bABOHAKJl.Y ■ PHYSIC^ ■ OAYTOV rt-^v: I f " ■' ' " ll in il i lllll n ii n w ill i n I a>.- ■ _ ,^__ »m'*mtimmmMimmimm (Qarnell Iniuerattg iCibcary Stifata, Wtta fork Corne« UnWer* ^*«'V The original of tiiis book is in tine Cornell University Library. There are no known copyright restrictions in the United States on the use of the text. http://www.archive.org/details/cu31924031363785 LABORATORY PHYSICS A STUDENT'S MANUAL FOB COLLEGES AND SCIENTIFIC SCHOOLS BY DAYTON CLARENCE MILLER, D.Sc. Pkofessor of Physics in Case School of Applied Science BOSTON, U.S.A. GINN & COMPANY, PUBLISHERS Cl)e Stbensenm preec! 1903 COPYKIGHT, 1903, BY DATTON CLAKENCE MILLER ALL BIGHTS BESEBVED PREFACE This Manual is designed to be a student's handbook for the performance of experimental problems in physics. The selection of problems and their treatment is the result of twelve years of teaching experience, and the descriptions of most of the exercises have been used in typewritten form for the past six years. The grade of work is that of the course in general physics in colleges and technical schools. It is presumed that the student has had a course in preparatory laboratory physics, and that these exer- cises wUl be accompanied, or preceded, by a full course of lec- tures and recitations in general physics, including instruction in the principles and manipulations of the various experimental operations. One hundred and twenty-eight exercises are described. Some of these, however, such as reading the barometer, determining the heat equivalent of a calorimeter, etc., are usually performed in connection with other problems. There is a break in the serial numbers of the exercises at the end of each part, to permit the assignment of numbers to additional exercises in their proper groups. The definite problems given under each heading have been formulated with much care, to cover as wide a range of the subject as is possible. They are based upon the work of the sophomore class in the Case School of Applied Science, and each one represents what may be expected of one or two students in a laboratory exercise of three hours' duration. Shorter exercises, or exercises covered by particular articles, may be conveniently assigned in the manner explained in the Introduction. IV PREFACE The book is not merely a compilation, though oi course most of the exercises have been used and described before. The writer has made free use of all sources of information, sufficient acknowledgment for which will be found in the many refer- ences given. It is thought that several important exercises appear for the first time in a laboratory manual, and that others have been made more efficient by the method of treatment. Among these may be mentioned those concerning the compari- son and calibration of graduated scales, the balance, density by hydrostatic weighing. Reed's method for i?ating a fork, ther- mometry and calibration of thermometers, high-temperature measurements, calorimetry by heating, mechanical equivalent of heat, hygrometry, photometry, spectrometry, concave-grating spectroscope, interferometer, silvering glass, refractometer, capUlary electrometer, and magnetic variometer. In making references the endeavor has been not to refer to original sources but rather to those books which contain infor- mation in the most useful form for the experiments described, and which are most likely to be available to the student. It is believed that the descriptions are ample for the performance of the exercises ; the references indicate where other methods are explained, or where information for advanced work may be found. The writer is greatly indebted to Professor Edward W. Morley for many valuable suggestions in general, and in particular in connection with the balance, the thermometer, and the inter- ferometer. Messrs. H. W. Springsteen, H. S. Hower, S. R. Cook, and J. W. Easton, present or former Instructors in Physics in Case School of Applied Science, have given efficient aid in reading the manuscript and proof sheets of the book. DAYTON C. MILLER. Cleveland, Ohio, July, 1903. CONTENTS PAET I — INTEODUCTION CHAPTER I. GENERAL INSTRUCTIONS PAGB Objects of Laboratory Practice — Available Problems — Equipment — Descriptions of Exercises — Assignment of Exercises — Notes and Records — Reports — Observations, Errors, and Corrections — Prob- able Error — Least Squares — Weighted Observations — Significant Figures — Graphical Methods — Units — Reading Divided Scales . 1 PAET II — MECHANICS CHAPTER n. GENERAL MEASUREMENTS, LENGTH, AND MASS I. Length with the Calipers. Length — The Vernier — The Vernier Caliper — The Micrometer Caliper . . 15 II. Length and Radius of Curvature with the Spherometer. The Spherometer 19 III. Constant of a Micrometer Microscope. The Micrometer Micro- scope .... 20 IV. Length with the Comparator. The Comparator 23 V. Length with the Dividing Engine. The Dividing Engine — Dividing Engine Comparator 25 VI. Circular Arc with the Dividing Engine. Dividing Circles . 27 VII. Errors of a Graduated Scale by Gay-Lussac's Method. Calibration of Graduated Scales — Calibration with a Dividing Engine and One Microscope — Calibration with a Dividing Engine and Two Microscopes — Calibration with a Micrometer- Microscope Comparator 28 VIII. Erboks op a Graduated Scale by Precision Methods. Cali- bration of Scales by Precision Methods 32 IX. Length with the Optical Micrometer. The Optical Micrometer — Three Legged Optical Micrometer — The Reading Telescope 86 X. Constants of a Level with the Level Trier. The Spirit Level 39 v VI CONTENTS , PAGE XI. Areas with the Planimeter. The Planimeter — Mensuration of Areas 42 XII. Angular Distance with the Sextant. The Sextant ... 46 XIII. Laws of the Equilibrium of Forces by the Triangle of Forces. Equilibrium of Forces 49 XIV. Conservation of Momentum with the Ballistic Pendulum. Momentum and Impact 51 XV. Mass by the Equilibrium of Moments. Equilibrium of Moments 54 XVI. Mass with the Balance by the Method of Vibrations and Double Weighing. The Balance — Weighing by Vibrations — Double Weighing and Eatio of Balance Arms — Weighing by the Rider Method — Sensibility of Balance — Practical Hints on the Use of the Balance 55 XVII. Absolute Mass. Weighing by Keversal — Weight in Vacuo . 64 XVIII. Errors of a Set of Weights by Comparison. Calibration of Weights — Adjustment of Weights 66 XIX. Volume by Weighing. Volume by Weighing — Volume and Eadius of a Tube 68 XX. Atmospheric Pressure and Altitudes with the Barometer. The Barometer — Beduction of Barometer Readings — Baro- metric Pressure — The Barye and Standard Pressure — Alti- tudes by the Barometer 69 CHAPTER III. TIME, ACCELERATION, AND GRAVITY XXI. Laws of Accelerated Motion with a Falling Tuning Fork. Time — Accelerated Motion — Acceleration with Variable Time Unit 74 XXII. Laws of Accelerated Motion with Atwood's Machine. Atwood's Machine — Gravity and Inertia of Pulley with Atwood's Machine 77 XXIII. Properties of the Path of a Projectile. The Trajectory . 79 XXIV. Gravity by the Simple Pendulum. Simple Pendulum — Peri- odic Time by the Method of Coincidences 81 XXV. Gravity with the Reversible Pendulum. Kater's Pendu- lum — Formula for the Compound Pendulum — The Chrono- graph — Mendenhall's Optical Method for comparing Two Pendulums 84 XXVI. Gravity by Free Fall. Freely Falling Body — The Tuning- Fork Chronograph — Smoked Paper and Glass 90 CONTENTS Vll CHAPTER IV. ELASTICITY, AND PROPERTIES OF MATTER PAGE XXA'II. Young's Modulus by Stretching. CoeflScients of Elasticity — Young's Modulus and Elastic Limit — Young's Modulus with a Suspended Wire and Scale — Young's Modulus with the Cathetometer — Adjustment of the Cathetometer . . 93 XXVIII. Modulus of Elasticity bt: Flexure. Flexure of a Rectan- gular Bar supported at Both Ends — Bar supported at One End ; Cylindrical Bar 98 XXIX. Coefficient of Rigidity with the Torsion Lathe. The Modulus of Rigidity — Simple Torsion Apparatus ... 99 XXX. Modulus of Torsion by the Torsion Pendulum. Modulus of Torsion — Periodic Time by the Method of Transits . 101 XXXI. Moment of Inertia by the Torsion Pendulum. Moment of Inertia by Torsion Pendulum — Formulse for Moments of Inertia 104 X X XTT . Compressibility of a Liquid with the Piezometer. The Piezometer 106 XXXIII. Boyle's Law with the U-Tube. Boyle's Law .... 108 XXXIV. Errors of an Aneroid with an Air Pump. Testing the Aneroid Barometer 110 XXXV. Coefficient and Laws of Friction by Several Methods. Coefficient of Friction 112 XXXVI. Surface Tension with Capillary Tubes. Capillarity and Surface Tension — Cleaning Glassware . ....... 11.3 XXXVII. Surface Tension by Direct Measure. Surface Tension . 116 XXXVni. Specific Viscosity with Torsion Pendulum. Viscosity . 117 CHAPTER V. DENSITY AND SPECIFIC GRAVITY XXXIX. Density by Hydrostatic Weighing. Density and Specific Gravity — Density by Hydrostatic Weighing — Other Methods for Hydrostatic Weighing. . . ... 119 XL. Density with the Pyknometer. Density with the Pyknom- eter . 124 XLI. Density of Air by Weighing and Exhaustion. Density of Air 126 XLII. Density of a Gas by Weighing and Comparison with Air. Density of a Permanent Gas . 127 XLIII. Density op Liquids with a U-Tube. Density with a U-Tube — Relative Density by Hare's Method 128 XLIV. Specific Gravity with the Jolly Balance. The Jolly Balance 129 XLV. Specific Gravity with Hydrometers. The Constant Immer- sion Hydrometer — The Variable Immersion Hydrometer 131 VUl CONTENTS PAET III — SOUND CHAPTER VI. FREQUENCY OF VIBRATION PAGB L. Frequency of a Sound by Beats. The Tuning Fork — Fre- quency of Sound with a Tuning Fork 133 LI. Frequency of a Sound with the Siren. Frequency of Sound with the Siren 134 LII. Frequency of Vibration by Graphic Methods. Frequency of Vibration by Graphic Methods 136 LIII. Ratio of Vibration FrbqiJencies by Lissajous's Figures. Fre- quency of Vibration by Optical Method — Copying a Standard Fork — Projection of Lissajous's Figures 137 LIV. Frequency of a Fork by Optical Comparison. Reed's Method for Rating- a Tuning Fork — The Stroboscopic Method . . . 139 CHAPTER VII. VELOCITY AND WAVE LENGTH OF SOUND LV. Velocity OP Sound by Resonance. Velocity of Sound in Air — Wave Length of Sound by Resonance 144 LVI. Velocity of Sound and Young's Modulus by Dust Figures. Relative Velocity of Sound by Stationary Waves — Young's Modulus by the Velocity of Sound 145 LVII. Velocity and Wave Length of Sound by Interference. Inter- ference of Sound 147 CHAPTER VIII. VIBRATING STRINGS AND AIR COLUMNS, AND SOUND ANALYSIS LVIII. Laws op Vibrating Strings with the Sonometer. Laws of Vibrating Strings — Melde's Experiments with Vibrating Strings ■ 149 LIX. Forms of Vibration in Organ Pipes by Manometric Flames. Nodes in Organ Pipes — Combined Sounds — Organ Pipe with Water Trough 151 LX. Composition op a Sound with Resonators. Sound Analysis . 152 CONTENTS IX PART IV — HEAT CHAPTER IX. EXPANSION PAGE LXX. Linear Expansion of a Solid with the Comparator. Coefficient of Linear Expansion . . 153 LXXI. Cubical Expansion of Glass with the Weight Thermom- eter. The Weight Thermometer . 155 LXXII. Expansion of Liquids with the Dilatometer. Coefficient of Expansion of Liquids ... 157 CHAPTER X. THERMOMETRY LXXTTT. Constants and Errors of a Thermometer by Calibration. Thermometry — Calibration of a Thermometer — Funda- mental Interval of a Thermometer — Table of Corrections for a Thermometer — Exposed Column of Mercury — Com- parison of Mercury-iu-Glass and Hydrogen Thermometers 159 LXXIV. Temperature and Expansion of Gases with the Air Ther- mometer. The Air Thermometer 166 LXXV. High Temperatures with Resistance and Thermo-Electric Pyrometers. Measurement of High Temperatures — The Platinum Thermometer — The Thermo-Electric Pyrometer — Fixed Points for High Temperatures . . .... 168 CHAPTER XL CALORIMETRY LXXVI. Calorimeter Constants by Calculation and Experiment. Calorimetry — Heat Capacity of a Calorimeter — Radiation Corrections .... 173 LXXVII. Specific Heat by Black's Method. Black's Ice Calorimeter 178 LXXVIII. Specific Heat with Bunsen's Ice Calorimeter. Bunsen's Ice Calorimeter 180 LXXIX. Specific Heat of a Solid by the Method of Mixtures — Specific Heat by Method of Mixtures 182 LXXX. Specific Heat of a Liquid by the Method of Mixtures. Specific Heat of Liquids by Method of Mixtures .... 184 LXXXI. Specific Heat of a Liquid by Cooling. Specific Heat by Method of Cooling 186 LXXXII. Specific Heat of a Liquid by the Method or Heating. Specific Heat of Liquids by Method of Heating .... 188 X CONTENTS PAGE LXXXIII. Heat Equivalent of Fusion of Ice. Heat Equivalent of Fusion 191 LXXXIV. Heat Equivalent of Vaporization of Water. Heat Equivalent of Vaporization 192 LXXXV. Mechanical Equivalent of Heat by Puluj's Method. Mechanical Equivalent of Heat 194 CHAPTER XII. HYGEOMETRY LXXXVI. Htgrometkic State by Various Methods. Hygrometry . 197 PAET V — LIGHT CHAPTER XIII. PHOTOMETRY C. Luminous Intensity with Simple Photometers. Photometry — Candle Power — Horizontal Candle Power — Simple Photometers 203 CI. Intensity of Light by Precise Methods. Standards of Light — Mean Spherical Candle Power — Gas Meter — Photometry of Intense Lights — The Lummer-Brodhun Photometer — The Rood- Whitman Flicker Photometer . 207 CHAPTER XIV. MIRRORS AND LENSES, MAGNIFYING POWER CII. Radii and Foci of Mirrors by Various Methods. Con- jugate Foci — Concave Mirrors — Convex Mirrors . . . 213 cm. Radii and Foci of Lenses by Various Methods. Lenses — Convex Lenses — Concave Lenses — Radius of Curvature of a Lens — Focal Length of a System of Lenses . . . 216 CIV. Magnifying Power. Magnifying Power .... . . 221 CHAPTER XV. GONIOMETRY CV. Angle of a Crystal with a Goniometer. The Reflecting Goniometer 228 CVI. Adjustment of the Spectrometer. The Spectrometer — Adjustment of the Spectrometer — Reading Divided Circles 225 CVII. Angle of a Prism with the Spectrometer. Adjustment of Prism — Angle of Prism ; First Method — Angle of Prism ; Second Method — Angle of Prism; Third Method . . . 230 CONTENTS XI CHAPTER XVI. INDEX OF REFRACTION PAGE CVIII. Index of Refraction by Minimum Deviation. Index of Refraction — Angle of Minimum Deviation 234 CIX. Index of Refraction with a Microscope. Index of Refrac- tion with a Microscope . . .... .... 236 ex. Index of Refraction by Displacement. Index of Refraction by Displacement . 238 CXI. Index of Refraction by Total Reflection. Total Re- flection — Total-Refleotometer — Refractometer — Crystal- Refractometer ... 239 CHAPTER XVII. WAVE LENGTH OF LIGHT CXn. Wave Length of Light by Fresnel's Interference Method. Interference of Light — Wave Length of Light with the Bi-Prism — Fresnel's Mirrors ... 246 CXIII. Wave Length of Light with the Plane Diffraction Grat- ing. Wave Length of Light by Diffraction 249 CXIV. Wave Length with the Concave-Grating Spectroscope. The Concave-Grating Spectroscope — Normal Diffraction Spectrum . . . . . 251 CHAPTER XVIII. THE INTERFEROMETER CXV. Small Lengths with the Interferometer. The Interferom- eter — Finding the Interference Bands — Circular Bands — Counting Fringes — Monochromatic Light . . 255 CXVI. Plane Surfaces by Optical Methods. Plane and Plane- Parallel Surfaces 264 CXVII. Silvering Glass by Chemical Methods. Brashear's Process for Silvering Glass — Roohelle-Salts Process for Silvering Glass — Cleaning Optical Surfaces for Silvering 266 CHAPTER XIX. THE SPECTROSCOPE AND POLARIMETER CXVIII. Chemical Composition with the Spectroscope. Spectrum Analysis — The Heliostat 271 CXIX. Optical Activity with the Polarimeter. Rotatory Polari- zation — The Polarimeter — Saccharimetry 275 xu CONTENTS PAET VI — ELECTRICITY AND MAGNETISM CHAPTER XX. RESISTANCE PAGE CXXV. Resistance by the Wheatstone's Bridge. Electrical Measurements and Ohm's Law — Wheatstone's Bridge — The Slide- Wire-Meter Bridge — The Galvanometer — Adjusting a Galvanometer — Telescope, or Lamp, and Scale — Standard International Ohm — Resistances and Rheostats — Keys 282 GXXVI. Resistance WITH THE Box Bridge. The Box Bridge — Max- well's Rule for Wheatstone's Bridge 293 CXXVII. Resistance with a Tangent Galvanometer. The Tangent Galvanometer — Resistance by Three Observations with a Tangent Galvanometer, and Battery Resistance by Ohm's Method — Commutators, Reversing Keys 295 CXXVIII. Resistance by the Differential Method. The Differential Galvanometer — To measure a Resistance greater than that of One of the Galvanometer Coils — To measure a Resistance less than that of One of the Galvanometer Coils .... 299 CXXIX. CXXX. Resistance by the Fall of Potential. Ammeters and Voltmeters — Resistance with Voltmeter and Ammeter — Battery Resistance with Voltmeter and Ammeter — Battery Resistance with Voltmeter and Standard Resistance — Bat- tery Resistance with Condenser and Resistance .... 302 Galvanometer and Battery Resistance by the Wheat- stone's Bridge. Thompson's Method for Galvanometer Resistance — Mance's Method for Battery Resistance . . CXXXI. Battery Resistance by Compensation. Beetz's Method for Battery Resistance — Benton's Method for Battery Resist- ance CXXXII. Electrolyte Resistance by Kohleausch's Method. Elec- trolyte Resistance with Alternating Currents — Electrolyte Resistance ... 305 307 309 CXXXIII. Insulation Resistance by Direct Deflection. Measure- ment of High Resistance by Direct Deflection — High Resist- ance by Direct Deflection and Double Readings .... 311 CXXXIV. Specific Resistance by the Comparison of Potentials. Specific Resistance — Resistance by Method of Comparison of Potentials — The Low-Resistance Bridge 313 CONTENTS xiu CXXXV. Temperature Coefficient of Resistance bv Foster's Method. Temperature Coefficient of Resistance — Carey Foster's Metliod for Comparison of Resistances — Resist- ance of the Slide Wire 316 CXXXVI. Errors of a Bridge Wire bv Barus's Method. Calibra- tion of Bridge Wire . 319 CHAPTER XXI. CURRENT STRENGTH CXXXVn. Galtajtometer Cosstant WITH THE Voltameter. Constant of Tangent Galvanometer — The Copper Voltameter — Standard International Ampere ; Silver Voltameter . . 322 CXXXVin. Jodle's Equivalent with the Electrocalorimetek. Joule's Equivalent ; the Joule ; the Watt .... 324 CXXXIX. Figure of Merit of a Galvanometer by Direct Deflec- tion. Figure of Merit of a Galvanometer — Sensitiveness of Galvanometers ; Shunts ... 325 CXL. Current Strength with the Electkodtnamometer — The Electrodynamometer 330 CHAPTER XXII. ELECTROMOTIVE FORCE CXLL Electromotive Force by Compensation. - Standard Inter- national Volt ; Standard Cells — Electromotive Force by Compensation — ^The Potentiometer 332 CXLII. Electromotive Force with a Condenser. Comparison of Electromotive Forces with the Condenser — The Ballistic Galvanometer 336 CXLni. Electromotive Force with the Quadrant Electrometer. The Quadrant Electrometer — Electrometer for measuring Large Potential Differences 339 CXLIV Electromotive Force with the Capillary Electrom- eter. The Capillary Electrometer — Contact Difference of Potential . , 342 CXLV. Electromotive Force with an Ammeter. Electromotive Force and Resistance of Cells with a Milliammeter and a Resistance 345 CXLVI. Thekmo-Electromotite Force by Direct Measure. Thermo-Electromotive Force — Thermo-Electric Power and Thermo-Electrio Diagram 347 CXLVn. Errors of a Voltmeter by Compensation. Calibration of Voltmeter 348 XIV CONTENTS CHAPTER XXIII. CAPACITY PAOE CXLVIII. Relative Capacity ■with a Ballistic Galtanometer. Standard International Coulomb and Farad; Standard Condensers — Condenser Keys — Comparison of Conden- ser Capacities 350 CXLIX. Relative Capacity by Bridge Methods. Bridge Methods for Comparison of Capacities .... 353 CL. Relative Capacity by the Method op Mixtures. Compari- son of Capacities by the Method of Mixtures 355 CLI. Absolute Capacity of a Condenser with a Ballistic Gal- vanometer. Absolute Capacity with a Ballistic Galva- nometer — The Ballistic Constant 356 CHAPTER XXIV. INDUCTION CLII. Inductance by Comparison. Standard Henry ; Coefficient of Self-induction 360 CLIII. Coefficient of Mutual Induction by Comparison. Mutual Induction — Comparison of Two Mutual Inductances . . 361 CHAPTER XXV. MAGNETIC QUANTITIES CLIV. Earth's Horizontal Magnetic Intensity with the Mag- netometer. The Earth's Magnetic Elements — The Mag- netometer — The Kew Magnetometer 363 CLV. Variation op the Earth's Horizontal Magnetic Intensity with the Variometer. The Magnetic Variometer — Mag- netic Declination — Comparison of Horizontal Intensities — Oscillation and Deflection Methods for Comparison of Horizontal Intensities . 366 CLVI. Earth's Magnetic Inclination and Intensity with the Earth Inductor. The Earth Inductor — Magnetic Incli- nation — Magnetic Intensity 370 CLVII. Distribution of Magnetism by Rowland's Method. Flow of Induction from a Magnet — Distribution of Magnetism . 374 CLVIII. Intensity of a Magnetic Field by Rowland's Method. Comparison of Magnetic Fields with the Earth's Field . . 375 CLIX. Temperature Coefficient op a Magnet by Deflection Methods. Temperature Coefficient of a Magnet . . . 376 CONTENTS XV PAET VII — APPENDIX CHAPTER XXVI. TABLES, CONSTANTS, AND KEFEEENCES PAGE Tables. Explanation of Tables 378 1. Reduction to Vacuum of Weighings made with Brass Weights in Air 379 2. Density of Various Substances 379 3. Density of Water and of Mercury 380 4. Volume of a Glass Vessel at 20° 380 5. Coefficient of Static Friction 380 6. Relative Viscosity at 19° ... 380 7. Elastic Constants of Solids ... 381 8. Compressibility of Water, Mercury, and Glass 381 9. Surface Tension at 20° ... 381 10. Absolute Value of Gravity 381 11. Local Geographical Data for Cleveland 381 12. Specific Gravity 'of Air 382 13. Capillary Depression of Mercury in Glass Tubes 382 14. Reduction of Barometer Readings to 0° 383 15. Reduction of Mercurial Thermometer Reading to the Normal Scale 383 16. Boiling Temperature of Water at Various Pressures 384 17. Fixed Points for High Temperatures 384 18. Heat Constants of Liquids ... ... 384 19. Heat Constants of Solids ... . . . 385 20. Reduction of Psychrometric Observations 385 21. Relative Humidity 386 22. Declination of the Sun, and Equation of Time 386 23. Tension and Mass of Aqueous Vapor in Saturated Air ... . 387 24. Index of Refraction of Various Substances . 387 25. Wave Length of Lines of Solar Spectrum 387 26. Specific Resistance of Various Substances 388 27. Electromotive Force and Internal Resistance of Cells 388 28. Vibration Frequency of Tones of the Musical Scale 388 29. Reference Books 389 30. Miscellaneous Constants and Numbers 390 31. Metric and English Equivalents and Abbreviations 390 32. Natural Trigonometrical Functions 391 33. Four-Place Logarithms 392, 393 Index 394 LABORATORY PHYSICS PaET I IlSTTRODTJCTIOF chapter i gej^eeal instructions 1. Objects of Laboratory Practice A course in general physics has for its primary object the inculcation of the funda- mental principles of the science. This is best accomplished for college classes by the proper coordination of lectures and demonstrations by the instructor, and of recitations and labora- tory practice by the student. The lectures, demonstrations, and recitations should consume half or more of the time allotted to physics, and should be founded upon a complete systematic text-book. This part of the course should be in advance of the laboratory work, so that the student shall have studied the theory of an experiment before attempting to perform it. A course of physical experimentation by the student has for its objects the fixing in mind of the essential principles studied in the class room, the training of the student's thinking and reasoning powers, and the furnishing of direct proof of some of the fundamental laws of the science ; and it has the further objects, of almost equal importance, of giving the student an acquaintance with the methods and instruments of physical and technical operations, and of developing skill in the manipulation of delicate apparatus and in the making and reducing of meas- urements of precision. 1 2 INTEODUCTION This book is designed as a student's handbook for use in the laboratory; it contains such practical explanations of the principles involved in the experiments, and such details of manipulation and reduction, as experience has shown to be necessary and helpful to the student. With these objects in view, a laboratory course is not con- sidered as consisting of a certain number of exercises to be worked out by each student, and to be complete when these are finished, but rather as consisting of a definite amount of time spent in judicious experimenting. Several days of work put upon some troublesome process which fails at first to give the desired results is as valuable and as much to the student's credit, if honestly done, as the completion of several probleins in which no difficulties were encountered. 2. Available Problems. — Certain problems in each branch of the subject are fundamental, and should be required of each student; but many may be given to some students and not to others, as circumstances determine. Only those problems which have a very clear object in view, and which demand some skill in manipulation and the use of apparatus neither too simple nor too delicate, should be used for a general course ; and usually an experiment should require not less than three nor more than six hours for its completion. These conditions greatly limit the number of available problems. Mechanics furnishes a larger number of valuable laboratory exercises than any other branch of physics, and some of these are best introduced at the end of the course after the student has acquired considerable skill. If each problem contains a distinct lesson, either in principle or in manipulation, it matters not whether one student receives this exercise at the same time that it is assigned to another. It is often advantageous to have students at work in several branches of the subject at the same time. With the work properly systematized, this method is not extravagant of teaching force. 3. Equipment — The duplication of sets of apparatus of cheap and simple construction, in order that all students may be at work upon the same experiment at the same time, is not GENERAL INSTRUCTIONS 3 advocated for college classes. The laboratory equipment should be of as great a variety as is possible, and the student should be trained in the use of the actual instruments employed in scien- tific work. If several instruments for one purpose are required, let them be of all varieties as regards size, adjustments, and attachments, and though a student may work with but one form, he cannot fail to obtain information from merely seeing other forms in use. Each piece of important apparatus should have a definite place in the laboratory ; it should be in position and in perfect order at the beginning of an exercise, and the student should leave it in the same condition at the completion of his work. Subsidiary apparatus, such as calipers, weights, thermometers, and tools, may be obtained from the instructor in charge, and these are to be returned by the one who borrowed them. Much of the apparatus of the physical laboratory is delicate and costly, and is liable to disarrangement by improper handling. If any instrument is out of order, the fact should be at once reported ; the student will be held accountable for all damages which result from neglect or carelessness. When a piece of apparatus is to be used with which the student is unfamiliar, the peculiarities of construction and adjustment should be care- fully studied before manipulation is begun, both to save time and to prevent injury to the instrument. "With large classes the making of apparatus by the individual student is not practicable. An apparatus made from the odds and ends of the laboratory will not command the beginner's respect and careful attention, even though it would do good work in the hands of an experienced manipulator. An essential part of the equipment of every laboratory is a reference library, which need not be large, but should contain the principal standard works on practical and theoretical physics. The student should have free access to the reference books, and should use the privilege constantly to obtain information in regard to the various forms of apparatus and the different methods of observation and reduction. A short list of reference books is given in the Appendix. 4 INTRODUCTION 4. Descriptions of Exercises. — The titles to the various experiments might all be preceded by the phrase, " Determina- tion of," "Measurement of," or "Proof of"; the titles them- selves mention what is to be determined, and specify the method or the principal piece of apparatus which is to be employed. There follows a concise and specific statement of just what is required of the student. In some cases more than one problem is given under one heading; these are then designated as (a), (b), etc. A problem is referred to in the laboratory work, both in assignment and in records, by its number ; as 8, or 117 (b). The articles grouped under each exercise describe the partic- ular methods of work to be adopted, and, together with the articles to which reference is made, they constitute sufficient information to enable the student who has already studied the principles involved to perform the experiment intelligently. These descriptions are largely explanations of methods of work rather than of particular pieces of apparatus. If more than one important form of instrument is used with a given method, brief descriptfions of these are given. This makes the manual useful in laboratories of various equipment, and it is also advantageous for the student using one form to know that other forms are often employed. 5. Assignment of Exercises. — For assigning the problems, small cards bearing the numbers of the exercises to be used are prepared ; the assignment may be announced in two ways. On each card is written the name of the student to whom the corresponding experiment is assigned and the card is given to him at the beginning of the exercise, to be returned at the end. These names are then crossed off, and for the next day new names are written on the same cards. Or there may be in the laboratory a bulletin board containing a list of the names of the students, and the cards with the numbers may be placed opposite the names selected ; then the students have only to refer to the book for the statements of the problems. The card system has the advantage that any variation desired in the specific statement of a problem may be written on the card, while the description of the method would be the same as GENERAL INSTKUCTIONS 5 given under the corresponding exercise in the book. Shorter exercises may thus be announced, or entirely different ones, according to the requirements of various laboratories. 6. Notes and Records. — Blank forms arranged for the records of each experiment are not recommended ; instead the student is required to arrange for himself the data and results of his work in a systematic way. The efficiency of experimental work will be greatly increased by intelligent and skillful records. Before beginning an experiment the student should carefully study the various operations and measurements involved, and plan a method of procedure and of recording the observations. Tabular and symmetrical forms are to be used whenever possible. Numerical results of several exercises are given in forms suit- able for the reports; the original notes should be similarly arranged, though they may of necessity contain more of detail and computation. Make the first right-hand page of the notebook a general title-page; several following leaves are to be used for a table of contents, which will be filled in as the experiments are per- formed throughout the course. When the book is filled with notes an index should be prepared and placed at the end. Begin the record of each experiment on a new right-hand page, giving a liberal amount of space to the title. There should be recorded all the original data of the experiment: date, fellow- observer, object of experiment, description, with the identifying numbers or names of the particular pieces of apparatus used, method, and all data of the observations, calculations, and results. All observations, whether used in calculating the final result or not, should be preserved, and any reason for suspecting certain results as being inaccurate should be noted. Never erase the result of an observation once recorded, even if it is deemed worthless. Important items should be conspicuous enough to be readily found, and they should be so arranged as to make comparisons and computations convenient. The record of every measurement should specify the unit employed. The scales used in graphical representations are to be explained. There should be diagrams b INTEODUOTION showing the arrangement of apparatus ; special formulae used should be analyzed and proved. Numerical calculations in multiplication, division, involution, and evolution must not be made by arithmetical processes. For the greater part of the work in this course, four-place logarithms (Appendix) or the slide rule are sufficient, though for a few exercises, five-place, or even six- and seven-place logarithms are required. The figures of calculation, logarithms, etc., must be arranged in an orderly manner. The final result and' its exact meaning should be made conspicuous ; if it is the mean of several determinations, compute and specify the probable error (Art. 9). When a result has been obtained it should be compared with what is considered the correct result, obtained by some independent method of proving, or from tables of constants, or from published results of research work. A notebook is valuable only in so far as it is a complete record of all that has been done in making the original experi- ment, and it should contain just so much of detail as will make it intelligible to the writer or to others at any time after the completion of the work. The necessity for full, unaltered, origi- nal notes cannot be too strongly impressed upon the beginner. Upon the completion of each exercise, before the student leaves the laboratory, he should present his notebook to the instructor for examination, criticism, and grading. If the work has been care- lessly or improperly done, a part or all of it may have to be repeated. When the notes and report mentioned in the next article are satis- factory, both will be approved and signed by the instructor. The notebooks for the entire class should be uniform in style and of a permanent kind, having a cloth or leather cover, and paper of good quality. The leaves are preferably of quadrille paper, while an unruled paper is better than that with lines in one direction only. The quadrille ruling facilitates tabulation and is convenient for graphic solutions. A suitable size for the page is fifteen by twenty-three centimeters. The original notebook is to remain the permanent property of the student, and if the records are properly made it will have become a valuable possession at the end of the course. GENEEAL INSTRUCTIONS 7 7. Reports. — Upon the completion of each experiment the student must make out a fuU and systematic report to be given to the instructor, for grading and permanent filing in the records of the laboratory. To secure uniformity, this report should be made upon a blank form which, whUe containing no form for the experiment proper, bears the title of the laboratory, and has a place for the student's name, title of experiment, and sufficient space for the data mentioned as necessary in the original notes. The report may be somewhat condensed in the data of observa- tions, giving only the essential results, and in the calculation, which may be indicated. The numerical results of several of the exercises which are given exhibit the proper forms for the reports. Credits and grades for the exercises will be given only after both notes and reports have been approved. 8. Observations, Errors, and Corrections. — When the highest precision is attempted it is found that repeated measures of the same quantity differ by appreciable amounts. The meas- ures are affected by errors, some of which are accidental and variable in magnitude, while there are others which are con- stant. The constant errors may be due to imperfections in the measuring instrument, to a faulty method, or to bias in the observer. Study will often discover the errors of instruments and methods, and they may be eliminated or made inappreciable by determining their values and applying corrections for them. Errors due to bias or prejudice are only to be reduced by the exercise of special care and skill, or by a change of observers. Whenever practicable the observations of one person should be checked by another. While it is not necessary that the student be in ignorance of the nature or value of a result to be obtained, yet it may require an effort on his part to prevent this knowledge from prejudicing the result, and to check the tendency to make a second measure agree with the first. Besides the constant errors there are always present accidental errors of observation, which in a large series of independent, equally trustworthy measures, are likely to be half positive and half negative; most of these errors will be of small magnitude, and only a very few will be large. The arithmetical mean is 8 INTRODUCTION the best result that can be obtained from such a series, and it is much more trustworthy than is a single measure. Theory- indicates that the probability of the mean increases as the square root of the number of observations; hence the mean of nine measures has a probable error one third as* large as the probable error of one measure, and the mean of twenty-five measures has a probable error one fifth as large. The proba- bility increases so slowly in comparison with the labor of obser- vation that a practical limit is soon reached. Usually ten measures of the same quantity are sufficient. The accidental errors are often small in comparison with the constant errors, and time which might be spent in making a longer series of measures is more profitably used in obtaining a second result after making a complete readjustment of the apparatus, or with new apparatus, or with a new method. Since in laboratory practice mere numerical results are not primary objects, the obtaining of a measure which by accident is correct will not excuse the student from making the repeated adjust- ments required in original work. Usually much more time is consumed in arranging and adjusting a set of apparatus than is required to make the final observations ; for the student this is the most instructive part of laboratory work, and it should be performed thoroughly and understandingly. Another class of errors which may be called mistakes are sometimes present. These generally result from inattention and lack of skill, which are inexcusable even in the beginner. The methods of procedure given in connection with the labo- ratory problems are largely concerned with the elimination and correction of errors. Reference. — Lupton, Notes on Observations. 9. Probable Error — From a number of observations, depend- ing upon their concordance, there may be computed a criterion of the precision with which the measures can be made, which is called the probable error. The probable error of a single observation is the quantity which when added to and sub- tracted from the mean gives limiting values, such that if a GENERAL INSTRUCTIONS 9 single measure of the same kind is made, it is as likely to lie outside of these limits, on either the positive or negative side, as it is to lie between them. The. probable error of the mean is a quantity which when added to and subtracted from the mean gives limiting values such that if another mean value is deter- mined as was the first, its value is as likely to lie outside of these limits, in either the positive or negative direction, as it is to lie between them. The probable error is not a limiting value such that there is no probability of a greater error ; it is such a value that in a large series there are certain to be as many errors greater than it as there are smaller ones. In other words, a result is as likely to have an error (compared with the mean) larger than the probable error as it is to have a smaller one. Probability shows that an error twice as large as the probable error is likely to occur in one out of 5 measures, that an error three times the probable error may be expected once in 23 cases, an error four times as large once in 142, while an error five times as large occurs only once in 1314 observations. To give reasonable security, in the ratio of 142 to 1, that the mean may not have an error exceeding four times the proba- ble error of a single observation, the mean must be the result of 16 measures. If m is the arithmetical mean of a series of n measures, aj, a^, fflg . . . Oj,, the probable error of a single observation is ± Q 6745 J(w - a^f -F (wT- a^f +---(m- * n — 1 ^ a„)2 n and the probable error of the mean is E=± 0.6745 J (w - ai)^ + (m - a^f + ■ ■ ■ (m - a,,)^ ^ _^_ * w(w— 1) Vn The numerical coefficient usually may be taken as |. The differences between the mean and the several measures are called the residuals or the deviations. The average of the deviations, without regard to sign, is often used as an indication of pre6ision. The percentage deviation, the value of which is 10 INTRODUCTION the deviation divided by the quantity, is useful when only a few measures are made. These precision measures, the probable error, the percentage deviation, etc., only indicate the agreement of the measures among themselves as regards the variable accidental errors ; they indicate nothing with respect to constant errors, which may be very large, and hence they do not show the relation of the result to the absolute truth, a relation which usually is wholly indeterminate. 