrup 228° Fahr. (109° Cent.) is the proper point. By the careful use of this instrument successive batches of the syrup may be brought to the proper point of concentration with perfect uniformity. There are some other simple tests of the density of boiling syrups which experience has proved to be reliable, and with which every practical sugar boiler should be acquainted. They are convenient at all times in confirm- ing the indications of the thermometer, and in the case of the accidental breakage of the instrument a knowledge of them would be almost indispensable. The first or lowest degrees of concentration beyond the condition of a very thin syrup are indicated by the appear- ances that it presents in falling from the thin edge of a skimmer or dipper upon which it has been taken up and exposed to the air for a few moments by turning it about. First, it falls slowly in large drops ; then when the con- centration is farther advanced it separates from the edge of the skimmer in broad thin sheets. Beyond this point the finger test or proof by the touch is regarded as the most accurate. The following account of it is given by Prof R. S. McCulloh ("Scientific Investigations in rela- tion to Sugar and Hydrometers," p. 2Y2). " The proof by the touch is used, I believe, alike by the refiners and sugar makers of all nations, both in Europe and America, with very slight modifications. A small portion of the syrup is taken for trial between the index finger and the thumb; when it is cool, the finger is sepa- rated from contact with the thumb, and the syrup exam- THE FINGEE-TEST. 109 ined by placing it between the eye and the light. At dif- ferent degrees of concentration the following indications successively occur :* ' 1. Two drops separate, that on the thumb and below is the larger. 2. The drops become nearly equal, and do not separate until the fingers are drawn more widely apart. 3. By the separation of half an inch a thread is drawn out which finally breaks below ; the end of the thread becomes claviform' (club shaped), ' and it rises slowly toward the finger. 4. The same thing occurs at a greater distance ; the end of the thread is folded back, and gives to the thread the shape of a rib- bon or long strip, which rises more rapidly than before. 5. After a greater separation of the fingers the thread breaks, being very fine at the end, which turns aside and twists up like a corkscrew. It does not fold itself upon the rest of the thread as before, and the thread does not increase in volume except by the.cohesion which draws the particles toward, the finger, which is the only adhering point. A little more concentration prevents the thread from shrinking at all upon itself " In the Ucited Stales the manufacturers of sugar from cane juice use the proof by the touch, and consider syrup sufiBciently concentrated when the broken thread curls up in the form of a corkscrew, or the fifth of the degrees above described." It is essential, however, to the correctness of these indi- cations as well as of those of the thermometer, that the syrup be of a standard degree of purity, such as will uni- formly result from the Juice of ripe cane of good quality subjected to the mode of treatment already indicated. The presence of impurities such as are found in imperfectly defecated syrups, or an excess of either acid or lime, be- * See Diotionnaira de I'Induatrie, p. 407. Paris, 1841. 10 110 PE0CES8 OF MANUrACTURE. sides injuring the sugar, impair the uniformity of all such indications. I have found that the fifth degree of concen- tration, as marked by the proof by the touch above de- scribed, is attained in properly refined sorghum syrup when the boiling temperature rises to 235° Fah. (113° Ceot.). If syrup only is designed to be made it should be dis- charged from the tilting pan when a temperature of 228° Fah. (109° Cent.) is reached. Syrup should remain in the cooler until it has parted with most of its heat before it can be safely transferred to barrels. If it is poured into the barrels hot, the prolonged action of the heat retained in the dense mass will be sufficient to scorch the syrup. New barrels should be limed and fumigated with sulphur before they are intended to be used. Old molasses barrels are not fit to contain choice syrup until in addition to this treatmeflt they have first been either steamed or thoroughly soaked with hot water. (See directions for cleansing, Chap. XXX.) CHAPTER XVII. PHOCESS OP MANUFACTURE (CONTINUED). Crystallization — Treatment of the Syrup in the Crystallizlng-room — Crystallizing Vessels — Dutrone's Crystallizing Box — How Drainage may be secured and Crystallization promoted. At the close of the day's boiling, transfer the cooler to the crystallizing-room. Here two modes of treatment are to be pursued to suit the kind of product to be obtained. By the first mode, a fair, yellow sugar, of a quality equal to that of the ordinary brown sugars of commerce, is the result. By the second, white sugar, or any grade intervening be- tween it and the crude article, may be obtained. As a prerequisite to success by either method, the crys- tallizing and draining rooms should be uniformly heated to a temperature of not less than 80° F. (26 6° Cent). To secure this, a close room is needed, opening by a door into another apartment instead of by an outside door. The crystallizing vessels should be ranged along the sides and a stove placed in the center. Crystallization and drainage should be performed in the same vessels, and their form should be such as to conduce to both these ends. I. Crude sugar of a good quality and large grain will uniformly result from well defecated syrup of the proper density at a temperature of 80° to 90° F. by means of slow crystallization and natural drainage. The vessels (111) 112 PROCESS OF MANUFACTURE. should be shallow to admit of the speedy downward pas- sage of the molasses through the crystallized mass, and their bottoms should be inclined sufBciently to secure its rapid transmission to a common outlet. They should be of a uniform size, and in order to secure a large-grained crystallization, should be made moderately large. Vessels conforming to these requirements may be of various forms, but for convenience and general efficiency, I give the pref- erence to a form of vessel which the experience of nearly a century has not modified for the better. I refer to Dn- trone's Crystallizing Box, a description of which I give in his own words, as translated by McCulloh (Report, p. 286).* "Experience has proved to me that the quantity of matter which combines the greatest number of advantages in the crystallization of cane sugar, is fifteen or sixteen cubic feet, for which reason the dimensions given to the crystallizing vessels are five feet in length by three feet in breadth. The bottom is formed of two planes, inclined six inches, the intersection of which form a groove in the middle. In this groove are twelve or fifteen holes of an inch in diameter, to permit the syrup to flow out. The depth is nine inches at the sides and fifteen inches at the center. The vessels should be made of boards one inch thick, and lined with lead" (or better, coated heavily with iron paint). "Before lining it, the holes should be bored in * Precis sur la Canne, page 184. Paris, 1790. To Dutrone la Couture belongs the honor of oiiginating and introduc- ing many most valuable improvements in the art of sugar making; his work embodies the results of conscientious and laborious research, and although now out of print in its original form, it has been partially re- produced in th .' English works of G. R. Porter and others. In spite of the crudcness which marked the chemistry of his day, Dutrone has given us a work that yet merits the distinction of being "the most able treat- ise ever written on the culture and manufacture of sugar." CRYSTALLIZING VESSELS. 113 the groove, and bnrnt out with a hot iron from the inside, so as to form a small cavity surroanding the hole, in coose- qaence of which not a drop of syrup will remain after draiaing. . . . Sooh vessels combine every possible advautage ia crystalliziDg and purging with the requi- site strength. " The crystallizing vessels rest upon strips of wood two inches thick and three inches broad, which are fastened to and supported by upright posts eight or ten inches high, at the distance laterally of ten inches from the middle line. Troughs counecting with a cistern on a lower level receive the molasses as it drips from the sugar." These vessels, when filled to within 3 inches of the top, will hold about 75 gallons of syrup for granulation, weigh- ing nearly 1000 pounds, of which one-half, or 500 pounds, will be good dry sugar. The depth of the crystallizing mass in these boxes may sometimes be diminished to 3 inches at the sides where the bottom is most elevated, aud 9 inches in the center, when there is reason to apprehend any difSculty of drainage by reason of the presence of an undue amount of grape sugar, or otherwise. After the molasses has all drained out, this depth will be much di- minished, and the large surface of sugar exposed permits it to dry speedily. The number of these boxes that will be required will of course depend npoa the amount of work to be done, and the length of time that must elapse before they can be refilled and used again. Two weeks is as short a time as can be reckoned upon for the completion of the crystalliza- tion and drainage. It will be found that one of these ves- sels will be required for each 450 or 500 gallons of juice delivered by the mill during that period. Close the openings in the bottom of the box with long, smooth wooden plugs, abruptly pointed, which may be 10* 114 PROCESS OF MANUFACTURE. allowed to project through the holes into the inside of the box two or three inches. Range the boxes in order on the supporting rack, around the sides of the room, and over the drippiug troughs, which are so arranged as to convey the molasses into a painted wooden or tin gutter, and thence into a cistern. The dripping troughs may be simply short open conductors of the same materials. In twenty four hours after the thick syrup has been passed into the crystallizing box from the cooler, the for- mation of crystals of small size will generally have com- menced. They may then be seen along the edges of the yet liquid mass, but on the bottom of the box they will be found in greatest abundance, and may be detached and brought to the surface at the shallow sides of the box, by means of a knife blade or the wooden scraper, which should be always at hand. The last-named implement is simply a long paddle of ash or hickory wood, with a stout handle and thin blade. With this the fine crystals should be loosened from the bottom and sides, and stirred into the mass, so as to distribute them as equally as possible through it, that they may act as nuclei for the formation of larger crystals. Generally in twenty-four hours after this opera- tion, and often in less time, the crystallization will have per- vaded the entire mass. When this is found to be so, then gently withdraw the stoppers and permit the molasses to drain. The sugar will be dry in ten days or less thereafter. It may then be shoveled into boxes or barrels, and the crystallizing boxes refilled. CHAPTER XVIII. PROCESS OF MANUFACTURE (CONTINUED). Drainage — In what it consists — Mode of Worliing — Extent to wliicli the Production of the Higher Grades of Sugar may profit- ably be carried in Draining Vessels — Sugar Moulds — Descrip- tion of the Process of Natural Drainage and the Mode of pre- paring White Sugar — Reboiling and Crystallization — Summary of Conditions necessary to Success in Liquoring Sugars — Sep- aration of the Molasses by Mechanical Pressure and Other Means — The Centrifugal Drainer. Natural drainage does not remove all the molasses in contact with the crystals of sugar, and hence sugars pre- pared by that mode are always more or less impure. Mo- lasses is hygroscopic, or attracts moisture from the air ; hence the sugar becomes more or less moist and "heavy." The crystals are always in some degree colored, because of the molasses which coats them, and fills the interstices, and for the same reason they have not the pure sweet taste of white sugar. The purification of sugar is effected by simply washing the crystals with a liquid that is capable of expelling or taking the place of the molasses without dissolving the sugar. This liquid is syrup of greater parity than that which is to be expelled or washed out. It is poured over the top of the mass of impure sugar contained in a vessel which admits of drainage, and is carried down by the force (115) 116 PROCESS Of MANTJPAOTUEE. of gravity through the porous mass, displacing the molasses as it descends, and finally driving it out at the bottom. By continuous " liquoring," the term technically applied to this infiltration, the whole mass of sugar operated upon may be made perfectly white and chemically pure. Bat except in large and well equipped establishments itAvill be found neither necessa.ry nor most profitable to carry tbe art to this degree of perfection. The aim of the manufacturer should be the production of a series of graded sugars, cor- responding in color and quality to the successive strata observed in a loaf of sugar which has been subjected to the liquoring process, to the extent only of rendering the upper part of it white, while the inferior portions gradu- ally deepen in color from a light yellow to brown at the tip. The mode of doing this is comparatively simple, and is precisely the same as that now practiced oii the sugar estates of Cuba and elsewhere. "Well crystallized sorghum sugar requires for its purification no modification of this mode. The directions given below are adapted to opera- tions of any degree of magnitude, and may be followed with success by any one who has grown but a patch of cane, and treated it as already described. Provide a number of iron sugar moulds that will hold about 12 gallons each. Smaller moulds may be used, but the after-treatment of the sugar in these vessels requires more time than in those of the larger size, and the rapidity of the crystallization and smalluess of the grain of sugars formed in small moulds is an objection to their use. They should .have received two or three coats of iron paint and been thoroughly dried and hardened some time be- fore being used. In place of these, cooical vessels of a similar capacity of earthenware or wood may be substi- tuted for experimental purposes, but for ordinary use those of iron will be found the cheapest and best. For each DRAINAGE. 117 mould a pot of earthenware to contain the drippings of the sugar (molasses) must be provided. These pots should hold at least half as much as the moulds. Range the moulds upon the pots in rows around the walls of the crystallizing-room, and fill them in succession from the cooler. The same method of producing a uni- form crystallization as already described, by diffusing the crystals after they have begun to form on the surface and at the sides through the concentrated syrup by means of a long wooden spatula, should be resorted to afterward ; but this should not be done oftener than once or twice, or it will defeat its intended object, and cause the production of a mass of minute grains from which the molasses will not readily drain. If from any cause crystallization in mi- nute grains has been induced, the sugar should be kept in a warm place (90° to 100° F.), and natural drainage en- couraged as much as possible. When it has ceased, or nearly so, melt and reheat the sugar along with a very small quantity of water to the striking point, and recrystal- lize under proper conditions. When the mass in the moulds has become solid, remove the plugs and allow the molasses to drain. If the drain- age is sluggish, thrust a large pointed wire or brad awl into the mass from below and withdraw it. This will break up any incrustation which may have formed at the bottom of the mould. After a period of from two to four days, the greater part of the molasses will have dripped out. Then the crust which has formed upon the surface of the sno-ar, and a portion of the granulated mass below it to the depth of about an inch, are to be scraped off by means of an instrument called a "bottoming trowel," a trowel with a circular blade, leaving the surface of the sugar level or slightly hollowed in the center. These "green cuttings," as they are termed, are put into a pan and kneaded with 118 PROCESS OF MANUFACTURE. cold water to the consistency of a thin paste, in which a large part of the sugar remains undissolved. The sugar in this half liqaid form is then to be replaced upon the sur- face of the mass in the moulds. Immediately the liquid part of the mixture, which is a saturated solution of sugar, begins to penetrate the mass below, displacing the molasses, and carrying it downward. At a particular point in the cone, at which the force of gravity is balanced by the cap- illary attraction, this downward movement will cease, and the remainder of the sugar below that point will still be charged with molasses. But the syrup derived from the mixture of water with the "green cuttings" was not pure, so that the sugar in the upper part of the mould, although much improved in quality by the application, is not white. To render it so, and to drive out the remainder of the mo- lasses from the lower part, the process must be repeated, but this time with a solution of pure sugar. This pure liquor could not have been used successfully at the first, because the molasses to be displaced differed from it too much in density for displacement to occur. Prepare a liquor by dissolving so much white sugar in pure water, that when boiling it will mark 32° Beaume's saccharometer, or 36^° Beaume at the temperature of 60° P. About two quarts of this liquor, cold, should now be poured upon the surface of the sugar in the nioulda treated as ^ove described. This liquoring should be repeated two or three times at the option of the operator, or according to the purity of the sugar, and at intervals of from 12 to 24 hours, varying with the rapidity with which the liquor penetrates the mass of sugar and disap- pears from the surface. The drippings of the sugar, after the second .application of the "white liquor," should not be allowed to commingle with the molasses which has pre- viously drained off, but be carefully collected and set apart "LIQUORING." 119 to be diluted to 18° Beaume, passed through the boneblack filter, concentrated, and reerystallized. If the concentrated syrup with which one of these sugar moulds was originally filled, weighed 140 to 150 pounds, 70 to 80 pounds of sugar will remain, which, treated in the way described, will consist almost entirely of two grades of sugar, the upper portion, the base of the cone, will be white, and the lower part a very light yellow, with a brown tip. If a less quantity of the liquor is used than that recommended, a smaller proportion of white sugar and a larger proportion of yellow and brown sugar will be the result. If, on the other hand, the liquor is applied until the loaf is neat, or the liquor comes through of its original color, the whole mass of the sugar will be white, but for reasons already mentioned, it will not generally be desirable to extend l^e operation so far. After the dripping has ceased, and the sugar has been turned out of the moulds, the different grades of sugar should be separated by cutting up the loaf with a heavy knife. The assorted pieces are then to be dried during a day or two upon shelves of a room artificially heated to 110°-120° F., and then crushed and packed away in boxes or barrels with the grade mark on each. The syrup of drainage, or molasses, may be reconcen- trated, and if but little glucose originally was contained in the jnace, it will generally yield about one-third of its weight in the form of crystallized sugar, but the molasses will be much inferior to the first product, and drainage will be more difficult. As long as the market price of syrup compares as favorably with that of sugar as it does at present, it will be found most profitable to crystallize but once, and rework only the drippings of the last liquorings. It should be remembered that the successive liquorings are not a source of much loss in well-regulated establish- 120 PEOCESS OE MANUFACTTJKE. ments, since nearly all the sugar in the last drippings is capable of being recrystallized and purified, or reworked to form a new liquor of a somewhat lower grade. But there is a loss, nevertheless, in the degradation of the white sugar to form a liquor that unites to a greater or less ex- tent with the impurities and coloring matter which it does not wholly displace. This may be avoided. A white liquor may be prepared from ripe juice of a known degree of purity, by carefully clarifying it and passing it twice through the filter, if necessary, to remove all coloring mat- ter, and finally concentrating it to 32° Beaume, boiling ■ hot. In whatever way prepared, a sufficient quantity of the liquor should be provided beforehand, and kept in a perfectly purified vessel in a cool place. Iron moulds are to be preferred to those of wood or earthenware. They are sufficiently strong, little liable to injury, convenient to handle, and easily emptied by expos- ing them for a few moments to a heat sufficient to liquefy the crystals immediately in contact with their inner surface and then inverting them. A summary of the conditions essential to success in the operation of liquoring sugar, is thus given by M. Payeu, a distinguished sugar manufacturer and chemist. " 1st. That the liquor be sufficiently charged with crys- tallizable sugar to dissolve little or none in filtering. " 2d. That the density of the liquor be nearly the same or very little less than that of the displaced syrup, for if too dense it will flow badly; too dilute it would escape without removing the syrnp or molasses adhering to the crystals. To attain this condition, the sugars used for preparing the liquor must be more impure in proportion as those to be liquored are so likewise ; for saturated syrups are more dense and viscid when they contain uncrystalHzable sugar. OTHER MODES OF DEAINING, 121 "3d. That the crystallization in the moulds be regular and not too compact; and to this end, that it commence and terminate in the same vessel. "4th. That the temperature of the room in which the liquori}ig is performed should not vary much, and be at least 10° F."* The practice of forcing out the molasses by mechanical pressure has commonly been resorted to by sorghum man- ufacturers, but the necessity of adopting this mode of drainage is an evidence of an inferior crystallization, result- ing from unripeness of the cane, imperfect defecation, injury by heat, or other like causes. Natural drainage will not take place with facility in such cases, and the choice of the operator lies between the production of a dark, clammy and inferior sugar by the application of the press, or the melting and reboiling of the refractory mass to form syrup. In such cases, a better quality of sugar can be made on a small scale by intimately mixing with the plastic mass of sugar and molasses, after pressure has been applied, a small quantity of water, which dissolves the molasses and coloring matter more readily than the crystals of sugar. Pressure is then quickly applied a second time, and the liquid part being thinner and less viscid than before, is more readily driven out. The objections to this mode of drying the sugar are that a single repetition of this process is seldom sufficient to produce a fair sugar from a mass which would not naturally drain, that in the successive washings and pressings a great quantity of the sugar is dissolved, and is rendered comparatively worthless by being mixed with the very impure molasses from which it cannot again be recovered, and that this operation involves a great * Quoted by McCuUoh, Report, p. 290, from "Cours de Chimie Ele- mentaire et I'-dustrielle, par M. Payen." 