<\ '/^, Cornell University Library The original of this book is in the Cornell University Library. There are no known copyright restrictions in the United States on the use of the text. http://www.archive.org/details/cu31924073916342 CORNELL UNIVERSITY LIBRARY 924 073 916 342 Production Note Cornell University Library produced this volume to replace the irreparably deteriorated original. It was scanned using Xerox software and equipment at 600 dots per inch resolution and compressed prior to storage using CCITT Group 4 compression. The digital data were used to create Cornell's replacement volume on paper that meets the ANSI Standard Z39. 48-1992. The production of this volume was supported in part by the National Endowment for the Humanities . Digital file copyright by Cornell University Library 1995. Scanned as part of the A.R. Mann Library project to preserve and enhance access to the Core Historical Literature of the Agricultural Sciences. Titles included in this collection are listed in the volumes published by the Cornell University Press in the series THE LITERATURE OF THE AGRICULTURAL SCIENCES, 1991-1995, Wallace C. Olsen, series editor. g>tate College of Agriculture at Cornell SHnibersfitp aitljaca, iS. g. ?Ci6rarj> SOIL FERTILITY AND FERTILIZERS. M g 3 Publishea by g I The Chemical Publishing Co. | ]k Easton, Penna. g g Publishers of Scientific Books " g Engineering Chemistry Portland Cement g Agricultural Chemistry Qualitative Analysis In! jg ij Household Chemistry Chemists' Pocket Manual ra g Metallurgy, Etc. g g| g Soil Fertility and Fertili izers By JAMES EDWARD HALLIGAN CHEMIST IN CHARGE, LOUISIANA STATE EXPERIMENT STATION EASTON. PA. THE CHEMICAL PUBLISHING CO. 1912 LONDON, ENGLAND: WILLIAMS & NORGATE 14 HENRIETTA STREET, COVENT GARDEN, W. C Copyright, 1912, by JEdward Hart. PREFACE. This book has been written to be within reach of the student, farmer, manufacturer and other persons interested in the sub- ject of "FertiHzers." Technical terms have been omitted as much as possible. It has been the aim of the writer to bring this subject up to date, not only from the manufacturers viewpoint but from the actual field results as well. A full discussion of the data in the tables has necessarily been avoided so as not to make the book too voluminous. Acknowledgments. The writer is indebted to the German Kali Works, Nitrate of Soda Propaganda, American Phosphate Mining Co., The Ameri- can Fertilizer Magazine and The American Coal Product.s Co. for illustrations. Credit is given in the text for illustrations secured from other sources. J. E. Halligan. Baton Rouge, La. CONTENTS. CHAPTER I— Chemical Elements Needed by Plants and the Composition of Plants 1-16 The Fifteen Elements. Distribution of the Elements. Composition of the Air. How Plants Feed. The Food of the Plant. Composition of Plants. Amounts of Water Used by Plants. Water in Young and Mature Plants. Dry Matter in Plants. Composition of the Dry Matter in Plants. Distribution of the Mineral Elements in Plants. Ash in Plants. Acids and Bases. Salts. Variation of Ash. Mineral Elements in Vege- table Substances. Distribution of Ash in Plants. Ash of Young and Mature Plants. CHAPTER II— The Fertility of the Soil 17-34 Composition of Soils. Factors Influencing Soil Fer- tility. The Plant Food Supply. Plant Food Removed by Some Crops. Plant Food not Available. The Es- sential Elements. One Element Cannot Replace An- other. Physical Condition of the Soil. Temperature. Mechanical Composition. Mechanical Analyses of Some Soils. Surface Area of Soil Grains. Relation of Mechanical and Chemical Composition. Lumpy Soil. Cracking of Soils. Puddling of Soils. Freezing and Thawing. Plants are Benefited by Open Soils. Plants Must Have Room. Plants Require Oxygen. Drainage. Capillary Water. The Biological Condition of the Soil. The Number of Bacteria in the Soil. Nitrification. Denitrification. Organisms that Gather Nitrogen. Inoculation of the Soil. CHAPTER III— Maintaining Soil Fertility 35-51 Erosion and Ways to Check It. Loss of Fertility by Drainage. Fallowing. Loss of Nitrogen by Con- tinuous Cropping. Losses of Phosphoric Acid and Potash. One Crop Farming. Diversification and Ro- tation of Crops. Make Up of a Rotation. Reasons for Rotating Crops. Rotation Keeps Down Weeds. Le- gumes are Profitable. Rotation Helps to Distribute F^arm Labor. Rotation Helps to Check or Eradicate Insects and Plant Diseases. It Furnishes Feed for LiveStcck. It Allows of a Regular Income. It Pre- vents Losses of Fertility. It Utilizes Plant Food More Evenly. It Saves Fertilizer Expenditure. It Regulates CONTENTS V the Humus Supply. Crop Rotations. System of Farm- ing. Loss of Fertility by Exclusive Grain Farming and by Stock Farming. CHAPTER IV— Farm Manures 52-74 Kinds of Manure. Conditions Affecting the Value of Manure. The Age of the Animal. The Use of the Animal. The Kind of Bedding and Amount Influences* the Value of Manure. Straw. Leaves. Sawdust. Peat. Absorptive Power of Bedding. Horse Manure. Cow Manure. Hog Manure. Sheep Manure. Hen Manure. Fowl Manure. Analyses of Farm Manures. How to Calculate the Amount of Manure Produced. The Na- ture and Amount of Feed Used Affects the Value of Manure. Commercial Value of Manure. Lasting Effect of Manure. Care, Preservaiion, and Use of Manure. Waste of Manure. Leaching. Fermenta- tions. Keep Manure Moist. Composition of Gases Formed in Manure Heaps. Composting Manure. Store Manure under Cover. Preservatives. Physical Effects of Manure. It Produces a Better Moisture Condition. Its Effect in Dry and Wet Seasons. It Improves the Texture of the Soil. Its Prevents Me- chanical Loss by Winds. It Benefits Grass Land. Bacteriological Effects of Manure. Time to Apply. Amount to Apply. How to Appl)'. CHAPTER V— High Grade Nitrogenous Materials. . 75-103 Forms of Nitrogen. The Meaning of the Form of Nitrogen. The Vegetable Substances. Cotton-Seed Meal. Commercial Classification Cotton-Seed Meal. Value of Cotton-Seed Meal. Linseed Meal. Castor Pomace. Rape Meal. The Chief Animal Substances. Dried Blood. Tankage. Grades of Tankage. Varia- tion in Tankage. Azotin. Steamed Horn and Hoof Meal. Dry Ground Fish. King Crab. Guano. Anal- yses of Guanos. Ammonium Sulphate. The Old and New Processes of Manufacture. Extent of Manufac- ture. Composition and Availability. Nitrate of Soda. Deposits and Shipments of Nitrate of Soda. Caliche. Composition and Properties of Nitrate of Soda. Cal- cium Nitrate. Process of Manufacture. Output and Value. Calcium Cyanamid. Composition of. Proper- ties of. Fertilizing Value of. Composition of High Grade Nitrogenous Materials. VI CONTENTS CHAPTER VI— Low Grade Nitrogenous Materials and Functions of Nitrogen 104-1 22 Raw Leather Meal. Feather Waste. Hair and Fur Waste. Mora Meal. Beet Refuse. Scutch. Horn and Hoof Meal. Wool Waste, Shoddies, Etc. Dissolved Wool, Shoddy, Etc. Garbage Tankage. Dried Peat. Availability of Nitrogenous Materials. Vegetation Ex- periments and Laboratory Experiments for Determining Availability. Description of Some Low Grade Mate- rials. Value of Low GradeMaterials. Use of Low Grade Materials is Increasing. Nitrogenous Materials to U.se. Statistics. Nitrogen Removed by Crops. Functions of Nitrogen. Excessive Nitrogen Invites Diseases. CHAPTER VII— Phosphates . . , 123-146 Bones. Raw Bone-Meal. Steamed Bone-Meal. Com- position of Raw and Steamed Bones. Bone-Black. Composition of Bone-Black. Bone-Ash. Composition of Bone-Ash. Dry Ground Fish. Mineral Phosphates. Production of. Exports. Western Deposits. Devel- opment and Production. Available Phosphate De- posits. Estimated Life of the United States Phosphate Deposits. Foreign Deposits. Utilization of the Phos- phates. South Carolina Pho.sphates. Florida Phos- phates. Tennessee Phosphates. Canadian Apatite. Rodunda Phosphates. Basic Slag. Comments on Basic Slag. Phosphatic Guanos. Classification of Phosphates. Form of Phosphates. Availability of the Phosphates. CHAPTER VIII— Superphosphates and Effect of Phosphoric Acid 147-177 Manufacture of Super or Acid Phosphate. Phosphates of Lime. Insoluble Phosphoric Acid. Soluble Phos- phoric Acid. Reverted Phosphoric Acid. Basic Slag Phosphate. Amounts of Acid to Dissolve Phosphates. The Reversion of Phosphoric Acid. Value of Reverted Phosphoric Acid. Difference Between Phosphate and Superphosphate. Names Applied to Superphosphates. Available Phosphoric Acid. The Diflference of the Forms of Phosphoric Acid in Superphosphate. Some People Favor Bone Superphosphates. Double Super- phosphates. No Free Acid in Treated Phosphates. The Color of an Acid Phosphate. Average Composi- tion of Superphosphates and Double Superphosphates. How to Make Superphosphate at Home. Amounts of CONTENTS Vll Phosphates Used for Manufacturing Fertilizers. Phos- phoric Acid Removed by Crops. Amount of Phos- phoric Acid in Soils. Fixation of Phosphoric Acid. Absorption of Phosphoric Acid. Functions of Phos- phoric Acid. Effect of Phosphoric Acid on Wheat. Crop Returns from Phosphatic FertiHzers. Rhode Is- land Field Experiments with Nine Different Phos- phates on Limed and Unlimed Plots. Comments and Summary on These Experiments. CHAPTER IX— Potash Fertilizers 178-206 Potash Salts (Stassfurt). History of. Discovery of. Kinds of. Kainit. Sylvinit. Muriate of Potash. Sulphate of Potash. Double Sulphate of Potash and Magnesia. Potash Manure Salts. Potassium. Magne- sium Carbonate. Composition of Stassfurt Potash Salts. Production of Crude and Manufactured Salts. Importations of. Consumption of. Potash from Or- ganic Sources. Wood Ashes. Analyses of Leached and Unleached Wood Ashes. Wood Ashes from Different Woods. Value of Wood Ashes. Tobacco Stems and Stalks. Cotton-Seed Hull Ashes. Carbon- ate of Potash. Beet Molasses. Wine Residues. Sta- tistics of Potash Fertilizer. Materials Used in Com- mercial Fertilizers. Amount of Potash Removed by Crops. Amount in Soils. Forms of Potash. Crop Producing Value of Potash Salts. Comparative Values of Sulphate of Potash and Muriate of Potash. Fixation of Potash. Functions of Potash. Potash Favors Car- bohydrate Formation. It Benefits Legumes. It Favors Seed Formation. It Effects the Leaves and Maturity. It Neutralizes Plant Acids. It Checks Insect Pests and Plant Diseases. CHAPTER X— Miscellaneous Fertilizer Materials... 207-227 Compost. Seaweed. Seaweed Ash. Marl. Peat and Muck. House Plant Fertilizers. Pulverized Manures. Fresh Fish Scrap. Lobster Shells. Mussels. Shrimp Waste. King Crab. Sewage. Sewage Sludge. Coal Ashes. Lime Kiln Ashes. Tan Bark Ashes. Rice Hull Ashes. Corn Cob Ashes. Leather Scrap Ashes. Brick Kiln Ashes. Ivory Dust. Spent Hops. Soot. Street Sweepings. Potassium Nitrate. Ammonium Nitrate. Silicate of Potash. Vegetation Experiments with Silicate of Potash. Production of Feldspathic Rock. Iron Sulphate. Common Salt. Powder Waste. Sul- VUl CONTENTS phates of Magnesia and Soda. Effect of Alkaline Salts on Wheat. Carbonate of Magnesia. Ammoniiini Chloride. Manganese Salts. CHAPTER XI — Lime, Gypsum and Green Manures. 228-249 Lime. Forms of. Sources of Carbonate of Lime. Analyses of Lime, Limestone, and Slaked Lime. When Soils Need Lime. How to Find out when Soils are Acid. How to Apply Lime. The Form to Use. Experiments with Slaked Lime and Limestone. Amount of Lime to Apply. Amount Removed by Crops. Amount of Lime in Soils. Mechanical Action of Lime. Lime Renders Plant Food Available. It Decreases the Action of Some Fungus Diseases. Rhode Island Ex- periments With Lime. Acidity of Upland Soils. Effect of Lime on the Growth of Plants. Effect of Lime in Conjunction with Nitrate of Soda and Sulphate of Am- monia. Gas Lime. Gypsum. Green Manures. Class- es of. Fertility Restored by Some Plants. Fixation of Nitrogen by Alfalfa. The Best Time to Plow Under a Green Manure. The Time to Grow a Green Manure. Deep Rooted Plants Valuable. CHAPTER XII— Commercial Fertilizers 250-274 Statistics. Consumption of Fertilizers by States. Cau- ses of the Large Consumption of Fertilizers. Fertilizer Materials Used by Manufactures. Approximate Output of Fertilizer Factories. Basis of Purchase. Unit and Ton Basis. Fertilizer Laws. Comparison of Require- mentsof. Model Fertilizer Law. Comments on. Ten- tative Definitions of Fertilizers and of Misbranding and Adulteration. The Meaning and the Interpretation of the Guarantee. Conversion Factors. Raw Materials Sometime Sold on Purity. CHAPTER XIII— Valuation of Fertilizers 275-291 Interpretation of Chemical Analyses. Agricultural Values. Commercial Values. Trade Values. How to Calculate Commercial Values. Comments Re- garding Valuations. Valuations Show Cost of Plant Food. Objections to Valuations. Some Favor Valua- tions. Valuations in Other States. CHAPTER XIV— High, Medium and Low Grade Fertilizers 292-307 Fillers. How to Avoid Paying Freight on. Cheap Fertilizers Often Demanded. Cost of Different Grades of Fertilizers. From the Standpoint of Cost. From CONTENTS IX the Standpoint of Value. Cost of Placing a Dollar's Worth of Plant Food in the Farmers Hands. As Between Manufacturers. Comparisons of Grades of Fertilizers. No Fertilizer Contains loo per cent, of Plant Food. Complete Analysis of a Commercial Fertilizer and of an Acid Phosphate. CHAPTER XV— Home Mixtures 308-325 Definitions. Manufacturers' Claims against Home Mixing. Reasons Why Farmers should Mix Fertilizers at Home. Plant Food Bought for $30 in Fertilizers. Selling Prices and Valuations of Factory Mixed Fertilizers. Home Mixing Acquaints the Farmer with Materials Used. Analyses and Valuations of Home Mixtures. Home Mixing Does Away with the Purchase of Unnecessary Constituents. How to Mix Fertilizers at Home. Rebates. How to Calculate Percentages from Known Amounts. How to Calculate Amounts from Known Percentages. Some Home Mixtures. How to Determine the Requirements of the Soil. CHAPTER XVI— A Few Remarks about Fertilizers. . 326-339 Brand and Trade Names. How to Purchase a Fer- tilizer. Study the Guarantee. Fertilizers Should Reach Their Guarantees. Fertilizer Recipes or Patent Formulas. Fertilizers do not Deteriorate Much on Standing. Incompatibles in Fertilizer Mixtures. How Fertilizers are Applied. Is it Profitable to Use Fer- tilizers ? Amount of Fertilizer to Use. CHAPTER XVII— Fertilizer Formulas for Crops 340-378 Staple and Special Crops. Small Grains. Corn. Cot- ton. Tobacco. Sugar-Cane. Irish Potatoes. Sweet Potatoes. Sugar-Beet. Sorghum. Peanuts. Flax. Hops. Lawns. Forage Crops. Soiling Crops. Scheme of. Ensilage. Pasturage. Hay and Grass Crops. Roots. Market Garden and Truck Crops. Requirements of. Formulas for. Fruits. Require- ments of. Pomaceous Fruits. Stone Fruits. Citrous Fruits. Bush Fruits. Miscellaneous Fruits. Nuts. Appendix. The Agricultural Experiment Stations 379 How to Collect an Exhibit of Fertilizer Materials 380-381 Fertilizer Constituents in Feed Stuffs 382-385 CHAPTER I. CHEMICAL ELEMENTS NEEDED BY PLANTS AND THE COMPO- SITION OF PLANTS. In order to thoroughly understand the subject "fertilizers," we must become familiar with the chemical elements needed by plants. There are about 8i chemical elements known to us, but only 15 of these are required for plant life so far as we know. The Fifteen Elements. — Hydrogen, oxygen, nitrogen, potassium, phosphorus, calcium, sulphur, silicon, iron, chlorine, magnesium, sodium, aluminum and manganese are the elements used by plants. Hydrogen, oxygen, nitrogen and chlorine, in the pure state, generally occur as gases, while the other elements are solids. The Symbols. — The chemist uses the following symbols for these elements. Hydrogen (H) Oxygen (O) Nitrogen (N) Carbon (C) Potassium (K) Phosphorus (P) Calcium (Ca) Sulphur (S) Silicon (Si) Iron (Fe) Chlorine (CI) Magnesium (Mg) Sodium (Na) Aluminum (Al) Manganese (Mn) Small amounts of oxygen are sometimes used by plants in the elementary state. Certain plants also use nitrogen in the free state. All other elements, and generally oxygen and nitrogen must be combined with other of these elements to be favorable for the support of plant life. Hydrogen. — This is a colorless invisible gas, having no smell or taste. It is generally found in combination with other ele- ments as water, hydrochloric acid, marsh gas, sulphuretted hydrogen, all acids and most organic (animal and vegetable) compounds. It is most commonly found as water (HjO), which is the most necessary food of the plant. In the free state hydro- gen occurs only in small quantities upon the earth in the gases of petroleum wells, around volcanic eruptions, and it is evolved by the fermentation and decomposition of some organic sub- stances. 2 SOIL KEUTILITY AND FERTILIZERS Oxygen. — In the free gaseous state, about one-fifth, by bulk, of the atmosphere is made up of this element, mechanically mixed with nitrogen. It is found in enormous quantities in combination with other elements. It constitutes about eight- ninths by weight of water and nearly one-half of the earth's crust. All combustion and decay require oxygen. The plant stores up oxygen in combination with other elements and with- out oxygen plants would die. The plant takes in oxygen, from the atmosphere, in combination with carbon, as carbonic acid gas, through the openings on the under sides of the leaves; the carbon is absorbed and the excess of oxygen given off. Oxygen combines with most other elements forming oxides. It often combines with other elements in varied amounts forming oxides of diflferent composition which are generally quite stable. The color of soils is often determined by oxides such as iron oxides. The iron oxides influence the moisture condition of soils be- cause of their absorptive qualities and help to oxidize organic substances in the soil. The roots of plants when deprived of air in the soil are able to draw upon iron oxides for oxygen. Nitrogen. — About four-fifths of the atmosphere, or about 35,000 tons over every acre of land, is made up of nitrogen in the free gaseous state. In combination this element is found in many substances such as ammonia, sodium nitrate (Chile salt- peter), potassium nitrate and many organic compounds. Cer- tain plants, namely the legumes, of which the pea, bean, alfalfa, clovers, cowpea, soy bean, etc. are members, have the power of gathering nitrogen from the air, by means of certain growths (tubercles) on their roots. Stone^ of the Massachusetts Agri- cultural College says in part: "There is evidence to show that a large number of organisms have the power of fixing nitrogen in the soil, for example, besides the species of clover bacteria, there is evidence to show that many of the algae which live in the soil and certain molds will do the same thing. In our work here, we find the largest percentage of nitrogen in those .-,olu- tions which are contaminated with the blue bread mold (Pen- cillium) showing that it is a nitrogen fixer. I think it will be CHEMICAI, ELEMKNTS NEEDED BY PLANTS 3 shown later on that quite a little nitrogen is fixed in the soil by this type of organism, exclusive of those on the nodules of the legumes." As far as we know our other plants are not capable of obtaining nitrogen in the free state. Although nitrogen is abundant in the free state it cannot be used as such by most plants and it must be combined with other elements to be avail- able as plant food. Nitrogen as sold in fertilizers is in com- bination with other elements, and is the most fugitive and ex- pensive of the essential elements. This will be described more fully later on. Carbon. — This element is found in the free state in charcoal, graphite and diamonds. In coal it is also present in an impure state. Muck and peat contain considerable carbon. Humus (the decayed organic matter in soils) is made up partly of car- bon. In combination with oxygen we find carbon as carbon dioxide (carbonic acid gas) in the air. It is present in greater quantities in plant life than any other element. Henry^ says : ■'10,000 volumes of air contain about 3 volumes of carbonic acid gas; 32 cubic yards of air hold one pound of this gas. An acre of growing wheat will gather during four months, 2,000 pounds of carbonic acid gas, or an amount equal to all the air contains over the same area of land to a height of three miles." All of our farm crops use a great amount of carbon in the form of carbonic acid gas. All carbonates (limestone, chalk, marble, shells, etc.) and all organic substances contain carbon. The carbonates of lime found in the soil exert a great influence upon the conversion of some forms of nitrogen into available plant food and in the general physical condition of the soil. Potassium in combination is very common. It is mined in large quantities as potassium salts in the Stassfurt mines of Germany. The presence of this element in wood ashes, as potassium car- bonate, makes this substance a valuable fertilizer. Potassium is found in most rocks and soils. In plants it is associated with organic acids. It is found in sea-water and saltpeter. This element is essential to plant growth and is found in the stems, leaves and fruits of plants. 4 SOIL FERTILITY AND FERTILIZERS Fhosphoms is found in combination with oxygen and metals, as phosphates. Vast deposits of phosphates are found in Ten- nessee, South CaroHna, Florida and some of the western states. It is present in many rocks and most soils and is an important element for plant food. It exists in combination with organic substances in plants and constitutes an important part of the ash of plants. Bones, which contain about 60-65 P^r cent, of calcium phosphate, are an important source of phosphorus for plant food. Calcium is an element which occurs in combination in many substances as lime, marble, shells, coral and gypsum. It makes up about one-sixteenth part of the earth's crust. Plants and animals require this element, sometimes in larger amounts than one would imagine. The bones of animals are made up largely of this element in combination as lime. Lime is a great factor in regulating the physical condition of soils. Sulphnr. — This is a yellow substance which is found in the free state in large deposits in Louisiana, western United States, and Sicily. It is found in combination in gypsum (an important in- direct fertilizer), pyrites (a source of sulphuric acid), galena, etc. It is also found in many natural waters. In plants it occupies an important place, occurring in organic compounds as protein, or nitrogenous portions, and also as sulphuric acid. Most of our soils are sufficiently supplied with this element for the nourishment of plants. Silicon occurs in combination as sand, flint, quartz, etc., and constitutes about one-half the earth's crust. It is present in most rocks and soils and plays an important part in the physical make up of the soil. Plants require this element to support certain parts of their structure. The hulls and straws of plant substances are often comparatively rich in this element. Iron is a very common element and in combination it is widely distributed. Although used in small amounts by plants it is nevertheless very important, as it is necessary for the produc- tion and activity of chlorophyll (the green coloring matter of CHEMICAL EI "E s lO fO CO CO VC vc vo VC vo vo vo vc vc c to oc s q fo CO 1^ tn — fO ^ dv oc CO lO fO CO 00 •a vo vt vo vc •a vo vo vo vO .2 2 1 ■c i 00 »o t^ lO c Z. q CO 00 q to ^ ON C ■^ u 00 lo N 00 a^ 3 >o vo vo vj: d vo vo vo so S O q « t- c ■» B lO « t^ 00 VO KJ - c^ c \o ^ M 00 CO* vO VC vo VC vo vo vo vo a _c s> in \o 00 o (ft q 00 ^9 « c ^ rJ d ON c h c ■^ tJ- >-^ 00 CO ■o vo >o vo vc ^ vo vo vO vo V oi O to u ? f q to 00 lo 1. N « Q d c rv 1 (S ro M r^ I^ V vo vT t^ vc ti vo vo vo vo C s rn to 00 « s t>. -^ W up z vo vo VD v£ r - z pI t-^ r^ vd vo vo vO vo ° O O " o lo «o w q -' " d c ^ N 11 r^ so vo vo r^ v£ vo vo vo vo O o c lO CO fO »o ao ^ d >- _ 00 N iJ I-C. vo* VO t^ r ■5 vo vo vo vo "? q u CO q q q vD d N P i \o rJ cJ CO r^ vo t^ r ^ vo vo vo vo a I n 1 _c i 1 s O ." , 1 \ ^ i 2 < , 1 i 5 1 t ■> 1 : 1 C > 1 !2; c > ■ J : c c i> ■■ ;c c a "s . t I ^ : S r ^ ^ (1 u c - r i > ^ - C 1 c i !2 E a a - c : a > M p. I 1 S ! ; p. < i o 'f CI * C 4 e ^ ? ^ ^ I a 5 "^ C 1 h- i/ ) V ! C > H I 5 3 a 3 1 THE FERTILITY OP THE SOIL 25 The germination of seed, the transference of soil water, which contains the available plant food, the movement of soil air, the development of organisms are all greater when the soil is warm. The coarser soils seem to warm up more readily than the heavy clays. The location of the land influences soil warmth. A soil with a southern exposure is naturally warmer than one with a northern location. In the following table are given the average mean monthly range in temperature of the air and soil for twelve years at Lincoln, Nebraska. ^^ >, >> .0 M u Depth 3 S 1 t < fl S V = 3 s u> s < s V to k 1 1 .a Air 25.2 24.2 .^S.8 52.^ 61.9 71.0 76.0 74-5 67.6 .55.5 38.7 28.3 Soil, I inch.. 27-.1 27.7 38.2 57-,S 68.7 78.1 8.S.I 82.9 73.8 56.7 38.7 31.6 Soil, 6 inches 28.6 27.8 36.6 5^■^ 65.1 7.'>.7 81.6 80.1 72.0 ,57-8 4i-,'> 32-0 Soil, 12 inches ?,i-?, 30.2 ?,^-4 49-3 60.7 69.9 7,5.7 y."!-? 69.2 ,'i7-8 44-7 ,3.'>-2 Soil, 36 inches 3«.5 35-5 35-« 43.« 53-5 61.3 67.4 69.8 67.6 61.3 52-2 43-3 The effect of the summer sunshine shows that the upper soil is warmer in summer than the lower or deeper soil. In winter the deeper soil is warmer than the surface soil. This shows the effect of the temperature of the air on soil warmth. Mechanical Composition. — Should we examine a few different soils we would find that there is a great difference in the size of the particles or grains that make them up. For example, when lumps of different soils are broken up and passed through sieves of various sizes, or shaken in bottles with water, particles vary- ing in size from gravel to fine dust are apparent. The grains or particles of soil are usually classified into four groups ; gravel, sand, silt and clay. Sandy soils predominate in the largest particles, gravel and sand, alluvial or silt soils contain more particles the size of silt, and clay soils have more of the finest particles, clay. It should be understood that all soils contain large and small particles. A loam soil contains all the particles in about equal proportions. 26 SOIL FERTILITY AND FERTILIZERS The Bureau of Soils of the United States Department of Agriculture has adopted the following measurements for the size of soil grains. Fine gravel 2.0 to i.o millimeters Coarse sand I.o to 0.5 millimeters Medium sand 0.5 to 0.25 millimeters Fine sand 0.25 to o.io millimeters Very fine sand o. 10 to 0.05 millimeters Silt 0.05 to 0.005 millimeters Clay. 0.005 'o 0.0000 millimeters Mechanicai, Analyses of Some Soils." Coarse Coarse Fine Heavy Heavy clay barren sandy sandy clay sand loam loam loam Fine gravel, 3 to i mm . . 0.2 7.6 05 2.8 0.4 Coarse sand, i to 0.2 mm. 22.6 44-9 15.0 14. 1 0.8 Fine sand, 0.2 to 0.05 mm. 60.8 23.1 490 31.2 6.4 Silt, 0.05 to o.oi mm 4.8- 4.3 15.3 17.4 18.6 Finesilt,o.oi to 0.005 mm. 0.6 2.9 3-9 6.9 13-6 Clay, below 0.005 mni ■ • ■ 1.8 11.7 9-7 18.5 42.2 The percentages of moisture, humus and carbonate of lime are not included in the mechanical analyses of soils. Surface Area of Soil Grains. — The surface area of soil grains varies with the size of the particles. The smaller the grains the more surface area is exposed to the action of water and soil organisms, and the more quickly is plant food rendered avail- able. Diameter Square feet of of surface grain in a pound Coarse sand, i mm 1 1.05 Fine sand, o.i mm iio.54 Silt, 0.01 mm 1,105.38 Clay, o.ooi mm 1 1,053.81 Fine clay, o.oooi mm 1,100,538.16 Relation of Mechanical and Chemical Composition. — The follow- ing table gives the chemical composition of different classes of soils.' ° THR FERTILITY OP THE SOIL 27 Conventional name . . . Per cent, present in soil . . Diameter of particles . . Clay 21.64 O.OII-O.OOO mm. Finest silt 23-56 0.005-o.ori mm. Pine silt 12.54 0.013-0.016 mm. Medium silt 13-67 0.022-0.027 mm. Coarsest silt 13- 1 1 0.033-0.038 mm. Constituents Per cent. Per cent. Per cent. Per cent. Per cent. Insoluble residue Soluble silica (SiOj) Alumina ( AljOg) Ferric iron { FCjOa ) Phosphoric acid (P2O5) • • Sulphur trioxide (SOg).- 15-96 33-IO 18.19 18.76 0.18 0.06 0.09 1-33 1.47 9.00 73-17 9-95 4-32 4.76 O.II 0.02 0.13 0.46 0.24 0-53 5-61 87-96 4.27 2.64 2-34 0.03 0.03 0.18 0.26 0.28 0.29 1.72 94-13 2-.^5 1. 21 1.03 0.02 0.03 0.09 O.IO 0.21 0.12 0.92 96- 52 Magnesia (MgO ) Soda (Na^O) Potash (KjO) Volatile matter Totals 99.84 99-30 100.00 100.21 96-52 Total soluble constitu- 75-18 20.52 10.32 5-16 The results given in this table show that clay contains more plant food than finest silt; finest silt more than fine silt and fine silt more than medium silt. In other words the finer the parti- cles in a soil the more total plant food is present. There is also more soluble silica and alumina in the finer soils. Lnmpy Soils. — The mechanical composition of a soil is import- ant, for the farmer to consider, in order to keep the soil recep- tive for growing crops. The clustering or lumping of soils is brought about by the adhering of the particles due to the surface tension of the films of water surrounding the grains. As the water dries out the grains are held together with the aid of the salts in solution. Fine soils, like clay, contain many more particles than sandy soils, so it is apparent that clay soils are more apt to form lumps than the coarser soils. Cracking of Soils. — When soils become dry the films of water around the soil particles become thinner and the soil contracts, breaking in the weakest point, causing cracks. 28 SOIL PEETILITY AND FERTILIZERS Fuddling of Soils. — If soils are worked when in a very wet con- dition the soil particles run together and a puddled soil is formed. After such a soil, especially a clay soil, dries out it becomes very hard and most difficult to restore to good con- dition. A farmer should never work a clay soil when it is too wet. Freezing and Thawing. — When soils are plowed deeply in the fall and allowed to be acted upon by the frosts a helpful crumb like condition results. The action of frosts is more apparent when northern and southern soils are compared. The northern soils treated as above are usually in better tilth than the southern soils in sections of little or no frost. Plants are Benefited by Open Soils. — A good tilth of the soil helps the plant a great deal in securing its food, and is therefore an important factor in the production of crops. A soil should be compact enough to support the plant in an upright position, but if it is too compact the young plant has to overcome a great deal of resistance in securing its food. Plants Must Have Room. — Only a certain number of plants can be grown successfully on a given space of land. We have only to examine the root development of mature plants to learn the spreading tendency of plants. If plants are too crowded, imperfect development is the result. The roots of plants spread somewhat and the distance apart is regulated to some extent by the available plant food, the nature of the plant and the tillage of the soil. In the foreign countries more plants are usually grown on a given area than in America but the land is perhaps more thoroughly tilled, because land is high in price and labor cheap, while in America land is comparatively cheap and labor high. In well tilled soils roots go deeper and do not spread so much as in soil in poor condition. Plants Require Oxygen. — A soil that is too compact will not per- mit of the free circulation of air. When air is excluded from the soil, free oxygen which is absolutely necessary for growth is excluded. It has been shown that when air is not freely supplied to plants they become sickly and growth is retarded. THE FERTILITY OF THE SOU, 29 When a soil becomes water-logged, plants will not grow and if the condition continues the plants will die. Some plants will grow in water but the water must be fairly free from soil so as to be able to absorb and diffuse oxygen from the air. It has been found that 40 to 60 per cent, of the water holding capacity of soils is the best amount and 80 per cent, is injurious. Drainage. — Good crops cannot be grown unless the land is well drained, either naturally or artificially. A certain amount of water is essential for crops, but a water-logged condition must be avoided to secure good results. Capillary Water. — In the preceding chapter we learned that crops use a great deal of water, the clover crop for example exhales as much as 1,096,234 pounds per acre. Crops usually rely on capillary water for their supply of this constituent. The upward movement of water in the soil is termed capillary moisture or capillary water, and is caused by the surface tension of the films of water around the soil particles becoming greater as evaporation from the upper surface of the soil takes place. One of the most important problems in farming is to conserve this soil moisture and prevent its evaporation. Amounts of Capillary Water Held by Soils. — Sandy soils hold very little capillary water. After a rain it is estimated that 5 to 10 per cent, by weight of the soil will be water. Sandy loams and silt loams retain 15 to 20 per cent, and heavy clay soils 30 to 50 per cent. Heavy clay soils are suitable for grass lands because of this power of holding water, as grasses re- quire considerable water for maximum growth. How to Prevent Loss of Capillary Water. — As capillary water is so important for the welfare of crops we should learn how to prevent its loss. Water will follow along the path of least resistance. So if we form a soil mulch by cultivating or stirring the soil to the depth of two or three inches we will offei- resist- ance to the upward movement of water. The soil should not be cultivated too deeply because some of the small roots are liable to be injured. 30 SOIL FERTILITY AND FERTILIZERS How to Increase the Upward Movement of Capillary Moisture. — When seed are planted in dry seasons it is often advisable to bring up the water to aid in their germination. This may be accomplished by rolling the soil thus making it firmer. After rolling it is important to form a soil mulch again to prevent the loss of all the water. The following table may be interesting in that it gives us some idea of the rate of the upward movement of water in different dry soils. ^° Time Min. Hours Days 15 I 2 I •3 8 13 19 Inches Inches Inches Inches Inches Inches Inches Inches Silt and very fine sand Very fine sand 2.7 7.6 9.0 5.8 4.0 4-7 lO.O 9-5 6.0 5-0 7.0 12.4 10.0 6.3 5-3 20.0 21.0 II.6 7-5 6.4 30 23 13 9 8 45-0 26.0 14-3 lo.o 9.0 52.0 27-5 15-2 II.5 lO.O 56-0 28.5 Coarse and medium 12.5 3. The Biological Condition of the Soil. — All cultivated pro- ductive soils are full of organisms, both animal and vegetable, which aid in furnishing plant food. There are many different organisms whose functions vary a great deal. Most of these organisms are so small that they cannot be seen without the aid of the microscope, while some, with which we are all familiar, are large. The rodents, worms and insects all have their place in stirring the soil although the rodents and some of the insects are in- jurious to crops. Plant roots are beneficial in that they leave organic matter in the soil and openings for the access of water and air. The organisms we are most interested in are the bacteria THE FERTILITY OP THE SOU, 3^ (minute plants) because of their beneficial efifect in crop produc- tion. The number of bacteria in the soil depends upon its physical condition. Water-logged soils, sandy soils, acid soils, and soils low in organic matter contain very few and sometimes no bacteria. Soils rich in humus, contain sometimes as high as 100,000,000 bacteria per gram,^ while the average well cultivated soil contains 1,000,000 to 5,000,000 per gram. The cold winters of the north decrease the number of bacteria but these multiply during spring and summer. The following table shows the number of bacteria found in a gram of soil during some part of the growing period.^^ state Soil Crop Investigator Number Grass, 12 yrs. Grass, 4 yrs . . Chester 425,000 425,000 Delaware . ■ . Chester Delaware • • . Clover follow- ing fallow . . Vegetables . . . Chester Rich garden Chester Chester 70,000 Loam (2.19 per Kansas cent, humus). Loam (3.07 per Mayo & Kinsley- 33-931.747 Kansas cent, humus). Thin soil , gumbo Mayo & Kinsley. 53,596,060 Kansas subsoil Loam, low in Mayo & Kinsley- 78,534 Kansas humus Loam, lo w in Mayo & Kinsley - 8,543,006 Kansas humus Mayo & Kinsley • 3.192. 131 Nitrification. — Certain bacteria have the power of converting the organic nitrogen present in animal and vegetable matter into ammonia. No doubt you are all familiar with the ammonia smell around fermenting manure. This is the result of the ac- tion of bacteria. The same action that takes place in the manure heap occurs in the soil when organic matter is present. When the ammonia is formed another kind of bacteria seizes it and changes the ammonia into nitrous acid or nitrites, and this latter 1 One ounce = 28.35 grams. 32 SOIL FERTILITY AND FERTILIZERS compound is in turn attacked by another organism and con- verted into nitric acid or nitrates. In this latter form it is readily dissolved by the soil water and available as plant food. There is a continual cycle of the forms of nitrogen. The plant 1 A' ootV j»iio--«4«4'«^ . ./ o NITROGEN CYCLE in l-he SOIL ■3 O o- o o c o e \ ^, il \ % .X Nitrogen of air Fis. 3.— The nitrogen cycle in the soil— after Whitson. uses the nitrogen in the form of nitrates, converts it into organic nitrogen, and when the plant dies it may be returned to the soil to go through the same process again. Manure or other organic matter helps nitrification as is shown in the following :^^ THE FERTILITY OF THE SOIL 33 Nitrates in parts per million, dry soil Unmanured soil 20 tons manure per acre for three years Land in timothy April 23 May 3 May 14 May 30 June I June 13 June 20 July 24 August 14 Land in maize May 19 June 22 July 6 July 28 August 10 8.2 4.1 .1-3 2.0 2.4 0.8 1-3 2.2 1.8 17-5 42.8 50-0 I95-0 151.0 31. 4.6 4-5 4.0 2.0 I.I 3-0 2.8 3-0 20.1 79-3 105.0 304.0 184.0 Keeping the soil well open so that a liberal supply of air may permeate it has a beneficial effect on nitrification.^^ Date of Analysis ' Nitrates in dry soil, parts per million Unaerated Aerated 3-2 4.2 9.0 3-2 17-6 45-6 The more porous the soil the deeper nitrification occurs. Dentrification. — There are some bacteria that set free nitrogen. These bacteria exert a reducing action rather than an oxidizing one. Some reduce nitrates (nitric acid) to nitrites (nitrous oxide) and ammonia. Others reduce nitrates to nitrites and then to free gaseous nitrogen. It has been found that there are more denitrifying organisms than nitrifying bacteria, although the loss of nitrogen from well drained and tilled soils is not large, because the denitrifying bacteria cannot attack the nitro- gen in such soils. The nitrogen wasting bacteria work con- siderable damage in manure heaps. 34 SOIL FERTILITY AND FERTILIZERS Organisms that Gather Nitrogen. — Other organisms found in the soil that exert an effect on its fertility are those that live in the tubercles or nodules on the roots of certain plants called the legumes, of which cowpea, bean, pea, clovers, alfalfa, vetch, etc. are examples. These plants through the action of these bacteria have the power of acquiring the free gaseous nitrogen from the air and utilizing it in their growth. The bacteria secure this free nitrogen from the air in the soil and the plant acquires it from the bacteria. When the plant dies the nitrogen left in the roots remains in the soil and thus enriches it. The par- ticular bacterium can only attach itself to the legume it is suit- able to. That is, bacteria forming tubercles on the roots of clover will not grow on cowpea roots. When there is a plenti- ful supply of nitrogen as nitrates in the soil the legumes will not always form tubercles and utilize the free atmospheric nitro- gen, but will gather their supply from the soil. Legumes therefore are able to secure nitrogen from the soil and the air. The tubercles seem to form better in alkaline soils containing lime. Inoculation of the Soil. — The absence of tubercles on the roots of legumes may therefore be due to the absence of the particular bacteria required, to the excess of nitrates, or to the acidity of the soil. Should the soil be deficient in the particular bacteria needed, the soil should be inoculated. This inoculation is ac- complished by sowing soil from a neighboring field that has produced a good crop of the kind desired, or if such a soil can- not be obtained, by inoculating the seed before planting with a pure culture which has been obtained from the tubercles of the kind of crop to be raised. These cultures may be obtained from the United States Department of Agriculture and dealers in seeds. In using soil from another field for inoculating, fungus diseases, insects and objectionable weeds are often introduced which become a serious menace in the production of crops. Care must be takefn to secure soil from a disease free field. The pure cultures are not always satisfactory, as they are hard to preserve in transportation, so that the use of soil is perhaps the better method just now. CHAPTER III. MAINTAINING SOIL FERTILITY. As the fertilizer ingredients, nitrogen, phosphoric acid and potash are the plant food elements that have to be supplied, let us find out some of the ways they are taken away from the soil and methods of preventing and restoring their loss. Erosion is the loss of soil by the action of water or wind. Any one who has ever lived in the South is familiar with the tremendous losses of fertility incurred by erosion. The most serious losses occur on hilly clay soils. Cotton and corn are grown on many of the southern soils year after year and the soil is left bare during the winter. These soils are not plowed very deep and when a heavy rain comes only a small amount of the water can soak into the soil. If the land is hilly the rain forms little rills at first which finally become gullies and much of the good fertile soil is washed to the valleys or bottom lands. In a few seasons a great deal of such hill land becomes unpro- ductive. There are other sections in America besides the South where erosion is damaging farms. In some of the far western states and other sections where the land is hilly, erosion is a source of loss of fertility. Erosion by water besides carrying away the most fertile part of the soil puts the land in such a condition that it is difficult to operate. Gullies are objectionable in growing crops. On light sandy soils the blowing away of the surface soil by wind often results in serious losses of fertility. Mounds or ridges are often formed which interfere with cultivating the soil. Ways to Check Erosion. — Plowing up and down hill is very bad practice as the furrows become regular waterways during a rain storm. In the South the lands that are subject to erosion are usually the clay soils which will not absorb water readily. Shallow plowing is practiced and deep plowing will cause more water to be absorbed and retained. Most of these soils are lack- ing in organic matter. By growing green crops in the winter 4 36 SOIL FERTIIvITY AND FERTILIZERS and turning them under in time for the summer crops, erosion will be stopped considerably during the winter and much organic matter will be supplied which will make clay soils more porous and spongy. Underdrainage prevents erosion by carrying the excess of water away gently. Many farmers terrace their soil to prevent it from washing away. This custom is not as beneficial as deep plowing, plowing under of green crops, or putting the land in pasture. Many of the most successful farmers keep their rows level so when it rains the water remains in the furrows instead of wash- ing down hill. These furrows will not be straight but answer the purpose of saving fertility. Drainage. — The loss of fertility by drainage is chiefly concerned in the loss of nitrogen. This element to be favorable for most plants to assimilate must be in the form of nitrates which are readily soluble in water. Phosphoric acid and potash are fixed in the soil so that they are insoluble in water and hence very inappreciable amounts are lost by drainage. The following table gives the composition of drainage waters from twelve plots upon which wheat was grown. These plots each possessed a tile drain at the depth of 2 feet to 2 feet 6 inches running down the center. Lime and sulphuric acid were carried away more than the other constituents and small amounts of potash and nitrogen as ammonia were lost. Nitrogen as nitrates show considerable loss while phosphoric acid was only present in drainage water in traces. Experiments have shown that the loss of nitrogen by drainage is greater on soils that are idle than on cultivated soils. At first thought one would suppose that the loss would be greater on the cultivated soils as they are more open and porous and hence permit of a more free passage of water through the soil. The excess of nitrates in cultivated soils is carried down in the soil but after a rain the capillary water carries it up again to the plant roots. Again, the plants are continually using up MAINTAINING SOIL FERTILITY 37 CI "33 o w O < g ft o O o o u M O r^vO 0\o r^^r^O 0^0^0 qsB^od }o ajBHdinsH- Bpos JO 3?Bqdins + lO ro w fO^O '"O r-»vo \0 0^ t^ <*i \o On ON M>-i ON « coOv\0«rO ■-I lO rj- rO — vO ro O ^O ^vD rOvO ON *0 ON 00 _ TT VO OnO " •^On'-' O O ^-^TfONON BpOS JO a^BJ^ia 'sqx oSS + NO 00 d 00 lO -^vd lO w i-J I CJ H, ^ « ID " -* ' fO O fO S3IB5 BIU -oiaoiB 'sqi o3fr + cho o ^t^ONONt-^i- ►- o\o o^ -^■^d moo «■ ooono d 00 i^w fO«-" 00 •-« WON lOi-fON 5)IB6 Bin -ouituB 'sqiooz + »oq6 d roi^^d « d f^M cf^Tj-r^ ononh- i-h w r^o t>-r^ r^vb ■-' on ^ w fodod io«-*vd lod '4dod dvo « ON l-> N Tt l-t Tj- M M — Tt q\ ■^ t>.NO r^ IH r^ t^ M vOVOdl^^iOrOpJONO I rn tn\0 cQ CO S M ■>! 2 bpii o2 is t3 5 O 0JJJ3SJ3 ffl S Ph 03 O U M (1| O tfltl 38 SOIL FERTILITY AND FERTILIZERS the available supply of nitrogen as fast as it is formed so that there is no appreciable excess to be carried away. It has been found that about 37 pounds of nitrogen per acre are lost from average idle land during a year. This loss of nitrogen is quite large when we consider the amounts removed by our farm crops. ^- Pounds of nitrogen removed per acre Wheat, 20 bushels 25 Straw, 2,000 pounds 10 Total 35 Barley, 40 bushels 28 Straw, 3,000 pounds 12 Total 40 Oats, 50 bushels 35 Straw, 3,000 pounds 15 Total 50 Flax, 15 bushels 39 Straw , 1 ,800 pounds 15 Total 54 Corn, 65 bushels 40 Stalks, 3,000 pounds 35 Total 75 Potatoes, 150 bushels 40 Fallowing. — In the arid sections of this country where dry farming is followed it is often necessary to let the land remain idle for a season to conserve enough moisture to produce pro- fitable crops. The land is usually plowed two or three times, at intervals, or plowed once and harrowed two or three times. This procedure keeps down the weeds and increases the mois- ture in the soil. According to King, 203 tons more water was found on fallowed land per acre in the spring following the fallow, than on land that was not fallowed, and 179 tons more water was found on the fallowed field after a crop was harvested than on the other field." MAINTAINING SOIt FERTILITY 39 Fallowing increases the supply of available nitrogen as nitrates and in some sections fallowing is practiced for this reason. The yield of the crop following fallowing is increased but consider- able humus is lost by being oxidized, and generally more ni- trates are formed than can be used up by the crop following fallowing. Snyder has found by experiments that 590 pounds of nitrogen per acre were lost by two years of summer fallow- ing, or an amount sufficient for five wheat crops. ^' At the Rothamstead Experiment Station experiments show that con- siderable more nitrogen was lost from bare soils than from wheat land.^' Nitrogen in Drainage Waters Average of 12 Years (or more). Rainfall (inches) January February March April May June July August September October November December January-April May-.-Vugust September-December January-December. . . 2.13 2.16 1.70 2.25 2.48 2.59 2.85 2.69 2.70 3.12 3.20 2.34 8.24 io.6i 11.36 30.21 Bare soil, 6o-inch gauge Drainage (inches) 1-93 1-74 0.94 0.79 0.79 0.78 0.62 0.76 0.82 1.68 2.32 1.88 5-40 2-95 6.70 15-05 Nitrogen (per mil- lion of water) 8.9 9-1 8-9 9.0 9-1 9-1 11.8 13-3 13-4 II. 9 11.4 10.6 9.0 10.6 II. 8 10.5 Nitrogen (pounds per acre) Wheat land, nitro- gen (per million of water) 3-88 3-57 1.89 1. 61 1-63 1.60 1.66 2.28 2.50 4-53 598 4-51 i°-95 7-17 '7-52 35-64 3-' 4.0 2.0 1-9 0.9 0.1 0.1 O.I 3-9 4-6 3-6 4-8 2.8 0-3 4-2 2.4 The loss of nitrogen from the bare uncropped soil reached 10.6 parts per million from May to August while that of the soil on which wheat was grown amounted to 0.3 pounds per million of water for the same period. After the wheat was harvested the loss of nitrogen increased. On rich soils the losses are greater than on soils deficient in organic matter because the oxidation of organic matter is more 40 SOIL FERTILITY AND FERTILIZERS rapid. It is evident, then, tiiat fallowing increases the production of crops at the expense of a reduction of organic matter. In sections of plentiful rainfall, fallowing is often injurious and it should only be practiced in the dry sections where there is not enough rainfall to carry away the nitrates and therefore not sufficient moisture for the continuous growing of crops. Other Ways Nitrogen is Lost. — The washing away of nitrogen as nitrates is not the only way this element is lost, but consider- able of this valuable constituent escapes in the form of gases. This loss as gas is occasioned by dentrification, which reduces the nitrates to gases, and to the liberation of nitrogen from organic matter. The loss on soils rich in organic matter is greater than on poor soils. Experiments show that in continuous cropping more nitrogen is usually lost than the crop removes. The following table il- lustrates this point.-" Loss OF Nitrogen by Continuous Cropping Per Acre Per Year. Name of crop Wheat Corn . . Oats - . Barley Nitrogen lost K°;i,'"i'™?- removed and lost Pounds 171 85 196 200 The loss of nitrogen by continuous cropping of cotton, corn, tobacco and the cereal crops is a very serious one. Loss of Phosphoric Acid and Potash. — Although phosphoric acid and potash are usually present in the soil as compounds in- soluble in water, nevertheless large quantities are lost every year by being carried away with the soil into rivers and other streams. Again, traces of phosphoric acid and potash are carried away in the soluble form by drainage and although this loss is not large per acre it amounts to a great deal in the course of time. The Mississippi River deposits in the Gulf of Mexico 3,702,758,400 cubic feet of solid material per year. One cubic foot of this solid material weighs about 80 pounds. MAINTAINING SOIL FEETIUTY 41 This material is quite rich in potash often containing as high as 0.50 per cent, of this constituent. The phosphoric acid con- tent is much lower than this figure but it is considerable. The rivers that empty into the oceans in the northern part of the United States do not perhaps carry away so much fertility as the rivers of the far south, but the annual loss of the mineral elements carried away in streams is appalling. One Crop Farming. — The exclusive growing of one crop caused more farms to be abandoned in the United States than any other practice. The continuous cropping of wheat in the West, to- bacco in Kentucky, Virginia and North Carolina, cotton in the South, and corn in the North Central States has always resulted in the loss of fertility and depletion of the soil. All of these crops with the exception of corn are sold from the farm without the return of any fertility. On most of these one crop farms no fertility is put on the soil and the farm is abandoned or else artificial (commercial) fertilizers are used. Most of our soils in the United States were formerly fertile but the practice of growing crops without returning organic matter has resulted in decreasing the yields on our older cultivated lands. Under the subject "fallowing" we learned that it was poor procedure to allow the land to lie idle except in dry regions, and the best farmers to-day are those that utilize their land continually and to the fullest extent. When we visit some of the European countries where land has been in cultivation for centuries, we find. that these lands are still producing valuable crops, and that the yields are as large, if not larger now, than they were two centuries ago. This condition exists in Europe because fer- tiHty has been returned to the soil every year to sustain crops. Fortunately, land has been comparatively cheap in the United States and when a farm failed to produce paying crops another piece of land was secured, and so on. The time has arrived when the acquiring of new land for one crop farming is hard to obtain at a price within the bounds of such farmers. So it is now necessary and more profitable for the farmer to grow other crops in conjunction with his money crop. This growing of other crops is called diversifying or rotating. 42 SOIL FERTILITY AND FERTILIZERS Diversification and Rotation of Crops. — Diversification is the growing of different crops without any regular or definite sys- tem. Rotation of crops is spoken of as growing a certain num- ber of crops, in regular order, on the same piece of land. For example, a rotation may consist of four crops, corn, oats, wheat and clover, and will be called a four year rotation because these crops will be grown in order on the same piece of land and take four years to complete. A farmer may have i6o acres in his rotation and each year 40 acres will be allowed for each of the four crops mentioned. Each 40 acres will grow the same crop every fifth year and one of the crops every year. The terms six-year, five-year, four-year, three-year, two-year, etc. are applied to rotations depending upon the time it takes to complete them.. Rotations taking 15 years to complete are known in Europe but the short rotations of three to six years are found to be profitable in the United States. Make up of a Rotation.— The crops used in rotations are natu- ally selected according to the location, nature of the soil, avail- able crops, market prices, kind of farming, insect and plant dis- eases, climate, etc. A stock farm would require different crops than a tobacco farm ; a dairy farm in Wisconsin could not pro- bably use the same rotation as a dairy farm in Alabama; two farms in the same state with different soil conditions would perhaps select different crops for a rotation; a farm ten miles from a market would no doubt find it more practical to grow different crops than one 1,000 miles away; and crops would not be chosen that insects or plant diseases ruin. Reasons for Rotating Crops. — Some of the reasons for rotating crops are: 1. To keep down weeds. 2. To gather nitrogen from the air. 3. To distribute farm labor more evenly. 4. To eradicate insect or other diseases. 5. To furnish feed for live-stock. 6. To give the farmer a regular income. 7. To prevent losses of fertility. MAINTAINING SOIL FERTILITY 43 8. To utilize plant food more evenly. 9. To include deep and shallow rooted plants. 10. To save fertilizer expenditure. 11. To regulate the humus supply. 12. To conserve moisture in dry sections. 1. Rotation of Crops Keeps Down Weeds. — It is well known that the growing of particular crops is accompanied by certain weeds. Those crops that are sown broadcast, as the small grains, are more apt to be weedy than cultivated crops as corn, cotton, tobacco, potatoes, etc. When crops like wheat, hay, etc. are grown continuously the yields or the quality of the crops are often materially reduced by weeds. Intertilled crops as corn, tobacco, cotton, potatoes, etc., when well cultivated, are known as "cleaning crops." So in planning a rotation crops should be selected that will tend to keep down weeds. Culti- vated crops should be included with those that are sown broad- cast. 2. legumes are Profitable. — By including legumes as clovers, Canada field pea, cowpea, velvet bean, soy bean, etc. in a rota- tion, it is possible to gather considerable nitrogen, which ia the most expensive fertilizing element to buy, from the air. A crop of red clover, one year old, is estimated to contain 20 to 30 pounds of nitrogen in the roots, per acre. A crop of cowpeas in Louisiana furnishes 100 pounds of nitrogen per acre. By plowing under leguminous crops enough nitrogen is often fur- nished so that the following crop does not require any extra supply, and of some nitrogen has to be supplied, that amount is much less than it would be were not nitrogen gathering crops utilized. The Minnesota Experiment Station^^ found a loss of 2,000 pounds of nitrogen per acre when wheat, barley, corn and oats were grown for twelve consecutive years ; two-thirds to three- fourths of this amount was not used by the crops but was lost in other ways. The Ohio Experiment Station^^ found that there was a gain of 300 pounds of nitrogen per acre in excess of what the crop utilized when clover was included in five-year rota- 44 SOIL, FERTILITY AND FERTILIZERS tions, covering periods of ten years. When timothy and non- legumes were used in place of clover, nitrogen was lost from the soil ; the loss of nitrogen from the soil was a little more than that removed by the crop. 3. The Distribution of Farm Labor. — One of the most important points in favor of a rotation of crops is that it allows of a more even distribution of farm labor. When several crops are grown every year the farmer is able to employ help the greater part of the year and thus secure more efficient labor at a less cost for the work performed than should single crop farming be in vogue. 4. The Checking or Eradication of Insects and Plant Diseases. Many times crops became so badly attacked by insects, or in- fested with plant diseases, that there are no profits and often large losses in trying to produce them, on the same iield con- tinually. A rotation of crops often eliminates such troubles because certain insects and plant diseases are only common to one particular crop. A good illustration of this is noticeable in the growing of cotton. There is an insect called the cotton boll weevil, which punctures cotton bolls and destroys the crop. Fields that once produced valuable crops of cotton must now be planted to other crops which. are not injured by this insect. 5. Kotation Furnishes Feed for Live-Stock. — One crop farmers are often forced to buy feed for their live-stock. A farmer who uses a rotation of crops can plan his rotation so that most of the feed will always be produced on the farm. In one crop farming the sale of the crop brings only one value. When several crops are grown it is possible to produce feed for live- stock and a double value is received for the crop. This double value is represented in the feeding value and fertilizing value, the crop is fed and the manure spread on the land. 6. A Regular Income. — Farmers who raise single crops receive their money but once a year and many of these farmers use their crops in paying the merchant for the last year's supplies. They often live from year to year on the credit basis and pay much more for their supplies than the farmer who is able to pay for MAINTAINING SOIL t'EKTILITY 45 what he gets in cash. In certain sections of this country this credit system of farming has proved disastrous because one or two bad years caused the loss of the farm. The single crop farmer generally has to buy more supplies than the farmer who grows several crops. The farmer who practices rotation has crops to sell at different times in the year and so has a more regular income than the single crop farmer who gets his money but once a year. 7. Preventing Losses of Fertility. — The farmer who rotates his crops may sell the crop that removes the least fertility from the soil and if the money crops remove a great deal of fertility, he may regulate his rotation so as to restore this loss cheaply. 8. A rotation of crops utilizes plant food more evenly than when single crops are continually grown. Corn, wheat and other grain crops use a great deal of nitrogen and phosphoric acid while tobacco and potatoes are heavy potash feeders. By the proper selection of crops forming a rotation, the plant food may be drawn on more evenly and losses of fertility prevented through leaching, etc. 9. Deep and Shallow Rooted Plants. — A rotation of crops has an advantage over single crop farming because of the variation in depth of root systems of different crops. Alfalfa and corn have deep tap roots and obtain food from the subsoil, while oats, timothy, blue grass, rye, etc. have shallow roots and feed from the upper soil. By alternating deep and shallow rooted plants the fertility from the subsoil and surface soil is more evenly utilized. Often the surface soil may predominate in nitrogen and phosphoric acid and the subsoil in potash and lime. When the fertility is thus distributed the alternating of shallow and deep rooted plants is important as the fertility of the subsoil is brought to the surface soil by the decay of roots. Another advantage of growing deep and shallow rooted plants is the improvement of the physical condition of the soil. Deep rooted plants tend to make a soil more porous because the decay of roots leaves passages in the soil which aid in draining and aerating it. Grass crops tend to make a soil compact, while 46 SOIL FERTII,ITY AND FERTILIZERS alfalfa, roots, grains and other cultivated crops tend to open up the soil. A rotation should be selected to keep the soil in good physical condition. Sandy soils are improved by crops that compact them while clay soils should he made more porous. 10. Rotation Saves Fertilizer Expenditure. — On some farms that formerly used 150 to 300 pounds of commercial fertilizer per acre, as high as 1,500 to 2,000 pounds must be used now to give the same yields. A proper rotation of crops will save the employment of such large quantities of commercial fertilizers. Farm manure may be used, and commercial fertilizer only ap- pHed to those crops that are most in need of nourishment. 11. Rotation of Crops Regulates the Humus Supply. — Some crops furnish humus while others tend to deplete the soil of this material. Single crop farming is very exhaustive on the humus supply of the soil while a rotation of crops should be selected to conserve the humus content of a soil. Grass crops tend to increase the humus supply, while grain, cotton, tobacco, etc. have the opposite effect of consuming humus. The addition of farm manure is helpful in supplying humus. The following table shows the effect of a rotation of crops on the humus supply.^^ ■e .-a £ft! o I" be V o u it "5 "■ft O 4) ^ m .0 S " g a u P4 u£Pn fe ",5' Cultivated 35 years; rotation of crops and manure; high state of productiveness Originally same as i; continuous grain cropping for 35 years; low state of productiveness Cultivated 42 years; systematic ro- tation and manure; good state of productiveness Originally same as 3; cultivated 35 years; no systematic rotation or manure; medium state of pro- ductiveness 70 72 70 67 3-32 1.80 346 2.45 0.30 0.16 0.26 0.21 0.04 0.03 0.03 48 39 59 57 MAINTAINING SOIL FERTILITY 47 cc •2 F". A J3 s 5 s > u - m i2 < X a. p O il' 6 b X >. 3 E^ > t. o X a-d Ri i o E ■o s t 1 s cd i2 efl •sS CO 1 CO s 1 i »4 o f, o a 2 bo 1 < 5 2 £ o m S bO -c C re U s w w o o i 1- I i J 1^ o V & V 1 1 < JU a 5 IS JO *a H 83 c o s-ss "^ "■0 135 Is. ■S a "§§ 1 U W Rl 'tn o = u o O 1 o u o in ei E rt , (ft O o B- "o'i si >> M V ■a 2 CO o g 1 is 1 u o n O 1 8 -a V 1 N Z 8 E S >, o I 1 s ! o u If 1 Clover cut for hay plowed under; f lowed by cowpc for hay; seeded small grain -0 n 0.2 V a V ' 5 |i eg re 1 a ^ >> S 5 a 5 1 "a 1 < i a 5 u re I u O re w o J; ii •E o 5; ■O o 11 1 £12 « « c 01 a c 3 u u ^ o ^ o o s u o CI U B Rl I: (A 2 . s 1^ si CO 5 2 'to' CO V .2 en 1 1 ^1: m'a ' .2 2 2 ■d s a >> g o t/} U) E « w m w 'iS s be CO S|S ■ i' T3 4l£ 1 o o ■c a a «j 1^ "1^ 1 1 1 o u u .c 8 S O "•5 o 1 u re u C re Cfl-O = '5 a E hT a is > b o :-H ^ 5 < u X w » w 48 SOIL FERTILITY AND FERTILIZERS Approximate Maximum Amounts Rkmovable Per Acre Annually Produce Pounds Market value Kind Corn, grain . Corn, stover. Corn crop' Oats, grain. Oat straw ■ ■ Oat crop . Wheat, grain Wheat straw Wheat crop Soy beans ■ • Soy bean straw Soy bean crop. Timothy hay. Clover seed — Clover hay . . . Cowpea hay. . Alfalfa hay . ■ . Cotton lint Cotton-seed .... Cotton stalks Cotton crop . . Potatoes . . . Sugar-beets. Apples Leaves Wood growth Total crop. Fat cattle . Fat hogs • . Milk Butter Nitro- gen ICO bush. 3 tons loo bush. lYz tons.. 50 bush.. 2% tons. 25 bush. 1% tons. 3 tons ■ . 4 bush. 4 tons . . 3 tons- . 8 tons. . 1,000 lbs. 2,000 lbs. 4,000 lbs- 300 bush. 20 tons... 600 bush • 4 tons I tree . . . 1,000 lbs.. 1,000 lbs. . [0,000 lbs. 400 lbs . . . 100 48 148 66 31 97 71 25 96 80 79 159 72 07 160 130 400 03 63 102 168 63 too 47 59 06 25 18 57 o.: Phos- phorus' 17 06 23 II 05 16 12 04 16 13 08 09 02 20 14 36 0.4 II 18 29.4 13 IS 05 07 02 14 07 03 07 0.2 Potas- siuni^ Nitro- gen 19 52 71 16 52 $15.00 7.20 9.90 4.65 68 13 45 58 24 49 14-55 10.65 3-75 14.40 0.48 12.00 11.85 73 71 03 120 98 192 04 19 59 82 90 157 57 47 05 109 ot 01 12 0.1 23.85 10.80 1.05 24.00 19-50 60.00 0.45 9-45 15.30 25.20 9-45 15.00 7-05 8.85 0.90 16.80 3-75 2.70 8.55 0.12 Phos- phorus 0.51 0.18 0.69 0-33 0.15 0.48 0.36 0.12 0.39 0.24 0.63 0.27 0.06 0.60 0.42 1.08 O.OI 0-33 0.54 0.88 0.39 0-54 0.15 0.21 o.o5 0.42 0.21 0.09 0.21 O.OI Potas- sium 1. 14 3 12 4.26 0.96 3-'2 4.08 0.78 2.70 3-48 1.44 2.94 4-.38 4.26 0.18 7.20 5.88 11.52 0.24 1.14 3-54 4.92 5-40 9.42 3.42 2.82 0.30 6.54 0.06 0.06 0.72 O.OI Total value fi6.65 10.50 27.15 II. 19 7.92 19. 1 1 11.79 6.57 18.36 13.83 15-03 28.86 15-33 1.29 31.80 25.80 72.60 0.70 10.92 19-38 31.00 15.23 24.96 10.62 11.88 1.26 23-76 4.02 2.85 9.48 0.14 ^ To change phosphorus to phosphoric acid, multiply by 2.29. - To change potassium to potash, multiply by 1.204. 