10. Least Squares. — When a number of independent direct measurements of the same quantity have been made, the arith- metical mean is the most probable value. But if the quantity is measured indirectly, being involved with others, the obser- vations furnish equations expressing the relations of these quantities. If the number of the equations equals that of the unknown quantities, only one solution is possible. If there are more equations than unknown quantities, no one set of values for the unknown quantities is likely to satisfy all the equations ; that is, an exact solution is impossible. Various approximate solutions may be made, and theory shows that the most probable one is that which makes the sum of the squares of the residual errors the least possible. This method of solution is known as the Method of Least Squares. The cal- culation is apt to be laborious, and is required only in impor- tant reductions. The student may consult the references for descriptions of the operations, and mathematical text-books for the full theory. Repekences. — Concerning the reduction of observations, the student is referred to Stewart and Gee, Practical Physics ; Kohlrausch, Physical Measure- ments ; Nichols, A Laboratory Manual of Physics ; JBolman, Precision of Measurements ; Merriman, Method of Least Squares. 11. Weighted Observations. — When a final result is to be calculated from a number of different determinations of the quantity, made perhaps by different observers, by different methods, with different apparatus, or resulting from different numbers of separate observations, these determinations will not all be equally trustworthy. In the computation each one must GENERAL INSTRUCTIONS 11 be allowed to affect the result only in proportion to its trust- worthiness, and weights must be assigned to them according to their probable accuracy. When the separate values are each the result of a number of observations, the weight is set equal to this number. If the probable error, e, is known (Art. 9), the weight is proportional to — • In other cases the weights must be assigned according to the judgment of the computer. In the calculation each value is multiplied by its weight, and the sum of these products is divided by the sum of the weights. The final mean, r, of several results, rj, r^, etc., having weights, »„ »,, etc., is 12. Significant Figures In order that numerical operations should have all the accuracy possible and yet not appear to claim an unwarranted precision, and to save time, the data of observation, computation, and results should contain only the proper number of significant figures. A significant figure is any one of the ten digits other than a zero which is used merely to locate the decimal point. In a series of measurements the significant places should be carried one place farther than that in which differences first occur. In casting off figures, increase by 1 the last figure retained when the following was 5 or more. When several numbers are to be added or subtracted, whose significant figures by the above rule reach to different decimal places, no significant places are to be retained beyond those of the number whose last significant figure is in the highest place. When numbers are to be multiplied or divided, there should be the same number of significant figures in all the data, con- stants, products, quotients, and result, as there are in that factor which has the fewest significant figures. In logarithmic computation there should be as many signifi- cant figures in the mantissse as there are significant places in the numbers operated upon. The characteristic is not considered in counting the significant places. 12 INTRODUCTION All records of measurements should show clearly the full degree of accuracy attained, and to this end final zeros in a decimal fraction should be considered as significant as any other figure in the same place. For example, if in weighing a mass with a balance and by a method capable of determining single milli- grams, the result is exactly twenty-one and six-tenths grams, record the result thus: 21.600 g. If the last figure in a num- ber representing a quantity is 9, this figure would of course be written; if the figure is 10, in the decimal system, the 1 of the figure is "carried" and added to the preceding figures, but the is as significant now as was the 9 in the first case. If the in the last place is dropped, it would indicate that no value had been found for this place, which is contrary to the supposition. 13. Graphical Methods. — When a series of observations has been made of the dependence of one quantity upon another, often the most perspicuous presentation of the results is by a curve representing this dependence. Using the values of the independent variable as abscissae, and the corresponding values of the dependent variable as ordinates, a series of points may be plotted. A curve drawn through these points as nearly as possible, so that very few points are far from the curve, and that with respect to any small portion of the curve there are as many points on one side of it as on the other, wiU graphically represent the observations (Art. 74). The exact form of the curve will be a matter of judgment, and hence the solution is somewhat indeterminate. An error in an observation may be indicated by the erratic location of a point. The values of unknown quantities may often be measured from such a plot ; that is, a graphic solution may be made. Whenever it is pos- sible, even though the solution has not been a graphic one, the results of an exercise should be shown graphically. 14. Units All measurements in mechanics are to be recorded in centimeter-gram-second units unless distinctly required other- wise. Do not record some measurements in meters and others in millimeters, but use the centimeter as the universal unit of length, and the gram as the only unit of mass. In final results GENERAL INSTRUCTIONS 13 all forces are to be expressed in dynes. Attention to these points may save much confusion in calculation. The centimeter is ^^-^ of the distance, at the temperature of 0°, between two certain marks on a certain bar of platinum-iridium, known as the International Prototype Meter, which is preserved at the International Bureau of Weights and Measures near Paris. The gram is y^^-jj of the mass of a certain piece of platinum- iridium, known as the International Prototype Kilogram, which is preserved at the International Bureau of Weights and Meas- ures near Paris. The second is ^g f-g-j of a mean solar day. Upon these three fundamental units are founded many derived imits, such as the dyne, erg, and joule ; there are also related units, such as the calorie, and many independent units, such as the degree centigrade, candle power, etc. When deemed neces- sary these units are described in connection with their first use in the experimental work. The employment of one system of units for all quantities sometimes results in numbers which are very large or very small. Such a number is best expressed as the product of two factors, one of which is the number with one integral place and as many decimal places as are significant, the other factor being a power of 10. Since logarithmic computation is almost uni- versal, this method is simple; the first factor is the number corresponding to the mantissa alone, while the second is 10 with an exponent equal to the characteristic of the logarithm. An illustration is the answer to the example in Art. 74. Reference. — For a complete treatment of the units of physios together with tables of constants, reference is made to Everett, Illustrations of the C. G. S. System of Units. 15. Reading Divided Scales. — In quantitative work the read- ing of some form of divided scale is almost universal, and when the highest precision is desired fractions of the smallest divisions must be determined. Often this is accomplished by means of either the vernier or the micrometer screw, described in Arts. 17 and 19. When this is not the case it is a general rule that the 14 mTKODUCTION fraction of a division is to be estimated in tenths. Never esti- mate in fourths or eighths, but always in tenths for recording decimally. This is to apply to straight and circular measuring scales; to the divided heads of measuring screws; to balance, galvanometer, and thermometer scales ; to the time intervals represented by pendulum beats ; and to all other readings wh^re such an estimation is possible. Paet II MECHAlSriCS CHAPTER II GENERAL MEASUREMENTS, LENGTH, AND MASS I. LENGTH WITH THE CALIPERS Measure the length of a steel rod with the vernier caliper, in both inches and centimeters, and find the ratio of the inch to the centimeter. Determine the dimensions of a steel cylinder with English and metric micrometer calipers, and find the ratio of the inch to the centimeter. Calculate the probable error of a single observatipn and of the mean for each set of measurements. 16. Length. — Measurements of length are always referred to real or virtual divided scales, and when precision is desired fractions of divisions must be determined. One of three methods is employed for this purpose. The simplest is that of estimation, mentioned in Art. 15, which depends upon the judgment of the observer. A second method, more precise and largely independent of judgment, is by means of the vernier. The greatest precision is attained through the application of the micrometer screw. These latter methods are directly applied in the calipers described below, and their use in more elaborate instruments for length measures and comparisons is described in connection with other experiments. 17. The Vernier. — To facilitate the reading of fractions of a division of a divided scale, the vernier is often employed. It consists of a short subsidiary scale, movable along the main 15 16 MECHANICS scale, the zero line of which is the index to the main scale. If the smallest indication desired is — of a division, the vernier is n usually n — 1 scale divisions in length, and is divided into n parts. If a vernier is applied to determine tenths of a scale division, it may be constructed so that its total length is nine scale divi- sions, while it is divided into ten equal parts ; each vernier part will therefore be equal to nine tenths of a scale division. Sup- pose, as is represented in Fig. 1, that the index or vernier line lies between the main scale graduations corresponding to 1.4 and 1.5, the fraction of a division from 1.4 to the index Une can be determined as follows. The vernier line No. 1 is nearer to its corresponding scale line by one tenth of a division (a vernier 11 10 Fig. 1. Scale with Versier division being nine tenths of a scale division), and the vernier line No. 2 is two tenths of a division nearer the next scale line, and so on. Each succeeding vernier line being one tenth of a division nearer its corresponding scale line, the number of the vernier line which exactly coincides with a scale line will represent the number of tenths of a division by which the first, or 0, line is separated from the preceding scale line. If, as shown, line No. 7 of the vernier thus coincides with a scale line, since it is seven tenths of a division nearer to this line than the vernier line is to its corresponding scale line, the reading to the nearest tenth of a division is 1.47. The following rule for reading vernier scales is usually appli- cable. From an examination of the main scale determine the value of its smallest division. This smallest division will be further subdivided by the vernier into as many parts as there are divisions in the entire vernier scale: determine what this THE CALIPEE 17 value is ; it may be called the value of a vernier division. A reading then consists of the sum of two parts. The first part is the exact reading of the main scale up to the line which imme- diately precedes the index or line of the vernier. The second part is the vernier reading for the fraction of a division. Look along the vernier until a line is discovered which exactly coin- cides with some line (no matter which) on the main scale. The vernier reading is then the product of the number, on the vernier, of this coinciding line, and the value of one vernier division. Fig. 2 represents a circular vernier in which the smallest division of the circle is ^°, or 10' ; the vernier subdivides this into sixty parts, therefore indicating 10" The first part of the reading (at a) is 158° 40', the vernier a b Fig. 2. Vernier for Divided Circle Eeading to 10" reading (at 6) is 7' 10", and the whole reading is 158° 47' 10"- Other forms of verniers are sometimes used, but it is not necessary to describe them, as their indications may be analyzed in a manner similar to that given above. Reference. —SteZey, Gillespie's Surveying, Vol. I, pp. 201-213. 18. The Vernier Caliper. — For quickly measuring various small lengths with moderate precision, the vernier caliper is useful. As compared with the screw caliper described in the next article, it is not so precise, but it has the advantage of greater range and of facility in setting for measures of different lengths. The vernier caliper (Fig. 3) consists of a straight scale having two jaws, whose plane and parallel surfaces are at right angles to the length of the scale. One jaw is fixed, and the other, movable along the length of the scale, carries an index and vernier, which indicates the distance between the jaws. The object whose length is to be measured is placed between the jaws, which are adjusted by the slow-motion screw until it 18 MECHANICS is very lightly held between them. The movable jaw is then clamped in position, and the reading of the vernier taken. The scale is sometimes graduated on one side in inches and on the other in centimeters, setting of the caliper. l ) \ y "\ j^ \ / ■\ y ^\ ^ ^ / ^ y 1 / "^ /J y 1 2 S ) A 5 3 6 IK 7 3 / 8 J £ \ \ / \ / \ / ' — Length in Centimetcra Fig. 13. Coerections to Geneva Nickel Meter No. 11 next upper diagonal ; and so continue until the square form is fiUed. The algebraic sum of all the numbers in each column of the square, divided by ten, is the correction to the correspond- ing decimeter space, expressed in thousandths of a turn of the micrometer screw. These corrections are reduced to microns by dividing by 20.791, the number of turns of the micrometer screw per millimeter. The successive sums of these numbers are the corrections to the spaces 1, 2, 3, . . . decimeters %,s meas- ured from the zero line ; these are given in the bottom row of Table II. Fig. 13 is a graphic representation of these results. The actual temperature of the scale during these observations is of no importance, but it is necessary that, during any one set of measurements, the temperature should not change. This is particularly-important when the microscopes are far apart. The comparator should therefore be in a constant-temperature room. o (z; CO et o » iz; i H § o ' o M to |25 A Pi o Ei3 W H 00 « ■* (30 o o + + I + + CO O ^ CO to , I OOTPcaEOOOOlO-^ 1-" cq S + I I + + I I + N CO ■ I CO 01 lO CO ' ' -^ C^ VS r^ I « »0 (N W ■ ■ CO t> 00 OS t «* »o ci ti. ( CO ^ lo S S S K ! »H l-< CO N + I + 1 + + I + COi-(t-00i-00O>r-l OiHcqco4Qoa 34 < < 8 3 03 i-Hc«Dooot^a»cooo 7+1 1 7 + + *T + "5 CO 1 o oq 1 d O O CO t^ CO lO It- (N 7 t 1 1 7 1 H- 1 1 o to 1 (M IN 05 1 + s C0rHC»Q0OThOOi-IC0 ,-HU3OlO5C0?O(M t-'^t* r-((Ni-HrHTH(MCO (N2^i'S'i'^2 and N^X^S-^S^, or the area Q^Qi^i^^i- Since any area which does not inclose the pole may be repre- sented by the sum of elements such as have been considered, it foUows that the tracing of the periphery by the style moving around it in a clockwise direction will cause the vs^heel to indicate directly the area inclosed. If the area boundary incloses the entire datum circle and the pole, it will be made up of elementary lines such as i^j-Bg ' ^^^ tracing of this line entirely around the circumference will cause the wheel to indicate, in the manner explained, only the area between the boundary and the datum circle. In this case, there- fore, the wheel indication must be added to the known area of the datum circle. When the boundary incloses the pole and lies within the datum circle, the wheel gives a negative indication (for clock- wise motion of the style) which is the area between the bound- ary and the circle ; hence the desired area, being the difference between that of the circle and the ring, is equal to the algebraic sum of the circle area and the wheel indication. The same rule naturally applies if the boundary inclosing the pole is partly inside and partly outside the circle. To find the Area of the Datum Circle. — In a strip of cardboard pierce two needle holes at a measured distance apart. Fasten the pole through one hole, and by resting the style in the other a circle of knovm area may be readily traced. The wheel read- ing is the area to be subtracted algebraically from this known circle to give the area of the datura circle. It is best to trace two known circles, one a little smaller than the datura circle, and one larger. General Rule for measuring Areas. — If possible place the pole outside the area ; trace the periphery with a clockwise motion of the style ; the wheel reading is the area. When the pole is inside the area trace the boundary with a clockwise motion of the style ; the wheel indication, attention being given to the sign, algebra- ically added to the area of the datum circle is the required area. 46 MECHANICS If in the last case a trial shows a negative turning of the wheel, it may be convenient to trace the boundary in a counter- clockwise direction when the direct reading of the wheel is the area to be subtracted from the datum circle. The setting of the wheel is so easily accomplished that it is usually best to start with the index at 0. Use a straightedge to facilitate the tracing of straight lines. Large areas may be subdivided and measured in parts. The details of setting the instrument to various scales will be obvious from the marks and figures engraved on the arm, or from the maker's instructions. The setting for a particular scale may be found or tested by trial measurements of a known area, such as a rectangle, or a circular groove in a metal plate. 36. Mensuration of Areas. — For figures of regular shape the following formulae may be used, the symbols requiring no explanation. Triangle = base x i altitude. Circle = trr^. Parabola = base x f height. Ellipse = irah. Cylinder = 2 -n-rZ + 2 nrr". Cone =-7rr^ + 2 Trr x -J- slant height. Sphere = 4 Trr\ For irregular plane figures the curved boundary may be drawn upon cross-section paper, and the number of squares inclosed counted, estimating fractions of squares ; or the figure may be cut out of a sheet of paper or metal of uniform thickness, and its weight compared with the weight of a piece of the same material whose area is known. XII. ANGULAR DISTANCE WITH THE SEXTANT Determine the angle between two distant points from two slightly different stations. Determine the angular elevation of a distant object. 37. The Sextant. — The angle in any plane between two points may be very conveniently measured, with considerable precision. THE SEXTANT 47 by means of the sextant. It is a small, light-weight instrument, with which the angle between the two objects is measured not by pointing first at one and then at the other but by observing both at the same time, the objects being brought into apparent coincidence by mirrors. The adjustment for coincidence can be made while the instrument is held in the hand, and even when the observer is in motion, as on board ship. This portability makes the instrument very useful in the laboratory and field as well as at sea. The sextant consists of an arc of a graduated circle of about 60°, at the center of which is pivoted an index arm with a vernier, V (Fig. 21), carrying the index mirror M. Attached to the frame of the sextant is a small telescope, T, and the horizon glass, H, both fixed in position. The horizon glass is half silvered and half trans- parent, so that upon looking through the telescope one sees objects in the direction JffB, and also, by reflection from the mirrors M and II, objects in the direction Jf^. j,^^ 2^ g^^^^^^ If the two mirrors are parallel the two lines of sight are parallel, while if one mirror is turned through any angle the lines of sight are inclined at twice this angle ; hence every half-degree division on the arc is numbered as a whole degree, aiid the readings give directly the required angle. Colored shade glasses are provided to reduce, the intensity of one or the other of the beams of light entering the telescope, in order that both objects may be seen equally well. The parts of a sextant, properly constructed, should fulfill the following conditions : the index glass and horizon glass should be perpendicular to the plane of the circle, the axis of the tele- scope should be parallel to this plane, and when the mirrors are parallel the vernier should read 0°. Sextants are provided with means for making these adjustments, and the following methods may be used to verify them ; but having been once properly made they shoidd not need altering. 48 MECHANICS Set the index at about 100°, and place the eye close to the index glass so that part of the divided circle is seen reflected by the glass and part by direct vision. These two portions of the arc should appear to be in the same plane. If they do not so appear, alter the inclination of the mirror till the condition is satisfied ; then the index mirror is perpendicular to the plane of the arc. Point the telescope at a small, distant object, and move the index arm till the reflected image of the same object comes into the field o^vievsr. If the horizon glass is perpendicular to the plane of the arc, the two images can be made to coincide by moving the index arm ; if not, alter the inclination of the horizon glass till this is possible. That the axis of the telescope is parallel to the plane of the sextant is sufficiently tested as follows. Support the sextant in a horizontal position, and place two sights on the ends of the divided arc. The sights should be of the same height and such that their tops are in a plane with the axis of the telescope, parallel to the plane of the arc. Observe a distant point in line with the sights, which should also be visible in the center of the field of the telescope. The method of correcting, if necessary, will be obvious from the construction of the instrument. To test the fourth condition, point the telescope to a distant object and turn the index arm till the reflected image coincides with the direct one, as for the second correction. The two mirrors are now parallel and the vernier should read 0°. If it does not, the construction may permit the correction of the error. Usually it is better to determine the amount of this index error, and to apply to all angle readings the index correction, which is the vernier reading for the above setting with its sign changed. When altitudes above the horizon are to be measured, the observer, if at sea, points the telescope to the visible horizon and brings the image of the object tangent to this line by moving the index arm ; but if the observer is on land the true horizon can rarely be seen, and an artificial horizon consisting of a shallow basin of mercury is used. Such a position is taken that the image of the sun, for instance, may be seen reflected from the mercury, EQUILIBRIUM OF FORCES 49 and the angle between the apparent direction of the image and of the sun is measured, which is twice the altitude of the sun. Measure the angle between two selected points distant half a mile or more, as seen from a given point. Make three settings to determine the index correction ; the sum of the means of the two determinations is the required angle. Move ten feet towards or from the objects (a half mile distant) and repeat the measurements. Using an artificial horizon, measure the altitude of an assigned point. References. — Chauvenet, Practical Astronomy, Vol. II, pp. 92-118 ; John- son, Surveying, pp. 108-112. Xm. LAWS OF THE EQUILIBRIUM OF FORCES BY THE TRIANGLE OF FORCES Prove the laws for the equilibrium of three forces about a point, using various combinations of forces. 38. Equilibrium of Forces. — The relation between three forces which, acting simultaneously at a point, result in equilibrium is of great importance in engineering work. By the polygon law, such forces are in equilib- rium if they are propor- tional to the sides of a triangle, the sides taken in order having directions parallel to the forces. Or the forces are in equilib- rium if each one is equal and opposite to the results ant of the other two. These relations are illus- trated by Fig. 22, in which A, B, and C represent the three forces, and B the resultant of A and B, which is equal to — C. In a triangle the sides are pro- portional to the sines of the opposite angles. It is evident that Fig. 22. Triangle and Paral- lelogram OF Forces 50 MECHANICS the angles a, h, and e are the supplements respectively of a, /3, and 7, the angles between the forces as originally applied to the point. Hence if these forces applied to a point are in equilibrium, they are proportional to the sines of the opposite angles ; that is ^ ^ B ^ C sin a sin /3 sin 7 This relation may be proved as follows. Arrange apparatus consisting of ball-bearing pulleys, cords, and weights in the manner shown in 'Fig. 23, preferably in front of a blackboard. The friction of the pulleys and the stiffness of the cords may cause the position of equilibrium to be a little uncer- tain, but by moving the system out of equilibrium and allowing it to return in various directions, a mean position can be found which -will be sufficiently exact. On the black- board draw lines parallel to the three cords, and with a large pro- tractor measure the three angles, a, /3, 7. Use different combinations of weights, varying their relations as much as possible, and record the results in the following tabular form. Equilibrium of Forces Fig. 23. Equilibeium of Forces December 20, 1901 Sekies FOKCBS, grams A^fGrLES, degrees RATIOS No. A JB C a /3 y A Sin a B siu)3 C sin y 1 59.8 69.8 102.8 146 139 75 106.5 106.9 106.4 2 3 4 5 THE BALLISTIC PENDULUM 51 XIV. CONSERVATION OF MOMENTUM WITH THE BALLISTIC PENDULUM Prove the conservation of momentum by the impact of elastic bodies, a larger body striking a smaller one, and also the smaller striking the larger ; find the coefficient of restitution in each case. Prove the prin- ciple for the impact of inelastic bodies. Compare the kinetic energies before and after impact. 39. Momentum and Impact. — The changes in motion im- pressed upon bodies by their impact is in general a complicated problem, but the study of several simple cases gives valuable illustrations of Newton's Second and Third Laws of Motion. The cases of impact to be considered are those of bodies whose centers of mass may move only in the same line, and for which the point of contact is also in this line. By the Second Law of Motion any change in momentum is the result of the action of a force ; if the only forces acting are those due to impact, then, since by the Third Law action and reaction are equal and opposite, regard being had to algebraic sign, the quantity of motion is unchanged by impact. In other words, the sum of the momenta before impact is equal to the sum of the momenta after impact ; this is the principle of the Conservation of Momentum. Perfectly elastic bodies after collision would separate with the same velocity as that with which they approach ; inelastic bodies would not separate at all. Actual bodies lie between these two extremes, and the ratio of the relative velocity after collision to the relative velocity before is the coefficient of restitution. The fact of imperfect restitution is not contrary to the Con- servation of Momentum nor to the Third Law of Motion ; it may diminish the action, but the reaction is diminished by the same amount, always remaining equal to the action ; thus the change in momentum of the system is zero. The usual result of imperfect restitution is a change in the kinetic energy of the system at the time of impact, this energy causing vibration, change of shape, etc., and being largely dissipated in the form of heat. 52 MECHANICS The conditions of collision above mentioned are very approx- imately secured by using bodies of spherical shape supported from parallel axes by bifilar suspensions, so that when they are at rest the. spheres are in contact without pressure, and their centers are in the same horizontal line in the plane of vibration. One body may be cylindrical, when four cords from the same axis are required for \ its proper support. These cords may be \ about a meter and a half long, and a \ graduated arc of 40° is suitable for measur- \ ing the swings of the pendulums. The \ separation of the two axes will slightly -■-■—--^4 displace them from the center of the arc, 4i^^r:Tr...J but the errors resulting are inappreciable. Pointers on the under sides of the balls Fig. 24. Relation of ,^^ move paper riders placed on the edge Fall and Amplitude -,, i.T,,i , ., OP Pendulum ^^° mdicate the extreme pomts of motion. If a sphere under the influence of gravity swings through an arc AB (Fig. 24), it will have acquired at 5 a velocity the same as if it had fallen vertically from A to -D, that is, through the height A, and its velocity will be ^2gh, or it is propor- tional to VA. By geometry, h = — — , C being the chord of the arc- and R its radius; hence, since VX is proportional to C, the velocity is proportional to the chord of the arc through which the ball swings. But further, for arcs not exceeding 20°, since the length of the chord of 20° is 0.348 and of the arc 0.349, the velocities may in this exercise be taken as pro- portional to the arcs for the purposes of comparing momenta and energies. Mastic Bodies. — Suspend two steel balls of about 3.5 cm and 5 cm diameter, so that the line joining the centers, the balls being at rest and in contact without pressure, is horizontal and in the plane of vibration. Withdraw the smaller ball to the end of the arc and allow it to fall through a measured arc, «! (Fig. 25), against the larger ball at rest. After collision the THE BALLISTIC PENDULUM 53 large ball will move forward through an arc, a^, while the small baU rebounds through the arc a^. The momenta are propor- tional to the products of the masses M and m into the respective arcs ; and it is to be shown, by allowing m to fall from different heights, that in each case waj = Ma^ — ma^. The coefficient of restitution is «2 + «3 Calculate the relations of the kinetic energies before and after collision. In this particular case the energy before colli- sion is proportional to ma^, and after collision to Ma^ + ma^. Make similar observations for the momenta, kinetic energies, and the restitution when the large ball is allowed to strike the small one. Inelastic Bodies. — A brass sphere and a lead cylinder serve for these experiments, being made inelastic in effect by plac- ing a piece of soft wax at the point of contact. They are to be supported as before, so that when the two hang at rest they are in contact without pressure, and the line joining the centers of mass is horizontal and in the plane of vibration. Allow the sphere to strike the cylinder, falling from various heights, and calculate the relations between the momenta before and after impact, and also between the kinetic energies. Collision Pendulums 54 MECHANICS XV. MASS BY THE EQUILIBRIUM OF MOMENTS Determine an unknown mass with a balanced bar ; determine the weight of the bar, using known masses ; determine an unknown mass, the bar not balanced. 40. Equilibrium of Moments. — A rigid body free to rotate about a fixed point will be in equilibrium only when the sum of the moments of the forces acting upon it is zero ; that is, when the sum of the moments tending to produce rotation in one direction is equal to the sum of the moments tending to produce rotation in the opposite direction. A sliding knife-edge is provided to support a meter stick from a stirrup attached to a suitable stand, as shown in Fig. 26. Slide the bar in its holder till it rests in a horizontal position. Fig. 26. Equilibbium of Moments By means of knife-edge hooks suspend a known mass near one end and an unknown mass near the other. Alter the position of the hooks to restore equilibrium, keeping them as near the ends as possible. Calculate the value of the unknown mass. The knife-edge support being balanced, its mass need not be considered; but the hangers must be considered parts of the suspended masses. Suspend masses of 200 g and 500 g 98 cm apart (Fig. 26), and shift the bar in its support until the moments are again in THE BALANCE 55 equilibrium. The three moments, due to the suspended masses and the mass of the bar, are now in equilibrium. With the aid of the principle that the weight of a body may be con- sidered as concentrated at its center of gravity, the mass of the bar is to be calculated. Substitute an unknown mass for one of the known masses, and shift the point of support to secure equilibrium ; deter- mine the unknown mass, taking into account the weight of the unbalanced bar. Verify the results by weighing the unknown masses on a balance. XVI. MASS WITH THE BALANCE BY THE METHOD OF VIBRATIONS AND DOUBLE WEIGHING Determine an unknown mass by vibrations. Determine a mass by double weighing, and find the rartio of the arms of the balance. 41. The Balance Perhaps the most generally useful and the most precise of scientific measuring instruments is the beam balance, with which masses are compared by the principle of the equilibrium of moments. The balance consists of a double lever or beam, B (Fig. 27), supported in a horizontal position upon a knife-edge through the center ; near the ends of the beam are knife-edges from which are suspended pans, P, in which can be placed the masses to be compared. The distances from the center knife- edge to the end knife-edges are the arms of the balance. A pointer attached to the beam and moving over a scale, S, indi- cates rotational displacements of the beam. An arrest is pro- vided which removes the beam and pan supports from the knife-edges, and in addition it often firmly supports the pans from beneath. It is usually operated by a milled head or lever at A. A system of lever rods, R, is provided for placing small weights called riders upon the beam at any point of its length, and for lifting them when they are not needed. A case to protect the balance from air disturbances is necessary. There 56 MECHANICS are numerous adjusting devices and conveniences, which need not be described. The theoretical conditions which a balance should fulfill to secure sensitiveness and precision are the following: the three knife-edges should be in the same plane and parallel to each other; the beam should be inflexible; the arms should be of equal length ; the center of gravity should be below the central knife-edge, and as near to it as possible. That the balance may be operated rapidly the beam should be short, and its center of gravity far from its support. Some of these requirements are practically inconsistent with each other, and one or another may be sacrificed according to the use for which the balance is desired. The highest sensibility and precision are attained in balances with long and heavy beams. Such bal- ances indicate variations of 1 part in 500 000000 in the maximum load of 500 g or 1000 g. The period of vibration is very long, being as much as 60 seconds in some instances. A balance which will indicate a variation of 1 part in 1 000000 for the maximum load of 200 g is usually amply sensitive. Such balances may be made with short and light beams and with a period of vibration of 10 seconds. If a perfect balance were used, a theoretical weighing would consist simply in placing the unknown mass in one pan and known masses or weights in the other pan, and in adjusting the latter to bring the balance to a position of rest exactly the same as its position of rest when no loads are in the pans ; but in practice it would be very difficult or impossible to T3 ^*V~ Fig. 27. The Balance 10 '1' 20 THE BALANCE 57 secure these conditions. In general it is easier to make a precise determination of the difference between two quantities than to secure their equality. The practical method of weigh- ing is, then, to select two groups of weights differing by a very small quantity, as for instance by 1 mg, such that one weight is smaller than the unknown mass and the other larger; and after comparing each of these with the unknown mass, to find the true value of the latter by interpolation. The practice of this method will be developed in the following articles. 42. Weighing by Vibrations. — A concrete example will aid in explaining the method of weighing by vibrations. Let it be required to determine the apparent weight of a brass cylinder, to the nearest tenth of a milligram, the smallest weight used being one milligram. The scale of the balance is usually ' I ' '( 1 1 graduated as shown in Fig. 28. The figures are often omitted, which fact, ^ „„ „ , ° .,, . J. . , , I^iG- 28. Scale of Balance however, will not interfere with mak- ing the readings described. Allow the pointer to swing two or three divisions each side of the center. Determine the zero point by reading one swing to the left, one to the right, and a second one to the left, estimating tenths of a division; or the readings may begin and end with a swing to the right. Suppose the reading, indicated in the figure, as the pointer swings to the left, is 6.0 ; then that it swings to the right to 13.1, and back to the left to 6.6. The average of the two left readings is 6.3, and the sum of the average left swing and the right swing, that is the sum of the excursions, is 19.4. The resting point is half the sum of the excursions ; but it is shorter and somewhat more precise to use the sums of the excur- sions instead of the equilibrium points in calculating the weights. Record the observations on one line as follows : Zero point 6.0 1-3.1 G.6 19.4 When beginning work with the balance it will be well to determine the zero point three times, arresting the beam after 58 MECHANICS each determination. The proper agreement of the results will indicate that the balance is in good condition. Now place the brass cylinder in the left pan, and weights to balance it as nearly as can be estimated, 93.217 g, in the right pan. Allow the balance to swing, and read three excursions as before, — to the right 10.4, to the left 8.6, and again to the right 10.2. Record thus: Cylinder left 93.217 g right 10.4 8.6 10.2 18.8 The weight in the right pan is evidently too great, as indi- cated by the sum of the excursions being smaller than for the zero point. Remove one milligram and observe another set of vibrations : 93.216 g right 13.0 7.9 12.7 20.7 Now the weight in the pan is too small, and the apparent weight of the cylinder lies between the two amounts tried. From these observations the exact weight can be calculated. The observations show that the removal of 1 mg caused a change in the sum of the excursions of (20.7 — 18.8) 1.9 divi- sions,, while the change desired was (19.4 — 18.8) 0.6 divisions. Therefore, if the weight removed had been ^g mg, the sum of the excursions would have been the same as for the zero point. This shows that a weight of (93.217 g - ^g mg) 93.2166 g would exactly balance the cylinder. Collecting the observations, the whole record for a complete single weighing by vibrations is as follows : Mass of Cylinder No. 5 METHOD OF SINGLE ' WEIGHING BY VIBRATIONS Balance No. 7, Weights No. 1 May SI, 189S Zero point 6.0 13.1 6.6 19.4 Cylinder left j 93.217 g right 10.4 8.6 10.2 18.8 ■^ ( 93.216 g right 13.0 7.9 12.7 20.7 Cylinder in left pan = 93.217 g - t\ mg = 93.2166 g. The assumptions made in this article, that the arms of the balance are of equal length, that the density of the weights and THE BALANCE 59 of the body weighed are equal, and that the weights are per- fectly adjusted, are never realized. The method must be extended to suit these circumstances, as explained in the next article and in Arts. 47, 48, and 49. 43. Double Weighing and Ratio of Balance Arms The method of double weighing described below theoretically gives the true apparent mass of a body by the elimination of the effects of inequality of the balance arms. It assumes that the position of equilibrium of the loaded balance is the same as that of the unloaded balance. Since this assumption is not justified, the method is not trustworthy for the determination of the true mass. The method of weighing ^ I ^ r ^ by reversal, described in Art. 47, is always to be preferred for this purpose, as it is # \ j.^,,. 29. Balance with precise in practice / \ Unequal Akms //J^ and requires fewer observations. The method of this article is the only one possible for finding the ratio of the balance arms, and it must therefore be used in investigating the constants of a balance. Let a body be weighed by vibrations, as described in the pre- ceding article, with a balance whose arms are unequal ; let the length of the left arm be represented by I, and of the right by r (Fig. 29) ; let X be the unknown mass in the left pan, and W^ the weight that balances it. The body is transferred to the right pan and a second complete weighing is made by vibrations ; let W^ be the weight balancing it in this position. Then from the principle of the equilibrium of moments the following equations are true. XI = W^r, Xr = W^l. The product of these equations is XHr = W^ W^lr ; therefore x=Vw^^, 60 MECHANICS which is the weight of the body independent of the lengths of the arms. Instead of the geometrical mean, the arithmetical mean, X 2 is sufficiently precise for a balance in which the arms are made as nearly equal as possible. Dividing one of the equations for the moments by the other, I r which gives the ratio of the arms. When the arms are of nearly equal length their ratio is more easily computed, and with sufficient accuracy, by the approximate formula, I _^ , w,-w^ A numerical illustration follows. r 2W^ Mass of Cylinder No. 5 and Ratio of Balance Arms method op double weighing by vibrations Balance No. 7, Weights No. 1 May SI, 1895 Zero point Cylinder left [f'T.