vtasomS^^V THE GIFT OF ENGINEERING LIBRARY A^Alffg^-. ±[§l\.%k.. Cornell University Library 131.A33 3 1924 005 064 195 .«> The original of this book is in the Cornell University Library. There are no known copyright restrictions in the United States on the use of the text. http://www.archive.org/details/cu31924005064195 GEOLOGICAL SURVEY OF MISSOURI. ARTHUR W1NSLOW, STATE GEOLOGIST. VOL. II. A REPORT QN THE IRON ORES OP MISSOURI FROM FIELD WORK PROSECUTED DURING THE YEARS 1891 and 1892. With 62 Illustrations and One Map. BY FRANK L. NASON, Assistant Geologist. PUBLISHED BY THE GEOLOGICAL SURVEY. JEFFERSON CITY. December, 1892. NIXON-JONES PMNTING CO., 215 Bine St., ST. LOUIS. BOARD OF MANAGERS. Governor DAVID R. FRANCIS, Ex-officio President of the Board, Jefferson City. / / G. C. BROADHEAD Columbia. WM. B. POTTER ... . .... St. Louis. J. H. BRITTS . . . . . . Clinton. W. O. L. JEWETT Shblbina. STATE GEOLOGIST. ARTHUR WINSLOW . ... . . N . Jkffbrson City (iii) ASSISTANTS. F. L. NASON, assistant geologist, C. R. KEYES, paleontologist. Specialties : Iron and Manganese. H. A. WHEELER, ass't geologist, Specialty : Clay. PAUL SCHWEITZER, ass't geologist, Specialty : Mineral Waters. ERASMUS HAWORTH, ass't geologist, J. E. TODD, ass't geologist, Specialty : Crystalline Rocks. Specialty : Quaternary Geology. J. D. ROBERTSON, chemist & ass't in C. F. MARBUT, ass't in Zinc and Lead Work. Charge of Detailed Mapping. E. H. LONSDALE, ass't in LEO GLUCK, ass't in Iron Ore Work and Detailed Mapping. Clay Work. T. B. MAKBUT, aid in Detailed Mapping. S. R. MANN, Secretary. TEMPORARY AND LOCAL ASSISTANTS. C. H. GORDON, Special Assistant in the Coal Fields. (iv) E. W. NEWTON, Local Assistant m Polk County. LETTER OF TRANSMITTAL. Office of the Geological Survey, ) Jefferson City, Missouri, y December 17th, 1892. j To the President, Governor David It. Francis, and the members of the Board of Managers of the Bureau of Geology and Mines : Gentlemen — I have the honor to transmit, herewith, a Report upon the Iron Ores of Missouri, by Mr. Frank L. Nason, assistant geologist. During the progress of the earlier surveys of the State the iron ores have been subjects of more or less attention. In Part II, of the Report of 1854, the two important iron mines of southeastern Missouri, the Iron mountain and Pilot Knob deposits, were described by Dr. Litton. In Chapters III. , IV. , V. and VI. of the Report of 1872, or what is known as the Pumpelly Report, the iron ores of the State received fuller treatment than ever before, by Dr. Adolph Schmidt. These chapters covered the iron ores of the porphyry region, the specular ores in sand- stone, the red hematites and the deposits of limonite in limestone. In the Report of 1873-74, or the Broadhead Report,' the limonites of southeastern Missouri are described. The fact that these ores had already received a good share of atten- tion in these earlier reports influenced the present Survey to delay their further examination until other subjects, which had received, heretofore, less study and which demanded notice, had been provided for. During the past few years, however, there has been a noticeable and lamentable decline in the iron industry of the State. Reference to Appendix B, at the end of this Report, will show the extent to which the iron ore pro- duction of the State has fallen off. Missouri, from having been in the year 1880 the sixth State in the Union in the production of iron ores, has now fallen to the rank of the thirteenth State. It was largely in recognition of the fact of this decline of Missouri's iron industry that the investigation of the iron deposits of the State was resumed in 1891. It was thought that a careful study of the region in which the various ores occur, aided by the light thrown upon the deposits by the developments of the twenty years which have elapsed since the last report was published, conclusions would be reached which VI LETTER OF TRANSMITTAL. would lead to the discovery of new ore deposits. How far and in what manner these anticipations have been realized will be detailed in the following pages. N Mr. Nason began work for the Survey early in the summer of 1891. His field work was completed and the greater part of his report written by the end of the summer of the year 1892. As is self-evident, such an amount of work could not be accomplished in so short a period without a thorough knowledge of the subject and a mastery of the methods of work, combined wi*h unflagging industry. Mr. Nason exhibited all of these qualities and he is to be complimented and the State to be congratulated upon the product of this short period of work. In the first part of the report Mr. Nason describes, in successive chapters, the various classes of ores, entering into detail with certain types of each class and discussing quite fully the origin and general , geology pf the different kinds of deposits. His theoretical deductions concerning the sources of the iron ores and their modes of accumula- tion are of the most direct value in the future development 1 of the ores. Although they may be termed by some, mere theories, they are theories based upon a careful observation and study of all the available facts. Such study is the only sound basis of knowledge, and the conclusions reached by it are always worthy of respect. It is true that sufficient facts are not always available for an absolute certainty to be reached ; at times a conclusion may be considered to rank as high as a certainty ; at other times it may deserve to rank merely as a suggestion. In all cases it is the best that can be obtained and in this light is always valuable. Correspondingly the results reached in this report are of variable value. Some conclusions which Mr. Nason has reached he shows are indubitable and can be followed without hesitation ; others he offers as mere suggestions, such alone as the meager supply of facts will allow of. The second part of this Eeport consists entirely of short descriptions of the more prominent iron ore localities of the State, visited and examined by various members of this and earlier Surveys. In the Schmidt Report of 1872, 257 such localities were mapped. On the map accompanying the present report 636 are located. This additional work was principally done by Mr. E. H. Lonsdale during the spring and summer of this year. He is also the author of many of the descrip- tions here published. It will be noted, however, that a large number of the descriptions from the report of 1872 are reprinted here. The reason for this is that at some of these localities the opportunities for examination are at present not so good as they were when the earlier work was done ; but in most cases the copied descriptions are of local- LETTER OF TRANSMITTAL. Vll ities at which no further work has been done since that time, and, hence, nothing can be added to the earlier writings. The descriptions of these occurrences are sometimes very brief. This is, however, necessarily so in many cases, because very little is to be seen. The principle has been followed out, however, that a few facts are better than none at all and that even a few words, describing the topographic location and the surface occurrences of ore, were better than a mere designation of the locality on the map. These descriptions must be read with an understanding of the general conclusions expressed in the preceding chapters in order that the prospector or miner may use them to the best advantage. In the township index, at the end of this volume, will be found a complete list of all iron ore localities described, arranged by townships. The idea of this index is to enable one to see at a glance just what deposits occur and are described within any specified area. It will be noticed that throughout this report the term Cambrian is applied to the rocks of the Ozark region in place of the term Silurian, which has heretofore been used. This, as explained in a foot-note on page 1 7, is because the stratigraphic studies of the Survey are tending to the conclusion that these rocks belong more properly to the Cambrian age than to the Silurian. The evidence in support of this we hope to adduce soon in a future publication of the Survey. Suffice it here to say that such evidence seems sufficient to warrant the departure here from previously accepted practice. Not only, however, is it probable that changes will be made in the age assigned the members of the Ozark series, but, as Mr. Nason has shown, in Chapter V. of this report, on the General Geology, it is prob- able that the details of the sections of these series will also undergo considerable modification. Other studies, besides those prosecuted by Mr. Nason, goto show that the division of the series into First, Second) Third and Fourth Magnesian Limestone, separated by persistent sand- stone beds, will not hold. In a paper soon to be published in the Amer- ican Journal of Science, the writer shows that the classification of the members of the so-called ''Magnesian Series," in St. Francois and Ste. Genevieve counties, was radically wrong. Mr. Nason has found it necessary, for the purposes of his report, and as indicative of the changes necessarj', to apply two names to members of the Ozark series. These are the " Roubidoux Sandstone " and the " Gasconade Lime- stone." These names express his classification of the rocks. They are accepted here provisionally until more extended work than he had opportunity to engage in, shall demonstrate their entire tenability. Concerning the porphyry ores of Pilot Knob, Mr. Nason has reached V1H LETTEK OF TRANSMITTAL. certain conclusions at variance with the results expressed concerning the origin of the porphyries by Mr. Haworth in Bulletin No. 5 of this Survey. During the past summer a conference and joint excursion to this field was arranged for. The party consisted of Prof. C. R. Van Hise, Prof. Wm. B. Potter, Mr. Nason, Prof. Haworth and the writer. A result of this trip and the consequent discussion on the ground was the yielding, by Mr. Haworth, of his position with reference to the origin of the porphyry conglomerates, iron ores and other immediately associated beds, occurring at the summit of Pilot Knob and at a few other localities in the immediate vicinity. Mr. Haworth now concedes that the evidence favors the conclusion that these beds are of sediment- ary origin rather than of igneous origin as previously advocated by him. As is frequently referred to and explained at different places in the following Report, it has been absolute^ impossible to reach, examine and report upon all the iron ore localities in the State, during the brief period and" with the small means allotted to the work. The area is too vast; the occurrences are too numerous. Effort has been made to direct attention merely to the principal areas and localities"; to describe types and emphasize principles rather than to include exhaustive details. It is, however, nevertheless true, that, in many sections of the iron re- gions of the State, detailed work could be advantageously prosecuted, and it is the intention of the Survey to prepare in the future, as supple- mentary to this report, a series of topographic and geologic maps of im- portant areas in the iron ore region, upon which shall be located all the various iron ore deposits, as well as other occurrences of economic value. A detailed report will accompany each of these sheets, describing every- thing of interest. The map attached at the end of this report is intended primarily to show the geologic and geographic distribution of iron ores. In addition, however, it is issued as a provisional geological map of the State. It embodies the results of the work of the several Geological Surveys of the State up to date. It is the intention to issue similar maps with each successive volume of publications, each one to express the result's of the most recent work-. i , Mr. Nason, in his preface, has considerately expressed his indebted- ness to various gentlemen for assistance in the prosecution of his work. I take pleasure in joining with him here in an expression of gratitude to the citizens of the State who have so courteously assisted and en- tertained him. I especially wish to acknowledge Prof . Wm. B. Potter's assistance in the contribution of data and in the revision of the chapter on the porphyry ores. To Mr. Geo. H. Nettleton and to Mr. Louis LETTER OF TRANSMITTAL. IX Houck we are particularly indebted for assistance rendered in the prosecution of the work along the lines, of their roads. Mr. Geo. C. Smith, assistant general manager of the Missouri Pacific system, has also extended us many favors, and to the St. Louis and San Francisco Ey. we are similarly under obligations. In the preparation of the Statistical Sketch, Appendix B, we received particularly valuable assistance from Mr. E. B. Sankey of Salem, Messrs. T. T. Lewis, E. A. Hitchcock and Wm. B. Potter of St. Louis ; from Messrs. J. L. Buskett and Wm. Kelley of Rolla, and from Mr. Wm. James and his book-keeper, Mr. Bacon, of St. James. In the proof-reading of this report Mr. J. D. Robertson has ren- dered much assistance, and he has also prepared the General Index at the end ; the Geographical Index was prepared by Mr. E. H. Lons- dale. Such literary defects and errata as exist in this volume must be attributed in large part to the unavoidable haste with which the work was put into print. I transmit this report with the feeling that it is a valuable and serv- iceable contribution to the literature of our iron ores, and with the hope that it may directly assist in the resuscitation of the iron industry of the State. Very respectfully submitted, Arthur Winslow, State Geologist., PEEFACE. In making a report on the iron ores of Missouri, one is, at the very outset, confronted with a difficulty of no little magnitude. In round numbers, what may be called the iron-producing belt covers an area of 30,000 square miles. This includes, 1st,, the porphyry districts ; 2d, the specular ore district; 3d, the limonite ore district; 4th, the bedded red hematite district, and 5th, the bog ore district. This last has had no definite boundaries. In forming an idea of the value of any ore deposits one must be largely influenced by the knowledge which may be acquired from deposits which have been worked in the past. No surface prospect, however promising, can give definite and reliable data upon which to base calculations as to extent, and, conse- quently, value. In other words, surface indications give only two dimensions ; the third dimension which is invaluable can only be gained either from actual trial of the locality in question, or by analogy from the inspection of similar deposits