2 To this might be added 1,000 pounds of corn cobs, containing 2 pounds of nitrogen, less than J^ pound of phosphorus, and 2 pounds of potassium. MAINTAINING SOII, FERTIUTY 40 12. Rotation of Crops Conserves Moisture. — In the arid regions the conservation of moisture is an important consideration in planning a rotation. Heavy moisture consuming crops should not be planted in succession in sections of small rainfall, but heavy consuming and light consuming moisture crops should be so grown as to conserve the moisture supply. Crop Rotations. — On page 47 are a few examples of crop rotations practiced in different sections of the United States. These have been secured from various sources. System of Fanning. — The loss of fertility sold from the farm every year depends upon the kinds of crops produced and sold. The table on page 48 gives the fertility removed by farm pro- duce." Note the small amount of fertility lost when live-stock are sold and also when butter and milk are marketed. The legumes and root crops remove a great deal of potash. When crops are fed to live-stock and the manure produced put on the land there is not a great loss of fertility, but when crops like the cereals are sold there is no saving of fertility. Loss BY Exclusive Grain Farming." Sold from the farm Nitrogen Founds Phosphoric acid Pounds Potash Pounds Flax, 40 acres . Flax straw Wheat, 50 acres Wheat straw • . ■ Oats, 20 acres . . Oat straw Barley, 50 acres Barley straw • • ■ Total 1,600 600 1,250 500 700 300 1,400 600 6,950 600 120 625 375 240 120 750 250 3,080 800 320 350 1,400 200 700 400 1,500 5.670 On this farm of 160 acres the loss of nitrogen is practically four times the amount (6,950) because in this system of farm- ing four times more nitrogen is lost by natural means than is removed by the crop. This will total the loss in this farm to 27,800 pounds of nitrogen, 3,080 pounds of phosphoric acid and 5,670 pounds of potash. On this farm the straw is burned and the ashes thrown away and no live-stock are kept. 50 SOII< FERTILITY AND FERTILIZERS On another farm of the same acreage where live-stock are kept, manure saved, several crops grown, and rotation practiced, the following are the losses i^" Stock Farming. Sold from the farm Nitrogen Pounds Phosphoric acid Pounds Potash Pounds Butter, 5,000 pounds Young cattle, 10 head Hogs, 20 of 250 pounds each Steers, 2 Wheat, 10 acres Flax, 10 acres Rye, 10 acrrs Total Raised and consumed on the farm Clover, 20 tons Timothy, 20 tons Com, 20 acres Corn fodder, i acre Mangels, 2 acres Potatoes, I acre Straw, 40 tons Peas, 5 acres Oats, 20 acres Barley, 20 acres with straw Total Mechanical loss of food con- sumed, 3 per cent. Feed and fuel purchased Bran, 5 tons Shorts, 5 tons Oil meal, i ton Hard-wood ashes Total Mechanical loss in material pur- chased, 3 per cent. Sold from farm Loss in feed consutned Total Feed and fuel purchased Balance lost from farm 5 200 100 48 250 390 _285 1,278 4.265 128 275 250 IOC 625 19 1,278 1 28 1.425 625 800 5 190 40 38 125 150 128 676 1,780 53 260 150 35 25 470 J4 676 53 743 470 273 5 16 10 4 70 190 85 380 00 270 600 600 180 800 1,500 300 800 75 '5 60 150 70 300 40 20 75 400 200 1,000 000 85 200 700 240 200 800 400 760 4.795 144 150 100 25 100 375 10 380 144 534 375 159 MAINTAINING SOIL FERTILITY 51 There is much less loss in the second system of farming than the first. The amounts of phosphoric acid and potash lost are very small and the loss of nitrogen is compensated for by that left in the soil by the legumes, peas and clover. From the foregoing data it is evident that the system of farm- ing determines the loss of fertility. CHAPTER IV. FARM MANUEES. Farm manure has been used for centuries in restoring fer- tility to the soil. It is the oldest and one of the most important of our fertilizers. It is formed from vegetable and animal sub- stances and naturally should prove of great value. In some sections of this country farm manure is wasted, but the value of this material is generally becoming better understood and is more carefully saved than formerly, especially in the older farm- ing regions. Kinds of Manure. — When there is a great deal of straw or hay in manure, it is said to be coarse. It is termed stable manure when it is accumulated in stables and contains all the solid and liquid portions. Barnyard manure is a name applied to manure which is subject to exposure of rains and sun and may be com- posed of pure solid excrement, or excrement and bedding. Conditions Affecting the Value of Manure. — There are many conditions which affect the value of manure. 1. The age of the animal. 2. The use of the animal. 3. The kind and amount of bedding used. 4. The kind of animal. 5. The nature and amount of feed used. 6. The care, preservation and use of the manure. 1. The age of the animal influences the value of manure. Ma- nure from young animals is not so rich in the fertilizer con- stituents, nitrogen, phosphoric acid and potash as that from mature animals, even when the same kind of feed is used. Young animals require and retain nitrogen and phosphoric acid for growth, while mature animals use these constituents for main- taining the functions of the body and for repairing broken down tissues, after which they are cast off in the manure. 2. The use of the animal influences the value of manure Lawes' and Gilbert's experiments along this line show :'' FARM MANURES 53 Nitrogen Mineral matter Contained in product Per cent. Contained in excrement Per cent. Contained in product Per cent, Contained in excrement Per cent, None None 24-5 3-9 14.7 4-3 lOO.O loo.o 7.S-0 tl 95-7 None None 10.3 2-3 4.0 3-8 }00 Milking cows Fattening oxen Fattening pigs Fattening sheep 89.7 97-7 96.0 96.2 Hall shows the nitrogen retained and digested by fattening oxen and milch cows. This table is calculated on feeding 100 pounds of linseed cake." In 100 lbs. linseed cake Fattening oxen Milch cows In meat In urine In faeces In milk In urine In faeces Nitrogen Phosphoric acid. 4-75 2.00 1.40 0.21 0.14 0.02 3.88 0.09 1. 10 0.66 1.77 0.28 1.32 0.50 0.14 2.75 0.07 1.05 0.66 1-43 It is shown that milch cows return less of the fertilizing con- Pig, 4. — Milch cows return less fertility from feeds than other farm animals. 54 SOIL KERTIIylTY AND l^ERTIUZERS stituents in the feed than other domestic farm animals. Fatten- ing pigs return less than fattening sheep and fattening sheep less than fattening oxen. Horses return the same relative amounts from the feed whether at work or at rest. 3. The Kind and Amount of Bedding Used. — Bedding besides affecting the value of manure renders stables more sanitary. It provides comfort for the animal, makes the manure lighter and easier to handle, absorbs the liquids, lessens fermentation and improves the texture of the manure. Straw is the most common bedding used and is well suited for this purpose, because it is largely made up of cellulose which is a good absorber, and on account of its hollow structure. The following table gives the composition of some of the principal straws. Kind Water Per cent. Ash Per cent. Organic matter Per cent. Nitrogen Per cent. Phosphoric acid Per cent. Potash Per cent. Wheat straw Oat straw Rye straw Barley straw 9.6 9.2 7-1 14.2 4.2 5-1 3-2 5-7 86.2 85.7 89.7 80.1 0.59 0.62 0.46 0.70 0.12 0.20 0.28 0.30 0.51 1.04 0.79 0.80 From the above it is shown that there is a difference in the composition of straws, but they all contain a high potash content. The nitrogen and phosphoric acid are rather low and when large amounts of straw are employed the fertilizing value of the manure is naturally lowered. Leaves. — Dried autumn leaves are often gathered and used as bedding. They are not as valuable as straw as they do not ferment very rapidly and are liable to cause acidity in the manure. Composition of Dried Leaves. Per cent. Nitrogen 0.65 Phosphoric acid o. 15 Potash 0.30 Sawdust is often used as bedding and it is much inferior to straw and dried leaves from a fertility standpoint. It decom- poses very slowly in the soil. However this material is a good FARM MANURES 55 absorber of the liquid portions and makes a good bedding when it can be obtained cheaply. Composition of Sawdust.'* Per cent. Nitrogen o-l Phosphoric acid o.2 Potash 0.4 Shavings are sometimes used as bedding and possess about the same properties as sawdust. Peat when dried is a good material to use in stables as it is an excellent absorber. It absorbs not only the liquid portions of the manure but also the nitrogen gases evolved, and renders the stable free from foul odor. It in itself contains considerable organic matter which is beneficial and it is readily fermented in the soil. It is a good material to use in conjunction with straw. The use of peat as bedding increases the nitrogen content of the manure. The nitrogen percentage in peat varies a great deal but it usually approximates i to 1.5 per cent. Absorptive Power of Bedding;. — ^According to Snyder/^ the ab- sorptive power of different kinds of bedding are : Per cent, of water absorbed Fine cut straw 30-0 Coarse uncut straw 18.0 Peat 60.0 Sawdust 450 Snyder^^ says : "The proportion of absorbents in manure ranges from a fifth to a third of the total weight of the manure." The following experiment shows the absorptive power of straw and peat in two similar stables carrying the same stock, in one of which straw was used and the other peat. Ammonia In Stable Per Million of Air.' Litter ist day 2d day 3d day 4th day 5th day 6th day 7th day 0.0012 0.0028 0.0045 0.0081 00153 trace 0.0168 o.oor Peat moss 0.017 4. The Kind of Manure. — Manure from different kinds of ani- mals varies in value. 56 SOII< FERTILITY AND FERTILIZERS Horse Manure. — The manure voided by the horse is rich in nitrogen and not so finely divided as the manure from cows, sheep, etc. This is due to the horse only having one compart- ment in its stomach and therefore the feed, especially coarse feed as hay, etc., is less broken up and digested. Horse manure is generally comparatively dry and hard to incorporate with bedding. On this account, and because of its coarse nature and chemical composition, fermentation readily sets in and con- siderable nitrogen is lost unless the fermentation is stopped. When fermentation is allowed to continue the value of horse manure is very much decreased. Boussingault found by experi- ment that when fermentation was allowed to continue, one-half of the nitrogen was lost from the fresh manure. The amount of manure produced by a horse per year is :^° Pounds Solids 12,000 Liquids 3,000 Boussingault and Hofmeister found, on the average, that 28.11 pounds of manure was produced daily by the horse. Heiden estimates that 4 to 6 pounds of straw should be used daily to absorb horse manure. Estimating the amount of straw at 5 pounds, the total weight of manure would approximate 6 tons for a year, or-* Pounds Solids 9,600 Liquids 2, 400 The above experiments show that a horse produces about 6 to 7.5 tons of manure per year in the stable, of which three- fourths are solids and one-fourth liquids. Composition of Horse Manure.'* Water Nitrogen Phosphoric acid Potash Solids Per cent. Liquids Per cent. Solids Per cent. Liquids. Per cent. Solids Per cent. Liquids Per cent. Solids Per cent. 84 92 0.30 0.86 0.25 0. 10 The liquid portion of hor.se manure contains a great deal more FARM MANURES 57 nitrogen that the solid. The liquid portion of horse manure contains very little phosphoric acid. Cow manure is much colder than horse manure and so a fine combination results when it is mixed with horse manure ; the f er- mention of the horse manure is stopped and the nitrogen saved, and the mixture is better than cow manure alone. Cow manure contains more water than horse manure due perhaps to the large amounts of water drank by this class of animal. Cow manure does not ferment rapidly and when dry decomposes very slowly in the soil. It is estimated that 6 to lo pounds of straw are necessary to absorb cow manure, depending upon the amount of liquids voided. The amount of manure produced by a cow per year is:^'' Pounds Solids 20,000 Liquids 8,000 Boussingault-' found that 73.23 pounds of manure was pro- duced by a cow per day. Of this amount about 25 pounds rep- resents the liquid portion. With bedding, the amount of manure produced per day would approximate 80 pounds. Composition of Cow Manure.'* Water Nitrogen Phosphoric acid Potash Solids Per cent. Liquids Per cent. Solids Per cent. Liquids Per cent. Solids Per cent. lyiquids Per cent. Solids Per cent. 76 89 0.50 1.2 0.35 0.30 The nitrogen content is present in greater amount in the liquids while there is little phosphoric acid present in this portion of cow manure. Hog Manure. — The composition of hog manure is quite variable depending upon the feed consumed. When tankage and other highly nitrogenous feeds are employed the manure is rich, but when feeds containing small amounts of fertilizing constituents are used, the manure is not so valuable. Hog manure contains a high percentage of water and is slow to decompose. It is es- 58 SOIL FBRTILITY AND FERTILIZERS timated that 4 to 8 pounds of straw are adequate for absorbing pig manure. The amount of manure produced by the hog per year is -P Pounds Solids 1,800 Liquids 1,200 Note the proportionately high liquid content of hog manure. Boussingault found by experiments that a hog produced 8.32 pounds of manure per day. Composition of Hog Manure." Water Nitrogen Phosphoric acid Potash Solids Per cent. I,iquids Per cent. Solids Per cent. I^iquids Per cent. Solids Per cent. Liquids Per cent. Solids Per cent. 80 97 0.60 0.80 0.45 0.12 0.50 The liquid portion of hog manure contains more phosphoric acid and the solids more potash than horse or cow manure. As previously mentioned, the nitrogen content of the liquid portion of hog manure depends upon the nature of the feed. Sometimes the nitrogen will reach 1.5 per cent, in the liquid portion. The liquid portion is higher in water than manure from other farm live-stock. Sheep Manure. — The manure from sheep is more valuable than that from other farm animals. On account of its being dry and rich in nitrogen it ferments rapidly although not so quickly as horse manure. The slower action is perhaps due to its more compact mechanical condition. Losses of nitrogen in sheep manure are apt to occur unless the manure is well taken care of. To absorb the liquid portion 3/5 of a pound of straw per day is sufficient per sheep. The amount of manure produced by a sheep per year is:^' Pounds Solids 760 Liquids 380 Heiden found that the average manure produced daily by sheep to be 3.78 pounds. FARM MANURES Composition of Sheep Manube." 59 Water Nitrogen Phosphoric acid Potash SoHds Per cent. Ifiquids Per cent. Solids Per cent. Liquids Per cent Solids Per cent. Liquids Per cent. Solids Per cent. 58 86.5 0.75 1-4 0.60 0.05 0.30 Both the solids and liquids of sheep manure run higher in nitrogen than the manure from other farm animals, and the water content is lower. The phosphoric acid content of the solids is also high and that of the liquids appreciable. Hen manure contains its nitrogen in a quickly available form and unless carefully preserved, fermentation sets in and drives off considerable of this valuable constituent as ammonia. Lime should not be used where the manure is kept as it hastens the liberation of ammonia. The per cent, of nitrogen in hen manure depends a great deal on the kind of feed consumed. Hens pro- duce, per 1,000 pounds live weight, about 35 pounds of manure per day, and about one bushel of manure is produced by a hen per year. Composition of Hen Manure. Per cent. Moisture 57.00 Nitrogen 1.3 Phosphoric acid 0.85 Potash 0.30 It is shown that hen manure approximates sheep manure in composition. It is a valuable manure because it acts quickly. Composition of Fowl Manure.'* Fowls Per cent. Pigeons Per cent. Ducks Per cent. Geese Per cent. Water Organic matter. Nitrogen Phosphoric acid Potash Lime Magnesia 56.00 25-50 1.60 1.5-2.00 0.80-.90 2.0-2.50 0-75 52.00 31.00 1-75 1.5-2.00 1-0-1.25 1.5-2.00 0.50 56.60 26.2cr 1. 00 1.40 0.62 1.70 0-35 77.10 13.40 0-55 0-54 0-95 0.84 0.20 6o SOIL FERTILITY AND FERTILIZERS A pigeon yields about 6 pounds of manure per year, a turkey or goose about 25 pounds, and a duck 18 pounds. Analyses of Bat Mandre.''* Insoluble phosphoric acid Per cent Total phosphoric acid Per cent Available phosphoric acid Per cent. Nitrogen Per cent. Potash Per cent. Texas . . Texas. . Texas ■ ■ Mexico o.io 0.12 0.13 0.24 2.65 2.98 2-43 4-73 2-55 2.86 2.30 4-49 8.64 8.65 5.81 8.76 2..'i9 1.80 I.7I 3-34 Average of Nine Analyses from Various Experiment Stations." Per cent. Total phosphoric acid 5.95 Nitrogen 8.50 Potash 1. 14 The following analyses of manures may prove interesting. Analyses of Farm Manures." Kind of manure Water Per cent. Nitrogen Per cent. Pota.sh Per cent. Phosphoric acid Per cent. Cattle (solid fresh excrement) 73-27 0.29 0.58 1.63 0.44 1-55 0-55 1-95 0.50 0.60 043 0.10 0.49 0.85 0-35 1.50 0.15 2.26 0.60 0.13 0.83 0.17 Hen manure (fresh) Horse (solid fresh excrement) 1-54 0.17 Sheep (solid fresh excrement) 0.31 01 0.30 0.41 0.07 Swine (solid fresh excrement) How to Calculate the Amount of Manure ProJuced. — A method used for determining the amount of manure produced by animals is to multiply the amount of dry matter in the feed consumed by 3.8 for a cow, 2.1 for a horse and 1.8 for a sheep. A horse that consumes feed containing 25 pounds of dry matter per day would void 25 X 2.1 = 52.5 pounds of manure a day. Add to this the amount of bedding used and you will arrive at the total amount of manure. The dry matter of the principal feeds FARM MANURES 6l found on the American market will be found in the Appendix. 5. The nature and amount of feed used afifects the value of the manure. The richer the feed the higher the fertilizing value of the manure. Coarse feeds like hay, straw, etc., produce less valuable manure than concentrated feeds like linseed meal, gluten meal, cotton-seed meal, etc. For the fertihzing value of feeds refer to the Appendix. Experiments were conducted at Rothamstead on the effect of the feed on the nitrogen content of the excrement, by feeding steers roots and hay and roots, hay and oil cake (a nitrogen concentrate). The results follow.' Composition of Farm Manure in Per Cent, from Roots and Hay Only, or from Roots and Hay and Cake. Roots and hay only Cake fed Roots and hay only Cake fed Roots and hay only Cake fed Roots and hay only Cake fed 1904 1904 1905 1905 1906 1906 1907 1907 qs 23.60 24.03 29.50 31-30 22.00 24.30 25-30 25-50 0-577 0.716 0.462 0.698 0.466 0.690 0.589 0.815 0.046 0.079 0.040 0.182 0.022 0.097 0.125 0.377 15 a 0.067 0.096 0.047 0.055 0.033 0.049 0.053 0.033 ,D Z s be 0.464 0.541 0.375 0.461 0.4II 0.544 0.4II 0.405 Mixed & stored Not stored It is seen that when steers were fed oil cake the manure was richer in nitrogen, by about 40 per cent., than when fed roots and hay alone. The nitrogen produced in the manure of those steers that were cake fed shows a higher availability. The manure produced in these experiments was applied to the soil with the following crop returns." Crop Returns from the Above Manures. Unmanured plot 16 tons per acre root and hay manure- 16 tons per acre cake fed manure Year of Application Mean of 4 100 132 183 Second Year Third Year Mean of 4 Mean of 3 100 131 137 100 112 118 62 SOIL FERTILITY AND FERTILIZERS The unmanured plot was taken as lOO. The crops grown were turnips, barley, mangolds and wheat in rotation^ and the manure was applied for one year. The availability of the nitrogen pro- duced by feeding cake is evidenced by the yield of the first year when the manure was applied. The yields of the second and third years are not much more than from the root and hay ma- nure. Commercial Value of Manure. — The commercial value of manure only represents the value from the standpoint of its plant food constituents nitrogen, phosphoric acid and potash. The nitrogen is valued at 15 cents per pound, the phosphoric acid at 6 cents and the potash at 4j4 cents. There is no litter in these manures.^' Percentage Pounds ingredients c Productoin per 1,000 pounds n Composition per ton manure live weight •c » J. a s. .5 g «5 I1 V 1 t •a.-2 1 1 tl CO s ^ -a « is ti.a CLi Z CLi.!j a. B. p. > P. Horses . . 48.70 0.49 0.26 0.48 9.00 5.20 9.60 $2.21 48.8 |27-74 Cows 75-25 0.43 0.29 0.44 8.60 5.80 8.80 2.02 74.1 29.27 Calves... 77-73 0.50 0.17 0.53 lo.oo 3-40 10.60 2.18 67.8 24-25 Swine . . . 74-13 0.84 0-39 0.32 16.80 7.80 6.40 3-29 83.6 60.88 Sheep . . . 5952 0.77 0-59 15.40 7.60 11.80 3-30 34.1 26.09 The table shows sheep manure to be the most valuable per ton and cow manure the least valuable. The commercial value ranges from $2.02 to $3.30 per ton. It must be remembered that these values do not represent the agricultural value (the power to produce crops) or the beneficfal effect it produces on the soil. Lastii^ Effect of Manure. — The lasting effect of manure is shown by the experiments conducted at Rothamstead. A plot of grass land received applications of 14 tons of manure per acre for 8 consecutive years and then the applications were discon- tinued. During the first year after the discontinuance of manure the yield was twice that of an unmanured plot. Since that time the yield on the manured plot has slowly decreased until at the end of 40 years the excess has been about 15 per cent, greater than the yield of the unmanured plot. FARM MANURES 63 An experiment was conducted with barley. Three plots were employed. One plot received 14 tons of manure per acre since 1852, another received 14 tons of manure per acre for 20 years and then the applications were stopped, and the third has been unmanured since 1852. ' The following table gives the results of this experiment.' ToTAi< Produce Per: Acre of Barlev Plots, Showing IvAsting Effect OF Manure. 2" " s s ■a >. ztr 5^1 Relation to Produce of Plot 7-2, 3 ca g 1 il reckoned as 100 S « p Plot 7-2 Plot 7-1 Plot I-O Plot 7-2 Plot 7-1 Plot I-O Mean lb. lb. lb. lb. lb. lb. I852-I87I 5-933 2,454 100 41 1872 1873 1,282 1,570 25 24 5 ,202 4-870 100 94 1874 6,561 5.165 1,922 ICO 79 24 1875 7-943 5.675 1,448 100 71 25 1876 5-825 3.955 i,56i 100 68 25 6,166 4,010 100 65 Mean 1877-1881 6,167 3>305 1.528 100 54 25 1882-1886 6,546 3.494 1.529 100 53 23 1887-189 1 5.334 2,664 1.379 100 50 26 1892-1896 6-477 3.101 1,508 JOG 48 23 1897-I90I 5,349 2,251 1,141 100 42 21 1 902-1906 6,223 2,485 1.301 100 40 21 The above experiment shows that the continuously manured plot has the largest yields but the plot that was manured for 20 years is still producing crops at least 40 per cent, greater than the unmanured plot. The results as shown in these experiments would not be found to be so apparent in actual farming, as the soils that were used for these experiments were more exhausted than the farmer would use. However, the results are interesting as they show the almost permanent effect of farm manure on soils. OJ. SOIL FERTILITY AND FERTILIZERS 6. The Care, Preservation and Use of Manure. — From the fore- going pages it is very evident that the composition of manure and the amounts produced by different kinds of animals are ex- ceedingly variable. It was also shown that a regular value for this product cannot be estimated from its chemical composition. Waste of Manure. — In some sections of the United States farm manure is dumped into streams, burned, buried in holes in the ground, or allowed to remain in large piles in some uncultivated place. The soils in many of such sections are fertile enough to produce profitable crops but it seems very wasteful to throw away such valuable fertilizer. Leaching. — When a manure heap is exposed to the washing of rain and the solutions allowed to wash away, the value of the manure is decreased. The soluble plant food elements are washed away together with more or less of the manure itself. Leach- ing is one of the most important subjects to consider in the care and preservation of manure because it is the source of one of the greatest losses in this valuable product. Roberts^^ shows the great losses that may occur by leaching. He experimented with horse manure by allowing it to remain in a loose pile out of doors exposed to the rain from March 30th to Sept. 30th. The rainfall averaged about 28 inches during this period. The composition of the manure at the beginning and at the end of the experiment follow : April 25 Pounds Sept. 30 Pounds l,oss Per cent. Gross weight... Nitrogen Phosphoric acid Potash 4,000.00 19.60 14.80 36.00 1,730.00 7-79 7-79 8.65 57 60 47 76 An experiment was conducted with cow manure at the same time under the same conditions except that 300 pounds of gypsum were mixed with it. FARM MANURES 65 A.pril 25 Pounds Sept. 30 Pounds I^oss Per cent. Gross weight Nitrogen Phosphoric acid Potash 10,000.00 47.00 32.00 48.00 5.125-00 28.00 26.00 44.00 49 41 19 8 It is shown that the cow manure did not leach so readily as the horse manure. The gypsum no doubt held back some of the nitrogen but even without the use of gypsum the loss would be less than from horse manure because cow manure is more firm and compact. The greater loss from the horse manure may also have been due to its more rapid fermentation, thus releasing con- siderable nitrogen as ammonia gas. Roberts-' also experimented with a mixture of horse and cow manure and straw, which was compacted by trampling of cattle in a covered shed, and put in a galvanized iron pan with a per- forated bottom, for six months. The losses were as follows : March 29 Pounds Sept. 30 Pounds Loss Per cent. Gross weight Nitrogen Phosphoric acid Potash 226.00 1.04 0.61 1.20 222.00 1. 01 0.58 0.43 3-2 4-7 35-0 The results in this last table show considerably less loss than when manure was not mixed or not compacted. The decrease in loss of nitrogen is greatest in the mixed tramped manure and this is due to the fact that fermentation was checked by mix- ing and tramping and therefore there was less loss of nitrogen as ammonia gas. Fermentations. — There are certain bacteria that produce fer- mentations in manure piles and liberate nitrogen as gas causing large losses in manure. These fermentations are brougfit about by two classes of organisms; aerobic bacteria and anaerobic bacteria. I. The aerobic bacteria require oxygen to be active and the anaerobic bacteria are only active in the absence of oxygen. On the outside of manure heaps where air circulates, the aerobic 66 SOIL FERTILITY AND FERTILIZERS bacteria work while in the interior of the heaps where no air can penetrate the anaerobic fermentation takes place. The aerobic bacteria convert the nitrogen present in the organic matter of the manure, into ammonia, in which form it passes off into the atmosphere. Because of the great amount of carbon dioxide formed during the action some of the ammonia is converted into carbonate of ammonia which is also volatile. 2. The anaerobic bacteria convert ammonia salts to nitrogen. Some of these bacteria have the power of reducing nitrates to nitrites, and to ammonia. The anaerobic bacteria do not bring about such losses as the aerobic bacteria, so it is important to keep the manure heap well compacted to prevent the action of the aerobic organisms. Keep the Manure Moist. — Dry manure ferments more readily than wet manure. To prevent active fermentation the manure heap should be kept moist. It is not necessary to add enough water to leach it. Water excludes the air and promotes anaerobic action which is beneficial. Composition of the Gases Formed in Manure Heaps. — The fol- lowing table is interesting as it shows the composition of the gases in manure heaps.^' Date 1899 Height of manure heap in meters^ Point at which samples were taken i s V °c ■2 K '■5 a 1 s 1 i Aug. 22 Aug. 23 Aug. 24 Aug. 26 Aug. 30 Sept. 20 Oct.4 2.00 2.00 2.30 2.30 2.50 2.50 2.50 middle middle f top \ middle (. bottom bottom ■j middle I bottom f top ] m ddle I bottom ■j middle i bottom 52 52 71 67 60 60 60 66 6s .52 65 40 54.3 58.0 50.0 68.0 49.0 51.0 7.2 14.5 50.8 42.7 49-5 47.8 54-0 42.7 48.3 0.00 7.0 4.7 0.0 l.I 0-5 7.8 14.2 17.4 23-9 40.8 46.6 0.0 1-3 49.2 52-4 48.3 512 43-0 56.1 51-7 3-1 7-4 3-9 2.4 14.4 16.0 29-5 0.7 6.0 0.0 85.8 79-5 0.0 9.8 2.2 I.O 2.0 0.0 0.0 1 A meter is equal to 39.37 inches. FARM MANURES 6? Sample of August 22d was taken when the manure heap was being formed and was too dry. Liquid manure was sprinkled over the manure on August 22d, after the sample was taken, which increased the fermentation as evidenced by the tempera- tures on August 24th. The evolution of hydrogen decreased during the process of fermentation and the marsh gas increased. By August 30th the manure heap was again too dry and the top and middle portions were full of air as is shown by the large amounts of nitrogen, presence of oxygen, and low content of car- bon dioxide. Such a condition, with the high temperature favored a loss of nitrogen as ammonia gas. When samples of Sept. 20th and Oct. 4th were taken the manure heap was moist and compacted, and the results show an anaerobic fermentation as is evidenced by the absence of hydrogen gas and the presence of almost equal amounts of carbon dioxide and marsh gas. The temperature in fermenting horse, sheep and poultry ma- nure often goes higher than 150° Fahrenheit (65° Centigrade). The highest temperature is usually near the surface as the fer- mentation is most active there. Composting manure is helpful in increasing the availability of the plant food. It also kills many weed seeds. There is less loss of plant food when the manure is applied to the soil fresh, than when allowed to rot. It is not generally convenient to haul the manure from the stable to the land as other work is of more importance, so that the manure has to be stored until the regular farm work becomes slack. When manure is composted it should be kept compact and moist and the heap should be shaped to shed water. A layer of earth on the top of the manure compost will tend to absorb some of the gases. Voelcker" gives the following as the composition of fresh and rotted manure. Water Soluble organic matter Soluble organic nitrogen . . . Soluble inorganic matter. . . Insoluble organic matter. . . I nsol uble inorganic matter. Fresh Rotted Per cent. Per cent. 66.17 75-42 2.48 3-71 015 0.30 1-54 1-47 25-76 12.82 4.05 6.58 6 68 soil, FERTILITY AND FERTILIZERS It is seen that manure that is composted contains the fertiHzer elements in a more available form than in fresh manure. The organic matter is decreased by allowing manure to rot. Snyder^* says: "A ton of composted manure is obtained from 2,800 pounds of stable manure." There are of course some losses of nitrogen in composting manure, the extent of these losses de- pending upon the compactness and dryness of the manure. The principal benefits derived from composting manure are ; the improvement of the physical condition, and decomposition takes place in the manure that ordinarily would have to be per- formed in the soil. Sometimes manure is composted with earth, sod, leaves and wastes from the farm. Store Manure Under Cover. — Whenever manure is left out of doors exposed to the rain losses occur. Many farmers preserve manure in different ways. Some use covered yards where the stock are allowed to exercise and the manure is kept compact by the tramping of the animals. In this practice bedding should be used to absorb all of the liquids and to allow the animals to be comfortable. The site should be well drained and kept dry. The manure from sheep, hogs, young stock, etc., is often pre- served in this way. Some farmers keep the manure in cellars under the stable. The fermentation of manure in the cellar of a stable is liable to produce foul odors and is especially ob- jectionable in dairy barns. Another method of storing manure that is used in the older farming sections, especially in dairies, is to build covered cement pits just outside the barn and dump the manure from trucks. The Uquid portions are drained to these pits by pipes. It may not always be possible for a farmer to build a covered cement pit but he can always afford to put a roof over the manure, for the cost of the shed will soon be returned in the increased value of the manure. The following table, the work of Biernatski, shows the com- position of uncovered and covered manure. FARM MANURES 69 Water Per cent. Nitrogen Per cent. Phosphoric acid Per cent. Potash Per cent. Uncovered manure Covered manure 83.78 76.54 0.47 0.68 0.26 0.31 0.43 0.76 Preservatives. — In the destruction of the nitrogen present in organic matter in manure, the aerobic bacteria produce ammonia and some of this gas unites with the carbon dioxide evolved and forms ammonium carbonate, a volatile compound. By adding moist gypsum (land plaster) to manure, the ammonium carbonate is converted into ammonium sulphate, a compound that does not pass away in the atmosphere. This latter compound is soluble in water and when manure is exposed to the leaching of rains, it is useless to employ gypsum. Gypsum is perfectly safe to use because it does not injure the feet of animals. Lime is objec- tionable because it liberates ammonia. Kainit, superphosphate and ground rock phosphate are sometimes used with good suc- cess, as they absorb nitrogen. These preservatives may be scat- tered at the rate of about one pound to an animal. They may also be economically used in covered manure heaps. Hall" es- timates that it will take about 100 pounds of gypsum per ton of manure to absorb the gases, as some of it is acted upon by the potassium carbonate in the urine. Physical Effects of Manure. — Manure has a greater value than is represented by its chemical composition. It improves the phy- sical condition of the soil by, 1. Producing a better moisture condition. 2. Producing a better texture. 3. Preventing mechanical losses by winds. 4. Benefiting grass land. I. Manure Produces a Better Moisture Condition. — Manure when added to soils increases the water holding power of those soils because of its humus content. Humus absorbs water readily. A soil that has had manure added to it will resist drought better 70 SOIL FERTII(ITY AND FERTILIZERS than one where there is little or no humus. During a heavy rainfall the soil with humus will absorb a great deal more water and give it up more gradually than one without humus. This is shown in the following table.® Percentages of Water in Unmanured and Manured Soils. Depth in inches Wheat field Barley field Unmanured Manured Unmanured Manured i6.o 19.8 23-3 19-3 17.0 18.4 17.0 22.5 22.1 20.7 17.7 18.3 8 to l8 l8 to 27 The wheat field samples were taken in September a day after a rainfall of 0.262 inches, but no rain had fallen for nine days previous. The plots where the samples were taken were fal- lowed so that the drying effect of the crop did not effect the results. The samples from the barley plot were taken a little over two weeks after the wheat plot samples. Three days before the barley samples were taken there was a rainfall of 0.456 inches, previous to which time there were 15 days of dry weather. The results are calculated on the percentages of fine earth after the stones were removed. The manured soil of the wheat and barley plots shows that the surface soil contains more water than the subsoil. There is about 3.5 per cent, more water in the surface soil than in the subsoil, which approximates 30 tons per acre or about 0.3 inch of rain. The loss between what was re- tained in the surface soil and the rainfall is due to evaporation. The unmanured soils show that the water percolated through to the subsoil. There were drains below the center of the wheat plots at a depth of 30 inches. The drain below the manured plot rarely contained water except after exceedingly heavy rain, while the drain below the unmanured plot contained water much more frequently. Effect of Manure During Dry Seasons. — Manure helps to con- serve the moisture supply of soil during dry seasons. The fol- lowing table is the work of the Rothamstead Experiment Station. FARM MANURES 71 Effect of Farm Manure in Dry and Wet Seasons with Wheat.' Rainfall in inches March to June Growing Season Yield Average 51 years Plot ; Fertilizer 1879 1893 1879 1893 1879 1893 13 2.9 Wet and Cold Dry and Hot Bushels Bushels 16.00 16.25 34-25 20.25 35.7 32-9 7 Complete fertilizer. The yield during the dry season of 1893 shows an excess of 14 bushels in favor of the manured plot, while the exceptionally wet year shows equal small yields from both plots. The small yield was due probably to the inactivity of the bacteria that make plant food available. For 51 years there has averaged a yield of about 3 bushels more on the manured plot than on the plot which received artificial fertilizer. 2. Manure Improves the Texture of the Soil. — Manure has a very beneficial effect on most soils in improving the texture. The addition of manure to sandy soils makes them more binding and increases their water holding capacity. Clay soils are made more porous by the addition of manure. Some soils may pro- duce good crops during favorable seasons without much organic matter but when the season is bad it is almost impossible to get the soil in good mechanical condition for crops. Number of Mangold Plants Taking 100 as the Possible.' Average pf 7 Years, T901-7. Farm Manure, Minerals and Nitrate of Soda Minerals and Nitrate of Soda Minerals and Rape Cake 69 62 83 * Hall, Fertilizers and Manure. The plot receiving rape cake, which was applied at the rate of 2,000 pounds per year, shows the best results, but rape cake like manure supplies a great deal of organic matter. A better stand was produced with farm manure than with the artificial fer- tilizer. 72 SOIL FERTILITY AND FERTILIZERS 3. Manure Prevents Mechanical Losses by Winds, — The losses occasioned by heavy winds on certain soils are sometimes more than one would expect. Dry light soils devoid of organic matter are easily blown away by heavy winds. The addition of manure to such soils tends to keep them moist and prevents such loss. 4. Manure Benefits Grass Land. — Manure benefits grass land not only by supplying plant food and increasing the moisture holding capacity, but also in protecting this crop from the frosts of early spring, by the mulch produced. It is noticed that grass that has been manured in the fall has an earlier growth in the spring than such lands unmanured Bacteriological Effects of Manure. — Manure when added to the soil aids the growth of bacteria that render plant food available. It also increases the number of these bacteria and supplies food for them, and fermentations are promoted that are very helpful in the production of crops. Time to Apply Manure. — In order to get all the value from farm manure it is better to apply it while fresh than when rotted. Manure in rotting loses some of its fertility. The Ohio Experi- ment Station have conducted experiments with fresh manure and exposed yard manure with the following crop returns for ten years. Amount ap- plied per acre in tons Yield of corn per acre bushels Yield of wheat per acre bushels Yield of hay per acre lbs. Bxposed yard manure • 8 8 16.03 22.24 8.21 9-73 698 I 280 The manure was applied to clover sod which was plowed under and followed by a three year rotation of corn, wheat an^ clover without the addition of any more manure. The yields favor the fresh manure with an increase of 6.21 bushels of corn, 1.52 bush- els of wheat and 582 pounds of hay. Sometimes it is not practicable to apply manure while fresh as some crops, especially the quick growing market garden crops. FARM MANURES 73 require plant food that is available and so prefer rotted manure. It is common in this country to apply fresh manure to gratis land in the fall and turn it under in the spring. This practice is beneficial in that it supplies a great deal of organic matter for the succeeding crop. Corn is a crop that thrives on fresh manure and so it is well to apply manure in this condition to corn and follow this crop with one that prefers rotted manure. Amount of Manure to Apply. — The amount of manure to apply depends upon the fertility and texture of the soil. Soils that already have considerable fertility sometimes require a light ap- plication of manure to improve their texture. Large applica- tions of manure on such soils would not be profitable. Most farmers use too much manure on their land at one time. Fre- quent light applications are more beneficial than large amounts applied at long intervals, as they keep the soil in an even state of fertility and losses of volatilization of nitrogen as gases and leaching of the soluble elements are less. Experiments show that small applications give greater percentage increase than large ap- plications, although large applications give larger yields. Sometimes manure does not furnish sufficient plant food to satisfy the needs of the crop. An addition of some commercial fertilizer which supplies the necessary fertilizer constituents is beneficial in such cases to supplement the manure. How to Apply Manure. — It is best to spread the manure over the land as it is hauled. Some farmers dump the manure in little piles over the field and leave it in this condition for two or three months. When fermentations take place in these piles nitrogen passes off in the air. This practice is objectionable be- cause the soil under and around the piles gets most of the avail- able plant food that is leached out, and the other soil does not receive its share. The result is that the succeeding crops grow uneven or in patches. There is no objection to dumping manure in small piles over the field if it is spread immediately The hauling of manure to the field and hand spreading it is perhaps the common method used in this country. It is difficult to spread manure evenly in this way and after the manure is distributed. 74 SOIL FERTILITY AND FERTILIZERS a brush drag should be used to scatter it more evenly. Manure spreaders distribute manure more evenly than any of the other methods in use. They are labor saving machines and although they usually carry less per unit of draft, they are considered a good investment for those who have much manure to spread. A ton of manure spread uniformly gives better results than a larger amount applied unevenly. CHAPTER V. HIGH GRADE NITROGENOUS FERTILIZER MATERIALS. Nitrogen is the most important element to consider in the study of fertilizers. It is the most expensive and most fugitive of the essential elements. Nitrogen usually costs about three times as much as phosphoric acid or potash. To be in a form available as plant food it must be as nitrates which are readily soluble in wrater. The air is made up of nitrogen, carbon and oxygen and although plants utilize the carbon and oxygen most of them do not seem to be able to use the nitrogen. There is one class of plants, the legumes (peas, beans, peanuts, alfalfa, clover, etc.) of which we have spoken, that can utilize this ele- mentary nitrogen but most of our other plants do not possess this power. The organic matter, which is made up of animal and vegetable matter, serves as a source of nitrogen, but plants can- not use it in this form. It is understood then that there is plenty of unusable nitrogen in the air and in soils rich in organic matter, but it has no direct plant food value in these forms until it is prepared by electrical means, oxidized and acted upon by certain bacteria. Forms of Nitrogen. — Nitrogen exists in different forms in the many substances containing it. Not including the nitrogen in the air we may classify these forms into four groups, namely : 1. Organic nitrogen, which is found in vegetable and animal substances, generally as protein. 2. Ammonia nitrogen, which is found in ammonium sulphate. 3. Nitrate nitrogen, which is found in nitrate of soda (Chile saltpeter) and nitrate of potash. 4. Cyanamid nitrogen, which is taken from the air by electrical means and combined with calcium, carbon, etc. Of these four forms all are soluble in water except organic nitrogen. The organic form is included in many substances, both animal and vegetable, while the remaining forms are found principally in a few products. 76 SOIL FERTILITY AND FERTILIZERS The Meaning of the Form of Nitrogen. — The fertilizer materials furnishing nitrogen contain this element in different forms. We have said that the substances containing nitrate nitrogen, am- monia nitrogen and cyanamid nitrogen are soluble in water and the organic nitrogen is insoluble in water. The nitrogen as ni- trates is always the same and of equal value no matter from what substance it is derived. The ammonia nitrogen is also of equal value and equal quantities of it are as good no matter what material it comes from. The soluble nitrogen from ammonium sulphate, however, is not the same as the soluble nitrogen from nitrate of soda and the insoluble nitrogen of organic materials is not the same or of equal value. Therefore the source of solu- ble and insoluble nitrogen makes a difference in value of the forms of nitrogen. The solubility of nitrogenous substances influences the availability, or the rate with which the nitrogen in a suitable form is supplied so that the plant can assimilate it, to some extent. The organic form of nitrogen is so called because the nitrogen is combined with other elements as hydrogen, carbon and oxygen in organic matter. Organic nitrogen is different in the various substances. Some animal and vegetable materials are quite rich in nitrogen while others do not contain much and are perhaps not so valuable. Some organic substances may contain consider- able amounts of nitrogen but in such a locked-up state that they are undesirable as plant food. When a substance gives up its nitrogen as nitrates readily we say that the nitrogen is in a form that is active ; it is quick acting, quickly available, readily assimilated, etc. When the nitrogen is locked-up we use the terms slow acting, slowly available, etc. There are many degrees of availability of the different forms of nitrogen and they range from the very quick acting of the solu- ble materials to the organic materials that may take two or three years or even longer before they give up their nitrogen for plants to us€ as food. There are many organic substances that contain nitrogen, but in such small amounts, or in such a locked-up con- dition that they cannot be used profitably in the manufacture of fertilizers. The principal sources of organic nitrogen will now be discussed. HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 77 The Vegetable Substances. Cotton-seed meal is one of the most important sources of vege- table nitrogen. It is usually a bright yellow product with a nutty odor when fresh. Attached'^ to the seed of cotton are long white fibers, or lint, known to us as cotton. When cotton is ginned most all of these fi- bers are removed, but a few short fibers always adhere to the seeds. The seeds are then taken to a cotton-seed oil mill and treated as Fig. 5.— A cotton gin. follows : First, the greater part of the short fibers are removed from the seed by a second ginning in a machine called the de- linter. The seed is composed of the hull, or hard outer brownish black covering, and the kernel or meat. The seeds are then put in a machine called the huller which separates the hulls from the seeds. This process is called decorticating the seed. The whole mass (hulls and meats) is now subjected to a separating process by shaking in a revolving screen, the meats passing through the perforations of the screen. The hulls obtained in this process are known as cotton-seed hulls. The meats are conveyed from 78 soil, FDRTIUTY AND FERTILIZERS the shaker to special steam- jacketed covered kettles and cooked. The cooked meats are transferred to a machine, called the cake former, where they are made up into cakes or forms of the proper size to fit the hydraulic press, and wrapped with camel's- hair cloth. These hot forms are now subjected to enormous pressure in a hydraulic press and the oil is removed. The re- maining product is ground and sold as cotton-seed meal, although a great deal of it is shipped to foreign countries without being ground. For the year 1908, 929,287,467 pounds of cotton-seed meal were manufactured in the United States.-' Yields of Products prom a Ton of Cotton-Seed. '° Linters 23 pounds Hulls 943 Crude oil (37.6 gals. ) 282 Cake or meal 713 Waste 39 Total 2,000 Composition of Cotton-Seed Meal. — The composition of cotton- seed meal varies a great deal. When it is not adulterated with hulls the variation in composition may be due to the season, the nature of the soil and the climate. Seed raised on high land is usually richer in nitrogen than seed raised on low land. The Texas meals seem to run high in nitrogen. In the past few years many of the manufacturers have been introducing ground cotton- seed hulls into their meal which of course lowers the value of this product. Cotton-seed meal is in great demand as feed for live-stock and the bright yellow meals are used for this purpose. The darker meals are not so valuable as feed and are usually sold for fertilizer. The dark color may be due to over-cooking, to fermentation, or to storing in a wet or damp place. If there is no loss of nitrogen, the product is not injured for fertilizing purposes. Commercial Classification. — The Inter-State Cotton-Seed Crush- ers' Association, which is made up of gentlemen dealing or in- terested in cotton-seed products, uses the following as a standard classification for cotton-seed meal : HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 79 Choice cotton-seed meal must contain by analysis 8 per cent, ammonia, which is equivalent to 6.58 per cent, nitrogen. Prime cotton-seed meal must contain by analysis 7.50 per cent, ammonia, which is equivalent to 6.17 per cent, nitrogen. Good cotton-seed meal must contain by analysis 7 per cent, ammonia, which is equivalent to 5.76 per cent, nitrogen. Most of the meal is sold on an 8 per cent, ammonia basis. It also contains about 1.5 per cent, pota.sh and 2.8 per cent, phos- phoric acid. Value of Cotton-Seed Meal. — Large quantities of this product are used in the South where it is especially suitable for the long growing crops as it suppHes plant food during the whole season. An insect, called the boll weevil, is reducing the acreage and yield of this crop. If the entomologists do not find a way of checking this pest the use of cotton-seed meal will be much less in the future. A physical examination will not always indicate its fertilizing value. Many of the meals have the hulls so finely ground that it is impossible to detect the extent of their presence with the naked eye. The color of a meal is not always an indication of its nitrogen content. Always purchase cotton-seed meal under a strict guarantee as this product is variable in composition and a physical examination of it does not show its fertilizing value. linseed meal is another vegetable compound used for fertilizing purposes. It is a by-product in the manufacture of oil from flaxseed. There are two classes of linseed meal, namely, the old and new process meal. The old process meal is obtained by pressing out the oil from the cold or warmed crushed flaxseeds. In the new process the oil is extracted with naphtha and the naphtha driven off by steam. The old process and new process meal average about 5.3 per cent, nitrogen, 1.25 per cent, potash and 1.6 per cent, phosphoric acid. Linseed meal is not used ex- tensively as fertilizer because of the high price it commands as feed for live-stock. Castor pomace is the remaining product from the extraction of oil from the castor bean. It is poisonous to live-stock and 8o SOIL FERTILITY AND FERTILIZERS therefore is used for fertilizer. It averages about 5.5 per cent, nitrogen, 1.8 per cent, phosphoric acid and i per cent, potash. As it decomposes rapidly in the soil it makes an excellent fertilizer' Rape meal is the ground product left after the expression or extraction of oil from rape seed. This product is not used much in the United States but as the cultivation of rape is increasing it was thought best to mention it. The high grade rape meal is usually fed for live-stock, but the lower grades, which contain weed seeds and impurities, are sometimes objectionable as feed but are valuable for fertilizer. Rape meal runs about 5 per cent, nitrogen and 1.6 per cent, phosphoric acid. The Chief Animal Substances. Dried blood is obtained from the large packing houses of the United States. There are two kinds on the market, namely, red and black blood. The red blood is obtained by drying blood very carefully with superheated steam and hot air. Should the blood be dried at too high a temperature it chars and turns black. If the blood is injured in any way it is sold as black blood. Red blood averages about 13.5 per cent, nitrogen with traces of phos- phoric acid while black blood is a more variable product but usually contains 12 per cent, nitrogen and i to 3 per cent, phos- phoric acid, depending upon the nature of the impurities. When bone is present the product contains sometimes as high as 4 per cent, phosphoric acid. Red blood is not used much for fer- tilizer because it commands too high a price for other purposes. Both red and black blood are ground and sold in a powdery condition. Black blood is a very valuable nitrogenous fertiUzer which is in great demand and is very popular with the manufac- turers of fertilizers in satisfying their formulas. It is one of the principal organic fertilizers used by manufacturers in the North. It is not used directly to any extent by farmers as the manufacturers purchase most of it. It is in a fine mechanical condition and is easy to mix with other materials. As plant food it gives excellent results as it decays very rapidly thus furnishing nourishment during the early stages of the growing period. HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 8 1 Sometimes salt and slaked lime are put in blood. It is very high in availabiUty being somewhat quicker than cotton-seed meal. Tankage is composed entirely of animal matter. It is the ref- use from slaughter houses and consists of meat, bone, etc. (from which the fat has been extracted) and more or less dried blood. Animals condemned as unsuitable for food are made into tankage. The phosphoric acid in tankage is slowly available as it is supplied principally by ground bone. The nitrogen is derived principally from meat and blood. When the percentage of bone is large, the phosphoric acid is high, and the nitrogen content is low, and when there is an excess of blood and meat, the nitrogen is high and the phosphoric acid low. Grades of Tankage. — There are several grades of tankage on our markets. The most popular nitrogenous grades are those containing 8, 9, and 10 per cent, ammonia which are equivalent to 6.58, 7.41, and 8.23 per cent, nitrogen, and 6.56, 7.64, 10, and 12 per cent, bone phosphate of lime, which are equivalent to 3; 3-5. 4-58, and 5.5 per cent, phosphoric acid. There are many other grades of tankage sold that carry more phosphoric acid and less nitrogen, but these are classed as bone tankages and will be later described under phosphates. Concentrated tankage is still another grade arid the richest of all since it contains more nitrogen and is a more uniform product. It is made by evaporating wastes that contain animal matter in solution, or in other words the tank water. It usually contains 10 to 12 per cent, nitrogen and small amounts of phosphoric acid. Variation in Tankage. — Because of the great variation in the chemical composition of tankage (no two shipments hardly ever run alike, for the manufacturers cannot seem to control the com- position of their output on account of the variation in the by- products), great care must be exercised in purchasing. The product should be bought on its chemical composition and not necessarily on its guarantee, for it may or may not reach its stated composition. Hoof meal and hair are sometimes present in shipments of tankage. For sugar-cane, cotton-seed meal has been found to be more valuable than tankage of the same nitrogen content. Nevertheless, tankage is a valuable fertilizer and its 82 SOII< FERTIUTY AND FERTIUZERS value depends a great deal on its nitrogen content. It is suitable for crops having a long growing season. About 1,000,000 tons of tankage and dried blood are produced annually. Azotin, meat meal, flesh meal, dried meat, animal matter and ammonite are practically the same product, but are by-products from different manufacturing establishments. Most of tfiis prod- uct comes from the slaughtering houses and beef extract facto- ries. It is a rich organic fertilizer containing about 13 per cent, nitrogen, but it may run higher or lower than this depending upon its purity. This product is made up generally of the flesh refuse of dead animals from which the fat has been extracted and the remains dried and ground. It is different from tankage because it does not contain bones. Steamed horn and hoof meal averages about 12 to 15 per cent, nitrogen and is principally marketed by the large packing houses. The choice horns and hoofs are sold for the manufacture of but- tons, combs, and novelties, and the imperfect and off-colored horns and hoofs are treated with steam, under high pressure, which renders the nitrogen more available and permits of the prod- uct being ground to a fine powder. Horn and hoof meal was not formerly thought much of, but since it has been subjected to superheated steam the product has been much sought after by the manufacturers of fertilizers. It is produced only in limited quantities and is not as valuable as dried blood, but has a fairly high degree of availability, according to recent investigations. There is another method used in treating horns and hoofs, which consists of subjecting these materials to a dry heat, in a machine called the dryer, until they are brittle enough to pul- verize or grind. Production of Fertilizers by Packing Houses. — In 1905 the pro- duction of fertilizer by all the packing house concerns in the United States amounted to 211,137 tons. The animals slaught- ered were 7,147.735 beeves, 10,875,339 sheep, 30,977,639 hogs, and 1,568.130 calves, or about Syi pounds of fertilizer were obtained for each animal.^ HIGH GRADE NITROGENOUS FERTIEIZER MATERIALS 83 Dry Ground rish. — This is also called fish scrap and fish guano and has a yellow color. It is obtained principally from canning factories where the refuse as bones, skin, heads, fins, tails, intes- tines, etc., of edible fish are saved, dried and ground. Estabhsh- ments expressing oil and manufacturing glue from inedible fish as Menhaden, furnish a considerable supply. The average annual catch of Menhaden is about 600,000,000 fish, which produce 70,- 000 tons of fish scrap and 35,000 barrels of oil. Thirty factories with 70 steamers are engaged in this industry, and the largest catch was in 1903 when 1,000,000,000 fish were caught.'^ The whale bone interests, after the bones are removed and the oil extracted from whales, utilize the remainder in the preparation of dry ground fish. Dried ground fish is variable in composition depending upon the nature of the materials of which it is made. The greater the percentage of bone, the higher is the phosphoric acid content and the lower the nitrogen, and the less bone, the higher the nitrogen and the lower the phosphoric acid. The amount of oil left also influences the composition. It usually ranges from 7.5 to 10.5 per cent, nitrogen, 5.7 to 16 per cent, phosphoric acid, with an average of 8.5 per cent, nitrogen and 9 per cent, phos- phoric acid. It is a popular and valuable fertilizer and large quantities are used in the North. Most sections of the South are too far away from where it is manufactured to prevent u.sing it at its market value. Dry ground fish is readily decomposed in the soil and is therefore quick acting. It is not considered as valuable as dried blood. Sing crab is obtained on the Atlantic coast and is dried and ground, in which state it is utilized by fertilizer manufacturers. It contains about 10 per cent, nitrogen and is similar to dried ground fish in fertilizer properties. Guano, or natural guano, is another important source of nitro- gen. It was used as early as the 12th century in Peru. On the west coast of South America there are thousands of sea fowl. These birds have roosting and breeding places along the unin- habited portions of the coast and many of them make their home on the smaller islands off the coast of Peru and also on the main- 7 84 SOIL FERTILITY AND FERTILIZERS land, because of the abundant supply of fish in that region. The excrement voided by these birds is rich in nitrogen and phos- phoric acid because their food, which is fish, is rich in these con- stituents. During breeding seasons they literally cover these is- lands and the young birds after they are hatched are fed on fish until they are able to fly. The excreta from the old and young birds, feathers, and the remains of the young birds that die. xsnft. Fig. 6.— Map showing location of Peruvian Guano Islands. all go to make up guano. As this region is practically rainless and has a dry hot temperature, these remains dry out rapidly and are preserved without much loss of phosphoric acid or nitrogen. There is some loss of nitrogen in these Peruvian guanos due to the formation of ammonium carbonate, a volatile form, and to leaching by occasional rains. However, these deposits have been HIGH GRADi; NITROGENOUS FERTILIZER MATERIALS «5 the best nitrogenous guanos in the world. There are deposits in other parts of South America, West Indies, Africa, Australia, Asia, and the islands of the Pacific, but the Peruvian deposits are the most notable. There is a wide difference in the compo- sition of guanos. In Peru, guano from the same island shows variation in chemical composition, while guano from different islands shows even a greater variation. The oldest deposits usually contain less nitrogen and more phosphoric acid than the more recent. In a wet, damp climate fermentation, aided by Fig. 7.— Cormorants. the presence of moisture, destroys all or most of the organic matter driving off the nitrogen as ammonium carbonate. Solu- ble phosphoric acid is also lost in such regions. Therefore it is easy to understand the wide differences in the composition of these deposits. Guanos range from rich nitrogenous deposits to phosphatic deposits which only contain traces of nitrogen and considerable amounts of phosphate of lime. There are therefore two classes 86 SOJh FERTILITY AND FERTILIZERS of guanos, namely, nitrogenous and phosphatic. The phosphatic guanos will be discussed under phosphates. Formerly guano was used more extensively in the United States but most of the nitrogenous deposits have been exhausted so that the impoitations are rather decreasing from year to year. There were 16,155 tons imported from Peru in 1905 and 5,500 tons in 1909.^= The nitrogen in guanos is present in different forms. Some of it is as nitrates, some as ammonia and some as organic nitro- gen. The presence of these various forms makes the nitrogenous guanos valuable because they supply plant food during the whole growing season. Anat.ysis of Chinchas Guano ■ 1897-' Percent. Per cent. 0.32 3-94 8.85 2.98 2.63 6.29 0.37 16.09 9.29 Guano does not contain appreciable amounts of potash. It is a fertilizer that does not require much intelligence to apply as it does not injure crops in any way. Sometimes Peruvian guano is acidulated with sulphuric acid to convert the volatile ammonium carbonate into ammonium sul- phate, which is a stable compound, and to make the phosphoric acid soluble. This product is called dissolved Peruvian guano and is a better fertilizer than the original material because the nitrogen is saved and the phosphoric acid rendered available as plant food. The Ichaboe guano, obtained from the Island of Ichaboe on the west coast of Africa, is a recent deposit and is being worked, but it is inferior to the Peruvian guanos that were formerly shipped. The following table gives the composition of nitrogenous guanos. Those printed in italics are being worked.^* HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 87 Angamos Chincha Ballestas Egyptian Guanape Macabi Corcovadc Saldanha Bay Ichaboe Independence Bay . Pabellon de Pica • ■ ■ Punta de Lobos ■ ■ • Huanillos Penguin Patagonian Falkland Islands ■ . Nitrogen Per cent. 20 14 12 II II II II 9 8 7 7 4 6 5 4 4 Phosphoric acid Per cent. 5 13 12 19 12 15 9 9 12 14 15 13 IT 18 14 In Mexico there are deposits of bat guano, many of which are good nitrogenous fertilizers, but they are not being worked be- cause of poor transportation facilities. There are also deposits of bat guano in Texas. The bat guanos are not as a rule valu- able as the high grade nitrogenous Peruvian guanos. For the composition of bat guanos refer to the chapter of Farm Manure. Ammonium sulphate is unlike the organic compounds as it is not a natural product but a manufacturing by-product. When pure it is a white crystalline salt but sometimes foreign substances become mixed with it, in the course of manufacture, which causes it to be grey, yellow, or blue. It is soluble in water and volatile, that is it will pass ofif as gas when strongly heated over a flame. It is derived from the distillation of coal in the manu- facture of gas ; from the distillation of bones in the manufacture of bone-black; and from the manufacture of coke from coal. Coal was formed vegetable matter and most coals average about 1.8 per cent, nitrogen. When coal is heated, as in the manu- facture of gas or coke, about Ij, of the nitrogen as ammonia is driven off and this ammonia may be saved by washing it in water in special apparatus. The solution thus formed is then distilled into sulphuric acid, concentrated and the crystals of sulphate of ammonia separate out on standing. Bones contain about 3 to 4.5 88 SOIL FERTILITY AND FERTILIZERS per cent, nitrogen and the nitrogen as ammonia is recovered in a similar way as in distilling coal or coke, when they are subjected I! Fig. S. — Old process of maiiufacturinK ammonium sulphate. to dry distillation by heat, as may be practiced in the manufacture of bone-black. The Direct Process. — There is another process called the direct process for recovering ammonia from coal, etc., that is being used in Germany. In this process the ammonia in the gas is com- bined directly with sulphuric acid forming sulphate of ammonia, thus doing away with the ammonia washers. The direct pro- cess has many advantages. It reduces the equipment ; the opera- tion is simpler ; the consumption of water is less ; ammonia stills are not required. In other words, the direct process is much less expensive, promises to revolutionize the recovery of am- HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 89 90 SOIL FERTILITY AND FERTILIZERS monia in coal and coke, and should cause a greater production of sulphate of ammonia in the United States. About I per cent, of the weight of the coal carbonized is sul- phate of ammonia, so that for the production of 5 tons, 500 tons of coal must be treated. Tabi,e Showing Percentages of Ammonia, Pure Ammonium Sul- phate, Nitrogen, and Pos-sible Impurities in Commercial Sulphate of Ammonia.' Ammonia Ammonium Sulphate Nitrogen Impurities Per cent. Per cent. Per cent. Per cent. 25.796 100.00 21.203 0.00 25-7 99-63 21.12 0.37 25.6 99.24 21.04 76 25-5 98.85 20.96 I-I5 25.4 98.46 20.88 1-54 25.3 98.08 20.79 1.92 25.2 97.69 20.71 2.31 25-1 97-3° 20.63 2.70 25.0 96.91 20.55 3-09 24.9 96-52 20.47 3-48 24.8 96.14 20.38 3-86 24.7 95-75 20.30 4-25 24.6 95.36 20.22 4.64 24-5 94.97 20.14 5-03 24.4 94.59 20.06 5.41 24.3 94.20 19.97 5.80 24.2 93-81 19.89 . 