^.M\La \,.^)^ h€i Cornell XHniverstt^ OF THE IRew l?orh State College of Hgriculture fl^..Goai ^ji... 3778 Cornell University Library QD 561.S36 The electrical conductivity and ionizati 3 1924 003 014 242 Cornell University Library The original of tiiis book is in tine Cornell University Library. There are no known copyright restrictions in the United States on the use of the text. http://www.archive.org/details/cu31924003014242 THE ELECTRICAL CONDUCTIVITY AND IONIZATION CONSTANTS OF ORGANIC COMPOUNDS THE ELECTRICAL CONDUCTIVITY AND IONIZATION CONSTANTS OF ORGANIC COMPOUNDS A bibliography of the periodical literature from 1889 to 1910 inclusive, including all important work before 1889 and corrected to the beginning of 1913. Giving numerical data for the ioniza- tion constants at all temperatures at which they have been measured ; and some numerical data of the electrical conductivity BY HEYWARD SCUDDER, B.A., B.S., M.D. Member of the Americcm Chemical Society, the American Electrochemical Society, etc. NEW YORK D. VAN NOStRAND COMPANY Twenty-five Pakk Place 1914 Copyright, 1914, By Heyward Sctjdder THE UNIVERSITY PUKSS, CAMBRIDQE, U.S.A. CONTENTS. Faoh Explanation 5 Abbreviations of Words . . 28 Abbreviations op Journal Titles 31 Cyclic Formulae 36 Tables 41 Compounds arranged Alphabetically, with the Ionization Con- stant, some Data of Conductivity, and ^ all Bibliographical References given under each Compound. Formula Index 323 Author List 390 Bibliography of Authors' Names arranged Alphabetically. Subject Index 540 Journal List 656 Names of Journals arranged Alphabetically. Addenda 567 ERRATA Page 52. /iscudo-Acetylpyrrolecarboxylic acid. Change the cross reference to 2-Methylpyrrylketone-5-carboxylic acid. Page 54. Adipic acid; line 7. Close the parenthesis after (1024 . Page 59. p-Aminobenzoic acid ethyl ester. There should be no period between the end of the first formula and the equality sign. Page 89. Butyl cyanide. The cross reference should begin with a capital V. Page 108. Cobalt. Add 1126 at the end of hne 7. Page 150. Dithiolcarboxyacetic acid. The cross reference should read Dithio-carbondiglycoUic acid. Page 167. Gliadin. Insert 145b before 2005. Page 170. Guanidine. The reference number is 1775, not 1175. Page 200. 2-Methoxy-3,5-dichloro-benzoic acid. The synonym in parentheses should read Methyl-dichloro-salicylic acid. Page 239. p-OrseUic acid. The synonym in parentheses should read p-, not p. . Oxaldihydroxamic acid; last line. The number 756 should be in bold-face type, as a reference number. Page 246. Phenaceturic acid. The synonym in parentheses should read Phenylaceturic acid. Page 257. Phosphorus; middle of line 6 should read sulphide, not oxide. Page 261. Platinum; last line. Insert 1417 before 1466. Page 285. Tellurium; line 2. The first word should read hydroxide, not chloride. Page 360. C8H10ON2. There should be a hyphen in the first name, between N and phenyl. Page 429. 557. The date should read 1890, not 1980. Page 530. 1915 ; last line. The bracket should be closed after 1929. Note. The cross references for substituted amides on pages 74, 79, 92, 132, 192 and 319 lead to the unsubstituted amide. Following this will be found the substituted amides. EXPLANATION. INTRODUCTORY. THE object of this book is to present, as far as lies in my power, a bibliography of all the measurements of the ionization con- stants and the electrical conductivity of organic compounds that have appeared in the periodical literature between the years 1889 and 1910 inclusive, together with the values of the ionization constants, and certain values of the electrical conductivity measure- ments. Qualitative work is also included. Before the year 1889, little work of value at the present time was published. All that is of value is included here. From 1910 to the beginning of 1913, im- portant corrections that have come to my notice have been inserted. Beginning with 1910, full data of the entire periodical literature are published in the Tables Annuelles Internationales de Constantes et Donn^es Num^riques. Exceptions. The references to subjects chiefly of biological in- terest, as albumin, blood, sap, etc., are complete only for the last few years (roughly the last five or ten), but afford a means both of knowing where to get at the important work, which is all recent, and where to start in any more thorough search of the literature. The references to the resistance of substances such as rubber, wood, etc., have not been looked up. They are of value almost exclu- sively in connection with the question of electrical insulation. A few are given. There is a biological interest in some cases. The fact that the references to the literature of any compound or substance are not complete, is stated in the tables immediately after the name. References to the conductivity of inorganic compounds in organic solvents have not been looked up specially, though in cases where salt formation is to be expected they have been taken. When given, they will be found under the head of miscellaneous measurements, either separately from the references to organic compounds, or dis- tinguished from them by being placed in parenthesis. A few pages farther on, in the detailed description of miscellaneous measure- ments, will be given certain considerations of the question of com- bination of solvent and solute in making new compounds. 6 EXPLANATION Additions. In the author list are given some artioles which con- tain only measurements of inorganic compounds, or matter which is theoretical. Such references are inclosed in parenthesis to dis- tinguish them, both in the author list and wherever else they may be used. The object of including them is to save time to persons who are interested only in original measurements of organic com- pounds. Experimental work in connection with theoretical con- siderations of dissociation and of electrical conductivity is almost invariably first carried on with inorganic compounds. Later work often refers to organic compounds for the sake of analogy, clearness or additional proof. In consequence of this, references are often met with, which are apparently to original work on organic compounds, when as a matter of fact the original article contains only quotations of experimental work on organic compounds, while the new experi- mental work is entirely on inorganic compounds. In the case of work on the conductivity of molten salts, which is quite recent, I have inserted a number of references to work on in- organic compounds, because experience has shown that these articles wiU be referred to, as soon as similar work on organic compounds be- comes common. In the tables, a number of references are given to work on the comparative strength of different compounds (measured in various ways), because to many chemists the chief value of the ionization constant of a compound, or of a measurement of its electrical con- ductivity, is to determine its strength as an acid or a base. When no quantitative data are available, 'qualitative data may be quite use- ful. Negative results, as the fact that a compound has no appreciable conductivity in hydrochloric acid, may be of use in determining the nature of a compound or as a guide for subsequent investigation. The statements in the tables always indicate when the work is of a qualitative nature, or when negative results have been obtained. A few measurements of inorganic compounds have been inserted for purposes of comparison. Method of search of the literature. Seventy-eight of the journals and about five thousand dissertations have been examined page by page; the other journals have been examined by index and table of contents, with page by page examination of articles that might con- tain information. The titles of articles usually give no indications of value, so omissions are to be expected. The omissions are most likely to occur in the case of measurements of the conductivity of salts, since these are frequently inserted very briefly, with no special mention of them in the text. EXPLANATION ARRANGEMENT. The book is divided into a set of tables arranged according to the names of the compounds, containing all the data that may be given, with a bibliography of all the references to each compound; a form- ula index to the compounds; a bibliography arranged according to the names of authors; a subject index to certain subjects; and a journal list giving the names of all journals examined with the number and date of the last volume examined. Order. Alphabetical order is used as a rule, but where the numeri- cal order is more natural (as in the case of mono- and di-, etc. com- pounds) that is used. With a few exceptions, due chiefly to recent practice, and the necessity of selecting a definite form or name in cases of dispute, Beilstein's Organische Chemie (3d edition), Richter's Lexikon der Kohlenstoff-Verbindungen and the International Cata- logue of Scientific Literature, have been used as guides and authori- ties. While I do not approve of a number of details in any one of these publications, it is obvious that if there is no yielding of personal prejudice all attempts at general uniformity will fail. Some incon- sistencies in names and formulae are due to the fact that no one authority can be followed throughout. In cases where more recent work has decided the composition or structure of a compound, such work has been accepted. It must always be remembered that the latest work on any subject is not necessarily the best, even when the newest theories and apparatus have been used. DETAILED DESCRIPTION OF THE DIVISIONS. TABLES. AiraBgement of the Compounds. While the arrangement of the compounds in the tables is alpha- betical, in order to bring together certain closely related compounds some exceptions are necessary, which are chiefly the use of customary names of isomers and of positions. Ortho-, meta- and para- com- pounds are placed in the usual order. Iso-, alio-, etc. compounds are placed after the normal compound, the prefixes (which are in italics) not being considered at all. The numerical order is followed in the case of mono-, di-, etc., derivatives of polybasic com- pounds. Immediately after each acid are given the amides, the anhydride and then the esters. On account of the small number of 8 EXPLANATION compounds and the system of nomenclature used, there is little actual displacement due to these exceptions. Thus, iso-butyl alcohol comes immediately after wor-TO.-butyl alcohol, while iso-butyric acid follows butyric acid, but on account of the intervention of the butyric acid amides and esters it comes immediately after butyric acid propyl ester. The few other exceptions will be found by means of the cross references. In the case of the substituted amides there is an im- portant exception discovered too late for correction. When an anilino or toluidino radical is substituted for a hydrogen atom in the NH2 group, the compound is not mentioned at all under the head of the amides. Thus, acetanilide is not mentioned as acetic acid phenyl amide, nor is oxanilic acid mentioned as oxalic acid mono phenyl mono amide. Nomenclature. When an alphabetical arrangement is used, the place of any com- pound will vary according to the judgment used in the selection of the name, as in the case of methoxy-benzoic acid instead of hydroxy- benzoic acid methyl ether, and also according to the way in which a compound is regarded, as in the case of oxanilic acid which may be regarded as an amide. In the tables, when the choice lies between a common name and a systematic name, as gallic acid or trihydroxy-benzoic acid, most compounds with very familiar names are given under the common name, since few chemists except those working with organic com- pounds are able to remember the structure of the higher organic compounds. This use of common names has the disadvantage of separating isomers. The use of systematic names has two chief disadvantages. It requires a knowledge of structure. Apart from the dilEculty of remembering the structure of a number of com- pounds, our ideas of structure are constantly changing with increased knowledge. In the second place, there is no fixed use of systematic names. On the other hand, any consistent use of systematic names will bring together isomers, and sometimes closely related compounds; and the name will furnish some knowledge of the structure. Cross references are in general given only to the parent compound and not to the substituted compound. Thus, nitroterephthalic acid is not given (though a nitro-p-phthalic acid is in the tables), because under terephthalic acid is given the cross reference to p-phthalic acid. The formula index shows at once the name used in the tables. The names and the formulae of dyes are given as accurately as is possible under the circumstances, but any information concerning them must be used with caution. In most articles, on account of EXPLANATION 9 the totally inadequate description given, and the ambiguous use of words, it is impossible to tell exactly what compound was used for measurement. Most commercial dyes are mixtures of compounds. If we assume that for any measurement the chief constituent of such a mixture has been isolated and purified, and is called in the article the pure dye, the structure may be in doubt, since different makers give the same name to dyes of different structure. Then in the case of the greater number of dyes, which are salts, it is quite impossible to tell which salt was the dye in question. There is some difference between the conductivity of a sodium and a potassium salt, or be- tween that of a hydrochloride, a sulphate and an acetate; yet as a rule, the descriptions do not state the particular salt which was used. In most cases, the statement that the pure dye base was used is mis- leading, for the statement really means that a salt of one compound was used, and not the salts of several compounds mixed — though as just mentioned, it is usually impossible to tell what the salt was. The same confusion of terms also exists in reference to the acid or base of a dye, here again a salt really being meant, and not an acid or a base. Hyphens and spaces are used to indicate particular groups, to avoid as far as possible the necessity of referring to the formulae. Numbers, letters and abbreviations used to indicate position are placed directly in front of the group or element which they affect. In a few cases, the termination of the name shows the character of the group, as " one " for the keto group in pyrazolone. In these cases the number follows in parenthesis. In the numbering of substituted cyclic compounds, the first sub- stituted group is always given the number one. Thus, in the sub- stituted benzoic acids, the carboxyl group is one; in the substituted anilines the amino group is one. In the toluic acids, the methyl group is one; but if they were regarded as methyl benzoic acids (derivatives of benzoic acid), the carboxyl group would be number one, and the number of the methyl group would vary according to the acid. The abbreviations C, N and (used instead of numbers) show that the substituting group is attached to the corresponding carbon, nitrogen or oxygen atom. Bz, shows substitution in the benzene ring; Py, in the pyridine ring. Carboxylic, in the name of an acid, shows the group COOH. For ambiguities in the use of the word hydro, see the following paragraph. The word nor, as in noropianic acid, shows that there is an unsubstituted compound, of which the substituted derivative (including esters and ethers as substituted compounds for the purpose of the present definition) has first been known, and named by the name which would naturally belong to 10 EXPLANATION the unsubstituted compound. In this case, opianic acid is the dime- thoxy acid, noropianic acid is the dihydroxy acid. The word oxy means only oxygen, hydroxy being used to show the hydroxy! group OH. The word sulphinic shows the group HSO2. The word sulpho (as in sulphobenzoic acid) or sulphonic, shows the group HSO3. The word sulphone, as in sulphonediacetic acid, shows the group SO2. Differences in nomenclature causing confusion. In comparing the name of a compound described in an article in a journal, with the name used in other articles, or in standard works as those of Beil- stein and of Richter, or with the name in these tables, a number of differences in usage will be found, which may lead to error. It seems advisable to explain a few of the most common of these, which have caused a number of mistakes. In the case of compounds containing sulphur, there is so much variation in nomenclature, that the formula should always be ex- amined. Most chemists use sulphinic, sulpho, sulphone and sul- phonic, in the manner described in the preceding paragraph as used in these tables. The word thio, is used to show the replacement of any element by sulphur, or in making a name for a sulphur compound which is analogous to any non-sulphur compound. Thus, a thio- acetic acid may be CH3.COSH, or CH3.CSSH, or CHS.COOH. There is much ambiguity in naming compounds containing a sub- stituting group. Methyl-salicylic acid may mean methoxy-benzoic acid, or it may mean hydroxy-toluic acid, depending on whether substitution is in the hydroxyl group or in the benzene ring. Cyano- acetamide may mean cyanoacetic acid amide, or acetic acid cyanoa- mide. It is sometimes impossible to tell what compound is meant in cases such as these, unless the context supplies some means of identi- fication. There is a certain amount of error in statements concern- ing the measurements of organic acids by Ostwald, published in 1889 (less than twenty-five years ago), simply from this sort of confusion of names. There is the same possibility of confusion, when the place of the substituting group is indicated in the name by a number or a letter. Thus, acridine in Beilstein has the nitrogen numbered 10, placed between carbons numbered 4 and 5. In Richter's Lexikon the nitrogen is also numbered 10, but is placed between carbons numbered 1 and 9. In journal articles the starting point of the numbering varies, and the direction of the numbering, as in the direction of the hands of a watch or the reverse. This last variation of direction while of minor importance, is apt to create confusion when isomers which are mirror images are concerned. The word " hydro " is used in a most confusing manner. Thus, pyrrole is CiHsN. Tetrahydro-pyrrole (pyrrolidine) is naturally EXPLANATION 11 C4H9N; yet it may be called hydro-pyrrole. In the same way in the case of other compounds, the dihydro- or hexahydro- compound of one man will be the hydro- compound of another. Furthermore, when substituting groups are present, the word hydro may be used to show the theoretical addition of hydrogen with subsequent sub- stitution of two atoms of hydrogen at that point. Thus, imideazole is C3H4N2. Parabanic acid, C3H2O3N2, is called triketo-tetrahydro- imideazole, though only two hydrogen atoms are present. In this case, four hydrogen atoms are supposed to be added; then, in the three CH2 groups, hydrogen is replaced by oxygen giving three CO or keto groups, leaving the fourth hydrogen attached to a nitrogen atom. This use of hydro is of convenience when type formulae are used, instead of printing formulae in the text, and is employed in Richter's Lexikon. Details of the arrangement under each compound. In order to aid identification or to show the purity of a compound for which any numerical data are given, the melting-point or boiling- point is given in the tables when it is stated in an article. This melting-point or boiling-point refers to the sample measured, and not necessarily to the most highly purified sample described in the article. In some cases the melting-point or boiling-point of a deri- vative (as a salt) may be given, when the article does not furnish such data for the pure compound. The position of these identifying data is directly after the ionization constant, or after the measure- ment of the conductivity. In many cases, where the original sup- plies no such data, I have looked up the mode of preparation, in order to make sure what the compound is. There is a good deal of reason- able doubt as to the position of substituted groups in a number of compounds, for instance in the toluidine sulphonic acids. Immediately after the name, are given (in parenthesis) the syno- nyms. These are inserted in some cases only for convenience in referring to the original articles, since the names used there have been abandoned. After the synonyms, comes the empirical formula, and when convenient the extended formula. Cyclic formulae are given only in the grouping on the pages directly in front of the tables. The extended formulae are intended to be of assistance, but not to represent the definitive structure, nor to exclude the possibility of tautomeric forms, floating double bonds, etc. The bibliographical references for each compound are arranged under definite headings which are not specifically named in the text. These headings are; (1) the specific conductivity of the pure com- pound; (2) the ionization constant; (3) the conductivity in aqueous 12 EXPLANATION solution; (4) the conductivity in solvents other than water; (5) mis- cellaneous measurements, as the conductivity of mixtures with other compounds, conductivity under varying pressure, etc.; (6) the con- ductivity of the salts. In general, a reference with no explanation is either to the conduc- tivity in aqueous solution, or to the measurement of. the ionization constant. With the exception of old values of specific conductivity, which have been changed to make them correspond to the modern values, all data are given in the tables as in the original articles, rounding off decimals to tenths — a change that is actually of slight importance, since few of the measurements justify the use of the hundredths place. Values given in Siemens or mercury unit * have not been calculated to the corresponding values in reciprocal ohms for reasons which will be given later. Under each heading are given all the references in the bibliography bearing on that subject. These references are given as numbers in bold face type, corresponding to the numbers in the author list. Duplicate references, that is, references to publication of the same measurement in more than one journal, are not given in the tables. They may be found by means of the author list, in which all such duplications are given, the fact being noted after the title of the article. Thus, under the heading of the ionization constant of butyric acid at 25°, is given number 180. The author list shows that this is an article by Billitzer in the Monatshefte fur Chemie. After the title is the statement in brackets, " [same as 183] ", showing that the same measurement will be found in 183, which is an article published in the Sitzungsberichte der kaiserlichen Akademie der Wissenschaften (Wien). Either article gives the original measurement. In these cases of duplication, the reference number used in the tables is to the article in the most readily accessible journal. While as far as possible, no references to repetitions of the same measurement in different articles are given in the tables, it is impos- sible to avoid this altogether. Some of the measurements, in an article containing a number of measurements, may have been made by a person whose name is not mentioned. This person may after- ward publish these measurements in an article under his own name, with no mention of the fact that they have already appeared in print. Such cases have come to my notice. References to new measure- ments of the same compound or to measurements of different prepa- rations of the same compound, by the same observer, are given be- cause they tend to establish the accuracy of the first value. * The customary usage of regarding this as a unit of conductivity is fol- lowed, instead of speaking of it as the reciprocal of the unit of resistance. EXPLANATION 13 When there is any advantage in one article, either from its greater accuracy, or from its more extended measurements, that reference number is placed first. In other cases the reference numbers are given in numerical order, though of course the number of an article from which any data are taken is placed directly after such data, followed by the numbers of the other articles. If the ionization constants or conductivity measurements in two articles are widely different, both are usually given, placing first the more rehable, and stating any possible explanation of such difference. But if the data in one article are evidently inaccurate, they are not given, though the reference number of that article is given. When there may be doubt from the name alone, what compound is referred to, greater weight is usually given to articles containing some means of determin- ing what compound was really measured, and how pure it was. In the case of isomers, when no identifying statements, such as melting- point, mode of preparation, etc., are made in an article, I have assumed that the most easily prepared or procured isomer was used. For all statements enclosed in brackets, I am responsible. Detailed description of the headings under each compound. 1. Specific conductivity. As is customary, the old values are mul- tiplied by 10^ to make them comparable to the modern. The generalization that the specific conductivity of a compound is a safe guide to its purity (the purest sample having the lowest conductivity), is incorrect. It seems probable that the character of the impurity has a considerable influence, and that the closer it is in structure to the compound to be purified, the more difficult it is to detect very small amounts by the fall in conductivity. It is also probable that there is some actual effect of solute on solvent in many cases. Turner 1766, finds that conductivity alone is not a sure indica- tion of the amount of water in ethyl alcohol containing very small amounts of water. Foussereau 597, and Walden 1843, 1844, hold to the opposite view. Dutoit, Rappeport 491, find that the conductivity gives no absolute indication of the presence of very small amounts of impurity. See also 456, 1223, 1388 and 1389 in this connection. 2. Ionization constant. The ionization constant, k, is calculated (a)^ from electrical conductivity measurements by the formula k = . (l-a)v In this, V is the volume in liters in which is dissolved one equivalent weight in grams of the compound, and a, is the degree of dissociation measured by . Text books must be consulted for a treatment A(oo) 14. EXPLANATION of the inaccuracy of this formula in the case of bases, stronger acids, and polybasic acids in which the influence of the second hydrogen ion is felt at moderate dilutions; and also for the calculation of the con- stant by other means, as the hydrolysis of salts, etc. See also the Subject Index under the headings, Dilution Law, and Ionization Constant, for articles on the subject. The earlier authors follow Ostwald in expressing the value in decimals, and using a constant one hundred times k = K, to avoid unnecessary ciphers. In the tables the true constant k is used, expressed in powers of 10; thus, for acetic acid at 25°, k XlO^ =1.86. It is given for each temperature at which it was measured, with an abbreviated explanation of the method used for its determination, if this was not by the direct measurement of the electrical conduc- tivity of an aqueous solution of an acid or a base. When the value is greater than 10^, the value found by direct measurement of the electrical conductivity is generally chosen. When it is less than 10^, a value determined in some other way, by hydrolysis, etc., is given when possible; though in certain cases the value found by electrical conductivity is also given for the purpose of comparison with similar compounds, for which no method of measurement other than the electrical has been used. In the case of measurements by the conductivity method, the fact that the specific conductivity of the water of solution has not been subtracted in calculating the value of the constant is noted by the abbreviation aq., placed directly after the value of the constant, thus, l.Saq. The difference between the value corrected and uncor- rected, as a rule is less than five per cent, but may be sufficiently great to account for discordant results obtained by different persons. The statement that the value of the constant increases or dimin- ishes on dilution, is given for the purpose of attracting attention to the fact, since it may indicate the change from one isomer to another, or the presence of impurity. The cause of such variation is not always known. The assumption that a constant value not affected by dilu- tion is a criterion of purity, and that a steady diminution is always an indication of impurity, was first made by Ostwald 1371, who in the same series of articles rejects this criterion when it affects un- favorably the position of an acid in a series. Since that time classes of acids have been found, as the alkyl succinic acids, in which there is always a diminution in value on dilution. Noyes 1342 in the case of a regular diminution in the value of the constant of o-nitrobenzoic acid of great purity, states that this diminution means nothing of great consequence. See also 515 and 2018. For a detailed treat- ment see 1609. If the value of the constant is determined by conductivity measure- EXPLANATION 15 ments, and there is an increase or diminution in the value on dilu- tion, the particular value chosen depends on the structure of the compound. In the case of a diminution in the value, the value at a dilution of about 32 liters is taken when possible, as being fairly accurate and affording a standard value for that compound com- parable with the greatest number of other compounds. If the value increases on dilution, in the case of the stronger amphoteric electro- lytes the value at a dilution of about 1024 liters is taken. This value is selected, because in a number of cases, as for instance the amino- benzoic acids, it corresponds fairly well with the value obtained by other methods. If the compound is a polybasic acid, the value for a lower dilution is chosen, when the influence of the second and third carboxyl groups is evident. In other cases, it has been impossible to follow any definite rules. The ionization constant for the second and third hydrogen and hydroxyl ions is also given, with an indication of the method by which it has been determined. In comparing the valiies of the ionization constant obtained by two different persons, certain general considerations have to be taken into account, as the purity of the compound (and sometimes its identity), the method employed and whether the value chosen as the best, is a mean value, or is extrapolated or otherwise derived from the measurements. If the method is that of the electrical conductivity, three factors must be especially considered; the temperature; the specific conductivity of the water (or other solvent); and the value used for A(oo). The temperature of the measurement is usually given, since its importance in chemical work has been recognized for such a long time. The ionization constant of most organic acids and bases increases with the temperature up to about 40° to 50°, and then diminishes as the temperature is raised still higher. See acetic acid for an illustration of this, and 1332 and 1341 for measurements cov- ering a wide range of temperature. When no temperature is stated in an article, it is safe to assume that it was either 18° or 25°, except for compounds like the diazo compounds which decompose readily at ordinary temperatures. The value of the specific conductivity of the water of solution gives an indication of it3 purity. The purification to water having a specific conductivity of 2 to 3 X lO"' at 25° is so easy, that for a number of years, measurements have been made with water at least as pure as that. The question of whether this conductivity is to be subtracted in whole or in part or not at all, is still a matter of dispute, the cor- rection made varying with the individual opinion. The difference made by this correction may be of some importance; thus in the case 16 EXPLANATION of a--iso-phenylacetic acid at 25°, the ionization constant (multiplied by 10^) is 3.76 with no correction, but is 3.67 when corrected for the conductivity of the water. This water had a specific conductivity of 1.4x10"' at 25°. See 1533 for the details of this measurement. The value used for A(oo) depends chiefly on the unit of conduc- tivity, and on the values used for the equivalent conductivity of the hydrogen and hydroxyl ions; to a much less degree, on whether it is calculated from the measurements made, or is taken from a set of tables. For almost all measurements made before the year 1898, the Siemens unit was used. Since that time, either this unit or the reciprocal of the ohm then proposed by Kohlrausch is used, the tendency being more and more to use the reciprocal ohm. For acetic acid, at 25°, the value of A(oo) is about 364 in Siemens unit, and 388 in reciprocal ohms, the mean factor for the conversion to reciprocal ohms being 1.066. The error of using one unit for the other is rarely made. It is due to the false assumption that all values for the specific and molar conductivity published in the last ten years, are in reciprocal ohms. The value for the molar conductivity (really in Siemens unit) will be taken from some article, the value for A(oo) in reciprocal ohms wiU be taken from a table, and the ionization con- stant calculated from this mixture will naturally differ from any that has been known before. The value for the equivalent conductivity of the hydrogen ion is not yet settled, there being a difference of about six per cent between the extreme values given for 25°, that is 340 and 365 in reciprocal ohms. There seems to be no doubt at the present time, that this value varies with the concentration; and it is possible that other factors may also influence it. See Kendall, Jour. Chem. Soc. 101, 1275, (1912), for a review of the subject with new data, and Lewis, Jour. Am. Chem. Soc. 34, 1631, (1912), for certain theoretical con- siderations. The value for A(oo ) of acetic acid at 25°, will vary from 381 to 408, in reciprocal ohms, depending on the value used for the hydrogen ion. Taking the molar conductivity at a dilution of 32 liters as 9.2, this gives the ionization constant (multiplied by 10^) as 1.86 in one case, 1.64 in the other. A difference as great as this is often used as a basis for showing that a compound has a particular structure, or is a new compound. Up to the year 1910, practically all the organic acids have had their ionization constants calculated with a value of A(oo) in which the equivalent conductivity of hy- drogen is from 345 to 348, occasionally a little higher, but in no case high enough to make such a difference from other measurements, as has just been shown possible. But the use of this much higher value for the hydrogen ion is becoming more common, and may lead to some mistakes. EXPLANATION 17 In the case of bases, the equivalent conductivity of the hydroxyl ion, makes a corresponding difference. But there have been practi- cally no changes made in it by new measurements, since the year 1894. It is to be noted that Bredig 271, used an older value in calculating the ionization constants of the bases published by him in that year, and stated that with the present value the ionization constants are about sixteen per cent too high. In the tables they are given in their uncorrected form, with a statement of the correction. In Kohlrausch and Holborn's Leitvermogen der Elektrolyte, they are given uncor- rected, though the values of the conductivity are calculated from the original form to reciprocal ohms. The values of A(oo) calculated from measurements of the salts of acids, made at the same time and under the same conditions as the measurements of the acids, do not vary enough from the values pub- lished in the tables of Ostwald, and of Lund6n* to cause any trouble. They ought to be more accurate for their purpose, than the table values. See White and Jones 1968a, for an illustration. In determining the ionization constant by methods other than the direct measurement of electrical conductivity, the value used for the ionization constant of water often enters into the calculation. The value most frequently used is the old one for 26°, k^ = 1.2x10""- If a measurement is made at 25°, the error from the use of this value is small, but the farther the temperature departs from 25° the greater is the error. At 0°, the constant of water is about 0.1 instead of 1.2, so that the substitution of this higher value in the equation k =— ^, X where x is the hydrolysis constant, will give a value for the ionization constant which is about ten times too large. Calculation of the ionization constant by factors for various groups and for different positions of the same group, gives results that are not reliable. In some cases, the agreement is good, in others bad. There is not yet sufficient knowledge to make such a calculation of much value except where the constants of closely related compounds are known. 3. Conductivity in water. As a rule the only data given under this head are the values for the molar conductivity at 25°, for dilutions of 32 and 1024 liters (or as close to these dilutions as possible) and the value at infinite dilution. Occasionally the values for the cor- responding dilutions at 0° are also given. In the case of the more important compounds, the references are arranged according to * Lund^n 1143 and Affinitatamessungen an schwachen Sauren und Basen, gives a table of the values of A( oo ) calculated for acids containing from twelve to thirty atoms, at temperatures from 0° to 50°. 18 EXPLANATION temperature. When only one measurement of a compound has been made and the ionization constant determined from this, the tempera- ture is given only under the head of the ionization constant, unless there is some intervening statement, such as the ionization constant of the second hydrogen ion. If all the references to the conductivity are desired, it is advisable to look up those given under the ioniza- tion constant as determined by the measurement of conductivity, as well as those given under this heading, though in general such references are given under both headings. The values given for the molar conductivity are not reduced to a common unit, nor corrected for the specific conductivity of the water used, because in many articles there is a lack of data for making such reductions. Experience shows that when corrections are made in some cases and not in others, persons using a set of tables will as- sume that the correction is always made and that the values are com- parable. Reference to the author list (which is necessary to find out the name of the person corresponding to the key number) shows at once whether an accurate comparison can be made with the values of other compounds. In articles published up to the year 1898, it is safe to assume that the unit is the Siemens unit. The factor to con- vert this into the reciprocal ohm varies from 1.063 to 1.069 for most measurements, the mean value 1.066 being sufficiently accurate for most purposes. For details see Kohlrausch, Holborn, Diesselhorst 1002, or Kohlrausch and Holborn, Leitvermogen der Elektrolyte. A few of the old measurements made in a special unit have been cal- culated to Siemens units when given in the tables, and a note of this change made both in the tables and in the author list. When the author list does not show the unit of measurement, it can often be found if a value of A(oo ) is given for an acid, by comparing this value to that of other acids, or with the values in tables. A comparison of the value of the conductivity at a given dilution with that (in a known unit) of some similar compound at the same dilution is useful. But it may be quite misleading, unless the compounds are near each other in an homologous series. 4. Conductivity in solvents other than water. No numerical data are given. The references to inorganic solvents are given first, then to organic solvents. No distinction is made between pure solvents and solvents diluted with water. Reference to the subject index in which such a distinction is made, will usually settle this point. When alcohols are used as solvents, many measurements often cover the entire range from the pure solvent to very high dilutions or to pure water. A number of researches of a qualitative nature have been made with these solvents, especially with the inorganic solvents. The results EXPLANATION 19 of such researches are expressed in the tables with a qualifying clause to show that they are not quantitative, thus, " In ethyl alcohol, small cond." When, for any solvent, quantitative as well as qualitative measurements have been made, the references to the quantitative work are always given first, then the references to the qualitative work prefixed by the qualifying clause to show their nature. 5. Miscellaneous measurements. Under this heading are given references to a variety of measurements, most of them to the con- ductivity of the compound in solutions containing other compounds. In consequence, the heading in the tables usually begins, " Cond. with". These measurements of mixtures have been made for a great variety of purposes and can not conveniently be subdivided in any brief way. For instance, under acetic acid they are divided into conductivity with inorganic compounds — acids, bases and salts ; and with organic compounds — acids, bases, salts and other compounds. In the case of an acid, the measurement of the conductivity with a base may be made to show the number of carboxyl groups, or to show the effect of the presence of small or large amounts of the salt of the acid, or whether any salt formation actually occurs. If the measurement is of a solution to which an alcohol is added, the object may be to show the effect of adding a non-electrolyte, or to show if any esterification occurs. In other cases, as of a phenol in a solution containing iodine, the measurement may show that oxidation or substitution occurs. These cases of mixtures of compounds can not strictly be separated from the cases of a compound in a dilute aqueous solution of a non- aqueous solvent, though in practice such a distinction is usually made. The references to the conductivity of mixtures of organic compounds are usually given under all the compounds in question. The references to the compound as solvent, are to the conductivity of the compounds dissolved in it, or to complexes that may form. Thus, under acetic acid, the first reference to the acid as solvent gives the conductivity of sodium acetate in the pure acid, and in aqueous solutions of various strengths. The same reference is also to be found under the sub-heading of conductivity with organic salts. The references to the conductivity of compounds as solvents, are not complete for the cases when an inorganic compound is the solute. The nature of the other miscellaneous measurements is obvious from the brief explanation, as, " under pressure," etc. 6. Salts. These are arranged, first as inorganic salts, then as or- ganic, in alphabetical order. The data given, when possible, are the molar conductivity at 25°, for dilutions of 32 and 1024 liters, of the sodium (or potassium) salts of acids, and the hydrochlorides of bases. This selection is made, 20 EXPLANATION because these salts are most often made, and the conductivity of their solutions measured, and these dilutions are used to determine the basicity of acids. In a number of cases, the only data of a con- ductivity measurement given in the original article is the.difference between the conductivity at 1024 and 32 liters. In the case of very readily hydrolyzed salts, when the measurement is also made with repression of hydrolysis by excess of acid or base, this measurement is also given. The number of radicals in the salt is indicated by the figure pre- fixed. Under oxalic acid, for instance, Na.A is the mono-sodium or acid salt, while 2Na.A is the di-sodium salt. Under acetic acid, Ca.2A, is the calcium salt, requiring two acid radicals. FORMULA INDEX. This is arranged in the customary manner. For each compound is given only the name used in the tables, the synonyms being given in the tables. A number of salts are inserted for convenience, especi- ally when the acid or base has not been made, or isolated in pure form. In general, salts are to be found by looking up the acid or base from which they are derived. AUTHOR LIST. The names of the authors are arranged alphabetically. Prefixes not beginning with a capital letter, as de and von, are not considered in the arrangement. A few errors may be present, on account of the apparent indifference of some persons as to the initials which belong to their names. The English names beginning with Mac and Mc are sometimes quoted in foreign literature without the prefix, thus. Coy instead of McCoy. . Each name is preceded by a number which is used throtighout the book for all reference to that particular article. After the name, is given the abbreviation of the journal title, the series number in parenthesis, the volume number, page number and date. Then follows the name of any person who is said to have made a measure- ment described in the article, thus, 11 . . . (1898). Meas. E. Cohen. A cross reference is given from the name of the individual making the measurement; thus, under the letter C, is Meas. E. Cohen, see 11. If only a part of the measurements were made by a person other than the author, the name is preceded by the sign ^ , thus Meas. Smith. The name of the measurer is so often given with scrupulous accuracy in the literature, that it has been necessary to burden the bibliog- raphy in this way in order to make known that such measurements EXPLANATION 21 were not overlooked. On the other hand, there are many cases in which there is no doubt that the author did not make the measure- ments, but there is no way of finding out who did make them. When an author has published articles in different journals, the journals are arranged in alphabetical order in two divisions, giving first the more accessible. Under each journal, the articles are ar- ranged chronologically. For an illustration, see the references to J. Walker. The title of the article is given in full, translated into English in the case of titles in Russian. If the same article, or a summary is printed in some other journal, the full title is not repeated, only enough being given to indicate that it is the same as in the first reference. Articles in parenthesis contain no original measurements of the ionization constant or of the electrical conductivity of organic com- pounds. In brackets immediately after the title, is given information as to whether the numerical data in the article are republished in some other journal. Such statements do not refer to the text. The un- qualified statement, " same as ", indicates that the numerical data are the same in both articles. The unqualified statement, " given in ", indicates that there are additional numerical data, or additional compounds measured, in the article referred to. When it does not take too much space, the difference between the two articles is stated in the bracket. The most common difference is that one will give only the ionization constant, while the other will give full details of the measurement from which the constant was calculated, with tables of the conductivity at different dilutions, in the case of con- ductivity measurements. This difference is always noted in the bracket, by some such statement as, " k, but not A is given in ". Information of other kinds is also given in brackets, as to whether an article contains only qualitative work, etc. In a certain number of cases, it is impossible to tell whether the same numerical data have been republished in different articles or whether new measurements of the same compounds have been made. Some duplications un- doubtedly have been given in the tables on this account. In the tables and in the subject index, in cases of repetition of measurements, only one key number is given, referring to the most accessible journal. Examination of the author list will show whether any other article contains the same numerical data. After the title are given (when the original supplies them) certain data of use in comparing constants, or for further information. These are; the temperature, with extremes if several different temperatures have been used; the unit of conductivity; and the specific conduc- 22 EXPLANATION tivity of the water of solution, with a note of whether this conduc- tivity was subtracted from the conductivity of the solution, indicated by the abbreviation, " sub." Thus, x aq. =1 Xl0~*; sub. SUBJECT INDEX. The headings in this index depend so much upon the individual point of view, that in using it, it is advisable first to look through the headings and to consider the definitions and illustrations. In cases of doubt, or in cases open to legitimate difference of opinion, the reference is given under all possible headings. For the sake of brevity, consecutive references by the same author are sometimes given inclusively, thus 60-63, instead of giving each number separately. These inclusions are never used if the numbers cover more than one name. JOURNAL LIST. The journals examined include all the important journals, and as many of the minor journals (and dissertations) as has been possible. Most of the articles in the Journal of the Russian Physico-chemical Society have been examined by Mr. G. Torossian, and the statements translated by him. They have been checked by me, as far as a very limited knowledge of the language allows. The arrangement is alphabetical for the chief words in the title, particles such as, and, de, der, etc., not being regarded. This sepa- rates distinct publications of the same society, as Proceedings, and Memoirs, but does not necessitate an exact knowledge of the title. The volume number (and when necessary the page number or division number) and the date of the last volume examined, are given immediately after the title. When a title is preceded by the sign -^ , as M Annales de, etc., the journal is not complete through the year 1910, either because it has been impossible to examine one or more volumes, or because the volume for the year 1910 has not been issued. A note of the number or of the date of missing volumes is given. The titles are those in use at the present time. If any important change in a title has been made, the fact is noted, and a cross refer- ence is given. Different libraries adopt different methods of numbering volumes when a publication appears in several series, some using continuous numbers, others following the numbers of each series. Different methods of dating are also used, when a volume covers more than one year, some giving the date of the year of publication, others the dates EXPLANATION 23 of the years included in the volume, others the date of the appearance or of the reading of the last article in the volume — a date that may- be several years earlier than the date of publication. These differ- ences are a source of some confusion in references in the literature. In addition to these difficulties, some societies issue a number of publications, which may be bound separately under individual titles, or in various combinations under various titles. Journals are sometimes referred to by the name of a past or present editor, as Drude's Annalen instead of Annalen der Physik. Cross references have been given to all the cases that have come to my notice. The names of journals which have contained no data are inserted in order to show exactly what journals have been examined. At the end is added a list of the authors of articles in the Journal of the Russian Physico-chemical Society, arranged chronologically, with the page numbers of the articles. This is given because the variations in names due to different systems of transliteration, make checking of references to this journal slightly difficult. BOOKS. Much of the numerical data published in the journals has been col- lected and republished in various forms in text-books and mono- graphs. Three of these are very useful. Taking them in chrono- logical order; Das Leitvermogen der Elektrolyte, Kohlrausch and Holborn, (1898), contains fairly complete data of the ionization con- stants, and of electrical conductivity in aqueous solution (with all values calculated to reciprocal ohms, but no values of A(tx)) given). Bredig's constants for the bases, as previously noted, are about six- teen per cent too high. The Conductivity of Liquids, Tower, (1905), contains data of the specific conductivity of pure liquids, and some data of the conductivity in solvents other than water; and also some data of conductivity in aqueous solution, published between the years 1898 and 1905. Affinitatsmessungen an schwachen Sauren und Basen, Lund6n, (1908), gives tables of the best values of most of the ionization constants published from 1889 up' to 1908, corrected (when necessary) for the values of the ionization constant of water at various temperatures, with a table of the values used in making these corrections. Bredig's ionization constants for the bases are given with no comment that they are too high. A number of tables of value are also given, though little numerical data of electrical con- ductivity are given, except as illustrations. All three books contain some bibliography. Die Theorie der elektrolytischen Dissociation, Abegg, (1903), also has some numerical data of value. Volume 1 of 24 EXPLANATION the Tables Annuelles Internationales de Constantes et Donn^es Num6riques, containing complete numerical data of ionization con- stants and of electrical conductivity published in the periodical litera- ture for 1910 has been issued. Volume 2 for the year 1911, is in print, but at the time of writing has not been published.* GENERAL. The difficulty of a search through the literature for all references to subjects which are rarely indicated by the titles of the articles, can be appreciated only by those who have done that sort of work. Omis- sions are to be expected, chiefly I should suppose, in the case of the measurements of the conductivity of salts. When an article has been found, there is sometimes doubt and sometimes entire uncertainty as to what the author really means. The confusion due to nomenclature has already been mentioned. There is also confusion from diversity in the use of symbols. For the ionization constant, a small k or a capital K is used indifferently (and occasionally an italic k), although in the majority of cases a capital K (following the usage of Ostwald) stands for 100k. When numerical data of the measurement are given, it is possible to find out by calculation, whether k or 100k is meant. But the simple statement that k (or K) is a given quantity, leaves the case in some obscurity, unless the compound is one of an homologous series, in which the values of the ionization constant for members of the series close to it are known. It must always be remembered, that the rules given for calculating constants by means of factors for certain groups, and positions, while satisfactory in many cases, are quite unreliable in many other cases. In the case of the ionization constant, the use of some letter other than a Roman k, may lead to confusion, unless there is a direct state- ment that this constant is meant. For instance, the Greek letter kappa, is frequently used as a symbol for specific conductivity. The statement, " electrical conductivity shows that x =0.14 ", may mean that the specific conductivity is 0.14, or it may mean that the ioniza- tion constant is this quantity, for an italic k may have been written, which was incorrectly printed. Almost every letter in the English alphabet, and many of the letters of the Greek alphabet have been used as symbols for specific conductivity, molar conductivity and degree of dissociation. The use of such a symbol with no explanation, leaves in doubt which of these three quantities was intended, unless there is some way to check it from preceding articles, or from the context. * It has been issued in July, 1913. EXPLANATION 25 It is interesting to note that in general the obscurity varies with the chief occupation of the author. At one extreme is the chemist chiefly interested in organic work. He describes his compound accurately, gives the formula, and some data, as melting-point, etc., by which it may be identified. Then he says, " The conductivity of this acid I have found as follows: fc = 1.4 x 10""." But he means the ionization constant, not the specific conductivity, and gives no data of conductivity values at all, in spite of his direct assertion that he does. It is left to the reader to find out what he means, and to check off as far as possible the value of the constant, in order to know whether k or 100k is meant. At the other extreme is the chemist chiefly interested in physical chemistry. He states that the com- pound he is using is methylsalicylamide; and that it is pure because it came from Kahlbaum, and the melting-point remained unchanged after five recrystallizations from alcohol. All the definitions and data relating to the measurement of the conductivity are given clearly. But there may be grave doubt as to what the compound is. The name is ambiguous, for the position of the methyl group is not stated. No formula is given, and no melting-point. Even the fact that this unknown melting-point remained unchanged after recrystal- lization is no proof of purity, for many cases are known of mixed com- pounds of definite melting-point which crystallize unchanged from one solvent and can be broken up only by crystallization from a dif- ferent solvent. In the determination of the ionization constant by methods other than the direct measurement of electrical conductivity, certain other obscurities may be present. The identity of the compounds, I have verified as far as possible by a careful examination of the formula, method of preparation, melting-point or any other data available in' the original. The values for the ionization constant have been checked off, whenever the necessary data have been given in the original, making possible the correction of some mistakes due to errors in calculation. Numerical data taken from publications generally inaccessible, as dissertations, are given more fully in the tables than the data from accessible publications. More numerical data and more explicit subdivisions of headings are given in the case of important compounds, than of unimportant compounds. A small number of compounds are given in the tables, which are mentioned neither in Beilstein, nor in Richter's Lexikon. Since the measurements of their conductivity are described by thoroughly re- liable men, it seems reasonable to suppose that such compounds were actually made, but that, for some reason, the description of them has never been published. 26 EXPLANATION Since the object of publishing bibliography is the saving of time to others, I have used much freedom in certain methods of presentation. Thus, the name Tschugaeff is familiar to many chemists. It is used in the author list under this form, and not under the form required by the system of transliteration employed. The cross reference is therefore from the unusual to the better known form. This same principle of using well known forms, has been employed in a variety of other cases. A liberal use of cross references and some repetition have been necessary to cover aU cases. The reliability of the work published in the journals is usually sufficient, but its accuracy is not as great as is supposed. This is due both to lack of definite knowledge of certain theoretical considera- tions necessary in making various corrections, and also to the uncer- tainty of some of the fundamental values. The limitations of the methods employed are fairly well understood, though there is a tend- ency to exaggerate the accuracy of some of these methods, as for instance colorimetric methods, especially when used in the case of very weak compounds. Our knowledge of the action of the solvent on the solute is still imperfect, and the corrections for such action, even when water is the solvent, are either matters of opinion, or are not known at all. Various other corrections are still uncertain, because our knowledge of the subject is not yet perfect. There are three fundamental values, the equivalent conductivity of the hydrogen ion, and of the hydroxyl ion, and the ionization con- stant of water, one of which enters into almost every calculation of the ionization constant of any compound. It must be emphasized again, that any considerable change in one of these values affects considerably the value of all the ionization constants calculated with its aid. A recalculation of practically every constant that has been published up to the present time, may be necessary when these three values are finally established. The rounding off to tenths of the numerical data printed in the tables has saved much space and added greatly to the accuracy of the comparison of the figures with the originals, while the error in- volved is too slight to be of consequence, except in a few cases. The apparently excessive number of abbreviations is due to the fact that all abbreviations are given, even those so commonly used that they are not usually explained, such for instance, as o for ortho. Most of the abbreviations, including those of the titles of journals, can be understood without looking up the full meaning. Details are given in this explanation which will appear to many to be unnecessary. But together with the abbreviations, they make it possible to understand anything that is in this book, without the EXPLANATION 27 special search for the usage of the time or place or school or author, so often necessary for the understanding of what has been printed; for, in addition to changes due to the growth of knowledge, there are changes of fashion in science as well as in the world at large. In the case of nomenclature, it has often happened that an author proposes, but Beilstein disposes of new ideas. Against two criticisms I have no defense. The first is, that this is an overelaboration of an unimportant subject. The second (which is not contradictory to the first) is, that sufiScient numerical data are not given to make the table of compounds of much value. Other criticisms could be answered, for many results are not yet positively established. Theories and compounds that have, " forever been swept from the literature," have at times come back with an in- creased knowledge, while others that have been firmly established by physical chemistry, have been greatly modified or have disappeared. Our understanding of the dissociation theory has changed so much by degrees, that the statement of James Walker made two years ago,* " We are justified in attributing the fact that acetic acid is a weak acid, whilst trichloracetic acid is a powerful one, rather to the properties of the un-ionized substances than to the properties of the ions," is an upholding of the dissociation theory and not an attack on it, as would have been the case twenty years ago. Serious physical disability coming when the greater part of the material for this bibliography was collected, has made necessary rather awkward insertions, has delayed its publication, and pre- vented as full a presentation of the subject as I had hoped. No information at all has been given about apparatus and methods. The references to the conductivity of inorganic compounds in organic solvents are incomplete, though recent work makes it clear that in many cases some complex is formed. I have been unable to make some changes in arrangement, which would have given a more sys- tematic presentation. The references often contain more informa- tion on the subject than might be gathered from the headings under each compound, for great detail in subdivision of headings is obvi- ously out of place in a bibliography of this sort. While its use will be limited to a small number of persons, I trust that the work as it stands will be of sufficient value to justify a very dreary and un- pleasant task. Thanks are due to Dr. Wilder D. Bancroft, Dr. Alice F. Blood and Dr. James F. Norris for advice, and to Dr. Olin F. Tower for per- mission to use some tables from his book. March, 1913. * Chem. News, 104, 106, (1911). ABBEEYIATIONS OF WORDS. A acid. For salts, A is used to indicate the acid radical, thus: NaCl=Na.A; Na2S04=2Na.A. Afd. afdeeling. ale. alcohol. aq. water. asym. asymmetrical. B base. For salts, this is used to indicate the radical, as under A. b.p. boiling-point. Bu butyl =C4H9. Bz benzoyl =C6HbC0. catal. catalysis. cf. compare. colorim. colorimetric. cond. conductivity. cor. corrected. d dextro. dec. decomposition. dil. dilute. diln. dilution. Et ethyl =C2H6. Fasc. fascicule. f.p. freezing-point. fum. fumaroid. g gram. Hg. U. mercury unit. hydrol. hydrolysis. inact. inactive. inorg. inorganic. insol. insoluble. k ionization constant. Second k or third k is the constant of the second or third H or OH ion. k . . . aq. ionization constant, calculated without subtracting the conductivity of the solvent, kw ionization constant of water. K specific conductivity. ABBREVIATIONS 29 A equivalent conductivity. 1 laevo. liq. liquid. m meta. M conductivity of a salt, when the hydrolysis is not checked by excess of acid or base. Used chiefly when the con- ductivity with hydrolysis checked by acid or base, is also given. mal. maleinoid. Me methyl =CH3. Meas. measured by. *Meas. =in part measured by. Mem. memoir. m. p. melting-point. M molar conductivity. N substituting group attached to nitrogen. neutral. neutralization. N. F. Neue Folge. no. number. norm. normal. N. S. new series. ortho. substituting group attached to oxygen. P para. part. partition. Ph phenyl =C6H6. Pr propyl =C3H7, in formulae. In names, as Pr-Methylin- dole, Pr shows the ring to which the substituting group is attached. qual. qualitative. q. V. which see. R ring or cyclic. rac. racemic. R. 0. reciprocal ohms. sapon. saponification. satd. saturated. Sect. section. sol. soluble. soln. solution. solub. solubility. Sp. gr. specific gravity. S. U. Siemens unit. sub. subtracted. sym. symmetrical. T temperature in degrees centigrade. 30 ABBREVIATIONS uncor. uncorrected. V volume. vac. vacuum. Vol. volume. 00 infinite dilution. ABBREVIATIONS OF JOURNAL TITLES. For a complete list of the journals examined see the section on Journals. The abbreviations are only of the titles of those journals from which references have been taken. Abhand. Kon. Sachs. Ges. Wis. Abhandlungen der koniglich sach- sischen Gesellschaft der Wissenschaften. Mathematisch- physische Classe. Am. Chem. Jour. American Chemical Journal. Am. Jour. Physiol. The American Journal of Physiology. Am. Jour. Science. The American Journal of Science. Analyst. The Analyst. Ann. Chemie. Annalen der Chemie. (Justus Liebig's), Ann. Chim. Phys. Annales de chimie et de physique. Ann. Physik. Annalen der Physik. Ann. Physik. Erganz. Annalen der Physik und Chemie. Erganz- ungsband. Ann. Univ. Lyon. Annales de I'universit^ de Lyon. Arbeit, k. Gesundh. Arbeiten aus dem kaiserlichen Gesundheitsamte. Arch. Anat. Physiol. Archiv fiir Anatomie und Physiologie. Phy- siologische Abteilung. Arch. Fisiol. Archivio di fisiologia. Arch. Gesammt. Physiol. Archiv fiir die gesammte Physiologie des Menschen und der Tiere. (Pfltiger's Archiv). Arch. Mus^e Teyler. Archives du Mus^e Teyler. (Haarlem). Arch. Pharm. Archiv der Pharmazie. Arch. Sci. Phys. Nat. Archives des sciences physiques et natureUes. Arkiv Kemi. Arkiv for kemi, mineralogi och geologi. Atti Accad. Gioenia. Atti della accademia Gioenia di scienze natu- raU in Catania. Atti Accad. Torino. Atti della reale accademia delle scienze di Torino. Atti 1st. Veneto. Atti del reale istituto veneto di scienze, lettere ed arti. Atti Pont. Accad. Nuov. Lincei, Atti della pontificia accademia romana dei nuovi Lincei. Beibl. Ann. Physik. Beiblatter zu den Annalen der Physik. Beitr. Chem. Physiol. Pathol. Beitrage zur chemischen Physiologie und Pathologie. Zeitschrift fiir die gesamte Biochemie. 32 ABBREVIATIONS Ber. Deutsch. Chem. Ges. Berichte der deutschen chemischen Gesell- schaft. Ber. Verhand. Sachs. Ges. Wis. Berichte uber die Verhandlungen der koniglich sachsischen Gesellschaft der Wissenschaften zu Leipzig. Mathematisch-physische Klasse. Bihang. Svensk. Vet.-Akad. Hand. Bihang till kongl. svenska vet- enskaps-akademiens handlingar. Biochem. Zeit. Biochemische Zeitschrift. Bol. Accad. Gioenia. Bollettino delle sedute della accademia Gioenia di scienze naturali in Catania. Bui. Acad. Belg. Bulletin de I'acad^mie royale des sciences, des lettres et des beaux-arts de Belgique. Bulletins de la classe des sciences. Bui. Acad. Craeov. Bulletin international de Tacad^mie des sciences de Cracovie. Bui. Soc. Chim. Bulletin de la soci^t6 chimique de France. Bui. Soc. Franc. Phys. Bulletin des stances de la soci6t6 franfaise de physique. Bui. Soc. Sci. Nancy. Bulletin de la soci^t6 des sciences de Nancy. Bui. Soc. Vaudoise. Bulletin de la soci6t6 vaudoise des sciences natu- relles. Chem. News. The Chemical News. Chem. Ztg. Chemiker-Zeitung. Compt. Rend. Comptes rendus hebdomadaires des stances de I'aca- d6mie des sciences. (Paris). Dis. Dissertation. Ergebn. Physiol. Ergebnisse der Physiologie. Festschr. Festschrift. Gaz. Chim. Ital. Gazzetta chimica italiana. Giorn. Sci. Nat. Econ. Giornale di scienze naturali ed economiche. Habilitschr. Habilitationsschrift. Jour. Am. Chem. Soc. The Journal of the American Chemical Society. Jour. Biol. Chem. The Journal of Biological Chemistry. Jour. Chem. Soc. The Journal of the Chemical Society. (London). Jour. Chim. Phys. Journal de chimie physique. Jour. Indust. Eng. Chem. The Journal of Industrial and Engineer- ing Chemistry. Jour. Phys. Journal de physique. Jour. Phys. Chem. The Journal of Physical Chemistry. Jour. Physiol. The Journal of Physiology. Jour. Prakt. Chem. Journal fur praktische Chemie. Jour. Russ. Phys.-chem. Soc. Journal of the Russian Physico-chemi- cal Spciety. ABBREVIATIONS 33 Jour. Soc. Chem. Ind. The Journal of the Society of Chemical In- dustry. Jour. Soc. Dyers Colour. The Journal of the Society of Dyers and Colourists. Kong. Danske Vids. Selsk. Skrift. Det kongelige danske videnska- bernes Selskabs Skrifter. Med. Nobelinst. Meddelanden fran k. vetenskapsakademiens No- belinstitut. M6m. Acad. Belg. M^moires couronn^s et autres m^moires publics par I'acad^mie royale des sciences, des lettres et des beaux- arts de Belgique. In 8°. Classe des sciences. Mem. Accad. Bologna. Meniorie della reale accademia delle scienze dell'istituto di Bologna. Mem. Accad. Lincei. Memorie deUa reale accademia dei Lincei. Classe di scienze fisiche, matematiche e naturali. Mem. Accad. Torino. Memorie della reale accademia delle scienze di Torino. Scienze fisiche, matematiche e naturali. Mem. Pont. Accad. Nuov. Lincei. Memorie della pontificia acca- demia romana dei nuovi Lincei. Mem. Proc. Manchester Lit. Phil. Soc. Memoirs and Proceedings of the Manchester Literary and Philosophical Society. Mem. R. Acad. Madrid. Memorias de la real academia de ciencias exactas, ffsicas y naturales de Madrid. Mem. R. Accad. Modena. Memorie della regia accademia di scienze, lettere ed arti in Modena. Monatsh. Monatshefte ftir Chemie. Nachr. Ges. Wis. Gottingen. Nachrichten von der konigl. Gesell- schaft der Wissenschaften zu Gottingen. Mathematisch- physikalische Klasse. Nature. Nature. Naturwis. Rundsch. Naturwissenschaftliche Rundschau. Nuovo Cim. II nuovo cimento. Ofvers. Finska Vet.-Soc. Forhand. Ofversigt af finska vetenskaps- societetens forhandlingar. (Helsingfors). Ofver. K. Vet.-Akad. Forhand. (Stockholm). Ofversigt af kongl. vetenskaps-akademiens forhandlingar. (Stockholm). Ov. Danske Vids. Selsk. Forhand. Oversigt over det kongelike danske videnskabernes Selskabs Forhandlinger. Phil. Mag. The London, Edinburgh and Dublin Philosophical Mag- azine and Journal of Science. Phys. Rev. The Physical Review. Phys. Zeit. Physikalisehe Zeitschrift. Proc. Am. Acad. Arts Sci. Proceedings of the American Academy of Arts and Sciences. 34 ABBREVIATIONS Proc. Am. Ass. Advanc. Sci. Proceedings of the American Associa- tion for the Advancement of Science. Proc. Cambridge Phil. Soc. Proceedings of the Cambridge Philoso- phical Society. Proc. Chem. Soc. Proceedings of the Chemical Society. (London). Proc. Iowa Acad. Proceedings of the Iowa Academy of Sciences. Proc. Phys. Soc. London. Proceedings of the Physical Society of London. Proc. R. Soc. Edinburgh. Proceedings of the Royal Society of Edin- burgh. Proc. R. Soc. London. Proceedings of the Royal Society of London. Proc. Trans. Nova Scot. The Proceedings and Transactions of the Nova Scotian Institute of Science. Proc. Trans. R. Soc. Canada. Proceedings and Transactions of the Royal Society of Canada. Proc. Washington Acad. Proceedings of the Washington Academy of Sciences. Progr. Programschrift. Ree. Trav. Chim. Recueil des travaux chimiques des Pays-Bas et de la Belgique. Rend. Accad. Lincei. Rendiconti della reale accademia dei Lincei. Rend. Accad. Scienz. (Napoli). Rendiconto dell'accademia delle scienze fisiche e matematiche (sezione della societsl reale di Napoli). Rend. R. 1st. Lombardo. Rendiconti. Reale istituto lombardo di scienze e lettere. Rend. Soc. Chim. Roma. Rendiconti della society chimica di Roma. Rev. R. Acad. Madrid. Revista de la real academia de ciencias exactas, flsicas y naturales de Madrid. Schrift. Naturw. Ver. Schleswig-Holstein. Schriften des naturwis- senschaftlichen Vereins fiir Schleswig-Holstein. Science. Science. Sitzber. Akad. Wien. Sitzungsberichte der mathematisch-naturwis- senschaftlichen Classe der kaiserlichen Akademie der Wissen- schaften. (Wien). Sitzber. Ges. Isis Dresden. Sitzungsberichte und Abhandlungen der naturwissenschaftlichen Gesellschaft Isis in Dresden. Sitzber. Ges. Naturw. Marburg. Sitzungsberichte der Gesellschaft zur Beforderung der gesammten Naturwissenschaften. (Mar- burg). Sitzber. K. Preuss. Akad. Berlin. Sitzungsberichte der koniglich preussischen Akademie der Wissenschaften. (Berlin). Sitzber. Phys.-med. Ges. Wurzburg. Sitzungsberichte der physik- med. Gesellschaft zu Wurzburg. ABBREVIATIONS 35 Trans. Am. Electrochem. Soc. Transactions of the American Elec- trochemical Society. Trans. Faraday Soc. Transactions of the Faraday Society. Trans. R. Scot. Soc. Transactions of the Royal Scottish Society of Arts. Trans. R. Soc. Edinburgh. Transactions of the Royal Society of Edinburgh. Trans. R. Soc. London. Philosophical Transactions of the Royal Society of London. Trans. Wisconsin Acad. Transactions of the Wisconsin Academy of Sciences, Arts and Letters. Verhand. Akad. Amsterdam. Verhandelingen der koninklijke aka- demie van wetenschappen. (Amsterdam). Verhand. Deutsch. Phys. Ges. Verhandlungen der deutschen phy- sikalischen GeseUschaft. Verhand. Naturf. Ges. Basel. Verhandlungen der naturforschenden GeseUschaft in Basel. Verh. Ges. Deutsch. Naturf. Aerzte. Verhandlungen der GeseUschaft deutscher Naturforscher und Aerzte. Verslag Akad. Amsterdam. Verslag van de gewone vergaderingen der wis- en natuurkundige afdeeling. Koninklijke akademie van wetenschappen te Amsterdam. Zeit. Analyt. Chem. Zeitschrift fur analytische Chemie. Zeit. Angew. Chem. Zeitschrift fiir angewandte Chemie. Zeit. Anorg. Chem. Zeitschrift fiir anorganische Chemie. Zeit. Biol. Zeitschrift fiir Biologic. Zeit. Chem. Ind. KoUoide. Zeitschrift fur Chemie und Industrie der Kolloide. Zeit. Elektrochem. Zeitschrift fiir Elektrochemie und angewandte physikalische Chemie. Zeit. Phys. Chem. Zeitschrift fiir physikalische Chemie. Zeit. Physiol. Chem. Zeitschrift fiir physiologische Chemie. (Hoppe- Seyler's). Zeit. Ver. Rubenzuck. Ind. Zeitschrift d. Vereins f. Riibenzucker Industrie. CYCLIC FOEMULAE. THE formulae given here are mostly type formulae, that is the formulae of compounds selected as the simplest members of various groups of compounds. The position of substituting groups is indicated in the name of a compound by numbers, the num- bers corresponding to those used in the formula of the type compound. The presence of CH is shown by an angle. Any other combina- tion of elements is given in full. Valences are not represented. Tautomej-ic formulae are not given as a rule, nor the formulae of alka- loids and dyes. For the purpose of comparison with original articles, and with older names, various letters which represent position are given as well as numbers. In the tables the name of the type compound may be given in the first name, as in dimethyl-parabanic acid, or it may be given in one of the synonyms in parenthesis, as in the case of alizarin (1,2-dihy- droxy-anthraquinone) . In a more complicated case, as in the case of anilopyrine (which is referred to pyrazole), iminopyrazole is also given as a type formula to show the manner of attachment of the imino group. In certain of the types no numbers are shown, as in cyclo- butane, because it is immaterial where the numbering begins. In such a case, the position of numbered substituting groups is readily found. For a detailed treatment of certain doubtful or unsettled points con- cerning names, see the heading " nomenclature," in the explanation. CYCLIC FORMULAE 3T Acridine NH.CO Alloxan 'NH.COv -NH.CO' "CO.NH' Alloxantine Anthracene /^-8. 9 10 Anthraquinone H 5 2 4 3 Azole (Pyrrole) ^2 N^.^ ^^ ^NH.CO-^ 3 4 Barbituric Acid /^f 2] a OtiU. Benzimideazole ^•''™ o-Benzoic sulphinide O /?\ 6 2 5 3 o p-Benzoqiiinone CH2.CH.CH2.CO2H I CMe2 CH:CMe a-Campholenic acid CHa.CHMe 1 CMez CH2.CMe.CO2H Campholic acid CH: CMe I CMe2 CH2.CH.CO2H Campholytic acid CO CHj.CMea I CMe CH2.C.CO2H zso-Campholytic acid -O MejC.CCMe) (CO2H) .CH.CO2H Camphoranic acid OC A: H MeCO ;>c \c/ o Me CO2H Carbozydehydroacetic acid CH2.CMe.CO2H I CMe2 CH2.CO Camphononic acid ^CH.COjH Camphorcarbozylic acid HO.C:N- -C.OH N:C(OH).N Cyanuric acid CH2.CH.CO2H I CMe2 CH2.CH.CO2H Camphopyric acid CH2.CH.CO2H I CMe2 CH2.CMe.CO2H Camphoric acid C'H2.CH2 CH2.CH2 Cyclobutane (Tetramethylene) 38' OHa.CHa.CHj CH2.CH2.CH: >CH2 Cycloheptane (Heptametiiylene) 0112.0112.0112 CH2.CI12.CI12 Cyclohexane (Hexahydro- benzene. Hexamethyl- ene) CYCLIC FORMULAE 5 6 7 CH.OH:CH CH.CH:CH'^ 1 4 3 2 2, 4, 6-Cyclohepta- triene 5 6 7 CH2.CH2.0Il2^ J. >C2 CH2.CH2.CH ^ 1 4 3 2 i-Cycloheptene CH2.CH2.OH2 CH2.CH : OH Cyclohexene (Tetrahydro- benzene) CIl2.CIl2^ I >CH2 CH2.CI12 Cyclopentane (Pentamethylene) CH2^ I >CH, CH2^ Cyclopro- pane (Trimethyl- ene) MeCO 00 > H..^ A: A o Me OH Dehydroacetic acid H GO O.OH H2C CH2 \o/ H2 GO CMe HO C.CO2H Me iso-Dehydroacetic acid H2 /\ GO 00 H2C " CII2 \/ H2 Dihydro-resorcinol. (m-Diketo- hezamethylene) Diketo-hexamethylene see Dihydro-resorcinol CI12.OI1; CO . 00 ;>CH2 Diketo-penta- methylene OH2.OH— OH.OO2H I NMe CH.OH OI12.CH — OH2 2-Ecgonine OH2 -CH2 CO.NMe.CH.OH2.OG2H rac-Ecgoninic acid OH, CH: '>o oo<: •NH.CH2 •NH.CH2 -CH,- ^ \/ Ethylene oxide Ethylene urea Fluorene Fluorenol = Hydroxy- fluorene ^5 2^ Fluorenone (9-Keto- fluorene) Furfurane (Furane) Glyoxaline (Imideazole') Heptamethylene see Cycloheptane CYCLIC FORMULAE 39 Hezahydro-benzene see Cyclohezane Hexamethylene see Cyclohexane r07 HCH.N.OH= HC( :N.OH) . OH Hydiozamic acid H H O /l\ /7\ \NH/N |6 ^■> a /7\/l\ 6 2] 4 3 \4/ 3 3 5 v/ 3l Imideazole see 2,5-Immopy- Indole. (Pr-shows Indone * Glyoxaline razole substitution in the (1-Ketoin- Nring) dene) Ketofluorene see Fluorenone /^/h. o' a' Naphthalene NH:Cco CO.NH. CO.NH- Parabanic acid Pentamethylene see Cyclopentane ^-nYN HjN i-^NH, A PhOH Phenosafranine CH-C.CO2H Ph.C.O.N Phenylisoxazolecar- boxylic acid CH.CO Ph.C.NH >o 3-Phenylisoxazo- lone (5) 1 N=CH 7 2 HC 5C— NH\_(fjj 3 isr— C— N ^ 4 9 Purine H 4 3 Pyrazole. See also Im- inopyrazole H .N 06 N HjC |5 2 ,4 3 6 2 a O V H H,C- -CH.? Pyrazo- Pyridine Pyrone Pyrrole Ione(5) (Azole) * The indone of rosindone contains a N ring. s 2 ,'HjC 1 CHja \n/ H Pyrrolidine 40 CYCLIC FORMULAE Pyrryl; used for de- rivatives of Pjnole 8 = 0- =[1] 7=m- = [2] 6=p- =[3] When numbered from the Bz ring Quinoline 3 3] ISO- Quinoline 1 2N 3 \f^/ H A\ I 5 2N 4 3| N N Tetrahydro-benzene see Cyclohezene Tetramethylene see Cyclobutane 1, 2, 4, 5- Tetrazine 1, 2, 3, 4- Tetrazole P 2 1 i^ or meso 2rj Thiazole ■N; NH2.C6H3<^ ^CeHs : NH Thienyl; used for deriva- tives of Thiophene ■S' Thionine 5 2| Thiophene 0C5 3C.SH Thiourazole H A |5 2 H A\ N5 2N 1,2,6-Triazole 1,3,4-Triazole Trimethylene see Cyclopropane 6 5 Uracil H Ods 3C.0H ll 2|| HN N Urazole Violuric acid TABLES THE compounds are arranged alphabetically, except where the numerical order is more natural, as in the case of mono- and di- derivatives. Immediately after each acid are given the amides, the anhydride and then the esters. Iso-, alio- etc. compounds are placed after the normal compound, the prefixes not being con- sidered. The headings under each compound are: (1) the specific conduc- tivity of the pure compound; (2) the ionization constant; (3) the conductivity in aqueous solution; (4) the conductivity in solvents other than water; (5) miscellaneous measurements; (6) the conduc- tivity of the salts. Numbers in bold face type are bibliographical key numbers, re- ferring to the corresponding numbers in the author list. When the same measurements are published in more than one journal, the key number is to the most accessible article. In the author list, after the title of this article are given references to the less accessible articles. When the value of the ionization constant has been determined by measurements of the conductivity of the compound, no statement of the method is made except for emphasis; other methods are shown by an abbreviation in parenthesis. The abbreviation aq., placed after the value, shows that the conductivity of the water has not been subtracted in calculating the value. Second, etc., k, means the constant of the second, etc. H or OH ion. Numerical values of conductivity, unless otherwise stated, are for aqueous solutions; with the obvious exception of those for the specific conductivity of the pure compound, which can always be recognized because neither concentration nor dilution is given. If all the refer- ences to the conductivity in water are desired, look up also the refer- ences given under the ionization constant, for in some cases these have not been repeated under the heading, conductivity in aqueous solution. The dilution in liters is given in parenthesis in its proper place. Thus, A(32) = 9, shows that the equivalent conductivity at a dilu- tion of 32 liters is 9 reciprocal ohms, or whatever unit may be used. The values given for the equivalent and the molar conductivity are in the unit used in the original article, unless otherwise stated in the table. Reference to the author list wiU show what this unit is. When different values of the ionization constant or of the conduc- tivity are compared, it is advisable to read in the explanation the precautions necessary for a proper comparison. 42 TABLES [Abi A. Abietic acid. C20H30O2; also given as C19H28O2. Cond. with NaOH; acid of m. p. 153°-154°, and m. p. 179°; 1017. With NaOH in Et ale; acid of m. p. 167°-172°; 1508. Acet- see Acetyl- for most compounds; see also Aceto-. Acetaldehyde. C2H4O = MeCHO. «X 108 at o°=1.20; b. p. 20''-21°; 1843. Also 1842, 1844. At 15°= 1.67; 1844. kAXlO" at 0°=7.0 (hydrol.); 512. At 1°=5.0 (hydro!.); 512. At 25°, A(13.1) = 4.9, (104.8) = 14.3; 959. T not stated; 1843. In HON, no cond.; 943. In NH3, qual.; 606. In MeNHs, fair cond.; 637. Cond. with inorg. acids and bases; 512, 1843. As solvent of various salts; 1844. Of compound with H2SO3; 959. Acetaldehyde ammonia in NH3, qual.; 606. Meta-acetaldehyde. (C2H40)x. x=2 or 4. In H2SO4; 750. Para-acetaldehyde. (Paraldehyde). (C2H40)x. x probably is 3. xxW at 25° is less than 3.4; 1106, 1107. At 15°, A(32) = 0.7, (64) = 1.1; 1741. - 1843. In H2S, no cond.; 1897. In H2SO4; 750. In NH3, qual.; 606. As solvent; 1106, 1107. Acetaldehyde ammonia. C2H7ON. In NH3, small cond.; 606. Acetaldehyde sulphurous acid. C2H6O4S =Me.CH0H.HS03. kiXlO at 25°=3.6; diminishes on diln. A(26.2) = 332.7, (104.8) = 338.8, (00) = 378; 959. Acetaldoxime. (Methyl aldoxime). C2H60N=MeCH:NOH. KXlO^ at 25° is less than 1; b. p. 114°-115° @ 749 mm.; 1843, 1844. Cond. as solvent of NEt4l; 1844. Acetamide see Acetic acid amide. Acetamino- see Acetylamino- AcetaniUde. C8H90N=MeCO.NHPh. ks X 10" at 40.2°=4.4 (catal.); m. p. 115°; 1995. In HBr, good cond.; in H2S, no cond.; 1897. In HCN, small cond.; 943. In NH3, fair cond.; 606. Acetanilino- see Acetylanilino- i-Q-i Acethydroxamic acid. C2H502N=MeCH.N.OH. kiXlO^ [at 25°] = 2.8. Ace] TABLES 43 A(14.5) = 0.21, (58.2) = 0.7, (oo) = [380]; 1353a. Fe.3A, cond. alone, and with HCl; 756. Acetic acid. C2H402=Me.C02H. KX 108 at 0° is less than 2; 943. At 15°=5.47; 1844. At 16°; 1419. At 18°= 1.2; 1470; also 362, 787, 986, 1957. At 20°; 694. At 25° is less than 2; 1388; also 44, 753, 908, 1427, 1844. See also 900, 1380. kAXlO= at 0°=1.77; 1144, 1968a, 141. Calculated; 1144. At 2.6°= 1.8; 387. At 8°= 1.83; 1144. At 9.2°= 1.79; 1968a. At 10°=1.81; 875, 1144. At 15°=1.85; 1143, 1144. At 17°= 1.78 aq.; 164. At 18°= 1.82; 93, 94, 1211, 1332, 1341, 1865; =1.86 in 44% Et ale; 613; (colorim.); 1563. At 20°= 1.85; 875. At 25°= 1.86; lowest value=1.70, high- est=1.89; 44, 295, 1143, 1144, 1184, 1368, 1370, 1500a, 1539, 1573a, 1968, 1968a, 1971; (catal.); 1043; =1.74 (sapon. and cond.); 1143; (neutralization); 463; (colorim.); 1729b. At 30°=1.87; 875. At 35° = 1.83; 1968a. At 40°=1.80; 875,1143,1144. At 50°= 1.74; 1144. At 52°= 1.62; 43, 44. At 54.3°= 1.62; 43, 44. At 55°= 1.46 (action of diastase on starch); 2002. At 60°= 1.66 (calculated); 1144. At 76°= 1.5; 1391a. At 100°= 1.114; 1332, 1341. At 156°= 0.536; 1332, 1341. At 218°=0.172; 1332, 1341. At 306°= 0.0139; 1332, 1341. T not stated; (colorim.); 278, 951, 1643, 1781, 1866; (precipitation of casein); 693. Cond. At 0°, A(32) = 5.3, (1024) = 28.0, (co) = 227; 1968a/ At 25°, A(32) = 8.7, (1024) = 46.0, (oo) = 364; 1370. At -3° to +10°; 347. At0°;141, 910, 943. At 0°-35°; 1968, 1968a. At 8°-50°; 1144. At 10°-50°; 875. At 14° and 19°; 838. At 18° and 52°; 43. At 18°-306°; 1332, 1341. At 35°-65°; 388a. See also 94, 145a, 145b, 171, 177, 294, 299, 377, 385, 386, 463, 542, 694, 782, 788, 900, 910, 1094, 1122, 1427, 1495, 1518, 1520, 1537, 1539, 1569, 1573a, 1635, 1747, 1954, 1957. In HBr; 30, 147a. No cond.; 1897. In HCl; 30, 147a, 223. Qual.; 1897. In HCN; 943. In HI, no cond.; 147a. In HaS, no cond.; 147a, 1897. In HNO3; 223. In H3PO4; 223. In H2SO4; 222, 223, 750. In N2O4, no cond.; 602. In SO2; 1842. In NH3, qual.; 606. In norwi.-amyl ale; 787, 788. In amyl ale; 647. In benzene, no cond.; 1801. In Et ale; 513, 647, 754, 782, 787, 788, 1311, 1791, 1820. In Me ale; 335, 787, 788. In MeNH2, good cond.; 637. Cond. with inorg. acids; 177, 378, 463, 799, 900, 1184, 1495, 1518, 1718, 1821. With inorg. bases; 171, 294, 299, 463, 1341, 1717, 1718. With inorg. salts; 378, 1388, 1470, 1539, 44. TABLES [Ace 1993, 1994. With other inorg. compounds; 1163, 1386, 1495, 1518. With organic acids; 44, 93, 145b, 463, 1388, 1717, 1718, 1821. With organic bases; 44, 145a, 145b, 513, 1011, 1144, 1388. With organic salts; 94, 378, 908, 1280, 1388, 1539, 1573a, 1618a, 1809, 1993, 1994. With other organic compounds; 45, 799, 1120, 1223, 1311, 1386, 1388, 1569, 1747, 2032. Under pressure of 1 to 500 atmospheres; at 0°; 220, 1708a; at 0.1°-40°; 1708; at 14°; 542; at room temperature; 1427. As solvent; 908, 1280, 1311, 1388, 1569, 1809, (1818), 1844, 1994. A1.3A; 1088. - NH4.A, at 15°-40°; 1143; at 18°-306°; 1332, 1341. Also 145a, 165, 463, 823. In HBr, good cond. ; in PH3, no cond.; 1645. - Ba.2A, at 0°-35°; 911. Also 1088, 1174, 1573a, 1953a. Cond. alone and with glycocoU; 1086. In NH3, qual.; 606. - Cd.2A; 881a, 1086, 1088. With glycocoll;' 1086. - Ca.2A; 1174, 1573a. In NH3, qual.; 606. - Ce.SA; 1088. - Cr.BA; 1953a. - Co.2A, at0°-35°; 911. Also 1086, 1088, 1573a, 1953a. With glycocoll; 1086. - Cu.2A; 377, 540, 1086, 1088, 1618a. With organic compounds; 45, 1086, 1569, 1618a. In NH3, qual.; 606. Under pressure of 1-500 atmospheres; 1427. Also 1047. - Fe.3A; 1962. - Gl com- plex; 1711. - La.SA; 1088. - Pb.2A; 377, 881a, 1088, 1343, 1746, 1747. Also 1047. In NH3, qual.; 606. With PbO; 1386. With organic compounds; 381, 1747. - Li.A; 1367. In flame; 682. - Mg.2A; 1836, 1953a. Under pressure of 1-500 atmospheres; 1427. - Mn.2A; 1086, 1088, 1737. With glycocoll; 1086. - Hg.2A; 247, 466, 1088, 1094. With FejOa; 466. With HgS; 247. 2Hg.2A in NH3, qual.; 606. - Ni.2A, at 0°-35°; 911; also 1086, 1088. With organic compounds; 1086. Under pressure of 1-500 atmospheres; 1427. - K.A, at -21° to +7°; 793. At 35°-65°; 388a. Also 94, 164, 165, 171, 294, 299, 377, 463, 588, 965, 996, 1078, 1367. In HCl, HNO3, H3PO4; 223. In H2SO4; 222. In NH3, qual.; 606. In acetic acid; 94, 1280, 1809. In Me and Et ale; 958, 1280, 1386b, 1807. In glycerol; 1279. With inorg. compounds; 379, 495. With organic compounds; 94, 381, 1280, 2032. In flame; 682. - Ag.A, at 25°-60°; 1637. Also 881a, 1111, 1174. Saturated soln.; 656. In Na.A, soln.; 1331. In NH3, qual.; 606. - Na.A, at 0°-35°; 532, 924, 1968a. At 10°-50°; 875. At 18°-306°; 1332, 1341, 1341b. At 25°-60°; 1537. At 35°-65°; 1953a. At 18° and 52°; 43. At 89°; 1229a. At 25°, A(32) = 75.5, (1024) = 85.0; 1367, 1368a. Also 94, 372, 377, 391, 738, 810, 889, 995, 1199, 1331, 1639, 1717, 1718, 1966, 1968a. In H2SO4; Ace] TABLES 45 223, 1834. In HCl, little cond.; in PH3, no cond.; 1645. In NH3, qual.; 606. In acetic acid; 94, 908, 1280. In Me and Et ale; 335, 391, 491, 1386b, 1390, 1470, 1807. With inorg. compounds; 796, 810, 1199, 1227. With organic compounds; 45, 94, 378, 381, 449, 908, 1280, 1539, 1746, 1747, 1994, 2032. Under pressure of 1-260 atmospheres; 542. In flame; 682. - Sr.2A; 319, 1174, 1953a. In flame; 682. - T1.3A, in flame; 682. - UO2.2A cond. alone and with Na.A; 449, 1953a. - Zn.2A; 377, 1086, 1088. In NH3, qual.; 606. With inorg. salts; 379, 381. With organic compounds; 381, 1086, 1573a. Under pressure of 1-500 atmospheres; 1427. E. m. f.; 1047.- Zr0.2A; 1520.- Or- ganic salts; 145a, 145b, 513, 637, 1011, 1143, 1144, 1388, 1791, 1801. Acetic acid amide. (Acetamide). C2H60N=Me.CONH2. XX 10* at 80°=3.0. At 81°=2.9; m. p. 82°; 1843. At 100°= 0.43; 1894. ksXlO" at 25°=0.31 (catal.); 1864 and 1150. At 40.2°=3.3 (catal); 1995. At 60°=41 (inversion); 1880 and 1150. Cond. at 15°; 1741. At 25°, A(32) = 0.95; 1729. Qual.; 1904. In HBr; 33, 1646; qual.; 1897. - In HCl; 1646; qual.; 1897. - In HI, poor cond.; in H2S, no cond.; 1897. - In NH3; 607, 610. - In MeNH2; 605; qual.; 637. - In SO2; 1842. Cond. with HCl; 17, 410, 781. - With NaOH; 412, 781. With KCN and inorg. salts; 1097, 1894. As solvent; 1894. Hg.2A at 0°; 725. At 25°, alone and with HCl; 1094. Also 963. - B.HCl at 25°, A(50) = 369.9. - 2B.H2SO4; 1864. Acetic acid benzylamide. (Benzylacetamide). C9HiiON=MeCO.NH(CH2Ph). Cond. with HgCk; 1097. Acetic acid bromoamide. (Acetbromoamide). C2H40NBr=MeCO.NH(Br). kAX 10' at 25°, is less than 1; is dec. in aq.; m. p. 138°. A(16) = 0.15, due to decomposition. Na salt, A(32) = 68.2, (1024) = 80.0; 757. Acetic acid chloroamide. (Acetchloroamide). C2H4ONCI =MeCO.NH(Cl). Cond. at 25° is due to presence of HCl; m. p. 110°; 757. Acetic acid cyanoamide. (Acetylcyanoamide). C3H40N2=MeCO.NH(CN). kAX 10* at 25°= 1.5; 70.- [Quoted?]; 757. A(24.8) = 21.3, (793.6) = 102.2, (oo) = 354; 70. Na salt at 25°, A(32) = 74.4, (1024) = 83.1; 270. 46 TABLES [Ace Acetic acid dimethyl amide. (Dimethyl-acetamide). C4H90N=MeCO.NMe2. Cond. with HCl; 781. Acetic acid anhydride. C4H603=(MeCO)20. «XlO«atO°=1.01; b. p. 137°-138°; 1843. At 20°=0.75; 1590a. At25°=1.18; b. p. 138''-139°; 1843; - 1844. Cond. Showing change to acid; 1600a. As solvent; 1590a, 1844. As solvent, under pressure; 1590a. Acetic acid amyl ester. C7Hi402=MeC02.C6Hii. In HCl, in HBr and in HI, good cond.; in H2S, no cond.; 1897. In NH3, qual.; 606. Effect of temperature on cond. ; 106. Acetic acid iso-butyl ester. C6Hi202=MeC02.iso-Bu. In NH3, qua!.; 606. Effect of temperature on cond. ; 106. Acetic acid capryl ester. (Octyl ester). CioH2o02=MeC02.C8Hi7. InNHs, qual.; 606. Acetic acid ethyl ester. C4H802=MeC02.Et. K X 10^ at 25°=4.5; 941, 1107. T not stated; 305. In HBr and in HCl, qual.; 16. In NH3, qual.; 606. Cond. with NaOH; 1879. With Cu oleate; 1569. With inorg. salts; 941, 1107. Effect of temperature on cond.; 106. As solvent; 1569, (1818). Relative basicity in organic solvents; 1051. Acetic acid glyceryl ester. (Triacetin). C9Hi406=(MeC02)3C3H6. Effect of temperature on cond.; 106. Acetic acid methyl ester. C3H602=MeC02.Me. % X 10* at 25° is less than 2; b. p. 54°; 1388. In HBr, qual.; 16. Cond. with HCl and acetone and glycerol; and with H2SO4; 799. With HNO3; 1569. With NaOH; 1879. Effect of temperature on cond.; 106. With inorg. and organic com- pounds; 1388. As solvent; (38). Acetic acid phenyl ester. C8H8O2. In NH3, qual.; 606. Acetic acid propyl ester. C6H10O2. InNHs, qual.; 606. Effect of temperature on cond.; 106. Acetnaphthalide. CuHuON. InNHs, qual.; 606. Aceto- see also Acetyl- and Acet- Acetoacetic acid. C4H603=MeCO.CH2.C02H. kAXlO^=1.5 (colorim.); 804. Ace] TABLES 47 Acetoacetic acid ethyl ester. C6Hio03=MeCO.CH2.C02.Et. xXlQS at 25°=4.0; b. p. 174°-176° @ 736 mm.; 941. =170 1669. Also 668. kAXlO^ at 1°=1.9; 1356. At 25°=0.02 (sapon.);=4 (cond.) 662. Also 661. At 35°= 5.4; 1356. At 25°, A(32) = 0.5, (512) = 2.1, (oo) = 360; not very accurate 661. - 698, 844, 1823, 1831. In HBr, and in HI, good cond.; in H2S, no cond.; 1897. In HCN, no cond.; 943. Cond. In NaOH+HCl; 844. - With inorg. salts; 941. As sol- vent; 478, 483, 668, (941). Salts. Fe.A; 756. - K.A. with HgNOa; 149. Acetoacetic acid methyl ester. CsHsOa. kAXlO" at 25°=2 (sapon.); 666, 1694. At 25°, A(64) = 0.26, («)= [360]; 698. /3-Aceto-iso-butyric acid. (a-Methyl-laevulinic acid). C6Hio03=MeCO.CH2.CHMe.C02H. kAXlO' [at 25°]=3.03; b. p. 153°-156° @ 3 mm.; 202. 7-Acetobutyric acid. C6Hio03=MeCO.(CH2)3.C02H. kAXlO* at 25° =2.2 aq.; b. p. 180° @ 20 mm. A(32) = 9.9, (1024) = 52.1, (oo) = 376; 1588. Acetoguanamine. C4H7NB. keXlO" at 40°=3.06 (catal.); 1995 and 1150. At 40.2°=2.96 (catal.); m. p. 265°; 1995. Acetol. C3H602=MeCO.CH20H. Cond. with NaOH; b. p. 145°-146°; 975. Acetone. C3H60=Me.CO.Me. xXlO'at-15°=0.011; 1863a. AtO°=3; 922; - also 906,916,918, 920. At 13°; 1477. At 18°=0.2; 478; also 362, 487, 1056, 1070. At 20°= 1.2; 1590a. At 25°= 1.73; 1844. =2.27; 1843; - also 334, 347, 904, 905, 906, 916, 918, 922, 941, 1388, 1569, 1830, 1847, 1853a. At 15° to 35°; 1477. T not stated; 305, 336, 475, 1620. At 25°, A(2) = 0.017; 1843. In HBr; 1646; good cond.; 1897. In HCN, no cond.; 943. In HCl and HI, good cond.; in H2S, poor cond.; 1897. In MeNH2, poor cond.; 637. Cond. with HCl and methyl acetate; 799. With inorg. bases; 979, 1036. With H2SO3 and Na2S03; 1535. With HCl qual.; 1553. With organic acids, bases and salts; 45, 475, 922, 979, 1056, 1388, 1569, 1620, 1844, 1847, 1848, 1863a. With HCl and benzene; 1569. As solvent; 334, 336, (347), 474, 475, (478), 487, (748), 767a, (904), (915), (916), (918), (920), 922, (941), 1056, 1070, 1286, 1329, 1379, 1388, (1389), 48 TABLES [Ace 1569, 1590a, 1620, 1623, (1681), 1712, 1830, 1841, 1844, 1847, 1848, 1863a. As solvent, under pressure; 1590a. Relative basicity in organic solvents, (colorim.); 1051. Acetone-diacetic acid see Hydrochelidonic acid. Acetone-dioxalic acid anhydride see Chelidonic acid. Acetone-dicarboxyUc acid. C6H605=CO(CH2C02H)2. kxXlO* at 25°=7.9 aq.; diminishes on diln.; m. p. 135°. m(21.5) = 43.1, (686.7) = 172.2, (co) = 354; 23. Acetone semicarbazone. C4H90N3=Me2.C:N.NH.CONH2. ksXlO^^ at 40°=3.29 (catal.); 1150 and 1995. At 40.2°=3.18 (catal.); m. p. 184°; 1995. Acetonitrile. C2H3N = Me.CN. XX 10' at 0°=3.195; 1843. = 39; 1844; - 482, 1845. At 25° = 3.98; 1843;=3.8; 1849; - 482, 1423a, 1842, 1844, 1845. AtO°, A(32)=0.18; 684, 683. In HBr; 1646; - qual.; 1897. In HCl; 33, 1646; - qual.; 1897. In HI, poor cond. ; in H2S, good cond.; 1897. In AsCls; 1842. In NH3, qual.; 606. Cond. as solvent of inorg. salts; 482, 1844, 1845. As solvent of organic compounds; 482, 767a, 936, 1423a, 1827, 1842, 1844, 1848, 1849. Acetophenone. (Methylphenylketone). C8H80=Me.CO.Ph. HXW at 25°= 1.8; 1106, 1107; = 2.2; 1323; - 1569. In HBr, good cond. ; in H2S, no cond. ; 1897. In NH3, qual. ; 606. Cond. With Cu oleate; 1569. As solvent of inorg. salts; 1106, 1107, 1323. As solvent of organic compounds; 482, 1106, 1107, 1569. p-Acetophenone-azo-diethyl-aniline. Ci8H2iON3=MeCO.C6H4.N2.C6H4.NEt2. Hion concentration=5X lO"* (colorim.); m. p. 162°-163°; 1730. p-Acetophenone-azo-diethyl-aniline oxime. C18H22ON4. H ion concentration is less than 5 X 10~^ (colorim.); m. p. 199°- 200°; 1730. p-Acetophenone-azo-dimethyl-aniline. CieHxyONa. H ion concentration is less than 5 X 10~^ (colorim.); m. p. 203°- 204°; 1730. p-Acetophenone-azo-phenylaniline. C20H17ON3. H ion concentration is less than 5 X 10"^ (colorim.) ; m. p. 184°- 185°; 1730. Acetophenone oxime. (Methylphenylketoxime). C8H90N=Me.C(N.OH).Ph. kiX 10^ at 25°=3.7 [aq.?]; 1748. - 733. At 25°, A(128) = 0.24, (1024) = 0.68, (oo) = [356]; 1748. /3-Acetopropionic acid see Laevulinic acid. Ace] TABLES 49 Acetoxime. C3H70N=Me2C:NOH. kAXlO" at 15°=4.05 (catal.). At 18°=4.6 (catal.). At 22° = 5.39 (catal.). At 25°=6.0 (catal.). At 28.07°=6.89 (catal.). At 35°=8.55 (catal.). At 40° =9.9 (catal.); m. p. 59.7°-60.0°; 1150. kfiXlOi' at 15°=2.86 (catal.). At 18°=3.7 (catal.). At 25°= 6.5 (catal.). At 35° = 13.0 (catal.). At 40°= 19.0 (catal.); 1150. At 40.2°= 17.5 (catal.); m. p. 61°; 1995. At 25°, A(32) = 0.07, (256) = 0.17, (co) = [356]; 1748. In NHs, no cond.; 604. o-Acetoxy-benzoic acid. (Acetylsalicylic acid. Aspirin). C9H804= MeCO.O.CeHi.COaH. kiXlO* at 25°=3.33. A(64)=48.4, (1024) = 151.5, (co) = 351; 1371. m-Acetoxy-benzoic acid. C9H8O4. kiXlO^ at 25°=9.86. A(256) = 51.5, (1024) = 95.2, (00) = 351; 1371. p-Acetoxy-benzoic acid. C9H8O4. kAXlO^ at 25°=4.22. A(64) = 17.8, (1024) = 64.4, (oo) = 351; 1371. p-Acettoluide. CsHuON. InNHs, qual.; 606. Acettolylglycine see Acetyltolyl amino-acetic acid. Aceturic acid see Acetylamino-acetic acid. Acetyl- see also Acet- and Aceto- Acetylacetone. C6H802=MeCO.CH2.COMe. XX 10^ at 0°=2.02; 1844. At 25°=2.79; 1844; - 1569, 1843; - qual.; 1904. kAXlO'at 25°=4.7aq.; 1588;=150; 698. At 25°, A(32)=0.47 (oo) = 378; 1588. - 844. In Et ale. qual.; 1298. Cond. With NaOH and HCl, qual.; 844. With boric acid; 756. With Cu oleate; 1569. As solvent; 1569, 1844. Salts. A1.3A; 756. - G1.2A, A(256) = 1.5, (512) = 1.7; 388. - Fe.3A. - La.3A; 756. - Na.A, A(32) = 82.6, (1024) = 109.0; 388. Acetylamino-acetic acid. (Aceturic acid. Acetyl glycine). C4H703N= (MeCO)NH.CH2.C02H. kA X 10* at 25°=2.3; aq. used for soln. was impure. A(32) = 29.2, (1024) = 133, (oo) = 355; 1370. Cu.2A, at 25°, A(32) = 42.7; 1086. o-Acetylamino-benzoic acid. C9H903N= (MeCO)NH.C6H4.C02H. [(MeC0)NH=2; C02H=1]. 50 TABLES Ace kiX 10* at 25°= 2.36. A(128) = 55.7, (1024) = 135.0, (co) = 350; 1371. Na.A, at 25°, A(32) = 62.4, (1024) = 74.1; 1367. m^Acetylamino-benzoic acid. C9H9O3N. kAX 105 at 25°= 8.5. A(256) = 47.9, (1024) = 88.8, (oo) = 350; 1371. p-Acetylamino-benzoic acid. C9H9O3N. kiX 106 at 25° =5. 17. A(256) = 37.9, (1024) = 71.8, (oo) = 350; 1371. 4-Acetylamino-in-phthalic acid. CioH905N= (MeCO)NH.C6H3(C02H)2. [C02H=1,3; MeC0NH=4]. kAXlO* [at25°]=7.9; 1914;=11; 1913. Second kx X 10^= 1.3; 1913. [At25°], M(2234) = 287, (co) = 375; 1913. 2-Acetylainino-p-phthalic acid. CioHgOgN. [C02H=1,4]. kA X 10* at 25°= 9.8; m. p. 355°. The value of k is probably too high, on account of influence of the second carboxyl group; 1684. Quoted in 1914. pi(600) = 197.7, (1200) = 248.5, (00) =375; 1684. 2-Acetylamino-p-phthalic acid 4-mono methyl ester. C11H11O5N. [C02H=1; C02Me=4]. kAXlO* [at25°] = 7; m. p. 163°; not entirely pure; 1684. Quoted in 1914. m(700) = 187.7, (1400) = 229.4, (oo) = 374.4; 1684. Acetylanilino-acetic acid see Phenylacetylamino-acetic acid. a-AcetylanUinobutyric acid. Ci2Hi603N=Et.CH.N(Ph)(MeCO).C02H. kiXlO* at 25°= 1.09; m. p. 119°. A(320) = 57.8, (1280) = 109.6, (oo) = 348; 1840. jS-Acetylanilino-iso-butyric acid. C,2Hi603N=(Ph)(MeCO)N.CH2.CHMe.C02H. kiXlO^ at 25°=2.9; m. p. 174°. A(295) = 29.7, (1180) = 58.7, (00) = 348; 1840. a-Acetylanilino-propionic acid. CiiHi303N = Me.CH.N(Ph)(MeCO).C02H. kiXlO* at 25°= 1.25; m. p. 143°. A(128) = 41.8, (1024) = 105, (oo) = 352; 1840. Acetyl bromide. C2H30Br=MeCO.Br. K X 10« at 0°=2.09. At 25°=2.38; 1843, 1844. In HBr and HCl, good cond.; in HI, no cond.; 1897. Cond. as solvent of NEt4l; 1844. Acetyl-bromoanilino-acetic acid see Acetyl-bromophenyl-amino- acetic acid. Ace] TABLES 61 Acetyl-bromophenyl amino-acetic acid. (Acetyl-bromoanilino-acetic acid. Acetyl-bromophenyl glycine). CioHio03NBr=(MeCO)(C6H4Br)N.CH2.C02H. kiXlO* at 25° = 2.85; m. p. 176°-177°. A(300) = 89.0, (1200) = 156, (co)=355; 1840. Acetylcarbopyrrolic see Methylpyrrylketone carboxylic. Acetyl chloride. C2H30CI= MeCO.Cl. xXW at 0°=3.52; 1844. At 25°=4.21; 1844, 1843. In HBr and HCl, good cond.; in HI and H2S, no cond.; 1897. In HON, fair cond.; 943. In SO2; 1842. Cond. As solvent of NEtJ; 1844. With allyl thiocarbimide, qual.; 1223. Acetylcyano- see Cyanoaceto- and Cyanoacetyl- Acetylcyanoamide see under Acetic acid amide. Acetyldibromo-acryUc acid. C5H403Br2=MeCOCBr:CBrC02H. LaX 10^ at 25°=6.2 aq.; m. p. 78°-79°; diminishes on diln. A(90.3) = 25.6, (1444.8) = 89.1, (a>) = 355; 23. Acetylene. C2H2=HC;CH. kAXlO" at 18° is less than 1.3; 1883. Cond. At 0°, no cond.; 895, 902. Of liquid acetylene alone and with Et ale. and ether, qual.; 1234. Qual.; 273. In MeNH2, no cond.; 637. Acidity shown by solubility experiments; 181; see also 182. Acetylene-dicarboxyUc acid. C4H204= CO2H.C ! C.CO2H. Second Isa too great to measure by inversion; 1638. At 25°, iu(64) = 467, (1024)=721; 1372. 2Na.Aat25°, A(32) = 84.2, (1024) = 101.4; 270. Acetylene tetrachloride see Tetrachloro-ethane. Acetylglycine see Acetylamino-acetic acid. Acetyhnalonic acid diethyl ester. C9Hi406=MeCO.CH(C02Et)2. No cond. in aq.; 698. Acetyhnalonic acid dimethyl ester. C7H10O5. Cond. increases on standing; at 25°, /i(128) = 13.7 after 15 minutes standing; 698. N-Acetylmethylamino-p-phthalic acid. CiiHu06N= (MeCO)NMe.C6H3(C02H)2. kAXlO' [at 25°] is less than 1.26; increase on diln. is due to the second carboxyl group; m. p. 255°. ju(700) = 223.5, (1400) = 280.4, (co) = 374.4; 1684. Acetyl-/3-naphthalino-iso-butyric acid see Acetyl-jS-naphthylamino- iso-butyric acid. Acetyl-a-naphthylamino-acetic acid. (Acetyl-a-naphthyl glycine). Ci4Hi303N= (MeCO) (CioH7)N.CH2.C02H. 52 TABLES [Ace kAX 10* at 25°=2.07; m. p. 156°. A(283) = 74.7, (11?2) = 132, (oo) = 348; 1840. Acetyl-jS-naphthylamino-acetic acid. (Acetyl-/3-naphthyl glycine). C14H13O3N. kAX 10* at 25°=2.41; m. p. 172°. A(500) = 100.7, (1000 = 135, (00) = 348; 1840. Acetyl-zS-naphthylamino-iso-butyric acid. (Naphthylamino-iso-buty- ric acid acetyl derivative). Ci6Hi703N=(MeCO)(CioH7)N.C3H6.C02H. kA X 10^ at 25° =2.2; m. p. 188°. A(800)=43.0, (1600) = 59.4, (co) = 347; 1840. Acetylphenylbut3rric acid see Phenylacetyl-butyric acid. Acetylphenyl glycine see Phenyl-acetylamino-acetic acid. Acetylphenylglycine-o-carboxylic acid. CiiHii06N=C02H.C6H4.N(COMe)(CH2.C02H.) kAXlO^ at 25°= 1.05; m. p. 213°, varies from 210° to 215° ac- cording to manner of heating; 1246, 1814. At 25°, A(79.4) = 92.5, (oo) = 373; 1245. Acetylphenylglycine-o-carboxylic acid eso mono ethyl ester. Ci3Hi506N=Et02C.C6H4.N(COMe)(CH2.C02H). kAXlO* at 25° = 3; m. p. 132°; 1245, 1814. A(72.3) = 51.8, (oo) = 371; 1245. Acetylphenylglycine-o-carboxylic acid exo mono ethyl ester. Ci3Hi506N=C02H.C6H4.N(COMe)(CH2.C02Et). kiXlO* at 25°=3.8; m. p. 87°; 1245, 1814. A(40.8) = 43.6, (co) = 371; 1245. ^seudo-Acetylpyrrolecarboxylic acid see 2,5-Methylpyrrylketone car- boxylic acid. Acetylsalicylic acid see o-Acetoxy-benzoic acid. Acetyltoluidino-acetic acid see Acetyltolyl amino-acetic acid. a-Acetyl-o-toluidinobutyric acid. C13H17O3N = MeC6H4.N(MeCO) . CHEt.COsH. kAXlO^ at 25°=9.2; m. p. 116°. A(290) = 52.2, (1160) = 97.2, (oo) = 348; 1840. jS-Acetyl-o-toluidino-iso-butyric acid. Ci3Hi703N=MeC6H4.N(MeCO).CH2.CHMe.C02H. ki X 105 at 25°=2.1; m. p. 219°. A(480) = 33.5, (960)=44.6, (°o) = 348; 1840. a-Acetyl-p-toluidinobutyric acid. C13H17O3N. kA X 10* at 25°= 1.07; m. p. 149°. A(300) = 56.4, (1200) = 105, (oo) = 348; 1840. o-Acetyl-p-toluidino-jso-butyric acid. C13H17O3N. ki X 10* at 25°=9.5; m. p. 146°. A(280) = 52.0, (1120) = 96.3, (oo) = 348; 1840. Aco] TABLES 53 ^-Acetyl-p-toluidino-iso-butyric acid. C13H17O3N. kAXlO^ at 25°=2.29; m. p. 206°. A(386) = 31.2, (1544) = 59.6, (oo) = 348; 1840. a-Acetyl-o-toluidinopropionic acid. Ci2Hi603N=(MeC6H4)N(MeCO).CHMe.C02H. kA X 10^ at 25°= 1.04; m. p. 177°. A(300) = 55.7, (1200) = 103, («>) = 348; 1840. a-Acetyl-p-toluidinopropionic acid. C12H16O3N. kA X 10< at 25°= 1.04; m. p. 166°. A(300) = 55.7, (1200) = 103, (co) = 348; 1840. Acetyl-o-tolyl amino-acetic acid. (Acetyltoluidino-acetic acid. Acet- yl-o-tolyl glycine). CiiHi303N=(MeC6H4)N(MeCO).CH2.C02H. kAXlO^ at 25°=2.19; m. p. 210°-212°; 1840; m. p. 214°; 1245. A(194) = 65.1, (1552) = 152.3, (co) = 352; 1840. Acetyl-p-tolyl amino-acetic acid. (Acetyl-p-tolyl glycine). C11H13O3N. kAX 10^ at 25°= 2.19; m. p. 175°-176°. A(200) = 66.5, (800) = 120, (co) = 352; 1840. Acetyltolyl glycine see Acetyltolyl amino-acetic acid. Aconitic acid. C6H606=C02H.CH2.C(C02H):CH.C02H. kiXlO' at 19°=1.3 aq.; 164. At 25°=1.36; m. p. 180°-183°; 1839. = 1.58; 1859. [It is possible that the disagreement of the values of k here, is due to the fact that different aconitic acids were measured. See under Aconitine.] Second kAXlO^=3.5 (cond.); 1911. At 25°, A'(32) = 66.4, (1024) = 251, (oo) = 353; 1839. ^(28.1) = 67.0, (899.2) = 249.0, (co) = 353; 1859. Also 172. Cond. with KOH; 172. InNHs, qual.; 606. Salts. 3Mg.2A; 1836. - 3K.A; 164, 495. - 3Na.A at 25°, m(32) = 81.8, (1024) = 109.6; 1367. ^seudo-Aconitic acid. (cis-frans-Trimethylene-l,2,3-tricarboxylic acid) . CeHeOe. 3 Na.A at 25°, ai(32) = 84.3, (1024) = 113.9; 1369. Aconitine. C33H45O12N and C34H47O11N. [The composition of aconi- tine from different sources varies, depending apparently, both on the species and also on the locality in which the plant grows. See Dunstan, Henry, Jour. Chem. Soc. 87, 1650, (1905). See F. 0. Taylor, Jourl Indust. Eng. Chem. 1, 549, (1909), foE references to recent literature on this subject.] ks X 10^ at 15°=3 (hydrol.); 1779. In HCN, small cond.; 943. B.HCI at 25°, A(32) = 72.4, (1024) = 83.9; 270. 54 TABLES [Acr Acridine. C13H9N. B.Mel; 763. Acridine Yellow. (2,7-Dimethyl-3,6-diamino-acridine). CisHibNs. B.HCl at 25°, A(1024) = 86.5; 882. AcryUc acid. C3H402= CH2 : CH.CO2H. kAX 10^ at 25°= 5.6; aq. used for soln. was impure. A(32) = 14.7, (1024) = 73.0, (oo) = 360; 1371. Na.A at 25°, A(32) = 71.0, (1024) = 81.7; 1368a. Adipicacid. C6Hio04=C4H8(C02H)2. kAXlO^ at 18°=4.2, (colorim.); 1563. At 25°=3.65; m. p. 147°; 279. This acid is probably the purest that has been meas- ured. The other measurements approximate 3.75; 1371, 1638, 1810. Second kAX 10^=3.2, (inversion); 1335; = 2.4; 1638. At 25°, At(32) = 11.9, (1024 = 61.7, (oo) = 352; 279. Cond. with organic acids; 1638. 2Na.A, at 25°, A(32) = 75.7, (1024) = 90.9; 270. Adipic acid anhydride. CeHgOs. Cond. of soln. showing change to acid; m. p. 98°; 1810. Adipic acid mono ethyl ester. C8Hi404=C4H8(C02H)(C02Et). kA X 10^ at 25°=2.5 (?), not perfectly pure. A(93.0) = 17.3, (1488.0) = 57.1, (co) = 351; 1869. Alanine see Aminopropionic acid. Alaninetoluric acid see Methylbenzoyl amino-propionic acid. Alanyl-aminoacetic acid. (Alanyl glycine). CBHio03N2=MeCH(NH2)CO.NH.CH2.C02H. kAX 108 at 25°= 1.8 (catal.). ksXlO" at 25°=2 (catal.); 519, 522. Cond. with NH4OH and HCl; 522. Alanyl glycine see Alanyl-aminoacetic acid. Albumin; egg albumin etc. [The references are not complete.] X at 18° is of the order of 1 XlO^^; 1225. At 16°, 25° and 42°; 2032. Cond. in aq.; 1207, 1225a, 1258, 1289a, 1973a, 1983, 2032. See also 1393, 1394, 1395, 1396. Qual.; 1618c. Cond. with inorg. compounds; 52a, 617a, 724a, 1137a, 1289b, 1973a, 1983. Qual.; 1618c. With organic compounds; 52a, 514a, 724a, 1289b, 2032. Cond. not affected by radium; 2031. H ion concentration; 375a, 1268b, 1259c, 1639b. See also Blood. 2-Aldehydo-3-nitrobenzoic acid. C8H605N=CHO.C6H3(N02).C02H. [CH0=2; N02=3; C02H=1.] AU] TABLES 55 kAXlQS [at 25°]= 1.3; m. p. 156°-157°. A(128) = 4.8, (1024) = 13.6, (oo) = 378; 1684. 2-Aldehydo-5-nitrobenzoic acid. CsHsOsN. kiX 10* at 25°= 1.0; m. p. 159°-160°; k diminishes on diln. A(128)=40.5, (1024) = 101.8, (oo) = 378; 1684. Alizarin. (1, 2-Dihydroxy-anthraquinone). Ci4H804= Ci4H602(OH)2. kAXlO' at 18°-19°=8.8 (colorim.); 1561, 1562. Resistance; 983a. In NHs, qual.; 606. - In MeNHa, small cond.; 637. Alizarin cyanin see Pentahydroxy-anthraquinone. Alkali Blue. [Structure not given. Probably it is triphenyl-p- rosaniline mono sulphonic acid.] The purity of the com- pound was doubtful. Na salt at 90°, ai(200) = 212.4, (800) = 242.4; 976a. Allantoin. C4H6O3N4. kAXlO' at 25° =1.17 (catal.); 1996. Alio- see under head of next word, e. g. allocinnamic acid, see under aUo-Cinnamic acid. Allophanic acid amide. (Biuret). C2Hb02N3=NH2.CO.NH.CO.NH2. In HON, small cond.; 943. Cond. with HgCl2; 1097. AUoxan. C4H2O4N2. kAXl0'at25°=2.3; ai(64) = 2.2; 1996. At25°, m(32) = 16.6, (1024) = 25.2; 1748. Hgsalt; 963. Allozantine. C8H6O8N4. At 25°, m(256) = 46.4, (1024) =45.0; 1748. InNHa, qual.; 606. Allylacetic acid. (7, S-Pentenoic acid). C5H802=CH2:CH.CH2.CH2.C02H. kAXlO^ at 25°=2.13; diminishes on diln.; 571; - 564. A(32) = 9.9, (1024) = 50.2, (oo) = 380; 571. Na.A at 25°, A(1024 - 32) = 10 - 11; 571. AUyl alcohol. C3H60=CH2:CH.CH2.0H. xXlO« at 25°=6.5; 1106, 1107. In HBr; 29. In NH3, qual.; 606. Cond. with oxalic acid; 45. As solvent; 334, 1106, 1107, 1626. Ally! amine. C3H7N=CH2:CH.CH2.NH2. ks X 10^ at 0°=3.85. At 25°=4.6; 776; = 5.7 aq.; about 16% too high; 271. At 30°=4.84. At 35°=5.00. At 40°=5.10. At 46°= 5.06; 776. At 25°, m(32) = 8.9, (256) = 23.5, (oo)=209; 271. At 0°; 501. Cond. with KCl; 501. B.HCl at 25°, A(32) = 97.6, (1024) = 109.2; 270. 56 TABLES [All l-Allyl-4-hydroxy-3-methoxy-benzene see Eugenol. Allyl iodide. C3H6l=CH2:CH.CH2.I. In SO2, cond. is very small; b. p. 102-102.5°; 1829, 1842. Allylmalonic acid. C6H804=CH2:CH.CH2.CH(C02H)2. kAX 103 at 25°= 1.54; m. p. 102°. /*(32) = 70.9, (1024) = 249, (oo) = 356; 1838. p-Allyl phenol methyl ether see Anethole. Allylpropylmalonic acid. C9Hi404= CH2 : CH.CH2.CPr(C02H)2. IjaX 103=9.3; diminishes on diln.; m. p. 115°; 828. m(32) = 147.9, (512) = 291, (co) = 357; 831. Allyl-fso-propyhnalonic acid. C9H14O4. kAXlO^=1.46; diminishes on diln.; m. p. 107.5°, varies with mode of heating; 112.5° was the highest obtained; 828. m(32) = 171.3, (512) = 307, (oo) = 351; 831. Allylsuccinic acid. C7Hio04=C02H.CH2.CH(CH2.CH:CH2).C02H. kiX 10* at 25°= 1.09; m. p. 92°-93°. m(32) = 20.3, (1024) = 98.4, (oo) = 353; 1838. Allyl thiocarbimide. (Allyl mustard oil). C4H6NS=C3H5.NCS. % X 10^ at 25° is less than 4.3; b. p. 150.0° @ 737.8 mm.; 939;= 800; 1223. InNHs, qual.; 606. Cond. with organic compounds, and as solvent; 1223. - 939. Allylthiourea. CiHsNaS. InNHs, qual.; 606. Allyltriethyl- see Triethyl-allyl- Ahnond oil. [The references to this are not complete. ] K at 24°; 1010. Aluminum. Complex oxalate; 1615, 1516. See also the following compounds. Aluminum acetylacetone see under salts of Acetylacetone. Aluminum bromide complexes. AlBrs in EtBr; 1437. - AlBrs in nitrobenzene; 1444a. - AlBrs in Br, CS2 and CHCI3, no cond.; 1445. AlBr3.3C6H6 and AlBr3.3C7H8 in toluene; 1314. - AlBr3.Et20 in Br, CS2 and CHCI3, moderate cond.; 1446. - AlBr6C2H6BrCS2 in Br; 1446; in EtBr; 1437. - AlBr7CS2 in Br; 1446. Aluminum chloride. Cond. in various organic compounds; 1893. Aminoacetic acid. (Glycine. Glycocoll). C2H602N=NH2.CH2.C02H. kA X lOi" at 18°= 1700 aq. ; 164. At 25°= 1.8 (hydrol.) ; 1160 and 1984. = 3.4 (hydrol.); 1984 and 890. kfl X 1012 at 25°=2.8 (hydrol.); 1984 and 890, 1160. - (Colorim.); 1773, 1775. At 60° =28 (inversion); 1880 and 1150. Ami] TABLES 57 At 18°, A(100) = 1.13, (150) = 1.45, (oo) = 278; 164. At 25°, A(16) = 0.05; 590. Also 89, 145b, 1027, 1619, 1874. In NHs, qual.; 606. Cond.; alone, and saturated with COa; 145b, 1619. With NaOH and HCl; 590, 1318. With CUSO4; 88, 89. With Ba, Cd, Co, Cu, Mn, Ni, and Zn acetates and with HCl. Qual. with aminopropionic and piperidinoacetic acid; 1086. With or- ganic acids and esters, 145a, 145b. E. m. f. ; 1639b. Cu.2A; 1087. - Hg.2A; 1094; also 963. - K.A alone; with HCl; 164.- Na.Aat25°,A(32) = 73.6, (1024) = 84.2; M(32) = 76.2, (1024) = 102.0; 1984. See also 1639b. - B.HCl at 25°, A(32) = 106.4, (1024) = 117.4; M(32) = 183.0, (1024) = 352.3; 1984; - 1864. Effect on inversion of sugar; 1880. - 2B.H2SO4; 1864. Aminoacetic acid anhydride. (Diketopiperazine. Glycine anhy- dride). C4H6O2N2. kfl X 1015 at 18°= 1.8 [hydrol.?]. Cond. with NaOH and HCl; 523. Aminoacetic acid ethyl ester. C4H902N=NH2.CH2.C02Et. ksXlO^ at 15°-18°=9.7 (colorim.); 1775. At 25°, is stronger than the methyl ester; 891. Cond. with the acid; 145a. Aminoacetic acid methyl ester. C3H7O2N. kfl XlQS at 25° = 2.2 (catal.); 890. Aminoazobenzene. Ci2HiiN3=Ph.N:N.C6H4.NH2. ksXlQi^ at 25°=9.5 (part.); 548. B.Acetate; 145a. Aminobarbituric acid. (Uramil). C4H6O3N3. In NH3, qual.; 606. Aminobenzene siilphonic acid see Aniline sulphonic acid. o-Aminobenzoic acid. (Anthranilic acid). C7H702N=NH2.C6H4.C02H. kAXlO^ at 0° = 0.55. At 7.5°=0.66; 1968a. At 15° = 0.865 (sapon.); 1150. At 17°=0.99 aq.; 164. At 18°=0.88 - 1.1 (colorim.); 1563. At 25°= 1.04 (catal.); 414; = 1.06 (catal.); 1160; also 855. (Colorim.); 496, 1773. Electrical con- ductivity measurements give values of k increasing on diln. The mean for v(64) = 0.66, v(1024) = 0.96, v(2048) = 0.91; 164, 1371, 1868, 1968, 1968a, 1984. At 35°= 1.25 (sapon.); 1150; (cond.); 1968a. At 40°= 1.35 (sapon.). At45°=1.44 (sapon.); 1150. ksXlO'^ at 12.42°=0.62 (catal.). At 13.1°=0.66 (catal.). At 14.1°=0.72 (catal.); 1150. At 25°= 1.35 (catal.); 414, 1150; (part.); 648; (hydrol.); 1984. At 25.75°= 1.45 (catal.). At 34.15°=2.22 (catal.). At 36.77°=2.64 (catal.). At 36.91° = 2.69 (catal.). At 40°=3.16 (catal.); 1150. 58 TABLES [Ami Cond. At 15° to 45°; 1150. -At 0° to 35°; 1968. At25°. A(64) = 7.2, (1024) = 33.5, (<=°) = 355; 1371. Also 170. In HBr, no cond.; 30. In NH3, qual.; 606. Cond. with KOH; 170. Na.A, at 25°, A(32) = 67.8, (1024) = 78.5; 1984, 1368a, 1968a. - B.HCl, at 0°; 177. At 17°; 164. At 25°, A(32) = 100.2, (1024) = 111.2; M (32) = 194.5, (1024) = 360.8; 1984.-B.HN03; 177. o-Aminobenzoic acid ethyl ester. C9Hii02N=NH2.C6H4.C02Et. ksX 1012= 1.5 (catal.); (B.HCl has m. p. 168°); 414. o-Aminobenzoic acid methyl ester. C8H9O2N. ksX 1012=1.7 (catal.); (B.HCl has m. p. 135°); 414. m-Aminobenzoic acid. C7H702N=NH2.C6H4.C02H. kAXlO^ at 17°=0.99aq.; 164. At 25°=1.63 (catal.); 414;=1.67 (catal.); 855. - T not stated (colorim.); 1773. Electrical conductivity measurements give values of k increasing on diln. after an initial diminution. The mean for v(64) = 1.0, v(1024) = l.l; 164, 1371, 1868, 1984. See also 1374. ka X 10" at 25°= 1.3 (catal.); 414, 1984 and 1150. At 25°, A(64) = 9.4, (1024) = 35.2, (cx=) = 355; 1984. Also 170. InNHa, qual.; 606. Cond. with KOH; 170. Na.A at 25°, A(32) = 65.9, (1024) = 75.7; 1984, 1368a. - B.HCl; 164. At 25°, A(32) = 97.4, (1024) = 108.4; M (32) = 128.9, (1024) = 269.9; 1984. m-Aminobenzoic acid methyl ester. C8H902N=NH2.C6H4C02Me. ks X 10" at 25°=4.4 (catal.); 414. p-Aminobenzoic acid. C7H702N=NH2.C6H4.C02H. kAXlO^ at 0°=0.68. At 10.2°=0.95; 1968a. At 17°=1.2 aq.; 164. At 18°=0.99 (colorim.); 1563. At 25°=1.2 (catal. and hydro!.); 855, 890 and 1984. - T not stated (colorim.); 1773. Electrical conductivity measurements give values of k in- creasing on diln. The mean for v(64) = 0.71, v(1024) = 1.06, v(2048) = 1.13; 1371, 1868, 1968, 1968a, 1984. At 35°= 1.2; 1968a. ksX 1012 at 25°= 3 (hydrol.); 1984, 890; =2.3 (corrected); 1150. At 25°, A(64)=7.5, (1024)=35.0, (oo)=355; 1371. At 0°-35°; 1968. At 17°; 170. InNHs, qual.; 606. Cond. with KOH; 170. K.A; 164. - Na.A at25°, A(32) = 66.5, (1024) = 77.0; 1984. - B.HCl; 164, 1984. At 25°, A(32) = 98.7, (1024) = 109.7; M(32) = 170.2, (1024) = 344.2; 1984. Ami] TABLES 59 p-Aminobenzoic acid ethyl ester. C9Hii02N. = NH2.C6H4.C02Et. kfiXlQi^ at 25°=2.88 (catal.); m. p. 91°; 890. p-Aminobenzoic acid methyl ester. C8H9O2N. kfiXlQi^ at 25°=2.42 (catal.); m. p. 112°; 890. o-Aminobenzoyl-formic acid. (Isatinic acid. Isatoic acid). C8H703N=NH2.C6H4CO.C02H. Na.A, with HCl, cond. on standing; 443. o-Aminobenzoyl-formic acid anhydride. (Isatin). CsHsOaN. Cond. of aq. soln. too small to measure; 733, 754. In pyridine, at 25°, /x(32) = 0.02; 754. Na salt, cond. on standing; 443. p-Aminobenzyl sulphonic acid. CyHaOsNS^NHz.CeHi.CHa.SOsH. kAXl05at25°=2.34. A(128) = 18.9, (1024) = 50.6, (00) = 355; 492. Y-Aminobutyric acid. (Piperidic acid). C4H902N=NH2.