iMiiliiiiMtl it! ' u t lit !i !! H »4tU KfllltUllHiitUlWiM 'HtUUl IUi(tH4W 133-134; Example 11a, Iron Mountain, Mo., 134-136; analyses of hematites, 186, 137 103-137 Chapter III. — Magnetite and Pyrite. Example 13, Magnetite beds, 138-145; Adirondack region, 138-140; New York and New Jersey Highlands, 141, 143; South Mountain, Penn., 143; Western North Carolina and Virginia, 143; Colorado, 144; California, 145, 146; Example 13, titaniferous magne- tite, 145, 146; Example 14, Cornwall, Pa., 146-150; Example 14a, Iron Co., Utah, 151; Example 15, magnetite sands, 151, 152; origin of magnetite deposits, 153, 153; distribution of phosphorus, 154; analyses of magnetites, 154; pyrite, 154^157; Example 16, pyrite beds, 154-157; statistics, 157; remarks on Cuban and Mexican iron ores, 157-159 .' 138-159 Chapter IV. — Copper. Table of analyses of copper ores, 160; Example 16, continued, pyrite beds, 160, 161; Ore Knob, N. C, 161; Spenceville, Calif., 163; Example 17, Butte, Mont., 162-165; Gilpin Co., Colo., 165; Llano Co., Texas, 166; Example 18, Keweenaw Point, Mich., 166-171; Example 19, St. Genevieve, Mo., 171, 173; Example 20, Arizona Copper, 173-180; Morenci, 173; Bisbee, 176; Globe, 178; Santa Rita, N. M., 178; Black Range, 179; Example 30^', Crismon-Mammoth, Utah, 180; Sunrise, Wyo., 180; Example 31, copper ores in triassic or Peruvian sand- stone, 180-182; Eastern States, 180, 181; Western States, 183; statis- tics of copper, 183 160-183 Chapter V. — Lead Alone. Introductory and analyses of lead ores, 184; Example 33, Atlan- TABLE OF OONTENTB. xi tic border, St. Lawrence Co., N. Y., 184, 185; Mass., Conn, and East- ern N. Y., 185; Southwestern Penn., 185; Davison Co., N. C, 185-186; Sullivan and Ulster Counties, N. Y., 186; Example 23, Southeast- ern Missouri, 186, 187; statistics of lead, 188 184-188 Chapter VI.— Lead and Zinc. Example 24, the Upper Mississippi Valley, 189-198; Washington Co., Mo., 194; Livingston Co., Ky., 194, 195; Example 25, Southwest Missouri, 195-200; Example 36, Wythe Co., Va., 201-203 189-303 Chapter VII. — Zinc Alone or with Metals other than Lead. Introduction: Tables of analyses of zinc ores, 204; Example 27, Saucon Valley, Penn., 204, 205; Example 38, Franklin Furnace and Sterling, N. J., 303-311; Zinc in the Rocky Mountains, 211-213; in New Mexico, 213; statistics, 313, 213 204-213 Chapter VIII. — Lead and Silver. Introduction, 214; Rocky Mountain region and the Black Hills, 214-226; New Mexico, 214-216; Example 29, Kelley Lode, 214; Lake Valley, 214-216; Colorado, 216-225; Example 30, Leadville, 216-219; Example 30a, Ten-Mile, Summit Co., 219, 220; Example 306, Mon- arch District, 220; Example 306, Eagle River, 220; Example 30d, Aspen, 220 and 222-224; Example 30e, Rico, 224; Example 31, Red Mountain, 224; South Dakota, Example 30/, 225; Montana -and Idaho, Example 33, Glendale, 235; Example 32ra, Wood River, 225, 226; Example 33, Wickes, 226; Example 34, Coeur d'Alene, 226; Region of the Great Basin, 226-232; Utah, Example 35, Bingham and Big and Little Cottonwood, 226-228; Example 35a, Tooele Co., 228; Example 356, Tintic, 228; Example 30g, Hornsilver, 239; Ex- ample 83a, Carbonate mine, Beaver Co., 229; Example 326, Cave mine, 229; Nevada, Example 86, Eureka, 230, 231; Arizona, Cali- fornia, 233 214-233 Chapter IX, — Silver and Gold. — Introductory: Eastern Silver Mines and the Rocky Mountain Region of New Mexico and Colorado. Introduction, 233; Examples 37-42, defined, 233, 234; silver ores, 234; Example 33a, Atlantic Border, 335; Example 42, Silver Islet, 235; region of the Rocky Mountains and the Black Hills, 236-249; New Mexico, geology, 236, 237; mines, 237, 238; Colorado, geology, 338, 339; San Juan region, 339-344; Gunnison District, 245; Eagle Co., 345; Summit Co., 345; Park, Chaffee, Rio Grande and Conejos Counties, 246; Custer Co., 246, 247; Gilpin, Clear Creek and Boulder Counties, 248; El Paso Co., 249 233-249 Chapter X.— Silver and Gold, Continued.— Rocky Mountain Re- gion, Wyoming, the Black Hills, Montana and Idaho. Wyoming, 250; the Black Hills, 250-252; Montana, geology, 352; Madison, Beaverhead and Jefferson Counties, 253; Silver Bow Co., 254, 355; Deer Lodge and Lewis and Clarke Counties, 355; Missoula Co., 356; Idaho, geology, 256; Custer, Boise, Alturas and other counties, 257 250-257 xii TABLE OF CONTENTS. CHArTER XL — Silver and Gold, Continued. — The Region op the GsEAT Basin, in Utah, Abizona and Nevada. Utah, geology, 258, Ontario and other mines, 359, 360; Silver Reef, 360-361; Arizona, geology, 261; Northern Counties and the Silver King mine, 363; Tombstone, 363; Pima and Yuma Counties, 363; Nevada, geology, 364; Lincoln Co., 364; Ney and White Pine Counties, 365; Lander and other counties, 266; the Comstock lode, 367-271 358-371 Chapter XII. — The Pacific Slope. — Washington, Oregon and California. Washington, geology, 373; mines, 373; Oregon, geology, 373; gold quartz and placers, 374; Example 44a, Port Orford, 374; Cali- fornia geology, 375; Calico District, 376, 277; Example 44, aurifer- ous gravels, 277-384; river gravels, 277-379; high or deep gravels, 379-383; general resume of geological history of gravels, 283-384; Example 45, gold-quartz veins, 384-390 373-290 Chapter XIII. — Gold Elsewhere in the United States and Canada. Example 45a, Southern States, 391; Example 456, Ishpeming, Mich., 292; Alaska, geology, 292, 293; Example 46, Douglass Island, 293, 294; Example 456, Nova Scotia, 294; Example 45c?, gold else- where in Canada, 395; statistics, 295, 296 391-296 Chapter XIV. — The Lesser Metals. — AnjMrNiaM, Antimony, Ar- senic, Bismuth, Chromium, Manganese. Aluminium, 397-300; antimony, 301, 302; Example 47, including California, Nevada, Arkansas and New Brunswick, 301; Example 48, Iron Co., Utah, 301, 303; arsenic, 302; bismuth, 303, 303; chromium, 303; Example 49, chromite in serpentine, 303; manganese; Example 50, manganese ores in residual clay, 304-308; statistics, 308 297-308 Chapter XV. — The Lesser Metals, Continued. — Mercury, Nickel AND Cobalt, Platinum, Tin. Mercury, 309; Example 50, New Almaden, 809, 310; Example 50as, Sulphur Bank, 310; Example 506, Steamboat Springs, 310, 311; resume regarding mercury, 313; nickel and cobalt, 312-323; introduc- tory, 812-314; Example 16c, pyrrhotite beds or veins, 314; Example 13a, Sudbury, Ont., Gap mine, Penn., 315-330; Example 49ffi, Riddle's, Oregon, 831, 322; Example 23a, Mine la Motte, Mo., 322; other occurrences of nickel ores, 322, 333; platinum, 333; tin, 324, 325; Example 51, Black Hills, 324 297-324 Chapter XVI. — Concluding Remarks. Summation of such general geological relations among North American ore deposits as can be detected 826-328 LIST OF ILLUSTRATIONS. FIGS. PAGE 1. Illustration of riftiog in granite at Cape Ann, Mass. After R. S. Tarr 13 2. Open fissure in the Aubrey limestone (Upper Carboniferous), 25 miles north of Canon Diablo Station, on the A. & P. R. R., Arizona. Photographed by (J. K. Gilbert, 1892 15 3. Normal fault at Leadville, Colo. After A. A. Blow 17 4. Reversed fault at Holly Creek, near Dalton, Qa. After C. W. Hayes 18 5. Illustration of one vein faulting another at Newman Hill, near Rico, Colo. After J. B. Parish 20 6. Banded vein at Newman Hill, near Rico, Colo. After J. B. Parish. . 36 '^, Illustrations of the oxidized zone, or gossan, the zone of enrichment, and the unchanged sulphides, at Ducktown, Tenn. After A. F. Wendt 39 8. Section of the Hurst limonite bank, Wythe Co., Va., illustrating the replacement of shattered limestone with limonite and the formation of geodes of ore. After E. R. Benton 83 I 9. Geological section of the Low Moor, Va., iron-ore bed. After B. S. Lyman 85 10. Geological section of the Amenia mine, Dutchess Co., N. Y., illus- trating a Siluro-Cambrian limonite deposit. After B. T.Putnam.. 89 11. View of the Siluro-Cambrian brown hematite bank at Baker Hill, Ala. Prom the Engineering and Mining Journal 92 12. Map and sections of the Burden spathic ore mines. After J. P. Kimball 99 13. Clinton ore, Ontario, Wayne Co., N. T. After C. H. Smyth, Jr 103 14. Clinton ore, Clinton, N. Y. After C. H. Smyth, Jr 104 15. Clinton ore, Eureka mine, Oxmoor, Ala. After C. H. Smyth, Jr 105 16. Cross section of the SIoss mine. Red Mountain, Ala. From the f En- gineering and Mining Journal 105 17. Map of the vicinity of Birmingham, Ala. After W. P. Barker 106 18. View of Cherry Valley mine. Mo. After F. L. Nason HO 19. Section of Cherry Valley mine. Mo. After P. L. Nason HI 20. Generalized section of Cherry Valley mine. Mo. After P. L. Nason. . Ill 21. Open cut in the Republic mine, Marquette range, showing a horse of jasper. From a photograph by H. A. Wheeler 117 32. Cross sections to illustrate the occurrence and associations of iron ore in the Marquette district, Michigan. After C. R. Van Hise 119 23. Plan of Ludington ore body, Menominee district, Michigan. After P. Larsson 133 xiv LIST OF ILLUSTRATIONS. 24. Sections of the Ashland mine, Iron wood, Mich 133 24a. Cross section of the Colby mine, Penokee-Gogebic district, Michi- gan, to illustrate occurrence and origin of the ore. After C. R. Van ,Hise 124 25. Open cut at Minnesota Iron Co.'s mine, Tower, Minn. Photographed by J. F. Kemp 126 26. General cross section of ore body at Biwabik, Mesabi Range, Minn. After H. V. Winchell 138 27. View of the Mesaba Mountain or Oliver mine, Virginia, Minn. Pho- tographed by J. F. Kemp 130 28. Cross section of Pilot Knob, Mo. From a drawing by W. B. Potter. . 133 29. View of open cut at Pilot Knob, Mo., showing the bedded character of the iron ore. From a photograph by J. F. Kemp 133 30. View of Iron Mountain, Mo. From a photograph by H. A. Wheeler 134 31. Cross section of Iron Mountain, Mo., showing the knob of por- phyry, with the veins of ore, the conglomerate, etc. After W. B. Potter 135 33. View of open cut and underground work in Mine 21, Mineville, near Port Henry, N. Y. From a photograph by J. F. Kemp 139 33a and 33J. Model of the Tilly Foster ore body. After F. S. Ruttmann and the model itself 142 34. Section along the Cornwall Railroad from Lebanon to Miners' Village. After E. V. d'Invilliers 147 35. Map of the Cornwall mines. After E. V. d'Invilliers 148 36. Illu.stration of overlapping lenses of pyrite. After A. F. Wendt 155 37. Cross section of the Bob-tail mine. Central City, Colo. After F. M. Endlich 165 38. Geological sections of Keweenaw Point, Mich., near Portage Lake and through Calumet. After R. D. Irving 167 39. Cross section of the St. Genevieve copper mine, illustrating the rela- tions of the ore. After F. Nicholson 172 '40. Section at the St. Genevieve mine, illustrating the intimate relations of ore and chert. After F. Nicholson 172 41. Geological map of the Morenci or Clifton copper district of Arizona. After A. F. Wendt 173 42. Vertical section of Longfellow Hill, Clifton district, Arizona. After Wendt 174 43. Horizontal sections of Longfellow ore body. After Wendt 174 44. Geological section of the Metcalf mine, Clifton district, Arizona. After Wendt 175 45. Section of Copper Queen ore body, Bisbee district, Arizona. After A. P. Wendt 176 46 View of the Copper Queen mine, Bisbee district, Arizona. From a pho- tograph by James Douglass 177 47. Cross section of the Schuyler copper mine, N. J. After N. H. Darton 181 48. Gash Veins, fresh and disintegrated. After T. C. Chamberlin 190 LIST OF ILL U81 UA TIONS. xv 49. Idealized section of "flats and pitches," forms of ore bodies In Wis- consin. After T. C. Cliamberlin 191 50. Verticle section of a typical zincblende ore body, near Webb City, Mo. After C. Henrich 197 51. Geological section of the Bertha zinc mines, Wythe Co., Va. After W. H. Case 200 58. Geological section, Altoona coal mines to Bertha zinc mines. After W, H. Case 201 53. View of the Bertha zinc mines, Wythe Co., Va. From a photograph by A. B. W. Miller 303 54 Cross section at Franklin Furnace, N. J. After J. F. Kemp 206 55. Geological map at Mine Hill, Franklin Furnace, N. J. After J. F. Kemp 209 56. Geological map at Sterling Hill, Ogdensburgh, N. J. After J. F. Kemp 209 57. Stereogram of ore body at Franklin Furnace, N. J. After J. F. Kemp 210 58. Stereogram of ore body at Ogdensburgh, N. J. After J. F. Kemp. . . . 210 59. Geological cross section at Lake Valley, N. M. After Ellis Clark. . . . 215 60. Section of the White Cap chute, Leadville, showing the geological re- lations of the ore, and its passage into unchanged sulphides in depth. After A. A. Blow 218 61. Geological section of the Eagle River mines, Colo. After B. E. Olcott 221 62. Geological section at Aspen, Colo. After A. Lakes 222 63. View of the Bunker Hill and Sullivan mines, Wardner, Idaho. From a photograph loaned by B. E. Olcott 227 64. Section at Eureka, Nev. After a plate by J. S. Curtis 231 65. Geological cross sections of strata and veins at Newman Hill, near Rico, Colo. After J. B. Farish 242 66. Geological cross sections of strata and veins at Newman Hill. After J. B. Farish 243 67. View of Lower Creede, Colo. From the Engineering and Mining Journal 244 68. Geological section of the Black Hills. After Henry Newton 251 69. Cross section of vein at the Alice mine, Butte, Mont. After W. P. Blake 254 70. Two sections of the argentiferous sandstone at Silver Reef, Utah. After C. M. Rolker ' 260 71. Section of Comstock lode. After G. P. Becker 267 72. Geological section of the Calico district, California. After W. Lindgren 276 73. View of the Union diggings, Columbia Hill, Nevada Co., California. From a photograph 277 74. View of the Timbuctoo diggings, Yuba Co., California. From a photograph 278 75. Generalized section of a deep gravel bed, with technical terms. After R. E. Browne 280 xvi LIST OF ILL USTRATIONS. 76. Section of Forest Hill Divide, Placer Co., California, to illustrate the relations of old and modern lines of drainage. After E. E. Browne 281 77. Cross section of a bauxite deposit in Georgia. After C. Willard Hayes 299 78. Sections of the Crimora mangansse mine, Virginia. After C. E. Hall 305 79. Geological sections illlustrating the formation of the manganese ores in Arkansas. After R. A. F. Penrose 306 80. The Turner mine, Batesville region, Arkansas. After R. A. F. Penrose 807 81. Section of the Great Western cinnabar mine. After G. F. Becker. . . 310 83. Map and sections of Gap nickel mine, Penn. After J. F. Kemp 316 83. View of Copper CliB mine, Sudbury, Ontario. Photograph by T, G. White 318 94. Horizontal section of the Etta granite knob. Black Hills. After W. P.Blake 324 ABBREVIATIONS A, A. A. S.— Proceedings of the American Association for the Advance- ment of Science. A. O. or Amer. Geol. — American Geologist, Minneapolis, Minn. A. J. S. or Amer. Jour. Sci. — American Journal of Science, also known as Silliman's Journal. Fifty half-yearly volumes make a series. The Journal is now (1893) in the third series. In the references the series is given first, then the volume, then the page. Ann. des Mines. — Annates des Mines. Paris, France. Bost. Soc. Nat. Hist. — See Proceedings of same. Bull. Oeol. Soc. Amer. or O. S. A. — Bulletin of the Geological Society of America. Bull. Mus. Comp. Zool. — Bulletin of the Museum of Comparative Zoology, Harvard University. Cambridge, Mass. B. und H. Zeitung. — Berg- und Huettenmdnnische Zeitung. Leipzig, Germany. M. E. — Transactions of the American Institute of Mining Engineers. Neues Jahrb. — Neues Jahrbuch fiir Mineralogie, Geologic und Palaeon- tologie, often called Leonhard's Jahrbuch. Stuttgart, Germany. Oest. Zeit.f. Berg-u. Huett. — Oesterreichische Zeitschrift fiir Berg- und Huettenwesen. Vienna, Austria. Phil. Magazine. — Philosophical Magazine. Edinburgh, Scotland. Proc. Amer. Acad. — Proceedings of the American Academy of Arts and Sciences. Boston, Mass. Proc. and Trans. N. 8. Inst. Nat. Sci. — Proceedings and Transactions of the Nova Scotia Institute of Natural Science. Halifax, Nova Scotia. Proc. Bost. Soc. Nat. Hist. — Proceedings of the Boston Society of Nat- ural History. Boston, Mass. Proc. Colo. Sci. Soc. — Proceedings of ^he Colorado Scientific Society. Den- ver, Colo. Raymond's Reports. — Mineral Resources West of the Rocky Mountains. Washington, 1867-1876. The first two volumes were edited by J. Ross Browne, the others by R. W. Raymond. xvm ABBREVIATIONS. Trans. Min. Asso. and Inst., Cornwall. — ^Transactions of the Mining As- sociation and Institute of Cornwall. Tuckingmill, Camborn, England. Trans. N. Y. Acad, of /Sfci.— Transactions of the New York Academy of Sciences, formerly the Lyceum of Natural History. Zeit. d. d. g. Ges. — Zeitschriff der deutschen geologischen Qesellschaft. Berlin, Germany. Zeitsch. f. B., H. und S. im P. St.—Zeitschrift fur Berg-, Huetten-, und Salinenwesen im Preussischen Staat. Berlin, Germany. Zeitschr. f. Krys. — Zeitsehrift fur Krystallographie. Munich, Germany. The remaining abbreviations are deemed self-explanatory. The num- bering of the paragraphs is on the following principle : The first digit refers invariably to the part of the book, the second two digits to the chapter, and the last two to the paragraph of the chapter. PAET I. INTRODUCTORY. CHAPTER I. GENERAL GEOLOGICAL FACTS AND PRINCIPLES. 1.01.01.* In the advance of geological science the standpoints from which the strata forming the earth's crust are regarded neces- sarily change, and new points of view are established. In the last few years two have become especially prominent, and there are now two sharply contrasted positions from which to obtain a con- ception of the structure and development of the globe. The first is the physical, the second the biological. We may, for example, consider the surface of the earth as formed by rocks, differing in one part and another, and these different rocks or groups of rocks are known by different names. The names have no special refer- ence to the animal remains found in them, but merely indicate that series of related strata form the surface in particular regions. On the other hand, the rocks are also regarded as having been formed in historical sequence, and as containing the remains of organisms characteristic of the period of their formation. They illustrate the development of animal and vegetable life, and in this way afford materials for historical-biological study. In the original classifica- tion the biological and historical considerations are all-important. But when once the rocks are placed in their true position in the scale, and are named, these considerations, for many purposes, no longer concern us. The formations are regarded simply as mem- bers in the physical constitution of the outer crust. The Interna- tional Geological Congress held in Berlin in 1885 expressed these different points of view in two parallel and equivalent series of geological terms, which are tabulated on p. 4. They are now very * The numbers at the beginning of the paragraphs are so arranged that the first figure denotes the part of the book, the next two figures the chapter, and the last two the paragraph. Thus 1.06.31 means Part I., Chapter VI., Paragraph 31 under Chapter VI, 4 KEMP'S ORE DEPOSITS. generally adopted. For clearness in illustration, the equivalent terms employed by Dana are appended. Biological Terms. Physical Terms. Dana's Terms. lUustrations. Era. Group. Time. Paleozoic. Period. System. Age. Devonian. Epoch. Series. Period. Hamilton. Age. Stage. Epoch, Marcellus. The United States Geological Survey divides as follows : Era and System, Period and Group, Epoch and Formation. In consider- ing the ore deposits of the country, we employ only the physical terms. We understand, of course, the chronological position of the systems in the historical sequence, but it is of small moment in this connection what may be the forms of life inclosed in them. The purely physical character of the rocks — whether crystalline or fragmental ; whether limestone, sandstone, granite, or schists ; whether folded, faulted, or undisturbed — are the features on which we lay especial stress. In all the periods the same sedimentary rocks are repeated, and in the hand specimen it is often impossible to distinguish those of different ages from one another. The classification, briefly summarized, is as follows : 1.01.02. AKCHEAif Group. — I. Laurentian System. II. Hu- ronian System. Additional subdivisions have been introduced by Canadian and Minnesota geologists (Animikie, Montalban, etc.), and there is a tendency to group all the latter clastic members, es- pecially in the region of the Great Lakes, under the name Algon- kian. (See discussion under Example 9.) Paleozoic Group. — III. Keweenawan System. (This may be- long with the Archeau.) IV. Cambrian System: (a) Georgian Stage ; (6) Acadian Stage ; (c) Potsdam Stage. V. Lower Silurian System. (A) Canadian Series : (a) Calciferous Stage ; (S) Chazy Stage. (This will probably experience revision.) (23) Trenton Series : (a) Trenton Stage ; (b) Utica Stage ; (c) Cincinnati or Hudson River Stage. VI. Upper Silurian System. (A) Xiagara Series : (a) Medina Stage ; (J) Clinton Stage ; (c) Niagara Stage. (J?) Salina Series. ( C) Lower Helderberg Series. (Z>) Oriskany Series. (The Oriskany may be made the base of the Devonian.) YII. Devonian System. (A) Corniferous Series : (a) Cauda-Galli Stage ; {b) Schoharie Stage ; (c) Corniferous Stage. (B) Hamilton Series : (a) Marcellus Stage ; {b) Hamilton Stage ; (c) Genesee GENERAL GEOLOGICAL FACTS AND PRINCIPLES. » Stage. (C) Chemung Series : (a) Portage Stage; (5) Chemung Stage. (Z>) Catskill Series. VIII. Carboniferous System. (A) Subcarboniferous or Mississippian Series. (B) Carboniferous Series. ( C ) Permian Series. Mesozoic Group. — IX. Triassic System. X. Jurassic System. IX. and X. are not sharply divided in the United States, and we often speak of Jura-Trias. A stratum of gravel and sand, along the Atlantic coast, that contains Jurassic fossils has been called the Potomac formation by McGee. XI. Cretaceous System. Sub- divisions differ in different parts of the country. Atlantic Border : (a) Raritan Stage ; (b) New Jersey Greensand Stage. Gulf States : (a) Tuscaloosa Stage ; (S) Eutaw Stage ; (c) Rotten Limestone Stage ; (d) Ripley Stage. Rocky Mountains : (a) Comanche Stage ; (5) Dakota Stage ; (c) Benton Stage ; (d) Niobrara Stage ; (e) Pierre Stage ; (/) Fox Hills Stage ; {g) Laramie Stage. Stages (c), (d), (e), and (/) are sometimes collectively called the Colorado Stage. Pacific coast : (a) Shasta Stage ; (b) Chico Stage ; (c) Tejon Stage. The Tejoii is now regarded as Eocene. Cenozoic Geoup. — XII. Tertiary System. (A) Eocene or Alabama Series : Gulf States, (a) Claiborne St3,ge ; {b) Jackson Stage ; (c) Vicksburg Stage. Western States, (a) Puerco Stage ; (b) Wasatch Stage ; (c) Wind River Stage ; (d) Bridger Stage ; (e) Uintah Stage. {£) Miocene or Yorktown Series, including perhaps the Sumter of the Atlantic Border. On the Pacific Slope it has the following : (a) White River Stage ; (b) John Day Stage ; (c) Loup Fork Stage. ( C) Pliocene Series. (Of doubtful Ameri- can determination.) XIII. Quaternary System. (A) Glacial Series. (B) Champlain Series. ( C) Terrace Series. (Z>) Recent Series. Pleistocene is sometimes employed as a name for the early Quaternary, especially south of the Glacial Drift; In accord with tlie practice of the U. S. Geological Survey, the Tertiary is now generally divided into the Eocene and the Neocene (including Miocene and Pliocene) series. Other terms are also often used, especially when we do not wish to speak too definitely. "Formation" is a word loosely employed for any of the above divisions. "Terrane" is used much in the same way, but is rather more restricted to the lesser divisions. A stratum is one of the larger sheet-like masses of sedimentary rock of the same kind; a bed is a thinner subdivision of a stratum. " Horizon " serves to indicate a particular position in the geologi- cal column ; thus, speaking of the JMarcellus Stage, we say that shales of this horizon occur in central New York. 6 KEMPS ORE DEPOSITS. 1.01.03. The rock species themselves are classified into three great groups — the Igneous, the Sedimentary, and the Metamor- phic. The Igneous (synonymous terms, in whole or in part: mas- sive, eruptive, volcanic, plutonic) include all those which have so- lidified from a state of fusion. They are marked by three types of structure — the holo-crystalline, the porphyritic, and the glassy, depending on the circumstances under which they have cooled. Under the first type of structure come the granites, syenites, dio- rites, gabbros, diabases, and peridotites; under the second, quartz- porphyries, rhyolites, porphyries, trachytes, porphyrites, andesites, and basalt; under the third, pitchstone, obsidian, and other glasses. The Sedimentary rocks are those which have been deposited in water. They consist chiefly of the fragments of pre-existing rocks and the remains of organisms. They include gravel, conglom- erate, breccia, sandstone, — both argillaceous and calcareous, — shales, clay, limestone, and coal. In volcanic districts, and especially where the eruptions have been submarine, extensive deposits of volcanic lapilli and fine ejectments have been formed, called tuffs. With the sedimentary rocks we place a few that have originated by the evaporation of solutions, such as rock salt, gypsum, etc. The Metamorphic rocks are usually altered and crystallized members of the sedimentary series, but igneous rocks are known to be subject to like change, especially when in the form of tuffs. They are all more or less crystalline, more or less distinctly bedded or laminated, of ancient geological age or in disturbed districts. They include gneiss, crystalline schists, quartzite, slate, marble, and serpentine. After a brief topographical survey, we shall employ the above terms to summarize the geological structure of the United States. The several purely artificial territorial divisions are made simply for convenience. Nothing but intelligent travel will perfectly ac- quaint one with the topographical and geological structure of the country, and in this connection Maefarlane's " Geological Railway Guide " and a geological map are indispensable. 1.01.04. On the east we note the great chain of the Appalachi- ans, with a more or less strongly marked plain between it and the sea. This is especially developed in the south, and is now generally called the Coastal Plain. It is of late geological age and contains the pine barrens and seacoast swamps. The Appalachians thern- Belves consist of many ridges, running on the north into the "White GENERAL GEOLOGICAL FACTS AND PRINCIPLES. 7 Mountains, the Green Mountains, and the Adirondaoks. Farther south the Highlands of New York and New Jersey, the South Mountain of Pennsylvania, the Alleghanies, the Blue Ridge, and the other southern ranges make up the great eastern continen- tal mountain system. In western New York and Ohio we find a rolling, hilly country; in Kentucky and Tennessee, elevated table- land, with deeply worn river valleys. Indiana, Illinois, Iowa, and Missouri contain prairie and rolling country, more broken in southern Missouri by the Ozark uplift. In Michigan, Wisconsin, and Minne- sota the surface is rolling and hilly with num^erous lakes. In Ar- kansas, Louisiana, and Mississippi there are bottom lands along the Mississippi and Gulf, with low hills back in the interior. Across Arkansas and Indian Territory runs the east and west Ouachita uplift. West of these States comes the great billowy prairie region, and then the chain of the Rocky Mountains, consisting of high, dome-shaped peaks and ridges, with extended elevated valleys (the parks) between the ranges. Some distance east of the main chain are the Black Hills, made up of later concentric formations around a central, older nucleus, and also the extinct volcanic dis- trict of the Yellowstone National Park. In western Colorado, Utah, and New Mexico, between the Rocky Mountains and the Wasatch, is the Colorado plateau, an elevated tableland. This is terminated by the north and south Wasatch range and is traversed east and west by the Uintah range. West of this lies the region called the Great Basin, characterized by alkaline deserts, and subordinate north and south ranges of mountains. Next comes the chain of the Sier- ra Nevada, and lying between it and the Coast range is the great north and south valley of California. This rises in the compara- tively low Coast range, which slopes down to the Pacific Ocean. To the north, these mountains extend into eastern Oregon and Washington, with forests and fertile river valleys. These topograph- ical features are important in connection with what follows, for the reason that the ore deposits especially favor mountainous regions. Mountains themselves are due to geological disturbances — upheav- al, folding, faulting, etc. — and are often accompanied by great ig- neous outbreaks. They therefore form the topographical surround- ings most favorable to the development of cavities, waterways, and those subterranean, mineral-bearing circulations which would fill the cavities or replace the rock with useful minerals. 1.01.05. Geological Outline. I. iV^ew Migland, New York, New Jersey, and Eastern Pennsylvania District. — In New Eng- 8 KEMP'S ORE DEPOSITS. land and northero New Tork the Archean is especially devel- oped, forming the White Mountains, the Adirondacks, and the Highlands of New York and New Jersey. These all consist of granite and other igneous rock, of gneiss, and of crystalline schists. There are also great areas of metamorphic rocks whose true age may be later. The Green Mountains are formed of such, and were elevated at the close of the Lower Silurian. In New England there are small, scattered exposures of the undoubted Paleozoic (Devo- nian, Carboniferous). In eastern New York, and to some extent in New Jersey and eastern Pennsylvania, the entire Paleozoic, except the Carboniferous, is strongly developed. Up and down the coast there are narrow north and south estuary deposits of red Jura-Tri- as sandstone, which are pierced by diabase eruptions. The Creta- ceous clays are strong, and Tertiary strata occur at Martha's Vine- yard, in Massachusetts, while over all as far south as Trenton is found the glacial drift. Between the Archean ridges of the High- lands and the first foldings of the Paleozoic on the west is found the so-called Great Valley, which also runs to the south and is a very important topographic and geologic feature. It follows the outcrop of the Siluro-Cambrian limestones, to whose erosion it is due. II. Eastern- Middle and Sovtheastern Coast District. — The low plains of the coast are formed by Quaternary, Tertiary, and Cretaceous, consisting of gravel, sand, shell beds, and clay. In- land there are exposures of Jura-Trias, as in the north. The Ar- chaean crystalline rocks are also seen at numerous points not far from the ocean. Florida is largely made up of limestones, with a mantle of calcareous sand. III. Alleghany Region and the Central Plateau. — The Ap- palachian mountain system, from New York to Alabama, con- sists principally of folded Paleozoic (largely Carboniferous), with Archean ridges on its eastern flank. There is an enormous devel- opment of folds, with northeast and southwest axes. On the west chey are succeeded by the plateau region of Kentucky and Tennes- see, chiefly Paleozoic. Along central latitudes the Archean does not again appear east of the Mississippi. IV. Region of the Great Lakes. — In Michigan, "Wisconsin, and Minnesota the Archean rocks are extensively developed, both Laurentian and Huronian. Around Lake Superior are found the igneous and sedimentary rocks of the Keweenawan, followed by the lower Paleozoic. Lake Michigan and Lake Huron are sur- rounded by Silurian, Devonian, and Carboniferous; Lake Erie, by GENERAL GEOLOGICAL FACTS AND PRINCIPLES. 9 Devonian ; Lake Ontario, by Silurian. Running south through Ohio, we find an important fold known as the Cincinnati uplift, with a north and south axis. It was elevated at the close of the Lower Silurian. In the lower peninsula of Michigan and in eastern Ohio and western Pennsylvania the Carboniferous is extensively developed. V. Mississippi Valley. — The head waters of the Mississippi are in the Aichean. It then passes over Cambrian and Silurian strata in Minnesota, Wisconsin, northern Iowa, and Illinois, which in these States lie on the flanks of the Archean "Wisconsin Island " of central Wisconsin. These are succeeded by subordi- nate Devonian, and in southern Iowa, Illinois, and Missouri by Car- boniferous. In southern Missouri the Lower Silurian forms the west bank. Thence to the Gulf the river flows on estuary deposits of Quaternary age, with Tertiary and Cretaceous farther inland. VI. Gidf Region. — The Gulf States along the water front are formed by the Quaternary. This is soon succeeded inland by very extensive Tertiary beds, which are the principal formation repre- sented. > VII. Prairie Region. — West of the. Paleozoic rocks of the States bordering on the Mississippi is found a great strip of Creta- ceous running from the Gulf of Mexico to and across British America, and bounded on the west by the foothills of the Rocky Mountains. A few Tertiary lake deposits are found in it. Quite extensive Triassic rocks are developed on the south. The surface is a gradually rising plateau to the Rocky Mountains. VIII. Region of the Rocl-y IIoimtaiuK, the Black Hills, and the Yellowstone National Park. — The Rocky Mountains rise from the prairies in long north and south ranges, consisting of Archean axes with the Paleozoic in i-elatively small amount, but with abun- dant Mesozoic on the east and west flanks. In the parks are found lake deposits of Tertiary age. There are also great bodies of igne- ous rocks, which attended the various upheavals. The principal upheavals began at the close of the Cretaceous. The outlying Black Hills consist of an elliptical Archean core, with concentric Paleozoic and Mesozoic strata laid up around it. The National Park consists chiefly of igneous (volcanic) rocks in enormous development. IX. Colorado Plateau. — The Rocky Mountains shade out on the west into a great elevated plateau, extending to central Utah, where it is cut off by the north and south chain of the Wasatch. 10 KEMP'S ORE DEPOSITS. The Uintah Mountains are an east and west chain in its northern portion. The rocks on the north are chiefly Tertiary, with Meso- zoic and Paleozoic in the mountains. To the south are found Cretaceous and Triassic strata, with igneous rocks of great extent. The principal upheaval of the Wasatch hegan at the close of the Carboniferous and seems still to be in progress. X. Region of the Great Basin. — Between the Wasatch and the Sierra Nevada ranges is found the Great Basin region, once lake bottoms, now very largely alkaline plains of Quaternary age. The surface is diversified by subordinate north and south ranges, formed by great outflows of eruptive rocks, and by tilted Paleozoic. The ranges are extensively broken and the stratified rocks often lie in confused and irregular positions. There is Jio drainage to the ocean. XI. Region of the Pacific Slope. — The depression of the Great Basin is succeeded by the heights of the Sierra Nevada. On the west the Sierras slope down into the Central Valley of California. The flanks are largely metamorphosed Jurassic and Cretaceous rocks with great developments of igneous outflows. The surface rises again in the Coast ranges, which slope away farther west to the ocean. In addition to the Jurassic and Cretaceous, the Tertiary and Quaternary are also developed, and in the Coast ranges are many outflows of igneous rock. The principal upheaval of the Sierra Nevada began at the close of the Jurassic, that of the Coast range at the close of the Miocene Tertiary. XII. Region of the iVbriAwesi.— Washington and Oregon, along the coast, are formed by Cretaceous and Tertiary strata similar to California. But inland, immense outpourings of igneous rocks cover the greater portion of both States and extend into Idaho. On the north the Carboniferous is extensive, running east- ward into Montana. Quaternary and Tertiary lake deposits are also not lacking. 1.01.06. On the Forms Assumed hy Rock Masses. — All sedimen - tary rocks have been originally deposited in beds, approximately horizontal. They are not of necessity absolutely horizontal, be- cause they may have been formed on a sloping bottom or in a delta, in both of which cases an apparent dip ensues. We find them now, however, in almost all cases changed from a horizontal posi- tion by movements caused primarily by the compressive strain in the earth's crust. Beds thus assume folds known as monoclines, anticlines, and synclines. GENERAL QEULOOICAL FACTS AND PRINCIPLES. 11 A monocline is a terrace-like dropping of a bed without changing the direction of the dip. There is usually a zone, more or less shattered, along the folded portion, and such a zone may become a storage receptacle. Monoclines of a gentle character in Ohio, which have been detected by Orton in studies of natural gas, have been called "arrested anticlines." An anticline is a convex fold with opposing dips on its sides, while a syncline is a concave fold with the dips on its sides coming together. We speak of the axis of a fold, and this marks the general direction of the crest or trough. The axis is seldom straight for any great distance. Folds are often broken and faulted across the strike of their axes, and this causes what is called a "pitch" of the axes and makes the original dips run diagonally down on the final one. Folds are the primary cause of the phenomena of dip and strike. Horizontal beds have neither. A dome-like elevation of beds, with dips radi- ating in every direction from its summit, is called a quaquaversal, but it is a rare thing. An anticline or syncline with equal dips on opposite sides of its axes is called a normal fold. If the dip is steeper on one side than on the other, it is an overthrown fold ; if the sides are crushed together, it is a collapsed or sigmoid fold. Igneous rocks are in the form of sheets (the term " bed " should be restricted to sedimentary rocks), knobs or bosses, necks, lacco- lites, and dikes. A sheet is the form naturally assumed by surface flows, and by an igneous mass which has been intruded between beds. It has relatively great length and breadth as compared with its thickness, and coincides with its walls in dip and strike. A knob, or boss, is an irregular mass, of approximately equal length and breadth, which may be related in any way to the position of its walls. Such masses are often left projecting by erosion. A neck is the tilled conduit of a volcano, which sometimes remains after the overlying material has been denuded. A laccolite is a lenticular sheet which has spread between beds radially from its conduit, and thus has never reached the surface, unless re- vealed by subsequent erosion. A dike is a relatively long and narrow body of igneous rock which has been intruded in a fissure. It is analogous to a vein, but the term " vein " ought not to be ap- plied to an undoubtedly igneous rock. Some granitic mixtures, however, of quartz, feldspar, and mica, leave us yet in uncertainty as to whether they are dikes or veins. (See Example 51.) From the above it will be seen at once that bosses, knobs, and necks may be practically indistinguishable. CHAPTER II. ON THE FORMATION OF CAVITIES IN ROCKS. 1.02.01. By Local Contraction. — In the contraction caused by cooling, drying, or hardening, both igneous and sedimentary rocks break into more or less regular masses along division planes, called joints, or diaclases. Numerous cracks and small cavities are thus formed. Basaltic columns, or the prismatic masses, formed by the separation, in cooling and consolidating, of the heavier basic rocks, along planes normal to the cooling surface, are good illustra- tions of the first. Larger manifestations of them often become filled with zeolites, calcite, and other secondary minerals. Granitic Fig. 1. — Illustration of rifting in granite at Cape Ann, Mass. After B. 8. Tarr. rocks and porphyries break up less regularly from the same cause, but still exhibit prismoids and polygonal blocks and benches. (J. P. Iddings' paper on "The Columnar Structure in the Igneous Rocks on Orange Mountain, IST. J.," Amer. Jour. Sci., III., xxxi. 320, is an excellent discussion.) Large cracks have been referred to this cause, which have afterward formed important receptacles for ores. (See Example 11a.) Very small microscopic cracks may occasion lines of weakness and brecciation which are not readily apparent. They afford a cleavage, called rifting, but are not well understood. (See R. S. Tarr, " On Rifting in Cape Ann Granites," Amer. Jour. Sci., April, 1891.) Joints are generally prominent in ON THE FORMATION OF CAVITIES IN ROCKS. 13 sedimentary rocks, and probably afford many of the regular planes of separation which, are often seen crossing one or several beds. They are chiefly due to drying and consolidation. Both the joints formed by cooling and those formed by drying may be afterward modified or increased by rock movements, so that it may be a matter of difficulty to decide between the two forms of origin. The undulatory tremors of an earthquake have been cited, with great reason, by W. O. Crosby as a prolific cause of joints.* 1.02.02. Cavities Formed by More Extensive Movements in the Earth's Crust. — The strains induced by the compression in the outer portion of the earth are by far the most important causes of fractures. The compression develops a tangential stress which is resisted by the archlike disposition of the crust. (By the term " crust " is simply meant the outer portion of the globe without reference to the character of the interior.) Where there is insuf- ficient support, gravity causes a sagging of the material into syn- clinals, which leave salient anticlinals between them. Where the tangential strain is also greater than the ability of the rocks to resist, they are upset and crumpled into folds from the thrust. Both kinds of folds are fruitful' causes of fissures, cracks, and general shattering, and every slip from yielding sends its oscilla- tions abroad, which cause breaks along all lines of weakness. The simplest result, either from sagging or from thrust, is a fissure, on one of whose sides the wall has dropped, or on the other of which it has risen, or both, as will be more fully described under "Faults." If the rocks are firm and quite thickly bedded, as is the case with limestones and quartzites, the separation is cleanly cut ; but if they are softer and more yielding, they are sheared downward on the stationary or lifting side, and upward on the one which rela- tively sinks. Such fissures may pass into folds along their strike, as at Leadville, Colo. *In addition to the usual text-books the following references may be consulted : W. O. Crosby, "On the Origin of Jointed Structures," Boston Soc. Nat. Hist., XXII., October, 1882, p. 73; Amer. Jour. Sci., III., xxv. 4'i6;Q. K. Gilbert, " On the Origin of Jointed Structures," Amer. Jour. Sci., III., xxiv. 50, and xxvii. 47; J. H. Kinahan, Valleys, and their Relations to Fissures, Fractures, and Faults, London, Trubner & Co. See also a short letter in the Amer. Jour. Sci., III., xxiv., p. 68, on the " Origin of Jointed Structures;" J. Leconte, "Origin of Jointed Structure in Undis- turbed Clay and Marl Deposits," Amer. Jour. Sci., III., xxiii. 233; W. J. McGee, "On Jointed Structure," Amer. Jour. Sci., III., xxv. 152, 476. 14 KEMP'S ORE DEPOSITS. 1.02.03. A phenomenon which is especially well recognized in metamorphic regions, and which is analogous to those last cited, is furnished by the so-called " shear zones." A faulting move- ment, or a crush, may be made apparent by changes in mineralogi- cal composition and structure. Massive diabases, for instance, pass into hornblende-schists or amphibolites for limited stretches. Garnets and other characteristically metamorphic minerals ap- pear, and pyroxenes alter to amphiboles. Strains are manifested in the optical behavior of the minerals in thin sections of specimens taken from such localities. These crushed strips, or shear zones, may be formed with very slight displacement, but they aflPord favorable surroundings for the formation of ore bodies. This con- ception of the original condition of a line of ore deposition is a growing favorite with recent writers, and combined with the idea of replacement is often applicable. (See Example 17, Butte, Mont.) Fahlbands, which are very puzzling problems, may have originated as shear zones. 1.02.04. A more extended effect is produced by the mono- cline, which has a double line of shattered rock marking both the crest and the foot of its terrace. Anticlines and synclines occasion the greatest disturbances. Comparatively brittle materials like rocks cannot endure bending without suffering extended fractures. When sirained beyond their limit of resistance, along the crest of an anticline and in the trough of a syncline, cracks and fractures are formed which radiate from the axis of each fold. As these open upward and outward in anticlines, they become the easiest points of attack for erosion, so that it is a very common thing to find a stream flowing in a gorge, which marks the crest of an anticline, while synclinal basins are frequently left to form the summits of ridges, as is so markedly the case in the semi-bituminous coal basins of Pennsylvania. It is quite probable, however, that the anticline may have been leveled off at this fissured crest because it was up- heaved under water and became exposed at its vulnerable summit to wave action. Ore deposits may collect in these fissured strips, of which the lead and zinc mines of the upper Mississippi Valley (Example 24) are illustrations. Such fissures are peculiar in that they exhibit no displacement. The accompanying figure is from a photograph of a gaping crack in the Aubrey (Upper Carboniferous) limestone, twenty-five miles north of Caflon Diablo station, Ariz., on the At- lantic and Pacific Railroad. It was caused by a low anticlinal ON THE FORMATION OF CAVITIES IN ROCKS. 15 roll, and contained water about one hundred feet below the top. Its reproduction of the conditions of a vein, with horse, pinches and swells, devious course, and all, is striking. The photograph was made by Mr. G. K. Gilbert, of the United States Geological Survey, and to his courtesy its use is due. Fig. 3. — Ojjen fissure in the Aubrey limestone (Upper Carhoniferons), 35 -^niles north of Canon Diablo station, Ariz., on the A. & P. R. R. Photogriqilu'it by 0. K. (Hlbert. 1?92. While it is true that in many regions the folds and fractures have resulted in this simple way, and exhibit the unmistakable course through which they have passed, yet geological structure is by no means always so clear. ExtemliMl disturbances, gi-eat faults and displacements, combined with folds and the intrusion nf 16 KEMFS ORE DEPOSITS. igneous rocks, have often so broken up a district that it is a matter of much difficulty to trace out the course through which it has passed. Subsequent erosion, or the superposition of heavy beds of gravel or forest growths, etc., may so obstruct observation even of the facts as to add to the obscurity. The expense of making and the consequent scarcity of accurate contour maps to assist in such work are other obstacles. The profound dynamic effects wrought by mountain-making processes, although in individual cases pro- ducing only the simpler phenomena already cited, yet in general are much more extensive, and must be considered in the study of many large districts. When folds are the result of compression or thrust, the dynamic effects are more marked than in those formed by sagging. Faults are larger and more abundant. When sedi- mentary beds have been laid down along an older axis of granite or some equally resistant rock and the thrust crowds the beds against this axis, the conditions are eminently favorable to great fracturing and disturbance. The flanks of the Rocky Mountains furnish such examples. 1.02.05. There are also great lines of weakness in the outer portion of the earth, which seem to have been the scene of fault- ing movements from a very early period. Thus on the western front of the Wasatch Mountains, in Utah, is a great line of weak- ness, that was first faulted, as nearly as we can discover, in Archean times, and has suffered disturbances even down to the present. A few instances of actual movements within recent years have been recorded. In 1889 a sudden small fold and fissure developed under a paper mill near Appleton, Wis., and heaved the building four and a half inches. (See F. Cramer, "Recent Rock Flexure," Amer. Jour. Set., III., xxxix. 220.) This occurred in what was regarded a settled region and one not liable to disturb- ance. 1.02.06. Wherever igneous rocks form relatively large por- tions of the globe they necessarily share extensively in terrestrial disturbances. Not being often in sufficiently thin sheets, they rarely furnish the phenomena of dip and strike. Folds are largely wanting. They are replaced by faults and shattering. The fis- sures thus formed are at times of great size and indicate impor- tant movements. The Comstock Lode fissure is four miles long and in the central part exhibits a vertical displacement of three thousand feet. (See 2.11.1 9.) Such fissures seldom occur alone, but minor ones are found on each side and parallel with the main one. ON THE FORMATION OF CAVITIES IN ROCKS. 17 • 1.02.07. The intrusion of igneous dikes may start earthquake vibrations which fracture the firm rock masses. Fissures caused in this way radiate from the center of disturbance or else appear in concentric rings. The violent shakings which so often attend great volcanic eruptions, and the sinking of the surface from the removal of underlying molten material, all tend to form cracks f / X X ''sV\ V « » "Ix" .« * '/x"x ^ _ix:«\ " " \i 35 « ' " w< X X Fig. 3. — Normal fault at Leadville, Colo. After A. A. Blow, and cavities. They are possible causes which may well be borne in mind in the study of an igneous district. 1.02.08. Faults. — When fractures ha\'e been formed by any of the means referred to above, and the opposite walls slip past each other, BO as not to corresjjond exactly at all horizons, they arc called "faults," a terra which indicates this lack of correspondence. The separation is chiefly due to the relative slipping down or sink- ing of one side. The distance through which this has taken place is called the amount of displacement, or throw. Faults are most commonly inclined to the horizon, so that there is both a vertical and a horizontal displacement. What would be the dip of an in- clined stratum is in a fault now generally known as the "hade," although the word formerly had a different meaning. Experience has shown that where beds or veins encounter faults and opera- 18 KEMP'S ORE DEPOSITS. tions are brought to a standstill, the continuation is usually found as follows, according to Schmidt's law. If the fault dips or hades away from the workings, the continuation is down the hade ; if it dips toward the workings, it should be followed upward. Such a fault is called a normal fault, and is illustrated in the figure on IX 17, after A. A. Blow. This is a natural result of the draw- ing apart of the two sides. The least supponed mass would nWp down on the one which has the larger base. Less commonly the opposite movement results. Thus when the fault is due to com- pression, the beds pass each other in the reverse direction, and what is called a reversed fault results. The accompanying cut il- lustrates a very extended one in the southern Appalachians. While we would naturally think of a reversed fault as resulting r—^-HS^^^''^:;^^^^ ~~^"5~5r Coivnasauga. Shales TTv^ Cohuttoy Contjlomecate Ocoee Slate JCnax Dolomite Fig. 4:.— Reversed fault at Holly Creek, near Dalton, Ga. After C. W- Hayes, Bull. G. S. A., Vol, II., PI. 3, p. 152. from a compressive strain, in that in this case the lower wedged- shaped portion would be forced under the upper one, yet normal faults can likewise, in instances, be explained by compression. If we consider the fault to be caused by the vertical thrust or com- ponent, that would always be present in the compression of a completely supported arch, this would tend to heave upward the portion next the fissure, that had the larger base. Along an in- clined fracture such portion is manifestly the under one. It is also important to note whether the fault plane, both in normal and in reversed faults, cuts inclined beds in the direction of the dip or across it. (See Margerie and Heim, DisloJcation der Erdrinde Zurich, 1888.) 1.02.09. The movement of the walls on each other produces grooves and polished sui-faces called slickensiJes, or slips. Thev ON THE FORMATION OF CAVITIES IN ROCKS. 19 are usually covered with a layer of serpentine or talc or some such secondary product. The strain caused by the movement may in rare instances leave the slips in such a state of tension that when, from any cause such as excavation, the pressure is relieved, they will scale off with a small explosion. (See A. Strahan, " On Exjjlosive Slickensides," Geological Magazine, iv. 401, 622.) Ob- servations on the directions of slips may, in cases of doubt, throw some additional light on the direction of the movement which caused the fault. But the best guide in stratified rocks is a knowl- edge of the succession of the beds as revealed by drill cores or ex- cavations. Attempts have been made to deduce mathematical formulas for the calculation of the amount of downthrow or up- throw, and when sufficient data are available, as is often the case in coal seams, this may be done. The methods depend on the projection of the planes in a drawing, on the jjrinciples of analytical geometry, and on the calculation of the displacements by means of spherical trigonometr}'. (See G. Koehler, Die Storuiujen der Gdnge, ITotze unci Lager, Leipzig, 1886 ; William Engelmann. A transla- tion by W. B. Phillips, entitled, "Irregularities of Lodes, Veins, and Beds," appeared in the Engineering and Mining Journal, June 25, 1887, p. 454, and July 2, 1887, p. 4. A very excellent paper, having a quite complete bibliography, is F. T. Freeland's "Fault Rules," M. E; June, 1892.) Prof. Hans Hoefer has called attention to the fact that in faulting there is frequently a greater displace- ment in one portion of the fissure than in a neighboring 2jart, and even a difference of hade. This causes a twisting or circular move- ment of one wall on the other, and needs to be allowed for in some calculations. ( Oestereich. ZeitRchrift fiir Herg- und Huettenvesen, Vol. XXIX. An abstract in English is given by R. "W Raymond, M. E; February, 1882.) In the Engineering und Mining Journal for April and May, 1892, a quite extended discussion of faults by several jirominent American mining engineers and geologists is given, apropos of the question raised by Mr. J. A. Church as to whether fissure veins are more regular on the dip or on the strike. In a relatively uniform masnivo rook the regularity should be greater on the dip, but in inclined and diversified stratified rocks tiio many variables enter to warrant any sweeping assertions. In soft r(joks like shales the fissure may become so split into small stringers as to be valueless. Again, in very firm rock, where there is little drawing apart, the fissure may be very tight. In the veins of Xewman Hill, near Rico, Colo, (see 2.00.10), the fissure is so 20 KEMPS ORE DEPOSITS. narrow above a certain stratum as practically to fail. Quartzite is a favorable rock for sucb effect. Despite all rules, faults are often causes of great uncertainty, annoyance, and expensive ex- ploration. 1.02.10. If a number of faults succeed one another in a short distance they are called " step faults." An older and completed vein may also be faulted by one formed and filled later. In such a case the continuous one is the younger. The figure below will illustrate each case. At the intersection of the two, the later vein is often richer than in other parts. 1.02.11. If a faulted series of rocks is afterward tilted and eroded, so as to expose a horizontal section across the strike of the faulting plane, an apparent horizontal fault may result ; or if the erosion succeeds normal faulting and lays bare two unconformable beds each side of the fissure, a lack of correspondence in plan as Fig. 5. — Illustration of one vein faulting another at Newman Hill, near Rico, Colo. After J. B. Farish, Proa. Colo. Sei. Soc, April 4, 1892. well as in section may be seen. Faulting fractures are seldom straight ; on the contrary, they bend and corrugate. When the walls slip past each other, they often stoj) with projection opposite projection, and depression opposite depression. These irregularities cause pinches and swells in the resulting cavity, and constitute one of the commonest phenomena of veins. Fissures also graduall}- pinch out at their extremities, or break up into various ramifica- tions that finally entirely cease. They also pass into folds, as stated above. 1.02.12. Secondary/ Ilodificatioiis of Cavities. — Fractures and cavities of all sorts speedily become lines of subterranean drainage. The dissolving power of water, and to a much smaller degree its eroding power, serve to modify the walls very greatly. An en- largement may result, and what was j^erhaps a small joint or fis- sure may become a waterway of considerable size. This is especially true in limestones, in which great caverns (like the ON THE FORMATION OF CAVITIES IN BOCKS. 21 Mammoth Cave and Luray's Cave) are excavated. Caves are, however, almost always due to surface waters, and do not extend below the permanent water level unless they have been depressed after their formation. (See J. S. Curtis, Monograph VTI., U. S. Geol. Survey/, Chap. VIII.) The solvent action of water is vastly augmented by the car- bonic acid which it gathers from the atmosphere, and this is the chief cause of the excavations wrought by it in limestones. Pure cold water has comparatively small dissolving and almost no ero- sive power. It has also been advocated that various acids which result from the decay of vegetable matter aid in such results. (A. A. Julien, Amer. Asso. Adv. Set., 18T9, p. 311.) This may be true, but in general carbonic acid is the chief agent. Iron in minerals falls an easy prey, as well as calcium, and is dissolved out in large amount. (See Example 1.) When charged with alkaline carbon- ates, water has the power to attack other less soluble minerals, such as quartz and the silicates, and by such action the walls of a cavity in the crystalline rooks may be much affected. 1.02.13. Waters percolating to great depths in the earth, or circulating in regions of igneous disturbances, become highly heated, and this too at great pressure. Under such circumstances the solvent action is very strongly increased, and all the elements present in the rock-making minerals are taken into solution. Alkaline carbonates are formed in quantity ; silica is easily dis- solved ; alkaline sulphides result in less amount ; and even the heaviest and least tractable metals enter into solution, either in the heated waters themselves, or in the alkaline liquors formed by them. The action on the walls of cavities and courses of drainage is thus profound, and accounts for the frequent decomposed character of the walls and the general lack of sharpness in their definition. The vast amount of siliceous material, etc., deposited by hot springs and geysers is additional evidence of its importance. Magnesia is one of the alkaline earths readily taken into solu- tion by carbonated waters, and when such waters again meet lime- stone the effect is often very great, and constitutes one of the most important methods of the formation of cavities. Solutions of magnesium carbonate, on meeting calcium carbonate, effect a par- tial exchange of the former for the lattei-. This leaves the rock a double car.bonate of calcium and magnesium, which is the composi- tion of the mineral and rock dolomite. The process is therefore called dolomitization. (See Exan^ple 25.) It may bring about a 22 KEMPS ORE DEPOSITS. general shrinkage of eleven or twelve per cent. In any extended thickness of strata this would cause vast shattering and porosity. As an illustration of its results, the following analyses of normal, unchanged Trenton limestone of Ohio, and of well drillings from the porous, gas-hearing, dolomitized portions of the same, are given. They are taken from a paper hy Edward Orton. {Amer. Manvf. and Iron World, Pittshurg, Dec. 2, 1887.) CaCO,.- MgCOs. Fe, ,03.A1,03. SiO,. Unchanged Trenton limestone.. .79.30 0.93 7.00 12.00 " " ...82.86 1.67 0.58 12.34 Dolomitized " " ...53.50 48.50 1.25 1.70 ...51.78 36.80 1.02.14. Late studies in ore deposits hy Posepny, Curtis, and Emmons indicate also that solutions of metallic ores may effect an interchange of their contents with the carhonate of calcium or magnesium, in limestones and dolomites, leaving an ore body in place of the rocks. This change is effected molecule by molecule, and is spoken of as a metasomatic interchange or replacement. (See Example 30.) By "metasomatic" is meant an interchange of substance without, as in pseudomorphs, an imitation of form. Alteration of the metallic ores may follow and occasion cavities from shrinkage. (See Example 36, and Cui-tis, on Eureka, Nev., Monograph VII., TT. S. Oeol. Survey, Chap. VIII.) CHAPTER III. THE MINERALS IMPORTANT AS ORES ; THE GANGUE MINERALS, AND THE SOURCES WHENCE BOTH ARE DERIVED. 1.03.01. The minerals which form the sources of the metals are almost without exception included in the following compounds : the sulphides, the related compounds of arsenic and antimony, ox- ides and oxidized compounds such as hydrous oxides, carbonates, sulphates, phosphates, and silicates, and one or two compounds of chlorine. A few metals occur in the native state. All the other mineral compounds such as a chromate or two, a bromide or iodide, etc., are rarities. It may be said that nine tenths of the produc- tive ores are sulphides, oxides, hydroxides, carbonates, and na- tive metals. The ores of each metal are subsequently outlined before its particular deposits are described. 1.03.02. The most common gangue mineral is quartz, while in less amount are found calcite, siderite, barite, fluorite, and in places feldspar, pyroxene, hornblende, rhodonite, etc. The silicates are chiefly present where the gangue is a rock and the ore is dis- seminated through it. All the common rocks serve in this capaci- ty in one place or another. 1.03.03. Source of the Metals. — The metallic contents of the minerals which constitute ores must logically be referred to a source, either in the igneous rocks or in the ocean. If the nebular hypothesis expresses the truth, — and it is the best formulation that we have, — all rocks, igneous, sedimentary, and metamorphic, must be traced back to the original nebula. This, in cooling, afforded a fused magma, which chilled and assumed a structure analogous to the igneous rocks with which we are familiar. Igneous rocks must thus necessarily be considered to have furnished by their erosion and degradation the materials of the sedimentary rocks ; while igneous and sedimentary have alike afforded the substances whose alterations have produced the metamorphic rocks. It may also be true that eruptive rocks, especially when basic, have been 24 KEMPS ORE DEPOSITS. formed, by the oxidation and combination with silica, of inner metallic portions of the earth, for such is one of our most reason- able explanations of volcanic phenomena, suggested alike by the composition of basalts, by the high average specific gravity of the globe, and by analogy with meteorites. 1.03.04. As opposed to this conception, there are those who would derive the metallic elements of ores from the ocean, in which they have been dissolved from its earliest condensation. Thus it is said that substantially all the metals are in solution in sea water. From the sea they are separated by organic creatures, it may be, through sulphurous j)recipitation, attendant on the de- cay of their dead bodies. The accumulations of the remains of organisms bring the metals into the sedimentary strata. Once thus entombed, circulation may concentrate them in cavities. When present in igneous rocks, the latter are regarded as derived from fused sediments. If the metallic contents of sedimentary rocks do not come from the ocean in this way, the igneous rocks as outlined above are the only jjossible source. No special men- tion is here made of the metamorphic rocks, because in their origi- nal state they are referable to one or the other of the two remain- ing classes. But it is not justifiable, in the absence of special proof, to consider them altered sediments, any more than altered igneous rocks, and it is doubtless true that the too generally and easily admitted sedimentary origin for our gneisses and schists has materially hindered the advance of our knowledge of them in the last forty years. 1.03.05. Microscopic study of the igneous rocks has shown that, with few exceptions, the rock-making minerals separate from a fused magma on cooling and crystallizing, in a quite definite ordei'.' Thus the first to form are certain oxides, magnetite, spec- ular hematite, ilmenite, rarely chromite and picotite, a few sili- cates, unimportant in this connection (zircon, titanite), and the sulphides pyrite and pyrrhotite. Kext after these metallic oxides, etc., the heavy, dark-colored, basic silicates, olivine, biotite, au- gite, and hornblende, are formed. All these minerals are character- ized by high percentages of iron, magnesium, calcium, and alumi- num. They are very generally provided with inclusions of the first set. Following the bisilicates in the order of crystallization, 1 H. Eosenbusch, "Ueber das Wesen der Kornigen und Porphyrischen Structur bei Massengesteine," Neues Jahrbuch, 1883, ii., I. THE MINERALS IMPORTANT AS ORES, ETC. 35 come the feldspars, and after these, when some residual silica re- mains uncombined, it separates as quartz. 1.03.06. If we regard the igneous rocks as the source, the metallic elements are thus to be ascribed to the first and second series of crystallizations, while the elements of the gangue minerals are derived from the last three. It is a doubtful point whether the less common metals, such as copper, silver, and nickel, enter into the composition of the dark silicates as bases, replacing the iron, alumina, lime, etc., or whether they are present in them purely as inclusions of the fii'st series. F. Sandberger ^ argues in support of the first view, but his critics, notably A. W. Stelzner, cast doubt upon his conclusions on the ground that his chemical methods were indecisive. The case is briefly this : Sandberger, as an advocate of views which will be subsequently outlined, sep- arated the dark silicates of a great many rocks. By operating on quantities of thirty grams he proved the presence in them of lead, copper, tin, antimony, arsenic, nickel, cobalt, bismuth, a'nd silver, and considered these metals to act as bases. The weak point of the demonstration consists in dissolving out from the powdered silicate any possible inclusions. There seems to be no available solvent which will take the inclusions and be without effect on the silicates. This is the point attacked by the critics, and apparently with reason. It is, however, important to have shown the presence of these metals, even though their exact relations be thus doubtful. Quite recently in a series of " Notes on Chilean Ore Deposits " (Tschermaks 3Iin. unci Petrog. Mittli. XII., p. 195) Dr. Moricke mentions native gold in pearlstone (obsidian) from Guanaco, in skeleton crystals in the glass, as inclusions in perfectly fresh plagioclase and sanidine crystals, and in spherulites. The existence of silver in quartz-porphyry has been demonstrated in this country by J. S. Curtis, at Eureka, Nev.;'' both the precious metals have been shown by G. F. Becker to be in the diabase near the Com- 1 The principal paper of Professor Sandberger is his " Untersuchungen iiber Erzgange," 18*^3, ubstracted in the Engineering and Mining Journal, March 15, £3, and 39, 1884; but a long series ot others might be cited in which the investigations, notably at Pribram, Bohemia, are interpreted as indicated above A. W. Stelzner, B. and H. Zeit. , xxxix.. No. 3. Zeitsch. d.d.g. Gesell., xxxi. 644. " Die Lateral-secretions-Theorie, etc." Reprint Freiberg, 1889. ^ Monograph VII., U. 8. Oeol. Survey. 26 KEMP'S ORE DEPOSITS. stock Lode ; ' and, by the same investigator, antimony, arsenic, lead, copper, gold, and silver were proved to be contained in the granite near Steamboat Springs, Nev.^ S. F. Emmons has also shown that the porphyries at Leadville contain appreciable, though small, amounts of silver.' Of forty-two specimens tested, thi-rty- two afforded it ; of seventeen tested for lead, fourteen yielded re- sults. Undoubtedly the multiplication of tests will show similar metallic contents in other regions. Thus the augite of the eastern Triassic diabase will probably yield copper, for this metal is abun- dant in connection with the outflows. 1.03.07. That the metals are so generally combined with sul- phur in ore deposits seems to be due to the extended distribution of this element, and to its being a vigorous precipitating agent of nearly all the metals at the temperatures and pressures near the surface. Sulphur is widespread as pyrite, an original mineral in many igneous rocks, and one much subject to alteration ; while sulphuretted hydrogen is common in waters from sedimentary rocks, and is a very general result of organic decomposition. Nat- ural gas and petroleum from limestone receptacles almost always contain it. (See, in this connection, J. F. Kemjj, " The Precipita- tion of Metallic Sulphides by Natural Gas," Engineering and Mining Journal, Dec. 13, 1890.) Many sulphides, too, are soluble under the pressures and temperatures prevailing at great depths, but are deposited spontaneously at the pressures and temperatures prevailing at or near the surface. 1.03.08. Where veins occur in igneous rocks the bases for gangue minerals have been obtained from the rock-making silicates. Calcium is afforded by nearly all the important ones ; silicon is everywhere present ; barium has been proved in many feldspars, in small amount ;* and magnesia is present in many pyroxenes and amphiboles. Of the sedimentary rocks, limestone of course affords unlimited calcium, and recently Sandberger reports that he has identified microscopic crystals of barite in the insoluble residues of one. [Sitzungsberichte d. Math. phys. Glasse d. h. hayer, ATcad. d. Wiss., 1891, xxi. 291.) This is of interest, as barite is such a com- mon gangue in limestone. 1.03.09. It may be remarked that the natural formation of both 1 Monograph III., XT. S. Oeol. Survey. 2 Monograph XIII. , Cf. 8. Oeol. Survey. 8 Monograph XII. . U. 8. Oeol. Stirmy. * W. F. Hillebrand, "Tlie Widespread Occurrence of Barium and Stron- tium in Silicate Rocks," Jour. Amer. Uhem. Soc, Feb., 1894, p. 81. THE MINERALS IMPORTANT AS ORES, ETC. 27 ore and gangue minerals has doubtless proceeded in nature with great slowness, and from very dilute solutions. Both classes ex- hibit a tendency to concentrate in cavities, even from a widely dispersed condition through great masses of comparatively barren rock. The formation may have proceeded when the walls were far below their present position with regard to the surface, so that to those inclined a wide latitude for speculation on origin is afforded. It is also possible that in the earlier history of the globe circulations were more active than they are now — a line of argu- ment on which a conservative writer would hesitate to enlarge. CHAPTER IT. ON THE FILLING OF MINERAL VEINS. 1.C4.01. Bearing in mind what precedes, the preliminaries for the discussion of mineral veins are set in order. We have traced the formation of cavities by the shrinkage of rock masses in cool- ing or drying, by the movements and disturbances of the earth's crust (which are far the commonest and most important causes), and by dolomitization. The enlargement of such cavities by sub- terranean circulations followed, and the general eifect of waters, cold and heated. The sources of the elements of the useful min- erals were pointed out so far as known. All these general and in- disputable truths assist in the drawing of right conclusions. It should be emphasized, as will appear later, that mineral veins or cavity fillings do not embrace all metalliferous deposits. On the contrary, the deposits which either form beds by themselves, or which are disseminated through beds of barren rock and are of the same age with them, do not enter into the discussion. They are characterized by being younger than their foot walls and older than the hanging. Their geological structure is far simpler, and, as will appear in the discussion of particular examples, the work- ing out of their origin does not so often carry the investigator into the realms of speculation and hypothesis. And yet it is not to be inferred from the prominence here given to the discussion of veins that bedded dejiosits yield to them, in any degree, in importance. Iron ores, for instance, are often in beds. 1.04.02. Methods of Filling. — Methods of filling were summed up a very long time ago by Von Herder and Von Cotta,^ as fol- lows : 1. Contemporaneous formation. 2. Lateral secretion. .3. Descension. 4. Ascension by (a) infiltration, or (b) sublimation with steam, or (c) by sublimation as gas, or (cT) by igneous injec- tion. To these should be added the more recent theory of (5) re- 1 Erzlagerstatten, 3d ed., 1859, Vol. I., p. 172. ON THE FILLING OF MINERAL VEINS. 29 placement, which, however, is rather a method of precipitation than of derivation. No one longer believes in contemporaneous for- mation, and descension has an extremely limited, if, indeed, any application. Ascension by sublimation as gas or with steam, or by igneous injection, has few, if any, supporters. The discussion is practically reduced to lateral secretion and to ascension by infiltra- tion. 1.04.03. Lateral Secretinn. — By lateral secretion is understood the derivation of tlie contents of a vein from the wall rock. The wall rock may vary in character along the strike and in depth. Three interpretations may be made, two of which approach a com- nion middle ground with ascension by infiltration. It may first be supposed that the vein has been filled by the waters near the surface which are known to be soaking through all bodies of rock, even where no marked waterway exists, and which seep from the walls of any opening that may be afforded. Being at or within comparatively short distances of the surface, the waters are not especially heated. As they emerge to the oxidizing and evaporating influence of the air in the cavity, their burden of minerals is deposited as layers on the walls. The second interpretation supposes the walls to be placed during the time of the filling at considerable depth below the surface, so that the percolating waters are brought within the regions of elevated temperature and pressure. Essentially the same action takes place as in the first case. The third interpreta- tion increases the extent of the rock leached. Thus if a mass of granite incloses a vein and extends to vast depths, we may suppose the waters to come from considerable distances, and to derive their dissolved minerals from a great amount of rock of the same kind as the walls. Portions of this may even be in the regions of high temperature, while the place of precipitation is nearer the surface. These last two interpretations have much in common with the theory of ascension by infiltration, and on this common middle ground lateral-secretionists and infiltration-asoensionists maybe in harmony. 1.04.04. Ascension by InJilt7'ation. — The theory of infiltration by ascension in solution from below considers that ore-bearing solutions come from the heated zones of the earth, and tliat they rise through cavities, and at diminished temperatures and pressures deposit their burdens. No restriction is placed on the source from which the mineral matter has been derived. Indeed, beyond that it is "below," and yet within the limits reached by 30 KEMP'S ORE DEPOSITS. waters, all of which have descended from the surface, and that the metals have been gathered up from a disseminated condition in rocks, — igneous, sedimentary, and metamorphic, — no more definite state- ment is possible. This theory is of necessity largely speculative, because the materials for its verification are beyond actual inves- tigation. 1.04.05. Lateral Secretion. — In favor of lateral secretion the following arguments may be advanced. I. According to Sandberg- er, actual experience witli the conduits, either natural or artificial, of mineral springs, shows that a deposit seldom, if ever, gathers in a moving current. It is only when solutions come to rest on the surface and are exposed to oxidation and evaporation that precipita- tion ensues. Deposits in veins have therefore formed in standing waters, whose slight overfl.ow or evaporation has been best compen- sated by the equally slight and gradual inflow from the walls. If in hot springs there is a strong and continuous flow from below and discharge from iibove, the mineral mattei- will reach the surface. (Sandberger, U liter sucliungeu uber Erzgdiige, Heft I.) Hence the deposit will be more likely to gather by the slow infiltrations from the wall rock, which stand in cavities likti a well. We have, however, some striking instances of deposits in artificial con- duits. Prof. H. S. Munroe has called the writer's attention to a case recently met by him. The fourteen-inch column pipe of a pump at the Indian Ridge Colliery, Shenandoah, Penn., which was rais- ing ferruginous waters, became reduced in diameter to five inches within two years by the deposit of limonite. The same amount of water was forced through the five-inch as through the fourteen- inch. By figuring out the stroke and cylinder contents, it was found that in the clear pipe the water moved 162 feet per minute, and in the contracted pipe 1268 feet. And yet the deposit gath- ered. The conditions necessitated the continuous action of the pump, and it was not idle over two hours in each two months of that period. The boiler feed-pipes of steamers plying on the Great Lakes also become coated with salts of lime. Years ago a disastrous boiler explosion occurred from the virtual stoppage of the feed by this precipitation. 1.04.06. II. If a vein were opened up, in mining, which ran through two different kinds of rock, and if in the one rook one kind of ore and gangue minerals were found, and in the other a different set, the wall rock would clearly have some influence. ON THE FILLING OF MINERAL VEINS. 31 Thus in a mine at Schapbaah, in the Black Foi-est, investigated by Sandberger, a vein ran through granite and gneiss. Tlie mica of the granite contained arsenic, copper, cobalt, bismuth, and silver, but no lead. The principal ore in this portion was gray copper. The mica of the gneiss contained lead, copper, cobalt, and bismuth, and the vein held galena, chalcopyrite, and a rare mineral, schap- bachite, containing bismuth and silver, but probably a mixture of several sulphides. No two ores were common to both parts of the vein. Another well-established foreign illustration is at Klausen, in the Austrian Tyrol. Lead, silver, and zinc occurred in the veins where they cut diorite and slates, but copper where mica schist and felsite formed the walls. In America there are a num- ber of similar cases. At the famous Silver Islet Mine' on Lake Superior the vein runs through unaltered flags and shales, and then crosses and faults a large diorite dike. Where the diorite forms the walls, the vein carries native silver and sulphides of lead, nickel, zinc, etc., but where the flags form the walls, the vein contains only barren calcite. Along the edges of the estuary Triassic sandstones *of the Atlantic border, where they adjoin Archean gneiss, a number of veins are found afEording lead min- erals, while in the sandstones near the well-known diabase sheets and dikes are others carrying copper ores. It was early remarked by J. D. ^/''hitney that the lead was usually associated with the gneiss, the copper with the diabase. 1.04.07. From instances like these it is infen-ed that the ores were derived each from its own walls, and by just such a leaching action by cold surface waters as is outlined above. As opposed to this, it has usually been claimed that each particular wall ex- erted a peculiar selective and pi-ecipitating action on the metals found adjacent to it and none on the others ; so that if a solution arose carrying both sets, each came down in its particular sur- roundings, while the others escaped. Dr. W. P. Jenney has called the writer's attention to such a case. The Head Centre mine, in ' W. M. Courtis, " On Silver Islet," Engineering and Mining Journal, Deo. 31, 1878. ilf. ^,, V. 474. E. D. Ingall, Geol Survey of Canada, 1887-88, p. 27, H. F. .\. Lowe, "The Silver Islet Mine," etc., Engineering and Mining Journal, Dec. Ifl, 1882, p. 321. T. MicFarlane, "Silver Islet," M. E., VIII. 226. Canadian Naturalist, IV. 37. McDermolt, Engineering and Mining Journal, January, 1877. 32 KEMP'S ORE DEPOSITS. the Tombstone district, Arizona, is on a vein which pierces elates, and in one place forty feet of limestone. In the slates it carried high-grade silver ores, with no lead, hut in the limestone, lead-sil- ver ores. A rock like limestone might well exercise a precipita- ting action, which, however, we cannot attribute to rocks composed of the more inert silicates. Again, it has been said that the solu- tions coming from below have varied in different portions of the vein or at different periods. An earlier opening would thus be filled with one ore, a later opening with another. This is hy- pothetical, but has been advanced for Klausen by Posepny. (Ar- chiv f. Praktische Geologie, p. 482.) A further general objection to the first interpretation of lateral secretion is the weak dissolv- ing power of cold surface waters, and this is a very serious one. 1.04.08. As opposed to the second interpretation, it may be advanced that precipitation in a cavity at a great depth would be retarded by the heat and the pressure, to just that extent to which solution in the neighboring walls would be aided. The tempera- ture and pressure being practically the same, the tendency to re- main in solution would be great until the minerals had reached the upper regions and filled the cavity by ascension. Under such cir- cumstances ores would only be deposited below, by some such ac- tion as replacement. To the third interpretation no theoretical ob- jections can be made. 1.04.09. Infiltration by Ascension. — On the side of infiltration by ascension, if two veins or sets of veins were found in the same wall rock, but with different kinds of ores and minerals, the con- clusion would be irrefutable that the respective solutions which formed them had come from two different sources below. Thus at Butte, Mont., there is a great development of a dark, basic granite. It contains two series of veins, of which the southern produces copper sulphides in a siliceous gangue, the northern sulphides of silver, lead, zinc, and iron, also in a siliceous gangue, but abundantly associ- ated with manganese minerals, especially rhodonite. No manganese occurs in the copper belt, nor is any copper found in the silver belt. Such results could originate only in different, deep-seated sources. Again, at Steamboat Springs, Xev., and Sulphur Bank, Cal., the hot springs are still in action and are bringing their burdens of gangue and ore to the surface. The former has afforded a long series of metals, the latter chiefly cinnabar, G. F. Becker^ has shown that the cinnabar probably comes up in solution with alkaline sulphides. 1 G. F. Becker, " Natural Solutions of Cinnabar, Gold, and Associated ON THE FILLING OF MINERAL VEINS. 