6.19 24.1 93-42 19.81 6.58 24.0 93-04 19-73 6.96 23-9 92.6s 19.64 7-35 23.8 92.26 19-56 7.74 23.7 9>-87 19.48 8.13 23.6 91.49 19.40 f-5^ 23-5 91.10 19-32 8.90 23-4 90.71 19.23 9.29 23-3 90.32 19-15 9.68 23.2 89.94 19.07 10.06 23-1 89.55 18.99 10.45 23.0 89.16 18.90 1084 Extent of Manufacture. — This product is manufactured exten- sively in England and Germany. About 348,000 tons were pro- duced in England and 325,000 tons in Germany for 1909. About 100,000 tons will approximate the output in this country but the tonnage will in all probability be much larger as many of ' American Coal Products Co. HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 9I the coke ovens in the United States are not saving the ammonia. . About 40,000 tons of ammonium sulphate were imported for 1909 mainly from England."^ On account of this product containing such a high content of nitrogen it may sometimes be purchased cheap, as the freight per unit of nitrogen is less than when a product containing less nitrogen is selected. Composition and Availability. — Sulphate of ammonia when pure contains 21.2 per cent, nitrogen but the commercial article usually runs about 20 per cent. It is in a form very suitable for distri- bution in the soil and is readily converted into available plant food. It more available than the organic forms. It is a quick acting fertilizer and suitable therefore for quick returns in crop production, an especial advantage for truckers and market gard- eners. It is sometimes substituted for nitrate of soda. It is usually a uniform product and adulterants are not often added to it. Should adulteration be expected the following tests may suffice to prove its purity. It should dissolve in water; it should have the appearance of salt; it should pass off as gas when a small quantity is heated red hot on a shovel or iron plate. As it is readily soluble in water it should be used sparingly, and frequent small applications are more effective than large amounts applied at long intervals. A continued use of it may cause the soil to become acid because of the sulphates left in the soil after the nitrogen is given up. Nitrate of Soda. — This is a white or yellow or pink crystalline salt. The nitrogen in nitrate of soda is in a form that can be used by plants without undergoing any change. Nitrate of soda is the highest in point of availability of any of the nitrog- enous fertilizer materials. It induces roots to grow deep. The nitrate diffuses into the subsoil and the plants send down their roots for it. This is indeed of great benefit because it enables the plant to better stand dry spells and it increases the area of plant food supply. Deposits and Shipments. — It is found in extensive deposits on the west coast of Chile and is often called Chile saltpeter. There if a difference of opinion regarding the origin of these deposits 92 SOIL FERTIUTY AND FERTILIZERS but it is thought that they were formed by the decomposition of marine vegetation, as seaweed in combination with sea salt. The exportation of nitrate of soda brings a vast revenue to HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 93 the Chilian government. The export duty per year amounts J^^H^H^B^^^^^HE^B^/j^^^EgG^^xMn ■^^^H^hBH^HKhp^/^^^^I^mHH^^B Bh^^^ ^>"i^ f" V ■ >•"*" 1^^^ • W^m < mK. --.'^faiiSfl 11^ *# i k^ ' ■ ^^■Btf^lf rM ^HS^.»4aB^^^^H ■Si^B^ 'A pHBiESB^H^^^^-^^^^J W^fffKK^^^m B^^^SI to about $20,000,000 or approximately three-fourths of the in- come of that country. The exportation of this salt started in 94 son, FERTILITV AND FERTILIZERS 1830 with a trial shipment of about 9,000 tons and the total exportation from 1840 to 1904 amounted to 25,947,994 tons. From igo4 to 1923 it is estimated that 35,336,180 tons will be exported. Up to and including 1909 about 40,000,000 tons were shipped.''^ Shipments of Nitrate of Soda for 1908-9." Production Europe United States Other points Total shipments 1908 2.075.039 1,583.278 453,831 70,401 2,107 510 1909 1,947,603 1,644.505 326,818 55.367 2,026,690 The value of this product may better be realized when it is known that it has a wholesale market value of $45 to $53 [)er ton in this country. A great deal of it is used for the manu- facture of explosives. The following shows the amounts used for the manufacture of fertilizers. '- 1900 Tons 17,203 1905 Tons 40.234 Caliche. — The native deposit of nitrate of soda is called caliche. Caliche contains from small percentages to 60 per cent, nitrate of soda. It is not worked at present unless it contains about 18 per cent, nitrate of soda. Impurities as .sodium chloride, potassium sulphate, calcium sulphate, sodium sulphate, magne- sium sulphate, etc., are associated with the nitrate of soda. The caliche is found in layers sometimes 6 feet thick, about 2 to 10 feet below the surface, and is blasted out with more or less earthy matter which adheres to it. It is put in vats where it is dissolved in hot water and steam. After it is dissolved the solu- tion is piped to crystallizing pans where the crystals of nitrate of soda separate out on cooling. The mother liquor is saved and used over again. HIGH GRADi; NITROGENOUS FERTIUZlJR MATERIALS 95 96 SOIL FERTIUTY AND FERTILIZERS Analysis of Nitrate of Soda Crystals After Being Dried IN THE Sun." Per cent. Per cent. Sodium nitrate Potassium nitrate Sodium chloride 94.164 1.763 0.933 O.OIO 0.138 0.289 Calcium sulphate Magnesium snlphate. . . Potassium perchlorate . Water 0.102 0.219 0.282 2 100 Insoluble matter Magnesium chloride. ■ . Total Composition and Properties. — Nitrate of soda contains 15 to 16 per cent, nitrogen and the average product found on the Ameri- can market contains 15.3 per cent, nitrogen. It is very soluble in water and therefore it should be supplied in small quantities frequently to prevent losing it by leaching. It should be kept in dry storage as it absorbs water and is liable to liquefy. It is hard to distribute evenly on the soil unless it is mixed with earth or some other material. On account of its caustic action it should be applied around the plants and not on them as it spots green vegetation. It should be kept away from live-stock as it is poisonous. Acid phosphates when damp should not be mixed with nitrate of soda as nitrogen is lost. The acid attacks the nitrate of soda liberating the nitrogen. A continued use of nitrate of soda prevents losses of carbonate of lime from the soil. The following experiment was con- 'lucted for 40 years." Fertilizer Uti manured Complete minerals and 275 lbs., ni- trate of soda Complete minerals and 400 lbs. am- monium salts Farm manure Per cent, in fine dry soil 1865 4-54 4.24 3-82 4.20 1904 3.29 3.36 2.25 3.28 Loss per acre per year lbs. 800 564 1,010 590 Nitrate of soda reduced the loss of carbonate of lime con- siderably, from 236 pounds to 446 pounds respectively. HIGH GRADE NITROGENOUS FERTHvIZER MATERIALS 97 3 ^5 --rp^ "Py^ j k.. "i^ -r~- 1 KM kiSi 1 HRI' '' -jH 98 SOIL FERTILITY AND FERTILIZERS Nitrate of soda used continuously and abundantly is liable to put the soil in poor condition, as the sodium is not taken up by the plant as rapidly as the nitrogen, and is left behind as sodium carbonate. The compacting of soils due to nitrate of soda may be relieved to a certain extent by applications of acid phosphate and ammonium sulphate, which have acid reactions in the soil and tend to neutralize the alkaline condition due to the nitrate of soda. The utilization of nitrogen from the air by artifically uniting and fixing it with other elements to form compounds that could compete with the other nitrogenous fertilizer materials has attracted the attention of chemists and investigators for many years. It seems that at last the problem has been solved and it is now only a matter of a short time when the present modes of manufacturing artificial nitrogen compounds will be so perfected that we will not be forced to worry about the future supply of this important element. There are two of these artificial nitrog- enous compounds being sold to-day, namely, calcium nitrate and calcium cyanamid. Calcium nitrate sometimes called Hme nitrogen, Ca(N03)24H20, is manufactured by the Berkeland-Eyde process, with cheap water-power, in Notodden, Norway. A brief description of the process may be of interest. Process of Manufacture. — The nitrogen is united with oxygen at a high temperature (2,600° C. to 3,000° C.) with the aid of an electric arc flame. Hall says :" "In the Berkeland-Eyde pro- cess an alternating current at about 5,000 volts is set to form an arc between U-shaped copper electrodes, which are hollow and kept cool by a current of water within. The electrodes are placed equatorially between the poles of a powerful electro- magnet, which has the effect of causing the arc to spread out into a broad flat flame. Though the temperature of the arc-flame is calculated to be 2,600° C, it is not particularly luminous ; it may be looked directly from a yard's distance. "Through the furnace in which this special arc is generated about 15,000 liters' of air are blown per minute at gentle pres- ^ One liter equals 1.057 quarts. HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 99 sure and the issuing air contains about i per cent, of nitric oxide and is at a temperature of 600° to 700° C. It is cooled and then passes into two oxidizing chambers, where the com- bination of the nitric oxide with the oxygen of the uncombined air takes place, after which it passes into a series of five con- densing towers. Down the fourth tower, which is filled with broken quartz, water trickles and picks up enough of the nitrous gases to become 5 per cent, nitric acid at the bottom ; this is pumped up and trickles down the third tower, the process being repeated until the liquid leaving the bottorn of the first tower contains 50 per cent, of nitric acid. In the fifth and last tower the absorbing liquid is milk of lime, and the resulting mixture of solution of calcium nitrite and nitrate is treated with enough, of the previously formed nitric acid to convert it wholly into nitrate, the nitrous fumes evolved being led back into the oxi- dizing chambers. The product is then concentrated until it solidifies as a material containing about 13 per cent, of nitrogen, or 75 per cent, of pure calcium nitrate. "The present factory has three electric furnaces installed, each employing 500 kilowatts, and the production amounts to about 150 kilograms^ of nitrogen fixed per kilowatt year. Output and Value. — "Berkeland calculates that the cost of manufacturing calcium nitrate containing 13 per cent, of nitro- gen is about $20 per ton, and that it can be sold at a profit at $40 a ton, which would be equivalent to nitrate of soda at about $50 a ton. The present large factory at Notodden has been put- ting calcium nitrate on the market for two years or more, the rate of production now being about 20,000 tons per annum. When the extensions to the factory are completed it is expected the output will amount to nearly 3,000 tons per month. As a fertilizer there cannot be the least doubt that nitrate of lime will be just as valuable, nitrogen for nitrogen, as. nitrate of soda. At Rothamstead a chemically prepared nitrate of lime has been used for two or three years for a special purpose on one of the mangold plots, and it has given exactly equal results to the nitrate of soda plot alongside. Many field experiments have 1 One kilogram equals 2.20 pounds. 8 100 SOIL FERTILITY AND FERTILIZERS been carried out with the electrical product in Norway during the last year or two, and have shown that the new material can be strictly valued against nitrate of soda on the basis of the nitrogen it contains. Indeed, on some soils it is likely to be more valuable, because, as will be shown later, part at least of the lime base will be left behind in the soil as calcium carbonate. This will be an advantage in peaty soils, and will also save clay soils from the peculiar wetness and stickiness which results from the employment of much nitrate of soda." Galcitun cyanamid is a grey black crystalline powder. It is 1 ;*« , ^^^^^UKj.faB.'S?^ — ^, ' -_■■,■ -^^ Fig. 14. — American Cyanamid Co. Plant, Niagara Falls, Ont. made from limestone, coke and nitrogen gas. The first step in the manufacture of this compound consists in the production of calcium carbide which is made by heating a mixture of coke and limestone in an electric furnace under a high temperature (1,100" C.) The following is the reaction: CaO +3C = CaC, +CO. The carbide is powdered and introduced into air-tight coal- fired retorts. After the carbide has reached a white heat pure nitrogen gas is passed over it and the carbide absorbs the nitro- HIGH GRADE NITROGENOUS FERTILIZER MATERIALS lOI gen gas, forming calcium cyanamid. The nitrogen gas is ob- tained by passing air over red-hot copper, which removes the oxygen by forming copper oxide which is reduced again to metalHc copper by passing coal gas over it. There is another process called the liquid air process used, wherein the nitrogen gas is obtained by fractional distillation from liquefied air, the nitrogen being evaporated at a lower temperature than the oxy- gen. The calcium cyanamid as it comes from the retorts is cooled in air-tight receptacles, powdered and packed for the market. The reaction is: CaCj + Nj = CaCNj -|- C. The composition of calcium cyanamid is about as follows :^- Per cent. Calcium cyanamid (CaCN,) 57 Carbon 14 Lime (CaO) 21 Silica 25 Iron oxide 4 Calcium sulphide, phosphide, and carbonate 1.5 Nitrogen 20 When calcium cyanamid was first placed upon the market small quantities of carbides, sulphides and phosphides were present which are undesirable for fertilizing purposes as they are decomposed by the moisture in the soil forming acetylene, sulphuretted hydrogen and phosphine. These gases are poison- ous to plants and especially injurious to young germinating plants. Considerable experimentation was done by the manu- facturers to rid cyanamid of these poisonous substances and a product is now claimed to be manufactured in Baltimore, Md. by the American Cyanamid Co., in which these poisonous ma- terials are absent. This new product is known as, "Improved Cyanamid" and has the following proximate composition :'° 102 SOIL FERTII.ITY AND FERTILIZERS Per cent. Calcium cyanamid 29.26 ' ' carbonate o. 2 1 ' ' nitrate 20.06 hydrate 28.78 Sodium cyanamid 10.38 Free carbon 7.89 Silica 1 .03 Alumina 1.37 Iron oxide 0.69 Not determined 0.33 100.00 Total nitrogen 17.01 Total calcium oxide 34-73 Nitrate nitrogen 3.39 Cyanamid nitrogen 1 3.62 Properties. — About 80 per cent, of the nitrogen in the improved cyanamid is as cyanamid and the remaining 20 per cent, as nitrate. Calcium cyanamid contains about 20 per cent, of free lime which absorbs water and carbonic acid gas from the air, causing the lime to slake and the product to decompose so that ammonia is formed. This ammonia is not lost to any great extent when the product is kept in bags, but if it is exposed in a loose pile the loss may be appreciable. Calcium cyanamid is soluble in water and when steam is introduced into it ammonia is driven off. In the soil the ammonia is given off by the action of water and soil micro-organisms. The action with water is: CaCN, + 3H2O = CaCOj + 2NH3. Fertilizing Value. — Experiments show that this product has about the same fertilizing value as ammonium sulphate orr most .soils. It is therefore highly available. It would no doubt show to good advantage on soils deficient in lime. Care should be exercised in its application. When the product contains in- jurious substances it is liable to injure seedlings and it is safe practice to apply it sometime before the seed is planted. It is thought to be injurious when used as a top dressing but this point has not been thoroughly proved. Should the "Improved Cyanamid" be free from injurious substances it will prove a much more desirable fertilizer. HIGH GRADE NITROGENOUS FERTILIZER MATERIALS 103 On the Rothamstead soil which contains an ample supply of lime as carbonate, the following results were obtained.' Fertilizer Calcium cyananiid Sulphate of ammonia . Barley Grain Bushels 34-3 37-5 straw Pounds 1,900 2,400 Mangolds roots Tons Tons Tons 22.0 23-5 II. I lO.O 28.9 27.9 Composition of High Grade Nitrogenous Materials. Cotton-seed meal Linseed meal Castor pomace Rape meal Red blood Black blood Tankage Concentrated tankage Azotin Steamed horn and hoof meal Dry ground fish King crab Guano Ammonium sulphate Nitrate of soda Calcium nitrate Calcium cyanamid Nitrogen Per cent. 6.58 5-3° 5-5° 500 13-50 I2.00 6.58-7-41 10-12 13.00 12-15 8.50 10.00 4-12 20.00 15-30 13.00 16-20 Phosphoric acid Percent. 2.80 1.60 1.80 1.60 3-5-5 9.00 5-20 Potash Per cent. 1.50 1-25 1.00 CHAPTER VI. LOW GRADE NrTROGENOUS MATERIALS AND FUNCTIONS OF NITROGEN. The nitrogenous substances discussed in the previous chapter are all considered high class and valuable standard materials. Some of them as the mineral compounds are immediately or almost immediately available, while the organic materials, both animal and vegetable, vary in their degree of availability, but stay with the crop during the whole or the greater part of the season. The high prices of these desirable and valuable nitrogenous materials have caused some of the manufacturers of commercial fertilizers to seek and use cheaper sources of nitrogen. Many of these cheaper materials, to be sure, are rich in nitrogen but really of little value as the nitrogen is present in such forms as to be inert or else too slow acting to stimulate plant growth. Many of these low grade nitrogenous waste products are im- ported from foreign countries yet we produce our share of them in this country. They are made up of wastes from the manufacture of silk, wool, feathers, combs, hair, skins, sugar and some few are derived from vegetable sources. The ma- terials most commonly used will be discussed. Raw Leather Meal. — This product contains about 8 per cent, nitrog-en, which is in a form that is very slowly utilized by plants; it may remain in the soil for two or three years before decaying. It takes such a long time for it to decompose that it has not much value for fertilizing purposes. One of the ob- jects in the treatment of leather is to prevent its decay and for this reason raw leather may remain in the soil for a very long time before undergoing any change. This material is sold vary- ing in the degree of fineness from a dust to coarse particles. If it is ever used it should be powdered. At best it is a tough material. Dissolved leather, sometimes called treated leather or extracted leather, is made in Belgium. The raw leather is roasted and I,OW GRADE NITROGENOUS MATERIAIvS, ETC. 105 very finely ground and treated with superheated steam which removes most of the tannic acid. It is then acidulated with sulphuric acid to fix the nitrogen and render it more available. This material is being used by the manufacturers in the United States to quite a considerable extent because it is cheaper than the more desirable nitrogenous materials per unit of nitrogen. This product contains about 8 per cent, nitrogen and is more valuable than raw leather. Feather waste and various skin wastes are also saved for fer- tilizing purposes. Hair and fur waste is rich in nitrogen. It is unsuitable as fertilizer because it is so slowly decayed. When properly treated with sulphuric acid and rendered assimilative for plants it is more valuable. Hair to a limited extent is often found in tankage. Mora meal is a vegetable product, brown in color, which is imported from Europe. The mora seed, which are grown in India and probably other tropical countries, are sent to Europe where they are subjected to pressure and the oil extracted. The remaining pomace is ground and sold as mora meal. This product has been used for the past nine years in the United States and the consumption has increased every year. It carries about 2.5 per cent, of nitrogen which is of low availability. It is not sold with any guarantee of nitrogen, phosphoric acid and potash, but on a flat basis. It is used by manufacturers of commercial fertilizers principally as a dryer and filler. It is good for both of these purposes because it is an excellent absorbent and bulky. The quantity available from year to year depends upon the amount of seed raised and on the price. European pressers will not handle it unless the price of the seed is such that they can make a profit. Beet Refuse. — This compound is a grey black powdery sub- stance. It contains from 5 to 7 per cent, nitrogen and about 0.5 to I per cent, potash. One manufacturer used this compound in some of his mixtures because he believed it would kill insects Io6 SOIL FEKTILITY AND FEETILIZURS in the soil. He believed this because of the presence of sulpho- cyanic acid in this compound. Scutch. — This is a by-product or waste product in the manu- facture of glue and the dressing of skins. It is manufactured in England and contains about 7 per cent, nitrogen. Horn and hoof meal, horn shavings, etc., are products obtained from slaughtering houses or by-products in the manufacture of combs and similar articles. In the raw state they are ex- tremely hard to grind and are not valuable in this form be- cause they decay too slowly to supply plant food with any degree of rapidity. When steamed and pulverized they become high grade products as mentioned in the previous chapter. Wool Waste, Shoddies, Etc. — "Shoddy should consist of the short, broken fragments of wool which are rejected in the vari- ous processes for preparing woollen fabrics because they are not long enough to make up into yarn, but now the term is applied more generally to any form of waste from silk or wool manufacturing which is no longer profitable to work up for cloth. The material is thus extremely valuable in composition; pure wool contains over 17 per cent, of nitrogen, pure silk about as much, and at one end of the scale of shoddies come materials like carpet waste, cloth clippings, gun wad waste, which are nearly pure and may contain as much as 14 per cent, of nitrogen. Less valuable, because of the greater admixture of dirt, are wool combings, flock dust, and other cloth wastes where cotton is also used, these may have 5 to 10 per cent, of nitrogen ; while lower still come the manufacturing dust from textile factories, the sweepings of workshops, etc., in which the nitrogen may fall as low as 3 per cent."" These products are all slow to decay and are rather undesir- able as fertilizer. Shoddy and wool waste are often coarse and bulky and hard to mix in a manufactured fertilizer or to distrib- ute evenly when applied to the soil. Dissolved Wool, Shoddy, Etc. — Wool waste, shoddy, etc., are sometimes treated with superheated steam, the liquid evaporated to dryness and the product ground, or else they may be acid- LOW GRADE NITROGENOUS MATERIALS, ETC. I07 ulated with sulphuric acid for a long time (2 months) to render the nitrogen available. When treated by either of the above methods, they are known as dissolved wool, shoddy, etc., and are of course more valuable than the raw products from which they were made. Garbag^e Tankage. — Many of the large cities have plants where the garbage is accumulated. The garbage is digested with hot water and steam in special digesters for about 6 to 8 hours. It is then subjected to hydraulic pressure and the grease is ob- tained. The grease is separated from the extracted water; this latter product is evaporated and the residue mixed with the pres- sed tankage and dried to a low moisture content. The pro- duct is then screened and ready for sale. It carries about 2 to 4 per cent, of nitrogen, 2.5 to 5 per cent, of phosphoric acid and about 0.3 to 1.5 per cent, of potash. Garbage tankage is slow- ly assimilated by plants and is not a valuable fertilizer. Dried peat, sometimes called dried muck, is used principally by the manufacturers because of its excellent drying properties. The use -of it enables the manufacturer to put out a fertilizer in a fine mechanical condition which may be distributed evenly on the soil. This material varies in composition, depending on the amount of vegetable and mineral matter present, but may be considered as averaging 1.5 to 2 per cent, of nitrogen. Availability of Nitrogenous Fertilizer Materials. — The only cor- rect way to determine the value of any nitrogenous substance is by running experiments with growing plants. The high grade products as nitrate of soda, sulphate of ammonia, dried blood, cotton-seed meal, linseed meal, castor pomace, dry ground fish, tankage, ground bone, steamed horn and hoof meal, etc., have been tested by field experiments to determine their crop produc- ing power. Laboratory methods have been introduced to cor- respond as near as possible with the field results. The availability of nitrate of soda is always taken as 100 and the availability of other materials is based on the results secured when compared to nitrate of soda. Should nitrate of soda give an increased yield of 50D pounds per acre for a crop, the yield io8 SOIL FERTILITY AND FERTILIZERS of a nitrogenous fertilizer of 75 per cent, availability would give an increase of 375 pounds, etc. Not Always Possible to Run Field Experiments. — To conduct field experiments is often impossible, because of the great ex- pense, the long time required, the difference in soils, the varia- tion in seasons, the ability of the various crops for securing plant food, the association with other fertilizing materials con- taining phosphoric acid, potash, lime, etc., so that much of our information on the low grade products has been worked out in the laboratory by chemical methods. These methods are not entirely satisfactory but indicate to a great extent the relative values of nitrogenous fertilizers, as to whether they are high grade, medium grade or low grade. The Vermont and Con- necticut Experiment Stations have done considerable work along this line. Vegetation Experiments. — Wagner conducted some vegetation experiments on the relative availability of some nitrogenous materials. Summer rye, followed by flax, summer wheat and carrots were used in these experiments. RESULTS OF Wagner's Experiments. The Relative Availability OF Various Forms of Organic Nitrogenous Matter.'* The experi- ments of first year Average of 1 and second year's experi- ments first Average offirst second and third year's experiments Nitrate of soda Sulphate of ammonia Peruvian guano Blood meal Castor pomace Green crop manure • . Horn meal Fish, guano Steamed bone-meal . . Flesh meal Wool dust Stable manure Leather meal ICO 85 84 67 62 62 63 51 42 44 27 II 13 74 88 67 65 60 61 59 53 47 28 16 100 88 80 69 67 68 63 64 61 54 33 32 20 Wagner says in discussing the results of these experiments: "Of course these statements of value can only represent approxi- LOW GRADE NITROGENOUS MATERIALS, ETC. 109 mately the availability of these nitrogenous matters in com- parison with nitrate of soda. It would be foolish to attempt a numerical expression which should be absolutely correct in all cases. "Under conditions more favorable to the decay and nitrifica- tion of organic matters, than prevailed in our tests, — if the soil is richer in humus or lime, lighter, warmer, etc., or if a crop is grown which has a longer period of growth and with it a greater capacity for assimilating nitrogen — then the above figures will be somewhat higher, and on the other hand (under less favorable conditions), lower." Recent experiments show that calcium nitrate and calcium cyanamid are about equal to ammonium sulphate in availability. The results of the vegetation tests of the Connecticut Ex- periment Station show the following availability for different nitrogenous materials.'^ Experiments of 1894 Experiments of 1894 and 1895 Experiments of 1894,1895 and Nitrate of soda Collier castor pomace . Cotton-seed meal Red seal castor pomace Linseed meal Dried blood Dry fish Dissolved leather Horn and hoof Tankage Steamed leather Roasted leather Raw leather 100 90 87 73 74 79 69 76 77 73 8 9 2 100 83 79 73 72 72 69 70 67 64 10 10 2 100 77 74 70 70 68 69 65 67 61 13 9 2 "The availability of the nitrogen of roasted, steamed and raw leather, while not alike in the three years, is so much lower than that of any other materials tested, as to demonstrate that the nitrogen in them is comparatively inert and of little effect un- less applied in large quantities. no SOIL FERTILITY AND FERTILIZERS rO r^OO 00 1^ lO ON r^oo lOOO OO fO ■ «;= S3 o.« ■ u > B « .- 1, "a < 05. s n < B-O h = OOOOO-OOOi-iOOwOOOOOOOOOOOOO Si: oS, ON cO^ f*^ r^ lO fOQO f^^ O '-' »0 O t>. t-- OvsO t^vo 00 q ON ^ « r^NO vo -^ io\o oo oo no q ^ fo -4 w -^No -^o' OMowvo'-^M -4 TJ-« 00 r^oo' Ch i>.vo t^no 1- c .iif^ i i « M , 6ec5 ^'o o ^ sa u u a 3 c a as CA n 3 3 O O a B p o ziz; LOW GRADE NITROGENOUS MATERIALS^ ETC. Ill 'tnB ^ art" I I I I I I u > Us = 8! n \D\D\0 rD CM CN t^ ^T TT 3=5 HHS=;2i^<:i- (U ^>, >- U t« U )h CC Qi CO c] ■« Q U U li ti U 0- S E-. :- H H 5- o c . - o S •«! 4» ?^ ^ 5 -a g S r .r rt S CO ra o S 3 3 « ij S : oT 3 rt rt iH g ■•-• "T- r- «« n L. ^- ^- fl; -- cd cc R m s n *-" "^ ■3—11 c t. s: r^CO 0\ O " W rO Tf lOVD l^CO C7^ O ^ 01 fO -^ lOvO I^C» OO — M CS N rOr»5rOfOtOc 112 SOIL FERTIUTY AND FERTILIZERS "The experiments also demonstrate that leather may be dis- solved in oil of vitriol so as to make its nitrogen nearly as avail- able to the maize and oat crops as that of tankage. Samples of roasted leather, steamed leather and dissolved leather were prepared each year from a common stock of raw leather, and slight differences in their preparation might explain the differ- ences of availability observed in different years. "Of the nine materials tested, other than leather, tankage certainly has the lowest nitrogen-availability, ranking 7th, 9th, and 9th, in the three years tests. Regarding the nitrogen-avail- ability of the other organic matters the experiments are not al- together conclusive." Laboratory Experiments. — Jones'" determined the availability of the principal nitrogenous organic materials. It will be seen that cotton-seed meal gives low results with permanganate solution due perhaps to the large amount of non-nitrogenous organic matter present. Vegetation tests were run on four of these materials by Hart- well. His results follow: Availability by : Original nitrogenous ma- nure Extracted leather Tartar yeast manure Patent nitrogenous potash manure Pot experiment Barley Millet Oats 52 10 19 34 70 49 o 39 62 38 38 Alkaline perman- ganate method Organic Total 43 37 32 15 46 37 37 35 Pepsin 49 45 6 The summary of the results are given in the following table: LOW GRADE NITROGENOUS MATERIALS, ETC. 113 AvAii.ABii.iTY Summary. Material Dried blood Dried fish Tankage Bone-meal Cotton-seed meal Castor pomace Tobacco stems Hoof meal Leather preparations Peat Mora meal ■ Tartar pomace Garbage tankage Sugar-beet — gas house refuse Fillerine Beet refuse Average alkaline per- manganate availability Average pepsin availa- Organic Total bility Per cent. Per cent. 65 65 97 68 68 77 56 56 71 56 56 75 46 46 88 46 50 78 12 12 63 66 67 25 44 45 49 27 27 -23 26 26 46 33 37 20 22 22 20 21 42 19 18 43 14 29 31 43 According to Jones: "Briefly reviewing the results as sum- marized in the above table we have in the first group the prob- ably readily available ammoniates. Excepting the three vege- table ammoniates to which the alkaline permanganate method is not applicable, but whose rank is clearly established by the pep- sin figure, we find the permanganate availability running from 55 to 68 and the pepsin from 71 to 97 per cent. It should be noted that pepsin treatment gives a low result, 25 per cent., for hoof meal, against 66 per cent, by the permanganate process. Certain vegetation tests by the Connecticut Experiment Station indicate that the higher figure is possibly more nearly correct. "The second group, whether of vegetable or animal origin, shows a decided drop in availability percentage by both methods and fall into the questionable class. The leather preparations were mechanically very fine and dry in many instances partially soluble in water. Many of them carried a considerable per- centage of ammonia, for which credit is given in the column headed total." "The inert nature of the nitrogen in peat is well recognized. 114 SOII< FERTILITY AND FERTILIZERS Note the low permanganate availability of 27 per cent, and the pepsin figure of minus 25 per cent." Sample No. 37 shows the in- crease of availability of peat by treating with sulphuric acid. Recent work performed at the Rhode Island Station shows that the availability of nitrogen as determined by pot experiments closely approximates the availability by the alkaline permanganate method.^ Description of Some of the Low Grade Materials. — The author wrote to Mr. Jones for information as to the sources, pro- cess of manufacture and composition of some of the materials mentioned in the foregoing tables. In his reply he states: "I have been on the lookout for all kinds of organic ammoniates during the past ten years ; I really know very little of the pro- cess of manufacture, nor do I know just where you could obtain definite information on the subject. Such notes as I have ob- tained from the senders of the samples are as follows: "Soluble organic nitrogen is principally made up of hair and wool. "Beet refuse compound contains from one-half to one per cent, of actual potash. It is beet refuse treated with gas waste and has been criticised as containing sulpho-cyanic acid. "High grade potash manure, is a pure vegetable beet refuse containing 6 to 8 per cent, ammonia and 6 to 9 per cent, actual potash and is very soluble. "Tartar pomace or tartar yeast, is a residue of wine lees of France: a pure vegetable compound. "Another ammoniated manure is described as the process treated leather which is mixed with gas ammonia liquor, con- taining in addition to ammonia upwards of i per cent, potash. "Fillerine is a heavy dark purple material containing cyanide. "Ordinary treated leather, is probably leather refuse baked under steam pressure and ground. Many of the other leather preparations may have been otherwise treated to remove most of the tannic acid and render them non-cakable. "French mora meal contains in addition to ammonia, upwards of 3 per cent, potash. Mr. Hartwell of the Rhode Island Sta- 1 Journal of Industrial and Engineering Chemistry, Aug., 1911. IvOW GRADE NITROGENOUS MATERIAES^ ETC. II5 tion tells me that the tree from which it is derived is a legume, grows in Guiana and Trinidad and has a pod 6 to 8 inches long by 3 inches wide, which contains a single large bean. It is probable that the mora meal comes from this material, although I have seen no positive statement to that effect. "Tygert tankage is a leather preparation which I have always understood was manufactured in the vicinity of Philadelphia and may possibly contain some ordinary tankage. "Please understand that I do not vouch for the accuracy of the statements above given as I have had to take all of them .second hand." Value of Low Grade Materials. — Raw leather, wool waste, shoddy, hair, etc., may be rendered fairly available as plant food by special treatment, but such treatment usually is expensive and the market value does not always permit it. The standard high grade materials are always to be preferred and these low grade wastes cannot be sold imless they are much cheaper. Hence these low grade substances are usually only partially treated or not at all, so they have very little value as fertilizer and the use of them is liable to cause disappointment and poor yields. They are not always sold alone but are sometimes mixed to- gether. The writer has examined a product imported from Belgium and sold as Foreign Imported Tankage which wai made up of shoddy, wool waste, hair, and leather and was only partially treated. Most of the material was in the raw state and in poor mechanical condition ; chemical methods showed it to be poor plant food. This material contained about 7 per cent, nitrogen with traces of phosphoric acid. Should any of these low grade substances be used, the purchaser should de- mand that they be powdered, or ground very fine, in order to give the soil organisms a better chance to decompose them. The purchaser should not expect to get quick results with many of these wastes as some of them, particularly the raw leather, may remain in the ground for two or three years without any apparent change. Note. — Recent experiments show that the wet process of treating low grade materials increases their availabilitv considerably. This process conststs of treating fertiiizer ma- terials with sulphuric acid and sealing the same in a den or receptacle for a few days. Il6 SOIL FERTILITY AND FERTILIZERS The Use of Low Grade Materials is Increasing. — The use of these low grade materials seems to be increasing and many manu- facturers are using them in their low grade cheap fertilizers which carry low percentages of nitrogen, to a greater or less extent. The writer believes that some of these materials have no doubt been misrepresented to the manufacturers or else they would not use them. In order to insure future business they endeavor to put out fertilizers that will give good crop returns, and by satisfying their formulas with much of this class of material the poor crop returns will surely hurt them in repeating orders. Some of these materials are said to be used as dryers by the manufacturers (peat and mora meal for example) but analyses of fertilizers containing them often show that the manufacturers counted the nitrogen content in making the fertilizers. Peat to be sure is a valuable filler for fertilizers as in addition to its dry- ing qualities it contains about 30 per cent, of humus, but its nitrogen is not readily available and fertilizers containing it should have their guarantees satisfied by the use of more avail- able substances. The Nitrogenous Materials to Use. — We have learned that most plants assimilate nitrogen from the soil as nitrate and occasional- ly as ammonia. We also know that certain organisms in the soil convert the nitrogen from organic sources into ammonia and from ammonia into nitrates. Therefore it is reasonable to suppose that substances containing nitrogen as nitrates are to be preferred for immediate results in plant growth. As am- monia is converted to nitrates in the soil, materials containing nitrogen as ammonia, as ammonium sulphate for example, are less active than nitrate of soda. Again, nitrogen from organic sources is less active than from substances containing nitrogen as nitrates or ammonia, as organic nitrogen must be changed to ammonia and nitrates before teing usable, and we would use materials furnishing this form of nitrogen for slower and more lasting results. We have seen that the nitrogen from organic products varies a great deal in the power of giving up or hold- LOW GRADE NITROGENOUS MATERIALS, ETC. II7 ing nitrogen. Dried blood and cotton-seed meal, for example, give up nitrogen quicker than tankage and dry ground fish, and these latter substances do not hold nitrogen as long as leather preparations and wool waste. Therefore in selecting the proper nitrogenous material or materials to use we must consider the condition of the soil, climate, locality, kind of crop, etc. For Immediate Eesults. — Should immediate results be desired, applications of nitrate of soda, sulphate of ammonia, lime nitrate, or calcium cyanamid should serve the purpose. The locality may prevent the use of organic substances as a certain amount of heat (37° F.) is required for the soil organisms to convert organic nitrogen into nitrates. A wet season checks nitrifica- tion and hence nitrate of soda and sulphate of ammonia should give better results than the organic materials. For Soils Well Supplied and Long^ Growing Crops. — Should the soil have a sufficient natural supply of organic nitrogen as from some leguminous crop plowed under, etc., perhaps no organic nitrogenous material should be applied and a small application of some one of the mineral salts may suffice to give the crop a start. If the crop is a long growing one, an organic product may prove best, as it gives up its nitrogen in smaller amounts and more slowly than the chemicals and will thus stay with the crop the whole season. Mixtures of mineral and organic materials may sometimes be best so as to enable the plant to get a quick start by supplying immediate food and when this supply is exhausted, to furnish nourishment from the organic sources for the re- mainder of the season. The fertilizer manufacturers often use two or three different nitrogenous substances of different forms, as nitrate of soda, sulphate of ammonia and cotton-seed meal, in their fertilizers to allow the plant a continual supply of available nitrogen. Mixtures of organic materials of different availabilities may make excellent combinations for certain crops. For large Crops and Building up the Soil. — Should a large crop be desired the chemicals and the active organic substances would perhaps be preferable, but should the building up of the soil for some future crop be wished, the less active organic materi- n8 SOIL FERTILITY AND FERTILIZERS als would prove more valuable than nitrate of soda, ammonium sulphate, lime nitrate, calcium cyanamid, dried blood, cotton- seen meal, etc., as these materials are all changed to the nitrate form, except nitrate of soda which is already in this form, either immediately or during the season and would in all prob- ability be lost because nitrates do not become fixed in the soil and are readily washed away by heavy rains. The nitrogen in organic materials is not soluble in water to any great extent as is the case with nitrate of soda, sulphate of ammonia, lime ni- trate and calcium cyanamid so that the losses by leaching of the former substances are not considerable as compared to those of the latter. It is evident then that the farmer should select those sub- stances that will give the best results for his conditions and not purchase nitrogenous fertilizer that some neighbor recommends who secured good crops with an entirely different crop and soil, etc. Statistics.^^ — The principal materials containing nitrogen that were used in the manufacture of fertilizers for 1900 and 1905 follow : 1900 1905 Tons Tons 168,510 236,906 354,075 439,206 28,977 58,437 146,488 183,368 4,120 10,540 17-203 40,234 884 1,160 Bones, amtnoniates, etc. Tankage, etc. Fish products Cotton-seed products. . . Ammonium sulphate- . . Sodium nitrate Potassium nitrate Total 720,257 969,851 Potassium nitrate, although an excellent source of nitrogen and potash, is usually too expensive to use in commercial fer- tilizers. The total ammonia contained in manufactured fertilizers for 1900 and 1905 was distributed as follows : LOW GRADE NITROGENOUS MATERIALS^ ETC. iiy Bones, ammoniates, etc. Tankage, etc Fish products Cotton-seed products . . . Ammonium sulphate - ■ ■ Sodium nitrate Potassium nitrate Total Per cent, increase 1900 Tons Tons 8,931 20,182 2,8ll 16,690 5,668 9,212 1,022 15,036 2,614 3-217 124 7,524 162 45,499 56,065 23.22 Nitrogen Removed by Crops. — Some crops do not remove as much nitrogen as others but still these crops may deplete the soil of nitrogen by allowing it to escape in other ways as by leaching and denitrification. Functions of Nitrogen. — Nitrogen increases growth and defers maturity. In a certain parish in Louisiana where the people were ignorant along fertilizing lines, cotton-seed meal was the only fertilizer known to them. So year after year they applied this fertilizer to their cotton. For the last three years that they practiced this, they produced excellent large cotton plants but the crop did not mature well or produce scarcely any cotton. The people could not understand it. They did not know that cotton-seed meal was a nitrogenous fertilizer nor did they know that nitrogen produced growth. The Experiment Station was called upon to investigate the trouble and as the soil was naturally rich in potash, applications of acid phosphate corrected the con- dition. The above example shows the results of an excess of nitrogen in producing growth and deferring maturity. When excessive nitrogen is applied to potatoes it produces a vigorous growth of vines but very few tubers are formed. Should an excess of nitrogen be supplied the small grain crops it would cause them to lodge and produce grain of inferior quality and the excess of the weight of the crop to the weight of the grain would be high. Excessive nitrogen retards the for- mation of fruit. It produces growth of wood and leaves when the fruit should be forming. 120 SOIL FERTILITY AND FERTILIZERS Weights of Nitrogen Removed by Ordinary Crops in Pounds Per Acre." Crops Meadow hay, lyi tons Timothy hay, i % tons Clover hay, 2 tons Wheat Grain, 25 bushels- ■ ■ Straw Total Rye Grain, 30 bushels- - ■ Straw Total Oats Grain, 50 bushels- . - Straw Total Barley Grain, 50 bushels- - - Straw Total Corn Kernel, 50 bushels . Cobs Stover Total Potatoes Tubers, 200 bushels ■ Haulm (stems) Total Sugar-Beets Roots, 20 tons Tops Total Mangei.^ Roots, 25 tons Tops Total Turnips Roots, 20 tons Tops Total Swedes Roots, 16 tons Tops Total Cabbage, 20 tons Onions, 500 bushels ■ - - Tobacco, leaf Wt. as harvested Nitrogen 3,000 3,000 4,000 37.8 28.3 79-4 1,500 2,500 4,000 28.3 13-6 41.9 1,680 2,000 28.5 9.6 3,6So 38.1 1,600 2,100 30.2 13-4 3-700 43-6 2,350 2,800 5,150 46.6 13-7 60.3 2,800 700 2,300 5,800 46.1 2.7 14.0 62.8 14,000 4.500 47.0 21. 1 18,500 68. t 40,000 20.000 115-2 76.0 60,000 191.2 50,000 18.500 68,500 112.0 5>-8 163.8 40,000 11,600 5«,6oo 70.4 49.8 120.2 32,000 4,800 36,800 40,030 28,500 1,500 61. d 28.6 90.0 153-6 63.0 58-S LOW GRADE NITROGENOUS MATERIALS, ETC. 121 When nitrogen is lacking in the soil the plants do not grow so high as when the supply is sufficient. With crops grown on such soils the proportion of grain or seed to the weight of the crop is high. No matter how much phosphoric acid and potash there may be in the soil the crops can only use quantities in pro- portion to the growth of the plants, and the growth of plants will be in proportion to the nitrogen supply. Generally speaking an application of a nitrogenous fertilizer will produce increased yields without the application of potash and with an occasional supply of phosphoric acid. The nitro- gen produces a better leaf development, a better growth, the color of crops became a darker green, and the crop matures later. Often the supplying of nitrogen alone will increase yields to such an extent that farmers may overate the value of this constituent. On soils that are deficient in organic matter, that have been continually cropped, the need of nitrogen is generally greater than phosphoric acid and potash. The following table shows the value of nitrogen in increasing yields. Average Yield OF Wheat — 56 Years (1852-1907).' Fertilizer Graiu Bushels straw Pounds 12.9 U.8 20.5 23-7 31-6 1,050 1,230 1,870 2 280 Nitrogen only, no minerals 3.190 It is seen that the plot receiving phosphoric acid and potash but no nitrogen produced 1.9 bushels more of grain and 180 pounds more straw than the unfertilized plot. The plot that received nitrogen only produced 5.7 bushels more of grain and 640 pounds more of straw than the plot that was supplied with phosphoric acid and potash. Nitrogen and phosphoric acid show a gain over the nitrogen plot and the complete fertilizer gave the best results. Market gardeners often take advantage of the power of nitro- 122 SOIL FERTIUTY AND FERTILIZERS gen in the growing of lettuce and similar vegetables. Vegetables grown on soils more than amply supplied with nitrogen produce more delicate and tender vegetables, especially lettuce and cab- bage, but they do not stand shipping so well; although better for immediate consumption than vegetables grown on average soils they wilt and spoil quickly and are not popular with the commission houses. The cell walls and tissues are not so strong with crops grown on excessive nitrogen as when not. Excessive Nitrogen Invites Diseases. — Crops grown on soils that have excessive nitrogen are more suceptible to plant diseases than on average soils. This may be noticed to a limited extent with oats and wheat. When the season is especially favor- able to the production of nitrates in the soil during the growing period or when oats and wheat are grown on rich nitrogenous soils rust is more prevalent than usual. Plant diseases due to excessive nitrogen are perhaps more noticeable with crops grown under glass than outside. Most of the soils that are used in hothouses are very rich in nitrogen and the high temperature kept renders nitrification very rapid. The color of the leaves of hothouse crops becomes a darker green when excessive nitrogen is present, the leaves become tender and thin and seem to be easily attacked by certain fung^ unless extra precautions are taken. Cucumbers are especially susceptible to disease in the presence of excessive nitrogen. CHAPTER VII. PHOSPHATES. Phosphates are those materials that contain phosphoric acid. The phosphates occur as phosphate of lime, iron and alumina, in which compounds the phosphoric acid is united with lime, iron and alumina respectively. Since the phosphoric acid in fertilizers is derived mainly from phosphate of lime we will limit our treatment of the subject to the important materials composing this group. The phosphates of lime occur as organic, organic and mineral, and mineral compounds. Bones. — The chief source of phosphoric acid from the organic phosphates of lime are bones. The composition of bones is variable. The bones from old mature animals are richer in phosphate of lime than bones from young animals. Different bones from the same animal also show a variable composition, as the harder more compact bones are richer in phosphate of lime than the softer, porous ones. Raw Bone-Meal. — This is the finely ground product derived from raw bones and it contains all the constituents of them. It carries considerable organic matter much of which is in the form of fats, which makes it hard to grind and to handle on the market. The presence of organic matter makes it objectionable. The fatty matter, which slowly decomposes, tends to make this fertilizer very slowly available for plant food and so it is called a slow acting fertilizer. Raw bone-meal usually contains about 19 to 25 per cent, of phosphoric acid and 2 to 4 per cent, of nitrogen, with an average of 22 per cent, of phosphoric acid and 3.5 per cent, of nitrogen. Composition of Raw Bones.'" Per cent. Moisture 9.90 Organic matter 33.70 Lime phosphate 49- 12 Alkaline salts, magnesia, etc 6.18 Insoluble silicious matter i . 10 Total • 100.00 Nitrogen 3.76 124 SOIL FERTILITY AND FERTILIZERS The phosphates are sold to the trade on the basis of tricalcium phosphate present. To convert tricalcium phosphate to phos- phoric acid, multiply by the factor 0.4S76 and to get the equival- ent of tricalcium phosphate from a given percentage of phos- phoric acid, multiply by 2.185. Steamed Bone-Meal. — Most of the bone sold for fertilizing pur- poses has been boiled or steamed in the rendering factories to extract the fats and nitrogenous compounds which are used in making soap, glue, and gelatine. The bones are then ground or pulverized and sold as steamed bone-meal, bone-meal and bone-dust. This product is variable in composition, ranging from 17.5 to 29 per cent, of phosphoric acid and 1.5 to 4.5 per cent, of nitrogen. Good clean bone-meal should contain at least 2.5 per cent, of nitrogen and 25 per cent, of phosphoric acid. The treatment of the rawr bones affects the final composition of the product (steamed bone-meal) ; the boiling or steaming re- duces the nitrogen content and increases the phosphoric acid. Steamed bone-meal is a more quickly available fertilizer than raw bone-meal and is therefore better for most crops. There is a great difference in the steamed bone-meals put upon the market not only in the composition but in the hardness of the product. Steamed bone-meal from some factories is more porous and softer than from others. Some factories put out a product that crumbles easily while others sell meal that is extremely hard. Composition of Steamed Bone-Meai..-"' Moisture Organic matter Phosphate of lime, magnesia, etc Sulphate of lime Alkaline salts, carbonate of lime Silicious matter Total Nitrogen Good quality Bad quality Per cent. Per cent. 11-57 3-95 19.01 14.40 60.02 40.32 0.52 35-42 S.02 4.21 O.S6 1.70 100.00 100.00 1.60 1.20 PHOSPHATES 125 Degree of Fineness. — The bones when sold for fertilizing pur- poses are ground fine and are known as fine ground bone, bone- meal, bone-dust and bone-flour. The mechanical condition of fineness does not affect the composition but increases the avail- ability of the product for plant food. Hence the finer the bones are ground the more valuable they are as quicker acting fertili- zers. These products are generally valued according to their degree of fineness and chemical composition. It must be re- membered that all bone-meals give up their plant food slowly and are not desirable for immediate results in the production of crops. Composition of Raw and Steamed Bone for Comparison, Krocker.' Raw Per cent. Moisture Organic matter (^ nitrogen ) Phosphoric acid Lime Carbonic acid Iron oxide, magnesia, alkalies, etc. Insoluble matter Total 7-5° 38.00 (4.05) 19-50 24.20 4.10 3.20 3-50 Steamed Per cent. 5.30 33-40 (3-8o) 22.80 27.70 3.80 3-40 3.60 Bone-Black. — In the manufacture of bone-black, the choicest bones are selected, cleaned and dried. They are then put in air- tight vessels, heated and distilled until all the organic or volatile matter has passed off. The product is then ground to a coarse consistency and sold to the sugar refineries for clarifying or decolorizing syrups in the manufacture of white table sugar. After it has served its usefulness in the sugar refineries it is sold for fertilizer. It contains usually about 30 per cent, of phosphoric acid in the form of phosphate of lime. It is a slow acting fertilizer and is not used extensively in this condition. 126 SOIL FERTILITY AND FERTILIZEKS Composition of Bone-Black from Sugar Refineries." Percent Per cent. 3 Percent Per cent. 6 Per cent. Carbon (nitrogenous). Calcium phosphate Calcium carbonate Calcium sulphate Iron oxide Silicious matter Total 9-74 82.80 592 0.67 0-33 0.54 100.00 10.60 83.20 4-15 0.64 0.55 0.86 12.86 81.80 2.92 0.42 0.67 1-33 100.00 19.64 73.20 3.18 1. 12 0.66 2.20 7.42 87.08 1.92 0.95 0.85 1.78 10.64 80.56 4-52 2.24 ■ 0.72 1-32 100.00 Average Composition of Bone-Black, Krocker.'* Per cent. Moisture 2.350 Carbon 12.388 Lime 38.416 Phosphoric acid 29.690 Carbonic acid 2.400 Sand 13-300 Other matters 1.456 Total 100.00 Bone-Ash. — When bones are burned the remaining product is called bone-ash. It is not manufactured a great deal in this country because of the greater value of bone-black. It is an excellent fertilizer and the only shipments received to-day come from South America where the bones are burned to save freight. In burning bones the nitrogen is driven oflf, so that bone ash is valuable only for the phosphoric acid it contains. It varies in phosphoric acid content from 30 to 39 per cent. It is used in some countries in the manufacture of fertilizers. Composition of Bone-Ash.'* Commercial bone-ash Per cent. Pure ox bone-ash Per cent. Water and carbon Phosphoric acid ( ^ tricalcium phosphate) Lime Magnesia Iron oxide Carbonic acid, alkalies and substances not deter mined Silica Total 1.86 39-55 (86.34) 52.46 1.02 0.17 4-43 0.51 PHOSPHATES 127 Froiu shank bone of horse Per cent. From ox bone Per cent. Phosphoric acid Lime Magnesia Potash Soda Carbonic acid . - Sulphuric acid ■ Chlorine Total 40.29 5501 0.84 0.25 0.03 2.99 < trace > 99.41 3981 55-43 0.80 0.49 0.60 3-52 0.04 0.06 100.75 Bone Tankage. — This product is composed entirely of animal matter. It is the refuse from slaughter houses and rendering factories and consists of meat, bone, etc. (from which the fat has been extracted), and sometimes a little dried blood. There are many grades of tankage put upon the market. Those tank- ages coming under the head of bone tankage contain consider- able bone and small amounts of meat and sometimes dried blood. The amount of phosphoric acid in tankage varies with the bone content. The more bone present the higher is the percentage of phosphoric acid. The bone tankages range from iij4 per cent, to 20 per cent, of phosphoric acid. Those tankages fall- mg below 11 5^ per cent, of phosphoric acid are discussed under the chapter on nitrogenous fertilizer materials. The phosphoric acid in bone tankages has about the same value as in steamed bone, since both of these products are steamed or boiled to ex- tract the fats, etc. The bone tankages are very popular among farmers in certain sections of this country. Dry Ground Fish. — This is also an organic source of phosphoric acid from phosphate of lime. The phosphoric acid content de- pends upon the amount of bones present. This product was described with the fertilizer materials containing nitrogen. Suffice it is to say that dry ground fish carries from 6 to 16 per cent, of phosphoric acid. 128 SOIL FERTILITY AND FERTILIZERS Average Composition of Organic Phosphates of Lime. Phosphoric acid Per cent. Nitrogen Per cent. Raw bone-meal Steamed bone-meal . Bone-black Boue-ash Bone tankage Dry ground fish 22 25 30 36 II.5-20 9 3-5 2.5 4-6 8.5 The phosphoric acid present in raw bone-meal, steamed bone- meal, bone tankage, bone-black, bone-ash and dry ground fish is insoluble in water and slowly available as plant food. Mineral Phosphates. — These phosphates occur in natural beds in different parts of the world. The following descriptions on the production of phosphate rock for 1908 have been mostly taken from Van Horn's article in the American Fertilizer. The occurrence of rock phosphates in the United States has a very important bearing upon the agricultural industry, since certain classes of plant life cannot exist without the presence of phosphoric acid in the soil. Growing crops deplete the soil of its phosphoric acid, and if no steps are taken to restore this substance, the soil must eventually become non-productive. Florida, South Carolina, and Tennessee have for several years been the main sources of phosphate in the United States. North Carolina, Alabama, and Pennsylvania have produced phosphate rock, but never on a large scale, and there is at present no pro- duction from these states. In 1900 Arkansas entered the field as a producer, and in 1906 a new field was discovered in Wyom- ing, Idaho, and Utah. Phosphate mining began in the United States in 1868 in South Carolina. The existence of the rock had been known since 1837, but the possibilities of its commercial use were not recog- nized until 1859. Until 1888 South Carolina enjoyed a monopoly of the phos- phate industry of the United States. In that year Florida came forward as a phosphate state, with a production of 3,000 long tons. In 1904 the production surpassed that of South Carolina, PHOSPHATES 129 and Florida has maintained its lead up to the present time, per- haps because its rock is richer. In 1892 phosphate was discovered in Tennessee, and two years later the production from that state was 19,188 long- tons. In 1899 Tennessee went ahead of South Carolina, the production from the latter state having decreased steadily since 1893. Production. — The production of phosphate from South Caro- lina from the beginning of the industry in 1867 to the year 1888, during which period that state was the only producer, was 4,442,945 long tons, valued at $23,697,019. The following table shows the total production in the United States from 1867 to 1908: Marketed Production OF Phosphate Rock in the United States, 1867-1908, IN Long Tons. Year Quantity Value 1 867-1887 4,442-945 123,696,019 1888 448,567 2,018,552 1889 550,245 2.937.776 1890 510,499 3 213,795 I89I 587,988 3,651,150 1892 681,571 3,296,227 1893 941,368 4,136,070 1894 996,949 3,479,547 1895 1,038,551 3,606,094 1896 930.779 2,803,372 1897 1,039.345 2,673,202 1898 1,308,885 3,453,460 1899 1,515.702 5,084,076 1900 1,491,216 5,359,248 I90I 1,483,723 5,316,403 1902 1,490,314 4,693,444 1903 1,581,576 5.319,294 1904 1,874,428 6.580,875 1905 1,947,190 6,763,403 1906 2.080,957 8,579,437 1907 2.265,343 10,653,558 1908 2,386,138 31.594,279 11,399,124 1128,715,126 Of this quantity South Carolina has furnished 12,138,454 tons; Florida, 14,087,833 tons; Tennessee, 5,315,422 tons; and other states, 53,570 tons. In twenty-one years Florida has produced more phosphate than has South Carolina in thirty-two years. 130 SOIL FERTILITY AND FERTILIZERS Q « ■< ■< en / C .-I f-c O M 3 K a tH n _ o w 13 < Q n ►J T) fa qa g CO EA P r J H W Ul vi < s (4 (J o CIS III H •t. K pi< tfi o S ^ Tt rv. lO ro U 00 lo r-» "o - lOI^-** eq mao 1^00 > W lO »o "* ■<* lO^OO ««*- >^ \0 lO lO N o o^ o •J I-. lO CO" ■^ Tfr^ w HH rO rOvO " " " " Q O " O Q O N CO s ~ « rorO W t-. « W. >> i^ fO »o o Tl-kOOO VO 00 ■* 1- •- d r^ 1-.^ - a 00 Tj- CO" O N — ►-! I-. O »X> '^ HI CI W O ■«:f « l>.CO O O fDOO t-- '^ r|- O CO -Tf M 0^ lO '^ 0_ w 00 lO lO to « r^ r>.oo lovO ^D o r*o r^ r^ -i r-^ M CO O « GO vD rD r^ (7v lo r-. VO >0 H- -^ t-^ i^vo" "9 »o u-)\0 lO lovo r-00 o o o o O^ 0^ CTv ON VO VO vT) CO -_ O_C30_M oo" r^ d" d> r^ ►-. 00 CO 00 00 a* ON lO lO HH lO M t^ P) ON W vO 01 tJ- 0~ CO r~^ lO r^ w lo « M W M W N »-« N -^ W N O -^ t^VO Ov O ON lO r^ M lO TtOO N rv. t-^ lo rv. ■<^Tt ONCO ■4 --r (o-tF I^ •-( CO lO t^ t^OO CO VO O Tf rO r^oo lovo vO HH rO N tF o*co' n (O O^ N ON rt M N »-i I I ON- VO 00 ON CO w fOONOO (N) (orC f^ t-^ rO Tj- -rl- r^ ^ ^ CO M M fO ON t^ N lo r-«. « CO 00 VO VO ■^ lO 00 •<*- CO lO ■- CO ONOO -^ ■^ ON CO ON M On cor^ covo Ov •-< O VO ONJ>. 00 r^ -^ lo Tt — O N r>- ON ON lo c^ fC o" N~ O W CO t^ lO O CO lO w" n" pT t-T Ov lO-^ -^ coo ON- >-■ r*. lo H-" 00* o' -^ •* CO -I On r^i ■^ lO lO CO »OVO t^oo o o g o On On On On PHOSPHATES 131 The foregoing tables give the amounts of phosphate rock marketed by Florida, South Carolina and Tennessee classified into grades, for the years 1905-6-7-8. Exports. — The following table shows the production and ex- portation of phosphate rock since 1899: Production and Exportation of Phosphate Rock in the United States, 1899-1908, in Long Tons. Year Production 1899 1900 1 90 r 1902 1903 i9°4 1905 1906 1907 1908 Total 1,515.702 867,790 I,4c)i,2i5 619,995 1.483.723 729.539 1,490,314 802, ob6 I.58I.576 785.259 1,874,428 842,484 1.947,190 934,940 2,080,957 904,2 r 4 2,265,3J3 1,018,212 2,386,138 1,188,411 18,116,587 Exportation 1,692,930 Western Deposits. — Within the last few years a large area of phosphate-bearing rock has been discovered in the western United States. This discovery is of much importance since it opens a new field in an area which is tributary to the great agricultural region of the middle west. The phosphate occurs over a con- siderable area in southeastern Idaho, southwestern Wyoming, and northeastern Utah. It is found in rocks of "upper carbonif- erous" age in a series of shales and limestones, 100 feet Ihick, within which are several beds of phosphate rock ranging in thick- ness from a few inches to 10 feet. At the base of the series is a limestone, and 6 to 8 inches of soft brown shale separates this from the principal phosphate bed, which is 5 to 6 feet thick. This phosphate bed is high in phosphoric acid. There are in the series several beds ranging from a few inches to 10 feet in thick- ness, and separated by thin beds of limestone or shale. Usually one and sometimes two of these b'eSs at a given section are work- able, and probably some of the others will eventually be mined. The lime phosphate content in the workable beds varies from 56 to 80 per cent., with an average of 72 per cent. 132 SOIL FERTILITY AND FERTILIZERS is o N CO \o rf 00 m fO M lO fO q_ r^ « in fO 00 r^ ro 00 1 >. VO ■^ rO ■o \B o_ lO m -*; Tj- V 3 in w Tt M ^ t^ TT Ov VO * 00 * r^ -^t O r^ 5 o\ w 00 CO lO 1 > «%. pT CO' )_l O) WH 00 W 8 Q w >t rO ro ■^ CN H CO § m lO lO ^ ■^ CO M fO VO M 01 0^ fO NO ^ CD n m a^ VD On CO s fO Tj- r^ "^, Of w vC 00 w 'O ao 00 in ro ro M X ON t^ vo c\ ON O w 00 r* « • ^ pT ^o" *fi a CT^ _^ rj- r^ to 00 a\ o w o lO t^ o rO « w r^ •^ "^ »o a\ — { 5 1 c i '< I i <. 1 i ►i ' t 1 t 01 a a 1 _« a 1 1 "O c n 1 I HH .