which have been worked. In the great area given above there are at present only the following workings : two localities ^in the porphyry ore district, four in the specular ore district, one^in the great limonite district, and in the red hematite district not'a singlejone. The reasons for this state of inactivity are various, but as these have^been pointed out in the appended reports on the various districts they will not be touched upon here. The diffi- culties which this condition entails upon the worker in such fields can only be fully appreciated by one who has had experience in such work. Another obstacle to study which mining districts generally present, and the Missouri iron district in particular, is inaccessibility, the lack of railroads, the lack of good public roads, the inevitable concomitants of a scattered population, make the expenditure of a great amount of time absolutely unavoidable. Yet this difficulty has been largely obviated, or at least obviated to a greater degree than would at first seem possible, by the hearty and intelligent co-operation of the citizens of the iron ore district. Considering these difficulties, and the limited time which could reasonably be placed at the disposal of the writer for this work, the following plan was devised and carried out so far as practicable. Instead of attempting a detailed examination of each township, to study (xi) Xll PREFACE. in a general way, 1st, the modes of occurrences ; 2d, the character- istics of the ores; 3d, the geographical distributions, the results of these operations resulted in the division of the limonite ore district into the Ozark district, the Osage district and the Mississippi district. These districts are not exactly outlined, this is impossible, but they indicate, ^ in general, a distinct geographical distribution, and form convenient points from which to work. The idea has been to distribute the time allowed in the following manner. To give the greatest amount of time to points practically untouched in previous surveys, though controlled by the promise of iron ore in a given district : second, to distribute the remaining time as seemed best to serve the objects of a general report upon the iron ore of the whole State. By consulting the "Preliminary Map showing the Distribution of Iron Ores of Missouri" by Dr. Adolph Schmidt, Geological Survey of Missouri, 1872, it will be seen that considerable work was done on the limonites on the Belmont branch of the Iron Mountain railway and on the middle Osage river. The deposits there pointed out are as yet hardly touched, the Osage deposits especially, and attention has thus been called here to these localities as possible ore fields. The whole tier of counties along and immediately above the Arkansas border from and including Stoddard county to Taney county was hardly touched. There are ten counties and only six localities reported. The work of the Survey shows this field to be at least as productive as any in the State, and consequently much time has been devoted to it. Even the most conscientious effort to locate every outcrop of iron ore, would in the end fail in the present state of development of the coun- try. It has not, therefore, been attempted. Enough work has been done to prove that limcnite ore exists in sufficient quantity to warrant the erection of local furnaces for its smelting and that other conditions- are favorable for such an enterprise. This fact has been enlarged upon in the report. The location of ore deposits that has been done means, however, more than the mere fixing of these outcrops alone. One outcrop points certainly to others, neither now located nor re- ported, and the particular aim of the work done has been to point the direction in which others may be confidently looked for. In the porphyry ore regions there is little use in minute examinations. The high grade of the ores and their accessibility to markets has stim- ulated private research to such a degree that probably every outcrop is known. Moreover, the detailed study which Prof. Haworth, with his assistants, has pursued, would inevitably have resulted in the discovery of such deposits had they existed. This careful study has resulted in PREFACE. XI 11 a discouraging, or at least a negative state of affairs. No new localities have been discovered. Attention in this field has, therefore, been confined to a careful study of the great deposits of Iron Mountain and Pilot Knob, to the probable conditions of their origin, and to the probabilities of the existence of other deposits now hidden from sight. The conclusions reached from this course of investigation are not capable of exact verification without considerable expense, but it is earnestly believed that prospecting along the lines laid down in the following report will, in many cases, be successful. The same method has been pursued in the specular ore field in the sandstone region. Here, owing to the greater number of deposits which are now being worked or which have been worked, data of a much more satisfactory nature has been available. The conditions of occurrence and mode of deposition are seen with what seems to be unmistakable clearness. Basing his conclusions on the facts thus obtained, the writer has little hesitation in hazarding the prediction that the future of this district is at least as bright as its past has been. The red- hematite district has never been brought into notice as an iron-producing belt. " Some exploring has been done in Callaway and Henry counties. The work has shown the beds to be ihin and rather uncertain. Some of the beds could be worked with profit if a furnace were near by, but there is not in this field a promise of ore sufficient to warrant a plant's being erected. Enough work has been done in this field to establish the fact that the ores are of good quality, and that they are bedded deposits. To sum up briefly the foregoing statements, it has been the aim of the Survey to establish districts in which iron ores were most abundant ; to get at the nature of the deposit in order that subsequent prospecting might be done in the most intelligent manner, and to determine if conditions were favorable to the establishment of local smelting works. The result has been gratifying, . for even with the most conservative estimates the question has an affirmative answer. In the prosecution of the work on the iron ores the writer is greatly indebted to the State Geologist for his cordial support in the work as well as for direct and valuable assistance in many ways and especially in the preparation of this report. Editorial supervision is always a wearisome and oftentimes a thankless task, and it is with pleasure that I acknowledge my indebtedness for this assistance. In the field many have given such personal assistance as not only to materially forward the work, but to make the work itself a pleasure. The writer wishes to tender his cordial thanks to Prof. W. B. Potter, of St. Louis ; Mr. Geo. XIV PREFACE. H. Nettleton, president of the K. C. M. and B. E. R., of Kansas City; Dr. J. H. Britts, of Clinton ; Mr. E. L. Foote, superintendent of Sligo Furnace; Louis Houek, Esq., Cape Girardeau, president of St. L., C, G. and Ft. S. R. R. ; J. B. White, Esq., general manager, Missouri Lum- ber & Mining Co., Grandin ; Capt. John Halstead, West Plains; Mr. David Carson, West Plains; Dr. J. E. Mosley, Alton; Messrs. Sanky, Salem ; Mr. E. A. Kimmel, of Cape Girardeau ; Mr. H. W. Hickman, Puxico, Stoddard Co. ; Dr. Taylor, Brownington ; Mr. L. W. Munsell, Eminence ; Mr. E.^Y. Gannett, Nelson. This list could be indefinitely extended were the writer to mention every one to whom he is indebted for kind attentions. It is a matter of no little pleasure to acknowledge the cordial manner in which he has been received. During the field season of 1892 Mr. E. H. Lonsdale has assisted me, both in the field and in the preparation of the report. The chapter on the " Special Description of Iron Deposits " is almost exclusively his work ; it is with pleasure that I acknowledge his assistance. To Mr. J. D. Robertson, of the Survey, I am indebted for many of the draw- ings in the accompanying text and I gladly take this opportunity of acknowledging the same. Mr. A. Schmidt has reproduced many of the photographs and these are credited to him in the body of the report. F. L. N. CONTENTS. Page. Letter of Transmittal v Preface xi PAET I. CHAPTER I. Introduction. The Ores of Iron 1 The Forms in which Iron occurs 1 The Ores of Iron 1 The Maguetites . 3 The Hematites 4 The Limonites 4 The Carbonates -5 The Relative Values of Iron Ores 6 The Influence of the Percentage of Iron 7 The Influence of Deleterious Accessories 7 The Influence of Proximity to Market 7 The Influence of Impurities on Product 8 CHAPTER II. The Iron Ores op Missouri 12 The Classes of Ores , 12 The Distribution of the Ores 13 CHAPTER III. The Specular Ores of the Porphyry Region 16 Introductory Remarks 16 The Distribution of the Crystalline Rocks 16 The Topography 16 The Lithology 18 The Associated Minerals 19 The Relations of Porphyries to Cambrian Rocks 20 The Iron Ores, their Modes of Occurrence 21 The Iron Mountain Ore District 23 Early Description by Dr. Litton 23 The Distribution of Vein Ore in the Porphryry 24 The Residuary Clays and Boulder Ores 26 Pilot Knob 32 Early Description by Dr. Litton 32 The Character of the Ores 34 The Modes of Occurrence 34 The Boulder Ores 34 The Massive Ores 36 The Conglomerates -. 38 Cedar Hill ; 40 Shepherd Mountain ■. 41 Clark's Mountain 42 • (XV) XVI CONTENTS. PAGE. The Composition of the Specular Ores ia Porphyry * 2 The Iron Mountain Ores 42 The Pilot Knob .Ores is The Shepherd Mountain Ores * 6 The Cedar Hill Ores i7 Complete Analyses *7 The Origin of the Iron Ores 50 Topographic Changes Involved 57 ' Formation of the Pilot Knob Beds 61 Limitations of Theory Advanced 65 Bearings of Theory on Future Developments 65 Summary 69 CHAPTER IV. The Red Hematites of Missotjei 70 Henry County 70 Monroe County 71 Lincoln County 73 Callaway County 75 Cooper County 79 Saline County 80 Benton, Henry and St. Clair Counties 80 Conclusions 82 The Source of the Ores 82 The Extent of the Deposits- 82 The Cost of Mining 83 The Accessibility of the Ores 83 CHAPTER V. The General Geology op the Ozark Uplift 85 The Ozark Mountains 8 5 Area and General Characteristics 85 Topographic Subdivisions 86 The Soils 88 The Drainage 88 Springs and Subterranean Erosions * 90 The Vegetation 92 The Rocks Composing the Uplift 93 The Minerals of the Region 95 The Stratigraphy of the Ozarks 95 Earlier Correlations and Descriptions 97 The First Magnesian Limestone 100 The Saccharoidal Sandstone > 100 The Second Magnesian Lim,estone * 101 The Second Sandstone 101 The Third Magnesian Limestone 102 Inadequacy of Earlier Observations 102 Means Available for Correlation • : 104 Sections along the Big Piney, Gasconade and Current Rivers 104 Disturbance of Strata 108 Paleontology of the Region 110 The Identity of the First Sandstone Questionable 112 Nomenclature 1 CONTENTS. xvii page. CHAPTER VI. The Specular Ore op Sandstone Region 1 16 Introduction U6 General Distribution. : 116 Geological Horizon of the Ores 117 Character of the Ores and Associated Minerals US Chert Associated with the Ore 119. Relations of Sandstones and Ores 120 Simmons Mountain Mine 12$ Description hy Dr. Adolph Schmidt 123. Present Conditions 125 Principles taught by this Deposit 127 The Cherry Valley Mines 129 Description by Dr. Adolph Schmidt in 1872 130 Present Condition 131 Attitude of Sandstone explained 133 Conditions Affecting the Extension of the Ore Deposit 134 Cherry Valley and Simmons Mountain compared 136 Peculiarities of the Ores 137 The Origin of the Specular Ores in Sandstone 138 Evidences of Past Erosion 138 Evidences of Underground Erosion 139 Mode of Ore Accumulation 140 Evidences of Metamorphism 142 The Dehydration of the Ores 143 Prospects for the Future 146 Existence of Buried Deposits Probable 149 Conclusions 151 The Composition of the Specular Ores of the Sandstone Region 152 Phosphorus Contents 152 Sulphur Contents 153 Dent County Ores 153 Phelps county ores 155 Crawford county ores 155 Franklin county ores 156 CHAPTER VII. The Limonite Ores 158 The Ozark District 159 Structure of the Ozark Mountains 159 Development of the topography. 159 Locations favorable for limonite deposit 160 Ores associated with limestones 161 Ores imbedded . in clays 162 Cedar Bay mine 162 Mt. Nebo in Oregon county 164 The Lamons mine 165 Other banks in the vicinity of West Plains 170 The J. B. Old mine,. 171 The J. N. Hains bank 173 Other Localities in the Ozark district 174 b XV1U • CONTENTS. Page. The Osage District 174 General distribution and character of the ores 174 Deficient transportation facilities. . ..: 175 Mississippi River District 176 General distribution of ores 176 Ores near Puxico 176 Descriptions- by P. N. Moore 1 78 Hendrickson mine ; 178 Limonites in Outlying Districts 181 Near Fray's Mill, in Randolph county . . . 182 At Clinton, Henry county 183 At Brownington 183 In Dade county, G. A. Compton 184 General conclusions. ..., 185 The formation of limonites 185 The secondary growth of limonites 186 Growth of large deposits 187 Process of concentration 188 Topographic relations of deposits 189 The processes of deposition 191 Migration of iron deposits 192 The value of the Missouri limonites ' 192 Comparison with foreign limonites 193 Conclusions from this comparison 194 Conditions necessary for the successful manufacture of iron 198 The quantity of ore available 198 The quality of the ores , 199 The transportation facilities 199 The fuel supply 201 Timber for charcoal 202 Value of lands 204 Limestone available 205 The water supply 205 Market for iron 206 Cost of producing pig iron 207 Conclusions 209 PART II. CHAPTER VIII. Introduction to Part II 213 CHAPTER IX. The Specular Ores in Sandstone 218 Crawford county 218 Dent county 220 Franklin county 224 Iron county'. ; 224 Montgomery county „ 225 Phelps county 226 Reynolds county 230 CONTENTS. . xix Page. Texas county 230 Washington county 231 CHAPTEE X. The Limonites 232 Benton county 232 Bollinger county 233 Butler county 237 Camden county 240 Carter county 241 Cole county 243 Crawford county 243 Douglas county 244 Franklin county 245 Howell county 246 Iron county 246 Madison county 246 Morgan county 248 Oregon county 248 Ozark county 250 Reynolds county 254 Ripley county 254 St. Clair county 260 Shannon county ' , 261 Stoddard county 263 Texas county 266 Washington county 267 Wayne county 267 CHAPTER XI. The Red Hematites 279 Callaway county 279 Henry county 280 St. Clair county 281 Other counties 281 i APPENDIX A. The Ikon Deposits of Northeastern Arkansas 283 (Lawrence, Sharp, Fulton and Randolph Counties.) The location of the deposits 283 The geologic relations of the deposits 283 The nature of the ores 284 Analyses of iron ores from Northeastern Arkansas. . . 