33 1.04.10. Replacement. — The conception of replacement is one that has been applied of late years by some of the most reliable observers. About 1873 it appears to have been first extensively developed by Franz Posepny, an Austrian geologist, in relation to certain lead-silver deposits at Raibl, in the Province of Kaernthen. About the same time it was suggested by Pumpelly, then State Geologist of Missouri, to Adolf Schmidt, who was engaged in studying the iron deposits of Pilot Knob and Iron Mountain (see Examples 11 and 11a), and by Schmidt it was considered applicable to them. ("Iron Ores and Coal 'Fields,''' Missouri Geol. Survey, 1873.) Some ten years later J. S. Curtis based his explanation of the formation of the Eureka (Nev.) lead-silver deposits on the same idea, and according to Emmons (1886) it holds good forLead- ville. R. D. Irving, who credited Pumpelly with bringing it to his attention, published in 1886 an explanation of the hematite beds of the Penokee-Grogebio range (Example 9c;), in which the idea is ap- plied, and Van Hise has since elaborated it. In the process of re- placement no great cavity is supposed to exist previously. There is little, in fact, but a circulation or percolation of ore-bearing solu- tions which exchange their metallic contents, molecule by molecule, for the substance of the rock mass. We would not expect the ore body to be as sharply defined against the walls as when it filled a fissure, but rather to fade into barren material. Thus rock ma}' be impregnated but not entirely replaced, and, while apparently unchanged, yet carry valuable amounts of ore. Some of the ores of Aspen, Colo. (Example ZOd), are at times only to be distinguished by assay from the barren limestones. Yet decomposition may bring out the limits of each. 1.04.11. The chemistry of the replacement process is none too well understood, but it presents fewer difficulties when applied to a soluble rock, like limestone or dolomite, than when rocks composed of silicates and quartz have given away to ores. Acid solutions would readily yield to calcium carbonate; but if the metals are pres- ent as sulphates, some reducing agent, such as organic matter, is necessary in order to change the metallic sulphate to sulphide.' Or else, if the metallic sulphides come up in solution with alkaline sulphides, some third agent is needed to remove the calcium car- Sulphides," 4roer. Jomj". Sci., III., xxxili. 199; Eighth Ann. Rep. Direc- tor U. S. Geol. Survey ; Monograph XIII., U. S. Qeol. Survey, p. 965. 1 Compares. F. Emmons, " On the Replacement of Leadville Limestones and Dolomites by Sulphides," Monograph XIL, U. S. Geol. Survey, p. 563. 34 KEMP'S ORE DEPOSITS. honeite, pari passu, ]vLst before the metallic sulphide is precipitated. It must be confessed that for enormous bodies of ore, like those of Leadville, the small amount of organic matter present seems hard- ly equal to the task assigned it, and the delicate balance of the lat- ter case — causing deposition to tread so closely on the heels of rock removal, in order to avoid assuming an extended cavity — makes it appear that the entire chemistry of the process is perhaps hardly understood. 1.04.12. When silicate rocks are replaced, leaving a siliceous gangue, the process may have been somewhat as suggested by R. C. Hills for the mines of the Summit district, Rio Grande County, Colorado. (See Proc. Colo. iSci. Soc, Vol. I., ]>. 20.) Alkaline solu- tions remove silica and have slight action on silicates, but solutions acid with sulphuric acid attack silicates, such as feldspar and bio- tite, remove the alumina or change it to kaolin, and cause the sep- aration of free silica. In the alteration products abundant opportu- nity would be afforded for the precipitation of sulphides, which would in part at least replace the rock. Along a crack or line of drainage definite walls would thus easily fade out. Such phenome- na are afforded by innumerable ore deposits (see R. "W. Raymond, discussion of S. F. Emmons' " Notes on the Geology of Butte, Mont.," M. S., July, 1877), and often come under the notice of every one familiar with mining. Yet we cannot but hope that in tlie future our knowledge of the chemical reactions involved will be increased. It may again be stated that the formation of ore deposits has proceeded with great slowness, and the solutions bringing the met- als have been, beyond question, very dilute. The extremely small amounts of the metals that have been detected in relatively large amounts of igneous rocks, even by the most refined analytical meth- ods, have necessarily made the progress of solution a protracted one. Curtis records some careful observations on the growth of ai-agonite at Eureka, Nev., where he found that in three weeks, so long as wet by a drop of water, the crystals increased in one case as a maximum, five eighths of an inch, and in another three eighths. But this was where the whole inclosing mass of rock consisted of the compound deposited. CHAPTER Y. ON CERTAIN STRUCTURAL FEATURES OF MINERAL VEINS. L05.01. Bayided Structvre. — Mineral veins sometimes exhibit a banded structure, by which is understood the arrangement of the ore and gangue in parallel layers that correspond on opposite walls. They are most conspicuous where the walls are well de- fined. The solutions which have brought the minerals have varied from time to time, and the precipitated coatings correspond to these variations. They alternate from gangue to ore, it may be, several times repeated. The ore may be in small scattered masses preserving a distinct lineal arrangement in the midst of the barren quartz, calcite, barite, fluorite, siderite, etc., or itself be so abun- dant as to afford a continuous parallel streak. The commonest ores so observed are pyrite, chalcopyrite, galena, blende, and the various sulphides of silver. The veins of the Reese River district, in Nevada, furnish good illustrations of alternating ruby silver ores and quartz. Those of Gilpin County, Colorado (Example lla), afford alternations of pyrite, chalcopyrite, and gangue. (See figures in Endlich's report, Hayderi's Survey, 1873, p. 280.) The Bassick Mine, in Colorado, has pebbles remarkably coated. The figure on p. 36 shows a vein at Newman Hill, near Rico, Colo. Banded veins, however, except of a rude character, are not com- mon in this country. They have received much more attention in Germany, where, especially near Freiberg, they show remarkable perfection. The famous Drei Prinzen Spat Vein, figured by Von Weissenbach and copied in many books, has ten corresponding al- ternations of six different minerals on each wall. 1.05.02. A line of cavities, or vuggs, is often seen at the cen- tral portion of a vein, into which crystals of the last formed miner- als emerge, forming a comb (see p. 36). These may project into each other and interlock, — especially if quartz, — forming a comb in comb. The same may occur between side layers. These cavities are a most prolific source of finely crystallized minerals. If, after the 36 KEMP '8 ORE DEPOSITS. fissure — perhaps at the time small — has become once filled, subse- quent movements take place, they may strip the vein from one wall and cause a new series of minerals to be deposited, witii tlie previously formed vein on one side and the wall rock on the other. This oc- casions uns3'mmetrical fillings. But it may also happen that, with otherwise symmetrical fillings, one layer may be lacking on one side or the other. "Where portion- of the wall rock have been torn off by the vein matter in these secondary movements, they may be buried in the later deposited vein filling, and form great masses of barren rock called horses. The vein then forks around them. If the ore and thegangue have partly replaced the wall in deposition, East Fig. 6. — Banded vein at Newman Hill, near Rico, Colo. After J. B. Far- ish, Proa. Colo. Sai. Soc, April 4, 1892; Engineering and Mining Journal, Aug. 30, 1893. unchanged masses of wall may also become inclosed and afford horses of a different origin. An originally forked fissure gives an analogous result. It is a curious fact that veins are often most productive just at the split. If the masses are small, or if the vein fills a shattered strip and not a clean fissure, or if it occupies an old volcanic con- duit, deposition and replacement may surround unchanged cores of wall rock with concentric laj^ers of ores and minerals. Thus the Bassick, at Rosita, Colo., referred to above, consists of rounded cores of andesite, inclosed in five concentric layers of metallic sul- phides. The Bull Domingo, in the same region, exhibits shells of galena and quartz mantling nodules of gneiss. Such cores strongly ON STRUCTURAL FEATURES OF MINERAL VEINS. 37 resemble rounded, water-worn boulders, a similarity which has suggested some rather improbable hypotheses of deposition. 1.0.5.03. Clay Selvage. — An extremely common feature is a band of clay, most often between the vein matter and the wall. This is called a selvage, gouge, flucan, clay seam, or parting. It may come in also between layers of different minerals, and even rests as a mantle on the crystals which line cavities. It is at times the less soluble portion left by the decay and removal in solution of wall rock (residual clay), at times the comminuted material re- sulting from the friction of moving walls (attrition clay), and again it may be taken up by currents and redeposited from bodies of the first two sorts. Such layers of clay, being wellnigh imper- vious to water, may have exercised an important influence in di- recting the subterranean circulations. (See Becker on the Com- stock Lode, 2.11.19.) 1.05.04. Pinches, Swells, and Lateral Enrichments. — The swells and pinches of veins have been referred to above and ex- plained. Aside from these thicker portions of the ore, it is often seen that the richer or even the workable bodies follow certain more or less regular directions, forming so-called " chutes." They probably correspond to the courses taken and followed by the richer solutions. J. E. Clayton observed that they follow the di- rections of the slips, or strisB, of the walls rather more often than not, and in the west this disposition or tendency is called Clayton's law. Chute is sometimes spel 1 oil "shoot " or"shute." Chimney and ore-courLj are synonyms of chute. Bonanza is used, especially on the Comstock Lode, to indicate a localized, rich body of ore. Lateral enrichments are caused by the spreading of the ore- bearing cuiTents sidewise from the vein, and often along particu- lar beds of rock, which they may replace more or less with ore. Beds of limestone — it may be quite thin, when in a series com- posed of shales or sandstones — are faA'orite precipitants, and from such lateral enlargement the best returns may be obtained. The valuable ore bodies of Newman Plill, near Rico, Colo., whose inter- esting description by J. B. Farish has already been several times cited, are found as lateral enrichments along a bed of limestone less than three feet thick and embedded in shales. Above the lime- stone the veins practically cease. Lateral enrichments may closely resemble bedded deposits if the supply fissures are relatively small. This interpretation is placed by W. P. Jenney on the disseminated lead ores of southeastern Missouri (2.15.09), and he has suggested 38 KEMP'S ORE DEPOSITS. the expressive term "melon vein," tlius comparing them with a vine and its melons. 1.05.05. Changes in Character of Vein Filling. — In discuss- ing the influence of wall rock the changes that occur in veins were briefly mentioned. But even where the walls remain uniform there is always variation in contents, and of course in value, from point to point. Ore, gangue, horses, and walls alternate both longitudinally and in depth, and such changes must be allowed for and averaged by keeping exploration well in advance of excava- tion. Even a series of parallel veins may all prove fickle. In illustration of the above the Marshall tunnel of Georgetown, Colo., may be cited. It cut twelve veins below their actual workings, and every one was barren at the tunnel though productive above. (J. J. Stevenson, Wheeler's Survey, Geology, Vol. III., p. 351.) 1.05.06. Secondary Alteration of the Minerals hi Veins. — It has already been stated that the chief ore minerals in vein fill- ings are sulphides. Where these lie above the line of permanent subterranean water they are exposed to the oxidizing and hydrat- ing action of atmospheric waters, M-hich, falling on the surface, percolate downward. The ores are thus subjected to alternating soakings and dryings which encourage alteration. The sulpliides change to sulphates, carbonates, oxides, or hydrous forms of the same, and the metallic contents are in part removed in the acid waters which are also formed. Pyrite, which is the most wide- spread of the sulphides, becomes linionite, staining evervthing with its characteristic color. Galena becomes cernssite or anglesite. Blende affords calamine and sniithsonite. Copper ores, of which the usual one is chalcopyrite, change to malachite, azurite, chryso- colla, cuprite, and melaconite, and to the sulphide chalcocite. The silver sulphides afford cerargyrite. The rarer metals alter to cor- responding compounds of less frequency. These ujDper jjortions are also more cellular and porous, being at times even earthy. The rusty color from the presence of limonite often marks the outcrop and is of great aid to the prospector. It has been called the iron hat, or gossan. This feature has important economic bearings. The character of ores may entirely change at a definite point in depth, and the later products, if not lower in grade, as is often the case, may demand different, perhaps more difficult, modes of treat- ment. Oxidized ores are the easiest to smelt, and the benefit of careful exploration before indulging in too confident expectations may be emphasized. As examples, the Ducktown copper deposits ON STRUCTURAL FEATURES OP MINKRAL VEINS. 39 (see Example 16), the Leadville silver mines (Example 30), the boiithwest Virginia zinc deposits at Bonsacks (Example 26), the copper and silver veins at Butte, Mont. (Example 17), and others ill LliUK) County, Texas (Example lib), may be cited. At Duck- town a considerable thickness of chalcocite, melaconite, and carbon- ates accumulated just at the water line and abruptly changed to low-grade, unworkable pyrite and chalcopyrite below it. At Bon- sacks, near Roanoke, Va , very rich, easily treated earthy limon- ite and smithsonite (30-40 ^ zinc) passed into a refractory, low- grade (15-20 Wliitney's Metallic Wealth of the U. 8., 1854, p. 44. CLASSIFICATION OF ORE DEPOSITS. 45 (3) B. von Cotta, idem, p. 80. According to Shape and Position. I. Wahre, einfache Spaltengange (Fissures). (a) Querdurchsetzende, Cross fissures, {b) Lagergange, Bed veins. (c) Kliifte (Cracks), Adern (Veinlets). II. Gangziige (Linked Veins).^ III. Netzgange (Reticulated Veins). IV. Contaktgange (Contact Veins). V. Lenticulargange (Lenses). VI. Stockformige Gange (Stocks, Masses). (4) B. von Cotta, idem, p. 80. According to the texture of the vein filling. I. Diohte Gange (Compact Veins). II. Krystallinische Gauge. III. Krystallinisch, kornige (granular) Gange. IV. Krystallinisch, massige (massive) Gange. V. Gange niit Lagentexlur (Banded veins). {a) Ohne Symmetric der Lagen (unsymmetrical). (b) Mit Symmetric der Lagen (symmetrical). VI. Gange mit Breccien oder Conglomerattextur. (5) J. Leconte, Amer. Jour. Sci., July, 1883, p. 17. 1. Fissure Veins. 2. Incipient Fissures, or Irregular Veins. 3. Brecciated Veins. 4. Substitution Veins. 5. Contact Veins. 6. Irregular Ore Deposits. 1.06.05. In Von Weissenbach's table the sedimentary veins are much the same as the " sandstone dikes " which J. S. Diller has recently described. {Bull. Geol. Soc. Amer., I. 411.) They and the stalactitic veins have small practical value, although of great scientific interest. Under {d), the stockworks with tin ores ' Gang-ziige is happily translated "linked veins," by Mr. G. F. Becker (Quicksilver Deposits, p. 410). Any attempt to render the original by preserving the figure of a flock of birds or of a school of fish, etc., is, as Mr. Becker remarks, infelicitous, if not impossible. 46 KEMP'S ORE DEPOSITS. are the principal illustration of economic prominence. The attri- tion veins are an important class, and increasing study has wid- ened the application of this or synonymous terms. Segregated veins and true veins are well-known forms. In the comments of Von Cotta, which follow Von Weissenbach's paper, veins are grouped from every possible standpoint, Von Weissenbach's scheme being taken as the one based on origin. Nos. 2 and 4 have small claims to attention. No. 3 foreshadows the drift of many subsequent writers. The meanings of the terms are self-evident, except perhaps Oangzuge (linked veins). This refers to a group of parallel and more or less overlapping veins, deposited along a series of openings, evidently of common origin. It is a convenient term. The terms used by Leconte may be passed without comment as being self-evident in their meaning, except (4) and (6). The scheme was devised, as a perusal of the citation will show, after the author had set forth some original views of the causes which lead to the precipitation of ores, and had forcibly stated others very generally accepted. In the explanatory text some quite curious as- sociations are found, which are cited by way of illustration. Thus under group (4), stalactites, caves, gash veins, and the Leadville ore bodies are considered examples, and under group (6) the grouping together of beds, igneous masses, and all other forms of so-called irregular deposit is decidedly open to criticism. This is the more emphatic because the concluding sentences of the paper (of whose general value and excellence there can be no question) give the im- pression that the author felt he had cleared up all the points in the origin of ore bodies which would be of interest or importance to a purely scientific investigator as contrasted with a practical miner. 1.06.06. B. General Schemes Based on Form. (6) Von Cotta and Prime. Ore Deposits, New York, 1870. I. Regular Deposits. A. Beds. B. Veins. {a) True (Fissure) Veins. (5) Bedded Veins. (e) Contact Veins. {d) Lenticular Veins. n. Irregular Deposits. CLASSIFICATION OF ORE DEPOSITS. 47 C. Segregations. (a) Recumbent. (5) Vertical. D. Impregnations (Disseminations). (^) Lottner-Serlo, Leitfaden zur BergbauJeunde, 1869. I. Eingelagerte Lagerstatten (Inclosed Deposits). A. Plattenformige (Tabular). (a) Gange (Veins). (5) Flotze und Lager (Strata, beds, seams). B. Massige Lagerstatten (Massive Deposits). (a) Stocke \ ^r_„„„, ib) Stock werke [ ^^'^^^es. C. Andere unregelmiissige Lagerstatten (other irregu- lar deposits), (a) Nester (Pockets). (5) Putzen. (c) Nieren (Kidneys). II. Aufgelagerte Lagerstiltten (Superficial Deposits). D. Triimmerlagerstutten (Placers). E. Oberflachliche Lager (Surface beds). (8) Koehler, Lehrbuch der Bergbaukunde, ISSV. I. Plattenformige Lagerstatten (Tabular Deposits). (a) Gange (Veins). (b) Flotze und Lager (Strata, beds, seams). II. Lagerstatten von unregelmiissige Form (Deposits of irregular Form). (a) Stocke und Stockwerke (Masses). (5) Butzen, Nester, und Nieren (Pockets, concre- tions, etc.). (9) Gallon, Lectures on Mining, 1866 (Foster and Galloway's translation). I. Veins. II. Beds. III. Masses (i.e., not relatively long, broad, and tbin). 1.06.07. The scheme of Von Gotta and Prime carries out the principle of form to its logical and somewhat trivial conclusion. 48 KEMPS ORE DEPOSITS. Thus under irregular deposits it is a matter of extremely small classificatory moment whether an ore body is recumbent or vertical. Otherwise the scheme is excellent, and its influence can be traced through most of those that are of later date. The original draft came out in the German in 1859. All the others are from treatises on mining, in which this subject plays a minor r61e, and indicates the tendency, referred to above, of mining engineers, when writing theoretically, to imagine certain fairly definite forms, which are to be exploited. As previously remarked, however, considering the uncertainty of ore bodies and their variability in shape, it is here argued that the genetic principle might better take precedence. Several of the German terms are difficult to render into English mining idioms, as for example. Stock, Butzen (Putzen), Nester, and Nieren. 1.06.08. C Schemes, Partly Hased on lorm, Partly on Origin. (10) J.. D.Whitney, Metallic Wealth, 1854. I. Superficial. n. Stratified. (a) Constituting the mass of a bed or stratified deposit. (5) Disseminated through sedimentary beds, (c) Originally deposited from aqueous solution, but since metamorphosed. III. Unstratified. A. Irregular. (a) Masses of erujjtive origin. (6) Disseminated in eruptive rocks, (c) Stockwork deposits. (t?) Contact deposits. (e) Fahlbands. B. Regular. if) Segregated veins. {g) Gash veins. (A) True or fissure "veins. (11) J. S. Newberry, School of Mines Quarterly, March, 1880, May, 1884 I. Superficial. CLASSIFICATION OF ORE liEPOSlTS. 4S II. Stratified. (a) Forming entire strata. (b) Disseminated through strata. (c) Segregated from strata. III. Unstratitied. (a) Eruptive masses. (b) Disseminated through eruptive rock. (c) Contact deposits. (d) Stockworks. (e) Fahlbands. (/) Chambers. {ff) Mineral veins. 1. Gash veins. 2. Segregated veins. 3. Bedded veins. 4. Fissure veins. (12) J. A. Phillips, Ore Deposits, 1884. I. Superficial. (a) By mechanical action of water. {h) By chemical action. II. Stratified. (a) Deposits constituting the bulk of metalliferou-s beds formed by precipitation from aqueous solution. (J) Beds originally deposited from solution but sub- sequently altered by metamorphism. (c) Ores disseminated through sedimentary beds, in vsrhich they have been chemically deposited. III. TJnstratified. (a) True veins. (6) Segregated veins. (c) Gash veins. (d) Impregnations. (e) StockvForks. (/) Fahlbands. [g) Contact deposits. (A) Chambers or pockets. 1.06.09. It is at once apparent that Whitney's scheme contains the essentials of the others, which are merely slight modifications. Newberry introduces impregnations, chambers, and bedded veins. 50 KEMP'S ORE DEPOSITS. The first named is a useful term, although it is not always easy to distinguish impregnations from otbers earlier given. Thus, they may be very like the division, disseminated through strata, or dis- seminated through, eruptive rock, or, if in metamorphic rock,fahl- bands. The word is also used to indicate places along a vein where the ore has spread into the walls. The term " chambers," or " caves," nas found application in the West, and is a useful ad- dition. Bedded veins appear also in Von Cotta above (No. 6). Phillips seeks to explain the methods of origin in his use of Whit- ney's scheme and clearly feels the importance of emphasizing the genetic principle more strongly. Much of it is implied in the simpler phraseology, however, and the extended sentences lack the incisiveness of the earlier schemes. The arrangement as set forth by Whitney is worthy of high praise, and the scheme is one of the many valuable things in a book that has played a large part in the economic history of the United States. 1.06.10. D. Schemes Largely Based on Origin. (13) J. Grimm, Lagerstdtten, 1869. I. Gemengtheile oder grossere Einschliisse in den Gebirgsgesteinen. Einsprengung, Impragnation. (Essential component minerals and inclusions in country rock. Impregnations.) (a) Urspriingliche Einsprengung. (Original with the inclosing rock.) (5) Von anderen Lagerstatten weggefiihrte Bruch- theile, etc. (Fragments brought from a dis- tance. Placers, ore-bearing boulders. Brec- cias.) II. Untergeordnete Gebirgsglieder oder besondere Lager- statten. (Subordinate terranes or special forms of Deposits.) (a) Plattenformige Massen. (Tabular masses.) 1. Lager oder Flotze. Bodensatzbildung. (Beds, strata.) 2. Gauge, Kliifte, Gangtriimmer, etc. (Veins of varying sizes.) 3. Plattenformige Erz-ausscheidungen und Anhiiufungen. (Segregated veins.) (6) Stocke und regellos gestaltete Massen. (Stocks and irregular masses.) CLASSIFICATION OF ORE DEPOSITS. 51 1. Lagerstocke Linsenstocke, Linsen. (Len- ticular deposits, etc.) 2. Stocke, Butzen, Nester, etc. (Masses, pockets, etc.) 3. Stockwerke. (Stockworks.) (14) A. von Groddeck, Lehre voti den Lagerstdtten, etc., 18 79, p. 84. I. Urspriingliche Lagerstatten (Primary deposits). A. Gleichzeitig mit dem Nebengestein gebildet. (Formed at the same time with the walls.) 1. Geschichtete. (Stratified.) (a) Derbe Erzflotze. (Entire beds in fossiliferous strata.) (6) Ausscheidungsflotze. (Disseminated in beds.) (c) Erzlager. (Lenticular beds, mostly in schists.) 2. Massige. (Massive; the word is nearly synonymous with igneous.) B. Spater wie das Nebengestein gebildet. (Formed later than the walls.) 3. Hohlrauinsfiillungen. (Cavity fillings.) (a) Spaltenfiillungen oder Gange. (Fissure fillings or veins.) (1) In massigen Gesteinen. (In igneous rocks.) (2) In geschichteten Gesteinen. (In strati- fied rocks.) (5) Hohlenfullungen. (Chambers.) 4. Metamorphische Lagerstatten. (Altera- tions, replacements, etc.) II. Triimmor-lagerstatten. (Secondary or detrital deposits.) (15) R. Pumpelly, Johnson^ s Encyclopoedia, 1886, VI. 22. I. Disseminated concentra- tion, (a) I m p r e g n at i o n s , Fahlbands. XL Aggregated Concentration. (a) Lenticular aggrega- tions and beds. (5) Irregular masses, (c) Reticulated veins. {d) Contact deposits. Forms due to the text- ure of the inclosing rock, or to its mineral constitution, or to both causes. 5-Z KEMP'S ORE DEPOSITS. III. Cave deposits. ] Forms chiefly due to pre- IV. Gash veins. V existing open cavities V. Fissure veins. ) or fissures. VI. Surface deposits. (a) Residuary deposits. (b) Stream deposits. (c) Lake or bog deposits. 1.06.11. These three are all excellent, and give some interest- ing variations in the several points of view from which each writer regarded his subject. There are instances in the two German schemes where it is difficult to render the original into a corre- sponding English term and recourse has been had to the explana- tory text. Grimm especially writes an obscure style. He divides accordingly as the ore forms an essential and integral part of the walls or a distinct body. Von Groddeck has in view the relative time of formation as contrasted with the walls, Grimm afterward •emphasizes geometrical shape, but this Von Groddeck practically ■does away with, and continues more consistently genetic. His scheme might perhaps come more appropriately in the next section. Pumpelly's conception varies considerably from the others. He Tvrites, as his full paper states, in the belief that the metals have all been derived primarily from the ocean, whence they have passed into sedimentary, and, by fusion of sediments, into igne- ous rocks. The group of residuary surface deposits, carrying out as it does a favorite idea of Professor Pumpelly, as set forth in his papers on the secular decay of rocks, is an important distinction. 1.06.12. E. Schemes Entirely Based on Origin. (16) H. S. Munroe. Used in the Lectures on Mining in the School of Mines, Columbia College. I. Of surface origin, beds. (a) Mechanical (action of moving water). 1. Placers and beach deposits. (J) Chemical (deposited in still water). 1. By evaporation (salt, gypsum, etc.). 2. By precipitation (bog ores). 3. Residual deposits from solution of lime- stone, etc. (hematites), (c) Organic. 1. Vegetable (coal, etc.). CLASSIFICATION OF ORE DEPOSITS. 53 2. Animal (limestone, etc.). (d) Complex (cannel coal, bog ores, etc.). II. Of subterranean origin. (a) Filling fissures and cavities formed mechani- cally. 1. Fissure veins, lodes. 2. Cave deposits — lead, silver, iron ores. 3. Gash veins. The cavities of 2 and 3 are enlarged by solution of limestone. (b) Filling interstitial spaces and replacing the walls. 1. Impregnated beds. 2. Fahlbands. 3. Stockworks. 4. Bonanzas. 5. Masses. 1.06.13. This scheme covers all forms of mineral deposits, whether metalliferous or not, while most of those previously given, as well as the one that follows, concern only metalliferous bod- ies. The scheme is consistently genetic and was elaborated be- cause such a one filled its place in lectures on mining better than one based on form. The general principle on which the main sub- division is made differs materially from any hitherto given. De- posits formed on the surface are kept distinct from those originat- ing below, even though the first class may afterward be buried. (17) 1.06.14. J. F. Kemp, 1892. Revised from the School of Mines Quarterly, November, 1892. I. Of Igneous Origin. Excessively basic developments of fused and cooling magmas. Peridotite, forming iron ore at Cumberland Hill, R. I.' Magneti'.e, Jacu- piranga, Brazil.^ Titaniferous magnetite in Min- nesota gabbros'; in Adirondack gabbros " ; in Swe- dish and Norwegian gabbros. Nickeliferous pyrrho- tite in gabbros and diorites derived from them.'' 1 M. E. Wadswortb, Bull. Mm. Gomp. ZoiJl, 1880, VII. 2 O. A. Derby, Amer. Jour. ScL, April, 1891. 3 N. H. Winchell, TentA Ann. Rep. Minn. Oeol. Survey, pp. 80-83. Bull. VI. of same Survey, p. 135. 4 J. F. Kemp, Bull. Geol. Sod. Amer., V. 333, 1894. 6 J. H. L. Vogt, Oeol. Foren. i. Stockholm- Furhand, XIII. 476, May, 1891. Englisli abstract and review by J. J. H. Teall. Oeol. Mug., February, 1892. Seea.lsoZeitschr.f'iirPraktischeOeologie.l. 4, 125, 257; 11. 41, 184, and 173. 54 KEMP'S ORE DEPOSITS. II. Deposited from Solution. 1. Surface precipitations, often forming beds, and caused by — (a) Oxidation. Bog ores. Ferruginous oolites, as in some Clinton ores.' {b) Sulphurous exhalations from decaying organic matter etc. (Pyrite.) (c) Reduction, chiefly by carbonaceous, organic matter. (Pyrite from ferrous sulphate.) (d) Evaporation, cooling, loss of pressure, etc. (Hot spring deposits, as at Steamboat Springs, Nev.^) (e) Secretions of living organisms. (Iron ores by algEB.') Note. — The first four causes of precipitation operate in subter- ranean cavities, although not again specially referred to. 2. Disseminations (impregnations) in par- ticular beds or sheets, because of — (a) Selective porosity. (Silver Cliff, Colo., silver ore in porous rhyolite.* Amygdaloidal fill- ings, as in copper-bearing amygdaloids, Keweenaw Point, Santa Rita, N. M.^ Im- pregnations of porous sandstone, as at Silver Reef, Utah.«) (5) Selective precipitation by limestone. (Lateral enlargements at Newman Hill, near Rico, Colo.') 3. Filling joints, caused by cooling or drying. (Mississippi Valley gash veins in part.) 4. Occupying chambers (caves) in limestone. (Cave Mine, Utah.«) > C. H. Smyth, Jr., Amer. Jour. Sci., June, 1893, p. 487. ' U. F. Becker, Monograph XIII., U.S. Geol. Survey, pp.331, 468; Laur, Ann. des Mines, 1863, p. 421; J. Leconte, Amer. Jour. Sci, June, 1883, p. 434, July, p. 1; W. H. Weed, idem, August, 1891, p. 166. " SjogTun, Berg- und HiUt. Zeit., 1865, p. 116. * Clark, Engineering and Mining Journal, Nov. 2, 1878, p. 314. ^ A. F. Wendt, Trans. Amer. Instit. Min. Eng., XV. 27. « C. M. Rolker, idem, IX. 21. ' J. B. Farish, Proc. Colo. Sci. Soc, April 4, 1892. " J. S. Newberry, School of Mines Quarterly, March, 1880. See also J. P. Kimball, on Santa Eulalia, Chihuahua, Amer. Jour. Sci., II., xlix. 161. CLASSIFICATION OF ORE DEPOSITS. 55 5. Occupying collapsed, (brecciated) beds, caused by solution and removal of sup- port, or from dolomitization of limestone. (Southwest Missouri zinc deposits.^) 6. Occupying cracks at Monoclinal bends, Anticlinal summits, Synclinal troughs, often with replacement of walls. (Gash veins in part ; galena deposits at Mine la Motte, Missouri ; zincblende deposits in the Saucon Valley, Pennsylvania.') 7. Occupying Shear-zones, or dynamically crushed strips along faults, whose dis- placement may be slight, closely re- lated to No. 8. (Butte, Mont.*) 8. True veins filling an extended fissure, often with lateral enlargements. See also un- der 5. 9. Occupying Volcanic necks, in agglom- erates. (Bassick and Bull Domingo Mines, near flosita, Colo.'*) 10. Contact deposits. Igneous rocks almost al- ways form one wall. Fumaroles. (Mar- quette hematites, Michigan." Greisen.) 11. Segregations formed in the alteration of igneous rock. (Chromite in serjientine.) III. Deposited from Suspension. Residual Deposits. 1. Metalliferous Sands and Gravels, whether now on the surface (placers, magnetite beach-sands), or subsequently buried. (Deep gravels, magnetite lenses ?) 2. Residual Concentrations, left by the weathering of the matrix. (Iron Moun- tain, SIo., hematite in part.') 1 F. L. Clerc, Lead and Zina Ores ia Southwest Missouri Mines, Carthage, Mo., 1887; A. Schmidt, Missouri Geol. Survey, 1874, p. 384. = T. C. Charaberlin, Wis. Geol. Survey, IV., 1882, 367. " F. L. Clerc, Mineral Resources, 1883, p. 361; H. 8. Drinker, Trans. Amer. Inst. Min. Eng., I. 367. 4 S. F. Emmons, Trans. Amer. Inst. Min. Eng., XVI. 49; W. P. Blake, idem, XVI. 65. " C. W. Cross, Proc. Colo. Soi. Soc., 1890, p. 389. « C. R. Van Hise, Amer. Jour. Sci , February, 1893, p. 116. ' R. Pumpelly, Bull. Geol. Soc. Amer., II., p. 330. 56 KEMPS O^E DEPOSITS. 1.06.15. It is believed that under the above heads are included all the forms of ore bodies which constitute well-recognized and fairly well understood geological phenomena. To these catego- ries year by year we are enabled, by the results of extended and careful investigation, to refer many that have been obscure. A number of familiar terms for ore bodies in mining literature fail to appear, but are mentioned in the classitications quoted from others. Many of these refer only to form, and geologically con- sidered are only convenient admissions of ignorance as to origin. Some other ore bodies whose methods of origin are involved in the processes of regional metamorphism are placed by themselves farther on. The explanations of them are as yet hypothetical. A few comments on the scheme may now be added, although in the main it explains itself. 1.06.16. I. Much attention has been given of late years to processes of rock formation from igneous magmas. Of these the excessively ba,sic are the only ones primarily concerned with ores. It is well known that in the series of igneous i-ocks we have suc- cessively those with less and less silica. It is quite conceivable that local develojjments might bring about such a decrease of the silica and such an increase of one of the oommonest of the bases, iron oxide, that the limits of an ore might be reached. Such bod- ies are almost always highly titaniferous, so much so that in this country they are not available. Not a little attention was direct- ed in earlier years to the Cumberland Hill outcrop in Rhode Island, but it was found to be too high in this element to be suited to furnace practice, j^o analyses are at hand of the Brazilian ex- ample, but a considerable percentage of titanium might be ex- pected. The presence of these ores in Canada, the Adirondacks, and Minnesota is very familiar. It is possible, as indicated by Vogt, that when magnetite crystals had formed in the still fused magma, they became aggregated by magnetic currents in the earth. And it is also conceivable that these early and heavy crystallizations may have settled to the lower portions of the mag- ma ai.J have become concentrated. Much that is more or less speculative is involved in these explanations. The increasing importance of nickel has directed especial at- tention to its deposits and their geological relations. Except in New Caledonia, the metal is chiefly obtained from bodies of nickeliferous pyrrhotite which are associated with rocks of the diorite and gabbro families and are found on the outer rims of in- CLASSIFICATION OF ORE VEPOSITS. bl triisions. Many such are known in Norway, in the Sudbury dis- trict of Canada, and in other places of which the famous but now abandoned Gap Mine in Lancaster Co., Penn., is an excellent ex- ample. An explanation of these relations has been sought in what IS known as Soret's principle.' It was proved by experiments in 1879 by Soret, a French chemist, that if differences of temperature are induced in a solution of common salt or otlier substance in water, the dissolved material will become relatively concentrated in those portions in which the temperature is lowest. It has also been shown ihat this would follow from the laws of osmosis, and that the relative degrees of concentration would be to one another inversely as the absolute temperatures (i. e. temperature Centigrade plus 273). The lower the temperature, therefore, the more dis- solved material would collect in such chilled portion. If now, we consider a fused rock-magma as a complex solution of several silicates, oxides, sulphides and one or two rarer compounds, some in others, and if we regard as the least soluble those that crystallize first in the process of cooling, we are led by Soret's principle to in- fer that these would tend to become concentrated in the portions first cooled, and that in such portions they would be especially abundant after consolidation. The portions of an igneous intrusion that are first cooled are obviously those next the wall rock. The minerals which crystallize first are, as set forth earlier under 1.03.05, magnetite, ilmenite, apatite, pyrite, pyrrhotite and several minor ones. In the case of nickeliferous pyrrhotite the ore bodies are especially rich along or near the contacts of gabbroitic and dioritic intrusions, with their walls, and the paper of J. H. L. Vogt, cited on page 53, has served to bring out some extremely inter- esting facts. The geological relations are more fully set forth later on under nickel and in connection with several American occui'rences, but it may be here added that away from the outer wall the ore bodies fade (at least at tne Gap Mine, Penn.), into barren gabbro, by a fairly gradual transition. In these respects they conform quite closely to conditions which would result from a ' The bearing of this explanation of magmatic differentiations in igneous rocks upon these nickeliferous deposits has been especially set forth by J. H. h. Vogt of Kristiania, Norway, in the ZeitscJirift fur PraktiscJie Oeologie, I. 135, 1898, under the title Sulphidische Ausscheidungen von Nickel-sulphid-erzen. Other related papers appear in the same, I. 4 and 357; II. 41, 134 and 173. 58 KEMP'S ORE DEPOSITS. development according to Soret's principle. We also find in such ore bodies much the same association of minerals, wherever they are mined. Pyrrhotite is in greatest amount and contains the nickel and cobalt, replacing a portion of its iron; as the rarer mineral pentlandite,' or as secondary coatings of millerite in cracks. Chalcopyrite is invariably present, often in important quantity. Vogt has sought to trace out some constancy in the relative amounts of these several metals, but the attempt is not specially successful. He also cites in connection with a discussion of their early formation and combination with sulphur in the fused magma the laws which we know apply in the metallurgical processes in- volving slags and mattes.^ The writings of Lagorio, Iddings, Roseubusch and others re- garding the development of rocks from igneous magmas have emphasized the fact that the laws of solution do not fail to apply, because materials are raised to very elevated temperatures and that they hold good for liquid, molten rock-magmas as well as for heated water or any other solvent. But we find that it is difficult to decide where solution ends and composite fusion begins; and in a heated complex aggregate to determine which is solvent and which dissolved mineral. It is also difficult to be certain that in so viscous a mass as a fused rock there would be sufficient free- dom in the movement of molecules or "ions"^ to enable them to respond to Soret's principle. But it must be admitted that the 1 S. L. Penfield, "Pentlandite from Sudbury, Ont., etc.'' Amer. Jour. Sci., June, 1893, 493. Pentlandite is a sulphide of iron and nickel, isometric, non- magnetic, and with a somewhat varying percentage of nickel, which reached at Sudbury 34.23. The general formula from Penfield's analysis is (Xi Fe) S. 2 As is well known the common metals can be ranged in the following order ("Foumet's Series") according to their decreasing afiLnitv for sulphur, Cu, Ni, Co, Fe, Sn, Zn, Pb, Ag, Sb, As, see Vogt, 1. c. p. 263. In their bearings on geological phenomena these metallurgical laws were discussed many years ago by V. Leonhard in Huttenerzeugnisse und andere auf KiXiutlicliem Wege gebildete Mineralien aZs StiUzpunkte geologiaher Hypothesen, Stuttgart, 18.58. 3 The term "ion" as employed in modern chemistry is more easily il- lustrated than defined. Thus if in a bath used for electroplating we hang at one pole an ingot of metal and turn on the current, we cause the metal to pass to the other pole. The condition of the atoms during transit and while prevented by the electrical force from forming compounds with other elements or stable combinations among themselves is indicated by speaking of them as constitut- ing " ions." CLAaSIfflGATION OF ORE DEPOSITS. 59 form and relations of these ore bodies are what would be developed, did Soret's principle act effectively and have free play. As opposed to the igneous view others have regarded them as contact deposits, brought about by solutions circulating along the outer portions of the intrusions and replacing or impregnating the gabbro, more or less, with ore. The conception is a time-honored one; it involves nothing unreasonable and has the support of some of our ablest investigators, as Emmons 'and Posepny.^ 1.06.17. Under II. 1, the precipitating agencies are men- tioned, which are the cliief causes in the chemical reactions of de- position, and tliese run through all the subterranean cavities as well. The general application is esteemed self-evident. The large part played by organic matter, both when living and when dead and decaying, is notable. Its office even in precipitating the gangue minerals in surface reactions we are just beginning to appreciate. Siliceous sinters have been shown by "W. H. Weed to be formed around the hot springs of the Yellowstone Park through the agency of algae, and A. Rothpletz has recently proved that the calcareous oolites around the Great Salt Lake are referable to mi- nute organisms. Many accumulations of iron ores have, with reason, been attributed to the same agency; but for this metal ordinary and common chemical reactions are oftenest applicable. When or- ganic matter decays, sulphurous gases are one of the commonest products, and likewise one of the most vigorous of precipitants. Thus under Example 24, Paragraph 2.06.03, when speaking of the Wisconsin zinc and lead mines, it will be seen that such an agency from decaying seaweeds has been cited by both Whitney and Chamberlin. When the products of such decomposition become imprisoned in the rocks as oils and gases, their action is unmistak- ably important and is especially available in limestones. Organic matter is a powerful reducing agent as well, and in this way is ca- pable of bringing down metallic compounds. The silver-bearing sandstones of southern Utah are cases in point, as they afford plant impressions now coated with argentite. The purely physical agen- cies cited under (d) have also an important role. 1.06.18. Under 2 (a) the uprising solutions may be diverted by porous strata so as to soak through them and become subject to 1 S. F. Emmons, "Geological Distribution of the Useful Metals in the United States," Trans. Amer. Inst. Min. Eng., Chicago, 1893. Reprint pp. 18-19. ^ F. Posepny, "The Genesis of Ore Deposits," Idem. Beprint p. 194. 60 KEMP- 8 ORIS DEPOSITS. precipitating agents of one kind or another. They furnish the simplest kind of cavities, and starting with these the scheme is de- veloped in a crescendo to the most complicated. The purely chem- ical action of limestone beds, however, seems at times to come into play and to cause precipitation along them. Of all rocks they are the most active chemical reagent. It may be questioned with rea- son as to whether caves or caverns (4), properly so called, have ever formed a resting-place for ores. So many which have been cited as such may with greater reason be referred to shrunken replacements that a doubt hangs over their character. 1.06.19. Under (5) brecciated beds whose fragments are coat- ed and whose interstices are filled with ore are, with great reason, referred to the collapse from the removal of a supporting layer. In addition to the illustration cited, the red hematite deposits of Dade and Crawford counties, Missouri, have been thought to have had a similar origin. Such phenomena are only to be expected in regions that have long been land. Cracks at the bends of folds may, in cases, have occasioned impregnations and disseminations, even when their character is obscured. The cracks need be but small and nu- merous to have occasioned far-reaching results. If a fault fissure, as a possible conduit of supply, crosses the axis of the fold, the necessary conditions are afforded for extended horizontal enrich- ment. Recent explorations with the diamond drill at Mine la Motte seem to corroborate such an hypothesis. Should the anticline or roll afterward sink toward the horizontal, a very puzzling de- posit might originate. Shear zones have been already discussed at length (1.02.03), as have true veins and volcanic necks (see also 2.09.20). As regards contact deposits, the igneous rock, which usually forms one wall, may serve two different purposes. It may act merely as an impervious barrier which directs solutions along its course, or serves to hold them, either because it is itself bent into a basin-like fold, or because it forms a trough with a dense bed dipping in an opposite direction. Such relations occur in the Mar- quette and Gogebic ranges of the Lake Superior iron region. It is not apparent that in these cases the igneous rock has in any degree stimulated circulations. In the more characteristic " contact depos- its " the igneous rock has apparently been a strong stimulator of ore-bearing circulations, and often the source of the metals them- selves. This form of deposit becomes, then, an attendant phenom- enon, or even a variety, of contact metamorphism. Under 11 chromite is the chief illustration. The mineral is practically limit- CLASSIFICATION OF ORB DEPOSITS. 61 ed to serpentinons rocks, and is distributed through them in irreg- ular masses. It appears to be an auxiliary product of alteration. 1.06.20. III. The debris that results from the weathering of rock masses under the action of frost, wind, rain, heat, and cold is washed along by the drainage system of a district, and the well- known sorting action transpires, which is so important in connec- ^'on with the formation of the sedimentary rocks. Minerals of great specific gravity tend to concentrate by themselves, while lighter materials are washed farther from the starting point, and settle only in still water. Stream bottoms supply the most favor- able situations, and in their bars are found accumulations of the heavier minerals which are in the surrounding rocks. The com- monest of these are magnetite, garnet, ilmenite, wolframite, zircon, topaz, spinel, etc., and with these, in some regions, native gold, platinum, iridosmine, etc.; in other places cassiterite, or stream tin, as described under tin. Even an extremely rare mineral such as monazite may make a sandbar of considerable size. (See O. A. Derby, Amer. Jour. Sci., III. xxxvii., p. 109.) The action of surf or smaller shore waves is also a favorable agent. The throw of the breaker tends to cast the heavier material on the beach, where its greater specific gravity may hold it stationary. The heavier min- erals may be sorted out of a great amount of beach sand. Mag- netite sands, which have accumulated in this way, are of quite wide distribution, and at present are of some though not great importance. (Example 15.) With the magnetite are found grains of garnet, hornblende, augite, etc., and often ilmenite. Gold is concentrated in the same way along the Pacific by the wash of surf against gravel clifiEs. In abandoned beaches of Lake Bonne- ville, near Fish Springs, Tooele County, Utah, placers of rolled boulders of argentiferous galena have been worked. A superficial deposit of somewhat different origin is the bed of hematite fragments that mantles the flanks of Iron Mountain, Mis- souri, and runs underneath the Cambro-Silurian sandstones and limestones. This seems to have been formed by the subaerial decay of the inclosing porphyry. The heavier specular ore has thus been concentrated by its greater specific gravity and resistant powers. (See R. Pumpelly, " The Secular Disintegration of Rocks," Proc. Geol. Soc. Amer., Vol. II., December, 1890.) 1.06.21. There remain a few of great importance, but whose geological history is less clearly understood. They are nearly all involved in processes of regional metamorphism, and therefore in 63 KEMP'S OS E DEPOSITS some of the most difficult problems of the science. Lenticular beds or veins of magnetite and pyrite that are interbedded. with schists, slates, or gneisses are the principal group. Such magnetite bodies have been regarded as intruded dikes, as original bodies of bog ore in sediments which have later become metamorphosed, and as concentrated delta, river, or beach magnetite sands. It is possible that in instances they may be replaced bodies of limestone, after- ward metamorphosed. The lenticular shape and the frequent over- lapping arrangement of the feathering edges in the foot wall are striking phenomena. The overlap was referred by H. S. Munroe in the School of Mines Quarterly, Vol. III., p. 34, to stream action during mechanical deposition, and a figure of some hematite lenses in the Marquette region was given in illustration. The arrangement in instances also suggests the shearing and buckling processes of dynamic meta- morphism and disturbance. The individual lenses, now in linear series, were thus all one original bed. The crumpling of the schistose rocks has pinched them by small buckling folds and shoved the ends slightly past each other in the process so familiar in the production of reversed faults from monoclines. Sheared granitic veins on a small scale are a not uncommon thing in areas of schistose rocks, such as Manhattan Island, in the city limits of New York, and suggest strongly this explanation. Should the compression not go so far as to bring rupture of the bed, but only a thickening by the formation of a sigmoid fold, it would occasion an enlarged cr£)ss section, as has been suggested by B. T. Putnam (Tenth Census, Vol. XV. 110) for the great magnetite ore body at Mine 21, Mineville, in the Lake Champlain region. , 1.06.22. Quartz veins, often auriferous and of a lenticular character, furnish another puzzling ore body. They are commonly called segregated veins, and lie interbedded in slates or schistose rocks. If in a pre-existing cavity, it must have been formed, either by the opening of beds under compression, or by displace- ment along the bedding, so that depressions came opposite each other. Replaced lenses of limestone which had been squeezed into this shape from an original, connected bed should also be instanced as a possibility. The name "segregated" would imply a filling by lateral secretion, but it is by no means impossible that solutions have come from below. The veins are another attendant feature on regional metamorphism, and as such deserve more investiga- tion. GLASSIFTCATION OF ORE DEPOSITS. 63 1.06.23. The veins that contain cassiterite in many parts of the world, and that yet have the mineralogical composition of granite, are another product of metamorphic action, both contact and regional. The gangue minerals, feldspar, quartz, and mica, are quite characteristic of acid, igneous rocks, but the coarseness of the crystallization in the comparatively narrow veins bars out a true igneous form of origin. All our artificial methods of repro- ducing these minerals lead us to infer that the veins were filled at a high temperature and pressure, therefore at considerable depths, and through the aid of steam. Cassiterite has also been detected in a few rare cases, under such circumstances that it seemed to be an original mineral in igneous granite. It is probable, therefore, that it may be an original and early crystallization from an igne- ous magma, much as is magnetite. More observed cases would be welcome as evidence. 1.06.24. The great iron ore bodies of Vermilion Lake have been referred by N. H. and H. V. Winchell, in the American Geologist, November, 1889, p. 291, to a precipitation from oceanic waters in the vicinity of submarine volcanic eruptions from whose ejectamenta they derived their iron and silica. The hypothesis is regarded as sufficient to account as well for the siliceous deposits associated with the ore. In the words of the authors : "Chemical precipitation in hot oceanic waters, united with simultaneous sedi- mentary distribution, might produce the Keewatin orrs in a man- ner consistent not only with the physical conditions that prevailed at the time of their formation, and with the structnial peculiari- ties which they exhibit, but also in accordance with the known reactions of heated alkaline waters, and with the chemical char- acter which the ores are known to possess." This hypothesis in- troduces new conditions and relations which are necessarily some- what speculative; and while it has claims to attention, it may best be tested by the general consideration of the geological pub- lic before being placed with the more simple and certain reactions grouped in the scheme. 1.06.25. Fahlbands should be mentioned here. The term re- fers to belts of schists, which are impregnated with sulphides, but not in sufficient amount in the locality where the name was first applied (Kongsberg, Norway) to be available for ores. The de- composition of the sulphides gave the schists a rusty or rotten ap- pearance that suggested the name. Whether the ores are an introduction into the schist, subsequent to metamorphism, or a 64 KEMP'S ORE DEPOSITS. deposit in and with the original sediment, is a doubtful point. The practical importance of these fahlbands lies in the enriching in- fluence that they exert on the small fissure veins that cross them. l."06.26. lu the report of the State Geologist of Michigan for 1891-92 (issued January, 1893) pp. 144, 145, Dr. M. E. Wadsworth has published a "Preliminary Classification of Metalliferous or Ore Deposits." The main outline is as follows : I. Eruptive Deposits {a) Non-Fragmental. (5) Fragmental. II. Mechanical Deposits (a) Unconsolidated. (5) Consolidated. III. Chemical Deposits (a) Sublimations. (V) Water Deposits. (c) Impregnations or Replacements. (d) Segregations or Cavity Deposits. Each of the above except III. {d) is then subdivided so that the table becomes practically a classification of rocks. Indeed, a moment's consideration will show that the scheme in its main divis- ions is closely modeled after the prevailing classification of rocks. III. {d) Segregations or Cavity Deposits contains the following : 1. Pockets. 2. Chambers. 3. Contact Deposits. 4. Veins, in- cluding Gash Veins, Segregated Veins, Reticulated Veins or Stock- work, Contact Veins, Fissure or Fault Veins. The author states in some appended comments that the table is not limited to those deposits now practically worked (which we ordinarily understand the expression ore deposits to mean), but is intended to include all that have been or may be of value. But in this respect there is good ground for preferring to make our clas- sifications in ore deposits, as in mineralogy, zoology, etc., embrace only the authenticated varieties, expecting additions to be incor- porated as discovered and suitably described. The same general grouping as this scheme employs is adopted by E. S. Tarr, in the Economic Geology of the United States, 1894. 1.06.27. For the meeting of the American Institute of Mining Engineers, held in connection with the various congresses at the "World's Fair in Chicago, July, 1893, Professor Franz Posepny of Vienna contributed a grand essay on the " Origin of Ore Deposits." The materials for it were specially assembled by Prof. Posepny while giving a course of lectures at the Przibram Mining Academy in the ten years following 1879. The paper is a theoretical discussion of the origin of ores, with illustrations selected CLASSIFIUA TION OF ORE DEPOSITS. 65 from all parts of the world, but especially from Europe and America. It forms one of the most important contributions to the literature that has yet been made. Posepny distinguishes at the outset between rocks and mineral deposits; i. e., between original materials, such as wall rock, and secondary intro- ductions, such as veins, etc. The former he calls " idiogenites," the latter " xenogenites," basing the names on the familiar Greek terms that run through all our literature. The latter are especially characterized by "crustification," by which term is indicated what has been called "banded structure," on p. 35. The subject of cavities is then taken up, and, while minute pores are stated to be in all rooks, a distinction is made between the larger openings, which originate in a rock mass as a part of its own structure, such as contraction joints in igneous rocks, amygdaloids, and the like, and those induced by outside causes, such as fault fissures. The circulation of water through these is next treated : first, surface waters or"vadose" circulations, which descend; second, ascending waters from great depths, such as springs in deep mines, hot springs, etc. The common salts in solution in these latter are tabulated, being of course mostly alkaline carbonates, sulphates, chlorides, etc. The " exotic " metallic admixtures which would bear on the origin of ores are next discussed, so far as possible with analyses of actual cases. The alterations produced by miner- al springs in rocks and the structural relations of the deposits of mineral springs, especially as expressed by " crustification," are then described. This preliminary material clears the way for the general discussion of the origin of ore bodies. The argument run- ning all through the paper is that ore bodies, even when apparently interbedded with sedimentary rocks, are of secondary introduction and, in general for veins, are from deep-seated sources. Precipita- tion from descending solutions and filling by lateral secretion are strongly controverted. The discussion of origin follows in its arrangement the follow- ing classification of ore deposits : I. Filling of spaces of discission (fissures). II. Filling of spaces of dissolution in soluble rocks. III. Metamorphic deposits in soluble rocks; in simple sedi- ments ; in crystalline and eruptive rocks. IV. Hysteromorphic {i.e., later or last formed) deposits. Secondary deposits due to surface action {i.e., placers, etc.). 66 KEMP 'S ORE DEPOSITS. The treatment, both in tlie introductory pages and in the later discussions, is often strikingly similar to that of this book, and the underlying argument is much the same. The standpoint in both essays is essentially a genetic one, and the main difference lies in the fact that the one is an exposition of an individual's views, fortified by examples from all parts of the world; the other endeavors to be a judicial statement with a complete description of the ore bodies of the United States alone. 1.06.28. An extended treatise on the useful minerals, earthy as well as metallic, by MM. E. Puchs and L. De Launay, has recently appeared {Traite des Gites Mineraux et Metalliferes, Paris, 1893). The book is based on the lectures on economic geology delivered in the Ecole Superieure des Mines, at Paris, in the last fifteen years by the two authors. (Professor Fuchs died in 1889, and was succeeded by Professor De Launay.) A vast amount of valuable information is brought together and discussed from various points of view, useful applications and methods of treatment being set forth as well as geological occurrence. The work is encyclopedic in scope and affords a reader descriptions of mineral resources and references to their literature in every quarter of the world. So far, however, as the United States are concerned the authors have suffered from the unavoidable limitations of those not native and conversant in a discriminating way with our literature. Nev- ertheless they have endeavored to give a large share of their space to this country, and where prominent monographs have appeared they have been read with care, but in many cases, if not in most, the descriptions consulted by them have been from older German or other foreign sources, and the results are often antiquated and confused. It is to be hoped that a later edition will correct most of these. 1.06.29. The classification of ore deposits as well as other useful minerals on a genetic principle has evidently been in many minds in the last few years. Mr. Frederick Danvers Power, ^ of Melbourne, Victoria, reviewed the subject in 1892, and after giving the schemes of others and summing up the various characteristics of veins, has formulated a classification whose main divisions are as follows : I. Contemporaneous ; Indigenous. II. Metasomatic or Chemical Alteration of the Original Constituents. III. Subse- 1 ' ' The Classification of Valuable Mineral Deposits, ' ' Trans, of the Australasian Institute of Mining Engineers, 1893. VLASSIFIGATION OP ORE DEPOSITS. 67 quently Introduced ; Exotic. Each of these has then a number of subdivisions too numerous to be repeated here. Prof. William 0. Crosby/ of Boston has recently discussed the same subject in a very suggestive way. The main headings are : A. Deposits of Igneous Origin (Igneous rocks); B. Deposits of Aqueo- Igneous Origin ; 0. Deposits of Aqueous Origin. The first and last are then subdivided at considerable length, but the second is chiefly limited to the pegmatite (granitic) veins which attend many plu- tonic intrusions. Lack of space prevents the full reproduction of both these schemes, but sufficient has been mentioned, it is hoped, to indicate the line of attack and to place a reader desiring to look the subject up in touch with the originals. 1.06.30. The phraseology of the above schemes will be employed in the subsequent descriptions. In addition, much emphasis will be placed on the character of the rocks containing the deposits, whether unaltered sedimentary, igneous, or metamorphic, and whether in the first and last cases igneous rocks, are near, for these considerations enter most largely into questions of origin. The ore deposits are illustrated by examples, somewhat as has been done by the best of modern writers abroad, Von Groddeck. The word "example" is preferred to "type," which was employed by Von Groddeck, because it implies less of an individual character. We may cite deposits under different metals thus which all might belong to one type. Under each metal will be given, first, a list of general treatises and papers. These will be marked " Hist." when especially valuable as history, and "Rec." when recom- mended for ordinary examination. If not marked by either, they are more adapted for special investigations. 1 " A Classification of Economic Greological Deposits based on Origin and Original Structure, " Arner. Geologist, April, 1894, p. 849. The paper also appears in the Technological Quarterly. 68 KEMP'S ORE DEPOSITS. GENERAL REFERENCES ON ORE DEPOSITS. Ansted, D. T. " On Some Remarkable Quartz Veins," Quar. Jour. Geol. Sci., XIII. 246. Bai-us, Carl. "The Electrical Activity of Ore Bodies," M B., XIII. 417. (See also Heeler's Monograph on the Gomstock Lode, p. .310, for references to other papers.) Becker, G. F. "The Relations of the Mineral Belts of the Pacific Slope to the Great Upheavals," Amer. Jour. Sci., III. 28, 209. 1884. Belt, Th. Mineral Veins: an Inquiry into their Origin, founded on a Study of the Auriferous Quartz Veins of Australia. Lon- don, 1861. Bischof, G. " On the Origin of Quartz and Metalliferous Veins," Jamesoii's Journal, April, 1845, p. 344. Abstract, Amer. Jour. Sci., I. 49, 396. Advocates aqueous deposition. Brown, A. J. "Formation of Fissures and the Origin of their Mineral Contents," M. E., II. 215. Bulkley, F. G. " The Separation of Strata in Folding," 3f. E., XIII. 384. Campbell, A. C. " Ore Deposits," Engineering and Jifi7iing Jour- nal, July 17, 1880, p. 39. Von Cotta-Prime. Ore Deposits. German, 1859; English, 1870. Reo. Emmons, E. American Geology, 134, 1853. General discus- sion. Emmons, S. F. " The Structural Relations of Ore Deposits," M. E, XVI. 304. Rec. " ISJ^otes on Some Colorado Ore Deposits," Proc. Colo. Sci. Soc, II., Part II., p. 35. " On the Origin of Fissure Veins," Proc. Colo. Sci. Soc, II., p. 189. Rec. (See also R. C. Hills, idem, III., p. 177.) "The Genesis of Certain Ore Deposits," M. E, XV. 125. Rea Endlich, F. M. Hayden^s Survey, 1873, p. 276. General descrip- tion of veins. Foster, C. L. " What is a Mineral Vein ? " Abstract in Geol. Mag., Vol. I., 513. CLASSIFICATION OF ORE DEPOSITS. GO Fox, R. W. " Formation of Metallic Veins by Galvanic Agency," Amer. Jour. Sci., I. 37, 199. Abstract from London and Edinburgh Phil. Mag., January, 1839. " On the Electro-Magnetic Properties of Metalliferous Veins in the Mines of Cornwall," Amer. Jour. Sci., I. 20, 136. Abstract of paper before the Royal Society. Grimm, J. "Die Lagerstiitten der Nutzbaren Mineralien," 1869. Von Groddeok, A. " The Classification of Ore Deposits," Engineer- ing and Mining Journal, .June 27, 1885, p. 437. " Die Lehre von den Lagerstatten der Erze," 1879. Rec. (See also Engineering and Mining Journal, Jan. 3, 1880, p. 2, for a review of same.) Hague, J. D. Mining Industries, Paris Exposition, 1878. Henrich, C. " On Faults," Engineering and Mining Journal, Aug. 24, 1889, p. 158. Hunt, T. S. " The Geognostical History of the Metals," M. E., I. 331. " The Origin of Metalliferous Deposits," in " Chemical anc^ Geological Essays." " Contributions to the Chemistry of Natural "Waters," Amer. Jour. Sci., n. 39, 176. Julien, A. A. " On the Part played by Humus Acids in Ore Deposit, Wall Rook, Gossan," etc., Froc. A. A. A. S., 1879, pp. 382, 385. Keck, R. "The Genesis of Ore Deposits," Engineering and Milling Journal, Jan. 6, 1883, p. 3. Review of Ore Deposits in Various Countries. Denver, 1892. 31 pages. Kemp, J. F. " A Brief Review of the Literature on Ore Deposits," School of Mines Quarterly, X. 54, 116, 326; XI. 359; XII. 219. " On the Filling of Mineral Veins," School of Mities Quar- terly, October, 1891. " The Classification of Ore Deposits," School of Mines Quar- terly, November, 1892. "On the Precipitation of Metallic Sulphides by Natural Gas," Engineering and Mining Journal, December, 1890. Kleinschmidt, J. L. " Gedanken ueber Erzvorkommen," B. and H. Zeit., 1887, p. 413. Koehler, G. " Die Storungen der Gange, Flotze, u. Lager." Leip- zig, 1886. Translated by ^Y. B. Phillips under title of "Ir- 70 KEMPS ORE DEPOSITS. regularities of Lodes, Veins, and Beds," Engineering and Mining Journal, June 25, 1887, p. 454; also July 2, p. 4. Leconte, J. " Mineral Vein Formation in Progress at Steamboat Springs and Sulphur Bank," Amer. Jour. Set., III. 25, 424. " Genesis of Metalliferous Veins," Amer. Jour. Sci., July, 1883. See other references under "Mercury." Miller, A. Erzgange. Basel, 1880. Necker. " On the Sublimation Theory," Proc. Geol. Soc. of Lon- don, Vol. I., p. 392; also Ansted's Treatise on Geology, Vol. II., p. 271. Hist. Newberry, J. S. " The Origin and Classification of Ore Deposits," School of Mines Quarterly, I., 1887, 1880. Engineering and Mining Journal, June 19 and July 23, 1880. A. A. A. S., Vol. XXXIL, p. 243, 1883. Rec. " The Deposition of Ores," School of Mines Quarterly, V. 329, 1884; Engineering and Mining Journal, July 19, 1884. *' Genesis of Our Iron Ores," School of Mines Quarterly, II. 1, 1880 ; Engineering and Mining Journal, April 23, 1881. See also under "Iron." ■"Genesis and Distribution of Gold," School of Mines Quar- terly, III., 1881; Engineering and Mining Journal, Dec. 24 and 31, 1881. Rec. Ochsenius, Carl. " Metalliferous Ore Deposits," Geol. Mag., I. 310. Hist. Pearce, Rich. " On Replacement of Walls," Chem. News, March 3, 1865. Phillips, J. A. " The Rocks of the Mining District of Cornwall and Their Relations to Metalliferous Deposits," Quar. Jour. Geol. Soc, XXXI. 319. "A Contribution to the History of Mineral Veins," Quar. Jour. Geol. Soc, XXXV. 390. "Treatise on Ore Deposits," London, 1884. Pumpelly, R. Johnson's EicycL, Vol. VI., p. 22. Rec. Raymond, R. W. "What is a Pipe Vein?" Engineering and Mining Journal, Nov. 23, 1878, p. 361. Translation of Lottner, and general remarks on classification. Min. Stat. West of Eochy Mountains, 1870, p. 447. Indicative Plants, M. E., XV. 645. " Geographical Distribution of Mining Districts in the United States," M. E., I., p. 33. Sandberger, F. " L'ntersuchungen iiber Erzgange," 1882; " Theo- CLASSIFICATION OF ORE DEPOSITS. 71 lies of the Formation of Mineral Veins," Engineering and Mining Journal, March 15, 22, 29, 1884, pp. 197, 212, 232. Wabner, R. " Ueber die Eintheilung der Minerallagerstatten nach ihrer Gestalt, sowie die Anwendung und die Beniitzung der "Worte, Lager und Flotz," B. und H. Z., Jan. 2, 1891, p. 1. Wadsworth, M. E. " The Theories of Ore Deposits," Proc. Bos- ton Soc. Nat. Hist., 1884, p. 197. Rec. " The Lateral Secretion Theory of Ore Deposits," Engineer- ing and Mining Journal, May 17, 1884, p. 364. " Classification of Ore Deposits," Mep. of Mich. State Geolo- gist, 1891-92, p. 144. Rec. Whitney, J. D. " Remarks on the Changes which take place in the Structure and Composition of Mineral Veins near tke Surface," Amer. Jour. Sci., ii. XX. 53. " Metallic Wealth of the United States," 1854. Rec. Whittlesey, C. " On the Origin of Mineral Veins," A. A. A. S., XXV. 213. Williams, Albert. "Popular Fallacies Regarding the Precious Metal Ore Deposits," Fourth Ann. Bep Director U. S, GeoL Survey, pp. 257-278. Crosby, W. 0. "A Classification of Economic Geological Deposits based on Origin and Original Structure," Amer. Geologist, April, 1894, p. 349. Eec. Also in Technology Quarterly. Emmons, S. F. " Geological Distribution of the Useful Metals in the United States," Trans. Amer. Inst. Min. Eng., Chicago Meeting, 1893. Eec. Moreau, George. " Etude Industrielle des Gites Metallif^res," Paris, 1894. Posepny, F. " The Genesis of Ore Deposits," Trans. Amer. Inst. Min. Eng., Chicago Meeting, 1893. Rec. Power, F. D. " The Classification of Valuable Mineral Deposits," Trans. Australasian Inst. Mining Eng., 1893. Tarr, E. S. "The Economic Geology of the United States,', 1894. Vogt, J. H. L. " Bildung von Ezlagerstatten durch Differen- tiationsprocesse in basischen Bruptivmagmata," Zeitschrift f. pralctische Geologie, 1893, pp. 4, 143, 257. " Ueber die Kieslagerstatten vom Typus Roros," etc., Idem, 1894, pp. 41, 117, 173. PART II. THE ORE DEPOSITS. CHAPTER I. THE IRON SERIES (IN PART).— INTRODUCTORY REMARKS ON IRON ORES.— LIMONITE.— SIDERITE. GENERAL LITERATURE. Birkinbine, J. " Prominent Sources of Iron Ore Supply," M. E., XVII. 715. Statistical; Rec. Various statistical papers in the volumes on Mineral Re- sources, U. S. Genl. Survey, especially 1886, p. 39 ; 1887, p. 30. t!hester, A. H. " On the Percentage of Iron in Certain Ores," M. M, IV. 219. Dunnington, F. P. " On the Formation of the Deposits of Oxides of Manganese," Anier. Jour. Sci., iii., XXXVI. 175. The paper treats of Iron also. Hewitt, A. S. "Iron and Labor," M. M, September, 1889. The paper contains valuable statistics. "A Century of Metallurgy," M. M, V. 164. Hunt, T. S. " The Iron Ores of the United States," M. E., October, 1890. Kimball, J. P. " Genesis of Iron Ores by Isomorphous and Pseudo- morphous Replacement of Limestone," Amer. Jour. Sei., September, 1891, p. 231. Continued in Amer. Geologist, December, 1891. Julien, A. A. "The Genesis of the Crystalline Iron Ores," Trans. Phil. Acad. Nat. Sci., 1882, p. 335 ; Engineering and Min- ing Journal, Feb. 2, 1884. " Origin of the Crystalline Iron Ores," Trans. JV. Y. Acad. Sci., II., p. 6 ; Amer. Jour. Sci., iii., XXV. 476. liesley, J. P. " The Iron Manufacturer's Guide," 1866. Hist. Rec. Newberi-y, J. S. International Review, November and De- cember, 1874. " Genesis of the Ores of Iron," School of Mines Quarterly j November, 1880. Rec. Amer. Jour. Sci., iii., XXI. 80. 76 KEMPS ORE DEPOSITS. " Genesis of the Crystalline Iron Ores," Trans. iV. Y'. Acad, ScL, II., October, 1882. Rec. Newton, H. " The Ores of Iron : Their Distribution with Ref- erence to Industrial Centers," M. E., III. 360. Pumpelly, R., and Othei-s. Tenth Census, Vol. XV., 1886, especially pp. 3-17. Rec. Reyer, E. "Geologic des Eisens," Oest. Zeit. f. B. und H., 1882, Vol. XXX., pp. 89, 109. Rogers, W. B. " On the Origin and Accumulation of the Proto- carbonate of Iron in the Coal Measures," Proc. Host. Soc. Nat. Hist., 1856. Smock, J. C. " On the Geological Distribution of the Ores of Iron," M. E; XII. 130. " Iron Mines and Iron Ore Districts in New York," Hull. N. IT. State Mas., June, 1889. Rec. Swank, J. M. Chapters on iron in Mineral Mesources, U. S. Geol. Survey, since 1883. "History of the Manufacture of Iron in All Ages." 1891. Whitney, J. D. "Metallic Wealth of the United States," 1854, p. 425. Hist. " On the Occurrence of Iron in the Azoic System," A. A. A. S., 1855, 209 ; Amer. Jour. Sci., ii., XXII, 38. Winchell, N. H. and H. V. " The Iron Ores of Minnesota," Dull. N'o. 6, 3Iin)i. Geol. Survey. Part IV. contains an exhaustive review of methods of origin, and Part V. a very complete annotated bibliography. Table of the Iron Ores, Limonite, Siderite, Hematite, Magnetite, Pyrite. Limonite (brown hematite, bog ore), 2Fe.,03 SHjO Siderite (Spathic ore, clay ironstone, black- band), FeCO^ Hematite (rpd and specular), FejOj Magnet. tn, FeCFejOs or FegOj Pyrite, FeSj Fe. 59.89 48.27 70.0 73.4 46.7 H,0. 14.4 CO,. 37.93 S. 53.3 2.01.01. No one of the iron ores ever occurs pure in large amounts. Only a few approach this condition. The Lovers' Pit opening, Mineville, N. Y., yielded 40,000 tons of magnetite that averaged 68.6^ Fe., with carloads at 72f»'. The micaceous specular THE IRON SERIES (IN PART). 77 of the Republic Mine, Mich., was shipped an entire season at 69^. The mines, near Tower, Minn., have cleared cargoes at fiS to 68.4^. In general the ores run much less. The richest are the mines of the Lake Champlain district have produced the former, and Lake Superior mines the latter, at 63 to 65^, or even more. The separated ores in the Lake Champlain district run about 65^. The unseparated ores have much less, and indeed all percentages from 60 to 65. Thus the lump ore (shipped as mined) from Chateaugay, N. Y., has about 50%. The Cornwall (Penn.) magnetite holds even less. The Clinton red hematites from Xew York afford about 44^ in the furnace, as the result of long experience. The limonites, as usu- ally mined, produce from 40 to 50^. The crude spathic ores are the lowest of all, and in the variety black-band may even be about Z0%. They are easily calcined, however, and on losing their carbonic acid, moisture, and bituminous matter the percentage of iron rises a third or more. A. H. Chester found in 1875, as the result of an endeavor to determine the average yield of certain standard ores in the furnace. Lake Superior specular, 62.5iJ ; Lake Superior limonite, 49.5^ (much too low to be salable to-day); Rossie (N. Y.) red hematite, 54.5^; Wayne County (N. Y.) Clinton ore, 40^. 2.01.02. The common impurities in iron ores are the common elements or oxides that enter most largely into rocks, and those which make up the walls of the deposit are usually the ones that appear most abundantly in the ore. Silica (SiO^), alumina (AljOj), lime (CaO), magnesia (MgO), titanium oxide (TiOj), carbonic acid (CO2), and water (HjO) appear in large amounts and determine to a great extent the character, fluxing properties, etc., of the ore- With these, and of more far-reaching influence, are smaller amounts of sulphur and phosphorus. The last two and titanium chiefly de- termine the character of the iron which is yielded in the furnace and are the first foreign ingredients sought. The suljjhur is present in pyrite, the phosphorus in apatite. As is well known, 0.1^ of phosphorus is set as the extreme limit for Bessemer pig irons, and as ores for these command the best market, they are eagerly sought. To obtain the allowable limit of phosphorus in the ore, its percentage in iron is divided by 1000. Thus a 65.3^ ore should not have over 0.065^ phosphorus to be ranked as Bessemer. If at the same time, with sufficiently low phosphorus, the gangue is highly siliceous, a composition desirable for Bessemer practice, ores have been of value, although of comparatively low grade and 78 KEMP'S ORE DEPOSITS. remotely situated. For Lake Superior ores the buyers insist to-day on a still lower Bessemer limit, and do not call any ore over 0.05^ phosphorus a strict Bessemer ore. The ore is required to be low enough to carry the phosphorus in both fuel and flux, and still yield a pig iron of not over 0.1^ P. On the other hand a moderate amount of phosphorus is not only no drawback for ordinary foundry irons, and such as are subjected to tool treatment, but is a prime necessity. Exoessivo amounts are desired only for weak but very fluid irons. Considerations like these, which are rather metallur- gical than geological, largely determine the availability of a deposit, and to some extent the present locations of the mining districts. 2.01.03. Iron itself is one of the most abundant and widely disseminated elements entering into the composition of the earth. Several writers have attempted to deduce the general composition of the outer portions of the globe,' but the most reliable computa- tion is that of F. W. Clarke in Bulletin 78 of the U. S. Geol. Surv., pp. 34—43. The crust to a depth of ten miles below sea- level is the subject of the estimate, and the air and ocean are in- cluded. The composition of the solid crust is reached by averaging analyses of igneous and crystalline rocks, 880 in all; 321 from the United States, 75 from Europe, and 486 from all quarters. Igneous rocks, being the ultimate source of the others, furnish a good average. The final result is the following, in which amounts less than 0.01^ are omitted. The total is 100. 49.98 Xa . . . .2.28 P 0.09 Si ....25.30 K ....2.23 Mn . . . , 0.07 Al 7.26 H . . . .0.94 S 0.04 Fe 5.08 Ti ....0.30 Ba 0.03 Ca .... 3.51 C ....0.21 N 0.02 Mg . . . . 2.50 CI. Br.... ....0.15 Cr . ...0.01 From this it is seen that iron is much the most abundant of the useful metals, and that its common impurities, titanium, phos- phorus and sulphur are all present in appreciable amounts. 2.01.04. A general comparison of tabulated analyses of igneous rocks (Eoth's Gestcinsanalysen and Allg. Geol.) shows that granites contain 0.0-7^ iron oxides, porphyries 0.0-14f^, rhyolites 0.0-8^, diorites and diabases 4-16^, andesites 3-15^, basalts 12-20^. 1 Compare Alex. Winchell, Geological Studies, pp. 19-20 — and Prestwicb's Geology, I. p. 10 — both of wbicli were quoted in the first edition of tbis work. THE IRON SERIES {IN PART). 79 Limestones invariably have at least small amounts, and at times very considerable percentages. Sandstones are often low, but not seldom are stained through and through. The metamorphic rocks offer close analogies to the igneous. In general distribution and in quantity, iron leads the list of the distinctively metallic elements. Its peculiar property of possessing two oxides, of different chemical quantivalence, assists greatly in the formation of ores and the general circulation of the metal. This is set forth under the following examples. LIMONITE. 2.01.05. Example 1. Bog Ore. — Beds of limonite, superficially formed in marshes, swamps, and pools of standing water. The general circulation of water through the rocks enables it very frequently to take up iron in solution. Ferruginous minerals are among the first and easiest that fall a prey to alteration. Car- bonic acid in the water aids in dissolving the iron, which thus, in waters containing an excess of COj, passes into solution as the protocarbonate FeCOj. Organic acids may also play a part. The alteration of pyrite affords sulphuric acid and ferrous sulphate, and the latter enters readily into solution. On meeting calcium carbonate, both ferric and ferrous sulphate are decomposed, yield- ing in the first case calcium sulphate, ferric hydrate, and carbonic acid; in the second, if air is absent, ferrous carbonate and calcium sulphate, but on the admission of air ferric hydrate soon forms. (See F. P. Dunnington, Anier. Jour. ScL, iii., XXXVI. 176. Ex- periments 10 and 11.) 2.01.06. Bodies of limonite that become exposed to a reduc- ing action from the favorable presence of decaying organic mat- ter likewise furnish the protocarbonate. In general it may be stated that free oxygen must be absent or only in small quantity where solution takes place. Sooner or later the ferruginous (or chalybeate) waters come to rest, especially in swamps. The proto- salt is exposed to the evaporation of the excess of COj, that held it in solution, and also to the action of oxygen. Two molecules of carbonate, together with one atom of oxygen and some water, break up into COj and FcjOj, x IT^O. The latter forms as a scum and then sinks to the bottom and accumulates in cellular masses. The eesquioxide is insoluble, and as against ordinary waters free from reducing agents it remains intact. Deposits of mud and peat forming above may cover the beds with a protecting layer. 80 KEMP'S ORE DEPOSITS. Hardly a bog exists which does not show, when cut in cross sec- tion, the bog ore beneath. Frequent associates of the ore are diatomaceous earth and shell marl, formed by the remains of or- ganisms which once inhabited the waters. At times excellent im- pressions of leaves and shells are preserved in the ore. Such ore bodies are not often practically available on account of the low percentage in iron, due to the abundance of sand and silt washed in, and to the frequent large amounts of sulphur and phosphorus which they contain. The sulphur is present in pyrite and the phosphorus in vivianite, sometimes in sufficient quantity to be visible (Mullica Hill, N. J., var. Mullicite). In certain parts of the country bog deposits have been and others may yet be utilized. 2.01.0'/. In eastern North Carolina bog-ore beds are frequent and are found lying just below the grass roots. Scattered nodules occur in the overlying soil, which are succeeded by a bed three feet or less in thickness, resting on sand.' In Hall's Valley and Handcart Gulch, Park County, Colorado, in- teresting and extensive deposits of limonite are in active process of formation. The iron comes from neighboring great beds of pyrite.^ Bog ore of good quality has recently been reported from the vicinity of Great Falls, Mont.' At Port Townsend Bay, in the vicinity of Puget Sound, and at the Patton mines, near Portland, Ore., the ores are of such quality as to be available.* Attention has been lately directed to the great deposits of bog ore in the Three Eivers district of the province of Quebec in Canada. Three Eivers is on the St. Lawrence about midway be- tween Montreal and Quebec but the district which furnishes the bog ores extends from nortlieast of Quebec to a point west of Ottawa, an area stated by GriflBn to be 400 miles long by 40-60 broad. The drainage of the old Archean heights of the Lauren- tides, the range that suggested the name Laurentian, crosses the belt and being more or less laden with ferruginous solutions it de- posits the ore in swamps, streams and lakes, wherever the water is 1 W. C. Kerr, Geology of mrth Carolina, 1875, p. 218. B. Willis, Tenth Census, Vol. XV., p. 303. H. B. C. ISTltze, BuU. I., N. C. Geol. Survey, 1893. 2 R. Chauvenet, ' ' The Iron Resoiirces of Colorado, "J/. E., Jxme, 1889. ' ' Notes on Iron Prospects in Northern Colorado, ' ' Ann. Rep. Colo. School of Mines, 1886. " Mineral Resources, U. 8. Oeol. Survey, 1888, p. 34. * B. T. Putnam, Tenth Census, Vol. XV , p. 496. THE IRON SERIES {IN PART). 