(CH2)3.C02H. kiXlO" at 25°=3.7 (hydro!.). ke X IQi" at 25°= 1.7 (hydrol.). At 25°, A(32) is about 0.2. Cond. with Cu acetate. Na.A at 25°, M(64) = 94.8, (128) = 102.5; A(64) = 74. - B.HCl at 25°, M(64) = 123.1, (256) = 149.5; A(64) = 104; 1086. 8-AminocaSeine. (6-AminocaHeine. l,3,7-Trimethyl-8-amino-2, 6-dioxy-purine) . CsHuOzNs. kfiXlOi' at 40°=4.8 (catal.); 1995 and 1150. Aminocaproic acid. (Leucine). C6Hi302N=Me2.CH.CH2.CHNH2.C02H. kAXlQi" at 25°=1.8 (hydrol.); 1150 and 1984. = 3.1 (hydrol.); 1984. ks X 101=^ at 25°=2.5(hydrol.); 1150 and 1984. - (Colorim.); 1775. In NH3, qual.; 606. Cond. with CO2, with inorg. and organic acids and bases, and with esters; 145a, 145b. NH4.A; 145a. - Na.A at 25° A(32) = 62.4, (1024) = 73.4; M(32) = 67.8, (1024) = 97.6; 1984. - B.HCl at 25°, A(32) = 95.4, (1024) = 106.4; M(32) = 177.9, (1024) = 352.5; 1984. - (hy- drol.); 1775. B. Acetate; 145a. Aminocaproic acid ethyl ester. C8H17O2N. Cond. is greater than that of the acid; 145b. Cond. with organic acids; 145a, 145b. 3-Amino-2-chlorobenzoic acid. C7H602NC1=NH2.C6H3C1.C02H. [C02H=1]. kAX 10^=6.6; increases on diln. ; m. p. 158°. A(64.1) = 63.4, (1025.8) = 209.0, (oo) = 378; 846. 60 TABLES [Ami S-Amino-G-chlorobenzoic acid. C7H6O2NCI. kiX 105=9; increases on diln.; m. p. 188°-188.5°. A(64) = 21.8, (1024) = 99.2, (oo) = 378; 79; 2-Amino-4-chlorophenol. C6H60NC1=NH2.C6H3C1.0H. [0H=1]. Cond. with NaOH alone, and with HCl; 1508, 1718. 4-Amino-2-chlorophenol sulphonic acid. C6H604NC1S= (NH2)(C1)C6H2(0H)(S03H). kAXlO^at 25°=8.22. m(128) = 34.5, (1024) = 88.9, (a>) = 354; 492. 2-Ainino-4,6-dimtro-phenol. (Picramic acid). CeHsOsNg. Cond. in Et ale. alone, and with NaOH; 1508, 1718. Aminoethyl- see Ethylamino- Aminoformic acid see Carbamic acid. d-Aminoglutaric acid. (Amino-normoZ-pyrotartaric acid. d-Gluta- mic acid). C6H904N=C02H.(CH2)2.CH(NH2).C02H. kA X 10* at 25° =4. 12 (catal.); 855. =4.75; increases on diln.; 1838. ju(32) = 9.6, (1024) = 69.6, (co) = 352; 1838. At 39.4°; 145b. Cond. with organic acids; 145a. d-Aminoglutaric acid ethyl ester. C7H13O4N. Cond. with organic acids; 145a. inac/.-Aminoglutaric acid. (moc^-Glutamic acid.) C6H9O4N. IcaXIO^ at 25° = 4; increases on diln.; m. p. 198°; 1838, 1824. m(32) = 9.7, (1024) = 69.9, (00) = 352; 1838. Amino-hydrocinnamic acid see Phenyl-aminopropionic acid. p-Aniiiio-2-hydroxy-benzoic acid, (p- Aminosalicylic acid) . C7H7O3N. Cond. alone and with NaOH; dec. above 200°; 1508, 1718. 3-Amino-2-hydroxy-5-sulphobenzoic acid. (3-Amino-5-sulphosalicylic acid). C7H7O6NS. Cond. alone and with NaOH; 1508, 1718. Aminoisethionic acid see Taurine. Aminomalonic acid. C3H504N=NH2.CH(C02H)2. IcaXIO* at 25°=7.7; m. p. 108°-109°. m(32) = 51.9, (512) = 164, (oo) = 357; 1157. 8-Amino-l-naphthol-3,6-disulphonic acid. CioH907NS2=OH.CioH4(NH2)(S03H)2. kAX 10^=7 (colorim.); 1774. 5-Amino-l-naphthol-3-sulphomc acid. CioH904NS=OH.CioH6(NH2).S03H. kAX 10^=5 (colorim.); 1774. 6-Aniino-l-naphthol-3-sulphonic acid. C10H9O4NS. kA X 10*= 1 (colorim.) ; 1774. 6-Amino-2-naphthol-4-sulphonic acid. CioH904NS. kAX 10*= 2.2 (colorim.); 1774. Ami] TABLES 61 8-Amino-l-naphthoU4-sulphonic acid. C10H9O4NS. ki X 106=3.5 (colorim.); 1774. S-Amino-l-naphthol-S-sulphonic acid. C10H9O4NS. kxX 10^=1 (colorim.); 1774. Aminonaphthylnaphthinduline see Naphthalene Red. 3-Amino-5-nitrobenzoic acid. C7H604N2=NH2.C6H3(N02).C02H. kA X 10* at 25°=2.1; increases on diln. iu(83.3)=40.4, (1333.3) = 144.8, (oo) = 354; 175. 2-Amino-4-nitro-diphenyl-methyl amine. Ci3Hi302N3=Ph.NMe.C6H3(N02).NH2. kaXlQi^ at 25°= 5.0 (part.); 583. 3-Amino-5-nitro-2-hydroxy-benzoic acid. (3-Amino-5-nitro-salicylic acid). C7H606N2= (NH2)(N02)C6H2(OH)(C02H). kAXlO' at 25°= 1.33 (neutral.). Cond. alone and with NaOH in Et ale; m. p. 223°; 1508, 1718. 2-Amino-4-nitrophenol. C6H603N2 = NH2.C6H3(N02).OH. kAXl0'at25°=2.6. M(202.5)=2.6, (810) = 5.2, (cx>) = 354; 70. Amino-nitio-salicylic acid see Amino-nitro-hydroxy-benzoic acid. Aminophenazine (C12H9N3) see Phenosafranine. o-Aminophenol. C6H70N=NH2.C6H4.0H. kflXlQiOat 15°=2.18 (colorim.); 1777. Cond. alone and with NaOH; 1508, 1718; with HCl; 1508. In NH3, qual.; 606. o-Aniinophenol ethyl ether see o-Phenetidine. o-Aminophenol methyl ether see o-Anisidine. m-Aminophenol. CeHjON. Cond. alone and with NaOH and HCl; 1508, 1718. p-Aminophenol. CbHtON. keXlO' at 15°= 6.6 (colorim.); 1777. Cond. alone and with NaOH and HCl; 1508, 1718. in NH3, qual.; 606. B.HCl at 25°, ai(50) = 94.9. - B.H2SO4; 1864. p-Aminophenol ethyl ether see p-Phenetidine. p-Aminophenol methyl ether see p-Anisidine. 2-Aminophenol-4-sulphonic acid. C6H704NS=NH2.C6H3(OH).S03H. [0H=1; NH2=2; S03H=4]. kAXl05at25°=9.41. m(64) = 26.5, (1024) = 94.3, (oo) = 355; 492. Cond. alone and with NaOH; 1508, 1718. 4-Aminophenol-2-sulphonic acid. C6H7O4NS. kiXlO^at 25°= 8.3. m(256) = 16.0, (1024) = 31.3, (oo) = 355; 492 62 TABLES [Ami o-Aminophenyl ethyl carbonate. (Carbonic acid ethyl o-aminophenyl di-ester). C9Hii03N=Et02.CO.C6H4.NH2. kBXl0i2at0°=9 (hydrol.). B.HCl; 1660. o-Aminophenyl methyl carbonate. CsHgOsN. kBXlO"atO°=l (hydrol.). B.HCl at 0°, M(32) = 78.5, (256) = 125.6; m(32)=45.9; 1660. p-Aminophenyl ethyl carbonate. C9H11O3N. ks XlO" at 0°=2.7 (hydrol.). B.HCl at 0°, M(32) = 51.0, (256) = 66.3; ai(32)=43.8; 1660. p-Aminophenyl methyl carbonate. CgHgOsN. kB XlO" at 0°=2.8 (hydrol.). B.HCl at 0°, M(32) = 52.8, (256) = 67.5; /i(32)=45.9; 1660. 2-Amino-p-phthalic acid. (Aminoterephthalic acid). C8H704N=NH2.C6H3(C02H)2. [C02H=1,4; NH2=2]. kiXlO^at 25°=2.65. /i(512) = 115.3, (1024) = 152.3, (co) = 377; 1684. 2-Amino-p-phthalic acid 4-mono methyl ester. C9H904N= NH2.C6H3(C02H)(C02Me). [C02H=1; C02Me=4]. kAXlO^ at 25° = 5.52; m. p. 213°. Ai(512) = 58.1, (1024)=79.5, (oo) = 376; 1684. ?-Amino-p-phthalic acid ?-mono methyl ester. CgHgOiN. kAXlO* is about 1.5; m. p. 216°-217° (cor.); 1915. a-Aminopropionic acid. (a-Alanine). C3H702N=Me.CH(NH2).C02H. kAXlO"" at 25°=2 (hydrol.); 1086, 1984 and 1150.- T not stated, (colorim.); 1773. kBXlQi^ at 25°=3.1 (hydrol.); 1086; = 5.14 (hydrol.); 1150 and 1984. At 25°, A(64) = 0.3, (1024) = 2.6, (oo) = 350; 601; - 145b, 590, 1619. In NH3, qual.; 606. In SO2; 1842. Cond. of soln. saturated with CO2; 145b, 1619. With organic compounds; 145a, 145b, 1086. - With inorg. compounds; 590. Na.A at 25°, M(32) = 70.8, (1024) = 99.8; A(32) = 68.5; 1984; M(64) = 84.6; A(64) = 76; 1086. - B.HCl at 25°, M(32) = 166.5, (1024) = 341.3; A(32) = 106.5; 1984; M(64)=225; A(64) = 108; 1086. o-Aminopropionic acid ethyl ester. C6H11O2N. Cond. is greater than that of the acid; 145b. jS-Aminopropionic acid. (jS-Alanine). C3H702N=NH2.CH2.CH2.C02H. kAXlO" at 25° = 7.1 (hydrol.). ksXlO" at 25°=5.1 (hydrol.). Ami] TABLES 63 Cond. with organic compounds. Na.A at 25°, M(64) = 90.8, (512) = 121.4; A(64) = 76. - B.HCl at 25°, M(64) = 141, (128) = 158.3; A(64) = 108; 1086. p-Aminosalicylic acid see Amino-hydroxy-benzoic acid. Aminosuccinamic acid see Aminosuccinic acid mono amide. Aminosuccinic acid. (Asparaginic acid. Aspartic acid). C4H704N=C02H.CH2.CH(NH2).C02H. kiXlO* at 15.4°=1.15 aq.; 164. At 25°=1.4 (catal. and hydro!.); 855, 1150, 1984. Electrical conductivity measurements give mean value for v(32) = 0.67, for v(1024) = 1.3; 1838, 1984 and 1673. - (Colorim.); 1773. ksXlQi^ at 25°= 1.2 (hydrol.); 1150 and 1984. Cond.; 145a, 166, 1227. At 25°, m(32) = 16.1, (1024) = 109.4, (°o) = 354; 1838. Cond. with inorg. acids, bases and salts; 145b, 166, 167, 1184, 1227, 1984. - With organic acids, esters, and salts; 44, 145a, 145b, 167. Na.A at 25°, m(32) = 66.1, (1024) = 75.9; 1984; also 166, 167, 1227. - K.A. and 2K.A; 164.- K.A.; 1227.- B.HCl at 25°, m(32) = 97.4, (1024) = 108.4; M(32) = 211.9; 1984; 1864. - 2B.H2SO4; 1864. Aminosuccinic acid mono amide. (Aminosuccinamic acid. Aspara- gine). C4H803N2 = CONH2.CH2.CH(NH2).C02H. kAXlC at 14.8°=0.69 (sapon.). At 15°=0.72 (sapon.). At 18°=0.88 (sapon.). At 25°=1.35 (sapon.); 1150; = 5.2 (hydrol.); 1984; =25 ; diminishes on diln. (cond.); 1838, 1984. At 28.1°= 1.84 (sapon.). At 35.0°=2.40 (sapon.). At 40°= 3.15 and 3.22 (sapon.); 1150. keXlQi^ at 15°=0.68 (sapon.). At 15.82°=0.74 (sapon.). At 25°=1.53 (sapon.); 1150. = 1.8 (hydrol.); 1984. At 35°=3.20 (sapon.). At 40°=4.23 (sapon.); 1150. At 60°= 19.0 (in- version); 1880 and 1150. At 25°, A((32) = 0.3, (256) = 0.9, (oo) = 355; 1984; - 590, 1838, 1868. Qua!.; 1584. In HCl, no cond.; 30. In NH3, qual.; 606. Cond. with NaOH and HCl; 590, 1318. With KCl; 590. Na.A at 25°, m(32) = 65.3, (1024) = 76.3; M(32) = 66.7, (1024) = 82.7; 1984. - B.HCl at 25°, ai(32) = 98, (1024) = 109; M(32) = 196.3, (1024) = 361.2; 1984; 1864. Effect on inversion of sugar; 1880. - 2B.H2SO4; 1864. 2-Amino-4-sulphobenzoic acid. C7H706NS= NH2.C6H3(S03H).C02H. [C02H=1; NH2=2; S03H=4.] kxXlO^ at 25°=3; diminishes on diln. /i(150) = 312.5, (1200) = 356.4, (00) = 377; 456a. 64 TABLES [Ami 4-Amino-2-sulphobenzoic acid. CjHjOsNS. [C02H=1; NH2=4;S03H=2.] IsaXIO^ at 25°=3; diminishes on diln. iu(150) = 187.8, (1200) = 302.4, (cx=) = 377; 456a. 4-Ainino-3-sulphobenzoic acid. CtStObNS. [C02H=1; NH2=4; S03H=3.] IcaXIO^ at 25°= 8; diminishes on diln. Ai(150) = 349.6, (600) = 360.0, (od) = 377; 456a. 6-Aimno-2-sulphobenzoic acid. CtHtOsNS. [C02H=1; NH2=5; S03H=2.] IcaXIO' at 25°=6; increases on diln. Ai(150) = 214.5, (1200) = 332.4, (oo) = 377; 456a. 5-Aiaino-3-sulphobenzoic acid. C7H7O6NS. [C02H=1; NH2=5; S03H=3.] IjaXIO^ at 25°=2; diminishes on diln. Ai(150) = 165.7, (1200) = 302.4, (oo) = 377; 456a. Aminosulphonic acid. NH303S=NH2.S03H. [The references to this are incomplete.] IjaXIO at 25°=1; diminishes on diln.; m. p. about 205°; 1557, 1984. AJ(32) = 294.7, (1024) = 363.7, (od) = 371; 1984. Na.A at 25°, m(32) = 81.5, (512) = 91.9, (1024) = 94.2?; 1984 - ; 1557. - B.HCl; 1984. Amino-sulphosalicyUc acid see Amino-hydroxy-sulphobenzoic acid. 6-Ainino-l,2,3,4-tetrazole. (Aminotetrazolic acid. Aminotetrazotic acid). CH3N6=NH2.C.N4H. kAXlO' at 0°=3.12. At 10°=4.16. At 18°= 5.4. At 20°= 5.73. At25°=6.6. At30°=7.44. At 40°=9.14; 143, and Lund6n, ' Affinitatsmessungen, and 142. At 25°, m(32) = 1.9, (1024) = 11.6, (oo) = 354; 1720, 142. In pyridine; 754. Na salt, at 25°, m(32)=78.7, (1024) = 93.3; 142, 143, 1720. At 0°-40°; 143. Aminotetrazotic acid see Aminotetrazole. l-Amino-l,3,4-triazole. {iso- or N-Dihydro-tetrazine). C2H4N4. ksXlOi^ at 25°= 1.77 (sapon.); m. p. 151°; 428. Amino-xylene see Xylidine. Ammonchelidonic acid. (4-Hydroxy-pyridine-2,6-dicarboxylic acid). C7H605N=OH.C5H2N.(C02H)2. At 25°, m(170.5) = 367, (1364) = 546; 1372. Ammonia. NH3. [The references to this are incomplete. ] x&t -33°isbelow lXlO-5; 610. At -20°=1.6X10-*; 678. Ammonium hydroxide. NH4OH. [The references to this are in- complete. ] Amy] TABLES 65 kBXlO«at.O°=sl3~9. At 18° = 17.2. At 25° =,18,0. At50°=18.1. At75°=l6;4.- At 100°=13.5. Atl25° = io.4. At 156°=6.28. At 218°=1.80. At 306° = 0.093; 1332. - Also 165, 271, 649, 660, 776, 949, 1144, 1283, 1341, 1363. Cond. Under pressure of 1 to 500 atmospheres; 220. - Of mix- ture with diacetone alcohol; 979. - See also 48 and 1631. Amniotic fluid. [The references to this are incomplete. ] Concentration of H and OH ions; 587. Amygdalin. C20H27O11N. In NH3, qual.; 606. Amygdalinic acid see Phenylglycollic acid. norm.-Amyl alcohol. C6Hi20=C6Hii.OH. xXlOS at 17°=6.9. As solvent; 787. iso-Amyl alcohol. (Pentyl alcohol.) C6H12O. xxW^ at 17.1° = 3.2; 1900. At 18°=5; 647, 478; also 362, 438, and 1472. At 20°=4.3; 1590a; 783; - 1316. At 25°=50; 1569; - 21 and 20. - T not stated; 305. In HBr; 29. In NH3, qual.; 606. Cond. under pressure of 100 atmospheres; 1472. Under pres- sure, as solvent; 1590a. With Cu oleate; 1569. As sol- vent; 20, 334, 438, 472, 483, 647, (783), (1477), 1569, 1590a. iso-Amyl amine. C5Hi3N=C6Hu.NH2. xXlO^ at 25°, is less than 2; b. p. 96°; 1388; - 942, 943. ks XlO* at 25°= 5 aq.; about 16% too high; 271. At 25°, m(32) = 24;3, (256) = 59.1, (oo) = 201; 271; 1363. In HCN; 943. In NH3, qual.; 606. Cond. As solvent; (942), 1388. With organic compounds; 1388. B.HCl at 25°, A(32) = 90.3, (1024) = 101.3; 270. Amylase. Cond. of aq. soln.; 590. Amyl bromide. CsHnBr. xXlO' at 25° is less than 2; b. p. 118.5°-119° @ 742 mm.; 1388. In NH3, qual.; 606. Cond. with inorg. and organic compounds; 1388. fso-Amylbrucinium chloride. (Brucine iso-amylochloride). C28H3704N2Cl = B.N.(CBHn)Cl. At 25°, A(64) = 79.8, (1024) = 89.8; 270. norm.-Amylene. CbHiq. xXlO^ at 25° is less than 2; b. p. 40° @ 724 mm.; 1388. Cond. affected by radium and X-rays; 417. With other com- pounds; 1388. 66 TABLES [Amy Amyl ether. (Diamyl ether). CioH220 = (C6Hii)20. In NH3, qual.; 606. Amyl iodide. C5H11I. ?<: XlQS at 25° is less than 2; b. p. 127°-128° @ 740 mm. Cond. with inorg. and organic compounds; 1388. iso-Amylisethionic acid. (Hydroxy-amyl sulphonic acid). C6Hi204S=C5Hio(OH).S03H. kA X 10^ is approximately 4. The acid is 97% dissociated at v(256). A(1024-32) of the salts shows that the acid is monobasic; 394. iso-Amyl mercaptan. (Amyl sulphhydroxide). C6Hi2S=C6HiiSH. xXW^ at 25° is less than 2; b. p. 115° @ 742.8 mm.; 1388. In HON, no cond.; 943. Cond. with inorg. salts; 149, 1388. With organic compounds; 1388. Amylmethyl- see Methylamyl- Amyl nitrate see Nitric acid amyl ester. Amyl nitrite see Nitrous acid amyl ester. Amylsulphhydrate see fso-Amyl mercaptan. Amyl sulphhydroxide see fso-Amyl mercaptan. Amyl thiocyanate see Thiocyanic acid amyl ester. jso-Amyltriphenyl phosphonium chloride. C23H26C1P= (C6Hll)(Ph3)P.Cl. At 25°, A(32) = 77.1, (1024) = 88.5; 270. Anethole. (p-AIlyl phenol methyl ether). C10H12O. InNHs, qual.; 606. Angelic acid. C6H802=Me.CH:CMe.C02H. kAXlO^ at 25°= 5.01; 1371 and 1368. A(32) = 13.9, (1024) = 71.9, (oo) = 355; 1371. Na.Aat25°, A(32) = 66.3, (1024)=76.0; 1368a. Anhydroecgonine. C9H13O2N. ksXlQii at 14°= 3.68 (colorim.); 1778. Anil- see AniUno- Anilido- see AniUno- Aniline. C6H7N=Ph.NH2. XX 10^ at 18° to 25°= 1. At 18°=0.92; 1900, 1472. At 20°=6; not purified; 1316. At 25° is less than 2; 1388. Also 305 and 1477. keXlOi" at 12°=2.6 (colorim.); 1777. At 15°=3.1 (hydrol.); 1143, (colorim.); 1777. At 18°=3.5 (hydrol.); 436, 532. At 25°= 5; (hydrol.); 270, 271, 436, 660, 1043, 1116, 1143, 1150, 1293; - (part.); 548; - (solub.); 660, 1116.=4.2 (col- orim.); 1729b. Electrical conductivity measurements; 269, 1241. At 40° = 7.6 (hydrol.); 1143, (catal.); 19 and 1150. At 60°= 17.1 (inversion); 1880 and 1150. Ani] TABLES 67 [At 25°], A(25.6)=0.10, (51.2) = 0.16; 269. Also 145a, 145b. In HON, no cond.; 943. In HBr and HI, small cond.; in H2S, no cond.; 1897. In NH3, small cond.; 610 and 606. In benzene, no cond.; 1802, 1803. Cond. under pressure of 100 atmospheres; 1472. Of thin layer; 301. With organic acids; 145a, 145b, 169, 513, 532, 1011, 1388, 1802, 1900. With organic bases; 1388. With Cu oleate; 1569. With xylene; 1900. As solvent; 480, 1552a, 1569, 1900. B.HBr, in organic solvents; 1552a. - B.HCl at 25°, A(32) = 99.7, (1024) = 147.5; 1327; A(64) = 96, (1024) = 103.3; M(64) = 106.2, (1024) = 144.0; 270.- 19, 165, 271, 434, 435, 734, 1143, 1659, 1791, 1864, 1880. Effect of diazotization on cond.; 1601. - B.H2SO4; 1327, 1864. - B.Acetate; 44, 145a, 145b, 165, 1143, 1791, 1802, 1803, 1864. - B.Benzoate; 1802, 1803. - B.Maleate; 145a. - B.iso-Nitrosomethylpyra- zolone; 1143. - B.Picrate-; 1802. - B.Salicylate; 145a, 532. Amline-2,4r-disulphomc acid. C6H706NS2=NH2.C6H3(S03H)2. kA is between k of m- and p- Aniline sulphonic acids, (colorim.); 1773. o-AniUne sulphonic acid. (o-Aminobenzene sulphonic acid). C6H703NS = NH2.C6H4.S03H. [NH2=1; S03H=2.] kA X 10' at 25°=3.3; diminishes on diln.; 1372. Cond.; 456a. At 25°, A(64) = 130.4, (1024) = 286.9, (oo) = 356; 1372. In NH3, qual.; 606. m-Aniline sulphonic acid. (Metanilic acid). CeHrOsNS. [S03H=3.] kAXlO^ at 0°=0.90. At 12°=1.34; 1968a. At ?5°=1.99; 1968a; = 1.85; 1372. - (Colorim.); 1773. At 35°=2.62; 1968a. At 25°, A(64) = 36.5, (1024) = 123.5, (co) = 356; 1372. A(1024) = 125.8, (00) = 351; 1968a. InNHs, qual.; 606. p-Aniline sulphonic acid. (Sulphanilic acid). CeHyOsNS. [S03H=4.] kAXlO* at 0°=3.3. At 6.3°=4.0; 1968a. At 25°=6.6; 1968a, 1968; = 5.9; 1984, 1372. - (Colorim.); 1773. At 35°=8.2; 1968a. Cond. at 0° to 35°; 1968, 1968a. At 25°, A(32) = 45.5, (1024) = 188.6, (oo) = 356; 1372. A(1024) = 193.0, (co) = 351; 1968a. - 456a, 1984. In NH3, qual.; 606. Na.A at 25°, A(32) = 68.1, (1024) = 78.3; 1984; 1968a. - B.HCl at 25°, M(32) = 384; 1984. Anilino-acetic acid see Phenylamino-acetic acid. 68 TABLES [Ani Anilinoacetic-acid-o-carboxylic acid see Phenylglycine-o-carboxylic acid. a-Anilinobutyric acid. CioHi302N=Et.CH(NHPh).C02H. IcaXIOS at 25° = 3.2; m. p. 140°; increases on diln. A(130) = 19.8, (1040)^58.4, (oo) = 350; 1840. a-AniUno-iso-butyric acid. CioHi302N = Me2C(PhNH).C02H. Wal- den calls this an Anilinobutyric acid. kxX 10^ at 25°=3.9; increases on diln.; m. p. 142°. A(200) = 27, (800) = 56.4, (tx>) = 350; 1840. Anilino-iso-butyric acid. C10H13O2N. kiXlO^at 25°=8; m. p. 178°-182°; impure?; 1840. |3-AniUno-iso-butyric acid. CioHj302N=(Ph)NH.CH2.CHMe.C02H. Ica X 10^ at 25°= 1.1; increases on diln.; m. p. 185°. A(200) = 4.9, (800) = 10.2, (oo) = 350; 1840. Anilinochlorooxalic acid see Chloro-oxanilic acid. Anilinochlorosuccinic acid see Chlorosuccinanilic acid. Anilinodiacetic-o-carboxylic acid. CiiHii06N = C02H.C6H4.N(CH2.C02H)2. kAXlO^ at 25°=3; increases on diln.; m. p. 212°; 1245, 1817, 1301. A(74.6) = 138.7, (596.6) = 305.4, (oo) = 372; 1245. Anilinofumaric acid see Fumaranilic acid. Anilinoglyoxylic acid see Diamino-stilbene dicarboxylic acid. Anilinomalonic acid see Malonanilic acid. AnUinooxalic acid see Oxanilic acid. a-Anilinopropionic acid. (Plienyl-a-alanine). C9Hii02N=Me.CH(NHPh).C02H. kAXlO^ at 25°=2.2; increases on diln.; m. p. 162°. A(136) = 18, (1088) = 50.3, (co) = 353; 1840. /3-Anilinopropionic acid. ( Phenyl- jS-alanine). C9Hii02N=PhNH.(CH2)2.C02H. kA X 10^ at 25°=4.2; increases on diln.; m. p. 59°-60°. A(200) = 9.4, (800) = 19.8, (c=o) = 353; 1840. Anilinosuccinic acid see Succinanilic acid. Aniloantipyrine see Amlopyrine. Anilopyrine. (Aniloantipyrine. 2,3-Methyl-l-phenyl-2,5-phenyli- minopyrazole). C17H17N3. Cond. at 18° is about one half that of Benzyliminopyrine; m. p. 79°-80°; 1256. Animals. [The references to this subject are incomplete.] Cond. of the body fluids of various animals; 250, 253, 634a. See also separate heads, as. Blood, Heart, etc. Anisaldehyde see Anisic aldehyde. Ani] TABLES 69 ) = 353; 54. K.A. - Na.A at 25°, A(32) = 61.6, (1024) = 75.5; 54. Anisole sulphonic acid see Methoxy-benzene sulphonic acid. Anisuric acid. CioHii04N=MeO.C6H4.CO.NH.CH2.C02H. kiXlO^ at 25°= 1.62. /i(716.9) = 100.8, (1433.8) = 132.9, (oo) = 350: 601. 70 TABLES [Ant Anthracene. C14H10. Resistance when solid and when molten; 983a. In MeNHz, no cond.; 637. In SO2; 1842. Vapor at 200°-250°, no cond. under diminished pressure; 859a, Anthranilic acid see o-Aminobenzoic acid. Anthraquinone. C14H8O2. In MeNHa, no cond.; 637. Antimony compounds see Tetraethyl and Tetramethyl stibonium hydroxide, and Trimethyl and Triphenyl stibine. Antipeptone a. (Trypsinfibrinpeptone a). CioHiyOsNs. Cond. in aq. soln. Cond. with NaOH and HCl. Na salt, m(32) = 72.98, (1024) = 90.8; 1318. Antipeptone /3. (Trypsinfibrinpeptone /S). CnHigOsNs. Cond. in aq. soln. Cond. with NaOH and HCl. Na salt, m(32) = 82.2, (1024) = 104.7; 1318. Antipyrine see 2,3-Dimethyl-l-phenyl pyrazolone. ApioUc acid. CioHio06=CH2:02:C6H(OMe)2.C02H. [0Me=2, 5; CH202=3, 4.] kAXlO^ at 25°=8.03 aq.; m. p. 175°. /i(1320) = 97.5, (oo) = 352; 23. Apionketonic acid see Apionylglyoxylic acid. Apionylglyoxylic acid. (Apionketonic acid). CnHio07=CH2:02:C6H(OMe)2.CO.C02H. kA X 102 at 25° = 3.35 aq.; m. p. 160°-172° dec. m(91.2) = 278.8, (729.9) = 335.3, (o=) = 351; 23. Cond. not increased by boric acid; 1186. Apocamphoric acid see Camphopyric acid. Arabinose. CsHioOe. In NH3, qual.; 606. Argenti- see under Silver., Argento- see under Silver. Arginine. (Guanidine-a-aminovaleric acid). C6Hi402N4=NH:C(NH2).NH.(CH2)3.CH(NH2).C02H. kAX 10" at 25° is over 1.11 (sapon.). kB X 10' at 25° is less than 1.0 (sapon.). Second ks X lO'^ is less than 2.2. Na salt at 25°, m(32) is about the same as that of NaOH; 948. Arsenic see Cacodylic acid, Methyl arsenic acid, Tetraethyl arsonium hydroxide, Tetramethyl arsonium hydroxide, Trimethyl arsine, Triphenyl arsine. - In complex salts. With tartaric acid. KASC4H4O6, /t(25) = 91.97, (1600) = 186.4; 938. Azo] TABLES 71 Arum italicum. [The references to this are incomplete.] Cond. of the fruit; 1326. Asparagic acid see Aminosuccinic acid. Asparagine see Aminosuccinic acid mono amide. Asparaginic acid see Aminosuccinic acid. Aspartic acid see Aminosuccinic acid. Aspirin see o-Acetoxy-benzoic acid. Atropic acid. (a-Phenylacrylic acid.) C9H802=CH2:CPh.C02H. kiXlO^at 25°= 1.43. A(128) = 45.8, (1024) = 111.4, (oo) = 352; 1371. iso-Atropic acid see Truxillic acid. Atropine. C17H23O3N. ks X 10' at 14°-18° is over 1 (hydrol.); 1778. At 25°, m(200) = 34.6, (800) = 43.7; 1864. InHCN, fair cond.; 943. With allyl thiocarbimide, no cond. ; 1223. Auramine. C17H21N3. Auramine; saturated soln. has no conductivity. Auraminium hydroxide is a strong base, changing on standing to the weak carbinol, auramine; 770. Auramine G. (Imino-dimethyl-diamino-di-o-tolylmethane). HN : C(Me.C6H3.NHMe)2. At 25°, Ai(1024) = 48.3 at once, = 35.4 after 56 minutes; also cond. at 0°. B.HCl at 0°, m(512) = 50.3. At 25°, m(512) = 96.5; 2006, 770. Auramine 0. (Imino-tetramethyl-diamino-diphenyl-methane). HN:C(C6H4.NMe2)2. | At 25°, ;u(1024)=43.7 at once, = 30.8 after 60 minutes; also cond. atO°. B.HCl at 0°, m(512)=77.6. At 25°, m(512) = 136.0; 2006. In 2006 it is stated that Hantzsch, in a letter, wrote that the measurements of 770 may have been made with Auramine G. Azelaic acid. C9Hi604=C02H.(CH2)7.C02H. kAXlO^ at 18°=2.6 (colorim.); 1563. At 25°=2.53 aq.; m. p. 106°-106.5°; 1638; = 2.96; 175, 1810. Second kiX 10^=2.4 (cond.), = 3.3 (part.); 370; also 1638, 1911. At 25°, ;u(68.2) = 14.3, (1091) = 55.1, (oo) = 350; 1638. NaH.A at 25°, /x(32) = 68.9, (1024) = 85. - 2Na.A at 25°, fi{32) = 75, (1024) = 91; 370. Azelaic acid anhydride. C18H30O7. Cond. of aq. soln., showing change to acid; 1810. Azobenzene. Ci2HioN2=PhN:NPh. In HBr, poor cond., in HI, no cond.; 1897. In H2S, no cond.; 27, 1897. In MeNH2, no cond.; 637. 72 TABLES [Azo Azobenzene-p-sulphonic acid. Ci2Hio03N2S = Ph.N2.C6H4.S03H. In pyridine at 25°, A(32) = 8.68; in 50% pyridine, A(28) = 36.2; 754. Azoimide see Hydrazoic acid. Azooxybenzene. Ci2HioON2=Ph.NON.Ph. In HBr, poor cond., in HI and H2S, no cond.; 1897. p-Azophenol. (4,4'-Dihydroxy-azobenzene. Quinone-p-oxyphenyl- hydrazone). Ci2Hio02N2=OH.C6H4.N2.C6H4.0H. Na.A at 25°, m(32) = 67.6, (1024) = 79.7; 546. Azophenosafranine see asj/m.-Phenosafranine. Azotetrazole. C2H2Nio= N4H.C.N2.C.N4H. 2Na.A at 25°, At(32) = 86.8, (1024) = 103.6; 142. B. Barbituric acid. (Malonyl urea). C4H4O3N2. kA X 10* at 25°= 1.0; 1748, 1996. iu(32) = 19.5, (1024) = 97.0, (°o) = 358; 1748. - 782. Cond. in Et ale. ; 782. Na.A at 25°, m(32) = 64.5, (1024) = 74.5. - 2Na.A at 25°, m(32) = 92.0, (1024) = 123.0; 1748. Begonia semperflorens. [The references to this are incomplete. ] Cond. of stem; 1326. Benzalanisal- see Methoxy-dibenzal- Benzaldehyde. C7H60 = Ph.CHO. xXlO^ at20°=4.9; 1590a. At 25°=1.6; 1843. = 4.5; 941; = 10; 1388. kiX 10" at 18° is about 1.2 (hydroL); 532. In HBr and HI, good cond.; in H2S, no cond.; 1897. In HCl, qual.; 16. In HCN, no cond.; 943. In NH3; 607. In Et ale; 1654. In MeNH2, fair cond.; 637. Cond. with HCl, qual.; 1553. With NaOH; 532. With KCN; 1654. As solvent; (941), 1388, 1590a, 1844. As solvent, under pressure; 1590a. Benzalmalonic acid. CioH804= Ph.CH : C(C02H)2. kiXlO^at 25°=4.08; 1372. Second kiX 106= 3.2 (cond.); jgn^ At 25°, m(32) = 106.7, (1024) = 294.1, (oo) = 353; 1372. Benzalpiperonal acetone. C18H14O3. Comparative strength (colorim.) ; 1663. Benzalpiperonal cyclopentanone. C20H16O3. Comparative strength (colorim.); m. p. 176°; 1663. iso-Benzalpiperonal cyclopentanone. C20H16O3. Comparative strength (colorim.); m. p. 192°; 1663. Ben] TABLES 73 Benzamide see Benzoic acid amide. Benzanilide. C13H11ON. In NH3, qual.; 606. Benzbetaine see under Trimethyl-aminobenzoic acid. Benzene. CeHe. Pure, no cond.; 935, 978, 1098. xXW^ at 25° is less than 2; b. p. 79.4°-79.5° @ 746.9 mm.; 1388; also 306, 384, 386, 872, 1010, 1830. In HCN, no cond.; 943. In NH3, qual.; 606. Cond. with organic compounds; 383, 384, 386, 935, 941, 1021, 1223, 1388, 1569, 1893. As solvent; 289, 431, (842), 935, 941, 1021, 1388, 1435, 1569, 1712, 1797, 1801, 1802, 1830, (1893). At critical point; 107, 133. As affected by long continued current; 1605. As affected by X-rays and rays from radium; 417, 872, 1491. Of thin layer; 301. Benzeneazodibromo-phenol see Hydroxy-dibromo-azobenzene. Benzeneazophenol see p-Oxy-azobenzene. Benzene- l-carboxylic-acid-amide-2-methylcarboxylic acid see Hom- ophthalic acid 1-mono amide. Benzene diazonium hydroxide. (Diazo benzene). C6H60N2=Ph.N2.0H. kB X lO' at 0°=1.23; 425, 501. m(31.9) = 24.9, (517) = 73.2, (oo) = l39.7; 425. Cond. with NaOH; 425. Na.A at 0°, ai(60) = 71.2, (650) = 147.2; 425. - B.Br, cond., and cond. with HBr at 0°; 425. Cond. at 1°; 730. - B.Cl, cond., and cond. with HCl and HI at 0°; 425. Cond. at 1°; 425, 730. - B.NO3, cond. at 0°; 425. At 1°; 425, 730. - B.CN; 735. Benzene sulphinic acid. C6H602S=Ph.S02H. kiXlO^ at 18°=4.4; 54. At 25°=3.5; 54, 1134. At 30°=2.7; 54. Diminishes on diln. in all these measurements. At 25°, A(34.4) = 229, (274.8) = 316, (co) = 356; 1134. Benzene sulphocyamic acid see Benzene sulphonic acid cyanoamide. Benzene sulphocyanoamide see Benzene sulphonic acid cyanoamide. Benzene sulphonamide see Benzene sulphonic acid amide. Benzene sulphone-aminoacetic acid. (Benzenesulphoneglycollic acid). C8H904NS = Ph.S02.NH.CH2.C02H. kA X 10* at 25°=3.51; diminishes on diln. A(64) = 49.0, (1024) = 155.9, (oo) = 349. Na.A at 25°, A(32) = 62.5, (1024) = 73.7; 1134. Benzene sulphone-aminosuccinic acid. (Benzenesulphone-aspartic acid). CioHii06NS = Ph.S02.NH.C2H3.(C02H)2. 74 TABLES [Ben kAX 10* at 25° = 7.15; increases slightly on diln. A(25) = 43.2, (1600) = 227.2, (oo) = 351; 1134. Benzene sulphone-aspartic acid see Benzene sulphone-aminosuccinic acid. Benzene sulphoneglycollic acid see Benzene sulphone-aminoacetic acid. Benzene sulphonic acid. C6H603S=Ph.S08H. At 25°, A(32) = 326, (1024) = 358; 1366. Cond. with maleic acid; 1630. Under varying pressures; 220. Li.A; 1366. - Mg.2A; 1836. - Na.A at 25°, A(32) = 69.1, (1024) = 80.6; 1366; alteration of cond. by KOH; 495. - Ag.A; 1111. Benzene sulphonic acid amide. (Benzene sulphamide. Benzene sul- phonamide.) C6H702NS=Ph.S02NH2. Cond. at 0°; 725. At 25°, A(32) = 0.98, (1024) = 5.63; 1576. In NHs; 607, 610. In MeNHa; 605. Cond. with HCl, and NaOH; 781. Benzene sulphonic acid benzoylamide. (Benzoyl benzenesulphonic amide). Ci3Hu03NS=Ph.S02.NH(CO.Ph). Na.A at 25°, A(32) = 59.7, (1024) = 70.1; 781. Benzene sulphonic acid cyanoamide. (Benzenesulphocyamic acid. Benzene-sulphocyanoamide). C7H602N2S=Ph.S02.NH(CN). kAXl05at25°=1.3; 70. A(115) = 12.7, (920) = 36.6, (co) = 353; 70. A(128) = 337.6; 782. [This difference is inexplicable. ] InEtalc; 782. Benzene sulphonic acid nitroamide. (Benzene sulphonitroamide.) C6H604N2S=Ph.S02.NH(N02). At 0°, A(40) = 214.0, (320) = 224.9, (oo) = 236.9. Na.A at 0°, A(1000) = 57.3; 143. p-Benzene sulphonic acid azo-(3-naphthol. C16H12O4N2S. 2Na.A (Orange II), cond. at 18° to 90°; 1796, 1798. Cond. with H2SO4; 1798. Benzene sulphonitroamide see under Benzene sulphonic acid amide. Benzenylphenylamino-p-tolylimidine see Phenyl-p-tolylbenzenylami- dine. Benzhydroxamic acid. C7H702N=PhCH.N.OH. kA X 10^ [probably at 25°] = 7.5. m(32) = 1.82, (64) = 2.11, (00)= [380]; 1353a. Benzidine. CuHi2N2=NH2.C6H4.C6H4.NH2. Hydrolysis value, (colorim.). Second kBXlO«=7.4 (hydro!.); 1777. BenzU. Ci4Hio02=Ph.CO.CO.Ph. Ben] TABLES 75 In HBr, good cond.; in HI, poor cond.; 1897. In HON, no cond.; 943. In H2S, no cond.; 27, 1897. In MeNHz, little cond.; 637. In NH3, qual.; 606. /3-Beiizil dioxime. C14H12O2N2. In NH3, qual.; 606. BenziUcacid. (Diphenyl-glycoUicacid). Ci4Hi203=Ph2.C(OH).C02H. kAXlO^ at 25°=9.1; m. p. 150°; 1186, 175. A(64)=75, (512) = 170, (oo) = 350; 1186. Cond. with boric acid; 1186. Benzimino- see Iminobenzoic- Benzine. [This is the commercial article, a mixture of different com- pounds in varying amounts. The references are not com- plete. ] k; 263, 931, 1206, 1556, 1605. With organic compounds; 263. As solvent of organic compounds; 931. Effect on k of long continued current; 1605. Benzoic acid. C7H602=Ph.C02H. kAXlO^ at 0°=6.2 aq.; diminishes slightly on diln.; 515, 1968a; increases slightly on diln.; 1018. At 15.8°=6.7; 1968a. At 17°=6.25 aq.; 164. At 18°=7.2 (colorim.); 1563. At 20°= 6.64 aq.; 515. At 25°=6.6; the highest value found is 7.4, the lowest is 6.0; in almost all these measurements, k dimin- ishes at dilutions greater than v(lOOO); 515, 1184, 1371, 1418, 1429, 1581, 1649, 1968, 1968a; (absorption of CO2); 139. At 30°=6.72 aq. At 35°=6.73 aq.; 515, 1968a. At 40°=6.75 aq.; 515, 1581. At 45°=6.68 aq.; 515. At 50°= 6.5 aq.; 515, 1581. At 60°=6.1 aq. At 70°=5.7 aq. At 80°=5.4 aq. At 90°=4.9 aq. At 99°=4.5 aq.; 1581. T not stated;=6.3 (colorim.); 496, (colorim.); 951, 1781, (part.); 1820. At 25°, A(64) = 22.3, (512) = 59.8, (1024) = 79.6, (co) = 351; 1968a. A(64)=21.4, (512) = 57.6, (1024) = 78.9, (co) = 356; 1371. Also 168, 171, 542, 782, 838. At 0°-50°; 515, 388a. In HBr; 30, 147a. Qual.; 1897. In HCl; 30, 147a. Qual.; 1897. In HON, no cond.; 943. In H2S, no cond.; 147a. In H2SO4; 223, 750. In N2O4, no cond.; 602. In NH3, qual.; 606. In MeNH2, good cond.; 637. In acetonitrile; 482. In alcohols; 754, 782, 1649. In benzene, no cond.; 1801. In dextrose soln.; 1649. In ether, very small cond.; 366. In piperidine and in pyridine; 764. Cond. with boric acid; 1184. With inorg. bases; 168, 169, 171, 1017. With aniline; 169. With KCN; 1654. Under pres- sure of 1-260 atmospheres; 542. Salts. NH4.A; 823. At 15°-40°; 1143. - Cs.A; 1728. - Gl com- 76 TABLES [Ben plex; 1712. - Li.A; 1728. In NHs, qual.; 606. - K.A; 1728, 164. At 35°-65°; 388a. In flame; 682. - Ag.A; 848. - Na.A at 25°, A(32) = 68.7, (1024) = 77.0; 1368a; - also 1728, 1275, 1968a. At 0°-50°; 515. At 25°-99°; 1581. Under pressure of 1-260 atmospheres; 542. In flame; 682. - Rb.A; 1728. - UO2.2A; 449. - Cinchonine.A, in Me ale, Et ale. and acetone; 1620. Benzoic acid amide. (Benzamide). C7H70N=Ph.CO.NH2. At 25°, A(64) = 1.3, (1024) = 4.2; 1729.. In NH3; 610. In Et ale, small cond.; 1904. In HON, small cond.; 943. Cond. with NaOH; 781. Hg.A.; 963. Benzoic acid cyanoamide. (Benzoylcyanoamide). C8H60N2=Ph.CO.NH(CN). kA X 10' at 25°=2; diminishes on diln.; m. p. 143°; 70, 757. A(88) = 117.0, (1408) = 263.1, (co) = 354; 70. In pyridine; 754. Na.A at 25°, A(32) = 66.8, (1024) = 75.3; 270. Benzoic acid anhydride. C14H10O3. In NHs, qual.; 606. Benzoic acid esters. Compounds of the type RR-carbinol benzoate; see under al- phabetical heading of the first R; as Methylethyl-dimethyl- amino-methyl carbinol benzoate. Benzoic acid amyl ester. Ci2Hi602=Ph.C02C6Hii. In NHs is insol.; 606. Effect of temperature on cond.; 106. Benzoic acid fso-butyl ester. C11H14O2. In NHs is insol.; 606. Effect of temperature on cond.; 106. Benzoic acid ethyl ester. C9Hio02=Ph.C02Et. K X 10' at 25°= 1.8; 1106, 1107. In HCl, good cond.; 1897. In HI; 1646. In NH3, qual. ; 606. In Et ale, qual.; 1815. Cond. in Et ale. with EtONa; 1816. Effect of temperature on cond.; 106. As solvent; 1106, 1107. Benzoic acid methyl ester. CsHgOz. In HCl, qual.; 16. In NH3, qual.; 606. Effect of temperature on cond. ; 106. Benzoic acid imide see Dibenzamide. o-Benzoic sulphinide. (Saccharin). C7H5O3NS. kAXlO' at 25°=3.6; m.p. 217°. A(320) = 228.0, (640) = 257.3, (00) = 353; 781, (colorim.); 1773. Ben] TABLES 77 In NHa; 607, 610; qual.; 606. In MeNH2, good cond.; 637. In pyridine; 754. Na.A, at 25°, A(32) = 69.5, (1024) = 80.5; 781. Benzoin. Ci4Hi202=Ph.CH(OH).CO.Ph. In HCl and HBr, good cond.; in HI and HjS, no cond.; 1897. Benzonitrile. C7H5N=Ph.CN. XX 10' at 0° = 33.6; 1844. At 20°=400; 1733. At 25°=1.7.; 1847. = 0.8; 1323; also 1084, 1106, 1107, 1388, 1569, 1843, 1844. T not stated; 617, 669. In NHs; 606. Cond. with organic compounds and with AgNOa; 1388, 1569. As solvent of inorg. compounds; 1106, 1107, 1323. As sol- vent of organic compounds; 669, 936, 1084, 1388, 1569, 1733, 1844, 1847. Benzophenone. Ci3HioO=Ph.CO.Ph. In HBr, HCl and HI; 147a. In HBr and HI, good cond.; 1897. In HCN, no cond.; 943. In HaS, no cond.; 147a, 1897. In MeNHa, very little cond.; 637. Benzophenone chloride see Diphenyl-dichloro-methane. Benzophenone oxime. (Diphenyl-ketoxime). CisHuON. In MeNHa, little cond.; 637. Benzopurpurine 4 B. The salt of o-tolidine-disazo-binaphthylamine sulphonic acid. C34H26N6(S03H)2. C34H26N6(S03K)2. At 18°, m(200) = 145.4, (1600) = 205.2. At 90°, iu(100) = 434.7, (1600) = 588.8. Cond. with KCl; 976a. C34H26N6(S03Na)2. Cond. before and after dialysis and filtration; 186; also see 186a. [The composition of the dye is not stated in 186, but it is said to have come from Merck. In Merck's Index for 1907 the dye is said to be the sodium salt, as given here. ] o-Benzoquinone dioxime. C6H602N2=NOH:C6H4:NOH. kAX 10' at 25°= 1.8. A(512) = 3.7, (1024) = 5.0; 758. In pyridine; 754. Na.A at 25°, A(64) = 74.4 at once. Changes on standing to the anhydride, Phenylenefurazane; 758. p-Benzoquinone. (Quinone). C6H4O2. kAX IQi' at 18° is greater than 1 (hydrol.); 524. At 25°, /i(32) = 0.03 for fresh soln.; = 6.2 after two hours standing, from formation of an acid; 547. Cond. with NaOH; 524. In NH3, qual.; 606. In MeNHa, fair cond.; 637. 78 TABLES [Ben p-Benzoquinone chloroimide. C6H4ONCI. Cond. of dil. soln. is about 0.3% that of corresponding saline chloride sola.; explodes above 85°; 318. p-Benzoqixinone monooxime. CeHsOaN. At 25°, Ai(1024) = 6.4; 547. See p-Nitrosophenol. p-Benzoquinone dioxime. (Quinone dioxime). CeHeOzNa ^NOHrCeHiiNOH. At25°, m(800)=0.25. Na.A at 25°, ai(32) = 64.5, (1024) = 82.1; changes, on standing, to the polymeric anhydride (C6H40N2)x; 547. Benzoylacetic acid ethyl ester. CiiH:203=PhCO.CH2.C02Et. xXlO^ at0°=6.91. At 25°=9.0; b. p. 185°-186° @ 39 mm.; 1843; 1844. Cond. as solvent of NEtJ; 1844. Fe.3A at 25°, in Et ale; m. p. 128°; 756. Benzoylacetone. C10H10O2. Fe.3A, too insol. in aq. to measure; 756. Benzoylalanine see Benzoylamino-propiomc acid. Benzoylamino-acetic acid. (Hippuric acid). C9H903N=CH2(NH.PhCO).C02H. kAXlO^ at 0°=2.2. At 12°=2.3; 1968a. At 25°=2.2; 1186, 1370, 1984; = 2.4; 1968a. At 35°=2.3; 1968a. At 25°, A(32) = 28.2, (1024) = 131.1, (co) = 350; 1370. In HBr, no cond. ; in HCl, small cond. ; 30. In NH3, qual. ; 606. In MeNH2, good cond.; 637. Cond. with boric acid; 1186. With NaOH; 1984. Na.A at 25°, A(32) = 63.0, (1024) = 73.4; 1984; 1968a. MeNHs.A, qual.; 637. Hg.A; 963. B.HClat25°, M(32)=384, (1024) = 448; 1984. Benzoylamino-propionic acid. (Benzoylalanine). CioHn03N=Me.CH(NH.PhCO).C02H. ki X 10* at 25°= 1.97; slight diniinution on diln. A(128) = 51.3, (1024) = 124.7, (oo) = 350; 601. Benzoylamino-succinic acid. (Benzoyl-aspartic acid). CiiHii06N=C02H.CH2.CH(NH.PhCO).C02H. kAXlO«at25°=5.31. iu(64) = 63.0. (256) = 114.8, (co) = 374; 1397a. Benzoylamino-succinic acid a-mono methyl ester. Ci2Hi305N=C02H.CH2.CH(NH.PhCO).C02Me. kAXlO* at 25°=1.93; diminishes on diln.; sinters 117°-120°, melts 123°-124°. m(32) = 28.3, (512) = 98.1, (oo) = 374; 1397a. Benzoylamino-succinic acid |3-mono methyl ester. Ci2Hi306N=C02Me.CH2.CH(NH.PhCO).C02H. Ben] TABLES 79 IjaX 10^ at 25°= 5; m. p. 154° (cor.). /i(64) = 61.3, (512) = 147.0, (oo) = 374; 1397a. Benzoyl-aspartic acid see Benzoylamino-succinic acid. Benzoyl benzenestdphonic amide see under Benzene sulphonic acid amide. o-Benzoylbenzoic acid. Ci4Hio03=PhCO.C6H4.C02H. kAX 10^=3.8; diminishes on diln. A(1024) = 171.7, (2048) = 211.5, (co) = 374.5; 1246. Benzoyl chloride. C7H60Cl=PhCO.Cl. Cond. with anisole and AICI3; 1893. Benzoyl cyanoamide see under Benzoic acid amide. Benzoylecgonine. C16H19O4N. kfl is of the order of lO^i" (colorim.); 1778. Benzoylecgonine methyl ester see Cocaine. Benzoylmethyl- see Methylbenzoyl- Benzoyl peroxide. Ci4Hio04= (Ph.CO)202. InS02, no cond.; 1842. ^-Benzoylpropionic acid. CioHio03=PhCO.CH2.CH2.C02H. kAX 10^ at 25°= 2.2; diminishes on diln. A(64) = 13.3, (1024) = 49.3, (oo) = 356; 768. labile /J-Benzoylpropionic acid oxime. (awii-Phenylketoximepropionic acid). CioHii03N=Ph.C(N.OH).C2H4.C02H. At 0°, A(100.6) = 17.7, (402.4) = 27.4; m. p. 91°; 768. stabile |3-Benzoylpropionic acid oxime. (sj/n-Phenylketoximepro- pionic acid). C10H11O3N. kAX 10^ at 25°= 1.7; increases on diln., from change in soln. to the isomeric anti- acid; m. p. 129°. At 0°, A(101.6)^10.8, (406.4) = 22.8. At 25°, A(64) = 11.7, (1024) = 50.5, (oo) = 355; 768. Benzoylpyroracemic acid. (Benzoylpyruvic acid). CioH804=Ph.CO.CH2.CO.C02H. kAX 10' at 25°=6.6 aq.; increases on diln.; m. p. 156°-158°. A(400) = 267.6, (1600) = 325.9, («=) = 354; 23. Benzoylsarcosine see Methylbenzoylamino-acetic acid. j3-Benzoyl-iso-succinic acid. CiiHio05=PhCO.CH2.CH(C02H)2. kAX lO' at 25°=2.5; diminishes on diln.; m. p. 178°-179°. Second kA X 10'=4.7 (inversion). At 25°, Ai(64) = 114.5, (1024) = 262.4, (co) = 351; 1638. Benzylacetamide see under Acetic acid amide. Benzylacetic acid see Hydrocinnamic acid. Benzyl alcohol. C7H80=PhCH2.0H. xX 10« at 25°= 1.76; 1106, 1107. InNHs, qual.; 606. As solvent; 334, 1106, 1107, 1580. 80 TABLES [Ben Benzylalcohol-o-carboxylic acid see o-Hydroxymethyl-benzoic acid. Benzyl amine. C7H9N=PhCH2.NH2. kBXl0^atO°=1.52; 776. At25°=1.95; 776;=2.4aq.; 16% too high; 271. At 30°=2.00. At 35°=2.18. At 40°=2.34. At 45°=2.33. At 50°=2.27. At 55°=2.23; 776. At 25°, A(32) = 5.6, (256) = 15.3, (oo) = 201; 271. With allyl thiocarbimide, no cond. ; 1223. Relative strength by optical rotation; 1631. B.HCl at 25°, A(32) = 90.7, (1024) = 101.4; 270. In SO2; 1855. Benzyl bromide. C7H7Br=PhCH2.Br. In SO2; 1829; qual.; 1842. Benzyl-iso-butenyltricarboxylic acid. (Methylbenzylcarboxyglutaric acid.) CuHi606=PhCH2.C(C02H)2.CMe2.C02H. kx X 102 at 25°= 1.4; m. p. 178°. m(64) = 209, (512) = 301, (co) = 348; 1839. Benzyl chloride. C7H7Cl=PhCH2.Cl. In HBr, no cond.; 1897. In SO2; 1842. /3-Benzylcinnamic acid see Diphenyl-crotonic acid. Benzylcresotinic acid. Ci6Hi403=(PhCH2)(Me)C6H2(OH)(C02H). Cond. increased by boric acid; m. p. 164°-166°; 1186. Benzyl cyanide. C8H7N=PhCH2.CN. XX 10' at. 0°= 1.10; 1843, 1844. At 20°= 12; 1590a. At 25°= 1.56; b. p. 127° @ 23-25 mm.; 1844, 1843. In NH3, qual.; 606. As solvent; 1590a, 1844, 1863a. As solvent, under pressure; 1590a. Benzyldimethyl- see Dimethyl-benzyl- Benzylethenyltricarboxylic acid. * Ci2Hi206=CH2(C02H).(PhCH2)C(C02H)2. kx X 102 at 25°-3.2; m. p. 168.5°. m(32) = 217.7, (1024) = 342, (oo) = 350; 1839. Benzylethyl- see Ethylbenzyl- Benzylglutaconic acid. Ci2Hi204=PhCH2.CH(C02H).CH:CH.C02H. kiX 10* at 25°= 1.53; m. p. 145°. m(69)=34.0, (1104) = 118.7, (oo)=353; 1838. BenzyUdene chloride. C7H6CI2 = Ph.CHCU. In HBr and H2S, no cond.; 1897. BenzyUdene di-thioglycollic acid. CiiHi204S2=PhCH: (SCH2.C02H)2. kxXW [probably at 25°]=5.75; increases on diln.; m. p. 126°- 127°. m(128) = 89.1, (512) = 166.7, (oo) = 375; 856. 7-Benzylidene-7-phenylpyrotartaric acid. Ci8Hi604=(Ph)(PhCH:)C.CH(C02H)(CH2C02H). Bis] TABLES 81 kAXlO*=1.2; m. p. 151° for A.2H2O. m(640) = 84.5, (1280) = 111.5; 1664. 2,5-Benzyliminopyrine. (2,3-Dimethyl-l-phenyl-2,5-benzyliminopyra- zole. Methylphenylbenzylaminopyrazole). C18H19N3. At 18°, A(20) = 157.6, (1000) = 154. B.HI; m. p. 159°; at 18°, A(30) = 65.7, (1200) = 78.0; 1256, 214. Benzylmalonic acid. CioHio04=(PhCH2)CH(C02H)2. kiXlO^ at 18°=1.6 (colorim.); 1563. At 25°=1.51; m. p. 117°; 1838. Second kxX 10''=4.9 (inversion); 1638. At 25°, m(32) = 68.9, (1024) = 243, (co) = 354; 1838. Benzyl mercaptan ethyl ether see Ethylbenzyl sulphide. Benzylmethyl- see Methylbenzyl- Benzylsuccinic acid. CiiHi204=C02H.CH2.CH(PhCH2).C02H. kiX 10= at 25°=9.1; m. p. 161°; 201, 1838. m(64) = 25.6, (512) = 67.5, (00) = 351; 1838. Benzyl sulphonic acid. (Tolyl sulphonic acid). C7H803S=PhCH2.S03H. At 25°, A(32) = 340.8, (co) = 350. kx calculated by different formulae gives no constant value. Na.A at 25°, A(32)=61.5, (1024) = 73.2; 423. Benzyltartronic acid. CioHio05=PhCH2.C(OH)(C02H)2. kiX 10' at 25°=5.5; m. p. 143°. m(72.5) = 163, (1160) = 312, (co) = 352; 1838. Benzyl urethane see Carbamic acid benzyl ester. Beryllium see Glucinum. Betaine see Trimethyl-aminoacetic acid. Bi- see also Di- Bibenzyldicarbozylic acid see Diphenyl-succinic acid. Bile. [The references to this are incomplete. ] Cond.; 251. Concentration of H and OH ions; 587. BiUverdic acid see Haemitinic unide. Biliverdinic acid see Haemitinic imide. 2,2'-Bis-ethylsalicylal-acetone. C21H22O3. Comparative strength; m. p. 89°; 1663. 2,2'-Bis-ethylsalicylal cyclopentanone. C23H24O3. Comparative strength; m. p. 110°; 1663. Bis-methylvanillal-acetone. C21H22O5. Comparative strength; m. p. 84°; 1663. Bis-methylvanillal cyclopentanone. C23H24O5. Comparative strength; m. p. 195.5°; 1663. Bis-nitrophenosy-malonic acid. Cl5HloOloN2 = (NO2. C6H40)2C (C02H)2. 2Na.A, A(1024-32) = 32; 194. 82 TABLES [Biu Biuret see Allophanic acid amide. Blood and blood serum. [The references are incomplete. ] X at 5° to 60°; 152, 153, 156a, 251, 252, 252a, 253, 255, 257, 258, 306, 307, 310a, 310b, 376a, 445b, 451, 507a, 544, 600, 623, 626a, 783a, 836a, 878, 880, 881, 1073, 1137a, 1239a, 1239b, 1351, 1352, 1353, 1462, 1532, 1570, 1619, 1622, 1623, 1624, 1625, 1626, 1626a, 1665a, 1665b, 1655c, 1768, 1769, 1983. Cond. With acids; 1239b. With bases; 252a, 1239b. With inorg. salts and organic compounds; 724a, 1353, 1397b, 1626a, 1655a, 1655c. With NaCl and with adrenaline; 257. With various alcohols and with acetone; 1239b, 1622, 1623, 1624, 1625, 1626. Effect of coagulation; 600. Effect of heating; 1239a, 1239b, 1462. Effect of pressure; 152, 153. Concentration of OH ions; 643, 587, 803, 835, 836, 1111a, 1268b, 1259. Concentration of H ions; 587, 803, 1111a, 1258b, 1258c, 1259, 1501a. Effect of CO2; 1016. Boric acid triethyl ester. C6Hi603B = B(OEt)3. In HCl, good cond.; 1897. Boric acid trimethyl ester. C3H903B=B(OMe)3. K X 10' at 0°=4.9. At 25° =6.2. As solvent of NEt4l; 1844. d-Bomeol. CioHi80=CioHi7.0H. In HCN, no cond.; 943. In NH3, qual.; 606. cjs-Bomeolcarboxylic acid. CiiHi803=CioHi6(OH).C02H. kAXlO*=1.05 (colorim.); m. p. 101°-102°; 274. CJS-) = 354; 1372. 84 TABLES [Bro 4-Broinoaniline-3-sulphomc acid. CeHeOsNBrS. [NH2=1; Br=4; S03H=3.] IcaX 10^ at 25°=7.2; diminishes on diln. A(64) = 70.0, (1024) = 197.5, {oo) = 354; 1372. Bromobenzene. CeHBBr. xXlO^at 18°=9.9; 386. In HBr and H2S, no cond.; 1897. In NH3, qual.; 606. In MeNHa, no cond.; 637. Cond. with carvene and chloroform; 386. p-Bromobenzene diazonium syn-cyanide. (p-Bromodiazo benzene cyanide). C7H4N3Br=C6H4Br.N2.CN. Cond. in Et ale; m. p. 43°; 735. p-Bromobenzene diazonium hydroxide. (p-Bromodiazo benzene). C6H60N2Br= C6H4Br.N2.OH. kBXlO«atO°=1.5. A(128) = 17.9, (1024) =47, (cx>) = 135; 501. B.Br; 730. - B.Cl cond. with KCN; 735. - B.CN; 735. - B.NO3; 730. anti-K.k; 774. o-Bromobenzoic acid. C7H602Br=Br.C6H4.C02H. kA X 10' at 18°= 1.35 (colorim.); 1563. At 25°= 1.45; diminishes on diln.; 1371. At 25°, A(128) = 124.5, (1024) = 242.2, (a>) = 356; 1371. K.A; 1728. - Na.A at 25°, A(64) = 66.1, (128) = 68.0; 1728; A(1024) = 75.0; 1581. m-Bromobenzoic acid. C7H602Br. kAXlO* at 18°=1.4 (colorim.); m. p. 153°-154°; 1563. At 25°= 1.37; 1371. At 25°, A(512) = 82.6, (1024) = 110.7, (oo) = 356; 1371. InNHa, qual.; 606. Na.A at 25°, A(32) = 67.2, (1024)=77.2; 1368a. At 25° to 99°; 1581. p-Bromobenzoic acid. C7HB02Br. kAX lO^at 25°= 6.6 (solub.); 1116. Too insol. in aq. to measure cond.; 1371. Cs.A. - K.A. - Na.A at 25°, A(64) = 65.1, (128) = 67.1. - Rb.A; 1728. a-Bromobutyric acid. C4H702Br=Et.CHBr.C02H. kAXlO'at25°=1.06. A(128) = 109, (1024) = 218, (oo) = 355; 1840. In SO2; 1842. a-Bromobutyric acid ethyl ester. C6Hii02Br. In SO2, no cond.; 1842. 7-Bromobutyric acid. C4H702Br=CH2Br.CH2.CH2.C02H. kAX 10^ at 25° = 2.62; m. p. 32°-33°; 1099 and 1908. A(32) = 10.9, (64) = 15.1, (a>) = 356; 1099. Bro] TABLES 85 a-Bromobutyryl bromide. C4H60Br2=Et.CHBr.COBr. In SO2; 1842. [Walden gives the formula for the normal Bro- mobutyryl bromide; but calls it the iso compound. No b. p. is given.] a-Bromo-iso-butyryl bromide. C4H60Br2=Me2.CBr.COBr. In AsCls and in SO2; b. p. 161°-163°; 1842. o-Bromocamphor sulphonic acid. (d-a-Bromocamphor-7r-sulphonic acid.) CioHi604BrS. At 25°, iu(30) = 329, (co) = 355; 1841. In acetone; 1841. In SO2, no cond.; 1842. Cond. with quinidine; 1841. Ba.2A. - G1.2A. - K.A. - Na.A at 25°, m(30) = 65.5, (960) = 76.0. - TLA. - Zn.2A. - Quinidine. A. ; 1841. Bromocamphorsulphonic chloride. CioHuOaClBrS. In SO2; 1842. ^-Bromocarmin. (Bromoearminic acid). CnHeOiBrs. 2Na.A at 25°, A(32) = 76.7, (1024) = 87.3; 1275. Bromoearminic acid see Bromocarmin. o-Bromocinnamic acid. C9H702Br=PhCH:CBr.C02H.(|3- acid). kAXlO* at 25°=9.3. A(441) = 165.0, (1764) = 246.2, (o=) = 352; 1371. /3-Bromocinnamic acid. C9H702Br=PhCBr:CH.C02H.(a- acid). kiXlO^ at 25°=1.44; 1371; = 1.3 aq.; 1581. At 40°=0.96 aq. At 50°=0.79 aq. At 60°=0.65 aq. At 70°=0.53 aq. At 80° = 0.44 aq. At 90°=0.36 aq. At 99°=0.29 aq.; 1581. At 25°, A(lll) = 246, (888) = 329, (oo) = 352; 1371. Bromocitraconic acid. C6H504Br= C02H.C(CH2Br) : CHCCOaH)? kA X lO' at 25°= 1.49 aq. ; diminishes on diln. ; m. p. of the anhyd- ride is 100°-101''. ;u(107) = 247.3, (856) = 325, (co) = 355; 23. Bromocitraconic acid anhydride. CsHsOsBr. Cond. of soln. in aq. showing change to acid; 23. Bromodehydracetic acid. C8H704Br. Too insol. to get cond.; m. p. 136°-137°; 558. Bromo-diamino-p-sulphotoluic acid see Bromo-2,6-toluylenediamine- 4-sulphomc acid. p-Bromodiazobenzene see p-Bromobenzene diazonium hydroxide. 2-(/3)-Bromoethyl amine. C2H6NBr=C2H4Br.NH2. B.HBr at 25°, A(32) = 98.0, (1024) = 109.7; 270. Bromoethyl brucinium chloride. C25H30O4N2ClBr=C23H26O4N2.(C2H4Br)Cl. At 25°, A(32) = 75.1, (1024) = 91.5; 270. 86 TABLES [Bro Bromoethyl strychninium chloride. CasHseOaNaClBr = C21H22O2N2. (CaHiBr) CI. At 25°, A(32) = 78.6, (1024) = 90.8; 270. Bromoform see Tribromo-methane. Bromogallic acid. (3,4,5-Trihydroxy-2-bromobenzoic acid). C7H606Br=(OH)3C6H(Br).C02H. kiXlO* at 25°=5.91. ;u(64) = 62.4, (1024) = 188.0, (oo) = 352; 1371. Bromomaleic acid. C4H304Br=C02H.CBr:CH.C02H. At 25°, m(32) = 263, (1024) = 355; 1372. Bromomethyl- see Methylbromo- l-(a)-Bromonaplithalene. CioHjBr. In SO2, no cond.; 1829, 1842. Bromonitro- see Nitrobromo- Bromophenylacetyl- see Acetyl-bromophenyl- p-Bromophenyl-cyanourea. C8H60N3Br=Br.C6H4NH.CO.NH(CN). IsaX 10^ at 25°=2 (cond. and colorim.). A(2048) = 188.4, (oo) = 378; dec. above 325°; 214a. l-p-Bromophenyl-5-liydroxy-l,2,3-triazole-4-carboxylic acid ethyl ester. CuHioOsNsBr. kAX 102 at 25°=2; m. p. 138.5° slowly heated. iu(420.3) = 335, (1681.2) = 359.9, (oo) = 371; 448. norm.-p-Bromophenyl-nitromethane. C7H602NBr=Br.C6H4.CH2.N02. At 0°, /i(2780) = 2.5, probably due to absorption of CO2; m. p. 60°; 775. iso-p-Bromophenyl-nitromethane. C7H602NBr. At 0°, M(388) = 23.2; m. p. 89°-90°. Na.A at 25°, /i(32) = 73.6, (128) = 79.9; also cond. with HCl; 775. 2-Bromo-p-phthalic acid. C8H604Br=Br.C6H3(C02H)2. [C02H=1, 4; Br=2.] kAX 10' at 25°= 6.2; 1909. Second kiX 10^=7.6; 1911. At 25°, m(254.8) = 263.3, (1020) = 359.5, (co) = 377; 1909. 2-Bromo-p-phthalic acid 1-mono methyl ester. C9H704Br=Br.C6H3(C02Me)(C02H). [C02H=4; C02Me=l.] kA X 10* at 25°=3.7; diminishes on diln.; m. p. 145°; 1909, 1930. m(471.4) = 127.8, (1888) = 207.3, (oo) = 376; 1909. 2-Bromo-p-phthalic acid 4-mono methyl ester. CgHjOiBr. [C02H=1; C02Me=4.] kAX 10' at 25°=5.0; diminishes on diln.; m. p. 164°; 1909, 1930. /i(260) = 249.6, (1041) = 316.9, (00) = 376; 1909. a-Bromopropionic acid. C3H602Br=Me.CHBr.C02H. kAXlO^ at 25°= 1.08; m. p. 15°-20°. Bro] TABLES 87 A(128) = 110.4, (1024) = 225, (») = 358; 1840. In SO2; 1842. In NH3, qual.; 606. /3-Bromopropionic acid. C3H602Br=CH2Br.CH2.C02H. kAX 10^ at 25°=9.8; diminishes slightly on diln.; m. p. 62.5°. A(32) = 19.5, (1024) = 95.3, (oo) = 358; 1840. In NH3, qual.; 606. Bromopyrotartaric acid. C6H704Br=C3H5Br(C02H)2. kA X IC at 25°=4.78; m. p. 204°; 1838. Second kAX 10^=5.1 (cond.); 1911. At 25°, m(64) = 150, (1024) = 322, (oo) = 356; 1838. (w)-12-Bromostyrolene. CsHjBr^Ph.CHiCHBr. In SO2, no cond.; 1829, 1842. mac/.-Bromosuccinic acid. C4H604Br=C02H.CH2.CHBr.C02H. kAXlO^ at 25°= 2.7; m. p. 160°-161°; 1824, 1838. Second kAX 10^=3.9 (cond.); 1911. At 25°, m(32) = 91.5, (1024) = 294, (oo) = 356; 1838. l-Bromosuccinic acid. C4H504Br. kAXlO'at25°=2.7; m. p. 172°; 1824. Second kAX 10^=2.5 (part.);=3.9 (cond.); 370. In SO2, is insol.; 1842. NaH.A; 370. - 2Na.A at 25°, A(32) = 81.7, (1024) = 99.4; 270; - 370. Bromotetric acid. C5HB03Br=Me.CBr.C3H203. kAXlO^ at 25°= 1; diminishes on diln.; m. p. 75°-77°. ju(640) = 27, (1280 = 34.9, (oo)=356; 1831. 3-Bromo-2-toIuidine-6-sulphoiiic acid. C7H803NBrS=(Br)(NH2).C6H2(Me)(S03H). [Me=l; NH2=2; Br=3; S03H=5.] kA X 10 at 25°= 1 ; diminishes on diln. A(32) = 283.3, (1024) = 333.1, (a>) = 354; 492. [In 492 this is given as Me=l; NH2=2; Br=5; S03H=3.] ?-Bromo-2-toluidine-?-sulphonic acid. CyHsOsNBrS. [In 492 given as, Me=l; NH2=2; S03H=4.] kA X lO' at 25° is about 1.4; diminishes on diln. A(256) = 159.2, (1024) = 213.3, (cx>) = 353; 492. ?-Bromo-4-toluidine-2-sulphonic acid. C7H803NBrS. [Me=l; NH2=4.] kAXlO' at 25°=4.5; diminishes on diln. A(64) = 145.7, (1024) = 287.6, (oo) = 353; 492. Bromo-2,6-toluylenediaimne-4-sulphomc acid. (Bromo-diamino-p- sulphotoluic acid) . C7H903N2BrS = Me.C6H(Br) (NH2)2.S03H. [Me=l; NH2=2,6; Br=3; S03H=4.] 88 TABLES [Bio kAX 10^ at 25° = 1.72; diminishes on diln. A(135.5) = 50.4, (1084) = 122.1, (oo) = 353; 1372. Bromotrihydroxy- see Trihydroxy-bromo- fi-Bromovaleric acid. C5H902Br=CH2Br.(CH2)3.C02H. kAX 10^ at 25°=1.91; m. p. 39°-40°; 1099, 1908. A(64) = 13.0, (oo) = 354; 1099. Brucine. C23H26O4N2. kfiXlO* at 15° is about 0.07 (hydro!.); 1779. Atl8°=0.1 (cond.); 1224. At 20° is over 1.7 (colorim.); 1776. At 25°=1 aq.; 1241. Second kBXlO"=2.5 (colorim.); 1776. At 18°, Ai(751) = 5.13, (oo) = l93; 1224. At 25°, m(713) = 11.1, (1426) = 22.3, (00) = 189.4; 1241. In HCN, fair cond.; 943. In NH3, qual.; 606. B.HCl at 25°, A(32) = 75.5, (1024) = 89.2; 270; 1224. In HCN, small cond.; 943.- B.HNO3 and 2B.H2SO4; 1611. - B.C5H11CI, B.EtCl and B.(C2H4Br)Cl; 270. - B.Acetate; 146b. Buckthorn see Rhaninus Frangula. Bulbine frutescens. [The references to this are incomplete. ] Cond. of sap of stem and leaves; 253, 1326. a-Butanetetracarbozylic acid. (Tetracarboxylic acid). C8Hio08=C02H.CH2.CH(C02H).CH(C02H).CH2.C02H. kAXlO^ at 25°=4.0; increases on diln.; m. p. 233°; 1839; m. p. 236°; 66. Ai(64) = 51.8, (1024) = 173, (oo) = 350; 1839. /i(32) = 37.4, (00) = 351; 868. 4Na.A, m(32) = 81.0, (1024) = 110.0; 66. jS-Butanetetracarboxylic acid. CgHioOs. kA X 10' at 25°=8; m. p. 189°; 1839;=4; m. p. 189°; 66. [Walden says that the acid he measured, titred as a dibasic acid, and that Bischoff got an acid, m. p. 185°, purer than that of Auwers.] m(32) = 37.1, (oo) = 351; 868. Nasalt, m(32) = 81.8, (1024) = 110.8; 66. Butenyltricarboxylic acid. (Ethylethenyltricarboxylic acid). C7Hio06=Et.CH(C02H).CH(C02H)2. kAXl05at25°=3.07; m. p. 136°-137.5°; 1839. Second kAX 10^=2.2 (cond.); 1911. At 25°, m(32) = 94.7, (1024) = 290, (oo) = 353; 1839. iso-Butenyltricarboxylic acid. (Dimethyl-ethenyl-tricarboxylic acid). C7Hio06=Me2.C(C02H).CH(C02H)2. kA X IC at 25°=3.34; m. p. 148°. But] TABLES 89 m(32) = 97.5, (1024) = 297, (oo) = 353; 1839. See also |3-Dimethyl- ethenyltricarboxylic acid. iso-Butylacetic acid. C6Hi202=Me2CH.(CH2)2.C02H. kiX 10^ at 25°= 1.5; b. p. 199.7° (cor.); 180, 601. A(32) = 7.8, (1024)=41.7, (oo) = 352; 180. Na.A at 25°, A(32) = 63.3, (1024) = 73.6; 601. norm.-Butyl alcohol. C4H10O. In NH3, qual.; 606. iso-Butyl alcohol. C4HioO = Me2.CH.CH2.0H. X X 10* at 18° is less than 1; 478. At 25°=8.4; 1649;=34; 1569. In NH3, qual.; 606. Cond. with oxalic acid; 45. As solvent; 334, 483, 1579, 1649. ) = 351; 1838. 2Na.A at 25°, m(32) = 74.7, (1024) = 92.3; 1823. iso-Butylsulphuric acid see Sulphuric acid mono iso-butyl ester. Butyramide see Butyric acid amide. 1-O-. Butyrhydroxamic acid. C4H902N=C3H7CH.N.OH. kA X 10^ [probably at 25°] = 2.3. m(16) = 0.2, (32) = 0.4, (00)= [380]; 1353a. Butyric acid. C4H802=Me.CH2.CH2.C02H. xXlO^at 18°=6; 1380; also 517. kAXlO^ at 0°=1.66 aq.; slight increase on diln.; 1018, 1968a. At 9.4°= 1.63; 1968a. At 10°= 1.67; 875. At 14°= 1.56 aq.; 838. At 18°= 1.6; 93, 94, 43; (colorim.); 1563. At 20°= 1.71; 875. At 25°= 1.6. The values vary greatly, probably because of the difficulty of purifying the acid. The extremes are, 1.45 and 1.75; 180, 461, 601, 1184, 1368, 1370, 1968, 1968a; - (absorption of CO2); 139. At 30°= 1.70; 875. At But] TABLES 91 35°= 1.47; 1968a. At 40°= 1.65; 875. At 52°= 1.64; 43. At 55°= 70 (action of diastase on starch); approximate; 2002. T not stated; (colorim.); 951, 1643, 1781; (precipita- tion of casein) ; 693. At 25°, A(32) = 7.7, (1024) = 40.6, (oo) = 356; 1370. A(1024) = 42.2; 180. At 0°-35°; 1968, 1968a. At 10°-50°; 875. Also 43, 93, 542, 646, 787, 788, 1747. In HBr and HCl; 30. In NH3, qua!.; 606. In Me, Et and norm. -amy! ale; 787, 788. In amyl ale; 932. Cond. with boric acid; 1184. With inorg. salts; 1994. With organic compounds; 93, 94, 1011, 1620, 1747, 1994. Under pressure of 1-260 atmospheres; 542. Ba.2A; 94. - Li.A; 1367. - Mg.2A; 1836. - K.A; 94, 1367. - Ag.A; 1537.- Na.A at 25°, A(32) = 67.4, (1024) = 77.4; 1368a, 1367. Also 43, 93, 94, 875, 1416, 1537, 1837, 1968a. With organic compounds; 94, 1994. Under pressure of 1-260 atmospheres; 542. - Cinchonine.A; 1620. Butyric acid amide. (Butyramide). C4H90N=Me.(CH2)2.CO.NH2. Cond. with HCl and NaOH; 410, 412. With HgCU; 1097. Butyric acid cyanoamide. (Butyrylcyanoamide). C6H80N2=Me.(CH2)2.CO.NH(CN). kA X 10* at 25°= 1.12; increases on diln. A(35.9) = 20.7, (1148.8) = 105.6, (oo) = 352; 70. Butyric acid amyl ester. C9Hi802=Me.(CH2)2.C02C5Hii. In NH3, qual.; 606. Effect of temperature on cond.; 106. Butyric acid iso-butyl ester. C8H16O2. In NH3, qual.; 606. Effect of temperature on cond. ; 106. Butyric acid ethyl ester. C6Hi202=Me.(CH2)2.C02Et. In NH3, qual.; 606. Effect of temperature on cond. ; 106. Butyric acid glyceryl ester. (Tributyrin). Cl5H2606=(PrC02)3.C3H5. In NH3, qual.; 606. Butyric acid methyl ester. C5H10O2. InNHs, qual.; 606. Effect of temperature on cond. ; 106. Butyric acid propyl ester. C7H14O2. Effect of temperature on cond. ; 106. ISO-Butyric acid. C4H802=Me2CH.C02H. X is very small; 517. kAXl05atO°= 1.55; 1968a. At 10°= 1.59; 875. At 16.5°= 1.53; 1968a. At 18°= 1.6 (colorim.); 1563. At 20°= 1.62; 875. 92 TABLES [But At 25° = 1.6. The variation of values is probably due to the difficulty of purifying the acid. The extremes are 1.41 and 1.62. See 180, 420, 461, 601, 1370, 1968a. At 30°= 1.61; 875. At 35°= 1.42; 1968a. At 40°= 1.56; 875. At 55°= 80 (action of diastase on starch); approximate; 2002. T not stated; (colorim.); 1643. At 25°, A(32) = 7.9, (1024) = 43.6, (oo) = 356; 180. A(32) = 7.5, (1024) = 39.7; 601. At 0°-35°; 1968a. At 14°-50°; 875; also 542, 619, 1554. In NHb, qua!.; 606. Cond. with inorg. salts; 1554. With organic salts; 1994. Under pressure of 1-260 atmospheres; 542. Li.A; 1367. - Mg.2A; 1836. - K.A; 1367. - Ag.A; 656, 1537. - Na.A at 25°, A(32) = 67.2, (1024) = 77.7; 1368a, 1367. At ia°-50°;875. Under pressure of 1-260 atmospheres; 542. ISO-Butyric acid amide. (iso-Butyramide). C4H90N= MejCH.CONHa. Cond. with HCl; 410. With NaOH; 412. iso-Butyric acid anhydride. CsHuOs. X X 10' at 0°=0.994. At 25°= 1.60; 1843, 1844. Cond. as solvent of NEt4l; 1844. ISO-Butyric acid iso-butyl ester. C8H16O2. Effect of temperature on cond. ; 106. ISO-Butyric acid ethyl ester. CeHiaOa. Effect of temperature on cond. ; 106. Butyro nitrile. (Propyl cyanide). C4H7N=C3H7.CN. xXlO^ at 25° = 1; b. p. 115.4°-115.6° @ 739 mm.; 482. Butyrylcyano- see Cyanobutyryl- Butyrylcyanoamide see Butyric acid amide. Cacalia anteuphorbium. [The references to this are incomplete. ] Cond. of sap; 253, 1326. Cacodylic acid. (Dimethyl-arsinic acid). C2H702As=Me2.AsO.OH. kAXlC at 0°=4.1; 2009. At 25°=7.5 (sapon.); 855a; = 6.4 (cond.); 888; 2009; (sapon.); 738, 1141, 1150. (Colorim.); 1773. ke X 1013 at o°=0.42 (hydrol.); 2009, 2010. At 25°=3.8; 888;= 5.6 (sapon.); 855a, also 2009, 2011, and 738. Cond.; 1269, 1747, 1836. At 25°, m(32) = 1.3, (256) = 4.4, (») = 354.5; 888. Cond. with HCl and HNO3; 2009. With M0O3; 1269. With lactose; 1747. Cam] TABLES 93 Ba.2A; 2009. - Mg.2A; 1836. - Na.A at 0°; 2009. At 25°, ' m(32) = 63.7, (1024) = 74.1; 2009; 738. -B.HCl and B.HNO3; 2009. Cadmium. In complex salts; 1384, 1481, 1482, 1946. See also the following compound. Cadmium cyanic acid. C4H2N4Cd=H2Cd(CN)4. 2K.Aat25°, A(32) = 110.0, (1024) = 125.1; 1832; 1485. Caffeic acid. (3,4-Diliydroxy-cinnamic acid). C9H8O4. Cond. increased by boric acid; 1186. Caffeine. (l,3,7-Trimethyl-2,6-dioxy-purine. 1,3,7-Trimethyl-xan- thine). C8H10O2N4. kA X 10" at 25° is less than 1 (solub.); m. p. 234°; 1997. kfi X 10^° at 15° is less than 1 (colorim.); 1775. At 25°= 200 aq. [of doubtful value]; 1241. At 40.1°= 0.0004 (sapon.); 1995, 1997 and 1150. At 25°, m(22) = 0.15, (42) = 0.2, (co) = 195; [accuracy doubtful]; 1241. In HON, no cond.; 943. In SO2; 1842. In NH3, qual. ; 606. [In 1842 this is given as theine, with formula C8H10O4N2, due probably to a typographical error.] Camphocarboxylic see Camphorcarboxylic. . a-Campholenic acid. CioHi602=C9Hi6.C02H. kAXl0« at 18°= 1.7; b. p. 258°-261°. A(361) = 22.3, (1911) = 53.1, (oo) = 317; 1899. Campholic acid. CioHi802=C9Hi7.C02H. kA X 10' at 25°=4.6; diminishes on diln. A(1024) = 23.5, (2048) = 30.8, (co) = 353; 1372. cis-frans-CamphoIytic acid. C9Hi402=C8Hi3.C02H. kAXlO« at 25°=9.3; b. p. 240°-242°. A(94.5) = 10.3, (756.0) = 28.8, (oo) = 352; 1861. iso-Campholytic acid. (wo-Lauronolic acid). C9Hi402=C8Hi3.C02H. kA X 10« [at 25°] = 8.6; m. p. 133° (cor.); 1862, 1861. [This is the camphothetic acid of 1861.] A(850) = 28.7, (00) = 351; 1862. Camphononic acid. C9Hi403=C7Hi3CO.C02H. kAXlO* at 18°=3.9 (colorim.); 1663. Camphopyric acid. (Apocamphoric acid. Pyrocamphenic acid). C9Hl404=C7Hl2(C02H)2. kAXlO^ at 18°=3.5 (colorim.); 1663. d-Camphor. CioHwO. In HON, no cond.; 943. Cond. with acetic acid; 1386. Camphoramic acid see Camphoric acid amide. 94 TABLES [Cam Camphoranic acid. (a-Hydroxy-camphoronic acid). CgHiaOa +H20= C6Hio02C(C02H)2 +H2O. kAX 10' at 25°= 3.2; 1372. Second kAXlO«= 6.5 (inversion); 1638;=13; 1911. At25°, /i(64) = 127.6, (1024) = 286.2. (co) = 352; 1372. Camphorcarboxylic acid. CiiHi603=CioHi60.C02H. kAXlO* at 18°=2 (colorim.); 1563. At 25°= 1.74; 1372. At 25°, A(64) = 35.0, (1024) = 119.6, (oo) = 351; 1372. In benzene, no cond.; 289. In Me ale; 290. Na.2A; in benzene, no cond. - Na.A in Me ale; 289. Camphorcarboxylic acid amyl ester. CieHaeOa. Na.A in ether, no cond. ; 289. Camphorcarboxylic acid methyl ester. C12H18O3. Na.A in benzene, no cond. Cond. in Me ale; 289. d-Camphoric acid. CioHi604=C8Hi4(C02H)2. kAXlO^ at 18° = 2.5 aq.; 164; (colorim.); 1562, 1563. At 25°= 2.25; 1372; m. p. 186° and 187°; 1666, 1824. Second kAX 10^=7 (inversion); 1638; = 140 (part.); 370. At 25°, m(64) = 13.0. (1024) = 49.3, (oo) = 352; 1372. Also 171. In HCN, little cond.; 943. Cond. with KOH; 171. Cond. not increased by boric acid; 1184. 2K.A at 18.2°, m(150) = 75.3, (1500) = 82.2. - KH.A; 164. Camphoric acid a-mono amide. (a-Camphoramic acid). CioHi703N=C8Hi4(C02H)(CONH2). [C02H=;8.] kAXlO^ at 25°= 1.4; diminishes on diln.;=0.84 after 16 hours; 1243. At 25°, m(64) = 10.3, (256) = 17.5, (oo)=350; 1244. Camphoric acid (3-mono amide. (^-Camphoramic acid). CioHi703N=C8Hi4(CONH2)(C02H). [C02H=a.] kAXlO^ at 25°= 1.28; increases on diln.; 1243. At 25°, m(64) = 9.7, (512) = 27.7, (co) = 350; 1244. d-Camphoric acid mono aHo-methyl ester. CiiHi804=C8Hi4(C02H)(C02Me). kAXlO^ at 25°= 1.08; m. p. 85.5°. m(209.5) = 16.2, (838.0) = 31.5, (00) = 350; 1860. d-Camphoric acid mono o-methyl ester. CiiHi804= C8Hi4(C02Me) (CO2H). kAX 108 at 25°=7.95; m. p. 76°. /i(118) = 10.5, (944) = 29.1, (a>) = 350; 1860. 1-Camphoric acid. C10H16O4. kAXlO^ at 25°=2.28; m. p. 187°; 1824. Second kAX 10' =7 (inversion); 1638. Cond. with organic acids; 1638. Cap] TABLES 95 mac/.-Camphoric acid. C10H16O4. kAX 10^ at 25°=2.29; m. p. 202°-203°; 1824. Second kAX 10^=7 (inversion); 1638. d-iso-Camphoric acid. C10H16O4. kAXlO^at 25°=1.74; m. p. 171°-172°; 1824. l-fso-Camphoric acid. C10H16O4. kiX 105 at 25°= 1.60; m. p. 172.5°; 1889. = 1.74; m. p. 171°-172°; 1824. Second kA X 10^=5.9 (inversion); 1638. At 25°, Ai(70.5) = 11.7, (564) = 31.8, (co) = 352; 1889. Cond. with organic acids; 1638. 1-iso-Camphoric acid mono o-ethyl ester. Cl2H2o04= C8Hi4(C02H) (COzEt). kA X 106 at 25°= 6.5; m. p. 73.5°. /i(244) = 13.8, (488) = 19.1, (a>) = 350; 1889. inac<.-iso-Camphoric acid. C10H16O4. kAXlO^at 25°=1.74; m. p. 190°-191°; 1824. meso-Camphoric acid. C10H16O4. [This was a mixture of acids.] Second kAX 10^=6.6 (inversion); 1638. Camphoric acid imide. (Camphorimide). CioHisOzN. Cond. with HgClj; 1097. 1-Camphoronic acid. (ao(3-Trimethyl-tricarballylic acid). C9Hi406=C02H.CH2.CMe(C02H).CMe2.C02H. kAX 10* at 18°= 1.8 (colorim.); 1562, 1563. At 25°= 1.75; 1372. Second kAXlO«= 8.3 (?) (inversion); 1638. At 25°, /x(32) = 25.3, (1024) = 121.3, (c°) = 352; 1372. Camphor oxime. C10H17ON. In NH3; 604. Camphor quinone. C10H14O2. KCN derivative (=CioHi40.0K.CN) is a moderately good electrolyte; 1050. Camphothetic acid see fso-Campholytic acid. Cane sugar see Saccharose. Capric acid. CioH2o02=Me.(CH2)8.C02H. In NH3, qual.; 606. Caproic acid. (Capronic acid. Hexoic acid). C6Hi202=Me.(CH2)4.C02H. kAXlO^ at 25°=1.46; 180, 461, 1370; = 1.38; b. p. 205.7°; 601; (colorim.); 1781. A(32) = 7.5, (1024) = 40.3, (oo) = 352; 1370. In NH3, qual.; 606. Na.A at 25°, A(32) = 64.0, (1024) = 73.8; 601, 1368a. Caproic acid amide. (Capronamide). C6Hi30N=Me.(CH2)4.CONH2. Cond. with HCl; 410. With NaOH; 412. 96 TABLES [Cap iso-Caproic acid. (iso-Capronic acid). C6Hi202=Me2.CH.CHMe.C02H. kiXlO^ at 25°=1.57. A(27.8) = 7.5, (442.5) = 29.6, (cx)) = 368; 461. Cond. with organic acids; 145b. Capronamide see Caproic acid amide. Capronic acid see Caproic acid. Ckpronitrile. (iso-Amyl cyanide. Caproyl nitrile). C6HiiN=C6Hii.CN. xXlO«at 25°=3.3. Cond. with Cu oleate; and as solvent; 1569. CapryUc acid. C8Hi602=Me.(CH2)6.C02H. kiXlflS at 25"= 1.44; b. p. 237.5° (cor.). A(256) = 20.6, (1024) = 40.2, (a>) = 351; 601. In HCl, little cond.; 30. In NH3, qual.; 606. Caprylic acid ethyl ester. C10H20O2. InNHs, qual.; 606. CarbaUylic acid see Tricarballylic acid. Carbamic acid. (Aminoformic acid). CH302N=NH2.C02H. NH4.A; 302a. Carbamic acid amide see Urea. Carbamic acid benzyl ester. (Benzyl urethane). C8H902N=NH2.C02.CH2Ph. In pyridine; 754. Carbamic acid ethyl ester. (Urethane). C3H702N=NH2.C02Et. «XlO'at 18°= 5; 1470. In HON, no cond.; 943. In NH3; 610. Cond. with HgCl2; 1097. As solvent of inorg. compounds; 748, 1470. Carbamide see Urea. Carbamide imide azide see Diazo guanidine. o-Carbaminebenzene sulphonic acid see o-Sulphobenzoic acid amide. CarbaminethioglycoUic acid. C3H503NS=NH2CO.SCH2.C02H. kA X 10* at 25° = 2.66; = 2.61 (catal.); m. p. 139°-139.5° with dec; 854, 1370. A(32) = 30.5, (1024) = 136.8, (oo) = 360; 1370. CarbaminethioglycoUic acid anhydride see Diketo-tetrahydro-thiazole. Carbazole. C12H9N. InNH3, qual.; 606. Carbon disulphide. CSj. [The references to this are incomplete.] XX 10' at 18°=2; 263, 305, 384, 386, 1010, 1098, 1344, 1556. Cond. with organic compounds; 263, 386. Complex with AlBr3, EtBr; 1437. Of thin layer; 301. Effect of radium and X-rays on cond.; 417, 872, 1491, 1805. As solvent; (711), (1445). Cas] TABLES 97 Carbonic acid. CH2O3. [The references to this are incomplete. ] kAXlO^ at 18°=3; 733, 1865, 1883. Carbonic acid diethyl ester. C6Hio03=OC(OEt)2. In NH3, qual.; 606. With allyl thiocarbimide, no cond.; 1223. Effect of tempera- ture on cond.; 106. Other esters of carbonic acid. Aminophenyl ethyl carbonate see under that head. Aminophenyl methyl carbonate see under that head. Methyl-aminophenyl ethyl carbonate see under that head. Carbon tetrachloride see Tetrachloro-methane. Carbonyldi-thioglycollic acid see Dithio-carbondiglycollic acid. Carbopyrrolic acid see Pyrrolecarboxylic acid. Carbostyril. (2-Hydroxy-quinoline). CgHyON. kfiXlO' at 18°= 1.94 (colorim.); 1777. Cond. very small, due to impurity; 733. o-Carboxyanilinoacetic acid methyl ester see Phenylglycine-o-car- boxylic acid exo mono methyl ester. Carboxydehydroacetic acid. (Dehydroacetylcarboxylic acid). CgHsOe. kAXlO^ is about 3. m(158) = 300.2, (632) = 318, (co) = 350; m. p. 154°; 1399, o-Carboxymethyl-anilinoacetic acid see Phenylglycine-o-carboxylic acid eso mono methyl ester. Carbyloxime see Fulminic acid. Carminic acid. C22H22O13. Also given as C11H8O4, diHnOe, CUH12O7 and CiyHisOio. Na.A at 25°, A(32) = 58.0, (1024) = 69.6 for molecular weight 480. " =63.1, " =80.0 " " " 492. " =56.5, " =87.6 " " " 534; 1275. Carvacrol. (4-iso-Propyl-2-hydroxy-toluene) . CioHi40 = Me2CH.C6H3(OH).Me. In HBr; 29. Cond. with NaOH alone, and with HCl; 1508. Carvene see Limonene. Carvole see Carvone. Carvone. (Carvole). C10H14O. In NH3, qual.; 606. Cascarilla. [The references to this are incomplete. ] Cond. of dil. soln. of bark; 146. Casein. [The references to this are incomplete. ] The composition of casein seems to depend on its source. There are several different caseins, and the difficulty of purifying. 98 TABLES [Cas makes it impossible to get one moderately pure compound. In the following references the casein is probably from cow's milk. For a partial review of the literature see 1501. Cond. alone; 145b, 1599. With acids; 1120, 1635. With bases; 145b, 1504, 1506a, 1636. With inorg. salts; 145b, 1599. With HgCla, formaldehyde and phenol; 1599. With pepsin and with trypsin; 145b. Concentration of H and OH ions; 422, 1506, 1511b. NH4 salt; 145a, 145b, 1054, 1504, 1505, 1555. - Mg salt; 1355a. - Na salt at 25°; composition uncertain, is 4Na or 6Na.A; A(40)=46.5, (640) = 69.5; 1053.- 145a, 1054, 1504, 1505, 1555, 1599, 1636. With NaOH soln. and erepsin; 523. - Acid Na salt; 1053. Casein from cow's milk. NH4 salt. - Li neutral and acid salts. - K neutral salt. - Na neutral salt at 20°, A(1024-32) = 26.2; also acid and basic Na salts; 1118. Effect of diges- tion with pepsin and HCl; 1119. Ba, Ca and Sr salts; 1506b. Casein from goat's milk. Neutral K salt and Na salt; 1118. Effect of digestion with pepsin and HCl; 1119. iso-Casein. [The references to this are incomplete.] Na salt at 25°, A(137) = 67.5, (1096) = 89.2; 1054. Qual.; 1555. j)ara-Casein. [The references to this are incomplete. ] Cond. at 25° is about 2% higher than that of casein; 1053. Caseinogen. All references to this are given under Casein. Castor oil. [The references to this are incomplete. ] Resistance; 1010. Castor oil plant see Ricinus communis. Cerebrospinal fluid. [The references to this are incomplete. ] x; 621. Cerebrum see Brain. Cetyl alcohol. Ci6H340=Ci6H33.0H. Cond. at 0°-104°; 101, 110. In NH3, insol.; 606. In MeNH2, no cond.; 637. Cetylmalonic acid. Ci9H3604=C02H.CH(Ci6H33).C02H. kA X 10' at 25°= 3; increases on diln. m(256) = 2.6, (1024) = 6.1, (a=) = 350; 1638. Chelidonic acid. (Acetone-dioxalic acid anhydride). C7H406=CO(CH:C.C02H)2:0. At 25°, Ai(62.9) = 427, (503) = 611; 1372. Chlor- see Chloro- Chloral. (Triehloro-acetaldehyde). C2HOCl3=CCl3.CHO. InHCN, no cond.; 943. Chloral alcoholate, hydrolysis; 292. Chi] TABLES 99 Chloralcyanohydrate see TricUoro-lacto nitrile. Chloral hydrate. C2HOCl3(=CCl3.CHO) +H20=C2H302Cl3. kiX 10" at 0°=0.4 (hydroL). At 18°= 1 (hydrol.); 512. At 0.65°, X X 10« of 0.01 normal soln. = 6; 502. In NH3, qual.; 606. Cond. with inorg. acids; 741. With inorg. bases; 502, 512. Hydrolysis measured by b. p. elevation and f. p. depression; 292. Chloroacetanilino-acetic acid see Chloroacetyl-phenyl amino-acetic acid. Chloroacetic acid. C2H302C1=CH2C1.C02H. kAXlO' at 0° = 1.81 aq.; diminishes on diln.; 1018. At 14.1°= 1.58 aq.; 838. At 25°= 1.55; 1370; (neutral.); 295, 1718; (colorim.); 1643. Relative strength (polarimetric) ; 1866; (precipitation of casein); 693. Cond.; 294, 347, 441, 782, 877, 1094. At 25°, A(32) = 72.4, (1024) = 249.2, (00) = 362; 1370. In HCl, poor cond.; in HBr, HI and H2S, no cond.; 1897. In SO2; 1842. In H2SO4; 223, 1834. In N2O4, no cond.; 602. In NH3, qual.; 606. In acetone; 475. In Et ale; 647, 782, 932. In pyridine; 754. In tetranitro-methane; 1844. Cond. with HCl; 425. Cond. not increased by boric acid; 1184. With KOH; 294. With KCl; 1994. With acetic acid and NaOH; 1717, 1718. Under pressure of 1-500 atmospheres; 220. NH4.A;823. - Hg.2A; 1094. - Na.A at 25°, A(32) = 73.4,(1024) = 85.2; 1368a, 270. In Et ale; 932. - UO2.2A; 449. Chloroacetic acid amide. (Chloroacetamide). C2H40NC1=CH2C1.C0NH2. In NH3; 610. Cond. with HgCl2; 1097. Chloroacetic acid ethyl ester. C4H702Cl=CH2Cl.C02Et. xXlO^ at 25° is less than 1.7; b. p. 143.5°; 1106, 1107. Effect of temperature on cond. ; 106. As solvent; 1106, 1107. Chloroacetyl bromide. C2H20ClBr=CH2Cl.COBr. InS02; 1842. Chloroacetyl-phenyl amino-acetic acid. (Chloroacetanilino-acetic acid. Chloroacetyl-phenyl glycine). CioHio03NCl=(Ph)(CH2ClCO)N.CH2.C02H. kiXlO* at 25° = 3.4; m. p. 130°. A(200) = 81.6, (1600) = 182, (oo) = 355; 1840. Chloroamino- see Aminochloro- 100 TABLES [Chi Chloroanil. (Tetrachloro-p-benzoquinone). C6O2CI4. In NH3, qual.; 606. Chloroanilic acid. (2,5-Dihydroxy-3,6-dichloro-p-benzoquinoiie). C6H204Cl2= (OH)2C6Cl202. m(192) = 369.1, (1536) = 514.3, (oo) = 754; 577. Quoted in 389. At 25°, A(128) = 192.4, (1024) = 263.7; 1275. -729. 2K.A; 577, 1275.- 2Na.A at 25°, A(32) = 78.6, (1024) = 88.7; 1275; Ai(192) = 175.1; 577. - Na.A; 1275. o-ChloroaniUne. C6H6NC1= Cl.CeHi.NHa. keXlO" at 19° = 9.16 (colorim.); 1777. B.HCl at 25°, /i(50) = 160.0. - 2B.H2SO4; 1864. m-Chloroaniline. CeHeNCl. ks X IQii at 10°=0.66 (colorim.). At 13°=0.77 (colorim.); 1777. At 25°=4.8 (hydro!.); 660, 1293. = 3.45 (part.); 584. B.HCI at 25°, M(50) = 132.5^ 1864. M(32) = 116.6, (512) = 190.7; M(32) = 92.6; 1293. - 2B.H2SO4; 1864. p-ChloroaniUne. CeHeNCl. kaXlO" at 10°=1.24 (colorim.); 1777. At 25°=9.9 (part.); 584, 548. B.HCl at 25°, ;u(50) = 120.0. - 2B.H2SO4; 1864. Chlorobenzene. CeHsCl. In NH3, qual.; 606. p-Chlorobenzene diazonium syn-cyamde. (p-Chlorodiazo benzene cyanide). C7H4N3C1=C1.C6H4.N2.CN. AtO°, m(327) = 15.3; 735. o-Chlorobenzoic acid. C7H602C1=C1.C6H4.C02H. kiX 10^ at 18°= 1.35 (colorim.); 1563. At 25°= 1.32; 1371, 1581. At 40°= 1.0 aq. At 50°=0.9 aq. At 60°=0.8 aq. At 70°= 0.7 aq. At 80°=0.6 aq. At 90°=0.5 aq. At 99°=0.4 aq.; 1581. At 25°, A(64) = 89.2, (1024) = 238.7, (co) = 356; 1371. Na.A at 25°, A(32) = 67.3, (1024) = 77.8; 1368a. At 25°-99°; 1581. m-Chlorobenzoic acid. C7H5O2CI. kiXlO^ at 18°=1.4 (colorim.); 1563. At 25°=1.55; 1371. At 25°, A(256) = 64.3, (1024) = 116.2, (oo) = 356; 1371. p-Chlorobenzoic acid. C7H6O2CI. kiXlO^ at 18°=9.9 (colorim.); 1563. At 25°=9.3; 1371. At 25°, A(2048) = 125, (a>) = 356; 1371. Chlorobromofluoroacetic acid. C2H02ClBrF=CClBrF.C02H. kj, X 10 at 25° is about 2. A(32) = 313.9, (1024) = 350.8, (oo) = 351.6. Na.A at 25°, A(32) = 67.4, (1024) = 75.8; 1701. Chi] TABLES 101 2-Cliloro-6-bromogallic acid ethyl ester. (3,4,5-Trihydroxy-2-chloro- 6-bromo-benzoic acid ethyl ester). C9H806ClBr=(Cl)(Br)C6(OH)3.C02Et. [C02H=1.] kx X 10^ at 25°= 2.2; diminishes on diln.; m. p. 134°-135°. m(32) = 3.0, (256) = 6.0, (oo) = 349; 404. 2-Chloro-6-bromogallic acid methyl ester. (3,4,5-Trihydroxy-2-chloro- 6-bromo-benzoic acid methyl ester). CsHeOsClBr. kiX 10^ at 25°=5.2; diminishes on diln.; m. p. 162°-163°. Ai(32) = 4.5, (256) = 7.2, (co) = 350; 404. p-Chlorobromosuccinic acid. C4H404ClBr=C02H.CHCl.CHBr.C02H. In SO2, insol.; 1842. a-Chlorobutyric acid. C4H702Cl=Me.CH2.CHCl.C02H. kxX 10' at 25°= 1.5; diminishes on diln.; b. p. 101.3° @ 15 mm. A(32) = 69.8, (1024) = 232.5, (oo) = 356; 1099. /3-Chlorobutyric acid. C4H702Cl=Me.CHCl.CH2.C02H. kAX 10^ at 25°=9; b. p. 108.5°-109.5° @ 17 mm. A(32) = 18.6, (1024) = 91.7, (co) = 356; 1099. 7-Chlorobutyric acid. C4H702C1=CH2C1.CH2.CH2.C02H. kAXlO^ at 25°=3. A(32) = 11.5, (64) = 16.2, (oo) = 356; hydrolyzes to HCl; 1099. Chlorocarbonic acid see Chloro-fonuic acid. l^-Chlorocinnamic acid. (a-Chloro-iso-cinnamic acid). C9H702Cl=PhCCl:CH.C02H. kiX 10^=1.14; diminishes on diln.; k (203) = 1.14, (812) = 1.00; m. p. 110.5°; 1299; quoted in 1683. P-Chlorocinnamic acid. (Phenyl-a-chloroacrylic acid). C9H702Cl=PhCH:CCl.C02H. kiX 10^=1.05; diminishes on diln.; k (273) = 1.05, (1892) = 0.087; m. p. 139°; 1299; quoted in 1683. j3-Chlorocinnamic acid. (|3-Chloro-iso-cinnamic acid). C9H7O2CI. kAXl0*=2.75; diminishes on diln.; k(342) = 2.75, (1368) = 2.67; m. p. 132.5°; 1299; quoted in 1683. aZZo-^-Chlorocinnamic acid. (/3-Chlorocinnamic acid). C9H7O2CI. kAXl0*=2.82; diminishes on diln.; k (707) = 2.82, (1414) = 2.75; m. p. 143°; 1299; quoted in 1683. o-Chlorocrotomc acid. C4H602Cl=MeCH:CCl.C02H. kA X 10* at 25°=7.2; increases on diln. A(32) = 49.7, (1024) = 203.7, (oo) = 357; 1371. /S-Chlorocrotonic acid. C4H602Cl=MeCCl:CH.C02H. kAX 10* at 25°= 1.44. A(32) = 23.4, (1024) = 113.4, (co)=357; 1371. Na.A at 25°, A(32) = 68.2, (1024) = 78.8; 1368a. a-Chloro-iso-crotonic acid. C4H6O2CI = MeCH : CCl. CO2H. kAX 10^ at 25°= 1.58; 1371, 1368. 102 TABLES [Chi A(32) = 71.6, (1024) = 250.7, (oo) = 357; 1371. Na.A at 25°, A(32) = 68.4, (1024) = 79.2; 1368a. |3-Chloro-!so-crotonic acid. C4H602Cl=MeCCl:CH.C02H. kA X 10* at 25°=9.47; increases on diln. A(32) = 19, (1024) = 95.7, (co) = 357; 1371. Na.A at 25°, A(32) = 68.4, (1024) = 78.9; 1368a. Chloro-dibromo-acetic acid. C2H02ClBr2=CClBr2.C02H. kA X 10 at 25° is about 3. - A(32) = 318.6, (1024) = 351, (°o) = 353.8. Na.A at 25°, A(32) = 68.1, (1024) = 78.2; 1701. Chloro-difluoro-acetic acid. C2H02C1F2=CC1F2.C02H. At 25°, A(32) = 379.8, (256) = 391.0; m. p. 22.9°. Na.A at 25°, A(32) = 83.0, (64) = 86.3, (co) = 96.3; 1690. m-Chloro-dimethyl-aniline. C8HioNCl= Cl.C6H4.NMe2. Weaker base than dimethyl-aniline, (hydrol. of B.HCI); 660. Chloroethyl alcohol see Glycol chlorohydrin. Chloroform see Trichloro-methane. Chloro-formic acid ethyl ester. (Chlorocarbonic acid ethyl ester). C3H602Cl=ClC02Et. In SO2; 1842. Effect of temperature on cond. ; 106. 2-CIilorogallic acid ethyl ester. (3,4,5-Trihydroxy-2-chloro-benzoic acid ethyl ester). C9H906Cl=Cl.C6H(OH)3.C02Et. [C02H=1.] kAXlO' at 25°= 1.8; m. p. 106°-107°. m(24.2) = 0.7, (193.6)=2.5, (oo)=350; 404. 2-Chlorogallic acid methyl ester. (3,4,5-Trihydroxy-2-chloro-benzoic acid methyl ester). CsHtOsCI. kAXlO' at 25°=3.6; diminishes on diln.; m. p. 159°-160°. m(32) = 1.2, (256) = 2.7, (o=) = 351; 404. Chlorohydrin. C3H702C1=CH2C1.CH(0H).CH20H. ^cXlO'at 25°=4.9. Cond. with Cu oleate; and as solvent; 1569. Chlorohydroxy- see Hydroxy-chloro- Chloromaleic acid. C4H3O4CI. InS02, insol.; 1842. Chloromalonic acid. C3H304C1=C1CH(C02H)2. kA X 10^ at 25° is about 4; m. p. 132° dec; 1838. Second kiX 10*= 1.94 (cond.); 1911. At 25°, m(32) = 236, (1024)=411, (a>) = 358; 1838. Chloromethyl- see Methylchloro- Chloronaphthophenazonium see Chlorophenylnaphthophenazonium. Chloronitro- see Nitrochloro- Chi] TABLES 103 o-Chloro-oxanilic acid. (Anilinochloro-oxalic acid. Chloroanilino- oxalic acid). C8H603NC1=C02H.C0.NH(C6H4C1). kAX 10^ at 25°=2.03; diminishes on diln. m(32) = 191.9, (1024) = 334.8, (oo) = 351; 1371. p-Chloro-oxanilic acid. CsHeOaNCl. kA X 10^ at 25°= 1.4; increases on diln. m(256) = 285.8, (1024) = 330.0, (co)^351; 1371. o-Chlorophenol. C6H60C1= Cl.CeHi.OH. kAX 10"* at 25°=7.7 (catal.); 1150 and 733, 1718; = 360 (cond.); 70. A(40.6) = 0.4, (324.8) = 1.6, (00) = 356; 70. Cond. in Et ale. Cond. with NaOH; 1508, 1718. Na.A at 25°, A(32) = 72.0, (1024) = 88.7 aq.; 733. p-Chlorophenol. CeHsOCl. kAXlQi" at 25°=4.1 (catal.); 1150 and 733, 1718; = 210; 70. A(64) = 0.4, (512) = 2.3, (co) = 356; 70. Cond. in Et ale. Cond. with NaOH; 1508, 1718. Chlorophenoplienazonium see Chloroplienylplienazoiiium. 6-Chloro-o-N-phenylnaphtliophenazonium hydroxide. C22H1BON2CI. This compound, not isolated, exists in the solution of rosindone + INaOH. At 0°, Ai(512) = 110 after two minutes. B.Cl=C22Hi4N2Cl2 (Rosindone chloride) at 25°, m(32) = 124.5 ex- trapolated, (1024) = 138.8. Cond. with NaOH; 770. norm.-p-Chlorophenyl-nitromethane. C7H602NC1= CI.C6H4.CH2.NO2. In 50% Me ale. at 1.1°, very small cond.; m. p. 33°-34°. K salt and Na salt; 1464. iso-p-Chlorophenyl-nitroniethane . CyHe O2 N CI . In 50% Me ale, conducts well, but becomes transformed to the normal compound; m. p. 64°. Na salt; 1464. 3-Chloro-N-phenylphenazonium bromide. (Chloro-N-phenophenazo- nium bromide). Ci8Hi2N2ClBr. M(64) = 82.8, (1024) = 101,1; 770. 4-Chloro-o-phthaUc acid. C8fe604Cl=Cl.C6H3(C02H)2. [C02H=1, 2.] kA X 10^ at 25°=2.5; extrapolated on account of great dissociation at small diln. ;«(64) = 259, (1024)=446, (co) = 356; 1372. Chloropicrin see Nitrotrichloro-methane. a-Chloropropionic acid. C3H502Cl=Me.CHCl.C02H. kA X lO' at 25° = 1.6; diminishes on diln.; b. p. 82.5° @ 13.5 mm. A(32) = 71.6, (1024)= 237.2, (oo) = 358; 1099. 104 TABLES [Chi |3-Chloropropionic acid. C3H602C1=CH2C1.CH2.C02H. kA X 10^ at 25°=8.6; increases, then diminishes on diln.; m. p. 40°. A(32) = 18.3, (1024) = 89.1, (oo) = 358; 1099. Chloro-salicylic acid see 2-Hydroxy-chlorobenzoic acid. o-Chlorosuccinanilic acid. (Anilinochlorosuccinic acid. Chloroanili- nosuccinic acid). CioHio03NCI=C02H.C2H4.CONH(C6H4Cl). kA X 10* at 25°=2.1; slight increase on diln. /i(128) = 17.7, (1024) = 47.6, (co) = 350; 1372. m-Chlorosuccinanilic acid. C10H10O3NCI. kA X 10* at 25° =2.1; slight increase on diln. ju(128) = 17.4, (1024) =47.2, (00) = 350; 1372. p-Chlorosuccinanilic acid. C10H10O3NCI. kA X 10* at 25°=2.1; slight increase on diln. iu(128) = 17.3, (1024)=47.9, (oo) = 350; 1372. inart.-Chlorosuccinic acid. C4H604C1=C02H.CHC1.CH2.C02H. kAXlO^ at 25°=2.94; m. p. 153°-154°; 1824, 1838. Second kAX 10*= 3.6 (oond.); 1911. At 25°, m(32) = 92.2, (1024) = 294, (co) = 356; 1838. d-Chlorosuccinic acid. C4H6O4CI. kA X 103 at 25°=2.94; m. p. 176°; 1824. l-Chlorosuccinic acid. C4H5O4CI. kAXlO^ at 25°=2.94; m. p. 176°; 1824. p-Chlorotoluene. C7H7CI. In NH3, qual.; 606. i8-Chloro-trimethylene diamine. C3H9N2C1=CHC1(CH2.NH2)2. B.2HC1 at 25°, A(32) = 106.9, (1024) = 127.8; 270. S-Chlorovaleric acid. C6H902C1=CH2C1.(CH2)3.C02H. kiX 10* at 25°=2; b. p. 141°-149° @ 12 mm. with dec. A(32) = 9, (1024)=47.8, (°o) = 354; 1099. Chromicyanic acid. C6H3N6Cr=H3Cr(CN)6. 3K.Aat25°, A(32) = 130.5, (1024) = 160.8; 1837. Chromioxalic acid. C6H30i2Cr=H3Cr(C204)3. 3NH4.A; 1192, 1198, 1516. - 3K.A; 971, 1515, 1516. - 3Ag.A; 971. -3Na.A at 25°, A(32) = 73.2, (1024) = 105.6; 1516, 1192, 1198. Chromithiocyanic acid. C6H3N6S6Cr=H3Cr(CNS)e. 3NH4.A; compound with acetic acid; 1164. - 3K.A; 1192, 1641. - 3 Na.A at 25°, A(20) = 265, (1280) = 344; 1192.- Com- pound with urea; 1944. Chromium see Chromicyanic acid, Chromioxalic acid, Chromithiocya- nic acid and Chromium complex salts. Chromium complex salts. 320b^ 1164, 1384, 1487, 1515, 1516, 1573, 1641, 1944. Cin] TABLES 105 aZio-Chrysoketonecarboxylic acid. CisHioOa. Comparative strength (colorim.); m. p. 285°-286° with dec; 1665. aZto-Chrysoketonecarboxylic acid ethyl ester. C20H14O3. Comparative strength; m. p. 187°-188°; 1665. Chrysophenine. A salt of Stilbenedisulphonic acid disazophenol mono ethyl ether. C28H2208N4S2K2=OH.C6H4.N2.C6H3(S03K).CH:CH.CaH3 (S03K).N2.C6H40Et. At 90°, m(200)=424, (1600) = 512; 976a. Chyle. [The references to this are incomplete. ] Cond.; 253. Cinchomeronic acid see Pyridine-3,4-dicarboxylic acid. iso-Cinchomeronic acid see Pyridine-2,5-dicarboxylic acid. Cinchona. [The references to this are incomplete. ] Cond. of dil. soln. of bark; 146. Cinchonamine. C19H24ON2. kfl X 10^ at 15° is less than 1 (colorim.). Second ks X lO^" is about 3 (colorim.); 1776. Cinchonidine. C19H22ON2. kflXlO' at 15°=3.72 (hydrol.); 1779. Second ks X lO'" is about 3.3 (colorim.); 1776. In NH3, qual.; 606. With allyl thiocarbimide, no cond.; 1223. Relative strength; 1631. B.HCl at 25°, A(32) = 76.9, (1024) = 91.1; 270. - 2B.H2SO4; 1611. Cinchonine. C19H22ON2. ksXlO^ at 15°=0.16 (hydrol.); 1779. At 18°=1.2; 1224. Second ks X 10" is about 3.3 (colorim.); 1776. At 18°, m(14020) = 24, («>) = 194; 1224. Cond. with acids and phenols in Me ale. and acetone; 1620. B.HCl at 25°, A(64) = 82.1, (1024) = 90.9; 270; 177, 1224. Salts of organic acids; 1620. Cinchoninic acid. (QuinoIine-4-carboxylic acid. 7-Quinoline car- boxylic acid). CioH702N=C6H4.C3H2N.C02H. kAXlO'at25°=1.3. m(64) = 9.9, (1024) = 37.2, (oo) = 355; 1372. Cinenic see Cineolenic. Cineole. (Eucalyptole). CioHigO. At 22°, almost no cond. With HCl, shows almost complete hydrolysis; 1553. Cineolenic acid. (Cinenic acid). C9Hi603=C8Hi60.C02H. (a). Acid; m. p. 83°-84°. At 18°, m(32) = 52.2, (1024) = 62.5; [this apparently means the conductivity of a salt]; 1544. 106 TABLES [Cin (6). fi-stabik Acid; b. p. 124.5°-125° @ 12 mm. At 20°, m(32) = 62.1, (1024) = 73.5; [this apparently means the conductivity of a salt]; 1546. CineoUc acid. CioHi605=C8Hi40.(C02H)2. kAXlO) = 380.6; 1295. In Me ale; 1390. In pyridine; 754. Na.A at 25°, m(64) = 76.7, (1024) = 82.9; 1295. In Me ale; 1390. Cyanonitrosoacetic acid methyl ester. C4H4O3N2. kAXlQS at 0°=1.32 aq. At 18°=2.21 aq.; 1296. At 25°=3.15 (extrapolated); m. p. 119°; 1295;=2.61 aq.; 1296. At 35°= 3.08 aq. At 40°=3.24 aq.; 1296. At 25°, /i(32) = 11.9, (1024) = 59.5, (o°)=383.4; 1295. Na.A at 25°, m(32)=74.8; 1296. /ii(64)=78.1, (1024) = 85.6; 1295. Cyanonitrosoacetic acid propyl ester. C6H8O3N2. kAX 10^ at 25°=2.3; m. p. 106°-107°. Ai(64) = 14.2, (1024) = 53, (00) = 377.5. Na.A at 25°, Ai(128) = 76.0, (1024)=79.5; 1295. Cyanooziminoacetic acid see Cyanonitrosoacetic acid. p-Cyano phenol. (p-Hydroxy-benzonitrile). C7HbON=CN.C6H4.0H. kAX 10^ at 0° is less than 3 aq.; 733. At 25°=1.3 (catal.); 1150, 733;=6aq.; 733. At 35°= 8 aq.; 733. At 25°, A(32) = 0.5, (256) = 1.3, (oo)=356; 733. Na.A at 25°, A(32) = 66.3, (1024)=78.0 aq.; 733. Cyanopropionylacetic acid methyl ester. C7H903N=EtCO.CH(CN).C02Me. kAXlO* at 25°=7.5; diminishes on diln.; m. p. 39°-40°. A(256) = 122.2, (1024) = 190.5, (oo) = 352; 699. Na.A at 25°, A(32) = 67.0, (1024)=78.9; 700, 699. Cyanotoluene see Tolunitrile. Cyano-iso-valerylacetic acid methyl ester. C9Hi303N=Me2CH.CH2.CO.CH(CN).C02Me. kAXl0^at25°=7; 700. Cyanuric acid. (iso-Cyanuric acid). C3H3O3N3. kAXlO' at 25°= 1.8; 742;=3.8; 70. At 0°, ju(64) = 0.66; 1428. At 25°, m(128) = 1.7, (1024) = 5.1; 742. /t(32) at 70° = 2.6; at 80°=2.8; at 90°=3.9; at 96.2°=4.2; 1428. At 30°-63°; 742. In NH3, qual.; 606. In pyridine; 754. Hg.A, e. m. f.; 963. - 2 Na.A at 25°, ^(32) = 176.5, (512) = 249.2. 3 Na.A at 25°, m(32) = 396, (512)=485; 742, 1428. Cyanuric acid N-dimethyl ester. (Dimethyl-cyanuric acid). C5H7O3N3. At 25°, m[(64)?]=0.26; m. p. 222°; 1428. Cyclobutane-carboxylic acid see Tetramethylene-carboxylic acid. 116 TABLES [Cyc Cycloheptane-carboxylic acid. (Suberane carboxylic acid). C8H14O2. kAXlO^ [at 25°]= 1.22. A(240.6) = 18.5, (962.4) = 35.7, (oo) = 352; 2026. Cycloheptatriene-carboxylic acid see Jso-Phenylacetic acid. 1-Cycloheptene-l-carboxylic acid. (Suberene carboxylic acid). C8Hl202. kAXlO« at 25°=9.92 aq.; 1633; = 8.3; (m. p. of amide is 134°- 135°); 1976. A(256) = 16.9, (1024) = 33.2, (oo) = 375; 1976. 2-CycIoheptene-l-carboxylic acid. C8H12O2. kAXlO^ at 25°=2.7 aq.; m. p. 18°-20°. A(63.9) = 15.3, (255.5) = 29.9, (00)= [375]; 1533. Cyclohexane-acetic acid. (Hexahydro-phenyl acetic acid). C8Hl402= C6H11.CH2.CO2H. kiXlO^ [at 25°] = 2.36. A(186.6) = 28.4, (1173.1) = 60.1, (co) = 352; 2026. Cyclohexane-carboxylic acid see Hexahydro-benzoic acid. Cyclohexane-propionic acid. (/3-Hexahydro-phenyl propionic acid). C9Hi602 = C6Hix.CH2.CH2.C02H. kiXlO^ [at 25°] = 1.34. A(185) = 17.1, (1480) = 46.2, (oo) = 352; 2026. Cyclohexene-acetic acid. Liquid isomer. C8H12O2. kxXlO^ [at 25°] = 2.60; 2026. Cyclohexene-acetic acid. Solid isomer. C8H12O2. kiXlO^ [at 25°]=2.49; m. p. 38°. A(52.2) = 12.6, (835.5) = 47.4, (co) = 352; 2026. Cyclopentane-carboxylic acid see Pentamethylene-carboxylic acid. Cyclopentane-dicarboxyUc acid see Pentamethylene-dicarboxylic acid. Cyclopropane-carboxylic acid see Trimethylene-carboxylic acid. Cymene. CioHi4=Me.C6H4.CHMe2. K X 10^ at 25° is less than 2; b. p. 167°-169° @ 740.2 mm. In HBr, HCl and H2S, no cond.; 147a. Cond. with other compounds; 1388. Cytisine. C11H14ON2. Cond.; m. p. 152°-153°; 303. D. Dahl's salt see l-Naphthylaniine-4,7-disulphonic acid. Datura stramonium. (Thorn-apple). [The references to this are in- complete. ] Cond. of dil. soln. of leaves; 146. Of root and stalk; 1326. Dehydroacetic acid. C8H8O4. kAXlO'at25°=5.3; 1372; = 1.0; 397. Dia] TABLES 117 m(119.4) = 8.9, (955.2) = 24.3, (oo) = 351; 1372. Cond. not increased by boric acid; 1184. iso-Dehydroacetic acid. (Dimethyl-coumalic acid. Hydroxy-mesi- tene-dicarboxylic acid anhydride). C8H8O4. kAXlO^ at 25°=5.3; m. p. 155°; 1186, 1372. m(65.3) = 155.6, (1044.8) =305.1, (oo) = 353; 1372. Cond. with boric acid; 1186. Dehydroacetylcarboxylic acid see Carboxydehydroacetic acid. Dehydrodiacetyl-laevulinic acid. C9H10O4. kAXlO'^=6.8; m. p. 151.5°-152°. m(265) = 44.0, (1060) = 84.2, (co) = 352; 1202. Desoxy-3-methylxanthine see 3-Methyl-2-oxy-l,6-dihydro-purine. Desoxytheophylline see l,3-Dimethyl-2-oxy-l,6-diliydro-purine. Desoxyxanthine see 2-Oxy-l,6-dihydro-purine. Dextrose see Glucose. Di- see also Bi- Diaceto-acetic acid ethyl ester. C8Hi204= (MeCO)2CH.C02Et. At 25°, A(128) = 4.22 after standing one-quarter hour; 698. Diacetone alcohol. CiRj202. Cond. with bases; 979. Diacetyl-diketo-hexamethylene-dicarboxylic acid. C12H12O8. m(1000) = 321.9; dec. 246°; 558. Diacetyl-succinic acid. C8H10O6. InNHs, qual.; 606. Diacetyl-tartaric acid. C8Hio08= (MeC02)2C2H2(C02H)2. kA X 10^ at 25° is more than 3. The anhydride (m. p. 128°- 129°) dissolved in water gives at 25°, ai(32) = 214, (1024) = 517, (co) = 354. No constant can be calculated.; 1838. Deakin, Rivett, Jour. Cham. Soc. 101, 127, (1912), find kA X 10^ at 25°=2.5 in strong soln. Second kA X 10^ approxi- mates 1.1 (cond.). Diacetyl-tartaric acid anhydride. C8H8O7. See the acid. DiaUyl-malonic acid. C9Hi2q4=(CH2:CH.CH2)2C(C02H)2. kAXlO' at 25°=7.6; diminishes on diln.; m. p. 133°. i«(32) = 136.0, (1024) = 313, (00) = 353; 1838. Dialuric acid. (5-Hydroxy-barbituric acid). C4H4O4N2. kA at 25° is probably of the order of 10~*. /i(128) = 51.5, (1024) = 67.7; 1748. InNHs, qual.; 606. Diamino-benzene see Phenylene-diamine. 3,5-Diamino-benzoic acid. C7H802N2=(NH2)2C6H3.C02H. [C02H=1; NH2=3, 5.] 118 TABLES [Dia kAXlO* at 25°=5; k on diln. diminishes, with minimum value near v(288), then increases. A(36) = 6.9, (288) = 12.5, (576) = 17.9, (oo) = 354; 175. Diamino-caproic acid see Lysine. 2,6-Diamino-phenol-4-sulphomc acid. C6H8O4N2S. [0H=1.] Cond. alone and with NaOH; 1508, 1718. 2,3-Diamino-propiomc acid. C3H802N2=CH2(NH2).CH(NH2).C02H. Cond. alone, and with organic acids; 145a. Diamino-stilbene dicarboxylic acid. (Anilinoglyoxylic acid). C16H14O4N2 or C8H7O2N. a- and j3- acids. Cond. with KOH; 499. [In 798 it is said that these acids in 499 should be interchanged. ] Diamino-triphenyl carbinol. Ci9Hi80N2=(NH2C6H4)2.CPh.OH. ksXlO* at 21°=4 (colorim.); 1617. Di-iso-amyl amine. CioH23N=(C5Hii)2.NH. keXlO* at 25°=9.6 aq.; about 16% too high. A(216) = 70.6, (432) = 87.6, (oo) = l9l; 271. In NH3, qual.; 606. B.HCl at 25°, A(32) = 80.2, (1024) = 91.6; 270. Diamyl ether see Amyl ether. Diamyl-|8-naphthyl amine. C20H29N. In SO2; 1842. Dianisal see Dimethoxy-dibenzal. Diaterebic acid anhydride see Terebic acid. Diazo compounds. At the present time the nomenclature of diazo compounds is not settled. Their structure also is still a matter of dispute. The most general usage is to speak of the compound as a diazo body, while its salt is a diazonium salt, e. g. diazo- benzene, benzenediazonium chloride. This is done regard- less of the question as to whether there are always two isomers, one a neutral body (diazo) the other a salt-forming body (diazonium). In these tables there is, therefore, a lack of uniformity in the position of diazo compounds, in- creased by the fact that the cyanides, chlorides, etc. are regarded by some as separate compounds and by others as salts. A duplication of references has been used to cover such differences of opinion, since our present knowledge does not seem to justify any final conclusion. p-Diazo anisole see p-Anisole diazonium hydroxide. Diazo benzene see Benzene diazonitxm hydroxide. Diazo benzene acid see Phenylnitroamine. Dib] TABLES 119 Diazo benzene cyanide. C7H6N3=Ph.N2.CN. At 0°, m(64) = 25.0, (256) = 30.3. Cond. with HON; 735. Diazo benzene p-sulphonic acid. (Diazo sulphanilic acid). C6H4O3N2S. AtO°, m(64) = 1.5; 635. Cond. with NaOH; 635, 731. K.A; 774.- a») = 354; 1372. 4,6-Dibromo-amline-3-sulphonic acid. C6H503NBr2S. kA X 10^ at 25°=2.9; diminishes on diln. A(71.9) = 262, (1150.4) = 340, (oo) = 354; 1372. 2,6-Dibromo-amline-4-sulplioiiic acid. C6H603NBr2S. At 25°, A(64) = 330.1, (1024) = 338.4, (oo) = 354; 492. Dibromo-barbituric acid. C4H203N2Br2. kxXlO^ at 25°=8.6; diminishes on diln. because of decomposi- tion. m(32) = 5.9, (512) = 24.2, (co) = 358; 1748. Dibromo-benzene. C6H4Br2. In NH3, qual.; 606. 2,4-Dibromo-benzene diazonium syn-cyanide. C7H3N3Br2=Br2.C6H3.N2.CN. At 0°, /i(512) = 5.0. In Et ale. ; 735. 2,4-Dibromo-benzene diazonium hydroxide. (2,4-Dibromo-diazo benzene). C6H40N2Br2=Br2.C6H3.N2.0H. kiXlO^at 0°=1.36; 501. Ai(256) = 23.7, (512) = 31.2, (co) = i37; 601. B.CN; 735. Dibromo-fluoroacetic acid. C2H02Br2F=CBr2F.C02H. At 25°, A(32) = 338.1, (1024) = 359.8, (°o) = 360.1; b. p. 198°. Na.A at 25°, A(32) = 71.7, (1024) = 82.3; 1694. Dibromo-gallic acid. (3,4,5-Trihydroxy-2,6-dibromo-benzoic acid). C7H406Br2=Br2.C6(OH)3.C02H. [C02H=1.] kAXl02at25°=1.21. M32) = 162.3, (1024) = 337.7, (oo) = 352; 1371. Dib] TABLES 121 Dibromo-gaUic acid ethyl ester. C9H805Br2=Br2.C6(OH)3.C02Et. kA X 10« at 25° is at least 1; m. p. 137°. m(80) = 4.8, (630) = 10.7, (oo) = 349;- but some HBr is probably present, making the values too high; 404. Dibromo-gallic acid methyl ester. C8H606Br2. kAXlO«at 25°=1.1; m. p. 169°. iu(32) = 2.1, (256) = 5.7, (oo) = 350; 404. Dibromo-hydroshikimic acid. (Dibromo-shikimic acid. Hydroshiki- mic acid dibromide). C7Hio06Br2. kA X 10' at 12° = 8; m. p. about 188° with dec. m(41.8) = 132.5, (334.0) = 239.1, (co) = 294.6; 541. Dibromo-hydroxy- see Hydroxy-dibromo- 2,3-Dibromo-l-indone. (Dibromo-indenone. Dibromo-ketoindene). CgHiOBrj. Comparative strength (colorim.); 1665. 3,4-Dibromo-l-methylpyrrylglyoxylic acid. C7H603NBr2=Me.N.C4HBr2(CO.C02H). At 25°, A(294.8) = 334.5, (1179.4) = 355.4, (oo) = 357; m. p. 160°; 23. jS-Dibronio-methylsiilphonepropionic acid . C4H6O4Br2S=CHBr2.S02.CH2.CH2.C02H. kAX 10^ [at 25°] =2.1; diminishes on diln. /i(32) = 27.8, (512) = 96, (oo) = 352. Na.A [at 25°], /t(32) = 63.0, (256) = 71.2; 1134. ao-Dibromo-propiomc acid. C3H402Br2=CH3.CBr2.C02H. kAX 10^ at 25°=3.3; diminishes on diln.; m. p. 61°. A(32) = 223, (1024) = 345, (co) = 357; 1840. a/S-Dibromo-propionic acid. C3H402Br2=CH2Br.CHBr.C02H. kAX IC at 25°=6.7; diminishes on diln.; m. p. 64°. A(32) = 131, (1024) = 332, (oo) = 357; 1840. Dibromo-shikimic see Dibromo-hydroshikimic. sj^m.-Dibromo-succinic acid. C4H404Br2=C02H.CHBr.CHBr.C02H. kAXlO^ at 25° is over 5; m. p. is over 200°; 1838, 1638. Second kA X 10'= 1.54 (part.) ; 370. At 25°, m(32) = 246, (1024) = 571; 1838, 1638. InNHs, qual.; 606. Na.A; 370.- 2Na.A at 25°, A(32) = 79.7, (1024) = 96.7; 270,370. jso-Dibromo-succinic acid. C4H404Br2. At 25°, m(65.2) = 283, (1043) =463; m. p. 161°; 1638. 3,5-Dibromo-2-toluidine-4-sulphonic acid. C7H703NBr2S = NH2.C6HBr2(Me).S03H. [Me=l; NH2=2; S03H=4.] kA X 10^ at 25°=3.8; diminishes on diln. A(64) = 269.3, (512) = 304.8, (co) = 354; 492. 122 TABLES [Dib Di-iso-butyl amine. C8Hi9N=(C4H9)2NH. ks X 10* at 25° = 5 aq.; diminishes on diln.; about 16% too high. A(64) = 31.7, (256) = 55.8, (oo) = 194; 271. In HaS, good cond.; 1897. B.HCl at 25°, A(32) = 82.6, (1024) = 94.4; 270. Di-zso-butyl-dithio carbamic acid. (Di-iso-butyl-thiosulphocarbamic acid). C9Hi9NS2=(C4H9)2N.CS.SH. Cu.2A in benzene, little cond. ; 431. Di-fso-butyl-pimelic acid. C16H28O4. Too insol. to get k accurately; m. p. 82°-84°; 1412. cis-sym.-Di-fso-butyl-succinic acid. Cl2H2204=C02H.CH(C4H9).(C4H9)CH.C02H. kiXlO* at 25° = 5.6; m. p. 97°-98°. /i(668.5) = 157.0, (1337.0) = 198.0, (00)= [351]; 236. frans-si/m.-Di-fso-butyl-succinic acid. C12H22O4. kAXlO* at 25°=2.25; m. p. 193°-195°. Ai(1060) = 134.5, (2120) = 172.2, (00)= [351]; 236. Di-fso-butyl-thiosulphocarbamic acid see Di-fso-butyl-dithio-carbamic acid. Dicarboxyl-glutaconic acid tetraethyl ester. Ci5H2208=(C02Et)2CH.CH:C(C02Et)2. Fe.3A, in Et ale; 756. - Na.A in SO2, no cond.; 1842. |3 7-Dicarboxylic-7-valerolactone. (/3 7-Dicarboxylic^-valerolactonic anhydride). C7H806= C6H604(C02H)2. kAX 10' at 25°=6.6; diminishes on diln.; m. p. 168° with dec. M(32) = 129, (1024) = 308, (ra) = 352; 1839. Dichloro-acetic acid. C2H202Cl2=CHCl2.C02H. kAXlO^ at 0° is about 7; 515, 2004. At 18°=5.15; 460. At ■ 21.5°=6.3 for v(20); 1416. At 25°=5.14; 1370;=5.7 aq.; 515; (neutral.); 295; (precipitation of casein); 693; (dis- sociation); 1972, 1973. Cond. at 0°; 2004. At 12.5°; 709. At 17°; 1011. At 18° and 52°; 43. At 25°, A(32) = 253.1, (1024) = 360.1, (oo) = 361; 1370; 294, 877. In H2SO4; 157, 157a, 750. In NH3, qual.; 606. In Et ale; 654, 667, 1579, 1970, 1971. In Me ale; 1579. Cond. with KOH; 294. Under pressure of 1-500 atmospheres; 220. K.A; 294. - Na.A at 25°, A(32) = 71.9, (1024) = 81.8; 1368a. At 18° and 52°; 43. - UO2.2A; 449. Dichloro-acetic acid ethyl ester. C4H6O2CI2. Effect of temperature on cond. ; 106. Dichloro-aniline-3-sulphonic acid. C6H603NCl2S=Cl2.C6H2(NH2).S03H. [NH2=1.] Die] TABLES 123 kAXlQS at 25°= 1.6; diminishes on diln. A(128) = 130.1, (1024) = 227.7, (°o) = 354; 492. Dichloro-barbituric acid. C4H2O3N2CI2. kAXlO^ at 25°= 1.75; diminishes on diln., because of decomposi- tion in soln. m(64) = 8.4, (1024) = 29.3, (oo) = 358; 1748. /um.-a/3-Dicliloro-butyric acid. C4H602Cl2=Me.CHCl.CHCl.C02H. kAXl03=6.1; m. p. 78°. A(32) = 127.5, (1024) = 314.1, (co) = 357; 1254. maZ.-a|S-Dichloro-butyric acid. C4H6O2CI2. kAXl0'=8.2; increases on diln.; m. p. 63°. A(32)=41.3, (1024) = 337.3, (oo) = 357; 1254. Dichloro-fluoroacetic acid. C2H02Cl2F=CCl2F.C02H. At 24.7°, A(32) = 332.7, (1024) = 356.4, (oo) = 358.4; b. p. 162.5°; 1700; qual. (sapon.); 1691. Na.A at 25°, A(32) = 73.3, (1024) = 85.3; 1700. Dichloro-gallein. C20H10O7CI2; formerly given as C20H8O7CI2. In MeNH2, very poor cond. ; 637. 2,6-Dicliloro-gallic acid ethyl ester. (3,4,5-Trihydroxy-2,6-dichloro- benzoic acid ethyl ester). C9H806Cl2=Cl2.C6(OH)3.C02Et. [C02Et=l.] kAXlO' at 25°=4.2; m. p. 151°-153°. m(32) = 1.3, (256) = 3.7, (a>) = 349; 404. 2,6-DicliIoro-gallic acid methyl ester. C8H60bC12. kAXlO^ at 25°=6.0; increases on diln.; m. p. 160°-170°. iu(32) = 1.5, (256) = 4.6, (oo) = 350; 404. Dichloro-hydrin. (s^/m.-Dichloro-iso-propyl alcohol). C3H60Cl2=CH2Cl.CHOH.CH2Cl. xxl05at25°=1.09. Cond. with Cu oleate; and as solvent; 1569. Dichloro-hydroxy- see Hydroxy-dichloro- /3-Dichloro-methylsulphonepropionic acid. C4H604Cl2S=CHCl2.S02.CH2.CH2.C02H. kAX 10^=2; diminishes on diln. ;i:(32) = 26.9, (256) = 70.5, (oo) = 352; 1134. Dichloronitro- see Nitrodichloro- 2,4-Dichloro-phenol. C6H40Cl2= Ck.CeHs.OH. kAXlO^ at 25°=1.3 (sapon.); 733 and 1150;=2; 733; (neutral.); 1718. A(64) = 0.5, (256) = 1.1, (co) = 356; 733. - 1508, 1718. Cond. with NH3; 733. With NaOH; 1508, 1718. NH4.A. - Na.A, A(32) = 64.2, (1024) = 76.1; 733. 3,6-Dicliloro-o-plithalic acid. C8H404Cl2=Cl2.C6H2(C02H)2. [C02H=1, 2; Cl=3, 6.] 124.. TABLES [Die kAXlO^ at 25°= 3.4; increases on diln.; (m. p. of anhydride= 187.5°-189.5°); 1909. Second kiX 10*= 2.8; 1911. At 25°, m(32.0) = 240.1, (1031)=444.7, (oo) = 377; 1909. 3,6-DichIoro-o-phthalic acid mono ethyl ester. CloH804Cl2=Cl2.C6H2(C02H)(C02Et). IsaXIO^ at 25° is about 1.5. Ai(514.5) = 335.6, (1030) = 354.3, (oo) = 374; 1909. sj/m.-Dichloro-fso-propyl alcohol see Dichloro-hydrin. 3,6-DichloTO-quinonediinalonic acid tetra ethyl ester. C20H22O10CI2. Satd. soln. has minimum cond.; 1188. /um.-2,3-Dichloro-succimc acid. C4H404Cl2=C02H.CHCl.CHCl.C02H. kiX 10^=4; increases on diln.; m. p. 215°. m(32) = 237.2, (64) = 291.1; (00)= [351]; 1254. nia?.-2,3-Dichloro-succinic acid. (aZZo-2,3-Dichloro-succinic acid). C4H4O4CI2. kAXl0^=7; increases on diln.; m. p. 175°. /i(32) = 252.3, (64) = 308.5, (00)= [351]; 1254. 5,6-Dichloro-veratric acid. (3,4-Dimethoxy-5,6-dichloro-benzoic acid). C9H804Cl2=(MeO)2C6H(Cl)2.C02H. [C02H=1.] kiXlO' at 25°=1; diminishes on diln.; m. p. 182°-183°. /i(1354) = 237, (2708) = 258, (oo) = 352; 404. Dicinnamenyl-acetone see Dicinnamenyl-vinyl-ketone. Dicinnanlenyl-cyclopentanone. C23H20O. Comparative strength (colorim.); m. p. 89°; 1663. Dicinnamenyl-dichloro-methane. (Distyryl-dichloro-methane). C17H14CI2. In SO2; m. p. 77°; 1676. Dicinnamenyl-vinyl-ketone. (Dicinnamenyl-acetone). C21H18O. Comparative strength (colorim.); m. p. 142°; 1663. Dicrotonic acid. (j3-Methyl-a-ethylidene-glutaric acid). C8Hi204=C02H.CH2.CHMe.C(:CHMe)C02H. kAXl05=2.81; m. p. 129°. Nasalt, cond. (1024-32) = 11.9; 1398. Dicuminal-acetone. C23H26O. Comparative strength (colorim.) ; 1663. Dicuminal-cyclopentanone. C25H28O. Comparative strength (colorim.) ; 1663. Dicyano-diamide. C2H4N4=NH:C(NH2).NH(CN). Very weak acid. H ion concentration of 2% soln. =10-^. 0.3% soln., xxl0«=2.4; 332. Dicyanogen see Cyanogen. I>ie] TABLES 125 3,4-Diethoxy-benzoic acid. (Diethyl-protocatechuic acid. Proto* catechuic acid 3,4-diethyl ether). CiiHi404=(EtO)2C6H3.C02H. [C02H=1.] kAXlO^at 25°=3.38. A(1024) = 59.3, (oo) = 350; 1371. Diethyl-acetic acid. C6H]202=CHEt2.C02H. kAXlO^ at 25°=2.03; b. p. 190°; 180, 1840; = 1.89; 601. A(76) = 13.5, (1216) = 50.5, (oo) = 352; 1840. Na.A at 25°, A(32) = 63.7, (1024) = 73.4; 601. Diethyl-amine. C4HnN=Et2NH. ks XIO^ at 25°= 1.26 aq.; about 16% too high. A(32) = 37.1, (256) = 86.6, (oo) = 203; 271. In NHa, qual.; 606. Cond. with ethyl sulphamide; 1576. B.HCl at 25°, A(32) = 92.0, (1024) = 103.7; 270. In HBr, good cond.; 1645. In SO2; 1855. In NH3; 610. In Et ale; 1884. Diethylamino-acetic acid. (Diethyl-glycine). C6Hi302N=NEt2.CH2.C02H. Cu.2A at 25°, A(32) = 0.15, (64)=0.28; 1087. Diethyl-amino-azobenzene. C16H19N3. Cond. in HCl of compound not wholly pure; 1984. 2,5-Diethyl-l-amino-l,3,4-triazDle. (Diethyl-isodihydro-tetrazine). C6HwN4. kBXlOio [at 25°] = 1.68 (solub.); m. p. 167°; 428. Diethyl-aniline. CioHiBN=C6H5.NEt2. kfi XlO' at 19° is at least 1 (colorim.); 1777. In HBr, good cond.; in H2S, poor cond.; 1897. In NH3, qual.; 606. B.HCl at 25°, A(64) = 87.9, (256)=93.8; 270. 6,5-Diethyl-barbituric acid. (Veronal.) C8H12O3N2. kiXlO^ at 25°=3.7; m. p. 187°. iu(64) = 0.6; 1996. In pyridine, almost no cond. ; 754. Diethyl-benzyl amine. CuHi7N=PhCH2.NEt2. kfiXlO^at 25°=3.6. m(137.7) = 13.1, (550.8) = 24.7, (oo) = l92; 664. Diethyl-m-chloroaniline. CioHi4NCl= Cl.C6H4.NEt2. kB XlQi" at 25° is less than 2.4 (colorim. and solub.); 660, 957. Diethyl-iso-dihydro-tetrazine see Diethyl-amino-triazole. Diethylene diamine. (Piperazine) . C4HioN2=NH(C2H4)2NH. kB XlO* at 25°=6.7 aq.; about 16% too high; diminishes on diln. A(32) = 9.1, (256) = 23.9, (a)) = 202; 271. B.2HC1 at 25°, A(32) = 116.0, (1024) = 145.2; 270. 126 TABLES [Die |3-DiethyI-ethylenelactic acid. C7Hi403=Et2C(OH).CH2.C02H. kAXlO^ at 25° = 3; m. p. 38°-39°. m(35.1) = 11.1, (1123.8) = 59.7, (oo) = 350; 1704. a-sym.-Diethyl-glutaric acid. C9Hi604=CH2(CHEt.C02H)2. kAXlO^ at 25° = 5.3; m. p. 118°-119°; 61, 1418. iu(128) = 27.7, (1024) = 74.8, (oo) = 351; 61. /3-sj/m.-Diethyl-glutaric acid. C9H16O4. kAXlQS at 25° = 5.9; m. p. 76°-78°; 61, 175, 1418. m(128) = 29.3, (1024) = 77.5, (00) = 351; 61. Diethyl-malonic acid. C7Hi204=Et2C(C02H)2. kAXl03atl8°=8.5 (colorim.); 1563. At 25°=7.4; m. p. 120°- 121°; 1838. Second kAXl0'=1.8 (inversion); 1638. At 25°, /i(32) = 135.7, (1024) = 312, (oo) = 354; 1838. Diethyl-malonic acid mono ethyl ester. C9Hi604=Et2C(C02H) (C02Et). kAXlO^ at 25°=2.31; diminishes on diln. ju(36.5) = 30.9, (1168.0) = 140.0, (co) = 351; 1859. Diethyl-pentanetetracarboxylic acid. Cl3H20O8=(CO2H)2CEt.(CH2)3.CEt(CO2H)2. kiXlO^at 25°=2.1. m(11.3) = 120.4, (1446.0) = 511.0, (co) = 350; 1859. Diethyl phosphoric acid see Phosphoric acid diethyl ester. 2,6-Diethyl-pimeUc acid. CiiH2o04=CH2(CH2.CHEt.C02H)2. kiXlO'^ at 25°=3.45; m. p. 96°-97°; 1412, 1859. Ai(155.0) = 24.6, (310.0) = 34.5, (oo) = 350; 1859. Diethyl-protocatechuic acid see 3,4-Diethoxy-benzoic acid. Diethyl selenium thetine. C6Hi403Se=OH.SeEt2.CH2.C02H. kBXl0i"=3 (hydrol.); 350 and 1150. Ai(32) = 7.2, (256) = 11.9. B.Br, /x(32) = 96, (1024) = 105; M(32) = 106.5; 350. /um.-sj/m.-Diethyl-succinic acid, (para- acid). C8Hi404=C02H.CHEt.CHEt.C02H. kiXlO* at 25°=2.35; m. p. 192°; 280, 196, 200, 1371, 1838, 2018. m(65.9)=41.2, (1054) = 136.6, (o=) = 351; 280. 7na/.-sym.-Diethyl-succinic acid, (anti- acid. Diethylene-succinic acid). C8H14O4. kAXlO* at 25°=3.47; m. p. 130°; 280, 196, 200, 1371, 1838, 2018. /i(93.7) = 58.0, (1499) = 177.2, (c=.) = 351; 280. Diethyl-succinic acid. (Bischoff's). kAXlO* at 25°=3.8; diminishes on diln.; impure?; m. p. 137.5°; 198, 1838. Dig] TABLES 127 m(32) = 36.9, (1024) = 160, (co) = 351; 1838. 2Na.A at 25°, m(32) = 73.1, (1024) = 90.6; 1838. Diethyl sulphide. (Ethyl sulphide). C4HioS=Et2S. Cond. with EtI in Me, Et and benzyl ale; 334. With Hglj in acetone; 1379. Diethyl sulphite see Sulphurous acid diethyl ester, asym. -Diethyl sulphite see Ethyl sulphonic acid ethyl ester. Diethyl thetine. C6Hi403S=OH.SEt2.CH2.C02H. kBXl0i'=5 (hydrol.); 350 and 1150. m(32) = 2.5, (256) = 3.1. B.Br. - B.Cl, m(32) = 93, (1024) = 103; M(32) = 268.4; 350, Diethyl-m-toluidine. CiiHi7N= Me.C6H4.NEt2. ke X108 at 25° is over 2.3 (solub.); 660, 957. Diethyl-triazole. CeHnNs. kBXlO"=5 (sapon.); m. p. 66°; 428. Diethyl-urea. C5H12ON2. B.HCl at 25°, A(50) = 362.3; 1864. Diferri-pentaacetyl hydroxide. CioHi60iiFe2=Fe2(C2H302)6.0H. At 25°, A(32) = 9.3, (1024) = 82.2; 1528. Difluoro-acetic acid. C2H202F2=CHF2.C02H. kiXlO^ at 25°=5.7; b. p. 134.2° (cor.) @ 766 mm. A(32) = 283.7, (1024) = 394.5, (co) = 395. Na.A at 25°, A(32) = 85.7, (64) = 89, (ra) = 99; 1696. Difluoro-ethyl alcohol. C2H40F2=C2H3F2.0H. 0.5 normal soln. [at 25°], A=0.02; b. p. 95.5°-96°; 1695. Difluoro-ethyl amine. C2H5NF2=CHF2.CH2.NH2. keXlO'^ [at 25°] = 3.3; b. p. 67.5°-67.8° (cor.) @ 757 mm. A(32)=0.8, (128) = 1.6, (c») = 245.2. B.HCl [at 25°], A(32.3) = 105.5, (1034.2) = 123.5; 1697. Difluoro-ethylnitroamine. C2H402N2F2= CHF2.CH2.NH(N02). kAXlO* [at 25°] = 1.36; b. p. 111°-112° @ 12 mm. A(33.2) = 8.0, (1061.1) =44.3, (oo) = 382.6. Na.A [at 25°], A(33.2) = 77.2, (1061.1) = 88.6; 1697. Diftiral see Difurfural. Difurfural-acetone. C13H10O3. Comparative strength (colorim.); 1663. l,3-Difurfural-cyclo-2-pentanone. C15H12O3. Comparative strength (colorim.); m. p. 163°; 1663. a-Digallic acid. Ci4Hio09=(OH)3.C6H2.C02.C6H2(OH)2.C02H. kiXlO^ at 25° = 1.2; sinters 120°, dec. 150°. ;u(32) = 6.8, (128) = 13, (co) = 350; 1825. Digitaline. [A mixture?] InNHs, qual.; 606. 128 TABLES [Dig Digitalis. (Foxglove). [The references to this are incomplete. ] Cond. of soln. of powdered drug; 146. Diglycolamic acid. C4H704N = NH(CH2.C02H)2. kAXlO^=2; increases on diln. m(32) = 59.5, (1024) = 265, (c°) = 354; 1673. Qual.; 1669. Hg.A, e. m. f.; 963. DiglycoUic acid. C4H605=0(CH2.C02H)2. kiXlO^ at 25°=1.1; 1370. Second kiX 105= 3.7 (cond.); 1911. At 25°, m(64) = 82.0, (1024) = 239.6, (a=) = 356; 1370. 2]^a.A ^t 25°, A(32) = 81.0, (1024) = 99.0; 270. Dihydro- see also Hydro- Dihydro-camphoric acid. CioHi804=C8Hi6(C02H)2. kAXl05=4.15; m. p. 106°; 413. Dihydro-collidinedicarboxylic acid diethyl ester. C14H21O4N. InNHs, qual.; 606. AajS-Dihydro-muconic acid, (stabile acid). C6H804= CO2H. (CH2)2.CH :CH.C02H. kAXlO^ at 25°=2.20; diminishes on diln.; m. p. 169°-170°; 1638, 1543. Second kxX 10^=7.9 (inversion); 1638. At 25°, m(66.7) = 40.4, (1077) = 103.0, ()=354; 1638. A|37-Dihydro-mucomc acid, (labile acid). C6H804=C02H.CH2.CH:CH.CH2.C02H. kiXlO* at 25°=1.02; m. p. 195°; 1638, 1543. Second kAX 10^= 5.3 (inversion); 1638. At 25°, m(64) = 27.4, (1024) = 96.0, (co) = 354; 1638. A^-Dihydro-a-naphthoic acid, (a or labile acid). CiiHxo02 = CioIl9.C02H. kiXlO^ at 25°= 1.14; m. p. 91°; 175, 71. A(80.2) = 31.9, (1282.7) = 112.1, (co) = 360; 175. A'-Dihydro-a-naphthoic acid. (0 or stabile acid). C11H10O2. kAXl0= at 25°= 8.0; m. p. 125°; 175, 71. A(335.1) = 53, (1340.4) = 99.1, (co) = 350; 175. A'-Dihydro-iS-naphthoic acid. (A^ ot labile a,cid) . C11H10O2. kAXlO^ at 25°=5.15; increases on diln.; m. p. 104°; 70, 71. A(226.7) = 35.8, (906.8) = 69.1, (co) = 352; 70. A^-Dihydro-(3-naphthoic acid. (A^ or stabile acid). CuHio02. kAXlO^ at 25°=2.9; increases on diln.; m. p. 161°; 70, 71. A(t795) = 72.2, (3590) = 97.3, (oo) = 352; 70. Ai.3-Dihydro-o-phthaUc acid. C8H804=C6H6(C02H)2. [C02H=1, 2.] kAXlO* at 25°=7.98; diminishes on diln. /i(32) = 55.6, (1024) = 199.3, (oo) = 377; (the anhydride has m. p. 58°); 1. Dih] TABLES 129 A^'^-Dihydro-o-phthalic acid. C8H8O4. kAXlO* [at 25°] = 1.55; m. p. 179°-180°; 72. A2.5-Dihydro-o-phthaUc acid. C8H8O4. kAXlO* at 25°= 5.5; diminishes on diln. m(32) = 46.9, (1024) = 187.6; (co) = 377; (the anhydride has m. p. 73°-74°); 3. A2.«-Dihydro-o-phthaUc acid. C8Hs04. kxXW at 25° = 1.7; m. p. 215°; 72, 1638. Second kAXlO^=1.2 (inversion); 1638. At 25°, ^(64) = 33.4, (1024) = 116.9, (co) = 353; 1638. ) = 377. Na.A at 25°, A(32) = 68.7, (1024) = 81.4; 1588. Dihydro-tetrazine see Amino-triazole. Dihydroxy- see also Dioxy- 1,2-Dihydroxy-anthraquinone see Alizarin. 4,4'-Dihydroxy-azobenzene see p-Azophenol. 2,4-Diliydroxy-benzaldehyde. (Resorcyl aldehyde). C7H603=(OH)2.C6H3.CHO. [CH0=1; 0H=2, 4.] kAXlO^ at 25°=3.57; m. p. 134°-135.° Ai(128) = 7.5, (1024) = 21.0, (oo) = 355; 643. 2,5-Dihydroxy-benzaldehyde. (Gentisic aldehyde). CyHeOs. kiXlO^ at 25°=4.2; m. p. 99°. /i(128) = 25.4, (1024) = 66.4, (oo) = 355; 643. 3,4-Dihydroxy-benzaldehyde. (Protocatechuic aldehyde). CrHeOa. kAXlO^at 25°=3.1; 643; = 0.0028; 1397c. m(256) = 32.4, (1024) = 58.2, (00) = 355; 643. m(32) = 0.4, (128) = 0.8, (00) = 379; 1397c. - 1718. [While the values of k and H in 643 are probably too high, the values in 1397c seem to be entirely too low. ] Cond. with NaOH in aq. and Et ale. ; 1718. o-Dihydroxy-benzene see Pyrocatechol. m-Dihydroxy-benzene see Resorcinol. p-Dihydroxy-benzene see Hydroquinone. 2,3-Dihydroxy-benzoic acid. (3-Hydroxy-salicylic acid. m-Oxy- salicylic acid. Pyrocatechin-o-carboxylic acid). C7H604=(OH)2.C6H3.C02H. [C02H=1; 0H=2, 3.] kAXlO' at 25°=1.14; 1368, 1371. /i(64) = 84.1, (1024) = 230.0, (00) = 356; 1371. 2,4-Diliydroxy-benzoic acid. (/3-Resorcylic acid, o-acid of Ostwald). C7H604. 130 TABLES [Dih kAXlO^ at 25° = 5; m. p. 188° to 206°; 1186, 1371, 1684;=8.8 (neutral.); 1718. Ai(64) = 58.6, (1024) = 181.7, (oo) = 356; 1371. In Et ale; 1185, 1718, 1970. Cond. with boric acid; 1185, 1186. With NaOH; 1508, 1718. 2,5-Dihydroxy-benzoic acid. (Gentisic acid. 5-Hydroxy-salicylic acid) . C7H6O4. kAXlO^ at 18°= 1.2 (colorim.); 1563. At 25°= 1.08; increases on diln.; 1371. At 25°, m(64) = 80.5, (1024) = 227.1, (co) = 356; 1371. 2,6-Dihydroxy-benzoic acid. (/3-Resorcylic acid of Ostwald). C7H6O4. kAXl02at25°=5. m(64) = 285, (1024) = 347, (oo) = 356; 1371.-1508, 1718. Cond. with NaOH; m. p. 150° dec; 1508, 1718. 3,4-Dihydroxy-benzoic acid. (Protocatechuic acid). C7H6O4. kAXlO^ at 18°=4.1 (colorim.); 1563. At 25°=3.3; increases on diln.; m. p. 199°; 1186, 1371. At 25°, m(32) = 10.7, (64) = 15.1, (1024) = 59.3, (oo) = 356; 1371. - 1718. In Et ale; 1185. Cond. with boric acid; 1185; qual.; 1184. With NaOH; 1508, 1718. 3,6-Dihydroxy-benzoic acid. C7H6O4. kAXlO^at 25°= 9.1. m(32) = 18.7, (64) = 26.1, (1024) = 94.5, (00) = 356; 1371. Di(hydroxybenzyl) hypophosphoric acid. Ci4Hi604P= (Ph.CH0H)2P0.0H. Relative cond. ; (the aniline salt has m. p. 190° dec.) ; 1771. Dihydroxy-carbostyril see Trihydroxy-quinoline. 2,4-Dihydroxy-cinnamic acid see Umbellic acid. 3,4-Dihydroxy-cinnamic acid see Caffeic acid. Dihydroxy-dibromo-benzoquinone see Bromoanilic acid. 3,4-Dihydroxy-2,5-dicliloro-benzoic acid. (Dichloro-protocatechuic acid). C7H404Cl2=(0H)2.C6HCl2.C02H. [C02H=1; OH=3,4; Cl=2, 5.] kAXlO' at 25° is about 1.^; increases on diln. M32) = 46.5, (64) = 70.7, (1024) = 229.1, (oo) = 355; m. p. 220°; 404. 3,4-Dihydroxy-2,5-dichloro-benzoic acid methyl ester. C8H6O4CI2. [C02Me=l.] kAXl0« at 25°=4.4; m. p. 105°. Ai(256) = 11.9, (1024) = 23.5, (co) = 352; 404. Dim] TABLES 131 3,4-Dihydroxy-5,6-dichloro-benzoic acid. C7H4O4CI2. [C02H=1.] kAXlO^ at 25° is about 1.2; increases on diln. m(64) = 70.6, (1024) = 223.5, (oo) = 355; m. p. 239°; 404. 3,4-Dihydroxy-5,6-dichloro-benzoic acid methyl ester. C8H6O4CI2. [COaMe^L] Too insol. in aq. to measure; m. p. 223°-225°; 404. a-Dihydroxy-dihydro-campholenic acid. CloHl804=C9Hl6(OH)2.C02H. kAXlO^ at 18°=2.5; increases on diln.; m. p. 144°-145°. m(59) = 11.8, (1185) = 50.4, (oo) = 317; 1899. Dihydroxy-dimethyl- see Dimethyl-dihydroxy- Dihydroxy-fumaric acid. (/3-acid). C4H406=C02H.C(OH) :C(0H).C02H. kAXltf" at 25.2° is about 7.2 aq. Cond. increases rapidly on standing, therefore the values are not accurate. m(64) = 306, (00) = 356; 1629. Dihydroxy-hydroshikimi.c acid, (inactive). C7H12O7. kiXlO^ at 19°=7.2; m. p. 156° dec. m(20) = 36.6, (320) = 121.7, (oo) = 323.8; 641. Dihydroxy-maleic acid. C4H406=C02H.C(OH):C(OH).C02H. kAXlO^ at 25° is about 7.2 aq. Cond. increases rapidly on standing; but the values are more accurate than for dihy- droxy-fumaric acid. iu(64) = 298.4, (128) = 325, (oo) = 356; 1629. 1,7-Dihydroxy-naphthalene. CioHgOa. Cond. with NaOH; m. p. 178°; 1017. Dihydroxy-picolinic acid see Comenamic acid. Dihydroxy-quinonedicarboxyUc acid diethyl ester. CisHi^Os. In pyridine; 754. Dihydroxy-tartaric acid. C4H608=C02H.C(OH)2.C(OH)2.C02H. kA XlO^ at 25° is about 1.24 aq. ; diminishes on diln., because of changing to tartronic acid and CO2. At(32) = 162, (1024) = 322, (00) = 354; 1629. 3,5-Dihydroxy-toluene see Orcinol. Dihydroxy-triazolidine- see Methyl-dihydroxy-triazole etc. Diketopiperazine see Aminoacetic acid anhydride. 2,5-Diketo-tetrahydro-thiazole. (Carbamine thioglycoUic acid anhy- dride. Dioxy-thiazole. Mustard oil acetic acid). C3H3O2NS. kAXl0'at0°=0.71. Atl8°=1.5. At 25°= 1.8; 949;= 2.4; 1370. At 25°, m(16) = 0.7, (32) = 1.0, (co) = 360; 1370. - 949. In Et ale; 782. NH4.A; 949. 3,4-Diniethoxy-benzoic acid see Veratric acid. 132 TABLES [Dim 2,2'-Dimethoxy-dibenzal acetone. (o,o'-Diamsal-acetone). C19H18O3. Comparative strength (colorim.); m. p. 125°; 74. 3,3'-Dimethoxy-dibenzal acetone. (m,m'-Dianisal-acetone). C19H18O3. Comparative strength (colorim.); m. p. 52°-54°; 74. 4,4'-Dimethoxy-dibenzal acetone. (p,p'-Dianisal-acetone). CigHiaOa. Comparative strength (colorim.); m. p. 130°; 74, 1663. l,3-Dimethoxy-dibenzal-cyclo-2-pentanone. (Dianisal-cyclopenta- none). C21H20O3. Comparative strength (colorim.); m. p. 212°; 1663. 3,4-Dimethoxy-5,6-dichloro-benzoic acid see 5,6-Dichloro-veratric acid. Dimethoxy-norhemipinic acid see Hemipinic acid. Dimethoxy-noropianic acid see Opianic acid. 3,6-Diniethoxy-phenylxanthonium carboxylic acid methyl ester. C23H2o06-(MeO)2Ci9HioO(C02Me).OH. At 0, A(200) = 82;=68 after 1 minute, = 15.6 after 20 minutes; 956a, 1292a. B.Cl (=C23Hi906Cl) at 18°, A(64) = 148.7, (1024) = 170.0; 956a. 3,4-Dimethoxy-o-phthalic acid see Hemipinic acid. Dimethyl-acetamide see Acetic acid amide. aa '-Dimethyl- /3-acetoxy-glutaric acid. (Dimethyl-hydroxy-glutaric acid acetyl derivative). C9Hi406=MeC02.CH(CHMe.C02H)2. liAXlO^ at 25° = 2; m. p. 120°-121°; 1475, 1704. m(33.4) = 27.2, (1068.8) = 126.6, («>) = 348; 1704. i8-Dimethyl-acryUc acid. CBH802=Me2C:CH.C02H. kiXlO* [at25°] = 2; m. p. 70°; 1411. a-si/m.-Dimethyl-adipic acid. (fum.). C8Hi404=C02H.CHMe.CH2.CH2.CHMe.C02H. kAXlO^ at 25°=4.2; m. p. 140°-141°; 2016, 2018, 2021. Second kAXlO«= 1.7 (inversion); 1638. At 25°, Ai(56.1) = 16.6, (448.6) = 44.9, (00) = 351; 2018. ^-sym.-Dimethyl-adipic acid. (mo/.). C8H14O4. kiXlOS at 25°=4.2; m. p. 74°-76°; 2016, 2018, 2021. Second kiX 10^=1. 7 (inversion); 1638. At 25°, m(24.8) = 11.1, (396.8) = 42.7, (oo) = 351; 2018. ' Dimethyl-alloxan. C6H6O4N2. At 25°, A(32) = 7.5, (1024) = 16.1, (00)= [356]; 1748. Dimethyl-amine. C2H7N = Me2NH. kBXl0*at0°=3.71. At5.5°=4.18. At 10°= 5.01. At20°=5.10. At 25°=5.35; 776;=5 (neutral.); 299a;=7.4 aq.; about 16% Dim] TABLES 133 too high; 271. At 30°= 5.36. At 35°= 5.45. At 40°= 5.67. At 45°=5.67. At 50°=5.63; 776. At 25°, A(32) = 31.0, (256) = 75.4, (oo) = 217; 271.- 299a. Cond. with HCl; 299a. With NaCl; 177. Complex with suc- cinimide; 1750, 1755. B.HCl at 25°, A(32) = 106.3, (1024) = 117.5; 270. In SO2; 1842, 1855. In NH4OE; 650. In CHCI3; 740. Dimethyl-aminoacetic acid. (Dimethyl-glycocoU). C4H902N=NMe2.CH2.C02H. kAXlQi" at 25°=1.4 (catal.);=2000 (cond.). ksXlQi^ at 25°= 1.06 (catal.); m. p. 157°-160°; 890. Dimethyl-aminoazobenzene. CuHisNs^ Ph.N2.C6H4.NMe2. ■ kiXlO" at 18°-19°=1.45 (colorim.); 1562. p-Dimethyl-aminoazobenzene-o-carboxylic acid. (Methyl Red). Cl6Hl602N3= Me2N.C6H4.N2.C6H4.CO2H. kxXW at 18°= 1.05 (colorim.). keXlO" at 18° = 3 (colorim.); 1729a. p-Dimethyl-aminoazobenzene sulphonic acid. (Sodium salt=Heli- anthine, Methyl Orange, Orange III or Tropaeolin). Cl4Hi503N3S=Me2N.C6H4.N2.C6lj4.S03H. kAXlO* at 18°-19°=4.6 (colorim.); 1562. At 25° is about 0.3; 1984. = 4.3 (colorim.); 1729a. ksXlO" at 25°, is less than 1 (colorim.); 1729a. At 25°, A(g70) = 52.0, (1940) = 62.4, (co) = 349; 1984. Cond. with HCl and with bases; 1984. Na.A at 25°, A(256) = 68.5, (1024) = 70.4; 1984, 1770. With inorg. acids; 1770, 1984. With NaOH; 1984. In MeNHj, fair cond.; 637. - K.A; 1984. [See 1705, 1705a, 1782, con- cerning accuracy of colorimetric methods.] o-Dimethyl-aminobenzoic acid. (Dimethyl-anthranilic acid). C9Hii02N= Me2N.C6H4.CO2H. kAXl09at25°=2.3 (catal.). ksXlQi' at 25°= 2.8 (catal.); m. p. 70°. At 25°, A(8) = 0.06. Na.A at 25°, A(32) = 67.4, (1024) = 80.8; 414. o-Dimethyl-aminobenzoic acid methj^l ester. CioHi302N= Me2N.C6H4.C02Me. ksXlO" at 25°=6.1 (catal.); (B.HCl has m. p. 145°-147°); 414. m-Dimethyl-aminobenzoic acid. C9Hii02N=Me2N.C6H4.C02H. kAXlO^ at 25°=8 (catal.). = 5.5 (cond.). ksXlO" at 25°= 1.9 (catal.). At 25°, A(128) = 8.6, (1024) = 27.0, (00) = 375; 414. m-Dimethyl-aminobenzoic acid methyl ester. C10H13O2N. ks XlO" at 25°=7.3 (catal.); (B,HC1 has m. p. 175°-177°); 414. 134 TABLES [Dim p-Dimethyl-aminobenzoic acid. C9Hii02N=Me2N.C6H4.C02H. kAXlO« at 25°=9.4 (solub.);=8.6 (cond.). ks XlQi^ at 25°=3.25 (solub.); m. p. 235°-236°. A(2260)=49.0. Na.A at 25°, A(32) = 67.0, (1024) = 79.0; 890. p-Dimethyl-aminobenzoic acid methyl ester. C10H13O2N. ksXlQi^ at 25°=3.34 (solub.); m. p. 102°; 890. m-Dimethyl-aminophenol. (m-Hydroxy-dimethyl-aniline) . C8HiiON=Me2N.C6H4.0H. In Et ale, alone and with NaOH; m. p. 85°; 1508. 2,5-Dimethyl-l-amino-l,3,4-triazole. (Dimethyl-isodihydrotetra- zine). C4H8N4. keXlOi" [at 25°] = 1.4 (solub.); m. p. 199°; 428. ao-Dimethyl-a'-iso-amylsuccinic acid. CiiH2o04=C02H.CMe2.CH(C5Hii).C02H. kAXlO^ at 25° = 6.16; diminishes on diln.; m. p. 143°-144°. m(121.2) = 83.4, (969.6) = 184.2, (co)=[351]; 236. Dimethyl-aniline. C8HiiN=C6H5.NMe2. ksXlOi" at 18°=2.42 (colorim.); 1777. In HBr, HCl and HI, good cond.; in H2S, poor cond.; 1897. In SO2; 1842. In NH3, qual.; 606. In benzene, no cond. ; 1802. Cond. with acetic acid; 1011, 1388. With picric acid; 1802. With aUyl thiocarbimide, no cond.; 1223. As solvent; 1552a. B.HCl at 25°, A(64) = 93.6, (256) = 98.3; 270, 1864.- B.H2SO4; 1864. Dimethyl-aniline-4-sulphonic acid. C8Hii03NS=Me2N.C6H4.S03H. [NMe2=l.] kAXlO^at 25°=3.75. A(32) = 36.6, (512) = 124.2, («=) = 353; 492. Dimethyl-anthranilic acid see o-Dimethyl-aminobenzoic acid. Dimethyl-arsinic acid see CacodyUc acid. 5,5-Dimethyl-barbituric acid. C6II8O3N2. kAXlO'at25°=7.3. m(64) = 0.9; 1996. 2,4-Dimethyl-benzoic acid. (l,3-Dimethyl-4-benzoic acid. m-Xylic acid). C9Hio02=Me2.C6H3.C02H. [C02H=1; Me=2, 4.] kAXlO^ at 25°= 9; diminishes on diln. A(1024) = 91.9, (2048) = 119.5, (od) = 352; 1418. 