285 The mode of occurrence of the ores 286 The commercial value of the deposits 288 Lawrence county 289 General features 289 The 3. W. Coffman tract 289 Analysis of iron ore from the J. W. Coffman tract, Lawrence County 289 The S. P. Hollo way tract No. 1 290 Analysis of iron ore from the S. P. Holloway tract No. I, Law- rence County 290 XX CONTENTS. PAGE. The Cazort tract 290 Analysis of iron ore from the Cazort tract, Lawrence County.. 291 The Holloway and Collins tract No. 1 . ., 291 Analysis of iron ore from the Holloway and Collins tract No. 1, Lawrence County • ••• 291 The Holloway and Collins tract No. 2 292 Analysis of iron ore from the S. P. Holloway tract No. 2, Law- rence County. 292 The S. P. Holloway tract No. 2 292 Analysis of iron ore from the S. P. Holloway tract No. 2, Lawrence county 293 The Wasson tract No. 1 ■ 293 Analysis of iron ore from the Wasson tract No. 1, Lawrence county 293 The Moore tract 293 The W. C. Sloan tract 294 Analysis of iron ore from the W. C. Sloan tract, Lawrence county 294 Strawberry or Cathaytown 294 Analysis of iron ores from Strawberry or Cathaytown, Law- rence county 294 Sharp county 295 General features 295 The Collins tract 295 Analysis of iron ore from the Collins tract, Sharp county 295 The Wasson tract No. 2 . . , 296 Analysis of iron ores from the Wasson tract No. 2, Sharp county '. 296 The Big Creek and Reed's Creek divide 296 Analyses of iron ores from the Big Creek and Beed's Creek divide, Sharp county 297 Fulton county 297 General features , 297 The Deadrick tract 297 Analysis of iron ore from the Deadrick tract, Pulton county. . . 298 Randolph county 298 General features 298 Ravenden springs 298 Analysis of Iron Ore from Bavenden springs, Randolph county 299 Jackson . 300 The B. B. Odom tract 300 Analysis of Iron Ore from the B. B. Odom tract, Randolph county 300 Iron Bank , 300 Analysis of Iron Ore from Iron bank, Randolph county 301 CONTENTS. XXI Page. APPENDIX B. Historical and Statistical Sketch of the Iron Industry. Introduction. Early discovery in America 303 First discovery in Missouri 303 Iron mining 304 Specular ores in Porphyry 304 Ashebran's Furnace. 304 Iron Mountain 305 Shipments of iron ore 306 Pilot Knob 307 Productions of iron ore 307 Decline of production 308 Values of' ores .". 308 The red hematites 309 The specular ores of the sandstone region 309 The Harrison-Reeves bloomary i 309 The Eversol, Perry and Euggles furnace ' 310 The Meramec ore bank 310 The Scotia iron furnace 311 The Old Franklin or Moselle furnace 311 The Hamilton Iron Works 312 The«Benton Creek mines 312 The Steelville iron mines 312 The Simmons Mountain mine 312 The Ozark furnace 313 Midland Furnace 313 The Cherry Valley mines 313 Iron ore shipped and valued per ton 314 The Hawkins mines 314 The Coons mine 315 The Letcher mine 315 Limonite ores 315 The Limonite of Southeastern Missouri 315 In Madison county '. 316 In St. Francois county .• 316 In Wayne county 316 In Butler county 316 In Oregon county 317 In Howell county 317 ' Productions of iron ores to date 317 Table of total productions of individual mines 318 Crawford county. '. 318 Dent county 319 Franklin county 320 Howell county 320 Iron county ' 320 Madison county 321 XX11 CONTENTS. I Page. Phelps county 321 St. Francois county 322 Summary of productions by classes of ores 322 Table of total annual productions 323 Sources of information 323 Estimates of values ; 325 Production of iron ore for the year 1 892 , 326 Missouri's' rank 326 The Metallurgy of iron 326 Blast furnaces 326 Coke in operation 326 Coke not operated 327 Charcoal, in operation 327 Charcoal not operated ' 327 Boiling mills and steel works 328 In operation 328 Not in operation 328 Forges and bloomaries 329 Bessemer steel works 329 Plate and sheet mills 329 Cut nail mills ., 329 Wire nail works 329 Wire mills 329 Cast iron pipe works 330 Car axle works 330 Car wheel works 330 Car builders 330 Tin plate works , 330 The productions of iron 331 Pig iron 332 ' Plate and sheet iron and rolled iron 332 Geographical index .' 335 General index 341 List of Errata 366 List of Survey publications to date at end of volume. PLATES. Page. Plate I. Views of slaty structure of hanging wall at Pilot Knob.. . .opposite 39 II. View in railway cut at Cedar Gap opposite 105 III. Sections along Gasconade river, from Arlington to Gasconade City opposite 106 IV. Sections along Current river, from Riverside to Doniphan opposite. 106 V. View in Simmons Mountain mine, showing broken outcrop of sandstone cemented with iron opposite 119 VI. Fig. 1. View in Simmons Mountain mine, showing bf ecciated sandstone opposite 125 VI. Pig. 2. View in Simmons Mountain mine, showing sandstone with underlying cherty clay opposite 125 VII. View of cut at Simmons Mountain mine, showing disturbed sandstone on tram road opposite 126 VIII. View of Cherry Valley mine opposite 134 Geological map of State, showing .iron ore localities attached at end of volume. (xxiii) FIGURES. PAGE. Fig. 1. Apparent bedding in porphyry in railway cut, three miles north of Iron mountain 19 " 2. Sketch on Current river showing limestone deposited under an overhanging porphyry cliff 21 " 3. Diagram showing the relation of porphyry to limestone on Current river 21 " 4. Relation of porphyry to limestone on Current river 21 " 5. Sketch illustrating a vein of specular ore in the porphyry 22 " fi. Sketch of Iron mountain as it appeared in 1872 24 " 7. Section of the Big Vein at Iron mountain 25 " 8. Diagram illustrating the spheroidal weathering of porphyry 25 " 9. Illustrating brecciated foot wall at Iron mountain. (Reduced by about one-twentieth) 25 " 10. Showing veins of specular ore , 26 " 11. Showing veins of ore 26 " 12. Showing veins of ore.... 26 " 13. Section of iron vein and overlying rock at Little mountain 28 " 14. Section through Little and Big mountains, showing the relations of the porphyry to the younger rocks, and of the veins and conglom- erate ore to the porphyry 29 " 15. Section of first conglomerate bed at Big mountain 30 " 16. Section showing relation of conglomerate bed to' Cambrian lime- stone 30 " 17. Section showing the relation of the two conglomerate beds to each other 31 " 18. Sketch of Pilot Knob as it appeared when first opened 33 " 19. A cross section through Pilot Knob 35 " 20. A sketch map showing the outline and extent of the ore bed on Pilot Knob • 37 " 21. Sketch of Pilot Knob showing the position of the ore bed 36 " 22. A topographic 1 sketch of Pilot Knob , 36 . " 23. Section of conglomerate and ore body of Pilot Knob.... .. 38 " 24. Sketch showing in detail the structure of the conglomerate above the ore body 39 " 25. Profile of Archaean topography prior to erosion 58 " 26. Profile of Archaean topography after erosion 58' " 27. Ideal section of Iron mountain before erosion exposed the veins. . 59 " 28. The same showing the beginning of the formation of boulder ore. 59 " 29. The same after boulder ore is buried under Cambrian strata 59 " 30. Ideal section of topography in Archaean time 64 " 31. The same after deposition of iron ores and after erosion 64 " 32. The same showing growth of boulder ore beds 64 (xxv) XXVI FIGURES. PA.GE. Fig. 33. Ideal section of Pilot Knob covered by Cambrian limestone 64 " 34. Same as exhibited to-day 6 * ' ' 3g. Section at Morris iron bank in Lincoln county 73 " 36. Sketch of the Eaph Dunn bank, in Callaway county 76 " 27. Section in Raph Dunn iron bank 77 " 39. Section at Shaft Hill 77 " 39. Section across the divide, between Grand and Osage rivers 81 " 40. Section of the Magnesian series of rocks compiled by Shumard from observations made in Ste. Genevieve county 96 " 41. Sections along the Gasconade river, showing the thinning of the sandstone 107 " 42. Simmons mountain in 1872 123 " 43. Incline at Simmons mountain 127 '" 44. Cherry Valley bank in 1872 ■■■■■ • 130 " 45. Sketch section of the northern end of the Cherry Valley mine . . . .' 131 " 46. Section showing the relative positions of country rock and ore at the Cherry Valley mine 134 " 47. Sketch showing plan near Cook's station on the St. L. & S. F. Ry. 139 " 48. View of cut at Cedar Bay mine, showing ore body and overlying cherty-clay ■ 163 " 49. Sketch section at Mt. Nebo, showing distribution of fragments of ore over the surface 164 " 50. A general view of Lamons iron mine, looking southeastwards . . . 165, " 51. A topographic sketch of Lamons iron mine 166 " 52. Sketch from a photograph of the southwest wall of Lamons ore bank, showing the face of ore under the overlying soil J 67 " 53. View of gorge in which the Old iron bank is located 172 " 54. View of stalactitic ore body at the Old bank 173 " 55. A cross-section at the Old bank 173 " 56. A stalactite geode of limonite 174 " 57. View showing manner of occurrence of large surface boulders of cherty ore near Puxico 177 " 58. Section through Hendrickson mine 179 " 59. Section at Fray's mill 182 " 60. (Fig. 1 of-Arkansas Report.) Section across Iron mountain on the Collins tract, Sharp county 207 " 61. Outline map of the State of Missouri, showing counties containing iron ores and distribution of productions to date 323 " 62. Diagram illustrating growth of production of iron ore in Missouri," from 1815 to 1892 325 PART I THE IRON ORES OF MISSOURI. A general discussion and description of the various ores and of the geology of the regions in which they occur. THE IRON ORES OF MISSOURI. BY FRANK L. NASON. CHAPTER I. INTRODUCTION. THE ORES OF IRON. THE FORMS IN WHICH IRON OCCURS— THE ORES OP IRON— THE RELATIVE VALBES OF IRON ORES. THE FORMS IN WHICH IRON OCCURS. Iron is one of the most widely distributed metals. It rarely occurs native or in the metallic state, but is generally combined Rarity of occur - .... _ . . rence of native with oxygen or some other non-metallic element. In the native iron, state it is found in meteorites in large masses, and in grains in eruptive rocks. The nativemetal is so rare, however, that there is no need of further mention of it in a work treating of the sources of iron for economic uses. Iron combines with sulphur as a sulphide and is then known combination nf 11 Iron with other as iron pyrites (often mistaken for gold on account of its yellow elements color), and, in the form of a sulphate, as copperas. It also com- bines with arsenic, phosphorus, silica, etc. In the forms of silicates and hydrous oxides (oxide of iron combined with water) and anhydrous oxides it forms the coloring matter of rocks and soil. THE ORES OF IRON. With the exception of metallic iron all of the compounds above noted are, properly speaking, ores of iron, but technic- ally they are not. In practice an ore of iron is a chemical combination of the metal or element iron with (a) oxygen IRON ORES OF MISSOURI. Compounds of iron not ores. what constitutes alone, (b) with oxygen and water, (c) with carbonic acid. A an ore of iron. ... . , rich ore is one which runs from nfty-five per cent, up ; a lean ore is one in which other substances are mechanically mixed, thus reducing the percentage of iron. There is no fixed limit to lean ores except that of profitable working. This limit varies with the market demand for iron. The sulphide (iron pyrites) or the sulphate (copperas), green vitriol, are worthless as sources of iron, since the sulphur which they contain is very injurious to the metal, and it is quite im- possible to get rid of it. Iron combined with phosphorus is also worthless for similar reasons, viz., the phosphorus injures the metal and is very difficult of removal. In addition to these facts other reasons exist why these compounds should be ex- cluded from the list of iron ores. In the first place, tbey rarely, with the exception of iron pyrites and arsenical iron pyrites, exist in large deposits; and, in the second place, the percentage of iron is so low as to preclude the possibility of working them, even were they abundant and were the elements with which the iron is combined harmless to the metal. Practically, therefore, the commercial source of iron is limited to three classes of iron ores, which are as follows: anhydrous oxides, hydrous oxides and carbonates. These ores may be presented in the following tabular form : — TABLE I. Anhydrous oxides. Hydrous oxides. Magnetite. Hematite. r T . . | Lamomtes or Brown hematite. Magnetic iron ore. < Magnetic titanic, iron ore. i Franklinite. J Specular. < Red hematite. I Red ochers. f Stalactitic or " pipe ores. J Compact earthy ores, j Porous or Bog ores. I Colored ochers, not red. THE ORES OF IRON. 3 | Siderite | Ordinary brown carbonate. Carbonates. - l Oxygen 30. „ . f Limonite or ] f Metallic iron 59.92 Hydrous . I I 2 Fe 2 O s + oxides. ] „ ° | 3H 2 0= I Hematite, j f Siderite or ] f Metallic iron 48.30 « Carbonate= | Spathic ore =*e CO s = Oxygen 13.80 " [ j [ Carbon Dioxide 37.90 " In other words a ton of 2,000 pounds will yield of metallic iron — Magnetite 1,448 lbs. Theoretical yield tt !-i i jnn . of metallic iron Hematite • • • • 1,400 «« from the princi- Limonite 1,198.4 " Carbonate 966 " These are theoretical yields from theoretically pure ores. But it must be borne in mind that no furnace yields the full per- centage of iron that is in the ores, and that practically there are no pure iron ores of any kind. The Magnetites. In the light of this last statement, let us examine Table I. In this table under " Magnetite," we find "Magnetic iron ore," "Magnetic titanic iron ore," and " Franklinite." This means simply that magnetite is frequently rendered impure by the admixture of titanic acid; and, in the case of Franklinite, a part of the iron is replaced by zinc and manganese. These ores usually occur interbedded with crystal- pal ores. IKON ORES OF MISSOURI. Impurities of magnetic iron ores. Impurities of hematites. line rocks, such as gneiss or mica schists ; and, mixed with the ore body, oftentimes, there is much of the adjacent rock together with other minerals, such as quartz, feldspar, horn- blende, etc. It is very evident, then, that in mining ores of this nature a ton of so-called ore will contain rock and minerals of a foreign na- ture and, in proportion as this foreign admixture increases, the percentage of iron is diminished. In the case of magnetite, therefore, the percentage of iron is commonly diminished in two ways. First, by a replacement of a part of the iron by some other metal such as zinc or manganese, or by some non-metallic element such as phosphorus, sulphur or titanic acid ; and sec- ondly, by admixture with the ore body of minerals like- quartz, feldspar, hornblende, apatite, etc. Magnetites are uniformly black and are attracted by a magnet. The Hematites. Hematite ore is less apt than magnetite to ■have, as mechanical impurities, minerals like feldspar, horn- blende,, mica, etc. It is quite as apt, though, to have phosphorus and sulphur, and it occasionally has titanic acid. This is true of the specular hematite. The red hematites occurring, as they generally do, in rocks less crystalline than either the magnetites or the specular ores, are also less apt to have, as mechanical- impurities, crystallized minerals, excepting carbonate of lime. Sand and clay are much more common, and the ore has more of an earthy appearance. Phosphorus and sulphur also occur. Where the red hematite occurs in loose friable masses, or if moistened feels greasy and free from grit, it is known as red ocher or red paint. Hematite is always to be distinguished by its color, even when in the mass it appears blue or black, its powder is cherry red. The Limonites. The limOnites present by far the widest range in form, mode of occurrence and color, of all the iron ores. Both hematite and magnetite have distinct crystalline forms. Magnetite is always crystalline, and the same can be said of the blue or black hematite, while the earthy or more crystalline varieties of hematite are always red. Limonite has no crystalline forms of its own and hardly a distinctive color. What is known as "pipe ore " is limonite in the form of long, THE ORES OF IROK . 