^'^^''' ^ \ 93.216 g right Zero point Cylinder right {93;2jJgLt Cylinder in right pan = 93.210 g + t\ mg = 93.2102 g. 6.0 13.1 6.6 19.4 10.4 8.6 10.2 18.8 13.0 7.9 12.7 20.7 mg = 93.2166 g. 6.8 12.3 7.1 19.3 11.4 7.7 11.2 19.0 15.0 6.1 14.4 20.8 Apparent mass = V93.2102 x 93.2166 g = 93.2134 g. „,.,,, I /93.2166 Katio of balance arms, - = V — = 1.000034. THE BALANCE 61 44. Weighing by the Rider Method. — A more rapid method of weighing than that described in Art. 42 is often required. Foi>the determination of specific gravity, and for chemical analy- sis, relative mass only is necessary. If bodies are always weighed on the same side of the balance, their masses are affected in the same proportion by inequality in the arms, and weighing by reversal is not necessary. The method of single weighing by vibrations may be simplified for these purposes. Small weights are troublesome to handle, and those of less than 10 mg value may be replaced by a rider, which is a piece of wire usually weighing exactly 10 mg, of such a shape that it may ride astride the beam of the balance at different distances from the central knife-edge. It may be manipulated by the handle shown at R in Fig. 27. If it rides over the end knife- edge it produces the same effect as though it were in the pan. But if it rides at a tenth of the distance from the center to the end its effect is one tenth as great; that is, it may be used in this position as a substitute for 1 mg in the pan. The arm may be divided into ten parts with subdivisions, and then when the rider is moved to a position for equilibrium, its effect in milligrams and fractions is read from the figures engraved on the beam. Often two riders are \ised, one on each arm ; or one rider may move over both arms. The effect of the rider, whether to be added to or subtracted from the weights in the pan, will be evident from inspection. The complete method of vibrations with interpolation may be employed as described, or it may be shortened with only a slight loss of precision, as follows. The sensibility of the balance for various loads (Art. 45) is carefully determined once for all, and a table is constructed showing the sensibility for all loads within the capacity of the instrument. When weighing, the zero point of the unloaded balance is determined as before. The body is placed in the pan and balanced as nearly as may be with weights and the rider. The difference between the equilibrium point and zero point, taken in connection with the table of sensibilities, will determine the amount by which the weight in the pan differs from the true weight. 62 MECHANICS Instead of finding the zero point in this manner, the unloaded balance may be made to swing equally on each side of the center of the scale by means of one rider; the center of the scale is then the zero point, which simplifies the readings. A second rider is used in balancing the body. Instead of reading three turning points on the scale, the equilibrium position may be taken as the mean of two readings. Each simplification slightly diminishes the precision, and the nature of the work must determine in each case the method to be adgpted. 45. Sensibility of Balance. — The scale displacement of the equilibrium position of the pointer of a balance, caused by a change of one milligram in the load in either pan, is the sensi- bility. The sensibility varies greatly with the loads in the pans ,- it may be determined for various loads, and a table or curve pre- pared for reference. It is somewhat more precise to determine the sensibility at each weighing, as explained in Arts. 42 and 47. The sensibility of a balance may be adjusted by altering the position of the center of gravity of the beam. A small screw is often attached above the central knife-edge for this purpose. The center of gravity of the beam must be below the point of support, otherwise the beam wiU be in unstable equilibrium. The nearer the center of gravity is brought to the point of sup- port, the more sensitive the balance; but increase of sensitive- ness results in a longer period of vibration and a less rapid use. The limits of precision of a balance vary greatly according to the design and quality of construction, and it is useless to increase the sensitiveness beyond the point of trustworthy indications. Often it is advantageous to make the sensibihty less than its maximum value, altering it so that it is not greater than is required for the particular work in hand. 46. Practical Hints on the Use of the Balance In addition to the general methods already described, the student should carefully observe the following hints. Remove dust from the pans and weights with a camel's-hair brush. Level the base. THE BALANCE 63 The unloaded balance should be in equilibrium when the pointer is near the center of the scale; this condition may be secured by adjusting the small screw attached to the beam. The student should not alter this, or any other adjustment of the balance, except upon deiinite orders. The beam and pans should be arrested when the balance is not in use, and also whenever weights are added or removed. Arrest the beam only when it is passing through its position of equilibrium. Avoid parallax in reading by having the line of sight perpen- dicular to the scale. The release of the arrest will usually cause the beam to vibrate as desired. If not, a breath of air under one of the pans will be sufficient. A small stream of air from a rubber bulb held in the hand may be directed against the pans to regulate the swing. The pans should have no pendular motion. Weighings should be made with the balance case closed, and precautions are required to avoid the effects of air currents in the closed case caused by uneven temperature. The larger weights should be placed near the center of the pan, and the others so distributed that the pan will not swing to one side when released. The weights should be handled only with the pincers and forks provided. Small weights may be removed from the pan with a camel's-hair pencil. To avoid mistakes, the weights should be counted several times. Count them while they are in the pan ; remove them from the pan, arranging them in groups in the order of magni- tude, and count again ; and finally they may be counted by the unoccupied places in the box, or as they are returned to their places in the box. When using gilded weights care should be taken that they do not come into contact with small particles of mercury. Volatile liquids and fuming acids should be weighed only in closed vessels. It is sometimes necessary, as when weighing hygroscopic bodies, to keep drying material in the balance case. 64 MECHANICS Arrest the balance, remove weights from the pan, arranging them in the proper order in the box, and close the balance case, upon the completion of the weighing. XVII. ABSOLUTE MASS WITH THE BALANCE BY THE METHOD OF VIBRATIONS AND REVERSAL Determine the true mass of a body. 47. Weighing by Reversal. — Any weighing which depends upon the determination of the zero point must be untrustworthy, as the position of equilibrium of the unloaded balance may not coincide with its position of equilibrium when loaded. The method of reversal here described does not require the position of the zero point to be known ; it eliminates the effect of the inequality of the arms, and is both short and accurate. For example, let it be required to compare the kilogram weight (lOOO)p with the normal kilogram Kj,. With Kj^ in the right pan and (1000)^ in the left, determine the sum of the excursions as described in Art. 42. Interchange the loads in the pans and again find the sum of the excursions. If the appar- ent weights of the two masses are equal, the sums of the excur- sions will be identical, regardless of the lengths of the beam arms ; while if the weights are unequal, the difference between the sums of the excursions will correspond to twice the difference between these weights. This difference will be expressed in milligrams by making the observed change in the sum of the excursions, caused by reversal, the numerator of a fraction whose denominator is the change in the sum of the excursions produced by adding a two-milligram weight to either side. The two-milligram weight should be dropped into the pan without arresting the balance. The complete record of such a comparison is given in the next article. 48. Weight in Vacuo. — When a weighing is performed in the air, as is usually necessary, all bodies in the pans are buoyed up by forces proportional to their volumes. If the volumes in THE BALANCE 65 the two pans are unequal, the apparent weight is in error because of this buoyancy. A correction for this is not always applied, though it is of sufficient importance to be regarded even in ordi- nary weighing. If m represents the weight which balances a body in air, I the density of the air, s the density of the body, and d the density of the weights, the true weight in vacuo is (Table 1, Appendix), ""•{'^'-ri)- Frequently this correction can be made with greater ease and precision from the known volumes of the bodies and the weights. Its amount is equal to the difference of volumes in the two pans multiplied by the density of the air at the temperature and pressure of the experiment, the apparent weight being too small by this amount, if the body has the larger volume. When the masses to be compared are of different materials, it is also necessary to consider their volumetric expansions. The volumes are to be reduced to 0°, using the coefficients of cubical expansion, which are three times the coefficients of linear expansion. A numerical illustration follows. Absolute Mass of Kilogram (1000) q by cojfparison with noemal kilogram kj, method of keveksal Staudinger Balance, Rueprecht Weights June 15, 1895 The true mass of the standard kilogram, Kj,, is known to be 999.9998 g. Barometer 74.6 cm; attached thermometer 2'2°.4; thermometer, air, 20°.7. (1000)q left Kif right 7.7 13.3 8.0 21.1 Ky left (1000)q right 8.1 11.6 8.3 19.8 Bd 2 mg left 8.7 14.0 8.9 22.8 (1000)g = ii:^+Hmg. Volume of iT^r at 0° referred to water at 4° = 118.876 ccm. Volume of (1000) the latitude, and II the required difference in altitude in centimeters ; then, H=l 843000 (log \ - log h^ (1 + 0.00367 t) (1 -f- 0.0026 cos 2 ^ -I- 0.00002 h + lh). The following approximate formula, which assumes the value of gravity as that of latitude 45°, that gravity does not THE BAROMETER 73 vary with altitudes, and that the air is half saturated with moisture, is sufficient for differences of altitude not exceeding 100000 cm. ^=1 600000 ^L^l? (1 + 0.004 1). "1 "r "2 References. — Kohlrausch, Physical Measurements, pp. 76-80; Staley, Gillespie's Surveying, Vol. II, pp. 273-296 ; Everett, C. G. S. System of Units, pp. 43-47. CHAPTER III TIME, ACCELEEATION, AND GRAVITY XXI. LAWS OF ACCELERATED MOTION WITH A FALLING TUNING FORK Verify the laws of accelerated motion and find the acceleration of gravity. 58. Time. — Of the three fundamental units of mechanics, determinations of length and mass are considered as belonging to the physicist, while the determination of time is usually dele- gated to the astronomer. In the physical laboratory it is required either to find the ratio of relatively short time intervals or to compare a periodic interval with the infiications of a standard timepiece. The methods for such comparisons are described in connection with the several exercises of this chapter. 59. Accelerated Motion. — A tuning fork is attached to a frame arranged to fall vertically about a meter, between guides which offer the least possible resistance. The fork may be held at the top of the guides by a catch having a trigger, which will release the fork and at the same time set it in vibration. One prong of the fork carries a style for recording the vibrations in a sinu- ous line upon a long plate of smoked glass. The glass may be lightly smoked with burning camphor gum. Make the guides vertical, so that the slide may fall freely, tracing a sinuous line. If necessary adjust the style and repeat the tracing after having moved the glass plate sideways about a centimeter. In this way obtain three good tracings to be measured as directed below. Remove the plate from the frame ; select a point, a (Fig. 31), near the beginning of a tracing where the waves are perfectly foi-med. From this point mark off spaces each containing exactly 74 THE FALLING TUNING FOEK 75 ten waves, as b, c, d, etc. When the fork was at a it had already acquired some velocity in falling, which is represented by v^y. In the interval of time t, corresponding to ten vibrations, the fork, because of this initial velocity alone, would pass over a space, v^t; but gravity also acts, and adds to this the space igt^. Hence in the first interval, from a to b, the fork passes over a space. In two intervals of time it would pass over a space, from a to c, represented by the same formula if for t we substitute 2 t : Similarly for the successive intervals, ad, ae, etc., we must substitute 3 i, 4 i, etc., obtaining S3 = 3 f o« + f 9t^ 84 = 4 v + ¥-^^'. The differences between these distances are the lengths of the spaces passed over in the successive ten-vibration intervals. These are s^ — Bq = ab = v^t + J gt\ g^-s^ = bo = v^t + lgt'^. s^ = cd ■ v + 9^^': These equations show that be — ab = cd — be = = gfi. Fig. 31. Trace made by a tun- ING FOKK Measure as many of the ten-vibration spaces of the trace as is possible, and find the differences between successive distances. The differences should all be equal, proving that the force act- ing on the fork, gravity, is constant. Compute the mean of these measured accelerations, which is equal to / = gfi. If the frequency of the fork, n, is known, the time interval is n 76 MECHANICS, Compute g, the acceleration due to gravity ; the result will be a little too small, because of the friction of the falling slide. Having found t and g, calculate the initial velocity, t)g, from the value of any of the measured internals ; as ah = v^t + \gt\ 60. Acceleration with Variable Time Unit. — Using the second and third wave traces, made ' as above described, mark off on one spaces of twenty and on the other spaces of thirty wave lengths. Find the average increase in lengths of the successive equal time intervals. Compare the accelerations thus obtained for the double and triple time intervals with that for the single interval obtained before. The relations should be /i • /a '/s ~ *i • ^2 • ^3 =1:4:9. In other words, the acceleration is proportional to the squares of the lengths of the time unit. A further >analy sis of the con- crete case of the experiment will make the meaning clear. The acceleration is obtained for two different units of time which have the ratio of 1:3. In the first instance the acceleration is measured by the increase of velocity per single interval. If, now, the force acts during the triple interval, it will produce three times as much increase in velocity as before, the velocity being measured, as before, per single interval. But if the velocity is now measured by the space passed over in the triple interval, its value will be again multiplied by three, or in aU by nine ; that is, the acceleration increases as the square of the unit of time taken for measuring. But liaving a fixed unit of time, as the second, the effect of a constant acceleration is proportional to the first power of the time during which it acts. Gravity in three seconds will increase the velocity of a falling body only three times as much, expressed in centimeters per second, as it would do in one second. ATWOOD'S MACHINE 77 XXII. LAWS OF ACCELERATED MOTION WITH ATWOOD'S MACHINE Verify the laws of uniformly accelerated motion. Determine gravity and the moment of inertia of the pulley. 61. Atwood's Machine. — The essential features of Atwood's machine are two equal weights, of mass w, suspended by a fine cord passing over a light pulley mounted on antifriction bear- ings. A third mass, r, is allowed to ride upon one of the masses, m, causing it to descend. After falling for a known time interval, the rider is removed by a ring through which m passes. A stop is placed to receive m a known time after the removal of the rider. The distance through which the rider falls is measured, and also that through which the weight falls after the lifting of the rider. The time intervals may be determined with a metronome, with a sounder in connection with a break-circuit clock, or with a chronograph. Many machines have pendulums or clock attachments for giving the time signals. Neglecting the inertia of the pulley, the moving mass may be represented by ^m + r; and, not considering friction, the force moving this mass is the weight, / = rg, of the rider. If a is the acceleration imparted to the moving mass by the rider, measured by the distance moved over in one succeeding second after the rider is lifted, divided by the time during which the rider acted, f=rg = mass X acceleration = {2m + r)a. Prove from measurements of the spaces passed over in one, two, and three seconds, that after the rider is lifted the masses move with constant velocity. Allow the rider to act for one, two, and three seconds, and show that the spaces through which it falls are as the squares of the times. Increase the size of the masses and that of the rider in the same proportion, and show that the fall in three seconds is the same as with the small masses, proving that heavy and light bodies fall equally fast. 78 MECHANICS Show that the acquired velocities are proportional directly to the times of the fall, by allowing the rider to act for one, two, and three seconds and measuring the velocities produced in each instance. Prove that a force is proportional to the product of the mass and the acceleration, as expressed by the above equation, by using one rider on two different masses. Prove the preceding proposition by measuring the accelera- tions produced by two different riders on the same mass. In this experiment the sum 2m + r should be kept constant by means of small auxiliary weights. 62. Gravity and Inertia of Pulley with Atwood's Machine The friction of the wheelwork and of the air is very difficult to determine, and it is therefore reduced to a minimum by suitable construction. The remaining friction may be compensated for by adding to the descending mass small pieces of tin foil of such a weight that after the motion is started by hand the mass will descend uniformly. The amount of foil required should be determined for each different load carried by the pulley. This adjustment is best made when the two movable masses are at the same level, so that the weights of the cord on the two sides of the pulley are equal. The rider in falling not only accelerates the masses m but it also must turn the wheel with increasing speed. The pulley is equivalent to a small additional balanced mass, P, for which allowance should be made. The equation of motion may now be written rg = (2 m + r + P) a.^^. Alter the masses m (for instance, double them) and represent the new masses by M. With the same rider as before, the equa- tion of motion is /n nr , , t,\ rg =(2M+ r + P) a^. By eliminating P from these two equations the following result is obtained for the acceleration due to gravity. «,«, 2M— 2 m PATH OF A PROJECTILE 79 Determine a^ and a2 as explained in the preceding article and calculate g. When the rider under the influence of gravity falls through a space s, it does work represented by rgs. This work imparts velocity to the masses and the wheel, and it is measured by their kinetic energies. The masses, 2m + r, acquire a velocity V, and the wheel, whose radius is H and moment of inertia is I, acquires an angular velocity ta. Therefore rgs = ^(2m + r)v^+ ^ la?'. But t)2 = 2as = i22(B2. hence '''9 = \ 2m + r -\ — ;)«» and -P = -4. That is, the equivalent mass of the pulley is its moment of inertia divided by the square of its radius. By eliminating g from the first two equations, _ (a^ — aj)r + a^2 M — a-j^2 m *i ~ '^2 Measure the radius of the wheel and compute /. /= PE^. The moment of inertia might be experimentally determined with the torsion pendulum, as described in Art. 84. XXm. PROPERTIES OF THE PATH OF A PROJECTILE Prove that the acceleration of gravity is constant and show that the path of a projectile is a parabola. 63. The Trajectory. — Arrange apparatus for projecting a ball horizontally in front of a blackboard or a sheet of paper, by allowing it to roll down a semicycloidal curve, as indicated in Fig. 32. The height of this curve may be 30 cm. A mechan- ical trigger should be arranged to release the ball uniformly. Determine the path of the ball by holding 3 straightedge in different parts of the path, so that the ball just grazes it in falling. 80 MECHANICS Fifteen or more points should be determined, and a smooth curve drawn through them. A parallel curve separated from this by the radius of the ball will be the path of the center. From the level of the center of the ball at the lowest point of its cycloidal path draw a horizontal line, and measure a series of distances, i, increasing by two centimeters each. Since the ball will move with a uniform velocity in a horizontal direction, these distances represent both the times of flight and the horizontal motion in these times. Measure the vertical distances, I, from each divi- sion to the plotted path. These rep- resent the spaces fallen in the several intervals of time, due to gravity. A level and thumb line will aid in plotting the coordinates. From the laws of falling bodies each pair of values of I and t should satisfy the equation Z = J at^ ; prove this by showing that the values of o / « = ^' computed for each point measured, are all equal. This value of a represents the acceleration produced by gravity in the time taken for the ball to move over 1 cm in a horizontal direction ; this would be equal to g if the unit of horizontal measure, instead of being 1 cm, was of such a length that it represented the horizontal distance traveled in one second. Since the acceleration produced is proportional to the square of the time, the unit of time represented by t is Fig. 32. Path of a Pkojbctile -^- and the velocity of the horizontal projection of the ball is 1 t Calculate both t and v. THE SIMPLE PENDULUM 81 The constancy of a, as determined above, proves the patli 2 to be a parabola, whose equation in the usual form is t^ — -l, a from which it appears that the distance of the focus from the origin is 2 a The length of the semi-latus rectum is Plot the focus and measure the latus rectum. XXIV. GRAVITY BY THE SIMPLE PENDULUM Determine the intensity of gravity. 64. Simple Pendulum. — An excellent pendulum consists of a metal sphere of from 3 to 5 cm diameter, suspended from a rigid support by a fine steel wire .about 0.01 ^.^ cm in diameter. A simple and sufficient (^)) support is made by fastening the wire to a ^^ light steel ring, such as a screw eye, and JU hanging this on a knife-edge, which may be a three-cornered file, ground smooth, as indi- cated in Fig. 33. ; The length of the pendulum for the pur- '; poses of this experiment may be about 99 cm or 396 cm. This length must be determined as accurately as possible : if it is about a /^'^^^ meter, a meter bar and a beam compass may / \ be used for measuring ; if longer, a steel tape ( 1 is convenient. The distance, d, from the V J point of support to the center of the sphere ^ ^ is required. The distance to the bottom of ^"o- 33. Simple the ball may be measured, from which is to ^ ^ be subtracted the radius of the ball, r, determined with the 82 MECHAIflCS calipers. The length of the equivalent simple pendulum is, neglecting the effect of the suspending wire, The pendulum is made to vibrate through a small arc, a, not exceeding 4°, and its period, j?, is determined, preferably by the method of coincidences as described in the next article. The time of vibration in an infinitely small arc is approximately t = I l + ^sin^l From the theory of the pendulum the acceleration of gravity is Since a dyne is the force which imparts unit acceleration to unit mass, and gravity imparts g units of acceleration, its intensity in dynes is represented by the numerical value of g. This result might be further corrected for the buoyancy of the air and the mass of the suspension wire ; but these are both very small, and moreover are of opposite sign, and they may be neglected. The error due to motion of the support is difficult of determination. If the formula without corrections, ^ = -2"' is used, the errors may be one part in two thousand. A pendulum about four meters long will swing in about two seconds, and will be convenient when the clock signals are given once in two seconds, as is frequently the case. 65. Periodic Time by the Method of Coincidences Arrange a telescope with its line of sight at right angles to the line of vibration, so that the vertical wire in the field of view coincides with the pendulum wire when it is at rest. The vibrations are METHOD OF COINCIDENCES 83 then compared with the audible beats of the seconds pendulum of a standard clock, or, better^ with the ticking of a sounder in connection with a break-circuit clock or chronometer. For many purposes this latter arrangement is very useful, as sounders may be placed in aU parts of a laboratory to distribute accurate time signals. In the absence of these devices an ordinary watch having a second-hand can be made to serve satisfactorily. An assistant looking at the second-hand may count the seconds to himself, and in any convenient manner beat them audibly for the observer. The comparisons between the pendulum and the clock can best be made by the valuable method of coincidences, which is useful for comparing two periodic phenomena whose periods are nearly equal. Let the pendulum be of such length that its period is very nearly one second. If the signals occur every second, a time will come when the pendulum wiU pass the center of its swing, as seen in the telescope, exactly as one of the signals is given; the transit of the pendulum and the signal coincide. But at the next swing they will not coincide, as the period of the pendulum differs from the interval between the two signals. This lack of coincidence will increase until the transit occurs midway between the two signals ; then it will apparently decrease until coincidence again occurs. The inter- val between these two coincidences should be determined as accurately as possible ; it will be an integral number of seconds. In this interval the number of vibrations of the pendulimi is one more or less than the number of time signals. Hence the period is obtained by dividing the number of seconds by this number plus or minus one, according as the pendulum is shorter or longer than the seconds pendulum. Whether the pendulum gains or loses on the time signals may be determined by a simple auxiliary observation. If there appears to be coincidence at several transits, note the first and last, and consider the mean as the true time of coincidence. Observe three or more coin- cidence intervals, and compute the period from each independ- ently. If the rate of the clock is known, and it exceeds one second per day, a further correction should be made because of March 5, 1902 Time of Coincidenc3 Interval 11" SSm 15« 10™ 108 12 8 12 18 12 28 25 20 19 9 55 9 59 84 MECHANICS it ; if the clock is gaining, the computed period is too large. A numerical example of a gravity determination follows. Gravity with the Simple Pendulum Riefler Mean-Time Clock Period f|f = 0.99836 s III = 0.99832 IJf = 0.99833 Mean = 0.99834 Rate of clock known to be less than 0.5 s per day. Average arc = 8°. Corrected period, t = 0.99830 s From the point of support to bottom of sphere, 101.41 cm Radius of sphere, 2.45 Length of equivalent simple pendulum, I — 98.985 '^ = ^ = 980.30^. ^ fi s2 If the pendulum has a period of neariy two seconds, and the coincidences of its transits with a time signal occurring once in two seconds are observed, the number of vibrations made in the coincidence interval is half the number of seconds, plus or minus one. Otherwise the method is as above described. XXV. GRAVITY WITH THE REVERSIBLE PENDULUM Determine the intensity of gravity. 66. Kater'5 Pendulum. — The reversible pendulum has the advantage over other forms, that it is easier to obtain an accurate value of the length of the equivalent simple pendulum. It con- sists of a rigid bar (Fig. 34) with a fixed knife-edge near each end. A heavy mass is fastened at one end, and lighter masses are adjustable along its length. The pendulum is to be swung first upon one knife-edge and then upon the other, and the adjustable masses moved nearer that knife-edge about which THE REVERSIBLE PENDULUM 85 A IS the time of swing is greater, until the times of vibration about the two knife-edges become equal. When this condition is secured the distance between the knife-edges is equal to the length of an ideal pendulum of equal period. To determine this distance the pendulum may be placed upon a comparator (Art. 22) and the microscopes set upon the knife- edges ; a standard scale is substituted for the pendulum and the length read directly. If proper apparatus is available, the length may be determined with a cathetometer while the pendulum is suspended. But probably the best method is to provide a steel rod with a screw end, whose length can be adjusted to reach from one knife-edge to the other while the pendulum is suspended. The length of this rod is then measured with an end com- parator, or in any other convenient manner. The period may be determined by the method of coincidences described in Art. 65. The comparisons with the standard clock will be facilitated by the use of the optical method of Art. 69, or by making the com- parison with the chronograph (Art. 68). For the latter method a platinum wire is attached to each end of the pendulum, so that when it is stationary the wire at the lower end just touches a small globule of mercury held in a small tube, completing an electric circuit through the chronograph. The swinging of the pendulum may thus be recorded, contact does not occur exactly at the middle of the swing, the resulting error will be eliminated by considering only intervals containing an even number of vibrations. It is advan- tageous to have an adjustment by which the mercury globule can be withdrawn from the contact wire after one coincidence, to be replaced when another approaches. The pendulum may be allowed to swing during several coincidence intervals, and Fig. 34. Risversible Pendulum If the 86 MECHAjnCS by taking the mean, the uncertainty due to the difficulty of determining the exact coincidence will be somewhat reduced. The period thus determined should be corrected for the ampli- tude of swing by the formula given in Art. 64. If the period of the pendulum about one knife-edge is exactly equal to that about the other, the time of a single oscillation, reduced to an infinitely small arc, being t, and the distance between the knife-edges being I, the acceleration of gravity is 67. Formula for the Compound Pendulum. — Instead of con- tinuing the adjustments until exact reversal is secured, when the times are approximately equal the following formula may be applied. Let \ and h^ be the distances from the center of gravity to the knife-edges, about which the times of vibration are respectively t-y and t^. Then g 21 2(Ai-/g' The center of gravity can be determined with sufficient exact- ness by balancing the pendulum upon a metal rod and measuring the distances hy and h^ with a meter stick. Further corrections" for the amplitude of swing, motion of the support, the drag of the air, etc., may be made when extreme precision is required, by methods described in the references. Refebences. — Stewart and Gee, Practical Physics, Vol. I, pp. 247-256 ; Bouth, Eigid Dynamics, pp. 72-85 ; Price, Integral Calculus, Vol. Ill, p. 582 ; Vol. IV, p. 290. 68. The Chronograph. — When it is desired to make a per- manent record of the time of the occurrence of a phenomenon, or of its duration, some form of chronograph may be used. This may print the time in plain figures, or the interval of time may be determined by comparison with the vibrations of a tuning fork (Art. 71), or by measuring a length. ■ The latter form is the more common. It consists of a cylinder (Fig. 35) covered THE CHRONOGEAPH 87 with paper, which is made to revolve upon its axis at a uniform rate, usually one turn per minute. A pen carried on the arma- ture of an electromagnet is moved slowly along the length of the cylinder as it revolves, tracing a spiral mark upon the Fig. 35. Ctlindek Chkonogbaph paper. Making or breaking an electric circuit through this magnet causes a little indentation in the trace, as represented in Fig. 36, which shows part of a chronograph record. The reading at a is 2" 26'° 4'.7. The chronograph is used in connection with a standard time- piece, having an attachment for either momentarily making or breaking the circuit at intervals of one or two seconds. To ^ 2h 30m Os ^ ^ „ ^ lOs „ ^ „ „ „ ,f^ ^ „ ^ „ „ „ finnr innn — ^ 3, » n „ ^ ^ „ „ n „ 2h2Sin0s Fig. 36. Ebcobd of Cylinder Chronograph indicate the beginning of each minute there may be some pecu- liarity in the circuit breaking. If the signals occur at intervals of one second, the fifty-ninth in each minute may be omitted ; while for an interval of two seconds, the odd second's signals, except the fifty-ninth in each minute, may be omitted. 88 MECHANICS A signal key, either to be held in the hand or attached to any apparatus as a pendulum, is included in the pen circuit, and permits the recording of the time of any phenomenon along with the clock signals. From this record the actual time of the occurrence, or the interval of time between two phenomena, can be determined by comparing the positions of the special signal marks with the nearest second's mark. A scale which divides the interval between two successive clock signals into parts cor- responding to tenths of a second is often convenient for measur- ing a chronograph record. Two pens may be used, one for the clock signals only, and the other for the observation signals. Sometimes provision is made for rotating the drum at higher rates, as one turn in Fig. 37. Flashing Appabatus ten seconds, or even one turn in one second. It is difficult to maintain uniform rotation at these high speeds. Observations which would require a rapid rotation, if the ordinary chroiio- graph is employed, are usually better made with the tuning- fork chronograph. 69. Mendenhall's Optical Method for comparing Two Pendu- lums. — This method employs the principle of coincidences (Art. 65), the coincidences being easily and accurately observed by optical means. The standard pendulum should have a break-circuit attach- ment, which produces a flashing line signal of the pendulum beats in the following manner. The clock breaks the primary circuit of an induction coil, the secondary circuit of which is connected to a Pliioker tube (Fig. 37). As the a,mount of current required in the primary of the coil would be likely MENDENHALL'S METHOD 89 to ruin the break-circuit mechanism, or to interrupt the clock, a relay is introduced. In the clock circuit a single cell of gravity battery is sufficient, while the coil circuit may contain one or more storage cells, or a few dry cells, for this experiment. When properly adjusted each beat of the pendulum will cause the tube to flash. If the pendulum breaks the circuit by swinging through a globule of mercury, a large current will do no injury, and the relay may be dispensed with. Instead of the coil and tube, an electrically controlled ^..^^ shutter may illuminate a ^^lisj' J-'''fl^- slit with flashes of light. ^\~\ - - ' ' ' iH-^ — A small mirror, perhaps ,,--'' 2cm wide and ,--''' 5cm long, is 3-^'"" I^">- 38. Pendulum for , T , Jcl,.^ — Mendenhall's Method attached to t»--^ the pendulum to be compared near its point of sup- port, the normal to the mirror lying in the plane of vibration. A second nlirror, m (Fig. 38), is held by the stationary support of the pendulum at one side of the flrst mirror, close to it, and in the same plane with it when the pendulum is at rest. The capillary part of the Pliicker tube, T, is placed horizontally so that it may be seen reflected in the two mirrors by means of a telescope, R. The image should appear straight and unbroken, one mirror being adjusted to secure this if necessary. If, now, the tube flashing with the clock beats, the pendulum is set in vibration, the two parts of the image of the flash made by the mirrors will appear discontinu- ous except when the two pendulums coincide ; this coincidence is thus determined by noting that flash which gives a perfectly continuous image. When this method is used with the reversible pendulum in addition to the mirror on the support, two are required on the pendulum, one near each knife-edge. A numerical example is given of the determination of the period of a pendulum to be used in Exercise LIV. 90 MECHANICS Period of a Pendulum; Mendenhall's Method Time from Standard Self-winding Clock Jii^y 26, 1902 An auxiliary pendulum was compared with the standard clock. Pen- dulum gaining: as nearly as can be judged, it makes 14 vibrations in 13. seconds. COINCinENCES 5h 26" 108 Number of Inteb- vals between Obsekvations 27 15 5 29 14 9 Period 30 30 40 09 6 10 ' = 16 858 — \ 32 36 858 + 66 38 33 11 40 28 _9 Interval 14™ 188 = 858= Total 66 0.9286 s XXVI. GRAVITY BY FREE FALL Determine the acceleration of gravity by observing a freely falling body. 70. Freely Falling Body. — An iron ball is supported by an electromagnet and released by a key which also records a signal upon an electric high-speed chronograph (Art. 68) or upon a tuning-fork chronograph (Art. 71). A contact piece is placed below by which a second signal is recorded when the ball strikes, thus permitting the time of fall to be determined. The contact may be placed at several known distances below the starting point of the ball, as 100, 200, and 300 cm ; and with the results the equations of accelerated motion given in Art. 59 may be verified. The method is more useful for a ball dropped from the top of a tall shaft, the acceleration of gravity being directly obtained. The distance fallen is measured with a steel tape, the temperature correction being applied. If I is the distance fallen in the time t, the acceleration of gravity is 2 ; .9 = l2-- THE TUNING-FORK CHEONOGRAPH 91 71. The Tuning-Fork Chronograph For accurately deter- mining an interval of time not exceeding a few seconds in duration, the tuning-fork chronograph is suitable. It is a machine by means of which a piece of smoked paper is moved under a style attached to one prong of a tuning fork of known vibration number, the vibrations of the fork causing the style to trace a sinuous line upon the paper. The paper may be attached to the surface of a rotating cylinder or may be in the form of a ribbon upon reels. There are two methods by which an obser- vation may be recorded. The cylinder and the fork may be connected to the terminals of the secondary circuit of an induction ^'''- ^^- Record of Tuning-Fork -1 .!_ . 1 • Chronograph coil, so that makmg or breaking the primary circuit causes a spark to pass from the style through the paper to the cylinder, producing a record. Or a second style attached to the armature of an electromagnet may trace a line beside the sinuous mark of the fork, and making or breaking the circuit through this magnet will produce an inden- tation in the line. Fig. 39 shows such a record made by an instrument having two recording styles, one on either side of the fork. Lines are drawn from the notches on one side of the wave to those on the other side; by counting the number of waves between two cross lines, the time interval is determined with great precision. A fork commonly used giyes one hundred complete vibra- tions per second, and is maintained in motion automatically by an electromagnetic attachment. The paper may be moved by clockwork, by hand, or in any other convenient manner. Uniform motion is desirable but not essential. In the absence of a tuning-fork chronograph, a pen chrono- graph, arranged for a high-speed rotation of the cylinder, may be used (Art. 68). 72. Smoked Pap'er and Glass. — Glass or paper may be smoked, as is required in many experiments, by passing it through the smoking flame of a candle or, better, by holding it in the, smoke 92 MECHANICS produced by burning camphor gum. Usually a very thin coating is preferable to a thick one. A paper ribbon may be conveniently smoked by passing it over the surface of a brass cylinder iilled with cold water, while a smoking kerosene flame plays against it. The water absorbs the heat, preventing burning and condensing the smoke. CHAPTER IV ELASTICITY, AISTD PROPEETIES OF MATTER XXVn. YOUNG'S MODULUS BY STRETCHING (a) Determine the modulus of elasticity and the elastic limit of a short iron wire. (b) Determine the modulus of elasticity of a long steel wire. 73. Coefficients of Elasticity. — The elasticity of an isotropic body under any form of stress may be described with the aid of two coeificients or moduli of elasticity, the modulus of bulk elasticity, the reciprocal of which is the compressibility, and the modulus of elasticity of shape or the modulus of rigidity. Only solids possess the latter form of elasticity, hence rigidity is chiefly used in describing them ; the modulus of bulk elasticity is used for fluids, though it applies also to solids. Besides the above a somewhat simpler modulus is frequently employed, called Young's modulus; it is the modulus for simple longitudinal strain, in which change of lateral dimensions is not considered. Each modulus is measured by the ratio of the applied stress to the resulting strain. The bulk modulus is denoted by K, the modulus of rigidity by -B,,and Young's modulus by M. When a varying stress not exceeding a certain limit is applied to a solid, the resulting strain is proportional to the stress. That limiting value of the stress beyond which the strain is no longer proportional to the stress is called the elastic limit of the substance. A body subjected to a stress greater than the elastic limit is permanently deformed. 