2,5-Dimethyl-benzoic acid. (l,4-Dimethyl-2-benzoic acid. p-Xylic acid). C9H10O2. [C02H=1; Me=2, 5.] kAXlO^ at 25°=1.2; increases on diln. A(512) = 75.6, (1024) = 102.7, (00) = 352; 1418. Dim] TABLES 135 3,5-Diniethyl-benzoic acid. (l,3-Dimethyl-5-benzoic acid. Mesi- tylenic acid). C9H10O2. [C02H=1; Me=3, 5.] kAXlO^ at 25°=4.8; 175. = 7.3; 1418. [These, apparently, are measurements of different acids. ] A(835.6) = 65.4, (1671.2) = 87.0, (oo) = 354; 175. A(2048) = 112.3, (<=°) = 352; 1418. Dimethyl-benzyl amine. C9Hi3N=PhCH2.NMe2. keXlO^ at 25°= 1.05. A(36.1) = 3.7, (578.2) = 15.2, (oo) = l96; 664. Dimethyl-benzylsuccinic acid. Ci3Hi604=C02H.CMe2.CH(PhCH2).C02H. kiXlO^ at 25°=4.55; m. p. 139°; 189, 1838. = 0.59; m. p. 128°- 130°; methylbenzylglutaric acid?; 201. m(64) = 55.0, (512) = 133.1, («>) = 350; 1838. a S-Dimethyl-butane-aiS 5-tricarboxylic acid. C9Hi406=C02H.C'HMe.CH(C02H).CH2.CHMe.C02H. kAXlO* at 25°= 1.6; increases on diln.; m. p. 107°. ju(83.5) = 39.1, (668.2) = 100.4; 813. Dimethyl-j3-iso-butylethylenelactic acid. C9Hi803=iso-Bu.CH(OH).CMe2.C02H. kAXlO^ at 25°=1.47; m. p. 81°; 1034, 1704. At 25°, m(35.6) = 7.9, (570.2) = 30.2, (co) = 349; 1704. ao-Dimethyl-a '-fso-butylsuccinic acid. CioHis04=C02H.CMe2.CH(wo-Bu).C02H. kiXlO* at 25°=4.32; m. p. 143°-144°. m(273.0) = 101.4, (1092.0) = 171.5; 236. Dimethyl-comnalic acid see Jso-Dehydroacetic acid. Dimethyl-cyanuric acid see Cyanuric acid dimethyl ester. l,3-Dimethyl-cyclohexane-3-carboxylic acid. C9H16O2. kAXlO^ [at 25°] = 6.30. A(282.1) = 14.5, (1128.4) = 28.4, (c») = 352; 2026. cjs-l,3-Dimethyl-cyclohexane-5-carboxylic acid. C9H16O2. kAXlO' [at 25°]= 1.07; m. p. 65°-65.5°. A(225.1) = 17.5, (900.4) = 34.4, (oo) = 352; 2026. frons-l,3-Dimethyl-cyclohexane-5-carboxylic acid. C9H16O2. kAXlO^ [at 25°] = 1.09; m. p. 67°-67.5°. A(312.2) = 19.5, (1249.2) = 39.3, (oo) = 352; 2026. l,2-Dimethyl-cyclopropane-l,2-dicarboxylic acid. (1,2-Dimethyl- trimethylene-l,2-dicarboxylic acid). C7H10O4. kAXlO^ at 25°=9.90; m. p. 149°-150.5°. m(26.4) = 17.5, (211.4) = 48.6, (co) = 380; 814. 1,3-Dimethyl-desoxyxanthine see l,3-Dimethyl-2-oxy-l,6-dihydro- purine. 136 TABLES [Dim Dimethyl diethyl ammonium hydroxide. C6Hi70N=Me2Et2N.OH. B.Cl at 25°, A(32) = 93.8, (1024) = 105.9; 270. Dimethyl-dihydro-resorcinol. C8Hi202= CsHnOCOH). kAXlO« at 25°=7.1 aq.; m. p. 130°-148°. A(64) = 7.8, (1024) = 30.8, (oo) = 374; 1588. In pyridine; 754. Dimethyl-iso-dihydro-tetrazine see Dimethyl-amlno-triazole. a-Dimethyl-dihydroxy-adipic acid. C8Hi4O6=C02H.MeC(OH).CH2.CH2.(OH)CMe.C02H. kAXlO^=3.17; m. p. 212°; 2025. 7-Dimethyl-dihydroxy-adipic acid. CsHuOe. kAXlO^=3.30; m. p. 19r-192°; 2025. Dimethyl-dihydroxy-glutaric acid. C7Hi206=CH2(MeC.OH.C02H)2. kiXlC at 25°=1.8; diminishes on diln.; m. p. 103°-104°. /^(36.2) = 80.0. (1159.7) = 256.6, (oo) = 353; 2018. Dimethyl-dihydroxy-glutaric lactone. CjHioOs. kAXlC at 25° is about 5.5; diminishes on diln. from change of lactone to acid. m(41.1) = 134.7, (1315.5) = 306.0; 2018. Dimethyl-dimethylamino-methyl carbinol benzoate. (Methyl sto- vaine derivative). Ci3Hi902N=PhCO.O.CMe2.CH2.NMe2. keXlO^at 15°=3.22 (hydrol.); 1779, 1777. l,3-Dimethyl-2,6-dioxy-purine. (1,3-Dimethyl-xanthine. Theophyl- line). C7H8O2N4. kAXlO' at 25°= 1.62 (sapon.). kaXlO" at 25°=1.9 (sapon.). At 40.1°=5.5 (sapon.); 1997. l,7-Dimethyl-2,6-dioxy-purine. (1,7-Dimethyl-xanthine. Paraxan- thine). C7H-802N4. kAXlC at 25°=2.22 (sapon.). ksXlO" at 40.1°=3.29 (solub.); 1997. 3,7-Dimethyl-2,6-dioxy-purine. (3,7-Dimethyl-xanthine. Theobro- mine). C7H8O2N4. kAXlO* at 18°= 1.3 aq.; 1391. At 25°=0.011 (sapon.); 1997. ksXlO" at 18°=1.5 (hydrol.); 1391; (colorim.); 1775. At 40.1° = 4.6 (solub.); 1997.= 16 (catal.); 1995. At 18°, m(601.3) = 1.0, (1202.6) = 1.4, (oo) = 335. At 25°, ^(601.3) = 1.7, (1202.6) = 2.2, (00)= [372]; 1391. — 1241. In HON, no cond.; 943. In NH3, qual.; 606. Cond. with NaOH and HCl; 1391. jS-Dimethyl-ethenyl-tricarboxylic acid. C7Hio06=C02H.CHMe.CMe(C02H)2. kAXlC at 25° = 5; diminishes, then increases on diln.; m. p. 156°-158°. m(32) = 115.5, (1024) = 322, (oo) = 352; 1839. Dim] TABLES 137 Dimethyl-ethenyl-tricarboxylic acid see iso-Butenyltricarboxylic acid. Dimethyl-ethylacetic acid. C6HM02=CMe2Et.C02H. kAXlO^at 25°=9.57. A(32) = 6.1, (1024) = 33.8, (oo) = 352; 180. Dimethyl-ethyl carbinol. C6Hi20 = CMe2Et.OH. , Cond. with oxalic acid; 45. Dimethyl-ethyl-ethylenelactic acid. C7Hu03=Et.CH(OH).CMe2.C02H. kiXlO^ at 25°= 1.50; m. p. 103°; 1704, 1706. m(30.2) = 7.4, (987.4) =40.0, (co) = 350; 1704. Dimethyl-ethylphenyl ammonium hydroxide. CioHi70N=(Me2)(Et)(Ph)N.OH. B.Cl at 25°, A(32) = 88.4, (1024) = 100.8; 270. Dimethyl-ethylsuccinic acid. C8Hi404=C02H.CMe2.CHEt.C02H. kiXlO* at 25° = 5.6; m. p. 139°-140°; 189, 198, 236, 1264, 1838. [Two. acids, one of m. p. 62°, kx 10^=5.7, the other of m. p. 105°, kxl0^=5.9, given in 201, apparently are methyl- ethyl glutaric acids.] m(32)=43.7, (1024) = 183.4, (oo) = 351; 1838. Dimethyl-fumaranilic acid. (Dimethyl-maleinanilic acid). Ci2Hi303N=NH(Ph).CO.CMe:CMe.C02H. NH4.A, A(28.3) = 120.0, (906.9) = 187.7; m. p. 67°-70°; (the acid has m. p. 59°-64°); 1749. 2,4-Dimethyl-furfurane-3-carboxylic acid. CvHgOa. kAX 10^ at 25°= 1.1; m. p. 122°. A(512) = 25.5, (1024) = 36.0, (co) = 356; 559. aa'-Dimethyl-glutaconic acid. C7Hio04=C02H.CHMe.CH:CMe.C02H. kAX 10* at 25°=1.29; diminishes on diln.; m. p. 146°-147°. /i(32.5) = 22.2, (1040) = 102.5, (oo) = 353; 1704. /um.-sj/m.-Dimethyl-glutaric acid, (a a-acid) . C7Hi204=CH2(CHMe.C02H)2. kAXlO^ at 25°=5.9; m. p. 140°-141°; 69, 60, 63, 1473, 1704. Second kAXlO«= 1.5 (inversion); 1638. At 25°, Ai(207.6) = 36.3, (1660.8) = 94.4, (oo) = 351; 1704. mo?. -sj/m.-Dimethyl-glutaric acid, (p-acid. m-acid). C7H12O4. kiXlO^ at 25°=5.5; increases on diln.; m. p. 127°-128°; 60, 175, 232, 1473, 1704, 1838, 2018. Second kAXlO«= 1.6 (inversion); 1638. At 25°, m(293) = 10.9, (1172) = 76.6, (oo)=351; 1704. (8|8-Dimethyl-glutaric acid. , C7Hi204=C02H.CH2.CMe2.CH2.C02H. kAXlO^at 25°=2.3; 1418. = 0.17; 61. m(64) = 39.9, (oo) = 352; m. p. 100°-101°; 1418; - ;u(64) = 11.3; 61. [The values of ix given in 61 give k=0.17, not 2.2. 138 TABLES [Dim Note that the melting-point and the value of k correspond to a methylethyl-succinic acid. ] si/m.-Dimethyl-glutaric acid, (aa-acid, |3-acid and m-acid). C7H12O4. kAXlO' at 25°= 5.0-5.5; in some measurements increases, in others diminishes, on diln.; m. p. 99°-101°, 102°-104°, 105°-106°; 65, 70, 175, 201, 1838, 2018. [This acid was a mixture of isomers. ] Dimethyl-glycocoll see Dimethyl-aminoacetic acid. Dimethyl-glyoxiine. C4H8O2N2. In complex compounds; 1751, 1753, 1754, 1756, 1757, 1759, 1760a, 1761. Dimethyl-hexylethylenelactic acid see Dimethyl-hydroxy-pelargonic acid. Dimethyl-hydroresorcylic acid methyl ester. CioHi404=OH.C8HioO.C02Me. kiXlO^at 25°=4.9 aq. A(28) = 13.4, (896) = 69.9, (00) = 372; 1588. aa'-Dimethyl-j3-hydroxy-glutaric acid. C7Hi206=OH.CH(CHMe.C02H)2. kiX 10^ at 25°= 1.2; m. p. 136°-137; 1473, 1475, 1704. Ai(74:.6) = 29.9, (1194.2) = 104.9, (oo) = 350; 1704. oa'-Dimethyl-(3-hydroxy-glutaric acid acetyl derivative see Dimethyl- acetoxy-glutaric acid. a-Dimethyl-|S-hydroxy-pelargonic acid. (Dimethyl-hexylethylene- lactic acid). CiiH2203=C6Hi3.CH(OH).CMe2.C02H. kA X 10^ at 25°= 1.9; diminishes on diln. /i(124.4) = 16.7, (1990.4) = 54.2, (oo) = 350; 1704. o-Dimethyl-laevulinic acid. (Mesitonic acid). C7H]203= Me.CO.CH2.CMe2.CO2H. kiX 10^ [at 25°]= 1.08; m. p. 74°-77°; 202. Dimethyl-maleic acid. (Pyrocinchonic acid). C6H804=C02H.CMe:CMe.C02H. kAX 10* at 25° is over 1.08; from cond. of soln. of the anhydride (m. p. 96°) which apparently polymerizes, giving too low cond.; 191, 1838. At 25°, m(64) = 28.3, (1024) = 101.2, (oo) = 354; 1838. Dimethyl-maleic acid anhydride. CeHeOs. Cond. of aq. soln.; 1838. Dimethyl-maleinanilic acid see Dimethyl-fiunaranilic acid. Dimethyl-malonic acid. (/3-iso-Pyrotartaric acid). C6H804=Me2C(C02H)2. kAXlO* at 18°=7.6 (colorim.); 1563. At 25°=7.6; m. p. 185°; 1838, 1371. Dim] TABLES 139 Second liAX 10'= 3 (inversion); 1336,1638. At 25°, m(32) = 51.3, (1024) = 204.4, (o=) = 356; 1838. Dimethyl-malonic acid mono ethyl ester. C7Hi204= MeaCCCOzH) (COaEt). kxX 10* at 25°=3.12; diminishes, then increases on diln. m(44.0) = 38.9, (1408.0) = 167.5, (co) = 352; 1859. DimethyI-2-naphthylamine-8-sulphonic acid. Ci2H,303NS= Me2N.C10H6.SO3H. kA X 10* is about 2 (colorim.); m. p. 244°; 1773. Dimethyl-nitrobarbituric acid. C6H706N3=CO(NMe.CO)2C:N02H. At 24.5°, A(32) = 313.3, (1024) = 337.6, («.) = 352; pure acid is dec. at 152°, slightly impure is dec. at 132°; 845. l,3-Dimethyl-2-oxy-l,6-dihydro-purine. (Desoxytheophylline. 1,3- Dimethyl-desoxyxanthine) . C7H10ON4. kiXlQi^ at 25°= 5.61 (sapon.); m. p. 215°-225° (in vac); 1707. Dimethyl-parabanic acid. C6H6O3N2. At 25°, A(32) = 0.33, (128) = 0.49; 1748. 2, 6-Dimethyl-pentane-2, 6-tetracarboxylic acid. CiiHi608=(C02H)2CMe.(CH2)3.CMe(C02H)2. kA X 10' at 25°=3.7; increases on diln. m(17.2) = 77.6, (275.0) = 240.5, (oo) = 350; 1859. Dimethyl-phenonaphthoxazine see Meldola Blue. 2,3-Dimethyl-phenyl-2,5-benzyliminopyrazole see 2,5-Benzylimino- pjrrine. Dimethyl-p-phenylene diamine. C8Hi2N2=Me2N.C6H4.NH2. At 25°, A(13) is over 0.19; 741. Dimethyl-phenyl-ethylenelactic acid see Phenylhydroxy-pivalic acid. Dimethyl-phenyl-hydroxy-propionic acid see Phenylhydroxy-pivalic acid. 2,3-Dimethyl-l-phenyl pyrazolone. ( Antipyrine) . C11H12ON2. In aq., little or no cond.; 977, 1256. 0.1 normal soln. cond.= 9.02x10-8; 214. B.HI at 18°, A(20)l=222, (1000) = 377; 1256. 3,4-Dimethyl-l-phenyl pyrazolone. C11H12ON2. In molten state, conducts fairly well. Cond. in aq. equals that of a 1% NaCl soln.; 977. 2,6-Dimethyl-4-phenylpyridine-3,5-dicarboxylic acid see Phenylluti- dine-dicarboxylic acid. Dimethyl-pimelic acid. C9H16O4. kAXlO^ at 25°=3.4; at 25°, m(128) = 22.1, (1024) = 59.4, (») = 350; the acid, m. p. 71°-73° and 74°-76°, of 1412, 1859, 2018, is made up of the following two isomers. 140 TABLES [Dim anft-aa'-Dimethyl-pimeUc acid. C9Hi604=CH2(CH2.CHMe.C02H)2. kAXlO^ [probably at 25°] = 3.43; m. p. 76°-76.5°; 965. />ara-aa'-Diinethyl-pimelic acid. C9H16O4. kAXlO^ [probably at 25°]=3.44; m. p. 81°-81.5°; 965. Dimethyl-a-propionyl thetine. C6Hi203S=OH.SMe2.CHMe.C02H. kB X 10" at 25°=2.1 (hydrol.); 350 and 1150. At 25°, m(32)=4.1, (256) = 6.9. B.Br.- B.Cl, Ai(32) = 93, (1024) = 103; M(32) = 275.6; 350. Dimethyl-/3-propioiiyl thetine. C6Hi203S=OH.SMe2.CH2.CH2.C02H. ks X 10" at 25°= 1.2 (hydrol.); 350 and 1150. B.Br, m(32) = 95, (1024) = 105; M(32) = 123.8; 350. a-DimethyI-|8-iso-propyl-ethylenelactic acid. C8Hi603= Me2CH.CH(OH).CMe2C02H. kiX 10= at 25°=2.2; increases on diln.; m. p. 92°. m(34.8) = 9.5, (1119.7) = 51.2, (cx.) = 350; 1704. Dimethyl-propylsuccinic acid. C9Hi604=C02H.CMe2.CHPr.C02H. kAXlO^ at 25°=6.0; m. p. 145°; 236. = 5.5; m. p. 140°-141.5°; 189, 1838. The acids, m. p. 101° and 51°, k=5xlO-5, in 201 are, apparently, Methylpropyl glutaric acids. At 25°, m(108.5) = 78.7, (868.0) = 176.5; 236. m(64) = 59.8, (1024) = 183, (oo) = 350; 1838. aa-Dimetliyl-a'-iso-propylsuccinic acid. C9H16O4. kAX 10* at 25°= 1.58; diminishes on diln. m(66.1) = 35.7, (528.8) = 85.1, (°°)=[351]; m. p. l-il°-142°; 236. N-3-Dimethyl pyrazole. C6H8N2. kfiXlOii [probably at 25°] = 1.3 (solub.); b. p. 148°; 428. 3,5-Diniethyl pjrrazole. C6H8N2. ksX 1010 [probably at 25°] = 2.5 (solub.); m. p. 107°; 428. 2,6-Dimethyl-pyridine. (2,6- or aa-Lutidine). C7H9N=Me2.C5H3N. kBXl0'at25°=l. m(32) = 0.4, (256) = 1.2; 1293. In SO2; 1842. B.HCl at 25°, A(50) = 92.2. - B.H2SO4; 1864. - B.MeCl; 270. Dimethyl-pyridine. C7H9N. B.HCl at 25°, A(64) = 95.5, (256) = 102.5; 270. 2,6-Dimethyl-pyridine-3,5-dicarboxylic acid. (aa'-acid. Lutidine- dicarboxylic acid). C9H904N=Me2.C6NH(C02H)2. kA X 10' at 25°=3.7; increases on diln. m(128) = 168.5, (1024) = 288.5, (00) = 352; 1372. 2,4-Dimethyl-pyridine-3,5-dicarboxylic acid. (a7-acid). C9H9O4N. kA X 10' at 25° =5.5; diminishes on diln. m(128) = 197, (1024) = 296, (") = 352; 1372. 2,6-Dimetliyl-pyrone. C7H8O2. kA X 1015 at 25°=8 (hydrol.). Dim] TABLES 141 kfiXlOi^ at 0°=3 (hydrol.); 1827; = 0.3 (corrected); 1150. At 25°=2 (hydrol.) 1827;=0.8 (corrected); 1150. At 40.2°= 6.5 (catal.); 1995. Cond. at 25°, m(32) = 0.10, (512) = 0.36, (oo) = 202; 1827. In HBr and HCl; 1233a. In H2SO4; 750, 167a. In AsCls; 1842. In SO2; 1827, 1842. In acetonitrile; 1827. In EtBr; 1435. In hydrazine hydrate; 1828. Cond. with HCl and H2SO4; 741. With NaOH; 1827. With tribromo-acetic acid; 1436, 1827. With trichloro-acetic acid; 1435. With picric acid; 1827. With potassium tri- chloro-acetate; 1439. Na.A; 1827. - B.HCl at 25°, A(32) = 369; 738, 401. - B.H2SO4; 741. - B.Oxalate; 401. Dimethyl-pyrone carboxylic acid. C8II8O4. kAX 10*=3.85; m. p. 98.5°-99°. m(43.2)=43.2, (346.0) = 104.2; 557. 2,4-Dimethyl-pyrrole-3-carboxylic acid. (m-Dimethyl-/3-acid). CrHgOaN. ki X 10' at 25°=7.5 aq.; m. p. 186°. Ai(228.8)=4.6, (915.2) = 9.3, (oo) = 356; 23. 2,4-Dimethyl-pyrrole-5-carboxylic acid. (m-Dimethyl-a-acid). C7H9O2N. kAX 10^ at 25°=2.15 aq.; diminishes on diln.; m. p. 137°. m(790) = 14.3, (1580) = 17.0, (oo) = 356; 23. 2,5-Dimethyl-pyrrole-3-carboxylic acid. (p-Dimethyl-j3-acid). C7H9O2N. kAXl08at25°=l.laq.; m. p. 213°. m(307.5) = 6.6, (1230.0) = 13, (oo) = 356; 23. 2,4-Dimethyl-pyrrole-3,5-dicarboxylic acid, (m-acid). C8H9O4N. kxX 10^ at 25°=2.13 aq.; diminishes on diln.; m. p. 260° dec. At(1320) = 54.2, (2640) = 73, (co) = 355; 23. 2,5-Dimethyl-pyrrole-3,4-dicarboxylic acid, (p-acid). C8H9O4N. At 25°, ;u(1316) = 323.6, (oo) = 356; m. p. 251°; 23. sj/m.-anft-Dimethyl-succinic acid, (ds- or maleinoid). C6Hio04=C02H.CHMe.CHMe.C02H. kxXlO^ at 25°=1.38; diminishes on diln.; m. p. 120°-121°; 280. = 1.23; 200, 234, 1838, 2018. Second kAX 10^=5.3 (inversion); 1638. At 25°, Ai(56.6) = 30.0, (904.8) = 104.4, (co) = 354; 280. sj/m.-anii-Dimethyl-succinic acid mono methyl ester. C7H]2O4=C02H.CHMe.CHMe.CO2Me. kAX 10^ at 25°=4.5; m. p. 38°. /*(22) = 11.1, (175.8)=29.8, (oo) = 352; 244. 142 TABLES [Dim sym.-p-Dimethyl-succinic acid, (trans- or fumaroid). C6Hio04= CO2H.HCMe.MeCH.CO2H. kAXlO* at 25°=2.08; diminishes on diln.; m. p. 193°; 280. = 1.91; 1838, 175, 200, 234, 1418, 2018. Second kAX 10'= 1.3 (inversion); 1638. At 25°, Ai(100)=47.7, (800) = 117.5, (oo) = 354; 280. In Me ale; 2029. sym.-p-Diinethyl-succinic acid mono methyl ester. C7H12O4. kA X 10^ at 25°= 6; increases on diln. /i(34.5) = 15.5, (275.8)=42.8, (oo)=352; m. p. 49°; 244. asi^m. -Dimethyl-succinic acid. C6Hio04=C02H.CMe2.CH2.C02H. kAXlO^ at 25°=8.0; increases, then diminishes on diln.; m. p. 140°; 61, 176, 201, 234, 1418, 1838. m(32) = 17.3, (512) = 63.5, (oo)=353; 1838. asym.-Dimethyl-succinic acid a-mono methyl ester. C7Hi204=C02H.CMe2.CH2.C02.Me. kAX 10^ at 25°=2.28; increases on diln.; m. p. 52°. /.i(25.2) = 8.3, (201.4)=23.2, (oo) = 352; 244. flSJ/m.-Dimethyl-succinic acid /3-mono methyl ester. C7Hl204= CO2Me.CMe2.CH2.CO2H. kA X 10^ at 25°= 2.56; increases on diln.; m. p. 40.5°. m(27.6) = 9.1, (220.8) = 25.8, (oo) = 352; 244. Dimethyl sulphide. (Methyl sulphide). C2H6S=Me2S. XX 10^ at 25° is less than 1; b. p. 35°-36.5°; 1843, 1844. As solvent; (1844). B.HNO3, A(32) = 391. - B.Br2; 760. Dimethyl thetine. C4Hio03S=OH.SMe2.CH2.C02H. ks X 10^^ at 25°= 1.9 (hydro!.); 350 and 1150. At 25°, A(32) = 2.2, (256) = 2.1. B.Cl, A(32) = 103, (1024) = 115; M(32) = 277.7. - B.Br; 350. Dimethyl thetine ethyl ester. C6Hi403S=OH.SMe2.CH2.C02Et. At 25°, A(32) = 2.7, (256) = 3.1, (512) = 7.4. B.Br, A(32) = 91.6, (1024) = 103.9; 350. Dimethyl-thiazole. CsHjNS. B.HCl at 25°, A(50) = 121.4. - B.H2SO4; 1864. 2,4-Dimethyl-thiazole-5-carboxylic acid. (meso-Methylthiazole-o- methyl-/3-carboxylic acid). C6H7O2NS. kAX 10* at 25°= 1.25; increases on diln. A(263.2) = 55.7, (1052.8) = 106.4, (°o)=357; 175. Dimethyl-o-toluidine. C9Hi3N=Me.C6H4.NMe2. [Me=l; NMe2=2.] kBXlO' at 15°=3.08 (colorim.); 1777. B.Picrate in benzene, no cond.; 1802. Dimethyl-m-tolmdine. C9H13N. kB X 109 at 25°=2.4 (solub.); 660, 957. Din] TABLES 14.3 Dimethyl-p-toluidine. C9H13N. ksXlO^ at 15°=6.36 (colorim.); 1777. Dimethyl-triazole. C4H7N3. ksXlO" [probably at 25°] = 6.2 (sapon.); m. p. 142°; 428. aa-Dimethyl-tricarballylic acid. C8Hi206=C02H.CMe2.CH(C02H).CH2.C02H. kA X 10* at 25° =3.2; diminisiies on diln. m(23.7) = 29.2, (189.4) = 75.1, (co)=[351]; m. p. 143°; 237. aa-Dimethyl-tricarballylic acid a?-mono methyl ester. C9Hi406=C02H.CMe2.CH(C02H).CH2.C02Me. kAX 10* at 25°= 1.8; diminishes on diln. m(31.2) = 25.3, (249.6) = 65.9, (co)=[351]; 237. oa-Dimethyl-tricarballylic acid ?-mono methyl ester. CgHuOe. kA X 10^ at 25°= 8.6; diminishes on diln. m(35.8) = 18.9, (71.6) = 26.3, (co)=[35l]; 237. aa '-Dimethyl-tricarballylic acid. C8Hi206=MeCH(C02H).CH.C02H.CHMe(C02H). a) acid, (ay-acid.) kAXlO* at 25°=4.45; m. p. 206°-207°; 237, 2017. m(33.7) = 40.2, (269.7) = 101.7, (co)=[351]; 237. b) acid, (ay-acid). kAX 10* at 25°= 5.4; m. p. 174°; 237, 2017. m(20.7) = 35.0, (165.6) = 90.6, (00)= [351]; 237. c) acid, (ay-acid). kAXlO*at25°=5.72; diminishes on diln. ; m. p. 143°; 237. = 5.1; m. p. 148°-149°; 2017. m(21.8) = 37, (174.2) = 94.3, (oo)=[351]; 237. Dimethyl-trimethylene-dicarboxylic acid see Dimethyl-cyclopropane- dicarboxylic acid. a-Dimethyl-uracU. C6H8O2N2. [Me=2, 3.] kAXlO" at 25°=8.8 (catal.); m. p. 220°-230°; 1996. j8-Dimethyl-uracil. C6H8O2N2. [Me=3, 6.] kAXlO" at 25°=7.4 (catal.); m. p. 258°; 1996. Dimethyl-violuric acid. C6H704N3=CO(NMe.CO)2C:NOH. kAXl05at25°=1.57. M(32) = 7.9, (512) = 29.9, (co)=352; 1188. In pyridine; 754. K.A at 25°, A(40) = 82.5, (1280) = 96.3; 1188. Dinicotinic acid see Pyridine-3,5-dicarboxylic acid. 2,4-Dimtro-aniUne. C6H604N3=(N02)2.C6H3.NH2. [NH2=1.] In NH3; 604; qual.; 610. In MeNH2, good cond.; 637. o-Dinitro-benzene. C6H404N2= (N02)2C6H4. In NH3; 604. lU TABLES [Din tn-Dinitro-benzene. C6H4O4N2. In HBr, good cond.; in H2S, no cond.; 1897. In NH3; 604, 607. In MeNH2, good cond.; 637. In pyridine, no cond. [m- Dinitro-benzene-?]; 764. p-Dinitro-benzene. C6H4O4N2. In NH3; 604. 2,3-Dinitro-benzoic acid. C7H406N2=(N02)2.C6H3.C02H. [C02H=1; N02=2, 3.] kAXlO^' at 25°= 1.44. At 40°= 1.38; diminishes on diln.; m. p. 201° and 204.1°. At 25°, A(100) = 256, (1600) = 348, (oo)=377. In Et ale; 1627. 2,4-Dimtro-benzoic acid. C7H4O6N2. kiXlO^ at 25°=3.85. At 40°=3.2; diminishes on diln.; m. p. 180.9°. At 25°, A(100) = 310.5, (1600) = 360.5, (cd) = 377. In Et ale; 1627. 2,5-Dinitro-benzoic acid. C7H4O6N2. ki XlO^ at 25°=2.64. At 40°=2.16; diminishes on diln.; m. p. 177°. At 25°, A(100) = 291.5, (1600) = 360.5, (a>) = 377. InEtalc; 1627. 2,6-Dimtro-benzoic acid. C7H4O6N2. kAXlO^ at 25°=8.15. At 40°=7.57; m. p. 202° and 206°. At 25°, A(100) = 339.5, (1600) = 369, (co) = 377. InEtalc; 1627. 3,4-Dinitro-benzoic acid. C7H4O6N2. kiXlO' at 25°=1.63. At 40°= 1.71; diminishes on diln.; m. p. 163.3°. At 25°, A(100) = 124.5, (1600) = 284.5, (co) = 377. In Et ale. ; 1627. 3,5-Dimtro-benzoic acid. C7H4O6N2. kAXlO' at 18°= 1.6 (colorim.); 1563. At 25°= 1.63; diminishes on diln.; 175, 1627. At 40°= 1.77; diminishes on dihi.; 1627. At 25°, A(200) = 162.5, (1600) = 292.5, (00) = 377. InEtalc; 1627. l,3-Dimtro-4-bromobenzene. C6H304N2Br= (N02)2C6H3.Br. In NH3; 604. Dinitro-bromomethane. CH04N2Br= Br.CH(N02)2. kiXlO^at 0°=1.7; 796. Cond. at 0° and 25°; 780. K.A at 0°, A(64) = 58.3, (256) = 59.8; 796. Dinitro-butane. C4H804N2= C4H8(N02)2. K.A at 25°, A(32) = 94.6, (1024) = 104.5; 796. Din] TABLES 145 jS^-Dinitro-caproic acid. C6Hio06N2=Me2.C(C02H).C(N02)2Me. ? kxXlO^ at 25°= 6.9; diminishes on diln. m(128) = 90.8, (1024) = 195.2, (oo) = 350; 1370. Dinitro-ethane. C2H404N2= Me.CH(N02)2. kAXlO«atO°=2.3; 796. At25°=5.8; 1092. A weak acid; 780, 795. At 25°, A(32.5) = 5.3, (130) = 10.2, (co) = 388; 1092. K.A at 25°, A(32) = 101.7, (512) = 111.0. With HCl; 796, 1092. Dinitro-ethane alcoholate. (Dinitro-ethane ethyl ester acid). C4Hio06N2=MeCH(N02).NO(OH)(OEt). kAXlO^at 25°=1.7. A(128) = 49.6, (1024) = 122.1, (oo) = 356.4. K.A at 25°, A(32) = 86.4, (1024) = 101.3; 772. 2,6-Dinitro-hydroquinone. (2,6-Dinitro-l,4-dihydroxy-benzene). C6H406N2= (N02)2C6H2(OH)2. kAXl0^at25°=7.1. Ai(200) = 40.1, (1600) = 105.3, (co) = 353; 70. Dinitro-methane. CH204N2= (N02)2CH2. kiXlO* at 0°=1.4. At 25°=2.8; diminishes on diln.; 780, 796. At 25°, A(64)=46.8, (512) = 110.6, (oo) = 369; 780. Qual.; 795. K.A at 0°, A(64) = 61.9, (256) = 64.9; 796. 2,4-Dinitro-l-naphthol-7-sulphonic acid. CioH608N2S=CioH4(N02)20H.S03H. [2K.A or 2Na.A is the dye Naphthol Yellow S.] At 18°, m(100)=416, (1600 = 600; 976a. At 25°, A(100)=245, (800) = 332.9; 1402. At 90°, m(100) = 753.9, (800) = 1019.2; 976a. Ca.A; 976a.- Mg.A. - 2Na.A at 25°, A(100) = 96.4, (1600) = 110.1; 1402, 1401. With Methylene Blue, qual.; 1401. Dinitro-oxybenzo furazane. C6H2O6N4. A(64) = 341.7, (512) = 361; m. p. 138° with dec; 1425. 2,3-Dinitro-phenol. (e-Dinitro-phenol) . C6H405N2=(N02)2C6H3.0H. [0H=1; N02=2, 3.] kAXl05at25°=1.3; 70,847. M(256) = 19.9, (1024) = 40.0, (oo) = 354; 847. 2,4-Dinitro-phenol. (a-Dinitro-) . C6H4O6N2. kAXlO* at 25°=1; m. p. 113°; 847; 70, 1362. Ai(256) = 51.7, (1024) = 99.9, (oo) = 354; 847. In NH3, qual.; 606. In pyridine. In piperidine; 754. In Et ale; 1508, 1718. Cond. with NaOH; 1508. 1718. 2,5-Dinitrol-phenol. (7-Dinitro-) . C6H4O6N2. kAXlO«at 25''=7.0; 70,847. ^(256) = 14.4, (1024) = 29.9, (00) = 354; 847. 146 TABLES Pin 2,6-Dinitro-phenol. ((3-Dinitro-). C6H4O6N2. kiXlO^ at 25°=2.7; m. p. 64°; 847. = 1.7; 70. m(256) = 78.5, (1024) = 145.1, (co) = 354; 847. 3,4-Dinitro-phenol. (S-Dinitro-). C6H4O6N2. kAXlO^ at 25°=4.3; m. p. 134°; 847, 70. m(256) = 11.4, (1024) = 22.6, (00) = 354; 847. 3,5-Dimtro-phenol. (e-Dinitro-). C6H4O6N2. kAX 10^ at 25°=2.1; m. p. 124°. m(100) = 1.6, (400) = 3.2, (co) = 354; 847. 2,6-Dmitro-plienoI-4-sulphomcacid. C6H4O8N2S. [S03H=4.] K.A, cond. alone and with NaOH; 1718. Dinitro-propane. C3H6O4N2. K.A at 25°, A(64) = 101.3, (512) = 107.5; 796. Di-iso-nitroso-butyric acid see Dioximino-butyric acid. l,2-Diiiitroso-3,5-dinitro-benzene. C6H206N4= (NO)2C6H2(N02)2. kAXl0*=l.l; m. p. 172°. /x(2000) = 142, (4000) = 172, (oo) = 384. K.A, m(128) = 96, (1024) = 109.5; 1425. 2,4-Diiiitro-toluene. C7H6O4N2. In NHs, qual.; 606. Dinitro-toluene mtroic acid see Trinitro-toluene. 3,5-Dinitro-2,4,6-tribromo-plienol. C6H06N2Br3= (N02)2C6Br3.0H. K.A, yeUow salt, at 25°, A(32) = 112.7, (1024) = 125.0. The orange and red salts were also measured. There is little difference between them and the yellow salt; 744. syn-Dioximino-butyric acid. (Di-iso-nitroso-butyric acid. Methyl- synglyoxime carboxylic acid). C4H604N2=MeC(N.OH).(OH.N)C.C02H. kAXlO^ at 25°= 1.4; increases on diln. m(32) = 172.1, (256) = 308.7, (ro) = 358; 768. am/>7ii-Dioximino-butyric acid. (Di-iso-nitroso-butyric acid. Methyl- amphiglyoxime carboxylic acid). C4H604N2=MeC(N.OH).C(N.OH).C02H. kAXlO^ at 25°= 2; [an extrapolated value.] Na.A, m(1024-32) = 10; 768. Dioximino-propionic acid. Labile. {amphi-Glyoxime carboxylic acid). C3H404N2=HC(OH.N).(OH.N)C.C02H. kAXlO^ at 25°=4.17; m. p. 140°-141°. At(32) = 109.2, (512) = 264.9, (c») = 358; 768. Dioximino-propionic acid. Stabile. (amfi-Glyoxime carboxylic acid). C3H404N2=HC(OH.N).(N.OH)C.C02H. kAXlO' at 25°=2.85; diminishes on diln.; m. p. 171°. M(32) = 93.1, (512) = 242.2, (a>) = 358; 768. I»ip] TABLES 14T aa-Dioximino-succinic acid. (anfo'-Glyoxime dicarboxylic acid). C4Hi06N2=C02H.C(OH.N).(N.OH)C.C02H. kiXlO^ at 25°= 1; increases on diln. m(32) = 167.4, (266) = 293.7, (oo)=358; 768. /3/3-Dioximino-succimc acid. (syn-Glyoxime dicarboxylic acid). C4H406N2=C02H.C(N.OH).(OH.N)C.C02H. kAXl02at25°=6 (?). m(32) = 287.4, (256) = 495. 4, (co)=358; 768. 2,6-Dioxy-purine see Xanthine. Dioxy-thiazole see Diketo-tetrahydro-thiazole. Dipentene. CioHie. Dipentene.2HBr, in SO2; 1829. - Dipentene.2HI, in SO2; 1829, 1842. Diphenic acid. (Diphenyl-dicarboxylic acid). Cl4Hio04= CO2H.C6H4.C6H4.CO2H. kA XlO* at 25° is about 5; inaccurate, because of impurity of aq. used for soln. m(128)=79.2, (1024) = 178.0, (00)= [356]; [in Hg.U.]; 1362. Diphenyl. Ci2Hio=Ph.Ph. In NH3, qual.; 606. In acetonitrile, no cond. ; 936. In MeNH2, no cond.; 637. Diphenyl amine. C]2HuN=Ph2NH. In HBr, good cond.; in H2S, no cond.; 1897. In HON, very small cond.; 943. In H2SO4; 750. In SO2; 1842. In acetonitrile and in benzonitrile, no cond.; 936. Diphenyl-p-anisyl carbinol. C20H18O2. Comparative strength (colorim.); m. p. 58°-61°; 74. l,2-Diphenyl-3-benzyl-hydroxy-aniidine. (Phenylbenzyl - etc.). C2oHi80N2=PhC(:NPh).N(C7H7).OH. B.HCl at 25°, M(128) = 116.6, (512) = 148.0; A(128)=85; m. p. 194°; (the base has m. p. 150°); 1083. Diphenyl-bromomethane. CisHnBr. In SO2; 669. Diphenyl-crotonic acid. (j3-Benzylcinnamic acid). Ci6Hi402=PhCH2.PhC: CH.CO2H. kA XlO^ at 25°=8; diminishes on diln. A(512) = 68.2, (1024) = 89.8, (oo) = 371; m. p. ISC-lSl"; 667, 1058. Diphenyl-cyclobutadiene-dicarboxylic acid see Phenylnaphthalene- dicarboxylic acid. Diphenyl-dicarboxylic acid see Diphenic acid. Diphenyl-dichloro-methane. (Benzophenone chloride). Cl3HloCl2= Ph2CCl2. In SO2; b. p. 186° @ 26 mm; 669, 1676. 148 TABLES [Dip NjN'-Diphenyl-endanilodihydro triazole. (Nitron). C20H16N4. B.Benzyl chloride. - B.Mel at 25°, A(272)=85; m. p. 213°; 314. Diphenylene-glycollic acid. (9-Fluorenol-9-earboxylic acid). C14H10O3 = C13H8 (OH) (CO2H) . kiXlO' [at25°] = 1.0. Ai(128.5) = 104.8, (1028) = 217.5, (co)=[356]; 1134. Diphenyl-glutaric acid, (sym.-acid). Ci7Hi604=CH2(CHPh.C02H)2. kiXlO* at 25°= 1.48; m. p. 164°. Ai(319.6) = 67.3, (1278.4) = 120.5, (oo) = 345; 2018. Diphenyl-glycollic acid see Benzilic acid. Diphenyl iodonitim hydroxide. Ci2HiiOI=Ph2l.OH. At 25°, A(32) = 186.2, (128) = 191.2. B.Cl at 25°, A(32) = 81.9, (1024) = 92.9; 1687. In NH3;604. -B.I in NH3, qual.; 606. - B.NO3; 1687. Diphenyl-ketoxime see Benzophenone oxime. sym.-Diphenyl-succinic acid, (a- or anti-acid). Ci6Hu04=C02H.CHPh.CHPh.C02H. liAXlO* at 25°=2.6; increases on diln.; m. p. 183° and 220°. m(92)=49.6, (736) = 127.1, (oo) = 350; 1838. |8-(^ara)Diphenyl-succinic acid. ()3-Bibenzyldicarboxylic acid). C16H14O4. kAXlO*at 25°=2; extrapolated; m. p. 229°. A((2250) = 177.3, (4500) = 220.8, (oo) = 350; 1838. Diphenyl-thio urea see Thiocarbanilide. Diphenyl-tolylamidine see Phenyl-tolylbenzenylamidine. l,2-Diphenyl-3-p-tolyl-hydroxy-amidine. C2oHi80N2=PliC(:NPli).N(OH).C6H4Me. B.HCl'at25°, A(512) = 144.5, (1024) = 171.5; m. p. 186°; 1093. (37-Diplienyl-vinylacetic acid. Ci6Hi402=PhCH:CPli.CH2.C02H. kxXlO^ at 25°=5.6; diminishes on diln.; m. p. 172°-173°. A(512) = 152.4, (1024) = 181.6, (oo) = 371; 567, 1058. Dipiperonal-acetone. CigHuOs. Comparative strength (colorim.) ; m. p. 87° [^ a typographical error for 187°]; 1663. Dipiperonal-cyclopentanone. C21I116O5. Comparative strength (colorim.); m. p. 252°; 1663. Dipropyl-amine. C6Hi5N=Pr2NH. ks X W at 25°= 1.02 aq.; about 16% too high. A(32) = 33.1, (256)=77.6, (oo) = 197; 271. In NH3, qual.; 606. B.HCl at 25°, A(32) = 86.1, (1024) = 97.9; 270. Di-fso-propyl-amine. CeHisN. In Me ale. at 25°, A(31.8) = 2.3, (254.1) = 12.0; b. p. 84° @ 757 mm. B. Hydrate in Me ale; 335. Dip] TABLES 149 Dipropyl-aniline. Ci2Hi9N=Ph.NPr2. ks X IQi" at 25° is at least 3 (solub.); too insol. to get a constant; 660, 957. Di-fso-propylene-succinic acid. CioHi404=C02H.C(:CMe2).C(:CMe2).C02H. kA X 10*= 1.4; diminishes on diln. m(128)=49.8, (1024) = 111.9, (oo) = 399.3; m. p. 231°; 440. Di-iso-propyl-glycollic acid. (Di-fso-propyl-oxalic acid). C8Hi603=iso-Pr2.C(OH).C02H. kA X 10* at 25°= 1.27; diminishes on diln.; m. p. 111°. M(32.5) = 22.0, (1040) = 106.2, (co) = 350; 1704. Dipropyl-malonic acid. C9Hi604=Pr2C(C02H)2. kAX 10= at 18°=1.2 (colorim.); 1563. At 25°=1.12; diminishes on diln.; m. p. 156°; 1638, 1667. Second kAX 10^= 5 (inversion); 1638. At 25°, Ai(64) = 196.2, (1024) = 320.0, (co) = 350; 1638. Di-iso-propyl-oxalic acid see Di-jso-propyl-glycollic acid. 2,6-Dipropyl-pimeUc acid. Ci3H2404=CH2(CH2.CHPr.C02H)2. kAX 105 at 25°=3.0; m. p. 95°-96°; 1412, 1859. m(1114.0) = 60.5, (2228.0) = 81.9, (co) = 350; 1859. 2,6-Di-iso-propyl-pimelic acid. C13H24O4. kiX 105 at 25°=3.2; m. p. 96°-98°; 1412, 1859. m(237.0) = 29.2, (948.0) = 56.0, (00) = 350; 1859. cis-sym.-Dipropyl-succinic acid. CioHi804=C02H.CHPr.CHPr.C02H. kiX 10* at 25°=4.9; diminishes on diln.; m. p. 119°-121°. m(128) = 77.4, (1024) = 173.5, (co)=[351]; 235. frans-sj/m.-Dipropyl-succinic acid. C10H18O4. kA X 10* at 25°=2.5; diminishes on diln. Ai(256) = 78.8, (1024) = 144.4, (00)= [351]; m. p. 182°-183°; 235. cis-sj^m.-Di-iso-propyl-succinic acid. CioHi804=C02H.CH-tso-Pr.CH-iso-Pr.C02H. kAXlO' at 25°=2.4; diminishes on diln.; m. p. 171°; 235. = at least 3.0; diminishes on diln; m. p. 180°, (varies with manner of heating) ; 61, 1418. Ai(128) = 146.8, (1024) = 262.4, (00)= [351]; 235. cjs-sym.-Di-Jso-propyl-succinic acid mono methyl ester. CiiH2o04=C02H.(CH-iso-Pr)2.C02Me. kA X 10* at 25°= 1.15; increases on diln. m(238) = 52.9, (952) = 98.3, (00)= [350]; 235. frans-sj/m.-Di-iso-propyl-succinic acid. C10H18O4. ' kA X 10* at 25°= 1.08; m. p. 226°. M(256) = 5a7, (1024) = 98.9, (co)=[351]; 235. 150 TABLES [Dip frans-sj/m.-Di-iso-propyl-succinic acid mono methyl ester. C11H20O4. kA X 10* at 25°= 6.4; diminishes on diln. m(380) = 50.4, (1520) = 91.4, (00)= [350]; 235. a7-Di-iso-propyl-tricarballylic acid. Ci2H2o06=C02H.CH-iso-Pr.CH(C02H).CH-iso-Pr.C02H. kA X 10^ at 25°= 1.93; m. p. 173°. M171.5) = 151.6, (1372.0) = 270.7, (oo)=[35l]; 237. a7-Di-iso-propyl-tricarballylic acid. C12H20O6. kA X 10^ at 25°= 1.63; increases on diln.; m. p. 156°. /i(95.9) = 113.7, (767.2) = 230.0, (ao)=[351]; 237. 3,2'-Dipyridyl-3'-carboxyUc acid. CuH802N2=C6H4N.C6H3N.C02H. kAX 10* at 25°= 2; increases on diln. m(64) = 10.2, (1024)=46.8, (oo) = 350; 1372. 3,2'-Dipyridyl-2,3'-dicarboxylic acid. Cl2H804N2=C02H.C5H3N.C5H3N.C02H. kAX lO'* at 25°=3.2; increases, then diminishes on diln. iu(128) = 63.1, (1024) = 150.9, (oo) = 350; 1372. Distyryl-dichloro-methane see Dicimiamenyl-dichloro-methane. Dithio-carbamine glycoUic acid. C3H602NS2=NH2CS.CHSH.C02H. kAXlO* is about 5 (catal., and cond.); unstable in aq.; m. p, 136°-137°. m(32)=46.0, (512) = 142.2, (oo) = 382; 854. Dithio-carbamine glycoUic acid anhydride see Rhodanin. Dithio-carbondiglycollic acid. (Carbonyldi-thioglycoUic acid. Dithi- olcarboxyacetic acid). C5H605S2=(C02H.CHSH)2:CO. kAX 10^ [at 25°] = 1.56; increases on diln. m(32.2) = 75.5, (1085)=301.1, (oo) = 378; m. p. 156°; 853. Dithio-diglycolUc acid see Di-thioglycollic acid. a-Dithio-dilactyUc acid. C6Hio04S2=C02H.CHMe.S2.CHMe.C02H. kAXlO*at25°=9. m(32) = 55.2, (1024) = 216.8, (co) = 356; 1133. /3-Dithio-dilactyUc acid. C6Hio04S2=C02H.(CH2)2.S2.(CH2)2.C02H. kA X 10* at 25°=9; diminishes on diln. m(256) = 52.2, (1024) = 91, (oo) = 356; 1133. Di-thioglycollic acid. (Dithio-digly collie acid). 041160482= CO2H.CH2.S2.CH2.CO2H. kA X 10^ at 25°= 6.8; increases on diln.; 1370. Second kAXl0«= 5.2 (cond.); 1911. At 25°, m(32)=49.3, (1024) = 215.6, (oo)=358; 1370. Dithiolcarboxyacetic acid see Dithio-carbonglycollic acid. norm.-Dodecane-dicarboxylic acid. Ci4H2604=C02H.(CH2)i2.C02H. Too insol. in aq. to measure; m. p. 123°; 279. Eth] TABLES 151 Dulcitol. C6Hi406=C6H8(OH)6. In NH3, qual.; 606. Cond. alone and with boric acid; 1180. Durenecarboxylic acid see 2,3,5,6-Tetrainethyl-benzoic acid. iso-Durenecarboxylic acid see 2,3,4,6-Tetramethyl-benzoic acid. Durylic acid see 2,4,5-Trimethyl-benzoic acid. iso-Durylic acid see 2,4,6-Triniethyl-benzoic acid. £. Ecgonine. C9H15O3N. kfi X 10" at 14° is between 0.2 and 8 (colorim.); 1778. rac. -Ecgoninic acid. C7H11O3N. kA X 10^ at 25°=9.5; increases on diln.; m. p. 93°-94°. A(71.2) = 27.6, (688.9) = 84.6, (a=) = 375; 1978. Edestin. [The references to this are incomplete. ] Concentration of H ions; 1511b. Egg albumin see Albumin. Elder see Sambucus nigra. Emetine. C30H40O6N2. Also given as C30H44O4N2 and C15H22O2N. koX 10^ at 15°= 1.98 (hydroL); 1779. Enteric see Intestinal. Eosin see Tetrabromo-fluorescein. Epichlorohydrin. C3H6OCI. xXl08atO°=3.9. At25°=5.2. Cond. as solvent of salts of amines; 1844, 1851. Erica see Erika. Erika B. A salt of Methylbenzenyl-amino-thio-xylenol-azo-a-naph- thol-disulphonic acid. C26Hl907N3S3K2= Cl6Hl4NS.N2.CloH4(OH) (S03K)2. At 18°, m(400) = 202.0, (1600) = 229.1. At 90°, m(400) = 539.6, (1600) = 590.4. Cond. with KCl; 976a. Erythran phosphoric acid see Phosphoric acid erythran ester. Erythrite see Erythrol. Erythrol. (Erythrite). C4Hio04=C4H6(OH)4. Cond. in aq. soln. is very small; 944, 1181. InNBU, qual.; 606. Cond. with boric acid; 944, 1181. Erythronitrolic acid see Ethylnitrolic acid; salts. Ethenylglycollic acid. (o-Hydroxy-butenoic acid. Vinylglycollic acid). C4H603=CH2:CH.CHOH.C02H. kAXlO*=5; diminishes on diln.; m. p. 33° and 40°; 300, 1633. A(32)=42, (1024) = 169.2, (oo) = 360.6; 1633. Na.A, A(32) = 71.4, (1024) = 83.7; 1633. 152 TABLES [Eth Ethenyl-tricarboxyUc acid. C5H606=C02H.CH2.CH(C02H)2. kAXlO^ at 25°=3.2; m. p. 150°. m(32) = 96.5, (1024) = 290, (oo) = 354; 1839. Ether bromide see Ethyl ether. Ethoxy-acetic acid. (Ethylglycollic acid. Gly collie acid ethyl ether). C4H803=EtO.CH2.C02H. kx X 10^ at 25°=2.34; diminishes on diln.; aq. used for soln. was not pure. A(32) = 29.5, (1024) = 134, (co) = 356; 1370. Na.A at 25°, A(32) = 67.2, (1024) = 78.6; 1367. o-Ethoxy-benzoic acid. (Ethyl-o-hydroxy-benzoic acid). C9Hio03=EtO.C6H4.C02H. kA X 10^ at 25° =7.2; diminishes on diln. A(128) = 32.1, (512) = 60.8, (oo) = 352; 1429. m-Ethoxy-benzoic acid. (Ethyl-m-hydroxy-benzoic acid). C9H10O3. kAX 10* at 25°=9.2; diminishes on diln. A(512) = 68.4, (1024) = 92, (oo) = 352; 1429. p-Ethoxy-benzoic acid. (Ethyl-p-hydroxy-benzoic acid). C9H10O3. kA X 10* at 25°= 5.1; diminishes on diln. A(2048) = 97.0, (oo) = 352; 1429. 2-Ethoxy-5-chlorobenzoic acid. (Chlorosalicylic acid ethyl ether). C9H903Cl=EtO.C6H3(Cl).C02H. ki X 10^ at 25°= 1.33; m. p. 118°. A(893) = 102.7, (1786) = 135, (co)=351; 404. Ethoxy phosphonis chloride. [C2H6OCI2P?]. InHCI, goodcond.; 1897. a-Ethoxy-propionic acid. (Ethyl-lactic acid. Lactic acid ethyl ether). C5Hio03=MeCH(OEt).C02H. K.A. - Na.A at 25°, A(32) = 64.2, (1024) = 75.1; 1367. 3-Ethoxy-p-toluic acid. (Ethyl-m-homo-o-hydroxy-benzoic acid). CioHi203=Me.C6H3(OEt).C02H. [C02H=4; Me=l.] kA X 10* at 25°=3.5; diminishes on diln. A(512)=44.3, (1024) = 60.1, (°°) = 352; m. p. 79.5°; 1429. Ethylacetoacetic acid ethyl ester. C8Hi403=MeCO.CHEt.C02Et. kAX 1015 at 25°=9 (sapon.); 666; is about 0.3 (sapon.); 1594. At 25°, A(256) = 0.07; 1823. a-Ethyl-iS-acetylpropionic acid. (Ethyl-laevulinic acid). C7Hi203= MeCO.CH2.CHEt.CO2H. kA X 10* [probably at 25°]=2.93; b. p. 170°-175° @ 45 mm.; 202. a-Ethyladipic acid. C8Hi404=C02H.(CH2)3.CHEt.C02H. kA X 10* at 24.2°=4.15; m. p. 48°. /t(47.2) = 15.1, (755.2) = 57.6, (oo) = 35l; 1240. Ethyl alcohol. C2H60=Et.OH. xxW at -9°=0.8; 1853a. At 0°=1.487; 1843, 1844, 1419;=2; 920. - 425, 916, 918, 922, 1472, 1590a, 1651, 1766. At 14.6°; Eth] TABLES 153 787. At 15°; 456, 597, 1419, 1421, 1472. At 16°; 1419. At 18°= 1; 491;= 1.53; 647; = 3; 1724; - 362, 366, 391, 478, 783, 956, 986, 1316, 1420, 1421, 1534, 1791, 1800, 1807, 1970. At 19°; 418, 1021. At 20°=1.11; 1766; - 1590a. At 24°; 1010. At 25° is less than 0.2; 1388. = 0.75; 1766.= 1.03; 1844; - 18, 347, 656a, 754, 764, 782, 904, 908, 912, 917, 918, 922, 941, 1423a, 1434a, 1569, 1580, 1592, 1649, 1815, 1843, 1849, 1853a, 1884, 1903a, 1971. [So-called " anhydrous " alcohol carefully prepared has x=2 X 10"^ or less. In 1766 it is stated that it is easy to prepare alcohol of x=2 X 10"^; and that its cond. is less affected by exposure to air than that of aq. See especially 1766, 1843.] At 30°= 1.12; 1766, 1472; - 1420, 1421. At 35°= 1.38; 1766. At 45°=6.7; 1434a; 1472. At 50°=1.85 and 4.5; 1766. At 60°; 1472. At 70°; 1800. T not stated; 263, 580, 816, 1098, 1344, 1556, 1620. Cond. of dil. soln.; 305, 455, 456, 1534, 1582, 1627. In HBr; 29, 30; good cond.; 1897; no cond.; 147a. In HCl, ix; 147a. In HON, no cond.; 943. In HI, n; 147a. In H2S, no cond.; 147a. In Nils, qual.; 606. In CI, no cond.; in CI with HCl, moderate cond. ; 887. Cond. with KOH; 597. With NaOH; 748, 1035, 1724. With inorg. salts; 34, 580, 597, 748, 904, 905, 906, 912, 916, 918, 920, 922, 941, 1388, 1634, 1582, 1592, 1844, 1994. With organic compounds; 45, 263, 816, 922, 1021, 1388, 1421, 1423a, 1434a, 1569, 1620, 1724, 1800, 1807, 1844, 1853a, 1903a. - Qual.; 1311. With very small amounts of aq.; 456, 491, 597, 1766, 1843. Effect of radium on cond.; 2031. Cond. of thin layer; 301. Under pressure; 1509, 1590a. As solvent; 16, 18, 20, (34), 75, 82, (90), 325, (327), 334, 344, (347), 391, 418, 425, 438, 480, 491, 513, 532, (580), 647, 654, 656a, 667, (697), (711), 754, 764, 777, 782, (783), 787, 788, 789, 833, (876), (912), (915), (916), (918), (920), 922, 923, 932, (1015), 1021, 1066, 1071, 1185, (1280), 1298, 1311, 1316, 1321, 1421, 1423a, (1432), 1434a, 1452, 1470, 1508, 1526, 1530, (1534), (1541), 1569, 1579, (1582), 1590a, 1620, 1622, 1627, 1649, (1651), (1653), 1654, (1681), 1718, 1724, 1763, (1766), 1791, (1794), 1797, 1807, 1815, (1818), 1820, 1844, 1853a, 1884, 1886, 1903a, 1904, 1970, 1971, (1994), 2029, (2031). Dielectric constant; 445, 1509. Relative basicity in organic solvents, (colorim.); 1061. Na.A; 344, 1452, 1724, 1815. With menthone; 1763. p-sym.-Ethylallylsuccinic acid. C9Hw04=C02H.CHEt.CH(C3H6).C02H. 154 TABLES [Eth kA X 10^ at 25°=2.69; diminishes on diln.; m. p. 155°-156°; 1838; m. p. 163°-166°; 826. Second kAX 10'= 2.3 (inversion); 1638. At 25°, m(32) = 31, (1024) = 135.8, (oo)=350; 1838. mcso-sj/m.-Ethylallylsuccinic acid. C9H14O4. kAX 10* at 25°=3.59; diminishes on diln.; m. p. 110°-115°; 826, 1838. m(32) = 35.7, (512) = 116.3, (co) = 350; 1838. Ethyl-amine. C2H7N=Et.NH2. X XlO'' at 0° is about 4; 1612. ks XlO* at 25°=5.6 aq.; about 16% too high; 271. At 25°, A(32) = 27.0, (256) = 65.6, (00) = 214; 271. Cond. as solvent of inorg. compounds; 1612. B.HCl at 25°, A(32) = 102.9, (1024) = 114.3; 270. In SO2; 1855. In NH3; 610. - Complex salts; 1750, 1751, 1757. Ethylaminosuccinic acid. C6Hii04N=C02H.CHNH2.CHEt.C02H. kAX 10^=3.47; m. p. 132°. /i(32) = 35.3, (1024) = 153.2, (oo) = 352; 1158. Ethylaniline. C8HiiN=Ph.NHEt. ksXlO^Oat 19°=4.17 (colorim.); 1777. In benzene, alone and with picric acid, no cond. ; 1802. B.HCl at 25°, A(64) = 90.4, (256) = 95.1; 270. Etliylamline-3-sulphomc acid. (Ethyl metanilic acid). C8Hii03NS=EtNH.C6H4.S03H. [EtNH=l; S03H=3.] kAXlO^=1.59; dec. 294°. A(32) = 24.6, (1024) = 116.3, (0°) = 356.5. Na.A, A(32) = 67.8, (1024) = 78.5; 645. Ethylaniline-4-sulplionic acid. (Ethyl sulphanilic acid). C8H11O3NS. kAX 10*= 1.25; dec. 258°. A(32) = 21.7, (1024) = 107.0, («=) = 355.5. Na.A, A(32) = 67.8, (1024) = 76.6; 645. 5-Ethylbarbituric acid. C6H8O3N2. kAXl05at25°=3.83. iu(64) = 18.2; 1996. Ethyl benzene. C8H10. InNH3, qual.; 606. o-Ethylbenzoic acid. C9Hio02=Et.C6H4.C02H. kiXlO* at 25°=1.7. A(256) = 66.5, (a>)=354; 1418. Ethylbenzyl ether. CsRnO. In NH3, qual.; 606. Ethylbenzyhnalonic acid. Ci2Hi404= (PhCHa) (Et) C (C02H)2. kA X 10^ at 25°= 1.46; diminishes on diln. /i(32) = 171.6, (1024) = 332, (oo) = 352; 1838. meso-Ethylbenzylsuccinic acid. Ci3Hi604=C02H.CHEt.CH(C7H7).C02H. Eth] TABLES 155 kAX 10^ at 25°=4.14; increases, then diminishes on diln.; m. p. 122°; 201, 1838. m(32) = 38.0, (512) = 126.9, (oo) = 350; 1838. ^ara-Ethylbenzylsuccinic acid. C13H16O4. tAXlO^ at 25°=2.62; increases, then diminishes on diln.; m. p. 154°; 200, 1838. m(64)=42.4, (1024) = 137.4, (cx)) = 350; 1838. Ethylbenzyl sulphide. (Benzyl mercaptan ethyl ether). 0911120= CTHy.SEt. In SO2; 1842. Ethyl bromide. CaHsBr. K X 10« at 25° is less than 2; b. p. 37.4°-41° @ 732.4 mm.; 1388, 1437. In NH3, qua!.; 606. Compound with AlBrs and AICI3; 1437, 1893. Cond. as solvent of inorg. and organic compounds; 1388, 1435, 1437. a-Ethylbromosuccinic acid. (N acid). C6H904Br= CO2H.CHBr.CHEt.CO2H. kiX 10' at 25° =4.23; diminishes on diln.; m. p. 114°; 1838. Second kAX 10^=3.6; 1911. At 25°, Ai(32) = 109.0, (1024) = 311, (oo) = 355; 1838. ;3-Ethylbromosuccinic acid. (H acid). C6H904Br=C02H.CHBr.CHEt.C02H. kiXlO' at 25°=5.41; increases on diln.; m. p. 192°; 1838. Second kAX 10= =6.4; 1911. At25°, m(32) = 120.1, (1024) = 330, (oo) = 355; 1838. Ethylbrucinium chloride. (Brucine ethochloride). C25H3i04N2Cl=B.EtCL At 25°, A(32) = 75.3, (1024) = 90.7; 270. Ethyl chloride. C2H5CI. K of commercial ethyl chloride; 534. Cond. with HgCl2; 534. With allyl thiocarbimide, no cond.; 1223. Ethylcrotonic acid see a-Methyl-jSy-pentenoic acid. Ethylcyclopentane-carboxylic acid see Ethylpentamethylene-carboxy- lic acid. Ethyl-aA-dithio-carbonglycollic acid. CBH803S2=EtS.CS.CH0H.C02H. kiXlO' at 25°=2.12; m. p. 77°-78°. /i(39.8) = 95.5, (627.2) = 257.8, (oo) = 378; 853. Ethyl-|8A-dithio-carbonglycollic acid. (Ethylsulphothiocarbonglycol- lic acid. Ethylxanthoacetic acid. Ethylxanthogenacetic acid). C5H803S2=EtO.CS.CHSH,C02H. 156 TABLES [Eth kA X 10^ at 25°=6.5 aq.; m. p. 57.5°-58°. m(31.8) = 50.6, (1071) = 210.1, (co) = 378; 852. Ethylene acetic acid see Trimethylene-carboxylic acid. Ethylene bromide. (Ethylene dibromide). C2H4Br2=CH2Br.CH2Br. xatl3°=5.5xl0-i'' [?]; 1477. At 25° is less than 2 X IQ-^; b. p. 128.5°-128.7° @ 741.2 mm.; 1388. In HBr and H2S, no cond.; 1897. In NH3, qual.; 606. In MeNH2, good cond.; 637. Cond. with AgNOs and organic compounds; 1388. Ethylene chloride. (Dichloro-ethane). C2H4Cl2=CH2Cl.CH2Cl. As solvent; 840. Ethylene chlorohydrin see Glycol chlorohydrin. Ethylene cyanide. (Succinic nitrile). C4H4N2=CN.CH2.CH2.CN. xXlO« at 25° = 0.165. At 60°= 1.50. At 63°= 1.58. At 72°= 1.78; b. p. 88°-90° @ 48-52 mm.; 1844, 1843. In HON, no cond.; 943. Cond. as solvent of NEt4l; 1844. Ethylene diamine. C2H8N2=NH2.CH2.CH2.NH2. kaXlO^ at 25°= 8.5 aq.; about 16% too high; diminishes on diln.; 271. Second ks X 10' at 16° is about 6 (colorim.); 1775. At 25°, A(32) = 10.8, (256) = 28.1, (00) = 210; 271. - 1354. B.HCl at 25°, A(32) = 98.3, (1024) = 143.2. - B.2HC1 at 25°, A(32) = 118.6, (1024) = 140.0; 270. In aq. and in Me ale; 2029. - Complex salts; 886, 1416, 1417, 1762, 1755, 1946, 1948, 1949. Ethylene dibromide see Ethylene bromide. Ethylene-ethyl amine see Methylenecyclopropane amine. Ethylene glycol. (Glycol). C2H602=OH.CH2.CH2.0H. K X 10' at 0°=2.37; 1844. At 25°=3.03; 1844, 1853a. In H2S, little cond.; 1897. In NH3, qual.; 606. Cond. with borax; 944. As solvent of NEtil; 1844, 1853a. Ethylenehexaphenyl phosphonium chloride. C38H34Cl2P2= C2H4(PPh3Cl)2. At 25°, A(32) = 80.4, (1024) = 98.0; 270. Ethylene oxide. C2H4O. Cond. in aq. soln. very small; 273. Cond. with HCl, showing change to glycol chlorohydrin; 760. Cond. with acids, very small; 1867. Ethylene urea. C3H6ON2. At 25°, ;u(32) = 0.32, (256) = 0.40; 1748. Ethylethenyltricarboxylic acid see Butenyltricarboxylic acid. Eth] TABLES 157 Ethyl ether. (Diethyl ether. Ethyl oxide). C4HioO=Et.O.Et. n is so small that no approximately accurate figures are possible. It is evidently less than 10~*. Attempts have been made to measure it at temperatures from 0° to about the critical point. See; 305, 362, 366, 635, 816, 986, 1010, 1098, 1316, 1344, 1421, 1556, 1596, 1842, 1843. Near critical tempera- ture; and dielectric constant; 534, 536; qual.; 133. At 25°, A(2) = 0.065; 1843. In HBr; 1646. Qual.; 1897. In HCl; 534, 1646. Qual.; 887, 1897. In HON, no cond.; 943. In HI; 33, 1646. Qual.; 1897. In H2S, no cond.; 1897. In H2SO4; 750. In CI, no cond.; addition of HCl gives a conducting soln.; 887. In NH3, qual.; 606. Cond. with HCl; 534. With inorg. salts; 748. With Et ale; 816, 1421. With Br; 1447. With AlBrs; 1445. With organic acids; 45. As influenced by radium; 2031. Efffect of Rontgen rays on cond. qual.; 1805. As solvent; 20, 289, 360, 366, (711), 1071, 1421, 1580, 1797. Relative basicity in organic solvents (colorim.); 1051. Ethyl ether bromide. C4HioOBr3. Cond.; 1447. [An addition product?] Ethylfumaric acid. (Methylmesaconic acid). C6H804= CO2H.CH : CEt.COsH. IsaXIO' at 25°=9.4; m. p. 193°-195°; 191, 1823, 1831, 1838. /i(32) = 56.2, (256) = 137, (oo) = 354; 1823, 1831, 1838. a-Ethylglutaric acid. C7Hi204=C02H.(CH2)2.CHEt.C02H. kAXlO^ at 24.2°=5.6; m. p. 60°-61°; 1240. = 5.9; increases on diln.; 61, 1418. At(44.6) = 16.9, (713.6) = 63.2, (co) = 352; 1240. Ethylglycollic acid see Ethoxy-acetic acid. /i-Ethyl glyoxaline. C6H8N2. ks X 10* [probably at 25°] = 1.0; m. p. 89°. A(32) = 1.2, (1024) = 7.2, (oo) = 222.7. B.HNO3 [probably at 25°], A(32) = 89.4, (1024) = 102.2; 428. N-Ethyl glyoxaline. C6H8N2. ksXlO' [probably at 25°] = 3; diminishes on diln.; b. p. 206°. A(32) = 0.7, (1024) = 3.1, (°o) = 222.0. B.Picrate [probably at 25°], A(128) = 61.1, (1024) = 69.5; 428. Ethyl-m-homo-o-hydroxy benzoic acid see Ethoxy-p-toluic acid. Ethyl-hydroxy-benzoic acid see Ethoxy-benzoic acid. Ethylidene chloride. (1,1-Dichloro-ethane). C2H4Cl2=Me.CHCl2. In NH3, qual.; 606. Cond. with Cu oleate; and as solvent; 1569. 158 TABLES [Eth a-Ethylideneglutaric acid. C7Hio04=Me.CH:C(C02H)CH2.CH2.C02H. kAXlO^at 25°=3.2; m. p. 152°; 568. A(32) = 11.9, (1024) = 60.9, (oo)=[380]; 1291. 2Na.A at 25°, A(32) = 82.3, (1024) = 98.7; 1291, 568. a-Ethylidene-(3-methylglutaric acid see Dicrotonic acid. Ethylidenepropionic acid. (/37-Pentenoic acid). C6H802=Me.CH:CH.CH2.C02H. kAXlO^ at 25°=3.6; diminislies on diln. A(32) = 12.6, (1024) = 62.5, (00) = 380. Na.A at 25°, A(1024-32) = 10-ll; 571, 564. Ethylidenesuccinic acid see iso-Succinic acid. Ethyl iodide. C2H6I. xxlO^ at 25° is less than 2; b. p. 71°-71.1° @ 747 mm.; 1388. In HCN, no cond.; 943. In NII3, qual.; 606. Cond. with Et2S in ale; 334. With AgNOs and organic com- pounds; 1388. WithAlCls; 1893. Ethyl-^seudo-isatin-|8-oxime. (Ethyl isatoxime). C10H10O2N2. kiX 10^ at 25° is about 2 (sapon.); 752 and 1150. Ethyl isatoxime see Ethyl-^seudo-isatin oxime. EthyUtaconic acid. C7Hio04=Et.CH:C(C02H).CH2.C02H. kAXlQS at 25°=3.6; diminishes on diln. A(32) = 12.6, (1024) = 58.9, (oo) = 376; m. p. 163°-167° with dec; 571a. Ethyl-lactic acid see Ethoxy-propionic acid. Ethyl-laevixlinic acid see Ethyl-acetylpropionic acid. Ethylmaleic acid. (Methylcitraconic acid). C6H804= COaH.CEt : CH.CO2H. kiXlO^ at 25°=2.4; diminishes on diln. ;u(32) = 85.3, (1024) = 263, (co) = 353; m. p. 100°-101°; 191, 1838.- 1823, 1831. Ethylmaleinanilic acid see Methylcitraconanilic acid. Ethylmalonic acid. (a-iso-Pyrotartaric acid). C6H804=CHEt(C02H)2. kiXlO' at 18°= 1.3 (colorim.); 1563, 1781. At 25°= 1.27; diminishes, then increases on diln.; m. p. 110°-112°; 1838, 1371. Second kAX 10^=6.4 (inversion); 1638, 1335. At 25°, /i(32) = 65.1, (1024) = 236, (00) = 356; 1838. 2Na.A at 25°, A(32) = 78.6, (1024) = 95.3; 270. Ethylmalonic acid mono ethyl ester. C7Hi204= CHEt(C02H) (COaEt). kiXlO^at 25°=4.0. /*(33.8) = 39.5, (1080.0) = 167.9, (oo) = 352; 1859. Eth] TABLES 159 1-Ethylmenthyl amine. Ci2H26N = CioHi9.NHEt. B.HCl at 25°, A(32) = 79.9, (512) = 92.2, (1024) = 99.1 (?). - B.HNO3. Also both salts in Me ale; 2029. Ethyl mercaptan. C2H6S=Et.SH. X at 25° is extremely small. Cond. as solvent of NEtJ; 1844. Ethyl-mesaconic acid see Propylfumaric acid. Ethyl metamlic acid see Ethylaniline-3-sulphonlc acid. Ethylmethyl- see Methylethyl- Ethyl mustard oil see Ethyl thiocarbimide. Ethyl nitrate see Nitric acid ethyl ester. Ethylnitrolic acid. (Nitroacetaldehyde oxime. Nitroaldoxime). C2H403N2= MeC(N02) : N.OH. kAX 10^ at 0°=6; m. p. 82°; 752, 683, 684, 733. At 0°, A(32) = 0.1, (cx.) = 213; 752. In pyridine; 754. On account of the small hydrolysis of the sodium salt at v(32), Hantszeh considers this ethylnitrolic acid a pseudo acid, while the salt-forming acid would be stronger than acetic acid. The following salts are derived from the isomer giv- ing colored salts=Erythronitrolic acid. K.A at 0°, A(32)=48.7, (1024) = 59.6. No acid potassium salt exists in aq. soln. - Pyridine. A, exists in aq. soln.; 684. Ethyl-jso-nitrosoacetone see fso-Nitrosomethylpropyl ketone. Ethyl oxide see Ethyl ether. l-Ethylpentamethylene-2-carboxylic acid. (l-Ethylcyclopentane-2- carboxylic acid). C8H14O2. kAXlO' [at 25°]=1.11. A(64.5) = 9.3, (1032.3) = 35.5, (o°) = 352; 2026. a-Ethyl-a/3-pentenoic acid. C7Hi202=MeCH2.CH:CEt.C02H. kAXlO^ at 25°=2.2; diminishes on diln.; b. p. 120° @ 12 mm.; 569, 570. A(64) = 14, (1024) = 48.1, (co)=[376]; 570. o-Ethyl-/37-pentenoic acid. C7Hi202=Me.CH:CH.CHEt.C02H. kAXlO^ at 25°=3.6; diminishes on diln.; b. p. 116° @ 12 mm.; 569, 570. A(32) = 12.6, (1024) = 61.4, (a>) = 376; 570. Ethylphenylethylenelactic acid see Ethylphenylhydroxypropionic acid. o-Ethyl-|S-phenyl-j3-hydroxy-propionic acid. (a-Ethyl-jS-phenylethyl- enelactic acid. Ethylphenyllactic acid). CiiHi403=PhCH(OH).CHEt(C02H). kAXlO^ at 25°= 3.08; increases, then diminishes on diln.; m. p. 111.5°-112.5°. A(29.7) = 10.3, (950.4) = 59.0, (00) = 348; 1704. Ethylphenyl ketone. C9HioO = Et.CO.Ph. In HBr, good cond.; in H2S, no cond.; 1897. Ethylphenyllactic acid see Ethylphenylhydroxy-propionic acid. 160 TABLES [Eth O-Ethyl-N-phenyl pseudo-urea. (Ethylphenyl zso-urea). C9H12ON2 = NH : C (NHPh) OEt. ks X 10^ at 25°= 5; b. p. 138.5°-139.5° @ 18 mm.; 285, 286. At 25°, /i(26.0) = 0.8, (833.1) = 5.4, (oo) = 224.2. B.HCl at 25°, A(32) = 89.0, (1024) = 101.4; 286. Ethyl phosphoric acid see Phosphoric acid mono ethyl ester. Ethyl-o-picoUnium chloride. C8Hi2NCl=C6H7.NEtCl. At 25°, A(32) = 90.6, (1024) = 103.0; 270. Ethylpropyhnalonic acid. C8Hi404=CEtPr(C02H)2. kAX IC =8.9; 1667. [Misprinted as Methylpropyl- etc.] Ethylpyridine. C7H9N=Et.C5H4N. B.HCl at 25°, A(64) = 96.1, (1024) = 102.2; 270. Ethylpyridinium chloride. (Pyridine ethochloride or chloro-ethylate). C7HioNCl=C6H5.NEtCl. At 25°, A(32) = 94.6, (1024) = 106.0; 270. Ethylquinolinium tri-iodide. (Quinolinium ethoiodide diiodide). CllHl2Nl3=C9H7.NEtI.l2. K of molten salt; m. p. 43°-45°; 1578. Ethylstrychninium chloride. (Strychnine ethochloride). C23H2702N2C1= C2lH2202N2.EtCl. At 25°, A(32) = 77.8, (1024) = 91.5; 270. Ethylsuccinic acid. C6Hio04=C02H.CHEt.CH2.C02H. kiX 10^ at 25°=8.5; m. p. 98°; 1838, 175, 200. Second kAX 10^= 1.3 (inversion); 1638. At 25°, m(32) = 17.9, (1024) = 90.1, (co) = 353; 1838. Ethyl sulphamide see Ethyl sulphonic acid amide. Ethyl sulphanilic acid see Ethylaniliae-4-sulphoiiic acid. Ethyl sulphide see Diethyl sulphide. Ethylsulphocyamic acid see Ethyl sulphonic acid cyanoamide. Ethyl sulphonic acid amide. (Ethyl sulphamide). C2H702NS = Et.S02.NH2. At 25°, A(32) = 5.0, (1024) = 20.2. Cond. with diethyl-amine; 1576. Ethyl sulphonic acid cyanoamide. (Ethylsulphocyamic acid). C3H602N2S=Et.S02.NH(CN). kxX 10^ at 25°=7.3; diminishes on diln., from decomposition in soln. /i(104.4) = 9.6, (835.2) = 22.6, (c=o)=350; 70. Ethyl sulphonic acid ethyl ester, (asym. -Diethyl sulphite). C4Hio03S=Et.S02.0Et. XX 10^ at 0°=3.00. At 25°=4.96; b. p. 93° @ 10 mm. Cond. as solvent; 1844. Ethylsulphothiocarbonglycollic acid see Ethyl-|8A-dithio-carbongly- collic acid. Eye] TABLES 161 Ethyl sulphuric acid see Sulphuric acid mono ethyl ester. Ethyl sulphurous acid see Sulphurous acid mono ethyl ester. Ethyl thiocarbimide. (Ethyl mustard oil). C3H6NS=CSNEt. n X 10' at 0°= 0.873; 1844. At 25°= 1.258; b. p. 131°-131.5° @ 760 mm.; 1844, 939, 1223, 1843. In NH3, qual.; 606. Cond. as solvent of organic compounds; 939, 1844. Ethyl thiocyanate see Thiocyanic acid ethyl ester. EthylthioglycoUic acid. C4H802S=EtS.CH2.C02H. kxXlO^at 25°= 1.83 aq. A(31.5) = 27.8, (503.4) = 99.1, (co) = 380; 1465. Pt.2A, v(40), cond. is of order of water; 1466. Ethylthio-phenyl- see Phenyl-ethylthio- Ethyltricarballylic acid. C8Hi206=C02H.CH2.CH(C02H).CHEt(C02H). kAX 10^ at 25°=3.2; m. p. 147°-148°; 1839, 67. Ai(32) = 33.6, (1024) = 151, (a=) = 341; 1839. Ethyltriphenyl phosphonium chloride. C2oH2oCIP= (Et) (Ph3)PCl. At 25°, A(32) = 79.6, (1024) = 90.6; 270. Ethyltrithio-carbonglycoUic acid. C5H802S3=EtS.CS.CHSH.C02H. kAXlO^ [at 25°]=8.2; m. p. 75.5°-76°. /i(91.4) = 90.7, (724.8) = 202.5, (co) = 378; 853. Ethyl ISO-urea. C3H80N2= NH2C(0Et) :NH. keXlO* at 25°= 1.04; b. p. 89° @ 10.5 mm.; 285, 286. A(32) = 13.3, (256) = 34.9, (oo) = 234.6. B.HCl at 25°, A(32) = 99.2, (512) = 110.8; m. p. 123°-124°; 286. Ethylxanthoacetic acid see Ethyl-|3A-dithiocarbonglycollic acid. Ethylxanthogenacetic acid see Ethyl-iSA-dithiocarbonglycollic acid. Ethyl zanthogenate see Xanthic acid ethyl ester, Eucalyptole see'Cineole. Eugenol. (l-Allyl-4-hydroxy-3-methoxy-benzene) . CioH:5.02=CH2:CH.CH2.C6H3(OH)(OMe). In NH3, qual.; 606. Cond. with NaOH and HCl; 1508. Euphorbia helioscopia. (Sun spurge). [The references to this are incomplete. ] Cond. of sap; 253. Eye. [The references to this are incomplete. ] Cond. of fluids of eye; 253. Concentration of H and OH ions in aqueous and in vitreous humor; 587. Cond. of crystalline lens; 259, 260. 162 TABLES [Fen Fencholenic acid. CioHi602=C9Hi6.C02H. kx X 10^ at 18° is about 1 ; increases on diln. A(381) = 18.0, (1933) = 44.3, (oo) = 317; b. p. 260°-261°; 1899. [This acid has been split into two isomers. The acid measured was chiefly the a-acid. ] Ferriacetoacetic ester see Acetoacetic acid ethyl ester; - salts. Ferriacetylacetone see Acetylacetone ; - salts. Ferribenzoylacetic ester see Benzoylacetic acid ester; - salts. Ferribenzoylacetone see Benzoylacetone; - salts. Ferricyanic acid. (Hydroferricyanio acid). C6H3N6Fe=H3Fe(CN)6. 3K.A, at 0°; 901, 903, 1959, 1963. At 18°; 971. At25°, A(32) = 121.3, (1024) = 153.0; 1836, 971. Cond. with colloidal cop- per; 313. E. m. f.; 372. Ferri-diacetyl bromide . C4H604BrFe = Fe (C2H302)2Br. Cond.; 1528. Ferri-diacetyl chloride. C4H604ClFe=Fe(C2H302)2CI. Cond.; 1528. Ferri-oxalic acid. C6H30i2Fe=H3Fe(C204)3. Cond.; 1577. 3(NH4).A; 971.- 3K.A; 1485. E. m. f.; 1581a. Ferrocyanic acid. (Hydroferrooyanio acid). C6H4N6Fe=H4Fe(CN)6. At25°,M(32) = 875, (1024) = 1223.6; [in Hg.U.]; 1362. Under pressure of 1-500 atmospheres; 220. 2Ba.A; 1338. - 2Ca.A; 158, 1338. - 2Mg.A; 1836. - 4K.A at 25°, A(32) = 108.1, (1024) = 152.2; 1836, 901, 903, 924, 1338; at 0° to 100°; 839, 889, 901, 903, 924, 1024, 1338, 1709, 1953a. Under pressure of 1-500 atmospheres; 220. Cond. with gelatin; 468. Cond. with CUSO4; 1709. E. m. f.; 372. - 2Sr.A; 158. - 2Zn.A in NH3, qual.; 606. Ferro-oxalic acid. C4H208Fe=H2Fe (0204)2. 3K.A, e. m. f.; 1581a. Ficus elastica. (India-rubber tree). [The references to this are in- complete. ] Concentration of H and OH ions in sap; 587. Ficus sicomorus. (Mulberry fig). [The references to this are incom- plete. ] Cond. of sap; 253. Fishes. [The references to this subject are incomplete.] Cond. of fluids of various parts and organs of fishes, with a bib- liography of the literature; 250, 253. Flavindulinium see Phenylphenanthrophenazonium hydroxide. For] TABLES 163 Fluor- see Fluoro- Fluorenol-carboxylic acid see Diphenylene-glycollic acid. Fluorenone. (Diphenylene-ketone. 9-Ketofluorene) . CiaHgO. Comparative strength (colorim.); 1665. Fluorenone-5-carboxylic acid. (Diphenylene-ketone carboxylic acid. 9-Ketofluorene-4-carboxylic acid). CuHsOs. Comparative strength (colorim.); m. p. 227°; 1665. Fluorenone-6-carboxylic acid ethyl ester. C16H12O3. Comparative strength (colorim.); 1665. Fluorescein. C20H12O6. Effect of fluorescence on cond.; 1476. Effect of light on cond.; . 325, 833, 1321. 2Na salt, effect of light on cond.; 1471a. [The salt may have been used in the other references.] Fluoroacetic acid. C2H302F=CH2F.C02H. kAXltf [at 25°]=2.17; m. p. 33°. A(32) = 82.3, (1024) = 270.4, (oo) = 362.5. Na.A [at 25°,] A(32) = 76.7, (1024) = 86.7; 1693. m-Fluorobenzoic acid. C7H502F=F.C6H4.C02H. kA X 10* at 25°= 1.36; increases on diln. A(64) = 31.5, (1024) = 111.4, (cc=) = 355; 1371. Formaldehyde. CH20=HCH0. kiXlO" at 0°=1.4 (hydroL); 529, 512, 528.=2.1 (hydrol.); 58. At 25°, A(38.1) = 2.5, (608.8) = 7.6; 959. Cond. with NaOH; 58, 528. With casein and with gelatin; 1599. Formaldehyde sulphurous acid. CH404S=HCHO.H2S03. At 25°, A(38.1)'=361.1, (608.8) = 381.4, (co) = 379.1 or 388.1; 959. K.A at 25°, A(32) = 97.8, (1024) = 116.7; 643.- Na.A at 25°, A(1000) = 89.6; 959. Formamide see Formic acid amide. Formanilide. C7H70N=Ph.NH.CHO. kAXlOi" at 25°=5. m(20) = 0.03, (160) = 0.10, (oo) = 355; 538. In NH3, qual.; 606. Cond. with NaOH; 538. r-0-) Formhydroxamic acid. CH302N=HCH.N.OH. kAXlO'at25°=l. /t(32) = 0.7, (64) = 1.2, (co)=[380]; 1353a. Formic acid. CH202=HC02H. xxl0*at0°=4.69; 787. At 8.52°=0.15, extrapolated; 1330. At 15°= 1.23; 1330. At 17°= 0.1705; 347. At 18°=6.47; 787; 1380. At 18.8°=0.4; m. p. 8.39°, contained about 0.2% aq.; 1575. At 19°=0.668; 1853c. At 25°=2.91; 2008;=1.6; 753. At 30° =7.99; 787. 164 TABLES [For In all the following measurements, k diminishes on dilution. kAXlO* at 10°= 1.94; 875. At 14.1°= 1.98; 838. At 17° = 2.07 aq.; 164. At 18°=2.2 (colorim.); 1563. At 20°=1.96; 875. At 25°=2.14; 1370, 44; = 2.0 (neutral.); 295. At 30°=1.97;875. At40°=1.96;875. At 54.3°= 1.83; 44. At 55° = 2.5 (action of disastase on starch); 2002. T not stated; comparative, (colorim.); 951; (precipitation of casein); 693. Cond.; 171, 294, 380, 542, 787, 788, 838, 1330, 1747, 1853c, 1957. At 25°, A(32) = 29.3, (1024) = 134.7, (oo) = 376; 1370. In HCl ; 30 ; qual. ; 1897. In HBr, no cond. ; 30, 1897. In HaS, no cond.; 1897. In II2SO4; 223. In N2O4, no cond.; 602. In SO2; 1842. In NH3, qual.; 606. In Et and Me ale; 787, 788. Cond. with KOH; 171, 294, 299. With boric acid, qual.; 1184. With alcohols and sugar; 45. With lactose; 1747. With Cu formate; 1618a. With albumin; 2032. Under pressure of 1-260 atmospheres; 542. E. m. f.; 372. As solvent; (223), (347), 746, 753, (1853c), 2008. NH4.A; 823. - Ba.2A; 911, 1953a. - Ca.2A; 502, 1953a. - Ce.3A; 1496. -Cu.2A; 1618a. In NH3, qual.; 606. Cond. with formic acid; 1618a. Cond. with pyridine; 1569. - Gl salt; 1711. -La.3A; 1496. - Pb.2A, in NH3, qual.; 606. - Li. A; 1367. - Mg.2A; 1836, 1837, 1953a. - K.A; 1367, 380, 753. In HCO2H; 753. In flame; 682. - Na.A at 25°, A(32) = 87.8, (1024) = 98.1; 1368a, 1367. At 10°-40°; 164, 875. Under pressure of 1-260 atmospheres; 542. Cond. with organic compounds; 1994. In HCO2II; 753. In NII3, qual.; 606. In flame; 682.- Sr.2A; 911. - UO2.2A; 449. Formic acid amide. (Formamide). CH30N=II.CONH2. xxl0=^ at 0°=1.80. At 25°=3.87; b. p. 118°-119° @ 18 mm.; 1844, 1843; 1506d, 1853b. At 19°= 17.7; 1853c. At 19°, A(17.7) = 0.06; 1853c. In SO2; 1842. In NH3; 610. Cond. with HCl; 410, 1506d. With NaOH; 412. With HgCl2; 1097. With Na formamide; 1506d. As solvent; 1506d, 1844, (1853c). B.3HC1; 1506d. Formic acid amyl ester. C6Hi202=H.C02C5Hu. InNH3, qual.; 606. Effect of temperature on cond. ; 106. Formic acid iso-butyl ester. CbHio02. Effect of temperature on cond. ; 106. Formic acid ethyl ester. C3H6O2. In NH3, qual.; 606. Effect of temperature on cond.; 106. Fum] TABLES 165 Formic acid methyl ester. C2H4O2. Effect of temperature on cond. ; 106. Formic acid propyl ester. C4H8O2. Effect of temperature on cond.; 106. Orthoformic acid see under the letter O. Formylcyano- see Cyanoformyl- Foxglove see Digitalis. Fructose. (Laevulose). C6Hi206=CH20H.(CHOH)3.CO.CH20H. kAXlQi^ at 0° = 3.6 (hydrol.); 512. At 10°=4.6 (catal.) At 18°=6.6 (catal.). At 25°=8.8 (catal.). At 40°=14.9 (catal.); 1177, and 1150. At 25°, A(4) = 1.54; 1843; -also 1108, 1110, 1497. In NH3, qual.; 606. Cond. with boric acid and inorg. salts; 1497. Fuchsine. This is the hydrochloride or acetate of rosaniline or of a mixture of bases of which rosaniline is the chief part. B.HCl [Probably, pure p-rosaniline HCl], at 25°, m(273) = 98.3; 1402. /i(256) = 87.3; 882, 1265, 1266. At 18°-90°; 1796. At 15°-100°; alone and with H2SO4; 1798. [Structure not given.] Effect of light on cond.; 1321. In MeNIl2, small cond.; 637. Fulminic acid. (Carbyloxime). CHON=C:N.OH. Hg.2A; 1094. In NH3, qual.; 606. - Na.A at 0°, A(32) = 52.4, (1024) = 57.6; 1986. In aqueous soln. the sodium salt gives also the reactions of hydroxamic acid, showing a change due to hydration; see Palazzo, Tamburello, Gaz. Chim. Ital. 37, I, 1, (1907). Fumaranilic acid. (Anilinofumaric acid). CioH903N=C02H.CH:CH.CO.NHPh. Na. A, [at 25°,] A(32) = 64.1, (1024) = 74.2; 191. Fumaric acid. C4H404=C02H.CH:CH.C02H. k increases on diln. in all measurements of cond. kAXlO^ at 0°=9.4; 1968a;=8.0 aq.; 1018. At 12°=9.7; 1968a. At 18° = 11 (colorim.); 1562, 1563, 1781. At 22°=9.4 aq. 164. At 25°= 10.1; 1968a. = 9.3; 1372; = 11.8 (neutral.) ; 1718. At 35°= 10.0; 1968a. Second kAXl05=2.2 (part.); 370; (inversion); 1335, 1638. = 3 (cond.); 370, 1911. Cond.; 170, 1718. At 25°, ai(32) = 58.0, (1024) = 228.1, (<») = 353; 1968a. ai(32) = 56.4, (1024) = 228.0, (<») = 357; 1372. -Qual.; 1387. In HBr, no cond. In HCl, small cond.; 30. Cond. with KOH; 170. With NaOH; 1508, 1718. 166 TABLES [Fum Mg.A; 319, 1836. -2K.A and KH.A; 164. - NaH.A; 370. -2Na.A, at 25°, A(32) = 89.5, (1024) = 108; 370, 270; -495. Fumaric acid mono ethyl ester. C6H804=C02H.CH:CH.C02Et. JiAXlO^ at 25°=4.8; diminishes on diln. m(22.0) = 34.5, (704.0) = 153.2, (co) = 354; 1859. Furfur- see also Furyl- FurfuracryUc acid. C7H603=C4H30.CH:CH.C02H. kAXl05=3.25; m. p. 141°; 1104. aHo-FurfuracryUc acid. C7H603= C4H3O.CH : HC.CO2H. kAXlO^=7.82; m. p. 82°-86°; this acid contained a little fur- furacrylic acid; 1104. Furfurol. (Furfuraldehyde. Furol). C6H402=C4H30.CHO. xXlO' at 0°=9.73; 1844, 1843. At 20°= 11; 1590a. At 25°= 1.61; b. p. 161° @ 753 mm.; 1847, 517, 1106, 1107, 1569, 1844. kAXlO" at 0° is less than 1 (hydrol.); 512. At 25°, A(2) = 0.15; 1843. In HBr and HI, good cond.; in H2S, poor cond.; 1897. Cond. with Cu oleate; 1569. As solvent; 1106, 1107, 1569, 1590a, 1844, 1847, 1849, 1853a. As solvent under pressure; 1590a. Compound with II2SO3, no cond.; 962. Furyldihydro-resorcinol. C10H10O3 = C4H3O . CeHeO (OH) . kAXlO* at 25°=1.5 aq.; diminishes on diln.; m. p. about 150° with dec. A(326.7) = 25.4, (1307)=48.0, (oo)=374; 1588. G. Galactose. C6Hi206=CH20H.(CHOH)4.CHO. K of soln. of 1 mol in 1 litre=3.5 XlO'^; 322. In NH3, qual.; 606. In MeNH2, little cond.; 637. Gallein. Gi^^Qr, formerly given as C20H10O7. In MeNH2, little cond.; 637. Gallic acid. (3,4,5-Trihydroxy-benzoio acid). C7H606=(OH)3C6H2.C02H. [C02H=1; 0H=3, 4, 5.] kAXlO^ at 0°=3.38; increases on diln. At-6.5°=3.6; increases, then diminishes on diln.; 1968a. At 18°= 5.9 (colorim.); 1563, 1781. At 25°=3.9; increases, then diminishes on diln.; 1371, 1968, 1968a, 1184. At 35°= 3.9; increases, then diminishes on diln.; 1968a. At 25°, m(32) = 11.7, (1024) = 66.5, (oo) = 356; 1371. ai(1024) = 62.5, (oo) = 348; 1968a. - 1718. In NH3, qual.; 606. In Et ale; 1185. Glu] TABLES 167 Cond. with boric acid; 1184, 1185. With NaOH; 1508, 1718. Na.A at 25°, m(2048) = 74.4; 1968a. Gallic acid ethyl ester. C9Hio06= (OH)3C6H2.C02Et. kAXlO^ at 25°=9.7; diminishes on diln.; m. p. 155°. /i(32) = 0.6, (256) = 1.6, (oo) = 351; 404. Gallic acid methyl ester. CsHgOs. kAXlO^ at 25°=9.7; diminishes, then increases on diln.; m. p. 193°. iu(32) = 0.6, (256) = 1.9,' (o°) = 352; 404. Gallotannic acid see Tannic acid. Gasteria maculata. [The references to this are incomplete.] Cond. of sap; 253. Gastric juice. [The references to this are incomplete. ] Cond.; 253. Concentration of H and OH ions; 687. Gelatin. There is still doubt as to whether gelatin is CxHxOxNx, or whether it also contains sulphur. X of 0.726 g in 100=5.2 xlO^^ 445a.- 145b, 468, 1225b, 1225c, 1226, 1397, 1599. Cond. with K4Fe(CN)6 and KCNS; 468. With HCl and inorg. salts; 1397. With KaCraOy; 1225b, 1225c, 1226. With NaOH; 617a. With inorg. salts; 145b, 1599. With dia- stase; 807, 808. With formaldehyde and phenol; 1599. With trypsin; 145b. Penetration by X-rays, [no cond.]; 154. Effect of light on chromatized gelatin; 1225b, 1226c, 1226. Gelsemine. C22H38O4N2; also given as C24H28O4N2. kfiXlO' at 15°= 1.8 (hydrol.); 1779. Gentisic acid see 2,5-Dihydroxy-benzoic acid. Gentisic aldehyde see 2,5-Dihydroxy-benzaldehyde. Gentisinic see Gentisic. Gliadin. [The references to this are incomplete. ] H ion concentration; 1611b. See also; 2005. Globulin. [The references to this are incomplete. ] See Edestin and Serum globulin; also Blood. Glu- see also Gly- Glucinum. (Beryllium). Complex salts with organic acids; 320a, 1621, 1711, 1712. Gluconic acid see Glyconic. Glucose. (Dextrose). C6Hi206=CH20H.(CHOH)4.CHO. kAXlQi^ at 0°=1.8 (hydrol.); 612. At 10° = 2.4 (hydrol.); 1177 and 1150. At 18°= 3.6 (hydrol.); 1177 and 1160; approxi- mates 0.14 (hydrol.); 532. At 25° =5.9 (sapon.); 1364, 392, 1036, 1177, 1160. At 40°= 9.8 (hydrol.); 1177 and 1150. 168 TABLES [Glu Cond.; 322, 1108, 1110, 1464a, 1497, 1746. In NHs, qual.; 606. In MeNH2, little cond.; 637. In Me ale; 1746. Cond. with inorg. acids; 741, 1497, 1746. With organic acids; 45. With NaOH and other bases; 532, 1746. With salts; 1497, 1746. Concentration of H ions; 1259b. Glutaconic acid. C6H604= CO2H.CH2.CH: CH.CO2H. kAXlO* at 25°=1.83; increases on diln.; m. p. 132°. m(32) = 26.2, (1024) = 127.0, (oo) = 356; 1838. Glutamic acid see Aminoglutaiic acid. Glutaminic acid see Aminoglutaric acid. Glutaric acid. C6H804=CH2(CH2.C02H)2. kiXlO^ at 18°= 5.3 (colorim.); 1563. At 25°=4.75; 1371, 1638, 1810. Second kAXlO'=2.7 (inversion); 1335, 1638. = 3.4 (part.);=2.9 (cond.); 370. At 25°, m(64) = 19.0, (1024) = 70.0, (oo) = 354; 1371. Co.A. - Mg.A. - Ni.A; 1736. - 2K.A; 494. - NaH.A; 370. - 2Na.A at 25°, A(32) = 82.9; (1024) = 99; 370, 270. Glutaric acid anhydride. CsHeOs. Cond. showing change to acid; 1810. Gluten. A mixture of gliadin and glutenin; (with some included starch; 2005). Relative cond. with inorg. and organic acids; 2006. a,|3-Glyceric acid. C3H604=CH20H.CHOH.C02H. kAXlO* at 25°=2.3; 1184, 1370. m(32) = 29.1, (128) = 55.3, (oo) = 357; 1184. Cond. with boric acid; 1184. Glycerine see Glycerol. Glycerol. (Glycerine). C3H803=C3H6(OH)3. X XlO^ at 0°=2.2. At 5.9°=3.6. At 11.7°=5.6. At 14.8°=7.8. At 16°=8.4. At 17.6°=9.6.; 361. At 20°=10; 1590a. At 21.3°=12.3; 361. At 25°= 6; 1592. Cond.; 806, 1181, 1222, 1434, 1980. In HBr, good cond. In H2S, no cond.; 1897. In HCN, no cond.; 943. In NH3, qual.; 606. In MeNH2, fair cond.; 637. Cond. with inorg. acids; 799, 1181. With organic acids; 799, 46. With KOH; 385. With NaOH; 1035. With salts; 145b, 361, 944, 1279, 1592. As solvent, under pressure; 1590a. As solvent; (361), (385), (1221), (1278), 1279, 1434a, 1590a, (1592). Dielectric constant; 582. Glycerol phosphoric acid see Phosphoric acid glycerol ester. Gly] TABLES 169 Glycine see Aminoacetic acid. GlycochoUc acid. C26H4306N=C24H3904.NH.CH2.C02H. kAXlO^ at 25°=1.32; diminishes on diln. m(750) = 97.7, (1500) = 128.3, (°o) = 363. Na.A at 25°, m(200) = 60.4, (800) = 64.9; 228. Glycocoll see Aminoacetic acid. Glycocoll-p-phenetidine. (Phenocoll). CioHi402N2=EtO.C6H4.NH.CO.CH2.NH2. B.HCl at 25°, A(32) = 82.4, (1024) = 93.0; 270. Glycocyamine see Guanidineacetic acid. Glycogen. (CeHioOs)^. Dialyzed soln., x at 20°, is of the order 3 XlO^^ 254, 256. - 252a. Cond. with NaOH; 252a. Glycol see Ethylene glycol. Glycolamide see Glycollic acid amide. Glycol chlorohydrin. (Chloroethyl alcohol. Ethylene chlorohydrin) . C2HbOC1=CH2C1.CH20H. Cond. with HCl; 760. Glycoliminohydrin. C4H10O4N2 or C2HBO2N. At 25°, iu(64) = 67.3, (1024) = 76.5 for formula, C4H10O4N2; m. p. = 162°-163°. Cond. with HCI and NaOH; 781. GlycolUc acid. C2H403=CH20H.C02H. kiXlO* at 17°= 1.57 aq.; 164. At 18° is about 1.5; 93. At 25°= 1.52; 1184, 1370; (colorim.); 1781. Cond.; 93, 94, 171, 782, 1094, 1495. At 25°, A (32) = 24.8, (1024) = 116.7, (oo) = 363; 1370. In HCI, no cond.; 30. In NH3, qual.; 606. In Et ale; 782, 1820. Cond. with boric acid; 1184. With Cr(0H)3; 320b. With M0O3; 1496. With acetic acid; 93, 1821. With KOH; 171. With organic salts; 94. Hg.2A; 1094. - K.A; 94. - Na.A at 18°; 93, 94. At 25°, A(32) = 74.0, (1024) = 84.7; 1368a.- UO2.2A; 449. Glycollic acid amide. (Glycolamide). C2Hb02N=CH20H.CONH2. Cond. with HCI and NaOH; 781. GlycolUc nitrUe. C2H30N=CH20H.CN. xXlO^ at 0°=5.16. At 25°=8.34; b. p. 98° @ 10 mm.; 1843, 1844. As solvent of NEt4l; 1844. Glycol phosphoric acid see Phosphoric acid mono glycol ester. Glyconic acid. (Gluconic acid). C6Hi207=CH20H.(CHOH)4.C02H. Ca.2A at 17°, A(0.09) = 25.0; 525. Glycosaccharic acid see Saccharinic acid. 170 TABLES [Gly Glycyl-aminoacetic acid. (Glycyl glycine). C4H803N2=NH2.CH2.CO.NH.CH2.C02H. kAXlO^ at 25°= 1.8 (hydro!.). kB XlO" at 25°=2 (hydro!.); 519, 523. Cond. with HC! and NH4OH; 522. With erepsin and pancreatin; 519, 523. Glycyl glycine see Glycyl-aminoacetic acid. Glycyl-hydroxjrphenyl-aminopropiomc acid. (G!ycy! tyrosine). Cond. after digestion with trypsin; 145b. Glycyl tyrosine see Glycyl-hydroxyphenyl-aminopropionic acid. Glyoxal. C2H202=OHC.CHO. InNHs, qua!.; 606. Glyoxalic acid see Glyoxylic acid. Glyoxaline. C3H4N2. ksXlO' [at25°] = 1.2; m. p. 90°. Ai(32) = 0.42, (256) = 1.4, (cd) = 231.4. B.HNO3 [at 25°], ;u(32) = 98.1, (1024) = 109.9; 428. Glyoxime carboxylic acid see Dioximino-propionic acid. Glyoxime dicarboxylic acid see Dioxunino-succinic acid. Glyoxylic acid. (GIyoxa!ic acid). C2H404=(OH)2.CH.C02H=CHO.C02H+H20. kAXlO* at 25° is about 4.7; aq. used for soln. was not pure. /i(32) = 41.7, (1024) = 174, (oo) = 361; 1370. Granatum. (Pomegranate) . [The references to this are incomplete. ] Cond. of soln. of bark; 146. Grape. [The references to this are incomplete. ] Concentration of H and OH ions in grape juice; 587. Guaiacol. (2-Methoxy-phenol. Pyrocatechol mono methyl ether). C7H802=MeO.C6H4.0H. xxl0''at25°=2.6; 1569. kAXlO' at 25° is about 1; increases on diln. ai(23.7) = 0.4, (189.2) = 2.0, (oo) = 356; 70. InNHs, qual.; 606. Cond. with NaOH and HCl; 1508. With Cu oleate; and as solvent; 1569. Guaiacolcarboxylic acid. (2-Hydroxy-3-methoxy-benzoic acid). C8H804=OH.C6H3(OMe).C02H. [C02H=1.] kxXlO^ at 25°=1.38 aq.; diminishes on diln.; m. p. 149°-149.5°. )u(128) = 121, (1024) = 235, (oo) = 354; 1186. InEt ale; 1185. Cond. with boric acid; 1185, 1186. Guanidine. CH6N3=HN:C(NH2)2. kaXlO* at 15°=1.1 (colorim.); 1175. Hel] TABLES 171 Cond. at 25°, m(32) = 189.7, (256) = 208.3; in aq. containing some NH4OH; 1363. B.HCl at 25°, A(32) = 106.1, (1024) = 117.1; 270.- B.HNO3 in NH3, qual.; 606. - B.Picrate; 405. Guanidineacetic acid. (Glycocyamine). C3H702N3=HN:C(NH2).NH.CH2.C02H. ksXlO" at 40°=2.4 (catal.); 1995 and 1150. At 40.2°=2.32 (catal.); 1996. Guanine. (2-Amino-6-oxypurine). CsHsONs. kfiXlQi'' at 40°=8.35 (catal.); 1995 and 1150. At 40.2°=8.07 (catal.) ; 1995. Gum arabic. [The references to this are incomplete. ] Cond. of aq. soln. is not affected by radium; 2031. Cond. with KCl; 145b. Haematinic acid anhydride. C8H806=C02H.H7C6: (C0)20. kAXlO* at 25°=2.4; increases on diln. m(40) = 33.8, (1280) = 157; m. p. 96°-97°; 1029. Haematinic imide. (Biliverdic acid. BUiverdinic acid. Haemo- tricarboxylic acid imide.) C8H904N= CO2H.H7C6 : (C0)2NH. kAXlO° at 25°=3.6; diminishes on diln.; m. p. 113.4°-114.5°. A((40) = 14.1, (1280) = 72.9; 1029. Cond. different from that in 1029; no data; 1032. Haematoxylin. CieHuOe- InNHa, qual.; 606. Haemotricarbozylic acid. C8Hi206=C02H.(CH2)2.(C02H)CH.CHMe.C02H. a)m. p. 140°-141°. kAXlO* at 25°=2.50; diminishes on diln. /i(32) = 32, (1024) = 125.3, (oo) = 375; m. p. 140°-141°; 1030, 1033. b) m. p. 175°-176°. kAXlO^ at 25°=2.45; diminishes on diln. ;it(32) = 31.7, (1024) = 130, (oo) = 375; m. p. 175°-176°; 1030, 1033. Heart. [The references to this are incomplete. ] Cond.; 156a, 253, 623, 624. Helianthine see Dimethyl-aminoazobenzene sulphonic acid. Heliotropine see Kperonal. Helvetia Blue. (Soluble Blue.) Trisulphonic acid. The dye is the sodium salt. The free acid is triphenyl-p-rosaniline-tri- sulphonic acid C37H280N3(S03H)3. Free acid, at 18°, /i(400) = 556.0, (1600) = 667.2. At 90°, ^(400) = 1156, (1600) = 1242. This is the cond. of a disulphonic acid. Cond. with KCl; 976a. 172 TABLES [Hem Hem- see also Haem- Hemipic see Hemipinic. Hemipinamic acid see Hemipinic acid mono amide. Hemipinic acid. (Dimethoxy-norhemipinic acid. 3,4-Dimethoxy-o- phthalic acid. Hemipic acid). CioHio06=(MeO)2C6H2(C02H)2. [C02H=1, 2; MeO=3,4.] kAXlO' at 25°=1.17; increases on diln. fi{S2) = 58.7, (1024) = 230.4, (oo) = 352; 966, 1909. Hemipinic acid 2-mono amide. (2-Hemipinamic acid, a- acid). CioHuOsN. [C02H=1; CONH2=2.] kAXlO^ at 25°=7.0; diminishes on diln. /i(64) = 22.6, (1024) = 75.4, (oo) = 350; m. p. 160°-162°; [k is not given correctly in the original]; 1243, 1244. Hemipinic acid 1-mono amide. (1-Hemipinamic acid. /3- acid). CioHiiOsN. [C02H=2; C0NH2=1.] kiXlO* at 25°=4.3; diminishes on diln. /i(64) = 53.7, (1024) = 147.5, (oo ) = 350; m. p. 142°; [k is not given correctly in the original]; 1243, 1244. Hemipinic acid 1-mono ethyl ester. (0- ester). Ci2Hi406=(MeO)2C6H2(C02Et)(C02H). [C02H=2; C02Et= 1.] kAXlO* [at25°] = 1.48; m. p. 144°-145°. At(182) = 52.8, (1456) = 123.6, (oo) = 350; 1907. Hemipinic acid 2-mono ethyl ester, (a- ester). C^HiiOe. [C02H=1; C02Et=2.] kAXlO' [at 25'']=1.01; m. p. 147.5''-149°. m(139.3) = 108.6, (1114.4) = 213.2, (co) = 350; 1907. Hemipinic acid 1-mono methyl ester. (j3- acid). CiiHiaOe. [C02H=2; C02Me=l.] kAXlO' at 25°=1.30; m. p. 136°-137°; 1371, 1941. m(136.1) = 126.9, (272.6) = 162.0, (oo) = 373; 1941. Hemipinic acid 2-mono methyl ester, (a- acid). CiiHisOe. [C02H=1; C02Me=2.] kAXlO* at 25°=1.67; m. p. 117°-119°; 1941;=1.60; diminishes on diln.; 1371. m(324.8) = 77.5, (650.6) = 104.3, (cc,) = 373; 1941. Hemipinic acid 1-mono propyl ester, (^-n-ester). CisHisOe. [C02H=2; C02Pr=l.] kAXlO* at 25°=9.3; m. p. 125°-125.5°; 1909, 1907. jn(255.5) = 142.6, (1025) = 225.8, (oo)=372; 1909. Hemipinic acid 2-mono propyl ester, (a-n-ester). CisHieOe. [C02H=1; C02Pr=2.] kAXl0^at25°=1.46; m. p. 131°-132°; 1909, 1907. m(510.9) = 88.9, (1023) = 117.0, (oo) = 372; 1909. Hex] TABLES 173 m-Hemipinic acid. (4,5-Dimethoxy-o-phthalic acid. Hemipinic acid of Ostwald). CioHio06= (MeO)2C6H2(C02H)2. [C02H=1,3; MeO=4,5. See Kirpal, Monatsh. 18, 462.] kAXlO^ at 25°= 1.47; diminishes on diln. At(64) = 92.6, (1024) = 237.0, (oo) = 352; 1371. Heptadi-inene-carboxylic acid see />seudo-m-Toluic acid. Heptane. CyHie. xXlO'^at 18°=4.1. Cond. with hydrocarbons; 386. As influenced by radium; 873. a|3-Heptenoic acid. C7Hi202=Me.(CH2)3.CH:CH.C02H. kiX 10^=1.5; b. p. 225°-228° @ 737 mm. A(64) = 11.9, (1024) = 42, (oo)=[376]; 1547. Heptinic acid. (iso-Gentisic acid. iso-Heptinic acid). C8H12O3. kAXlO^ at 25°=8.3; m. p. 149°-151°; 1823, 1831. m(128) = 34.4, (512) = 65.4, («>) = 352; 1823. Heptoic acid. (Heptylic acid. Oenanthylic acid). C7Hi402=Me.(CH2)6.C02H. kAXlQS at 25°=1.31; b. p. 221.3° (cor.); 601; = 1.47; 461. A(128) = 14.1, (1024) = 38.2, (oo) = 352; 601. A(90.9) = 13.2, (00) = 368; 461. InNHa, qual.; 606. Na.A at 25°, A(32) = 68.5, (1024) = 73.0; 601. Heptoic aldehyde see Heptyl aldehyde. Heptyl alcohol. C7H16O. ' InNHs, qual.; 606. Heptyl aldehyde. (Heptoic aldehyde. Oenanthylic aldehyde). C7Hi40=Me.(CH2)6.CHO. In HBr and HCl, good cond.; in HI, poor cond.; in H2S, no cond.; 1897. In NH3, qual.; 606. Heptylic acid see Heptoic acid. Heptylmalonic acid. CioHi804=Me.(CH2)4.CHMe.CH(C02H)2. kiXlO' at 25° = 1; m. p. 97°-98°; 1638, 1667. Second kxX 10' =6.1 (inversion); 1638. " At 25°, /*(199) = 125.8, (1592) = 240:0, (oo) = 349; 1638. Hetero cinnamic acid see Cinnamic acid. Heteroxanthine see 7-Methyl xanthine. Hexachloro-benzene. (Perchloro-benzene) . CeCle. InNHs, qua!.; 606. Hexahydro-benzoic acid. (Cyclohexane-carboxylic acid). C7Hi202= CeHii.C02H. kAXlO^ at 25°=1.28; increases on diln.; b. p. 232.5°; 1138; = 1.34; 2026. A(64) = 10.4, (1024)=40.6, (oo) = 374.5; 1138. A(80) = 11.5, (1280) = 43.3, (00) = 352;. 2026. 174 TABLES [Hex Hexahydro-phenyl acetic acid see Cyclohexane-acetic acid. Hexahydro-phenyl propionic acid see Cyclohexane-propionic acid. cfs-Hexahydro-o-phthalic acid. (Hexamet}iylene-l,2-dicarboxylic acid). C8Hi204=C6Hio(C02H)2. kiXlO^ [at25°]=4.4; m. p. 192°; 72, 1410. frans-Hexahydro-o-phthalic acid. CsRnOi. kiXlO^ [at 25°] = 6.2; m. p. 221°; 72, 1410. cis-Hexahydro-p-phthalic acid. (Hexamethylene-l,4-dicarboxylic acid). C8H12O4. kAXlO^ at 25°=2.97 aq.; m. p. about 162°. Second kAXlO'=3.0; (inversion). At 25°, Ai(68.4) = 15.5, (1094) = 57.3, (oo)=351; 1638. frans-Hexahydro-p-phthalic acid. C8H12O4. kAXlO^ at 25°=4.56 aq.; m. p. above 300°. Second kAXlO'=2.5 (inversion). At 25°, Ai(204.6) = 31.3, (1637) = 83.7, (co) = 351; 1638. Hexahydro-toluic acid see Methylcyclohexane-carboxylic acid. Hexahydroxy-trichloro-bromotriketo-liexamethylene. CeHaOsClsBr. [At 25°], ju(128) = 3.1, (512)=4.6; m. p. 87°; 727. Hexamethylene-dicarboxylic acid see Hexahydro-phthalic acid. 1,1,3, 3-HexamethyIene-tetracarboxylic acid. C10H12O8. kAXlO^ at 25°= 1.2; increases on diln. ^(21.3) = 52.1, (680.0) = 228.6, (00) = 350; 1859. Hexamethyl-p-rosaniline see Hexamethyl-triamino-triphenyl carbinol. Hexamethyl-p-triamino-triphenyl carbinol. (Crystal Violet. Hexa- methyl-p-rosaniline). C25H3iON3= (C6H4.NMe2)3C.OH. Free base at 0°; 770. At 25°, ai(256) = 150.6; 770. B.Br and B.Br.2HBr; 734, 1571. - B.Cl at 0°; 770. At 25°, m(128) = 88.3, (1024) = 95.0; 770, 1266. - B.HCI, B.3HC1; 734. Hexanaphthene-carboxylic acid see Methylpentamethylene-carboxy- lic acid. Hexane. C^Hu. K is extremely small; 386, 873a. Cond. alone and as affected by radio-active 'substances; 873. Cond. before and after continued passage of current; 1605. With organic compounds; 386. Hexanitro-diphenyl amine. C12H6O12N7. In aq. is too insol. to measure; 321,754. In pyridine; 754;qual.; 321. Hexaphenyl-ethane. C38H3o=Ph3C.CPh3. In SO2, no cond. ; 671. See also Triphenyl-methyl. Hexenlc acid see Hexenoic acid. Horn] TABLES 175 a/S-Hexenoic acid. (Hexenic acid). C6Hio02= Me.(CH2)2.CH: CH.CO2H. kiXlO* at 25°=1.89. A(32) = 9.2, (1024) = 49.2, (co) = 378. Na.A at 25°, A(1024-32) = 10-11; 671. |37-Hexenoic acid. (Hydrosorbic acid). C6Hio02=Me.CH2.CH:CH.CH2.C02H. kAXlO^ at 25°= 2.7; diminishes on diln.; 571. = 2.4; 1371. A(32) = 11.0, (1024)=55.3, (oo)=378; 571. A(32) = 9.7, (oo) = 357; 1371. Na.A at 25°, A(32) = 64.9, (1024)=75.2; 1368a;- 571. 75-Hexenoic acid. C6Hio02=Me.CH:CH.(CH2)2.C02H. kAXlO* at 25°=1.74; diminishes on diln. A(32) = 8.8, (1024) = 47.1, (00) = 378. Na.A at 25°, A(1024-32) = 10-11; 571. 5€-Hexenoic acid. C6H10O2 = CH2 : CH. (CH2)3.C02H. kxXlO^ at 25°=1.92; diminishes on diln. A(32) = 9.3, (1024) = 49.2, (00) = 378. Na.A at 25°, A(1024-32) = 10-ll; 571. Hexinic acid. C7H10O3. kAXl0«at25°=8.4; m. p. 126°-127°. m(64) = 25.1, (512)=66.3, (00) =354. Na. A at 25°, /*(32) = 65.9, (1024) = 75.9; 1823, 1831. Hezoic acid see Caproic acid. Hippuric acid see Benzoylamino-acetic acid. Histidine. (a-Amino-/3-imidazole-propionic acid). C6H902N3=C3H3N2.CH2.CH(NH2).C02H. kAXlO' at 25°=2.2 (hydrol.). kBXlO« at 25°=5.7 (hydrol.). Second kBXlO"=5.0 (catal.). At 25°, A(32) = 3.7, (1024) = 9.3. Na.A at 25°, A(32) = 65, (1024) = 76; M(32) = 66.3, (1024) = 87.0. - B.HClat25°, A(32) = 87, (1024) = 98; M(32) = 88.9, (1024) = 109.7.- B.2HC1; 948. Hofmann's Violet. (Triethyl-rosaniline). The dye is a mixture of salts of rosaniline and p-rosaniline bases. In HON, no cond.; 943. Effect of Rontgen rays on cond.; 416, 1476. Homatropine. C16H21O3N. kflXlO^ is over 1 (colorim.); 1778. Homo-hydroxy-benzaldehyde see Hydroxy-toluic aldehyde. Homo-hydroxy-benzoic acid see Hydroxy-toltiic acid. Homophthalamic acid see Homophthalic acid mono amide. 176 TABLES [Horn Homophthalic acid. C9H804=C6H4(C02H)(CH2C02H). [C02H=1; CH2C02H=2.] kAXlO* [at25°]=1.9. ju(256) = 74.5, (1024) = 132.6, («') = 376.5; 1684. Homo-o-phthalic acid 1-mono amide. (Benzene-1-carboxylic-acid- ainide-2-methylcarboxylic acid. Homophthalamic acid). C9H903N=C6H4(CONH2)(CH2C02H). [C0NH2=1.] kAXl05=5.0. m(512) = 55.6, (1024) = 75.7, (<») = 376; 1684. Homo-o-phthalic acid 2-mono amide. (Homophthalamic acid. Phenylacetamide-o-carboxylic acid) . C9H903N=C6H4(C02H)(CH2CONH2). [C02H=1.] kAXlO^=8.9; diminishes on diln. /i(256) = 52.7, (1024) = 93.7, (co) = 376; 1684. Homo-o-phthalic acid 1-mono ethyl ester, (a- ester). CuHl204= C6H4(C02Et) (CH2CO2H) . [C02Et= 1. ] kAXl06=4.6; diminishes on diln.; m. p. 111°-113°. ^(512) = 53.4, (1024)=71.9, (oo) = 374.6; 1684. Homo-o-phthalic acid 2-mono ethyl ester. (j3- ester). CiiHi204=C6H4(C02H)(CH2C02Et). [C02H= 1.] kAX 10^=7.1; diminishes on diln.; m. p. 107°. ai(256)=47.1, (1024) = 87.3, («>) = 374.6; 1684. Homo-o-phthalic acid 1-mono methyl ester, (a- ester). CioHio04= C6H4(C02Me) (CH2CO2H) . [C02Me= 1. ] kAXl05=4.34; m. p. 143°-145°; 1684; qual.; 1934. /i(512) = 51.9, (1024) = 71.2, (co) = 375.3; 1684. Homo-o-phthalic acid 2-mono methyl ester. (|8- ester). CioHio04=C6H4(C02H)(CH2C02Me). [C02H=1.] kAXl05=7.64; m. p. 96°-98°; 1684; qual.; 1934. /t(256)=48.9, (1024) = 90.7, (oo)=:375.3; 1684. Homo-salicyl aldehyde see Hydroxy-toluic aldehyde. Homo-salicylic acid see Hydroxy-toluic acid. Hydantoin. (2,4-Diketo-tetrahydro-imideazole). C3H4O2N2. kAXlQi" at 25°=7.59 (catal.); m. p. 216°-217°; 1996. At 25°, ;u(32) = 0.08, (256) = 0.12; 1748. Hydr- see also Dihydr- Hydracrylic acid. (/3-Hydroxy-propionic acid). C3H603=CH2(OH).CH2.C02H. kAXlQS at 25°=3; 1186, 1370. m(32) = 10.7, (1024) = 57.3, (00) = 358; 1186. Cond. with boric acid; 1186. Hydrastine. C21H21O6N. ksXlO' at 20° is about 1; (colorim.); 1779. Hyd] TABLES 177 Hydratropic acid. (a-Phenylpropionic acid). C9Hio02=Me.CHPh.C02H. kAXlO^ at 25°=4.25; increases on diln. A(64) = 17.8, (1024) = 66.6, (00 ) = 352; 1371. Hydraziacetic acid. C2H402N2=C02H.CH3N2. At 25°, A(32) = 73.0; dec. about 190°; 767. Hydrazine. N2H4=H2N.NH2. [The references to this are incom- plete. ] xXlO^ at 0°=3.4; b. p. 118.5°; 1828. At 25° = 4; 393. kfl XlO' at 25°= 3 aq.; diminishes on diln.; about 16% too high; 271. Cond.; 393; qual.; 1702. At 25°, A(32) = 1.9, (256) = 5.1, (oo) = 224; 271. Cond. as solvent; 393, 1828. B.HCl at 25°, A(32) = 111.5, (1024) = 125.0; 270. Hydrazoic acid. (Azoimide). HN3. [The references to this are incomplete. ] kAXlO^ at 0°=1.0; 733. At 25°=1.98; diminishes on diln.;= 1.86 (inversion); 1954; qual.; 419. At 25°, A(10) = 5.4, (1000)=46, (oo) = 385; 1954. Na.A at 25°, A(32) = 100.8, (1024) = 107.9; 1954. Hydro- see also Dihydro- Hydro metallo cyanic acids of the general type HiRx(CN)x, where R is a metal, should be looked for under the head of the metal. Those given in the tables, arranged by the metals, are: cadmium, chromium, cobalt, copper (cupri- and cupro-), iridium, iron (ferri- andferro-), manganese, mercury, molyb- denum, nickel, palladium, platinum, silver, zinc. The existence of some of these is denied, the so-called salts being regarded as mixtures or complexes of indefinite composition. Hydrochelidonic acid. (Acetone-diacetic acid). C7Hio05=CO(CH2CH2C02H)2. kiXlO^ at 25°=4.6 aq.; m. p. 143°. m(32) = 13.2, (512) = 50.0, (oo) = 352. Cond. with boric acid; 1186. Hydrochloric acid. HCl. [The references to this are incomplete.] Unit=R.O. v= (16) (32) (128) A at 0°=245.9 249.0 254.8 A at 15°=330.5 342.3 349.1 A at 25°=388.5 395.6 403.7 (Tower, Conductivity of Liquids.) Hydrocinnamic acid. (Benzylacetic acid). C9Hio02=PhCH2.CH2.C02H. (512) (1024) 256.4 256.5 349.3 349.3 403.7 403.7 178 TABLES [Hyd kAXlO' at 18°=2.5 (colorim.) ; 1563, 1781. At 25°=2.27; 1371, At 25°, A(64) = 13.2, (1024)=49.1, (oo) = 352; 1371. m-Hydrocoumaric acid. (m-Hydroxy-hydrocinnamic acid). C9Hio03=C6H4(CH2CH2C02H)(OH). Cond. alone and with NaOH in Et ale; 1508, 1718. p-Hydrocoumaric acid. C9H10O3. ki XlO^ at 25°= 1.75; diminishes on diln. A(128) = 16.3, (1024) = 43.4, (00) = 352; 1371. See Phloretic acid. Hydrocyanic acid. CHN^HCN and HN:C. xXlO^ at 0°=3.26; 1853c.=4.73; 943, 1843; 369.- 631. kAXlQi" at 10°=2.8 (catal.); 1177 and 1150. At 18°=4.7 (catal.); 1177 and 1160; - 1287. = 13; 1883, 1865. At 25°= 7.2 (catal.); 1177 and 1150. - 1043. At 40°= 15.7 (catal.); 1177 and 1150. Cond.; at 25°, A(25.9) = 2.4; 1984. - 1362. A(75) = 0.4; 770. - 1853c. In HCI; 1646. Cond. with HCl and NaOH; 1984. With NH3; 733. WithAgO; 510. As solvent; 369, 943, (1853c). Ba.2A; 1654. - Cd.2A, complex; 1485. - Cr, complex; 1487. - Cu.A in NH3, qual.; 606. - Au.2A in NH3; 610. - Hg.A; 246; complex; 246; 689. Hg.2A; 246, 841, 907, 1094, 1461. In NH3; 315, 607, 610. In NH3, qual.; 606. In MeNH2, fair cond.; 637. In organic solvents; 1106, 1107. With inorg. acids; 1097. With HgO; 246, 841. E. m. f.; 963. Complex; 149, 246, 604, 689, 786, 841, 1008, 1094. - K.A.; 907. In HBr and HCl, good cond. In HI and PH3, no cond.; 1646. In NH3; 610. In NH3, qual.; 606. In acetamide; 1894. In ale; 764, 1654. Cond. with organic compounds; 1654, 1746, 1747. Complex; 149, 604, 907, 1050, 1485.- Ag.A; 216. In HCN, little cond.; 943. In NH3; 604, 607, 610. In NH3, qual.; 606. In pyridine, little cond.; 1106.- Na.A; 1664.- Zn.2AinNH3; 610. In NH3, qual.; 606.- "Double" salts, and complex salts; 149, 246, 610, 604, 689, 785, 907, 971, 1008, 1050, 1094, 1434a, 1486, 1487, 1709, 1832. See also under the separate headings, as Ferricyanic acid etc., for the "double" salts. Hydrocyan-p-rosaniline. (p-Triamino-triphenyl acetic acid nitrile). C2oHi8N4= (HaN.CeHOsC.CN. The salt-forming base changes to a pseudo base. At 25°, /i(512) = 74.9 after 1 minute, = 11.9 after 60 minutes; 770. Base+3HC1, at 25°, ^(128) = 361.2, (1024) = 539.5; 1266. Hydroferricyanic acid see Ferricyanic acid. Hyd] TABLES 179 Hydroferrocyanic acid see Ferrocyanic acid. Hydronitroprussic acid. (Nitroprussic acid), C6H20N6Fe=H2Fe(CN)6NO. 2Na.Aat 25°, A(32) = 92.1, (1024) = 109.3; 1832. Hydroquinone. (1,4-Dihydroxy-benzene. Quinol). C6H602=C6H4(OH)2. kAXlOi''atO°=0.57 (hydro!.); 524. At25°=l.l (hydrol.); 624; = 200?; increases on diln.; 70. Cond.; 1718. At 25°, ju(23.2) = 0.3, (92.8) = 1.9, (oo) = 356; 70. In HBr, little cond., in H2S, no cond.; 1897. In NH3, qual.; 606. In MeNH2, good cond.; 637. Cond. with NH4OH; 733. With NaOH; 1508, 1718. With FeCls; 756. 2NH4.A. - 2Na.Aat25°, A(200) = 68.1, (400) = 69.5; 524. - Com- pound with FeCla; 756. Hydroshikimic acid. C7H12O5. kAXlO^ at 19°=3; m. p. 175° (uncor.). m(29.6) = 9.6, (59.2) = 13.2, (00) = 323.8; 541. Hydroshikimic acid dibromide see Dibromo-hydroshikimic acid. Hydrosorbic acid see /^T-Hexenoic acid. Hydroxy-amyl sulphonic acid, see iso-Amylisethionic acid. Hydroxy-azobenzene see Oxyazobenzene. o-Hydroxy-benzaldehyde. (Salicyl aldehyde). C7H602= C6H4(OH) (CHO) . xXlO' at 0°=1.0; b. p. 192°-193° @ 753 mm.; 1843;=2.3; 1844. At 25°= 1.64; 1843;=4.1; 1844; 1106, 1107. kAXl0« at 25° is under 10 (colorim.); 1397c;=15.7; 643. At 25°, A(32) = 7.8, (256) = 22, (od) = 356; 643. [The values of k and of A in 643 are probably too high. See the m- and p- isomers.] Also; 1508, 1718. Cond. with NaOH and HCI; 1508, 1718. As solvent; 1106, 1107, 1844. m-Hydroxy-benzaldehyde. C7H6O2. kAXlO^ at 25°=1.0 (cond.); is under 1.8 (colorim.); m. p. 104°; 1397c. At 25°, A(16)=0.17, (32)=0.20, (oo) = 380; 1397c. A(32)=3.8, (64) = 5.3, (oo) = 356; m. p. 104°; 643. Cond. with NaOH and HCI; 1508. p-Hydroxy-benzaldehyde. C7H6O2. kAXlO' at 25°= 2.2 (cond.); is under 8 (colorim.); 1397c. At 25°, A(32)=0.29, (128) = 0.63, (oo)=380; 1397c. A(64)=3.6, (512) = 10.3, (co) = 356; m. p. 116°; 643. Cond. with NaOH and HCI; 1508. 180 TABLES [Hyd o-Hydroxy-benzoic acid. (SalicyUc acid). C7H603=C6H4(OH)(C02H). kAXl05atO°=0.85aq.; 515;=0.83; 1968a. At 6.9°=9.3; 1968a. At 17°= 1.01 aq.; 164. At 18°= 1 (colorim.); 1781, 1563. At 20°= 1.04 aq.; 615. At 25°= 1.05; the extremes are 1.02 and 1.08 aq.; 473, 515, 1184, 1371, 1581, 1968, 1968a. (neutral.); 1718. At 30°= 1.09 aq.; 515. At 35°= 1.06; 1968a; 515. At 40°=1.12 aq.; 515; 1581. At 45°=1.13 aq.; 615. At 50°=1.14 aq.; 515, 1581. At 60°=1.11 aq. At 70°= 1.07 aq. At 80°= 1.01 aq. At 90°=0.95 aq. At 99°=0.87 aq.; 1681. Cond.; 168, 170, 388a, 515, 1968, 1968a. At 25°, /i(64) = 80.1, (1024) = 224.1, (co) = 357; 1371. In HBr and HCl; 30. In NHg, qual.; 606. In SO2, no cond.; 1842. In Et ale; 532, 647, 1316, 1649, 1718. In other organic solvents; 366,1589,1649; qual.; 934. Cond. with boric acid; 1184. With NaOH; 168, 1091, 1508, 1718. With KOH; 170. With NH4OH; 169. With ani- line; 145a, 169, 532. With allyl thiocarbimide, no cond.; 1223. NH4.A; 145a, 165, 823. Basic NH4 salt; 165.- Cu.2A, qual.; 1090. - Li.A in NH3, qual.; 606. In organic solvents; 474, 482, 1589. - K.A; 164, 165. Basic K salt; 164. - Ag.A; 848.- Na.A at 25°, A(32) = 68.3, (1024) = 79.7; 270, 1091, 1199. At 25°-99°; 1581. At 0°-50°; 515. At 0°-35°; 1968a. In NH3, qual.; 606. In organic solvents; 474, 647. With boric acid; 1199. - UO2.2A; 449. o-Hydroxy-benzoic acid amide. (Salicylamide). C7H702N= CeHiCOH) (CONH2) . Hgsalt, e. m. f.; 963. o-Hydroxy-benzoic acid methyl ester. C8H803=C6H4(OH)(C02Me). kAXlO" at 25°= 1 (hydrol.); 666, 1594. InNHs, qual.; 606. o-Hydroxy-benzoic acid phenyl ester. C13II10O3. In NH3, qual. ; 606. jso-o-Hydroxy-benzoic acid. (iso-Salicylic acid). C7H6O3. This acid, with IjaXIO^ at 25°= 1.1, was shown to be an impure salicylic acid; 473. m-Hydroxy-benzoic acid. C7H603= CsHiCOH) (CO2H) . In molten state, no cond. ; 1055. kAXlO^ at 0°=7.6 aq.; 515;=7.2; 1968a. At 13.2°=7.8; 1968a. At 17°=9.27 aq.; 164. At 18°=9.2 (colorim.); 1563. At 20°=8.29 aq.; 516. At 25°=8;=8.33 aq.; 515; = 7.60 aq.; m. p. 200°; 1186;=8.67; 1371; = 7.98; 1968a. At 30°=8.33 aq. At 35°=8.30 aq.; 515;=7.95; 1968a. At Hyd] TABLES 181 40''=8.26 aq. At 45°=8.20 aq. At 50°=8.11 aq.; dimin- ishes on diln.; 516. Cond.; 168, 170, 615, 1508, 1718, 1968a. At 25°, m(32) = 18.2 (1024) = 91.6, (oo) = 357; 1371. In NH3, qual.; 606. Cond. with boric acid; 1186. With NH4OH; 169. With KOH; 170. With NaOH; 168, 1091, 1508, 1718. With aniline; 169. NH4.A and basic NH4 salt; 166. - K.A; 164, 165. Basic K salt; 164.- Na.A at 25°, m(32) = 69.7, (512) = 78.6; 1091; 615. p-Hydroxy-benzoic acid. CrHeOs = CsHiCOH) (CO2H) . kAXlO^at 0°=2.51. At 13.2°=2.71; 1968a. At 17°= 2.88 aq.; 164. At 18°=3.3 (colorim.); 1563; - 1781. At 25°=2.86; 1371, 1968a; = 2.8; 1091;=2.68 aq.; m. p. 213°; 1186. At 35°=2.87; 1968a. Cond. ; 168, 170, 1508, 1718, 1968a. At 25°, ^(32) = 10.6, (1024) = 56.3, (00) = 357; 1371. InHCl;30. In HBr, no cond.; 30. In NH3, qual. ; 606. Cond. with boric acid; 1186. With NH4OH; 169. With KOH; 170. With NaOH; 168, 1091, 1508, 1718. With aniline; 169. NH4.A and basic NH4 salt; 165. - K.A; 164, 165. Basic K salt; 164.- Na.A at 25°, A(32) = 68.8, (512) = 77.0; 1091. - Cinchonine. A; 1620. Hydroxybenzyl hypophosphoric acid. C7H903P=Ph.CHOH.POH.OH. Relative cond.; (the aniline salt has m. p. 99°); 1771. 2-Hydroxy-3-bromo-a-naphthoquinone. CioH603Br= OH.CioH402Br. K.A at 25°, A(32) = 75.8, (1024) = 82.1; 1275. Hydroxy-butenoic acid see Ethenylglycollic acid. a-Hydroxy-butyric acid. C4H803=Et.CH0H.C02H. At25°, Ai(32) = 16.9, (1024) = 70.8, [in Hg.U.]; 1362. ;8-Hydroxy-butyric acid. C4H803=Me.CH0H.CH2.C02H. kAXl05=3.1; 1640; = 2 (colorim.); 804. A(32) = 11.2, (1024) = 58.4, (oo) = 358.7; 1640. In Et ale, cond. alone and with boric acid; 1185. Na.A, A(32) = 69.4, (1024) = 82.9; 1640. 7-Hydroxy-butyric acid. C4H803=CH20H.CH2.CH2.C02H. kAXlO==1.93. Ai(79.8) = 13.8, (319.0) = 27.3, (oo) = 358; 812. Hydroxy-iso-butyric acid. C4H803=Me2.C(OH).C02H. kAXlO* at 25°=1.06; 1370, 1186; (colorim.); 1643. At 25°, m(32) = 20.1, (1024) = 99.5, (oo)=355; 1370. In NH3, qual.; 606. Cond. with boric acid; 1186; qual.; 1184. Na.A at 25°, m(32) = 67.7, (1024) = 79.4; 1367. 182 TABLES [Hyd a-Hydrozy-camphoronic acid see Camphoranic acid. jS-Hydroxy-camphoronic acid. C9Hi407=C6Hio(OH)(C02H)3. kAXlC at 25° =6.5; diminishes, then increases on diln.; 1372. Second kAX 10'= 8.4 (inversion); 1638; = 21; 1911. At 25°, m(64) = 166.4, (1024) = 316.8, (°o) = 352; 1372. 2-Hydroxy-5-chlorobenzoic acid. (5-Cliloro-salicylic acid). C7H603C1=C1.C6H3(0H)(C02H). [C02H=1.] kAXlC at 25°=1.97; increases on diln.; m. p. 172°. /[i(320) = 191.5, (1280) = 274, (co)=356; 404. 3-Hydroxy-2-chIorobenzoic acid. C7H6O3CI. kAXlO' at 25°= 1.40; increases on diln.; m. p. 156°-157°. m(256) = 158.3, (1024) = 242.8, (oo)=356; 404. 3-Hydroxy-6-chlorobenzoic acid. C7H6O3CI. kAXlO' at 25°=1.40; increases on diln.; m. p. 178°. Ai(64) = 91.8, (1024) = 240.3, (oo)=356; 404. 4-Hydroxy-3-chlorobenzoic acid. C7H6O3CI. kAXlO^ at 25°=5.7; increases on diln.; m. p. 169°-170°. m(128) = 29.1, (1024) = 77.6, (co)=356; 404. 3-Hydroxy-2-chloro-6-bromobenzoic acid. C7H403ClBr= (CI) (Br)C6H2(OH) (CO2H). [C02H= 1. ] kiXlO'^ at 25°=2.4; diminishes on diln.; m. p. 116°-118°. m(139.4) = 286.0, (1115.2) =343.9, (co)=355; 404. 3-Hydroxy-6-chloro-2-bromobenzoic acid. C7H403ClBr. kAXlC at 25°=2; m. p. 194°-195°. ^1(128) = 139.5, (1024) = 256.4, (00) = 355; 404. a-Hydroxy-zso-cinchomeronic acid. (6-Hydroxy-pyridine-2,5-dicar- boxyUc acid). C7H506N=C6H2N.(OH)(C02H)2. kAXlO^ at 25°= 1.67; diminishes on diln.; 1372. Second kAXl0«=2 (cond.); 1911. At 25°, m(128) = 264, (1024) = 337, (oo) = 355; 1372. Hydroxy-cinnamic acid see Coumaric acid. Hydroxy-dehydroacetic acid. CgHgOs. kAXl0^=1.59; diminishes on diln.; m. p. 253°-255° with dec. /i(512) =210.1, (1024)=245.8, (oo) = 360; 558. Cond. increased by boric acid; 1186. Na.A, m(32) = 63.4, (1024) = 74.3; 658. 4-Hydroxy-3,5-dibromo-azobenzene. (Benzeneazodibromo-phenol.) Ci2H80N2Br2=Ph.N2.C6H2Br2(OH). In pyridine; 754. 4-Hydroxy-3,5-dibromo-benzoic acid. C7H403Br2=OH.C6H2Br2.C02H. [C02H=1.] In Et ale, cond. alone, and with boric acid; m. p. 267°-268°; 1185. Hyd] TABLES 183 2-Hydroxy-3,5-dichloro-benzoic acid. (3,5-Dichloro-salicylic acid). C7H403Cl2=OH.C6H2Cl2.C02H. [C02H=1.] kAXlO^ at 25°=4.65; diminishes on diln.; m. p. 219.5°. /i(630) = 279.7, (1260) = 308.9, (oo) = 355; 404. 3-Hydroxy-2,6-dichloro-benzoic acid. C7H4O3CI2. kiXlO^ at 25°=2.26; m. p. 122°-124°. m(128) = 279.4, (1024) = 342.7, (co) = 355; 404. m-Hydroxy-dimethyl-aniline see m-Dimethyl-aminoplienol. Hydroxyethyl sulphonic acid see Isethionic acid. Hydroxy-fumaric acid. C4H405= C02H.C(0H) : CH.CO2H. kAXlO' at 17°=2.76; m. p. 184°. m(20) = 70.4, (320) = 201.1, (oo) = 337.i; 1992. a-Hydroxy-glutaric acid. C6H806=C02H.(CH2)2.CHOH.C02H. Co salt.- Mg.A at 18°, ai(32) = 93.7, (T024) = 156.3. - Ni salt; 1736. m-Hydroxy-liydrocinnainic acid see m-Hydrocoumaric acid. Hydroxy-hydroquinone. (1,2,4-Trihydroxy-benzene). C6H603= C6H3(OH)3. Cond. alone and with NaOH; m. p. 140°; 1508, 1718. Hydroxy-hydroqiunone aldehyde. (2,4,5-Trihydroxy-benzaldehyde). C7H604=(OH)3C6H2.CHO. [CH0=1.] kiXlO^at 25°=1.8. At 25°, ii{128) = lQ.7, (1024)=45.2, (oo) = 355; 643. Hydroxylamine. H30N=NH20H. [The references to this are incomplete. ] xXlO^ at 33° is approximately 8; [in molten state]; 1176. ksXlO' at 15°=6.5 (colorim.); 1775. At 25°=7.4 (hydrol.); 1984. Cond. at v(14.2), is no greater than that of pure water; 1984. At 18°, m(20) = 0.4, (500) = 1.4; 1176; A(500) = 19; 1531. Cond. with NaOH; 1984. B.HCl at 25°, At(32) = 105, (1024) = 116; M(32) = 107; 1984; 270, 599, 1531, 2029. In NH3, qual.; 606. In Me ale; 2029. - B.HNO3; 1531. - B.H3PO4. - B.H2SO4; 599, 1531. Hydroxy-maleic acid. C4H405=C02H.C(OH):CH.C02H. kiXlO^ at 17°=2.5; m. p. 152°. ;it(20) = 68.5, (320) = 193.3, (co) = 337.1; 1992. Hydroxy-maleic acid anhydride. C4II2O4. Pyridine salt, in pyridine; 1991. Hydroxy-malonic acid see Tartronic acid. Hydroxy-mesitene-dicarboxylic acid anhydride see iso-Dehydroacetic acid. Hydroxy-methane sulphonic acid. (Hydroxy-methyl- etc.) CH404S=OH.CH2.S03H. 184< TABLES [Hyd kA XlO* is about 4; the acid is 97% dissociated at v(256); 394. KA at 25°, A(32) = 184.0, (1024) = 243.1; 643. A(1024-32) of the salts shows that the acid is monobasic; 394. 2-Hydroxy-3-methoxy-benzoic acid see Guaiacolcarboxylic acid. 4-Hydroxy-3-methoxy-benzoic acid see Vanillic acid. 3-Hydroxy-4-methoxy-beiizoic acid see iso-Vanillic acid. o-Hydroxymethyl-benzoic acid. (Benzylalcohol-o-carboxylic acid). CsHsOa = CeHiCCOsH) (CH2OH) . IsaXIO* at 25°= 1.51; diminishes on diln. M. p. 120°. m(50) = 29.4, (1600) = 123, (co) = 353; 395, 827. Hydroxymethylene-acetoacetic acid ethyl ester. C7Hio04=MeCO.C(:CHOH).C02Et. kxXlO^ at 3.7°=3. At 23.5°=3; increases on diln. from dec; b. p. 200° @ 750 mm. At 3.7°, m(64.1) = 8.7, (512.8) = 23.8, (co) = 202.6. At 23.5°, m(33.3) = 10.3, (266) = 32; 387. Hydroxymethylene-acetylacetone . C6H803= MeCO.C( :CHOH).COMe. kA XlO^ at 2.6°= 2.2; m. p. 47°-48°. m(32) = 5.1, (256) = 14.2, (co) = 195; 387. Hydroxymethylene-malonic acid diethyl ester. C8Hi20B=C02Et.C(:CHOH).C02Et. kA is greater than that of acetic acid; b. p. 217°-219°; 387. a-Hydroxy-naphthoic acid. GiiH803= CioH6(OH) (CO2H) . Cond. increased by boric acid; 1185. 2-Hydroxy-l,4-naphthoquinone. (Naphthalic acid). CloH603=OH.CloH602. Na.A at 25°, A(32) is about 71, (1024) is about 76; 1275. a-Hydroxy-nicotinic acid. (2-Hydroxy-pyridine-3-carboxylic acid. ' a-Hydroxy-picoIinic acid?). CeHsOsN. kAXl0« at 25°= 5.7; diminishes on diln. m(128) = 9.6, (1024) = 25.1, (co) = 357; 1372. o-Hydroxyphenyl-acetic acid. C8H803=OH.C6H4.CH2.C02H. Cond. in Et ale, alone and with NaOH; m. p. 137°; 1508, 1718. p-Hydroxyphenyl-acetic acid. C8H8O3. Cond. alone and with NaOH; m. p. 148°; 1508, 1718. p-Hydroxyphenyl-a-aminopropionic acid. (Tyrosine). C9Hii03N=OH.C6H4.CH2.CH(NH2).C02H. kAXlO« at 25° =4 (hydrol.);=67 (cond.). Second kAXl0i«=4 (hydroL). kB XlO''' at 25°=2.6 (hydrol.) At 25°, m(512) = 0.5, (1024) = 3, (co) = 365; 947. Hyd] TABLES 185 In NHs, qual.; 606. Na.A at 25°, M(64) = 68.3, (1024) = 82.2; m(64) = 66.5. - 2Na.A, M(128) = 166.4, (1024) = 196.7; m(128) = 160. - B.HCl at 25°, M(256) = 288.4, (1024) = 351.3; /i(256) = 110; 947. Hydroxy-phenyl-propionic acid see Phenyl-hydroxy-propionic acid. Hydroxy-phenyltrimethyl ammonium hydroxide see Trimethyl- aminophenol. o-Hydroxy-phenyl urethane. C9Hii03N=HO.C6H4NH.C02Et. K of satd. soln. at 25°=5.2 XlQ-^ With HCl, no change of cond.; 1660. * 4-Hydroxy-o-phthalic acid. ' C8H60s=OH.C6H3(C02H)2. [C02H=1, 2; 0H=4.] kAXlO' at 25°= 1.2; probably contained a trace of iron; m. p. 181°. [Bentley, Weizmann, Jour. Chem. Soc. 91, 99, (1907), say that the true m. p. is 204°-205°; the acid m. p. 181° contains some 3-Hydroxy-phthalic acid.] m(32.1) = 67.9, (1033) = 246.8, (oo) = 377; 1909. 4-Hydroxy-o-phthalic acid 1-mono methyl ester. CgHgOs. [C02H=2; C02Me=l; 0H=4.] kAXlO^ [at 25°]=1.54; m. p. 159°-160°; 1932. 4-Hydroxy-o-phthalic acid 2-mono methyl ester. CsHsOs. [C02H=1; C02Me=2.] kxXlO^ at 25°=2.05; m. p. 166°. /i(63.7) = 40.6, (1024) = 136.7, (o=) = 375; 1909. 4-HydrOxy-o-phthalic acid dimethyl ester. CioHio06= OH.C6H3(C02Me)2. kAXlO' at 25°=1 aq. m(127.4) = 1.5, (1022) = 3.1, (oo) = 374; 1909. 2-Hydroxy-p-phthalic acid. (2-Hydroxy-terephthalic acid). CgHeOs. [C02H=1, 4; 0H=2.] kiXlO' at 25°=2.7; increases on diln.; 1372, 1909. Second kAX 10^= 2.1 (inversion); 1638;=4.5 (cond.); 1911. At 25°, m(256) = 198.5, (1024) = 290.5, (oo) = 355; 1372. 2-Hydroxy-p-phthalic acid 1-mono methyl ester, (a- ester). CsHgOs. [C02H=4; C02Me=l; 0H=2.] kAXlO* at 25°=2.50; m. p. 206°-208°. m(910) = 141.3, (1820) = 181.8, (oo)=375; 1909. 2-Hydroxy-p-phthalic acid 4-mono methyl ester. (/S- ester.) CgHsOs. [C02Me=4.] kAXlO'at25°=2.77; m. p. 175°-176.5°. m(255.7) = 209.0, (1026) = 294.9, (oo) = 375; 1909. o-Hydroxy-picolinic acid see a-Hydroxy-nicotinic acid. /S-Hydroxy-picolinic acid see Comanamic acid. 186 TABLES [Hyd Hydroxy-pimelic acid anhydride. C7Hio04=C6H902.C02H. [A lac- tone acid of pimelic acid.] kAXlO^ at 25°=2.76; diminishes on diln.; m. p. 82.5°. Ai(32) = 11.0, (1024) = 57.4, (oo) = 376; 1975. Hydroxy-pivalic acid. (Hydroxy- trimethyl-acetic acid). C5Hio03=Me2.C(CH2.0H)C02H. kAXlO^ at 25°= 1.39; m. p. 124°. m(32) = 7.8, (1024) = 42, (oo) = 376.4; 1215. a-Hydroxy-propionic acid see Lactic acid. /3-Hydroxy-propiomc acid see Hydracrylic acid. 4-Hydroxy-pyridine-2,6-dicarboxylic acid see Ammonchelidonic acid. 6-Hydroxy-pyridine-2,5-dicarboxylic acid see a-Hydroxy-iso-cin- chomeronic acid. 2-Hydroxy-quinoUne see Carbostyril. p-Hydroxy-quinoline-o-carboxylic acid. C10H7O3N. Cond. increased by boric acid; m. p. 260°-262° with dec; 1186. Hydroxy-salicylic acid see Dihydroxy-benzoic acid. 2-Hydroxy-5-siilphobenzoic acid see B-Sulphosalicylic acid. 3-Hydroxy-o-tolmc acid. (m-Homo-salicylic acid). C8H803=Me.C6H3(OH)(C02H). [Me=l; C02H=2; 0H=3.] kAXlO^=1.06; 1670. A(1194.0) = 234.5; 1672. 6-Hydroxy-o-toluic acid. (|3-o-Homo-m-hydroxy-benzoic acid). CsHsOs. [Me=l; C02H=2; 0H=6.] kAXlO* at 25°=1.69; diminishes on diln.; m. p. 183°. iu(256) = 66.5, (1024) = 118.7, (oo) = 355; 1429. 2-Hydroxy-m-toluic acid. (^- or o-Cresotinic acid. o-Homo-sali- cylicacid). CgHgOa. [Me=l; C02H=3; 0H=2.] kAXlO' at 18°= 1.15 (colorim.); 1563. At 25°= 1.03; diminishes on diln.; 1186, 1429, 1670. = 0.98 aq.; 1186. = 1.06; 1429. At 25°, Ai(512) = 178, (1024) = 218, (oo)=354; 1186. InEt ale; 1185. Cond. with boric acid; m. p. 166°-167°; 1185, 1186. 4-Hydroxy-m-toluic acid, (a- or p-Cresotinic acid. p-Homo-sali- cylicacid). CgHgOs. [Me=l; C02H=3.] kAXlO* at 18°= 11 (colorim.); 1563. At 25°=8.9; diminishes on diln.; m. p. 151°; 1186, 1429, 1670. At25°, m(512) = 172, (1024) = 212, (o=) = 354; 1186. InEt ale; 1185, 1508. Cond. with boric acid; 1185, 1186. With NaOH; 1508. 3-Hydroxy-p-toluic acid. (7- or m-Cresotinic acid. m-Homo-sali- cylicacid). C8H8O3. [Me=l; C02H=4.] kAXlO* at 18°=6.5 (colorim.); 1563. At 25°=7.5; diminishes on diln.; m. p. 177°; 1186, 1429; = 6.8; 1670. At25°,M(512) = 162, (1024) = 202, (c») = 354; 1186. Hyd] TABLES 187 InEt ale; 1185. Cond. with boric acid; 1185, 1186. 6-Hydroxy-o-toluic aldehyde. (m-Homo-p-hydroxy-benzaldehyde). C8H802=Me.C6H3(OH).CHO. [Me=l; CH0=2; 0H=5.] kAXlO«at 25°=2.95; m. p. 110°. m(128) = 6.8, (1024) = 18.8, (co) = 354; 643. 2-Hydroxy-m-toluic aldehyde. (o-Homo-salicyl aldehyde). CsHgOz. [Me=l; CH0=3; 0H=2.] kAXlO^ at 25°= 1.52; b. p. 208°. m(128) = 15.2, (1024)=41.5, (oo) = 354; 643. 4-Hydroxy-m-toluic aldehyde. (p-Homo-salicyl aldehyde). CgHsOa. [Me=l; CH0 = 3; 0H=4.] kAXlO^ at 25°=2.17; m. p. 56°. Ai(256) = 25.4, (1024) = 49.3, (co) = 354; 643. 6-Hydroxy-m-toluic aldehyde. (o-Homo-p-hydroxy-benzaldehyde). CsHsOa. [Me=l; CH0=3; 0H=6.] kAXlO« at 25°=4.66; m. p. 118°. M(128) = 8.5, (1024) = 23.6, (oo) = 354; 643. 3-Hydroxy-p-toluic aldehyde. (m-Homo-salicyl aldehyde). CsHsOa. [Me=l; CH0=4; 0H=3.] kAXlO^ at 25°=7.62; b. p. 220°. m(256) = 15.3, (1024) = 29.9, (co) = 354; 543. Hydroxy-triazolinacetic acid see Methyl-hydroxy-triazole carboxylic acid. 4-Hydroxy-2 ',4 ',6 '-tribromo-azobenzene. (Tribromo-benzene-azo- phenol). Ci2H70N2Br3=Br3C6H2.N2.C6H4.0H. In pyridine; 754, Hydroxy-trimethyl-acetic acid see Hydroxy-pivalic acid. Hydroxy-trimethyl-phenyl ammonium hydroxide see m-Trimethyl- aminophenol. a-Hydroxy-a|8|S-trimethyl-propioiiic acid. C6Hi203=Me2CH.CMe(OH).C02H. kAXlO*=1.14; m. p. 75°-77°; 1411. /3-Hydroxy-a(3/3-trimethyl-propionic acid. (tertiary-TTimethyl-ethyl- enelactic acid). C6Hi203 = Me2C(OH).CHMe.C02H. kAXlO^ at 25°=3.5; diminishes on diln.; b. p. 160° @ 35 mm.; 640, 1411, 1704. Ai(39.5) = 13, (632) = 47, (co) = 351; 1704. Hydroxy-trimethyl-succinic acid. C7Hi206= C02H.C(OH)Me.CMe2.C02H. kAXlO* at 25° = 9; [the values 8.46 in 64, and 9.38 in 229, differ because of the use of different values of /i(oo)]; m. p. 151°, 153°, 159° depends on mode of heating; 64, 229, 1418. 188 TABLES [Hyd iu(28) = 52.3, (112) = 97.1, (co) = 351; 229. m(1112.5) = 214.7, («>) =353; 64. Hydroxy-uracil see Oxyuracil. a-Hydroxy-valeric acid. C6Hio03=Me.(CH2)2.CHOH.C02H. kAXlO*at25''=1.32aq. M(e4) = 30.7, (512) = 79.8, (oo) = 350. Cond. with boric acid; 1186. 7-Hydroxy-valeric acid. C6Hio03=Me.CHOH.(CH2)2.C02H. kAXlO^=2.07; diminishes on diln. m(36.4) = 9.7, (1163.2) = 50.4, (od)=358; 812. Hyoscyamine. (1-Tropic acid tropine ester). C17H23O3N. At 25°, m(100) = 18.1, (800) = 38.6; 1864. [Hyoscyamine is partly decomposed by aq., therefore the cond. may be due to tropic acid]. I. Imido see Imino. Iminobenzoic acid iso-amyl ester. (Benzimino amyl ether). Ci2Hi70N=Ph.C(NH)O.C6Hu. ksXlO* at 25°= 1.7 (hydrol.); 1233, 1657. B.HCl at 25°, A(32) = 86.7, (256) = 95.3; M(32) = 88.5; 1233. Iminobenzoic acid fso-butyl ester. CiiHi60N=Ph.C(NH)0.iso-Bu. ksXlO* at 25°=1.25 (hydrol.); 1233, 1657. B.HCl at 25°, A(32) = 85.8, (256) = 95.8; M(32) = 87.7; 1233. Iminobenzoic acid ethyl ester. (Benzimino ethyl ether) . C9HiiON=Ph.C(NH)O.Et. kflXlO' at 25°=1.1 (hydrol.); b. p. 115° @ 21.5 mm.; 439, 1657. B.HCl at 0°; 1590. At 25°, A(32) = 83.4, (256) = 92.4; M(32) = 85.1; 439. Iminobenzoic acid methyl ester. C8H90N=Ph.C(NH)O.Me. ks XlO' at 25°=4.7 (hydrol.); b. p. 104° @ 20.5 mm.; 439, 1657. B.HCl at 0°; 1590. At 25°, A(32) = 86.5, (256) = 94.5; M(32) = 89.7; 439. Iminobenzoic acid norm.-propyl ester. CioHi30N=Ph.C(NH)O.Pr. ksXlO^ at 25°= 1.54 (hydrol.); b. p. 121° @ 16 mm. B.HCl at 25°, A(32) = 82.4, (256) = 91.1; M(32) = 83.6; 439. Iminobenzoic acid iso-propyl ester. C10H13ON. kfl X108 at 25°=1.8 (hydrol.); b. p. 114° @ 20 mm. B.HCl at 25°, A(32) = 82.0, (256) = 90.1; M(32) = 83.9; 439. Iminomethyl- see Methylimino- Imino-|3-naphthoic acid ethyl ester. Ci3Hi30N=CioH7.C(NH)O.Et. ksXlO^ at 25°=7.9 (hydrol.); 1233, 1657. B.HCl at 25°, A(32) = 87.8, (256) = 96.6; M(32) = 90.0; 1233. lod] TABLES 189 Imino-m-nitrobenzoic acid ethyl ester. C9Hio03N2=N02.C6H4.C(NH)O.Et. kfiXlO^ at 25° = 1 (hydro!.); 1233, 1657. B.HCl at 25°, A(32) = 88.1, (256) = 96.9; M(32) = 94.1; 1233. Imino-m-nitrobenzoic acid methyl ester. C8H803N2=N02.C6H4.C(NH)O.Me. kflXlOio at 18°=3.7 (hydro!.); m. p. 50.6°. B.HC! at 18°, A(32) = 73.8, (256) = 80.8; M(32) = 79.3; 439. Imino-phenylacetic acid ethyl ester. C10H13ON. ksXlO' at 25°=4 (hydro!.). B.HCl at 25°, A(32) = 85.6, (128) = 93.2; M(32)=90.1; 1233. Imino-o-toluic acid methyl ester. C9H11ON. kB XlO' at 25°= 2.3 (hydro!.). B.HC! at 25°, A(32) = 94.8, (256) = 103.3; M(32) = 99.0; 1233. Imino-p-toluic acid ethyl ester. CioHi30N=Me.C6H4.C(NH)O.Et. ksXlO' at 25°=1.97 (hydro!.); 1233, 1657. B.HCl at 25°, A(32) = 88.0, (256) = 95.2; M(32) = 89.1; 1233. Indenone see Indone. [Derivatives given in 1665. ] Indigo. In MeNH2, good cond.; 637. Indigo White. Ci6Hi202N2=OH.Ci6HioN2.0H. Mono Na salt at 18°, m(19.4) = 62.6, (37.9) = 67.7; 976c. Measurement of an impure salt; 976b. Pr-2-(a)-Indolecarboxylic acid. C9H7O2N. kiXlO* at 25°= 1.77 aq.; m. p. 204°. A(173.2) = 56.4, (1385.6) = 136.1, (°o) = 352; 23. Pr-3-(j3)-Indolecarboxylic acid. C9H7O2N. kAXlO^ at 25°=5.6 aq.; diminishes on diln.; m. p. 218°. A(700) = 21.5, (1400) = 29.3, (oo) = 352; 23. Indophenosafranine see sym.-Phenosafranine. Indozylic acid ethyl ester. C11H11O3N. In pyridine, almost no cond. ; 754. Inosinic acid. C10H13O8N4P. kAXlO^ at 25°=1; diminishes on diln. /i(32) = 161, (1024) = 243.6, (00) = 373. 2Na.A at 25°, A(32) = 66.8, (1024) = 87.7; 708. Intestinal juice. [The references to this are incomplete. ] Concentration of H and OH ions; 587. Invertin. Concentration of H ions; 1639b. led- see lodo. lodoacetic acid. C2H302l=CH2l.C02H. kA XlO* at 25° =7.1; m. p. 82°. 190 TABLES [lod A(32) = 50.6, (1024) = 207, (<») = 362; 1840. In acetone; 475. lodoacetic acid ethyl ester. C4H702l=CH2l.C02Et. In SO2, little cond.; b. p. 178°-180°; 1829, 1842. lodobenzene. CeHsI. In SO2, no cond.; 1829, 1842. In NH3, qua!.; 606. o-Iodobenzoic acid. C7H602l=I.C6H4.C02H. kiXlO' at 25°=1.32;.m. p. 226°; 53, 1581. At 40''=1.1 aq. At 50°=0.93 aq. At 60° = 0.78 aq. At 70° = 0.68 aq. At 80°=0.58aq. At 90°= 0.49 aq. At 99° = 0.42 aq.; 1581. [At 25°,] A(169) = 134, (1352) = 254, (cc,)=[356]; 53. K.A; 1728. - Na.A at 25°, A(64) = 64.2, (128) = 67.4; 1728; A(1024) = 75.0; 1581. m-Iodobenzoic acid. C7H6O2I. kiXlO^ at 25°=1.63; diminishes on diln.; 175. At 60°=1.25 aq. At 70°= 1.2 aq. At 80°= 1.1 aq. At 90°= 1.0 aq. At 99°= 0.94 aq.; 1581. At 25°, A(1357) = 132.5, (2714) = 166.8, (c») = 356; 175. p-Iodobenzoic acid. C7H6O2I. Cs.A.- K.A. - Na.A at 25°, A(64) = 66.0, (128) = 67.4. - Rb.A; 1728. 7-Iodobutyric acid. C4H702l=CH2l.(CH2)2.C02H. kAXlO^ at 25°=2.3; m. p. 40°-41°; 1099 and 1908. A(32) = 10.2, (64) = 14, (co) = 356; 1099. Iodoform see Triiodo-methane. lodomethyl-triethyl ammonium chloride. C7Hi7NClI= (CH2l)(Et3)N.Cl. At 25°, A(32) = 86.1, (1024) = 98.6; 270. lodomethyl-trimethyl ammonium chloride. C4HiiNClI=(CH2l)(Me3)N.Cl. At 25°, A(32) = 92.6, (1024) = 105.2; 270. |3-Iodopropionic acid. C3H602l = CH2l.CH2.C02H. kAXlO^ at 25°=9; aq. used for soln. was not pure; 1370. A(32) = 18.6, (1024)=-90.7, (co) = 358; 1370. InSOz; 1842. Na.A at 25°, A(32) = 66.9, (1024) = 78.6; 270. lodosobenzene. C6H60I=Ph.IO. InNHs, qual.; 606. o-Iodosobenzoic acid. C7H603l=C6H4(IO).C02H. kAXlO' [at 25°] = 6; m. p. 226° to244°; varies with mode of heating. A(224)=4.4, (896) = 8.2, («)=[356]; 53. 4-Iodo-2-toluidine-5-sulphonic acid. C7H803NIS = Me.C6H2(NH2)(I).S03H. [Me=l; NH2=2.] Ita] TABLES 191 kiXlO* at 25° is about 5; decomposes during measurement. m(256) = 123.5, (1024) = 144.3, (oo)=[355]; 492. 5-Iodovaleric acid. C6H902l=CH2l.(CH2)3.C02H; kAXlO^ at 25°=1.7; m. p. 56°-57°; 1099 and 1908. A(64) = 12.3, extrapolated, (00) = 354; 1099. lodoxybenzene. C6H6O2I. InNHs, qual.; 606. Iridium cyanic acid. C6H3N6lr=H3lr(CNj6. 3Ba.2A. - 3Cu6NH3.2A. - 3K.A at 25°, A(32) = 136.0, (1024) = 173.3; 1494. Iron see Diferri-pentaacetyl-hydroxide, Ferricyanic acid, Ferri- diacetyl bromide, Ferri-diacetyl chloride, Ferri-oxalic acid, Ferrocyanic acid, Ferro-oxalic acid, Hydronitroprussic acid, Oxyhaemoglobin. Isatin see o-Aminobenzoyl-fonnic acid anhydride. Isatinic acid see o-Aminobenzoyl-formic acid. Isatoic acid see o-Aminobenzoyl-formic acid. Isatoxime. (Nitroso-oxindole) . C8H6O2N2. kiXlO* at 25° = 2.8 (catal.); = 0.02 (cond.); m. p. 202°. m(480) = 0.1, (960) = 0.2, (oo) = 351; 752. Isethionic acid. (Hydroxyethyl sulphonic acid). C2H604S=OH.CH2.CH2.S03H. kAXlO^ is approximately 4; the acid is 97% dissociated at v(256); A(1024-32) of the salts, shows that the acid is monobasic; 394. Iso see under letter beginning the next word; e. g. fso-Amyl is given under Amyl. Itaconic acid. C6H604=C02H.CH2.C(:CH2).C02H. kAXlO* diminishes on diln. at all temperatures above 17°. At 0°=1.24; 1968a. At 17°= 1.44 aq; 164. At 18°= 1.6 (colorim.); 1563, 1781. At 18.1°= 1.45; 1968a. At 25°= 1.51; m. p. 161°; 1638, 1968a; = 1.21; 1372, 1500b. At 35°= 1.55; 1968a. Second kAXlO^=2.2 (part, and inversion); 370, 1638. Cond.; 170. At 0°-35°; 1968a. At 25°, m(32) = 23.7, (1024) = 113.3, (00)= [351]; 1968a. ju(44.4) = 25.2, (oo) = 355; 1372. Cond. with KOH; 170. Mg.A; 1836.- Na.A; 370.- 2Na.A at 25°, A(32) = 80.7, (1024) = 97.0; 270, 370. Itaconic acid anhydride. C5H4O3. Cond. showing change to acid; 1500b. 192 TABLES [Ket K. Ketofluorene see Fluorenone. Ketoindene see Indone. [Derivatives given in 1665. ] Ketoxime-acetic-carboxylic acid see Oximinosuccinic acid. Kidney. [The references to this are incomplete. ] Cond.; 156a, 623 and 253. Kinase. [The references to this are incomplete. ] Cond. of gelatin soln. containing kinase; 807, 808. Laccase. [The references to this are incomplete. ] K at 17° of 0.9865 g in 50 cc. aq. = 4.485 XlO-'; 525. Lactic acid. (a-Hydroxy-propionic acid). C3H603=Me.CH(OH).C02H. kiXlO^ at 25° = 1.4; 1370, 1184; = 3.1; 657, and Ostwald, Zeit. Phys. Chem. 32, 163, (1900), for a commercial preparation. Relative strength (colorim. etc.) ; 693, 1643, 1781. Cond.; 320a, 542, 1635, 1495. At 25°, a'(32) = 23.1, (1024) = 109.7, (oo) = 358; 1370. In HBr, no cond.; 30. In NH3, qual.; 606. Cond. with boric acid; 1184. With GIO; 320a. With M0O3; 1495. With acetone; 1669. Under pressure of 1-260 at- mospheres; 542. Ca.2A; 1199. - Fe.2A in NH3, qual.; 606. - K.A; 1367. - Na.A at 25°, m(32) = 69.6, (1024) = 79.8; 1368a, 1367. Under pressure of 1-260 atmospheres; 542. - UO2.2A; 449. - Zn.2A in NH3, qual. ; 606. Lactic acid cyanoamide. (Lactocyanoamide). C4H602N2=Me.CH(OH).CO.NH(CN). kAXlO' at 25°=3; diminishes on diln. ; decomposed? m(33.1) = 1.1, (264.8) = 2.2, (cx>) = 355; 70. Lactic acid ethyl ester. C6H10O3. InNH3, qual.; 606. Lactic acid nitrile. (Lactonitrile). C3H60N=Me.CH(OH)(CN). xXlO^ at -68°=0.5. At -52°=1.4. At -15°=12; 1853a. At 0° = 0.18; 1844; = 24; 1853a. At 25°=0.311; b. p. 83.9° @ 12-20 mm.; 1844, 1843; = 44; 1853a. Cond. as solvent of NEtJ; 1844, 1853a. Lactocyanoamide see Lactic acid amide. Lactonitrile see Lactic acid nitrile. Lun] TABLES 193 Lactose. C]2H220u. n at 25° of 4.275 g (anhydrous) in 100 cc. aq. = 0.2218; 1747; 322. In NH3, qual.; 606. Cond. with organic and inorg. compounds; 1747. Laevulinic acid. (/3-Acetopropionic acid). C6H803=MeCO.CH2.CH2.C02H. kAXlO^ at 0° = 2.11; 701. At 25°=2.7; b. p. 150°-155° @ 10 mm.; 202; = 2.55; 1370; = 2.4; 701, 1186. At 35.5°=2.29; 701. Cond.; 701, 782. At 25°, A(32) = 9.9, (1024) = 52.5, («=) = 352; 1370. InEtalc; 782, 118B. Cond. with boric acid; 1186, 1185; qual.; 1184. Gl complex salt; 1711. - Na.A, alteration of cond. by KOH; 495. Laevulose see Fructose. iso-Lauronolic acid see iso-Campholytic acid. Lauth's Violet see Thionine. Lecithin. C42H84O9NP or C43H80O9NP or C44H80O11NP. Cond. of dil. soln. of lecithin from various sources; 1121. Lepidine. (4-Methyl quinoline). C10H9N. B.HCl at 25°, A(64) = 92.0, (256) = 95.9; 270. Leucaniline see Tri-p-aminotriphenyl-methane. Leucine see Aminocaproic acid. Leuconic acid. CsHgOg. At 25°, /i(54.8) = 48.6, (1752.4) = 60.0; 389. Leucotannic acid see Tannic acid. Leucylaminoacetic acid. (Leucylglycine). C8Hi603N2=C4H9.CH(NH2)CO.NH.CH2.C02H. kAXlO' at 25° = 1.5 (hydrol.). keXlO" at 25° = 3 (hydrol.); 519, 522. Cond. with NH3 and HCl; 522. Lev- see Laev- Limonene. (Carvene). CioHie. %Xl0'at 18°=3.3; 386. In NH3, qual.; 606. In SO2, little cond.; 1842. Cond. with organic compounds; 386. Linseed oil. [The references to this are incomplete. ] x; 1010, 1471. Liver. ■ [The references to this are incomplete. ] Cond.; 156a, 623 and 253. Concentration of H and OH ions in cell fluid; 587. Lung. [The references to this are incomplete. ] Cond.; 156a, 623 and 253. 194 TABLES [Lut Lutidlne see 2,6-Dimethyl-pyridine. Lutidine-dicarboxylic acid see Dimethyl-pyridine-dicarboxylic acid. Lutidinic acid see Pyridine-2,4-dicarboxylic acid. Lymph. [The references to this are incomplete. ] Cond.; 156a, 253, 258, 1137a, 1806. Concentration of H and OH ions; 587. Lysine. (ae-Diamino-caproic acid). C6Hi402N2=NH2.CH2.(CH2)3.CH(NH2).C02H. kAXlQii at 25° is about 1 (hydrol.). ks XlO' at 25° is less than 1 (hydrol.). Second ksX 101='= 1.1 (hydrol.); 948. Cond.; 145b. B.2HClat25°, M(64) = 331.0; ai(64) = 210.0; 948. B.Carbonate; 145b. M. Magdala Red see Naphthalene Red. Malamic acid see Malic acid mono amide. Maleic acid. C4H404=C02H.CH:CH.C02H. kAXlO^ diminishes, then increases on diln. At 0°=1.4; 1968a; 1018. At 12°= 1.45; 1968a. At 18°= 1.3; 460; - (colo- rim.); 1563, 1781. At 22°= 1.18 aq.; 164. At 25°= 1.3; 1372;=1.54; 1968a; = 1.2; 1500b. At 35°=1.51; 1968a. Second kAXlO'=2.0 (part.); 370; = 3.9 (inversion); 1638; = 5.5 (inversion); 1335; 2.6 (cond.); 370; = 80? (cond.); 1911. Cond.; 170, 1500b, 1508, 1630, 1718, 1968a. At 25°, m(32) = 168, (1024) = 331, (oo) = 357; 1372. m(32) = 175.4, (1024) = 337.9; ( 00) = 353; 1968a. In HCl, good cond.; 30. Cond. with inorg. and organic acids; 1630. With KOH and NaOH; 170, 1508, 1718. With aniline; 145a. 2(NH4).A; 145a. - Gl complex salt; 1711. - Mg.A; 319, 1836. - K.A and 2K.A; 164. - 2Na.A at 25°, m(32) = 90, (1024) = 108; 370; - 270, 1837, 1838. Alteration of cond. by KOH; 495.- Na.A; 370.- Zn.A; 319. Maleic acid anhydride. C4H2O3. xXlO^at 60°=1.19; 1843. Cond. of soln. showing change to acid; 1500b. Maleic acid mono ethyl ester. C6H804=C02H.CH:CH.C02Et. kAXlC at 25°=1.10. m(51.0) = 74.9, (816.0) = 212.0, (oo) = 354; 1859. MaUc acid. C4H606=C02H.CH2.CH(OH).C02H. [Probably 1-malic acid in all measurements. ] Mai] TABLES 195 kAXlO^ at 17°=3.83 aq.; 164. At 25''=4.0; m. p. 100°; 1372, 1824, 1186; (colorim.); 1643, 1781. Second kAXl08=7.5 (cond.); 1911. Cond.; 542, 691, 1495, 1518. At 25°, m(32) = 37.9, (1024) = 166.6 (oo) = 356; 1372. InHBrandHCl, nocond.; 30. In NH3, qual. ; 606. InEtalc; 1185. Cond. with boric acid; 1185, 1186; qual.; 1184. With M0O3; 691, 1495, 1518. Under pressure of 1-260 atmospheres; 542. Go.A; 1735. - Cu.A; 319. - Gl complex; 1521. - Mg.A; 1735, 1836. - Ni.A; 1735. - K.A; 164, 1648. - 2K.A; 164, 495, 588.- Na.A; 1838; qual.; 1643.- 2Na.A at 25°, A(32) = 82, (1024) = 100; 270, 1838. Under pressure of 1-260 at- mospheres; 542. - Complex salt; with M0O3 and WO3; 692; with ZrOj; 1648. 1-Malic acid mono amide. (Malamic acid). C4H704N=C02H.CH2.CH(OH).CONH2. kiXlO* at 25°=2.86; diminishes on diln.; m. p. 149°. A(32) = 32.5, (1024) = 146.1 (oo) = 356. Na.A at 25°, A(32) = 67.1, (1024) = 76.5; 1156. 1-MaUc acid dimethyl ester. C6Hio05=C02Me.CH2.CH(OH).C02Me. xxW at 0°=2.98; 1844. At 25°=5.45; 1843, 1844, 1830. In organic solvents; 1830. As solvent of NEtil; 1844. inact.-MaRc acid. C4H605=C02H.CH2.CH(OH).C02H. kAXlO* at 25°=4.0; m. p. 130°-131°; 1824; 1372. Second kAXlO«= 8.3 (inversion); 1638; = 5.5 (cond.); 1911. Malic acid from Crassulaceae. C4H6O6. Nasalt, /i(32) = 79.98, (1024) = 98.84; 11. Malonanilic acid. (Anilinomalonic acid). C9H903N=C02H.CH2.CO.NH(Ph). kAXlO^at 25°=1.96. A(64) = 37.1, (1024) = 126.3, (co) = 350; 1372. Malondihydroxamic acid. (Malonhydroxamic acid). , — O — 1 rOi C3H604N2= (N.0H)CH.CH2.C(N.0H)H. kAXlO^ at 25°=6; increases on diln. m(32) = 0.5, (128) = 1.1, (°°)=[400]; 1353a. Malonicacid. C3H404=CH2(C02H)2. kA at 10' at 0°=1.48; 1968a, 1887; = 1.36 aq.; 1018. At 4.9°= 1.52; 1968a. At 17°= 1.64 aq.; 164. At 18°= 1.6 (colorim.); 1563, 1781. At 25°= 1.63; m. p. 131°-132°; 1838, 1968a, 1968;=1.58; 1371;=1.71; 175. At 35° = 1.63; 1968a. Rel- ative value; 1866. 