5 usually slender tubes. These tubes generally have a small hole imparities m the . . " various forms of reaching from end to end, but this is usually so choked with limoniteores., ocher or other substance as to be hardly discernible. These tubes or " pipes " occur singly or in great bunches or masses so compactly connected together as to present the appearance of a solid mass rather than of a bundle of distinct pipes. The pipe ores are without exception formed as pendants from the roofs of -caves, or are built up from the bottom exactly in the same man- ner as stalactites of lime are formed in limestone caves. Pipe ores are usually the purest of, all the limonite ores. The com- pact earthy limonites have the appearance of a solid rock, and are usually very pure, butare sometimes mixed withfinesand and clay. They occur in large beds or layers mixed with loose ocherous ores and clays. The porous or bog ores are the most impure of all the limonite ores. They usually have the appearance of pumice stone, except in color. That is they are porous or cel- lular and they carry a large percentage of fine sand aud clay, thus reducing largely the percentage of iron. The above constitute the principal varieties of the forms of limonite. This class of iron ores carries the lowest percentage of iron, with one exception, of any worked ore. As impurities they rarely have any crystallized minerals such as quartz, feld- spar, etc. ; but they usually carry a high per cent, of silica, in the form of chert or flint, fine or coarse sand, sometimes both, aud alumina in the form of clay. The limonites usually carry rather large amounts of phosphorus, and sulphur is generally present, but rarely in sufficient quantities to prevent the use of the ore. To these must be added from 11 to 14 per cent, of water, which is an essential constituent of the mineral. Owing to the low percentage of iron in limonites, even when •comparatively pure, they are not so sought for as are the magnetites and red hematites or specular ores. They are rarely value of limonites. shipped to great distances, and, in the localities where the richer ores are found, they would not be used at all were it not for the fact that their open or porous structure causes them to be very easily reduced in a furnace. The Carbonates. The carbonates of iron carry the lowest per «ent. of iron of any worked ore, even when pure. They are of 6 IRON ORES OF MISSOURI. comparatively rare occurence in workable deposits in this country - Bulletin No. 113 of the Eleventh Census of the U. S. shows that carbonate iron the carbonates constituted only 2.98 per cent, of the 14,518,041 ores; their J A thefrvwteties. tons of iron ore mined in the year 1889. The principal vane- ties of siderite, the names of which are of no great significance, are "White horse" for a nearly pure carbonate of iron; " Clay iron-stone " for a very impure carbonate, the impurity being principally clay; and " Black band" for a carbonate of iron carrying much carbonaceous or coaly matter. This coaly matter is often so abundant that, by the addition of but a slight amount of fuel, the ores are self-roasting. THE RELATIVE VALUES OP IRON ORES. From the foregoing pages it will be gathered that the value of iron ores, according to the amount of metallic iron which they carry, is as follows : — T ttive°vai C a°e™ P of First. Magnetite, .ron ores. Second. Hematite (red, blue or black) ; Third. Limonite, or brown hematite ; • Fourth. Siderite, or spathic iron. This is the order of succession of pure ores ; yet impurities are so often present that, in a given locality, an iron ore of a normally inferior rank often contains more iron than one which ranks higher How impurities in the above list. Thus, in Alabama, red hematite ores are used, Taines o/ores" 6 which, instead of the theoretical 70 per cent, of iron, yield only 30.5 per cent, to 51.6 per cent, of metallic iron. In New Jersey 51 to 55 per cent, magnetic iron ores are used when pure magnetite is capable of yielding 72.4 per cent, of metallic iron. In still other places iron ores which carry from 55 per cent, of metallic iron and upwards are not used on account of the high per cent, of phos- phorus, sulphur or titanic acid present. The value of an iron ore does not, therefore, depend upon any one thing, but upon a combination of circumstances which will Factors determin- be pointed out in the following paragraphs. The principal factors in determining values are — 1. The amount of metallic iron; THE OEES OF IRON. 7 2. The freedom from deleterious substances, principally phos- phorus, sulphur and titanic acid ; 3. The proximity to markets or smelting points. Examining the above points a little more in detail we find (a) that there is no fixed price for iron ores of any class, but that the price varies from year to year or oftener. 1. The Influence of the Percentage of Iron. Other things being equal, the price of iron ore is determined by the amount of metallic iron which it carries, reckoned by units ; i. e., a ton In ^ e t °|| ^ mot of 2,240 lbs. is divided into 100 parts. If the ore is hematite alli ° ir °°- and absolutely pure, 70 of these parts or units are metallic iron. If, now, iron is selling at six cents per unit, the ton of 2,240 lbs. is worth $4.20. (b) If an iron ore, through impurities, drops much below 60 per cent., it cannot be shipped to any great dis- tance, as is shown by the figures of the Eleventh Census. 2. Influence of Deleterious Accessories, (a) If phosphorus is present in amounts from 2 per cent, up, the iron ore is unfit, for any purpose whatsoever, unless for mixture with an ore of a much lower percentage of phosphorus. Iron ores with phos- phorus in the proportion of -^^ or less {i. e., 1 part of phos- In t ^f n u o s e e o 1 |_ dele - phorus to 1000 parts of iron), bring a little higher price, since ments - such ores can be used for special purposes, such as the manu- facture of Bessemer steel, (b) Sulphur present in quantities greater than 1 per cent, makes roasting necessary, thus adding to the cost of the ore. If the percentage of sulphur is not too great, however, and the percentage of iron is high, sulphur is not an insuperable objection, (c) Titanic acid present in quantities from 3 per cent, up renders an ore unfit for use on account of the extreme difficulty of fusion. 3. The Influence of Proximity to Market. Proximity to con- suming points is another essential factor in determining the value of an iron ore. Proximity is a variable not a fixed term. Avaiue of ores af- •' fectedbyaprox- limonite carrying 55 per cent, of metallic iron will not bear imity to market. transportation by rail four hundred miles, while a Bessemer hematite or a magnetite carrying from 60to 65 per cent., or more, will stand transportation from one to three thousand miles, espe- cially if the greater part of the distance is by water. From what has been said, it is plain that not every iron-bear- 8 IRON ORES OF MISSOURI. ing mineral can be classed properly as an iron ore, although strictly speaking it may be so, and that impurities, on the one hand, and distance from manufacturing centers on the other may further prevent the mining of iron ores, even when they are apparently abundant. The Influence of Impurities on Product. But with even a consuming point near at hand, and with ore of good quality, the nature of the impurities associated with an ore has much to do with the use which is made of it. Dividing the common impuri- ties into the classes, inert and deleterious, we have as: Influence of lm- pmilied on the smelting of the ores. Inert, Deleterious, i Silica; Alumina and other refractory minerals. Phosphorus ; Titanic acid ; Sulphur ; i Arsenic. These impurities in iron ores determine the uses which can be made of them. At the present day, comparatively little wrought iron is made directly from the ore. Whatever kind of iron is ultimately intended, the first product is pig iron from the blast furnace. From pig iron as turned out from the blast furnace is made steel, wrought or merchant or forge iron, and cast, or foundry iron. Pig iron, then, as it comes from a furnace, may be rightly classed as : Immediate pro- duct from the ores. I Bessemer pig, For stuel, < Basic or I open hearth pig. For iron, Forge iron, Foundry iron. Steel is widely used at the present day, and is rapidly taking the place of iron in many structures. For rails, boilers and THE ORES OF IRON. V plates, hulls of ships, bridges, girders and trusses and for heavy castings, but where great tenacity and strength and comparative lightness is required, steel is almost exclusively employed. By far the greatest amount of steel that is used to-day is produced by a process patented by Mr. Henry Bessemer of England. In order to make what is known as Bessemer pig, iron ore low in phosphorus must be used. The presence of silica even in a large proportion is not fatally objectionable since in the process this is almost wholly removed, while the proportion of phos- phorus is slightly increased owing to the fact that none of the phosphorus is eliminated in the process, while the molten iron 0reB auitab i e for loses comparatively large amounts of silica, carbon and manganese f BM°emer pig and some iron. An iron ore, therefore, carrying much phos- iron ' phorus, is worthless for Bessemer steel. The modification of the Bessemer process, known as the Basic Bessemer process, is one in which the lining of the crucible is limestone, or " basic " in- stead of "siliceous" or acid. By this means the phosphorus is completely eliminated, or at least reduced to a point where it no longer acts injuriously on the steel. The process is slower and more expensive than the original Bessemer process, and, as iron ore c;in be obtained in this country almost wholly free from phosphorus, it is but little used here. Another method of steel making from pig iron is known as the Open hearth basic process. In this process the lining of the furnace is made from limestone, as in the basic Bessemer „ .. ' How the open process, and the phosphorus combines with the limestone and cess^Hrs'from passes off in the form of slag. This process, though, to be process 861 "" economical, requires an iron low in silicon, and thus the range of available ore is as restricted as in the case of the Bessemer process. Although the absence of phosphorus from the pig iron is not absolutely essential in this process of steel making, it is desirable to have it as low as is possible, and, in the few open hearth basic furnaces in this country, a low silicon Bessemer pig is frequently employed. There are other processes for making steel in which almost any workable ore can be used, but these processes are very slow, and it would be impossible to use them in practice. It follows, then, that, for the present at least, an iron ore 10 IRON ORES OF MISSOURI. must be low in phosphorus if it is to be made into steel. Steel though, however valuable it may be, is not the only desirable iron for structures. Wrought iron is generally cheaper than steel, cast iron is decidedly so, and there are many cases where Action of phos- these are even more suitable than steel. Phosphorus, which, as phorus on Iron ' and steel. we h ave seen, renders iron ores quite unfit for steel, is by no means an undesirable element in certain varieties of castings. In all cases where light castings for ornamental work or light* forms with little strength are needed, phosphorus is an almost indispensable ingredient. Its presence in cast iron renders the latter easily fusible, keeps it longer in the melted state, thus enabling it to fill delicate moulds in which a more sluggish iron would chill. In pig iron for such purposes 2.5 per cent, of phosphorus is by no means uncommon. Sulphur which is in- jurious in Bessemer pig iron is beneficial in foundry pig iron, in small quantities, increasing its strength very perceptibly. Sili- con, derived from silica in the ore, is always present in pig iron. It is occasionally 20 per cent, of the iron. In this case it is injurious, very decidedly tending to weaken any castings made from it, yet in moderate amounts of from one to five per cent, or more it has little apparent effect. Among the metals which are found in iron ores and in the pig iron made from them, some are injurious and some are some metals ai- beneficial. Manganese is the best known and is of the widest / loyed with iron . ., . . _ . , are beneficial, importance. An alloy oi iron and manganese is known as others injurious. . ' . ° opiegleiron or ierro- manganese, according to the proportion of manganese present. This alloy, however, is principally valua- ble in the manufacture of Bessemer steel, and thus, if much phosphorus is present, it also becomes worthless. Wrought iron or bar iron is sometimes made directly from the ores of iron in Catalan and other forges, but the greater part is composition of made from pig iron, by a process known as puddling. Wrought iron is the lowest in carbon, cast iron the highest, while steel stands between. Wrought iron has from .02 to .03 per cent, of carbon, while steel has from 1 per cent, to 1.8 per cent. Steel then is only a highly carbonized wrought iron. They have many points in common. Phosphorus and sulphur are alike injurious to them, as are also silicon, arsenic and antimony. Sulphur and THE ORES OF IRON, 11 copper i render both wrought iron and steel brittle and unf orga- ble while hot, and phosphorus makes it weak and brittle while cold. In other words, sulphur makes wrought iron and steel hot short or red short and phosphorus makes them cold short. Summing the effects of these impurities we find : Substances injurious to steel and wrought iron : Substances beneficial to cast iron, when in small quantities: f Phosphorus ; I Sulphur ; j Silicon ; Arsenic ; Copper; Antimony, f Phosphorus ; J Sulphur ; Silicon ; Vanadium. tin, etc. From this it will be readily seen that while a given iron ore Adaptability of may not make steel rails it is well fitted to make car wheels, various uaes. Or, to put it more generally, an iron ore quite unfitted to make steel or wrought iron may be eminently adapted to making cast- ings for a wide variety of uses. And so, though a given ore may be of restricted use in some directions, its value may not be correspondingly impaired. 