81 for a time stationary or choked with vegetation. The ore beds furnish ideal illustrations of bog ore deposits in all their forms. Beginning as a light film the ore gradually accumulates on the bottom, where it hardens into thick crusts. These are exposed in the dry season in the shallower reaches and become dried to very hard cakes. The succeeding wet season buries them again under more ore, or sand and ore. until the thickness attained is very con- siderable. The ore precipitates also in running water and has been obtained from ravines in goodly amount. Even in the pipes used at the furnace at Eadnor Forges for conveying the necessary water supply from the neighboring Eiviere au Lard the limqnite de- posits. The river flows from the swamp called Grand P16, in tlie midst of which is a shallow lake called Lac-a-la-Tortue. Ore is dug in the swamp and dredged in the lake. The supply is renewed after being removed. The deposits present many analogies with those of the Swedish lakes, later mentioned, but they supply caked ore rather than the oolitic form of the latter. The iron industry began in the region in 1730 and has continued more or less inter- mittently to date.' The iron furnished has especial excellence for oar-wheels and chilled castings. The lake ores seem to run some- what richer than those of the bogs. The latter contain about 42.5 Fe, the former 49. Both have a little over 0.3 P and less than 0.1 0. These ore bodies are of great scientific interest for they illustrate (as has been recognized for many years) the formation of bodies of other kinds of iron ores when in sedimentary series and even when metamorphosed. 2.01.08. A somewhat different variety of Type 1 is formed when the ferruginous waters come to rest in the superficial hollows of the rock which has furnished the iron. Depressions in the serpen- tines of Staten Island, N. Y., carry such deposits, and the iron is referred by N. L. Britton to the leaching of the underlying rock. The ore contains a notable percentage of chromium, which is known to occur in the serpentine. The mines have been in former years quite large producers. Similar limonltes occur at Eye, N. Y. * 1 See especially, P. H. Griffin, ' ' The Manufacture of Charcoal -iron from the Bog and Lake-ores of the Three Rivers District, ' ' Trans. Amer. Inst. Min. Eng., Feb., 1893. Also J. H. Bartlett, Idem, 1885. " N. L. Britton, School of Mines Quarterly, May, 1881. Compare also Amer. Jour. 8oi., iii., XX. 32, and XXII. 488. 82 KEMP'S ORE DEPOSITS. At the Prosser mines, near Portland, Ore., deposits of limonite are found in the superficial hollows of a Tertiary basalt of the Cascade range. The ore contains roots and trunks of trees, and is covered by a later flow of basalt. Similar bodies of limonite re- sulting from basalt are known in the German province of Hesse and in Ireland.' 3.01.09. The limonite sand, or oolite, that forms in the Swedish lakes about ten meters from the banks and in water up to ten meters in depth is another variety of this type. A layer half a meter and less in thickness accumulates every fifteen to thirty years and is periodically dredged out. The ore precipitates first as a slime that breaks up afterward into small concretions. It has been thought that the formation of these and similar bodies of limonite has been aided by small algoe and other plants or micro- scopic organisms. ^ 2.01.10. Example 2. Bodies of limonite in cavities of fer- ruginous rocks, on the outcrop, or below the surface, which have resulted either from the alteration of the rock in situ or from its partial replacement by limonite. Residual clay, quartz, and other remains of alteration usually occur with the ore. Ferruginous limestones are the commonest sources of such deposits, but otlier rocks may afford them. The deposits are not limited to any one geological series, but in different parts of the country occur when- ever the conditions have been favorable. Some of the ore may have been brought in by subterranean circulations which have leached the neighboring rocks. Considerable limonite has also re- sulted from the weathering of clay-ironstone nodules and black- baud beds in the Carboniferous system (to be mentioned later), and not infrequently from the alteration of nodular masses of pyrites. "■ B. T. Putnam, Tenth Census, Vol. XV., p. 16, on the Oregon ore. Tasche, Berg.- uad Hutt. Zeit., 1886, p. 209; also Wurtemberger, Xeues ,/ahrb. 1867, p. 685, on the Hessian ores. Tate and Holden, "On the Iron Ore Associated with the Basalt of Northeastern Ireland, " Qnar. Jour. Geol. Soc, XXVI. lul. 2F. M. Stapflf, Zeitschr. d. d. geolog. Gesellsh., 1866, Vol. XVm., p. 8, on the geology of the ores. Sjognm, Berg.- imd Huett. Zeit., 1865, p. 116, on the agency of algae. On the general formation of bog ores the fol- lowing papers are of interest : Gr. J. Brush and C. S. Rodman, ' ' Ob- servation on the Native Hydrates of Iron," Amer. Jour. Sci., ii. , XLIV. 319; J. S.Newberry, School of Mines Quarterly, Novembei, 1880; J. Roth, Cliem. mid Phys. Geologic, I., pp. 58, 97, 331; F. Senft, Humus, Marsch, Torf- und Limonil-hildaiigen. THB IRON SEUIES (IN PART). 83 The limonite is in cellular lumps, in pipes, pots, and various imita- tive forms which often have a beautiful luster. The hollow masses have in general resulted form the filling of reticulated cracks in shattered rock. The ore thus deposits around the cores of country rock, which afterward are removed, leaving a hollow shell or geode. (See Tenth Census, Vol. XV., pp. 275, 369, 370.) 2.01.11. Reserving the Siluro-Cambrian limonites for a subtype the ore bodies are described in order from east to west, taking up first the Alleghany region, then the Mississippi Valley, and lastly Fig. 8. — Section of the Hurst limonite bank, Wythe County, Virginia, illustrating the replacement of shattered limestone with limonite and the formation of geodes of ore. After E, B. Benton, Tenth Census, Vol. XV., p. 275. the Rocky Mountains. The limonites of Xew England and New York belong in the subsequent subtype, as do those of eastern Pennsylvania and the more important ones in Virginia, Tennessee, Georgia, and Alabama. In central and western Pennsylvania, however, not a small amount is obtained from the higher lying terranes. The Hudson River slates furnish small amounts in Franklin County, which are thought by McCreath to have resulted from the alteration of nodules of pyrites. (Second J-'enn. Geol. Sur- vey, M.3, p. X.) The Medina sandstones contain highly ferrugi- nous portions in Huntingdon County. (McCreath, Second Penn. Geol. Survey, MM, p. 198.) The Lower Helderberg and Oriskany 84 KEMP 'S ORE DEPOSITS. are locally quite productive in Blair County, affording several great banks of ore. (Report MM, 196, M3, p. 33.) The Oriskany is of greater importance in Virginia than in Pennsylvani'a. East of these last mentioned exposures, and in southern Carbon County, is a bed of paint ore between the Oriskany and the Marcellus. (C. E. Hesse, « The Paint-Ore Mines at Lehigh Gap," M K, New York meeting, 1890.) The Marcellus is the most productive of the Devo- nian stages. It affords considerable ore in Perry County (Report MM, p. 193 ; M3, p. 29), Juniata County, Mifflin County, Hunting- don County (Report M, p. 66 ; MM, p. 194 ; M3, p. 140), Fulton County (Report M3, p. 42), and Franklin County (Report M3, p. 1). All these are in southern Pennsylvania. Lesley states {Iron Manufacturer S Guide, p. 650) that the ore is weathered car- bonate. As shown under Example 4, beds of carbonate ore occur in Ulster County, New York, in the Marcellus. (Additional details on the above Pennsylvania deposits will be found in the geological reports on the particular counties.) 2.01.12. As already remarked, the greater part of the limonites in Virginia belong under the Siluro-Cambrian division and are there described, but in the James River basin, on Purgatory and May's Mountains, there are deposits in sandstones of the Clinton. (J. L. Campbell, The Virginias, July, 1880.) Other limonite beds occur in the Oriskany on Brushy Mountain (Longdale mines), on Rich Patch Mountain (Low Moor mines, called by Lyman, Marcellus), on Warm Spring Mountain, and on Peter Mountain. lu the Shenan- doah Valley, on Massanutton Mountain, the limonite is referred by Prime to the Clinton stage. {The Virginias, March, 1880, p. 35.) On North Mountain it lies in the Oriskany, according to Camp- bell {The Virginias, January, 1880, p. 6), and on the Great North Mountain in the Upper Silurian. Considerable oxide of zinc collects in the tunnel heads of the furnaces running on Low IMoor ores, indicating the presence of this metal in the limonite.' The Oriskany ores (including those referred by Lyman to the Marcellus) were formerly the chief sources of Vii'ginia iron, and at Longdale and Low Moor afforded very large amounts, but lately ' B. S. Lyman, ' ' Geology of the Low Moor, Va. , Iron Ores, ' ' Trans. Amer. Inst. Min. Eng., Feb., 1886. E. C. Means, "Flue Dust at Low Moor, Va. , ' ' Trans. Amer. Inst. Min. Eng. , 1888. E. C. Pechin, ' ' Vir- ginia Oriskany Iron Ores, " Engineering and Jlining Journal, Aug. 18, 1892, p. 150. " Iron Ores of Virginia, " etc. , Trans. Amer. Inst. 2Iiu. Eng., XIX. 1016, 1890. THE IRON SERIES (IN PART). 85 the Siluro- Cambrian have talcen pi'ecedence. Tlie Oriskany ores yielded from 40 to 43^ Fe in tlie furnace (Pechin), and were non- Bessemer. They had au excellent reputation for foundry and mill- work. Another prominent source of brown hematite ores in Virginia has been of recent years the weathered and oxidized npper portions of the great pyrites deposits in Floyd, Grayson and Carroll Counties, in the southwestern part of the State. This belt extends over 20 miles and is known as the "Great Gossan Lead." Although uniformly pyrites or pyrrhotite below the water line, it is sufficiently oxidized above to yield an ore of about 40 to 41^ Fe, with the sulphur not much over one per cent. The greatest depth is attained where the belt crosses tlie iiills. The ores supply a useful mixture for the neighboring Siluro-Cambrian brown hematites. 1 Fig. 9. — Geological Section of the Low Moor, Va., Iron-ore Bed. After B. 8. Lyman, Trans. Amer. Iiust. Min. Eng.. Feb., 1886. A — Marcellus Shale ; B — Oriskany Sandstone ; C — Lower Helderberg Limestone; D — Clinton Shales. The iron ores in Kentucky are found in three widely separated districts, one near Greenup, in the northeastern corner of the »State, known as the Hanging Eock region; the second near the central part along the Red and Kentucky Rivers, known as tlie Kentucky and Red River region; and the third in the southwestern part near Lyon and Trigg Counties, known as the Cumberland River region. Although the first two contain much limonite, it has altered from nodules of carbonate, and the ores are therefore described under Example 5. One locality near Owingsville, in the second region, has limonites altered from the Clinton hematite. (See Example 6.) The Cumberland region affords limonites in the Subcarbonif- erous. They are in rounded masses, either solid or hollow, and are distributed through a red clay along with angular fragments 1 E. C. Moxham, ' ' The Great Gossan Lead of Virginia, ' ' Amer. Inst. Min. Eng , XXI. 133, 1892. Trans. 86 KEMP 'S ORE DEPOSITS. of chert. The limonite pots are themselves filled with clay or water, i 2.01.13. In Tennessee the limonites of the eastern portion come mostly under Example 2a. In the west they are a southern ex- tension of the pot-ore deposits of Kentucky, and show the same as- sociated chert and clay. Safford has called the rocks containing them the Siliceous Group. The west Tennessee district projects into Alabama to a small extent.^ 2.01.14. The principal limonite deposits of Alabama come under Example 2a, as do those of western North Carolina and Georgia. Some limonite is produced in Ohio, but it is all weathered carbon- ate and is mentioned under Example 5. Hydrated ores are abundant in the Lake Superior region, but are mentioned in connection with hematite. (See also 2.01.3^.) Deposits of brown hematite are worked in a small way in the southeastern part of Missouri, where they rest upon Cambrian strata and have a marked stalactitic char- acter. (P. N. Moore, Geol. Survey of Missouri, Eeport for 1874; F. L. Nasou, Mo. Geol. Survey, 1892, II., p. 158.) Limonites re- ferred to the Cretaceous by N. H. Winchell occur in weste«L Minnesota. {Bull. VI., Minn. Geol. Survey, p. 151.) 2.01.15. Tlie Annual Reportofthe Geological Survey of Arkan- sas, Vol. I., consists of a report by E. A. F. Penrose on the ''Iron Deposits of Arkansas." It at once appears that there is little pros- pect of Arkansas producing any notable amounts of iron ore. Such deposits as have been found are practically all limonite (brown hematite) and are generally very low in iron. The ores occur in five districts, viz: Northeastern Arkansas, northwestern Arkansas, the valley of the Arkansas Eiver, the Ouachita Mountains, and southern Arkansas. They are generally associated with sandstones or cherty limestones. The first named district makes the best showing. In it the ores are in Lower Silurian (Calciferous or Lower) sandstones, cherts and limestones. In the second district they are in Lower Silurian cherts, and Lower Carboniferous sand- stones. In the third they occur with Carboniferous and Lower Carboniferous strata, but are also in the form of recent spring de- posits. In the Ouachita Mountains they are witli Lower Silurian 1 W. B. Caldwell, "Report on the Limonite Ores of Trigg, Lyon, and Caldwell Counties," Kentucky Oeol. Survey, New Series, Vol. V., p. 251. ^W. M. Chauvenet, Tenth Census, Vol. XV., p. 357; T. H. Saflford, Geology of Tennessee, p. 350. THE IRON mnilCS (IN PART). 87 shales and novaculites. In this district the magnetite or natural lodestone of Magnet Cove occurs, but it is only an interesting mineral and of no practical importance. The last district has the ores in sands and clays oE the Eocene. Its continuation in Texas and Louisiana is referred to below. In eastern Texas, along the latitude of the northern bound- ary of Louisiana, extended beds of limonite are foniid cap- ping the mesas or near their tops, and associated with glauconitic sands oi Tertiary age. They are described by Penrose {Mrst Ann. Bep. Texas Geol. Survey, p. 66; also G. S. A., III. 44) as (1) Brown laminated ores, (2) Nodular or geode ores, (3) Conglom- erate ores. The first form extended beds whose firmness has prevented the erosion of the hills, and which are thought to have originated by the weathering of the pyrites in the greensands and from the iron of the glauconite itself. The second group occur just north of the last, and have probably resulted from the altera- tion of clay ironstone nodules (Cf. Example 5), while the third has formed in the streams by the erosion of the first two and from the smaller ore-streaks and segregations. Limonite also occurs in northwestern Louisiana. [Mineral Resources, 1887, p. 51.) Mr. Lawrence C. Johnson has also written of these ores {Fiftieth Con- gress, First Session, Exec. Doc. No. 195), but the most complete account has been given by W. Kennedy (" Iron Ores of East Texas," Trans. Amer. Inst. Min. Eng., Feb., 1894). Mr. Kennedy speaks of the available ores as the " Laminated Ores " and the "Nodular Ores," both belonging, in serious amount, to the greensand beds of the upper Eocene. An abundant series of analyses are given which show the ores to be in general rather rich for limonites, and not high in sulphur or phosphorus. According to the grade of ore now demanded and obtained on Lake Superior, they are seldom Bessemer ores, but ought to yield excel- lent foundry irons. While the quantity is large, the situation pre- cludes the use of any fuel but charcoal, and the remoteness of markets will mostly restrict the output to the comparatively limited local demand. The ore can be won by shallow stripping or from exposed beds, up to two feet or so in thickness. The geological relations of these ores are interesting and important in that they are derived from greensands, whicli consist so largely of glauconite, the double silicate of iron and potassium, and which are comparatively deep-sea deposits. The formation of glauconite by precipitation from sea-water, and as a filling of the small chambers 88 KEMP'S ORE DEPOSITS. in minute shells and organisms indicates^ a marine method for the concentration of iron oxide. It is significant that J. E. Spurr has lately advocated a similar source for the ores of the Mesabi range, Minn. (See Example 9e.) Limonite is known in a num- ber of localities of Colorado. The chief productive mines lie in Saguache County, near Hot Springs. They furnish a most excel- lent ore from cavities in limestones, which are generally, but with no great certainty, considered Lower Silurian. K. Chauvenet states that the ores yield about 43^ Ee in the furnace.^ A great body of limonite nodules, bedded in red, residual clay, has been reported from the Clinton series of Allamakee County, Iowa. (E. Orr, Amer. Geologist, Vol. I., p. 129.) Much limonite occurs at Leadville in connection with the lead- silver ores, and is used as a flux by the lead smelters. Some grades low in silver and rich in manganese have even been used for spiegel at Pueblo. For the geological relations, see Example 30. 2.01.16. Limonites in supposed Carboniferous limestone occur in the East Tintec mining district in Utah, and seem to be as- sociated with a decomposed eruptive rock, somewhat as at Lead- ville. The limonite is chiefly used as a flux by lead-silver smelters.^ 2.01.17. Example 2a. Siluro- Cambrian Limonites. — Beds of limonite in so-called hydromica (talcose, damourite), slates and schists, often also with limestones of the Cambrian and Lower Silurian systems of the Appalachians. The great extent, the geo- logical relations, and the importance of these deposits warrant their grouping in a subt3-pe by themselves. They extend along the Ap- palachians from Vermont to Alabama, and are in the " Great Valley," as it was early termed, which marks the trough between the Archean on the east and the first corrugations of tlie Paleozoic rocks, often metamorphosed, on the west. The masses of limonite are buried in ochreous clay, and the whole often preserves the gen- eral structure of the schistose rocks which they have replaced. The 1 On the formation of greensands, see W. B. Clark, Journal of Ge- ology, II., 161, 1894. " R. Chauvenet, ' ' Preliminary Notes on the Iron Resources of Col- orado, " Ann. Rep. Colo. State School of Mines, 1885, p. 31; "Iron Re- sources of Colorado, " .V. E., 1889. F. M. Endlich, Hoyden's Reports, 1873, p. 333. B. T. Putnam, Tenth Census, Vol. XV., p. 482. C. M. Rolker! "Notes on Certain Iron Ore Deposits in Colorado, ' ' M. E., XIV. , 266. Rec. 8B. T. Putnam, Tenth Cen.ivs, Vol. XV., p. 490. THE IRON SERIES (IN PART). 89 original stringers of quartz remain following the original folds. Dolomitic limestone often forms one of the walls, and still less often (but especially in New England) masses of siderice are found inclosed. Manganese is at times present, and in Vermont is of some importance of itself. 2.01.18. The deposits begin in Vermont, where in the vicinity of Brandon they have long been ground for paint. A curious pocket of lignite occurs with them and affords Tertiary fossils. This prompted President Edward Hitchcock, about 1850, to refer all the limonites to the Tertiary, making an instructive example of the oc- casional hasty generalizations of the early days. Lignite has also been found at Mont Alto, Penn. In northeastern Massachusetts, at Richmond and West Stockbridge ; and just across the State line, in Columbia and Dutchess counties. New York, and at Salisbury, Conn., the mines are large, and were among the iirst worked in the A San^ J ^ 1 Engine House KwilH-5.nd Gra vel a K Pit Ore Fig. 10. — Geological section nf the Amenia Mme, Dutchess County, New York, illustrating a Siluro-Cambrian limonite deposit. After B. T. Putnam, Tenth Census, Vol. XV., p. 133. United States. The limonite forms geodes, or "pots," pipes, stalactitio masses, cellular aggregates, and smaller lumps from which the barren clays and ochers are removed by washing. The ore is but a fraction of the material mined and occurs in irregular streaks through the clays, etc. It is mostly obtained by stripping and open cuts, and only rarely by underground mining, which would present difficulties with such poor material for walls.' ' J. D. Dana, " Occurrence and Orlg-ln of the New York and New Eng- land Limonites," Amer. Jour. Sei., iii., XIV. 1.S3, and XXVIIl. 398. Rec. E. Hitchcock, "Description of a Brown Coal Depjfit at Brandon, Vt., with an Attempt to determine the Geological Age of the Principal Ore Beds of the United States," Amer. Jour. Sci., ii., XV. 95 ; Hist. 6eol. Survey of Vermont, I. 333. See also Lesley, below. A. L. Holley, " Notes on the Salisbury (Conn.) Iron Mines and Works," M. E., VI 220. J. P. Lesley, "Mont Alto (Penn.) Lignites," Proc. Amer. Acad. Sri., 1864, 463- 483 ; Amer. Jour. Sci., ii., XL. 119. L. Lesquereux, " On the Fts 11 Fruits found in Connection with the Lignite at Brandon, Vt.," Amer. Jour. Sci., 90 KEMP'S OUK DEPOSITS. A gap occurs in the succession of the deposits across southern New York and New Jersey, although a few minor ones are known in the western part of the latter State, in the magnesian limestone of the valleys between the hills of gneiss.' 2.01.19. In Lehigh County and to the southwest through York County, in eastern Pennsylvania, the limonites are again developed in great amount, and run southwesterly, with few gaps, to Alabama. It is in this portion that the " Great Valley " (called also the Cumberland Valley, or Valley of Virginia) is especially marked. Wherever the great limestone formation, No. II. of Rogers, is developed the ores are found. This corresponds to the Calciferous, Chazy, and Trenton of New York. Limonites also occur still lower in the Cambrian at about the horizon of the Potsdam sand- stone or in the overlying slates. According to McCreath, they are distinguishable in Pennsylvania as ores at the top, ores in the middle, and ores at the bottom of the great limestone No. II. Those at the top form the belt along the central part of the valley where the Trenton limestone underlies the Utica or Hudson River slates. Those in the middle are connected with various horizons of ferruginous limestones in the Chazy and Calciferous. Those at the bottom along the north or west part of the South Mountain- Blue Ridge range are geologically connected with the Potsdam sandstone, or the slates which intervene between it and the base of the Calciferous. {Second Penn. Survey, Rep. MM, p. 199.) Cobalt has been detected on those of Chester Ridge by Boye, but it is a rare and unique discovery.^ ii., XXXII. 355. H. Carvill Lewis, "The Iron Ores of the Brandon Pe- riod," ^mer. 4. ^. Sci., XXIX. 437, 1880. J. F. Lewis, "The Hematite (Brown) Ore Mines, etc., East of the Hudson Eiver," M. E., V. 216. J. G. Percival, Rep. on the Oeol. of Conn., p. 132 ; also, Amer. Jour. Sci., ii., 11.268. R. A. F. Penrose, " Report on Manganese Ores," Geol. Survey ArTc., 1890, Vol. I. (Contains many valuable descriptions of Vermont limonites.) B. T. Putnam, Tenth Census, Vol. XV. C. N. Shepard, "No- lice, etc., of the Iron "Works of Salisbury, Conn.," Amer. Jour. Sci., i., XIX. 311. J. C. Smook, Bull. VIl. New York State Museum, pp. 12, 52. N. H. and H. V. Winohell, " Taconic Ores of Minnesota and Western New England," Amer. Geol, VI. 263. 1890. 1 B. T. Putnam, Tenth Census, Vol. XX., p. 176. See also Oeol. Sur- vey Neiv Jersey, 1880. ° Dr. Boye, "Oxyd of Cobalt with the Brown Hematite of Chester Ridge, Penn., Amer. Phil. Soc, January, 1846. P. Eraser, Second Geol. Survey Penn., Reps. C and CC ; " Origin of the Lower Silurian Limonites THE IRON SKRIKS (IN PART). 91 2.01.20. The Siluro-Cambrian limonites run across Maryland in Carroll and Frederick counties, and are mined to small extent. (E. R. Benton, Tenth Census, Vol. XV., p. 254.) These limonites are again strongly developed in the Shenandoah Valley along the western base of the Blue Ridge, and in south- western Virginia in the Cripple Creek and New River belt. The ores occur in connection with calcareous shales, calcareous sand- stones, and impure limestones, but have not justified the expecta- tions formed of them. In Carroll County, Virginia, the gossan of the great deposit of pyrite is dug for iroa ore. The walls, however, are older than the Cambrian.' 2.01.21. The limonites of eastern Tennessee are the southern prolongation of the area of southwest Virginia. They lie between the Archean of the Unakn range on the east, and the Upper Silurian strata in the foot of the Cumberland tableland on the west. The ores outcrop in the longitudinal valleys or " coves." The bottoms of these valleys, according to Safford (p. 449), are formed by the shales, slates, and magnesian limestones of the Knox group, and in of York and Adams Counties." Proc. Amer. Phil. Soc, March, 1875. J. W. Harden, "The Brown Hematite Ore Deposits of South Mountain between CaiLsle,Waynesborough, and the Southeast Edge of Ihe Cumberland Val- ley," M. E., I. 136. J. P. Lesley, Summary, Final Repjrt, Vol. I., 1892, pp. 205, 341. Rec. A. S. McCreath, Second Oeol. Survey Penn., Vol. MM, 199. F. Prime, Second Geol. Survey Penn., Reps. D and DD ; "On the Ocfiirrence of tlie Brown Hematite Deposits ot the Great Valley," M. F., i;i. 410 ; Amer. Jour. Sci., ii., IX. 433 ; also, XI. 63, and XV. 361. Rec. B. T. P.itaam, Tenth Census, Vol. XV., p. 181. 1 D. R. Benton, Tenth Census, Vol. XV., p. 261. J. L. Campbell, "Report on the Mineral Prospects of the St. Mary Iron Property," etc., The Virginias, February, 1883, p. 19. See also The Virginias, January, 1880, p. 4 ; March, p. 43. F. P. Dewey, " The Rich Hill Iron Ores," M. E., X. 77. W. M. Fontaine, "Notes on the Mineral Deposits of Certain Lo- calities in the Western Part of the Blue Ridge," The Virginias, March, 1883, p. 44 ; April, p. 55 ; May, p. 73 ; June, p. 93. B. S. Lyman, "Oa the Lower Silurian Brown Hematile Beds of America," -.4. A. A. S., XVII. 114. A. S. McCreath, " The Iron Ores of the VaUey of Virginin," ;)/. £■., XII. 103; Engineering and Mining Journal, June, 1883, p. 334. E. C. Mux- ham, " The Great Gossan Lead of Virginia," M. £•., February, 1892. E. C. Pechin, "The Iron Ores at Bupna Vista, Rockbridge County, Virginia," Engineering and Mining Journal, Aug. 3, 1889, p. 92; "Mining of Potsdam Brown Ores in Virginia," Engineering and Mining Journal, Sept. 19, 1891, p. 337; "Iron Ores of Virginia and Their Developments,'' M. E., XIX. 101; "Ore Supply for Virginia Furnaces," Engineering and Mining Journal, Vol. LI., 1891, pp. 323, 349. R"c. '1 s - -^ i « -"M - ^ ^*. I ^ ^ THE IRON SEUIEa (IN PART). 93 the residual clay left by their alteration the ore is found. The gos- san of the neighboring veins of copper pyrites, best known at Duck- town (see Example 16), were originally exploited for iron.' The Tennessee limonite extends across northwestern Georgia, and still farther east the Hiironian limestones of North Carolina also enter the State. But as even these Huronian schists and as- sociated marbles have been considered by F. P. Bradley to be metamorphosed Silurian (Cambrian), the ores may also belong un- der Example 2a. The well-determined Siluro-Cambrian rocks form but a narrow belt of no great importance in North Carolina.' The limonites are again strongly developed in Alabama and furnish a goodly proportion of the ore used in the State. They form a belt lying east of the Clinton ores (Example 6), later de- scribed. As in Tennessee, they are associated with strata of the Knox group.' 3.01.22. Extensive deposits of hydrated ores also occur in all the Lake Superior iron ranges. They are often yellow aud ochreous, but they are not true limonites as their percentage in iron often reaches 62^. They are partially hydrated hematites. 2.01.23. Origin of the Silvro- Cambrian Limonites. — Dr. Jack- son of the First Pennsylvania Survey argued in 1839* that they originated in situ ; that is, by the alteration of the rocks in and with which they occur. Percival, in his report on the Geology of Connecticut, in 1842 (p. 132) attributed them to the alteration of pyrite in the neighboring mica-slate. Prime, in Pennsylvania, in 1875 and 1878 (Reports D and DD), considers that the iron has been obtained by the leaching of the neighboring dolomites and slates, it being in them either as silicate, carbonate, or sulphide ; that the ore has reached its position associated with the slates, be- cause, being impervious, they retained the ferruginous solutions ; and that the potash abundantly present in the slates probably as- sisted in precipitating it.* Frazer, in 1876,' in studying the beds of 1 J. M. Safford, Geol. of Tenn., p. 448, 1869. B. Willis, Tenth Census, Vol. XV., p. 331. 2 F. P. Bradley, " The Age of the Cherokee County Bocks, North CaroliQa," Amer. Jour. ScL, iii., IX. 379 and 320; B. "Willis, Tenth Cen- sus, Vol. XV. , p. 367. H. B. C. Nitze, Bull. I. , N. C. Geol. Survey, 1893. » W. M. Ctiauvenet, Tenth Census, Vol. XV., p. 383. For other ref- erences to Alabama iron ore deposits, see under Example 6. * Ann. Bep. First Penn. Survey, 1839. 5 M. E., II. 410. ' Second Penn. Survey, Rep. C, p. 136. 94 KEMP'S ORE DEPOSITS. York and Adams counties, Pennsylvania, found the Iiydromica slates filled with the casts of pyrite crystals, and held these to have been the sources of the iron, by affording ferrous sulphate and sulphuric acid. The latter reacted on the alkali of the slates, producing sodium sulphate. This, meeting calcium carbonate, af- forded calcium sulphate and sodium carbonate, which later precipi- tated the iron. Calcium carbonate alone is, however, abundantly able to precipitate iron carbonate and oxide from both ferrous and ferric sulphate solutions (even when natural) without the intro- duction of the alkali, although this might account for the alteration of the slates.^ 2.01.24. J. D. Dana has written at length on the Kew England and New York deposits, and finds them always at or near the junc- tion of a stratum of limestone, proved in many cases to be ferrif- erous, and sometimes entirely siderite, and one of hydromica slate or mica schist. In several mines bodies of unchanged spathic ore are embedded in the limonite. Hence Professor Dana explains the limonite as derived by the weathering of a highly ferruginous limestone, from which the limonite has been left behind by the removal of the more soluble elements, so as practically to replace the limestone in connection with other less soluble matter. The limonite has also at times replaced the schists, probably deriving its substance in part from iron-bearing minerals in them, and changing these rocks to the ochers and clays now found with the ores. These views are undoubtedly very near the truth for the region studied. (Cf. also Example 4.) Weathering limestones do furnish residual clay, ocher, etc., as is shown by the deposits of western Kentucky and Tennessee under Examjale 2. 2.0 .25. Another hypothesis early formulated and advocated by many is that the limonites have been derived by the surface drainage of the old Appalachian highlands and then precipitated in still water where they are now found. A precipitation around the shores of a ferruginous sea has also been urged on the analogy of certain explanations of the Clinton ore. (Example 6.) Their sup- posed Tertiary age has already been remarked. All these views are essentially hypothetical.^ 1 See F. P. Dunnington, "On the Formation of Deposits of Manga- nese," Amer. Jour. Sci., iii., XXXVI., p. 175. (Experiments 10 and 11.) 2 See H. D. Rogers, Trans. Asso. Amer. Qeol. and Nat., 1843, p. 345 ; E. Hitchcock, Geol. Vt., Vol. I., p. 233 ; J. P. Lesley, Iron Man., p. 501 ; Rep. A , Second Penn. Survey, p. 83 ; J. S. Newberry, International Re- view, November and December, 1874. THE IRON SERIES (IN PART). 95 ANALYSES OF LIMONITBS. 2.01.26. All published analyses, except when forming a suflB- ciently large and continuous series from the output of any one mine, are to be taken with caution. Ores necessarily vary much, and a single analysis or a selected set may give a very wrong impression. The percentage in iron is different for different parts of the same ore body. The few that follow have been selected to show the range and the average. The highest are exceptionally good, the lowest less than the average, and the medium values indicate ap- proximately the general run. Limonites afford from 40 to 50% Fe as actually exploited, but it is not difficult to find individual analy- ses that run higher. They are not, generally speaking, Bessemer ores. Analyses of Limonites. „ H,0. Berkshire County, Mass Connecticut Dutchess County, New York Staten Island 39.73 0.05J 0.39114.19 3.59 13.41 Pennsylvania Virg-inia (Low Moor) Tennessee (Lagrange Furnace) Alabama Colorado Colorado, average 43.00 0.080 30. 13. Prosser mine, Oregon Pure mineral 59.93 14.4 Fe. P. S. SiO, Al.Os 47.53 0.187 50.48 0.858 46.45 0.370 14.10 3.05J 39.73 0.05J 0.391 14.19 3.59 56.3 0.135 0.03 5.165 43.34 0.636 50.91 0.337 50.89 0.335 58.37 0.034 0.30 7.90 0.70 43.00 0.080 30. 44.71 0.666 59.93 SIDEEITE, OR SPATHIC ORE. 2.01.27. Siderite is the protocarbonate of iron. As a mineral it often contains more or less calcium, magnesium, and manganese. AVhen of concretionary structure, embedded in shales and contain- ing much clay, the ore is called clay ironstone. When the concre- tions enlarge and coalesce, so as to form beds of limited extent, generally containing much bituminous matter, they are called black-band, and are chiefly developed in connection with coal seams. 2.01.28. Example 3. Clay Ironstone. — The name is applied to isolated masses of concretionary origin (kidneys, balls, etc.) which may at time coalesce to form beds of considerable extent. They are usually distributed through shales, and on the weathering of the matrix are exposed and concentrated. They are especially 96 KEMP'S ORE DEPOSITS. characteristic of Carboniferous strata and differ from black-band only in the absence of bituminous matter and in the consequent drab color. They -weather to limonite, generally in concentric shells with a core of unchanged carbonate within. Fossil leaves or shells often furnish the nucleus for the original concretion, and are thus, as at Mazon Creek, 111., beautifully preserved. When in beds the ore is sometimes called flagstone ore; when broken into rectangular masses by joints, it is called block ore. 2.01.29. Example 3a. Black-hand. — The name is applied to beds consisting chiefly of carbonate of iron with more or less earthy and bituminous matter. They are of varying thickness, though rarely more than six feet, and are almost invariably associated with coal seams. They are thus especially found in the Carbonif- erous system, and to a far less degree in the eastern Jura-Trias. They are also recorded with the Cretaceous coals of the West. It is not possible to separate the two varieties in discussing their dis- tribution. The various productive areas are taken up geograph- ically, beginning with the Appalachian region. 2.01.30. The carbonate ores are of great importance in the Carboniferous of western Pennsylvania and in the adjacent parts of Ohio, West Virginia, and Kentucky. In these States the system is subdivided in connection with the coal, from above downward, as follows : I. The Upper Barren Measures, Permo-Carboniferous, or Dunkard's Creek Series ; II. The Upper Productive Coal Meas- ures, or Monongahela River Series ; III. The Lower Barren Meas- ures, or Elk River Series ; IV. The Lower Productive Coal Measures, or Alleghany River Series ; V. The Great or Pottsville Conglomerate. In the Upper Barren Measures of Pennsylvania, according to McCreath, there is hardly a stratum of shale or sand- stone without clay ironstone nodules, but no continuous beds are known.^ The deposits are not of great actual importance, and are worthy of only passing mention. In the Upper Productive Coal Measures some ore occurs associated with the Waynesburg Coal seam, and again, just under the Pittsburg seam, there is consider- able known as the Pittsburg Iron Ore Group. This latter ore be- comes of great importance in Fayette County and extends through several beds.^ The Lower Barren Measures in Pennsylvania also contain carbonate ore in a number of localities. The most per- 1 Second Penn. Survey, Rep. K, p. 386 ; MM, p. 159. 2 Rep. MM, p. 162 ; KK, p. Ill ; L, p. 98. THE IRON SKllIKH (/.V PATIT.) 07 sistent is the Johnstown ore bed, near the base of the series. There are two additional beds just over the Mahoning sandstone. The Lower Coal Measures are the chief ore producers in all the States. They furnish balls of clay ironstone in very many localities in western Pennsylvania, which will be found recorded with many additional references in Report MM, p. 174, Penn. Geol. Survey. The nodules are scattered through clay and shales. The so-called Ferriferous Limestone, which lies a few feet below the Lower Kit- taning Coal Seam, affords in its upper portion varying thicknesses of carbonate ore, known as " buhrstone ore," which is altered in large part to limonite. Some little carbonate ore was found in the early days in the anthracite measures of eastern Pennsylvania. Several beds of the same occur in the Great Conglomerate and its underlying (Mauch Chunk) shales. They are chiefly developed in southwestern Pennsylvania (Report KK), and may form either entire beds or disseminated nodules. The limonites of the Mar- cellus stage that pass into carbonate in depth in Perry and the neighboring counties have already been mentioned under Example 2. In West Virginia both Upper and Lower Measures afford the ore. From the latter black-band is extensively mined on Davis Creek, near Charleston.' 2.01.31. In Ohio a number of nodular deposits are known, but practically no ore is produced above the Mahoning sandstone of the Lower Coal Measures. Below this sandstone the ores are ex- tensively developed. They extend up and down the eastern part of the State and are both black-band and clay ironstone. Orton identifies twelve different and well-marked horizons distributed through the Lower Measures. He distinguishes the stratified ores mostly black-band, and the concretionary ores, including kidney ores, block ores, and limestone ores.^ 2.01.32. The general distribution of the iron ores of Kentucky has already been outlined under Example 2. The Hanging Rock region is a southern prolongation of the Ohio district of the same geological horizon. P. N. Moore has classified the local ores as limestone ores which are associated with limestone, block ores, and kidney ores. The last two names refer to the fracture or shape of 1 M. F. Maury and W. M. Fontaine, Resources of West Virginia, 1876, p. 247. ^ Oeol. of Ohio, V., p. 378, and supplemental report on the Hanging Rock region in Vol. III. 98 KEMP'S ORE DEPOSITS. the masses. They occur associated with the usual clay and shale. Farther west, between the Kentucky and Red rivers, are the other deposits, the principal one of which comes low in the series, just over the Subcarboniferous limestone.' 2.01.33. Small quantities of black-band have been found in the Deep River coal beds, in North Carolina, associated with the Tri- assic coals.^ A large bed, or series of beds, has recently been reported from Entei'priee, Miss., in strata of the Claiborne stage. They run from ten to eighteen feet in thickness and extend for miles.' Scattered nodules have been noted at Gay Head, Martha's Vineyard.* Car- bonate ores are as yet of no importance in the coal measures of the Mississippi Valley. They have been found associated with the Cretaceous coals of Wyoming and Colorado, — and indeed the first pig iron of the latter State was made from them in' Boulder County, — but they are not an important source of ore.^ An ex- tended bed of very excellent carbonate has recently been discov- ered with coal near Great Falls, in the Sand Coulee region of Montana. Being near coal, limestone, and other iron ores, it prom- ises to be of considerable importance.^ 2.01.34. Example 4. Burden Mines, near Hudson, K Y. Elongated lenticular beds of clay ironstone, passing into sub- crystalline siderite, inclosed conformably between underlying slates, and overlying calcareous sandstone, of the Hudson River stage. The ore occurs in four "basins," which outcrop along the western slope of a series of moderate hills, just east of the Hudson Riv- er. The hills have been shown by Kimball to be the eastern halves of anticlinal folds now reduced by erosion to easterly dip- ping monoclines. The western half of the ore bodies has been eroded away, leaving an outcrop forty-four feet thick as a maxi- mum, which pinches out along the strike and dip. The basins ex- 1 P. N. Moore, "On the Hangdog Rock District ia Kentucky,'' Ken- tucky Geol. Survey, Vol. I., Part 3. « B. WillU, Tenth Census, Vol. XV., p. 306 ; W. C. Kerr, Geology of North Carolina, 1875, p. 225. 5 A. F. Brainard, " Spathic Ore at Enterprise, Miss.," M. E.,XIV. U6. * W. P. Blake, "Notes on the Occurrence of Siderite at Gay Head, Mass.," 31. E., IV. 112. = R. Chauvenet, " Notes on the Iron Resources of Colorado," Ann. Rep. Colo. School of Mines, 1885, 1886 ; Trans. Amer. Inst. Min. Eng.. Colorado meeting, 1889. " O. C. MortsoD, Mineral Resources V. S., 1888, p. 34. THE IRON 8BRIE8 {IN PART.) 99 tend from southwest to northeast, parallel to the trend of the hills. The beds are more or less faulted. The southern part of the second basin affords Bessemer ores, but the others are too high in phos- phorus. At this point the principal mining has been done. Ac- cording to Olmstead, some varieties are richer in phosphorus than others, but they are so intimately mixed as not to be practicably separated. Up to 1889 the mines had produced 450,000 tons of roasted Bessemer ores. ■^QQ KEMP '8 OltE DEPOSITS. 2.01.35. In their geological relations the ores are of the greatest interest, as they occur on the western limit of the metamorphic belt, which forms the basis of the Taconic controversy, yet in strata which have been identified by fossils. Beds of limonite hitherto regarded as Slluro-Cambrian occur to the east ; and should further study, on the lines developed chiefly by J. D. Dana, W. B. Dwight, and C. D. AValcott, clear up their stratigraphical relations, the woi-k done in developing the structure of the siderite basins, as pointed out by Kimball, may be of great aid in explaining them. Very similar bodies of siderite occur with these limonites. (Ex- ample 2a.) The Burden ores are relatively high in magnesia, and this leads Kimball to suggest their original deposition from the ofE-shore drainage of the basic rocks of the Archean highlands. Further, it may be added that the ores in their lenticular shape are highly suggestive of a possible origin for magnetite de- posits, and they are again referred to under " Magnetite." Other deposits of siderite in the shales of the Marcellus stage are known and were formerly worked at Wawarsing, Ulster County, across the Hudson River.^ 2.01.36. Examples. Eoxbnry, Conn. A fissure vein in gneiss, six to eight feet wide, of crystalline siderite, with which are as- sociated quartz and a variety of metallic sulphides, galena, chal- copyrite, zincblende, etc. Although productive in former years, it is no longer worked, and is of scientific more than economic inter- est, being a unique deposit. It has furnished many fine cabinet specimens.^ 2.01.37. The spathic ores are the lowest in iron of all, and in the raw state are often, if not always, far below the limit of profita- ble treatment. Calcination, however, drives ofE the carbonic acid and moisture and brings the percentage of iron up to a merchant- able grade. The later development of the iron industry in this country has been unfavorable to spathic ores, and year by year their amount has decreased until now it is nearly obliterated, being about one per cent, of the total. 1 J. P. Kimball, " Siderite Basins of the Hudson River Epoch," 4mer. Jour. Sai., III., xl. 155. I. Olmstead, " Distribution of Phosphoius in the Hudson River Carbonate," M. E., 1889. R. W. Raymond, "The Spathic Ores of the Hudson River," 31. E., IV. 309. J. C. Smock, Bulletin of New York State Muxeum on Iron Ores, p. 62. = J. P. Lesley, Iron Manufacturers' Guide, p. 649. C. U. Shepherd, " Report on the Geology of ConDecticut," 1837, p. 30, Amer. Jour. Sei., I,, xix. 811. THE IRON SEJiTES (IN PART.) 101 3.01.38. The subjects of limonibe ami siderite cannot well be passed without further reference to their genetic relations as con- nected with limestone. Tiie processes involved concern not alone these ores, but also the more metamorphic forms — hematite and magnetite — into which they may pass by reason of subsequent changes. It was stated earlier (3.01.05) that calcium carbonate precipitated from ferric salts, ferric hydrate, and from ferrous salts, ferrous carbonate, which in the presence of oxygen quickly changed to ferric hydrate. J. P. Kimball ^ has recently added a note on the chemistry of the process which modifies it somewhat. He brings out tlie fact that it is the hydrous carbonate of iron which is precipitated from ferruginous salts by the various alkaline car- bonates, and that, being an unstable salt, it quickly oxidizes to a hydrous oxide. From this the argument is made that bodies of siderite, or anhydrous ferrous carbonate, could not have originated by direct precipitation, but must have done so by pseudomorphous replacement of limestone. Dr. Kimball then follows out the pos- sible metamorphism or changes of these bodies to other forms of iron ore, citing, however, among many that are unexceptionable, some instances as possible examples for which the field relations give but slight justification. The specular ores with tlie porphyries of Missouri are of this latter cliaracter, and the work of C. H. Smyth, Jr., later cited, on the oolitic Clinton hematites gives strong ground for thinking them accumulations in shallow waters as con- centric layers upon original nuclei of quartz. 3.01.39. While the importance of limestone as a cause of the formation of bodies of iron ore cannot be too highly emphasized, and it is quite possible that some puzzling ones, such as many magnetite beds, have originated in this way and that the limestone has so entirely disappeared as to give slight clue to its original presence; yet it must not be overlooked that siderite often does form in nature quite independently of calcite, and that conditions must be often such as to make this possible. If vuggs with free crystals, or if cleavage masses with the proper angle occur ill a deposit, we must admit that the siderite is produced under circumstances not different from those which prevailed during the formation of the walls or of the massive mineral. Repeated ex- perience indicates that tiiese are not extraordinary. ' J. P. Kimball , ' ' Genesis of Iron Ores by Isomorphous and Pseu- domorphous Replacement of Limestone," Amer. Jour. 8ui., Sept., 1891. p. 231, and conclusion in the Amer. Geol , Dec, 1891. CHAPTER IL THE IRON SERIES CONTINUED.— HEMATITE, BED AND SPECULAR. 2.02.01. The sesquioxide of iron, F2O3, is always of a red color when in powder. If it is of earthy texture, this color shows in the mass, and the ore is called red hematite ; if the ore is ■crystallized, the red color is not apparent, and the brilliant luster of the mineral gives it the name specular hematite. The red hematites are first treated. 2.02.02. Example 6. Clinton Ore. — Wherever the Clinton ■ stage of the Upper Silurian outcrops, it almost invariably contains one or more beds of red hematite, interstratified with the shales and limestones. These ores are of extraordinary persistence, as ■they outcrop in Wisconsin, Ohio, and Kentucky in the interior, and then beginning in New York, south of Lake Ontario, they run easterly across the State. Again in Pennsylvania they follow the waves of the Appalachian folds, and extend south into West Virginia and Virginia in great strength. They are found in east- ern Tennessee and northwestern Georgia, and finally in Alabama are of exceptional size and importance. The structure of the ore varies somewhat. At times it is a replacement of fossils, such as crinoid stems, molluscan remains, etc. (fossil ore) ; again as small oolitic concretions, like flaxseed (flaxseed ore, oolitic ore, lenticular ore) ; while elsewhere it is known as dyestone ore. The ore in many places is really a highly ferruginous limestone, and below the water level in the unaltered portion it often passes into limestone, while along the outcrop it is quite rich. 2.02.03. In Dodge County, southeastern AVisconsin, the ore is 14 to 26 feet thick and consists of an aggregate of small len- ticular grains.^ In Ohio it outcrops in Clinton, Highland, and 1 T. C. Cbamberlin, Geol. Survey Wis., Vol. I., p. 179. R. D. Irving, " Mineral Resources of Wisconsin," M. E., VIII. 478; Oeol. Survey Wis., Vol. I., p. 62^5, THE IRON SERIES CONTINUED. 103 Adams counties, in the southwestern portion of the State along the flanks of the Cincinnati Arch, but it is thin and poor in iron, al- though rich in fossils.' A small area of the Clinton has furnished considerable ore in Bath County, Kentucky, where it is altered to limonite.'' 2.02.04. Coming eastward, the limestones and the shales of the Clinton outcrop in the Niagara River gorge in New York, but show no ore. This appears first in quantity in "Wayne County, a hundred miles east and just south of Lake Ontario. One bed reaches 20 to 22 inches. Farther east are the Sterling mines, in Cayuga County ; and again near Utica, in the town of Clinton, which first gave the ore its name, it is of great economic importance. There are two Fig. 13. — Clinton Ore, Ontario, Wayne County, New York. After C. H. Smyth, Jr. workable beds, the upper of which, with a thickness of about two feet, is the only one now exploited. Beneath this are 12 or 15 inches of shale, and then the second bed of 8 inches of ore.' Some 25 feet over the upper bed is still a third, which is too low grade for mining. It is four to six feet thick, and is locally called red flux. It consists of pebbles and irregular fragments of fossils, which are coated with hematite and cemented with calcite. 2.02.05. The rooks of the Clinton thicken greatly in Pennsyl- vania and run southwestwai'd through the central part of the State. 1 J. S. Newberry, Geol. of Ohio, Vol. III., p. 7. E. Orton, Geol. of Ohio, Vol. v., p. 371. 2 N. S. Shaler, Geol. of Ky., Vo\ III., 163. ° A. H. Cliestt^r, "The Iron Rpg-lon of Ceotral New York;" address before the Utica Merchants and Munufacturt'is' Association, Utica, 1881. J. C. Smock, Bull, of N. Y. State Museum. C. H. Smyth, Jr., "On the Clinton Iron Ore," Amer. Jour. Sci., June, 1893, p. 487. 104 KEMP'S ORE DEPOSITS. Six different ore beds have been recognized, of which the lower are probably equivalent to the southern dyestone ores.^ The ores are of chief importance in the Juniata district. The belt extends southwestward across Maryland and eastern West Virginia, where the beds are quite thick, although as yet not much developed, and appears in the extreme southwest comer of Virginia. Thence it runs across eastern Tennessee, and is of very great im- ■<,;.|-..-.;.~ ^■G^.^ - 1 ' ' " ' *~( •ij --1 ~-'~T T"' , ■ ?^ -. ...- ^ . — ^ r?iE .' • ' •- = — Calcareous Sandstone and f thin Shale layers T'O- Non-Oolitic Ore / (Red Flux) 6 Calcareous r Sandstone 6 Blue Shale and thin , Sandstone layers 15' Oolitic Ore 2 Shale 2' , Oolitic Ore 1 _ Blue Shale — I and thi.n , Sandstone layers TOO i Fig. li.— Clinton Ore, Clinton, New York, After C. H. Smyth, Jr. portance. The lines of outcrop are known as "dyestone ranges." Tbey lie west of the Siluro-Cambrian limestones (Example 2a) and in the edges of the Cumberland tableland. Four or five are known, of which the largest extends across the State. This ore is 1 J. H. Dewees, "Fossil Ores of the Juniata Valley," Penn. Geol. Survey, Rep. F. E. d'Invilliers, Ibid., Eep. F3 (Union, Snyder, Mifflin, and Juniata counties). A. S. McCreath, Ibid., Rep. MM, p. 231. J. J. Stevenson, Ibid., Reps. MM and T3 (Bedford and Fulton counties). I. C. White, Ibid., Reps. MM and T3 (Huntington Counts'). H. H. Stoek, "Ores at Danville, Montour County," M. E., October, 1891. THE IRON SERIES CONTINUED. 105 more fossiliferous toward the south and more oolitic toward the north. It is very productive in the Chattanooga region.' 2.02.06. The Clinton just appears in northwestern Georgia, and continues thence into Alabama, where it is again of great importance, Flc. 15. — Clinton Ore, Eureka Mine, Oxmoor, Ala. After C. H. Smyth, Jr. and, with the less productive Siluro-Cambrian limonites, furnishes practically all the ore of the State. The outcrop can be traced almost continuously for 130 miles. The ore is rich in fossils and occurs in several beds, which, although averaging much less, may Fig. 16. — Cross section of the Sloss Mine, Red Mountain, Ala. aggregate, as at the Eureka furnace, as much as 34 to 37 feet. The chief mines are in Red Mountain, a northeast and southwest ridge, east and south of Birmingham. Folds and faults have brought the beds into close proximity with the coal and limestone of the region, and thus into a position very favorable for economic working.' 1 Killebrew and Safford, Resources of Tennessee. E. C. Pecliin, "The Iron Ores of Virginia," etc., M. E., XIX. 1016. ,1. B. Porter, " Iron Ores, Coal, etc., in Alabama, Georgia, and Tennessee," M. E., XV. 170. J. M. Safford, 6leol. of Tenn. P. N. Moore, Virginias, May, 1880, p. 78. 2 A. F. Brainerd, ' ' On the ' Iron Ores, Fuels, etc. , of Birmingham, Fig. 17. — Maj> of the Vicinity of Birmingham, Ala. From the Transac- tions of the American Institute of Mining Engineers, Vol. XIX., " Plate IV. THE IRON SEItlKS, CONTINUED. 107 The accompanying map, Fig. 17, illustrates tlie geography and ecoiioniic geology of the Birmingham district. In explanation it may be said, that the three coal fields, the Warrior, the Cahaba^ and the Coosa, make three elevated basins formed in part by synclinal foldings and in f)art by faulting. The intervening strips are relatively depressed and constitute the so-called valleys, each of which has its own name. Thus there is a long valley in which Birmingham is situated and which forks at the northeast corner of the map. The central portion of it consists of Cambrian and Lower Silurian rocks, Avhich yield brown hematite ores, as indicated on the map. They, liowever, are a minor feature and do not form over 10 per cent, of the total furnace supply. On each side of the valley there is a ridge called Eed Mountain, mostly formed by Clinton strata, with Trenton limestone beneath and black Devonian shale above. The Clinton reaches a thickness of 150 feet, but is quite variable in character. It may contain as many as five or more beds of ore of differing thickness and somewhat contrasted composition and structure. The best of these are worked. The Clinton beds in Eed Mountain dip on each side away from the centre of the valley, and really are the remains of an anticline eroded at its crest. The anticline is of the usual Appalachian type with steeper dips on one flank (in this case the northwestern) than on the other, and the crest is nearer the northwest side than the northeast. The dip at one important mine is shown in Fig. 15. The most productive points are east and south of Birming- ham, and along this line the largest mines are situated. The ore is chiefly won by open cuts, and is laid bare by stripping off the hanging. Curiously enough, for an ore in the midst of limestone and limey shales, it is prevailingly silicious, so that non-silicious or calcareous varieties are much sought for mixtures. The red hema- tites are also exposed in Murphrees Valley and are developed in some large and productive openings. While on the west this valley has the normal anticlinal flank, it is faulted along the east so that the Clinton measures lie against the Cambrian shales and are over- thrown to a steep northwesterly dip. Ala.," Jtf. ^., XVII. 151. "The Sloss Iron Ore Mines," Engineering and Mining Journal, Oct. 1, 1893, p. 318. T. S. Hunt, "Coal and Iron in Alabama," M. E.,X1. 236. J. B. Porter, "Iron Ores, Coal, etc., in Alabama, Georgia, and Tennessee," M. E., XV. 170. E. A. Smith, Alabama Geol. Survey, 1876 ; also A. A. A. S., XXVII, 346. 1 A detailed description of the Cahaba field, with a large geological 108 THE IRON SERIES, CONTINUED. 2.02.07. Red hematite, supposed to be of the Clinton stage, oc- curs in Nova Scotia in very considerable amount, in Pictou and Antigonish counties.* 2.02.08. In general the Clinton ore is characterized by a high percentage of phosphorus, and is seldom, if ever, available for Bes- semer pig. It is chiefljr employed for ordinary foundry irons. The percentage in iron varies much. Experience at Clinton, N. Y., shows that it averages about 44^ Fe in the furnace. These hema- tites have undoubtedly originated in some cases by the weathering of ferruginous limestones above the water level. I. C. Russell has shown that the unaltered limestones at the bottom of a mine in Atalla, Ala., 250 feet from the surface, contained but 7.75^ Fe, while the outcrop afforded 57.52^. J. B. Porter has recorded the gradual increase of lime also in another Alabama mine, from a trace at the outcrop to 30.55^ at 135 feet. Other writers have ex- plained these beds as due to the bringing of iron in solution into the sea of the Clinton age and to its deposition as small nodules, etc., or as ferruginous mud. (Roger, Lesley, Newberry.) In this way an oolitic mass has originated, as in the modern Swedish lakes (Newberry). (See Example 1.) N. S. Shaler has argued, on the basis of the Kentucky beds, that the iron has been derived from the overlying shales, and descending in solution has been precipi- tated by the lower lying limestones. As the shales are themselves calcareous, this seems improbable. A. F. Foerste has shown that the ore is very often deposited either in the interstices of frag- ments of bryozoans or as replacing their substance. The rounded, water-worn character of the original fragments is regarded as oc- casioning the apparent concretionary character. Admirable work upon the origin of the ore has also been done by C. IT. Smyth, Jr. He finds that the small oolites, or concretions, as they occur at Clinton, N. Y., and many other localities, have a water-worn grain of quartz as a nucleus. The character of the grain is such that it has evidently been derived from granitoid or schistose rocks. The hematite comes off at times in concentric layers, when map of it and the Birmingham valley was issued in 1890 by the Ala. Qeol. Survey, entitled " Report on the Cahaha Coal-Field by Joseph Squire. " A. M. Gibson, ' ' Report on the Geological Structure of Mur- phrees Valley, " Ala. Geol. Survey, 1893. 1 Sir J. W. Dawson, Acadian Geology, p. 591. Fletcher, Can. Geol. Survey, 1886. KEMPS ORE DEPOSITS. 109 tapped gently. It la^y also be dissolved away bo as to leave a siliceous cast or skeleton of the spherule. Dr. Smyth thus makes a strong argument that the ores in such cases are concretionary, and that they were formed in shallow waters around the nuclei of sand. But he also admits, as others quoted above have indicated, that the replacement of bryozoa and the weathering of ferruginous lime- stone have in many localities played their part. The iron ore is in the latter case a residual product, but now the mine waters are de- positing calcium carbonate rather than removing it.^ 2.02.09. Glenmore Estate, Greenbrier County,West Virginia. A bed of red hematite in Oriskany sandstones. Limonites are abundant in the Orisk.any of Virginia, and the hematite may have been de- rived from such ^ or vice versa. 2.02.10. Mansfield Ores, Tioga County, Pennsylvania. Three beds of ore are found in the strata of the Chemung stage of Tioga County, Pennsylvania. They are known as the (1) Upper or Spi- rifer Bed, (2) the Middle or Fish Bed, and (3) the Lower Ore Bed. No. 1 is full of shells and is about 200 feet below the Catskill red sandstones, and at Mansfield is two to three feet thick. No. 2 is oolitic, resembles the Clinton ore, and affords fish remains. It lies about 200 feet below No. 1 and varies up to six or seven feet thick. No. 3 is 100 to 200 feet lower, and contains small quartz pebbles.' The ore is not rich, and but little has been mined. It is a brown- ish red hematite.' 2.02.11. Beds of red hematite are reported by Schmidt in the Lower Carboniferous of western central Missouri.* 1 A. F. Foerste, "Clinton Group Fossils, with Speciul Reference to Collections from Indiana, Tennessee, and Georgia," Amer. Jour. Sci., iii., XL. 252. (Abstract; original not cited.) " Clinton Oolilio I onOres," ^mer. Jour. Sci, iii.,XLI.28. Rec. " Notes on Clinton Group Fossils, with Spe- cial Reference to Collections from Maryland, Tennessee, and Georgia, "Proc. Bast. Soc. Nat. Hist., XXIV. 263. J. P. Lesley, Iron Manufacturers' Guide, p. 611. J. S. Ne wberr^', "Genesis of the Ores cf Iron ," School of Mines Quarterly, November, 1880, p. 18. Rec. H. D. Rogers, Geol. of Penn., Vol. n., p. 127. N. S. Shaler, Geol. ofKy.,Yo\. III., p. 163, C. H. Smyth, Jr., " On the Clinton Iron Ore,'' Amer. Jour. Sci., June, 1892. p. 487. Rec. 2 W. N. Page, "The Glenmore Iron Estate, Greenbrier County, West Virginia," M. E., XVII. 115. * A. S. McCreath, Rep. MM, Second Penn. Survey, p. 831. * J. P. Lesley, Geol.of Penn., 1888, Vol. I., p. 811. A. Sherwood, Rep. G, Second Penn. Survey, pp. 83, 87, 41, 42, 67. A. S. McCreath, Rep. MM, Second Penn. Survey, p. 351. "> A. Schmidt, " Iron Ores and Coal Fields," Missouri Geol. Survey, 1873, p. 169. P. L, Nason. ' ' Iron Ores of Missouri, ' ' Idem, pp. 70-83. 110 KEMP'S OIIE DEPOSITS. 2.02.12. Example 7. Crawford County, Missouri. Bodies of finely ei-ystalliue specular hematite, associated with chert, sand- stone fi'agments, residual clays and some pyiite, in couical or rudely cylindrical depressions in the Cambrian (Ozark) Series. A broad area of upheaval runs across central Missouri from the east, near St. Louis, to the southwestern part of the State. lu theeastern and central portions it is chiefly composed of Cambrian and Silurian strata, but to the southwest Lower Carboniferous come in (see 2.0C.06). The hematites here consiiiered belong in the Cambrian. Li the region of the mines there is a heavy sandstone stratum, earlier called the " Second Sandstone," but in the later i-eports de- scribed as the Roubidoux. It is underlaid by a heavy limestone stratum locally called the Gasconade. The Ozark uplift was foi'med at the close of the L-ower Carboniferous and has remained exposed to atmospheric agencies ever since. Their effects are --a V .. -:'^f.,'»ZA.-. ...,i-7-..-r:S^.^: Fig 1^ — ] II 11 Hi ( Ii III/ T ill ii l/m \li n nuj sinii/ide)- li/niij ihiiti/ iluij Ihf ■^lUKhtoUL dijii wut/iea^t iiniaid tmvaril the ore. After F. L. Na.mn, Kept, on Iron Oi-e.'iofJIis.iuuri, p. 125. Plate YI. shown in the great mantles of residual clay, which are widely dis- tributed, and m the phenomena of the hematite deposits. Dr. A. Schmidt of the Missouri Survey of 1872 (Ueport on "L'on Ores," p. (16) thought that these had replacetl pre-existing rock, or had been deposited in hollows in the then existing surface. Pumpelly, however, in 1885 {Tenth Census, Vol. XV., p. 12) advanced a more probable hypothesis, which is strongly supported by F. L. Xason. The region is and has long been one of sink-holes caused by sub- THE IRON SERIES, CONTINUED. Ill terranean drainage through the Gasconade limestone and the cav- ing in, at times, of the overlying sandstone. Cavities were thus afforded in which ferruginous waters might stand and precipitate their dissolved burden of ore. Nason shows that several of the larg- est mines are along lines of old drainage valleys. The edges or walls of the pits are formed by the sandstone which dips inward, as shown in the accompanying figures. Just how much overlying Fig. 19. — Section of the northern end of the Cherry Valley Mine. 1, Clay detritus; 2, Sandstone; 3, Cherty and slaty clay; 4, Ore; 5, Blocks of sandstone. After F. L. Nason, Re- port on Iron Ores of Missouri, p. 131. Fig. 30. — Cross section of the Cherry Valley Mine. 1, Sandstone; 2, Clay and chert; 8, Sandstone dipping inward; 4, Magnesian limestone. After F. L. Nason, Report on the Iron Ores of Missouri, p. 134. rock has washed away does not appear with all desirable certainty, but the presence of large amounts of chert mixed with the ore in- dicates that the cap must have been to a great extent limestone with interbedded layers of this rock. As Nason states ("Iron Ores of Missouri," p. 138) the limestone that fell into the cavities has been replaced witli ore. It is very probable that the former was an important precipitating agent to the latter. A fossil crinoid was found at Cherry Valley, replaced by hematite, giving evidence that even Lower Carboniferous strata had been present. The leaching of these old, overlying beds and the superficial drainage seem to indicate the method of derivation of the ore. The most productive counties are Crawford, Phelps and Dent, ] 13 KEMP 'S OR E DEPOSITS. but smaller deposits occur in several others. The largest mines are the Cherry Valley, with a total product of over half a million tons, the Simmons Mountain, which has yielded about half as much and the Meramec with three hundred and seventy-five thou- sand. The total product of all the mines is computed by Nason at about two and one-quarter millions of tons. A sample from a stockpile made up at St. Louis furnaces from several mines, yielded Fe 56.43, P. 0.065 (Nason, I.e. p. 157) but many are much lower in iron. In former years 100,000 to 200,000 tons were an- nually produced; recently, however, much less. Some anomalous features are presented by these ores in that they are specular hematite in a practically unmetamorphosed sandstone, whereas some less crystalline form would naturally be expected. Nason be- lieves that they were originally sulphides and that the heat generated by the decomposition of this mineral has afEected the change to specular.^ 3.02.13. Example 8. Jefferson County, New York. Large but irregular bodies of red hematite associated with crystalline limestone, serpentine, and pyritous gneiss and overlain by Pots- dam sandstone. The crystalline limestone is certainly pre-Cam- brian, and would be called Algonkian in the later use of this term, and later Laurentian in the earlier nomenclature.^ In a forthcom- ing report to James Hall, State Geologist, C. H. Smyth, Jr., has named the limestone series the Oswegatchie. The ore bodies occur along a northeast belt, from Philadelphia, Jefferson County, to Gouverneur, St. Lawrence County. They range up to 30 or 40 feet in thickness and consists of red, earthy hematite in porous or cellular masses, with some specular. Many interesting minei-als, including siderite, millerite, chalcodite, quartz, etc., are found in cavities. The alignment of the mines along a marked belt has given some ground for thinking them interbedded deposits, and their association with Potsdam sandstone has created the impres- 1 "W. M. Chauvenet, Tenth Census, Vol. XV., 1885, p. 403. F. L. Nason, " Report on Iron Ores," pp. 119-156, 218-331. Missouri Geol. Survey, 1893. Rec. R. PumpeUy "On Origin," Tenth Census, Vol. XVI. , p. 13. Rec. A. Schmidt, ' 'Iron Ores and Coal Fields, ' ' Missouri Geol. Survey, 1872, p. 124. 2 C. H. Smyth, Jr. , " Geological Reconnaissance in the Vicinity of Grouverneur, N. Y.," Trans. N. Y. Acad. ScL, XII. 97, 1893. THE IRON 8EB1E8, CONTINUED. 113 sion that they are of Cambrian (or, as it was then called, Lower Silurian) age.' J. P. Kimball has stated that they are replace- ments of Calciferous limestone.' E. Emmons in the "Eeport on the Second District in the early New York Survey," regarded the associated crystalline limestone as an intruded igneous mass, and the same method of origin was applied to the ores and accompany- ing serpentine. The latter was called Rensselaerite by Emmons. Brooks gave the following section, taken at the Caledonia Mine: 1. Potsdam sandstone, 40 feet. 2. Hematites, 40 feet. 3. Soft, schistose, slaty, green, magnesian rock with pyrite and graphite, 90 feet plus. 4. Granular, crystalline limestone, with phlogopite and graphite. 5. Sandstone (like 1), 15 feet. 6. Crystalline lime- stone with beds and veins of granite. 0. H. Smyth, Jr., has re- corded the stratigraphical observations, cited earlier, and has form- ulated the following explanation of origin. Tiie lineal arrange- ment of the ore-bodies is referred to their association with a great stratum of pyritous gneiss belonging to the Oswegatchie Series. This weathers deeply and becomes light and porous (constituting thus a "fahlband.") It contains considerable disseminated magnetite. The so-called serpentine or rensselaerite only occurs iu association with ore and itself v_ries in chariicter, so that one is justified in regarding it as an ttltered form of several different kinds of rocks. Smyth infers that the decay of the ferruginous minerals, but especially of pyrite in the pyritous gneiss, has fur- nished the iron-bearing sdlutions, which following down the dip have replaced the crystalline limestone where the presence of in- tended granites or the flattening of the dip checked the circula- tions. The action of the acidulated ferruginous waters has altered the granites and gneisses in the limestone series to the so-called serpentine.' These views are fortified by microscopic study of the rocks, 1 See T. B. Brooks, Amer. Jour. Sci. iii. , TV. 23. 2 J. P. Kimball, Amer. Geologist, Dec. , 1891, p. 368. 3 T. B. Brooks ' ' On Certain Lower Silurian Rocks in St. Lawrence Co., New York," Amer. Jour. Sci., iii., IV., p. 23. Rec. G. S. Colby, Jour. U. S. Assoc. Charcoal IronWorhers, XL, p. 268. E. Emmons, N. Y. Geol. Survey, Second District, p. 93. T. S. Hunt, ' ' Mineralogy of the Laurentian Limestones of North America, ' ' ^Ist Ann. Rep. Regents N. Y. State Univ., 1871, p. 88. J. C. Smock, Bull. N. Y. State Mus., No. 7, 1889, p. 44. Reo. C. H. Smyth, Jr., "Forthcoming Report of James Hall, ' ' State Gteologist, submitted March, 1894. Reo. 114 KEMP '8 ORE DEPOSITS. and though advanced only as an hypothesis are worthy of great confidence. The mines have afforded in the past a moderately rich (50 to 55^ Fe), non-Bessemer ore. The best known and largest producers are the Old Sterling, the Caledonia and Kearney properties, but they are not now operated and are not likely to be reopened in the im- mediate future. 2.02.14. Ji,xample 9. Lake Superior Hematites. Bodies of hematite, both red and specular, soft and hard, in metamorphic rocks. They vary widely in shape, although at times quite per- fectly lenticular. They are usually associated with jasper and chert, and have for a footwall a relatively impervious rock of some sort. Magnetite is at times present. Although of varying physical structure and associations, all the Lake Superior hematites are here grouped under one general example, in order to avoid unnecessary subdivisons, and to emphasize their related characters. There are live principal ore-producing belts or districts, which are also called in instances "ranges," as they follow ranges of low hills. They are, in the order of their chronological exploitation, the Marquette, just south of Lake Superior, in Michigan ; the Menominee, on the southern border of the Upper Peninsula and partly in Wisconsin ; the Gogebic or Penokee-Gogebic, on the northwestern border be- tween Michigan and "Wisconsin ; the Vermilion Lake, in Minnesota, northwest of Lake Superior ; and the Jlesabi (Mesaba), in the same general region as the last. 2.02.15. The geology of these districts has been a subject of much controversy, not alone in the relations of the separate areas, but in the subdivisions of a single one. The ever-present difficulty of classifying and correlating metamorphic rocks has here been very great. Moreover, there are other separate districts, of re- lated geological structure, which ought also to be brought into harmony, and only at a very recent date has this been even par- tially attained. 2.02.16. The ores and their inclosing rooks have usually been called Huronian, as this is the name formerly applied to the 1 T. B. Brooks, "On Certain Lower Silurian Rocks in St. Lawrence County, New York," Amer. Jour. Sci., iii. IV., p. 32. G. S. Colbj', Jour. U. S. Asao. Charcoal Iron Workers, Vol. XI., p. 263. E. Emmons, N. Y. Oeol. Survey, Second District, p. 93. T. S. Hunt, "Mineralogy of the Lanrentian Limestones of North America," 2T.st Ann. Report Regents of N. Y. State Univ., 1871, p. 88. J. C. Smock, Bulletin of N. Y. State Museum. TEE IRON SERIES, CONTINUED. 115 schistose and metamorphic rocks overlying what was conceived to be the basal, gneissic Laurentian. The later and more careful work has essentially modified such grouping. The reorganization has been chiefly brought about by K. D. Irving, C. E. Van Hise, Alexander Winchell, M. E. Wadsworth, and the Canadian geolo- gists, especially A. C. Lawson, who has worked in the Rainy Lake region. The definite introduction of Iluronian in the classification is especially due to Logan (ISST). Previously Foster and "Whitney had merely called all the metamorphic rocks concerned with the iron ores in the Lake Superior regions "Azoic." T. B. Brooks in the Marquette district distinguished twenty members (ISVS), but, as Major Brooks frankly states, the classification was chiefly in- tended to aid explorations for ores. Rominger made the classi- fication much simpler (1884), and many others have since written on the subject.' 2.02.17. As now viewed, the Laurentian is regarded as con- sisting of granites and gneisses and a higher series of gneisses and schists. They are grouped under the name of " Fundamental Com- plex" by Irving and Van Hise (Cascade Formation of Wads- worth, 1892), but the upper series is called Coutchiching in the Rainy Lake Region by Lawson. The unconformity is an eruptive one. Above these, after an unconformity not always clearly marked, comes the succession of schistose rocks, which are grouped together under the name Algonkian. They consist of a lower series, called by various names in the different regions, but which in the Marquette, Menominee, and Vermilion Lake districts contains some of the most important mines. It is variously denominated Lower Huronian, Lower Marquette, Keewatin, Lower Vermilion, and Menominee proper in the different exposures, and probably the great cherty limestone of the Penokee-Gogebio series is its local equivalent. In the Marquette district "Wadsworth has re- cently divided it still further into the Republic and Mesnard forma- tions. The upper part follows an unconformity and is called in the different regions Upper Huronian, Animikie, Upper Vermilion, Up- per Marquette, "Western Menominee, and Penokee-Gogebic proper. 1 See Hr. E. Wadsworth, Notes on the Oeology of the Iron and Copper Districts, 1880; N. H. Winchell, "A Last "Word wuh the Huronian," Oeol. Sac. Amer., "Vol. II., p. 85 ; C. R. "Van Hise, "An Attempt to Har- monize some apparently conflicting Views ot Lake Superior Strati- graphy." Amer. Jour. Sci., ii., XLI. 117 ; and Tenth Ann. Rep. Director U. 8. Oeol. Survey. The papers give many references. 116 KEMP'S ORE DEPOSITS, For the Marquette region this nas also oeen further divided hy "Wadsworth into two, the Hoiyoke and the Negaunee formations. It is much less metamorpnosed than the lower member, and in the Marquette district contains some ore. In the Menominee region of Wisconsin it affords the deposits there -wrought and carries the ore in tne Gogebic range. Still higher, after another unconformity foiio-ws the Keweenawan (Keweenian) or Nipigon. This closes tne Aigonkian. Still above is the Potsdam sandstone. 2.02.18. Example 9a. Marquette District. The Marquette district was earliest known and has been most thoroughly studied ; out owing to the confused geological structure, there has been, as already remarked, much discordance of interpretation. In the Mar- quette district the Huronian Algonkian rocks form a broad syn- clinal trough with many subordinate folds and several tongues or projections running out from the main body. They rest on and are bounded by Laurentian gneiss. They consist of green schists, ■quartzites, banded jaspers, slates, ore bodies, and dikes altered to ■" soapstone " or " soaprock." Brooks divided them into twenty members, of -which Beds YL, X., XIII., and a horizon below V. afford the ore. Bed XIII. contains the magnetite, -which increases in amount to-^vard tlie -western portion of the iield. Rominger in Vol. IV. of the Jlinhi j:iii S-iroey, 1884, reduced the number to seven. Irving and Vtin llise have contributed much in late years toward a solution of the gsology. Irving regarded the series as separable into a lower division of greenstone schists and more acidic rocks, both of which are dynamically metamorphosed erup- tive rocks, and an unconformable, overl3dng, iron-bearing division of sedimentary origin. (See papers cited below.) Van Hise, how- ever, in his latest paper places a break above the most important ore bodies. 3.02.19. The ores were classed by Brooks under five heads — {ii) Ked specular, (h) Magnetic, (c) Mixed, (d) Soft Hematites, au lion Ore of the Marquette District,'' Amer. Jour. Sci., ii., XXXIX. 290. B..S.M\Jinroe, Schoolof Mines Quarterly, III., p. 43. E. Reyer, "Geologie der Amerikanischon Eisenerzlagerstatten (insbeFondere Michigan)," Oest. Zeit. f. Berg.- u. Hiltt., Vol. XXXV., pp. 120, 131, 1887. C. Rominger, Geol. Survey of Michigan, Vol. IV., 1884. C. R. Van Hise, " An Attempt to Harmonize Some Apparently Conflicting Views of Lake Superior Stratigraphy," Amer. Jour. Set., iii., XLL, p. 117, February, 1891; Tenth jinn. Rep. Director U. S. Geol. Survey ; " The Iron Ores of the Marquette Dis'rict of Michigan,'' Amer. Jour. Sci., February, 1892, p. 115. M. E. "Wadsworth, "Notes on the Inn and C >pper Districts of Lake Superior," Bull. Mus. Comp. Zool., VII. 1, 1880 ; "On the Ori :in of the Iron Ores of the Marquette Distrkt, Lake Superior," Proc. Dust. Soc. Na,t. Hist., Vol. XX., p. 470 ; Enginrering and Mining Journal, Oct. 29, 1881, p. 286 ; Ann. Rep. Mich. State Geologist, 1891-93. "The Geology of the Lake Superior Ri'g-ion," in a parr phlet issued by the Duluth, South Shore and Atlantic R. R., 1892. Dr. Wadsworth announces a new subdi- vision of Formations in this and in AnLer. Jour. Sci., J.inuary, 1893, p. 73. n. 'Wedding. Zeitsch. f. Berg.-, IliVt -, und Salincnwcscn in Preus. Staat., XXIV., p. 339. C. E. Wright and C. D. Lawton, Reps, of the Commis- sioners of Mineral Statistics of Michigan, 1880, and annually to date. G. H. Williams, " Greenstone Schist Areas < f the Menominee and Mar- quet'e Regions of Michigan," introduction by R. D. Irving, Bull. 63, ?7. S. Geol. Survey. 123 KF.MFS ORE DEPOSITS. planes of deposition in (2) and not far from the contact with (1), while minor bodies have been found in the Potsdam, which seem to have resulted by the erosion of the older lenses in the Potsdam times. (See paper by J. Fulton, cited below.) Especially instruc- tive exposures of green schists are found which have furnished some of the best evidence that they are metamorphosed, igneous, in- trusive rocks. The ores are generally soft, blue, earthy hematites, which give a red powder and consist of very finely divided parti- cles of specular. The brown hematites are of very limited occur- rence, being known only in the Emmet mine. The lenticular shape of the ore bodies is better shown than in the Marquette district, and even the large masses clearly exhibit this cross section. They strike about N. 75° W., and dip 70° to 80° N. They also pitch to the FiQ. 19. — Plan of Ludington ore tody, Menominee district, Michigan, After P. Larsson, M. E., July, 1887. west; i.e., run down diagonally on the dip. (Cf. New Jersey Mag- netite, Example \Zd). There were produced up to 1891 a grand total of 12,800,000 tons since mining began.^ 2.02.24. Example 9c. Penokee-Gogebic District. This lies in an east and west range of hills, which crosses the westerly boun- dary of the Upper Peninsula and Wisconsin, and is from ten to twenty miles south of Lake Superior, and eighty to one hundred 1 T. B. Brooks, Geol. Survey of Wisconsin, Vol. III., 430-663. D. H. Browo, "Distribution of Phosphorus In the Ludington Mine," M. E., XVI. 525. J. Fulton, "Mode of Depositioa of the Iron Ores of the Me- nominee Range, Michigan," M. E., XVI. 535. Per. Lirsson, "The Chapin Mine," M. E., XVI. 119. C. E. Wright, Geol. Survey cf Wiscon- sin, III. 666, 784. G. H. Williams, "Greenstone-Schist Areas of the Me- nominee and Marquette Regions of Michigan, with an Introduction by R. D. Irving," Bull. 62, U. 8. Geol. Survey. lU KEMP'S ORK DEPOSITS. miles west of the Marquette mines. The rocks are less metamor- pliosed than in the previous two districts. The strata run east and west with a northerly dip of 60° to 80°, and with no subordinate folds. They consist of cherty limestone at the base, followed by quai-tz, slates, quartzite, iron ore, and ferruginous cherts, and final- ly slate and schists. The strata are traversed by dikes. The ore is a soft, red, somewhat hydrated hematite, with more or less man- ganese, which is often considerable and is most abundant in the southern mines. Hard specular is rare. Irving first showed that these ore bodies had originated from the replacement of dolomitic or Fig. 34. — Cross section of the Colby mine, Penokee Gogebio district, Mich- igan, to illustrate occurrence and origin of the ore. After C. R. Van Hise, Amer. Jour. Sci., January, 1891. calcific beds with iron oxide. Since then Van Hise has proved them to be in the troughs formed by the intersection of northerly dipping compact quartzites and southerly dipping trap dikes. He has traced the iron to a source in the layers of cherty carbonates, parallel with the quartzites and above them. From this it has been leached out by the percolating water and has been deposited in the apices of the troughs, where it has replaced the original car- bonate rooks. Somewhat the same process is outlined for the Mar- quette ores in his latest paper. Up to 1891, there were jiroduced a grand total of 8,300,000 tons of ore.' 1 R. D. Irving, Geol. Survey of Wisconsin, III., pp. 100-167, 1880. " Or- igin of the Ferruginous Schists ar:d Iron Ores of the Lake Superior Re- THE mow SEBiaS, CONTINUED. 125 2.02.25. Example 9(?. Vermilion Lake, Minnesota. Beds of hard specular with but little soft, intimately associated with jas- per (or jaspilyte, as locally called), and both contained in green schists. The district is situated in the northeastern corner of Minnesota, and northwest of Lake Superior. Two Harbors, the shipping point, is twenty-six miles east of Duluth, and Tower, the chief mining town, is sixty-seven miles from the docks. Leav- ing the lake, the railroad first crosses the north flank of the Lake Superior synclinal, consisting of southerly dipping igneous rocks belonging to the Keweenawan. Underlying these are a series of gabbros and augite-syenites that contain titaniferous magnetite and may be a parallel to the Adirondack norites. Next follow the black slates of the Animikie, and then a bed of quartzite called the Pewabic quartzite. N. H. Winchell applies to these collectively the name Taconio, a term which the best work in the East rejects in its home. They form the Mesabi range of hills. Sedimentary, gneissic, and eruptive exposures, referred to the Laurentian, suc- ceed in the north. Next come the Vermilion mica and hornblende schistc, and after these the Keewatin sericitic schists, jaspilyte, etc., containing the ore bodies at Tower. The Laurentian rocks appear again on the north, and beyond to the northwest is the Rainy Lake region, studied by A. C. Lawson. All the formations referred to above run in belts, having a general direction north and east. The ore bodies which are important as yet are all in the Keewatin. They vary in size from small bodies up to masses, which extend as much as a mile on the strike. They approximate the lenticular shape so characteristic of crystalline iron ore de- posits. The jasper, or jaspilyte, is everywhere associated, often very intimately, in parallel bands with the ore, while the contain- ing rock is a green schist which is regarded as an altered igneous rock or tuff. The principal mines are located at Tower, on Ver- milion Lake, and at Ely, which is twenty-three miles farther north- east. N. H. and H. V. Winchell, in the Bulletin referred to be- gion," Amer. Jour. Sei., iii., XXXII. 