196 TABLES [Mai Second kAXlO^=2.0 (part, and cond.); 370;=1.0 (inversion); 1638, 1335; = 10 (cond.); 1911. Relative value; 1866. Cond.; 164, 171, 175, 370, 388a, 1018, 1371, 1887, 1968, 1968a. At 25°, m(32) = 73.0, (1024) = 250.8, (oo) = 358; 1838. In HBr and HCl, no cond.; 30. In N2O4, no cond.; 602. In Et ale; 647, 1590a. Cond. with KOH; 171. Under pressure, in alcohols; 1590a. Under pressure at 0°; 1708a. 2(NH4).A; 1126. -Ba.A; 469. - 2Cs.A; 1126. - Ca.A; 469. - Co.A; 1126, 1735. - Mg.A; 1736, 1836. - Ni.A; 1735. K.A; 164. - 2K.A; 164, 1126. - Na.A; 1838, 370. - 2Na.A at 25°, A(32) = 91.7, (1024) = 112; 370; 494, 1367, 1838. -2Rb.A; 1126. - Sr.A; 469. - " Double " salts; 1126. Malonic acid di-amide. (Malonyl amide). C3H6O2N2. Hg salt, e. m. f.; 963. Malonic acid mono ethyl ester. C6H804=C02H.CH2.C02Et. liAXlO* at 25°=4.6; increases, then diminishes on diln. m(17.1) = 30.3, (274.2) = 104.1, (oo) = 356; 1859. Malonic acid diethyl ester. C7Hi204=CH2(C02Et)2. Isa at 25° is not very different from that of aq.; (hydro!.); 665; = 1.6x10"^; increases on diln. ; 1815. Cond.; no cond. in aq.; 844, 1298. [Cond. is probably due to sapon.] At 25°, m(128) = 0.17, (256)=0.15; 1831; - 1815. Effect of temperature on cond.; 106. In HBr, good cond.; 1897. In NH3, qual.; 606. In Et ale, little or no cond.; 1815, 1298. Malonic acid dimethyl ester. C6Hs04=CH2(C02Me)2. xXlC at 0° = 0.794. At 25°=1.20; b. p. 181°-182° @ 752 mm.; 1843, 1844. Cond. at 25°, A(64) = 0.49, (128) = 0.63; 698. Cond. as solvent; 1844. Malonitrile. C3H2N2=CH2(CN)2. At 25°, m(64) = 0.37; 698. Malonyl amide see Malonic acid di-amide. Malonyl urea see Barbituric acid. Maltose. C12H22OU. In NH3, qual.; 606. Cond. with potassium tartrate; 1468. Mandelic acid see Phenylglycollic acid. Manganese cyanic acid. C6H3N6Mn=H3Mn(CN)6. 3K.A at 25°, A(32) = 126.3, (1024) = 143; 1832. Mannide phosphoric acid see Phosphoric acid mono mannide ester. Mannite see Mannitol. Mes] TABLES 197 d-Mannitol. (Mannite). C6Hi406=CH20H.(CHOH)4.CH20H. At 25°, m(33.1) = 0.17; 1518. Also; 322, 944, 1434. Cond. of satd. soln.; 1179, 1189. In HBr and HaS, no cond.; 1897. In NII3, qual.; 606. Cond. with boric acid; 944, 1179, 1183, 1189, 1316. With M0O3; 1518. With inorg. salts; 748. With oxalic acid; 45. Meconic acid. (Hydroxy-chelidonic acid). C7H407 = CbH02.(OH)(C02H)2. At 25°, m(32)=413, (1024) = 664; 1186; 1372. Cond. with boric acid; 1186. Meldola Blue. (|8-Naphthol Violet. New Blue R). A salt of Dime- thyl-phenonaphthoxazine. C1SII16ON2. B.HCl at 25°, A(64) = 78.1, (1024) = 92.0; 741. MeUitic acid. Ci2H60i2=C6(C02H)6. Cond. at 10°; 164. At 25°, m(69.9) = 421.6, (1118.4) = 717.7; 175. 6K.A; 164.- Na.A at 25°, m(32) = 171, (1024) = 313.- 2Na.A. - 3Na.A. - 4Na.A. - 5Na.A. - 6Na.A at 25°, /*(32) = 68, (1024) = 122; 1838. Menthol. CioH2oO=CioHi9.0H. In HCN, no cond.; 943. In NH3, qual.; 606. 1-Menthone. CioHi80=C9Hi8.CO. Cond. in organic solvents; b. p. 81° @ 21 mm.; 1763. Menthyl amine. CioH2iN=CioHi9.NH2. B.HCl at 25°, A(32) = 82.0, (1024) = 93.4; 270. Mercury. See compounds that follow; see also Trimercury-diacetone hy- droxide. " Double '' salts and complex salts, see; 149, 246, 604, 689, 785, 841, 907, 1008, 1094, 1379, 1485. Mercury cyanic acid. (Mercurocyanic acid). C4H2N4Hg=H2Hg(CN)4. 2K.Aat25°,A(32) = 113.1, (1024) = 134.8; 1832;- 149,907,1485. Cond. with salts; 149. Mercury diethyl. C4HioHg=Hg.Et2. InS02, no cond.; 1842. Mercury ethyl chloride see under the hydroxide. Mercury ethyl hydroxide. C2H60Hg=Et.Hg.OH. At 25°, A(64) = 1.7; 425; 271. Cond. with NaOH; 425. B.Cl=Et.Hg.Cl; 1569. Mesaconanilic acid see Citraconanilic acid. Mesaconic acid. C6H604=C02H.CMe:CH.C02H. kxXlO*; increases on diln. in all measurements. At 0°=8.4; 1018, 1968a. At 12°=8.4; 1968a. At 17°=8.0 aq.; 164. At 18°=8 (colorim.); 1563, 1781. At 25°=8.0;m. p. 198 TABLES [Mes 201°-202°; 1372, 1823, 1831, 1838, 1968a. At 35°=7.7; 1968a. Second kiXlO^ =6.8 (inversion); 1638, 1335; = 9 (cond.); 1911. Cond.; 170, 1968a. At 25°, m(32) = 52.0, (1024) = 209.8, («>) = [351]; 1968a. ^(48) = 63, (co) = 355; 1372. In HCl, no cond.; 30. In NHs, qual.; 606. Cond. with KOH; 170. Mg.A; 1836. - 2K.A; 170. - 2Na.A at 25°, A(32) = 80.6, (1024) = 96.6; 270; - 1823, 1831. Mesitonic acid see Dimethyl-laevulinic acid. Mesitylene. C9Hi2. Insol. in NHs; 606. Mesitylene mono-carboxylic acid see 2,4,6-Trimetliyl-benzoic acid. Mesitylenedicarboxylic acid. (2,4,6-Trimethyl-m-phthalic acid). CiiHi204=Me3.C6H(C02H)2. [C02H=2,4; Me=l,3,5.] IsaXIO* at 25°=9.8; diminishes on diln. /i(64) = 82.3, (1024) = 180.0, (oo) = 373; m. p. 283° with dec. 2Na.A at 25°, m(32) = 70.1, (1024) = 89.5; 275. Mesitylenediglyoxylic acid. Ci3H]206=Me3.C6H(CO.C02H)2. [CO.C02H=2,4; Me=l, 3,5.] kxXlO^ at 25°=5; diminishes on diln. m(32) = 260.2, (1024) = 377.1, (oo) = 371; m. p. not definite. 2Na.A at 25°, m(32) = 73.2, (1024) = 89.4; 275. Mesityleneglyoxylic acid. (Mesitylene-mono-glyoxylic acid. Tri- methyl-benzoylformic acid). CiiHi203 = Me3.C6H2.CO.C02H. [CO.C02H=2; Me=l,3,5.] kxXlO^ at 25°= 5.4; diminishes, then increases on diln. /i(32) = 256.5, (256) = 334.9, (1024) = 359.0, (co) = 360.7; m. p. 115°. Na.A at 25°, A(32) = 63.8, (1024) = 80.3; 275. Mesitylenic acid see 3,5-Dimethyl-benzoic acid, meso- see under letter beginning the next word, e. g. Mesomethyl- see meso-Methyl- Mesozalic acid. (Dihydroxy-malonic acid). C3H406= (OH)2.C.(C02H)2. Cond. increased by boric acid; 1186. Metacetaldehyde see Acetaldehyde. MetaniUc acid see m-Aniline sulphonic acid. Methacrylic acid. Polymeric. (Polymethacrylic acid). C32H480i6=(C4H602)x; x=7or8. kAXlO^ at 25°=3.4; diminishes on diln. /x(32) = 3.6, (1024) = 15.8, (cd) = 345; dec. 200°-300° without melting. Li salt.- K salt.- Na salt at 25°, ai(32) = 32.9, (1024)=79.7; 1273. Met] TABLES 199 Methane-disulphonic acid see Methylene-disulphonic acid. Methanetricarboxylic acid triethyl ester. CioHi606=CH(C02Et)3. Cond. very small; 1298. Methinetrithio-glycoUic acid. C7Hio06S3= (C02H.CHSH)3CH. kAXlO= [at 25°]=1; increases on diln. m(32) = 58.7, (512) = 210, (ao) = 375; m. p. 173°; 850. Methoxy-acetic acid. (Glycollic acid methyl ether. Methyl-glycollic acid). CsHeOs^CHa.OMe.COsH. kA XlO* at 25°=3.4; aq. used for soln. was not pure. A(32) = 35.2, (1024) = 151, (co) = 358; 1370. Na.A at 25°, A(32) = 70.0, (1024) = 81.6; 1367. p-Methoxy-benzaldehyde see Anisic aldehyde. o-Methoxy-benzene sulphonic acid amide. (o-Anisole sulphonic acid amide). C7H903NS= MeO.C6H4.S02NH2. In NHg; 607, 610. m-Methoxy-benzene sulphonic acid amide. (m-Anisole sulphonic acid amide). C7H9O3NS. In NH3; 604, 607, 610. p-Methoxy-benzene sulphonic acid amide. (p-AnisoIe sulphonic acid amide). C7H9O3NS. In NH3; 607, 610. o-Methoxy-benzoic acid. (Methylsalicylic acid). C8H803= MeO.C6H4.CO2H. kAXlO^ at 18°=11 (colorim.); 1563. At 25°=8.2; increases, then diminishes on diln.; 1371, 1429. At 25°, A(32) = 17.5, (1024) = 86.9, (co) = 355; 1371. Na.A at 25°, A(32) = 69.7, (512) = 79.1; 1091. m-Methoxy-benzoic acid. CsHsOs. kAXlO' at 25°=9.0; diminishes on diln.; m. p. 95° and 106°. A(256) = 50.0, (1024) = 92.1, (oo) = 355; 1429. p-Methoxy-benzoic acid. (Anisic acid). CsHsOs. kAXlO^ at 18° = 4.1 (colorim.); 1563, 1781. At 25°=3.2; 1371; =3.6; 1429. At 50° = 3.2 aq. At 60° = 3.1 aq. At 70° = 3.0 aq. At80°=2.8aq. At 90°= 2.6 aq. At 99° = 3.6 aq.; 1581. At 25°, A(512) = 42.7, (1024) = 58.1, (oo) = 355; 1371. InNHs, qual.; 606. Na.A at 25°, A(32) = 65.8, (1024) = 75.2; 1368a. A(32) = 69.7; 1091, 1581. 3-Methoxy-6-chlorobenzoic acid. C8H703Cl=MeO.C6H3Cl.C02H. [C02H=1.] kAXlO^ at 25°=1.36; increases on diln.; m. p. 168°-169°. A(458) = 190.5, (916) = 232, (co) = 354; 404. 200 TABLES [Met 4-Methoxy-dibenzal-acetoiie. (Benzal-p-anisal-acetone) . C18H16O2. Comparative strength ([colorim.); m. p. 96.5°; 74, 1663. 4-Methoxy-dibenzal-cyclopentanone. (Benzal-p-anisal-cyclopenta- none) . C20H18O2. Comparative strength (colorim.); m. p. 153°; 1663. iso-Methoxy-dibenzal-cyclopentanone. (iso-Benzalanisal-cyclopenta- none). C20H18O2. Comparative strength (colorim.); m. p. 147°; 1663. 2-Methoxy-3,5-dichloro-benzoic acid. (Dichloro-salicylic acid). C8H603Cl2= MeO.C6H2CI2.CO2H. kAXlC at 25°=1.37; m. p. 166.5°-167°. A(2170) = 279.7, (4340) = 309.2, (oo) = 354; 404. o-Methoxy-phenyl urethane. CioHi303N=MeO.C6H4.NH.C02Et. At 25°, K of satd. soln. = 5.2 XKT*; 1660. 4-Methoxy-m-phthalic acid. C9H806=MeO.C6H3(C02H)2. [C02H=1, 3; Me0=4.] kiXlO^ at 25°=2.5, extrapolated; m. p. 260°. /i(5l2) = 107.5, (1024) = 142.6, (oo) = 352; 1429. 5-Methoxy-o-toluic acid. (Methyl-m-homo-p-hydroxy-benzoic acid). C9Hio03=MeO.C6H3Me.C02H. [Me=l; C02H=2; Me0=5.] kAXlO* at 25°= 5.4; diminishes on diln. A(2048) = 98.8, (4096) = 128.6, (oo) = 352; 1429. 4-Methoxy-m-toluic acid. (Methyl-p-homo-o-hydroxy-benzoic acid). C9H10O3. [Me=l; C02H=3; Me0=4.] kiX 105 at 25° = 6.8. A(128) = 31.2, (1024) = 81.2, (oo) = 352; 1429. 6-Methoxy-m-toluic acid. (Methyl-o-homo-p-hydroxy-benzoic acid). C9H10O3. [Me=l; C02H=3; Me0=6.] kAXlO^ at 25° =3.48; diminishes on diln. A(2048) = 82.3, (4096) = 108.7, (00) = 352; 1429. 3-Methoxy-p-toluic acid. (Methyl-m-homo-o-hydroxy-benzoic acid). C9H10O3. [Me=l; C02H=4; MeO=3.1 kxXlO^ at 25°=4.1; diminishes on diln.; m. p. 103°. A(256) = 34.4, (1024) = 65.1, (oo) = 352; 1429. Methylacetoacetic acid ethyl ester. C7Hi203=MeCO.CHMe.C02Et. ki is between 10"" and lO"'' (catal.); 1594. ;3-Methyl-7-acetylbutyric acid. C7Hi203=MeCO.CH2.CHMe.CH2.C02H. kAXlO* at 25°=2.7 aq.; b. p. 141° @ 15 mm. A(31) = 10.8, (990.7) = 56.4, (00) = 374; 1588. Methylacridine. CmHuN. B.OH at 0°, A(256)=23. B.Mel; 763. Met] TABLES 201 Methylacridinium iodide. CwH^NI. Cond. with NaOH; 763. a-Methyladipic acid. C7Hu!04=C02H.(CH2)3.CHMe.C02H. IsaXIO^ at 24.4°=4.0; increases on diln.; m. p. 63°. m(54.3) = 15.8, (869) = 62.6, (co) = 352; 1240. Methyladipic acid see 7-Kmelic acid. Methylal. CsHsOa. In NH3, qual.; 606. Methyl alcohol. CH40 = Me.0H. KXlO^ at 0° = 0.8; 920;=1.0; 916, 918; - 906, 1651. At 17°= 1.3; 289; 290. At 18°=0.44; 1724; = 1.2; 1807; 362, 438, 580, 783, 787, 842, 1470. At 20°=5.8; 1590a. At 25° = 0.07; 337; =0.74; 1844. Carefully purified methyl alcohol has x=l-2. See also 335, 338, 347, 904, 905, 906, 908, 912, 913, 917, 918, 922, 941, 1388, 1390, 1423a, 1434a, 1579, 1580, 1592, 1620, 1746, 1843, 1987, 2029. At 35°= 1.0; 1390. At 45°=1.7; 1434a. At critical point, qual.; 107; 133. kA is very small; qual.; 58. Relative basicity in organic sol- vents (colorim.); 1051. Concentration of OH ions; 343. Cond.; 337. In HBr; 29. In HBr, HCl and HI, good cond.; in H2S, poor cond.; 1897. In HCN, no cond.; 943. In H2SO4; 750. In NH3, qual.; 606. In MeNHa, little cond.; 637. Cond. with other compounds; 45, 145b, 433, 748, 1035, 1388, 1724, 1746. As solvent; 82, 289, 290, (327), (331), 334, 335, (337), 338, 344, (347), 433, 438, (580), 746, (783), 787, 788, (842), (904), (912), (915), (916), (918), (920), 922, 923, (941), 958, (1025), (1026), 1263, 1286, 1386b, 1388, 1390, 1423a, 1434a, 1464, 1470, 1679, 1580, 1590a, (1592), 1620, 1624, (1651), 1724, 1746, 1759, 1807, 1844, 1848, 1849, 1853a, 2029. Under pressure; 1590a. NH4.A. - K.A; 335. - Na.A at 18°, A(12) = 32.5, (31)=40.8, (50) = 43.7, (oo) = 94 (?); 433; 335, 344, 1724. Methyl aldozime see Acetaldozime. Methylalloxan. C6H4O4N2. At 25°, m(32) = 9.3, (1024) = 18.8; 1748. a-Methylallylphenylbenzyl ammonium chloride. Ci7H2oNCl=(Me)(C3HB)(Ph)(PhCH2).NCl. At 25°, A(64) = 92.9, (512) = 102.2; m. p. 152°-154°; 1903. meso-Methylallylsuccinic acid. C8Hi204=C02H.CHMe.CH(C3H6).C02H. kAXlO* [at 25°] = 2.34; diminishes on diln. a'(32) = 29.1, (1024) = 125.5, (oo) = 351; m. p. 86°-87°; 826. 202 TABLES [Met p-Methylallylsuccinic acid. C8H12O4. kiXlO^ [at 25°] = 2.49; diminishes on diln. m(32) = 30, (1024) = 131.0, (oo) = 351; m. p. 147°-148°; 826. Methyl amine. CH5N=MeNH2. xXlO^ [at 20°?]=7; 605. kfiXlO^ at 25°=5 aq.; diminishes on diln.; about 16% too high; 271;=4.1 (neutral.); 299a. Relative strength; 1631. Cond.; 299a. At 25°, A(32) = 27.0, (256) = 65.4, (a=) = 225; 271. InNHs, qual.; 606. Cond. with HCl; 299a. With AgO; 510, 520. With succini- mide; 1752. As solvent; (520), 605, 637. B.HCl at 25°, A(32) = 113.4, (1024) = 125.1; 270. In NH4OH; 650. In SO2; 1829, 1855. - Complex salts; 1750, 1752, 1755. Methylamino-acetic acid. (Methylglycine. Sarcosine). C3H702N=NHMe.CH2.C02H. kAXlO" at 25° = 1.3 (hydro!.); 1984. ksXlQi^ at 25° = 1.8 (hydrol.); 1984; 890, 1150; (colorim.); 1775. At 25°, A(914) = 228.6, (co) = 350; 601. In NH3, qual.; 606. Na.A at 25°, A(32) = 68.0, (1024) = 82.6; M(32)=76.1, (1024) = 111.- B.HCl at 25°, A(32) = 102, (1024) = 113; M(32) = 199, (1024) = 366; 1984. o-Methylamino-benzoic acid. (N-Methylanthranihc acid). C8H9O2N = NHMe.C6H4.CO2H. kAXlO«at25°=4.6. kBXl0i3at25°=9.4 (catal.). At 25°, A(775) = 21.1, (1025) = 24.9, (oo) = 378. Na.A at 25°, A(32) = 68.9, (1024) = 78.4; 414. o-Methylamino-benzoic acid methyl ester. (N-Methylanthranilic acid methyl ester). C9Hii02N = NHMe.C6H4.C02Me. ksXlO" at 25°=3.36 (catal.); 414. m-Methylamino-benzoic acid. C8H902N=NHMe.C6H4.C02H. kAXlO« at 25°=8 (catal.); = 6.7 (cond.); m. p. 147°. ks XlO" at 25° is about 1.2 (catal.). At 25°, A(82) = 7.5, (1312) = 31.8, (co) = 377. Na.A at 25°, A(32) = 69.9, (1024) = 79.7; 414. p-Methylamino-benzoic acid. C8H902N=NHMe.C6H4.C02H. kiXlO^ at 25°=9.2 (catal.); = 8.8 aq. (cond.); m. p. 144°-145°. ksXlQi^ at 25°=1.66 (catal.). At 25°, A(128) = 10.2, (1024) = 34.1, (00)^377. Na.A at 25°, A(32) = 68.3, (1024) = 80.7; 890. p-Methylamino-benzoic acid methyl ester. C9H11O2N. kBXlO'^ at 25°= 2.0 (part.); m. p. 75°-76°; 890. Met] TABLES 203 4-Methyl-2-aminophenyl ethyl carbonate. CioHi303N=Et02CO.C6H3(Me).NH2. kfiXlO" at 0° = 1.23 (hydrol.). B.HCl at 0°, m(32)=42.6; M(32) = 73.5. Cond. on standing; m. p. 135°-137°dec.; 1660. 6-Methyl-2-aminophenyl ethyl carbonate. C10H13O3N. kflXlO" at 0°=2.16 (hydrol.). B.HCl at 0°, /i(32)=42.6; M(32) = 69.1. Cond. on standing; 1660. 6-Methyl-2-aminophenyl ethyl carbonate. C10H13O3N. keXlO" at 0°=1.05 (hydrol.). B.HCl at 0°, Ai(32) = 42.6; M(32) = 78.5; 1660. 2-N-Methylamino-p-phthaUc acid. C9H904N = MeNH.C6H3(C02H)2. [C02H=1,4; MeNH=2.] kA X 10^=3; m. p. 277°-279°; 1684. In 316 it is stated that this acid contained some dimethyl-amino-p-phthalic acid, and that kA of the pure acid is a little smaller. No figures are given. Ai(610) = 130, (1200) = 171.2, (cx>) = 376; 1684. Methylanunonium acetate see Acetic acid; organic salts. Methylammonium hippurate see Benzoylamino-acetic acid; salts. Methylanunonium phenylacetate see Phenylacetic acid; salts. Methyl-jso-amyl-dimethylamino-methyl carbinol benzoate. {iso- Amyl stovaine derivative). Ci7H2702N=PhCO.O.CMe(C6Hii).CH2.NMe2. kBXlO'^ at 15° is about 1 (hydrol.); 1777, 1779. cis-a-Methyl-a '-iso-amyl-succinic acid. CioHi804=C02H.CHMe.CH(C5Hii).C02H. kAXlO* at 25° = 3.85; m. p. 93°. Ai(52.3)=46.3, (418.4) = 115, (00)= [351]; 236. ) = 354; 492. Methylanthranilic acid see o-Methylamino-benzoic acid. Methyl arsenic acid. (Mono methyl arsenic acid. Methyl arsenic acid). CH608As=Me.AsO(OH)2. kA XlO^ at 25° is about 1; 2009. Cond. alone and with M0O3; 1269. Methyl arsonic acid, see Methyl arsenic acid. Methylbenzenyl-amino-thio-xylenol-azo-a-naphthol disulphonic acid see Erika B. a-Methyl-m-benzimideazolecarboxylic acid. (meso-Methylphenmi- azolemonocarboxylic acid). C9H8O2N2. kAXlO^ at 25°= 1.0. m(760.7) = 9.6, (1521.4) = 13.5, (oo)=350; 70. m-Methyl-a-benzimideazolecarboxylic acid. C9H8O2N2. kAXlO" [at 25°] = 1.1; m. p. 143° slowly heated; 80. Methylbenzoylamino-acetic acid. (Benzoylsarcosine). CioHii03N=PhCO.NMe.CH2C02H. kAXlO*at25°=5.05. m(64) = 57.6, (1024) = 175.6, (00) = 350; 601. 2-Methylbenzoyl amino-propionic acid. (o-Alaninetoluric acid). CiiHi303N= MeC6H4CO.NH.CHMe.CO2H. kiXlO^ at 25°= 1.65. m(411.4) = 80, (1645.6) = 141.3, (cx>)=350; 601. 4-Methylbenzoyl amino-propionic acid. (p-Alamnetoluric acid). C11H13O3N. kAXlO* at 25°= 1.70; diminishes on diln. m(408.5) = 81.1, (1634.0) = 141.5, (co) = 350; 601. Methylbenzylcarboxyglutaric acid see Benzyl-iso-butenyltricarboxylic acid. Methylbenzylglutaric acid. Ci3Hie04. kAXl05at25°=5.9; m. p. 128°-130°; called dimethyl-benzylsuc- cinic acid, with some doubt as to real structure. m(32) = 14.5, (512) = 55.7, (oo) = 350; 201. Methylbenzylmalonic acid. CiiHi204=(Me)(PhCH2)C(C02H)2. kAXlO^ at 25°=2.66 aq.; diminishes on diln.; m. p. 138°. Second kAXlO''=1.2 (inversion). At 25°, Ai(64) = 117.9, (1024) = 265.9, (oo) = 35l; 1638. nicso-si/m.-Methylbenzylsuccinic acid. Ci2Hi404=C02H.CHMe.CH(PhCH2).C02H. kAXlO* at 25° =2.47; increases, then diminishes on diln.; m. p. 137°-138°; 201, 1838. m(32) = 29.7, (512) = 103.4, (oo) = 350; 1838. Met] TABLES 205 p-sym.-Methylbenzylsuccinic acid. C12H14O4. kAXlO* at 25°=2.18; increases on diln.; m. p. ISQ'-ieO"; 201, 1838. At(32) = 27.8, (512) = 99.1, (co) = 350; 1838. Methyl-bromo-uracil. C6H602N2Br. kAXlO'at 25° = 2.6. m(512) = 1.3, (1024) = 1.8; 1748. cis-aa '-Methyl-iso-butyl-succinic acid. C9Hi604=C02H.CHMe.CH(iso-Bu).C02H. kAXlO* at 25°=4.27; diminishes on diln.; m. p. 88°-90°. m(34.5) = 40.1, (276.0) = 101.0, (00)= [351]; 236. ) = 352; 2026. l-Methylcyclohexane-4-carboxylic acid. (Hexahydro-p-toluic acid). C8H14O2. 206 TABLES [Met kAXlO^ [at 25°]= 1.11. m(209.5) = 16.5, (1676.3) = 45.3, (oo) = 352; 2026. l-Methylcyclopentane-3-carboxylic acid see l-Methylpentamethylene- 2-carbozylic acid. S-Methyl-desoxyxanthine see 3-Methyl-2-oxy-l,6-dihydro-purine. Methyldiethyl-amine. C6Hi3N=Me.N.Et2. ks XlO^ at 25°=2.7 aq.; about 16% too high. A(32) = 18, (256) = 46.2, (ao) = 203; 271. B.HCl at 25°, A(32) = 91.7, (1024) = 103.2; 270. m-Methyldihydro-resorcinol. C7H10O2. kAXlO«at25° = 5.7aq. A(33.2) = 5.1, (1031) = 27.9, (co) = 376; 1588. 4-Methyl-l,2-diliydroxy-l,2,5-triazole S-caibozylic acid ethyl ester, (Dihydroxy-triazolidine-acetic acid ethyl ester. Methyl- dihydroxy-triazolidine-carboxylic acid ethyl ester). C6Hn04N3. kiXlO' at 18° = 6.17; m. p. 70°-71°. At 18°, A(23.8) = 108.2, (119.2) = 193, (00) = 340; 527. Methyl-dihydroxy-triazolidine see Methyl-dihydroxy-triazole, Methyldiphenyl amine. C13H13N. In NH3, qual.; 606. Methylene Blue see Tetramethyl-thionine chloride. Methylenecyclopropane amine. (Ethylene-ethyl amine). C4H9N=(C3H6.CH2)NH2. ks XlO* at 25° = 4.4; b. p. 86° (in vapor.) /i(29.4) = 21.7, (471) = 74, (co) = 204; 420. Methylene-dihydro-benzoic acid see iso-Phenylacetic acid. Methylene di-hydroresorcinol. C13H16O4. Too insol. in aq. to measure, therefore kA is less than that of dihydroresorcinol, ( = 5.5x10^^); m. p. 132°; 1816. Methylene-dimethyl-succimc acid. C7Hio04=C02H.Me2C.C(:CH2).C02H. kxXW at 25°= 1.67; m. p. 142.5°. m(20) = 19.7, (80) = 38.5, (oo) = 352; 229. Methylene-disulphonic acid. (Methane-disulphonic acid). CH406S2=CH2(S03H)2. 2Na.A at 25°, m(32) = 92.7, (1024) = 117.5; 1367. Methylenedi-thioglycoUic acid. C6H804S2=(C02H.CHSH)2:CH2. kAXlO* [at 25°] = 4.67; increases on diln. ju(32) = 43.6, (512) = 158.2, (co) = 378; m. p. 128.5°-129° (uncor.); 856. xi-Methyleneglutaric acid. C6H804=C02H.C(:CH2).(CH2)2.C02H. kAXlO* at 25°=6.7; increases on diln.; m. p. 130°-131°. A(32) = 17.0, (1024) = 86.8, [(00) is about 380]. 2Na.A at 25°, A(32) = 84.5, (1024) = 101.9; 565. Met] TABLES 207 7-Methylene-7-phenylp3rrotartaric acid. (Methylphenylaticonic acid). Ci2Hi204=Ph(CH2:)C.CH(C02H).CH2.C02H. kAXlO^ [at 25°]=1.95; m. p. 152°-154°. m(63.8) = 36.8, (1021) = 124.6, (oo) = 350; 1661, 817. Methylethylacetic acid. CBHio02=(Me)(Et)CH.C02H. kAXlO* at 25°=1.69; b. p. 175°; 180, 1840. A(32) = 8.3, (1024)=43.6, (co) = 352; 1840. Methylethylacrylic acid see a-Methyl-a,|3-pentenoic acid. Methylethylaniline. C9Hi3N=Ph.N(Me)(Et). B.HCl at 25°, A(64) = 90.2, (256) = 94.9; 270. Methylethyl-aticonic acid. (7-Methyl-7-ethylidenepyrotartaric acid). C8Hi204=Me(Me.CH:)C.CH(C02H).CH2.C02H. kAXlO^ [at 25°] = 1.12; m. p. 140°-141°. m(45.7) = 24.2, (1462) = 114.9, (cx.) = 351; 1662. Methylethylcarbiaainine see secondary-Bntyl amine. Methylethylcarboxylglutaric acid. C9Hi406=Me.CH(C02H).CH2.C(Et)(C02H)2. kiXlO' at 25° = 9.74; m. p. 166°. in(32) = 148.4, (1024) = 324, (oo) = 350; 1839. Methylethyl-dunethylamino-methyl carbinol benzoate. (B.HCl is Stovaine). Ci4H2i02N=PhOCO.C(Me)(Et).CH2.NMe2. keXlO^at 15°=1.5 (hydrol.); 1779; 1777. meso-a-Methyl-a '-ethylglutaric acid. C8Hi404=C02H.CHEt.CH2.CHMe.C02H. kiXlO^ at 25°=5.6; m. p. 63°-67°; 189, 201, 1838. [Called also, dimethyl-N-ethylsuccinic acid in 201.] m(32) = 14.4, (1024) = 73.2, (oo) = 351; 1838. ;8-Methyl-a-ethylglutaric acid. C8Hi404=C02H.CH2.CHMe.CHEt.C02H. kAXlO^ [at 25°?] = 6.7; m. p. 100°-101°; 1398. [? same as di- methyl-H-ethylsuccinic acid, kA=5.9; m. p. 105°. m(32) = 14.9, (512) = 54, (co) = 351; 201.] Methylethyl glyoxime. C5H10O2N2. Co complex salt; 1759. Methylethylidene-glutaric acid see Dicrotonic acid. Methylethylidenepyrotartaric acid see Methylethyl-aticonic acid. Methylethyl-itaconic acid. C8Hi204=MeEtC:C(C02H).CH2.C02H. kAXlO* at 25° = 1.50 aq.; diminishes on diln.; m. p. 179°-181° dec; 1638, 1662. Second kAXlO'=4.6 (inversion). At 25°, m(139.4) = 47, (1115) = 116.3, (oo) = 351; 1638. Methylethyl ketone. C4H80=Me.CO.Et. xXlO^at 25° = 1.0; 1423a;=3.07; 1323. Cond. as solvent; 474, 1106, 1107, (1323), 1423a. 208 TABLES [Met Methylethylmaleic acid. C7Hio04=C02H.CMe:CEt.C02H. kA XlO^ at 25° =9.7 from soln. of the anhydride in aq. Apparently polymerizes in soln. as shown by small cond. /x(128)=37, (1024) = 94; 1838, 1030. Methylethylmaleic anhydride. CjHsOs. See the acid. Methylethylmalonic acid. C6Hio04=(Me)(Et)C(C02H)2. kAXlO' at 18°=1.6; 1563. At 25°=1.61; m. p. IISMIQ"; 1838, 175. Second kAX 10'= 1.7 (inversion); 1638. At 25°, m(32) = 71.8, (1024) = 248, (oo) = 355; 1838. asym.-Methylethylsuccinic acid see iso-Pimelic acid. /um.-sj/m.-Methylethylsuccinic acid. (/3, or h-, or p- acid). C7Hl204= CO2H.CHMe.CHEt.CO2H. kAXlO^ at 25°=2.10; m. p. varies from 169° to 180°; pure acid has m. p. 180°; 61, 62, 175, 200, 1418, 1838. At 25°, /i(32) = 27.5, (1024) = 126.4, (oo)=352; 1838. ma/ .-sj/m.-Methylethylsuccinic acid, (a, or meso-, or n- acid). kAXlO* at 25°=2.10; m. p. varies from 84° to 101°; pure acid has m. p. 101°-102°; 62, 175, 201, 1418, 1838. - 61. At 25°, m(32) = 27.1, (512) = 95.3, (00) = 352; 1838. cis-|3-Methylglutaconic acid. C6H804=C02H.CH:CMe.CH2.C02H. kAXlO^ at 25°=1.3; diminishes on diln.; m. p. 152°. m(32) = 22.9, (1024) = 110; 572. ) = 345; 2018. ma/.-si/m.-Methylphenylsuccinic acid. C11H12O4. kAXlO^ at 25°=2.33; diminishes on diln.; m. p. 170°-171°; 2018, 2023. /i(78.8)=43.7, (1260) = 139.8, (oo) = 345; 2018. 4-Methyl-l-phenyl-3-thio-urazole. C9H9ON3S. kAXlO^ at 25°= 1.8; diminishes on diln.; m. p. 196°. A(256) = 299.7, (512)=309.7, (co)=355; 18. 2-Methyl-l-phenyI-urazole. C9H9O2N3. kAXlO* at 25°=6.7; m. p. 185°. A(128) = l, (1024) = 2.5, (co) = 345. Na.A at 25°, A(64) = 59.1, (1024) = 66.1; 18. 4-Methyl-l-plienyl-urazole. C9H9O2N3. kAXlO^ at 25°=1.2; diminishes on diln.; m. p. 225°. A(512) = 27, (1024) = 37.5, (cx=) = 355. Na.A at 25°, A(64) = 55.8, (1024) = 63.8; 18. O-Methyl-N-phenyl-/>seu(f0-urea. C8H10ON2 = NH :C (NHPh) OMe. ksXlO'' at 25°=2.5; m. p. 46.5°; 285, 286. A(32) = 0.6, (256) = 2.1, (oo) = 225.5; 285. B.HClat 25°,'A(32) = 90.4, (1024) = 102.6; 286. Methyl-m-phthalic acid see Uvitic acid. MethylpicoUnium chloride. C7HioNCl=C6H7N.MeCl. At 25°, A(32)=94.4, (1024) = 106.6; 270. a-Methylpimelic acid. C8Hu04=C02H.(CH2)4.CHMe.C02H. kAXlO^ [at 25°] = 3.15; m. p. 57°-58°; 2024. Methylpropylcarboxyglutaric acid see Propyl-jso-butenyltricarboxylic acid. 214 TABLES [Met o-sym.-Methylpropylglutaric acid. C9Hi604=C02H.CHMe.CH2.CHPr.C02H. IjaXIO^ at 25°=5.4; m. p. 51°-53°, [Given as either Dimethyl- N-propylsuccinic acid or this acid.] m(64)=20, (512) = 62.2, (cx>) = 350; 201. ^-sym.-Methylpropylglutaric acid. C9H16O4. kA X 10^ at 25°= 5.9; m. p. 101°-102°. [Given as either Dimethyl- H-propylsuccinic acid or this acid.] m(64) = 20.9, (512) = 53.8, (a>) = 350; 201. Methylpropyl ketone. C6HioO=Me.CO.Pr. «X10' at 25°=9.5; 1106, 1107. In HBr and H2S, fair cond.; 1897. As solvent; 474, 1106, 1107. Methylpropylmaleic acid. C8Hi204=C02H.CMe:CPr.C02H. kAXlO^ at 25°=7.3; measured in aq. soln. of the anhydride. At(64) = 25.2, (1024) = 89.5, (co) = 376; 1031. Methylpropylmaleic acid anhydride. CsHioOs. B. p. 241°-242° cor.; see the acid. Methyl-jso-propylmaleic acid. C8H:204=C02H.CMe:Ciso-Pr.C02H. kAXlO* at 25° = 1.5; diminishes on diln.; measured in aq. soln. of the anhydride. Ai(64)=35, (1024) = 84.7, (oo)=376; 1031. Methyl-fso-propybnaleic acid anhydride. CsHioOs. B. p. 240°-242°; see the acid. Methylpropylmalonic acid, C8H14O4, in 1667 is a misprint for Ethyl- propyl- etc. Methylpropylphenylbenzyl ammonium bromide. Ci7H22NBr=(Me)(Pr)(Ph)(PhCH2)N.Br. At 25°, A(32) = 86.9, (1024) = 91.6. In Et ale; 1903a. C!s-aai-Methylpropylsuccinic acid. C8Hl404= CO2H.CHMe.CHPr.GO2H. kAXlO^ at 25° = 2.71; m. p. 92°-93°. /i(26.5) = 28.4, (212.0) = 74.7, (00)= [351]; 236. )=[351]; 235. N-Methyl pyrazole. C4H6N2. kfiXlOi^ [at 25°] = 1.1 (catal.); b. p. 127°; 428. Met] TABLES 215 3-Methyl pyrazole. C4H6N2. ksXlO^i [at 25°] = 3.6 (solub.); b. p. 202°; 428. Methylpyridine see Picoline. 2-Methylpyridme-3,5-dicarboxylic acid. C8H7O4N. kAXlO' at 25° = 2. m(128) = 138.6, (1024) = 264.4, (co) = 353; 1372. 2-Methylpyridme-3,5,6-tricarboxylic acid. CgHyOeN. At 25°, m(128) = 285, (1024) =468; 1372. Na.A at 25°, m(32) = 84.3, (1024) = 115.1; 1369. 4-Methylpyridine-3,5,6-tricarboxylic acid. (7-Methyl- etc.). CsHjOeN. At 25°, m(128) = 343, (1024) = 538; 1372. Methylpyridinium hydroxide. C6H90N=C5H5N.MeOH. At 25°, A(32) = 217.4, (256) = 224; 763. B.Cl(=C5H6N.MeCl) at 25°, A(32) = 99.7, (1024) = 112.2; 270. - B.I, in pyridine; 753. - B.I.Bra; m. p. 68°-69°, cond. when molten; 1578. N-Methyl-pyrrolidine-aa'-dicarboxylic acid. C7H11O4N. IcaXIO^ at 25° is over 1. m(32) = 198.8, (1024) = 620.1; m. p. 273°-274°; 1979. 1-Methylpyrrylglyoxylic acid. C7H703N=Me.C4H3N.CO.C02H. kAXl02at25°=2.7aq. m(30) = 208, (960) = 340, (=») = 357; m. p. 142.5°; 23. Cond. not increased by boric acid; 1186. 2-Methylpyrrylketone-5-carboxylic acid, (a- or psetido-Acetylcarbo- pyrrolic acid. 2-Acetyl-pyrrole-5-carboxylic acid.) C7H703N = MeCO.C4H3N.C02H. kAXlO* at 25° =3 aq.; increases, then diminishes on diln.; m. p. 186°; 23, 1186. /i(40) = 37.0, (1280) = 163.7, (co) = 357; 23. Cond. with boric acid; 1186. 2-Methyl quinoline see Quinaldine. 4-Methyl quinoline see Lepidine. 6-Methyl quinoline see p-Tolu quinoline. Methylquinolinium hydroxide. CioHiiON=C9H7N.MeOH. At 0°, A(32) = 209; changes in soln. to Methylquinolinium oxide; 763. B.Cl ( = C9H7N.MeCl) at 25°, A(32) = 92.0, (1024) = 104.4; 270. - B.I, in propionic aldehyde; 1844. - B.I.I2, m. p. 108.6°- 109.6° and B.I.I4, m. p. 72°-73°; cond. when molten; 1578. Methyl-iso-quinolinium hydroxide. CioHuON. AtO°, A(32) = 206.9; 763. B.Cl(=C9H7N.MeCl) at 25°, A(32) = 92.4, (1024) = 104.6; 270. 216 TABLES [Met Methylquinolinium oxide. C2oH2oON2=(C9H7NMe)20. No cond. in aq.; 763. [In 763 it is claimed that this compound was prepared pure. Decker (Ber. Deutsch. Chem. Ges. 36, 1210) could not make a pure compound of this description.] Methyl Red see p-Dimethyl-amino-azobenzene-o-carboxylic acid. Methylsalicylic acid see o-Methoxy-benzoic acid. Methylsuccinic acid see Pyrotartaric acid. Methyl sulphide see Dimethyl sulphide. Methyl sulphuric acid see Sulphuric acid mono methyl ester. Methyl sulphurous acid see Sulphurous acid mono methyl ester. Methyltartaric acid see Tartaric acid mono methyl ester. /3-Methyltetramethylene diamine. C6HuN2=NH2.(CH2)2.CHMe.CH2.NH2. ks XlO* at 25° = 5.6 aq.; about 16% too high. A(64) = 33.8, (256) = 60.6, (oo) = 197; 271. B.2HC1 at 25°, A(32) = 104.6, (1024) = 125.6; 270. 4-Methylthiazole-5-carboxylic acid. C6H6O2NS. kiXlO^ at 25°=3.9; increases on diln. A(131.1) = 65.8, (1048.4) = 163.8, (oo) = 357; 175. 2-Methylthiazole-4,5-dicarboxylic acid. CeHsOdNS. kxXlO^ at 25°= 7; diminishes on diln. m(98.9) = 317.5, (1581.6>=355, (cx>) = 357; 175. meso-Methylthiazolemethylcarboxylic acid see 2,4-Dimethyl-thiazole- 5-carboxylic acid. Methyl thiocarbimide. (Methyl mustard oil.) C2H3NS=CSN.Me. XX 10' at 50°= 3.3; b. p. 117° @ 758 mm.; 1843. As solvent; 1844. Methyl thiocyanate see Thiocyanic acid methyl ester. Methylthio-phenyl- see Phenyl-methylthio- Methyl-thio-uracil. C6H6ON2S. kAXlO^at 25°=5. m(512) = 1.7, (1024) = 2.4. Na.A at 25°, m(32) = 241.0, (1024) = 346.3; 1748. 6-Methyl-2,3-triazo-4-hydroxy-7,0"-pyridazine. C6H60N4=Me.C6H2N4.0H. kAXlO^ at 25°=1.74; decreases on diln. A(256) = 24.3, (1024) = 43.8, (a>) = 376; 305a. /um.-a-Methyltricarballylic acid, (trans- acid). C7Hio06=C02H.CH2.CH(C02H).CHMe(C02H). kiXlO^ at 25°=3.2; increases on diln. m(32) = 33.4, (1024) = 153.3, (<»)=352; m. p. 180°; 1839; - 237, 67. ma/.-a-Methyltricarballylic acid, (as- acid). C7H10O6. kAXlO* at 25°=4.8; increases on diln. m(20.6) = 32.8, (165.1) = 90, (00)= [351]; m. p. 134°-135°; 237. Mor] TABLES 217 ma/.-a-Methyltricarballylic acid mono methyl ester. CgHisOe. kAXlO^ at 25° = 8.93;=8.57 and 8.88 for other preparations; 237. [The methyl group may be in different places in these three. ] Methyltriethyl ammonitim chloride. C7Hi8NCl=MeEt3NCl. At 25°, A(32) = 90.2, (1024) = 102.0; 270. sym.-Methyltrimethenyl-dicarboxylic acid. C6H604=Me.C3H(C02H)2. kAXlO*=5.9; increases, then diminishes on diln.; m. p. 200°. Ai(64) = 62.8, (1024) = 191.9, (oo) = 356; 559. Methyltriphenyl phosphonium chloride. CigHisClP = (Me) (Phs) PCI. At 25°, A(32) = 80.2, (1024) = 91.3; 270. Methyltriphenyl phosphonium iodide. Ci9Hi8lP= (Me) (Ph3)PI. In SO2; 1855. Methyluracil. C6H6O2N2. kiXlOi" at 25° = 3.14 (catal.); 1996;=46 (cond.); 1748. At 25°, m(64) = 0.19, (1024) = 0.87, («>)= [356]; 1748. Methyl urea. C2H60N2=NH2.CO.NHMe. Cond. with HCl; 781. B.Oxalate at 25°, ai(32) = 176.1, (1024) = 228.1; 1748. O-Methyl-iso-urea. C2H60N2=NH2.C(OMe) ;NH. ksXlO^ at 25°=6.4; diminishes on diln.; m. p. 44°-45°; 285, 286. A(32) = 10.6, (512) = 37.4, (oo) = 239.6. B.HClat25°, A(32) = 104.1, (512) = 115.7, (1024) = 118?; 286. 7-Methyl xanthine. (Heteroxanthine. 7-Methyl-2,6-dioxy-purine.) C6H6O2N4. kiXlO" at 40.1°=4.02 (solub.). ks XlO" at 40.1°=1.18 (solub.); 1997. Milk; see also Casein. [The references to this are incomplete.] Cond.; 253, 308, 1072, 1511a. Concentration of H and OH ions; 422, 587. Molybdenum. Complex salts; 692, 1162, 1163, 1269, 1495, 1515, 1516, 1572. See also the following compounds. Molybdenum cyanic acid. C8H4N8Mo=H4Mo(CN)8. 4K.A at 25°, A(32) = 119.3, (1024) = 166.0; 376. A(32) = 118.7, (1024) = 167.7; 1517. Molybdenum oxalic acid. Complex salts; 692, 1495, 1515, 1516. Molybdenum thiocyanic acid. Complex salts; 1162, 1163. Morphine. C17H19O3N. kBXl0« at 18°=1; m(2134) = 9.48, (») = 195; 1224. At 25°, kxl0«=20 aq.; m(1708) = 32.6; 1241. [It is evident from 218 TABLES [Muc the difference in cond. of these two measurements that at least one of them is in error. ] n of satd. soln. at 0° = 1.31 xlO"^; 943.- Also 1224, 1241, for cond. In HON; 943. B.HCl at 18°; 1224. At 25°, A(32) = 78.4, (1024)=90.7; 270. With allyl thiocarbimide, no cond.; 1223. - B.HNO3. - 2B.H2SO4; 1611. - B.MeCl; 270. Mucic acid. C6Hio08=(CHOH)4(C02H)2. kA XlO^ at 25°=6.3 aq.; diminishes, then increases on diln.; m. p. 213.5°; 1186; (colorim.); 1781. At 25°, m(60) = 62.2, (960) = 186, (co) = 352; 1186. In NH3, qual.; 606. In Et ale; 1185. Cond. with boric acid; 1185, 1186. Mucous membrane. [The references to this are incomplete.] E. m. f.; 622a. Murexide see Purpuric acid; ammoniimi salt. Muscle. [The references to this are incomplete.] Cond.; 251, 252, 253, 622a, 624, 1655b. Mustard oils see Thiocarbimides. Mustard oil acetic acid see Diketo-tetrahydro-thiazole. N. Naphthalene. CjoHs. Resistance when solid, and when molten; 983a. In NH3, qual. ; 606. In acetonitrile, no cond. ; 936. In MeNHa, no cond.; 637. Cond. with AICI3 and EtBr; 1893. With benzene and toluene; 384. With picric acid in SO2; 1842. Naphthalene Red. (Magdala Red). [The dye is a mixture of aminonaphthyl-naphthazonium compounds. ] Effect of light on cond.; 833, 1321. Naphthalenesulphonecyamic acid see Naphthalene sulphonic acid cyanoamide. Naphthalenesulphonecyanoamide see Naphthalene sulphonic acid cyanoamide. a-Naphthalene sulphonic acid. CioH803S=CioH7.S03lI. At 25°, A(32) = 318.9, (1024) = 351.7; 1366. Li.A. - K.A; 1366.- Ag.A; 1111.- Na.A at 25°, A(32) = 65.0, (1024) = 78.4; 1366. a-Naphthalene sulphonic acid cyanoamide. (o-Naphthalenesulphone- cyamic acid. a-Naphthalenesulphonecyanoamide). CiiH802N2S=CioH7S02.NH(CN). Nap] TABLES 219 kA XlO^ at 25°= 1.6. [Incorrect in the original.] A(1950) = 57.7, (3900) = 76.4, (oo) = 354; 70. /3-Naphthalene sulphonic acid. CioH803S=CioH7.S03H. kAXlO' at 25°=2.7 aq. A(39.9) = 360.3, (1278) = 378.1, (oo) = 378.2; m. p. 122°-124°. K.A. - Na.A at 25°, A(256) = 76.7, (1024) = 79.6; 1940. j3-Naphthalene sulphonic acid cyanoamide. (/3-Naphthalenesul- phonecyamic acid. |3-Naphthalenesulphonecyanoainide). CiiH802N2S=CioH7S02.NH(CN). kAXl0^at25°=6.9. A(2368) = 113.2, (4736) = 135.1, (°°) = 354; 70. 1,4-Naplithalene sulphonic acid azo-|S-naphthol. C20H14O4N2S. 2Na.A (Roccelline) at 18°, ai(32) = 102-115. Cond. with H2SO4; 1796, 1798. Naphthalic acid see Hydroxy-naphthoquinone. o-Naphthoic acid. (Naphthalene-1-carboxylic acid). CuH802. kAXlO* at 25°=2; m. p. 160°; 175, 71. A(2133) = 167, (00) = 350; 175. Cond. with NaOH; 1017. ^-Naphthoic acid. (Naphthalene-2-carboxylic acid). C11H8O2. kAXlO^ at 25°=7; m. p. 182°; 175, 71;=5; 70. A(3124) = 128.3, («') = 350; 175. Cond. with NaOH; 1017. o-Naphthol. (1-Hydroxy-naphthalene.) C10H8O. kiXlO* at 25° is about 1. A(500) = 0.80, (1000) = 1.15; 1823. In HBr; 29. In NH3, qual.; 606. In MeNHa, good cond.; 637. /3-Naphthol. (2-Hydroxy-naphthalene.) CioHgO. In HBr; 29. In NH3, qual.; 606. -In MeNHa, good cond.; 637. Cond. with picric acid; 1042, 1842. /3-Naphthol Violet see Meldola Blue. Naphthol Yellow see 2,4-Dinitro-l-naphthol-7-sulphonic acid. a-Naphthonitrile. CiiH7N=CioH7.CN. InHCN, nocond.; 943. j8-Naphthonitrile. C11H7N. InHCN, nocond.; 943. o-Naphthyl amine. (1-Amino-naphthalene.) C10H9N. ksXlOi" at 15°=2.8 (colorim.); 1777. At'25°=0.99 (part.); 648. In HBr, HI and H2S, no cond.; 1897. In NH3, qual.; 606. In benzene, alone and with picric acid, no cond.; 1802. B.HCl at 25°, A(100) = 112.2, (400) = 124.8; 1864. Effect of diazotization on cond.; 1601.- 2B.H2SO4; 1864. /3-Naphthyl amine. (2-Amino-naphthalene.) C10H9N. ksXlO"* at 15°=3.9 (colorim.); 1777. At 25°=2.0 (part.); 548, 220 TABLES [Nap In HBr, little cond. In HI, no cond.; 1897. In HaS, no cond.; 27, 1897. In NH3, qual.; 606. In benzene, alone and with picric acid, no cond.; 1802. B.HCl at 25°, A(100) = 105.6, (400) = 118.5; 1864. Effect of diazotization on cond.; 1601.- 2B.H2SO4; 1864. l-Naplithylamine-2,4-disulphomc acid. CioH906NS2=NH2.CioH6(S03H)2. [NH2=1; HS03=2,4.] (Colorim.) [ki XlO* is about 1.7]; 1773. l-Naphtliylaimne-2,5 [?]-disulphonic acid. C10H9O6NS2. [NH2=1; HS03=2,5 [?].] At 25°, Ai(64) = 317.2, (1024) = 377.4; 492. l-NaphthyIamine-4,6-disulphonic acid. C10H9O6NS2. [NH2=1; HS03=4,6.] At25°,Ai(64) = 197.6, (1024) = 313.8, (CO )= [350]; 492; (colorim.) 1773. l-Naptitliylamine-4,7-disulphonic acid. CioHgOeNSa. [NHj^l; HS03=4,7.] At 25°, m(32) = 174.0, (1024) = 335.6, (00)= [350]; 492; (colo- rim.); 1773. Na.A (Dahl's salt); catal. shows that one sulphonic acid group is much dissociated, the other is little dissociated; 957. l-Naphthylamine-4,8-disulphonic acid. C10H9O6NS2. [NH2=1; HS03=4,8.] Almost no acid reaction; (colorim.); 1773. l-Naphthylamine-5,7?-disulphomc acid. C10H9O6NS2. [NH2=1; HS03=5,77.] No acid reaction; (colorim.); 1773. 2-Naphthylamine-3,6-disulphonic acid. C10H9O6NS2. [NH2=2; HS03=3,6.] About as strong as the l-Naphthylamine-4,7-disulphomc acid (colorim.); 1773. 2-Naphthylamine-4,8-disulphoiiic acid. C10H9O6NS2. [NH2=2; HS03=4,8.] At 25°, /t(64) = 112.8, (1024) = 226.4, (00)= [350]; 492. [From this measurement kA X 10' is about 2. ] 2-Naphthylamine-6 , 8-disulphonic acid . CioHgOsNSs. [NH2=2; HS03=6,8.] No acid reaction (colorim.) ; 1773. l-Naphthylamine-2-sulphonic acid. CioH903NS=NH2.CioH6.S03H. [NH2=1; HS03=2.] kAXlO^ at 25°=2.2; diminishes on diln.; 492, 504; (colorim.); 1773. At 25°, M(64) = 238.0, (1024) = 327.6, (oo) = 351; 492. Nap] TABLES 221 l-Naphthylamine-4-sulphonic acid. C10H9O3NS. [NH2=1; HS03=4.] kAXlC at 25°=2; diminishes on diln.; 492, 504. At 25°, m(1024) = 258.7, (2048) = 282.8, (co) = 351; 492. l-Naphthylamine-5-sulphomc acid. C10H9O3NS. [NH2=1; HS03=5.] kxXlO* at 25° = 2.4; diminishes on diln.; 492, 504; (colorim.); 1773. At 25°, m(256) = 77, (1024) = 130.5, (°o) = 351; 492. l-Naphthylamine-6-sulphonic acid. C10H9O3NS. [NH2=1; HS03=6.] kAXlO^at 25°=1.96; 492,504; (colorim.); 1773. At 25°, m(256) = 70.3, (1024) = 126.0, (00) = 351; 492. l-Naphthylaniine-7-sulpliomcacid. C10H9O3NS. [NH2=1; HS03=7.] kAXlO* at 25° = 2.3; diminishes on diln.; 492, 504; (colorim.); 1773. At25°, Ai(128) = 55, (1024) = 132, (co) = 351; 492. l-Naphthylamine-8-sulphonicacid. C10H9O3NS. [NH2=1; HS03=8.] kxXlO^ at 25°= 1.02; 492, 504. No acid reaction, (colorim.); 1773. At 25°, m(1024) = 34.1, (2048)=47.4, (oo) = 351; 492. 2-Naphthylamine-l-sulphonicacid. C10H9O3NS. [NH2 = 2; HS03=1.] About the same strength as the l-Naphthylamine-2-sulphonic acid, kxX 10^=2.2 (colorim.); 1773. 2-Naphtliylamine-5-sulphomcacid. C10H9O3NS. [NH2=2; HS03=5.] kAXlO^at 25°=9.4; 492; (colorim.); 1773. At 25°, Ai(256) = 50.3, (1024) = 93.2, (oo) = 35i; 492. 2-Naphthylamine-6?-suIphonic acid. C10H9O3NS. [NH2=2; HS03=6?.] kAXlO* at 25°=1.7; 492; (colorim.); 1773. At 25°, m(1024) = 118.1, (oo) = 35i; 492. 2-Naplithylaniine-7-sulphonicacid. C10H9O3NS. [NH2=2; HS03 = 7.] kiXlO^at 25°=1.0; 492; (colorim.); 1773. At 25°, Ai(512) = 71.6, (1024) = 96.6, (co) = 351; 492. 2-Naphthylamine-8-sulphonicacid. C10H9O3NS. [NH2=2; HS03=8.] kAXlO^ at 25°= 1.2; 492. No acid reaction, (colorim.); 1773. At 25°, m(512) = 77.6, (1024) = 104.3, (oo) = 351; 492. l-Naphthylamine-2,4,7-trisulphoEdc acid. CioH909NS3 = NH2.CioH4(S03H)3. [NH2=1; HS03=2,4,7.] At 25°, m(96) = 180.6, (1536) = 233.1; 492. [kA is of the order of 10^.] l-Naphthylamine-3,6,8-trisulplionic acid. C10H9O9NS3. [NH2=1; HS03= 3,6,8.] 222 TABLES [Nap At 25°, m(96) = 185.4, (1536) = 270.3; 492. [kj, is of the order of lO-'.] a-Naphthylamino-acetic acid. (a-Naphthyl glycine). Ci2Hii02N= (CioH7)NH.CH2.C02H. IjaXIO^ at 25°=3.3; diminishes on diln.; m. p. 199°; 195, 1840. [k=4 is an extrapolated value.] A(1040) = 58.9, (2080)=78.1, (co) = 350; 1840. j8-NaphthyIamino-acetic acid. (|8-Naphthyl glycine). C12H11O2N. kAXlO^ at 25°=5.9; m. p. 133°-136°; 195, 1840. A(560) = 58.1, (1120) = 74.2, (oo) = 350; 1840. Naphthylamino-iso-butjmc acid acetyl derivative see Acetyl-/3- naphthyl-amino-iso-butyric acid. Naphthyl glycine see Naphthylamino-acetic acid. a-Naphthylimino-diacetic acid. Ci4Hi304N = CioH7.N(CH2C02H)2. kAXlO^ at 25°=5.1; m. p. 133°-134°. m(212) = 96, (848) = 166, (oo) = 348; 1840. /3-Naphthylimino-diacetic acid. C14H13O4N. kAXltf' at 25°= 2.5; diminishes on diln.; m. p. 182°-183°. m(200) = 173, (800) = 248, (oo)=348; 1840. jS-Naphthylnitroso amine. CioH80N2=CioH7.NH(NO). No cond. in aq., when pure; 500. Naphthylphenyl- see Phenylaaphthyl- Narcotine. C22H23O7N. kBXlO* at 17°=7.9 (colorim.); 1779. At 18°=8; 1224. At 18°, m(23837) = 8.3, (co) = l96; 1224. In HON, no cond.; 943. B.HCl at 18°, m(251.3) = 89.8, (1005.2) = 101.9; 1224. Nerium oleander. (Oleander) . [The references to this are incomplete. ] Cond. of sap; 253. Neurine see Vinyltrimethyl ammonium hydroxide. New Blue R see Meldola Blue. Nickel. Complex and "double" salts; 427, 971, 1384, 1481, 1482, 1734, 1752, 1755, 1832, 1946. See also the following compounds. Nickel carbonyl. C404Ni=Ni(CO)4. xXlO" at 0°=1; 1272; = 20; 28. At 20° and at -20°; 1272. Nickel cyanic acid. C4H2N4Ni=H2Ni(CN)4. 2K.A at 25°, A(32) = 126.2, (1024) = 146.6; 1832; 971. Nicotine. C10H14N2. At 25°, m(32) = 1.87, (1024) = 32.0; 1306. [This gives a value of ksXlO^ increasing from 0.3 to 3.] In HBr, fair cond. In HI and HjS, good cond. ; 1897. In HCN, no cond.; 943. In H2S; 1646. In NH3, qual.; 606. Nicotinic acid see Pyridine-3-ceirboxylic acid. Nit] TABLES 223 iso-Nicotinic acid see Pyridme-4-carboxylic acid. Night Blue. C38H41N3.HCI. The dye is the chloride of p-Tolyl-tetraethyl-triamino-diphenyl- a-naphthyl carbinol, with the formula given above. Cond. of soln. at 25°, showing the effect of dialysis; 186, 186a. Niobium see Columbium. Nitr- see Nitro- Nitric acid. HNO3. [The references to this are incomplete.] At 25°. V (16) (32) (128) (512) (1024) Unit = reciprocal ohm. A 383.8 389.1 389.5 390.5 392.3. (Tower, Conductivity of Liquids). Nitric acid amyl ester. (Amyl nitrate). C6Hii03N=N02.0CbHii. xXlO'at 25°=2.6. Cond. with Cu oleate; and as solvent; 1569. Effect of temperar ture on cond.; 106. Nitric acid fso-butyl ester. (wo-Butyl nitrate). C4H903N=N02.0C4H9. xXW^ at 25° is less than 2; b. p. 120°-124° @ 728 mm. Cond. with AgNOs and organic compounds; 1388. Effect of temperature on cond.; 106. Nitric acid ethyl ester. (Ethyl nitrate). C2H503N=N02.0Et. xXlO^ at 0°=2.26; b. p. 87.2° @ 767 mm.; 1844; 1843. At 25°= 1.0; 1847; 1844, 1569. Cond. with organic salts; 1569, 1844, 1847. Effect of tempera- ture on cond.; 106. As solvent; 1569, 1844, 1847. Nitric acid methyl ester. (Methyl nitrate). CH303N=N02.0Me. X XlO* at 25°=4.52; b. p. 64.4° @ 730 mm. Cond. with AgNOs and organic compounds; and as solvent; 1388. Nitric acid propyl ester. (Propyl nitrate). C3H703N=N02.0Pr. InHCN, nocond.; 943. Nitroacetaldehyde oxime see Ethylnitrolic acid. Nitro-acetaldehyde phenylhydrazone. C8H902N3= Me.C(N02) :N.NH.Ph. No cond. in aq. soln.; m. p. 141''-142°; 78. Nitroacetic acid ethyl ester. C4H704N=N02.CH2.C02Et. kA XlO^ at 25°=1.4; diminishes on diln. A(29.1) = 2.5, (465.8) = 9, (00)= [380]; 1092, 1567. Nitroacetone. C3H603N = Me.CO.CH:NO.OH. IcaXIO^ at 25°= 1.0; m. p. 49°. /i(32) = 6.4, (256) = 18.0, (oo) = 358; 1137.- 782. Qual.; 780. InEt ale; 782. 1^-Nitroacetophenone. (iso-Nitro- etc.). C8H703N= Ph.CO.CH :NO.OH. 224 TABLES [Nit kAXlO^ at 25° =6.3; increases on diln.; m. p. 108°. m(256)=41.1, (1024) = 79.2, (oo) = 350; 780.- 782. InEt ale; 782. Na.A at 25°, /[i(128) = 65.0, (512) = 70.0; 780. Nitro-aldehydo- see Aldehydo-nitro- Nitroamide. H202N2=N02.NH2. [The references to this are in- complete.] kiXlO^ at 0° is about 3. ai(26.8)=0.85, (63.1) = 1.13; 141, 145, 765. In NHs; 610. Nitroamino- see Aminonitro- Nitroanilic acid. (3,6-Dimtro-2,5-dihydroxy-p-benzoquinone). CeHjOsNs. /i(31.6) = 634.1; decomposes in soln. ; 729. o-NitroaniUne. C6H602N2= NO2.C6H4.NH2. No acid properties (part.) ; 548. ksXlO" at 25°=1.5 (solub.); 659, 1116;=0.56 (part.); 548. In benzene, alone and with picric acid, no cond. ; 1802. B.HCl at 25°, A(IOO) = 378.3. - B.H2SO4; 1864. m-Nitroaniline. C6H6O2N2. kaXlQi^ at 17°=3.2 (part.); 583. At 25°=4 (solub.); 1116; (part.); 548. In HBr, HCl and H2S, no cond.; 1897. In NH3, little or no cond.; 606, 610. In benzene, alone and with picric acid, no cond.; 1802. B.HCl at 25°, A(50) = 182.1. - B.H2SO4; 1864. p-Nitroaniline. C6H6O2N2. ksXlQi^ at 25°=1.1 (solub.); 1116; = 0.12 (part.); 548. In HBr and H2S, no cond.; 1897. In NH3, little or no cond.; 606, 610. 3-Nitroaniline-6-sulphonic acid. C6H606N2S=NH2.C6ll3(N02).S03H. [NH2=1; N02=3; HS03=6.] kiXlC at 25° = 8. 5; increases on diln. A(64) = 180, (512) = 324.1, (oo) = 355; 492. p-Nitroanisole. (l-Methoxy-4-Nitrobenzene. p-Nitrophenol methyl ether). C7H703N=N02.C6H4.0Me. In aq. and in Me ale, very small cond. In HCO2H, no cond.; 746. In NH3, qual.; 606. Nitrobarbituric acid. C4H3O6N3. At 25°, M(32) = 323.4, (512) = 341.4, (oo) = 356; 845. 1748. Cond. with NaOH; 845. Na.A at 25°, m(32) = 67.0, (1024) = 77.1; 1748. Nit] TABLES 225 m-Nitrobenzaldehyde. C7H503N= NO2.C6H4.CHO. In NH3, qual.; 606. In MeNH2, little oond.; 637. p-Nitrobenzaldehyde. CrHsOaN. kiXlQi^ at 18° is about 3 (hydroL). Cond. with NaOH; 632. Nitrobenzamide see Nitrobenzoic acid amide. Nitrobenzene. C6H602N = Ph.N02. 7t at 0° is extremely small; 923. At 20°, j<:X10'=1.8; 1590a. At 25°, KXW is less than 0.2; 517, 923, 1388;= 1.13; 1844; - 941, 1106, 1107, 1569. In HBr and HI, good cond. In H2S, no cond. ; 1897. In NH3, qual.; 606. In MeNH2, little cond.; 637. Cond. with HCl; 1553. With inorg. and organic compounds; 923, 941, 1106, 1107, 1223, 1388, 1569, 1844. Dielectric constant; 582. As solvent, under pressure; 1590a. As solvent; (147), (291a), (293), 923, (941), (1444a), 1569, 1590a, (1818), 1844. p-Nitrobenzene-azo-a-naphthol sulphonic acid. Ci6Hii06N3S=OH.CioH6.N2.C6H3(N02).S03H. kA is about the same as that of phenolphthalein (colorim.) ; 818. p-Nitrobenzene diazonium hydroxide. (p-Nitro diazo benzene). C6H603N3 = N02.C6H4.N2.0H. kA XlC at 0° decreases, from 8.8 to 4.0, on account of decompo- sition. A(128) = 12.9; 501. Na.A at 0°, A(1024-32)=4.8. At 25°, A(32) = 66.2, (1024) = 77.1; 774. iso-p-Nitrobenzene diazonium hydroxide. (p-Nitrophenylnitrosoa- mine). C6H6O3N3. B.C1(=N02.C6H4.N2.C1) at 0°, A(512) = 75.5; 501. m-Nitrobenzene sulphimide. In MeNH2, good cond.; 637. o-Nitrobenzene sulphonic acid amide. C6H604N2S= NO2.C6H4.SO2NH2. Cond. with NaOH; 781. m-Nitrobenzene sulphonic acid. C6H605NS=N02.C6H4.S03H. At 25°, A(32) = 326.0, (1024) = 355.6; 1366. Li.A. - K.A; 1366. In NH3; 607. - Na.A at 25°, A(32)=68.0, (1024) = 78.8; 1366. Alone and with Na^S; 660a. m-Nitrobenzene sulphonic acid amide. C6H604N2S= NO2.C6H4.SO2NH2. In NH3; 607, 610. In MeNH2; 605. Cond. with NaOH; 781. p-Nitrobenzene sulphonic- acid amide.^ ,C6H604N2S. Cond. with NaOH; 781. 226 TABLES [Nit o-Nitrobenzoic acid. C7H604N=N02.C6H4.C02H. k diminishes on diln. in almost all these measurements. See 1342 for explanation that this is not due to impurity. kAXlO« at 0°=10 aq.; 515. At 10°=7.6. At 15°=7.07; 1342. At 18°= 7 (colorim.) 1563. At 20°= 6.56; 1342; = 6.96 aq.; 515. At 25°=6.15; 515, 656, 1371, 1581; (hydrol.); 1972, 1973;=6.02; m. p. 146.33° cor. and 146.27° cor.; 1342. At 30°=5.86aq.; 515; = 5.48; 1342. At 35°=5.39 aq.; 515. At 40°=4.94 aq.; 515, 1581. At 45°=4.53 aq.; 515. At 50°= 4.14 aq.; 515, 1581. At 60°=3.4 aq. At 70°=2.8 aq. At 80°=2.4 aq. At 90°=1.9 aq. At 99°=1.6 aq.; 1581. [Values in 1581 are approximate. ] Of satd. or nearly satd. soln., at 25°=6.03; 1342. Cond. at 0°-35°; 515, 911, 1342. At 25°-99°; 1681, 515. At 25°, A(32) = 140.2, (128.2) = 223.8, (a') = 396.9; 1342. A(128) = 205.3, (1024) = 312.3, (co) = 355; 1371. In HBr, no cond.; 30. In HCN, small cond.; 943. In NH3, qual.; 606. In Et ale; 647 and 144, 1820. In MeNHj, good cond.; 637. In pyridine; 754. Na.A at 25°, A(32) = 66.7, (1024) = 76.4; 1368a. At 25°-99°; 1581. m-Nitrobenzoic acid. C7H6O4N. kAXlO* at 0°=2.98 aq.; 515. At 18° = 3.5 (colorim.); 1563. At 20°=3.35 aq.; 515. At 25° = 3.45; 1371, 515, 1581. At 30°=3.43aq.; 515. At 35° = 3.45 aq.; 515. At40°=3.47 aq.; 515, 1581. At 45°=3.47 aq.; 515. At 50°=3.48 aq.; 515, 1581. At 60°=3.5 aq. At 70°=3.3 aq. At 80°=3.1 aq. At 90°=2.9 aq. At 99°=2.6 aq.; 1581. [Values in 1581 are approximate.] Cond. at 0°-35°; 515, 911. At 25°-99°; 1581, 515. At 25°, A(64)=48.7, (1024) = 157.6, (co) = 355; 1371. In HBr and HCl, small cond.; 30. In NH3, qual.; 606. In N2O4, no cond.; 602. Na.A at 25°, A(1000) = 78.3; also at 0°-50°; 515. At 25°-99°; 1581. m-Nitrobenzoic acid amide. C7H603N2=N02.C6ll4.CONIl2. Cond.; 1479. p-Nitrobenzoic acid. C7II5O4N. kiXlO^ at 18°=4 (colorim.); 1563, 1781. At 25°=4.01; dimin- ishes on diln.; 1371. At 25°, A(256) = 97, (1024) = 164.7, (oo) = 355; 1371. In HBr, no cond.; 30. In NH3, qual.; 606. Na.A at 25°, A(32) = 67.4, (1024) =76.4; 1368a. At 25°-99°; 1581. Nit] TABLES 227 p-Nitrobenzoic acid amide. C7H6O3N2. Cond.; 1479. o-Nitrobenzoyl-malonic acid diethyl ester. Ci4Hi607N=C6H4(N02).CO.CH(C02Et)2. kAXlO* at 25°=2.08. /i(1200) = 136, (2400) = 174, (oo) = 349. K.A. - Na.A at 25°, /i(32) = 61.1, (1024)=70.2; 1823, 1831. 2-Nitro-3-bromobenzoic acid. C7H404NBr=N02.C6H3Br.C02H. [C02H=1; N02=2; Br=3.] kiXltf' [at 25°] = 3.4. A(1024) = 287, (c°) = 353; 849. 3-Nitro-2-bromobenzoic acid. C7H404NBr. kAXlO^ [at 25°] = 1.16. A(256) = 278, (1024) = 328, (oo) = 353; 849. 6-Nitro-2-bromobenzoic acid. C7H404NBr. kAXlC [at 25°] = 9.1; increases on dUn. A(256) = 266, (1024) = 324, (oo) = 353; 849. 6-Nitro-3-bromobenzoic acid. C7H404NBr. kAXlO^ at 25°= 1.5; increases on diln.; 849;= 1.4; diminishes on diln.; 1371. A(256)=290, (512) = 318, (d°) = 355; 849. Nitrobromomethane. CH202NBr=CH2(N02)(Br). A(32) = 0.1; b. p. 145°-146°; 780. Nitrocaproic acid. C6H11O4N = CsHio(N02) .CO2H. kAXlO* at 25°= 1.23; diminishes on diln. A(64) = 29.9, (1024) = 102.5, (oo)=352; 1370. Nitrocarbamic acid ethyl ester. (Nitro-urethane) . C3H604N2= N02.NH.C02Et. kAXlO*at 0° = 3.03. At 10° = 3.85; 143. At 20° =4.83; 143;= 3.9; 767. At 30°= 5.71. At 40° = 6.44; 143. Cond.; 141, 143, 782. At 20°, A(32) = 40.9, (256) = 104.4, (co) = 351.9; 143. In Et ale; 754, 782. In piperidine and in pyridine; 754. NH4.A in NH3; 610. - Na.A at 0°-40°; at 20°, A(1000) = 100.5; 143. m-Nitrochlorobenzene. C6H4O2NCI. In NH3, qual.; 606. p-Nitrochlorobenzene. C6H4O2NCI. InNHs, qual.; 606. 2-Nitro-3-chlorobenzoic acid. C7H404NC1=N02.C6H3C1.C02H. [C02H=1; N02=2; Cl=3.] kAXlO' [at 25°]=4.5; diminishes on diln. A(512) = 268, (1024) = 298, (co) = 356; 849. 228 TABLES [Nit 2-Nitro-4-chlorobenzoic acid. C7H4O4NCI. IcaXIO^ at 25°= 1.0; diminishes on diln. A(245.7) = 271.4, (982.8) = 317.7, (00) = 356; 175. 3-Nitro-2-chlorobenzoic acid. C7H4O4NCI. kAXlO^ [at25°]=8.7; m. p. 185°. A(256) = 267, (1024) = 323, (co) = 356; 849. 3-Nitro-4-chlorobenzoic acid. C7H4O4NCI. IjaXIO^ at 25°=4.6; diminishes on diln. A(390.5) = 122.8, (1562) = 196.9, (oo) = 356; 175. 4-Nitro-2-chlorobenzoic acid. C7H4O4NCI. kiXlO^ at 25°= 1.03; diminishes on diln. A(32.1) = 153.8, (514.1) = 302.2, (oo) = 356; 175. 5-Nitro-2-clilorobenzoic acid. C7H4O4NCI. kxXlO^ at 25°= 6.5; diminishes on diln.; 175, 849. A(256) = 252, (1024) = 309, (co) = 356; 849. 6-Nitro-3-chlorobenzoic acid. C7H4O4NCI. kiXlO^ at 25°=1.44; diminishes on diln.; 849;=1.52; dimin- ishes on diln. ; 175. A(256) = 291, (1024) = 333, (oo) = 356; 849. 4-Nitro-2-chlorophenol. C6H403NC1=N02.C6H3C1.0H. [0H=1.] kAXlO*at25°=1.8. A(345.2) = 78.6, (1380.8) = 137.1, («>) = 354; 70. 3-Nitro-4-chlorotoluene. C7H6O2NCI. InNHs, qual.; 606. o-Nitrocinnamic acid. C9H7O4N. In NH3, qual.; 606. m-Nitrocinnamic acid. C9H704N=N02.C6H4.CH:CH.C02H. Na.A at 25°, A(32) = 64.1, (1024) = 76.5; 1367. p-Nitrocinnamic acid. C9H7O4N. Na.A at 25°, A(32) = 64.8, (1024)=77.0; 1367. S-Nitrocuminic acid. CioHii04N=C3H7.C6H3(N02).C02H. kiXlO^at 25°=2.15. A(2008) = 167.8, (4016) = 207.3, (00) = 350; 175. p-Nitro diazo benzene see p-Nitrobenzene diazonium hydroxide. 4-Nitro-2,6-dichloro-ph.enol. C6H303NCl2= NO2.C6H2CI2.OH. [0H= 1. ] kAXlO^at 25°=2.1. A(374) = 84.1, (1496) = 151.2, (co) = 353; 70. Nitro-l,4-dimethoxy-benzene see Nitro-hydroquinone dimethyl ether. Nitro-dimethyl-aniline sulphonic acid. C8Hio06N2S=NMe2.C6H3(N02).S03H. At 25°, A(32) = 82.9, (1024) = 90.6, (°o) = 353; [this gives a value of ki diminishing from 2x10"^ to 8X10^']; 492. Nit] TABLES 229 Nitroethane. C2Hb02N=C2H6.N02. No cond. in aq. soln. The salts are really the salts of iso- nitroethane. Cond. with NaOH and Ba(0H)2 showing change to isomer; 780. [The salts are described here, on account of their mode of preparation and the doubt as to the structure of the isomer. ] K.A, cond. with HgNOs; 149. - Na.A at 25°, A(32) = 69.0, (1024) = 81.9; 1686. jso-Nitroethane. C2H5O2N. The pure compound would be as strong as acetic acid, as shown by cond. of salts. At 0°, A(48) = 9.4; 780. Salts; see under Nitroethane. Nitroform see Trinitro-methane. a-Nitrofonnaldehyde phenylhydrazone, m. p. 74.5°-75.5° and /3-Nit- roformaldehyde phenylhydrazone, m. p. 84.5°-85.5°. C7H702N3=N02.CH:N2H.Ph. [The references are to both compounds.] In aq. soln., almost no cond.; 82; - 78, 1593. Cond. in Me and Et ale; 1593. Cond. with NaOH and HCl; 82, 1593. Na.A; 82, 1593. Nitroguanidine. CH402N4= NO2.N :C(NH2)2. ksXlO" at 40.2°=2.1 (catal.); 1995 and 1150. In NH3; 610. Nitrohemipinic acid. CioH908N=(MeO)2C6H(N02)(C02H)2. [C02H=1, 2; 0Me=3, 4; N02=6.] kAXlO^ [at25°] = 2.1; increases on diln. A((32) = 205.4, (256) = 335.7, (c») = 374; 1684. Nitro-hydroquinone dimethyl ether. (Nitro-l,4-dimethoxy-benzene). C8H9O4N. Cond. in aq. and in Me ale, very small; in HCO2H, no cond. ; 746. 3-Nitro-2-hydroxy-benzoic acid. (o-Nitrosalicylic acid). C7H605N=OH.C6H3(N02.).C02H. kAXlO^ at 25°=1.57; diminishes on diln.; m. p. 146°; 1186, 1371, 1365. A(128) = 260, (1024) = 335, (oo)=355; 1371. InEtalc; 1185, 1508, 1718. Cond. with boric acid; 1185, 1186. With NaOH; 1508, 1718. 6-Nitro-2-hydroxy-benzoic acid. (p-NitrosalicyUc acid). CjHbObN. kAXlO' at 25°=8.9; 1371;=8.0 aq.; m. p. 228°-228.5°; 1186, 1365. A(256) = 267, (1024) = 322, (oo) = 355; 1371. InEtalc; 1186, 1508, 1718. Cond. with boric acid; 1185, 1186. With NaOH; 1508, 1718. 230 TABLES [Nit Nitro-4-hydroxy-3-methoxy-benzoic acid see Nitrovanillic acid. Nitromalonic acid amide. C3H604N3=CH(N02)(CONH2)2. kAXlO* at 25°= 5.9; diminishes on diln. /i(128) = 90.9, (512) = 157.3; 745; 1567. Nitromalonic acid diethyl ester. C7Hii06N=CH(N02)(C02Et)2. kiXlO^at 25°=7.3. m(81.6) = 81.2, (163.1) = 108.4; 745; 1567. Nitromethane. CH302N = Me.N02. xxW at 0°=4.43; b. p. 101.5° @ 757 mm.; 1843; - 1844. At 18°=6.4; 291. At 25°=5.44; 1843; - 1844, 1423a. kAXlQi^ at 25° is about 7; 1092. Cond.; 780, 1092. At 25°, A(10.3) =0.003, (co) = 389; 1092. In NH3; 607. In Et ale; 754. In MeNH2, fair cond.; 637. In pyridine, no cond.; 754. Cond. with Ba(0H)2; 780. As solvent; 291, 1423a, 1844, 1848, 1853a. Na.A at 25°, A(32) = 84.4, (1024) = 108.6; 1686. In NH3; 610. iso-Nitromethane. CH3O2N. Very weak acid (cond.) ; 780. Nitron see Diphenyl-endanilodihydro triazole. l-(a)-Nitronaplithalene. CioH702N=CioH7.N02. In H2S, no cond.; 27. Nitroopianic acid. CioH907N=(MeO)2C6H(N02)(CHO).C02H. IC02H=1; 0Me=2, 3; N02=5; CH0=6.] kiXlO^ [at25°] = 2.9; 1684,1906. A(256) = 10.1, (1024) = 19.5, (co) = 375; 1684. o-Nitrophenol. C6H603N=N02.C6H4.0H. kiXlO* at 0°=6 aq.; 733. At 18°=5.6 (cond. and hydro!.); 524. At25°=6.8; 847;=5.6; 746;=7aq.; 733; =40; 70. At 35° = 8 aq.; 733. Cond.; 614, 1362. At 25°, A(100) = l, (800) = 2.6, (oo) = 355; 847. In HBr, HCl and HI, fair cond.; 1897. In H2S, no cond.; 27, 1897. In NII3; 604, 607. In Et ale; 1508, 1718. In pyridine; 754. Cond. with NaOH; 1508, 1718. With cinchonine; 1620. m-Nitrophenol. CeHsOsN. kAXlO^at 10°=0.33. At 15° =0.39; 1150a. At 25°= 1.0; 847;= 0.53; 1150a, 524; 70. At 40°=0.77. At 50°=0.95; 1150a. Cond.; 614, 1362. At 25°, A(50) = 0.21, (200) = 0.56, (a>) = 355; 847. In Et ale; 1508, 1718. In pyridine; 754. Cond. with NaOH; 1508, 1718. Nit] TABLES 231 p-Nitrophenol. CeHsOaN. kAXlQS at 0°=5 aq.; 733. At 10''=4.5 (hydro!.). At 15°=5.2 (hydro!.); 1144. At 18° =5.8 (cond. and hydro!.); 524; = 23 (co!orim.); 1562. At 25°=6.4 (solub.); 1116; (cond.); 847; =7.0 (hydro!.); 1144;=4.4 (catal.); 733 and 1150;= 10 (neutra!.); 299; (cond.); 733; - also 70, 746. At 35°= 15 aq.; 733. At 40°= 10.2 (hydro!.). At 50° = 12.7 (hydro!.); 1144. Cond.; 614, 655, 733, 1144, 1362. At 25°, A(32)-=0.5, (512) = 2.2, (oo) = 355; 847. In NHs; 609; qua!.; 606. In Et a!c.; 1508, 1718. In pyridine; 754. Cond. with NaOH; 299, 1508, 1718. With cinchonine; 1620. With trimethyl-pyridine; 1144. Na.A at 25°, A(231.1) = 79.4, (923.0) = 81.8; 1144. At 0°-35°; 733. At 10°-50°; 1144;-655. p-Nitrophenol methyl ether see p-Nitroanisole. o-Nitrophenol-4-sulphonic acid. CeHeOeNS. K. A, cond. alone and with NaOH in Et ale. ; 1718. o-Nitropheno3cy-acetic acid. (o-Nitrophenyl-g!ycol!ic acid). C8H70sN=N02.C6H40.CHa.C02H. !cAXl0«at25°=1.58. A(64) = 95.1, (1024) = 244.6, (oo) = 351; 1370. p-Nitrophenoxy-acetic acid. (p-NitrophenyI-glyco!lic acid). CgHjOsN. IsaXIO^ at 25°= 1.56; diminishes on diln. A(128) = 125.6, (1024) = 241.6, (co) = 35i; 1370. Nitrophenoxy-malonic acid see Bis-mtrophenozy-malonic acid. Nitrophenyl-glycollic acid see Nitrophenozy-acetic acid. m-Nitrophenyl-nitromethane. C7H604N2= NO2.C6H4.CH2.NO2. At 25°, m(600) = 5-6; 1092; 844. The salts are from the isomeric NO2.C6H4.CH.NO.OH. At 25°, ^(320) = 132; 844. Na.A; 1092. p-Nltrophenyl-mtrosoamine. C6H603N3= NO2.C6H4.NH.NO. Cond. showing change to isomeric diazo compound; 501. o-Nitro-phenylpropioUc acid. C9H604N= NO2.C6H4.C ': C.CO2H. kAXlO^ at 25°= 1.08; diminishes on diln. A(256) = 272, (1024) = 322, (co) = 349; 1371. InNHs, qua!.; 606. Nitrophenyl-trimethyl- see Trimethyl-nitrophenyl- 3-Nitro-o-phthalic acid. (a-Nitrophthalic acid). CsH606N = N02.C6H3(C02H)2. [C02H=1,2.] 232 TABLES [Nit kA X 10^ at 25° is about 1.3. =1.2; aq. used for soln. was impure; 1372;= 1.3; 1909. In 1911 the value in 1372 is considered the better value. Second kAXl05=4.0; 1911. At 26°, m(32) = 164, (1024) = 342, (oo) = 352; 1372. Mg.A; 1836.- Na.A. - 2Na.A at 25°, m(32) = 76, (1024) = 93; 1838. 3-Nitro-o-phthalic acid 1-mono methyl ester. CgHvOeN. [C02Me=l; C02H. = 2.] kAXlO'' at 25°= 1.68; diminishes on diln.; m. p. 157°. m(63.9) = 235.4, (512.8) = 336.2, (oo) = 375; 1909, 1938. 3-Nitro-o-phthalic acid 2-mono methyl ester. CgHjOeN. [C02H=1; C02Me=2.] kA X 10' at 25° is about 2; diminishes on diln. ; not perfectly pure; m. p. 146°-149°. m(128) = 151.3, (1026) = 270.6, (oo) = 375; 1909, 1938. 4-Nitro-o-phthalic acid. (j3-Nitrophthalic acid). CgHsOeN. kAXlO' at 25°=7.7; m. p. 160°-160.5°; 1909; = 6; aq. used for soln. was impure; 1372. Second kAX 10^=4.0; 1911. At 25°, m(32) = 146.1, (1028) = 353.3, (oo)=376; 1909. 4r-Nitro-o-phthalic acid 1-mono ethyl ester. CioHgOeN. [C02Et=l; C02H=2.] kAXlO' [at 25°] =3.05; m. p. 127°; 1932. 4-Nitro-o-phthalic acid 2-mono ethyl ester. CioHgOeN. [C02H=1; C02Et=2.] kAXlC [at25°]=5.2; m. p. 137°; 1932. 4-Nitro-o-phthaUc acid?-mono methyl ester. CgHvOeN. kAXlO' at 25°=4.8; diminishes on diln.; m. p. 128°-129°. m(64) = 157.9, (1029) = 314.2, (oo) = 375; 1909. 2-Nitro-p-phthalic acid. (2-Nitroterephthalic acid). C8H606N = N02.C6H3(C02H)2. [C02H=1,4.] kAXl0^at25°=1.87; 1909. Second kAX 10*= 2.00; 1911. At 25°, iu(32) = 199.3, (256.4) = 333.9, (oo) = 376; 1909. 2-Nitro-p-phthalic acid 1-mono methyl ester. CgHvOeN., [C02Me=l; C02H=4.] kAXlO^at 25°=7.7; diminishes on diln. ; m. p. 174°-175.5°. ju(257) = 133.6, (1028) = 213.2, (co) = 375; 1909. 2-Nitro-p-phthalic acid 4-mono methyl ester. C9H7O6N. [C02H=1; C02Me=4.] kAXlO^ at 25°=1.98; diminishes on diln.; m. p. 133°-134°. m(64) = 247.4, (1027) = 355.4, (oo) = 375; 1909. Nit] TABLES 233 Nitropropane. C3H702N=Et.CH2.N02. B. p. 125°-127°. Na.A at 25°, A(32) = 67.8, (1024) = 80.8; too high, on account of increase of cond. on standing; 1686. 2-Nitropropane. (Nitro-iso-propane) . C3H702N=Me.CH(N02).Me. B. p. 115°-120°. Na.A at 25°, A(32) = 65.0, (1024)=93.1; approximate values; different measurements do not agree; 1686. a-Nitropropionic acid ethyl ester. C6H904N=Me.CH(N02).C02Et. kiXlO' at 0°=0.67; 1567. At 25°=4.6; diminishes on diln.; 1092, 1567. At 25°, A(39.7) = 1.6, (158.7) = 2.7, (oo)=[380]; 1092. Na.A, cond. with HCl; 1092, 1567. The preceding salt is formed from an isomeric ester Me.C.NO.- 0H.C02Et, kiXlO^ at 0°=5.85, extrapolated from cond. of Na.A+HCl. It changes in soln. to the true ester; 1567. ^-Nitropropionic acid. C3Hb04N=CH2(N02).CH2.C02H. kAXlO* at 25°=1.62; diminishes on diln. A(32) = 24.9, (512) = 86.3, (co) = 358; m. p. 65°-67°; 1840. Nitropropionic aldehyde phenylhydrazone. C9Hii02N3=Et.N02.C:N2H.Ph. No cond. in aq. soln.; m. p. 98.5°-99.5°; 78. Nitroprussic acid see Hydronitroprussic acid. 2-Nitroresorcinol. (2-Nitro-l,3-dihydroxy-benzene). C6H604N = N02.C6H3(OH)2. kAXlO=at25°=1.3. Ai(299) = 21.3, (1196) = 40.8, (co) = 354; 70. 4-Nitroresorcinol. (4-Nitro-l,3-dihydroxy-benzene). C6H5O4N. kAXlO«at25°=1.2. m(120)=3.9, (960) = 12, (co)=354; 70. Nitrosalicylic acid see Nitro-hydroxy-benzoic acid. Nitrosoacetic acid see Oximino-acetic acid. iso-Nitrosoacetoacetic acid ethyl ester. C6H904N=MeCO.C(:NOH)C02Et. kAXlO^ at 0° = 4.0 aq. At 18°=7.3 aq.; 1296. At 25°=8.6 aq.; m. p. 58°-59°; 1296; = 7.0; 1567. At 35°= 10.9 aq. At 40°= 11.8 aq.; 1296. At 25°, A(32) = 0.66, (64) = 0.97, (co) = 395.3; 1296. Na.A at 25°, A(32) = 67.6, (1024) = 79.7; 1296; 1567. iso-Nitrosoacetone. C3H602N= Me.CO.CH(NOH). kAXlO' at 18° is about 3 (colorim.). At 25° = 3.8 (catal.);=3 (cond.); m. p. 66°; 1141, 1143; = 2.7 (catal.); 752; - 547, 1092. ks XlO" at 25° is less than 1 (catal.); 1141, 1143. 234 TABLES [Nit At 25°, A(21.6) = 0.12, (43.2)=0.18, (oo) = 384; 1143. 647, 1092. NaA at 25°, A(32) = 68.8, (1024) = 81.2; 547. /3-Nitroso-benzymydroxylamine. C7H802N2=PhCH2.N(NO)OH. kAXlO«atO°=5.8. At25°=6.5. At25°, m(512) = 19.6; 736. 6-Nitroso-m-cresol. (Toluquinone-o-oxime) . C7H702N=Me.C6H3(NO).OH. kAXlO' at 25°=4; diminishes on diln. A(128) = 2.5, (1024) = 6.6. Na.A at 25°, A(32) = 65.9, (1024) = 76.6; 547. Nitrosocyano- see Cyanonitroso- fso-Nitrosodiketo-hydrindene. CgHsOsN = C6H4(CO)2 :C :NOH, kAXlO«at25°=1.7; 752; 1188. A(256) = 7.7, (1024) = 14.4, (co) = 354; 752. Na.A at 25°, A(32) = 67.8, (1024) = 80.4; 752. Nitrosodimethyl amine. (Nitrosodimethylin). C2H60N2=Me2N.NO. XX 106 at 0°= 1.192. At 25°= 1.615; b. p. 149°-149.5° @ 755 mm.; 1844, 1843. At 19°=20; 1853c. At 19°, A(15.0) = 0.41; 1853c. Cond. as solvent; 1844, (1853c). p-Nitroso dimethyl aniline. C8HioON2=NO.C6H4.NMe2. ksXlOio at 25°= 1.95 (part.); 548. Nitrosodimethylin see Nitrosodimethyl amine. Nitrosomethyl- see also Methylnitroso- Nitrosomethylacetone see fso-Nitrosomethylethyl ketone. p-Nitroso-methylaniline. C7H80N2= NO.CeHi.NHMe. kAXl0i'at6°=1.12 (part.). kBXlO" at 6°=1.63 (part.); 548. iso-Nitrosomethylethyl ketone. (Nitrosomethylacetone.) C4H702N=Me(NOH:)C.COMe. kAXlQiOat 18°=1.3 aq.; m. p. 76°. Na.A at 25°, A(100) = 83.4; 1296. iso-Nitrosomethylpropyl ketone. (Ethyl iso-nitrosoacetone). C6H902N= MeCO.C( :NOH)Et. kAXlO^" at 25°=3.1 (catal.); 752. 4-Nitroso-l-naphthol. (a-Naphthoquinone oxime. a-Nitroso-a-naph- thol. 4-Nitroso-l-hydroxy-naphthalene) . CioH702N=NO.CioH6.0H. kAXlO'at25°=2.6. Ai(1024) = 5.7, (2048) = 8, (oo)=[355]; 1748. 2-Nitroso-l-naphthol. (/3-Naphthoquinone oxime. |8-Nitroso-a-naph- thol). C10H7O2N. Nit] TABLES 235 kAXl08at25''=2.6. m(512) = 1.4, (1024) = 1.8; 1748. l-Nitroso-2-naphthol. (j3-Naphthoquinone oxime. a-Nitroso-j3- naphthol.) C10H7O2N. kAXl08at25°=2.6. m(512) = 1.4, (1024) = 1.8; 1748. In NH3, qual.; 606. 7-iso-Nitroso-|3-mtrosoamino-crotonic acid ethyl ester. C6H9O4N3. NH4.A (=C6Hi204N4), at 18°, K of 0.511 g. in 50.1 cc. aq. = 3.7x 10-5; m. p. 170°; 526. 4-Nitrosoorcmol. C7H703N=Me.CaH2(OH)2.NO. YeUow isomer; dec. 163°. kAXl04at25°=3.7; 777; = 3.3; 810;=4.5; 547. At25°, m(512) = 108, (1024) = 130; 777.- 782. InEtalc; 777,782. K.A, A(32) = 88.8, (1024) = 99.8, - Na.A, A(32) = 67.3, (256) = 73.5; 810. Red isomer; dec. 124°-125°. kAXl0^at25°=5.1. Cond. in aq. and in Et ale; 777. 547. At 25°, /i(128) = 85, (1024) = 190; 777. Nitroso-oxindole see Isatoxime. p-Nitrosophenol. (Benzoquinone mono oxime). C6H502N=NO.C6H4.0H=0:C6H4:NOH. kAXlO' at 25°=3; increases, then diminishes on diln. ; 647;=7.5; 1748. Cond. in aq.; 782. At 25°, ai(128) = 2.1, (1024) = 6.4; 647. In pyridine; 754. In Et ale; 782. Na.A at 25°, /i(32) = 67.2, (1024) =77.3; 547. Nitrosophenyl- see Phenylnitroso- Nitrosopropionic acid see Oximinopropionic acid. iso-Nitrososuccinic acid see Oximinosuccinic acid. iso-Nitrosothioliydantoin. C3H3O2N3S. kAXl08at-25°=5. A(512) = 1.8, (1024) = 2.8, (oo) = 358. Na.A at 25°, A(32) = 77.7, (1024) = 86.7-; 752. Nitroso-urethane see anft-Diazo-urethane. 4-Nitro-2-sulphobenzoic acid ethyl ester. C9H907NS=N02.C6H3(S03H).C02Et. [C02Et=l.] As strong as HCl, (colorim.) ; 950. o-Nitrotoluene. C7H702N= Me.C6H4.NO2. X XlO' at 25° is less than 1.8; 1106, 1107. In HBr; 1646. In HBr and HCl, fair cond. In H2S, no cond.; 1897. In NH3, qual.; 606. 236 TABLES [Nit Cond. with inorg. and organic salts; 1106, 1107, 1893. As sol- vent; (1893). m-Nitrotoluene. C7H7O2N. xxW at 25° is less than 1.8. As solvent; 1106, 1107. p-Nitrotoluene. C7H7O2N. In HBr, good cond. In II2S, no cond. ; 1897. In NH3, qual. ; 606. m-Nitrotoluene sulphonic acid. C7H706NS=Me.C6H3(N02).S03H. KA, at 25°; x of 0.1 g. in 50 cc. aq. = 7.7 XlQ-^; 456a. 3-Nitro-4-toluidine. C7H802N2= Me.C6H3(N02).NH2. [Me=l; NH2=4; N02=3.] kBXlQi* at 25°=5.4 (solub.); 659. 2-Nitro-4-toluidine-5-sulpliomc acid. C7H806N2S=Me.C6H2(N02)(NH2).S03H. [HS03=5.] At 25°, A(128) = 3pi.9, (1024) = 318.9, (00)= [355]; 492. 2-Nitro-4-tolyUiydrazine-5-sulphonic acid. C7H906N3S=Me.C6H2(N02)(NHNH2).S03H. [Me=l; N02=2; NHNH2^4; HS03=5.] IjaXIO^ at 25°= 1.3; diminishes on diln. A(512) = 79.6, (1024) = 97.9, (o°) = 352; 492. Nitro-trichloro-methane. (Chloropicrin). C02NCl3=N02.C.Cl3. ji XlO^ at 18° is less than 6; 291. In NH3, qual.; 606. As solvent; 291. Nitrotrimethyl-aniline see Trimethyl-nitrophenyl ammonium hy- droxide. Nitro-uracil. C4H3O4N3. kAXl0^at25°=3.25. Ai(128)=7.2, (1024) = 20.0, (co) = 356; 1748. Nitro-uracilcarboxylic acid. CsHsOeNs. At 25°, Ai(32) = 318.7, (1024) = 349.6. Na.A. - 2Na.A at 25°, m(32) = 81.3, (1024) = 99.9; 1748. Nitro-urea. CH303N3=NH2.CO.NH(N02). kAXlQS at 0°=3.9; 141, 143. At 10°=5.5. At 20°=7.1. At 30°=8.6. At 40° is over 9. From 0° to 20° k diminishes, then increases on diln. ; at 30° and 40° k diminishes on diln. because of dec; 143; [quoted?]; 757. At 20°, A(32) = 19, (512) = 69.0, (oo)=403.2; 143. Na.A at 20°, A(1000) = 151.8; - also at 0°-40°; 143. Nitro-urethane see Nitrocarbamic acid ethyl ester. Nitrous acid. HNO2. [The references to this are incomplete. ] kAXl04at20°=4.5; 1601; (hydrol.); 578. [At 25°] = 6.4 + 10%; 139. At 20°, A(512) = 151.2, (1024) = 190.5, (oo) = 391.5; 1601. Ole] TABLES 237 Nitrous acid amyl ester. (Amyl nitrite). C6Hii02N=N02.C6Hii. xxW at 18°=3.6; 360. At 25°=1.8; 1106, 1107; = 15; 1569. In HBr and HI, fair cond. In H2S, no cond.; 1897. In NH3, qual.; 606. In ether; 360. Cond. with inorg. and organic salts; 1106, 1107, 1569. As sol- vent; 1569. Nitrous acid ethyl ester. (Ethyl nitrite). C2H602N=N02.Et. A(512) = 152.6, showing complete saponification; 578. Nitro-iso-valeric aldehyde phenylhydrazone. CiiHi602N3= (C4H9)(N02)C:N2H.Ph. a-) m. p. 51.5°-52°. j8-) m. p. 92.5°-93°. In aq. soln., no cond.; 78. Nitrovanillic acid. (?-Nitro-4:-hydroxy-3-methoxy-benzoic acid). C8H706N=N02.C6H2(OH)(OMe).C02H. [C02H=1.] kAXlO* at 25°= 1.2; diminishes on diln. A(600) = 82.8, (1200) = 108.6, (00) = 353; 175. 6-Nitroveratric acid. (6-Nitro-3,4-dimethoxy benzoic acid). C9H906N=N02.C6H2(OMe)2.C02H. [C02H. = 1.] kAXlO^ at 25°=3.6; diminishes on diln. A(126) = 170, (504) = 238.4, (co) = 351; 175. Norhemipinic acid dimethyl ether see Hemipinic acid. Noropianic acid dimethyl ether see Opianic acid. Oak. [The references to thisare incomplete.] Cond. of soln. of bark; 146. iso-Octinic acid. C9H14O3. kiXlG^ at 25°=7.7; m. p. 128°-129°. At(256)=45.6, (512) = 62.9, (oo) = 350; 1823, 1831. Octoaspartic acid. C32H42O25N8. Cond. with NaOH. 8K.A. - 4Na.A. - BNa.A. - 8Na.A at 28°, ju(32) = 45.6, (1024) = 69.9. Cond. with NaCl and NaOH; 1227. Octyl alcohol. CsHisO. InNHs, qual.; 606. Octylmalonic acid. CiiH2o04=CH(C8Hi7)(C02H)2. kAXlO^ at 25°=9.2 aq.; diminishes on diln. Second kAXlO' =6.5 (inversion). At 25°, M(450) = 163.9, (1800) = 241.6, (oo) = 349; 1638. Oenanthylic acid see Heptoic acid. Oenanthylic aldehyde see Heptyl aldehyde. Oleander see Nerium oleander. 238 TABLES [Ole Oleic acid. Ci8H3402=CivH33.C02H. In benzene, no cond.; 935. In amyl, Et and Me ale; 438. Co.2A and Cu.2A in benzene, no cond. ; 935. - Cu.2A cond. with organic compounds; 1569. - Mg.2A in commercial benzine; 931.- Ni.2A in benzene, no cond.; 935. - K.A in aq., Et and Me ale; 438. - Na.A at 25°, A(32) = 42.1, (512) = 70.6, (1024) = 84.4; 945. A(32) = 23, (512) = 60; 438. At 18°-75°; 438, 945. In amyl, Et and Me ale; 438. In HON, small cond.; 943. Cond. of thin layer; 1480. Olive oil. [The references to this are incomplete. ] Cond.; 1010. In commercial benzine; 931. Cond. increased by radium rays; 1491. Opianic acid. (Dimethoxy-noropianic acid). CioHio06=(MeO)2.C6H2(CHO).C02H. [CH0=1; C02H=2; MeO=3,4.] kiXlO^ at 18°=9.3 (colorim.); 1563. At 25°=8.8; 1371. At 25°, A(128) = 99.9, (1024) = 212.5, (oo)=352; 1371. Cond. not increased by boric acid; 1186. Orange U see p-Benzene sulphonic acid azo-;3-naphthol. Orange III see p-Dtmethyl-aminoazobenzene sulphonic acid. Orcinol. (3,5-Dihydroxy-toluene). C7H802=Me.C6H3(OH)2. [Me=l; OH=3,5.] kiXlO' at 25° is over 3. m(26) = 0.1, (208) = 0.9, (oo)=355; 70. Cond. alone and with NaOH; 1508, 1718. InNHs, qual.; 606. Orcinolcarboxylic acid. (3,5-Dihydroxy-phenylacetic acid). C8H804=(HO)2C6H3.CH2.C02H. [OH=3,5; CH2.C02H=1.] Cond. decreased by Ba(0H)2; 1719. In Et ale, alone and with NaOH; m. p. 165°; 1508, 1718. Orcyl aldehyde. C8H803=Me.C6H2(OH)2.CHO. [Me=l; OH=3,5; CH0=2.] kiXlO^ at 25°=4.1; m. p. 179°; 643. At 25°, m(1024) = 64, (oo) = 354; 643.- 1718. Cond. increased byBa(0H)2; 1719. In Et ale, alone and with NaOH; 1508, 1718. Orobanche hederaeolia. [0. hederafolia? Ivy broom-rape.]. [The references to this are incomplete.] Cond. of sap; 253. Of stem and buds; 1326. Orsellic acid. (Orsellinic acid). C8H804=Me.C6H2(OH)2.C02H. [Me=l; C02H=2; OH=3,5. Possibly Me=2; C02H=1.] kAXl0*at25°=1.3; dee 175°-176°. ju(128) = 43.2, (1024) = 103.6, (oo) = 358; 809.- 1508, 1718. Oxa] TABLES 239 Cond. increased by Ba(0H)2; 1719. Cond. in aq. and in Et ale, with NaOH; 1508, 1718. p-Orsellic acid. (p. Orsellinic acid). C8H804=Me.C6H2(OH)2.C02H. [Me=l,- C02H=4: 0H=3, 5.] kAXlO^ at 25°=4.1; 1371. Measurement of 1371 confirmed; [no data]; 809. At25°, Ai(128)=307, (1024)=355, (oo)=358; 1371. In Et ale, alone and with boric acid; 1185. Orsellinic acid see Orsellic acid. Ortho-fonnic acid triethyl ester. (Ethyl orthoformate). C7Hi603=CH(OEt)3. In NHs, qual.; 606. Ovo-mucoid. [The references to this are incomplete. ] Cond. in HCl and in KOH shows it to be more basic than acid; 1506c. Oxalacetic acid. C4H4OB. kAXlO^ at 25°=1.33; 926. See Hydroxy-fumaric and Hydroxy- maleic acids, the isomers into which this acid has been split. Oxalacetic acid phenylhydrazone. C10H10O4N2. kAXlO' at 25°= 1; dec. 95°-100°; 926. See the acid. Oxaldihydroxamic acid. C2H404N2=C202(NHOH)2. kAXlO^ [at 25°]= 2; increases on diln. iu(32) = 0.9, (128) = 2.1, (co)=[380]; 1353a. Fe.A; 756. OxaUc acid. C2H204=C02H.C02H. kA diminishes on diln. in all measurements. kiXlO^ at 18°=9 (colorim.); 1562, 1563. At 20°=6 aq.; 164. At 25°= 10; 1371. Relative strength (colorim. etc.); 693, 1643. Second kAXlO'=4.1 (part.)j=4.9 (cond.); 370;=1.6 (inversion); 1336. At 0°, M(32) = 169.8, (512) = 223.7; 924;- 910. At 11.8°; 924. At 15°; 1741. At 15°-25°; 171, 377, 591, 1122, 1123, 1211, 1577. At 25°, m(32) = 267, (512) = 364, (1024) = 383, (00) = 365?; 1371; m(32) = 262.3, (512) = 349.9; 924; - 691, 1023, 1270, 1495, 1508, 1518, 1718. At 35°; 388a, 924. At 50°. At 65°; 388a. - See also, 401, 556. In HCl, no cond.; 30. In H2SO4; 223, 750. In Me ale; 1579, 2029. In Et ale; 788, 789, 1579. In pyridine; 754. Cond. with inorg. compounds; 171, 223, 556, 691, 692, 750, 1023, 1184, 1209, 1350, 1495, 1508, 1516, 1518, 1718. With or- ganic compounds; 45, 378, 401, 556, 754, 1223, 1577, 1630, 2005. Under pressure of 1-500 atmospheres; 1427. 240 TABLES [Oxa NH4.A; 1550. - 2(NH4).A; 145a, 556, 823, 1519, 1577. In HCl, smaU cond.; 1645.- Ba.A; 990, 991, 993, 1004.- Cd.A; 990, 991, 993. - Ca.A; 848, 990, 991, 993, 1004. - 2Ce.3A; 1496. - Cr, see Double and complex salts, also Chromioxalie acid, and Chromium, complex salts. - Cb double salts; 1550. - Cu.A; 1577. - 2re.3A; 1577. - 2La.3A; 1496. - Pb.A; 216, 990, 991, 993. - Mg.A; 990, 991, 993, 997, 1003. - 2Nd.3A; 1496. - Ni.A; 427. - K.A; 164, 1519, 1550. - 2K.A; 164, 171, 427, 692, 889, 997, 1023, 1174, 1338. 1516, 1519. - 2Pr.3A; 1496. - 2Sa.3A; 1496. - 2Ag.A; 216, 990, 991, 993.- Na.A at 25°, m(32) = 97, (1024) = 182; 370; 1550, 1643, 1838.- 2Na.A at 25°, m(32) = 93, (1024) = 113; 1838; 370, 449, 495, 692, 1023, 1227, 1367. - Sr.A; 990, 991, 993, 1004. - 2T1.A; 10, 216. - UO2.A; 449. - 2Yb.3A; 1496. - 2Yt.3A; 1496, - Zn.A; 990, 991, 993. - " Double " and complex salts. The number of atoms and of acid radicals is not given under this heading. NH4, K, Rb or Na with; -Al; 1515, 1516;- with Sb; 1519;- with Cr; 971, 1192, 1198, 1515, 1516;- with Co; 1948;- with Cb; 1550;- with Fe; 971, 1209, 1515, 1577, 1581a;- with Mo; 691, 692, 1023, 1515, 1518;- with Ni; 427;- with Ag; 971;- with Te; 1530a;- with W; 692, 1023, 1515, 1516;- with V; 1515, 1516. Oxalic acid mono amide. (Oxamic acid). C2H303N= CO2H.CONH2. kAXlC at 25°=8.5; diminishes on diln. /i(32) = 146.4, (512) = 300.2, (oo)=352; 1371. OxaUc acid di-amide. (Oxamide). C2H402N2=CONH2.CONH2. InNHs, qual.; 606. Hg salt, e. m. f.; 963. Oxalic acid diethyl ester. C6Hio04=C02Et.C02Et. xXlO'at 25°=7.12; 1106, 1107;= 11; 1569. In HBr, good cond. In H2S, fair cond.; 1897. In NH3, qual.; 606. Cond. with inorg. and organic salts; 1106, 1107, 1569. Effect of temperature on cond.; 106. As solvent; 1106, 1569. Oxalic acid dimethyl ester. C4H604= (C02Me)2. Effect of temperature on cond. ; 106. Oxalic acid nitrile see Cyanogen. Oxaltoluidic acid see Tolyloxamic acid. Oxaluric acid. C3H404N2=NH2CO.NH.CO.C02H. kAXlO'at25°=4.5. iii(64) = 284, (a>) = 360; 1371. k=0.3. ^(64) =98.8, (1024) = 144.5; decomposes in soln.; 1748. [It is Oxi] TABLES 241 impossible to harmonize these measurements. The acid in 1371 may have been decomposed.] NH4.A, in NH3, qual.; 606. Na.A at 25°, ^(32) = 168.2; de- composes in soln.; 1748. Oxamic acid see Oxalic acid mono amide. Oxamide see Oxalic acid di-amide. Oxanilic acid. (Anilinooxalic acid). C8H703N=CO(NH.Ph).C02H. kAXlO^ at 25° = 1.2; 1371, 1334; (colorim.;) 1773. At 25°, m(32) = 161.2, (1024) = 322.7, (co) = 351; 1371. Oximino-acetic acid. (Aldoxime-sj/n-carboxylic acid. Nitrosoacetic acid). C2H308N=H.C(:NOH)C02H. kAXl05at25°=l; 768;=1; diminishes on diln. ; m. p. 140°-141° with dec; 865. m(32) = 59.4, (1024) = 227.6, (oo) = 365; 768. Na.A at 25°, m(32) = 75.6, (1024) = 92.0; 865. o-Oximino-butyric acid. (Ethyl-syn-ketoxime carboxylic acid. Nitro- sobutyric acid). C4H703N=Et.C(:NOH)C02H. kAXlO* at 25°=8; diminishes on diln.; = 8.67; 768;=7.8; m. p. 154° with dec; 865. m(32) = 55, (1024) = 209.1, (co) = 359; 768. m(32) = 55, («>) = 379; 865. Na.A at 25°, m(32) = 69.6, (1024) = 85.0; 865. j3-Oximino-butyric acid. C4H7O3N. kx at 25° is probably about the same as that of the a-acid, as shown by cond. of the anhydride; 768. j8-Oximinobutyric anhydride. (Methyl-syn-ketoxime carboxylic acid. Methylisoxazolone or Methyl-sj/n-oxazolone). C4H6O2N. kAXlO* at 25°= 5; diminishes on diln. At 25°, m(512) = 1^2.5, (1024) = 155.1, (00) = 355. The cond. is probably due to presence of the acid; 768. Oximino-cyanoacetic acid see Cyanonitrosoacetic acid. Oximinomethyl- see Methyloximino- a-Oximino-propionic acid. (Methyl-sj/n-ketoxime carboxylic acid. Nitrosopropionic acid). C3H603N=MeC:NOH.C02H. kAXlO* at 25°=5; diminishes on diln. = 5.0; m. p. 176°-178°; 1840;=4.9; m. p. 180°-181° with de'c; 865;=5.3; 768. m(32)=43.7, (1024) = 182.5, (oo) = 359; 768. m(32)=45, (») = 381; 865. Na.A at 25°, m(32) = 72.0, (1024) = 89.0; 865. l3-Oximino-propionic acid. (Aldoxime-anii-acetic acid). C3H603N=H(NOH:)C.CH2.C02H. kAXlO^ at 25°=1; diminishes on diln. m(64) = 28.1, (1024) = 90.8, (00) = 359; 768. 242 TABLES [Oxi a-Oximino-succinic acid. (Ketoxime-a?iii-acetic-carboxylic acid, iso- Nitrososuccinic acid). C4H606N=C02H.(NOH:)C.CH2.C02H. kAXlO' at 25°= 1.1; increases on diln. lx{32) = Q0.5, (1024) = 249.7, (oo) = 357; 768. a-Oximino-succimc acid mono ethyl ester. C6H906N=C02Et.(NOH:)C.CH2.C02H. kAXlO*at25°=1.9. Ai(32) = 26.6, (1024) = 125.9, (co) = 357; 768. /3-Oxiimno-succimc acid. C4H606N=C02H.C(:NOH).CH2.C02H. In soln. decomposes instantaneously to cyanoacetic acid; 768. j8-Oximino-succinic acid mono ethyl ester. C6H906N=C02Et.C(:NOH).CH2.C02H. kAXlO' at 25°= 5.3? m(32) = 120.1, (1024) = 287, (oo) = 357; 768. a-Oximino-valeric acid. (Nitrosovaleric acid. Propyl-sj/n-ketoxime carboxylic acid). C6H903N=Pr.C(:NOH).C02H. kAXlO* at 25° is over 6; diminishes on diln.; 768; m. p. 140° with dec. ; 865. m(32) = 49, (1024) = 190.3, (co) = 356; 768. m(32)=49.4, (oo) = 378; 865. Na.A at 25°, A(32) = 68.7, (1024) = 84.5; 865. 7-Oximino-valeric acid. (Methyl-sj/n-ketoximepropionic acid). C6H903N=Me.C(:NOH).CH2.CH2.C02H. kAXlO^ at 25°=2.7; diminishes, then increases on diln. /i(32) = 10.4, (1024)=45.6, (co) = 356; 768. Oxy- see also Hydroxy-. Compounds containing an OH group are called hydroxy. p-Oxyazobenzene. (Benzeneazophenol. Hydroxy-azobenzene.) C:2HioON2= :C6H4:N(NH.Ph). kAXlO^ at 25° =4.9 (part.); 545. At 25°, m(1100) = 1; 546. In pyridine; 754. Na.A at 25°, ju(32) = 62.6, (1024) =74.2. The salt, formed from the hydroxy compound [=acid+Il20] is PhNH.N:C6H4.(OH)(ONa), and is the salt of a strong acid; 546. Oxy-iso-butyryl-/3-aiiilino-iso-butyric anhydride. C14H17O3N. Na.A at 25°, A(32) = 60.4, (1024) = 70.5; m. p. of the anhydride is 120°; 1840. j3-0xy-jso-butyryl-o-toluidino-iso-butyric anhydride. CibHiqOsN. Na.A at 25°, A(32) = 59.6, (1024) = 69.4; m. p. of the anhydride is 95°; 1840. Pap] TABLES 243 ^-Oxy-iso-butyryl-p-toluidino-iso-butyric anhydride. CisHigOsN. Na.A at 25°, A(32) = 59.2, (1024) = 69.0; m. p. of the anhydride is 170°; 1840. 2-Oxy-l,6-dihydro-purine. (Desoxyxanthine). CsHeONi. kiXlQi^ at 25°= 2.97 (catal.); 1707. Oxyhaemoglobin. [The references to this are incomplete.] Cond. in aq. at 0°-39°; 625, 1655a. Oxymenthylic acid. CioHigOs. kAXlO^ at 25°=2.1; diminishes on diln. m(42.7) = 10.5, (1366.4) = 54.9, (oo) = 351; 1372. Oxymethylene-cyanoacetic acid see Cyanoformylacetic acid. Oxypyridine. CsHbON. Cond. less than that of phenol; 733. Oxyuracil. (Hydroxy-uracil.) C4H4O3N2. kAXlO^ at 25°=2.5 (catal.); 1996. P. Palladium. Complex salt; 1762. See also the following compounds. Palladium cyanic acid. C4H2N4Pd=H2Pd(CN)4. 2K.A at 25°, A(32) = 113.1, (1024) = 134.0; 150. PaUadium thiocyanic acid. C4H2N4S4Pd=H2Pd(SCN)4. 2K.A at 25°, A(32) = 106.7, (1024) = 126.3; 150. Palmitic acid. Ci6H3202=Ci6H3i.C02H. In HBr, no cond.; 30. In MeNH2, fair cond.; 637. KA; 945.- Na.A at 89.75°, A(20) = 86.0, (100) = 135.3; 1229a. Pancreatic juice. [The references to this are incomplete.] Concentration of H and OH ions; 587. Cond. with gelatin; 807, 808. Papaveric see Papaverinic. Papaverine. C20H21O4N. ksXlO' at 18°=2.8; 1224. At 20°=0.9 (colorim.); 1779. At 25°=500 aq. [probably too high. ] ; 1241. At 18°, m(7634) = 8.9, (oo) = l96; 1224. At 25°, m(6130) = 81.1, ( CO) = 190.5; 1241. InHCN, nocond.; 943. B.HCI at 18°, m(260) = 82.5, (1040) = 85.9; 1224. Papaverinic acid. Ci6Hi307N=(MeO)2.C6H3.CO.C5H2N(C02H)2. kAXlO^ at 25°= 1; increases on diln.; 966, 1372. Second kAXl05=7; 1911. At 25°, Ai(256) = 273, (1024)=340.2, (co) = 350; 966. 244 TABLES [Pap Papaverinic acid j3-mono methyl ester. Ci7Hi607N=(MeO)2.C6H3.CO.CBH2N(C02H)(C02Me). kxXlO' at 25°=4=t20%; saponifies in soln.; m. p. 156°; 1909; = 7.8; 966. m(593) = 280.2, (1190)=303.2, (co) = 372; 1909. m(512)=290.2, (oo) = 350; 966. Papaverinic acid 7-mono methyl ester. C17H16O7N. IjaXIO^ at 25°=6±20%; saponifies in soln.; m. p. 195.5°-197°; 1909, 966. Ai(910) = 322, (a>) = 372; 1909. Papaverinic acid oxime. (Papaverinic ketoxime). C16H14O7N2. At 25°, m(463.5) = 380.5; 175. Papaverinic acid phenylhydrazone. C22H19O6N3. kAXl02at25°=4.7. /i(2124) =319.6, (oo) = 350; 175. Parabanic acid. C3H2O3N2. kAXlO'at25°=7.5; 1996. Cond.; 1748. At 25°, iu(32) = 2.1; 1996. InNHa, qual.; 606. Hgsalt, e. m. f.; 963. Paraffine. [The references to this are incomplete. ] Effect of radium on cond. ; 148. ParaflSne oU. [The references to this are incomplete.] Effect of radium and of a-rays on cond. ; 687, 834. Parafuchsine see Fuchsine. Paraldehyde see Acetaldehyde. Paratartaric acid see Tartaric acid. Paraxanthine see l,7-Dimethyl-2,6-dioxy-purLne. Pear. [The references to this are incomplete. ] Concentration of H and OH ions in pear juice; 587. Pelargonic acid. C9Hi802=C8Hi7.C02H. kAXl05at25°=l. A(1226)=38.8, (2452) = 53.1, (co) = 351; 601. Pelargonic acid ethyl ester. C11H22O2. In NH3, qual.; 606. Pentachloro-butenecarboxylic acid see Pentachloro-pentadiene-car- boxylic acid. 1,1,3,4,4-Pentacliloro-pentadiene-carboxylic acid. (Pentachloro- butenecarboxylic acid). C6H02Cl6= CCI2 :C :CCl.CCl2.C02H. kAXlO''=6 [no data given]; 1028, 2030. Pentacyanin see Pentahydroxy-anthraquinone. l,2,4,5,8-Pentahydroxy-anthraq\iinone. (Ahzarin cyanin. Pentacy- anin). C14H8O7. Pep] TABLES 245 At 25°; 2Na.A, A(32) = 81.1, (1024) = 119.8. - SNa.A, A(32) = 97.8, (1024) = 120.- SNa.A, A(32) = 107.6, (1024) = 148.9; 1275. Pentamethylene-carboxylic acid. (Cyclopentane-carboxylic acid). CeHioOa. kAXlO^ [at 25°] = 1.24. A(20.9) = 5.6, (667.2)=30.5, (oo) = 352; 2026. Pentamethylene diamine. C6Hi4N2=NH2.C6Hio.NH2. kflXlO* at 25°=7.3 aq.; about 16% too high; 271. Cond.; 1354. At 25°, A(32)=28.2, (256) = 67.8, (oo) = 197; 271. B.2HC1 at 25°, A(32) = 105.0, (1024) = 125.8; 270. cjs-Pentamethylene-l,2-dicarboxyUc acid. C7H10O4. kiXlO* [at 25°] = 1.58; m. p. 141°; 1410. frans-Pentamethylene-l,2-dicarboxylic acid. (a|8-acid). C7H10O4. kAXlO* at 25°=1.2; m. p. 160°; 1410, 1638, 1859. Second kAXlO'=3.7 (inversion); 1638. At 25°, Ai(70.8) = 31.3, (1132) = 109.1, (co) = 352; 1859. cfs-Pentamethylene-l,3-dicarboxylic acid. (as-Cyclopentane-1,3- dicarboxylic acid). C7H10O4. kAXl05=5.3; increases on diln. /i(32) = 14.1, (1024) =74.8, (==) = [352]; m. p. 120°-121.5°; 1450. frans-Pentamethylene-l,3-dicarboxyUc acid. (<^Oi'' at 10°=0.56 (hydrol.). At 15°=0.66 (hydrol.); 1150a. At 18°= 1.3; 1865, 1883. At 21° = 160 (solub.); inaccurate; 1116. At 24°= 1.2 (catal.); 1610a and 1116, 661, 1043. At 25°=0.97 (hydrol.); 1150a; = 1.2 (catal.); 733 and 1150;= 50 (cond.); 733, 70. At 40°= 1.51 (hydrol.). At 50°=2.05 (hydrol.); 1150a. Cond.; 70, 168, 733, 789, 1488, 1508, 1718, 1747, 1865, 1883. At 25°, A(32) = 0.14, (256) = 0.43, (oo) = 357; 733. In HBr; 29; qual.; 1897. In HCl and in H2S, no cond.; 1897. In HCN, no cond.; 943. In NH3, qual.; 606. In Et ale; 789. In MeNH2, good cond.; 637. Cond. with bases; 165, 168, 169, 512, 733, 1150a, 1508, 1718. Phe] TABLES 247 With salts; 756, 1488, 1599. With organic compounds; 1569, 1599, 1747. As solvent; (1488), 1569. NH4.A; 165, 169, 733, 1150a,; (hydrol.); 302, 302a. - K.A; 165, 168. Na.A at 25°, A(32) = 72.7, (1024) = 100.9; 733; 168, 1508, 1718. Phenol-2,4-disulphonic acid. C6H607S2=OH.C6H3(S03H)2. Stronger than Phenolsulphonic acid (hydrol.); qual.; 1345. Phenol ethyl ether see Phenetole. Phenol methyl ether see Anisole. Phenolphthalein. C20H14O4. kA is probably of the order 10"" to 10"'". The following values are approximate. See 1916. Phenolphthalein is dibasic; 1916, 532. kAXlQi" at 18° to 19°=8 (colorim.); 1562. At 23°=1.8 (colorim.); 1916. At 25°= 0.75 (colorim.); 1230;= 1.7 (colorim.); 822. Cond. alone and with NaOH in Et ale; 532. In MeNH2, fair cond. ; 637. o-Phenol sulphonic acid. C6H604S=HO.C6H4.HS03. Stronger than p- acid, (hydrol.) ; 1345. Cu.2A at 25°, m(32) = 67.0, (512) = 81.4; 1090. - Na.A cond. alone and with NaOH; 1508, 1718. m-Phenol sulphonic acid. C6H6O4S. Weaker than p- acid, (hydrol.) ; 1345. p-Phenol sulphonic acid. C6H6O4S. Weaker than o- acid, (hydrol.) ; 1345. Cu.2Aat25°, m(32) = 65.6, (512) = 81.9; 1090.- Na.A; 1508. Phenosafranine. Ci8Hi60N4=Ci8Hi5N40H; or Ci8Hi4N4,(+H20). Barbier, Sisley, 86, state that they have split this into two isom- ers. Hewitt, Newman, Winmill, Jour. Chem. Soc. 95, 577-584, (1909), say that the asymmetrical isonier (azo- phenosafranine) is really aminophenazine. Therefore the particular compound measured seems to be in doubt. The arrangement here follows the old order. Phenosafranine. At 25°, A(512) = 176.6; 770. B.HCl (=Ci8Hi5N4Cl) at 25°, A(128)=79.4, (256) = 81.7, (1024) = 83.1.; 882, 1266. A(256) = 90.6, (1024)=92.6; 770. sj/m-Phenosaf ranine. (Indophenosaf ranine) . B.HCl; 86. asj/m-Phenosafranine. (Azophenosafranine). Aminophenazine? B.HCl; 86. Phenoxy-acetic acid. (GlycoUic acid phenyl ether. PhenylglycoUic acid. Phenyloacetic acid). C8H803=PhO.CH2.C02H. kAXlO^ at 25° =7.7; diminishes irregularly on diln.; 1370, 1670. 248 TABLES [Phe A(32) = 51.2, (1024)=202.2, (oc,) = 353; 1370. Na.A at 25°, A(32) = 64.7, (1024) = 74.8; 1368a. o-Phenoxy-butyric acid. CioHi203=Et.CH(OPh).C02H. kAXlO* [at 25°] =6.82; m. p. 82°-83°; 193. a-Phenoxy-jso-butyric acid. CioHi203=PhO.CMe2.C02H. kAXlO^ [at 25°]=4.34; m. p. 97.5°-98.2°; 193. a-Phenoxy-propionic acid. (Lactic acid phenyl ether). C9Hio03=Me.CH(OPh).C02H. kAXlO* [at 25°] = 7.75; b. p. 265°-266°; 192. /3-Phenoxy-propiomc acid. C9Hio03=PhO.CH2.CH2.C02H. kAXlO^ [at25°]=5.4; m. p. 98°; 192. a-Phenoxy-iso-valeric acid. CiiHi403=Me2CH.CH(OPh).C02H. kAXlO* [at 25°]=4.66; m. p. 81.5°-82.3°; 193. Phenylacetamide see Phenylacetic acid amide. Plienylacetamide-o-carboxylic acid see Homo-o-phthalic acid 2-mono amide. Phenylacetic acid. (a-Toluic acid). C8H802=PhCH2.C02H. kAXlO*, increases, then diminishes on diln. At 0°=5.4. At 13.25°=5.4; 1968a. At 25°=5.4; 1968, 1968a;=5.5; 1371; 1673. At35° = 5.3; 1968a. Cond.; 1495. At 0°-35°; 1968, 1968a. At 25°, A(32) = 14.8, (1024) = 76, (oo) = 356; 1371. In NH3, qual.; 606. In Et ale; 1066. In MeNH2, good cond.; 637. In pyridine; 754. Cond. with M0O3; 1495. Ba.2A; 1066.- Na.A at 25°, A(32) = 66.5, (1024)=76.4; 1368a. - MeNHs.A; 637. Phenylacetic acid amide. (Phenylacetamide). C8H90N=PhCH2.CONH2. In NH3; 610. ti-zso-Phenylacetic acid. (o-Cycloheptatriene-carboxylic acid. Me- thylene-dihydro-benzoic acid). C8H802=C7H7.C02H. kAXlQS at 25°=3.67;=3.76 aq.; m. p. 71°. A(75.7) = 19.5, (908.0) = 63.4, (co)=377; 1533. /3-iso-Phenylacetic acid. (7-Cycloheptatriene-carboxylic acid. j3-p- Methylene-dihydro-benzoic acid). CgHsOa. kAXlO^ at 25° is about 4;=3.96;=4.10 aq.; 1533; = 3.79; m. p. 55°; 1976. A(104.4) = 23.9, (417.8) = 46, (co) = 377; 1533. A(64) = 18.1; 1976. 5-iso-Phenylacetic acid. (a-p-Methylene-dihydro-benzoic acid). C8H8O2. kAXlO^ at 25°=3.96; m. p. 32°. A(64) = 18.5, (1024) = 68.4, (oc,) = 377; 1976. Phe] TABLES 249 Phenylaceturic see Phenaceturic. Phenylacetylamino-acetic acid. (Acetylanilino-acetic acid. Acetyl- phenyl glycine). CioHii03N = PhN(MeCO).CH2.C02H. kiXlO* at 25°=2.6; m. p. 194°-195°. A(200) = 72.5, (1600) = 168, (co) = 356; 1840. ;3-Phenyl-7-acetylbutyric acid. Cl2Hl403= MeCO.CH2.CHPh.CH2.CO2H. kAXlO«at 25°=3.2aq. A(32) = 11.6, (1024) = 61.1, (co) = 372; 1688. Phenylacridinemethyl- see Methyl-phenyl-acridinium- Phenylacrylic acid see Atropic acid and Cinnamic acid. Phenylalanine see a-Anilinopropionic acid and Phenyl-aminopropionic acid. Phenylamino-acetic acid. (Anilino-acetic acid. Phenyl glycine). C8H902N=PhNH.CH2.C02H. kAXlO^ at 25°=3.8; m. p. 127°-128°; 1840, 1370, 195. A(128) = 22.6, (1024) = 63.5, («=) = 356; 1840. znacf.-Phenyl-a-aminopropionic acid. (roc. 1^-Amino-hydrocinnamic acid. Phenylalanine). C9Hii02N=Ph.CH2.CHNH2.C02H. kAXlO' at 25°=2.5 (hydrol.); = 950 (cond.). keXlO'^ at 25°=1.3 (hydroL); 947. A(128) = 3.9, (1024) = 10.8, (oo) = 365; 947. Also 145b. Cond. with organic compounds; 145a, 145b. - Na.A at 25°, A(32) = 61, (1024)=72; M(32) = 62.9. - B.HCl at 25°, A(128) = 108, (1024) = 112; M(128) = 271; 947. Phenylazoxazolecarboxylic acid. C9H603N2=Ph.C20N2.C02H. kAXl0^at25°=3.3?. A(64) = 260.5, (128)=302.7, (oo)=350; 768. Phenylbenzyloxyamidine see Diphenyl-benzyl-hydroxy-amidine. Phenylboric acid. C6H702B = Ph.B(OH)2. At 25°, /i of 0.3792 g. in 25 cc. aq. = 0.13; m. p. 216°; 1676a. d-Phenylbromoacetic acid iso-butyl ester. Ci2Hi602Br=Ph.CH.Br.C02.C4H9. In SO2, very small cond.; 1829; 1842. Phenylcarbamic acid ethyl ester [?] (Ethylphenylcarbamate). C9H11O2N. InNHs, qual.; 606. Phenylcarbopyrrodiazolic acid see l-Phenyl-5-pyrrodiazolone-3-car- bozylic acid. Phenyl-di-p-anisyl carbine!. C21H20O3. Comparative strength (colorim.) ; 74. l-Phenyl-3,5-diethoxy urazole. C12H16O2N3. Cond. in alcoholic HCl; m. p. 53°; 18; qual.; 16. 250 TABLES [Phe Phenyldihydro-resorcinol. C12H12O2. kAXlO^ at 25°= 1.2 aq.; diminishes on diln. A(512)=28, (1024) = 38.2, (co) = 374; 1588. Phenyldihydro-resorcylic acid ethyl ester. Ci6Hi604=Ph.C6H60(OH).C02Et. IsaXIO^ at 25°=6.3 aq.; diminishes on diln. A(270.2)=45.3, (1081) = 83.4, (co)=[372]; 1588. Phenyldihydro-resorcylic acid nitrile. CisHuOzN = Ph. CeHeO (OH) . CN. kAXlO^ at 25°=2.0 aq.; diminishes on diln. A(339.7) = 85.1, (1359) = 145.5, (co) = 373; 1588. Phenyldimethyl- see Dimethyl-phenyl- Phenyldinitro-methane. C7H604N2=Ph.CH(N02)2. In aq. too insol. to measure. Cond. in pyridine; 754. o-Phenylenediacetic acid. CioHio04=C6H4(CH2C02H)2. kAXlO*=l.l; m. p. 148.5°-149°. /Li(67.8) = 28.9, (1085.4) = 102.6, (°o) = 350; 81. o-Phenylene diamine. (o-Diamino-benzene). C6H8N2=C6H4(NH2)2. ksXlO^" at 25°=3.3 (part.); 548. Comparative strength (colo- rim.); 1777. — Second ksX 101^=1.45 (colorim.); 1777. m-Phenylene diamine. C6H8N2. Weaker than o-Phenylene diamine (hydroL). Second keX 1012= 1.35 (colorim.); 1777. p-Phenylene diamine. C6H8N2. Stronger than o-Phenylene diamine (hydro!.). Second kBXl0i2=2.48 (colorim.); 1777. O-Phenylene diamine 3-sulphonic acid. (Diamino-benzene sulphonic acid). C6H803N2S=(NH2)2C6H3(S03H). [NH2=1,2; HSO3 = 3.] kAXlO' at 25°= 5; increases on diln. A(43.7) = 14.8, (1398) = 81.3, (oo) = 352; 1372. Phenylene furazane. (o-Benzoquinone dioxime anhydride). C6H4ON2. Cond. with NaOH; 758. Phenylene Violet see Thionine. Phenylethoxyacetic acid. CioHi203=Ph.CH(OEt).C02H. kAXlO^=5.3; increases, then diminishes on diln. A(22.3) = 38.4, (712.9) = 163.2, (oo) = 375; 574. l-Phenyl-3-ethoxy-urazole. C10H11O2N3. kAXlO' at 25°= 3; m. p. 152°. A(1024)=2.1, (2048) = 3.5, (a>)=357.8; 18. In HBr, qua!.; 16. In alcohohc HCI; 18; qual.; 16. Na.A at 25°, A(32) = 59.1, (1024) = 69.7; 18. Phe] TABLES 251 l-Phenyl-3-ethylthio-urazole. CioHuONsS. kAXlO' at 25°= 5; m. p. 137°-138°. A(2048) = ll, (4096) = 19.3, (co) = 355; 18. Phenylglucosazone. CJ.8H22O4N4. In NH3, qual.; 606. Phenylglutaric acid. CiiH]204=Ph.CH(CH2C02H)2. kAXlO« at 25°=7.7; m. p. 138°; 1245, 1813. A(45.6)=21.5, (364.8) = 57, (oo)=373; 1813. Phenyl glycine see Phenylamino-acetic acid. Phenylglycine-o-carboxylic acid. (Anilinoacetic acid carboxylic acid). C9H904N=C02H.C6H4.NH(CH2.C02H). kAXlO* at 25°=2.3; diminishes on diln. A(^40.8)=77.3, (co) = 374; 1245. Phenylglycine-o-carboxylic acid eso mono methyl ester. (o-Carboxy- methyl-anilinoacetic acid). CioHu04N=C02Me.C6H4.NH(CH2.C02H). kAXlO* at 25°=1.4; diminishes on diln.; m. p. 182°. A(963.9) = 112.4, (oo) = 373; 1245. Phenylglycine-o-carboxylic acid exo mono methyl ester. (o-Car- boxyanilinoacetic acid methyl ester). CioHii04N=C02H.C6H4.NH(CH2.C02Me). kAXlO« at 25°=2.8; diminishes on dUn.; m. p. 160°. A(297.3) = 32.5, (od) = 373; 1245. fnocf.-Phenylglycollic acid. (Amygdalinic acid. Mandelic acid). C8H803=Ph.CH(OH).C02H. kAXlO^ at 0°=4.30. At 12°=4.29; 1968a. At 25°=4.17; 1371, 1184;=4.29; 1968a;=4.3; m. p. 118°-119°; 1824;=3.7 (neu- tral.); 463. At 35°=4.24; 1968a. Relative value; 1866. Cond. at 0°-35°; 1968a; 1495. At 25°, A(32) = 38.5, (1024) = 167.5, (oc,) = 353; 1371. A(32) = 38.6, (co) = 349; 1968a. Cond. with boric acid; 1184. With M0O3; 1495. With KOH and acetic acid; 463. Na.A at 25°, A(32) = 64.6, (1024) = 75.0; 1368a; A(32) = 67.7, (1024)=78.0; 1275. At 0°-35°; 1968a. PhenylglycoUic acid methyl ester. C9Hio03=Ph.CH(OH).C02Me. InHCl, good cond.; 1897. 1-Phenylglycollic acid. CgHsOa. kAXlO*at25°=4.3; m. p. 130°; 1824. Phenylglyoximecarboxylic acid. (Phenylamphiglyoxime carboxylic acid). C9H804N2=PhC(:NOH).C(:NOH)(C02H). Exists only in soln. From cond. of the lactone in water, kA XlO' at 25° is at least 2; 768. See the lactone, Phenyloximino- s2/TO-oxazolone. Cond.; 701. 252 TABLES [Phe Phenylglyoxylcarboxylic acid see Phthalonic acid. Phenylglyoxylic acid. (Benzoylformic acid). C8H603=Ph.CO.C02H, kAXlO^ at 25°=6; increases on diln. A(29.1) =252.6, (931.2) =325.7, (oo) = 354; 70. Phenylglyoxylic acid an^i-oxime. (Phenylanii-ketoxime carboxylic acid. Phenyloximinoacetic acid; an) = 376; 574. /S-Phenyl-iS-hydroxy-propionic acid. C9Hio03=PhCH(OH).CH2.C02H. kAXl05=4. A(109) = 23.9. (872) = 65.4, (oo) = 376; 574. l-Pheiiyl-6-hydroxy-l,2,3-triazole-4-carboxylic acid methyl ester. C10H9O3N3. Phe] TABLES 253 kAXl0^at25°=1.6; diminishes on diln. At 50°= 1.5; diminishes ondiln.; m. p. 74°. At 25°, A(148.4) = 280.3 (1187) = 346.3, (co) = 371; 447. Enolic and ketonic forms in pyridine; 754. Na.A at 25°, A(32) = 63.3, (1024)=72.9; 447. Phenyliminodiacetic acid. CioHii04N=PhN(CH2C02H)2. kAXlO^ at 25°=2.73; diminishes on diln.; m. p. 150°-155°. m(210) = 184, (840)=262, (oo) = 352; 1840. Phenylindone-acetic acid. (3-Phenyl-l-ketoindene-2-methylcarboxy- lic acid). CwHiaOa. Comparative strength (colorim.); m. p. 167.5°; 1665. Phenylindone-acetic acid methyl ester. CisHuOa. Comparative strength (colorim.); 1665. Phenylisoxazolecarboxylic acid. C10H7O3N. kAXlO'at25°=5.5aq. A(186.6) = 218.5, (1492.8)=320, (co)=354; 23. 3-Phenylisoxazolone(5). (Phenyl-sj/n-oxazolone). C9H7O2N. kAXlO^ at 25°=5.5; diminishes on diln. A(512) = 54.1, (1024) = 72.7, (oo) = 355; 768. PhenyUtaconic acid. CiiHio04=Ph.CH:C(C02H).CH2.C02H. kAXlO* [at 25°] = 1.37. m(128)=46.4, (1024) = 115.6, (oo) = 375; 1684. Phenylketoximepropionic acid see |8-Benzoylpropiomc acid ozune. Phenyllutidinedicarboxylic acid. (2,6-Dimethyl-4-phenylpyridine-3, 5-dicarboxylic acid). Ci6Hi304N=(Me2)(Ph)C6N(C02H)2. kAXlO*at25°=1.2. M(512) = 76.9, (1024) = 101.4, (oo)=350; 1372. Phenyllutidinedicarboxylic acid mono ethyl ester. Ci7Hi704N= CiaHiiNCCOaH) (C02Et). kAXlO^ at 25°=5.3; diminishes on diln. iu(128) = 27.6, (1024) = 66, (co) = 350; 1372. 1-Phenyl-methoxy-acetic acid. (l-PhenylglycoUic acid methyl ether). C9Hio03=Ph.CH(OMe).C02H. kAXlO* at 25°=7.4; m. p. 63°-64°; 574, 1239. A(32) = 53.9, (1024) = 211.1, (oo) = 376; 574. Phenylmethyl- see Methylphenyl- l-Phenyl-3-methylthio-urazole. CgHgONsS. kAXlO^ at 25°=1.3; m. p. 174°-175°. A(1024) = 4, (2048) = 5.4, (co) = 355. Na.A at 25°, A(64) = 63.6, (1024) = 72.9; 18. l-Phenyl-2,3-naphthalenedicarboxylic acid. (3,4-Diphenyl-2,4-cyclo- butadiene-l,2-dicarboxylic acid. Phenenyltribenzoic acid. Triphenyl-trimesic acid). Ci8Hi204=Ph.CioH5(C02H)2. Na salt at 25°, /i(32) = 63.3, (1024) = 84.3; 1213. 254 TABLES [Phe Phenyl-j3-naphthylamine trisulphonic acid. (a-Naphthylphenylamine trisulphonic acid). Ci6Hi309NS3=Ci6HioN(HS03)3. At 25°, Ai(768) =329.7, (1536) = 329.7; 492. Phenylnitroamine. (Benzene diazoic acid. Diazo benzene acid). C6H602N2=Ph.NH(N02). kAXlO^ at 1°=1.2. At 10°=1.5. At 18°=1.7; m. p. 46.7°; 513. At 25° = 2.3; 736; = 1.3; 77. At 25°, A(128) = 19, (1024) = 51.6, (oo) = 35i; 736. InEt ale; 513. Phenyl-iso-nitroamine see Phenylnitrosohydroxylamine. Phenylnitromethane. (li-Nitrotoluene). C7H702N=Ph.CH2.N02. No cond. in aq.; 775. iso-Phenylnitromethane. C7H702N=Ph.HC.(ONOH). Na.A at 25°, A(32) = 75.8; m. p. of acid is 84°, rapidly heated; 775. Phenylnitrosohydroxylaniine. (Phenyl-iso-nitroamine) . C6H602N2=Ph.N(NO)OH. kAXlO^ at 0° = 5; increases on diln. A(128) = 5.5, (512) = 11.7, (oo)=221. Na.A at 0°, A(128) = 66.6, (1024) = 70.0; 736. Phenyl-fso-ox- see Phenylisox- Phenyl-syn-oxazolone see Phenylisoxazolone. Phenyloximinoacetic acid see Phenylglyoxylic acid oxime. Phenyloximino-syn-oxazolone. C9H6O3N2. kAXlO* at 25°=1.9; 768; 701. ju(512) = 93.7, (1024) = 122.1, (00) = 350; 768. InEt ale; 701. K.A at 0°, m(32)=46.6, (1024) = 51.2; 701. Phenylparaconic acid. C11H10O4. Cond.; m. p. 170°; 579. fso-Phenylparaconic acid. C11H10O4. Cond.; m. p. 170°; 579. Phenylphenanthrophenazonium hydroxide. C26H18ON2. At 0°, A(512) = 3.4 from cond. of B.Cl+NaOH. Is a strong base, but changes almost at once to the pseudo base, which has no cond. B.Cl (flavindulinium chloride) at 25°, A(64) = 86.3, (512) = 92.5; 770. PhenylpropioUc acid. C9H602= Ph.C i C.CO2H. kA XlO' at 25° =5.9; diminishes, then increases on diln. A(60) = 158.5, (960) = 305.5, (a=) = 352; 1371. Na.A at 25°, A(32) = 64.6, (1024) = 74.3; 1368a;- 1213. Phenylpropittnic acid see Hydratropic acid. Phe] TABLES 255 Phenylpropoxyacetic acid. CiiHi403=Ph.CH(OPr).C02H. kAXlO*=4.9; increases, then diminishes on diln. A(27.1)=40.6, (867.5) = 170, (oo) = 374; 574. 1-Phenyl pyrazole. CeHsNa. In aq., no cond.; 977. 3-Phenylpyridiiiecarboxylic acid. (Bz-2). (o-Pyridinebenzoic acid). Ci2H902N=C02H.C6H4.C6H4N. [C02H=2.] kAXlO« at 25°=5. A(128) = 7.7, (1024)=23.3, (oo) = 350; 1372. a-Phenylpyridine-dicarboxylic acid. (2-Phenylpyridine-Bz-2,Py-2- dicarboxylic acid). Ci3H904N=C02H.C6H4.C6H3N.C02H. kAXlO* at 25°=1.4. m(128) = 40.2, (1024) = 110.3, (oo) = 350; 1372. 2Na.A at 25°, m(32)=70.5, (1024) = 88.6; 1369. ^-PJienylpyridine-dicarboxylic acid. (3-Phenylpyridine-Bz-2,Py-2- dicarboxylic acid). C13H9O4N. kAXlO*at25°=l.l. At(64) = 27.2, (1024) = 100.9, (00) = 350; 1372. l-Phenyl-5-pyrrodiazolone-3-carboxylic acid. (Phenylcarbopyrro- diazolic acid). C9H7O3N3. A strong acid [no data]; m. p. 183°-184°. Cond. increased by boric acid; 1186. Phenylrosinduline. C28H19N3. Very small cond.; is really a non electrolyte; 770. Phenylsuccinic acid. CioHio04=C02H.CHPh.CH2.C02H.'l kAXlO* [at 25°]= 1.64; 1684, 1936. m(64.2) = 35.8, (1035) = 123.1, («>) = 374; 1936. Phenylsuccinic acid a-mono methyl ester. CiiH,204=C02Me.CHPh.CH2.C02H. kAXlO^ [at25°]=4.9; diminishes on diln.; m. p. 102°. At(510.9) = 54.6, (1023) = 74, (oo) = 374; 1936. Phenylsuccinic acid /3-mono methyl ester. CiiHi204= C02H.CHPh.CH2.C02Me. kAXlO^ [at 25°] = 1.1; diminishes on diln.; m. p. 92°; 1684, 1936. m(256.6) = 57.4, (1030) = 102.6, (co) = 374; 1936. Phenylsulphone-acetic acid. C8H8O4S = Ph.SO2.CH2.CO2H. kAXlO^ at 25°=4.22 (hydrol.); m. p. 112.5°-113° (cor.); 1467 and Lund6n, Aiiinitatsmessungen. a-Phenylsulphone-propionic acid. C9Hio04S=MeCH(S02Ph).C02H. kAXlO' at 25°=3.14 (hydrol.); 1467 and Lund6n, Affinitatsmes- sungen. Phenyltetric acid. C11H10O3. kAXlO* at 25° = 1.94. m(270) = 72, (1080) = 128, (oo)=353. Na.A at 25°, m(32) = 65.3, (1024) = 74.0; 1831. 256 TABLES [Phe Phenyl thiocarbimide. (Phenyl mustard oil. Phenyl-iso-sulphocya- nate). C7H5NS=CSNPh. 7^X10' at 25°=1.8; b. p. 222° @ 754 mm.; 1843; - 1223. InNHs, qual.; 606. Cond. with I; 1223. l-Phenyl-3-thio-urazole. CsHjONaS. kAXlO^ at 25°=1.7; increases on diln.; m. p. 192°-193°. A(64)=226.4, (256) = 292.8, (oo) = 355. Ba.2A. - Na.A at 25°, A(32) = 43.0, (1024) = 65.0; 18. Phenyl-p-tolylbenzenylamidine. (Benzenylphenylamino-p-tolylimi- dine. l,2-Diphenyl-3-p-tolylaniidine). C2oHi8N2=PhC(NHPh) :N.C6H4Me. B.HCl, A(128) = 84.1, (1024) = 92.2; m. p. 243°-244°; 1093. [The base has m. p. 135°-136°.] Phenyltriethyl- see Triethyl-phenyl- Phenyltrimethyl- see Trimethyl-phenyl- /3-Phenyl-7-trimethylacetyl-butyric acid. Ci6H2o03=Me3C.CO.CH2.CHPh.CH2.C02H. kAXlO^at 25°=2.6aq. A(641)=45.3, (1282) = 60.7, (co)=372; 1588. 1-Phenyl-urazole. CsHyOaNs. kAXl05at25°=l.l; m. p. 265°-267°. A(512)=26.4, (1024) = 36.3, (ao)=356.2. Na.A at 25°, A(32) = 60.0, (1024) = 81.6; 18. Phloretic acid. C9Hio03=MeCH(C6H4.0H).C02H. kxXlO^ at 25°=2.03. [Bougault, Compt. Rend. 131, 43, says that this is the same acid as p-Hydrocoumaric acid, k Xl0^= 1.7.] A(64) = 12.5, (1024)=46.6, (oo)=376; 1371. Phloridzin. C21H24O10. InNHs, qual.; 606. Phloroglucinol. (1,3,5-Trihydroxy-benzene). C6H603=C6H3(OH)3. kA=?. At 25°, k XIO^ for v (33.4) = 8, for v (133.6) = 18. /i(33.4) = 0.6, (133.6) = 1.7, (oo) = 355; 70. Cond. alone and with.NaOH; 1508, 1718. Phloroglucinol aldehyde. (2,4,6-Trihydroxy-benzaldehyde). C7H604=CHO.C6H2(OH)3. [CHD=1.] kAXl0Sat25°=4.3. Ai(315.4) = 39, (1261.6) = 72.8, (c») = 355; 643. Phloroglucinol carbozylic acid. (2,4,6-Trihydroxy-benzoic acid). C7H605=C02H.C6H2(OH)3. [C02H=1.] kA XlO^ at 25°=2; diminishes on diln. /i(32) = 194, (1024)=329, (a>) = 356; 1371. Cond. alone and with NaOH in Et ale; 1508, 1718. Pht] TABLES 257 Phorone. C9Hi40=Me2C:CH.CO.CH:CMe2. In SO2; 1842. Phosphoric acid mono iso-butyl ester. (iso-Butyl phosphoric acid). C4Hu04P=OP(OC4H9)(OH)2. At 25°, /i(32)=237, (512) = 366; 354. Phosphoric acid mono erythran mono ester. (Erythran phosphoric acid). C4H906P=OP(O.C4H702)(OH)2. At 25°, m(32) = 283, (512) = 370; 354. Phosphoric acid mono erythran di ester. (Dierythran phosphoric acid). C4H706P=OP(02:C4H60)(OH). Mixed with 65% of the mono ester, at 25°, m(8) = 232; 354. Phosphoric acid mono ethyl ester. (Ethyl phosphoric acid). C2H704P= OP(OEt) (0H)2. At 25°, m(32) = 241, (512) = 369; 354. Phosphoric acid diethyl ester. (Diethyl phosphoric acid). C4Hii04P=OP(OEt)2(OH). kAXlO^ at 25°=9.8 (cond.); = 10 (inversion). At 25°, m(32) = 300.8, (1024) =373, (00) =379. Na.A at 25°, m(32) = 68.4, (1024) = 80.4; 859. Phosphoric acid tetrafluoro-diethyl ester. (Tetrafluoro-diethyl phos- phoric acid). C4H704PF4=OP(OC2H3F2)2(OH). kAXlO at 25°=6.2 (inversion). At 25°, M(32)=346.5, (1024) = 379.2, ()=350; 175. Pyroracemic acid. (Acetyl formic acid. Pyruvic acid). C3H403=Me.CO.C02H. kAXlO' at 25° is about 5.6 (inversion); 768; is about 3 (cond.); diminishes on diln.; 1370. In H2SO4; 223. Cond. not increased by boric acid; 1184. Pyrotartaric acid. (Methylsuccinic acid). C6H804=C02H.MeCH.CH2.C02H. kiXlO^ at 0°=7.9. At 12°=7.9; 1968a. At 17°=8.3 aq.; 164; (colorim.); 1781. At 25°=8.6; m. p. 111°; 234, 1371, 1500b, 1823, 1831, 1838;=8.7; 1968a. At 35°=8.9; 1968a. Second kAX 10'= 1.6 (inversion); 1335, 1638. Cond. at 0°-35°; 1968a. At 17°; 171. At 25°, m(32) = 18.1, (512) = 66.5, (oo)=354; 1838. m(1024) = 89.7, (oo) = 349; 1968a. Cond. with KOH; 171. K.A.- 2K.A; 164.- Na.A at 25°, /i(32) = 70, (1024) = 89; 1838. - 2Na.A at 25°, ^(32) = 78, (1024) = 96; 1838; 270, 1367, 1823, 1831, 1837. Pyrotartaric acid anhydride. CbHbOs. Cond. of soln. showing change to acid; 1500b. Pyrotartaric acid mono methyl ester. C6Hio04= CO2Me.MeCH.CH2.CO2H. Three different preparations gave; kAXlO* at 25°=3.90 for ester, b. p. 140° @ 11 mm.; =3.85 for ester, b. p. 142°-143° @ 15 mm.; =3.80 for ester, b. p. 138°-140° @ 13 mm. Qui] TABLES 271 /u(42.4) = 14.1, (169.6)=27.6, (oo)=353; for the first ester, k= 3.90; 244. a-iso-Pyrotartaric acid see Ethylmalonic acid. /3-Jso-Pyrotartaric acid see Dimethyl-malonic acid. Pyrrole. C4H6N. In HBr, HCl and HI, good cond. In H2S, no cond. ; 1897. Pyrrole-2-carboxylic acid. (Carbopyrrolic acid). C6H6O2N. kAXlO^ at 25°=4.03 aq.; m. p. 192°; 23;=3.65 aq.; 1186. A(40) = 14.2, (1280) = 72.8, (oo)=359; 23. Cond. with boric acid; 1186. 2-Pyrrolepyroracemic acid. C8H704N=C4H4N.CO.CH2.CO.C02H. kxXlO^at 25° =8.9 aq.; from soln. of the anhydride in aq.; diminishes on diln. A(200) = 121.6, (1600)=236.3, (00) = 355; 23. 2-Pyrrolepyroracemic acid anhydride. (2-Pyrroylpyroracemic acid anhydride). CsHeOaN. For measurement see the acid. PyrroUdine-a-carboxylic acid. (Proline). C6H9O2N. Cond.; m. p. 206°-207°; 145b. Pyrroylcarboxylic acid see Pyrrylglyoxylic acid. 2-(a)-PyTrylglyoxylic acid. (a-Pyrroylcarboxylic acid). C6H603N=C4H4N.CO.C02H. kAXlO' at 25° =9.7 aq.; diminishes on diln. from decomposition. A(60) = 188, (960)=263.4, (oo) = 358; m. p. 76°; 23. Pyruvic acid see Pyroracemic acid. Q. Quillaja. [The references to this are not complete. ] Cond. of soln. of bark; 146. Quinaldine. (2-Methyl quinoline). C10H9N. ks XlO' at 14°=3.6 (colorim.); 1777. At 25° is about 4 (hydrol.); 664. B.HClat25°, A(64)=90.4, (256) = 95.2; 270; - 1864.- B.H2SO4; 1864. Quinaldinic acid. (a-Quinoline carboxylic acid. Quinoline-2-car- boxylic acid). C10H7O2N. kAXlO'at25°=1.26; diminishes on diln. A(128) = 13.9, (1024) = 34.8, (oo)=355; 1372. Quinalizarin. (1,2,5,8-Tetrahydroxy-anthraquinone). CuHgOe. 2Na.A at 25°, A(32) = 95.6, (1024) = 118.4. - 3Na.A at 25°, A(32) = 120.6, (1024) = 133.5.- 4Na.A at 25°, A(32) = 138.6, (1024) = 1527; 1275. 272 TABLES [Qui Quinic acid. C7Hi206= (OH)4C6H7.C02H. kAXlO^ at 14.1°=2.77; m. p. 161°; 541. At 18°=2.6 (colorim.); 1563. At 25°=2.9 aq.; 1186;=2.8 increasing on diln.; 1648. Cond.; 1495. At 25°, m(32) = 32.7, (512) = 108, (=°) = 350; 1186. InEtalc; 1185. Cond. with boric acid; 1185, 1186. With M0O3; 1495. With Zr02 and NaOH; 1648. inac^-Quinic acid. C7H12O6. kAXl0^at9°=2.2; 541. Quinic acid see also Quininic acid. Quinidine. (Conquinine). C20H24O2N2. ksXlCat 15° = 2.36 (hydrol.); 1779. Second kBXl0i''=3.2 (colorim.); 1776. Cond. with o-bromocamphor sulphonic acid in aq. and in acetone; 1841. Quinine. C20H24O2N2. ksXlO' at 15° =2. 16 (colorim.); 1779. At 16°=26 (colorim.); 98a. At 18°= 17 (cond.); 1224. At 25°= 120 aq. (cond.); 1241. Second kBXl0i'>=3.3 (hydrol.); 1776; = 1.3 (colorim.); 98a. At 18°, Ai(1671) = 10.3, (oo) = l96; 1224. At 25°, m(1335.7) = 21.5, (CO ) = 189.4; 1241. In SO2; 1842. With allyl thiocarbimide, no cond. ; 1223. B.HBr in SO2; 1842.- B.HCl at 25, A(82)=75.8, (1024) = 89.1; 270; 1224, 304. In SO2; 1842. - B.HF and B.HI in SO2; 1842. - B.HNO3; 304, 1611. - B.H3PO2 in NH3, qual.; 606. - B.H2SO4; 304. - 2B.H2SO4; 304; qual.; 943, 1223. - B.Ace- tate; 304. Quininic acid. (6-Methoxy-quinoline-4-carboxylic acid. Quinic acid. Xanthoquinic acid methyl ether). CuHgOsN. kiXlO^ at 25° = 9.7; diminishes on diln. A(256) = 17.1, (1024) = 31.4, (co) = 351; 1372. Quinol see Hydroquinone. Quinoline. C9H7N. xxW at 0°=3.8; 1844. At 25°=3.7; 1106, 1107. ksXlC at 15°= 1.6 (colorim.); 1777. At 25°=0.8 (hydrol.); 664. At 60°=7.4 (inversion); 1880. In HBr and H2S, fair cond.; 1897. In HCN, small cond.; 943. In SO2; 1842, 1855. In AsCls, in POCI3, and SO2CI2; 1842. InNHs, qual.; 606. Cond. with inorg. compounds; 1106, 1107, 1481. With organic compounds; 1388. As solvent; 1844. Rho] TABLES 273 B.HCl at 25°, A(64) = 95.6, (256) = 99.2; 270; 1864.- B.H2SO4; 1864. - B.MeCl; 270. - B.Mel; 1844. - B.HI.I2, - B.BuI.Iz, -B.-ts0-BuI.I2, - B.Etl.Ij, - B.Mel.Ij, - B.MeI.l4, - B.PrI.12; cond. of these iodides in molten state; 1678. iso-Qtiinoline. C9H7N. ksXlO' at 15°=3.6 (colorim.); 1777. [10" in 1777 is a typo- graphical error.] InNHs, qual.; 606. ^ B.HCl at 25°, A(64) = 95.2, (256) = 100.1. - B.MeCl; 270. a-Quinoline carboxylic acid see Quinaldinic acid. 7-Qiiinoline carboxylic acid see Cinchoninic acid. Quinolinic acid see Pyridine-2,3-dicarboxylic acid. Quinone see p-Benzoquinone. Quinone-p-oxyphenyl-hydrazone see p-Azophenol. R. Racemic acid see para-Tartaric acid. Raffinose. C18H32O16. Cond. alone and with lactose; 1747. Cond. with KCl; 145b. In NH3, qual.; 606. Resorcinol. (1,3-Dihydroxy-benzene). C6H602=C6H4(OH)2. kA X10« at 0° is less than 3.1; 733. At 18°=0.36 (hydrol.); 524. At 25° is less than 6; 733. - (solub.); 1116; (cond.); 70. At 40° is less than 37; 733. Cond.; 70, 733, 1184, 1508, 1718. At 25°, m(34.1) = 0.3, (68.2) = 2.1, (eo)=356; 70. m(32)=0.14; 733. In HBr; 29. In HCN, no cond.; 943. In NH3, qual.; 606. In MeNH2, good cond.; 637. Cond. with boric acid; 1184. With NaOH; 1017, 1508, 1718. With FeCls; 756. NH4 salt at 18°, A(200)=44.4, (400) =46.2; 524. Resorcyl aldehyde see 2,4-Dihydroxy-benzaldehyde. ^ Resorcylic acid see 2,4:-Dihydroxy-benzoic acid and 2,6-Dihydroxy- benzoic acid. Rhamnus Frangtda. (Buckthorn). [The references to this are in- complete. ] Cond. of soln. of bark; 146. Rhodamine. [C20H14O3N2? There are several Rhodamines of dif- ferent composition. The following references do not state which was used.] In Et ale, cond. is increased by light; 833, 1321. Rhodanic acid see Rhodanin. 274 TABLES [Rho Rhodanin. (Dithio-carbamine glyeoUic acid anhydride. Rhodanic acid.) C3H30NS2=CO.CH2S.CS.NH. kiXlO* at 25°=3 (catal.); m. p. leSMBQ"; 854. Rhodanoacetic acid see Thiocyanoacetic acid. Rhodizonic acid. C6H206=C604(OH)2? At 25°, m(254.8) = 130.6, (1019.1) = 161.3. Na.A at 25°, m(128) = 178.6, (1024) = 198.7; 389. Ricinus communis. (Castor oil plant). [The references to this are incomplete. ] Cond. of sap of root and stalk; 253, 1326. Roccelline see Naphthalene sulphonic acid azo-jS-naphthoI. Rosa banksia. [The references to this are incomplete. ] Cond. of sap; 253. RosanUine see Fuchsine. p-Rosaniline see Triamino-triphenyl-carbinol. Rosindone. (Rosindulone). C22H14ON2. Is a non-electrolyte; 770. B.CI see under Chlorophenylnaphthophenazonium hydroxide. Rosinduline. C22H16N3. Pure rosinduline is a pseudo-base with no cond. The salts are formed from Rosindulinium hydroxide, C22H16N3.OH; which gives at 25°, /i(512)=23.4. B.Cl=C22Hi6N3Cl (Rosinduline HCl); at 25°, m(256) = 94.0, (1024) = 95.9; 770. Rosindulone see Rosindone. Rosolic acid. C20H16O3. kAXlO« at 18°= 1.1 (colorim.); 1562. d-Saccharic acid. C6Hio08=(OH)4C4H4(C02H)2. At 25°, kxXlO' is about 1, calculated from values given by a slightly impure acid; 1249; is about 1.9; aq. used for soln. was impure; 1362. [In 1249 the value of A(<») is given as 330, an unusual value. ] At 25°, A(32) is about 60, (1024) is about 225; (oo) = 330; 1249. In HCl, no cond.; 30. Saccharin. (Saccharinic acid anhydride or lactone). CeHioOB. kxXlO^ at 25°=1.3; diminishes on diln.; 1823, 1831. Cond.; 1493. At 25°, At(32)=2.3, (128)=4, (oo) = 358; 1823. Saccharin see Benzoic sulphinide. ISO-Saccharin. (iso-Saccharinic acid anhydride or lactone). CeHioOe. Sap] TABLES 275 kAXlO« at 25°= 1.8; diminishes on diln.; 1823, 1831. m(32) = 2.7, (128)=4.5, (oo)=358; 1823. Saccharinic acid. (Glycosaccharic acid). C6Hi206=(OH)4C6H7.C02H. K.A at 25°, A(32)=78.9, (1024) =99.2. - Rb.A; 1493. Saccharinic acid anhydride see Saccharin. Saccharinic acid lactone see Saccharin. iso-Saccharinic acid lactone see iso-Saccharin. d-Saccharo-lactonic acid. C6H807=(CHOH)2.CO.O.CH(CHOH).C02H. kA XlO' at 25°=1.7; m. p. 129°-130°. [The value of A(co ) used here is 330, an unusual value.] A(32) = 67, (1024) = 235.8, (oo)=330; 1249. Saccharose. (Cane sugar. Sucrose). CviSziOu. kAXlQi' at'lO°=0.7'(catal.). At 18°=1.14 (catal.); 1177 and 1160. At 20.7°= 1.1 (catal.); 1036. At 25°= 1.85 (catal.). At 40°=4.3 (catal.); 1177 and 1150. (Colorim.); 1639b. Cond.; 588, 641, 686, 1036, 1108, 1110, 1222, 1478, 1747, 1983. In NHa, qual.; 606. In MeNHa, small cond.; 637. Cond. with inorg. acids and bases; 741, 1035, 1039, 1220, 1383. With inorg. salts; 145b, 210a, 324, 686, 1220, 1432, 1983. With organic compounds; 45, 1468, 1569, 1639b, 1747. Salicin. CisHisO?. In NHa, qual.; 606. Salicyl aldehyde see o-Hydroxy-benzaldehyde. homo-Salicyl aldehyde see Hydroxy-toluic aldehyde. Salicylamide see o-Hydroxy-benzoic acid amide. I-0-, SaUcylhydroxamic acid. C7H703N=OH.C6H4.CH.N.OH. kAXl0« [at 25°] = 6.4. m(32) = 5, (128) = 11.2, (oo)=[380]; 1353a. Salicylic acid see o-Hydroxy-benzoic acid. iso-Salicylic acid see fso-o-Hydroxy-benzoic acid. Saliva. [The references to this are incomplete. ] Cond.; 257, 290a, 878, 879, 880, 881, 1447a; 253. Concentration of H and OH ions; 587. Sambucus nigra. (Elder). [The references to this are incomplete.] I » Cond. of sap; 263. Saponin. There are a number of saponins of different formulae; C17H26O10, CisHisOio, C19H30O10, C32H62O17, C32H64O18. See also Weil, Arch. Pharm. 239, 363, (1901). Soln. of saponin, CisHisOio, has no cond.; 2013. In benzine; 931. Cond. with NaOH; 617a. With allyl thiocarbimide, no cond.; 1223. 276 TABLES [Sar Sarcosine see Methylamino-acetic acid. Scombrine. CsoHeoOsNie. B.2H2SO4 shows increase of cond. after digestion with trypsin; 146b. Sebacic acid. CioHi804=C02H.(CH2)8.C02H. kiXlO^ at 18°=2.5 (colorim.); 1563. At 25°=2.76; m. p. 128°; 279; = 2.8 aq.; m. p. 134.5°; 1810; = 2.34; 1371, 1638. Second kAXlO«=2.6 (part.);=2.5 (cond.); 370;=2.6 (inversion); 1638. At 25°, m(256) = 28, (1024) = 54.3, (m) = 350; 279. In HBr and HCI, no cond.; 30. Na.A; 370. - 2Na.A at 25°, A(32) = 69.4, (1024) = 84.4; 270; 370. Sebacic acid anhydride. CioHieOs. Cond. of soln. showing change to acid; 1810. Sebacic acid mono ethyl ester. Ci2H2204=C02H.(CH2)8.C02Et. kiXlO^ at 25°= 1.4; m. p. 38°. m(483) = 28.1, (966) = 38.8, (co)=350; 1859. Selenium see Diethyl selenium thetine, and the following compounds. Selenium diglycolUc acid. C4H604Se=Se(CH2.C02H)2. kiXlO^ [at 25°] =4.2. m(32) = 39.2, (1024) = 183.6, (co)=358; 1134. Selenium dilactylic acid. C6Hio04Se=Se(C2H4.C02H)2. (a) kAXlO* at 25°=4.16; m. p. 145°. ^^(42.4) = 43.5, (1356.2) = 187.6, (a>)=356. (b) kAXlO* at 25°=3.8; increases on diln.; m. p. 109°. m(44.2)=42.4, (1413) = 187, (oo)=356; 403. Semicarbazide. CH60N3=NH2.CO.NH.NH2. kaXlOi" at 15°=91 (colorim.); 1775. At 40.2°=0.26 (catal.); 1995. Senna. [The references to this are incomplete.] Cond. of soln. of leaves; 146. Serum see Blood. Serum globuUn. [The references to this are incomplete. ] Serum globulin is probably a mixture of at least two compounds. The following references are to the globulin of the blood of the horse and ox. As acid, at 20°, it is about the strength of phosphoric acid, (catal.); 783a. Cond. of suspension in aq. at 18°; 783a. Cond. with inorg. acids; 783a, 1503. With inorg. bases; 617a, 783a, 1503. With organic acids; 783a. Concentration of H ions; 1511b. Sta] TABLES 277 ShiMmic acid. CvHioOj. kAXlO^ at 14.r=7.1; m. p. 184°. [The same measurement is given in both references.] m(41) = 15.9, (1305) = 78.4, (oo) = 303; 541, 838. Silicic acid tetra ethyl ester. C8H2o04Si=Si(OEt)4. X XlO« at 25° is less than 3; b. p. 165.5° @ 740 mm. Cond. with trichloro-acetic acid; as solvent; 1223. Silicic acid tetramethyl ester. C4Hi204Si=Si(OMe)4. xXlO^ at 25°=1.6; b. p. 120°-122°. Cond. with FeCla and with trichloro-acetic acid; as solvent; 1223. Silicon. See the preceding and succeeding compounds. Silicon tetraphenyl. C24H2oSi=Ph4Si. In SO2; 1842. Silver. See the succeeding compound, and 971. Silver cyanic acid. (Argenti- or argento- cyanic acid). C2HN2Ag=HAg(CN)2. See 510. K.A at 25°, A(32) = 103.2, (1024) = 115.5; 1832; 971; - 1434a. In organic solvents.; 1434a. Skatolecarboxylic acid see 3-Methyl-indole-3-carboxylic acid. Solanum laciniatum. [The references to this are incomplete. ] Cond. of fruit; 1326. Soluble Blue see Helvetia Blue. Sorbic acid. C6H802=MeCH:CH.CH:CH.C02H. kAXl0=at25°=1.73. A(128) = 16.2, (1024)=44.3, (oo)=355; 1371. In HCl, smaU cond. ; 30. Sparteine. C15H26N2. ks XlO* at 15° is over 1 (hydrol.); 1779. Spirit Blue. Trisulphonic acid. [This is called Triphenyl-p-rosaniline tri- sulphonic acid (=C37H3iOioN3S3) in the following reference. The dye is usually said to be the hydrochloride, sulphate or acetate of a mixture of triphenyl-p-rosaniUne and triphenyl- rosaniline. ] At 90°, m(200) = 1239, (1600) = 1486; 976a. Spleen. [The references to this are incomplete. ] Cond.; 156a, 623,624; 253. Stanni- see under Tin. Stanno- see under Tin. Starch. (C6Hio06)x. When pure is insol. in aq. The last wash liquor has xX 10^=4; 1209a. 1% soln., x xlO^ at 18°=1.8; 1160. 2% soln. 278 TABLES [Ste xXlO^ at 25°= 1.5; 690. Increase of cond. during trans- formation from colloidal to granular form; 695. Form when in so}n. ; 260a. Cond. with acids; 783a; qual.; 594. With bases; 693, 783a. With KI and I; 1160, 1381. Stearic acid. Ci8H3602=Ci7H36.C02H. Dielectric constant; 1206. K.A at 25°, A(64) = 68.8, (1024) = 110.2; 945. Stearic acid glyceryl ester. (Tristearin). C67Hllo06= (Cl8H3602)3C3H6. Effect of temperature on cond. ; 106. Stilbene disulphonic acid disazophenol mono ethyl ether see Chry- sophenine. Storax cinnamic acid see Cinnamic acid. Stovaine see Methylethyl-dimethylamino-methyl carbinol benzoate. Strychnine. C21H22O2N2. ksXlO^ at 15°=1.43 (hydrol.); 1779, 1776. At 18°=8.6; 1224. At 25° =600 aq. [apparently erroneous]; 1241. Second kBXl0ii=5.95 (hydrol.); 1776. Cond. at 18°, m(4382) = 11.6, (oo) = l95; 1224; - 943. At 25°, /i(4906) = 83, (cx>) = 190; 1241. In HBr and H2S, no cond.; 1897. In HCN; 943. B.HClat25°, A(32)=79.0, (1024)=91.9; 270; - 1224. -B.HNO3; 1611.- B.Hgt; 1223.- B.(C2H4Br)Cl. - B.EtCl; 270. Styphnic acid see Trinitro-resorcinol. Suberane carbozylic acid see Cycloheptane-carboxylic acid. Suberene carboxylic acid see 1-Cycloheptene-l-carboxylic acid. Suberic acid. C8Hi404=C02H.(CH2)6.C02H. kAXlO^ at 18°=2.8 (colorim.); 1663. At 25°=2.96; m. p. 138°; 279; 1638, 1810;=2.58; 198, 1371; = 3.11; 175. Second kAXl0'=2.1 (inversion); 1336; = 2.5 (inversion); 1638;= 1.9 (cond.);=3.7 (part.); 370; - 1911. At 25°, jit(128) = 21, (1024) = 56.2, (oo) = 351; 279. Na.A; 370. - 2Na.A at.25°, A(32)=72.3, (1024) = 87.3; 270; 370. Suberic acid anhydride. C8H12O3. Coiid. of soln. showing change to acid; 1810. , Suberic acid mono ethyl ester. CioHi804=C02H.(CH2)6.C02Et. kAXlO* at 25°= 1.46; m. p. 18°. m(74.5) = 11.5, (1192)=43.3, (oo) = 351; 1859. Succinamide see Succinic acid amide. Succinanilic acid. (Anilinosuccinic acid). CioHii03N= CO2H.C2H4.CO.NHPh. kAXlO^ at 25°=2.07; increases on diln. i«(64) = 12.2, (1024)=47.3, (co)=350; 1372. Sue] TABLES 279 Succincyanamic acid see Succinic acid mono cyanoamide. Succincyanoamide see Succinic acid di-cyanoamide. Succin-dialdehyde. C4H602= CHO.CH2.CH2.CHO. xXlO^ [at 20°?]