12 IRON ORES OF MISSOURI. in Missouri. CHAPTER II. THE IRON ORES OF MISSOURI. THE CLASSES OP ORES— THE SISTRIBUTION OF THE OKKS. The Glasses of Ores. The iron ores of Missouri occupy an intermediate position in the table of values given on page 3 of this report. The rich magnetites and the lean siderites. are Twociassesoi practically unknown in the State. Even among the porphyries and granites, where magnetite is usually found in disseminated grains, there is hardly a trace. Siderite, which is usually char- acteristic of Coal Measures, if not of older formations, exists in name only. Several thin seams, an inch or so in thickness, have been found in the Coal Measures, but this far they have been without commercial significance. "Black band," "white horse," and "clay iron-stone " are practically unknown. There are left then, two ores, hematite and limonite. These two ores have given the State its rank as an iron ore producer. The hematites are by no means confined to Iron mountain and Pilot Knob, or in other words to the porphyry regions, but'they are found in the Cambrian or Ozark series 1 of limestones and sandstones and in the Lower Carboniferous formations. The limonites, however, are confined almost exclusively to the Ozark group of Cambrian age. The following table shows the varieties of these ores which occur in the State. 1 The term " Ozark Series," has been proposed by Prof. G. C. Broadhead as a substitute for the term " Magnesian limestones," previously used by him and others in the early reports of the Survey. See Amer. Geologist, Vol. VIII, No. 1, July, 1891. It is here adopted as the most appropriate name for that series of rocks. A. W. THE IRON ORES OF MISSOURI. 13 Hematite. Limonite. < Coarse specular hematite or porphyry ore; Fine specular ore of the Ozark series of rocks ; Vermilion ochers, or paint ores of the Ozark series of rocks ; Earthy red hematite of the Lower Carboniferous Te t S e va two 'ciasL* formation; recognized. ■ Kidney hematite of the Lower Carboniferous formation. Pipe iron ore; Compact limonite ; Limonite pseudomorph after pyrite ; Yellow and brown ocher paint ores ; Bos: iron ore. The Distribution of the Ores. In regard to the distribution of the iron ores, a brief glance at the map accompanying this report will show that the various classes are confined by rather strict boundary lines. In addition, these boundary lines are ' somewhat concentric, and lie in the following manner. First, the great area occupied by the specular iron ores in the sandstone specular ores o£ . , ,i i n i , ti tDe sandstones. region is situated at nearly the crest or broad plateau-like apex of the Ozark mountains. Proceeding in any direction from this point these specular ores grow less distinct, as one passes from the sandstones to the limestones, and gradually we come to the great belt of limonites. The limonites are on and in the magnesian limestones, princi- pally, and inclose this central area of specular iron on three sides quite effectually. 1 Wright and Greene counties break this ring. The next band is that of the red hematites of the Lower Car- boniferous formations. These ores are bedded and they are the only bedded deposits of iron yet found in Missouri except the Red hematltes of beds of specular ore on Pilot Knob. They appear in promising Coniferous. ° ar outcrops in Callaway county. Following this junction line be- tween the Cambrian series and the Carboniferous, through Ben- i These limestones extend under the sandstones,- but the sandstones being destroyed cause the appearance of a surrounding belt of limestone. 14 IRON ORES OF MISSOURI. ton, Henry and Hickory counties, we find these bedded, red hematites quite persistent, but not in the same promising manner that we find them in Callaway county. Another band, beginning also on the north and reaching to the west and to the south is that of the thin seams of carbonate iron found in the Coal Measures. As was mentioned in the beginning of this chapter, these ores are not considered abun- dant and hardly deserve to rank as forming a belt. Yet these lie in the Coal Measures and are characteristic deposits of that formation. So long, therefore, as it is not positively knowu that there are no workable deposits of this ore, it is hardly safe to predict that productive seams or beds will never be found. coal Measure de- The Coal Measures of Missouri occupy a great territory, and i P ron t o« s . Bpi ' tllic at present it is comparatively little explored. But certainly, no great deposits have as yet been discovered. There is another class of iron deposits occurring in the Coal Measures but they will probably prove of no more value than the carbonates prom- ise to be. Eeference is made to the bog iron ores which are no doubt formed by chalybeate springs, which may now be active or may have long since ceased flowing. Such deposits were found near Clinton and Brownington, in Henry county, and also at Fray's mill, in Randolph county. Finally, there is one area of iron ores that has not been men- tioned. This is the Archean area and it is unique for many reasons. The specular iron ores in porphyry are recognized as belonging to this age. Though they are in the midst of the A ap b ecnrarores 01 limonite belt which surrounds the specular iron ores in the sand- stone region, they are wholly distinct from these ores. These porphyry ores are unique, not in age alone, but also in that they evidently occur as vein deposits. In fact, prospecting with a diamond drill at Iron Mountain has shown that these veins run in the hard porphyry to depths of over one hundred feet. They are frequently no more than an inch in width ; yet near the sur- face these veins, as mined, have been over one hundred feet in width . With a certain degree of propriety, then, we can recognize the following classes of iron ore as occurring in Missouri, and each one is assignable to its special geological horizon, save that THE IRON ORES OF MISSOURI. 15 of the'limonites, which are never constant but represent a con- tinual state of motion. These classes, then, beginning with the oldest, are as follows : — 1. Coarse specular iron ore, Occurs in veins and conglomerate beds in and on the porphyry and in true beds at Pilot Knob. 2. Fine specular iron ore, Occurs in large pockets lying under the sandstones and on the limestones of the lower Cambrian. 3. LlMONITE IRON ORE, T ?rtn™ el^ccn?! Occurs upon or in depressions of the Ozark limestones. anifthei^'llo"" (a) derived from the specular ores; ogoa (b) derived from the rotting of the rocks above; (c) derived from the Lower Carboniferous red hematites. 4. Red hematite, Occurs bedded in the Lower Carboniferous rocks. 5. Carbonate ore, Occurs as siderite, bedded in the Coal Measure. 6. Boo iron ores, Derived from chalybeate springs. In the following pages we shall take up these ores under the headings given above. In Part I will be included, in separate chapters, a general discussion of the Specular Iron Ores of the Porphyry Region, of the Red Hematites, of the Specular Ores of the Sandstone Region and of the Limonites; the two last being preceded by a chapter on the General Geology of the Ozark Uplift, in which regions these two classes of ore occur. Part II is a systematic description of the more important and most promising occurrences of Specular Ores in Sandstone, of • Limonites and of Red Hematites, with especial emphasis on the Limonites; descriptions of the deposits of Specular Ores in Por- phyry are contained in the chapter of Part I devoted to those ores, and are, hence, not repeated in Part II. 2 16 IRON ORES OF MISSOURI. CHAPTEE III. THE SPECULAR IRON ORES OF THE PORPHYRY REGION. INTRODUCTORY REMARKS— THE IRON ORBS, THEIR MODES OP OCCURRENCE — THE IRON MOUNTAIN ORE DEPOSIT — PILOT KNOB — CEDAR HILL — SHEPHERD MOUNTAIN — CLARK'S MOUNTAIN — THE COMPOSITION OP THE SPECULAR ORES IN PORPHYRY — THE ORIGIN OP THE IRON ORES — SUMMARY. INTRODUCTORY REMARKS. Distribution of the Crystalline Rocks. Id the southeastern part of Missouri, in St. Francois, Washington, Iron, Reynolds, Madison, Wayne and Shannon counties are extensive areas of crystalline rocks. Interesting as these rocks are, both from their isolated position with regard to other crystalline rocks and T flned CS to ar louth- from their structural peculiarities, a wider interest has been sou'!™ Mls aroused in them on account of the deposits of iron, worked for so many years, at Iron mountain and Pilot Knob. The appar- ent extent of these ore bodies when first discovered, as well as the remarkable purity of the ore, have made them famous. Unfortunately, unlike most other iron-producing crystalline rocks, the iron deposits of the porphyry are not co-extensive with the porphyry itself. In fact, the Iron mountain and Pilot Knob localities, the first to attract attention, have been, with a few minor exceptions, the only deposits of iron ore worked. Shepherd and Cedar mountains, near Pilot Knob, have each con- . tributcd to the total iron output of these localities, but the amount is utterly insignificant as compared with the first men- tioned deposits. The Topography. The topography of the porphyry region is picturesque in the extreme. Prof. Pumpelly speaks of the ^fotnrefquel 1718 Archaean hills as " an archipelago of islands in the Lower Silur- ian strata which surround them as a whole, and separate them THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 17 from each other." The figure is an extremely happy one for the rocks of the younger formation cover all the inequalities of the older, and their very erosion leaves the valleys as they now exist at an almost uniform level. Unlike the ridges and peaks of the so-called Ozark mountains the hills of porphyry and granite, have how, at least, no com- mon level. They vary in height above the level of the sur- rounding Cambrian 1 rocks from one hundred feet, or even less, F i™ e oambi5«w B lo five or six hundred feet. They rarely reach seventeen hun- stui rise above -dred feet above the level of the sea. Bearing in mind that the age. highest point of the Ozark mountains is about seventeen hundred feet above sea level, it can very easily be imagined that the 'Cambrian formation once covered even the highest of these hills. But as limestone and sandstone yield more readily to the attacks of denuding agents than do the refractory porphy- ries and granites, the area is gradually resuming its ancient topography, and we can easily picture to ourselves in a high degree of perfection, the general aspect of the country before the Cambrian seas covered it with the mantle of sedimentary rocks. Whether we regard these porphyries and granites to be of sedimentary or igneous origin, they are now highly crystalline, and thus the contour of the hills, as the result of weathering, is ^lstinqtw/form much more irregular than that of the hills of the stratified lime- pared with those stones and sandstones. Pilot Knob, protected, as it is, by its mattons. compact cap of specular ore has a conical shape almost as regu- lar as a volcanic cone, while others are more like lonsf ridges and have their summits scolloped into rounding peaks of unequal heights. Although many of the hills were once undoubtedly precipitous, very few are st> at present. The tendency of the rocks is to break or spall into irregular blocks. These blocks 1 The recent investigations of the^Geological Survey are leading to the conclusion that the magnesian limestone and associated sandstone strata immediately about the Archsean hills of the Southeast are all of Cambrian age, rather than that part are Lower Silurian as has heretofore been held. Moreover, it is probable that the same applies to the rocks of the *hole central portion of the Ozark uplift. Hence, in this report, these rocks are referred to as Cambrian and are so represented on the map. The evidence in support of this will be adduced in a forthcoming later publication. A. W. and texture. 