74. Young's Modulus and Elastic Limit. — Attach the wire to be tested to a comparator, in the manner shown in Fig 40. The 93 94 MECHANICS wire is held at one end by a firm screw, S, which permits of longitudinal adjustment; while the other end is attached to a right-angled arm in order that the weight of a load, F, placed in the pan shall be transmitted as a horizontal stress on the wire. Sufficient load should be placed in the pan to take the kinks out of the wire. An index microscope, X, is adjusted upon a fine mark placed near the end of the wire, and a micrometer microscope, M, is set upon a mark at the other end, about a meter distant. Note the reading of the micrometer microscope. Place a weight, for instance a kilogram, in the pan ; readjust the mark under the index microscope by the screw S, set the microm- eter microscope again on the mark, and note reading. The 5 -^iT l|nni i"i&. 40. Apparatus fob MEASnEiuG Elongation J^ difference between the first and second readings will give the elongation produced in the length of wire between the two marks by a weight of one kilogram. Remove the kilogram, readjust the screw, and repeat the zero reading. Make the load two kilograms, then one kilogram; three kilo- grams, and then two ; adjusting the screw S, and observing the elongation produced in each case. In this manner increase the load a kilogram at a time, removing the last added kilogram to determine whether the wire has been permanently stretched. Continue until the elastic limit is reached. Plot the results, the abscissae representing the stresses, and the ordinates the strains. From the observations within the elastic limit find the elon- gation produced by each kilogram of change in the load. YOUNG'S MODULUS 95 expressing the mean value in centimeters (Art. 21). This is the quantity s of the formula, and F is the load producing the stretch, in this case 1000 g. Measure a number (ten) of diam- eters of the wire in different directions and in different parts, and let r be the mean radius. With a meter bar placed upon the table of the comparator determine the original length, I, of the wire between the marks. Fa Then the stress in dynes per square centimeter is -—, and g the strain per unit length is -• Young's modulus is Trr" M _ stress _ Fgl strain The report may be in the following form. Young's MoDtri.us or Annealed Iron Wike WITH A MICEOMETER-MICKOSCOPE COMPARATOE August 15, 1902 Loads, grams Eeadings Averages Elongatioks Diameters 2100 + 1st 2(1 Turns per 1000 g cm 0.00 0.08 0.04 1000 2.67 2.69 2.68 2.64 0.0568 2000 5.63 5.50 5.56 2.88 9 3000 8.62 8.50 8.56 3.00 5 4000 11.72 11.84 11.78 3.22 9 5000 14.66 14.60 14.63 2.85 5 6000 17.46 17.44 17.45 2.82 8 7000 20.36 20.41 .20.39 2.94 6 8000 23.69 61.4 elastic limit 7 9000 61.4 9 10000 wire broke 6 Means 2.907 0.0567 96 MECHANICS Micrometer microscope, No. 2, 169.7 turns per cm. 2 907 Elongation, s = 7^777-;^ = 0.01712 cm. Load, F= 1000 g. Radius, 169.7 r = 0.0284 cm. M= — = 2.02 X 1012. irr's Length, Z = 89.3 cm. 10.000 Load grams — ^ n ■^ ^~ '~~ ~ r— V~ , ~ "~ ~ ^ ^ ■" SiOOO "~ ^ — ^ ^ ~~ ~^ ^ ■* _ ( ) 1 El on 9" ion 20 Turns 0/ Screw Plot of the Observations 75. Young's Modulus with a Suspended Wire and Scale. — Suspend from the same support two pieces of wire, each from 3 m to 10 m long, and to one piece attach at its lower end a millimeter scale and a small weight to keep it stretched. To the other wire fasten a vernier arranged to move over the scale, and below all a pan for weights. Measure with a steel tape the length of the wire to be stretched when there is suf- ficient weight in the pan to keep it straight. Then proceed to determine the elongation produced by the successive addition of weights in the manner described in the preceding article. The modulus of elasticity is calculated by the same formula. Refebence. — Glazehrook and, Shaw, Practical Physics, p. 141. 76. Young's Modulus with the Cathetometer. — Suspend ver- tically from a firm support a wire about a meter long, to the lower end of which is attached a pan for weights. The elon- gation produced by the addition of weights is then measured with the cathetometer (Art. 77), having one or two reading telescopes. Needles may be fastened to the wire with wax, to serve as indices. The method of procedure and calculation is as described in Art. 74. Reference. — Nichols, A Laboratory Manual of Physics, Vol. I, p. 74. THE CATHETOMETER 97 ^ 77. Adjustment of the Cathetometer A cathetometer (Fig. 41) is essentially a vertical scale carrying a horizontal telescope capable of motion up and down, the amount of this motion being determined by a vernier attached to the telescope. The follow- ing are the adjustments usually required. The second and third, having once been carefully made, should not thereafter be dis- turbed, so that ordinarily it is necessary only, to adjust for parallax, to set the scale vertical and the telescope horizontal. To adjust for Parallax. — Adjust the sliding eyepiece until the cross wires are seen with perfect distinctness ; then focus by the rack and pinion, or long draw tube, upon the ob- ject or mark. If, now, a motion of the eye produces a relative motion of the cross wires and the image of the object, the preceding adjustments must be altered and the process repeated until no such motion is produced by moving the eye, and both the cross wires and object are seen distinctly. To adjust the Line of Collimation. — Set the cross wires exactly upon some well-defined point, and rotate the telescope upon its own axis. If the cross wires move away from the point, they mtist be brought back partly by adjusting the reticule held by small screws in the eyepiece and partly by altering the direc- tion of the telescope. Repeat this process until the cross wires remain exactly upon the point during a complete rotation of the telescope. To set the Level Parallel to the Optical Axis of the Telescope. — Move the telescope until the level bubble is central. Reverse the telescope with the attached level in its Y's. If the bubble is not central it must be made so, partly by means of the screws that attach it to the telescope and partly by moving the whole telescope. Repeat this operation until the bubble remains cen- tral, when the telescope is reversed. Fig. 41 Cathetometer 98 MECHANICS To set the Scale Vertical and the Telescope Horizontal. — Turn the column till the level is parallel to the line joining two of the leveling screws in the base, and make the bubble central. Turn the column through 180°, and if the telescope is not level, adjust it, partly by means of the leveling screws and partly by altering the angle between telescope- and scale. Turn the col- umn through 90° and level by the third leveling screw. Repeat the whole process until the bubble remains central during an entire revolution of the column. Reference. — Stewart and Gee, Practical Physics, Vol. I, pp. 27-35. XXVIII. MODULUS OF ELASTICITY BY FLEXURE Determine the modulus of elasticity of a rectangular steel bar when it is resting on its broader side; also when resting on its edge. Make the same measurements for a wood bar. Find the modulus of elasticity of a round brass rod. 78. Flexure of a Rectangular Bar supported at Both Ends. — The ends of the bar are supported upon knife-edges resting on MODULUS OF RIGIDITY 99 a rigid bedplate, as shown in Fig. 42. Midway between the knife-edges there hangs upon the bar a hook or pan for carrying weights. Above the bar, supported by this hook, is a divided scale or a fine wire, which serves as an index. Attached to the bedplate is an adjustable microscope with which the flexure may be measured. Adjust the microscope and observe the reading. Add a weight (500 g, more or less, according to the strength of the beam) and determine the flexure produced; add weights, one at a time untU. five have been used, observing the increase of flexure produced by each one. Let P be the value of each of the weights expressed in grams, F the average deflection produced by this load in its successive additions expressed in centimeters, L the. distance between the supports of the bar, a the vertical dimension of the cross section of the bar, and h the horizontal dimension ; then the modulus of elasticity of the bar is p rs M^—^ — 4:Fa^ 79. Bar supported at One End ; Cylindrical Bar. — If the bar is fixed at one end and the weight is applied at the other end, the modulus is a p^jz ^= ^• Fa% If the section of the bar in either case is a circle of radius r, instead of a% substitute 3 Trr*. Keperences. — Stewart and Gee, Practical Physics, Vol. I, pp. 179-186; KoMrausch, Physical Measurements, pp. 128-130. XXIX. COEFFICIENT OF RIGIDITY WITH THE TORSION LATHE Determine the coeflBcients of rigidity of one- steel rod and of two brass rods of different diameters. 80. The Modulus of Rigidity. — When a substance is in the form of a solid rod its modulus of rigidity may be determined from measures of its torsion. If a rod of length I and radius r 100 MECHANICS is twisted through an angle 6 (radians) by a couple C (gram- centimeters), the modulus of rigidity is 2gCl E- Ti^e Clamp the ends of a metal rod, from 3 mm to 6 mm in diam- eter, in the chucks of the torsion lathe, so that the length of the rod to be twisted shall be about a meter. One chuck is rigidly attached to the base, while the other is capable of rotation about the axis of the rod by means of a large pulley (Fig. 43), the amount of rotation being determined by a divided circle. This circle may be divided into two hundred parts, when, since the circumference equals 2 ir radians, each division is 0.01 tt radians. Apparatus fob Measuring Torsion Place a 500 g weight in each of the two pans, which are attached by cords to the pulley so that they act as a couple to twist the rod. Observe the amount of twist produced. To eliminate the effects of friction disturb the cii-cle from its posi- tion of rest several (five) times, reading its indications each time, and take the average position as a single measure. Add a second 500 g weight to each pan, then a third, and then remove the weights one at a time ; determine the twist resulting from each change of couple. Find the average effect. The. couple is measured by the mass, 1000 g as described, multiplied by the radius of the pulley. Rods of the same material, of equal lengths but of different radii, of the same radius but of different lengths, and rods of various materials, should be experimented with. In this manner all the laws of torsion and rigidity may be demonstrated. 81. Simple Torsion Apparatus The laws of torsion may be illustrated by simple apparatus, the rod or wire being suspended TORSION AND RIGIDITY 101 m> MP CZ) vertically in a firm clamp, which is attached to the wall or sup- ported on a tripod. To the bottom is fastened a heavy weight carrying a pointer moving over a divided circle of paper (Fig. 44). Two spring balances or weights are attached to cords passing around the weight, acting as a couple, of any desired moment, tending to twist the wire. Pointers attached to the wire by wax and moving over divided circles, placed at various posi- tions along its length, may be used to show that the angle of torsion varies as the length of the wire. To prove the relation of torsion to the radius of the wire, fasten together two pieces of unequal diameter and of equal length, and suspend as before with a pointer attached to the bottom of each piece. The respective angles of torsion should satisfy the formula, 2gCl Tig. 44. Simple Torsion Appakatus = ■Er^ being the angle of torsion of a wire whose length is I, radius r, and rigidity B, which is twisted by a couple C. If is expressed in radians, the modulus of rigidity, S, may be computed as described in the preceding article. XXX. MODULUS OF TORSION BY THE TORSION PENDULUM Determine the modulus of torsion of several wires with the torsion pendulum. 82. Modulus of Torsion. — Suspend a heavy weight of some simple, regular, geometrical shape by a fine wire (Fig. 45), the upper end of the wire being rigidly clamped. Turn the weight 102 MECHANICS through an angle of 30°, twisting the wire, and release it ; it wUl oscillate with a rotary motion, and constitutes a torsion pendu- lum. The formula expressing the condition of vibration is T = 2 7rV-' in which T is the time of a complete vibration, / the moment of inertia of the weight, and r the modulus of torsion of the wire. The time of vibration is to be determined by the method of the following article, and the moment of inertia may be calculated by the formula given in Art. 85. 83, Periodic Time by the Method of Transits. — This method of determining the time of a slow periodic movement is so valuable that it will be described in detail. Adjust a telescope so that the vertical cross wire is seen in the prolongation of the torsion wire and covers an index mark placed on the edge of the disk when it is stationary. Cause the disk to vibrate, stopping any pendular vibration with the hand, and the index will move back and forth in the field of view, crossing the wire twice in each complete vibration. Let one observer, watching the vibration, give the signal "tick" each time the index crosses the wire, for ten successive transits ; while another observer records the time of each signal from a clock, chronometer, or watch, noting the day, hour, minute, second, and tenths of a second. With a clock beating seconds or a chronometer beating half seconds, a single observer can note the time by the eye-and-ear method, observing the index at the second just before and just after transit to assist in estimating the tenths of seconds. Repeat the series of ten readings twice, at intervals of fifteen or twenty minutes, being careful that the disk swings in the same direction at the beginning of each series. , Fig. 45 TOKSION PENDULtrM PERIODIC TIME BY TRANSITS 103 Add together the fifth and sixth times of transit of each set ; also the fourth and seventh, the third and eighth, the second and ninth, and the first and tenth. Divide each sum by two, and average the five quotients of each series. These results will give the times of the middle elongations, or the times when the index was at its greatest distance from the cross wires between the fifth and sixth transits of each series. Dividing the interval between the two middle elongatipns by the number of vibrations win give the periodic time with great accuracy. The number of vibrations may be determined from the observations without the trouble of counting. Between the first and ninth, or second and tenth transits of each set, there were four complete vibra- tions, and this interval divided by four is approximately the periodic time. If all the observations were exact, the period thus found would be exact. To reduce the unavoidable errors of observation it is desirable to find the period from a longer interval. The interval between any two elongations would contain the exact period an integral number of times, provided the disk moved in the same direction at the beginning of each set. The quotient will be a whole number plus a half, if the disk moved in opposite directions. Divide the interval between two elongations by the approximate period; in general the result wiU not be an integer, but will be so near a whole number that there will be no doubt as to the true number of vibrations. Having thus found the number of vibrations in the long interval, the interval divided by this number wiU give a more precise value of the period. The length of time to be allowed between the sets of observa- tions will depend upon the accuracy of the work and the peri- odic time ; other things being equal, the longer the interval the more exact the final result. Two sets of observations are sufii- cient, but it is better to make three, as directed, to guard against errors. If the interval between the first and third sets is too long to give a sure result, one of the shorter intervals can be used. The middle set may also aid in determining the number of vibrations in the long interval. A numerical example of such a determination will illustrate the method. 104 MECHANICS Period of Torsion Pendulum ; Method of Transits Time from Chronometer May 2^, 1895 Transit Time Blongation Transit Time Elosgatiok 1 h m B 2:10: 8.2 1 h m s 2:30:51.3 2 2 : 10 : 14.6 2 2 : 30 : 58.0 3 2 : 10 : 20.8 3 2:31. 4.1 4 2 : 10 : 27.0 4 2 : 31 : 10.5 5 6 2 : 10 : 33.7 2 : 10 : 40.0 h in s 5-6 2:10:36.85 5 6 2:31:16.9 2:31 :23.5 h m s 5-6 2:31:20.20 7 2 : 10 : 46.9 4-7 2:10:36.95 7 2 : 31 : 30.0 4-7 2 : 31 : 20.25 8 2:10:53.0 3-8 2:10:36.90 8 2 : 31 : 36.3 3-8 2:31:20.20 9 2 : 10 : 59.3 2-9 2:10:36.95 9 2 : 31 : 42.4 2-9 2 : 31 : 20.20 10 2 : 11 : 5.6 1-10 2 : 10 : 36.90 10 2:31:48.9 1-10 2:31:20.10 Average 2 : 10: 36.91 Average 2:31 :20.19 The interval between the two sets is 20 m 43.28 s, equail to 1243.28 s. The approxiiliate time of vibration, determined from the first and ninth observations of the first set (51.1 -^ 4), is 12.8 s. 1243.28 H- 12.8 = 97.1+. From this result it is certain that there were 97 vibrations in the interval, which gives the final value of the period, P = 1243.28 -^ 97 = 12.817 s. XXXI. MOMENT OF INERTIA BY THE TORSION PENDULUM Determine the moment of inertia of an irregularly shaped body. 84. Moment of Inertia by Torsion Pendulum If a body is suspended by a wire and caused to vibrate as a torsion pendulum, 47r2' its moment of inertia is MOMENT OF INERTIA 105 T being the period, and t the modulus of torsion of the wire. To determine the moment of inertia of a body, it may be sus- pended by a wire whose modulus of torsion is known (Art. 82), in such a manner that the axis about which the moment of inertia is required shall be in the prolongation of the wire. The system is then made to vibrate as a torsion pendulum, and its period is determined by the method of Art. 83. If the modulus of torsion of the wire is unknown, it will be necessary to make two observations. The period of the pendu- lum is determined when the body, the moment of inertia of which is required, is suspended as described above ; the second observation is for the period of the pendulum when the sus- pended body is one whose moment of inertia is known, by cal- culation from its dimensions (Art. 85) or otherwise. If Jj is the unknown moment of inertia, and Zj the known, and T^ and T^ the respective periods, by elimination between two equations of the previous form, Instead of substituting the body with known moment of inertia for the one whose moment of inertia is to be determined, the former may be added to the latter, and the period of the pendu- lum, consisting of the combined bodies, is determined. Let /j be the unknown moment of inertia, and Jj the known moment of inertia, and Tj the period when the first body only is sus- pended, and Tj^2 ^^ period with the combined bodies; then 7, = /, -^ 1 2 /•n2 _ ya' -' 1 + 2 ^\ 85. Formulae for Moments of Inertia. — The moment of inertia of a solid cylinder about its axis of figure is r being the radius and m the mass. 106 MECHANICS For a hollow cylinder about its axis of figure, the moment of inertia is I=m ^ ^ ^' , rj and r^ being the inner and outer radii of the ring, and m its mass. For a sphere of radius r and mass m, the moment of inertia about a diameter is 2 mr^ . ~b~' The moment of inertia of a parallelopipedon of mass m, about an axis passing through its center of mass and perpendicular to the face whose edges are a and b, is a2 + P Eeference. — Stewart and Gee, Practical Physics, Vol. I, p. 243. XXXII. COMPRESSIBILITY OF A LIQUID WITH THE PIEZOMETER Determine the compressibility of water. 86. The Piezometer. — The compressibility of a liquid may be determined with a piezometer, which consists of a strong glass cylinder (Fig. 46) the ends of which are closed by metal caps, so that when the cylinder is filled with water, a great internal pressure may be produced by means of a screw plug. A glass bulb, B, with a narrow, open stem, is provided for containing the liquid whose compressibility is to be determined. This bulb, a thermometer, T, and a manometer, M, are attached to a suitable support, and during the experiment are placed in the water in the cylinder. It is necessary to know the volume, V, of the liquid experi- mented upon, and the change in volume, v, which is caused by a change in pressure, P. Carefully weigh the bulb when it is THE PIEZOMETEE 107 empty and dry. Then draw into the stem a thread of mercury which is nearly as long as the stem, and measure the length of the thread. Allow the mercury to drop into the bulb, and again weigh to determine the weight of the mercury. Complete the calibration by the method of Art. 52, finding the volume, c, of one centimeter of length of the tube. Now drive the mercury out of the bulb, and fill it and about half of the stem with water. Immerse the bulb in a water bath; notice the temperature and the exact position of the end of the water column in the stem. Wipe the outside of the bulb and again weigh ; by the formulae of Art. 51 find the volume, F, of the bulb. A drop of mercury is placed in the stem for an index, to show the position of the end of the liquid column. The bulb is attached to its support and is placed in the cylinder, which is fiUed with water. The caps are firmly fastened, the vent screw, S, being open. The manometer may be a glass tube, Jf, closed at the top and open at the bottom, which is filled with air while it is placed in the water. The pressure, H, of the air in M is equal to the barometric pressure plus the pressure due to the depth of the water. The latter is expressed in terms of" a mercury column by dividing the distance from S to the bottom of M in centi- meters by 13.6. Observe the position of the mercury index, and the length, I, of the air column in M, and the temperature, t. Close the vent and increase the pressure as much as is con- venient, to 5 or 10 atmospheres for instance. Again observe the length, l,^, of the air column, and the position of the index. The volumes of the air may be taken as proportional to the lengths of the column, a proper allowance being made for the change in shape of the tube where it is sealed. It would be more precise if the tube were graduated and calibrated as to volume. Fig. 46. Piezometer 108 MECHANICS Make ten determinations, and let n be the mean change of the index. Then the apparent change in volume is w = w x c. The change of pressure in dynes is P = ^^.^x 13.6x980. '2 The apparent compressibility is then 7 v PV The pressure in the piezometer will decrease the volume of the bulb, notwithstanding its being open, by the same amount as though it were of solid glass. Hence the observed compres- sion is the difference between that of the liquid and the glass. The real compressibility, at the temperature t°, is k^ being the eompressibiUty of glass, which is 2.6 x 10 ~" per dyne per square centimeter. XXXTTT. BOYLE'S LAW WITH THE U-TUBE Verify Boyle's Law for pressures both greater and less than one atmosphere. 87. Boyle's Law. Pressures greater than One Atmosphere. — An apparatus for verifying Boyle's Law consists of a U-tube about a meter in length, one branch ending in a funnel, the other capable of being closed by a stopcock (Fig. 47). At the bottom is an outlet closed by a stopcock, and between the tubes is a scale. The upper stopcock being open, pour mercury into the tube till it stands at the zero of the scale in both branches ; if too much mercury is introduced, some may be drawn off at the bottom. Close the stopcock at K tightly. Pour mercury in at the funnel till it stands at the height of 10 cm in the open arm. Denote this height by h, and read the height, A', of the column in the left branch. Add mercury to make h 20 cm, and read h'. Continue increasing A by 10 cm at a time till it becomes 100 cm, finding the corresponding values of A'. Then make a set of BOYLE'S LAW 109 K D measures in reversed order, by drawing off mercury at the bottom so that A is 90 cm, 80 cm, etc. The top of the mercury column is represented in each case by the plane tangent to the meniscus. The products of the volumes and the corresponding pressures of the inclosed gas should all be equal provided the temperature has remained constant. The volumes may be taken proportional to the lengths of the tube occupied by the air. Let K be the division of the scale at the top of the inclosed part of the tube (so chosen that it corrects for the distortion of the tube where the stopcock is sealed on) ; then the volumes are represented by K— h'. A further correction may be made by adding a small quantity, e, which represents the volume of air contained between the tangent plane to the mercury meniscus and its actual sur- face. The pressures are equal to the barometer reading plus the differences between heights of the two columns of mercury in the U-tube, P = B + (A — A'). Corrections for the temperature of the mercury are not required if the barometer ajid manometer columns are at nearly the same tem- perature. Record the observations in tabular form (see table on following page), and plot them, using the pressures as abscissae and the volumes as ordinates. Pressures less than One Atmosphere. — With the stopcock, K, open, fill the U-tube with mer- cury till the top of the column is about 10 cm below K. Close X, and read the heights, h and h', of the right and left columns. Draw off mer- cury at the bottom to lower the column h by 10 cm, and record the height h'. Continue lowering A 10 cm at a time till it becomes zero, finding the corresponding values of h'. Repeat the meas- ures by increasing h 10cm at a time till it is again 100 cm. Record and plot as described in the preceding article, the pressures in this case being P = B — (h' — h). Fig. 47 Boyle's Law 110 MECHANICS Other forms of apparatus are frequently used ; for instance, the mercury may be forced from a cistern into the tubes by com- pressed air, or the two tubes may be joined by a flexible tube, or a tube closed at one end may be dipped into a jar of mercury. But with any form the measurements outlined are to be made. h K P=B + (h-h') V=K-K+c PV 10 20 30 100 XXXIV. ERRORS OF AN ANEROID WITH AN AIR PUMP Find the corrections to an aneroid barometer for each centimeter of pres- sure from 65 to 76 cm. 88. Testing the Aneroid Barometer. — The aneroid barometer has the advantage of portability, and if frequently compared with a mercurial barometer and adjusted, it will serve excel- lently for approximate determinations of altitude. The aneroid may be set, by turning the adjusting sprew, so that its reading agrees with that of the mercurial barometer, though this will not be necessary if the error is small. Place it in a receiver (Fig. 48) having a plate-glass cover with a ground joint. The receiver connects through a stopcock with an air pump and with a U-tube -5^ I Aneroid \ mercury manometer. Partially exhaust the receiver till the aneroid indicates exactly an even centimeter (or half-inch) mark on its scale. It may be easier to exhaust a little too much, allowing air slowly to leak in Fio. 48. Testing Aneroid THE ANEROID BAEOMETEE 111 till the pressure is that desired. Read the difference in the level of the mercury columns in the manometer with a scale, or, better, with a cathetometer. The actual pressure on the aneroid is measured by the external barometric pressure less the manom- eter pressure. Both of the quantities should be corrected for the temperature of the mercury; but if the barometer reading is corrected at the beginning, usually appreciable errors wUl not be introduced by neglecting the temperature correction to the manometer. Reduce the pressure till the aneroid indicates the next point on its scale for which the correction is desired, and repeat the observations. Continue until 'Cach point has been tested. If the cover of the receiver is firmly held in place, it will be possible slightly to compress the air and then to test the aneroid at pressures greater than the external atmospheric pressure. The corrections are the quantities which must be added to the aneroid indications to make them equal to the actual pressure. Record the work in tabular form as indicated below, and plot a curve of corrections. The table shows the comparison of an aneroid having an inch scale with a barometer having a centimeter scale. The temperature corrections to an aneroid must be determined empirically ; therefore the table of corrections can only be relied upon for the temperature of the trial, which should be recorded. Calibration op Aneroid No. 1 R February 27, 1902 Barometric reading, 74.30 cm ; « = 2r.6; ^ = 74.04 cm Aneroid Manom, B — Manom. B — iViANOM. C0RKEUT10N.S inches cm cm inches inches 30.00 29.50 29.16 0.00 74.04 29.15 -0.01 29.00 0.43 73.61 28.98 -0.02 28.50 112 MECHANICS XXXV. COEFFICIENT AND LAWS OF FRICTION BY SEVERAL METHODS Determine the coefficients of friction, both static and kinetic, for pine wood sliding on a horizontal cast-iron plane ; determine the kinetic friction when the pressure is increased by one and by two kilograms. Deter- mine the kinetic friction for the same body on an inclined cast-iron plane ; determine the kinetic friction for a brass block sliding on each of its unequal faces upon the inclined plane. Determine the kinetic rolling friction for a wood and a brass cylinder. 89. Coefficient of Friction. — Adjust the friction table so that its surface is horizontal, and place upon it the body to be tested, adding weights to make the total pressure three or more kilo- grams. By means of a cord and weights arranged to pull the block in a horizontal direction (Fig. 49) determine what force Zl ^ ] c Fig. 49. Fkiction Apparatus n. D ft is necessary to start the body from rest. The ratio of this force to the total pressure is the coefficient of static friction. Deter- mine also the force necessary to keep the body in uniform motion after it is started, and the ratio of this to the pressure is the coefficient of kinetic friction. A correction to these obser- vations may be made for the friction of the pulley over which the cord passes, determined as described below. Make a number of experiments with different substances, as pine, oak, iron, and brass, for the sliding body. Also make a series of observations to determine the manner in which the friction increases with the increase in pressure between any two given surfaces, by repeating the observations with the pressure CAPILLARITY 113 increased by one, two, and three kilograms. Represent the results graphically. The work may be simplified by using a spring balance attached to the cord and drawn horizontally. When used in this position a correction must be applied for the index error of the spring balance. The body can be weighed with the spring balance. * Friction on an Inclined Plane. — Place the blocks used in the preceding experiment, loaded as before, upon an inclined plane (Fig. 49) -whose surface is of the same material as that of the horizontal plane. So adjust the angle of inclination that the body starts to slide downward. Then the ratio of the height of the inclined plane to its base, that is the tangent of the angle of inclination, is the coefficient of static friction, which should agree with the result already obtained. The tangent of the angle of iaclination necessary to maintain the body in uniform motion after it is started is the coefficient of kinetic friction. Determine the coefficient of kinetic friction of a brass block the dimensions of which may be 2.5 X 5 x 10 cm, sliding in turn upon each of the three unequal faces. Rolling Friction. — Arrange a cylinder to roll upon a track of two horizontal and parallel bars (Fig. 49). Suspend two equal weights by a cord passing around the cylinder, and by applying additional weights to one side determine the coefficients of static and kinetic rolling friction. Vary the experiment by using different substances ; also use tracks of several materials, and vary the loads in each case. Reference. — Barker, Physics, pp. 81-87. XXXVI. SURFACE TENSION WITH CAPILLARY TUBES Determine the surface tension of water, using three different capillary tubes. 90. Capillarity and Surface Tension. — If a tube is held ver- tically, dipping into a liquid which from the nature of the materials wets the tube, the liquid is drawn upward along the walls of the tube. Since liquids possess surface tension, this 114 MECHANICS effect alone would cause the liquid to rise and fiU the tube to its top, regardless of length or diameter ; but when the liquid rises above the normal surface, gravity begins to act to draw it downward. These two forces are oppositely directed, and tend to stretch the surface of the liquid. It will rise, therefore, only so high that the maximum tension which the surface can exert is counterbalanced by the weight of the liquid lifted. The tension exerted by the surface on a line one centimeter long is called the surface tension, and is designated by T. For a tube of radius r the tension exerted along the circum- ference is 2 irrT. The weight (in dynes) of the liquid column is irr^Mg, h being its height and 8 its density. These two forces are equal. 2 irrT = irr^Sg, from which 2 ■ To correct for the meniscus, h should be measured from the level of the liquid in the outer vessel to a point one third of the radius of the tube above the lowest surface of the meniscus, as indicated in Fig. 50. The tubes may have a diameter varying from 0.1 cm to 0.01 cm. These tubes may be readily drawn from larger ones if those of the desired size are not provided. The radius of the tube required is that at the top of the capillary column ; the tube may be broken at this point after the experiment, and its diam- eter measured with the micrometer microscope. If the tube is of uni- form bore, its radius may be conveniently determined by mercury calibration. The height of the liquid column may be measured with a glass scale or, better, with a cathetometer. The surface tension varies with the temperature; therefore record the temperature of the liquid. 1 T per minute, with a mean temperature difference from that of the room of 6°.2, a gain of 0°.005 per degree per minute. After the iron was introduced the average temperature for the two-minute duration of the experiment was 16°.31, differing from that of the room by 2°.2. Therefore the gain in temperature during the experiment because of absorption is 0°.005 X 2.2 X 2 = 0°.022. The observed temperature change of the calorimeter was 17°.18 — 12°.43 = 4°.75 ; while the iron changed 99°.42 - 17°.18 = 82°.24. The specific heat of the iron is ^ 458.5 X (4.75- 0.02) _p^p3^ 243.2 X 82.24 Radiation Correction when Temperature Change of Calorimeter is Uniform. — In some calorimetric observations the calorimeter changes temperature at a nearly uniform rate (Arts. 147, 148, 149, and 150). If the temperature of the calorimeter at the beginning is as much below the room temperature as at the end it will be above that of the room, the calorimeter will gain about as much heat during the first half of the experiment as it will lose during the second half. When the highest precision is required it may be desirable to verify or correct this assump- tion by determining the heat exchanges for each experiment. Observations are made, as described in the preceding article, to determine the increase in temperature because of absorption. Similar observations made during the time the calorimeter is above room temperature will permit the loss because of radiation to be computed. The algebraic sum of the two effects is the error ; the correction has the same magnitude but the opposite algebraic sign. This method is illustrated in the numerical example given in Art. 150. LXXVn. SPECIFIC HEAT BY BLACK'S METHOD Determine the specific heats of iron, zinc, lead, and brass. 142. Black's Ice Calorimeter. — If the heat given out by a body is caused to melt ice, the quantity of heat may be deter- mined from the mass melted. The calorimeter consists of a THE ICE CALORIMETEE 179 block of ice with a cavity to contain the warmed body and the water produced in cooling, and a cover to prevent loss of heat. The method is both simple and accurate when solid ice, such as manufactured ice, is used. Weigh the body to be tested, which may conveniently be in the shape of a sphere of four centimeters diameter, with a small hook attached by which to lift it. Heat the body to a known temperature in a water or steam bath. A piece of solid ice, selected to be free from air bubbles and cracks, is shaped so that its upper surface is slightly convex. In the middle of this surface make a cavity large enough to contain any ode of the bodies whose specific heat is to be deter- mined. The cavity may be made of the proper size and with a smooth surface, by causing one of the warmed spheres to melt its way into the ice. Provide a smooth slab of ice, slightly con- cave on its under surface, to serve as a cover. The shapes of surfaces suggested are to prevent the water produced by surface melting from running into the cavity. Select a sponge of a size corivenient to wipe out the cavity, moisten it, squeeze it dry, place it in a small beaker, cover with a watch glass, and weigh carefully. Wipe the ice cavity with another sponge, transfer the warmed body to the cavity with the least possible loss of heat, and quickly cover it with the ice slab. As soon as the body has cooled to 0°, which may be in ten minutes under the circumstances described, remove the cover and body, wipe up all the water in the cavity with the weighed sponge, and weigh again to determine the amount of ice melted. If w is the mass of the body, t its temperature when placed in the ice, and M the mass of the ice melted, the specific heat of the substance is 80.1 Jf c = mt 180 HEAT LXXVIII. SPECIFIC HEAT WITH BUNSEN'S ICE CALORIMETER Prepare a Bunsen ice calorimeter and use it to determine the specific heat of copper. 143. Bunsen's Ice Calorimeter. — If the heat given out by a body is caused to melt ice, the quantity of heat may be deter- mined from the change of volume which results. One gram of ice has the volume 1.0908 ccm, while one gram of water at 0° has the volume 1.0002 ccm. The quantity of ice that must be melted to cause a change of 1 ccm in volume is ^.-jy^ o 6 ~ 11'04 g ; and the heat required to melt it is 11.04 x 80.1 = 884 calories. When properly applied this method is not subject to the errors of radiation, and it may be used to measure small and slow thermal changes. It is suitable for determining the specific heat of solids and liquids, and especially when only a small quantity of the substance to be experimented upon is available. The disadvantage of the ^ , , method is the trouble of preparation, and its accuracy is not greater than that of other common methods. The calorimeter is a peculiarly shaped glass vessel (Fig. 68) into which is sealed a tube closed at its inner end, to receive the body to be tested ; this will be called the test tube. Another tube, or stem, leads into the calorimeter; through this the calorimeter is filled with distilled water which has been recently boiled to remove air. Mercury is poured into the stem, dis- placing some of the water, till the stem is wholly filled with mercury, and the lower portion of the body is partially filled, as indicated. Place the calorimeter carefully in crushed ice, which may be conveniently contained in a wooden pail. Pack the ice closely and fill the interstices with ice-cold water. A tube about 30 cm long, the bore of which is iiniform and has a diameter of 0.5 mm, is fitted by a rubber cork or a ground joint Fig. 68. Bdnsen's Ice Calorimeter THE ICE CALOKIMETER 181 into tKe upper end of the stem, so as to steind in a horizontal position. Calibrate this tube with mercury by the method of Art. 52, determining the volume of the bore of the tube per cen- timeter of length. Insert the tube in the stem and push it down tUl it is filled with mercury, taking care that no air remains in the stem between the cork and mercury. When the calorimeter has been packed long enough for the whole to have become cooled to 0°, pour a little ether or carbon bisulphide into the test tube, and rapidly evaporate it by forcing air through it with a foot blower. This will cause some of the water in the body to freeze around the test tube. Since ice has a greater volume than the water from which it is formed, the progress of freezing can be inferred by the flow of mercury from the calorimeter. Continue the freezing until about a cubic centimeter or more of mercury has been forced out. When the carbon bisulphide or ether has all been evaporated or removed, pour into the test tube sufficient water at 0° to half fill it, and place a cork in the mouth. The body whose specific heat is to be determined may be in the form of a wire spiral. Weigh it and heat it in a water bath to the boiling point. If the mercury in the fine tube is moving outward, the water in the body of the calorimeter is freezing, which may be caused by impurities in the packing ice producing a temperature below 0° ; if the mercury is moving inward, the packing is probably imperfect and must be improved ; if the mercury is stationary for fifteen minutes or more, the calorimeter is ready for use. It is often impossible to secure a stationary condition, in which case the rate of motion may be observed and a correction applied for the error thus introduced into the observations. Taking great care to avoid loss of heat, transfer the warmed body to the inside of the test tube ; care is also necessary to prevent breaking the tube. The heat given up by the body as it cools to 0° will melt some of the ice around the test tube, causing a contraction of volume, which is indicated by the inward move- ment of the end of the mercury column in the fine tube. Meas- ure the motion which has thus taken place when the mercury 182 HEAT has become stationary, which may require an hour's tiihe. A scale is often etched upon the tube for making this measure- ment, but a separate scale is equally convenient. If the motion of the mercury column produced by the cool- ing of the body to 0° is I, and v is the volume of unit length of the bore of the tube, the heat given out by the body is 884 Iv calories ; and if m is the mass of the body, and t its temperature when put into the calorimeter, its specific heat is 884 Zv = . mt Refeeences. — Ostwald, Physico-Chemical Measurements, p. 136 ; Eohl- rausch, Physical Measurements, p. 121 ; Preston, Theory of Heat, p. 217; Nicliols, A Laboratory Manual of Physics, Vol. II, p. 237. LXXIX. SPECIFIC HEAT OF A SOLID BY THE METHOD OF MIXTURES Determine the specific heat of aluminum and of iron. 144. Specific Heat by Method of Mixtures. — One of the most useful methods for determining the specific heat of solids and liquids is that known as the method of mixtures. In this method the body to be tested has its heat mixed with the heat of the calorimeter ; usually there is no physical mixture of the substances. In Regnault's apparatus the heating of the body is accom- plished without wetting it. A large vessel to hold steam or hot water has a tubular hole through its middle, passing in either a vertical or inclined direction. The body to be heated is held in the middle of the tube by a string; there are contrivances for stopping the ends of the tube, and a thermometer is passed through the upper stopper, so that its bulb is near the body. The heating is to be continued until the water has been boiling for some time, and the indication of the thermometer is constant. The calorimeter, usually of the form described in Art. 139, is mounted on a small carriage running on a track so that it THE METHOD OF MIXTUKES 183 may be quickly brought under the lower end of the tube through the heater, to receive the warmed body with little loss of heat. A protecting screen should be placed between the heater and the calorimeter. The measurement of a specific heat, with the determination of the heat capacity of the calorimeter and the radiation correc- tion, as described in Arts. 140 and 141, requires the following observations. Weigh the body to be tested and place it in the heater. Weigh the dry calorimeter cup and stirrer, and measure the volume of that part of the thermometer to be used. Pour into the cup sufficient water to cover the body tested when the latter lies on the bottom of the cup, and determine the mass of the water. In order that the radiation correction may be small, the tem- perature of the calorimeter when the body is introduced should be so much below that of the surroundings that the final tem- perature shall be very nearly the same as that of the room. A preliminary trial of the experiment may be made to determine approximately the temperature change that will occur ; or the change to be expected may be calculated from assumed values of the quantities involved. After the body has become thoroughly heated, cool the calorim- eter a little below the temperature desired for the beginning of the test, and make observations of the temperature at inter- vals of a minute to determine the rate of warming. At a noted time observe the temperature of the calorimeter, that of the heated body, and transfer the latter to the calorimeter as quickly as possible and without splashing the water. Remove the calorimeter from the heater. Stir the water and note the temperature at intervals of 20 seconds till it becomes constant, or until it changes uniformly because of radiation or absorption. Continue the temperature observations for several minutes at intervals of a minute, to determine the rate of change. Calcu- late the radiation correction as explained in Art. 141. If K is the heat capacity of the calorimeter, t^ its temperature when the body is introduced, t^ the highest temperature attained 184 HEAT by the calorimeter, B the radiation correction, M the mass of the body being tested, and ^3 its temperature when introduced into the calorimeter, from which c, the specific heat of the substance, is to be calculated. LXXX. SPECIFIC HEAT OF A LIQUID BY THE METHOD OF MIXTURES Make two determinations of the specific heat of glycerin. 