^ I 01 p. ^ a- 1 i- ^ ) c 1 PHOSPHATES 133 Development and Production. — The newness of the field, the lack of transportation facilities, and the high freight rates have prevented the development of this phosphate territory to any great extent, although there have been some shipments from Montpelier, Idaho, in the last three years. This field embraces the largest area of known phosphate beds in the world, and at some future time it will doubtless furnish a large part of the world's production of commercial fertilizer. The development of intensive farming as a result of the re- clamation of arid lands in the west will afford an increasing home market. Available Phosphate Deposits. — The known phosphate deposits of the United States are distributed principally among four lo- calities : (i) along the west coast of Florida, running back 20 to 25 miles inland; (2) along the coast of South Carolina, ex- tending 6 to 20 miles inland; (3) in central Tennessee ; and (4) in an area comprising southeastern Idaho, southwestern Wy- oming, and northeastern Utah. In addition to these areas, some deposits occur in north-central Arkansas, along the Georgia" Florida State line, and in North Carolina, Alabama, Mississippi, and Nevada, but these are mainly of low grade and not utilized at the present time. The three important deposits first men- tioned have been worked from ten to thirty years; the fourth is a new field which has as yet had but a small output. Estimated life of United States Phosphate Deposits. — The rate of increase in production for the last twenty years has been 117 per cent, for each decade. Assuming that this rate of increase will continue, it will require but a comparatively short time to exhaust the available supply of phosphate rock in the United States. The annual production, at the stated rate of increase, will be approximately 17,000,000 tons in 1932. It is hardly probable that the rate of increase in production will be so great as for the last decade, since the agricultural lands of the Middle West do not at present need artificial assistance. But increasing population, with its accompanying intensive farm- ing, will eventually force these .states to the use of fertilizing 134 SOIL FERTILITV AND FERTILIZERS materials. The reclamation of arid lands in the West will prob- ably postpone the day, but even those lands will early need some assistance to grow the large crops which will be required of them. Of course the vast amount of low grade rock which is now available will be in reserve, and some time before the exhaustion of the high grade phosphates we shall doubtless have begun to use this rock. The increasing price of the 60 to 80 per cent, phosphate will have a hastening effect on the utilization of the present low grade material. The deposits of Arkansas, Georgia, North Carolina, Alabama, Tennessee, and the West, which run from 30 to 50 per cent, in lime phosphate, will be available to draw upon after the high grade rock is exhausted. This class of deposits, especially in Tennessee and in the Western States, win afford an enormous tonnage, but, based upon present availa- ble deposits, the life of the phosphates must at best be a short one. Foreign Deposits. — Deposits of phosphate rock exist in Algeria, France, New Zealand, Canada, Russia, Spain, Tunis, Belgium, French Guiana, and some of the South Sea Islands. The de- posits of France and Belgium are practically exhausted, only those of low grade remaining. Concerning the other countries no infor- mation as to reserve tonnage is at hand' except for the three South Sea Islands — Ocean, Pleasant, and Makatea. These three islands have deposits which are estimated to aggregate 60,000,000 tons of high grade phosphate rock. Utilization of the iPhosphates. — From the foregoing pages it is evident that the utilization of our phosphate deposits to the best possible advantage is imperative. Our farm lands must be pre- served for future generations. The phosphate rock of South Carolina is nearly exhausted ; the Florida deposits have projjably reached their maximum production ; the output of the Tennessee deposits is on the increase, but this field alone would at the pres- ent rate of increase in production, last only a few years; there is some phosphate in Arkansas, but it is of low grade ; therefore the large deposits of the public land states of the West must be depended upon for the greater supply of phosphate rock in the PHOSPHATES 135 future. These Western deposits should be controlled by the government in such a way that only a limited amount may be mined and this amount should be saved for domestic consump- tion. It is seen that the most important deposits in this country are in Florida, South Carolina, and Tennessee and that the prodiiction in the United States amounts to over two million long tons (2,240 pounds) a year while that of the remaining countries ap- proximates one million tons. A glance at the tables is sufficient to impress one with the magnitude and value of this industry in the United States. South. Carolina phosphates were first put upon the market in 1868. There are two kinds of phosphates found in South Caro- lina, namely, the land and river phosphates. The land phosphate is mined from the land and is known as land rock, while the river phosphate is obtained by dredging rivers and is called river rock. These phosphates occur in the form of nodules varying in weight from a fraction of an ounce to more than a ton. Whether the rocks are mined or dredged, they are washed free from the clay and other adhering matter and dried, when they are ready for shipment. When phosphate rock is ground or pul- verized it is known as floats, and is used in this form in the middle western states quite extensively. The land rock is light fawn colored; the river rock is black; both are very hard. The South Carolina land rock averages about 50 per cent, tricalcium phosphate, which is equivalent to about 23 per cent, of phosphoric acid, and the river rock runs about 50 to 60 per cent, tricalcium phosphate, which is equivalent to 23 to 27.5 per cent, of phosphoric acid. Including the year 1908, South Carolina's total production of phosphates was 12,138,454 long tons of rock, of which about one- third was shipped to Europe. The discovery of the Florida phos- phates decreased the exportation of those from South Carolina to about 30,000 tons annually, because the Florida phosphates that are exported contain more phosphoric acid and less impuri- ties. 136 SOII< FERTILITY AND FERTILIZERS Analyses of South Carolina Phosphates."* Water Phosphoric acid (= tricalcium phosphate) Lime Iron oxide, alumina, magnesia, carbonic acid Silicious matter Total River rock 1-56 26.89 (58.70) 42.28 18.47 10.80 4.07 28.44 (62.09) 45-07 15.16 7.26 Land rock Per cent. Per cent. 7.40 26.50 (57.85} 37.20 16.27 12.63 10.30 22.06 (48.16) 37.24 15-45 14-95 Florida phosphates occur as soft phosphate, pebble phosphate ^^M^, «teliiL %^ii,a:n^ tii j^. _„. ..Ii^'i^^->^^j^^<»*'- ^V^x.-- : r - ..-..^y,^.^^,. ^ r'"^Xv -^' '' ''^'^SfS?'*'' ' - ^^"^^"^^ -Ci^^- :^:*^^ 0m.'^'~*^h>^ •' -' ""■';::,•■' ,' J^^ :■■' ■•■'""li^''': ':'"' -r^:' '' /■..:' .:■■;..., ^5--. 'h^?^^^-"- " ,,..•';-•*""■ ,■„■ /'"'••■' -^ - .■ . ■'W^^ %8'^ii**-.*if>,-~^~. j^ , - v^iSl-' /^ '^ ^ -^ : ;,^-^'' -^^-t •"»-*•■ ■ ' Fig. 15. — Mining phosphate rock, showing the water gun in action. and boulder or hard rock phosphates. The soft phosphate re- sembles a whitish clay and generally contains 50 to 60 per cent, of tricalcium phosphate, which is equivalent to 23 to 27.5 per cent. PHOSPHATES 137 of phosphoric acid. The hard rock ranges from 60 to 75 per cent, of tricalcium phosphate which is equivalent to 27.5 to 34.3 per cent, of phosphoric acid, ahhough many samples show even a higher content of phosphoric acid. Most all of the high grade phosphates of Florida are exported to Europe where they find a ready market. Florida has put out 14,087,833 tons of phos- phate rock from 1888 to 1908. In some Florida mines a water gun is used for mining the rock. The overburden, as sand, clay, etc., is removed, usually by steam shovels, and then a water gun is employed to shoot into the bank of phosphate rock, sand, etc., which is all washed down into a pool. It is then pumped with centrifugal pumps and elevated into a washer, where the rock is separated from the sand, water, and other foreign material. From there it is conveyed by cars to a bin called the Wet Rock Bin, from which the rock is transferred into large rotatory steel dryers. A flame passes through these cylinders, and as the rock comes out at the lower end it is elevated by a conveyor to a large house called the Dry Bin, from which the shipments are made to the trade. Analyses of Florida Phosphates.*' Moisture Phosphoric acid Rock Per cent. 0.53 36.72 Soft Per cent. 4.46 26.48 Low Grade Soft Phosphates.*' Water Silica Phosphoric acid (= tricalcium phosphate) . Iron oxide Alumina Lime Aluminum phosphate Calcium carbonate 1.77 9.62 36.90 24.42 21.49 19-93 (46.91) (43-55) 0.44 0.50 13.06 17.14 28.00 1.97 2.50 Tennessee Phosphates. — These are perhaps the most extensive deposits in the United States that are being worked. Their commercial importance was made known in 1893. The Tennessee 138 SOIIv FEKTII.ITY AND FERTILIZERS phosphates are known as brown rock, blue rock and white rock. About one-fourth of the high grade Tennessee phosphate is shipped to Europe the remainder being used in this country. The output of Tennessee phosphate has amounted to 5,315,422 tons from 1893 to 1908. The Tennessee rock phosphates are not in favor in Europe because of their high content of iron and alumina oxides, which run from 2 to 4.5 per cent. The brown rock has been sold more than the blue or white rock. Analyses of Five Samples of Brown Rock.^' Per cent. Per cent Per cent. Per cent. Per cent Insoluble (silica etc. ) Phosphoric acid Phosphate of lime Iron and alumina oxides • ■ Carbonate of lime Organic matters and water I-3I 36-55 79.80 2 00 13-27 3.62 256 36.55 79.80 2.48 12.05 3-11 1.85 35-47 77-45 3-i6 11.46 6.08 2.16 35-50 77..50 3.H8 14.29 3-17 5-87 32-85 71-73 4-52 9-93 7-95 The blue rock varies from 50 to 70 per cent, lime phosphate or 23 to 32 per cent, phosphoric acid. Composition of Blue Rock. Per cent. Phosphate of lime 50 to 70 Iron and alumina oxides 2.5 to 5 Silica 1. 5 to 5 White Rock. — There are several varieties of white rock vary- ing a great deal in composition. Analyses of Tennessee White Rock.'" Per cent. Per sent. Per cent. Per cent. Per cent. Per cent. Silica Linje Phosphoric acid Lime phosphate Lime carbonate . 61.34 20.30 12-55 27.40 9-75 49-43 26.40 15.12 33-00 15-21 54-30 22.87 14.86 32.45 9-36 54-88 22.76 ■5-30 33-40 8.23 50.18 25-57 15-21 33-20 13-45 56.46 22.01 ■3-15 28.60 ir.56 This phosphate, as is shown by the above analyses, contains a great deal of silica and is rather low in phosphoric acid. Not much of this product is consumed. By proper selection of this PHOSPHATES 139 grade of phosphate a higher product may be obtained than is represented in the above table. Canadian Apatite. — This is rock where the phosphate has be- come crystalline and is known as apatite and is found principally in the provinces of Ontario and Quebec. It is not mined very ex- tensively, only 748 tons being produced for 1907. It is a variable product and contains impurities. The Canadian apatite carries from 75 to 90 per cent, of tricalcium phosphate, which is equiva- lent to 34 to 41 per cent, of phosphoric acid. Preparing Canad- ian apatite for the market is a more expensive operation than mining the American phosphates. Apatite is usually considered one of the purest forms of tricalcium phosphate for manufactur- ing fertilizers. Composition of Canadian Apatites.'* Moisture Phosphoric acid ( ^ tricalcium phosphate) Lime Iron oxide, alumina, etc. • ■ • - Sandy matter Total O.II 37.68 (82.25) 51-04 6.88 4.29 100.00 0.62 33-51 (73-15) 46.14 7-83 11.90 o. 10 41-54 (90.68) 54-74 3-03 0-59 100.00 Rodunda Phosphate. — This phosphate is found on the Rodunda Island. Composition of Rodunda Phosphate." Water Phosphoric acid Alumina and iron oxides. Silicious matter Total 23-23 36-95 36-38 3-44 Per cent. 24.20 38-52 35-33 1-95 27.70 19.40 25-65 27-25 It is seen that this is not a phosphate of lime but a phosphate of iron and alumina. Although the per cent, of phosphoric acid is high, this material cannot be used to manufacture into acid phosphate because of the absence of lime. The gypsum (sulphate 140 SOIL FERTILITY AND FERTILIZERS of lime) formed in tlie manufacture of acid phosphate from phosphate of lime acts as a drier. Rodunda phosphate may be used for crops provided it is well pulverized but it must be con- sidered as slow acting. This product is sometimes called iron and alumina phosphate rock. Basic Slag. — This is known by several names as iron phosphate, Thomas phosphate powder, odorless phosphate, and phosphate slag. When phosphatic iron ores are used for the manufacture of steel by the basic process, an excess of lime is used which unites with the phosphoric acid and iron and forms a product known as basic slag. There is not much of this product manufactured in this country but the production is large in England, France and Germany. According to Wiley : "The quantity of basic slag manufactured in Germany in 1893 was 750,006 tons; in England 160,000; in France 115,000. making the total production of cen- tral Europe about 1,000,000, a quantity sufficient to fertilize nearly 5,000,000 acres. During the year 1907, it is estimated that German agriculture made use of from 1,500,000 to 1,600,000 tons of basic phosphate slags. The total output of basic slag is undoubtedly not far from 2.000,000 tons. The total production of basic slag is therefore approximately one-half of that of crude phosphates."'" Composition of Basic Slag Phosphate.'* Lime Magnesia Ferrous oxide • • - Ferric oxide Manganous oxide Alumina Phosphoric acid ■ Sulphuric acid • - ■ Sulphur Vanadium oxide • ' Silica Total 99-93 Per cent. Per cent. 41-54 45-04 6.13 6.20 14.66 11.64 8.64 5-92 3-81 3-51 2.60 1.72 14-32 18.H 0.31 0.41 0.23 0.30 0.29 0.24 7.40 6.90 99-99 This product is sold in the form of an impalpable powder which is black in color. The phosphoric acid in basic slag is often PHOSPHATES 141 rated as valuable as the phosphoric acid in bone-meal. The composition of this product is variable depending on the amount of phosphoric acid in the iron ore, but it is possible to obtain this product containing 23 per cent, of phosphoric acid, but the lower grades are most common. It averages about 14.20 per cent, of phosphoric acid. On account of the large amounts of iron oxide present, it is not suitable for manufacturing artificial fer- tilizers. Leavens says in part the following of basic slag:*" 1. The phosphoric acid in basic slag is in a form which can not revert or go back to more insoluble forms when mixed with the soil as is the tendency with all superphosphates. 2. The phosphoric acid in basic slag is not washed from the soil by the heavy rains and leached away in the drainage waters as is the case with many other phosphates. 3. Since the phosphoric acid in basic slag never wastes after application to the soil, it follows that basic slag may be applied at any time, either fall, spring, summer, or even in winter without danger of loss. 4. In addition to its high content of phosphoric acid, the large amount of lime in basic slag greatly adds to its value. Instead of having a souring effect on the land, as do superphosphates, basic slag on account of its strong alkaline reaction sweetens acid soils and restores them to a prodiictive condition. 5. Basic slag also contains a considerable amount of magnesia which is extreriiely valuable in changing crude forms of plant foods in the soil into forms which the plant may take up readily. So powerful is its action in this direction that it is often spoken of as "a chemical plow." 6. The large amount of iron in the basic slag should not be overlooked. "Iron" says Prof Sorauer, in his excellent treatise on the physiology of plants, "is necessary in the building of chlorophyll," the substance that gives the green color to all foliage. "As it is the function of chlorophyll to form new plastic material under the influence of the sunUght, it is natural that the absence of iron, which is shown by the paleness of the leaves, should cause a cessation of assimilation." 142 SOIL FERTILITY AND FERTILIZERS 7. In addition to all of the above, basic slag commends itself strongly on account of the high degree of availability to plants possessed by its phosphoric acid. While little or none of its phosphoric acid is soluble in pure distilled water, it is soluble in the secretions of the plant roots which feed upon it readily. Experiments indicate that the total phosphoric acid or basic slag is practically as effective as the available phosphoric acid of acid phosphate.*^ The average total results show that insoluble phosphoric acid, that is phosphates which have not been treated or dissolved in sulphuric acid (oil of vitriol), have more pounds of crop, both straw and marketable grain, than the phosphoric acid in the solu- ble and reverted forms ; that is, in phosphates which have been dissolved in sulphuric acid.^- 8. The comparative low cost of basic slag with resulting economy in crop production, is a matter that should appeal to every practical farmer. Slag phosphate plots produced a greater yield and at a less cost than the average of the soluble phosphoric acid plots and the bone-meal plots. All yields were produced at less cost with slag phosphates than with bone-meal. *- 9. While basic slag generally should not be mixed with ma- terials containing nitrogen in organic forms such as dried blood, ground bone, dried fish or tankage, many highly desirable and splendid combinations of it with nitrate of soda and potash salts may be made. By varying the amount of nitrate of soda and potash salts mixed with the slag, fertilizers adapted for use on all of our leading crops may be prepared. Wheeler states that basic slag is an effective source of phos- phoric acid for use upon all kinds of soils, and on account of its lime it is of special promise in the reclamation of exhausted acid soils, particularly such as are rich in organic matter, like many marsh or muck soils.*' Basic slag has been found useful for peaches, apples, grapes, oranges, and fruits in general, and for all the cereals. It has also proved very beneficial to clover, alfalfa, and the grasses. PHOSPHATES 143 Phosphatic Guanos. — These guanos are of the same origin as nitrogenous guanos. They are the excreta of sea fowls. Be- fore the phosphate deposits were discovered in the United States these guanos were imported into this country and used largely by the manufacturers. All of these guanos originally contained nitrogen. However, the nitrogen, soluble phosphates, and al- kalies have disappeared by decomposition of organic matter and leaching of water, so that most of them only contain traces of nitrogen. The phosphoric acid is in the form of tricalcium phosphate and insoluble in water. Some of these guanos contain too much iron and alumina oxides to manufacture profitably. They are not imported into the United States very much now, as many of the deposits are exhausted or else too expensive to compete with our native mineral phosphates. The following gives a list of the phosphatic guanos that have been used. Those printed in italics are still being shipped. Phosphatic Guanos. Maracaibo, or Monks Raza Island Curacao Baker Island Starbuck Enderbury Californian Aves Fanning Island Rowland Sidney Island Mejillones Lacepede Island Maiden Island Sombrero Browse Island Huon Island Patos Island Jarvis Island Cape Vert Phosphoric acid Per cent. 42 40 40 39 38 37 35 34 34 34 34 33 33 32 32 31 28 24 20 II The composition of some phosphatic guanos follow:^* 144 SOIL FERTILITY AND FERTILIZERS Water Organic matter. • • Phosphoric acid - - Lime Magnesia Iron oxide Alumina Potash Soda Sulphuric acid Carbonic acid Chlorine Fluorine Calcium carbonate Alkaline salts Insoluble matter- ■ Nitrogen . Aves Per cent. 6.83 7-03 33-12 42.62 2.03 I I (■ 2.16 • I J 1. 19 3-84 1.07 0-35 traces Cape Vert Per cent. 15-21 10.63 11-37 [ 20.49 j 0.92 41.06 0.03 Baker Island Per cent. 4.71 6.17 39-44 43-01 2.32 } 0.96 ] includes sulphuric acid 0.27 2-33 0.79 0-34 Sidney Island Per cent. 7-38 7.29 34-41 42-96 2-03 0.76 1.63 2-64 0.87 0.40 0.28 Mejillones Per cent. 8.98 8.36 32-59 38.57 4-30 3-34 3.86 It should be understood that there are many other phosphates used in other countries but they cannot compete with our mineral phosphates and therefore are not found on the American market- Classification of Phosphates. — From the foregoing it is shown that there are three classes of phosphates used for fertilizing purposes. r I I . Bone phosphates ^ I I I r I 2. Rock phosphates { Raw bone-meal Steamed bone-meal Bone-black Bone-ash Bone tankage Dry ground fish Florida South Carolina Tennessee L Apatite Rodunda phosphate Phosphatic guanos Land pebble River pebble Hard rock Land rock River rock Brown rock Blue rock White rock 3. Basic slag phosphates. Of the bone phosphates, bone-ash is not found much on the PHOSPHATES 145 American market and bone-black is usually acidulated (treated with sulphuric acid) before being applied as fertilizer. The production of rock phosphates in the United States has almost entirely discouraged the importation of the mineralized or phos- phatic guanos. Form of the Phosphates. — The phosphoric acid in bone phos- phates and rock phosphates is in the form of tricalcium phos- phate. Bone phosphates are always as phosphate of lime while rock phosphates contain more or less impurities as iron, alumina and silica. It is customary to apply the name, "bone phosphate of lime," to the phosphate present in rock phosphates, although tricalcium phosphate is the correct name. The phosphoric acid in basic slag is not in the same form as in the other phosphates. It was formerly accepted that the phosphoric acid in basic slag existed as tetra-calcium phosphate, but Hall" claims that the phosphoric acid is in the form of double phosphate and silicate of calcium CajCCaO) (PoJ^CaSiO,. Availability of the Phosphates. — All of the phosphates are slow- ly available as plant food and practically insoluble in water. The phosphoric acid in phosphates is not entirely used the first year so that maximum crop returns cannot be expected immediately, but the continued use of phosphates give good results. For quick growing crops the phosphates are not always desirable. The phosphates from bones are perhaps more readily decomposed than the rock phosphates. There is more or less organic matter in bones which decays quite rapidly and attacks the phosphoric acid with which it is closely associated. In the rock phosphates there is no organic decay and the impurities as iron and alumina retard to a certain extent the fermentation and decomposition of the phosphoric acid present. Basic slag phosphate as shown by the statistics in this chapter, is used extensively in Europe. European experiments show that this material is of higher avail- ability than the insoluble bone and rock phosphates. The nature of the soil has a great deal to do with the avail- ability of phosphates. Soils in good tilth will disintegrate the phosphates more readily than those in poor physical condition. The sandy and gravel soils are liable to give poorer results than 146 soil, fert;i,ity and fertilizers clay soils or soils containing considerable organic matter and potash. Organic matter tends to promote fermentations which attack the phosphates and make them available as plant food, and with the aid of potash, it tends to act upon the lime of the phosphates. The kind of crop also influences the rate of decom- position of phosphates. Some plants are more able to make use of the phosphoric acid of phosphates than others. The degree in fineness of phosphates influences the readiness with which they are acquired by plants. For this reason these products when used are usually ground very fine, especially basic slag which is ground to a powder. Wagner, a German investi- gator, obtained the following results with basic slag of various degrees of fineness. Availability of Basic Slag of Different Degrees of Fineness. Basic slag degree of fiueness Amount per acre in pounds Superphosphate • • Inpalpable powder Fine Coarse Barley 300 425 425 875 100 65 59 13 Wheat 100 61 61 13 57 55 16 In the above results the yields from 300 pounds of superphos- phate were taken as 100 and the yields from the basic slag were figured on this Basis. The results show that the finer the me- chanical condition of the basic slag the more available it is. This same condition is true for the other phosphates, as grinding gives a larger area for the soil acids to act upon. When a farmer wishes to use raw phosphates, the market value per unit of phosphoric acid should govern to a great extent his .^election. CHAPTER VIII. SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID. The phosphates mentioned in the previous chapter, with the exception of basic slag, are not always used in the raw condition for fertilizing purposes, but are treated with sulphuric acid in the manufacture of commercial or artificial fertilizers to make the phosphoric acid available; that is, to convert the phosphoric acid into forms that may readily be used by the plant as food. Manufacture of Super or Acid Phosphate. — The manufacturing of artificial fertilizers began some time after 1840 in which year Liebig, a German scientist, discovered that by adding sul- phuric acid (oil of vitriol) to bones the phosphoric acid was made soluble. This discovery paved the way for the manufacture of commercial fertilizers which are sold in such large quantities to-day. Manufacturing Sulphuric Acid. — The manufacture of super- phosphate is rather technical but a knowledge of this important industry may prove of interest. To begin with, the manufac- turer purchases pyrites of brimstone and phosphate rock. Py- rites is a compound of sulphur and iron and is obtained from Spain and mines in this country. The pyrites or brimstone are burned . in special burners and the sulphurous gases are mixed with nitrous gases obtained from nitrate of soda. These mixed sulphurous and nitrous gases are introduced into large high lead towers and then into lead chambers which are also large and high. Steam is introduced into the lead chambers, mixed with the gases and sulphuric acid is formed which falls to the bottom as a liquid. These lead towers and lead chambers are very costly. Preparing the Phosphate Rock. — The manufacturer purchases phosphates that contain sufficient tricalcium phosphate to warrant profitable treatment. Phosphates that contain considerable im- purities as iron and alumina are avoided. The phosphate rock is broken into small pieces by a machine called the crusher. These small pieces are then ground to a fine powder by special 148 SOIL FKRTILITV AND FERTILIZERS grinding machinery. This is an important feature in the suc- cessful manufacture of superphosphate as the finer the raw pro- duct the better is the finished material. When the phosphate is well pulverized the acid can more readily act upon it and so the decomposition is more complete, and an even, high class product is produced. There has been a great deal of money spent in securing machinery that would grind or pulverize phosphates. Some of the phosphates as apatite are extremely hard to pulverize. Making Superphosphate. — After the phosphate has been well pulverized certain amounts, say 1,000 pounds, of phosphate pow- der and dilute sulphuric acid (chamber acid) are weighed and dumped into a mixer, which is a cylindrical cast iron container furnished with a revolving shaft on which there are paddles or stirrers, to thoroughly mix or stir the acid and the ground rock. During this mixing great heat is evolved and the sulphuric acid attacks the lime which hold the phosphoric acid and unites with it to form sulphate of lime or gypsum. The phosphoric acid is still held by a small amount of lime. The acid used must contain enough water so that gypsum is formed to insure a dry product. The amount of acid to use depends upon the amount of phosphate of lime and carbonate of lime in the raw product. The acid first acts on the carbonate of lime and cannot act upon the phos- phate of lime until the carbonate is decomposed. Therefore the more carbonate of lime present in the raw material the more acid must be used. After the phosphate and acid are thoroughly mixed the mass is dumped into an iron car and the contents tilted into a pit or chamber. This process is repeated many times until the pit or chamber contains many tons of superphosphate. W^hen the mixture of sulphuric acid and powdered rock is first dumped into the pit, it is a semi-liquid mass and dries out in a few days and is ready for shipment. If it is allowed to remain too long in the pit, it becomes caked or hard and must be disinte- grated in special machines before being sacked. Chemistry of the Process. — The phosphoric acid is in the form of tricalcium phosphate in phosphates, or three parts of lime are united with one part of phosphoric acid. When the sulphuric acid is added it attacks the phosphate and dissolves it, setting SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID I49 free two parts of lime (that were originally combined with the phosphoric acid) which unite or combine with the sulphuric acid forming superphosphate (one lime phosphate or mono-calcic phosphate) and gypsum (sulphate of lime). In other words the phosphoric acid in superphosphate is only combined with one part of lime as the remaining two parts of lime, with which the phosphoric acid was formerly combined, have been set free. From the above it is evident that superphosphate is made up of one lime (mono-calcic) phosphate and gypsum (sulphate of lime). Or the reaction is: (3CaO, P.Os) 4- 2 (H2O, SO,) = (CaO, 2H2O, PjOj) + 2 (CaO, SO,) Tricalcic phosphate Sulphuric acid Monocalcic phosphate Gypsum Phosphates of Lime. — In the phosphoric acid fertilizers used there are four different forms of phosphates of lime, all of different availability. These phosphates of lime are known as the insoluble, soluble, reverted, and basic slag forms. 1. Insoluble Phosphoric Acid. — The most common form of phosphate of hme is that which is found in bones, mineral phos- phates, guanos, etc., and is called insoluble. The lime and phos- phoric acid are combined as three parts of lime and one of phos- phoric acid. This is called tricalcic, tribasic, bone phosphate and three lime phosphate. We may represent this form as fol- lows: I,ime ') Lime [• Phosphoric acid Lime .) This is the most insoluble form of phosphate of lime and is called insoluble phosphoric acid. 2. Soluble Phosphoric Acid. — When insoluble phosphate of lime is acted upon by sulphuric acid, two parts of lime are replaced by two parts of water and soluble phosphate of lime is formed. This soluble phosphate is called super or acid phosphate and is a saturated compound. It is also known as monobasic, mono- calcic, and one lime phosphate. This compound may be graphically represented as : Lime ") Water >■ Phosphoric acid Water ) 150 SOIL FERTILITY AND FERTILIZERS This form is entirely soluble in water and readily available as plant food. It is the highest valued form of phosphate of Hme and is called soluble phosphoric acid. 3. Reverted Phosphoric Acid. — Between the soluble and insolu- ble phosphate of lime there is another form known as reverted, citrate soluble, dicalcic, and two lime phosphate, in which there are two parts of lime and one part of water as represented : Lime ^ Lime [■ Phosphoric acid Water ) The name reverted is applied to this form of phosphate of lime because it is formed by reversion or retrograding of some of the soluble towards the insoluble. This form is not as solu- ble as the soluble phosphoric acid and is more soluble than the insoluble form. It is insoluble in water, but the weak acids of the soil render it favorable for plant food. The sum of the soluble and the reverted is called available, because both forms may be used by plants. 4. Basic Slag Phosphate. — It used to be accepted that the three forms just described were the only forms of phosphoric acid. However, the phosphate of lime in basic slag is in another form. It was supposed that one part of phosphoric acid was combined with four parts of Hme, and in this form it was known as tetracalcic, tetrabasic, and four lime phosphate. Lime 1 J . J- Phosphoric acid Lime J Recently, however, there seems to be some uncertainty as to whether or not the phosphoric acid in basic slag exists as tetra- calcic phosphate of lime. Hall says: For example, basic slag is found to be readily attacked by a solution of carbon dioxide or other very weak acid ; a much larger proportion of phosphoric acid goes into solution than would be the case with an equally fine ground sample of tricalcium phosphate containing the same amount of phosphoric acid. Nearly the whole of the phosphoric acid in basic slag also goes into solution when it is shaken with an SUPERPHOSPHATES AND EEFECT OF PHOSPHORIC ACID 15I alkaline solution of ammonium citrate, in whch tricalcium phos- phate is not very soluble. The analysis of certain flat square plate crystals, occasionally found in cavities in the balls of slag proved them to consist of a tetrabasic phosphate of calcium of the formula (CaO)4P|205, the molecule of phosphorus pentoxide being combined with four molecules of lime instead of vsfith three as in ordinary calcium phosphate. To this tetrabasic phosphate of lime the properties of basic slag have usually been ascribed, it is supposed to be readily acted upon by carbon dioxide with the formation of calcium carbonate and dicalcium phosphate, and as this latter phosphate is readily soluble in water containing carbonic acid, the availability of the basic slag is accounted for. But it is by no means certain that this association of tetra- calcium phosphate with basic slag is correct. In the first place, the detailed analysis of the basic slag hardly bears out this view ; there is more lime than is necessary to make up tetracalcium phosphate even when every allowance is made for silica and sulphur, and the amount of free lime that can be determined is not sufficient to make up the balance. Moreover, the crystals of tetracalcic phosphate are only to be foynd in basic slags made from irons poor in silicon ; the usual crystals found in the basic slag cavities are long hexagonal needles, pale green or blue in color, of which considerable quantities can be picked out from the cindery portions of the slag. The appearance also of a fractured surface of the ordinary molten parts of the slag would agree much better with a structure built up of such prismatic crystals than of the flat crystals of tetracalcium phosphate. The prismatic crystals, according to Stead, consist of a double sili- cate and phosphate of lime of the composition (CaO)5P,Or,SiO,, and contain about 29 per cent, of phosphoric acid, 11 per cent, of silica, and 56 per cent, of lime. Moreover, when separated from the mass of the cinder, finely ground, and attacked with water charged with carbon dioxide or with very dilute citric acid, the phosphoric acid they contain shows approximately the same solubility as that of the phosphoric acid in an ordinary sample of basic slag, whereas the crystals of tetrabasic phosphate of lime are markedly less soluble. On the whole, it seems more 152 SOIL FERTILITY AND FERTILIZERS probable that the typical phosphoric acid compound of basic slag is this (CaO)5Pa05Si02 — and not the tetracalcium phos- phate, (CaOjjPaOr,, especially as there is plenty of other evidence to show how large a part silica will play in bringing phosphoric acid into a soluble state. Whatever may be the form of combination of the phosphoric acid in basic slag, it is undoubtedly easily attackable by the soil water, so that it is more available to the plant than any of the forms of tricalcium phosphate, though as a rule it falls below superphosphate." Amounts of Acid to Dissolve Phosphates. — Voorhees states: Mineral phosphates, both because of their hardness and of the presence of other minerals, which are attacked by the acid, are less easily dissolved, and require more acid in proportion to the phosphate present than those from organic sources. They are also less absorbent, preventing the acid from permeating the mass of the material, and hence it is more difficult to secure good condition when sufficient acid is used to dissolve the phosphate. In making superphosphates from these materials, less acid is used than is required to completely dissolve the phosphates, and there is, therefore, always present in them more or less of the insoluble phosphoric acid. In the case of animal bone, too, less sulphuric acid is used than is required to completely dissolve the phosphoric acid. Other- wise, a gummy, sticky product would result, due largely to the organic matter in the bone. The insoluble phosphoric acid in bone, bone-black, and bone-ash superphosphates is, however, of greater value than the insoluble in the mineral phosphates, for reasons already given. In superphosphates, too, there is nearly always present a great- er or less amount — depending upon the material — of the second form of phosphoric acid, the dicalcic, reverted or retrograde. This form usually exists in the greatest amounts in those made from mineral phosphates, which is believed to be due either to the soluble acting upon the insoluble portions, or to the presence of oxide of iron and alumina, which combine with a portion of SUPERPHOSPHATBS AND EFFECT OF PHOSPHORIC ACID 1 53 the soluble phosphoric acid. The soluble goes back to the less soluble dicalcic form.*^ The Eeversion of Phosphoric Acid. — Aikman says: A change which is apt to take place in superphosphate after its manufac- ture is what is known as reversion of the soluble phosphate. Thus it is found that on keeping superphosphate for a long time the percentage of soluble phosphate becomes less than it was at first. The rate at which this deterioration of the superphos- phate goes on varies in different samples. In a well-made arti- cle, it is practically inappreciable, whereas in some superphos- phates, made from unsuitable materials, it may form a consid- erable percentage. The causes of this reversion are two-fold. For one thing, the presence of undecomposed phosphate of lime may cause it. This source of reversion, however, is very much less important than the other, which is the presence of iron and alumina in the raw material. When a soluble phosphate re- verts, what takes place is the conversion of the monocalcic phos- phate into the dicalcic. Wherever reversion is due to the presence of iron and alumina in the raw material, the nature of the reaction is not well under- stood, and is, consequently, not so easily demonstrated as in the former case. Where iron is present in the form of pyrites, or ferrous silicate, it does not seem to cause reversion. It is only when it is present in the form of oxide (and in most raw phos- phatic materials it is generally in this form) that is causes re- version in the phosphate. Value of Reverted Phosphoric Acid. — The value of reverted phosphate is a subject which has given rise to much dispute among chemists. That it has a higher value than the ordinary insoluble phosphate is now admitted, but in this country (Eng- land), in the manure trade, this is not as yet recognized. At first it was thought that it was impossible to estimate its quantity by chemical analysis. This difficulty, however, has been over- come, and it is generally admitted that the ammonium citrate process furnishes an accurate means of determining its amount. Both on the continent and in the United States reverted phos- phoric acid is recognized as possessing a monetary value in ex- 154 SOIL FliRTILITY AND FERTILIZERS cess of that possessed by the ordinary insoluble phosphates. The result is, that raw mineral phosphates containing iron and alumina to any appreciable extent are not used in this country (England), although they do find a limited application in America and on the continent.-* Difference Between Phosphates and Superphosphates. — It is cus- tomary among some farmers to call every fertilizer a phosphate and among others this name is used for the product — superphos- phate. A phosphate is a product containing phosphoric acid as its main ingredient, in the insoluble form, as bone phosphates, rock phosphates and basic slag phosphates. A superphosphate is a fertilizer containing principally soluble phosphoric acid. The phosphates, except basic slag, may be manufactured into superphosphates by the addition of sulphuric acid as previously mentioned in this chapter. Thus we have superphosphates from bones and minerals, as raw bone superphosphate, steamed bone superphosphate, bone-ash superphosphate, bone-black superphos- phate, Florida hard rock superphosphate, Florida pebble super- phosphate, Florida soft rock superphosphate, South Carolina land rock superphosphate. South Carolina river rock superphos- phate, Tennessee brown rock superphosphate, Tennessee blue rock superphosphate, Tennessee white rock superphosphate, etc. Of course all of these superphosphates will not contain the same amounts of soluble phosphoric acid, as the mode of manufacture and content of phosphoric acid in the raw products determine this. A superphosphate made from bone-black containing 30 per cent, of phosphoric acid will be richer in soluble phosphoric acid than one made from South Carolina land rock running 23 per cent, of phosphoric acid. Bone-black and bone-ash because of their higher phosphoric acid contents make richer superphos- phates than those manufactured from most of the mineral phos- phates. Some Names Applied to Superphosphates. — Acid phosphate, dis- solved bone, dissolved bone-black and dissolved bone-ash are names that are used indiscriminately by the trade. A manufac- SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 1 55 turer may call a product made from rock phosphate, "dissolved bone," and sell it under this name. Dissolved bone, strictly speak- ing is a dissolved bone superphosphate, or a superphosphate made from raw or steamed bones. Dissolved bone-black is a super- phosphate manufactured from bone-black. Dissolved bone-ash is a superphosphate made from bone-ash. The superphosphates made from rock phosphates are usually called acid phosphates by the trade, although this latter term is applied to any superphos- phate and is perhaps a more common name in the United States than superphosphate. For superphosphates made from ground rock phosphate, acid phosphate is perhaps a more correct name as it is the phosphate acted upon by acid. Available Phosphoric Acid. — There seems to be a great deal of confusion among farmers over what constitutes available phos- phoric acid and this is not to be wondered at when one considers the number of terms applied to reverted and insoluble phos- phoric acid. Reverted phosphoric acid is soluble in the weak acids of the soil. The chemist uses a solution called ammonium citrate or citrate, which has a similar action to the weak soil acids, in dissolving out this form of phosplioric acid. For this reason the term citrate soluble is often applied to reverted phos- phoric acid. The insoluble phosphoric acid is not soluble in this citrate solution but it is soluble in strong acids; hence the names citrate insoluble and acid soluble are applied to insoluble phosphoric acid. Reverted phosphoric acid is equivalent to citrate soluble phosphoric acid. T luii. I.- -J- -i^if citrate insoluble phosphoric acid Insoluble phosphoric acid is equivalent to | ^^.^ ^^j^y^ phosphoric acid. The sum of the soluble and reverted phosphoric acid is called available phosphoric acid, or the sum of the soluble and citrate soluble phosphoric acid is available phosphoric acid. The farmer often confuses the term acid soluble as belonging to the available phosphoric acid on account of the use of the word soluble. Again, the difference between the total phosphoric acid (which is the sum of the soluble, reverted and insoluble forms) and the insoluble phosphoric acid is available phosphoric acid. 156 SOIL FERTILITY AND FERTILIZERS Available phosphoric acid : f soluble + reverted phosphoric acid soluble -j- citrate soluble phosphoric acid I ^ total — insoluble phosphoric acid I total — citrate insoluble phosphoric acid [.total — acid soluble phosphoric acid. f soluble + reverted -j- insoluble phos. acid I soluble -j- reverted + acid soluble phos. acid Total phosphoric acid = ] ^°|"^i^ + "^^J"'^"^ + citrate insol. phos. acid *^ '^ 1 soluble + citrate soluble + insol. phos. acid I soluble -j- citrate soluble -j- acid sol. phoS. acid [soluble 4- citrate soluble -f- cit. iii.'sol. phos. acid. The available phosphoric acid contained in manufactured fer- tilizers for 1900 and 1905, in short tons, was as follows:"^ Bones, ammoniates, etc Tankage, etc Fish products Cotton-seed products Phosphate rock (acid phosphate). Total 278,701 1900 Tons •905 Tons 16,177 13.455 1,768 879 246,422 15,162 11,127 3.565 1,100 273.241 304,195 The Difference of the Forms of Phosphoric Acid in Superphos- phates. — In the manufacture of superphosphates not all of the tricalcium phosphate is converted into soluble phosphoric acid. The manufacturer generally calculates to add just enough acid to convert most of the phosphoric acid into the soluble form. However he does not wish to add much acid in order to put a profitable marketable product. Hence most of the superphos- phates found on the market contain some insoluble phosphoric acid, ranging perhaps from a few hundredths to as high as four per cent, in poor acidulation. This insoluble phosphoric acid in superphosphates is different. That in the bone superphos- phates is of more value as regards availability than the insoluble phosphoric acid in the mineral superphosphates. The insoluble phosphoric acid is also of different value in the mineral super- phosphates depending upon the nature or purity of the rock from which it was made. However, the insoluble phosphoric acid in super or acid phosphates is generally present in small amounts and would only have to be seriously considered when the acidula- tion proves insufficient. The soluble phosphoric acid in all sup- SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 1 57 erphosphates is the same, whether the superphosphates are made from bones, bone-ash, bone-black, or any of the mineral phos- phates. It is an erroneous opinion among some, that the material from which the superphosphate is made influences the value of the soluble phosphoric acid. Many farmers would rather pur- chase soluble phosphoric acid as superphosphates manufactured from bones than soluble phosphoric acid from mineral super- phosphates. There is not any difference in the soluble phos- phoric acid of superphosphates no matter what raw material is used in making it. Of course a dissolved bone superphosphate will perchance give better results than a raw rock superphos- phate of equal soluble phosphoric acid composition as the dis- solved bone superphosphate will contain in addition to the phos- phoric acid, a certain amount of nitrogen ; so if we judge the value of soluble phosphoric acid in this way we are assuming an unequal and unfair task. Some Farmers Favor Bone Superphosphates. — Many farmers seem to be prejudiced against the mineral superphosphate- and always demands superphosphates made from bone. Often the price is much higher for the bone superphosphates on account of the greater price bones bring when sold for bone-black, manu- facturing interests, etc. These farmers could generally pur- chase their phosphoric acid more cheaply from mineral super- phosphates. Of course when dissolved bone and mineral super- phosphates of equal available phosphoric acid content, are offered for the same price, it is more economical to select the dissolved bone; but it is seldom that one can get such a bargain as the dealers in fertilizers always charge for the ammonia content. Generally phosphoric acid can be purchased cheaper from mineral superphosphates than from dissolved bone superphosphates. Double Superphosphate. — This is sometimes called double phos- phate. This double superphosphate is manufactured as follows: Phosphates are treated with an excess of sulphuric acid (cham- ber acid) and the phosphoric acid is dissolved out as free phos- phoric acid. The fluids, sulphuric acid and phosphoric acid are filtered or separated from the insoluble matter and concen- trated. This concentrated solution is then used in dissolving 158 SOIL FERTILITY AND FERTILIZERS high grade phosphates and the resulting product is called double superphosphate because the phosphoric acid content is more than double and generally three times as much as in superphosphates. Wiley^" suggests that superphosphate is a more correct name for this class of material as it is a phosphate acted upon by free phosphoric acid and superior to acid phosphate. Phosphates con- taining too low a percentage of phosphate of lime for profitable manufacture of acid phosphate may be utilized in obtaining the free phosphoric acid. Not much double superphosphate is found on the American market but it is quite popular in Germany where it is manufac- tured principally. Double superphosphates contain about 40 to 45 per cent, of available phosphoric acid. They contain less im- purities than acid phosphates. The phosphoric acid is present in the same forms as in acid phosphate, namely as soluble, reverted and insoluble phosphoric acid. Double superphosphates are expensive but sometimes economical to purchase when freight is high. No Free Acid in Treated Phosphates. — Acid phosphates and double superphosphates when well manufactured do not contain any free acid as all of the sulphuric acid is united with lime and forms gypsum. Of course it is possible for a manufacturer to make a product that will contain free acid, but this is not done and the product delivered to the trade does not contain any free acid. The Color of an Acid Phosphate. — There seems to be a prefer- ence among some for a light colored acid phosphate while others demand a dark colored product. The color and nature of the raw material from which acid phosphates are made determine their final color. The manufacturers in order to satisfy the trade often carry two different colored acid phosphates of the same chemical composition which are made from the same raw product. The dark or black color is obtained by mixing in lamp- black when the final product is not sufficiently dark. Some raw materials as bone, bone-black, etc., produce a black superphos- phate without the addition of any coloring substance. The color of an acid phosphate does not indicate its fertilizing value. SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 159 Average Composition of Superphosphates and Double Superphosphates. Acid phosphate Acid pliosphate Acid phosphate Dissolved bone-black • . Dissolved bone-meal . . . Dissolved bone-ash . . . Double superphosphate Total Available Phos. acid Phos. acid Per cent. Per cent. 14 12 16 14 18 16 17-5 16.S 16.5 12.5 28 26 48 1 43 The most common of the above fertilizers found on the Ameri- can market are the acid phosphates carrying 14 per cent, of avail- able phosphoric acid. How to Make Superphosphate at Home. — Sometimes farmers live far away from places where fertilizers may be purchased and should such farmers save the bones that accumulate on the farm, superphosphate may be made at home. The process may be con- ducted as follows ; Break up the bones in as small pieces as pos- sible and add one-third their weight of water to them in a long wooden trough lined with sheet lead or with a thick coating of pitch ; the lead is better. To the bones and water, add very slow- ly sulphuric acid (oil of vitriol). This acid must be added very slowly as great heat is evolved on the addition of sulphuric acid to water. The amount of acid to add depends upon its strength or concentration. About one-third the weight of the bones of strong white sulphuric acid or one-half of the brown sulphuric acid should suffice. The whole mass should be thoroughly mixed with a wooden shovel, allowed to stand for an hour and removed to some dry place and stored for two months when it will be ready for the land. If sulphuric acid gets on your clothes it will ruin them and it will burn the skin wherever it touches it. Amount of Phosphates Used for Manufacturing Fertilizers. — The following table gives the tonnage of bone products, tankage, and rock phosphates used in the manufacture of fertilizers in the United States for 1900 and 1905 in short tons.^^ l6o SOIL FERTILITY AND FERTILIZERS 1900 Tons Tons Bone products Tankage 168,510 354,075 958,802 236,906 439,206 1,063,195 PhosT)ha.te rock Phosphoric Acid Removed by Crops. — ^According to \'oorhees ;" the crops of the United States take away from the soil 7,000,000 tons of 14 per cent, acid phosphate annually. There are also large losses by erosion and drainage. So it is probable that at least 1,000,000 tons of phosphoric acid are required to restore the losses of phosphoric acid anmially. Hopkins^" says : "To restore to the soils of the United States the phosphorus (P) removed by the corn crop alone, would require the annual application of our total annual production of phosphate rock, counting 23 pounds of phosphorus for a hundred-bushel crop of corn, and 2^ billion bushels as the average corn crop of the United States." The following table shows the amounts of phosphoric acid re- moved by some common farm crops. Grain contains more phosphoric acid than straw and roots take away more than tops. Sugar-beets, mangels, turnips, cab- bages and onions take away a great deal of phosphoric acid from the soil. Amount of Phosphoric Acid in Soils. — The phosphoric acid in soils is generally found in largest amounts in the surface soil and is usually derived from the disintegration of rocks. It is often deficient and many soils show only traces of phosphoric acid. Even fertile soils only contain small amounts of this con- stituent. Soils average from traces to 0.25 per cent, of phos- phoric acid. We may figure that an average soil contains about 3,500 to 4,000 pounds of phosphoric acid per acre. Only a small amount of this is available. Some soils may contain large quan- tities of phosphoric acid but the poor condition of the soil keeps this locked up so that plants cannot utilize it. Organic matter, lime and good tillage help to increase the available supply of phos- phoric acid. SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID i6[ Weights of and Phosphoric Acid Removed by Ordinary Crops IN Pounds Per Acre." Meadow hay, i% tons Timothy hay, I'/i ton.s Clover hay, 2 tons Wheat Grain, 25 bus Straw Total Rye Grain, 30 bus Straw Total Oats Grain, 50 bus. Straw Total Barley Grain, 50 bus Straw Total Corn Kernel, 50 bus Cobs Stover Total Potatoes Tubers, 200 bus Haulm (stems) Total Sugar-Beets Roots, 20 tons Tops Total Mangels Roots, 25 tons Tops Total Turnips Roots, 20 tons Tops Total Swedes Roots, 16 tons Tops Total Cabbages, 20 tons Onions, 500 bus Tobacco, leaf Wt. as harvested Phosphoric acid 3,000 3.000 4,000 13.6 21.0 22.4 1,500 2.500' 4,000 12.4 5.8 18.2 1.680 2.000 14.8 5-4 3,680 20.2 1,600 2,100 11.4 6.3 3.700 17.7 2.350 2.800 5.150 19.2 5-4 24.6 2.800 700 2 300 5,800 16.40 0.04 8.74 25.18 14,000 4.500 18,500 18.9 6.8 25-7 40,000 20,000 60,000 25.2 23-3 48.5 50,000 18,500 68,500 29.4 16.7 46.1 40,000 11.600 51,600 38.7 13.2 51-9 32,000 4.800 3t>,boo 40,000 28,500 1,500 18.4 4-9 23-3 48.6 32.4 10.8 1 62 SOIL FERTILITV AND FERTILIZERS Fixation of Phosphoric Acid. — When soUible phosphoric acid is added to soil it becomes iixed and does not wash out readily. Crawley** found that when a fertilizer containing water soluble phosphoric acid was applied to the soil and followed by irriga- tion, more than one-half of the soluble phosphoric acid stayed in the first inch of the soil, more than nine-tenths remained in the first three inches, and about all of it in the first six inches. Soluble phosphoric acid is added to soils because a better distri- bution is affected, but Crawley's results show that this form of phosphoric acid does not distribute so readily as has been sup- posed, even when there are heavy rains or irrigation. The soils Crawley worked on were suitable for fixing phosphoric acid and not so acid as many of our soils. Experiments conducted at Rothamstead show that phosphoric acid is retained in the surface soil. PHO.SPHORIC Acid Soluble in Five Extractions With One Per Cent. Citric Acid, Compared With That in Manure and Crop.' Phosphoric acid pounds per acre Supplied in Removed in Surplus in Dissolved by i per manure crop soil cent, citric acid 550 —550 565 3,960 790 3-170 3-000 3-810 1-370 2,440 2,470 3.810 I-520 2,290 2-055 555 —555 400 3.390 1,200 2,190 2,315 3.390 1,240 2,150 2,000 The above table shows that the phosphoric acid applied to the soil is all accounted for by the removal of crops and the surplus. It shows that the phosphoric acid did not leach out of the soil. The soils of this experiment were well supplied with carbonate of lime which was favorable to the extraction of the phosphoric acid by the citric acid. It is generally supposed that soluble phosphoric acid from fer- tilizers becomes readily distributed and unites with the minerals forming compounds insoluble in water; the phosphoric acid in SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 163 soluble phosphoric acid is in a very finely divided state and the distribution takes place before the insoluble compounds are formed. Soils rich in lime readily fix phosphoric acid and a certain amount is probably fixed in combination with iron and alumina. Experiments show that phosphoric acid is not carried away by leaching to any extent. All soils are not of equal fixa- tion value ; most soils fix phosphoric acid but some are better equipped to perform this process than others. Clay soils rich in lime fix phosphoric acid very rapidly while soils deficient in lime act much slower in this respect. Sandy and gravel soils, lacking in organic matter and clay, do not fix the phosphoric acid rapidly. Absorption of Phosphoric Acid. — Jofifre states : That contrary to what is usually thought, the combinations soluble in water ap- pear to be absorbed by vegetation. The proportion absorbed is, without doubt, very small, but it may have a very great import- ance because the absorption takes place at a moment when the plants have vtsed up the material in the seed and have not yet developed sufficiently to evaporate the large quantity of water and to be able thus to extract from the soil the useful sub- stances, difficultly soluble, which there exist. This theory explains perfectly the results of the remarkable researches of Schloesing and Prunet who have found that, when fertilizers are planted in the rows, they produce greater effects than when they are mixed with the soil. This evidence depends upon the fact that when they are planted in rows, they become soluble less rapidly and the plants thus have more time to absorb the combinations of phosphoric acid soluble in water. Moreover, in the culture experiment made in pure sand where there was nothing which could produce insolubility of phosphate soluble in water and where it is seen that this body causes an in- crease in the crops, it is necessary to admit that the combinations of phosphoric acid soluble in water enter into the plant and are assimilated there. I have not said that insoluble phosphate is without utility in agriculture. It produces, indeed, in certain earth eiifects which are as beneficial as the soluble phosphate, but in the greater part of soils, if it produces an action, this action x64 soil, FERTILITY AND FERTILIZERS is less than that of superphosphates and the inferiority of this action appears to be caused, at least in part, because no portion of it can enter immediately into the plant in a condition of aqueous solution. To resume, the whole of my experiment seems to make clear that the favorable action of superphosphate is not only caused by a greater dissemination of the combination of phosphoric acid in the arable earth, but that it is also necessary to take into ac- count the absorption in the form of combinations, soluble in water, of a portion of soluble phosphoric acid of superphos- phates. If we desire to obtain a maximum result it is necessary to distinguish two sorts of soil; first, the soil analogous to those, of which numerous examples are found in Bretagne, in which insoluble phosphates succeed as well as superphosphates and where it is natural to employ phosphate simply ground. Second, the other soils which are far more numerous and in which the phosphoric acid fertilizers in combinations soluble in water are absolutely indispensable to obtain the maximum effect.*' Functions of Phosphoric Acid. — Phosphoric acid hastens maturity of crops. It has a ripening effect and seems to hasten grain and fruit formation ; it stimulates root development in young plants. The influence of phosphoric acid on grain formation is shown in the following table. Effect of Phosphoric Acid on Barlev.' Grain Bushels Grain to 100 straw Nitrogen per cent. in grain 1893 1894 1893 1894 1893 1894 11.6 18.1 i6.8 30.8 10.4 34.9 17.8 41.4 85-3 lOI.O 85.9 102.2 67-5 77.0 73-8 77.7 2.19 2.13 2.17 2.08 1.65 1 60 Ammonium salts and super- Ammonium salts and potash ■ Ammonium salts, superphos- 1.61 1.44 The year 1893 was a particularly dry one and in 1894 there was considerable rain and the season was very wet. It is seen that the phosphoric acid increases the yield of grain SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 165 and of grain to straw. It also decreases the nitrogen in the grain. The same effect of phosphoric acid is shown on wheat. Effect of Phosphoric Acid on Wheat.' Grain Bushels Straw Cwt. Weight per bushel Pounds Grain to 100 straw Wet season, 1879 Untnanured Nitrogen only Nitrogen and phosphoric acid Nitrogen, phosphoric acid and potash Dry season, 1893 Unmanured Nitrogen only Nitrogen and phosphoric acid Nitrogen, phosphoric acid and potash 4-5 4-3 II. I 16.0 10.7 8.4 7-7 16.4 6.7 8.5 18.0 27.2 5-6 5-6 6.2 9-7 51.8 50-8 54-6 57-8 62.5 59-1 56.4 62.6 42.8 33-6 36.2 35-2 110,3 84.4 67.3 98.0 Experiments conducted at the Ohio Experiment Station on a rotation of potatoes, wheat and clover from 1894 to 1908 showed greater yields from phosphoric acid than from nitrogen and pot- ash. The Pennsylvania Experiment Station conducted a rota- tion from 1885 to 1908 with corn, oats, wheat and hay on four acres of land with similar results and the Iowa Experiment Sta- tion found that phosphoric acid increased the yield of clover more than did lime, manure, and potash. Many other experiments have been conducted showing that phosphoric acid helps to in- crease the yield of grain crops. Experiments indicate that a better root system is had when phosphoric acid is available to the young plant. Phosphoric acid helps in transferring substances from the stalks, leaves, and other growing parts to the seed. Certain substances are aided by phosphoric acid by being rendered soluble enough to pass through the plant tissues. Phosphoric acid helps to build up protein substances in the plant as certain proteid bodies require phosphoric acid for their i66 SOIIy FERTILITY AND FERTILIZERS complete development. Therefore a lack of phosphoric acid would necessarily cause the plant to suffer. Crop Returns of Fhosphatic Fertilizers. — The Ohio Experiment Station ran an experiment for seven years to find out the crop increase of certain commercial (artificial) fertilizers compared to raw and steamed bone-meal. As we are interested in the latter two products the results are here given for these. Increase per acre Corn Bushels Wheat Bushels Hay Pounds. 6.40 11.02 13.22 J 1,309 The bone-meals were applied at the rate of 200 pounds per acre to the corn and wheat, which were grown in rotation, fol- lowed by clover for one year. It is evident that the steamed bone-meal gave the better results and at the price of these pro- ducts the phosphoric acid in the steamed bone-meal was the cheaper. Hall" gives returns from phosphatic fertilizers in the follow- ing table. Returns From Phosphatic Fertilizers. 1878 1879 l83o 1881 Swedes Tons Barley uii manured Total produce Pounds Seeds hay unmanured Pounds Oats manured Total produce Pounds Ground rock phosphates Raw bone-meal Phosphatic guano Dissolved rock phos- 150 134 154 15.8 15-1 13-1 5,844 6,052 6,016 5,964 6,364 5,955 3.850 4,150 3.380 4,130 4.430 3.350 5.9II 6,686 6.726 7,696 7,460 7,132 Dissolved bone-meal . . . The results in the above table show lower yields for the raw products than for those that were treated with acid. It is rather to be expected that the raw materials should give lower SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 167 returns because they are slow acting and do not give up phos- phoric acid so readily as the superphosphates that contain their phosphoric acid mostly in the soluble form. Considering the price that raw bone-meal carries the results are disappointing, showing that this product cannot be economically purchased for fertilizing purposes. It is to be expected that raw bone-meal on account of the fatty matter should be slowly disintegrated. Steamed bone-meal usually gives good results on certain crops. The returns from raw rock phosphate however deserve consid- eration as this product can be purchased for about one-half of what acid phosphate costs. For certain crops therefore it is often advisable to use raw rock phos_^ihate finely ground. Experiments at the Ohio Experiment Station gave favorable results with a combination of ground rock phosphate and stall manure on corn, wheat and clover grown in rotation. In this experiment a comparison was made with mixtures of rock phos- phate and manure, and acid phosphate and manure, with the result that the above crops were grown for about one-half the cost with the raw rock phosphate. For quick growing crops acid phosphate is no doubt more satisfactory unless the raw rock phosphate is decomposed and rendered available in some way to satisfy the needs of such crops. Field Experiments with Nine Phosphates. — The Rhode Island Station started an experiment in 1894 to ascertain fhe relative values of the different phosphatic fertilizers. Quoting from this work: According to the original plan like money values of phosphate were to be compared, and the applications were made for several years upon that basis. Owing, however, to the widely varying market prices from year to year, it was decided in 1898 to change the plan of the experiment so as to make it a comparison of like amounts of phosphoric acid. The crops of 1894 and 1895 were Indian corn and oats, re- spectively. In the autumn of 1895 the land was replowed and seeded to clover and grass, as follows : Seed per acre Timothy 12 quarts Redtop 6 pounds Medium red clover 12 pounds l68 SOIL FERTILITY AND FERTILIZERS Owing chiefly to the dryness of the soil, a stand of clover was not secured, and medium red clover seed was sown again, the next April, at the same rate. On account of the fact that some of the phosphates con- tained soluble phosphoric acid while others were practically insoluble in water, all of the more insoluble phosphates were sown broadcast after plowing, and were then thoroughly har- rowed into the soil before seeding. These applications were made sufficiently large to cover the crop requirements during the three years that the land was expected to be left in grass. It was planned to divide the application of soluble phosphates into three parts, one-third to be applied annually as a top-dressing, in the spring, together with the nitrogenous and potassic manures which have been applied annually at like rates to all of the plats in both series. Owing to the change in the plan of the experi- ment in 1898, the land was left for an additional year in grass. In the spring of 1899 such quantities of phosphates were applied as were suppKDsed, based upon their composition, to equalize the amount of phosphoric acid upon all of the plats. It was dis- covered, however, in 1902 that the assistant to whom the cal- culations were intrusted in 1899 omitted to take into account the applications of the insoluble phosphates which had been made in the autumn of i8g6, and owing to this oversight the complete equalization of the phosphoric acid was not finally accompHshed until the spring of 1902. The total amount of phosphoric acid which was applied per plat (two-fifteenths acre) to all excepting the two check plats, from 1894 to 1902 inclusive, amounted to 98.5 pounds, or to 738.6 pounds per acre. This equals 82 pounds per acre annually, an amount which would be supplied by an annual application of about 360 pounds of fine ground boiie or of about 500 pounds of acid phosphate. The following phosphates were used; dissolved bone-black, dissolved bone, dissolved phosphate rock (acid phosphate), steamed bone-meal, basic slag, raw rock phosphate (floats), iron and alumina phosphate, roasted iron and alumina phosphate and double superphosphate. One ton of air slaked lime was applied SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 169 -jadns siqnoa 00 ON ON -^00 t1- r^ io»o r-. O Tt r*5 ro o . vO»^ 00 ■ O •- *£l 00 I M M •- w I Ph en o K CM H 'A W Pi w Q '^ s « OS X w p i4 W Q O Pi psiXddE ■-' OM^ r^ Tt^ Tf ^o ON -^ r*^ r^ N o W « -^ to IOM3 ON lO t^ »o « rO - ON r^ 00 10 o oO'*D rO ON rt-OO -^ t^ c^ N M W OMO i-^ *0 O M -^ ON Tt -^ 10 CO CO W NO O 10 t*^ vO O 00 -^CO 10 . W M CO CS ON rO'^r^'-it--r^r^l Onioi i-ioooo IB3ai-3Uoq pamBsqs VD CO r^ Tj- ►-. 