11 122 PROCESS OF MANUFACTTIRE. waste of time as well as of materials, and is very injurious to the grain of the sugar. In all cases when the choice must be between drainage by pressure and the reduction of the sugar to the condition of syrup, the former alterna- tive should generally be accepted; but I would recommend that the sugar after the first pressure be washed but once, with a small quantity of cold water, and then pressed a second time. If it be then melted and recrystallized in the proper manner, a fine quality of sugar, of large, sharp grain, will be the result. This sugar will drain well either in moulds or the crystallizing boxes. This plan is not wasteful, for the drippings form a good quality of syrup. There are other means of drainage that might be resorted to more or less successfully, such as driving the molasses through the crystallized mass by atmospheric pressure to- ward a vacuum formed by the action of an air pump, as is the practice in some refineries. But of all artificial methods of drainage, by far the most rapid and thorough is that which is accomplished by the use of the centrifugal mill. This simple machine has been adopted very generally of late years in sugar manufacture, both in tropical countries, and in France and Germany. It is one of a number of im- provements by means of which, in Cuba and Java, the sugar cane is now made to yield almost twice the quantity of sugar which was obtained from an equal weight of the canes half a century ago. It seems to be admirably adap- ted to meet the wants of the sugar manufacturer at the North. Although the method by natural drainage is not likely to be supplanted by any other, when it is conducted under favorable circumstances — that is, when a uniform and suflBciently high temperature can be maintained in the draia- ing-room, and a good crystallization has been secured — it is extremely convenient as well as economical for the oper- ator to have at hand a machine by which obstacles to nat- CENTRIFUGAL DRAINING MACHINE. 123 Ural drainage, whenever exhibited, may be readily over- come. The uneqnaled celerity with which it does its worlc will enable the Northern sugar grower to achieve a result which heretofore could not be secured even in working up the comparatively pure sap of the maple, and which is now attained only in Southern sugar countries, namely, the pro- duction of perfectly dry, crystallized sugar in the evening, from cane which in the morning of the same day was standing in the field 1 The essential parts of the centrifugal drainer are a cyl- indrical vessel or metallic drum, with a tight bottom, and closed -at the top by a movable cap, the cylinder being fixed in an upright position upon a frame, and within it a smaller cylinder of wire gauze, or sheet metal pierced with small holes, supported upon a vertical shaft, which is made to re- volve at a high speed, the motive power being communi- cated by a belt. The mass of sugar to be drained mnst be warmed to about blood heat, and placed within the inner cylinder, which is then made to revolve. The half fluid mass becomes distributed over the inner face of the cylinder, and the ve- locity is rapidly increased. The sugar is retained within the revolving screen, but the molasses is thrown out by cen- trifugal force, and caught in the outer case, from which it is conveyed away by a spout. In the course of two or three minutes the motion may be checked, and the inner cylinder may then be lifted up, the dry sugar turned out of it, another charge inserted, and the process resumed. CHAPTER XIX. SUGAR MILLS. Compoaition of Sorghum Cane Juice — Extraction of the Juice — Su- gar Mills — Percentage of Juice ordinarily extracted by Mills — Loss froni Inefficiency of Mills — Obstacles to the complete Re- moval of the Juice — To what extent they may be OTeroome — The Common Three Roll Mills at the South — Mean Results of Exper- iments with these Mills in Guadaloupe — British West Indies — Cuba, Java, and Louisiana — Importance of further Improvements — Necessity of Grinding at alow rale of Speed — How the Advan- tages of the Process of Maceration may be successfully combined with those derived from the use of the Mill — Mills with Four Rolls provided with a Pipe for the Injection of Jets of Steam into the Begassa — Value of these Improvements. If a ripe stalk of Chinese cane, the juice of which clar- ified is of the density of 9° Beaume, be thoroughly dried by artificial means, in air the temperature of which does not exceed 212 Far. (100° Cent.) it will be reduced to about 27 percent, of its original weight, the remainder — "73 per cent., or nearly three-fourths, being water which has passed off by evaporation. In the dried stem there is left the saccharine matter constituting about 145 per cent, of its original weight, and 12-5 percent, of woody fiber-starch, albumen, salts, etc. The fresh, undried stalk, therefore, contained 87 5 per cent, of its weight of saccharine juice. The "ordinary crushing mills extract but 50 to 60 percent. ri24) LOSS FROM INEFFICIENCY OF MILLS. 125 of tbe whole weight of the stalk ; most of the lighter class of mills do not average more than 50 per cent. A perfect machine would produce 87"5 pounds of juice from each 100 pounds of stalk. If in practice but 50 pounds are ob- tained, 37 '5 pounds, or more than 43 per cent, of the whole amount of juice originally contained in the stalk, is still retained in the trash. We have thus revealed the astonishing fact that about three-sevenths of the whole product is utterly wasted at the outset, in consequence of the imperfect means ordinarily used in extracting the juice. Such a loss is enough to ship- wreck any industrial pursuit of common magnitude, and it is a proof of the importance which sugar growirsg at the North is destined to assume, and of the firmness of the basis upon which it rests, that it has proved highly profitable under such circumstances. Land which has heretofore yielded the very moderate amount of 140 gallons of crude syrup per acre, worth in that condition 60 cents per gallon, or $84, would yield if the means of extracting the juice were perfect, 200 gallons per acre, worth $120; and land which, with better cultiva- tion, has ordinarily yielded 200 gallons per acre, would yield 350 gallons. These facts demand more attention from planters than they have hitherto received. Here, in the case last men- tioned, is a loss of 150 gallons of syrup per acre, the greater part of which is recklessly, and in many cases, ignorantly incurred. It is true that a part of this waste is inevitable. In the manufacture of sugar from the Southern cane, in which the most highly improved and powerful crushing mills have been used, the loss from this source is still very great, and in many cases much greater than need be, on account of slovenly practice, yet it is still far less than is commonly 11* 126 SUaAR MILLS. incurred at the North in the sorghum manufacture. Sor- ghum and the Southern cane are composed of about the same relative proportions of juice and woody fiber; and although the obstacles to the complete removal of the juice are greater in the case of the latter, on account of the joints being more numerous, and the stem generally of closer and more unyielding texture, yet they are the same in kind, and we may adopt here without hesitancy suggestions, which in this instance, experience with cane mills at the South has dictated, and proved to be valuable. The importance of improving to the highest possible degree the machinery for extracting the juice, forced itself upon the attention of the planters as soon as the composi- tion of the cane became accuratelyvknown. Within the last half century nothing has been omitted in the constrL'.ction of mills of the common form with three rolls, that ijTould in any degree add to their power and efBcieney. The re- sults arrived at by careful trial in a great number of in- stances, with these mills in different countries, have beea pretty uniform. Some of the most valuable^and trust- worthy statements, selected from different sources, are given below. In the Island of Guadaloupe the results of 44 trials per- formed with IT water mills, 15 wind mills, 1 mills with hor- izontal cylinders, and 5 steam mills, was 61-8 per cent, of juice by hydraulic mills. 61-2 " " " those with horizontal rolls. " steam mills. " water and wind mills. " mills with vertical cylinders. " mills of animal power. " wind mills which are still employed to some extent in Guadaloupe. 59-3 per cent, maybe assumed as the yield furnished by 60-9 59-3 59-2 58-2 56-4 EXPERIMENTS IN LOUISIANA. 12T the kind of mills which are the most nnmerons. The loss amounts to about one-third of the whole quantity of juice contained in the cane.* In the British West Indies, the loss by reason of the in- efficiency of mills, is stated to be at least one-third of the juice. "Of the 90 per cent, of sweet juice which the cane contains, only 50 to 60 per cent, are usually expressed. "f In Cuba and Java the yield was no greater, previous to the introduction of certain recent improvements. In Louisiana, "experiments made upon the plantation of Mr. Y. B. Marmillion, 25th November, 1842, with a first- rate horizontal mill, moved by a steam engine of 16-horse power,"! gave the following results: Juice. Density of Juice. "Variety. Expressed. Begaasa. (Beaume.) Ribbon Cane 63-1 36 9 8-25° Violet Cane 63-0 370 8-5° Gray Cane 64-0 36-0 7-75° Otaheiie Cane 65-8 34-2 8-5 Creole Cane 67-8 32-3 9-0 M. Avequin, who makes the foregoing statement, adds : "I could mention other experiments made for the same purpose in other mills, which experiments have clearly de- monstrated that a large number of planters in Louisiana obtain from 63 to 64 per cent, of juice." The following is an extract from an article written by J. P. Benjamin, Esq., of Louisiana, and published in De Bow's Review for January, 1848 :§ " I have taken some pains to ascertain during the present season the yield of juice from our mills of ordinary con- » Peligot, Eeport, etc. Paris, 1842. I Johnston, Chemistry of Common Life, vol. i. p. 209. Appleton, N. T. J De Bow's Review, vol. vL, No. 1, p. 31. J MoCulIoh's Report, p. 607-8. 128 SUGAR MILLS. BtrQCtion. I found the yield from the three-roller mills of average size and van at a speed of S^ revolutions per minute, to be 61 per cent. ; whilst from another of very- large size, of which the rollers were 5^ feet in length, and 28 inches in diameter, and which was run at a speed of only 2^ revolutions per minute, the yield was 66 per cent., the begassa being delivered from the latter almost pulver- ized and apparently dry. These results are undoubtedly much more satisfactory than would have been afforded some years ago ; still, they show that after all the care bestowed in raising our crops, from one-fourth to one-third of our produce is absolutely lost. And if we take what I believe to be a fair average of the yield of juice in sugars, that is, if we assume that one-tenth of the weight of the juice is the product in crystallized sugar, we find that we obtain only 6|- per cent, of the weight of the cane in sugar, whereas chemical analysis shows that it contains 18 per cent.'' Is there then no means by which the yield of juice may be increased ? Mr. Benjamin's experiment indicates a de- cided increase by diminishing the speed of the rolls. On this subject Prof. R. S. McCulloh makes the following val- uable observations,* which are as applicable to sorghum manufacturers at the North, as to those for whose benefit they were originally intended : "During the grinding season, when the chief object of many seems to be rather to hurry through with the crop as rapidly as possible than to obtain the largest quantity of sugar of good quality, the grinding of the cane is often performed in a very improper and ineffectual manner. * * * * * _A. general spirit of haste and hurry pervades the whole force of the plantation, and in consequence much is done without system. In grinding, to obtain the proper * MoCuUoh's Report, p. 204. HOW TO INCREASE THE YIELD OF JUICE. 129 yield, the most perfect system should be strictly observed. The mill should not only be regulated to a uniform speed, but should be of sufficient power to work off the entire crop without requiring the speed to exceed the rate which will permit the juice to flow off readily before the begassa is liberated from the mill, so that this begassa may not in expanding act as a sponge, to absorb a large proportion of the expressed juice. The importance of grinding at a low speed is rendered evident by the following mean results of numerous experiments made by the Marquis de St. Croix, a very intelligent planter of the Island of Martinique, and which I extract from a work* he has written on the manu- facture of sugar. " With the same mill, and its rollers set in the same way, the juice obtained constituted 45 per cent, of the weight of the canes ground when the rollers made six revolutions in a minute, and TO per cent, when the velocity was only two and a half revolutions per minute; a difference of 25 per cent. "As the surface developed is for an equal number of rev- olutions proportional to the diameters of the rollers, M. de St. Croix asserts that a good result will be obtained by rollers which develop a surface of four or five yards in length per minute, so that a roller of two feet diameter should make from two to two and a half revolutions per minute. "And if it be objected that this velocity is insufficient to express the requisite amount of juice in a given time, then the length of the rollers should be increased, and, if necessary, also the power of the engine. It is the quantity of juice required per hour, under circumstances the most favorable for perfect extraction thereof, which should deter- mine the power of the engine to be employed." * Fabiioation Aotuelle de Suore aux Colonies. Paris, 1843. 130 SUGAR MILLS. It has been proved that by the process of maceration, the saccharine matter may be extracted almost entirely from the canes. This process consists in cutting the canes into thin transverse slices, placing them in a succession of boxes with perforated bottoms, one over the other, and pouring into the highest of the series hot water, which as it descends gradually through each removes the greater part of the sugar. But this mode of working is tedious, the hard coating of the canes soon blunts the edges of the circular knives used in slicing, and the cost of evaporation is much increased. Although impracticable for these rea- sons, it is suggestive of an improvement in the ordinary mode of expression, which has already been put in practice in some sugar countries with very gratifying results. One mode which suggests itself is to steep the begassa in hot water, and press a second time. This Is liable, however, to several weighty objections, such as the additional labor and time to be expended in rehandling the crushed cane, and in passing it a second time through the mill, the liability of the very dilute saccharine solution to fermentation and the greatly increased cost of evaporation. The efficiency of the mill may be increased by increasing the number of the rollers. When mills with five rollers were used, arranged three below and two above, a yield of '10 per cent, of juice was the result, but the very consider- able increase of motive power required, prevented them from coming into general use. But mills with four rolls, placed in pairs one directly above the other, with little if any increase of motive power above that which is required for an ordinary three-roller mill, produce TO to 75 per cent, of juice at one operation. Such mills have been used in Louisiana, yielding the very best results. If to a mill of this form be added the improvement originally proposed by M. Payen^ the distinguished sugar IMPROVEMENTS SUGGESTED. 131 manufacturer and chemist, which is certainly practicable and valuable, it would, I think, leave nothing to be desired in the crushing apparatus. This improvement consists in introducing between the feed and discharge rolls of the mill, or above them, " a pipe placed longitudinally, pierced with numerous small orifices to permit jets of steam to issue, which would be absorbed by the begassa, and acting by dis- placement, allow the juice to be expressed, which is firmly held by capillary forces in the spongy tissue of the begassa ; the steam pipe being supplied from the boiler of the engine, and the mill inclosed in a case of sheet-iron to prevent loss of steam." The softer texture of sorghum cane warrants the state- ment that at least '15 per cent, of the weight of the stalk could be extracted by such means, without loss of time or any considerable increase of expense. It cannot be doubted that a mill so constructed, and pos- sessed of such advantages, would, if brought into general use, add one-fourth to the annual production of sorghum in the United States. CHAPTER XX. CHEMICAL ACTION OP SUBSTANCES USED IN DEFECATION. Chemical Influence of Lime upon Sorghum Juice — Defecation by Tannic Acid and Albumen — Upon what the Peculiar Action of these Substances, so combined, depends — Conditions favorable to the Use of this Method — Another Method of Defecation — The Action of the Chemical Compound used — The Composition de- scribed and the Advantages to be derived from its Use. Pure quick-lime may be used preferably to soda, potash, or other bases, not only to saturate the free acid in sorghum juice, but, in this process, its employment in the mode al- ready prescribed is indispensable for other purposes, no less important. Its action may be briefly stated as follows : 1st. It destroys acidity. Fresh sorghum juice always contains a variable proportion of free acid or acidulous salts, which should always first be saturated or neutralized : the deleterious effects of this acid are : 1. It communicates its peculiar harsh taste, resembling that of unripe fruit, to the syrup. 2. It prevents the separation by heat of the albumen, another substance dissolved in the juice most inimical to the constitution of the sugar, and a most effi- cient promoter of subsequent fermentation in the syrup. The albumen is held in solution in hot syrup by the acid, but lime, by neutralizing the acid, causes It to coagulate, and it rises and is removed with the scum. 3. This acid has a peculiarly unfavorable influence upon the crys- tallization of the sugar (indepeudent of its effect in pre- (132) CHEMICAL ACTION OF LIME. 133 4 venting the coagulation of the albuminous matter) in caus- ing the crystals to be small, ill defined, and difficult of drainage, and although it is not certain that it causes di- rectly the conversion of cane into uncrystallizable sugar during evaporation, as some have supposed, it is other- wise sufficiently obnoxious, and lime, by saturating it, rea- ders it comparatively harmless. . 2d. Lime in excess converts grape sugar in cane juice into glucic acid, glucate of lime, and finally molassate of lime, a peculiar dark-colored soluble substance, uncrystalli- zable, and without sweetness. In making sugar, this trans- formation is not- to be dreaded, inasmuch as the molassate of lime in solution is much more liquid than the dissolved grape sugar from which it was formed, and facilitates drainage by rendering the molasses less viscid than a solu- tion of grape sugar. 3d. Upon cane sugar the action of an excess of lime is much less energetic. Four parts of sugar by weight unite with one of lime, forming sugar lime, orsaccharate of lime, a soluble substance, which becomes coagulable by heat and passes into the scum. But unless the excess of lime used be very great, the quantity of sugar lime formed will be very small, and in a heated solution containing both cane and grape sugar, the lime does not attack both, but decom- poses the grape sugar, leaving the cane sugar uninjured. 4th. During evaporation, the decomposition of a small quantity of neutral salts of ammonia and potash present in the juice is effected by lime, which has a stronger affinity for the acids than those bases, the ammonia being given off in the steam, and the potash remaining in the solution. The potash, if in considerable quantity, would have a tend- ency to render the sugar deliquescent, but as the propor- tion of potash thus liberated is very small, the influence which it exerts is inappreciable, or reduced to nothing, if, as 12 134 CHEMICAL AGENTS IN DEFECATION. Scoflfern asserts, it assists in the conversion of a portion of grape sugar into glucate and molassate of potash, which, like the product of the decomposition of grape sugar by lime, is to be preferred to a solution of grape sugar itself, being less viscid. The decomposition of organized sub. stances containing nitrogen also, is inferred to take place during the evaporation. After complete neutralization of tlie acid by the use of lime, the juice must be defecated or deprived of a number of substances which, if allowed to remain, would totally prevent the crystallization of the sugar, besides being pro- ductive of other injurious effects. I here recommend two methods for common use, giving the preference to that first mentioned only when its employment is indicated by certain favorable conditions described in Ch. XXX. It effects the separation of a very large amount of impurities, and particu- larly those which are the chief obstacles to crystallization. DEFECATION BY TANNIC ACID AND ALBUMEN. The peculiar advantage derived from the use of these substances consists in the removal of all glutinous, albu- minous, mucous, or gummy substances, together with all feculancies and other matters mechanically suspended in the juice, at the same instant, after heat has been applied, and they are firmly incorporated with the scum, which is not again permitted to remain in contact with the clarified juice. In the method of Wray, described in a subsequent page, one of these agents, tannic acid, is used ; but in that case it is necessary to add a second dose of lime ; the tannic compounds are suspended in the liquid, and are separable only by repeated filtrations, and much time is lost and much trouble incurred before the juice can be prepared for evap- oration. Besides, the clarification is by no means as per- SECOND MODE OF DEFECATION. 