263,265; see also under Van Hise. C. D. Lawton, "Gop,'ebic Iron Mines,' Engineering and Mining Journal, Jan. 15, 1887, p. 42. C. R. Van Hise, "On the Origia of the Mica Schists and Black Mica Slates of the Penokee-Gogebic Iron bearing- Se- ries," Amer. Jour. Sai., iii., XXXI. 453-459. "The Iron Ores of the Penokee-Gogebic Series in Michigao and Wisconsin," Amer. Jour. Sci., iii., XXXVII. 33. 0. E. Wright, Geol. Survey of Wisconsin, III., pp. 239- 301. "li., •i:>.—eii- =^ THE IRON SEItlKS, CONTINUED. 131 (probably miigiiesinii) also occur. Spnrr is thus led to regard the lock as an altered gieeiisand, to which view similar conclusions re- garding tlie much more recent and unmetamorphosed ores of Texas and Lonisiana (see 3.01.15) give support. Tiie chemistry of the deposition is considered by Spun- to be the following. Atmos- pheric waters, with dissolved carbonic acid, and some alkaline salts have filtered into the cracks and become charged with ferrous carbonate where the conditions prevented oxidation. The greater solubility of the ferrous salt led to its solution before the alkali attacked the silica. Later, reaching more open and fissured portions, the ferrous salt was oxidized and deposited while the silica was attacked and re- moved by the alkali. In time, thus the iron oxide was concen- trated along fissured strips, near faults, and the like, whereas the silica was removed. It is recognized as well that the ferrous salt was precipitated as carbonate, amid deoxidizing conditions. The change from silicate or carbonate to hydrous oxide of iron led to shrinkage and shattering, and the passage from hydrous oxide to carbonate, where such occurred, to expansion and shattering. It follows from the explanation that the regions of rich ore bodies would be those of notable geological disturbances, so that faults are presumed near Virginia, Biwabik and elsewhere. * 2.02.39. Example 10. James River, Virginia. Specular hema- tite in narrow beds (lenses), interstratified with quartzitesand slates of metamorpbic character and Archean age. Tliey run four to six feet, or less, in thickness, with prevailingly vertical dip, but they also pitch diagonally down on the dip like tlie lenses of magnetite, later described. They furnish a very excellent grade of ore. Tiie ore bodies are found along both sides of the James River, a few miles above Lynchburg. Some magnetite also occurs in the region, and some limoniDe. More or less clay accompanies tiie ore.^ 2.02.30. Similar lenses of specular ore and magnetite are found 1 H. V. Winchell, Tioentieth lAnn. Rep. Minn. State GeologiU, p. 113, 1893 ; reprinted M. E. , 1893. Reo. The Nevr York Tiiiies of Deo. 14, 1898, has a quite extended account. H. V. Winoheii and J. T. Jones, "The Biwabik Mine, " M. E., February, 1893. '^ E. B. Benton, Tenth Cemns, Vol. XL, p. 363 (on Virginia). J. L. Campbell, Oeologij and Resources of the James River Valley, p. 49, New York, 1883. B. Willis, Tenth Census, Vol. XV., p. 301. The Virginias, a monthly formerly published by Jed. Hotchkiss, at Staunton, contains much information on Virginia in general. 133 KEMP'S ORE DEPOSITS. in central Nortli Carolina, in schistose rocks, which have been referred to the Huronian. 2.02.31. Lenses of specular hem- atite of very excellent quality are found also in metamorphio rocks, north of Fort Laramie, Wyoming, which may prove productive in time. But little is as yet known about them. 2.02.32. Example 11. Pilot Knob, Mo. Two beds of hard specular hem- atite separated by a thin seam of so- called slate (probably volcanic tuif), and interstratified with breccias and sheets of porphyry. Along the eastern limit of the Ozark uplift of Missouri and Arkansas a series of knobs of granite and porphyritic rocks project through the Cambrian limestones and sand- stones. They are older than the lime- stones, and clearly were not intruded through them. The limestones and sandstones lie up against the porphyry and in the valleys between. The un- derlying porphyry has been found in the valley near Pilot Knob, after pene- trating four hundred feet of sediment- ary rocks. The porphyry and ores have often been called Huronian, but in view of the recent reorganization of the Huronian (see Example 9), this is not done, nor ever has been, on any ac- curate grounds. Pilot Knob is formed by one of these eruptive knobs. It con- sists of sheets of porphyries that are capped by porphyry breccia, the two ore beds, and the intervening tuff. The beds strike and dip 13° S. S. W. The hill is over 600 feet high. The lower bed has furnished most of the ore, run- ning from 25 to 40 feet thick, and af- fording a dense bluish, specular hema- tite of from 50 to 60^ Fe, siliceous, and very low in phosphorus. The upper bed THE IRON SERIES, GONriNUED. 133 is ii'i-egular and of lower grade and rnii.s from G to 10 feet tbidc. Tlio Pilot Knob mines in this solid ore are now sulistantially exhausted. Recent drill holes ou the northerly slope and below the out- cropping face of ore have shown that under the Cambrian strata of M ../' Fia. 29. — Vieiv of open cut at Pilot Knob, Mo., shouting the bedded char- acter of the iron ore. From a photograph by J. F. Kent}:!, 1888. tlie valley there is a great bed of ore boulders or breccia in clay, much as is the case at Iron Mountain, later described. Analyses of cores were not, however, sufficiently encouraging for devehip- ment during the present low prices for iron. Doulitless the bee\\is mountains), s\(T a mile on thi' slriki.'. '2.0:!.():i. IJesides these extended bed,^ there arc otiuu dejiosits 140 KEMPS ORE DEPOSITS. exhibiting more perfectly the peculiar lenticular shape characteris- tic of magnetite, and to this class are to be referred the greater number of smaller bodies (Hammondville). They pinch and swell, roll and fold and feather out, and often come off sharply from the walls. They frequently follow and overlap one another like shin- gles, the second one succeeding the first in the footwall. They are not infrequently cut by trap dikes and are thrown by these and b}' normal faults. At Hammondville small gulches seem to cut off the ore, and are probably due to faults. Other deposits are of enormous size, as at Mineville (200 to 300 feet clear ore between the walls), and their relations are less clear. They may be large lenses doubled over in a sigmoid fold. The Champlain magnetite is quite notably granular as contrasted with New Jersey, which tends rather more to break in prisms. 2.03.04. C E. Hall has divided the metamorphic rooks of the Adirondacks into the (a) Lower Laurentian Magnetite Iron Ore series, containing the most important ore beds, {b) The Lauren- tian Sulphur Ore Series, (c) The Limestones and the Labrador or Upper Laurentian, with Titaniferous Iron Ores, (c) is thought to be certainly later than (a), but the relations of (6) are uncertain. T. S. Hunt also states that the titaniferous ores are associated with the Labradorite series or Norian, which he places as of later age than the gneisses with the good ore. Commercially the ores are divided into (1) ores high in phos- phorus but low in sulphur ; (2) ores low in both phosphorus and sulphur ; (3) pyritous ores ; (4) titaniferous ores ( Tenth Census, Vol. XV.). Under class (4) come numerous beds which are worth- less, but which if the titanium could be neutralized would be very valuable (Lake Henderson; see 2.03.11). Mineville is by far the most productive region. It ships 400,000 to 500,000 tons yearly. Chateaugay and Hammondville are next. The Arnold mines pro- duce some, while the Palmer Hill mines with the decline of the bloomaries have gradually ceased. The mines on the west side of the mountains are less important. They afford, so far as developed, a low grade of ore, that, however, with the improvements in mag- netic concentration, seems to promise well. The largest openings are at Jayville and Little River. There are numerous magnetite deposits in Canada of analogous geological relations, but they are often highly titaniferous.' 1 L. C. Beck, Mineralogy of New York, Part I., pp. 1-38. J. Blrkin- MAGNETITE AND PTRITR!. 141 2.03.05. Example 135. New York and New Jersey Highlands, and the South Mountain of Pennsylvania. Beds of lenticular shape in Archean gneiss and crystalline limestone. From Putnam County, New York, a ridge of Archean rocks runs southwest across the Hudson River, traversing Orange County, New York, and northern New Jersey, and running out in Pennsylvania. Lenses of magne- tite occur throughout its entire extent. They are not as large as in the Adirondacks, but are more regularly distributed. East of the Hudson, in Putnam County, the Tilly Foster mine is the most important, and the descriptions and figures of it are the best illus- trations of the shape of lenses published. West of the Hudson, in Orange County, the Forest of Dean mine affords considerable ore yearly. It is cut by an interesting trap dike. As the results of study of the Archaean of this region, N. L. Britton has divided it into a Lower Massive group, a Middle Iron Bearing, and an Upper Schistose. {Geol of N'. J., 1886, p. '77.) F. L. Nason has also sought to classify it on the basis of rock types, of which he makes four, named, from their typical occurrences. Mount Hope type, Oxford type, Franklin type, and Montville type. They are ar- bine, " Crystalline Magnetite in the Port Henry (N, Y.) Mines,'' M. E., Feb- ruary, 1890. Eec. H. Credner, Zeitsch. d. d. g. GeselL, 1869, XXI., p. 516; B. und H. Ze.it., 1871, 369. J. D. Dana, "On the Theories of Orig-in," Amer. Jwir. iSci.,iii., XXII. 153, 403. E. Emmons, Geology of Neio York, Second District, pp. 87, 98, 331, 355, 291, 309, 850. Hist. C. E. Hall, "Laurentian Magnetite Ore Deposits of Northern New York," Z'Zd Ann. Rep. State Museum, 1884, p. 133. Rec. J. F. Kemp, " Notes on the Miner- als Occurring near Port Henry, N. Y.," Amer. Jour. Sci., iii., XI. 63, and Zeitsch. f. Kryst., XIX. 183. G. W. Maynard, "The Iron Ores of Lake Champlain," Brit. Iron and Steel Inst., Vol. I., 1874. "W. C. Redfield, "Some Account of Two Visits to the Mountains of Essex County, N. Y., in 1836-37," Amer. Jour. Scl, i., XXXIII. 301. Hist. B. Silliman, "Re- marks on the Magnetites of Clifton, St. Lawrence County, N. Y.," M. E., I. 364. J. C. Smock, " Iron Mines of New York," Bull. VII., N. Y. State Museum. Rec. J. Stewart, "Laurentian Low Grade Phosphate Ores," M. E., February, 1892. Wedding, Zeitschr. f. B., H., und S. im. p. St., XXIV. 330, 1876. See also the general works on Iron Ores cited at begin- ning of Part II. On Canadian magnetites the following papers may be mentioned. F. P. Dewey, "Some Canadian Iron Ores," M. E., XII. 193. B. J. Harrington, " On the Iron Ores of Canada," Can. Geol. Survey, 1873- 74. T. S. Hunt, Can. Geol. Survey, 1866-69, pp. 261, 362. T. D. Ledyard, " Some Ontario Magnetites," M. E., XIX. 28, and July, 1891. W. H. Mer- ritt, " Occurrence of Magnetite Ore Deposits in Victoria County, Ontario," A. A. A. S., XXXI. 413, 1882. 142 KEMP'S ORE DEPOSITS. ranged in their order of probable age. Tliej^ correspjond in some respects to Britton's grouping, but differ materially in others. (Geol. of i\\ J., 1889, p. 30.) Four courses, or mine-belts, have been recognized in Kew Jersey, — the Rauiapo, the Passaic, the Mus- conetcong, and the Pequest, — in order from east to west. The lenses strike northeast with the gneisses, and usually have, like them, high dips. In addition they have also a so-called "pitch" Fig. 3.3a. Fig. mb. Figs. ^Z-:i riixl ?M.—Jfiide7 of the Ttlly Foster ore hody. 33a, Top xieu\ sUowiitij faulted slviidder. After F. S. Ruttmann, Trans. Amer. Inst. Mill. Eiiij.. -IT. 79. 336, Yieir of bottom of same. Photoijraplted by .J. F. Kemp from the model now at the School of Jlines, Columbia College. along the strike, s(j that they run diagonallv down the di]). They have been obser\ed to pitch northeast with an easterlvdip and southwest with a westerly. Either by the overiapjiing c,f lenses or li\' an approximation to an elongated bed, thev sometimes, as at Ililici-iiia, extend a mile or more in unbroken series. ^\gain, they may be alim.jst circular in cross section (Kurd mine). At Frank- lin Fiirn.'ice one is found in crystalline limestone.' 1 E. S. Breidentiangli, "Ori the Minerals Found at the Tilly Foster Mine. New Y..rk,'' Amer. Jour. Sci., ii ., VI. 207. J. F. Ivemp, " Diorite MAGNETITE AND PYRITE. 143 2.03.06. South Mountain, Penn. Small lenses of magnetite oc- cur in Berks, Bucks, and Lehigh counties of southeastern Pennsyl- vania, in the metamorphic rocks of the South Mountain belt. They are very like those to the north in New Jersey, but are lower in both iron and phosphorus. Their product is about 100,000 tons yearly. The Cornwall magnetite is described under Example 13, for its geological structure is entirely different from the lenses.' 2.03.07. Example 12c. Western North Carolina and Virginia. Beds of magnetite, of the characters already described, in Archean gneisses and schists. The ore body at Cranberry, N. C, is the lar- gest and best known. It occurs in Mitchell County, and has lately been connected by rail with the lines in east Tennessee. Accord- ing to Kerr, the principal outcrop is 1500 feet long and 200 to 800 feet broad ; but, of course, all of this is not ore. The mines can afford very large quantities of excellent Bessemer grade. Pyrox- ene and epidote are associated with the ore. Kerr has referred the magnetite to the Upper Laurentian. In the southern central por- tions of North Carolina other magnetites occur in the mica and tal- cose schists, which have been referred to the Hnronian. (SeeH. B. C. Nitze, Bull. I. N. C. Geol. Survey, for detached report.) (Ex- ample 10.) Magnetite has also been lately reported from Franklin and Henry Counties, Virginia, and Stokes County, North Caro- lina. Some doubt, however, is cast on its amount and quality.^ Dike at the Forest ot Dpcan Mine," Amer. Jour. Sci., iii., XXXV. 331. F. H McDowell, " The Rpopeniog of the TiUy Foster Mioe," M. £., XVII. 758 ; Engineering and Mining Journal, Sept. 7, 1889, 206. F. S. Ruttnian, "Notes on the Geology of the Tilly Foster Ore Body, Putnam County, New York," M. £•., XV. 79. Rec. J. C. SmocXi, Bull. VII., N. Y. State Museum. Rec. A. F Wgndt, " The Iron Mines of Patnatn County,'' 3£ ^., XIII. 478. "Iron Mines of New Jersey," School of Mines Quarterly, iv., III. N. L. Britton, Ann. Rep. N. J. Survey, 1886, p. 77. Rec. G. H. Cook and J. C. Smock, Oeol. of N. J., 1868. Rec. (See aUo subsequent annual reports, especially 1873, p. 12.) F. L. Nason, Ann. Rep. N. J. Survey, 1889. Rec. J. W. Pullmann, "The Production of the Hibeinia Mine, New Jersey," M. E., XIV. 904. J. C. Smock, "The M.ignetite Iron Ores of New Jersey," M. E., II. 314 ; " A Review of the Iron Mining In- dustry of New Jersey," M. E., June, 1891. Rec. 1 E. D'Invillieis, Rep. D3, Penn. Survey, "VoX. II. (South Mountain Belt of Berks County). Rec. F. Piime, Rep. D3, Vol. I. Penn. Survey (Lehigh County). B. T. Putnam, Tenth Census, Vol. XV., p. 179. 2 W. C. Kerr, Geol. of N. C, 1875, 264. H. B. C. Nitze, " On Some ot the Magnetites of Southwestern Virginia, etc., and Discussion of Same, by E. C. Pechin," M. E., June, 1891. B. Willis, Tenth Census, Vol. XV., p. 335. E. & M. Journal, Jan. 7, 1888. Kerr & Hanna, " Ores of North Carolina," 1893. 144 KEMPS ORE DEPOSITS. 2.03.08. Example \2d. Colorado Magnetites. Beds of mag- netite of a lenticular character in rocks described as syenite (Chaf- fee County) and diorite (Fremont County). With these a number of others are mentioned which vary from the example, but of which more information is needed before they can be well classified. The last are mere prospects. The mines in ChafPee County have been the only actual producers. There are three principal claims — the Cal- umet, Hecla, and Smithtield. They extend continuously over 4000 feet. The wall rock is called syenite. Chauvenet describes them as having resulted from the oxidation of pyrites, and as being in rocks of Silurian age. They average 57^ Fe, with only 0.009 P, but are comparatively high in S, reaching 0.1 to 2.0^. These mines and those at the Hot Springs, mentioned under Example 2, have furnished the Pueblo furnaces with most of their stock. The de- posit in Fremont County is at Iron Mountain, but is too titanifer- ous to be valuable. It is a lenticular mass in so-called diorite. A large ore body has been reported from Costillo County, in limestone (Census Report) or syenite (Rolker). In Gunnison County, at the Iron King and Cumberland mines, excellent ore occurs in quartz- ites and limestones, called Silurian. At Ashcroft, near Aspen, high up on the northern side of the Elk Mountains, is a great bed or vein of magnetite, in limestones of Carboniferous age, with abundant eruptive rocks near. It is thought by Devereux to be al- tered pyrite. Still, pyrite is a common thing with magnetite else- where. There are other smaller deposits in Boulder County and elsewhere in the State.' 2.03.09. In Wyoming an immense mass of titaniferous magne- tite is known near Chugwater Creek. It is described by Hague as resembling a great dike in granite.^ Gabbro is in the neighborhood. 2.03.10. Example 12e. California Magnetite. Beds of mag- netite of lenticular shape in metamorphic slates and limestones on the western slope of the Sierra Nevada. Others of different char- acter are also known. In Sierra and Placer counties lenses of excellent ore are found, accompanying an extended stratum of lime- 1 E. Chauvenet, " Papers on Iron Prospects of Colorado," Ann. Reps. Colo. State School of Mines, 1885 and 1887 ; a'so M. E., Denver meeting, 1889. Eeo. W. B. Devereux, " Notes on Iron Prospects in Pitkin County, Colorado," M. E., XII. 608. B. T. Putnam, Tenth Census, Vol. XV., p. 472. Eec. C. M. Rolker, " Notes on Iron Ore Deposits in Colorado," M. E., XIV. 306. Rec. 2 " Iron Mountain, Wyoming," 40<7i Parallel Survey, Vol. II., p. 14. MAGNETITE AND PYBITE. 145 stone in chlorite slate. A great ore body of magnetite described as a vein has lately been reported from San Bernardino County. It is said to be from 30 to 150 feet thick, and to lie between dolo- mitic limestone and syenite.' A great bed of a kind not specified is reported from San Diego County.^ 2.03.11. Example 13. Masses of titaniferous magnetite in igneous rocks which are most often gabbros or related types. General comments were made upon these in 1.06.14 and 1.06.16. In many cases such ore bodies seem undoubtedly to be excessively basic segregations of fused and cooling magmas. Whether the tendency of these early crystallizations to concentrate is due to Soret's principle, to magnetic currents or attractions, or to the high specific gravity of the mineral which might cause it to sink in the magma is perhaps not always clear, for all these explanations have been suggested. The masses are not yet of practical value in North America, and hence are not, strictly speaking, ores, but no one fa- miliar with their size and amount can resist the conviction that they will ultimately be utilized. The commonest rocks form- ing the walls are gabbros, norites, diorites or peridotites, all of which are close relatives. Later metamorphism, such as moun- tain-making processes and the like, sometimes give the wall-rock a gneissic structure and stretch out the ore into apparent beds. In the great series of labradorite rocks, which is so extensive in Canada and the Adirondacks, and which was called by T. S. Hunt the Norian, these ores are very abundant. What are doubtless the largest masses of them in this region occur at the headwaters of the Hudson Kiver near Lake Sanford and Lake Henderson. Prof. E. Emmons, of the New York Geological Survey in 1835-40, de- scribed them at length in his report on the Second District. For some 15 or 20 years a small charcoal furnace treated them to ad- vantage but was blown out before the war. A recent survey by Uno Sebenius has indicated even more ore than was known to Emmons, although he recorded a mass 500 feet wide and 1600 1 Ann. Rep. State Mineralogist, 1889, p 335. 2 Ibid., 1889, p. 154. J. R. Browne, " Mineral Resources West of the iJocky Mountains," 1868. C. King and J. D. Hague, "Mineral Resources West of the Rocky Mountains," 1874, p. 44. H. G. Hanks and W. Irelan, Ann. Reps. State Mineralogist, California. (Very little on iron.) F. von Eichthofen, private reports quoted in Tenth Census, Vol. XV., p. 495. J. D. Whitney, Oeol. Survey Cal, Vol. I. 146 KEMP '8 ORE DEPOSITS. feet long. Smaller bodies are frequent elsewhere in the Adiron- dacks^ (as at the Split Kock Mine, Westport, the Crag Harbor, Port Henry, the Humbug Vein, Mineville). The TiOj ranges up to about 15^ and with it is much AI2O3, but on the other hand very little sulphur or phosphorus. Whether the TiOo is present in mechanically mixed non-magnetic ilmenite (menaccanite) or in an actually titaniferous magnetite is not always clear. This ques- tion has its practical bearings, for hopes have been entertained that magnetic concentration might reduce the TiO^- It cannot be relied on, however, for 0. A. Derby has mentioned to the writer natural lodestone from Brazil with 20^ TiOg. Fairly high titaniferous ores occur in New Jersey on Schooley's Mountain and to the southwest of it. Small percentages up to 1^ TiOj are known in many other magnetites.^ The wall rocks of these ores deserve microscopic determination so as to compare them with the Adirondack gabbros. Titaniferous ores are also known in Virginia and North Caro- lina,3 in the gabbros of Minnesota (2.02.35), in "Wyoming (2.03.09), and in Colorado (2.03.08). Microscopic determinations of the wall rock in the western cases would be of great interest. The geolog- ical relations of these ores have long been known in Sweden and Norway, but an igneous form of origin has of late received especial attention from J. H. L. Vogt (see 1.06.16). 2.03.12. Example 14. Cornwall, Pa. Deposits of soft mag- netite, resting against igneous dikes and associated with green, pyritous shales, Siluro-Cambrian limestone and Triassic sandstone. These ore-bodies are to be classed among the largest ever mined. They form three hills extending in an east and west direction and called respectively Big Hill, Middle Hill and Grassy Hill. As the accompanying contour map shows. Big Hill is the highest and ' E. Emmons, Rep. on Second District, N. Y. State Survey, pp. 244- 255, 1843. J. F. Kemp, ' ' Iron Ores in Moriah and Westport Townships, Essex County, N. Y. , in Rep. of F. J. H. Merrill on the K. Y. State Ex- hibit at the World's Fair. A. J. Rossi, "Titaniferous Ores in Blast Furnace,'' Trans. Amer. Inst. Min. Eng., Feb., 1893. J. C. Smock, Bulletin N. Y. State Museum, p. 37. 2 B. F. Fackenthal, Trans. Amer. Inst. Min. Engineers, XXI. 378. R. W. Raymond, Ihid., 374. " H. B. C. Nitze, ' ' Notes on Some of the Magnetites of Southwest Virginia and the Contiguous Territory of North Carolina, ' ' Trans. Amer. Inst. Min. Eng., XX. 174; " Magnetite Iron Ores of Ashe Co. , N. C. , Ibid., XXI. 372 ; "Iron Ores of North Carolina, ' ' Bull. I., X. C. Geol. Sur., 1893. MAGNETITE AND P TRITE. 147 narrowest, while Middle Hill contains the most ore. The hills lie just at the southeastern edge of the Great Valley and are six miles from the flourishing little city of Lebanon. The geological section (Fig. 34) illustrates the position of the strata. The Siluro-Cam- brian series is cut by an immense diabase dike near its southeastern limit, and on the south side of the dike which forms the northern rampart of the three hills lies the ore. The ore is a soft, rather .^cale ofjuil^a. Fig. %^.— Section along Cormvall Railroad from Lebanon to Miner''s Vil- lage. After E. V. Wlnvilliers, Amer. Inst. Min. Eng., Feb., 1886. earthy magnetite, which occasionally sliows octahedra. While richer and purer on the original weathered surface, it is now in terlaminated and closely involved with layers of limy shales which contain pyrite, at times in beautiful crystals. Most of the ore is merchantable raw, but large quantities are so low from this admix- ture of shales that they are being saved for possible future mag- netic concentration. The presence of the pyrite makes it neces- sary to roast all the raw ore before smelting, but the phosphorus is so low that Bessemer pig is the chief resulting product. Big Hill differs from the others in structure. The nothern dike with a steep southerly dip has an offsetting and very heavy branch to the southwest which forms with it a great trough or basin so fa'r as one can see. The bottom of the ore has been reached by one rather shallow hole, but it seems quite certain that the dikes will come together at a point indicated by the several dips. The sur- face of the southerly branch is strongly corrugated. The ore of Middle Hill extends to a greater distance south from the dike than that of Big Hill and is cut by one small and unimportant offset of trap that is two or three feet across. At the western end of the MAGNETITK AND PTRITE. MiJ workings, limestone is quite thick and in good exposure. It reaches well over to Grassy Hill. Grassy Hill is smaller, and is much less developed than either of the others. E. V. d'Invilliers has empha- sized the important point that the dip of the ore in Big Hill is south- west at such an angle as to bring it below the Middle Hill bed, and that this latter also dips below the limestone and the Grassy Hill beds. Such being the case enormous reserves must lie under the two western hills. The depths of the several bore holes given on the map and all in ore indicate its presence in very great amount, but it is important to show in this connection the absence of faults, for the map of Bailey Willis notes their presence, and observations of the writer corroborated their existence. The pyrite in the calcareous shales is occasionally replaced by chalcopyrite in irregular nodules or veiulets. The presence of copper was early noted, and some mining was done for it near the surface. Fine museum specimens of moss-copper, azurite, mala- chite, etc., were afforded. Even during the earlier iron-mining some copper ore was set aside as a small by-product. Copper is still present in the mine-water, for bright shovels left in it become coated, and the bones of dead animals thrown out on the ore banks, as well as chips of wood, etc., become tinted a bright green. Much difEerence of opinion has prevailed about the age and geo- logical relations of these ores. Some have thouglit them Mesozoio and a part of the Triassic, while others, and notably J. P. Lesley, have regarded them as belonging to the Siluro-Cambrian series and analogous to the limonites of the Great Valley but metamorphosed. The great trap dikes afford the most reasonable explanation or cause of the change, and to these may be referred the alteration. The apparent origin of many Siluro-Cambrian limonites from the hydration and oxidation of pyritous shales and schists gives much support to this view, and the association of limestone with the ore and the general stratigraphical relations are hard to explain in any other way.^ The total production to date (April, 1894) is stated by Mr. Boyd, the superintendent of the mines, to be upwards of 12,000,000 IE. V. d'Invilllers, "Cornwall Iron Ore Mines," Trans. Amer. Inst. Min. Eng., XIV. 873. Rec. Lesley and d'Invilliers, Ann. Eep. Second Penn. Oeol. Suv., 1885, 491. Reo. J. P. Lesley, Pinal Rep., I. 351, 1893. T. S. Hunt, "The Cornwall Mines, " etc., Trans. Amer. Inst. Min. Eng., IV. 819. H. D. Rogers, First Penn. Oeol. Svrv., II. 718. B. WiUis, Tenth Census, XV. 233. 150 KEMP'S UBK DEPOSITS. tons, while an annual output of 800,000 can be easily maintained. The on; varies from 40 to 55^ Fe. It almost never contains as much as 0.02 P., but runs up to 4^ S. It is also siliceous. 2.03.13. Several other mines of somewhat related character to the Cornwall deposits are known along the edges of this Triassic belt and associated with its trap intrusions. The mining districts lie near its north and south boundaries, and not far from its contacts with the older rocks. On the north side from east to west there are the Boyertown (Berks County), the Fritz Island and the Wheat- field, near Reading, and finally the Dillsburg in York County, west of the Susquehanna. On the south side in the same order are the Frencli Creek, St. Mary's and the Jones, all quite near together and nearly south of Reading. Of these the Boyertown mines have been most worked. ^ The Cornwall mines are between the Wheat- field and the Dillsburg. At the Boyertown mines the ore lies both between a brecciated limestone and Mesozoic sandstone and wholly within the limestone, but trap dikes are not lacking. At Fritz Island the ore is entirely enclosed in limestone, and is penetrated by a trap dike. In the Wheatfield mines the same brecciated limestone appears and has the ore intimately associated with it. On both occurs the Mesozoic sandstone and the succession is five times repeated by faulting. The usual trap penetrates the ore. The French Creek and St. Mary's mines are unique in that they are contained in gneiss. They are famous sources of fine crystals of pyrite, chalcopyrite and other minerals. The Jones mine exhibits the ore between trap and limestone, the trap being over the ore in the north pit and under it in the south. A green shale is also met here, as indeed in most of the other localities, although not specially mentioned. At Dillsburg the evidence against the Triassic age of the ores is less positive, and upon this occurrence Fraser has based a strong argument for the latter view. Triassic sandstone at times forms both walls, although there are instances where limestone appears as the foot. In all these local- ities the presence of copper is notable. It and the magnetic or metamorphosed condition of the ore are probably leferable to the trap. ' B. WiUis, Tenth Census, Vol. XV., 323. Rec. P. Fraser, "Study of the Specular and Hematite Ores of Iron of the New Red Sandstone, in York County, Penn. , Trans. Amer. Inst. Min. Eng., V. 132. Also Perm. Oeol. Survey, Bep. CC, 205, 217. H. Hoefer, "Die Kohlen und Eisenerzlagerstatten Nord Amerika's, " 241. MAGNETITE AND P TRITE. 151 2.03.14. Example 14a. Iron County, Utah. Beds of mag- netite and hematite bearing evidence of being metamorphosed limonite, in h'mestones of questionable Silurian age, and associated with eruptive rocks described as trachyte. The limestones have been much upturned, metamorphosed, and pierced by dikes and eruptive masses. The ore forms great projecting ridges and prom- inent outcrops, locally called " blow-outs." The usual lenticular shape is not lacking. They occur over an area of fifteen by five miles, and are in the southern end of the Wasatoh Mountains. The samples show rich ores, which at times exceed the Bessemer limit of phosphorus. In the Star district the ore apparently lies between quartzite and granite. Hematite occurs in large amount, as does quartz, while some streaks have large crystals of apatite. The importance of the deposits lies in the future. They are the largest in the West, and are interesting in their bearing on the general origin of magnetite. Coal, not proved to be good for smelting, is near, but centers of iron consumption are very far away.' 2.03.15. Example 15. Magnetite Sun>l8. Beds of magnetite sands concentrated on beaches or bars by waves and streams. The magnetite has been derived from the weathering of igneous and metamorphic rocks, through which it is everywhere dis- tributed. When in the sand of a sea beach, it and other heavy minerals tend to be concentrated by the sorting action of the waves. They resist the retreating undertow better than lighter materials. Such deposits are very abundant at Moisie, on the St. Lawrence, below Quebec, and in the United States are known in smaller de- velopments on Lake Champlain ; at Quogue, L. I.; on Block Island ; in Connecticut ; along the Great Lakes, and on the Pacific coast. Grains of garnet, olivine, hornblende, etc., minerals of high Also Penn. Survey, Rep. C2. E. V. D'lavilliers, "Cornwall Iron Ore Mines,'' M. E., XIV. 873. Rec. Lesley and D'lQvilLers, Ann. Rep. Second Penn. Survey, 1885. J. P. Lesley, Final Report, Vol. I., p. 351, 1892. Rec. T. S. Hunt, "The Cornwall Mines," etc., M. E., IV. 319. H. D. Rogers, First Penn. Geol. Survey, II. 718. B. Willis, Tenth Census, Vol. XV., p. 233. Rec. 1 W. P. Blake, "Iron Ore Deposits of Southern Utah," M. E., XIV. 809. J. S. Newberry, " Genesis of Our Iron Ores," School of Mines Quar- terly, March, 1880. Rec. Engineering and Mining Journal, April 23, 1881, p. 286. Proc. National Academy, 1880. B.T.Putna,m, Tenth Census, Vol. XV. 486. Rec. 152 KEMP'S ORE DEPOSITS. specific gravity, are also in the sands. Many are too high in titanium to be of use, but there is no more difficulty in concentrat- ing them than artificially crushed ore. In Brazil and New Zea- land they have attracted attention. * 3.03.16. Onthe Origin of Magnetite Deposits. — It is important to note that magnetite deposits are almost always in metamorphic rocks, Avhich owe their character to regional metamorphism, or to the neighborhood of igneous rocks (Pennsylvania and Utah). Gneisses form the commonest walls, but so-called norites, or gab- bros, and crystalline limestones also contain them. Where there is lamination, or bedding, the magnetite conforms to it. As the his- tory of the metamorjDhic rocks is so often uncei'tain, the magnetites share the same doubt. In igneous rocks magnetite is the most widely occurring of the rock-making minerals. In all explanations the prevailing lenticular shape, the general arrangement in linear order, and the existence of great beds must be considered. The shape is very similar to that of dej>osits of specular hematite, with which magnetite is often associated. (Examples 9 and 10.) The following hypotheses have been advanced as to their origin : 1. As intruded (eruptive) masses. This supposes an origin for the lenses on the analogy of a trap dike. Though formerly much advocated, it is now generally rejected. 2. As excessively basic portions of igneous rocks. This supposes that large amounts of iron oxide separate in the cooling and crystallizing of basic magmas. There are such occurrences, although seldom, if ever, pure enough or abundant enough for mining. The titaniferous magnetite of the Minnesota gabbros has been alluded to (2.02.25), and also the Brazilian ore and the Cumberland Hill (R. I.) peridotite. (See also Dakyns and Teall, Q. J. G. S., XLYIII., p. 118.) Should such igneous rocks be subjected to regional metamorphism and the stretching action characteristic of it, the ore masses might be drawn out into lenses. .3. As metamorphosed limonite beds. This idea has been most widely accepted in the past. It presupposes limonite beds formed as in Examples 1 and 2, which become buried and subjected to metamorphism, changing the ore to magnetite and the walls to schists and gneisses. Igneous rocks have ap- parently changed limonites to magnetite at Cornwall, Penn., and in Utah, but such changes by regional metamorphism are less easy 1 T. S. Hunt, Geol. Survey Canada, 1866-69, 361, 363; Canad. Nat, VI. 79. A. A. Julieo, " The Genesis of the ( rystalline Iron Ores," Acad. Nat. Sci., Phil., 1882, 335 ; Ewjineering and Mining Journal, Feb. 2, 1884. MAGNETITE AND PTBITE. 153 to demonstrate. The limonite may Lave resulted from, the oxida- tion of lenses of pyrite. 4. As replaced limestone beds, or as sider- ite beds subsequently metamorphosed. Such deposits may pass through a limonite stage. The general process is outlined under Example 9e, as developed by Irving and Van Hise in the Gogebic district. The lenticular deposits of siderite at the Burden mines (Example 4) are very suggestive, and some such original mass might in instances be metamorphosed to magnetite. 5. As sub- marine chemical precipitates. This is outlined under Example 9c?, as applied by the Winchells in Minnesota. 6. As beach sands. The lenses are regarded as having been formed as outlined under Example 15. The same heavy minerals sometimes occur with magnetite lenses as are found on beaches. (See B. J. Harrington, Can. Geol. Survey, 1873, 193 ; A. A. Julien, Phil. Acad. Sci., 1882, 335.) v. As river bars. This regards the lenses as due to the concentration of magnetite sands in rivers or flowing currents. Hence the overlapping lenses, the arrangement in ranges or on lines of drainage, and the occasional swirling curves found on the feather- ing edges of lenses, as in the Dickerson mine, Ferromont, N. J. (See H. S. Munroe, School of Mines Quarterly, Vol. HI., p. 43 — an important paper.^ It is also reasonable to suppose that lakes or still bodies of water may have occurred along such rivers, and have occasioned the accumulation. 8. As segregated veins. By this method the iron oxide is conceived to concentrate from a state of dissemination in the walls by slow segregation in solution to form the ore bodies along favorable beds. The action is analogous to the formation of concretions and is illustrated on a small scale by the well-known discs of pyrite, or of siderite, that form in clays and shales. It is a curious fact, however, that some magnetites are in wall rock that hardly shows a trace of a dark silicate. The lenses at Hammondville, in the Lake Champlain district, are in a white or light colored gneissoid rock, consisting of quartz, acidic plagioclase, and a few scattered garnets. In such surround- ings segregation could not be applieJ, but where the walls are sup- plied with hornblende, and other ferruginous minerals, and are reasonably basic, it might be advocated. Several other hypotheses with small claims to credibility could be cited. They are outlined at length in Bull. VI., Minn. Geol. Survey, p. 224, but in this place there has been no desire to take up any but those deserving serious attention. It may be said that while one or the other of the above seven bypotlieses may in instances be 154 KEMP'S ORE DEPOSITS. applied with reason, yet most candid observers with widened ei- perience have grown less positive in asserting them as axiomatic. 2.03.15. Of importance in connection with iron ore deposits are the recent studies of the distribution of phosphorus along certain lines in the beds, by a knowledge of which it is possible to keep more valuable Bessemer ore distinct from less valuable. Such lines have been found in Michigan, and have been called by Mr. Browne " isochemic lines." Though less marked at the Burden mines (Example 3), the phosphorus was characteristic of certain varieties of the ore. Much work has also been done on the same question at Iron Mountain, Mo.' ANALYSES OF MAGNETITES. (Caution in interpreting analyses is again emphasized .as under 2.01.26.) Fe. P. S. TiOa. SiOj. 60.28 9.80 49.34 0.029 0.052 18.447 66.00 0.003 62.10 1.198 63.00 0.621 0.148 48.82 0.021 0.08 11.75 53.75 0.364 42.7 0.185 0.620 64.64 0.004 0.115 49.23 0.026 3.85 58.75 0.044 0.133 62.6 0.12 4.80 60.68 10.87 AljO, Canada (Bideau Canal) Chateaugay mines, N. Y . , lump . . " " concentrated. Mineville, N. Y. (Mine 21) Orange County, N. Y. (Forest of Dean) Putnam County, N. Y New Jersey (Hibernia) Cornwall, Penn Cranberry, N. C Colorado (Calumet) " (Iron King) Utah (Iron County) California (Gold Valley) 3.50 3.411 PYEITE. 2.03.16. Example 16. Pyrite Beds. Beds (veins) of pyrite, often of lenticular shape and of character frequently analogous to magnetite deposits, in slates and schists of the Cambro-Silurian or Huronian systems, and less often in gneiss of the Archean. Slates are most common, and gneiss least so. They extend from Canada down the Appalachians to Alabama, being found at Capelton, 1 D. H. Browne, " On the Distribution of Phosphorus at the Ludding- ton Mines." etc., M. E., XVII., p. 616. I. Olmsted, " The Distribution of Phosphorus in the Hudson River Carbonates," M. E., Colorado meeting, June, 1889. W. B. Potter, Analyses of Missouri ore published in Mineral Resources, 1890, p. 47. MAGNETITE AND P 7 RITE. 155 Quebec ; Milan, N. H. ; Vershire, Vt. ; Charlemont, Mass. (An- thony's Nose, N. Y., and the Gap mine, Pennsylvania, being pyr- rhotite, will be mentioned under " Nickel " with other similar oc- currences) ; Louisa County, Virginia ; Ducktown, Tenn. (see above, Fig. 6), and at many points less well known in Alabama. Also at Sudbury, north of Lake Superior, recent developments have shown an enormous deposit, specially discussed under " Nickel." 2.03.17. The ore bodies lie interbedded in the slates, and often the different lenses overlap and succeed each other in the footwall and exhibit all the phenomena cited under magnetites. Chalco- pyrite is usually present in small amount, and where the copper reaches 3 to b% they are valuable as copper ores. (See under ^^^^^2ZZZ2^ y////y/////////////'/y//y^y^^''''^y^^^'''''''-'''''''>y Fig. 86. — Illustration of overlapping lenses of pyrite. After A. F. Wendt, School of Mines Quarterly, Vol. VIZ., 1886. "Copper.") At present they are of increasing importance as a a source of sulphuric acid fumes for the manufacture of sulphuric aoid. Small amounts of lead and zinc sulphide are often present, rarely a little silver. Nickel and cobalt occur especially in the pyr- rhotitic varieties. They are worthless as a source of iron. The auriferous pyrites of the Southern States will be mentioned under "Gold." 2.03.18. They may have accumulated in a way analogous to the bog ore hypothesis, cited under " Magnetite ; " but instead of the iron being precipitated as oxide, it has probably come down as sulphide from the influence of decaying organic matter, and has subsequently shared in the metamorphism and solidification of the 156 KEMP'S ORE DEPOSITS. wall rock. At the same time it must be admitted to be an obscure point. By many they are thought, with more reason, to have originated like a bedded fissure vein whose overlapping, lenticular cavities have been formed by the buckling of folded schists.* (Of. '•' Gold Quartz," as later described.) 3.03.19. The excavations in some of the mines in the pyrite beds of Canada, just north of the Vermont line, have shown dikes of granite in close association with the ore. Thin sections of the granite indicate that it has suffered extremely severe dynamic metamorphism, for crushed and strained crystals make up nearly all of its substance. It is quite probable that the disturbance which caused the schistosity or slaty cleavage of the country lock likewise developed the strains in the granite which must thus have been intruded previous to its operation. Before the shattering the dikes may have exerted a genetic influence in connection with the ore body, but now the ore is usually lean near them. The ore bodies are also cut by fine examples of the trap (camptonite) dikes ■which are abundant in the Lake Champlain Valley. Prof. J. H. L. Vogt, of Christiania, Norway, has written of late regarding the origin of similar great bodies of sulphides in Europe, and when they occur in connection with rocks, which though now gneissoid have been originally igneous, he regards them as basic segregations of an igneous magma. (See further 1.06.16.) Where they occur in schists he attributes their formation to ore-bearing solutions, penetrating along planes of weakness, and stimulated by neighbor- ing igneous intrusions. In some of the instances cited the known 1 W. H. Adams, " The Pyrites Deposits of Louisa County, Virginia," M. E., XII., p. 527. C. R. Boyd, " The Utilization of the Iron and Copper Sulphides ot Virginia, North Carolina, and Tennessee," M. E., XIV., p. 81; Resources of S. W. Virginia. H. Credner, " AtSt. Anthony's Nose, Hudson River,'' B. und H. Zeit., 1866, p. 17 ; "Pyrite in Virginia, Tennessee, and Georgia," B. und H. Zeit., 1871, p. 370. H. T. Davis, Mineral Resources of the U. S., 1885, p. 501. H. M. Howe, " The Copper Mines of Vermort," M. E., Baltimore meeting, February, 1892. William Marty n, Mineral Re- nources, 1883-84, p. 877. E. C. Moxham, "The Great Grossan Lead of Virginia " (altered pyrite in CarroU County), M. E., February, 1893. A. F. Wendt, "The Pyrites Deposits of the AUeghanies, " School of Mines Quarterly, Vol. VII. , and separate reprint ; also Engineering and 3Iining Journal, June 5, 1886, p. 32 and elsewhere. Rec. H. A. Wheeler, ' ' Copper Deposits of Vermont, ' ' School of Mines Quarterly, IV. 310. Arthur Winslow, ' ' Pyrites Deposits of North Carolina, ' ' Ann. Kept. N. C. Experiment Station, 1886. MAGNETITE AND PyRITB.. 157 igneous intrusions (as at Rammelsberg) are at some distance and tlms are not directly associated, so far as one can see, witli the ore. The genetic connection is therefore somewhat hypothetical. 3.03.30. The relative importance of the different kinds of ore is shown by the following tables for 1880 and 1890. The increase in red hematite is due to the Lake Superior region and to Alabama. In the immediate future the soft ores of the Mesabi district will help to greatly swell the total, but during 1893-94 there was great depression in the mining of iron ore throughout the country. 1880. Red hematite 2,512,',' l;j Magnetite 2,390,389 Brown hematite 2,149,417 Carbonate 922,288 Per cent. Per cent. of Total. 1890. of Total. 31.51 10,527,650 65.65 39.98 2,570,838 16.03 26.95 2,559,938 15.96 11.56 377,617 2.36 7,974,806 100.00 16,036,043 100.00 As indicating the relative importance of the different mining regions, the following figures are of interest. No individual State producing less than 100,000 tons is given. states. Total in mo. States. Total in 1S90. Michigan 7,141,656 New Jersey 495,808 Alabama 1,897 815 Tennessee 465,695 Pennsylvania 1,361,632 Georgia 344 088 New York 1,353,393 Missouri 181.690 Wisconsin 948,965 Ohio 169 088 Minnesota 891.910 Colorado 114 875 Virginia 543,583 All the others 326.455 Grand total 16,036,043 2.03.21. Note. Large quantities of excellent Bessemer hema- tite are shipped to Baltimore and other Atlantic ports from the mines on the southeastern coast of Cuba, in the Juragua Hills. Santiago de Cuba is the largest town in this region and is some twenty miles west of the mines. The coast range of hills consists mainly of syenite, according to J. P. Kimball, and the syenite is penetrated by many dikes and mantled by sheets of diorite with which the ores are associated. Kimball refers the precipitation of much of the iron oxide which came from the diorite to coral- line limestone, which had been accumulated as coral reefs on the syenite before the diorite was intruded, but he also mentions other deposits in the diorite not associated with limestone. From observ- 158 KEMP'S ORE DEPOSITS. ations of another group of ores sixteen miles east of those studied by Kimball, F. F. Chisholm reached a dififerent conclusion regarding their origin. Chisholm refers them to a source below and apparently regarded them as veins or replacements of dikes. The amount of ore along this coast, both in place and as float is very great,' and will be an important feeder to American furnaces. Between three and four hundred thousand tons are now annually imported. Chis- holm gives the following analysis: Fe. s. p. Juragua (Kimball) 64.75 0.146 0.037 Sigua (Graham) 64.00 0.040 0.016 Berraco (Chisholm) 60.00 0.037 0.027 Although not a source of supply for American furnaces, it is in- teresting to note in this connection' that in Mexico vast deposits of hematite and martite occur in Cretaceous limestone associated with intrusions of diorite. The paper of K. T. Hill cited below gives a review and full bibliography of the various localities. The notable deposits so far as yet opened up are the Cerro de Mercado, in Du- rango,^ the Sierra de Mercado, near Monclova in Coahuila,' and ' J. P. Kimball, ' ' Geological Relations and Grenesis of the Specular Iron Ores of Santiago de Cuba," Amer. Jour. ,Sci., Dec. , 1884, p. 416; also "The Iron Ore Range of the Santiago District of Cuba, " Trans. Amer. Inst. Min. Eng., XIII. 613; Eng. and Min. Jour., Dec. 20, 1884, p. 409. F. F. Chisholm, "Iron Ore Beds in the Province of Santiago, Cuba," Proc. Colo. Sci. Soc, in. 259, 1890. H. Wedding, "Die Eisen- erze der Insel Cuba," Stahl und Eisen, 1892, No. 12. Prof. J. W. Spencer has been recently workiiig on the geology of Cuba and pre- sented some of his results at the meeting of the American Association in Brooklyn, August, 1894. 2 J. Birkinbine, ' ' The Cerro de Mercado or Iron Mountain of Du- letngo," Trans. Amer. Inst. Mill. Eng., Xni. 189, 1884. J. P. Carson, "Iron Manufacture in Mexico," Idem., VI. 899. R.T.Hill, "The Oc- currence of Hematite and Martite Iron Ores in Mexico, " Amer. Jour. ,S'ci., February, 1893, 111. B. SiUiman, "Mai-tite of the Cerro de Mer- cado or Iron Mountain of Durango, and Certain Iron Ores of Sinaloa, ' ' Amer. Jour. Sci., Nov., 1882, 875. See also on the Durango Iron Moun- tain, Anales del Ministerio de Fomento de la Rep. Mej:icana Tomo., TIT. 1877 ; and Engineering and Mining Journal on "Iron in Mexico," Nov. 10, 1888, p. 891. " P. Fraser, ' ' Certain Silver and Iron Mines in the States of Neueva Leon and Coahuila, Mex.," Trans. Amer. Inst. Min. Eng., XII. 537. R. T. HiU, as cited in previous footnote. MAGNETITE AND PTRITE. 159 others of minor importance in the States of Jalisco/ Guerrero^ and elsewhere. Several of these are now the basis of a small local smelting industry. ^ J. P. Carson, as cited in second footnote, page 158. ^ N. S. Manross, ' ' Notes on Coal and Iron Ores in State of Guer- rero, Mex. , Amer. Jour. Sci., May, 1865, p. 309 ; Remarks by J. D. Dana, p. 358. CHAPTER IV. COPPER. 2.04.01. Copper Ores. TABLE OF ANALYSES. Cu. S. Fe. Native copper (generally with some silver) 100. Chalcocite, Cu^S 79.8 20.3 Chalcopyrite, CuFeSs 34.6 34.9 30.5 Bornite, CusFeSs 61.79 25.8 11.7 Tetrahedrite, 4CuS8Sb2S3 (variable) 26.50 Sb' 36.40 26.7 1.39 Enargite, Cu3AsS4(As.l9.1) 48.4 32.5 Cuprite, CusO. 88.8 Melaconite (tenorite), CuO 79.86 Malachite, 2CUO+CO2+H2O 57.4 Azurite, SCuO+COj+HaO 55.0 Chrysocolla, CuO+Si02+2H20 36.1 2.04.02. Example 16, Continued. Pyrite or pyrrhotite beds (veins), with intermingled chalcopyrite. Whether the deposits are true beds or veins parallel with the stratification is as yet a matter of dispute. The resemblance to magnetite argues a bed, and this view is generally taken by German writers. The Cali- fornia mines occur closely associated with the auriferous (pyritous) quartz bodies, which are always esteemed veins. The interbedded lenticular deposits are placed by themselves as the main example. The undoubted veins like Ore Knob, N. C, are then made a sub-example. Pyrites and pyrrhotite (called mundic by the miners) are the principal constituents of such bodies, but often the copper reaches 4 to 5%, and then they are valuable for copper. The ores are often roasted for sulphurous fumes in acid works, and afterward the residues are returned to the copper smelters. They have been or are being worked for this metal at Capel- ton, Quebec, just north of Vermont. At Milan, N. H., there are several deposits in argillitic schists, and in the same region are numerous other locations. At Vershire, Vt., there is a belt some COPPER. 161 twenty miles long with three principal mining points. Of these the middle one, containing the Ely mine, is the largest. Two beds of ore occur, separated by from 10 to 20 feet of schists. The lower averages about four feet, but fluctuates; the upfiev is still more variable, and may reach 25 feet. They are both formed by a succession of thin lenses. The ore is chalcopyrite, mingled with pyrrhotite and quartz. At Ducktown, Tenn., which is in the ex- treme southeast corner of the State, there are three ranges of ore hills in a width of a mile. The outcrop is marked by great masses of gossan, and below this, and along the contact with the sulphides, was found the rich black ore which gave the early impetus to the mines. When this was exhausted the sulphides alone remained. They consist of chalcopyrite and pyrrhotite, with considerable quartz and country rock, less often calcite. (See Fig. 7, p. 39.) 2.04.03. Example 16a. OreKnob, N. C This is described by Kerr as a true fissure vein, extending 2000 feet on the strike, which is parallel to that of the gneiss, but cutting the dip in descent. The width averaged about 10 feet. The gossan extended to a depth of 50 feet, and furnished the usual body of rich ore at the contact with the sulphides. It has not been operated for some years.^ 1 J. T. Bailey, " The Copper Deposits of Adams County, Pennsyl- vania," Engineering and Mining Journal, Feb. 17, 1883, p. 88. H. Cred- ner, "On Ducktown, Tenn.," B. und H. Zeit., 1867, p. 8. Engineering and Mining Journal, Nov. 6, 1886, p. 337 (contains " The Elizabeth Copper Mines, Vermont";) see also April, 1886. P. Fraser, "Some Copper Deposits of Carroll County, Maryland," M. E., IX. 33; " Hypothesis of the Structure of the Copper Belt of the South Mountain, Pennsylvania," M. E., XII. C. H. Henderson, "Copper Deposits of the South Mountain, Pennsylvania," M. E., XII. 85. C. H. Hitchcock, Geol. of N. H., Vol. III., Part III., p. 47. H. M. Howe, "The Copper Mines of Vermont," M. E., February, 1892. T. S. Hunt, "Ore Knob and Some Related Deposits," M. E., II. 135. Kleinschmldt (on Virginia, Tennessee, and North Carolina), Gangstudien, Vol. III., p. 356. (Agood, short, but oldaccount.) E E. Olcott, " Ore Knob Copper Mine and Reduction Works," M. E., III. 391. Rho. Richardson, ' Copper Ore of Stafford, Vt., Amer. Jour. Sci., I. 31, 383. Tripple and Credner, "Report on the Ducktown Region to the American Bureau of Mines," 1866. M. Tuomey, "A Brief Note of Some Facts Connected with the Ducktown (Tenn.) Copper Mines," Amer. Jour. Sci., II. 19, 181. A. F. Wendt, " The Pyrites Deposits of the AUeghanies," School of Mines Quar- terly, Vol. VII., 1886 ; Engineering and Mining Journal, July 10 and fol- lowing, 1886. Rec. H. A. Wheeler, "Copper Deposits of Vermont," School of Mines Quarterly, Vol. IV., 319. Rec. 163 KEMPS ORE DEPOSITS. 2.04.04. Example 165. Spenceville, Cal. Beds of pyrites witli considerable chaloopyrite, in Jurassic slates, on the western slopes of the Sierra Xevada. The Jurassic slates along the western Sierras contain, in the gold belt, some mterbedded deposits of j)y- rite with considerable chaloopyrite intermingled. The most im- portant are at Newton, Amador County, Copperopolis and Campo Seco, Calaveras County, and Spenceville, Nevada County. At the first named there is a body of sulphides 7 to 8 feet wide and proved about 400 feet. In the adjoining county of Calaveras, the Union mine, at Copperopolis, is on a very large body of sulphides, which impregnate the slates on each side without forming a very sharp foot or hanging wall. The Campo Seco deposits are on the same general line as the Copperopolis. The extension passes also through those at Newton. A long distance north are the mines in Spenceville, Nevada County. The general geology is similar, and the ore body large. It affords from 3.50 to 5.50^ copper. All these ores are worked by wet methods.' Note. — For Examples 16c and I6cl see under "Nickel." 2.04.05. Example 17. Butte, Mont. Veins originally fissures, or shear zones, but greatly enlarged by replacement of the walls with ore, filled with copper sulphides, bornite, chaloopyrite, etc., in a siliceous gangue. Much silver is associated with the copper. At Butte there is a north and south valley six miles wide between high granite ridges on the east and lower rhyolite ridges on the west. The bounding heights north and south are still farther distant. Near the middle of this valley the butte of rhyolite arises which gives the town its name. Silver Bow Creek, which gives the name to the county, flows south along the eastern ridge and then bends westward at a point south of the butte, and, after flowing directly across the valley, leaves it through the western ridge. In the half of the valley east of the meridian of the butte is a very dark basic granite, and also in the extreme west. It consists of quartz, orthoclase, piagiocla.se, and an unusual amount of mica, augite, and hornblende. In the part west and south of the butte is a highly 1 J. E. Ellis, "Oq the Speuceville Mines," Mineral Resources V. S., 1884, p. 340. H. G. Hanks, Rep. California State Mineralogist, 1884, p. 148. J. B. Hobson, "On Spenceville," Rep. California State Mineral- ogist, 1890, p. 892. William Irelan, Jr., "On Calaveras County Mines," Rep. California State Mineralogist, 1888, pp. 150-158. "On the Newton Mines,'' ibid., p. 106. COPPER. 163 acidic, light-colored granite, which consists of quartz and ortho- clase feldspar with a very little biotite. Dikes of quartz porphyry penetrate the basic granite, and dikes of rhyolite are also found associated with the ore bodies. Tongues of rhyolite are met, ap- parently offshoots of the butte. 2.04.06. East of the butte and In the basic granite are found the older mines along two strongly contrasted east and west zones. A second, later-developed, group is west of the butte in the acidic granite. Of the former, the southern affords argentiferous copper ores, consisting of chalcocite, bornite, chalcopyrite, enargite, and pyrite in a siliceous gangue. The northern zone contains silver ores, chiefly sulphides of silver, lead, zinc, and iron, in a siliceous gangue with much rhodonite. Strangely enough, hardly any cop- per occurs in the silver zone, and no manganese is met in the copper zone, except in the Gagnon vein, which also contains zinc. The silver zone is mentioned again under " Silver." The zone west of the butte is silver-bearing with manganese. The occurrence of these two parallel systems of fissures in the same country rock and not far from each other, yet filled with such contrasted ores, is a very remarkable phenomenon and points to different and — at least for one of them — deep-seated sources of the ores. The copper-bearing zone begins on tlie west with the Gagnon claim and runs eastward through the Original and Parrott. The surface rises in a hill along this course, and the system of veins with a jog to the north continues up-hill across the Anaconda and St. Lawrence to the Mountain View on the summit. Thence it passes down-hill through the Shannon, Colusa and Hattie Harvey. The topography had an important influence on tlie character of the veins when first exploited^ for wliile in the lower lying claims (Gagnon, Original, Colusa and Hattie Harvey) the copper sulphides were near the surface, because the water line was not far down, in the claims on the hill (Anaconda and Mountain View) tlie upper 400 feet were practically leached of copper. The silver was however left behind, as is the usual experience, so that the vein was first mined as a silver-bearing vein. When the shafts reached the zone of enrichment, they penetrated the immense masses of bornite and chalcocite as much as 200 feet thick and 150 feet across. These ores yielded up to bQfo or more of copper and were the ones which gave the immense impetus to the copper mining in Butte. The similar geological relations at Ducktovvn, Tenn., (see Fig. 7 — 1.05.06) are worthy of remark. Below the zone of enrichment the ore is chang- 164 KEMP'S ORE DEPOSITS. ing to the usual pyritous aggregate, and will of necessity yield a lower percentage of copper. (The yield averaged about 5.5^ in 1893.) It is a curious fact that the oxidation of the upper ores yielded al- most no carbonates, for the ores in the zone of enrichment were higher in sulphides than the original vein filling. It would seem from this to be a general experience that the carbonates form most readily when the original sulphides are in limestone, whereas, when granite or some similar crystalline rock constitutes the walls, chal- cocite or bornite results. The Arizona copper deposits are cases in point (see 2.04.19). In the Moreuci district the Longfellow Mine in limestone yielded oxides and carbonates, while the Metcalf and Coronado groups in porphyry, and the veins near Chase Creek, in granite, yielded chalcocite. Besides the chief veins at Butte, which furnish the largest amounts of ore and are worked by the largest companies, there are smaller side ones, whose aggregate is by no means unimportant. The principal operators of the district are the Chambers syndicate, the Boston and Montana and the Bntte and Boston. The ores from the western end of the system of veins have proved richest in silver. The productive ground stretches about two miles from east to west and furnishes thus a remarkably extensive series of ore bodies, whose eastern limit has been found foufl^ further from the center than was at first suspected. The ores have been for the most part concentrated when necessary and smelted to a matte in Butte. The subsequent refining has been done in the East or in Europe, but lately large works have been erected at Great Falls, Mont., by the Boston and Montana Co., and the entire refining is contem- plated. 2.04.07. The ore bodies do not, in general, present very sharply defined walls, but the ores fade into the wall rock. From this S. P. Emmons has suggested that they have formed along a series of small fissures marking some line of disturbance, and not from a general faulting, and have enlarged the original channels by re- placement of the walls. It would seem probable that the frequent dikes are connected with the butte, or with the same parent body that sent it oif. The same eruptive activity probably shattered the rock along the zones. In this event it must have been from an easterly offshoot of the western rhyolite area, and have operated with the same Assuring action which attends earthquakes from the intrusion of subterranean dikes. The Butte district alone rivals the Lake Superior copper mines in output, and has in recent years COPPER. 165 surpassed them. Reference will again be made to this regiotij under "Silver." i 2.04.08. Example iVa. Gilpin County, Colorado. Veins of pyrite and chalcopyrite, replacing gneiss (tlie rock may be granite), and dikes of quartz-porphyry, and felsite along the planes of joints, which cross the gneiss (or granite) perpendicularly to the laminations. The veins are highly auriferous and are worked primarily for gold, the copper being produced as a by-product. The concentrates from the stamps are afterward treated for cop- per. The veins occupy an area of only about a mile and a half in diameter, centering about Central City. They show little indica- tion of filling a fissure, as usually understood, but follow the cleav- FlG. 37. — Cross section of the Bob-tail mine. Central City, Colo. After F. M. EndUich, Hayden's Survey, 1873, p. 386. age joints of the gneiss and replace the country rock on each side of them. The joints also cross the porphyry dikes, and the veins are often in the latter rock. They are closely related in structure and origin to the galena veins of the neighboring Clear Creek 1 "Butte Copper Mines," Engineering and Mining Journal, June 19, 1886, p. 445 ; also April 34, 1886, p. 399. S. P. Emmons, ' ' Notes on the Gteology of Butte, Mont. ," M. E., XVI. 49. Bee. Richard Pearce, ' ' The Association of Minerals in the Gaguon Vein, Butte City, Mont. , ' ' M. E. , XVI. 68. "On the Occurrence of Goslarite in the Gag non Mine, Butte City, ' ' Proc. Colo. Sci. , Vol. II. , Part I. , p. 13. E. D. Peters, Mineral He- sources of the U. S., 1888-84, p. 374. A. Williams and E. D. Peters, "On Butte, Mont.," Engineeriny and Mining Journal, March 23, 1885, p. 208. G. vom Rath, ' ' Ueber das Gangrevier von Butte, Mont. , ' ' Neues Jahr" buck, 1885, I. 158. 166 KEMP 'S ORE DEPOSITS. County, which are referred to under " Silver," but the contrast in mineral contents between the two is very marked. They were the basis of the first extensive deep mining in Colorado, and were located through the placer deposits in the neighboring gulches, i 2.04.09. Example 176. Llano County, Texas. Impregnations in granite, and veins with quartz gangue in granite, carrying car- bonates above, but sulphurets and tetrahedrite with some gold and silver below. Contact deposits between slates and granite are also known. It is not demonstrated as yet whether the ores are to be actually productive. ^ 2.04.10. Example 18. Keweenaw Point, Mich. Native cop- per, with some silver, in both sedimentary and interstratified igneous rocks of the Keweenawan system. The metal occurs as a cement, binding together and replacing the pebbles of a porphyry conglomerate ; or filling the amygdules in the upper portions of the interbedded sheets of massive rocks ; or as irregular masses, sometimes of enormous size, in veins, with a gangue of calcite, epi- dote, and various zeolites; or in irregular masses along the contacts between the sedimentary and igneous rocks. I 2.04.11. The rocks of the Keweenawan system are most strongly developed on the south shore of Lake Superior, especially in Keweenaw Point, which juts out northeasterly, cutting the lake into two nearly equal portions. They extend some distance east and west and are also known on the north shore. They consist of sandstone and thin beds of conglomerate, interstratified with sheets of diabase, both compact and amygdaloidal, and of melaphyre. They are succeeded on the east by the Eastern Sandstone, which on the south shore in some places abuts uncomforraably against them, and in others passes under them from an overthrust fault. The Eastern Sandstone forms a comparatively low flat bench some miles across between the lake and the ridge of the Kewee- nawan, whose rocks rise quite abruptly in a marked fault-scarp. The several streams that fall over this scarp in cascades have served 1 S. F. Emmons, Tenth Census, Vol. XIII. , p. 68. The veins are de- soritied as cited above. J. D. Hague, Fortieth Parallel Survey, UI. , p. 493. The veins are called fissure veins by Mr. Hague. A. Lakes, Ann. Pep. Col. State School of Mines. 1887, p. cii. A. W. Rogers, "The Mines and Mills of Grilpin County, Colorado, ' ' J/. E. , 11. 39. Further references will be found under ' ' Silver and Grold iu Colorado. ' ' 2T. B. Comstock, First Ann. Rep. Texas Geol. Survey, 1889, p. 334. W. H. Streeruwitz, in Mineral Resources of the U. S., 1884, p. 342. 168 KEMP'S ORE DEPOSITS. by thrsir erosion to expose the coutacts. The best known are the Hungarian and Douglas Houghton Elvers. On the west or north- west side the escarpment is much less pronounced and the contact is less well shown and has not been so sharply located. The sand- stone is called the Western Sandstone. It is now pretty well shown that the Eastern Sandstone is a close equivalent to the Potsdam, for though itself lacking in fossils it is known to pass conformably be- neath fossiliferous Lower Silurian limestone near L'Anse. On Keweenaw Point the beds dip northwesterly and pass under Lake Superior to reappear with a southeasterly dip on Isle Rovale and the Canadian shore. Western Lake Superior occupies this synclinal trough. In Keweenaw Point the dip is greatest on the southwest, being about 60° at Hancock. To the northeast it gradually flattens to 30° or less on the lake shore. (E'or the general geology of the neighboring region see under Example 9.) It is interesting to note that the early investigators of the geology of this country drew a parallel between the sandstones and traps of Lake Superior and the similar Triassic deposits of the Atlantic coast (see Example 21), even going so far as to regard the former as the western equivalent of the latter.^ There are three principal mining districts — the Keweenaw Point, on the end of the Point ; the Portage Lake, in the middle ; and the Ontonagon, at the western base. Mines have also been worked on Isle Royale, and copper is found in small amounts on the north shore. The Portage Lake district is now the princi- pal and almost the only producer. In the first-named district most of the mines are on original fissures, which have later become much enlarged by the alteration of the walls. They are usually from 1 to 3 feet broad, but may reach 10, 20, and 30 feet, this last in the looser textured rocks. These expansions are also richer in copper. The veins stand nearly vertical and cross the beds at right angles. They were the earliest discovered and the first to be ex- tensively worked. The metallic masses, both large and small, occur distributed through the gangue. The best known mines of the district are the Central, Cliff, Phcenix and Copper Falls. All these are now closed, the Central being the last to succumb (1894). A bed of conglomerate cut off the fissure and appears to have thrown the vein to some inaccessible point. Tlie other vein mines in the prevailing low price of copper (189-1) cannot be profitably 1 C. T. Jackson, Amer. Jour. Sci. , i. , XLIX. , 1845, pp. 81-93. COPPER. 169 worked. The yein mines have been the great source of fine minerals in the past, the Phoenix being well known for its zeolites. 2.04.12. In the Portage Lake district the mines are either in conglomerate (Calumet and Hecla, Tamarack, Peninsula, etc.) or in amygdaloidal, strongly altered diabase, certain very scoriaceous sheets of which are known as ash-beds (Quincy, Franklin, Atlantic, etc.). In the conglomerates the copper has replaced the finer frag- ments, so as to appear like a cement, and often the boulders them- selves, or particular minerals in them, are permeated with copper. The rich portions are of limited extent along the strike as they give way to barren rock, after a stretch it may be of several thou- sands oi feet, and they go down as great chutes somewhat diag- onally on the dip to very great depths. The Tamarack workings, below the Calumet and Hecla have been pushed on the bed nearly a mile below the outcrop and show no diminution or essential change in the copper rock. Three copper-bearing conglomerates have been identified, the Calumet and Hecla, the Albany and Bos- ton (also called the Peninsula) and the Allouez. The first is much the richest but has not been found productive at any other point on the strike, than in the great mine which gives it its name. The Amygdaloids have copper in their small cavities, but in the open or shattered rock it fills all manner of irregular spaces, often in fragments ot great size. It is associated with calcite, the zeolites (often of great beauty), epidote, and chlorite, (the last containing FcjOj). The distribution of the copper in the amyg- daloidal sheets is much the same as in the conglomerates. It is limited along the strike, and goes down at a slight diagonal in great chutes whose ends have never yet been reached. This ar- rangement must have an important bearing on the method of origin. 2.04.13. In the Ontonagon district the copper follows planes approximately parallel to the bedding of the sandstones and igneous rocks, and in one case at least (the National mine) along the con- tact between the two. The copper is quite irregular in its distri- bution, but has the same associates that are mentioned above. On the Origin of the Copper. — The original source of the copper was thought by the earlier investigators to be in the eruptive rocks themselves, and that with them it had come in some form to the surface and had been subsequently concentrated in the cavities. Pumpelly has referred it to copper sulphides distributed through the sedimentary, as well as the massive rocks from which the circulating waters have leached it out as carbonate, silicate, 170 KEMP '8 ORE DEPOSITS. and sulphate. Althougli the traps are said by Irving to be devoid of copper, except as a secondary introduction, it -would be interest- ing to test their basic minerals for the metal in a large way, as has been so successfully done by Sandberger on other rocks. It is probable that these may be its source. Irving states that the coarse basic gabbros of the system con- tain chalcopyrite, but they do not occur near the productive mines. The electro-chemical hypothesis of deposition was earliest advo- cated (Foster and Whitney), and on account of the electrolytic properties of the two metals copper and silver, at first thought it has strong claims to probability. Still the unsatisfactory charac- ter of all experiments made in other regions to detect such action militates against it. Pumpelly, however, has worked out an ex- planation much more likely to be the true one. He found, on studying the mineralogical changes which have taken place in the rocks, that the alteration had been very extensive ; that it had proceeded through a series of minerals involving at one stage a change in the iron present from protoxide to sesquioxide (which would occasion a reducing action), and that at this stage the cop- per was deposited. As stated in mentioning the great chutes above, the circulations must have followed the general lines indi- cated by them, and we are justified in thinking that the rich cur- rents were of limited extent. The progress of mining will be watched with interest to see if the native copper ever passes in depth into sulphides. A little whitneyite and domeykite (copper arsenides) and chalcocite occur in the amygdaloid, formerly worked at the Huron mine, chalcocite has been found in the Bohemian Mountains, and in the Copper Falls mine. Native copper changes to chalcocite, 90 feet down in the Mamaisne mine, near the Sault (L. L. Hubbard). A pocket of melaconite, the black oxide, was opened in the early days at Copper Harbor. 2.04.15. The discovery of copper dates back to the explorations of the French, who in the seventeenth century left the settlements on the lower St. Lawrence and penetrated the Great Lakes. The country was the scene of a great mining excitement in the forties. After many vicissitudes and exploded schemes the district settled down to the largest production of any American region. Within the last few years, however, Butte, Mont., has temporarilv ex- ceeded it. Many interesting traces of prehistoric mining were found by the early explorers, for the copper was a much prized commodity among the aborigines. COPPER. 171 2.04.16. Some important mining for copper has been done on Isle Koyale, along the Canadian shore, and in Minnesota, but al- though Keweenawan rocks are in great force, no large amount of the metal has been found. * 2.04.17. Example 19. St. Genevieve, Mo. Beds of chalco- pyrite associated with chert in magnesian limestone of the Cam- brian system. St. G-enevieve is situated on the Mississippi, about forty miles south of St. Louis. The Second Magnesian Limestone of the Cambrian outcrops, with the Carboniferous on the north, and more or less Quaternary in the vicinity. There are two nearly horizontal beds of ore, of widths varying between three ' It would be impos-ible and undesirable to give in this place com-- plate references to the literature. Such bibliography will be found in Irv- ing's monograph, and in Wadsworth's. The more important papers are given below, with some additions to the lists mentioned above. Blake, W. P., "Mass Copper of the Lake Superior Mines," etc., M. E., IV. 110. Credner, H., On the geology, etc., Neues Jahrbuch, 1869, p. 1. Engineering and Mining Journal, ' ' History of Copper Mining in the Lake Superior District," March 18, 1883, p. 141. Foster and Whitney, Report on the Lake Superior Copper Lands, 1850. Hall, C. W., "A Brief History of Copper Mining in Minnesota," Bull. Minn. Acad. Nat. Sci., Vol. III., No. 1, p. 105. Irving, R. D., " The Copper-bearing Rocks of Lake Superior," Monograph v., IT. S. Geol. Survey, especially p. 419. Rec. Jackson, C. T., "The Great Copper-bearing Belt of Canada," Boston Soe. Nat. Hist., IX. 203. LawsoD, A. C, "Note on the Occurrence of Native Copper in the Animi- Ide Rocks of Thunder Bay," Amer. Oeol., V. 174. Poole, H., " Michipicoten Island and its Copper Mines," Engineering and Mining Journal, Aug. 6, 1893, p. 125 ; Sept. 3, p. 220. Pumpelly, R., Oeol. Survey of Mich., 1873, Vol. I. " On the Origin of the Copper," Amer. Jour. Sci., iii.. III. 183-195, 348- 353, 347-353. Rec. A later and fuller paper is in Proc. Amer. Acad., 1878, Vol. XIII., p. 333. Wadsworth, M. E., Notes on the Geology of the Iron and Copper Districts of Lake Superior. Cambridge, 1880. Whitney, J. D., " On the Black Oxide of Copper of Lake Superior," Proc. Boston Soo. Nat. Hist., January, 1849, p. 103 ; Amer. Jour. Sci., ii., VIII. 373. Metallic Wealth in the United States, p. 345. Rec. Whittlesey, C, "On Electrical Deposition," A. A. A. S., XXIV. 60. Wright, C. E., and Lawson, C. D., Mineral Statistics of Michigan. An- nual. 172 KEMP'S ORE DEPOSITS. inches and several feet. They lie between chert seams and are associated with clay and sand. The ore is thought by Nicholson to have been deposited in cavities formed by dolomitization, much ^ 2nd._MagDesian Limeston* Roof Limestone ,> Chert seams Sulphuret ore ^^^ Fioor 2nd. Magnesian Lrmestooa Fig. 39, — Cross section in the St. Genevieve copper mine, illustrating the relations of the ore. After F. Nicholson, M. E, X., p. 450. as is advocated by Schmidt for the lead and zinc deposits of south- west Missouri, and as is described under Example 25. For ten years the mines have not been operated.' Limestone Fig. 40. — Section at the St. Genevieve mine, illustrating the intimate re- lations of ore and chert. After F. Nicholson, M. E., X., p. 451. 2.04.18. Example 20. Arizona Copper. Bodies of oxidized copper ores in Carboniferous limestones, associated with eruptive rocks. In addition to these, which are the most important, are ' F. Nicholson, "Review of the St. Genevieve Copper District," M. E., X. 444:. B. F. Shumard, " Observations on the Geology of the County of St. Genevieve, Missouri," Trans. St. Louis Acad. Sci., Vol. I., p. 40 ; ab- stract in Amer. Jour. Sci., ii., XXVIII. 126. COPPER. 173 veins in eruptive rocks, or in sandstones, or ore bodies of still different character as set forth under the several sub-examples. The copper districts are nearly all in the southeastern part of the territory, but the Black range is near the center. 2.04.19. Example 20a. Morenci. The Morenci district, known also as the Clifton or Copper Mountain, lies in a basin, six to ten miles across, whose high surrounding hills consist of limestone. Fia. 41, — Geological map of the Morenci or Clifton copper district of Arizona. After A. F. Wendt, M. E. probably Lower Carboniferous, which rests on sandstone, and this on granite. The principal mines are grouped about the town of Morenci. Clifton is seven miles distant at the point where the smelter of the Arizona Copper Company is located. In the basin is a mass of por- phyry, containing frequent great inclusions of limestone. Felsite or porphyry dikes are also abundant in the surrounding sedimentary and granite rocks. Several miles to the east there is an outflow of late trachyte and evidence of recent volcanic action. From this it appears that eruptive phenomena are abundant and widespread. 174 KEMP'S ORE DEPOSITS. 2.04.20. The ores are classified by Henrich as follows : 1. Contact deposits. These occur in a zone of decomposed and teHOFELtOW H LV Fig. 42. — Vertical section of Longfellow Hill, Clifton district, Arizona. After Wendt, M. E., XV. 53.; Fig. Ad.Sorizontal sections of Longfellow ore body. After Wendt. kaolinized porphyry, between a bluish, fine-grained limestone, and solid porphyry. Many ore bodies, and probably the largest, are COPPER. 175 directly on the limestone, while others are surrounded by the de- composed porphyry. As included masses of limestone, with as- sociated ore, are found in the decomposed porphyry, it is probable that these ore bodies may have originally replaced such. The ores are malachite, azurite, cuprite with some metallic cojaper and melaconite, in a gangue principally of limonite. Wad is also frequent. Much clay of a residual character occurs with the ores. 2. Deposits in limestone. These are closely associated with ^^* *"*:** **%» Fig. 44. — Geological section of the Metcalf mine, Clifton district, Arizona. After Wendt. the first class, and have apparently formed as outlying bodies in the limestone, as they are connected by ore channels with the principal lines of circulation along the contact. They appear to contain more wad and lime than the typical contact de- posits. 3. Deposits in porphyry. These form sheets and pockets in porphyry, or impregnate the solid rock itself. They are oxidized at the surface, but pass in depth into chalcocite. The principal gangue is kaolinized porphyry. According to Wendt, the Coronado vein fills a longitudinal fissure in a quartz porphyry dike. It afforded chalcocite above, 176 KEMP'S ORE DEPOSITS. but passed into chalcopyrite below^. Wendt also mentions a group of veins in granite that likewise afforded chalcocite.' 2.04.21. Example 20b. The Bisbee district, called also the Warren district, is situated in the Mule Pass Mountains in southern Arizona, near the Mexican line. The range runs east and west and consists of beds of Lower Carboniferous limestone, dip- ping away from a central mass of porphyritic rock. The ores are found in the canons on the south side, which have been formed by erosion, along the contact of the limestone and porphyry. They are of the same oxidized character as at Morenci, and in the H 'Ar-x < X + y + ERUPTIVE ROCK •*> » -(.J, ERUPTIVE ROCK X , Fig. 45. — Section of Copper Queen ore. body Bisbee district, Arizona. After A. F. Wendt, M. E., XV, 52. important mines occur in the limestone. The ore-bearing solutions seem to have spread out chiefly along the bedding planes and to have replaced the limestone at a distance from the contact. The ore bodies leave great chambers when excavated and partake of the nature of bedded veins. Empty caves occur associated with 1 J. Douglass, " Copper Resources of the United States,'" M. E., Sep- tember, 1890. Reo. " Arizona Copper and Copper Mines," Engineering and Mining Journal, Aug. 13, 1881, p. 103. " Clifton Copper Mines of Ari- zona," Ibid., Feb. 21, 1880, p. 183. C. Henrich, " The Copper Ore Deposits near Morenci, Ariz.," Ibid., March 26, 1887, pp. 202, 219. Reo. ■ A. Wendt, " Copper Ores of the Southwest," M. E., XV., p. 23. Rec. i ■ r Jl. ' -: i ?r "5) o ^ o; 178 KEMPS ORE DEPOSITS. them, doubtless formed, as at Eureka, Nev. (Example 36), by surface waters and having no genetic connection with the ore. Evidences of hydrothermal action along the contact are abundant. The Copper Queen and the Arizona Prince are the principal mines. There are minor deposits in the porphyry of oxidized ores above, changing to chalcocite and this to chalcopyrite in depth. ^ 2.04.22. Example 20c. Globe District. As in the other dis- tricts, the most productive mines are in limestone near the contact with eruptive rocks. 1. Contact deposits in limestone. At the Globe mines the Carboniferous limestone abuts against a great dike of diorite, while trachyte and granite are near. Along the contact there is abundant evidence of thermal action in the kaolinized rock. The great bodies of oxidized ores are found on this contact and extend out into the limestone. The one on the Globe claim is described by Wendt as resembling a great chimney. 2. A fissure vein in sandstone, containing arsenical and anti- monial copper ores and known as the Old Dominion, was formerly worked. 3. Fissure veins in talcose slate and gneiss, and filled by a quartz gangue with bunches of malachite and azurite (New York and Chicago mines), and now no longer worked. 4. Numerous small veinlets forming a stockwork, in gneiss near a dike of diorite, which is crossed by a dike of trachyte. These are known as the Black Copper Group. The ores are too low grade for profitable exploitation. Of greater interest are the bodies of chrysocolla, found in the wash, down the hill from the outcrop of the veins, and evidently due to the superficial drainage of the stockworks. Similar bodies of ore, though not chrysocolla, were found at Rio Tinto, in Spain. ^ 2.04.23. Example 20cZ. Santa Rita District. Although in New 1 J. Douglass, " Copper Resources of the United States," M. E., Sep- tember, 1890. Rec. A. Wendt, " Copper Ores of the Southwest," M. E., XV., p. 52. Rec. ' J. Douglass, " Copper Resources of the United States," M. E. , Sep- tember, 1890. Rec. " The Globe District," Engineering and Mining Journal, April 9, 1881, p. S43. W. E. Newberry, " Notes on the Produc- tion of Copper in Arizona,'' School of Mines Quarterly, VI. 370. A. Trip- pel, " Occurrence of Gold and Silver in Oxidized Copper Ores in Arizona," Engineering and Mining Journal, June 16, 1883, p. 485. A. Wendt, " Cop- per Ores of the Southwest," M. E., XV., p. 60. COPPER. 