00 N NO ONOO W O 00 10 n f-t 10 N lo r-. OMO - 00 W VO - 10 -^ r^ ONvO t-.00 i-i (N (-1 h-i (-« I- r^ CO cono ^ 00 10 I r^ t^rj- a^Bqdsoqd ppV 10 10 ro ON >-■ O ND ON H- O •- W lONO CO CO ►" ^O O lONO •^ co«^ i-\DvO0 I '-Hr^i lor^pt I-. tN N h- .-1 C^ I hH I jBdui-auoq paAiossiQ 00 fN ^ O 00 0\\D »0 r^ ON N « w O CO w ON On 10 t^ Tj-WioOco--' r*-0 CD O^VO . Tj-00 i-H\OvOCM I r^^iOl lOOrD 31DB|q-3UOq paAiosBja h- h- CO VO ■^00 M 10 r^ <-< NO CO ON ON Td- CO >- lO ON "^ T^ CUV 10^ E« Pi o D Sj= o M-rSi ono o a „, "M " cC O ^ ri OJ CJ ~ * _M ■ ■ • «^ CT3. a; ^ n o ^ S - -_ ^- ^4) hoc H„Sja 2 It o a; (0 I- -a lU S tn o j=.S"3 a ■ -0-5; &,»>_, s^ffl £ 1 > 1^ , (A 00 U g ; 4-t '"' U( Vh :*- ;= 2 •5 Tt »0 invD Q o 0^ ON ON ON ON O O 00 00 00 00 CO ON ON oj y', w 2 a-'Jix! lyo SOIL FERTILITY AND FERTILIZERS aieqdsoqd -jsdns 3[qnOQ pdi^ddB 9)Bqd'uoiid on 3)ipuop3j p9)S60H CO rO t-^ lO ro fO -^ f^ CO W vO I O « O I W vO I CO UO f^CO lO -< vo MCO cO^O rO C>CO rO N lO r^ ON t-^-vO I- 1-. fO -^ CO rO I O O I HH On O ! 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N i-H r W i-i 0^ OxX 1-1 0^ tj-vO lO O^vO ^ rO "^ lO Md fO'-ifO'-'i-'-'-' I I I a r>.« 00 W OOO'-H OQ0i-i-o\O lOO^ Nj-hhh rO'-irO'-'W'-i'-' " I I " I I o 00 Cm p. o o ON _ en S (U c ^ _ 01 -'^ S^ 2 I- ? .5 B s S — * = " -3 '" n cu ^ La '^ > ** &'S E." S'C o wi ea ^ u m -tr**- -^ u S MS ' — ttj ||ll|i|-3«| O W w cc to m u u pq (i< s 2 S o S OH a; u rt tn —'n o o S (U'CL V i-tCOP< o .1 = S "i 0.-S ° SUPERPHOSPHATES AND EFFECT OF PHOSPHORIC ACID 175 9)cqdisoqd -aadns ajqnoa I ! ^ pdi|ddB s3)«qdsoiid OK CO' H fH : ^ a a H ii 3 w •a IS S M (^ III ■S c Q S Z Ph .4 w Q o R PS p's^SGOH 91ipuOp9J -Soqd ALB^ IBsm-anoq paiuES^s d^EqdEoqd PPV lEsm-anoq paAiossja 31DEiq-suoq paA[oiiSia s-0 O..S o a s a. ad a, o O J3 O o Mr - -is n (U. to OJ I- O ■ Eio; a 3 i 5^ ca CO = - "-s s H M iH ^ .S -^i»J— rtC81-i O W « CO fiH pq CI U SB ;3 c s'5 •r— be ?. a 3 SI'S u o MPM CO 'q^ oj i-tccrt -O o CD O ^ o s 8s UCO " 176 SOIL FERTILITY AND FERTILIZERS phate failed to give good results. The same inferior action, in a less degree, was observed in the case of certain plants both with dissolved bone-black and acid phosphate. In one or two cases the results with acid phosphate were quite poor even in the limed series, but whether this was incidental or due to the presence of some compound peculiar to this sub- stance which is particularly toxic to certain plants, remains to be determined. Basic slag meal and fine ground bone proved to be excellent phosphatic manures for acid soil, the former being immediately efficient and the latter becoming so after remaining in the soil for two or three years or long enough for extended decomposi- tion to result. In employing for the first time either raw or steamed bone- meal on land greatly in need of phosphoric acid, supplementary applications of dissolved bone, dissolved bone-black, or acid phosphate should be repeated for two or three years, after which the bone may be expected to meet the demand, provided the applications of bone are generous and are also continued from year to year. Farmers who are taking up exhausted land or who are plan- ning to grow crops which do not seem to have great feeding power for phosphoric acid, as was shown, for example, in this experiment, by the cabbage, should be very careful to select fertilizers which contain a large proportion of the phosphoric acid in a soluble condition, that is, as soluble phosphoric acid. They should bear in mind 'that fertilizers, excepting basic slag meal, containing high percentages of the so-called "available" phosphoric acid, none or practically none of which is soluble or capable of being at once dissolved by water, are not adapted to conditions where the soils lack assimilable phosphorus, nor to plants that are lacking in feeding power for phosphoric acid. It should be again emphasized that the "available" phosphoric acid, as shown by analysis, is obtained by adding together the soluble and reverted phosphoric acid. Bearing this in mind it will be seen that a fertilizer might be made by using roasted SUPERPHOSPHATES AND EEFECT OF PHOSPHORIC ACID I// Redondite as the sole source of phosphoric acid which would contain a high percentage of reverted and available phosphoric acid and but little soluble phosphoric acid. Such a fertilizer if applied to a' very acid soil lacking in assimilable phosphoric acid would prove practically worthless for certain varieties of plants. If it is known, however, that the land is but slightly or not at all acid, or if lime or wood ashes have been applied recently, then the danger in using such fertilizers is less than it would be otherwise, particularly if legumes, oats, Japanese millet, golden millet, or other plants are grown which have a great feeding power for phosphoric acid in such combinations ; nevertheless, even under such conditions the after effect upon many varieties of plants is far less than with bone, basic slag meal and with superphosphates. It must be evident after a study of the foregoing results, especially when it is stated that fertilizers containing small and even very large amounts of roasted and raw Redondite have been sold in Rhode Island, that a safe course for the farmer is to buy the materials and mix his own fertilizer, or he should have a positive assurance as to the character of the materials entering into the ready mixed goods. If the latter can be secured, then it becomes merely a question of price which shall determine his choice. The results ought to show that attention must be paid to the kind of crop, the kind of phosphate, and the kind of soil, if one will make sure that the phosphoric acid shall pay proper re- turns for the money employed in its purchase.'^ CHAPTER IX. POTASH FERTILIZERS. Before the discovery of the potash mines in Stassfurt, Ger- many, the main source of supply of potash was wood ashes. History. — The following description tells how the deposits of potash salts were formed. The Stassfurt salt and potash deposits had their origin, Fig. i6. — Section of potash salt mine shaft. POTASH FERTILIZERS 179 thousands of years ago, in a sea or ocean, the waters of which gradually receded, leaving near the coast, lakes which still re- s w I tained communication with the great ocean by means of small 13 i8o SOIL FERTILITY AND FERTILIZERS channels. In that part of Europe the climate was then tropical, and the waters of these lakes rapidly evaporated, but were con- stantly replenished through these small channels connecting POTASH FERTILIZERS l8l them with the main body. Decade after decade this contimied, until by evaporation and crystalHzation the various salts present in the sea water were deposited in solid form. The less soluble material, such as sulphate of lime or "anhydrite," solidified first and formed the lowest stratum. Then came common rock salt, with a slowly thickening layer which ultimately reached 3,000 feet, and is estimated to have been 13,000 years in forma- tion. This rock salt deposit is interpersed with lamellar de- posits of "anhydrite," which gradually diminish towards the top and are finally replaced by the mineral "polyhalit," which is composed of sulphate of lime, sulphate of potash, and sulphate of magnesia. The situation in which this "polyhalit" pre- dominates is called the "polyhalit region," and after it comes the "kieserit region," in which, between the rock salt strata, kieserit (sulphate of magnesia) is embedded. Above the kieserit lies the "potash region," consisting mainly of deposits of carnallit, a mineral compound of chlorides of potash and magnesia. The carnallit deposit is from 50 to 130 feet thick and yields the most important of the crude potash salts and that from which are manufactured most of the concentrated articles, including muriate of potash. Overlying this region is a layer of impervious clay which acts as a water-tight roof to protect and preserve the very solu- ble potash and magnesia salts, which, had it not been for the protection of this overlying stratum, would, have been long ages ago washed away and lost by the action of the water percolating from above. Above this clay roof is a stratum of varying thick- ness of anhydrite, and still above this is a second salt deposit, probably formed under more recent climatic and atmospheric influences or possibly by chemical changes resulting in dissolving and subsequent precipitation of the compounds. This salt de- posit contains 98 per cent, (often more) of pure salt, a degree of purity rarely found elsewhere. Finally, above this are strata of gypsum, tenacious clay, sand and limestone, which crop out at the surface. The perpendicular distance from the lowest to the upper sur- l82 SOIL FERTILITY AND FERTILIZEKS face of the Stassfurt salt deposits is about 5,000 feet (a little less than a mile), while the horizontal extent of the bed is from the Harz Mountains to the Elbe River in one direction, and from the city of Magdeburg to the town of Bernburg in the other.'- It is evident that these deposits are sufficient to supply the world for many centuries. Discovery. — The Stassfurt deposits, which are the main sources of supply of potash salts for fertilizing purposes, were first used for the rock salt they contained. The presence of potash salts in these mines spoiled the rock salt and it was not until 1857 that the value of these mines was known. In 1862 potash salts were first put upon the market and since that time the use of these salts for agricultural purposes has steadily increased. Potash Salts Used for Fertilizing Purposes. — The principal pot- ash salts obtained from these mines that are used as fertilizers in the United States are: 1 . Kainit 2. Sylvinit 3. Muriate of potash 4. Sulphate of potash 5. Double sulphate of potash and magnesia 6. Potassium — magnesium carbonate. These products may be classified as crude and manufactured as follows : Crude salts f Kainit Natural products ( Sylvinit f Muriate of potash Manufactured salts ( Sulphate of potash Concentrated salts j Double sulphate of potash and magnesia t Potassium-magnesium carbonate. There are many other salts as carnallit, polyhalit, krugit, hartsalz, sylvin, kieserit and schonit found in these deposits but are not usually sold on the American market. I. Kainit as sold in this country is finely ground, gray-colored and contains small red and yellow particles. This potash salt has been used more extensively in this country than any of the others, but the kainit deposits are gradually becoming ex- POTASH I-'ERTILIZERS 183 hausted so that it is not so common on our markets as formerly. Kainit is made up of potassium, sodium and magnesium chlorides, ;■■;■ -r~-: ^-v " *'^'- -S.-V _ ■ He E -^ii ,, '- ■- .■- «. 'is;'.,-. - ^f^ Wl '' ** f*%i v-.-?''n]T 5 S ,! EJ ^^ My^ 1 ■ . »r ||wy|Bp 1 , ■ ' '■ 1 usiirai wmm. and potassium, magnesium and calcium sulphates. The potash 184 SOIL FERTILITY AND FERTILIZERS is present chiefly as sulphate but on account of the large amounts of sodium and magnesium chlorides present, the potash has the same action as if it were chloride. Kainit usually contains 12 to 12.5 per cent, of potash. Composition of Kainit. Per cent. Actual potash 12.8 Sulphate of potash 21.3 Chloride of potash 2.0 Sulphate of magnesia 14.5 Chloride of magnesia 12.4 Chloride of sodium 34.6 Sulphate of lime 1.7 Insoluble substances 0.8 Water » 12.7 When kainit is kept for a long time it tends to become very hard and compact, due to the presence of sodium and magnes- ium chlorides. This effect can be eliminated to a great extent by mixing earth with it. Kainit cannot be used advantageously on crops that are in- jured by chlorine. Therefore it is objectionable for tobacco. It should be applied to the soil sometime before planting as the chlorides present in this salt are liable to burn or injure the young tender roots. The chlorides of sodium and magnesium often exert a beneficial effect on certain soils because they are easily diffused and thus help to distribute the other ingredients. Kainit is said to check insect damage and prevent certain plant diseases. 2. Sylvinit. — This salt when ground is much more red in color than kainit. It is being used more in this country than formerly because of the scarcity of true kainit. It is often sold in the United States by the fertilizer manufacturers under the name kainit. Sylvinit consists chiefly of chlorides ; in fact it is com- posed principally of sodium chloride and potassium chloride. POTASH FERTILIZERS 185 The sylvinit sold in this country contains from 12.5 to 15.5 per cent, of potash. Like kainit it helps to make available other 1 86 SOIL FEKTILITY AND FERTILIZERS Composition of Sylvinit. Actual potash Sulphate of potash ■ ■ ■ Chloride of potash • . . Sulphate of magnesia Chloride of magnesia . Per cent. •■ 174 ■- 1.5 .. 26.3 .. 2.4 .. 2.6 Chloride of sodium S^-? Sulphate of lime 2.8 Insoluble substances 3-2 Water 4-5 plant food ingredients in the soil, particularly the phosphates, and so it is somewhat of an indirect fertilizer. 3. Muriate of Potash. — As has been said, this product is a manufactured one. It is sold in large quantities in this country. The crude salts of the mines are refined, during which process most of the useless impurities are removed, as Hme, magnesia, soda, etc. The principal grades of muriate of potash as manu- factured are: Muriate of potash (KCl) Per cent. Actual potash (K.O) Per cent. 70 to 75 = 46.7 80 to 85 = 52-7 90 to 95 . = 57-9 98 = 62.0 The product sold in the United States usually contains 80 per cent, of muriate of potash which is equivalent to 50.5 per cent, of potash. Composition of Muriate of Potash. Actual potash Sulphate of poiash. . . Chloride of potash . . . Sulphate of magnesia Chloride of magnesia . Chloride of sodium . . . Sulphate of lime Insoluble substances. Water Grades 90 to 95 Per cent. 8a to 8s Per cent. 70 to 75 Per cent. 57-9 91.7 0.2 52-7 83-5 0.4 46.7 1-7 72-5 0.8 0.2 0.3 0.6 7.1 14-5 21.2 0.2 0.2 0.2 0-5 0.6 I.I 2-5 POTASH FERTILIZERS 187 The principal impurity in this product is sodium chloride and the lower grades contain more common , salt than the higher grades. Muriate of potash is one of the cheapest sources of pot- i88 soil, FERTILITY AND FERTILIZERS ash and can be used for all crops that chlorine does not injure. Tobacco, potatoes, sugar-beets, and oranges are a few crops that will not do well on large quantities of this fertilizer. 4. Sulphate of Potash. — This is a yellow, dry, almost powdery substance. It is sold containing 90 to 97 per cent, of sulphate of potash which is equivalent to 46 to 52 per cent, of potash. High grade sulphate of potash containing 50 per cent, of potash is mostly used in America. Composition of Sulphate of Potash. Actual potash Sulphate of potash - - . Chloride of potash . . . Sulphate of magnesia Chloride of magnesia Chloride of sodium . . Sulphate of lime Insoluble substances. Water Grade Grade 90 per cent. 96 per cent. 49-9 52.7 90.6 97.2 1.6 0-3 2.7 0.7 i.o 0.4 1.2 0.2 0.4 0-3 0.3 0.2 2.2 0.7 Sulphate of potash is more expensive than muriate because the cost of manufacture is more, but it is desirable for tobacco, potatoes, citrous fruits, and other crops that are injured by ex- cessive chlorides. The orange growers of Florida supply pot- ash often as sulphate. The concentrated products, as muriate and sulphate, are often cheaper than kainit and sylvinit per unit of potash. In purchasing the concentrated potash salts there is a saving in freight charges, as it costs as much to ship crude salts as concentrated salts, and the freight for the impurities is saved. 5. Doable Sulphate of Potash and Magnesia. — This product is somewhat similar in action on crops to high grade sulphate of potash. It contains considerable sulphate of magnesia which is believed to exert a beneficial effect. It usually carries about 26 per cent, of potash. It is not used to any great extent in this country, except by sorne fruit growers who prefer it to sulphate of potash. POTASH FERTILIZERS I»5 Composition of Double Sulphate of Potash and Magnesia. Per cent. Actual potash 27.2 Sulphate of potash 50.4 Sulphate of magnesia 34.0 Chloride of sodium 2.5 Sulphate of lime 0.9 Insoluble substances 0.6 Water 1 1 .6 Potash Manure Salts. — There are other potash salts that vary from 20 to 30 per cent, of potash called double manure salts and potash manure salts which are not used extensively in fertilizers; although a potash manure salt containing 20 per cent, of potash is sometimes sold which acts like kainit. Composition of Potash Manure Salts. Actual potash Sulphate of potash . . Chloride of potash- - . Sulphate of magnesia Chloride of magnesia Chloride of sodium . • Sulphate of lime Insoluble substances- Water 20 per cent. 30 per cent. 21.0 30.6 2.0 1.2 31-6 47.6 10.6 9-4 5-3 4.S 40.2 26.2 2.1 2.2 4.0 3-5 4.2 5-1 The cost of the potash is double sulphate of potash and mag- nesia and double manure salts is generally more than in kainit, sylvinit, and muriate of potash. All the salts described are very soluble in water and care should be exercised in their application. 6. Potassitun-Magnesinm Carbonate. — This is a dry, white manu- factured product. It is not sold as extensively as kainit, sylvinit, muriate of potash, and sulphate of potash, but it is well liked by tobacco growers. It is also used in Florida on oranges and pineapples. This product is an excellent source of potash for any crops that chlorides prove injurious to. It usually contains from 20 to 25 per cent, of potash in the form of carbonate. On account of its dry nature, and because it does not absorb water from the atmosphere, it is always easy to distribute. igo 190 SOIL FERTILITY AND FERTILIZERS ss M a w ►J < to o {-I Pi » < 03 Hi O ;? o o o o w o si w > < 5E CO 00 ■* 00 vo 0> 00 lO >- >- 00 10 vo rr 8, 10 Tj- (N 10 10 ^ w d ja^BAV d ci ^ d " w -n|osui S33UB)sqns CO up « d d ro odd odd -4 *OSBD 9taii jo a^Eiidins r^ a^oo l-i »-.' P4 d d d TDBJSC uinipos JO spuomo d ■-* -• -^ 1^ t^ O d cI ^ N Tl-CO d d d d i{SB)od JO 9)BunK O in ro « 10 'O d -' r^ 10 »o vO i{SB)od JO a^Bifdins "I I I V -a s ^ , MS - a = c - *S.^\S.E ^ e 5S.«S. M 0) !S "^ >" a 2 ^ o M ii 9^«> •> - a 4) - . V 'C °^<» f^-S — l- "m M •» 3 J3 j: J3 " ^ STh p,q,q,Mo o o s « "a « . j7 c fl, a. o. c -si .« « «j-3 ° °° H 2 -exja ja o.JS.S.Sm •g tc to M ^ S S S cu tn 2 M a 2 CO o C o a. p. o-g o « O f^ o w ;'J3 ^ lo^o ''■' t^oo a^ o 11 w POTASH FERTILIZERS 191 Composition op Potassium— Magnesium Carbonate.'' Per cent. Potassium carbonate 35 to 40 Magnesium carbonate 33 to 36 Water of crystallization 25 Potassium chloride, potassium sulphate, and insoluble 2 to 3 Production OF Crude Potash Salts , 1905 TO 1909.'* Year Carnallit dzi Kieserit dz Kainit with hard salt and Schoenit dz Sylvinit Total dz 1905 1906 1907 1908 J 909 22,397.099 22,631,972 25,347.888 27.687,939 32,807,260 27.308 91,905 103,595 184.730 73.878 24.055.361 27,540,215 27,889,734 29.215,093 32,680,871 2,306,216 2.849,435 3.041,431 3,052,824 3,447.493 48,785,984 53.113.527 56,382,648 60,140,586 69.011.539 1 Dz = 2Z0.47 pounds. Production of Manufactured Salts. 1905 to 1908.= a > Chloride of potash 80 per cent. dz. Sulphate of potash 90 per cent. dz. Sulphate of potash- magnesia 48 per cent, dz. t a h4 a 1 Crystallized sulphate of magnesia c U U K Calcined ground kieserite dz. 1905 1906 1907 1908 2.547,107 2.793.196 2,912,476 2,885,243 422,204 511,815 562.534 547,5" 305.892 370,907 315.028 337,564 2.154.075 2,782,850 2,862,613 3,132,205 7.178 8,342 7,881 6,652 350,025 294,109 265,209 255,325 6.001 6,318 4,566 6,684 Importations of Potash Salts from Germany to the United States, 1908-1909, in Tons.''' Year Hartz salts, Kainet, Kieserit. etc. Muriate of potash Sulphate of potash 1908 1909 364,731 469.963 100.587 132,198 59.869 63,845 The following table gives the consumption of potash salts in actual potash, acres of arable land, and the amounts of actual potash used per 100 acres of arable land in the countries enum- erated for the year 1900.'^ IQ2 SOIL FEUTILITV AND FERTILIZERS Consumption of Potash Salts in Actual Potash. Countrv Potash salts consumed in tons of actual potash (K.O) 1900 Germany Holland Sweden Scotland Belgium Denmark England Norway Switzerland United States Finland Ireland France Spain Italy Austria-Hungary . Portugal Russia 117,712 7,106 8,197 3.370 3,607 1,692 4,020 286 1,026 66,595 382 600 8,229 2,428 1,380 2,389 43 1,597 Arable land in acres 1900 86,971,300 5,012,100 8.622,000 3,641,200 5,232,800 6,305,000 16,915,400 1,412,900 5,258,700 348,212,300 2,755,100 5,322,500 92,649,800 72,201,100 50,421,000 99,416,900 11,329,000 515,055,200 Piitash sails used per 100 acres arable land in pounds of actual potash (K2O 1900 298.3 312.5 209.5 204.0 151-9 59- 1 524 44-7 43-0 42.2 30.6 24.8 19-5 7-4 6.1 5-3 0.8 0.7 Potash Investigation in the United States. — From the forego- ing it is evident that Germany has a monopoly on the mineral potash output of the world and our farmers are dependent on this supply. Recently the American fertilizer manufacturers had some difficulty with their German potash contracts and consid- erable discussion was entered into before settlement was reached. Because of this trouble our government has appropriated money and placed it under the supervision of the Geological Survey for the purpose of investigating certain western sections of the United States where paying potash deposits are liable to be found. Present reports are quite favorable. Should the Geological Survey succeed in this investigation we will be independent of Germany for our potash and it will be the greatest fertilizer dis- covery of recent times in the United States. Potash from Organic Sources. — Most of the potash used in fertilizers is derived from the mineral sources but a small amount POTASH FERTILIZERS 193 is sometimes purchased in the form of wood ashes, tobacco stems, cotton-seed hull ashes, and beet molasses. 1. Wood Ashes. — Before the discovery of the Stassfurt de- posits wood ashes were used more extensively than now and were practically the chief source of potash to be found on the American market. The potash in wood ashes is in a form (as carbonate) which is very desirable for all plants. The product offered to the trade is not uniform as different woods, parts of the same wood as bark, twigs, etc., and methods of handling, all influence the composition. The ashes from soft woods usually contain a lower percentage of potash than the ashes from hard woods. Leached wood ashes naturally carry much less potash than the unleached ashes. Ashes contain small amounts of phos- phoric acid and large percentages of lime. They usually contain more or less dirt and moisture which lower the composition. The main source of wood ashes is Canada as not much wood is burne'd in the United States. The following compilation made by the Massachusetts Agri- cultural Experiment Station shows the composition of 97 sam- ples of unleached wood ashes.'' Composition of Unleached Wood Ashes. Potash Phosphoric acid Lime Magnesia Insoluble matter Moisture Carbon dioxide and undetermined Average Per cent. 5-5 1-9 34-4 3-5 12.9 12.0 29.8 Maximum Per cent. 10.2 4.0 50-9 7-5 27.9 28.6 Minimum Per cent. 2-5 0-3 18.0 2-3 2.1 0.7 The analyses of 15 samples from domestic wood fires in New England show the following average.'* Per cent. Potash 9.63 Phosphoric acid 2.32 The analyses of leached and unleached ashes follow :'° 194 SOIL FERTILITY AND FERTILIZERS Insoluble matter Moisture Calcium carbonate and hydroxide Potassium carbonate Phosphoric acid Undetermined Uiileached Leached Per cent. Per cent. 13.0 I3-0 12.0 30.0 61.0 51.0 5.5 I.I 1-9 1.4 6.6 3-5 In leaching wood ashes the phosphoric acid and potash are principally lost. Amounts of Ingredients in Different Kinds of Wood Ashes. — The table on page 195 gives the amounts of ingredients in the ashes of several common woods. Value of Wood Ashes. — From a chemical standpoint the value of wood ashes is represented in the contents of potash, phos- phoric acid and lime. Ashes have another value in improving the condition of the soil. They seem to help to conserve mois- ture, improve the texture of soil and correct acidity, thereby increasing the action of the organisms that promote nitrification. Most soils are benefited by an application of wood ashes. Grasses and legumes especially do well when wood ashes are applied as a top dressing. 2. Tobacco Stems. — Wherever cigars, cigarettes, smoking and chewing tobacco are manufactured there are considerable wastes of stems and stalks collected. This material was formerly thrown away or burned. The burning of tobacco wastes caused the nitrogen to be lost. To-day these wastes are saved and used as fertilizer. Analyses of Tobacco Stems.°^ Moisture Organic matter - Ash Phosphoric acid Potash Kentucky Connecticut stems stems Per cent. Per cent. 26.70 13-47 60.18 70.85 13.12 1568 0.67 0.53 8.03 6.41 POTASH FERTILIZERS 195 Q P o Ph a z < « D O X f-> z St H a a < m H H B w O (siiiui J) amd pjag pio (BAIJBS JO (EjSiu Baoij) aiiid 5iaBia (spini 'd) auid AwoipA (su^snied •^) auid biSjosq (BJOHipuEjS -iM) eiiouSejs (EqlB -5) 1«o siiqAV (Bso)ii9iuoi eXjedI Xjojidjh (Bjqnj -5) 31EO paa (EUB0U31UV 'd) MSV (Eqoiisnjqo 0) 3iE0 )S0J (sjiEluap -paosnnejBid) sJOUiBDiCg (epijoy snuiJOD) pooAkSoa SsS rO O w O N- ^ M ON t^ r^ ^ « \0 vO »0 uo S « . o_ (N q. 1 «£ ^^ '-^" pT N (N .□ s> rs vo vo vo fo CO VO ll r^ ON CO I^ q ro CO Tj- «' vd lO r^ r^ ro r^ in CM (N « W (N « N *-4 IK 8 fO CO vo fO ro fO s-^ t^ up fo « I-" U] S£ a\ »-i ^ d co" y5 rh N 1 o (Cm rO ro rO rO fO to lO rr 4-< 1 5 ut* o r^ \o CJN o to VO VO Ph CO * -a- q ^ o r^ « 00 CO I-l r^ r^ ij CO >o Cfv <=^ ►^5 ■^r o CN CO "^ rn rO (O rO r*0 m - (B II un ^ VO CO ^ O N vo N t^ lO r- t^ n o o_ ^ q; rt w - w CO VO Tt r^ to VO N rO Cv vo -T \n CO PO !N c^ o_ "? ^ ■^ ■^ n n CO cT CN cn' pT (m" n' cT pT r? O o lO O »o in o f' c CO r>. ON n lO ''I- II d" lO o d" rO Tt- "^ rO ^ ■^ T^ fO en O lO r^ in r-* « 00 in O r~>. t^ Ov r^ c» lO m W3 -^ » lO « o_ ■^ q_ 1 "£ ^■^ i-T i-T N I-T f^ pT (N ^ in .SI CT\ rf) "O lO ^ CO o ro .2^ -^ vq ro CO 00 "^ ■"i- lO vd TT r^ •a J^ ca (/I -M cd o •*-• a. a o o u 4) .— ' CO Ul .a a. a CO •a 1 1 t en O •5 a a 01 -s (U -a c«-< O ii o t O a bo 2 V ■n 3 ii 2 s o •s V 1 ;z 1 ^ ii ^- } % ? C ; t? 1 POTASH FERTILIZERS 203 Rhubarb, lbs Stalks Leaves Cabbage, lbs Hard heads Softheads Pototoes, bus. Market Small Onions, bus. Scallions, lbs. Timothy and clover hay, lbs. . • Timothy and clover rowen, lbs Yield per acre Muriate of potash Sulphate of potash 8,421 11,957 8.559 14,286 872 22,791 2,071 24,319 208 215 53 no 10,811 4,710 1,745 39 75 8,828 4,725 1,997 Fixation of Potash. — Potash is quickly fixed in the soil; it re- places the sodium and calcium in soils and forms compounds in- soluble in water. The chlorides of potash are liable to render the lime content of a soil deficient, as the chlorine unites with lime and forms a soluble compound that is readily leached from the soil. In experiments at the Massachusetts Experiment Sta- tion, Goessmann found that continued applications of muriate of potash produced sickly crops which were made well and healthful by an application of lime. Therefore acid soils should always receive an application of lime before the use of potash as chloride. As potash is quickly fixed in the soil and the chlorides washed out, it is often advisable to apply chloride of potash some time before the crop is planted, especially when the crop that is to be planted is injured by chlorine. The fixation of potash usually occurs in the surface soil and so rapidly does this fixation take place on some alluvial soils, that it fs necessary to work it in soon after applying to insure an even distribution. Functions of Potash. — The intelligent use of potash fertilizers requires a knowledge of the effect of this constituent on crops. Potash is essential to the formation of starch, sugar and cellulose (pure fiber) in plants. When there is a deficiency of available potash in soils, certain plants do not mature well. 204 SOIL FERTILITY AND FERTILIZERS Potash Favors the Formation of Carbohydrates. — The effect of potash on the sugar content of mangolds in shown in the fol- lowing table." Fertilizer Leaf per acre tons Roots per acre tons Sugar per acre tons Nitrogen and phosphoric acid Nitrogen, phosphoric acid and potasl. 2-95 3-25 12.00 2S.95 0.797 2.223 The two plots received equal quantities of ammonium salts and superphosphate. The plot that received potash shows a yield in roots of about 2)4 times more than the plot that had no potash. The leaf development per acre was nearly the same in both plots and as the ro6ts of this crop are made up largdy of carbohydrates the effect of potash is readily seen. Another system of fertilizing mangolds gave the following results." AvER.\GE OF 12 Years. ^ .... ! No potash Fertilizer | xons 1 ■f Phosphates and potash Tons Manure only iS.6 27.7 21.S 249 24.2 195 26 S Manure and ammonium salts 25-9 28 6 Manure, rape cake, and aumionium salts 29.9 The above data show that potash increased the yield in every case except where nitrate of soda was added. The soda present in nitrate of soda renders unavailable potash in the soil available, which accounts for this increase. It is also seen that the addi- tion of potash to manure was beneficial. This is interesting be- cause 14 tons of manure was applied per acre which amount supplied considerable potash, yet was unable to furnish all the potash needed for this crop. Potash Benefits Legumes. — Another beneficial effect of potash is the increase it gives to the growth of legumes. At Rotham- stead the yields of plots of mixed grasses and legumes show this effect." POTASH FERTILIZERS Dry hay Fertilizer 1856 to J902 I Cwts. Complete mineral fertilizerj 38.8 Nitrogen and phosphoric acid 28.1 Superphosphate only 23.3 Unfertilized 21.9 1893 to 1902 Cwts. 3b-5 21.6 17.8 15-9 Composition of Herbage in 1902 Grasses Per cent. 28.8 54-4 34-3 Legumin- ous plants Per cent. 55-3 22.1 15-4 7-S Weeds Per cent. 24.4 49.1 50.2 58.2 The complete mineral manure consisted of phosphates and sulphates of potash, soda and magnesia. The plot receiving the complete mineral manure gave the highest yields and also showed the greatest percentages of legumes and least of weeds. The plot receiving nitrogen and phosphoric acid without pot- ash gave the next highest yields and shows a larger percentage of leguminous plants than the plots that received phosphates and no fertilizers. On the unfertilized plot the percentage of leguminous plants is very low. The effect of the soda in the mineral fertilizer without potash, which comes second in the above table, is shown by the comparatively higher yields over the plot that received phosphates only. It is thus evident that pot- ash is the most important fertilizing constituent for legumes and large applications of phosphoric acid do not increase their growth materially. Potash Favors Seed and Straw Formation. — Hall says: "On these grass plots another very striking effect of potash manuring is also very manifest. On the potash-starved plots the grasses fail to a large extent to develop any seed, and the heads are soft and barren, presumably because of the deficiency in carbo- hydrate formation. For the same cause the straw, not only of the grasses, but also on the similarly manured wheat and barley plots, is also weak and brittle when potash is wanting." Potash Effects the Leaves. — Grass grown on soils deficient in potash tends to show the effect of this constituent by producing a brown sickly appearance. The grass blades often turn brown about 2 inches from the tip and die off. The leaves of root 206 SOIL FERTILITV AND FERTILIZERS crops also often show a lack of potash when they are nearing maturity, by a spotted brown coloration. Potash Effects Maturity. — Experiments show that soils without sufficient potash do not produce as valuable grain crops in dry seasons as soils rich in this constituent. This is probably due to the fact that potash causes a longer growing period and holds back maturity. With root crops the opposite effect has been found to exist. That is the maturity of -these crops is hastened by a supply of potash. Potash Helps to Neutralize Plant Acids. — Many plants contain acids ; for example, in the grape there is tartaric acid ; in the apple, malic ; in the orange, citric ; and potash helps to neutralize these plant acids and form acid salts. Potash Sometimes Checks Insect Pests and Plant Diseases. — Ex- periments show that certain forms of potash are distasteful to some insects and tend to check their ravages. Potash seems to make plants better able to resist attacks of certain fungi, especial- ly when soils are deficient in this constituent, by producing a stronger and more vigorous growth. CHAPTER X. MISCELLANEOUS FERTILIZER MATERIALS. The fertilizer materials discussed in the previous chapters are those products most commonly used and constitute the main sources of nitrogen, phosphoric acid and potash. There are, however, other substances that are occasionally utilized that have some value. Some of these materials are used at times by fer- tilizer manufacturers while others are employed directly by farm- ers. Some of them furnish one or more of the essential ele- ments in amounts sufficient to warrant their use, when they can be obtained cheaply, while others are not applied for their fer- tilizer value but to improve the condition or texture of the soil, to increase the available plant food supply or to conserve mois- ture. There are some products discussed in this chapter that have no particular value as fertilizer but are taken up to set 'clear impressions that are prevalent among some who feel that these products can be used to replace to a certain extent the more important fertilizer materials. It should be remembered that many of these materials we are about to discuss do not contain sufficient amounts of the essential elements to produce paying crops but they may be used to partially replace commercial fertilizers. Compost. — A compost is usually made up of layers of manure and vegetable matter. Sometimes lime, acid phosphate, ground raw rock phosphate, cotton-seed, gypsum, and similar fertilizer materials are added to it. A compost can be made in the fol- lowing manner. First select a shady place and provide a good drainage. Then make a foundation with a layer of earth. On top of this place a layer of leaves or manure then a layer of earth, another layer of leaves, cotton-seed and manure, a layer of earth, etc. The top of the compost should be covered with earth and it should be shaped to shed water. The compost should be kept moist to prevent the loss of nitrogen as ammonia. The manure, leaves, cotton-seed, raw rock phosphate, etc., will de- cay or undergo changes due to the action of organisms similar 208 SOII^ FERTII,ITY AND FERTIUZERS to what would take place in the soil, when the compost is kept thoroughly moist. Before applying any of the compost to the land it should be well mixed to make it uniform. The earth is used in layers to absorb the ammonia that may be set free in the process of decay of the organic materials. The amount of fertilizing material obtained from a compost will be equal to the amount of fertilizer material added to it, provided there is no loss ; but the availability of these materials will be greater. Seaweed. — In states bordering on the ocean seaweed is used a great deal for fertilizer. Stormy weather throws considerable quantities on the beach and the states of Rhode Island, New Jersey, New Hampshire, and Massachusetts have used this fer- tilizer for many years. Storer says: "Here in New England there is abundant evidence of the great value of seaweed. Abundant crops of hay and (in former times more than now) of potatoes are there grown and sold year after year, while the country remains fertile and fortunate. It is interesting to see the fields in that region remain green throughout the summer droughts, at times when the scantily manured fields of the interior are brown and parched. It is not the showers of summer alone, but the good tilth which comes with cultiva- tion and careful tillage, as well as abundant supplies of plant food, which enable crops to support intense heat. In the dis- trict now in question, (behind Rye Beach in New Hampshire) the use of the seaweed extends back some eight or ten miles from the beach, and to a less extent, even to twelve and fourteen miles."'' The best way to apply seaweed is in the fresh state. The dififerent varieties of seaweed contain from 70 to over 80 per cent of moisture and when it is to be transported any consid- erable distance it may be spread thin and sun-dried to avoid carting so much water. Should it rain during the process of sun-drying some of the nitrogen and potash might be washed away. In some of the European countries the seaweed is thrown in heaps to dry and rot. Such practice, because fermentations set in, necessarily causes losses of nitrogen as ammonia, and of potash by leaching. In some countries seaweed is composted MISCELLANEOUS FERTILIZER MATERIALS 209 and the same precautions should be exercised as in composting farm manure or else losses will occur. Preservatives as gypsum may prevent the loss of considerable nitrogen. The experience of the New England farmers shows that better results are se- cured when the seaweed is not composted. In New England fresh seaweed is used as a top dressing for grass or plowed in. About 20 to 25 per cent, of the ash of seaweeds is chlorine. Therefore it would be safer to use some other fertilizer for to- bacco, potatoes, etc. Seaweed is rather quick acting and gives up its fertilizer constituents during the first season. Analyses of Different Varieties of Seaweed.'* ■5< « •6 1 g ST3 3 u = •31 3 ■5 ^ S II IS a* V S < tu s 372 381 32 II. o 128.2 5-7 0.5 18.0 25-9 0.8 O.I 8.0 69.7 3-2 7.0 2,267 1.972 8 6.0 54-8 40.2 0.2 3-5 5-7 3-7 • 0.0 5-0 26.7 7-9 0.0 47.0 2,819 1. 185 27 42.0 69.8 32.5 0.7 39-0 8.3 4-3 O.I 23.0 38.6 8.0 0.2 30.0 5,533 864 32.0 116.2 13.2 35-0 18.3 2.2 18.0 123.0 10.9 13-5 lo.o 8.0 There is a great difference in the proportion of nitrogen, phosphoric acid and potash in the tops and roots of the above plants. The cowpea, soy bean, vetch, crimson clover, and rape especially contain a large proportion of nitrogen in the tops. 248 SOIt FERTILITY AND FERTILIZERS Although alfalfa contains more nitrogen in the tops, the amount in the roots is quite considerable and in a larger proportion than in the other legumes. Crimson clover is higher in phosphorus and potassium than the other legumes. Alfalfa contains less potassium than the other crops, and next to cowpeas, the smallest amount of phosphorus. Rape uses a great deal of potash, especially in the tops. Amount of Nitrogen Obtained from the Air. — The importance of using legumes when possible is emphasized by the amount of nitrogen that is fixed by bacteria from the air. Fixation of Nitrogen by Ai,fai,fa in Field Culture." Treatment applied Dry matter in crops (Pounds) Nitrogen in dry matter (Percent.) Nitrogen in crops (Pounds) None Bacteria Lime Lime, bacteria Lime, phosphorus ■ Lime, phosphorus, bacteria i,i8o 2,300 1,300 2,570 1,740 3.290 1.85 2.70 2.02 2.65 2.03 2.71 21.81 62.04 26.20 68.02 35-40 89.05 Nitrogen fixed by Bacteria (Pounds) 40.23 41.82 53-65 It should be known that the legumes do not necessarily draw all of their nitrogen from the air when soils are well supplied with nitrogen. On such soils the legumes may use the nitrogen in the soil instead of fixing the nitrogen from the air. Green manures are generally grown to increase the nitrogen supply in the soil so that on most farms where green manuring is practiced the nitrogen will be derived mostly from the atmos- phere by the leguminous plants. Should organic matter be needed on a soil containing sufficient nitrogen, a non-leguminous crop may be grown. The Best Time to Plow Under a Green Manure. — Crops used for green manuring should be plowed under before they become dry. When they are plowed under while green and fresh they are more readily decayed and prevent the loss of water somewhat from Hght soils. Dry crops plowed under interfere with the use of water from the subsoil and on light LIME, GYPSUM AND GREEN MANURES 249 sandy soils may lower the yield of the crop that follows. If possible the green manure should be plowed under some two or three weeks before planting time to give it a chance to partially decay so as not to injure the planted crop and to furnish some food for the young seedlings. The Best Time to Grow a Green Manure. — If the soil is poor and run down it is sometimes advisable to keep it in a green manure for a season or two. Generally, however, green manures fit well into rotations and may often be grown when the land is ordinarily idle or between money crops. In the South, crops like rye, crimson clover, red clover, vetch, etc. may be grown in the winter and turned under in time for the summer crop. In the North, rye and vetch may be used as winter crops. Some- times it is advisable to sow a green manure at the time another crop is laid by. Then when the crop is harvested the green manure crop will have grown sufficiently to turn under and the land may be sowed to some small grain crop; or the green manure crop may be planted after harvest and remain on the land all winter and plowed under in the spring. In fruit orchards green manure crops (cover crops) as rye, oats, clover, etc., are often sown about mid-summer to absorb moisture and available plant food from the soil and to cause the buds to mature and cease growth of the wood and leaves. This crop is allowed to remain on the soil all winter and in the spring it is plowed under. By keeping the land covered during the winter leaching of plant food and washing away of soil is lessened. Deep Rooted Plants Valuable. — ^Alfalfa, clover, etc., have very long tap roots which penetrate the subsoil, thus securing a great deal of plant food that would not be within reach of many culti- vated plants. These leguminous plants also bring a great deal of plant food from the subsoil to the surface soil and leave it there for succeeding crops. When these deep roots decay they leave openings in the soil which help to increase drainage and aera- tion and thus improve the physical condition of soils. CHAPTER XII. COMMERCIAL FERTILIZERS. Since i860, when fertilizers were used on a comparatively small scale, the fertilizer industry has increased until to-day it is of great importance. In i860 the wholesale cost of the out- put of the fertilizer factories was $891,344; in 1890, $39,180,844; in 1900, $40,445,661 ; and in 1905, $50,506,294 or a difference of $49,614,950 between the years i860 and 1905. These figures do not represent what the consumer paid for fertilizer during these years as these amounts cover practically the wholesale cost. The above tigure.s are only approximate at the best and in all probability they should be larger for the years 1900 and 1905, but they will serve to impress one with the magnitude of the fertilizer industry in the United States to-day. Statistics on Fertilizers." 1890 Establishments ■ . Hands employed Capital Wages Materials Products 47 390 308 10,158 $466,000 $40,594, iCS 95,016 4,671,831 590.816 25,113,874 891.344 39,180,844 Statistics on Fertilizers, 1900-1905.'' 1900 1905 $60,685,753 5.451. 153 10,247,759 28,958,473 40,445,661 2,887,004 $69,023,264 6,490,727 10,798,212 39.343.914 50,506,294 3.591.771 Cost of materials Total cost of products (fertilizers) • . - From this last table it will be seen that 3,591,771 tons of fertilizers were manufactured during 1905. If the consumer paid on the average $25 a ton for his fertilizer, the total cost would be $89,794,275 or an amount equal to the annual sugar crop (beet and cane in the United States) ; or to the barley crop; COMMERCIAL FERTILIZERS 25 1 or to the rice, rye and flaxseed crops combined. As the con- sumption of manufactured fertilizers is increasing and consider- ing that the tonnage for 1905 was greater by 704,767 tons than for 1900, and that the estimates are only approximate and prob- ably too low, we may safely conclude that for the year 19 10 over $100,000,000 was spent for fertilizers in the United States, or an amount equal to the oat crop for 1909. Distribution of Fertilizer. — The following table shows the dis- tribution of manufactured fertilizers used in some of the states for the year 1907. Consumption of Fertilizers by States." Alabama 301,657 Arkansas 21,400 California 21,647 Connecticut 45,000 Delaware 15,000 Florida 107,226 Georgia 786,736 ♦Illinois 15,000 Indiana 118,000 *Kansas 5,000 Kentucky 48,000 Louisiana 102,454 *Maine 75,ooo Maryland 180,000 ♦Massachusetts 85,000 Michigan 20,000 Mississippi 138,668 Missouri 15,000 *New Hampshire 42,000 New Jersey 130,000 *New York 300,000 North Carolina 459,181 Ohio 140,000 ♦Pennsylvania 300,000 ♦Rhode Island 12,000 South Carolina 631,033 Tennessee 37,798 Texas 21,600 Vermont 17,000 Virginia 237,018 West Virginia 22,105 Wisconsin i ,000 Total of 4,451.523 * Estimated. 1 .'Vmerican Fertilizer Handbook, 1909. 252 SOIL FERTILITY AND FERTILIZERS It should be understood that there is considerable fertilizer used by other states not included in the above table but it is practically impossible to get complete data along this line. How- ever it shows that most of the fertilizer is used by those states bordering on the Atlantic Ocean or near to it. It is estimated that the consumption of fertilizers for 1908 was about 3 per cent, over 1907, and that the consumption for 1909 was about 15 per cent, more than for 1908.^ In the season of 1874- 1875, Georgia used 48,648 tons of com- mercial fertilizer and for 1908-1909, 884,295 tons, or an increase of 835,647 tons. It is estimated that Georgia consumed about 1,000,000 tons for the year 19 10. Should the other states and territories in the Union increase in the same proportion as Georgia, think of the enormous amount of money that will be expended for plant food in the future. Statistics show that the older states in the East and Southeast did not formerly use much fertilizer but the consumption in these states has been increasing every year until to-day it is very large. If our newer lands are treated in the same way as those in the East and Southeast, think of the large amount of fertilizer that will be necessary to pro- duce profitable crops in the future. Causes for the Large Consumption of Fertilizers. — The causes for the large and increasing use of commercial fertilizers are many. Single crop farming has caused many farms to run down in fertility. Money crops have been principally raised. Legumes have been grown occasionally or not at all. Green manuring has not been practiced enough. Poor drainage has caused losses of fertility. Some farms have lost much of their fertile soil by erosion. Farm manure has not always been saved and when saved it has not been preserved properly. According to Bulletin 140 by the Kentucky Experiment Station, it is esti- mated that the annual production of farm manure in the United States is equal in value to the corn crop at $1.05 per bushel, or nearly two and one-half billions of dollars. The most con- servative estimate would put the waste of farm manure at one- third, an annual loss of about $800,000,000.00. This is about eight I Ware Bros. Co., American Fertilizer. COMMERCIAL FERTILIZERS 253 times the amount spent annually in this country for commercial fertilizers. There is little wonder that so much of our soil is becoming unproductive. The crops have also been sold away from the farm instead of being fed to live-stock. Cover and catch crops have i.ot always been grown. To sum up, we may say that the fertility of the soil has not been maintained, and farms that formerly yielded profitable crops with applications of 200 pounds of commercial fertilizer per acre, now require 400 to 600 pounds and sometimes 800 to 1,200 pounds to produce the same results. With the market gardner and trucker conditions are different. The demand for vegetables in our large cities has caused the market gardner in the north and the trucker in the south to use heavy applications of fertilizers to produce profitable crops. Many of these crops are heavy feeders and require to be mar- keted or shipped as early as possible, as a few days often means a great difference in the prices received, and so high priced quick acting fertilizers are generally used. The truckers are often located on sandy soils of low fertility that must have plenty of fertilizer to produce money crops. The market gard- ner, who usually lives near or in a city or town, produces crops on lands that would bring a, high price for building and other purposes, and can hardly ever afford to allow his land to be idle or to be sowed to some soil improving crop, but must have a money crop growing continually. The market gardner cannot afford to raise live-stock on such high priced land. So with the market gardner and trucker the consumption of fertilizer will increase with the demand for their products, and as the popula- tion of this country is increasing every year we may expect more artificial fertilizers to be used in producing market garden and truck crops. With these farmers, and especially the market gardner, the use of large quantities of commercial fertilizers is a necessity. How the General Farmer May Lessen the Use of Commercial Fertilizers. — The consumption of commercial fertilizers may be reduced a great deal by many farmers. A better system of 254 soil, FERTIIvITY AND FERTILIZERS farming should be adopted. A rational rotation system in- cluding money crops and soil improving crops should be prac- ticed. Legumes should be included whenever possible in rota- tions to add to the supply of nitrogen and organic matter in the soil. Live-stock should be kept and the farm crops marketed through them. In this way a two-fold or full value will be obtained, namely, the feeding and fertilizer values. Farm manure should be saved and preserved. It should be saved to supply humus and fertility to the soil and it should be preserved to prevent losses of the essential elements by fermentation and leaching. The land should be well drained and tilled. Crops should occupy the land continually. Erosion must be prevented. Li^se commercial fertilizers only to supplement the organic mat- ter and those constituents which should be contained in the soil. Fertilizers are not expected to produce crops alone, unless in- creased amounts are used every year. This is well illustrated by an experiment conducted at the Louisiana Experiment Sta- tion on corn. For four years commercial fertilizer only was applied to one plot and legumes and farm manure were used on another plot. The yield on the plot receiving commercial fer- tilizer alone, showed 12 bushels pei: acre and that on the plot receiving organic matter, 52 bushels, at the end of four years. Fertilizing Materials Used by Manufacturers. — The fertilizing materials described in the previous chapters are those that the manufacturers draw on for making their mixtures. The farmer generally purchases his fertilizer in the mixed state under some brand name, as Corn Fertilizer, B. C. Brand, etc., which does not indicate the materials of which it is composed. The fer- tilizer materials usually predominate in one constituent while the manufactured fertilizers show usually two or three of the con- stituents, as nitrogen, phosphoric acid and potash. The manu- facturers may employ materials that furnish large amounts of a particular constituent, as nitrate of soda, sulphate of ammonia, dried blood, sulphate of potash, muriate of potash, kainit, and Tennessee or Florida rock phosphate. He may choose some high grade materials as those just mentioned and some low grade materials as beet refuse, leather preparations, low grade COMMERCIAL FERTILIZERS 255 cotton-seed meal, soluble hair and wool waste, low grade bone- meal, etc. So when a mixed fertilizer reaches the farmer the identity of the materials of which it is composed is not known. Approximate Output of the Fertilizer Factories. — To give an idea of the raw materials used by manufacturers in making up their brands, and the amounts, the following table is given. The data does not include all the fertilizer used in the United States but represents the output of the regular manufacturing plants as near as can be ascertained.^- 1900 1905 Materials Tons Cost Tons Cost Bones, ammoniates, etc 168,510 354,075 28,977 146,488 4,120 17.203 884 958.802 54,700 109,407 l3,30t,iii 7,495,768 183,542 167,410 186,609 625,501 32,156 4,228,317 520,833 3,098,400 236,906 439,206 58,437 183,368 10,540 40,234 1,160 1,063,195 190,493 183,161 342 2,407,042 922,853 261,876 3,591,771 $2,807,336 5,687,718 880,412 2,376,448 600,856 1,677,761 39,039 5,092,694 1,891,073 3,606,701 2,050 Cotton-seed products . . Ammonium sulphate • ■ . Sodium nitrate Potassium nitrate Phosphate rock Kajnit Other potash salts Tnfnl 1,5^43,838 832,240 210,926 2,887,004 $19,839,647 4,868,806 4,250,020 $24,661,818 5,057,234 9,624,862 Sulphuric acid (soBe) • Dryers, sacks, etc. Grand total $28,958,473 139,343,914 The following prices represent the actual average cost per pound for the ammonia, phosphoric acid and potash used in 1900 and 1905 in the raw materials employed in manufacturing fer- tilizers.^^ Ammonia Organic ammonia Available phosphoric acid Organic phosphoric acid . Actual potash Organic potash 1900 Cents Cents 10.06 10.34 12.60 1500 2.14 2.05 4.50 5-00 4.94 4 39 4-50 4.50 1905 256 SOIL FERTILITV AND FERTILIZERS It should be noted that the prices used for the organic materi- als, practically all of which are credited at market prices, are somewhat higher than the average fertilizer raw material on factory account. From these prices the actual cost for ammonia, available phos- ,phoric acid and potash were calculated to be: 1900 Ammonia Available phosphoric acid • Actual potash Total 19.150,838 11.954,492 3,647,673 $24,753,003 111,594,232 12,464,062 5,660,758 129,719,052 From the foregoing data we have : Per ton of fertilizer 1900 1905 $3-17 4.14 J. 26 1.46 f3-'3 3-44 1-54 2.74 Average cost of available phosphoric acid- - Average cost of dryers, sacks, etc Xotal fio.03 f 1 0.95 According to these figures the wholesale cost of a ton of fer- tilizer was $10.95 for the year 1905. This figure of course does not include anything but the cost of materials. The salaries of the executive force, the wages of the hands employed, the cost of running the machinery, insurance, travelling expenses, adver- tising expenses, office expenses, taxes, rent of land, interest on in- vestment, and the many other considerations too numerous to mention, are not included in the above estimates. Classification of Commercial Fertilizers. — We have learned that the manufacturers use the different fertilizer materials in mak- ing up their formulas. When these materials are mixed and put on the market, nitrogen, phosphoric acid and potash, nitrogen and phosphoric acid, phosphoric acid and potash, or any single one of the constituents may be present. Again, the manu- facturers or other fertilizer dealers may sell some of the fertilizer COMMKRCIAI, FERTILIZERS 257 materials unmixed. As the manufactured mixtures are sold un- der many different brand names, and the unmixed fertilizer materials predominate in one or two of the essential elements, the chemist classifies them according to the constituents present. Classification of Commercial Fertilizers. 1. Fertilizers furnishing nitrogen as the chief constituent. Nitrate of soda. Ammonium sulphate. Lime nitrate. Calcium cyanamid. Dried blood. Azotin. Concentrated tankage. Steamed horn and hoof meal. Cotton-seed meal. Linseed meal. Castor pomace. Nitrogenous guano. 2. Fertilizers furnishing phosphoric acid as the chief con stituent. Double superphosphate. Superphosphate. Ground raw rock phosphate (floats). Bone ash. Bone-black. Basic slag. Phosphatic guano. 3. Fertilizers furnishing potash as the chief constituent. Sulphate of potash. Muriate of potash. Double sulphate of potash and magnesia. Potash manure salt. Kainit. Sylvinit. Potash-magnesia carbonate. Carbonate of potash. 258 SOIL FERTIUTY AND FERTILIZERS 4. Fertilizers furnishing nitrogen and phosphoric acid. Tankage (bone and nitrogenous). Fish fertilizers ) , -j , 4. j T, r 4.M- t raw and acidulated Bone fertilizers J Bat guano. Peruvian guano. 5. Mixed fertilizers. Nitrogenous superphosphates ) ^^ mixtures Special fertilizers ) ■' Home mixtures. 6. Miscellaneous fertilizers. Potassium nitrate. Tobacco stems and stalks. Wood ashes. Cotton hull ashes. Lime kiln ashes. Brick kiln ashes. Corn cob ashes. Pulverized manures (sheep, poultry, pigeon, etc.). Leather preparations. Wool and hair waste (treated and untreated). Fertilizers from beet molasses. Fertilizers from wine lees. Dried peat. Marl. Liquid fertilizers. Flower fertilizers. Shoddy (treated and untreated). Soot. Seaweed. Sewage. Ground feldsphatic rock (silicate of potash). Manufacturing wastes, etc. COMMERCIAI, FERTIWZERS 259 7. Indirect fertilizers — amendments. Ground limestone. Lime. Gypsum. Common salt (agricultural salt). Silicate of soda. Sulphate and carbonate of magnesia. Manganese salts. Iron sulphate. The factory fertilizers coming under the class, "mixed fer- tilizers," are not sold under the names, nitrogenous superphos- phates and special fertilizers. The manufacturers use attrac- tive names for these fertilizers and these names are no indica- tion of the composition and source of these mixtures. For ex- ample a nitrogenous superphosphate or a special mixture may be sold as Complete Potato Manure, Cotton King, Wheat Har- vester, Golden Dust, Best Ever, Non Pariel, or any other name that suits the fancy of the manufacturer. This classification, as nitrogenous superphosphate and special fertilizer, is made by the chemist to cover all the factory mixed fertilizers whether they furnish nitrogen, phosphoric acid and potash, nitrogen and potash, or nitrogen and phosphoric acid. Basis of Purchase of Fertilizers. — There are two systems used in purchasing fertilizers, namely, the unit system and the ton system. I. The Unit System. — A unit is 20 pounds or one per cent, of a ton. Manufacturers and dealers in fertilizer materials use the unit system almost entirely. Tankage, bone products, blood, azotin, steamed horn and hoof meal, potash salts, nitrogenous salts, superphosphates, dry ground fish, raw rock phosphates, cotton-seed meal, castor pomace, etc., are all purchased on the unit basis. For example, muriate of potash will be quoted at 80 cents a unit. This means that the actual potash in muriate of potash will cost 80 cents for 20 pounds, or 4 cents for one pound. Dried blood perhaps will be quoted at $3.30 per unit of nitrogen. This means that 20 pounds of nitrogen in dried blood will cost $3.30, or 16^ cents for one pound. 26o soil, FERTILITY AND FERTILIZERS In the unit system of purchasing and selling, the buyer and seller usually employ a competent neutral chemist to draw a re- presentive sample of the material and settlement is made on the chemist's findings. This is indeed an excellent system because the buyer pays for just what is present in the material and the seller receives compensation for what his product contains. It may be said that this system is very satisfactory to the fertilizer trade. 2. The ton basis of purchase is the one commonly used by the manufacturer, dealer, etc., in selling to the consumer. The prod- ucts, both mixed and unmixed, are sold to the consumer at a fixed price per ton of 2,000 pounds. This system is not as satisfactory as the unit system because the purchaser does not always receive a stipulated amount of the constituents contracted for. To be sure, the manufacturers guarantee their products to contain given amounts of fertilizer constituents and aim to meet or even to exceed their guarantees, but sometimes the fer- tilizers do not reach them in every particular. The prices of the fertilizers sold on the ton basis to the consumer do not usually fluctuate with the market, as the manufacturer tries to fix a price that will guard against loss, although many of them sell their fertilizers at times with very small and sometimes no profit when they have a large stock which they do not wish to carry over for another season. Fertilizer Laws. — In order to protect the consumer and the >-^ 100 LBS CORN FERTILIZER. MANUF/ICTU/t£0 BY JOHN BHOVJN MEMPHIS, TENN. /iVArLABLB PHOSPHORIC ACID 11.00 % NiTftOOEN 1.65 AMMONIA 2.00 POTASH 2.00 Fig. 22.— A fertilizer tag with guarantee. honest manufacturer, several states have passed laws regulating COMMERCIAI, FERTIUZERS 261 the sale of fertilizers. The enforcement of these laws is gen- erally controlled by the Experiment Stations or the State Boards of Agriculture, through a staff of chemists and inspectors. The inspectors, who may or may not be chemists, draw samples of the various fertilizers, forward them to the laboratory, and the chemist analyzes them to find out if they are as represented. The results of the chemists' findings are published in bulletins or reports which are sent to the consumers, manufacturers, deal- ers, and other interested parties. These laws require the manufacturers and dealers in fertili- zers "to state what they sell and sell what they state." In other words they are compelled to guarantee their products. For ex- ample. The Smith Fertilizing Company are putting out a com- plete fertilizer, one that furnishes nitrogen, phosphoric acid and potash. Before The Smith Fertilizer Comipany can ship any of this fertilizer they must have printed on the bags, or on tags attached to the bags, the composition of the fertilizer, expressed by the minimum percentages of nitrogen, available phosphoric acid and potash, the weight of the package, the name, brand, or trade mark, and the manufacturer's or dealer's or jobber's name and address. Let us suppose The Smith Fertilizer Company has the fol- lowing statement printed on their sacks or on tags attached thereto. THE SMITH FERTILIZER COMPANY NEW ORLEANS, LOUISIANA. CORN FERTILIZER. Weight 100 lbs. Guaranteed Analysis. Nitrogen 1.65 per cent. Ammonia 2.00 per cent. Soluble phosphoric acid 8.00 per cent. Reverted phosphoric acid 2.00 per cent. Insoluble phosphoric acid 2.00 per cent. Total phosphoric acid 12.00 per cent. Available phosphoric acid 10.00 per cent. Potash 4.00 per cent. 262 SOIL FERTILITY AND FERTILIZERS The name of the manufacturer, address, name^of brand, weight of the package, and the amounts of the essential elements nitro- gen, phosphoric acid and potash are given; therefore such a statement is the guarantee. The weight of the package is a good requirement in fertilizer laws because the purchaser is able to tell just the amount con- tained in the package. The composition of the fertilizer enables the consumer to tell the amounts of fertilizer constituents he is buying. The guarantee then protects the consumer and pro- hibits the unscrupulous manufacturer from selling fertilizer not as represented in those states where fertilizer laws are enforced. Comparison of Some of the Requirements of Fertilizer Xaws. — The fertilizer laws in the several states are not all the same. They all agree on requiring, 1. The name of the manufacturer, dealer, jobber, or agent. 