135 feet as when albumen is employed. Defecation is accom- plished by albumeu and tanuin without loss of time. Each of these agents possesses in a pre-eminent degree those qualities in which the other is deficient. The tannic acid unites with and renders insoluble all that most pernicious class of substances, gluten, mucilage, etc., upon which albu- men has no chemical action, and the albumen employed in sufficient quantity not only envelops and carries to the sur- face, when coagulated, all feculancies and mechanical impu- rities in the liquid, but also all the suspended compounds of tannin, which by other means are so difficult to separate, and forms an insoluble compound separable in the same manner, with any excess of tannin which would otherwise remain dissolved. DEFECATION BY ALBUMEN, ALUiNUNA, AND TANNIN. This mode consists in the addition, to the cold juice, of alumina, united with a definite proportion of albumen and tannin. The tannin as well as the albumen dissolve readily in the juice, which should previously have been carefully neutralized. A preparation composed of a com- bination of these substances in the dry state, in the proper proportions, is most convenient. Its peculiar action upon the juice immediately follows upon the application of heat. A reaction takes place, and a new group of substances is instantly formed, all of which, upon the application of heat to the liquid, become insoluble. The alumina has a most powerful attraction for coloring matters, which it takes up and unites to itself in the insoluble form. Its use as a decolorizer has long been known. Formed from alum, its use as a mordant, in fixing colors, is as old as the art of dyeing, and it has been applied to a very limited extent also as a defecator in sugar manufacture from the 136 CHEMICAL AGENTS IN DEFECATION. cane of the tropics. But its employment on the planta- tions was attended with difiSculty, inasmuch as it was deemed necessary to heat the juice to the boiling point in a deep tank, and then to allow it a long period of rest be- fore the precipitation of the alumina and the impurities with which it was combined could fully take place. The loss of time in the heating of the juice, and in the slow precipitation, together with the difficulty of separating from the bulky sediment the portion of juice in immediate contact with it by any means that could conveniently be applied, were obstacles which were generally thought to outweigh the advantages derived from its use. While alumina is one of the most energetic decolor- izers known, not excepting even animal charcoal, it does not remove from caue juice by ordinary precipitation some impurities of another kind. These are feculancies very abundant in sorghum juice for which the alumina possesses little or no attraction — and which do not naturally separate by heat — glutinous and gummy matter are also present in considerable quantities. And if these are permitted to remain until the syrup becomes more dense by evaporation, they cannot afterward be entirely separated, and they im- pair the quality of the syrup not only by reason of the viscidity which they impart to it, and by the destruction of a portion of tiie sugar through the chemical changes which they produce when assisted by heat, but also by the precipitation upon the bottom of the pans of a peculiar gummy sediment which, adhering to them, forms, with earthy matters, the hard scale so common where the defecation has been imperfect. This differs from ordinary lime scale not only in its composition, but also in its liability to burn at once upon the bottom of the pan. For the removal of this class of impurities, at this stage of the evaportion, no means that I have employed can be ADVANTAGES OP THIS MODE. 131 compared to albumen, assisted by a very small but definite pro- portion of tannic acid. Albumen, in small quantity, is always present in sorghum juice, and by its coagulability at a tem- perature below the boiling point it assists considerably in its clarification, and is suggestive of the effects which it is capable of producing when added in sufficient quantity. But the quantity naturally incorporated with the other impurities above mentioned is too small to effect the re- moval of but a part of them, and this effect even is produced only when the juice has been previously neutralized, for it is not coagulable in juice containing an excess of acid. If we compare the results of defecation by means of alumina, albumen, and tannin separately, we find that each has a peculiar attraction for certain substances, and that neither used singly nor in any way combined in pairs, are they capable of accomplishing the work of the three com- bined in the proper proportions. They unite together, and with the substances that they are designed to remove from the juice, in the insoluble form, and all are carried away. Separately they would act in a different way. The alumina being an earthy substance, when used alone, carries down the coloring matters with which it unites and de- posits them as a sediment in a liquid at rest. The tannic and albuminous compounds, on the contrary, rise to the surface of the heated juice. Yet I find that when suitably combined, all three and the associated impurities rise to the surface — the superior buoyancy of the albumen, especi- ally, overcoming the tendency of the alumina to sink and bringing It up along with it. Each minute particle of the alumina is a center of attraction for the coloring matter in the fluid around it, which it seizes upon and forcibly retains. When the juice is admitted into the evaporating pan, the tannin and albumen are dissolved, and the alumina is suspended in the liquid. The juice becomes almost im- 12* 138 CHEMICAL AGENTS IN DEFECATION. mediately heated to the boiling point, and then the albumen and the tannin become visible in the compounds which they form — the former weaving through the liquid mass myriads of gossamer-like filaments, enveloping all the suspended substances in its folds, in which, as in a drag net, It sweeps them up to the surface, and immediately in the form of scum they are carried oyer into the receptacles provided at the end and sides of the pan — the juice, meanwhile, trans- parent as glass, being borne onward in the opposite direc- tion. Thus, at the same instant the natural impurities and all the associated defecating substances that, a moment before, were commingled in the juice, are separated from it in the insoluble form. This componnd seems to conform to all the conditions required of a defecator of the juice of sorghum. It may be afforded at a low cost — it is entirely free from any prop- erties injurious to health if by accident, or mismanagement, any of it should remain in the syrup. — and it is especially adapted to a system of rapid heating in a shallow pan, so constructed as to remove the scum from all subsequent contact with the syrup, as fast as formed, by a superficial current flowing in a direction opposite to that taken by the clarified jaice. It thus, with far better results, renders entirely needless any precipitating tanks, and the loss of time and labor attendant upon their use.* Pure neutral sulphate of alumina, followed by lime, may be used to decolorize the juice, with advantage, but time must be given for the precipitate to settle, which it does very slowly, — and in point of general efficiency it is very ^' In order to supply this substance to those "who may need it, of the requisite purity, and accurately compounded, arrangements have been made for its manufacture, at a price which will place it within common roach. SULPHATE OF ALUMINA. 139 far inferior to the defecating compound above mentioned. Alum has been used in the beet sugar manufacture, and has sometimes been highly commended, but its employ- ment should be entirely discarded. It leaves in the juice a solution of sulphate of potash, a salt which, in addition to imparting a bitter and offensive taste, also gives the property of deliquescence to the sugar. CHAPTER XXI. ANIMAL CARBON, OR BONEBLACK. Filtration — Animal Charcoal or Boneblack — Mode of preparing it, and the Condition in which it is employed in this Process — Properties of the Charcoal in this form — Mode of using it — Its Action — Use in removing the Extractive Matter and Harsh Flavor — Decolorizes — Promotes Crystallization — Removes any Excess of Lime, Tannin, etc., etc. — Separfites all Soluble Sub- stances mechanically suspended in the Liquid — Mode of restoring the Powers of the Charcoal when exh.austed — Dif- ferent Modes of Reburning — New Method of Revivification — Substitutes for it in Filtration. After defecation by the means indicated in tlie foregoing chapter, the cane juice is beautifully clear, and apparently free from all impurities. It is not entirely pure, however, for there still remains a little of a harsh vegetable flavor due to extractive matter, which is separable neither by the process of defecation, nor by the action of heat. The entire removal of this is the primary object sought in the peculiar filtration to which the syrup is now to be subjected. This done, it is evident that a syrup so prepared is a refined syrup of the first quality. It should be even supe- rior to the best refined syrups of the market, because a long and tedious series of operations, including dilutiou with water, clarification, filtration and reboiling, as prac- ticed by the refiner upon the crude article, is not only made unnecessary, but also the waste, and the injurious effects resulting thereby to both syrup and sugar, are avoided. (140) ACTION OP FILTERING MATERIAL. 141 The filter used in this proces differs from the boneblacls; filters of the ordinary form in its shallowness, the compara- tively small quantity of the charcoal used, the fineness of division of its particles, and in some of its chemical properties. Ordinary boneblack, as used by the sugar refiners, is prepared by subjecting clean beef-bones in iron retorts, or covered pots in a furnace, to a red heat for some hours. An imperfect combustion of the bones takes place, access of air is prevented, all volatile substances which are pro- duced are driven off, and a dull black substance remains behind retaining the original form of the bones, consisting of phosphate of lime associated with a little carbonate of lime, sulphuret or oxide of iron, andsilicatedcarburet of iron 90 parts, carbon ] parts. The charred bones are excluded from the air until cool, and then are broken up in a mill into small fragments, averaging 01 to 0'3 of an inch in diameter, and the finer particles are sifted out. This charcoal is exceedingly porous, and its superior decolor- izing power, as well as its chemical action, seems to depend upon the very great extent of surface presented by the carbon to the liquid with which it comes in contact. For the same reason the more finely divided its particles are the more effective it becomes. It is far more energetic in its action than most other forms of charcoal, besides pos- sessing other properties peculiar to itself. All these prop- erties, however, may be variously modified, by the mode in which it is prepared, and its particular form, to suit certain ends. The action of the filtering material used in this process embraces the following particulars: 1. It removes the extractive matter which imparts to sorghum syrup its peculiar harsh flavor, and which resists the action of heat and all other means that have been used to effect its separation. 142 ANIMAL CARBON, OR BONEBLACK. 2. It decolorizes. Althougli this, as has already been said, is not a primary object, the color of the previously clarified syrup being very fine, it is still further improved, and the syrup acquires a glassy brightness and purity of color not otherwise attainable. 3. It promotes crystallization in a high degree, and increases the quantity and improves the quality of the sugar. The ordinary boneblack is said to increase the crystallizing property of the juice of the tropical cane in a remarlsable degree, in some instances 18 to 20 per cent. Upon the juice of sorghum its influence, in this respect, is very decided. 4. It removes any small excess of lime which may have been added in saturating the free acid in the juice. This property of boneblack is practically of much value. To insure a perfect neutralization of the acid, and the conse- quent coagulation of the albumen, the" juice should be made to exhibit a faint alkaline reaction — or, in other words, a slight excess of lime should have been added. This the filter vrholly removes. So also it removes any excess of tannin or alumina that may inadvertently have been introduced. 5. Independent of the above-mentioned properties, it acts as a strainer of the most effective kind for arresting any insoluble substances mechanically suspended in the liquid, such as compounds of lime and fine particles of sand, more or less of vfhich are found in all unrefined syrups. As the intensity of the action of the carbon may be modified indefinitely according to the state of division to which it is reduced, the density and temperature of the syrup, and the nature and quantity of the impurities which the syrup contains, the boneblack must conform, when used as above, to a certain standard in quality and properties, and it must be used in the manner already described. HOW BONEBLACK IS MADE. 143 The boneblack should be reduced to fragments of con- siderably less than half the size of those of refiner's bone- black, varying between 005 and O'l of an inch. The depth of the stratum in the filter drawer need not exceed 6 to 8 inches; the density of the syrup should not exceed 15° to 18° Beaume's saccharometer,aiid it should always be passed through hot. The rapidity and perfection of the filtration is secured by the position of the filter immediately- over a boiling bed of syrup, where it is enveloped in an atmosphere of steam, by which contact with currents of cold air is prevented, and it is kept continually at a uniform degree of heat, receiving the boiling syrup from the pan above. This system of refining simultaneously with the evapora- tion is advantageous in several important particulars. It saves time; the syrup is passed directly from one compart- ment of the evaporator to the other through the filter. It effects more easily the separation of the imparities than if they had been suffered to remain and form new compounds at higher temperatures. The sugar also is then more readily crystallizable, is of better quality, and may be pro- duced in larger quantity than after reboiling at any subse- quent time. The bone-charcoal should be prepared from large and solid beef-bones, carefully burned, according to the usual method, as already described. It should be neither of an ashy-gray color, nor lustrous black as if glazed, but of a deep dull black, and destitute of both odor and taste. When it has been exposed to too high a heat, it becomes glossy and is partially fused, and when allowed too free access to the air while burning, or while being cooled, much of the carbon is consumed, and in either case it is com- paratively inefficient. When not exposed to the proper heat, for a sufficient length of time, a part of the substance of the 144 ANIMAL CARBON, OR BONEBLACK. boDes is not charred at all, and it proves ruinous to the syrup by communicating to it the peculiarly oifeusive flavor and odor of the animal oil and empyreumatic matter, vphich has not been driven off. This flavor and odor cannot be afterward removed from the syrup by any means known. lu burning boneblack a low red heat, prolonged for about six hours, in the ordinary covered iron pots, is productive of the best results, and no difficulty whatever need be appre- hended when the covers of the pots are luted with clay, or when pairs of pots are used fitting closely together, mouth to mouth, or when the bones are calcined in retorts. The powers of the boneblack become exhausted by use, and as has been mentioned, it is necessary to replenish the filter daily. But little loss of the material is thus incurred, however, for its energy may be restored by reburniiig, and this process of successive exhaustion and revivification may be repeated indefinitely, if the very fine particles or dust, amounting to but a small percentage of the whole mass, be sifted out each time after reburning, and enough of fresh carbon be added to supply its place. In order that its action may not be impaired, the boneblack should always be washed free from sugar before reburning it. (See Ch. XVI.) The revivification of the carbon is accomplished econom- ically on the large scale in different ways. It may be ex- posed to a red heat in cast-iron retorts of a conical shape, placed vertically over openings in a bed-plate in a furnace. Through these openings the boneblack is discharged, when red hot, by drawing a slide, and through similar apertures in the tops of the retorts, they are refilled. Or it may be placed in a cylinder, and steam, heated to '700° or 750° P., driven through it. It may also be reburnt in the iron pots above mentioned, with success. Large retorts are some- times made of fire-bricks, of the shape of a square hollow HOW TO REVIVIFY BONEBLAOK. 145 pillar, or right rectangular prism, closed at the top by a movable iron plate, and below by a double trap door, open- ing downward. Surrounding this retort is a furnace of brick work, of the same height as the retort, but wider below than above. (Pereira.) The revivification of the boneblack used in this process may perhaps most readily be accomplished by inclosing it in a cast-iron cylinder, placed horizontally in the floor of the evaporator furnace itself, jast beyond the grate bars. The cylinder may be revolved, so as to expose its contents equally to the heat, by means of projections at its ends, outside of the furnace walls, where also there are openings through which to fill and empty the retort. A method of restoring, or even of augmenting (as is asserted), the powers of animal charcoal has recently been discovered by Mr. Edward Beanes, of England, who intro- duced some improvements in sugar manufacture in the Island of Cuba. It consists* in treating the exhausted charcoal, when dry and hot, with dry hydrochloric acid gas, which it absorbs with astonishing avidity. Another portion of charcoal is then added to that which has received the acid gas, the combined gas remaining in the pores of the latter is taken up by the former, and the whole becomes neutral : chloride of calcium is formed, which is easily washed out, and the charcoal is then reburned in the usual way. The advantages of this method are said to consist chiefly in the removal of any lime that the charcoal may have taken up without attacking the phosphate, and in augmenting the decolorizing powers of the coal more than 100 per cent. The efficiency of this means has not yet been tested in this country. Freshly burned charcoal should be carefully excluded • Medlock, in London Chem. News — Soi. Amerioan, vol. xiii. p. 224. 13 146 ANIMAL CAKBON, OR BOJTEBLAOK. from the air until it has cooled, or it may be quenched while hot by sprinkling it with water, taking care to add no more than is necessary for that purpose. Thorough defecation, according to the method already prescribed, is a valuable auxiliary to the action of this filter, and these operations may be regarded as inseparable and indispensable in this process. Although many other forms of carbon might be proposed as substitutes for this preparation of boneblack, none of them have been found at all equal to it. for attaining the desired results CHAPTER XXII. THE ACTION OP HEAT. The Influence of Heat upon Caiiie Juice — Imperfect convection of Heat in deep masses of Syrup — How Heat is economized by this Method, and its Intensity regulated,, according to the Effect re- quired at each Stage of the Braporation — The Tilt Pan — Injuri- ous Effects of a Low but Prolonged Heat — Soubeiran's Experi- ments — Open-air boiling indispensable up to a certain point of Concentration — Payen's Experience — Evaporation by a Water- Bath or by Steam at 212° F. — Why injurious — Advantages de- rived from the use of a Vacuum Finishing Pan — Why it cannot come into general use. The application of heat to cane juice until its tempera- ture rises to the boiling point, is capable, unassisted by other agents, of effecting an imperfect clarification. This it does chiefly by effecting the coagulation of that portion of the albumen of the juice not held in solution by the acid, and by the separation along with this albumen of a great part of the leaf green (chlorophyll) and other substances mechanically suspended in the liquid. During the subsequent evaporation the temperature con- stantly rises, and when it reaches a certain point the heat causes the decomposition of some of the nitrogenous impu- rities not before separated. This action of the heat, how- ever, may be very much assisted by the chemical action of lime. At a much higher temperature the sugar itself is decomposed (burnt), and the application of a very strong (147) 148 THE ACTION OF HEAT. heat at the closing stage of the evaporation is capable of producing this disastrous result vpheii the great mass of the syrup is of a much lower temperature than that at which caramelization of the sugar occurs. The cause of this is to be found in the imperfect convection of the heat through the sluggish mass of half liquid syrup. It is not conveyed away as fast as it is received by that portion of the syrup which is directly in contact with the bottom of the pan. Hence the necessity of placing the finishing pan at that extremity of the evaporating range which is farthest re- moved from the furnace. The pan, too, should be shallow, in order that the evaporation may be rapid, and that the transmission of the heat through it may be as rapid as its absorption by the lower stratum of the liquid. It should be provided with a thermometer capable of indicating at any moment to the eye the temperature, and thence the density, and the pan^ should be so adjusted as readily to admit of the instant removal of its contents from exposure to the heat, and, with equal facility, of being emptied, re- placed and refilled. Such a finishing pan should secure the best results attainable by a system of open-air evapo- ration, and the form which most fully meets those require- ments in practice, and seems best adapted to common use, is that of the tilt pan. (D. See engraving.) It is merely a modification of the old French baficule, a vessel long in use among sugar manufacturers in Mauritius, Guadaloupe, and elsewhere. A prolonged heat is exceedingly injurious to a solution of sugar. The control of heat over the chemical affinities which determine the form and sensible properties of most substances, and especially of organic bodies which are isomeric, is well known. Sorghum juice contains a number of substances which are peculiarly unstable in their nature. DECOMPOSITION OF SUGAR BY A LOW HEAT. 149 Some of these are starch, dextrine (cane gum), grape sugar, and cane sugar. They seem to be mutually con- vertible in the growing plant, and by the action of heat upon the juice, assisted by merely the presence of an acid, are capable of being transformed, the one taking the form of tlie other in the order above named,— with the excep- tion of the conversion of grape into cane sugar, which no art can accomplish, although such a change takes place with facility in the growing plant. The occurrence of de- grading transformations, or such as follow in the reverse order of the substances named, such as that whereby cane sugar is made to take the form of grape sugar, or other inferior forms during evaporation, is common; indeed it may always be inferred to take place when the acid and impurities natural to the cane juice have not been neutral- ized or removed, although such change may not be immedi- ately perceptible, either to the eye or to the sense of taste. It is a great error to suppose that no such change is taking place unless the effects of the decomposing power of heat are visible to the eye. Heat, with the presence of an acid, will convert cane into uncrystallizable sugar, without any marked indications that such a destructive process is in progress. But a moderate heat alone, if prolonged, is capable of decomposing a pure solution of cane sugar. The experi- ments of Soubeiran proved this conclusively. He dissolved a given quantity of sugar in a given quantity of water, and applied heat to the solution for 36 hours. " The apparatus was so constructed, that the water given off by evaporation was continually returned to the original solution, by which contrivance the latter was always composed of the same quantity of sugar, or its derivatives, and the same quantity of water, as when the experiment commenced. Gradually 13* 150 THE ACTION OP HEAT. the solution acquired darkness of color, and at tbe end of 36 hours it had become black. The effects of long appli- cation of the heat were : 1. The disappearance of cane sugar. 2, The appearance of grape sugar or glucose. 