179 Mexico, this district has much in common with those already mentioned. A great dike of felsite cuts limestones, and along the contact, as well as in the felsite itself, copper ores are found. 1. Contact deposits in limestone. These afforded the usual ox- idized ores, hut were not found to extend to any great depth, and while for a time productive, they were soon exhausted. 2. Deposits in felsite. These consisted of pellets and sheets of native copper in the dike itself, which were oxidized to cuprite near the surface. (Cf. Lake Superior amygdaloids. Example 13.) They were worked by the Mexicans in the early part of the pres- ent century.' 2.04.24. Example 20e. Black Range District. The mines of this region differ from those described above, and in some respects resemble the pyrite beds of the Alleghanies. (Example 19.) The ore occurs in one or more great fissure veins, along the contact of vertical slates with a great dike of porphyrite. The veins run com- pletely into the porphyrite and into the slate, and afford oxidized ores above, changing into chalcopyrite below. They contain con- siderable silver and gold, as well as arsenic and antimony. The principal mines are the Hampton and Eureka. They are situated in the valley of the Verde River, twenty miles east of Prescott.^ 2.04.25. Example 20/. Copper Basin. Beds of closely text- ured conglomerate and sandstone, resting on granite and gneiss, and having a cement of copper carbonates. Copper Basin lies about twenty miles southwest of Prescott, and is formed by a de- pression in greatly decomposed granite, which is traversed by numerous small veinlets of copper ores. The granite is pierced by j)orphyry dikes, and covered by the sedimentary conglomerates and sandstones into which its copper is thought by Blake to have partially leached and precipitated as a cement. Reference, by way of comparison, may be made to the Lake Superior conglomer- ates, in which, in part, the native copper serves as a cement.^ 1 A. F. Wendt, "Copper Ores of the Southwest," M. E., XV. 27. Wislizenus, " On the Santa Eita Mines : Memoir of a Tour in Northern Mexico, 1846-47," p. 47 ; Amer. Jour. Sci., ii., VI. 385, 1848. 2 J. F. Blandy, "The Mining Region around Prescott, Ariz.," Jf. E., XI. 386. G. K. Gilbert, "On the General Geology of the Black Mountain District," Wheeler's Survey, III., p. 35. A. R. Marvine, " Brief Details of the Verde Valley," Wheeler's Survey, III., p. 209. A. F. Wendt, " Copper Ores of the Southwest," M. E., XV. 63. Rec. » W. P. Blake, "The Copper Deposits of Copper Basin, Arizona, and Their Origin," M. E., XVII. 479. 180 KEMP'S ORE DEPOSITS. 2.04.26. There are numerous other copper districts in Arizona of minor importance or entirely undeveloped, but the examples above cited probably illustrate the occurrences quite fully. Those not referred to above are of sporadic development. Mention should also be made of the mines in Lower California, opposite Guaymas, a brief description of which will be found in "Wendt's paper.' Much copper is now met in depth at Leadville, Colo. 2.04.2V. Example 20^. Crismon-Mammoth, Utah. In the Tintic district, Juab County, Utah, are three great ore belts, in vertically dipping dolomitic limestone, as more fully set forth under "Silver" (Example 35a). One of these, the Crismon-Mam-" moth, contains ores that bear silver, gold, and copper in propor- tions of about equal value. They have been a very difficult mixture to treat successfully. Of late considerable copper has been produced, placing the ore deposits among those deserving mention. The Crismon-Mammoth vein or belt covers a maxi- mum width of 10 feet, and runs 500 feet on the strike, dipping 75° Tvest. The ores seem to have been deposited along the bedding planes, though often cutting across them. The productive por- -tions are found in richer chutes or chimneys, amid much low-grade material and gangue, and are of all shapes and sizes, from 25 feet in diameter, down. The Copperopolis is thought to be on the same belt, and is a neighboring location of similar geological structure and ores.^ 2.04.28. Sunrise, Wyoming. Oxidixed ores have been ex- ploited to some extent at the Sunrise mines, in the Laramie range, Wyoming, but were never of much importance. 2.04.29. Example 21. Copper ores in Triassic or Permian sandstone. They occur as oxidized ores, with native silver, and chalcocite in contact deposits in Triassic and Permian sandstones at their junction with diabase or gneiss, or as disseminated masses replacing organic remains. Copper ores are very common throughout the estuary Triassic rocks of the Atlantic coast, and although formerly much mined, they are now proved valueless, and of scientific interest only. 2.04.30. Example 21a. Contact deposits in sandstone at its 1 See also M. E. Saladin, "Note sur les Mines de Cuivre du Boles (Basse Californie)," Bull, de la Societe de Vlndustrie Minirale, 3 Serie, VI. 5, 283. 2 O. J. Hollister, "Gold and Silver Mining in Utah," M. E., XVI., p 10. D. B. Huntley, Tenth Census, Vol. XIII., p. 456. COPPER 181 junction with diabase. These include the New Jersey ores, vigor- ously worked before the Revolution. They consist of the carbon- ates, of cuprite and native copper, disseminated through sand- stone near the trap. The Schuyler mines, near Arlington, IST. J., and several other openings near New Brunswick, N. J., are best known. These Triassic diabases often sliow chalcopyrite, and it is probable that the copper came from this or from copper in the augite of the rock, in accordance with Sandberger's investigations. The deposits are unreliable, and except at a very early period have never been an important source of ore. 2.04.31. Example 215. Contact deposits in sandstones at the Fig. 47. — Cross section of the Schuyler Copper mine, New Jersey, trap; b, sandstone; c, shales; the black shading, copper ores. After N. H. Darton, U. S. Geol. Survey, Bull. 67, p. 57. a, junction with gneiss. A number of deposits were formerly worked of this character, especially at Bristol, Conn., and at the Perkiomen mine, Pennsylvania. The mine at Bristol, Conn., is a well-marked contact deposit, on the line between the Triassic sandstone and the schistose rocks. The contact runs northeast and southwest, has suffered great decomposition from mineral solutions, and has been largely kaolinized. A broadband of this decomposed material, 30 to 120 feet wide, lies next the sandstone and contains disseminated ore. Then follow micaceous and hornblende slates, often with horses of gneiss. The slates are much broken by movements that have formed cavities for the ores. It is reason- able to connect the stimulation of the ore currents with the neighboring trap outbreaks. Unusually fine crystals of chalco- 182 KEMP'S ORE DEPOSITS. cite and barite have made the mine famous the world over. While at one time a source of copper, for many years it has been unpro- ductive.' 2.04.32. Example 21c. Chalcocite and copper carbonates re- placing vegetable remains, etc., in the Permian or Triassic sand- stones of Texas, New Mexico, and Utah. In the Permian of iiorthei-n central Texas are three separate copper-bearing zones, forming three lines of outcrop that extend in a general north- easterly direction over a range of about three counties. The ore is largely chalcocite in beds of shale, and often replacing frag- ments of wood. It may be available in time.^ At various places in Utah and New Mexico (Abiquiu, N. M., Silver Reef, Utah) the sandstones, as reported by Newberry and others, have copper ores disseminated through them and deposited on fossils, at times with associated silver (Utah). The copper, "whether coming from the waters along the shore line or from sub- terranean currents, was precipitated by the organic matter. (See also under "Silver," in Utah.) These deposits are not yet sources of copper.^ ' L. C. Beck, " Notice of the Native Copper Ore*, Copper, etc., near New Brunswick, N. J.," Amer. Jour. Sci., i., XXXVI. 107. G. H. Cook, Geol. ofN. J., 1868, p. 675; also L. C. Beck, Ibid., 218-334. J. G. Percival, Rep. on Geol. of Conn., p. 77. C. A. Shaefler, "Native Silver in New Jersey Copper Ore," Engineering and Mining Journal, February, 1882, p. 90. C. Shepard, Geol. of Conn., 1837, p. 47. B. Silliman and J. D. Whitney, "Notice of the Geological Position and Character of the Copper Mine at Bristol, Conn.," Amer. Jour. Sci., ii., XX. 361. J. D. Whitney, Metallic Wealth. RtfC. * W. F. Cummins, "Report on the Permian of Texas and its Over- lying Beds," First Ann. Rep. Texas Geol. Survey, p. 196. J. F. Furman, " Geology oE the Copper Region of Northern Texas and Indian Territory," Trans. N. Y. Acad. Sci., 1881-83, p. 15. * F. M. F. Cazin, "The Origin of the Copper and SUver Ores in Tri- assic Sand Rock," Engineering and Mining Journal, April 80, 1880 ; Dec. 11, 1880, p. 331. "Tlie Nacemiento Copper Deposits,'' Ibid., Aug. 22, 1885, p. 124. A. W. JdcksoQ, Sep. Director of the Mint. 1880, p. 334. J. S. Newberry, "Copper in Utah, Triassic Sandstones," Engineering and Mining Journal, Vol. XXXI., p. 5. Also Oct. 23, 1880, p. 269; Jan. 1, 1881, p. 4. See also Tenth Census, Vol. XIII., Precious Metals, pp. 40, 478. C. M. Rolker, "The Silver Sandstone District of Utah," M. E., IX. 21. R. P. Roth well, Quoted in Tenth Census, Vol. XIII., p. 478. B. Silliman, " The Mineral Regions of Southern New Mexico," M. E., XVI. 437. COPPER. . 183 2.04.33. Copper production in 1882 and 1890, in tons of 2000 pounds each. 1883. 1890. LakeSuperior 28,578 50,373 Montana 4,529 56,490 Arizona 8,993 17,398 Colorado 747 441 New Mexico 434 485 California 413 11 Utah 303 503 Elsewhere , 1,413 3,906 45,408 139,546 The figures indicate in general a vast increase in production, and, above all, the advance of Montana. For detailed statistics the volume on " Mineral Industry " issued by the Scientific Pub- lishing Company (New York, 1894) is most available. CHAPTER V. LEAD ALONE. 2.05.01. The deposits of lead are treated in three different classes, according as they produce or have produced lead alone, lead and zinc, or lead and silver. Of late years the lead-silver ores have been the great source of the metal. Only the southeast Missouri region is of much importance among the others, although considerable lead is also obtained in association with zinc. LEAD SEPaES. Pb. S. Galena, PbS 86.6 13.4 Cerussite, PbCOj 77.5 Anglcsite, PbSO^ 67. 7 Pyromornhite, PbjPsOs + l/SPb.ClB 75.36 Earthy mixtures of these last three aad limonite. 2.05.02. Example 22. Atlantic border. Veins of galena in the Arcliean rocks of the States along the Atlantic border; also others into Paleozoic strata, as described in the sub-examples. 2.05.03. Example 22a. Veins in gneiss and crystalline lime- stone, sometimes with a barite or calcite gangue. These deposits were vigorously exploited forty years ago or more, but have since been of small importance other than scientific. They may be described best by districts, as they hardly deserve a greater prom- inence. 2.05.04. (1) St. Lawrence County, New York. Veins with galena in a gangue of calcite in Arcliean gneiss. Those near Rossie are perhaps best known, especially for their unusually in- teresting calcite crystals. There are numbers of veins in the dis- trict which are notable in that the galena is without zinc or iron associates. The lead carries a very small amount of silver, not enough to separate. Hornblende and mica schists occur in the same region and the Potsdam sandstone is not far removed. A few LEAD ALONE. 185 minor veins cut the Trenton limestone near Lowville, Lewis County, sometimes with fluorite for a gangue.' 2.05.05. (2) Massachusetts, Connecticut, and eastern New York. Veins of galena with more or less chalcopyrite and pyrite in a quartz gangue in gneiss, slates, limestones, or mica schists. The mines near Northampton, Mass., were formerly well known, although never productive of a great deal of metal ; but as there is a large, prominent vein, it attracted attention. There are nu- merous others in the same region. Veins also occur at Middle- town, Conn., -where much silver is said to be found in the galena. More recently {circa 1873) at Newburyport, Mass., argentiferous galena attracted attention, but was not of any importance. Other veins are known in Lubeck, Me., and in various parts of New Hampshire and Vermont. For a time small lodes in the slates of Columbia County, New York, were unsuccessfully exploited, of which the Ancram mine is of historic interest. Although these galena veins are numerous, they are not to be taken too seri- ously.^ 2.05.06. (3) Southeastern Pennsylvania. Veins on the con- tact of Archean gneiss and Triassic sandstone and diabase. These were referred to under Example 21 5. As noted by Whitne}', the copper is especially strong in the sandstone, and the lead in the gneiss. Trap dikes are abundant, and the eruptive phenomena in connection with them doubtless occasioned the activity of circula- tion which filled the veins. The Wheatley mine is best known. It has afforded a great variety of lead minerals, especially pyro- morphite. They have not been worked in years.^ 2.05.07. (4) Davison County, North Carolina. Veins in tal- cose slate were formerly exploited, but are now little known. ' L. C. Beck, Mineralogy of New York, p. 45. E. Emmons, "Geology of the Second District," N. Y. Geol. Survey, 1843. G. Hadley, "Crystal- lized Carbonate ot Lead at Rossie," Anier. Jour. Sci., ii., II. 117. F. L. Na- son, 'Calcite from Rossie," Bull. 4, N Y. State Museum, 1888, J. D. Whitney, Metallic Wealth. Rec. ^ C. A. Lee, "Notice of the Ancram Lead Mine," Amer. Jour. Sci., i., VIII. 247. A. Nash, "Notice of the Lead Mines and Veins in Hampshire County, Massachusetts," Amer. Jour. Sci., i., XII. 388. R. H. Richards, "The Newburyport Silver Mines," M. E., III. 443. J. D. Whitney, Me- tallic Wealth. « H. D. Rogers, Oeol. of Perm,., II. 701 ; also Amer. Jour. Sci., ii., XVI. 423. J. D. Whitney, Metallic Wealth, p. 396. 186 KEMP'S ORE DEPOSITS. except as having furnislied beautiful crystals of oxidized lead minerals.^ 2.05.08. Example 22b. Sullivan and Ulster Counties, New York. Veins along a line of displacement on the contact between the Hudson River slates and the sandstones of the Medina stage (Shawangunk grit), carrying galena and chalcopyrite in a quartz gangue ; or else gash veins filled with the same in the grit. These mines formerly produced considerable lead and copper, but are now best known for the excellent quartz crystals which they have furnished to all the mineralogical collections of this and other lands.^ 2.05.09. Example 23. Southeast Missouri. Galena accom panied by nickeliferous pyrite, disseminated through beds of the Third or Lower Magnesian limestone of the Missouri geologists, which is doubtless Cambrian in age. The mines are at Bonne Terre, Mine La Motte, and Doe Run, twenty-five miles west of the Mississippi River and forty to one hundred miles south of St. Louis. The strata lie almost horizontal, and are known to carry lead through over 200 feet in thickness. The productive places fade out into barren rock and appear to be local enrichments of the limestone, of which the galena forms an integral part. At Bonne Terre they are of enormous size, one working running 3000 feet, and being 100 to 200 feet broad and 25 to 60 feet high. No zinc, how- ever, occurs with the lead, and the silver contents are very small, being about four ounces to the ton of lead. _A.t Mine La Motte some copper is found, and considerable nickel and cobalt. The rare mineral siegenite, a variety of linnaeite, impregnates a sand- stone supposed to be the equivalent of the Potsdam. Pyrite accom- panies the galena both at Mine La Motte and at the other mines, and carries the nickel and cobalt, which is obtained as a by-product in the lead smelting. All the ore bodies are crossed by small faults, ad- joining which the rock is invariably barren. Knobs of Archean granite, containing diabase dikes, crop out near the mines both at Mine La Motte and at Doe Run. But the dikes never penetrate the limestone, and were evidently intruded before it was deposited. ' J. C. Booth, " Analyses ot Various Ores of Lead, etc., from King's Mine, Davison County, North Carolina," Amer. Jour. Sci., i., XLI. 348. W. C. Kerr, Oeol. of North Carolina, p. 289. 2 J. D. Whitney, Metallic Wealth. W. W. Mather, New York State Surrey, Report on First District, 358. LEAD ALONE. 187 The ore must have been deposited with the limestone or it must have been introduced since the latter was formed, and by the per- colation of ore-bearing solutions through the rock, with no marked fissure vein development. The first view has been advanced by J. F. Kemp (1887), it being thought that decaying marine vegetation had precipitated the ores from solution in sea-water, as is outlined for another region under Example 24, but this explanation has been practically disproved. W. P. Jenney has considered the ore to have come in ascending solutions through the small fault fis- sures referred to above, and from these to have spread outward, replacing the limestone (privately communicated). Places where several fissures cross are said to be specially favorable. It is a curious fact, however, that as the ore bodies are followed up to the faults they invariably become lean or run out. Their place of formation has apparently some connection, as recent explorations seem to indicate, with low folds at right angles to the faults. The ore bodies favor the anticlinal bends. This whole region of Cambrian and Lower Silurian rocks, over nearly 3000 square miles, contains lead, and within a year or so past some new mines, not yet under way (1892), have been started. These disseminated deposits are in no way to be confused with the mines of the Upper Mississippi in Wisconsin and Iowa. They are now large producers of lead and the only mines worked in the United States for lead alone. The ore affords an average of about eight per cent, galena. Except at Mine La Motte, lead was also obtained at this region, previously to 1865, from small gash veins like those of Example 24, but the workings were never in any de- gree commensurate with the present mines of disseminated ore. The history of Mine La Motte dates back to the early part of the eighteenth century, and it is said to have furnished lead for bullets used in the Revolution.' 2.05.10. The great increase in lead production in the United States came about 1880, with the opening of the Leadville ore 1 G. C. Broadhead, " The Southeastern Missouri Lead District," M. E., V. 100. Rec. J. R. Gage, " On the Occurrence of Lead Ores in Missouri," M. E., III. 116. Rec. Geol Survey of Missouri, 1873-74, pp. 30, 603. J. F. Kemp, "Notes on the Ore Deposits, etc., in Southeastern Missouri," School of Mines Quarterly, October, 1887. Rec. Several other papers have been published on the metallurgical treat- ment and methods of ore dressing in the Trans. Inst, of Mining Engineers and the School of Mines Quai terly. 188 KEMPS ORE DEPOSITS. bodies. From 1877 until 1881 Eureka, Nev., was an important source, but since then it has greatly declined. Utah has preserved a fairly uniform production since the early seventies. Lead from all sources is here mentioned, although lead-silver ores are sub- sequently treated. The amounts are in tons of 2000 pounds. For detailed statistics see the volume on " Mineral Industry." (New York : Scientific Publishing Company, 1893.) 1880. 1890. Missouri, Kansas, Wisconsin, Illinois 37,690 55,000 Colorado 35,674 60,000 Nevada 16,659 2,500 Utah 15,000 24,000 Idaho, Montana 34,000 Elsewhere 3,803 15,994 97,835 181,494 From 80 to 85^ of the total product is from lead-silver ores. Note. — "The Economic Gleology of Lead " is the title of a series of papers by Prof. H. A. Wheeler in the Colliery Engineer, Scranton, Penn. , during 1893. CHAPTER VI, LEAD AND ZINC. 2.06.01. Example 24. The Upper Mississippi Valley. Gash veins and horizontal cavities (flats), limited to the Galena and Trenton limestones of the Upper Mississippi Valley, and contain- ing galena, . zinchlende, and pyrite (or marcasite), with calcite, barite, and residual clay. The deposits are found in southwest Wisconsin, eastern Iowa, and northwestern Illinois. The greater portion of the productive territory lies in Wisconsin, and covers an area which would be included in a circle of sixty miles' radius, whose limits would pass a few miles into Illinois and Iowa. A low north and south geanticline runs through central Wisconsin dat- ing back to Archean times and called by Chamberlin " Wisconsin Island." On its western slope the Cambrian and Lower Silurian rocks are laid down, and these in the western limit of the lead dis- trict pass in the adjoining States under the Upper Silurian. They are folded also in low east and west folds, but in the aggregate the whole series dips very gradually westward. The chief east and west fold forms the south bank of the Wisconsin River, and may have been the cause that deflected it from a southerly course. The easterly part of the lead region is 350 feet higher than the western, and the northern is 500 feet above the southern. The general slope is thus southwesterly. 2.06.02. The Galena limestone is a dolomite reaching 250 feet in thickness. On the hilltops left by erosion Maquekota (Hudson River) shales are seen. The Galena has shaly streaks, which have largely furnished the residual clay of the cavities. There are also cherty layers and sandy spots. Under the Galena lies the Tren- ton, from 40 to 100 feet thick, and made up of an upper blue por- tion, which is a pure carbonate of lime, and a lower buff portion that is magnesian. The upper portion of the blue has a band of shale locally called the "Upper Pipe Clay," and the pure, crypto- crystalline limestone under this is called " Glass Rook." The blue 190 KEMP'S ORE DEPOSITS. contains mucli bituminous matter. The buff is locally called " Quarry Rook " and is prolific in fossils. Under the Trenton lies the St. Peter's sandstone, 150 feet below w-hich is the Lower Mag- nesian, 100 to 250 feet, and still lower the Potsdam, averaging VOO to 800 feet. The Potsdam rests on the quartzites and schists of the Archean. The ore beds especially favor the shallow, syn- clinal depressions of the east and west folds. They occur in crev- ices, the great majority of which run east and west. The pro- ductive ground comes in spots which are separated by stretches ^~Z^^{ '-"^^^^ -^Miiii ■^—Tlllli'- Fig. 48. — 0ash veins, fresli and disintegrated. The heavy black shading indicates galena. After T. C. Chamherliu, Qeol. Wis., Vol. IV., 454. of barren ground. The lead ores are chiefly produced by the crevices in the Upper Galena. In the Lower Galena the zinc ores become relatively more abundant, and they are also in the Tren- ton. The ores do not extend in any appreciable amounts either above or below these horizons. The upper deposits favor the ver- tical gash vein form ; the lower tend rather to horizontal open- ings, called flats, which at the ends dip down (pitches) and often connect with a second sheet (flat) lying lower. There are several m.inor varieties of those two main types of cavity, which mainly def)end for their differences on the grade of decomposition, which the walls have undergone, and whether there was an original open- LEAD AND ZING. 191 iug, or only a brecciated and crushed strii). Oliiimberlin cites twelve varieties in all, some of which are based on rather fine dis- tinctions. 2.06.03. The cavities were referred by J. D. Whitney to joints, formed either by the drying and consolidating of the rock or by gentle oscillations of the inclosing beds. The later work has largely corroborated this, and they are generally thought to be chiefly caused by the cracks and partings formed by the gentle synclinal foldings. Such cavities have usually been enlarged by subsequent alteration of the walls. Whitney also essentially out- lined the explanation of origin, which has been more fully elabo- p^ Galena ~l — timrstone i-. ^ Fig. 49. — Idealized section of '•flats and pi.tclies,^'' forms of ore bodies in Wisconsin. After T. C. Chambei-lin, Oeol. Wis. , Vol. 1 V. , jO. 458. rated by Chamberlin. Both these writers have urged that the ores could not have come from below, for the lower rocks are sub- stantially barren of them. The conclusion therefore follows that they were deposited in the limestones at the time of their forma- tion. The source of the ores is placed in the early Silurian sea, from which it is thought they were precipitated by sulphuretted hydrogen, exhaled by decaying seaweeds, or similar dead organ- isms on the bottom. In carrying the idea further, Chamberlin has endeavored to reproduce the topography of the region in the Lower Silurian times and to indicate the probable oceanic cur- rents. These are conceived to have made an eddy in the lead district and to have collected there masses of seaweed, etc., re- sembling the Sargasso Sea. While interesting, this must be con- sidered very hypothetical. When the sulphides became precipi- 192 KEMPS ORE DEPOSITS. tated they were doubtless finely disseminated in the rock and were gradually segregated in the crevices. The sulphurous exhala- tions from the bituminous limestones may have aided in their second precipitation. The paragenesis of the minerals shows the following succession : (1) Pyrite, (2) Galena, (3) Pyrite; or (1) Pyrlte, (2) Blende, (3) Galena, (4) Pyrite; or (4) Calcite. The ores, especially of zinc, are often oxidized, and afford considerable calamine and smithsonite. Some oxidized copper ores are pro- duced at Mineral Point, formed by the alteration of chalcopyrite. In the early mines lead alone was sought, but of late years the zinc has been produced in greater quantities and is more valuable than the lead. Dr. W. P. Jenney, whose work in the region of southwest Mis- souri is later referred to (2.06.07), has also written of these mines, and his views are quite different from those of any of the writers mentioned above. His investigations cover all the lead and zinc regions of the entire Mississippi Valley. The east and west fissures, already mentioned as crevices, are regarded as faulting planes. They are usually not far from the vertical, but in a few instances dip 35° to 45°. The smaller north and south series are considered to be due to the same cause, but to an earlier period of disturbance, as they are faulted by the east and west set. The latter exhibit but little vertical displacement, although some con- siderable horizontal. The ore is principally in and along the east and west fissures, but these seem to be locally enriched at their intersections with the north and south series. The deposits are described as runs ; that is, lateral enrichments along a fissure. The ores are thought to have come up from below through the chief fissures, and in this respect Dr. Jenney's views mark a return to the earlier ones of Percival. The solutions are said to have favored particular beds for the following reasons. The beds were cellular from long exposure to atmospheric agents, or they were chemically (being dolomitic) and physically of a nature to occasion it, or they were soft and permeable shaly beds.i (See also under 2.06.07.) * Wisconsin. J. A. Allen, " Description of Fossil Bones of Wolf and Deer from Lead Veins," Amer. Jour. Sci., in., II. 47. T. C. Chamberlain, Wis. Geol. Sur- vey, Vol. IV., 1882, p. 367. Rec. E. Daniels, " Geolog-y of the Lead Mines of Wisconsin," A. A. A. S., VII. 290; Engineering and Mining Journal, July 6, 13, 20, 27, Aug. 8, 10, 24, Oct. 5, 1878 ; Wis. Geol. Survey, 1854. LEAD AND ZINO. 193 Especial attention was direeted in the summer of 1893 to these and the other lead and zinc deposits of the Mississippi Valley. Ill addition to the paper of W. P. Jenney, earlier cited, W. P. Blake presented two.' Blake brings out the fact that PerciTal, the early State geologist of Wisconsin, had advocated the existence of faults, and that the later work is a confirmation of these, the ear- liest of all views. Although Percival's report is cited on a previ- ous page, his name is not bo generally associated with the geology of the Wisconsin deposits as those of his successors. The diffi- culties that have been met in detecting these geological dis- turbances, notwithstanding that the mines have been long and vig- orously worked, indicate what obscure phenomena they are. Blake, however, cites a case in the Helena mine, near Shullsburg, where mineralization occurs near a pair of faults. Blake also lays stress upon the presence of thin seams of a rich bituminous shale in layers usually about as thick as cardboard, which are present in a richly fossiliferous limestone at the top of the Trenton, just be- neath the ore-bearing "Galena" dolomite. 'So doubt these richly bituminous layers (locally called " oil-rock") are genetically con- nected with the precipitation of the ores as Blake mentions. It should be added that the region is unglaciated, and has, there- fore, been long exposed to atmospheric agents. In the general dis- cussion which followed the papers of Jenney and Blake great dif- erences of views were developed, and it must be admitted that to-day there is as little unanimity of opinion regard- ing the origin of these ores as in the past. The method of origin, whether from circulations, permeating the lower Silurian lime- stones themselves, and leaching them of disseminated galena and blende, and concentrating the ores in cavities, or from uprising solutions along fissures, has an important practical bearing as re- gards the future of the country. The latter view gives greater hope of lower lying productive horizons, but the old question raised by Percival, answered in the negative by Whitney and Chamberlin, and somewhat favorably regarded by Jenney and Blake, as to whether there are lower lying ore bodies in the Lower Magnesian limestone, is not yet solved by a deep shaft or boring. 1 W. P. Blake, "Tlie Mineral Deposits of Soutliwest Wisconsin," Trans. Amer. Inst. Min. Engineers, Chicago Meeting, 1893 ; Amer. Geol. , XII. 337 , 1893. ' ' Wisconsin Lead and Zinc Deposits, ' ' Bull. Oeol. Soc. Amer. V. 25, 1898. Attention shotild also be called to a previous paper, ' ' Progress of Geological Surveys in the State of Wisconsin ; A Review and Bibliography, ' ' Trans, Wis. Acad. Sci., LX. 335. 194 KEMP'S ORE DEPOSITS. 2.06.04. Example 24a. Washington County, Missouri. Gash veins in the Lower Magnesian limestones of eastern Missouri in the same region as the disseminated ores of Example 23, and con- taining galena, barite (locally called "tiff"), calcite, and residual clay. The cavities are described by Whitney as resembling in all respects the gash veins farther north, which, however, lie in rocks higher in the geological series. These mines were the earliest worked, but have been given up since the price of lead has been at present figures (1875 and subsequently). The ore was obtained from pockets, cave.3, irregular cavities, and from the overlying residual clays. This whole region has been exposed and above water since the close of Carboniferous times and has suffered enormous surface decay (see R. Pumpelly, Tenth Census, Vol. XV., p. 12, and Geol. Soc. Amer., Vol. II., p. 20), which has left a mantle of residual clay spread widely over its extent. In this, more or less float mineral occurred. The mines were located in Washington, Franklin, Jefferson, and St. Francois counties.' 2.06.05. Example 24S. Livingston County, Kentucky. Veins in limestone of the St. Louis stage of the Lower Carboniferous, containing galena in a gangue of fluorite, calcite, and clay. The James Hall, "Notes on the Geology of the Western States," Amer. Jour. Sci., 1., XLII. 51. J. T. Hodge, " On the "Wisconsin and Missouri Lead Re- gion," Amer. Jour. Sci., i., XLHI. 35. R. D. Irving, "Mineral Resources of Wisconsin," M. E., VIII. 478. E. James, "Remarks on the Limestones of the Mississippi Valley Lead Miues," Phil. Aoad. Sci., V., Part I., p. 51. J. Murrish, Report on the lead regions, 1871, as commissioner for their survey. D. D. Owen, "Report on the Lead Region," U. S. Senate Docu- ments, 1844. J. G. Percival, Wis. Geol. Survey, 1856. Squier and Davis, Historical account, Smithsonian Contributions, Vol. I., p. 208. M. Strong, Wis. Geol. Survey, 1877, 1. 637 ; II. 645, 689. J. D. Whitney, iris. Geol. Survey, 1861-63, 1. 231. Rec. Metallic Wealth, p. 408, 1856. " On the Oc- currence of Bones and Teeth in the Lead-bearing Crevices," A. A. A. S., 1859. Illinois. J. Shaw, Geol. Survey of Illinois, 1873, Vol. II., p. 840. J. D. Whit- ney, Geol. Survey of Illinois, 1866, Vol. I. 153. Iowa. C. A. White, Iowa Geol. Survey, 1870, Vol. II., p. 339. J. D. Whit- ney, Iowa Geol. Survey, 1858, Vol. I., p. 433. 1 Compare the older references under Example 33, and the following: A. Litton, Second Ann. Rep. Missouri Geol. Survey, 1854. J. D. Whitney, Metallic Wealth, p. 419. LEAD AND ZING. 195 ore bodies have never been well described and no very accurate diagnosis can be given. They are found in Livingston, Crittenden, and Cald-well counties, Kentucky, in that portion of the State lying south of the Ohio River and east of the Cumberland. While limestone always forms one wall, a sandstone of geological rela- tions not well determined forms the other. The veins run from two to seven feet wide and in instances are richer in their upper portions than in the lower. As yet they are of greater scientific than practical importance. Some galena occurs also in irregular cracks in the limestone. As a possible indication of a stimulating cause for the formation of the veins, the interesting dike of mica- peridotite may be cited, which has been described by J. S. Diller.^ The dike occurs in the same fissure with a vein of fluorspar.^ 2.06.06. Example 25. Southwest Missouri. Zincblende and very subordinate galena with their oxidized products, associated with chert, residual clay, calcite, a little pyrite and bitumen, in cavities of irregular shape and in shattered portions of Subcarbon- iferous limestone. Across Missouri, from a point south of St. Louis, and including the country as far to the northwest as Sedalia and Glasgow, a broad belt, called the Ozark uplift, extends southwesterly into Arkansas. It has formed a great plateau in central and southern Missouri and consists largely of Silurian rocks. These have a fringe of Devonian on the edges and dip un- der the Lower Carboniferous. The plateau reaches 1500 feet above the sea in Wright County, but on the limit is succeeded by lower country. To the southwest it drops somewhat, with Lower Car- boniferous strata outcropping, which in Kansas are overlain by the coal measures. The surface then rises again in the prairies. At the edge of the plateau is a trough, in whose bottom the Lower Carboniferous strata are cut by the Spring River, which flows southwesterly from Missouri across the western State line into Kansas and has a general direction parallel to the western limits of the uplift. It receives tributary streams on each bank, which cut the strata in strongly marked valleys and afford good ex- posures. Those on the east bank, from south to north, are Shoal ' " Mica-Perldotite from Kentucky,'' Amer. Jour. Sei., October, 1892. * S. F. Emmons, "Fluorspar Deposits of Southern Illinois," M. E., February, 1893. C. J. Norwood, " Report on the Lead Region of Living- ston, Crittenden, and Caldwell Counlies," Kentucky Oeol. Survey, 1875, New Series, Vol. I., p. 449. 196 KEMPS ORE! DEPOSITS. Creek, Short Creek, Turkey Creek, and Center Creek, while from the west come the Brush, Shawnee, and Cow creeks, all in Kansas. Along the first mentioned creeks the principal mining towns are situated, but others are found on the minor streams. They extend through an area fifteen miles broad from east to west and twenty- five miles from north to south. Newton and Jasper are the most productive counties in Missouri, while Cherokee County, in Kansas, also contains notable mines. Undeveloped districts are recorded in Arkansas, but apparently at a lower geological horizon. The ore occurs in the Keokuk or Archimedes limestone of the Lower Car- boniferous. A generalized section of the rocks, according to F. L. Clerc, is as follows. On the higher prairie, some 15 feet of clay or gravel ; 10 feet of flint or chert beds ; 40 ^feet of lime- stone with thin beds of chert ; 60 feet of alternating layers of limestone and chert; 100 feet and more of chert, sometimes chalky with occasional beds of limestone ; 225 feet in total. In basins and extensive pockets in these rocks, deposits of slates with small coal seams are found, of undetermined geological relations. The large bed of limestone of the section affords a datum of reference in relation to which the ores may be described. A few minor, shallow deposits occur in the flints over it. In the limestone the ores are associated with a gangue of dolomitic clay and residual flint. They occupy irregular cavities or openings, locally known as circles, spar openings, and runs. (Clerc.) Below the limestone the ore is found in " sheets, bands, seams, and pockets," and filling in the interstices of a breccia of chert, which has been formed by the breaking down of the chert layers on the solution and removal of the interbedded limestones. There are districts where the over- lying bed of limestone has also disappeared, and they then lack it for a capping. The deposits extend to considerable depths be- low the position of the limestone. The present mines have not demonstrated as yet their limit of depth. At times the ore is associated with a later formed quartz rock that has coated and filled the cavities of the breccia. 2.06.07. The removal of the interbedded layers of limestone and the caving in of the associated cherts have been the principal causes of the formation of cavities. Adolph Schmidt referred the shrinkage to the dolomitization of pure lime carbonate, an idea that has had extended adoption, and has also had an important part in causing the general porosit}'. Schmidt traced five periods in the geological history of the ore bodies: 1. Period of deposition LEAD AND ZINO. 197 of the rocks. 2. Period of dolomitization of certain strata and of principal ore deposition. 3. Period of dissolution of part of the limestone, of breaking down of chert, and of continued but di- minishing ore deposition. 4. Period of regeneration, secondary- deposition of carbonate of lime and quartz, and continued ore de- position. 5. Period of oxidation. Schmidt's work was done in 1871-72. Since then the increased / / I' • / ■ /••'"'/''///''' ' / ■' Pi'obable flint floor of '■J J v'^' J~J\J v' -J^'^'J-jJ^ y vV ^VVv/v-'v'V^A--^-'^-'^-^ --' ore.deposit. TvPTOAL ZINC-BLENDE ORE-BOOy NEAR WeBB CitY, Mo. VERTICAL SECTION. -^ ^ubcarboniferoua Limestone ^^^inc-blende ope-bodiee •^-•^•••' l^l'"* '•""='< ^^•2!^& Flint rock — ^ ^ — ^K« Galenite in fissures & beddin^ptanes in limestone Fig. 43. — Vertical section of a typical zincblende ore body, near Webb City, Mo. After C. Henrich, M. E., June, 1892. development of the mines has afforded greater opportunities for observation. Haworth, in 1884, referred, with much reason, the shattering of the chert in certain areas to oscillations of the strata, and Clerc, in 1887, emphasized particularly the dissolving action of water. It is a hard problem to discover the original source of the metals. The earlier writers said nothing of this subject, or else, as in Haworth's paper, discussed a possible precipitation from the ocean or, as in Clerc's, referred them to the pockets of slate and coal. In 1893, at the Chicago meeting of the American Institute 198 KEMP'S ORE DKPOSITS. of Mining Engineers, W. P. Jenney presented an abstract of the results of his work while detailed by the U. S. Geological Survey to study these ore deposits. As will appear in the abstract of the paper given below, the ores are supposed to have come up through fissures of displacement, and hence from below. These con- clusions have been con- troverted by others, on account of the difficulty in proving the ex- istence of faults when evi- dence of displacement is so obscure. In Jenney's paper all the lead or lead and zinc regions of the Mississippi Valley are considered together. They are described as occurring along three lines of upheaval. The region of Wisconsin and Iowa is on the flanks of the Archean " Wisconsin Island " of Chamber- lin, referred to above under 3.06.01. The southeast and southwest Missouri regions are on the Ozark uplift, while a minor argentif- erous galena district is on the line of the Ouachita uplift of Ar- kansas and Indian Territory. The formation of the ore bodies in the first three of these is regarded as having been in general the same. They are thought to have originated from uprising solu- tions, which came through certain principal fissures, and spread laterally into strata favorable to precipitation. In southwest Mis- souri this was the Cherokee limestone of the Lower Carboniferous. In its unaltered state it is an extremely pure carbonate of lime. It lias a maximum thickness, where not eroded, of 165 to 200 feet, and contains many interbedded layers of chert. Much organic matter, and moi'e or less bitumen, are also at times present. The limestone seems to have been raised above the ocean level at the close of the Lower Carboniferous and to have remained for a long period exposed to the atmospheric agents. Much caving in of unsupported layers of chert and much attendant brecciation re- sulted. The general stratum became quite open and cellular in certain portions. At a later period, supposed from several indica- tions to be at the close of the Cretaceous, dynamic disturbance occurred, which along certain lines produced fissures, sometimes parallel, sometimes intersecting. Solutions arose through these which dolomitized much of the remaining limestone and caused additional porosity. Zinc and lead ores were afforded, and where the conditions were favorable they spread laterally from the fis- sures and deposited the sulphides in the cellular rock or replaced the limestone itself. The intersection of crossing fissures is a fre- quent point of deposition, and at times parallel master fissures have given a wide area of impregnation. This form of ore '^"- LEAD AND ZING. 199 posit is called a run. The runs are from 5 to 50 feet in height, 100 to 300 feet long, and 10 to 50 feet across. At Webb City they are even larger. As a general thing the ore is in the inter- stices of the brecciated chert, but it is also in limestone and dolo- mite, and associated with a silicified form of the insoluble residue left by the solution of the limestone, which Dr. Jenney calls " cherokite." All the ores require concentration. Galena usually occurs near the surface, while blende is more abundant in depth. Cadmium is at times present in the blende in notable amount. 2.06.08. Some interesting alterations of the minerals have oc- curred, which have changed the blende to smithsonite and cala- mine. In one case a secondary precipitation of zinc sulphide has occurred as a white amorphous powder which is of very recent date. With the original precipitation of the blende the asphaltic material may have had something to do. In the matter of produc- tion Dr. Jenney fixes the ratio of the blende, galena, and pyrite at about 1000 : 80 : 0.5} 2.06.09. Other zinc and lead deposits are known in central Missouri generally resembling the above quite strongly, but of less economic importance. Some, however, are described by Schmidt as conical stockworks. They sometimes are found in Lower Silurian strata. 1 G. C. Broadhead, "Geological History of the Ozark Uplift," Amer. Geol, III. 6. H. M. Chance, "The Rush Creek (Arkansas) Zioc District," Trans. Amer. Inst. Min. Eng., Wa.shington meeting, 1890. F. L. Clerc, Geological description of the mines in a statistical pamphlet on the Lead and Zinc Ores of Southwest Missouri Mines, p. 4, published by J. M. Wil- son, Carthage, Mo., 1887. Eec. See also Engineering and Mining Jour- nal, June 4, 1887, p. H97. " Zinc in the United States," Mineral Resources, 188y, p. 368. Engineering and Mining Journal, Nov. 3, 1888, p. 389 ; March 8, 1890, p. 386. E. Haworth, A Contribution to the Geology of the Lead and Zinc Mining District of Cherokee County, Kansas, Oskaloosa, Iowa, 1884. C. Henrich, " Zincblende Mines and Mining near Webb City, Mo.," M. E., February, 1893 ; Engineering and Mining Journal, June 4, 1893. R. W. Raymond, "Note on the Zinc Deposits of Southern Missouri," M. E., VIII. 165 ; Engineering and Mining Journal, Oct. 4, 1879. J. D. Rob- ertson, "A New Variety of Zinc Sulphide from Cherokee County, Kansas,'' Amer. Jour. Sci., iii., XL., p. 160. A. Schmidt and A. Leonhard, Missouri Geol. Survey, 1874. A. Schmidt, "Forms and Origin of the Lead and Zinc Deposits of Southwest Missouri," Trans. St. Louis Acad. Sci., III. 246; Amer. Jour. Sci., iii., X., p. 300. Die Blei und Zink Erzlagerstdtten von SiXdwest Missouri, Heidelberg, Germany, 1876. W, H. Seamen, "Zinc iferous Clays of Southwest Missouii,' Amer. Jour. Sci., iii., XXXIX., p. 38. !iOO KEMP'S ORE DEPOSITS. All the Missouri deposits will furnish the subject of a forth- coming report by Arthur Winslow, late State geologist, which will be issued by the State survey. Preliminary papers, cited below by Mr. Winslow, indicate that he does not regard the derivation of the ores from below as proved, and the full statement of his views will be awaited with interest. ENLARGED SECTION SHOWING RELATION OF ZINC-ORE TO THE. -LIMESTONES AND CLAY. Tig. 51. — Geological section of the Bertha zinc mines, Wythe County, Va. After W. H. Case, Trans. Am. Inst. Min. Eng., August, 1893. 2.06.10. Both the mines of Example 25 and those of Example 24 were originally worked for lead, and the zinc minerals were re- garded as a nuisance ; of late years the zinc has been much more of an object than the lead. The deposits in southwest Virginia (Example 26) also produce lead, but are best known for zinc. ^ C. R. Boyd, Resources of Southwest Virginia, p. 71; "Mineral Wealth of Southwest Virginia," M. E., V. 81 ; Ibid., VIII. 340. Eec. H. Credner, Zeitschr. fur die gosammten Naturwissenschaften, ISTO, Vol. XXXIV., p. 21. F. P. Dewey, "Note on the Falling Cliff Zinc Mine," M. E.,X. 111. A. V. Groddeck, Typus Austin, Lehre von den Lagerstat- ten der Erze., p. 103. 2 Dr. Jenney's paper appeared in the Trans. Amer. Inst. Min. Eng., Chicago meeting, 1893, and was entitled ' ' The Lead and Zinc Deposits of the Mississippi VaUey. ' ' It prompted an important discussion. Arthur Winslow has contributed the following : ' ' Notes on the Lead and Zinc Deposits of the Mississippi Valley and the origin of the Ores, ' ' Jour, of Geology, I. 612, 1893; and a brief account in "The Geology and Mineral Products of Missouri, " pamphlet, distributed at the World's Fair, Chicago, 1893. His full report is in press (July, 1894). LEAD AND ZINC. 201 3.06.11. Example 26. Wythe County, Va. Veins or beds of oxidized ores, changing to blende below, in crystalline limestone or dolomite, which lies just above the Calciferous, but is as yet not sharply deter- mined stratigraphically. A' so residual deposits of oxidized ores resting on the limestone, in clays which have resulted from its decay. The ore-bearing terrane is known over a considerable extent of country, running from near Roanoke, one hundred miles westward. The largest mines are in Wythe County, and of these the Bertha is best known. The Bertha ores are calamine and smith- sonite, both crystallized and earthy or ochreous. They lie upon a limestone which is of very irregular surface, being so deeply pitted by superficial decay that it pro- jects in knobs and pillars, and sinks in intervening depressions. These are shown very graphically in Fig. 53, p. 203, where they are left in relief by the stripping. They are man- tled and rounded ofE by the overlying residual clay, which may be 50 to 75 feet deep. The ore lies in sheets and balls or as a powdery fe qs «a &! s O ALTOONA COAL-MINE* 4 s § g fi- fe^ fe iow*wo>Mai(Do » " o a o S > M 5 P D J I 53 g* » S N' & W. Tlv ft. PEAK CREEK DRAPER MOUNTAIN DtUeEft VAU'EV ® NEW RIVER N. A W. R. R. N. C. DIV. BERTHA ZINC-MINES ROARING TAUe. MOUNTAIN 302 KEMP'S ORE DEPOSITS. mass upon or near the limestone In the clay, and is won either by stripping this, or by shafts and drifts. (See Fig. 51.) Accord- ing to Boyd, in one section there are 486 feet of strata impreg- nated with zinc and lead sulphides, with some pyrite. At the Wythe Company^s mines both the oxidized ores and the unchanged sulphides in the underlying limestone are exploited. More or less limonite is obtained from all these surface workings, and is sent to neighboring blast furnaces. Near Bonsacks the gossan of the ore was exposed but not recog- nized for a long time, in a cut of the Norfolk and Western E. E. The mine yielded rich earthy oxidized ores which, however, passed in depth into a very intimate and rebellious mixture of zinc-blende and pyrite. These deposits extend over a wide stretch of country, running from near Eoanoke, one hundred miles westward.^ Eelated deposits occur in northeastern Tennessee, between Knoxville and Bristol, and have furnislied more or less ore, chiefly calamine. They are not large. 2.06.12. Blende is a frequent associate of galena in the Eocky Mountains, but it has been only recently worked for any zinc product, and then largely as a by-product in extracting silver. (See 3.07.10.) 1 C. B. Boyd, " Resources of Southwest Virginia, " p. 71. "Mineral Wealth of Southwest Virginia, ' ' Trans. Amer. Inst. Min. Eng., V. 81 ; Ibid., VIII. 840. ' ' The Wythe Lead and Zinc Mines, Va. , ' ' Engineering and Mining Journal, June 17 and 34, 1893. W. H. Case, " The Bertha Zinc Mines at Bertha, Va. , ' ' Trans. Amer. Inst. Min. Eng., Chicago Meeting, Aug., 1893. H. Credner, Zeitsch. furdie gesammten Naturwis- senschaften, 1870, XXXIV. p. 24. F. P. Dewey, "Note on the Falling Cliff Zinc Mine (Bertha Company)," Trans. Amer. Inst. Min. Eng., X. 111. A. V. Groddeck, Typus Austin. Lehre von den Lagerstotten der Erze, p. 103. CHAPTER VII. ZINC ALONE, OR WITH METALS OTHER THAN LEAD. 2.07.01. Zinc ores commonly occur in association with lead, but there are one or two exceptional deposits in this country which are without lead and which have no parallel in other parts of the world. The minerals containing zinc at Franklin Furnace and Ogdens- burg, N. J., are known elsewhere only as rarities, although they are found in vast amounts in New Jersey.^ ZINC SERIES. Zn. S. Fe. SiO^. Mn. Sphalerite (commonly called blende) ZnS 67 33 Zincite, ZnO 80.3 Franklinite,(Fe.Zn.Mn)0,(Fe.Mn)203 (variable) 5.54 51.8 7.5 Willemite, 2ZaO.Si02 58.5 27.1 Calamine, SZnO.SiO^.HaO 54.2 25.0 Smithsonlte, ZnOCOj 51.9 2.07.02. Example 27. Saucon Valley, Pennsylvania. Zinc- blende and its oxidation products, calamine and smithsonite, fill- ing innumerable cracks and fissures in a disturbed, magnesian lime- stone, thought to belong to the Chazy stage. The ore bodies occur in the Saucon Valley near the town of Friedensville, about four miles south of Bethlehem. The limestone is inclosed between two northerly spurs of the South Mountain, and has apparently been tilted and shattered by the upheaval of the latter. The shattering and disturbances decrease as the South Mountain is left and the dijj decreases. There are three principal mines, the Ueberroth, the Hartman, and the Saucon, the first named being in the portion which is tilted nearly to a vertical dip and is much dis- turbed, while the next is where the dip has gradually decreased to 35°. The mines are on a belt some three quarters of a mile long. At the Ueberroth an enormous quantity of calamine was found on 1 F. L. Clerc, "Zinc in the United States," Minercl Resources, 1883, p. 358. ZINC ALONE. 205 the surface, but it passed in depth into blende and was clearly an oxidation product. In the others the blende came nearer the sur- face. The ore follows the bedding planes and the joints normal to these throughout a zone varying from 10 to 40 feet across and fills the cracks. At their intersection the largest masses are found. Six larger parallel fissures were especially marked at the Ueberroth. This mine jDroved in development to be very wet, and a famous pumping engine, the largest of its day, was built to keep it dry. The Hartman and Saucon are less wet. A little pyrite occurs with the blende, and thin, powdery coatings of greenockite sometimes appear on its surface, but it is entirely free from lead and a very high grade spelter is made from it. The mines were strong pro- ducers from 1853 to 1876, but little has been done since. It is re- ported (1891) that the great pumping engine has been started, and they may once more furnish considerable quantities of ore. 2.07.03. The mines wei"e evidently filled by circulations from below that brought the zinc ore to its present resting place in the shattered and broken belt. Drinker considers it to have been de- rived from a disseminated condition in the limestone.' 2.07.04. Example 28. Franklin Furnace and Sterling, N. J. A bed consisting of franklinite, willemite, zincite, etc., in crystal- line limestone, in many respects analogous to the magnetite of Ex- ample 13. The franklinite and zincite beds are in a belt of white, crystalline limestone which runs southwesterly from Orange County, New York, across northwestern New Jersey. It was considered metamorphosed Lower Silurian by H. D. Rogers, but its associa- tion with Archean gneiss is so close that it has with some reason been regarded as of the same age with the gneiss. Beyond the gneiss to the west a blue limestone supposed to be Lower Silurian outcrops, and the same rock appears again to the southeast. F. L. Nason, of the New Jersey Survey, has recently argued, after careful and praiseworthy field work, and after discovering in unmetamor- phosed portions some fossils which belong to the Olenellusfaunaof the Cambrian, that the blue and white limestones are of the same age, and that the latter owes its character to a great dike of granite. 1 F. L. Clerc, Mineral Resources, 1883, 361. Eec. H. S. Drinker, "On the Mines and Works of the Lehigh Zinc Company," M. E., I. 67. C. E. Hall, in Rep. D3, Second Geol. Survey Penn., p. 239. Die Gruben und Werke der Lehigh Zink Oesellschaft in Pennsylvanien, B. und H. Zeit., 1873, p. 51. 206 KEMPS ORE DEPOSITS. which appears at various points. The granite is not always con- tinuous, and is often in isolated masses or horses, as in the Trotter mine. There is also in some portions of the belt a curious scapo- lite rock, regarded as igneous. It is not unlikely that the great dikes may have been a factor in the formation of the ore, although this is not demonstrated. At Franklin Furnace the crystalline limestone forms a low hill (Mine Hill) east of the upper waters of the AVallkill, and again at Ogdensburg, two miles south, another (Sterling Hill), on the west bank. There is a valley and unex- posed strip between, so that the unbroken continuity without a possible intervening fault cannot be established. The bed at Franklin outcrops on the west side of the hill. It begins on the north just across the Hamburg road and runs south 30° west as a Fig. 54.— Cross Section at Franklin Furnace, Sf. J., corresponding to A A- of Map (Fig. 55), andfotir times the scale of Map. At the left is blue limestone and quartzite. After J. F. Kemp, Trans. N. Y. Acad, of Sciences, XIII. 86, 1893. continuous bed for about 2500 feet. This portion is called the Front vein. It contains on the north the old Hamburg mine, then the Trotter mine, and in the southern portion belongs to the New Jersey Zinc and Iron Company. It runs from 8 to 30 feet broad at the outcrop, but swells below. It dips southeast 40 to 60° into the hill, and is interbedded in the limestone. In the Trotter mine a wedge or horse of hornblende, augite, plagioclase, and various other silicates enters the bed a short distance. In this horse some of the most interesting minerals have been found, such as fluorite, rhodonite, blende (var. cleiophane), smaltite (var. chloanthite), axinite, etc. At the end of the Front vein — or, more properly, bed — a branch or bend strikes off at an angle of 30 to 40° to the east. This more easterly branch, which is called the Buck- wheat mine, outcrops on the surface some 500 feet, and then, after being cut by a trap dike 32 feet wide, pitches down at an angle of 37° and passes under the limestone. The portion of the mine north- east of the dike furnishes the most and best ore. The surface out- ZINO ALONE. 207 crop of the Buckwheat was 25 to 30 feet across, but it swelled be- low to 52 feet, and in the second level, about 200 feet from the surface, it was penetrated by a cross-cut 125 feet without finding the wall. The character of the ore varies ; for while it is excellent at the point of the cross-cut, at 125 feet nearer the intersection with the front bed it becomes lean, while preserving its width lower. Beyond the dike the bed is likewise broad, and is mined out for 40 to 50 feet across. The workings are now some distance down on the pitch. The imjjression made by the arch of the roof and by the curving beds is that this is the crest of an anticline whose axis pitches north 27°, and whose central portion is formed by the franklinite bed being doubled up together on itself bf. fore the two parts diverge in depth. Its western portion probably is continuous in a synclinal trough with the front bed, and its eastern portion dips east at some unknown angle. If this is true, it would doubtless be struck by drilling in the surface to the east- ward. Mining has generally been followed along the entire out- crojD except at the junction of the two branches. At present the most active work is being done on the front bed at the Trotter mine and on the rear bed of the Buckwheat, the latter being much the larger. 2.07.05. The ore consists of franklinite in black crystals usually rounded and irregular, but at times affording quite a per- fect octahedron combined with the rhombic dodecahedron and set in a matrix of zincite, willemite, and calcite. The richest ore lacks the calcite and consists of the other three in varying proportions. This best ore is in largest amount in the Buckwheat mine, beyond the trap dike which cuts it. The limestone containing the ore has a notable percentage of manganese replacing the calcium, and where it is exposed to the atmosphere it weathers a characteristic brown. An analysis of a sample occurring with the ore at Sterling Hill afforded F. C. Van Dyck : CaCOa 82.2,8 M11CO3 16.57 FeoOa 0.50 SiOj 0.30 H2O 1.0 100.50 The percentage of manganese is veiy high for a limestone. 2.07.06. The Sterling Hill outcrop is less extensive. It begins on 208 KEMPS ORE DEPOSITS. the north with the New Jersey Zinc and Iron Company's property and runs south 30° west for 1100 feet. It then branches or bends around to the west and runs north 60° west for 300 feet, bend- ing again to north 30° east, and pitches beneath the surface. Thus the general relations between the front and back beds are somewhat the same as at Mine Hill, and the dip and pitch are similar. The principal workings are on the Front vein, where there are two veins (beds), according to the older descriptions, one rich in franklinite and the other in zinoite. It is doubtful if there really are two distinct beds, but probably one portion is richer in zincite than the other. The part mined is from two to ten feet. The footwall is corrugated and causes many pinches and swells, whose troughs pitch north. The limestone between the front and back outcrop is charged with franklinite and various silicates (jef- fersonite, augite, garnets, etc.), and has been mined out in large open cuts now abandoned. A deposit of calamine was found in the interval about 1876, and has furnished many fine museum specimens. 2.07.07. It is not clear that the Sterling Hill and Mine Hill deposits were once continuous. The bed at Mine Hill runs in the front portion close to the contact of the white limestone and the gneiss. The Sterling Hill bed is much farther away from the gneiss, and this would indicate that it is at a higher horizon. The evidence, too, of a pitching syncline is strong, but a pitching S-fold is not as clear. A faulting of the Archean rocks in an east and west line across their strike, and a subsequent tilting so as to give them a northerly pitch, is a very widespread phenomenon in the Highlands, and lends weight in this instance to the idea that a fault intervenes between the two hills. Such faulting is shown even in New Yorl: City. 2.07.08. The origin of these beds is very obscure. They are so unique in their mineralogical composition that very little direct aid is furnished by deposits elsewhere. At Mine Hill, below the fork of the franklinite bed, there was formerly a large lense of magnetite that has now been mined out. It was in the white limestone. There are many points of analogy between the frank- linite beds and extended magnetite deposits. They are both min- erals of the spinel group, and the spinels are a common result of metamorphic action. The presence of zincite and willemite com- plicates matters, however, and while an original ferruginous de- posit might be conceived with a large percentage of manganese ZINC ALONE. 209 yet sucli abundance of zinc is beyond previous experience. It is, however, suggestive that no inconsiderable amount of zinc is found in the Low Moor (Va.) limonites, as shown by the flue dust (see E. C. Means, " The Dust of the Furnaces at Low Moor, Va.," Buf- falo meeting Amer. Inst. Min. Eng., October, 1888), and this in the course of a protracted blast may amount to many tons, but it does not approach the Franklin Furnace ores. None the less, in the absence of a better explanation, the franklinite bed may be thought of as perhaps an original manganese, zinc, iron de- posit in limestone, much as many Siluro-Cambrian limonite beds are seen to-day, and that in the general metamorphism of the re- gion it became changed to its present condition. Minerals of the spinel group occur all thi'ough this limestone belt, and in Orange County, New York, to the north, there is an old and prolific source of them. 2.07.09. If it is possible to demonstrate the connection between the white limestone and a granite dike, as Mr. Nason argues, this may have been an important factor in the ore formation. It is very reasonable that the igneous intrusion should start ore-bearing currents along a certain stratum in the limestone, which would re- place it with ore. Subsequent folding and metamorphism must then have changed these ores, whatever they were, to the present unusual minerals.^ Figures 55 and 56.— Geological Maps of Mine Hill and Sterling Hill, showing the geological relations of the ore-bodies. After J. F. Kemp, Trans. N. Y. Acad, of Sciences, XIII. 81 and 85, 1893. This view of the method of origin has been advocated by J. P. Kemp in the paper cited below, and more careful search, as well 210 KEMP'S ORE DEPOSITS. as the sinking of the new shaft on the strike of the back vein at Mine Hill, have served to bring to light more intrusions of gran- ite than were previously known. Chondrodite, fluorite and other contact minerals occurred near them. Nason has also shown by an interesting series of analyses that the limestone next the granites tends to be pure CaC03, shading gradually at a distance to dolomitic varieties. Victor Monheim, in discussing the vein of willemite worked in the forties at Stolberg, near Aachen, has urged that at temperatures sufficiently high the anhy- drous silicate of zinc may separate directly from solutions, while at lower temperatures the hydrous salt results. His experi- ments and conclusions give support to the view that the igneous^ FiGUBES 57 and 58. — Stereograms of the ore-bodies at Mine Hill and Sterling Mil. After J. F. Kemp, Trans. N. Y. Acad. of Sciences, XIII. 83 and 89, 1893. plutonic intrusions have played an important r61e in the ore depo- sition. (See V. Monheim, YerTi. d. Naturldst Ver. der p7'eus. Rheinlande u. Wes fphalen Y. 162, 1848; VI. 1, 1849.) Were this true we would not be compelled to assume an original bed of blende from which these oxidized compounds have been derived. It is a general experience, however, that hydrated oxidized ores of zinc have passed in depth into blende, and this fact, in connection with ip. Alger, "On the Zinc Mines of Franklin, Sussex Co., N. J. ," Amer. Jour. Sci. i., XLVIII. 252, 1845, Rec. J. Beco. De I'Etat actual, des Industries du Zinc, etc., aux Etats Unis d'Amerique, Revue TJniver- selle des Mines, 1877, II. 139. W. P. Blake, in paper on ' ' Zinc Ore De- posits of South.western New Mexico, ' ' Trans. Amer. Inst. Mia. Eng., Feb. , 1894, gives notes on the ' ' New Jersey Ore Bodies. " N. L. Britton, Annual Report of the State Oeologist, N. J., 1886, p. 89. An excellent ZING ALONE. 311 the almost entire absence of blende in these mines, adds to their puzzling character. Were they, however, at one time a thor- oughly oxidized gossan containing the three metals specially prom- inent, the intrusions of granite are probably responsible for the change to their present combinations. 2.07.10. Blende is known in numerous places in the Kocky Mountains, and is often argentiferous. When mixed with lead- silver ores it has generally proved a drawback and has raised the cross-section of Mine Hill is given. Gr. H. Cook, ' ' On the probable age of the White Limestone at the Sussex and Franklin Zinc Mines, " Amer. Jour. Sci., ii., XXXII. 208. Geology of New Jersey, 669, 1868, with map. Rec. H. Credner, " On the Franklinite 'BediS," Berg-u. Hiltt. Zeilung, 1866, 29 ; 1871, 369. Bee. E. F. Durre, ' ' MetaUurgisohe Notizen aus New Jersey und dem Lehigh Thai," Zeitsch. des Vereins deutscher Ingenieure, 1894, p. 184. B. K. Emerson, "On the Dykes of Micaceous Diabase, penetrating the bed of Zinc Ore at Franklin Furnace, Susses Co. , N. J. , " Amer. Jour. Scl, May, 1882 , 376. Aug. F. Foerste, ' 'New fossil localities in the early Paleozoics of Penn. , N. J. and Vt. , ' ' etc. , Amer. Jour. Sci., iii. , XL VI. , 345. Discusses the local stratigraphy with a map. P. Groth, "Die Zinkerzlagerstatten von New Jersey. Zelt- Bchrift fur Praktische Geologie, May, 1894, p. 230. W. H. Keating and L. Vanusem, "Geology and Mineralogy of Franklin in Sussex Co., N. J.," Jour. Phil. Acad. Nat. Sci., II. 277, 1822. Rec. J. F. Kemp, "The Ore Deposits at Franklin Furnace and Ogdensburgh, N. J.," Trans. N. Y. Acad. So!., XIII. 76-98, 1893. Gives a full bibliography and annotated list of minerals. Rec. F. L. Nason , ' ' Annual Report of the State Geologist of New Jersey -1890, " p. 25. Amer. Geol, YU. 241;VIIL 166; XIL 154. Atner. Jour. Sci., iii., XXXIX., 407—1890. "The Franklinite Deposits of Mine HiU, Sussex County, N. J. ," Trans. Amer. Inst. Min. Eng., Feb., 1894. E]tg. and Mia. Jour., May 3, 1894, p. 197. Rec. ' 'Chemical Composition of some of the White Limestone in Sussex Co., N. J.," Amer. GeoL, March, 1894, p. 154. T. Nuttall, "Geo- logical and Mineralogical Remarks on the Minerals of Paterson and on the Valley of Sparta," New York Medical and Physical Journal, April, May and June, 1822. Amer. Jour. Sc!., i., V. 239, 1822. Jos. C. Piatt, Jr. , " The Franklinite and Zinc Litigation concerning the Deposits of Mine HiU at Franklin Furnace, Sussex Co. , N. J. , Trans. Amer. Inst. Min. Eng., V. 580, 1876-77. H. D. Rogers, "Geology of New Jersey, 1840, 63-71, with a list cf Minerals by Dr. S. Fowler. ' ' Rec. G. C. Stone, "Analyses of Franklinite and some Associated Minerals (2anals. Zinoite, 4 of Franklinite, 5 of Willemite, 1 of Tephroite)," School of Mines Quarterly, VIII. 148, 1887. G. Troost, "Observations on the Zinc Ores of Franklin and Sterling, Sussex Co. , N. J. , " Jour. Phil. Acad. Nat. Sci., IV. 220, 1824. J. D. Whitney, "Metallic Wealth of the United States, p. 348, 1854. 212 KEMP'S ORE DEPOSITS. smelting charges. Recently works have been erected at Canon City, Col., for the treatment of such ores, and very considerable quanti- ties of blende are there turned into zinc-white. While the local demand for this pigment is not so heavy in the West as in the East, any process which frees the lead-silver or copper-silver ores of the objectionable zinc will operate favorably on many mines now handicapped. This has already proved to be the case with the refractory sulphides met in depth at Leadville. Deposits of oxidized ores in southwestern New Mexico, near the town of Hanover, have recently been mined to a notable extent. The smithsonite and calamine, as well as the blende, which is met in the same vicinity, are unmixed with galena, but the blende often contains intermingled pyrites, and the oxidized products are at times stained with manganese. The ores occupy irregular caverns and seams in Paleozoic or Archean limestone, in close geological association with intru- sive granite, contact zones and iron ores. Prom Blake's descrip- tion the contact zones offer close mineralogical parallels with those in the great limestone belt of northwestern New Jersey and New York, and it is quite probable that scapolite will be found mixed with the other silicates of which he makes mention. A lenticular shape is often notable in the masses of blende. As remarked by Blake, the deposits show some interesting points of resemblance to those of New Jersey, but further metamorphism would be needed to change them to the anhydrous condition of the latter. We can scarcely avoid, however, attributing a strong genetic influence in both cases to the igneous intrusions. The richest carbonates and calamine have been shipped to the Bast, but with the unavoidably high freights only the purest and best surface ores are available. (W. P. Blake, Zinc-ore Deposits of Southwestern New Mexico, Trans. Amer. Inst. Min. Eng., Feb., 1894.) Large deposits of hematite and magnetite have been worked to some extent in the same region, as a flux for lead-silver smelters, but their remoteness militates against their use as au iron ore. 2.07.11. A large amount of zinc ore is turned directly into zinc white and employed as a pigment. For this reason later statistics of the metal do not indicate all the ore mined. The accompany- ing figures are short tons. For detailed statistics see the volume on "Mineral Industry" of the Engineering and Mining Journal, 1894. Zma ALONE. 213 1882. 1890. Dlinois 18,201 26,243 Kansas 7,366 15,199 Missouri 2,500 13,127 Eastern and Southern States 5,698 9,114 33,765 63,683 These amounts are from the Mineral Resources of the United States, 1889-90, p. 89. CHAPTER VIII. LEAD AND SILVER. 2.08.01. There are two general methods of extracting silver from its ores, the one indirectly, by smelting with and for lead ; the other by amalgamation, chlorination, or some such process. Hence under silver there are two classes of mines — lead-silver and high-grade silver ores. Both have almost always varying amounts of gold. The lead -silver mines furnish also, as noted above, by far the greater portion of the lead produced in the United States. Ores adapted to lead-silver metallurgical treatment foi'm, in gen- eral, the oxidized alteration products of the upper parts (above permanent water level) of deposits of galena and pyrites. They may be well-marked fissure veins, chimneys, chambers, or contact deposits. Ores which of themselves are adapted to other pro- cesses are often worked in with the lead ores, and unchanged sul- phides are artificially oxidized by roasting preparatory to smelt- ing. The localities are taken up geographically from east to west. 2.08.02. Lead-Silver Deposits in the Rocky Mountain Region and the Black Hills. — The mines are described in order from south to north, beginning with New Mexico. NEW MEXICO. 2.08.03. Example 29. The Kelley Lode. Oxidized lead ores, with some blende, calamine, etc., forming a contact deposit be- tween slates and porphyry. The ore body is in the Magdalena Mountains, thirtj' miles west of Socorro, and has supplied the Billings smelter at that point. Numerous other ore bodies along the contact between sedimentary and eruptive rocks occur in the same region. 2.08.04. Lake Valley. Farther south in Dofla Afla County the mines of Lake Valley are and have been worked upon deposits very closely analogous to those of Leadville, which furnish the LEAD AND SILVER. 215 principal type. They contain less lead, hardly enough in fact to be classed as lead-silver ores, according to the recent valuable paper of Ellis Clark, although earlier descriptions place greater emphasis on the presence of carbonates of this metal. According to Clark the geological section involved includes quartzite and limestone, consid- ered Silurian, 600 feet; Lower Carboniferous, black shale, 100 feet; green shale, 60 feet; nodular limestone, 48 feet; blue limestone, 34 feet; crinoidal limestone, 125 feet, and overlying limestone, 50 feet; about 1000 feet in all. These are penetrated by four distinct erup- tions of igneous rocks, hornblende-andesite, rhyolite, obsidian and porphyrite. The obsidian is comparatively unimportant, and of the Fig. 5^.— Geological cross-section at Lake Valley, New Mexico, toshotothe relations of the ore. The Hack mass is ore; the dark hachures in the lower left-hand corner are black shale. After Ellis Clark, Trans. Amer. Inst. Min. Eng., Feb., 1894. others the porphyrite is most intimately associated with the ore. The ore-bodies are always connected with the blue limestone, and lie along the contact of this, either with the porphyrite or the overlying crinoidal limestone. They are in the nature of large chutes or elongated contact deposits, very similar, as the figure will indicate, to those at Leadville. The ores are of several varieties but the general components, in addition to the silver, are silica, oxides of iron and manganese, limestone, some galena at times, and some zinc. The varying percentages of the silica and bases afford basic, neutral and siliceous ores. In the bonanza called the Bridal Chamber, great masse_8 of horn- silver were found. Many ores, and interesting minerals, such as vanadinite, descloizite, etc., have made the district well known to collectors. Clark favors the view that the leaching of the porphyrite (which is argentiferous) during its exposure and erosion, by descending surface waters, has 216 KEMP'S ORE DEPOSITS. been the source of the ore. An earlier view attributed it to uprising currents.^ COLOEADO. 2.08.05. Example 30. Leadville. Bodies of oxidized lead- silver ores, passing in depth into sulphides, deposited in much faulted Carboniferous limestone, in connection with dikes and sheets of porphyry. Leadville is situated in a valley which is formed by the head waters of the Arkansas River. The valley runs north and south, being confined below by the closing in of the hills at the town of Granite. It is about twenty miles Isng and sixteen broad, and even to superficial observation is seen to be the dried bottom of a former lake. The mountains on the east form the Mosquito range, a part of the great Park range, while those on the west are the Sawatch, and constitute the Continental Divide at this point. Leadville itself is on the easterly side, upon some foothills of the Mosquito range. The eastern slope of the Mosquito range rises quite gradually from the South Park to a general height of 13,000 feet. The range then forms a very ab- rupt crest, with steep slopes looking westward, which are due to a series of north and south faults whose easterly sides have been heaved upward as much as 7500 feet. The faults pass into anti- clines along their strike. The Mosquito range consists of crystal- line Archean rocks, foliated granites, gneisses, and arnphibolites, and of over 5000 feet of Paleozoic sediments and igneous rocks. The former inch de Cambrian quartzite, 150 to 200 feet; Silurian white limestone, 160 feet, and quartzite, 40 feet ; Carboniferous blue limestone, 200 feet (the chief ore-bearing stratum) ; Weber shales and sandstones, 2000 feet; and Upper Carboniferous lime- stones, 1000 to 1500 feet. The igneous rocks are generally por- phyries. The sedimentary rocks were laid down in Paleozoic time on the shores of the Archean Sawatch Island, and were penetrated by the igneous rocks, probably at the close of the Cretaceous. They were all upheaved, folded, and faulted in the general eleva- tion of the Rocky Mountains, about the beginning of the Tertiary period. The intrusion of the igneous rocks was the prime mover IB. Clark, "The Silver Mines of Lake VaUey, IST. M.," Tram. Amer. Inst. Min. Eng., Feb., 1894. Rep. of Director of the Mint, 1882, Lake VaUey, p. 341, Kelley Lode, p. 376. B. Silliman, "Mineral Regions of New Mexico," Trans. Amer. Inst. Min. Eng., X. 224. LEAD AND SILVER. 317 in starting ore deposition, and the solutions favored the under side of the sheets, along their contacts with the blue Carboniferous limestone. 2.08.06. The early history of Leadville will be subsequently referred to in speaking of auriferous gravels. The lead-silver ores first became prominent in 1877, although discovered in 1874, and by 1880 the development was enormous. The region grew at once to be the largest single producer of these ores, and has re- mained such ever since. The mines are situated east of the city on the three low hills. Fryer, Carbonate, and Iron, but recently a deep shaft in the city itself has found the extension of the ore chutes and opened up great future supplies. The ores have chiefly come in the past from the upper oxidized portions of the deposits. Of late years, however, the older and deeper workings have been showing the unchanged sulphurets. The ores are chiefly earthy carbonate of lead, with chloride of silver, in a clayey or siliceous mass of hydrated oxides of iron and manganese. In the Robert E. Lee mine silver chloi'ide occurred without lead. Some zinc is also found, and a long list of rare minerals. Where the ore is in a hard, siliceous, limonite gangue it is called hard carbonate, but where it is sandy and incoherent it forms a soft carbonate, or sand carbonate. All the mines produce small amounts of gold, which in one case (the Printer Boy) has been of more importance than the silver. A few ore bodies are found at other horizons than the Carboniferous. They also run in instances as much as 100 feet from the contact, and may likewise be found in the por- phyry, doubtless replacing included limestone. They were all deposited as sulphides, and, according to Emmons, when the rocks were at least 10,000 feet below the surface. 2.08.07. In the valuable monograph on the region, which is now a classic on the subject and which is cited below, Emmons endeavors to prove the following points : I. That the ores were deposited from aqueous solution. II. That they were originally deposited mainly in the form of sulphides. III. That the process of deposition involved a metasomatic interchange with the material of the rock in which they were de- posited. IV. That the mineral solutions or ore currents were concen- trated along natural water channels, and followed, by preference, the bedding planes at a certain geological horizon, but that they LEAD AND SILVER. 219 also penetrated the adjoining rocks through cross joints and cleav- age cracks. These additional points are also advanced : I. That the solutions came from above. II. That they were derived mainly from the neighboring eruptive rocks. 2.08.08. The first four points are doubtless correct, and No. III. is an important application of the theory of replacement, fre- quently referred to in the introduction. The last two propositions merit less confidence. Seven additional years of mining have brought many new facts to light and have led others (A. A. Blow in particular, whose valuable paper is cited below) to refer the ores to upward rising currents. Emmons foresaw this possibility and mentioned it on p. 584 of his monograph. The amount of the adjacent, igneous rocks is quite insufficient to afford the ore. In alteration the galena has passed through an intermediate stage of sulphate before changing to carbonate. These mines have been important not alone in their own metallic products, but in fur- nishing the smelters with oxidized lead ores they have sup- plied a means of reduction for many other more refractory ones, "which could be conveniently beneficiated through the medium of lead.^ Much copper occurs with the sulphides now met in depth. 2.08.09. Example 30a. Ten Mile, Summit County. Bodies ' F. M. Amelung, "The Geology of the Leadville Ore District," Engi- neering and Mining Journal, April 16, 1880, p. 35. " On the Origin of the Ore," Ibid., Dec. 20, 1879. A. A. Blow, "The Geology and Ore Deposits of Iron Hill, Leadville, Colo.," M. E., June, 1889. Rec. Ann. Rep. Colo. School of Mine.'!, 1887, p. 63. S. F. Emmons, " Geology and Mining lodua- try of Leadville," Monograph 13, U. S. Geol. Survey. Rec. Second Ann. Rep. Director of U. S. Geol. Survey. Rec. Tenth Census, Vol. XIII., p. 76. F. T. Freeland, "The Sulphide Deposits of South Iron Hill, Lead- ville," M. E., XIV. 181. C. Henrich, " The Character of the Leadville Ore Deposits," Engineering and Mining Journal, Deo. 37, 1879, p. 470. "Ori- gin of the Leadville Deposits," Engineering and Mining Journal, May 13, 1888, p. 33. "On the Evening Star Mine," Ibid., May 7, 1881, p. 361. "Leadville Geology," Ibid., June 3 and 10, 1883 ; Historical, May 30, April 6, 13, 30, 37, 1878 ; also many other allusions, 1879-81. R. W. Raymond, Rep. on the Little Pittsburg Mine, Engineering and Mining Journal, June 28, 1879. L. D. Rickelts, The Ores of Leadville, Princeton, 1883. C. M. Rolker, "Notes on Leadville Ore Deposits," M. E., XIV. 273, 949. F. L. Vinton, " Leadville and the Iron Mine," Engineering and Mining Journal, Feb. 15, 1879, p. 110 ; also Juno 38, p. 465. 220 KEMP'S ORE DEPOSITS. of argentiferous galena, pyrite, and blende, in beds of Upper Car- boniferous limestone, on their contact with overlying, micaceous sandstones, or with sheets and dikes of porphyry. The Carbonif- erous limestones that contain the ores at Leadville extend both north and south, and their equivalents occur also on the west flank of the Sawatch range. Ten Mile is another productive por- tion, north of Leadville and at a higher altitude. The strata are enormously disturbed, and pierced even more than at Leadville by sheets and dikes of porphyry. The ores are less oxidized and more rebellious. The Robinson is the principal mine.^ 2.08.10. Example 30b. Monarch District, Chaffee County. Oxidized lead-silver ores in limestone. The belt of limestones south from Leadville contains some notable ore bodies in Chaffee County. The Monarch district is the most important. It is situ- ated at the head waters of a branch of the South Arkansas River. The ore lies in limestones whose age is not yet accurately deter- mined. The Madonna mine is the best known and has shipped much ore to Pueblo.^ 2.08.11. Example 30c. Eagle River, Eagle County. Galena and its alteration product, anglesite, in Carboniferous limestone, on the contact between it and quartzite or porphyry. The mines lie in the valley of Eagle River, on the western slope of the Con- tinental Divide. The galena has changed to the sulphate, instead of carbonate, probably having been less completely oxidized than at Leadville, and marking the intermediate stage in the process. The wall rocks lie quite undisturbed, having a low dip of 15° north, and not being faulted. Lying lower than the lead-silver deposits, and in Cambrian quartzite, on the contact with an overlying sandstone are found chutes carrying gold in talcose clay.