145. Specific Heat of Liquids by Method of Mixtures. — The method of mixtures described in the preceding article may be used for determining the specific heat of a liquid, the variations in the details of construction and operation of the calorimeter being mentioned below. The liquid to be tested is placed in a heater, H (Fig. 69), which is supported in a larger vessel in such a manner that it may be entirely surrounded by water. Heating arrangements and a stirrer for the water bath are provided, while a ther- mometer with its bulb in the heater will indicate the tempera- ture of the liquid. If the liquid is not too volatile, the water bath may be boiled ; for very volatile liquids an ice bath or a freezing mixture may be substituted for the hot water, and the variations in procedure required will not need description. In either case the liquid must be left in the bath till the indication of the thermometer is constant. A tube having a suitable stopcock leads from the bottom of the heater through the water bath, and through a double wooden protecting screen, into the calorimeter. The calorimeter cup is supported, inside the usual protecting case, on an adjustable stand. In the interior of the cup, fastened so as to be entirely surrounded by the water of the calorimeter, is a receptacle,- R, for the liquid. The tube from the heater leads into the upper part of this receiver ; while above it, and connected with it by a short tube, is a smaller vessel, C, which serves to condense THE METHOD OF MIXTURES 185 any vapor that may rise from the warm liquid. The condenser opens to the air through a tube. The calorimeter is provided with a finely divided thermometer and a stirrer. The calorimeter cup, with the receptaple, stirrer, etc., are weighed when clean and dry. Sufficient water is then placed in the cup to cover the receptacle and condenser, the mass of the water being deter- mined. To minimize the errors of radiation the calorimeter should be cooled so much be- low the temperature of the room that the final temperature shall be nearly the same as that of the room. If the liquid to be tested is cooled instead of heated, the calorimeter must be warmed at the beginning of the ex- periment. The change in the temperature of the calorimeter to be expected is determined by calculation from , known constants or by I. a preliminary trial of the experiment. When the liquid has become thoroughly heated, cool the calorimeter a little below the temperature desired for the beginning of the test, and make observations of the temperature at intervals of a minute to deter- mine the rate of warming. Place the calorimeter in position to receive the liquid from the heater. At a noted time observe the temperature of the calorimeter and of the liquid, open the stop- cock, and, by air pressure applied to the tube T of the heater. Fig. 69. Apparatus for Specific Heat OP Liquids 186 HEAT , force the liquid quickly into the calorimeter. Remove the calo- rimeter from the heater. Stir the water and note the temper- ature at intervals of 20 seconds tUl it becomes constant or until it changes uniformly because of radiation or absorption. Con- tinue the temperature observations for several minutes at inter- vals of a minute to determine the rate of change. Calculate the radiation correction as explained in Art. 141. Weigh the calorimeter and contents to determine the mass of the liquid which has been tested. If K is the heat capacity of the calorimeter (Art. 140), of incidence i becomes 0°, while the angle of diffraction is at once meas- ured by turning the telescope to the desired spectrum line. The formula then becomes Fig. 104. Relations op X ^ — sin d. Angles fob Gkating '* Measures A transmission grating may also be used in a manner analo- gous to that for a prism (Art 178) by setting it in the position of minimum deviation. The deviation D is directly measured, and since D = i + d, and i = d, the wave length is \ = — sin i- D. n ^ CXIV. WAVE LENGTH WITH THE CONCAVE-GRATING SPECTROSCOPE (a) Assuming the wave lengths of the solar spectrum lines Z>j and F, find the wave lengths of the lines B, C, E, G, and H (second order). (b) Construct a wave length scale for the spectroscope. (c) Photograph the bands of the spectrum of carbon (second order). (d) Find the wave lengths of the principal lines of any assigned spectrum by photographic comparison with the solar spectrum. 190. The Concave-Grating Spectroscope. — If a diffraction grat- ing the lines of which are ruled on a spherical concave reflecting surface is used for spectroscopic observations, the coUimating 25^ LIGHT and view telescopes of the plane-grating spectroscope are not required. The absorption of the lenses is thus avoided, which is an important consideration in some kinds of investigations, and various other advantages are secured. A concave grating is usually mounted at one end of a rigid bar, at the other end of which, exactly at the center of curva- ture of the concave surface, is an eyepiece or photographic plate. An L-shaped track (Fig. 105) is provided with a slit, S, mounted at the angle. The bar is pivoted to wheel supports resting on the tracks, so that the grating G is always over one arm of the L, and the eye- piece S is always over the other arm. As the bar is moved along the tracks in the various possible positions, the grating, eyepiece, and slit will always lie on the circumference of a circle whose diameter is the radius of curva- ture of the grating. As the bar is moved to various positions the several spectra of the light illuminating the slit, which are produced by the grating, are all brought to focus on the cir- cumference of this circle. As the eyepiece is moved along the track the spectra may be observed successively without any other adjustment. This arrangement is especially convenient for photographic investigation, since a sensitized plate may be bent to coincide with the circumference of the circle mentioned, and a consider- able portion of the spectrum may be distinctly photographed at one time. Glass plates about 5 by li inches are used for work with a grating of 6 feet radius ; the camera is arranged to hold the plate bent to the proper radius. Adjustment. — It is to be determined that the two tracks are at right angles, level, and in the same plane, and that the slit Fig. 105. Concave-Grating Spectroscope THE NORMAL SPECTRUM 253 is directly over their intersection and at the height of the grat^ ing center. The instrument having been properly constructed, and once mounted and adjusted, will presumably not require alteration of these relations. Place the grating, with the lines vertical, in its support at one end of the bar, and, with a collimating eyepiece at the other end, adjust the inclination of the grating and the length of the bar until the cross wires of the eyepiece are exactly at the center of curvature of the mirror. This is shown by the coin- cidence of the direct and reflected images of the cross wires and by the absence of parallax. The slit being illuminated, as the diagonal bar is moved along the tracks the several spectra should be seen in the center of the field. If they rise or fall in the field of view, it indicates imperfect mechanical construction as regards the surfaces of the tracks, or the pivots which join the bar to the wheels. It may be necessary to sacrifice the perfection of the previous adjustment by altering the inclination of the grating until the spectra may be seen throughout the required motion of the diagonal bar. The slit being narrow, it is to be made accurately parallel to the lines of the grating by rotating it until the definition of the spectral lines is the best possible. It should be ascertained, when the camera is substituted for the eyepiece, that the plate coincides exactly with the previous position of the cross wires, and that it is perpendicular to the radius of curvature of the grating. 191. Normal Diffraction Spectrum Diffraction spectra pos- sess the great advantage over prismatic spectra that the devia- tion is proportional to the wave length and to the order of the spectrum. For different gratings the deviation varies inversely as the grating space. Thus all the spectra of any given sub- stance produced by different gratings are exactly similar, and may differ only in relative size. This is not true of spectra pro- duced by other means. A disadvantage of diffraction spectra is the small intensity of illumination. The deviation being proportional to the wave length, the comparison of wave lengths, with moderate precision, is reduced 254 LIGHT to a comparison of lengths. By measuring the distance between two known lines, the value of the scale in wave lengths is deter- mined ; the wave length of an unknown line is then found by measuring its distance from one of the standard lines. The value of the scale is inversely as the order of the spectrum ; for instance, the distance between two given lines is twice as great in the second-order spectrum as in the first. The first-order spectrum is separate from the others, but the red of the second order overlaps the violet of the third, and in the higher orders the overlapping increases. Sometimes a screen of colored glass or gelatine may be convenient for sepa- rating the different spectra; for instance, if the overlapped second- and third-order spectra be observed through a red glass, the violet light is absorbed while the second-order red is seen distinctly. References. — Preston, Theory ol Light, pp. 226-242; Scheiner, Astro- nomical Spectroscopy, p. 52. CHAPTER XVIII THE INTEEFEEOMETEE, CXV. SMALL LENGTHS WITH THE INTERFEROMETER (a) Determine the distance between the two planes of an optical standard of length. (b) Determine the length of a division of a scale which is nominally one tenth of a millimeter. 192. The Interferometer. — Perhaps the most precise method for measuring small distances and displacements is by means of the interferometer devised by Michelson. The measurements are made in terms of the wave length of light as a unit, and displacements as small as ^-^ of a wave length may be meas- ured. The interferom- eter consists essentially of a half-silvered mir- ror, ff (Fig. 106), which divides incident light from a source, S, into two beams, one of which is reflected to a fixed mirror, Jfj, and back, the other is trans- mitted to a movable „;,„^ ,»- J T ,1, Fig. 106. Plan of Interferometer mirror, M^, and back. The two beams which have returned to the half-silvered glass are each partially transmitted or reflected to the observer in the direction 0. The beam to M^ passes twice through the glass plate supporting the half-silvered film, and to render the paths of the two beams optically equal the beam to M-^ is caused to 255 Jtfp 256 LIGHT pass twice through a parallel clear glass plate, C, of the same thickness as H; this is called the compensating glass, and it may have any convenient position between H and M-^. Let the light falling on H be parallel, and the mirrors M^ and M^ perpendicular to the incident rays. If, then, the paths of the two beams between separation and reunion differ by any odd number of half wave lengths (including the phase difference introduced by one internal and one external reflection), upon reunion at H there will result interference, and no light will be sent to 0. There is evidently an indefinite series of positions of M^, with half wave-length intervals, which produce interference; while whenever M^ is midway between any two positions of this series, there will be reenforcement of the two beams, with illumination in the direction 0. If M^ moves slowly and continuously, one may count the number of times it passes through an interference position, and thus determine the distance moved. Instead of adjusting the mirror M^ so that its entire surface is in one interference plane of the series mentioned, it is usual to give it a slight inclination, about 30" of arc, so that it cuts across several planes, as shown in vertical projection in Fig. 107. If the plate is observed in the direction of the arrow, as is done in the inter- ferometer, it is seen (as represented in Fig. 108) crossed by a series of parallel bands, which represent the intersection of the plate with the series of interference planes. Further, if the plate is moved parallel to itself in the direction of the arrow, the band Fig. 107. Mikeor intek- representing intersection with any one the edge a to the edge b. Let band No. 4, for instance, be over an index mark (a cross scratched in the silvering) on the surface of the plate ; as the plate is moved this band will move toward h, and when band No. 5 has moved to the index, the plate has evidently been moved THE INTEEFEROMETER 257 one half a wave length ; if the motion has caused a displacement of the bands of 0.7 of the distance between bands, the plate has been moved 0.7 -, \ being the wave 7 6 5 4 3 2 1 length of the light employed (Art. 196). Or, in general, if during the motion a number of bands pass the index (whole and fractions) equal to w, the distance moved, in centimeters, is Fig. 108. Field of View OF Intekferometer If the inclination of the plate is slight, it cuts few planes, and the bands appear to be far apart. The distance between them may be such that it is possible to estimate a hundredth part of this distance, and thus to measure a displacement of M^ of -^-^ of a wave length. The measurement of a fraction of a band depends upon the fact that a slight change in the inclination of the compensating glass displaces the system of bands. This glass is mounted on a flexible support so that a micrometer screw, F (Fig. 109), pressing against a spring, alters this inclina- tion. By trial the amount by which the screw must be turned to displace the system by the width of one band is determined, thus facilitating the measurement of fractions. The influence of the inclination of the mirror M^ upon the simple theory of interference outlined need not be considered here, since it does not alter the practical conclusions. If, instead of the linear change in the path of either beam described, there is a variation of any optical property of a medium which the light traverses between the separation and reunion, such as an alteration in density, the result is a displacement of the bands. To measurements of this kind, and others which cannot be described, the interferometer is especially adapted ; its range of application to physical investigations is very wide. References. — Michelsoyi,, Philosophical Magazine, Vol. 13, pp. 236-242, 1882 ; Morlev, Physical Review, Vol. 4, pp. 3-22, 1897 ; Wadsworth, Physical Review, Vol. 4, pp. 480^91, 1897 ; Shedd, Physical Review, Vol. 11, pp. 304- 315, 1900 ; Michelson, Light Waves and Their Uses. 258 LIGHT 193. Finding the Interference Bands. Monochromatic LigM. — It is assumed that the interferometer has been properly con- structed so that the diagonal glasses H and C(Fig. 109) are held vertical, parallel, and in the direction of the bisector of the angle between the two mirrors M-^ and M^, to the degree of precision ordinarily attained in machine-shop practice. All the glasses may be provided with adjusting screws, though it is usual to have only one mirror, Jlfj, so arranged. To protect the instrument against vibrations it is best supported on a properly constructed pier ; but it is usually suificient to place it on any table, resting the feet of the instrument on soft rubber corks. Notice that the half-silvered side of H is toward the compensator. Turn the lead screw by the han- dle L to make the distance of M^ from the silver film H. the same as that of M^. A scale with index, J, may indi- cate this position ; if not, measure with a compass or scale from any point on the edge of the silvered surface of H to My, and set M^ at an equal distance from the same point of H. Place a sodium or other monochromatic light near the focus of a lens so that an approximately parallel beam of light shall illuminate the whole of the half-silvered film, as shown in Fig. 106. Since the interferometer is a symmetrical device, the light may enter in the direction Oilfj, and the bands be observed in the direction SM^^ without in any way altering the phenomena ; either arrangement may be adopted according to convenience or chance. Place fine wires or threads over the surface of the lens to mark its horizontal and vertical diameters. Fig. 109. Interfekometeu THE INTEEFEROMETEK 259 Look towards the interferometer in the direction OMp and alter the position of the light or lens, and also of the diagonal mirror IF if necessary, to cause the entire surface of the mirror to be evenly illuminated. Usually there will also be visible three images of the cross wires, the third image being due to the reflection from the unsilvered side of the glass H. By slightly altering the inclination of the adjustable mirror (Jfj or M^) in its frame, either one cross will move and two will be stationary, or two will move and one will be stationary. The odd image must be brought into exact coincidence with one of the pair; which one might be determined by simple theory, but usually trial gives the quickest solution. Having produced coincidence between two of the images, and after the vibration of the appa- ratus caused by touching the screws has subsided, the interfer- ence bands may be visible. Search for them by moving the eye farther from or nearer to the mirrors, and by moving it cross- ways. If they are not readily found, adjust the mirror to bring the odd image of the cross into coincidence with the second one of the pair. If the bands cannot be found now, the setting of M^ ^t a distance from H equal to the distance of M^ was not sufficiently exact. Turn the screw to move M^ a fifth of a millimeter in one direction or the other, and repeat the search for the bands as described. Having found the bands, they may be given any direction and any width by further careful adjustment of the inclination of the mirror. Usually they should be made vertical and of such a width that from five to ten bands are visible at one time. Trial will best indicate what particular movements to give to the mirror. ' Bands in White Light. — Two beams of light of mixed wave lengths (white light) will ordinarily produce interference phe- nomena only when the relative retardation is a small number of wave lengths, not over thirty. To obtain bands in the inter- ferometer with white light, the distance of M^ from H may not differ from that of M^ by more than fifteen wave lengths, a quantity less than a hundredth of a millimeter. Having found the bands with sodium light, as explained above, by means 260 LIGHT of the slow- motion screw S move the mirror M^ so slowly that the bands may be distinctly seen as they pass across the field. Examination will show that the distinctness of the bands suffers periodic changes, there being about a thousand bands in each group. These changes result from the fact that sodium light consists of two wave lengths which differ from each other about one part in a thousand. The combination produces fluc- tuations analogous to beats in sound. Further, the bands in the middle of one particular group will be found more distinct than those in any other group on either side. Set the mirror in this position of greatest maximum distinctness by quick estimation ; it is then nearly in the position giving equality of paths to the two beams. Place a luminous gas flame, or other source of white light, just beyond the sodium flame without disturbing the latter ; regulate the intensity of the white light until the sodium bands are seen very faintly, perhaps in one portion of the field only. Obsei-ving the mirror carefully, slowly move M^ one way or the other till the group of brilliantly colored bands due to white light is found. Care must be taken that the motion is not so rapid that the bands pass through the field unobserved ; the faintly visible sodium bands permit the control of the speed. If the colored bands are not readily found, it may be that the wrong group has been selected ; therefore search in the middle of the next group on either side of the one first tried. With experience one may find the bands in white light cer- tainly and more expeditiously by using the handle L, instead of the slow-motion screw, for making these settings. Another criterion for finding the colored bands is as follows. Usually the bands with monochromatic light appear more or less curved. A motion of the screw L in one direction increases this curvature, while an opposite motion decreases it till the bands appear straight, and a continued movement gives them a curvature in the opposite direction. The position where the curvature changes — that is, where the bands are straight — is the one near which the colored bands will be found. Search for them with white light as described. THE INTERFEROMETER 261 The middle band of the colored group is black. It corre- sponds to light which has moved over paths of equal lengths, but for which interference and not reenforcement takes place because of the phase difference introduced by the reflection of one part internally and the other part externally at the silver film H. This center black band is the only one that can be identified ; it is therefore taken as a starting point in making measurements. 194. Circular Bands. — If the movement of the mirror M^ required in any measurement is small, — a millimeter or less, for instance, — the straight bands described above are most con- venient for observation. But when a much greater difference of path of the two beams is necessary, circular fringes are more suit- able. They are produced when the mirrors Jfj and M^ are both exactly perpendicular to the incident light. The bands are con- centric circles ; a motion of M^ causes them to enlarge and dis- appear, while new ones continually form at the center, or else they contract and vanish at the center. The center therefore appears alternately light and dark, in accordance with the first simple explanation. As the path to M^ becomes more nearly equal to that to JIfj, the circles enlarge in size, and finally the center of the system covers the entire plate. This is therefore the position near which colored fringes may be iound. In finding the circular bands it is convenient to begin by making the path to M^ differ from that to Jfj by a thousand or more wave lengths, as then the circles will be smaller and several may be seen at once. The inclination of ^^-^^^ the adjustable mirror is then to be changed so as f^^^\^p to increase the curvature of the bands until they become circles, with the center in the center of the field of view. These circles ^^ ^ may be conveniently observed with a | telescope focused for distant obiects. „ ,,„ ^ '- Fig. 110. Intekfekential 195. Counting Frmges. — For the pur- s^^^„^„„ ^^ ^^^^^^ pose of laboratory exercises an optical standard of length of about 0.1 mm is desirable. This consists of a solid metal support carrying two plane-parallel plates of equal thickness, Pj and P^ (Fig. 110). Each plate rests against 262 LIGHT three projecting points, with which it is kept in contact by suit- able springs. The points against which Pj rests are shorter than those for P^ by about a tenth of a millimeter, and they are adjusted by careful grinding so that the front surfaces of the plates are accurately parallel. A cross scratched through the silvering in the center of each plate serves as an index. The mirror M^ of the interferometer is removed, and the standard is substituted for it. With sodium light the adjust- ments are made so that the fringes are seen from both plates at once. The fringes of the two sets should be of about the same width, and in the same general direction, preferably vertical. With white light find the colored system of fringes on one plate, as Pj, and bring the black fringe exactly to the cross mark. Illuminate with sodium light and give attention to the fringes from plate P^. Having previously determined the direction in which the bands will be displaced when the plate P^ is brought toward the plane in which P^ is now set, turn the fraction-screw F to displace the bands in this direction until the center of the first dark band to come to the cross is exactly on the mark. Thus the first fraction of a band is measured. Then from this position as zero the slow-motion screw S is slowly turned, and the bands are counted as they pass the mark. It is convenient to count ten bands, then to take a new hold on the screw, to count ten more, and thus to continue until a number has been counted which is perhaps five less than the supposed number in the length being measured. Substitute white light. If the system of colored fringes is not in sight, count five more bands with sodium light, and again look for the bands in white light. Continue the count until the colored system is found and the central black band is on the cross mark. If the colored system is not found, either to6 many bands were counted before search was made with white light, or the screw may have been turned in the wrong direction.' The number of whole fringes plus the first fraction is the length required expressed in half wave lengths of the mono- chromatic light employed. MONOCHEOMATIC LIGHT 263 To give definite direction to the line of sight a telescope is convenient; but the cross wires in the eyepiece must not be used as the index for counting, — the marks on the surfaces of the plates sefve better. The slow-motion screw may be extended to the telescope by means of a glass tube, connected to the screw by a short piece of rubber tube to prevent the communication of vibrations to the instrument. The count may be interrupted to rest the eye. Stopcocks for controlling the gas may be placed within reach of the observer, so that either monochromatic or white light may be used at will. 196. Monochromatic Light. Sodium Light. — The ordinary laboratory requirements for monochromatic light are fulfilled by placing some common salt held in a platinum wire loop or gauze basket in the edge of a Bunsen flame, where it is vaporized and rendered incandescent. The sodium light which results is not of great intensity, but it may be made of large surface. The light is made steady, and somewhat more intense, by placing an iron chimney over the flame, as indicated in Fig. Ill, which shows a convenient form of sodium lamp. Instead of salt, borax may be fused into the platinum wire loop. Sodium light consists of two principal wave lengths, Rowland's values for which are Z>i = 0.00005896154 cm, and Da = 0.00005890182 cm. It is not possible to separate these two com- ponents of sodium light in large surface illu- mination, and the wave length may be taken as the mean, 0.00005893 cm. Mercury Light. — A light which is more nearly monochromatic and at the same time of greater intensity is obtained from the mercury arc lamp. The essential part of the lamp is a fl -shaped vacuum chamber (Fig. 112) con- taining mercury. By means of platinum wires the mercury in the interior is connected to two mercury cups, which receive the Fig. Ill Sodium Lamp .264 LIGHT terminals of an electric circuit. The quantity of mercury in the branches of the chamber may be so adjusted that the two portions are separated by a small space. By gentle shaking the two portions may be made to touch, and as they separate an electric arc is formed which vaporizes the mercury and emits a brilliant greenish- white light. The current required is of from 6 to 10 amperes, and from 24 to 32 volts. By immersing the lamp in a water bath, it can be operated for hours without interruption. The mercury light consists of several wave lengths which, however, may be readily separated by a prism. The green portion is the most useful, and its wave length according to Fabry and Perot is 0.0000546074 cm. -Michelson describes in Travaux et MSmoireB du Bureau International des Poids et Mesures, Tome XI, a lamp in which metallic cadmium is vaporized with a Bunsen burner, and then rendered incandescent by the electric spark. By pris- matic analysis a red light of great purity is obtained, the wave length of which is perhaps determined with gi-eater precision than that of any other light. The wave length of this red cadmium light is 0.00006438472 cm. Fig. 112. Mercury Akc Lamp Cadmium Light. ■ CXVI. PLANE SURFACES BY OPTICAL METHODS Test the surfaces of a prism for flatness, and the two surfaces of a glass plate for plane parallelism. 197. Plane and Plane-Parallel Surfaces. — The surfaces of prisms, of the plates used in interference experiments, some surfaces of lenses and of other optical plates are required to be optically plane. The skill of the optician is such that the sur- face of a firs1>quality plate will not deviate from a true plane by more than a tenth or a twentieth of a wave length of light. A PLANE SURFACES 265 plane-parallel plate is one the two surfaces of which are accu- rately plane and parallel to each other. When two plane-parallel plates of equal thickness are required they are constructed in one piece, which is afterwards cut. Plane Surfaces are conveniently tested only by optical com- parison with a test true plane. This true plane is made by the optician by grinding three planes together until they fit, two and two, in all positions. Such a true plane being available, it is placed upon the surface to be tested; the surface of contact is illuminated with sodium light by transmission through either plate as is convenient. Before the plates are brought into contact the two surfaces should be freed from dust and dirt, both to avoid injury to the surfaces and to permit proper contact. To light the entire sur- face a sodium flame is placed in the focus of a large lens, so arranged that the bundle of parallel rays produced falls on the surfaces and is then reflected to the eye. Fig. 113 shows the arrangement for testing a prism. Interference bands should appear over the entire surface. If both surfaces are plane, these bands are straight, parallel, and equidistant. If the plates are pressed closely together, the bands will be far apart and a very small depar- ture from planeness may be discovered. A width of bands of from five to ten millimeters ^ ,,„ ,„ t, Fio. 113. Testing a Plane IS most useful. After the Surface plates have been placed in contact they must be left till they have come to a uniform temperature throughout before the testing can be relied upon. The form of the surface being tested may be inferred from the interference pattern exhibited, since a band traces the locus of all points in the unknown surface which are at a constant 266 LIGHT distance from the true plane. The bands are analogous to the contour lines on a topographic map. Plane-Parallel Surfaces. — The parallelism of the plane sur- faces of a glass plate may be roughly tested by observing any well-defined distant object as seen reflected from the plate at an angle of about 45°. If the two surfaces are inclined, two images will be seen, one of which revolves about the other when the plate is turned in its own plane. If the surfaces are parallel there will be but one image, which should be sharply defined. If the reflected image is observed with a telescope, the test becomes much more delicate because of the magnification, and it is then sufficiently sensitive for the usual requirements. A spectrometer is most convenient for this test. Set the tele- scope at right angles to the collimator, and place the plate to be tested so that the illuminated slit is reflected in the telescope. A more suitable object is obtained by opening the slit wide and crossing fine wires over the opening. Then, as the plate is rotated in its own plane, the image should remain single and sharply defined. CXVn. SILVERING GLASS BY CHEMICAL METHODS (a) Make a thick-film mirror by Brashear's process. (b) Make a half -silvered mirror by the Rochelle-Salts process. 198. Brashear's Process for Silvering Glass. — Mirrors for optical experiments are often made by preparing a glass sur- face of the desired form, upon which is then deposited a uni- form film of silver. The following method, by which a hard, •brilliant film is deposited from an ammoniacal solution of nitrate of silver by an organic reducing agent, is usually the most convenient and satisfactory. Two solutions are required : one, the reducing solution, should be prepared at least a week before it is used, and it may be made in large quantity and kept in stock with advantage; the other solution is to be prepared when used. SILVERING GLASS 267 Reducing Solution Distilled water 700 ccm Pure sugar (loaf, granulated, or rock candy) ... 80 g When dissolved add Alcohol . ... .... 175 ccm Strong nitric acid (sp. gr. 1.42) ... ... 3 ccm Add water to make . 1000 ccm For silvering, the mirror may rest face up on the bottom of a suitable dish; it may stand on edge, or be supported in any manner, face downward, dipping into the upper part of the solu- tion. In the latter case the mirror may be fastened with wax to a stick laid across the dish, or it may be supported on glass feet or on paraffined wood wedges. Dr. Brashear recommends that the mirror, if round, form the bottom of the silvering dish, which is completed by wrapping a strip of paraffined paper around the edge of the mirror, this being held in place by rubber bands or fastened with several wrappings of cord. Having selected a dish and support for the mirror, measure with water the quantity of solution that will be required to make a layer a centimeter or two thick over the surface to be silvered. For each 150 ccm of final solution, 1 g of silver nitrate and 0.5 g of caustic potash (purified by alcohol) will be required. Dissolve the silver and potash separately, using quantities of water of the proportion of 100 ccm to 1 g of the solution. Ordinary graduates or flasks are the most convenient form of vessel in which to mix the solutions. Into the silver nitrate solution pour a few drops of dilute aqua ammonia. The solu- tion wiU turn to a dark brown color ; add ammonia little by little till the precipitate is nearly but not quite redissolved. Now add the potash solution, when a precipitate will again be formed. This is to be nearly, but not entirely, redissolved by the addition of more ammonia, a few drops being sufficient this time. After the ammonia has been added, shake or stir the solution well and wait a minute or two to be certain that it does not entirely clear. If by chance too much ammonia has been used, a little silver nitrate is to be dissolved and added, a few drops at a time, till a permanent precipitate is formed. This excess of silver must 268 LIGHT be present, the solution showing a decided brown tint. The solution may be filtered, though usually this is not necessary. A quantity of reducing solution equal to about a twenty-fifth part of the solution just prepared is measured out. The mirror, having been properly cleaned and rinsed with distilled water, is placed in position. The reducing solution is poured into the silver and potash solution, and mixed by a quick shaking of the graduate or stirring with a glass rod; the whole is then poured into the dish. If the mirror is immersed face down, care is necessary to remove air bubbles ; the min-or may well be immersed after the solution is in, being dipped in at one side first. If the mirror is at the bottom of the dish, after cleaning it is covered with a thin layer of water, and the prepared solutions are poured into the dish without further trouble. In the latter case the dish must be rocked during the time of deposition. The solution soon turns to a black color, which in a few minutes will turn to a brown ; and when it becomes a light gray and the precipitate is flocculent, which may be in ten or fifteen minutes, the operation is at an end. If the mirror is allowed to remain in the solution too long, the surface will have a bleached appear- ance, which polishing will hardly remove. Remove the mirror, rinse with water, and carefully wipe off the sediment with a tuft of absorbent cotton. It is then set on edge to dry ; a rins- ing with alcohol wiU facilitate the drying, or all water may be safely taken up by pressing clean blotting paper over the surface. When dry the surface may be polished, if necessary, with a small pad of chamois leather stuffed with cotton, on which is spread a little rouge. Small, circular strokes of the pad, with light pressure, will soon bring out the deep luster of the silver. A uniform temperature of the bath and the glass, of about 20° is essential to success. Since fulminating silver is liable to be produced by the action of ammonia on silver oxide, especially in a warm room, all solu- tions should be thrown away as soon as the silvering operation is completed. The used solutions may be poured into a large jar, in which is thrown some common salt ; this causes the silver SILVERING GLASS 269 to be precipitated as the chloride, and about ninety per cent, of the original silver may be recovered. 199. Rochelle-Salts Process for Silvering Glass. — For deposit- ing the uniform thin film of silver required on the half-silvered glass of the interferometer, the following method is more suit> able than the one described above, as the silver is deposited more slowly. If a thick film is desired, two or more successive deposits may be made, each of which may require an hour's time. Dissolve 5 g of silver nitrate in 300 ccm of distilled water, and add dilute aqua ammonia until the precipitate formed is nearly, hut not entirely, redissolved in the manner explained in the preceding method. Filter the solution and add water to make 500 ccm. Dissolve 1 g of silver nitrate in a small quantity of water, and pour into about half a liter of boiling water; dissolve 0.83 g of Rochelle salts in a small quantity of water, and add to the boil- ing solution. Continue the boiling for half an hour, till the gray precipitate collects as a powder in the bottom of the flask. Filter hot, and add water to make 500 ccm. These solutions may be kept in the dark for a month or two. For silvering, equal volumes of the two solutions are mixed, and the glass is supported in the mixture in whatever fashion is convenient. Various methods are mentioned in the preceding article. The thickest possible deposit may require an hour's time. A second deposit may be made upon the first if necessary to secure the desired thickness. The drying and polishing may be carried out as described above. A half-silvered film will be produced in about a minute ; only experience can determine when the proper thickness has been secured. The glass appears as though it were very lightly smoked. A film that reflects a little more than half the light incident at 45° is desirable for interferometer use. A simple method of testing is to look at two similar gas flames, one seen through the film and the other seen reflected by it. It is well to silver at once all four surfaces of the two plane-parallel plates of the interferometer and to select for use that film which is of the proper and most uniform thickness. 