2. The address of the manufacturer, dealer, jobber, or agent 3. The name, brand or trade mark. 4. The weight of the package. In the guaranteed chemical analysis there is not much uni- formity in the requirements of different states. For example, one state will require the percentage of nitrogen and its equiva- lent in ammonia, another the nitrogen only, and still another will require the percentage of available nitrogen. Some require in- soluble phosphoric acid; others do not. Some require a state- ment of available phosphoric acid; others state that the avail- able phosphoric acid is not sufficient, but the soluble and reverted phosphoric acid must be given. Some require soluble potash; others require potash. Kansas and Illinois require the plant food to be guaranteed as elements (nitrogen, phosphorus and potassium) instead of as phosphoric acid and potash. Some states require the sources of nitrogen, phosphoric acid and potash; others do not. Georgia does not allow fertilizers that are very wet or in a bad mechanical condition to be sold; some of the other states 'do not make this provision. Indiana requires that the names of the towns where the fertilizer is to be sold must be furnished the State Chemist. Some states require COMMERCIAL FERTILIZERS 263 that a stipulated weight of sample be drawn; others do not. Some states require that a duplicate sample be left with the party or parties where the sample is drawn. Some states do not allow the total amount of plant food to be lowered during the season in a given brand. They allow changing of the amounts of the constituents but the total plant food must not be lowered on any brand. There is a great difference in other requirements of these laws. For example, some states exempt wood ashes, manures and marl from being licensed or tagged; others do not. Some states will not allow leather to be used ; others do not stipulate that it cannot be used. Pennsylvania will not allow leather, hair, ground hoof or horn, wool waste, raw, steamed or in any form to be used in commercial fertilizer. Some states require that no fertilizer shall be sold that contains less than 12 per cent, of total plant food, when nitrogen is calculated as ammonia. Some states require all mixed fertilizers and acid phosphates to be sold with the names High Grade or Standard Grade printed on the sacks or tags, and that High Grade mixed fertilizers and acid phosphates shall contain at least 14 per cent, of total plant food, calculating nitrogen as ammonia, and Standard Grade shall contain, in all mixed fertilizers and acid phosphates, at least 12 per cent, of total plant food when nitrogen is calculated as ammonia ; and less than 0.82 per cent, of nitrogen and i per cent, of potash cannot be sold in any High Grade or Standard Grade fertilizer. Massachusetts states that the retail prices per ton and the comparative commercial values may be published. Some states fine the manufacturer, jobber, or dealer when fertilizers fail to reach their guarantee and the fines vary with the laws. Some states sieze shipments when they are not guaranteed. Some states require a license tax, i.e., a stipulated amount per brand per year. Indiana requires a license tax and a tonnage tax ; that is, a brand tax and a tax on every ton or part of a ton sold. Many states require a tonnage tax. Georgia requires 10 cents a ton tax, while Louisiana stipulates 25 cents a ton. Louisiana has 12 to 15 inspectors on the road all the time who draw the samples. Many other states send out inspectors at certain times 264 SOII< FEKTILITY AND FERTILIZERS of the year who draw the samples wherever they can get them. In Louisiana the manufacturer, dealer, or jobber must notify the chief inspector when and where he ships his fertilizers. There are many other variations in the state fertilizer laws, almost too numerous to mention in this discussion. Model Fertilizer Law. — On account of the variations in the re- quirements of the several state fertilizer laws, the following law was adopted by the Association of American Agricultural Col- leges and Experiment Stations. This law requires the plant food to be stated as elements nitrogen, phosphorus and potassium instead of phosphoric acid and potash. An ACT to prevent fraud in the manufacture and sale of com- mercial fertilizers. Section i. Be it enacted by the people of the State of represented in the General Assembly: That any person or com- pany who shall offer, sell, or expose for sale, in this State any commercial fertilizer, the price of which exceeds five dollars a ton, shall affix to every package in a conspicuous place on the outside thereof, or furnish to the purchasers of goods sold in bulk, a plainly printed certificate, naming the materials, includ- ing the filler (if any), of which the fertilizer is made, stating the name or trade mark under which the article is sold, the name of the manufacturer and the place of manufacture, and a chemical analysis, stating only the minimum percentages of nitrogen in available form, of potassium soluble in water, of phosphorus in available form (soluble or reverted), and of insoluble phosphorus, the analyses to be made in accordance with the methods adopted by the Association of Official Agricultural Chemists of the United States. Section 2. Before any commercial fertilizer is sold, or offered for sale, the manufacturer, importer, or party who causes it to be sold, or offered for sale, within the State of shall file in the office of the State Board of Agriculture, a certified copy of the certificate referred to in Section i of this ACT, and shall deposit with the secretary of the said Board of Agriculture COMMERCIAI, FERTILIZERS 265 a sealed glass jar, containing not less than one pound of the fer- tilizer, accompanied with an affidavit that it is a fair average sam- ple. Section 3. The manufacturer, importer, or agent of any com- mercial fertilizer exceeding five dollars per ton in price, shall pay, annually, a license fee of twenty-five dollars for each one thousand tons (or fraction thereof) of said fertilizer, for the privilege of selling or offering for sale, within the State, during the calendar year, said fee to be paid to the treasurer of State Board of Agriculture : Provided, that whenever the manu- facturer or importer shall have paid the license fee herein re- quired, any person previously certified to the Office of the State Board of Agriculture to be an authorized agent for such manu- facturer or importer shall not be required to pay the fee named in this section. Section 4. All analyses of commercial fertilizers sold within the State, shall be under the direction of the State Board of Agriculture, and paid for out of funds arising from license fees, as provided for in Section 3. At least one analysis of each fer- tilizer shall be made annually, from a sample collected in open market. Section 5. Any person or party who shall offer or expose for sale any commercial fertilizer without complying with the pro- visions of Sections i, 2, and 3 of this ACT; or shall permit an analysis of such fertilizer to be furnished, stating that it contains a larger percentage of any one or more of the constituents named in Section i of this ACT, than it really does contain, shall be fined not less than two hundred dollars for the first offense, and not less than five hundred dollars for every subsequent offense; and the offender, in all cases, shall also be liable for damages sustained by the purchaser of such fertilizer: Provided, how- ever, that a deficiency of one-half per cent, of the nitrogen, po- tassium, or phosphorus claimed to be contained, shall not be con- sidered as evidence of fraudulent intent. Section 6. Suit may be brought for the recovery of fines or damages under the provisions of this ACT, in the county where 266 soil, FERTXI,ITY AND FERTILIZERS the fertilizer was offered for sale, or where it was manufactured ; and all fines so recovered, shall be paid into the treasury of the State Board of Agriculture by the court collecting the same. The treasurer of the State Board of Agriculture, after payment of expenses for collecting and analysis, and the publication of the annual report relating to the analysis, use, and results ob- tained from fertilizers, shall on or before the first day of July pay into the treasury of the State any surplus remaining in his hands, on account of license fees and fines, received during the previous calendar year through the provisions of this ACT. Section 7. The State Board of Agriculture shall pub- lish, annually, a correct report of all analyses made and certifi- cates filed, together with a statement of moneys received on ac- count of license fees and fines, and expended for analyses and publication of the report relating to fertilizers. Section 8. The officers and members of the State Board of Agriculture or any person authorized by said board is here- by empowered to select from any lot or package of commercial fertilizers exposed for sale in any county of , a quantity not exceeding two pounds, which quantity shall be for analysis to compare with the sample deposited with the secretary of said Board of Agriculture, as provided for in Section 2 of this ACT, and with the printed certificate described in Section i. Section 9. All suits for the recovery of fines, under provi- sions of this ACT, shall be brought by the Attorney-general of the State in the name of the people of the State of .^° Comments on this Law. — The committee on fertilizer legislation, of the Association of Official Agricultural Chemists, make the following statements, in Bui. 116, Bureau of Chemistry: It is evident, however, that there would be many points of dispute, not only between the officials of the various States re- specting the proper method of tagging and of expressing analyti- cal results, but also a still wider disagreement between the State Officials and the manufacturers. It seems, therefore, unwise to press the subject of national legislation in regard to fertiH- zers further until the officials of this association, representing as COMMERCIAL FERTILIZERS 267 they do the majority of States exercising fertilizer control, can come to an agreement respecting a uniform system of labels and of methods of expressing analysis. This subject, as is well known, has been under discussion by our association for several years, and satisfactory and encouraging progress has been made. This leads to the hope that in a few years more the representa- tives of each State in this association may come to an agreement on this important subject. The committee does not deem it wise to favor any form of national legislation which would in any way interfere with the State system of control of fertilizers. That is a matter with which, in our opinion, the National Government has nothing whatever to do. The systems of control, as is well known, are not uniform. In some States a tax is laid upon the gross tonnage of fertilizers sold. In other States a tax is laid upon the labels which are attached to the various packages, and other forms of control are exercised. It is believed that the wisest control of this kind is that which seems best to the State officials who have charge of such matters, and the State legislatures which estab- lish the legal status of such control. This committee, therefore, is opposed to any national legislation which would attempt to influence the States in any way respecting the method of control of fertilizer sales within the States. After repeated attempts to secure suggestions from manu- facturers, your committee is of the opinion that upon the whole the manufacturers themselves would rather not have national legislation and prefer to submit to the disadvantages of the pres- ent system rather than to see incorporated in a national law any system of stating analyses or the character of the materials used in the compounding of fertilizers which would be objectionable to them. This, however, does not seem a sufficient ground upon which to advise that no national action be taken, and it seems ad- visable to endeavor to secure from the manufacturers a full ex- pression of their views in order that the matter may be widely discussed. If it were possible to extend the agreement among the State officials already referred to relating to methods of tag- 268 soil, FERTILITY AND FERTILIZERS ging and of stating the results of analytical work, so as to ob- tain the approval of the manufacturers, the difficulties in the way of a national law would be practically eliminated. In this case the enactment of such a law would prove beneficial to all parties by aiding in securing the agreement among the various States. Your committee therefore recommends that for the present no attempt be made to bring a national fertilizer law to the at- tention of the Congress with the object of controlling commerce in fertilizers in the District of Columbia and the Territories of the United States and in interstate commerce, but that, on the other hand, an effort be made to secure an agreement among all the State officials respecting the fundamental definitions of the misbranding and adulteration of a fertilizer, and a common understanding respecting the proper method of tagging or brand- ing, and the proper method of stating the results of analysis; that an attempt be made to secure an agreement between the officials of the States and the fertilizer manufacturers respecting the proper method of referring to the crude sources of the plant food which may be present in any given fertilizer. This com- mittee believes that all these points should be settled before any concerted effort is made to bring the matter of national fertilizer control to the attention of Congress. Further than this, your committee is of the opinion that when such an effort is made it should relate solely to the fundamental conditions above men- tioned, and should be so conducted as not in any way to affect the States in respect to the proper methods of raising revenue from fertilizers sold under the State control. Tentative Sefinitions of Fertilizers and of Misbranding and Adulteration. — (i) A fertilizer shall be defined as any simple, compound, or mixed material, prepared for the purpose of sell- ing, or sold, or offered for sale, to be applied to the soil as nourishment for plants, or as a modifier of the soil in any re- spect in its relation to the growth of plants. The term "fertilizer material" (or ingredients) shall include every plant- food materia] which is utiHzed, or intended to be utilized, in the manu- facture, preparation, or mixing of the fertilizers defined above. COMMERCIAI, FERTIUZERS 2^ (2) A fertilizer, or fertilizer material (or ingredient), shall be deemed to be adulterated: (a) If the percentage of any of its ingredients fall materially below the professed standard under which it is sold, whether this standard appear as a label upon the package or as a guaranty in any other way by the vendor thereof. (b) If any of the ingredients thereof have an origin other than that indicated upon the package, or guaranteed in any other way by the vendor thereof. (c) If any of the ingredients of the fertilizer, or fertilizer material, be in a state of combination different from that indi- cated by the label or guaranteed by the vendor thereof. (3) A fertilizer, or fertilizer material, shall be deemed as mis- branded : (a) If any false name or misleading statement or design or device be affixed to any package thereof or used in any way as a representation of the materials thereof by the vendor. (b) If any false or misleading statement respecting the origin of the material be made upon the label, or any statement or guaranty of the vendor. (c) If any false or misleading statement be made upon the label, or by the vendor, respecting the country or origin of the materials of which the fertilizer is composed. (d) If any false or misleading statement be made on the label, or by the vendor, respecting the virtues or qualities of the fertilizer or the materials composing it. (e) If sold under any false name or appellation, whether such name appear upon the package or label or be given to the article by the vendor thereof. (f) If it be an imitation of or offered for sale under the name of another fertilizer or fertilizer material. 270 soil. FERTILITY AND FERTILIZERS The Meaning of the Guarantee. — It has been said that the manu- facturer, dealer, or jobber must have printed on the bags or tags attached to the bags, his name and address, the weight of the package, the name, brand or trade mark, and the chemical com- position of the fertilizer. This guarantee does not mean that each particular shipment, or lot, or bag, that the consumer may purchase has been analyzed by the state chemist and that he found the stipulated amounts of nitrogen, soluble phosphoric acid, reverted phosphoric acid and potash, as the case may be, that are printed as the guaranteed chemical analysis on the bags or tags. It does mean that the manufacturer says he has fur- nished at least those amounts of plant food as stated. The Interpretation of the Guarantee. — Some manufacturers do not make a simple statement of the guaranteed chemical com- position of their brands of fertilizers, but use other terms which are equivalent, to be sure, but are misleading to the ordinary per- son not familiar with fertilizer parlance. A few examples may serve to illustrate this point. Guaranteed Chemical Analysis No. i. Per cent. Nitrogen i.oo Ammonia 1.22 Equal to nitrate of soda 6.06 Total phosphoric acid 12.00 Equivalent to bone phosphate 26.00 Available phosphoric acid 10.00 To simplify this guarantee we would state it as: Per cent. Nitrogen as nitrate i Total phosphoric acid 12 Available phosphoric acid 10 All the other statements omitted in the simplified chemical guarantee are correct but unnecessary and misleading. The percentage given under "equal to nitrate of soda," and "equivalent to bone phosphate" are simply restatements. Conversion Factors. — The following may be of help in obtain- ing equivalents of fertilizer ingredients: COMMERCIAL FERTILIZERS 27I I per cent, nitrogen = 1,2154 per cent, ammonia. I per cent, ammonia = 0.823 per cent, nitrogen. I per cent, nitrogen = 6.06 per cent, nitrate of soda. I per cent, nitrate of soda = 0.165 P^"^ cent, nitrogen. I per cent, nitrogen = 7. 207 per cent, nitrate of potash. I per cent, nitrate of potash = o. 139 per cent, nitrogen. I per cent, nitrogen — 4.791 per cent, sulphate of am- monia. 1 per cent, sulphate of ammonia . . .= 0.209 per cent, nitrogen. 1 per cent, potash = 1.5S2 per cent, muriate of potash. I per cent, muriate of potash = 0.632 per cent, potash. I per cent, potash = 1.849 per cent, sulphate of potash. 1 per cent, sulphate of potash = 0.541 per cent, potash. I per cent, potash = 1.467 per cent, carbonate of potash. 1 per cent, carbonate of potash = 0.682 per cent, potash. 1 per cent, nitrate of potash = 0.466 per cent, potash. I per cent, potash = 2.146 per cent, nitrate of potash. I per cent, phosphoric acid ^ 2. 185 per cent, bone phosphate of lime. 1 per cent, bone phosphate of lime. -^ 0.458 per cent, phosphoric acid. Example : Muriate of potash guaranteed 80 per cent, contains 80 X 0.632 or 50.56 per cent, potash. Nitrate of soda guaran- teed 95 per cent, contains 95 X 0.165 or 15.68 per cent, nitrogen. 15.68 per cent, nitrogen is equivalent to 15.68 X 1-2154 or 19.06 per cent, ammonia. Guaranteed Chemicai, Analysis No. 2. Per cent. Total phosphoric acid 11-14 Equivalent to total bone phosphate 24-30 Available phosphoric acid 10-12 Equivalent to available bone phosphate 22-26 Soluble phosphoric acid 8-10 Equivalent to soluble bone phosphate 17.5-22 Insoluble phosphoric acid 1-2 Equivalent to insoluble bone phosphate 2-4.25 Potash 4-5 Equivalent of sulphate of potash 7-4-9 Total nitrogen 2-3 Equivalent to total ammonia 2.4-3.6 This is not an exaggerated guarantee but one that is often found in the fertilizer trade. Simplified the above reads : 272 soil, FERTILITY AND FERTIUZERS Percent. Total phosphoric acid 11 Available phosphoric acid 10 Soluble phosphoric acid 8 Insoluble phosphoric acid i Potash 4 Nitrogen 2 Or we may further simplify this to read : Per cent. Available phosphoric acid 10 Potash 4 Nitrogen 2 It will be noticed that the simplified statements contain the minimum percentages; for example, available phosphoric acid is guaranteed as 10 to 12 per cent, and in the simplified state- ment it is given as being 10 per cent. This latter figure, 10 per cent., is all the manufacturer guarantees and the maximum guarantee of 12 per cent, is misleading and does not mean anything. It seems to be common practice with the manu- facturers to use both the minimum and maximum guarantees. Guaranteed Chemical Analysis No. 3. Per cent. Total phosphoric acid lo.o to 12.0 Available phosphoric acid 9.0 to lo.o Insoluble phosphoric acid i .0 to 2.0 Soluble phosphoric acid 6.0 to 8.0 Equal to available bone phosphate 19.7 to 22.0 Potash 3.5 to 5.0 Nitrogen 0.82 to 1.65 Ammonia i.o to 2.0 Simplified this guarantee would read: Per cent. Available phosphoric acid 9.0 Potash 3.5 Nitrogen 0.82 Guaranteed Chemicai, Analysis No. 4. Per cent. Total bone phosphate 32. 7 to 43.7 Yielding total phosphoric acid 15.0 to 20.0 Soluble bone phosphate 22.0 to 28.0 Yielding soluble phosphoric acid lo.o to 13.0 Reverted bone phosphate 8.7 to 10.9 Yielding reverted phosphoric acid 4.0 to 5.0 Insoluble bone phosphate 2.2 to 4.4 Yielding insoluble phosphoric acid i.o to 2.0 COMMERCIAL FERTILIZERS 273 Simplified this would read: Per cent. Soluble phosphoric acid- • • • lo-o Reverted phosphoric acid 4° Insoluble phosphoric acid i-o Or we could state it as follows : Per cent. Available phosphoric acid i4-o There are many manufacturers who put guarantees on their brands that are not misleading and may be easily interpreted by the ordinary person. A few brands from a large fertiliz- er factory are tabulated. Name of brand Total phosphoric acid Per cent. High grade acid phosphate Acid phosphate Kainit Sulphate of potash Muriate of potash Cotton-seed meal Blood, bone and meat Farmers' choice Ground bone and potash High grade truck grower Ammoniated raw bone superphos- phate and potash Vegetable fertilizer Sugar-cane grower Raw bone rice Special formula Bone meal Acid phosphate and potash Guarantee Available phosphoric acid Per cent. 17 15 10.50 10.50 15.00 10.00 10.50 7.00 1 1. 00 1050 8.50 18.50 11.00 16 14 9-50 950 8.00 9-5° 6.00 10.00 9-5° 7-50 10.00 Nitrogen Per cent. 6.58 1.65 1.65 2.75 3-5° 1.65 2.50 2.50 1.65 4.12 2.50 Potash Per cent. 12 50 50 I-50 1. 00 3.00 7.00 1.50 5.00 2.00 1-5° Raw Materials are Sometimes Sold on Purity. — Raw materials like nitrate of soda, raw rock phosphate and the potash salts are often sold to the manufacturers and jobbers according to the per cent, of purity as illustrated. Per cent. Nitrate of soda 95 Raw rock phosphate 78 Sulphate of potash 96 Muriate of potash 80 274 SOIL FERTILITY AND FERTILIZERS This means that: 95 per cent, nitrate of soda contains 95 per cent, nitrates. 78 per cent, raw rock phosphate contains 78 per cent, phosphate of lime. 96 per cent, sulphate of potash contains 96 per cent, sulphate. 80 per cent, muriate of potash contains 80 per cent, muriate. Using our conversion factors we find that the above corre- spond to : 15.68 per cent, nitrogen from 95 per cent.Jnitrate of soda. 35.72 per cent, phosphoric acid from 78 per cent, raw rock phosphate. 51.94 per cent, potash from 96 per cent, sulphate of potash. 50.56 per cent, potash from 80 per cent, muriate of potash. CHAPTER XIII VALUATION OF FERTHIZERS. Interpretation of Chemical Analyses. — A chemical analysis of a fertilizer may indicate to a great extent the value or suitability of it. The following two analyses illustrate this point. Chemical Analysis No. i. Per cent. Nitrogen as nitrate .- i Nitrogen as ammonia i Organic nitrogen 2 Total nitrogen 4 Water soluble phosphoric acid 8 Reverted phosphoric acid 2 Insoluble phosphoric acid 2 Available phosphoric acid lo Total potash 9 Potash as chloride 2 Potash as sulphate 7 Chemical Analysls No. 2. Per cent. Nitrogen as nitrate — Nitrogen as ammonia — Organic nitrogen 4 Total nitrogen 4 Water soluble phosphoric acid 2 Reverted phosphoric acid 8 Insoluble phosphoric acid 2 Available phosphoric acid 10 Total potash 9 Potash as chloride 8 Potash as sulphate i Both of the above fertilizers contain equal amounts of nitro- gen, phosphoric acid and potash and could be stated as fol- lows: Per cent. Nitrogen 4 Available phosphoric acid 10 Potash 9 Fertilizer No. i contains nitrogen as nitrates and as ammonia while No. 2 does not. Both brands contain organic nitrogen; No. I containing 2 per cent, and No. 2 carries all of its nitro- 19 276 SOIL FERTILITY AND FERTILIZERS gen in this form. The chemist cannot always tell the source of the organic nitrogen. When the organic nitrogen is derived from dried blood, azotin, cotton-seed meal, steamed horn and hoof meal, and similar nitrogenous organic materials it is valu- able but when derived from leather preparations, dissolved wool and shoddy wastes, etc., it is not so desirable. Therefore the purchaser would perhaps select Brand No. i for its nitro- gen content as it is to be supposed that the manufacturer using high grade materials as nitrate of soda and sulphate of ammonia would furnish organic nitrogen from high grade materials. A glance at the phosphoric acid constituents shows that both run 10 per cent, available phosphoric acid but No. I contains 6 per cent, more phosphoric acid in the soluble form. As solu- ble phosphoric acid distributes more readily in the soil than reverted phosphoric acid and is more available as plant food, we would naturally prefer Analysis No. i from the phosphoric acid standpoint. Glancing at the potash we find that No. i carries 2 per cent, as chloride and 7 per cent, as sulphate, while No. 2 shows 8 per cent, as chloride and i per cent, as sulphate. For crops like tobacco, potatoes, sugar beets, oranges, etc.. No. I would be the most suitable, since these crops do better with sulphate of potash than with muriate of potash. The potash in No. T was in all probability derived mostly from sulphate of potash while that in No. 2 came mostly from muriate of potash. Here is another statement that is used by some chemists in reporting analyses. Chemical Analysis No. 3. Per cent. Nitrogen 2 Soluble phosphoric acid 7 Reverted phosphoric acid 3 Insoluble phosphoric acid 2 Available phosphoric acid 10 Potash Q This statement is not so valuable as Nos. i and 2 because the forms of nitrogen and potash are not given. The nitrogen may all be from nitrate of soda, or sulphate of ammonia, or organic sources, or from any two or perhaps be furnished from ill of VALUATION OP FERTILIZERS 2/7 these sources. The potash may be as sulphate, or as chloride, or as carbonate, or as a mixture of any two or three of these forms in any pi'oportion. Here is still another statement. Chemical Analysis No. 4. Per cent. Nitrogen 4 Available phosphoric acid 10 Potash 9 This analysis besides not furnishing the amounts of the forms of nitrogen and potash does not give the forms of phosphoric acid. Of this lo per cent, available phosphoric acid all of it may be as soluble, or as reverted. It may contain both soluble and reverted phosphoric acid but in just what amounts we do not know. The chemical analysis, when the different forms of plant food are reported, may often prove of value to those farmers who can interpret them and who understand the influence of the plant food forms on profitable crop production. Agricultural Values. — The agricultural value of a fertilizer is represented by the crop produced. The price that is paid for a fertilizer has no bearing on its agricultural value. The agricultural value will vary with the season, the amount of fertilizer used, the nature of the soil, kind of crop, care of the crop, locality, insect damage, plant diseases, and many other conditions. It cannot be estimated and is often beyond the con- trol of man. However, the nature of the materials that make up a fertilizer may influence its agricultural value. Market garden crops will no doubt do better with fertiHzers containing plant food in available and soluble forms. For example, avail- able phosphoric acid will give quicker returns than insoluble phosphoric acid. Nitrogen in a soluble form will be taken up more readily than nitrogen in an organic form and some organic forms of nitrogen will be more quickly available than others. In other words fertilizers that give up their plant food slowly will not have a high agricultural value for quick growing crops. Again, the crop to be raised may have a long growing season. 278 SOIL FERTILITY AND FERTILIZERS If such is the case it would not pay to use fertilizer whose plant food is all in soluble forms. If the nitrogen is all soluble, as in nitrate of soda and sulphate of ammonia, it may be used up or lost before the crop has finished growing and some slower acting form of nitrogen, as is contained in dried blood, cotton- seed meal, tankage, etc., would no doubt give greater crop re- turns. The value of the crop must also be considered, for crops of low market value cannot always be expected to give profitable returns with high priced fertilizers. The cost of a fertilizer of low agricultural value may be greater than one that has a high value in producing crops. Farm manures, wood ashes, land plaster, etc., may be comparatively high in price for the amount of plant food they contain or the good they do. Commercial Values. — The commercial value of a fertilizer is entirely different from the agricultural value. It represents the retail cost of raw materials of standard quality in the market, from which the commercial or trade value of plant food may be calculated. For example, nitrate of soda may be quoted at $50 a ton. This represents its commercial value. As nitrate of soda contains 15.5 per cent, of nitrogen or 310 pounds of nitrogen in a ton, its nitrogen has a commercial or trade value of a little over 16 cents a pound. An acid phosphate containing 14 per cent, of available phosphoric acid may carry a retail price of $14 a ton, which is its commercial value. The com- mercial or trade value of the available phosphoric acid would be 5 cents a pound, since 14 per cent, of available phosphoric acid is equal to 280 pounds of available phosphoric acid in a ton. Or an acid phosphate may be quoted at $1 per unit. This is its com- mercial value. This means that the retail cost of 20 pounds of available phosphoric acid is $1. The commercial or trade value is then 5 cents a pound. The commercial or trade value does not mean that nitrogen at 16 cents a pound will produce 16 cents worth of crops, or available phosphoric acid at 5 cents a pound will produce crops that will bring 5 cents. These constituents may produce crops valued at more or less than 16 VAI^UATION OF FERTILIZERS 279 and 5 cents respectively, depending upon many conditions as season, locality, kind of crop, condition of the soil, tillage, etc. The commercial or trade value only serves as a comparison of the relative values of the different forms of plant food in the raw materials. This valuation does not represent the cost of the mixed goods. In the manufacture of fertilizers the cost of mixing, sacking, dryers, manufacturers' profit, long credits, freight, insurance, agents' profits, etc. are all added to this com- mercial or trade value, so that the farmer pays much more for plant food than is represented in the commercial or trade valua- tion. But the farmer may purchase the plant food contained in the rawr materials (unmixed), for the prices as represented by the commercial or trade values, at thoSe points where the retail prices are quoted. To get the fertilizer to his farm he will of course have to pay freight. Trade Values. — The Experiment Stations of Connecticut, New York, Rhode Island, Massachusetts, New Jersey and Vermont make out trade values every year for those materials that are most commonly used in the manufacture of mixed fertilizers. These values are arrived at by calculating the prices of fer- tilizer materials for the six months preceding March 1st, and are obtained from the leading markets of southern New England and the middle northern states. The following give the wholesale prices in New York City for fertilizer materials on January i, 1910. New York Wholesale Prices, Current January i, 1910— Fertilizer Materials." Ammoniates. Ammonia, sulphate, foreign, prompt, per 100 pounds.. $ 2.65 @ — futures 2.65 @ — sulphate, domestic, spot 2.67^@ — futures 2.651^® — Fish scrap, dried, 11 per cent, ammonia and 14 per cent. bone phosphate, f. o. b. fish works, per unit 2.85 & 10 wet, acidulated, 6 per cent, ammonia, 3 per cent, phosphoric acid, f. o. b. fish works. 2.35 & 35 28o soil. FERTILITY AND FERTILIZERS Ground fish guano, imported, lo and 1 1 per cent, am- monia, and 15-17 per cent, bone phosphate, c. i. f. N. Y., Baltimore or Philadelphia 3.00 & 10 Tankage, 11 per cent, and 15 percent., f. u. b. Chicago 2.75 (ri) 2.80 & 10 concentrated, f. o. b. Chicago, 14-15 per cent., b. Chicago 2.75 (w, — Garbage, tankage, f. o. b. Chicago 8.00 @ — Sheep manure, concentrated, f. o. b. Chicago, per ton 9.50 @ — Hoofmeal, f. o. b. Chicago, per unit 2.55 @ — Dried blood, 12-13 per cent, ammonia, f. o. b. New York 2.95 @ — Chicago 2.90 @ — Nitrate of soda, 95 per cent, spot., per 100 pounds — @ 2.10 futures, 95 per cent — @ 2.10 Fhosp/iaies. Acid phosphate, per unit 0.55 @ 0.60 Bones, rough, hard, per ton 20.50 @ 21.50 soft steamed, unground 18.50 @ 21.00 ground, steamed, l^ per ceut. ammonia and 60 per cent, bone phosphate 19.00 @ 19.50 ditto, 3 and 50 per cent 22.50 @ 22.50 raw, ground, 4 per cent, ammonia and 50 per cent, bone phosphate 26.00 @ 27.00 South Carolina phosphate rock, undried, per ^,400 lbs. f. o. b. Ashley River 5.50 @ 5.75 South Carolina phosphate rock, hot air dried, f. o. b. Ashley River 7.00 @ 7.25 Florida land pebble phosphate rock, 68 per cent., f. o. b. Port Tampa, Fla 3.75 @ 4.00 Florida high grade phosphate hard rock, 77 per cent., f. o. b. Florida or Georgia ports 7.00 @ 7.50 Tennessee phosphate rock, f. o. b. Mt. Pleasant, do- mestic, per ton, 78 @ 80 per cent 5.00 @ 5.50 75 per cent., guaranteed 4.75 @ 5.00 68 @ 72 per cent 4.00 @ 4.25 PoiasAes. Muriate potash, basis 80 per cent., per 100 pounds 1.90 @ — Manure salt, 20 per cent., actual potash 14-75 @ — double manure salt. 48 per cent i.i6^@ — Sulphate potash (basis 90 per cent.) 2.i8j^@ — Kainit in bulk, 2,240 pounds 8.50 @ — To give an idea of how these trade values are obtained we may presume that the wholesale price of sulphate of ammonia VALUATION OF FERTILIZERS 281 for the six months preceding March 1st averaged $56.80 per ton, or 14.2 cents a pound for the nitrogen. A certain amount, usually 20 per cent., is added to this wholesale price to cover the cost of handling, insurance, etc., which would raise the price to $68 per ton, which would be the retail or commercial value of ammonium sulphate. The nitrogen then would be represented as carrying a commercial or trade value of 17 cents a pound. The trade values on all other fertilizer materials are calculated in the same way as described for sulphate of ammonia. TRADE VALUES OF FERTILIZER ELEMENTS FOR 1909.'° The average trade-values or retail costs in market, per pound, of the ordinarily occurring forms of nitrogen, phosphoric acid and potash in raw materials and chemicals, as found in New Eng- land, New York and New Jersey markets during 1908 were as follows : Cents per pound Nitrogen in nitrates i6)4 ammonia salts 17 Organic nitrogen in dry and fine ground fish, meat and blood, and in mixed fertilizers 19 in fine'' bone and tankage 19 in coarse^ bone and tankage 14 Phosphoric acid, water-soluble 4 citrate-soluble' 3>^ of fine ground bone and tankage 3>^ of coarse bone and tankage 3 of cotton-seed meal, castor pomace and ashes 3 of mixed fertilizers, if insoluble in ammon- ium citrate' 2 Potash as high-grade sulphate in forms free from muriate (or chlorides) 5 as muriate 4X 1 Adopted at a conference of representatives of the Maine, Massachusetts, New Jer- sey, Rhode Island, Vermont and Connecticut stations held in March, 1909. 2 In this report "fine," as applied to bone and tankage, signifies smaller than 1/r^o inch; and "coarse,'' larger than l/joinch. 3 Dissolved from 2 grams of the fertilizer, previously extracted with pure water, by 100 cc. neutral solution of ammonium citrate, sp.gr. 1.09, in thirty minutes, at 65° C., with agitation once in five minutes. Commonly called "reverted" or "backgone" phos- phoric acid. 282 SOIL FERTILITY AND FERTILIZERS The foregoing are, as nearly as can be estimated, the prices at which, during the six months preceding March last, the respec- tive ingredients were retailed for cash, in our large markets, in those raw materials which are the regular source of supply. The valuations obtained by use of the above figures will be found to correspond fairly with the average retail prices, at the large markets, of standard raw materials. A study of the above table is interesting. It shows that valua- tions are given for nitrogen as nitrate, as ammonia and as or- ganic nitrogen. The trade values for organic nitrogen are also different depending upon the source. Soluble phosphoric acid is valued higher than reverted phosphoric acid and there is also a trade value for insoluble phosphoric acid. In some states there is no distinction made between soluble and reverted phosphoric acid in trade valuation and the insoluble phosphoric is often not considered at all in mixed fertilizers. The bone products in the foregoing table are valued on their degree of fineness ; ■ the finer bone-meals command higher market prices than those that are coarse as is shown in the trade valuations of nitrogen and phos- phoric acid. The potash as sulphate carries a higher trade value than potash as chloride, but this is to be expected because sulphate of potash costs more to manufacture than muriate of potash. There are many fertilizer materials not included in the above table. Those included in the table are high class products com- monly used in New England and New Jersey. How to Calculate the Commercial Value of a Fertilizer. — Let us suppose a chemist analyzes a mixed fertilizer and finds its com- position to be as follows: Chemical Analysis. Per cent Nitrogen as nitrates 0.50 Nitrogen as ammonia i . 30 Nitrogen as organic 2.00 Water soluble phosphoric acid 6,00 Phosphoric acid soluble in ammonium citrate (reverted) . . i.So Phosphoric acid insoluble (in water and ammonium citrate) 1.50 Potash as sulphate 0.40 Potash as chloride 3.60 VALUATION OF FERTILIZERS 283 The commercial valuation of the above fertilizer would be ob- tained by multiplying each ingredient by 20 to change to a ton basis, and multiplying this product by the trade value of each. The sum of these values would be the total commercial value as derived from the raw products. CoMMERCiAi, Valuation. Lbs. per 100 or per cent. Nitrate nitrogen o 50 X 20 ^ Ammonia nitrogen i .30 X 20 = Organic nitrogen 2.00 X 20 ^ Soluble phosphoric acid 6.00 X 20 = Reverted phosphoric acid i.So X 20 = Insoluble phosphoric acid i .50 X 20 := Potash as sulphate 0.40 X 20 ^ Potash as chloride 3.60 X 20 = Trade Commercial I,bs. value value per per lb. per ton cents ton 10 X 16.5 = fl.65 26 X 17 = 4.42 40 X 19 = 7.60 120 X 4 = 4.80 36 X 3-5 = 1.26 30X 2 = 0.60 8X5=- 0.40 72 X 4-25= 3.06 Total commercial value =)f23.79 Should we wish to determine the commercial value of a bone or tankage that contains fine and coarse bone the following ex- ample may illustrate the method employed. Let us suppose that on sifting the sample (which in this case is tankage), 60 per cent, of the tankage is finer than 1/50 of an inch and is therefore fine, and the remaining 40 per cent, is coarser than 1/50 of an inch and is therefore coarse. The nitrogen and phosphoric acid in the fine and coarse tankage are found to be the same and the tankage contains 6 per cent, of nitrogen and 10 per cent, of phosphoric acid. Then : Lbs. per 100 Per cent. Per cent, or per cent, of fineness lbs. per 100 Nitro.'en / 6 X 60 = 3.6 in fine tankage. iNitro^en \ 6 X 4o = 2.4 in coarse tankage. _,, . . .J ( 10 >' 60 = 6 in fine tankacfe. Phosphoric acid ^ jo ^ 40 == 4 i„ coarse tankage. Referring to the table of trade values we arrive at the follow- ins: commercial valuation of this tankage. 284 soil. FERTILITY AND FERTILIZERS Lbs. Trade value Commercial Lbs. per 100 per per lb. value per per cent. ton cents ton Nitrogen in fine tankage 3.6 X 20 = 72 X 19 = |i3-68 Nitrogen in coarse tankage- • 2.4 X 20 ^ 48 X I4 ^ ^-72 Phosphoric acid in fine tank- age 6 X 20 = 120 X 3-5 = 4-20 Phosphoric acid in coarse tankage 4 X 20 = 80 X 3 = 2.40 Total commercial value • ^ J27.00 The same methods as illustrated in the foregoing examples are used for obtaining the valuations on all fertilizers. Comments Begarding Valuations. — The Vermont Experiment Station has the following to say regarding valuations. Year after year the meaning of the valuation system is un- folded in the station bulletins, both in connection with the sched- ule and as a footnote to every table of analyses. Black faced type and italics are used to emphasize this matter and to point out more particularly what these valuations are not. Yet not- withstanding this extreme care they doubtless are often misun- derstood and misused. Indeed this condition is met to such an extent that the application of money valuations to fertilizers is forbidden by law in one New England state and is omitted in one or two others. The writer, however, believes that they serve a good purpose when properly used, and that it is better for the present at least to employ them than to abandon them, laying, however, all possible stress on their true meaning, repeating, re- iterating, stating and then restating in another form, the more surely to accompHsh the desired end. The "valuations" simply show the retail cash value of raw unmixed plant food of good quality in Boston and New York. Thus for example we will assume that the system is applied in due course to an analysis of Smith's Sugar Cane Grower and that the nitrogen in a ton "valued" at $7.94, the phosphoric acid "valued" at $8.68 and the potash "valued" at $6.81. These statements, which are just such as are made in the tables of analyses under the headings of "Valuation of nitrogen in one ton" (and similarly for the other two ingredients), do not mean that a ton of Smith's Sugar Cane Grower is worth $7.94 -|- VALUATION Of FERTILIZERS 285 $8.68 + $6.81 or $23.43. They do not mean that $23.43 is a proper price to pay the local agent for this brand. They do not mean that this is the agent's buying price. They do not mean that this is the probable service a ton of this brand will give the farmer expressed in terms of money. They do not mean that this sum is the commercial value of the brand ; much less do they mean that it is any measure of its agricultural worth. What they do mean and all they mean is simply this; that the same amounts of the very best forms of plant food as are found in a ton of Smith's Sugar Cane Grower could have been bought at retail in an unmixed condition in Boston or New York for $23.43. They do not mean that the plant food the manufacturer used of necessity had this commercial value during this time. It may have had a less one, but it can hardly have had a greater (except in cases of marked fluctuations during the fall and winter in the prices of the crude fertilizing materials, or unless the manufac- turer deliberately elected to use a commercially expensive form of phosphoric acid). The station does not pretend dogmatically to state the commercial worth or valuation of any given fertilizer. And as for its agricultural value, its crop producing power, no man can say. Adverse weather conditions, insect depredations, blight injuries, poor tillage, the use of insufficient amounts, or a dozen other contingencies may make the best of plant food of little service. Valuations Show Cost of Plant Food. — It will be seen by this that valuations simply show the cost of ready-made plant food. The cost of this plant food, however, is but one of the many charges which determine the retail cost of commercial fertilizers. It is the main item, but there are others. The sundry forms of plant food when ready for use in making commercial fertilizers have to be mixed, stored, reground, bagged, loaded, and freighted. Then, too, commissions to agents and dealers, the expense of sell- ing on long credit, the item of bad debts, the interest on in- vestments, the depreciation of the manufacturing plant, profits, etc., are also proper and fixed charges. All these cost money and must, in the end, be paid for by the consumer of mixed fertilizers. Not one of them contributes in the least to plant 286 SOIL FERTILITY AND FERTILIZERS growth, Commercial fertilizers are usually applied in the mixed form, but this is simply a matter of convenience. The mixing adds no virtue to them (except the mixing of sulphuric acid with raw phosphate) and as good results may be obtained by the separate application of the crude ingredients. An illustration may serve to make these statements more clear. A farmer buys in Boston or New York 50 pounds of nitrate of soda, 350 pounds of dried blood, 1,475 pounds of acid phosphate, and 125 pounds of muriate of potash and mixes these ingredients together at home on his barn floor as thousands have done be- fore him. He will then have a complete fertilizer analyzing much the same as the average goods sold in Vermont and not essentially different chemically from many standard brands now in the market. The cost of the ton after mixing — if the farmer prefers to mix the ingredients himself — will be made up as follows : (o) Cost of material in the market. (b) Cost of transportation. (c) Cost of mixing. The first item (a) entering into the total cost is the only one included in the "valuation." If there is added to this one item not only the charges of transportation and mixing, but also the expenses of selling through agents and dealers, long credits, bad debts, etc., we have the factors involved in the cost of our ordinary complete fertilizers when delivered. It is clear, there- fore, that the selling price must of necessity exceed the "valua- tion," the excess representing the manufacturer's charges for converting raw materials into finished products, for freighting and for selling them. Since the cost of mixing and selling vary somewhat with differ- ent companies, and since freight rates to the different sections of the state are quite unlike, it is unsafe to assign any arbitrary sum to cover these charges. These can be estimated best by the consumer to fit his local conditions. Some Object to Valuations. — There are other arguments both for and against the use of valuations. The opponents of the system say : VAI30i-5 -^ 1.416 = 2.30% nitrogen. 80 X 50 = 4,000 -;- 1.436 = 2.79% potash. The analysis with and without the filler is : — With 564 lbs. filler Without filler 2.000 lbs. 1,436 lbs. Per cent. Per cent. 8 1.65 2 11. 14 2.30 2.79 Potash From this it is readily seen that 1,436 pounds of the higher grade fertilizer is better than 2,000 pounds of the lower grade. The purchaser would do well to buy the above fertilizer without the filler for he would receive more for his money. But the purchaser must have 8-2-2 fertilizer and so the manufacturer, to oblige him, must add some 564 pounds of worthless material to make the ton. The fertilizer is shipped and the purchaser has 294 SOIL FERTILITY AND FERTILIZERS got more bulk in the 2,000 pounds than in 1,436 pounds. But he pays freight and has the trouble of handling 564 pounds of use- less filler. Or he pays freight on 10 (200 pound) sacks when a little over 7 of such weight packages would contain the same amount of plant food. It would indeed be a better proposition, should the fertilizer be too concentrated, to add soil to it when ready to use on the farm. Cheap Fertilizers Often Demanded. — It is the writer's belief, from conversations with many fertilizer manufacturers, that these gentlemen would much prefer selling only high grade fer- tilizers. These manufacturers argue that high grade fertili- zers are cheaper for the consumer to purchase and give better crop returns than low grade fertilizers; hence the use of high grade fertilizers would mean an increase in business as nobody is well pleased unless successful. Many farmers want the cheapest fertilizers they can get per ton price regardless of the plant food furnished, and many unscrupulous merchants desire the lowest price per ton fertilizers because they claim they can sell them for almost as much as high grade fertilizers bring; thus they make greater profits. The manufacturer rather than lose a customer, by showing the folly of such practice, ships the fertilizer with 100 to 1,000 pounds of worthless material as filler. Cost of the Different Grades of Fertilizers. — The Vermont Ex- periment Station discusses the values of the different grades of fertilizers as follows :'° I. From the Standpoint of Cost. — The brands of fertilizers analyzed for the season of 1909 may be classified as to selling price as follows : Low priced, selling at $28 or below Medium priced, selling from $28.50 to $32.50 High priced, selling for I33 or more- Number of brands 39 54 38' Percent, of total 41 29 Average sell- ing price $26.29 29-93 37.84 HIGH, MEDIUM AND LOW FERTILIZERS 295 The average, largest and smallest values of plant food offered in the groups of brands appear below. The figures show the values of plant food bought for a dollar in the average goods of each grade, including the greatest as well as the least value ob- tained in any brand in each class. Value of Plant Food Bought for a Dollar. Average Smallest Largest Low priced Medium priced- High priced Jo-53 0.58 0.65 fo.40 0.40 0.49 I0.70 0.74 0.74 a highly nitrogenous and relatively costly oats and top dressing and a high priced tobacco goods are omitted from the comparison. It is interesting to note the number of brands in each group which furnish less than 55 cents' worth of plant food^ for a dol- lar, as well as the number which afforded more than 65 cents' worth for the same sum : Low priced: Less than 55c. worth, 22; more than 65c. worth, i. Medium priced: Less than 55c. worth, 13; more than 65c. worth, 7. High priced: Less than 55c. worth, 2; more than 65c. worth, 20. The comparisons can be shown graphically. The relative length of the following lines show the average money value in plant food at retail seaboard prices bought for a dollar at Ver- mont delivery points in brands selling for $28 or less (low priced), from $28.50 to $32.50 (medium priced), and for $33 and above (high priced) : Low priced ■■^^^—^.^■^^^^^—^^i^^^ii,^^^ 53 cents for a dollar spent Medium priced ^^^,i__^^^^^__^^_^^^^,„___^_ 58 cents for a dollar spent High priced ,^^^___ 65 cents for a dollar spent The following lines show the proportion of the total number of brands in each group containing 55 cents or less worth of plant food for each dollar invested: 1 The phrase " 55 cents' worth of plant food " should be construed to mean an amount of plant food which, if bought for cash at retail at the seaboard, would have cost 55 cents in standard, unmixed, raw materials. 296 soil.. FERTILITY AND FERTILIZERS Low priced ,^^™^^^^.^™,«.^™^»«^.«.^«^..^i^i».5^^ Medium priced ^^,_i___^.^^24% High priced ■;% The final set of lines show the proportion of the total number of brands in each group containing 65 cents or more worth of plant food for each dollar invested of the purchase price : Low priced t '& Medium priced ^^„^^_I3% High priced ':2% If lines and figures are put into words, it will be seen that: 1. The same amounts of plant food which cost a dollar in the average low priced brands ($28 and below) might have been bought in the unmixed state at retail' and at the seaboard for 53 cents; in the average medium priced goods ($28.50 to $32.50) for 58 cents ; and in the average high priced goods ($33 and up- wards) for 65 cents. Extremes of values were 74 and 40 cents. In more than a quarter of the brands the sums charged for manufacture, transportation, sale, etc., comprised 45 per cent, or more of the retail cost, thus leaving only 55 per cent, or even less to pay for the plant food; while in an eighth of the entire number these charges exceeded the seaboard value of the un- mixed plant food. 2. In nearly three-fifths of the total number of low priced brands the charges for mixing, sale, etc., aggregate at least 45 per cent, of the selling price, while in only one in four of the number of medium priced brands and in but two out of thirty- eight of the h-gh cost goods were the charges thus large. 3. Half of the total number of high class goods contained an equivalent of 65 cents or more worth of plant food at retail seaboard prices. But one in eight of the medium and one in forty of the low grade goods contain so high an equivalent. These things are naturally so, inevitably so. There are good and sufficient reasons for this showing, which may be condensed in a nutshell as follows: It costs as much to mix, to store, to regrind, to bag, to ship, to freight, to sell, to collect for sales, etc., a ton carrying 1,200 pounds of genuine fertilizer and 800 HIGH, MEDIUM AND LOW FERTILIZERS 297 pounds of mere filler (diluent) as one that contains 2,000 pounds of undiluted fertilizer ingredients. Therefore the 'buyer of low grade goods must pay for all this useless handling of the nearly or quite worthless filler. It is an old story, reiterated year after year, but it is one which needs to be told as long as material usage of low grade brands obtains. 2. From the Standpoint of Value. — Let us now turn the matter about and study it from the standpoint of worth. The figures and proportions naturally differ from those just presented. The brands may be classified as to valuation as follows : Number of brands Low grade, valuing at f 15.50 or less Medium grade, valuing at $15.51 to J22 High grade, valuing at $22.01 and upwards . . 42 59 29' Per cent, of total 32 45 23 Average valuation l'3-52 18.22 26.30 1 Exclusive of three brands, a highly nitrogenous and relatively costly oats and top dressing, and a high priced tobacco goods, valuations of which are relatively very high, and a lawn dressing milled extra fine and sold on that account at an advance in price. The composition, selling price and valuation of the average brand of each group appears below : Low grade . . . . Medium grade- High grade 0.99 2.34 319 9 00 8-55 7-52 2.53 430 9.06 1 = ao _ 0. 12.5 15-2 19.8 $27.10 30.00 38-93 l'3-52 18.22 26.30 HO l'3-58 11.78 12.63 A survey of this table indicates that: 1. The proportion of nitrogen increases in regular gradua- tions from group to group ; that of phosphoric acid drops one- half per cent, from the lower to the medium and one and one-half per cent, in the high grade goods; while the potash increases nearly two per cent, in the medium and over six and one-half per cent, in the high grade brands, as compared with the lower ones. 2. The low grade goods carry nine times as much phosphoric 298 SOIL FERTILITY AND FERTILIZERS acid as they do of nitrogen and nearly four times as much phos- phoric acid as they do of potash. These proportions become, roughly, four and two in the medium grade. In the high grade fertilizers there are but two and one-third times as much phos- phoric acid as nitrogen, and one and one-half per cent, more potP^-. than phosphoric acid. The latter grade more closely restf'ibles the proportions commonly present in the crops ordina- rily grown than do either of the other grades. A study of the main tables and of the data in hand further shows that nine out of ten high grade goods and three out of four medium grade brands contained either nitrate or ammonia salts (water-soluble nitrogen). Only one brand in five or nine in the entire forty-two of the low grades contained this valuable form of plant food; and five of these nine contained each less than 5 pounds to a ton and but one more than 10 pounds peir ton. Moreover, the organic nitrogen availability of the low grade goods tended to run somewhat lower than that of the bet- ter classes. 3. The medium grade goods for one-ninth advance in price over the cost of the low grade brands offer an eighth more plant food and three-eighths more commercial value. 4. The high grade fertilizers for three-sevenths advance in price over the cost of the low class goods furnish four-sevenths more plant food and almost double the commercial value. 5. The higher the grade the less the margin between cost and worth, both actually and relatively. In buying the average low grade brand one paid this year $13.58 for service of one sort or another (factory and office charges, freight, selling expenses, etc.) incurred in the delivery of $13.52 worth of plant food; when medium grade goods were bought, $11.78 service charges placed $18.22 worth of plant food in the buyer's hands; and when high grade goods are bought $12.63 service charges placed $26.30 worth of plant food in the buyer's hands. Or, phrasing the matter another way. HIGH, MEDIUM AND LOW FERTILIZERS 299 The Cost of Placing A Doi,lar's Worth of Plant Food in the Farmer's Hands Was: In low grade goods one dollar In medium grade goods 65 cents In high grade goods 48 cents It may be worth while now to scan the prices paid for a ;iound of nitrogen, of available phosphoric acid and of potash the several grades. The next table shows this, including the aver- age, lowest and highest costs as well as the retail cash cost of these ingredients in Boston or New York, or, in other words, their "valuations." Cost of a Pound of Plant Food in Fertilizers of Various Grades. Nitrogen Available phosphoric acid Potash V < X 1 3 J Fibre 1.77 100.00 Per cent. {a) Contains water soluble phosphoric acid 5.78 (6) Contains reverted phosphoric acid 1.58 (a) and (6) contain available phosphoric acid 7.36 (c) Contains insoluble phosphoric acid 0.91 Total phosphoric acid 8.27 (d) Contains actual potash, 2.45 per cent. (e) Contains nitrogen, 2. 11 per cent. The protein, carbohydrates, fat and fiber were furnished by the cotton-seed meal. The analysis of this fertilizer would be reported as : Per cent. Available phosphoric acid 7.36 Insoluble phosphoric acid 0.91 Nitrogen 2. 11 Potash 2.45 This would make a total of 12.83 per cent, of plant food and for the remaining 87.17 per cent, consult the analysis as given. Mc. Candless also made a complete analysis of an acid phos- phate or superphosphate made from South Carolina rock: 306 soil fertility and fertilizeks Complete Analysis of an Acid Phosphate. Per cent. {a) Mono-calcic, or superphosphate of lime J 8. 13 {b) Di-calcic, or reverted phosphate of lime 5.75 (c) Tri-calcic, or bone phosphate of lime 3.80 Sulphate of lime, or gypsum, or land-plaster 46.05 Potash o. 12 Soda 0.38 Sodium chloride 0.03 Bi-sulphide of iron or pyrites 0.74 Magnesia o. 14 Peroxide of iron 1. 10 Alumina 1.22 Fluoride of lime 0.75 Sand or silicious insoluble matter 9.29 Water 12.50 100.00 Per cent. {a) Contains water soluble phosphoric acid 11.00 (b) Contains reverted phosphoric acid 3.00 (a) and {b) contain available phosphoric acid 14.00 (c) (Contains insoluble phosphoric acid i . 74 Total phosphoric acid = 15.74 The above analysis shows 15.74 per cent, of total phosphoric acid and the remaining 84.26 per cent, can be found in the analysis as given. Our previous study of the foregoing chapters has taught us that muriate of potash contains 50 to 60 per cent, of potash, sulphate of potash 50 per cent, of potash, ammonium sulphate 20.4 per cent, of nitrogen, nitrate of soda 15.5 per cent, of nitrogen, rock phosphates about 30 to 36 per cent, of phosphoric acid, and in all our study of these chapters we did not find one fertilizing material carrying 100 per cent, of any of the constit- uents. The plant food in fertilizer materials, that is, the nitro- gen, phosphoric acid and potash, is combined with other elements, and must necessarily be so to form compounds that may be used by man. Should nitrogen equal 100 per cent, it would be a gas HIGH, MEDIUM AND tOW FERTILIZERS 307 separated from all other gases and impossible to use as a ferti- lizer commodity. But when it is combined with soda and oxygen the compound nitrate of soda is formed which is readily trans- ported and used. What has been said about nitrogen also applies to the elements potassium and phosphorus; so it is evident that we cannot buy or make a fertilizer containing 100 per cent, of plant food. CHAPTER XV. HOME MIXTURES. Definitions. — When fertilizer materials such as tankage, dried blood, nitrate of soda, sulphate of ammonia, superphosphate, bone-meal, muriate of potash, etc., are purchased and mixed at home the process is called home mixing and the product a home mixture. When these fertilizer materials are mixed by the fac- tory the product is called a fertilizer or a mixed fertilizer. Most of the fertilizer materials contain either one or two constituents and only a few carry all three constituents. Most of the mixed fertilizers contain three constituents, namely, nitrogen, phos- phoric acid and potash and are called complete fertilizers be- cause they contain the three essential elements. There has been a great deal of discussion as to whether fertilizer materials or mixed fertilizers are the best for the consumer to purchase. Manufacturers' Claims. — The manufacturers claim that mixed fertilizers are the best for the farmer to purchase because : 1. The factory mixed fertilizers are in a fine mechanical con- dition. The mixed fertilizers are ground fine and uniformly mixed, which is indeed an important consideration to permit of an even distribution on the land. 2. The mixed fertilizers can generally be purchased in the locality at most any time and in any amount. 3. The mixed fertilizers are specially treated with acid and the constituents in substances like tankage, dry ground fish, etc., are made partially available. 4. The mixed fertilizers are claimed to be made up in such proportions as to satisfy the need of crops. 5. The manufacturers often allow the farmer some time to settle and often wait until harvest time before getting their money. The credit system is in vogue in the South where enor- mous quantities of mixed fertilizers are used. Reasons Why the Farmer Should Mix Fertilizer Materials at Home. — The mixing of fertilizer materials at home is becoming more popular among the farmers. Some of the reasons why the farmer should mix his own fertilizer materials follow : H0M13 MIXTURES 309 1. Plant food is obtained at a lower price. 2. The fanner knows the materials used. 3. Unnecessary constituents are not purchased. Mechanical Condition of Factory and Home Mixed Fertilizers. — The factory mixed fertilizers are usually much better mixed than those that are mixed at home. Fertilizer factories are well equipped with special machinery to insure producing a uniform product that may easily be distributed on the farm. However, the careful farmer may mix his fertilizer materials uniformly enough for all practical purposes. Mixed Fertilizers More Easily Purchased. — Mixed fertilizers can generally be purchased in the locality and the raw materials must be ordered away from home which of course takes some time. Sometimes certain raw materials are hard to obtain. If the farmer starts early enough, say in the winter, the raw ma- terials can generally be obtained. Mixed Fertilizers Compounded for the Needs of the Crop. — When a manufacturer makes up his formulas he has to allow for the general existing conditions of soil, climate, and needs of the crop, and he cannot expect to make a particular brand that will suit each farmer's requirements. When he makes up a potato brand he must make a mixture that will suit most of the farm- ers growing potatoes and he cannot expect to meet every condi- tion of soil. Manufacturers Often Allow Credit. — On the whole, the credit system is a poor system for the farmer, for when his crop is made he may or may not be ahead financially. Those that live on the credit system are usually a year behind and two or three poor crops result in the loss of the farm. The manufacturers, however, are often too lenient in selling their mixed fertilizers on the credit basis as they often have large losses which take away much of their profit. Plant Food is Obtained at a Lower Price in Home Mixtures. — The work of the Experiment Stations has proved conclusively that plant food is obtained at a lower price when the fertilizer materials are purchased and mixed at home than when mixed fertilizers are employed. Of course in using home mixtures, 3IO SOIL FERTILITY AND FERTILIZERS freight on fillers is saved. The following table shows the amount of plant food that was purchased for $30 in factory mixed fer- tilizers and home mixtures for the year 1906 in Connecticut.'^ Plant Food Bought for ^30. Nitrogenous superphosphates In the best In those of medium quality In the least valuable Special tnatiures In the best In those of medium quality In the least valuable Home mixtures In the average of all Nitrogen Phosphor- ic acid Potash Pounds Pounds Pounds 73 188 III 44 180 97 23 279 53 69 170 143 47 174 112 32 174 66 77 200 168 Total 372 321 355 382 333 272 445 The amounts of nitrogen, potash and total plant food in the home mixtures are higher than in any of the factory mixtures. The phosphoric acid is only exceeded in the least valuable of nitrogen superphosphates, but the total plant food is less in this grade by 90 pounds than in the home mixtures. This is indeed a fine showing for home mixtures, and as the figures in the table represent actual market conditions, the use of home mixtures should be thoroughly considered by every farmer who is in a position to use them. The following table covers the inspection of fertilizers for the year 1909 in Vermont.'" Selling Prices and Valuations of Factory Mixed Fertilizers. Nitrogen Total phosphoric acid Available phosphoric acid ■ Potash Selling price . Per cent, guaranteed 0.8 5-0 3-9 1 .0 it22 Valuation % 9-45||39-S6 j 5ofo8 8-5 16.0 I r .0 12.0 00 2.01 9-o8 7-53 4-36 3'-4^ 17.19 Per cent, found 0.98 6.88 3-65 1 .02 I.I0.04IJS43-3 8-95 16.60 12.18 13-19 2-23 IO-53 8.32 4.70 IJS18.84 >1 = w 0.22 1-45 0.79 0-34 lr.65 HO MB MIXTURES 311 Note the great differences between the selling prices, or cost to the consumer, and the valuations. The average selling price of fertilizers for the year 1909 in Vermont was $31.43 and the average valuation was $18.84. These great differences in selling prices and valuations are easily accounted for. The valuations, you well remember, are figured on the retail cost of fertilizer materials on the open market in the unmixed state. These valuations represent what a farmer should purchase his fertilizer materials for in centers like Bos- ton, New York, etc., and they do not represent the prices of these fertilizer materials when laid down at his place, as the freight and cost of handling are not considered. When factory mixed fertilizers are purchased the consumer must pay for the cost of assembling the raw materials, cost of mixing, insurance, long credit, bad debts, storage, freight, cost of inspection, cost of filler, cost of sacks, travelling men's expenses, dealers' profits, manu- facturers' profits and any other expenses that may be incurred in the manufacture and sale of the mixed fertilizer. When fertilizer materials are purchased that run high in any constituent the unit of plant food is usually obtained cheaper than when purchased in materials, or mixtures of materials, that run low. So when a fertilizer material like muriate of potash, which carries 50 per cent, of potash, is bought, the potash is se- cured at a lower price than when a mixture containing 2 to 5 per cent, of potash is selected. Home Mixing Acquaints the Farmer with the Materials Used. — When a farmer buys a factory mixed fertilizer he does not always know just the sources of the nitrogen, phosphoric acid and potash. He may desire his potash wholly as sulphate; he may want a part of his nitrogen as nitrate and a part in the organic form from dried blood. When he buys factory mixed fertilizers he has to take the word of the agent or the manu- facturer. Most manufacturers are honest men who give what is asked for but when you mix at home you know just the amount and kind of materials you are using. Again, when you mix your own fertilizer materials )'0U deal in the subject "plant food," that is, so much nitrogen, so much available phosphoric acid and so 312 SOIL FERTILITY AND FERTILIZERS much potash, and you do away with your old bad habit of pur- chasing fertilizer for a given amount per ton regardless of its plant food value. The table on page 313 gives a few home mixtures with the analyses, cost and valuations, that were used in Connecticut.'" It is readily observed that the cost per ton fairly approximates the valuations. In our previous table of factory mixtures the costs were much greater than the valuations. Note the variety of materials that were used in making up these mixtures. Note the high percentages of nitrogen and potash. These are to be sure high grade fertilizers that would probably cost $5 to $15 more if factory mixed. Home Mixing Does Away with the Purchase of Unnecessary Con- stituents. — Manufacturers make many brands of fertilizers but as previously said they cannot make and one brand that will suit the requirements of every individual farmer. For example, two farmers in the same locality wish to purchase a mixed fertilizer for their corn. One of these farmers may have applied farm manure or he may have plowed under a leguminous crop, while the other farmer has not supplied his soil with any organic matter and his soil may be poor and in need of humus. The fertilizer agent or merchant in this particular locality is selling a corn fer- tilizer guaranteed to contain nitrogen, phosphoric acid and potash in stipulated amounts. Is it reasonable to suppose that this one brand of corn fertilizer is the best fertilizer for both soils under the above conditions? The first farmer who has sup- plied farm manure or plowed under a leguminous crop would be wasting money in purchasing nitrogen, unless a little in the form of nitrate, which may help to give the crop a start. The other farmer would need a fertilizer containing both nitrogen as nitrate and nitrogen in some desirable organic form to help produce a crop. Again, a farmer may be growing cotton, corn, sugar- cane, etc., on a soil that is very rich in available potash. It would certainly be a waste of money for him to purchase a fer- tilizer containing potash. HOME MIXTURES 313 w a D H M w S o W Ik O 0) o < u ij > a z. < > < c ea UOl J3d UOIlEniBA P4 00 ID 10 T CO ON ON 00 NO ON PI \o uo; jad )soo 1 8 rt 00 CO (N 8 8 00 p* PJ 2 < HSB^OJ IT) ON 00 pi <» 00 ON ->* 00 00 10 pIOB ouoqdsoiid'iBiox 0^ ON 10 CI 00* CO ■4 10 CO d ppB ouoqd -soqd a[C|,nios-3}BJ)T0 0. ON d d p» CO pi 00 d piDB Duoqd -solid 3|qnios-3jBa;i3 q 10 10 1^ CTv NO 10 00 p) PI CO P» pi piDB Duoqd -soqd 3iqnids-J3iEAV 00 00 00 q ° CTs d PI d ua3oJiiu IB30X co ON ^ •"d- ON CO 10 oo_ pi 00 CO 00 DIIIB3JO *U330J?IN ON d ci pi PI pi sd;Bj)iu SB uaSoj^iM CO d 6 pj pj rn r^ ON CO 6 1 to Of s t? 1- s. •s s 3 S, CO s E U IJUIBX i; ^ 1 1 1 1 1 1 1 1 aiSBAV j3i3d:HBS 1 1 1 1 1 1 1 i 1 1 1 i|se)od JO 9iBt[dinb* aiqnoa 10 1 8 1 1 1 1 1 1 iIsB^od JO a^Bunw 10 ID 8 1 8 P4 a CO 8 a^Eqdsoqd ppv 1 8 1 8 10 1 i CO 8 3[3Biq-9UOq paAiossiQ 1 1 1 i 1 1 § ! 