^ 2.08.12. Example 30d. Aspen, Pitkin County. Bodies of • S. F. Emmons, Tenth Census, Vol. XIII., p. 73 ; also a forthcoming monograph of the U. S. Geol. Surve3'. ' S. F. Emmons, Tenth Census, Vol. XIII., p. 79. Eep. Director of the Mint, 1884, p. 191. » S. F. Emmons, " Notes on Some Colorado Ore Deposits," Colo. Sci. Soc, Vol. II., Part II., p. 100. E. E. Olcott, "Battle Mountain Mining District, Eagle County, Colorado," Engineering and Mining Journal, June 11, 1887, pp. 417, 436; Ibid., May 21, 1893, p. 545. G. C. Tilden, "Mining Notes from Eagle County," Ann. Rep. Colo. State School of Mines, 1886, p. 129. s i a e s B^ fcl Is 3" ?s. lO ^ ai , « ^ oa 00 5 1-H o l-H •§ S^ 05 <5 223 KEMPS ORE DEPOSITS. lead-silver ores, largely oxidized, occurring with much barite, chiefly along the contact between extensively faulted, Lower Car- boniferous, blue limestone and a brown, dolomitized, underlying portion of the same; but also in fissures and less regular deposits in these and older limestones and quartzite. Aspen is on the west- ern slope of the Continental Divide, in the valley of the Roaring Fork, just at the point where it crosses the contact of crystal- line Archean gneisses and Paleozoic sediments. The stream cuts them at right angles to the strike. Aspen Mountain lies on the south side and Smuggler Mountain on the north. The limestone belt continues north and south, and is prospected over a stretch of nearly forty miles. At Aspen there is evidence of a faulted, syn- ARCH^AN - Cavon nf RnarinaJforJc iWAi\WO\'V^WO??y^ DRIFT AND DEBRIS 0. (, o Pr «^ O tfAMETAMOHPHOSED CAMBRIAN SILURIAN CARBONIFEROUS CARBONIFEROUS AND SILURIAN Middle and lower CARSOnlFB Fig. 63. — Geological section at Aspen, Colo. After A. Lakes, Ann. Bep. Colo. School of Mines, 1886. clinal fold, with m.any minor disturbances. The westerly dipping rocks by the faulting are repeated to the west and are pierced by a great granite intrusion and much porphyry. Still farther west the Red Jura-Trias sandstones are in great force. The faulted repetitions of the Paleozoic rocks are eroded into a narrow ridge, between Castle Creek and the Roaring Fork, just below the town. Over beyond Aspen Mountain, and to the south, lies Tourtelotte Park, in a small synclinal basin of the limestones, and eight or ten miles farther is Ashcroft. The dips in Tourtelotte Park are low, but they increase going down the mountain toward Aspen, and are steepest of all at its foot, where the strata at 60° run un- der the stream gravels and glacial deposits. The geology when closely viewed is very complicated, and involves the following sections according to D. W. Brunton. (See papers of W. E. New- beri-y and S. F. Emmons, cited on page 219. LEAD AND SILVER. 223 BeU if TON. Archean. 1. Cambrian quartzite, 400 feet. 2. Silurian quartzite and limestone, 460 feet. 3. Lower Carboniferous dolomite, 225 feet. 4. Lower Carboniferous blue limestone, 110 feet. 5. Middle Carboniferous (Weber) shales, 50 to 450 feet. 6. Intruded diorite, maximum 400 feet. 1. Middle Carboniferous limestone, 10 to 160 feet. 8. Jura-Trias sandstone. Emmons. Archean. 1. White quartzite of Upper Cambrian, 200 feet. 2. Silurian limestone and sandstone, 340 feet. 3. Lower Carboniferous brown and blue limestone, 240 feet. 4. Middle Carboniferous clays (Weber shales), 425 feet. 6. Middle Carboniferous green and red sandstone, of the Weber grits, with thin limestone. 6. Jura-Trias sandstone. 2.08.13. Two other sections by different writers (Lakes and Henrich) have been published; but as fossils are almost unknown, the strata can be divided more or less at will. The blue lime- stone is certainly Lower Carboniferous, for fossils gathered by J. F. Kemp from the same horizon on Lime Creek, twenty-iive miles north, where they are plentiful, were pronounced by authori- ties in the East to be such. • 2.08.14. On Smuggler Mountain the same section is shown, but it is not broken by igneous rocks; and although there is a faulting along planes striking parallel with the beds and cutting the dip at a sharp angle, the geology is less complicated. 2.08.15. On Aspen Mountain the ore bodies favor the contact between the blue limestone and the brown dolomite. The former is a very pure limestone, while the latter contains from 20 to 28^ magnesium carbonate. The ore replaces and impregnates the blue limestone, often with very little change in its appearance, but it fills the numerous cracks in the more broken dolomite, coating larger and smaller blocks. The ore occurs also in minor fissures. On Smuggler Mountain the ore especially follows the fissure veins. 224 KEMP'S ORE DEPOSITS. To the north the mines at Woody are on a great fissure, according to W. E. Newberry (private communication), which carries ore where not filled hy a porphyry dike. They ai'e of recent develop- ment, but promise to be rich. Although further systematic study is needed, it is quite clear that the ore bodies of Aspen Mountain have originated by replacement of the blue limestone and by coat- ing the fragments of brown dolomite. The solutions doubtless came up along the fault fissures and selected the contact for the chief point of deposition. The United States Geological Survey has had a party in the region.' 2.08.16. Example 30e. Rico, Dolores County. Contact de- posits of lead-silver ores, in Carboniferous limestones, along intru- sive porphyries. Considerable base bullion has been shipped. There are coals in the vicinity, but the operation of the smelter has been somewhat intermittent. The Newman Hill mines are mentioned under " Silver." " Note.— Example 30/" will be found after Example 31, which has been inserted for geographical reasons. 2.08.17. Example 31. Red Mountain, Ouray County. Oxi- dized lead-silver ores passing in depth into sulphides, in large and small cavities, in knobs of silicified andesite. The cavities have a close resemblance to caves, but differ from ordinary caves in not being in limestone. They permeate the mountain in an irregular way, and mark the courses of old hot spring conduits. The ande- site is generally altered to a mass of quartz, but the process is thought by Mr. Emmons to have taken place at a considerable depth, and that the quartz is a residual deposit left by the re- moval of more soluble elements of the andesite. T. B. Comstock regards them as hot spring deposits.^ 1 D. W. Bruaton, "Aspen Mountain: Its Ores and Mode of Occur- rence," Engineering and Mining Journal, July 14 and 21, 1888, pp. 22, 42. S. F. Emmons, "Preliminary Notes on Aspen," Proc. Colo. Sci. Soc, Vol. 11., Part III., p. 251. Eec. C. Henrich, "Notes on the Geology and on Some of the Mines o£ Aspen Mountain," M. E., XVII. 156. A. Lakes, " Geology of the Aspen Mining Region,'' Ann. Rep. Colo. School of Mines, 1886. W. E. Newberry, " Notes on the Geology of the Aspen Mining Dis. trict," M. E., June, 1889. Rec. L. D. Silver, "Geology of the Aspen (Colo.) Ore Deposits," Engineering and Mining Journal, March 17 and 24, 1888. * M. C. Ihlseng, "Review of the Mining Regions of the San Juan,'' Ann. Rep. Colo. School of Mines, 1885, p. 43. ' T. B. Comstock, "Hot Spring Deposits in Red Mountain, Colorado." LEAD AND SILVER. 225 SOUTH DAKOTA. 2.08.18. Example 30/ Galena (town), in the Black Hills. Contact deposits of galena, in part altered to carbonate, in Car- boniferous limestone along intruded porphyries. The ore occurs in the Carboniferous limestone, which overlies the Potsdam sand- stone near Deadwood, in the northerly flank of the Black Hills. The principal localities are the towns of Galena and Carbonate. Sheets and dikes of igneous rocks penetrate the limestones and have occasioned the ore deposits. Several smelters have had some- what desultory campaigns.^ MONTANA IDAHO. 2.08.19. Example 32. Glendale, Beaver Head County. Ore bodies of argentiferous galena, zincblende, copper and iron pyrites, and their oxidation products, occurring parallel with the stratifica- tion planes of a blue-gray limestone, of age not yet determined. These deposits constitute the Heola mines, and are in the south- western part of the State. They oifer some parallel features with those of southeastern Missouri. (Example 23.) They differ from Example 30 in not being associated, so far as known, with igneous rocks.^ 2.08.20. Example 32a. "Wood River, Idaho. Bodies of ar- gentiferous galena and alteration products, irregularly distributed in limestone, of age as yet undetermined. Southwestern Idaho is largely formed of granite, southeastern is covered by the immense fissure outpourings of basalt along the Snake River. North of these, and on the flanks of the granite, are slates and limestones, especially on the Wood River. The latter contain the lead-silver ores. They are not in immediate association with igneous rocks, and from published descriptions appear to be somewhat irregu- M. E., XVIII. 361. S. F. Emmons, "Notes on Some Colorado Ore De- posits," Proc. Colo. Sci. Soc, Vol. II., Partll., p. 97. M. C. Ihlseng, "Re- view of the Mining Interests of the San Juan Region," Ann. Rep. Colo. School of Mines, 1885, p. 46. T. E. Schwartz, "The Ore Deposits of Red Mountain, Colorado," M. E., June, 1889 ; Proc. Colo. Sci. Soc, Vol. III., Part I., p. 77. 1 F. R. Carpenter, " Ore Deposits of the Black Hills of Dakota," M. E., 1879, New York meeting. See also report by Dr. Carpenter on the geol- ogy etc. , of the Black Hills, to the trustees of the Dakota School of Mines, 1888, p. 134. S. F. Emmons, Tenth Census, Vol. XIII., p. 91. 2 S. F. Emmons, Tenth Census, Vol. XIII., p. 97. 226 KEMP'S ORE DEPOSITS. larly distributed, although possibly connected with fissures. The structural relations with Example 23 may again be referred to. The neighboring slates and granite contain gold and silver veins, which are taken up later on. Several small smelters have been erected in the region, and have been intermittently operated. The country is really in the northern end of the Great Basin.^ 2.08.21. Example 33. Wickes, Jefferson County, Mont. Fis- sure veins near the contact of granite and liparite, but cutting both rocks and carrying in a gangue of quartz the ores, galena, zincblende, copper and iron pyrites, and mispickel. The liparite is said by Lindgren to be Cretaceous or Tertiary. Wickes is just south of Helena, and was one of the first places in the West to establish successful concentration. There are two companies, the Helena and the Gregory, both large producers. 2.08.22. Example 34. Coeur d'Alene, Idaho. Galena and very subordinate alteration products, in a mineralized zone having a well-marked quartzite footwall and an impregnated, brecciated hanging of the same rock. The ore is in large chutes, which fill innumerable small fractures in the rock. The mines are in Ward- ner Canon, in the Bitter Root ^Mountains, northern Idaho. The rocks are quartzite and thin beds of schists, much folded along east and west axes. In this way they became faulted and shat- tered, and in the principal mineral belt afforded an opportunity for the ore to deposit. The gangue is siderite. The mines are ex- tremely productive and are the chief sources of ore supply for lead smelters in Montana and on the Pacific coast. '^ THE REGION OF THE GREAT BASIX. 2.08.23. Example 35. Bingham and Big and Little Cotton- wood Canons, Utah. Bed veins, often of great size, containing oxidized lead-silver ores above and galena and pyrite below the water level, in Carboniferous limestones, or underlying quartzite, or on the contact between the two. The mines are situated in the Oquirrh and Wasatch Mountains, southwest and southeast of Salt Lake City, in caBions well up toward the summits. The region is 1 G. F. Becker, Tenth Census, Vol. XIII., p. 55. Engineering and Mining Journal, July 3, 1887, p. 2. iJep. Director of the Mint, IHHi, p. 198. ^ J. E. Clayton, "The Coeur d'Alene Silver-lead Mines," Engineering ui,d il uimj Journal, Feb. 11, 1888, p. 108. o ^ 1*3 ~: fO ^j 7^ 'ii ^ 6 *-> ~ S* s 'S? i:) ■w CO .^ "W .gi a 0) o 228 KEMPS ORE DEPOSITS. mucli disturbed, and there are great faults and porphyry dikes and knobs of granite associated with ih,e sedimentary rocks. The ores occur in belts, extending considerable distances, and these in places have the rich chutes or chimneys of oxidized products. In Bing- ham Cafion an immense bed of auriferous quartz is found, overly- ing the lead zone and next the hanging. Some jieculiarity about the gold prevents its easy treatment, but much of the rock is very low grade. Other fissure veins in the massive rock of the region are known, but are of less importance. The general geological relations suggest the deposits mentioned under Example 30 and subtypes. The mines were the occasion of the first development of the lead-silver smelters in the West, and have made Salt Lake City an important center of the industry. The Telegraph group, the Emma, Flagstaff, and others were famous mines in their day. As will appear, nearly all the Utah mines are productive of lead- silver ores. 2.08.24. Example 35a. Tooele County. Bedded veins in limestone, or between it an 1 quartzite, and containing lead-silver ores with oohers, in rich chutes. The deposits occur in the west side of the Oquirrh range, in Ophir and Dry canons, over the di- vide from Bingham. The principal mine is the Honorine. Fis- sure veins also occur in the region, but are of less importance. The Deep Creek district, near the Nevada line, is mentioned under 2.11.04.1 2.08.25. Example 35b. Tintic District. Ore beds or belts, three in number, and one to three miles long, generally parallel with the stratification of vertical blue limestones, but sometimes run- ning across them. The ore-bearing zone is from 300 to 600 feet wide in at least one belt, and bears in places rich chutes of car- bonate ore. The Crismon-Mammoth has been referred to under 1 W. P. Blake, " Brief Description, of the Emma Mine,'' Amer. Jour. Sci., ii., II. 216. C. E. Fenner, "The Telegraph Mine," School of Mines Quarterly, Julj-, 1893. O. J. Hollister, " Gold and Silver Mioing in Utah," M. E.,XV1. 8. Rec. D. B. Huntley, Tenth Cen.sus, Yo\. XIII., p. 407. G. Lavagnino, "The Old Telegraph Mine," M. E., 2VI. 25. " Little Cotton- wood and Bingham, Utah," Engineering and Mining Journal, Aug. 14, 1880, p. 106 ; also July 19, 1889. J. S. Newberry, School of Mines Quarterly, 1884, p. 329. R. W. Raymond, Mineral Resources West of the Rocky Moun- tains, 1868-76, and J. R. Brown, Ibid., 1867-68. Ann. Reps, of Director of the Mint. B. SiUiman, "Geological and Mineralogical Notes on Some Mining Districts of Utah,'' Amer. Jour. Sci., iii., III. 195. LEAD AND SILVER. 329 " Copper " (Example 20h), as it contains much copper. The ore is thought by HoUister to have replaced the limestone.' Passing mention should also be made that lead-silver ores occur in Summit County, at the Crescent and other mines. 2.08.26. Example 30ejf. Horn Silver Mine, Beaver County. A great contact fissure between a rhyolite hanging wall and a limestone footwall, and carrying, at the Horn Silver mine, oxi- dized lead-silver ores, chiefly anglesite, with considerable barite, and with many other rarer minerals. The town of Frisco, con- taining the mine, is at the southern end of the Grampian Moun- tains. The great fissure is known for two miles, but is proved valuable only between the lines of the Horn Silver mine. It strikes north and south and dips 70° east. In the neighborhood of the vein the rhyolite is largely altered to residual clay. The mine is very dry and the entire region lacks good water. The Tein in general varies from 20 to 60 feet, but has pinched twice in going down, and of late years has largely ceased producing, al- though there may yet be much ore below. The ores are smelted near Salt Lake, and the base bullion is refined at Chicago. Some free milling ore has been afforded.^ 2.08.27. Example 33a. Carbonate Mine, Beaver County. A fissure vein in hornblende andesite, filled with rounded fragments of wall rock, which are cemented by residual clay and galena. Some oxidized products occur near the surface. The mines are two and a half miles northeast of Frisco, but are in a different eruptive rock from that forming the walls of the Horn Silver. The literature is the same as for Example 30^/, especially Hooker, 1. c. p. 470. 2.08.28. Example 325. Cave Mine, Beaver County. Cham- bers irregularly distributed in the limestone, and more or less filled with limonite and oxidized lead-silver ores. Small leaders of ores, which mark old conduits, connect the chambers. Up to 1880 five large and fifteen small chambers had been found. They are of very irregular shape, and have a vacant space of from one to ten feet between the ore and the roof. This deposit was the typical one cited by Newberry as illustrating the chamber or cave 1 D. B. Huntley, as above (footnote, p. 194) ; also O. J. HoUister, as above, under Example 85a. J. S. Newberry, Engineering and Mining Journal, Sept. 13 and 20, 1879. 2 O. J. HoUister, "Gold and Silver Mining in Utah," M. E., XVI. 3. R»'C. W. A. Hoolier, Report quoted in Ihe Tenth Census, Vol. Xlli., p. 464 230 KEMP'S ORE DEPOSITS. form of deposit. According to this view, the chambers were formed before the ore was brought in. It is also possible that the ore bodies have been deposited by replacement of the limestone with sulphides, as is known abundantly elsewhere, and that the alteration of these to oxides has occasioned the apparent caves. The products of the mine afford but 5 to 1% lead, but are valuable as an iron flux to the neighboring smelters. The mines are in the Granite range, seven miles southeast of Miiford.' Note. — Although the larger part of the Utah mines are for lead and silver, several others of great importance will be taken up under " Silver " itself. NEVADA. 2.08.29. Example 36. Eureka. Bodies of oxidized lead-sil- Ter ores in much faulted and fractured Cambrian limestone, Tvith great outbreaks of eruptive rocks near. The Eureka geo- logical section is one of the most interesting in the entire country, and involves some 30,000 feet of Paleozoic strata, divided as fol- lows : Cambrian quartzite, limestone, and shale, 7700 feet ; Silu- rian limestone and quartzite, 5000 feet ; Devonian limestone and shale, 8000 feet ; Carboniferous quartzite, limestone, and conglom- erate, 9300 feet. These have afforded some extremely valuable materials for comparative studies with homotaxial strata in the East. The ore occurs especially in what is called the Prosjsect Mountain limestone of the Cambrian, one smaller deposit being also known in Silurian quartzite. The limestone has been crushed and shattered along a great fault, and through its substance ore solutions have circulated, replacing it in part with large bodies of sulphides which have afterward become oxidized to a depth of 1000 feet. The ore bodies were puzzling as regards their classification, and a famous mining suit, with many interpre- tations from various experts, resulted. The alteration of the ore has caused shrinkage and the formation of apparent caves over it. But there are many empty caves, formed by surface waters long after the ore was deposited, and Mr. Curtis very clearly shows that the ore bodies originated by replacement. All are connected 1 O. J. HolUster, "Gold and Silver Mining iu Utah," M. E., 1887. D. B. Huntley, Tenth Census, Vol. XIII., p. 474. J. S. Newberry, School of Mines Quarterly, March, 1880. Reprint, p. 9. Cf. also J. P. Kimball, "The Silver Mines of Santa Eulalia, Chihuahua," Amer. Jour. Sci.,ii., XLIX. 161. LEAD AND SILVER. 231 with more or less strongly marked fissures which formed the con- duits. Mr. Curtis made a careful series of assays of the neigh- boring igneous rocks to find some indication of the source of the ore. A quartz porphyry gave significant results and to this the metals are referred, but the portions of the mass at a great Fio. 64. — Section at Eureka, Nev. Reproduced in line work after colored plate by J. S. Curtis, Monograph VI., U. S. Oeol. Survey. depth are considered to have furnished them. " Eureka was one of the first jDlaces in this country where the hypothesis of replace- ment was applied to ores in limestone. The district is now far less productive than it was ten or fifteen years ago.' 1 G. F. Becker, Tenth Census, Vol. XIII., p. 32. Rec. W. P. Blake, " The Ore Deposits of the Eureka District, Nevada," M. E., VI. 554. J. S. Curtis, "Silver-lead Ore Deposits of Eureka, Nev.," Monograph VII., 233 KEMP'S ORE DEPOSITS. ARIZONA CALIFOENIA. 2.08.30. Some $98,000 worth of lead ores were shipped from Arizona in 1889, chiefly from Cochise County (Tombstone region) and Pima County (Tucson region). They will he mentioned un- der "Silver." Insignificant amounts are also afforded by Cali- fornia (about $2000 in 1889), mostly from Inyo County. (See Eleventh Census, Bull. No. 80, June 18, 1891.) v. S. Geol. Survey. A. Hague, " Geology of the Eureka District," Mon- ograph XX., U. S. Geol. Survey. Abstract in Third Ann. Rep. Director U. S. Oeol. Survey. W. S. Keyes, "Eureka Lode of Eureka, Nev.," M. E., VI. 344. J. S. Newberry, School of Mines Quarterly, March, 1880. R. W. Raymond, "The Eureka^Richmond Case," M. E., VI. 371. C. D. Walcott, " Paleontology of the Eureka District," Monograph VIIL, U. S, Oeol, Survey, CHAPTER IX. SILVER AND GOLD.— INTRODUCTORY : EASTERN SILVER MINES AND THE ROCKY MOUNTAIN REGION OF NEW MEXICO AND COLORADO. 2.09.01. The two " precious " metals are so generally associ- ated that they cannot be separately treated. While endeavoring to preserve the distinctive impression given by examples, it is practi- cally impossible to set forth all the vt-'idely varying phenomena of the silver-gold veins of the West in any other than an approxi- mate way. Hence geographical considerations are placed iirst, and where markedly similar ore bodies in different States are to be grouped together cross references are given. The following gen- eral examples have been made because their individual features are based on those geological relations which are most vitally con- cerned with questions of origin. 2.09.02. Example 37. Veins containing the precious metals usually with pyrite, galena, chalcopyrite, and less common sul phides, sulpharsenides, sulphantimonides, etc., in igneous rocks. No special subdivision is made on the character of the gangue, which may be quartz, calcite, barite, fluorite, etc., one or all. The first named is commonest. A great and well-defined original fis- sure is not necessarily assumed, but some crack, or joint, or crushed strip must have directed the ore-bearing solutions, which may have then replaced the walls in large measure. For other structural features see the discussion of veins (1.05.01) ; compare also Ex- ample 17, Butte, Mont. Example 37a. Replacements more or less complete of igneous dikes, which have usually been described as porphyry. Compare Example l7a under "Copper" (Gilpin County, Colorado), and Example 20c? (Santa Rita, N. M.). Ore and gangue (where the matrix is not the dike rock) as in Example 37. Example 38. Contact de2:)osits between two kinds of igneous rock or between two different flows. Ore and gangue as in Ex- ample 37. 234 KEMP'S VBE DEPOSITS. Example 39. Agglomerates of rounded, eruptive boulders, bombs, etc., in abandoned volcanic necks or conduits, and coated with ores. The mines of Custer County, Colorado, are the only examples of ore deposits of this kind yet identified. Example 40. Contact deposits between igneous and sedimen- tary rocks. No subdivisions are made on the kind of rocks. Ore and gangue as in Example 37. Compare also Example 20, " Ari- zona Copper ; " Example 21a, " Triassie Copper;" Example 30, " Leadville ; " and Example 30^, " Horn Silver Mine." Example 41. Veins in sedimentary rocks, generally cutting the bedding, but at times parallel with it. Lateral enlargements are frequent. The ore body may be largely due to replacement. Ore and gangue as in Example 37. Example 42. Veins cutting both sedimentary and igneous rocks, and therefore due to disturbances after the intrusion of the latter. Ore and gangue as in Example 37. No special examples are made for metamorphic rocks. 2.09.03. Silver minerals. Ag. S. As. Sb. CI. Native silver 100. Argenite (silver glance), AgjS 87.1 12.9 Prousite (light ruby silver), 3AgjS.As2S8 . . 65.5 19.4 15.1 Pyrargerite(darkruby silver), SAgaS.SbaSj. 59.8 17.7 22.5 Stephanite (brittle silver), SAgsS.SbjSs 68 . 5 16 . 2 15 . 8 Cerargerite (horn silver), AgCl 75.3 24.7 Silver also occurs with galena (Cf. "Lead") and with tetrahe- drite (Cf. " Copper "). Gold occurs combined with tellurium in a few rare tellurides, mechanically mingled with pyrites, and as the uncombined native metal. From a metallurgical point of view the ores of the precious metals are divided into two classes. 1. Those whose amount of precious metal amalgamates readily with mer- cury, and is thus obtained with comparative ease — the free milling ores. 2. Those which require roasting or some previous treatment before amalgamation, chlorination, or similar process, or which must be smelted primarily for lead or copper, from which the precious metals are afterward extracted — the rebellious ores. In the subsequent description the endeavor has been made to work from the distinctively silver mines to those of gold where geo- graphically possible.^ 1 Ann. Reps. Directors of the Mint. Eec. W. P. Blake, " The Vari- SILVER AND GOLD. 235 2.09.04. Example 22a. Atlantic Border. Already mentioned (2.05.02), the region is only of historical interest as affording sil- ver, although lately some attention has been directed to Sullivan, Me., where the veins have pyrite and probably stephanite, in a quartz gangue, in slates, associated with granite knobs and trap dikes which are of later age than the veins. Some silver is gener- ally found in the galena of the Eastern States, but the ores have never yet proved abundant enough to be important.' Mention m^ay also be made at this point of the argentiferous galena veins along the Ouachita uplift of Arkansas. A few are known, usually with Trenton shales or slates for walls. They are low gi'ade, and though once the basis of a small excitement, their production has never been serious. Additional reference to the region will be found under "Antimony." Some mines of the lat- ter metal are stated by W. P. Jenney to show low-grade, argentif- erous ores in depth.' 2.09.05. Example 42. Silver Islet, Lake Superior. A fissure vein carrying native silver, argentite, tetrahedrite, galena, blende, and some nickel and cobalt compounds in a gangue of calcite, in flags and shales of the Animikie (Cambrian) system, and cutting a large trap dike, within which alone the vein is productive. Silver Islet is or was originally little more than a bare rock some ous Forms in which Gold Occurs in Nature," Rep, Director of the Mint, 1884, p. 573. Rec. Brown, Raymond, and others, 1868 to 1876, ' ' Mineral Resources West of the Rocky Mountains." Annual. T. C. Chamberlain, "On the Geological Distribution of Argentiferous Galena," Oeol. of Wis., Vol. rv. Clarence King, "Production of the Precious Metals in the United States," Second Ann. Rep. Director U. S. Oeol. Survey, p. 333. A. G. Lock, Gold, 1882. Mineral Resources of the U. S.; annual publication of the Geological Survey. R. I. Murohison, "General View of the Conditions under which Gold is Distributed," Quar. Jour. Geol. Soc, VII. 134. Also in Siluria and Amer. Jour. Sci., ii., XVIII. 301. J. S. Newberry, " On the Genesis and Distribution of Gold," School of Mines Quarterly, III., No. 1, and Engineering and Mining Journal, Dec. 24 and 31, 1881, pp. 416, 437. R. Pearce, "On the Ores of Gold," etc., Colo. Sci. Soc, III., p. 237. J. A. Phillips, Ore Deposits, 1884. The Mining and Metallurgy of Gold and Silver, 1867. Tenth Census Report on the Precious Metals. 1 0. W. Kempton, "Sketches of the New Mining District at Sullivan, Me.," M. E., VII. 349. M. E. Wadsworth, "Theories of Ore Deposits," Proc. Boston Soc. Nat. Hist, 1884, p. 305. Engineering and Mining Jour- nal, May 17, 1884. Bull. Mus. Comp. Zool, 3, Vol. VII., 181. ' T. B. Comstock, Ann. Rep. Geol. Survey of Arkansas, 1888, Vol. I., "Gold and Silver." 236 KEMP'S ORE DEPOSITS. 90 feet square, lying off the north shore of Lake Superior just out- side of Thunder Bay, and within the Canadian boundaries. The native silver was detected outcropping beneath the water. The vein was productive to a depth of 800 or 1000 feet, but below this it yielded little. The trap dike has usually been called diorite, but is determined to be norite by Wadsworth {Bull. 2, 3finn. Geol. Survey, p. 92), and gabbro by Irving {Monograph V., U. S. Geol. Survey, p. 378). Some $3,000,000 were obtained from the mine, yet the expenses were so great in keeping up the surface works against winter gales and ice that but little profit was realized. The vein has been traced 9000 feet but is nowhere else productive. Considerable graphite has been found in the work- ings, and some curious pockets of gas.^ 2.09.06. Example 42. Thunder Bay, Canada. The mainland near Silver Islet contains many similar veins. They have fur- nished considerable silver as argentite in a gangue of quartz, barite, caloite, and fluorite, and associated with zincblende, galena, and pyrite.^ THE REGION OF THE ROCKY MOUNTAINS AND BLACK HILLS. NEW MEXICO. 2.09.07. Geology. — The general topography and geology of New Mexico were outlined in the introduction. Much remains to be done in developing its geology. The eastern part belongs to the prairie region and is very dry. A few rivers, notably the Pecos and the Rio Grande, afford water for irrigation, the former of which is now being utilized on a grand scale, and for the latter plans have been prepared. In the central portion many subordi- ' R. Bell, Engineering and Mining Journal, Jan. 8 and 15, 1887. See also May 14, 1887. W. M. Courtis, "On Silver Islet," Engineering and Mining Journal, Dec. 21, 1873, and M. E., Y. 474. E. D. Ingall, Ann. Rep. Can. Geol. Survey, 1887-88, Part II., p. 14. F.A.Lowe, "The Silver Islet Mine and its Present Development," Engineering and Mining Jour- nal, Dec. 16, 1883, p. 321. T. MacFarlane, " Silver Islet," M. E., VIII. 236. Oeol, of Canada, 1863, 717. Canadian Naturalist, Vol. IV. , p. 37. McDer- mott, Engineering and Mining Journal, Vol. XXIII., Nos. 4 and 5. 2 R. Bell, "Silver Mines of Thunder Bay," Engineering and Mining Journal, Jan. 8 and 15, 1887. E. D. Ingall, Ann. Rep. Can. Survey, 1887- 88, Part II., p. IH. Rec. See also Engineering and Mining Journal, May 14, 1887 ; Feb. 18, 1888, p. 133 ; May 36, 1888, p. 383. SILVER AND GOLD. 237 nate north and south ranges of mountains are found, which are less elevated than those of Colorado. The Colorado ranges vir- tually die out at the northern boundary. The northwestern por- tion comes in the great Colorado Plateau, and has been quite fully described by Captain Button {Eighth Ann. Rep. Director TJ. S. Geol. Survey). In numerous localities throughout the Territory volcanic action has been rife and in places is but re- cently extinct. The eastern part is largely Cretaceous, and also the northwestern plateau, which contains much valuable coal. The mountain ranges often have nuclei of Archean ci-ystalline rocks, with successive strata of Carboniferous, Permian, Triassic, Juras- sic, and Cretaceous on the flanks. The mining regions are in these ranges of mountains.^ 2.09.08. The southwestern county is Grant, whose lead-silver deposits have been briefly referred to. North of Silver City are quartz veins of gold and silver ores, in diabase and quartz por- phyry (Example 37), and again, west of Silver City, are ferru- ginous deposits with chlorides and sulphides of silver in limestone. In the Burro Mountains are silver ores in limestones, apparently Lower Silurian. The Santa Rita Mountains contain, in addition to the copper (Example 20d), silver and gold in quartz veins in 1 W. P. Blake, Proc. Bost. Soc. Nat. Hist., 18o9, Vol. VII., p. 64 " Geology of the Rocky Mountains in the Vicinity of Santa Fe,"^. A. A. S., 1859. A. R. Conkllng, "Report on Certain Foothills in Northern New Mexico," Wheeler's Survey, Rep. of Chief of U. S. Engineers, 1877, II. 1298. E. D. Cope, " Report on the Geology of a Part of New Mexico,"' Wheeler's Survey, 1875; Appendix Gl. C. E. Button, "Mount Taylor andtheZuni Plateau," Sixth Ann. Rep. U. S. Geol. Survey, pp. 111-305. S. F. Emmons, Tenth Census, Vol. XIII. 100. O. Loew, "Report on the Geology and Mineralogy of Colorado and New Mexico," Wheeler's Survey, 1875 ; Ap- pendix G2, p. 27. J. Marcou, " The Mesozoic Series of New Mexico," Amer. Geol, IV. 155, 216. R. E. Owen and E. J. Cox, "Report on the Mines of New Mexico," Washington, 1865, 60 pp., Amer. Jour. Sci., ii., XL. 391. G. F. Runton, " On the Volcanic Rocks of New Mexico," Quar. Jour. Geol. Soc., Vol. VI., p. 351, 1850. B. Silliman, Jr., "The Mineral Regions of Southern New Mexico," M. E., X. 434. F. Springer, "Occur- rence of the Lower Burlington Limestone in New Mexico," Amer. Jour. Sci., iii., XXVII. 97. J. J. Stevenson, "Geological Examinations in Southern Cjlorado and Northern New Mexico,'' Wheeler's Survey, 1881. " Geology of Galisteo Creek," Amer. Jour. Sci., iii., XVIII. 471. " On Ihe Laramie Group of Southern New Mexico," Am^r. Jour. Sci., iii., XXII. 870. 238 KEMP'S ORE DEPOSITS. eruptive rooks (Examijle SY). Lake Valley, in Dona Ana County, has been mentioned (2.08.04). In Lincoln County gold ores are reported from the AVhite Oak district. The principal mines of Socorro County have been mentioned (Example 29), and the cop- per in Permian sandstone under Exampile 21e. There are other silver-bearing lodes in the Socorro Mountains near the town of Socorro. Henrich has described (1. e.) a curious deposit of quartz carrying gold and silver (the Slayback Lode) on the contact be- tween the older bedded eruptions and a later siliceous dike in the Mogollon range (Example 38). In Santa Fe County are impor- tant placer mines (Example 44) and thin veins of galena in rhyo- lite. In Bernalillo County are placers on the slopes of the Sandia Mountains. In Colfax County, in the Rocky Mountains, are other placers, and reported gold and silver mines.J COLORADO. 2.09.09. Geology. — The eastern portion contains prairies and is a region lacking water. It consist of Quaternary and Creta- ceous rocks. The plains rise in the foothills, which are chiefly up- turned Jura-Triassic and Cretaceous strata. The Paleozoic is rela- tively limited, although known. It rests on the crystalline rocks of the Archean. There are some minor uplifts, running out at right angles to the Front range, that divide the foothill country into basins, and are especially important in connection with coal. Next come the easterly ranges of the Rooky Mountains, in linear north and south succession. They consist largely of dome-shaped 23eaks of granite, with great local developments of volcanic rocks. To the west follow the several parks, largely consisting of Mesozoic strata. They are bounded by ranges again on the west, some of which, like the Mosquito range (see under Example 30), mark great lines of post-Cretaceous upheaval, and are accompanied by immense igneous intrusions. On the east and west flanks of the Sawatch range (the granitic Continental Divide) are Paleoznic 1 W. P. Blake, "Gold in New Mexico," Proc. Bast. Soc. yat. Hist., VII., p. 16, July, 1859. "Observations on the Geolog-y, etc., near Santa Fe," A. A. A. S., X. 1859. S. F Emmons, Tenth Census, XIII., p. 101. C. Henrich, "The Slayback Lode, New Mexico," Engineering and Mining Journal, July 13, 1889, p. 27. E. E. Owen and E. T. Cox, iJep. on the Mines of New Mexico, Washingi^on, 1865. Rep. Director of. the Mint, 1882, )>. 339. B. Silliman, "Mineral Resources of Southern NewMexico," 21. E., X. 434. Engineering and Mining Journal, Oct. 14 and 21, 1882, pp. 199, 212. SILVER AND GOLD. 33f strata in considerable thickness, but to the west they dip under the vastly greater development of Mesozoic terranes which shade out into the Colorado Plateau. In northern, central, and south- western Colorado are vast developments of igneous rocks that have attended the geological disturbances.^ 2.09.10. The San Juan region includes several counties in southwestern Colorado, in whole or in part, viz. : Ouray, Hinsdale, San Juan, Dolores, and La Plata. The chain of the San Juan Mountains consists of great successive outflows of eruptive rocks, porphyry, diabase, diorite, basalt, etc., which cover up the Archae- an and later sedimentary terranes, except in a few scattered ex- ^ G. L. Canaon, "Quaternary of the Denver Basin," Proc. Colo. Sci. Sac, III. 48. See also III. 200. W. Cross, "The Denver Tertiary Forma- tion," Amer. Jour. Sci., iii., XXXVII. 361. G. H. Eldredge, "On the Country about Denver, Colo.," Proc. Colo. Sci. Soc, III. 86. See also 140. S. F. Emmons, " Orographic Movements in the Rocky Mountains," Oeol. Soc. of America, I. 245-286. F. M. Endlich, " On the Eruptive Rocks of Colorado," Tenth Ann. Rep., Hayden's Survey. H. Gannett, " Report on the Arable and Pasture Lands of Colorado," Hayden's Surrey, 1876, p. 313. H. C. Freeman, " The La Platte Mountains," 3L E., XIII. 681. G. K. Gil- bert, "Colorado Plateau Province as a Field for Geological Study," Amer. Jour. Sci., iii., XII. 16,85. J. D. Hague, Fortieth Parallel Survey, Vol. III., p. 475. F. V. Hayden, Reports of Hayden's Survey, 1873, 1874, p. 40 ; 1875, p. 33 ; 1876, pp. 5, 70. R. C. Hills, " Preliminary Notes on the Erup- tions of the Spanish Peaks," Proc. Colo. Sci. Soc, III. 24, p. 224. "Tiie Recently Discovered Tertiary Beds of the Huerfano River Basin," Proc. Colo. Sci. Soc, III., pp. 148, 217. " Jura-Trias of Soutiieastern Colorado," Amer. Jour. Sci., iii., XXIII., p. 243. A. Lakes, " Extinct Volcanoes in Colorado,'' Amer. GeoZ., January, 1890, p. 38. OacarLoew, " Report on the Minerals of Colorado and New Mexico," Wheeler's Survey, 1875, p. 97. " Eruptive Rocks of Colorado, " Wheeler's Survey, 1873. C. A. H. McCauley , "On the San Juan Region," Rep. Chief of U. S. Engineers, 1878, III., p. 1753. C. S. Palmer, "On the Eruptive Rocks of Boulder County," 'tc, Proc Colo. Sci. Soc, III., p. 230. A. C. Peale, " Oa the Age of the Rocky Mountains in Colorado," Amer. Jour. Sci., iii., XIII., p. 172 ; Reply to the above by J. J. Stevenson, Amer. Jour. Sci., iii, XIII. 297. S. H. Scudder, "The Tertiary Lake Basin at Florissant," Hayden's Survey, 1878, p. 371 ; see also 1877. J. A. Smith, Catalogue of the Principal Minerals of Colorado, Central City, 1870. J. J. Stevenson, "Notes on the Laramie Group of Southern Colorado," Amer. Jour. Sci., iii., XVIII, 129. "The Mesozoic Rocks of Southern Colorado," Amer. Geol, III., p. 391. P. H. Van Diest, "Colorado Volcanic Cones,'' P?-oc. Colo. Sci. (Soc, III., p. 19. C. A. White, "On Northwestern Colorado," Ninth Ann. Rep. Director U. 8. Geol. Survey, 683-710. 240 KEMPS ORE DEPOSITS. posures. Considerable masses of rocks formed of fragmental ejectamenta are also known. All these are crossed by immense vertical veins, largely with quartz gangue, and containing argen- tiferous minerals of the usual species, galena, tetrahedrite, pyrar- gerite, and native silver, as well as bismuth compounds. Gold has been quite subordinate, although late developments near Ouray have shown some peculiar and interesting deposits. R. C. Hills, in the Proc. Colo. Sci. Soc, 1883, traced three systems of veins. (1) Silver-bearing, narrow (six inches to three feet), nearly verti- cal veins, with base metal ores and no selvage. (2) Large, strong, gold-bearing veins dipping 60° with selvages and intersecting (1). (3) Like (1), but larger and more persistent, and carrying occa- sionally bismuth and antimonial ores with gold and little or no silver. T. B. Comstock {M. E., XV. 218) has classified the veins in three radiating systems. (1) The northwest, with tetrahedrite (freibergite). (2) The east and west, with bismuth and less often nickel and molybdenum. (3) The northeast, with tellurides and antimony and sulphur compounds of the precious metals. Quite recently a series of small caves near Ouray, in quartzite overlaid by bituminous shales, have been found to contain native gold, agd have excited great interest-.-" -St-iis thought by Endlich that they represent inclusions of shale, now dissolved away, and that the gold was precipitated on the walls. If this view is correct, they mark one of the very few illustrations of chamber deposits which are known. More extended mining work has proved them to be in all cases connected with a supply fissure from which small lead- ers guide the miners to the chambers. Placer gold mines (Examj)le 44) are quite extensively worked in San Miguel County. J. B. Farish has recently described the veins at Xewman Hill, near Rico, in a valuable paper cited below. The lowest formation exposed is magnesian limestone, supposed to be Carboniferous. It contains large ore bodies of low grade, and is also, strangely enough, heavily charged with carbonic acid gas. Above this for 500 feet are alternating sandstones and shales, and then a narrow stratum of limestone 18 to 30 inches thick. This is followed by about 500 feet additional of shales and sandstone, regarded as Carboniferous. Fifty feet above the low- est limestone a laccolite of porphyrite has been intruded. Two sets of fissures are present — one nearly vertical and striking north- east, the second dipping 30 to 45° northeast and striking north- west. The former are the richest, are banded (see Fig. 5) and per- SILVER AND GOLD. 241 sistent, being worked in one case for 4000 feet. The flatter fissures are less rich. The principal ore bodies, however, occur as hori- zontal enlargements of both these sets of veins. Just over the thin bed of limestone mentioned above the ores have spread out into sheets from 20 to 40 feet wide and from a few inches to three feet thick. They consist of solid masses of the common sulphides, galena, pyrite, gray copper, etc., and are very rich. Above them the fissures apparently cease, or at least are tight. Two hundred feet down from them the vein filling becomes nearly barren, glassy quartz. These are most remarkable ore bodies, and would appear to have been formed by uprising solutions, which met the tight place ai.d spread sidewise, depositing their minerals; but as Mr. Farish advances no explanation, it is hardly justifiable for others, less familiar than himself with the phenomena, to do so. The lead-silver ores of Red Mountain and Rico have already been mentioned (2.08.17). Silverton and Ouray are the principal towns of the San Juan.' 2.09.11. The new mining region of Creede, now decided to be in Saguache County, should be mentioned in this connection. It ' T. B. Comstock, " The Geology and Vein Structure of Southwestern Colorado," M. E., Vol. XV., 218 ; also XI. 165, and Engineering and Min- ing Journal, numerous papers in 1885. "Hot Spring Formation in the Eed Mountain District, Colorado," M. E., XVII. 361. Rec. S. F. Em- mons, "On the San Juan District," Engineering and Mining Journal, June 9, 1883, p. 333. " Structural Relations of Ore Deposits," M. E., XVI. 804. Rec. Tenth Census, Vol. XIll., p. 60. F. M. Endlich, " Origin of the Gold Deposits near Ouray," Engineering and Mining Journal, Oct. 19, 1889. "Sin Juan District," Hayden's Survey, 1874, p. 239. Ibid., 1875, Bull. in.;Amer. Jour. Set., lii., X. 58. J. B. Farish, "On the Ore De- posits of Newman Hill, near Rico, Colo.," Colo. Sci. Soc, April 4, 1893. Rec. R. C. Hills, Proc. Colo. Sci. Soc, 1883. Rec. W. H. Holmes, " La Plata District," Hayden's Survey, 1875 ; Amer. Jour. Sci., iii., XIV. 430. M. C. Ihlseng, " Review of the Mining Interests of the San Juan Region," Hep. Colo. State School of Mines, 1885, p. 37. G. E. Kedzie, " The Bedded Ore Deposits of Red Mountain Mining District, Ouray County, Colorado,"' JIf. J7. , XV. 570. Rec. G. A. Koenig and M. Stocker, "Lustrous Coil and Native Silver in a Vein in Porphyry, Ouray County, Colorado," M. E., IX. 650. T. E. Schwartz, "The Ore Deposits of Red Mountain, Ouray County, Colorado," M. E., 1889. J. J. Stevenson, "On the San Juan," Wheeler's Survey, III., p. 376. " The San Juan Region," Engineering and Mining Journal, Aug. 37, 1881, p. 136 ; Sept. 24, 1881, p. 301 ; July 17, 1880 ; Dec. 30, 1879 ; and many other references in 1879 and 1880. P. H. Van Diest, "On the San Juan District," Proc. Colo. Sci., January, 1886. SILVER AND GOLD. 243 is situated near the junction of Saguache, Ouray, and Hinsdale counties, and some ten or twelve miles from Wagon "Wheel GajD. There is a great develoiDment of igneous rocks as well as of Car- boniferous limestone, but the veins as yet developed are in the form'^. They appear to be fissure veins and have quartz, in large Fig. 66. — Geological cross sections of strata and veins at Newman Hill, near Rico, Colo. After J. B. Farish, Proa. Colo. Sci. Soc. , April 4, 1893, See also Figures 5 and 6. part amethyst, with some manganese minerals as a gangue, and, "with these, oxidized silver ores. The mines are on two moun- tains, Bachelor and Campbell, which are on opposite sides of Wil- low Creek Caflon.' 1 E. B. Kirby, " The Ore Deposits of Creede and Their Possibilities," Engineering and Mining Journal, March 19, 1892, p. 335. Rec. T. R. MacMechen, "The Ore Deposits of Creede," Engineering and Mining Journal, March 13, 1893, p. 301. Rec. j.*^- '*>>pPR^-i^J-^| s fel I; O d l-H ^ o e ^1. , -. -^JCJ. SILVER AND GOLD, 245 2.09.12. The Gunnison region lies on the 'western slope of the Continental Divide and embraces both mountains and plateaus. West of the main and older range are the later Elk Mountains, in which several mining districts are located. Aspen has already- been mentioned, and the long series of ore bodies in the Carbonif- erous limestones. The other principal districts are Independence, Ruby, Gothic, Pitkin, and Tin Cup. The ores at Independence are sulphides with silver, in the Archean granite rocks. In the Tin Cup district the Gold Cup mine is in a black limestone and con- tains argentiferous cerussite and copper oxide. In the Ruby dis- trict the ores are in the Cretaceous rocks, and in the Forest Queen they are ruby silver and arsenopyrite, partly replacing a porphyry dike. On Copper Creek, near Gothic, a series of nearly vertical fissures traverse eruptive diorite. They contain sulphide of silver and native silver. The Sylvanite is one of the principal mines.^ 2.09.13. Eagle County. The lead-silver mines of Red Cliff have ah-eady been mentioned (Example 30c), and also the under- lying gold deposits. The Homestake mine, northwest of Lead- ville, over toward Red Cliif, is on a vein of galena in granite, and was one of the first openings made in the region.^ 2.09.14. Summit County. The Ten Mile district, which is the principal one, has been mentioned under Example 30rt. The Pride of the West mine, on Jacque Mountain, is peculiar, being on a quartz porphyry dike which is partly replaced by ferruginous quartz and barite. Lake County, containing Leadville, has been treated under Example 30. Mention should also be made of the placer deposits in California Gulch, which first attracted prospectors to the region in 1860. In its eastern part Summit County borders on Clear Creek County, and at Argentine are some veins related to those of the latter. They are high up on Mount McClellan, and are remarkable for the veins of ice that are found in them.' 1 F. Amelung, " Sheep Mountain Mines, Gunnison County," Engineer- ing and Mining Journal, Aug. 28, 1886, p. 149. F. M. Chadwick, "The Tin Cup Mines, Gunnison County, Colorado," Engineering and Mining Journal, Jan. 1, 1881, p. 4, See also Example \2d for iron mine?. 2 Guiterman, "On the Gold Deposits of Red Cliff," Proc. Colo.Sci. Soc, 1890. " On the Battle Mountain Quartzite Mines," Mining Industry, Den- ver, Jan. 10, 1890, p. 28. E. E. Olcott, "Battle Mountain Mining District, Eagle County," Engineering and Mining Journal, June 11 and 18, 1887, pp. 417, 436 ; May 21, 1892. G. C. Tilden, " Mining Notes from Eagle County," Ann. Reii. Colo. State School of Mines, 1886, p. 129. " E. L. Berthoud, " Oa Rifts of Ice in the Rocks near the Summit of Mount McClellan," etc., Amer. Jour. Sci., in., II. 108. 246 KEMP'S ORE DEPOSITS. 2.09.15. Park County, which lies east of Lake County and embraces the South Park, has some mines on the eastern slope of the Mosquito range, and in the Colorado range, to the northwest. The latter are similar in their contents to the Georgetown silver ores, mentioned under Clear Creek County, but the former are bodies of argentiferous galena and its alteration pi-oducts in lime- stone and quartzite. Pyrite is also abundant, and at times a gangue of barite appears. The mines are in the sedimentary series, resting on the granite of the Mosquito range, and are pierced by por- phyry instrusions, as at Leadville. The placer deposits at Fair- play deserve mention, as it was from these that the prospectors spread over the divide to the site of Leadville in I860.' 2.09.16. ChaflEee County, on the south, contains the iron mines referred to under Example I2d. There are some other gold-bearing veins near Granite and Buena Vista. The lead-silver deposits of the Monarch district are mentioned under Example 305. In Huerfano County, in the Spanish Peaks, veins of galena, gray copper, etc., are worked to some extent.^ 2.09.17. Rio Grande County. In the Summit district are a number of rich gold mines, of which the Little Annie is the best known. The gold occurs in the native state, in quartz on the con- tact between a rhyolite and trachyte breccia and andesite. The de- posits are thought by R. C. Hills to be due to a silicification of the rhyolite along those lines, probably by the sulphuric acid, which brought the gold. Then the rocks were folded. Oxidation and impoverishment of the upper parts followed, forming bonanzas below. The paper has a very important bearing on the formation of many replacements.' 2.09.18. Conejos County. Some deposits of ruby silver ores have recently been developed in this county, near the town of Platoro. The county lies near the middle of the southern tier. 2.09.19. Custer County affords some of the most interesting deposits in the West. Rosita and Silver Cliff are the principal towns and are situated in the Wet Mountain Valley, between the Colorado range on the north and the Sangre de Cristo on the 1 J. L. Jernegan, "Whale Lode of Park County," M. E., III. 352. = R. C. Hills, " On the Eruption of the Spanish Peaks," Proc. Colo. Scd. Sac, III., pp. 24, 234. 8 R. C. Hills, Proc. Colo. Sci. Soc, March, 1883. Abstract by S. F. Emmons in the Engineering and Mining Journal, June 9, 1883, p. 333. SILVER AND GOLD. 247 south. At Silver Cliff an outbreak of pinkish rhyolite occurs, im- pregnated with silver chloride. It affords a free-milling although low-grade ore. This forms a unique deposit. There is a great thickness of tuffs beneath it, as shown in the Geyser mine, and some remarkable forms of spherulitic crystallizations. 2.09.20. Example 39. Bull Domingo and Bassick. The first named is two miles north of Silver Cliff, and the latter seven miles east, near Roslta. The Bull Domingo is in Arcliean, hornblende gneiss, and consists of what appear to be pebbles or boulders of the wall rock, which are coated with argentiferous galena and an out- er shell of quartz. The ore body is 40 to 60 feet across. The Bassick is in andesite, and likewise consists of what appear to be boulders and pebbles of the country rock, coated by concentric shells of rich ores, and in an elliptical chimney 20 to 100 feet across. The first coat is a mixture of lead, antimony, and zinc sulphides, and is always present. A second, somewhat similar, but of lighter color and richer in lead and the precious metals, is sometimes seen. A third is chiefly zincblende, rich in silver and gold, and is the largest of all. A fourth, of chalcopyrite, sometimes occurs, and lastly a fifth, of pyrite. Various other minerals are found, and, curiously enough, carbonized wood on the outer limits. Both these deposits have been thought to be the tubes of geysers, in which boulders have been tossed about, rounded, and finally ce- mented together. Mr. Emmons has argued against this view, and in a forthcoming monograph will present the results of extended study. A brief account of these results has, however, been pub- lished by Dr. Whitman Cross. The region is shown to be one containing numerous, although not always large, volcanic out- breaks. One of them furnished the sheet of rhyolite at Silver Cliff, while others had for their conduits the chimneys of the Bull Domingo and the Bassick. The ore bodies thus occur in volcanic necks, and make a new form for the science. 2.09.21. Humboldt-Pocahontas. These mines are near Rosita on fissure veins in andesite, but of a different flow and kind from the walls of the Bassick. They are filled with gray copper and chalcopyrite, in a barite gangue. Other mines of less importance occur in the district, but the three above cited are given prom- inence because of their own intrinsic interest and because they have often been referred to in discussions about the origin of ores.^ 1 E. N. Clark, " Humboldt-Pocahontas Vein," M. £., VII. 21. "Sil- 248 KEMFS ORE DEPOSITS. 2.09.22, Gilpin County has already been mentioned undei " Copper " (2.04.08). The general geology of the veins is much like that of Clear Creek, although the ores are quite different. R. Pearce has shown the existence of bismuth in the ore, and gives reasons for believing that the gold is in combination with it. Clear Creek County contains veins on a great series of jointing planes in gneiss (granite), and in large part replacements of the wall. Others are replacements of porphyry dikes or of pegmatite segregations. The ores are chiefly galena, tetrahedrite, zincblende, and pyrite, and the gangue is the wall rock. The curious decrease of value in depth of a series of parallel veins in Mount Marshall was referred to (1.05.05). Georgetown is the principal town and mining center. Others of importance are Idaho Spi'ings and Silver Plume.^ 2.09.23. Boulder County contains veinsalong joints or faulting planes in gneiss, or granite, or associated with porphyry dikes, or pegmatite segregations, and carrying tellurides of the precious metals more or less as impregnations of the country rock. The prevalent country rock is called by Emmons a granite-gneiss. Van Diest distinguishes four successive terranes of massive and schistose rooks along three principal axes and two side ones, and states that the mines are on the sides of the folds. The country is very generally pierced by porphyry dikes, with which the ore bodies are often associated. A large number of species of tellu- ride minerals have been determined from the region, especially by the late Dr. Genth of Philadelphia. The mines afford very rich ores, somewhat irregularly distributed.^ ver Cliff, Colorado," Engineering and Mining Journal, Nov. 2, 1878, p. 314. W. Cross, " Geology of the Eosita Hills," Proc. Colo. Sci. Soc, 1890, p. 269. Eec. S. F. Emmonp, "The Genesis of Certain Ore Deposits," M. E.,XV.U6. TenthCensus,\'o\. XIII., p. 80. L. C. Graybill, " On the Peculiar Features of the Bassick Mine," M. E., XI., p. 110 ; Engineering and Mining Journal, Oot. 28, 18S2, p. 226. Eec. O. Loewand A. E. Conk- ling, "Eosita and Vicinity," Wheeler's Survey, 1876, p. 48. See also Ste- venson in the Eeport for 1873. 1 S. F. Emmons, Tenth Census, Vol. XIII., p. 70. Eec. F. M. Eod- lich, Hayden's Survey, 1873, p. 298 ; 1876, p. 117. P. Eraser, Hayden's Survey, 1869, p. 301. J. D. Hague, Fortieth Parallel Survey, Vol. III., p. 589. Eec. E. Pearce, Proc. CoZo. Sci. Soc, Vol. III., pp. Tl, 210. "The Association of Gold with Other Metals," M. E., 1890. J. J. Stevenson, Wheeler's Survey, Yo\. III., p. 351. F. L. Vintoa, "The Georgetown (Colo.) Mines," Engineering and Mining Journal, Sept. 13, 1879, p. 184. 2 A. A. Eilers, " A New Occurrence of the Telluride of Gold and Sil- SILVER AND GOLD. 349 2.09.24. El Paso County. Within the last three or fonryearsa rich gold district has been opened in the hills west of Pike's Peak. The country is rugged and elevated, and although more or less pros- pected in former years, it has only in very recent times been shown to be an actual producer. A number of minor hills have been formed by trachytic outbreaks, or by these and the red granite of Pike's Peak. The trachytic sheets (they may prove andesites or rhyolites) are cut, as is also the granite, by dikes of typical phono- lite, with nepheline, nosean and other characteristic minerals of this rock. Along the sides of the dikes ore bodies have been formed as well as in fissures. Decomposed country rock (granite, trachyte and phonolite) is often mingled with the ore, and in some veins is found red auriferous jasper. The walls of the veins, whether along the dikes or the fissures, exhibit the results of f uma- role action and purple fluorite is a common veinstone. The origi- nal ore seems to have been a telluride of gold (probably sylvanite, according to Eichard Pearce, or calaverite or krennite, according to Blake), but it has been largely oxidized to the native metal. The trachytic country rock is thickly charged with pyrites.^ 2.09.25. The resources of the remaining counties of Colorado are chiefly in coal. ver," M. E., Vol I, p. 16. S. F. Emmons, Tenth Cmsus,Yol. XIII. , p. 64. J. B. Farish, "Interesting Vein Phenomena in Boulder County, Colorado, " il/. £., September, 1890. F. A. Gtenth, "On Tellurides," Amer. Jour. Sci., ii., XLV., p. 805, and other papers in the same jour- nal. C. S. Palmer, ' 'Eruptive Bocks of Boulder and Adjoining Coun- ties," Proc. Colo. Sci. Soc, Vol. III., p. 230. P. H. Van Diest, "The Mineral Eesources of Boulder County," Ann. Rep. Colo. State School of Mines, 1886, p. 25. 1 "W. P. Blake, "The Gold of Cripple Creek," Engineering and Min- ing Journal, Jan. 13, 1894. Whitman Cross, of the U. S. Greologioal Survey, has in preparation one of the survey atlas sheets of this district. H. L. MoCarn, "Notes on the Geology of the Gold Field of Cripple Creek, Colo.," Science, Jan. 19, 1894, p. 31. R. Pearce, "The Mode of Occurrence of Gold in the Ores of the Cripple Creek District, ' ' Froc. Colo. Sci. Soc, Jan. 8, 1894; Eikj. and Min. Jour., March 24, 1894. E. Skewes and H. J. Eder, "The Victor Mine, Cripple Creek, Colo.," En- gineering and Mining Journal, Aug. 19, 1893 , p. 193. NoTB. — Important discoveries of gold have been lately reported near Leadville, Colo. The veins appear to be of the same geological charac- ter as those which have yielded silver-lead, but lie further east. CHAPTER X. SILVER AND GOLD, CONTINUED.— ROCKY MOUNTAIN REGION, WYOMING, THE BLACK HILLS, MONTANA, AND IDAHO. WYOMING. 2.10.01. Geology. — The southeastern part of Wyoming is in the Prairie region, the southwestern in the Plateau. The Rocky Mountains shade out more or less on leaving Colorado, hut are again strongly developed in northern Wyoming. The northwestern portion contains the great volcanic district of the National Park, and the northeastern, a part of the Black Hills. The Cretaceous and Tertiary strata chiefly form the plains and plateaus. Granite and gneiss constitute the central portion of some of the greater ranges. Paleozoic rocks are very subordinate. The resources in precious metals are small, consisting chiefly of gold in quartz veins in the gneisses, schists, and granites of Sweet- water County. The great mineral wealth of the State is in coal. The iron mines have already been mentioned (2.03.09), and the copper (2.04.27).' THE BLACK HILLS. 2.10.02. Geology. — The Black Hills lie mostly in South Da- kota. They consist of a somewhat elliptical core of granite and metamorphic rocks, with a north and south axis, and on these are laid down successive strata of Cambrian, Carbonifer- 1 H. M. Chance, " Resources of the Black Hills and Big Horn Coun- try, Wyoming," 31. K, XIX., p. 49. T. B. Comstock, "On the Geology of Western Wyoming," Amer. Jour. Sei., iii., VI. 426. S. F. Emmons, Tenth Census, Vol. XIIL, p. 86. F. M. Endlich, "The Sweetwater Dis- trict," Hayden's Survey, 1877, p. 5 ; " Wind River Range Gold Washings," p. 64. A. Hague, "Geological History of the Yellowstone National Park," M. K, XVI. 783. See also F. V. Hayden, Amer. Jour. Sci., iii.. III. 105, 161. F. V. Hayden, Rep. for 1870-73, p. 13; also Amer. Jour. Sci., ii., XXXI. 229. A. C. Peale, "Report on the Geology of the Green River Dis- trict," Hayden's Survey, 1877, p. 511. Raymond's Statistics West of the Eochy Movntains. W. C. Knight, BnU. 14 ^yyo. Exp't. Station, Oot.'^^. SILVER AND GOLD, CONTINUED. 251 OU8, Jura-Trias, and Cretaceous rocks. There are some igneous intrusions. The principal product of the Black Hills is gold. The lead-silver deposits have already been described (2.08.18), and the tin, mica, etc., will be mentioned later.' 2.10.03. The gold occurs in placers of Quaternary and recent age, as well as in Potsdam sandstones, which are old shore beaches now hardened to rock ; in pyritous beds in schistose rocks, and in segregated quartz veins. The Quaternary and recent placers are the usual gravels, which are more fully described under " Cali- fornia." The Potsdam sandstone is an extremely interesting de- posit. It has resulted from the wearing action of the waves of the Potsdam ocean on the Archean schists. Tlie Potsdam also carries other deposits in the vicinity of porphyry sheets and dikes, Fig. 68.— Geological section of the Black Hills. After Henry Newton Report on the BlacJe Hills, p. 206. 1. Schists. 2. Granite. 3. Potsdam sandstone. 4. Carboniferous. 5, 6. Jura-Trias. 7. Cretaceous. which consist of auriferous pyrite, sometimes oxidized. This has replaced the original calcareous cement of the quartzite. The pyritous beds are in a great impregnation zone 2000 feet broad (Carpenter), of slates and schists, with portions especially rich in auriferous pyrites. They occur near the town of Lead City, not far from Dead wood, in the northern hills. The deposits present many analogies with Example 16, and also are like fahlbands (1.06.10). The ore is not high grade, running $3 to $4 per ton, but it is treated at great profit by mining it in enormous quanti- ties. There are also many so-called segregated quartz veins in the 1 F. R. Carpenter, "Ore Deposits in the Black Hills," M. E., XVII. 370. Prelim. Rep. on the Geol. of the Black Hills, Rapid City, So. Dak., 1888. W. O. Crosby, "Geology of the Black Hills," Bost. Soc. Nat. Hist., XXIII., p. 89. Newton and Jenney, Report on the Black Hills, Washing- ton, 1880. C. R. Van Hise, " The Pre-Cambrian Rocks of the Black Hills," Bull. Geol. Soc. Amer., I. 203-244. N. H. Winohell, " Report on the Black Hills," Rep. Chief of U. S. Engineers, 1874, Part II., p. 680. 252 KEMP'S ohj'J deposits. schists and slates. These are lenticular masses of limited extent, horizontally and below, somewhat like a magnetite lens (Example 12) in shape, and carrying a small amount of gold with little or no pyrites.^ MONTANA. 2.10.04. Geology. — The eastern part of the State belongs to the Prairie region, which is, however, in portions greatly scarred by erosion, forming the so-called Bad Lands. The approaches to the Rocky Mountains are not abrupt and sudden as in Colorado, but are marked by numbers of outlying ranges of both eruptive and sedimentary rocks. The chain of the Rookies takes a north- westerly trend in Wyoming, and so continues across Montana. It is rather the jjrolongation of the Wasatch than of the Colorado Mountains, whose strike is for the Black Hills. The character of the ranges is also very different. They are less elevated and have broad and well-watered valleys between, that admit of considera- ble agriculture. Geologically the country is in marked contrast with Colorado. While in the latter the Paleozoic is feebly de- veloped, in the former it reaches great thickness. In the eastern ranges W. M. Davis gives Lower Cambrian 10,000 to 15,000 feet; Silurian and Devonian, not yet recognized ; Carboniferous lime- stones, 3500 feet; Trias, not definitely recognized; Jurassic and Cretaceous sandstones, shales, and thin limestones, 15,000 feet. This more closely resembles the Wasatch and Great Basin sections (see 2.08.29, and 2.11.01). Much granite of a basic or dioritic character is present (Example IV), and great develop- ments of eruptive rocks of extremely interesting character. Xo more interesting field for geological work awaits the investigator.^ 1 A. J. Bowie, "Notes on Gold Mill Construction," il/. E., X. 1881. W. B. Devereux, "The Occurrence of Gold in the Potsdam Formation," M. E., 465 ; Engineering and Mining Journal, Dec. 23, 1882, p. 3S4. H. O. Hofman, "Gold Mining in the Black Hills," M. E., XVII. 498 ; also in preliminary report cited under Carpenter, under Geology. ^ S. Calvin, "Iron Butte: Some Preliminary Notes," Amer. GeoL, IV. 95. G. E. Culver, " A Little Known Region of Northwestern Mon- tana," Wis. Acad., Dec. 30, 1891. W. M. Davis, "The Relation of the Coal of Montana to the Older Rocks," Tenth Census, Vol. XV., p. 697. Rec. J. Eccles, "On the Mode of Occurrence of Some of Ihe Volcanic Rocks of Montana," Quar. Jour. Geol. Scl, XXXVII. 399. G. H. El- dridge, "Montana Coal Fields," Tenth Census, Vol. XV., p. 739. S. F. Emmons, Tenth Census, Vol. XIII., 97. Rec. Hayden's Survey, Ann. SILVER AND GOLD, CONTINUED. 253 2.10.05. Montana took the lead of all the States .in 1887 in the production of silver, was second in gold, and first in the total production of the two. It is now second. In its mineral wealth it yields to no other State in the Union. The mining districts are mostly in the western central and western portions. Develop- ments have progressed so rapidly that all the desirahle data are not available. 2.10.06. Madison County. Veins in gneiss containing galena and pyrite in a quartz gangue. Virginia City is the principal town, and the veins are north of it in the northern part of the countj'.^ 2.10.07. Beaverhead County. Near Bannack City quartz veins with auriferous pyrite on the contact between the limestone and so-called granite.' At Glendale, in the northern part of the county, are the Hecla mines, referred to under " Lead-silver " (Example 32). Auriferous quartz veins are reported farther north. ^ 2.10.08. Jefferson County. This county contains ore bodies chiefly aui-iferous quartz, in gneiss, porphyry, or limestone. The Rep., 1871-72. W. S. Keyes, in Brown's first report on mineral resources, etc., last part, Amer. Jour. Sci., II. 46, 431. Rec. W. Lindgren, "Eruptive Rocks," Tenth Census, Vol. XV., p. 719, forming Appendix B of Davis's flrstpaper. SeealsoProc. Cat. Acad. Sci., SeconASeries, Vol. III., p. 39. J. S. Newberry, "Notes on the Surface Geology of the Country bordering on the Northern Pacific Railroad," Annals N. Y. Acad. Set, Vol. III. 243 ; Amer. Jour. Sci., iii., XXX. 337. " The Great Falls Coal Fields," in Geol. Notes, School of Mines Quarterly, VIII. 327. F. Rutley, "Microscopic Character of the Vitreous Rocks of Montana," Quar. Jour. Geol. Sci., XXXVII. 391. See Eccles, above. W. H. Weed, "The Cinnabar and Bozeman Coal Fields of Montana," Bull. Geol. Soc. Amer., II. 349-364. Engineering and Mining Journal, May 14 and 21, 1892. "Montana Coal Fields," Bull. Geol. Soc. Amer., III. 301-330. C. A. "White, " Existence of a Deposit in Northwestern Montana and Northeastern Dakota that is Pos- sibly Equivalent with the Green River Group,'' Amer. Jour. Sci., iii., XXV. 411. R. P. Whitfield, "List of Fossils from Central Montana," Tenth Census, Vol. XV., p. 713 ; Appendix A to Davis's paper. J. E. Wolff, " Notes on the Petrography of the Crazy Mountains," etc., North- ern Trans. Survey. " Geology of the Crazy Mountains," Bull. Geol. Soc. Amer., III. 445. H. Wood, "Flathead Coal Basio," Engineering and Mining Journal, July 16, 1893, p. 57. H. R. Wood, "Mineral Zones in Montana," Engineering and Mining Journal, Sept. 34, 1892, p. 292. 1 S. F. Emmons, Tenth Census, Vol. XIII., p. 97. = Ibid. 254 KEMP'S ORE DEPOSITS. lead-silver mines near Wiokes have been referred to. (Example 33.) Red Mountain lies at the head of a valley like Wiokes and contains many narrow argentiferous veins. A concentrator was at work on them in 1892.' 2.10.09. Silver Bow County. The copper mines and the gen- eral geology of the Butte City region were referred to under "Copper" (Example 17). In the basic granite, and north of the copper zone, is a belt carrying sulphides of silver, lead, zinc, and iron in a siliceous gangue, but abundantly associated with manga- nese compounds of various sorts, especially rhodochrosite. No manganese is known in the copper belt, nor any copper in the silver belt — most striking phenomena in veins in the same wall /O'.of^co 5 6 7 69 —Cross section of vein at the Alice mine, Butte, Mont. The of vein is 40 feet. After W. P. Blake, M. E., XVI., p. 72. t. Granite country. 2. Softened granite with small veins. 3. Cay wall with [granite. 4. Quartz, broken and seamed. 5. Clay anddecomposed^ranite. 6. and manganese spar — "curly ore." 7. Quartz and ore — " hard vein." 8. Soft with veinlets. 9. Dark colored, hard granite of the hanging-wall countrj'. Fig decom- Quartz granite rock. The line of outcrop has a cresoentic sweep, and it was therefore called by J. E. Clayton the Rainbow Lode. It includes from west to northeast six claims, all but two of which are con- trolled by the Alice Company. There are as many as four dis- tinct veins present in the Magna Charta. All the mines show that the ore and gangue have replaced the granite along a shat- tered strip, for cross sections exhibit alternations of quartz with ore, rhodochrosite, crushed wall rock, residual clay, occasional horses of granite, etc. In the more siliceous granite west of the butte is another silver belt with the same ores as in the Rainbovv' 1 S. F. Emmons, Tenth Census, Vol. XIII , p. 97. J. S. Newberry, 'On R^•d Mountain," Annals N. Y. Acad. Sci., III., p. 351. SILVER AND GOLD, CONTINUED. 235 Lode and likewise having manganese minerals associated. The Blue- bird is the principal mine. The manganif erous outcrop was a notable feature in the landscape, and exhibited a broad, rusty-black belt, not rich at the surface, but only showing the silver in depth. Like the veins in the basic granite, these were also formed by replacement of the rock along a shattered strip. Placer mines were early worked near Butte and led to the location of the deep mines. They are still pro- ductive and are again referred to under "Auriferous Gravels."' 2.10.10. Deer Lodge County. Placer deposits are numerous along the Deer Lodge River, and auriferous quartz veins are known, but the greatest mine is the Granite Slountain, a source of very handsome returns. This is in the southern part of the covmty, nea..- Phillipsburg, and is a fissure vein in granite, prin- cipally with silver ores, although affording considerable gold. On the same vein is the Bimetallic. Farther west sedimentary rocks come in, much metamorphosed by contact with the later irrup- tive granite. On the edge of the county, and not far from the Drumlummon group of veins, later mentioned, are the veins of the Bald Butte Company, in slates and intrusive diorite. A number of other veins are in the same general region.' 2.10.11. Lewis and Clarke County. The placer mines, near Helena (in Last Chance and Prickly Pear gulches), were the first in the county to attract attention. They were found by the prospectors, who spread through the Rocky Mountains as the Cali- fornia gold diggings gave out. Since then many auriferous quartz veins in granite and slates have been developed. Some twenty 1 W. P. Blake, "Silver Mining and Milling at Butte, Mont.," ilf. E., XVI. 38. "Rainbow Lode, Butte, Mont.," M. E., XVI. 65. Rec. S. F. Emmons, " Notes on the Geolog-y of Butte, Mont.," M. E., XVI. 49. Rec. Richard Pearce, "The Associations of Minerals in the Gagnon Vein, Butte City," M. E., XVI. 63. E. D. Peters, Mineral Resources of U. S., 1883-84, p. 374. E. G. Salisbury, " Pl.iccr Mining in Montana," Engineering and Mining Journal, Sept. 8, 1887, p. 167. Rec. " Silver Mines of Butte, Mont.," Ibid., April 18, 1885, p. 261. AVilliams and Peters on Butte, Mont., Engineering and Mining Journal, March 38, 1885, p. 308. 2 H. M. Beadle, " The Coaditioa of the Mining Industry in Montana in 1898," Engineering and Mining Journal, Feb. 11, 1893, p. 123. G. W. Goodale and W. A. Ackers, "Concentration, etc.. with Notes on the Geol- ogy of the Flint Creek Mining District," 31. E. , 1890. Rec. "The Granite Mountain Mine,'' Engineering and Milling Journal, Dec. 10, 1887 ; Nov. 33, 1889. E. G. Spilsbury, " Placer Mining in Montana," Ibid., Sept. 3, 1887, p. 167. 356 KEMPS ORE DEPOSITS. miles north of Helena, in the town of Marysville, is the Drum- lummon group of veins, which carry refractory silver and gold ores, in a quartz gangue, on the contact between a granite knob and the surrounding metamorphic schists. There are also other veins in the granite. Dikes of intrusive rocks occur associated with the ore bodies.^ 2.10.12. Missoula County. In the northwestern corner of the State is a region of very recent development, and more especially since the Northern Pacific Railroad has been built through it. At Iron Mountain and elsewhere mining districts are growing up, but available descriptions have not yet been received. (See paper by G. E. Culver, cited under 2.10.04.) In Meagher County, in the central part of the State, there are a number of mining districts in the Little Belt Mountains. Neihart is the location of some rich silver mines, and is now connected with Great Falls by rail. Other camps are as yet too remote for profitable working. IDAHO. 2.10.13. Geology. — The southern part of the State extends into the alkaline deserts of the Great Basin and is dry and barren. North of this is the Snake River Valley, which is filled by a great flood of recent basalt which stretches from the "Wyoming line nearly across the State. North of the Snake River a large area of granite appears in the western portion and contains many mines. Extensive deposits of gravel also occur. Metamorphic rocks and Paleozoic strata largely constitute the northern portion of the State, and are penetrated by many igneous intrusions. The eastern part lies on the western slopes of the Bitter Root Moun- tains, whose general geology was outlined under Montana. The geology of Idaho has been but slightly studied, and the few re- liable records have resulted from the scattered itineraries of Hay- den's survey, isolated mining reports, and the collections of the Tenth Census.^ "^ J. E. Clayton, '• The Drumlummon Group of Veins," etc.. Engineer- ing and Mining Journal, Aug. 4 and 11, 1888, pp. 85, 106. S. F. Emmons, Tenth Census, Vol. XIII., p. 97. 2 G. F. Becker, Tenth Census, Vol. Xin., 52. F. H. Bradley, Hayden's Survey, 1873, p. 208. F. V. Hayden, Ann. Rep., 1871, pp. 1, 147 ; 1872, p. 20. J. S. Newberry, "Notes on the Gi;ology and Botany along the North- ern Pacific Railroad," Annals N. Y. Acad. Sci., III. 353. Eaymond's Re- ports on Mineral Resoures West of the Rocky Mountains. O. St. John, Hayden's Survey, 1877, p. 323 ; 1878, p. 175. SILVER AND GOLD, OONTTNUED. 257 2.10.14. Custer Comity lies soutli of Lumhi and contains several well-known mines. The Ramshorn is in metamorphic slates on a fissure vein that has rich chutes of high-grade silver ores in a siderite gangue. The Custer and the Charles Dickens are farther west, near Bonanza City, and afford both silver and gold in quartz gangue from veins in porphyry. Smelting ores oc- cur in the region and have been used in some operations based on this treatment. In Boise and western Alturas counties a granite area forms the greater part of the surface, and in it are numerous productive veins. In the former they are chiefly gold quartz ex- cept in the Banner district, where silver predominates. The placer deposits of Boise County, which were developed in 1863, were very rich, but are now less productive than in former years. In Alturas County gold quartz veins occur, and also others carrying silver, and the county is a strong producer. The Wood River mines in slates and limestones, southeast of the granite, have already been referred to under Example 32a. Owyhee County is in the southwestern corner of the State. It is probable that the granite of the two last mentioned counties extends under overlying drift and comes up again near Silver City (Becker). Southwest of it quartz porphyry and metamorphic rocks are found, with dikes of basalt. Gold quartz and high-grade silver ores are present. The Poorihan Lode is famous for ruby silver ores. W. P. Blake mentions seeing a piece from this mine at the Paris Ex- position which weighed about 200 pounds.' It was awarded a gold medal. The crystal from which it was broken weighed 500 pounds.' In Cassia and Oneida, two other counties in the southern part, placers are being or have been worked, and in Bear Lake County, in the southeast corner, salt and sulphur deposits are re- corded.' 1 Amer. Jour. Sci., ii., XLV. 97. ' Eaymond's Reports on Mineral Resources West of the Roehy Moun- tains, 1868, p. 533. " G. F. Becker, Tenth Census, Vol. XIII., p. 59. Raymond's Reports on Mineral Resources West of the Rocky Mountains, Rep. Director of the Mint, 1883, p. 237. CHAPTER XL SILVER AND GOLD, CONTINUED.— THE REGION OF THE GREAT BASIN, IN UTAH, ARIZONA, AND NEVADA. T7TAH. 2.11.01. Geology. — The eastern half of Utah, terminating with the western front of the Wasatch, is in the Colorado Pla- teau, but the western is within the limits of the Great Basin. The plateau portion consists largely of Mesozoic strata, quite horizontal and more or less carved by erosion. The east and west arch of the Uintah Mountains, in the northern part, has upheaved them, so that where the Green River has cut a channel across, the Paleozoic is exposed in great strength. The Wasatch range rises with a gradual ascent from the east, and then terminates with a great fault line having a steep westerly front. This line of weak- ness was developed in the Archean and has been a scene of move- ment even to recent times. It is a very important structural feat- ure. West of the Wasatch, which is a fine example of block tilt- ing in mountain-making, the mountains belong to the Basin ranges, which are more typically developed in Nevada. The Wasatch section was shown by the Fortieth Parallel Survey to involve 12,000 to 14,000 feet of the Upper Archean and nearly 30,000 feet of the Paleozoic. In southern Utali the Triassic rocks are im- portant and contain some rich mines.^ 1 Or. F. Becker, Tenth Census, Vol. XIH., 38. C. E. Dutton, Bep. on the High Plateaus of Utah, Washington, 1880. A. G«ikie, "Archean Rocks of the Wasatch Mountains," Amer. Jour 8ei., hi., XIX. 363. G. K. Gilbert, " Cent ribu' ions t") the History cf Lalie Bonneville,'' Seconc? Ann. Rep. Director U. S. Geol. Survey, 169-300, and Monograph II. "The An- cient Outlet of Great Salt Lakp," Amer. Jour. Sci., iii., XV. 256, XIX. 341; see also A. C. Peale, Ibid , XV. 439. The Henry Mountains,'WashiBgton, 1877. Hague, Kinp-, and Emmons, Fortieth Parallel Survey, Vols. I. and II. O. C. Marsh, '-On the Geology of the Eastern Uintah Mountains," Amir. Jour. Sci., iii., I. 191. B. Silliman, ''Geological and Mineralogical No.es on Some of the Mining Districts of Utah Territory," ^mer. Jour. SILVER AND GOLD, CONTINUED. 259 2.11.02. The greater number of the Utah mines are for lead- silver ores and have been mentioned under " Lead Silver." The northwestern county, Box Elder, is in the alkaline desert region of the Great Basin. The mining districts occur in the central part of the State, in the Wasatch and Oquirrh mountains, and are also found in the extreme southwest. 2.11.03. Ontario Mine. Nearly east of Salt Lake City, in Summit County, is the Ontario mine, a vein from four to twenty- three feet wide (averaging eight feet), in quartzite, but extremely persistent, being opened continuously for 6000 feet. In the lower working a jjorphyry dike has come in as one of the walls. It is extensively altered by fumarole action to clay. The best parts of the mine have quartzite walls. The ores consist of galena, gray copper, silver glance, blende, etc. Other somewhat similar ore bodies are known in the same region but are less developed.^ 2.11.04. The lead-silver veins of Bingham Canon, in Salt Lake County, have already been mentioned. Reference may again be made to the great bed-veins of gold quartz associated with them. Ophir Canon and Dry Canon, in Tooele County, and the Tintic district, in Juab County, have also been described. In addition to the smelting ores, others have been treated by milling. Quite recently interest has been directed to the mines of the Deep Creek district, on the extreme western border of Utah, in the Ibapah range. Limestones regarded by Blake as Carboniferous, and other sedimentary rocks, have been broken through by great outflows of granite, andesite, hypersthene-ande- site, etc. The ore bodies appear to be contact deposits in lim.e- stone near igneous rocks, and carry much free gold.^ In Beaver County the interesting deposits of the Horn Silver, the Carbonate, and the Cave ore bodies have been mentioned Sci., iii., III. 195. Wheeler, Gilbert, Lockwood and others on Western Utah, Wheeler's Survey, Rep. Prog. 1869-71-78. Idem, Final Reports, Vol. III. ' T. J. Almy, "History of the Ontario Mine, Park City, Utah," M. E., XVI. 35. " The Ontario Mine," Engineering and Mining Journal, May 38, 1881, p. 865. D. B. Huntley, Tenth Ceiswt, Vol. XIII., p. 438. 2 W. P. Blake, "Age of the Limestone Strata at Deep Creek, Utah, and the Occurrence of Gold," etc., Amer. Geol, January, 1893, p. 47. Engi- neering and Mining Journal, Feb. 33, 1893, p. 353. S. F. Emmons, For- tieth Parallel Survey, Vol. II. J. F. Kemp, " Petrographical Notes on a Suite of Rocks collected by E. E. Olcott, " N. Y. Acnd. Set., May, 1893. W. H. Dodds, "Granite Mountain Mine," Collier ij Engl urn; Dec, 1893. 260 KEMP'S ORE DEPOSITS. under Examples 30ff, 33a, and 32b. The great iron mines of Iron County will be found under Example 14. In Piute County, near the town of Marysvale, around Mount Baldy, are a number of mines with lead-silver or milling ores in quartz porphyry (copper belt), or between limestone and quartzite (Deer Trail, Greeneyed Monster, etc.). Selenide of mercury is found in the Lucky Boy.' 2.11.05. Example 41. Silver Reef, Utah. Native silver, cerar- gerite, and argentite, impregnating Triassic sandstones, and often replacing organic remains. These deposits were earlier referred to under Example 21, p. 80. They were discovered in 1877. At Silver Reef there are two silver-bearing strata or reefs, w'ith beds of shale between. Above the water line the ore is horn silver ; below, it is argentite. At times it replaces plant remains ; at other times no visible presence of ore can be noted, although the rock Ore-*- Fig. 70. — Two sections of the argentiferous sandstone at Silver Reef, Utah. After C. M. Rolker, M. E., IX., p. 31. may afford $30 to the ton. The silver always occurs along certain ore channels, distributed through parts of the sandstone. The origin of the deposits has given occasion to a vigorous discussion. J. S. Newberry holds that the silver was deposited in and with the sandstone from the Triassic sea, although it may have been concentrated since in the ore channels. F. M. F. Cazin holds that the organic remains were deposited in and with the sandstone, and that these were the immediate precipitating agents of the ores. R. P. Roth well explained them much as does Rolker, below. C. M. Rolker, who was for some years in charge of several of the mines, has also written about them, and is probably nearest to the truth. Rolker argues that the impregnation was subsequent to the forma- tion of the sandstone, and was caused by the igneous outbreaks in the neighborhood, and probably runs along old lines of partial -.veakening or crushing that afterward healed up. Eruptive rocks Ore 1 G.J, Brush, "On the Onof rite, etc.," ^mer. Jour. Set., iii., XXI. 313. SILVER AND GOLD, CONTINUED. 261 are known in the neighborhood of the ores both in Utah and in the Nacemiento copper district of New Mexico. From what we know of ore deposits in general this seems most probable.^ AKIZONA. 2.11.06. G-eology. — Arizona lies partly in the plateau region and partly in the Great Basin. The Basin ranges converge with the Rocky Mountains, which, however, are chiefly in New Mexico. The uplands of the ranges are well watered and covered with timber, but the low-lying portion of the Great Basin is an arid desert, and in southwestern Arizona is the hottest jsart of the United States. Cretaceous and Jura-Trias largely form the plateau region. Running southeast to northwest is the great development of Carboniferous limestone so often referred to under " Copper," and underlying this are found Archean granites, gneisses, etc. A great series of ore deposits is ranged along this contact. In the southwest are mountains of granites and metamorphic rocks. The Territory also contains vast flows of igneous rocks, and in the pla- teau country between the converging ranges some 20,000 or 23,000 square miles are covered by them. The Grand Canon of the Colo- rado has laid bare a magnificent geological section of many thou- sand feet, from the Archean to the Tertiary.