=].0; diminishes on standing from polymeriza- tion; b. p. 169°-170°; 784. Succinic acid. C4H604=C02H.CH2.CH2.C02H. kAXlO^ at 0°=5.62; 1968a; = 5.11 aq.; 1018. At 5.7°=6.15; 1968a. At 17°= 6.35 aq.; 164. At 18°=6.9 (colorim.); 1563; 1781. At 21.5°=6.0; 1416. At 25°=6.8; m. p. 180°; 279, 190. The other values vary from 6.3 to 6.9 aq.; - 1184, 1371, 1500b, 1587, 1810, 1968, 1971;=6.65; 1968a; (com- parative); 1643. At 35°=6.69; 1968a. Second kAXlO^=2.2 (part.); = 2.7 (cond.); 370;=2.3 (inversion); 1335, 1638; =4 (part.); 1231. Cond.; 171, 642, 691, 782, 1023, 1122, 1495, 1500b, 1508, 1718; qua!.; 865. At 0°; 910. At 0°-35°; 1968, 1968a. At 5°- 18°; 1741. At 18° and 52°; 43. At 35°-65°; 388a. At 25°, m(32) = 16.3, (1024)=83, (oo)=356; 279. In H2SO4; 223. In N2O4, no cond.; 602. In Et ale; 754, 782. In p3rridine, fair cond.; 934. Cond. with boric acid; 1184. With M0O3; 691, 1023, 1495. With KOH; 171. With NaOH; 1508, 1636, 1718. With Na2W04; 1023. With acetic acid; 1821. With iso-caproic acid; 145b. Under pressure of 1-260 atmospheres; 542. 2(NH4).A; 145a, 823. - Co.A; 1735. - Mg.A; 1735, 1836. - Ni.A; 1735. - KA; 164. - 2K.A; 164, 171, 494. - Na.A at 25°, A(32)=76, (1024)=94; 370; - 43, 1643. - 2Na.A, at 0°; 635. At 25°, A(32) = 81.7, (1024) = 98.0; 270, 370; 1508, 1636, 1718. Under pressure of 1-260 atmospheres; 542. Succinic acid di-amide. (Succinamide). C4H802N2= CONH2.C2H4.CONH2. Hg salt, e. m. f.; 963. Succinic acid mono cyanoamide. (Succincyanamic acid). C6H603N2=C02H.C2H4.CO.NH(CN). kAXlO* at 25°=3.0. i«(61.9)=45.6, (990.4) = 146.4, (oo) = 352; 70. Succinic acid di-cyanodiamide. (Succincyanoamide). C6H602N4=CO.NH(CN).C2H4.CO.NH(CN). kA XlO^ at 25°=6.7; diminishes on diln. m(157.5) = 34.3, (1260) = 62.4, (00) = 350; 70. Succinic acid anhydride. C4H4O3. Cond. of soln. showing change to acid; m. p. 120°; 1500b, 1810, 1838. 280 TABLES [Sue Succinic acid mono ethyl ester. C6Hio04=C02H.C2H4.C02Et. kiXlO^at 25°=3.02. m(36.4) = 11.5, (582)=43.5, (o3) = 352; 1859. Succinic acid diethyl ester. C8Hu04=C2H4(C02Et)2. InNHs, qua!.; 606. Effect of temperature on cond. ; 106. Succinic acid mono methyl ester. C5H804=C02H.C2H4.C02Me. kiXlO^ at 25° = 3.2; m. p. 58°; 244, 1859. iu(38.8) = 12.4, (620.8) = 46.9, (oo)=354; 1859. iso-Succinic acid. (Ethylidenesuccinic acid. Methylmalonic acid) C4H604= Me.CH(C02H)2. kA XlO* at 25°=8.6; diminishes on diln.; m. p. 128°; 1838, 1371. Second kAXlO^=7.6 (inversion); 1638. At 25°, Ai(32) = 54.4, (512) = 168.9, («>)=357; 1838. iso-Succinic acid mono ethyl ester. C6Hio04=Me.CH(C02H)(C02Etj. kAXlO* at 25°=3.9; diminishes on diln. M(34) = 38.3, (544) = 127.8, (co)=352; 1859. iso-Succinic acid diethyl ester. C8H14O4. Relative strength (inversion) ; 1764. Succinic nitrile see Ethylene cyanide. Succinimide. C4H6O2N. kAXlO"at25° = 3.0(catal.); 1996.- 1838. Cond. at 25°, m(32) = 0.4; 1097, 1838; qual.; 70. InNHa, qual.; 606. Cond. with inorg. salts; 149, 1097. With organic compounds; 1096. Cu.2A; 1085. - Hg.A; 1094, 1097. In NH3; 610. E. m. f.; 149, 963.- KA with inorg. salts, e. m. f.; 149.- Ag.A; 1096. - Na.A at 25°, m(32) = 74.8, (1024) = 95.4; 1838. - Com- plex salts; 1097, 1750, 1752, 1755. Succinthionuric acid see Thiosuccinuric acid. Succintoluidic acid see Tolylsuccinamic acid. Succinuric acid. C6H804N2=C02H.C2H4.CO.NH(CONH2). kAXlO*at25°=3.1. A(64) = 15.2, (1024) = 57.4, (oo) = 352; 1372. Na.A at 25°, A(32) = 63.2, (1024) = 73.1; 1368a. Sucrose see Saccharose. Sulphamide see Sulphuric acid di-amide. o-Sulphaminebenzoic acid. C7H704NS = C02H.C6H4.S02NH2. kAXlO'at 25°=2.3; m. p. 152°; 1981; = 2.1; 781. A(25) = 76, (800) = 251.1, (oo) = 360; 1981.- 781. p-Sulphaminebenzoic acid. C7H7O4NS. kAXl0^at25°=2.6. Sui] ^ TABLES 281 A(160) = 64.4, (1280) = 149.1. Na.A at 25°, A(32) = 62.5, (1024) = 72.5; 781. Sulphaminobarbituric acid see Thionuric acid. Sulphanilic acid see p-Aniline sulphonic acid. Sulphimide see Trisulphimide. o-Sulphobenzoic acid amide. (o-Carbaminebenzene sulphonic acid). C7H-,04NS= CONH2.C6H4.SO3H. At 25°, A(50) = 317, (100) = 326.5, (oo) = 361; m. p. 193°-194° (uncor.). Na.A at 25°, A(20) = 69.1, (40) = 72.8; 1981. m-Sulphobenzoic acid. C7H606S=C02H.C6H4.S03H. kiXlOat 25°=4?. /i(22.6) = 343.9, (a>) = 377; 1909. m-Sulphobenzoic acid a-mono methyl ester. (Sulphonic ester). C8H80BS = C02H.C6H4.S03Me. kAXlO* at 25°= 6.8; extrapolated, because of saponification; m. p. 134°-136°. A(651) = 198.6 at once, =239.7 after 225 minutes, (co ) = 375; 1909. m-Sulphobenzoic acid /S-mono methyl ester. (Carboxylic ester). CsHsOsS = COzMe. C6H4.SO3H. kAXlO at 25°= 2?; m. p. 56°-62°. A(43.2) = 341.8, (1397) = 373.2, (ra) = 375; 1909. Sulphocyanic acid see Thiocyanic acid. iso-Sulphocyanic acid. See the thiocarbimides; e. g. allyl thiocarbi- mide etc. Sulphonediacetic acid. C4H6O6S = SO2 (CH2C02H)2. kAXl02at25°=1.30; 1133. Second kAXlO*=4.8 (cond.); 1911. At 25°, m(32) = 168, (256) = 328, (co) = 358; 1133. a-Sulphonedipropionic acid. C6Hio06S=S02(CHMe.C02H)2. kAXl02at25°=1.03; 1133. Second kAX 10*= 3.6 (cond.); 1911. At 25°, m(32) = 155.6, (256) = 304, (co) = 355; 1133. (S-Sulphonedipropionic acid. C6Hio06S=S02(CH2.CH2.C02H)2. kAXlO^at 25°=2.4. m(128) = 58, (256) = 77.3, (1024) = 139.2, (a>)=355; 1133. a-Sulphonepropionicacetic acid. C5H806S=C02H.CH2.S02.CHMe.C02H. kAXl02at25°=1.2; 1133. Second kAX 10^=4.5 (cond.); 1911. At 25°, m(32) = 163.3, (256) = 321.3, (oo) = 356; 1133. /3-Sulphonepropionicacetic acid. C6H806S=C02H.CH2.S02.(CH2)2.C02H. kAXlO^at 25°=5.1. Ai(32) = 117.2, (256) = 235.8, (oo)=356; 1133. 282 TABLES [Sul 5-Sulphosalicylic acid. (2-Hydroxy-5-sulphobenzoic acid). C7H606S=HS03.C6H3(OH).C02H. [C02H=1; 0H=2; S03H=5.] Cond. alone and with NaOH; m. p. 120°; 1608, 1718. Sulphuric acid. H2SO4. [The references to this are incomplete. ] V (16) (64) (256) (512) (1024) At 0°, A= 187.0 213.6 239.8 253.2 260.3 At 15°, A=237.0 270.9 304.7 335.8 343.0 At 25°, A=261.2 310.6 359.8 371.5 376.2 In reciprocal ohms. (Tower, Conductivity of Liquids.) Sulphuric acid di-amide. (Sulphamide). 02S(NH2)2. [The refer- ences to this are incomplete.] No cond. in aq. soln.; m. p. 91.5°; 761. In NH3; 610. Sulphuric acid mono fso-butyl ester. (iso-Butyl sulphuric acid). C4H10O4S = O2S (OC4H9) (OH) . At 25°, m(32) = 328.4, (1024) = 354.8. Na.A at 25°, ai(32) = 67.2, (1024) = 79.1; 1366. Sulphuric acid mono ethyl ester. (Ethyl sulphuric acid). C2H604S = 02S(OEt)(OH). At25°, m(32) = 340.9, (10r4) = 367.4; 1366. Ag.A; 1111.- Na.A at 25°, /i(32)=77.2, (1024) = 87.5; 1366. InNHs, qual.; 606. Sulphuric acid diethyl ester. (Diethyl sulphate). C4Hlo04S=02S(OEt)2. xXlC at 0°=1.64. At 25°=2.63; b. p. 110°-111° @ 25 mm. Cond. as solvent of NEt4l; 1844. Sulphuric acid mono methyl ester. (Methyl sulphuric acid) . CH404S=02S(OMe)(OH). At 25°, /i(32) = 345.0, (1024) = 368.1; 1366. Comparative strength (colorim.); 1643. Na.Aat25°, m(32) = 79.6, (1024) = 91.4; 1366. Sulphuric acid dimethyl ester. (Dimethyl sulphate). C2H604S=02S(OMe)2. KXlO' at 0°=1.644; 1844. At 20°=10.0; 1843. At 25°=3.085; 1844; - 1834, 1843, 1669. InH2S04, qual.; 760. Cond. as solvent; 1669, 1834, 1844. Sulphuric acid propyl ester. (Propyl sulphuric acid). C3H804S=02S(OPr)(OH). At 25°, m(32) = 333.8, (1024) = 359.9. Na.A at 25°, m(32) = 71.0, (1024) = 83.0; 1366. Sulphurous acid. H2SO3. [The references to this are incomplete.] Tan] TABLES 283 kAXl02at25°=1.6; 460; = 1.74 (cond.);=1.64 (hydro!.); 960. m(20.1) = 169.5, (40.0) = 207.6, (79.3) = 244.5, (oo) = 390; 960. Sulphurous acid mono ethyl ester. (Ethyl sulphurous acid). C2H6O3S =08 (OEt) (OH) . Na.A at 25°, m(32) = 79.7, (1024) = 105.4; 1623. Sulphurous acid diethyl ester. (Diethyl sulphite). C4Hio03S = OS(OEt)2. K XlO' at 0°=2.06. At 25°=3.46; b. p. 158.5° @ 750 mm. Cond. as solvent; 1844. asi/m.-Sulphurous acid diethyl ester see Ethyl sulphonic acid ethyl ester. Sulphurous acid mono methyl ester. (Methyl sulphurous acid). CH403S=OS(OMe)(OH). Na.Aat25°, m(32) = 78.9, (1024) = 115.5; 1523. Sun spurge see Euphorbia helioscopia. Sweat. [The references to this are incomplete. ] Cond.; 1713. Concentration of H and OH ions; 587. T. Tannic acid. (Gallotannic acid. Leucotannic acid. Often called tannin). C41H32O26? C14H12O9? See also Digallic acid and Tannin. The formula and structure are in doubt. Fischer, Freudenberg, Ber. Deutsch. Chem. Ges. 45, 915, 2709, (1912) have made a synthetic pentagaUoyl-glucose [called by them pentadigalloyl-glucose in some places] C4iH32026=C6H706[C6H2(OH)3CO]5 which gives the reac- tions of purified tannin (=tannic acid). Nierenstein, Ber. Deutsch. Chem. Ges. 43, 628, (1910) finds that the formula is Ci4Hi209=(OH)3C6H2.CHOH.O.C6H2(OH)2.C02H. Pan- iker, Stiasny, Jour. Chem. Soc. 99, 1819, (1911) show by partition measurements the probable presence of a carboxyl group. The purity of the preparations used in making the following measurements is rather doubtful under the cir- cumstances. It is probable that tannins from various sources will be found to contain isomeric or homologous tannic acids, instead of all containing one acid. . kAXlO« at 25°= 1. ^(32) = 2, (128) = 3, (00) = 350; 1825. At 18°, xXlO^ of 1% soln. = 8.97; after boiling 12 hours=14.97; Nierenstein, Manning, (Private communication). Also; 1160. In HBr, no cond.; 30. In NH3, qual.; 606. Cond. with iodine; 1160. 284 TABLES [Tan Tannin. See also DigalUc acid and Tannic acid. This is a mixture. In the literature up to within a few years, the word tannin is used very loosely. In general it means a more or less well purified mixture of acids, chiefly tannic and digallic acids. At 18°, xXlO* of a 1% soln. = l.l, after heating for some time near 60°. Cond. with iodine; 1160. d-Tartaric acid. C4H606=C02H.CHOH.CHOH.C02H. kAXlO^ at 0°=5; 910. At 17°= 10.1 aq.; 164. At 18°= 11 (colorim.); 1562, 1563. At 25°=9.7; m. p. 170°; 200, 692, 1182, 1372, 1824, 1838; - relative value; 1643, 1781, 1866. Second kAXlO^=5.9 (inversion); 1638;=3.4 (part.); 1231;=4.5 (cond.); 1911; - (part.); 1866. Cond. at 0°; 910. At 17°; 170. At 18°; 377, 1122, 1554. At 20°; 1463. At 25°; 372, 691, 692, 1495, 1518, 1554, 1648, 1747. m(32) = 57.9, (1024) = 232, (oo) = 357; 1838. At 37°; 309. At 0°-42°; 179. In HBr and HCl, no cond.; 30. In HON, small cond.; 943. In H2SO4; 223. In NH3, qual.; 606. In pyridine, fair cond.; 934. Cond. with inorg. acids and bases; 170, 691, 1182, 1189, 1495, 1518. With inorg. salts; 378, 1463, 1648, 1554, 1994. With organic compounds; 45, 377, 378, 1223, 1747. Under pres- sure of 1-500 atmospheres; 220. Ba.A; 1735. - 2Ce.3A; 1496. - Co.A; 1734, 1735. - 2La.3A; 1496. - Pb.A; 938. - Mg.A; 1735, 1836. - Mn.A; 1736. - Ni.A; 1734, 1735.- K.A at 25°, m(32) = 95.0, (1024) = 155.6; 1838; 200, 1199. - 2K.A; 164, 170, 495, 588, 1468, 1519, 1734. - KSb.A; 160, 705, 1468. - 2Rb.A; 1492. - Na.A at 25°, m(32)=73, (1024) = 132; 1838; 1648. Rela- tive strength; 1643. - 2Na.A at 25°, m(32) = 82, (1024) = 101; 1838; 179, 377, 378, 449, 1199, 1367. Under pressure of 1-500 atmospheres; 220. - NaNHi.A; 179. - UO2.A; 449. -Complex salts; 692, 938, 1519, 1521, 1648, 1734. d-Tartaric acid diethyl ester. CsHuOe. In NH3, qual.; 606. Tartaric acid mono methyl ester. (Methyltartaric acid). C6H806=C02H.CHOH.CHOH.C02Me. kxXlO^ at 25° = 4.6; diminishes on diln.; m. p. 69°-70''. M(32) = 39.9, (1024) = 163, (°o) = 350; 1838. 1-Tartaric acid. C4H606=C02H.CHOH.CHOH.C02H. kAXlO^ at 25°=9.7; m. p. 170°; 200, 1372, 1824, 1838. Second kAXlO«=4.2 (cond.); 1911. Tel] TABLES 285 Cond.; 309. At 25°, /i(32) = 57.9, (1024) = 232, (oo) = 357; 1838. K.A at 25°, Ai(32) = 95.2, (1024) = 155.4; 1838; 200. inacf.-Tartaric acid, (meso- or anii-Tartaric acid). C4H6O6. kAXlO^ at 17°=5..82 aq.; 164. At 25°=6.0; m. p. 140°-143°; 200, 1824, 1838. Cond.; 170, 309. At 25°, ai(32)=46, (1024) = 190.4, (oo) = 357; 1838. Cond. with KOH; 170. K.A at 25°, /.i(32) = 89.3, (1024) = 128.2; 1838; 200. ^ara-Tartaric acid. (Racemic acid). C4H6O6. kAXlO* at 0°=9.1. At 12°=9.9; 1968a. At 17°=10.1 aq.; 164. At 25°=9.7; m. p. 205°-206°; 200, 1372, 1824, 1838; = 10.8; 1968a. At 35° = 11.2; 1968a. Second kiX 10^=4.0 (cond.); 1911. Cond.; 170, 309, 692. At 0°-35°; 911, 1968a. At 0°-42°; 179. At 25°, /i(32) = 57.9, (1024) = 231.9, (oo) = 357; 1838. In HBr and HCl, no cond.; 30. Cond. with KOH; 170. With Na^WOs; 692. K.A at 25°, /i(32) = 95.2, (1024) = 155.0; 1838; 200. - 2K.A; 164. - Na.A at 25°, /.i(32) = 73, (1024) = 132; 1838.- 2Na.A at 25°, ju(32) = 82, (1024) = 101; 1838; 179.- NaNH^.A; 179. Complex salt; 692. Tartronic acid. (Hydroxy-malonic acid). C3H405=C02H.CHOH.C02H. kiXlO' at 25°=5; m. p. 158°-159°; 1629; = 1.07; 1372. [There is no way of determining why these values are so far apart. It is probable that this acid is stronger than malonic acid, kx 10^=1.6.] At 25°, ju(44.3) = 132, (88.6) = 167.5, (oo)=358; 1629. m(32) = 60.2, (1024) = 234.2, (oo) = 357; 1372. Cond. increased by boric acid; 1186. Co.A.- Mg.A at 25°, m(32) = 51.5, (1024) = 123.0. - Ni.A; 1735. - 2K.A; 495. Taurine. (Aminoisethionic acid). C2H703NS=NH2.CH2.CH2.S03H. kAXlO^ at 25°=1.6 (hydro!.). ka at 25° is between that of aspartic acid and of hippuric acid. Na.A at 25°, A(64) = 72.9, (1024) = 80.4; M(64) = 76.2, (1024) = 87.5. - B.HCl at 25°, A(64) = 373, (1024) = 386; 1984. Tears. [The references to this subject are incomplete.] Concentration of H and OH ions; 587. Tellurium see Triethyl tellurium chloride, Trimethyl tellurium chloride and the following compound. Tellurium complex oxalate; 1530a. 286 TABLES [Ter Teraconic acid. C7Hio04=C02H.CH2.C(:CMe2)C02H. kAXlO^ at 25°= 1.40 aq.; increases, then diminishes on diln.; m. p. 161°-163°. Second IjaX 10'= 4.6 (inversion). At 25°, m(49.6)=28.2, (794.2) = 97.8, (co) = 352; 1638. Terebic acid. (Diaterebic acid anhydride). C7H10O4. IsaXIO^ at 25°=2.65; diminishes on diln. m(32) = 31, (1024) = 138.8, (co)=352; 1372. Terephthalic acid see p-Phthalic acid. Terpylonic acid. CgHuOe. kiXlO^ at 25°= 1.05; m. p. 135°. iu(32) = 19.9, (1024) = 97, (oo) = 352; 1597. Tetraaspartic acid. C16H22O13N4. 4K.A. - 4Na.A at 28°, m(32) = 65.9, (1024) = 76.8. Cond. with NaOH and NaCl; 1227. Tetrabenzyl phosphonium hydroxide. C28H290P. B.Cl=(PhCH2)4P.Cl, at 25°, A(512) = 88.1, (1024) = 89.6; 270. Tetrabromo-fluorescein. (Eosin. Tetrabromo-fluoresceinic acid anhydride). C2oH806Br4. [The 2K and 2Na salts are also called Eosin. ] Effect of light on cond.; 325, 833, 1321, 1476. Effect of Rontgen rays on cond.; - 1476. 2Na salt, effect of light on cond.; 1471a. Tetrabromo fluoresceinic acid anhydride see Tetrabromo-fluorescein. Tetrabromo-phenolphthalein. C2oHio04Br4. Cond. with NaOH; 1250, 1251. Tetracarboxylic acid see Butanetetracarboxylic acid. Tetrachloro-diketo-pentamethylene-hydroxy-carboxylic acid. C6H2O5CIJ. [At 25°?] A(23.3) = 388.4; m. p. 217°; 729; 728. Tetrachloro-ethane. (Acetylene tetrachloride). C2ll2Cl4= CHCI2.CI1CI2. With perchloric acid, no cond.; b. p. 144° @ 720 mm. As sol- vent; 840. Tetrachlpro-gallein. C2oH807C]4; formerly given as C20H6O7CI4. In MeNH2, poor cond. ; 637. Tetrachloro-methane. (Carbon tetrachloride). CCI4. ;iXl08 at 25° is less than 2; b. p. 75.2°-75.7° @ 740.4 mm.; 1388; 386, 715, 872. Cond. with carbon disulphide and hexane; 386. Effect of radium on cond.; 872. With inorg. and organic compounds; 1388. As solvent; (293), 1388. Tetrachloro-quinone see Chloroanil. Tet] TABLES 287 Tetraethyl ammonium hydroxide. C8H21ON = Et4N.0H. [At 25°] A(32) = 79.6, (1024) = 182.6; aq. used for soln. was not pure; 1363. In Me ale; 335. Relative strength; 409. B.Br(=NEt4Br). In PBra, no cond.; 1833. In acetonitrile; 1844. In Me ale; 335.- B.Cl(=NEt4Cl) at 25°, A(32) = 88.2, (1024) = 99.5; 270. In epichlorohydrin; 1844. In Me ale; 335.- B.I(=NEt4l) at 0°, A(32)=47.7, (1024) = 54.8; 1826. At 25°, A(32) = 86.8, (1024) = 104.0; 335; 923, 1423a, 2029. In inorg. solvents; - in bases; 1828; - in bromides, chlorides and oxy chlorides; 1833, 1834; - in esters; 1834, 1844, 1847; - in oxides, as SO2; 1826, 1833, 1855. In organic solvents; - in acids; 1844; - in acid chlorides, etc.; 1844; - in alcohols; 335, 923, 1423a, 1590a, 1844, 1848, 1849, 1853a, 2029; - in aldehydes; 1590a, 1844, 1847, 1849, 1853a; - in amides; 1844; - in anhydrides; 1590a, 1844; - in bases; 1844; - in esters; 1834, 1844, 1847, 1863a; - in hydrocarbons and nitrohydrocarbons; 923, 1423a, 1590a, 1844, 1848, 1853a; - in ketones; 336, 1423a, 1590a, 1844, 1847; - in nitriles; 1423a, 1590a, 1844, 1847, 1848, 1849, 1863a; - in oximes; 1844; - in thiocarbimides, thiocya- nates, mercaptans, etc.; 1844, 1846, 1847, 1849, 1863a. - Under pressure, in organic solvents; 1690a. Tetraethyl arsonitmi hydroxide. CgHziOAs. B.Cl(=Et4As.Cl) at 25°, A(32) = 85.5, (1024) = 97.5; 270. Tetraethyl-diamino-triphenyl carbinol see Brilliant Green. Tetraethyl-dichloro-quinone diamalonate see Dichloroqtiinone-dima- lonic acid. Tetraethyl phosphonium hydroxide. CgHziOP. B.Cl(=Et4P.Cl) at 25°, A(32) = 86.2, (1024)=98.3; 270. Tetraethyl stibonium hydroxide. C8H2iOSb. B.Cl(=Et4Sb.Cl) at 25°, A(32) = 83.3, (1024) = 95.1; 270. Tetraethyl-succinic acid. Ci2H2204=C02H.CEt2.CEt2.C02H. kAXlO^ at 25° is about 4; m. p. 149°. /*(889) = 171, (00) = 373. These values are only approximate; 1888. Tetraethyl-succinic acid mono methyl ester. Ci3H2404= C02H.CEt2.CEt2.C02Me. Too insol. in aq. to get good values of k; 1888. Tetrafluoro-diethyl amine. C4H7NF4=(CHF2CH2)2NH. ksXlOi" [at 25°]=1.51 (hydrol.); b. p. 124.4° (cor.) @ 755 mm. [At 25°], m(16) = 0.12. B.HCl [at 25°], a((32) = 108.6, (1024) = 182.9; 1697. 288 TABLES [Tet Tetrafluoro-diethyl phosphoric acid see Phosphoric acid tetrafluoro- diethyl ester. Tetrafluoro-triethyl amine. C6HiiNF4= (CHF2.CH2)2NEt. Base has b. p. 137° @ 754 mm. No good values for cond. can be obtained. B.HCl [at 25°], m(32) = 133.9, (1024) = 302.1; 1698. A'-Tetrahydro-benzoicacid. C7Hio02=C6H9.C02H. a) Liquid phase, b. p. 240°-243°; kAX 105=2.14; diminishes on diln. A(32)=9.2, (1024)=40.7, (co) = 350. b) Solid phase, m. p. 29°; kAXlO^=2.22; diminishes on diln. A(32)=9.4, (1024)=45, (co) = 350; 52. A^-Tetrahydro-benzoic acid. C7H10O2. kAXl05=3.05; diminishes on diln. A(32) = ll, (1024) = 50.5, (00) = 350; b. p. 234°-235°; 52. Ar-a-Tetrahydro-naphthoic acid. CuHi202=CioHii.C02H. kiXlO^ at 25°=4.45; m. p. 85°; 175; 71. A(112.6) = 23.9, (900.8) = 63.4, (co) = 350; 175. (3-Tetrahydro-naphthoic acid. C11H12O2. kAXlO^ at 25°=2.5; m. p. 96°; 70, 71. A(205.8) = 23.9, (823.2) = 47, (00) = 350; 70. f rans- A i-Tetrahydro-o-phthalic acid. C8Hio04=C6H8(C02H)2. kAXlO* [at25°] = 5.9; m. p. 120°; 72. A^-Tetrahydro-o-phthalic acid. CsHioO^. kAXlO^ at 25°=7.59; diminishes on diln.; m. p. 215°; 1638; 72. Second kAX 10'= 3.2 (inversion); 1638. At 25°, Ai(64) = 23.7, (1024) = 84, (cx>)=352; 1638. A'-Tetrahydro-o-phthallc acid. C8H10O4. kAXlO* at 25°= 5.85 aq. ; increases, then diminishes on diln.; from cond. of soln. of the anhydride (m. p. 70°). At25°, Ai(32) = 47.7, (1024) = 195.9, (00)= [377]; 1. A'-Tetrahydro-o-phthalic acid anhydride. CgHgOs. Cond. of soln. in aq., see the acid; 1. cis-A*-Tetrahydro-o-phthalic acid. C8Hio04=C6H8(C02H)2. kAXlO« [at25°] = 6.2; 7. frflns-A*-Tetrahydro-o-phthalic acid. C8H10O4. kAXlO* [at 25°] = 1.18; m. p. 218°; 72;= 1.30; 7. [No measure- ments of cond. are given in either of these articles. ] A'-Tetrahydro-p-phthalic acid. C8H10O4. kAXlO^ at 25°=5.0 aq.; m. p. above 300°. Second kAXl0*=2.8 (inversion). At25°, m(321)=41.9, (1284)=78.8, (oo) = 352; 1638. Tetrahydro-a-thiophenecarboxylic acid. C5H802S=C4H7S.C02H. kAXlO^ at 25°= 1.15; increases on diln. A(35.4) = 22.1, (566.4) = 81, (c°) = 359; 70. Tet] TABLES 289 1,2,5,8-Tetrahydroxy-anthraqumone see Quinalizarine. sjfm.-Tetramethyl-/3-acetoxy-glutaric acid. CiiHi806=MeCO.O.CH(CMe2.C02H)2. IsaXIO' at 25°=5.3; increases, then diminishes on diln.; m. p. 158°-159°. Ai(38.4) = 14.9, (613.8) = 55.7, (co) = 349; 1261. Tetramethyl ammonium hydroxide. C4Hi30N=Me4N.OH. At 25°, A(16) = 205, (64) = 211, (co) = 211; 271. B.Br(=Me4N.Br); 2029. In HBr; 1646. In PBrs, no cond.; 1833. In SO2; 485, 1855. In Me ale; 2029. In epichloro- hydrin; 1844. - B.Cl(=Me4N.Cl) at 25°, A(32) = 99.1, (1024) = 111.4; 270. In HBr; 1646; qual.; 1645. In H2S; 1646. InNH4OH;650. InS02;1855. In epichlorohydrin; 1844. - B.I(=Me4N.I) at 0°, A(32) = 54.8, (1024) = 62.6; 1826. At 25°, A(32) = 103.4, (1024) = 123.8; 822a, 2029. In HBr; 1646. In H2S, fair cond.; 27. In Br, no cond.; 1833. In SO2; 485, 1826, 1855. In NH3, qual.; 606. In acetone; 336. In epichlorohydrin; 1844. In Me ale; 335, 2029. - B. Acetate; 145a. Tetramethyl arsonium hydroxide. C4Hi30As=Me4As.OH. At 25°, A(64) = 202, (256) = 204, (co) = 205; 271. B.Cl(=Me4As.CI) at 25°, A(32) = 93.6, (1024) = 105.5; 270. 2,3,4,5-Tetramethyl-benzoic acid. (Prehnitene-carboxylic acid. Preh- nitic acid. l,2,3,4-Tetramethyl-5-benzoic acid). CiiHi402=Me4.C6H.C02H. [C02H=1; Me=2,3,4,5.] kAXl05at25°=6. A(2048) = 103.4, (00) = 351; 1418. 2,3,4,6-Tetramethyl-benzoic acid. (iso-Durenecarboxylic acid. l,2,3,5-Tetraniethyl-4-benzoic acid) . C11H14O2. [C02H=1; Me=2,3,4,6.] kAXl04at25°=l. A(2048) = 131.5, (oo) = 351; 1418. 2,3,5,6-Tetramethyl-benzoic acid. (Durenecarboxylic acid. 1,2,4,5- Tetramethyl-3-benzoic acid). C11H14O2. [C02H=1; Me=2,3,5,6.] kAXl0*at25°=3. A(1024) = 146.9, (co) = 35l; 1418. Tetramethyl-diamino-benzophenone. Ci7H2oON2= CO(C6H4.NMe2)2. In HBr and HI, poor cond. In H2S, no cond. ; 1897. aaa 'a '-Tetramethyl-dihydro-muconic acid. CioHi604=C02H.CMe2.CH:CH.CMe2.C02H. kAXlQS at 25°, for acid, m. p. 68°,= 1.8. m(46) = 9.9, (184) = 19.5, (00) = 350. 290 TABLES [Tet kAXlO^ at 25°, for acid, m. p. 61°, = 1.83. ju(40) = 9.3, (160) = 18.5, (oo) = 350; 229. Tetramethylene-carboxylic acid. (Cyclobutane-carboxylic acid. Tri- methylene-acetic acid). CsHsOj. kAXlO^ at 25°= 1.82; b. p. 192°-197°; 1414, 1859, 2026. At 25°, m(29) = 8.1, (928)=43.3, (oo) = 356; 1859. Tetramethylene diamine. C4Hi2N2=NH2.(CH2)4.NH2. ksXlO* at 25°=5.4 aq.; about 16% too high; 271. Cond.; 1354. At 25°, A(32) = 24.6, (256) = 59, (oo) = 200; 271. B.2HClat25°, A(32) = 108.8, (1024) = 129.9; 270. Tetramethylene-l,l-dicarboxylic acid. C6H8O4. kxXlO^ at 25°=8.33; 1414, 1859; = 8.0; diminishes on diln.; m. p. 158°; 1638, 1666. Second kAXlO'=3.0 (inversion); 1638. At25°, m(33) = 53.8, (1056) = 215.2, (00) = 353; 1859. cis-Tetramethylene-l,2-dicarboxylic acid. (Ethylenesuccinic acid). C6H804= CO2H.C4H6.CO2H. kiXlO* [at25°] = 6.6; m. p. 138°; 1410. ) = 353 ; 54. A(33) = 207.2, (528) = 320.8, ( CO) = 355; 1134. o-Toluenesulphone-aminoacetic acid. (o-ToluenesulphoneglycocoUic acid). C9Hii04NS=Me.C6H4.S02.NH.CH2.C02H. kAXlO* [at 25°] = 2.82. A(67.4)=44.4, (1077.6) = 146.6, (co) = 349; 1134. p-Toluenesulphone-aminoacetic acid. (p-ToluenesulphoneglycocoUic acid). C9H11O4NS. kAXlO^ [at 25°] = 3.47. A(81.7) = 53.9, (653.6) = 132.6, (co) = 349; 1134. p-Toluene sulphonic acid. €7118038= Me.C6H4.SO3H. kAXlO at 25°=2?; 423, 1940. Tol] TABLES 297 A(64.4) = 366, (a)) = 380; 1940. A(32) = 336.6, (64) = 344.6, (») = 350; 423. In H2SO4; 157. K.A. - Ag.A; 1940.- Na.A at 25°, A(32) = 61.4, (1024) = 72.7; 423; 1940. a-Toluic acid see Phenylacetic acid. o-Toluic acid. CsH802=Me.C6H4.C02H. kx X 10^ at 0°= 1.59; 1968a; = 1.45 aq.; 515. At 12°= 1.49; 1968a. At 18°= 1.3 (colorim.); 1563. At 20°= 1.29 aq.; 515. At 25°= 1.25; 515, 1371, 1418; = 1.37; 1968a, 1581. At 30° = 1.20 aq.; 515. At 35°=1.25; 1968a; = 1.17 aq.; 515. At 40°=1.11 aq.; 515, 1581. At 45°=1.06 aq.; 515. At 50°= 1.01 aq.; 515, 1581. At 60°= 0.96 aq. At 70°=0.86 aq. At 80°=0.77 aq. At 90°=0.67 aq. At 99°=0.59 aq.; 1581. Cond. at 0°-35°; 1968a. At 0°-50°; 515. At 25°-99°; 1581. At 25°, A(128) = 41.3, (1024) = 103.4, (oo) = 356; 1371. A(1024) = 106.7, (oo)=349; 1968a. In HBr; 30. In HCl, good cond.; 30. In NH3, qual.; 606. In N2O4, no cond. ; 602. Na.A at 25°, A(32) = 66.5, (1024) = 76.5; 1368a. At 0°-35°; 1968a. At 0°-50°; 515. At 25°-99°; 1581. m-Toluic acid. C8H8O2=Me.C6H4.C02H. kAXl0=at0°=5.15. At 12°=5.48; 1968a. At 18°= 5.9 (colorim.) 1563. At 25°=5.2; 1371, 1418; = 5.60; 1968a; =5.8 aq.; 1581. At 35°=5.54; 1968a. At 40°=5.8 aq. At 50°=5.5 aq. At 60°=5.3 aq. At 70°=5.0 aq. At 80°=4.7 aq. At 90°=4.4 aq. At 99°=4.0 aq.; 1581. Cond. at 0°-35°; 1968a. At 25°-99°; 1581. At 25°, A(128) = 27.4, (1024) = 72.5, (00) = 356; 1371. A(1024) = 74.2, (00) = 349; 1968a. In HBr and HCl; 30. In NH3, qual.; 606. Na.A at 25°, A(32) = 66.6, (1024) = 76.6; 1368a. At 0°-35°; 1968a. At25°-99°; 1581. /seu(fo-m-Toluic acid. (Aaf-Heptadi-inene-5-carboxylic acid). C8H802=(CHI C.CH2)2CH.C02H. kAXl0*=1.3; m. p. 47°; 1413. p-ToIuicacid. C8H802=Me.C6H4.C02H. kAXlO^ at 0°=3.8. At 12°=4.1; 1968a. At 18° = 5.4 (colorim.); 1563, 1781. At 25°=4.5. The values given vary consider- ably, ranging from 5.2; 1371, to 3.8; 1418. In all cases k diminishes on diln. k=4.3; 1968a; = 4.6; 1429, 1581. At 35°=4.4; 1968a. At 40°=4.6 aq. At 50°=4.5 aq. At 60°= 4.3 aq. At 70°=4.1 aq. At 80°=3.9 aq. At 90°=3.6 aq. At 99°= 3.3 aq.; 1581. 298 TABLES [Tol Cond. at 0°-35°; 1968a. At 25°-99°; 1581. At 25°, A(256) = 38.7, (1024) = 72.6, (oo) = 356; 1371. A(1024) = 66.1, (o°) = 349; 1968a. InHBr;30. In HCl, good cond. ; 30. In H2SO4; 157a. In NH3, qual.; 606. Na.A at 25°, A(32) = 66.2, (1024) = 76.6; 1368a. At 0°-35°; 1968a. At 25°-99°; 1581. o-Toluidine. C7H9N=Me.C6H4.NH2. «Xl06at25°=1.7; 1569. kEXlO"" at 12°=1.34 (colorim.); 1775. At 18°=3.0 (hydrol.); 436, 435. At 25°=3.5 (hydrol.); 435;=3.2 (hydro!.); 271; = 0.7 (part.); 548. 'At 60°= 10.9 (inversion); 1880 and 1150. In benzene, alone and with picric acid, no cond.; 1802. In NH3, qual.; 606. Cond. with HCl; 1553. With acetic acid; 1011. With organic compounds; 1223, 1569. As solvent; 1569. B.HCl at 25°, A(64) = 93.9, (256) = 97.4; 270; A(32) = 89.7; M(32) = 98.5; 271.-435, 1601, 1864. - B.H2SO4; 1864. - Organic salts, in benzene, no cond. ; 1801, 1802. m-Toluidine. C7H9N. keXlOi" at 13°=3.5. At 14°=3.9 (colorim.); 1777. At 25°= 5.5 (part.); 584;=6 (hydrol.); 271; = 2.9 (part.); 548. In benzene, alone and with picric acid, no cond. ; 1802. B.HCl at 25°, A(64) = 92.8, (256) = 97.3; 270; A(32) = 89.0; M(32) = 95.7; 271; 1864.- B.H2SO4; 1864. p-Toluidine. C7H9N. kBXlO' at 15°=0.45 (colorim.); 1777. At 18°=1.6 (hydrol.); 436; 435. At 25°=2.1 (solub.); 1116; = 2.2 (hydrol.); 436, 435; = 1.6 (hydrol.); 271; (part.) 584; = 1.1 (part.); 548. At 60°=3.6 (inversion); 1880 and 1150. In HBr, HI and H2S, no cond.; 1897. In HCN, no cond.; 943. In NH3, qual. ; 606. In benzene, alone and with picric acid, no cond.; 1802. B.HCl at 25°, A(64) = 93.0, (256) = 97.4; 270; A(32) = 89.2; M(32) = 93.6; 271; - 435, 1601, 1864, 1882. - B.H2SO4; 1864. - Organic salts, in benzene, no cond. ; 1801, 1802. 2-Toluidine-3,5-disulphomc acid. C7H906NS2=Me.C6H2(NH2)(S03H)2. [Me=l; NH2=2; S03H=3,5.] At 25°, m(64) = 332.0, (1024) = 363.4, (oo) = 355; 492. 3-Toluidine-2,4-disulphonic acid. C7H9O6NS2. [Me=l; NH2=3; S03H=2,4.] At 25°, M(32)=44.2, (1024)=253.6, (c»)=355; 492. Tol] TABLES 299 2-Toluidme-4-sulphonic acid. C7H903NS=Me.C6H3(NH2)(S03H). [Me=l; NH2=2; S03H=4.] kAXlO*at25° = 2.4; 1372; = 2.5; 492. A(32)=30.4, (512) = 106.1, (co) = 355; 492. A(1024) = 137.5, ( 00) = 355; 1372. 2-Toluidme-5-sulphonic acid. C7H9O3NS. [Me=l; NH2=2; S03H=5. S03H=3 in 492 and 1372.] kA XlO* at 25°=7.5; 492, 1372. A(32) = 51, (512) = 162.5, (co)=355; 492. 3-Toluidine-2-sulphomc acid. C7H9O3NS. [Me=l; NH2=3; S03H=2.] kAXlO* at 25°=3.57; diminishes on diln.; 492, 1372. A(128)=68.2, (1024) = 158.7, (oo) = 355; 492. 4-Toluidine-2-sulphomc acid. C7H9O3NS. [Me=l; NH2=4; S03H=2.] kAXlO^at 25°=4.08. A(32) = 12.6, (512)=47.7, (oo) = 355; 492. 4-Toluidine-3-sulphonic acid. C7H9O3NS. [Me=l; NH2=4; S03H=3.] kAXlO*at 25°=8.5. A(32) = 53.9, (1024) = 210.9, (00) = 355; 492. 4-Toluidine-?-sixlplionic acid. C7H9O3NS. [Me=l; NH2=4; S03H=?.] kAXlO* at 25° = 7.95; diminishes on diln.; 1372. [Given in 1372, as of doubtful structure. Note that k approaches in value k of 4-Toluidine-3-sulphonic acid.] A(64)=71.4, (1024) = 203.9, (cx>) = 354; 1372. Toluidino-acetic acid see Tolylamino-acetic acid. 0-0-Toluidinobutyric acid. CiiHi502N = Me.C6H4.NH.CHEt.C02H. kAXlO* at 25°=5.3; increases on diln.; m. p. 84°. A(200) = 33.5, (800) = 66.1, (00) = 349; 1840. a-o-Toluidino-fso-butyric acid. CiiHi602N=C7H7NH.CMe2.C02H. kAXlOS at 25°=4.9; m. p. 62°. A(200) = 10.6, (800) = 21.2, (oo) = 349; 1840. /3-o-Toluidino-iso-butyric acid. CiiHi502N=C7H7NH.(CH2)3.C02H. kA XlO* at 25°=4.0; increases on diln.; m. p. 112°. A(200) = 9.4, (800) = 19.7, (oo) = 349; 1840. a-p-Toluidinobutyric acid. C11H15O2N. kAXlO^ at 25°= 1.04; increases on diln.; m. p. 153°-156°. A(287) = 18.5, (1148) = 36.2, (oo) = 349; 1840. a-p-Toluidino-iso-butyric acid. C11H16O2N. kAXlO« at 25°=6.8; m. p. 150°. A(200) = 12.7, (800) = 24.6, (oo) = 349; 1840. 300 TABLES [Tol |3-p-Toluidino-iso-butyric acid. C11H15O2N. kAXlO^ at 25°=4.1; m. p. 195°-196°. A(200) = 3.1, (800) = 6.5, (00) = 349; 1840. Toluidino-oxalic acid see Tolyloxamic acid. a-o-Toluidinopropionic acid. CioHi302N=C7H7NH.CHMe.C02H. kAXlO^ at 25°=3.9; increases on diln.; m. p. 115°. A(207) = 28.8, (828) = 59, (°=) = 358; 1840. a-p-Toluidinopropionic acid. C10H13O2N. kAXlO«at25° = 6.9; m. p. 158°. A(467) = 19.1, (934) = 27, (00) = 350; 1840. /3-p-Toluidinopropionic acid. CioHi302N=C7H7NH.CH2.CH2.C02H. kAXlO« at 25°=2.2; m. p. 86°. A(200) = 7.8, (800) = 14, (co) = 350; 1840. Toluidinosuccinic acid see Tolylsuccinamic acid. p-Tolunitrile. (Cyanotoluene). C8H7N=Me.C6H4.CN. %Xl0«at25°=5.4; 1569. In NH3, qual.; 606. Cond. with Cu oleate; and as solvent; 1569. p-Tolu quinoline. (6-Methyl quinoline). CioH9N=Me.C9H6N. kBXl0'at25°=l (hydrol.). B.HN03at25°, m(32) = 82.5, (256) = 88.5; M(32) = 88.4; 1293. Toluquinone-o-oxime see Nitroso-cresol. o-Toluric acid. (o-Toluyl glycine). CioHii03N=MeC6H4.CO.NH.CH2.C02H. kAXl0^at25°=1.93. A(256) = 69.8, (1024) = 124.8, (co) = 350; 601. m-Toluric acid. C10H11O3N. kAXl0^at25°=2.1. A(253) = 72.1, (1012) = 128.5, (00) = 350; 601. p-Toluric acid. C10H11O3N. kAXl0^at25°=2.0. A(275.4) = 73.2, (1101.6) = 130, (a.) = 350; 601. 2, 4-Toluylene diamine. C7HioN2=Me.C6H3(NH2)2. [Me=l.] kfl at 15° is probably of the order 10"^. Second kBXl0"=3.2 (colorim.); 1777. 2,5-Toluylene diamine. C7H10N2. kfl at 15° is probably of the order 10"^. Second kBXlO'2= 1.45 (colorim.); 1777. 3,4-Toluylene diamine. C7H10N2. ku at 15° is probably of the order 10"'. Second kBXl0i2=l. 16 (colorim.); 1777. 2,4-Toluylene-diamine-5-suIphonic acid. C7Hio03N2S = Me.C6H2(NH2)2.S03H. [Me=l; NH2=2,4; S03H=5.] Tol] TABLES 301 kAXl0^at25°=2.2. A(256) = 74.1, (1024) = 131.2, (co) = 353; 492. 2.6-Toluylene-diamine-4-sulphonic acid. (Diamino-p-sulphotoluic acid). C7H10O3N2S. [Me=l; NH2=2,6; S03H=4.] kAXlO^ at 25° =4.7; increases on diln. A(60.4) = 17.7, (965.6) = 67.3, (co) = 353; 1372. Toluyl glycine see Toluric acid. o-Tolylamino-acetic acid. (o-Toluidino-acetic acid. o-Tolyl gly- cine). C9Hii02N= MeC6H4.NH.CH2.CO2H. kiXlO' at 25°=5.9; increases on diln.; m. p. 148°-149°; 196, 1840. A(200) = 34.7, (800) = 68.7, (oo)=353; 1840. p-Tolylamino-acetic acid. (p-Tolyl glycine). C9H11O2N. kAXlO^ at 25°=1.7; increases on diln.; m. p. 112°-114°; 196, 1840. A(200) = 17.7, (800) =39.2, (oo) = 353; 1840. Tolylene see Toluylene. Tolyl glycine see Tolylamino-acetic acid. l-p-Tolyl-5-liydroxy-l,2,3-triazole-4-carboxylic acid ethyl ester. C12H13O3N3. Enol ester, kAXlO^ at 25°=1; m. p. 98°-99° heated slowly. A(173.5) = 265.7, (694) = 326, (co) = 370. Na.A at 25°, A(32) = 61.5, (1024) = 71.7; 448. o-Tolylimino-diacetic acid. CiiHi304N=Me.C6H4.N(CH2C02H)2. kA XlO^ at 25°=2.1; diminishes on dUn.; m. p. 158°-162°. iu(206) = 167, (824) = 243, (00) = 351; 1840. p-Tolylimino-diacetic acid. C11H13O4N. kAXlC at 25°= 1.5 (extrapolated); diminishes on diln.; dec. 100°. m(300) = 173.3, (600) = 206, (oo) = 351; 1840. p-Tolyloxamic acid. (p-Oxaltoluidic acid. Toluidino-oxalic acid). C9H903N = C02H.CO.NH(C6H4.Me). kAXlO»at25°=9. A(128) = 223.5, (1024) = 314.8, (co) = 350; 1371. o-Tolylsuccinamic acid. (o-Succintoluidic acid. o-Toluidinosuccinic acid). CiiHi303N=C02H.C2H4.CO.NH(C7H7). kAXl05at25°=2.1. A(64) = 12.3, (1024)=47.3, (oo) = 350; 1372. p-Tolylsuccinamic acid. C11H13O3N. kAXl05at25°=1.93. A(256) = 23.7, (1024)=45.9, (oo) = 350; 1372. Na.A at 25°, A(32) = 59.8, (1024) = 69.9; 1367. Tolyl sulphonic acid see Benzyl sulphonic acid. 302 TABLES [Ton Tongue. [The references to this are incomplete. ] Cond.; 623, 253. Triacetin see Acetic acid glyceryl ester. p-Triamino-triphenyl-acetonitrile see Hydrocyan-p-rosaniline. p-Triamino-triphenyl carbinol. (p-Rosaniline leucohydrate). Ci9Hi90N3= (C6H4NH2)3.C.OH. The salt-forming base changes to a pseudo-base; at 0°, A(512) = 85.5 after 1 minute, = 1.7 after 222 minutes. At 25°, A(512) is about 135 after 1 minute, is about 0.1 after 180 minutes; 770. In MeNH2, small cond.; 637. In ale; 75. B.Cl at 25°, A(128) = 84.2, (1024) = 93.3; 1266; 741, 770, 1265. - B.3HC1; 734, 1266. - B.I. - 2B.SO4; 1731. - B.CN; 770, 1266. Tri-p-aminotriphenyl-methane . (p-Leucaniline) . Ci9Hi9N3=(C6H4NH2)3.CH. B.3HC1 at 25°, m(128) = 343.9, (1024)=465.3; 1266, 770. Tri-fso-amyl amine. Ci6H33N=N(C6Hii)3. B.HI in SO2; 1855. Tri-o-anisyl carbinol. C22H22O4. Comparative strength (colorim.); m. p. 181°; 74. OjOjp-Trianisyl carbinol. C22H22O4. Comparative strength (colorim.); m. p. 109°-110°; 74. Tri-m-anisyl carbinol. C22H22O4. Comparative strength (colorim.); m. p. 119.5°; 74. Tri-p-anisyl carbinol. C22H22O4. Comparativvi strength (colorim.); m. p. 83.5°-84°; 74. B.Perchlorate=C22H2i03.C104; m. p. 195°; in ethylene chloride conducts. Cond. in tetrachloro-ethane; 840. Triazo-acetic acid. C2H302N3=N3.CH2.C02H. kAXlO'* at 25°=9.9 aq.; diminishes on diln.; m. p. about 16°. A(28.7) = 59.5, (287) = 151.6, (od)=390. Na.A, A(oo) = 91; 1422. 1,2,4-Triazole. (1,3,4-Triazole). C2H3N3. ' ksXlOi^ [at 25°] = 2 (sapon.); m. p. 121°; 428. The 1,2,4- and 1,3,4-Triazoles are identical, the position of the N apparently fluctuating from 2- to 3-. a-Triazo-propionic acid. C3H602N3=MeCH(N3).C02H. kA XlO'* at 25°=8.8 aq.; diminishes on diln. A(32.6) = 59.9, (326) = 155.5, (oo) = 386. Na.A, A(oo) = 87; 1422. Tribenzyl amine. C21H21N = (PhCH2)3.N. Too insol. in aq. to measure. From hydrolysis, ks is hardly greater than 4 XlO"'; 664. Tri] TABLES 303 Tribromo-acetic acid. C2H02Br3=CBr3.C02H. At 25.2°, A(32) = 321.4, (oo) = 357.9; 1694. In inorgj solvents; 1833. In organic solvents; 291, 1827, 1834. Cond. with dimethyl-pyrone; 1436, 1827. Na.A at 25°, A(32) = 69.4, (1024) = 80.1; 1694. 4,5,6-Tribromo-aniline-2-sulphomc acid. (Tribromo-aminobenzene sulphonic acid). C6H403NBr3S=Br3C6H(NH2).S03H. [NH2=1; Br=4,5,6; S03H=2.] At 25°, A(194.5) = 343, (a>) = 354; 1372. 2,4,6-Tribroino-amline-3-sulphomc acid. CeHiOsNBrsS. [NH2=1; Br=2,4,6; S03H=3.] At 25°, A(lll) = 340, (oo)=354; 1372. 2,5, 6-Tribromo-aniline-3-stilphomc acid . C6H403NBr3S. [NH2=1; Br=2,5,6; SOsH^S.] At 25°, A(111.5)=338, (co) = 354; 1372. Tribromo-benzene-azophenol see Hydroxy-tribromo-azobenzene. 2,4,6-Tribromo-benzene diazonium hydroxide. (Tribromo-diazo benzene). C6H30N2Br3=Br3.C6H2.N2.0H. ks XlO^ at 0° is less than 1; 501, 737. B.NO3 at 25°, A(32)=is about 80; 425. - B.CN in Et ale, no cond.; 735. 2,4,6-Tribromo-benzene sulphonic acid amide. C6H402NBr3S=Br3.C6H2.S02NH2. Cond. with NaOH; 781. 2,4,6-Tribromo-benzoic acid. C7H302Br3=Br3.C6H2.C02H. kAXlO^ at 25°=3.9. A(128.6) = 324.5, (co) = 379; m. p. 188°- 189°; 1909. Tribromo-diazo benzene see Tribromo-benzene diazonium hydroxide. Tribromo-methane. (Bromoform). CHBr3. xXlO' at 25° is less than 2; b. p. 144°-146.2° @ 740.6 mm.; 1388. InNHs, qual.; 606. Cond. with AgN03 and organic compounds; 1388. Tribromo-triketo-pentamethylene. CsHOsBis. M(30.4) = 324.6, (972.8) =349.6; 729. Tri-iso-butyl amine. C12H27N = (C4H9)3N. kg XlO* at 25°= (2.7 aq.); about 16% too high. A(489) = 57.6, (978) = 74.2, (a=) = 190; the values are only approx- imate; 271. Tributyrin see Butyric acid glyceryl ester. TricarbaUylic acid. (Carballylic acid). C6H806=C02H.CH2.CH(C02H).CH2.C02H. 304 TABLES [Tri kAXlO* at 15.3°=2.2 aq.; 164. At 25°=2.2; m. p. 158°; 237. 1839, 1859, 67. At 25°, ;t(32) = 28.3, (1024) = 139, (co) = 353; 1839. Also; 172, 1495. Cond. with KOH; 172. With M0O3; 1495. K salts; 164, 495. Tricarballylic acid a-mono methyl ester. C7Hio06=C02Me.CH2.CH(C02H).CH2.C02H. kAXlO« at 25°=7.5. Ai(30.5) = 16.4, (61) = 23, (co)=[351]; 237. TricarbaUylic acid jS-mono methyl ester. C7Hio06=C02H.CH2.CH(C02Me).CH2.C02H. kAXlO* at 25°=9.25, and 9.45. m(25.6) = 16.8, (102.8) = 32.9, (00)= [351], for k=9.45; 237. Trichloro-acetaldehyde see Chloral. Trichloro-acetic acid. C2H02Cl3=CCl3C02H. K at 60° = 0; 1957. kAXlO at 0° = 3 (hydrol.); = 9 (cond.); 461. At 12.5°=2; 709. At 16° = 2; 1499. At 18°=2-4 (cond.); = 3 (hydro!.); 460; = 2.2 (hydrol.); 1973. At 25°= 12.1 (inversion); 1370. 12.1 is a better value than 4, (calculated) ; 584. Relative value; 693, 1643. Cond. at 0°; 461, 911, 2004. At 10°; 911. At 12.5°; 709. At 16°; 1499. At 18°; 460, 1317. At 25°, A(32) = 323.0, (1024) = 356.0, (00)= [360]; 1370.- 294, 782, 877, 911, 2004. At 35°; 911. At 60°; 1957. In HBr, HCl, HI and H2S, no cond.; 1897. In HBr, no cond.; 1645. In HON; 943. In H2SO4, no cond.; 157, 157a, 750. In N2O4, no cond.; 297, 602. In SO2, no cond.; 1842. In NH3, qual.; 606. In acetone; 336, 1286. In alcohols; 335, 654, 754, 782, 932, 1021, 1263, 1286, (1620), 1820, 1970, 1971, 2029. In EtBr, no cond.; 1435, 1437. In formic acid; 2008. In hydrocarbons; 1223. In pyridine; 754. In silicic acid esters; 1223. In thiocyanic acid esters; 939. In thiocarbimides; 939, 1223. Cond. with KOH; 294. With aniline; 1900. With dimethyl- pyrone in organic solvents; 1435. — [See also cond. in vari- ous solvents in preceding paragraph. ] — Under pressure of 1-500 atmospheres; 220. Puritj'^ as shown by e. m. f. ; 372. Ba.2A, in EtBr, slight cond.; 1437. - Li. A; 1367. - Hg.2A; 1084. - K.A; 294, 1367, 1437, 1439. - Na.A at 25°, A(32) = 69.6, (1024) = 79.2; 1368a, 1367; - 335, 1084, 1437. - UO2.2A; 449. Tri] TABLES 305 Trichloro-acetic acid amide. C2H20NCl3= CCI3.CONH2. Cond. with NaOH; 781. Trichloro-acetic acid ethyl ester. C4H6O2CI3. Eifect of temperature on cond. ; 106. 2,4,6-Trichloro-benzene diazonium hydroxide. (Trichloro-diazo ben- zene). C6H3ON2CI3. B.Cl(=Cl3.C6H2.N2.Cl) at 25°, A(32) = 94.6, (512) = 102.8; 730. aa(3-Trichloro-butyric acid. C4H602Cl3=Me.CHCl.CCl2.C02H. kA XlO at 18°=2; 460, 1317. At 25° is about 1 ±50%; 1370. Cond.; 1317. At 25°, A(32) = 288.5, (1024) = 343.1, (oo) = 352; 1370. In N2O4, no cond.; 602. In Et ale; 656a; 654. Trichloro-diketo-pentamethylene-hydroxy-carboxylic acid. CeHsOsCls. kiXlO^ at 25°=6; m. p. 170°. m(32) = 258, (1024) = 353.4, (00) = 355; 729, 1186. In Et ale, alone and with boric acid; 1185. Cond. with boric acid; 1186. Trichloro-lactic acid. C3H303Cl3=CCl3.CHOH.C02H. kAXlO' at 18°=4.8; 1317. At 25°=4.8; diminishes on diln.; 1370, 1186. Cond.; 943. At 25°, A(32) = 115.1, (1024) = 302.2, (co) = 356; 1370. In HCN; 943. In Et ale, alone and with boric acid; 1185. Cond. with boric acid; 1186. Na.A at 25°, A(32) = 65.2, (1024) =74.4; 1368a. Trichloro-lacto nitrile. (Chloralcyanohydrate). C3H20NCl3=CCl3.CHOH.CN. In NH3, qual. ; 606. Trichloro-methane. (Chloroform). CHCI3. xXlO' at 25° is less than 2; 740, 1388;=4.4; 1830; 305, 386, 1477. In HBr and H2S, no cond.; 1897. In HCN, no cond.; 943. In NH3, qual.; 606. In MeNH2, fair cond.; 637. Cond. with AgN03; 1388. With organic compounds; 386, 1388. As solvent; 740, 1435, (1445), 1830. Trichloro-R-pentene-dihydroxy-carboxylic acid. CeH604Cl3= (OH)2C6H2Cl3.C02H. kA XlO' at 25° = 8.8 aq.; diminishes on diln.; m. p. 177° with dec; 1186, 727. Ai(64) = 183, (512) = 288, (00) = 352. Cond. with boric acid; 1186. 2,4,6-Trichloro-phenol. C6H30Cl3= CI3.C6H2.OH. kAXlO* at 25°=2.6 (hydro!.); 733 and 1150; is less than 100 (cond.); 733; see also 738. 306 TABLES [Tri At 25°, A(256) = 5.4, (1024) = 12.3, (co)=356; 733. InS02;1842. In Et ale. ; 782. In pyridine; 754. Cond. with cinchonine, in acetone, Et and Me ale. ; 1620. Trichloro-tetraketo-liexamethylene-hydrate. CeHsOBCls. kAXl02=1.2; diminishes on diln. m(64) = 317, (1024) = 359, (00 ) =355; m. p. 158°; 729. Trichloro-triketo-pentamethylene. CbHOsCIs. m(31.2)=323, (998.4) = 354; 729. Tricyano-methane see Cyanoform. Triethyl-allyl ammonium chloride. C9H2oNCl=(Et3)(C3H6)N.Cl. At 25°, A(32) = 87.3, (1024) = 98.9; 270. Triethyl-amine. CeHisN = EtsN. kBXl0^atO°=2.2. At 9°=3.8; 776. At 25°=4.4; 776; = 6.4 aq., 16% too high; 271, 664. At 30°=4.6. At 35°=4.6. At 40°=5.1. At 50°=5.0; 776. - See also 1283. Cond.; 979, 1363. At 25°, A(32) = 27.1, (256) = 66.4, (a>) = 200; 271. In Me ale.; 335. Cond. with organic compounds; 979. B.HCl at 25°, A(32) = 88.3, (1024) = 100.2; 270. In HBr; 1646; qual.; 1237. In HCl; 1646. In HI; 32, 1646. In HjS; 33, 1646; qual.; 1237. In SOj; 1855. Triethyl-fso-amyl ammonium hydroxide. C11H27ON. B.Cl, = (Et3)(C6Hu)N.Cl, at 25°, A(32) = 82.2, (1024) = 93.7; 270. Triethyl-iso-butyl ammonium hydroxide. C10H25ON. B.Cl,= (Et3)(C4H9)N.Cl, at 25°, A(32) = 84.8, (1024) = 96.4; 270. Triethyl-iodomethyl- see lodomethyl-triethyl- Triethyl-phenyl ammonium hydroxide. Ci2H2iON=(Et3)(Ph)N.OH. At 25°, A(32) = 184, (1024) = 185; aq. used f.or soln. was not pure; 1363. Quoted in 271. Triethyl phosphine. C6Hi5P=Et3P. Triethyl phosphine dibromide. Et3P.Br2, m(64) = 513.6; 760. Triethyl-phosphine-earbon-disulphide methyl iodide. (Triethyl- phosphonium thiocarboxylic acid anhydride methyl iodide). Et3P.CS2.MeI, m(32) = 93.8; 760. Triethyl phosphine sulphide. C6Hi6SP=Et3PS. B.Mel, at 25°, A(32)=89.7, (512) = 105.7; 760. Triethyl-propyl ammonium chloride. C9H22NCl=(Et3)(Pr)N.Cl. At 25°, A(32) = 85.1, (1024) = 97.0; 270. Triethyl-rosaniline see Hofmann's Violet. Triethyl-sulphine see Triethyl sulphonium. Triethyl sulphonium hydroxide. ^Triethyl sulphine hydroxide). C6Hi60S=Et3S.OH. Tri] TABLES 307 At 25°, A(32) = 201, (1024) = 205; 1363. Quoted in 271. Qual.; 1302. B.Cl(=Et3S.Cl), at 25°, A(32) = 89.7, (1024) = 102.2; 270.- B.I in aq.; 334, 336, 760, 2029. In acetone; 334. In alcohols; 334, 336, 2029. Triethyl tellurium chloride. C6Hi6ClTe=Et3TeCl. At 25°, A(32) = 87.4, (1024) = 100.2; 270. Triglycolamic acid. C6H906N=N(CH2C02H)3. Hg'salt, e. m. f.; 963. Triglycyl-aminoacetic acid ethyl ester. (Aminoacetyl-bisglycyl- aminoacetic acid ethyl ester). C10H18O6N4. On hydrolysis shows a rise in cond. ; 145b. Triglycyl-glycine see Triglycyl-aminoacetic acid. 1,2,4-Trihydroxy-anthraquinone see Purpurin. Trihydroxy-benzaldehyde see Hydroxy-hydroquinone aldehyde. " see Phloroglucinol aldehyde. see Pyrogallol aldehyde. 1,2,3-Trihydroxy-benzene see Pyrogallol. l,2,4:-Trihydroxy-benzene see Hydroxy-hydroquinone. 1,3,5-Trihydroxy-benzene see Phloroglucinol. 2,3,4-Tiihydroxy-benzoic acid see Pyrogallol carboxylic acid. 2,4,6-Trihydroxy-benzoic acid see Phloroglucinol carboxylic acid. 3,4,5-Trihydroxy-benzoic acid see Gallic acid. 3,4,5-Trihydroxy-2-bromobenzoic acid see Bromogallic acid. 3,4,5-Trihydroxy-chlorobenzoic acid see Chlorogallic acid. 3,4,5-Trihydroxy-2,6-dibromo-benzoic acid see Dibromo-gallic acid. 3,4,5-Trihydroxy-2,6-dichloro-benzoic acid see Dichloro-gallic acid. l-Trihydroxy-glutaric acid. C5H807=C02H.(CHOH)3.C02H. kAXl0= at 25°= 1.5; diminishes on diln.; m. p. 127°; 1542. [Since k is twice the value of k of the other stereo isomers, apparently there is some error. Compare the tartaric acids. ] M(52.6) = 82.2, (105.3) = 107.7, (oo) = 352; 1542. Co. A.- Mg.A at 18°, ai(32) = 52.0, (1024) = 124.0. - Ni.A; 1736. rac. -Trihydroxy-glutaric acid. CsHgO?. kA XlO* at 25°=6.9; m. p. 154.5° cor. m(52.5) = 61.4, (105.3) = 82.9, (oo) = 352; 1642. inac<.-Trihydroxy-glutaric acid. CsHsOy. kAXl0^at25°=6.6. m(52.5) = 59.5, (105.3) = 81.6, (oo) = 352; 1542. 2,3,4-Trihydroxy-quinoline. (|37-Dihydroxy-carbostyTiI). C9H7O3N. At 25°, ;u(1250) = 2.03; 1823. Triiodo-methane. (Iodoform). CHI3. In H2S, conducts; 27. In NH3, qua!.; 606. Cond. with allyl thiocarbimide; 1223. 308 TABLES [Tri Trimercury-diacetone hydroxide. C6Hi206Hg3. At 18°, m(256) = 0.018, (512) = 0.022. Cond. with HCl, showing decomposition. B.Picrate at 18°, m(1100) = 0.04; 59. Trimesicacid. C9H606=C6H3(C02H)3. [C02H= 1,3,5.] kA XlO^ at 25°=9?. Increases on diln. Ai(55) = 56.5, (220) = 125.5, (880) = 225, (oo) = 352; 175. Trimethyl-acetic acid. (Pivalic acid). C6Hio02 = Me3C.C02H. kAXlO«=9.8; m. p. 34°-35°. A(32) = 6.2, (1024) = 32.9, (oo) = 354; 1448. Trimethyl-acryUc acid. C6Hio02=Me2C:CMe.C02H. kA X105 at 25°=3.9; m. p. 69.6°-70.5°; 640, 1704. At 25°, A(116.5) = 22.9, (932) = 60.2, (oo) = 353; 1704; Trimethyl-allyl ammonium chloride. C6Hi4NCl=(Me3)(C3H6)N.Cl. At 25°, A(32) = 93.9, (1024) = 105.3; 270. Trimethyl amine. C3H9N = MesN. ks X105 at 0°=2.4; 776. At 25°=5.9; 776;=7.4 aq.; about 16% too high; 271;= 6.5 (neutral.); 299a. Relative strength; 1631. At 35°= 6.8; 776. Cond.; 299a, 759, 1363. At 25°, A(32) = 10.2, (256)=27.5, («) = 214; 271. In NHs, qua!.; 606. Cond. with HCl; 299a. With HCIO; 759. B.HCl at 25°, A(32) = 102.7, (1024) = 114.6; 270. In SO2; 1856. In NH4OH; 650. Trimethyl-aminoacetic acid. (Betaine. Trimethyl-glycocoU). C6Hii02N+H20=OH.NMe3.CH2.C02H. kAXlO" at 25° is about 1 (catal.); 890;=1.33 (hydro!.); 1682. ksXlO's at 25°=8.7 (catal.); 890;=7.6 (hydro!.); 1984, 271;= 6.2 (hydro!.); 350 and 1150; - 1682, 1773< At 25°, A(32) = 1.7, (256) = 1.8; 350. Cond. with NaOH; 1984. B.HBr; 350.- B.HCl at 25°, A(64) = 103, (1024) = 111; M(64) = 273; 271; - 350, 890, 1984. Trimethyl-aminoacetic acid ethyl ester. C7H15O2N +H20=OH.NMe3.CH2.C02Et. kBXl0i''at25°=l.l (catal.); 890. o-Trimethyl-aminobenzoic acid anhydride. (o-Benzbetaine). CioHi302N+H20=OH.NMe3.C6H4.C02H. kA XlO^* at 25° is less than 1 (catal.); m. p. 225°. kBXlO«at25°=2.8. Cond. of 0.06 normal soln. is about three times that of aq.; 414. o-Trimethyl-aminobenzoic acid methyl ester. C11H17O3N = OH.NMes. C6H4. COzMe. Tri] TABLES 309 ks at 25° is very great (catal.) At 1.2°, A(60) = 0.13; 414. [If ks is really large, the cond. ought to be greater than the value given. ] m-Trimethyl-aminobenzoic acid anhydride. (m-Benzbetaine). CioHi302N+H20 = OH.NMe3.C6H4.C02H. kAXlO" at 25° is less than 1 (catal.); m. p. 215°-220°. kaXlO" at 25°= 3.4 (catal.); 414. m-Trimethyl-aminobenzoic acid methyl ester. CiiHi703N=OH.NMe3.C6H4.C02Me. ks at 25° is very great (catal.); 414. ' p-Trimethyl-aminobenzoic acid anhydride. (p-Benzbetaine). CioHi302N+H20=OH.NMe3.C6H4.C02H. kA at 25° is about 10"" (catal.); is between 10"' and 10~* (cond.); m. p. 255°. ksXlOii at 25° = 3.2 (catal.); 890. p-Trimethyl^aminobenzoic acid methyl ester. CiiHi703N=OH.NMe3.C6H4.C02Me. ks at 25° is very great (catal.); 890. o-Trimethyl-aminophenol. C9Hi502N=OH.NMe3.C6H4.0H. At 25°, m(32) = 1.7. B.Cl(=Cl.NMe3.C6H4.0H) at 25°, m(32) = 89.4, (1024) = 99.9; 755. m-Trimethyl-aminophenol. (m-Hydroxy-trimethyl-phenyl ammo- nium hydroxide). C9H16O2N. At 25°, m(32) = 2.2; m. p. 110°-111°. B.Cl at 25°, m(32) = 102.9, (1024) = 114.9; 755. p-Trimethyl-aminophenoI. C9H15O2N. At 25°, /i(32) = 2.6. B.Cl at 25°, Ai(32) = 114.1, (1024) = 121.4; 755. Trim.ethyl-iso-amyl ammonium hydroxide. C8H21ON. B.Cl, = (Me3)(C6Hii)N.Cl, at 25°, A(32)=86.7, (1024) = 98.2; 270. Trimethyl arsine. C3H9AS. Trimethyl arsine dibromide, Me3As.Br2, /i(64) =496.8, (1024) = 559.6; 760. 2,3,4-Trimethyl-benzoic acid. (Hemellitolcarboxylic acid. Preh- nitylic acid. l,2,3-Trimethyl-4-benzoic acid). CioHi202=Me3.C6H2.C02H. [C02H=1; Me=2,3,4.] kAXl05at25°=3.5; m. p. 165°; 275;=3.1; 1418. A(512) = 44.3, (1024) = 61, (oo) = 351; 275. Na.A at 25°, A(32) = 60.6, (1024) = 70.9; 275. 2,4,5-Trimethyl-benzoic acid. (psewdo-Cumene carboxylic acid. Durylic acid. l,2,4-Trimethyl-5-benzoic acid). CioHiaOz. [C02H=1; Me=2,4,5.] kxXlO^ at 25°=9.9; diminishes on diln. A(1024) = 94.8, (00) = 351; 1418. 810 TABLES [Tri 2,4,6-Triinethyl-benzoic acid. (^-iso-Durylic acid. Mesitylene 2- mono carboxylic acid. l,3,5-Trimethyl-4-benzoic acid). C10H12O2. [C02H=1; Me=2,4,6.] kAXlO* at 25°=3.8; increases, then diminishes on diln.; m. p. 150.5°-15r; 275, 1418. A(128) = 69.2, (1024) = 160.2, («>) = 352; 276. Na.A at 25°, A(32) = 61.5, (1024)=72.4; 275. Trimethyl-benzoyl formic acid see Mesityleneglyoxylic acid. Trimethyl-2-bromoetliyl ammonium chloride. C6Hi3NClBr=(Me3)(C2H4Br)N.Cl. At 25°, A(32) = 91.5, (1024) = 104.0; 270. Trimethyl-iso-butyl ammonium chloride. C7Hi8NCl=(Me3)(C4H9)N.Cl. At 25°, A(32) = 89.7, (1024) = 101.2; 270. Trimethyl-carbinamine see tertiary-Butylaimne. Trimethyl-carbinol see ) = 355; 70. Xylenolcarboxylic acid see p-Xyletic acid. p-Xyletic acid. (2-Hydroxy-l,4-xylenecarboxyhc acid). C9Hio03=Me2.C6H2(OH).C02H. [Me=l,4; C02H=3.] kAXlO* at 25°=6 aq. A(600) = 158, (1200) = 196, (oo) = 350. Cond. with boric acid; 1186. m-Xylic acid see 2,4-Dimethyl-benzoic acid. p-Xylic acid see 2,5-Dimethyl-benzoic acid. 322 TABLES [Xyl asym.-m-Xylidine. (4-Amiiio-l,3-xylene). C8HiiN=Me2.C6H3.NH2. [Me=l,3.] ksXlQiOat 15°=6.3 (colorim.); 1777. In NHs, qual.; 606. B.HCl at 25°, A(64) = 89.9, (256) = 94.4; 270. p-XyUdine. (2-Amino-l,4-xylene). CgHuN. [Me=l,4.] ksXlOi" at 20°=9.6 (colorim.); 1777. XyUdine. CsHuN. [No statement as to which was used. The preceding xylidines are the common isomers. ] In HCN, no cond.; 943. In benzene, alone and with picric acid, no cond. ; 1802. Cond. with pjrridine and acetic acid; 1388. l,4,2-Xylidine-6-sulphonic acid. (l,4-Dimethyl-2-amino-benzene-5- sulphonic acid). C8Hu03NS=Me2.C6H2(NH2).S03H. [Me=l,4; NH2=2.] kAXlO*at25°=4.4. A(64) = 55.4, (1024) = 170.1, (oo) = 354; 1372. Xylyl sulphonic acid see p-ToIubenzyl sulphonic acid. Z. Zinc. In complex salts; 1384, 1946. See also the following compound. Zinc cyanic acid. C4H2N4Zn=H2Zn(CN)4. 2K.A at 25°, A(32) = 117.5, (1024) = 132.4; 1832; 1486. Zirconium. In complex salts; 1520, 1648. C29H37N3. A dye-base analogous to the triphenyl-methane bases. B.3HC1, cond. alone and with NaOH to show change to a car- binol; 1668. FOEMULA INDEX. Only the names used in the tables are given here. Synonyms are given in the tables. Some salts are given, but in general they should be looked for under the head of the acid or base from which they are derived. 1 I. GG14 Tetrachloro-methane. c& Carbon disulphide. 1 n. CHN Hydrocyanic acid. CHCI3 Trichloro-methane. CHBrs Tribromo-methane. CHI3 Triiodo-methane. CH2O Formaldehyde. CH2O2 Formic acid. CH2O3 Carbonic acid. CH2N2 Cyanoamide. CH2N4 Tetrazole. CH3N5 Aminotetrazole. CH3I Methyl iodide. CH4O Methyl alcohol. CHsN Methyl amine. CHsNs Guanidine. COgN* Tetranitro-methane. CNI Cyanogen iodide. 1 in. CHON Cyanic acid. Fulminic acid. CHOeNs Trinitro-methane. CHNS Thiocyanic acid. CH2O4N2 Dinitro-methane. CH3ON Formic acid amide. CH3O2N Carbamic acid. 324 FORMULA INDEX CH302N Formhydroxamic acid. Nitromethane. iso-Nitromethane. CH303N Nitric acid methyl ester. CH303N3 Nitro-urea. CHsBrsSn Tin methyl tribromide. CH4ON2 Urea. CH4O2N2 Methylnitroamine. CH4O2N4 Nitroguanidine. CH4O3S Sulphurous acid mono methyl ester. CH4O4S Formaldehyde sulphurous acid. Hydroxy-methane sulphonic acid. Sulphuric acid mono methyl ester. CH4O6S2 Methylene-disulphonic acid. CH4N2S Thiourea. CHeONs Semicarbazide. CHsONs Diazo guanidine. CH6O3AS Methyl arsenic acid. C02NC13 Nitro-trichloro-methane. CBitSzAI See under Aluminum. 1 IV. CHOiNaBr Dinitro-bromomethane. CHaOsNBr Nitrobromomethane. C2H2 2 I. Acetylene. C2N2 Cyanogen. 2 II. C2H2O2 Glyoxal. C2H2O4 Oxalic acid. C2H2N10 Azotetrazole. C2H2CI4 Tetrachloro-ethane. C2H3N AcetonitrUe. C2H3N3 1,2,4-Triazole. C2H4O Acetaldehyde. Meta-acetaldehyde= (C2H40)i. Para-acetaldehyde= (C2H40)x. Ethylene oxide. C2H4O2 Acetic acid. Formic acid methyl ester. C2H4O3 Glycollic acid. FORMULA INDEX 325 C2H404 Glyoxylic acid. C2H4N4 l-Amino-l,3,4-triazoIe. Dicyano-diamide. C2H4C12 Ethylene chloride. Ethylidene chloride. CaHiBrz Ethylene bromide. C2HBCI Ethyl chloride. CaHsBr Ethyl bromide. C2H6I Ethyl iodide. CaHeO Ethyl alcohol. C2H6O2 Ethylene glycol. C2H6S Dimethyl sulphide. Ethyl mercaptan. C2H7N Dimethyl-amine. Ethyl amine. C2H8N2 Ethylene diamine. 2 III. C2HOCI3 Chloral. Chloral hydrate. C2HOBr3 Bromal hydrate. C2HO2CI3 Trichloro-acetic acid. C2H02Br3 Tribromo-acetic acid. C2HN2Ag Silver cyanic acid. C2H20Br2 Bromoacetyl bromide. C2H2O2CI2 Dichloro-acetic acid. C2H202Br2 Dibromo-acetic acid. C2H2O2F2 Difluoro-acetic acid. C2H3ON GlycoUic nitrile. C2H3OCI Acetyl chloride. C2H30Br Acetyl bromide. C2H3O2N3 Triazo-acetic acid. C2H3O2CI Chloroacetic acid. C2H3O2CI3 Chloral hydrate. C2H302Br Bromoacetic acid. C2H302Br3 Bromal hydrate. C2H3O2I lodoacetic acid. C2H3O2F Fluoroacetic acid. C2H3O3N Oxalic acid mono amide. Oximino-acetic acid. C2H3NS Methyl thiocarbimide. Thiocyanic acid methyl ester. C2H4OF2 Difluoro-ethyl alcohol. 326 FORMULA INDEX C2H40S TMoacetic acid. C2H402N2 Hydraziacetic acid. Oxalic acid di-amide. C2H402S Thioglycollic acid. C2H403N2 Ethylnitrolic acid. QH404N2 Dinitro-ethane. Oxaldihydroxamic acid. C2H60N Acetaldoxime. Acetic acid amide. C2H50C1 Glycol chlorohydrin. C2HB02N Acethydroxamic acid. Aminoacetic acid. GlycoUic acid amide. Glycoliminohydrin. Nitroethane. iso-Nitroethane. Nitrous acid ethyl ester. C2HB02N3 Allophanic acid amide. C2H503N Nitric acid ethyl ester. C2H6NF2 Difluoro-ethyl amine. CaHsClHg Mercury ethyl chloride. CaHeONa Methyl urea. 0-Methyl iso-urea. Nitrosodimethyl amine. CzHeOHg Mercury ethyl hydroxide. C2H6O3S Sulphurous acid mono ethyl ester, C2H6O4S Acetaldehyde sulphurous acid. Isethionic acid. Sulphuric acid mono ethyl ester. " " dimethyl ester. CzHeNBr 2-(|8)-Bromoethyl amine. C2H7ON Acetaldehyde ammonia. C2H7O2AS Cacodylic acid. C2H7O4P Phosphoric acid mono ethyl ester. C2H7O6P Phosphoric acid mono glycol ester. C2N2AgK Potassium silver cyanide. 2 IV. C2H02ClBr2 Chloro-dibromo-acetic acid. C2HO2CIF2 Chloro-difluoro-acetic acid. C2HO2CI2F Dichloro-fluoroacetic acid. C2H02Br2F Dibromo-fluoroacetic acid. C2H2ONCIS Trichloro-acetic acid amide. FORMULA INDEX 327 CzHsOClBr Chloroacetyl bromide. C2H4ONCI Acetic acid chloroamide. Chloroacetic acid amide. CzHiONBr Acetic acid bromoamide. C2H4O2N2F2 Difluoro-ethylnitroamine. C2H6OCI2P Ethoxy phosphorus chloride. C2H7O2NS Ethyl sulphonic acid amide. C2H7O3NS Taurine. 2 V. C2H02ClBrF Chlorobromofluoroacetic acid, 3 II. C3H2N2 Malonitrile. C3H4O2 Acryhc acid. C3H4O3 Pyroracemic acid. C3H4O4 Malonic acid. C3H4O6 Tartronic acid. C3H4O6 Mesoxalic acid. C3H4N2 Glyoxaline. Pyrazole. C3H6N Propionitrile. C3H6I Allyl iodide. C3H6O Acetone. Allyl alcohol. Propionic aldehyde. C3H6O2 Acetic acid methyl ester. Acetol. Formic acid ethyl ester. Propionic acid. C3H6O3 Hydracrylic acid. Lactic acid. Methoxy-acetic acid. C3H6O4 0|8-Glyceric acid. C3H6S3 Trithio-formaldehyde. C3H7N Allyl amine. C3H7Br Propyl bromide. C3H7I Propyl iodide. C3H8O Propyl alcohol. iso- Propyl alcohol. C3H8O2 Methylal. Propylene glycol.. C3H8O3 Glycerol. 328 FORMULA INDEX C3H9N norwi.-Propyl amine. iso- Trimethyl amine. C3H9AS Trimethyl arsine. CsHgSb Trimethyl stibine. C3H10N2 Propylene diamine. Trimethylene diamine. 3 III. C3H2O3N2 Cyanonitrosoacetic acid. Parabanic acid. C3H2N3CU Cupricyanic acid. C3H3O2N Cyanoacetic acid. C3H3O3N3 Cyanuric acid. C3H3O3CI3 Trichloro-lactic acid. C3H3O4CI Chloromalonic acid. C3H3NS Thiazole. C3H4ON2 Acetic acid cyanoamide. Cyanoacetic acid amide. C3H4O2N2 Hydantoin. C3H402Br2 aa-Dibromo-propionic acid, aP- " C3H4O4N2 Dioximino-propionic acid. Oxaluric acid. CsHsON Lactic acid nitrile. C3H6OCI Epichlorohydrin. C3H6O2N zso-Nitrosoacetone. C3H6O2N3 a-Triazo-propionic acid. C3HBO2CI Chloro-formic acid ethyl ester. a-Chloropropionic acid. |3- C3H502Br a-Bromopropionic acid. fi- " " C3HBO2I ^-lodopropionic acid. C3H6O3N Nitroacetone. a-Oximino-propionic acid. C3HBO4N Aminomalonic acid. j3-Nitropropionic acid. C3H5O4N3 Nitromalonic acid amide. C3H6NS Ethyl thiocarbimide. Thiocyanic acid ethyl ester. C3H6ON2 Ethylene urea. FORMULA INDEX 329 CsHeOCla Dichloro-hydrin. CaHeOSs Xanthic acid. C3H6O2N2 Malonic acid di-amide. C3H6O3N2 anti-Diazo urethane. C3H6O4N2 Dinitro-propane. Malondihydroxamic acid. Nitrocarbamic acid ethyl ester. C3H7ON Acetoxime. Propionic acid amide. C3H7O2N Aminoacetic acid methyl ester. o-Aminopropionic acid. fi- " " Carbamic acid ethyl ester. Methylamino-acetic acid. Nitropropane. 2-Nitropropane. Propionhydroxamic acid. C3H7O2N3 Guanidineacetic acid. C3H7O2CI Chlorohydrin. C3H7O3N Nitric acid propyl ester. C3H8ON2 Ethyl ISO-urea. C3H8O2N2 2,3-Diamino-propioiiic acid. C3H8O4S Sulphuric acid propyl ester. C3H9O3B Boric acid trimethyl ester. C3H9O6P Phosphoric acid mono glycerol ester. C3H9N2CI /J-Chloro-trimethylene diamine. C3H10OS Trimethyl sulphonium hydroxide. C3HioOTe Trimethyl tellurium hydroxide. C3HioOSn Tin trimethyl hydroxide. C3N3CuNa2 Sodium cupricyanide. 3 IV. C3H2ONCI3 Trichloro-lacto nitrile. C3H2O2N2S Thioparabanic acid. C3H3ONS2 Rhodanin. C3H3O2NS Diketo-tetrahydro-thiazole. Thiocyanoacetic acid. C3H3O2N3S jso-Nitrosothiohydantoin. C3H4ON2S Thiohydantoin. C3H6O2NS2 Dithio-carbamine glycoUic acid. C3H6O3NS CarbaminethioglycoUic acid. Thiocarbamine glycoUic acid. C3H6Br6S2Al See under Aluminum. 330 FORMULA INDEX CsHeOaNaS Ethyl sulphonic acid cyanoamide. C3H7ONS Thiocarbamic acid ethyl ester. C3H10ONCI Trimethyl-hydroxy ammonium chloride. C3H10ONI Trimethyl-hydroxy ammonium iodide. CsHioOBrSb Trimethyl-stibine hydroxy bromide. 4 II. C4HN3 Cyanoform. C4H2O3 Maleic acid anhydride. C4H2O4 Acetylene-dicarboxylic acid. Hydroxy-maleic acid anhydride. C4H4O2 Tetrolic acid. C4H4O3 Succinic acid anhydride. C4H4O4 Fumaric acid. Maleic acid. C4H4O6 Hydroxy-fumaric acid. Hydroxy-maleic acid. Oxalacetic acid is a mixture of the above acids. C4H4O6 Dihydroxy-fumaric acid. Dihydroxy-maleic acid. C4H1N2 Ethylene cyanide. C4H4S Thiophene. C4H6N Pyrrole. C4H6O2 a-Crotonic acid. Methacrylic acid. Succin-dialdehyde. Trimethylene-carboxylic acid. Vinylacetic acid. C4H6O3 Acetic acid anhydride. Acetoacetic acid. EthenylglycoUic acid. C4H6O4 Methylmalonic acid. Oxalic acid dimethyl ester. Succinic acid. iso-Succinic acid. C4H6O5 Diglycollic acid. Malic acid. maci.-MaUc acid. C4H6O6 d-Tartaric acid. 1 t( It moc^ -Tartaric acid. paro-Tartaric acid. FORMULA INDEX 331 QHeOs Dihydroxy-tartaric acid. CANa o-Methyl glyoxaline. N- " N-Methyl pyrazole. 3- " Butyro nitrile. C4H7N C4H7N3 Dimethyl-triazole. C4H7N6 Acetoguanamine. C4H8O iso-Butyl aldehyde. Methylethyl ketone. C4H8O2 Acetic acid ethyl ester. Butyric acid. iso-Butyric acid. Formic acid propyl ester. Propionic acid methyl ester. C4H8O3 Ethoxy-acetic acid. a-Hydroxy-butyric acid. .y, £aq.=9XlO-5. Meas. Barth; see 558. A. Barth see A. Hantzsch. Meas. C. Barth; see 729. 99. (A. BartoU. Gaz. Chim. Ital. 13, 27-34, (1883). Sulla costituzione degli elettroliti.) [Theoretical and general.] 100. A. BartoU. Gaz. Chim. Ital. 14, 516-522, (1884). La conducibilit^ elettrica delle combinazioni del carbonio. [Same as 115 and 126.] 101. A. BartoU. Gaz. Chim. Ital. 14, 522-526, (1884). Di un singolare fenomeno elettrico osservato nell'alcool cetilico solido. [Same as 116. See 110.] 398 AUTHOR LIST 102. A. BartoU. Gaz. Chim. Ital. 15, 392-397, (1885). La conducibiliti elettrica delle oombmazioni del carbonio ed in ispecie suUa conducibilitS, delle ammidi, dei nitroderivati ecc. [Same as 117 and 127]. 103. A. Bartoli. Gaz. Chim. Ital. 15, 397-399, (1885). Sulla dipendenza deUa conducibUit^ elettrica della dietilammina dalla tem- peratura. [Same as 119 and 130. Qualitative.] T=-10°to +80°. 104. A. BartoU. Gaz. Chim. Ital. 15, 400-403, (1885). La conducibilit^ elettrica di alcuni composti organici alio stato solido. [Same as 118 and 129.] 105. A. BartoU. Gaz. Chim. Ital. 15, 410-416, (1885). La conducibUiti elettrica delle mescolanze di combinazioni organiche. [Same as 120 and 128.] T=-40°to 120°. 106. A. BartoU. Gaz. Chim. Ital. 24, II, 156-172, (1894). Sulla dipendenza deUa conducibUit^ elettrica degli eteri composti daUa tem- peratura. [Same as 112 and 126. ] T = 13°to210°. 107. A. BartoU. Gaz. Chim. Ital. 25, I, 205-207, (1895). Sulla conduttivitll elettrica di alcuni composti in prossimitS, della tempera- tura critica. [Same as 113. QuaUtative.] 108. A. BartoU. Atti Accad. Gioenia. (4), 2, 45-80, (1889-1890). Sulla conducibUit^ elettrica di alcuni mescugli naturaU di composti organici ed in particolare suUa conducibilitS, elettrica degli oUi, dei grassi, delle cere, delle essenze, dei balsami e delle resine. [Same as 124.] T=0° toSOO'- lOg. A. BartoU. Bol. Accad. Gioenia. (N. S.), Fasc. 4, 4-8, (1889). Sulla conducibilitS. elettrica, etc. [An abstract of 108. Qualitative.] 110. A. BartoU. Bol. Accad. Gioenia. (N. S.), Fasc. 23-24, 12-13, (1892). Abstracted in Beibl. Ann. Phys. 17, 1085, (1893). Spiegazione delle anomalie che presenta la conducibilitS, elettrica dell'etalio. T = 0°to 104° 111. A. BartoU. Bol. Accad. Gioenia. (N. S.), Fasc. 26-28, 4r-5, (1892). La conducibilitS, elettrica di alcuni liquidi molto viscosi, dopo raffreddamenti rapidi, e dopo lenti raffreddamenti. [Qualitative.] 112. A. BartoU. Rend. R. 1st. Lombardo. (2), 27, 490-503, (1894). Sulla dipendenza deUa conducibiUt^, etc. [Same as 106 and 125.] 113. A. BartoU. Rend. R. 1st. Lombardo. (2), 28, 246-248, (1895). Sulla conduttivit^ elettrica, etc. [Same as 107. ] 114. A. BartoU. Nuovo Cim. (3), 15, 203-210, (1884). Relazione fra la conducibilitEl elettrica e la composizione dei carboni di varie specie. 115. A. BartoU. Nuovo Cim. (3), 16, 64-69, (1884). La conducibilit^ elettrica, etc. [Same as 100 and 126.] 116. A. BartoU. Nuovo Cim. (3), 16, 70-74, (1884). Sopra un singolare fenomeno osservato nel misurare la conducibilitS, elettrica dell'etalio. [Same as 101. See 110.] 117. A. BartoU. Nuovo Cim. (3), 19, 43-48, (1886). La conducibilitS, elettrica delle combinazioni, etc. [Same as 102 and 127.] 118. A. BartoU. Nuovo Cim. (3), 19, 48-52, (1886). La conducibilit^ di alcuni, etc. [Same as 104 and 129.] 119. A. BartoU. Nuovo Cim. (3), 19, 52-54, (1886). Sulla dipendenza della conducibilitS., etc. [Same as 103 and 130.] AUTHOR LIST 399 120. A. BartoU. Nuovo Cim. (3), 19, 55-61, (1886). La conducibilit^ elettrica delle mescolanze, etc. [Same as 106 and 128. ] 121. A. BartoU. Nuovo Cim. (3), 20, 121-125, (1886). Sulla conducibilitd, elettrica delle combinazioni del carbonio alio stato liquido, ed in ispecie su la conduoibilitS, delle combinazioni dei radicali acidi con gli alogeni, dei rodanati, delle essenze di senape, dei nitrili, dei solfuri e delle com- binazioni organometalliche. [Same as 134. Qualitative.] 122. A. BartoU. Nuovo Cim. (3), 20, 125-136, (1886). Sulla dipendenza della conducibilitS, elettrica daUa temperatura nelle soluzioni degli alcoli CnH2n+20 nei Uquidi poco conduttori od isolanti. [Qualitative. Same as 132. ] 123. A. BartoU. Nuovo Cim. (3), 20, 136-139, (1886). La conducibilitS, elettrica al punto critico. [Same as 133. ] 124. A. BartoU. Nuovo Cim. (3), 28, 25-40, (1890). Sulla conducibilitS, elettrica di alcimi mescugli naturali di composti organic! ed in partioolare sulla conducibilitS, elettrica degli olii, dei grassi, delle cere, delle essenze, dei balsame e delle resine. [Same as 108.] T = 0°to300°- 125. A. BartoU. Nuovo Cim. (3), 36, 57-70, (1894). SuUa dipendenza della conducibilita, etc. [Same as 106 and 112.] 126. A. BartoU. Rend. Aecad. Lincei. (3), 8, 334-337, (1883-1884). La conducibilita elettrica, etc. [Same as 100 and 115. ] 127. A. BartoU. Rend. Accad. Lincei. (4), 1, 546-550, (1884-1885). Sulla conducibiUt^ elettrica delle combinazioni, etc. [Same as 102 and 117.] 128. A. BartoU. Rend. Accad. Lincei. (4), 1, 650-555, (1884^1885). La conducibiliti elettrica delle mescolanze, etc. [Same as 105 and 120.] 129. A. BartoU. Rend. Accad. Lincei. (4), 1, 569-572, (1884r-1885). La conducibiUtS, elettrica di alcuni composti, etc. [Same as 104 and 118.] 130. A. BartoU. Rend. Accad. Lincei. (4), 1, 572-573, (1884-1885). Sulla dipendenza della conducibilita, etc. [Same as 103 and 119. Error in the title, dimetil for dietil, is corrected in 103. ] 131. A. BartoU. Rend. Accad. Lincei. (4), 1, 586-590, (1884-1885). La conducibUit^ elettrica delle resine. 132. A. BartoU. Rend. Accad. Lincei. (4), 2, II, 122-129, (1885-1886). Sulla dipendenza deUa conducibilita, etc. [Same as 122. ] 133. A. BartoU. Rend. Accad. Lincei. (4), 2, II, 129-131, (1885-1886). La conducibilitll elettrica al punto critico. [Same as 123.] 134. A. BartoU. Rend. Accad. Lincei. (4), 2, II, 132-135, (1885-1886). SuUa conducibilitS, elettrica, etc. [Same as 121.] 135. (A. BartoU, G. PapasogU. Gaz. Chim. Ital. 13, 35-37, (1883). SuU'elettrolisi dell'acqua e delle soluzioni di acido borico.) [Electrolytic] 136. (A. BartoU, G. PapasogU. Gaz. Chim. Ital. 13, 37-55, (1883). Ricerche suUa elettrolisi con elettrodi di carbone delle soluzioni dei composti binarii e di vari altri composti acidi e salini.) [Electrolytic] 137. (A. BartoU, G. PapasogU. Gaz. Chim. Ital. 13, 281-286, (1883). Elettrolisi deUe soluzioni di ammoniaca e dei saU ammoniacali, con elettrodi di carbone.) .[Electrolytic] 138. (A. BartoU, G. PapasogU. Gaz. Chim. Ital. 13, 287-293, (1883). Elettrolisi della glicerina con elettrodi di carbone e di platino.) [Electrolytic] H. P. Bassett see H. C. Jones. J. P. Batey see E. Knecht. 400 AUTHOR LIST 139. E. Bauer. Zeit. Phys. Chem. 56, 215-222, (1906). Ueber die Dissociationskonstanten schwacher Sauren. T = 25°. Meas. Bauer; see 1349. E. Bauer see P. T, Muller. 140. (H. Bauer. Jour. Prakt. Chem. (2), 72, 201-210, (1905). Beitrag zur Natur der Kohlenstoffdoppelbindung.) [Quoted.] Meas. M. Bauer; see 1720. 141. E. Baur. [Probably same as Bauer]. Ami. Chemie. 296, 95-100, (1897). Ueber die Leitfahigkeit des Nitramids. T = 0°. Xoaq. = 1.99X10-^ 142. A. E. Baur. [Same as E. Baur]. Zeit. Phys. Chem. 18, 183-1 84, (1895). Bestimmung einiger Leitfahigkeiten. [Corrected in 143.] T = 25°. 143. E. Baur. [Thisis A. E. Baur.] Zeit. Phys. Chem. 23, 409-416, (1897). Bestimmung der AflSnitatsgrossen und Dissociationswarmen einiger Stick- stoffsauren. [Given in 145. ] T = 0°to40°. X20 aq. = 2.5Xl0-«; sub. 144. E. Baur.. Zeit. Elektrochem. 11, 936-938, (1905). Ueber die Beziehung zwischen elektrolytischer Dissociation und Dielektri- zitatskonstante. 145. E. Baur. [This is A. E. Baur.] Dis. Munchen. (1897). Bestimmungen von Umwandlungspunkten, Affinitatsgrossen, Dissoziations- warmen, etc., auf elektrischem Wage. [Same as 143, with addition of azotet- razole, acetic acid and nitroamide.] T=0°to40°. xaq. sub. E. Baiur see W. Kerp. 145a. W. M. BayUss. Arch. Fisiol. 7, 357-368, (1909). The dissociation of salts of weak acids with weak bases. T = ll°to40° R. O. 145b. W. M. Bayliss. Jour. Physiol. 36, 221-252, (1907-1908). Researches on the nature of enzyme action. I. On the causes of the rise in electrical conductivity under the action of trypsin. T = 10°to40''. R. O. 146. E. Beckmann, [B. Held.] Arch. Pharm. 247, 110-120, (1909). Beitrage-zur Beurteilung von Drogen. T = 25°. 147. (E. Beckmann, G. Lockemann. Zeit. Phys. Chem. 60, 385-398, (1907). Ueber Molekulargewichts- und Leitfahigkeitsbestimmungen in Nitrobenzol.) [Inorganic] T = 18°. 147a. E. Beckmann, P. Waentig. Zeit. Anorg. Chem. 67, 17-61, (1910). Kryoskopische Bestimmungen bei tiefen Temperaturen (—40° bis —117°). T=-51°to -120°. 148. H. Becquerel. Compt. Rend. 136, 1173-1176, (1903). Conductibilit6 et ionisation r&iduelle de la paraffine solide, sous I'influenoe du rayonnement du radium. 149. R. Behrend. Zeit. Phys. Chem. 11, 466-491, (1893). Elektrometrische Analyse. A. Beisswenger see F. Fichter. 150. I. Bellucci. Gaz. Chim. Ital. 35, I, 343-355, (1905). Sui composti solfocianici del palladio. [Same as 151.] T = 25°. AUTHOR LIST 401 151. I. Bellucci. Rend. Accad. Lincei. (5), 13, II, 38&-393, (1904). Sui composti, etc. [Same as 150.] I. Bellucci see A. Miolati. J. Beuce see A. v. Kordnyi. 152. A. Benediceati. Arch. Fisiol. 1, 403-i09, (1904). Sui mutamenti fisico-chimici del sangue nelle variazioni della pressione san- guigna. T=25°. R. O. 153. A. Benedicenti. Arch. Fisiol. 3, 309-316, (1906). Sui mutamenti fisico-chimici del sangue arterioso e venoso nelle variazioni della pressione sanguigna. 154. L. Benoist, D. Hunnuzescu. Jour. Phys. (3), 5, 110-111, (1896). NouveUes propri^t^s des rayons X. 155. (L. Benoist, D. Hurmuzescu. Jour. Phys. (3), 5, 358-362, (1896). Action des rayons X sur les corps (51ectris^s.) [Inorganic. ] 156. (A. Benrath. Zeit. Phys. Chem. 64, 693-706, (1908). Ueber die elektrische Leitfahigkeit von Salzen und Salzgemischen.) [Inor- ganic] Meas. A. Benrath ; see 440. 156a. R. L. Benson, H. G. WeUs. Jour. Biol. Chem. 8, 61-76, (1910). The study of autolysis by physico-chemical methods. T. Bentivoglio see G. Magnanini. Meas. Benz; see 487. 157. F. Bergius. Zeit. Phys. Chem. 72, 338-361, (1910). Ueber absolute Schwefelsaure als Losungsmittel. [Different from 157a.] T = 25°. R. O. X of solvent sub. 157a. F. C. R. Bergius. Dis. Leipzig. (1907). Ueber absolute Schwefelsaure als Losungsmittel. T = 25°. x: of solvent sub. Meas. F. C. R. Bergius; see 750. 158. Earl of Berkeley, E. G. J. Hartley, J. Stephenson. Trans. R. Soc. London. A. 209, 319-336, (1909). On the osmotic pressures of calcium ferrocyanide solutions. Part II. Weak solutions. T = 0.00° ±0.01°. R. O. ;>ioaq.= 1-2X10-1=. 159. (E. Berl. Ber. Deutsch. Chem. Ges. 37, 325-331, (1904). Beitrage zur Kenntniss der Elektrolyse geschmolzener organischer Salze.) B. Berle see E. Bamberger. Meas. W. Bemays; see 657. 160. G. Bemdt. Ann. Physik. (4), 23, 932-950, (1907). Ueber den Einfluss des Magnetfeldes auf den Widerstand von Elektrolyten. [Summary given in 161, 162 and 163. ] T = 34.2°. 161. G. Bemdt. Jour. Phys. 7, 221-223, (1908). Influence d'un champ magn^tique sur la resistance des ^lectroljrtes. [Given in 160. Same as 162.] 162. G. Bemdt. Phys. Zeit. 8, 778-779, (1907). Ueber den Einfluss des Magnetfeldes auf den Widerstand von Elektrolyten. [Given in 160. Same as 161.] 163. G. Bemdt. Verhand. Deutsch. Phys. Ges. 9, 240-242, (1907). Ueber den Einfluss des Magnetfeldes auf den Widerstand von Elektrolyten. [Given in 160.] Meas. Bersch; see 1374. A. Bertheim see A. Rosenheim. 402 AUTHOR LIST 164. D. Berthelot. Ann. Chim. Phys. (6), 23, 1-115, (1891). Recherches sur les conductibilit6s flectriques des acides organiques et de leurs sels. T = 15.3° to 22°. K aq. not sub. 165. D. Berthelot. Ann. Chim. Phys. (6), 24, 1^5, (1891). Etude sur la neutralisation des acides et des bases par la m^thode des conducti- bilit^s flectriques. T = 14°. 166. D. Berthelot. Compt. Rend. 109, 801-804, (1889). Sur I'emploi des conductibilit^s ^lectriques pour 6tudier les d^placements et partages des acides ei fonction complexe. T = 20°. 167. D. Berthelot. Compt. Rend. 109, 864-867, (1889). Conductibilit6s ^lectriques et affinitSs multiples de I'acide aspartique. T = 12°andl4° 168. D. Berthelot. Compt. Rend. 110, 703-705, (1890). Sur les conductibUitfe des phenols et des acides oxybenzoiques. T = 10°. 169. D. Berthelot. Compt. Rend. 110, 1066-1069, (1890). Sur les conductibiUtSs des combinaisons de I'ammoniaque et I'aniline avec les acides oxybenzoiques. 170. D. Berthelot. Compt. Rend. 112, 46-48, (1891). Sur les oonductibilit& des acides organiques isomfires et de leurs sels. T = 17°. 171. D. Berthelot. Compt. Rend. 112, 287-289, (1891). Sur la basicite des acides organiques, d'apres leur conductibUitS. Acides monobasiques et bibasiques. T = 17°. 172. D. Berthelot. Compt. Rend. 112, 335-337, (1891). Sur la conductibilit6 des acides organiques tribasiques; caract^ristique nou- velle de la basicity. 173. (D. Berthelot. Compt. Rend. 113, 851-854, (1891). Sur les trois basicitfe de I'acide phosphorique.) T = 17°. 174. (M. Berthelot, W. C. Matignon. Compt. Rend. 113, 672-679, (1891). Sur la chaleur de formation de I'hydrazine et de I'acide azothydrique.) P. Berti see G. Bruni. A. Besredka see N. Zelinsky. 175. H. G. Bethmann. Zeit. Phys. Chem. 5, 385-422, (1890). Ueber die Affinitatsgrossen einiger organischen Sauren imd ihre Beziehungen zur Konstitution derselben. T = 25°. Meas. H. G. Bethmann; see 71, 728, 1178. 176. (M. Betti. Gaz. Chim. Ital. 37, II, 5-13, (1907). Costituzione chimica e potere rotatorio. II. SuU'influenza della fimzione chimica dei gruppi sostituenti.) 177. H. H. Beveridge. Proc. R. Soc. Edinburgh. 29, 648-667, (1908-1909). Hydrolysis of salts of amphoteric electrolytes. T = 0°and25°. R. O. x^s aq.=0.8-1.3X10-«. Meas. H. H. Beveridge; see 318. H. H. Beveridge see J. Walker. Bezredka see Besredka. 178. (O. Biach. Zeit. Phys. Chem. 50, 43-64, (1905). Ueber Regelmassigkeiten in homologen Reihen.) [Theoretical and quoted.] AUTHOR LIST 403 179. E. Bichat. Bui. Soc. Nancy. (2), 11, Bui. des Stances. 7°, 16-18, (1891). Sur la resistance 61ectrique des dissolutions d'acide tartrique et des tartrates. T=0°to42°. U = ohm. Meas. S. L. Bigelow; see 1099. 179a. E. BiUmann. Ber. Deutsch. Chem. Ges. 43, 568-580, (1910). Meas. N. Bjerrum. Ueber die isomeren Zimtsauren. T=25°. R. O. xaq.=2X10-«. 180. J. BiUitzer. Monatsh. 20, 666-678, (1899). Ueber die Affinitatsgrossen gesattigter Fettsauren. [Same as 183. ] T=25°. xaq.= 2.4X10-". 181. J. Billitzer. Monatsh. 23, 489-501, (1902). Ueber die saure Natur des Acetylens. [No conductivity. Same as 184. ] 182. J. BiUitzer. Monatsh. 23, 502-511, (1902). Ueber die Fahigkeit des Kohlenstoffes, lonen zu bilden. 183. J. BiUitzer. Sitzber. Akad. Wien. 108, 2 b, 416-428, (1899). Ueber die Affinitatsgrossen, etc. [Same as 180.] 184. J. BUUtzer. Sitzber. Akad. Wien. Ill, 2 b, 221-233, (1902). Ueber die saure Natur des Acetylens. [Same as 181.] 185. (W. BUtz. Zeit. Phys. Chem. 40, 185-221, (1902). Zur Kenntnis der Losiingen anorganischer Salze in Wasser.) 186. W. Biltz, A. V. Vegesack. Zeit. Phys. Chem. 68, 357-382, (1909). Ueber den osmotischen Druck der KoUoide. Erste Mitteilung; Ueber die RoUe der Elektrolyte bei der Dialyse von KoUoiden. T = 25°. xaq.=2X10-^ 186a. W. Biltz, A. v. Vegesack. Zeit. Phys. Chem. 73, 481-512, (1910). Meas. Pfenning. Ueber den osmotischen Druck der KoUoide. Zweite Mitteilung; Der osmo- tische Druck einiger Farbstofflosungen. T = 25°. 187. E. C. Bingham. Dis. Johns Hopkins. (1905). The conductivity and viscosity of solutions of certain salts in mixtures of acetone with methyl alcohol, with ethyl alcohol, and with water. [Same as 904.] E. C. Bingham see H. C. Jones. Meas. A. Binz; see 1899. 188. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 24, 1041-1049, (1891). Ueber Trimethylbemsteinsaure. 189. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 24, 1050-1064, (1891). mMeas. P. Walden. Ueber Aethyl-, Propyl-, und Benzyldimethylbernsteinsaure. 190. C. A. Bischofi. Ber. Deutsch. Chem. Ges. 24, 1064r-1074, (1891). Meas. P- Walden. Weitere Beitrage zur Kenntniss der substituirten Bernsteinsauren. 191. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 24, 2001-2025, (1891). Meas. P. Walden. Weitere Beitrage zur Kenntniss der Fumarsaurereihe. 192. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 33, 924^931, (1900). Meas. Centnerszwer. Phenoxypropionsauren und Derivate. 193. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 33, 931-939, (1900). Meas. Centnerszwer. a-Phenoxy-Buttersaure, -Isobuttersaure und -Isovaleriansaure und deren Ester. 4.04 AUTHOR LIST 194. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 40, 3150-3177, (1907). Studien iiber Verkettungen. Bis-nitrophenoxy-malonsaureester, Bis-nitrophen- oxy-acetylentetracarbonsaureester und unerwartete Isomeriefalle bei ersteren. 195. C. A. Bischoff, A. Hausdorfer. Ber. Deutsch. Chem. Ges. 25, 2280- 2290, (1892). Meas. P. Walden. Ueber Paratolylglyoin und seine Derivate. 196. C. A. Bischoff, E. Hjelt. Ber. Deutsch. Chem. Ges. 21, 2089-2097, (1888). Meas. P. Walden. Ueber symmetrische Diathylbemsteinsauren. 197. C. A. Bischoff, K. Jaunsnicker. Ber. Deutsch. Chem. Ges. 23, 3399- 3409, (1890). Meas. P. Walden. Ueber Pimelinsauren verschiedenen Ursprungs. 198. C. A. Bischoff, N. Mintz. Ber. Deutsch. Chem. Ges. 23, 3410-3413, (1890). Meas. P. Walden. Ueber Aethyldimethylbemsteinsaure. [The measurement of ZeUnsky referred to here, is given in 2018.] 199. (C. A. Bischoff, N. Mintz. Ber. Deutsch. Chem. Ges. 25, 2326-2334, (1892). Ueber Anilidoisobuttersauren.) [Quoted.] 200. C. A. Bischoff, P. "Walden. Ber. Deutsch. Chem. Ges. 22, 1819-1822, (1889). Ueber bisubstituirte Bernsteinsauren. [Probably repubhshed by P. Walden in 1838.] 201. C. A. Bischoff, P. Walden. Ber. Deutsch. Chem. Ges. 23, 1950-1958, (1890). Ueber das Leitvermogen der substituirten Bernsteinsauren und Glutarsauren. Hg. U. 202. C. A. Bischoff, P. Walden. Ber. Deutsch. Chem. Ges. 26, 1452-1460, (1893). Die Anwendung der dynamischen Hypothese auf Ketonsaurederivate. K. Bittner see R. Wegscheider. Meas. N. Bjerrum; see 179a. 203. (P. Blackmail. Chem. News. 93, 284, (1906). Relative strengths of acids.) [Theoretical.] 204. (P. Blackman. Chem. News. 94, 164, (1906). Molecular conductivities; quantitative relation). [Theoretical and quoted.) 205. (P. Blackman. Chem. News. 94, 176, (1906). Ionic conductivities at 26°.) [Theoretical and quoted.] 206. P. Blackman. Jour. Phys. Chem. 13, 144^153, (1909). Tables of molecular conductivities. [Calculated from measurements by him- self and by others. ] T = 18°and25^ 207. P. Blackman. Jour. Phys. Chem. 13, 609-629, (1909). An electrionic theory. [Summary and enlargement of 203 to 206.] 208. (P. Blackman. Phil. Mag. (6), 11, 416-418, (1906). Quantitative relation between molecular conductivities.) [Theoretical and inorganic] 209. (P. Blackman. Phil. Mag. (6), 12, 150-152, (1906). Atomic conductivities of the ions.) [Theoretical. ] ' 210. (P. Blackman. Phil. Mag. (6), 14, 215-216, (1907). Electrical ionic conductivities.) 210a. D. De Blasi. Arch. Fisiol. 7, 501-510, (1909). Sul comportamento delle emazie di cane in miscela isotoniche di cloruro di sodio e saccarosio. AUTHOR LIST 405 211. L. Bleekrode. Ann. Physik. (3), 3, 161-196, (1878). Ueber die Electricitatsleitung und Electrolyse der chemischen Verbindungen. [Same as 212 and 213 together.] 212. L. Blee^ode. Phil. Mag. (5), 5, 375-389, (1878). On the electric conductivity and electrolysis of chemical compounds. [Same as first part of 211. ] 213. L. Bleekrode. Phil. Mag. (5), 5, 439-451, (1878). On the electric conductivity and electrolysis of chemical compounds. [Same as last part of 211.] Blom see Oker-Blom. 214. R. Blume. Dis. Rostock. (1904). Ueber die Einwirkung von Benzylamin und Methylbenzylamin auf das Chjor- methylat des l-Phenyl-3-methyl-5-chlorpyrazols. [Same as 1266.] T = 18°- xaq.= 6.72X10-". Meas. Blume; see 1256. 214a. J. BSeseken. Rec. Trav. Chim. 29, 275-292, (1910). §Meas. H. Convert. Sur les produits de I'action des amines primaires sur les dinitrosacyles (glyox- imeperoxydes). T=25°. A. Bohi see R. Lorenz. 215. C. Bohm-Wendt, E. v. Schweidler. Phys. Zeit. 10, 379-382, (1909). Ueber die spezifische Geschwindigkeit der lonen in flussigen Dielektrikas. 216. W. Bottger. Zeit. Phys. Chem. 46, 521-619, (1903). Loslichkeitsstudien an schwer losUchen Stoffen. T = 19.96°. xaq. =0.92-1.18X10-". 217. W. Bottger. Zeit. Phys. Chem. 56, 83-94, (1906). Loslichkeitsstudien an schwer loshchen Stoffen. II. Die Loslichkeit von Sil- berchlorid, -bromid und -rhodanid bei 100°. T = 100°. R. O. S. Bogdan see P. A. Guye. 218. S. I. Bogdan. Dis. GenSve. (1902). Application des m^thodes physico-chimiques 3. I'analyse des liquides physi- ologiques. [Probably same as 703. ] 219. (A. Bogojawlensky, G. Tammann. Zeit. Phys. Chem. 23, 13-23, (1897). Ueber den Einfluss des Drucks auf die Reaktionsgeschwindigkeit in homogenen flussigen Systemen.) 220. A. Bogojawlensky, G. Tammann. Zeit. Phys. Chem. 27, 457-473, (1898). Ueber den Einfluss des Drucks auf das elektrische Leitvermogen von Losungen. T=0''. Hg. U. X aq. =5.52X10-"; also 2.9 X 10-". 221. (A. Bogorodskij. Jour. Russ. Phys.-chem. Soc. 40, 192-197, (1908). Specific electrical conductivity of molten KNO3 and NaNOa.) 222. G. Boizard. Ann. Chim. Phys. (8), 13, 289-361, (1908). Sur la conductibUit^ ^lectrique dans les melanges d'acide ou de base et d'eau. [Same as 224 and 225. Text much fuller.] T = 18°. 223. G. Boizard. Ann. Chim. Phys. (8), 13, 43.3-479, (1908). Sur la conductibilit6 ^lectrique dans les melanges d'acide ou de base et d'eau. T = 25°. 224. G. Boizard. Jour. Phys. (4), 7, 119-135, (1908). Sur la conductibilit6 ^lectrique dans les melanges d'acide (ou de base) et d'eau. [Given in 222 and 226.] T = 18°. 406 AUTHOR LIST 225. G. Boizard. Bui. Soc. Franc. Phys. (1907), 308-324. Sur la conductibilit^ ^lectrique dans les melanges d'acide (ou de base) et d'eau. [Same as 222 and 224.] T = 18° I. Bolin see H. E'oler. 226. E. G. de BoUemont. Bui. Soc. Chim. (3), 25, 28-38, (1901). Ethers oxym6tlitoe-cyanac6tiques. [k same as 227. A also is given here. ] T=25°. R. O. 227. E. G. de BoUemont. Compt. Rend. 129, 50-53, (1899). Etude de I'oxymethylene-cyanac^tate de m^thyle et de quelques-uns de ses homologues. [For A and A of sodium salt see 226. Only k is given here.] E. Bondi see R. Wegscheider. 228. S. Bondi. Zeit. Physiol. Chem. 53, 8-13, (1907). Beitrage zur Chemie der Galle. II. Mitteilung. Ueber die Starke der Glyko- cholsaure. T=25° 7caq. = 1.55XlO-^ 229. W. A Bone, H. Henstock. Jour. Chem. Soc. 83, 1380-1391, (1903). The elimination of hydrogen bromide from bromo-gem-dimethylsuccinic acid and from bromotrimethylsuccinic anhydride, [k, with shghtly different value, but no A, given in 230.] T = 25°. 230. W. A. Bone, H. Henstock. Proc. Chem. Soc. 19, 247-248, (1903). The elimination of hydrogen bromide, etc. [k slightly different from 229. No A given here. ] 231. W. A. Bone, "W. H. Perkin, Jr. Jour. Chem. Soc. 67, 108-119, (1895). Meas. J. Walker. The condensation of ethylic trimethylenedicarboxylate with ethylic malonate. 232. W. A. Bone, W. H. Perkin, Jr. Jour. Chem. Soc. 67, 416-433, (1895). Meas. J. Walker. Trimethylsucoinic and aai-dimethylglutaric acids. 233. (W. A. Bone, W. H. Perkin, Jr. Jour. Chem. Soc. 69, 268-269, (1896). Note on the aoi-dimethylglutaric acids.) 234. W. A. Bone, C. H. G. Sprankling. Jour. Chem. Soc. 75, 839-864, (1899). Researches on the alkyl-substituted succinic acids. Part I. Methods of prep- aration. T = 25° [In the original, T is misprmted 23°; see 236.] 235. W. A. Bone, C. H. G. Sprankling. Jour. Chem. Soc. 77, 654-673, (1900). Researches on the alkyl-substituted succinic acids. Part II. s-Dipropyl, s-diisopropyl, and aai-propylisopropyl-succinic acids, [k, but not jj,, is given in 239 and 240 together, except for esters.] T = 25° 236. W. A. Bone, C. H. G. SprankUng. Jour. Chem. Soc. 77, 1298-1310, (1900). Researches on the alkyl-substituted succinic acids. Part III. Dissociation constants, [k, but not /i, is given in 241.] T = 25°. 237. W. A. Bone, C. H. G. SprankUng. Jour. Chem. Soc. 81, 29-50, (1902). The synthesis of alkyl tricarballylio acids, [k, but not n, is given in 242.] T = 25°. AUTHOR LIST 407 238. W. A. Bone, C. H. G. Sprankling. Jour. Chem. Soc. 83, 1378-1380, (1903). Dissociation constants of trimethylenecarboxylic acids, [k, but not fi, with slightly different values, is given in 243.] T = 25°. 239. W. A. Bone, C. H. G. SprankUng. Proc. Chem. Soc. 15, 149, (1899). The symmetrical di-isopropylsuccinic acids, [k is given in 236. No fi here. ] 240. "W. A. Bone, C. H. G. SprankUng. Proc. Chem. Soc. 16, 71-72, (1900). The sym-dipropyl, sym-diisopropyl, and aa'-propylisopropylsuccinic acids, [k is given in 236. No fi is given here. ] 241. W. A. Bone, C. H. G. SprankUng. Proc. Chem. Soc. 16, 184-185, (1900). Researches on the alkyl-substituted succinic acids. III. Dissociation con- stants, [k is same as 236. No /j, is given here.] 242. W. A. Bone, C. H. G. Sprankling. Proc. Chem. Soc. 17, 215^216, (1901). The synthesis of alkyl-substituted tricarballylic acids, [k is same as 237. No fj. is given here. ] 243. W. A. Bone, C. H. G. SprankUng. Proc. Chem. Soc. 19, 247, (1903). Dissociation constants of trimethylenecarboxylic acids. [The values of k differ slightly from 238. No fi is given here. ] 244. "W. A. Bone, J. J. Sudborough, C. H. G. Sprankling. Jour. Chem. Soc. 85, 534-555, (1904). The acid esters of methyl substituted succinic acids. T = 25°- 245. (W. A. Bone, J. J. Sudborough, C. H. G. SprankUng. Proc. Chem. Soc. 20, 64, (1904). Acid esters of methylsuccinic acids.) [Qualitative.] Bonomi da Monte see DaMonte. 246. V. BoreUi. Gaz. Chim. Ital. 38, I, 361-426, (1908). Delia costituzione di alcuni composti mercurici con cationi complessi. [Given in 248,] T = 25° 247. V. BorelU. Gaz. Chim. Ital. 39, I, 455-477, (1909). Delia costituzione di alcuni composti mercurici con cationi complessi. [Given in 248.] T = 25°. 248. V. BorelU. Mem. Accad. Torino. (2), 58, 451-560, (1908). Sulla costituzione di alcuni composti mercurici con cationi complessi. [Same as 246 and 247 together.] T=25°. 249. (I. Bosi. Nuovo Cim. (4), 5, 249-266, (1897). Sulla resistenza elfettrica delle soluzioni saline in movimento.) [Inorganic. ] 260. F. Bottazzi. Arch. Fisiol. 3, 416-446, (1906). Sulla regolazione della pressione osmotica negli organismi animali. Nota I''. Pressione osmotica e conduttivit^ elettrica dei liquid! di animali acquatici. T = ll° to30°. 251. F. Bottazzi. Arch. Fisiol. 3, 547-556, (1906). Sulla regolazione della pressione osmotica negU organismi animali. Nota 3*. Pressione osmotica e conduttivitA elettrica del sueco musculare, del siero di sangue e dell'orina dei pesci. T = 21.5°- 408 AUTHOR LIST 252. F. Bottazzi. Arch. Fisiol. 5, 243-252, (1908). Ricerche sulla regolazione della pressione osmotica negli organismi animali. Nota 4*. Origine dell'urea nei Selacii. T=21°to22°. 252a. F. Bottazzi. Arch. Fisiol. 7, 579-637, (1909). Ricerche sopra soluzioni di coUoidi organici. 253. F. Bottazzi. Ergebn. Physiol. 7, 161-402, (1908). mMeas. Nicolosi. Osmotischer Druck und elektrische Leitfahigkeit der Fliissigkeiten der ein- zelligen, pflanzlichen und tierisehen Organismen. [Contains a bibliography of osmotic pressure, freezing-point and conductivity of plant and animal fluids.] T = 18°to36° 254. F. Bottazzi. Rend. Accad. Lincei. (5), 18, II, 87-90, (1909). Sul trasporto elettrioo del glicogeno (e dell'amido). T = 20°. 255. F. Bottazzi, G. Buglia, A. Jappelli. Rend. Accad. Lincei. (6), 17, II, 49-57, (1908). Ricerche chimico-fisiche sui liquidi degli animali- III. Variazioni della con- duttivitS, elettrica, viscosity, e tensione superficiale del siero del sangue durante la dialisi. T = 37°. 256. F. Bottazzi, G. D'Errico. Arch. Gesammt. Physiol. 115, 359-385, (1906). Physiko-chemische Untersuchungen uber das Glykogen. T = 37°. R. O. 257. F. Bottazzi, G. D'Errico, G. Jappelli. Biochem. Zeit. 7, 431-470, (1907). Wirkung des Adrenalins auf die Speichel- und Hamabsonderung. T = 29.5°and37°. 258. F. Bottazzi, A. Jappelli. Biochem. Zeit. 11, 331-345, (1908). Physiko-chemische Eigenschafteri des Blutes und der Lymphe nach Trans- fusion homogenen Blutes. T = 37°. 259. F. Bottazzi, N. Scalinci. Rend. Accad. Lincei. (5), 17, II, 153-159, (1908). Ricerche chimico-fisiche sulla lente cristallina. 280. F. Bottazzi, N. Scalinci. Rend. Accad. Lincei. (5), 17, II, 305-316, (1908). Ricerche chimico-fisiche sulla lente cristallina. 2e0a. F. Bottazzi, C. Victorow. Rend. Accad. Lincei. (5), 19, II, 7-14, (1910.) Sulle propriety colloidali, e particolarmente sul trasporto elettrico dell'amido. 261. (W. R. Bousfield. Zeit. Phys. Chem. 53, 257-313, (1905). lonengrossen in Beziehung zur Leitfahigkeit von Elektrolyten.) [Inorganic] 262. (W. R. Bousfield, T. M. Lowiy. Proc. R. Soc. London. 71, 42-54, (1902-1903). Influence of temperature on the conductivity of electrolytic solutions.) [In- organic. ] 263. E. Bouty. Ann. Chim. Phys. (6), 27, 62-94, (1892.) Sur la coexistence du pouvoir di61ectrique et de la conductibilit^ iSlectroIytique. [Same as 266.] 264. (E. Bouty. Compt. Rend. 114, 533-535, (1892). Sur la coexistence du pouvoir diSlectrique et de la conductibilit6 ^lectroly- tique.) [Dielectric constants.] AUTHOR LIST 409 265. (E. Bouty. Compt. Rend. 114, 1421-1423, (1892). Sur la coexistence du pouvoir di^lectrique et de la conductibilit6 ^lectroly- tique.) [Dielectric constants.] 266. E. Bouty. Bui. Soc. Franc. Phys. (1892), 244-258. Sur la coexistence, etc. [Same as 263. ] 267. (G. Bredig. Ber. Deutsch. Chem. Ges. 37, 4140, (1904). Die Theorie der amphoteren Elektrolyte.) [A priority claim.] 268. G. Bredig. Zeit. Elektrochem. 6, 33-36, (1899-1900). Meas. K. Winkelblech. Ueber amphotere Elektrolyte und innere Salze. [Quabtative. See 1984 and 1985 for measurements. ] 269. G. Bredig. Zeit. Phys. Chem. 11, 829-831, (1893). Die Dissociation des Wassers. S. U. X aq. sub. 270. G. Bredig. Zeit. Phys. Chem. 13, 191-288, (1894). Beitrage zur Stochiometrie der lonenbewegUchkeit. T=25°. S. U. ;« aq.=2-4X10-^ sub. 271. G. Bredig. Zeit. Phys. Chem. 13, 289-326, (1894). Ueber die Affinitatsgrossen der Basen. [The values of k are about 16% too high, because of the value used for A( «> ) of OH. ] T = 25.0°- S. U. ;^aq. = l-2X10-8;notsub. Meas. Bredig; see 81, 503. 272. (G. Bredig, W. Fraenkel. Zeit. Elektrochem. 11, 525-528, (1905). Eine neue, sehr empfindliche Wasserstoffionen-Katalyse.) 273. G. Bredig, A. Usoff. Zeit. Elektrochem. 3, 116-117, (1896-1897). 1st Acetylen ein Elektrolyt? T= 25° for part of this. 274. J. Bredt. Ann. Chemie. 366, 1-70, (1909). Meas. E. Salm. Untersuchungen iiber die Constitution des Kamphers und seiner Derivate. 275. M. B. Breed. Dis. Bryn Mawr. (1901). The polybasic acids of mesitylene. T = 25°. xaq.= 2.2X10-". 276. (R. Brenosa. Mem. R. Acad. Madrid. 24, 1-488, (1906). La polarizaci6n rotatoria de la luz.) [Quoted.] 277. (M. Brillouin. Ann. Chim. Phys. (8), 7, 289-320, (1906). Considerations th^oriques sur la dissociation flectrolytique. — Influence du dissolvant sur la stabiUt^ des molecules dissoutes.) A. Bringhenti see G. Carrara. C. Brittlebank see V. Kohlschutter. 278. J. Brode, W. Lange. Arbeit, k. Gesundh. 30, 1-54, (1909). Beitrage zur Chemie des Essigs mit besonderer Beriicksichtigung seiner Unter- suchungsverfahren. 279. A. C. Brown, J. Walker. Ann. Chemie. 261, 107-128, (1891). Elektrolytische Sjmthese zweibasischer Sauren. [Same as 283.] T=25°. 280. A. C. Brown, J. Walker. Ann. Chemie. 274, 41-71, (1893). Elektrolytische Synthese zweibasischer Sauren. [Same as 284. k, but not jx, is given in 281 and 282. j T=25°. 281. C. Brown, J. Walker. Proc. R. Soc. Edinburgh. 18, 95-97, (1890- 1891). Electrolytic synthesis of dibasic acids. Alkyl derivatives of succinic acid. [This Brown is A. C. Brown. Same as first part of 280 for k. ] 410 AUTHOR LIST 282. C. Brown, J. Walker. Proc. R. Soc. Edinburgh. 19, 243-248, (1891- 1892). Synthesis by means of electrolysis. [This Brown is A. C. Brown. Same as last part of 280 fork.] 283. A. C. Brown, J. Walker. Trans. R. Soc. Edinburgh. 36, 211-224, (1889-1891). Electrolytic synthesis of dibasic acids. [Same as 279. ] T = 25°. Hg. U. 284. A. C. Brown, J. Walker. Trans. R. Soc. Edinburgh. 37, 361-379, (1891-1895). Electrolytic synthesis of dibasic acids. [Same as 280. ] 285. W. M. Bruce. Jour. Am. Chem. Soc. 26, 419-436, (1904). On the oxygen ethers of ureas. [Same as part of 287. ] 286. W. M. Bruce. Jour. Am. Chem. Soc. 26, 449-464, (1904). On the oxygen ethers of ureas. [Same as part of 287.] T = 25° ±0.01°. R. 6. 287. W. M. Bruce. Dis. Chicago. (1904). On the oxygen ethers of urea. [Same as 285 and 286 together.] 288. (J. W. Briihl. Ber. Deutsch. Chem. Ges. 24, 3701-3737, (1891). Untersuchungen iiber die Terpene und deren Abkommlinge.) 289. J. W. Briihl, H. Schroder. Ber. Deutsch. Chem. Ges. 37, 2512-2524, (1904). Physiko-chemische Untersuchungen der Camphocarbonsaure, ihrer Salze, Ester und Estersalze. T = 17°. 290. J. W. Briihl, H. Schroder. . Zeit. Phys. Chem. 50, 1^2, (1905). Ueber Salzbildungen in Losungen, inbesondere bei tautomerisierbaren Kor- pern (Pseudosauren, Pseudobasen). 290a. B. Brunacci. Arch. Fisiol. 8, 421-457, (1910). Sulla funzione secretoria della parotide nell'uomo. Nota prima. Influenza della quality, dello stimolo sulle propriety, fisico-chimiche della saliva parotidea. T = 37°. R. F. Brunei see A. Michael. 291. L. Bruner. Ber. Deutsch. Chem. Ges. 36, 3297-3298, (1903). Meas. J. Kozak, and G. Mariasz. Ueber Nitromethan als Losungsmittel. T = 18°. 291a. (L. Bruner. Zeit. Elektrochem. 16, 204r-205, (1910). Ueber die Leitfahigkeit der Halogene in Nitrobenzol.) 292. (L. Bruner. Bui. Acad. Cracov. (1901), 464-473. Ueber die Dissociation des Chloralhydrates und Chloralalkoholates in Lo- sungen.) 293. (L. Bruner. Bui. Acad. Cracov. (1907), 731-738. Ueber die elektrolytische Leitfahigkeit von Brom und Jod in Nitrobenzol- losungen.) [Inorganic] T = 7°and20°. 294. G. Bruni. Zeit. Elektrochem. 14, 701-706, (1908). Meas. A. Aila. Vergleichende Untersuchungen iiber Salzbildung und iiber die Basizitat der Sauren vom physiko-chemischen Standpunkte. [Acetic, formic and chloro- acetic acids are given in 296. See 1716. ] T = 25°. X aq. = 1 X 10~^ sub. when necessary. 295. G. Bruni. Zeit; Elektrochem. 14, 729-734, (1908). Meas. A. Aita. Vergleichende Untersuchungen iiber Salzbildung und iiber die Basizitat der Sauren vom physiko-chemischen Standpunkte. [See 1716.] AUTHOR LIST 411 296. G. Bnmi, A. Aita. Rend. Accad. Lincei. (5), 17, II, 295-303, (1908). Contributi alio studio dei fenomeni di salificazione dal punto di vista chimioo- fisico. [Given in 294.] T=25°- 297. G. Bnini, P. Berti. Gaz. Chim. Ital. 30, II, 161-157, (1900). Sulle proprietEl deU'ipoazotide come solvente. [Qualitative. Same as 298.] 298. G. Bruni, P. Berti. Rend. Accad. Lincei. (5), 9, 1, 321-326, (1900). Sulle propriety,, etc. [Same as 297. ] 299. G. Bruni, C. Sandonnini. Zeit. Elektrochem. 14, 823-825, (1908). Vergleichende Untersuchungen iiber Salzbildung und iiber die Basizitat der Sauren vom physiko-chemischen Standpunkte. X aq. =3X10-^ sub. when necessary. 299a. G. Bruni, C. Sandonnini. Zeit. Elektrochem. 16, 223-227, (1910). Vergleichende Untersuchungen iiber Salzbildung vom physikochemischen Standpunkte. T = 25°. B. R. de Bruyn see A. F. Holleman. 300. C. A. L. de Bruyn. Rec. Trav. Chim. 18, 299-301, (1899). Meas. G. V. d. Sleen. Sur la demonstration de la force relative des acides. [Full tables ot A and k are given in 1633 and 1634.] C. L. de Bruyn see E. Cohen. L. de Bruyn, E. Cohen. Verslag. Akad. Amsterdam. (1902-1903). See E. Cohen, C. L. de Bruyn. 301. G. B. Bryan. Phil. Mag. (5), 45, 253-272, (1898). On the determination of the conductivity of liquids in thin layers. T = 9° to 12°. Meas. K. Bube; see 507. 302. K. Buch. Ber. Deutsch. Chem. Ges. 41, 692-695, (1908). Ueber Ammonium-phenolat. T=25°. 302a. K. Buch. Zeit. Phys. Chem. 70, 66-87, (1910). Die Hydrolyse der Ammoniumsalze fluchtiger Sauren. T = 25°. 303. K. Buchka, A. Magalhaes. Ber. Deutsch. Chem. Ges. 24, 674-680, (1891). Meas. Nemst. Ueber das Cytisin. T = 18°. Hg. U. Meas. M. Buchner; see 736, 781, 1094. L. Buchstab see N. ZeUnsky. 304. E. Buckingham. Zeit. Phys. Chem. 14, 129-148, (1894). Ueber einige Fluoreszenzerscheinungen. T = 25°. 305. E. Buckingham. Trans. Am. Electrochem. Soe. 9, 265-276, (1906). The settling of suspensions. T = 13°to25°. R. O. 305a. C. Billow, (K. Haas). Ber. Deutsch. Chem. Ges. 43, 3401-3412, (1910). Sjmthese von Derivaten des 1,2,7-Pyrazo-pyridins, einer neuen Ordnung homo-(C. C.)-kondensierter, bisheterocycUscher Verbindungen. T=25°. E. Biirkle see H. Goldschmidt. 412 AUTHOR LIST 306. G. Buglia. Arch. Fisiol. 4, 56-66, (1907). Variazioni fisico-chimiche del siero di sangue durante rinvecchiamento. T = 30°. 307. G. Buglia. Biochem. Zeit. 13, 400-439, (1908). Ueber die Regulierung der physiko-chemischen Eigenschaften des Blutes nach Injektionen von verschiedenen Losungen. T=37°. 308. G. BugUa. Zeit. Chem. Ind. KoUoid. 2, 353-354, (1908). Ueber einige physikalisch-chemisehe Merkmale der homogenisierten Milch. T = 37°. G. BugUa see F. Bottazzi. " " see L. Sabbatani. 309. G. Buglia, L. Karczag. Rend. Accad. Lincei. (5), 18, II, 374r-380, (1909). Influenza della configurazione stereochimica su alcune propriety fisico-chi- miche dei coUoidi organici. T = 37°. 310. (G. Buglia, L. Karczag. Rend. Accad. Lincei, (5), 18, II, 474-481, (1909). Influenza della configurazione stereochimica su alcune propriety, fisico-chi- miche dei colloidi organici.) 310a. F. J. J. Buijtendijk. Verslag Akad. Amsterdam. 18, 261-264, (1909). Verslag Akad. Amsterdam, English translation, 12, 377-380. Over de veranderingen in het bloedserum van haaien na verbloeding. T=25°. 310b. F. J. J. Buijtendijk. Verslag Aka-d. Amsterdam. 18, 264-267, (1909). Verslag Akad. Amsterdam, English translation, 12, 380-383. Over de samenstelling der urine van haaien, bij normale en versterkte diurese. T = 25°. O. D. E. Bunge see A. Michael. O. Burger see J. Sand. 311. (C. H. Burgess, D. L. Chapman. Jour. Chem. Soc. 85, 1305-1317, (1904). The nature of a solution of iodine in aqueous potassium iodide.) {Inorganic. ] 312. (C. H. Burgess, D. L. Chapman. Proc. Chem. Soc. 20, 62-63, (1904). The nature of, etc.) [Same as 311.] 313. E. F. Burton. Phil. Mag. (6), 17, 583-597, (1909). The action of electrolytes on copper colloidal solutions. T = 18°. xaq. =2X10-8. 314. M. Busch, G. Mehrtens. Ber. Deutsch. Chem. Ges. 38, 4049-4068, (1905). #Meas. Jordis. Ueber Endiminotriazole. T = 25'' Bz see Tijmstra Bz. C. 315. H. P. Cady. Jour. Phys. Chem. 1, 707-713, (1896-1897). The electrolysis and electrolytic conductivity of certain substances dissolved in liquid ammonia. T=-34°. 316. P. Cahn-Speyer. Monatsh. 28, 803-817, (1907). Meas. N. L. Miiller. Untersuchungen uber die Veresterung unsymmetrischer zwei- und mehrbasis- cher Sauren. XVI. Abhandlung; Ueber Abkommlinge der Aminotereph- thalsaure. [Same as 317. ] AUTHOR LIST 413 317. P. Cahn-Speyer. Sitzber. Akad. Wien. 116, 2b, 705-719, (1907). Meas. N. L. Mailer. Untersuchungen iiber die Veresterung, etc. [Same as 316.] 318. J. C. Cain. Jour. Chem. Soc. 91, 1049-1056, (1907). Meas. H. H. The constitution of the diazo-compounds. 319. P. Calame. Zeit. Phys. Chem. 27, 401-420, (1898). Meas. Brauer, Dittrich, Martin, Smith, Winkelblech. Ueber die Dissociation mehrwertiger Salze. [Same as 320. ] T=25°. 320. P. Calame. Dis. Leipzig. (1898). Meas. as 319. Ueber die Dissociation, etc. [Same as 319].] 320a. G. Calcagni. Rend. Accad. Lincei. (5), 19, II, 290-293, (1910). Sul lattato di beriUio. T=25°. 320b. G. Calcagni. Rend. Accad. Lincei. (5), 19, II, 333-337, (1910). Studii sulla capacity degli ossidrili alcoohci a formare complessi. Meas. B. P. Caldwell; see 1981. B. P. Caldwell see H. C. Jones. 321. K. S. CaldweU. Chem. News. 96, 75-76, (1907). On the conductivity of electrolytes in pyridine and other solvents. [Given in 764.] K. S. Caldwell see A. Hantzsch. 322. R. J. Caldwell. Proc. R. Soc. London. A, 78, 272-295, (1906). Studies of the processes operative in solutions. Part I. The sucroclastic ac- tion of acids as influenced by salts and non-electrolytes. R. O. 323. (R. J. Caldwell, R. Whymper. Proc. R. Soc. London. A, 81, 112-117, (1908-1909). The determination of optical rotatory power.) 324. R. J. CaldweU, R. Whymper. Proc. R. Soc. London. A, 81, 117-140, (1908-1909). The changes effected by the reciprocal interference of cane-sugar and other substances (salts and non-electrolytes) in aqueous solutions. X26 aq. less than 2X10"^. 325. C. Camichel. Jour. Phys. (4), 4, 873-884, (1905). Fluorescence. T = 16°to21°. 326. G. Campenhausen. Dis. Heidelberg. (1896). Meas. A. Pfaff. I. Ueber Oxytrimethylbernsteinsaure. [Same as 64. ] G. V. Campenhausen see K. Auwers. 327. (A. Campetti. Nuovo Cim. (3), 35, 225-234, (1894). SuU'influenza del solvente suUa velocity degU ioni.) [Inorganic] 328. (A. Campetti. Atti Accad. Torino. 38, 64-75, (1902-1903). Sul calore di dissociazione elettrohtica.) 329. (A. Campetti. Atti Accad. Torino. 43, 1071-1094, (1907-1908). Sulla variazione del grado di dissociazione di alcuni elettroliti colla tempera- tura.) [Inorganic] 330. (A. Campetti, M. Nozari. Atti Accad. Torino. 40, 177-185, (1904- 1905). Sulla variazione del grado di dissociazione elettrohtica colla temperatura.) [Inorganic. ] T. Carlson see P. Klason. 414 AUTHOR LIST 331. (A. Garz6n y Carmona. Rev. R. Acad. Madrid. 8, 70-94, (1909-1910). Sobre la conductibilidad de disoluciones de CIK y ClNa en mezclas de agua y alcohol metlUco. (Variaciones con el tanto per ciento de alcohol, la concen- trati6n y la temperatura).) [Inorganic] T=0°to50°. 332. N. Caro, H. Grossmann. Chem. Ztg. 33, 734-735, (1909). Meas. Magnus. Zur Kenntnis der chemischen Natur des Dicyandiamids. 333. (G. Carrara. Gaz. Chim. Ital. 23, II, 587-596, (1893). Sulla dissociazione elettrolitica in relazione col potere rotatorio ottico.) [Quoted.] 334. G. Carrara. Gaz. Chim. Ital. 24, II, 504-535, (1894). Dissociazione elettrolitica e legge della diluizione nei solventi organici. [Same as 340. ] T = 25°. 335. G. Carrara. Gaz. Chiip. Ital. 26, I, 119-195, (1896). Per la teoria della dissociazione elettrolitica in solventi diversi dall'acqua. I. Alcool metilico. T=25°. X alcohol sub. 336. G. Carrara. Gaz. Chim. Ital. 27, I, 207-222, (1897). Per la teoria della dissociazione elettrolitica in solventi diversi dall'acqua. II. Acetone. X acetone sub. 337. G. Carrara. Gaz. Chim. Ital. 27, I, 422-440, (1897). Sulla dissociazione elettrolitica dell'alcool metilico e dell'acqua in esso disci- olta. [In two cases Carrara distilled the alcohol over sodium. Cf. Loomis 1123 and 1124.] 338. G. Carrara. Gaz. Chim. Ital. 33, I, 241-311, (1903). Per la teoria della dissociazione elettrolitica in solventi diversi dall'acqua. III. Influenza del solvente sopra i numeri di trasporto. [Same as 341.] [T probably 25°.] R. O. 339. (G. Carrara. Gaz. Chim. Ital. 37, I, 525-561, (1907). Elettrochimica dalle soluzioni non acquose.) [Same as 342. ] 340. G. Carrara. Rend. Accad. Lined. (5), 3, II, 383-390, (1894). Dissociazione elettrolitica, etc. [Same as 334. ] 341. G. Carrara. Mem. Accad. Lincei. (5), 4, 338 and 339-387, (1901). Per la teoria della dissociazione, etc. [Same as 338.] 342. (G. Carrara. Mem. Accad. Lincei. (5), 6, 268-291, (1906-1908). Elettrochimica delle soluzioni non acquose.) [A review of work done up to date on the electrical conductivity of non-aqueous solutions. Same as 339.] 343. G. Carrara, L. D'Agostini. Atti 1st. Veneto. 62, II, 793-802, (1902- 1903). Sul grado di dissociazione elettrolitica dell'alcool metilico. 344. G. Carrara, A. Bringhenti. Gaz. Chim. Ital. 38, I, 698-708, (1908). Sopra i potenziali di scarica degli ioni contenuti neUe soluzioni di alcoolati alcalini. [Same as 345.] 345. G. Carrara, A. Bringhenti. Rend. R. 1st. Lombardo. (2), 40, 1190- 1200, (1907). Sopra i potenziali, etc. [Same as 344.] 346. (G. Carrara, M. G. Levi. Gaz. Chim. Ital. 30, H, 197-217, (1900). Sopra elettrostrizione degli ioni in solventi organici.) [Quoted. See 348. ] 347. G. Carrara, M. G. Levi. Gaz. Chim. Ital. 32, II, 36-53, (1902). Sui coefficienti di temperatura della conducibiUtS, elettrica delle soluzioni in AUTHOR LIST 4.15 acqua e solventi organiei. influenza della soprafusione e del massimo di density,. [Same as 349.] T=-3°to25°. R. O. 348. (G. Carrara, M. G. Levi. Nuovo Cim. (4), 12, 284-288, (1900). Sopra elettrostrixione, etc.) [The text is an abridgement of 346.] 349. G. Carrara, M. G. Levi. Atti 1st. Veneto. 61, II, 525-542, (1901- 1902). Sui coefficienti di temperatm-a, etc. [Same as 347.] 350. G. Carrara, U. Rossi. Gaz. Chim. Ital. 27, II, 505-532, (1897). Sopra I'energia di alcime basi a funzione mista. [Same as 351, 352 and 353 together. ] K aq. sub. 351. (G. Carrara, U. Rossi. Rend. Accad. Lincei. (5), 6, II, 152-158, (1897). Sopra I'energia, etc.) [Same as first part of 350.] 352. G. Carrara, U. Rossi. Rend. Accad. Lincei. (5), 6, II, 208-216, (1897). ConducibiUtS, elettrica di alcune basi a funzione mista e dei lore cloridrati. [Same as middle part of 350.] 353. G. Carrara, U. Rossi. Rend. Accad. Lincei. (5), 6, II, 219-226, (1897). Catalisi dell'acetato di metUe per mezzo dei sali di alcune basi a funzione mista. [Same as last part of 350. The affinity constants given here are not ionization constants; see 1864.] 354. P. Carre. Bui. Soc. Chim. (3), 33, 1314-1316, (1905). Sur la conductibilit6 molficulaire des others phosphoriques. [Same as 355. ] T=25°. R. O. xaq.=0.6X10-^ 355. P. Carre. Compt. Rend. 141, 764-766, (1905). Sur la conductibilit^, etc. [Same as 354. ] 356. (C. G. CairoU. Am. Chem. Jour. 36, 594-599, (1906). Ionic velocity and ionic hydration.) 357. C. G. Carroll. Dis. Johns Hopkins. (1904). I. A study of the conductivity of certain electrolytes, etc. [Same as 908.] C. G. Carroll see H. C. Jones. G. A. Carse see T. H. Laby. 358. (G. A. Carse, T. H. Laby. Proc. Cambridge Phil. Soc. 14, 1-12, (1907-1908). A relation between the velocity and volume of organic ions in aqueous solu- tions.) 359. (W. Cassie. Proc. R. Soc. London. 46, 357-358, (1889). On the effect of temperature on the specific inductive capacity of a dielectric.) 360. C. Cattaneo. Rend. Accad. Lincei. (5), 2, I, 295-298, (1893). Coefficiente negative di temperatura per la conducibilit^ elettrica delle solu- zioni eteree. [Given in 366. ] T=0°to25'' Hg. U. 361. C. Cattaneo. Rend. Accad. Lincei. (5), 2, II, 112-119, (1893). Sulla oonducibilitS, elettrica dei sali disciolti in-glicerina. T = 0° to24.8°. 362. C. Cattaneo. Rend. Accad. Lincei. (5), 4, II, 63-70, (1895). Sulla cqnducibilit&, elettrica dei sali in var! solventi. T = 18°. Hg. U. 363. (C. Cattaneo. Rend. Accad. Lincei. (5), 4, II, 73-77, (1895). Considerazioni sulla conducibilitll elettrica dei sali in vart solventi.) [Inor- ganic and quoted. ] 364. (C. Cattaneo. Rend. Accad. Lincei. (5), 5, II, 207-214, (1896). Dell'influenza del solvente sulla velocity, degli joni.) [Inorganic] 416 AUTHOR LIST 365. (C. Cattaneo. Rend. Accad. Lincei. (5), 6, I, 279-286, (1897). Sul numero di trasporto del cloro dell'acido cloridrico in solvent! diversi.) [Inorganic. ] 366. C. Cattaneo. Atti Accad. Torino. 28, 617-631, (1892-1893). Sulla oonducibilit^ elettrica dei sali in varii solventi. [Part is in 360.] Hg. U. Centnersver see Centnerszwer. 367. M. Centnerszwer. Jour. Russ. Phys.-chem. Soc. 33, 545-547, (1901). Some properties of liquid cyanogen. [Same as part of 369. ] 368. M. Centnerszwer. Jour. Russ. Phys.-chem. Soc. 33, 547-549, (1901). The ionizing properties of liquid hydrogen cyanide. [Same as part of 369. ] T = 0°. S. U. 369. M. Centnerszwer. Zeit. Phys. Chem. 39, 217-224, (1902). Ueber losende und dissociierende Eigenschaften des flussigen Cyans und des fliissigen Cyanwasserstoffs. [Same as 367 aad 368 together. ] T = 0°. S. U. Meas. M. Centnerszwer; see 192, 193, 1843. M. Centnerszwer see P. Walden. 370. E. E. Chandler. Jour. Am. Chem. Soc. 30, 694-713, (1908). The ionization constants of the second hydrogen ion of dibasic acids. [Cor- rected in 1917.] T = 0°and25°±0.01°. R. O. ^ 371. A. M. Chanoz. Jour. Phys. (4), 6, 114-127, (1907). fitude sur les contacts liquides directs. [Given in 372.] 372. A. M. Chanoz. Ann. Univ. Lyon. I, Fasc. 18, 1-99, (1906). Recherches exp^rimentales sur les contacts liquides. [Contains also meas- urements not given in 371.] D. L. Chapman see C. H. Burgess. 373. J. Chaudier. Ann. Chim. Phys. (8), 15, 67-140, (1908). Sur les propri6t6s ^lectro-optiques des liqueurs mixtes. ^ 374. J. Chaudier. Jour. Phys. (4), 8, 422-439, (1909). Etude experimentale des propri6t6s ^lectro-optiques des liqueurs mixtes. 375. G. Chavanne. Ann. Chim. Phys. (8), 3, 507-574, (1904). Sur I'acide isopyromucique. 375a. H. Chick, C. J. Martin. Jour. Physiol. 40, 404^30, (1910). On the " heat coagulation " of proteins. 376. A. Chilesotti. Gaz. Chim. Ital. 34, II, 493-503, (1904). Di due sali complessi di molibdeno. T = 25°. 376a. A. Chistoni. Arch. Fisiol. 8, 193-204, (1910). Influenza dello jodo sulle costanti fisico-chimiche del sangue. T=25°. Chroushtchoff see Chroustchoff. 377. P. Chroustchoff. Compt. Rend. 108, 1003-1006, (1889). Sur I'^tude de conductibilit6 61ectrique des dissolutions salines, appliqu^e aux problfimes de m^canique chimique. [Most of the measurements are same as 380, but T varies slightly in some cases, and formic acid is not given here. ] T = 18°to21°- 378. P. Chroustchoff. Compt. Rend. 108, 1100-1102, (1889). De la conductibilitfi 61ectrique des dissolutions salines. D6placement r6ci- proques des acidea. T = 18°to21''. AUTHOR LIST 417 379. P. Chroustchoft. Compt. Rend. 108, 1161-1162, (1889). Sur r^tude de la conductibiliti flectrique des dissolutions salines, appliqu^e aux probtemes de micanique chimique. Doubles decompositions. T = 20°. 380. P. Chroustchoff. Jour. Russ. Phys.-chem. Soc. 22, 115-116, (1890). Electrical conductivity of aqueous solutions of some salts and acids. [Almost the same as 377.] 381. P. Chroustchoff, V. Pachkoff. Compt. Rend. 108, 1162-1164, (1889). Sur la conductibiliti 61ectrique des dissolutions salines contenant des mflanges de sels neutres. [Same as 382. ] 382. P. Chroustchoff, V. Pachkoff. Jour. Russ. Phys.-chem. Soc. 22, 110- 115, (1890). Electrical conductivity of solutions of mixtures of some neutral salts. [Same as 381.] Chroutschoff see Chroustchoff. Chruscov see Chroustchoff. 383. G. di Ciommo. Phys. Zeit. 3, 373-374, (1901-1902). TJeber die elektrische Leitungsfahigkeit von isolierenden Fltissigkeiten und ihren Mischungen. [Apparently an abridgement of 386.] 384. G. di Ciommo. Phys. Zeit. 4, 291-293, (1902-1903). TJeber die ionisierende Kraft einiger nichleitenden organischen Flussigkeiten. 385. G. di Ciommo. Nuovo Cim. (5), 2, 81-87, (1901). Sulla conducibilita elettrica degli idrati di sodio e potassio in soluzioni gli- ceriche. Hg. U. 386. G. di Ciommo. Nuovo Cim. (5), 3, 97-121, (1902). Sulla conducibilitEl elettrica dei Uquidi isolanti e dei loro miscugli. [Ab- stracted in Zeit. Phys. Chem. 44, 508, (1903). See 383.] Hg. U. 387. L. Claisen. Ann. Chemie. 297, 1-98, (1897). Meas. Holleman. Untersuchungen iiber die Oxymethylenverbindungen. T = 2.6°to23.5° Meas. R. W. L. Clarke; see 1051, 1052. P. Claussner see A. Wohl. 388. J. A. CUnch. Dis. Gottingen. (1904). TJeber einige anorganische KoUoide und Metallacetylacetonate. X aq. sub. A. M. Clover see P. C. Freer. 388a. A. M. Clover, H. C. Jones. Am. Chem. Jour. 43, 187-223, (1910). The conductivities, dissociations, and temperature coefficients of conductivity between 35° and 80° of solutions of a number of salts and organic acids. T = 35°to80°. S. U. xaq.= 2.0X10-8; sub. 389. G. Coffetti. Gaz. Chim. Ital. 30, II, 235-246, (1900). Sopra I'energia di alcuni acidi organici non carbossilici. [Fiorini is quoted. See 577 for original. ] T = 25°. 390. (G. Coflfetti. Gaz. Chim. Ital. 33, I, 53-68, (1903). Contribute alia conoscenza delle relazioni fra la natura e la propriety, del solvente e la sua forza ionizzatrice. Conducibilita elettrica e suoi coefficienti di temperatura in solventi organici.) [Inorganic] 391. E. Cohen. Zeit. Phys. Chem. 25, 1^5, (1898). Experimentaluntersuchung uber die Dissociation geloster Korper in Alkohol- Wassergemischen. T = 18°. Hg. TJ. Kie aq. is less than 0.24 X 10-". 418 AUTHOR LIST 392. E. Cohen. Zeit. Phys. Chem. 37, 69-83, (1901). Meas. Y. Osaka. Studien uber die Inversion. Meas. E. Cohen; see 11. 393. E. Cohen, C. L. de Bruyn. Verslag Akad. Amsterdam. 11, 621-626, (1902-1903). Verslag Akad. Amsterdam, English translation, 5, 551- 556, (1902-1903). Het geleidingsvermogen van hydrazine en van daarin opgeloste stoffen. T = 25'?. «25aq. =2.8X10-". Cohn see Lassar-Cohn. 394. F. Cojazzi. Gaz. Chim. Ital. 30, I, 187-188, (1900). Sull'energia di alouni acidi ossisolfonici. 396. U. CoUan. Zeit. Phys. Chem. 10, 130-140, (1892). Ein Beitrag zur Kenntnis der Autokatalyse. [Same as 396. ] T = 25°. 396. U. CoUan. Ofvers. Finska Vet.-Soc. Forhand. 34, 249-262, (1891- 1892). Ein Beitrag, etc. [Same as 395. ] Meas. U. CoUan; see 52, 826, 827, 830, 1838. 397. J. N. CoUie. Jour. Chem. Soc. 77, 971-977, (1900). Meas. J. Walker. Dehydracetic acid. [Same as 398.] 398. J. W. Collie. Proc. Chem. Soc. 16, 147, (1900). Meas. J. Walker. Dehydracetic acid. [Same as 397. ] 399. J. N. CoUie, T. P. Hilditch. Jour. Chem. Soc. 91, 787-789, (1907). An isomeric change of dehydracetic acid. [Same as 400.] 400. J. N. Collie, T. P. Hilditch. Proc. Chem. Soc. 23, 92, (1907). An isomeric change of dehydracetic acid. [Same as 399.] 401. J. N. Collie, T. Tickle. Jour. Chem. Soc. 75, 710-717, (1899). Meas. Kellas. The salts of dimethylpyrone, and the quadrivalence of oxygen. L. H. Cone see M. Gomberg. 402. E. J. Constam, J. White. Am. Chem. Jour. 29, 1-49, (1903). Physico-chemical investigations in the pyridine series. T = 25°. S. U. :x:aq.= 0.9 -1.5X10-"; sub. Meas. H. C. Cooper; see 1341b. H. C. Cooper see A. A. Noyes, A. C. Melcher. 403. N. Coos. Ber. Deutsch. Chem. Ges. 35, 4109-4112, (1902). TJeber Selendilactylsauren. T = 25°. S. U. 404. A. Coppadoro. Gaz. Chim. Ital. 32, I, 537-572, (1902). Sulla grandezza di affinity degli acidi ossibenzoici alogenati in rapporto alia loro costituzione. T = 24° ;x: aq. =3X10-"; probably sub. 406. V. v. Cordier. Monatsh. 27, 697-729, (1906). Ueber einen Fall von wahrscheinlicher Stereoisomerie beim Guanidin. [Same as 406 and 407. ] T = 20°. 406. V. V. Cordier. Sitzber. Akad. Wien. 115, 2b, 497-529, (1906). Ueber einen Fall, etc. [Same as 405 and 407.] 407. V. V. Cordier. Verh. Ges. Deutsch. Naturf. Aerzte. 76, II, 1, 105-108, (1904). Ueber eine wahrscheinliche Stereoisomerie, etc. [Same as 405 and 406. ] W. Cormack see J. Walker. AUTHOR LIST 419 408. E. Comec. Compt. Rend. 149, 676-678, (1909). fitude cryoscopique de la neutralisation de quelques acides. T. Costa see R. Nasini. H. R. Courtman see J. C. Philip. Meas. H. Couvert; see 214a. Coy = McCoy, q. v. 409. D. C. Crichton. Jour. Chem. See. 91, 1793-1797, (1907). Hydrates of some quaternary bases. Meas. D. C. Crichton; see 1858, 1879. 410. J. C. Crocker. Jour. Chem. Soc. 91, 593-612, (1907). The velocity of hydrolysis of aliphatic amides. T = 63.2°. R. O. xaq. =2.7X10-8. 411. (J. C. Crocker. Proc. Chem. Soc. 23, 63, (1907). The velocity of hydrolysis of aliphatic amides.) [No data. ] 412. J. C. Crocker, F. H. Lowe. Jour. Chem. Soc. 91, 952-962, (1907). The velocity of hydrolysis of the aliphatic amides by alkali. T = 40.06°, 63.2° and 95.9°. R. O. 413. A. W. Crossley, W. H. Perkin, Jr. Jour. Chem. Soc. 73, 1-44, (1898). Meas. T. Ewan. Decomposition of camphoric acid by fusion with potash or soda. D. Crothers see H. E. Armstrong. 414. A. C. Cumming. Zeit. Phys. Chem. 57, 574-599, (1906). Die AflBnitatskonstanten amphoterer Elektrolyte. II. Methylderivate der Ortho- und Metaamidbenzoesaure. [Same as 415. ] T = 25°. X25 aq. not more than 1.5X10-^- 415. A. C. Cumming. Proc. R. Soc. London. A, 78, 103-139, (1906). The affinity constants of amphoteric electrolytes. II. Methyl derivatives of ortho- and meta-aminobenzoic acids. [Same as 414. ] 416. J. A. Cunningham. Proc. Cambridge Phil. Soc. 11, 431^33, (1900- 1902). On an attempt to detect the ionisation of solutions by the action of light and Rontgen rays. 417. P. Curie. Compt. Rend. 134, 420-423, (1902). Conductibilit^ des di^lectriques liquides sous I'influence des rayons du radium et des rayons de Rontgen. 418. R. S. Curtiss. Am. Chem. Jour. 28, 315-326, (1902). On an acid derivative of ethyl anilinomalonate. T = 19° and 19.5°. 419. T. Curtius, R. Radenhausen. Jour. Prakt. Chem. (2), 43, 207-208, (1891). Meas. W. OstwaU. Zur Kenntniss der Stickstoffwasserstoffsaure. L. D'Agostini see G. Carrara. 420. P. DaUe. Reo. Trav. Chim. 21, 123-154, (1902). Sur le trim^thylfene-carbinol et ses d6riv6s. [Same as 421.] T=25°. 421. P. Dalle. Bui. Acad. Belg. (1902), 36-79. Sur le trim^thylene-carbinol, etc. [Same as 420. ] 422. W. van Dam. Zeit. Physiol. Chem. 58, 295-330, (1908-1909). Beitrag zur Kenntnis der Labgerinnung. 420 AUTHOR LIST 423. P. B. DaMonte, A. Zoso. Gaz. Chim. Ital. 27, II, 467-475, (1897). Sulla energia di alcuni aoidi solfonici del toluolo e del xilolo. T = 25°. 424. (H. Danneel. Zeit. Elektrochem. 11, 249-252, (1905). Notiz uber lonengeschwindigkeiten.) [Inorganic] H. Davidsohn see L. Michaelis. Meas. W. B. Davidson; see 731, 735, 775, 1729. W. B. Davidson see A. Hantzsch. 425. W. B. Davidson, A. Hantzsch. Ber. Deutsch. Chem. Ges. 31, 1612- 1648,(1898). » Meas. Kissel. Physikochemische Untersuchungen iiber Diazoniumsalze, Diazoniumhydrat und normale Diazotate. T=0°, 1° and 25°. R. O. E. Davis see C. H. Herty. 426. H. M. Dawson. Zeit. Phys. Chem. 69, 110-122, (1909). On the nature of ammoniacal solutions of cupric hydroxide. T = 18°- de; see under the letter beginning the next word, e. g., de Bruyn, see under Bruyn. 427. S. Deakin, M. Scott, B. D. Steele. Zeit. Phys. Chem. 69, 123-135, (1909). On the complex oxalates of cobalt and nickel. De Blasi see Blasi. 428. G. Dedichen. Ber. Deutsch. Chem. Ges. 39, 1831-1856, (1906). Affinitatsgrossen einiger cyclisoher Basen. [T probably 25°.] R. O. 429. (C. Deguisne. Ann. Physik. (3), 62, 604-606, (1894). Ueber die Frage nach einer Anomalie des Leitvermogens wasseriger Losungen bei 4°.) [Inorganic] 430. C. Deguisne. Dis. Strassburg. (1895). Abstracted in Beibl. Ann. Physik. 20, 996-997, (1896). TemperaturkoefBzienten des Leitvermogens sehr verdiinnter wasseriger Losungen. de la; see under the letter beginning the next word, as for de. 431. M. Delepine. Bui. Soc. Chim. (4), 3, 643-652, (1908). Composes sulfur^s et azotes d^rivfe du sulfure de carbone (XII). Thiosulfo- carbamates mStalliques. [Same as 432.] 432. M. Delepine. Compt. Rend. 146, 981-984, (1908). Propri6t6s des thiosulfocarbamates m^talliques. [Same as 431.] H. Demierre see P. Dutoit. 433. C. Dempwolff. Phys. Zeit. 5, 637-641, (1904). lonenwanderung im Methylalkohol als Losungsmittel. T = 18°. 434. H. G. Denham. Jour. Chem. Soc. 93, 41-63, (1908). The electrometric determination of the hydrolysis of salts. T = 25°. xaq. = 1.2 -2.5X10-6. 