270 LIGHT 200. Cleaning Optical Surfaces for Silvering. — Probably the most important part of the silvering process is the proper cleaning of the surface to be silvered. The surface is thoroughly cleaned of grease or other organic matter by the usual methods (Art. 91), using alcohol or chromic acid. Then it should be carefully cleaned with strong nitric acid, the whole surface being firmly rubbed with pure cotton tied to a rod of wood or glass. Care should be taken not to injure the surface. Rinse with water, and then wash the surface thoroughly with a strong solution of caustic potash, rubbing with a cotton brush as before. Finally rinse with distilled water, and keep the surface wet until it is placed in the silver- ing solution. If the distilled water wets the whole surface uniformly, the cleaning may be sufficient; if it does not wet uniformly, the operations must be repeated. The fingers should not touch the edges of the glass during the latter cleaning operations, as a layer of organic matter is apt to spread over the surface and render the silvering uneven. Dr. Brashear recommends that the surface, after the washings described above, be rubbed with prepared chalk on a cotton wad until it is thoroughly dry and clean. .It may then be put into the silvering solution at one's convenience. The following method is sometimes convenient for holding a mirror while cleaning and immersing it. A funnel having a ground edge is placed against the back of the mirror with a ring of sheet rubber between them. Connect the stem of the funnel to an air pump with rubber tubing. A few strokes of the pump will firmly attach the funnel, which will serve as a safe and clean handle. CHAPTER XIX THE SPECTROSCOPE AND POLARIMETEE, CXVm. CHEMICAL COMPOSITION WITH THE SPECTROSCOPE (a) Map the principal lines in the solar spectrum, and calibrate the scale of the spectroscope. Find the wave lengths of the lines, and draw a map of the spectrum of a solid and of a gas. (b) Idsntify several unknown substances by comparing their spectra with the spectra of known elements. 201. Spectrum Analysis. — A spectroscope usually differs from the spectrometer (Art. 171) in that it has fewer adjustments, and instead of a divided circle it has a linear scale made visible in the field of the view telescope. A spectrometer may always be used as a spectroscope. The dispersion part of a spectro- scope may be one or several prisms, or a diffraction •^ grating. Fig. 114 shows the relations of the essential p.irts of a two-prism spectroscope. The flame to be analyzed is placed at F, illumi- nating the slit S. The slit must be in the principal focus of the collimating lens C, in order that the rays v^ falling on the prism Pj shall be parallel. It may have been Fio.lM. SP.CTKOSCOPB - ^ permanently placed by the maker, or a mark on the draw tube may indicate its correct position; otherwise it must be adjusted as follows. Remove the telescope T and focus it on a distant object ; replace it so as to view the slit through the collima- tor, the prisms being removed ; focus the slit by means of its draw tube till it is seen distinctly in the telescope. (See Art. 172.) 271 272 LIGHT Adjust the prisms, P^, Pg, etc., to the position of minimum deviation, as explained in Art. 179, placing first one and then another till all are properly arranged. Illuminate the scale JIf by a light at L, just bright enough to render it visible. Cause the scale image to be reflected from the prism face nearest the telescope so that it appears iu the field of view crossing the whole spectrum. Focus it for dis- tinctness, and so that there is no parallax displacement with regard to the sht image, when the eye is moved sideways. The relative positions of the lines of the spectrum of a given substance produced by a prism vary with the composition of the material of the prism. In order that one prismatic spectrum may be compared with that from a different prism, an absolute scale of reference must be adopted. The most useful of such scales is one of actual wave lengths. To find the wave-length values of the arbitrary spectroscope scale a standard spectrum must be observed, and the relation between the positions and known wave lengths of various lines may be plotted on coordinate paper, from which the wave length of any observed line may be found. The solar spectrum is a con- venient standard. If the spectrum is formed by a diffraction grating, it is a normal spectrum; that is, the dispersion is proportional to the wave length. The relative positions of the lines in the spectra of any given substance formed by different gratings are always identical (Art. 191). If a spectrometer is employed, all the adjustments described for determining index of refraction should be made. The spec- tral lines may be located by reference to the divided circle, the wave-length values being found by observing a standard spectrum, as described above. Arrange a heliostat (Art. 202) to throw sunlight upon the slit of the spectroscope. If this is not convenient, the light from a bright sky will serve. Alter the width of the slit until the transverse (Fraunhofer) lines are distinct. If longitudinal lines are visible, they are due to dust or irregularities in the slit. To remove dust draw a fine sliver of soft wood throusrh the slit. SPECTEUM ANALYSIS 273 If this does not remove the lines, widening the slit may be advantageous, though it may render the spectrum too bright or the spectral lines too wide. Identify and locate on the scale the principal Fraunhofer lines, the B, C, D, A\ h, F, G, H, and A' lines, referring to a map of the spectrum if necessary. Using the known wave lengths of the lines (Table 26), plot a curve showing the wave-length values of the scale. The spectra of all the obtainable elements have been observed, and the wave lengths of the principal lines have been tabulated. Spectrum analysis in its simplest form consists in observations of the lines given by the unknown substance, which by refer- ence to. the tables enable the identification of the substance. Besides position, features which aid in the identification are brightness, width, color, and sharpness. Full descriptions of the methods, which may become very complex, will be found in the references. To study the spectrum of a solid, such as the chlorides of barium, calcium, lithium, sodium, strontium, thallium, etc., the substance may be vaporized and rendered incandescent in the Bunsen flame. Place a little of the material on a platinum wire, and hold it just within the surface of the flame, near the middle of its length. The temperature of the flame, and the length of time the substance has been in it, influence the appear- ance of certain lines. Less volatile substances may be rendered incandescent by being placed in the crater of an electric arc between carbons, or an arc may be formed between electrodes of the substance being studied. The Bunsen flame and the carbon arc both give spectral lines, which must be identified and differentiated from the lines of the material being analyzed. The sodium line is almost universally present in flame spectra. Many lines are faint, and to observe them all outside light must be excluded, by a screen behind the source, by covering the prisms, and by covering the observer's head if necessary. The slit must be widened when searching for faint lines. 274 LIGHT To observe the spectrum of a gas, the gas is usually placed in a glass tube having platinum electrodes, between which the discharge of an induction coil takes place, rendering the gas incandescent. Sun Refekences. — Kohlrausch, Physical Measurements, pp. 169-173; Schuster and Lees, Practical Physics, pp. 178-193 ; Scheiner, Astronomical Spectroscopy ; Landauer, Spectrum Analysis. 202. The Hellostat. — In experimental work it is often desired to project a beam of sunlight in a direction which shall remain fixed throughout the day. This may be accomplished by means of a heHostat, the essential part of which is a mirror provided with various adjustments, moved by clockwork in such a manner as to neutralize the effects of the earth's rotation on its axis. In some forms of heliostat the beam of light is thrown in a direction parallel to the earth's axis, the beam being received on a second mir- ror, which then reflects it in any desired direction. In other forms the beam is sent in any given direc- tion at the first reflection. The first form is the simpler and more certain in action, its disadvantage being one additional reflection. A two-mirror heliostat is shown in Fig. 115. The polar axis P is to be placed in the plane of the merid- ian and elevated at an angle equal to the latitude of the sta- tion. The graduated arc L indicates the proper latitude setting. The axis is thus made parallel to the earth's axis. A clock, C, is arranged to rotate this axis from east to west at a rate corresponding to the diurnal motion of the sun. Fig. 115. Heliostat ROTATOEY POLAEIZATION 275 At the upper end of the polar axis the mirror is held so as to be movable about a line through a, which constitutes the decli- nation axis. The normal to the surface of the mirror, iV, should bisect the angle between the direction of the sun and the polar axis. When the sun is on the equator the normal makes an angle of 45° with the polar axis, and the declination circle D reads 0°. As the sun moves north or south the mirror must be inclined from this position by an amount equal to half the sun's declination. The declination circle is usually ^radijated with half-degree spaces numbered as whole degrees, and the setting is therefore equal to the sun's declination. Attached to the polar axis is an hour circle, which reads when the dechnation axis is horizontal. In starting the instrument this circle is to be set to the apparent solar time (standard time reduced to local mean time, and then corrected for the equation of time). Approximate values of the sun's declination and the equation of time, sufficient for heliostat settings, are given in Table 22, in the Appendix. More complete tables will be found in the Nautical Almanac. Other forms of heliostats require similar settings. The man- ner of making these will usually be evident from inspection. Reference. — Le,isi, Die optisclien Instrumente, pp. 284-305. CXrX. OPTICAL ACTIVITY WITH THE POLARIMETER Determine the specific rotation of cane sugar, and find the percentage of cane sugar in an unknown solution. 203. Rotatory Polarization. — Certain solids, liquids, vapors, and solutions have the property, when plane-polarized light is passed through them, of rotating the plane of polarization. This phenomenon is called optical activity. Some substances rotate the plane to the right and others to the left ; that rota- tion which is related to the propagation of light, as the rotation and translation in a right-handed screw, is said to be right- handed. The amount of rotation for any active substance varies 276 LIGHT directly as the thickness of the layer through which the light passes, and varies with the wave length of the light. For a liquid it also varies with the density or the concentration of the solution and with the temperature. The rotatory power of fluids is much less than that of solids. About thirty crystals are known to possess optical activity, while over seven hundred liquids and solutions belonging to all groups of organic com- pounds also have this property. The specific rotation of a liquid or substance in solution is the rotation in degrees of arc, per unit length of path of the light, per unit density of the substance. If r is the rotation produced when the light passes through I centimeters of length of the fluid, and d is its density, the specific rotation is If the active substance is mixed with an inactive liquid, d in the above formula represents the number of grams of the sub- stance in one cubic centimeter of the solution. A statement of the specific rotation of a substance should include the tempera- ture, the kind of light used, as the sodium D line, and the direction of rotation, -I- for right-handed ; as turpentine [af^ = - 3°.701. The specific rotation multiplied by the molecular weight gives the molecular rotation. Founded upon these principles there are methods of analysis useful for distinguishing one substance from another, or for determining the nature or strength of a solution. Rotatory polarization is employed as an aid in the analysis of various carbon compounds, such as gum resins, camphor, essential oils, alkaloids, dyestuffs, and many others ; and it is extensively used in sugar analysis to determine the purity of various samples and the proper concentration of syrups in manufacturing. 204. The Polarimeter. — An instrument designed to measure the rotatory polarization of a substance is a polarimeter (Fig. 116). For general uses the rotation is measured in degrees THE POLAEIMETEE 277 of arc. Often the instrument is arranged for sugar analysis, with a scale showing the percentage of sugar in solution as compared with a standard solution; it is then a saccharimeter. The field of view of a polariscope consisting of two Nicol prisms is dark when the prisms are crossed. An optically active substance placed in the path of the light between the prisms rotates the plane of the polarized light and causes the field to appear brighter. That rotation of either prism necessary to restore darkness measures the rotation of the substance. To determine the exact position of the prism producing this effect is difficult, and various devices have been made to secure in- creased sensitiveness. Some of the more com- mon forms are men- tioned below. Half Shade (Lau- rent).— The field of view embraces a plate one half of which is glass while the other is quartz cut parallel to the axis and of such -thickness as to introduce a retardation of half a wave length of the particular color of light to be used (commonly sodium) between the ordinary and extraordinary rays. This causes the two halves of the field to appear unequally illuminated, except when the principal plane of the analyzing nicol is parallel to the axis of the quartz ; then the two halves appear of uniform brightness. This brightness of the field and therefore the sensitiveness may be regulated by changing the position of the polarizer with respect to the quartz plate. The sensitive position is that of the eyepiece nicol producing uniformity of field illumination. Monochro- matic (sodium) light is necessary. Fig. 116. Polakimetek 278 LIGHT Interference Bands (Wild). — Two plates of calcite or quartz are cut at an angle of 46° to the axis, and placed together with their principal sections at right angles. This plate is inserted in the path of the rays near the eyepiece nicol, and gives in the field of view a series of bands alternately light and dark. The polarizing nicol is rotated until these bands disappear in the center of the field, a sensitive condition. The sensitiveness, A NE X 1 S * P N /S7D (DO] I I /S7 Fig. 117. Wild's Polabistrobombteb depending upon the brightness of the light used, may be adjusted by changing the position of the eyepiece nicol with respect to the interference plate. Either monochromatic or white light may be used, though the first is better, as the entire field is then covered by the bands. Fig. 117 represents the arrangement of the optical parts of Wild's polaristrobometer. FN is the polarizing nicol, S the active substance, / the interference plate, AN the analyzing nicol, X the cross wires, and and E the observing lenses. Sensitive Tint (Soleil). — Two quartz plates of equal thick- ness but of opposite rotations are placed side by side in front of the polarizing nicol. The sensitive condition is secured by rotating the eyepiece nicol until it is parallel to the polarizing nicol, in which case the two halves of the field appear equally bright, or of the same color, a grayish violet, called the tint of passage or sensitive tint. A slight displacement of the nicol either way causes one half to appear red and the other blue, with white light, or to appear unequally bright with monochro- matic light. With each of these devices the critical condition can be secured by rotating one of the Nicol prisms, and the rotation produced by an active substance put in the path of the light between the nicols may be determined by the rotation of the nicol required to compensate that of the substance. There are always two positions of the nicol, 180° apart, satisfying this THE POLAEIMETEE 279 condition, and sometimes there are four positions 90° apart. To determine whether the rotation of an active substance is less or greater than 90° or 180°, or whether it is right- or left- handed, it may be necessary to use two different lengths of the substance, or two different strengths of solution. For example, an observed rotation of 30° to the right may actually be one of 60° to the left. A second observation with half the length of substance would in the latter case show the sensitive condi- tion at a point 30° to the left and at 60° to the right; while if the first observation corresponded to an actual rotation to the right of 80°, the second observation would show only 15° to the right and 75° to the left. Often, instead of measuring the angle of rotation produced by the active substance by rotating one of the Nicol prisms an equal amount in the opposite direction, as described, the rota^ tion of the plane of polarization by the substance is neutralized by the opposite rotation produced by a quartz compensator. This consists of two quartz wedges having left-hand rotation, one of which can slide over the other, varying their combined thickness, together with a right-handed quartz plate. Any desired rotation either right or left can be introduced, accord- ing as the wedges combined are thicker or thinner than the single plate. The thickness of wedge required to secure the sensitive condition is measured by an arbitrary scale, which usually indicates percentage of pure sugar in a solution made W E OAN I D\Z\ H Q S B PN CON U I ~1 B\Z\ D\Z\ Fig. 118. Quartz Wedge Saoohakimeter according to rule. In instruments of German manufacture one division of the scale equals 0°.346, and for sugar analysis 26.05 g of the sample is dissolved in 10 ccm of solution. The scale reading then gives at once the percentage of pure sugar. In instruments of French manufacture one scale division equals 0°.217, and the standard solution contains 16.35 g per 100 ccm of solution. 280 LIGHT Fig. 118 shows the optical parts of a saccharimeter. FN is the polarizing nicol, B the quartz plate, S the active substance, Q the right-handed quartz plate, W the left-handed quartz wedges, AN the analyzing nicol, and and E are the observing lenses, focused on B. To neutralize the effect of colored solu- tions, or colored light, or to secure any desired tint of field, a color regulator consisting of a nicol, CN, and a quartz plate, C, are often provided. The rotation of these alters the color of the field. 205. Saccharimetry. — Granulated sugar may be considered pure cane sugar, and its specific rotation is determined in accordance with the definition of Art. 203. For cane sugar the specific rotation is nearly independent of temperature. Dissolve 20 g of dry granulated sugar in about 80 ccm of warm water, contained conveniently in a 100 ccm flask. When the sugar is thoroughly dissolved, cool the mixture to 20° and add water to make 100 ccm of solution. Fill a 20 cm solution tube with distilled water, place it in the saccharimeter, and make the critical adjustments as described above, either for equal tint, equal shade, or for the disappear- ance of the interference bands. Make a number of settings, ten for example, and use the average as the zero reading of the instrument. Fill the tube with the prepared solution of pure sugar, and make the critical adjustments again, taking the aver- age of the ten readings. Then if there are w g of sugar in v ccm of solution, and the tube has a length of I centimeters, and the observed rotation in degrees of arc is r, the specific rotation is rv W = ^- Using a tube 10 cm long, repeat the observations and find the specific rotation. Dilute the solution still remaining to half strength, by adding an equal volume of water, and with the 20 cm tube again determine the specific rotation. With the value of the specific rotation thus found, determine the amount of cane sugar in an unknown solution provided for testing. SACCHARIMETRY 281 (When the work is finished, wash all tubes and dishes used for the sugar solutions.) The method above described is of general application in the measurement of the rotatory power of any active substance. The treatment for clarifying colored solutions, and for the deter- mination of sugar in the presence of invert sugar, or other active substances, may be found in treatises on chemical analysis. References. — Landolt, Optical Rotating Power; Kohlrausch, Physical Measurements, pp. 190-198 ; Preston, Theory of Light, pp. 449-457. Paet yi — Electeicity ai^d Magis^etism CHAPTER XX EESISTANCE CXXV. RESISTANCE BY THE WHEATSTONE'S BRIDGE Determine the resistance of a high- and of a low-voltage incandescent lamp (cold) ; also the resistances of two wire coils, separately, in series, and in parallel. Make three measures of each. 206. Electrical Measurements and Ohm's Law. — Electrical measurements consist of the direct or indirect determinations of resistances, current strengths, electromotive forces, quantities of electricity, and magnetic quantities. Of these classes of electrical measurements the first three are much the more com- mon in technical work. The principles underlying many of the various methods are contained in what is known as Ohm's Law, and though this law is stated in very simple fashion, its wide application renders it worthy of the student's careful study. If a specified conductor is carrying a steady current, there are three factors to which attention must be given in order that the electrical conditions may be understood. These are the difference of potential, E, between the ends of the conductor, the strength of the current, /, and the resistance, B. Ohm's Law expresses the relations between these quantities, that the product of resistance and current strength is equal to the 282 WHEATSTONE'S BEIDGE 283 difference of potential. It is also often stated by the following equation : „ The units in which these quantities are measured, the ohm, the ampere, and the volt, are defined in Arts. 212, 244, and 249 respectively. Other electrical and magnetic units are defined in Arts. 262, 269, and 272. 207. Wheatstone's Bridge. — Wheatstone's bridge is a device by which the principles involved in Ohm's Law may be applied to a variety of electrical measurements. Before describing the methods specifically, a general explanation will be given. Let A and C (Fig. 119) be two points connected by two conductors, ADC and AUG, and B a source of electromotive force producing a difference of potential between A and C, that at A being the higher. There will result a steady flow of current from A to C and through the battery ; a part of the current, Jq, will go from ^ to C through D ; and a part, J^, from A to C through H. Represent the resistances from ^ to Z>, D to C, ^ to E, and U to C, by r-j, r^, r^, and r^ ; and the potential difference between two points by V with proper subscripts. The same current flowing from A to D must also flow from D to C; therefore by Ohm's Law, tB Fig. 119. Branched Circuit It> = _ yAD_ "DC and similarly, Ie = Vae _ ^EC . from which V^d : V^c = ''i = ''a' ^^^ ^ab ■ Vec = '"s = '*4- ^he potential of any point on the branch D is less than the potential of A and greater than the potential of C, and likewise for any 284 ELECTRICITY point on the branch E. Therefore, whatever may be the poten- tial of a point on the D branch, there is always some point on the E branch having the same potential. Let D and E be two points having the same potential. Then Vad= Vae, and F^c = Vec; and r^: r^ = r^: r^, or r-^: r^ = r^: r^, and r^r^ = r^T^. The last equation, stated in words, is that the products of opposite, or alternate, resistances are equal. From these equations, if the values of any three of the resist- ances, Ty r^, j-g, and r^, are known, the fourth is determined; or, if only the ratio of any two adjacent resistances, together with the value of one of the other resistances, is known, the fourth is determined. There are two distinct methods of adjustment for locating the point E, whose potential is the same as that of J), as required in the above relations. The two forms of apparatus for this pur- pose, the slide-wire-meter bridge and the post-office-box bridge, are described in Arts. 208 and 214. 208. The Slide- Wire-Meter Bridge.— The simplest form of the Wheatstone's bridge is the slide-wire-meter bridge. The conductor represented by AEC (Fig. 120) is made of a uniform wire one meter long, and the point E is determined by a slid- ing contact which moves over a millimeter scale. The lengths of the portions of the wire, AE and EC, can be read directly. A C resistance box, jB, of known value, corre- FiG. 120. Wheatstone's sponds to r^ (Art. 207), while the Unknown resistance, X, replaces r^. Any convenient value being given to R, the potential of B becomes fixed. To find the point E, having the same potential, a " bridge " conductor containing a galvanometer is connected to D and to the slider. THE GALVANOMETER 285 If the bridge joins two points whose potentials are equal, evi- dently no current will flow through the galvanometer. Usually, however, when the key, K, of the bridge is closed, there will be a deflection of the galvanometer needle caused by a flow of current from Z> to E, or in the opposite direction. But it will always be possible to find a point of contact by moving the slider nearer to A or to C, such that there shall be no deflection of the galvanometer ; then the bridge is said to be balanced, and the potential at E is the same as at B. The resistances of the two portions of the meter wire, AE and EC, are considered as proportional to their lengths, l^ and l^. Therefore With this form of apparatus it is desirable to have B and X approximately equal, since in this case the contact will be near the middle of the meter wire, and errors of reading and of the wire will have a minimum effect. Often the index on the slider is not over the contact, or the resistances of the connections are unsymmetrical, or the wire is of uneven size ; the result determined as above described may then be slightly in error. A second determination should there- fore be made after interchanging R and X; the mean of the two values will be nearly free from these errors. 209. The Galvanometer. — The most common instrument for measuring or detecting electrical currents is the galvanometer, which is founded on Oersted's discovery of the mutual action between a current and a magnet. In the galvanometer a circuit is arranged with its plane parallel to the force of a magnet ; when a current passes, there is a tendency for the plane of the coil and the lines of magnetic force to set perpen- dicular to each other. Either one of these parts, the circuit or the magnet, may be fixed in position, the other being delicately suspended so as to move under the force mentioned. Thus there are two types of galvanometers, while there are many varieties of each. In one type a small magnet is freely suspended and allowed to come to rest in the magnetic meridian ; coils of wire are placed 286 ELECTRICITY around the magnet, with the plane of the coils in the meridian. Fig. 121 represents this type, some of the details of which are shown in Fig. 123. Figs. 125, 130, and 134 show other forms of this same type of galvanometer. When the current passes through the wire the magnet is deflected in one direction or the other, depending upon the direction of the current. In the second type of gal- vanometer a small coil of fine wire is suspended by a delicate metallic ribbon between the poles of strong stationary per- manent magnets. The torsion of the suspension causes the coil to seek its equilibrium position, which is made to be that in which the plane of the coil is parallel' to the magnetic force of the field magnets. Fig. 122 represents a small instrument of this type, while a large one of the highest sensibility is shown in Fig. 161. The essential parts are indi- cated in Fig. 124. A current may enter the coil through the suspension, and pass out through a delicate spiral of metal ribbon attached to the bottom of the coil. When the current passes, the coil tends to rotate so as to set itself perpendicular to the field ; this rotation is counteracted by the torsion. This type is often called the D'Arsonval galvanometer. It possesses the distinct advantage of being practically independent of the earth's magnetic field and of magnetic disturbances of all kinds. Such' galvanometers are made of great sensitiveness, though the extreme of sensitiveness has so far been obtained only with the first type of instrument. Galvanometers are used for three different kinds of measure- ments. They may measure currents of definite strength, there Fig. 121. Galvanometer THE GALVANOMETER 287 being produced a steady deflection. Such instruments are the tangent galvanometer (Art. 216), the ammeter and voltmeter (Art. 222), the electrodynamometer (Art. 248), etc. These are usually of small or medium sensitiveness. Instruments of another class are used for detecting the presence of minute currents, and are of the highest attain- able sensitiveness. This class is perhaps used more than any other in electrical measurements. They are used with all null methods, in which the adjustments are made so that no current flows. Ballistic galvanometers, constituting the third class, measure, not the strength of a steady current flowing as do the first two classes, but the total quantity of electricity which passes in an impulse of short duration (Art. 253). Galvanometers of any one of the three classes may be of either of the two types mentioned. In instruments of the first and second classes, which are used to measure steady currents, it is very desirable that the needle should quickly come to rest either in its deflected or zero position. Gal- vanometers in which the needle moves to its equilibrium position without vibra- tion are called aperiodic or dead-beat. In a suspended magnet galvanometer this condition is secured by causing the magnet to move in a cavity in a solid mass of copper. Induced currents are generated in the copper by motion of the magnet ; the copper has no effect when the magnet is stationary. The parts of such a galvanometer may be arranged as indicated in Fig. 123. A Fig. 122. D'Arsonval Ga lv axom kte r Fig. 123. Details of Galvanometer 288 ELECTRICITY R, bell or n -shaped magnet has its poles at iV" and S, inside the copper mass A ; C-y and C^ are the coils of wire, and M is the mirror attached to the hook by which the magnet is suspended. A galvanometer with a suspended coil is made dead-beat by winding the wire on a metal frame, or by surrounding it with a metal tube in which the induced currents are generated by the motion in the magnetic field. Fig. 124 shows the arrangement of the parts of this type, C being the coil suspended by the ribbons of metal, -Bj and B^; iV and S are the poles of the permanent magnets, and M the mirror for scale reading. The suspended part of a galvanometer sometimes consists in effect of two magnets rigidly fastened together with their poles oppositely directed. Thus the earth's effect upon the system is nearly neutralized. The magnets are suspended inside the coils in such a manner that the effect of the current is twice as great as upon a single magnet. This arrangement constitutes an astatio needle, and makes the most sensitive galvanometer that has been devised. This extreme sensitive- ness renders the instrument somewhat trouble- some to use. Fig. 125 shows the form of an astatic galvanometer with two sets of coils. 210. Adjusting a Galvanometer Before a galvanometer is moved it should be ascer- tained that the weight of the needle is taken from the suspension, to prevent breaking the latter. The manner of doing this will be evident from the con- struction. When the galvanometer is in position, on a pier or other suitable support, if it is of the suspended magnet type, the whole instrument should be turned on its base so that the plane of the coils is approximately in the magnetic meridian. Simple inspection will determine this sufficiently, unless the deflections of the instrument are to be used for measurement. Fig. 124. Parts OF D'Arsonval Galvanometer THE GALVANOMETER 289 When greater care is necessary in any of the exercises the methods are mentioned (Arts. 216 and 253). The instrument should be leveled. A- level on the base may indicate this condition, but it often happens that the level is itself out of adjustment. In any case the needle usually serves as a better indicator of the proper position of the galvanometer. When the needle is released it should swing freely and without rubbing, and after a slight deflection it should return to the starting point. After the needle has taken its position in the meridian it may be found that the mir- ror faces in an inconvenient direction. In some instruments it is possible, by carefully holding the needle, to turn the mirror so that it faces in any direction desired. It should be so turned that when a scale is placed in front of it the scale will be well illuminated. A control magnet may be advantageous in adjusting a galvanometer. This may be any permanent magnet, placed near the instrument, or preferably attached to it in some convenient manner, as shown at X, Figs. 121 and 125. When a control magnet is used it is not necessary to place the coils in the magnetic meridian, as the magnet may be so placed as to bring the axis of the needle into the plane of the coils, in what- ever direction this may be. The control magnet may increase the sensitiveness of the instrument by partially neutralizing the earth's field. A consideration of the sensitiveness of a galvanometer is given in Art. 247. When the galvanometer is of the suspended coil type its direc- tion with respect to the meridian is not important, and it may be set facing in the most convenient direction, and leveled. The replacing of a broken galvanometer suspension is such a troublesome operation that especial care should be taken to avoid breaking one. Fig. 125. Astatic Ballistic Galva- nometer 290 ELECTRICITY 211. Telescope, or Lamp, and Scale. — A galvanometer deflec- tion may be observed by means of a pointer attached to the needle ; but with a sensitive instrument it is usual to attach a light mirror to the needle and to observe the deflections with a telescope and scale, or with a lamp and scale. The adjustment and use of a telescope and scale are sufficiently described in Arts. 33, 253, and 264. A light illuminating a slit or a wire may replace the tele- scope. A lens is placed between the slit and mirror, and the various parts are adjusted so that the image of the slit, reflected by the mirror, is focused on the scale. The movements of this image indicate the needle deflections. 212. Standard International Ohm ; Resistances and Rheostats. — The international ohm is defined as the resistance of a column of mercury, at 0°, 106.3 cm long, and 1 square mm area of cross section. The mass of this quantity of mercury is 14.4521 g. Standard resistances for electrical measurements are com- monly made of wire. Various alloys have been devised such that the specific resistance is high while the temperature coeffi- cient and thermo-electric power are low, and such that the resist- ance shall not change with time and use. Manganin is the „„„^^^,,^ , most suitable alloy; it ^ f 1 1 consists of 0.84 copper, 0.12 manganese, and 0.04 nickel. Other alloys are constantan, platinoid, and German silver. To avoid the self- induction of a simple helix, the wire for a resistance coil is first doubled at its middle, and the two wires are wound side by side in such fashion that the current will flow through the two in opposite directions. In coils of many turns this method gives Fig. 126. Standard Resistance in Oil Bath RESISTANCES AND RHEOSTATS 291 considerable capacity. This, as well as the self-induction, may- be avoided by winding a single wire, with freqxient changes in the direction of the winding, so that in the end there are as many turns in one direction as in the other. This method is necessary only for coils of more than 400 ohms resistance. Fig. 127. Resistance Box Standards of single resistance are usually so constructed that they may be placed in an oil bath to secure a definite and known temperature. Connections are best made by means of mercury cups, into which the terminals dip. Fig. 126 shows the con- struction of such a standard. Sets of resistances, mounted to permit various combinations, are usually inclosed in wooden boxes, and are called resistance boxes. On the top of the box are rows of metal blocks, and between these are fitted taper plugs (Fig. 12T). The coils are so joined to the blocks that when the plugs are all removed a current connected to the terminals of the box must pass through all the coils in succession, and the resistance is equal to their sum. By the insertion of a plug any coil may be shunted by a resistance so small that, for ordinary measurements, the resist- ance of the plugged part may be considered 0. If all the plugs are in place, the total resistance is 0. With this arrangement any combination of resistances may be secured. The actual resistance through a plug, when it is in good order, with clean and well-fitting surfaces, is from 0.00005 to 0.0001 ohm. 292 ELECTRICITY The plugs are to be inserted with a firm pressure and a slight twisting movement, but care must be taken that they are not forced into the taper holes so tightly as to injure the apparatus. Plugs belonging to different boxes should never be interchanged. Sometimes the insertion of a plug warmed by contact with the hand may produce thermo-electric currents. This is avoided by the use of a nonconducting handle. Resistance boxes are adjusted for a temperature of 20° ; if the temperature differs much from this, a temperature correc- tion may be necessary. The temperature coefficient of man- ganin wire may vary from + 0.00001 to -|- 0.00004. Resistance boxes should never be used to control large currents; the heat developed may ruin the insulation or even melt the wire. A variable resistance, not standardized, is often useful for regulating a current. Such a rheostat may consist of coils of wire with suitable switches, or wire arranged so that various lengths of it may be used. A pile of short carbon rods, through which the current passes, has a resistance which varies with the contact pressure of the rods against each other. By a screw press this pressure may be varied, and thus the current strength may be continuously altered through a small range. If such a rheostat is inserted in addition to a coil rheostat, it will be possible to adjust a current exactly to a desired value. 213. Keys. — A great variety of keys and connectors are required in arranging electrical apparatus. Single keys and switches need not be described. For work with the Wheat- stone's bridge, and other in- struments, a double successive contact hey is useful. There are four contact points, 6j, h^, ^1, and g^ (Fig. 128), which are connected with the bind- ing posts B,, B„, G,, and G„ Fig. 128. Double Successive „ ,• i t) . i j _ ^ respectively. Between o„ and Contact Kbt . . ^ ffi IS an insulating button. The battery circuit is connected to ^j and B^, and the galvanom- eter circuit to G^ and G^. When the knob K is pressed the THE BOX BRIDGE 293 battery circuit is first closed, and then the galvanometer circuit is closed by a further depression of the knob. Thus the current is started in the apparatus and assumes a steady condition before the galvanometer is applied. The bridge contact often serves as one key, in which case only a single key is required; or if the battery is a constant cell, it may be put in a closed circuit, when no key will be required. Various forms of commutating keys are described in Art. 218, a condenser key is shown in Art. 263, and other forms are men- tioned in Arts. 229, 230, 239, 254, and 256. CXXVI. RESISTANCE WITH THE BOX BRIDGE Determine the resistances of the magnet coils of a sounder, of a relay, and of the primary and secondary windings of an induction coil. Use several ratios for each resistance. 