* 1 F.M.F.Cazin, "TheOrig'iQof the Copper aod Silver Ores in Triassic Sandrock," Engineering and Mining Journal, Dec. 11, 1880, p. 381 ; April 30, 1881, p 800. " The Silver SandstoDe Formation of Silver Reef," Ibid., May 22, 1880, p. 851 , Jan. 10, 17, 24, 1880, pp. 25, 48, 79 (Rothwell). A. N. Jackson, " Silver ia Sedimentary Sandstone," Rep. Director of Mint, 1882, p. 384, reprinted from Cal. Acad. Sci. J. S. Newberry, "Report on the Properties of the Stormout Silver Mining Company," etc.. Engineering and Mining Journal, Oct. 38, 1880, p. 269. "The Silver R-ef Mines," Ibid., Jan. 1, 1881, p. 4. C. M. Rolker, " The Silver Sandstone District of Utah," M. E., IX. 21. ' "Central Arizona," Engineering and Mining Journal, April 23. 1881, p. 285. "Colorado River of the West," review of Ives Expedition, Amer. Jour. Sci., ii., XXXIII. 387. G. F. Becker, Tenth Census, Vol. XIII., p. 44. C. E. Dutton, " The Physical Geology of the Grand Canon District," abstract of Monograph II., Second Ann. Rejj. Director U. S. Geol. Survey, 49-161 ; see also the monograph. Patrick Hamilton, The Resources of Arizona, A. L. Bancroft & Co., San Francisco, 1884. B. Silli- man, "Report on Mining Districts of Arizona, near the Rio Colorado," En- gineering and Mining Journal, Aug. 11, 1877, p. Ill ; taken from Amer. Jour. Sci., ii. XLI. 289. C. D. Walcott, " P.^rmiin an.l Ot er Paleozoic 363 KEMP'S ORE DEPOSITS. 2.11.07. Apache County is in the northeastern comer. In the southern part of the county gold and silver ores, in veins in lime- stone, associated with copper ores, are reported, and some small placers. 2.11.08. Yavapai County. Gold and silver ores, in quartz veins, in granite and metamorphic rocks. The Black Range copper dis- trict has already been referred to under Example 20e. Mohave County. Silver sulphides, arsenides, etc., and alteration products in veins in granite, at times showing a gneissoid structure. Only the richest can now be worked. Yuma County. Quartz veins, with silver ores and lead miner- als in metamorphosed rocks (gneiss, slate, etc.), or in granite. Maricopa County contains both Paleozoic aud Archean expos- ures. The ore deposits lie mostly along the contact of the two, in granite or highly metamorphosed strata. They are usually quartz veins, with silver ores and copper, lead, and zinc minerals. The Globe district, extending also into Pinal County, is the principal ■one. Mention has already been made of it under " Copper," Ex- ample 20c. Pinal County adjoins Maricopa on the south and contains a number of important mines. They produce mostly silver ores, with lead and copper associates, and some blende. The gangue minerals are quartz, calcite, etc., occasionally manganese com- pounds, and sometimes, in the granites, barite. Limestone, slate, sandstone, and quartzite, as well as granite, diabase, and diorite, occur as wall rock. 2.11.00. Silver King Mine. A central mass or chimney of quartz, with innumerable radiating veinlets of the same, carrying rich silver ores and native silver, in a great dike of feldspar por- phyry, with associated granite, syenite (Blake), porphyry, gneiss, and slates, all of Archean age. The veinlets ramify through the strongly altered porphyry, and form a stockwork, which furnishes the principal ores. In the region are also Paleozoic strata, whose upper limestone beds are referred by Blake to the Carboniferous. The minerals at the mine are native silver, stromeyerite, argen- tite, sphalerite, galenite, tetrahedrite, bornite, chalcopyrite, pyrite, quartz, calcite, siderite, and, as an abundant gangue, barite. Groups of the Kanab Vallej', Arizona,'' Amer. Jour. Sci., in., XX. 321. " Pre-Carboniferous Slrata iathe Grand Canon of the Coloi-ado, Arizona," Amer. Jour. Sei., December, 1883, 437. Wheeler's Survey, Vol. III., and Supplement. SILVER AND GOLD, CONTINUED. 2C3 trraham County contains the Clifton copper district, referred to under Example 20a. Cochise County is the southeastern county, and contains the Tombstone district, the most productive of the precious metals in the Territory. 2.11.10. Tombstone. A great porphyry dike up to 70 feet wide, cutting folded Paleozoic strata, and itself extensively faulted and altered, and carrying above the water line in numerous verti- cal joints, or partings, quartz with free gold, horn silver, and a lit- tle pyrite, galenite, and lead carbonate. Curiously enough, in the porphyry itself, and far from the quartz veins, flakes and scales of free gold have been found, evidently introduced in solution. Ore also occurs along the side of the dike. There are also other fis- sures parallel with this principal dike, and still another series crossing these and the axis of the great anticline of the district. Connected with these fissure veins are bedded deposits in the limestone, along the bedding planes or dropping from one to an- other, appearing to have originated by replacement. Blake offers two explanations of the first-mentioned dike deposit — either that the dike itself held the precious metals, or that they came from the pyrite of the adjoining strata. Several other mining districts of less note occur in the county. The important copper deposits of the Bisbee region have already been mentioned under Example 20/! 2.11.11. Pima County is the central county of the southern tier and has Tucson as its principal city. There are numbers of mines of the precious metals, and a few less important copper de- posits. Yuma County, in the southwestern corner, has some mines along the Colorado River, on quartz veins in metamorphosed rocks, containing silver and lead minerals.^ 1 G. F. Becker, Tenth Census,Yo\. XIIL, p. 44. G. H. Birnie, " Castle Dome District," Wheeler's Survey, 1876, p. 6. W. P. Blake, " The Geology of Tombstone, Ariz.," M. E., X. 334, Engineering and Mining Jour- nal, June 34, 1882, p. 328 ; The Silver King Mine, a short monograph, New Haven, March, 1883. Rec. See also Engineering and Mining Jour- nal, April 28, 1883, p. 238. J. F. Blandy, "The Mining Region around Prescott, Ariz.," M. E., XI. 286, Engineering and Mining Journal, July 21, 1883. " On Tombstone, Ariz.," Ibid., May 7, 1881, p. 316 ; March 18, 1882, p. 145. "Silver in Arizona," General Review, Engineering and Min- ing Journal, Sept. 21 and 25, 1880, pp. 172, 203. " Central Arizona," Ibid., April 33, 1881, p. 285. O. Loew, "Hualapais District," Wheeler's Survey, 264 KEMP'S ORE DEPOSITS. NEVADA. 2.11.12. Geology. — Nevada lies almost entirely in the Great Basin, only the western portion being in the Sierras. The surface is thus largely formed by the dried basins of former great lakes, principally Lakes Lahontan and Bonneville. A large number of ranges extend north and south through the State, known collec- tively as the Basin ranges. They have been formed by block tilt- ing on a grand scale and present enormously disturbed strata. The geological sections exposed are of surpassing interest (cf. Ex- ample 36), and show Archean and Paleozoic in great thickness. In these mountains are found the mining districts, while between them lie the alkaline plains.' 2.11.13. Lincoln County is in the southeastern corner and con- tains a number of small mining districts. The ores are in general silver-lead ores in limestone, or veins with sulphuret ores in quartz- ite and granite. Pioche is one of the principal towns, near which is found the once famous and now reopened Raymond & Ely mine. A strong fissure cuts Cambrian quartzite and overlying limestone, where the latter has not been eroded, and is occupied, by a great porphyry dike. Along the contact between the por- phyry and the wall rock the chutes of ore have been found. Mr. Ernest Wiltsee, at the Montreal meeting of the American Insti- tute of Mining Engineers, February, 1893, described and figured the Half Moon mine, on this same great fissure, where the quartz- 1876, p. 55. B. Silliman, "Report on the Mining District of Arizona near the Rio Colorado," ATner. Jour. Sci., ii., XLI. 289 ; see also Engineering and Mining Journal, Aug. 11, 1877, p. 111. Raymond's Reports, and those of the Diroctor of the Mint. 1 J. Blake, "The Great Basin," Proc. Cal. Acad. Sci., IV. 275, Amer. Jour. Sci., iii., VI. 59. W. P. Blalie, " On the Geology and Mines of Ne- vada " (Washue silver region), Quar. Jour. Geol. Sci., Vol. XX., p. 317. H. G. Claik, "Aurora, Nev.: a Little of its History, Past and Present," School of Mines Quarterly, III. 133. G. K. Gilbert, "A Theory of the Earthquakes of the Great Basia, with a Practical Application," Amer. Jour. Sci., iii., XXVII. 49. I. C. Russell, "Geology End History of Lake Lahontan, a Quaternary Lake of NorthwesternNevada," Monograph XL, U. S Oeol. Survey ; also Third Ann. Rep. Director U. S. Geol. Survey, 195. C. D. Walcott, " Paleontology of the Eureka District," Mononraph VIIL, U. S. Geol. Survey. Gilbert, Wheeler, Lockwood, and others, "Eastera Nevada: Notes on its Economic Geology," Wheeler's Survey, Rep. Prog., 1869, 71, 72 ; also Vol. III. and Supplement. For further lit- erature, see under Example 36. SILVER AND GOLD, CONTINUED. 365 ite still retained a limestone cap. The ore-bearing solutions, on reaching a shaly streak containing a limestone layer, departed from the fissure and followed under the limestone, so as to form a lateral enlargement, much like those described and figured from Newman Hill, Colorado, under 2.09.10. The Pahranagat and Tern Pahute districts, still farther south, have had some prominence, but the whole region is so far from the lines of transportation that the conditions are hard ones.' 2.11.14. Ney County, next west, has an important mining center, in its northern portion, around the town of Belmont. Quartzite and slates rest on granites in the order named, and in them are veins with quartz gangue and silver chlorides, affording very rich ores. Southeast of Belmont is Tybo.^ 2.11.15. "White Pine County lies to the northeast, and contains the White Pine district. The principal town is Hamilton, about 110 miles south of Elko, on the Central Pacific. The Humboldt range is prolonged southward in some broken hills, consisting chiefly of folded Devonian limestone. At Hamilton these are bent into a prominent anticline, and this has a strong fissure cross- ing the axis. The geological section is Devonian limestone, thin calcareous shale, thin siliceous limestone, argillaceous shale, prob- ably Carboniferous sandstone, and Carboniferous limestone. The ore bodies occur, according to Arnold Hague, in four forms, all in the Devonian limestone: (1) in fissures crossing the anticlinal axis; (2) in contact deposits between the limestones and shales; (3) in beds or chambers in the limestone parallel to the stratification; (4) in ir- regular vertical and oblique seams across the bedding. The ore is chiefly chloride of silver in quartz gangue. It is thought by Mr. Hague to have probably come up through the main cross fissure, and, meeting the impervious shale, to have spread through the limestone in this way.' Egan Caflon is in the northern part of the county and shows a geological section of granite, quartzite, and slate in the order named. In slates, and perhaps extending into the quartzite, is a quartz vein five to eight feet wide carrying gold and silver ores. 1 E. P. Howell, Wheeler's Survey, III. 257. Gr. M. Wheeler, Report, Wheeler's Survey, 1869, p. 14. 2 S. F. Emmons, Survey of the Fortieth Parallel, Vol. III., p. 393. G. K. Gilbert, "On Belmont and Neighborhood," Wlieeler's Survey, III. 36. " J. E. Clayton, "Section of the Roclts at Hamilton, Nev.," Cal. Acad. Sci. A. Hague, Fortieth Parallel Survey, Vol. III., p. 409. 266 KEMP'S ORE DEPOSITS. Eureka County is the next county west of White Pine. The deposits at Eureka have already been described under " Lead-sil- ver " (Example 36). 2.11.16. Lander County lies next west of Eureka. The Toy- abe range runs through it from north to south and in its southern portion, in Ney County, contains the Belmont deposits. (See above, 2.11.14.) At Austin, which is 80 or 90 miles south of the Central Pacific Railroad, now connected with it by a branch, are the mines of the Reese River district, named from the principal stream near by. From Mount Prometheus, which consists of biotite- granite or granitite, and which is pierced by a great dike of rhyolite, a western granite spur runs out known as Lander Hill. The ore bodies are in this hill, and are narrow fissure veins with a general northwest and southeast trend, carrying rich ruby silver ores, with gray copper, galena, and blende, in a quartz gangue with associated rhodochrosite and calcite. They are also often faulted. At times they show excellent banded structure. Antimony has recently been found in this region.' (See under " Antimony.") 2.11.1V. Elko County lies north of White Pine and Eureka counties and contains the Tuscarora mining district. The depos- its are high-grade silver ores in veins, in a decomposed hornblende andesite.^ Humboldt County is the middle county of the northern tier, and contains a number of mining districts, which produce both sil- ver and gold from quartz veins in the Mesozoic slate. Small amounts of the precious metals come also from Washoe County, in the northwest corner of the State.' Churchill County adjoins Lander on the west and possesses a few silver mines. Esmeralda County, in the southwest, has a considerable num- ber of rich silver and gold mines, which produce high-grade ores from veins, with a quartz gangue in metamorphic rocks, slates, schists, etc. (See also under " Xickel.") 2.11.18. Storey and Lyon are two small counties in the west- ern central portion of the State, but the former contains the most important and interesting ore deposit in Nevada, if indeed it is not the largest and richest single vein yet discovered. 1 S. F. Emmons, Fortieth Parallel Survey, Vol. III., p. 349. 2 G. F. Becker, Tenth Census, Vol. XHI., p. 34. 3 Ibid., p. 33. SILVER AND GOLD, CONTINUED. 367 2.11.19. Comstock Lode. A great fissure vein, four miles long, forked into two branches above, along a line of faulting in eruptive rocks of the Tertiary age and chiefly andesites. In the central j)art of the vein the displacement has been about 3000 feet, shading out, however, at the ends. The ores are high-grade silver ores in quartz, and occur in great bodies, called " bonanzas," along the east vein. Over $325,000,000 in gold and silver has been extracted, in the ratio of two of the former to three of the ^lA CIT Y TlanX of W Davidson yxxxv'<;x'' yXXXX >''xX^ ^^fe^G; XXXXX XX" X "^ o ifXXXVXXXXX x^ ^ »xxyvxxxyx* X >» nXxxxxvxxX>^ 'o y x>'xx.xxxxxxxyyx y x>|x xxxx XX xyx>^ '>< X Jjy^2j?^x>xxxxyxx X X^ *^ ^ «XX JJx >?>"<^xxxyxxxxx>' x'" X ^,^, «XXXXXy^>'?JXX>< X y i ^"^ ^ X ^ X X X XV XX V ^5^ ^ ^ ,XXXyy>^J- 437. contain many leaf impressions of species thought by Lesquereux to be late Tertiary. The gravels also contain bones of extinct verte- brates, and have affoi-ded some authentic human remains and stone implements of good workmanship. The volcanic tuffs have been strong factors in modifying the original drainage lines. They have flowed into the ancient valleys in a state of mud and have then consolidated. 2.12.10. The richest gravels are those nearest the bed rock. In these the distribution of the gold is governed more or less by the character of the ancient channels. It favors the inside of bends and the tops of steeper runs. The gradients of the old channels were fairly high, often running 100 to 200 feet per mile. Gold has also been found by assay in pyrite that has been formed in the gravels since their deposition, and from this it is evident that the precious metal does circulate in solution with sulphate of THE PACIFIC SLOPE. 381 iron, but on this slender foundation some quite unwarranted chemical hypotheses for the origin of nuggets have been based. Substantially all the gold has been derived by the mechanical degradation of the quartz veins in the slate. 2.12.11. The depths to which the modern streams have cut out their channels below the old drainage lines have received con- siderable attention. Whitney avers that no disturbance has taken place since the old gravels were laid down, but Leconte thinks that there has been a tilting or elevation of the higher parts of the range, all moving as a block. Becker has recently shown in the I 2 3 ♦ S 6 7 e 9 10 II 12 13 14- 15 16 17 la 19 20 21 IZ 23 24- 25 26 27 Fig. 76. — Section of Forest Hill Divide, Placer County, California, to il- lustrate the relations of old and modern lines of drainage. After R. E. Browne, Rep. Cal. State Mineralogist, 1890, p. 444. high portions a great series of small north and south faults with uniform downthrow on the western side or upthrow on the east- ern. (See paper below, cited from Geological Society of America.) This is of varied intensity in different portions and is limited to the strip just west of the summit. It occurred in the Pliocene and increased the gradient of the streams where the present deep caQons occur, but had no effect near the plains, where the old and new channels are nearljr on the same level. 2.12.12. After the formation of the deep gravels and after the volcanic flows, glaciation took place in great extent over the mountain sides, but it was doubtless later in time than the glacial period of the East. References to the similar great development of the ice in Washington have already been made. Many hypoth- eses were early advanced to explain the deep gravels. They 2S2 KEMP'S ORE DEPOSITS. have been referred to the ocean, to ocean currents, and to glaciers ; but it is now well established that they are river gravels, formed when the rainfall was probably in excess of what it is to-day, and when the attitude of the land toward the ocean may have been different.' 2.12.13. The II. S. Geological Survey has been directing its attention in recent years to the geology of the gold belt in the Sierras in connection with the issue of atlas sheets, based on topo- graphic and geologic surveys. Several of these are practically complete, and they and the auxiliary papers which have resulted from the work have served to throw a flood of light upon the ob- scure problems of the geology of the Sierras. At the same time, as cited under subsequent paragraphs, other local workers have been active. The geological relations of the gravels as well as the solid strata have been made clear in greater detail than ever before. Waldemar Lindgren has discussed the geological history of the 1 G. F. Becker, "Notes on the Stratigraphy of California," Bull. 19, U S. Geo!. Survey. " Structure of the Sierra Nevadas," G. S. A., 11. 43. W. P. Blake, " The Various Forms in which Gold Occurs," Rep. Director of the Mint, 1884, p. 573. A. J. Bowie, Jr., "Hydraulic Miniog Iq Cali- fornia," M. E., VI. 37. E. E. Browne, "The Ancient Eiver Beds of the Forest Hill Divide," Rep. Cal. State Mineralogist, 1890, p. 435. Rec. T. Egleston, "Formation of Gold Nuggets and Placer Deposits," M. E., IX. 63. "Working Placer Deposits in the United States," School of Mines Quarterly, VII., p. 101. J. H. Hammond, "Auriferous Gravels of Cali- fornia,'' Rep. Director of the Mint, 1881, p. 616. Eec. Rep. Cal. State Mineralogist, 1889, p. 105. H. G. Hanks, "Placer Gold," Rep. Director of the Mint, 1882, p. 728. H. G. Hanks and William Irelan, Rep. Cal. State Mineralogist, Annual. T. S. Hunt, " On a Recent Formation of Quartz, and on Silicification in California," Engineering and Mining Journal, May 29, 1880, 869. J. Leconte, " The Old River Beds of California," Amer. Jour. Sci., iii., XIX. 80, p. 176. J. J. McGillivray, "The Old River Beds of the Sierra Nevada of California," iJep. Director of the Mint, 1881, p. 630. E. I. Murchison, " Siluria," etc. Contains a sketch of the distribu- tion of gold over the earth. J. S. Newberrj-, " On the Genesis and Distri- bution of Gold," School of Mines Quarterly, Vol. III.; Engineering and Mining Journal, Dec. 24 and 31, 1881. J. A. Phillips, " Notes on the Chemical Geology of the California Gold Fields," Philos. Mag., Vol. XXXVI., p. 321 ; Proc. Roy. Soc, XVI. 394 ; Amer. Jour. Sci., ii., XL VII. 134. B. Silliman, "On the Deep Placers of the South and Middle Yuba, Nevada County, California," Amer. Jour. Sci., ii., XL. 1. J. D. Whitney, " Auriferous Gravels of the Sierras," Cambridge, 1880. " Climatic Changes in Later Geological Times," Cambridge. THE PACIFIC SLOPE. 283 American and Yuba rivers in his valuable paper entitled, "Two Neocene Kivers of California" {Bull. Geol. Soc. of America, IV., 257-298, 1893). The conclusion is that the old divide in general coincided with the present one, but that the slope of the Sierra has been considerably increased since the time when the Neocene {i. e., Miocene and Pliocene) ante-volcanic rivers flowed over its surface. " It finally appears probable . . . that the surface of the Sierra Nevada has been deformed during this uplift, and that the most noticeable deformation has been caused by a subsidence of the portion adjoining the great valley, relatively to the middle part of the range." J. S. Diller has also discussed the same sub- ject, and for a wider range of country (Kevolution in the Topog- raphy of the Pacific Coast since the Auriferous Gravel Period, Journal of Geology, II., 32, 1894). Mr. Diller shows that the western side of the present Sierras formed in tne Eocene or Tejon times a gently-sloping base-level of erosion, with quiet streams and extensive superficial deposits of a residual character. The Sierras were from 4000 to 7000 feet below their present altitude. With the Miocene came a period of upheaval, of increased gradients and rapid denudation of the soft surface materials. The old auriferous gravels were thus formed in the stream channels while the lighter materials floated out to sea. The course of development is graph- ically traced out by Mr. Diller in accordance with our modern knowledge of stream-erosion and transportation. For Southern California Dr. A. C. Lawson has described a somewhat similar de- velopment in later geological time (The Post-Pliocene Diastroph- ism of the Coast of Southern California, Bull, of the Dept. of Geol., Univ. of Calif., I., 115, Dec, 1893), but as the region is not one of auriferous gravels, it is only cited here as of interesting correlative character. H. W. Turner has lately reviewed the whole stratigraphy of the region south of the fortieth parallel, has cor- related the new formational names adopted in the survey atlas sheets, has added many valuable notes on the petrography of the igneous rocks, and has outlined the sti'atigraphical relations of the gravels ("Geographical Notes on the Sierra Nevada," Amer. Geol- ogist , XIU ., ^2^ &n(i 221 , 1894). Mr. Turner distinguishes two series of Neocene river gravels (p. 241). 1st. The older gravels composed chiefly of white quartz pebbles and frequently capped by rhyolitic flows. These may be characterized in a broad way as the gravels formed before the volcanic period. 2d. A later series, con- taining volcanic pebbles chiefly of andesite and later in age than 284 KEMP'S ORE DEPOSITS. the rhyolitic flows. These may be called the gravels of the vol- canic period. Such gravels are often capped by andesite-tufE." Included fossil leaves indicate that the older gravels are Miocene, the later Pliocene. The Pliocene river gravels merge into shore gravels of the same age in Amador and Calaveras Counties. The pebbles in the shore gravels are quartzite, mica-schist, quartz-por- phyrite, granitoid rocks, andesite, and rhyolite, the last named being at times very abundant and characteristic. They appear to have been deposited along the shores of the great gulf which filled the central valley of California in these times. They now range as a general thing 500 to 700 feet above the sea. Later than the Pliocene gravels are the Pleistocene, both shore and river deposits. The former occur in the depressions between the Neocene and older hills and at u lower altitude, by one to several hundred feet. They seem to consist of the harder pebbles of the Pliocene gravels, the softer ones having been destroyed by abrasion. The Pleisto- cene river gravels lie usually less than 100 feet above the present streams, and also in remnants of the channels left behind by old changes of course. They and the shore deposits of this time are often highly auriferous. Several lake-bottoms of this period have been recognized where for some reason, such as the damming of a stream by a volcanic flow, or a probable orographic upheaval, the waters were set back. These lakes have left benches which mark their old shore lines. Finally, we have the recent stream gravels and alluvium. These papers show that the geological relations are more complex than was earlier known, but in their practical bear- ings the gravels can perhaps hardly be better grouped than into the Kiver gravels or placers, in the beds of running streams, and the High or Deep gravels, according to the old nomenclature. 2.12,14. Example 45. Gold Quartz Veins. Veins of gold- bearing quartz, usually described as segregated veins, in slates and other metamorphic rocks, and more or less parallel with the bedding. The quartz contains auriferous pyrite, free gold, arsenopyrite, chalcopyrite, tetrahedrite, galena, and blende, but pyrites is far the most abundant. Som-e tellurides have been noted by Silliman at Carson Hill, Calaveras County. The veins approximate at times a lenticular shape, which is less marked in California than in some other regions, and which shows analogies of shape with pyrites lenses (Example 16) and magnetite lenses (Example 12). In such cases the fissure-vein character is some- THE PACIFIC SLOPE. 285 what obscure. In California the veins occupy undoubted fissures in the slates. The largest and best known is the so-called Mother Lode, which is a lineal succession of innumerable larger and smaller quartz veins that run parallel with the strike, but which cut the steep dip of the slates at an angle of 10°. It was doubt- less formed by faulting in steeply dipping strata. The wall rocks of the California veins are serpentine, diabase, diorite, and granite, as well as slate, for all these enter into the western slopes of the Sierras. The serpentine is probably a metamorphosed igneous rook, while the diabase and diorite form great dikes. Considerable calcite, dolomite, and ankerite occur with the quartz, and very often it is penetrated by seams of a green chloritic silicate, which is provisionally called mariposite, as it is probably not a definite mineral, but rather an infiltration of decomposition products. The quartz veins vary somewhat in appearance, being at times milk white and massive (locally called " hungry," from its general bar- renness), at times greasy and darker, and again manifesting other differences, which are difficult to describe, although more or less evident in specimens. The richer quartz in many mines is some- what banded, and is called ribbon quartz. The quartz has been studied in thin sections, especially in rich specimens, by W. M. Courtis, who shows that fluid or gaseous inclusions of what is probably carbonic acid are abundant. In rich specimens the cavi- ties»tend to be more numerous than in poor, but more data are needed to form the basis of any reliable deductions. Some quartz showed evidence of dynamic disturbances. The walls of the veins are themselves impregnated with the precious metal and the at- tendant sulphides. The rich portions of the veins occur in chutes to a large degree. 2.13.15. The great Mother Lode is the largest group of veins in California. It extends 112 miles in a general northwest direc- tion. Beginning in Mariposa County, in the south, it crosses Tuolumne, Calaveras, Amador, and El Dorado counties in succes- sion. It is not strictly continuous nor is' it one single lode, but rather a succession of related ones, which branch, pinch out, run off in stringers, and are thus complex in their general grouping. Over 500 patented locations have been made on it. Whitney has thought it may have originated from the silicification of beds of dolomite, but others regard it, with greater reason, as a great series of veins along a fissured strip. The veins are often left in strong relief by the erosion of the wall rock, and thus are called 286 KEMPS ORE DEPOSITS. ledges, or reefs. Some discussion has arisen over the condition of the gold in the pyrite, but in most cases it is the native metal mechanically mixed, and not as an isomorphous sulphide. It has been detected in the metallic state, in a thin section of a pyrite crystal from Douglass Island, Alaska, as later set forth (2.13.04), and the fact that it remains as the metal when the pyrite is dis- solved in nitric acid makes this undoubtedly the general condition. The association of gold with bismuth, which has been shown by K Pearce to occur in the sulphurets of Gilpin County, Colorado (referred to on p. 212), and the difficulty experienced in amalga- mating some ores, indicate the possibility of other combinations. When crystallized, gold has shown, in one specimen and another, nearly all the holohedral forms of the isometric system, but the octahedron and rhombic dodecahedron are commonest. The veins are younger than any of the igneous dikes with them. They may have been filled, as thought by Whitney, during the metamor- phism of the rocks attendant upon their upheaval in post-Jurassic time. Certain it is that a very extensive circulation of siliceous solutions was in progress. For the gold in the similar veins of Australia a precipitation by organic matter has been urged. (See William Nicholas, "The Origin of Gold in Certain Victorian Reefs," Engineerhig and Mining Journal, Dec. 15, 188,3.) In the development of explanations of origin, hoAvever, a wide field for study yet remains.^ 1 M. Attwood, "On the Wall Rocks of California Gold Quartz and the Source of the Gold," iSep. Cal. Mineralogist, 18f8, p. 771 (tliought to be due to igneous injection in diabase). W. P. Biake, "On the Parallelism between the Deposits of Auriferous Drift of the Appalachian Gold Field and those of California," Amer. Jour. Sci., ii., XXVI. 128. "Remarks on the Extent of the Gold Region of Californi-i and Oregon," etc.. Ibid. ii., XX. 72. "The Carboniferous Age of a Portion of the Gold-bearing Rocks of California," Ibid., ii., XLV. 264. W. H. Brewer, reply to above, Ibid., ii., XLV. 397. A. Bowman, " Gei logy of the Sierra Nevada in Re- la! ion 1o Vein Mining,"' Jlfm. Resources West Rocky Mountains, 1875, p. 441. W. H. Brewer, " On the Age of the Gold bearing Rocks of the Pacifio Coast," Amer. Jour. Sci., ii., XLII. 114. F. O. Corning, "The Gold Quartz Mines of Grass Valley, California," Engineering and Mining Journal, Dec. 11, 1886, p. 418. W. M. Courtis, "Gold Quartz," M. E., 1889, Ottawa meetmg. H. W. Fairbanks, " Geology of the Mother Lode," Tenth Ann. Rep. Cal. Mineralogist ; also in briefer form in Amer. Geol., April, 1891, p. 201. Rec. "On the Pre-Cretaceous Rocks of the California Coast Ranges," Amer. Oeol., March, 1892, February, 1893. J. H. Hammond, THE PAOmO SLOPE. 287 2.13.16. In rare instances the gold is associated with some otlier gangue tlian quartz. Thus in Vol. XIII., p. 24, of the Tenth Census, G. F. Becker records gold in calcite, in the Mad Ox mine of Shasta County, where the hanging wall is a siliceous limestone. J. S. Diller has cited a similar case from Minersville, Trinity County. The gold occurred in veinlets of calcite in a dark, carbonaceous shale [Amer. Jour. Sci., Feb., 1890, p. 160). Waldemar Liud- gren* has described an instance of gold with some silver occurring in seams of barite, which were themselves in a kaolinized zone in diabase and diabase-porphyrite. In the kaolin 0.34^ Ba SO^ was determined by analysis. It may have been derived from the feld- spar of the original diabase. "W". F. Hillebrand^ has lately shown the wide distribution of both barium and strontium. Through the kindness of Mr. Leo von Eosenberg, the writer (J, F. Kemp) has had the opportunity to examine a suite of ores from the Shaw mine, El Dorado County, which have been donated to the School of Mines. The same had been previously examined by H. W. Turner, of the U. S. Geol. Survey, by whom the determinations were originally made. The mine is based on a dike of porphyrite, sixty or seventy feet thick and charged with pyrites. It is auriferous throughout, but richest next the walls. The gold in the native form occurs in veinlets of albite, which ramify through the por- " Mining' of Gold Ores in California," Tenth Ann. Rep. State Mineralogist, p, 8.58. Eec. P. Laur, " Du Gisempnt et de I'Exploration de I'Or en Cali- fornie," Ann. des Mines, Vol. III., 1863, p. 412. G. W. Maynard, "Re- marks on Gold Specimens from California," M. E., VI. 451. J. S. New- berry, " On the Genesis and Distribution of Gold," School of Mines Quar- terly, III., p. 16. A. Eemond, "Mining Statistics," No. 1, Cal. Geol. Survey (tabular statement of quartz mining and mills between the Merced and Stanislaus rivers). J. A. Phillips, "Mining and Metallurgy of Gold and Silver," Wiley, N. Y.; also treatise on Ore Deposits, p. 534. Rec. C. M. Rolker, " The Late Operations in the Mariposa Estate," M. E., VI. 145. B. Silliman, "Notice of a Peculiar Mode of Occurrence of Gold and Silver in the Foothills of the Sierra Nevada, California," Amer. Jour. Sci., ii., XLV. 93; Cal. Acad. Sci., Vol. III., p. 333. H. M. Turner, review of recent papers by H. W. Fairbanks and others on California geology, in Amer. Geol, June, 1893. Rec. J. D. Whitney, Cal. Geol. Survey, Geol- ogy, Vol. I., p. 313. J. S. Wilson, "On the Gold Regions of California," Quar. Jour. Geol. Sci., Vol. X., p. 808, 1854. iW. Lindgren, "The Gold Deposit at Pine Hill, Calif.," Amer. Jour. Sci., Aug., 1893, p. 91. 2 W. F. Hillebrand, ' 'The widespread Occurrence of Barium and Strontium in Rocks," Jour. Amer. Chem. Soc, Feb. , 1894, p. 81. 288 KEMP '3 ORE DEPOHITS. phyrite. An analysis by Mr. Hillebrand established the identity of the albite.' T. A. Eickard'' has called attention to the especial richness of gold at the intersection of small quartz veins in Tuol- umne and Calaveras Counties, California, and to the occurrence of a particularly rich pocket in the Rathgeb mine, San Andreas, where a small vein was faulted a few inches, and where the gold was associated with pitch-blende or uranite, and uranium ochre.' 2.13.17. The recent work of T. A. Rickard,* both descriptive and theoretical, on the remarkable saddle-shaped auriferous quartz deposits of Bendigo (or Sandhurst), Victoria, which are locally called "saddles," has led to an extended and interesting discussion regarding the origin of auriferous quartz, and the source of the gold. All must agree in attributing the origin of the quartz to more or less heated solutions penetrating along fault-cracks, planes of schistosity or bedding planes, but whether the gold comes up from below, or from the adjacent walls, is the old point of differ- ence between the lateral-secretionists and the infiltration-ascen- sionists. Mr. Eickard, in the case in point, attributes it to gold deposited from the ocean in the original marine sediments of the walls, and instances the salts of iodine in sea-water as the original solvent, subsequently the release of iodine contained in the brines which soaked the sediments, and in the fucoids, etc., likewise in the sediments, facilitated the migrations of the gold to the veins. This emphasizing of iodine is somewhat new, and while not to be denied on theoretical grounds, yet the question ultimately becomes the point of difference between the two views noted above. In the discussion of the paper Philip Argall gives a very complete review of the experiments and observations, hitherto recorded, re- garding the chemistry of gold in nature. 1 Since the above was written Mr. Turner has published the results of his examination of this ore , as weU as many additional important notes on the associates of the gold. (H. W. Turner, "Notes on theGrold Ores of California," Amer. Jour. ScL, June, 1894, p. 467.) Mr. Turner also cites gold in quartz in rhyolite , and gold with, cinnabar. ^ T. A. Rickard , ' ' Certain dissimilar Occurrences of Gold-bearing Quartz," Proc. Colo. Sci. Soc, Sept. , 1893, pp. 6-9. ' Henry Lewis has given a very complete review of the associates and occurrence of gold in the Mineralogical Magazine, X. , 241, London, 1893. 4 T. A. Rickard, "The Bendigo Gold Field, " Trans. Amer. Inst. Min. Eng., XX., 463, Oct., 1891 ; XXI., 686, 1892. "Origin of the Gkild-bear- THE PAGIFIG SLOPE. 289 2.13.18. The stratigraphy of the auriferous strata in the Sierras was briefly referred to above as involving Paleozoic and Mesozoic strata. It would be impossible and undesirable to give in this place any complete bibliography of the subject, but in the papers of Diller,* J. P. Smith^ and Turner', cited below, quite full references are to be found to earlier work. In the atlas sheets of the U. S. Geol. Survey local names are given to the various forma- tions, which are classified on the physical basis as outlined in the introduction (l.Ol.Ol), but as regards geological time, strata have been identified as follows: Pre-Silurian crystalline schists; Silurian quartzite and slate, with included lenses of limestone; Devonian coralline limestone; probably both Lower and Upper Carboniferous argillite, quartzite, mica-schist, and metamorphosed tuffs; various Triassic and Jura-trias sediments more or less metamorphosed; Jurassic slates; Cretaceous (Chico) sandstone; Tertiary and Qua- ternary sandstone, sands, gravels and clays. (See paper of H. W. Turner, cited below, pp. 328-249. Also Diller op. cit.) In the auriferous belt, .J. P. Smith has admitted the presence of Silurian, Carboniferous, Triassic and Jurassic strata, but rejects Cretaceous. Our knowledge has also increased of late regarding the intru- sions of granite and the relations of the various sedimentary forma- tions to the old basement upon which they were laid down. The work of H. W. Fairbanks, often cited in the text, and that of the U. S. geologists, Becker, Diller, Turner and Lindgren, have been bringing out forcibly the intrusive nature and Mesozoic age of much of the granite of the Sierras and of the Coast Range. Most recently among the Canadians Gr. M. Dawson has traced sim- ilar effects to the north, and A. C. Lawson * from an extended survey of the western coast and search in the literature of Mexico, Central and even South America, forcibly portrays the advance of ing Quartz of the Bendigo Reefs, Australia," Idem, Aug., 1893; and discussion of same. 1 J. S. Diller and Charles Schuchert , ' ' Discovery of Devonian Rocks in Calif.," Amer. Jour. Sci., June, 1894,416. 2 J. P. Smith, "Age of the Auriferous Slates of the Sierra 'Ne- yaAa," Bull. Geol. Sac. Amer., V., 343,1894. » H. W. Turner, "Greological Notes on the Sierra Nevada," Amer. Geol, April and May, 1894, 338-297. * A. C. Lawson, ' ' The Cordilleran Mesozoic Revolution, ' ' Journal of Geology,!., 579, 1898. 290 KEMP'S ORE DEPOSITS. the great granitic "batholites" (t. e., plutonic masses) toward the surface, the fusing into their magmas of the overlying strata, and the metamorphic effects. All these cannot but be strong fac- tors to consider in connection with the ore bodies, and as time goes on this connection will probably be shown. In regard to the other forms of igneous rocks involved in the gold belt and often greatly metamorphosed, we are advancing rap- idly in knowledge. These were referred to earlier under 3.13.13, but in his review of the igneous rocks Mr. Turner {Amer. Geol., May, 1894, pp. 297-316) cites nearly the entire series of plutonic and effusive types. In many instances the more basic members have passed, under the influence of dynamo-metamorphism, into amphibolites and talcose rocks, but in other cases the dikes and sheets are still little if at all changed. Great areas are formed of them or involve them, and lead to the inference that they have not been without their influence in stimulating ore-bearing circulations. CHAPTER XIII. GOLD ELSEWHERE IN THE UNITED STATES AND IN CANADA. 2.13.01. Example 45a!. Southern States. (1) Gold quartz veins (segregated veins) in metamorphic slates, talcose schists, etc., of late Archean or early Paleozoic age, with numerous as- sociated trap (diabase) dikes. (2) Beds of auriferous slates, gneiss, feldspathic and hydromica schists, and even limestone. The general geology of the southern Atlantic States has been outlined in the introduction. Reference may again be made to the Coastal Plain of Quaternary, Tertiary, and ^Mesozoic rocks, and to the Archean strip back of this. In the latter are found the gold de- posits. At times they resemble the Western quartz veins, but they are also extremely diverse in character, and involve almost every sort of rock. Gold has even been found in a trap dike by Genth. It is generally in pyrite, and the rock, where productive, is heavily charged with this mineral. The trajj dikes have also exerted an important influence, and in some localities, as at the Haile mines, South Carolina, the rock is rich only near them. They have probably stimulated the ore-bearing solutions. The belt of aurif- erous rocks begins in Maryland, although gold is known in the States farther north. It runs with varying width into Alabama, where it terminates. It reaches a maximum of VO miles in Korth Carolina. The country rock in these unglaciated regions is often covered to a great depth by the residual clays and other products of its alteration which are as much as 100 feet in places. This substance is sometimes called laterite. Where the original rocks have been auriferous they have furnished loose material for panning and washing, which is essentially different from the Western placers. It gradually works down hill, and has been called by Kerr "frost drift." The ores of the Southern States are gen- 292 KEMP'S ORE DEPOSITS. erally low grade, and need careful management to be made profit- able.^ 2.13.03. Example 455. In the fundamental complex (3.C3.17) north of the iron region at Ishpeming gold occurs at the Ropes mine in reticulations of pyritous quartz and country rock at the contact of a great intrusion of peridotite and greenstone schist. Other lees developed locations are on quartz veins in the schist.^ ALASKA. 2.13.03. Geology. — Our knowledge of the geology of Alaska is very fragmentary, and is chiefly obtained from the reports of ex- ploring expeditions along the coast and up the Yukon River. The Cretaceous and Tertiary rocks of Washington and of British America extend north into the southern portion. Igneous rocks 1 W. P. Blake, A. Eaton, D. Olmstead, C. U. Shepard, the elder Sllli- man, and others have made many references to gold in the Southern States in the early numbers of the American Journal of Science. H. M. Chance, " Auriferous Gravels of North Carolina," Amer. Philos. Soc., July 15, 1881, p. 477. H. Credner, " Report of Explorations in the Gold Fields of Virginia and North Carolina," Amer. Jour, of Mining, 1868, pp. 361, 877, 398, 407. W. B. Devereux, "Gold and its Associated Minerals at Kings Mountain, North Carolina," Engineering and Mining Journal, Jan. 15, 1881, p. 89. S. F. Emmons, "Notes on the Gold Deposits of Montgomery County, Mary- land," June 11, 1881, p. 397. F. A. Genth, " Contributions to Mineralogy," Amer. Jour. Sci., ii., XXVIII, 246. F. C. Hand, " Southern Gold Fields,'' Engineering and Mining Journal, Dec. 7, 1889, p. 495. G. B. Hanna, " Fineness of Native Gold in the Carolinas and Georgia," Ibid., Sept. 18, 1886, p. 201. W. C. Kerr, " Gold Gravels of North Carolina," M. E., VIII. 463. " Some Peculiarities in the Occurrence of Gold in North Carolina," M. E., X. 475 ; also Geological Report on North Carolina, 1875. O. M. Lieber, " Ueber das Gold-vorkommen in North Carolina," Gangstudien, Vol. III., p. 353. Lieber states that Whitney's Metallic Wealth was writ- ten to "boom " certain mines ! " Gold in South Carolina," Oangstudien, Vol. III., pp. 353, 481. P. H. Mell, " Auriferous Slate Deposits in South- ern Mining Regions," M. E., IX. 399. W. B. Phillips, "The Lower Gold Belt of Alabama," Bull. No. 3, Geol. Survey Ala., 1893. E. G. Spillsbury, " Gold Mining in South Carolina," J/. E., XII. 99; Engineer- ing and Mining Journal, June 23, 1883, p. 363. A. Thies and W. B. Phillips, "The Thies Process, etc., at the Haile Mine, South Carolina," M. E., September, 1890. A. Thies and A. Mezger, " Geology of the Haile Mine," M. E., September, 1890. ^ C. D. Lawton, Rep. Mich. Com. of Mineral Statistics, 1887, p. 167. "The New Michigan Gold Field," Engineering and Mining Journal, Sept. 22, 1888, p. 338. M. E. Wadsworth, Am. Rep. Mich. State Geologist, is- sued January, 1893. GOLD ELSEWHERE IN UNITED STATES AND CANADA. 293 often pierce them. Tertiary coals are recorded from several local- ities in the ai-chipelago in the southern part. The Aleutian Isl- ands mark a long stretch of volcanic eruptions. W. H. Dall has given a general section of the banks of the Yukon River from the British boundary to the delta. There are, in rough order from east to west, granite, talcose slates, and Azoic rocks, 150 miles ; sandstone and conglomerate, 250 miles ; shales with one small coal seam, 75 miles ; blue slate, conglomerate, eruptive rocks, slate, eruptive rock, blue slate, and black sandstone, 325 miles ; blue sandstone, slate, trap, blue and black slate, volcanic rock, to the northwest mouth. The interior is largely composed of tundras, or great plains of moss and other plants, frozen into perpetual ice at a depth of a foot or so. These hide the geology. Doubtless the slates of the upper waters have supplied the gold, which is rich in some of the river gravels. On the Aleutian Islands some brown Miocene sandstones are seen (Shumagin), and granite and meta- morphic rocks. ^ 2.13.04. Example 46. Douglass Island. A dike or boss of granite 400 feet wide, piercing slates regarded as Triassic by G. M. Dawson, and impregnated (i.e., the granite) with auriferous pyrites. This enigmatical ore body is thought by Dawson to be the upper part of a granite dike. It consists in great part of a mass of quartz, feldspar, calcite, and pyrite, in which are buried the so- 1 " Alaska as a Mining Territory," Engineering and Mining Journal, June 37, 1885, p. 444. "Mineral and Asrricultural Wealth of Alaska," En- gineering and Mining Journal, Aug. 24, 1887, p. 134. T. A. Blakn, Rep. on the Geo), of Alaska, Ex. Doc. No. 177, Fortieth Congress, New Serie.o, p. 314, Washington, 1868. W. H. Dall, "Explorations in Alaska,'' ^mer. Jour. Sci., ii., XLV. 96. Rec. "Notes on Alaska and the Vicinity ot Bering Straits," Ibid., in., XXI. 104. " Notes on Alaska Tertiary Deposits, GeologicalSeotionoftheShumaginIslands,"I6id.,!ii., XXIV. 67. "Alaska and its Resources," Washington, 1870. Rec. "Glaciation in Alaska," Bull. Phil. Soc, Vol. VI., p. 33, Washington, 1884. G. H. Dawson, "Re- port on the Yukon District in 1887," Geol. Survey of Canada, 1887-88, Vol. III., Part B, pp. 14B-18B, 154B-156B. H. W. Elliot, "Our Arctic Provinces," p. 163, New York, 1887. E. J. Glave, "Pioneer Packhorses in Alaska," The Century, September and October, 1892. R. G. McConnell, "Glacial Features of Parts of the Yukon and Mackenzie Basins," Geol. Soc. of Amer., L, p. 540. I. C. Russell, " The Surface Geology of Alaska," Geol. Soo. of Amer., I., p. 99. E. R. Skidniore, "Alaska," Rep. Director of the Mint, 1883, p. 17, and 1884, p. 17. J. Stanley-Brown, "Auriferous Sands at Yakutat Bay, Alaska," Nat. Geog. Mag., Vol. III., 1891. 294 KEMP'S ORE DEPOSITS. called kernels, which have been shown by F. D. Adams to be mass- es of less altered granite, almost without pyrite. Both varieties show abundant cataclastic or crushed structure, as an evidence of having suffei'ed from dynamic movements. Adams concludes that the mass was originally a hornblende granite that has been sub- jected to solfataric action, which has brought in the gold. The gold in itself is in irregular masses in the pyrite. The Treadwell mine, located here, is very extensive, and the chief source of Alaska bullion.' 2.13.05. Example 45e. Nova Scotia. The southeastern por- tion of Nova Scotia is composed of Cambrian slates. They stretch from Canso to Yarmouth, and, together with associated granites, cover from 6000 to 7000 square miles. There are two well-marked divisions. The upper, 3000 feet thick, consists of dark pyritous slates, with beds of quartzite and small irregular veins; the lower, 8000 feet thick, has quartzites, sandstones, and slates, which in parts contain the veins. The slates are folded along east and west axes. The veins are not large, averaging from 4 to 8 inches, while 20 inches is very exceptional. The gold is both free and associated with the usual sulphides, among them often mispickel. The assays are such that with careful working the mines pay good returns.^ 1 F. D. Adams, " On the Microscopical Character of the Ore of the Treadwell Mine, Alaska," Amer. Geol., August, 1889, p. 88. G. M. Daw- son, "Notes on the Ore Deposits of the Treadwell Mine, Alaska," Amer. Geol. , August, 1889, p. 84. Mining and Scientific Press, San Francisco, Sept. 27, Oct. 4, 1884. 2 J. W. Dawson, " On Recent Discoveries of Gold in Nova Scotia," Canadian Naturalist and Oeologist, December, 1861. E. Gilpin, Jr., "The Nova Scotia Gold Mines," M. E., XIV. 674. Eec. H. Y. Hind, "Report on the Mount Uniache, Oldham, and Renfrew Gold Mining District," Hali- fax, 1872 ; Amer. Jour. ScL, iii., IV. 497. D. Honeyman, "On the Geol- ogy of the Gold Fields of Nova Scotia," Quar. Jour. Geol. Sci., Vol. XVIII., p. 842, 1862. T. S. Hunt, "On the Gold Region of Nova Scotia," Can. Geol. Survey, 1868 ; Canadian Naturalist, February, 1868. W. E. Logan, " Notes on the Gold of Eastern Canada," Can. Geol. Survey, 1864. O. C. Marsh, "The Gold of Nova Scotia," Amer. Jour. Sci., ii., XXXH. 395. A. Michel and T. S. Hunt, "Report on the Gold Region of Canada," Can. Geol Survey, 1866. H. S. Poole, "The Gold Leads of Nova Scotia," Quar. Jour. Geol. Sci., Vol. XXXVL, p. 307. A. R. C. Selwyn, " On the Gold Fields of Quebec and Nova Scotia," Can. Geol. Survey, 1870-71, pp. 252-389. B. Symons, " The Gold Fields of Nova Scotia," Trans. Min. Asso. and Inst. Cornwall, III. 80, 1898. GOLD ELSEWHERE IN UNITED 8TA TES AND CANADA. 295 2.13.06. Example 45c?. Gold elsewhere in Canada. At the headwaters of the Chaudi^re River, in eastern Quebec, auriferous gravels have been located, and also quartz veins in the raetaraor- phic rocks. They have been vs^orlfed to a small extent. Gold oc- curs in many places north and west of Lake Superior in the region of the Lake of the Woods. Some small mining has been carried on. An interesting and important vein, carrying auriferous mis- pickel in quartz, occurs in Marmora, Hastings County, just north of Lake Ontario. It is more fully described under " Arsenic," as it is the one American source of that metal. Auriferous gravels occur in British Columbia in not a few places and are being worked. They are also found along the disputed boundary of Alaska, and scattered reports of their existence have reached civ- ilization from the Mackenzie River and the remote Northwest.' 2.13.07. The following table gives an idea of the relative im- portance of the several States. Full details of the United States and other countries are given in the Annual Reports of the Di- rector of the Mint, the Mineral Mesources of the United States Geological Survey, and the annual statistical number of the En- gineering and Mining Journal. 1881. 1890. Snvur. Gold. Silver. Gold. Alaska $15,000 . $9,697 $763,500 Arizona $7,800,000 1,060,000 1,293,929 1,000,000 California 750,000 18,300,000 1,168,636 13,500,000 Colorado 17,160,000 3,300,000 34,307,070 4,150,000 Dakota 70,000 4,000,000 139.393 8,200,000 Georgia 125,000 517 100,000 Idaho 1,300,000 1,700,000 4,788,888 1,850,000 * " Descriptive Catalogue of ihe Economic Minerals of Canada at the Colonial and Indian Exhibition," London, 1886, p. 54. " The Marmora Gold Mine," Engineering and Mining Journal, Oct. 23, 1880, p. 366. R. Bell, "Mineral Resources of the Hudson Bay Territories," M. E., Febru- ary, 1886. E. Coste, "Report on the Gold Mines of the Lake of the Woods," Rep. Prog. Can. Survey, 1883-84, K, 3-32. W. M. Courtis, "Animikie Rocks and their Vein Phenomena as shown at the Duncan Mine, Lake Su- perior," M. E., XV. 671. R. W. Ells, " Mining Industries of Eastern Que- bec," M. E., October, 1889. T. S. Hunt, "On Gold in the Laurentian Rocks of Canada,'' A. A. A. S., XVIIth meeting. A. Michel and T. S. Hunt, "Report on the Gold Regions of Canada," Can. Oeol. Survey, 1866- 68. R. P. Roth well, "The Gold-bearing Mispickel Vein of Marmora, On- tario," M. E., IX. 409. A. Blue, "The Gk)ld-mining Industry in Canada in 1893," Engineering and Mining Journal, June 16, 1894, p. 558. 296 KEMP'S ORE DEPOSITS. 1881. 1890. Silver. Gold, Silver. Gold. Montana $3,630,000 $3,330,000 |30,363,686 $3,300,000 Nevada 7,060,000 3,250,000 5,753,535 2,800,000 New Mexico 375,000 185,000 1,680,808 850,000 North Carolina 115,000 7,757 118,500 Oregon 50,000 1,100,000 96,969 1,100,000 South Carolina 35,000 517 100,000 Utah 6,400,000 145,000 9,050,505 680,000 Washington 120,000 90,505 204,000 Other States 5,000 20,000 461,574 130,000 Total $43,000,000 $34,700,000 $70,485,714 $82,845,000 A glance at the table will indicate where the heaviest pro- ducers and most important districts are situated. In the next few years a heavy falling off in silver and a relative increase in gold seems inevitable. CHAPTEE XIV. THE LESSER METALS: ALUMINIUM, ANTIMONY, ARSENIC, BISMUTH, CHROMIUM, MANGANESE. ALUMINIUM. 2.14.01. The importance of aluminium grows with improved and cheaper methods of production. Its sources are, or have been, alums, either natural or artificial, corundum, cryolite, kaolin and bauxite. The first of these is formed in nature by the decay of pyrite in shales and slates, and is little if at all used as an ore at present. The second is more valuable as an abrasive, and with the fall in the price of the metal has given way to other and cheaper ores. Still corundum (AljOj) with 53.3 Al, is the richest natural mineral. Cryolite and bauxite are now the staple ores, but in the Grabau process kaolin is employed, although not as yet in any such amount as these other two. The fused cryolite plays the r61e of a bath in which the alumina is dissolved and reduced by electrolysis, so that really bauxite has come to be the principal source. Cryo- lite occurs as an immense bedded deposit in gneiss at Evigtok, on the Arksut Fjord, Greenland. It is mined as an open cut, and being near the water's edge, on a steep cliff, after hand-picking, it is loaded directly upon vessels, which moor to the cliff. The cryo- lite is associated with various related minerals, all rare and mostly limited to this locality, with sulphides of iron, copper and lead, and with siderite. The Pennsylvania Salt Co., of Natrona, Pa., receive by contract two-thirds of the output, the remaining third going to Denmark. The other localities of this mineral at Miask, in the Urals, and near Pike's Peak, Colo., are small and commer- cially unimportant pockets. Cryolite when pure contains 13.02 Al, and of itself is tlius a very low grade ore.' 1 On the geology of Greenland Cryolite see G. Hagennann, ' ' On some Minerals associated with the Cryolite in Greenland," Ainer. Jour. ScL, ii., XLIL, 93. C. Hart, "On the Cryolite Deposit, " Joaninl of Analytical aad Applied Chemistry, Oct., 1893. G. Lunge, in the treatise entitled ' ' The Manufacture of Sulphuric Acid and Alkali. ' ' J. W. Tay- lor, " Cryolite of Evigtok, " Quar. Jonr. Geol. Sac, XII., 140. See also the ' ' Mineral Industry, ' ' Vols. I. and II. , and a pamphlet published by the Pennsylvania Salt Manufacturing Co. 298 KEMP'S OBE DEPOSITS. Bauxite (AI2O3, SH^O) is now the main source of the metal. In the pure condition and of the composition given above it contains AI2O3, 65.55, or Al, 34.94, but various impurities are always with it, of which the commonest are silica, oxide of iron, oxide of man- ganese, carbonates of lime and magnesia, phosphoric acid, and, in the Southern States, small but constant amounts of titanic acid. The merchantable ore ranges from about 40 to over 60^, or even over 70^ AI2O3, but any analysis over 65.55^ AI2O3 indicates a mineral of diflerent composition from AljOs SH^O. There is no doubt that such exist, and in an interesting paper entitled "The Bauxites; A Study of a new Mineralogical Family," M. Francis Laur^ has advocated that there is a whole series of hydrated com- pounds of alumina belonging here, as complex, perhaps, as the anhydrous compounds of this metal. Bauxite is now known to occur in economic quantities in Georgia and Alabama, and in Arkansas. It has been mentioned, however, from numerous other points in States immediately north of these two. The deposits in Georgia and Alabama^ occur along a narrow belt in the Coosa Valley, extending some sixty miles from Adairsville, Ga., to Jack- sonville, Ala. The mineral itself is pisolitic or oolitic in structure, as a general thing, and the individual masses are often in concentric layers, and are held together either by non-oolitic bauxite or by silica. Less often the ore is more massive, and may be in fairly hard lumps or soft and earthy. The surface ore is often pitted and cellular. The general geological relations will be best understood by referring to Figure 4, p. 18. The region is largely formed by Cambrian strata, of which the Connasauga shales are the upper member, and the Eome sandstone, or Weissner qnartzite, is the lower. Above the Cambrian is found the Silurian Knox dolomite, rich in chert. These strata are broken by folds and faults of sev- eral series and formed at different periods. The great overthrust ' Trans. Amer. Inst. Min. Eng., Feb., 1894. 2 C. W. Hayes, ' ' Greologioal Eelations of the Southern Appalachian Batixite Deposits, " Trans. Amer. Inst. Mir).. Eng., Feb., 1894. Reo. H. McCalley, "Alabama Bauxite," Proc. Ala. Indust. and Sci. Soc, 1893. "Ba-axite'' in "The 3Iineral Industry," U., 57, 18H. Bee. Also in a forthcoming report of the Ala. Gteol. Sxirvey. E. Nichols, ' ' An Almninimn Ore : Bauxite," Trans. Amer. Inst. Min. Eng., XVI., 905. R. L. Packard, "Altmiinium., " Mineral Resources, 1891, 147. J. W. Spencer, ' ' Greology and Resources of Ten Counties in N. W. Gieorgia, ' ' p. 310, 1893. Rec. THE LESSER METALS. 399 shown in Pig. 4. is of post-Carboniferous time, long after the prin- cipal Appalachian upheaval. 0. W. Hayes has shown that the ore bodies lie along certain of these fault lines, and the association gives us a possible clue to their method of deposition. The ores are always found in the residual alteration products of the Knox dolomite, from which, however, they are quite sharply separable. The accompanying cross-section shows the relations. While more or less irregular in shape they have proved quite persistent, and many years' supply is now in sight. Mr. Hayes suggests that the crushing attendant on the faulting developed great heat, and that atmospheric waters penetrating along these zones became charged with sulphuric acid, derived from decomposing pyrite. The acid would dissolve alumina from the Connasauga shales, possibly form- \ DRAINAnF n-Tfu • \^^-, Fig. 77. — Cross-section of a Bauxite deposit in Georgia. After C. Willard Hayes, Trans. Amer. Inst. Min. Eng., Feb., 1894. ing alums, with some alkali. Calcium carbonate would react on such solutions so as to precipitate hydrate of alumina, and this ris- ing as a flocculent precipitate in springs gave rise to the oolitic and pisolitic deposits, which were afterward, in the decay of the Knox dolomite, involved in its residual products. The explana- tion is reasonable and has great claims to confidence. The same may be applied to the neighboring limonites. The deposits in Arkansas have been less fully described as yet. They occur near Little Eock, in Pulaski County, and near Benton, in Saline County, and aggregate about one square mile. The ore is pisolitic, and is interbedded in Tertiary sandstone, but it is only found in the vicinity of intruded syenites. At times the bauxite is high in iron. J. F. Williams rather favored a method of origin from hot springs, regarding this as more tenable than that the ores were derived from the superficial decay of the -syenite. In this re- spect C. W. Hayes is in accord with him. The Arkansas deposits 300 KEMP 'S ORE DEPOSITS. have not shipped as much as those in tlie South, owing doubtless to their more remote situation.' Bauxite is employed for many other purposes besides furnishing an ore of aluminium, as this is one of its later adaptations. Great quantities are used to produce alums, and as a refractory material it has long been appreciated. In the earlier development of the aluminium industry corun- dum was somewhat sought as an ore. The varieties with vitreous luster and light colors are called sapphire, the duller and more smoky ones, corundum, while the impure kinds, which are mixed more or less with magnetite, hematite, spinel, etc., pass under the name of emery. The last named is of no importance in this con- nection. Some sapphire and corundum have been obtained in Chester County, Penn., but, practically the only source of any mo- ment is in a belt of a curious rock called dunite, which consists of grains of olivine, and which traverses western North Carolina and Georgia. The corundum occurs along the contacts of the dunite and a hornblende gneiss with which it is associated. It lies in scattered lumps distributed through decomposed micaceous mate- rial which is at times so soft as to be washed out in the hydraulic way. The mineral appears to have resulted from some reactionary effects of the two rocks, or of solutions emanating from them, on each other. The gneiss is aluminous, the dunite magnesian.^ 1 J. C. Branner, "Bauxite in Arkansas," Airier . Oeol., VII., 181, 1891. An extended report was annoxmced for Vol. I., 1889, of Dr. Branner's Annual Reports as State Greologist of Arkansas, but it has not yet (1894) been issued. J. Francis Williams, Ann. Rep. Oeol. Siirv. Ark., 1880, II., 134. 2 T. M. Chatard, Mineral Resources, U. S. Geol. Sun:, 1883-84, 714. Rec. ' ' The Gneiss-Dunyte Contacts of Corundum Hill, N. C. , " etc. , Bull. U. S. Geol. Surv., XLII. 45, 1881. Rec. Short abstract in the Eng. and Min. Journal, July 31, 1888, p. 46. J. P. Cooke, Proc. Amer. Acad., IX. 48, 1874. F. A. Genth, "Corundum, Its Alterations and Associated Minerals, " Amer. Phil. Soc, Sept. 19, 1873; July 17, 1874; Amer. Jour. Sci., iii., VI. 461, 1873. T. S. Hunt, Trans. Roy. Soc. Canada, U. 1884. C. W. Jenks, Quar. Jour. Geol. Soc, XXX. 303, 1874. A. A. Julien, Proe. Post. Soc. Xat. Hist, XXH. 131, 1893. W. C. Kerr, ' ' Geol. of North Carolina, Supplement, ' ' 64, 1875. R. W. Ray- mond, "Jenks' Corundum Mine, N. C," Trans. Amer. Inst. Min. Eng., VII., 88, 1878. C. U. Shepard, "On the Corundum Region of N. C. and Ga. , " Amer. Jour. Sci. , iii. , IV. 109, 175, 1873. Rec. C. D. Smith, "Geol. N. C. I., Appendix D.," 91, 1875, II. 43, 1881. J. L. Smith, "Notes on the Corundum of N. C. , Ga. ," etc., Amer. Jour. Set., iii., VI., 180, 1873. Rec. M. E. Wadsworth, Mem. Mm. Comp. ZooL, XL Part I., p. 118, 1884. THE LESSER METALS. 301 ANTIMONY. Senarmontite, SbjOj ; Sb. 83.56 ; 0.16.44. StibnitG (Antimonite, Antimony Glance), SbjSj ; Sb. Vl.8 ; S. 28.2. 2.14.02. Antimony occurs in composition with several silver ores, but almost its sole commercial source is stibnite. The oxide, senarmontite, is rarely abundant enough to be an ore. Stibnite was one of the minerals formerly cited as having originated in veins by volatilization from lower sources. But it has probably, in all cases, been derived from solutions of alkaline sulphides. 2.14.03. Example 47. Veins containing stibnite, usually in quartz gangue. California, Kern County. At San Emigdio a vein of workable size has been found. It has a quartz gangue and is in granite. The vein varies from a few inches to several feet across, and has afforded some metal. Several others are known in San Benito and Inyo counties. 2.14.04. Nevada, Humboldt County. Stibnite has been known for some years in veins with quartz gangue. The Thies-Hutchens mines, about 15 miles from Lovelock station, were productive in 1891. Lander County. The most important of the American mines are the Beulah and Genesee, at Big Creek, near Austin. The vein is reported as showing three feet of nearly pure stibnite. It produced 700 tons of sulphide in 1891, and was operated in 1892. 2.14.05. Arkansas, Sevier County. Stibnite occurs in veins with quartz gangue in southwestern Arkansas. Some attempts have been made to develop them, but the ore is rei^orted to be too remote for profitable working. The veins appear to be generally interbedded in Trenton shales and to lie along anticlinal axes, which trend northeast. They are all controlled by the United Slates Antimony Company of Philadelphia. 2.14.06. New Brunswick, York County. Veins of quartz or quartz and calcite, carrying stibnite, occur over several square miles. The wall rocks are clay slates and sandstones of Cambro-Silurian age. The mines have been commercially productive. The veins vary from a few inches to six feet. 2.14.07. Example 48. Utah, Iron County. Disseminations of stibnite in sandstone and conglomerate, following the stratification. In Iron County, southwestern Utah, masses of radiating needles occur in sandstones and between the boulders of an associated conglomerate. Very large individual pieces have been obtained. 303 KEMP'S ORE DEPOSITS. but not enough for profitable mining. Blake thinks that the ore has crystallized from descending solutions. Eruptive rocks are present above the sandstones. 2.14.08. An interesting deposit of senarmontite was worked for a time in Sonera, just south of the Arizona line, but it was soon exhausted.' ARSENIC. 2.14.09. This metal occurs with many silver ores in the West and in arsenopyrite, or mispickel, a not uncommon arseno-sulphide in the gold quartz veins, east and west. At the Gatling mines, in the town of Marmora (more lately called Deloro), in Hastings County, Ontario, auriferous mispickel occurs in great quantity in granite, in veins with quartz gangue. Considerable oxide of arsenic has been obtained in the past from the roasters, but for five years or more the mines have not been productive. For reference to the printed descriptions see under "Gold in Canada" (2.13.0'7). BISMUTH. 2.14.10. Bismuth occurs with certain silver ores in the San Juan district, Colorado, and is referred to in describing the country under "Silver and Gold" (2.09.10). Lane's mine, at Monroe, Conn., has furnished museum specimens of native bismuth in quartz. Some neighboring parts of Connecticut have afforded * General references: W. P. Blake, "General Distribution of Ores of Antimony," Mineral Resources of the U. S., 1883-84, p. 641. Arkan- sas : T. B. Comstock, Geological Survey of Arkansas, 1888, I., p. 136. F. P. Dunnington, " Minerals of a Deposit of Antimony Ores in Sevier County, Arkansas," A. A. A. S., 1877. Rec. J. W. Mallet, Chemical News, No. 533. C. E. Waite, " Antimony Deposits of Arkansas," M. E., VII. 43. C. P. Williams, " Notes on the Occurrence of Antimony in Ar- kansas," M. E., III. 150. California : W. P. Blake, "Kera County," U. 8. Pac. R. R. Explorations and Survey, Vol. V., p. 391. H. G. Hanks, Rep. Cal. State Mineralogist, 1884. See also subsequent reports by William Irelau, Jr. Mexico : E. T. Cox, " Discovery of Oxide of Antimony in So- nora," Amer. Jour. Sci., XX. 431. J. Douglass, "The Antimony Deposit of Sonora," Engineering and Mining Journal, May 21, 1881, p. 850. Nevada: Engineering and Mining Journal, 1892, p. 6. New Brunswick : L. W. Bailej', " Discovery of Stibnite in New Brunswick," Amer. Jour. Sci., ii., XXXV. 150, and in Rep. on the Geol. of Neiv Brunswick, 1865 ; also H, Y. Hind, in the same. Utah : D. B. Huntley, Tenth Census, Vol. XIII., p. 463. THE LESSER METALS. 303 bismuth minerals, and not a few other places in the country con- tain traces, but the San Juan is the only serious one as yet.^ CHROMIUM. 2.14.11. Chromite, whose theoretical composition is FeO.CraOj, with CrjOj 68^, often has MgO and FejOj replacing its normal oxides. The percentage of CrjO, is thus reduced. It is always found in association with serpentine, which has resulted from the alteration of basic rocks consisting of olivine, hornblende, and pyroxene. These minerals contain the chromic oxide probably as a base in their fresh condition, but lose it on alteration. A chrome spinel, picotite, which is an original mineral in these rocks, likewise affords it. The chromite is scattered through the serpentine, often forming masses of large size. Traces of nickel minerals are fre- quently noted associated with the chromite. 2.14.12. Example 49. Disseminations of chromite in serpen- tine. Pennsylvania and Maryland. Great areas of this rock are found in southeastern Pennsylvania and in the adjacent parts of Delaware and Maryland. Considerable mining has been done in the past. Woods mine, in Lancaster County, Pennsylvania, has furnished great quantities, and other large producers are situated in the Bare Hills, near Baltimore. This section is now no longer commercially productive. Chromite has also been announced from several places in the South, no one of which has yet sent notable quantities to the market. 2.14.13. California. As already mentioned under the precious metals, great areas of serpentine occur on the western flanks of the Sierras and in the Coast range. In Del Norte, San Luis Obis- po, Placer, and Shasta counties, California, they furnish commer- cial amounts of chromite. In some places the ore is followed by underground mining, and in others it is gathered as float material. The irregular distribution, always characteristic of the mineral, renders underground work uncertain. Good ore should afford 50^ CrjOj, and in California no ore less than Al% is accepted. It brings in the East |22 to $35 per ton. Considerable quantities are imported.^ 1 Mineral Resources of the U. S., 1885, p. 899. B. Silliman, " Bismuth- inite from the Granite District, Utah," Amer. Jour. Sci., iii., VI. 133. H. L. Wells, " BismuthosphcErite from Willimantic and Portland, Conn ," Amer. Jour. Sci., iii., XXXIV. 371. * F. D. Chester, A7in. Rex). Penn. Survey, 1887, p. 93, describes the 304 KEMPS ORE DEPOSITS. COBALT (SEE UNDEE "Nickel"). MANGANESE. 2.14.14. Ores: Pyrolusite MnOj, Mn. 63.2, braunite, Mn.jOs, Mn 69.68. Some SiOj, which may be chemically combined, is usually present, and small amounts of MgO, CaO, etc. Psilome- lane has no definite composition, but usually contains barium or other impurities. An Arkansas variety has afforded Brackett MnO, 77.85. There are various other oxides and hydroxides, which are rare- ly abundant enough to be ores. The carbonate, rhodochrosite, and the silicate, rhodonite, are rather common gangue minerals with ores of the precious metals. Franklinite is also an impoi'tant source (2.07.04). Pyrolusite and psilomelane are the commonest ores the country over, but braunite is the one in the Batesville (Ark.) region. Manganese is widely distributed, and yet is com- mercially important in but few localities. It imitates limonite very closely in its occurrence and is often associated with this ore of iron. To make a manganese ore valuable, at least 40^ metallic manganese should be present, and this is a lower limit than was formerly admissible when the ores were chiefly used in chemical manufactures. Under present conditions, if iron is present, the ore may be suited to spiegel, although even lower in manganese than 40^. Further, there should be low phosphorus ; Penrose says not over 0.2 to 0.25^ in Arkansas, and not over 12^ SiOj. High-grade ores run 50 to 60^ manganese. 2.14.15. Example 50. Manganese ores, chiefly psilomelane serpentine along the State line near Delaware. B. T. Day, Mineral Re- sources of the U. S., 1882, p. 428 ; 1883-84, p. 567 (Eec.) ; 1885, p. 357 ; 1886, p. 176 ; 1887, p. 132. J. Eyerman, " On "Woods Mine, Pennsylvania," Min- eralogy of Penn., Easton, 1889. P. Fraser, "The Northern Serpentine Belt in Chester County, Pennsylvania," M. E., XII. 349. Rep. C3 (Lan- caster County), Penn. Geol. Survey. T. H. Garrett, "Chemical Examina- tion of Minerals associated with Serpentine," Amer. Jour. Sci., ii., XIII. 45, and XV. 332. Also F. A. Genth, Amer. Jour. Sci., ii., XLI. 120. E. Goldsmith , " Chromite from Monterey County, California ," Phil. Acad. Sci., 1873, p. 365. William Irelan, Jr., Reps. Cal. State Mineralogist, especially 1890, pp. 167, 189, 313, 582, 583, 638. G. H. Williams, "The Gabbros and Associated Hornblende Rocks near Baltimore," Bull. 23, U. S. Geol. Sur- vey, pp. 50-59. " The Geology of the Crystalline Rocks near Baltimore," distributed at the Baltimore meeting of the Institute of Mining Engineers, February, 1892. Rec. THE LESSER METALS. 305 and pyrolusite, often in concretionaiy masses, disseminated through residual clay, which with the ores has formed by the alteration of limestones and shales. The deposits are entirely analogous to Examples 2 and 2a, under "Iron." Along the Appalachians the favorite horizon is just over the Cambrian (Potsdam) quartzite. Such is the case at Brandon and South Wallingford, Yt., where the ores occur in a great bed of clay between quartzite and lime- stone. They are referred to under Example 2a, where mention is made of the associated limonites and interesting lignite. They have never been important producers of manganese. Crimora, in SECTION NO SECTrON NO. ». Fig. 78. — Sections of the Crimora manganese mine, Virginia. The trough is formed by Potsdam sandstone and is filled with clay carrying nodules of ore. After C. E. Hall, M. E., June, 1891. Augusta County, Virginia, is the largest mine in the country. The containing clay bed is very thick, as a drill hole of 276 feet failed to strike rook. The ores occur in pockets, which as a maximum are .5 to 6 feet thick and 20 to 30 feet long, and of lenticular sliape. Other irregular stringers and smaller masses run through the clay, which preserves the structure of the original rock. Potsdam quartzite underlies it. Other similar bodies occur at Lyndhurst and elsewhere in the Great Valley of Virginia, but Crimora is now no longer a source of ore. Cartersville, Ga., is second to Crimora in production. The ores again occur in pockets in a stifp clay and are associated with quartzite, which is not sharply identified as yet. It may be Cambrian (Potsdam) or Upper Silurian (Medina). West of Cartersville is the Cave Spring IDEAL Sections showing the formation of manganese-BEARing CLAY FROM THE DECAY OF THE ST.CLAIR LIMESTONE. ^BOONE Chert ^^ MANGANESE-BeARlNfi CLAY I LIlZARO LIMESTONE 3 St. Clair limestone l^Saccharoioal Sandstone Fig. 1.— Obiqinal Condition of the Socks. Fig. 2.— First Stage op Deoosiposition. Fig. 3.— Second Stage of Decomposition'. Fig. 4, — Third Stage of Decomposition. Fig. 79. — Geological sections illustrating the formation of the manganese ores in Arkansas. After R. A. F. Penrose, Oeol. Survey of Ark., 1890, Vol. I., p. 177. 264 THE LESSER METALS. 3or region, where the ores occur with Lower Silurian cherts. There are numerous other localities not yet of commercial importance along the Appalachians, in Tennessee and elsewhere. Full de- scriptions will be found in Penrose's report, cited below. 2.14.16. Batesville, Ark. The ore is braunite, and is found in masses disseminated in a residual clay left by the alteration of a Fig. 80.— The Turner mine, Batesville region, Arkansas. After B, A, F, Penrose, Geol. Survey Ark,, 1890, Vol. L,p. 372. limestone locally called the St. Clair. It is of geologic age be- tween the Trenton and Niagara periods, and is underlain by another limestone called the Izard, which is later than the Calcif- erous. On the St. Clair a series of cherts called the Boone cherts is found, which is of Subcarboniferous (Mississippian) age. The clays are sometimes in valleys, sometimes on hillsides, according to the unequal decay of the limestone. South of the Bates- ville district are the Boston Mountains, a range of low hills 500 308 KEMPS ORE DEPOSITS. feet high, and from these the manganiferous rocks form a low monocline to the north. This district is in northern central Ar- kansas. Southwestern Arkansas contains a second district in which the ore occui's in a great stratum of novaculite of probable Lower Silurian age. The ores are of no practical importance, being too lean and too disseminated. Small amounts of manga- nese ore have been obtained in California, in San Joaquin County, and from Red Rock, in San Francisco harbor. The former, and perhaps others in the State, may prove important hereafter. 2. 14.17. Quite productive deposits are found in pockets at Markhamville, Kings County, N. B., in Lower Carboniferous lime- stone. Some thousands of tons have been shipped. Other mines are situated at Quaco Head. At Tenny Cape, in the Bay of Mi- nas, Xova Scotia, is another deposit in Lower Carboniferous lime- stone which has furnished several thousand tons of ore. Others less important occur on Cape Breton. The production of manganese ores in the United States seems to be falling off. In 188V it reached its maximum, 34,524 long tons. In 1889 it was 23,927 tons, divided as follows : The Vir- ginias, 14,616; Arkansas, 2528; Georgia, 5208; other States, 1575.^ ^ "Manganese Mines near Santiago, Cuba," Engineering and Mining Journal, Nov. 24, 1888, p. 439. H. P. Brumell, "Notes on Manganese in Canada," Amer. Geol., August, 1892, p. 80. D. T. Day, Mineral Resources, 1882, p. 424; 1883-84, p. 550. F. P. Dunnington, "Oa the Formation of the Deposits of Oxides of Manganese," Amer. Jour. Sci., in., XXXVI. 175. Rec. W. M. Fontaine, "Crimora Manganese Deposits,'' The Virginias, Mirch, 1883, pp. 44-46. Rec. C. E. Hall, "Geological Notes on the Man- ganeseOre Deposits of Crimora, Va.," M. E., June, 1891. E. Halse, " Notes on the Occurrence of Manganese Ore, near Mulege, Baja California, Mex- ico," Trans. N. of Eng. Min. and Mech. Eng., XLI. 302, 1892. H. Hoy, "Ores of Manganese and their Uses," Proc. and Trans. N. S. Inst. Nat. Sci., Halifax, 11., 1864-65, p. 139. " Manganese Mining in Merionethshire, England," Engineering and Mining Journal, Deo. 18, 1886, p. 438. R. A. F. Penrose, Ann. Rep. Ark. Oeol. Survey, 1890, Vol. 1. The best work published. Rec. " Origin of the Manganese Ores ot Northern Arkansas," etc., A. A. A. S., XXXIX. 250. J. D. Weeks, Mineral Resources of the U. S., 1885, p. 303 (Rec) ; 1886, p. 180; 1887, p. 144. D. A. Wells, "On the Distribution of Manganese," A. A. A. S., VI. 375. C. L.- Whittle, " Genesis of the Manganese Deposits at Quaco, N. B.," Proc. Bost. Soc, Nat. Hist, XXV., p. 253. Note. — H. S. "Williams has recently stated on paleontologic evi- dence, that the St. Clair limestone of Penrose represents both Lower and Upper Silurian, with an intermediate (Cason) shale of Clinton-Niagara age, which has yielded the manganese nodules. G. S. A. , Aug. , 1894, CHAPTER XV. THE LESSER METALS, CONTINUED— MERCURY, NICKEL AND COBALT, PLATINUM, TIN. MERCURY. 2.15.01. Ores : Cinnabar, HgS. Hg. 86.2, S. 13.8. Metacin- nabarite is a black sulphide of mercury. Native mercury also occurs. Mercury deposits are found in workable quantities in the United States only in California, in Oregon, and in one locality in Nevada. In all cases cinnabar is the principal ore. The Cali- fornia deposits are limited to the Coast range and in their forma- tion seem to have followed great basaltic eruptions of post-Plio- cene age. 2.15.02. Example 50. New Almaden. Cinnabar with sub- ordinate native mercury, in a gangue of crystallized and chalce- donic quartz, calcite, dolomite, and magnesite, forming a stockwork, or " chambered vein," in shattered metamorphic rocks (pseudo- diabase, pseudo-diorite, serpentine, and sandstone). There are two main fissures, making a sort of V, with a wedge of country rock between. The ore bodies are in the fissures and also in the intervening wedge, and have associated with them much attrition clay. A great dike of rhyolite runs nearly parallel to the fissures, and to this Becker attributes the activity of circulations which filled the vein. New Idria is farther south, high up toward the summit of the Coast range. The ore is deposited in shattered metamorphic rocks of Neocomian (Lower Cretaceous) age, and in overlying Chico beds. The ore is accompanied by bitumen. Ba- salt is abundant ten miles away. North of San Francisco other mines have been opened, among which are the Oat Hill, Great Eastern, and Great Western. The mines are in a region pierced by eruptions of basalt and andesite, which doubtless gave impetus dlO KEMP'S ORE DEPOSITS. to the ore-bearing solutions. The ores are deposited in hotli meta- raorphic and unaltered sedimentary rocks. 2!l5.03. Example 50a. Sulphur Bank. This is in the same general region as the last, but from its peculiar character has been one of the best known of ore deposits. A great flow of basalt has come down to the shores of Clear Lake from the west. Waters charged with alkaline (including ammonia) carbonates, chlorides, borates, and sulphides, and with COj, HaS, SOj, and marsh gas, have circulated through it. Sulphur and sulphuric acid have formed at the surface, and the latter has dissolved the bases of the rock, leaving pure white silica behind. Lower down, cinnabar Fig. 81. — Section of the Great Western cinnabar mine. After G. F. Becker, Monograph XIII,, U, S. Geol. Survey, p. 360. is found, both in the basalt and in the underlying sedimentary rocks, with other sulphides and chalcedony. Leconte attributed its precipitation to cold surface waters, charged with sulphuric acid, which trickled down and met the hot alkaline solutions. Becker refers the same to the ammonia set free toward the sur- face by diminished heat and pressure. The California cinnabar deposits have been often, but wrongly, referred to vapors of the sulphide volatilized by internal heat and condensed above. 2.15.04. Example 50S. Steamboat Springs, Nevada. These springs are in Nevada, only six miles from the Comstock Lode. Granite is the principal rock, while on it lie metamorphic rocks of the Jura-Trias, and much andesite and basalt. The hot springs, coming up through small fissures, deposit chalcedony in some THE LESSER METALS, CONTINUED. 311 places, carDonates in others, with cinnabar as well as gold. The following minerals have been noted : " Sulphides of arsenic, anti- mony, sulphides or sulphosalts of silver, lead, copper, and zinc, ox- ide, and possibly sulphide of iron; manganese, nickel and cobalt compounds, and a variety of the earthy minerals " (Becker). Becker thinks the source of the cinnabar is in all classes in the underlying granite, and that it has come up in solution with sodium sulphide, and been precipitated toward the surface by the other compounds in the hot alkaline waters, with which it would remain in solution at greater depths, temperatures, and pressures. The Steamboat Springs are often and properly cited as metalliferous veins in ac- tive process of formation.' 3.15.05. Gr. F. Becker^ has recently given an admirable review of quicksilver deposits, the world over, their mineralogical asso- ciates and probable methods of origin, and the same subject has been treated by A. Sclirauf.' Becker has tabulated the minerals associated with cinnabar from twenty-eight world-wide localities, and has made it evident that silica, either as quartz or in opaline forms, and calcite, are the common gangue associates. Pyrite or marcasite is almost invariably present, and bitumen is very wlde- 1 W. P. Blake, " Quicksilver Mine at Almaden, Cal.," Amer. Jour, Sci., ii., XVII. 438. G. F. Becker, "Quicksilver Deposits of the Pacific Slope," Monograph XIIL, V. S. Geol. Survey, Chap. 17. Rec. " On New Almaden," Cal. Geol. Survey, I., p. 68. S. D. Christy, " On the Genesis of Cinnabar Deposits," Amer. Jour. Set., June, 1878, p. 453 ; Engineering and Mining Journal, Aug. 3, 1879, p. 65. D. de Cortazar, "General Re- view of Occurrence, etc., of Mercury," Reps, and Awards Group L, Cen- tennial Exposition, p. 196. William Irelan, Ann. Reps. Cal. State Mineral- ogist. Laur, "On Steamboat Springs," Annales des Mines, 1863, 423. J. Leconte and Rising, "Metalliferous Vein Formation at Sulphur Bank," Amer. Jour. Sci., July, 1882 ; Engineering and Mining Journal, Aug. 26, 1882, p. 109. J. Leconte, "On Steamboat Springs," Amer. Jour. Set, June, 1883, p. 424. "Genesis of Metalliferous Veins," Amer. Jour. Sci., July, 1883. J. A. Phillips, "On Sulphur Bank, California," Phil. Mag., 1871, p. 401 ; Quar. Jour. Geol. Sci., XXXV., 1879, p. 390. Rolland, An- nales des Mines, XIV., 384, 1878. B. Silliman, "Notes on the New Al- maden Quicksilver Mines," Amer. Jour. Sci., ii., XXXVII. 