3. The production of carbonaceous powder and acids." It is impossible, indeed, to prevent the formation of a small portion of darker colored liquid sugar (molasses) in a solution of white sugar, chemically pure, which has been heated to boiling, and afterward recrystallized. Claiming for the tilt pan no other merits than those which have recommended it in plantation use for the last hundred years, I here give place to some remarks by Prof McCul- loh, founded upon the experience of M. Payen, the emi- nent French chemist, in regard to open-air boiling and the employment of an evaporating vessel somewhat similar. "It seems to be a disputed point whether or not saccha- rine solutions and juices are injured in evaporation by exposure to the air. M. Payen, whose opinion and ex- perience are entitled to great credit, remarks that it is the more important to refute the belief that syrups are injured and rendered dark colored in evaporation by an elevated temperature, or by the action of the air aided by heat, be- cause these views have been sustained by eminent scientific men, and given rise to most ruinous speculations. In corroboration of his opinion that injury is done rather by long duration of heat, M. Payen adduces the facts that boiling for thirty or forty- five minutes, according to the old system, deepens the color, and renders a much larger quantity of sugar uncrystallizable than rapid concentration in six or eight minutes by means of a tilt or bascule pan; that slow evaporation, by steam, of large quantities of beet juice at a temperature below that of boiling water, far from producing a better result, gives very dark and per- OPEN-AIR EVAPORATION. 151 fectly uncrystallizable syrups ; that slow evaporation either hy an open fire or by a water-bath, gives equally bad results. As for exposure to the action of the air during concentration, M. Payen remarks that, far from considering it very prejudicial, the effect should be regarded as almost nothing ; for comparative experiments made in vacuo, in carbonic acid gas, in nitrogen and in atmospheric air, gave him like results for like temperatures and times of evaporation. "Again, it is considered as a fact fully established by the use of apparatus, similar to that described above in the manufacture of beet sugar, that saccharine juices do not sustain appreciable injury in concentration by exposure to the air; and for this we have the authority. of the most intelligent and experienced manufacturers and chemists."* The truth of the foregoing observations has been fully confirmed by six years' experience in the manufacture of sorghum syrup in the United States. Up to a certain point of concentration, no prejudicial influence whatever is occasioned by exposure to the air or to rapid boiling. But when a temperature of 220° F. is reached, the danger of decomposition of the sugar becomes very much in- creased, on account of the greater density of the syrup. Nor can this difficulty be fully obviated by any of the usual methods of evaporation at the ordinary pressure of the atmosphere, — for if the evaporation be conducted at a diminished temperature, as by the use of steam at 212° P., or in a vessel immersed in a water-bath — all the evil con- sequences of the prolonged action of heat will result, and the sugar will be much more injured than by the action of a strong heat at the close of the operation. » MoCuUoh's Report, Senate Doo. 60, p. 238. 152 THE ACTION OF HEAT. Happily, the problem of rapid evaporation at a low temperature has already been solved. The application of the principle, that rapid boiling and evaporation will take place at a low temperature under diminished atmospheric pressure, was a great stride in the progress of sugar manu- facture. And now the vacuum pan of Howard, or of others who have variously modified it, is used wherever skill and large capital are combined in the production of sugar from the tropical cane. In the manufacture of sugar from sorghum, wherever a steam engine is used to propel the crushing mill, a v&cuum finishing pan of the simplest form would unquestionably be better than any other : the steam furnishing the heat to the jacket of the boiler or to the coils within it, and the engine driving the air pump by which the exhaustion is maintained. By this means the syrup, previously boiled to the proper density in the open air, is reduced with wonderful rapidity to the proper de- gree of concentration, at a temperature not exceeding 1T0° F., the sugar which results after complete crystallization being not only somewhat more abundant, but also superior in fairness of color and sharpness of grain to that obtained by the use of an open-air iinishing pan. At the same time the molasses is reduced in quantity, and what is more im- portant, it is of so much better quality as to furnish, after reboiling by the same means, a second crop of crystals but little inferior to the first. These advantages will no doubt secure the adoption of the vacuum finishing pan in all sugar works wherein capital is largely invested, but its expensiveness will preclude its general use. When a vacuum pan is employed, the syrup should pass through the same process in the evaporating range as before mentioned, only it should not be retained so long in the last two pans of the series, but should pass APPARATUS ORDINARILY REQUIRED. 153 from tbe tilt pan to the reservoir supplying the vacaum pan when the boflirg heat rises to about 220° F. In large operations where it is desirable to increase the evaporative capacity of the range without unduly increas- ing its length, it may be divided conveniently into two, placed upon separate parallel flaes opening into the same smoke stack, the pan comprising the first and second divi- sions, A and B being placed upon fnrnace walls sufficiently elevated above those supporting the pans C and D, to permit the syrnp to flow into the head of C from the filtering box. Tiie length of each half of the divided range may be increased to at least 24 feet, by increasing the length of all the divisions except A. The expensive vacuum finishing pan, although the best for use in large sugar factories, is not equally well adapted to the sphere of operations within which sorghum sugar production will ordinarily be conducted. For working up a crop of less than T5 acres of cane, undertaken by ordinary farm hands, no better apparatus is needed than the double evaporating range above described. Upon it a golden syrup, unexcelled either in color or flavor by the best products of the refineries, ihay be made with but little expenditure of money, time, or labor, and as much sugar as will be sufficient to satisfy any reasonable expectation, equal in all respects, either for sale or for domestic purposes, to the article which during the past fifty years has been most in demand for common use. If the intelligent farmer, at a season of comparative leisure, expends in the produc- tion of a given amount of sugar proportionally more time and care than the large manufacturer, he needs to spend but little money in the purchase and repair of costly ap- paratus, which can be used only a part of the year. Within his limited sphere of operations, growing and manufactur- 154 THE ACTION OP HEAT. ing fair yellow sugar upon his own farm, and utilizing all waste products, he can successfully compete with the large manufacturer. Waste of fuel is one of the evils attendant upon the system of evaporation in short pans heretofore much used. In districts where wood and coal are scarce, the cost of fuel is often more than 50 per cent, of the current expenses. Experiment has proved that the expense of fuel, to supply the long evaporating ranges here recommended, is reduced to one-half of that which is ordinarily incurred. CHAPTER XXIII. OTHER METHODS. Description of various Methods of Manufacture lieretofore used or recommended — The Method of Wray described — Its Merits and Disadvantages — Its Impraoticahility — Melsen's Method — Specifications — Its Advantages dependent upon the presumption that Sorghum and Tropical Cane Juice are identical, which is untrue— Further Reasons why Bisulphite of Lime, as a De- fecator of Sorghum Juice, is of no Peculiar Value. Having in the preceding chapters given the details of a system of sugar manufacture from sorghum, which has been uniformly successful in my own hands, and which I have reason to believe will prove equally so in common use, and in which all the main practical difficulties that have hitherto stood in the way have been overcome, I shall now trace ont briefly the outlines of the different processes that have here- tofore been used, and define what I conceive to be their defects, judging from experiment, and the causes of their failure. The complex nature of sorghum cane juice, and the marked peculiarities which distinguish it from the juices of the tropical cane and the sugar beet should not be lost sight of in an investigation of the comparative merits of different methods of manufacture. These character- istic properties require at least a modification of the modes of treatment usually applied to the Southern cane and the beet, to the extent to which these properties are (155) 156 OTHER METHODS. uniformly found to be exhibited. In all cases, the separa- tion of the sugar in the crystalline form from the other constituents of the juice, includes several di-stinct opera- tions, resolved into an apparently simple routine by prac- tice, — and is in fact throughout a process of analysis on an extended scale, involving in its different stages : 1st. The separation of the crude saccharine solution from the woody and cellular tissues of the plant. This is best accomplished by the mill. 2d. The separation of various impurities from the sac- charine solution, and the neutralization or transformation of others of a mischievous nature which cannot be sepa- rated. This is the process of defecation. 3d. The separation of the greater part of the water in which the sugar is dissolved. Evaporation accomplishes this object. 4th. The separation of crystallized sugar, more or less colored and impure, from the resulting semiiiquid mass or mother-liquor which still contains crystallizable sugar and molasses. This includes crystallization and drainage. 5th. The separation of all remaining impurities from the more or less colored sugar of the last operation. This is commonly the work of the refiner. Chemically pure white sugar is its best result. It involves various processes, the most important of which is that technically known as "liquoring." Few manufacturers, however, will find it profitable to carry the process through this last stage. As complete defecation or the separation of the sac- charine matter from the different substances, with which it is combined in solution is the chief difficulty to be sur- mounted, it will be sufficient at present to call attention to this oue point, as I am satisfied that if this be perfectly attained, the difl'erent steps which precede and follow it will present no difficulty, as they depend chiefly upon me- wkay's method. 151 chanical means which are of wider application, and more generally understood. Defecation requires the use of such chemical agents, and mechanical appliances, as will cause the separation of the impurities from the juice without im- pairing the quality of the sugar — a substance which in such association is remarkably unstable, and liable to be either injured or totally destroyed. It should be men- tioned also that there are many beautiful methods known to the chemist, and extremely useful and successful in the laboratory, which, on account of the expense, complexity in the use of the means employed, or for other reasons, are totally inapplicable on the larger scale in practice. With these at present we have nothing to do. wray's method first deserves attention, as it was originally brought into notice in connection with the earliest attempt to make sugar from sorghum in this country. At the first view the merits of this process are obvious. Throughout, it is simple and easily understood. It consists in treating sorghum juice — previously neutralized by lime — with a solution of nut-galls (tannin), which has the property of precipitating in an insoluble form from the juice of ripe cane, nearly all the impurities which hinder the crystalliza- tion and drainage of the sugar. Tannin, or tannic acid, the active agent used, is an abundant natural product, and, as has been already mentioned, may be obtained in a suffi- ciently pure and inexpensive form for ordinary use. The defecation is begun and finished in the cold juice, and the detrimental effects of successive reheatings are entirely avoided, and the evaporation may be carried on expedi- tiously to the close without any interruption. These are important considerations. I will add to them by saying, U 158 OTHER MSTHODS. that the defecation is more complete than can be effected by the use of any single substance of which I have any knowledge that may be legitimately employed in common use for this purpose. As a result of this, crystallization takes place with great facility. In my hands, samples of a very light-colored sugar have erystallized in a solid mass with but little molasses almost as soon as cold. Yet, with all these advantages, the cause of the failure of this method, as uaed by its inventor and others, must, I think, be apparent to every one who has subjected it to a rigorous practical test. The tediousness of this process is the first prominent objection that presents itself. Three filtrations of the whole volume of cold juice are necessary. One to remove the precipitate after neutralization by lime; another to remove the insoluble matter precipitated after treating with the solution of tannin ; and a third, after again treating the juice with lime in such quantity as to form a precipitate with all the tannin remaining in the so- lution. The loss of time consequent upon this series of fil- trations, will appear when this process is compared with any one by which defecation is attained during the brief period in which the juice passes through the first stage of concentration, in which no filtration through fine cloth or some medium of equally close texture, such as is necessary in this, is required. Tannic acid, as is well known, possesses the property of imparting an inky color to solutions containing any of the salts of the sesquioxide of iron even in very minute quan- tities, and inasmuch as contact of the acid juice with iron implements, such as the crushing mill, etc., would be suffi- cient to form in it a trace of iron in solution, it has been objected to this method that a discoloration of the juice invariably ensues after the addition of the tannic acid. It will be found, however, that in all ordinary cases, little or melsen's process. If) 9 no change of color will be produced in this way ; bat if there should be, it will be but temporary, and of no con- sequence. The dark coloring matter being a precipitate which is merely mechanically suspended, and not dissolved in the liquid, is thrown up with the other impurities when lioat is applied, and it is removed with the scum. A much more serious disadvantage is the extreme de- gree of care that is necessary^ much more than would ordinarily be exercised — in apportioning the chemical agents used to the exact effect designed to be produced. Three times — once*before each filtration — the juice must be treated with lime or tannin ; these must be in due pro- portion to each other, or to the variable amount of im- purities in the juice with which they combine. It is true that the bad consequences of a failure to exercise proper care in the use of defecating agents is not peculiar to this process, but belongs to all others in which such substances are used. Yet, here, the lapse of an extended interval between each application imposes a tax upon the memory of the operator whose attention is divided between tins and other matters, and the liability to commit errors through forgetfulness is in this case much greater than in those in which the required additions are made in immediate suc- cession. The practical difficulties attendant upon the successive filtrations of the cold juice are the chief impediments known to the general adoption of this method, and we are compelled to abandon it with regret, since in other respects its results are very satisfactory. melsen's method, which has acquired considerable celebrity in Europe as applied in the beet-sugar manufacture, and also in Louis- 160 OTHER METHODS. iana, where it has been nsed lately to some extent on the plantations, is asserted to possess peculiar merits, — stated by its discoverer in the following words : Bisulphite of lime (the agent employed) acts — 1. As a powerfal antiseptic, preventing the production or formation of fermenting matter. 2. As froifi its affinity for oxygen capable of preventing the changes which the presence of that agent causes in the juice. 3. As an agent which at 100° Centigrade defecates the juice, and removes from it all the albumen and coagulated matter. 4. As carrying away the pre-existing discoloration. 5. As an agent capable in the highest degree of pre- venting the formation of coloring matters. 6. As capable of neutralizing all the hurtful acids which exist or may be formed in the juice, substituting for them an acid almost inert (sulphurous acid). — {Extract from Mons. Melsen's Memoir. Translated by F. Gt. Clemsen, and published in the Agricultural Report of the Patent Office, 1849-50, p. 404.) The value of bisulphite of lime in preventing fermenta- tion can scarcely be overestimated ; and one great hope of the discoverer of this process, and that which led him to the selection of this agent was, " that in the equatorial regions at least, sugar might be extracted by the heat of the sun alone." The antiseptic power of the bisulphite, preventing fermentation for an indefinite length of time, was thus most prominent in his view ; its defecating prop- erties, although important, seem to have been in his view, as they are in reality, entirely subsidiary to that end. As a defecator of the juice of the tropical cane and the beet, its action is not complete, as asserted by himself, as, after the clarification, " there remains a matter which is colored melsen's process. 161 first violet, and afterward brown, by the air or the influ- ence of an alkali." Specifications 4, 5, and 6 (see above), assert facts which are practically of small importance, for by the use of suitable evaporating apparatus after com- plete clarification no injurious discoloration is subsequently incurred ; and by the use of common lime, the hurtful acids may be effectually neutralized. The sulphurous taste said to be imparted to sugar by this mode of treatment, is not a serious obstacle to its adoption, as it is removed by exposure to the air or by the operation of "claying.'' In a hot climate, where fermenta- tion is rapid, and the saccharine juice is comparatively pure, demanding but a low defecating power, this method is successful ; but its merits are not apparent in this cli- mate in its application to sorghum cane. The advocates of the adoption of this method by the sorghum growers of the North, proceed upon the assump- tion that "the constituents of the sorghum and Louisiana cane are very nearly, if not altogether, identical;-' and hence it is predicted that Mons. Melsen's discovery " is destined to exert an influence upon the production of sugar from the sorghum no less marked and decided than that which it has already accomplished in the manufacture from the Southern cane." This assumption, it is scarcely necessary to say, is entirely erroneous ; the constituents of sorghum and Louisiana cane are by no means identical, and any conclusions based upon such identity, and not verified by experiment, are valueless. As a defecator of sorghum juice, I have found the bi- sulphite of lime much inferior to other agents that may be employed. One of the most experienced sorghum growers in this country asserts that he is "unwilling to recommend its use from any evidence yet adduced." (Ag. Rep. for 1861, p. 303.) Though inadequate to accomplish the 14* 162 OTHER METHODS. main object in view, this agent has, I believe, an import- ant use in being readily applicable in preventing fermenta- tion, nnder circnmstances when the immediate application of heat is impracticable. It is said also by some to have the power of restoring the original taste and color to the jnice of soured canes, but the statement " needs confirma- tion." CHAPTER XXIV. THE COMMON METHOD BY HEAT. Extent to which Defecation takes place by this Means without the use of Other Agents — The Advocacy of Erroneous Opinions con- cerning the Action of Heat productive of much Mischief — Sugar cannot ordinarily be made by such Means. Several modifications of a single method of manufac- ture have been applied for the production of sorghum syrup ; the merits of these are made to depend solely upon different forms of evaporating surface in order to secure certain real or fancied advantages from the application of heat. The principle of rapid evaporation in shallow pans is certainly correct, but rapid evaporation and the separa- tion of such impurities only as heat can remove, are but a part of the means requisite to success in the manufacture of merely a fine syrup, not to mention sugar. If boiling and skimming alone could do the work, sorghum sugar would now be found upon every table in the land, and the fact that this is not so, but on the contrary that not more than one operator in a hundred has produced it, under any circumstances, is directly chargeable to the essentially im- perfect mode of treatment which sorghum producers have been induced to adopt; for nothing is more certain than tliat the saccharine matter in the best varieties of sorghum is almost wholly cane sugar, which may readily be crystal- lized when the juice is properly defecated, and that the (163) 164 THE COMMON METHOD BT HEAT. want of success in crystallizing it, is due the presence of just those impurities which heat alone cannot remove. Popular opinion, guided by an experience of more than six years with the common method of defecation by heat, and by the representations of persons pecuniarily interested in securing its continued adoption, is now more unsettled than ever it has been in regard to the practicability of sugar production from Northern cane. No progress has been made in this pursuit commensurate with its import- ance, or with the results reasonably to have been antici- pated from the zealous efforts of the many practical men that it numbers among its supporters and friends. If we seek the cause of this condition of things we shall find it partly, at least, in the injudicious teachings of some who should know better, leading to misdirected efforts and un- promising results. In the face of repeated analyses by the most trustworthy and eminent chemists, and in spite of convictions which a candid examination could not fail to impress upon their own minds, we yet find some advocates of the "heat" theory strenuously asserting that it is only the inferior, and practically uncrystallizable grape sugar which sorghum juice contains, and hence the manifest impropriety of any further attempts toward advancement on this line. Others profess to have reached the " ultima thule" of discovery by sailing in a different direction ; they denounce loudly all "chemicals," even to the use of lime, in satura- ting the free acid ; attribute to heat almost miraculous powers, and then gravely proceed to inform us that the talisman whereby this giant of the elements may be aroused to such unwonted activity is intrusted entirely to their own keeping, or, in other words, that there is only one form of evaporating pan upon which heat as an agent in clarification can be used with success. IMPERFECT DEFECATION BY HEAT ALONE 165 The advantage of the auxiliary action