1 9uoq punojo 1 1 1 1 8 1 00 00 1 a3B3[UBX 10 1 1 ; 8 CO 8 ex3 1 8 qsy Aia 1 1 1 1 i 1 1 1 PN. SDBIUOd J 01s BO 1 1 1 1 ! 1 1 1 1 1 1 BpOSJOS^BJlIisr 8 10 8 8 8 p< 8 1 314 soil, FERTILITY AND FERTILIZERS When home mixing is practiced the farmer can purchase those fertilizer materials that supply the needed constituents and in the most desirable forms for the needs of his soil and crop. How to Purchase Fertilizer Materials. — The large consumer should certainly try home mixing and find out its advantages. The small farmer may find it impracticable to purchase other than factory mixed fertilizers. However, several small con- sumers may often advantageously club together and purchase fer- tilizer materials in mixed carload lots. Many manufacturers will gladly mix fertilizer materials for the farmer when the order is large enough. Of course the farmer must know just the amounts and kinds of materials he wishes when he orders in this way. To purchase fertilizer materials to mix at home, it is necessary to start early, say in the early winter, so that they may be mixed before the heavy spring work starts. Quotations should be se- cured from different parties in the nearest or nearby fertilizer markets. In most large cities bids can be secured. Be ready to pay cash because these raw materials are not usually sold on credit. Buy on the guarantee and if the constituents, nitrogen, phosphoric acid and potash fail to reach their guarantees de- mand a rebate. This can be easily arranged by making a contract with the manufacturer or broker. How to Mix Fertilizer Materials at Home. — The fertilizer ma- terials may be mixed in a wagon box, or better, on a tight barn floor, or a floor covered with canvas. Whenever chemicals as nitrate of soda, potash salts, etc., are used, they should be well broken up and rendered as fine as possible. In mixing, the light bulky materials as dried blood, cotton-seed meal, dry ground fish, etc., should be put on the bottom of the floor and on top of these spread the other materials. The materials should be spread evenly and then turned over and over and thoroughly mixed by shoveling. It takes considerable time to mix fertilizer materials so that the mixture is uniform. After the mixing is completed the fertilizers should be bagged and kept in dry storage until ready for use. If the mixture predominates in concentrated salts, some earth may be incorporated to insure a more even mixture. It should be HOME MIXTURES 315 remembered that the chief advantage of buying factory mixed fertilizers is that they are better mixed and the farmer cannot spend too much time in the process of thoroughly mixing his fer- tilizer materials. Rebates. — Every large consumer of fertilizers or those that purchase directly from the manufacturers or jobbers should enter into a contract in which it is stipulated that the material will be paid for according to its percentages of nitrogen, phosphoric acid and potash. The trade values of the different constituents will, of course, vary from time to time but the principle as il- lustrated here will remain the same. The writer has figured a great many rebates for the Louisiana planters, who buy directly from the manufacturers, or jobbers, who always demand a rebate when the fertilizer fails to reach the guarantee. The method given here has met with satisfac- tion among the planters and the manufacturers. Let us suppose that a farmer purchased 20 tons of fertilizer at $28 a ton, guaranteed to contain : — Per cent. Available phosphoric acid 10.00 Nitrogen 1.65 Potash 2.00 The chemist finds the analysis of this shipment to be: — Per cent. Available phosphoric acid 10.20 Nitrogen 1.32 Potash 2.31 From the ruling values for the season, potash is taken as 1.20, nitrogen as 3.35 and available phosphoric acid as i. These are the ruling trade values per unit of these ingredients in unmixed fertilizers, namely: Per unit Available phosphoric acid fi.oo Nitrogen 3.35 Potash 1.20 Then, if we multiply the percentages of available phosphoric acid, nitrogen and potash as guaranteed by their respective units we get the total units guaranteed. Example : 3l6 SOIL FERTILITY AND FERTILIZERS Available phosphoric acid lo.oo X i ^ lo.oo Nitrogen 1.65X3-35= 5-53 Potash 2.00 X I-20 = 2.40 Total units guaranteed 17-93 In a similar manner the total units as found by analysis are figured. Example : Available phosphoric acid 10.20 X i = 10.20 Nitrogen 1.32X3-35= 4.42 Potash 2.31X1.20= 2.77 Total units found by analysis 17.39 Then the units guaranteed are, to the units found, as the con- tract price paid per ton, is to the actual price that should be paid per ton. Or 17.93 : 17.39 = 28 : y 17.93 y = 17.39 X 28 17.93 y = 486.92 y = f27.i6, or the actual price that should be paid per ton. Now $28 (the contract price per ton) minus $27.16 (the actual price that should be paid per ton) equals $0.84, or the rebate per ton. There were twenty tons purchased; then, 20 X $0.84 = $16.80, the total rebate on twenty tons. The rebate on cotton-seed meal is arrived at in the following manner. Example: The meal is sold at $27.00 per ton and guaranteed to contain 6.59 per cent, of nitrogen. An examina- tion of this meal shows 6.30 per cent, of nitrogen. Then, 6.59 (the per cent, of nitrogen guaranteed) is to 6.30 (the per cent, of nitrogen found) as $27 (the contract price per ton) is to (the actual price that should be paid per ton). That is, 6.59 :6.30 = 27 : y 6.59 y = 170.10, y = $25.81 or the actual price that should be paid per ton. Then $27 (the contract price per ton) minus $25.81 (the actual price that should be paid per ton) equals $1.19, or the rebate per ton. These figures are not the same as those adopted by the Inter- State Cotton-Seed Crushers' Association for fixing rebates, as we figure on the actual nitrogen content as guaranteed and found. The phosphoric acid and potash contents are not considered in figuring the above rebate as the planters in purchasing cotton- seed meal for fertilizing purposes, contract only for the percent- HOME MIXTURES 317 age of nitrogen. The phosphoric acid and potash in cotton-seed meal are less variable than the nitrogen. If the purchaser is will- ing to accept the excess of potash and phosphoric acid at full value the price should be arranged accordingly. The rebate on acid phosphate is figured as follows: An acid phosphate guaranteed 14 per cent, available phosphoric acid analyzes 13.23 per cent, available phosphoric acid. Contract price per ton, $16.00. Then 14 (the per cent, of available phosphoric acid guaran- teed) is to 13.23 (the per cent, of available phosphoric acid found) as 16 (the contract price per ton) is to the actual price that should be paid per ton. Or, 14 : 13.23 = 16 : y 14 y = 13-23 ^ 16. 14 y = 211.68 y = $15.12, or the actual price that should be paid per ton. Then, $16.00 (the contract price per ton) minus $15.12 (the actual price that should be paid per ton) equals $0.88, the rebate per ton. The rebates on other fertilizers are obtained in the same way as explained in the above exam.ples, unless some other style of contract is agreed upon by the purchaser and the manufacturer or dealer or agent. How to Calculate Percentages from Known Amounts. — Suppose you want to find out the analysis of a mixture made up of the following : Mixture 600 pounds acid phosphate analyzing 14 % available phosphoric acid 150 pounds sulphate of ammonia analyzing 20 ^0 nitrogen 100 pounds sulphate of potash analyzing 50 % potash 850 pounds, total To find out the number of pounds of available phosphoric acid, nitrogen and potash in the above mixture, make the following multiplication. 6 X 14 = 84 pounds available phosphoric acid 1. 5 X 20 = 30 pounds nitrogen I X 50 ^ 50 pounds potash. To calculate the percentages of available phosphoric acid, ni- 3l8 SOIL FERTILITY AND FERTILIZERS trogen and potash, divide the amounts of the constituents by the total amount of the mixture. Available phosphoric acid, lbs., 84 -e- 850 = 9.88 % available phosphoric acid Nitrogen, lbs., 30 -5- 850 = 3.53 % nitrogen Potash, lbs., ,50 -7- 850 = 5.88 % potash If percentages are wished when one of the materials contains two constituents, the calculations may be made as follows : Mixture jj. .J, ,. (IS % available phosphoric acid 200 pounds dissolved bone analyzing < % c f/ nitrogen 100 pounds nitrate of soda analyzing 18.84 % ammonia 50 pounds carbonate of potash analyzing 64.00 fo potash 350 pounds, total The dissolved bone superphosphate furnishes two constituents, available phosphoric acid and nitrogen, so we must take these into consideration in our calculations. The nitrate of soda is given as carrying an equivalent of 18.84 per cent, of ammonia. The table of conversion factors prev- iously given, taught us that to convert ammonia into nitrogen we must multiply by the factor 0.823. 18.84 per cent, ammonia X 0.823 = 15.5 per cent, nitrogen. Then: 2 X I5-0 = 30-0 pounds available phosphoric acid 2 X 2.5^ 5.0 pounds nitrogen from dissolved bone superphosphate I X 15-5 = 15-5 pounds nitrogen from nitrate of soda 0.5 X 64.0 = 32.0 pounds potash. The percentages in this mixture would be: Available phosphoric acid, lbs., 30.0 -i- 350 = 8.57 fe avail, phosphoric acid Nitrogen, lbs., 20.5 -^ 350 = 5.85 % nitrogen Potash, lbs., 32 -^ 350 = 9.14 % pota.sh. How to Calculate Amounts from Known Percentages. — If 2,000 pounds of a mixture analyzing Available phosphoric acid 7 per cent. , Nitrogen 5 per cent. , and Potash 6 per cent. is desired from HOMU MIXTURES 3 19 Acid phosphate analyzing i5 per cent, available phosphoric acid, Calcium cyanamid analyzing 17 per cent, nitrogen, and Muriate of potash analyzing 50 per cent, potash. it may be calculated in the following way: First find out the number of pounds of available phosphoric acid, nitrogen and potash that would be required. Since 2,000 is 20 times 100 we may multiply the percentages by 20. 20 X 7 (% avail, phos. acid) = 140 lbs. avail, phos. acid req. for 2,000 lbs. 20 X 5 if" nitrogen) = 100 lbs. nitrogen req. for 2,000 lbs. 20 X 6 (% potash) = 120 lbs. potash req. for 2,000 lbs. To determine the number of pounds of acid phosphate, calcium cyanamid and muriate of potash needed to give the analysis de- sired, we may divide the pounds of available phosphoric acid, nitrogen and potash by the percentages that the materials analyzed. Avail, phos. acid lbs. 140 -5- 16% = 875 lbs. acid phosphate required Nitrogen lbs. 100 -^ 17% = 588 lbs. calcium cyanamid required Potash lbs. 120 -r- 50^ = 240 lbs. muriate of potash required Total 1,703 lbs. We have only 1,703 pounds and not 2,000 pounds the amount desired. To make 2,000 pounds an addition of 297 pounds of some make weight material as sand, earth, gypsum, etc., is nec- essary. Supposing we wished to substitute kainit, analyzing 12 per cent, of potash, for the muriate of potash in the above mixture. By calculating as explained above we find that it would require 1,000 pounds of kainit to analyze 6 per cent, of potash. This amount would make our total add up to 2,463 pounds, or 463 pounds more than we wish. This shows that kainit could not be used to supply all of the potash in a 2,000 pound mixture of the above analysis made from such materials. We could, however, supply one-third of the potash from kainit and two-thirds from muriate of potash. Potash lbs. from kainit 40-7- 12% = 333 lbs. kainit Potash lbs. from muriate 80 -=- 50% =: 160 lbs. muriate of potash Assembling the potash salts, acid phosphate and calcium cy- anamid we have: 320 soil. FERTILITY AND FERTILIZERS Founds Acid phosphate 875 Calcium cyanamid 588 Kainit 333 Muriate of potash 160 Total 1,956 By using kainit and muriate of potash in the above proportions only 44 pounds of filler would be necessary to add to make 2,000 pounds. Some Home Mixtures. — The following are a few mixtures that furnish practically equal amounts of nitrogen, phosphoric acid, and potash and show the possibilities of the varieties of fertilizer materials that may be used to satisfy the same percentages of the essential elements."^ Muriate of potash Acid phosphate Nitrate of soda Muriate of potash Acid phosphate Cottou-seed meal Cotton-seed hull ashes ■ ■ . Acid phosphate Cotton-seed meal Wood ashes (unleached) Acid phosphate Cotton-seed meal 30 334 125 20 281 286 45 261 286 164 261 286 Sulphate of potash Acid phos. & potash ( 2 Yo Kfi ) Cotton-seed meal Kainit Acid phosphate Nitrate of soda Stable manure Acid phosphate Nitrate of soda Stable manure Muriate of potash Acid phosphate Dried blood Pounds ID 3'2 286 58 300 70 2,000 266 13 4,000 30 334 167 How to Determine the Bequirements of the Soil. — There are people all over this country who seem to think a chemist can tell from analyzing a soil just the amount and kind of fertilizer that is needed for growing any crop or crops. The following explanation, from the Georgia Department of Agriculture, of the value of a soil analysis explains the chemists' position in this matter and also oflfers the farmer a way that he may determine the requirements of his soil. homb; mixtures 321 The Way for the Farmer to Analyze His Own Soil. — If any one element in a soil essential to plant growth be lacking in an avail- able form, then that soil can not produce a good crop, no matter how rich the soil may be in- the other essential elements. You naturally exclaim, then, why not have a chemist analyze the soil, and tell the farmer what element or elements are lacking in his soil and what are abundant, so that he will know how to fertiHze — whether he ought to apply acid phosphate, or kainit, or cotton- seed meal, or lime, one or all, to his land, so as to get the best results, and at the same time use the wisest economy in the pur- chase and application of fertilizers. Yes, this is a very natural idea, and it was at one time, in the earlier days of agricultural science, thought that by means of a chemical analysis of the soil, the key had been found by means of which we could unlock the secrets of Nature, and solve all the problems of practical agriculture. It was found, however, on trial, that this idea, so beautiful in theory, did not work well in practice. It was dis- covered, for instance, that a soil which was producing poor crops contained one-tenth of one per cent, of phosphoric acid, or, cal- culating to a depth of nine inches, about three thousand pounds of phosphoric acid per acre, and yet this soil was in need of phosphoric acid, because when acid phosphate was used on it as a manure it responded with largely increased yields. Evidently the phosphoric acid in this soil, although abundant in quantity, 3,000 pounds per acre, was not in a condition available to the plant, so that it could be absorbed by the roots. Elements Soluble in Acids not Always Available. — Still when the chemist came to treat this soil with his strong chemicals, he could dissolve the phosphates in it readily. Thus, it would hap- pen that a chemist analyzing a soil and finding in it, say, 3,000 pounds of pho.sphoric acid, 5,000 pounds of potash, and 4,000 pounds of nitrogen per acre, and knowing nothing else about the soil, except the results of his analysis, would report that the soil contained ample plant food for producing good crops, and was a good soil, not in need of fertilizers, when, as a matter of fact, the soil might be so poor as hardly to "sprout peas." After 322 SOIL FERTILITY AND FERTILIZERS many trials and efforts to imitate the action of Nature in the laboratory, the conclusion was reached that it was not possible to tell by a chemical analysis, in the case of cultivated soils, whether the soil was a fertile one or not, or what particular element should be added to it for the production of full crops. Analysis Shows the Ultimate Resources of the Soil. — Whilst the chemical analysis is a failure from this standpoint, still it is of value from another. For instance, if I make an analysis of your soil and tell you that it contains 3,000 pounds phosphoric acid, 2,500 pounds potash, and 4,000 pounds of nitrogen, then you would be encouraged to go ahead and make this plant food more avail- able by judicious cultivation and treatment, such as liming, the turning under of green crops, etc., feeling assured that in the end you could bring that soil up to a point where it would yield bountifully. But if as the result of my analysis I should tell you that the soil only contained 150 pounds of phosphoric acid and 200 pounds of potash per acre, why, then, you would know that the best thing you could do with that land would be to abandon it or give it away, and not waste further time and labor on it. There is, however, a practical method by which you can analyze your soil for yourself, far better than any chemist can do it for you, and by means of which you can tell for yourself whether your soil needs hme, phosphoric acid, potash or nitro- gen, one or all. That method is as follows: Method by Which the Fanner May Analyze His Own Soil. — First, select a piece of ground as level as possible, so that rain may not wash the fertilizer from one plot into an adjoming plot. Secondly, for the purpose of the experiment, mark off ten plots, each one just one-tenth of an acre in area. If con- venient make the plots long and narrow, say one hundred and thirty-six feet long by thirty-two feet wide; these dimensions would enable you to have eight long rows, four feet apart, in each plot. Any other shape of plot will answer, only be careful to lay off the plots so that they shall each contain one-tenth of an acre, or 4,356 square feet. Separate the plots from each other by paths, at least three feet wide, so that the effect of HOMS MIXTURES 323 fertilizer in one plot may not be felt in an adjoining plot. It would be well to locate these experimental plots on some of your poorest land, or that which stands most badly in need of fertili- zer. When all is ready carefully number the plots from one to ten so that you may keep a record of the nature and amount of fertilizer applied on each plot. Let us suppose that you decide to plant cotton on the ten prepared plots for the purpose of find- ing out what fertilizer, constituent is most needed by your soil when growing cotton. Plant the cotton in your usual manner, after a careful preparation of the soil of the plots, thoroughly ploughing and harrowing the plots in order. Then apply the fertilizer as follows : No. I. — No fertilizer. No. 2. — 143 pounds of cotton-seed meal. No. 3. — 200 pounds of 14 per cent, acid phosphate. No. 4. — 80 pounds of kainit. No. 5. — No fertilizer. No. 6. — 200 pounds of acid phosphate and 143 pounds of cot- ton-seed meal No. 7. — 143 pounds of cotton-seed meal and 80 pounds of kai- nit. No. 8. — 200 pounds of acid phosphate and 80 pounds of kainit. No. 9. — 200 pounds of acid phosphate, 80 pounds of kainit and 143 pounds of cotton-seed meal. No. 10. — 500 pounds of air-slaked lime. In many of our soils lime is sadly lacking, and it may be just the thing needed by the soil, in conjunction with certain other fertilizers ; to discover if this be the case, after having fertilized plot No. 2, mark off a strip 21^2 feet in width diagonally across the plot ; that is, running from one corner to the opposite corner. Apply to this strip 50 pounds of air-slaked lime, and work it in well with the soil and other fertilizer with a rake. Do the same with each of the other plots, omitting No. 10. Then when the crop begins to grow, if lime was specially needed by the soil in any of the plots, you ought to notice a marked superiority in 324 SOIL FERTILITY AND FERTILIZERS the 2i^ foot strip which runs diagonally across all the rows in all nine plots. In the above fertilizers it is presumed that the acid phosphate is the kind most usually sold, containing 14 per cent, of available phosphoric acid, so that 200 pounds supplies 28 pounds of actual phosphoric acid to the plot. The cotton-seed meal is presumed to contain 7 per cent, of nitrogen, so that 143 pounds of it supplies 10 pounds of nitrogen to the plot, and the kainit to contain i2i-4 per cent, of potash, so that 80 pounds yield 10 pounds of potash to the plots the kainit is applied to. In applying the fertilizers observe the following precautions : Sow each fertilizer on the plot to which it is to be applied broad- cast, using your best care and judgment to distribute the fertilizer evenly over the entire plot. In order to get an even distribution it is best to sow in such quantity that you will have to go over each plot at least twice to get all the fertilizer distributed. Take care not to sow while the wind is blowing, as it may blow some of the fertilizer on to the adjoining plots. After sowing harrow the ground, and then it will be ready for you to plant. Plant thick enough to insure a perfect stand, and at the proper time thin out to a uniform stand. Treat all the plots exactly alike, except as to the fertilizers applied. Prepare the ground in each plot the same, plant the cotton all at the same time, and always cultivate the same and at the same time each day. Take pains to have the same number of plants in each row. Keep a Record of the Results. — It will be well to keep a note- book, with a page for each plot, in which to record your ob- servations. In this book record: ist. The kind of fertilizer applied to each plot and the amount applied, on the pages set apart for the respective plots from i to 10. 2d. Note down the date the cotton was planted. 3d. Note the date the cotton came up in each plot. 4th. When the cotton is about two inches high on the plot containing no fertilizer, note the height and appearance of the other plots. 5th. After you have thinned out to a uni- HOMF, MIXTURES 325 form stand record the number of missing plants, if any, in each plot. Of course, use every endeavor to have the same num- ber of plants in each plot, but in case of accident to some, be sure to put down the number missing in any plot so as to make al- lowances. 6th. Record any other observations of interest dur- ing the growth of the crop on the different plots such as the com- parative dates of blooming, number bolls to the stalk, date of opening of the bolls, height of the stalks after maturity of the plant. 7th. Keep the seed cotton from each plot to itself, weigh it by itself, and record the weight of the seed cotton from plot number one on page number one, and so on with the others. When you have picked and weighed the last pound of cotton, then you will, I think, be easily able to decide for yourself what fertilizer or combination of fertilizers your land requires. Of course, if you have had a bad season, very dry or very wet. you will not be able to decide so well, and in that case repeat the ex- periment another year. In this way you can analyze your own soil, and do it better than the best chemist in the world can do it for you, because you have appealed to the soil itself, you have spoken to it in the language of Nature, and it has replied in the same mute, but eloquent tongue, demonstrating the truth of her answers before your very eyes."' CHAPTER XVI. A FEW REMARKS ABOUT FERTILIZERS. Brand and Trade Names. — There are too many farmers who purchase fertihzers on the brand or trade name and not on the plant food these fertilizers contain. The manufacturers are well acquainted with the importance of selling their fertilizers under attractive names. Some of the manufacturers even go so far as to have their brand names copyrighted to prevent their com- petitors from using them. Some of the older brand or trade names are well known by all the farmers in the locality where they have been sold from year to year and many of these farmers purchase Dixie Cotton Fertilizer, Great Western Wheat Fertiliz- er, Home Mixture, Standard Special Tobacco Manure, Cele- brated Potato Fertilizer, Royal Corn Special, etc., from year to year withotit ever knowing their plant food content. The name sounds good to these farmers, the fertilizer has a good strong odor, the right color, and with some farmers the proper taste. These are brand and ton farmers and not plant food farmers. These farmers will tell you that their fathers used these same fertilizers. To show that the name is no indication of the composition and suitableness of a fertilizer for a crop, the following data is sub- mitted. In the state of Massachusetts for the year 1909, out of 66 brands sold as potato fertilizers, 46 contained potato as the only crop name, and 20 were sold in conjunction with other crop names as potato, hop, and tobacco ; potato and root crop ; potato and tobacco; potato and vegetable; corn and potato; potatoes, roots and vegetables ; onion and vegetable. Twelve compinies put out 2 brands, 5 put out 3 brands, and 3 put out 4 brands. The nitrc^en guaranteed varied from 0.80 to 3.71 per cent., the available phosphoric acid from 4 to 9 per cent., and the potash from 2 to ID per cent. All of these potato fertilizers could not have been the best for the farmer to purchase. The manu- facturers evidently cater to the trade and some of them put out 2 to 4 brands so as to be able to sell one of them to the farmer. A FBW REMARKS ABOUT FERTILIZERS 327 the brand depending upon the price the farmer is willing to pay. Many of these fertilizers were high grade but the farmer should consult the plant food guarantee and not the name in selecting fertilizer. Those that were sold for corn and potato, tobacco and potato, vegetables, root crops and potatoes, etc., either do not meet the requirements of these crops, or else the purchaser is wasting money in buying excesses of plant food. Some manufacturers put out two or three different brands made from the same goods and guaranteed the same. Thus we will find Dixie Cotton Fertilizer and Corn King Guano on the market with the same guarantee, bagged from the same pile of goods, and sold for different crops. Sometimes two diffenent brand names are used for the same material to be sold for one crop. For example. Golden Imperial and Special Mixture may be sacked from the same material, carry the same guarantee, and be sold for one crop. The writer has seen two agents, one a merchant and the other a farmer, selling the same fertilizer under different names in the same village. The farmer, who was the least successful in disposing of his lot, thought and I guess, still thinks that the merchant had a better brand. These fertilizers of course sold for the same price and the merchant sold three times as much as the farmer, because he was a bit more popular and had a better stand. So you see the brand name helps to sell fertilizer. The farmer should buy on the plant food content and not by the name or per ton. The manufacturers also often sell superphosphates made from rock phosphates under the name of dissolved bone, and mix- tures of superphosphates (made from rock) and potash, as dis- solved bone and potash. We have learned that dissolved bone contains nitrogen and phosphoric acid and superphosphates made from rock only carry phosphoric acid. So when dissolved bone or a dissolved bone and potash are sold without any nitrogen guaranteed you can rest assured that the material was made from rock. However, the soluble phosphoric acid from rock super- phosphates is just as valuable as that from dissolved bone, and 328 soil, FERTII,ITY AND FERTILIZERS the reverted is perhaps ahnost equally valuable from these two phosphates. There are a large number of brands sold in the different states. Georgia uses more fertilizer than any other state and the number of brands inspected, analyzed and placed upon the market in that state since 1874-1875 follow:*'* For the season of 1874-5 no brands For the season of 1875-6 loi brands For the season of 1876-7 125 brands For the season of 1877-8 127 brands For the season of 1878-9 162 brands For the season of 1879-80 182 brands For the season of 1880-1 226 brands For the season of 1881-2 270 brands For the season of 1882-3 354 brands For the season of 1883-4 336 brands For the season of 1884-5 369 brands For the season of 1885-6 345 brands For the season of 1886-7 322 brands For the season of 1887-8 337 brands For the season of 1888-9 355 brands For the season of 1889-90 440 brands For the season of 1890-1 492 brands* For the season of 1891-2 608 brands* For the season of 1892-3 598 brands* For the season of 1893-4 736 brands* For the season of 1894-5 874 brands* For the season of 1895-6 1,062 brands* For the season of 1896-7 1,178 brands* For the season of 1897-8 ... 1 ,300 brands* For the season of 1898-9 779 brands For the season of 1899-1900 699 brands For the season of 1900-1 640 brands For the season of 1901-2 735 brands For the season of 1902-3 895 brands For the season of 1903-4 i ,241 brands For the season of 1904-5 i ,352 brands For the season of 1905-6 1,917 brands For the season of 1906-7 i ,840 brands For the season of 1907-8 i ,822 brands For the season of 1908-9 2,274 brands The number of brands marked with a star are incorrect and A FEW REMARKS ABOUT FERTILIZERS 329 misleading, as in the season of 1897-8, 843 brands were inspected, analyzed and admitted to sale, and not 1,300. How to purchase a Fertilizer. — Sometime before you intend to purchase your fertilizer write to your Experiment Station or State Board of Agriculture for bulletins on the crops you intend to raise and also for a fertilizer bulletin. These bulletins may be had free of charge. Study these bulletins. In the bulletins on crops you will no doubt learn the plant food requirements, that is, the amounts and kinds of plant food most suitable for the crops you are interested in. The fertilizer bulletin will no doubt acquaint you with some timely suggestions on how to purchase fertilizers and will also give you the names, guarantees, analyses, and valuations of the fertilizers sold in your state. You can in all probability select a fertilizer that will meet your requirements. If any element as nitrogen, phosphoric acid, and potash is not needed, do not waste your money by purchasing a complete fertilizer but select one that contains the constituents you need and in the form or forms you desire. You are now ready to talk business with your merchant or dealer. Find out from him if he has the particular fertilizer you wish. Perhaps he has not it in stock and he will no doubt tell you he has some- thing just as good. If the amount and kind of plant food that you wish is present in the brand that he has, why it is just as good and if not it is'nt what you want. No doubt the factory for which he is agent puts out a fertilizer of the composition you desire ; you can find this out by referring to your fertilizer bulletin. If so, you may be able to get your merchant to order it for you. If his factory hasn't got it buy from one that has. Y'ou have your fertilizer bulletin and you can easily write for your fertilizer and perhaps save the agent's profit. Study the Guarantee. — You have learned that many of the fer- tilizer materials as cotton-seed meal, tankage, bone-meal, dry ground fish, etc., do not always contain the same amounts of fertilizer constituents and are quite variable in composition. Therefore do not buy any of these products just because rhey are so named. Consult the guarantee and find out how much 330 SOIt FERTILITY AND FERTILIZERS plant food is offered for a certain price. The following com- parative valuation shows the necessity of purchasing cotton-seed meal on its nitrogen content. When cotton-seed meal carrying 6.58 per cent, of nitrogen, which is equivalent to 8 per cent, of ammonia, is worth $30 a ton, the other grades assume the following values, when the nitrogen content alone is considered: Choice 6.58 per cent, nitrogen or 8 per cent, ammonia $30 per ton. Prime 6.17 per cent, nitrogen or 7.5 per cent, ammonia $28.13 per ton. Good 5.76 per cent, nitrogen or 7 per cent, ammonia $26.25 per ton. This illustration of the differences in value of cotton-seed meal holds for tankage, bone meals, dry ground fish, linseed meal, castor pomace, wood ashes and similar fertilizer materi- als. Nitrate of soda, sulphate of ammonia, the Stassfurt potash salts, etc., are usually standard products which do not show much variation ; but even in the purchase of these high class materials one should know just the amount of plant food he is buying. Usually the higher the percentages of constituents in a fertilizer material, the cheaper is the plant food. Fertilizers Should Eeach Their Guarantees. — The manufactur- ers, as a whole, are endeavoring to do an honest business. In making their mixtures they aim to give a little more plant food than they guarantee, so that the fertilizer will meet the guarantee under reasonable conditions. The bulletins of the different states setting forth the results of fertilizer inspection, show that the majority of the factory mixed fertilizers exceed the guarantee. But sometimes fertilizers fail to reach the guarantee in all constituents. Factory mixed fertilizers often fall below the guarantee in one element but exceed the guarantee in other elements so that the relative value is above the guaranteed value. Of course the manufacturer should furnish the consumer with fertilizer that reaches its guarantee in all elements as the pur- chaser has a right to expect this. Such variation is often due to A FEW REMARKS ABOUT FERTILIZERS 33 1 poor mechanical mixture as the manufacturer usually puts in enough of the raw materials to exceed the guarantee in all con- stituents. When a shipment of fertilizer fails to meet its guar- antee in one or more elements, and runs above the guarantee in one or more elements, the purchaser should give the manufacturer some consideration and settle on an equitable basis and allow the manufacturer for whatever excess that may be present in any of the elements, within reasonable limits. If the purchaser con- tracts for a certain amount or amounts of constituents and they fall materially below the guarantee a rebate should be demanded. Fertilizer Recipes or Patent Formulas. — In Texas, Louisiana, Mississippi and Kentucky, and in all probability in other states, certain parties have been selling recipes or formulas to the farmers. The following is a copy of one of these recipes.'^ Farm Right. $5.00. Wallis Complete Guide for Compounding Fertilizers. — Take Salt- peter, 2 pounds; Bluestone, 2 pounds; Soda Ash, 4 pounds; Nitrate Ammonia, 2 pounds; Potash, 4 pounds. Dissolve the whole in six gallons of water; put 100 pounds of stable manure in a pen and sprinkle it wfith a portion of the solution. Then take 50 pounds of unslacked ashes, 5 pounds of salt and 5 pounds of lime ; sprinkle these on the manure, continuing the pro- cess until the ton is completed, and let it remain in a dry place for 30 days. Use from 200 to 400 pounds per acre and bed it on the other' fertihzers. We prefer the form thus presented, but it may be variously modified without departing from the principle of our invention, so long as the same steps are taken in the manner of preparing. For example : When prepared for corn the hme and ashes may be omitted and fifty pounds more of the salt and two pounds more of the soda ash added to the ton. Second: If a lower grade of fertilizer is desired, use less of the ingredients: if a higher grade is wanted, use more. Third: Cotton-seed makes a most desirable base for the fertilizer. Note — For lime lands add salt instead of lime. Any rich soil or muck will answer instead of stable manure. When earth 332 SOIL FERTILITY AND FERTILIZERS is used always use lime and ashes. To use as Guano, put in sand instead of stable manure, and add fifty pounds more of lime to the ton, add six pounds more of ammonia and fifty pounds more of salt. For land that is infested with bugs and worms that destroy the young plants, put in ten pounds more of bluestone to the ton. Use 200 to 400 pounds to the acre and bed on it as other fertilizers. The compound destroys all bugs and in- sects. Any person using this formula without authority will be liable to a fine and imprisonment under the United States laws, and any person using same without authority will be prosecuted to the full extent of the law. Entered in the Patent Office, June 11, 1892. Serial No. 436,386. Wallis & Roach. The above recipe is practically worthless and anybody who pays $5.00 for such a fraud gives away his hard-earned money. The bluestone and soda ash have no fertilizing value and the amount of fertilizing material present in saltpetre, nitrate of ammonia and potash can be purchased on our market for 50 cents, or less. The stable manure and the cotton-seed meal men- tioned in the above circular are of course good fertilizers, but the addition of lime and potash to these materials would act upon the nitrogen present and drive it off as ammonia. The potash present in the above mixture would drive off the nitrogen in the nitrate of ammonia. Prof. Newell, Texas State Entomologist, says: "Bluestone in the amount mentioned in this recipe would render conditions more favorable for the ordinary insects which are injurious to farm crops." Some of the formulas call for the use of Paris green to de- stroy the insects. Copper sulphate and Paris green are very liable to injure the bacteria present in farm manure and in the soil, and thus the young plants would be deprived of nourish- ment, to a certain extent, when such insecticides and fungicides are used. Any farmer following the unscientific directions as laid down in this circular is bound to be disappointed with the results ob- A FEW REMARKS ABOUT FERTIWZERS 333 tained. The Experiment Stations and State Boards of Agricul- ture are always glad to help anybody in fertilizer problems, free of charge, and it is an injustice to the honest fertilizer manu- facturers to waste time and money with fertilizer recipes and patent formulas. Fertilizers do not Deteriorate Much on Standing. — The mixed fertilizers and the raw materials do not change much when kept in dry storage. The mixed fertilizers are usually compounded from materials that do not attack and set free the nitrogen present. The soluble phosphoric acid may revert and change to insoluble phosphoric but not to any appreciable extent. There- fore should a farmer have some fertilizer left over from a past season he may rest assured that it is still valuable provided it has been kept in a dry place. If fertilizer gets wet from rain 01' becomes very moist from any cause, there may be consider- able losses of plant food. The following table shows the effect on the soluble and in- soluble phosphoric acid of fertilizers from 9 manufacturers, when kept in dry storage for the period mentioned.^" Phosphoric Acid of Fertilizers in 1905 & 1907. Lab- oratory No." 66 77 51 45 17 n6 79 73 62 50 37 33 Water-soluble phosphoric acid Insoluble phos- phoric acid Capital bone and potash compound. ■ . Vegetable Special Blood, bone and potash Caddo cotton Meridian home mixture Texas pride soluble guano African cotton grower Primo H. G. raw bone spuerphosphate. Scott's gossipium phospho special Vegetable grower Dissolved bone and potash Acid phosphate Average Maximum difference. Minimum difference. 1.47 6.40 6.60 5-90 8.20 6.07 7.07 7-47 6.27 5-65 8.15 "•54 6.73 1.38 0-37 1907 1905 1.09 6.35 6.05 5-94 7.22 6.45 6.81 7. II 6.22 5-69 6.87 10.16 6.33 2.25 0.32 1.27 0.52 1.24 0.28 0-33 0.17 1.44 1.02 0.52 1.87 0.94 1907 2.56 0.99 1.22 0.52 0.99 0-37 0.82 0.50 I-5I 0-75 0.61 1-34 1.02 +.67 —•53 Samples represent nine manufacturer.s, mostly mixed goods. 334 SOIt FERTILITY AND FERTILIZEKS Incompatibles in Fertilizer Mixtures. — It should be understood that fertihzer materials cannot be mixed indiscriminately. Cer- tain fertilizer materials, when mixed, set up reactions which cause losses of plant food or change the plant food to a form or forms which are less available. When lime, or basic slag, or lime nitrate, are mixed with farm manure, guano, sulphate of ammonia, etc., or mixtures containing any of these materials, the nitrogen is set free and escapes. When lime is mixed with acid phosphate or superphosphate, the soluble phosphoric acid is changed to reverted phosphoric acid. Below are a few analyses of factory mixed fertilizers to which lime has been added. Analyses of Fertilizers with Lime Added. Soluble phos- phoric acid Reverted phos- phoric acid Insoluble phos- phoric acid Total phos- phoric acid Available phos. acid Potash 1-57 1.36 0.63 4.12 8.57 8.49 8.87 6.40 1.27 1-39 0.95 0.84 II. 41 11.24 10.45 11.36 10.14 9-85 9-50 10.52 4.20 3.28 2.45 3-82 These fertilizers were distributed at the rate of 75 to 100 pounds per acre. To distribute such a small quantity per acre, requires a small outlet on the fertilizer distributor which would clog when ordinary fertilizers are used, so that the manufacturers in order to sell to this trade are forced to add lime to keep these special fertilizers dry and in a fine mechanical condition. Note the high percentages of reverted . phosphoric acid and the cor- respondingly low percentages of soluble phosphoric acid in these fertilizers. Hall says : "Superphosphates cannot long remain mixed with nitrate of soda without setting free a certain amount of nitric acid, which is both wasteful and injurious to anyone handling the mixture. It is, however, safe enough to make up the mixture and sow it straight away; the nitric acid only begins to be in evidence when the mixture is left in a heap or in bags over night, or when it is sown from a machine which has some moving A FEW REMARKS ABOUT FERTILIZERS 335 part working in the fertilizer. Most mixtures containing super- phosphate will turn into a paste round machine parts working in this material. Kainit and superphosphate will also begin to set free hydrochloric acid if they are left long together."" Mixtures of certain materials tend to form products that cake or become hard, thus making them difficult to distribute evenly. A mixture of basic slag with any of the Stassfurt potash salts forms a hard cake. The following diagram may be of interest.''' Lime. Superphosphate. Thomas slag Barnyard manure Ammonium sulphate. f ^fi>f^T \f\ j^,-/*^^ j/^ /^ W ^^b ™* guaho. Potash salts Lime nitrogen (cal- r i ^^-J . '; , \,/ = |\v;i i \3 l>* Norwegian nitrate cium cyanamid). ^^^^r^-t-^^J\[ //V/^J /iL^^S^C^^W (basic calcium nitrate). Nitrate of soda. \J''^ • ^ Bone meal. Fig. 23. The heavy lines unite materials which should never be mixed. The double lines those which should be applied immediately after mixing. The single lines those which may be mixed at any time. In regard to nitrate of soda and superphosphate read what Hall says in the foregoing. The Time to Apply Fertilizer. — Nitrate of soda, sulphate of ammonia, and calcium nitrate are soluble in water and are not fixed in the soil. They should be applied in small quantities and at the proper time, or when nitrogen is needed, to give the best results. When large applications of these materials are made, some of the nitrogen may be lost by leaching. These fertilizer materials should never be worked into the soil too deeply as they 336 soil. FERTILITY AND FERTILIZERS may be lost by leaching before the plant can appropriate them. The organic materials furnishing nitrogen all have to be oxidized and converted into nitrates before they may readily be acquired as plant food. These materials may be applied early enough so that they may be acted upon by the soil organisms and par- tially decomposed to furnish food for the young plant. The very slowly available organic substances will of course be de- composed more slowly than dried blood, cotton-seed meal, tank- age, steamed horn and hoof meal, castor pomace and similar substances. One of the functions of nitrogen is to produce growth. It would be wasteful to apply any nitrogenous sub- stance to hasten maturity. It seems almost unnecessary to make this statement but some farmers use nitrate of soda late in the season to help fill out ears of corn after the crop has been made. If nitrate of soda is added in the middle of the growing period before the ears are formed it will help to produce more vigorous growth. Generally speaking, the nitrogenous fertilizers may be applied in the spring at planting time and during the growing period when needed. Phosphoric acid is readily fixed in the soil. When soluble phosphoric acid is added from superphosphates, it becomes well distributed in the soil, because of its fine mechanical condition, and changes to insoluble forms which are not apt to be lost by leaching. Superphosphates are very beneficial to young crops and tend to produce strong plants that can better resist the attacks of fungi and insects. Superphosphates may be applied before or during planting time. Raw bone-meal and ground rock phosphate may be applied at most any time because they are slow- ly available; but other fertilizers carrying phosphoric acid in the available form should be applied just before, or at planting time. Potash is very quickly fixed in the soil by the double silicates, so that it is difficult to distribute it evenly. Potash may be ap- plied sometime before planting so that the plowing and harrow- ing may help to mix it with the soil and insure a uniform dis- tribution. In mixed fertilizers we have found that any combination of A FEW REMARKS ABOUT FERTILIZERS 337 fertilizer materials may enter into their composition. There may be nitrate of soda, organic materials, superphosphates, and potash salts present in these fertilizers and so in the application of them we must consider the properties of all the fertilizer ma- terials. It is generally best to apply these fertilizers in the spring. Sometimes an additional application during the grow- ing period will help to force the crop. When much fertilizer is to be applied, especially on sandy soils, part of it may be ap- plied in the spring and part later on when the crop may be back- ward or need forcing. Crops like wheat which are sown in the fall need fertilizer at that time and also a light dressing of some nitrogenous fertili- zer in the spring to help it recover from the winter. Some of the market garden crops require fertilizer at planting time and al short intervals during the growing period. How Fertilizers are Applied. — Fertilizers are usually applied broadcast, partly broadcast and partly in the drill or hill, and in the drill or hill. When heavy applications are applied, broad- casting is perhaps the best method. The fertilizer may be ap- plied after the last plowing and harrowed into the top part of the surface soil with a wheel harrow or some kind of a cultivator. In this way the fertilizer will become well mixed with the soil. If a broadcast distributor is not used, one-half of the fertilizer may be applied by walking north and south and the other half by walking east and west. In this way the fertilizer should be uniformly applied. When home mixtures containing farm manure or fertilizers mixed with manure are used, the manure spreader may be employed to distribute the fertilizer. Some farmers apply fertilizer partly by broadcasting and partly in the drill or hill. This is an excellent practice for some crops and on some soils. That which is applied in the drill or hill furnishes plant food during the first growth before the roots are developed and that which is sown broadcast helps the later growth when the roots spread out. In this system of applying fertilizers it is perhaps better to apply most of the fer- tilizer broadcast. When farm manure is used it may all be spread broadcast and the fertilizer used to supplement it, which 338 SOIL FERTILITY AND FERTILIZERS is no doubt quick acting, put in the drill or hill. Potatoes, corn and market garden crops are often fertilized in this way. With small grain, roots and other crops with small root sys- tems, fertilizers are often apphed wholly in the drill or hill. Great care should be taken in applying fertilizer in this way to keep the fertilizer away from the seed. Most fertilizers contain some nitrate of soda, potash salts, or other materials that will injure the seed if they come in contact with it. Therefore a little earth should separate the seed from the fertilizer. The fertilizer dis- tributors usually cover the fertilizer sufficiently to protect the seed. When fertilizer is applied in the hills it should be spread over the place where the hill is to be and not applied all in one place. Earth should be spread over it as in drill application. When fertilizer is to be applied during the growing season it may be distributed on both sides of the plants to the center of the row and worked in with a cultivator. On many hoed crops this method is used; it is also advisable on light soils that are subject to leaching. On these soils sufficient fertilizer may be applied at planting time to give the crop a start and the remainder during those periods in the growing season when the crop needs nourishment or wishes to be forced for an early market. When fertilizers are applied to trees and bushes they should be distributed in a circle around the tree; the radius of which is equal to the height of the tree or bush. They should be worked into the soil by shallow cultivation. The feeding roots of many trees are near the surface and extend to quite a distance from the base of the tree so that by applying the fertilizer for some distance from the tree, the roots are better able to assimilate it and the soil organisms which render it available can act upon it more readily. Is it Profitable to Use Fertilizers ? — Every farmer should be able to decide this question for himself. The nature of the crop and the condition and fertility of the soil will determine whether fertilizers should be used. If intensive farming is practiced and large crops are grown on small areas fertilizers are generally re- quired. Market garden and truck crops generally more than pay for the liberal use of fertilizer. When market garden and A FEW REMARKS ABOUT FERTILIZERS 339 truck crops are grown on high priced land large applications of fertilizer are necessary to produce maximum crops to insure profitable returns on the investment. In some sections potatoes, onions, tobacco, oranges, and other crops receiving large amounts of fertilizer give profitable returns. If the soil is kept in good physical condition the use of ferti- lizers is more profitable than on soils not properly cared for. On poor soils the use of fertilizers is necessary for crop produc- tion, for without them a profitable crop cannot be produced. On farms where a systematic rotation is practiced, and farm ma- nures and green manures are employed, the use of fertilizer to supplement the deficiencies of the soil is usually very profitable, while on farms where one crop farming is continued, the response to fertilizers is not so satisfactory. The farmer can keep his soil in good condition and profit by the use of fertilizers. Fer- tilizers should not always be blamed for unprofitable returns as the trouble generally rests with the farmer who is careless in his methods. Farmers should spend a great deal of time tilling the soil and not expect the fertilizer to do all the work. Sometimes fertiUzers do not prove profitable because the soil is acid or too alkaline. If these conditions are corrected the use of fertilizers is often profitable. It should be remembered that some fertilizers like raw bone- meal, ground rock, phosphate, etc., do not give up all of their plant food during the first season but may help the crops for two or three years and prove profitable in this way. Amount of Fertilizer to Use. — Enough fertilizer should be used to produce profitable crops. This amount depends upon a great many factors, as the system of farming, the nature of the soil, the crop to be raised, and its value, the fertility of the soil, the value of the land, etc. Frequent light applications are usually more profitable than occasional heavy applications. Market gard- en and truck crops require more fertilizer than the staple crops. From 500 to 2,500 pounds of fertilizer are used for market gard- en, truck, and special crops, and 30D to 700 pounds for the staple crops, unless previous experience has shown that more or less than these amounts are necessary and profitable. 23 CHAPTER XVII. FERTILIZEB, FORMULAS FOB, CROPS. It may be said that it is almost impossible to state just the amounts of nitrogen, phosphoric acid and potash to apply to crops. There are so many factors which enter into the needs of crops that one can only generalize. The formulas which follow were taken from various sources and may be used as guides and not accepted as absolutely correct for all conditions. Voorhees' Fertilizers; Sempers' Manures; Snyder's Soils and Fertilizers; Card's Bush Fruits; Maynard's Successful Fruit Culture; Florida Department of Agriculture Bulletins; Georgia Department of Agriculture Bulletins; United States Department of Agriculture Farmers' Bulletins ; and var- ious Experiment Station Bulletins were used in collecting the formulas used in the following pages. I. Staple and Special Crops. Small Grains. — The crops that are included in this group are shallow feeders and do not utilize all the fertilizer that is neces- sary to apply for good substantial yields. When wheat, oats, rye, barley, or buckwheat follow some other crop as corn, an applica- tion of quickly available nitrogen and phosphoric acid is essen- tial. Potash will also be required on light soils or following crops that use up this constituent. Top dressings of nitrate of soda in the spring help these crops to get a good start after se- vere winters, but nitrogen should not be added when the crop is nearing maturity as the weight of straw should be lessened to insure a good yield of grain. Wheat is a weaker feeding crop than barley and is a harder crop to grow as it requires the soil to be in better condition. Wheat does well when it follows oats which in turn follows heavy clover sod. It may follow corn which has been well fertilized with farm manure. Barley has a stronger root system than wheat and can thrive on soils that are not in such fertile condition as good wheat FERTILIZER FORMULAS FOR CROPS 34I soils. Because of its different feeding habits it may often follow wheat to good advantage. It does well on open light soils. Oats is an easier crop to grow than wheat or barley and is more capable of gathering food than either of these crops. Oats will grow on most any type of soil that is in good physical con- dition. Rye is somewhat similar to barley and is better able to acquire plant food than wheat. It is also easier to grow. Formulas for Wheat. {Nitrate of soda, or 1 Sulphate of ammonia I Dried blood I 300-600 r D. B. black, or )■ lbs. per Avail, phos. acid 6 to 8 per cent, from < Basic slag, or I acre. ( Acid phosphate I Potash 3 to 4 per cent, from Muriate of potash. J Acid phosphate, 300 lbs ■» Sulphate of ammonia, 130 lbs V per acre. Muriate of potash, 90 lbs J This last formula is to supplement farm manure and should be applied in the fall. In the spring a top dressing of 90 pounds of nitrate of soda should be distributed. The following formulas for wheat should receive 75 to lOO pounds of nitrate of soda in the spring in those formulas where nitrate of soda is not included. Applications of 500 pounds to the acre are recommended. Muriate of potash 30 lbs. Muriate of potash 20 lbs. Acid phosphate 167 lbs. Acid phosphate 140 lbs. Nitrate of soda 125 lbs. Cotton-seed meal 286 lbs. Cotton hull ashes (20 per cent. K.fi) 45 lbs. Unleached wood ashes 164 lbs. Acid phosphate 130 lbs. Acid phosphate 130 lbs. Cotton-seed meal 286 lbs. Cotton-seed meal 286 lbs. Kainit 64 lbs. Acid phosphate 133 lbs. Acid phosphate 137 lbs. Nitrate of soda 13 lbs. Cotton-seed meal 143 lbs. Stable manure 2 tons. Cotton-seed i^'/i bush. Muriate of potash 30 lbs. Muriate of potash 15 lbs. Acid phosphate (with 2 per Acid phosphate 167 lbs. cent, potash) 120 lbs. Dried blood 167 lbs. Cotton-seed meal 286 lbs. 342 SOII< FERTILITY AND FERTIIvIZEES Kainit 58 lbs. Muriate of potash 20 lbs. Acid phosphate 150 lbs. Acid phosphate 150 lbs. Nitrate of soda 70 lbs. Nitrate of soda 64 lbs. Stable manure i ton. Cotton-seed i^'A bush. Commercial Fertilizer to analyze as follows : Kainit 45 lbs. Avail, phos. acid. 4>^ to 5 per cent. Acid phosphate 132 lbs. Ammonia 4.85 per cent. Cotton-seed 267^ bush. Potash 3 per cent. Formula for Barley — 250 to 600 Pounds Per Acre. XT ,. , /- 1 r I Nitrate of soda or Nitrogen 5-6 per cent, fro n < c,i.. r ° '' ^ \ Sulphate of ammonia Available phosphoric acid 7-8 per cent, from ( „^^^,^,t p'hosph^'i'''' ' Potash 3-5 per cent, from { ^^.f, -^fpoTash Formula for Rye— 300 to 600 Pound.'? Per Acre. Nitrogen 4-5 per cent, from Nitrate of soda f Acid phosphate, or Available phosphoric acid 5-7 per cent, from ^ Basic slag, or [ Dissolved bone-black Tj„+„,v, c ,^ r.„ „„„f f,«~ I Wood ashes, or Potash a-io per cent, irom •, ,. . ^ , ' . , *^ I. Muriate of potash Formula for Oats — 300 to 600 Pounds Per Acre. Nitrogen 4-5 per cent, from { ^^^ -f °"' Available phosphoric acid 5-6 per cent, from | Basfc^k"*^^*'^' °'^ Potash 8-10 per cent, from \ Wood ashes, or '^ i Muriate of potash For Oats Followikg Corn— 200 Pounds Per Acre. 50 lbs. Nitrate of soda 1 jj . u i- u. j -i 150 lbs. Acid phosphate | ^^^ P°'^^'^ °" ^'S^^ ^^"^y ^°''* Buckwheat is a heavy feeding crop. It is often grown on new lands. It doesn't do well on soils rich in nitrogenous matter as the straw grows too vigorously and the grain does not fill out. It is often grown on poor soils and should be well fertilized. As it matures in early summer it should be furnished nitrogen in quickly available forms in the early spring so as to establish good growth and not interfere with seed formation. fkrtii,izer formulas for crops 343 Formula for Buckwheat— 400 to 800 Pounds Per Acre. Nitrogen 4-4.5 per cent from Nitrate of soda Available phosphoric acid 7-8 per cent. from. . | BSfc^^a"^^*'^'^' ""^ Potash 9-10 per cent, from Muriate of potash Rice. — Fertilizers are not used extensively in Louisiana and Texas for this crop and the influence of the different forms of fertilizer constituents has not been determined. Phosphoric acid generally increases the yield of rice in Louisiana and Texas and potash is thought to harden the grain and improve its milling quality. Nitrogen is not necessary only on old lands and then in small amounts. If too much nitrogen is applied the plants will lodge. If organic nitrogen is employed it should be applied a long time before the crop is planted as the soil organisms that produce nitrification are retarded in activity when irrigation is practiced. The following formula is employed by many planters. 200 lbs. Acid phosphate \ ^^^^ 50-100 lbs. Kainit / ^ On old lands 50 pounds of cotton-seed meal are added. Formula for Irrigated Rice— 500 to 600 Pounds Per Acre. Nitrogen 2-3 per cent, from Ground bone Phosphoric acid 8-10 per cent, from | ground W ""^ _ ^ , . - f Muriate of potash, or Potash 3-4 per cent, from j Kainit If ground bone is used as a source of nitrogen it will have to be applied a long time before the crop is planted to be of any benefit. In Louisiana more quickly available forms of phosphoric acid are preferred than in this formula. Formula for Unirrigated Rice (Called Mountain Rice or High- land Rice) —600 to 700 Pounds Per Acre. Nitrogen 2-3 per cent, from Nitrate of soda Available phosphoric acid 6-7 per cent, from . . | gasic'^slag^^ ^**^' °'^ „ , , „ J. c f Muriate of potash, or Potash 6-S per cent, from j Kainit 344 SOIL FERTILITY AND FERTILIZERS Staple and Special Crops. Corn is a gross feeder and requires help in securing phosphoric acid. It is a crop that does well on large applications of farm manure, and after leguminous green manures. As this crop is a heavy feeder all the essential elements are needed. Potash helps to produce a firm stalk, nitrogen helps in vigorous growth and phosphoric acid is used in forming grain. When farm manure or leguminous green manure are supplied liberally, only a little nitrogen in a quickly available form is necessary for early growth. Potash and phosphoric acid, however, must be abundantly sup- plied. Like other crops the fertility of the soil and other factors influence the amount and kind of fertilizer to use. FoRMDL.is FOR Corn — 500 to 1,000 Pounds Per Acre. „.. .. r _ f Nitrate of soda, or Nitrogen 2-3 per cent, from | q^^^^j^ nitrogen Available phosphoric acid 7-8 per cent, from .. { Sv'^ed bone'-meal _.., »r_ / Wood ashes, or Potash 6-7 per cent, from | ^^^.^^^ ^^ ^^^^ 2 parts cotton-seed meal ■) .„_ ,u. „„ acre I part acid phosphate / ^°° '°^- ^'^ ^"^ This last formula is for soils rich in potash as in Louisiana. If corn follows cowpeas the nitrogen may be eliminated and 300 pounds of acid phosphate applied per acre. 1,200 lbs. 13% Acid phosphate "| 600 lbs. Cotton-seed meal J- 400 lbs. per acre 200 lbs. Muriate of potash j 2,000 lbs. total 1,000 lbs. Acid phosphate ] 30 lbs. Muriate of potash }■ 230 to 450 lbs. per acre 1,250 lbs. Cotton-seed meal J 2,280 lbs. total 200 lbs. Cotton-seed meal 1 100 lbs. Dried blood ! 200 lbs. Superphosphate . \ P^"^ ^'^^^ 100 lbs. Muriate of potash J 600 lbs. total Cotton is not considered an exhaustive crop but as it is often grown continuously on the same land it gradually depletes the soil of fertility. Most of the essential elements are lost to the FERTILIZER FORMULAS FOR CROPS 345 soil when the seed are sold away from the farm. Phosphoric acid is the important element for this crop. Nitrogen is usually supplied from high grade organic materials and when nitrate of soda is employed it should be applied at the time when it is needed. Potash seems to prevent the shedding of leaves pre- maturely. On soils that produce a large stalk or where cow- peas or other legumes have been turned under, no nitrogen is necessary. Some soils are rich enough in available potash to eliminate the addition of it in fertilization. Phosphoric acid in an available form seems to be always necessary. Formulas for Cotton. 150— 200 pounds cotton-seed meal "1 150 — 200 pounds acid phosphate / " a re. This formula is suitable for Louisiana and other parts of the South where the soil is rich in available potash. For sections where the Boll Weevil is present it is desirable to" produce an early matured crop. Therefore the crop must be forced, and 50 pounds of nitrate of soda should be applied when the plants start growth. Nitrogen 2-3 per cent, from { S-^oTsor ^ ^ { { Avail, phos. acid 7-9 per cent, from { ^^^^X'^d Cm^Ial > '^^ITs Cotton-seed hull ashes, I per acre Potash 4-5 per cent, from -{ Wood ashes, or | Kainit. J Georgi.\ Experiment Station Cotton Formulas— 350 to 880 Pounds Per Acre. Pounds Acid phosphate 1,000 Cotton-seed meal 700 Muriate of potash 75 Barnyard manure 750 pounds ] Cotton-seed 750 pounds | 400 to 800 lbs. Acid phosphate 367 pounds [ per acre. Kainit 133 pounds J Total .■ 2,000 346 SOIL l-'EETILITY AND FERTILIZERS Georgia Cotton Formulas on Worn Soils. Muriate of potash 30 lbs. Muriate of potash 30 lbs. Acid phosphate 334 lbs. Acid phosphate 334 lbs. Nitrate of soda 125 lbs, Dried blood 167 lbs. Muriate of potash 20 lbs. Acid phosphate 281 los. Cotton-seed meal 286 lbs. Cotton-seed hull ashes 45 lbs. Acid phosphate 261 lbs. Cotton-seed meal z86 lbs. Muriate of potash 10 lbs. Acid phosphate with potash 2 per cent. (K^O) 312 lbs. Cotton-seed meal 286 lbs. Kainit 58 lbs. Acid phosphate '■■ 300 lbs. Nitrate of soda 70 lbs. Stable manure 2,000 lbs. Wood ashes (unleached) Acid phosphate Cotton-seed meal 164 lbs. Muriate of potash 20 lbs. 261 lbs. Acid phosphate . ■ . ■ 300 lbs. 286 lbs. Nitrate of soda 64 lbs. Cotton-seed 13^^ bush. Kainit 64 lbs. Acid phosphate 273 lbs. Cotton-seed meal 143 lbs. Cotton-seed I3>^ bush. Acid phosphate 266 lbs. Nitrate of soda 13 lbs. Stable manure 4,000 lbs. Kainit 45 lbs. Acid phosphate 264 lbs. Cotton-seed 26% bush . Commercial fertilizer to analyze as below : Available phosphoric acid 10.00 Ammonia 4.85 Potash (KjO) 3.00 Use 500 pounds per acre. All cotton formulas that do not include nitrate of soda should receive an application of this material at the rate of 50 pounds per acre, when the plants start growth, in sections infested with the Boll Weevil. Cotton Formula Sold by Manufacturers. Avail, phos. acid 8.00 per cent, from Acid phosphate ] Nitrogen Potash 1.65 per cent, from 2.00 per cent, from Acid phosphate Nitrate of soda and Cotton-seed meal Kainit 300-600 lbs. ( per acre. This formula or one very similar to it, is used extensively and only small amounts of nitrate of soda are used when this mate- rial is included. FERTILIZER FORMULAS FOR CROPS 347 Tobacco is a crop that must be fertilized very carefully to pre- vent injuring the flavor of the leaf. Chlorine seems to be det- rimental to the production of good flavored leaf. Therefore muriate of potash, kainit and sylvinit must not be used. The potash may be furnished from sulphate of potash, carbonate of potash, or from cotton hull and wood ashes. Nitrogen as nitrate or organic nitrogen from dried blood, cotton-seed meal, castor pomace and linseed meal are excellent. These nitrogenous fer- tilizers are often combined so as to supply available nitrogen dur- ing the whole growing period. Phosphoric acid in the available form is best suited for this crop. Most of the high priced to- bacco is grown on light soils which are rather deficient in fer- tility. Large applications of complete fertilizers are essential although excessive amounts should be avoided to produce profit- able yields. Farm manures and green manures tend to produce a coarse leaf which is undesirable for grades of high quality. Florida Tobacco Formula.s. No. 1. Per cent. 300 lbs. of carb. of'pot. (60 per cent. ) "| 400 lbs. of tobacco dust (2-5) | 200 lbs. of cotton-seed meal (V/2-1%-^ %)■■■■ i \°^^ a^aZble 750 lbs. of bone-meal (4-10) \ °^f potash 300 lbs. of concentrated phos. (25 percent.). . ] •=> v 50 lbs. of nitrate of soda (17 per cent. ) J 2,000 Commercial value per ton mixed and bagged. . $38.30 Plant food per ton 440 pounds. No. 2. Per cent. 300 lbs. of nitrate of potash ( 13-42 ) ] 100 lbs. of carb. of pot. ( 60 per cent. ) I 3.05 ammonia Soo lbs. of tobacco dust ( 2-3 ) \ 8.95 available 200 lbs. of bone-meal (3-12) I 10.50 potash 600 lbs. of concentrated phos. (25 per cent. ) • j 2,000 Commercial value mixed and bagged I3S.30 Plant food per ton 440 pounds. 