190. Siveking', B. und H. Zeitung, 1876, p. 45. ' Or. F. Becker, ' ' Quicksilver Ore Deposits, with Statistical Tables, ' ' Mineral Resources of the United States, 1892. "A. Schrauf, "Aphorismen uber Zinuober, " Zeitschrift fur prak- tische Geologie, Jan., 1894, p. 10. 312 EBJMP'S ORE DEPOSITS. spread. Various other antimony, arsenic, silver, lead, copper and zinc minerals, as well as gold, are of somewhat irregular occurrence. Becker reaffirms the previously cited theory of origin, that the cinnabar has come up in solution as a double sulphide with the alkaline sulphides, but lays stress upon the precipitating proper- ties of bituminous substances, which reactions were corroborated by experiment. He favors the view that the cinnabar has saturated porous or decomposed rock, rather than that it has actually replaced it by metasomatic processes. The probable source of the ore in deep-seated and widely-distributed granitic rocks, and especially in such portions as overlie the foci of volcanic activity, is reaffirmed, NICKEL AND COBALT. 2.15.06. These two metals almost always occur together. * Their ores embrace the following general classes: 1. Compounds with arsenic and rarely with antimony, or with arsenic (or antimony) and sulphur; 2. Sulphur compounds, including nickeliferous pyr- rhotite and pyrite; 3. Oxidized ores, mostly hydrated silicates re- lated to serpentine.* Although the number of minerals involving nickel and cobalt is quite large, the ores properly speaking are com- paratively few; nickeliferous pyrrhotite is much the most important, especially as concerns this country, but the oxidized ores may yet prove serious. Only the ores (i. e., minerals commercially impor- tant) are mentioned in the table below, Niccolite. . . .NiAs, Ni.43.9 As. 56.1 MiUerite NiS, Ni. 64. 4 S. 35. 6 Linnaeite . . . . ( CoNi ) 3S4 Co. 31. 34, Ni. 30. 58, Fe. 3. 37 S. 41. 54 Pentlaiidite..(NiFe)S, Ni.34.28 re.30.25 S.33.43 1 Tlie following general papers on nickel and cobalt axe important : F. D. Adams, ' ' On the Igneous Origin of Certain Ore Deposits, ' ' Gen- eral Mining Assoc. Prov. Quebec, Jan. 12, 1894. P. ArgaU, "Nickel: the Occiirrence, Geological Distribution and Genesis of its Ore Deposits, ' ' Proc. Colo. Sci. Soc, Dec. 4, 1893. W. L. Austin, "Nickel, Historical Sketch," Idem, same date. H. B. v. Foullon, "Ueber einige Niokel- BTZYorkoioiiiejx, " Jahrbuch d. k. k. geol. Reichsanstalt, Vienna, XLII., 223, 1893. D. Levat, Annnles des Mines, 1892, Part 3. J. H. L. Vogt, " Nikkelf orkomster og Nikkelproduktion ("Occurrence and production of Nickel"), Norwegian Geol. Surrey, Kristiania, 1892. A resumg in G!er- man accompanies the paper. Sulphidische Ausscheidungen von Nickel- sulphiderzen, etc., Zeitsclirlft fur praktische Geologic, April, 1893, 135. ^ This is practically the same grouping that is given by J. H. L. Vogt, Zeitschrift fur praktische Geologic, April, 1893, 135. See also P. Aigall, Proc. Colo. Sci. Soc, Deo. 4, 1894. THE L38SER METALS, CONTINUED. 313 Gtenthite 3NiO,3Mg0.38 -.OseHsO Ni.33.6 Garnierite. . .HjO(Ni,Mg)O.Si02 + Aq.Ni.25.0 Zaratite NiCos,2Ni(OH)8 + 4H20 Ni.46.8 To these nickeliferous pyrrhotite and pyrite should be added, the former being the most important of all. Niccolite was reported years ago at Tilt Cove, Newfoundland, in some quantity, but elsewhere has not been found in any serious amount in North America. It also, occurs in some of the western openings of the Sudbury district. Millerite furnished a small portion of the nickel at the Gap Mine, Penn., as noted below. Linnaeite, variety siegenite, occurs in a sandstone bed at Mine la Motte in disseminated octahedra, and although small attempts have been made to utilize it, the amounts are, so far as known, not large enough for success. Pentlandite must be mentioned together with nickeliferous pyrrhotite. It has been somewhat of a question among mineralogists in just what relations the nickel occurs in pyrrhotite; whether replacing the iron in PeiSj, or some other vari- ety of re„Sn_|_i, to the extent of a fraction of one per cent, up to five, or whether there is an isomorphous or distinct nickel or iron- nickel sulphide intermingled with the pyrrhotite. As far back as 1843 Scheerer identified pentlandite from southern Norway, and several other minerals, such as polydymite, have been less definitely described. More recently it has been shown that the nickel-rich portions of the pyrrhotitic ores are quite feebly magnetic, aud pro- cesses have even been suggested for concentrating the nickel based on this principle.' Pentlandite is non-magnetic, aud possibly this mineral in very fine disseminations may contribute of its richer percentage of nickel to raise the total of the pyrrhotites as mined. Some nickel, however, always remains in the strongly magnetic residues, so that we are not yet justified in abandoning the earlier view that this metal replaces some of the iron of the pyrrhotite. Pyrrhotite is the chief ore at Sudbury, and was the ore at the Gap Mine, Penn., until the workings were dismantled in 1894. In south- east Missouri, but more especially at Mine la Motte, nickeliferous pyrite accompanies the galena (see 3.05.09) and has furnished a considerable amount as a by-product in tlie metallurgy of lead. Of the oxidized ores it is not easy to speak as regards their indi- 1 See in this connection D. H. Browne, ' ' On the Sudbury Ores, ' ' Engineering and Mining Journal, Dec. 3, 1893. Rec. S. H. Emmens, "The Constitution of Nickeliferous Pyrrhotite," Jour. Amer. Chem. Sac, XIV., No. 10. 314 EEMP'H ORE DEPOSITS. vidual importance. The hydrated silicates are of extremely vari- able composition, and while one or two illustrations of the type are selected for the table, no one of them is yet seriously mined in America. 2.15.07. Example 16c. (See 2.03.16 and 2.04.03.) Pyrrhotite Beds or Veins.' Lenticular masses of pyrrhotite interbedded in gneisses and schists as described for pyrite. They are known at various places in the East. Openings have been made at Lowell, Mass., Chatham and Torrington, Conn., and on the mountain on the east bank of the Hudson called Anthony's Nose. The last is much the largest of those namedj and though never mined for the nickel which is known to be present, it was utilized as a material for sul- phuric acid fumes during the ten years succeeding 1865. The geo- logical relations give it especial interest. The ore body is entirely analogous to the magnetite lenses, which are not rare in the High- lands of the Hudson. It lies in a light-colored gneiss, conforma- bly to the laminations, and must have attained twenty or thirty feet in thickness. It has been mined down 300 or 400 feet, and apparently for 50 feet or more on the strike. About one hundred yards west is found a basic gneiss, consisting of green hornblende and plagioclase, with a little biotite. The wall rock contains quartz, plagioclase and very subordinate hornblende. In the thin section it appears fully as acidic as a quartz-diorite. Much hornblende is associated with the pyrrhotite, and occa- sional lumps of magnetite, with which are found titanite and apa- tite. The ore yielded about 28^ sulphur as used for years in the chemical works, and was especially prized because it contained no trace of arsenic. The geological relations give no reason for re- garding the ore body as a basic segregation of a gabbroitic magma, but quite the contrary.'' Several of the magnetite mines in this region, it may be added, are troubled with pyrrhotite in the ore, but whether it is nickeliferous has not been determined. 1 H. Credner, "Berg- und Huett. Zeit., 1866," p. 17. Dana's Treat- ise on Mineralogy, 6th edition, under Pyrrhotite gives several analy- ses from Putnam Co. , N. Y. J. F. Kemp has a paper in manuscript on the old mine at Anthony's Nose, which will soon appear. 2 W. H. Hoffman, ' ' The late Discovery of Large Quantities of Mag- netic and Non-magnetic Pyrites in the Croton Magnetic Iron Mines, N. Y.," Trans. Amer. Inst. Min. Eng., June, 1893. J. C. Smock, Bulletin of N. Y. State Museum, Dunderberg Mine, p. 18, Hobby Opening, p. 24. THE LBS8EB METALS, CONTINUED . 315 3.15.08. Example 13a. Sudbury, Ont.; Gap Mine, Penn. Bodies of nickeliferous pyrrhotite and chalcopyrite with very subordinate pyiite, in the outer portions of intrusions of basic igne- ous rocks, which may be metamorphosed to amphibolites. Cobalt is present in less amount than nickel and varies much in its rela- tive proportions. Secondary millerite sometimes forms in cracks, as do quartz, siderite and one or two other minerals, but in variety of species ore-bodies of this type are exceptionally barren. The type is of world-wide distribution, as noted by Vogt, and is well known in Norway, Sweden and one or two other European locali- ties. The number of the Example indicates its genetic parallelism with the titaniferous magnetites of 2.03.11. 2.15.08. The Gap mine in Lancaster County, in southeastern Pennsylvania* was originally opened for copper in the previous century. The copper enterprises were all failures, and not until in the fifties was the presence of nickel recognized. The mine then became the largest single producer of its day and remained active until 1893, since which time it has been abandoned. As shown in the accompanying map and sections a lenticular outcrop or mass of greenish black rock, about 3000 feet in length and 500 feet as a maximum width, is found in the midst of mica schist, and appar- ently conformable to the laminations. It strikes nearly east and west, and is contracted along the section AA, where it was most productive. It seemed to pinch in somewhat in depth, so far as the workings extended (about 350 feet). The ore was chiefly found at the eastern end of the lense, and was much less abundant where followed to the westward on the south side with a drift, as far as is colored black. Prospect holes still further west proved the presence of the amphibolite, but failed to show ore. A dike of olivine-diabase of the familiar Triassic sort common in southeastern Pennsylvania outcrops about 1500 feet southeast, but it is much later in time than the amphibolite, with which and with the ore it has no apparent connection. The ore is pyrrhotite in far the largest amount, but when cut in thin sections along with the con- 1 P. Fraser, "Report CCC, " Snd Penn. Geol. Survey. (A geological descriptioa and historical sketch are given, and also an outline map in the accompanying atlas, on which the figure here used is based. The description, however, gives the impression that the ore is miUerite, and hardly mentions pyrrhotite, whereas the miUerite is a comparatively rare mineral. ) Joseph Wharton, ' ' Analysis of the Nickel Ore from the Gap Mine, Lancaster County, Pa.," Proc. Phila. Acad. Sci., 1870, p. 6. THE LESSER METALS, CONTINUED. 317 taining amphibolite, it is seen under the microscope that a light yellow mineral, presumably pyrite, is mixed all through the bronze- colored pyrrhotite. The ore is richest near the contact and fades into lean disseminations as this is left. The lense consists in far the largest part of green hornblende of the common variety, quite pale in thin section, and with pleochroism from green to yellow. Many specimens are formed of this and nothing else, except scat- tered grains of pyrrhotite. Others show a little plagioclase, and a few flakes of biotite. Recognizable remains of orthorhom- bic pyroxene and olivine were detected despite the general and thorough metamorphism of the rock. No more accurate name can be given it than amphibolite, although there is little doubt that it originally was a very basic gabbro or pyroxenite. The ore contains considerable secondary millerite, which forms crusts on the cracks of pyrrhotite, and often veins and stringers of quartz traverse it. In vuggs in these, beautiful crystals of vivianite are rarely met. The close parallel that the ore-body affords in its geology to several Norwegian mines figured by Vogt in the Zeitschrift filr prakt. Geologie, April, 1893, Plates V. and VI., is very striking. (See especially Meinkjar Grubenfeld, Pig. 3 of Plate VI.) The views of Vogt on the origin of such ore-bodies by differentiation of a basic igneous magma in cooling, and by concentration of the early crys- tallizations at the contacts, according to Soret's principle, were outlined earlier in the discussion of the table of classification of ore deposits. In a metamorphosed rock, such as the Gap amphib- olite, there is a reasonable ground for regarding the ore as a con- tact deposit due to deposition from solutions, but after seeing the larger less metamorphosed but otherwise closely analogous ore-bodies of the Sudbury district, the writer (J. F. Kemp) sees no escape from the conclusion that they and it are original crystallizations from the igneous magma as much as any other component minerals of the intruded mass.* 2.15.09. The Sudbury nickel mines are of quite recent develop- ment, as they have not yet (1894) been operated ten years. They are situated forty miles north of Georgian Bay, an arm of Lake Huron, and on the eastern portion of the original Huronian belt. The Laurentian granites and gneisses, which to the east form a " Literature on the Gap Mine, W. P. Blake, Mineral Resources, 1882, p. 399. J. Eyerman, "Mineralogy of Penn.," P. Fraser, Eep. CCC, Second Penn. Geol. Survey, p. 163. J. Wharton, "Analysis of Nickel Ore from the Gap Mine," Proc. Phila. Acad. Sci., 1870, p. 6. 315 KEMP'S ORE DEPOSITS. vast, monotonous stretch of low glaciated hillocks and swamps, ai-e covered near Sudbury, and for a himdi-ed miles west, by a gi'eat area of later Hnronian sediments (graywaclces, quai-fzites, scliists) ;iiid by immense intrusions and dikes, of diorites and more basic I'ocks, at times more or less metamoi'phosed; eruptive breccias anil otlier interesting varieties too numerous to cite in detail are also present. Fig. 83. — Yieiv of the Copper Cliff 2Iine, near Siiilbiifii. Ontario mine is in iliurife. TJie riihje at the haikipmi ml is ijranite. From a pliotuijraiiti hij T. G. ^VItitl-. In'.M. The The geology is vei'y comple.x, and is in large part concealed bv swamps and almost impenetral>le tbickets. It is evident, hiiwever, that several great intrusions of a general dioritic character run iioi'fliea.st and southwest through the Hurouian area. <_)ne on the southeast has along its own southeastern sidesomerich deposits, in- cludiiig the Evans, Copper Cliff, Stobie and Blezard. The Evans THE LESSER METALS, CONTINUED. 319 is on a small outlier from the main mass, and the Stobie and Blezard are further in from the actual contact than is the Copper Cliff. Some miles west of the great diorite dike just referred to is the large Murray mine in another intrusion with a stretch of sup- posed Laurentian granite between. Some twenty miles southwest, and in connection with a still different diorite dike are found the Worthington mine and several undeveloped openings in Drury and Denison townships. About the same distance northwest of Sud- bury is a region around Wahnapitae Lake, well thought of, but not yet productive. The ore-bodies betray their presence by great outcrops of rusty gossan, consisting of limonite in layers and cellular masses, which has resulted from the decay of the pyrrhotite and clialcopyrite. The interrupted outcrop of this gossan may run for long distances. When it was penetrated in the early prospecting the chalcopyrite lying below attracted attention, and the deposits were regarded as copper mines. Later the presence of the nickel in the pyrrhotite was recognized, and the nickel became the principal object. The two ores are inseparably intermingled and themselves form irregu- lar masses often of great size in the diorite. It is stated by Peters that the early work at the Stobie showed ore over 100 feet across. The diorite is a dense black rock resembling most closely black basalt in its appearance. Quite pure pieces of sulphides of large size are at times obtained, but practically all the ore contains rock up to 30^ or more of its weight, and the sulphides form irregular masses in it. Great heaps of rock too lean to work, but showing bits of sulphides through the pieces, are thrown out on the dumps. The workings are in the form both of open cuts and of shafts, from which the drifts wander out somewhat irregularly in search of the ore-masses. Wliile it is truly said the ores favor the con- tacts this should not be too closely interpreted. The mines and the gossan do lie along the outer portions of the diorite masses, yet as now mined at all the large producers they are entirely in the diorite, and often very considerable distances from the actual con- tact, of which no evidence appears from the workings. Included masses of granite occur with the ore at Copper Cliff, and as a gen- eral thing have a run of chalcopyrite. Some small, secondary and insignificant quartz veins ramify through the diorite, and contain chalcopyrite and some pyrrhotite, both of which are secondary, but they are trifling in amount. On the contrary the masses of the sulphides are irregularly distributed, often as small isolated bits. 320 KEMP S ORE DEPOSITS. throughout the fresh, dense diorite, leave one no reasonable alter- native but to conclude that they are as much an original crystalliza- tion from the igneous magma as any other of the minerals in the rock. Evidence of disturbance has been found in the region and apparent fault lines are not lacking, but the great open cuts of the mines show no evidence of them. The method of igneous origin has been somewhat attacked. Posepny, for example, refers to it as something extraordinary when he cites Vogt's work, in his great essay on " Genesis of Ore-Deposits," and controverts it strongly, but it appears to the writer, after having seen the mines, that no process of solution and replacement can be conceived of as intro- ducing these scattered masses of sulphides into dense, undecomposed and apparently unbroken igneous rock which would not strain the faith of a conservative observer to a far greater degree. It is an interesting fact that sperrylite, the unique arsenide of platinum, occurs in the Sudbury region, but was not first discov- ered in a nickel mine. Traces are, however, said to occur in the nickel ores. Cobalt is in comparatively small amount, much less than iu some other nickel regions. The ores vary in richness in difEerent mines and in different parts of the same mine. They run from over 1^ to over 5^ nickel, and have a copper percentage some- what under the nickel. The Worthington has yielded a little gers- dorffite (NiAsS), and niccolite (NiAs) in secondary quartz veins, and a vein is reported from Denison township containing both these. A galena vein is reported from the same region, a little mil- lerite is said to have been found in the Copper Cliff mine, and traces of zinc blende have also been noted in some of the ores, but aside from these the mineralogy is limited to the two principal sulphides.'' 1 On Sudbury see F. D. Adams, ' ' The Igneous Origin of certain Ore Deposits," General Mining Assoc, Prov. Quebec, Jan. 12, 1894. A. E. Barlow, ' ' The Nickel and Copper Deposits of Sudbury, Ont. , ' ' Ottawa Naturalist, June, 1891. R. Bell, Geolog. Survey of Can., 1890-91; F. 5, 91. Bull. Geol. Soc. Amer., 11. p. 135. T. G. Bonney, "Notes on a part of the Huronian Series near Sudbury, ' ' Quart. Jour. Geol. Soc. , XLIV. 32, 1888. D. N. Browne, Engineering and Mining Journal, Sept. 16 and Deo. 2, 1893. E. R. Bush, ' ' The Sudbury Nickel Region, Idem, March 17, 1894, p. 345. F. W. Clarke and C. Catlett, " Platinif erous Nickel Ore from Canada, " ^mer. .Jour. Sci., iii., XXXVU., 372. J. H. Collins, "Note on the Sudbury Copper Deposits," Quart. Jour. Geol. Sue, XLIV. 834. J. Gramier, "Mines dn Nickel, Cuivre et Platine, du District du Sudbury, ' ' Memoires de la Societie des Ingenieurs Civils. , thsTlesseb metals, CONTINUKD. 321 3.15.10. Example 49a. Kiddle's, Douglass County, Oregon. Irregular deposits of hydrated silicates of nickel and magnesia, in serpentine formed by the alteration of peridotites or related rocks, Limonite, chalcedonic quartz and chromite are quite invariable associates, as are clays and other products of alteration. The ore occurs in loose boulders on the surface, and as a coating on the walls of small cracks and veinlets that penetrate the more massive serpentine. The largest deposits of this character so far as yet opened in this country are in the Coast Eange, southwest of Riddle's Station, Douglass County, Oregon, on the Oregon and California Railroad. The mines occur on a steep hillside, in ser- pentine that has resulted from the alteration of the variety of peri- dotite, called harzburgite, i. e., bronzite and olivine. Open cuts, small drifts and test pits have served to show the nickel silicates, richest at the outcrop and fading out into small veinlets and retic- ulations in depth until beyond the zone of snperficial decay they disappear. The openings are still in the condition of prospects, and productive mining is yet to be begun. The nickel has been shown by J. S. Diller to have been derived from the olivine of the rock, as chemical analysis of this mineral indicated 0.2G^ NiO. By the familiar and ready alteration of the olivine the nickel has separated as the silicate and has finally been concentrated suffi- ciently to be noticeable.^ At Webster, in North Carolina, are sur- face deposits of nickel silicate which have attracted attention. They occur in the variety of peridotite, which is chiefly olivine, and is called dunite. The geological relations and origin are practi- cally the same as those in Oregon, just cited. The mines are not yet producers.^ Green crusts of oxidized nickel compounds have been found with the chromite in the town of Texas, Penn., but are Paris, March, 1891. W. H. Merritt, Tram. Amer. Inst. Min. Eng., XVn. 395. E. D. Peters, "On Sudbiary Ore Deposits," Trans. Amer. Inst. Min. Eng. , Oct. , 1889 ; Eng. and Min. Jour. , Oct. 36, 1889. Berg, u. Huet. Zeit., L. 149, 1891. IF. W. Clarke and J. S. DiUer, "Nickel Ores from Riddle's, Webster and New Caledonia, ' ' Amer. Jour. Soi. , iii. , XXXV. 483. H. B. V. Foullon, "On Riddle's, Jahr d. k. k. Geol. Reichsanstalt, 1893, 334. Rec. 2 Clarke and Diller as cited in preceding reference. S. H. Emmens, ' ' The Nickel Deposits of North Carolina, ' ' Eng. and Min. Jour. , April 30, 1893, p. 476. H. Wurtz, ' ' On the Occurrence of Cobalt and Nickel in Q-aston County, North Carolina, "Amer. Assoc. Adv. Sci., XII. 331, Amer. Jour. Sci., ii., XXVII. 34. 332 KEMP'S ORE DEPOSITS. of no practical importance. Such superficial discolorations are very common in serpentinous districts, but it is a cnrions fact that they are notably lacking in the dioritic varieties of Example 13a. The greatest deposits in serpentinous are found in New Cale- donia, in the South Pacific, vrhere they have been mined for some years past, and have furnished in the last decade the largest part of the world's supply. The ores occur, as is the usual case, associated ■with serpentine, and along the contact of the serpentine with over- lying beds of red clay.' 2.15.11. Example 23a. Mine la Motte. Considerable pyrite occurs with the lead ores mentioned under Example 23, and is sep- arated in the ore-dressing and treated by itself, as it contains nickel and cobalt. Such pyrite is most abundant at Mine la Motte, and considerable matte is made and shipped abroad. Sieg- enite, a variety of linnaeite, is also found impregnating a bed of Cambrian sandstone that underlies the lead-bearing dolomite. It is not abundant enough to be of practical importance.^ 2.15.12. Nickel ores have also been reported from Salina County, Arkansas.^ Millerite occurs in a vein with quartz gangue in black shales. It is not practically productive. Nickel is also reported in a rather fine conglomerate from Logan County, Kansas. It oc- curs with manganese and limonite in the cementing material of the rock.* Oxidized nickel ores have also been reported at the Love- lock mines, Churchill County, Nevada, which passed in depth into sulphides. 5 Although they were originally regarded as promising • F. Benoit, ' ' Etude snr las Mines de Nickel de la NouveUe Cale- donie, " -B«ZZ. de la Societe de I'Ind. Minerale, VI. 753., 1892. J. G^ar- nier, ' ' Memoire snr les Gisements de Cobalt, de Chrome et de Fer a la Nouvelle Caledonie, " Soc. des Ingenieurs civils., 1887. J. Heard, Jr., "New Caledonia Nickel and Cobalt," Eng. and Min. Jour., August 11, 1888, p. 103. D. Levat, Association Francaise pour I' Advancement des Sciences, Paris, 1887. L. Pelaton, "Carte Geologique de la NouveUe Caledonie, ' ' Genie civile, 1891. 2 J. M. Neill, ' ' Notes on the Treatment of Nickel and Cobalt Mattes at Mine la Motte, " Trans. Amer. last. Mm. Eng., XTTT. 634. For ad- ditional literature see under 2.05.09. s Ark. Geol. Survey, 1888, Vol. I. pp. 34, 35. * F. P. Dewey, ' ' On the Nickel Ores of Russell Springs, Logan County, Kansas," Trans. Amer. Inst. Min. Eng., XVII. , 636. 5 A. D. Hodges, ' ' Notes on the Occurrence of Nickel and Cobalt Ores in Nevada," Trans. Amer. Inst. Min. Eng., X. 657. S. B. New- berry, "Nickel Ores from Nevada, " Amer. Jour. Sci., iii., XXVHI. 133. TEW LESSER METALS,. CONTIN VED. 323 they have not proved a productive source as yet. Millerite occurs as an interesting mineral in many other places (St. Louis, Mo.; with red hematite in Jefferson County, N. Y., etc.), but is only a rarity. Its interesting position at the former locality, in hair-like tufts in the midst of geodes indicates that nickeliferous solutions must have circulated rather widely in these limestories. In Jefferson County it probably resulted from the decaying pyritous mineral to which Smyth refers the iron ore, as outlined earlier. Canada is now the chief producer of nickel (1,336,637 lbs. in 1891); New Caledonia follows (885,300 lbs. in 1890). Norway and Sweden come next; while the United States, with the cessa- tion of the Gap mine, are no longer to be reckoned in the list of producers. PLATINUM. 2.15.12. Some hundreds of ounces of platinum are annually gathered from placer washings in northern California, and two or three times as much more from British Columbia. Much iridium and osmium are associated with it. In October, 1889, F. L. Sperry, the chemist of the Canadian Copper Company, of Sudbury, dis- covered a heavy crystalline powder in the concentrates of a small gold-quartz mine in the district of Algoma. He detected the presence of platinum, and sent the material to Professors "Wells and Penfield of Yale, by whom it was analyzed, and crystallo- graphically determined to be the arsenide of platinum, PtAsj, the first compound of platinum, other than an alloy, detected in nature. It has been appropriately named sperrylite by Wells, and although not at present a source of platinum, it may merit atten- tion, as the price of the metal has recently approximated that of gold. The chief reliance of the world for platinum is Russia, whose deposits are in the Urals. More or less comes also from Colombia, South America, and from placer washings elsewhere. Serpentine is very generally its mother-rock.^ ' California : Engineering and Mining Journal, June 29, 1889, 587. B. SilJiman, "Cherokee Gold Washings, California," Amer. Jour. Sci., ill., VI. 133. Canada: F. W. Clarke and Ch. Catlett, " Platiniferous Nickel Ore from Canada," Amer. Jour. Sci., iii., XXXVII. 373. H. L. Wells and S. L. Penfield, " Sperrylite, a New Mineral," Amer. Jour. Sci., ill., XXXVII. 67. Russia: A. Daubree, "On the Platiniferous Rocks of the Urals," Trans. French Acad. Sci, March, 1875 ; Amer. Jour. Sci., iii., IX. 470. General paper by C. Bullman, The Mineral Industry for 1892, p. 373. Rec. 324 KEMP'S ORE DEPOSITS. TIN. 2.15.13. Ores : Cassiterite, SnOj, Sn. 78.67,0. 21.33. The sul- phide stannite is a rather rare mineral. Cassiterite occurs in small stringei's and veins on the borders of granite knobs or bosses, either in the granite itself or in the adjacent rocks, in such relations that it is doubtless the result of fumarole action consequent on the intrusion of the granite. It appears that the tin oxide has probably been formed from the fluoride. A favorite rock for the ore is the so-called greisen, a mixture of quartz and muscovite or lithia mica, and probably an 1»IG. 84. — Horizontal section of the Etta knob. After W. P. Blake, Min- eral Resources, 1884, p. 602. o/iginal granite altered by fumarole action. Topaz, tourmaline, and fluorite are found with the cassiterite, indicating fluoric and boracio fumaroles. Cassiterite seems also to crystallize out of a granite magma with the other component minerals. Cassiterite, being a very heavy mineral, accumulates in stream gravels, like placer gold, affording thus the stream tin. When of concentric character it is called wood tin. It is not yet demonstrated that the United States have workable tin mines. 2.15.14. Example 51. Black Hills. Knobs of granite rock containing cassiterite, disseminated in a mass of albite and mica, and associated with immense crystals of spodumene. Columblte, tantalite, and beryl are also found. There are two granite knobs which are best known, the Etta and the Ingersoll. The former is a conical hill, 250 feet high by 150 feet by 200 feet, piercing mica and garnetiferous slates. Tunnels show it to have a concentric struct- ure — first, a zone of mica ; second, a zone of great spodumene crystals, with an albitio, so-called greisen and cassiterite in the THE LESSER METALS, CONTINUED. 325 interstices ; lastly, a mixture of quartz and feldspar as a core. Other tin-bearing granites occur as dikes, or veins, as much as 80 feet wide, and bearing the so-called greisen and tin ore in quartz. They are called segregated veins by Carpenter, who doubts their igneous character, probably on good ground. No tin is yet com- mercially produced. The tin deposits extend also into Wyoming.^ 2.15.15. Tin ores as stream tin have been found in gold wash- ings in Montana and Idaho. Tin is also known in the Temescal Mountains, southern California, and according to Blake is in various small veinlets in a granite region. This locality attracted much interest years ago, but has never yielded any practical re- sults until lately. Operations after being carried on for a time have, however, proved a failure.^ 2.15.16. Narrow veins carrying cassiterite are being exploited in the granite and schistose rocks of Rockbridge and Nelson counties, Virginia, in North Carolina, and in Alabama. Compa- nies have been formed to work the two former, but as yet without a notable output.' 2.15.17. Cassiterite has been discovered in narrow veins in mica schists with lepidolite and fluorite at Winslow, Me., and is known at other places in Maine and New Hampshire. A salted tin pros- pect several years ago spread the impression that tin was to be found in southwest Missouri.* ' W. P. Blake, Mineral Resources, 1884-85, p. 603. Rec. Amer. Jour. Sci., September, 1883, p. 335 ; Engineering and Mining Journal, Sept. 8, 1886. " Tin Ore Deposits of the Black Hills," M. E., XIII. 691. F. R. Carpenter, Prelim. Rep. Dak. School of Mines, 1888 ; also M. E., XVII. 570. "Tin in the Black Hills," Engineering and Mining Journal, Nov. 38, 1884, p. 353. Mineral Resources of the U. S., annually under "Tin." 2 W. P. Blake, "Occurrence of Wood Tin in California, Idaho, and Montana," Mining and Scientifio Press, San Francisco, Aug. 5, 1883. H. G. Hanks, Rep. Cal. State Mineralogist, 1884, p. 131. ' H. D. Campbell, "Tin Ore, Cassiterite, in the Blue Ridge in Vir- ginia,' The Virginias, October, 1883. A. R. Ledoux, " Tin in North Caro- lina," Engineering and Mining Journal, Dec. 14, 1889, p. 531 ; see also February, 1887, p. 111. McCreath and Piatt, Bull. Iron and Steel Asso., Nov. 7, 1883, p. 209. W. Robertson, London Mining Journal, Oct. 18, 1884. A. Winslow, "Tin Ore in Virginia," Engineering and Mining Journal, November, 1885. Rec. * W. P. Blake, Mineral Resources, 1884, p. 588. C. H. Hitchcock, "Discovery of Tia Ore and Emery at Winslow, Me.," Engineering and Mining Journal, Oct. 2, 1880, p. 318. T. S. Hunt, " Remarks on the Oc- currence of Tin Ore at Winslow, Mh.," M. E., I. 573. C. T. Jackson, " Tin Ore at Winslow, Me.," Proc. Bost. Soo Ndt. Hist., XII. 367. CHAPTER XVI. CONCLUDING REMARKS. 2.16.01. In review of the western border of the country, we note the elevated plateau rising from the Mississippi to the Rocky- Mountain range, which consists of various ranges of general north and south or northwest and southeast trend, with broad valleys between. Next comes the Colorado Plateau, and then the Wa- satch Mountains and the Great Basin, with its various subordinate north and south ranges. These are succeeded by the Sierra Ne- vada, and the great valley of California, the Coast range, and finally the Pacific Ocean. From the Archaean to the close of the Carboniferous there Tvere granite islands around which active sedimentation proceeded. At the close of the Carboniferous the elevation of the Wasatch and the region of eastern Nevada occurred. At the close of the Jurassic the elevation of the Sierra Nevada took place. The chief upheaval of the Rocky Mountain system came at the close of the Cretaceous and that of the Coast range at the close of the Miocene Tertiary. Smaller and less important oscillations have occurred before and since. Each elevation was accompanied by foldings, faultings, and extensive outpourings of eruptive rocks. The re- sultant fractures and the solfataric action, occasioned by the dying volcanic activity, constitute the primary cause of the for- mation of the ore deposits, which in some cases lie in ranges along the lines of faulting or of disturbances, and in others are irreg- ularly scattered. We can recognize the Coast range belt with mercury and chromium ; the California gold belt in the western Sierras ; the silver belt of Utah on the western flank of the Wa- satch ; a belt in Arizona from southeast to northwest, along the contact between Paleozoic limestone, mostly Carboniferous, and the Archaean ; and the great stretch of lead-silver mines in the Carboniferous limestones of Colorado. The other areas are scat- CONGL nniNG B EM A RKS. 32? tered, and apparently exhibit no such grand general relations to these geographical and geological phenomena.^ 2.16.02. In the Mississippi Valley, W. P. Jenney has re- marked the connection of the antimony and silver deposits of Ar- kansas with the Ouachita uplift that traverses that State and In- dian Territory ; also, the location of the Missouri lead and zinc ores along the Ozark uplift ; and he has referred the Wisconsin lead and zinc mines, as well as those in the neighboring part of Iowa and Illinois, to an uplift south of the Arch83an area of Wis- consin. The limitation of the Lake Superior copper deposits to the Keweenawan system may be mentioned, and such parallelism as prevails among the Lake Superior iron ores. In the East the great belt of Clinton Ores ; the long succession of Siluro-Cambrian limo- nites in tJie Great Valley ; the black-band ores and clayironstones of the Carboniferous ; the closely similar geological relations of nontitaniferous, magnetite lenses in the Archaean gneisses ; and the general association of titaniferous magnetites with rocks of the gabbro family the country over — all are striking illustrations of broad, general geological features that may characterize extended areas. To these may be appended the great series of pyritous beds or veins in the slates and schists of the East, the gold belt of the southeastern States, and the small copper deposits associated with the Triassic traps and sandstones. Aside from these, while there are important mines not included in the list, the others do not exhibit the same widespread uniformities of structure or asso- ciations. Yet, from the list cited, it forcibly appears that similar conditions have brought about related ore bodies over great stretches of country ; and while in the opening schemes of clas- sification points of difference were emphasized, in the closing pages points of resemblance may be with equal right brought to the fore- ground. 2.16.03. A few general conclusions suggest themselves from the preceding pages. (1) The extreme irregularity in the shape of metalliferous de- 1 G. F. Becker, Amer. Jour. ScL, 3d Series, Vol. XXIII., 1884 p. 309. W. P. Blake, Rep. Cal. State Board of Agriculture, 1866. S. F. Emmons, " The Structural Relations of Ore Deposits," M. E., XVI. 804. R. W. Ray- mond, " Geographical Distribution of Mining- Districts in the United States," M. K, I. 33. Fortieth Parallel Survey, Vol. III., Chap. I. " Pre- cious Metals," Tenth Census, Vol. XII. 338 KEMP'S ORW DEPOSITS. posits, and from this the unwisdom of the United States law in the West, which is based on well-defined fissure veins. The only practicable method is that a man should own all that is embraced in his property lines, whether the ore body outcrops outside or not. "A square location is the square thing " (Raymond). (2) The very general proximity of eruptive rocks in some form to the ore bodies. Except in the case of iron, there are only a few where these are not present, and apparently strong factors in the circulations which formed the ore. The lead and zinc deposits of eastern and western Missouri and the neighboring States, and of New York and Virginia, are almost the only ones, and we are justified in concluding that eruptive rocks are of great importance. (3) We know from the investigations of Sandberger and others that the dark silicates of many rocks contain percentages of the common metals. The choice is open whether to refer the ore to original dissemination in these, and derive it by gradual concentra- tion, probably at great depths, or to some indefinite unknown source, which can only be described as " below." INDEX. Abiquiu, N. M., copper ores, 183. Adams, F. D. , on granite at Douglass Island, 355. Agglomerates, 334. Alabama, Clinton ore, 105, 106. Gold mines, 391. Tin, 335. Alaska, geology, 393, 393. Aleutian Islands, 393. Algoma, platinum, 333. Alice mines, Butte, Mont., 354. Allegbany Mountains, geology, 8. Alturas Co., Idabo, 357. Aluminium, 397. Amador Co., Cal., 385. Ancram lead mine, N. T., 185. Antbony's Xose, N. Y., pyrrbotite mine, 154, 314. Anticlines, 11. Cause of cavities, 11. Antimony, 301, 303. Nevada, 366. Apacbe Co., Ariz., 363. Appalacbians, general description, 6, 7. Topograpby, 6, 7. Geology, 7, 8. Argentine, Clear Creek Co., Colo., 845. Arizona copper mines, 173-180. Geology. 361. Copper deposits, gossan of, 164. Lead-silver ores, 333. Prince copper mine, Ariz., 178. Silver mines, 336. Arkansas, antimony, 301. Bauxite, 397, 399. Iron ores, 86. Manganese, 306-308. Nickel, 333. Silver mines, 835. Arksut Fjord, Greenland, 397. Arlington, N. J., copper mines, 181. Arnold iron mines, N. Y., 140. Arsenic, 308. Ascension by infiltration, 89, 30-38. Asbcroft iron mines, Colo., 144. Asbland mine, Ironwood, Miob., 133. Aspen, Colo., 330-334, 345. Iron mines near, 144. Atlantic copper mine, Micb., 169. Augusta, Va., manganese, 305. Auriferous beacb sands, 374. Gravels, 877-388. Austin, Nev., 876. Antimony, 301. Bacbelor Mountain, near Creede, Cole 343. Baker Co., Ore., 373, 374. Bald Butte Co.'s mines, Mont., 855. Baltimore, Md., cbromite, 303. Banded structure of veins, 35. Bannack City, Mont., 353. Banner district, Boise Co., Idabo, 357. Bare Hills, Md., cbromite mine, 303. Barton Hill iron mines, N. Y., 139. Barus, C, experiments on electrical ac- tivity of veins, 40. 41. Experiments on tbe Comstock Lode, 869. Bassick mine, Colo., 35, 36, 347. Batesville, Ark., manganese, 366, 307, 308. Bauxite, 397, 398. Beacb deposits, 61. Bear Lake Co., Idabo, 857. Beaver Co., Utab, 859. Beaverbead Co., Mont., 853. Becker, G. F., precious metals in dia- base, 85. Cited on Steamboat Springs, Nev., 38. On tbe Comstock Lode, 867-871. On California gravels, 381. On California mercury, 369, 309- 311. Various metals in granite, 36. Beds, in sedimentary rocks, 10. Belmont, Nov., 864, 365. Belts of ore deposits in tbe West, 336, 337. Berks Co., Penn., iron mines, 143. Bernalillo Co., N. M., 338. Bessemer limit of Lake Superior ores, 78. Betblebem, Penn., zinc mines near, 804. Beulab antimony mine, Nev., 301. Big Cottonwood Caiion, Utab, 836. Big Creek, Nev., .801. Bimetallic mine, Butte, Mont., 355. 330 INDEX. Bingham Canon, Utah, 226, 259. Cited as illustration of gossan, 39. Birmingham, Ala., 107. Bisbee copper district, Ariz., 276. Bismuth, 302, 303. Bitter Root Mountains, Idaho, 256. Black-band iron ore, 96. Black copper groups of copper mines, Arizona, 178. Black Hills, geology, 9. Geology and mines, 240-242. Gold in Potsdam, 274. Placers, 279. Tin, 324. Black Range copper mines, Ariz., 179. Copper district, 263. Blake, W. P., on the Deep Creek mines, 259. On lead and zinc in Mississippi Valley, 193. On the Silver King mine, Arizona, 262. On Tombstone, Ariz., 263. On Utah antimony, 302. Ruby silver ore, Poormau lode, 257. Blende in the Rocky Mountains, 211. Block iron ore, 96. Block Island, R. I., magnetite sands, 151. Blow, A. A., Illustration of fault by, 17. Cited on Leadville, Colo., 219. Bluebird mine, Butte, Mont. , 255. Blue lead in California gravels, 280. Bl ue Mountains, Oregon, 273. Bog iron ore, 79. At Three Rivers, Quebec, 80. Precipitated by algae, 82. Boise Co.. Idaho, 257. Bonanza City, Idaho, 257. Bonanza of ore, 37. Bonne Terre, Mo., lead mines, 186. Bonneville, Lake, 264. Bonsacks, Va., illustration of gossan, 39. Zinc mines, 200. Boone cherts, Arkansas, 307. Boss of igneous rock defined, 11. Boston Mountains, Ark., 307. Boulder Co., Colo., 248. Iron ores, 144. Box Elder Co., Utah, 259. Boyd, C. R. , on zinc in Virginia, 202. Boyertown mines, Penn., 150. Brandon, Vt., manganese, 305. Bristol, Conn., copper mine, 181. British Columbia gold gravels, 295. Platinum, 323. Britton, N. L., cited on the geology of the Highlands, N. J. , 151. Britton, N. L., on Staten Island bog ore, 81. Brooks, T. B., on the Marquette dis- trict, 115, 116. Origin of ores, 120. Browne, D. H., on phosphorus in iron mines, 153. Browne, R. E., on California gravels, 280, 381. Brunton, D. W., cited on Aspen, Colo., . 222. Bucks Co., Penn., iron mines, 143. Buckwheat mine, Franklin Furnace, N. J., 207. Buena Vista, Colo., 246. Buford Mountain, Mo., 134. Buhrstone ore, 97. Bull Domingo mine, Colo., 36, 247. Burden spathic ore mines, Hudson, N. Y., 98. Burro Mountains, N. M., 237. Butte, Mont., 354. Copper mines, 137, 143, 162, 163, 168. Illustrates infiltration by ascension, 32. Placers near, 379. Cahaba coal field, Ala., 107. Calavaras Co., Cal., 385. Caldwell Co., Ky., lead and zinc mines, 195 Calico district, Cal., 376. California, chromite, 303. Copper mines, 162. Literature, 163. Geology, 375, 282, 289. Gulch, near Leadville, Colo., 245, 279. Kern Co., antimony. 301. Lead-silver ores, 232. Magnetite, 144. Mercury, 309, 310. Platinum, 333. Tin, 325. Gallon scheme of classification of ore deposits, 47. Calumet and Hecla copper mines, Mich igan, 169. Iron mine, Colorado, 144. Campbell Mountain, near Creede, Colo., 243. Campo Seco, Cal., copper mines, 162. Canada, bog ore, 80. Gold, 294, 295. Magnetite ore mines, 140. Canso, N. S., 294. Cape Breton, N. S., manganese, 308. Capelton, Quebec, mines of pyrlte, 154; chalcopyrite, 160. Carbonate Hill, Leadville, Colo., 217. INDEX. 331 Carbonite mine, Utah, 239. Carpenter, F. R., on the Black Hills, S. D., 251. On Black Hills tin, 325. Carson Hill, Calavaras Co., Cal., 284. Cartersville, Ga., manganese, 305. Cascade Mountains, 273. Cascade Range, Cal., 275. Cassia Co., Idaho, 257. Cassiterite, 324. Cave mine, Utah, 329. Caves, origin of, 21. As a form of ore body, 57. Cave Spring manganese mines, Georgia, 305. Cazin, P. M. F., on Silver Reef, Utah, 250. Cedar Mountain, Mo., 134. Central City, Colo., copper mines, 165. Chaffee Co., Colo., 246. Magnetite, 144. Chalcopyrite with pyrite, 160-162. Literature, '161. Chamberlin, S. C, on Wisconsin lead and zinc mines, 163, 189-191. Chambered vein, 309. Chalcopyrite with nickel ores, 58. Charlemont, Mass., mines of pyrite, 154. Charles Dickens mine, Idaho, 357. Chateaugay iron mines, N. Y., 138. Chaudiere River, Canada, gold, 395. Chauvenet R,, cited on Colorado iron ores, 149. Cherry Valley, Mo., 111. Chester, A. H., on the average yield of certain well-known iron ores, 77. Chicago copper mine, Arizona, 178. Chico beds, California, 309. Chimney of ore, 37. Chisholm, F. F., on Cuban ores, 158. Chromite distribution, 303. Chromium, 303. Mines, California, 336. Chugwater Creek, Wyo., iron ores, 149. Church, J. A., on the Comstock lode, 367, 368. Churchill Co., Nev., 266. Chute of ore, 37. Cincinnati uplift, 9. Cinnabar, 309. Clark, E., on Lake Valley, N. M., 214, 215. Clarke, F. W., on the composition of the earth, 78. Classification of ore deposits, 43, 67. Classification of ore deposits, underly- ing principles, 43. Clay ironstone defined, 95. Deposits of, 95-97. Clay selvage, seam, or parting, 37. Attrition clay, 37. Residual clay, 37. Clayton, J. E., on Butte, Mont., 254. Clayton's law, 37. Clear Creek Co., Colo., 245, 246-248. Clear Lake, Cal., mercury, 309. Clerc, F. L., cited on zinc mines of southwestern Missouri, 196-198. Cliff copper mine, Michigan, 169. Clifton, Ariz., copper district, 173. Clinton ore, 102-109. Distribution, 103-108. Origin, 108. Clinton ores, general relations, 327. Coal measures, classification of in Pennsylvania, 96. Coastal Plain, 291. Geology, 8. Topography, 6. Coast Range belt of mines, 336. Chromite, 303. Oregon, 39. Washington, 373. Cobalt, 304. Cochise Co., Ariz., 363. Coeur d'Alene, Idaho, lead silver ores, 226. Colfax Co., N. M., 338. Colombia, platinum, 333. Colorado, geology, 238. Gold at Cripple Creek, 349. Iron ores, 88. Lead-silver mines, 216-235, 375. Magnetite, 144. Literature, 144. Plateau, 7-9. Silver and gold, 339-350. Spathic iron ore, 98. Columbia Co., N. Y., lead mines, 185. Columbia Hill, gravels, California, 379. Comb-in-comb structure in a vein, 35. Comstock lode, Nev., 367-271. Comstock, S. B., on Red Mountain, Colo., 224. On vein systems of the San Juan, 240. Conejos Co., Colo., 246. Connecticut, bismuth, 303. Lead mines, 185. Limonite, 89, 94. Magnetite sands, 151. Roxbury siderite, 100. Contact deposits, 60. Cobalt, ores and general remarks, 313-314. Coosa coal field, Ala., 107. Copper Basin, Ariz., 179. 332 INDEX. Copper Creek, near Gothic, Colo., 345. Copper Falls copper mine, Michigan, 169. Copper Mountain, Ariz., copper district, 373. Copperopolis, Cal., copper mines, 163. Copperopolis copper mine, Utah, 180. Copper ores, analyses of ore minerals, 160. Copper Queen mine, Arizona, 178. Copper, statistics, 183. Cordillera region, general geology, 386. Cornwall, Penn., iron mines, 143, 145, 146. Literature, 145. Corundum, as an ore of aluminium, 300. Costillo Co., Colo., iron mines, 144. Cotta, B. von, on filling of mineral veins, 38. Schemes of classification of ore de- posits, 44^6. Courtis, W. M., on the microscopic structure of gold-quartz, 385. Cranberry magnetite mines. North Car- olina, 143. Crawford Co., Mo., red hematites, 110. Credner, H., on origin of Marquette ores, 130. Creede, Colo., 341-343. Crimora, Va., manganese, 305. Cripple Creek, Colo., 349. Crismon-Mammoth copper mine, Utah, 180, 194, 328. Crittenden Co., Ky., lead and zinc veins, 195. Crosby, W. 0., cited on joints, 13. On classification of ore deposits, 67. Cross, W., on the mines near Rosita, Colo., 247. Crustification, 65. Cryolite, 300. Cuba iron ores, 157. Cumberland iron mine, Colorado, 144. Curry Co. ore, 274. Curtis, J. S., cited on caves, 21. On Eureka, Nev., 197, 830, 331. On growth of aragonite crystals, 34. On replacement, 33. On silver, in quartz porphyry, 25. Custer Co., Colo., 212, 213, 246, 247. Idaho, 257. Custer mine, Idaho, 357. Dakyns and Teall, cited on origin of magnetite, 158. Dall, W. H., on Alaska, 292. Dana, divisions of geological time, 4. Davison Co., N. C, lead mines, 185. Dawson, G. M., on Douglass Island, 293. Deadwood, S. D., 351. Deep Creek mines, Utah, 259. Deep gravels, California, 279. Deer Lodge Co. , Mont. , 255. Deer Trail mine, Utah, 260. De la Biche, electrical activity of veins, 41. DeLaunay, cited, 66. Delaware, chromite, 303. Del Norte Co., Cal., chromite, 803. Deloro, Can., arsenic mine, 308. Deloro (Marmora), Can., gold mine, 895. Dent Co., Mo., iron ores. 111. Devereux, W. B., cited on Colorado iron ores, 144. Devonian system at Hamilton, Kev., 365. Diaclases. See under "Joints." Dickerson iron mine, New Jersey, 153. Dike defined, 11. Distinction from vein, 11. Cause of earthquakes, 17. Diller, J. S., cited on Kentucky perido- tite, 195. On California, 875. On the California gravels, 283. Dillsburg mines, Penn., 150. Doe Run, Mo., lead mines, 186. Dolomitization, 31, 22. Dolores Co., Colo., 239. Dona Ana Co., N. M., 214. Douglass Island, Alaska, 286, 393. Drinker, H. S., cited on the Saucon Valley zinc mines, 805. , Drumlummon mines, Montana, 255, 356. Dry Canon, Utah, 838, 259. Ducktown, Tenn., illustration of gos- san, 39. Mines of pyrite and chalcopyrite, 154, 161. Dutton, Capt. C. E., cited on the geol- ogy of New Mexico, 237. Dyestone iron ore, 103. " Dyestone ranges," 104. Eagle Co., Colo., 245. Eagle River district, Colo., 320. Earth, average composition of crust, 78. Eastern sandstone, Keweenaw Point, Mich., 166. Egan Canon, Nev., 365. El Dorado Co., Cal., 285. Electrical activity of ore bodies, 269; of veins, 40. Elk Jlountains, Colo., 245. Iron mines, 144. Elko, Nev., 365. Elko Co., Nev., 266. INDEX. 333 El Paso Co., Colo., 349. Ely copper mines, Vermont, 135, 160, 161. Emma mine, Utab, 228. Emmons, E. , Jefferson Co., N. Y., red liematites, 113. Emmons, S. F., cited on replacement, 33. • On Butte, Mont., 164 On country rock of Boulder Co., Colo., 248. On Leadville, Colo., 217-319. On Red Mountain, Colo., 224. On the mines near Rosita, Colo., 247. Endlich, P. M., on gold mines, near Ouray, Colo., 340. Enterprise, Miss., spathic ore, 98. Esmeralda Co., Nev., 266. Etta granite knob, with tin ore, 273. Eureka Co., Nev., 266. Electrical activity of ore, 369. Illustration gossan, 39. Lead- silver, 330. Evigtok, Greenland, cryolite, 300. Fahlbands, defined, 63. Fairplay, Colo., 346, 279. Farish, J. B., illustration by, 20. On the veins at Newman Hill, near Rico, Colo., 240, 241. Faults, cause of, 13. Defined and described, 17-20. Hade, 17. Norma], 18. Reversed, 18. Schmidt's law of, 18. Step faults, 30. Feather River, Cal.,375. Felch Mountain, area and iron ores, Michigan, 118. Fisher Hill iron mines. New York, 139. FlagstafE mine, Utah, 338. Flagstone iron ore, 96. Flaxseed iron ore, 103. Fiotz defined, 43. Floyd Co., Ga., bauxite, 297. Flucan of a vein, 37. Foerste, A. F., on Clinton ore, 108. Folds, various kinds defined, 11. Axes of, 11. Cause of cavities, 13. "Pitch "of, 11. Forest of Dean iron mine. New York, 141. Forest Queen mine, Ruby district, Colo., 245. Formation defined, 5. Fort Laramie, Wyo., iron ore near, 132. Fossil iron ore, 103. Foster and Whitney, cited on Mar- quette district, 115. Foster and Whitney, Marquette dis- trict, origin of its ores, 118. On Keweenaw Point copper, 170. Fousnet's series, 58. Franklin copper mines, Michigan, 169. Franklin Co. , Mo. , lead and zinc mines, 194. Franklin Co. , Va. , magnetite, 143. Franklin, N. J., 141. Franklin Furnace, N. J., 174, 175-179, 304, 305-309. Iron mines, 143. Frankiinite, 304. Eraser, P., on Penn. magnetite, 150. FredHand, F. T., cited on faults, 19. Fremont Co., Colo., magnetite, 144. French Creek mines, Penn., 150. Friedensville zinc mines, Penn,, 204. Frisco, Utah, 339. Fritz Island mine, Penn., 150. Frost Drift, North Carolina, 391. Fryer Hill, Leadville, Colo., 317. Fuchs and De Launay, cited, 66. Fulton, J., on the Menominee district, 108, 121, 122. Gagnon vein, Butte, Mont., 163. Galena (town), S. D., lead-silver mines, 335. Gangue, minerals forming, 33. Source of, 36. Gap mine of pyrrhotite, Pennsylvania, 154, 315. Gatling arsenic mines, Deloro, Can., 303. Genesee antimony mine, Nevada, 301. Genth, F. A., on Boulder Co., Colo., 248. On gold in Southern States, 391. Geology, modern standpoints, 3. Tabulation of geological sub-divis- ions, 4, 5. Georgetown, Colo., 348. Georgia, bauxite, 297. Clinton ore, 105. Limonite, 93. Manganese, 305. Geyser mine, Custer Co., Colo., 347. Gilbert, G. K., cited on joints, 13. Illustration loaned by, 15. Gilpin Co., Colo., 248, 286. Banded veins, 35, Copper mines, 165. Glendale, Mont., 353. Lead-silver ores, 325. Glenmore estate, West Virginia, 109. Globe copper district, Arizona, 178, 263. Gobebic district of Lake Superior, 123. 334 INDEX. Gold, Alaska. 293, 294. Black Hills, 251. California, 284-286. Mineralogical associates, 287. In sea beaches, 280. Nova Scotia, 294. Occurrence and ores, 234. Oregon, 274. Quartz, 284. Quartz veins, 284. Southern States, 291. Statistics, 295. Washington, 273. Gold Cup mine, Tin Cup, Colo., 245. Gossan, 88. Gossan lead of Virginia, 85. Gothic, Colo., 245. Gouge of clay in a vein, 37. Graham Co., Ariz., 263. Granby. Mo., zinc and lead mines near, '171, 195-199. Grand Cafion of the Colorado, 261. Granite, Chaffee Co., Colo., 246. Granite Mountain mine, Butte, Mont., 255. Granite in mines of pyrite, Ontario, 156. Grant Co., N. M., 237. Grant Co., Ore., 274. Great Basin, 3-7, 10. In California, 275. In Oregon, 273. Great Eastern mercury mine, 309. Great Lakes, geology, 8, 9. Great Valley, 8, 327. Iron ores, 88. Great Western mercury mine, 309. Green-eyed Monster mine, Utah, 260. Greenland cryolite, 297. Green Mountain placers, 279. Green River, Utah, 224, 258. Greensands, iron ores in, Texas, 87. Greisen with tin ores, 324. Griffin. P. H. on Quebec bog ore, 80. Grimm J., scheme of classification of ore deposits, 50. Groddeck, A. v., scheme of classifica- tion of ore deposits, 51. Gulf region, geology. 9. Gunnison Co., Colo., iron mines, 144. Gunnison region, Colorado, 245. Hade of a fault, 17. Hague, A., cited on Wyoming iron ore, 144. On Hamilton, Nev., 265. Hague, A., and Iddings, J. P., on the Comstock lode, 267, 270, 271. Haile gold mine. South Carolina, 291. Hall, C. E., cited on the iron mines of the Adirondacks, 140. Hamilton, Nev., 265. Hammondville, N. T., iron mines^ 140, Hampton and Eureka copper miueg, Arizona, 179. Hancock, Midi., 166. Hanging Rock region, Ky., 85. Spathic ores, 97. Hanover, N. M., zinc, 212. Harrington, B. J., cited on the origin of magnetite, 153. Hartman zinc mine, Pennsylvania, 204. Hastings Co., Can., 302. Haworth, E., cited on zinc and lead ores of southwestern Missouri, 198. Hayes, C. W., illustration by, 18. On southern bauxite, 298. Hecla iron mine, Colorado, 144. Hecla mines, Glendale, Mont., 225. Hecla mines, Montana, 253. Helena, Mont, 255. Hematites, red and specular, table of analyses, 136. Henrich, C, cited on Aspen, Colo., 223. On Clifton, Ariz., copper mines, 174. On the Slayback lode. New Mex- ico, 238. Henry Co., Va., magnetite, 143. Hesse, Germany, bog ore, 82. Hiberuia iron mines. New Jersey, 142. High or deep gravels, California, 279. Hill, R. T., on iron ore in Mexico. 158. Hills, R. C!. , cited on the chemistry of replacement, 34. On the Little Annie mine, Colo., 246. On the vein systems of the San Juan, 240. Zone of enrichment in the mines of the Summit district, Colo., 39, 40. Hinsdale Co., 239. Hoefer, H., cited on faults, 19. Hogan Mountain, Mo., 134. Homestake mine, Eagle Co., Colo., 245. Honorine mine, Utah, 228. Horizon defined, 5. Horn Silver mine, Utah, 229, Horses of barren rock in a vein. 36. Hot Springs iron mines, Colorado, 88, 144. Huerfano Co., Colo., 246. Humboldt Co., Nev., 266. Antimony, 301. Humboldt-Pocahontas mine, Custer Co., Colo., 247. Humboldt Range, Nev., 265. On the iron mines of the Adiron- dacks, 140. Hurd iron mines. New Jersey, 142. INDEX. 335 Hysteromorphic ore bodies, 65. Ibapah range, Utab, 259. Ice, veins of, on Mount McClellan, Colo., 245. Idabo, geology, 356. Lead silver ores, 235, 336. Tin, 325. Idabo Springs, Colo., 248. Iddings, J. P., on basaltic columns, 13. On tbe Comstock lode, 367, 370, 271. Idiogenites, 65. Igneous roclis, defined and rougbly classified, 6. Forms assumed by, 11. Illinois lead and zinc mines, 189. Independence, Colo., 245. lugersoU granitic knob, witb tin ore, 334. International Geological Congress, 1885, classification recommended by, 3,4. Inyo Co., Cal., antimony, 301. Ion defined, 58. Iowa iron ores, 88. lovpa lead and zinc mines, 189, Ireland, bog ore, 83. Iridium, vpitb platinum, 333. Iron Co., Utab, 360. Magnetite, 151. Literature, 151. Iron hat, 38. Iron Hill, Leadville, Colo., 317. Iron in rocks, 78. Iron King iron mine, Colorado, 144. Iron Mountain, Colo., 144. Iron Mountain, Missoula Co., Mont., 256. Iron Mountain, Mo., 134, 153. Bibliography, 136, 137. Porphyries, 135. Iron ores, bibliography of general pa- pers, 75. Brown hematite ore, 79-94. General remarks on, 76-79. Impurities, 77. Iron ore, magnetite, 137, 153. Iron ore localities: Adirondack Mountains, 138, 140. Alabama, 93. Clinton ore, 103, 106. Colorado, 98. Connecticut, 89-94, 100. Cuba, 1.58. Georgia, 93. Clinton ore, 105. Hesse, Germany, 83. Ireland, 82. Kentucky, 97. Clinton ore, 103. Iron ore localities: Maryland, 91. Clinton ore, 104. Massachusetts, 89-93, 88. Mexico, 158. Michigan: General outline. 111. Marquette district, 105.116-119. Monominee district, 131, 123. Penokee-Gogebic district, 132. Minnesota: Vermilion district, 135, 137. Mesabi range, 127. Missouri : Cambrian, 110. Iron Mountain, 134. Lower Carboniferous, 109. Pilot Knob, 132. Mississippi, 98. Montana, 68. New Jersey, 90. New York, 89, 94. Burden mines, 98. Clinton ore, 103. Jefferson Co., 110. Wawarsing, 100. North Carolina, 93, 98. Specular, 133. Nova Scotia, Clinton ore, 108. Ohio, 97. Clinton ore, 102, 103. Oregon, Port Townsend Bay, Port- land, 83. Pennsylvania, 96. Adams Co., 94. Franklin Co., 83. Huntingdon Co., 83. Lehigh Co., 90, 93. York Co., 85, 90, 93, 94. Clinton ore, 103. Mansfield ores, 109. Tennessee, 91. Clinton ore, 104. Vermont, 89. Virginia, 89-91. Clinton ore, 104. West Virginia, 97. Clinton ore, 104. Oriskany ore, 109. Wisconsin, Clinton ore, 102. Menominee district, 121, 122. Penokee-Gogebic district, 122, 124. Wyoming, 98. Iron ore, pyrite, 154, 155. Red and specular hematite, 103-137 Iron ores: Siluro-Cambrian limonites. 89-94. Spathic, 95-100. Statistics, 157. 336 INDEX. Iron ores: Swedish lakes, 83. Table of and compositions, 76. Irving and Van Hise on the Marquette district, 115, 116. Origin of the ores, 120. Irving, E. D., cited on Silver Islet, 236. On replacement, 33. Penokee-Gogebic district, 124. Ishpeming, Mich., gold, 292. Isle Royale, Lake Superior, 166, 168, 171. Izard limestone, 307. Jacque Mountain, Summit Co., Colo., 245. James River, Va., iron ores, 131. Jasper Co., Mo., zinc and lead mines, 196. Jayville iron mines. New York, 140. Jefferson Co., N. Y. , iron ore, 112. Jefferson Co., Mont., 253. Jefferson Co. , Mo. , lead and zinc mines, 194. Jenney, W. P., cited on Arkansas sil- ver mines, 235. On lateral enrichments, 37. On lead ores of southeastern Mis- souri, 187. On lead and zinc mines of the Mis- sissippi Valley, 192. On mines of Mississippi Valley, 327. On the Head Center mine, Tomb- stone, Ariz., 31. On zinc and lead mines of south- western Missouri, 198. Johnson, L. C. , on Louisiana iron ores, 87. Joints defined, 12. Jones mine, Penn., 150. Joplin, Mo., zinc and lead mines, 171, 195-199. Josephine Co., Oregon, 274. Juab Co., Utah, 259. Julien, A. A., action of organic acids on rocks, 21. Cited on the origin of magnetite, 153. Juragua Hills, Cuba, iron ores, 157. Kaolinization at the Comstock lode, 269. Kelley lode. New Mexico, 214. Kemp" J. F., scheme for the classifica- tion of ore deposits, 53-55. On Missouri lead deposits, 187. Kennedy, W., on Texas iron ores, 87. Kentucky, lead and zinc ores of Liv- ingston Co., 194. Clinton ore, 103. Limonite or brown hematite orej,85. I Kentucky, spathic ores, 97. Kern Co., Cal., antimony, 301. Kerr, W. C, on North Carolina gold, 291. Keweenaw Point, Mich., copper, 166, 171. Kimball, J. P., cited on the Burden mines. New York, 98. On Cuban iron ores, 157. On Jefferson Co., N. Y., red hema- tites, 113. On origin of siderite, 101. King, C, on the Comstock lode, 267, 268. Kinahan, J. H., cited on joints, 13. Kittitas Co. , Washington, gold, 273. Klausen in the Austrian Tyrol, veins illustrating lateral secretion, 31, 33. Knob of igneous rock defined, 11. Koehler, G., cited on faults, 19. Scheme of classification of ore de- posits, 47. Lahontan Lake, 264. Laccolite defined, 11. Lac la Belle, Keweenaw Point, 169. Lager defined as contrasted with " Flotz " and " Gang," 43. Lagoni, cited, 58. Lakes, A., cited on Aspen, Colo., 223. Lake Champlain iron region, 138. Magnetite sands, 151. Lake Co., Colo., 245. Lake of the Woods, gold district, 295. Lake Superior gold region, 295. Iron ore districts. 111. Mines, 327. Lake Valley, N. M., lead -silver ores, 214, 215. Lancaster Co., Penn., chromite, 303. Lander Co., Nev. 266. Antimony mines, 301. Lane's mine, Monroe, Conn., 302. La Plata Co., Colo., 239. LassensPeak, Cal., 275. Last Chance Gulch, near Helena, Mont., 245, 255. 279. Lateral enrichments in a vein, 37; se- cretion, 29. Lead City, Black Hills, 251. Leadville, Colo., 185, 216-219. Figure of Moyer Fault, 17. Lead minerals, 184. Statistics, 188. Leadsilver ores, 214. Lebanon, Penn., 147. Leconte, J., on California gravels, 281. On joints, 13. On mercury deposits, California, 309. INDEX. 337 Leconte, J., scheme of classification of veins, 45. Lehigli Co., Penn., iron mines, magne- tites, 143. Lenses of ore, 63. Lesley, J. P., on Cornwall, Penn., 149. Lesser metals, 397-328. Lesquereux, cited on Calif ornia gravels, 280. Lewis and Clarke Co., Mont., 255. Lewis Mountain, Mo., 234. Lime Creek, Colo., Lower Carbonifer- ous fossils, 233. Limonite, deposits of, 79-95. See also under iron ore for geographical distribution. Analyses, 95. Lincoln Co., Nev., 264. Lincoln Co., N. M., 238. Lindgren on Wickes, Mont, 226. Lindgren, W., on Calico district, Cal., 277. On the geology of the California gravels, 282. Little Annie mine, Rio Grande Co., Colo., 346. Little Belt Mountains, Mont., 356. Little Cottonwood Canon, Utah, 226. Little River iron mines. New York, 139. Little Rock, Ark., bauxite, 300. Livingston Co., Ky., lead and zinc mines, 194. Llano Co. , Texas, copper mines, 166. Lottner-Serlo scheme of classification of ore deposits, 47. Louisa Co., Va., mines of pyrite, 154. Louisiana iron ores, 87. Lovelock, Nev., antimony, 301; nickel, 333. Lowville, Lewis Co., N. Y., lead mine, 185. Lubeck, Me., lead mine, 185. Lucky Boy mine, 260. LyndUurst, Va., manganese, 305. Lyon Co., Ky., iron ores, 85. Lyon Co., Nev., 266. Lyon Mountain, N.Y., iron ores, 188. Mackenzie River, gold gravels, 295. Madison Co. , Mont. , 253. Magdalena Mountains, N. M., 214. Magna Charta mine, Butte, Mont., 354. Magnet Cove, Ark., magnetite, 87. Magnetite iron ore, 131, 138-154. Analyses, 154. General description, 138. Origin of, 152. Origin in igneous magmas, 56. Ore bodies, general relations, 327. Sands, 151. Maine tin, 325. Manganese, 366, 304-308. Statistics, 308. Mansfield ores, Pennsylvania, 109. Margerie and Heim, cited on faults, 18. Maricopa Co., Ariz., 262. Mariposa Co., Cal., 285. Mariposite, 285. Markhamville, N. B., manganese, 308. Marmora, Can., arsenic mine, 302. Gold mines, 295. Marquette district. 111. Marshall tunnel, Georgetown, Colo., 38. Maryland, chromite, 303. Clinton ore, 104. , Gold mines, 291. Limonite, 91. MarysviJle, Utah, 260. Marysville, Mont., 222, 256. Massachusetts, lead mines, 185. Limonite, 89-93. Spathic ore at Gay Head, 98. McGee, W. J., Appomattox and Colum- bia formations, 5. On joints, 13. Meagher Co., Mont., 256. Melaconite, Keweenaw Point, 170. Mendota mines, Keweenaw Point, 170. Menominee district. Lake Superior, 131. Mercury, 269, 309-311. Mines, California, 326. Mercury, mineralogical associates, 311. Mesaba Mountain mine, 129. Mesabi range, Minnesota, 127, 139. Metacinnabarite, 309. Metamorphic rocks, defined and roughly classified, 6. Michigan, copper, 166. Gold, 292. Marquette district, 116-119. Menominee, 107, 108, 131, 132. Penokee-Gogebic, 122. Middletown, Conn., lead mine, 185. Milan, N. H., mines of pyrite, 154. Chalcopyrite, 160. Mine la Motte, Mo , anticlines, 60. Lead mines, 186, 187. Nickel, 333. Mineral Point, Wis., copper ores, 193. Mineville, N. Y., iron mines, 122, 139, 140. Mine waters with dissolved metals, 40. Minnesota copper mines, 171. Mesabi range, 127. Vermilion district, 125, 137. Missabe. See Mesabi. Mississippi, spathic ores at Enterprise 97. 338 INDEX. Mississippi Valley, geology, 9. Lead and zinc mines, 189. Relations of ore bodies, 337. Missoula Co., Mont., 256. Missouri, Cambrian bed hematite in Crawford, Dent and Phelps Counties, 110. Copper at St. Genevieve, 171. Iron Mountain, 134. Lead mines of southeastern Mis- souri, 186. Limonite, 86. Lower Carboniferous red hematite, 99. Pilot Knob, 133. Red hematites, 110. Tin, 325. Zinc and lead in the southwest, 195. Mitchell Co., N. C, iron mines, 143. Mohave Co., Ariz., 262. Moisie, Can., magnetite sands of, 151. Monarch district, Chaffee Co., Colo., 330, 246. Monheim, V., on the origin of willem- ite, 310, Monocline defined, 11. Montana, Butte, 137, 163, 163. Montana, geology of, 352. Lead-silver ores, 225, 326. Silver and gold mines, 332, 253- 256. Spathic iron ore at Sand Coulee, 98. Tin. 325. Montville, N. J., 141. Moore, P. N. , on Missouri limonite, 86. Morenci, Ariz., copper district, 173. Moricke, on gold in Chilian volcanic rocks, 25. Mosquito range, Colo., 216. In Park Co., Colo., 346. Mother lode, Cal., 285. Mount Baldy, Utah, 260. Mount Davidson, Nev., 367. Mount Hope, K. J., 141. Mount Marshall, near Georgetown. Colo., 348. Mount McClellan, Clear Creek Co., Colo., 345. Mount Prometheus, Nev., 266. Mount Shasta, Cal., 375. Mule Pass Mountains, Ariz., 176. Munroe, H. S., citation from, 30, 62. Cited on the origin of magnetite, 153. Scheme of classification of ore de- posits, 52, 53. Murphree's Valley, Ala., 107. Musconetcong iron belt. New Jersey, 142. Nacemiento copper mines, New Mexico 261. Nason, F. L., cited on the geology of the Highlands, N. J., 141. On geology near Franklin Furnace, N. J., 205. On Missouri iron ores, 110, 111. Neck of igneous rock defined, 11. Neihart, Mont., 256. Nelson Co., Va., tin, 325. Neocomiau beds, California, 367. Nevada, antimony, 301. Geology, 364. Lead- silver mines, 230. Nickel, 332. New Almaden, Cal., mercury, 309. Newberry, J. S. , cited on the Cave mine, Utah, 339. On Clinton ore, 98. On Silver Reef, Utah, 360. Scheme of classification of ore de- posits, 48, 50. Newberry, W. E., cited on Aspen, Colo., 222, 224. New Brunswick, antimony, 301. Manganese, 308. New Brunswick, N. J., copper mines, 181. Newburyport, Mass., lead mine, 185. New Caledonia nickel, 332. New England, outline of geology, 7, 8. New Hampshire, tin, 335. New Idria, Cal., mercury, 309, 310. New Jersey copper ores, 181. Iron mines, 141, 143. Limonite, 90. Outline of geology, 7, 8. Zinc mines, 205. New Jersey Zinc and Iron Co.'s mine, Franklin Furnace, N. J., 206. Newman Hill, Colo., banded veins, 35, 36. Figure of faulted vein at, 30. Lateral enrichments, 37. Mines of, 365. New Mexico, geology, 336. Lead-silver mines, 314. Silver and gold mines, 336-238. Triassic copper ores, 182. Zinc, 212. Newton, Amador Co., Cal., copper, 163. Newton Co., Mo., zinc mines, 196. New York copper mine, Arizona, 178. New York: Iron mines of the Highlands, 141. Literature, 143, 143. Iron ore of Adirondacks, 138, 139. Literature, 140, 141. Lead mines, 185, 186. INDEX. 339 New York: Limonite, 89, 94. Outline of geology, 7, 8. Spathic ore of Burden mines, 98. At Warwarsing, 100. Clinton ore, 103. Jefferson Co.. 110. Ney Co., Nev., 265. Nicholas, W., cited on precipitation of gold, 286. iSTicbolson, F., on tlie St. Genevieve, Mo., copper mines, 172. Nickel, Arkansas, 322. Nevada, 322. Norway, .57. Ores and general remarks, 312- 314. Pennsylvania, 57. Nickeliferous pyrrbotite, igneous or- igin, 56, 57. Northampton, Mass., lead mine, 185. North Carolina, gold mines, 391. Limonite, 93. Magnetite, 143. Literature, 143. Nickel, 331. Spathic ores, 98. Specular ores, 132. Tin, 325. Nova Scotia, Clinton iron ore, 108. Gold, 294. Nova Scotia, manganese, 308. Oat Hill mercury mine, 309. Ogdensburg, N. J., 204, 205-209. Ohio, Clinton ore, 102, 103. Spathic Ores, 97. Okanogan Co.. Wash., 272. Old Dominion copper mine, Arizona, 178. Oliver mine, Virginia, Minn, 139. Olmstead, I. , cited on the Burden mines, New York, 99. Olympic Mountains, 273. Oneida Co., Idaho, 357. Ontario, arsenic mine at Deloro, 303. Nickel mines, 315-317. Ontario mine, Utah, 359. Ontonagon, Mich., 269. Ophir Caiion, Utah, 228, 359. Oquirrh Mountains, Utah, 236, 259. Orange Co., N. Y., iron mines, 141. Ore deposits, bibliography, 68-71. Oregon, geology, 273. Mercury, 309. Oregon, nickel ores, 331. Ore Knob, N. C, copper mines, 160, 161. Ores, minerals forming, 23. Original source of, 33. Of iron, table of, 76. Organic matter as a precipitating agent, 59. Orton, E., cited on dolomitizatiot, 33. Osmium, with platinum, 323. Ouachita uplift of Arkansas, 198, 335, 337. Ouachita Mountains, Ark., iron ores, 86. Ouray Co., Colo., 339. Owybee Co., Idaho, 257. Oxford, N. J., 141. Ozark uplift, 7, 110, 133, 198, 337. Pacific slope, geology, 10. Pahranagat district, Nev., 365. Palmer Hill iron mines, N. Y., 140. Park Co., Colo., 346. Passaic iron belt. New Jersey, 143. Pearce, R., bismuth with gold in Col- orado, 386. On gold ores of Gilpin Co., Colo., 248. Pechin, E. C, on Virginia iron ores, 85. Penfield, S. L., on pentlandite, 58. Peninsula copper mines, Michigan, 168. Pennsylvania, Cornwall, 146. Penrose, R. A. F., on Arkansas iron ores, 86. On Louisiana iron ores, 87. On manganese, 306-308. Pennsylvania, brown hematites. See under Iron, brown hematite. Chromite, 303. Clinton ore, 103. Lead mines, 165. Limonite, 83, 90, 93, 94. For index of counties see under Iron ores, limonite. Mansfield ore, 109. Spathic ores, 96. Penokee-Goffebic district, Lake Supe- rior, 133. Pentlandite, 313. Pequest iron belt, New Jersey, 143. Perkiomen copper mine, Pennsylvanif , 181. Phelps Co., Mo., iron ores. 111. Phillips, S. A., scheme of classification of ore deposits, 49. Phoenix copper mine, Michigan, 169. Phosphorus in iron ores, 77, 78. Pilot Knob, Mo., 132. Bibliography, 136, 137. Pima Co., Ariz,, 263. Pinal Co.. Ariz., 263. Pincbes and swells in a vein, ,37. Pioche, Nov., 264. Pipe clays in California gravels, 380. Pitkin, Colo., 245. Piute Co., Utah, 260. Placer Co., Cal., iron ores, 144 Chromite, 303. 340 INDEX. Placers, 277-384. Plateau region of Wyoming, 350. Platinum, 833. Platoro, Couejos Co., Colo,, 346. Point Orford, Ore., 374. Poorman lode, Idalio, 357. Portage Lake, Michigan, 169. Porter, J. B., cited on Clinton ore, 108. Port Henry, N. Y. , iron mines near, 139, 140. Posepny, F. , on the origin of ores, 64. Cited on replacement theory for Raibl, 83. Power, F. D., on classification of ore deposits, 66. Prairie region, 9. Of Wyoming, 350. Prescott, Ariz., 179. Prickly Pear Gulch, near Helena Mont. , 355, 379. Pride of the West mine. Eagle Co. Colo., 345. Prime, F., and Von Cotta, scheme of classification of ore deoosits, 46 47. Printer Boy mine, Leadville, Colo., 217 Prosser mines, Oregon, 83. Psilomelane, 304. Puget Sound, 373. Pumpelly, R., cited on replacement, 88, On suhaerial decay, 59. On Keweenaw Point copper mines 170. On Missouri iron ores, 110. Scheme of classification of ore de posits, 51, 53. Putnam Co., N. T., iron mines, 141. Pyrite, 154, 155. Literature, 155. Origin of, 155. Pyrite ore bodies, general relations, 337. Pyrolusite, 804. Quaquaversal defined, 11. Quaco Head, X. B., manganese, 308. Quartz veins, 62. Quincy copper mine, Mich., 169. Quicksilver (mercury), 309-311. See also under Mercury. Quogue, Long Island, magnetite sands, 151. Radnor Forges, Quebec, 81. Raibl, Austria, silver-lead deposits, originating by replacement, 33. Rainbow lode, Butte, Mont,, 354. Rainier Mountain, 373. Ramapo iron belt, N. J., 143. Ramshorn mine, Custer Co., Idaho, ' 357. Ranges of ore deposits, 336, 327. Raymond & Ely mine, Piocbe, Nev., 264. Raymond, R. W., 828. Red Cliff, Eagle Co.. Colo., 245. Red Mountain, Birmingham district, Ala., 107. Red Mountain, Mont., 254. Red Mountain, Ouray Co., Colo., 234. Red Rock, San Francisco, manganese, 308. Reese River district, Nov., banded veins, 35. Geology of, 364. Rensselaerite, 113. Replacement, method of vein filling by, 83. Residual deposits, 61. Reyer, E., on the Marquette ores, 130. Rickard, T. A., on Australian gold- quartz, 388. Rico, Dolores Co., Colo., lead-silver mines, 334. Riddle's, Oregon, nickel, 831. Rifting in granite at Cape Ann, Mass., 13. Rim of deep gravels. California, 379. Rio Grande Co., Colo., 346. River gravels with gold, 377. Roaring Fork Creek, Colo., 333. Robert E. Lee mine, Leadville, Colo., 317. Robinson mine. Summit Co., Colo., 330. Rockbridge Co., Va., tin, 335. Rocks, classification of, 6. General percentage of iron oxide, 78. Rockv Mountains, geology, 9. Zinc ores, 309. Rogers, H. D., on geology at Franklin Furnace, N. J., 305. RoLker, C. M., cited on Colorado iron ores, 144. On Silver Reef, Utah, 360. Rominger, C, on the Marquette dis- trict, 115, 116. Ropes mine, gold, Michigan, 293. Rosenbusch, H., cited on succession of rock forming minerals, 34. Rosita, Colo., 346, 347. Rothpletz, A., cited on oolites, 59. Rothwell, R. P., on Silver Reef, Utah, 360. Roubidous sandstone, Mo., 110. Roxbury, Conn., spathic ore, 100. Ruby, Colo., 245. Russell, I. C, cited on Clinton ore, 108. Russia, platinum, 323. Rye, N. Y., bog ore, 81. INDEX. 341 Sacramento Valley, 277. Saddles of gold-bearing quartz in Aus- tralia, 288. Saguache Co., Colo., 24iX-2iS. Salt Lake Co., Utah, 259. San Benito Co., Cal., antimony, 301., San Bernardino Co., Cal,, iron ore, 145. Sandberger, F., cited on source of ores, 25. Barite in limestone, 26. On lateral secretion, 30. San Diego Co., Cal., iron ores, 145. San Emigdio, Kern Co., Cal., antimony, 801. Sangre de Cristo range, Colorado, 246. Sandia Mountains, N. M., 238. San Joaquin Co., Cal., 308. San Juan Co., Colo., 239. Bismuth, 302. San Juan Mountains, 239. San Juan region, Colo., 239. San Luis Obispo Co., Cal., chromite, 303. San Miguel Co., Colo., 240, 279. Santa Fe Co., N. M., 238. Placers of, 279. Santa Rita, N. M. , copper mines, 178, 179. Santa Rita Mountains, 237. Saucon Valley zinc mines, Pennsyl- vania, 204, 205. Schmidt, A., on Missouri iron ores, 110, 236. On replacement theory as applied to Missouri iron ores, 33. On zinc mines of southwestern Missouri, 196. Schapbach in the Black Forest, veins at, 31. Schuyler copper mine. New Jersey, 181. Sedimentary rocks defined and roughly classified, 6. Forms assumed by, 10, 11. Segregation as applied to magnetite, 153. Senarmontite, 301. Sevier Co., Ark., antimony, 301. Shasta Co., Cal., chromite, 303. Shear zones defined, 13. Sheet of igneous rock defined, 11. Shepherd Mountain, Mo., 134. Shumagin, Alaska, 254. Siderite, iron ore, 95-100. Genetic relations, 101. Sierra Co., Cal., iron ore, 144. Sierra Nevada, chromite, 303. Sierra Nevada in California, 275. Geology of, 289. Sigmoid fold defined, 11. Silliman, B., on gold quartz, 284. Siluro-Cambrian limonites, 327. Silver and gold, mode of occurrence, 233 *^34 Silver belt of Utah. 326. Silver Bow Co., Mont., 254. Silver Bow Creek, Butte, Mont., 162. Silver, California, 276. Silver City, Idaho, 257. Silver Cliff, Colo., 246, 247. Silver Islet, Lake Superior, vein illus- trating lateral secretion, 31. Literature, 31. Mines, 235. Silver King mine, Arizona, 262. Silver minerals, 284. Silver Plume, Colo., 248. Silver Reef, Utah, 182, 260. Silverton, Colo., 241. Silver, Washington, 273. SI ay back lode. New Mexico, 238. Slickensides, or slips, defined, 18, 19. Smithfield iron mine, Colorado, 144. Smuggler Mountain, near Aspen, Colo., 223. Smyth, C. H., Jr., on Clinton oolitic ores, 101. On Clinton ore, 108. On Jefferson Co. , N. Y. , red hema- tites, 112. Snake River, Idaho, basalt, 256. Placers, Idaho, 279. Socorro Co., N. M., 238. Sonora, Mex., antimony, 802. Soret's principle, 57, 145. South Dakota, lead-silver ores, 225. Geology, 250. Southern States, gold, 291. South Mountain, Penn., iron mines, 141, 193. Literature, 142, 143. South Park, Colo., 246. South Wailingford, Vt., manganese, 305. Spanish Peaks, Colo., 246. Spathic iron ore, 95-100. Spenceville, Cal., copper mines, 162. Sperrylite, 320, 323. Spurr, J. E., on Mesabiores, 129. St. Clair limestone, Arkansas, 307. St. Frangois Co., Mo., gash veins, 194. St. Genevieve, Mo., copper mines, 171. St. Lawrence Co., N. Y., lead mines, 184. St. Mary's mine, Penn., 150. Stanley-Browne, J., cited on gold in sea beaches, 274. Stannite, 324. Star district, Utah, iron mines, 151. Staten Island bog ore, 81. 343 INDEX. Steamboat Springs, iSTev., illustrate in- filtration by ascension, 32. Mercury mines, 309. Stein Mountains, Ore., 273. Stelzner, A. W., cited on source of ores, 25. Sterling Hill zinc mines, Ogdensburg, N. J., 204-208. Stevens Co., Wash., gold, 372. Stibnite, 301. Stokes Co., N. C, magnetite, 148. Storey Co., Nev., 266. Straban, A. , cited on explosive slicken- sides, 19. Stream tin, 324. Structure of veins, 35. Sudbury, Ontario, 154. Sudbury, Can., nickel ores, 57, 315, 317. Sullivan Co., N. Y., lead mines, 186. Sullivan, Me., silver mines, 235. Sulphur Bank, Cal., mercury mine, 309. Summit Co., Colo., 245. Ten. Mile district. 319, 320. Summit Co., Utah, lead silver, 329. Silver mines, 259. Summit district, Rio Grande Co., Colo., 286. Sunrise, Wye, copper, 180. Sweden, lake ore, 82. Sweetwater district, Wyo , 279. Sylvanite mine, Gothic, Colo., 345. Syncline defined, 11. Cause of cavities, 14. Tacoma Mountain, 373. Tamarack copper mines, Michigan, 169. Tarr, R. 3., on rifting, 13; cited; 64. Telegraph mine, Utah, 228. Telluride ores, Colo., 248. Tellurides in gold quartz, 284. Temescal tju mines, California, 335. Tem Pahute district, Nev., 365. Ten-Mile district, Colo., 319, 245. Tennessee, Clinton ore, 104. Tennessee, limonite, 86, 91. Tenny Cape, N. S., manganese, 308. Terrane defined, 5. Texas, copper, Llano Co., 166. Iron ores, 87. Triassic or Peruvian copper ores, 182. Thiess-Hutchins antimony mines, Nev., 301. Three Rivers, Quebec, bog ores, 80. Thunder Bay, Lake Superior, 336. Tilly Foster iron mine, N. Y., 141, 143. Tin," 324, 325. Tin Cap, Colo., 245. Tintec district copper mines, Utah, 180. Utah iron ores, 88. Lead-silver, 238. Other silver mines, 359. Titaniferous magnetite, 140, 145. In the Adirondacks, 145. In Canada, 145. Colorado, 146. Minnesota, 146. New Jersey, 146. North Carolina, 146. Norway, 146. Virginia, 146. Tombstone district, Arizona, 363. Tooele Co., Utah, 338, 259. Tourtelotte Park, near Aspen, Colo., 323. Toyabe range, Nev., 366. Treadwell mine. Alaska, 394. Triassic copper ores, 180-183. Copper mines, general relations, 337. Trigg Co. , Ky. , iron ores, 85. Trotter zinc mine, Franklin Furnace, N. J., 306. Tucson, Arizona, 363. Tuolumne Co.. Cal., 385. Turner, H. W., on the California grav- els, 283. Tuscarora district, Nev., 366. Tybo, Nev., 265. Ueberroth zinc mine, Penn., 204. Uintah Mountains, 10, 258. Ulster Co., N. Y., lead mines, 186. U. S. Antimony Co., Philadelphia, 301. United States Geological Survey, terms used by in geological classification, 4. Results of work in the Sierras, 283. United States, general geology, 7-10. General topography, 6, 7. Uralitization in the rocks of the Corn- stock lode, 270. Utah, antimony, 301. Copper, 180. Geology, 258. Iron ores, 88. Lead-silver ores, 226-330. Magnetite, 151. Silver mines, 326. Triassic copper ores, 182. Vadose circulations, 65. Van Diest, P. H., on Boulder Co., Colo., 348. Van Dyck, F. C. , analysis by, 307. Van Hise, C. R., cited on replacement, 33. On the Marquette district, 115, 116. On the Penokee-Gogebic district, Lake Superior, 134. INDEX. 343 Veins, metlaods of filling, 28. Verde River, Ariz., 179. Vermilion district, Lake Superior, 135. Vermilion Lake iron ores, origin of, 60, 61. Vermont, copper ores, 160, 161. Limonite, 89. Versliire, Vt. , mines of pyrite, 154. Chalcopyrite, 160. Virginia, Clinton ore, 104. Limonite or brown hematite, 91. Louisa Co., pyrite, 154. Magnetite, 143. Manganese, 305. Virginia City, Mont., 353. Vogt, J. H. L., on nickel ores, 57, 330. On the origin of pyrite bodies, 156. Von Herder, on filling of veins, 38. Von Richthofen, on the Comstock lode, 367-370. Vuggs of a vein, 35. Wadsworth, M. E., on the Marquette district, 115, 116. On Silver Islet, 336. On classification of ores, 64. Origin of the ores, 118. Wagon Wheel Gap, Colo., 343. Wall rock of veins, precipitating influ- ence of, 81. Wardner, Idaho, lead-silver ores, 336. Warren or Bisbee copper district, Ari- zona, 176. Warrior coal field, Ala., 107. Wasatch Mountains, 9, 358. Washington Co., Mo., lead and zinc mines, 194. Washington, geology, 372. Washoe Co., Nev., 266. Webb City, Mo., zinc and lead mines near, 195-199. Webster, N. C, nickel. 321. Weed, W. H., on siliceous sinters, 59. Weissenbach, Von, scheme of classifi- cation of ore deposits, 44. Wendt, A. F. , on Arizona copper mines, 175. Western sandstone, Keweenaw Point, 168. Westport, N. Y., iron mines, 138. West Virginia, Clinton ore, 104. Oriskany, red hematite, 109. Spathic ores, 97. Wet Mountain Valley, Custer Co., Colo., 246. Wheatfield mine, Penn., 150. Wheatley lead mine, Penn., 165. White Pine Co., Nev., 265. Whitney, J. D., cited on Missouri ores, 136. On California gravels, 281. Whitney, J. D., on gold veins, 286. On lead and zinc veins of the Mis- sissipi Valley, 191. On Washington Co., Missouri, lead and zinc mines, 194. Scheme of classification of ore de- posits, 48. Wickes, Mont., lead-silver mines, 336, 854. Williams, J. P., on Arkansas bauxite, 397. Willis, B., on Cornwall, Penn., 149. Willow Creek, near Creede, Colo., 343. Wiltsee, E., on the Half Moon mine, Pioche, Nev., 264. Winchell, H. V., on Mesabi ores, 139. Winchell, N. H. and H. V., cited on origin of Vermilion Lake iron ores, 63. Winchell, N. H., cited on the Vermil- ion Lake district, 125. Winchell, H. V., on origin of ore, 127 Winslow, A., on Missouri lead and zius 200. Winslow, tin, 325. Wisconsin, Clinton ore, Dodge Co., 102. Lead and zinc mines, 189. Menominee district, 121, 122. Penokee-Gogebic district, 132, 124. Wood River mines, Idaho, lead-silver, 225, 257. Woods mine, chromite, 308. Wright, C. E., origin of Lake Supe- rior ores, 120. Wyoming copper mines, 180. Geology of, 250. Iron mines, 144. Iron ore near Fort Laramie, 132. Spathic iron ore, 98. Specular ore near Fort Laramie, 133. Tin ores, 325. Wythe Co., Va., zinc, 201. Xenogenites, 65. Yakima Co., Wash., gold, 272. Yakutat Bay, Alaska, 274. Yarmouth, N. S., 294. Yavapai Co., Ariz., 362. York Co., N. B., antimony, 301. Yuma Co., Ariz., 263, 363. Yukon River, Alaska, 393. Zinc minerals, 204. Zinc ores at Hanover, N. M., 362. In Rocky Mountains, 311. Virginia, 201. Statistics, 313. Zirkel, F., on the rocks of the Com- stock lode, 370. Zone of oxidized ores in a vein, 38. Of sulphides, 38. The Mineral Industry, ITS Statistics, Technology and Trade, IN THE UNITED STATES AND OTHER COUNTRIES, FROM THE EARLIEST TIMES. Vol. I. From the Earliest Times to the Close of I 892, Vol. II. Supplementing Vol. I " " Vol. III. " Vols. I & II " Vol.IV. " Vols. 1, II & III " Vol.V. " Vols. I to IV " BY RICHARD P. ROTHWELL. Editor of the Engineering and Mining Journal, Ex-President American Institute of Mining Engineers, Member American Society of Civil Engineers, Fellow Royal Statistical Society, etc., etc £ s. d. 1892, ,g2.50 10 5 1893, 5.00 1 10 1894, 5.00 1 10 1895, 5.00 1 )0 1896. 5.00 1 ID These are the most thorough and exhaustive works published in any language on mining, metallurgy, markets, and uses of the commercial minerals and metals. Every one interested in knowing the very latest and best methods in use for mining, extracting, and refining the useful minerals and metals, and the amounts and values of each produced and consumed in every part of the world, can find the information in these annual volumes. 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