of heat in defeca- tion has never been qaestioned ; it is, in fact, wholly indis- pensable; but it is a great mistake to ascribe to its agency more than is due, and to make that the sole agent vchich cannot in any case rank higher than a subordinate. Much less warrant is there for the assertion that the purifying virtue of " a simple active heat" is of a superior quality when the evaporating surface is made to take the form of a crooked channel by means of a series of metallic strips placed transversely, extending nearly across the pan ''rom the opposite sides. No peculiar advantage in defecation by this mode is discernible, but the reverse ; for each time that the cur- rent of juice passes to the side of the pan it is compelled to pass through the dense body of scum settled there, and much of the feculent and mucilaginous matter which had already been separated from the juice at the heated center of any one of the transverse channels, soon becomes firmly incorporated with the same juice again, when the latter, rendered more dense by evaporation, passes onward through it, and this deleterious effect is produced as often as the current is led from side to side. Nor does the novelty of this mode of evaporation more deserve to pass unques- tioned than its merits. It may be original, but it is cer- tainly not new. Prof. McCulloh, in his work {Reports of Scientific Investigations in Relation to Sugar and Hy- drometers, revised edition, p. 237), describing various arrangements of evaporating surfaces, and particularly inclined planes, with a grooved or undulated surface to diffuse and retard the descent of the syrup, says : " M. Derosne has invented an apparatus of this kind, in which he causes the liquid to traverse the whole surface of the inclined plane, by means of numerous strips of metal placed across, and which are not quite as long as the in- 166 THE COMMON METHOD BY HEAT. clined plane is broad. The space between these strips forms a continuous channel through which the juice flows alternately in opposite directions, and thus passes slowly over the whole surface before it arrives at the bottom." It would be difficult to describe more accurately and minutely in its essential features the sorghum evaporator before mentioned, but from the connection in which the description of this one is found, it is evident that it was proposed to limit its use to the evaporation of previously defecated solutions, and therefore that it was not open to the objection above alluded to. Derosne's pan was heated by steam, but this form of surface was not found to possess any peculiar advantages, nor can any such be justly claimed for it now in its present resuscitated form. It is noteworthy, also, that those who advocate the use of heat, unassisted even by lime, thereby limit its action to a very small share of the influence of which otherwise it is really capable. Fresh cane juice is always more or less acid, and when in this condition its temperature is raised to the boiling point, and it is afterward allowed to remain at rest for a short time, a" scum separates, in which maybe detected more or less albumen, green coloring mat- ter, etc. The liquid underneath is still more or less turbid, and of a greenish-yellow tinge. The action of heat is con- fined to the coagulation of only a portion of the albumin- ous matter, the remainder is held in solution by means of the acid, a boiling heat has no further effect upon it, and it passes into the syrup. The greenish tinge so common in all the light-colored acid syrups is the best evidence of the presence in it also of incoagulable albuminous matter and gum, which hold a portion of the coloring matter suspended in the solution. The consequences of this practice are hurtful to both the sugar and syrup by 1. The production of an acid syrup. 2. The destruction of a part of the FARTHER INJURIOUS EFFECTS. 16T cane sugar. 3. Presenting a great barrier to the crystalli- zation of the remainder. 4. Making the evaporation more troublesome on account of excessive foam. 5. Caus- ing subsequent fermentation in the syrup. Acid sorghum syrup not only always retains more strongly than any other the peculiarly harsh, unpleasant flavor of the green parts of the plant, but also is subject to deteriora- tion, because either by the action of the heat assisted by the impurities during evaporation, or by subsequent trans- formation induced by the retained albumen, a large part of the sugar really contained in the juice is converted into nncrystallizable or grape sugar, and the presence of this lower grade of sugar in any considerable quantity is an in- superable barrier to the crystallization of the cane sugar which has not suffered transformation. Such syrups also, however dense they may be boiled, become invariably thinner after the winter is past, the result of partial de- composition. Fermentation soon sets in. During evap- oration such syrups are more frothy, and the viscidity of the scum renders its separation more difficult. The solution of albuminous matter in the boiling syrup is productive of further evil effects. It impedes the action of boiling, itself, by preventing the mobility of the parti- cles and the free circulation of the currents in the heated liquid. Such syrup is heated less readily and cools more slowly ; more fuel is used to reduce it ; the boiling point 18 higher, and consequently there is much more danger, than in well-clarified syrup, of destruction of the sugar at the last by converting it into caramel. A slimy feculent matter commonly separates from undefecated syrup, col- lecting upon the bottom of the evaporating pan, which soon hardens and burns upon the metal. This, if not constantly removed, soon destroys the pan, as well as barns and dis- colors the syrup, which scorches upon the burning crust 168 THE COMMON METHOD BY HEAT. and beneath it when it cracks open. This crust is of a very different kind from that which is formed when too much lime is used, and is more abundant and difficult to get rid of. In the production of sugar, the common mode of treat- ment is never in the least successful, except when the canes have been selected, the juice naturally very pure, and the quantity of acid and albuminous matter which it contains is extremely minute. CHAPTER XXV. SUGAR MAKING AT HOME. Adaptation of the System herein recommended to Operations of Diiferent Degrees of Magnitude — Outlines of a Method designed to meet the wants of the Farmer who cultivates and works up a Crop of Fifteen or Twenty Acres of Cane. No process of sugar manufacture can be considered complete, or is well adapted to general introduction, that cannot be applied to operations of very different degrees of magnitude. It is neither possible nor desirable here to detail the various modifications to which varying condi- tions and circumstances may give rise, but ordinary intel- ligence and good judgment will readily supply them. A general plan only can be indicated, the essential features of the method to be used pointed out, and the apparatus and means necessary to the attainment of the desired ends de- scribed. The growth of this new branch of industry will doubtless in many places give rise to large establishments, supplanting to some extent more limited individual opera- tions, yet it must be remembered that it is with the latter that the success of the whole enterprise is at present iden- tified. It was only after many years of trial of mills propelled by animal power and inexpensive apparatus that the sugar industry of Louisiana was established upon a solid basis ; and notwithstanding that the most elaborate and expensive machinery has of late years been in use there, small plaut- 15 (169) no SUGAR MAKING AT HOME. ers still adhere to the more simple appliances, and with a very marked degree of success and profit. Here also large works will not interfere with those conducted on a very moderate scale, if the latter be managed with skill and pru- dence. In fact, the expense of transporting large quanti- ties of cane from different parts of an extended area of country to one great central manufactory is a source of great loss in many respects, which is scarcely balanced by the advantages accruing to a great concentration of capi- tal and skill. There is a large class of persons in our country having lands well adapted to sugar growing, and possessed of sufficient energy and intelligence, whose means or oppor- tunities do not permit them to engage largely in this pur- suit, but who would be glad to have it within their power to work up the cane which they could grow upon their own lands ; and it is just this class of persons — farmers of in- telligence and energy, desirous of making use of all avail- able means of enhancing their own comfort, profit, and independence, who have thus far, under so many discour- aging circumstauces, lent their aid to this' enterprise, while capitalists have been lagging in the rear. The question is often asked by such, How can the planter work up to advantage a crop of from ten to twenty acres of cane on his own land and under his own care — con- ducting the whole series of operations, beginning with the working of the soil, and the planting of the seed, and ending with the production of a good article of brown suagar ? The answer that I shall give to this inquiry is based entirely upon my own observation and experience. By pursuing the method of cultivation referred to in a former part of this work, fifteen to twenty acres of cane can be well attended to by a single hand, from the time of planting until the close of the period of cultivation ; or iu lat. 40°, from the 20th of April until the close of June, ARRANQEMEXT OF APPARATUS. 171 except at the time of the second plowing, when two more persons will be needed to hoe the caue. During this period it will have received one good hoeing, and will have been twice or three times plowed. The ground at that time will be free from weeds, and the cane shooting. It may then be safely left to take care of itself. It will require no more work until September, when the blading, cutting, hauling, and the subsequent process of manufacture will follow in regular order, and require generally the labor of three persons until the cane is all worked up, and then one intelligent man can prepare the sugar and syrup for the market as the different lots come into condition to be suc- cessively operated upon. The evaporating range should be not less than twenty- four feet in length, and the mill should be of the largest size, adapted to horse-power. The rolls should not be less than a foot in diameter, and fifteen inches long, if all of the same size ; with the requisite strength in all the other parts to sustain the strain that would ordinarily be applied by the use of four horses. The mill should be placed upon a strong platform of plank, supported by stout timbers. This platform should be built on a declivity, or preferably, when circumstances will permit of it, it may extend from the projection commonly known as the "over- shot" of a side-hill barn. The horses work on the ground floor below ; the swape is a straight beam secured in a horizontal position at a height suitable for easy draught, to a vertical wooden shaft often or twelve inches in diam- eter, which is strongly coupled to the shaft of the driving roll. Mills with horizontal rolls possess superior advant- ages when used in this manner, and require an increase of motive power scarcely appreciable in practice. The convenience of this arrangement is obvious. The horses work to good advantage ; the vicinity of the mill is clear of all encumbrance ; the loss by waste, dirt, damage 1Y2 STTGAR MAKING AT HOME. to machinery, etc. is much diminished. There is room at one side, and sufficient elevation to allow the trash to be thrown into the barn-yard either by hand or by means of a carrier or apron, dumping it over the platform outside the horse-walk, where it will be in a situation to be disposed of to the best advantage in its subsequent conversion into manure. (See Chap. VII.) On the other side, the barn floor is on a level with the ground, where the cane is re- ceived to be passed through the mill. Part of the cane may be piled up outside in a protected situation ; but as much of it as possible should be stored away in the side bays of the barn, where it will keep iu perfectly good con- dition, and may be worked up during all the wet and in- clement weather, when that outside should not be handled. A supply of cane, sufficient for a day's work, may always be stacked alongside the mill, on the barn floor, at inter- vals of leisure, so that the constant attendance of one man to carry cane to the person who feeds the mill-may be dis- pensed with. The mill, the horses, the cane, and all the machinery being thus under roof, there need be no inter- ruption of the work. The evaporator, etc. should be placed at one side under cover, about on a level with the horses, securing thereby an abundance of fall for the juice through a long pipe into the tanks and pans to the cooler, and thence into the vessels to contain the sugar or syrup. The evaporating room should stand at such a distauce, and should be so placed as to avoid all danger to the sur- rounding buildings from fire. There is but little danger, however, from this source, if the furnace is properly con- structed, and the smoke-stack is of sufficient height to se- cure a good draught, and to prevent the escape of sparks. The evaporating and crystallizing rooms should be con- tiguous to each other, and a tram- way constructed from one into the other upon which to convey on a truck the syrup to be crystallized. CHAPTER XXVI. VALUE OP SORGHUM IN SUGAR PRODUCTIOX. Capacity of Sorghum for Sugar Production as ascertained by Analysis and Experiment — Analyses by Dr. Jackson, of Boston — Prof. Lawrence Smith, of Louisyille — Analyses in France by Madinier and Vilmorin — Extended series of Experiments made by Mr. Jos. S. Levering, of Philadelphia — Observations upon a Report of Analyses made by Dr. Wetherill in the Laboratory of the Depai'tment of Agriculture, at Washington. In ortJer to arrive at a true estimate of the value of tbis plant in sugar production, some established variety of it must be assumed as a standard of comparison : and it is to be regretted that for want of due care on the part of planters in preserving the purity of the cane, no one va- riety can at present be selected which, making due allow- ance for diflFerances of soil, climate, and culture, is of an entirely uniform character. This is especially true of the Chinese sorghum. Yet I am convinced, from my own ex- periments and those of others, that care in preventing hy- bridization of the cane, and providing for it the conditions of successful cultivation already indicated, improvement in saccharine richness, as well as in the general vigor of the plant, will be the uniform result. Instead of a juice mark- ing in the unclarified state 7° or 8° Beaame, this variety with me now marks regularly not less than 10° — often 12° with an average of 11°, or 9|^° when properly clarified, and containing seventeen or eighteen per cent, of saccha- rine matter — nearly all of which is true cane sugar. 15* (UB) 174 VALUE OP SORGHUM IN SUGAR PRODUCTION. The followiD^ I have found to be average results from ripe cane, grown on good upland soil : Specific gravity of fresh juice at 60° F., 1085 or 11° Beaum^. Specific gravity of clarified juice at 60° F., 1070 or 9J° Beaum^. Whole amount of saccharine matter, 17 per cent., -which is cane sugar almost exclusively. How this accords vrlth an analysis made by Dr. Charles T. Jackson, an eminent chemist of Boston, Mass., in the year 1857, will be seen in the following extract from his report. (Ag. Rep. of Patent OfBce, 1857, pages 187 and 189.) The subject of this analysis was ripe Chinese cane. Specific gravity of the filtered juice, 1-062. Calculated saccharine matter per cent., 15|. Obtained result, sac- charine matter (cane sugar nearly all crystallized), 16'6 per cent* Some imphees analyzed by him gave from 14-3 to 15 '9 per cent, of sugar (well crystallized cane sugar) (see table), which also corresponds closely with the per cent, of saccharine matter obtained from imphee by Mr. Leonard Wray. In the same Report, p. 194, Prof J. Lawrence Smithi of Louisville, Ky., publishes an account of an "investiga- tion of the sugar-bearing capacity of Chinese cane," in which he gives the following as the composition of the stalk of the cane : Water 75-6 per cent. Sugars 12-Ot " Woody fiber, salts, etc 12-4 " 100-0 * Aji erroneous statement appears in the Report of the Department of Agriculture for 1862, p. 533 (table), in which the result as obtained by this chemist is stated to be 10-15 per cent, total of sugar, instead of 16-6 per cent, as above. ■j- This is equal to nearly 14 per cent, of the juice, instead of 12 per cent., as it is made to appear on p. 533 of the Report for 1862. ANALYSES— SMITH — MADINIKR. 175 In this twelve per cent, of sugar, an examination by Soleil's polariscope indicated the proportion of the crjs- tallizable to the non-crystallizable sugar to be as 10 to 2. And hence he asserts the opinion that "this result settles the question that the great bulk of the sugar contained in the sorgho is crystallizable or cane sugar proper." From the .above it is evident that tbe cane juice ex- amined by Prof. Smith contained about 14 per cent, of sugars (13-7), the proportions of cane and uncrystallizable sugars being respectively 11'4 and 2-3 per cent. The juice did not equal in saccharine richness that analyzed by Dr. Jackson, but this diiference of quality is not greater than is often met with in canes grown on different varieties of soil, or under other dissimilar conditions; but the statement that the uncrystallizable sugar exists in it in very small quantity relatively, is in accordance with the foregoing results. These analyses were made at about the same period, the one upon canes grown on the Atlantic slope, the other upon caae of the same variety grown in the Mississippi Valley ; and they have a permanent value as indicating the saccharine qualities of this cane at the time of its in- troduction into this country. M. !Madinier, of Paris, in a letter, an extract of which is published in the Agricultural Report for 1S56, p. 313, states that the juice of Chinese cane grown in the north of France, in lat. 49°, yielded 16 per cent, of sugars as determined by Clerg^'t's optical instrument. This must be regarded as a very favorable result, inasmuch as the climate in which the cane was grown is scarcely better suited to this- plant than that of England — being sufficiently moist, but lacking the fervid glow of sunlight which prevails during the summer months in this country in the same latitude ; and it is remarkable that there the percentage 116 VALUE OF SORGHTIM IN SUGAK PRODUCTION. of uncrystallizable sugar was found to be so low relatively in the juice of canes necessarily but imperfectly matured. M. Madinier writes : " It is certain that from this plant crystalljzable sugar can be extracted similar in every re- spect to that made from the cane of the tropics. Of this I entertain the highest conviction, which is supported by authentic, though not very numerous facts. * * * The stalks of the sorgho contain crystallizable sugar, without furnishing a greater quantity of molasses than the cane. An experiment made at Verieries, with Clerget's apparatus, showed the juice to contain 16 per cent, of sugar, of which there were only 10^ per cent, crystallizable, and 5f per cent, uncrystallizable. Yet, we can by no means depend upon a result gained from plants grown in the Department of the Seine and the Oise, in a climate altogether beyond the range adapted to the sorgho." M. Louis Vilmorin, of Paris, alluding to his own experi- ments upon canes grown, no doubt, in a more favorable climate than those of which M. Madinier gives an analysis, says:* "The crystallization of the sugar of the sorgho, it seems, should be easily obtained in all cases where the cane can be sufficiently ripened ; and as the proportion of the sugar is an unfailing index of ripeness, it follows that we should always be sure of obtaining a good crystallization of juices, the density of which exceeds I'OTS, while weaker ones could not yield satisfactory results after concentration. " I attribute this peculiarity to the fact that the sugar is preceded in the juice by a gummy principle, which seems to be transformed, at a later date, for its proportion dimin- ishes in exact correspondence with the increase of the saccharine matter. «• Ag. Rep. for 1856, p. 312. M. Viljnorin'B letter is dated AprU 20, 1867. LOVERINO'S EXPERIMENTS. 117 ' " The ancrystallizable sugar, or glucose, undergoes the same change ; that is to say, it is more abundant before than after the complete maturity ; but its action seems less unfavorable to the progress of crystallization. The gummy principle obstructs it in two ways; for, besides Being a serious obstacle to the commencement of crystallization, it afterward renders it almost a matter of impossibility to purge the crystals, if obtained. " However, as I observed, this difficulty only presents itself in the employment of unripe canes ; for as soon as the juices attain the density of r080 and more, they con- tain but little else than crystallizable sugar, and their treatment presents no difficulty. " The lime employed, even to a slight excess, is not so detrimental, it seems to me, in practice, as theory would perhaps indicate. Perhaps a slight fermentation, which is inevitable, may disengage enough carbonic acid to destroy the uncrystallizable compound formed by its union with the sugar. The fact is, that the best crystallizations ob- tained have occurred in those experiments in which I feared to have used too much lime." All the authorities above quoted concur in proving the fact that immediately before and after the introduction of the Chinese cane into this country, cane sugar constituted nearly all of the saccharine matter in the ripe plant. A complete practical demonstration, however, of this fact, outside the laboratory, with only such aids as are within common reach, guided by good judgment and ripe experi- ence, was made about the same time, and the results pub- lished to the world. During the autumn of the year 185T, Mr. Joseph S. Lovering, the eminent sugar refiner of Philadelphia, in- stituted an extended series of experiments upon cane grown upon his own grounds ; and from the yield of sugar and ITS VALUE OF SORGHUM IN SUQAE PEODUCTION. molasses actually obtained by him, he gives the product of an acre of cane definitely as follows : lbs. gans. Actual yield, oryatallized sugar 1221-85 Molasses, 74-39 Add for inefficiency of mill 10 per cent. " " reheatings, etc 5 " " footings, etc 5 " (( (( Total 20 per cent. =244-37 Probable yield per acre. Sugar 1466-22 Molasses, 74-39 The actual yield of sugar and syrup as above stated per acre is, I believe, about a fair average result — such as may be attained from pure cane planted upon a suitable soil, from the latitude of Philadelphia southward. But it will be observed that the yield of juice was much greater, and its saccharine richness proportionally much less than or- dinarily is to be anticipated. The expressed juice amounted to 1847 gallons per acre, or about one-third more than is commonly produced from an equal area ; its density in the crude state was 10° Beaume, but only ^1^° clarified (at 162 F.), containing about 13 per cent, of saccharine mat- ter, as indicated by its specific gravity, or 12-72 per cent, the actual yield of sugar and molasses. Of this, 7'35 per cent, was crystallized sugar, 5 37 per cent, molasses (drip- pings). Taking into the account the 10 per cent, of sugar lost in reheating and footings as above stated, we should have of cane sugar 8 08 per cent; molasses, 4 '64 per cent. The molasses, however, still contained an indeterminate proportion of crystallizable sugar ; another proportion of it consisted of cane sugar necessarily converted into liquid or uncrystallizable sugar during evaporation : hence the per cent, of cane sugar originally contained in the juice must have been considerably greater, and that of uncrys- tallizable sugar proportionally less than in the above estimate. lovering's experiments. 