18 IRON ORES OF MISSOURI. yield but slowly to the weather and thus retain their irregular shapes for a long time and occasionally completely cover the side to near the summit. This of course precludes the formation of soil, and, so long as it lasts, the hills on one side are bare or,, at best, are covered with a scant vegetation. This condition isy however, of comparatively rare occurrence. In general the easy slope of the hill retains either the soil resulting from the weath- eriug of the crystalline rocks, or even the mantle of clayey soil left by the removal of the soluble constituents of the stratified rocks which once covered the former. Here the hills are covered with vegetation as flourishing as that of the limestone hills- of the Ozarks, leaving only the general contour to distinguish them. Lithology. To the ordinary observer the porphyries are of a generally similar character. The differences most readily The porphyry noticed are, first, color ; second, texture. The color varies from a rocksvarysome- ■,-,,, m, . i i ,, ,. what incoior red to a dull brown. Ihere seems to be no law governing the dis- tribution of the red and brown varieties, both occurring in close connection in the same outcrop. The red porphyry, though, seems to have generally more of a bedded structure, while the more common brown makes up the greater bulk of the outcrops. In Shannon county and also in parts of Reynolds and St. Fran- cois the surface color is gray, while a fresh or recently broken surface is inclined to be brown. In Shannon county, along Current river, the color is exclusively brown. Proximity to iron veins appears to modify both color and bedding, and the agencies which have produced the deposits of iron are probably respon- sible for much of this modification. The texture of the porphyry is more widely variable. Nearly every outcrop has places where the rock is almost aphanitic and in .other's the crystals of white feldspar are sometimes one fourth of an inch square. There are outcrops where the crystals are an inch square. The range in texture is, however, but little wider than is often found in metamorphosed gneisses. Bedded Structure. Though the porphyries generally, on weathered surfaces, have more the appearance of traps or green stones, the rock face being checked by numerous lines of fracture producing sharp angular spalls which cover the ground near the THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 19 foot of a cliff, there are other places where this structure appears to be almost wholly wanting. Elsewhere there are strong indications of ^m^l^^ SBBStS^ ^MjiSK. bedding. About three ^ ' ** ' * <***** ■ *&> taY«deej*jUy ., , T FIG. 1. Apparent bedding in porphyry in Ry. ont, three a nce miles above IrOll niOUll- miles north of Iron Mountain. tain on the Iron Moun- tain Railway there is an outcrop of porphyry which has a decidedly bedded appearance. The beds are four feet thick, some are less, and dip to the S. E. Figure 1 shows this apparent bedding. At Iron mountain the porphyry forming the foot wall at both the west and the east end of the mine has a decidedly bedded appearance. Here, however, the beds are so irregular that the appearance can as well be assigned to weathering from a massive rock as to deposition by water. At Pilot Knob, however, bed- ding structure occurs in such a way as to leave little room for doubt in the writer's mind as to the sedimentary origin of the porphyry in which the ore beds occur. The ore here rests on a porphyry conglomerate which passes gradually into a fer- ruginous slate, this into heavy beds of fine grained slaty ore. This is again capped by slaty ore much less pure, and this > finally by a conglomerate which reaches to the summit of the Knob. Associated Minerals. In spite of the fact that iron is found in workable deposits in only two localities, hematite is widely disseminated through both the granites and porphyries. In the granites it occurs in fine crystalline scales, which in many in- stances have been mistaken for lead or even silver by' people who have found it. Just below Van Buren in Carter county and on the Current river is an outcrop of granite where this oc- currence is well shown and several assays for silver have been made, but, of course, without favorable results. Veins of specu- lar ore are rarely or never found in this rock. Intheporphyry, Bx tinKiron however, not only does the hematite occur in disseminated the porphyry ^ grains, but frequently in veins as well. These veins are usually jj]££ ot aDnn " small and irregular and are often interrupted by quartz. At Shepherd mountain, Cedar hill and Iron mountain these veins are 20 IRON ORES OF MISSOURI. Some manganese occurs. Oambilan rocks seen to be yoongcrtban granites and porphyries. exposed at \he surface of large proportions. At these places also the smaller veins occur sometimes at depths of two hundred feet or more as is shown by the diamond drill. Manganese also occurs in the porphyry rocks. In Shannon county, T. 23 N., R. 2 W., Sec. 31, veins of manganese, from three inches in thickness down to minute seams, occur of remarkable purity. Prof. Pumpelly, in his report, 1 mentions several bedded de- posits of manganese occunng in porphyry. Several other local- ities have been discovered, but none of them have realized the- hopes of the discoverers. The porphyries as well as the granites are generally remarkably free from other minerals. Apatite is- occasionally found at Iron mountain in well defined crystals in connection with the iron ore. Quantities of hornblende, appar- ently of secondary origin, as well as crystals of quartz, garnet and also copper in the form of blue and green carbonates is- sparingly found. In the porphyry region of Jack's Fork in Shannon county copper has been reported to occur quite exten- sively. Crystalline galena is also occasionally found. In the granite, veins filled with quartz occur frequently and occasion- ally crystals of great beauty are found. Relations of Porphyries to Cambrian Rocks. The relation of the porphyries to the Cambrian rocks is very simple. Though there are porphyry knobs and ridges that rise high above the Cambrian strata, yet the floor upon which the latter rest is of porphyry or granite over a large area. Mining operations at Iron mountain show sandstone and limestone resting on the flanks of the porphyry mountain. Diamond drill holes at Pilot Knob, in the valleys between Pilot Knob and Shepherd mount- ain, Pilot Knob and Buzzard mountain show that, in these places, the overlying horizontal rocks from one to four hundred feet thick, rest upon a porphyry floor. Along Current river between the mouth of Jack's Fork and Van Bureii there are numerous outcrops of porphyry, many of which show the limestone lying on the uneven porphyry sur- In some places the limestone reaches under a porphyry face. ledge, being, of course, deposited under a former overhang- 1 " Geological Survey of Missouri, 1?72," Part I, pp. 90-25. THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 21 ing porphyry cliff. Along the river are often low porphyry hills com- pletely encircled on the land side by limestone. Almost without exception when the limestone lies near the por- phyry, there is a water course separating the two. The accompanying figures Flo 2 . :;i fti , h „ n 1Jnrrnne tiym show the relations of the two rocks, «5SS% "angtng 1 $$£ at different points along the river below ry cliff " Relations of por- phyry and lime - stone on Car- rent river. g^rg^t?w.v,^7;'A^ Riven tcvet. Fig. 3. Diagram showing the relation of porphyry to limestone on Current river. Jack's Fork. The granite hill below Van Buren is thus encircled by limestone hills with river levo-. Sandstone bed* the FlG- *• Relation of porphyry to limestone on Current ' ' river. hills being four hundred and thirty feet high. At Doe Kun and Mine La Motte work in the lead mines shows that granite underlies the lead- bearing rocks. From the facts stated above, the conclusion is inevitable that the limestone series is younger than the porphyries and granites. THE IRON ORES, THEIR MODES OF OCCURRENCE. As has already been stated hematite, and, to a slight extent, magnetite occur in crystalline scales and grains throughout the porphyries and granites. In the granites especially the hematite is a very prominent constituent, the scales being readily visible to the unaided eye. Thus far, however, these rocks do not differ in this respect from many rocks both massive and stratified. Even in other rocks, massive and bedded, it is no uncommon thing to Large veins of n 1 . . -r . *Z-i ir0n are f° unl * nnd occasional veins of hematite. At Iron mountain, Pilot only in the por- / phyries. Knob, Shepherd mountain and Cedar hill these veins are remark- ably developed. At Iron mountain, in what is known as Big 22 IRON ORES OF MISSOURI. mountain, the veins of hematite are from forty to sixty feet in thickness. As the more solid porphyry is reached these veins diminish in size down to one inch and less in thickness. In places these form a perfect net work in the solid porphyry. Drill cores two hundred feet or more in depth show that these veins exist even at that depth. Veins much more irregular, but of con- siderable size are to be found on Cedar hill Pilot Knob in Iron county. The ad- pitgllw ''& ^ '^M^*|||p5&£j joining cut 1 shows the nature of these veins. Workings subsequent to Prof. Pumpelly's ^ein^'s^eoulafSe"! re P ort have failed to reVeal lal 'S e deposits. porphyry. Larger veins on Shepherd mountain have The only bedded been more extensively worked. On Pilot Knob the deposits in ptio t 8 Knob! t general are of a wholly different character as will be pointed out later on, but in the solid porphyry, which underlies the main ore bed, veins of hematite of small size are found. On the slopes of all the mountains above mentioned there are numerous boul- ders of specular ore. These in every case partake of the nature of the ore in the veins of the mountains on which they occur. There is no difficulty thus in assigning these boulders to their respective sources. At Iron mountain and Pilot Knob these boulder deposits have yielded great quantities of excellent ore, and such deposits at Iron mountain have not yet been exhausted. On Clark's mountain, in Wayne county, boulders of specular ore have been found in considerable abundance, but the attempts to find the mother vein have thus far failed. The source of these boulders is, of course, the veins of he- matite which are yet found in the porphyry. The porphyry has Boulders of he- rotted, leaving the veins standing in the form of dikes of iron matlte derived o & veins are a oft e en dore - ^ s ^ e decomposed porphyry has washed away, these found. dikes are exposed to the weather, are broken up, and their frag- ments are rolled down the slopes of hill. These have been worn by the action of the rain and, probably, by water as well, into rounded or sub-angular boulders of ore. In places like Clark's mountain it may well be that the degradation of the porphyry 1 From the Report of the Geological Survey of Missouri, 1872, Part I, p. 19. THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 23 has proceeded to a point below the vein, thus leaving only, scat- tered boulders of the ore, remnants of formerly existing veins. THE IRON MOUNTAIN ORE DEPOSIT. Passing from the general discussion of the iron ores in the porphyry rock, let us examine more minutely the more prominent •of these deposits. One of the first reports written was by Dr. A. Litton of Washington University of St. Louis. His report soription of the ... pit • . * ton mountain gives us a very graphic picture ot the deposits before extensive deposit. mining operations had begun. Dr. Schmidt's report in 1872 will also be drawn upon, as this shows us some very important phases of these deposits which have long since been obliterated by the progress of mining operations. Early Description by Dr. Litton. In Prof. Swallow's Report of the Geological Survey of Missouri, published in 1855, Part II, p. 76, Dr. Litton writes as follows: — " As we ascend the southwestern termination of the little Iron Mountain, we find it covered with soil and clay, with, now and then, the iron ore lying loose on the surface. In passing over L *^ ii '9™ l ^ ut J| B the ridge connecting it with Iron Mountain proper, we find these were ex P° sea - angular and partially weatherworn pebbles and mnsses increasing in size, even until we reach its summit, where we find discon- nected masses, many tons in weight and often six or eight feet in ■diameter. These are sometimes almost totally uncovered; but, at other points, are seen projecting out from the soil and clay with which they are partially covered. Nowhere, on the Iron Mountain, can we find any rock ; and the masses of iron ore can- not be seenin place on the surface, but seem scattered irregularly, in confused masses." "It is not until we leave the jlron Mountain, and begin to ascend the ridge of higher hills, with which it is connected on the east, the course of which is about northeast southwest, that we could find anything else than iron ore, and where we find the hill composed of feldspathic porphyry. According to Mr. p ™ h "*^f5° 1 ™g or_ Mersch, who had opportunities to examine at the most favorable sharp! 8 roc '" seasons, this locality, there is a narrow wall connecting the mountain on the east with the main ridge* along the line of which 24 IRON ORES OF MISSOURI. The removal of the mantle of boulder shows the mother veins. wall the iron ore and the porphyry are intermixed for a short distance; but to the east of whiph, the porphyry, and to the west of it the iron ore, are each found perfectly pure and unmixed." "From surface indications, and from all explorations made, the whole of Iron Mountain seems to be a mass of iron ore." The above description made by Dr. Litton gives one a very graphic idea of the Iron mountain of forty years ago. There is little reason to wonder at the estimates which were then made as to the inexhaustible supply which this deposit was supposed to contain, when we couple Dr. Litton's description of the surface appearance with the fact that the base of the mountain covers about five hundred acres and that the highest point of the mountain is about two hundred and fifty feet above the level of the railroad. Distribution of Vein Ore in the Porphyry. In 1872 the work of mining had progressed to a considerable extent, enough to show that the mantle of boulder ore did not extend to the base of the mountain undiminished in rich- ness. The adjoining topographic- al^sketch, Fig. 8, by Dr. Schmidt, shows graphically the hill over which the surface boulder ore was strewn, and the positions of the cuts in the veins are marked by the letters A, B, C, D, E, F, G, and H. From the positions of these cuts, which are opened up on a more or less continuous vein, the general direction of the main ore body is seen to be nearly due southeast. When first the boulder ore was removed from the summit of the mountain, it was seen that this had been derived from a solid bed or vein which was then for the first time exposed. This vein measured sixty feet across at its widest place. Instead, however, of holding this width downward for any depth, it soon divided into two independent veins. These veins varied in width from 12 to 18 feet. Fig. 7 shows the positions of the veins and Fig. 6. Sketch of appeared In 1872. 100. Iron mountain as it From Report 1872, p. THE SPECULAR IRON ORES OP THE PORPHYRY REGION. 