435. R. B. Denison, B. D. Steele. Jour. Chem. Soc. 89, 999-1013, (1906). A new method for the measurement of hydrolysis in aqueous solution based on a consideration of the motion of ions. [See correction in 436. k at 25° is given in 437. ] T = 18°and25°. 436. R. B. Denison, B. D. Steele. Jour. Chem. Soc. 89, 1386-1387, (1906). A new method for the measurement of hydrolysis in aqueous solution based AUTHOR LIST 421 on a consideration of the motion of ions. A correction, [k at 25° is same as in 436. The correction is for 18°. ] T = 18° and 25° 437. R. B. Denison, B. D. Steele. Proc. Chem. Soc. 22, 162-163, (1906). A new method, etc. [k at 25° same as 435. No A given here.] 438. R. Dennhardt. Ann. Physik. (3), 67, 325-344, (1899). Ueber Beziehungen zwischen Fluiditat und elektrolytischer Leitfahigkeit von Salzlosungen sowie iiber die Leitfahigkeit von Oelsaure und deren Alka- lisalzen in Wasser bez. Alkoholen bei verschiedenen Temperaturen. T = 0°to60°. R. O. :>iaq. = 1.0-2.2X10-«; sub. 439. I. H. Derby. Am. Chem. Jour. 39, 437-473, (1908). Studies in catalysis. IV. The catalysis of imidoesters. [k same as in part of 1656 and 1657.] T = 18° and 25° ± 0.01 °. Hg. U. Meas. I. H. Derby; see 1657. I. H. Derby see J. Stieglitz. D'Errico see Errico. des; see under the letter beginning next word, as for de. C. H. Desch see A. Hantzsch. 440. J. Deschauer. Dis. Heidelberg. (1905). Meas. A. Benrath. Ueber die Kondensation von Aceton mit Bernsteinsaureester. [Probably R. O.] x aq. =6.23X10"^ 441. E. Deussen. Zeit. Anorg. Chem. 44, 300-340, (1905). Zur Kenntnis der Plusssaure. [Same as 442. ] T = 25°. 442. E. Deussen. Habilitschr. Leipzig. (1905). Zur Kenntnis der Plusssaure. [Same as 441.] 443. E. Deussen, G. Heller, O. Notzel. Ber. Deutsch. Chem. Ges. 40, 1300-1303, (1907). Lfeitfahigkeit wassriger Losungen von N-Isatin-natrium und isatinsaurem Natrium. T = 25° 444. A. Devrient. Dis. Leipzig. (1897). Isomere der Camphoronsaure. T = 25°. J. Dewar see J. A. Fleming. 445. J. Dewar, J. A. Fleming. Proc. R. Soc. London. 61, 2-18, (1897). Note on the dielectric constant of ice and alcohol at very low temperatures. T=-185°. 445a. C. Dhere, M. Gorgolewski. Compt. Rend. 150, 934-936, (1910). Sur la preparation et sur quelques propri6t6s physicochimiques de la gelatine d^mineralis^e. xaq. = 1.5X10-^ 445b. C. Dhere, M. Gorgolewski. Compt. Rend. 150, 993-996, (1910). Sur I'obtention, par dialyse 61ectrique, d'un s^rum extrSmement appauvri en Electrolytes. 446. (H. C. Dibbits. Zeit. Analyt. Chem. 13, 137-146, (1874). Ueber die Loslichkeit des schwefelsauren Bleioxydes in Losungen von essig- saurem Natron.) H. Diesselhorst see F. Kohlrausch, L. Holbom. 447. O. Dimroth. Ann. Chemie. 335, 1-112, (1904). Ueber desmotrope Verbindungen. [See 653.] T = 25°and50°. R. O. 422 AUTHOR LIST 448. O. Dimroth. Ann. Chemie. 338, 143-182, (1905). (Afeas. H. StahU) Ueber desmotrope Verbindungen. T = 25. ° [Probably R. O., cf . 447. ] 449. C. Dittrich. Zeit. Phys. Chem. 29, 449-490, (1899). ■ Die Uranvlsalze vom physikalisch-chemischen Standpimkte aus betrachtet. T=25°. Hg. U. xaq. =2-3.2X10-5; sub. Meas. C. Dittrich; see 1029, 1673, 1674. 450. (H. Ditz. Chem. Ztg. 25, 1, 109-112, (1901). Ueber einige Reactionen des Kobalts und Eisens und den Einfluss der Alkohole und anderer organischer Stoffe auf die elektrolytische Dissociation der Salze in wasseriger Losung.) J. Dodt see J. Tafel. F. E. DoUfus see A. Hastzsch. "iMeas. Dongier; see 1108. Dongier see Lesage. 451. Dongier, Lesage. Compt. Rend. 134, 834-835, (1902). Valeurs de la r&istance 61ectrique, de I'indice de refraction et du pouvoir ro- tatoire de scrums sanguins normaux. [Corrected for typographical errors in Compt. Rend. 134, 932.] T = 16.7°- 452. (F. G. Donnan. Phil. Mag. (5), 45, 529-532, (1898). The Thomson effect in a binary electrolyte.) 453. (F. G. Donnan. Phil. Mag. (6), 3, 305-310, (1902). Condensation of the vapours of organic liquids in presence of dust-free air.) F. G. Donnan. Phil. Mag. 15, 305, is the preceding reference. 464. O. Dony-Henault. Bui. Acad. Belg. (1909), 342-409. Contribution k I'^tude m^thodique des oxydases. T=25°. Meas. A. Dom; quoted in 7. Doroschewsky gee Doroievskij. 465. A. G. Dorosevskij, M. S. Roidestvenskij. Jour. Russ. Phys.-chem. Soc. 40, 739-740, (1908). The electrical conductivity of mixtures of alcohol and water. [A summary of 456.] T = 15°andl8°. R. O. 466. A. G. Dorosevskij, M. S. Rozdestvenskij. Jour. Russ. Phys.-chem. Soc. 40, 887-908, (1908). The electrical conductivity of mixtures of alcohol and water. [A summary is given in 465. ] T = 15°andl8°- R. O. 466a. S. van Dorssen. Rec. Trav. Chim. 29, 368-393, (1910). Contribution \ la connaissance des acides nitro- et amidosulfobenzoiques. T=25°. R. O. 457. (J. M. Douglas. Dis. Johns Hopkins. (1901). The dissociation of certain acids, bases and salts at different temperatures.) [Same as 909.] J. M. Douglas see H. C. Jones. 458. Dreser. Zeit. Elektrochem. 10, 656-660, (1904). Die Gefrierpunkts- und Leitfahigkeitsbestimmung des Hams in einigen phar- makologischen Ergebnissen. 459. (K. Drucker. Zeit. Elektrochem. 13, 81-83, (1907). Beweglichkeit von lonen in Wasser.) AUTHOR LIST 423 460. K. Drucker. Zeit. Ptys. Chem. 49, 563-589, (1904). Messungen und Berechnungen von Gleichgewichten stark dissoziierter Sauren. T = 18°±0.05° R. O. Xi8aq. = 1.3X10-5; sub.; also gives data without sub. 461. K. Drucker. Zeit. Phys. Chem. 52, 641-704, (1905). Studien an wasserigen Losungen aliphatischer Sauren. [Same as 462.] T=0°and25°. R. O. X26 aq. = 1.7X10-«; sub. 462. K. Drucker. Habilitschr. Leipzig. (1905). Studien an wasserigen, etc. [Same as 461. ] Meas. K. Drucker; see 1979. K. Drucker see V. Rothmund. 463. M. Duboiix. Dis. Lausanne. (1908). Contribution h I'analyse physieo-chimique des vins. [See P. Dutoit, M. Duboux, Compt. Rend. 147, 134 and 351, (1908), for use of this method.] T=25°. R. O. M. Dubouz see P. Dutoit. 464. J. Duclaux. Zeit. Chem. Ind. KoUoid. 3, 126-134, (1908). Die Filtration koUoider Losimgen. [Contains a bibUography of measure- ments of the electrical conductivity of colloidal solutions to date. ] 466. A. DumaasM. Jour. Russ. Phys.-chem. Soc. 39, 1379-1391, (1907). The electrical conductivity of electrolytes in aqueous solutions of gelatin. [Same as 467 and 468.] T = 25°. 466. A. V. Dumanski. Jour. Russ. Phys.-chem. Soc. 41, 252-258, (1909). Mendelejeff number. Influence of colloids on the electrical conductivity of electrolytes. 467. A. Dumanski. Zeit. Chem. Ind. Kolloid. 2, Suppl. Heft . 1, 18-22, (1908). Ueber die Leitfahigkeit der Elektroljrte in wasserigen Losungen von Gelatine. [Same as 465 and 468.] T = 25°. 468. A. Dumanski. Zeit. Phys. Chem. 60, 553-562, (1907). Ueber die Leitfahigkeit der Elektrolyte in wasserigen Losungen von Gelatine. [Same as 465 and 467.] Dumanskij see Dtunanski. Dumansky see Dumanski. H. Duperthuis see P. Dutoit. 469. E. L. Durand. Dis. Geneve. (1902). Recherches experimentales sur la solubility des malonates aJcalino-terreux et BUT quelques constantes physico-chimiques de leurs solutions. T = 22° to 40°- R. 0. K aq. sub. 470. P. Dutoit. Jour. Chim. Phys. 1, 617-656, (1903). Conductibilit6, dissociation et propri6t6s des Electrolytes dans les dissolvants autres que I'eau. [Contains a full review of the literature to date. ] 471. P. Dutoit. Zeit. Elektrochem. 12, 642-644, (1906). Meas. Ottiker. Ueber molekulare Leitfahigkeit, Betrag und Gesetze der Dissociation organi- scher und unorganischer Losungsmittel. 472. P. Dutoit. Bui. Soc. Vaudoise. Compt. Rend. June (1906), I. Les conductibilit^s et les reactions des Electrolytes dans les dissociants autre que I'eau. 473. P. Dutoit. Bui. Soc. Vaudoise. Proc. Verb. 41, VI-XI, (1904- 1905). L'acide isosalicyUque. 424 AUTHOR LIST 474. P. Dutoit, E. Aston. Compt. Rend. 125, 240-243, (1897). Relation entre la polymerisation des corps liquides et leur pouvoir dissociaat BUT les electrolytes. T = 20°. 475. P. Dutoit, H. Demierre. Jour. Chim. Phys. 4, 565-575, (1906). Reactions ioniques dans Tac^tone. T usually 37.5°. S. U. 475a. P. Dutoit, M. Duboux. Bui. Soc. Vaudoise, (5), 45, 417-461, (1909). Quelques r&ultats de 1' analyse physico-chimique des vins. 476. P. Dutoit, M. Duboux. Bui. Soc. Vaudoise. Compt. Rend. (1908), IV. Determination des bases volatiles du vin. 477. P. Dutoit, M. Duboux. Bui. Soc. Vaudoise. Proc. Verb. 45, 43-44, (1908-1909). Acidite r^elle dans les vins. 478. P. Dutoit, H. Duperthuis. Jour. Chim. Phys. 6, 699-725, (1908). Meas. Gagnaux; Ottiker. Chaleurs de dissociation de quelques electrolytes dans des dissolvants orga^ niques. T=0''to80°. S. U. 479. (P. Dutoit, H. Duperthuis. Jour. Chim. Phys. 6, 726-731, (1908). Viscosites et conductibilites hmites.) 480. P. Dutoit, H. Duperthuis. Bui. Soc. Vaudoise. Compt. Rend. (1908), I. Relations qui existent entre les conductibilites limites et la viscosite. [Qual- itative. ] T = 0''to80°. 481. P. Dutoit, H. Duperthuis. Bui. Soc. Vaudoise. Compt. Rend. (1908), V. Conductibilites moieculaires limites. [Qualitative. ] T = 0°to80°. 482. P. Dutoit, L. Friderich. Bui. Soc. Chim. (3), 19, 321-337, (1898). Sur la conductibilite des electrolytes dans les dissolvants organiques. T=0°, 25°and50°. R. O. 483. P. Dutoit, L. Gagnaux. Arch. Sci. Phys. Nat. (4), 23, 213-214, (1907). Conductibilite de quelques electrolytes binaires dans I'ether acetylacetique, I'alcool isobutylique et I'alcool isoamylique. [Same as 484.] 484. P. Dutoit, L. Gagnaux. Bui. Soc. Vaudoise. Compt. Rend. (1906- 1907), III. Les conductibilites de quelques electrolytes binaires dans I'ether acetylacetique etc. [Same as 483. ] 485. P. Dutoit, E. Gyr. Jour. Chim. Phys. 7, 189-203, (1909). Conductivites eiectriques de solutions trSs diluees dans 1' anhydride sulfureux. [Same as 704. Abstracted in 486.] T=-15°. R. O. 486. P. Dutoit, E. Gyr. Bui. Soc. Vaudoise. Compt. Rend. April, (1906), I-II. Les conductibilites moMculaires limites dans I'anhydride sulfureux S, —5°. [Given in full in 485 and 704. ] 487. P. Dutoit, A. Levier. Jour. Chim. Phys. 3, 435-454, (1905). mMeas. Bern. Conductibilites limites de quelques electrolytes binaires dans I'acetone. T = 18°. S. U. 488. P. Dutoit, Ottiker. Arch. Sci. Phys. Nat. (4), 23, 215. (1907). Dissociation des electrolytes dans I'alcool propylique et la pyridine. [Same as 489. Qualitative. ] AUTHOR LIST 425 489. P. Dutoit, Ottiker. Bui. Soc. Vaudoise. Compt. Rend. (1906-1907), V. La dissociation des flectrolytes dans ralcool propylique et la pjTidine. [Same as 488.] 490. P. Dutoit, H. Rappeport. Arch. Sci. Phys. Nat. (4), 24, 417^18, (1907). Conductibilitfe limites de quelques sels dans I'alcool gthylique. [Given in 491 and 1470.] T = 18°. S. U. 491. P. Dutoit, H. Rappeport. Jour. Chim. Phys. 6, 545-551, (1908). Conductivites limites de quelques Electrolytes dans I'alcool 6thylique. [Given in 1470. Part is same as 490. ] T = 18°. S. U. E. G. W. Eastman see A. A. Noyes, A. C. Melcher, H. C. Cooper. 492. F. P. Ebersbach. Zeit. Phys. Chem. 11, 608-632, (1893). Ueber die Affinitatsgrossen aromatischer Amidosulfonsauren. T=25°. Meas. F. P. Ebersbach; see 504. O. Ecker see F. Straus. ESendi see Said-ESendi. 493. (H. E. Eggers. Jour. Phys. Chem. 8, 14-36, (1904). On the dielectric constants of solvents and solutions.) 494. R. Ehrenfeld. Zeit. Elektrochem. 9, 335-342, (1903). Meas. W. Storer. Ueber die Bildung von Wasserstoffionen aus den Methylengruppen der Bernsteinsaure, der Malonsaure und Glutarsaure. T = 20.3°. 495. R. Ehrenfeld. Zeit. Elektrochem. 10, 3-9, (1904). Ueber die Veranderung der spezifischen Leitfahigkeit von Salzlosungen durch AlkalHauge. T=20.3°. 496. F. H. Eijdman Fils. Rec. Trav. Chim. 25, 83-95, (1906). Sur la colorimetrie et sur une m^thode pour determiner la constante de dis- sociation des acides. [Same as 497.] 497. F. H. Eijdman Jr. Verslag Akad. Amsterdam. 14, 97-107, (1905- 1906). Verslag Akad. Amsterdam, English translation, 8, 166-175, 1905-1906). Over colorimetrie en over een colorimetrische methode om de dissociatie-con- stante van zuren te bepalen. [Same as 496. ] 498. (G. F. Emery. Proc. R. Soc. London. 55, 356-373, (1894). Thermo-electric properties of salt solutions.) 499. R. Emrich. Dis. Erlangen. (1902). Ueber die Einwirkung von Dichloressigsaure auf Anilin. [See 798 for correc- tion. The a- and /3- acids here should be interchanged. ] R. O. Meas. R. Emrich; see 798. C. Ende see L. W. Andrews. 500. A. Engler. Ber. Deutsch. Chem. Ges. 33, 2188-2190, (1900). Antidiazonaphtalinsalze und Naphtylnitrosamin. T = 0°. A. Engler see A. Hantzsch, M. Schumann. 426 AUTHOR LIST 501. A. Engler, A. Hantzsch. Ber. Deutsch. Chem. Ges. 33, 2147-2158, (1900). Diazoniumhydrate und Diazohydrate. [Corrected in 737. ] T=0°. 602. J. E. Enklaar. Rec. Trav. Chim. 24, 419-443, (1905). Nouvelles recherches sur I'action des bases sur I'hydrate de chloral. T=0.65°. R. O. Xo.66aq.=2.5 and2.4X10-«; not sub. 503. A. Eppens. Dis. Munchen. (1892). Meas. G. Bredig. Ueber das Campher-Phoron. [981 gives no numerical data.] A. Eppens see W. Koenigs. 504. H. Erdmann. Ann. Chemie. 275, 184-309, (1893). Meas. F. P. Ebersbach. AUgemeines iiber Scheidung und Constitution der isomeren Naphtalinver- bindungen. 505. (T. Erhard. Chem. Ztg. 23, I, 283-284, (1899). Verdiinnte Losungen und elektrolyt. Dissociation.) 606. (T. Erhard. Chem. Ztg. 23, I, 285-287, (1899). Verdiinnte Losungen und elektrolyt. Dissociation.) 507. E. Erlenmeyer. Ber. Deutsch. Chem. Ges. 42, 2655-2675, (1909). Meas. K. Bube. Die Abhangigkeit der Unterschiede bei den Zimtsauren von dem Ausgangs- material. T = 25.00° ±0.04°. O. Erler see H. Ley. 507a. G. D'Errico. Arch. Fisiol. 8, 177-186, (1910). Influenza dell'inanizione e dell'ingestione di sostanze non elettroliti suUa pressione osmotica e la conduttivit^ elettrica del sangue. T = 37.2°. D'Errico see F. Bottazzi. 508. (J. A. Erskine. Ann. Physik. (3), 62, 454-459, (1897). Ueber das electrische Leitungsvermogen der Electrolyte filr sehr schnelle electrische Schwingungen). [Inorganic] 609. A. Esmann. Dis. Leipzig. (1905). Zwei stereoisomere Butentricarbonsauren aus Natriummalonsaureester und den beiden o-Bromcrotonsaureestem. T = 25°. S. U. A. Euler see H. Euler. 510. H. Euler. Ber. Deutsch. Chem. Ges. 36, 1854-1860, (1903). Ueber Silberammoniakbasen und Silbercyanwasserstoffsaure. T = 18°. R. O. 511. H. Euler. Ber. Deutsch. Chem. Ges. 37, 2768-2773, (1904). Ueber ComplexbUdung. II. Pyridincomplexe. T = 18°. 512. H. Euler. Ber. Deutsch. Chem. Ges. 39, 344-350, (1906). Die Aldehyde als Sauren. T=0°to 18°. 513. H. Euler. Ber. Deutsch. Chem. Ges. 39, 1607-1615, (1906). Zur Kenntniss der Pseudosauren. [Same as 521.] T = l°, 10° and 18°. 514. (H. Euler. Ber. Deutsch. Chem. Ges. 39, 2265-2269, (1906). Ueber Pseudosauren. Antwort auf Hrn. Hantzsch' Kritik.) 514a. H. Euler. Ergebn. Physiol. 9, 241-333, (1910). Die chemische Dynamik der Enzymreaktionen. [Quotes J. Sjoqvist.] AUTHOR LIST 427 515. H. Euler. Zeit. Phys. Chem. 21, 257-271, (1896). Ueber die Abhangigkeit des Dissociationsgrades einiger Sauren von der Tem- peratur und uber ihre Dissociationswarme. T=0° to 50°. X aq. not sub. 516. (H. Euler. Zeit. Phys. Chem. 25, 536-542, (1898). Ueber die innere Reibung elektrolytischer Losungen.) 517. H. Euler. Zeit. Phys. Chem. 28, 619-628, (1899). Ueber den Zusammenhang zwischen der dissooiierenden Kraft, der Dielek- trizitatskonstanten imd der molekularen Beschaffenheit von Flussigkeiten. [Qualitative. ] 518. (H. Euler. Zeit. Phys. Chem. 29, 603-612, (1899). Dissociationsgleichgewicht starker Elektrolyte.) [Inorganic] 519. H. Euler. Zeit. Physiol. Chem. 51, 213-225, (1907). Fermentative Spaltung von Dipeptiden. [Part is same as 622 and 523, ] T = 18° and 25°. 520. H. Euler. Arkiv Kemi. 1, 77-91, (1903-1904). Ueber Ammoniak und Metallammoniakbasen I. [Inorganic.] 521. H. Euler. Arkiv Kemi. 2, no. 22, 1-13, (1905-1907). Zur Kenntnis der Pseudosauren. (Same as 513. ] 622. H. Euler. Arkiv Kemi. 2, no. 31, 1-10, (1905-1907). Fermentative Spaltung von Dipeptiden. [Part is same as 519. ] T = 18°and25°. 523. H. Euler. Arkiv Kemi. 2, no. 39, 1-13, (1905-1907). Zur Kenntnis der alkalischen Verdauung. [Part is same as 519.] T = 18°and37°. 524. H. Euler, I. Bolin. Zeit. Phys. Chem. 66, 71-77, (1909). j^Meas. H. Inindin. Ueber die Dissociationskonstanten der Dioxybenzole. T = 0°andl8°. xis aq. = 1.6X10-«; sub. 525. H. Euler, I. Bolin. Zeit. Phys. Chem. 69, 187-202, (1909). Ueber die cfiemische Zusammensetzung und die biologische RoUe einer Oxy- dase. T= 17°. xi7. 5 aq.= 1.8X10-". 526. H. Euler, A. Euler. Ber. Deutsch. Chem. Ges. 36, 4246-4253, (1903). Ueber die Einwirkung von Amylnitrit auf ;3-Aminocrotonsaureester. 527. H. Euler, A. Euler. Ber. Deutsch. Chem. Ges. 36, 4253-4256, (1903). Ueber die BUdung hydrirter Osotriazole. [See 530 for full measurement. Only k is given here, no A.] 528. H. Euler, A. Euler. Ber. Deutsch. Chem. Ges. 38, 2551-2560, (1905). Zur Kenntniss des Formaldehyds und Formiatbildung. [See 529 and 58.] T=0°. 529. H. Euler, A. Euler. Ber. Deutsch. Chem. Ges. 39, 36-39, (1906). Nachtrag zu unserer Mittheilung uber Formaldehyd und Formiatbildung. 530. H. Euler, A. Euler. Arkiv Kemi. 1, 111-126, (1903-1904). Ueber die Bildung von aliphatischen Isonitrosoverbindungen und Osotriazolen aus |8-Amino-Crotonsaureester. [627 gives k without tables of A.] T = 18° and 21.5°. 531. H. Euler, A. Hantzsch. Ber. Deutsch. Chem. Ges. 34, 4166-4169, (1901). Ueber ein festes Diazoniumcyanid und uber Diazojodide. T = 18°. 428 AUTHOR LIST 532. H. Euler, B. af Ugglas. Zeit. Phys. Chem. 68, 498-510, (1909). Hydrolyse und Reaktionsgesohwindigkeit in wasserig-alkoholische Losungen. [Same as 533. ] T=-50° to +30°. 533. H. Euler, B. af Ugglas. Arkiv Kemi. 3, no. 21, 1-14, (1908-1910). Hydrolyse, etc. [Same as 532.] 534. P. Eversheim. Ann. Physik. (4), 8, 539-567, (1902). Bestimmung der Leitfahigkeit und Dielektricitatsconstanten von Losungs- mitteln und deren Losungen in ilirer Abhangigkeit von der Temperatur bis uber den kritischen Punkt. [Same as 537.] T=20'' to 196°. 535. P. Eversheim. Ann. Physik. (4), 13, 492-511, (1904). Verhalten von Leitfahigkeit und Dielektrizitatskonstanten einiger Substanzen vor und in dem kritischen Zustand. 536. P. Eversheim. Phys. Zeit. 4, 503-507, (1902-1903). Leitfahigkeit und Dielektrizitatskonstante von Losungen und Losungsmittel im kritischen Zustande. 637. P. Eversheim. Dis. Bonn. (1902). Bestimmung der Leitfahigkeit, etc. [Same as 534.] E. Evieux see L. Vignon. 538. T. Ewan. Jour. Chem. Soc. 69, 96-97, (1896). Note on the electrolytic conductivity of formanilide and thioformanilide. T = 25°. S. U. 539. (T. Ewan. Proc. Chem. Soc. 12, 8, (1896). Note on the electrolytic conductivity of formanilide and thioformanilide.) [Qualitative. ] 540. T. Ewan. Proc. R. Soc. London. 57, 117-161, (1894-1895). Meas. van't Hoff. On the absorption spectra of dilute solutions. T = 14.1°. Meas. T. Ewan; see 413, 1411. Eydman see Eijdman. 541. J. F. Eykman. Ber. Deutsch. Chem. Ges. 24, 1278-1303, (1891). Ueber die Shikimisaure. T = 9° to 19°. Meas. J. F. Eykmann; see 838. 542. I. Fanjung. Zeit. Phys. Chem. 14, 673-700, (1894). Ueber den Einfluss des Druckes auf die Leitfahigkeit von Elektrolyten. T = 14°tol9°. X aq. sub. for salts. 543. G. Farkas. Arch. Gesammt. Physiol. 98, 551-576, (1903). Ueber die Concentration der Hydroxylionen in Blutserum. T = 19°to22°. 544. G. Farkas, E. Scipiades. Arch. Gesammt. Physiol. 98, 577-587, (1903). Ueber die molekularen Concentrationsverhaltnisse des Blutserums der Schwan- geren, Kreissenden und Wochnerinnen und des Fruchtwassers. T = 18°. R. O. 545. R. C. Farmer. Jour. Chem. Soc. 79, 863-870, (1901). A new method for the determination of hydrolytic dissociation. T=25°. R. C. Farmer see P. F. Frankland. AUTHOR LIST 429 646. R. C. Fanner, A. Hantzsch. Ber. Deutsch. Chem. Ges. 32, 3089-3101, (1899). Die Constitution der sogen. Oxyazokorper. T=25°. 547. R. C. Farmer, A. Hantzsch. Ber. Deutsch. Chem. Ges. 32, 3101-3109, (1899). a-Gximidoketone und Chinonoxime als Pseudosauren. T = 25°. 548. R. C. Farmer, F. J. Warth. Jour. Chem. Soc. 85, 1713-1726, (1904). The affinity constants of aniline and its derivatives. T= 6° and 25°. 549. (R. C. Fanner, F. J. Warth. Proc. Chem. Soc. 20, 244, (1904). The affinity constants of aniline and its derivatives.) [Only comparative. No data.] 550. F. Fassbender. (A. Werner.) Zeit.Anorg. Chem. 15, 123-142, (1897). Beitrag zur Konstitution anorganischer Verbindungen. VIII. Mitteilung. Ueber die Anderson'sche Reaktion. [Same as 551.] 551. F. Fassbender. Dis. Zurich. (1896). Untersuchungen viber die Anderson'sche Reaction und iiber die isomeren Platosoxalsauren. [Same as 550. ] 552. C. E. Fawsitt. Zeit. Phys. Chem. 41, 601-629, (1902). Die Zersetzung des Harnstoffs. [Same as 555. ] T = 99.2° for part. R. O. x aq. = 1.8-2.1Xl0-«; sub. 553. C. E. Fawsitt. Zeit. Phys. Chem. 48, 585-592, (1904). Phyaikalisch-chemische Untersuchungen in der Amidgruppe. [Same as 554.] T = 25° and 34.2°. 554. C. E. Fawsitt. Proc. R. Soc. Edinburgh. 25, I, 51-60, (1903-1905). Physico-chemical investigations in the amide group. [Same as 553.] 555. C. E. Fawsitt. Dis. Leipzig. (1902). Die Zersetzung des Harnstoffs. [Same as 552.] 556. A. Fedorov. Jour. Russ. Phys.-chem. Soc. 35, 651-652, (1903). Ab- stracted in Beibl. Ann. Physik. 28, 969, (1904). Electrical conductivity of solutions of oxalic acid in the presence of neutral salts. 557. F. Feist. Ann. Chemie. 257, 253-297, (1980). Meas. G. Magnanini. Ueber Dehydracetsaure. 658. F. Feist. Ber. Deutsch. Chem. Ges. 25, 315-335, (1892). Meas. Barth. Ueber neue S}Tithesen mittelst Dehydracetsaure. 559. F. Feist. Ber. Deutsch. Chem. Ges. 26, 747-764, (1893). Meas. A. Miolati. Ueber den Abbau des Cumalinringes. 560. (B. Fels. Zeit. Elektrochem. 10, 208-214, (1904). Studien iiber die Indikatoren der Acidimetrie und Alkalimetrie.) 561. (H. J. H. Fenton, H. O. Jones. Jour. Chem. Soc. 79, 91-101, (1901). Relationships of oxalacetic acid.) [Qualitative. Same as 562. See correction in 926 and 927.] 562. (H. J. H. Fenton, H. O. Jones. Proc. Chem. Soc. 16, 205, (1900). Relationships of oxalacetic acid.) [Same as 561.] 663. (H. J. H. Fenton, H. O. Jones. Proc. Chem. Soc. 17, 24^26, (1901). Note on a method for comparing the affinity values of acids.) [Continuation of 662. See also 925 and 927.] 564. F. Fichter. Verhand. Naturf. Ges. Basel. 16, 245-298, (1903). Ueber ungesattigte Sauren. [A summary of 665, 568 and 571.] 430 AUTHOR LIST B64a. F. Fichter. Arch. Sci. Phys. Nat. (4), 27, 409-410, (1909). Constantes d'affinitfi des acides bibasiques non satur^s. [Given with tables of A in 571a.] 565. F. Fichter, A. Beisswenger. Ber. Deutsch. Chem. Ges. 36, 1200-1205, (1903). Die Reduction des Glutarsaureanhydrids zum S-Valerolacton. T=25°. R. O. 666. F. Fichter, E. Gisiger. Ber. Deutsch. Chem. Ges. 42, 4707-4710, (1909). Ueber /3-Methyl-pentensauren. [Same as 642 for acids, k is given in 669. No salts are given here. ] T = 25°. R. O. ;>i25aq. =3.5X10-". 667. F. Fichter, W. Latzko. Jour. Prakt. Chem. (2), 74, 327-332, (1906). Studien an ungesattigten Sauren. Div. VII. Ueber Diphenylvinylessigsaure. [Latzko's name appears only under Div. VII. See 1058 for full tables of A and k. Only k is given here. ] T=25°. 568. F. Fichter, B. Miihlhauser. Ber. Deutsch. Chem. Ges. 35, 341, (1902). Messungen an der o-Aethylidenglutarsaure. [Same as 1291 for k; no tables of A are given here. ] T = 25°. R. O.; also S. U. for sodium salt. 669. F. Fichter, H. Miiller. Ann. Chemie. 348, 256-259, (1906). Meas. E. Gisiger, and H. Obladen. Affinitatsmessungen an einbasischen ungesattigten Pettsauren. [For tables of A and k see 666 and 570. Same as 1292. ] T = 25°. R. O. JC25aq.=3.5X10-«. 670. F. Fichter, H. Obladen. Ber. Deutsch. Chem. Ges. 42, 4703-4707, (1909). Ueber a-Aethyl-pentensauren und uber Xeronsaureanhydrid. [Same as 1347. Only k is given in 569.] T = 25°. R. O. xaq. =3.5X10-8. 571. F. Fichter, A. Pfister. Ann. Chemie. 334, 201-210, (1904). gMeas. E. Fiieg and E. Rudin. Leitfahigkeitsmessungen an ungesattigten Sauren. [Part is same as 622. ] T = 25°- R. O. 671a. F. Fichter, H. Probst. Ann. Chemie. 372, 69-79, (1910). Leitfahigkeitsmessungen an zweibasischen, ungesattigten structurisomeren Sauren. [k only, is given in 564a.] T = 25°. 572. F. Fichter, J. Schwab. Ann. Chemie. 348, 251-266, (1906). Ueber /3-Methylglutaconsauren. [Same as 1603.] T = 25°. R. O. xaq.=3X10-''. 573. F. Fichter, F. Sonnebom. Ber. Deutsch. Chem. Ges. 35, 938-943, (1902). Ueber Vinylessigsaure. [Given with full tables of A in 1640. ] T = 25°. R. O. D. Filippi see R. Luzzatto. 574. A. Findlay, W. E. S. Turner, G. E. Owen. Jour. Chem. Soc. 95, 938- 942, (1909). AflBnity constants of hydroxy- and alkyloxy-acids. [k, but no A, is given in £75.] T=25°. AUTHOR LIST 431 676. A. Findlay, W. E. S. Turner, G. E. Owen. Proc. Chem. Soc. 25, 146, (1909). The affinity constants of hydroxy- and alkyloxy- acids. [Given ia 574.] T = 25°. 676. (J. Fink. Ann. Physik. (3), 26, 481-517, (1885). Ueber den Einfluss des Druckes auf den electrischen Leitungswiderstand von Electrolyten.) [Inorganic] 577. C. Fiorini. Gaz. Chim. Ital. 31, I, 33-39, (1901). Sugli spettri di assorbimento degli acidi cloranilico, bromanilico e dei loro sali alcalini. [Quoted in 389. ] 578. W. M. Fischer. Zeit. Phys. Chem. 65, 61-69, (1908-1909). Ueber die Kinetik der Bildung und Verseifung von Salpetrigsaureestern. Meas. W. Fischer; see 764. 579. R. Fittig. Ann. Chemie. 330, 292-361, (1904). Meas. P. Jehl. Ueber Umlagerungen bei den ungesattigten Saure. [Same as 885. ] T=20°. R. O. 580. T. C. Fitzpatrick. PhU. Mag. (5), 24, 377-391, (1887). On the action of the solvent in electrolytic conduction. T varies; usually 15° to 18°. U = legal ohm. Meas. Flaschner; see 1246, 1247. J. A. Fleming see J. Dewar. 581. J. A. Fleming, J. Dewar. Proc. R. Soc. London. 61, 299-316, (1897). On the dielectric constants of certain frozen electrolytes at and above the temperature of Uquid air. ' 682. J. A. Fleming, J. Dewar. Proc. R. Soc. London. 61, 316-330, (1897). On the dielectric constants of pure ice, glycerine, nitrobenzol and ethylene dibromide at and above the temperature of liquid air. 583. B. Fliirscheim. Jour. Chem. Soc. 95, 718-734, (1909). The relation between the strength of acids and bases and the quantitative distribution of affinity in the molecule. T = 17°and25°- 584. B. Fliirscheim. Jour. Chem. Soc. 97, 84r-97, (1910). The relation between the strengths of acids and bases, and the quantitative distribution of affinity in the molecule. [m-Toluidine is given qualitatively in 686.] T = 25°. Kw = l. 18X10-". 586. (B. Fliirscheim. Proc. Chem. Soc. 25, 22-23, (1909). The relation between the strength of acids and bases and the quantitative distribution of affinity in the molecule.) 586. B. Fliirscheim. Proc. Chem. Soc. 25, 193-194, (1909). The relation between, etc. [Given in 684.] 587. C. Foa. Arch. Pisiol. 3, 369-415, (1906). La reazione dei liquidi dell'organismo determinata col metodo elettrometrico (pile di concentrazione). 688. A. Fock. Zeit. Ver. Rubenzuck. Ind. (1889), 710. Abstracted in Zeit. Analyt. Chem. 29, 35-56, (1890). Die Anwendung des elektrischen Leitungsvermogens zu quantitative Bestim- mung. T=25°. S. U. ;;i aq.= 6.-37 X 10-'- Meas. Foote; see 1661, 1664. 589. (H. W. Foote, N. A. Martin. Am. Chem. Jour. 41, 453-457, (1909). On the molecular condition of salts dissolved in a fused salt. II. The electrical conductivity of salts in fused mercuric chloride.) 432 AUTHOR LIST 590. J. S. Ford, J. M. Guthrie. Jour. Chem. Soc. 89, 76-92, (1906). The influence of certain amphoteric electrolytes on amylolytic action. T = 25°. R. O. xaq. = 1 — 1.5X10-"; not sub.; given only for one meas- urement. P. V. d. Forst see H. Grosstaann. 691. W. Foster. Phys. Rev. 8, 257-281, (1899). The conductivity and dissociation of some electrolytes. T = 18°. S. U. and R. O. Xia aq. is about lXlO-«. 592. E. Fouard. Bui. Soc. Chim. (4), 3, 836-840, (1908). Sur les propri6t6s coUoidales de I'amidon. [Given iu 595.] 593. E. Fouard. Bui. Soc. Chim. (4), 5, 828-834, (1909). La solubUisation de I'amidon colloidal sous I'action des alcalis. T = 30°. 594. E. Fouard. Compt. Rend. 144, 1366-1368, (1907). Sur les propri^t^s coUoidales de I'amidon. 595. E. Fouard. Compt. Rend. 146, 978-981, (1908). Sur les propri^t^s de I'amidon en rapport avec sa forme coUoidale. [Gives more details of measurements than 592. ] T = 25°. xaq.= 2.785 XlO-«. 596. (G. Foussereau. Ann. Chim. Phys. (6), 15, 533-544, (1888). Sur la decomposition des hyposuliites par les acides.) [Inorganic] 597. G. Foussereau. Jour. Phys. (2), 4, 450-456, (1885). Sur la resistance eiectrique de I'alcool. T = 15°- 598. (W. Fraenkel. Zeit. Phys. Chem. 60, 202-236, (1907). Zur ohemischen Kinetik des Diazoessigester.) W. Fraenkel see G. Bredig. 599. L. Fraacesconi, A. Milesi. Gaz. Chun. Ital. 32, 1, 425-436, (1902). Sulla formazione della cetossima. [T apparently is 11°.] Meas. E. FranciUon; see 1401. 600. R. T. Frank. Am. Jour. Physiol. 14, 466-468, (1905). A note on the electric conductivity of blood during coagulation. 601. E. Franke. Zeit. Phys. Chem. 16, 463-492, (1895). Beitrage zur elektrischen Leitfahigkeit von Salzen und Sauren in wassriger Losung. T= 25°. Hg. U. xaq.=2-3XlO-«; sub. Meas. E. Franke; see 1212. 602. P. F. Frankland, R. C. Fanner. Jour. Chem. Soc. 79, 1356-1373, (1901). Liquid nitrogen peroxide as a solvent. T = 0°. 603. (P. F. Frankland, R. C. Farmer. Proc. Chem. Soc. 17, 201, (1901). Liquid nitrogen peroxide as a solvent.) [Qualitative.] 604. E. C. Franklin. Zeit. Phys. Chem. 69, 272-303, (1909). The electrical conductivity of liquid ammonia solutions. III. T=-44° to -33°. R. O. 605. E. C. Franklin, H. D. Gibbs. Jour. Am. Chem. Soc. 29, 1389-1396, (1907). The electrical conductivity of methylamine solutions. [T is probably 20.3°.] R. O. 606. E. C. Franklin, C. A. Kraus. Am. Chem. Jour. 20, 820-836, (1898). Liquid ammonia as a solvent. [Qualitative.] AUTHOR LIST 433 607. E. C. Franklin, C. A. Kraus. Am. Chem. Jour. 23, 277-313, (1900). The electrical conductivity of liquid ammonia solutions. [The measure- ments are given in abridged form in 612.] T=-38°. R. O. 608. The reference under this number has been omitted intentionally. 609. E. C. Franklin, C. A. Kraus. Am. Chem. Jour. 24, 83-93, (1900). The conductivity temperature coefficient of some liquid ammonia solutions. T = 23°to363°. 610. E. C. Franklin, C. A. Kraus. Jour. Am. Chem. Soc. 27, 191-222, (1905). The electrical conductivity of liquid ammonia solutions. T=-33°. R. O. 611. (E. C. Franklin, C. A. Kraus. Proc. Am. Ass. Advanc. Sci. 47, 215- 217, (1898). Some properties of liqmd ammonia.) [An abstract. No data.] 612. E. C. Franklin, C. A. Kraus. Proc. Am. Ass. Advanc. Sci. 48, 157-159, (1899). The electrical conductivity, etc. [Given in 607.] 613. (W. S. Franklin, L. A. Freudenberger. Phys. Rev. 25, 294-302, (1907). Measurement of electrolytic resistance.) [Inorganic] 614. J. C. W. Frazer. Am. Chem. Jour. 30, 309-323, (1903). On relations between the color and the composition and constitution of the alkali salts of the nitrophenols. [Same as 616. ] T = 25°. 615. J. C. W. Frazer. Dis. Johns Hopkins. (1901). On the relations between, etc. [Same as 614. ] 616. (C. Fredenhagen. Ann. Physik. (4), 17, 285-331, (1905). Entwurf einer allgemeinen Theorie elektrolytischer Losungskonstanten und Spannungsreihen, sowie der L6.slichkeit und Dissoziation von Sauren und Basen.) 617. P. C. Freer, A. M. Clover. Am. Chem. Jour. 25, 390-413, (1901). On the constituents of Jamaica dogwood. T = 25°. 617a. W. Frei. Zeit. Chem. Ind. Kolloide. 6, 94^103, (1910). Ueber Leitungshemmung durch Kolloide nebst Bemerkungen zum Serumleit- vermogen. T=35°. L. A. Freudenberger see W. S. Franklin. L. Friderich see P. Dutoit. 618. (H. Friedenthal. Zeit. Elektrochem. 10, 113-119, (1904). Die Bestimmung der Reaktion einer Fltissigkeit mit Hilfe von Indikatoren.) [Quoted. ] H. Friedenthal see A. Auerbach. " " see E. Salm. 619. J. Friediander. Zeit. Phys. Chem. 38, 385-440, (1901). Ueber merkwiirdige Erscheinungen in der Umgebung des kritischen Punktes teilweise mischbarer Fliissigkeiten. [Same as 620. ] T = 17°to43°. R. O. 620. J. Friediander. Dis. Leipzig. (1901). Ueber merkwurdige Erscheinungen etc. [Same as 619. ] 621. A.Fuchs. Verb. Ges. Deutsch. Naturf. Aerzte. 76, 11,2, 292, (1904). Untersuchungen des Liquor cerebrospinalis, mit spezieller Berucksichtigung der Chemie desselben. Meas. E. Fueg; see 571. 434 AUTHOR LIST 622. G. Fueg. Dis. Basel. (1904). I. Ueber l-Phenyl-3-methyl-5-pyrazolidon-3-carbonsaure. II. Ueber o-Methyl- 75-pentensaure. [This is the same Fueg as in 671, and the same measm'ement.] T=26°. Meas. L. Gagnaiiz; see 478. L. Gagnatiz see P. Dutoit. Meas. R. D. Gale; see 1338. 622a. G. Galeotti. Arch. Fisiol. 7, 413-420, (1909). Sui fenomeni elettrici della mucosa stomacale della rana. T = 12°to 14°. 623. G. Galeotti. Zeit. Biol. 43, 289-340, (1902). Ueber die elektrische Leitfahigkeit der tierischen Gewebe. T = 12°to38°. 624. G. Galeotti. Zeit. Biol. 45, 65-78, (1904). Neue Untersuchimgen uber die elektrische Leitfahigkeit und den osmotischen Druck der tierischen Gewebe. T = 18°. 625. A. Gamgee. Chem. News. 85, 145-147, (1902). On certain chemical and physical properties of haemoglobin. [Same as 626.] T=0°to39°. R. O. xaq. not over 2.5X10-'*. 626. A. Gamgee. Proc. R. Soc. London. 70, 79-83, (1902). On certain chemical, etc. [Same as 625.] 626a. E. Gardella. Arch. Fisiol. 8, 408-420, (1910). Le costanti fisico-chimiche del siero di sangue di cane dopo I'ablazione dell'ap- parato tiro-paratiroideo. T = 25°. 627. (J. A. Gardiner. Proc. Trans. R. Soc. Canada. (3), 2, Sect. Ill, 37-62, (1908). On the conductivity of mixtures of dilute solutions.) [Inorganic] 628. (D. D. Gardner, D. G. Gerassimoff. Jour. Russ. Phys.-chem. Soc. 36, 605, (1904). On the determination of the solubility of salts of weak acids by the measure- ment of the electrical conductivity.) [An abstract of 629 and 630.] 629. (D. D. Gardner, D. G. Gerassimoff. Jour. Russ. Phys.-chem. Soc. 36, 746-753, (1904). On the determination of the solubility of salts of weak acids by the measure- ment of the electrical conductivity.) [Same as 630. Inorganic] 630. (D. D. Gardner, D. Gerassimoff. Zeit. Phys. Chem. 48, 359-364, (1904). Ueber die Bestimmung der Loslichkeit von Salzen schwacher Sauren durch Messung der Leitfahigkeit.) [Same as 629.] 631. F. GarelU. Rend. Soc. Chim. Roma. 1, 74-80, (1903). Dissociazione elettrolitica in soluzioni acquose e in solventi organici ed inor- ganici. 632. (A. E. Garrett. Proc. Phys. Soc. London. 20, 584-606, (1905- 1907). Electrical conductivity produced by heating salts.) [Inorganic] 633. (A. E. Garrett, R. S. WiUows. Phil. Mag. (6), 8, 437-454, (1904). Chemical dissociation and electrical conductivity.) [Same as 634. Inorganic. ] AUTHOR LIST 435 634. (A. E. Garrett, R. S. WiUows. Proc. Phys. Soc. London. 19, 325-342, (1903-1905). Chemical dissociation, etc.) [Same as 633]. V. Garuti see L. Pelet. Garz6n see Carmona. 634a. W. W. H. Gee, F. Brotherton. Mem. Proc. Manchester Lit. Phil. Soc. 54, Mem. 13, (1909-1910). The electrical resistance of the human body. 634b. (W. W. H. Gee, W. Harrison. Trans. Faraday Soc. 6, 42-62, (1910). The electrical theory of dyeing.) A. Generosow see N. Zelinsky. Gerasimov see Gerassimoff. D. G. Gerassimoff see D. D. Gardner. 635. D. Gerilowski, A. Hantzsch. Bar. Deutsch. Chem. Ges. 29, 743-755, (1896). Weiteres iiber die stereoisomeren Salze aus Diazosulfanilsaure. T=0°. 636. P. Gerlinger. Ber. Deutsch. Chem. Ges. 37, 3958-3963, (1904). Zur Umlagerung echter Farbbasen in Carbinolbasen und echter Farbstoff- cyanide in Leukocyanide. [Correction of 770.] F. H. Getman see H. C. Jones. 637. H. D. Gibbs. Jour. Am. Chem. Soc. 28, 1396-1422, (1906). Liquid methylamine as a solvent, and a study of its chemical reactivity. [Qualitative. ] H. D. Gibbs see E. C. Franklin. 638. (J. Gibson. Proc. R. Soc. Edinburgh. 26, 234-237, (1905-1906). Preliminary note on the conductivity of concentrated aqueous solutions of electrolytes.) 639. (J. Gibson. Trans. R. Soc. Edinburgh. 45, 241-259, (1905- 1907). On the relationship between concentration and electrolytic conductivity in concentrated aqueous solutions.) [Quoted.] 640. A. Giliaov. Jour. Russ. Phys.-chem. Soc. 28, 501-509, (1896). Synthesis of tertiary trimethylethylene lactic acid. T = 25°. 641. Gin, Leieux. Compt. Rend. 120, 917-920, (1895). Sur la resistance ^lectrique des Hquides sucr6s. O. Girard see H. Goldschmidt. 642. E. Gisiger. Dis. Basel. (1905). Ueber ;3-Methyl-|37-pentensaure und jS-Methyl-a/J-pentensaure. II. Ueber TolUsaure. [Same as 566 for acids, but sodium salt is also given here. Same as part of 569 for k, but also gives A.] T = 25°. R. O. X25aq.=3.5XlO-«. Meas. E. Gisiger; see 669. E. Gisiger see F. Fichter. 643. E. Glimm. Dis. Freiburg. (1902). Ueber die Constitution Formaldehydschwefligsaurer Salze. II. Ueber die Affinitatsgrosse aromatischer Oxyaldehyde. [The values for the hydroxy-alde- hydes are probably too high. Cf. 1397c.] T = 25° X aq. sub. A. Glogau see R. Wegscheider. 436 AUTHOR LIST 644. W. H. Glover. Dis. Leipzig. (1905). Ueber die Korperiarbe von Chinon- und Ketonderivaten sowie von Oxyazo- korpern. [Same as 758. ] Meas. W. H. Glover; see 758. W. H. Glover see A. Hantzsch. 645. R. Gnehm, T. Scheutz. Jour. Prakt. Chem. (2), 63, 405-427, (1901). Ueber alkylirte Amidobenzolsulfosauren und Metamidophenole. [Same as 1585.] 646. T. Gnesotto. Atti 1st. Veneto. 59, II, 987-1006, (1899-1900). Considerazioni e ricerche intorno alia anomalia della resistenza elettrica delle soluzioni acquose in prossimit^ dei 4°. T = 0.16° to7.43°. 647. T. Godlewski. Jour. Chim. Phys. 3, 393^34, (1905). Sur la dissociation des electrolytes dans les solutions alcooliques. [Same as 648.] T = 18°±0.1°. R. O. X of alcohol not sub. except for acetic acid. 648. T. Godlewski. Bui. Acad. Cracov. (1904), 239-276. Sur la dissociation des Electrolytes dans les solutions alcooliques. [Same as 647. Abstracted in Zeit. Phys. Chem. 51, 751, and Zeit. Elektrochem, 11, 121. ] 648a. (J. B. Goebel. Zeit. Phys. Chem. 71, 652-666, (1910). Ueber einige Beziehungen zwischen den Gefrierpunktsemiedrigungen, lonen- konzentrationen und Leitfahigkeiten der Elektrolyte.) A. Gortz see E. Lellmann. E. G. Goldberg see A. W. Speranskij. 649. F. Goldschmidt. Phys. Zeit. 1, 287-289, (1899-1900). Ueber das Leitvermogen wassriger Ammoniaklosungen. 650. F. Goldschmidt. Zeit. Anorg. Chem. 28, 97-139, (1901). Physikalisch-chemische Studien an wasserigen Ammoniaklosungen. [Same as 662.] T = 25°±0.05°. ?<:aq.= 3.5X10-"; not sub. 651. (F. Goldschmidt. Zeit. Elektrochem. 10, 221-222, (1904). Zur Theorie der Verseifung.) 652. F. Goldschmidt. Dis. Breslau. (1901). Physikalisch-chemische Studien, etc. [Same as 660.] 653. (H. Goldschmidt. Zeit. Elektrochem. 11, 5-7, (1905). Ueber Desmotrope Verbindungen.) [An analysis of 447.] 664. H. Goldschmidt. Zeit. Elektrochem. 15, 5-10, (1909). Meas. Udhy. Untersuchungen uber Esterbildung. T = 25°. 655. H. Goldschmidt. Zeit. Phys. Chem. 17, 145-163, (1895). Die molekulare Loslichkeitserhohung. T = 23.7°to50.1°. 666. H. Goldschmidt. Zeit. Phys. Chem. 25, 91-99, (1898). Meas. G. v. Maarseveen. Ueber die Beziehung zwischen Losungswarme, Loslichkeit und Dissociations- grad. [Same as 1161.] T = 25°. 656a. H. Goldschmidt. Zeit. Phys. Chem. 70, 627-643, (1910). Ueber Esterbildung mit schwachen Sauren als Katalysatoren. T=25°. 657. H. Goldschmidt, E. Biirkle. Ber. Deutsch. Chem. Ges. 32, 355-378, (1899). Meas. W. Bernays. Djmamische Untersuchungen iiber die Bildung der Azofarbstoffe. AUTHOR LIST 437 658. (H. Goldschmidt, O. Giraid. Ber. Deutsch. Chem. Ges. 29, 1224- 1242, (1896). Kryoskopische Versuche mit Phenolsalzen.) 659. H. Goldschmidt, K. Ingebrechtsen. Zeit. Phys. Chem. 48, 435-466, (1904). Ueber die Reduktion von Nitrokorpern durch Zinnhalogeniire. 660. H. Goldschmidt, H. KeUer. Ber. Deutsch. Chem. Ges. 35, 3534-3549, (1902). HMeas.M. Mundler. Dynamische Untersuchungen tiber die Bildung der Azofarbstoffe. [Part is given in 957; part in 1293.] 660a. H. Goldschmidt, H. Larsen. Zeit. Phys. Chem. 71, 437-512, (1910). Die Reduktion der Nitrogruppe durch Schwefelwasserstoff. Ein Beitrag zur Kenntnis der Katalyse. T=2S°. 661. H. Goldschmidt, L. Oslan. Ber. Deutsch. Chem. Ges. 32, 3390-3399, (1899). Zur Kenntniss des Acetessigesters. [Same as 1366 for 25°.] T=25°. 662. H. Goldschmidt, L. Oslan. Ber. Deutsch. Chem. Ges. 33, 1140-1152, (1900). Zur Kenntniss des Acetessigesters. T=25°. 663. H. Goldschmidt, L. R5der. Ber. Deutsch. Chem. Ges. 28, 2013-2020, (1895). Zur Kenntniss der Aldoximsalze. 664. H. Goldschmidt, R. M. Salcher. Zeit. Phys. Chem. 29, 89-118, (1899). Studien tiber die Aminolyse. [Same as 1568.] T=25°. 665. H. Goldschmidt, V. Scholz. Ber. Deutsch. Chem. Ges. 36, 1333-1341 , (1903). Ueber Verseifungsgeschwindigkeit und Affinitatsgrosse des Malonsauredia- thylesters. 666. H. Goldschmidt, V. Scholz. Ber. Deutsch. Chem. Ges. 40, 624-641, (1907). Ueber die Verseifungsgeschwindigkeit einiger Keto- und Oxysaureester. [Given m 1594.] T=25°. 667. H. Goldschmidt, E. Sunde. Ber. Deutsch. Chem. Ges. 39, 711-725, (1906). Ueber EsterbUdung. T=25°. 668. M. Gomberg. Am. Chem. Jour. 25, 317-335, (1901). On trivalent carbon. 669. M. Gomberg. Ber. Deutsch. Chem. Ges. 35, 2397-2408, (1902). Ueber Triphenylmethyl. Ein Beitrag zur Kenntniss der Carboniumsalze. T=-18°to -10°. 670. (M. Gomberg. Ber. Deutsch. Chem. Ges. 36, 3927-3930, (1903). Ueber die Existenzfahigkeit einer Klasse von Korpern, die dem Triphenyl- methyl analog sind.) [Quoted.] M. Gomberg see N. E. Tousley. 671. M. Gomberg, L. H. Cone. Ber. Deutsch. Chem. Ges. 37, 2033-2051, (1904). Ueber TTriphenylmethyl. [Corrected in 673. ] T=0°. 438 AUTHOR LIST 672. M. Gomberg, L. H. Cone. Ber. Deutsch. Chem. Ges. 37, 3538-3547, (1904). Ueber Triphenylmethyl. 673. M. Gomberg, L. H. Cone. Ber. Deutsch. Chem. Ges. 38, 1333-1344, (1905). Ueber Triphenylmethyl. [Also corrects 671. ] 674. (H. M. Goodwin, H. T. Kabnus. Phys. Rev. 27, 322-328, (1908). On the conductance and fluidity of fused salts.) [Inorganic] 675. (H. M. Goodwin, R. D. Mailey. Phys. Rev. 25, 469-489, (1907). On the density, electrical conductivity and viscosity of fused salts and their mixtures.) [Inorganic. Abstract given in 677. ] 676. (H. M. Goodwm, R. D. Mailey. Phys. Rev. 26, 28-60, (1908). On the density, electrical conductivity and viscosity of fused salts and their mixtures.) [Inorganic] 677. (H. M. Goodwin, R. D. Mailey. Trans. Am. Electrochem. Sec. 11, 211-223, (1907). On the density, electrical conductivity, and viscosity of fused salts.) [An abstract of 675.] 678. (H. M. Goodwin, M. de K. Thompson. Phys. Rev. 8, 38-48, (1899). On the dielectric constant and electrical conductivity of liquid ammonia.). 679. (H. M. Goodwin, H. A. Wentworth. Phys. Rev. 24, 77-92, (1907). On the ionization of fused salts.) [Inorganic. ] M. Gorgolewski see C. Dhere. 680. H. Gorke. Zeit. Phys. Chem. 61, 495-502, (1907-1908). Ueber die Leitfahigkeit von Pikrinsaurelosungen und die Beweglichkeit des H- Ions. t = 0°, 18° and 25°.- x^ aq.=0.8XlO-8; sub. 681. H. Gorke. Dis. Leipzig. (1905). Ueber Losungen stark dissoziierter Elektrolyte. II. Ueber die angeblichen Isomerieen bei Phosphiten und Hypophosphiten. III. Ueber chinoide aci- Nitrophenolather. Meas. H. Gorke; see 1092. S. v. Gorski see S. v. Laszczynski. 682. U. Gouttefangeas. Ann. Chim. Phys. (8), 17, 515-525, (1909). Sur la conductibilit6 ^lectrique des flammes salves. Meas. W. Graf; see 738. W. Graf see A. Hantzsch. 683. O. Graul. Dis. Wurzburg. (1898). Ueber isomere Salze aus Aethylnitrolsaure. [Most measurements are given in 684.] T = 0°. /iaq. = 1.9X10-2. Meas. O. Graul; see 733, 776. 684. O. Graul, A. Hantzsch. Ber. Deutsch. Chem. Ges. 31, 2854r-2879, (1898). Ueber isomere Salze aus Aethylnitrolsaure. [Most measurements are given in 683.] T = 0°. 685. (W. H. Green. Jour. Chem. Soc. 93, 2023-2048, (1908). Studies on the viscosity and conductivity of some aqueous solutions. Part I. Solutions of sucrose, hydrogen chloride, and lithium chloride.) 686. W. H. Green. Jour. Chem. Soc. 93, 2049-2063, (1908). Studies on the viscosity and conductivity of some aqueous solutions. Part. II. Mixtures of solutions of sucrose and lithium chloride. A contribution towards AUTHOR LIST 439 the elucidation of the connexion between ionic mobDity and the fluidity of the solution. T = 25.00°- Gregory = MacGregory, q. v. 687. H. Greinacher. Phys. Zeit. 10, 986-997, (1909). Ueber die Erhohung der Leitf ahigkeit flussiger Dielektrika durch a-Strahlen. H. Gross see £. Lelbnann. 688. (H. Grossmann. Zeit. Anorg. Chem. 54, 40-44, (1907). Zui Komplexbildung in Molybdansaurelosungen.) H. Grossmaim see N. Caro. 689. H. Grossmann, P. v. d. Forst. Ber. Deutsch. Chem. Ges. 37, 4141- 4144, (1904). Die Doppelcyanide des Quecksilbers. T=25°. 690. H. Grossmann, P. v. d. Forst. Zeit. Anorg. Chem. 43, 94-110, (1905). Die Doppelcyanide des Kupfers. T=25°. 691. H. Grossmann, H. Kramer. Ber. Deutsch. Chem. Ges. 36, 1606-1610, (1903). TJeber die Einwirkung organischer Sauren auf die Leitfahigkeit der gelben Molybdansaure. [The measurements are given more fully in 692 and 1023.] R. O. xaq. = 1.5 -2X10-"; sub. 692. H. Grossmaim, H. Kramer. Zeit. Anorg. Chem. 41, 43-60, (1904). iflMeas. A. Rosenheim. Ueber einige Komplexverbindungen der Molybdan- imd Wolframsaure mit organischen Sauren. [See also 1023. ] T = 15°and25°- R. O. H. Griinbaimi see A. Rosenheim. E. Griineisen see F. Kohlrausch. 693. P. Griitzner. Arch. Gesammt. Physiol. 68, 168-175, (1897). Die Caseinausfallung, ein einfaches Mittel, um die Aciditat von Sauren zu bestimmen. 694. L. Grunmach. Ann. Physik. (4), 28, 217-258, (1909). Bestimmung der Oberflachenspannung und anderer physikalischer Konstanten von Essigsaure-Wassermischungen. T = 19.00° and 20.00°. [R. O.? ] 695. F. Gudzent. Zeit. Physiol. Chem. 60, 25-37, (1909). Physikalisch-chemische und chemische Untersuchungen uber das Verhalten der Harnsaure in Losungen. T=37°. R. O. Xi8aq.=0.9-1.0XlO-«; sub. unless otherwise stated. 696. F. Gudzent. Zeit. Physiol. Chem. 60, 38-68, (1909). Physikalisch-chemische Untersuchungen iiber das Verhalten der harnsauren Salze in Losungen. R. O. xis aq.=0.9-1.0X10-''. A. Giinther see T. Paul. 697. (G. GugUelmo. Atti Accad. Torino. 17, 543-565, (1881-1882). SuU'uso dell'elettrometro nella misura della resistenza dei liquidi col metodo di Mance e con quello di Wheatstone e suUa resistenza di alcune soluzioni al- coohche di potassa.) Abstracted in Beibl. Ann. Physik. 6, 803-804, (1882). [Inorganic. ] 698. J. Guinchant. Compt. Rend. 120, 1220-1223, (1895). Conductibilit^ de quelques others ;8-c6toniques. [Given in 700.] T=25°. [S. U.] 440 AUTHOR LIST 699. J. Guinchant. Compt. Rend. 121, 71-73, (1895). Preparation et conductibilit.6 de nouveaux others cyanom6thiniques. [Given in 700.] T = 25°. [S. U.] 700. J. Guinchant. Zeit. Phys. Chem. 24, 174^177, (1897). Studien tiber die sauren Eigenschaften der Methen- und Methinverbindungen. R. O. [This is an abstract of Guinchant's thesis, Paris, (1897). The measurements are given in 698 and 699 together, but A of the sodium salts is given in full here. ] 701. J. Guinchard. Ber. Deutsch. Chem. Ges. 32, 1723-1741, (1899). Ueber die farbigen Salze aus Violursaure und anderen ringformigen Oximi- doketonen. [Given in 702 with more details. ] T=0°to54.1°. 702. J. Guinchard. Dis. Uppsala. (1899). Beitrage zur Kenntniss labiler Atomgruppirungen und ihrer Umlagerung. [Same as 701 with more detailed measurements. ] J. M. Guthrie see J. S. Ford. 703. P. A. Guye, S. Bogdan. Arch. Sci. Phys. Nat. (4), 15, 502-513, (1903). M(Sthodes rapides pour I'analyse physieo-chimique des liquides physiologiques. [Probably same as 218. ] 704. E. Gyr. Dis. Lausanne. (1907). Conductibilit^s limites dans quelques dissolvants inorganiques. [Same as 485. ] T=-15°±0.2°. S. U. X SOzsub. E. Gyr see P. Dutoit. K. Haas see C. Biilow. Meas. K. Haas; see 1030, 1031. 705. H. Hadrich. Zeit. Phys. Chem. 12, 476-497, (1893). Optisches Drehvermogen und elektrolytische Dissociation. R. Haertel see H. Stobbe. Meas. Hauptli; see 77. 706. (A. Hagenbach. Ann. Physik. (4), 5, 276-312, (1901). Ueber die Aenderung der Leitfahigkeit von Salzlosungen in flussiger schwefliger Saure mit der Temperatur bis iiber den kritischen Punkt. Elektrolytische Leitung in Gasen und Dampfen. Absorptionsspectra von Losungen mit Jodsalzen.) [Inorganic] 707. (A. Hagenbach. Phys. Zeit. 1, 481-483, (1899-1900). Ueber elektrolytische Leitung in Gasen beim kritischen Punkte.) [Inorganic. ] 708. F. Haiser, F. Wenzel. Monatsh. 30, 377-386, (1909). Ueber Karnin und Inosinsaure. [Same as 708a. ] T = 25°. 708a. F. Haiser, F. Wenzel. Sitzber.Akad.Wien. 118,2b, 153-162, (1909). Ueber Karnin und Inosinsaure. [Same as 708.J 709. "W. HaUwachs. Ann. Physik. (3), 68, 1^5, (1899). Ueber ein Doppeltrogrefractometer und Untersuchungen mit demselben an Losungen von Bromcadmium, Zucker, Di- und Trichloressigsaure, sowie deren Kaliumsalze. [Same as 710. ] T = 12.5°. 710. W. Hallwachs. Sitzber. Ges. Isis. Dresden. (1898), 49-81. Ueber ein Doppeltrogrefractometer, etc. [Same as 709.] W. Hallwachs see F. Kohlrausch. F. J. Hambly see J. Walker. Meas. F. Hambtirger; see 1616. AUTHOR LIST 441 1. (W. Hampe. Chem. Ztg. 11, 816, (1887). sr die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 2. (W. Hampe. Chem. Ztg. 11, 846-847, (1887). sr die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 3. (W. Hampe. Chem. Ztg. 11, 904-905, (1887). sr die electroljiiische Leitungsfahigkeit der Haloidverbindungen.) 4. (W. Hampe. Chem. Ztg. 11, 934-935, (1887). ir die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 5. (W. Hampe. Chem. Ztg. 11, 1109-1110, (1887). sr die electrolytische Leitungsfahigkeit der Haloidverbindungen.) )ted.] 6. (W. Hampe. Chem. Ztg. 11, 1158, (1887). 3r die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 7. (W. Hampe. Chem. Ztg. 11, 1549-1550, (1887). 3r die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 8. (W. Hampe. Chem. Ztg. 12, 4r-5, (1888). sr die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 9. (W. Hampe. Chem. Ztg. 12, 23-24, (1888). ST die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 10. (W. Hampe. Chem. Ztg. 12, 106, (1888). ST die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 11. (W. Hampe. Chem. Ztg. 12, 122, (1888). er die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 12. (W. Hampe. Chem. Ztg. 12, 140, (1888). er die electrolytische I;eitungsfahigkeit der Haloidverbindungen.) 13. (W. Hampe. Chem. Ztg. 12, 171-173, (1888). sr die electrolytische Leitungsfahigkeit der Haloidverbindungen.) 14. M. Handa. Ber. Deutsch. Chem. Ges. 42, 3179-3182, (1909). Charakterisierung von Indicatoren. 14a. H. Handovsky. Biochem. Zeit. 25, 510-538, (1910). srsuchungen iiber physikahsche Zustandsanderungen* der KoUoide. X. ieilimg. Die Einwirkung von organischen Basen und amphoteren Elek- rten auf Eiweiss. T=25°. H. Handovsky see W. Pauli. 15. A. Hantzsch. Ann. Chemie. 296, 84-94, (1897). Meas. H. Ley. Kenntniss der Saureamide. T = 0°. 16. (A. Hantzsch. Ann. Chemie. 296, 111-119, (1897). lerkungen uber Nitramid.) [Corrects 765.] 17. A. Hantzsch. Ber. Deutsch. Chem. Ges. 22, 2827-2840, (1889). Meas. W. Ostwald. vandlung von Derivaten des Pentamethylens in solche des Benzols, dins und Thiophens. 18. A. Hantzsch. Ber. Deutsch. Chem. Ges. 23, 1483-1489, (1890). Meas. 6. Bethmann. Spaltung des Pentamethylenringes. 19. A. Hantzsch. Ber. Deutsch. Chem. Ges. 25, 827-841, (1892). Meas. C. Barth. er die Spaltungsproducte der Anilsauren. 10. A. Hantzsch. Ber. Deutsch. Chem. Ges. 28, 1734-1753, (1895). soniumverbindungen xmd normale Diazoverbindungen. T = l°and25°. 442 AUTHOR LIST 731. A. Hantzsch. Ber. Deutsch. Chem. Ges. 30, 339-347, (1897). Mias. W. B. Davidson. Zur Kenntniss normaler Diazoverbindungen. 732. (A. Hantzsch. Ber. Deutsch. Chem. Ges. 32, 575-600, (1899). Zur Constitutionsbestimmung von Korpem mit labilen Atomgruppen.) [Quoted.] 733. A. Hantzsch. Ber. Deutsch. Chem. Ges. 32, 3066-3088, (1899). Meas. 0. Graul. Zur Charakteristik von schwachen Sauren und von Pseudosauren. [The values given here are too high; see 738.] T = 0°, 25° and 35°. x aq. not sub. 734. A. Hantszch. Ber. Deutsch. Chem. Ges. 33, 752-760, (1900). Zur Kenntniss der Salze und Basen aus Triphenylmethanfarbstoffen. T = 25°. 735. A. Hantzsch. Ber. Deutsch. Chem. Ges. 33, 2161-2179, (1900). Meas. Schumann, Osswald, Davidson. Syndiazocyanide und Diazoniumcyanide. T = 0°. 736. A. Hantzsch. Ber. Deutsch. Chem. Ges. 35, 265-268, (1902). Meas. M. Buchner. Affinitatsconstanten einiger Nitramine und Isonitramine. T=0°and25°. 737. A. Hantsch. Ber. Deutsch. Chem. Ges. 36, 2069-2075, (1903). Zur Atomwanderung bei Diazoverbindungen. [Corrects 501.] 738. A. Hantzsch. Ber. Deutsch. Chem. Ges. 37, 1076-1084, (1904). Meas. W. Graf, S. Pilat, P. Wiegner. Notiz Tiber amphotere Elektrolyte und speciell iiber Kakodylsaure. T = 25°. 739. A. Hantzsch. Ber. Deutsch. Chem. Ges. 37, 2705-2708, (1904). Berichtigungen zu Hm. v. Zawidzki's Arbeit iiber Kakodylsaure. [See 2011.] 740. A. Hantzsch. Ber. Deutsch. Chem. Ges. 38, 1045-1048, (1905). Zur Molekulargrosse von Salzen in indifferenten Losungen. 741. A. Hantzsch. Ber. Deutsch. Chem. Ges. 38, 2143-2154, (1905). Ueber Oxonium- und Ammonium- Salze. T = 25°. 742. A. Hantzsch. Ber. Deutsch. Chem. Ges. 39, 139-153, (1906). Meas. F. Hofmann, and M. Lehmann. Die Cyanursaure als Pseudosaure. T = 25°. 743. (A. Hantzsch. Ber. Deutsch. Chem. Ges. 39, 2098-2112, (1906). Ueber Hm. Euler's Arbeit " Zur Kenntniss der Pseudosauren.") [See 613 and 514.] 744. A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 330-351, (1907). Meas. N. Rosanof. Ueber Isomerie von Nitrophenolsalzen und die Existenz von Metachinoiden. T = 25°. 745. A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 1523-1532, (1907). Meas. A. Salway. Ueber farblose, gelbe und rote Salze aus Nitroketonen. [Given in 1567. ] 748. A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 1556-1572, (1907). Meas. W. Praetorius. Ueber Konstitution und Korperfarbe der Nitrophenole und speziell des Nitro- hydrochinonathers. X aq. sub. AUTHOR LIST 443 747. A. Hantzsch. Ber. Deutsch. Chem. Ges. 42, 68-85, (1909). Meas. H. LeupoM. Polymerie als Ursache der Farbverschiedenheit von Haloidsalzen und Sulfiten. [Given in 1076.] T = 25°. 748. A. Hantzsch. Zeit. Anorg. Chem. 25, 332-340, (1900). Ueber den Einfluss von Nichtelektrolyten aiif das Leitvermogen von Elek- trolyten. T = 25°. '749. (A. Hantzsch. Zeit. Phys. Chem. 56, 57-64, (1906). Bemerkungen tiber Pseudosauren und amphotere Elektrolyte.) 750. A. Hantzsch. Zeit. Phys. Chem. 61, 257-312, (1907-1908). Meas. F. C. R. Bergius, M. Lehmann. Ueber den Zustand von Stoffen in absoluter Schwefelsam'e. T =25°. R. O. X solvent sub. 751. (A. Hantzsch. Zeit. Phys. Chem. 65, 41-60, (1908-1909). Ueber den Zustand von Stoffen in absoluter Schwefelsaure.) [For a criticism of 750 and 751 see 1348 and Oddo, Scandola, Gaz. Chim. Ital. 40, II, 163-209, (1910); also A. Hantzsch, Gaz. Chim. Ital. 39, II, 512, (1909), and Zeit. Phys. Chem. 68, 204, (1909).] . Hantzsch see S. M. Auld. " " W. B. Davidson. " " A. Engler. " " H. Euler. " " R. C. Farmer. " " D. Gerilowski. " " O. Graul. " " H. Ley. " K. H. Meyer. 752. A. Hantzsch, A. Barth. Ber. Deutsch. Chem. Ges. 35, 210-226, (1902). HMeas. W. Praetorius. Charakteristik von Pseudosawen durch abnorme Beziehungen zwischen der Affinitatsconstante und der Hydrolyse ihrer Seize. T=0° and 25°. x aq.=0.6X10-8. 753. A. Hantzsch, K. S. Caldwell. Zeit. Phys. Chem. 58, 575-584, (1907). Ueber abnorm grosse lonenbeweglichkeiten. T = 25° 754. A. Hantzsch, K. S. Caldwell. Zeit. Phys. Chem. 61, 227-240, (1907- 1908). a Meas. W. Fischer. Vergleich von Sauren und Pseudosauren in Pyridinlosung. [The conclusions and some qualitative statements are given in 321.] T=25°. R. O. 755. A. Hantzsch. W. B. Davidson. Ber. Deutsch. Chem. Ges. 29, 1522- 1536, (1896). Ueber Diazophenole. T = 25°. ?caq.=3XlO-^ sub. 756. A. Hantzsch, C. H. Desch. Ann. Chemie. 823, 1-31, (1902). Ueber farbige organische Ferriverbindungen. T=0°and25°. x aq. sub. 757. A. Hantzsch, F. E. Dollfus. Ber. Deutsch. Chem. Ges. 35, 226-265, (1902). ■ , . „ Charakteristik von Pseudosauren durch die " Ammomakreaction. T=20°and25°. 444 AUTHOR LIST 758. A. Hantzsch, W. H. Glover. Ber. Deutsch. Chem. Ges. 40, 4344-1350, (1907). Meas. H. Glover. Zur Konstitution iind Korperfarbe von Derivaten der Dioxime des o-Benzo- chinons und Naphthochinons. [Same as 644. ] T = 25° 759. A. Hantzsct, W. Graf. Ber. Deutsch. Chem. Ges. 38, 2154-2161, (1905). Ueber Additionsproducte tertiarer Amine. T=25° 760. A. Hantzsch, H. Hibbert. Ber. Deutsch. Chem. Ges. 40, 1508-1519, (1907). iH Meas. G. Schick. Ueber Additionsprodukte von Trialkylphosphinen, -arsinen und -stibinen. T=25° for one compound. 761. (A. Hantzsch, A. Holl. Ber. Deutsch. Chem. Ges. 34, 3430-3445, (1901). Ueber das sogen. SuMmid.) [Inorganic] 762. A. Hantzsch, P. C. C. Isherwood. Ber. Deutsch. Chem. Ges. 42, 986-1000, (1909). Ueber Salze und Ester der Violursaure-Gruppe. T = 25°. 763. A. Hantzsch, M. Kalb. Ber. Deutsch. Chem. Ges. 32, 3109-3131, (i899). Ueber Pseudoammoniumbasen. T = 0°and25°. :«: aq.= 2.1X10-'. 764. A. Hantzsch, M. Kalb. Ber. Deutsch. Chem. Ges. 33, 2201-2208, (1900). Cotamincyanid als Pseudosalz. T=0°to40°. 765. (A. Hantzsch, L. Kaufmann. Ann. Chemie. 292, 317-340, (1896). Zur Kenntniss der untersalpetrigen Saure.) [Qualitative; see 726.] T = 0°. 766. A. Hantzsch, H. Kissel. Ber. Deutsch. Chem. Ges. 32, 3137-3148, (1899). Ueber Derivate von Nitrosauren und die Reactionen der Nitrokorper. T = 25°andO°. 767. A. Hantzsch, M. Lehmann. Ber. Deutsch. Chem. Ges. 33, 3668- 3685, (1900). Ueber Bisazoxyessigsaure, Bisazoxymethan und Hydraziessigsaure. T = 25°. 767a. A. Hantzsch, K. H. Meyer. Ber. Deutsch. Chem. Ges. 43, 336-340, (1910). Ueber die BUdung farbloser lonen aus Triphenylmethylbromid. [Part is same as part of 1260.] T = 25°. 768. A. Hantzsch, A. Miolati. Zeit. Phys. Chem. 10, 1-33, (1892). Ueber die Beziehungen zwischen der Konfiguration und den Affinitatsgrossen stereoisomerer Stickstoffverbindungen. T = 0°and25°. 769. A. Hantzsch, G. Osswald. Ber. Deutsch. Chem. Ges. 32, 641-650, (1899). Ueber Cyanoform. T = 0°and25° AUTHOR LIST 44-5 770. A. Hantzsch, G. Osswald. Ber. Deutsch. Chem. Ges. 33, 278-317, (1900). TJeber die Umwandlung von Parbbasen in Pseudoammonium-Hydrate, -Cya- nide und -Sulfonsauren. [Corrected in 636.] T=0°. 771. A. Hantzsch, N. Picton. Ber. Deutsch. Chem. Ges. 42, 211&-2128, (1909). Ueber den Chromophor der Salze aus Polynitrobenzol-Derivaten. 772. A. Hantzsch, A. Rinckenberger. Ber. Deutsch. Chem. Ges. 32, 628-641, (1899). Ueber Nitroform. T = 0°and25° 773. A. Hantzsch, R. Robison. Ber. Deutsch. Chem. Ges. 43, 92-95, (1910). Notiz liber Purpursaure. T=0°. 774. A. Hantzsch, M. Schiimaan, A. Engler. Ber. Deutsch. Chem. Ges. 32, 1703-1716, (1899). Antidiazohydrate imd primare Nitrosamine. [Part is same as 1602. ] T = 0°and25°. 775. A. Hantzsch, O. W. Schultze. Ber. Deutsch. Chem. Ges. 29, 2251- 2267, (1896). Meas. W. Davidson. Ueber Isomerie der Nitrokorper. T=0°and25°. 776. A. Hantzsch, F. Sebaldt. Zeit. Phys. Chem. 30, 258-299, (1899). Meas. O. Graul. Ueber den Zustand wasseriger Ammoniak- und Aminlosmigen. T=0°to50° 777. A. Hantzsch, C. H. Sluiter. Ber. Deutsch. Chem. Ges. 39, 162-166, (1906). Zur Kenntniss der isomeren Nitroso-orcine. T = 25°. 778. (A. Hantzsch, B. C. Stuer. Ber. Deutsch. Chem. Ges. 38, 1022-1043, (1905). Neue Reactionsproducte aus Ammoniak und Sulfurylchlorid.) [Inorgamc. ] 779. A. Hantzsch, A. Vagt. Ann. Chemie. 314, 339-369, (1901). »Meas. M. Schumann. Ueber das sogenannte Diazoguanidin. T = 25°. 780. A. Hantzsch, A. Veit. Ber. Deutsch. Chem. Ges. 32, 607-627, (1899). Zur Kenntniss der Isonitrokorper. T=0°and25°. 781. A. Hantzsch, E. Voegelen. Ber. Deutsch. Chem. Ges. 34, 3142-3163, (1901). fUMeas. M. Buchner. Zur Kenntniss der sogenannten Isoamide und der echten Saureamide. T = 25°. 782. A. Hantzsch, E. Voegelen. Ber. Deutsch. Chem. Ges. 35, 1001-1009, (1902). §Meas. W. Praetonus. Charakteristik von Pseudosauren durch Leitfahigkeit in wassrigem Alkohol. T=25°. xaq. notsub. 783. W. Hardt. Dis. Erlangen. (1901). Spektroskopisches Verhalten und elektrische Leitfahigkeit des Kobaltchlorids in verschiedenen Losungsmitteln. T = 18°and20°. R. 0. 446 AUTHOR LIST 783a. W. B. Hardy. Jour. Physiol. 33, 251-337, (1905-1906). Colloidal solution. The globulins. T= 18°. R. O. xaq. =3X10-5. W. B. Hardy see T. B. Wood. 784. C. Harries, P. Hohenemser. Ber. Deutsch. Cham. Ges. 41, 255-260, (1908). Ueber den monomolekularen Succindialdehyd. [T = 20°?] "W. Harrison see W. W. H. Gee. 785. T. Harth. Zeit. Anorg. Chem. 14, 323-353, (1897). Ueber Quecksilberhalogen-Doppelverbindungen. E. G. J. Hartley see Berkeley. 786. H. Hartley, N. G. Thomas, M. P. Applebey. Jour. Chem. Soc. 93, 638-560, (1908). Some physico-chemical properties of mixtures of pyridine and water. T=0°and25°. R. O. xo aq. = 1.2X10-8. 787. K. Hartwig. Ann. Physik. (3), 33, 58-80, (1888). Die electrische Leitungsfahigkeit von Losungen einiger Glieder der Fett- saurereihe in Wasser und einigen Alkoholen. [See 788.] T=0°to30°. Hg. U. 788. K. Hartwig. Ann. Physik. (3), 43, 839-840, (1891). Ueber die moleculare Leitungsfahigkeit von Losungen einiger GUeder der Fettsaurereihe in Wasser und einigen Alkoholen, sowie der Oxalsaure in Aethylalkohol. [Chiefly a recalculation of the measurements in 787.] T = 18°. 789. K. Hartwig. Progr. Niimberg. (1886). Abstracted in Beibl. Ann. Physik. 11, 101-102, (1887). Die electrische Leitungsfahigkeit der wasserigen und alkohohschen Losungen des Phenols und der Oxalsaure. T = 18°to41°. Hg. U. 790. (F. Hasenoehrl. Sitzber. Akad. Wien. 105, 2a, 460-476, (1896). Ueber den Temperaturcoefficienten der Dielektricitatsconstante in Fliissig- keiten und die Mosotti-Clausius'sche Formel.) 791. (R. V. Hasslinger. Monatsh. 28, 173-207, (1907). Ueber das Wesen metallischer und elektrolytischer Leitung.) [Inorganic] A. Hausdorfer see C. A. Bischoff. 792. F. De F. Heald. Science. (N. S.), 15, 457, (1902). The electrical conductivity of plant juices. [Qualitative.] 793. W. Hechler. Ann. Physik. (4), 15, 157-173, (1904). Pluiditat und Leitfahigkeit einiger konzentrierter wasseriger Salzlosungen unter 0°. [Same as 794 with some corrections.] T= -20.86° to +7.17°. R. O. 794. W. Hechler. Dis. Munster. (1904). Fluiditat und Leitfahigkeit, etc. [Same as 793 except for some slight errors. ] J. Hecht see R. Wegscheider. 795. E. P. Hedley. Ber. Deutsch. Chem. Ges. 41, 1195-1204, (1908). Spektroscopische Untersuchung isomerisierbarer Nitrokorper im Ultraviolett. [Measurements given in 796. ] 796. E. P. Hedley. Dis. Leipzig. (1908). Spektroskopische Untersuchung, etc. [QuaUtative statement given in 795.] T=0°and25°. R. O. « aq. =0.7-1.0X10-"; sub. AUTHOR LIST 447 797. E. Heiten. Dis. Bonn. (1907). Ueber Saccharin und Saccharinate und ihre Bildungsgeschwindigkeit auB Zuckerarten unter dem Einfluss von Alkalien. [Same as 1493. ] T=25°. R. O. xaq. sub. E. Heiten see E. Rimbach. B. Held see E. Beckmann. 798. (G. HeUer. Ann. Chemie. 332, 247-304, (1904). § Meas. R. Emrich. Ueber die Einwirkung von Dichloressigsaure auf Anilin und die Toluidine.) [See 499 for measurement. A correction is made here. ] G. Heller see E. Deussen. 799. A. de Hemptinne. Zeit. Phys. Chem. 31, 35-41, (1899). Sur les vitesses de reaction. T about 24°. Henault see Dony-Henault. 800. (L. J. Henderson. Am. Jour. Physiol. 21, 173-179, (1908). Concerning the relationship between the strength of acids and their capacity to preserve neutrality.) 801. (L. J. Henderson. Am. Jour. Physiol. 21, 427-448, (1908). The theory of neutrahty regulation in the animal organism.) [Inorganic] 802. (L. J. Henderson. Jour. Am. Chem. Soc. 30, 954r-960, (1908). A diagrammatic representation of equilibria between acids and bases in solu- tion.) [Quoted; and theoretical.] 803. L. J. Henderson. Ergebn. Physiol. 8, 254-325, (1909). Das Gleichgewicht zwischen Basen und Sauren im tierischen Organismus. 803a. (L. J. Henderson, A. Forbes. Jour. Am. Chem. Soc. 32, 687-689, (1910). On the estimation of the intensity of acidity and alkalinity with dinitro- hydroquinone.) [Indicators. ] 804. L. J. Henderson, K. Spiro. Biochem. Zeit. 15, 105-113, (1908- 1909). Zur Kenntnis des lonengleichgewichts im Organismus. I. Teil. Ueber Basen- und Sauregleichgewicht im Ham. 805. H. Henkel. Dis. Berlin. (1905). Beitrage zur Kenntnis der physikajisch-chemischen Eigenschaften verdunnter Glycerinlosungen und zur Analyse derselben. [Same measurements in 806. ] T = 18°. R. O. »:i8aq. = 1.36X10-«; sub. 806. H. Henkel, A. W. Roth. Zeit. Angew. Chem. 18, II, 1936-1941, (1905). Chemische und physikalische Methoden zur Analyse verdunnter rein wasser- iger Glycerinlosungen. [Same as 805. ] T = 18°. R. O. J<:i8aq. = 1.36X10-8; sub. 807. V. Henri, L. des Bancels. Compt. Rend. 136, 1088-1090, (1903). Loi de Faction de la trypsine sur la gelatine. T=44°. 808. V. Henri, L. des Bancels. Compt. Rend. 136, 1581-1582, (1903). Loi de Faction de la trypsine sur la gelatine. T = 44°. 809. F. Henrich. Bar. Deutsch. Chem. Ges. 37, 1406-1415, (1904). Ueber die Constitution der Orselhnsaure. T=25°. 810. F. Henrich. Monatsh. 18, 142-188, (1897). Ueber zwei Modificationen des Mononitrosoorcins. [Same as 811.] 811. F. Henrich. Sitzber. Akad. Wien. 106, 2b, 155-201, (1897). Ueber zwei Modificationen, etc. [Same as 810. ] 448 AUTHOR LIST 812. P. Henry. Zeit. Phys. Chem. 10, 96-129, (1892). Ueber die wechselseitige Umwandlung der Laktone und der Oxysauren. H. Henstock see W. A. Bone. 813. H. Henstock, C. H. G. Sprankling. Jour. Chem. See. 91, 354^-360, (1907). aa7-Trimethyl- and aayy- tetramethyltricarballylic acids and a7-dimethyl- butane-a;86-tricarboxylic acid. T=25°. 814. H. Henstock, B. E. WooUey. Jour. Chem. Soc. 91, 1954-1958, (1907). The action of phosphorus pentachloride on hydroxytrimethylsuccinic ester. 1 : 2-Dimethylcyclopropane-l : 2-dicarboxyUc acid. (1 : 2-Dimethyltrime thylene-1 : 2-dicarboxyUc acid). T = 25°. E. Hepner see A. Michaelis. C. Herty see A. Werner. 815. C. H. Herty, R. O. E. Davis. Jour. Am. Chem. Soc. 30, 1084-1089, (1908). The character of the compomid formed by the addition of ammonia to ethyl- phospho-platino-chloride. T = 25°. J. Hertzmann see A. Rosenheim. 816. H. Herwig. Ann. Physik. (2), 159, 61-93, (1876). Ueber den Durchgang starker Inductionsstrome dm'ch Fliissigkeiten. Meas. Herwig; see 847. 817. G. Heun. Dis. Leipzig. (1897). Meas. Smith. Ueber die Producte der Condensation des Acetophenons mit dem Diaethyl- Ester der Bernsteinsaure und Malonsaure unter dem Einfluss des Natrium- aethylates. 817a. G. V. Hevesy. Zeit. Elektrochem. 16, 672-673, (1910). Ueber die Elektrolyse in Pyridin geloster Erdalkalijodide. T = 25° 818. J. T. Hewitt. Analyst. 23, 85-90, (1908). The constitution of indicators used in acidimetry. 819. A. HeydweiUer. Ann. Physik. (4), 28, 503-512, (1909). Ueber lonisationswarme und lonisationskonstante des Wassers. Hg. U. 820. A. HeydweiUer. Ann. Physik. (4), 30, 873-904, (1909). Meas. J. Wigger. Ueber physikalische Eigenschaften von Losungen in ihrem Zusammenhang. I. Dichte und elektrisches Leitvermogen wasseriger Salzlosungen. T = 18°. R. O. 821. (A. HeydweiUer. Verhand. Deutsch. Phys. Ges. 11, 37-44, (1909). Eine einfache Beziehung zwischen Dichte und Dissoziationsgrad wasseriger Salzlosungen.) [Quoted. See 1714.] A. HeydweiUer see F. Kohlrausch. H. Hibbert see A. Hantzsch. " " see A. Michael. S. Higuchi see W. Lob. 822. J. HUdebrand. Zeit. Elektrochem. 14, 349-353, (1908). Das Konigsche Spektralphotometer in neuer Anordnung und seine Verwen- dung zur Bestimmung chemischer Gleichgewichte. T = 26°. T. P. HUditch see J. N. CoUie. AUTHOR LIST 449 822a. A. E. HUl. Jour. Am. Chem. Soc. 32, 1186-1193, (1910). The inconstajicy of the solubility product. T = 25.00° ±0.08°. X25aq. =2.9X10-8. 823. E. G. HiU. Jour. Chem. Soc. 89, 1273-1289, (1906). The hydrolysis of ammonium salts by water. T = 18°. Xis aq. = 1.5X10-«, or less. 824. (G. D. Hinrichs. Compt. Rend. 143, 549-550, (1906). La m^canique de I'ionisation par solution.) F. W. Hinrichsen see E. Rasch. 825. W. ffis, T. Paul. Zeit. Physiol. Chem. 31, 1-42, (1900-1901). Physikalisch-chemische Untersuchungen iiber das Verhalten der Hamsaure und ihrer Salze in Losungen. T = 18°. R. O. 7t aq. = 1.0X10-"; measurements given both with and without sub. 826. E. Hjelt. Ber. Deutsch. Chem. Ges. 25, 488-491, (1892). Meas. U. Collan. Allylathyl- und AUylmethylbernsteinsauren. [For tables of fi and of k of the aUylethyl succinic acids, see 830 and 1838.] 827. E. Hjelt. Ber. Deutsch. Chem. Ges. 25, 524r-525, (1892). Meas. U. Collan. Notiz tiber Benzylalkohol-o-carbonsaure. T=25°. 828. E. Hjelt. Ber. Deutsch. Chem. Ges. 29, 1855-1859, (1896). Meas. R. Malmstrom. Ueber einige alkylsubstituirte Valerolactone. [For full tables of fi and k see 831. This only gives k.] 829. (E. Hjelt. Ber. Deutsch. Chem. Ges. 31, 1844^1847, (1898). Ueber die relative Verseifungsgeschwindigkeit der Ester der normalen Sauren der Oxalsaurereihe.) [Quoted.] 830. E. Hjelt. Ofvers. Finska Vet.-Soc. Forhand. 34, 7-10, (1891-1892). Meas. U. Collan. Undersokningar ofver symmetrisk allyl-etylbernstenssyra. [Given in 1838. Same as part of 826, but contains fuU tables of fi and k. ] 831. E. Hjelt. Ofvers. Finska Vet.-Soc. Forhand. 38, 132-139, (1895-1896). Meas. R. Malmstrom. Ueber einige alkylsubstituirte Valerolactone. [Same as 828 but contains fuU tables of /j, and k. ] E. Hjelt see C. A. Bischoff. 832. (P. Hodge. Phys. Rev. 26, 540-541, (1908). A study of photo-electric cells containing a fluorescent electrolyte.) [A sum- mary of 833. ] 833. P. Hodge. Phys. Rev. 28, 25-44, (1909). An experimental study of photo-active cells with fluorescent electrolytes. I. T=0° and room temperature. 834. B. Hodgson. Phil. Mag. (6), 18, 252-258, (1909). The conductivity of dielectrics under the action of radium rays. 835. R. Hober. Arch. Gesammt. Physiol. 81, 522-539, (1900). Ueber die Hydroxylionen des Blutes. 836. R. Hober. Arch. Gesammt. Physiol. 99, 572-593, (1903). Ueber die Hydroxylionen des Blutes. 836a. R. Hober. Arch. Gesammt. Physiol. 133, 237-253, (1910). Eine Methode die elektrische Leitfahigkeit im Innern von Zellen zu messen. 450 AUTHOR LIST 836b. (R. Hober. Zeit. Elektrochem. 16, 681-686, (1910). Fortsohritte in den Beziehungen zwiscben physikalisoher Chemie und Physiol- ogie. II. Die Beteilung von Wasserstoff- und Hydroxylionen bei physiolo- gischen Vorgangen.) 837. (J. H. van't Hoff. Zeit. Phys. Chem. 18, 300-304, (1895). Ueber das Verdtinnungsgesetz bei Salzen.) [Quoted.] Meas. J. H. van't Hoff; see 540. 838. J. H. van't Hoff, L. T. Reicher. Zeit. Phys. Chem. 2, 777-781, (1888). m Meas. J. F. Eyhmann. Ueber die Dissociationstheorie der Elektrolyte. T = 14.1° and 19.1°. Hg. U. x aq. not sub. 839. J. H. van't Hoff, L. T. Reicher. Zeit. Phys. Chem. 3, 198-202, (1889). Beziehung zwischen osmotisohem Druck, Gefrierpunktserniedrigung und elektrischer Leitfahigkeit. T = 14°. Hg. U. >caq. sub. Meas. F. Hofmann; see 742, 1137. 840. K. A. Hofmann, H. Kirmreuther, A. Thai. Ber. Deutsch. Chem. Ges. 43, 183-188, (1910). Carboniumperchlorate (2. Mitteilung) und das Losungsvermogen der gechlor- ten Aethane. T = 17°, 18° and 19°. P. Hohenemser see C. Harries. C. Hohmann see W. Nemst. L. Holbom see F. Kohlrausch. 841. K. Holdermann. Arch. Pharm. 243, 600-617, (1905). Ueber Queoksilberoxycyanid. T = 25°. ;C26 aq. =6.6X10"°; measurements made with and without sub. A. Holl see A. Hantzsch. 842. R. J. Holland. Ann. Physik. (3), 50, 261-292, (1893). Ueber die Aenderung der electrischen Leitfahigkeit einer Losung durch Zusatz von kleinen Mengen eines Nichtleiters. T = 18°. Hg. U. 843. C. Hollander. Dis. Munchen. (1902). Meas. V. Rothmund. Synthese der Ecgoninsaure. Studien zur Synthese des Hygrins. [Same as 1978.] T = 25°. C. Hollander see R. Willstatter. 844. A. F. HoUeman. Rec. Trav. Chim. 14, 121-130, (1895). Recherohes sur le ph6nylnitrom6thane. T = 24.9°. 845. A. F. HoUeman. Rec. Trav. Chim. 16, 162-171, (1897). Sur les acides nitrobarbitiirique et dim^thylnitrobarbiturique. T = 24.5°to25.0°. 846. A. F. HoUeman. Rec. Trav. Chim. 21, 66-58, (1902). [Meas. G. L. Voerman? ] Quelques observations sur I'acide chloro-amidobenzoique. R. O. 847. A. F. HoUeman. Rec. Trav. Chim. 21, 432-447, (1902). jUMeas. Herwig. Sur la preparation des dinitrophtools et des dinitranisols, et sur quelques-unes de leurs propri6t6s physiques. T=25.0°. AUTHOR LIST 451 848. A. F. HoUeman. Zeit. Phys. Chem. 12, 125-139, (1893). Bestimmungen der Losliohkeit sogenannter unloslicher Salze. T = ll°to26°. S. U. Kaq.=8X10-«; sub. Meas. HoUeman; see 79, 387. 849. A. F. HoUeman, B. R. de Bruyn. Rec. Trav. Chim. 20, 360-364, (1901). Slir la conductibilit^ 61ectrique des acides chloro- et bromomtrobenzoiques. A. F. HoUeman, H. A. Sirks, see 1628. A. F. HoUeman, G. L. Voermau, see 1812. 850. B. Holmberg. Ann. Chemie. 353, 131-138, (1907). Ueber Methintrithioglycolsaure. 851. B. Holmberg. Ann. Chemie. 359, 81-99, (1908). Organische f olysiilfide. T = 25°. R. O. 852. B. Holmberg. Jour. Prakt. Chem. (2), 71, 264r-295, (1905). Estersauren von schwefelsubstituierter Kohlensaxire mit aUphatischen Alko- holsauren. T = 25°. X aq. = 1.3X10-8; not sub. 853. B. Holmberg. Jour. Prakt. Chem. (2), 75, 169-187, (1907). Estersauren von schwefelsubstituierter Kohlensaure mit aUphatischen Alko- holsauren. 854. B. Holmberg. Jour. Prakt. Chem. (2), 79, 253-270, (1909). Estersauren von schwefelsubstituierter Kohlensauren mit aUphatischen Alko- holsauren. 855. B. Holmberg. Zeit. Phys. Chem. 62, 726-730, (1908). Zur Kenntnis der amphoteren Elektrolsrte. T=25.0°. xaq. notover2X10-«. 855a. B. Holmberg. Zeit. Phys. Chem. 70, 153-157, (1910). Ueber den amphoteren Charakter der Kakodylsaure. T=25°. J(26aq.= 1.4 -1.5X10-8. 856. B. Holmberg, K. Mattisson. Ann. Chemie. 353, 123-130, (1907). Zur Kenntniss einiger Mercaptalsauren. R. O. 857. (J. Holmes, P. J. Sageman. Jour. Chem. Soc. 95, 1919-1943, (1909). Contributions to the theory of solutions.) E. Holzweissig see H. Ley. 858. (R. Hosking. Phil. Mag. (6), 7, 469-484, (1904). The electrical conductivity and fluidity of solutions.) [Inorganic. ] 859. T. van Hove. Bui. Acad. Belg. (1909), 282-294. Etude dynamique de deux d^riv^s alkyKs de I'acide phosphorique. T=25°. 859a. H. E. Howe. Phys. Rev. 30, 453-459, (1910). The electrical conductivity of fluorescent anthracene vapor. T=200° to260°. 860. W. T. H. Howe. Am. Chem. Jour. 18, 390-401, (1896). On the existence of two orthophthalic acids. [Untrustworthy. See Am. Chem. Jour. 18, 829.] 861. F. H. Howies, J. F. Thorpe. Proc. Chem. Soc. 15, 103-104, (1899). Meas. lAdbury. j8-Isopropylglutaric acid. 862. (W. Huiskamp. Zeit. Physiol. Chem. 34, 32-54, (1901-1902). Ueber die Elektrolyse der Salze des Nucleohistons und Histons.) 452 AUTHOR LIST 863. E. Humphrey. Dis. Zurich. (1901). Ueber die Bindungsstelle der Metalle in ihren Verbindungen und uber Dini- tritodiathylendiaminkobaltisalze. [Same as 1949.] E. Humphrey see A. Werner. D. Hurmuzescu see L. Benoist. 864. (M. Huybrechts. Ann. Chim. Phys. (8), 11, 68-101, (1907). Sur la Vitesse des ions des Electrolytes; sulfate de magn&ium et acide sulfurique en solutions aqueuses dilutes.) [Inorganic] I. K. Ingebrechtsen see H. Goldschmidt. H. Ingle see J. Thiele. 865. J. K. H. IngUs, L. E. Knight. Jour. Chem. Soc. 93, 1595-1600, (1908). The conductivities of the a-Oximino-fatty acids. T=25°. [R. O.] 7caq.=2.1X10-^ 866. J. K. H. IngUs, L. E. Knight. Proc. Chem. Soc. 24, 191, (1908). The conductivities of the a-oximino-fatiy acids. [Qualitative. A summary of 865.] W. Isajew see N. Zelinsky. Isaposhnikow see Sapoznikov. P. C. C. Isherwood see A. Hantzsch. 867. H. Itzig. Dis. Erlangen. (1899). Ueber einige complexe Salze der Wein- und Aepfelsaure von hoher specifischer Drehung. [Same as 1521.] T = 25°. H. Itzig see A. Rosenheim. Izgaruishev see Izgarysev. N. Izgarysev see N. Zelinsky. J. L. L. Jackson see K. Auwers. 868. A. Jacob. Dis. Heidelberg. (1894). Meas. H. Wislicenus. Ueber zwei stereochemisch isomere Butantetracarbonsauren. [Same as 66 for acids, with tables of /i. ] A. Jacob see K. Auwers. 869. C. A. Jacobson. Dis. Johns Hopkins. (1908). The conductivity and ionization of electrolytes in aqueous solutions as con- ditioned by temperatxire, dilution and hydrolysis. [Same as 911. ] T = 0°to35°. xaq. sub. C. A. Jacobson see H. C. Jones. 870. (G. jager. Sitzber. Akad. Wien. 104, 2a, 408-425, (1895). Ueber die elektrolytische Leitfahigkeit von wasserigen Losungen, inbesondere deren Abhangigkeit von der Temperatur.) [Inorganic. ] 871. (G. Jager. Sitzber. Akad. Wien. 104, 2a, 671-679, (1895). Zur Theorie der Dissociation der Gase.) 872. G. Jaffe. Ann. Physik. (4), 25, 257-284, (1908). Ueber die lonisation fltissiger Dielektrika durch Radiumstrahlen. 873. G. Jaffe. Ann. Physik. (4), 28, 326-370, (1909). Die elektrische Leitfahigkeit des reinen Hexans. T=0°to40°. AUTHOR LIST 453 873a. G. JafEe. Ann. Physik. (4), 32, 148-178, (1910). Ueber die spezifische Geschwindigkeit und Wiedervereinigimg der lonen in Hexan. 874. G. Jaffe. Jour. Phys. (4), 5, 263-270, (1906). Sur la conductibilit6 flectrique de I'^ther de p6trole sous Taction du radium. 875. H. Jahn. Zeit. Phys. Chem. 16, 72-90, (1895). Meas. E. Schroder. Ueber die Abhangigkeit des Dissociationszustandes einiger Sauren der Pett- reihe von der Temperatur. T = 10°to54°± 0.1°. S. U. xaq. sub. 876. (H. Jahn. Zeit. Phys. Chem. 58, 641-658, (1907). Ueber die Wanderungsgeschwindigkeit der lonen in verdiinnten Losungen.) [Inorganic. ] 877. A. A. Jakowkin. Zeit. Phys. Chem. 29, 613-657, (1899). Ueber die Hydrolyse des Chlors. T = 25°and0° 877a. (A. A. Jakowkin. Zeit. Phys. Chem. 70, 158-197, (1910). Zur Theorie der Losungen.) 878. A. JappeUi. Zeit. Biol. 51, 435-459, (1908). Untersuchimgen iiber die Speichelabsonderung. IV. Einfluss einiger Nicht- Elektrolyten auf die physiko-chemischen Eigenschaften des Blutes und des Speichels und auf die Speichelsekretion. A. Jappelli see F. Bottazzi. " " see F. Bottazzi, G. Buglia. 879. G. JappeUi. Zeit. Biol. 48, 398-431, (1906). Ueber die physiko-chemischen Bedingungen der Speichelabsonderung. 880. G. Jappelli. Zeit. Biol. 51, 42-78, (1908). Untersuchungen tiber die Speichelabsonderung. II. Speichelvarietaten und Einfluss des Reizungsortes auf die physiko-chemischen Eigenschaften des Unterkieferspeichels. T = 37°. 881. G. JappeUi. Zeit. Biol. 51, 127-176, (1908). Untersuchungen iiber die Speichelabsonderung. III. Einfluss der Frequenz, Intensitat und Dauer der elektrischen Reize auf die physiko-chemischen Eigenschaften des Speichels. T = 37°. 881a. A. Jaques. Trans. Faraday Soc. 5, 225-243, (1910). Contributions to the study of ionisation in aqueous solutions of lead acetate and cadmium acetate. T=25°. 882. G. F. Jaubert. Ber. Deutsch. Chem. Ges. 28, 1578-1585, (1895). Meas. A. Miolati. Ueber Beziehungen der Safranine zu den Mauve'inen und Indulinen. T = 25°. 883. (G. Jaumann. Ann. Physik. (4), 3, 578-617, (1900). Zur Theorie der Losungen.) [Same as 884.] 884. (G. Jaumann. Sitzber. Akad. Wien. 109, 2a, 512-553, (1900). Zur Theorie der Losungen.) [Same as 883.] K. Jaunsnicker see C. A. Bischoff. W. P. Javorskij see J. L Michajlenko. 885. P. Jehl. Dis. Strassburg. (1901). Ueber die sechs stereoisomeren Phenylparaconsauren. [Same as 579. ] T=20°. R. O. Meas. P. Jehl; see 579. 454 AUTHOR LIST 886. S. M. Jorgensen. Zeit. Anorg. Chem. 19, 10^157, (1899). Meas. E. Petersen. Zur Konstitution der Kobalt-, Chrom- und Rhodiumbasen. T = 25°. F. M. G. Johnson see J. W. Walker. 887. F. M. G. Johnson, D. Mcintosh. Jour. Am. Chem. See. 31, 1138-1144, (1909). Liquid chlorine. T below -34°- J. M. Johnson see S. F. Acree. 888. J. Johnston. Ber. Deutsch. Chem. Ges. 37, 3625-3627, (1904). Ueber den amphoteren Charakter der Kakodylsaure. T= 25°. xi8aq.= 0.65X10-^; not sub. 889. J. Johnston. Jour. Am. Chem. See. 31, 1010-1020, (1909). The change of the equivalent conductance of ions with the temperature. 890. J. Johnston. Zeit. Phys. Chem. 57, 557-573, (1906). Die Affinitatskonstanten amphoterer Elektrolyte. I. Methylderivate der p- Amidobenzoesaure und des GlykokoUs. [Same as 891.] T = 25°. X25aq. =1.5X10-"; not sub. 891. J. Johnston. Proc. R. Soc. London. A, 78, 82-102, (1906). The afiSnity constants of amphoteric electrolytes. I. -Methyl derivatives of pararaminobenzoic acid and of glycine. [Same as 890.] Meas. J. Johnston; see 1868, 1877. J. Johnston see A. A. Noyes. 892. (S. M. Johnston. Trans. R. Soc. Edinburgh. 45, 193-240, (1905-1907). On the elevation of the boiling points of aqueous solutions of electrolytes.) [Inorganic. ] 893. (S. M. Johnston. Trans. R. Soc. Edinburgh. 45, 855-884, (1905-1907) . The boiling and freezing points of concentrated aqueous solutions, and the question of the hydration of the solute.) [Inorganic] T = 0°and 99.4°. Jolivet see Pelet-Jolivet. 894. H. C. Jones. Am. Chem. Jour. 16, 1-19, (1894). On the combination of sulphuric acid with water in the presence of acetic acid. [Same as 900.] T=25°. S. U. 895. H. C. Jones. Am. Chem. Jour. 18, 623-624, (1896). The conductivity of solutions of acetylene in water. [A correction of 902. ] 896. (H. C. Jones. Am. Chem. Jour. 25, 232-249, (1901). The dissociating power of different solvents. A summary.) [A fairly com- plete review of the literature up to that date. ] 897. (H. C. Jones. Am. Chem. Jour. 35, 445-450, (1906). The bearing of hydrates on the temperature coefficients of conductivity of aqueous solutions.) [Same as 899. Inorganic] 898. (H. C. Jones. Am. Chem. Jour. 41, 19-57, (1909). The present status of the solvate theory.) [A summary of his work done with others. ] 899. (H. C. Jones. Chem. News. 93, 274-275, (1906). The bearing of hydrates on the temperature coefficients of conductivity of aqueous solutions.) [Same as 897.] 900. H. C. Jones. Zeit. Phys. Chem. 13, 419-436, (1894). Ueber die Verbindung von Schwefelsaure mit Wasser in Gegenwart von Essigsaure. [Same as 894. ] T = 25°. S. U. AUTHOR LIST 455 901. H. C. Jones. Zeit. Phys. Chem. 55, 385-434, (1906). Die annahernde Zusammensetzung der Hydrate, welche von verschiedenen Elektrolyten in wasseriger Losung gebildet werden. [This seems to be a summary of his previous work with others. See 903 and 910.] T = 0°and25°. S. U. 901a. (H. C. Jones. Zeit. Phys. Chem. 74, 325-379, (1910). Im hiesigen Laboratorium wahrend der vergangenen zwolf Jahre erhaltene Anhaltspvmkte fur die Existenz von Solvaten in Losung. ) [Conclusions drawn from work by himself and others. See 894 and the references that follow. ] H. C. Jones see A. M. Clover. " " " see M. R. Schmidt. " " " see G. F. White. 902. H. C. Jones, C. R. Allen. Am. Chem. Jour. 18, 375-377, (1896). Meas. C. B. Allen. The conductivity of solutions of acetylene in water. [See correction in 896.] T is about 0°. S. U. 903. H. C. Jones, H. P. Bassett. Am. Chem. Jour. 34, 290-349, (1905). The approximate composition of the hydrates formed by a number of electro- lytes in aqueous solutions; together with a brief general discussion of the re- sults thus far obtained. T=0°and25°. S. U. 904. H. C. Jones, E. C. Bingham. Am. Chem. Jour. 34, 481-554, (1905). a Meas. L. McMaster. The conductivity and viscosity of solutions of certain salts in mixtures of acetone with methyl alcohol, with ethyl alcohol, and water. [Same as 187. Given in 905 and 906.] T = 25°. S. U. 906. H. C. Jones, E. C. Bingham, L. McMaster. Zeit. Phys. Chem. 57, 193-243, (1906). Ueber Leitfahigkeit und innere Reibung von Losungen gewisser Salze in den Losungsmittelgemischen; Wasser, Methylalkohol, Aethylalkohol und Aceton. T=0°and25°. Xo aq. = 1 X 10"^. S. TJ. [This is a summary of work by Jones and the others. See 904 and 918. ] 906. H. C. Jones, E. C. Bingham, L. McMaster. Zeit. Phys. Chem. 57, 257-320, (1906). Ueber Leitfahigkeit und innere Reibung von Losungen gewisser Salze in den Losungsmittelgemischen; Wasser, Methylalkohol, Aethylalkohol und Aceton. T=0°and25°- S. U. [A continuation of 905. See 992 for correction regarding priority.] 907. H. C. Jones, B. P. Caldwell. Am. Chem. Jour. 25, 349-390, (1901). Contribution to the study of aqueous solutions of double salts. IV. Iodides, cyanides, nitrates and sulphates. T = 25°. S. U. xaq. = 1.10-3.0X10-8; sub. 908. H. C. Jones, C. G. Carroll. Am. Chem. Jour. 32, 521-583, (1904). A study of the conductivities of certain electrolytes in water, methyl and ethyl alcohols, and mixtures of these solvents. Relation between conductivity and viscosity. [Same as 357. Given in 913. ] T = 0° and 25°. S. U. x of solvent is sub. 909. (H. C. Jones, J. M. Douglas. Am. Chem. Jour. 26, 428-453, (1901). The dissociation of certain acids, bases and salts at different temperatures). [Same as 467. Inorganic. ] T=0°to35°. 456 AUTHOR LIST 910. H. C. Jones, F. H. Getman. Am. Chem. Jour. 32, 308-338, (1904). The existence of hydrates in solutions of certain non-electrolytes and the non- existence of hydrates in solutions of organic acids. T=0°- S. U. 911. H. C. Jones, C. A. Jacobson. Am. Chem. Jour. 40, 355-410, (1908). The conductivity and ionization of electrolytes in aqueous solutions as con- ditioned by temperature, dilution and hydrolysis. [Same as 869.] T = 0°, 10°, 25° and 35°. S. U. kh. aq. = 1.6-2.2X10-8; sub. 912. H. C. Jones, C. F. Lindsay. Am. Chem. Jour. 28, 329-370, (1902). A study of the conductivity of certain salts in water, methyl, ethyl, and propyl alcohols, and in mixtures of these solvents. [Same as 1109. Given in 913. ] S. U. 913. H. C. Jones, C. F. Lindsay, C. G. Carroll. Zeit. Phys. Chem. 56, 129- 178, (1906). Ueber die Leitfahigkeit gewisser Salze in gemischten Losungsmitteln; Wasser, Methyl-, Aethyl- und Propylalkohol. [A summary of 908 and 912.] T varies. S. U. x aq. = 2 - 0.8 X 10-«. 914. (H. C. Jones, E. Mackay. Am. Chem. Jour. 19, 83-118, (1897). A contribution to the study of water solutions of some of the alums.) [In- organic. ] 915. (H. C. Jones, E. G. Mahin. Am. Chem. Jour. 41, 433-442, (1909). The conductivity of solutions of Uthium nitrate in ternary mixtures of ace- tone, methyl alcohol, ethyl alcohol, and water; together with the viscosity and fluidity of these mixtures.) [Inorganic] 916. H. C. Jones, E. G. Mahin. Zeit. Phys. Chem. 69, 389-418, (1909). Conductivity and viscosity of dilute solutions of lithium nitrate and cadmium iodide in binary and ternary mixtures of acetone with methyl alcohol, ethyl alcohol and water. T = 0°and25°. S. U. xo aq. = 1.2X10-^ 917. H. C. Jones, L. McMaster. Am. Chem. Jour. 35, 316-326, (1906). On the formation of alcoholates by certain salts in solution in methyl and ethyl alcohols. S. U. 918. H. C. Jones, L. McMaster. Am. Chem. Jour. 36, 325-409, (1906). The conductivity and viscosity of solutions of certain salts in water, methyl alcohol, ethyl alcohol, acetone and binary mixtures of these solvents. [Given in 906 and 906.] T=0°and25°. S. U. X26 aq. = 1.5-2.0X10-«. 919. (H. C. Jones, J. N. Pearce. Am. Chem. Jour. 38, 683-743, (1907). Dissociation as measured by freezing point lowering and by conductivity. Bearing on the hydrate theory. The approximate composition of the hydrates formed by a number of electrolytes.) [Inorganic] 920. H. C. Jones, C. A. Rouiller. Am. Chem. Jour. 36, 427-487, (1906). The relative migration velocities of the ions of silver nitrate in water, methyl alcohol, ethyl alcohol and acetone, and in binary mixtures of these solvents, together with the conductivity of such solutions. T = 0°and25°. S. U. xo aq. = 1.0X10-5. 921. (H. C. Jones, C. M. Stine. Am. Chem. Jour. 39, 313-402, (1908). The effect of one salt on the hydrating power of another salt present in the same solution.) [Inorganic] 922. H. C. Jones, W. R. Veazey. Zeit. Phys. Chem. 61, 641-697, (1907- 1908). Die Leitfahigkeit und innere Reibung von Losungen gewisser Salze in Wasser, AUTHOR LIST 457 Methylalkohol, Aethylalkohol, Aceton und binaren Gemischen dieser Losungs- mittel. [Same as 1772.] T= 0° and 25°. S. U. xzb aq.= 1.8-2.5X10-°. 923. H. C. Jones, W. R. Veazey. Zeit. Phys. Chem. 62, 44-58, (1908). Die Leitfahigkeit und innere Reibung von Tetraathylammoniumjodid in Wasser, Methylalkohol, Aethylalkohol, Nitrobenzol und binaren Gemischen dieser Losungsmittel. T=0°and25°. 924. H. C. Jones, A. P. West. Am. Chem. Jour. 34, 357-422, (1905). A study of the temperature coefficients of conductivity in aqueous solutions and on the effect of temperature on dissociation. [Same as 1953.] T=0°to35°. S. U. JC26aq. = 1.5-2.0X10-6. H. O. Jones see H. J. H. Fenton. 925. (H. O. Jones, O. W. Richardson. Jour. Chem, Soc. 81, 1140-1158, (1902). The decomposition of oxalacetic acid phenylhydrazone in aqueous and acid solutions, and a new method of determining the concentration of hydrogen ions.) [A correction of 561 and 563. See also 926 and 927. ] 926. H. O. Jones, O. W. Richardson. Jour. Chem. Soc. 81, 1158-1160, (1902). The dissociation constants of oxalacetic acid and its phenylhydrazone. [Same as 929. See correction in 1991.] T = 25° 927. (H. O. Jones, O. W. Richardson. Proc. Cambridge Phil. Soc. 11, 337-339, (1900-1902). Note on a method for determining the concentration of hydrogen ions in solu- tion.) [Corrects 563. An abstract of 925.] 928. (H. O. Jones, O. W. Richardson. Proc. Chem. Soc. 18, 140-141, (1902). The decomposition of oxalacetic hydrazone in aqueous and acid solutions, and a new method of determining the concentration of hydrogen ions in solution.) [An abstract of 925. ] 929. H. O. Jones, O. W. Richardson. Proc. Chem. Soc. 18, 141, (1902). The dissociation constants, etc. [Same as 926.] Meas. Jordis; see 314. 930. (P. Joubin. Compt. Rend. 124, 228-229, (1897). Sur la conductibUit^ molficulaire des sels en dissolution ^tendue.) 931. G. Just. Zeit. Elektrochem. 10, 202-204, (1904). Ueber Benzinbrande. T about 15°. R. O. K. 932. I. Kablukoff. Jour. Russ. Phys.-chem. Soc. 23, 391-422, (1891). On the electrical conductivity of hydrochloric acid in different solvents and on the electrical conductivity of acids dissolved in aqueous alcohol. T = 10° to 80° [Almost the same as 933, but has more measurements.] 933. (I. Kablukoff. Zeit. Phys. Chem. 4, 429-434, (1889). Ueber die elektrische Leitfahigkeit von Chlorwasserstoff in versohiedenen Losungsmitteln.) [Same as 932, except that there is no measurement of the chloroacetic acids.] Kablukov see Kablukoff. 934. L. Kahlenberg. Jour. Phys. Chem. 5, 339-392, (1901). The theory of electrolytic dissociation as viewed in the light of facts recently ascertained. [Chiefly theoretical; the measurements are qualitative.] 458 AUTHOR LIST 935. L. KaMenberg. Jour. Phys. Chem. 6, 1-14, (1902). Instantaneous chemical reactions and the theory of electrolytic dissociation. [Qualitative. ] 936. L. Kahlenberg. Jour. Phys. Chem. 6, 45-49, (1902). NitrUes as solvents in molecular weight determinations. [Qualitative.] 937. (L. Kahlenberg. Phil. Mag. (6), 9, 214-229, (1905). Recent investigations bearing on the theory of electrolytic dissociation.) 938. L. Kahlenberg. Zeit. Phys. Chem. 17, 577-619, (1895). TJeber komplexe Tartrate und gewisse alkalische Losungen des Kupfers und des Bleies. 939. L. Kahlenberg. Zeit. Phys. Chem. 46, 64-69, (1903). On the electrical conductivity of solutions in sulphocyanates and mustard oils. T = 25°. R. O. 940. (L. KaMenberg. Trans. Am. Electrochem. Soc. 13, 265-272, (1908). On the nature of electrolytic conductors.) [Theoretical; with some quaUtative statements. ] 941. L. Kahlenberg, A. T. Lincohi. Jour. Phys. Chem. 3, 12-35, (1899). The dissociative power of solvents. [Given in 1107. ] T = 25°. 942. L. Kahlenberg, O. E. Ruhoff. Jour. Phys. Chem. 7, 254-258, (1903). On the electrical conductivity of solutions in amyl amine. T=25°. R. O. 943. L. Kahlenberg, H. Schlundt. Jour. Phys. Chem. 6, 447-462, (1902). Solubility, electrolytic conductivity and chemical action in liquid hydrocyanic acid. T=0°. R. O. 944. L. Kahlenberg, O. Schreiner. Zeit. Phys. Chem. 20, 547-568, (1896). Ueber Borsaure und ihrer Salze. 946. L. Kahlenberg, O. Schreiner. Zeit. Phys. Chem. 27, 552-566, (1898). Die wasserigen Losungen der Seifen. T=25°; for part is 25° to 80°. S. U. M. Kalb see A. Hantzsch. 946. (F. Kalkow. Dis. Halle. (1897). TJeber die Formaldehyd- Verbindung des Hydroresorcins.) [No conductivity. ] F. Kalkow see D. Vorlander. H. T. Kalmus see H. M. Goodwin. " " " see R. Lorenz. 947. A. Kanitz. Arch. Gesammt. Physiol. 118, 539-546, (1907). Die Affinitatskonstanten des Tyrosins und des Phenylalanins. T = 25°. S. U. xaq.=2.2X10-^ sub. 948. A. Kanitz. Zeit. Physiol. Chem. 47, 476-495, (1906). Die Affinitatskonstanten einiger Eiweissspaltungsprodukte. T = 25°±0.05°- S. U. X aq. = 1.6-2X10-*'; not sub. unless so stated. 949. C. W. Kanolt. Jour. Am. Chem. Soc. 29, 1402-1416, (1907). Ionization of water at 0°, 18° and 25° derived from conductivity measure- ments of the hydrolysis of the ammonium salts of diketotetrahydrothiazole. T=0.00°, 18.00° and 25.00°±0.01°. R. O. Kn aq.= 0.15-0.60X10-8; sub. C. W. Kanolt see J. L. R. Morgan. T. Karaulow see L. Asher. L. Karczag see G. Buglia. E. Karp see L. Pissarjewsky. AUTHOR LIST 459 950. J. H. Kastle. Am. Chem. Jour. 33, 46-59, (1905). A method for the determination of the aflSnities of acids colorimetrically, by means of certain vegetable coloring matters. 951. J. H. Kastle, B. C. Keiser. Am. Chem. Jour. 17, 443-449, (1895). On the determination of the affinities of acids colorimetrically by means of potassium dichromate. Meas. Y. Eato; see 1341. Y. Kato see A. A. Noyes. 952. ( H. Kauffmann. Ber. Deutsch. Chem. Ges. 37, 2468-2469, (1904). Zur Theorie der Pseudosauren.) 953. (H. Kauffmann. Ber. Deutsch. Chem. Ges. 41, 4396-4412, (1908). Ueber den Nitro-hydrochinondimethylather und zur Theorie der Losungen.) 954. (H. Kauffmann. Zeit. Phys. Chem. 47, 618-624, (1904). Zur Theorie der Pseudosauren.) [Quoted.] F. Kaufler see R. Lorenz. L. Kaufmann see A. Hantzsch. 955. W. Kawalki. Ann. Physik. (3), 52, 166-190, (1894). Untersuchungen iiber die Diffusionsfahigkeit einiger Electrolyte in Alkohol. T = 18°. 956. W. Kawalki. Ann. Physik. (3), 52, 300-327, (1894). Untersuchungen tiber die Diffusionsfahigkeit einiger Electrolyte in Alkohol. S. A. Kay see J. Walker. 956a. F. Kehrmann. Ann. Chemie. 372, 287-355, (1910). Meas. W. J. Muller. Xanthen imd Triphenylmethan. [Measurement of the free ester is given in 1292a.] T=0°andl8° B. C. Keiser see J. H. Kastle. Meas. Kellas; see 401. 957. H. Keller. Dis. Heidelberg. (1902). Dynamische Untersuchungen iiber die Bildimg von Azofarbstoffen. [Same as 660, but contains also the constant of dipropylaniline. ] T=25°. H. Keller see H. Goldschmidt. 958. A. Kerler. Dis. Erlangen. (1894). Molekulargewichtsbestimmungen von Salzen in Methyl- und Aethylalkohol nach der Siedemethode neben Bestimmungen der molekularen Leitfahigkeit derselben Salze in obigen Losungsmitteln und in Wasser. 959. W. Kerp, E. Baur. Arbeit, k. Gesundh. 26, 231-268, (1907). Zur Kenntnis der gebundenen schwefligen Sauren. T = 25°. R. O. X aq. =0.6 [X10-«?]; sub. for sodium salt. 960. (W. Kerp, E. Baur. Arbeit, k. Gesundh. 26, 297-300, (1907). Ueber die elektrolytische Dissoziationskonstante der schwefligen Saure.) T=25°. R. O. xaq. =5.8X10-'. 961. W. Kerp, P. "Wohler. Arbeit, k. Gesundh. 32, 89-119, (1909). Zur Kenntnis der gebundenen schwefligen Sauren. IV. Abhandlung; Ueber die Verbindungen der schwefligen Saure mit dem Citronellal und dem Zimt- aldehyd. 962. W. Kerp, P. Wohler. Arbeit, k. Gesundh. 32, 120-143, (1909). Zur Kenntnis der gebundenen schwefligen Sauren. V. Abhandlung; Ueber Sulfitzellulose- Ablauge und furfurolschweflige Saure. T = 25° 963. R. Kieseritzky. Zeit. Phys. Chem. 28, 385-423, (1899). Elektrometrische Konstitutionsbestimmungen. [Same as 964. ] 460 AUTHOR LIST 964. R. Kieseritzky. Dis. Leipzig. (1899). Elektrometrische Konstitutionsbestimmungen. [Same as 963.] 965. F. S. Kipping. Jour. Chem. Soc. 67, 139-155, (1895). Meas. J. Walker. Stereoisomeric aa'-dimethylpimelic acids. H. Kinnreuther see K. A. Hofmann. 966. A. Kirpal. Monatsh. 18, 461^66, (1897). Zur Kenntniss der Hemipinsaure und der isomeren Estersauren der Papaver- insaure. [Same as 968. ] T = 25°. xaq. = 1.7X10-". 967. A. Kirpal. Monatsh. 28, 43^-445, (1907). Leitfahigkeitsmessungen an den isomeren Estersauren der Chinolin- und Cinchomeronsaure. [Same as 969.] X aq.=2.24X10-^ 968. A. Kirpal. Sitzber. Akad. Wien. 106, 2b, 460-465, (1897). Zur Kenntniss der Hemipinsaure, etc. (Same as 966. ] 969. A. Kirpal. Sitzber. Akad. Wien. 116, 2b, 337-343, (1907). Leitfahigkeitsmessungen an den isomeren Estersauren, etc. [Same as 967.] Meas. Kissel ; see 425. H. Kissel see A. Hantzsch. " " see H. Ley. Kistiakovskij see Kistiakowsky. 970. W. Kistiakowsky. Jour. Russ. Phys.-chem. Soc. 22, 411-430, (1890). Aqueous solutions of double salts. [Same compounds as in 971, but with additional measurements.] T = 18° and 25° Xis aq. about 2.1 XlO-«; [probably sub.]. 971. "W. Kistiakowsky. Zeit. Phys. Chem. 6, 97-121, (1890). Die wasserigen Losungen von Doppelsalzen. [Given in 970.] T = 18° and 25°. xis aq. about 2.1 X ID-"; [probably sub. ]. 972. P. Klason, T. Carlson. Ber. Deutsch. Chem. Ges. 39, 732-738, (1906). Zur Kenntniss der Thioglykolsaure. [Same as 973.] T = 25°. R. 0. X25aq. = 1.6X10-«; notsub. 973. P. Klason, T. Carlson. Arkiv Kemi. 2, no. 19, 1-9, (1905-1907). Zur Kenntnis der Thioglykolsaure. [Same as 972.] C. Kleber see F. Stohmann. 974. (Z. Klemensiewicz. Bui. Acad. Cracov. (1908), 485-494. Antimonchloriir als ionisierendes Losungsmittel.) [Inorganic] Meas. R. Klien; see 1947. 976. A. Kling. Ann. Chim. Phys. (8), 5, 471-659, (1905). Contribution ^ I'^tude des alcools cStoniques. [Measurements same as 976, but table also is given. ] T = 10.7° and 10.8°. 976. A. Kling. Bui. Soc. Chim. (3), 33, 755-760, (1905). Sur les solutions aqueuses d'ac^tol. [Curve of measurements same as 975, but no table. ] 976a. E. Knecht, J. P. Batey. Jour. Soc. Dyers Colour. 25, 194-203, (1909). On the condition of some dyestuffs in aqueous solution. T = 18°and90°. R. O. 976b. E. Knecht, J. P. Batey. Jour. Soc. Dyers Colour. 26, 4-5, (1910). On the condition of Indigo White in aqueous solution. [Given accurately in 976c.] T = 18° R. O. AUTHOR LIST 461 976c. E. Knecht, J. P. Batey. Jour. Soc. Dyers Colour. 26, 171-173, (1910). On the condition of Indigo White in aqueous solution. [The measurements in 976b are of an impure compound.] T = 18°. R. O. L. E. Knight see J. K. H. IngUs. 977. L. Knorr. Ber. Deutsch. Chem. Ges. 28, 706-714, (1895). Ueber Abkonunlinge der PhenoUorm des l-Phenyl-3-methyl-5-pyrazolons. [Qualitative. ] L. D. Kobozev see V. F. Timofejev. 978. K. R. Koch. Ann. Physik. (3), 50, 482-484, (1893). Notiz iiber eine einfache Methode, um dieleotrische Fliissigkeiten auf ihr Leitungsvermogen zu untersuchen. E. Kobner see K. Auwers. jilMeas. R. Koefoed; see 1639b. 979. K. KoeUchen. Zeit. Phys. Chem. 33, 129-177, (1900). Die chemische Dynamik der Acetonkondensation. [Same as 980. ] 980. K. KoeUchen. Dis. Leipzig. (1900). Die chemische Dynamik der Acetonkondensation. [Same as 979. ] 981. (W.Koemgs,A.Eppens. Ber. Deutsch. Chem. Ges. 26,810-811,(1893). Ueber das Campherphoron.) [See 503 for measurements.] 982. (J. Koenigsberger. Phys. Zeit. 8, 833-836, (1907). Ueber die Elektrizitatsleitung in festen Korpem und die Elektronentheorie derselben.) 983. (J. Koenigsberger. Zeit. Elektrochem. 15, 97-105, (1909). Ueber Elektrizitatsleitung.) 983a. J. Koenigsberger, K. Schilling. Ann. Physik. (4), 32, 179-230, (1910). Ueber Elektrizitatsleitung in festen Elementen und Verbindungen. T = 20°to302°. 984. (F. KSrber. Zeit. Phys. Chem. 67, 212-248, (1909). Ueber den Einfluss des Druckes auf das elektrolytische Leitvermogen von Losungen.) [Inorganic. Some bibhography. See 1154, for priority claim.] 985. (F. Kohlrausch. Ann. Physik. (3), 66, 785-825, (1898). Die BewegUchkeiten electrischer lonen in verdtinnten wasserigen Losungen bis zu 1-10 normaler Concentration bei 18°.) [Quoted.] 986. F. Kohlrausch. Ann. Physik. Erganz. 8, 1-16, (1878). Ueber das elektrische Leitungsveniiogen des Wassers imd einiger anderer schlechter Leiter. S. U. 987. (F. Kohkausch. Zeit. Elektrochem. 13, 333-344, (1907). Ueber lonenbeweglichkeiten im Wasser.) 988. (F. Kohlrausch. Zeit. Elektrochem. 14, 129-133, (1908). Der Temperaturkoeffizient der lonenbeweglichkeiten im Wasser als Funktion der Beweglichkeit selbst.) [Inorganic. ] 989. (F. Kohlrausch. Zeit. Phys. Chem. 18, 662, (1895). Ueber die Formel von van't Hoff fiir das Verdtinnungsgesetz bei Salzen.) 990. F. Kohh-ausch. Zeit. Phys. Chem. 44, 197-249, (1903). j^Meos. F. Rose. Ueber gesattigte wassrige Losimgen schwerlosUcher Salze. I. Teil; Die elek- trischen Leitvermogen. T = 18°. R. O. xaq. sub. 991. F. Kohlrausch. Zeit. Phys. Chem. 50, 355-356, (1905). Die LosUchkeit einiger schwerlosUcher Salze in Wasser bei 18°. [This is a revision of 1004.] T = 18°- 462 AUTHOR LIST 992. (F. Kohlrausch. Zeit. Phys. Chem. 58, 630-631, (1907). Ueber den Temperaturgang des Leitvermogens einer Losung.) [A correction of 906 regarding priority.] 993. F. Kohlrausch. Zeit. Phys. Chem. 64, 129-169, (1908). Ueber gesattigte wasserige Losungen schwerlosUcher Salze. II. Teil; Die gelosten Mengen mit ihrem Temperaturgang. T = 0°to38°. xaq. sub. 994. F. KoWrausch. Sitzber. K. Preuss. Akad. Berlin. (1900), 1002-1008. Ueber das elektrische Leitvennogen von Losungen der Alkali- Jodate und eine Formel zur Berechnung von Leitvermogen. [Inorganic. ] 995. (F. Kohkausch. Sitzber. K. Preuss. Akad. Berlin. (1901), 1026-1033. Ueber den Temperatureinfluss auf das elektrische Leitvermogen von Losungen, insbesondere auf die BewegUchkeit der einzelnen lonen in Wasser.) 996. (F. Kohlrausch. Sitzber. K. Preuss. Akad. Berlin. (1902), 572-580. Ueber die Temperaturcoefficienten der lonen im Wasser, insbesondere uber ein die einwerthigen Elemente umfassendes Gesetz.) 997. F. Kohlrausch, E. Griineisen. Sitzber. K. Preuss. Akad. Berlin. (1904), 1215-1222. Das Leitvermogen wasseriger Losungen von Elektrolyten mit zweiwertigen lonen. 998. (F. Kohkausch, W. Hallwachs. Ann. Physik. (3), 50, 118-126, (1893). Ueber die Dichtigkeit verdunnter wasseriger Losungen.) 999. F. Kohlrausch, A. Heydweiller. Ann. Physik. (3), 53, 209-235, (1894). Ueber reines Wasser. [Same as 1000 and 1001.] T= -3° to +51.0°. Hg. U. 1000. F. Kohlrausch, A. Heydweiller. Zeit. Phys. Chem. 14, 317-330, (1894). Ueber reines Wasser. [Same as 999 and 1001.] 1001. F. Kohlrausch, A. Heydweiller. Sitzber. K. Preuss. Akad. Berlin. (1894), 295-308. Ueber reines Wasser. [Same as 999 and 1000. ] 1002. (F. Kohlrausch, L. Holbom, H. Diesselhorst. Ann. Physik. (3), 64, 417-455, (1898). Neue Grundlagen fiir die Werthe der Leitvermogen von Electrolyten.) 1003. F. Kohlrausch, F. Mylius. Sitzber. K. Preuss. Akad. Berlin. (1904), 1223-1227. Ueber wassrige Losungen des Magnesiumoxalats. T = 18°. 1004. F. Kohlrausch, F. Rose. Ann. Physik. (3), 50, 127-137, (1893). Die Loslichkeit einiger schwer loslicher Korper im Wasser, beurtheilt aus der electrisohen Leitungsfahigkeit der Losungen. [Same as 1005 and 1006. See 991 for correction. ] T =2° to 42° Hg. U. K aq. sub. 1005. F. Kohh-ausch, F. Rose. Zeit. Phys. Chem. 12, 234r-243, (1893). Die Loslichkeit einiger schwer loslicher Korper, etc. [Same as 1004 and 1006.] 1006. F. Kohlrausch, F. Rose. Sitzber. K. Preuss. Akad. Berlin. (1893), 453-462. Die Loslichkeit einiger schwer loslicher Korper, etc. [Same as 1004 and 1005. ] 1007. F. Kohlrausch, H. v. Steinwehr. Sitzber. K. Preuss. Akad. Berlin. (1902), 581-587. Weitere Untersuchungen tiber das Leitvermogen von Elektroljrten aus ein- Tverthigen lonen in wasseriger Losung. T = 18°- AUTHOR LIST 463 1008. V. Kohlschiitter, C. Brittlebank. Ann. Chemie. 349, 232-268, (1906) Ueber Thiohamstoffcuprosalze. T=25°. 1009. H. KoUer. Phil. Mag. (5), 27, 526-527, (1889). On the passage of electricity through bad conductors. [An abstract of 1010.] 1010. H. KoUer. Sitzber. Akad. Wien. 98, 2a, 201-266, (1899). Ueber den Durchgang von Elektricitat durch sehr schlechte Leiter. [Ab- stracted in 1009.] S. U. Meas. Eoller; see 1471. Konovalofi see Konowalow. Konovalov see Konowalow. 1011. D. Konowalow. Ann. Physik. (3), 49, 733-760, (1893). $Meas. Isaposhnikow. Ueber die Eigenschaften der Losungen, welche Amine mit Sauren bilden. [This contains both 1012 and 1013.] T=21°andl6°. Hg. U. 1012. D. Konowalow. Jour. Russ. Phys.-chem. Soc. 24, 440-450, (1892). On the electrical conductivity of solutions. [Same as part of 1011.] T = 21°andl6°. Hg. U. 1013. D. Konowalow. Jour. Russ. Phys.-chem. Soc. 25, 192-201, (1893). ^Meas. Sa-p6znikov. On the electrical conductivity of solutions. [Same as part of 1011.] 1014. (D. Konowalow. Jour. Russ. Phys.-chem. Soc. 25, 211-222, (1893). Heat phenomena produced by mixtures of amines with acids.) Meas. I. Koppel; see 1516. 1015. (J. Koppel. Zeit. Anorg. Chem. 28, 461-473, (1901). Alkoholhaltige Chromihalogenverbindungen.) [Inorganic] T = 0°to70°. 1016. A. V. Korinyi, J. Bence. Arch. Gesammt. Physiol. 110, 513-532, (1905). PhysikaUsch-chemische Untersuchungen tiber die Wirkung der Kohlensaure auf das Blut. 1017. F. Koritschoner. Zeit. Angew. Chem. 20, 641-645, (1907). Beitrage zur Kenntnis der Abietinsaure. T=25°. F. Korten see E. Rimbach. 1018. F. L. Kortright. Am. Chem. Jour. 18, 365-371, (1896). The heat of electrolytic dissociation of some acids. T=0°. Xo aq. = 1.7X10-^; not sub. from acids, sub. from salts. 1019. (J. Kossonogoff. Phys. Zeit. 3, 207-208, (1901-1902). Zur Frage der Dielektrika.) 1020. (J. Kowalski. Bui. Acad. Cracov. (1891), 255-258. Ueber den Einfluss des Druckes auf die elektrische Leitungsfahigkeit der Elektroljrte.) [Inorganic. ] 1021. J. de Kowalski, B. Zdanowski. Arch. Sci. Phys. Nat. (4), 18, 105-134, (1904). Abstracted in Zeit. Elektrochem. 11, 118-120, (1905). Nouvelle m6thode pour la mesure des resistances §lectrolyi;iques liquides et plusieurs de ses applications. [Part is in 1022.] T = 18.9°- R. O. 464 AUTHOR LIST 1022. J. Kowalski, B. Zdanowski. Bill. Acad. Cracov. (1903), 793-794. Nouvelle m^thode pour la mesure, etc. [An abstract of 1021, but without tables of A.] Meas. J. kozak; see 291. H. Kramer see H. Grossmann. 1023. J. Kraemer. Dis. Munster. (1904). mMeas. A. Rosenheim. Ab- stracted in Zeit. Elektrochem, 10, 930-931, (1904). Beitrag zur Kenntnis der Leitfahigkeit molybdan- und wolframsaurer organ- ischer Complexe. [This appears to be the same Kramer as in 691 and 692. Same measurements as in 691 and 692, with addition of succinic acid with Na2W04.] T = 25°±0.05° R. O. xaq.=2-1.5X10-«; sub. 1024. E. Krannhals. Zeit. Phys. Chem. 5, 250-258, (1890). Elektrische Leitungsfahigkeit einiger Losungen bei Temperaturen zwischen 18° und 100°. T is about 18°, 51°, 82° and 99°. S. U. x aq. =8XlO-«. Krapivin see Krapiwin. S. Krapiwin see W. Zelinsky. 1025. (C. A. Kraus. Phys. Rev. 18, 40-56, (1904). The electrical conductivity of solutions in methyl alcohol in the neighborhood of their critical point.) [Inorganic] 1026. (C. A. Kraus. Phys. Rev. 18, 89-103, (1904). The electrical conductivity of solutions in methyl alcohol in the neighborhood of their critical point.) [Inorganic. ] C. A. Kraus see E. C. Franklin. A. Kreichgauer see R. Schenck. B. Kronig see T. Paul. 1027. O. Kiihling. Ber. Deutsch. Chem. Ges. 38, 1638-1646, (1905). Meas. W. A. Both. Ueber die Elektrolyse des GlykocoUs. 1028. F. W. Kiister. Sitzber. Ges. Naturw. Marburg. (1896), 24r-28. Ueber die Konstitution der Pentachlorpentdiensaure, hergeleitet aus ihrer elektrischen Leitfahigkeit. [Same as 2030.] Meas. F. Kiister; see 2030. [This is the same Kiister as in 1028.] 1029. W. Kiister. Aim. Chemie. 315, 174r-218, (1901). Meas. DiUrich. Ueber die Constitution der Hamatinsauren. T=25°. 1030. W. Kuster. Ann. Chemie. 345, 1-59, (1906). Meas. Haas and Mezger. Ueber die Constitution der Hamatinsauren. T=25°- 1031. W. Kiister. Ann. Chemie. 346, 1-27, (1906). Meas. K. Haas. Ueber die Constitution des Hamopyrrols. T = 25°. 1032. W. Kiister. Ber. Deutsch. Chem. Ges. 35, 1268-1273, (1902). Meas. Westhausser. Beitrage zur Kenntniss der Gallenfarbstoffe. [Qualitative.] 1033. "W. Kiister. Ber. Deutsch. Chem. Ges. 35, 2948-2954, (1902). Meas. O. Mezger. Beitrage zur Kenntniss des Hamatins. [Same as 1252. ] T = 25°. 1034. I. Kukulesko. Jour. Russ. Phys.-chem. See. 28, 293-299, (1896). Meas. Szyszkowski. The preparation and properties of a-dimethyl-j3-isobutylethylenelactic acid. AUTHOR LIST 465 1036. C. KuUgren. Zeit. Phys. Chem. 37, 613-622, (1901). Ueber die Einwirkung von Nichtelektrolyten bei Verseifung von Aethylacetat. [Same as 1037.] T = 20.7°. 1036. C. Kullgren. Zeit. Phys. Chem. 41, 407-426, (1902). Studien uber die Inversion. [Same as 1038. ] T=20°. 1037. C. KuUgren. Bihang Svensk. Vet.-Akad. Hand. 24, Afd. II, no. 3, 1-26, (1898-1899). Icke-elektrolyters inverkan ra reaktionshastigheten vid saponifikation af etylacetat. [Same as 1036.] 1038. C. KuUgren. Bihang Svensk. Vet.-Akad. Hand. 27, Afd. II, no. 2, 1-41, (1902-1903). Studien tiber die Inversion. [Same as 1036.] T = 20°. 1039. C. KuUgren. Dis. Uppsala. (1904). Om metaUsalters hydrolys. 1040. (J. Kunz. Compt. Rend. 135, 788-790, (1902). Sur la conductibilitS des dissolutions aux basses temperatures.) [Same as 1041. Inorganic. ] 1041. (J. Kunz. Zeit. Phys. Chem. 42, 591-596, (1902-1903). Ueber die Abhangigkeit der elektrolytischen Leitfahigkeit von der Temper- atur unter 0°.) [Same as 1040.] T=-69°to0°. 1042. B. Kurilofif. Zeit. Phys. Chem. 23, 90-94, (1897). Anwendung des Massenwirkungsgesetzes zur Untersuchung der organischen Additionsprodukte. Die Reaktion zwischen Pikrinsaure und ^-Naphtol in der wassrigen Losung. T=25°. xaq. =0.35X10-6; not sub. E. K. Kurovskij see S. M. Tanatar. 1043. J. J. van Laar. Zeit. Phys. Chem. 12, 742-750, (1893). Ueber die Dissociationskonstante des Wassers und der Cyanwasserstoffsaure. 1044. (J. J. van Laar. Zeit. Phys. Chem. 58, 567-574, (1907). Ueber den Dissociationsgrad gesattigter Losungen eines Elektrolyten in ver- schiedenen Losungsraitteln, und von Losungen, welohe im Teilungsgleichge- wicht stehen.) 1046. (J. J. van Laar. Zeit. Phys. Chem. 59, 212-217, (1907). Ueber die Loslichkeit von Elektrolyten.) [Quoted.] 1046. (J. J. van Laar. Arch. Mus6e Teyler. (2), 7, 59-95, (1902). Sur la loi de diluation chez les electrolytes fortement dissoci6es.) [Quoted.] 1047. 8. Labendzinski, R. Abegg. Zeit. Elektrochem. 10, 77-81, (1904). Zur Kenntnis der Konstitution von Salzlosungen. Meas. H. Labhardt; see 1612, 1544, 1646. T. H. Laby see G. H. Carse. 1048. (T. H. Laby, G. A. Carse. Proc. Cambridge Phil. Soc. 13, 288-295, (1904-1906). On a relation between the velocity and the volume of the ions of certain organic acids and bases.) [Theoretical and quoted.] W. S. Landis see J. W. Richards. 466 AUTHOR LIST 1049. (W. Landsberger. Zeit. Anorg. Chem. 17, 422-454, (1898). Ein neues Verfahren der Molekelgewichtsbestimmung nach der Siedemethode.) H. Langbein see F. Stohmann. " " see F. Stohmann, C. Kleber. W. Lange see J. Erode. 1050. A. Lapworth. Jour. Chem. Soc. 85, 1206-1214, (1904). Meas. J. Walker. Reactions involving the addition of hydrogen cyanide to carbon compounds. Part II. Cyanohydrins regarded as complex acids. [Qualitative.] 1051. A. Lapworth. Jour. Chem. Soc. 93, 2187-2203, (1908). Meas.. B. W. L. Clarke. An examination of the conception of hydrogen ions in catalysis, salt forma- tion, and electrolytic conduction. 1052. A. Lapworth. Proc. Chem. Soc. 24, 275, (1908). Meas. R. W. L. Clarke. An examination of the conception of hydrogen ions, etc. [Summary of 1061.] 1053. E. Laqueur. Beitr. Chem. Physiol. Pathol. 7, 273-297, (1905-1906). Ueber das Kasein als Saure und seine Unterschiede gegen das durch Lab veranderte Kasein. (Parakasein). Theorie der Labwirkung. T = 25°. R. O. 1054. E. Laqueur, O. Sackur. Beitr. Chem. Physiol. Pathol. 3, 193-224, (1902-1903). Ueber die Saureeigenschaften und das Molekulargewicht des Kaseins und seine Spaltung beim Trocknen. [Part given in 1665. ] T = 25°. R. O. Jcaq.=2.6X10-«; sub. H. Larsen see H. Goldschmidt. 1055. Lassar-Cohn. Ann. Chemie. 251, 335-359, (1889). Electrolyse der Losungen organischer Kaliumsalze und des geschmolzenen Kaliumacetats. 1056. S. V. Laszczynski. Zeit. Elektrochem. 2, 55-57, (1895-1896). Ueber die Leitfahigkeit der Losimgen einiger Salze in Aceton. T = 18°. 1057. S. V. Laszczynski, S. v. Gorski. Zeit. Elektrochem. 4, 290-293, (1897-1898). Leitfahigkeit von Losungen einiger Salze in Pyridin. T = 18°. 1058. W. Latzko. Dis. Basel. (1904). Ueber /37-Diphenylvinylessigsaure und ihre Verwandten. [k is given in 667, but no tables of A are there. ] T = 25°. R. O. W. Latzko see F. Fichter. 1059. (B. Lean. Jour. Chem. Soc. 65, 1024^1028, (1894). Note on the affinities of polybasic acids.) [Same as 1060. Theoretical and quoted. ] 1060. (B. Lean. Mem. Proc. Manchester Lit. Phil. Soc. (4), 9, 19-30, (1895). On the affinities of polybasic acids.) [Same as 1059. ] Meas. M. Lehmann; see 742, 760. M. Lehmann see A. Hantzsch. Leleux see Gin. 1061. E. Lellmami. Ann. Chemie. 270, 204-208, (1892). Ueber die Affinitatsgrossen der Sauren. 1062. E. Lellmann, A. GBrtz. Ann. Chemie. 274, 121-141, (1893). Ueber die Affinitatsgrossen der Basen. AUTHOR LIST 467 1063. E. Lellmann, H. Gross. Ann. Chemie. 260, 269-289, (1890). Ueber die AflBnitatsgrossen der Basen. 1064. E. Lellmann, H. Gross. Ann. Chemie. 263, 286-299, (1891). Ueber die AflBnitatsgrossen der Basen. 1065. E. Lellmann, A. Liebmann. Ann. Chemie. 278, 141-152, (1894). Ueber die AflBnitatsgrossen der Basen. 1066. E. Lellmann, A. Liebmann. Ann. Chemie. 278, 152-173, (1894). Ueber die AflBnitatsgrossen der Sauren. 1067. E. Lellmann, J. Schliemann. Ann. Chemie. 270, 208-235, (1892). Ueber die AflBnitatsgrossen der Sauren. 1068. E. Lellmann, J. Schliemann. Ann. Chemie. 274, 141-156, (1893). Ueber die AflBnitatsgrossen der Sauren. 1069. E. Lellmann, J. SchUemann. Ann. Chemie. 274, 156-173, (1893). Ueber die AflBnitatsgrossen der Sauren. N. Lemcke see L. Pissarjewsky. Lemke see Lemcke. 1070. H. Lemme. Progr. Glauchau. (1897). Aceton als Losungsmittel fiir Salze in chemischer und physikalischer Hinsicht. T = 18°and25°. 1071. R. Lenz. Mem. St. Petersburg. (7), 30, (1882). Abstracted in Beibl. Ann. Physik. 7, 399-406, (1883). Ueber das galvanische Leitungsvermogen alkoholischer Losungen. [Original not examined. The title is that of the abstract.] Lesage see Dongier. 1072. Lesage, Dongier. Compt. Rend. 134, 612-614, (1902). Etude de la fermentation lactique par I'observation de la resistance 61ectrique. T = 16.7°. 1073. Lesage, Dongier. Compt. Rend. 135, 111-113, (1902). R6sistivit6s flectriques de scrums sanguins pathologiques et d'6panchementa s6reux chez I'homme. T = 16.7°. 1074. R. Lessing. Dis. Gottingen. (1902). Meas. V. Rothmund. Ueber l,4^N-Methylpyrrolidindicarbonsaure. Ueber eine Bildung von Phenyl- cyclohexan aus Chinit. [Corrected in 1979.] R. O. R. Lessing see S. B. Schryver. " " see R. Willstatter. 1075. H. Leupold. Dis. Leipzig. (1908). Polymerie als Ursache der Farbverschiedenheit von Acridin- und Chinolin- salzen. [A of sulphate is given in 747.] T=25°. Meas. H. Leupold; see 747. M. G. Levi see G. Carrara. A. Levier see P. Dutoit. 1076. W. Levy. Dis. Berlin. (1904). Studien iiber Molekularverbindungen. I. Doppelsalzbildung imgesattigter Ketone, Aldehyde und Sauren. II. Ueber Platinphosphorhalogenverbin- dungen und ilire Derivate. [Part is same as 1622, but this also gives AatO°.] T = 25°andO°. W. Levy see A. Rosenheim. 1076a. (G. N. Lewis. Zeit. Phys. Chem. 70, 212-219, (1910). The use and abuse of the ionic theory.) [Theoretical and inorganic] 468 AUTHOR LIST 1077. (G. N. Lewis, L. W. Sargent. Jour. Am. Chem. Soc. 31, 355-363, (1909). The potential of the feiro-ferricyanide electrode.) 1078. G. N. Lewis, L. W. Sargent. Jour. Am. Chem. Soc. 31, 363-367, (1909). Potentials between liquids. T=25°. 1079. (G. N. Lewis, P. Wheeler. Zeit. Phys. Chem. 56, 179-192, (1906). Die elektrische Leitfahigkeit von Losungen in flussigem lod.) [Same as 1080. Inorganic. ] 1080. (G. N. Lewis, P. Wheeler. Proc. Am. Acad. Arts Sci. 41, 417-432, (1905-1906). The electrical conductivity of solutions in Uquid iodine.) [Same as 1079.] 1081. (W. K. Lewis. Zeit. Phys. Chem. 63, 171-176, (1908). Eine Methode zur Berechnung von lonenkonzentrationen aus Potentialmes- sungen von Konzentrationsketten.) [Inorganic and theoretical.] 1082. (H. Ley. Ber. Deutsch. Chem. Ges. 30, 2192-2196, (1897). Ueber die hydrolytische Dissociation.) [Inorganic] 1083. H. Ley. Ber. Deutsch. Chem. Ges. 34, 2620-2631, (1901). Ueber Oxyamidine. T=25° S. U. K aq. =0.8X10-6; not sub. 1084. H. Ley. Ber. Deutsch. Chem. Ges. 38, 973-978, (1905). Ueber Quecksilbemitroform; ein Beitrag zur Constitution von Salzlosungen. [T probably 25°.] R. O. 1086. H. Ley. Ber. Deutsch. Chem. Ges. 38, 2199-2203, (1905). Ueber coUoidales Kupferoxyd. T=25° R. O. 1086. H. Ley. Ber. Deutsch. Chem. Ges. 42, 354-376, (1909). Beitrage zur Theorie der inneren Komplexsalze. T = 25°. R. O. xaq. averages 1.2X10-6; not sub. 1087. H. Ley. Zeit. Elektrochem. 