179 Further, since 16,530 pounds of juice (1847 gallons, weighing 8 95 pounds per gallon) produced but 2114|- pounds of saccharine matter — the product per acre of syrup reduced to the striking point — 238° F., could not have exceeded 180 gallons, and hence it required 10 gal- lons of juice to produce one of such syrup. These results prove that the juice of ripe and unhybridized cane contains a variable amount of sugars and impurities due, in a great measure, to peculiarities of soil and season, and confirm the conclusion, then reached by analysis, that the quantity of uncrystallizable sugar contained in the juice as a natural product, and not formed from the cane sugar by the action of heat, etc., is comparatively insignificant. Mr. Lovering did not repeat his experiments, his object being simply to test the value of sorghum as a sugar-pro- ducing plant. In a recent letter he says: "In the year 1857, with no other object in view than to satisfy my own curiosity, I undertook to ascertain a fact thut had been denied by some notable chemist, viz.: — the presence of cane sugar in the juice of sorghum. The use of Soliel's sac- charometer very speedily proved the fact that it does con- tain cane sugar in sufficient quantity to render its extraction profitable, and highly important in our Middle and South- western States. Having ascertained this truth, I was encouraged to proceed a step further, and undertook the experiments, of which I published a detailed account in 1858."* * It is surprising that Mr. Lovering's unasserted but just claim to the thanks of the public for the faithful performance of an undertaking to the success of which he was in no sort pledged, and in which he had only a common interest with all men who desire to know the truth, should in some quarters call forth only disparagement, or subject him to such invidious comparison as is expressed in the following extract from a widely circulated advertising pamphlet ; 180 VALUE OF SORGHUM IN SUGAR PRODUCTION. Since then, occasional instances of successful crystalliza- tion have been recorded ; but they stand out as isolated examples in the midst of many failures ; the results have been far from uniform — success has been the exception rather than the rule — and they have been valuable only as showing the utter futility of the means ordinarily employed. Encouraged by the fact that sugar has been made from sorghum, many practical men have spent years in vainly striving "to learn the knack of it," and failing, have abandoned it in despair, or catching at straws, have become the victims of the first " patent recipe" vender that came their way. The report of Dr. C. M. Wetherill, late Chemist in the National Department of Agriculture, is a valuable contribu- tion to our knowledge upon this subject, but it is unfortu- nate that the opportunities afforded him for making an analysis of the best varieties of the new cane were entirely inadequate. No analyses were made before the month of November, when most of the samples of cane, some of them transported several hundred miles, were, as is inti- mated, more or less injured. Some of the specimens were immature, others were undergoing fermentation, and hence the examination of them was necessarily hurried, and under "A RECOLLECTION. " In 1857 two men were at the same time laboring to develop the merits of the sorgo : one in a Philadelphia re6nery with all the appli- ances capital could confer; the other a backwoods chemist, with nothing but an old skillet and a cooking stove. The experiments of the former were very elaborate and expensive, but there they ended. The latter, ridiculed by his neighbors as a fool for thus wasting bis time, sat pa- tiently over his skillet, studying into the nature of the juice as developed before him, and clutching every new idea, until after many failures in his efforts to embody the suggestions made by his study, be succeeded in bringing out that remarkable and justly celebrated boiler known as Cook's Evaporator," oto. DR. WETHERILL'S ANALYSES. 181 these circnmstances were regarded as merely preliminary to future investigations of a more extended and valuable character. The discordant results of the different analyses, how- ever, after making due allowance for all assigned influences, as well as those peculiarities induced by differences of cli- mate and soil, reveal the unwelcome fact of which there was previously some evidence, that the great bulk of the sorghum now grown in this country is of an inferior qual- ity to that first introduced. Tiiis misfortune is the result of the hybridization of the cane with broom corn, and de- terioration by improper culture, the consequences in most cases of ignorance of the nature and wants of the plant. This discovery is of itself sufficient to impair the value which these analyses would otherwise have possessed as aft'ording a fair index of the saccharine quality of the cane in its native purity. While there is yet in this country nn- deteriorated cane, the juice of which uniformly contains not less than 16 per cent, of saccharine matter, which is cane sugar almost exclusively, none of the specimens sent to the laboratory at Washington contained more than 10 per cent, of cane sugar, and some of them not more than 2 or 3 per cent. ; the whole amount of sugars of both kinds rarely equaled 15 per cent., and in some canes it fell as low as from 5 to 7. The report upon the canes examined is valuable as an exhibit of the present condition of the plant in this conn- try, but as an index of its true value for the production of sugar, it is not to be relied upon. Nor for the determina- tion of this important point are the analyses of sugars and syrups there presented of much greater consequence, how- ever skillfully and conscientiously they may have been made. Nearly all the samples of syrup exhibited a precipitate of crystals of cane sugar in the vessels which contained them. 16 182 VALUE or SORGHUM IN SL'QAR PRODUCTION. In some cases the mass of crystals deposited equaled in volume the clear syrup above them from which they had separated. For the reason that the conditioner the syrups at the time they were sent to the laboratory at Washing- ton could not, in many cases, be ascertained ; in the analy- ses no account is made of the sugar which had been de- posited in this way ; but in the table inserted in the Report only the amount of cane and uncrystallizable sugar in solu- tion at the time the analysis was made, is made to appear. The necessity which led to this arrangement is to be re- gretted, for some true syrups of drainage (molasses) from which the greater part of the sugar had already separated are here compared side by side with others which were known to contain all their original sugar. But it is worthy of note that specimens which had previously deposited a mass of crystals equal in bulk to half the length of the bottle which contained the syrup, still contained a very large per cent, of cane sugar, — in one instance, 35 62 per cent, of cane and 2811 per cent, of uncrystallizable sugar.* * No. 7. White imphee syrup, uncryst. sugar, 28'11 per cent.; crystal- lizable sugar, 35'62; water and impurities, 36-27 = 100*00. If to tlie 35*62 per cent, of cane sugar, we add the "sediment of light-colored crystals of cane sugar extending half the length of the bottle," which may he inferred to have amounted to near 50 per cent, of the whole contents of the bottle by weight — say 45 per cent., the 55 per cent, of clear syrup, analyzed, contained ; Uncrystallizable sugar 15*46 Cane sugar ....*... 19*59 "Water and impurities 19*96 55*00 To which add cane sugar crystallized . . . 45*00 100*00 Hence this syrup originally contained 64*59 per cent, cane sugar, and 15*46 uncrystallizable. It may be inferred that a part of the 15*46 per cent. Is sugar reduced to an uncrystallizable condition by the action of heat. The original per cent, of uncrystallizable sugar must have been exceedingly small and the juice of great purity. DR. WETITERILL'S ANALYSES. 183 It is probable that in all cases in which the cane from which these syrups and sugars were made was pure, that nearly all the uncrystallizable sugar left in the molasses was decomposed cane sugar, resulting from defective means of evaporation, want of proper defecation, etc. This is now known to be true as respects the uncrystallizable sugar in the syrup made from Southern cane, although it was long thought to be a natural product, and treated as such. The samples of sugar sent to Dr. Wetherill were un- equivocally cane sugar, and in most cases exhibited a degree of purity equal to that of commercial sugars made from the tropical cane and the beet. The results of all the foregoing analyses and practical experiments, corroborated by my own investigations, made with care, during a series of years, fully justify me in asserting that there is yet unhybridized Chinese cane in this country, containing in the matured juice not less than 16 or It per cent, of saccharine matter, which is nearly all crystallizable cane sugar. CHAPTER XXVII. HOW TO TEST CANE JUICE. Importance to the Manufacturer of some Means by which he may learn the Value of any given Sample of Cane Juice — Character- istica of Crystallizable and Uncrystallizable Sugars — Microscopic Sections of the Stem of Chinese Sorghum and Imphee — How to distinguish between Grape and Cane Sugar in the Solid Form — Methods of determining approximately the Relative Propor- tions of Cane and Grape Sugars, and Impurities in'Sorghum Juice — The Hydrometer — Subacetate of Lead — Modification of Feh- ling's Copper Test — Peligot's Test by Sugar Lime. It is possible, by means of certain chemical processes, to determine accurately the composition of the cane juice, and to indicate the precise quantities of crystallizable and uncrystallizable sugars in any given sample. To the sugar grower it is always of the first importance to have at hand the means of ascertaining this, if not with rigorous accu- racy, at least to within a close approximation to the truth. Often a simple experiment directed to this end, if carefully performed by him, will serve as a guide to the mode of treatment to be pursued in any given case. It is not ne- cessary that he should previously be possessed of any chem- ical knowled'ge ; he has simply to become acquainted with some of the characteristic properties of the substances which are daily passing through his hands. Without this he cannot have a competent knowledge of his art. A pre- liminary test, requiring but little time or care, would often ri84) CANE SUGAIl IN THE CELLS OF THE PLANT. 185 be invaluable to the manufacturer, if he knew how to apply it, in order that he might avoid errors, in which much time and money would be tlirowu away. It is true, that by adopting a proper system of cultivation, the caiie may be made to yield a juice of a pretty uniform character, yet we never can have the product under perfect control; the quality of the juice will vary within certain limits, with ■ the variable influences of soil, season, situation, and other conditions. It is desirable, oftentimes, to know what particular changes may have been the results of certain methods of culture, or of the use of special fertilizers. Improvement in the sac- charine quality of the juice, and in the health and vigor of the plant, are objects of constant solicitude to the planter: but without a criterion by which to mark his progress, haw can he know whether he is doing well or ill ? The characteristic properties of the two kinds of sugar usually found in sorghum juice, here first demand attention. In the ripe, unadulterated plant, the uncrystallizable sugar is found only in minute quantity, its presence being mani- fested only by the use of very delicate chemical tests. In ripe cane, which has hybridized with an inferior variety, or which has been grown upon unsuitable soil, or exposed to other improper influences, the disproportion between the two kinds of sugar is very much diminished, and the juice is more impure. In imripe cane, grape sugar is largely predominant, and is often the exclusive product. It seems to be impossible to separate this sugar, along with the cane sugar, in the solid form, although a part of it may be made to assume a granular condition when cane sugar is not present, after evaporation and a long period of rest. Another part, however, permanently retains the liquid form under all circumstances, and this has been denominated fruit sugar, but a solution containing cane sugar is capa- 16* 186 HOW TO TEST CANE JUICE. ble of yielding in the solid or crystalline form cane sugar only. Inasmuch as the other two varieties of sugar above mentioned are not distinguishable from each other by the ordinary chemical tests, and exhibit the same properties, they are recognized throughout this volume by one name, that of grape sugar. They form a viscid liquid, which, if found in large proportion in syrup, renders the cane sugar practically uncrystallizable, by acting as a barrier to the union of its particles. An incontrovertible evidence of the preseitee of cane sugar almost exclusively in the juice of sorghum, is afforded in the fact that thin sections of the fresh stalk of the plant under the microscope exhibit the cells filled with innumer- able minute crystals of pure white sugar, which by their form and other criteria are shown to be cane sugar only. Scarcely a trace of any other substance is found in the cells. This is well represented in the engravings. Fig. 3 represents a thin slice of the stalk of Chinese cane (transverse section, from near the center of the stem), magnified 200 diameters. Fig. 3. ''■^ .?tl^fe^i:^:■ 0-4 0-773 0-809 salts, j Water 72-0 72-1 76-080 76-729 100-0 100-0 100-000 100-000 SORGHUM. Smith. Stewart. Sugar 12-0 14-5 Woody fiber, albumen, and salts 12-4 12-5 Water 75 6 73-0 100-0 100-0 208 COMPARISON OF SOUTHERN CANE AND SORGHUM. On account of the softer texture of the outer covering of the stalk of sorghum, and es-peoially on account of the greater length of the internodes — or spaces between the joints of this cane, as compared with the tropical cane — its juice may be more readily and perfectly expressed. (See Ch. XIX.) 11. Chemical Composition — The Juice. S. cane Properties of the juice : color, pale yellowish gray, faint balsamic odor, frothy as it flows from the mill, turbid and- opalescent, on account of the suspension of finely divided matter separable by filtration. A few drops of sulphate of copper solution and an excess of caustic potash occasion, on heating, a very -abundant red precipitate of suboxide of copper in the juice, indicating the presence of glucose or grape sugar (Fownes). Specific gravity 1-070 to 1-090, (Fownes, Evans), but sometimes varies from 1 046 to 1 -110, or from 7° to 15° Beanme (Evans). Otaheitan cane juice 1-070 at 77° F. (McCulloh). The juice gives a slightly acid reaction with litmus paper. Sorghum. — Color of the fresh juice, bright green, with a tinge of yellow (Chinese cane), or yellowish green, inclining to brown in some samples (imphee) — a faint and peculiar odor most marked in imphee juice. The presence of grape sugar is generally indicated by the application of the copper test. Blue litmus paper is instantly reddened when dipped into the juice, showing that the solution is acidulous — least so in pure Chinese cane juice, most so in red imphee (Shlagoova). Specific gravity varies from 1-050 to 1-090, or from 7° to 12° Beaume. Average of crade juice, Chi- nese, ripe, 1-075 to 1-080, or 10° to 11° Beaume. CHEMICAL COMPOSITION OP THE JUICE. 209 TROPICAL SUGAR CANE. Avequin. (La.) Sugar 15 784 Organic matter and salts 0-376 Water 83-840 Casaseca. Evans. (Cuba.) 20-94 18-20 0-26 0.80 78-80 81-00 100-000 100-00 100-00 SORGHUM. Juice of Chinese Cane. (Stewart.) Sugar 16-00 Organic matter and salts... 1-60 Water 82-40 100-00 Per cent. of Sugar. Variety of Cane. 13-7 Chinese (Smith.) 16-6 Chinese (Jackson.) 15-9 Imphee " 16 Chinese ....(Madinier.) 18* CHAPTER XXIX. NATURAL AFFINITIES OF THESE CANES — INFERENCES DERIVED THEREFROM. The Nature of the Relationship between Chinese Cane, Imphee, etc. — Species — Varieties — Are they all of one Species or of several? — Facts which throw Light upon this Question — Tests of Specific Identity — The Inference that they are of one Species not at yari- ance with the Fact of their wide Geographical Distribution — The Climate of China — Early Planting of Cane necessary in that Country — The Climate of Southeastern Africa — Inferences — Precautions to be observed — Mr. Wray's Account of the Imphee Canes of South Africa. A KNOWLEDGE of the true nature of these new sugar plants, and of their relationship to each other, would en- able us to determine how far the very variable characters, exhibited by each, are capable of being retained or fixed, what probable limits there are to their fature improvement, and what precautions must be observed in order that the saccharine matter in the juice may reach its most perfect development. The affinities of plants are determined by certain common points of resemblance, and naturalists have generally agreed in the opinion that, certain peculiarities, which are contin- ually reproduced by the individual forms possessing them^ are characteristic of Species. In other words, species are represented by individuals descended from a common stocli, which invariably retain certain peculiarities of form, etc., through all successive generations wherever they are found. (210) ARE THESE CANES OP ONE SPECIES? 211 Yery striking, but less constant, peculiarities of a subor- dinate kind are also exhibited. Some of these, however, as long as they are subjected to human control or to highly favorable influences, are likewise regularly reproduced, and individuals, which possess them in common, are thrown into sub-groups, which are known as Varieties. When the controlling influence is withdrawn, these varieties or races generally revert by degrees to their original form, losing totally, in time, their subordinate characteristics, and at last are distinguishable in no respect from their primitive type. Thus the essential characters of species are permanent; those of varieties are inconstant. It has also been observed, and is generally conceded, especially by botanists, that vari- eties freely hybridize with each other, and thus become modified, while species naturally do not; or if hybrids have in some instances been produced from two individuals of closely allied species, their offspring is barren. The tendency of different varieties, of a single species, to freely intermix and produce an offspring as fertile as the parents is suflBciently constant, if it may not be regarded as an evidence of specific identity among all the individuals possessing it. We are less concerned to know what is the true place of these canes in botanical classification than to determine their real affinities, and how certain peculiarities, which they now exhibit, may be perpetuated ; yet, as the one involves the other, the answer must be to the question : are all the different kinds now grown in this country vari- eties of one species, or are they not ? If they are varieties of a single species, we may infer that they will be constantly liable to change, until their qualities have become fixed and perpetuated, through in- fluences continually exerted upon them under human direc- 212 NATURAL AFFINITIES — INFEEENCES. tion, or, on the other hand, that they will continually degenerate if those controlling infiiiences are withheld. Now what is the evidence of the facts which regularly come under our observation ? We find that ever since sorghum and imphee have been cultivated withio the United States, they have not only freely commingled when grown in each other's vicinity, but they have also freely amalgamated with doura, or Guinea corn, and with broom corn, and new and fertile varieties may thus readily be pro- duced and perpetuated. No other grasses exhibit an ex- ample of such prolificacy in the hybrids of well-determined species. But if they are distinct species, there must be found some characters to fasten upon which can be regarded as constant, and such also as demand recognition, as belonging to spe- cies. Such a character is certainly not presented in the saccharine quality of the juice, for the same is possessed in a greater or less degree by other kindred species of grasses ; nor can any others properly be so regarded. Among the most decisive tests of specific identity are the following : two races may be regarded as specifically dis- tinct when there are no intermediate gradations tending to connect them, and, conversely, two races may be re- garded as specifically identical when they are connected together by close intermediate gradations. (Carpenter.) Applying this principle, we discover, in collections embracing the different kinds of this cane grown in the United States, that all the prominent characters, which might be thought at first sight to indicate specific diversity, are manifested in a greater or less degree by all alike, and that there is almost every possible gradation between ex- treme forms. Chinese sorghum, the different kinds of imphee, doura corn, and broom corn, are distinguishable from each other chiefly by such trivial characters as the GEOGRAPHTCAL DISTRIBUTION. 213 open or more compact form of the panicle, the color and degree of prominence of the seeds beyond the glumes, the shape of the seeds, whether round, or more or less elliptical or oval, pubescence, difference of stature, and in the proportions of saccharine and other matters in the juice. None of these characters are of such a kind or importance as to entitle them to be regarded as a basis of specific dis- tinction. We conclude, therefore, that like the different varieties of Indian-corn, of the potato, the cabbage, and the tomato, these races are all referable to a common stock. This inference is not at variance with the fact that dif- ferent varieties are now found apparently indigenous to geographical regions very widely separated. On the sup- position that they had a common origin, there is nothing improbable in believing that through Egypt the original plant may readily have found its way to the extremity of either of the connected continents, where they now grow. But community of origin is not essential to specific identity, and the question whether these plants originated in a single locality or not, is unimportant in this connection. The wide geographical distribution of the several varieties is more easily accounted for upon the supposition that they, as well as other plants, were created in the regions where they were found. The reason why one strongly-marked variety is found only in a remote district of Eastern Asia (Chinese cane), and another on the southeastern coast' of Africa (Imphee), and another in Nubia and Egypt (Doura), is certainly no more difficult of explanation than why the red currant should be truly indigenous to both this country and Europe, or why the wild hop- vine of our glades, or the "Jerusalem artichoke" from the great western plains should here en- counter their own living fac-similes migrating with man from an eastern clime. 