214. The Box Bridge. — The slide-wire form of Wheatstone's bridge (Art. 208) may be uncertain in its results because of irregularities in the wire or in the contact. In it the sum of the ratio resistances is constant, being equal to the resistance of the meter wire, while it is often advantageous to change this sum (Art. 215) ; the ratio is usually a fraction, precluding mental computation, and the apparatus lacks portability. The box bridge obviates these difficulties somewhat ; it is an appara- tus in which the ratio resistances {r^ and r^ of the previous form), as well as the standard resistance, are all wire coils con- tained in one box. This form of bridge was introduced in connection with the telegraph work of the postroffice depart- ment in England ; hence it is often called the post-office resistance box. The sets of ratio coils, Bg and B^ (Fig. 129), take the place of the meter wire and slider, and each usually contains resistances of 1, 10, 100, and 1000 ohms. One resistance only from each set is to be used at a time ; these may be selected so that the ratio shall be either 1, 10, 100, 1000, 0.1, 0.01, or 0.001. If the reference resistance has a total value of 10000 ohms, the 294 ELECTEICITY range of measurement is from 0.001 ohm to 10 000000 ohms, there being from one to four significant figures in the result. Often more significant figures may be obtained by interpolation from the galvanometer readings. Sometimes the three sets of resistances are permanently con- nected, and sometimes the connections have to be made as required. In the latter case arrange the apparatus in accord- ance with the scheme of Fig. 129. Having selected a ratio, the known resistance B is varied to secure a balance between the points D and E, as indicated by zero deflection of the galvanometer in the bridge when the key K is closed. Then, since (Art. 207) -B ; JC = Ro '. Hi, Fig. 129. Box Bridge the unknown resistance is obtained by the very simple calculation of multiply- ing B by some power of ten. When X is wholly unknown it is well to select a ratio of equality, as 10:10; and with this to find an approximate value for X. Then change the ratio so that B shall have the largest possible value, and make a final determination of X. For instance, if with a ratio of 10 : 10, X is found to lie between 7 and 8 ohms, make the ratio 1000 : 1, when the balance may be found with B equal to 7341 ohms, giving for X the final value 7.341 ohms. Sometimes, in addition to the ratio coils and the resistance coUs, a key, galvanometer, and battery are included in the case of the apparatus. The collection is then called a testing set, and it may be exceedingly compact and convenient. It is also evident that the method may be employed when the apparatus is made up with three separate, simple, resistance boxes. 215. Maxwell's Rule for Wheatstone's Bridge An inspec- tion of Fig. 129 indicates that the resistances B, X, Bg, and B^ are represented by the four sides of a parallelogram, in one diagonal of which the galvanometer is placed, and in the other the battery. From the symmetry of the arrangement it does THE TANGENT GALVANOMETER 295 not matter, so far as the relations between the resistances are concerned, which diagonal contains the battery. But to secure the greatest sensitiveness Maxwell gives the following rule. " Of the two resistances, that of the battery and that of the galvanometer, connect the greater resistance so as to join the two greatest to the two least of the four other resistances." CXXVn. RESISTANCE WITH A TANGENT GALVANOMETER Measure several unknown resistances, both large and small, by the method of three observations with a tangent galvanometer; also find the resistance of the battery employed and the electromotive force. 216. The Tangent Galvanometer. — A simple form of galva- nometer consists of a number of turns of wire wound on a circular frame of large diam- eter, usually twenty centi- meters or more, supported with its plane in the plane of the magnetic meridian, and having a short perma- nent-magnet needle sus- pended in the center of the coil (Fig. 130). The needle carries a light pointer, and a divided circle is provided for measuring the angular deflection of the needle. If various steady currents be sent through such a galva- nometer, they will produce deflections of the needle such that the current strengths are proportional to the tangents of the angles of deflection. Therefore these current strengths may be expressed in any desired units by multiplying the tangents of the angles of deflection by a Fio. 130. Tangent Galvanometer 296 ELECTEICITY properly determined constant. If -K" is the constant found as described in Art. 242, and 6 is the deflection observed, the current strength in amperes is I=Kta.n0. Before a tangent galvanometer is used for measurement it must be carefully adjusted to the magnetic meridian. Its own needle wiU serve as a compass in making an approximate adjustment. Connect a cell of battery, in series with a rheostat if necessary, through a reversing key (Art. 218) to the galva- nometer. Observe the deflection produced, by averaging the readings of the two ends of the pointer ; reverse the current and read again. If these opposite deflections are equal, the instrument is properly placed ; if they are not equal, rotate the plane of the coil and repeat the observations; continue until the opposite deflections are equal. References. — For an extended account of the tangent galvanometer, and of work to be done with it, consult Stewart and Gee, Physical Measurements, Vol. II, pp. 225-274 ; Gray, Absolute Measurements in Electricity and Mag- netism, Vol. II, pp. 347 et seq. 217. Resistance by Three Observations with a Tangent Gal- vanometer, and Battery Resistance by Ohm's Method. — Connect the unknown resistance, X, a rheostat, B, and a constant battery, B, in series, through a reversing key, K, with the galvanometer, G (Fig. 131). By changing the number of cells of battery used, or by altering the resistance R, cause the deflection of the galvanometer to be about 45°. The battery should be so arranged that B may be as small as pos- sible, preferably 0. Observe the deflection of the galvanometer, measured, as should Fig. 131. Resistance always be the case, by the average of the WITH Tangent Gal- ^^^ readings given by the two ends of the needle when the current flows first in one direction and then in the reversed direction. If H represents the electromotive force of the battery, B its resistance, G the resistance of the galvanometer, B^ the value THE TANGENT GALVANOMETEE 297 of E, X the unknown resistance, ^j the galvanometer deflection, and ^the galvanometer constant, then, by Ohm's Law, from the first observation, „ = ^tan e.. B+ G + R^-^X ^ Leaving the battery unchanged, remove X, and alter B till a deflection, 6^, of about 30° is obtained, and let R^ be the value of R giving this result ; then, from the second observation, E = ^tan^. B+ G + R^ Further, alter R to give a deflection, ^3, of about 60°; if ^3 is the value of the resistance required, = ^tan 0o. B+ G + R^ ^ Dividing the second equation by the third, ^ + g + .^3 _ tan ^g B+ G-\- R^~ t&zi e^ and ^^^^Je^tan^.-iggtan^a tan ^3 — tan 6^ Calculate the value oi B -{■ G, which is required in finding X. If the galvanometer resistance is known, the resistance of the battery is determined by making the second and third observa- tions only. Dividing the third of the above equations by the first, B-V g + -Si + X ^ tan^3 J? + G + i?3 ~ tan 6^ tan 6. -^iB+G + R^)-{B+G + R^). ^1 from which X = tan I By eliminating B + G between the second and third equa- tions given above, the electromotive force of the battery may be obtained if the galvanometer constant K is known, as expressed in the following relation. ^ = JTtan e, tan 6, — ^ ~ ^^ tan ^3 — tan 0^ 298 ELECTEICITY Fig. 132. Rotating Commctatok The above methods for battery resistance and electromotive force are known as Ohm's methods ; they may be used with any nonsensitive galvanometer, for constant current cells. 218. Commutators, Reversing Keys. — When frequent changes in the direction of a current through part of an apparatus are required, some form of com- mutator should be used. An efficient and easily con- structed one may consist of a block of wood in which are four holes, bored only part way through, these holes being filled with mer- cury and connected as fol- lows. One terminal of the circuit is connected to hole 2 (Fig. 132), and the other to hole 3 ; while the apparatus through which the current is to be reversed is connected to holes 1 and 4. Two wire links are placed to join 1 and 2, and 3 and 4, as shown by the heavy lines. If, now, the links are lifted and rotated 90°, so that they connect 1 and 3, and 2 and 4, as indicated by the dotted lines, the current through G will be reversed. A plug commutator is sometimes made, in which the four mercury cups are replaced by quadrants of brass, and the wire links by plugs which join the quadrants as desired. The rocking commutator, using six mercury cups, is a most convenient form. Gups 1 and 2, or 3 and 4 (Fig. 133), are connected to the battery, and 5 and 6 to the galvanometer or other instrument ; 1 and 4, and 2 and 3 are permanently connected by diagonal wires. A rocker of the form shown, consisting of two three-pronged forks, joined by an insulating handle, H, Fig. 133. Rocking Commctator THE DIFFERENTIAL GALVANOMETER 299 permits 5 to be joined to either 1 or 3, and at the same time 6 is joined to either 2 or 4. The removal of the rocker opens all circuits. If the diagonal wires of the commutator are removed, one circuit whose terminals are joined to 5 and 6 may be connected to either one of two other circuits whose terminals are 1 and 2, or 3 and 4. There are many other forms rSP of commutators, the operation of which will be understood from inspection. CXXVm. RESISTANCE BY THE DIFFERENTIAL METHOD Compare several large and small resistances of a resistance box ■with approximately equal standard resistances, by means of a differential galvanometer, using the methods of single observation, substitution, and reversal. 219. The Differential Galva- nometer. — The coils of a gal- vanometer are often wound in two equal parts, Cj and C^ (Fig- 134), synunetrically placed with respect to the needle, and so connected that the same current, or equal currents, may flow through the coils in opposite direc- tions. These currents in the two coils tend to turn the needle in opposite directions, and it can then indicate only the differ- ence in their effects. Often the terminals of each coil are separately brought to binding posts in order that the coils may be connected to give differential effects, or by joining them so that the current flows through both in the same direction the galvanometer becomes a sensitive one of the ordinary type. Fig. 134. Differential Galvanometer 300 ELECTRICITY Fig. 135. Magnetic Adjustment Magnetic Adjustment. — Connect the coils as indicated in Fig. 135, so that the current going in at the inner end, i, of the first coil enters the second by its outer end, o. If the termi- nals of the coils are not marked, a simple trial will indicate whether the coils are con- nected for differential or summational effects. By altering the position of one coil or a part of one coil, the adjustment is to be made so that the same current flowing through the two coils in opposite directions shall produce no effect upon th6 needle. Resistance Adjust- ment. — Connect the coils in parallel to give differential effects ; that is (Fig. 136), connect one terminal of the battery to the outer end of one coil and to the inner end of the other. Make the other connections as shown; then, when the resistances of the two branch circuits are equal, equal currents will flow through the two coils, and there will be no deflec- tion. If necessary insert external resistance in one branch circuit until this condition is fulfilled. This may be accomplished by using a rheostat, or by varying the length of one of the lead wires. 220. To measure a Resistance greater than that of One of the Galvanometer Coils. By Single Observation. — After completing the adjustments insert a standard resistance, B, and the unknown resistance, X, as indicated in Fig. 137. Adjust R until no deflection of the galvanometer is caused by closing the battery circuit. Then Xis equal to R. If It cannot be adjusted to produce an exact balance, calculate the true value of X by interpolation between the nearest two values of B. Fig. 136. Resistance Adjdstment Fig. 137. Method OP Single Obsek- vation THE DIFFERENTIAL GALVANOMETER 301 By Substitution. — In case the adjustment of the galvanom- eter is uncertain, after securing a balance as nearly as possible by the method described above, note the constant deflection resulting ; substitute for X a standard resistance box, and adjust it to produce the same deflection. The substituted resistance is equal to A'. In this case the resistance B serves merely as a rheostat, and need not be a standard. By Reversal. — The galvanometer may be connected as indicated in Fig. 138, without any previous adjustment. S, a rheostat inserted in one branch circuit, is so adjusted that no Fig. 138 Fig. 139 Method of Reversal Fig. 140 deflection occurs when the battery circuit is. closed. Insert the standard resistance B and the unknown resistance X (Fig. 139) ; adjust B until a balance is again effected, and let B-^ be its value. Interchange B and X (Fig. 140), and let B^ be the resistance required to produce a balance. If g-^ and g^ are the entire resistances (unknown) of the two branches of the circuit. B^-.X^g^-.g^, and ^•■R'i=9\-9v from which X= ViJjiJ^ (Compare the above methods of using a galvanometer with the methods of using a balance described in Arts. 43 and 47.) 302 ELECTRICITY 221. To measure a Resistance less than that of One of the Galvanometer Coils When the unknown resistance is less than that of one of the galvanometer coils, greater sensitiveness will be obtained by a modification of the previous methods. Connect the battery to the galvanometer so that the same current shall pass through the two coils in series in opposite directions (Fig. 141) ; make the standard resistance B a shunt to one coil, and the unknown resistance X a shunt to the other. Adjust B to secure a balance, when, if the galvanometer is in perfect adjustment both for magnetic effect and resistance, X is equal to B, as in the method of single observations previously described. Without previous adjustment of the galvanometer the methods of substitution and reversal may also be applied with this system of connections. Fig. 141. Method OF Shunts CXXIX. RESISTANCE BY THE FALL OF POTENTIAL Measure the resistance of an incandescent lamp while it is lighted ; also the internal resistance of a series of secondary cells, and of the several cells separately. 222. Ammeters and Voltmeters. — The ammeter is a low- resistance galvanometer in which a pointer, moving over an empirical scale, indicates the strength of the current flowing through the instrument. It is to be connected in series with the circuit, its resistance being so low that for the currents to which it is adapted its insertion does not appreciably alter the current strength. The voltmeter is a high-resistance galvanometer in which the empirical scale indicates the potential difference which must be applied to its terminals to cause a sufficient current to flow through it to deflect the pointer by various amounts. It is to be used on a shunt circuit, and preferably only for momentary RESISTANCE BY FALL OF POTENTIAL 303 observations. Its resistance is so high that when applied as a shunt it does not appreciably alter the strength of the current. The voltmeter may be applied to measure the difference of potential of two points between which no current is flowing, provided that the very small current which will flow through the voltmeter does not disturb the potential difference. Voltmeters and ammeters are commonly of the D'Arsonval galvanometer type (Art. 209), though other forms are sometimes used. 223. Resistance with Voltmeter and Ammeter. — The method of fall of potential is based upon Ohm's Law. It may be very Fig. 142. Resistance with Voltmetee and Ammetee conveniently applied to the measurement of resistances of mod- erate size, and also of small resistances, if suitable voltmeters and ammeters are available. Arrange to send a current of any convenient value through the resistance to be measured, and a suitable ammeter in series. Connect the voltmeter to the terminals of the unknown resist- ance in a shunt circuit. (See Fig. 142.) If E is the difference of potential indicated by the voltmeter while the current I is flowing, the unknown resistance is I 224. Battery Resistance with Voltmeter and Ammeter. — Con- nect an ammeter, a rheostat, and a key in series with the bat- tery, and a voltmeter as a shunt to the battery, as indicated in Fig. 143. Adjust the rheostat so that when the key is closed 304 ELECTRICITY the current passing shall have any convenient value, /, and let E^ be the difference of potential between the terminals of the battery, as indicated by the voltmeter, while this current is flow- ing ; let E^ be the voltmeter reading when the key is open and no current is flowing ; then the internal resistance of the battery ^ \^4\v^^ IS I ^-\X\ ^ ^^ Internal Resistance OF Battery This method is particularly applicable to the measurement of the resistance of a secondary battery. 225. Battery Resistance with Voltmeter and Standard Resist- In the place of the ammeter and rheostat, in the above method, put a standard resistance. Let -fi^j be the difference of potential while the current is flowing through the resistance B ; and let E^ be the difference of potential of the battery on open circuit ; then the battery resistance is Fig. 143. ance. B = B E, 226. Battery Resistance with Con- denser and Resistance. — The method last described will be better adapted to the measurement of the resistances of single cells if the voltmeter is replaced by a condenser and ballistic galvanom- eter. The charges received by the con- denser are proportional to the potential differences. Make the connections as indicated in Fig. 144. Close the key ^2, completing the battery circuit, and at once press the key K^ firmly and for a very short time upon the lower contact ; release the key quickly. The condenser will have been charged 'to a potential difference equal to that of the battery terminals when Fig. 144. Battery Resistance with Condenser THOMPSON'S METHOD 305 on the closed circuit, and the galvanometer will be deflected an amount proportional to this charge (Art. 253). Let d-^ be the deflection. Now, leaving the key K^ open, again charge and discharge the condenser, and let d^ be the deflection produced. Then, if B is the resistance in the battery circuit, the battery resistance is The observed deflections of the ballistic galvanometer, if made with a telescope and scale, must be corrected, to make them proportional to the quantities of electricity, as described in Art. 252. The value of B should not be much greater than that of B, though if the latter is very small, too small a value of B will cause too rapid a polarization of the cell. The method is there- fore adapted to constant cells and those of high resistance. A very full description of the method is given in the reference. Refekence. — Carhart and Patterson, Electrical Measurements, pp. 100-109. CXXX. GALVANOMETER AND BATTERY RESISTANCE BY THE WHEATSTONE'S BRIDGE Determine the resistance of a galvanometer by Thompson's method, and the resistance of a gravity cell by Mance's m^ethod. 227. Thompson's Method for Galvanometer Resistance. — This method is based upon the principle of Wheatstone's bridge. The arrangement of apparatus differs from that previously described (Fig. 120) in that the galvanometer is taken out of the " bridge " and is placed as the unknown resistance, as shown in Fig. 145. A current will now flow through the galvanom- eter continually, producing a deflection. If this deflection is too large, it may be modified by a control magnet, by a shunt, by a resistance in the battery circuit, by using the galvanom- eter differentially, or by using two cells of battery joined in opposition, according to circumstances. 306 ELECTEICITY Making the bridge connection from D to E will usually alter the current flowing from A to C, and thus cause a change in the galvanometer reading. But by trial a point, E, may be found which has the same potential as D, so that opening and closing the bridge causes no change in the galvanometer deflection. Then the resistances are related as follows (Art. 207) : r^:r^ = R: G. If the galvanometer is of high resistance, a box bridge is preferable to the slide-wire form, as the resistance of the ratio arms may then be made more nearly equal to that of the galva- nometer, a condition securing greater sensitiveness. 228. Mance's Method for Battery Resistance. — The details of this method are those of the preceding one, except that the Fig. 145. THOiMPSON's Method Fig. 146. Mange's Method battery and galvanometer change places. The method is suit- able only for a constant cell. The connections are shown in Fig. 146. Some current from the battery will always flow through the galvanometer, causing a deflection. The adjustment consists in finding such a point of contact, E, that opening and closing the bridge does not alter the galvanometer reading. Then B and E are at the same potential, and the resistances are in the following proportion. r^:r^ = R:B. COMPENSATION METHODS 307 CXXXI. BATTERY RESISTANCE BY COMPENSATION Determine the resistances of various cells of bp,ttery. 229. Beetz's Method for Battery Resistance The following method for measuring the resistance of a battery has the advan- tage of requiring the circuit to be closed only momentarily, thus avoiding to some extent the polarization of the cell. The h E' R R, B D Tvpjz 3 — r^v Fig. 147. Beetz's Method for Battery Eesistance principles of the method may be described in connection vrith the apparatus as follows. Fig. 147 represents a slide-wire bridge, the resistance of the slide wire of which is known, H^ and B^ two small resistance boxes, X a three-point key, G a galvanometer, U the cell whose resistance, JS, is to be deter- mined, and e a cell of less electromotive force than U. The connections having been made as indicated, the like poles of both cells being connected to the key, it is evident that the resistances Hi and Jt^ and the point of contact C can be so adjusted that the difference of potential produced by e between the points K and C will be counterbalanced by the opposite potential difference between the same points produced by U. When this condition is secured the galvanometer will show no deflection. This must be determined by making only very short contacts with the key. If the key is closed even for a few seconds, the resistance of the cell changes, owing to polari- zation, and thus becomes uncertain. Represent the total length of the bridge wire, BD, by li, the length from 5 to C by l^, and 308 ELECTRICITY the resistance of unit length of the wire by p (Art. 240). Neg- lecting the connections, the external resistance in the upper circuit is E-^ + l^ p + JR^ ; represent this by a^, and let b^ be equal to B^ + l^ P\ then by Ohm's Law the current in the upper circuit is j_ ^ _« ^ + «! i>i' from which E JS + aj e \ Alter the resistance B^, or B^, so as to obtain a new point of contact, differing considerably from the first, which will give new values, a^ and h^, corresponding to aj and 5j of the first observation. Then, as before, E _B + a^_B + a^ and "2 h Fig. 148. Benton's Method FOR Battery Eesistance Instead of the two resistance boxes, B^ and B^, and the slide-wire bridge, a single thin stretched wire may be used, simplifying the apparatus required. 230. Benton's Method for Battery Resistance. — Beetz's method can be applied to the investigation of only such cells as have an electromotive force greater than the auxili- ary cell. The following method is not limited in this respect, and it is better adapted for cells of low internal resistance. The apparatus required consists of three resistance boxes, an auxiliary cell, a low-resistance galvanometer, and a special key. These are connected as indicated in Fig. 148, E' being the cell investigated, and E" the auxiliary cell, the like poles of which are connected to the key. The key has five connections, such that the first pressure brings three points into contact, closing KOHLRAUSCH'S METHOD 309 the two battery circuits, and then a further pressure closes the galvanometer circuit by means of an insulating contact piece. With R'" = 0, and R' set at any small resistance, R" is adjusted so that there is no deflection of the galvanometer when the key is closed ; then A and C are at equal potentials. The key is to be closed only for an instant, otherwise polarization may result. If R^ and R^' are the values of the resistances in the boxes, and B' and B" are the respective battery resistances, the condition for equal potentials at A and C is i?i' + B' R^' + B" R' is now set at a large resistance, ^2'' while R" is left unchanged. R'" is adjusted until no deflection occurs upon closing the key ; let R^" be the resistance required. The condition for equal potentials at A and C is -B2 -^1 R^ + R^" + B' ~ R^' + B"' Equating the first members of these equations and reducing, the internal resistance of the cell is R-i ~ -^1' Reference. —J. R. Benton, Physical Review, Vol. 16, p. 253, 1903. CXXXn. ELECTROLYTE RESISTANCE BY KOHLRAUSCH'S METHOD Find the specific resistance of a ten per cent, solution of copper sulphate and the internal resistance of various cells singly, in series, and in parallel. 231. Electrolyte Resistance with Alternating Currents.— Kohlrausch's method for electrolyte resistance avoids the influ- ence of polarization and allows the resistance to be measured directly, just as that of a metallic conductor, by using in the measuring device currents rapidly alternating in direction and 310 ELECTEICITY of exactly equal strength, between electrodes of large capacity. This current is conveniently obtained from an induction coU, and the detector is usually a telephone. The principle of measurement is that of Wheatstone's bridge, though the bridge is often of special construction to facilitate the use of the induc- tion coil and telephone, which replace the battery and galva- nometer respectively. The cell whose internal resistance is required, or the vessel containing the electrolyte, is connected as the unknown resistance. A separate cell is, of course, required to operate the induction coil. A sketch of the con- nections is shown in Fig. 149. ^3 and R^ represent the slide Fig. 149. Telephone Bridge for Alternating Currents wire, and A the sliding contact. The observation consists in adjusting the contact until the sound of the induction current in the telephone becomes a minimum. Then the ratios of the various resistances are The scale attached to the slide wire, instead of being a scale of equal lengths, may be divided to show directly the ratio of the lengths, ^3 to B^, for the various positions of the sliding contact. -Bj may then be conveniently 1, 10, or 100 ohms, and the unknown resistance is found at once by multiplying the scale reading by Ry 232. Electrolyte Resistance. — The specific resistance of an electrolyte may be calculated, as for a solid (Art. 235), from DIRECT DEFLECTION METHODS 311 measurements of the resistance of a column of the liquid of known length and cross section. Geometrical measurement of the space between two electrodes is seldom convenient, and the more usual method is to compare the unknown electrolyte with that of a standard solution in the same containing vessel. A useful standard solution is a saturated solution (about twenty- six per cent.) of sodium chloride. The liquid is to be shaken up with an excess of salt just before being used. The conductiv- ity of the solution is as follows (Kohlrausch) : Temperature 15° 16° 17° 18° 19° 20° 21° Conductivity, K 0.2015 0.2063 0.2112 0.2161 0.2210 0.2260 0.2310 Fill the electrolyte vessel with the salt solution and deter- mine its resistance, rj, using the Kohlrausch method described in the preceding article ; substitute the unknown electrolyte and find its resistance, r^ ; then the conductivity desired is, since the conductivities are inversely as the resistances, '•2 Eefeeences. — Kohlrausch, Physical Measurements, pp. 317-321; Ostwald, Physico-Chemical Measurements, pp. 222-229. CXXXm. INSULATION RESISTANCE BY DIRECT DEFLECTION Find the resistances of glass and porcelain insulators, and of the insulation of a cable. 233. Measurement of High Resistance by Direct Deflection. — A cup-shaped insulator may be arranged for testing by pouring mercury into the interior and partially immersing the cup in a mercury bath, the edge of the cup where not immersed hav- ing been previously cleaned, dried, and coated with paraffin. Connect one terminal of the circuit to the mercury in the cup, and the other to the exterior bath. In the case of insulated wire that is waterproof, make of it a coil of a known length, and immerse it, except the ends, in a water bath. One circuit terminal is to be connected to the wire and the other to the 312 ELECTRICITY water bath. When the material is in sheets, portions of the surfaces may be silvered, and the electrodes connected to these silvered portions. Care should be taken to have a wide margin of clean and dry surface around the silvered portion. The con- nections for tests of the insulations of permanently placed wires and cables will suggest themselves. Connect a sensitive galvanometer and the unknown resistance in series with a battery or other source of electromotive force. Usually as high an electromotive force as is available will be required, such as that of a large storage battery, a commercial lighting circuit, or a railway power circuit. Let E be the elec- tromotive force used, measured with a voltmeter ; X, G, and B the unknown, galvanometer, and battery resistances respectively ; d the number of divisions of the scale at a meter distance, meas- uring the constant deflection produced; and K the figure of merit of the galvanometer. Then dK ^ X+B^ (?' and X=^-{B+G). dJi The battery resistance may be neglected in comparison with the other resistances. 234. High Resistance by Direct Deflection and Double Read- ings. — ■ The measurement of high resistances by the method of double readings is often more convenient than the one described above. It is not necessary to know the electromotive force and galvanometer constant, but a standard resistance of high value, 100000 ohms, for instance, is required. The electromotive force is first connected to the galvanometer and unknown resistance in series, and then to the 100000 ohms resistance and galvanometer. The deflections produced, d^ and d^, may be considered as inversely proportional to the resistances, from which X=4^ 100000. SPECIFIC RESISTANCE 313 It is desirable to have the two deflections nearly equal ; to secure this it will usually be necessary to shunt the galva- nometer when it is used with the 100000 ohms. If this shunt is such that the galvanometer sensitiveness is reduced to - of n that which it had in the first trial, then A-=w^ 100000. In these formulte the resistance of the battery and galvar nometer are considered as inappreciable in comparison with the high resistance being measured. This is clearly permissible for the comparison with the insulation resistance, and in comparison with 100000 ohms the resistance of the shunted galvanometer is also very small. If it is not permissible to neglect the galva- nometer and battery resistance, the following complete formula may be used. Represent the high comparison resistance by B, the shunt resistance by S, and the battery and galvanometer resistances by B and G ; then the unknown resistance is dX B+G + B + ^^±^\-{B+G). CXXXIV. SPECIFIC RESISTANCE BY THE COMPARISON OF POTENTIALS Determine the resistances of short pieces of copper and German silver wire, and And their specific resistances. 235. Specific Resistance. — The resistance in ohms of a centi- meter of length of a substance when the area of cross section is one square centimeter and its temperature is 0°, is its specific resistance. If Bf is the measured resistance at the temperature t of the substance in the form of a wire of length I and sectional area s, and a is the temperature coefficient of the substance (Appendix, 314 ELECTEICITY Table 26), then the resistance B^, of the piece of wire at 0°, is found from the relation Bf = i?g (1 + at), and the specific resists ance p is determined by the equation 236. Resistance by Method of Comparison of Potentials. — The method of comparison of potentials is applicable to the meas- urement of very small resistances, such as the resistances of short lengths of conducting wires. A standard resistance is required whose value is nearly equal to that of the unknown resistance. If no single stand- ard of a sufficiently small value is available, several standards of higher value may be used in parallel; or, if the unknown resistance is a wire, a piece of it may be selected such that its resistance is approximately equal to that of the standard. Connect the unknown resist- ance X, a standard resistance, B, a rheostat, r, and a constant bat- tery, B, in series. By means of a suitable key (Art. 218), or switch, arrange to connect a high-sensibility galvanometer, G, to the terminals of either B or X, as indicated in Fig. 150. The readings of the galvanometer when so connected can be given a convenient value by altering r. Since the fall of potential is proportional to the resistance, the ratio oi B to X will be the same as that of the currents which will flow through the galvanometer when it is connected first to B and then to X. When the apparatus is arranged as described, these currents will be very small and nearly equal, and it may be assumed that they are proportional to the observed galvanometer deflec- tions, c?j and d^ respectively. Then B-.X^d^-.d^. Fig. 150. Compakison op Potentials THE LOW-EESISTANCE BRIDGE 315 237. The Low-Resistance Bridge. — A form of apparatus often employed for measuring the resistance of wires and rods, or irregular low resistances such as armature windings, consists of a Wheatstone's bridge specially constructed so that the resistances of the connections may be eliminated by a method of double readings. The known resistance, J?j (Fig. 151), is a straight wire attached to a graduated scale which shows the actual resist- ance in ohms of different- lengths of wire. The portion of this wire which is used in balancing the bridge is deter- mined by a sliding contact, A^. The unknown resistance, X, if a wire or rod, is stretched be- tween two clamps, and the length of this used in balancing is limited by a movable contact, Cj, and is measured by a centi- meter scale. The ratio arms are two resistances, S^ and JR^, arranged to give various ratios. The galvanometer and battery are connected as indicated. With the contact on the unknown resistance at Cj, and with a suitable ratio between Bg and B^, move the sliding contact ^j until a balance is secured, indicated by no deflection of the galvanometer when the bridge connection is made. Then A^B : DC^ = ^3 : E^. Move the contact on the unknown resistance to C^. Adjust the slider to secure a balance, and if A^ is its new position, from which it follows that Fig. 151. Low-Eesistance Bridge AA c^c^ B„: R. 316 ELECTKICITY The resistance A-^A^ is read directly from the graduated scale, and this multiplied by the ratio of B^ to B^, usually a power of 10, gives the resistance of the known length of the substance being investigated. Any irregular resistance may be connected to the clamps, and the contacts Cj and Cj may be made to these clamps, or to other points between which the resistance is required. A slide-meter bridge may be used for ^^ if the resistance of its wire is known, and two resistance boxes will serve for ^3 and B^, making the method one easily applied with simple apparatus. CXXXV. TEMPERATURE COEFFICIENT OF RESISTANCE BY FOSTER'S METHOD Determine the constants of an ohm coil, that is, its resistance at 0° and its temperature coefficient. 238. Temperature Coefficient of Resistance. — Standard resist- ance coils are usually constructed, as described in Art. 212, so that they may be surrounded with ice, water, or oil baths, to give them definite known temperatures. Let the values of the resistance whose coefficient is desired be determined as described in Art. 239, when it is at two temperatures differing consider- ably, at 10° and 40°, for example. Care must be taken that all other parts of the apparatus remain at a constant temperature. Let i?j and B^ be the observed resistances at temperatures t^ and t^, and J?o its resistance at 0°, and a the temperature coefficient; then Bj^ = i^o (1 + at^), and -Eg = Bq(1 + at^) ; , Be, — -K, whence a = — — R\h ~ R-ih 239. Carey Foster's Method for Comparison of Resistances. — This method is adapted to the accurate comparison of two nearly equal resistances, and it is very convenient for determining the variations in the resistance of a coil due to changes in its CAREY FOSTER'S METHOD 317 temperature. The principle of the method is that of Wheat- stone's bridge, modified so that, by two observations, the difference between two resistances is determined in terms of the slide wire, the resistance of all connections being eliminated. It is analogous to the comparison of masses by the method of double weighing, and, like this method, it is of the highest precision. Designate the coil to be tested by X, a standard coil of the same nominal value by S, and two auxiliary coils whose resist- ances are each approximately equal to S, by iJj and B^. Con- nect these four coils, a galvanometer, a battery, and a suitable Fig. 152. The Carev Foster Method bridge apparatus, as indicated in Fig. 152. Adjust the bridge contact until a perfect balance is secured. Since the four resists ances are approximately of the same value, the contact will be near the middle of the wire (Art. 208). Interchange the resist- ances S and X. If these are exactly equal, the balance will not be disturbed ; if they are not equal, it will be necessary, in order to restore the balance, to move the contact in the direction of the greater resistance just so much that the resistance of the short length of the slide wire between the two points of contact is equal to the difference in the resistances of the standard, S, and the unknown, X. Determine this length of wire by observa- tion, and find its value in ohms by the aid of the methods of the following article. 318 ELECTRICITY For conveniently interchanging the resistances, and for accu- racy in the measurements by this method, elaborately constructed bridges are often provided. 240. Resistance of the Slide Wire. — Usually the direct obser- vations give the difference between the resistances compared in terms of a length of the slide wire, and it is necessary to ascer- tain the resistance, />, of the unit length of the wire, in order to express this difference in ohms. Method I. — If a single standard resistance is available, the resistance of which is less than that of the slide wire, this standard may be balanced against a heavy copper bar of inap- preciable resistance put in place of X, as described in the pre- vious article. By interchanging and again balancing, a length of the slide wire whose resistance is equal to that of the standard is determined. From this is deduced the resistance, p, of unit length of the wire. If no single standard of sufficiently small value is available, two one-ohm coils and one ten-ohm coil may be used. Place the ten- and one-ohm coils in parallel, on one side of the bridge, and the other unit coil on the opposite side, and proceed as before. The combined resistance of the pair of coils is 10 X 1 -i- 10 -|- 1 = 0.90909 ohms, giving for the difference between the interchanged resistances, 0.09091 ohms. Other similar combinations will suggest themselves if they are available and more convenient. Method U. — In case the only available standard has a resist- ance greater than that of the slide wire, the following method, requiring two complete observations, may be useful. Let Q be any convenient but unknown resistance, a piece of wire for example, whose resistance is less than that of the slide wire. Balance this against the negligible copper bar resistance, and by interchanging determine the length, Zj, of the slide wire whose resistance is the same as that of Q\ then Q = ply Place the standard S in parallel with §, and balance the com- bination, in two positions, against the negligible resistance, as CALIBRATION OF BRIDGE WIRE 319 before. Then if l^ is the length of the slide wire between the two points of contact, and p = s^' ~ ^" tjig Method m. — The resistance of the slide wire may be meas- ured directly with an independent Wheatstone's bridge. (See Arts. 208 and 237.) Calibration of Slide Wire. — It has been assumed that the shde wire is of uniform resistance throughout, and usually the errors from such assumption are very small. But where extreme accuracy is required, it becomes necessary to calibrate the wire (Art. 241). CXXXVI. ERRORS OF A BRIDGE WIRE BY BARUS'S METHOD Make a ten-part calibration of the wire of a Wheatstone's bridge. 241. Calibration of Bridge Wire. — Barus's method for cali- brating a bridge wire is an adaptation of the Gay-Lussac method of simple calibration, described in Art. 26. To use this method there must be provided as many separate coils of approximately equal resistance as there are parts in the proposed calibration ; for instance, ten coils of one ohm each. Each coil should have terminals arranged to dip into mercury cups for making connec- tions. For the purposes of this problem provide a series of eleven mercury cups so spaced that the ten coils may be con- nected in series as indicated in Fig. 153. Designate the iirst coil the calibrating coil, K, and the other coils by the numbers II, III, IV, etc. Connect the series of coils to the bridge wire by means of heavy copper wires or bars dipping into the two end cups ; connect a cell of constant battery as indicated. A sensitive galvanometer has one terminal joined to the first mer- cury cup, and the other terminal to the slide contact. The current flows from Ato C through the two branches of the circuit. 320 ELECTRICITY the series of ten coils, and the bridge wire. As explained in Art. 207, corresponding to the potential of any point in one branch, there is exactly the same potential at some point in the other branch. Theoretically, then, it ought to be possible to place the slide contact at a point, p^, having a potential equal to that of cup 1, in which case no current will flow through the galvanometer. The construction of the slider will probably render it impossible to find this point, and it may be assumed to be at the very beginning of the wire. Take the galvanometer wire out of cup 1 and place it in cup 2, and find a contact p^ such that there is no deflection of the galvanometer. 