10, 954-956, (1904). Ueber innere Metall-Komplexsalze. T=25°. R. O. 1088. H. Ley. Zeit. Phys. Chem. 30, 193-257, (1899). Studien uber die hydrolytische Dissociation der Salzlosungen. [Same as 1089.] T = 25°. X aq. = 1.3 XIO-^; sometimes sub. 1089. H. Ley. Habilitschr. Wtirzburg. (1899). Studien uber die hydrolytische Dissociation der Salzlosungen. [Same as 1088. ] Mms. H. Ley; see 725. 1090. H. Ley, O. Erler. Zeit. Anorg. Chem. 56, 401-421, (1907). Ueber Salz- und Komplexsalz-Bildung bei hydroxylhaltigen organischen Sauren. [See 1346 and 1715.] T = 25°. R. O. 1091. H. Ley, O. Erler. Zeit. Elektrochem. 13, 797-799, (1907). Leitfahigkeitsmessungen bei Natriumsalzen der isomeren Oxybenzoesafiren; zur Frage nach der Wanderungsgeschwindigkeit isomerer Anionen. [See 1346 and 1715.] T=25°. xaq. = 1.0 -1.5X10-6; sub. 1092. H. Ley, A. Hantzsch. Ber. Deutsch. Chem. Ges. 39, 3149-3160, (1906). Mms. H. Gorke and A. H. Salway. Ueber den Zustand der Pseudosauren in wassriger Losung. [Part is given in 1567.] T=0°and25°. R. O. x aq. sub. AUTHOR LIST 469 1093. H. Ley, E. Holzweissig. Ber. Deutsch. Chem. Ges. 36, 18-24, (1903). Ueber Oxyamidine. T = 25°. S. U. 1094. H. Ley, H. KisseL Ber. Deutsch. Chem. Ges. 32, 1357-1368, (1899). ^Meas. Buchner. Beitrage zur Chemie des Quecksilbers. T = 25°. [Probably for all measurements. Not stated in some cases.] X aq. = 1.3X10-*; not sub. 1095. H. Ley, K. Schaefer. Ber. Deutsch. Chem. Ges. 35, 1309-1316, (1902). Beitrage zur Chemie des Quecksilbers. [Given in 1097; not quite so full here. ] [T probably 25°.] R. O. 1096. H. Ley, K. Schaefer. Ber. Deutsch. Chem. Ges. 39, 1259-1266, (1906). Ueber Silbersalze von Saureamiden und Saureimiden. II. T = 25°. R. O. X aq. = 1.5X10-6; not sub. 1097. H. Ley, K. Schaefer. Zeit. Phys. Chem. 42, 690-704, (1902- 1903). Untersuchungen uber die Dissociation von Schwermetallsalzen. I. Ueber Quecksilberstickstoffsalze. [Same as 1095 with a few additional measure- ments. ] T=25°. R. O. jcaq. = 1.0X10-6; not sub. 1098. G. T. LhuilUer. Compt. Rend. 121, 345-348, (1895). Sur la conductibilit^ des melanges de hmailles m^talliques et de di^lectriques. 1099. D. M. Lichty. Ann. Chemie. 319, 369-390, (1901). #Meas. S. L. Die Geschwindigkeit der Esterbildung mid die elektrische Leitfahigkeit der a-, ;8-, 7- und 5- Halogenfettsauren. [See 1908.] T = 25°. S. U. Meas. Lidbury; see 861. 1100. (C. Liebenow. Zeit. Elektrochem. 8, 933-938, (1902). Ueber die Dissociation der Elektrolyi;e.) 1101. (C. Liebenow. Zeit. Elektrochem. 11, 301-306, (1905). Zur Frage der Dissociation der Elektrolyte.) [Theoretical and inorganic. ] 1102. C. Liebermann. Ber. Deutsch. Chem. Ges. 23, 512-516, (1890). Meas. W. Ostwald. Zur Kenntnis der Isozimmtsaure. [See 1373.] 1103. C. Liebermann. Ber. Deutsch. Chem. Ges. 24, 1101-1110, (1891). Meas. W. Ostwald. Ueber AUozimmtsaure. 1104. C. Liebermann. Ber. Deutsch. Chem. Ges. 28, 129-134, (1895). Meas. Paul. Ueber Allofurfuracrylsaure. 1106. C. Liebermann. Ber. Deutsch. Chem. Ges. 36, 176-183, (1903). Meas. W. Ostwald. Zur Frage nach der Isozimmtsaure. T is about 25°. O. Liebknecht see A. Rosenheim. A. Liebmann see E. Lellmann. 1106. A. T. Lincohi. Jour. Phys. Chem. 3, 457-494, (1899). The electrical conductivity of non-aqueous solutions. [Given in 1107. ] T = 25°. Hg. U. 470 AUTHOR LIST 1107. A. T. Lincoln. Trans. Wisconsin Acad. 12, II, 395-453, (1898- 1899). The electrical conductivity of non-aqueous solutions. [Part is in 941, the rest is in 1106.] T=25°. A. T. Lincoln see L. Kahlenberg. 1108. L. Lindet. Compt. Rend. 138, 508-510, (1904). Meas. Dongierl Sur I'inversion du sucre. 1109. C. F. Lindsay. Dis. Johns Hopkins. (1902). A study of the conductivity of certain salts in water, methyl, ethyl and propyl alcohols, and mixtures of these solvents. [Same as 912.] C. F. Lindsay see H. C. Jones. 1110. E. O. V. Lippmann. Ber. Deutsch. Chem. Ges. 34, 3747-3750, (1901). Zur Inversion des Rohrzuckers. [Qualitative. ] A. Lipschitz see R. Wegscheider. G. Lockemajon see E. Beckmann. Z. Lockemann see H. Paidy, K. Schiibel. W. Lodter see E. Bamberger. 1111. M. Loeb, W. Nemst. Zeit. Phys. Chem. 2, 948-963, (1888). Meas. W. Nernst. Zur Kinetik der in Losung befindlichen Korper. II. Ueberfuhnmgszahlen und Leitvermogen einiger Silbersalze. T = 25°. Hg. U. x:25aq.= 2.5X10-8; sub. 1111a. W. Lob, S. Higuchi. Biochem. Zeit. 24, 92-107, (1910). Ueber lonenkonzentrationen in Organfliissigkeiten. 1112. (K. F. LBwe. Ann. Physik. (3), 66, 390-410, (1898). Experimental-Untersuchung tiber electrische Dispersion einiger organischer Sauren, Ester, und von zehn Glassorten.) [Dielectric constants.] 1113. (K. F. Lowe. Ann. Physik. (3), 66, 582-596, (1898). Experimental-Untersuchung uber electrische Dispersion einiger organischer Sauren, Ester und von zehn Glassorten.) 1114. (R. Lowenherz. Zeit. Phys. Chem. 15, 389-398, (1894). Ueber die Verseifungsgeschwindigkeit einiger Ester.) 1115. R. Lowenherz. Zeit. Phys. Chem. 20, 282-302, (1896). Ueber den Einfluss des Zusatzes von Aethylalkohol auf die elektrolytische Dissociation des Wassers. 1116. R. Lowenherz. Zeit. Phys. Chem. 25, 385-418, (1898). Bestimmung von Dissociationskonstanten dm'ch Loslichkeitserhohung. T = 25°. 1117. W. Loewenstanun. Dis. Berlin. (1901). Ueber Metallsalzverbindungen des Schwefelhamstoffs, ein Beitrag zur Kennt- nis der komplexen Verbindungen einwertiger Metalle. [Same as 1524 for 25°. ] T = 25°. W. Loewenstamm see A. Rosenheim. 1118. J. H. Long. Jour. Am. Chem. Soc. 28, 372-384, (1906). Some investigations on salts of casein. T=20°. 1119. J. H. Long. Jour. Am. Chem. Soc. 29, 223-230, (1907). On some phenomena observed in the peptic digestion of caseins. T = 20°. 1120. J. H. Long. Jour. Am. Chem. Soc. 29, 1334-1342, (1907). On the combining power of casein with certain acids. T = 20° AUTHOR LIST 471 1121. J. H. Long. Jour. Am. Chem. Soc. 30, 881-895, (1908). Observations on the stability of lecithin. T=20°. xaq. notsub. 1122. E. H. Loomis. Ann. Physik. (3), 60, 523-546, (1897). Der Gefrierpunkt verdiinnter wasseriger Losungen. [Same as 1125. ] Hg. U. 1123. E. H. Loomis. Ann. Physik. (3), 60, 547-551, (1897). Ueber das specifische Gewicht mid das electrische Leitungsvermogen der NormaUosmigen von Natrimn- mid Kaliumhydroxyd, von Salzsam-e, Schwef el- sam:e, Salpetersaure und Oxalsam-e. [Same as 1124. ] T = 18° ±0.05°. Kg. U. at 4°. 1124. E. H. Loomis. Phys. Rev. 4, 252-255, (1896-1897). On the specific gravity and electrical conductivity of the normal solutions of sodium and potassium hydroxides, and hydrochloric, sulphuric, nitric and oxalic acids. [Same as 1123. ] T = 18° ±0.05°. Hg. U. aU°- 1126. E. H. Loomis. Phys. Rev. 4, 273-296, (1896-1897). The freezing-points of dilute aqueous solutions. [Same as 1122. ] T = 18°. Hg. U. 1126. R. C. Lord. Jour. Phys. Chem. 11, 173-200, (1907). An investigation of the double cobalt malonates. T = 18°. Hg. U. «isaq.=2XlO-«orless. 1127. (R. Lorenz. Ber. Deutsch. Chem. Ges. 40, 3308-3311, (1907). Die elektrolytische Dissoziation geschmolzener Salze.) [Inorganic] 1128. (R. Lorenz. Ber. Deutsch. Chem. Ges. 40, 4378-4380, (1907). Die elektrolytische Dissoziation geschmolzener Salze.) 1128a. (R. Lorenz. Zeit. Phys. Chem. 70, 230-238, (1910). Ueber die Anwendung der Theorie der elektrolytischen lonen auf die geschmolzenen Salze.) [Inorganic] 1129. R. Lorenz, A. Bohi. Zeit. Phys. Chem. 66, 733-751, (1909). Beitrage zur Theorie der elektrolytischen lonen. II. Die elektrolytische Dissociation des Wassers. 1130. (R. Lorenz, H. T. Kahnus. Zeit. Phys. Chem. 59, 17-30, (1907). Das Leitvermogen einiger geschmolzener Salze und iiber die Methode der Bestimmung desselben.) [Inorganic] 1131. (R. Lorenz, F. Kaufler. Ber. Deutsch. Chem. Ges. 41, 3727-3738, (1908). Der Molekularzustand der geschmolzenen Salze.) [Inorganic] 1132. (R. Lorenz, W. Ruckstuhl. Zeit. Anorg. Chem. 52, 41-47, (1907). Untersuchungen iiber die Wanderung der lonen bei der Elektrolyse eines geschmolzenen Salzpaares.) [Inorganic] W. Lotz see H. Rupe. " " see H. Rupe, M. Ronus. 1133. J. M. Loven. Zeit. Phys. Chem. 13, 550-560, (1894). Ueber die Affinitatsgrossen einiger schwef elhaltigen Substitutionsderivate von der Essigsaure und der Propionsaure. T=25°. 1134. J. M. Loven. Zeit. Phys. Chem. 19, 456-464, (1896). Affinitatsgrossen einiger organischen Sauren. 1136. (J. M. Loven. Zeit. Phys. Chem. 21, 134-136, (1896). Notiz iiber die Trithiodilaktylsaure.) [Quoted.] F. H. Lowe see J. C. Crocker. T. M. Lowry see W. R. Bousfield. 472 AUTHOR LIST 1136. J. Lublin. Ber. Deutsch. Chem. Ges. 37, 3467-3469, (1904). Dinitrile und Amylnitrit. [Qualitative. ] 1137. A. Lucas. Ber. Deutsch. Chem. Ges. 32, 3179-3182, (1899). Meas. F. Hofmann. Ueber Nitroaceton. T = 25°. 1137a. A. B. Luckhardt. Am. Jour. Physiol. 25, 345-353, (1909-1910). Contributions to the physiology of lymph. X. The comparative electrical conductivity of lymph and serum of the same animal, and its bearing on the- ories of lymph formation. T = 35.3°- Special unit. 1138. J. S. Lumsden. Jour. Chem. Soc. 87, 90-98, (1905). The physical properties of heptoic, hexahydrobenzoic, and benzoic acids and their derivatives. T=25°. 1139. H. Lunden. Arkiv Kemi. 2, no. 11, 1^4, (1905-1907). . Ueber amphotere Elektrolyte. [Same as 1160.] 1140. (H. Lunden. Arkiv Kemi. 2, no. 18, 1-6, (1905-1907). Bemerkungen zur Theorie der amphoteren Elektrolyte.) [Theoretical.] 1141. H. Lunden. Arkiv Kemi. 2, no. 28, 1-10, (1905-1907). Die Kriterien der Pseudosauren. T=25°. ?C25 aq. = 1.3XlO-«; not sub. 1142. H. Lunden. Jour. Biol. Chem. 4, 267-288, (1908). Amphoteric Electrolytes. [Same as 1148.] 1143. H. Lunden. Jour. Chim. Phys. 5, 145-185, (1907). Sur la relation entre les coefficients d'aflBnit^ et I'hydrolyse des sels des cfitones isonitros6es. [Same as 1146. ] T = 15°, 25° and 40°. xn aq. = l.l-1.6Xl0-8; sub. as a rule. 1144. H. Lunden. Jour. Chim. Phys. 5, 574r-608, (1907). Hydrolyse des sels des acides faibles et des bases faibles et sa variation avec la temperature. [Same as 1147. ] T = 8°to50°. :x:26aq. = 1.0-1.3X10-°; sub. 1145. (H. Lunden. Jour. Chim. Phys. 6, 681-698, (1908). Influence de la temp&ature sur I'^nergie interne et I'^nergie libre des dissoci- ations flectrolytiques des acides et bases faibles.) [Same as 1149.] 1145a. H. Lunden. Jour. Chim. Phys. 8, 331-336, (1910). La constante de dissociation de la tropine et sa variation avec la temperature. T = 10°, 25°, 50°. X26 aq. = 1.0-1.4X10-«; sub. 1146. H. Lunden. Med. Nobelinst. 1, no. 7, 1-38, (1906-1909). Sur la relation, etc. [Same as 1143.] 1147. H. Lunden. Med. Nobelinst. 1, no. 8, 1-33, (1906-1909). Hydrolyse des sels, etc. [Same as 1144.] 1148. H. Lunden. Med. Nobelinst. 1, no. 11, 1-21, (1906-1909). Amphoteric electrolytes. [Same as 1142.] 1149. (H. Lunden. Med. Nobelinst. 1, no. 12, 1-16, (1906-1909). Influence de la temperature sur I'energie interne et I'^nergie libre, etc.) [Same as 1146.] 1160. H. Lundgn. Zeit. Phys. Chem. 54, 532-668, (1906). Ueber amphotere Elektrolyte. [Same as 1139. ] T = 15°to45°. R. O. J.:iBaq. = 1.2 -1.5X10-8; not sub. 1150a. H. Lunden. Zeit. Phys. Chem. 70, 249-255, (1910). Phenol and m-nitrophenol as acids. T = 10°to50°. R. O. X25aq. = 1.00X10-8; sub. Meas. H. Lunden; see 624. AUTHOR LIST 473 1151. (S. Lussana. Nuovo Cim. (3), 34, 217-226, (1893). La resistenza elettrica delle soluzioni acquose e sua variazione in comspon- denza al massimo di density,.) [Inorganic. Same as 1155.] 1152. (S. Lussana. Nuovo Cim. (4), 5, 357-385, (1897). Contributo alio studio della resistenza elettrica delle soluzioni, considerata come funzione della pressione e deUa temperatura.) [Inorganic] 1153. (S. Lussana. Nuovo Cim. (4), 6, 441^59, (1897). Contributo alio studio della resistenza elettrica delle soluzioni, considerata come funzione della pressione e della temperatura.) [Inorganic] 1164. (S. Lussana. Nuovo Cim. (5), 18, 170-172, (1909). Sull'influenza della pressione e della temperatin-a sulla resistenza elettrolittica.) [Correction of 1151-1153; also a priority claim; see 984.] 1155. (S. Lussana. Atti 1st. Veneto. 51, 1466-1481, (1892-1893). La resistenza elettrica deUe soluzioni acquose e sua variazione in corrispon- denza al massimo di density.) [Same as 1151.] 1156. O. Lutz. Ber. Deutsch. Chem. Ges. 36, 2460-2466, (1902). Ueber einige Falle von Sauerstoffwanderung in der Molekel. T = 25°. 1157. O. Lutz. Ber. Deutsch. Chem. Ges. 35, 2549-2554, (1902). Ueber die Einwirkung von Ammoniak auf halogensubstituirte Malonsauren. [Same as 1159.] T=25°. 1158. O. Lutz. Ber. Deutsch. Chem. Ges. 35, 4369-4377, (1902). Ueber einige Falle von Sauerstoffwanderung in der Molekel. II. Einwirkung von Ammoniak auf alkylsubstituirte Monobrombernsteinsauren. 1159. O. J. Lutz. Dis. Rostock. (1899). Ueber die Einwirkung von Ammoniak und Aminbasen auf Halogenbemstein- sauren. [Same as 1157.] Meas. P. Lux; see 1912, 1913, 1914, 1926, 1927, 1928, 1932, 1933, 1940, 1940a. P. Lux see R. Wegscheider. 1160. R. Luzzatto, D. FiUppi. Arch. Fisiol. 6, 250-264, (1909). I cosidetti composti jodotannici. T = 18°- M. 1161. G. W. P. van Maarseveen. Dis. Zurich. (1897). Ueber die Beziehung zwischen Losungswarme, Loslichkeit und Dissociations- grad. [Same as 656.] T=25°. Meas. G. W. P. van Maarseveen; see 656. 1162. J. Maas. Dis. Munchen. (1909). Hexarhodanatosalze des Molybdans. [Part given in 1163. ] T=25°. 1163. J. Maas, J. Sand. Ber. Deutsch. Chem. Ges. 41, 1500-1514, (1908). Die Hexarhodanatosalze des Molybdans. [Given in 1162. See 1164. ] T=25°. R. O. 1164. J. Maas, J. Sand. Ber. Deutsch. Chem. Ges. 41, 3367-3376, (1908). Die Hexarhodanatosalze des Molybdans. T=0°. R. O. [For a criticism of 1163 see A. Rosenheim, Ber. Deutsch. Chem. Ges. 41, 2386, (1908), and 42, 149, and 2295, (1909). Answered in 1164 and Ber. Deutsch. Chem. Ges. 42, 2642, (1909).] 474. AUTHOR LIST 1165. (J. G. MacGregor. Phil. Mag. (5), 41, 276-287, (1896). On the calculation of the conductivity of mixtures of electrolytes.) [Theoret- ical. ] 1166. (J. G. MacGregor. Phys. Rev. 8, 129-140, (1899). On the applicability of the dissociation theory to the electrolysis of aqueous solutions containing two electrolytes with a common ion.) [Inorganic and theoretical. ] 1167. (J. G. MacGregor. Zeit. Phys. Chem. 33, 529-539, (1900). Ueber die Bestimmung der Dissociation von zusammengesetzten Losungen von gegebener Konzentration und uber das umgekehrte Problem.) [Inor- ganic and theoretical. ] 1168. (J. G. MacGregor. Proc. Trans. R. Soc. Canada. (2), 2, Sect. Ill, 65-82, (1896). On the calculation of the conductivity of electrolytes.) [Inorganic and the- oretical. ] 1169. (J. G. MacGregor. Proc. Trans. R. Soc. Canada. (2), 4, Sect. Ill, 117-148, (1898). On the caleulability of the results of electrolysis in solutions containing two electrolytes with one ion in common.) [Inorganic and theoretical. ] 1170. (J. G. MacGregor. Proc. Trans. Nova Scot. 9, 101-119, (1894-1898). On the calculation of the conductivity of mixtures of electroljrtes.) [Inorganic and theoretical. ] 1171. (J. G. MacGregor. Proc. Trans. Nova Scot. 10, 67-78, (1898-1902). On finding the ionization of complex solutions of given concentration, and the converse problem.) [Inorganic and theoretical.] 1172. (J. G. MacGregor, E. H. Archibald. Phil. Mag. (5), 45, 151-157, (1898). On the calculation of the conductivity of aqueous solutions containing two electroljrtes with no common ion.) [Inorganic and theoretical.] 1173. (J. G. MacGregor, E. H. Archibald. Phil. Mag. (5), 46, 509-519, (1898). On the conductivity method of studying moderately dilute aqueous solutions of double salts.) [Inorganic and theoretical.] 1174. A. C. MacGregory. Ann. Physik. (3), 51, 126-139, (1894). Die electrische Leitfahigkeit einiger Losungen von Salzen, besonders des Calciums, Strontiums, und Bariums. [Same as 1176.] T = 18.00° ±0.02°. Hg. U. ?«aq.= 0.75 -1.5X10-"^; sub. 1175. A. C. MacGregory. Phys. Rev. 2, 361-372, (1894r-1895). Determination of the electric conductivity of certain salt solutions. [Same as 1174.] E. Mackay see H. C. Jones. 1176. G. M. J. MacKay. Proc. Trans. Nova Scot. 11, 324r-337, (1902- 1906). Contribution to the study of hydroxylamine. T = 18.00° ±0.02°. R. O. xaq. = 1.05 -1.6X10-=; sub. W. MacPherson see H. A. Torrey. 1177. T. Madsen. Zeit. Phys. Chem. 36, 290-304, (1901). Versuche iiber die Abhangigkeit der Hydrolyse von der Temperatur. T. Madsen see S. Arrhenius. A. Magalhaes see K. Buchka. 1178. H. Mager. Ann. Chemie. 275, 356-366, (1893). Meas.G. Bethmann. Ueber die Constitution des Suberons und uber die Ringketone der PimeUnsaure und Azelainsaure. [This is a chapter in an article by J. Wislicenus, pages 309-382.] AUTHOR LIST 475 1179. G. Magnanini. Gaz. Chim. Ital. 20, 428^40, (1890). Sul comportamento della mannite rispetto all'acido borico. [Given in 1189, Same as 1193.] T=25°. 1180. G. Magnanini. Gaz. Chim. Ital. 20, 441-447, (1890). Sulla conducibilita. elettrica delle soluzioni di acido borico in presenza di dulcite. [Same as 1196. ] T = 2S°. 1181. G. Magnanini. Gaz. Chim. Ital. 20, 448-452, (1890). Sulla conducibilit^ elettrica delle soluzioni acquose di acido borico in presenza degli alcoli polivalenti. T = 25°. 1182. G. Magnanini. Gaz. Chim. Ital. 20, 453-458, (1890). Influenza dell' acido borico sulla conducibilitS, elettrica delle soluzioni acquose di acido tartarico. 1183. G. Magnanini. Gaz. Chim. Ital. 21, II, 134-141, (1891). Sul punto di congelamento delle soluzioni acquose di acido borico e mannite. T = 20°to50°. 1184. G. Magnanini. Gaz. Chim. Ital. 21, II, 215-228, (1891). Influenza dell' acido borico sulla conducibiUt^ elettrica delle soluzioni acquose degli acidi organici. T = 25°. X aq. =0.0034; not sub. 1185. G. Magnanini. Gaz. Chim. Ital. 22, I, 541-558, (1892). Influenza deU'acido borico sulla conducibilit^ elettrica delle soluzioni idroal- cooliche degli acidi organici. T = 25°. 1186. G. Magnanini. Gaz. Chim. Ital. 23, I, 197-251, (1893). Ricerche ulteriori intorno aUa influenza deU'acido borico sulla conducibilitS, elettrica delle soluzioni acquose degli acidi organici. [Same as 1191.] T=25°. X aq. less than 0.004; not sub. 1187. G. Magnanini. Gaz. Chim. Ital. 24, I, 48-56, (1894). Intorno alia ipotesi deUa colorazione degli joni. [Same as 1190 and 1196.] Hg. U. 1188. G. Magnanini. Gaz. Chim. Ital. 26, II, 92-96, (1896). Intorno alia ipotesi della colorazione degli joni. [Same as 1197.] 1189. G. Magnanini. Zeit. Phys. Chem. 6, 58-70, (1890). Ueber das Verhalten des Mannits gegen Borsaure. [Part is same as 1179 and 1193.] T=25°. 1190. G. Magnanini. Zeit. Phys. Chem. 12, 56-62, (1893). Ueber die Hypothese der Farben der lonen. [Same as 1187 and 1196.] T for potassium salt is 18° Hg. U. 1191. G. Magnanini. Atti Accad. Gioenia. (4), 6, Mem. Ill, 1-51, (1892- 1893). Ricerche ulteriori, etc. [Same as 1186. ] 1192. G. Magnanini. Mem. R. Accad. Modena. (2), 11, 259-270, (1895). Dissociazione elettrolitica e colorazione. T = 25°. 1193. G. Magnanini. Rend. Accad. Lincei. (4), 6, I, 260-266, (1890). Sul comportamento deUa mannite rispetto all'acido borico. [Same as 1179. Given in 1189.] 1194. (G. Magnanini. Rend. Accad. Lincei. (4), 6, I, 411-416, (1890). Sulla conducibilita, elettrica delle soluzioni acquose di acido borico in presenza di mannite.) [Theoretical and quoted. ] 476 AUTHOR LIST 1195. G. Magnanlni. Rend. Accad. Lincei. (4), 6, I, 457-463, (1890). Sulla conducibilitS, elettrica delle soluzioni di acido borico in presenza di dul- cite. [Same as 1180.] 1196. G. Magnanini. Rend. Accad. Lincei. (5), 2, I, 369-376, (1893). Intomo alia ipotesi della colorazione degli joni. [Same as 1187 and 1190.] 1197. G. Magnanini. Rend. Accad. Lincei. (5), 4, II, 60-63, (1895). Intorno alia ipotesi della colorazione degli joni. [Same as 1188.] Meas. G. Magnanini; see 667. 1198. G. Magnanini, T. Bentivoglio. Gaz. Chim. Ital. 23, II, 444-451, (1893). Intorno alio spettro di assorbimento delle soluzioni di alcuni cromoossalati della serie bleu. [Same as 1200. ] T=25°- Hg. U. 1199. G. Magnanini, T. Bentivoglio. Gaz. Chim. Ital. 23, II, 451-457, (1893). ConduoibilitEl elettrica delle soluzioni dei sali di acidi organici in presenza di acido borico. [Same as 1201.] 1200. G. Magnanini, T. Bentivoglio. Rend. Accad. Lincei. (5), 2, II, 17-23, (1893). Intomo alio spettro di assorbimento, etc. [Same as 1198.] 1201. G. Magnanini, T. Bentivoglio. Rend. Accad. Lincei, (5), 2, II, 54r-58, (1893). Conducibilitll elettrica delle soluzioni dei sali, etc. [Same as 1199. ] 1202. G. Magnanini, M. Scheldt. Gaz. Chim. Ital. 22, I, 436-448, (1892). Sul comportamento dell' acido deidiodiacetillevulinico rispetto alia feniUdrar zina ed alia idrossUamina e sopra un nuovo derivato dell'acido deidrodiace- tillevulinico. [Same as 1203. ] 1203. G. Magnanini, M. Scheldt. Rend. Accad. Lincei, (5), 1, I, 169-174, (1892). Sul comportamento, etc. [Same as 1202.] Meas. Magnus; see 332. 1204. (G. Magri. Rend. Accad. Lincei. (5), 16, I, 171-178, (1907). Ricerche sopra solventi inorganici a basse temperature. Disposizione sperimentale.) 1206. (G. Magri. Rend. Accad. Lincei. (5), 16, I, 518-525, (1907). Ricerche sopra il solvente H2S liquefatto.) [Inorganic] T=-60°. G. Magri see U. Antony. E. G. Mahin see H. C. Jones. R. D. Mailey see H. M. Goodwin. 1206. L. Malcles. Ann. Chim. Phys. (8), 16, 153-236, (1909). Recherches exp^rimentales sur les di^lectiiques. 1207. G. Malfltano. Compt. Rend. 139, 1221-1223, (1904). Sur la conductibiIit6 eleotrique des solutions colloidales. 1208. (G. Malfltano. Compt. Rend. 148, 1045-1047, (1909). Sur les propriSt^s physico-chimiques des particules colloidales dites micelles.) 1209. G. Malfltano, L. Michel. Compt. Rend. 146, 338-341, (1908). Sur I'hydrolyse du perchlorure de fer. Effet de la valence des ions negatifs. T = 50°. 1209a. G. Malfltano, A. N. Moschkoff. Compt. Rend. 151, 817-819, (1910). Sur la purification de I'amidon. AUTHOR LIST 477 1210. (R. Malmstrom. Ann. Physik. (4), 18, 413-449, (1905). Versuch einer Theorie der elektrolytischen Dissoziation unter Beriicksichti- gung der elektrischen Energie.) [Theoretical and inorganic] Meas. R. Malmstrom; see 828, 831. 1211. M. E. Maltby. Zeit. Phys. Chem. 18, 133-158, (1895). Methode zur Bestimmung grosser elektrolytischer Widerstande. 1212. O. Manasse, H. Rupe. Ber. Deutsch. Chem. Ges. 27, 1818-1822, (1894). Meas. Franke and Paul. Ueber die Oxydation des Menthons. Mandate see Oliveri-Mandaia. 1213. W. Manthey. Ber. Deutsch. Chem. Ges. 33, 3081-3086, (1900). Ueber die Condensation der a-Bromallozimmtsaure. [Same as 1214.] T=25°. xaq.=8XlO-«. 1214. "W. Manthey. Dis. Berlin. (1900). Ueber die Kondensation von a-Bromallozimmtsaure, sowie Uber die Konsti- tution des Truxons und seiner Derivate. [Same as 1213. ] 1215. L. Marcilly. Bui. Soc. Chim. (3), 31, 119-130, (1904). Sur I'acide oxypivalique. [Same as 1216.] T = 25°. 1216. L. Marcilly. Dis. Nancy. (1903). Etude des acides aa-Dialcoylhydracryliques. [Same as 1216.] Meas. G. Mariasz; see 291. Markovnikov see Markownikoff. 1217. W. Markownikoff. Jour. Prakt. Chem. (2), 49, 409-444, (1894). Meas. N. Zelinsky. Untersuchung des Suberons. [Same as 1218 and 1219 together. Zelinsky's measurement is really quoted from 2018. ] 1218. (W. Markownikoff. Jour. Russ.Phys.-chem. Soc.25,364-378, (1893). Investigation of suberone.) [Same as part of 1217.] 1219. W. Markownikoff. Jour. Russ. Phys.-chem. Soc. 25, 547-564, (1893). Investigation of suberone. [Same as part of 1217. Zelinsky is quoted from 2018.] 1220. C. J. Martin, O. Masson. Jour. Chem. Soc. 79, 707-714, (1901). The influence of cane sugar on the conductivities of solutions of potassium chloride, hydrogen chloride, and potassium hydroxide, with evidence of salt formation in the last case. T = 18°. R. 0. N. A. Martin see H. W. Foots. E. Mascetti see A. Miolati. O. Masson see C. J. Martin. 1221. (P. MassouUer. Compt. Rend. 130, 773-775, (1900). Relations entre la conductibilit^ ^lectrolytique et le frottement interne dans les solutions salines.) [Inorganic] 1222. P. Massoulier. Compt. Rend. 143, 218-220, (1906). Sur la relation qui existe entre la resistance 61ectrique et la viscosity des solu- tions flectrolytiques. T = 0°and25°. Master = McMaster, q. v. 1223. J. H. Mathews. Jour. Phys. Chem. 9, 641-681, (1905). On the relation between electrolytic conduction, specific inductive capacity and chemical activity of certain hquids (with a bibUography of dielectric constants) . T=25°- W. C. Matignon see M. Berthelot. K. Mattisson see B. Holmberg. 478 AUTHOR LIST 1224. P. Mauz. Dis. Tubingen. (1904). Physikalisch-chemisohe Untersuchungen iiber Alkaloide. T = 18°. R. O. X aq. sub.; A also given without sub. of aq. fUMeas. P. Mauz; see 1391a. 1225. A. Mayer. Compt. Rend. 143, 515-516, (1906). Sur les complexes de I'albumine pure. 1225a. A. Mayer, G. Schaeffer. Arch. Fisiol. 7, 457-489, (1909). Contribution k I'^tude des acidalbumines, particuli^rement des acidalbumines d'acides gras. 1225b. H. Mayer. Jour. Phys. (4), 9, 584r-599, (1910). Nouvelle m^thode ^lectrique pour mesurer I'influence de la lumiSre sur la chromog^latine. 1225c. H. Mayer. Zeit. Chem. Ind. KoUoide. Beiheft I, 58-90, (1909-1910). Ueber eine elektrische Methode zur Messung der durch Belichtung in Chro- matgelatineschichten verursachten Veranderungen. T = 20°. 1226. H. Mayer. Zeit. Phys. Chem. 66, 33-70, (1909). Ueber eine elektrische Methode zur Messung der durch Belichtung in Chromat- gelatineschichten verursachten Veranderungen. T=20''to30°. 1227. A. Mazzucchelli. Rend. Soc. Chim. Roma. 3, 80-96, (1905). Sopra la cosidetta " regola di valenza " dei sali polibasici. T = 25°and28°. R. O. 1228. A. MazzucchelU. Rend. Soc. Chim. Roma. 6, 344-346, (1908). SuUe curve di neutralizzazione graduate degli acidi. [Priority claim; and criticism of 1718.] 1229. (J. W. McBain. Proc. Washington Acad. 9, 1-78, (1907). The experimental data of the quantitative measurements of electrolytic mi- gration. To the end of the year 1905.) [Gives a critical bibliography, with tables of experimental values found by each author. ] 1229a. J. W. McBain, M. Taylor. Ber. Deutsch. Chem. Ges. 43, 321-322, (1910). Ueber die elektrische Leitfahigkeit von Seifenlosungen. T = 89.75°. 1230. H. N. McCoy. Am. Chem. Jour. 31, 503-521, (1904). On the ionization constants of phenolphthalein and the use of this body as an indicator. 1231. H. N. McCoy. Jour. Am. Chem. Soc. 30, 688-694, (1908). Two new methods for the determination of the secondary ionization constants of dibasic acids. T = 20°. 1232. (H. N. McCoy. Jour. Am. Chem. Soc. 30, 1074^1077, (1908). The relation between the ionizing power and the dielectric constants of sol- vents.) 1233. W. McCracken. Am. Chem. Jour. 39, 586-613, (1908). Studies in catalysis. The catalysis of imidoesters. [k same as in part of 1656 and 1657.] T = 25°±0.01°. R. O. X aq.=4X10-«; sub. for neutral solutions, but not for acid solutions. Meas. W. McCracken; see 1657. 1233a. D. Mcintosh. Jour. Am. Chem. Soc. 32, 542-547, (1910). The basic properties of oxygen: compounds of dimethylpyrone and the halogen hydrides. T= -100° and -78°. AUTHOR LIST 479 1234. p. Mcintosh. Jour. Phys. Chem. 11, 306-317, (1907). The physical properties of liquid and solid acetylene. 1236. (D. Mcintosh. Phil. Mag. (5), 41, 510-516, (1896). On the calculation of the conductivity of mixtures of electrolytes having a common ion.) [Same as 1236. Inorganic and theoretical.] 1236. (D. Mcintosh. Proc. Trans. Nova Scot. 9, 120-133, (1894^1898). On the calculation, etc.) [Same as 1236.] D. Mcintosh see E. H. Archibald. " " see F. M. G. Johnson. " " see B. D. Steele. " " see J. W. Walker. 1237. D. Mcintosh, B.D.Steele. Proc. R. Soc. London. 73,450-453,(1904). On the Uquefied hydrides of phosphorus, sulphur, and the halogens as con- ducting solvents. [QuaUtative. ] 1238. The reference under this number has been omitted intentionally. 1239. A. McKenzie. Jour. Chem. Soc. 75, 753-770, (1899). Meas. W. [A.] Both. Active and inactive phenylalkyloxyacetic acids. T=25°. Hg. U. Meas. L. McMaster; see 904. L. McMaster see H. C. Jones. " " see H. C. Jones, E. C. Bingham. G. Mehrtens see M. Busch. A. C. Melcher see A. A. Noyes. 1239a. J. MeUanby. Jour. Physiol. 35, 473-499, (1906-1907). The physical properties of horse serum. T=20°to70°. 1239b. J. MeUanby. Jour. Physiol. 36, 288-333, (1907-1908). The precipitation of the proteins of horse serum. 1240. J. W. Mellor. Jour. Chem. Soc. 79, 126-134, (1901). Some o^alkyl substitution products of glutaric, adipic, and pimelic acids. T is about 24°. 1241. R. H. Mennicke. Dis. Leipzig. [Probably 1897]. Ueber fraktionirte Fallung organischer Basen. [The accuracy of the values given is doubtful. ] T=25°- S. U. xaq.=0.7-1.5XlO-«; notsub. 1242. (N. Menschutkin. Zeit. Phys. Chem. 6, 41-57, (1890). Ueber die Aflfinitatskoeffizienten der Alkylhaloide und der Amine.) [Velocity of reaction in organic solvents.] E. Merritt. Phys. Rev. 27, 367-399, (1908). See E. L. Nichols, E. Merritt. E. Merritt see E. L. Nichols. 1243. P. H. v. d. Meulen. Rec. Trav. Chim. 16, 323-348, (1896). L'action des alcools sur les isoimides. [FuU tables of A in 1244. Only k is given here. ] T=25°. 1244. P. H. V. d. Meulen. Dis. Basel. (1896). Zur Kenntniss einiger Derivate der Camphersaure und Hemipinsaure. [Has full tables of A, otherwise same as 1243.] T=25°- 1245. W. Meusel. Dis. Halle. (1900). Ueber Acetphenylglycin-o-carbonsaure. [Part given in 1813, 1814 and 1817. ] T=25.0°. R. O. xaq.=2.3-3.0X10-«. Meas. W. Meusel; see 1813. 480 AUTHOR LIST F. V. Meyenburg see K. Auwers, E. Kobner. 1246. H. Meyer. Monatsh. 28, 1231-1237, (1907). Meas. Flaschmr. Die Konstitutionsbestimmung der isomeren Orthoketonsaurederivate. [Same as 1247.] 1247. H. Meyer. Sitzber. Akad. Wien. 116, 2b, 1137-1143, (1907). Meas. Flaschner. Die Konstitutionsbestimmung, etc. [Same as 1246.] 1248. J. Meyer. Ber. Deutsch. Chem. Ges. 36, 3599-3601, (1903). Zur Kenntniss der Citronensaure. T=25°. 1249. J. Meyer. Zeit. Elektrochem. 13, 494-506, (1907). Zur Kenntnis der umkehrbaren Reaktionen erster Ordnung. T is about 25.0°. 1250. K. H. Meyer. Dis. Leipzig. (1907). Untersuchungen iiber Halochromie. [Most is given in 767a, the rest is same as 1251.] T=25°. R. 0. K. H. Meyer see A. Hantzsch. 1251. K. H. Meyer, A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 3479- 3488, (1907). Ueber die Halochromie des Phenolphthaleins und seiner Ester. [Given in 1250.] T = 25°. R. O. V. Meyer see P. Askenasy. V. J. Meyer see A. Rosenheim. Meas. W. Meyerhoffer; see 1907, 1921. 1252. O. Mezger. Dis. Tiibingen. (1902). Beitrage zur Kenntnis des Hamatins. [Same as 1033.] T = 25°. Meas. O. Mezger; see 1030, 1033. 1263. (A. Michael, R. F. Brunei. Am. Chem. Jour. 41, 118-148, (1909). On the relative ease of addition in the alkene group.) 1254. A. Michael, O. D. E. Bunge. Ber. Deutsch. Chem. Ges. 41, 2907- 2913, (1908). Ueber den stfireochemischen Verlauf der Addition von Chlor zu Crotonsaure. X aq.= 0.6X10-8- 1266. (A. Michael, H. Hibbert. Ber. Deutsch. Chem. Ges. 41, 1080-1091, (1908). Ueber die vermeintUche Beziehung zwischen Dielektrizitatskonstante und iso- merisierender Kraft organischer Losungsmittel bei Enol-Keton-Desmotropen.) 1256. A. Michaelis. Ann. Chemie. 339, 117-193, (1905). Meas. Blume. Ueber 5-Aminopyrazole und tiber Iminopyrine. [Same as 214. ] 1257. (A. Michaelis, E. Hepner. Ber. Deutsch. Chem. Ges. 36, 3271-3279, (1903). Ueber Anilopyrin und Phenyl-methyl-anilino-pjTazol.) 1258. L. MichaeUs. Biochem. Zeit. 19, 181-185, (1909). Die elektrische Ladung des Serumalbumins und der Fermente. L. Michaelis see P. Rona. > 1258a. L. Michaelis, H. Davidsohn. Biochem. Zeit. 28, 1-6, (1910). Die isoelektrische Konstante des Pepsins. 1258b. L. Michaelis, B. Mostynski. Biochem. Zeit. 24, 79-91, (1910). Die isoelektrische Konstante und die relative Aciditatskonstante des Scrum- albumins. T = 18° kw = 0.60X10-" at 18° AUTHOR LIST 481 1258c. L. Michaelis, B. Mostynski. Biochem. Zeit. 25, 401-410, (1910). Die innere Reibung von Albuminlosungen. [See criticism by Pauli, Wagner, Biochem. Zeit. 27, 296, and reply by Michaelis, Biochem. Zeit. 28, 353.] 1259. L. Michaelis, P. Rona. Biochem. Zeit. 18, 317-339, (1909). Elektrochemische Alkalinitatsmessungen an Blut und Serum. T = 10°to40° 1259a. L. Michaelis, P. Rona. Biochem. Zeit. 23, 61-67, (1909-1910). Der Einfluss der Neutralsalze auf die Indicatoren. 1259b. L. MichaeUs, P. Rona. Biochem. Zeit. 23, 364r-369, (1909-1910). Beitrage zur Frage der Glykolyse. I. Die Alkaliempfindlichkeit des Trau- benzuckers. 1259c. L. Michaelis, P. Rona. Biochem. Zeit. 27, 38-52, (1910). Beitrage zm- allgemeinen Eiweisschemie. I. Die Koagulation des denaturier- ten Albumins als Funktion der Wasserstoffionenkonzentration und der Salze. 1260. L. MichaeUs, P. Rona. Zeit. Elektrochem. 14, 251-253, (1908). Zur Frage der Bestimmung der H'-Ionenkonzentration durch Indikatoren. 1261. J. I. Michajlenko. Jour. Russ. Phys.-chem. Soc. 30, 466-476, (1898). Action of zinc on a mixture of bromoisobutyric ether and formic ether. T = 25°. Meas. J. I. Michajlenko; see 1475. 1262. J. I. Michajlenko, W. P. Javorskij. Jour. Russ. Phys.-chem. Soc. 32, 328-346, (1900). Action of zinc on a mixture of bromoisobutyric ether and formic ether. T=25°. L. Michel see G. Malfitano. 1262a. (G. Mie. Ann. Physik. (4), 33, 381-399, (1910). Hydratisierung imd Molekularwarme der lonen in sehr verdunnten wasserigen Losungen.) [Inorganic] A. Milesi see L. Francesconi. 1263. A. Minozzi. Gaz. Chim. Ital. 29, I, 421^39, (1899). Sopra I'affinitS, fra alcuni acidi ed alcune basi in alcool metilico. [T probably 25°.] 1264. N. Mintz. Dis. Leipzig. (1891). Meas. [P.] Walden. Ueber Aethyldimethylbernsteinsaure und symmetrische Aethylmethylglutar- sauren. N. Mintz see C. A. Bischofi. 1265. A. Miolati. Ber. Deutsch. Chem. Ges. 26, 1788-1790, (1893). Zur Kenntniss des Parafuchsins. [Same as 1267. ] T = 25°. 1266. A. Miolati. Ber. Deutsch. Chem. Ges. 28, 1696-1701, (1895). Ueber die Constitution der Fuchsine. [Same as 1268 with abridged text. ] 1267. A. Miolati. Gaz. Chim. Ital. 23, II, 18-21, (1893). Sulla costituzione della parafucsina. [Same as 1265.] T=25°. S. U. 1268. A. Miolati. Gaz. Chim. Ital. 25, II, 217-232, (1895). Sulla costituzione dalle fucsine. [Same as 1266.] T = 25°. 1269. A. Miolati, (R. Pizzighelli). Jour. Prakt. Chem. (2), 77, 417-456, (1908). Zur Kenntnis der komplexen Sauren. I. Ueber die Leitfahigkeit von molyb- dansaurehaltigen Gemischen. T=25°. K aq. very small; not sub. Meas. A. Miolati; see 559, 882. A, Miolati see A. Hantzsch. " " see A. Werner. 4-82 AUTHOR LIST 1270. A. Miolati, I. Bellucci. Zeit. Anorg. Chem. 26, 209-221, (1901). Ueber die Pentachlorplatinsaure. T = 25°. R. O. 1271. (A. Miolati, E. Mascetti. Gaz. Chim. Ital. 31, I, 93-139, (1901). Contributo alia conoscenza di alcuni acidi inorganici.) [Inorganic] 1272. A. Mittasch. Zeit. Phys. Chem. 46, 37-42, (1903). Einige Beobachtiingen tiber Losimgsvermogen und elektrische Leitfahigkeit von flussigem Nickelkohlenoxyd. T = 0°; for qualitative measurements = —20° to +20°. 1273. J. A. Mjoen. Ber. Deutsch. Chem. Ges. 30, 1227-1240, (1897). Ueber die Polymethacrylsaure. [Same as 1274. ] T = 25°. 1274. J. A. Mjoen. Dis. Leipzig. (1894). Ueber die Polymethacrylsaure. [Same as 1273. ] 1275. M. Moest. Dis. Basel. (1899). Ueber die elektrische Leitfahigkeit von Oxychinonen und Salzen derselben. T = 25°. S. U. xaq. notover IXIO-^ 1276. P. B. Mojoiu. Dis. Lausanne. (1909). I. Determination des poids moMculaires a I'^tat liquide. II. Dosage et separation par conductivity 61ectrique des haloglnes et des m^taux alcali- no-terreux. Monte =DaMonte, q. v. Meas. Montemartini; see 76. 1277. (V. Monti. Nuovo Cim. (3), 35, 75-81, (1894). Sulla relazione fra la conducibiKtS, elettrica e I'attrito intemo degli elettroliti.) [Inorganic. An abstract, with data, of 1278.] 1278. (V. Monti. Atti Accad. Torino, 28, 476-487, (1892-1893). Sulla relazione fra la conducibilit& elettrica e I'attrito interno degli elettroliti.) [Inorganic. ] 1279. V. Monti. Atti 1st. Veneto. 50, 1705-1714, (1891-1892). Sulle conducibilit^ molecolari di alcuni sali alcalini disciolti in mescolanze d'acqua e gUcerina. T = 18°. Hg. U. 1280. V. Monti. Atti. 1st. Veneto. 51, 1482-1488, (1892-1893). Di alcuni casi anomali di dissociazione elettrolitica. T = 18°- 1281. (B. E. Moore. Phys. Rev. 3, 321-334, (1895-1896). On the viscosity of certain salt solutions.) [Quoted.] 1282. (T. S. Moore. Jour. Chem. Soc. 91, 1373-1378, (1907). A method for the determination of the equilibrium in aqueous solutions of amines, pseudo-acids and -bases, and lactones.) [Theoretical. Abstract in 1284.] 1283. T. S. Moore. Jour. Chem. Soc. 91, 1379-1384, (1907). The " true " ionisation constants and the hydration constants of piperidine, ammonia, and triethylamine. [Abstract in 1286. ] 1284. (T. S. Moore. Proc. Chem. Soc. 23, 154, (1907). A method for the determination, etc.) [An abstract of 1282.] 1285. T. S. Moore. Proc. Chem. Soc. 23, 154, (1907). The " true " ionisation constants, etc. [An abstract of 1283, with data.] T. S. Moore see N. V. Sidgwick. 1286. A. Morello. Gaz. Chim. Ital. 30, I, 257-264, (1900). Energia di alcuni acidi sciolti in miscugli di solventi organici ed acqua. T = 25°. AUTHOR LIST 483 1287. J. L. R. Morgan. Zeit. Phys. Chem. 17, 513-535, (1895). Die Bestimmung von Cyanionen auf elektrometrischem Wege. [Same as 1288.] T = 17.5°tol9°. 1288. J. L. R. Morgan. Dis. Leipzig. (1895). Die Bestimmung von Cianionen auf elektrometrischem Wege. [Same as 1287.] 1289. (J. L. R. Morgan, C. W. Kanolt. Jour. Am. Chem. Soc. 28, 572-588, (1906). The combination of a solvent with the ions.) 1289a. G. Moruzzi. Biochem. Zeit. 22, 232-243, (1909). Untersuchungen iiber die Gelatinierung des Eiweisses. T = 25°. 1289b. G. Moruzzi. Biochem. Zeit. 28, 97-105, (1910). Ueber die Aenderungen der durch Harnstoff in eiweisshaltigen Fliissigkeiten hervorgerufenen inneren Reibung und elektrischen Leitfahigkeit. T = 25°. A. N. Moschkoff see G. Malfitano. B. Mostynski see L. Michaelis. W. R. Mott see H. E. Patten. 1290. (P. F. Mottelay. Trans. Am. Electrochem. Soc. 13, 453-479, (1908). Bibliography of electrochemistry and allied subjects.) 1291. B. Muhlhauser. Dis. Basel. (1902). A. Ueber Untersuchungen in der Acridinreihe. B. Zur Kentnniss der a-Ae- thylidenglutarsaure. [Same as 568 for k; gives also tables of A.] T=25°. R. O. B. MiihUiauser see F. Fichter. 1292. H. MiiUer. Dis. Basel. (1905). Die Reductionsprodukte des 2,4-Dinitrorhodanbenzols. Affinitatsmessungen an einbasischen Fettsauren. [Same as 569. No details of conductivity meas- urements are given here, but measurements of saponification are given in full.] H. Miiller see F. Fichter. Meas. N. L. Miiller; see 316, 317, 1915, 1929. P. Miiller see A. Rosenheim. 1292a. W. J. Miiller. Ber. Deutsch. Chem. Ges. 43, 2609-2613, (1910). Ueber die Geschwindigkeiten der Umlagerung von Oxoniumbasen, Farbbasen und -cyaniden in die Carbinolbasen und Leukocyanide. [Given in 956a. ] T=0°. Meas. W. J. Miiller; see 956a. 1293. M. Miindler. Dis. Heidelberg. (1901). Ueber Aminolyse. [Part of these measurements is given in 660.] T = 25°- Meas. M. Miindler; see 660. 1294. P. T. MuUer. Bui. Soc. Chim. (3), 17, 390, (1897). [An abstract with no title. Measurements given in fuU in 1295.] 1295. P. T. Muller. Bui. Soc. Chim. (3), 27, 1011-1014, (1902). Etudes physico-chimiques sur la fonction acide oximid^e. (I). Conductibilite ^lectrique des others oximidocyanac^tiques. [Abstract given in 1294. ] T=25°. R. O. 1296. P. T. Muller, E. Bauer. Jour. Chim. Phys. 2, 472-497, (1904). Determination de la chaleiu' de dissociation de quelques acides isonitros^s (pseudo-acides) par la m^thode des conductibilit^s. T=0° to 40°. xu aq.= 1.24X10-^; not sub. for acids, sub. for salts. 484 AUTHOR LIST 1297. P. T. MuUer, M. Paul. Bui. Soc. Chim. (3), 35, 197-198, (1906). [An abstract with no title. Measurements given in full in 1390. ] T = 25°and35°. 1298. S. P. Mulliken. Am. Chem. Jour. 15, 523-533, (1893). A new class of organic electrosyntheses. 1299. S. P. Mulliken. Dis. Leipzig. (1890). Ueber die Konstitution der Chlorzimmtsauren. [Quoted in 1683.] 1300. O. Murom. Zeit. Phys. Chem. 62, 589-600, (1908). Die Kinetik des Diazoessigesters und das Verdunnungsgesetz. 1301. E. Mumme. Dis. Halle. (1901). Ueber die Einwirkung von Chloressigsaure auf Anthranilsaure. [Qualitative. Same as 1817. See 1245 for measurements. ] Meas. E. Mumme; see 1815. E. Mumme see D. Vorlander. F. Mylius see F. Kohlrausch. N. 1302. R. Nasini, T. Costa. Gaz. Chim. Ital. 21, I, 554-565, (1891). Ricerche sopra i derivati solfinici e loro confronto con le combinazioni degli ammonii organici. [Same as 1304.] 1303. (R. Nasini, T. Costa. Rend. Accad. Lincei, (4), 6, 11,284-291, (1890). Sul potere rifrapgente di alcuni derivati della trietilsolfina.) [No conductivity. ] 1304. R. Nasini, T. Costa. Rend. Accad. Lincei, (4), 7, I, 623-631, (1891). Ricerche sopra i derivati solfinici, etc. [Same as 1302. ] 1305. R. Nasini, A. Pezzolato. Gaz. Chim. Ital. 23, I, 43-58, (1893). Spostamento della nicotina dai suoi sali e azione dell'alcool sopra di essi. [Same as 1306 and 1307.] T = 25°. 1306. R. Nasini, A. Pezzolato. Zeit. Phys. Chem. 12, 501-504, (1893). Die Verdrangung des Nikotins aus seinen Salzen und die Wirkung des Alkohols auf dieselben. [Same as 1305 and 1307.] T = 25°. 1307. R. Nasini, A. Pezzolato. Rend. Accad. Lincei. (5), 1, II, 332-343, (1892). Spostamento della nicotina dai suoi sali, etc. [Same as 1305 and 1306. ] 1308. (A. Naumann. Ber. Deutsch. Chem. Ges. 32, 999-1004, (1899). Ueber Reactionen in nichtwassrigen Losungsmitteln.) 1309. (A. Naumann, A. Riicker. Jour. Prakt. Chem. (2), 74, 209-217, (1906). Seitherige Verfahren zur Bestimmung der Hydrolyse.) [Bibliography of methods of determining hydrolysis.] 1309a. R. Naumann. Zeit. Elektrochem. 16, 772-778, (1910). Ueber die Hydrolyse des Cyans. T = 0° and 18°. R. 0. 1310. (J. U. Nef. Ann. Chemie. 270, 267-335, (1892). Ueber das zweiwerthige Kohlenstoffatom.) [Quoted.] F. Neger see H. v. Pechmann. 1311. Negreano. Compt. Rend. 106, 1665-1668, (1888). Mesure de la vitesse d'6th6rification k I'aide des conductibiUt^s ^lectriques. [Qualitative.] C. Neizert see E. Rimbach. AUTHOR LIST 485 1312. (P. Nell. Ann. Physik. (4), 18, 323-347, (1905). Studien tiber DiSusionsvorgange wasseriger Losungen in Gelatine.) [Inor- ganic. ] 1313. V. V. Neminskij, W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 337, (1908). The electrolysis of compounds of aluminum bromide with toluene and ben- zene. [Summary of 1314.] 1314. V. V. Neminskij, W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 391-396, (1908). The electrolysis of compounds of aluminum bromide with toluene and benzene. [Summary given in 1313.] T = 18°. R. O. 1315. W. Nemst. Zeit. Phys. Chem. 14, 155-156, (1894). Zur Dissociation des Wassers. T = 18°. 1316. W. Nemst. Zeit. Phys. Chem. 14, 622-663, (1894). Methode zur Bestimmung von Dielektrizitatskonstanten. Meas. W. Nemst; see 303^ 1111. W. Nemst see M. Loeb. 1317. W. Nemst, C. Hohmann. Zeit. Phys. Chem. 11, 352-390, (1893). BUdung der Amylester aus Sauren und Amylen. T = 18.5°. 1318. W. Neumann. Zeit. Physiol. Chem. 45, 216-251, (1905). Ueber Peptone. [Same as 1319.] R. O. 1319. W. Neumann. Dis. Leipzig. (1905). Ueber Peptone. [Same as 1318.] 1320. E. L. Nichols, E. Merritt. Phys. Rev. 18, 447-449, (1904). The effect of light upon the absorption and the electrical conductivity of fluo- rescent solutions. [Same as 1321. The text is abridged. ] 1321. E. L. Nichols, E. Merritt. Phys. Rev. 19, 396-421, (1904). Studies of luminescence. IV. The influence of light upon the absorption and electrical conductivity of fluorescent solutions. [Same as 1320.] 1322. (E. L. Nichols, E. Merritt. Phys. Rev. 27, 367-399, (1908). [This article is by Merritt alone, though both names are given.] Studies in luminescence. Nichols and Merritt. X. The phenomena of phos- phorescence considered from the standpoint of the dissociation theory.) 1323. M. Nicollier. Dis. Lausanne. (1907). Conductibiht^s limites de 2 Electrolytes binaires dans quelques dissolvants organiques. T = 25° S. U. 1324. M. Nicollier, P. Dutoit. Bui. Soe. Vaudoise. Compt. Rend. April (1906). 11. Variation de conductibilit^ des solutions d'iodures et bromures alcalins dans les dissolvants organiques, sous I'influence de la lumifere. [Same as 1325.] 1325. M. Nicollier, P. Dutoit. Bui. Soc. Vaudoise. Proc. Verb. 42, VI, (1905-1906). Variation de conductibilit6, etc. [Same as 1324.] Meas. Nicolosi; see 253. 1326. F. Nicolosi-Roncati. Rend. Accad. Scienz. (Napoli). (3»), 13, 357- 364, (1907). Ricerche su la conduttivitH elettrica e la pressione osmotica nei vegetali. T=25°to28°. 486 AUTHOR LIST 1327. S. V. Niementowski, J. v. Roszkowski. Zeit. Phys. Chem. 22, 145- 169, (1897). Ueber die Diazotierung des Anilins. T=25°. 1328. (S. Niementowski, J. Roszkowski. Bui. Acad. Cracov. (1896), 324- 325. Ueber die Diazotirung des Anilins.) [An abstract. No data. See 1327 for measurements. ] S. Nirdlinger see S. F. Acres. . O. Nbtzel see E. Deussen, G. Heller. 1329. J. F. Norris. Am. Chem. Jour. 38, 627-642, (1907). On the base-torming property of carbon. 1330. V. Novak. Phil. Mag. (5), 44, 9-20, (1897). Specific electric conductivities and freezing-points of solutions of water in formic acid. T = 8.52°. Hg. U. 1331. A. Nowizki. Dis. Heidelberg. (1898). Ueber den Einfiuss der Temperatm- auf die Zuruckdrangung der Loslichkeit schwer loslicher Salze durch Zusatz eines gleichionigen Elektrolyten. T = 25''and35°. Hg. U. 1332. A. A. Noyes. Jour. Am. Chem. Soc. 30, 335-353, (1908). The conductivity and ionization of salts, acids and bases in aqueous solutions at high temperatures. [Same as 1333.] T = 18°to306°. R. 0. 1332a. (A. A. Noyes. Jour. Am. Chem. Soc. 32, 815-861, (1910). Quantitative application of the theory of indicators to volumetric analysis.) 1333. A. A. Noyes. Jour. Chim. Phys. 6, 505-523, (1908). La conductibilit6 et I'ionisation des sels des bases et des acides en solution aqueuse aux temperatures ^lev^es. [Same as 1332.] 1334. A. A. Noyes. Zeit. Phys. Chem. 6, 241-267, (1890). Ueber die gegenseitige Beeinflussung der Loslichkeit von dissociierten Korpern. 1335. A. A. Noyes. Zeit. Phys. Chem. 11, 495-500, (1893). Ueber die Wasserstoffionabspaltung bei den sauren Salzen. 1336. (A. A. Noyes. Zeit. Phys. Chem. 26, 699-710, (1898). Ueber die Zuverlassigkeit der mittels der elektrischen Leitfahigkeit bestimmten Dissociationswerte.) [Theoretical and quoted.] 1337. A. A. Noyes, C. G. Abbot. Zeit. Phys. Chem. 16, 125-138, (1895). Eine Pruf ung der Prinzipe der Loslichkeitsbeeinflussung und ein Vergleich der daraus und aus der elektrischen Leitfahigkeit berechtneten Dissociationswerte. T = 39.75°. Hg. U. X4oaq. = 1.7 -2.4X10-'. 1338. A. A. Noyes, J. Johnston. Jour. Am. Chem. Soc. 31, 987-1010, (1909). Meas. R. D. Gale. The conductivity and ionization of polybasic salts. T = 0°tol56°. R. O. xaq.=0.6-0.7X10-«; sub. 1339. A. A. Noyes, Y. Kato. Jour. Am. Chem. Soc. 30, 318-334, (1908). The equivalent conductance of hydrogen-ion derived from transference ex- periments with nitric acid. [Same as 1340.] 1340. A. A. Noyes, Y. Kato. Zeit. Phys. Chem. 62, 420-439, (1908). Ueberfuhrungsversuche mit Salpeter- und Salzsaure. [Same as 1339. ] 1341. A. A. Noyes, Y. Kato, R. B. Sosman. Jour. Am. Chem. Soc. 32, 159-178, (1910). Meas. Y. Kato, R. B. Sosman. The hydrolysis of ammonium acetate and the ionization of water at high tem- peratures. [Same as 1341a.] T = 18°to306°. AUTHOR LIST 487 1341a. A. A. Noyes, Y. Kato, R. B. Sosman. Zeit. Phys. Chem. 73, 1-24, (1910). Die Hydrolyse von Ammoniumacetat und die lonisation von Wasser bei hohen Temperaturen. [Same as 1341.] 1341b. A. A. Noyes, A. C. Melcher, H. C. Cooper, G. W. Eastman. Zeit. Phys. Chem. 70, 33&-377, (1910). Meas. H. C. Cooper. The conductivity and ionization of salts, acids and bases in aqueous solutions at high temperatures. [See also 1332. ] T = 18°to306°- 1342. A. A. Noyes, G. V. Sammet. Zeit. Phys. Chem. 43, 513-538, (1903). Experimentelle Prufung der thermodynamischen Beziehung zwischen der Losungswarme und der Aenderung der Loslichkeit mit der Temperatur im FaUe dissociierter Substanzen. T = 0°to30°. R. O. 1343. A. A. Noyes, W. H. Whitcomb. Jour. Am. Chem. Soc. 27, 747-759, (1905). The solubility of lead sulphate in ammonium acetate solutions. T = 25°. R. O. M. Nozari see A. Campetti. 1344. A. Oberbeck. Ann. Physik. (2), 155, 595-602, (1875). TJeber eine Methode die Leitungsfahigkeit von Flussigkeiten fUr Elektricitat zu bestimmen. "1346. J. Obermiller. Ber. Deutsch. Chem. Ges. 40, 3623-3647, (1907). Ueber die Einwirkung von Schwefelsaure auf Phenol. 1346. J. ObenniUer. Zeit. Anorg. Chem. 69, 79-81, (1908). Die Aciditat der verschiedenen Phenolsulfonsauren. [Criticizes adversely 1090 and 1091. See also 1716. Measurements given in 1346. ] 1347. H. Obladen. Dis. Basel. 1-40, (1906). Ueber a-Aethyl-jS^-pentensaure und a-Aethyl-aj3-pentensaure. [Same as 670. Same as part of 669 for k, but also gives A.] T = 25°. R. O. xaq. =3.5X10-8. MeoLs. H. Obladen; see 569. H. Obladen see F. Fichter. 1348. (G. Oddo, E. Scandola. Gaz. Chim. Ital. 39, II, 1-21, (1909). Sullo stato delle sostanze in soluzione in acido solforico assoluto.) [Criticism of 760 and 761.] 1349. E. Oehler. Dis. Miinchen. (1896). Meas. Bauer. Abkommlinge von Menthon und Tetrahydrocarvon. 1360. H. V. Oettingen. Zeit. Phys. Chem. 33,, 1-38, (1900). Ueber die Zersetzimg des Natriimithiosulfats durch Sauren. T = 20°. P. Offenhauer see F. Stohmann, C. Kleber, Langbein. 1361. M. Oker-Blom. Arch. Gesammt. Physiol. 79, 111-145, (1900). Thierische Safte und Gewebe in physikalisch-chemischer Beziehung. I. Die elektrische Leitfahigkeit des Blutes. 1352. M. Oker-Blom. Arch. Gesammt. Physiol. 79, 510-533, (1900). Thierische Safte und Gewebe in physikalisch-chemischer Beziehung. II. Die Abhangigkeit der elektrischen Leitfahigkeit des Blutes von den Blutkorper- chen. Beitrag zur Lehre von der Leitfahigkeit der Suspensionen. 488 AUTHOR LIST 1353. M. Oker-Blom. Arch. Gesammt. Physiol. 81, 167-221, (1900). Thierische Safte imd Gewebe in physikaUsch-chemischer Beziehung. III. Mittheilung. Die Durchlassigkeit der rothen Blutkorperchen fur verschiedene Stoffe, beurtheilt nach der elektrischen Leitfahigkeit. 1353a. E. OUveri-Mand,aia. Gaz. Chim. Ital. 40, I, 102-107, (1910). Conduttivit^ elettrica di alcuni acidi idrossammici. [Probably 25°.] X25 aq. = 1.5XlO-«. 1354. Y. Osaka. Zeit. Phys. Chem. 35, 661-706, (1900). Ueber die Birotation der d-Glukose. 1355. (Y. Osaka. Zeit. Phys. Chem. 36, 539-542, (1901). Beziehung zwischen der Dissociationskonstante und dem !Dissociationsgrade eines Elektrolyts in Gegenwart anderer Elektrolyte.) Meas. Y. Osaka; see 392. 1355a. W. A. Osborne. Jour. Physiol. 27, 398-406, (1901-1902). Caseinogen and its salts. T = 25°to48.8°. 1356. L. Oslan. Dis. Heidelberg. (1901). Dynamische Untersuchungen uber die Verseifung des Acetessigesters und seiner Methylsubstitutionsprodukte. [Same as 661 for 25°, but gives also measurements at 1° and 35°.] T = l°, 25°, and35°. L. Oslan see H. Goldschmidt. Meas. G. Osswald; see 735. G. Osswald see A. Hantzsch. 1357. W. Ostwald. Jour. Prakt. Chem. (2), 30, 93-95, (1884). Notiz tiber das elektrische Leitungsvermogen der Sauren. 1358. W. Ostwald. Jour. Prakt. Chem. (2), 30, 225-237, (1884). Elektrocheiaische Studien. Die elektrische Leitungsfahigkeit der Sauren. T=25° Special unit for conductivity; see also 1363. 1359. W. Ostwald. Jour. Prakt. Chem. (2), 31, 219-223, (1885). Ueber die Zuverlassigkeit elektrischer Widerstandsbestimmungen mit Wechsel- stromen. T = 25°. Special unit. 1360. W. Ostwald. Jour. Prakt. Chem. (2), 31, 307-317, (1885). Studien zur chemischen Dynamik. Die Inversion des Rohrzuckers. T = 25°. Special unit. 1361. W. Ostwald. Jour. Prakt. Chem. (2), 31, 433-462, (1885). Elektrochemische Studien. Das Verdiinnungsgesetz. T=25°. Special unit. 1362. W. Ostwald. Jour. Prakt. Chem. (2), 32, 300-374, (1885). Elektrochemische Studien. Ueber den Einfluss der Zusammensetzung und Constitution der Sauren auf ihre elektrische Leitfahigkeit. T = 25°. Special unit. [Multiply by 4.248 to change to Hg. U.; see 1363. ] In the tables, all the measurements quoted from this article have been changed to Hg. U. 1363. W. Ostwald. Jour. Prakt. Chem. (2), 33, 352-370, (1886). Elektrochemische Studien. Die elektrische Leitfahigkeit der Basen. T = 25°. Hg. U. 1364. W. Ostwald. Jour. Prakt. Chem. (2), 35, 112-121, (1887). Studien zur chemischen Dynamik. Ueber die Affinitatsgrossen der Basen. T = 25°. 1365. W. Ostwald. Zeit. Phys. Chem. 1, 61-62, (1887). Ueber die Natur der chemischen Verwandschaft. T = 25°. AUTHOR LIST 489 1366. W. Ostwald. Zeit. Phys. Chem. 1, 74-86, (1887). Elektrochemische Studien. Ueber das Gesetz von F. Kohlrausch. T = 25°- Hg. U. 1367. W. Ostwald. Zeit. Phys. Chem. 1, 97-109, (1887). Elektrochemische Studien. Ueber das Gesetz von F. Kohlrausch. T = 25°. Hg. U. 1368. W. Ostwald. Zeit. Phys. Chem. 2, 270-283, (1888). Ueber die Dissociationstheorie der Elektrol3rte. T = 25°. Hg. U. J(:aq. = 1.8-2.0X10-^ 1368a. W. Ostwald. Zeit. Phys. Chem. 2, 840-851, (1888). Elektrochemische Studien. T = 25°. Hg. U. xaq. = l.&-2.0XlO-« sub. 1369. W. Ostwald. Zeit. Phys. Chem. 2, 901-904, (1888). Ueber die Bestimmung der Basicitat der Sauren aus der elektrischen Leit- fahigkeit ihrer Natriumsalze. T = 25°. Hg. U. 1370. W. Ostwald. Zeit. Phys. Chem. 3, 170-197, (1889). Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Zusammensetzung und Konstitution derselben. [Given in 1377.] T=25°. Hg. U. 1371. W. Ostwald. Zeit. Phys. Chem. 3, 241-288, (1889). i^Meas. P. Walden. Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Zusammensetzung und Konstitution derselben. [Given in 1377.] T = 25°. Hg. U. 1372. W. Ostwald. Zeit. Phys. Chem. 3, 369-422, (1889). Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Zusammensetzung und Konstitution derselben. [Given in 1377. ] T=25°. Hg. U. 1373. W. Ostwald. Zeit. Phys. Chem. 5, 268, (1890). Meas. Bader. Ueber die Isozimmtsaure, eine in den Nebenalkaloiden des Cocains vorkom- mende Saure. [This is a review of 1102 and the measurement by Bader is the same as in 1102. ] 1374. W. Ostwald. Zeit. Phys. Chem. 8, 427-428, (1891). Meas. Bersch. [The value of k, without a table of A, is given in a review of 165. ] 1375. (W. Ostwald. Zeit. Phys. Chem. 9, 553-562, (1892). Ueber mehrbasische Sauren.) [Same as 1378. Quoted.] 1376. W. Ostwald. Zeit. Phys. Chem. 11, 521-528, (1893). Die Dissociation des Wassers. 1377. W. Ostwald. Abhand. Kon. Sachs. Ges. Wis. 15, 95-241, (1889). $Meas. P. Walden. Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Zusammensetzung und Constitution derselben. [Same as 1370, 1371 and 1372, together.] 1378. (W. Ostwald. Ber. Verhand. Sachs. Ges. Wis. 43, 228-238, (1891). Ueber mehrbasische Saiiren.) [Same as 1375.] [It is probable that the following measurements, stated to have been made by Ostwald, were in many cases made by students in his laboratory and are published elsewhere.] Meas. W. Ostwald; see 63, 72, 419, 727, 1102, 1103, 1105, 1543. A. Oswald see K. Auwers. 490 AUTHOR LIST, 1379. K. Ott. Dis. Munchen. (1908). Ueber Sulfide und Sulfine. T = 25°. 1380. J. D. Otten. Dis. Munchen. (1887). Die electrische Leitungsfahigkeit der Fettsauren und ihre Abhangigkeit von der Temperatur. [Abstracted in Beibl. Ann. Physik. 12, 259-260, (1888). Original not examined by me.] Meas. Ottiker; see 471, 478. Ottiker see P. Dutoit. G. E. Owen see A. Findlay, W. E. S. Turner. P. V. Pachkoff see P. Chroustchoff. 1381. M. Padoa, B. Savare. Gaz. Chim. Ital. 36, I, 313-321, (1906). Sulla natura del ioduro d'amido. [Same as 1382. ] T = 18°. 1382. M. Padoa, B. Savare. Rend. Accad. Lincei (5), 14, I, 467-47'6, (1905). Sulla natura del ioduro d'amido. [Same as 1381.] H. H. Paine see W. C. D. Whetham. F. C. Palazzo see A. Peratoner. Meas. S. Palitzsch; see 1639b. 1383. W. Palmaer. Zeit. Phys. Chem. 22, 492-504, (1897). Ueber das Verhaltnis zwischen Inversionsgeschwindigkeit und Konzentration der Wasserstoffionen. T=20°. Meas. C. S. Palmer; see 1697. G. Papasogli see A. Bartoli. 1384. N. Parravano, A. Pasta. Gaz. Chim. Ital. 37, II, 252-264, (1907). Sopra alcuni bicromati di metaUi bivalenti con le basi organiche. 1385. N. Parravano, G. Tommasi. Gaz. Chim. Ital. 39, II, 60-64, (1909). I sali dell'acido feniltioglicolico. 1386. C. L. Parsons. Jour. Phys. Chem. 11, 659-680, (1907). Solution in a dissolved solid. T = 25° R. 0. 1386a. J. R. Partington. Jour. Chem. Soc. 97, 1158-1170, (1910). Ionic equilibrium in solutions of electrolytes. F. Paschke see E. Wedekind. 1386b. Paschkow. Dis. Charkow. (1892). [Original not examined by me. ] Quoted in 1843. 1387. W. P. Paschkow. Congr. russ. Naturf. Aerz. Abstracted in Chem. Ztg., 14, I, 126, (1890). Ueber die electrische Leitungsfahigkeit einiger organischer Sauren und deren Saize mit AlkalimetaUen. V. Pashkoff see V. Pachkoff. Paskov see Pachkofi. A. Pasta see N. Parravano. W. A. Patrick see E. H. Archibald. 1388. H. E. Patten. Jour. Phys. Chem. 6, 554r-600, (1902). Influence of the solvent in electrolytic conduction. T = 25°. R. O. :w:aq.=4X10-«. AUTHOR LIST 491 1389. H. E. Patten, W. R. Mott. Jour. Phys. Chem. 12, 49-74, (1908). Decomposition curves of lithium chloride in pyridine and in acetone — the effect of water. 1390. M. Paul. Dis. Nancy. (1906). Contribution k I'^tude de la dissociation ^lectrolytique en milieu hydroalco- olique. [This gives data and tables of A for 1297. ] T = 25°and35°. R. O. X25 aq. =1X10-8- M. Paul see P. T. Mullet. 1391. T. Paul. Arch. Pharm. 239, 48-90, (1901). Untersuchungen uber Theobromin und Koffein und ihre Salzbildung. [Cor- rected in Zeit. Phys. Chem. 36, 749, foot-note. (1901).] T = 18° and 25°. R. O. x aq. = 1.0 and I.IXIO-^; sub. Meas. T. Paul; see 60, 63, 68, 69, 1104, 1212, 1398, 1670, 1672. T. Paul see W. His. 1391a. T. Paul, A. Giinther. Arbeit, k. Gesundh. 29, 218-271, (1908). ifi Meas. P. Mam. Untersuchungen iiber den Sauregrad des Weines auf Grund der neueren The- orien der Losungen. T=76°. 1392. T. Paul, B. KrSnig. Zeit. Phys. Chem. 21, 414-450, (1896). Ueber das Verhalten der Bakterien zu chemischen Reagentien. [Qualitative. ] 1393. W. Pauli. Beitr. Chem. Physiol. Pathol. 7, 531-547, (1905-1906). Untersuchungen iiber physikalische Zustandsanderungen der KoUoide. Fiinfte MitteUung. Die elektrische Ladtmg von Eiweiss. 1394. W. PauU. Beitr. Chem. Physiol. Pathol. 10, 53-79, (1907). Untersuchungen iiber physikalische Zustandsanderungen der KoUoide. Sechste MitteUung. Die Hitzekoagulation von Saureeiweiss. 1395. W. PauU. Naturwis. Rundsch. 21, 3-5, (1906). Ueber die elektrische Ladung von Eiweiss und ihre Bedeutung. 1396. W. PauU. Naturwis. Rundsch. 21, 17-20, (1906). Ueber die elektrische Ladung von Eiweiss und ihre Bedeutung. 1397. W. Pauli, H. Handovsky. Biochem. Zeit. 18, 340-371, (1909). Untersuchungen iiber physikaUsche Zustandsanderungen der KoUoide. VIII. Mitteilung. Studien am Saureeiweiss. *1397a. H. Pauly, J. Weir. Ber. Deutsch. Chem. Ges. 43, 661-670, (1910). Ueber die einseitige EsterbUdung der Benzoyl-asparaginsaure. T = 25°. *1397b. W. PauU, H. Handovsky. Biochem. Zeit. 24, 239-262, (1910). Untersuchungen iiber physikalische Zustandsanderungen der KoUoide. IX. MitteUung. Studien am AJkalieiweiss. T = 25°. *1397c. H. Pauly, K. Schiibel, K. Lockemann. Ann. Chemie. 383, 288-337, (1911). Ueber die Reaktionsfahigkeit der Phenolgruppen in den Phenolaldehyden. T=25°. R. O. j<:26aq.= 8.7X10-'. J. N. Pearce see H. C. Jones. 1398. H. V. Pechmann. Ber. Deutsch. Chem. Ges. 33, 3323-3341, (1900). Meas. T. Paid. Ueber Dicrotonsaure. 1399. H. T. Pechmann, F. Neger. Ann. Chemie. 273, 186-214, (1893). Ueber die Einwirkung von Essigsaureanhydrid auf Acetondicarbonsaure. Pelet see Pelet-JoUvet. * These are out of order on account of late insertion. 492 AUTHOR LIST 1400. L. Pelet-Jolivet. Bui. Soo. Vaudoise. (5), 45, 73-152, (1909). Etudes th^oriques sur les ph^nom^nes de teinture. [Same as 1402 and 1404, except that no measurement is given for Congo Red. ] T = 25° R. O. 1401. L. Pelet, V. Garuti. Bui. Soc. Vaudoise. (5), 43, 1-29, (1907). Meas. E. Francillon. Dosage volume trique des matiSres colorantes. Dosage des matiferes colorantes basiques au moyen des matiSres colorantes acides. 1402. L. Pelet- JoUvet, A. Wild. Bui. Soc. Chim. (4), 3, 1087-1094, (1908). Etudes des matifires colorantes en solution. [Same as 1404. Same as 1400, except that measurement of Congo Red is given here. Summary with some data is given in 1403. ] T=25°. R. O. 1403. L. Pelet- JoUvet, A. Wild. Compt. Rend. 147, 683-685, (1908). Etat de mati^res colorantes en solution. [Given in 1400, 1402 and 1404. ] T = 25°. R. O. 1404. L. Pelet-Jolivet, A. WUd. Zeit. Chem. Ind. KoUoid, 3, 174^177, (1908). Untersuchungen ilber die Farbstoffe in Losung. [Same as 1402. See 1400 and 1403.] T = 2S°. R. O. 1405. (H. Pellat. Compt. Rend. 144, 902-904, (1907). Determination directe de la valeur absolue de la charge flectrique d'un ion eiectrolytique monovalent. — DiamStre d'un atome.) 1406. (H. Pellat. Jour. Phys. (4), 7, 195-203, (1908). Sur la th^orie de M. Nernst concernant la difference de potentiel entre elec- trode et eiectroljrte.) 1407. A. Peratoner, F. C. Palazzo. Gaz. Chim. Ital. 36, I, 7-13, (1906). Sulla costituzione dell'acido comenioo. [Same as 1408 and 1409.] 1408. A. Peratoner, F. C. Palazzo. Giorn. Sci. Nat. Econ. 25, 245-251, (1905). Sulla costituzione dell'acido comenico. [Same as 1407 and 1409.] 1409. A. Peratoner, F. C. Palazzo. Rend. Soc. Chim. Roma, 1, 40-41, (1903). Sulla costituzione dell'acido comenico. [Same as 1407 and 1408. ] 1410. W. H. Perkin, Jr. Jour. Chem. Soc. 65, 572-591, (1894). Meas. J. Walker. The cis- and trans- modifications of l;2-tetramethylenedicarboxylic acid, and 1; 2-pentamethylenedicarboxyHc acid. 1411. W. H. Perkin, Jr. Jour. Chem. Soc. 69, 1457-1506, (1896). Meas. T. Ewan, and J. Walker. Some derivatives of propionic acid, of acrylic acid, and of glutaric acid. W. H. Perkin, Jr. see W. A. Bone. " " " " see A. W. Crossley. 1412. W. H. Perkin, Jr., B. Prentice. Jour. Chem. Soc. 59, 818-852, (1891). Meas. J. Walker. Synthesis of homologues of pentanetetracarboxylic acid and of pimelic acid. 1413. W. H. Perkin, Jr., J. L. Simonsen. Jour. Chem. Soc. 91, 840-848, (1907). The action of tribromopropane on the sodium derivative of ethyl malonate. Part II. Formation of A"f heptadi-inene-3-carboxylic acid (i/'-m-toluic acid), (CH:C.CH2)2C(C02H)2. AUTHOR LIST 493 1414. W. H. Perkin, Jr., W. Sinclair. Jour. Chem. Soc. 61, 3&-66, (1892). Meas. J. Walker. The synthetical formation of closed carbon chains. Part II. Derivatives of tetramethylene. 1415. E. Petersen. Zeit. Phys. Chem. 22, 410-423, (1897). Ueber die Anzahl der lonen in einigen Kobalt-Ammoniakverbindungen. T = 0°and25° xzs aq.= 2.7X10-6; sub. 1416. E. Petersen. Kong. Danske Vids. Selsk. Skrift. (6), 7, 303-336, (1890-1894). Om den elektrolytiske Dissociationsvarme af nogle Syrer. T = 21.5°. Meas. E. Petersen; see 886. 1417. (J. Petersen. Zeit. Phys. Chem. 10, 580-592, (1892). Einige Versuche, die physischen Verhaltnisse der Metallammoniakverbin- dungen betreffend.) T = 18°. A. Pezzolato see R. Nasini. 1418. A. Pfaff. Dis. Heidelberg. (1897). [In autobiography gives the name as A. E. Pfaff.] Ueber die elektrische Leitfahigkeit organischer Sauren. T=25°. Meas. A. Pfaff; see 61, 64, 326. 1419. E. Pfeiffer. Ann. Physik. (3), 25, 232-245, (1885). Ueber die electrische Leitungsfahigkeit der Mischungen von Wasser und Alkohol. T = 0°tol6°. 1420. E. Pfeiffer. Ann. Physik. (3), 26, 31-44, (1885). Ueber die electrische Leitungsfahigkeit des absoluten Alkohols. T=B,oom T and 30°. 1421. E. W. R. Pfeiffer. Ann. Physik. (3), 26, 226-239, (1885). Ueber die electrische Leitungsfahigkeit der Mischungen von Aethylalkohol mit Aethylather. Hg. U. T = 15°and30°. Meas. Pfenning; see 186a. Meas. A. Pfister; see 1547. A. Pfister see F. Fichter. Meas. A. Pheophilaktowa; see 1670. 1422. J. C. Philip. Jour. Chem. Soc. 93, 925-927, (1908). The dissociation constants of triazoacetic and a-triazopropionic acids. T=25°. ^26 aq. =2X10-6; sub. only for sodium salts, [k, but not A given in 1423.] 1423. J. C. Philip. Proc. Chem. Soc. 24, 114-115, (1908). The dissociation constants of, etc. [Same as 1422 for k.] 1423a. J. C. Philip, H. R. Coxirtman. Jour. Chem. Soc. 97, 1261-1271, (1910). Behaviour of two salts with a common ion, when dissolved in an organic sol- vent. [A qualitative statement is given in 1423b.] T =25°. K of solvent is sub. 1423b. J. C. Philip, H. R. Courtman. Proc. Chem. Soc. 26, 140, (1910). Behaviour of two salts, etc. [Qualitative. Given in 1423a with full data. ] 1424. (A. Piccini. Zeit. Anorg. Chem. 8, 115-120, (1895). Ueber die Losungen des grunen Chromchlorids CrCl3.6H20.) [Inorganic] 494 AUTHOR LIST 1425. N. Picton. Dis. Leipzig. (1908). Ueber Umlagerungen aromatischer Nitrokorper. N. Picton see A. Hantzsch. 1426. (B. Piesch. Phil. Mag. (5), 38, 336, (1894). Alterations of the electrical resistance of aqueous solutions and of galvanic polarization with pressure.) [An abstract of 1427 without data.] 1427. B. Piesch. Sitzber. Akad. Wien. 103, 2a, 784-808, (1894). Aenderungen des elektrischen Widerstandes wasseriger Losungen und der galvanischen Polarisation mit dem Drucke. [See 1426.] T = RoomT. S. U. 1428. S. Pilat. Dis. Leipzig. (1905). Intramoleculare Veranderungen der Cyanursaure und ihrer Salze. T = 25° to96.2°. Meas. S. Pilat; see 738. 1429. W. Pip. Dis. Heidelberg. (1898). I. Ueber die elektrische Leitfahigkeit einiger aromatischer Sauren. II. Ueber die Farbstoffbildung aus DiazobenzolsuUosaure und salzsaurem Monoathyl- p-toluidin. T = 25°. xaq. = 2.6X10-8; [probably sub.] Pisarzevskij see Pissarjewsky. 1430. (L. Pissarjewsky, E. Karp. Jour. Russ. Phys.-chem. Soe. 40, 564- 565, (1908). Relations between the constant of diffusion, the internal friction and electrical conductivity.) [Summary of 1431 without data.] 1431. (L. Pissarjewsky, E. Karp. Jour. Russ. Phys.-chem. Soc. 40, 599- 611, (1908). Relations between the constant of diffusion, the internal friction and electrical conductivity.) [Same as 1432. See 1430.] 1432. (L. Pissarjewsky, E. Karp. Zeit. Phys. Chem. 63, 267-268, (1908). Die Beziehung zwischen der Diffusionskonstante, der innern Reibung und dem elektrischen Leitvermogen.) [Same as 1431. Inorganic] 1433. L. Pissarjewsky, N. Lemcke. Jour. Russ. Phys.-chem. Soc. 37, 492- 502, (1905). Electrical conductivity and internal friction. [Same as 1434.] T = 25°. 1434. L. Pissarjewsky, N. Lemcke. Zeit. Phys. Chem. 52, 479-493, (1905). Der Einfluss des Losungsmittels auf die Gleichgewichtskonstante und die Beziehung zwischen dem elektrischen Leitvermogen und der innem Reibung. [Same as 1433.] T=25°. 1434a. L. Pissarjewsky, A. SapoTalenko. Jour. Russ. Phys.-chem. Soc. 42, 905-938, (1910). The electrical conductivity of KBr and KAg(CN)2 in mixtures of glycerol with alcohols. T = 25°and45°. R. Pizzighelli see A. Miolati; 1269. Plotnikov see Plotnikow. 1436. W. A. Plotnikow. Ber. Deutsch. Chem. Ges. 39, 1794-1804, (1906). Ueber die Verbindungen von Dimethylpyron mit Trichloressigsaure. Elektrisches Leitvermogen der Losungen in Aethylbromid, Chloroform und Benzol. [Tables of A and conclusions same as in 1439 and 1440 together, «xcept that potassium trichloroacetate in ethyl bromide is not given here. ] T = 18°- R. O. AUTHOR LIST 495 1436. W. A. Plotniko-w. Ber. Deutsch. Chem. Ges. 42, 1154-1158, (1908). Ueber die Verbindungen von Dimethyl-pyron mit Tribrom-essigsaure. [Same as 1442.] T = 18°. 1437. "W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 34, 466-472, (1902). The electrical conductivity of solutions in ethyl bromide. T = 18°. 1438. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 35, 794-810, (1903). The electrical conductivity of bromine solutions. [Same as 1446.] T = 18° 1439. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 37, 318-337, (1905). Investigation of the electrical conductivity of non-aqueous solutions. IV. The electrical conductivity of solutions in ethyl bromide. On compounds of dimethylpyrone with acids. [Tables of A and conclusions are given in 1435. ] 1440. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 37, 875-881, (1905). Investigation of the electrical conductivity of non-aqueous solutions. V. The electrical conductivity of solutions of compounds of dimethylpyrone and tri- chloroacetic acid in chloroform and benzene. [Tables of A are given in 1436.] 1441. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 38, 1096-1104, (1906). Investigation of the electrical conductivity of non-aqueous solutions. VI. Bromine and ether. [Same as 1447.] T = 18°and0''. 1442. "W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 1238-1243, (1908). The electrical conductivity of solutions of tribromoacetio acid dimethyl pyro- nates in ethyl bromide. [Same as 1436. ] T = 18°. 1443. (W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 1243-1247, (1908). Anomalies of the direction of curves which express the change in molecular electrical conductivity in connection with the concentration.) [Theoretical and quoted. ] 1444. (W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 1247-1257, (1908). The decomposition of complex ions.) 1444a. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 42, 1589-1596, (1910). The electrical conductivity of non-aqueous solutions. VIII. Aluminum brom- ide and nitrobenzol. T = 25°. 1445. W. A. Plotnikow. Zeit. Anorg. Chem. 56, 53-57, (1907). Ueber die Verbindung von Aluminiumbromid mit Aether. 1446. W. A. Plotnikow. Zeit. Phys. Chem. 48, 220-236, (1904). Das elektrische Leitvermogen der Losungen in Brom. [Same as 1438. ] T = 18° R. O. 1447. W. A. Plotnikow. Zeit. Phys. Chem. 57, 502-506, (1906). Die elektrische Leitfahigkeit der Gemische von Brom und Aether. [Same as 1441.] W. A. Plotnikow see V. V. Neminskij. 1447a. G. Polara. Atti Accad. Gioenia. (5), 3, Mem. 6, (1901). Sulla conducibihta elettrica della saliva mista dell'uomo. T = 18°. 496 AUTHOR LIST 1448. C. Pomeranz. Monatsh. 18, 575-581, (1897). Zur Kenntniss des Pinacolins. [Same as 1449. ] 1449. C. Pomeranz. Sitzber. Akad. Wien. 106, 2b, 579-585, (1897). Zur Kenntniss des Pinacolins. [Same as 1448.] 1450. K.T.Pospischill. Ber. Deutsch. Ch.em. Ges. 31, 1950-1957, (1898). Ueber die beiden stereoisomeren 1,3-Pentamethendicarbonsauren. [Same as 1461.] 1451. K. T. Pospischill. Dis. Leipzig. (1896). Ueber die beiden stereoisomeren, etc. [Same as 1450.] Meas. A. Postinkov; see 1760a. 1452. A. Praetorius. Monatsh. 28, 767-802, (1907). Ueber die alkoholische Verseifung der Benzolsulfosaureester. [Same as 1463.] T = 50°. R. O. 1463. A. Praetorius. Sitzber. Akad. Wien. 116, 2b, 669-704, (1907). Ueber die alkoholische Verseifung der Benzolsulfosaureester. [Same as 1452. ] Meas. W. Praetorius; see 746, 752, 782. B. Prentice see W. H. Perkin, Jr. H. Probst see F. Fichter. 1464. D. Protopopov, S. Reformatsky. Jour. Russ. Phys.-chem. Soc. 33, 242-246, (1901). Synthesis and properties of a-isopropyl-/3-isobutylethylenelactic, acid. 1465. (P. F. S. Provenzali. Atti Pont. Accad. Nuov. Lincei. 43, 58, (1890). Presentazione di una memoria manoscritta sulle relazioni fra le propriety, ottiche dei corpi, e la loro faooltS, conduttrice per I'elettrico.) [Summary of 1466.] 1468. (P. F. S. Provenzali. Mem. Pont. Accad. Nuov. Lincei. 6, 7-23, (1890). Sulle relazioni fra le propriety ottiche dei corpi.) [Inorganic] 1467. (M. Prud'homme. Bui. Soc. Chim. (4), 1, 562-569, (1907). Relations entre la conductibilit6 mol^culaire des Electrolytes et la dilution.) [Same as 1458 and 1460. Quoted.] 1468. (M. Prud'homme. Jour. Chim. Phys. 5, 386-397, (1907). Relations entre la conductibihtE, etc.) [Same as 1457 and 1460.] 1459. (M. Prud'homme. Jour. Chim. Phys. 5, 497-510, (1907). Sur les demi-(51ectrolytes.) [Quoted.] 1460. (M. Prud'homme. Zeit. Elektrochem. 13, 471-474, (1907). Beziehungen zwischen der molekularen Leitfahigkeit von Elektrolyten und der Verdiinnung.) [Same as 1457 and 1468.] 1461. L. Prussia. Gaz. Chim. Ital. 28, II, 113-122, (1898). Ricerche sul cianuro di mercurio. [Qualitative.] 1462. G. Quagliariello. Rend. Accad. Lincei. (5), 18, II, 217-222, (1909). Modificazioni deUe propriety, chimico-fisiche del siero di sangue riscaldato a 55°-60° C. T = 37°. 1462a. P. Quinet. Compt. Rend. 147, 203-206, (1908). Formation de composes dans les solutions d'acide tartrique et de molybdate de soude. [Given in 1463. ] T = 20.5°±0.5°. AUTHOR LIST 497 1463. P. Quinet. Jour. Phys. (4), 8, 278-290, (1909). Formation de composes dans les solutions d'acide tartrique et de molybdates. [1462a gives only sodium molybdate,] T =20.5° ±0.5°. ^ 1464. A. V. Raalte. Rec. Trav. Chim. 18, 378-407, (1899). Sur le phenyl- et le parachlorph6nyl- nitrom^thane. T = l.l° to25.2°. 1464a. P. Rabe. Ber. Deutsch. Chem. Ges. 43, 2964-2971, (1910). Meas. C. Boy. Ueber Mutarotation und elektrische Leitfahigkeit bei Zuckern. I. Mitteilung; Ueber den Traubenzucker. T = 20°. xaq. =2.07X10-°; not sub. R. Radenliausen see T. Curtius. 1465. L. Ramberg. Ber. Deutsch. Chem. Ges. 40, 2588-2589, (1907). Notiz iiber die Aethyl-thioglykolsaure. T = 25°. R. O. xaq. =2X10-6; not sub. 1466. L. Ramberg. Zeit. Anorg. Chem. 50, 439-445, (1906). Ueber die Platosalze einiger schwefelhaltigen organischen Sauren. [Qualita- tive. ] 1467. L. Ramberg. Zeit. Phys. Chem. 34, 561-592, (1900). Ueber die Einwirkung von Brom auf Phenylsulfonessigsaure und a-Phenylsul- fonpropionsaure in wasseriger Losung, ein Beitrag zur chemischen Kinetik. 1468. C. Ranken, W. W. Taylor. Proc. R. Soc. Edinburgh. 27, 172-180, (1906-1907). The physical properties of mixed solutions of independent optically-active substances. T = 15°and25°. R. O. 1469. (F. M. Raoult. Compt. Rend. 107, 442-445, (1888). Sur les tensions de vapeur des dissolutions faites dans I'alcool.) 1470. H. Rappeport. Dis. Lausanne. (1907). Conductibilit& Umites dans quelques dissolvants organiques. [Most is given in 491.] T = 18°. S. U. H. Rappeport see P. Dutoit. 1471. E. Rasch, F. W. Hinrichsen. Zeit. Elektrochem. 14, 41-46, (1908). Meas. Roller. Ueber eine Beziehung zwischen elektrischer Leitfahigkeit und Temperatur. T=297°to408°- 1471a. A. Rassenfosse. Bui. Acad. Belg. (1909), 995-1007. Contribution h I'^tude des phSnomSnes de conductibiUtS ^lectrolytique des solutions fluoresoentes. 1472. F. Ratz. Zeit. Phys. Chem. 19, 94-112, (1896). Ueber die Dielektrizitatskonstante von Flussigkeiten in ihrer Abhangigkeit von Temperatur und Druck. T = 0°to60°. Reformatskij see Refonnatsky. 1473. S. Refonnatsky. Ber. Deutsch. Chem. Ges. 28, 3262-3265, (1895). Neue DarsteUungsmethode der a,a-Dimethylglutarsaure aus der entsprechen- den Oxysaure. [Same as 1474, but does not state that Szyszkowski made the measurement. ] T=25°. 498 AUTHOR LIST 1474. S. Reformatsky. Jour. Russ. Phys.-chem. Soc. 28, 149-158, (1896). Meas. Szyszkowski. New method of obtaining a,a-dimethylglutarie acid from the corresponding oxyacid. [Same as 1473.] T=25°. 1476. S. Refonnatsky. Jour. Russ. Phys.-chem. Soc. 30, 453-466, (1898). Meas. J. I. Michajlenko. Preparation and properties of a,a-dimethyl-/3-oxyglutaric acid. S. Refonnatsky see D. Protopopov. " " see B. Szyszkowski. 1476. K. Regner. Phys. Zeit. 4, 862-865, (1902-1903). Ueber die Frage der Widerstandsanderung von wasserigen Salzlosungen durch Bestrahlung. 1477. M. Reich. Dis. Berlin. (1900). Ueber elektrische Leitung reiner Substanzen. T = 13°to22°. L. T. Reicher see J. H. van't Hoff. 1478. E. Reichert. Zeit. Analyt. Chem. 28, 1-26, (1889). Anwendung des elektrolytischen Leitungsvermogens zu quantitativen Bestim- mungen. T = 18°±0.1°. S. U. 1479. E. E. Reid. Am. Chem. Jour. 41, 483-510, (1909). The alcoholysis or esterification of acid amides. 1480. A. "W. Reinold. Nature. 48, 624-626, (1893). The thickness and electrical conductivity of thin liquid films. T = 17° to27°. 1481. F. Reitzenstein. Zeit. Anorg. Chem. 11, 254r-263, (1896). Ueber einige Metallsalze mit organischen Basen. T = 18°. 1482. F. Reitzenstein. Zeit. Anorg. Chem. 18, 253-304, (1898). Ammoniak-P3T:idinsalze und Hydrate bivalenter Metalle. T=0°. F. Reizenstein. Zeit. Anorg. Chem. 11, 264, should be Reitzenstein. 1483. (A. Reychler. Jour. Chim. Phys. 7, 58-67, (1909). Sur I'^quilibrfi de dissociation des Electrolytes binaires.) 1484. (J. W. Richards, W. S. Landis. Trans. Am. Electrochem. Soc. 16, 85-91, (1909). The practical conductance of electrolytes.) [Inorganic] O. W. Richardson see H. O. Jones. 1485. E. Rieger. Zeit. Elektrochem. 7, 871-876, (1900-1901). Ueber die Konstitution halbkomplexer Salze nach ihrer elektrolytischen Ueberfiihrung. [Same as 1486. ] 1486. E. Rieger. Dis. Breslau. (1901). Ueber die Existenz komplexer lonen in Doppelsalzen auf Grund von Ueber- fuhrungsbestimmungen. [Same as 1486. ] 1487. E. H. Riesenfeld. Ber. Deutsch. Chem. Ges. 41, 3536-3552, (1908). Meas. A. Wesch. Hohere Oxydationsprodukte des Chroms. 4. MitteUung. Ueber Chromte- troxyd- Verbindungen. [Same as 1962.] T = 18°. R. O. «aq. = 1.8X10-5 and 5.8X10-6. 1488. E. H. Riesenfeld. Zeit. Phys. Chem. 41, 346-352, (1902). Ueber den Molekularzustand von Jodkalium in Phenol. T=25°and43°. AUTHOR LIST 499 1489. (A. Righi. Jour. Phys. (4), 7, 589-617, (1908). Sur quelques ph^nomtoes dus aux rencontres entre Electrons, iona, atomes et molecules.) [Gases; and theoretical. ] 1490. A. Righi. Nuovo Cim. (5), 10, 113-122, (1906). Sulla diminuzione di resistenza prodotta nei eattivi conduttori dai raggi del radio. [Same as 1491. Qualitative.] 1491. A. Righi. Rend. Accad. Lincei. (5), 14, II, 207-214, (1905). Sulla diminuzione di resistenza, etc. [Same as 1490. ] 1492. E. Rimbach. Zeit. Phys. Chem. 16, 671-676, (1895). Dissociation und optische Drehung aktiver Salzlosungen. T = 20°. 1493. E. Rimbach, E. Heiten. Ann. Chemie. 359, 317-335, (1908). Ueber Eigenschaften, inbesondere das Drehungsvermogen des Saccharins und der Alkalisaccharinate. [Same as 797.] T = 25°. R. O. xaq. sub. 1494. E. Rimbach, F. Korten. Zeit. Anorg. Chem. 52, 406-415, (1907). Ueber einige Verbindungen dss Iridiums. T = 25°. 1495. E. Rimbach, C. Neizert. Zeit. Anorg. Chem. 52, 397-405, (1907). Zur Komplexbildung in Molybdansaurelosungen. T = 25°. R. O. xaq. sub. 1496. E. Rimbach, A. Schubert. Zeit. Phys. Chem. 67, 183-200, (1909). Loslichkeit einiger schwerloslicher Salze seltener ErdmetaUe. [Same com- pounds with additional measurements given in 1600. ] T = 19°to27°. R. O. xaq. = 1X10-^ or less; measurements given =i=x aq. 1497. E. Rimbach, O. Weber. Zeit. Phys. Chem. 51, 473-493, (1905). Ueber Einwirkung anorganischer Substanzen auf die Drehung von Lavulose und Glukose. [T probably 20°.] R. O. x aq. not over 2X10-«; sub. E. Rimini see A. Angeli. A. Rinckenberger see A. Hantzsch. 1498. W. E. Ringer. Zeit. Physiol. Chem. 60, 341-363, (1909). Zur Aciditat des Hams. T = 18°. 1499. P. Rivals. Ann. Chim. Phys. (7), 12, 501-574, (1897). Recherches thermochimiques sur quelques composes chlor^s des series an- tique, benzoique et sahcylique. [Same as 1500. ] T = 16°. S. U. 1600. P. Rivals. Compt. Rend. 125, 574^576, (1897). Sur la conductibiht^ flectrolytique de I'acide trichlorac^tique. [Same as 1499. ] A. C. D. Rivett see N. V. Sidgwick. 1500a. A. C. D. Rivett, N. V. Sidgwick. Jour. Chem. Soc. 97, 732-741, (1910). The rate of hydration of acetic anhydride. T = 25°. R. O. X aq.=0.6-1.5X10-^ 1500b. A. C. D. Rivett, N. V. Sidgwick. Jour. Chem. Soc. 97, 1677-1686, (1910). The rate of hydration of acid anhydrides; succinic, methylsuccinic, itaconic, maleic, citraconic, and phthalic. [k, but no cond. is given in 1500c.] T = 25° 1600c. A. C. D. Rivett, N. V. Sidgwick. Proc. Chem. Soc. 26, 200, (1910). The rate of hydration, etc. [Only k is given here. Tables of cond. are given in 1600b.] D. J. Roberts see J. J. Sudborough. 500 AUTHOR LIST 1501. T. B. Robertson. Jour. Biol. Chem. 2, 317-383, (1906-1907). Studies in the chemistry of the ion-proteid compounds. IV. On some chem- ical properties of casein and their possible relation to the chemical behavior of other protein bodies, with especial reference to hydrolysis of casein by trypsin. 1501a. T. B. Robertson. Jour. Biol. Chem. 7, 351-357, (1909-1910). Concerning the relative magnitude of the parts played by the proteins and by the bi-carbonates in the maintenance of the neutrality of the blood. T = 34°. 1502. (T. B. Robertson. Jour. Phys. Chem. 10, 624-582, (1906). On the conditions of equilibrium of an associating amphoteric electrolyte in the presence of any number of non-amphoteric electrolytes.) [Theoretical. Gives also a bibliography of the dissociation of proteins. ] 1503. T. B. Robertson. Jour. Phys. Chem. 11, 437^59, (1907). On the dissociation of ssrum globulin at varying hydrogen ion concentrations. T usually 20°. R. O. x aq.=7.3XlO-«; sub. 1504. T. B. Robertson. Jour. Phys. Chem. 11, 542-552, (1907). On the dissociation of solutions of the neutral caseinates of sodium and am- monium. T=25°. R. O. xaq. =8X10-8; sub. 1505. T. B. Robertson. Jour. Phys. Chem. 12, 473-483, (1908). On the dissociation of solutions of the " basic " caseinates of sodium and am- monium. 1506. T. B. Robertson. Jour. Phys. Chem. 13, 469-489, (1909). On the refractive indices of solutions of the caseinates and the acid- and alkali-equivalents of casein. 1506a. T. B. Robertson. Jour. Phys. Chem. 14, 528-568, (1910). Studies in the electrochemistry of the proteins. I. The dissociation of po- tassium caseinate in solutions of varying alkalinity. T = 30°. R. 0. K aq. not over SXlO-^; not sub. 1606b. T. B. Robertson. Jour. Phys. Chem. 14, 601-611, (1910). Studies in the electrochemistry of the proteins. II. The dissociation of solu- tions of the " basic " caseinates of the alkaline earths. T = 30°- R. O. xaq. =4.5X10-"; sub. 1506c. T. B. Robertson. Jour. Phys. Chem. 14, 709-718, (1910). Studies in the electrochemistry of the proteins. III. The dissociation of the salts of ovo-mucoid in solutions of varying alkalinity and acidity. T = 20°. R. O. R. Robison see A. Hantzsch. L. Roder see H. Goldschmidt. 1506d. H. Rohler. Zeit. Elektrochem. 16, 419-436, (1910). Untersuchungen Tiber Formamid als Losungsmittel fiir anorganische Salze und ilber die Elektrolyse dieser Losungen. [Same as 1507.] T=25°. 1507. H. Rohler. Dis. Leipzig. (1909). Untersuchungen iiber Formamid als Losungsmittel, etc. [Same as 1506d. ] 1508. H. Roemer. Dis. Munster. (1907). Bestimmung der Basizitat durch Titration mittels Leitfahigkeitsmessung mit besonderer Beriicksichtigung hydroxylhaltiger aromatischer Verbindungen. [Most is given in 1718. ] T = 25°. R. O. ;«: aq.= 9.5X10-8; not sub. H. Roemer see A. Thiel. " " see A. Thiel, A. Schumacher. AUTHOR LIST 501 1509. W. C. RSntgen. Ann. Physik. (3), 52, 593-603, (1894). Ueber die Einfluss des Druckes auf die Dieleotricitatsconstante des Wassers und des Aethylalcohols. 1510. (W. C. RSntgen. Naohr. Ges. Wis. Gottingen. (1893), 505-511. Ueber den Einfluss des Druckes auf das galvanische Leitungsvermogen von Electrolyten.) [Inorganic] 1511. (W. C. Rontgen. Sitzber. Phys.-med. Ges. Wtirzburg. (1895), 132- 141. Ueber eine neue Art von Strahlen.) P. Rona see L. Michaelis. 1511a. P. Rona, L. MichaeUs. Biochem. Zeit. 21, 114-122, (1909). Ueber den Zustand des Calciums in der Milch. T = 25°- 1511b. P. Rona, L. MichaeUs. Biochem. Zeit. 28, 193-199, (1910). Beitrage zur aUgemeinen Eiweisschemie. II. Mitteilung. Ueber die Fallung der Globuline im isoelektrischen Punkt. Roncati see Nicolosi-Roncati. 1512. M. Ronus. Dis. Basel. (1901). Meas. H. Labhardt. Ueber Cineolsaiu-e. [Same as 1546.] T=20°. M. Ronus see H. Rupe. 1513. (E. B. Rosa. Phil. Mag. (5), 31, 188-207, (1891). Specific inductive capacity of electrolytes.) [Temperature coefficients. ] Meas. N. Rosanofi; see 744. Roschdestvensky see Roidestvenskij. Meas. F. Rose; see 990. F. Rose see F. Kohlrausch. 1614. (A. Rosenheim. Zeit. Anorg. Chem. 11, 175-222, (1896). Ueber die Einwirkim.g anorganischer Metallsauren auf organische Sauren.) 1515. A. Rosenheim. Zeit. Anorg. Chem. 11, 225-248, (1896). Meas. F. Hamburger. Ueber die Einwirkung anorganischer Metallsauren auf organische Sauren. [See 1516 for more accurate measurements. ] T = 18°. 1516. A. Rosenheim. Zeit. Anorg. Chem. 21, 1-18, (1899), Meas. I. Koppel. Ueber die Einwirkung anorganischer Metallsauren auf organische Sauren. T=25°. 1517. A. Rosenheim. Zeit. Anorg. Chem. 54, 97-103, (1907). Untersuchungen tiber die Halogenverbindungen des Molybdans und Wolframs. T = 25°. Meas. A. Rosenheim; see 692, 1023. 1518. A. Rosenheim, A. Bertheim. Zeit. Anorg. Chem. 34, 427-447, (1903). Die Hydrate der Molybdansaure und einige ihrer Verbindungen. T = 25°. 1519. A. Rosenheim, H. Grunbaum. Zeit. Anorg. Chem. 61, 187-201, (1909). Ueber tetragene Doppelsalze des Antimonfluorids. T = 0°. aq. is " purest conductivity aq." 1520. A. Rosenheim, J. Heftzmann. Ber. Deutsch. Chem. Ges. 40, 810- 814, (1907). Zirkoniumtetrachlorid und koUoidales Zirkoniumhydroxyd. T=0°and25°. R. O. 502 AUTHOR LIST 1621. A. Rosenheim, H. Itzig. Ber. Deutsch. Cham. Ges. 32, 3424-3440, (1899). Ueber einige complexe Salze der Weinsaure und Aepfelsaure und ihr speci- fisches Drehungsvermogen. [Same as 867.] T=25°. 1622. A. Rosenheim, W. Levy. Zeit. Anorg. Chem. 43, 34r-47, (1905). Ueber Platinphosphorhalogenverbindungen und ihre Derivate. [Part is same as 1076, but has no measurement at 0°.] T = 25°. 1623. A. Rosenheim, O. Liebknecht. Ber. Deutsch. Chem. Ges. 31, 405- 414, (1898). Ueber alkylschwefligsaure Salze. T = 0°and25° 1524. A. Rosenheim, W. Loewenstamm. Zeit. Anorg. Chem. 34, 62-81, (1903). Ueber die Thiocarbamidverbindungen einwertiger Metallsalze. [Same as 1117 for 25°.] T = 25°and0°. 1625. (A. Rosenheim, W. Loewenstamm. Zeit. Anorg. Chem. 37, 394-406, (1903). Ueber Platinphosphorhalogenverbindungen imd ihre Derivate.) [Inorganic] 1526. A. Rosenheim, V. J. Meyer. Zeit. Anorg. Chem. 49, 13-27, (1906). Ueber die Thioltarbamidverbindungen zweiwertiger Metallsalze. T = 25°. 1527. A. Rosenheim, V. J. Meyer. Zeit. Anorg. Chem. 49, 28-33, (1906). Notiz iiber die Absorptionsspektra von Losungen isomerer komplexer Ko- baltsalze. T = 25°. 1628. A. Rosenheim, P. Miiller. Zeit. Anorg. Chem. 39, 175-186, (1904). Ueber Ferriacetoverbindungen. T = 25°. 1529. A. Rosenheim, W. Stadler. Ber. Deutsch. Chem. Ges. 38, 2687-2690, (1905). Die Thioapfelsaure und ihre Salze. T = 25°. 1530. A. Rosenheim, W. Stadler. Zeit. Anorg. Chem. 49, 1-12, (1906). Ueber Verbindungen des Thiokarbamids und Xanthogenamids mit Salzen des einwertigen Kupfers. T = 25°. 1530a. A. Rosenheun, M. Weinheber. Zeit. Anorg. Chem. 69, 261-265, (1910). Ueber Tellurssaureoxalate. T=25° 1631. W. H. Ross. Proc. Trans. Nova Scot. 11, 95-114, (1902-1906). Contribution to the study of hydroxylamine and its salts. T = 18°. Hg. U. xisaq. isabout I.IXIO-"; sub. 1632. G. Rossi. Arch. Fisiol. 1, 500-504, (1904). La viscosity e la resistenza elettrica del siero di sangue a temperature diverse e prossime a quella dell'organismo. T = 30°to60°- TJ. Rossi see G. Carrara. J. V. Roszkowski see S. v. Niementowski. A. W. Roth see H. Henkel. AUTHOR LIST 503 1533. W. A. Roth. Ber. Deutsch. Chem. Ges. 33, 2032-2035, (1900). AflSnitatsconstanten einiger Sauren mit Kohlenstoffsiebenring. T = 25°- R. O. K25 aq. = 1.3-1.5XlO-«; not sub. Also gives k with aq. sub. 1534. W. A. Roth. Zeit. Phys. Chem. 42, 209-224, (1902-1903). Elektrisches Leitvermogen von Kaliumchlorid in Wasser-Aethylalkoholgem- ischen. T = 18°. R. O. Meas. W. A. Roth; see 1027, 1239, 1542. 1535. V. Rothmund. Monatsh. 26, 1545-1558, (1905). Ueber die Einwirkung des Acetous auf Alkalisulfite. T = 25°. R. O. Meas. V. Rothmund; see 843, 1074, 1974, 1975, 1976, 1977, 1978, 1979. 1536. V. Rothmund, K. Drucker. Zeit. Phys. Chem. 46, 827-852, (1903). Ueber die elektrolytische Dissociation der Pikrinsaure. T=25°. R. O. X26aq. = 1.5X10-«; not sub. C. A. Rouiller see H. C. Jones. Meas. C. Roy; see 1464a. M. S. Roidestvenskij see A. G. DoroSevskij. W. Ruckstuhl see R. Lorenz. Meas. E. Rudia; see 571. 1537. M. Rudolphi. Zeit. Phys. Chem. 17, 277-300, (1895). Ueber Losungs- und Dissociationswarmen. T = 25°to60°. S. U. xaq. sub. 1538. (M. Rudolphi. Zeit. Phys. Chem. 17, 385-426, (1895). Ueber die Giiltigkeit der Ostwaldschen Formel zur Bereohnung der Affinitats- konstanten.) [Quoted.] 1539. G. Rudorf. Zeit. Phys. Chem. 43, 257-304, (1903). ZuT Kenntnis der Leitfahigkeiten und irinern Reibungen von Losungen. [jBame as 1640.] T=25°=t0.05°. X aq. about 4X10-'; not sub. 1540. G. Rudorf. Dis. Breslau. (1903). Zur Kenntnis der Leitfahigkeiten, etc. [Same as 1539. ] A. Rucker see A. Naumann. 1541. (H. Riiping. Dis. Erlangen. (1897). Abstracted in Beibl. Ann. Physik. 22, 412, (1898). I. Beitrage zur Kenntnis der Ketomenthylsaure und Menthoximsaure. II. Leitfahigkeit wasserig-aLkohoUscher Salzl6sung6n.) [Inorganic] 1542. O. Ruff. Ber. Deutsch. Chem. Ges. 32, 550-560, (1899). Meas. W. [A.] Roth. d- und r-Ajabinose. T=25°- O. E. Ruhoflf see L. Kahlenberg. 1543. H. Rupe. Ann. Chemie, 256, 1-28, (1890). Meas. W. Ostwald. Ueber die Reductionsproducte der Dichlormuconsaure. [Baeyer's name is not in the title of this article. ] 1544. H. Rupe. Ber. Deutsch. Chem. Ges. 33, 1129-1140, (1900). Meas. Labhardt. Ueber Cineolsaure. T = 18°. H. Rupe see O. Manasse. 1545. H. Rupe, W. Lotz. Ber. Deutsch. Chem. Ges. 36, 2796-2802, (1903). Ueber einige Condensationen mit Citronellal. [Qualitative. Corrected in Ber. Deutsch. Chem. Ges. 40, 2813-2817, (1907).] 504 AUTHOR LIST 1546. H. Rupe, M. Ronus. Ber. Deutsch. Chem. Ges. 34, 2191-2206, (1901). Meas. H. Labhardi. Ueber Cineolsaure. [Same as 1612.] T = 20°. 1B47. H. Rupe, M. Ronus, W. Lotz. Ber. Deutsch. Chem. Ges. 35, 4265- 4272, (1902). Meas. A. Pfister. Ueber die Darstellung von ungesattigten aliphatischen Sauren mit einer Doppelbindung in der a,;8-Stellung. 1548. This reference has been omitted intentionally. 1549. E. Ruppin. Zeit. Phys. Chem. 14, 467-485, (1894). Volimianderungen bei der Neutralisation starker Sauren und Basen. P. V. Ru§nov see R. Wegscheider. 1550. F. Russ. Zeit. Anorg. Chem. 31, 42-91, (1902). Ueber Nioboxalsaure. K. Russwurm see H. Stobbe. S. 1561. (B. Sabat. Bui. Acad. Cracov. (1906), 62-79. Ueber den Einfluss der Radiumstrahlen auf das Leitvermogen der Elektrolyte.) [Inorganic. ] 1652. (L. Sabbatani, G. Buglia. Arch. Fisiol. 3, 154^163, (1906). Velocity, di coagulazione al calore di liquidi albuminosi.) 1552a. A. Sachanov. Jour. Russ. Phys.-chem. Soc. 42, 683-690, (1910). The electrical conductivity of solutions in aniline, methylamline and dimethyl- aniline. T = 25°. R. 0. 1553. O. Sackur. Ber. Deutsch. Chem. Ges. 35, 1242-1252, (1902). Ueber die basischen Eigenschaften des vierwerthigen Sauerstoffs. T = 15°and22°. R. O. 1554. O. Sackur. Zeit. Phys. Chem. 38, 129-162, (1901). Ueber den Einfluss gleichioniger Zusatze auf die elektromotorische Kraft von Fliissigkeitsketten. Ein Beitrag zur Kenntnis des Verhaltens starker Elek- trolyte. T = 18°and25°. 1565. O. Sackur. Zeit. Phys. Chem. 41, 672-680, (1902). Das elektrische Leitvermogen und die innere Reibung von Losungen des Caseins. [An abridgement of 1054. No measurement of isocasein is given here. ] T = 25°. R. O. xaq.=2.6XlO-«; sub. O. Sackur see E. Laqueur. P. J. Sageman see J. Holmes. 1566. S^d-Effendi. Compt. Rend. 68, 1565-1567, (1869). Mesure de la conductibilit6 flectrique des liquides consid^r^s jusqu'^ present comme isolants. 1567. J. Sakurai. Jour. Chem. Soc. 69, 1654-1662, (1896). Molecular conductivity of amidosulphonic acid. T = 25.00°±0.05°. X aq. = 1.9XlO-«; not sub. for acid, sub. for salt. 1558. R. Salcher. Dis. Heidelberg. (1899). Studien (iber die Aminolyse. [Same as 664.] T=25°. R. M. Salcher see H. Goldschmidt. 1669. (W. Salessky. Zeit. Elektrochem. 10, 204-208, (1904). Ueber Indikatoren der Acidimetrie und Alkalimetrie.) AUTHOR LIST 505 1560. (E. Salm. Zeit. Elektrochem. 10, 341-346, (1904). Die Bestimmung des H-Gehaltes einer Losung mit Hilfe von Indikatoren.) 1561; E. Salm. Zeit. Elektrochem. 12, 99-101, (1906). Kolorimetrische Affinitatsmessungen. [Given in 1662.] 1562. E. Salm. Zeit. Phys. Chem. 57, 471-501, (1906). Studie tiber Indikatoren. I. Teil. Die Verwendung der Indikatoren zu Affinitatsmessungen. [Same as 1661, but contains also camphoronic acid.) ; T = 18°to 19°. 1663. E. Salm. Zeit. Phys. Chem. 63, 83-108, (1908). Messungen der Affinitatsgrossen organischer Sauren mit Hilfe von Indikatoren. T = 18°. Meas. E. Salm; see 274. 1564. (E. Salm, H. Friedenthal. Zeit. Elektrochem. 13, 125-130, (1907). Zur Kenntnis der Acidimetrischen und Alkalimetrischen Indikatoren.) 1566. (R. Salvadori. Gaz. Chim. Ital. 26, I, 237-254, (1896). Dissociazione elettrolica in relazione colle variazioni della temperatura. I. Studi crioscopi ed ebullioscopiei sopra le soluzioni acquose e in alcool metilico di alcuni cloruri.) [Inorganic] 1666. (R. Salvadori. Gaz. Chim. Ital. 30, II, 544-548, (1900). Riconoscimento deUa dissociazione idroUtica per mezzo deUa conducibilit^ elettrica.) [Inorganic] 1667. A. H. Salway. Dis. Leipzig. (1906). Ueber farbige Salae aus farblosen Nitrokorpem. [Part is given in 746; part in 1092.] T = 0°and25°. Meas. A. H. Salway; see 746, 1092. 1668. M. Samec. Monatsh. 26, 391-411, (1905). Kondensation von Formisobutyraldol mit Dimethylanilin. T = 25°and0°. G. V. Sammet see A. A. Noyes. 1569. J. L. Sammis. Jour. Phys. Chem. 10, 593-625, (1906). On the relation of chemical activity to electrolytic conductivity. T = 25°, except for a few measurements at 7° and 7.5°. 1570. A. Samojloff. Biochem. Zeit. 11, 210-225, (1908). Meas. with A. Pheophilaktowa. Ueber den Einfluss der Gerinnung des Blutes auf die Leitfahigkeit desselben. T=25° and 38.9° 1671. J. Sand. Ber. Deutsch. Chem. Ges. 38, 3642-3654, (1905). Salze der Krystallviolettgruppe. J. Sand see J. Maas. 1572. J. Sand, 0.«Burger. Ber. Deutsch. Chem. Ges. 39, 1761-1770, (1906). Reduction von Molybdansaure in rhodanwasserstoffsaurer Losung. 1573. J. Sand, O. Burger. Ber. Deutsch. Chem. Ges. 39, 1771-1779, (1906). Oxydation von Chromosalzen. T=24°. R. O. C. Sandonnini see G. Bruni. 1573a. C. Sandonnini. Zeit. Elektrochem. 16, 227-229, (1910). Vergleichende Untersuchungen iiber Salzbildung vom physikochemischen Standpunkte. T=25°. 506 AUTHOR LIST 1574. H. Sandqvist. Ann. Chemie. 369, 104-117, (1909). TJeber Phenanthren-3-sulfosaure und einige ihrer Derivate. T = 18.00° R. O. Xi6aq. = 1.8X10-6. Saposchnikoff see Sapo2nikov. Saposchnikov see Sapoinikov. A. Sapovalenko see P. Pissarjewsky. 1575. W. Sapoinikov. Jour. Russ. Phys.-ohem. Soc. 25, 626-631, (1893). On the electrical conductivity of formic acid. T =8.3° to 18.8°. Meas. W. Sapoinikov; see 1011, 1013. L. W. Sargent see G. N. Lewis. 1576. "W. Sarow. Dis. Berlin. (1905). Ueber die Konstitution der schwefligen Saure und ihrer Derivate. Versuche uber das Sulfamid. T = 25°. xaq.=4.9XlO-^ B. Savarfe see M. Padoa. N. Scalinci see F. Bottazzi. E. Scandola see G. Oddo. 1577. H. Schafer, R. Abegg. Zeit. Anorg. Chem. 45, 293-323, (1905). Untersuchungen tiber die Elektroaflfinitat der Anionen. 1. Das Oxalat-Ion. T = 15.5°, 18.5° and 25°. K. Schaefer see H. Ley. 1578. C. Schall. Zeit. Elektrochem. 14, 397-405, (1908). Ueber organische und geschmolzene Salze. T = 17°toll3°. R. O. 1579. C. Schall. Zeit. Phys. Chem. 14, 701-708, (1894). Ueber die Abnahme der molekularen Leitfahigkeit einiger starken, organischen Sauren bei Ersatz des Losungswassers durch Alkohole. [See 1680.] T = 25°. 1580. C. SchaU. Zeit. Phys. Chem. 19, 699-700, (1896). Nachtrag zur Letzten Abhandlung. [Supplementary to 1579. ] 1581. R. Schaller. Zeit. Phys. Chem. 25, 497-524, (1898). Messungen der elektrischen Leitfahigkeit an verdiinnten Losungen bei Tem- peraturen bis 100°. [The values of k are only approximate values.] T = 25° to 99°. X aq. not over 1.6 XIO"''; not sub. 1581a. C. Schaper. Zeit. Phys. Chem. 72, 308-322, (1910). Ueber das Oxydationspotential der Oxalate des Eisens und des Oxalations. T = 17°to30°. 1582. B. Schapire. ^eit. Phys. Chem. 49, 613-541, (1904). Beitrag zur Kenntnis des elektrischen Leitvermogens von Natrium- und Kaliumchlorid in Wasser-Aethylalkoholgemischen. [Same as 1583.] T = 18°. R. O. xigaq.^ 1.25X10-=. 1583. B. Schapire. Dis. BerUn. (1904). Beitrag zur Kenntnis des elektrischen Leitvermogens, etc. [Same as 1582. ] M. Scheldt see G. Magnanini. 1684. R. Schenck, [A. Kreichgauer]. Sitzber. Ges. Naturw. Marburg. (1899), 43^7. Ueber den Einfluss von Sauren auf das optische Drehungsvermogen von Asparaginlosungen. 1585. T. Scheutz. Dis. Zurich. (1901). Ueber alkylierte Amidobenzolsulfosauren und Metamidophenole. [Same as 646.] T. Scheutz see R. Gnehm. Meas. G. Schick; see 760. AUTHOR LIST 507 1586. (U. Schiff. Gaz. Chim. Ital. 28, I, 4&-64, (1898). Intomo a composti poliaspartici.) [No conductivity.] K. Schilling see J. Eoenigsberger. 1587. R. V. Schilling. Dis. Halle. (1899). Die elektrolytische Leitfahigkeit der Hydroresorcine und 5-Ketonsauren. [Same as 1688, with some additional measurements of succinic and 7-acetyI- butyric acids. ] 1588. R. V. Schilling, D. Vorlander. Ann. Chemie. 308, 184-202, (1899). Die elektrolytische Leitfahigkeit der Hydroresorcine und 3-Ketonsauren. [Given in 1587.] T = 25°. R. O. xaq.= 2. 1-3.4X10-8; not sub. 1589. A. Schlamp. Zeit. Phys. Chem. 14, 272-285, (1894). Zur Dissociationstheorie der Losungen. T = 15.6°. 1590. H. I. Schlesinger. Am. Chem. Jour. 39, 719-771, (1908). Studies in catalysis. VI. The catalysis of imidoesters. T = 0°. R. O. J. Schliemann see E. Lellmann. H. Schlundt see L. Kahlenberg. 1590a. E. W. Schmidt. Zeit. Phys. Chem. 75, 305-336, (1910-1911). Ueber den Einfluss des Druckes auf das elektrolytische Leitvermogen von Losungen in verschiedenen Losungsmitteln. T = 0°to60°. 1691. (M. R. Schmidt. Am. Chem. Jour. 40, 305-313, (1908). The basicity of acids as determined by their conductivities.) [Inorganic] 1592. M. R. Schmidt, H. C. Jones. Am. Chem. Jour. 42, 37-95, (1909). Conductivity and viscosity in mixed solvents containing glycerol. T=25°and35°. S. U. x aq. = 1.2-1.5X10-«. 1593. O. Schmidt. Dis. Bonn. (1898). Ueber die Konstitution der Einwirkungsprodukte von Diazoverbindungen auf primare Nitrokorper und uber stereoisomere Hydrazone. [Same as 82.] T = 0° and 25°. Xjs aq.=3XlO-S; not sub. Meas. O. Schmidt; see 78, 82. O. Schmidt see E. Bamberger. R. Schmidt see F. Stohmann. 1594. V. Scholz. Dis. Heidelberg. (1902). Dynamische Untersuchungen tiber die Verseifung von Saureestem und die Affinitatsconstanten derselben. [Part is given in 666. ] V. Scholz see H. Goldschmidt. O. Schreiner see L. Kahlenberg. Meas. E. Schroder; see 875. H. Schroder see J. W. Briihl. 1596. (I. F. Schroder. Jour. Russ. Phys.-chem. Soc. 30, 333-334, (1898).) [No title. This is in a report of a meeting. The subject is the conductivity of ammonium nitrate in ammonia. ] 1696. J. Schroeder. Ann. Physik. (4), 29, 125-152, (1909). Das Verhalten des Aethylathers beim Durchgange eines elektrischen Stromes. T = l°, 18°, and 30°. 1597. S. B. Schryver. Jour. Chem. Soc. 63, 1327-1345, (1893). Meas. C. S. Palmer. Researches on the oxidation products of turpentine oil. [k is given in 1598, but no table of fi and k. ] T=25°. 508 AUTHOR LIST 1598. S. B. Schryyer. Proc. Chem. Soc. 9, 187, (1893). Studies of the oxidation products of turpentine. [Same as 1597 for k. ] 1599. S. B. Schryver, R. Lessing. Jour. Soc. Chem. Ind. 28, 60-67, (1909). A physico-chemical method for comparing the antiseptic value of disinfectants. T=37°. 1600. A. Schubert. Dis. Bonn. (1908). Loslichkeitsbestimmungen an schwerlosUchen Salzen seltener Erdmetalle. [Most is given in 1496.] T = 18°to26°. R. O. X25aq. =2X10-8; sub. A. Schubert see E. Rimbach. Meas. A. Schubert; see 1749. K. Schiibel see H. Pauly. 1601. M. Schumann. Ber. Deutsch. Chem. Ges. 33, 527-533, (1900). Zur Kenntniss des Diazotierungsprocesses und der salpetrigen Saure. T=20°. 1602. M. Schumann. Dis. Wiirzburg. (1899). Zur Kenntnis des Diazotierungs-Processes xmd der Verbindungen R.N2OH. • [Given in 774.] T = 0°. . Meas. M. Schumann; see 735, 779. M. Schumann see A. Hantzsch. Meas. A. Schugowitsch; see 1916. O. W. Schultze see A. Hantzsch. A. Schimiacher see A. Thiel. 1603. J. Schwab. Dis. Basel. (1904). I. Ueber die stereoisomeren /3-Methylglutaconsauren. II. Ueber o-Diamino- guajacol und sein Oxydationsprodukt. [Same as 672.] T = 25°. R. O. ?«aq.=3Xl0-^ J. Schwab see F. Fichter. 1604. E. V. Schweidler. Ann. Physik. (4), 4, 307-315, (1901). Ueber das Verhalten fliissiger Dielektrika beim Durchgange eines elektrischen Stromes. [Same as 1607.] 1605. E. V. Schweidler. Ann. Physik. (4), 5, 483-486, (1901). Ueber das Verhalten fltissiger Dielektrika beim Dtn:chgange eines elektrischen Stromes. R. O. 1606. (E. V. Schweidler. Ann. Physik. (4), 24, 711-770, (1907). Studien iiber die Anomalien im Verhalten der Dielektrika.) [Same as 1608.] 1607. E. V. Schweidler. Sitzber. Akad. Wien. 109, 2a, 964-973, (1900). Ueber das Verhalten, etc. [Same as 1604. ] 1608. (E. V. Schweidler. Sitzber. Akad. Wien. 116, 2a, 1019-1080, (1907). Studien iiber die Anomalien, etc.) [Same as 1606.] E. V. Schweidler see C. Bohm-Wendt. E. Scipiades see O. Farkas. M. Scott see S. Deakin. 1609. (H. Scudder. Jour. Phys. Chem. 7, 269-299, (1903). The reliability of the dissociation constant as a means of determining the iden- tity and purity of organic compounds.) [Quoted. ] F. Sebaldt see A. Hantzsch. AUTHOR LIST 509 1609a. (S. W. Sgrkov. Zeit. Phys. Chem. 73, 557-577, (1910). Die elektrische Leitfahigkeit von Losimgen und der Zustand des gelosten Stoffes.) [Inorganic. ] S. Seydel see H. Stobbe. Meas. G. H. Shadinger; see 15. G. H. Shadinger see S. F. Acree. 1610. (W. N. Shaw. Proc. Cambridge Phil. See. 7, 21-31, (1889-1892). On the relation between viscosity and conductivity of electrolytes.) [Quoted. ] 1610a. J. Shields. Zeit. Phys. Chem. 12, 167-187, (1893). Ueber Hydrolyse in wasserigen Salzlosungen. [Saponification of esters 1 T = 24.1° and 24.2°. 1611. F. L. Shinn. Jour. Phys. Chem. 11, 201-224, (1907). On the optical rotatory power of salts in dilute solutions. [T is probably 25°.] x aq. is about 2X10-^- sub. 1612. F. L. Shinn. Jour. Phys. Chem. 11, 537-541, (1907). On the electrical conductivity of solutions in ethyl amine. T = 0°. R. O. 1613. I. Shukoft. Ber. Deutsch. Chem. Ges. 38, 2691-2693, (1905). Beitrag zur Kenntniss der metallorganischen Verbindungen. T = 25°. N. V. Sidgwick see A. C. D. Rivett. 1614. N. V. Sidgwick, T. S. Moore. Jour. Chem. Soc. 95, 889-898, (1909). The rate of reaction of the triphenylmethane dyes with acid and alkali. Part II. Brilliant-green and malachite-green. [Same as 1615 for k. Measurements given in full here. ] 1615. N. V. Sidgwick, T. S. Moore. Proc. Chem. Soc. 25, 123-124, (1909). The rate of reaction, etc. [Same as 1614 for k.] 1616. N. V. Sidgwick, T. S. Moore. Zeit. Phys. Chem. 58, 385-408, (1907). Zur Dynamik der Tautomerie. I. Brillantgrun. 1617. N. V. Sidgwick, A. C. D. Rivett. Jour. Chem. Soc. 95, 899-908, (1909). The rate of reaction of the triphenylmethane dyes with acid and alkali. Part III. Diaminotriphenylcarbinol. [Same as 1618 for k. Measurements given in full here.] 1618. N. V. Sidgwick, A. C. D. Rivett. Proc. Chem. Soc. 25, 124-125, (1909). The rate of reaction, etc. [Same as 1617 for k. ] 1618a. N. V. Sidgwick, H. T. Tizard. Jour. Chem. Soc. 97, 957-972, (1910). The colour and ionisation of cupric salts. [Qualitative statement in 1618b. ] T = 18°. R. O. 7<:i8aq. = l-1.5X10-s. 1618b. N. V. Sidgmck, H. T. Tizard. Proc. Chem. Soc. 26, 67, (1910). The colour and ionisation of cupric salts. [Qualitative. Given in 1618a with full data.] 1618c. M. Siegfried. Ergebn. Physiol. 9, 334r-350, (1910). Die Carbamino- und Hydroxylkohlensaurereaktion. 1619. M. Siegfried. Zeit. Physiol. Chem. 46, 401^14, (1905). Ueber die Bindung von Kohlensaure durch amphotere Amidokorper. T=25°. X26aq.= 2.5X10-5; sub. 1620. H. F. SiU. Zeit. Phys. Chem. 51, 577-602, (1905). Ueber das Gleichgewicht zwischen einer Stickstoffbase und organischen Satiren in verschiedenen Losungsmitteln. [Same as 1621.] 1621. H. F. Sill. Dis. Leipzig. (1905). Ueber das Gleichgewicht zwischen einer Stickstoffbase imd organischen Sauren in verschiedenen Losungsmitteln. [Same as 1620.] Meas. E. Siller; see 1754, 1760. 510 AUTHOR LIST 1622. I. Simon. Arch. Fisiol. 4, 594-604, (1907). Ricerche sulla coagulazione delle albumine. I. Variazioni fisico-chemiche del siero per aggiunta di alcool. T = 25°. 1623. I. Simon. Arch. Fisiol. 5, 394-401, (1908). Ricerche sulla coagulazione delle albumine. II. Variazioni fisico-chimiche del siero per aggiunta di acetone. T = 25°. 1624. I. Simon. Arch. Fisiol. 5, 402-406, (1908). Ricerche sulla coagulazione delle albumine. III. Variazioni fisico-chimiche del siero per aggiunta di alcool metilico. T = 25° 1625. I. Simon. Arch. Fisiol. 5, 470-476, (1908). Ricerche sulla coagulazione delle albumine. IV. Variazioni fisico-chimiche del siero per aggiunta di alcool propilico. T = 25°. 1626. I. Simon. Arch. Fisiol. 5, 477-478, (1908). Ricerche sulla coagulazione delle albumine. V. Variazioni fisico-chimiche del siero per aggiunta di alcool allilico. T = 25°. 1626a. I. Simon. Arch. Fisiol. 8, 361-382, (1910). Ricerche sulla coagulazione! delle albumine. VII. Variazioni fisico-chimiche del siero per aggiunta di sali di metalli pesanti. T = 25°. J. L. Simonsen see W. H. Parkin, Jr. W. Sinclair see W. H. Perkin, Jr. 1627. H. A. Sirks. Rec. Trav. Chim. 27, 207-250, (1908). Etudes sur les six acides dinitrobenzoiques. [Same as 1628 for k. Tables of A also given here.] T = 25° to 40°. R. O. xJB about 1 XIO-^. 1628. H. A. Sirks. Verslag Akad. Amsterdam. 15, 264-270, (1906-1907). Verslag Akad. Amsterdam, English translation, 9, 280-286, (1906- 1907.) De zes isomere dinitrobenzoezuren. [Same as 1627 for k. It is indexed, as, HoUeman, Sirks.] Si§kovskij see Szyszkowski. P. Sisley see P. Barbier. J. Sjoqvist. Ergebn. Physiol. 9, 241-333, (1910). See H. Euler. 1629. S. Skinner. Jour. Chem. Soc. 73, 483-490, (1898). Affinity constants of dihydroxymaleic, dihydroxyfumaric, dihydroxytartaric, and tartronic acids. T = 25°. Hg. U. xaq. notsub. 1630. Z. H. Skraup. Monatsh. 12, 107-145, (1891). Ueber die Umwandlung der Maleinsaure in Fumarsaure. [Same as 1632.] T=22°, 58°and96°. S. U. 1631. Z. H. Skraup. Monatsh. 15, 775-786, (1894). Ueber die Affinitat einiger Basen in alkoholischer Losimg. T = 25°. 1632. Z. H. Skraup. Sitzber. Akad. Wien. 100, 2b, 124-162, (1891). Ueber die Umwandlung der Maleinsaure in Fumarsaure. [Same as 1630. ] 1633. G. V. d. Sleen. Rec. Trav. Chim. 21, 209-251, (1902). L'acide vinylglycolique (butSnolique 1, 3) et ses transformations. [Same as 1634. k, but no A, is given in 300.] R. O. X aq. sub. AUTHOR LIST 511 1634. G. V. d. Sleen. Dis. Basel. (1901). Ueber die a-Oxybutensaure (Vinyl-glycolsaure) und ihre Umlaeerungen. [Same as 1633. See 300.] Meas. G. v. d. Sleen; see 300. 1634a. (W. H. Sloan. Jour. Am. Chem. Soc. 32, 946-949, (1910). On the conductivity of some concentrated aqueous solutions at zero.) [In- organic. ] C. H. Sluiter see A. Hantzsch. D. D. Van Slyke see L. L. Van Slyke. 1636. L. L. Van Slyke, D. D. Van Slyke. Am. Chem. Jour. 38, 383-456, (1907). The action of dilute acids upon casein when no soluble compounds are formed. T=25°±0.03°. xaq. =1-1.8X10-"; sub. 1636. L. L. Van Slyke, D. D. Van Slyke. Am. Chem. Jour. 38, 619-626. (1907). The hydrolysis of the sodium salts of casein. T=25°±0.03°. xaq. = l-1.8X10-«; sub. 1637. (W. A. Smith. Zeit. Phys. Chem. 25, 144-177, (1898). Ueber die stufenweise Dissociation zweibasischer organischer Sauren.) [Same as part of 1639.] 1638. W. A. Smith. Zeit. Phys. Chem. 25, 193-264, (1898). Ueber die stufenweise Dissociation zweibasischer organischer Sauren, II. [Same as part of 1639. ] T = 25°. J^Tcaq. sub. 1639. "W. A. Smith. Dis. Leipzig. (1898). Ueber die stufenweise Dissociation zweibasischer organischer Sauren. [Same as 1637 and 1638 together. ] Meas. W. A. Smith; see 817, 1661, 1662. 1639a. This reference has been omitted intentionally. 1639b. S. P. L. Sorensen. Biochem. Zeit. 21, 131-304, (1909). Meas. S. Palitzsch and R. Koefoed. Enzymstudien. II. Mitteilung. Ueber die Messung und die Bedeutung der Wasserstoffionenkonzentration bei enz3rmatischen Prozessen. T = 18° kw at 18° =0.72X10-". W. Sokoloff see L. TschugaeS. M. Solimene see G. Abati. 1640. F. Sonnebom. Dis. Basel. (1902). Zur Kenntnis der Vinylessigsaure. [Only vinylacetic acid and its sodium salt are given in 573. ] F. Sonnebom see F. Fichter. Meas. R. B. Sosman; see 1341. R. B. Sosman see A. A. IToyes, Y. Eato. J. F. Spencer see R. Abegg. 1641. A. W. Speranskij. Jour. Russ. Phys.-chem. Soc. 28, 329-334, (1896). On chromiimi thiocyanates. T=25°. 1642. (A. W. Speranskij, E. G. Goldberg. Jour. Russ. Phys.-chem. Soc. 32, 797-804, (1900). Electrolysis of solutions of metallic salts in organic solvents.) Speransky see Speranskij. Speyer see Cahn-Speyer. K. Spiro see L. J. Henderson. 512 AUTHOR LIST 1643. W. Spitzer. Arch. Gesammt. Physiol. 50, 551-573, (1891). Ueber die Benutzung gewisser Farbstoffe zur Bestimmung Affinitaten. C. H. G. Sprankling see W. A. Bone. " " " " see W. A. Bone, J. J. Sudborough. " " " " see H. Henstock. 1644. W. Spruck. Dis. Zurich. (1898). Ueber Additionsprodukte v. Aethylendiamin an Salze zweiwertiger Metalle. [Same as 1946. ] Meas. W. Spruck; see 1946. W. Stadler see A. Rosenheim. IMeas. H. Stahl; see 448. B. D. Steele see S. Deakin, M. Scott. " " " see R. B. Denison. " " " see D. Mcintosh. 1646. B. D. Steele, D. Mcintosh. Proc. Chem. See. 19, 220-221, (1903). Conductivity of substances dissolved in certain liquified gases. Preliminary notice. [Qualitative. ] 1646. B. D. Steele, D. Mcintosh', E. H. Archibald. Zeit. Phys. Chem. 55, 129-199, (1906). Die Halogenwasserstoffsauren als leitende Losungsmittel. [Same as 1647. ] T=-100°, -81° and -50°. 1647. B. D. Steele, D. Mcintosh, E. H. Archibald. Trans. R. Soc. London. A, 205, 99-167, (1906). The halogen hydrides as conducting solvents. Part I. The vapour pressures, densities, surface energies and viscosities of the pure solvents. Part II. The conductivity and molecular weights of dissolved substances. Part III. The transport numbers of certain dissolved substances. Part IV. The abnormal variations of molecular conductivity, etc. [Same as 1646.] 1648. L. Stem. Dis. Bonn. (1906). Ueber die Drehungsanderungen aktiver Oxysauren durch Zirkon- und Zinn- verbindungen. T = 25°. R. O. 1649. K. Steinitz. Dis. Berlin. (1906). Ein Beitrag zur Beeinflussung des Leitvermogens schwacher Elektroljrte in Wasser durch Zusatze von anderen nicht leitenden Substanzen. T = 25°±0.02°. R. O. X aq.=1.25X10-^ or less; not sub. 1650. (H. V. Steinwehr. Zeit. Elektrochem. 7, 685-686, (1900-1901). Ueber die Gultigkeit des Massenwirkungsgesetzes bei starken Elektrolyten.) H. V. Steinwehr see F. Kohlrausch. 1651. D. Stenquist. Zeit. Elektrochem. 12, 860-862, (1906). Bestimmung der elektrischen Leitfahigkeit des Jod-, Brom- und Chlorkaliums in Aethyl- und Methylalkohol. [Same as 1652. ] T = 0°. 1652. D. Stenquist. Aikiv Kemi. 2, No. 25, 1-8, (1905-1907). Bestamning af elektriska ledningsform&gan for jod-, brom- och klorkahum i etyl- och metylalkohol. [Same as 1661.] 1663. (C. Stephan. Ann. Physik. (3), 17, 673-701, (1882). Beitrage zu den Beziehungen zwischen Fluiditat imd galvanischem Leitungs- vermogen.) [Inorganic] J. Stephenson see Berkeley, E. G. J. Hartley. 1654. E. Stem. Zeit. Phys. Chem. 50, 513-559, (1905). Die chemische Kinetik der Benzoinsynthese (Cyanionenkatalyse). [Same as 1666.] T=0°, 25°and60°. R. O. AUTHOR LIST 513 1655. E. Stem. Dis. Heidelberg. (1904). Die chemische Kinetik der Benzoinsynthese (Cyanionenkatalyse). [Same as 1664. ] 1655a. G. N. Stewart. Jour. Physiol. 24, 211-238, (1899). The behaviour of the haemoglobin and electrolytes of the coloured corpuscles when blood is laked. T = 6°. R. O. 1655b. G. N. Stewart. Jour. Physiol. 24, 460-463, (1899). The effect on the molecular concentration and electrical conductivity of muscle extracts of removal of the proteids. T = 5°. R. O. 1655c. G. N. Stewart. Jour. Physiol. 26, 470-496, (1900-1901). The conditions that underlie the peculiarities m the behaviour of the coloured blood-corpuscles to certain substances. T = 5°. R. O. 1666. J. Stieglitz. Am. Chem. Jour. 39, 29-63, (1908). Studies in catalysis. I. The catalysis of esters and of imidoesters by acids. [See 439 and 1233 for measurements. ] 1657. J. StiegUtz. Am. Chem. Jour. 39, 166-183, (1908). Meas. by I. H. Derby and W. McCracken. Studies in catalysis. II. The catalysis of imidoesters. [k is same as in 439 and 1233 together.] 1658. (J. Stieglitz. Jour. Am. Chem. Soc. 30, 946-954, (1908). Note on the solubility product.) 1669. J. Stieglitz, I. H. Derby. Am. Chem. Jour. 31, 449^58, (1904). A study of hydrolysis by conductivity methods. T=25°±0.01°. ?iaq.= 2.0X10-8. 1660. J. StiegUtz, H. T. Upson. Am. Chem. Jour. 31, 458-502, (1904). Meas. H. T. Upson. The molecular rearrangement of aminophenyl alkyl carbonates. T = 0°. Hg. U. kw = 1.2X10-". [The values of k calculated with kw for 0°, are about 0.1 of those given in this article.] C. M. Stine see H. C. Jones. 1661. H. Stobbe. Ann. Chemie. 308, 114^165, (1899). Meas. Foote, and W. A. Smith. Condensation Acetophenons mit Bemsteinsaureester. 1662. H. Stobbe. Ann. Chemie. 321, 105-126, (1902). Meas. W. A. Smith. Condensation des Aethylmethylketons mit Bemsteinsaureester. 1663. H. Stobbe, R. Haertel. Ann. Chemie. 370, 99-129, (1909). Lichtabsorption, Basenstarke, Constitution und Salze der Ketone der Dibenz- alaceton- und Dibenzalcyklopentanonreihe. 1664. H. Stobbe, K. Russwurm. Ann. Chemie. 308, 156-174, (1899). Meas. Foote. Condensation des Desoxybenzoins mit Bemsteinsaureester. 1666. H. Stobbe, S. Seydel. Ann. Chemie. 370, 129-141, (1909). Lichtabsorption, Basenstarke, Constitution und Salze einiger ungesattigter cyklischer Ketone, Ketonsauren und Ketonsaureester. 1666. F. Stohmann, C. Kleber. Jour. Prakt. Chem. (2), 45,475-499,(1892). Calorimetrische Untersuchungen. Hydrirung geschlossener Ringe; die Con- stitution der Camphersaure vom thermo-chemischen Standpunkte. 1667. F. Stohmaim, C. Kleber, H. Langbein, P. Offenhauer. Jour. Prakt. Chem. (2), 49, 99-129, (1894). Calorimetrische Untersuchungen. Ueber den Warmewerth der aUphatischen Sauren. [Same as 1668.] 514 AUTHOR LIST 1668. F. Stohmann, C. Kleber, H. Langbein, P. Offenhauer. Ber. Verhand. Sachs. Ges. Wis. 45, 604-658, (1893). Ueber den Warmewerth der aliphatischen Sauren. [Same as 1667.] 1669. F. Stohmann, H. Langbein. Jour. Prakt. Chem. (2), 49, 483-501, (1894). Meas. [H.] Wislicenus. Calorimetrische Untersuchungen. Ueber die thermischen Vorgange bei der Bildung einiger Aminsauren und NitrUe. [Same as 1671. Qualitative. ] 1670. F. Stohmann, H. Langbein. Jour. Prakt. Chem. (2), 50, 388-400, (1894). mMeas. Paul. Calorimetrische Untersuchungen. Ueber den Warmewerth isomerer Sauren von der Zusammensetzung CrHeOs und CsHsOs. [Same as 1672, except that A of o-oxy-o-toluic acid is not given here. ] 1671. F. Stohmann, H. Langbein. Ber. Verhand. Sachs. Ges. Wis. 46, 49- 72,(1894). Meas. [H.] Wislicenus. Ueber die thermischen Vorgange, etc. [Same as 1669.] 1672. F. Stohmann, H. Langbein. Ber. Verhand. Sachs. Ges. Wis. 46, 226-251, (1894). jUMeas. Paul. Ueber den Warmewerth, etc. [Same as 1670 with addition of A of o-oxy-o- toluic acid.] 1673. F. Stohmann, R. Schmidt. Jour. Prakt. Chem. (2), 53, 345-369, (1896). Meas. H. Wislicenus, and Dittrich. Calorimetrische Untersuchungen. Ueber den Warmewerth der Hippursaure, ihrer Homologen und der Anisursaure. [Same as 1674. ] 1674. F. Stohmann, R. Schmidt. Ber. Verhand. Sachs. Ges. Wis. 47, 375- 399, (1895). Meas. H. Wislicenus, and Dittrich. Ueber den Warmewerth der Hippursaure, ihrer Homologen und der Anisur- saure. [Same as 1673.] 1676. (L. Storch. Zeit. Phys. Chem. 19, 13-19, (1896). Ueber das Verdiinnungsgesetz der Elektrolyte.) [Inorganic] Meas. W. Storer; see 494. 1676. F. Straus, O. Ecker. Ber. Deutsch. Chem. Ges. 39, 2977-3006, (1906). Ueber Dibenzalaceton und Triphenylmethan. T = 0°. 1676a. W. Strecker. Ber. Deutsch. Chem. Ges. 43, 1131-1144, (1910). Einwirkung von Organomagnesiumverbindungen auf Bortrichlorid, Chlor- schwefel, sowie auf das Chlorid und die Ester der schwefhgen Saure. T = 25° 1677. (F. Streintz. Ann. Physik. (4), 3, 1-19, (1900). Ueber die elektrische Leitfahigkeit von gepressten Pulvern.) [Inorganic. Same as 1679.] 1678. (F. Streintz. Ann. Physik. (4), 9, 854-885, (1902). Ueber die elektrische Leitfahigkeit von gepressten Pulvern.) [Same as 1680. Inorganic. ] 1679. (F. Streintz. Sitzber. Akad. Wien. 109, 2a, 221-241, (1900). Ueber die elektrische, etc.) [Same as 1677]. 1680. (F. Streintz. Sitzber. Akad. Wien. Ill, 2a, 345-378, (1902). Ueber die elektrische, etc.) [Same as 1678.] 1681. (N. Strindberg. Zeit. Phys. Chem. 14, 161-162, (1894). Ueber die Aenderung der Leitfahigkeit einer Losung durch Zusatz von kleinen Mengen eines Nichtleiters.) [Inorganic] 1682. D. Stromhohn. Ber. Deutsch. Chem. Ges. 32, 2892-2911, (1899). Ueber Diathylendisulfidthetin. B. C. Stuer see A. Hantzsch. J. J. Sudborough see W. A. Bone. AUTHOR LIST 515 1683. J. J. Sudborough, D. J. Roberts. Jour. Chem. Soc. 87, 1840-1854, (1905). Esterification constants of substituted acrylic acids. Part I. [Quoted from 1299.1 H. Siiss is same as J. H. Siiss. 