214 NATURAL AFFINITIES — INFERENCES. Nor is ttere any greater difference between the Chinese cane and the Imphee, or between the Imphee and the Doura, than the peculiarities of climate and soil are uni- formly found to eastamp upon plants or animals exposed to them — or than the diversity of physiognomy of the races of men native to those regions — the Mongul and the Caf- fre, or the Caffre and the Copt. The history of sorghum sugar cane is buried in such deep obscurity that it is almost useless to inquire what was the original type of the species. One variety — the Doura or Guinea corn — has been known to Europeans, perhaps, longer than any other. It was introduced into Jamaica, and thence into our Southern States, in the last century.* The brief sketch given in Chap. I. embraces nearly all the information respecting the Chinese sorghum accessible at present. The Chinese assert that they have made sugar for 3000 years. In the neighboring Islands of Japan much of the common sugar in use is made from sorghum, as we are told by the Rev. Dr. Betelheim, recently a missionary in that country. To what extent, if at all, the plant is used for the same purpose in the north of China, which has a similar climate, cannot yet be determined. Prom the best information hitherto obtained, the climate of Niphon (one of the Japanese Islands) and of the northern parts of China corresponds closely in temperature to the midland regions of this country in the latitude of St. Louis, Mo., or the climatic belt in which sorghum culture has heretofore proved the most successful. In Eastern Asia, however, the geographical range of the plant northward is abruptly checked by the great rainless plateau, or Desert of Shamo, the southern limit of which follows closely the northern boundary of China, or the * Morse, Geog., p. 76i. CLIMATE OF NORTHERN 'CHINA. 215 Great Wall. The whole of Northern China is drained by the river Hoangho and its tributaries, and possesses very diversified features, — lofty mountains, warm, sunny slopes, elevated plains, and broad, rich valleys. At Shanghae, which is on the coast on the southeastern border of this district, spring opens early, and the rains are periodical or at the changes of the monsoons. These occur from the middle of March to the middle of April, and from the middle of September to the middle of October. Crops are planted there before the middle of March, so as to en- joy the benefit of the spring rains. Succeeding them, or from the end of April to the middle of September, the weather is generally dry, the sky clear, hot at noonday, often rising to 100° F. in the shade during the months of July and August, and pleasant at night. These peculiari- ties of climate would make it necessary to plant the cane before the spring rains, or before the middle of March, and to cut it before the middle of September in this its native climate. Evidence is thus afforded that the natural habits of the plant are adapted, during the early part of its growth, to just such climatic conditions as are usual during early spring in our own country — a period of low tempera- ture and frequent rains, succeeded rapidly by hot summer weather. The soil* of this portion of China is said to be chiefly clay on the uplands, of a yellowish-brown color, derived from clay-slate, largely commingled with loam from the underlying rocks. The valleys are often broad and very fertile. The correspondence of the climate of China, as well as of all Eastern Asia to that of the eastern coast of North America, is a noteworthy fact, which is due, in a great * Patent Office Eep., 1857, p. 169, etc. Missing Page WaAY'S ACCOUNT OF THE IMPHEES. 217 ties, — some have deteriorated, while others have certainly improved. It is also evident that the planter is, to a high degree, responsible for these changes. Within certain well- defined limits, he holds the destiny of this plant under his control. The care and enthusiasm of the stock-raiser is needed in this pursuit. Certain qualities may be made transmissible, and permanent varieties, like new breeds of cattle, may thus be originated and perpetuated. Without sedulous attention, and enlightened skill bestowed both in the culture of the plant and in selecting for it those condi- tions of growth and of improvement which its proper nature demands, gradual deterioration will be the result; but if the aim is to improve to the utmost every good quality, under the guidance of a just judgment of its wants and its capacity for improvement, we shall have varieties much superior to any at present known. For the purpose of comparison, Mr. Leonard Wray's account of the different varieties of iraphee cane, at the time of their introduction into this country (the year 1851), is here appended. " I am acquainted with fifteen varieties of the Holcus Saccharatus, although I doubt not there are yet others in different parts of the world that have not come under my notice. I shall therefore confine my remarks to the fifteen varieties ; and to prevent the constant repetition of their botanical name I shall use their Zulu-Kaffir name of imphee alone. "Among Europeans, residing in South Africa, no dis- tinction is known in regard to the varieties, and there they will be much surprised at learning that there are really fifteen different kinds of imphee growing before their eyes and being constantly eaten by them. There is certainly that degree of similarity between them, when seen growing 19 218 NATURAL AFFINITIES — INFERENCES. together, which is quite sufBcient to puzzle any one who has not thoroughly studied them, and this is so much the case that there are very few male KafBrs even who can dis- criminate between some of the varieties; in consequence of which I had very frequently to call in the superior agri- cultural knowledge of the old KafBr women, until I had learned to distinguish them with certainty myself. "When I had attained this first most desirable step, I had next to learn their several peculiarities and value, which I was able to do with greater exactness by planting the seed, watching them daily during their growth, and eventually testing the saccharine value of their juices, and making sugar from them all in large quantities. " Vim-his-chu-a-pa. This is the largest size, and the tallest of the whole, while it is full of juice and very sweet. When planted in rich alluvial soil it attains its greatest size and most perfect development, requiring from four to five months to arrive at maturity. It grows to a height of from ten to fifteen feet, is one and a half to two inches in diameter at the lower end of the stalk, and usually cracks or splits as its ripens. By means of a most primitive and ill constructed little wooden mill, I obtained sixty per cent, of juice from the stalk. This juice was clean and clear, and the saccharometer showed it to contain fourteen per cent, of sugar, after I had removed the feculae by means of cold defecation. The sugar it yielded was folly equal to the best cane sugar of the West Indies. The stalks, carefully weighed, were found to vary from one and a half to two and a half pounds English weight each, trimmed ready for the mill. The seed head, which is very large and beautiful, is generally from twelve to eighteen inches in length, con- taining many thousands of fine plump seeds, of a sandy, yellow color, strongly held by a sheath, which partially en- velops them. wray's account of the imphees. 219 " E-a-na-moo-dee is the next in size, and is very similar both in habit and value to the last. It attains a height of twelve to thirteen feet, but is not so coarse in appearance, nor does it contain so much woody fiber as the Vim-bis- chu-a-pa, but is rather softer and more juicy, I haviug obtained from it sixty-four per cent, of juice, containing fourteen per cent, of sugar. The stalks weigh from one to two pounds when trimmed ready for the mill, and I have cut as many as eleven such stalks from one root or stool. The seed heads are large, but stiff and erect, con- taining quantities of large, round, plump seeds, of a clear yellow color. In general they may be said to ripen two weeks earlier than the last named. Like the Yim-bis-chu- a-pa, this variety ratoons in about three to three and a half months after the first cutting. " E-en-gha. This is a fine, tall kind, being from ten to twelve feet high when full grown, but it is more slender than either of the foregoing, and exceedingly graceful in appearance. It begins flowering in ninety days, and is fully ripe three weeks after ; we will, therefore, class it at four months. I have had stalks weighing as much as one pound fourteen ounces each. The largest commonly obtained may then be estimated at two pounds weight; yielding, by my poor little mill, sixty-eight per cent, of juice, containing fourteen per cent, of sugar. I have obtained ten stalks from one stool. They ratoon in three months after cutting. The seed head of the Een-gha is large and very pretty, the seed being upon long, slender foot-stalks, which are bent down by the weight of the seed, forming a graceful drooping. The seeds, which are of a dull yellow color, are rather long and flat than plump and round. "Nee-a-za-na" (White Imphee) "is held by the Zulu- Kaffirs to be the sweetest of all the imphee kind ; but I 220 NATURAL AFFINITIES — INFERENCES. found the Boom-vwa-na and the Oom-see-a-na quite as sweet, and, in my estimation, their juices are superior to it in some points. My Zulus have told me that under favor- able circumstances the Nee-a-za-na frequently ripens in seventy-five days ; and my head-man (a most intelligent native plowman) declares that he has had them from his own land as sweet as any sugar cane. From my own actual experience I found that they ripened in about three months, and that they were the softest and most abounding iu juice of any. With my mill, I obtained seventy per cent, of juice, much still remaining in the trash, and the saccharometer showed fifteen per cent, of sugar after cold defecation. This, then, for European culture is a perfect gem of a plant ; one which will be anxiously sought after, and very generally cultivated throughout Europe at least. In two months after the first cuttings I have had the ratoons six feet high, and in flower. The Nee- a-za-na is a very small sized variety, but tillers out greatly, having sometimes fifteen stalks to one root. I have had its stalks varying from four ounces to twelve ounces in weight, but they do grow rather larger than this. It always appeared to me that their juice was more mucila- ginous, and abounding in faculae than the two varieties I have just mentioned. The seed head is very bushy and branchy, and, when thoroughly ripe, the seeds are large, round and plump. " Boom-vwa-na is a most excellent and valuable variety, of which I have eaten single pieces, containing certainly two or three per cent, more sugar than the average juice obtained from large bundles of stalks taken as they come. This average jnice never contained less than fifteen per cent, of sugar, as indicated by the saccharometer, after the raw juice had been cold defecated ; and there is a clear- ness, a brightness, and a genuine sugar cane sweetness in ■wray's account op the imphees 221 the juice of this variety, and of the Oom-see-a-na that I very much admire. In its growth and general appearance it is very much lilie tbe E-en-gha, but its stalks are brighter and more slender; its leaves are not so broad, audits seed vessels are upon shorter and stiffer foot-stalks. The stalks have a pinkish-red tint, which increases as they approach maturity; and the seed cases have a pink and purple hue, mixed with the general yellow ground. The Boom-vwa-na tillers very much, giving from ten to twenty stalks for one root; but they seldom weigh more than one pound each. I have obtained seventy per cent, of juice, which is easily clarified, and makes a beautiful sugar. The plant reaches perfection iu from three to three and a half months. " Oom-see-a-na" (a variety of this misnamed " Ota- heitan") "is a peculiarly marked variety, in consequence of the purple or black appearance of its seed heads, arising from the sheath or seed cases being of this color, and not the seed itself. The seed head is very stiff and erect, with short strong foot-stalks, and the seed is large, round and full. In time of growth and goodness of juice, it is very similar to the Boom-vwa-na ; its stalks are small, but numerous. They both ratoon well from first cuttings. " Shlagoo-va " (Red Imphee) "is slightly inferior to the three last named varieties, but is nevertheless very valua- ble, and much prized by the Zulus. It takes three and a half months to ripen, and becomes a tall, good sized plant, but its chief distinction is the exceeding beauty and ele- gance of its seed heads. The foot-stalks are extremely long, which causes them to have a graceful drooping, while the seed cases, or sheaths, vary in color from a deli- cate pink to a red, and from a light to a very dark purple, but each color very bright and glistening, forming on the whole an extremely beautiful appearance. " Shla-goon-dee, This is a sweet and good variety, and 19* 222 NATURAL AFFINITIES — INFERENCES. under favorable conditions produces fine-sized stalks. The seed lieads are very stiff and erect, and the seed vessels are compact and very close. It usually takes three and a half months to reach maturity, and it ratoons very quickly, as the following memorandum of my diary will show : 'December 13th. Cat down a small patch of imphee, and dug up the ground for the purpose of planting arrow-root, but some of the imphee not being entirely eradicated, sprung up afresh, some roots having fifteen stalks each. On the 18th of February, one of them (Shla-goon-dee) was upwards of six feet in height, with a thick stalk, and the seed head just thrown out, being only two months and five days from its being cut down and apparently de- stroyed.' This bunch of seed I gathered during the first week in March, and I have it now in England. " Zim-moo-ma-na. This is likewise a sweet and good variety, with seed heads upright and compact, and fine plump seeds, very numerous. " E-hoth-la, Boo-e-a-na, Koom-ha-na, See-en-gla, Zim- ba-za-na, and E-thlo-sa, form the remainder of the fifteen varieties, each differing slightly from the others in its saccharine qualities, as well as in appearance, but still easily distinguished from each other by any one who .has studied them." It will be seen from the above descriptions, that the imphees now most commonly grown in this country have already suffered considerable modification. The Neea- zana and Oomseeana have improved. CHAPTER XXX. OTHER PRODUCTS. — SYNOPSIS OF PROCESS OP MANUFACTURE. Success in Sugar Manufacture in a great degree dependent upon Economy in the Use of the Waste Products — Value of the Cane Trash for Manure — Paper Manufacture — Rooiing — How Silk, Wool, and Cotton may be dyed various Colors from a Material contained in the Seeds and Trash — Use of defecated unripe Juice as a Source of Grape Sugar, to add to Grape Wine by Dr. Gall's Method — Uses of the Seed, etc. — Vinegar. Synopsis of the Process of Manufacture — Cream of Lime — Mode of Purifying Barrels. The utilization of what are commonly regarded as the waste products of a sugar manufactory is of much import- ance. Although the capacity of the plant for the produc- tion of sugar and syrup is to be regarded as the principal and almost exclusive element in any rational computation of its value, we should not lose sight of the fact that success in this branch of industry at the North will depend in a great degree upon the skill of the sugar planter, in making the best possible use of every material within his reach. It is of primary importance to him to increase the pro- ductiveness of his lands to 'the utmost extent within his power. It has already been shown (Ch. VII.) how the trash pile may readily be made subservient to that end by restoring annually to the land most of the substances ne- cessary to the growth of future crops, which are annually (223) 224 OTHER PEODTJCTS. removed with the cane. This use of the trash and of all other waste materials, derived from the plant or introduced during the process of manufacture, will generally be found preferable to any other uses to which they may be applied. It has been found that a cheap and good quality of paper can be produced from the crushed cane, and where a paper mill is convenient, it may be more economical to dispose of it for that purpose, provided that a larger quantity of ma- terials, as valuable for manure as the trash, is purchased and returned again for the price for which the latter was sold. There is another use, however, to which cane trash may be put, that well deserves attention. It has been known for some years past, that the Chinese produce in fabrics of silk and wool a beautiful red color, which is derived from the seeds of sorghum. Experiments made both in this country and in Europe, likewise show that the same dye may be obtained from the crushed canes. For this purpose they must be sheltered from the rains after they are re- ceived from the mill, and thrown in close piles until fer- mentation sets in. Afterward the heaps are to be opened, and stirred frequently to prevent heating, which would destroy the coloring matter. When their color has changed to red or reddish brown, they are then cut up, washed and dried. A weak lye of caustic potash may be used to extract the color from them.* By neutralizing this alkaline solu- tion with a weak solution of oil of vitriol the color falls in the form of red flakes, which are easily soluble in alcohol, alkalies, and diluted acids. To Mr. Henri Erni, Chemist in the National Agricul- tural Department, we are indebted for the following obser- » A. Winters, in Liebig's Jahresberioht, 1859, p. 754; quoted by Weth- erill, Ag. Eep. 1862, p. 535. SORGnUM DYE. 225 vations respecting the mode of using this new dyeing ma- terial, derived from experiments conducted by himself in the laboratory at Washington City : * " The simplest solvent is alcohol (very expensive at present). Dilate acids were resorted to with very good success, and at an expense and trouble hardly worth men- tioning. The seeds were boiled in vinegar, or in water to which oil of vitriol had been added, before heating, until the mixture tasted as acid as vinegar. Other acids, such as tartaric, oxalic, etc., can be used, but are more expensive. When the liquid assumes a red or rather an intense orange color it is ready for use. The articles to be colored are at once brought into the hot solution, and agitated until the color no longer increases. They are at once removed and dipped into a weak solution of salt of tin (chloride of tin), obtained by dissolving tin in hydrochloric acid. They are then exposed to the air for a short time, and washed. " Cotton and silk may thus be colored red, wool turns to a beautiful purple, and an almost unlimited variety of colors and shades may be obtained by substituting for salts of tin other mordants. All the various shades of red, purple, orange, gray, etc. are thus produced from the same bath, the cloths being afterward drawn through solutions of pro- tochloride of tin, bichromate of potash, sulphate of copper, ammonia, lime-water, snbnitrate of bismuth, etc. Yellow is produced by adding to the seed sufficient nitric acid to form a thick mushy mass. Too much acid will make a straw color. " The dye turns solid by standing, and may thus be stored. To dye silk or wool yellow, the solid dye is dissolved in boiling water, the goods dipped into it and afterward washed. * Report of Department of Agriculture, 1864, p. 532, Missing Page SORGHUM FLOUR. — VINEGAR. 221 thus prepared differ but little from those prepared from well-ripened grapes, and are much to be preferred to the fermented fruit juices in common use. Sorghum seed has frequently been used for the manufac- ture of a kind of flour which has proved to be nutritions and valuable. It somewhat resembles buckwheat flour. In the Southern States particularly, large quantities of it were used during the late rebellion. That made from cer- tain varieties of cane contracts a light pinkish color from the outer covering of the seed. The seed, ground with oats or corn, or without intermixture, forms a valuable feed for horses and cattle, and is considered to be equal to rye for this purpose. The whole grain boiled is also excellent food for cattle or fowls. From thirty to fifty bushels of seed may be grown upon an acre of ground. The blades, and young cane from the second cutting of early ripening varieties, may profitably be cured (see Ch. XII.) and used as hay. The scum produced in this process is very valuable for feeding swine for fattening, but the precaution must be taken to commence feeding it in small quantities, gradually increased, and always in connection with grain. It should not be fed in a fermented condition. Ordinary cane juice is capable of being converted into from 5 to 9 per cent, of alcohol. The mode of making vinegar from sorghum juice, or from the washings of the pans, the filter, etc., differs in no respect from that ordina- rily pursued in converting cider into vinegarj except that when the juice of cane is used, it must previously have been thoroughly defecated. Before fermentation a cupful of fresh yeast must be added to each cask. SYNOPSIS OF THE PROCESS OF MANUFACTUEE. Into one division of the double tank M, admit the juice from the mill through the pipe (Fig. 5) represented below, Fig. 5. and placed as indicated in Ch. XV., adopting the precau- tions there mentioned.* If the mill is placed upon a plat- form (Ch. XXV.), a straight pipe only is required Fill up one division of the tank to the mark, and turn the current of juice into the other. Add gradually to the former milk of lime until the red litmus paper changes color, stirring the juice well. Then pour in the proper measure of the clarifier, and stir. Meanwhile, the fire has been kindled in the furnace. When the water in the evap- orator is boiling briskly, open the gate of division A for its escape into B. At the same time permit the prepared * For the bucket upon the head of the pipe a larger vessel may be sub- stituted (if preferred), consisting of a tightly jointed box about 2 feet in length by 15 inches in width and the same in depth. Two or three light frames, covered with coarse canvas, iitting into grooves in the sides of the box, divide it transversely into compartments, through which the juice passes successively, entering the box at one end and passing out into the pipe at the other. All the suspended matters in the liquid are thus removed, and with the advantage that the canvas strain- ers in the upright position are not easily clogged, and are removed with facility when it is necessary to clean them. The first of the series of strainers should be coarse, so as to arrest the grosser impurities, such as fragments of pith, etc., and the rest successively finer. A modification of this simple arrangement constitutes the celebrated leafjilter of Mr. Jos. S. Levering. (228) SYNOPSIS OF THE PROCESS OF MANtTFACTTJRE. 