25 Character of veins. Pig. 7. Section of the Big Vein at Iron mountain. Cnt A, Fig. 6. their relations to the surrounding rocks. Flanking these veins on the southwest and the southeast are great masses of decomposed porphyry. The greater part of these bluffs are standing at the present time. They are com- posed of porphyry which has decomposed in situ. As is often the case in the weathering of massive rocks there is here an apparent bedding structure. In addition to this weathering in layers the rock at first sight seems to be made up of rounded water-worn pebbles of porphyry. Examination shows that these apparent pebbles are of porphyry and that they break into concentric shells. The interstitial matter is also decomposed porphyry. This material is laminated and it is seen that the laminae go entirely through the supposed pebbles. Further it is seen that this conglomer- atic structure ceases very often from side to side or along the greater axes of the lamina?. The accompanying sketch shows the appearance of the conglomerate. , Under the mine openings at the west side of the mountain, in fact in the foot wall of this ore body, the porphyry has a brec- ciated appearance. It seems to lie in beds which are more or less separated by bedding or parting planes. These parting Tne f00t waU of planes divide the foot wall rock into irregularly shaped masses, tafnvelifi's a UU " bed-like in appearance, of four inches to several feet in thickness. reoc a- The fragments of porphyry are comparatively fresh. The interstices are filled principally with a hard blue ore, with a coarse crystalline structure. Although the veins are very persistent, the filling matter is not constant. There are long spaces which are completely filled with light green crystals of the hornblende family. Crystals of milky quartz are also numerous. Apatite is, more rarely found. Yet embedded in the solid ore Fig. 8. Diagram illustrating the spheroidal weathering of por- phyry. Fio. 1. Illustrating brec- clated foot wall at Iron mountain. Reduced by about one-twentieth. 26 IRON. OEES OF MfSSOURI. the porphyry. Fig. 10. Showing veins of specular ore in Cut B, Fig. 6. The workings show the rela- tion of the veins io the porphyry. are crystals of apatite ranging from acicular crystals to large prisms one-half of an inch in diameter. Near the surface these Apatite fonnd in a re represented almost wholly by hexagonal cavities in the ore. The accompanying Fig. 9 shows the appearance of this breccia. Cut B, Fig. 6, shows' the relations of the veins which were exposed during the progress of the working in 1872. At that time, however, the veins were enclosed in the more decomposed por- phyry. They were of a workable size, but these have now been entirely ex- hausted. The remaining veins have also diminished in size and, in the fresher porphyry, they have thinned out to a point where it is no longer profitable to work them. Cuts C..C. and D, illustrated by Figs. 11 and 12, still fur- ther show the irregular distri- bution of these veins .through the rock mass and, by com- parison with the topographical sketch onp. 24, their relationsto the main body of the mountain will be apparent. It is a fact worthy of notice that only the smaller veins of ore have been Fig. 12. Showing veins of ore in Cut D of found to extend illto the fiesh- Flg. 6. er porphyry. Residuary Clays and Boulder Ores. The residuary clay, the " bluff" of the miners and the enclosed boulder ore is, with ex- ceptions which will be mentioned, practically about the same as it was in the earlier days of Iron mountain. This clay is tough and deeply stained with iron. To one with a love of color, nothing can be more beautiful than the various shades, from deep vermillion to the soft creamy brown and yellow, of the less The residuary weathered portions of this clay. On the summit and slopes of manybouiders Big mountain this richly colored clay is sparingly filled with blocks or boulders of iron ore of varying size. These blocks, though of remarkable purity, are not abundant enough to pay r^m^f^fc* 5iSife v CUT CC. •B- 1 ,-^^^ HON MOvNTAlK. «Of» !i&ps?=^ ■i-.-.V •'•■;-..■■■• Fig. 11. Showing veins of ore in Cut C. C. of Fig. 6. ore sur- THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 27 for systematic working on the summit of the mountain. Lower down on the slopes, though, the mountain is completely flanked by a thick mantle of this clay which lies on top of the Cambrian ^"n^er'thel rocks which also encircle the mountain. Inclosed in this clay f»°e° la y- are numerous smaller fragments of iron. These of themselves, are not of sufficient abundance to pay for working. Under the clay, however, and resting near the Silurian rocks' is a bed of varying thickness composed almost wholly of fragments of iron. Mingled with the iron are numerous small irregular fragments of chert. This detrital deposit is now being systematically worked. The iron of course, came from the decomposed por- phyry rock, while the chert must have come from a decomposed bed of Cambrian limestone. The enclosing clay is tough and bright red in color. The whole of this deposit, resting as it does upon Cambrian rocks, represents erosion and weathering since Cambrian time. As has been stated, this mantle of clay or "bluff" to-day, is about the same as in 1872. But all that is left to indicate the position, size and shape of the veins of ore are the cuts in the more decomposed porphyry, as well as small ones which, on Big mountain, reach into the fresher rock. The only remnant, of the great veins of 1872 is now being worked on Big mountain. The workings of to-day present quite a different phase. Following clown a lead on the west end of Little mountain a large body of comparatively undisturbed ore was found. This ore body dips steeply down on a foot wall of decomposed por- phyry which is intersected by a complete network of small ore g ts foand on veins of iron ore. The entire length of this ore body measured of Little monn- on the slope is about 360 feet. The thickness of the vein meas- ured from foot to hanging wall varies somewhat, but is between thirty and forty feet. The slope on the foot wall is nearly 40 G . The immediate hanging wall is a mass of a probably pseudo-con- glomeratic porphyry containing more or less iron or ore (see Fig- 8, p. 25). This hanging wall' conforms very closely to the foot wall as to slope. Overlying this are the Cambrian rocks. These are unconformable to the ore body. They have a slight dip with the vein, but this may haye been caused by the settling of the rocks owing to removal by solution of a part of 28 IRON ORES OF MISSOURI. the limestone. The comparatively recent clays and boulder iron ore overlie all. The adjoining cut, Fig. 13, gives a fair ~S5"S^57Ti== Boulders of Iron and chert In red Section at Little mountain. clay. Sandstone. Gritty limestone, not exceeding 15 ft. Indurated greenish clay. Psendo conglomerate. Solid iron ore, 30 to 40 ft. Brecciated porphyry with inter- stitial Iron. Solid porphyry with small iron veins. Fig. 13. Section of iron vein and overlying rock at Little mountain. representation of the relations of the rocks to the ore body. Owing to the fact that the Cambrian rocks thin out on the slopes of the mountain no exact measurement of the thicknesses of the rocks can be given. In' addition to this the individual beds thin out and thicken horizontally is such a way that a section correct in one locality would be incorrect at a distance of twenty feet. The location of this deposit is at cut H, on Dr. Schmidt's topographical map, p. 24. From the fact that on the east side of the mountain there is a large deposit of boulder iron ore which underlies the Cambrian rocks, this last described vein at first thought might be consid- ered as belonging to the same formation. It must, however, be T tain vein u oun considered as an undisturbed vein for the following reasons: > < « n u ' '"' The ore is comparatively solid, being only broken by seams such as are liable to occur in any rock. The ore body has a steeper dip than the slope of the mountain side. It ends abruptly at the bottom. It has a porphyry conglomerate as a ctfp rock or hanging wall which bears a close resemblance to a rock which has rotted in place. It is very safe to conclude then, comparatively undisturbed. THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 29 o if 2 fe 35 a a Eg Sg «■*■.. ©B rt-O ■§£ ■3 3 / that this is an undisturbed vein such as were found on the sum- mit of Big mountain. As will be seen by looking at the topo- graphical sketch map before referred to, all of the large veins were on Big mountain. It will further be noticed, by referring to the adjoining section (Fig. 14) through Big and Little mountains that the large ■conglomerate beds are at the eastern foot of Big mountain also. There is a bed of conglomerate which seems at first sight to be divided into two parts. The first, or upper part, is near F, on the topo- graphical map (see Fig. 6. p. 24). It runs under the overlying Cambrian rocks at an angle of about 30°. From the mouth of the slope to the point where it is intersected by the vertical shaft is about 480 feet. The deposit does not seem to have been laid down on the flat surface of the mountain but in a gorge or waterway down the slope. The thickest part of the bed from foot to hanging wall is about fifteen feet. This grad- ually thins out laterally towards the edges, giving a cross section of the bed of a roughly lenticular shape. It holds its size remark- ably well longitudinally along its slope. The ore body is not made up wholly of ore boulders, but there are found occasion- ally fragments of porphyry rock. The in- terstices between the boulders are filled with a bluish gray clay derived from the porphyry. The foot and hanging walls are related as follows: The foot wall a few feet below the actual contact of the ore is comparatively fresh porphyry which is filled with a net-work of veins of iron. The por- phyry itself, as is usual, contains scales of The section through Big and Little mount- ains. The deposit on the east side of Big mountain is not made up of iron boulders alone. 30 IRON ORES OF MISSOURI. hematite. This solid bed passes gradually upwards into one which is less fresh and, from that, into a conglomeratic looking mass which has large fragments of solid ore. This is succeeded Section of con- glomerate ore at big mountain. "iSSsS^iQj Porphyry boulders in clay. Boulders of specular iron ore. " porphyry. " iron ore. !$$$$?M " porphyry. " iron ore. " porphyry. Porphyry with veins of specular ore. Fig. 15. Section of first conglomerate bed at Big mountain. by a regular conglomerate of iron ore, the interstitial spaces of which are filled with a bluish green or gray decomposed por- phyry having little or no iron. The cap rock or hanging wall is Section of con- glomerate and limestone. Cambrian Limestone. Porphyry boulders in clay with grains of sand. First stratum of bonlder ore. Porphyry boulders. Iron ore " Porphyry " Iron ore " HI Porphyry " Solid porphyry with iron ore veins. PlO. 16. Section showing relation of conglomerate bed to Cambrian limestone. THE SPECULAR IRON ORES OP THE PORPHYRY REGION. 31 nearly identical with the parting beds in the iron, boulder beds, with the exception, that there are large boulders of porphyry clay with much quartz sand. The above section, Fig. 15, shows the relations of these alternate strata to the foot wall. This section is taken from one of the pillars of the slope near the mouth. Farther down the slope, towards the shaft, the ore bed is covered by a cap rock of limestone. The limestone, how- ever, is separated from the ore body by the porphyry conglom- erate, which does not seem to be conformable to the limestone, as the last section, Fig. 16, shows. The second, or lower portion of the boulder deposit, or the ^"eposttubnt part reaching from the foot of the shaft downwards, extends to the east from the foot of the upper portion and is partially separated from it by a tongue of Cambrian sandstone. The cap rock or hanging wall of the lower ore bed is of sand- stone and the foot wall is of porphyry. From the relative posi- tions of the two portions of the conglomerate bed to the sand- stone, it would seem that the lower ore body was formed in a period of time somewhat antedating the Cambrian age. This deposit, covered for the most part by a mantle of porphyry clay, reached up to and upon the slope of the mountain. This was then covered by the Cambrian sandstone which partially cuts off this deposit from the upper one. The following, Fig. 17, shows the relation of these parts of the bed to each other and to the accompanying rocks. From the section it will be seen that the continuation of the first de- posit from the foot of the shaft eastward. Fig. 17. Section showing the relations of the two conglomerate beds to each other. a tongue of ore reaches from the upper portion over the sand- stone but that this portion also continues down on the slope of the porphyry. The'tongue of ore, the foot of the upper portion, is 32 IRON ORES OP MISSOURI. much thicker than the head of the lower deposit and represents- an accumulation of ore after the sandstone had formed. From the beginning of the lower deposit to the end, or rather to the breast of the present workings, the length is about one thousand two hundred feet. The two deposits very closely resemble each other in cross sections. The first deposit is, however, very uni- form as to thickness along its entire length, while the second deposit in its thickest part is over forty feet. The gangue of the ore body in the second deposit is, like the The gangaeofthefi rs t> entirely of porphyry detritus consisting of a hard ?s, c iftethe P flrst indurated clay, which, in addition to fragments of hematite, has phf^yVetritns. fragments of hard, red porphyry, in some instances looking like jasper. At the extreme end of the workings, as now known, these porphyry fragments are becoming more numerous and the iron correspondingly less. At the foot of the shaft the sandstone seems to rest directly upon the ore body. About 240 feet east of the shaft, the bed of indurated porphyry clay begins and increases in thickness towards the east. So far as is known at present these are all of the great deposits of ore at Iron mountain. Vigorous prospecting, directed by a skilled geologist and engineer, is thoroughly test- ing the ground and it is to be hoped that this famous deposit may by this means have a renewed lease of life. PILOT KNOB. Early Description of, by Dr. Litton. Pilot Knob is hardly less famous than Iron mountain. Promising almost greater things Dr. Litton de- than did Iron mountain it has, however, never begun to realize scribes the ap- . ° pearanceof the hopes of its operators. Dr. Litton, in speaking of this PilotKnobwhen * x ' r a flrat opened, deposit, says : x " About six miles south and a little to the east of the Iron mountain, are other deposits of iron ore not less rich, and, in all probability, not less extensive. The rocks, near the base of Pilot Knob, are seldom seen in place; but when so, are of a dark gray color, present quite a siliceous and slaty or shaly character, and offer strong indications of stratification -~ Report Geological Survey of Missouri, 1856, Part II, p. 79. THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 33 They are not, however, horizontal, but dip at an angle of twenty- five degrees to the southwest. 