1684. J. H. Siiss. Monatsh. 26, 1331-1342, (1905). Leitfahigkeitsmessungen an organischen Sauren. [Same as 1686.] R. O. 1685. J. H. Siiss. Sitzber. Akad. Wien. 114, 2b, 867-878, (1905). Leitfahigkeitsmessungen an organischen Sauren. [Same as 1684.] Meas. [J.] H. Suss; see 1906, 1934, 1935. 1686. O. Sulc. Zeit. Phys. Chem. 32, 625-629, (1900). Leitfahigkeit einiger natriumsubstituierter Nitroparaflfine. T = 25°. X aq. about 2X10"^; not sub. 1687. E. C. Sullivan. Zeit. Phys. Chem. 28, 523-545, (1899). Studien tiber einige Jodverbingungen. T = 25°. £. Sunde see H. Goldschmidt. 1687a. (A. F. Sundell. Zeit. Phys. Chem. 70, 539-550, (1910). Elektrolysen betraktad ur energetisk synpunkt.) 1688. (W. Sutherland. Phil. Mag. (6), 3, 161-177, (1902). Ionization, ionic velocities, and atomic sizes.) [Quoted. ] 1689. (W. Sutherland. Phil. Mag. (6), 14, 1-35, (1907). Ionization in solutions and two new types of viscosity.) [Quoted. ] 1690. F. Swarts. Rec. Trav. Chim. 26, 244r-252, (1906). Sur I'acide difluorchlorac^tique. [Same as 1699.] T=25°. 1691. F. Swarts. Zeit. Phys. Chem. 16, 118-124, (1895). Einige Betrachtungen iiber elektrische Leitfahigkeitskurven. [Qualitative.] 1692. (F. Swarts. Bui. Acad. Belg. (3), 28, 130-131, (1894). Sur la conductibilit6 6Iectrique de I'acide dichloriluorac6tique.) [Published in full in 1700.] 1693. F. Swarts. Bui. Acad. Belg. (3), 31, 675-688, (1896). Sur I'acide fluorac^tique. S. U. xaq. = 1.5Xl0-^ 1694. F. Swarts. Bul. Acad. Belg. (3), 35, 849-868, (1898). Sur I'acide dibromfluorac^tique. T=25.1° and 25.2°. S. U. 1695. F. Swarts. Bul. Acad. Belg. (1902), 731-760. Sur I'alcool bifluor^. S. U. 1696. F. Swarts. Bul. Acad. Belg. (1903), 597-633. Sur I'acide difluorac^tique. T=25°. R. 0. 1697. F. Swarts. Bul. Acad. Belg. (1904), 762-801. Sur quelques amines k radical alooolique fluor6. [T probably 25°.] R. O. x aq. =2X10"^; sub. 1698. F. Swarts. Bul. Acad. Belg. (1904), 955-969. Sur quelques amines A radical alcoolique fluor^. [No data of T nor of unit, but see 1697.] 1699. F. Swarts. Bul. Acad. Belg. (1906), 42-51. Sur I'acide difluorchIorac6tique. [Same as 1690.] T = 25°. 516 AUTHOR LIST 1700. F. Swarts. M6m. Acad. Belg. 51, M^m. 3. (1894-1895). Sur la conductibilit6 ^lectrique de I'acide dichlorfluorac6tique. [Abstract in 1692 is qualitative.] T is about 25°. S. U. x aq. = 1.49-1.6XlO-^ 1701. F. Swarts. U6m. Acad. Belg. 54, M6m. 2, (1896). Sur I'acide fluorchlorbromae^tique. T = 25°- S. U. xaq. = 1.9X10-5. R. Swinne see P. Walden. 1702. E. C. Szanrasy. Jour. Chem. Soc. 77, 603-608, (1900). Electrolysis of the nitrogen hydrides and of hydroxylamine. 1703. B. Szyszkowski. Jour. Russ. Phys.-chem. Soc. 28, 664:-683, (1896). The question of the dissociation constants of organic acids. [Same as 1704.] T = 25°. 1704. B. Szyszkowski. Zeit. Phys. Chem. 22, 173-188, (1897). Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Konstitution derselben. [Same as 1703.] T = 25° 1705. B. V. Szyszkowski. Zeit. Phys. Chem. 58, 420-424, (1907). Beitrag zur Kenntnis der Neutralsalzwirkung. [Indicators. ] 1705a. B. V. Szyszkowski. Zeit. Phys. Chem. 73, 269-283, (1910). Ueber das Wesen der Neutralsalzwirkung. [Indicators.] Meas. B. Szyszkowski; see 1034, 1474. 1706. B. Szyszkowski, S. Refonnatsky. Jour. Russ. Phys.-chem. Soc. 33, 158-163, (1901). Synthesis and properties of a-dimethyl-;3-ethylethylenelactic acid. 1707. J. Tafel, J. Dodt. Ber. Deutsch. Chem. Ges. 40, 3757-3759, (1907). Aciditat der Desoxyxanthine. T=25°. 1708. G. Tammann. Ann. Physik. (3), 69, 767-780, (1899). Ueber die Abhangigkeit des elektrischen Leitvermogens vom Druck. T = 0°to40°. 1708a. G. Tammann. Zeit. Elektrochem. 16, 592-599, (1910). Ueber den Einfluss des Druckes auf das elektrische Leitvermogen von Losun- gen. T=0°. 1709. G. Tammann. Zeit. Phys. Chem. 6, 237-240, (1890). Ueber das Leitvermogen von Niederschlagmembranen. T = 18.5°. 1710. (G. Tammann. Zeit. Phys. Chem. 17, 725-736, (1895). Ueber den Einfluss des Drucks auf das elektrische Leitvermogen von Losun- gen.) [Quoted.] G. Tammann see A. Bogojawlensky. 1711. S. M. Tanatar, E. K. Kurovskij. Jour. Russ. Phys.-chem. Soc. 39, 936-943, (1907). Some salts of beryllium and zirconium. [The existence of many of these salts is denied by Parsons, Sargent, Jour. Am. Chem. Soc. 31, 1202, (1909).] 1712. S. M. Tanatar, E. K. Kurovskij. Jour. Russ. Phys.-chem. Soc. 39, 1630-1632, (1907). Benzoyl salts of berylUum and zirconium. [See criticism under 1711.] AUTHOR LIST 617 1713. B. Tarugi, G. Tomasinem. Arch. Fisiol. 5, 581-S90, (1908). Costanti fisico-chimiche del sudore deU'uomo ottenuto col bagno di luce. T = 25° M. Taylor see J. W. McBain. W. W. Taylor see C. Ranken. 1714. (S. Tereschin. Verhand. Deutsch. Phys. Ges. 11, 211-214, (1909). Ueber die Beziehung zwischen Dichte und Dissoziationsgrad wasseriger Salzlosungen.) [Quoted. A simplification of 821.] Tessarin see Zaiminovich-Tessarin. A. Thai see K. A. Hofmann, H. Kirmreuther. 1716. (A. Thiel. Zeit. Anorg. Chem. 59, 371-372, (1908). Notiz betreffend die Starke der zweiten Stufe von Phenolcarbon- und Phenol- sulfonsauren.) [Criticism of 1346. See 1718 for measurements.] 1716. (A. Thiel. Zeit. Elektrochem. 15, 1^, (1909). Ueber das Leitfahigkeitsminimum in der Titrationskurve mittelstarker und schwacher Sauren.) [Theoretical. See 294 and 295. ] 1717. A. Thiel, H. Roemer. Zeit. Phys. Chem. 61, 114-126, (1907- 1908). Ein Beitrag zur Kenntnis der Verteilung einer Base zwischen zwei Sauren. T = 25°. R. O. 1718. A. Thiel, H. Roemer. Zeit. Phys. Chem. 63, 711-761, (1908). Vergleichende Untersuchungen uber .Basizitat und Starke von Sauren und Phenolen. [Most is given in 1608. Some new measurements are given here. See 1228.] T = 25°. R. O. xaq. is about IX 10-5. 1719. A. Thiel, A. Schumacher, H. Roemer. Ber. Deutsch. Chem. Ges. 38, 3860-3862, (1905). Zur'Kenntniss der sauren Function des aromatischen Hydroxyls. [Qualitar tive. ] 1720. J. Thiele, H. Ingle. Ann. Chemie. 287, 233-265, (1895). Meas. M. Bauer. Ueber einige Derivate des Tetrazols. T = 25°. 1721. O. Thiele. Zeit. Physiol. Chem. 37, 251-301, (1902-1903). Ueber Uroferrinsaure. [Qualitative. ] N. G. Thomas see H. Hartley. M. deK. Thompson see H. M. Goodwin. 1722. (J. J. Thomson. Jour. Phys. (3), 5, 165-167, (1896). D^charge de I'^lectricit^ produite par les rayons de Rontgen, eflets produits par ces rayons sur les diflectriques qu'ils traversent.) [Same as 1723.] 1723. (J. J. Thomson. Proc. R. Soc. London. 59, 274r-276, (1895-1896). On the discharge of electricity produced by the Rontgen rays and the effects produced by these rays on dielectrics through which they pass.) [Same as 1722.] J. F. Thorpe see K. Auwers. " " see F. H. Howies. T. Tickle see J. N. Collie. 1724. S. J. Tijmstra Bz. Zeit. Phys. Chem. 49, 345-367, (1904). Leitfahigkeitsbestimmungen an Losungen von Natrium in absoluten und mit Wasser verdunnten Alkoholen und in Gemischen von zwei Alkoholen. [Part is same as 1726. Propyl alcohol and mixtures of ethyl and methyl alcohols are also given here. ] T = 18° R. O. xaq. = 1.3XlO-«. 518 AUTHOR LIST 1725. S.TijmstraBz. VerslagAkad. Amsterdam, 12,166-169,(1903-1904). Verslag Akad. Amsterdam, English translation, 6, 104-107, (1903- 1904). De electrolytische geleidbaarheid van oplossingen an natrium in mengsels van aethyl of methylalcohol+ water. [Given in 1724.] T = 18°. Timofeeff see Timofejev. 1726. (V. F. Timofejev. Jour. Russ. Phys.-chem. Soc. 41, 241-244, (1909). Mendelejeff mimber. The influence of the functional distinctions of the ingredients of the solution on the curve of the solution.) 1727. (V. F. Timofejev, L. D. Kobozev. Jour. Russ. Phys.-chem. Soc. 36, 255-275, (1904). Decomposition of trichloroacetic acid and some of its salts in aqueous solution.) [Velocity of reaction. ] 1728. A. Tingle. Jour. Am. Chem. Soc. 21, 792-803, (1899). The influence of substituents on the electrical conductivity of benzoic acid. T=25°. Hg. U. Mean xaq.= 4.4X10-8; sub. Meas. I. Ti§£enko; see 1760a. 1729. A. W. Titherley. Jour. Chem. Soc. 79, 391-411, (1901); Meas. W. B. Davidson. Preparation of substituted amides from the corresponding sodamides. T = 25°. 1729a. H. T. Tizard. Jour. Chem. Soc. 97, 2477-2490, (1910). The colour changes of methyl-orange and methyl-red in acid solution, [k is given in 1729c. ] T = 18°and25°. kwXlO" = 0.6 at 18°; =1.1 at 25°. 1729b. H. T. Tizard. Jour. Chem. Soc. 97, 2490-2495, (1910). The hydrolysis of aniline salts measured colourimetrically. T = 25°- kwX10" = l.lat25° 1729c. H. T. Tizard. Proc. Chem. Soc. 26, 225, (1910). The coloiu* changes, etc. [Given in 1729a.] H. T. Tizard see N. V. Sidgwick. G. Tomasinelli see B. Tarugi. G. Tommasi see N. Parravano. 1730. H. A. Torrey, W. MacPherson. Jour. Am. Chem. Soc. 31, 579-583, (1909). Some azo dyes from p-aminoacetophenone. 1731. M. Tortelli. Ber. Deutsch. Chem. Ges. 28, 1702-1707, (1895). Zur Constitution der Puchsine. [Text an abridgement of 1732, but has full tables of A. ] 1732. M. Tortelli. Gaz. Chim. Ital. 25, II, 233-248, (1895). SuUa costituzione delle fucsine. [Same as 1731.] 1733. N. E. Tousley, M. Gomberg. Jour. Am. Chem. Soc. 26, 1516-1523, (1904). Some tri-p-tolylmethane derivatives. T = 20°. 1734. O. F. Tower. Jour. Am. Chem. Soc. 22, 501-521, (1900). The precipitation of the sulphides of nickel and cobalt in an alkaline tartrate solution, together with an investigation into the nature of certain tartrates of these metals. [The measurements in 1736 are more accurate.] T = 18°. R. O. AUTHOR LIST 519 1735. O. F. Tower. Jour. Am. Chem. Soc. 24, 1012-1023, (1902). On the constitution of certain organic salts of nickel and cobalt as they exist in aqueous solutions. [Also corrects 1734. ] T = 18°±0.1°. R. O. xaq. =2.0-3.0X10-8; sub. 1736. O. F. Tower. Jour. Am. Chem. Soc. 27, 386-391, (1905). Note on the constitution of certain organic salts of nickel and cobalt as they exist in aqueous solution. T = 18°. R. O. xaq. = 1.8X10-«; sub. 1737. O. F. Tower. Zeit. Phys. Chem. 18, 17-50, (1895). Studien tiber Superoxyd-Elektroden. 1^=15°. *1738. (I. Traube. Ber. Deutsch. Chem. Ges. 42, 86-94, (1909). Ueber den Haftdruck. Beitrag zur Theorie der Losungen.) [Summary of 1739.] *1739. (I. Traube. Verhand. Deutsch. Phys. Ges. 10, 880-930, (1908). Der Haftdruck. Beitrag zur Theorie der Losungen.) [Summary with data in 1738.] 1740. (J. Traube. Ann. Physik. (3), 62, 490-506, (1897). Ueber osmotischen Druck und electrolytische Dissociation.) [Theoretical.] 1741. J. Traube. Ber. Deutsch. Chem. Ges. 24, 1859-1864, (1891). Zur Dissociationshypothese. Ueber elektrisches Leitungsvermogen und Ge- frierpunkt. T = 15° and 18°- Hg. U. x aq. sub. 1742. (J. Traube. Ber. Deutsch. Chem. Ges. 25, 2989-2993, (1892). Die Hypothesen der elektrolytischen Dissociation und der Jonisation.) 1743. (J. Traube. Chem. Ztg. 26, 2, 1071-1074, (1902). Ueber die modemen Losungstheorien. Die osmotische Theorie und die elek- troljrtische Dissociationstheorie.) 1744. (J. Traube. Phil. Mag. (6), 8, 158-165, (1904). A theory of solutions.) 1745. J. E. Trevor. Zeit. Phys. Chem. 10, 321-353, (1892). Ueber die Messung kleiner Dissociationsgrade. 1746. H. Trey. Zeit. Phys. Chem. 22, 424r^63, (1897). Ein weiterer Beitrag zur Birotation der Glykose. T=25°. S. U. X25aq. =2X10-"; sub. 1747. H. Trey. Zeit. Phys. Chem. 46, 620-719, (1903). Ein Beitrag zu den Rotationserscheinungen der Laktose. T = 25°. S. U. 1748. P. A. Triibsbach. Zeit. Phys. Chem. 16, 708-728, (1895). Die Affinitatsgrossen der Ureide imd Isonitrosoderivate. T =25°. K aq. = 1.5 —2.5 X 10-"; sub. for some compounds; no statement in other cases. 1749. P. Trummel. Dis. Bonn. (1908). Meas. with A. Schubert. Beitrage zur Kenntnis der Konstitution der Citraconsaure und ihrer Homo- logen. R. O. K aq. less than 2X10-^• sub. 1750. L. Tschugaeff. Ber. Deutsch. Chem. Ges. 38, 2899-2914, (1905). Ueber complexe Verbindungen organischer Imide. Succinimidkupfer-Deri- vate. T=25° 1751. L. Tschugaeff. Ber. Deutsch. Chem. Ges. 39, 2692-2702, (1906). Ueber Kobaltidioximine. T=25°. * I. Traube is the same name as J. Traube. 520 AUTHOR LIST 1752. L. TschugaefE. Ber. Deutsoh. Chem. Ges. 39, 3190-3201, (1906). Ueber complexe Verbindungen organische Imide; Succinimidnickel-Derivate. [Part is in 1758. ] T=25°. 1753. L. Tschugaeff. Ber. Deutsch. Chem. Ges. 40, 3498-3504, (1907). Ueber Kobalti-dioximine. [Given in 1759. ] T = 25°. 1754. L. Tschugaeff. Ber. Deutsch. Chem. Ges. 41, 2226-2232, (1908). Meas. E. Siller. Ueber eine neue Komplexsaure. (StudientiberKobaltidioximinelll). [Same as 1760.] T = 25°. 1756. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 39, 1262-1323, (1907). Investigations in the sphere of complex compounds. I. Complex compounds of organic imides. T = 25°. 1756. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 285-286, (1909). Mendelejeflf number. A new series of complex acids. T=25°. 1757. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 184-252, (1909). Investigations in the sphere of complex compounds. III. Metallic derivatives of a-dioximes. T = 25°. 1758. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 253-287, (1909). Investigations in the sphere of complex compounds. IV. On the conditions of formation of complex compounds of the metal-ammonia type. [Given in 1752.] T = 25° 1759. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 1332-1354, (1909). Investigations in the sphere of complex compounds. V. The non-ionized cobalt dioximines. [Part is same as 1753.] T = 25°. 1760. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 1355-1368, (1909). Meas. E. Siller. Investigations in the sphere of complex compounds. VI. A new series of complex acids. [Same as 1754.] T = 25° 1760a. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 42, 1466-1487, (1910). Meas. A. Postinkov and I. Tiscenko. Investigations in the sphere of complex compounds. VII. On some complexes made from dioximines. T = 25°. 1761. L. Tschugaeff. Zeit. Anorg. Chem. 46, 144-169, (1905). Ueber komplexe Verbindungen der a-Dioxime. T=25°. 1762. L. Tschugaeff, W. Sokoloff. Ber. Deutsch. Chem. Ges. 40, 3461- 3465, (1907). Ueber einige Komplexverbindungen des optisch-aktiven l-Propylendiamins. T=25°. AUTHOR LIST 521 1763. C. Tubandt. Ann. Chemie. 339, 41-93, (1905). Quantitative Bestimmung des Natriumalkoholats mit Menthon. [Given in 1765.] T = 25°. xaq.=3.7XlO-«. 1764. (C. Tubandt. Ann. Chemie. 354, 259-324, (1907). Zur Kenntniss der Reactionskinetik in nichtwassrigen Losungen.) [Inversion of menthone by alcohols and acids. Given in 1765. ] 1765. C. Tubandt. Dis. Halle. (1904). Die Inversionsgeschwindigkeit des Menthons. [Same as 1763 and 1764 together. ] 1766. B. B. Turner. Am. Cham. Jour. 40, 558-674, (1908). The limiting conductivity and degree of ionization of alcohoUc solutions. T = 0°to50° R. O. 1767. D. Turner. Nature. 60, 245, (1899). The electrical resistance of the blood. [Abstract of 1769.] T = 60° P. [ = 15.6°.] 1768. D. Turner. Nature. 66, 127, (1902). The electrical resistance of the blood. 1769. D. Turner. Trans. R. Scot. Soc. 16, 6-7, (1906). On an apparatus for measuring the electrical resistance of the blood, with some deductions therefrom. [Abstract is given in 1767. ] T = 60° F. [ = 15.6°]. W. E. S. Turner see A. Findlay. Tymstra see Tijmstra. U. Meas. TTdby; see 664. B. af Ugglas see H. Euler. Meas. H. T. Upson; see 1660. H. T. Upson see J. Stieglitz. A. Usoff see G. Bredig. A. Vagt see A. Hantzsch. 1770. P. VaiUant. Compt. Rend. 137, 849-851, (1903). Sur la couleur des solutions aqueuses de m^thylorange et le changement qu'y dgterminent les acides. T = 25°. 1771. C. VaUee. Ann. Chim. Phys. (8), 15, 331-432, (1908). Recherehes sur les isocyanates de ph^nyle, de naphtyle et de menthyle. van see the letter beginning the next word, as under de. 1772. W. R. Veazey. Dis. Johns Hopkins. (1907). The conductivity and viscosity of solutions of certain salts in water, methyl alcohol, ethyl alcohol, acetone and binary mixtures of these solvents. [Same as 922.] T = 0°and25°- S. U. x aq. is about 1X10-*. W. R. Veazey see H. C. Jones. A. V. Vegesack see W. Biltz. A. Veit see A. Hantzsch. 1773. V. H. Veley. Jour. Chem. Soc. 91, 153-175, (1907). The affinity constants of aminooarboxylic and aminosulphonic acids as de- termined by the aid of methyl-orange. [See 1781 for method. Gives only relative values. Abstract in 1783. ] 522 AUTHOR LIST 1774. V. H. Veley. Jour. Chem. Soc. 91, 1246-1251, (1907). The aflSnity constants of aminosulphonic acids as determined by the aid of methyl-orange. [Gives only relative values. Abstract given in 1784. ] 1775. V. H. Veley. Jour. Chem. Soc. 93, 652-666, (1908). The affinity constants of bases as determined by the aid of methyl-orange. T = 12° to 18°. 1776. V. H. Veley. Jour. Chem. Soc. 93, 211^2122, (1908). The affinity of certain alkaloids for hydrochloric acid. [Summary in 1787 is qualitative. ] T = 10° to20°. 1777. V. H. Veley. Jour. Chem. Soc. 93, 2122-2144, (1908). The affinity constants of bases as determined by the aid of methyl-orange. T = 10°to20°. 1778. V. H. Veley. Jour. Chem. Soc. 95, 1-8, (1909). The affinity values of tropine and its derivatives. [Abstract in 1789 has some data. ] T = 14°tol8°. 1779. V. H. Veley. Jour. Chem. Soc. 95, 758-767, (1909). The affinity values of certain alkaloids. [Summary given in 1790. ] T = 15° to 20°. 1780. (V. H. Veley. Phil. Mag. (6), 11, 73-81, (1906). A modified form of apparatus for the determination of the dielectric constants of non-conducting liquids.) 1781. V. H. Veley. Zeit. Phys. Chem. 57, 147-167, (1906). Ueber die Reaktionen zwischen Sauren und Methylorange. 1782. (V. H. Veley. Zeit. Phys. Chem. 61, 464^67, (1907-1908). Ueber die Reaktionen zwischen Sauren und Methylorange.) 1783. (V. H. Veley. Proc. Chem. Soc. 22, 313-314, (1906). The affinity constants of aminocarboxylic and aminosulphonic acids as de- termined by the aid of methyl-orange.) [No data. See 1773.] 1784. (V. H. Veley. Proc. Chem. Soc. 23, 179-180, (1907). The affinity values of aminosulphonic acids, etc.) [An abstract of 1774.] 1785. (V. H. Veley. Proc. Chem. Soc. 23, 284-285, (1907). The affinity constants of bases as determined by the aid of methyl-orange.) 1786. (V. H. Veley. Proc. Chem. Soc. 24, 60, (1908). The affinity constants of bases as determined by the aid of methyl-orange.) [Qualitative. A summary of 1775.] 1787. (V. H.„Veley. Proc. Chem. Soc. 24, 234^235, (1908). The affinity of certain alkaloids for hydrochloric acid.) [Summary of 1776. ] 1788. (V. H. Veley. Proc. Chem. Soc. 24, 238, (1908). The affinity constants of bases as determined by the aid of methyl-orange.) [Summary of 1777.] 1789. V. H. Veley. Proc. Chem. Soc. 24, 280-281, (1908). The affinity values of tropine and its derivatives. [Summary of 1778 with some data.] 1790. V. H. Veley. Proc. Chem. Soc. 25, 115-116, (1909). The affinity values of certain alkaloids. [Summary of 1779. ] 1791. A. Vesterberg. Arkiv Kemi. 2, no. 37, 1-18, (1905-1907). Forsok ofver hydrolys af Salter i vattenhaltig alkohol. T = 18°- 1792. (G. Viceatini. Atti Accad. Torino. 19, 832 and 897-898, (1883-1884). Sulla conducibilitS, elettrica delle soluzioni alcooliche di alcuni cloruri.) [In- organic. A summary of 1794. ] AUTHOR LIST 623 1793. (G. yicentini. Atti Accad. Torino. 20, 869-895, (1884-1885). Sulla conducibilitS, elettrica dei sali in soluzioni acquose molto diluite.) [In- organic] 1794. (G. yicentini. Mem. Accad. Torino. (2), 36, 385-404, (1885). Sulla conducibilitS, elettrica delle soluzioni alcooliche di alcuni cloruri.) [In- organic. Summary given in 1792. ] 1795. (G. Vicentini. Atti 1st. Veneto. (6), 2, 1699-1726, (1883-1884). Sulla conducibilita elettrica delle soluzioni saline acquose molto diluite.) [In- organic. ] 1796. L. Virion. Bui. Soc. Chim. (4), 1, 273-279, (1907). Teinture et ionisation. [Same as 1799 and 1800a for A, but also gives k. ] T = 18° to 90°. Legal ohms. 1797. L. Vignon. Bui. Soc. Chim. (4), 5, 492-495, (1909). Sur les propri^t^s colorantes et tinctoriales de I'acide picrique. [Same as 1800 T = 18°, 70° and 80°. and 1800c. ] 1798. L. Vignon. Bui. Soc. Chim. (4), 5, 495-500, (1909). ConductibUit^ flectrique de certains bains de teinture. [Same as 1800b.] T = 15°tolOO°. 1799. L. Vignon. Compt. Rend. 144, 81-83, (1907). Teinture et ionisation. [Same as 1796 for A. Same as 1800a. ] 1800. L. Vignon. Compt. Rend. 148, 844-846, (1909). Sur les propri^t^s colorantes, etc. [Same as 1797 and 1800c.] 1801. L. Vignon, E. Evieux. Bui. Soc. Chim. (4), 3, 1012-1019, (1908). Chaleur de neutrahsation de I'acide ac6tique et de I'acide benzoique par 1' ani- line en milieu benz6nique. [Part is same as 1803. Salts of toluidines are also given here. ] 1802. L. Vignon, E. Evieux. Bui. Soc. Chim. (4), 3, 1019-1030, (1908). Chaleur de neutralisation de I'acide picrique par diverses bases aromatiques en milieu benz6nique. [Part is same as 1804. ] 1803. L. Vignon, E. Evieux. Compt. Rend. 146, 1316-1318, (1908). Chaleur de neutralisation de I'acide ac^tique, etc. [Given in 1801.] 1804. L. Vignon, E. Evieux. Compt. Rend. 147, 67-70, (1908). Chaleur de neutralisation de I'acide picrique, etc. [Given in 1802.] 1805. E. Villari. Nature. 56, 91, (1897). Influence of Rontgen rays upon electrical conductivity. V. Villiger see A. Baeyer. 1806. G. Vinci. Arch. Fisiol. 6, 41-56, (1909). Contributo aUa conosoenza della lintogenesi. I. Sulle propriety fisico-chimiche della linfa della linforrea sperimentale. T = 25°. E. Voegelen see A. Hantzsch. 1807. B. Vollmer. Ann. Physiii. (3), 52, 328-356, (1894). Die electrische Leitfahiglieit von einigen Salzen in Aethyl- und Methylalkohol. [This is 1808 with additions.] T = 10°, 18° and 26°. S. U. 1808. B. Vollmer. Dis. Halle. (1892). Die molekulare elektrische Leitfahigkeit von einigen alkoholischen Losungen. [Original not examined by me. This title is from an abstract in Zeit. Phys. Chem. 10, 668-669, (1892). See 1807.] 1809. B. Vollmer. Festschr. Halle. (1898). Das elektrolytische Verhalten einiger Losungen yon essigsaurem Kali in Essigsaure. [Original not examined by me. This title is from an abstract in Zeit. Phys. Chem. 29, 187, (1899).] T = 20°and30°. 524 AUTHOR LIST 1810. G. L. Voerman. Rec. Trav. Chim. 23, 265-282, (1904). Recherches sur quelques anhydrides d'acides bibasiques saturfe, en connexion avec la th^orie de tension de v. Baeyer. [Probably same as 1812a of which it is an extract.] T = 25°. R. O. jC25aq. = 1.6X10-«; notsub. 1811. G. L. Voerman. Rec. Trav. Chim. 26, 293-310, (1907). Sur les acides monocarboniques du thiophene. [Same as 1812 for a-acid, but gives also a table of A for /3-acid. ] T = 25°? R. O. X aq. less than 2X10-8. 1812. G. L. Voerman. Verslag Akad. Amsterdam, 15, 545-555, (1906- 1907). Verslag Akad. Amsterdam, English translation, 9, 514r-524, (1906-1907). Het a- en het /3-thiopheenzuur. [Indexed as Holleman, Voerman. Same as 1811 fork.] 1812a. G. L. Voerman. Dis. Groningen. (1904). [Not examined by me. See 1810.] ?Meas. G. L. Voennan; see 846. von see imder the letter beginning the next word, as under de. 1813. D. Vorlander. Ann. Chemie. 320, 66-98, (1902). Meas. Meusel. Kohlenstoffdoppelbindung und Carbonyl. [Given in 1246. ] T = 25°. R. O. K;aq.=2.6X10-^ 1814. D. Vorlander. Ber. Deutsch. Chem. Ges. 35, 1683-1698, (1902). Indoxylbildung aus Phenylglycin-o-carbonsaure. [These measurements were apparently made by Meusel. See 1245 for tables of A and k.] T = 25°. 1815. D. Vorlander. Ber. Deutsch. Chem. Ges. 36, 268-281, (1903). Meas. E. Mumme. Die sauren Eigenschaften des Malonsaureesters. T = 25°. %aq.= 2.8X10-6. D. Vorlander see R. v. Schilling. 1816. D. Vorlander, F. Kalkow. Ann. Chemie. 309, 356-374, (1899). Die Formaldehydverbindung des Hydroresorcins. [Qualitative.] 1817. D. Vorlander, E. Mumme. Ber. Deutsch. Chem. Ges. 33, 3182-3183, (1900). Ueber Anildiessig-o-carbonsaure. [Qualitative. For tables of A and k see 1246. Same as 1301.] W. 1818. P.Waentig. Zeit.Phys. Chem. 68,513-571, (1909). Meas. Hermdorf. Ueber den Zustand des gelosten Jods. T=20°. P. Waentig see E. Beckmann. 1819. J. Wagner. Zeit. Phys. Chem. 12, 314-321, (1893). Ueber die Farbe der lonen. [Qualitative.] 1820. A. J. Wakeman. Zeit. Phys. Chem. 11, 49-74, (1893). Das Verhalten einiger Elektrolyte in nichthomogenem Losungsmittel. 1821. A. J. Wakeman. Zeit. Phys. Chem. 15, 159-182, (1894). Ueber die Beeinflussung der Molekular-Leitfahigkeit der Essigsaure durch kleine Mengen anderer elektrolytischer Substanzen. Anwendung der Theorie der isohydrischen Losungen. [Same as 1822. ] 1822. A. J. Wakeman. Dis. Leipzig. (1894). Ueber die Beeinflussung, etc. [Same as 1821.] Meas. A. Wakeman; see 1904. AUTHOR LIST 525 1823. P. Walden. Ber. Deutsch. Chem. Ges. 24, 2025-2039, (1891). Zur Kenntnisa der Tetrinsaure, Oxytetrinsaure und ihrer Homologen. [Given in 1831.] T = 25°. 1824. P. Walden. Ber. Deutsch. Chem. Ges. 29, 1692-1707, (1896). Zur Charakteristik optisch-isomerer Verbindungen. 1826. P. Walden. Ber. Deutsch. Chem. Ges. 31, 3167-3174, (1898). Ueber die vermeinthche Identitat des Tannins mit der a-Digallussaure. T = 25°. 1826. P. Walden. Ber. Deutsch. Chem. Ges. 32, 2862-2871, (1899). Ueber ein neues, anorganisches, ionisirendes Losungsmittel. [Given more acciirately in 1856. ] T = 0° 1827. P. Walden. Ber. Deutsch. Chem. Ges. 34, 4185-4202, (1901). Ueber die basischen Eigenschaften des Sauerstoffes. T = 0°and25° x aq.=3.45Xl0-«- 1828. P. Walden. Ber. Deutsch. Chem. Ges. 35, 1764^1772, (1902). Ueber den mehrwerthigen Sauerstoff. T = 0°and25°. R. O. 1829. P. Walden. Ber. Deutsch. Chem. Ges. 35, 2018-2031, (1902). Ueber die basischen Eigenschaften des Kohlenstoffs. T = 0°. R. O. 1830. P. Walden. Ber. Deutsch. Chem. Ges. 38, 345-409, (1905). Ueber das Drehungsvermogen optisch-activer Korper. T=25°. R. O. 1831. P. Walden. Jour. Russ. Phys.-chem. Soc. 23, 632-652, (1891). The question of the structure of Demargay's acids. [Same as 1823 with a few additions.] 1832. P. Walden. Zeit. Anorg. Chem. 23, 373-377, (1900). ^Meas. [J.] V. Zawidzki. Ueber einige zusammengesetzte Rhodan- und Cyanverbindungen. T = 25°. 1833. P. Walden. Zeit. Anorg. Chem. 25, 209-226, (1900). Ueber einige anorganische Losungs- und lonisierungsmittel. T = 25°and0°- 1834. P. Walden. Zeit. Anorg. Chem. 29, 371-395, (1902). Ueber anorganische Losungs- und lonisierungsmittel. T = 25° and 33°. [Probably R. O. ] 1836. (P. Walden. Zeit. Elektrochem. 14, 713-724, (1908). Ueber die Schmelzwarme, spezifische Kohasion und Molekulargrosse bei der Schmelztemperatur.) 1836. P. Walden. Zeit. Phys. Chem. 1, 529-549, (1887). Ueber die Bestimmung der Molekulargrossen von Salzen aus der elektrischen Leitfahigkeit ihrer wasserigen Losungen. T = 25°. Hg. U. 1837. P. Walden. Zeit. Phys. Chem. 2, 49-77, (1888). Ueber die Bestimmung der Molekulargrossen von Salzen aus der elektrischen Leitfahigkeit ihrer wasserigen Losungen. T = 25°. 1838. P. Walden. Zeit. Phys. Chem. 8, 433-503, (1891). [HMeas. U. CoUan. See 826.] Ueber die Affinitatsgrossen organischer Saitfen imd ihre Beziehungen zur Konstitution derselben. T=25° S. U. aq. very well purified. ^ 526 AUTHOR LIST 1839. P. Walden. Zeit. Phys. Chem. 10, 563-579, (1892). Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Konstitution derselben. II. Teil; Trikarbonsauren. [Continuation of 1838. ] 1840. P. Walden. Zeit. Phys. Chem. 10, 638-664, (1892). Ueber die Affinitatsgrossen organischer Sauren und ihre Beziehungen zur Kon- stitution derselben. III. Teil; Monokarbonsauren. [Continuation of 1839.] 1841. P. Walden. Zeit. Phys. Chem. 15, 196-208, (1894). Ueber die optisohe Drehung der lonen. T = 25°. 1842. P. Walden. Zeit. Phys. Chem. 43, 385-464, (1903). Ueber abnorme Elektrolyte. T=-10°, 0°and25°. R. O. 1843. P. Walden. Zeit. Phys. Chem. 46, 103-188, (1903). #Meas. Centnerszwer. Ueber organische Losungs- und lonisierungsmittel. I. T = 0°and25°. R. O. 1844. P. Walden. Zeit. Phys. Chem. 54, 129-230, (1906). Ueber organische Losungs- und lonisierungsmittel. II. Teil. Messungen der elektrischen Leitfahigkeit. T = 0°to25°. R. O. 1846. P. Walden. Zeit. Phys. Chem. 55, 207-249, (1906). Ueber organische Losungs- und lonisierungsmittel. III. Teil. Innere Reibung und deren Zusammenhang mit dem Leitvermogen. T = 0°and25°. R. O. 1848. P. Walden. Zeit. Phys. Chem. 55, 281-302, (1906). Ueber organische Losungs- und lonisiervmgsmittel. IV. Teil. EbuUiosko- pische Messimgen. T=25''andl30°. 1847. P. Walden. Zeit. Phys. Chem. 55, 683-720, (1906). Ueber organische Losungs- und lonisierungsmittel. V. Teil. Losungsvermogen. T = 0°and25°. 1848. P. Walden. Zeit. Phys. Chem. 58, 479-511, (1907). Ueber organische Losungs- und lonisierungsmittel. VI. Teil. Losungswarmen. T=0°and25. R. O. x solvent sub. 1849. P. Walden. Zeit. Phys. Chem. 59, 192-211, (1907). Ueber organische Losungs- und lonisierungsmittel. VII. Teil. Losungs- und Dissociationswarmen. T = 0°and25° 1850. (P. Walden. Zeit. Phys. Chem. 59, 385-415, (1907). Ueber organische Losungs- und lonisierungsmittel. VIII. Teil. Lichtbrech- ungsvermogen und elektrolytische Dissociation.) [Quoted. ] 1851. P. Walden. Zeit. Phys. Chem. 60, 87-100, (1907). Ueber organische Losungs- und lonisierungsmittel. IX. Teil. Elektrostriktion. T = 25°- 1852. (P. Walden. Zeit. Phys. Chem. 61, 633-639, (1907-1908). Ueber organische Losungs- und lonisierungsmittel. X. Teil. Losende Kraft und Dielektrizitatskonstante.) 1853. (P. Walden. Zeit. Phys. Chem. 65, 129-225, (1908-1909). Ausdehnungsmodulus, spezifische Kohasion, Oberflachenspannung imd Mole- kulargrosse der Losungsmittel.) 1863a. P. Walden. Zeit. Phys. Chem. 73, 257-268, (1910). Ueber die elektrolytische Leitfahigkeit nichtwasseriger Losungen bei tiefen Temperaturen. T= -112° to -1-103°. R. O. X solvent sub. AUTHOR LIST 527 1853b. P. Walden, (R. Swinne). Zeit. Phys. Chem. 75, 555-577, (1910- 1911). Ueber einige abnorme Temperaturkoeffizienten der molekularen Oberflachen- . d(7V%) energie 3- — von organischen Stoffen. T = 25°. R. O. Meas. P. Walden; see 62, 67, 189, 190, 191, 195, 196, 197, 198, 1264, 1371, 1377. P. Walden see C. A. Bischoff. 1853c. P. Walden. Trans. Faraday Soo. 6, 71-78, (1910). Is water an electroljrte? T = 0°and25° R. O. x of solvent is sub. 1864. P. Walden, M. Centnerszwer. Zeit. Anorg. Chem. 30, 145-250, (1902). Fliissiges Schwefeldioxyd als Losungsmittel. [Same as 1855 and 1866a. More accm'ate than 1826.] T=-74°to +175°. S. U. 1865. P. Walden, M. Centnerszwer. Zeit. Phys. Chem. 39, 513-596, (1902). Fliissiges Schwefeldioxyd als Losmigsmittel. [Same as 1854 and 1866a. ] T=-75°to +175°. S. U. 1866. (P. Walden, M. Centnerszwer. Zeit. Phys. Chem. 42, 432-468, (1902-1903). Ueber Verbindungen des Schwefeldioxyds mit Salzen.) A. P. Walker see J. Walker. 1857. J. Walker. Ber. Deutsoh. Chem. Ges. 34, 4115-4118, (1901). Ueber Sauerstoffbasen. [Qualitative.] 1868. J. Walker. Chem. News. 94, 138-139, (1906). Meas. D. C. Crichton. A method for determining velocities of saponification. [Same as 1879.] 1869. J. Walker. Jour. Chem. Soc. 61, 696-717, (1892). The dissociation constants of organic acids. T=25°. X aq. compared favorably to specially prepared aq.; sub. 1860. J. Walker. Jour. Chem. Soc. 61, 1088-1096, (1892). The methyl salts of camphoric acid. [Gives 1873 correctly.] T = 25°. X aq. sub. 1861. J. Walker. Jour. Chem. Soc. 63, 495-510, (1893). The electrolysis of sodium ortho-ethyl camphorate. [See 1862 for correction of part of this. ] T = 25°. 1862. J. Walker. Jour. Chem. Soc. 67, 347-348, (1895). " Camphothetic " acid; a correction. [See 1861.] 1863. (J. Walker. Jour. Chem. Soc. 83, 182-184, (1903). The state of carbon dioxide in aqueoiis solution.) 1864. J. Walker. Zeit. Phys. Chem. 4, 319-343, (1889). Zur Aifinitatsbestimmung organischer Basen. T = 25°. 1866. J. Walker. Zeit. Phys. Chem. 32, 137-141, (1900). Ueber die Beziehung zwischen den Dissociationskonstanten schwacher Sauren und der Hydrolyse ihrer Alkalisalze. [Measurements same as 1883. ] 1866. J. Walker. Zeit. Phys. Chem. 46, 30-36, (1903). The determination of avidity by the polarimetric method. 1867. (J. Walker. Zeit. Phys. Chem. 49, 82-94, (1904). Theorie der amphoteren Elektrolyte.) [Same as 1876. Quoted.] 528 AUTHOR LIST 1868. J. Walker. Zeit. Phys. Chem. 51, 706-716, (1905). Meas. J. John- ston. Theorie der amphoteren Elektrolyte. [Same as 1877.] 1869. (J. Walker. Zeit. Phys. Chem. 56, 575-576, (1906). Bemerkung zur Theorie der amphoteren Elektrols^te.) [Theoretical.] 1870. (J. Walker. Zeit. Phys. Chem. 57, 600-610, (1906). Die Affinitatskonstanten amphoterer Elektroljrte. III. Methylirte Amino- sauren.) [Theoretical. A simamary of 415 and 890. Same as 1878.] 1871. (J. Walker. Proc. R. Soc. Edinbm'gh. 20, 255-263, (1892-1895). Hydrolysis in some aqueous salt solutions.) [Quoted.] 1872. (J. Walker. Proc. Chem. Soc. 8, 137, (1892). The dissociation constants of organic acids.) [No data.] 1873. J. Walker. Proc. Chem. Soc. 8, 156, (1892). The methylic salts of camphoric acid. [Evidently intended to be same as 1860, but the names of the compounds are interchanged and kXlO* for one is given as 9.75 instead of the correct value 7.95.] 1874. J. Walker. Proc. Chem. Soc. 10, 94-95, (1894). Note on the constitution of glycocine. [Qualitative. ] 1875. (J. Walker. Proc. Chem. Soc. 18, 246, (1902). State of carbon dioxide in aqueous solution.) 1876. (J. Walker. Proc. R. Soc. London. 73, 155-165, (1904). Theory of amphoteric electrolytes.) [Same as 1867.] 1877. J. Walker. Proc. R. Soc. London. 74, 271-280, (1904-1905).. Meas. J. Johnston. Theory of amphoteric electroljrtes. [Same as 1868.] 1878. (J. Walker. Proc. R. Soc. London. A, 78, 140-149, (1906). The aflSnity constants of amphoteric electrolytes. III. Methylated amino- acids.) [Same as 1870.] 1879. J. Walker. Proc. R. Soc. London. A, 78, 157-160, (1906). Meas. D. C. Crichton. A method for determining velocities of saponification. [Same as 1868.] Meas. J. Walker; see44,231,232,397,398,965,1060,1410,1411,1412,1414. J. Walker see A. C. Brown. 1880. J. Walker, E. Aston. Jour. Chem. Soc. 67, 576-586, (1895). AfBnity of weak bases. T = 60°. 1881. (J. Walker, E. Aston. Proc. Chem. Soc. 11, 112, (1895). Affinity of weak bases.) [No data. A summary of 1880.] 1882. J. Walker, H. H. Beveridge. Jour. Chem. Soc. 91, 1797-1802, (1907). para-Toluidine monohydrate. 1883. J. Walker, W. Connack. Jour. Chem. Soc. 77, 5-21, (1900). The dissociation constants of very weak acids. [Same measurements in 1866.] T = 18°. S. U. Xia aq. less than 0.65 X 10-^. 1884. J. Walker, F. J. Hambly. Jour. Chem. Soc. 71, 61-72, (1897). Electrical conductivity of diethylammonium chloride in aqueous alcohol. T = 25°. S. U. X26aq. = 1.5X10-6; sub. 1885. (J. Walker, F. J. Hambly. Proc. Chem. Soc. 12, 246, (1896). Electrical conductivity of diethylammonium chloride in aqueous alcohol.) [No data.] 1886. J. Walker, S. A. Kay. Jour. Chem. Soc. 71, 489-508, (1897). Velocity of urea formation in aqueous alcohol. T = 32°. AUTHOR LIST 529 1887. J. Walker, A. J. Robertson. Proc. R. Soc. Edinburgh, 24, 363-379, (1901-1903). Freezing-point depression in electrolytic solutions. T = 0°. S. U. 1888. J. Walker, A. P. Walker. Jour. Chem. Soc. 87, 961-967, (1905). Tetrethylsuccinic acid. T = 26°. 1889. J. Walker, J. K. Wood. Jour. Chem. Soc. 77, 383-390, (1900). Configuration of the camphoric acids. [Same as 1891 for k, but also gives it. 1 T = 25°. 1890. J. Walker, J. K. Wood. Jour. Chem. Soc. 83, 484r-491, (1903). Hydrolysis of urea hydrochloride. [Same as 1892 for k.] T=25°. 1891. J. Walker, J. K. Wood. Proc. Chem. Soc. 16, 59-60, (1900). The configuration of the camphoric acids, [k same as 1889.] 1892. J. Walker, J. K. Wood. Proc. Chem. Soc. 19, 67, (1903). Hydrolysis of urea hydrochloride. [Same as 1890 for k.] 1893. J. W. Walker. Jour. Chem. Soc. 85, 1082-1098, (1904). lonisation and chemical combination. T = 18°. R. O. 1894. J. W. Walker, F. M. G. Johnson. Jour. Chem. Soc. 87, 1597-1600, (1905). The electrical conductivities of some salt solutions in acetamide. T = 100°. 1895. (J. W. Walker, F. M. G. Johnson. Proc. Trans. R. Soc. Canada. (2), 11, Sect. Ill, 29-30, (1905). The electrical conductivity of salt solutions in acetamide.) [No data.] 1896. (J. W. Walker, F. M. G. Johnson. Proc. Chem. Soc. 21, 233, (1905). The electrical conductivities of some salt solutions in acetamide.) [No data.] 1897. J. W. Walker, D. Mcintosh, E. H. Archibald. Jour. Chem. Soc. 85, 1098-1105, (1904). lonisation and chemical combination in the liquefied halogen hydrides and hydrogen sulphide. [QuaUtative. ] T= -50°, -80° and -100°. 1898. (J. W. Walker, D. Mcintosh, E. H. Archibald. Proc. Chem. Soc. 20, 134, (1904). lonisation and chemical combination in the liquefied halogen hydrides and hydrogen sulphide.) [No data.] 1899. O. Wallach. Ann. Chemie. 269, 326-347, (1892). Meas. A. Binz. Zur Kenntniss der Terpene und der atherischen Oele. T = 18°. S. U. 1900. E.Warburg. Ann. Physik. (3), 54, 396^33, (1895). Ueber electrische Leitung und Convection in schwach leitenden verdiinnten Losungen. T = 16°to 18°. F. J. Warth see R. C. Farmer. 1901. (E. W. Washburn. Jour. Am. Chem. Soc. 31, 322-355, (1909). The hydration of ions determined by transference experiments in the presence of a non-electrolyte.) [Inorganic and theoretical. Same as 1902.] 1902. (E. W. Washburn. Zeit. Phys. Chem. 66, 513-554, (1909). Bestimmung der Hydratation von lonen durch TJeberfuhrungsversuche in Gegenwart eines Nichtelektrolyten.) [Same as 1901.] Meas. O. Weber; see 78. O. Weber see E. Rimbach. 530 AUTHOR LIST 1903. E. Wedekind. Ber. Deutsch. Chem. Ges. 32, 3561-3569, (1899). Zur Charakteristik stereoisomerer Ammoniumsalze. T=25°. 1903a. E. Wedekind, F. Paschke. Zeit. Phys. Chem. 73, 118-128, (1910). Zur Kinetik des Zerfalls quartarer Ammoniuinsalze in Chloroform. T = 25°. xaq. = 3X10-«. 1904. J. B. Weems. Am. Chem. Jour. 16, 569-588, (1894). ^Meas. A. Wakeman. On electrosyntheses by the direct union of anions of weak organic acids. [Qualitative. ] 1905. (H. Wegelius. Zeit. Elektrochem. 14, 514-518, (1908). Ueber den Einfluss der Konzentration auf die Optimumtemperatur der elek- trischen Leitfahigkeit der schwachen Elektrol3rte mit negativer Dissoziations- warme.) [Inorganic] 1906. R. Wegscheider. Ber. Deutsch. Chem. Ges. 36, 1541-1544, (1903). Meas. H. Suss. Ueber die Tautomeric der o-Aldehydsauren. 1907. R. Wegscheider. Monatsh. 16, 75-162, (1895). Meas. W. Meyer- hoffer. Untersuchungen uber die Hemipinsaure und die Esterbildung. [Same as 1921. ] [T probably 25°. ] S. U. x aq. = 7 X 10-^. 1908. R. Wegscheider. Monatsh. 23, 287-316, (1902). Ueber den Einfluss der Constitution auf die Affinitatsconstanten organischer Sauren. [Calculated from Liohty; see 1099. Same as 1922.] 1909. R. Wegscheider. Monatsh. 23, 317-356, (1902). Untersuchungen iiber die Veresterung unsymmetrischer zwei- und mehr- basischer Sauren. IV. Abhandlung; Ueber die Leitfahigkeit einiger Sauren und Estersauren. [Same as 1923.] T = 25''±0.05°. R. O. xaq. =0.6-1.3X10-'=; [not sub.? On page 325 it is stated that aq. is sub. for one compound.] 1910. (R. Wegscheider. Monatsh. 23, 357-368, (1902). Untersuchungen iiber die Veresterung unsymmetrischer zwei- und mehr- basischer Sauren. V. Abhandlung; Ueber die Constitution einiger Estersau- ren.) [Same as 1924. Quoted.] 1911. (R. Wegscheider. Monatsh. 23, 599-668, (1902). Ueber die stufenweise Dissociation zweibasischer Sauren.) [Same as 1925. Values of second kA are calculated. ] 1912. R. Wegscheider. Monatsh. 26, 1231-1234, (1905). Meas. P. Imx. Ueber die Konstitution der o-Aldehydsauren in wasseriger Losung. [Same as 1926.] 1913. R. Wegscheider. Monatsh. 26, 1235-1239, (1905). Meas. P. Lux. Ueber die stufenweise Dissoziation zweibasischer Sauren. [Same as 1927. ] 1914. R. Wegscheider. Monatsh. 26, 1265-1276, (1905). Meas. P. Imx and J. H. Suss. Ueber die Affinitatskonstanten der Aminosauren. [Same as 1928. ] 1915. R. Wegscheider. Monatsh. 28, 819-824, (1907). Meas. N. L. Midler. Untersuchungen iiber die Veresterung unsymmetrischer zwei- und mehrbar sischer Sauren. XVII. Abhandlung; Ueber Aminoterephtalestersauren. [Same as 1929. 1916. R. Wegscheider. Zeit. Elektrochem. 14, 610-512, (1908). Meas. A. Schugowitsch. Ueber den Farbenumschlag des Phenolphthaleins. T=22°to24°. AUTHOR LIST 531 1917. R. Wegscheider. Zeit. Elektrochem. 14, 740-741, (1908). Die lonisationskonstanten des zweiten WasserstofBons zweibasischer Sauren. [Corrects 370.] 1918. (R. Wegscheider. Zeit. Phys. Chem. 69, 603-629, (1909). Ueber die Anomalie der starken Elektrolyte und die Giiltigkeitsgrenzen des Verdtinnungsgesetzes.) [Quoted.] 1919. (R. Wegscheider. Verhand. Deutsch. Phys. Ges. 11, 544-545, (1909). Giiltigkeitsgrenzen des Ostwaldschen Verdilnnungsgesetzes.) [Qualitative. See 1918.] 1920. (R. Wegscheider. Sitzber. Akad. Wien. 104, 2b, 111-116, (1895). Ueber die AfBnitatsconstanten der mehrbasisohen Sauren und der Ester- sauren.) [Quoted. ] 1921. R. Wegscheider. Sitzber. Akad. Wien. 104, 2b, 117-194, (1895). Meas. W. Meyerhoffer. Untersuchungen liber die Hemipinsaure und die Esterbildung. [Same as 1907.] 1922. R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 67-96, (1902). Ueber den Einfluss der Constitution auf die Affinitatsconstanten organischer Sauren. [Same as 1908.] 1923. R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 97-136, (1902). Untersuchungen iiber die Veresterung unsymmetrischer zwei- und mehr- basisoher Sauren. IV. Abhandlung; Ueber die Leitfahigkeit einiger Sauren und Estersauren. [Same as 1909. ] 1924. (R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 154-165, (1902). Untersuchungen iiber die Veresterung unsjrmmetrischer zwei- und mehr- basischer Sam-en. V. Abhandlung; Ueber die Constitution einiger Ester- sauren.) [Same as 1910.] 1925. (R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 441-510, (1902). Ueber die stufenweise Dissociation zweibasischer Sauren.) [Same as 1911.] 1926. R. Wegscheider. Sitzber. Akad. Wien. 114, 2b, 765-768, (1905). Meas. P. Lux. Ueber die Konstitution der o-Aldehydsauren in wasseriger Losung. [Same as 1912.] 1927. R. Wegscheider. Sitzber. Akad. Wien. 114, 2b, 769-773, (1905). Meas. P. Lux. Ueber die stufenweise Dissoziation zweibasischer Sauren. [Same as 1913. ] 1928. R. Wegscheider. Sitzber. Akad. Wien. 114, 2b, 801-812, (1905). Meas. P. Lux and J. H. Siiss. Ueber die Affinitatskonstanten der Aminosauren. [Same as 1914. ] 1929. R. Wegscheider. Sitzber. Akad. Wien. 116, 2b, 721-726, (1907). Meas. N. L. Miiller. Untersuchungen iiber die Veresterung, etc. [Same as 1915.] Meas. R. Wegscheider; see 1930, 1931, 1938, 1939, 1941, 1942. 1930. R. Wegscheider, K. Bittner. Monatsh. 21, 638-654, (1900). Meas. B. Wegscheider. Untersuchungen iiber die Veresterung unsymmetrischer zwei- und mehrba- sischer Sauren. II. Abhandlung; Ueber die Verestenmg der Brom- und der Oxyterephtalsaure. [Same as 1931.] 1931. R. Wegscheider, K. Bittner. Sitzber. Akad. Wien. 109, 2b, 523-539, (1900). Meas. R. Wegscheider. Untersuchungen uber die Veresterung, etc. [Same as 1930. ] 532 AUTHOR LIST 1932. R. Wegscheider, E. Bondi. Monatsh. 26, 1039-1068, (1905). Mea^. P. Lux. Untersuchungen uber die Veresterung unsymmetrischer zwei- und mehrba- sischer Sauren. XIII. Abhandlung; Ueber Estersauren 4-substituierter Phtalsauren. [Same as 1933.] 1933. R. Wegscheider, E. Bondi. Sitzber. Akad. Wien. 114, 2b, 573-602, (1905). Meas. P. Lux. Untersuchungen iiber die Veresterung, etc. [Same as 1932. ] 1934. R. Wegscheider, A. Glogau. Monatsh. 24,915-958,(1903). Meas. H. Siiss. Untersuchungen tiber die Veresterung unsymmetrischer zwei- und mehr- basischer Sauren. XII. Abhandlung; Ueber die Veresterung der Phtalon- saure und der Homophtalsaure. [Qualitative. Same as 1936. Measiu-ements given in 1684.] 1935. R. Wegscheider, A. Glogau. Sitzber. Akad. Wien. 112, 2b, 749-792, (1903). Meas. H. Suss. Untersuchungen iiber die Veresterung, etc. [Same as 1934.] 1936. R. Wegscheider, J. Hecht. Monatsh. 24, 413-433, (1903). Untersuchungen iiber die Verestenmg unsymmetrischer zwei- vmd mehr- basischer Sauren. X. Abhandlung; Ueber Phenylbemsteinsaure und ihre Veresterung. [Same as 1937.] R. O. xaq. = 2.1X10-". 1937. R. Wegscheider, J. Hecht. Sitzber. Akad. Wien. 112, 2b, 241-261, (1903). Untersuchungen iiber die Veresterung, etc. [Same as 1936. ] 1938. R. Wegscheider. A. Lipschitz. Monatsh. 21, 787-812, (1900). Meas. R. Wegscheider. Untersuchungen iiber die Veresterung unsymmetrischer zwei- und mehr- basischer Sauren. III. Abhandlung; Ueber die Veresterung der 3- und 4- Nitrophtalsaure. [Same as 1939. Corrected in 1909. ] 1939. R. Wegscheider, A. Lipschitz. Sitzber. Akad. Wien. 109, 2b, 586- 611, (1900). Meas. R. Wegscheider. Untersuchungen iiber die Veresterung, etc. [Same as 1938. ] 1940. R. Wegscheider, P. Lux. Monatsh. 30, 411^45, (1909). Meas. P. Lux. Die Sulfonsauren und das Ostwald'sche Verdiinnungsgesetz. [Same as 1940a.] T=25°±0.05°. R. 0. Kaq. = 1-1. 8X10-8; sub. in some cases. 1940a. R. Wegscheider. P. Lux. Sitzber. Akad. Wien. 118, 2b, 189-223, (1909). Meas. P. Lux. Die Sulfonsauren, etc. [Same as 1940. ] 1941. R. Wegscheider, P. v. RuSnov. Monatsh. 24, 375-390, (1903). Meas. R. Wegscheider. Untersuchungen uber die Veresterung unsymmetrischer zwei- und mehrba- sischer Sauren. XI. Abhandlung; Verhalten der Hemipinestersauren gegen Hydrazinhydrat und gegen Thionylchlorid. [Same as 1942.] R. 0. 1942. R. Wegscheider, P. v. RuSnov. Sitzber. Akad. Wien. 112, 2b, 207- 222, (1903). Meas. R. Wegscheider. Untersuchungen iiber die Veresterung, etc. [Same as 1941.] M. Weinheber see A. Rosenheim. J. Weir see H. Pauly. H. G. Wells see R. L. Benson. AUTHOR LIST 533 1943. (R. C. WeUs. Jour. Am. Chem. Soc. 31, 1027-1035, (1909). The electrical conductivity of ferric sulphate solutions.) [Inorganic and quoted. ] Wendt see Bohm-Wendt. H. A. Wentworth see H. M. Goodwin. F. Wenzel see F. Haiser. 1944. A. Werner. Ann. Chemie. 322, 295-351, (1902). Ueber die Constitution der Oxoniumsalze. 1945. , (A. Werner. Zeit. Anorg. Chem. 15, 1-41, (1897). Beitrag zur Konstitution anorganischer Verbindungen. VII. Mitteilung. Ueber die Molekiilargrosse anorganischer Salze.) [Inorganic] A. Werner. Zeit. Anorg. Chem. 15, 123-142, (1897), see under Fassbender. 1946. A. Werner. Zeit. Anorg. Chem. 21, 201-242, (1899). Meas. W. Spruck. Beitrag zur Konstitution anorganischer Verbindungen. XVIII. Mitteilung. Ueber Aethylendiamin- und Propylendiaminverbindungen von Salzen zwei- wertiger MetaUe. [Same as 1644.] 1947. A. Werner. Zeit. Anorg. Chem. 22, 91-157, (1900). fjlMeas. R. Klien. Beitrag zin- Konstitution anorganischer Verbindungen. XV. Mitteilung. Ueber rhodanatokobaltiake und strukturisomere Salze. 1948. A. Werner, C. Herty. Zeit. Phys. Chem. 38, 331-352, (1901). Beitrage zur Konstitution anorganischer Verbindungen. T = 25°. 1949. A. Werner, E. Humphrey. Ber. Deutsch. Chem. Ges. 34, 1719-1732, (1901). Ueber stereoisomere Dinitritodiaethylendiaminkobaltsalze. [Same as 863. ] 1950. (A. Werner, A. Miolati. Zeit. Phys. Chem. 12, 35-55, (1893). Beitrage zur Konstitution anorganischer Verbindimgen.) 1951. (A. Werner, A. Miolati. Zeit. Phys. Chem. 14, 506-521, (1894). Beitrage zur Konstitution anorganischer Verbindungen.) 1952. A. Wesch. Dis. Freiburg. (1908). Ueber Chromsaurederivate. [Same as 1487. ] T = 18°. R. O. 7<:aq.= 5.8X10-8. Meas. A. Wesch; see 1487. 1953. A. P. West. Dis. Johns Hopkins. (1905). A study of the effect of temperature on dissociation and on the temperature coefHcients of conductivity in aqueous solutions. [Same as 924. ] A. P. West see H. C. Jones. 1953a. A. P. West, H. C. Jones. Am. Chem. Jour. 44, 508-544, (1910). The conductivity, dissociation and temperature coefficients of conductivity at 35°, 50° and 65° of aqueous solutions of a number of salts. T = 35°, 50°, 65°. S. U. 1954. C. A. West. Jour. Chem. Soc. 77, 705-707, (1900). The dissociation constant of azoimide (hydrazoic acid). T=25°. S. U. xaq.= 5.85X10-6; sub. Meas. Westhausser; see 1032. E. Wheeler see H. E. Armstrong. P. Wheeler see G. N. Lewis. 1965. (W. C. D. Whetham. Chem. News. 98, 98-100, (1908). The electrolytic properties of dilute solutions of sulphuric acid.) [Given in 1967.] 534 AUTHOR LIST 1966. W. C. D. Whetham. Phil. Mag. (5), 38, 392-396, (1894). On the velocities of ions and the relative ionization-power of solvents. 1957. W. C. D. Whetham. Phil. Mag. (6), 44, 1-9, (1897). The ionizing power of solvents. T = 18° and 60°. C. Cx. S. units. 1958. (W. C. D. Whetham. Phil. Mag. (6), 5, 279-290, (1903). The theory of electrolytic dissociation.) 1969. W. C. D. Whetham. Zeit. Phys. Chem. 33, 344-352, (1900). Die Dissociation verdtinnter Losungen beim Gefrierpunkte. [Same as 1960. Given in 1963.] T = 0°. C. G. S. units, x aq. sub. 1960. W. C. D. Whetham. Proc. R. Soc. London. 66, 192-203, (1899-1900). The ionisation of dilute solutions at the freezing-point. [Same as 1969. Given in 1963.] 1961. (W. C. D. Whetham. Proc. R. Soc. London. 71,332-338,(1902-1903). The electrical conductivity of solutions at the freezing-point of water.) [In- organic. ] 1962. W. C. D. Whetham. Trans. R. Soc. London. A, 186, 507-522, (1895). On the velocities of ions. T = 16°tol8°. C.G.S. units. 1963. W. C. D. Whetham. Trans. R. Soc. London. A, 194, 321-360, (1900). The ionization of dilute solutions at the freezing point. [Same as 1959 and 1960 with one additional table of A of K3Pe(CN)6.] T = 0°. C. G. S. units, xis aq. about 0.9 X 10~^; sub. except in one table. 1964. (W. C. D. Whetham, H. H. Paine. Chem. News. 98, 118-120, (1908). The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic. Given in 1967.] 1966. (W. C. D. Whetham, H. H. Paine. Chem. News. 98, 127-130, (1908). The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic. Given in 1967.] 1966. (W. C. D. Whetham, H. H. Paine. Chem. News. 98, 158-159, (1908). The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic. Given in 1967.] 1967. (W. C. D. Whetham, H. H. Paine. Proc. R. Soc. London. A, 81, 58-80, (1908-1909). The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic. Same as 1955, 1964, 1965 and 1966 together.] W. H. Whitcomb see A. A. Noyes. 1968. G. F. White, H. C. Jones. Am. Chem. Jour. 42, 520-541, (1909). The effect of temperature and dilution on the conductivity of organic acids in aqueous solution. T=0''to35°. S. U. X26aq.=1.2-1.7X10-«. 1968a. G. F. White, H. C. Jones. Am. Chem. Jour. 44, 159-199, (1910). The conductivity and dissociation of organic acids in aqueous solution at different temperatures. T=0°to35°. S. U. J. White see E. J. Constam. R. Whymper see R. J. Caldwell. 1969. G. Wicke. Dis. Erlangen. (1898). Beitrag zur Kenntnis des Pulegons und Menthons. Hg. U. Meas. P. Wiegner; see 738. Meas. J. Wigger; see 820. A. Wild see L. Relet- Jolivet. AUTHOR LIST 535 1970. M. ■WUdermann. Zeit. Phys. Chem. 14, 231-246, (1894). Die methode von Kohlrausch in ihrer Anwendung zur Untersuchung der elek- trischen Leitfahigkeit schwach dissociierter Stoffe. T = 18°. S. U. 1971. M. "Wildermann. Zeit. Phys. Chem. 14, 247-271, (1894). Ueber eine weitere Methode zur Bestimmung der elektrischen Leitfahigkeit schwach dissociierter Stoffe. T=25°±0.05°. X25aq. =2.83X10-°. 1972. M. Wildermann. Zeit. Phys. Chem. 15, 337-357, (1894). Der experimentelle Beweis der van't Hoffschen Konstante, des Arrheniusschen Satzes, des Ostwaldschen Verdiinnungsgesetzes in sehr verdtinnten Losungen. 1973. M. Wildermann. Zeit. Phys. Chem. 19, 233-250, (1896). Experimenteller Beweis der van't Hoffschen Konstante, des Arrheniusschen Satzes, des Ostwaldschen Verdunnungsgesetzes, des Daltonschen Gesetzes u. s. w. in sehr verdiinnten Losungen. 1973a. E. G. Willcock. Jour. Physiol. 37, 27-36, (1908). Crystalline egg-albumin. R. S. Willows see A. E. Garrett. 1974. R. Willstatter. Ber. Deutsch. Chem. Ges. 28, 3271-3292, (1895). Meas. V. Rothmund. Ueber die Aufspaltung der Tropinsaure. [Same as 1977.] 1975. R. Willstatter. Ber. Deutsch. Chem. Ges. 31, 1534-1553, (1898). Meas. V. Rothmund. TJeber die Constitution der Spaltungsproducte von Atropin und Cocain. T = 25° R. O. 1976. R. Willstatter. Ber. Deutsch. Chem. Ges. 32, 1635-1641, (1899). Meas. V. Rothmund. Ueber einige Derivate des Ecgonins. T = 25°. R. O. X aq. sub. 1977. R. Willstatter. Habilitschr. Munchen. (1896). Meas. V. Rothmund. Untersuchungen in der Tropingruppe. [Same as 1974.] 1978. R. WiUstatter, C. Hollander. Ann. Chemie. 326, 79-90, (1903). Meas. V. Rothmund. Synthese der Ecgoninsaure. [Same as 843.] T=25°. 1979. R. WiUstatter, R. Lessing. Ber. Deutsch. Chem. Ges. 35, 2065-2073, (1902). Meas. V. Rothmund, and Drucker. Ueber N-Methylpyrrolidin-ai-ardicarbonsaure. [Same as 1074 with cor- rections. ] T=25°. R. O. 1980. E. Wilson. Proc. R. Soc. London. 71, 241-243, (1902-1903). Some dielectric properties of solid glycerine. T=-81° to 4-13°. 1981. F. P. Wilson. Dis. Johns Hopkins. (1899). Meas. B. P. Caldwell. I. Orthosulphaminebenzoic acid. II. Orthocarbaminebenzenesulphonic acid. T=25°. 1982. (J. H. Wilson. Am. Chem. Jour. 35, 78-84, (1906). Some concentration cells in methyl and ethyl alcohols.) [Inorganic and quoted. ] 1983. T. M. WUson. Am. Jour. Physiol. 16, 438-467, (1906). On the comparison of conductivity and freezing points of small quantities of body fluids in health and disease. 536 AUTHOR LIST 1984. K. Winkelblech. Zeit. Phys. Chem. 36, 546-695, (1901). TJeber amphotere Elektrolyte und innere Salze. [Same as 1986. ] T = 25°. S. U. X aq. less than 3X10-«; sub. 198B. K. Winkelblech. Dis. Leipzig. (1901). Ueber amphotere Elektrolyte und innere Salze. [Same as 1984.] Meas. K. Winkelblech; see 268. Meas. H. Wislicemis; see 66, 868, 1669, 1671, 1673, 1674. 1986. L. Wohler. Ber. Deutsch. Chem. Gea. 38, 1351-1359, (1905). Die Molekulargrosse der Knallsaure. T=0° R. O. X aq. = 1.73XlO-8; not sub. P. Wohler see W. Kerp. 1987. J. Woelfer. Ann. Physik. (3), 57, 91-111, (1896). Die Siedepunktserhohung von einigen aethyl- und methylalkoholischen Salz- losungen. [Part is same as 1988. ] Hg.U. 1988. J. Woelfer. Dis. Halle. (1894). Ueber die Erhohung des Siedepunktes von absolutem Alkohol durch Losung einiger Salze. [Given in 1987. ] 1989. (A. WSrmann. Ann. Physik. (4), 29, 194-200, (1909). Die Temperaturkoeffizienten der elektrischen Leitfahigkeit einiger Sauren und Basen in wasseriger Losung.) [Inorganic. Corrected in 1990. ] T = 0°to32°. 1990. (A. Wormann. Ann. Physik. (4), 29, 623-624, (1909). Berichtigung zu der Mitteilung " Die Temperaturkoeffizienten der elektrischen Leitfahigkeit einiger Sauren und Basen in wasseriger Losung.") [Corrects' 1989.] 1991. A. Wohl. Ber. Deutsch. Chem. Ges. 40, 2282-2293, (1907). Ueber Oxyfumar- und Oxymaleinsaure. [Corrects 926.] 1992. A. Wohl, P. Claussner. Ber. Deutsch. Chem. Ges. 40, 2308-2312, (1907). Messungen an der Oxymalein- und Oxyfimiarsaure. t = 17°. 1993. H. Wolf. Zeit. Elektrochem. 8, 117-119, (1902). Zur Kenntnis der Leitfahigkeit von Losungen gemischter Elektrolyte. [Qual- itative. Given with complete data in 1994. ] 1994. H. Wolf. Zeit. Phys. Chem. 40, 222-255, (1902). Beitrag zur Kenntnis der Leitfahigkeiten gemischter Losungen von Elektro- lyten. T =25° ±0.05°. :«aq.=2.0XlO-^ 1995. J. K. Wood. Jour. Chem. Soc. 83, 568-578, (1903). The affinities of some feebly basic substances. [Same as 1998.] T = 40.2°. 1996. J. K. Wood. Jour. Chem. Soc. 89, 1831-1839, (1906). The acidic constants of some ureides and uric acid derivatives. T=25° R. O. X26aq. not over 1.5 XlO-«. 1997. J. K. Wood. Jour. Chem. Soc. 89, 1839-1847, (1906). The affinity constants of xanthine and its methyl derivatives. T = 40.1°and25°. 1998. J. K. Wood. Proc. Chem. Soc. 19, 67-68, (1903). The affinities of some feebly basic substances. [Same as 1996.] 1999. (J. K. Wood. Proc. Chem. Soc. 22, 271, (1906). The acidic constants of some ureides and uric acid derivatives.) [No data. ] ' AUTHOR LIST 537 2000. (J. K. Wood. Proc. Chem. Soc. 22, 271-272, (1906). The aflBnity constants of xanthine and its methyl derivatives.) [No data. ] J. K. Wood see J. Walker. 2001. (R. W. Wood. Am. Chem. Jour. 15, 663-670, (1893). The action of salts on acids.) 2002. R. W. Wood. Am. Chem. Jour. 16, 313-325, (1894). The affinity constants of weak acids and the hydrolysis of salts. [T = 55°?] 2003. R. W. Wood. Phil. Mag. (5), 41, 117-120, (1896). On the dissociation degree of some electrolytes at 0°. [Same as 2004.] T=0°and25°. S. IT. x aq. sub. 2004. R. W. Wood. Zeit. Phys. Chem. 18, 521-523, (1895). Notiz liber den Dissociationsgrad einiger Elektrolyte bei Null Grad. [Same as 2003.] T=0° and 25° S. U. x aq. sub. 2005. T. B. Wood, W. B. Hardy. Proc. R. Soc. Soc. London. B, 81, 38-43, (1908-1909). Electrolsrtes and colloids. The physical state of gluten. B. E. Woolley see H. Henstock. 2006. R. G. Wright. Dis. Basel. (1902). Zur Kenntnis des Auramins G. T = 0°and25°. Z. 2007. U. Zanninowich Tessarin. Gaz. Chim. Ital. 26, 1, 311-323, (1896). Dissociazione elettrolitica delle soluzioni in acido formico. [Same as 2008. ] T = 25°. 2008. H. Zanninovich-Tessarin. Zeit. Phys. Chem. 19, 251-260, (1896). Elektroljrtische Dissociation der Losungen in Ameisensaure. [Same as 2007.] 2009. J. V. Zawidzki. Ber. Deutsch. Chem. Ges. 36, 3325-3337, (1903). Ueber den amphoteren Charakter der Kakodylsaure. [Corrected in 2010. ] T=25°and0°. S. U. x aq. sub. 2010. J. V. Zawidzki. Bar. Deutsch. Chem. Ges. 37, 153-154, (1904). Ueber den amphoteren Charakter der Kakodylsaure. [A correction of 2009. ] 2011. J. V. Zawidzki. Ber. Deutsch. Chem. Ges. 37, 2289-2298, (1904). Ueber die basischen Eigenschaften der Kakodylsaure und des Hamstoffs. [See 739.] T = 25° 2012. (J. V. Zawidzki. Ber. Deutsch. Chem. Ges. 37, 2298-2301, (1904). Zur Theorie der Pseudosauren.) 2013. J. V. Zawidzki. Zeit. Phys. Chem. 42, 612-616, (1902-1903). Ueber Saponinschaum. T=25° S. U. X aq. probably sub. Meas. J. V. Zawidzki; see 1832. B. Zdanowski see J. Kowalski. 2014. F. Zecchini. Gaz. Chim. Ital. 23, II, 601-607, (1893). Esperienze sul potere rotatorio della coniina e dei suoi sali. [Same as 2015. ] T=25°. 2015. F. Zecchini. Rend. Accad. Lincei. (5), 2, II, 168-173, (1893). Esperienze sul potere rotatorio, etc. [Same as 2014. ] Zelinskij see Zelinsky. 2016. N. Zelinsky. Ber. Deutsch. Chem. Ges. 24, 3997-4005, (1891). Ueber die stereoisomeren Dimethyladipinsauren und Dimethylpimelinsauren. 538 AUTHOR LIST 2017. N. Zelinsky. Ber. Deutsch. Chem. Ges. 29, 616-«18, (1896). Zur Kenntnisa der stereoisomeren Dimethyltricarballylsauren. 2018. N. Zelinsky. Jour. Russ. Phys.-chem. Soc. 23, 612-632, (1891). Electrolytic conductivity of aqueous solutions of stereoisomeric acids and their mixtures. T = 25°. 2019. (N. D. Zelinsky. Jour. Russ. Phys.-chem. Soc. 26, 608-611, (1894).) [No title. A report on the electrolysis of potassium salts of nitro-organic compounds. ] 2020. (N. D. Zelinsky. Jour. Russ. Phys.-chem. Soc. 26, 611-612, (1894).) [No title. A report on the electrolysis of sodium salts of nitromethane. ] Meas. N. Zelinsky; see 1217. 2021. N. Zelinsl^, A. Besredka. Ber. Deutsch. Chem. Ges. 24, 459-478, (1891). Ueber das gegenseitige Verhalten der Dimethylglutar- und Trimethylbern- steinsauren und iiber die stereoisomeren Trimethylbemsteinsauren. [Same as 2022.] 2022. N. Zelinsky, A. Besredka. Jour. Russ. Phys.-chem. Soc. 23, 126-147, (1891). Of the mutual relation of isomeric dimethylglutaric and trimethylsuccinic acids and of stereoisomeric trimethylsuccinic acids. [Same as 2021.] 2023. N. Zelinsky, L. Buchstab. Ber. Deutsch. Chem. Ges. 24, 1876-1880, (1891). Ueber stereoisomere Phenylmethylbemsteinsauren. 2024. N. Zelinsky, A. Generosow. Ber. Deutsch. Chem. Ges. 29, 729-733, (1896.) Untersuchungen in der Hexamethylenreihe. 2026. N. Zelinsky, W. Isajew. Ber. Deutsch. Chem. Ges. 29, 819-820, (1896). Ueber stereoisomere Dimethyldioxyadipinsauren. 2026. N. Zelinsky, N. Izgarygev. Jour. Russ. Phys.-chem. Soc. 40, 1379- 1388, (1908). The electrolytic dissociation constants of cycloparaffin acids. 2027. (N. Zelinsky, S. Krapiwin. Jour. Russ. Phys.-chem. Soc. 28, 414- 416, (1896). On the electroljrtic condition of some salts and some acids in methyl-alcohol.) [This is a report of 2028. ] 2028. N. Zelinsky, S. Krapiwin. Jour. Russ. Phys.-chem. Soc. 28, 579-593, (1896). On the electrolytic state of solutions of salts and some acids in methyl alcohol. [Same as 2029.] T = 25°. ;'caq. sub. ^ 2029. N. Zelinsky, S. Krapiwin. Zeit. Phys. Chem. 2J, 35-52, (1896). Ueber den elektrolytischen Zustand der Losungen von Salzen und einiger Sauren in Methylalkohol. [Same as 2028. ] Meas. Zengelis; see 80. 2030. T. Zincke. Ann. Chemie. 296, 135-158, (1897). Meas. F. Kuster. Ueber die Einwirkung von Chlor auf o-Amidophenole und o-Diamine. [Same as 1028.] 2031. L. Zlobicki. Bui. Acad. Cracov. (1907), 1009-1016. Ueber den Einiluss des Radiums auf die elektrolytische Leitfahigkeit kol- loidaler Losungen. [The organic solvents used were not chemically pure.] T = 18°to24°. R. O. AUTHOR LIST 539 2032. L. Zoja. Zeit. Chem. Ind. KoUoid. 3, 249-269, (1908). Physikalisch-chemische Untersuchungen der Reaktionen zwischen Eiereiweisa und Essigsaure. T = 16°, 25''and42°. A. Zoso see P. B. DaMonte. SUBJECT INDEX. In using this index, it is advisable to look through all the headings and con- sider the definitions and illustrations given, since no two persons would agree on exactly the same arrangement. In cases of doubt, and in cases open to legitimate difference of opinion, the reference is given under all the possible headings. For the sake of brevity, consecutive references to the same author are some- times given inclusively, thus 1-4, instead of giving each number separately. These inclusions are never used if the numbers cover more than one name. When the same measurements are published in more than one journal, the key number given here is to the most accessible article. In the author list, after the title of this article, are given references to the less accessible articles. SUBJECT INDEX. ACIDS AND THEIR SALTS. Carboxylic; as acetic and benzoic acids. Non-carboxylic; as hydrocyanic, ferrocyanic, thiocyanic; and barbituric, croconic and uric acids. a) No substituting group. CnHnOn. 1, 3, 7, 10, 11, 23, 26, 30, 43, 44, 45, 52, 60, 61, 62, 63, 65, 66, 67, 68, 69, 70, 71, 72, 76, 81, 93, 94, 105, 114, 139, 141, 145, 146a, 145b, 147a, 157, 157a, 164, 165, 168, 169, 170, 171, 172, 175, 177, 179a, 180, 188, 189, 190, 191, 196, 197, 198, 200, 201, 202, 211, 216, 220, 222, 223, 229, 231, 232, (233), 234, 235, 236, 237, 238, 244, 246, 247, 270, 274, 275, 278, 279, 280, 289, 290, 294, 295, 299, 319, 347, 354, 360, 362, 366, 370, 372, 375, 377, 378, 379, 381, 385, 386, 387, 388a, 389, 391, 397, 399, 401, 403, 408, 413, 420, 427, 430, 438, 440, 444, 449, 464, 461, 463, 466, 469, 482, 491, 494, 495, 496, 502, 603, 507, 508, 513, 515, 517, 632, 640, 542, 556, 657, 558, 659, 566, 566, 667, 568, 669, 570, 571, 571a, 672, 573, 579, 588, 591, 601, 602, 606, 619, 636, 637, 640, 642, 646, 647, 666, 682, 691, 693, 694, 698, 699, 701, 738, 760, 753, 754, 768, 782, 787, 788, 789, 793, 796, 799, 804, 810, 813, 814, 817, 823, 826, 827, 828, 838, 848, 860, 861, 865, 875, 881a, 889, 894, 908, 910, 911, 924,' 926, 931, 932, 934, 935, 943, 946, 951, 956, 968, 966, 966, 986, 991, 993, 995, 997, 1003, 1004, 1011, 1017, 1018, 1023, 1029, 1030, 1031, 1033, 1043, 1047, 1066, 1078, 1086, 1088, 1094, 1102, 1103, 1104, 1105, 1111, 1122, 1123, 1126, 1138, 1143, 1144, 1160, 1174, 1178, 1184, 1185, 1186, 1199, 1202, 1209, 1211, 1212, 1213, 1217, 1223, 1227, 1229a, 1231, 1240, 1245, 1246, 1248, 1261, 1264, 1270, 1273, 1275, 1279, 1280, 1330, 1331, 1332, 1335, 1338, 1341, 1341b, 1343, 1349, 1360, 1357- 1362, 1367, 1368, 1368a, 1369, 1370, 1371, 1372, 1373, 1380, 1386, 1386b, 1387, 1388, 1390, 1391a, 1398, 1399, 1407, 1410, 1411, 1412, 1413, 1414, 1416, 1418, 1419, 1427, 1429, 1448, 1450, 1470, 1473, 1480, 1496, 1496, 1600a, 1600b, 1608, 1518, 1619, 1620, 1533, 1637, 1539, 1643, 1644, 1645, 1546, 1647, 1654, 1562, 1663, 1569, 1673a, 1575, 1677, 1579, 1681, 1681a, 1588, 1590a, 1597, 1618a, 1620, 1630, 1635, 1636, 1638, 1639b, 1640, 1643, 1646, 1649, 1654, 1661, 1662, 1664, 1665, 1666, 1667, 1673, 1684, 1704, 1708, 1708a, 1711, 1712, 1717, 1718, 1728, 1729b, 1735, 1736, 1737, 1741, 1745, 1747, 1781, 1791, 1801, 1807, 1809, 1810, 1813, 1820, 1821, 1823, 1824, 1831, 1834, 1836, 1837, 1838, 1839, 1840, 1842, 1843, 1844, 18e3c, 1869, 1860, 1861, 1862, 1866, 1866, 1887, 1888, 1889, 1897, 1899, 1907, 1909, 1911, 1912, 1934, 1936, 1941, 1953a, 1954, 1956, 1967, 1962, 1968, 1968a, 1969, 1971, 1974, 1976, 1976, 1991, 1993, 1994, 2002, 2008, 2016-2018, 2021, 2023, 2024, 2026, 2029. 542 SUBJECT INDEX CnHnNn; as hydrocyanic acid; and CnHnOnNn; as pyridine carboxylic acid, cyanic acid and uric acid. 18, 23, 70, 77, 80, 142, 143, 145b, 175, 216, 228, 246, 316, 369, 443, 447, 448, 499, 510, 527, 652, 601, 604, 606, 607, 610, 631, 637, 683, 684, 696, 696, 701, 733, 742, 752, 756, 764, 767, 768, 782, 825, 841, 865, 907, 943, 963, 967, 1043, 1086, 1092, 1094, 1097, 1106, 1160, 1166, 1177, 1186, 1188, 1190, 1246, 1287, 1309a, 1353a, 1369, 1372, 1397a, 1422, 1428, 1461, 1645, 1646, 1654, 1747, 1748, 1814, 1840, 1843, 1853c, 1865, 1886, 1894, 1978, 1979, 1984, 1986, 1996. Metallo-cyanic acids; as ferro- and ferri-cyanic acids. 149, 160, 168, 220, 313, 372, 376, 468, 610, 604, 606, 689, 690, 839, 889, 901, 903, 907, 924, 943, 971, 1024, 1338, 1362, 1434a, 1486, 1494, 1617, 1709, 1832, 1836, 1837, 1953a, 1969. Thiocyanic. 216, 217, 468, 471, 474, 478, 482, 487, 491, 606, 681, 793, 820, 911, 922, 943, 990, 993, 1004, 1007, 1066, 1067, 1070, 1106, 1162, 1163, 1164, 1192, 1276, 1337, 1362, 1392, 1470, 1526, 1527, 1673, 1641, 1747, 1752, 1826, 1832, 1844, 1866, 1944, 1947, 1948. b) Amino-, anUino-, imino- etc., including acids with substitution of H in the NH2 or NH group; as, aminoacetic acid CH2(NH2).C02H, anilinobutyric acid Et.CH(NHPh).C02H, acetylamino-acetic acid (MeCO)NH.CH2.C02H. 23, 30, 79, 142, 143, 146a, 145b, 164, 166, 167, 170, 175, 177, 186a, 191, 195, 228, 268, 271, 302a, 316, 360, 414, 439, 443, 466a, 492, 496, 499, 604, 619, 622, 523, 627, 590, 601, 606, 637, 646, 846, 864, 856, 890, 947, 948, 963, 1027, 1029, 1086, 1087, 1134, 1160, 1157, 1158, 1184, 1186, 1227, 1233, 1243, 1245, 1318, 1334, 1353a, 1367, 1368a, 1370, 1371, 1372, 1374, 1397a, 1407, 1508, (1667), 1663, 1590, 1619, 1639b, 1669, 1673, 1682, 1684, 1718, 1720, 1749, 1773, 1774, 1775, 1814, 1817, 1824, 1838, 1840, 1868, 1874, 1913, 1914, 1915, 1968, 1968a, 1978, 1979, 1981, 1984, 1996. c) Complex. These complexes, formed (for the most part) by the combination of organic and inorganic compounds, are chiefly of the types established by Wer- ner, Tschugaeff and others. In most cases, only the salts are known. 88, 89, 149, 246, 247, 320a, 320b, 427, 560, 691, 692, 708, 756, 786, 816, 938, 1023, 1050, 1086, 1094, 1095, 1096, 1097, 1162, 1163, 1164, 1192, 1198, 1269, 1386, 1463, 1485, 1487, 1494, 1495, (1514), 1616, 1616, 1517, 1618, 1619, 1620, 1521, 1527, 1530a, 1560, 1572, 1573, 1577, 1681a, 1641, 1648, 1709, 1711, 1721, 1750- 1757, 1759, 1760a, 1761. d) Cyano; as cyanoacetic acid CH2(CN).C02H. 226, 294, 296, 647, 698, 699, 754, 768, 943, 1296, 1296, 1370, 1371, 1390, 1820, 1821, 1831, 1897. SUBJECT INDEX 543 e) Halogen; as bromoacetic acid CHzBr.COaH. 23, 43, 63, 79, 157, 157a, 176, 220, 223, 270, 291, 294, 296, 297, 335, 336, 347, 370, 371, 372, 404, 441, 448, 449, 460, 461, 474, 476, 492, 515, 541, 558, 577, 584, 602, 606, 647, 654, 656a, 667, 693, 709, 727, 728, 729, 760, 754, 782, 823, 838, 846, 849, 859, 877, 911, 932, 939, 943, 951, 1011, 1018, 1021, 1084, 1094, 1099, me, 1134, 1184, 1186, 1186, 1223, 1264, 1263, 1286, 1299, 1317, 1367, 1368, 1368a, 1370, 1371, 1372, 1416, 1435, 1436, 1437, 1439, 1499, 1508, 1563, 1579, 1681, 1638, 1643, 1690, 1691, 1693, 1694, 1696, 1700, 1701, 1717, 1718, 1728, 1748, 1820, 1824, 1827, 1831, 1833, 1834, 1838, 1840, 1841, 1842, 1844, 1866, 1897, 1908, 1909, 1911, 1930, 1957, 1970, 1971, 1972, 1973, 1994, 2004, 2008, 2029, 2030. f) Hydroxy- with their ethers; as glycollic acid CH2(OH).C02H and methoxy-acetic acid CH2(OMe).C02H. 11, 23, 30, 46, 64, 70, 93, 94, 145a, 160, 164, 165, 168, 169, 170, 171, 175, 179, 192, 193, 194, 200, 202, 220, 223, 226, 229, 270, 274, 300, 305a, 309, 319, 320a, 320b, 360, 366, 371, 372, 377, 378, 387, 388a, 389, 394, 395, 404, 418, 430, 447, 448, 449, 463, 473, 474, 482, 492, 495, 616, 625, 527, 532, 541, 542, 558, 574, 688, 606, 617, 640, 643, 647, 657, 691, 692, 693, 701, 705, 727, 728, 729, 742, 754, 782, 804, 809, 812, 823, 827, 848, 853, 889, 910, 911, 934, 938, 943, 947, 966a, 966, 1023, 1034, 1055, 1090, 1091, 1094, 1122, 1134, 1182, 1184, 1185, 1186, 1189, 1199, 1202, 1215, 1223, 1231, 1239, 1248, 1249, 1261, 1262, 1276, 1316, 1317, 1345, 1357, 1362, 1365, 1367, 1368, 1368a, 1370, 1371, 1372, 1407, 1411, 1418, 1429, 1454, 1463, 1466, 1466, 1468, 1473, 1476, 1492, 1493, 1496, 1496, 1608, 1618, 1519, 1621, 1542, 1564, 1562, 1563, 1569, 1581, 1689, 1629, 1633, 1635, 1638, 1640, 1643, 1648, 1649, 1670, 1672, 1684, 1704, 1706, 1718, 1719, 1734, 1735, 1736, 1747, 1781, 1820, 1821, 1823, 1824, 1825, 1836, 1838, 1839, 1842, 1869, 1866, 1899, 1906, 1907, 1909, 1911, 1932, 1941, 1968, 1968a, 1969, 1970, 1991, 1992, 1994, 2018, 2025. g) Nitro and nitroso; as nitrobenzoic acid NO2.C6H4.CO2H and nitroso or oximino-acetic acid H.C:N0H.C02H. 30, 175, 194, 456a, 492, 615, 626, 602, 606, 607, 637, 647, 656, 660a, 754, 766, 768, 772, 844, 845, 849, 911, 943, 960, 1092, 1094, 1186, 1186, 1296, 1296, 1342, 1366, 1366, 1367, 1368a, 1370, 1371, 1390, 1608, 1663, 1581, 1627, 1684, 1718, 1748, 1781, 1820, 1836, 1838, 1840, 1906, 1909, 1932, 1938, 1972, 1973. h) Acids containing sulphur; as benzene sulphiaic acid Ph.S02H, phenol sulphonic acid HO.CeHi.HSOs, thioacetic acid Me.COSH. Thiocyanic acid has been given under a separate heading. 18, 23, 54, 70, 143, 149, 157, 176, 186a, 220, 270, 394, 423, 431, 466a, 492, 495, 604, 606, 607, 636, 637, 643, 645, 660a, 731, 754, 768, 774, 781, 782, 818, 850, 851, 852, 853, 864, 856, 949, 950, 959, 972, 976a, 1090, 1111, 1133, 1134, 1346, 1357, 1366, 1367, 1370, 1372, 1385, 1401, 1402, 1465, 1466, 1467, 1508, 644 SUBJECT INDEX 1523, 1629, (1557), 1562, 1574, 1630, 1718, 1721, 1748, 1770, 1773, 1774, 1796, 1811, 1836, 1841, 1842-1844, 1909, 1911, 1940, 1968, 1968a, 1981, 1984. i) Unclassified. 142, 305a, 606, 683, 684, 733, 738, 752, 754, 756, 767, 768, 769, 773, 782, 888, 948, 976c, 1053, 1054, 1094, 1118, 1119, 1120, 1188, 1353a, 1563, 1676a, 1697, 1720, 1748, 1771, 1837, 1996. ALCOHOLS; as ethyl alcohol Et.OH. 18, 20, 21, 29, 30, 34, 45, 58, 74, 101, 105, 107, 110, 133, 145b, 147a, 263, 289, 290, 301, 305, 322, 335, 337, 338, 343, 344, 347, 361, 362, 366, 385, 391, 392, 418, 425, 433, 438, 445, 466, 466, 478, 491, 512, 532, 580, 582, 597, 606, 637, 647, 656a, 741, 760, 754, 760, 764, 770, 783, 787, 799, 806, 816, 840, 842, 887, 904, 908, 912, 916, 917, 918, 920, 922, 941, 943, 944, 955, 956, 976, 979, 986, 1010, 1021, 1035, 1036, 1051, 1098, 1106, 1107, 1108, 1110, 1160, 1177, 1179, 1180, 1181, 1183, 1189, 1222, 1269b, 1279, 1316, 1344, 1364, 1388, 1390, 1419-1421, 1423a, 1434, 1434a, 1462, 1464a, 1470, 1472, 1497, 1609, 1618, 1634, 1666, 1569, 1579, 1680, 1682, 1689, 1590a, 1692, 1614, 1620, 1627, 1649, 1661, 1696, 1724, 1746, 1763, 1766, 1777, 1791, 1800, 1807, 1815, 1829, 1842-1844, 1849, 1853a, 1884, 1897, 1900, 1903a, 1970, 1971, 1980, 1987, 1994, 2029, 2031. ALDEHYDES; as acetaldehyde Me.CHO. 16, 58, 78, 602, 612, 517, 628, 529, 532, 633, 638, 606, 607, 637, 643, 663, 741, 760, 784, 941, 943, 969, 961, 962, 1106, 1107, 1388, 1608, 1663, 1569, 1690a, 1654, 1718, 1719, 1741, 1842-1844, 1847, 1853a, 1897. AMIDES; as acetic acid amide Me.C0NH2. 17, 33, 70, 102, 141, 143, 145, 145a, 149, 211, 214a, 285, 286, 332, 410, 412, 662, 663, 604, 606, 606, 607, 610, 637, 660, 726, 745, 748, 750, 764, 767, 761, 779, 781, 782, 943, 963, 1008, 1051, 1094, 1096, 1097, 1166, 1243, 1289b, 1318, 1371, 1372, 1479, 1606d, 1624, 1626, 1530, 1676, 1646, 1684, 1729, 1741, 1747, 1748, 1791, 1842-1844, 1853b, 1853c, 1864, 1880, 1890, 1894, 1897, 1904, 1944, 1981, 1983, 1984, 1996, 1996, 2011. ANHYDRIDES AND LACTONES. 1, 3, 7, 202, 211, 223, 360, 414, 443, 523, 579, 606, 701, 733, 741, 750, 764, 864, 890, 1029, 1030, 1031, 1186, 1249, 1262, 1493, 1600a, 1600b, 1644, 1646, 1662, 1690a, 1810, 1823, 1838, 1839, 1840, 1843, 1844, 1975, 1984, 1991, 2018. ANILIDES etc.; as acetanilide. 638, 606, 637, 1995. SUBJECT INDEX 545 BASES CONTAINING NITROGEN, AND THEIR SALTS. a) No substituting group; as ethyl amine and aniline. 19, 27, 32, 33, 44, 69, 76, 86, 98a, 102, 103, 146a, 146b, 166, 169, 177, 186, 269, 270, 271, 286, 286, 299a, 303, 304, 306, 314, 336, 336, 347, 360, 393, 401, 402, 406, 409, 420, 426, 426, 428, 434, 436, 439, 478, 486, 492, 604, 610, 611, 613, 620, 632, 648, 684, 693, 699, 606, 606, 610, 637, 646, (649), 660, 660, 664, 706, 734, 740, 741, 747, 748, 750, 753, 754, 769, 763, 764, 767a, 770, 776, 779, 786, 817a, 822a, 833, 882, 923, 936, 936, 943, 977, 979, 1011, 1057, 1075, 1084, 1093, 1106, 1116, 1143, 1144, 1160, 1175, 1176, 1223, 1224, 1237, 1241, 1268, 1266, 1266, 1283, 1293, 1316, 1321, 1327, 1332, 1354, 1363, 1364, 1388, 1389, 1391, 1402, 1423a, 1472, 1476, 1477, 1481, 1631, 1662a, 1663, 1662, 1669, 1571, 1576, 1578, 1590a, 1601, 1611, 1612, 1614, 1616, 1617, 1631, 1645, 1646, 1659, 1660, 1707, 1729b, 1731, 1756, 1760a, 1770, 1776, 1776, 1777, 1778, 1779, 1791, 1796, 1798, 1801, 1802, 1823, 1828, 1829, 1833, 1834, 1842, 1844, 1846-1849, 1851, 1863a, 1856, 1864, 1880, 1882, 1884, 1897, 1900, 1903, 1903a, 1996, 1997, 2006, 2014, 2029. b) Alkaloids; as brucine. 98a, 146b, 177, 270, 271, 303, 304, 426, 426, 693, 606, 650, 705, 763, 764, 776, 943, 948, 979, 1106, 1223, 1224, 1241, 1283, 1306, 1611, 1620, 1631, 1646, 1707, 1775, 1776, 1778, 1779, 1842, 1864, 1897, 1978, 1995, 1997, 2014. c) Complex; or in complex compounds. 59, 149, 510, 511, 620, 550, 816, 886, 943, 1008, 1076, 1384, 1416, 1417, 1481, 1482, 1622, 1530, 1672, 1760-1757, 1759, 1760a, 1761, 1762, 1946-1949. d) Halogen; as bromoaniline. 270, 271, 428, 492, 548, 584, 606, 660, 1293, 1601, 1697, 1698, 1777, 1864. e) Nitro and nitroso; as nitroaniline NO2.C6H4.NH2 and nitroso-methyl- aniline NO.C6H4.NHMe. 102, 492, 548, 583, 604, 606, 610, 637, 669, 660a, 733, 736, 764, 767, 782, 1094, 1116, 1802, 1843, 1844, 1863c, 1864, 1897, 1996. f) Containing sulphur; as thiourea. 149, 177, 271, 350, 748, 943, 1008, 1302, 1363, 1402, 1524, 1526, 1549, 1748, 1826, 1864, 1880. g) Unclassified. 501, 648, 733, 948, 1083, 1093, 1266, 1601, 1660, 1687, 1707, 1777, 1995, 1997. 546 SUBJECT INDEX CARBOHYDRATES. 46, 145b, 210a, 264, 266, 260a, 322, 324, 392, 632, 688, 690, 593, 694, 595, 606, 637, 641, 686, 741, 783a, 1036, 1036, 1039, 1108, 1110, 1160, 1177, 1209a, 1220, 1222, 1364, 1381, 1383, 1468, 1478, 1497, 1669, 1746, 1747, 1843, 1983. DIAZO-COMPOUNDS. 77, 142, 143, 318, 426, 600, 601, 631, 635, 730, 731, 736, 736, 737, 766, 774, 779, 1601, 1720. DILUTION LAW. 15, 84, 478, 483, 485, 488, 647, 837, 989, 994, 1046, 1100, 1300, 1386a, 1483, 1538, 1660, 1675, 1863, 1918, 1940. DYES. The references indexed here include both conductivity and all other measure- ments. 75, 85, (87), 146, 186, 186a, 326, 416, 606, (634b), 636, 637, 667, 660, 734, 741, 763, 770, 833, 882, 943, 976a, 976c, 1265, 1266, 1321, 1401, 1402, 1471a, 1476, 1661, 1662, 1668, 1671, 1614, 1616, 1617, 1706a, 1729a, 1730, 1731, 1796, 1798, 2006. ESTERS. 16, 18, (38), 70, 106, 141, 143, 146a, 146b, 149, 175, 226, 236, 236, 237, 244, 270, 285, 286, 289, 306, 360, 354, 360, 366, 387, 404, 414, 418, 439, 447, 448, 478, 483, 626, 627, 678, 606, 610, 661, 662, 666, 666, 667, 668, 698, 699, 700, 746, 748, 750, 754, 766, 757, 762, 766, 768, 774, 782, 799, 844, 854, 869, 887, 890, 939, 941, 943, 960, 966a, 966, 967, 1061, 1092, 1097, 1106, 1107, 1111, (1114), 1188, 1223, 1233, 1246, 1296, 1296, 1298, 1311, 1366, 1366, 1371, 1372, 1388, 1390, 1397a, 1428, 1470, 1623, 1530, 1569, 1588, 1590, 1694, 1646, 1666, 1657, 1660, 1666, 1684, 1776, 1777, 1779, 1814, 1816, (1818), 1823, 1829, 1830, 1831, 1834, 1838, 1842-1844, 1846, 1847, 1849, 1863a, 1858, 1869, 1860, 1864, 1879, 1888, 1889, 1897, 1907, 1909, 1914, 1916, 1930, 1932, 1934, 1936, 1938, 1941. ETHERS; of alcohols, as ethyl ether Et.O.Et; and of phenols, as anisidine WH2.C6H4.OMe. 33, 45, 70, 133, 273, 305, 360, 362, 366, 601, 631, 534, 636, 536, 548, 606 607, 643, 736, 746, 750, 760, 816, 887, 943, 986, 1010, 1061, 1098, 1316, 1344, 1421, 1446, 1447, 1608, 1666, 1569, 1696, 1601, 1646, 1718. 1777, 1805, 1842-1844, 1847, 1867, 1893, 1897, 2031. FLAMES. Conductivity of flames containing organic compounds. 682. SUBJECT INDEX 547 FLUORESCENCE. Effect of fluorescence on conductivity. 325, 833, 859a, 1321, 1471a, 1476. GUMS, OILS, RESINS, WAXES etc. Ill, 124, 131, 146b, 606, 931, 1010, 1471, 1491. HALOGEN DERIVATIVES OF ACIDS; as acetyl chloride. 1842-1844, 1893, 1897. HYDROCARBONS. a) No substituting group. 105, 107, 133, 147a, 181, 182, 211, 263, 273, 301, 305, 383, 384, 386, 417, 500, 606, 637, 669, 671, 672, 673, 842, 859a, 872, 873, 873a, 895, 902, 935, 936, 941, 943, 978, 983a, 1010, 1021, 1098, 1223, 1234, 1314, 1344, 1388, 1491, 1566, 1569, 1604, 1606, 1829, 1830, 1842, 1883, 1893, 1897, 2031. b) Halogen; as chlorobenzene and ethyl iodide. 27, 73, 211, 291, 305, 334, 386, 634, 604, 606, 637, 668, 669, 740, 767a, 775, 780, 796, 840, 872, 943, 1223, 1260, 1329, 1388, 1437, 1464, 1477, 1669, 1676, 1733, 1829, 1830, 1842, 1893, 1897. c) Nitro; as nitrobenzene. 105, 149, 291, 517, 604, 606, 607, 610, 637, 683, 684, 752, 754, 771, 772, 775, 780, 782, 795, 796, 844, 923, 941, 1092, 1094, 1106, 1107, 1223, 1388, 1423a, 1426, 1464, 1663, 1669, 1690a, 1646, 1686, 1843, 1844, 1863a, 1897. d) Containing sulphur; as thiophene. 1388, 1897. IMIDES ; as succinimide. 149, 318, 606, 607, 610, 637, 754, 781, 963, 1029, 1032, 1085, 1094, 1095, 1096, 1097, 1143, 1750, 1762, 1765, 1773, 1838, 1996. INDICATORS ; as phenolphthalein. 57, 70, 186, 268, 278, 299, 325, 332, 473, 496, 624, 532, 560, 590, 693, 694, 595, 606, 618, 637, 724, 733, 746, 750, 803a, 818, 822, 833, 847, 882, 936, 943, 950, 1116, 1143, 1144, 1150, 1160, 1230, 1250, 1251, (1269a), 1260, 1266, 1266, 1275, 1321, (1332a), 1381, 1402, 1471a, 1476, 1606, 1659, 1660-1564, 1643, 1705, 1705a, 1729a, 1770, 1777, 1782, 1796, 1798, 1842, 1897, 1916, 1984. IONIZATION CONSTANT. I. Constant of second H and OH ion in polybasic acids and bases. 173, 370, 1231, 1335, 1638, 1745, 1775-1779, 1866, 1911, 1913, 1917. 548 SUBJECT INDEX II. Ionization constant of water. 46, 269, 819, 822, 949, 999, 1043, 1115, 1129, 1144, 1269, 1316, 1341, 1376, 1777. III. Measurements of the ionization constant by methods other than by the electrical conductivity of a dilute solution of the acid or the base. Most of these are measurements of the hydrolysis of salts. They are classified by the method used. a) Absorption of ammonia and of carbon dioxide. 139, 302, 302a, 661, 926. b) Elevation of the boiling-point. 292, (892), (893), 917, (1049), 1987. c) Catalysis and saponification. 16, 17, 19, 48, 177, 272, 350, 392, 409, 414, 428, (598), (651), 661, 662, 666, 666, 724, 738, 752, 854, 865, 865a, 890, 1043, 1141, 1143, 1160, (1300), 1354, (1590), 1594, 1691, 1707, 1864, 1890, 1995, 1996, 1997. d) Colorimetric. 74, 98a, 214a, 274, 278, 439, 496, 804, 822, 950, 961, 1051, 1061- 1069, 1143, 1230, 1346, 1506, 1562, 1563, 1614, 1616, 1617, 1643, 1663, 1666, 1729a, 1729b, 1730, 1773-1779, 1781, (1782), 1916. e) Electrical conductivity of salts. 177, 269, 270, 271, 350, 370, 409, 436, 436, 439, 532, 664, 1086, 1143, 1160a, 1233, 1293, 1590, 1666-1660, 1984, 2009. f) Depression of the freezing-point. 68, 177, 186, 292, 297, 408, 461, 512, 628, 629, 658, 663, (751), (893), (919), 1302, 1972, 1973, 1983, 2011. g) General and unclassified. 272, 295, 410, 412, 435, 624, 658, 693, 925, 1177, (1309), 1656- 1660, 1718, 1779, 1827, 2002, 2009, 2011. h) H ion concentration by measurement of electromotive force. 177, 343, 434. i) Optical rotation. 768, 859, 1036, 1631, 1637, 1746, 1866, 1880, 1890, 2009, 2011, j) Partition. 370, 645, 648, 683, 684, 890, 1231, 1820, 1866. k) Solubility. 428, 669, 660, 890, 967, 1116, 1997. SUBJECT INDEX 549 KETONES ; as acetone and benzophenone. 27, 45, 59, 74, 147a, 306, 334, 336, 347, 362, 387, 388, 475, 478, 487, 547, 606, 637, 669, 698, 752, 754, 756, 780, 782, 799, 844, 887, 904, 916, 918, 920, 922, 941, 943, 1035, 1051, 1056, 1070, 1092, 1106, 1137, 1141, 1143, 1296, 1298, 1323, 1386, 1388, 1423a, 1477, 1535, 1653, 1569, 1688, 1590a, 1620, 1646, 1663, 1666, 1676, 1748, 1763, 1830, 1842-1844, 1847, 1863a, 1897, 1904. LIGHT. Influence of light on conductivity. 176, 276, 325, 373, 374, 416, 471, 833, 1226b, 1226c, 1226, 1321, 1322, 1324, 1471a, 1476. MAGNETIC FIELD. Influence of magnetic field on conductivity. 160. MOLTEN SALTS. (40), (41), (42), (55), 100, 110, (166), (159), (221), (589), (674), (675), (676), (679), (711-723), 977, 983a, 1055, (1127), (1128), (1128a) (1130-1132), 1176, 1488, 1578, 1711, (1836), 1894. NEUTRALIZATION. This includes the measurement of the effect on electrical conductivity, of the addition of an acid to a base or vice versa. 165, 168, 169, 170, 171, 172, (173), 294, 295, 299, 299a, 408, 454, 463, (476a), 476, 477, 494, 496, 499, 512, 522, 523, 524, 628, 532, 653, 975, 1017, 1036, 1227, 1228, 1250, 1251, (1271), 1401, 1608, (1549), (1691), 1636, 1716, 1717, 1718, 1719, 1868. NITRILES. 33, 70, 482, 617, 531, 606, 610, 669, 683, 684, 698, 736, 763, 769, 779, 943, 1060, 1084, 1106, 1107, 1323, 1388, 1423a, 1669, 1588, 1690a, 1646, 1733, 1842-1846, 1847, 1849, 1853a, 1864, 1880, 1897, 1995. OXIMES. 70, 176, 547, (699), 604, 606, 635, 637, 663, 733, 762, 754, 768, 768, 782, 866, 1160, 1188, 1190, 1748, 1843, 1844, 1996. PHENOLS and their ethers and salts; as phenol Ph. OH, anisole Ph.OMe and sodium phenolate Ph.ONa. 27, 29, 70, 105, 147a, 166, 168, 169, 297, 299, 302, 302a, 402, 449, 460, 492, 496, 601, 512, 624, 631, 546, 547, 548, 677, 602, 604, 606, 607, 609, 614, 637, 643, 664, 655, 658, 661, 680, 729, 733, 736, 744, 746, 750, 753, 754, 756, 766, 777, 782, 789, 810, 550 SUBJECT INDEX 847, 911, 941, 943, 976a, 976c, 1017, 1042, 1043, 1071, 1116, 1144, 1160, 1160a, 1184, 1230, 1260, 1261, 1362, 1366, 1437, 1488, 1608, 1636, 1562, 1669, 1579, 1580, 1588, 1601, 1620, 1718, 1719, 1747, 1748, 1777, 1796, 1797, 1798, 1802, 1816, 1823, 1827, 1836, 1842, 1865, 1893, 1897, 1916. PHENYLHYDRAZONES; as nitro-acetaldehyde phenylhydrazone. 78, 82, 176, 546, 926. PRESSURE. Effect of pressure on conductivity. (219), 220, 642, (676), (984), (1020), (1152), (1153), (1154), 1427, 1472, 1509, (1610), 1590a, 1708, 1708a, (1710). QUINONES ; as benzoquinone and croconic acid. 389, 624, 646, 547, 577, 606, 637, 729, 758, 1050, 1275, 1562. RADIO-ACTIVITY, X- RAYS ETC. Effect on conductivity. 148, 164, (165), 216, 416, 417, 687, 834, 872, 873, 874, 1476, 1491, (1511), 1561, 1722, 1806, 2031. SALTS. a) Of acids. 10, 11, 18, 43, 45, 64, 66, 70, 93, 94, 142, 143, 146a, 146b, 149, 150, 158, 160, 164, 165, 166, 167, 168, 169, 170, 171, 172, 179, 186a, 191, 194, 216, 217, 220, 222, 223, 226, 228, 246, 247, 270, 275, 289, 294, 299, 313, 315, 319, 320a, 320b, 335, 366, 370, 372, 376, 377, 378, 379, 381, 388, 388a, 389, 391, 394, 414, 418, 423, 427, 430, 438, 443, 447, 448, 449, 454, 456a, 463, 466, 468, 469, 471, 474, 478, 482, 487, 491, 494, 495, 502, 510, 513, 616, 623, 626, 626, 632, 640, 542, 562, 656, 568, 565, 568, 571, 673, 688, 590, 601, 604, 606, 607, 610, 617, 636, 637, 642, 643, 646, 647, 656, 660a, 681, 682, 689, 690, 696, 699, 701, 706, 729, 731, 738, 742, 752, 753, 756, 764, 766, 769, 772, 773, 774, 781, 793, 796, 810, 820, 823, 825, 839, 841, 844, 848, 869, 865, 876, 881a, 889, 890, 901, 903, 907, 908, 911, 922, 924, 931, 932, 936, 943, 945, 947, 948, 949, 965, 968, 969, 963, 971, 976c, 990, 991, 993, 995, 997, 1003, 1004, 1007, 1011, 1023, 1024, 1047, 1053, 1064, 1056, 1057, 1066, 1070, 1078, 1084, 1086, 1087, 1088, 1090, 1091, 1094, 1097, 1106, 1111, 1118, 1126,. 1134, 1143, 1144, 1156, 1162, 1163, 1164, 1174, 1188, 1190, 1192, 1199, 1209, 1213, 1215, 1227, 1229a, 1273, 1276, 1276, 1279, 1280, 1296, 1296, 1309a, 1331, 1332, 1337, 1338, 1341, 1341b, 1343, 1366, 1367, 1368a, 1369, 1386, 1386b, 1388, 1390, 1392, 1398, 1402, 1416, 1427, 1434a, 1437, 1439, 1461, 1466, 1468, 1470, 1480, 1486, 1492, 1493, 1494, 1496, 1506a, 1508, 1616, 1616, 1617, 1519, 1526, 1627, 1637, 1639, 1646, 1660, 1669, 1573, 1573a, 1677, 1581, 1589, 1618a, 1620, 1633, 1640, 1641, 1646, 1648, 1654, 1690, 1693, 1694, 1696, 1700, 1701, 1709, 1711, SUBJECT INDEX 551 1717, 1718, 1720, 1728, 1734, 1735, 1736, 1737, 1747, 1748, 1749, 1752, 1791, 1796, 1807, 1809, 1823, 1826, 1832, 1834, 1836, 1837, 1838, 1839, 1841, 1844, 1856, 1886, 1894, 1940, 1944, 1947, 1948, 1953a, 1956, 1969, 1962, 1969, 1984, 1986, 1994, 2009. b) Of bases. 32, 33, 44, 85, 146a, 145b, 165, 186, 269, 270, 271, 286, 299a, 304, 314, 336, 336, 360, 401, 402, 406, 428, 434, 435, 439, 485, 613, 632, 690, 599, 606, 610, 650, 660a, 734, 738, 740, 741, 747, 763, 759, 763, 764, 767a, 770, 822a, 882, 923, 943, 948, 956a, 1011, 1075, 1083, 1086, 1093, 1143, 1144, 1224, 1237, 1266, 1266, 1266, 1293, 1327, 1388, 1402, 1423a, 1531, 1652a, 1671, 1578, 1590a, 1601, 1611, 1646, 1669, 1660, 1697, 1698, 1731, 1775-1779, 1791, 1801, 1802, 1826, 1828, 1829, 1833, 1834, 1842, 1844, 1846-1849, 1861, 1863a, 1865, 1864, 1884, 1903, 1903a, 1984, 2006, 2029. c) Complex salts and salts of complex compounds. Salts both of acids and of bases are given here, and complexes as of aluminum bromide with benzene. 59, 88, 89, 149, 246, 247, 320a, 320b, 427, 511, 520, 550, (688), 691, 692, 708, 756, 785, 816, 886, 938, 1008, 1023, 1060, 1076, 1086, 1094, 1095, 1096, 1097, 1162, 1163, 1164, 1192, 1198, 1269, 1314, 1379, 1384, 1385, 1416, 1417, 1435, 1436, 1437, 1445, 1446, 1447, 1463, 1481, 1482, 1486, 1487, 1494, 1496, (1514), 1515, 1516, 1517, 1518, 1619, 1620, 1621, 1622, 1524, 1526, 1627, 1528, 1630, 1630a, 1560, 1572, 1573, 1677, 1581a, 1641, 1648, 1709, 1711, 1750-1757, 1769, 1760a, 1761, 1762, 1944, 1946-1949. SOLUBILITY. This includes only electrical measurements of solubility. Measurements of the conductivity of diflBcultly soluble compounds are also given. 10, 216, 217, 469, (630), 666, 848, 990, 991, 993, 1003, 1004, 1174, (1331), 1496. Measurements of conductivity in SOLVENTS OTHER THAN WATER. a) Inorganic solvents. 16, 27, 29, 30, 32, 33, 147a, 167, 157a, 222, 223, 297, 315, (393), 470, 471, 472, 486, 602, 604, 606, 607, 609, 610, 660, 669, 671, 672, 673, (706), 750, 887, 943, (974), (1079), (1204), (1206), 1233a, 1237, (1348), (1445), 1446, (1595), 1645, 1646, 1676, 1733, 1826, 1827, 1828, 1829, 1833, 1834, 1842, (1853c), 1856, 1897, (1946). b) Organic solvents. — Not diluted. 16, 18, 20, (34), (38), 73, 75, 82, (90), 122, (147), (223), 289, 290 291, (291a), (293), 321, 325, (327), 334, 335, 336, (337), 338 339, 344, 346, (347), 360, (361), (362), (363), (364), (365), 552 SUBJECT INDEX 366, 369, (386), (390), 418, 426, 431, (433), 438, 470, 471, 472, 474, 475, 478, 480, (481), 482, 483, 487, 488, 491, (620), (580), 605, 637, 647, 654, 656a, 667, 668, 669, (697), (711-723), 740, 746, 753, 754, 764, 767a, 782, (783), 787, 788, 789, (817a), 833, 840, (842), (904), 908, (912), (915), (916), (918), (920), 922, 923, 931, 932, (933), 934, 935, 936, 939, (941), (942), 943, 958, 1012, 1013, (1015), 1021, 1022, (1026), (1026), (1044), (1051), 1056, 1057, 1070, 1071, 1084, 1106, 1223, 1250, (1255), 1263, (1278), 1280, (1308), 1311, 1314, 1316, 1321, (1323), (1324), 1329, 1379, 1386b, 1388, (1389), 1390, 1421, 1423a, (1432), 1434a, 1435, 1437, 1444a, (1446), (1469), 1470, (1477), (1488), 1506d, 1526, 1530, (1534), 1562a, 1669, 1679, 1680, 1689, 1590a, (1692), (1609a), (1612), 1620, 1622-1626, (1661), 1664, 1712, 1724, 1733, 1746, 1759, 1763, (1764), (1766), (1794), 1797, 1801, 1802, 1807, 1809, 1815, (1818), 1827, 1830, 1834, 1842, 1843, 1844, (1845), 1846, 1847, 1848, 1849, 1861, 1863a, (1853c), 1884, (1893), 1894, 1900, 1903a, 1904, 1970, 1971, (1987), 1991, (1993), 2008, 2029, (2031). o) Organic solvents. — Diluted with water. 16, 46, 82, 94, 223, (331), 344, 391, 613, 532, 647, 666a, 764, 764, 777, 782, 822, (876), 908, (912), (915), (916), (918), (920), 922, 923, 926, 932, 1066, 1071, 1185, (1221), 1279, 1280, 1286, 1298, 1316, 1390, 1419, 1452, 1464, (1488), 1508, (1641), 1679, (1682), (1609a), 1627, 1649, (1663), 1654, (1681), 1718, 1724, 1746, 1763, 1791, 1820, 1841, 1884, 1886, (1916), 1994. SPECIFIC CONDUCTIVITY OF PURE COMPOUNDS. a) Acids. 44, 211, 347, 360, 362, 369, 617, 631, 694, 753, 787, 894, 908, 943, 986, 1330, 1380, 1388, 1419, 1470, 1676, 1843, 1844, 1863c, 1967, 2008. b) Alcohols. 18, 20, 21, 263, 289, 290, 305, 335, 337, 338, 347, 361, 362, 366, 391, 418, 425, 438, 465, 466, 478, 491, 580, 597, 647, 656a, 754, 764, 783, 787, 842, 904, 908, 912, 916, 917, 918, 920, 922, 941, 955, 956, 986, 1010, 1021, 1106, 1107, 1316, 1344, 1388, 1390, 1419, 1420, 1421, 1423a, 1434a, 1470, 1472, 1634, 1656, 1569, 1579, 1580, 1589, 1590a, 1692, 1620, 1649, 1661, 1724, 1746, 1766, 1791, 1800, 1807, 1843, 1844, 1849, 1853a, 1884, 1900, 1903a, 1970, 1971, 1987, 2029, 2031. c) Aldehydes. 517, 784, 941, 1106, 1107, 1388, 1569, 1690a, 1842-1844, 1847, 1863a. d) Amides. 211, 1606d, 1843, 1844, 1863b, 1863c, 1894. SUBJECT INDEX 553 e) Anhydrides. 211, 1690a, 1843, 1844. f) Bases — containing nitrogen. 211, 306, 347, 393, 478, 606, 754, 786, 817a, 942, 943, 1057, 1084, 1106, 1176, 1250, 1316, 1388, 1389, 1472, 1477, 1569, 1612, 1843, 1844, 1863c, 1900. g) Esters. 306, 360, 366, 939, 941, 1106, 1107, 1223, 1388, 1470, 1569, 1830, 1834, 1843, 1844, 1847, 1863a. h) Ethers. 306, 360, 362, 366, 634, 636, 816, 986, 1010, 1098, 1316, 1344, 1421, 1666, 1669, 1596, 1842-1844, 2031. i) Halogen derivatives of acids; as acetyl chloride. 1842, 1843, 1844. j) Hydrocarbons. 211, 263, 291, 306, 384, 386, 617, 634, 740, 842, 872, 873a, 923, 935, 941, 978, 983a, 1010, 1098, 1106, 1107, 1234, 1344, 1388, 1423a, 1437, 1477, 1656, 1569, 1590a, 1604, 1605, 1830, 1843, 1844, 2031. k) Ketones. 306, 334, 336, 347, 362, 476, 478, 487, 904, 916, 918, 920, 922, 941, 1066, 1070, 1106, 1323, 1388, 1423a, 1477, 1669, 1590a, 1620, 1830, 1843, 1844, 1847, 1863a. 1) Nitriles. 367, 369, 482, 617, 669, 1084, 1106, 1107, 1323, 1388, 1423a, 1669, 1690a, 1733, 1842, 1843, 1844, 1846, 1847, 1849, 1863a. m) Oximes. 1843, 1844. n) Compounds containing sulphur. This includes CS2. 263, 301, 306, 384, 386, 417, 872, 939, 1010, 1098, 1106, 1223, 1344, 1388, 1491, 1666, 1806, 1843, 1844, 1846, 1847, 1853a. o) Unclassified. 28, 211, 369, 1272, 1669. SULPHUR COMPOUNDS; as mercaptans, sulphides etc. Sulphinic and sulphonio acids are not given here, but under the head of ACIDS containing sulphur. 149, 263, 270, 301, 306, 334, 335, 336, 360, 369, 384, 386, 417, 431, 604, 606, 762, 760, 872, 939, 943. 1010, 1098, 1223, 1302, 654 SUBJECT INDEX 1344, 1363, 1379, 1388, 1437, 1491, 1649, 1666, 1806, 1833, 1842, 1843, 1844, 1863a, 1866, 2029. TEMPERATT7RE. Under this heading are arranged in four groups those references bearing on the effect of temperature on conductivity, or containing measurements of the ionization constant or of conductivity at temperatures other than those generally used. The author list shows, whenever possible, the particular temperatures or the limits of temperature. a) At or near the critical temperature. 107, 133, 634, 636, 536, 619, (706), (707), (1025), (1026), 1865. b) General articles. 262, 329, 330, 616, (870), 876, 889, (909), (1152), (1153), (1164), 1177, 1471, 1472, (1565), (1906), 1968. c) High temperature (above 26°). (19), 43, 44, 62a, 54, 103, 105, 106, 110, 122, 124, 143, 145a, 145b, 160, 164, 179, 217, 250, 263, 256, 266, 267, 268, 290a, 306, 307, 308, 309, (331), 376a, 388a, 410, 412, 438, 447, 469, 476, 478, 480, (481), 482, 507a, 515, 523, 532, 534, 536, 652, 663, 593, 609, 617a, 619, 625, 665, 695, 701, 733, 764, 776, 787, 789, 807, 808, 869a, 873, 876, (876), 880, 881, (909), 911, 924, 932, 945, 976a, 983a, 993, 1004, (1016), 1024, 1137a, 1143, 1144, 1150, 1183, 1209, 1226, 1227, 1229a, 1239a, 1259, 1296, 1326, 1331, 1332, 1337, 1338, 1341, 1341b, 1342, 1365a, 1366, 1390, 1391a, 1428, 1434a, 1462, 1462, 1471, 1472, 1488, 1506a, 1506b, 1506c, 1532, 1537, 1570, 1578, 1581, 1690a, 1592, 1596, 1599, 1627, 1654, 1708, (1766), 1796, 1797, 1798, 1800, 1809, 1834, 1843, 1844, 1846, 1853a, 1865, 1880, 1886, 1894, 1963a, 1967, 1968, 1968a, (1989), 1996, 1997, 2002, 2032. d) Low temperature (below 17°). 27, 29, 30, 32, (48), 82, 88, 103, 105, 106, 110, 122, 124, 141, 143, 145a, 146b, 147a, 158, 164, 165, 167, 168, 177, 179, 220, 260, (293), 301, 315, 325, (331), 347, 360, 361, 369, 370, 387, 425, 438, 445, 451, 456, 461, 478, 480, (481), 482, 486, 600, 601, 602, (612), 513, 516, 524, 628, 632, 640, 641, 542, (680), 681, 582, 697, (699?), 602, 604, 607, 610, 622a, 625, 635, 646, 669, 671, 680, 683, 684, 701, 709, 725, 730, 733, 735, 736, 752, 756, 763, 764, (766), 766, 768, 769, 770, 772, 773, 774, 775, 776, 780, 786, 787, 793, 796, 833, 838, 839, 848, 873, 875, (876), 877, 887, 901, 902, 903, (906), 908, (909), 910, 911, 916, 918, 920, 922, 923, 924, 932, 943, 949, 956a, 975, 993, 1004, (1016), 1018, (1041), 1076, 1092, 1143, 1144, 1160, 1164, (1206), 1222, 1233a, 1269, 1272, 1296, 1309a, 1330, 1338, 1342, 1356, 1415, 1419, 1464, 1468, 1472, 1477, 1482, 1499, 1519, 1620, 1623, 1524, 1663, 1568, 1669, 1676, 1577, 1590, 1690a, 1596, 1612, 1634a, 1646, 1651, 1664, SUBJECT INDEX. 555 1656a-1655c, 1660, 1676, 1708, 1708a, 1737, 1741, (1766), 1769, 1775-1779, 1798, 1807, 1826, 1827, 1828, 1829, 1833, 1842, 1843, 1844, 1845, 1847, 1848, 1849, 1853a, 1853c, 1855, 1887, 1897, 1959, (1961), 1962, 1968, 1968a, 1980, 1986, (1989), 2004, 2006, 2009, 2032. 301, 416, 1480. THIN LAYERS. Conductivity of thin layers. JOURNAL LIST. This gives a complete list of all the journals examined. The journals are arranged in alphabetical order, disregarding particles such as, and, de, der, etc. After the title of each journal is given the number and date of the last vol- ume examined, with the page number, or division number, if the complete volume has not been examined. Journals having the title preceded by the sign )(! (as, # Annales de, etc.) are not complete through the year 1910 either because it has been impossible to examine one or more volumes, or because the volume covering the year 1910 has not been issued. A note of the number or of the date of missing volumes is given. At the end is added a list of the authors of articles in the Journal of the Russian Physico-chemical Society, arranged chronologically, with the page numbers of the articles. This is given because the variations in names, due to different systems of transliteration, make checking of references to this journal slightly diflBcult. JOUENAL LIST. Abhandlungen der koniglichen Gesellschaft der Wissenschaften zu Gottingen. Math.-Phys. Klasse. Through N. F., Volume 9, no. 2, (1911). Abhandlungen der koniglich preussischen Akademie der Wissenschaften. (Berlin). Through (1910). Abhandlungen der koniglich sachsischen Gesellschaft der Wissenschaften. Mathematisch-physische Classe. Through Volume 32, page 506, (1910-1911). Abhandlungen der mathematisch-physikalischen Classe der koniglich bayer- ischen Akademie der Wissenschaften. (Munchen). Through Volume 25, no. 10, (1909-1912). American Chemical Journal. Through Volume 44, (1910). The i^Lmeriean Journal of Physiology. Through Volume 27, (1910-1911). The American Journal of Science. Through Volume 30, (1910). The Analyst. Through Volume 35, (1910). Annaes scientificos da academia polytecnica do Porto. (Coimbra). Through Volume 5, (1909-1910). Annalen der Chemie. (Justus Liebig's). Through Volume 378, (1910). Annalen der Physik. [This journal is often referred to by the name of the editor, first Poggen- dorff, then Wiedemann, then Drude. There has been a board of editors since the year 1909. Before the beginning of the fourth series the title was, Annalen der Physik und Chemie.] Through Series 4, Volume 33, (1910). Annalen der Physik und Chemie. Erganzungsband. Through Volume TX. Annales de chimie et de physique. Through Series 8, Volume 21, (1910). # Annales de Tuniversit^ de Lyon. Through N. S., Fascicule 29, (1909). Annals of the New York Academy of Sciences. Through Volume 20, (1910). Arbeiten aus dem kaiserlichen Gesimdheitsamte. Through Volume 36, (1910-1911). Archiv fur Anatomie und Physiologie. Physiologische Abteilung. Through (1910). Archiv ftir die gesammte Physiologie des Menschen und der Tiere. (Pfliiger'a Archiv). Through Volume 135, (1910). 558 JOURNAL LIST Archiv der Pharmazie. Through Volume 248, (1910). Archives du Mus^e Teyler. (Haarlem). Through Series 2, Volume 11, (1907-1909), Archives nSerlandaises des sciences exactes et naturelles. ' Through Volume 15, (1910). Archives des sciences physiques et naturelles. (BibliothSque universelle). Through Series 4, Volume 30, (1910). Archivio di fisiologia. Through Volume 8, (1909-1910). Arkiv for kemi, mineralogi och geologi. Through Volume 3, (1908-1910). Arkiv for matematik, astronomi och fysik. Through Volume 6, (1910-1911). Atti della accademia Gioenia di scienze naturali in Catania. Through Series 5, Volume 3, (1910). Atti della pontificia accademia romana dei nuovi Lincei. Through Volume 63, (1910). Atti della reale accademia dei Lincei. Memorie. See Memorie della reale accademia, etc. Atti della reale accademia dei Lincei. Rendicpnti. See Rendiconti della reale accademia, etc. M Atti della reale accademia delle scienze fisiche e matematiche. SocietS, reale di Napoli. ■> Through Series 2, Volume 14, (1909). Atti della reale accademia di scienze, lettere e belle arti di Palermo. Through Volume 9, (1912). Atti della reale accademia delle scienze ,di Torino. Through Volume 45, (190^1910). Atti del reale istituto veneto di scienze, lettere ed arti. Through Volume 69, (1909-1910). Beitrage zur chemischen Physiologie und Pathologic. Zeitschrift fiir die gesamte Bioohemie. Through Volume 11, (1908). Publication discontinued. Berichte der deutschen chemischen Gesellschaft. Through Volume 43, (1910). Berichte der deutschen physikalischen Gesellschaft see Verhandlungen der deutschen physikalischen Gesellschaft. Through Volume 8, (1910). Berichte der naturforschenden Gesellschaft zu Freiburg. Through Volume 18, (1909-1910). Berichte iiber die Verhandlungen der koniglich sachsischen Gesellschaft der Wissenschaften zu Leipzig. Mathematisch-physische Klasse. Through Volume 62, (1910). Bihang till kongl. svenska vetenskaps-akademiens handUngar. (Stockholm). Through Volume 28, (1902-1903). Publication discontinued. Biochemische Zeitschrift. Through Volume 28, (1910). BoUettino delle sedute della accademia Gioenia di scienze naturali in Catania. Through N. S., Fasc. 15, (1911). Bulletin de I'acadSmie royale des sciences, des lettres et des beaux-arts de Belgique. Bulletins de la classe des sciences. [The volumes are not numbered after the year 1898.] Through (1910). JOURNAL LIST 559 Bulletin of the Chicago Academy of Sciences. Through Volume 3, no. 5, (1909-19—). Bulletin international de I'aead^mie des sciences de Cracovie. S6rie A; scien- ces math^matiques. S6rie B; sciences naturelles. Through A, (1910). " B, (1910). Bulletin des stances de la soci6t6 frangaise de physique. [Before 1893 the title was, Stances de la soci6t6 frangaise de physique.] Through (1910). Bulletin des stances de la soci6t6 des sciences de Nancy. Through Series 3, Volume 11, (1910). Bulletin de la soci6t6 chimique de France. [Before 1910 the title was, Bulletin de la soci6t4 chimique de Paris.] Through Series 4, Volume 7, (1910). Bulletin de la soci6t6 des sciences de Nancy. [Continued in, Bulletin des stances de la soci6t6 des sciences de Nancy.] Through Series 2, Volume 16, (1899). Bulletin de la soci6t6 vaudoise des sciences naturelles. (Lausanne). Through Series 5, Volume 46, (1910). The Chemical News. Through Volume 102, (1910). Chemiker-Zeitung. Through Volume 34, (1910). Comptes rendus hebdomadaires des stances de l'acad6mie des sciences. (Paris). Through Volume 151, (1910). Denkschrif ten der kaiserliohen Akademie der Wissenschaften. Mathematisch- naturwissenschaftliche Klasse. (Wien). Through Volume 86, I, (1911). Drude's Annalen see Annalen der Physik. Ergebnisse der Physiologie. Through Volume 9, (1910). Forhandlinger i Videnskabs-Selskabet i Christiania. Through (1910). Gazzetta chimica italiana. Through Volume 40, (1910). Giomale di scienze naturali ed economiche. (Palermo). Through Volume 28, (1911). Goteborgs kungl. vetenskaps- och vitterhetssamhalles handlingar. Through Series 4, Volume 13, (1910). Helios. Organ des naturwissenschaftlichen Vereins des Regierungsbezirkes. (Frankfurt). Through Volume 26, (1910). Hoppe-Seyler's Zeitschrift see Zeitschrift fiir physiologische Chemie. Isis see Sitzungsberichte und Abhandlungen etc. The Journal of the American Chemical Society. Through Volume 32, (1910). The Journal of Biological Chemistry. Through Volume 8, (1910). Journal of the Chemical Society. (London). Through Volume 97, (1910). Journal de chimie physique. Through Volume 8, (1910). The Journal of Industrial and Engineering Chemistry. Through Volume 2, (1910). 560 JOURNAL LIST The Journal of Physical Chemistry. Through Volume 14, (1910). The Journal of Physiology. Through Volume 40, (1910). Journal de physique. Through Series 4, Volume 9, (1910). Journal ftir praktische Chemie. Through Series 2, Volume 82, (1910). Journal of the Russian Physico-chemical Society. Through Volume 42, (1910). See also the end of this section. The Journal of the Society of Chemical Industry. Through Volume 29, (1910). The Journal of the Society of Dyers and Colourists. Through Volume 26, (1910). Justus Liebig's Annalen see Annalen der Chemie. KoUoidchemische Beihefte see Zeitschrift fiir Chemie und Industrie der KoUoide. Kolloid Zeitschrift see Zeitschrift fiir Chemie und Industrie der KoUoide. Det kongelige danske videnskabernes Selskabs Skrifter. Through Series 7, Volume 8, (1909-1911). Kungliga svenska vetenskapsakademiens handUngar. Through N. F., Volume 46, (1910-1911). Liebig's Annalen see Annalen der Chemie. The London, Edinburgh and Dublin Philosophical Magazine see Philosophi- cal Magazine. Meddelanden rfrS,n k. vetenskapsakademiens NobeUnstitut. Through Volume 1, (1906-1909). M^moires de I'acad^mie nationale des sciences, arts et belles-lettres de Caen. Through (1910). Mtooires de I'acad^mie des sciences, belles-lettres et arts de Lyon. Through Series 3, Volume 11, (1911). Mdmoires couronn^s et autres m6moires publics par I'acadiSmie royale des sciences, des lettres et des beaux-arts de Belgique. In 8°. Classe des sciences. Through Series 2, Volume 2, (1907-1910). Mfimoires de la soci6t6 royale des sciences de Li6ge. Through Series 3, Volume 9, (1912). Memoirs of the American Academy of Arts and Sciences. Through N. S., Volume 13, (1908). Memoirs and Proceedings of the Manchester Literary and Philosophical Society. Through Volume 54, (1909-1910). 1^ Memorias de la real academia de ciencias exactas, fisicas y naturales de Madrid. Through Volume 26, (1908). Memorie della pontificia accademia romana dei nuovi Lincei. Through Volume 28, (1910). Memorie della reale accademia dei Lincei. Classe di scienze fisiche, mate- matiche e naturali. Through Series 5, Volume 7, (1908-1910). Memorie della reale accademia delle scienze dell'istituto di Bologna. Through Series 6, Volume 7, (1909-1910). JOURNAL LIST 561 Memorie della reale accademia delle scienze di Torino. Scienze fisiche, mate- matiche e naturali. Through Series 2, Volume 60, (1910). Memorie della regia accademia di scienze, lettere ed arti in Modena. Through Series 3, Volume 9, (1910). Mitteilungen der naturforschenden Gesellschaft in Bern. Through (1910). Monatshefte ftir Chemie. Through Volume 31, (1910). Nachrichten von der konigl. Gesellschaft der Wissenschaften zu Gottingen. Mathematisch-physikalisohe Klasse. Through (1910). Nature. Through Volume 85, (1910-1911). Naturwissenschaftliche Rundschau. Through Volume 25, (1910). Nova acta regiae societatis scientiarum upsaliensia. Through Series 4, Volume 2, (1907-1911). II nucvo cimento. Through Series 5, Volume 20, (1910). Ofversigt af finska vetenskaps-societetens forhandlingar. (Helsingfors). Through Volume 62, (1909-1910). Ofversigt af kongl. vetenskaps-akademiens forhandlingar. (Stockholm). Through (1901-1902). Oversigt over det kongeUke danske videnskabemes Selsk-abs Forhandlinger. (Copenhagen). Through (1910). Pfluger's Archiv see Archiv gesammte Physiologic. The London, Edinburgh and Dubhn Philosophical Magazine and Journal of Science. Through Series 6, Volume 20, (1910). Philosophical Transactions of the Royal Society of London see Transactions of the Royal etc. The Physical Review. Through Volume 31, (1910). Physikalische Zeitschrift. Through Volume 11, (1910). Poggendorff's Annalen see Annalen der Physik. Proceedings of the American Academy of Arts and Sciences. Through Volume 45, (1909-1910). Proceedings of the American Association for the Advancement of Science. Through Volume 61, (1910). Proceedings of the American Philosophical Society. Through Volume 49, (1910). Proceedings of the Birmingham Natural History and Philosophical Society. Through Volume 12, no. 5, (1907-19—). Proceedings of the California Academy of Sciences. Through Series 3, Volume 4, (1905). Proceedings of the Cambridge Philosophical Society. Through Volume 15, (1909-1910). Proceedings of the Chemical Society. (London). Through Volume 26, (1910). 562 JOURNAL LIST Proceedings of the Davenport Academy of Sciences. (Davenport, Iowa). Through Volume 12, (1907-1910). Proceedings of the Indiana Academy of Sciences. Through (1910). Proceedings of the Iowa Academy of Sciences. Through Volume 17, (1910). Proceedings of the Physical Society of London. Through Volume 22, (1910). Proceedings of the Royal Dublin Society see Scientific Proceedings of, etc. Proceedings of the Royal Irish Academy. Through Volume 28, (1909-1910). Proceedings of the Roval Physical Society. (Edinburgh). Through Volume 18, (1909-1912). Proceedings of the Royal Society of Edinburgh. Through Volume 30, (1909-1910). Proceedings of the Royal Society of London. Through A, Volume 83, (1909-1910). " B, Volume 82, " The Proceedings and Transactions of the Nova Scotian Institute of Science. Through Volume 12, (1907-1909). [Volume 12 contains one paper dated 1911.] Proceedings and Transactions of the Royal Society of Canada. Through Series 3, Volume 4, (1910). Proceedings of the Washington Academy of Sciences. Through Volume 12, (1910). Proces-verbaux des stances de la soci6t6 des sciences physiques et naturelles de Bordeaux. Through (1909-1910). RecueU des travaux chimiques des Pays-Bas et de la Belgique. Through Volume 29, (1910). Rendiconti della reale accademia dei Lincei. Classe di scienze fisiche, mate- matiche e naturali. Through Series 5, Volume 19, (1910). Rendiconti. Reale istituto lombardo di scienze e lettere. Through Series 2, Volume 43, (1910). j^ Rendiconti deUa society chimica di Roma. Through Volimie 6, (1908). Rendiconto deU' accademia delle scienze fisiche e matematiche (sezione della society reale di NapoU). Through Series 3», Volume 16, (1910). M Rendiconto deUe sessioni della reale accademia delle scienze dell'istituto di Bologna. Through N. S., Volume 14, (1909-1910). The years 1889 to 1896 inclusive have not been examined. Revista de la real academia de oiencias exactas, flsicas y naturales de Madrid. Through Volume 9, (1910-1911). Schriften des naturwissenschaftlichen Vereins fiir Schleswig-Holstein. Through Volume 15, page 222, (1909-1911). Science. Through N. S., Volume 32, (1910). The Scientific Proceedings of the Royal Dublin Society. Through Volume 12, (1909-1910). The Scientific Transactions of the Royal DubUn Society. Through Series 2, Volvmie 9, (1905-1907). Publication discontinued. JOURNAL LIST 563 Sitzungsberichte und Abhandlungen der naturwissenschaftlichen Gesellschaft Isis in Dresden. Through (1910). Sitzungsberichte der Gesellschaft zur Bef orderung der gesammten Naturwissen- Bchaften. (Marburg). Through (1910). , Sitzungsberichte der koniglich bohmischen Gesellschaft der Wissenschaften. Mathematisch-naturwissenschaftliche Classe. (Prag). Through (1910). Sitzungsberichte der koniglich preussischen Akademie der Wissenschaften. (Berlin). Through (1910). Sitzungsberichte der mathematisch-naturwissenschaftlichen Classe der kaiser- lichen Akademie der Wissenschaften. (Wien). Through Volume 119, (1910). Sitzungsberichte der mathematisch-physikalischen Klasse der koniglich bay- erischen Akademie der Wissenschaften zu Miinchen. Through Volume 40, (1910). Sitzungsberichte der physik-med. Gesellschaft zu Wurzburg. Through (1910). Transactions of the Academy of Science of St. Louis. Through Volume 19, (1910). Transactions of the American Electrochemical Society. Through Volume 20, (1911). Transactions of the American Philosophical Society. Through N. S., Volume 21, (1905-1908). [Volume 22 begins with the year 1911.] Transactions of the Cambridge Philosophical Society. Through Volume 21, (1908-1912). Transactions of the Connecticut Academy of Arts and Sciences. Through Volume 16, (1910). Transactions of the Faraday Society. Through Volume 6, (1910). Transactions of the Kansas Academy of Science. Through Volume 24, (1911). Transactions of the New York Academy of Sciences. Through Volume 16, (1896-1897). Publication discontinued. Transactions of the Royal Dublin Society see Scientific Transactions, etc. )K Transactions of the Royal Scottish Society of Arts. Through Volume 18, (1908-1909). Transactions of the Royal Society of Edinburgh. Through Volume 47, (1908-1911). Philosophical Transactions of the Royal Society of London. Through Series A, Volume 210, (1910). " B, " 201, (1910). Transactions of the Texas Academy of Science. Through Volume 11, (1911). j« Transactions of the Wisconsin Academy of Sciences, Arts and Letters. Through Volume 16, (1908-1909). ;ii! Travaux scientifiques de I'universiti de Rennes. Through Volume 6, (1907). University Studies. (University of Nebraska). Through Volume 10, (1910). 564 JOURNAL LIST Verhandelingen der koninklijke akademie van wetenschappen. (Amsterdam). Through Series 2, Volume 11, no. 2, (1910-19—). Verhandlungen der deutschen physikalischen Gesellschaft. [This is some- times bound with the Berichte der deutschen physikalischen Gesell- schaft under that title, but with a double title page.] Through Volume 12, (1910) = Volume 8 of Berichte, etc. Verhandlungen der Gesellschaft deutscher Naturforscher und Arzte. Through Volume 82, (1910). Verhandlimgen der naturforschenden Gesellschaft in Basel. Through Volume 20, (1909-1910). Verhandlungen der physikalischen Gesellschaft zu Berlin. [Continued as Verhandlungen der deutschen physikalischen Gesellschaft.] Through Volume 17, (1898). Verslag van de gewone vergaderingen der wis- en natuurkundige afdeeling. Koninklijke akademie van wetenschappen te Amsterdam. Through Volume 18, (1909-1910). Wiedemann's Annalen see Annalen der Physik. Zeitsehrift ftir analytische Chemie. Through Volume 49, (1910). Zeitsehrift ftir angewandte Chemie. Through Volume 23, (1910). Zeitsehrift fur anorganische Chemie. Through Volume 69, (1910). Zeitsehrift fiir Biologie. Through Volume 54, (1910). Zeitsehrift fiir Chemie und Industrie der KoUoide. (KoUoid-Zeitschrift). Through Volume 7, (1910). KoUoidchemische Beihefte. Through Volume 1, (1909-1910). Zeitsehrift fiir Elektrochemie und angewandte physikalische Chemie. Through Volume 16, (1910). Zeitsehrift fiir die gesamte Biochemie see Beitrage zur chemischen Physiolo- gie und Pathologie. Zeitsehrift fiir Naturwissenschaften. Through Volume 82, (1910). Zeitsehrift fur physikalische Chemie. Through Volume 75, (1910-1911). Zeitsehrift fiir physiologische Chemie. (Hoppe-Seyler's). Through Volume 69, (1910). Journal of the Russian Physico-chemical Society. Through Volume 42, (1910). 1890. Vol. 22. 110-115 Chroustchoff, Pachkoff. 115-116 Chroustchoff. 411-430 Kistiakowsky. 1891. Vol.23. 126-147 Zelinsky, Besredka. 391-422 Kablukoff. 612-632 Zelinsky. 632-652 Walden. JOURNAL LIST 1892. Vol. 24. 440-450 Konowalow. 1893. Vol. 26. 192-201 Konowalow. (211-222 Konowalow). (364-378 Markownikoff). 547-564 Markownikoff. 626-631 SapoiSnikov. 1894. Vol. 26. (608-611 Zelinsky). (611-612 Zelinsky). 1896. Vol. 28. 149-158 Reformatsky. 293-299 Kukulesko. 329-334 Speranskij. (414r416 Zelinsky, Krapiwin). 501-509 Gillaov. 579-593 Zelinsky, Krapiwin. 664-683 Szyszkowski. 1898. Vol. 30. (333-334 Schroder). 453^66 Reformatsky. 466-475 Michajlenko. 1900. Vol. 32. 328-346 Michajlenko, Javorskij. (797-804 Speranskij, Goldberg). 1901. Vol. 33. 158-163 Szyszkowski, Reformatsky. 242-246 Protopopov, Reformatsky. 545-547 Centnerszwer. 547-549 Centnerszwer. 466-472 Plotnikow. 651-652 Fedorov. 794-810 Plotnikow. 1902. Vol. 34. 1903. Vol. 36. 1904. Vol.36. (255-275 Timofejev, Kobozev). (605 Gardner, GerassimofT). (746-753 Gardner, Gerassimoff). 566 JOURNAL LIST 1905. Vol.37. 318-337 Plotnikow. 492-502 Pissarjewsky, Lemcke. 875-881 Plotnikow. 1096-1104 Plotnikow. 1906. Vol.38. 1907. Vol.39. 936-943 Tanatar, Kurovskij. 1262-1323 Tschugaeff. 1379-1391 Dumanski. 1630-1632 Tanatar, Kurovskij. 1908. Vol.40. (192-197 Bogorodskjj). 337 Neminskij, Plotnikow. 391-396 Neminskij, Plotnikow. (564-565 Pissarjewsky, Karp). (599-611 Pissarjewsky, Karp). 739-740 DoroSevskij, Roidestvenskij. 887-908 DoroSevskij, RoJdestvenskij. 1238-1243 Plotnikow. (1243-1247 Plotnikow). (1247-1257 Plotnikow). 1379-1388 Zelinsky, IzgarySev. 1909. Vol.41. (241-244 Timofejev). ] 252-258 Dumanski. ■ In the Mendelejeff 285-286 Tschugaeff. . 184-252 Tschugaeff. 253-287 Tschugaeff. 1332-1354 Tschugaeff. 1355-1368 Tschugaeff. 1910. Vol.42. 683-690 Sachanov. 905-938 Pissarjewsky, Sapovalenko. 1466-1487 Tschugaeff. 1589-1596 Plotnikow. ADDENDA. TO AUTHOR LIST. 1800a. L. Vignon. Bulletin Soci6t6 Industrielle Mulhouse. 77, 82-84, (1907). Teinture etc. [Same as 1799. Same as 1796 for A. ] 1800b. L. Vignon. Bulletin Soci6t6 Industrielle Mulhouse. 79, 133-139, (1909). Conduotibilit6 61ectrique etc. [Same as 1798.] 1800c. L. Vignon. Bulletin Soci6t6 Industrielle Mulhouse. 79, 139-142, (1909). Sur les propri6t^s etc. [Same as 1797 and 1800.] 1866a. P. Walden, M. Centnerszwer. Bulletin Academic Imp6riale Sciences St. P6tersbourg. (5), 15, 17-119, (1901). Flussiges Schwefeldioxyd etc. [Same as 1854 and 1866.] TO JOURNAL LIST. The American Journal of Pharmacy. Through Volume 82, (1910). Bulletin de l'acad6mie imp&iale des sciences de St. P^tersbourg. Through Series 6, Volume 4, (1910). Bulletin de la society chimique de Belgique. Through Volume 24, (1910). Bulletin de la soci6t6 industrielle de Mulhouse. Through Volume 70, (1910). Bulletin de la soci6t6 industrielle de Rouen. Through Volume 38, (1910). Bulletins of the Minnesota Academy of Science. Through Volume 4,_ (1892-1910). Forhandlingar see also Ofversigt etc. Handlingar see Bihang till kongl. svenska etc., Goteborgs kungl. etc. and Kungliga svenska etc. Journal of the Academy of Natural Sciences of Philadelphia. Through Series 2, Volume 14, (1909-1912). Journal and Proceedings of the Royal Society of New South Wales. Through Volume 44, (1910). The Kansas University Quarterly. Through Volume 10, (1901). Publication continued in the following journal. The Kansas University Science Bulletin. Through Volume 5, (1910-1911). Det kongelige norske videnskapers Selskaps Skrifter. Through (1910). 568 ADDENDA M^moires de I'acad^mie imp^riale des sciences de St. P^tersbourg. Class© des sciences physiques et math6matiques. Through Series 8, Volume 25, (1910). M^moires de la soci6t6 des sciences physiques et natureUes de Bordeaux. Th/ough Series 6, Volume 6, Fasc. 1, (1910-19—). Papers and Proceedings of the Royal Society of Tasmania. Through (1910). Precis analytique des travaux de Tacadtoie des sciences, belles-lettres et arts de Rouen. Through (1910-1911). Proceedings of the Academy of Natural Sciences of Philadelphia. Through Volume 62, (1910). The Proceedings of the Colorado Scientific Society. Through Volume 9, (1908-1910). Proceedings of the Royal Society of Queensland. Through Volume 22, (1910). Proceedings of the Royal Society of Victoria. Through N. S., Volume 23, (1911). Sammelschrift der mathematisch-naturwissenschaftlich-arztUchen Sektion der Sev5enko-Gesellschaft der Wissenschaften in Lemberg. Through Volume 14, (1910). Skrifter see Kongelige danske etc. and Kongelige norske, etc. Transactions and Proceedings and Report of the Royal Society of South Australia. Through Volume 34, (1910). Transactions of the Royal Society of Victoria. Through Vohime 5, (1910). University of Illinois. The University Studies. Through Volume 3, (1908-1910). . University of Missouri Studies. Science Series. Through Volume 2, No. 2, (1911). University Studies. University of Cincinnati. Through Series 2, Volume 6, (1910). FINIS