229 juice from the tank to enter A in a small continuous stream. (See directions, Ch. XV.) Draw off the water succes- sively from all the divisions of the pan, and admit in its place the clai'ifled juice. The boneblack filter should pre- viously have been carefully filled with well washed, odor- less (well burned) animal charcoal. Retain the water upon the filter, so that it may cover its surface, until the syrup is to be admitted into C, when it must be allowed to es- cape in advance of the juice. Admit the syrup into the finishing pan D, at intervals, in sufficient quantities, but not to a greater depth than 1| inch at a time. Boil for Byrup to 228° F., or for sugar to 230°-232° F. For the defecation of juice which is more than ordina- rily impure or unripe, the first method indicated in Ch. XX. is perhaps to be preferred, but the second method should generally be employed when the cane is in good condition. Remember to keep the depth of juice in A at about ^ inch, and never flood it. The central square betweeen the ledges should be continually overspread by a sheet of boiling juice. Do not permit the filter to be overflowed, but allow the syrup in the filter to cover constantly the surface of the charcoal. Syrup for crystallization should be allowed to accumu- late in the cooler, and should be removed at night to a room kept heated to not less than about 80° F. Observe the precautions to be used in filling the boxes, draining, etc. (Refer to Ch. XYII., etc.) Cream of Lime. This should always be prepared be- forehand, from good quick-lime, as follows : Upon a half peck of lime, freshly slacked, pour two or three gallons of boiling water, stir the mixture, and let the lime have time to settle to the bottom ; decant the clear liquid ; pour 20 230 SYNOPSIS OF THE PROCESS OP MANUPAOTUEE. upon the lime another gallon or two of hot water, and decant a second time. Place the washed lime in a deep jar, mixed with just enough of water to make a mixture of the consistence of very thick cream. The coarse particles will fall to the bottom, while the finer sediment will occupy the upper part of the jar. Dilute it with a little water when it is to be used. Cleansing of Barrels. Syrup barrels of all kinds, and especially those which hare contained old molasses, should be thoroughly cleansed. The importance of this will be bettej appreciated when it is known that if it be neglected or imperfectly performed, a refined syrup will acquire from the barrel a flavor which will render useless all the care and skill previously bestowed upon it. The barrels should first be washed out by pouring hot water into them, turn- ing them frequently, and standing them up on each end alternately until the water has abstracted all that it is ca- pable of dissolving. Lime-water may then be poured in, the bung inserted, and the casks turned at intervals, for a day or two, as before. Finally rinse them out, and suspend into each barrel, upon a bent wire, a lighted sulphur match, made beforehand by dipping a piece of cotton cloth into melted brimstone. A narrow slip of muslin may be so prepared, and afterward cut into pieces of three or four inches square, one of which is sufficient for fumigating a single cask. Insert the bung while the match is burning. Afterward withdraw the wire, and keep the barrel bunged up until just before it is to be used, when it should be care- fully rinsed out. New casks of oak may be purified simply by introducing into them a few gallons of lime-water, or a smaller quantity of thin milk of lime, and rolling them about frequently, 80 that the whole of the interior may be saturated with HOW TO REMOVE "TANG." 231 the lime solution. Wasli out with a little fresh water when they are wanted for use. A mouldy smell or iang may be removed by introducing a peck of wheat or rye bran, mixed with a little warm water, into the barrel, and add to it a cupful of fresh yeast. Insert the bung loosely, and let the mixture remain in the barrel for a week. Turn the barrel occasionally, and during the fermentation which ensues, the mouldiness will be entirely removed. The fermentation will be more rapid if the cask is kept in a moderately warm place. 232 WEIGHT or SUGAR, ETC. IN 100 LBS. OP JUICE. I. Table " Showing the quantity of sugar contained in one hun- dred pounds of expressed cane juice, or syrup, of good quality, and also of the quantity of water that must be evaporated, to reduce the same to the state of saturated syrup at each degree. A saturated solution of very pure sugar contains five parts of sugar and three parts of water. This is indicated by 34° of Beaum^'s sacoharo- meter, at the temperature of 82° Fahr." — Dutrone. Degrees of Weight of Water in each 100 lbs. of Juice or Syrup, beyond the water of solution. density by Beaiim6'a Scale. Weight of Sugar ii lbs. of Juice or each 100 Syrup. lbs. oz. dT. lbs. oz. dr. 1 1 13 6 97 15 2 8 10 12 94 "{ 14 3 5 8 3 91 2 13 4 7 5 10 88 3 12 5 9 3 85 4 11 6 11 "7 82 5 10 7 12 13 14 79 6 9 8 14 11 4 76 7 8 9 16 8 11 73 8 7 10 18 6 1 70 9 6 11 20 3 8 67 10 6 12 22 15 64 11 4 13 23 14 5 61 12 3 14 25 11 12 58 18 3 15 27 9 2 55 14 1 16 29 6 9 52 16 1 17 ' 31 4 50 ... ... 18 33 1 "e 47 15 19 34 14 13 44 "i 14 20 36 12 3 41 2 13 21 38 9 10 38 3 12 22 40 7 1 85 4 11 23 42 4 7 32 5 10 24 44 1 14 29 6 9 25 45 15 4 26 7 8 26 47 12 11 23 8 7 27 49 10 1 20 9 G 28 51 7 8 17 10 5 29 53 4 15 14 11 4 30 55 O 5 11 12 3 ' 31 56 15 12 8 13 2 32 - 58 13 3 5 14 1 33 60 10 9 2 16 34 62 8 SUGAR IN SOLUTIONS OP DIFFERENT DENSITY. 233 II. Table by Dr. Evans, showing the per cent, of sugar in solutions of different degrees of density, according to the scale of Beaum^, and corresponding specific gravities. Degrees of density, Beaumg. Sugar in 100 parts. Specif, grav. Degrees of density, Beaum^. Sugar in 100 parts. Specif, gray. 1 ■018 1-007 19 •352 1^152 2 •035 1-014 20 •370 1-161 8 •052 1-022 21 •388 1-171 4 •070 1-029 22 •406 M80 5 •087 1-036 23 •424 1^190 6 •104 1-044 24 •443 1.199 7 •124 1-052 25 •462 1-210 8 •144 1-060 26 •481 1-221 9 •163 1-067 27 -500 1-231 10 •182 1-075 28 •521 1-242 11 •200 1-083 29 •541 1-252 12 •218 1-091 30 •560 1-261 13 •237 1-100 31 •580 1.275 14 •256 1-108 32 •601 1-286 15 •276 1-116 33 •622 1-298 16 •294 1-125 34 •644 1-309 17 •315 1-134 35 •666 1-321 18 •334 1143 III. Table showing how a saturated solution of sugar is affected by being reduced to different degrees of density, as indicated by the thermometer, commencing at the point of saturation. This table was prepared with great care by Dutrone from actual experiments. By means of it the number of pounds of sugar, which will crys- tallize in syrup of any given density, aa determined by its tempera- ture at the boiling point, may be accurately predicted, and the 20* 334 SOLUTIONS OP SUGAR AFFECTED BY DENSITY. number of pounds of water which it has lost by evaporation between the temperature of saturation and the given temperature. Also the number of pounds of sugar and water respectively, which remain combined in the form of syrup (drippings). At 81 -5° F. (22° Eeum. ) Dutrone found that three parts of water and five parts of sugar form a saturated solution. He formed a saturated syrup therefore consisting of 60 pounds of water and 100 pounds of sugar, and upon this the table is based. If 160 pounds of such syrup be raised from the boiling point, 219° F. to 232° F. (for example), 33 lbs. 11 oz. 10 dr. of water will have evaporated; 56 pounds of sugar will crystallize when the syrup is cooled to the proper temperature and treated in the regular manner, and 26 lbs. 4 oz. 6 dr. of water and 44 lbs of sugar still remain combined. To determine this it is necessary only to have a, thermometer which will register accurately the temperature of the boiling syrup. Degree of therm t'r, Fahrenheit. Weight of Sugar wliich separates in crystals. Weight of Water evapurated. Weight of Sugai- yet comhined with water in the state of syrup. Weight of Wa- ter still com- hined with sugar in the state of syrup. 219 221 22S 226-6 228 230 232 234-6 237 239 211 243-5 246 248 260 262-6 266 267 259 261-6 264 266 268 270-6 273 276 277 279-6 lbs. 8 19 30 41 62 66 60 63 66 69 72 75 77 80 83 86 87 88 90 91 92 94 95 97 98 99 100 oz. ...„. ...„. 4 3 2 1 "Y 6 3 ...„. 6 1 4 7 2 6 ...„. 2 dr. U,s. 4 11 18 24 31 33 36 38 39 41 43 46 46 48 60 61 52 63 64 66 65 66 57 68 68 69 60 oz. '12" 8 "9" 3 11 3 1 4 7 4 ...„. 7 1 6 1 1 3 12 7 3 6 14 7 dr. "ii" 14 16" 4 10 "io" .„„. 8 10 "ii" 6 "16" "16" 8 8 8 10 Ihs. 100 92 80 70 69 48 44 39 36 33 30 27 25 22 19 16 16 12 11 9 8 7 6 4 3 1 14 oz. 12" "ii" 12 13 14 16 ...„. 11 13 "12" 10 15 12 9 14 11 dr. lbs. 60 65 48 42 35 28 26 23 21 20 18 16 16 13 11 9 9 7 6 5 4 4 3 2 1 1 oz. ...„. 7 "T 12 4 13 16 12 8 12 ...„. 8 14 "ib" 14 15 12 4 8 12 9 1 8 dr. ""2 2 ...„. 12 6 "T "12" 8 6 ...„. 10 "e" ...„. 8 8 8 8 14 1 1 pelioot's table. 235 IV. Peliqot's table for determining the per cent, of sugars in a solution by saocharate of lime Quantity of sugar dissolv- ed m 100 parts Density of Syrup. Density of Syrup when saturated with 100 parts of residue dried at 120° (Cent.) contain— of water. lime. Lime. [ Sugar. 400 1-122 1-179 21-0 79-0 37-5 1-116 1-175 20-8 79-2 &50 1-110 1-166 20-5 ■ 79-5 ' 32-5 1-103 1-159 20-3 79-7 30-0 1096 1-148 201 79-9 27-5 1-089 1-139 19-9 80-1 25 1-082 1-128 19-8 80-2 22-5 1-075 1-116 19 3 80-7 20-0 1-068 1-104 18-8 81-2 17-6 1-060 1-092 18-7 81-3 15 1-052 1-080 18-5 81-5 12-5 1-044 1-067 18-3 81-7 10.0 1-036 1-053 18-1 81-9 7S 1-027 1-040 16-9 83-1 5-0 1018 1-026 15-3 84-7 2-5 1-009 1-014 13-8 86-2 Tables of Weights anb Measures officially recognized in the United States by recent Act of Congress. MEAStfRES OP LENGTH. Metric Denominations and Values. Equiyalents in D nominations in use. Myriameter .-. Kilometer H»-ctonieter.,.. Dekameter Meter 10,000 meters, 1,000 meters, 100 meters, 10 meters, 1 meter, -jljyth of a meter, j^jj^th of a meter, 6-2137 miles. 0-62137 mile, or 3,280 feet and 10 inches. 32S teet and one inch. 393-7 inches. 39-37 inches. 3-937 inches. 0-3937 inch. 0-0394 inch. Decimeter Centimeter.... Millimeter 236 WEIGHTS AND MEASURES. MEASURES OF SURFACE. Metric Denominations and Values. Equivalents in Denominations in use. 10,000 square meters, 100 square meters, 1 square meter, 2*471 acres. 119-6 square yards. 1550 square inches. Are MEASURES OF CAPACITY. Metric Denominations and Values. Equivalents in Denominations in use. Names. No. of liters. Cubic Measure Dry Measure. Liquid or "Wine Measure. Kiloliter ) or atere J Hectoliter... Dekaliter.... Liter 1,000 100 10 1 1-308 cubic yards.... 2 bus. & 3-35 pecks.. 9-08 quarts 264-17 gallons. 26-41T gallons. 2-6417 gallons. 1-056T quarts. 0-845 gill. 0-338 fluid oz. 0-27 fluid drm. f-jJjjth of a cubic) . i meter J 10 cubic decimeters.. 1 cubic decimeter.... f ■y'jjth of a cubic I 1 decimeter f rlO cubic centi-i X meters J 1 cubic centimeter... Deciliter Centiliter Milliliter.... 6-1022 cubic inches 0-6102 cubic inch.... 0-061 cubic inch WEIGHTS. Meteic Denominations and Values. Equivalents in Denominations IN use. Names. Number of grams. Weight of what quantity of water at maximum density. Avoirdupois Weight. Millier or tonneau 1,000,000 100,000 10,0U0 1,000 100 10 1 iV 1 cubic'meter 2204-6 pounds. 220-46 pounds. 22-046 pounds. 2-2046 pounds. 3 5274 ounces. 0-3527 ounce, 15-432 grains. 1-5432 grains.. 0-1543 grain. 0-0154 grain. Kilogram or kilo 1 liter 1 deciliter ■j^th of a cubic centimeter 10 cubic millimeters INDEX. Acid in sorghum juice, influence ofi 132, 133. how neutralized, 101-104. in syrup3, effc'Ct deconipoaition, 167. Affinities of different varieties of cane, lilt). Alirend's experiments with oats, 31. Albumen of cane juice and acid, 132. IQ delecation, 134. combined witli tannin, 137. tannin and alumina. io acid syrup, 167. Alcohol, use of, in analysis, 193. Alum, injurious effects of, 139. Alumina, gflatinous, in def.^cation, 135. objection to it removed, 135. decolorizing power of, 136, sulphate of (neutral), 13S, 139. Ammonia, effect of, as a manure, 48. incroasL's quantity of gluten, 49. as a neutral salt in juice, 49. under stimulation by, 50. when properly applied to caoe, 51. and gypsum, 60. salts and lime in juice, 133. Analysis of sorghum juice, 174. by Dr. Jackson. 174. by l*rof. Smith, 174. by Madinier, 175. by Dr. M'etbenll, 180. by Vilmoriu, 176 approximate, method of, 191, 192. Peligot's methoti, 198. accurate quantitative, 193, 195. Fresenius' mode of, 196. Ancients knew little of sugar, 15. Apparatus, ev-iporating range, etc., 97,98. Arabians carried the cane to Mesopota- mia, 16. Ash of the seed, composition of, 51. dried plant, 52. Avequin, experiments with cane mills, 127. Barna, use of, for storing cane, 172. Barn-yard manure, 49. and trash cane, 56. Barrels for syrup, how to cleanse, 230. Boaumfi's hydrometer, 19U. Beet sugar, 20. Begasse (see Cane Trash). Benjamin, exiJeiiments with mills, 127, 12S. Bisulphite of lime in Melaeu's process, 161 Blodget's Climatology, 69. Bluff soils of the West, 65. Bone-dust as manure, 57. Boneblack, condition in which to be used, 143. how prepared, 143. manner of using, 143, 144. revivificiition of. 144. new mode of revivifying, 145. properties of, 145, 146. substitutes for, 146. filtration by this mode, 141. removes all harsh flavor, 141. remuves lime, etc., 142. decoloiizes, 142. removes all suspended matter, 142. filter, how to use it, 106. Cane, hnw protected ftom frost, 171. ti'ash as manure, 53. various uses, 54. mode of converting into manure, 55. versus cotton growing in the South- west, 67. Centrifugal drainer, 122. construction of, 123. advantaa;es in using, 122. Cereal and siiccharine plants, 26. China, climate of, 214, 216. early planting in, 215. geographical range of sorghum in, 214. Chinese cane (see Sorghum). Chloride of lime and ammonia, 61. Climate of the Zulu country, 216. of N'oi thern China, 214, 216. and distribution of species, 68. subtropical summer in U. S., 68. sum mer isothe rms of 70° and 72°, 69. of sugar district of the U. S., 70. and sorghum, 23. Climatology of tropical cane, 19. Coal, bituminous, Uow used, 104, Coloring matter of juice, how removed, 137. 142. Composition of juice, 95. Cooler fur syrup, 100. Copper test, 193. Cotton, dye for. from sorghum, 225. Cream ofiime,how prepared, 214,217, 229. Crystallization of sugar, why unsuccess- ful, 111, ISO. process, how conducted, 114. precautions to be observed in, 117. impeded by presence of acid, 137. promoted by filtration, 142. what necessary to, 95. Cryst-allizing vessels. 111. (Dutrone'a boxes), 112-114. (237) 238 INDEX. Crystallizing, mode of using, 113, 114. Cultivation of sorghum, 25. adapted to waats of the plant, 25,33, wlien it should ceaae, 45. (after-cu'ture), 43. plan fur farmera, 171. Defecation, importance of, 156 and the '-striking point," 109. explanation of first method of, 134. second, 135. advantages of, 137. why neceasiu-y, 95. Density of syrup, determined by finger test, 1U8. thermometer, 108. Drainage of sui^nr, 115. theory of, 115,116. liquoring process, 116. directions for, 117. Tiisseis I sugar moulds), 116, 117. "liquor," lis. syiLip of (mol asses), 119. liquor from refined juice, 120. P.iyeu's directions in, 120, 121. by prt-ssure, 121. objections to, 121, 122. centrifugal machine, great advant- ages oi, 122. impeded by presence of acid, 133. eaily ripening conducive to, 73. good, how to secure, 42. Dutrone'a cry.stiLllizing boxes, 112-114. Dyeing materials from seed and trash 221-226. Early planting of cane in China, 215. why necessary, 34-37. and root development, 36. climatic conditions, 36. and early ripening, 37. other reasons for, 38. in CInna, 38, 215. and tillering, 44. and when to plant, 37. ripening, how secured, 71. importance of, 72. ■ and nature of the plant, 73. influence of drainage upon, 73. and selection of seed, 73. elevation of surface, 73. southerly slope, 74. course of cane rows, 74. Europe, introduction of sugar into, 16. Evaporation, how managed, 94, 102. in open air ( Payen), 150. vaciium pans, 152, by the conlmon mode, 163. how best conducted, 153. in pans with channeled surfade, 165. Evaporating range, general directions fur using, 171. Farm machinery for sugar making, 171 Fehliug's solution (test), 193. how prepared, 194, 195. how to use, 194, 195. Filter, uses of, 105. Filter, mode of using, 106. how to prepare for use, 106. Finishing pan, 92. . best form of, 148. Flour from surghum seed, 227. Food of the cane plant, 46. mineral, special functions of, 52. France, Noith of sorghum in, 175. Freezing of cane, how prevented, 88. experiment, 89. Fresenius' method of analysis, 195. Frost, effect under different cii'cum- stances, 81. upon ripe cane, 85. and fall plowing, 40. Fuel, how economized, 99, 154. Fumigation of casks, '23'). Furnace, construction of, 99, 102. Gall, Dr., method of wine making, 226. Geographical distribution of different va- rieties, 2 1 3. Gluten in the seed, 49. Grape sugar {see Sugar). Grasses, annual growth of, 31. Guano, how and when applied, 51. Guinea corn or doura, history of, 212-211 Gyp-iuni and early planting, 38. as a fertilizer, 57. Liebig'a observations upon, 60. Harrifi' experiments upon manures, 57. H.irvesting of cane, 81. Heat, action of upon siirghum juice, 147. how regulated in furnace, 147, 148. injurious when prolonged, 148. effects not always visible, 149. Soubeiran's experiments, 149. and open air evaporation, 150. imperfect defecation by alone, 163. and evaporating surfaces, 163-166. and lime, 166,167. Hue, Abbe, observations on sorghum, 24. Hydrometer, uses of, 189. Illustrations, evaporating range, IVontiS' piece. Fig. 2, 44. Fig. 3, 186. Fig. 4, 186. Fig. 5, 228. Imphee, Wray's description of, 217-222. must not remain uncut long when bhided, 82. Iron paint for tanks, etc., 99. Jackson's analysis of ash, 51, 52. Japan, sugar grown in, 214. climate of, 214. Johnson, Prof. S. W., action of gypsum, Juice of sorghum , effect of manures upon. 48. ^ ' neutral salts in, 49. influence of common salt upon, 50. of soils, 63, 64. quantity extracted by mills, 124r-138. INDEX. 239 Juice of sorghum, yield, how increased, 1-28-131. cbomic;il action of lime upon, 132. renioviil of harsh flavor from, 141. evaporation of, from utored cane, 88. deffcation of, 91. chemical conatitution of, 95. how to tpat, 184. Jnico pipe (illustrated), 228. Leaf growth and root growth, 32. expansion, period of, 36. Leaveii of cane, when to remove, 81. function of, 81, 82. valuL^ as fodder, 81. Liebig's observations upon gypsum, 60. Lime, cream of, bow to prepare, 22^, 230. application of, Wl, 104. how removed from bonebiack, 142, 146. chemical action upon the juice, 132, 134. as a fertilizer, 57. Limfistone soils, influence of, 64. Litmus paper, how naed, 101. Maceration of cane by steam and press- ure, 129. Maize, geographical range of, 69. Manufacture of sugar, 91. methods of, 155. on the farm, 169. Manures for cane, 46. nitrogenons Influetjce of, 47. on Southern cane, 50. from cane trash, 53, 55, 223. waste products, 56. Melsen's process of d<-fecation. 159-162. Meteorological spring in the Middle States, 36. Microscopic section of Chinese cane, 186. Neeazana cane, 186. Mills for crushiiig cane, 124, 171. inefficiency of, 125. results of trials (Guadaloupe), 126. (West Indies), 127. (Lnuiaiana), 127. how to remedy defects, 128-131. speed of rolls of, 128. length ofroUs of, 129. improvements in suggested, 130, with fuur rolla, etc., 129. position of the, 97. Missouri, '-volunteer cane" in, 35. "Bluff" soils of, 65-67. Molasses, what, 119. Monsoons, influence on climate of China, 215. Must, improved by addition of grape sugar, 226. Neeazana, or white imphee cane, 219. Neutralization of juice with lime, iQl. Oats, analogy to sorghum, 31-33. Ohio terrace soils, tff . Oomseeana cane, 221. Orange, Borthelot and Buignet'a experi- ments, 205. Paint for tanks, etc., 99. Paper frum cane trash, 224. Patent recipe venders, 180. Payen's di rections for draining sugar, 120. Peiigot'a method of analysis, 198. Physiology of tlie seed, 28. Planting season in China, 214, 215. Plaster of Paris !is manure, 57. Pluw, uae of double Michigan, in sod, 40, Plowing in the fill, 38. advantage of deep, 39, Poke weed in " Bluff" aoils, 66. Potash in sugar plants, 61. as manure, 57. Prince Salm Hortsmar's experiments, 52. Process of miinufacture described, 101. synopsis, 2^8. Range of sorghum northward, 69. Indian-corn, 69. Range, evaporating, deacribed, 98. Red imphee, des'ci'iptiou of, 221. Refining and evaporation, simultaneous, 105. Refining process, 92, Richardson, Sir John, disti'ibution of plants, 17. Ridging of tand in the fall, 40. and early cultivation, 43. bow performed (ill us.), 41-45. advantages of, 45. and drainagu, 42. and evaporation, 42. and aeration of soil, 42, Ripening of cane, indications of, 82. Root and stem, unequal development, 30, :n. at different stages of growth, 32. development and climate, 33. and early planting, 33. in subaoil, 64. Rotation of crops not necessary, when, 53. Saccharate of lime (test), 198. Saccharometer, what, 191. Scum, use of, for feeding swine, 227. how separated, 92. Seed of sorghum, uses of, 227. us'rd in dyeing, 224, germinates early, 36, 38. selection of, 26, qualities of good, 28. teat ot germinatiug power, 28. liquid manures for, 29. steeping of, 29. physiology of the, 28. yield of, from Si'rgbum, 82. may be inci'-eased, how, 47, ash of, analysis, 51. steeping solutions for, 73. Silk, sorghum dye for, 224 Soils, quickening powei of some, 73. Soil, value of, fui- -■'II X u- growing, 62. combinations witliin the, 62. 240 INDEX. Soil, texture, etc., of, 63. influence upon cane, diflferent kinds, 63. of calcareous soil, 64. wesiprn " lilnff," 65. natural drainage of, 66. of Ohio terraces, 67. of Nnrthcrn China, 215. the Zulu country, "216. Sorghum sugar cane, sketch of its his- tory, 20-24. south African or imphee, 20. relations to soil and climate, 23. true character, how known, 24, relaiionship to Indian-corn, 25. systematic culture uf, 26. Chinese variety, 27. imphee canea, 27. unequal development of stem and roots of, 31. howada|»ted to our climate, 31. lengtii of periods of growth of, 33. analogy of, to oats, 31-33. " volunieer," 35. peneral condition of, in 1864, 181. Ciiinese, composition of staik, 124. food of th,p plant. 46. analysis of ash of seed, 51. . ash of dried plant, 52. influence of g.vpsuin upon, 59. influence of soil upon, 63. northern range of, 69. period of growth of, 70. influence of tillering upon, 78. analogy to wheat, 79. Species, what are, 210. are Chinese and imphee of different, 211. Specific distinctions, based upon what, 212. Specific gravity bottle, 190. Stalk of cam*, hnw its bulk increased, 59. Store-houses for cane, 86-88. S^toiinp; of cane, 85. Stripping of can'e, 82. Sugar, per cent. of. in sorghum, 181. in syrups, Wetherill, 182, fruit, what, ]85. grape, what, 186. in ceils of c;inc (illustrated), 186. distinction between cane and grape in the solid form, 187. in solution, 189. estimation of, by copper test, 193, 195. how made to crystallize, 93. Peligot's method, 198. from starch. 18. in honey, 18. grape, low rank of, 18. from maizp, IS. pioduction in the U. S., 19. plants which yield, 17. making at home, 169. separation of, ]5fi. of cane, action of lime on, 133. Sugar, liquid, what, 95. grape, 133. in the plant, whence derived, 51. promotion, how retarded, 71. how graded, 116. ■white, how made, 118. moulds, 116. yield, how increased, 125. production, value of, from sorghum, 173. production, Lovering's experiments, 178. Sugar cane (tropical) and sorghum con- trasted in botanical characters, 201. period of growth, 202. propagation, mode of, 202. tillering, 203. climate, 203. soil, 203. manures, 204. matuiity of juice, 204. chemical composition, staVe, 207. juice, 2u8, history of, 16. Sugar beet, 20. Sugar cane in Louisiana, 19. maple, geographical range, 17. product of, 19. Subacetate of lead (test), 191. Sulphate of ammonia as a fertilizer, 60. Superphosphate of lime, 58. Swalhnv, G. C, Missouri Q-eol. Eept., 66. Syrupa, analyses of, 182. Tables, 232-236. Tang, how removed, 231. Tank, juice described, 98, 100. Tannic acid in defecaiion, 134. Test paper, use uf 101. Tests, quantitative, of sugais, 192. Thatching with trash, 87. Thermometer, use of, 108. Tillering and early planting, 44. opposite opinions coucerning, recon- cilpd, 75. natural to sorghum, 77-80. and deep culture, 7y. Tilt pan, how used, 1U7. Topping of cane, best mode of, 83. Under draining, 41. Vacuum pans, 152. , Vari itiou, capacitv of sorghum for, 216. Varieties, what, 211. Vinegar from sorghum, 227. Waste products, how utilized, 223. Wetherill, Dr., analysis by, 180. White imphee, 219. Wine, how improved, 226. Wray, Leonard, account of impheea, 217- 222. Zulu country ia South Africa, 216.