348 SOIL FERTILITY AND FERTILIZERS No. 3. Per cent. 400 lbs. of nitrate of potash ( 13-42) ") 100 lbs. of cotton-seed meal (T/i-iii-iyi) I 4.20 ammonia 700 lbs. of tobacco dust ( 2-5 ) \ 9.45 available 100 lbs. of bone-meal (3-12) | 10.20 potash 700 lbs. of concentrated phos. (25 per cent. ) . . J 2,000 Commercial value mixed and bagged J37. 15 Plant food per ton 477 pounds No. 4. Per cent. 500 lbs. of nitrate of potash ( 13-42) 1 4.45 ammonia 700 lbs. of tobacco dust ( 2-3) >■ 10.00 available 800 lbs. of concentrated phos. (25 per cent. ) ■ . j II.55 potash 2,000 Commercial value mixed and bagged $39- 50 Plant food per ton 520 pounds No. 5. 300 lbs. of cotton-seed meal 150 lbs. of nitrate of soda 300 lbs. of acid phosphate 200 lbs. of sulphate of potash Part of the nitrate of soda may be applied after the plant has started growth. Connecticut Tob.^cco Formula — Per Acre. ,„., IK, -:* .»_ <-„™ / Mixtures of nitrate of soda, sulphate of 100 lbs. mtrogen from | ammonia and high grade organic forms. 75 lbs. avail, phos. acid from superphosphates 150 lbs. potash from sulphate of carbonate forms. Kentucky and Virginia on heavier soils may give good yields with smaller applications than for Connecticut. Sempers recommends a formula furnishing 1,000-2,000 pounds per acre, of Nitrogen 5-7 per cent, from Nitrate of soda Avail, phos. acid 5-6 per cent, from Dissolved bone-black {Cotton-seed hull ashes, or Wood ashes, or Sulphate of potash. Sugar-cane is another crop which is grown in limited areas. The Louisiana Sugar Experiment Station has investigated the FERTILIZER FORMULAS FOR CROPS 349 needs of this crop. It is customary to rotate this crop with corn and cowpeas. Cane is grown for two years as plant and first year stubble, and corn the third year with cowpeas sown be- tween the rows at the last cultivation. The cowpeas are usually fed to the plantation mules but the roots and more or less of the plants are left on the land. Sugar-Cane Formula with Cowpeas. Plant Cane 300400 Pounds. Acid Phosphate Per Acre. 1st year stubble 200 lbs. acid phosphate ) 200 lbs. cotton-seed meal, !• per acre, or tankage J Without Cowpeas Plant cane 200 lbs. acid phosphate I 200 lbs. cotton-seed meal, [ per acre or tankage j 1st year stubble 100 lbs. acid phosphate ] 200 lbs. cotton-seed meal, )■ per acre, or tankage J Florida Formula. 400 to 500 lbs. cotton-seed meal "1 50 to 100 lbs. nitrate of soda ! ^^^^ 300 to 400 lbs. acid phosphate j ^ 100 to 150 lbs. kainit J Part of the nitrate of soda in this last formula may be used as a second application after the plants have started. Sugar-cane has a long growing season and the nitrogen there- fore is furnished mostly from organic sources so as to be able to supply available nitrogen during this period. Although sugar-cane requires available potash the Louisiana cane lands are sufficiently supplied with this constituent to meet the requirements of this crop. Sugar-Cane Formula-Semper Makures-6oo-9oo Pounds Per Acre. -T.. . , f Nitrate of soda and Nitrogen 1.5-2 per cent, from | Cotton-seed meal Avail, phos. acid 7-9 per cent, from { Dis^oFv^ed bone%Lk _ ^ , . c f Muriate of potash, or Potash 7-9 per cent, from | Kainit Irish potatoes are an exhaustive crop from the fertility stand- point, but from the money value viewpoint they are less ex- haustive than the small grains. They are grown as an early and late crop in the North and in the South they are generally 350 SOIL FERTILITY AND FERTILIZERS most profitable when harvested in very early spring. They are usually grown in rotation and the early crops are forced by heavy fertilization, while the late crops are allowed to grow slowly and with less fertilizer. Potash is an important constit- uent for potatoes as it aids in carbohydrate formation. The chlorides seem to produce inferior potatoes and potatoes that will not stand storage. The sulphates of potash seem to pro- duce better looking and more uniform potatoes. For early spring potatoes the nitrogen may be supplied partly in quickly available forms and partly from organic substances as dried blood, cotton- seed meal, etc. The late potatoes do not require quickly avail- able plant food as they have a long growing season. Excessive nitrogen should be avoided as the vines will grow too vigorously and the tubers will not develop. Phosphoric acid from super- phosphates is desirable for early and late potatoes. Formulas for Irish Potatoes— 500-1, 500 lbs. per Acre. .,.. ^ ^ c I Nitrate of soda and Nitrogen 4-6 per cent, from | Dried blood Available phosphoric acid 5-7 per cent, from -. { DL^oWed'bonl%rack Potash 7-9 per cent, from Sulphate of potash Early Potatoes — 800-2,000 lbs. per Acre. Nitrogen 3-4 per cent, from available forms Available phosphoric acid 6-8 per cent, from superphosphate. Potash 8-10 per cent, from sulphate of potash. This formula is employed in New York and New Jersey. Late Potatoes— 600-800 lbs. per Acre. Nitrogen 2.5 per cent. Available phosphoric acid 6 per cent. Potash 8 per cent. Maine Potatoes Harvested in Early Sept.— 1,200-1,500 lbs. per Acre. Ammonia 4-6 per cent. Available phosphoric acid 6-8 per cent. Potash 7-10 per cent. The potatoes that receive this formula follow clover sod which is turned under in the fall. Some farmers in Maine use higher quantities of ammonia to force growth in that northern latitude and potash to benefit the clover which follows. FERTILIZER FORMULAS FOR CROPS 35 1 Louisiana Potatoes Harvested in Early May— 1,000-1,500 lbs. per Acre. 500-600 lbs. cotton-seed meal 500-600 lbs. acid phosphate'. 175-200 lbs. sulphate of potash. The Louisiana soils are rich in potash but for heavy yields the addition of sulphate of potash is beneficial. This formula is for an average soil with no cowpeas plov^red under. With Cowpeas — Turned Under — 800-1,000 lbs. per Acre. 500:600 lbs. acid phosphate. 175-200 lbs. sulphate of potash. Sweet Potatoes. — In the growing of sweet potatoes the north- ern market demands must be catered to. A small rather round •potato that is dry and mealy when baked is desirable. In the South a larger more oblong potato is relished. The phosphoric acid and potash requirements are about the same as for Irish potatoes except that chlorides may be used. As short round po- tatoes are desired, less nitrogen must be used than in growing Irish potatoes. When large amounts of nitrogen are used the potatoes grow too large and oblong. In the South nitrogen as nitrates and organic forms are used. The organic nitrogen seems to produce a better product and may be used to advantage in the South, but in the North, nitrates are preferable especially in cold seasons. Formulas For Sweet Potatoes. Requirement— 3 Per Cent- Ammonia, 7 Per Cent. Available Phos- phoric Acid and 8 Per Cent. Potash. 100 lbs. nitrate of soda 'l f _ June 5, '98 i 25 lbs. muriate of pot. J ( 25 lbs. nitrate of soda "| 5 i Oatsandpeas...April20..98]-j^--^d^P^-^^^^^^^^ [ 50 lbs. muriate of pot. J I Soybeans Aug. i, •98{ ^^^^^ L^^eTp^^! } Oct x. '98 f f 150 lbs. acid phosphate ^ I Rye Sept. 29, '97 -I 50 lbs. ground bone |-Mayi, '98 I L 25 lbs. muriate of pot. J I f 75 lbs. nitrate of soda "l I Millet May i, '^S'{ 150 lbs. acid phosphate fjuly i, '98 I 75 lbs. muriate of pot. J [ Cowpeas July 20, '98 { ^ {^^ St'e^o^ } ^^^'- -' '^ 3S8 SOIL i'ERTILITY AND FERTILIZERS Scheme op Soiling Qrovs.— (Continued) No. of Crop Time of Amount of ferti- Time of acre rotation seeding lizer applied harvesting r f 25 lbs. nitrate of soda 1 Oats and peas. . .April 10, ',, \ '- j^^ ^L^^d bot^^^ [ J"- -■ ''^ [ 50 lbs. muriate of pot. J S>y beans July:, '98 { ^^ j^^; -j^^iS^/- } ^^P'" ^- '^^ f 25 lbs. nitrate of soda 1 Barley and peas, Sept. i, '98^ 100 lbs. acid phosphate ^ Nov. i, '98 L 50 lbs. muriate of pot. J f 25 lbs. nitrate of soda ] Oats and peas- • . April i, -98 ] '~ '^ gt^^ffife^^^ [ June r, .98 |_ 50 lbs. muriate of pot. I Cowpeas June ,5. '98 { ^^ '^^_ ^S^^f!^. ] ^"S. ^5, '98 f 25 lbs. nitrate of soda ^ Barley and peas, Aug. 20, '98 < 100 lbs. acid phosphate \ Oct. 20, '98 [ 50 lbs. muriate of pot. J f 25 lbs. nitrate of soda 1 Rye and vetch. -Sept. 10, '97 •( 150 lbs. acid phosphate |- May 5, '98 1_ 75 lbs. muriate of pot. J f 100 lbs. acid phosphate \ 9 { Corn June I, '98 •( 50 lbs. ground bone } Aug. i, '98 L 50 lbs. muriate of pot. ) f 25 lbs. nitrate of soda "1 Barley and peas. Aug. 15, '98-j 100 lbs. acid phosphate j^Oct. 15, '98 [ 15° lbs. muriate of pot. J Rape is often used as a soiling crop. It is a vigorous feeder and capable of obtaining food more readily than cereal crops. Nitrogen in available forms helps this crop in early growth. It requires phosphoric acid and abundant supplies of potash. Formula for Rape. Nitrogen 2-3 per cent, from { S llood°^^ Avail, phos. acid, 4-5 per cent, from Superphosphate Poush 4-5 per cent, from { ^^^^ °f V°^^^'^' °^ Ensilage. — In the production of corn for ensilage the formation of ears is desirable and the crop should be fertilized somewhat the same as field corn. More nitrogen is needed however for silage than for field corn, because a larger growth of stalk is re- quired. Legumes are often mixed with corn and sorghum in growing crops for ensilage. The legumes require liberal sup- plies of phosphoric acid and potash. fertilizer formulas for crops 359 Formula for. Silage Corn. 450 pounds cotton-seed meal, or ] 250 pounds dried blood i 300 pounds acid phosphate | ^ 120 pounds muriate of potash j Pasturage. — In applying fertilizers to pastures the main object is to produce growth of legumes and grasses. If too much nitrogen is supplied the grasses will crowd out the legumes. It should therefore be better to encourage the growth of the leg- umes as these furnish the richer feed. Mixtures of bone-meal, acid phosphate, muriate of potash and kainit, are excellent for pastures. An occasional dressing of lime is sometimes essen- tial. Hay and Grass Crops. — Grass crops do well when supplied with complete fertilizers. Nitrogen is essential for vigorous growth and a little nitrate of soda is very beneficial in helping grass to recover from a severe winter. These crops feed close to the surface and are unable to search and obtain mineral food unless it is supplied. Phosphoric acid and potash help a great deal in increasing the yields. Stable manure, ground bone and muriate potash are very beneficial. Formula for Grass Crops. f Nitrate of soda and Nitrogen, 5-6 per cent, from { Dried blood, or [ Raw bone-meal. f Raw bone-meal, or Avail, phos. acid 5-6 per cent, from \ Basic slag, or [ Acid phosphate. Potash 7-8 per cent, from | Ka°nk''^''"' °'' Koots. — Turnips, fodder beets, rutabagas, mangels, carrots, sugar-beets, etc., are grown for feeding live-stock. They as- similate large amounts of plant food and liberal fertilization is necessary for the production of large yields. Fodder beets, carrots and sugar-beets need plenty of nitrogen and phosphoric acid to keep up a rapid and continuous growth. Potash is re- quired on soils deficient in this constituent and especially on light soils. The nitrogen and phosphoric acid should be in readi- ly available forms so as to help in early growth. Mangels are perhaps the largest feeders and seem to be able to secure phos- 360 SOIL FERTILITY AND FERTILIZERS phoric acid from the soil. Turnips cannot secure phosphoric acid as well as mangels and they feed also more from the sur- face soil. The turnip uses a great deal of potash. Nitrogen is necessary for early, rapid, and continuous growth in all root crops. Irish and sweet potatoes when grown for stock feed require the same fertilization as when produced for market. Usually these crops are not fed to stock unless the market price is too low to warrant shipping. FoRMTOAS FOR Roots. Mangels— 400-800 Pounds Per Acre. Nitrogen 5-6 per cent, from Nitrate of soda , ., . -J ■ £ i. f / Dissolved bone-black, or Avail, phos. acid 5-6 per cent, from | ^^j^ phosphate Potash 7-9 per cent, from Sulphate of potash. Turnips (Rutabagas) — 300-800 Pounds Per Acre. .... , , , r I Nitrate of soda Nitrogen 4-5 per cent, from | dissolved bone-meal f Dissolved bone-meal, or Avail, phos. acid 6-7 per cent, from -| Dissolved bone-black, or (^ Acid phosphate. T, . . i r ) Wood ashes, or Potash 7-9 per cent, from [ j^^^j^^^ „f ^^^^^^ Fodder Beets and Sugar-Beets — 1,000 Pounds Per Acre. Nitrogen 4 per cent. Available phosphoric acid 5 per cent. Potash 10 per cent. 3. Market Garden and Truck Crops. Requirements. — These crops require large applications of high grade fertilizers because they are usually forced for an early market. If these crops are late most of the profits are lost. Many of these truck crops are grown on sandy, or light soils, which are naturally deficient in fertility. Market garden crops are often grown near cities on high priced land which necessitates early and large yields to make them pay. An excess of all the constituents should be furnished to be certain that enough plant food is present. Part of the nitrogen in fertilizers for these crops should be as nitrate to give the plants an early start as these crops are often grown in the spring before the nitrate forming organisms are active. FERTII. Dissolved bone-meal, or (^ Acid phosphate. Potash 8-.0 per cent, from { St^'^"' "^ Grape, because of the large yields, is an exhaustive crop and requires liberal fertilization. Potash and phosphoric acid are especially required. Grapes — 500-joo Pounds Per Acre. -... 1. r „ f Nitrate of soda and Nitrogen 1.5-2 per cent, from { ^^^ bone-meal f Dissolved bone-black, or , ., , ., 1 f „ I Dissolved bone-meal, or Avail, phos. acid 7-9 per cent, from ^ ^^^ bone-meal, or (^ Acid phosphate ( Wood ashes, or Potash 10-12 per cent, from \ Muriate of potash, or [-- • ■ Kainit 1,000-2,000 lbs. 100 lbs. bone-meal 100 lbs. acid phosphate ^^^^ 100 lbs. muriate of potash J ^ 150 lbs. bone-meal j 1,000-2,000 lbs 100 lbs. muriate of potash I per acre. FERTmZER FORMULAS FOR CROPS 37 1 On light soils a dressing of 200 pounds of nitrate of soda is often desirable in the spring in addition to these last two formulas. Miscellaneous Fruits. — Other fruits which are grown in some sections require special fertihzation and a few formulas are given for reference. Pineapples— 2,000-3,000 Pounds Per Acre. ■-T. . c f Dried blood, or Nitrogen 3 per cent, from { cotton-seed meal { Ground bone, or Phos. acid 7 per cent, from \ Basic slag, or [ Dissolved bone-black Potash 7 par cent, from Sulphate of potash Apply in two dressings; one in February and the other in July. "I Cotton-seed meal, or ' Nitrogen 5 per cent, from \ Dried blood, or 3,500-4,000 J. Castor pomace \ lbs. per Avail, phos. acid 4 per cent, from Superphosphate acre Potash 10 per cent, from Sulphate of potash This last formula should be applied in three or four dressings. When acid phosphate is used, lime at the rate of 750 pounds per acre is necessary every two years, because acid phosphate has an injurious effect on pineapples which lime corrects. The banana plant requires a rich soil and some chlorine for best development. Potash seems to be beneficial and 300 pounds more than is included in the formula is sometimes helpful. The potash should be supplied as chloride. Banana Formulas. 200 lbs. nitrate of soda i 200 lbs. dried blood I per acre in two 500 lbs. acid phosphate [ applications 400 lbs. muriate of potash j „.. . , f Nitrate of soda 1 Nitrogen 4-5 per cent, from { Cotton-seed meal ^^ g^ ^^^ Avail, phos. acid 6-8 per cent, from { ^u jlft'os^hat'e °' P^"" «"^- '" Potash 7-9 per cent, from Kainit ) Japanese Persimmons. 5 lbs. to a tree. Nitrogen 3 per cent. Phosphoric acid 6 percent. Potash 10 per cent. 25 372 SOIL FERTIUTY AND FERTILIZERS Most any of the fertilizer materials are acceptable for this fruit. The nitrogen may be supplied from some leguminous green manure. Olives— 500-joo Pounds Per Acre. Nitrate of soda, or ' ammonia 500-700 Nitrogen 4-5 per cent, from { f^^^^^^, Avail, phos. acid 5-7 per cent, from { ^^^j^^^^J"-^^^^^^ fbt^er Potash 7-8 per cent, from {^^';;f^'«=°fP°*^^^'°^ 1^"^' Figs, Avocada Pear and Guava. — There is not much known about the requirements of these fruits but the following general formula is recommended. 300 lbs. nitrate of soda. 500 lbs. acid phosphate. 200 lbs. sulphate of potash. Figs in addition to the above fertilizer requires a dressing of lime when the soil is deficient in this constituent. For guava, 600-1,000 pounds per acre of this formula are recommended. Nuts. — Pecans do well on formulas furnishing : Nitrogen Avail, phos. acid Potash 6 per cent, from Cotton-seed meal, or Dried blood, or Tankage and . Nitrate of soda f Acid phosphate, or 3 per cent, from \ ^^""^"^ rock phosphate, or ^ '^ I Bone-meal, or L Basic slag. f Wood ashes, or 3 per cent, from \ Muriate of potash, or [ Kainit. Most of the nitrogen can be furnished from organic sources with occasional applications of nitrate of soda or sulphate of ammonia when growth is needed in early spring. Black wal- nuts, chestnuts and other nuts may be fertilized similarly to pecans. Cocoanuts. — This tree visually grows near the seashore, and seaweed may often be profitably utilized as a source of fertilizer. FERTILIZER FORMULAS FOR CROPS 373 Table Showing the Number of Pounds of a Fertilizer Required TO Furnish One Pound of Any Element When the Per- centage OF That Element Present in the Fertilizer is Known.** li. i V OJ a.- i Of i es H "■S S = ^■s CO « «,% m ;- ^■s •c S ■c E T, w -o Z ■O u 11 S3 off So. 1 = ^ ii U u n ^ m (M ft. CLi h \\ °< B. O.I 1,000.00 4-4 ■ 22.73 8-7 11.49 13-0 7.692 0.2 500.00 4-5 22.22 8.8 11.36 '3-1 7-634 0-3 333-33 4.6 21.74 8-9 11.24 13.2 7-576 0.4 250.00 4-7 21.28 9-0 11. II '3-3 7-512 0.5 200.00 4.8 20.83 9-1 10.99 13-4 7463 0.6 166.67 4-9 20.41 9-2 10.87 13-5 7.407 0.7 142.86 5-0 20.00 9-3 10.75 13.6 7-353 0.8 125.00 5-1 19.61 9-4 10.64 13-7 7-299 0.9 III. II 5-2 19-23 H 10.53 13-8 7.246 I.O 100.00 5-3 18.87 9-6 10.42 13-9 7- '94 1. 1 90.91 5-4 18.52 9-7 10.31 14.0 7-143 1.2 83-33 5-5 18.18 9.8 10.20 14. 1 7.092 1-3 76.92 5-6 17.86 9-9 iO.lO 14.2 7.042 1.4 71-43 5-7 17-54 lO.O 10.00 14-3 6-993 1-5 66.63 5-8 17.24 10. 1 9.901 14-4 6.944 1.6 62.50 5-9 16.95 10.2 9.804 14-5 6.897 1.7 58.82 6.0 16.67 10.3 9.709 14.6 6.849 1.8 55-56 6.1 16.. ^9 10.4 9-615 14.7 6.803 1-9 52-63 6.2 16.13 10.5 9524 14.8 6.757 2.0 50.00 6.3 15-87 10.6 9-434 14.9 6.711 2.1 47-62 6.4 15-63 10.7 9-346 15-0 6.667 2.2 45-45 6.5 15-38 10.8 9259 15- 1 6.623 2.3 43-48 6.6 1515 10.9 9-174 152 6-579 2.4 41.67 6-7 14-93 II. 9.091 15-3 6.536 2-5 40.00 6.8 14.71 11. 1 9.009 15-4 6.494 2.6 38.46 6.9 14-49 II. 2 8.929 iS-5 6.452 2.7 37-04 7-0 14.29 11-3 8.850 15.6 6.410 2.8 35-71 7-1 14.08 11.4 8.772 15-7 6.369 2.9 34-48 7-2 13-89 II-5 8.696 15-8 6.329 3-0 33-33 7-3 13-70 ir.6 8.621 15-9 6.289 3-1 32-26 7-4 13-51 11.7 8.547 16.0 6.250 3-2 31-25 7-5 13-33 II. 8 8.475 16. 1 6.211 3-3 3°-30 7-6 13.16 11.9 8.403 16.2 6.173 34 29.41 7-7 12.99 12.0 8-333 16.3 6.135 3-5 28.57 7-8 12.82 12.1 8.264 16.4 3-6 27-78 7-9 12.66 12.2 8.197 16.5 6^061 3-7 27-03 8.0 12.50 12-3 8.130 16.6 6.024 3-8 26.32 8.1 12-35 12.4 8.065 16.7 5.988 3-9 25.64 8.2 12.20 12.5 8.000 16.8 5-952 4.0 25.00 8.3 12.05 12.6 7-937 16.9 5-9'7 4.1 24-.39 8.4 11.90 12.7 7.874 17.0 5-882 4.2 23-81 8-5 11.76 12.8 7-813 17.1 5-848 4-3 23.26 8.6 11.63 12.9 7-752 17.2 5-814 374 SOIL FERTILITY AND FERTILIZERS Table. — ( Continued) V i. V V &- k S- i Is «1 -g'S CO - 1" ^1 3" •g'S =■ u °' So. n So- n fi. »< h a, (L, a< 0. Ci. 17.3 5-780 22.0 4-545 26.7 3-745 31-4 3-185 17.4 5-747 22.1 4-525 26.8 3-731 31 5 3-175 17-5 5.7>4 22.2 4505 26.9 3-717 31-6 3-165 17.6 5.682 22.3 4.484 27.0 3-704 31-7 3 155 17.7 5-650 22.4 4.464 27.1 3.690 31-8 3-145 17.8 5.618 22.5 4.444 27.2 3.676 319 2-I3S 17.9 5-587 22.6 4-425 27-3 3-663 32.0 3-125 18.0 5-556 22.7 4405 27-4 3650 32.1 3-115 18. 1 5-525 22.8 4.386 27.5 3-636 32.2 3.106 18.2 5-495 22.9 4-367 27.6 3623 32.3 3.096 18-3 5-464 23.0 4-348 27.7 3.610 32.4 3.086 18.4 5-435 23-1 4329 27.8 3-597 325 3-077 18.5 5-405 23.2 4.310 27.9 3-584 32-6 3.067 18.6 5-376 23-3 4-292 28.0 3-571 32.7 3-058 18.7 5-348 23-4 4-274 28.1 3-559 32.8 3049 18.8 5-319 23-5 4.255 28.2 3-546 32.9 3.040 18.9 5-291 23-6 4-237 28.3 3-534 330 3-030 19 5-263 23.7 4.219 28.4 3-521 33-1 3.021 19.1 5-236 23.8 4.202 28.5 3-509 33-2 3.012 X9.2 5-208 23-9 4.184 28.6 3-497 33-3 3-003 i9 3 5-i8i 24.0 4.167 28.7 3-484 33-4 2-994 19.4 5-155 24.1 4.149 28.8 3-472 33-5 2.985 19-5 5-128 24.2 4.132 28.9 3-460 33-6 2.976 19.6 5- 102 24.3 4-115 29.0 3448 33-7 2.967 19.7 5.076 24.4 4.098 29.1 3-436 33-8 2-959 19.8 5-051 245 4.082 29.2 3-425 33-9 2.950 19.9 5-025 24.6 4.065 29-3 3-413 34-0 2.941 20.0 5.000 24.7 4.049 29.4 3.401 34-1 2.933 20.1 4-975 24.8 4.032 295 3-390 34-2 2.924 20.2 4-950 24.9 4.016 29.6 3-378 34-3 2-915 20.3 4-926 25.0 4.000 29.7 3-367 34-4 2.907 20.4 4.902 25-1 3984 29.8 3-356 34-5 2899 20.5 4.878 25.2 3.968 29.9 3-344 34-6 2.890 20.6 4.854 253 3-953 30.0 3-333 34-7 2.882 20.7 4.831 25-4 3.937 30.1 3-322 .^4-8 2.874 20.8 4.808 25-5 3-922 30.2 3-3II 34-9 2.865 20.9 4.785 25-6 3.906 30-3 3-300 35.0 2.857 21.0 4,762 25-7 3-891 30.4 3.289 35-1 2.849 21. 1 4-739 25-8 3.876 30.5 3-279 35-2 2.841 21.2 4-717 259 3.861 30.6 3.268 35-3 2.833 21.3 4.695 26.0 3-846 307 3-257 35-4 2.825 21.4 4.673 26.1 3-831 30.8 3-247 35-5 2.817 21.5 4.651 26.2 3-817 30.9 3-236 35-6 2.809 21.6 4.630 26.3 3.802 31,0 3-226 35-7 2.801 21.7 4.608 26.4 3-788 3I-I 3-215 35.8 2.793 21.8 4587 26.5 3-774 31.2 3-205 359 2.786 21.9 4-566 26.6 3-759 31-3 3-195 36-0 2.778 FERTILIZER FORMULAS FOR CROPS 375 Table. - (Continued) &- ^- £ a^ i a. i £ = ,«■« 5c -•O -2 .,•0 -S ^ ■.■o S» •Si! = S £S -sj; c ^ -sj; 11 i'^ 11 n =•3 0°' So. 11 p. £ n. a, a. PU h b 36.1 2.770 40.8 2.451 45.5 2.198 50.2 1.992 36.2 2.762 40.9 2-445 45-6 2-193 50.3 1.988 36.3 2-755 41.0 2-439 45-7 2.lh8 50.4 1.984 36.4 2.747 41. 1 2.433 45.8 2.183 50-5 1.980 36.5 2.740 41.2 2.427 45.9 2.179 50.6 1.976 36.6 2.732 41.3 2.421 46.0 2.174 50.7 1.972 36.7 2.725 41.4 2.415 46.1 2.169 50.8 1.969 36.8 2.717 41.5 2.410 46.2 2.165 50-9 1-965 36.9 2 710 41.6 2.404 46-3 2- 160 51.0 1. 961 37.0 2.703 41-7 2.398 46.4 2.155 5I.I 1.957 37.1 2.695 41.8 2.392 46.5 2. 151 51-2 1-953 37-2 2.688 41-9 2.387 46.6 2.146 5[.3 1.949 37-3 2.681 42.0 2-381 46.7 2. 141 51-4 1.946 37.4 2.674 42.1 2-375 46.8 2-137 5 '.5 1.942 37-5 2.667 42.2 2.370 46.9 2-132 51.6 1.938 37.6 2.660 42.3 2.364 47.0 2.128 51.7 1-934 37-7 2-653 42-4 2-358 47.1 2-123 51.8 1. 931 37.8 2.646 42-5 2-353 47.2 2. 119 51.9 1.927 37-9 2.639 42.6 2.347 47.3 2. 1 14 52.0 1.923 38.0 2.632 42-7 2.342 47.4 2. no 52.1 1.919 38' 2.625 42.8 2.336 47.5 2.105 52.2 1.916 38.2 2.618 42.9 2.331 47.6 2.IOI 52-3 1. 912 38.3 2. 611 43-0 2.326 47-7 2.096 52-4 1.908 38.4 2.604 43-1 2.320 47.8 ^■°fi 52-5 1.905 3S.5 2-597 43-2 2.315 47.9 2.088 52-6 1.901 38.6 2.591 43-3 2.309 48.0 2.083 52-7 1.898 38.7 2.584 43.4 2.304 48.1 2.079 52.8 1.894 38.8 2-577 43-5 2.299 48.2 2.075 52.9 '■^§° 38.9 2-571 43-6 2.294 48.3 2.070 53.0 1.887 39-0 2.564 43-7 2.288 48.4 2.066 53.1 1.883 391 2.558 43-8 2.283 48.5 2.062 53-2 1.880 39-2 ^■551 43-9 2.278 48.6 2.058 53-3 1.876 39-3 2.545 44.0 2.273 48.7 2.053 53-4 1.873 39-4 2.538 44.1 2.268 48.8 2.049- 53-5 1.869 39- S 2.532 44.2 2.262 48.9 2.045 53-6 1.866 39-6 2.525 44.3 2.257 49.0 2.041 53-7 1.862 39-7 2.519 44.4 2.252 49.1 2.037 53-8 1.859 39-8 2-513 44.5 2.247 49.2 2.033 53-9 1.855 39-9 2.506 44.6 2.242 49-3 2.028 54-0 '•^52 40.0 2.500 44.7 2.237 49-4 2.024 54-1 1.848 40.1 2.494 44.8 2.232 49-5 2.020 54-2 1.845 40.2 2.488 44-9 2.227 49-6 2.016 54.3 1.842 40.3 2.481 45.0 2.222 49-7 2.012 54.4 1.838 40.4 2-475 45-1 2.217 49-8 2.008 54.5 1.835 40-5 2.469 45-2 2.212 49-9 2.004 54.6 1.832 40.6 2.463 45-3 2.208 50.0 2.000 54-7 1.828 40.7 2457 45-4 2.203 50.1 1.996 54-8 1.825 376 SOII< FERTILITY AND FERTILIZERS Ta.'bvb.. — (Continued) 1- 1 a.- Si i a^ K \l ^1 2 s £« .si Is sl U a! fl ^ i'l 11 n n n Il< c L| CLi b tv 0. Pk ( i< 54-9 I 821 59-6 1.678 64.3 1-555 69.0 I 449 55° I 818 59-7 1.675 64-4 1-553 69-1 I 447 55-1 1 815 59-8 1.672 645 1-550 69.2 I 445 55-2 I 812 59-9 1.669 64.6 1.548 69-3 1 443 55-3 I 808 60.0 1.667 64.7 1-546 69-4 1 441 55-4 I 805 60.1 1.664 64.8 1-543 69-5 I 439 55-5 I 802 60.2 1. 66 1 64.9 1-54' 69.6 I 437 55.6 1 799 60.3 J. 658 65.0 1-538 69.7 I 435 55-7 I 795 60.4 1.656 65.1 1.536 698 I 433 55-8 I 792 60.5 1.653 65-2 1.534 69.9 I 431 55-9 ' 789 60.6 1.650 65-3 1-531 70.0 1 429 56.0 I 786 60.7 1.647 65-4 1.529 70.1 1 427 56.1 1 783 60.8 1.645 65.5 1.527 70.2 1 425 56.2 I 779 60.9 1.642 65.6 1-524 70.3 ' 422 56-3 I 776 61.0 1.639 65-7 1-522 70.4 I 420 56.4 I 773 61. 1 1.637 65.8 1.520 70.5 I 418 56.5 I 770 61.2 1.634 65.9 1-517 70.6 1 416 56.6 I 767 61.3 1.63 c 66.0 1-515 70.7 I 414 56.7 J 764 6. .4 1.629 66.1 1-513 70.8 1 412 56.8 I 761 61.5 1.626 66.2 1.511 70.9 I 410 56.9 I 757 6r.6 1.623 66.3 1.508 71.0 I 408 57-0 I 754 61.7 1. 62 1 66.4 1.506 71.1 1 406 57-1 I 75' 61.8 i.6i8 66.5 1504 71.2 1 404 57-2 I 748 61.9 1. 616 66.6 1.502 71-3 I 403 57-3 I 745 62.0 1.613 66.7 1.499 71-4 I 401 57-4 I 742 62.1 1.610 66.8 1.497 71-5 I 399 57-5 I 739 62.2 1.608 66.9 1-495 71.6 I 397 57-6 I 736 62.3 1.605 67.0 1.493 71.7 1 395 57-7 J 733 62.4 1.603 67.1 1.490 7.8 1 393 57.8 I 730 62.5 1.600 67.2 1.488 71.9 1 391 57.9 I 727 62.6 1.597 67-3 1.486 72.0 1 389 58.0 I 724 62.7 1.595 67.4 1.484 72.1 I 387 58.1 I 721 62.8 1.592 67.5 1.481 72.2 1 385 58.2 I 718 62.9 1.590 67.6 1-479 72.3 1 383 58.3 I 7'5 63.0 1.587 67.7 1-477 72.4 1 381 58.4 I 712 631 1.585 67.8 1-475 72.5 I 379 58.5 I 709 63.2 1.582 67.9 1-473 72.6 I 377 58.6 I 706 633 1.580 68.0 1.471 72.7 I 376 58.7 I 704 63-4 1.577 68.1 1.468 72.8 1 374 58.8 I 701 63.5 1.575 68.2 1.466 72.9 1 372 58.9 I 698 63.6 1.572 68.3 1.464 730 1 370 59-0 I 695 63.7 I -570 68.4 1.462 73-1 1 368 59-1 I 692 63.8 1.567 68.5 1.460 73-2 1 366 59-2 I 689 63-9 1-565 68.6 1.458 73-3 1 364 59-3 I 686 64.0 1.563 68.7 1.456 73-4 1 362 59-4 I 684 64.1 1.560 68.8 1.453 73-5 1 361 59-5 I 681 64.2 1.558 68.9 1.451 73-6 I 359 FERTILIZER FORMULAS FOR CROPS 377 Table.— {Conii nued) V ILI V tfw t a.- V &- i 5? «.'0 s = .^•o 20 il-a «c ^"^ R w ■oK e% ■ss £" •SS •SK fcp. n n c u U U n CU a. ft( ». h ai P, a. 73-7 1-357 78-4 1.276 - 83.1 1.203 87.8 1139 73-8 1-355 78.5 1-274 83.2 I 202 87-9 1. 138 73-9 1-353 78.6 1.272 83-3 1.200 88.0 1.136 74.0 1-351 78-7 1. 271 83-4 1.199 88.1 1 .135 74-1 1-35° 78.8 1.269 83-5 1. 198 88.2 I- 134 74.2 1-348 78.9 1.267 83.6 ..196 88.3 1-133 74-3 1.346 79.0 1.266 83-7 1-195 88.4 1.131 74-4 1-344 79.1 1.264 85.8 1-193 88.5 1.130 74-5 1-342 79.2 1.263 83-9 1. 192 88.6 1.129 74-6 1-340 79.3 1. 261 84.0 1:190 88.7 1,127 74-7 1-339 79.4 1-259 84.1 1.189 88.8 1. 126 74.8 1-337 79.5 1.258 84.2 1. 188 88.9 1-125 74-9 1-335 79.6 1.256 84.3 1.186 89.0 1. 124 75-0 1-333 79.7 1-255 84-4 1. 185 89.1 1.122 75-1 1-332 79.8 1-253 84.5 1.183 89.2 1. 121 75.2 1-330 79-9 1-252 84.6 1.182 89-3 1.120 75-3 1.328 80.0 1.250 84.7 i.i8[ 89.4 1.119 75-4 1.326 80.1 1.248 84.8 1.179 89-5 1.117 75-5 1-325 80.2 1.247 84.9 1.178 89.6 1. 116 75-6 1-323 80.3 1-245 85.0 1. 176 89-7 1. 115 75-7 1.321 80.4 1-244 85.1 I-I75 89.8 1. 114 75-8 1-319 805 1.242 85.2 1-174 89.9 1. 112 75-9 1.318 80.6 1. 241 85-3 1. 172 90.0 I. Ill 76.0 1-316 80.7 1-239 854 1. 171 90.1 1. 110 76.1 1-314 80.8 1.238 85-5 1.170 90.2 1.109 76.2 1-312 80.9 1.236 85.6 1.168 90.3 1. 107 76.3 1-311 81.0 1-235 85-7 1. 167 90.4 1.106 76.4 1-309 81. 1 1-233 85.8 1.166 90.5 1.105 76.5 1-307 81.2 1.232 85.9 1. 164 90.6 1. 104 76.6 1-305 81.3 1.230 86.0 1. 163 90.7 1.103 76.7 1.304 81.4 1.229 86.1 1.161 90.8 l.IOl 75.8 1.302 81.5 r.227 86.2 1.160 90.9 I.IOO 76.9 1.300 81.6 1.225 f^3 1.159 91.0 1.099 77.0 1-299 81.7 1.224 86.4 1. 157 91.1 1.098 77.1 1.297 81.8 1.222 86.5 1. 156 91.2 1.096 77.2 1-295 81.9 1. 221 86.6 1.155 91.3 1-095 77-3 1-294 82.0 1.220 86.7 1. 153 91.4 1.094 77-4 1.292 82.1 1. 218 86.8 1.152 91.5 1.093 77-5 1.290 82.2 1. 217 86.9 1. 151 91.6 1.092 77.6 1.289 82.3 1.215 87.0 1.149 91-7 1.091 77-7 1.287 82.4 1. 214 87.1 1. 148 91.8 1.089 77.8 1.285 82.5 1. 212 87.2 1.147 91.9 1.088 77-9 1.284 82.6 1. 211 87.3 1-145 92.0 1.087 78.0 1.282 82.7 1.209 87.4 1.144 92.1 1.086 78.1 1.280 82.8 1.208 87.5 1-143 92.2 1.085 78.2 1.279 82.9 1.206 87.6 1.142 92.3 1.083 78.3 1.277 83.0 1.205 87.7 1. 140 92.4 1.082 378 soil, FERTILITY AND FERTILIZERS TABtE.— ( Concluded) E &- £ &- £ &- i «s .-■o 2n ,.■0 Sf ■«'0 K 3 -.■o s ^ •SS c ^ " s •oE gs •SE *- a. n U 11 u n n h & m Ph B. 0. 0. B. 92-5 i.oSi 94-4 1-059 963 1.038 98.2 1.018 92.6 1.080 94-5 1.058 96.4 1-037 98-3 1.017 92.7 1.079 94.6 I -057 96-5 1.036 98.4 1.016 92.8 1.078 94-7 1.056 96.6 1-035 98-5 1.015 92.9 1.076 94.8 1-055 96.7 1034 98.6 1.014 93-0 I -075 94.9 1054 96.8 1-033 98.7 1.013 93-1 1.074 95 -o 1-053 96.9 1.032 98.8 1.012 93-2 1-073 95-1 1.052 97-0 1.031 98.9 i.oir 93-3 1.072 95-2 1.050 97.1 1.030 99.0 l.OIC 93-4 1.071 95-3 1.049 97.2 1.029 99.1 1.009 93-5 1.070 95-4 1.048 97.3 1.028 99.2 i.oo8 93-6 1.068 95-5 1.047 97-4 1.027 99-3 1.007 93-7 1.067 95-6 1.046 97-5 1.026 994 1.006 93-8 1.066 95-7 1.045 97.6 1.025 99-5 1.005 93-9 1.065 95-8 1.044 97-7 1.024 99.6 1.004 94.0 1.064 95-9 1-043 97-8 1.022 99-7 1.003 94.1 1.063 96.0 1.042 97-9 I.021 99.8 1.002 94.2 1.062 96.1 1.041 98.0 1.020 99-9 1. 001 94-3 1.060 96.2 1.040 98.1 1.019 lOO.O 1. 000 APPENDIX. THE AGRICULTUKAL EXPERIMENT STATIONS. Alabama — College Station : Auburn. Canebrake Station : Uniontown. Tuskegee Station : Tusbegee Insti- tute. Alaska — Sitka. Arizona — Tucson. Arkan s as — Fayetteville. California — Berkeley. Colorada — Fort Collins. Connecticut — State Station : New Haven. Storrs Station : Storrs. Delaware — Newark. Florida — Gainesville. Georgia — Experivtent. Guam — Island of Guam. Hawaii — Federal Station : Honolulu. Sugar Planters' Station : Honolulu. Idaho — Moscow. Illinois — Urbana. Indiana — Lafayette. Iowa — Ames. Kansas — Manhattan. Kentucky — Lexington. Louisiana — State Station : Baton Rouge. Sugar Station : Audubon Park, New Orleans. North Louisiana Station : Calhoun. Rice Experiment Station : Crow- ley. Maine — Orono. Maryland — College Park. Massachusetts — Amherst. Michigan — Bast Lansing. Minnesota — University Farm, St. Paul. Mississippi — Agricultural College. Missouri — College Station : Columbia. Fruit Station : Mountain Grove. Montana — Bozeman. Nebraska — Lincoln. Nevada — Reno. New Hampshire— Uwr/iam. New Jersey — New Brunswick. New Mexico — Agricultural College. New York — State Station : Geneva. Cornell Station : Ithaca. North Carolina — College Station : West Raleigh. State Station : Raleigh. North Dakota— Agricultural Col- lege. Ohio — Wooster. Oklahoma — Stillwater. Oregon — CorvalHs. Pennsylvania — State College. State College: Institute of Animal Nutrition. Porto Rico — Mayaguez. Rhode \s,^a-sxd— Kingston. South Carolina— C/^mwom College. South Dakota — Brookings. T^NHtssTiZ—Knoxville. Texas — College Station. Utah — Logan. Vermont — Burlington. Virginia — Blacksburg. Norfolk: Truck Station. Washington — Pullman. West Virginia — Morgantown'. Wisconsin — Madison. Wyoming — Laramie. 380 SOIL FERTILITY AND FERTILIZERS How to Collect an Exhibit of Fertilizer Materials. If the teacher wishes to make this subject more interesting an elaborate exhibit of the different fertiHzer materials and mixed fertilizers should be secured. The mixed fertilizefs may be obtained on the local market during late winter or early spring, or perhaps from your state chemist. For special ma- terials you may be able to obtain them from the following ad- dresses. When you write for any of these materials, state that you wish to use them in class work. The farmer or consumer cannot expect to receive a collection of these materials. Stassfurt potash salts, German Kali Works, 93 Nassau St., New York City. Nitrate of soda. Nitrate Agencies Co., 64 Stone St., New York City. Calcium cyanamid, American Calcium Cyanamid Co., Baltimore, Md. Sulphate of ammonia, American Coal Products Co., New York City. Cotton-seed meal, American Cotton Oil Co., New York City. Linseed meal, American Linseed Co., Chicago, 111. Acid phosphate, from any Fertilizer Co. Rock phosphate, (Florida land pebble). The Phosphate Mining Co., 92 Williams St., New York City. Rock phosphate, (Florida hard rock), Camp Phosphate Co., Ocala, Florida. Rock phosphate, (Tennessee), Tennessee Blue Rock Phosphate Co., Mt. Pleasant, Tenn. Rock phosphate, (Tennessee), Williams Phosphate Co., Mt. Pleasant, Tenn. Basic slag and Peruvian Guano, Coe-Mortimer Co., New York City. Tankage and Bone Products, Swift and Co., or Armour and Co., Chicago, 111. Blood, Armour and Co., Chicago, 111. Azotin, J. B. Sardy, Chicago, 111. Bone-black, American Agricultural Chemical Co., New York City. Carbonate of potash, Peters, White and Co., New York City. Concentrated superphosphate, Virginia-Carolina, Chemical Co., Rich- mond, Va. Concentrated tankage. Heller, Hirsh & Co., New York City. APPENDIX 381 Dried fish scrap, White & Co., Baltimore, Md. Garbage tankage. Heller, Hirsh & Co., New York City. Ground tobacco stems and dust, Kentucky Tobacco Product Co., Louis- ville, Ky. Hair, all kinds. White and Co., Baltimore, Md. Hoof meal and peat, J. B. Sardy, Chicago, 111. Pyrites, Naylor & Co., New York City. Potassium nitrate; obtain this in a general store, or at a drug store. Whale guano, Hollingshurst & Co., New York City. Foreign imported materials, H. J. Baker & Bro., William St., New York City, or, E. J. Walter Co., Baltimore, Md. It must be understood that there are several parties who handle fertilizer materials and if you are unable to secure what you de- sire by writing to the one mentioned here, kindly ask the concern you write, to furnish you with some addresses of people who are liable to have the desired material or materials in stock. The following table, the work of American and foreign in- vestigators will acquaint the student with the fertilizer constit- tients in feed stuffs : 382 SOIL FERTILITY AND FERTILIZERS Fertilizing Constituents in A.merican Feed Stuffs Name of feed Water Ash Nitrogen per cent. per cent percent 14.30 2.48 1. 51 8.00 .S.40 1.60 6. 98 6. IS 3.05 75 o' 1.00 0.89 14.10 3.40 1.63 14.10 2.00 1.44 14.70 1.40 i.l8 10.88 1.53 1.82 9.10 1.30 1.63 S.96 1.50 1.41 10.30 3.50 3.13 9.90 6.82 6.64 14.80 3.20 3-33 8.00 1.70 4.50 9.20 4.20 3-61 9.70 4.30 3.'8 12.20 0.60 1.89 12.00 2.00 2.89 8.10 1.30 2.65 8.59 0.73 5.03 8.50 1.70 3-84 5.80 2.80 4.98 11.10 2.50 1.63 11.00 2.50 1.66 11.30 3.80 4.07 8.88 6.08 5.43 7-77 5-37 5.78 10.38 5.72 3-55 14.00 3-30 2.04 20.80 10.60 1.46 22.40 9.30 0.47 11.00 3.00 2.06 650 6.90 2.16 7.70 3.70 1.72 7.90 2.00 2.35 10.70 4.90 7.56 10.50 2.60 308 10.00 7.90 4.96 12.80 0.70 1.08 9.90 13.00 0.71 10.30 3.50 1.97 11.60 1.90 1.76 11.60 4.60 2.32 9.30 590 1.84 10.80 4.70 5-30 12.80 2.10 1.48 8.60 2.60 2.28 10.80 6.70 5.55 Phosphoric acid per cent. Potassium oxide per cent. Concentrates Barley Beet pulp (dried ) Brewers' grains (dried) Brewers' grains (wet) Broom corn seed Buckwheat Buckwheat middlings Corn (grain) Corn bran Corn and cob meal Cotton-seed (raw) Cotton-seed meal Cowpea seed Distillers' dried grains Flax-seed Flour (dark feeding) Flour (high grade) Flour ( low grade } Germ meal Gluten meal ■ Gluten feed ■ Grano-gluten Hominy chops Hominy meal Horse bean Unseed meal (old process) Linseed meal ( new process) Malt sprouts Millet seed Molasses (beet) Molasses (cane, blackstrap) Oats Oat dust Oat feed (shorts) Oat meal Peanut meal Peas Rape-seed meal Rice (clean) Rice brail (impure) Rice polish Rye Rye bran Rye shorts Soja.(soy) bean Sorghum seed Sun flower seed Sunflower seed cake 0.79 0.16 1.26 0.31 0.44 0.68 0.70 1.21 0.57 1.27 2.68 0.61 1-39 2.14 0.22 0.56 0.80 033 o 41 0.51 0.98 1.25 1.20 1.66 1.83 1-43 0.85 0.05 0.14 0.82 0.91 1.31 0.82 2.00 0.18 0.29 0.30 0.82 2.28 1.26 1.87 0.81 1.22 2.15 0.53 1.50 0.99 1.30 0.09 0.24 0.71 0.54 1.40 0.81 1.99 0.42 0.56 1. 17 APPENDIX 383 FERTiLtztNG Constituents in American Feed Stuffs. — {Continued) Name of feed Water per cent. Ash per cent. NitroRen per cent. Phosphoric acid per cent. Potassium oxide per cent. Concentrates— ( Continued ) Wheat (grain ) Wheat bran Wheat middlings Wheat screenings Wheat shorts Waste Products (low grade) Buckwheat hulls Corn cob Cotton-seed hulls Oat hulls Rice hulls Green Fodders Alfalfa Apple pomace silage Canada field pea Clover (alsike) Clover (red) Clover (scarlet) Clover (white) Corn silage Corn and soy bean silage Cowpea Flat pea Horse bean Italian rye grass Lupine (white) Lupine (yellow) Millet (common) Millet ( Hungarian grass) Millet (Japanese) Millet (silage"! Millet and soy bean silage. - Oat fodder Oats and vetch ( i-i ) Orchard grass Pasture gra.sses ( mixed ) Perennial rye grass Prickly comfrey Rape Rye fodder Serradella Soja (soy I bean Sorghum fodder Timothy Vetch (common ) Hay and Dry Coarse Fod DERS Alfalfa 10.50 1 1. go 12.10 11.60 11.80 13.20 10.70 II. 10 7-30 9.00 75-3° 75.00 85.00 81.80 80.00 82.50 81.00 79.10 76.00 78.81 71.60 84.20 74.S5 85-3S 83-15 62.58 71 10 80.00 74.00 79.00 «3 36 80.00 73- '4 63.12 75.20 84.36 85.00 76.60 82.59 75. to 79.40 66 90 84.50 8.40 1.80 6.30 3-30 2.90 4.60 2.20 1.40 2.80 6.60 18.30 2.25 1.05 1.20 1-47 '•45 1.42 1.40 2.40 1.47 1-93 0.96 1.20 1.70 1. 10 2.80 i-3i 1.80 2.09 327 2.60 2.45 2. 10 1.82 2.60 l.IO 2-15 1.94 7.40 2.36 2.67 2.63 2.44 2.82 0.49 0.50 0.69 0.52 0.58 0.72 0.32 0.50 0.44 0.53 0.43 0.56 0.28 0.79 0.27 I-I3 0.68 0.54 0.44 0.51 0.61 O..S9 0.53 0.26 0.42 0.49 0-43 0.43 0.91 0.47 0.42 0.34 0.33 0.41 0.29 0.23 0.48 0.59 2.19 0.79 2.89 0.95 1. 17 1-35 0.07 0.06 0.25 0.24 0.17 0.13 0.15 0.12 o. II 0.13 0.13 0.20 0.1 1 0.42 O.IO 0.18 0-33 0.29 0.35 0.1 1 0.19 0.16 0.20 0.14 o. II 0.13 0.14 0.16 0.23 0.28 0.1 1 O.IO 015 0.14 0.15 0.09 0.26 1. 19 0.51 0.50 1. 61 0.63 0.84 0.59 0.52 0.60 1.02 0.52 0.14 0.56 0.40 0.38 0.20 0.46 0.49 o 24 037 0.44 0.31 0.5S 1-37 1. 14 '■73 0.15 0.41 0.55 0-.34 0.62 0.44 0.38 0.30 0.76 0.75 1. 10 0.75 0.78 0.73 U.42 0-53 0.23 0.76 0.70 1.68 384 SOIL FERTILITY AND FERTILIZERS Fertilizing Constituents in American Feed Stuffs.— (Conitn tied ) Name of feed Water per cent. Ash per cent. Nitrogen per cent Phosphoric acid per cent. Potassium oxide per cent. Hay AND Dry Coarse Fod DERS— (Continued) Branch grass Broom corn stalks (waste) ■ ■ . Blue melilot Carrot tops (dry) Clover (alsike) Clover (Bokhara) Clover (crimson) Clover (mammoth red) Clover (red ) Clover (white) Corn fodder (with ears) Corn fodder (without ears) .. English hay (mixed grasses) - Fox grass Italian rye grass Japanese buckwheat Kentucky blue grass Meadow fescue grass Meadow foxtail Millet ( common ) Millet ( Hungarian grass ) Millet (Japanese) Mixed grasses Oat fodder Orchard grass Oxeye daisy Perennial rye grass Red top Rowen ( mixed ) Sainfoin Serradella Spanish moss Soybean (whole plant) Sulla Tall meadow oat grass Teosinte Timothy Vetch and oats ( i-i ) White daisy Straw Barley straw Barley chaff Millet straw Oac straw Rye straw Soja bean 16.00 10.00 8.22 9.76 9-94 7-43 9.60 1500 15-00 7.85 9.12 14.00 16.00 8.71 572 lo..^5 8.89 15.35 9-75 7.69 10.45 11.99 15.00 8. 84 965 9- '3 7.71 16.60 12.17 7-39 1500 H.30 9-39 15.35 6.06 13.20 1.5.00 10.30 14.20 13.08 15.00 9.20 7.10 10.10 6.40 5.80 5.10 3.20 5.80 1.06 0.87 l.q2 3.13 2.34 1.98 2.05 2.14 2.07 2-75 1.76 1.04 1-34 1.18 1. 19 1.63 1.19 0.99 1.54 1.28 1.20 I. II 1. 41 1.90 1-31 0.28 1.23 1. 15 i.6i 2.63 2.70 0.61 2.32 2.46 1. 16 1.46 1.26 1.80 0.26 1. 31 l.OI 0.68 0.62 0.46 1.75 0.19 0.47 0.54 0.61 0.67 0.56 0.40 0.52 0.48 0.52 0.54 0.29 0.32 0.18 0.56 0.85 0.40 0.40 0.44 0.49 0.35 0.40 0.27 0.65 0.41 0.44 0.56 0.36 0.43 0.76 0.78 0.07 0.67 0.4s 032 0.55 0.53 0.60 0.41 0.30 0.27 0.18 0.20 0.28 0.40 0.87 1.87 2.80 4.88 2.23 1.83 1-3' 1.80 2.20 1. 81 0.89 1.40 1. 61 0.95 1.27 3-32 1-57 2.10 1.99 1.69 1.30 1.22 1-55 1.90 1.88 1.25 1-55 1.02 1.49 2.02 0.65 0.56 1.08 2.09 1.72 3.70 0.90 1.27 1. 18 2.09 0.99 1.73 1.24 0.79 1-32 APPENDIX 385 Fertilizing Constituents in American Feed Stuffs. — (Continued) Name of feed Water per cent, Ash per cent. Nitrogen per cent. Phosphoric acid per cent Potassium oxide per cent. Straw— (Continued) Wheat straw Wheat chaff Roots, Tubers, Etc. Artichoke Beet ( mangel ) Beet (red) Beet ( sugar) Beet (yellow fodder) . . . Carrot Mangold Parsnip Potato (Irish) Radish (Japanese) Rutabaga Turnip (flat) Dairy Products Butter Buttermilk Colostrum (cows' milk) Skim milk ^centrifugal) Skim milk (gravity) . . . Whey Whole milk Miscellaneous Apples Cabbage Dried blood Dried fish Meat scrap Pumpkin (garden) Spurry Sugar beet leaves 9.60 14.30 78.00 90.9 88.50 86.50 89.00 88.60 88.00 86.30 78.90 93.00 88.60 90.50 12.50 90.10 74.60 90.60 90.40 93.80 87.20 78.00 90.50 8.50 10.80 10.70 86.80 75.60 88.00 4.20 9.20 1. 00 l.io 1. 00 0.90 1.20 0.70 1. 00 1.20 0.80 0.70 I 50 0.70 o 70 0.40 0.60 1.40 4.70 29.20 4.10 0.90 4.00 2.40 0.59 0.79 0.26 0.19 0.24 0.22 0.23 0.15 0.15 0.18 0.21 0.08 0.19 0.18 0.19 0.48 2.82 0.56 0.56 0.15 0.53 0.12 0.3S 13-50 7-75 1J.39 0.1 1 0.38 0.41 0.12 0.70 0.14 0.09 0.09 o.io o. n 0.09 0.14 0.20 0.07 0.05 0.12 O.IO 0.17 0.66 0.20 0.20 0.14 0.19 O.OI O. II 1-35 12.00 0.70 0.16 0.25 0.15 0.51 0.42 0.47 0.38 0.44 0.48 0.56 0-5I 0-34 0.44 0.29 0.40 0.49 0-39 0.16 O.II 0.19 0.19 0.18 0.18 0.17 0-43 0.77 0.20 0.10 0.09 0-59 0.62 NOTES. 1. Bowker, Plant-Food. 2. Heni-y, Feeds and Feeding. 3. Clark, Bulletin Philos. Soc, Washington, XI, 227, from Ingle, Manual of Agricultural Chemistry. 4. Hinrichs, Conipt. Rend., 1900, 131, 442, from Ingle, Manual of Agricultural Chemistry. 5. Halligan, Elementary Treatise on Stock Feeds and Feeding. 6. Stockbridge, Rocks and Soils. 7. Jordan, The Feeding of Animals. 8. Bulletin 201, Ohio Experiment Station. 9. Hall, Fertilizers and Manures. 10. Bulletin 91, Louisiana Experiment Station. 11. Fletcher, Soils. 12. Bulletin 47, Minnesota Experiment Station. 13. Lyon and Fippin, Soils. 14. Hall, from Whitson, Notes on Soils. 15. Loughbridge, from Lyon and Fippin, Soils. 16. Hall, The Soil. 17. Roberts, The Fertility of the Soil. 18. Snyder, Soils and Fertilizers. 19. Hopkins, Soil Fertility and Permanent Agriculture. 20. Bulletin 53, Minnesota Experiment Station. 21. Bulletin 89, Minnesota Experiment Station. 22. Bulletin 1 10, Ohio Experiment Station. 23. Yearbook, 1895, United States Department of Agriculture. 24. Aikman, Manures and Manuring. 25. Morton's Cyclopedia of Agriculture, Vol. II. 26. Made by the author. 27. Deherain, from Hall, Fertilizers and Manures. 28. Cornell Experiment Station. 29. Yearbook, 1908, United States Department of Agriculture. 30. Lanborn, Cotton-Seed Products. 31. American Fertilizer. 32. American Fertilizer Handbook, 1910. 33. Chile of To-Day. 34. Report, 1894, Connecticut Experiment Station. NOTES 387 35. Report, 1896, Connecticut Experiment Station. 36. Journal of Industrial and Engineering Chemistry, July, 1910. 37. Annual Report, 1899-1900, Pennsylvania State College. 38. Griffiths, Treatise on Manures. 39. Wiley, Principles and Practice of Agricultural Analysis, Vol. II. 40. Basic Slag and Its Uses, 1906. 41. Bulletin 100, Ohio Experiment Station. 42. Bulletin 68, Maryland Experiment Station. 43. Farmers' Bulletin 77, United States Department of Agriculture. 44. Bulletin 13, Florida Experiment Station. 45. Fourteenth Annual Report, Hatch Experiment Station. 46. Voorhees, First Principles of Agriculture, from Voorhees, Fertilizers. 47. Journal of the Franklin Institute. 48. Journal of the American Chemical Society. 49. Bulletin of the Chemical Society of Paris, from Wiley, Principles and Practice of Agricultural Analysis, Vol. II. 50. Bulletin 1 14, Rhode Island Experiment Station. 5r. Bulletin Ij8, Rhode Island Experiment Station. 52. Potash, German Kali Syndicate, igo6, from Wiley, Principles and Practice of Agricultural Analysis, Vol. II. 53. Annual Report, 1888, Hatch Experiment Station. 54. Annual Report, 1889, Connecticut Experiment Station. 55. Connecticut Experiment Station. 56. Annual Report, 1902, Hatch Experiment Station. 57. Storer, Agriculture, Vol. I. 58. Bulletin 2r, Rhode Island Experiment Station. 59. Voorhees, Fertilizers. 60. Bulletin 119, Hatch Experiment Station. 61. Bulletin 163, Connecticut Experiment Station. 62. Bulletin 124, New Jersey Experiment Station. 63. Wolff and Lehmann. 64. Handbook of Experiment Station Work. 65. Bulletin 28, Office of Public Roads. 66. Bulletin 129, Rhode Island Experiment Station. 67. Bulletin 104, Bureau of Plant Industry, United States Department of Agriculture. 68. Storer, Agriculture. 69. Bulletin 30, Minnesota Experiment Station. 26 588 SOIL FERTILITY AND FERTILIZERS 70. Bulletin 163, Connecticut Experiment Station. 71. Annual Report, 1895, Rhode Island Experiment Station. 72. Annual Report, 1896, Rhode Island Experiment Station. 73. Annual Report, i8g8, Rhode Island Experiment Station. 74. United States Census Report. 75. Florida Experiment Station. 76. Connecticut Experiment Station Report. 77. Bulletin 99, Vermont Experiment Station. 78. Bulletin 49, Georgia Department of Agriculture. 79. Bulletin 143, Vermont Experiment Station. 80. Bulletin 140, Kentucky Experiment Station. Si. Bulletin 41, Georgia Department of Agriculture. 82. Annual Report, 1906, Connecticut Experiment Station. 83. Bulletin 46, Georgia Department of Agriculture. 84. Bulletin 49, Georgia Department of Agriculture. 85. Bulletin 113, Louisiana Experiment Station. 86. Bulletin 96, Texas Experiment Station. 87. Farmers' Bulletin 388, United States Department of Agriculture. 88. Bulletin 169, Kansas Experiment Station. INDEX. Acid phosphate, 147; color of, 158; manufacture of, 147, 148, 149. Acidity of soils, 231, 239; how to find out when soils are acid, 231. Acidity of upland soils, 238, 239, 240, 241, 242, 243. Acids and bases, 13. Adulteration of fertilizers, defini- tion of, 268. Aerobic fermentation, 65. Agricultural experiment stations, 379. Agricultural salt, 224. Agricultural values of fertilizers, 277. Air, composition of, 6. Air slaked lime, 228, 231. Aluminum, 5. Ammonium chloride, 227. Ammonium nitrate, 221. Ammonium sulphate, 87 ; composi- tion and availability of, 91 ; manufacture of, 87, 88, 89, 90- Anaerobic fermentation, 66. Apatite, Canadian, 139. Apple, fertilizer formula for, 367, 368. Apricot, fertilizer formula for, 369. Ashes, see wood ashes, coal ashes, etc. Ash in plants, 12, 13, 14, 15, 16; per cent, of in vegetable sub- stances, 15. Asparagus, fertilizer formula for, 361. Available phosphoric acid, 155. Avocado pear, fertilizer formula for, 372. Azotin, 82. Bacteria, number in soil, 31 ; aero- bic and anaerobic, 65, (A. Banana, fertilizer formula for, 371. Barberries, fertilizer formula for, 370. Basic slag, 140, 141, 142; phosphate, 14s, 146. Bat guano, 87; analyses of, 60. Beans, fertilizer formula for, 361. Bedding for litter, 54; absorptive power of, 55 ; kind and amount used, 54. Beet molasses ash, 198. Beet refuse, 105, 114. Beets, fertilizer formula for, 362. Blackberries, fertilizer formula for, 370. Blood, dried, 80. Bone-ash, 126. Bone-black, 125, 126. Bone-dust, 125. Bone-meal, raw, 123, 125 ; steamed, 124, 125. Bone phosphates, 144. Bone tankage, 127. Bones, 123 ; mechanical composition of, 125. Brand and trade names of fer- tilizers, 326. Brick kiln ashes, 219. Brussel sprouts, fertilizer formula for, 362. Cabbage, fertilizer formula for, 362. Calcium, 4 ; sulphate of, 149, 244. Calcium cyanamid, 100; composition of, loi ; fertilizing value of, 102 ; properties of, 102. Calcium nitrate, 98; output and value, 99; process of manufac- ture, 98. 390 INDEX Calculation of amounts from known percentages, 318. Calculation of percentages from known amounts, 317. Caliche, 94. Capillary water, 29; amounts of held by soils, 29 ; how to in- crease upward movement of, 30; how to prevent loss of, 29. Carbon, 3. Carbonate of lime, 228, 229. Carbonate of potash, 197. Carbonic acid, 228. Castor pomace, 79. Cauliflower, fertilizer formula for. 362. Celery, fertilizer formula for, 363. Chemical analyses, interpretation of, 275 ; examples of, 275, 276, 277. Chemical elements, i. Chemical symbols, i. Cherries, fertilizer formula for, 369. Chlorine, 5. Coal ashes, 217. Cocoanut, fertilizer formula for, 372. Commercial fertilizers, chapter on, 250; approximate output of fertilizer factories, 255 ; basis of purchase, 259; causes for large consumption, 252 ; classi- fication of, 256, 257, 258, 239 ; distribution of by states, 251 : fertilizing materials used by manufacturers, 254; how to lessen use of, 253 ; ton basis, 260; unit system, 259. Commercial values, 278 ; how to calculate, 282. Compost, 207. Conversion factors, 271. Corn, fertilizer formula for, 344 ; for sweet corn, 363. Corn cob ashes, 218. Cotton, fertilizer formula for, 344, 345, 346. Cotton-seed, yield of products from, 78. Cotton-seed hull ashes, 196. Cotton-seed meal, TJ ; commercial classification of, 78, 79 ; com- position of, 78 ; how manufac- tured, "/■] ; value of, 79. Cow manure, 57 ; analysis of, 57, 60. Cucumbers, fertilizer formula for, 362. Currants, fertilizer formula for, 370. Denitrification, 33 ; loss of nitrogen by, 40. Diversification of crops, 42. Double sulphate of potash and mag- nesia, 188. Double superphosphate, 157; com- position of, 159. Drainage, 29: losses from, 36. Drainage waters, composition of, 37, 39. Dry matter, composition of in plants, 10. Duck manure, composition of, 59; produced per year, 60. Egg plant, fertilizer formula for, 363- Elements sometimes lacking in the soil. 21 ; distribution of in earth's crust and air, 5 ; dis- tribution of mineral elements in plants. II ; obtained from air and water, 22 : present usually in sufficient amounts, 21 ; that make up plants, 10. Ensilage, fertilizer formula for, 358. Erosion, 35 ; ways to check, 35, 36. Essential elements. 21 ; replacing of, 22. INDEX 391 Fallowing, 38; losses from, 39. Farm manures, chapter on, 52; amount to apply, 73; amount produced by different kinds of fowl, 60; analyses of, 60; bacteriological effect of, 72 ; benefits grass land, 72 ; care, preservation and use of, 64; commercial value of, 62; com- position of covered and uncov- ered, 69; composition of fresh and rotted, 67 ; composition of gases in heaps of, 66; compost- ing, 67; conditions affecting value of, 52; effect of fresh and exposed manure on crop production, 72 ; effect of during dry seasons, 70, 71 ; effect on kind and amount of bedding used on value of, 54; effect of kind of animal and kind of work on value of, S3 ; effect of on mangolds with other fer- tilizers, 71 ; effect of leaching on, 64, 6s ; effect of nature and amount of feed on 61 ; fer- mentations in, 6s, 66; how to apply, 73 ; how to calculate amount produced, 60; improves the texture of soil, 71 ; influ- ence of age and use of animal on value of, S2 ; keep manure moist, 66; kinds of manure, S2; lasting effect of, 62, 63 ; phys- ical effects of, 69; preserva- tives, 69; prevents mechanical loss by winds, 72 ; produces a better moisture condition, 69 ; store manure under cover, 68 ; time to apply, 72; waste of, 64. Feather waste, los. Feed stuffs, fertilizer constituents in, 382, 383, 384, 385- Feldspar, 221, 222, 223. Fermentations, kinds of, 65, 66. Fertility, loss by exclusive grain farming and stock farming, 49, 50 ; removed by farm produce, 48; restored by some plants, 247. Fertilizers, chapter on, 2So; a few remarks about, chapter on, 326; agricultural values of, 277; amount to use, 339; brand and trade names of, 326; calcula- tions on, 317, 318, 319; cheap grades often demanded, 294; commercial values of, 278 ; comparison of grades of, 302; complete analyses of 30s, 306; cost of different grades, 294; cost as between manufacturers, 301 ; cost from standpoint of cost, 294; cost from standpoint of value, 297 ; deterioration on storage, 333; flower, 212; high, medium and low grade, chapter on, 292; how applied, 337; how to purchase, 329; incompatibles in, 334; is it profitable to use, 338; liquid, 212; production of by packing houses, 82; rebates on, 31S, 316, 317; recipes or patent formulas of, 331 ; sell- ing prices of, 310; tentative definitions of, 268 ; time to apply, 335 ; trade values of, 279; valuation of, chapter on, 275- Fertilizer formulas for crops, chap- ter on, 340. Fertilizer laws, 260; comparison of requirements of, 262 ; model law, 264. Fertilizer materials, low grade, value of, IIS; basis of pur- chase, 259; how to collect an exhibit of, 380; how to mix at 392 INDEX home, 314; how to purchase, 314; sometimes sold on purity, 273; used by manufacturers, 254- Figs, fertilizer formula for, 372. Filler, 292; how to avoid paying freight on, 293. Fillerine, 114. Fish, dry ground, 83, 127. Fish scrap, fresh, 213. Flax, fertilizer formula for, 353. Flower fertilizers, 212. Fowl manure, composition of, 59. Garbage tankage, 107. Gas lime, 243. Geese manure, amount produced per year, 60; composition of, 59- Gooseberries, fertilizer formula for, 370. Grape, fertilizer formula for, 370. Grape fruit, fertilizer formula for, 370. Green manures, 245 ; classes of, 246 ; deep rooted plants val- uable, 249; leguminous crops preferable for, 246; the best time to grow, 249 ; the best time to plow under, 248. Guanos, how deposited, 83; nitro- genous, 83, 84, 85, 86, 87 ; phos- phatic, 143, 144- Guarantee of fertilizers, 270, 271, 272, 273 ; examples of, 273 ; fer- tilizers should reach their guar- antees, 330 ; interpretation of, 270; meaning of, 270; study the guarantee, 329. Guava, fertilizer formula for, 372. Gypsum, 149, 244. Hair and fur waste, 105. Hay and grass crops, fertilizer for- mula for, 359. Hen manure, 59; analysis of, 59, 60. Hog manure, 57, 58 ; analysis of, 58, 60. Home mixtures, chapter on, 308; acquaints the farmer with the materials used, 31 1 ; analyses and valuations of, 313 ; calcu- lations of percentages and amounts in fertilizers, 317, 318; definitions, 308 ; does away with the purchase of unnecessary constituents, 312; examples of, 320 ; manufacturers allow credit, 309 ; manufacturers claims, 308 ; mechanical condition of factory and home mixed fertilizers, 309 ; mixed fertilizers com- pounded for the crop, 309; mixed fertilizers more easily purchased, 309; plant food obtained at a lower price, 309, 310; reasons for and against the use of, 308. Hops, fertilizer formula for, 353 ; spent, 220. Horn and hoof meal, steamed, 82; untreated, 106. Horse manure, 56; analysis of, 56. Huckleberries, fertilizer formula for, 370. Humus, 17 ; effect of rotation on supply of, 46. Hydrated lime, 228, 230. Hydrochloric acid, i. Hydrogen, i. Hygroscopic moisture, 8. Incompatibles in fertilizers, 334. Inorganic matter, 17. Insoluble phosphoric acid, 149. Irish potatoes, fertilizer formula for, 349, 350. Iron, 4. Iron sulphate, 223. INDEX 393 Ivory dust, 219. Japanese persimmons, fertilizer for- mula for, 371. Kainit, 182, 183, 184. King crab, 83, 215. Kumquats, fertilizer formula for, 369. Lawns, fertilizer formula for, 354. Leaching, 64. Leather meal, dissolved, 104; raw, 104; treated, 104, 114. Leather scrap ashes, 219. Leaves for bedding, 54; composi- tion of, 54. Legumes, fertilizer formula for, 356. Lemons, fertilizer formula for, 369. Lettuce, fertilizer formula for, 362. Lime, 228; amount in soils, 236; amount to apply, 233 ; amount removed by crops, 235; car- bonate of, 228; decreases many fungus diseases, 238; experi- ments with, 232, 233, 238, 239, 240, 241, 242, 243; forms of, 228; form to use, 232; how to apply, 232 ; how to find out when soils need lime, 231 ; mechanical action of, 236; phosphates of, 149; renders plant food available, 237; re- sults with legumes, 234. Limestone, 229, 230. Lime-kiln ashes, 217. Linseed meal, old and new process, 79- Lobster shells, 214. Loquats, fertilizer formula for, 369. Liquid fertilizers, 212. Magnesium, 5 ; carbonate of, 227 ; sulphate of, 225. Manganese, 5; salts of, 227. Manures, pulverized, 213 ; see farm manures. Marl, 210. Meat meal, 82. Melons, fertilizer formula for, 362, 363- Mineral elements in plants, distri- bution of, II; occurrence of, 16; per cent, of in vegetable substances, 15. Miscellaneous fertilizer materials, chapter on, 207. Model fertilizer law, 264; com- ments on, 266. Mora meal, 105, 114. Muck, 107. Muriate of potash, 186. Mussels, 214. Nitrate of soda, 92, 93; composi- tion and properties of, 96; deposits and shipments of, 93, 94- Nitrification, 31, 32, 33. Nitrogen, 2 ; amounts lost on bare soils and wheat land, 39; amounts removed by crops, 38, 120; amount secured from air, 248; available, 108, 109, no, III, 112, 113; excessive nitro- gen invites disease, 122; for large crops and building up the soil, 117; for soils well sup- plied and long growing crops, 117; forms of, 75, 76; func- tions of, 119; how lost from the soil, 36, 37, 38, 39, 4o; organisms that gather, 2, 34; the fixation of, 248; utilization of from air, 98; value of in increasing wheat yields, 121. Nitrogen cycle in the soil, 32. Nitrogenous materials, high grade, chapter on, 75 ; low grade, chapter on, 104; availabihty of, 107, 113; composition of, 103; field experiments with, 108; 394 INDEX for immediate results, 117; kinds to use, 116; statistics of, 118, 119; use of low grade increasing, 116; value of low grade, 115; vegetation and laboratory experiments with, 108, 109, no. III, 112, 113. Odorless phosphate, see basic slag. Olives, fertilizer formula for, 372. One crop farming, effect on fer- tility, 40, 41. Onions, fertilizer formula for, 364. Onion sets, fertilizer formula for, 364. Oranges, fertilizer formula for, 369. Organic matter, 17. Organic nitrogen, 75, 76. Oxygen, 2. Pasturage, fertilizer formula for, 359. Patent formulas, 331. Peaches, fertilizer formula for, 368, 369. Peanuts, fertilizer formula for, 353. Pears, fertilizer formula for, 367, 368. Peas, fertilizer formula for, 361. Peat, 107 ; for bedding, 55 ; absorp- tion of, ss; dried, 211. Pecan, fertilizer formula for, 372. Phosphates, chapter on, 123; amounts of acid to dissolve, 152; amount used for manu- facturing, 159; availability of, 14s ; available deposits of, 133 ; classification of, 144; degree of fineness, 146; development and production of, 133 ; estimated life of, 133 ; field experiments with nine phosphates on limed and unlimed plots, 167 to 177; how they occur, 123 ; influence of soil on availability of, 145 ; Florida phosphates, 136; for- eign, 134; foreign shipments of, 131 ; form to use and kind to use, 145; mineral, 128; organic, 123; production of, 129, 130; South Carolina phos- phates, 13s ; Tennessee phos- phates, 137, 138; utilization of, 134; Western deposits of, 131; world's production of, 132. Phosphatic fertilizers, crop returns from, 166, 167. Phosphoric acid, 147 ; absorption of, 163 ; amount in soils, 160 ; amount removed by crops, 160, 161 ; available, 155 ; difference between phosphates and super- phosphates, 154; difference of the forms of in superphos- phates, 156; effect of on barley, 164; effect of on wheat, 165; fixation of, 162 ; functions of, 164 ; insoluble, 149 ; loss of, 40 ; reversion of, 153; reverted, 150 ; soluble, 149; value of reverted, 153- Phosphorus, 4. Physiological water, 8. Pigeon manure, composition of, 59; amount produced per year, 60. Plant food, amount available in soils, 21 ; amount in American soils from different States, 18: amount removed by crops, 19. Plants, acids and bases in, 13; amounts of water used by, 8; ash in, 12, 13, 14, 15, 16; ash of young and mature, 16 ; com- position of, 7, 10; distribution of ash in, 16; dry matter of, 9; elements that make up, 13 ; food of, 7 ; how benefitted by open soils, 28 ; how they feed, 7 ; must have room, 28 ; occur- rence of mineral elements in. INDEX 395 1 6 require oxygen, 28; salts in, 13 ; variation of ash in, 13, 14, IS ; variation of water in, 8 ; water in young and mature, 9. Plums, fertilizer formula for, 368. Pineapple, fertilizer for, 371. Potash, amounts removed by crops, igg, 200; benefits legumes, 204; chloride of, 186; discovery of, 182; effects maturity, 206; effects the leaves, 205 ; favors carbohydrate formation, 204 ; favors seed and straw forma- tion, 20s ; fixation of, 203 ; forms of, 199; from organic sources, 192 ; functions of, 203 ; helps to neutralize plant acids, 206; in soils, 199; loss of, 40; sometimes checks insect pests and plant diseases, 206; sul- phate of, 188. Potash fertilizers, chapter on, 178; materials used in, 198. Potash-magnesia carbonate, 189. Potash manure, high grade, 114. Potash manure salts, 189. Potash salts, 182; composition of, 190; crop producing value of, 201, 202, 203 ; importations of, 191 ; production of, 191. Potassium, 3. Potassium nitrate, 221. Powder waste, 225. Preservatives for farrti manures, 69. Pulverized manures, 213. Pumpkins, fertilizer formula for, 364- Quick-lime, 228. Radishes, fertilizer formula for, 364. Rape, fertilizer formula for, 358; meal of, 80. Raspberries, fertilizer formula for, 370. Rebates on fertilizers, 315, 316, 317. Reverted phosphoric acid, 150. Rice hull ashes, 218. Rock phosphates, 128. Rodunda phosphate, 139. Roots, fertilizer formula for, 359. Rotations, advantages of, 42; con- serves moisture, 49 ; definitions of, 42 ; effects of on humus supply, 46; furnishes a regular income, 44; furnishes feed for live-stock, 44; helps check insect and plant diseases, 44; helps distribute farm labor, 44; keeps down weeds, 43 ; legumes profitable in, 43 ; make up of, 42; practiced in different sec- tions of the United States, 47; prevents losses of fertility, 45 ; regulates humus supply, 46; saves fertilizer expenditure, 46; utilization of deep and shallow rooted plants, 45; utilizes plant food more evenly, 45. Rhubarb, fertilizer formula for, 361. Salt, common, 224, 225. Salts in plants, 13. Sawdust and shavings for bedding, 54, ss ; absorptive power of sawdust, 55 : composition of, 55. Scullions, fertilizer formula for, 364. Scutch, 106. Seaweed, 208, 209. Sewage, 215, 216. Sewage sludge, 216, 217. Sheep manure, 58 ; analysis of, 59, 60. Shoddies, etc., 106. Shrimp waste, 215. Silicate of potash, 221, 222, 223. 396 INDEX Silicon, 4. Slaked lime, 228. Sodium, 5 ; chloride of, 224 ; sul- phate of, 225, 226, 227. Soil fertility, chapter on, 17; fac- tors influencing, 17; limiting factors in, 23 ; loss by one crop farming, 40, 41 ; loss by system of farming, 49, 50; maintain- ing, chapter on, 35 ; revolving fund of, 18. Soil grains, surface area of, 26. Soiling crops, 355; scheme of, 357, 358. Soils, biological condition of, 30; cracking of, 2T, composition of, 17; from different states, 18; how to determine require- ments of, 320; how soil may be analyzed by the farmer, 322 ; inoculation of, 34; lumpy, 2T, mechanical composition of, 25 ; movement of water in, 29, 30 ; nitrogen cycle in, 32 ; percent- age of water in effected by manure, 69, 70 ; plant food sup- ply of, 18, 19, 20; puddling of, 28 ; physical condition of, 23 ; relation of chemical and me- chanical composition of, 27; temperature of, 23, 24, 25 ; thawing and freezing of, 28. Soluble organic nitrogen, 114. Soluble phosphoric acid, 149. Soot, 220. Sorghum, fertilizer formula for, 352. 3SS- Spinach, fertilizer formula for, 363. Squash, fertilizer formula for, 364. Stable manure mixed, composition of, 60. Straw as bedding, 54; absorptive power of, 55 : amount necessary to absorb liquid portion of horse manure, 56; composition of, 54- Strawberries, fertilizer formlua for, 36s. Street sweepings, 221. Sugar beet, fertilizer formula for, 352. Sugar cane, fertilizer formula for, 348, 349. Sulphate of potash, 188. Sulphur, 4. Sulphuric acid, 147; manufacture of, 147- Superphosphates, chapter on, 147; composition of, 159; favoritism for bone superphosphates, 157: how to make at home, 159 1 manufacture of, 147, 148 ; names applied to, 154; no free acid in, 158; the difference between phosphates and superphos- phates, 154; the difference of the forms of phosphoric acid in, 149, 150, 151, IS5- Sweet potatoes, fertilizer formula for, 351. Sylvinit, 184. Tan bark ashes, 218. Tankage, 81 ; grades of, 81 ; varia- tion in, 81. Tartar pomace, 114. Thomas phosphate powder, see basic slag. Tobacco, fertilizer formula for, 347, 348. Tobacco stems and stalks, 194, 196. Tomatoes, fertilizer formula for, 363, 364. Total phosphoric acid, 156. Trade values of fertilizers, 279, 280, 281 ; discussion of table of, 284; how obtained, 280. Tubercles, 3. INDEX 397 Turkey manure, amount produced per year, 60. Turnips, fertilizer formula for, 364. Tygert tankage, 115. Unit system of purchase of fer- tilizers, 259. Valuation of fertilizers, chapter on, 27s ; comments on, 284 ; in other states, 289; objections to, 286; show cost of plant food, 285 ; some favor, 288. Values, agricultural and commer- cial, 277, 278, 289, 290, 291 ; trade, 279. Vegetable substances that furnish nitrogen, "jy. Water in plants, 7, 8, 9 ; movement of in soils, 30; percentage of in soils effected by manure, 70. Wine residues, 198. Wood ashes, 193; composition of from different kinds of wood, 195; value of, 194. Wool waste, shoddies, etc., 106; treated, 106. SCIENTIFIC BOOKS PUBLISHED BY THE CHEMICAL PUBLISHING CO., EASTON, PA. BENEDICT— Elementary Organic Analysis. Small 8vo. Pages VI + 82. IS Illustrations $1.00 BERGEY— Handbook of Practical Hygiene. Small Svo. Pages 164.. $1.50 BILTZ — The Practical Methods of Determining Molecular Weights. (Translated by Jones). Small Svo. 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