1 After ascending about 300 feet, the rock assumes more of a ferruginous character and, at the height of 440 feet, we find, on the north side of the mountain, an exposure of a heavy bed, or rather stratum of iron ore, about T i s e ° w tn1y*fcrar 273 feet in length and twenty-four feet in height, or thickness, apparently passing, parallel with the lower slaty rocks, and with the same dip, through the mountain, to the southwest. It is said that at still lower points than the above stratum, and beneath it, are other beds, interstratified with the siliceous rock, but at the time of my visit the side of the mountain wa so covered with debris and undergrowth that I didn't find these in place. ( " Above the heavy stratum of iron ore, which is now quarried for smelting, the iron ore seems to be interstratified with the siliceous rock, even to the summit of the mountain." The following sketch copied from Dr. Litton's report gives an idea of the ore deposit at Pilot Knob when it was first opened. Sketch of the Enob in 1854. FIG. 18. Sketch of Pilot Knob as it appeared when first opened. In many of its physical aspects Pilot Knob differs from the porphyry hills in general. It is decidedly cone-shaped. It is almost isolated from the adjoining porphyry hills. It is con- 1 The dip, according to Pampelly, is, on an average, 13 degrees, and later workings, make this evident. 34 IRON ORES OF MISSOURI. nected on the east, however, with the higher hills by a low neck of porphyry which rises only about 200 feet above the surround- ing Cambrian rocks. The Character of the Ores. The ores of Pilot Knob are characteristically different from the other porphyry ores. The ores of Iron and Shepherd mountains and Cedar hill as well, are usually crystalline and massive in structure. The ores of Pilot Knob, though Knob are, on the other hand, fine grained, almost aphanitic, and very compact, . are siaty in are universally slaty. As they occur in the mine these bands structure. ^ J alternate with less rich ores or with thin bands of rock that carry so little iron as to give a gray streak and are thus totally unfit for smelting. In addition the ores were very low in phosphorus and such phosphorus as was present was distributed very uniformly. The Iron mountain ores, on the other hand, though in large part high grade Bessemer, contain a good deal of ore that is totally unfit for the manufacture of steel. The Modes of Occurrence. There are three distinct modes of occurrence of iron at Pilot Knob. As usual there are veins of iron in the massive porphyry, but no veins of economic impor- tance have been found. Boulder Ores. Distributed over the slopes of the mountain are numerous fragments of boulder iron. These fragments have, on the north side of the mountain, been in such abundance as to enable them to be dug with profit. They are embedded in a There are boulder tough red clay. One of these banks is at least thirty-five feet deposits on Pilot ,,.,-n , , 1 •• n , , , , , Knob which are thick. Jb rom the nature and position of the boulders there is no evidently de- ,.«.,. . . . rived from the difficulty in assigning their origin to the bedded deposits above them. Their slaty structure, close and fine grained, make this certain. Moreover they are always found belovi the outcrop of - ore. Whether the boulder ore is the same as that which extends under the Cambrian rocks on the flanks of Pilot Knob is hot certainly known. The following section, Fig. 19, is taken north, and south through the main body of ore on Pilot Knob, through the 1 Cambrian rocks in the valley between the Knob and Buzzards mountain. It is from a report made in 1890, to the Pilot Knob Company, by Prof. Wm. B. Potter, and is pub- lished here with the author's permission. THE SPECULAR IRON ORES OF THE PORPHYRY REGION. 35 The diamond drill holes (Nos. 48, 58, 49, 46 and 51) seem to indicate that the conglomerate ores which crop out in the open cut at 4 are continuous to the above mentioned point. In all five of these holes more or less iron ore was found and it is essentially of the same character as that found in the clays and resting on the porphyry rocks. As will be seen by consulting the figure, the sedimentary rocks nowhere extend below 200 feet in depth. It is a little remarkable that no sandstone occurs. The limestone, which is the ordinary magnesian, lies directly upon the porphyry detritus. Between this limestone and the solid porphyry lies the ore. Diamond drill holes have been bored cov- ering, in a very thorough manner, an area of about 400,000 square feet. This prospecting has dis- covered a very considerable deposit of iron, but its quality does not seem to warrant its being worked at present. This ore deposit occupies a position analogous to the boulder deposit at Iron mountain, the points of difference being that the Iron mountain deposit has a hanging wall of sandstone instead of limestone and the iron is rich and remarkably low in phosphorus, while the Pilot Knob boulder ore is rather lean though low in phosphorus and sulphur. Numer- ous bore holes put down at the west- ern foot of Pilot Knob have not discovered other boulder deposits. The accompany iiig section through Pilot Knob is de- scribed. 36 IRON ORES OF MISSOURI. Massive Ores. It is in the main ore body of Pilot Knob, how ever, that the greatest interest centers. Whatever its origin it is unique among the porphyry ores of Missouri in that it is bed- ded and bears strong evidence of a sedimentary origin. It is a P body °s ev°d e ent. sheet of roughly pear-shaped outline with its longest axis running nearly north and south. It has an average dip to the southwest of thirteen degrees. Fig. 20, on the opposite page, from Bulletin No. 5, Geological Survey of Missouri, shows this. Fig. 21, below, from the same Bulletin, shows the position of the ore body with reference to the hill. From this ly sedimentary in origin. Fig. 21. Sketch of Pilot Knob showing the position of the ore bed, 0-0, the cut on the north, the three tunnels Nos. 1, 2 and 3, the Simpson shaft, S, the out east of the company's office, 0, and several places where mas- sive rocks are exposed, M. Width of ore body irregular. sketch it will be seen that this ore deposit is near the summit of the Knob. If one measures the outcrop of the ore body on the arc of a circle repre- sented by the cuts A, B, and C of Fig. 22, it will be found that the arc is nearly 1,000 feet long. From this arc to the southwestern extremity the width of the ore body increases slightly and then rapidly contracts until it is cut out by the country rock. In bedded deposits generally the beds do not disappear in this manner, the bed usually grows either thinner until it is entirely FIG. 22. A topographic sketch of Pilot . , . , , - , , Knob. A, B, and U represent outs in the replaced DV the lOOt aim hanging ore body. From Report 1872, p. 110. r J ° ° wall coming together, or " pmches THE SPECULAR IRON ORES OP THE PORPHYRY REGION. 37 Fig. 20. A sketch map showing the outline and the extent of the oie bed on Pilot Knob. This ore bed reaches the sniface on the north and north-east sides of the hill; but on the west, south-west and south It gradually changes into porphyry. The double line represents the tramways. 38 IRON ORES OF MISSOURI. Pilot Knob ore bed fades into the country rock. out " in the words of the miner, or it breaks up into thin strings of ore. At Pilot Knob the ore bed gradually grows leaner until it finally passes, by almost insensible gradation, into the hard, apparently unstratified porphyry. This is true for the south- western side of the mine. On the northern and eastern sides the stratified ore body and its accompanying rocks come to the surface in a precipitous bluff. As to the relations of the ore body to the foot and hanging walls the following section, Fig. 23, shows this quite accurately. warn Heavy beds of conglomerate with an average thickness of 100 feet. Highly ferruginous slate.l to 3 feet thick. Main ore body, 19 to 29 feet thick. Slaty, ripple marked stratum in Im- mediate contact with ore body. Beds of conglomerate like hanging wall ; but finer and fresher ; under this the massive porphyry. Fig. 23. Section of conglomerate and ore body of Pilot Snob. Dimensions of the different strata are not given in ever3 r instance as they could not be measured owing to the falling in of the rocks. The Conglomerates. A more detailed study of these beds- may possibly give some clue to the origin of the conglomerates. The entire summit of the Knob is made up of a coarse conglom- erate, the interstitial filling of which is composed of sericite scales, occasional grains of sand and a large percentage of hematite. Were it not for the large conglomerate pebbles this gangue would in most cases pass for a lean iron ore. It gives a red streak tinged with gray. There is, besides the sericite The interstitial scales, a very fine constituent which is derived from the por- congfomerate is phy r y' The angular or subangular nodules which gives the rock tfte^ ely hema its name, at first sight resemble quaftzite. A close examination. Geological Survey or Missouri. Report on Ikon Ores, Plate I. Views illustrating the slaty structure of the hanging wall at Pilot Knob. Reproduced from photographs by F. L. N. THE SPECULAR IBON ORES OF THE PORPHYRY REGION. 39 shows most of them to be soft and talcose or sericitic. They are not filled with iron as are the interstices and they are much lighter colored. Some are still hard enough to scratch steel. Close inspection shows, further, that these fragments have B ^{SeSf™w inclosed within them still other smaller angular fragments. In breociated - other words this breccia conglomerate is made up of a still older breccia. 1 Some of the boulders of the conglomerate as it exists now are a foot or more across. The annexed, Fig. 24, drawn from a photograph, shows the conglomerate in a typical form. The Slaty and Jointage Structure. Towards the top of the ore bed the rock grows finer and shows a tendency to split into comparatively thin beds. The percentage of iron, however, does not increase to any extent. Fig. 24. Sketch showing In detail the structure of the _,. . . '. conglomerate above the ore body. ■^ 1 g- * °I the opposite Plate I, from a photograph, shows this eminently slaty structure to a very marked degree. Fig. 1, of the same plate, also from a photograph, giving a general view of the beds above the ore, shows this characteristic more in the thickly bedded. and„, J Slaty structure coarser conglomerates. The blocks into which the ioints divide and the jointing: ° J or the rocks and' the rocks are uniformly rectangular, or at least have little biethat y o r f e tySl departure from a right angle. These blocks most closely resem- cal8lat e s - ble the joint structures seen in slate beds. The undermining of these beds by the removal of the ore body has caused the rocks to settle unevenly and the great cracks extending to the very summit of the mountain show the blocks very clearly. These blocks have been referred by Prof. E. Haworth, to the basaltic or columnar structure often seen in eruptive rocks. 2 This structure, however, differs very essentially from the basaltic The jointing is by- forms. In the latter, the blocks or columns are often regularly the basaltic ' hexagonal and are also pentagonal and sometimes triangular; the eruptive rocks- 1 Attention has already been called to this fact by Prof. Haworth in Bulletin No. 5, p. 29, Geological Survey of Missouri, Jefferson City, 1891. 2 Bulletin No. 5, p. 17, Geological Survey of, Missouri, Jefferson City, 1891. 40 IEON ORES OF MISSOURI. edges are usually sharp and the columns are rarely more than two feet in diameter, and break horizontally with a ball and socket joint. At Pilot Knob the columns are without exception rectanr gular. They split along planes with no trace of ball and socket, and the blocks often are forty feet across one of the edges. In a word, they have the appearance of being modeled after the jointed and slaty structure of slate beds rather than after the basaltic structure of eruptive rocks. This jointage extends into the ore body, though not in so marked a degree. Separating this bed of conglomerate from the iron ore body AthinbedofsiateP ro P er > is abed of slate. This slate is highly ferruginous, so |iomeme°an j grained than ain. The conglomerate of that locality, it will be remembered, ^JJ^ fPilot was supposed to be due to the weathering of the porphyry in the one case, or to crushing in another. The porphyry of the ore body on Ced;ir hill is much coarser in grain than that of Pilot Knob. From the position and size of the vein on Cedar hill it is not difficult to imagine that it is but the mere remnant of a •once greater deposit. SHEPHERD MOUNTAIN. The ore deposits on Shepherd mountain, one mile to the west -of Pilot Knob, are also undoubted veins. These veins are nearly east and west in strike. They have been quite ex- tensively worked, but at a loss. On the western face the mountain has many rounded boulders of specular iron. This The iron ore of J L Shepherd iron, mingled with fragments of porphyry, is embedded in a mountain is de- ~ ° L £ J J rived from veins ■clay which is doubtless derived from the porphyry. These andboniderore. boulders are magnetic to an extraordinary degree. The deposits of Iron mountain and Pilot Knob have considerable magnetism, but none of them to the extent of those of Shepherd mountain. Practically this is the only point of difference between the ores -of this deposit and others, excepting Pilot Knob. The porphyry of this mountain is coarse and shows no traces either of bed- ding or conglomeratic structure. Some of the rocks, however, ■especially those associated with vein ores, are beautifully banded. The general appearance of the veins on Shepherd mountain as well as of the scattered fragments of ore lead to the conclu- mountain seems sion that the summit of the mountain has been much eroded and much eroded, that the vein has been worn down with it. No extensive pros- pecting with the object of testing the clays containing the boul- ders of iron has been done. If the vein is but the remnant of a once larger deposit, as seems to, be the case, there should be boulder deposits of considerable magnitude buried here. Smaller deposits have been discovered in several other locali- ties near Pilot Knob, but none have been found to be of com- mercial importance. 42 IRON ORES OP MISSOURI. CLARK S MOUNTAIN. On Clark's mountain, in Wayne county, large boulders of specular ore have been found. An attempt to locate the vein The veins from from which these boulders were derived met with no success. which the boulder ore on Shafts were sunk in the clay in which the boulders were embedded,. Clark's mount- J 7 n 1 ave V not d D 3 eer 1 e