5 ii|iiM|iiii{iin|iiii|iiii|iiii|iiii|iiii|iiii|iiii|iiii|iiii|iiiiniii|iiii|iiii|iiii|iiii|iii Fig. 153. Caweeation of Bkidge Wire The potential of p^ is the same as that of cup 2. It then fol- lows that the resistance of that portion of the bridge wire between Pi and p^ is in the same ratio to the resistance of the whole wire as the resistance of K is to the resistance of the series of ten coils.' Now interchange coils K and II, and find a new contact point, p^, giving no deflection while the galvanometer connection is in cup 2, and find a similar point, p^, when the galvanometer is connected to cup 3. The resistance of the portion of the wire between pg and p^ must be equal to that between p-^ and p^. Point pg will probably be near to p^, but will not coincide with it. Interchange coils K and III, and find new contacts, p^ and Pel giving no deflection when the galvanometer is connected to cups 3 and 4, and continue the operation till the coil ^occupies CALIBEATION OF BRIDGE WIRE 321 the place of Z, and the last contact is the end of the wire. Thus there will have been found ten successive portions of the wire, h=P^-Pv h=Pi-Ps' h='P&-Pf.^ etc., each having exactly the same resistance. If the bridge wire were of perfectly uniform resistance through- out, these observed lengths would aU. be equal. Otherwise, the correction to each portion of the wire is the quantity which must be added to it to make it equal to the average of the observed lengths ; and the correction at any point of the wire is the sum of the corrections to the several sections between the point and the beginning of the wire. These corrections being applied to any observed length of the wire, the length becomes strictly proportional to the resistance of the wire. The method can be employed for a calibration in any number of equal parts other than ten. Compare this description with that for the calibration of scales and thermometers, Arts. 26-30 and 129. An example of the calibration of a bridge wire in ten sec- tions is given. Calibration op Bridge Wire by bakus's method Hartmann & Bbaitn Wheatstone's Bridge No. 39 MarcTi 1, 1900 Position OF Coil. K Readings Section I Section COBREC- TION Point COKKECTION Pn Pn+1 Kx 0.00 cm 9.89 cm 9.89 cm 0-10 + 0.073 cm Oom 0.000 cm K\ 9.90 19.89 9.99 10-20 -0.027 10 + 0.073 A-, 20.00 20.99 9.99 20-30 -0.027 20 + 0.046 X, 30.12 40.10 9.98 30-40 -0.017 30 + 0.019 Kr. 40.19 50.20 10.01 40-50 -0.047 40 + 0.002 Jr« 49.92 59.90 9.98 50-60 -0.017 50 -0.045 K, 59.91 69.90 9.99 60-70 -0.027 60 - 0.062 X, 70.00 79,93 9.93 70-80 + 0.033 70 -0.089 K„ 80.06 90.05 9.99 80-90 -0.027 80 -0.056 ^1. 90.12 100,00 9.88 9.963 90-100 + 0.083 90 100 -0.083 0,000 CHAPTER XXI CURRENT STRENGTH CXXXVII. GALVANOMETER CONSTANT WITH THE VOLTAMETER Determine the constant of a tangent galvanometer by the electrolytic • deposition of copper. 242. Constant of Tangent Galvanometer. — The constant of a tangent galvanometer (Art. 216) is the factor K, which when multiplied by the tangent of the angle of deflection, 6, produced by a current, J, gives the measure of that current ; that is, J=^tan^. To determine the constant it is only necessary to observe the deflection produced by any known current. The strength of the current can be most conveniently measured by the work it will do in a specially arranged electrolytic cell called a voltam- eter. The most useful forms are those in which the amounts of oxygen and hydrogen gas liberated in the water voltameter are measured, or in which the amounts of silver or copper depos- ited from solutions of these metals are ascertained. The silver voltameter is the most accurate and is best suited for small cur- rents ; for large currents the copper voltameter is sufficient. 243. The Copper Voltameter. — Prepare a nonsaturated solu- tion of pure copper sulphate by dissolving 1 g of the crystals in each 4 com of distilled water. The solution should have a density of about 1.14. Provide an anode of pure copper and a cathode of platinum or copper. The latter must be carefully cleaned, dried, and weighed. 322 STAJ^DARD AMPERE 323 Adjust the galvanometer to the magnetic meridian (Art. 216), and arrange to pass a current through it and the voltameter in series. Notice that the connections ai-e such as to make the prepared plate the cathode. A rheostat may be included in the circuit (Fig. 154) to regulate the current, which should not exceed 1 ampere for each 25 square cm of cathode area. The deflection of the galvanometer should not be less than 30° nor greater than 60°. Allow the current to pass for from a half hour to two hours, and note the exact time in seconds. The galvanometer should be read frequently during this time, — every five minutes perhaps, — to detect any unsteadiness of the current. Adjust the rheostat, if necessary, to keep the current constant. The deflection of the galva^ , , , , I- . , Fig. 154. Constant of nometer is measured by the average of the Galvanometer four readings given by the two ends of the pointer when the current flows in one direction, and when it is reversed (through the galvanometer only) by the commutator K. At the end of the experiment the cathode is removed and again carefully washed, dried, and weighed. If w grams of copper are deposited in a copper voltameter in t seconds, the current flowing is, in amperes, 0.0003294 t 244. Standard International Ampere; Silver Voltameter. — The ampere is that current strength which, in a specified vol- tameter, deposits 0.001118 g of silver in one second. The spe- cifications for the voltameter are given in the references. The silver voltameter is employed when the greatest accuracy is desired, and especially for currents of less than one ampere. It may be used to calibrate a standard ammeter. Reference. — Carhart and Patterson, Electrical Measurements, pp. 158 and 328. 324 ELECTRICITY CXXXVm. JOULE'S EQUIVALENT WITH THE ELECTRO- CALORIMETER Determine the mechanical equivalent of heat with the electrooalorimeter. 245. Joule's Equivalent ; the Joule ; the Watt. — J-oule's equivalent of heat (Arts. 139 and 150) must be distinguished from the unit of energy, the joule. The joule is 10^ ergs, and Joule's equivalent is 4.2 joules. The joule is defined electric- ally as the quantity of work done in the transference of a quantity of electricity of 1 coulomb under a pressure of 1 volt ; it is also equal to the work done in 1 second by a current of 1 ampere passing through a resistance of 1 ohm. The joule is the quantity of work equal to that defined, regardless of the time in which it is performed. The power to do this much work in one second — that is, to do a joule of work per second — is the watt. From the relation of the various units it follows that the power of a given current in watts is measured by the product of the current strength in amperes and the pressure in volts. Joule's equivalent of the unit of heat may be determined with the electrooalorimeter, which consists of a coil of wire so placed in a water calorimeter that the heat developed by the passage of a current through the coil can be measured. Fig. 155 shows a simple form of such a calo- rimeter, while a more elaborate form is shown in Fig. 71. Weigh the calorimeter cup and stirrer, and measure the thermometer; fill the cup with water, cooled 10° below the air temperature, to such a depth that the coil will be wholly immersed when it is in position, and find the weight of the water. Let K be the heat capacity of the calorimeter, determined as explained in Art. 140. Fig. 155. Electrooalorimeter FIGURE OF MEEIT 325 Measure the resistance of the coil when it is in place. Observe the temperature of the calorimeter. Connect the current through a rheostat and an ammeter to the coil terminals, and allow it to flow until the temperature is as much above that of the room as at the beginning it was below this temperature. The current strength, which may be about five amperes, should be kept constant, and its average value, /, must be measured as accurately as possible. Note carefully the temperature and time when the current is started, and the temperature and time at the end of the experiment. Again measure the resistance of the coil, and let B be the mean of its resistance before and after heating. If t^— tj is the temperature change in the calorimeter while the current is passing, the heat developed is H=K{t^-t^). The current, /, being expressed in amperes, the resistance, R, in ohms, and the time, T, during which the current passes, in seconds, the value of Joule's equivalent in C. G. S. units is H By assuming the value of J, the method may be used to determine the current strength or the resistance. CXXXIX. FIGURE OF MERIT OF A GALVANOMETER BY DIRECT DEFLECTION Determine the figure of merit of a galvanometer, including the measure- ment of the battery and galvanometer resistances. 246. Figure of Merit of a Galvanometer. — The figure of merit of a galvanometer is a statement of its sensitiveness, and is usually expressed by the fraction of an ampere of current that would cause an apparent deflection, in a reflecting galva- nometer, of 1 mm on a scale placed 1 m from the mirror. It is also sometimes expressed by stating the number of ohms resist- ance through which an electromotive force of 1 volt would have 326 ELECTRICITY to be passed in order that the current shall be so reduced as to produce 1 mm deflection on a scale 1 m distant from the mirror. Connect the galvanometer in series with a cell of known electromotive force and a high resistance. Adjust the resist- ance to secure a readable deflection, preferably small. From the known electromotive force and the resistance of the circuit, including that of the galvanometer and battery, the current strength can be calculated. This in connection with the observed deflection enables the calculation of the figure of merit as defined. If the galvanometer is a sensi- tive one, it will not be convenient to put a sufficiently high resistance in series with it to keep the deflec- tion within readable limits. It will then be necessary to shunt the galvanometer (Art. 247). Connect the galvanometer, shunt, resistance, battery, and key, as indicated in Fig. 156. Let G, S, B, and B represent the resistances of the several parts of the apparatus, and B the electromotive force of the battery. Then the current through the battery is Fig. 156. Figuke of Mekit /„ = . B B + B + GS G+ S and that part of the current which flows through the galva- nometer is B S Ia = - B-\-B + GS G+ S If -B, -( B + B + G+ S GS \G + S G + SJ S la B FIGUEE OF MERIT 327 The quantity By may be called the virtual resistance ; it is the resistance through which the given electromotive force would produce a current equal to that which actually passes through the galvanometer. If the observed deflection of the needle is d centimeters on a scale D centimeters from the mirror, the deflection expressed in millimeters for a scale at a distance of one meter is ^ 10 d 1000 i A = = ; _D_ D 100 and finally the figure of merit is A ^,/l000^" A Daniell cell is usually sufficient for this work, though a standard ceU may be used. The galvanometer resistance may be determined by Thompson's method (Art. 227) or otherwise, and the battery resistance by Kohlrausch's method (Art. 231). Usually, however, the resistance of the battery and of the shunted galvanometer will be small, and may be neglected in comparison with the resistance R. A numerical example follows. Figure of Merit Queen D'ArsonTal Ballistic Galvanometer No. 92 May SO, 1897 Clark Standard Cell, H. & B. No. 100, at 19° . E= 1.43 volts By the telephone bridge the resistance of cell . B = 20. ohms Galvanometer resistance G= 1039.5 Series resistance ^ = 22000. Shunt resistance •*>' = 2- / „„ 2 X 1039.5 \ 1039.5 + 2 ,, -„-„«« i. Rjr= (22000 + 20 + ^^^ggg^^ ) 2 " ^^ *^^°°*^ °^"''- 328 ELECTRICITY The following steady deflection readings were obtained with the scale distance D = 100 cm. Zero Beading Second Keading - Deflection 38.85 cm 56.35 cm 17.50 cm 39.30 56.60 17.30 39.33 56.60 17.27 39.33 56.68 17.85 89.20 56.40 17.20 39.30 56.40 17.10 39.30 56.43 17.13 89.30 56.40 17.10 39.30 56.40 17.10 39.35 56.45 17.10 Mean d= 17.22 cm F = 1.43 X 100 11 465000 X 1000 X 17.22 = 0.000000 00072 amperes. 247. Sensitiveness of Galvanometers ; Shunts. — A suspended magnet galvanometer is made more sensitive by using a longer suspension fiber, or one with less torsion. A fiber of quartz is used for the most delicate work. The sensitiveness also varies with the number of turns of wire in the coils and with their nearness to the needle. The coils are often subdivided, are made interchangeable, and adjustable as to distance, as shown in Fig. 134. The sensitiveness will be increased by diminish- ing the effect of the earth's field, through astatization or a con- trol magnet (Art. 210), or by surrounding the galvanometer with an iron shield. The sensitiveness of a suspended coil galvanometer depends upon its suspension, the number of turns of wire in the coil, and the strength of the field magnets. It is nearly independent of the earth's field. Practically the sensitiveness of this type of instrument is altered by interchanging the entire suspended sys- tem, the construction often making this a convenient operation. SHUNTS 329 Galvanometers such as are commonly used for laboratory work have figures of merit ranging from 0.000000 3 to 0.000000 0002. If a less sensitive arrangement of the galvanometer is desired, it may be secured by using fewer turns of wire, either employ- ing only a part of the windings already provided or substituting new windings. The two coils may be connected differentially (Art. 219) so that one portion only partially neutralizes the other. Often the most convenient method is to use a shunt, — that is, to connect the two galvanometer terminals by a small resistance. A shunt does not reduce the sensitiveness proper of a gal- vanometer, but it enables the instrument to be used for meas- uring larger currents, since the shunt carries the greater part of the current, and only the smaller part passes through the galvanometer. If the ratio between the two parts is known, and that part through the galvanometer is measured, the total current may be determined. The current divides between the galvanometer and shunt in the inverse ratio of their resistances. If Is and Iq represent the currents through the shunt and gal- vanometer, and S and G are their respective resistances, then and Is + Ia S+G, but Is + Ig = I, the total current, and hence S±G I-Ig- ^ li S=\ G, the current through G is J^ of the total current, G and similarly for other values of S. — — — is the multiplying power of the shunt. The actual resistance through the galvanometer and shunt combined is found from the conductivity of the combination, which is equal to the sum of the separate conductivities. This conductivity is \ 1 8+ G ^''''^7i^7s^~G^' 330 ELECTRICITY The resistance of the combination is equal to the reciprocal of the conductivity ; that is, _ 1 ^ GS "' Kas S+G' The resistance of any number of multiple circuits is found in the same manner. CXL. CURRENT STRENGTH WITH THE ELECTRO- DYNAMOMETER Calibrate an electrodynamometer and measure with it the strength of an alternating current. 248. The Electrodynamometer. — An electrodynamometer is an instrument for measuring the strength of a current by means of the attractions and repulsions between a fixed and a movable conductor carrying this current. The conductors usually con- sist of flat rectangular coils of wire, the movable one being sus- pended with its plane normally at right angles to that of the fixed coil. The suspension is a silk thread and a spiral spring to give increased torsion. The support of this spring can be turned through a measurable angle to increase the torsidn at will. In use the instrument is to be set up with the plane of the fixed coil in the magnetic meridian, and with the movable coil swinging freely. The torsion head is adjusted so that the index of the movable coil is at 0, — that is, until the two coils are at right angles. The current to be measured is then sent through the coils, which will tend to rotate the movable coil. This tendency is counteracted by turning the torsion head of the spring to maintain the coil in its initial position. If 6 is the twist of the spring and K the constant of the instrument, the current strength is I=KVe. The instrumental constant may be determined by the copper voltameter in a manner similar to that described for the tangent galvanometer in Art. 242. THE ELECTEODYNAMOMETER 331 The electrodynamometer is particularly adapted to the meas- urement of alternating currents, since a current in either direction tends to turn the coil in one direction. Reference. — Carhart and Patterson, Electrical Measurements, pp. 127 and 167. CHAPTER XXII ELECTROMOTIVE FORCE CXLI. ELECTROMOTIVE FORCE BY COMPENSATION Compare the electromotive forces of several cells with that of a standard cell, using the compensation method. 249. Standard International Volt; Standard Cells. — The inter- national volt is that potential difference which will produce a current strength of one ampere (Art. 2i4) through a resistance of one ohm (Art. 212). It is impossible to produce directly an electromotive force of exaxjtly one volt ; it is therefore necessary to define it as a certain fraction of the electromotive force of a standard cell. A standard cell must be capable of reproduction, and must be constant. The Clark Standard Cell is the almost universal standard of electromotive force. It has mercury for its positive electrode, and amalgamated zinc for the negative; the electrolyte is a saturated solution of mercurous sulphate and zinc sulphate. Minute specifications and notes for the preparation of standard cells are given in the reference. The form of the Carhart- Clark portable cell is shown in Fig. 157. The materials are sealed in a small test tube, and the whole is mounted in a protecting case which often contains a thermometer. The electromotive force of the Clark cell at t° is E^ = 1.4292 - 0.00123 {t - 18) - 0.000007 {t - 18)2 yolts. At the usual laboratory temperatures this cell has the electro- motive force, in volts, as given in this table. I 15° 18° 20° 21° 22° 23° 24° 25° Ec 1.4328 1.4292 1.4267 1.4255 332 1.4242 1.4229 1.4216 1.4202 COMPENSATION METHOD 333 The Weston Standard Cell is similar to the Clark cell except that cadmium and cadmium sulphate are substituted for zinc and zinc sulphate. It has the advantages aver the Clark cell of a temperature coefficient which is practically zero, and in having an electromotive force which is nearly one volt. If it is made with a constant solution of cadmium sulphate which is saturated at 4°, its electromotive force at the usual laboratory temperatures is ^,,.= 1.0190 volts. That the electromotive force of a standard cell may remain constant the cell must be used with great care and only in open circuit or compensation methods. To pre- vent polarization and consequent deterioration, the current taken from such a cell should never exceed ^■jf-^-jj-g- of an ampere; that is, it should not be used directly in a circuit of less than 30000 ohms resistance. If the cell is of small size, a much higher safety resistance may be required. Reference. — Carhart and Patterson, Electrical Measurements, pp. 176-186, 330-.335. 250. Electromotive Force by Compensation. — One of the most useful methods for the comparison of electromotive forces, the compensation method, may be described as follows. Connect two similar resistance boxes, B and R' (Fig. 158), each of 10000 ohms or more, in series with a constant battery. The battery may consist of one or more cells, such that its electromotive force shall be somewhat in excess of that of any cell to be measured. The total resistance in use in the two boxes between A and B is always to be equal to the total resistance of one box. Fig. 157. Carhaet-Clakk Standard Cell 334 ELECTEICITY The battery B will maintain a constant potential difference, e, between these points, while the fall of potential between A and D will be proportional to that part of the total resistance which is in E. Connect one of the cells to be tested, a sensitive galvanometer, a safety high resistance (100000 ohms, for instance), and a key, in series, as a shunt to the resistance B, as indicated. The cell must be so placed that its electromotive force will oppose that of the battery B. Keepirig the sum of the resistances in use in R and B' always the same, so vary that K— .^^ part of the total resistance Gj Q I — >^ which is in B that upon momentarily closing the key the galvanometer shows no deflection. If the two resistance boxes are of the same pattern, the adjust- ment is facilitated by noting that when a plug is removed _ ,,Q „ ,, from any place in one box Fig. 158. Compensation Method •' ^ a plug is always put into the corresponding place in the other box. If the arrangement is not sufficiently sensitive, the resistance Q may be removed after compensation has been approximately secured, and the adjustment is then perfected. The resistance Q must be replaced before beginning measurements for a second cell. When the adjustment is completed, the electromotive force tested, Ey is compensated by the potential difference between A and D ; and if R^ is the resistance used in R, and B^i that in R\ E^:e = R^:R-^ + R^. Substitute for E^ a second cell of electromotive force E^, and adjust as before; if R^ is the resistance in R necessary for compensation, E^:e = R^:R^ + R^; and since R^ + R^ = R^ + R^, E-^: E^ = R^: B^. THE POTENTIOMETEE 335 251. The Potentiometer With an especially arranged resist- ance box, called a compensation apparatus or potentiometer, the method described above for comparing electromotive forces becomes very convenient, and is perhaps the most precise method known. The resistance box is constructed so that the resist- ance in one circuit remains constant while that in the branch circuit is varied through all possible values. One of the most convenient forms of compensation apparatus has its parts arranged as shown in Fig. 159, its total resistance being 14999.9 ohms. The following order of adjustment may be followed. The standard cell, a Clark element for instance, is connected at S; the unknown electromotive force, Fig. 159. The Potentiometer which may not exceed 1.5 volts, is connected at X; a galvanom- eter at G; and a battery in series with a resistance of 5000 ohms or more is connected as shown at B and P. This battery must have an electromotive force somewhat greater than 1.5 volts; it may be a single accumulator cell, or two gravity or Leclanche cells. The several switches are to be set to indicate the significant figures of the electromotive force of the standard cell. If the Clark cell is at the temperature 19°, for example, its electromotive force is 1.4279. Set the switch of the thou- sands row at 14, the hundreds switch at 2, the tens at 7, the units at 9, and the tenths switch at 0. Then the resistance of 336 ELECTRICITY that part of the main circuit to which the galvanometer is con- nected is 14279.0 ohms. Turn the switch B to 100000, which places a safety resistance of 100000 ohms in the circuit of the standard cell corresponding to Q of Fig. 158. Now adjust the resistance P so that upon closing the key K there will be no deflection of the galvanometer. Turn Z) to 10000 and improve the adjustment of P if required ; and finally turn B to 0, which cuts out the safety resistance, and perfect the adjustment of P till no deflection results from closing the key. This makes the instrument direct reading, in that the number of ohms required for compensation is exactly ten thousand times the electromotive force of the cell attached, the standard in this case. Turn the switch B back to 100000, and turn the switch C to X, which places the unknown cell in the compensation cir- cuit. By adjusting the resistance levers of the potentiometer, place them so that again there is no deflection when the key is closed; turn B to 10000, and improve the adjustment, and finally turn B to 0, and perfect it. The reading of the various dials of the potentiometer is then ten thousand times E, the electromotive force of the cell X being tested. The potentiometer may be used without the extra resistance P, but it is then not direct reading, and the proportion of the previous article is to be used in computing the unknown elec- tromotive force. In this case also the unknown electromotive force may have any value not exceeding that of the battery B. CXLII. ELECTROMOTIVE FORCE WITH A CONDENSER Compare the electromotive forces of several cells with that of a standard cell by means of a condenser. 252. Comparison of Electromotive Forces with the Condenser. — If a condenser (Art. 262) is charged from several different sources, the charges received will be proportional to the electro- motive forces of the sources. By measuring these charges the electromotive forces may be compared. This method has the THE BALLISTIC GALVANOMETER 337 advantage that the cells are used only on open circuit, thus avoiding polarization. Connect a ballistic galvanometer, G (Art. 253), a condenser, C, a charge and discharge key, K (Art. 263), and one of the cells to be tested, B, as indicated in Fig. 160. The key being in charge position, the condenser will receive a charge propor- tional to the electromotive force, E., i of the cell. By pressing the key ( ' J I ^ firmly, but for a very short time, c upon the galvanometer contact, the "^ X condenser vsrill discharge through ^-^ the galvanometer, and wrill deflect ^ (p ) ■ — ^ the needle through an angle, 9,, I, u-u i. • . 1 a ■ ^- \ } ^«^- ISO- Condenser Method such that sin iV^ is proportional to the charge. By substituting for the cell first used a second one of electromotive force E^, a deflection, 0^, will be obtained. If the distance of the scale from the mirror is D and the two observed scale readings are d^ and d^, E^:E^ = sin \ 6^ : sin \0^ = sin \ tan"' - : sin ^ tan"' ^ . If the angular deflections of the needle do not exceed 6°, the sines and tangents may be taken as proportional to the corre- sponding arcs, and then I^\'- E^ = d^: c?2- Any number of cells being thus compared, if one of them is a standard, the electromotive forces of the others may be determined. (Caution Do not allow the cells to be short circuited nor to be directly- connected to the galvanometer.) 253. The Ballistic Galvanometer A ballistic galvanometer is one designed to measure the total quantity of electricity pass- ing through it in a current of very short duration. The needle must have a period so long that the current will have ceased before it has moved appreciably from its position of rest. The needle should have the least possible damping. The quantity of 338 ELECTRICITY 3 electricity thus passing through the galvanometer is proportional to the sine of half the angle of the first swing of the needle. The deflections of the needle are usually measured by observ- ing with a telescope a centimeter scale as seen reflected in a mirror attached to the needle. The following adjustments are essential. If the galvanometer is of the suspended magnet type (Art. 209), the plane of the coils must be in the plane of the magnetic meridian ; and the suspension must be so adjusted that when the needle is at rest the torsion is zero, and so that the needle is magnet- ically symmetrical with respect to the plane of the magnetic meridian. If the galvanometer is of the suspended coil (D'Arsonval) type, the effect of the earth's field may be neglected ; and it is sufficient that the torsion of the sus- pensions is zero when the needle is at . rest, and that the plane of the coil is parallel to the force of the stationary field magnets. The direction of the mirror will usually indicate whether these conditions are approximately ful- filled, while a sufficient test of the accuracy of the adjustment is that equal charges sent through the galva- nometer in opposite directions produce equal and opposite deflections. Fig. 161 represents a high sensibility D'Arsonval galvanometer, which is exceedingly convenient for ballistic observations. In addition to these adjustments of the galvanometer it is necessary that the telescope and scale be so placed that the mirror when at rest reflects to the cross wires of the telescope that point of the scale which is in the same vertical plane as the axis of the telescope. When these adjustments are made the observed displacements of the scale, when the needle is deflected, are proportional to the D'Aksonvai, Galva- NOMETEK THE QUADRANT ELECTROMETER 339 tangents of twice the angles of deflection. Tables are often pro- vided, giving corrections, which, when added to the scale read- ings, make these readings directly proportional to the arcs, or to some function of the arcs, whose tangents they measure. After a ballistic galvanometer has been deflected, some special manipulation is required to bring the needle quickly to rest. If it is of the suspended coil type, a short circuiting of the galva- nometer is the most efficient method. The current induced by the motion of the needle in the field of the magnet reacts upon the needle, damping its vibrations. If the galvanometer is of the suspended magnet type, the motions of the needle may be checked by the manipulation of a permanent magnet held in the hand ; or by temporarily connecting to the galvanometer a small coil of wire which is arranged to slide over the end of a fixed bar magnet. By moving this coil on the magnet an induced current is produced whose direction and strength are easily con- trolled, and which can be made to bring the needle to rest. When this is accomplished the circuit of the auxiliary coil is broken. If the needle cannot be brought entirely to rest, the condenser may be discharged precisely when the needle is at a turning point in its vibrations, and the deflection is to be calculated from this turning point and not from the point of equilibrium. For further consideration of the ballistic galvanometer, see Arts. 267 and 268. CXLIII. ELECTROMOTIVE FORCE WITH THE QUADRANT ELECTROMETER Compare the electromotive forces of various cells. 254. The Quadrant Electrometer. — The quadrant electrom- eter has four metallic quadrants, which together form a short cylindrical box, the quadrants being supported within a metal case by insulating posts and separated from one another by small spaces ; the alternate quadrants are connected by wires, and each pair is connected to an insulated binding post outside the case ; within the quadrants a flat aluminum needle is 340 ELECTRICITY A lu suspended either by a bifilar silk suspension or by an insulated metallic wire suspension. In Fig. 162 the electrometer is shown with the case open. The quadrants are at Q, one of them being removed to show the needle N. In the bottom of the case is a glass dish containing pure concen- trated sulphuric acid. The needle connects with the acid either by a platinum wire or by a piece of mica. The acid may serve three purposes : it keeps the interior of the electrom- eter dry, and it checks the vibra- tion of the needle ; it may also serve as the inner coating of a Leyden jar, whose outer coating is the metal case, giving to the needle an increased capacity. This last use of the acid is not necessary, and if the connection between needle and acid is mica, the con- denser effect is not employed. By means of sliding rings on the quadrant binding posts, connect the quadrants to the metal case, and connect the case to the ground. The needle being discharged, so adjust its support that it hangs symmetrically over one of the diam- etral spaces separating the quad- rants. The position of the mirror will indicate this adjustment with sufficient accuracy. Give the needle a static charge from any convenient source, as an electrophorus, through the acid or through the metallic sus- pension, according to the construction of the instrument. If the needle is permanently deflected by this charge, it must be brought back to its zero position by adjusting one of the quadrants provided with a movement for this purpose, or by Fig. 162. Quadrant Electbombtee THE QUADRANT ELECTROMETER 341 means of the leveling screws, or by a slight adjustment of the torsion head. Now insulate the quadrants and connect one pole of the cell to be tested to one quadrant binding post, and the other pole to the second post. The potential difference given to adjacent quadrants will turn the needle until the electrostatic actions are balanced by the couple generated in the twisted suspension. The angle of deflection is proportional to the potential differ- ence. It is desirable to deflect the needle first in one direction and then in the other by reversing the cell connections ; this is conveniently accomplished by means of a special reversing key devised by Lord Kelvin. The mean of the two deflections is free from errors of torsion. If the average scale deflection produced by an electromotive force, ^j, is d-^, and d^ is that due to an electromotive force, E^, the scale being distant from the mirror D, then ^i:i-„ = tan-i^:tan-'^. To determine the potential of an insulated conductor, connect one pair of quadrants to the ground, and the second pair to the conductor in question. The electrometer may also be used by connecting the quad- rants to the poles of a large series battery, the middle of the series being connected to the ground. This maintains the adjacent quadrants at equal opposite potentials. The conduc- tor whose potential is to be determined, as referred to the zero potential of the earth, is connected to the needle. 255. Electrometer for measuring Large Potential Differences. — If the electrometer is too sensitive when arranged as above explained, it may be made less sensitive by connecting the needle and one pair of quadrants to one pole, and the other pair of quadrants to the second pole. In this case the deflection of the needle is proportional to the square of the potential difference. Arranged in this manner the quadrant electrometer is appli- cable to the measurement of alternating potentials. Refebence. — Stewart and Gee, Practical Physics, Vol. II, pp. 431-438. 342 ELECTKICITY CXLIV. ELECTROMOTIVE FORCE WITH THE CAPILLARY ELECTROMETER Determine the variation of contact difference of potential between copper and copper sulphate solution, as the concentration of the solution varies. 256. The Capillary Electrometer. — Lippmann has devised a simple electrometer based upon the fact that the surface tension of mercury in contact with an electrolyte varies with the differ- ence of potential at the surface of contact. When a current passes from the acid to the mercury the area of the surface of i separation tends to decrease, owing to an increase of surface tension. A large mer- cury surface and a small capillary surface are connected by dilute sulphuric acid (one part of acid to five of water) in a suitably shaped glass vessel (Fig. 163). At C is a capillary surface in a tube of about 0.5 mm bore, and at S is the large surface. Plati- num wires connect with the two portions of mercury. When a difference of potential is applied to the two wires the capillary meniscus changes its position by amounts approxi- mately proportional to this difference when it does not exceed a tenth of a volt. A small microscope with an eyepiece micrometer is convenient for observing the menis- cus. The deflection may be from five to ten scale divisions for 0.001 volt. A more sensitive form of electrometer, giving certain indica- tions to 0.0001 volt, employs a much finer capillary, and has its parts arranged as shown in Fig. 164. The upper mercury tube is 50 cm or more long ; connected to it by a flexible tube is a reservoir, permitting the height of the mercury to be varied. The capillary dips into dilute sulphuric acid which rests on mercury in the lowest vessel. A microscope is provided to Fig. 163. Capillaky Electrometer observe the capillary surface of separation. THE CAPILLARY ELECTEOMETER 343 The sensitiveness of the electrometer depends upon the fine- ness of the capillary ; if the point is conical, the mercury may be made to assume a desired position by varying the height of the upper column. The displacement of the meniscus meas- ured with the micrometer eyepiece may serve to determine the potential difference ; or when the surface has been displaced it may be restored to its former position by changing the pressure above, the potential difference being considered proportional to the change in pressure. The electrometer is standardized by comparison with a standard cell ; but as the relation between pressure and potential changes and has therefore to be ire- quently redetermined, the instrument is satisfactory only for measuring very small differences of potentials and for indicating the absence of potential difference in compensation methods (Art. 250). The mercury in the capillary should always be connected to the negative (zinc) pole, otherwise the mercury becomes corroded. If the difference of potential exceeds one volt, hydro- gen is evolved, which interferes with proper action. If either of these effects has been produced, the capil- lary meniscus is cleaned by forcing a drop of mercury entirely through the capillary. Occasionally the mercury should be drawn up out of the capillary, allowing the acid to wet the small tube, as this is a condition of sensitiveness. The electrometer remains in condition for use only when it is kept on closed circuit. Hence a three-point key (Fig. 170) is desirable, arranged to short circuit the electrometer when the lever is in its normal position, the short circuit being broken Fig. 164. Capillary Electrometer 344 ELECTRICITY i :K] and the external electromotive force being applied when the key is pressed. Instructions for making three forms of capillary electrometers are given in the reference. Eefekence. — Ostwald, Physico-Chemical Measurements, pp. 202-208. 257. Contact Difference of Potential. — Any two dissiniilar substances in contact are at different potentials. In the cases of two solids or two metals this difference is usually very small, while for a metal and an electrolyte it may be about a volt. The difference depends, for a given metal and electro- lyte, upon the concentration of the ions • of this metal in the electrolyte. The variation with concentration may be observed in a concentration cell, as suggested by Ostwald, arranged as shown in Fig. 165. Two short glass tubes each have one end conically reduced; in the small end is placed a plug of macerated filter paper. These tubes are filled with the electrolytes, either of diiferent salts or of different concentrations of the same salt. The electrodes are supported by corks, and the bottoms of the tubes are placed in a suitable dish which contains a conducting liquid, — mercury, for instance. The compensation method is the best for making the meas- urements. The connections are to be made as shown in Fig. 166. B and H' are two resistance boxes which for ordinary measure- ments may be of 1000 ohms, or for more refined work may be of 10000 ohms each, as described in Art. 250. B is a, cell which furnishes a constant difference of potential greater than that of the cell being investigated. It may be a small second- ary cell or a gravity cell. C is the concentration cell to be measured, JE is the capillary electrometer, and K is a three- point short-circuiting key. The resistances in H and It' are to be varied, their sum always being 1000 (or 10000) ohms, tiH Fig. 165. Contact Cell ELECTEOMOTIVE FORCE WITH AMMETEE 345 compensation is secured. The value of the difference of potential at C is determined by substituting for C a standard cell (Art. 249) . The difference of potential measured is the difference of the two contact differences of potential of the two electrodes of C, since these are oppositely- directed. For the laboratory exercise iirst fill the two tubes with equal solutions of 1 : 200 gram-molecular solution of anhydrous copper sulphate. The proportions for this are copper sulphate crystals (CuSO^ + S HgO), 250 g, and water (3600 - 90), 3510 g. One tube still containing the first solution, the second is to be filled with a 1 : 150 solution (250 g of crystals to 2610 g of water) ; and again with a 1 : 100 solution (250 g of crystals to 1710 g of water) ; the change of potential being measured in each case. Reference. — Ostwald, Physico-Cliemical Measurements, pp. 209-216. CXIV. ELECTROMOTIVE FORCE WITH AW AMMETER Fig. 166. Compensation Method WITH Electrometer Determine the electromotive forces and resistances of several cells, using a milliarameter or tangent galvanometer. 258. Electromotive Force and Resistance of Cells with a Milliam- meter and a Resistance. — The following methods for investi- gating constant cells are based upon Ohm's Law, and they require very simple apparatus. A sensitive ammeter, a tan- gent galvanometer, or pther galvanometer whose law is known, and a resistance box, are all that is needed. For three of the methods it is necessary to know the resistance of the galvanom- eter, and for one its constant is required. The formulae will be given for the ammeter, but if another instrument is used, it is only necessary, except in the first formula, to substitute for 346 ELECTEICITY the current value /, the function which is proportional to the current, as tan 6 for a tangent galvanometer, etc. In the same manner as is developed in Art. 217, if /j and I^ are the current strengths flowing through resistances i?^ and B^ in series with the ammeter, produced by a cell whose electro- motive force is required, the value of the electromotive force, independent of the resistances of the battery and ammeter, is and if G is the resistance of the ammeter, the battery resistance is B = ^'^^ " ^'-^^ - G. Electromotive forces may be compared, using a miUiammeter and a resistance box, in four ways, as follows. Let G be the ammeter resistance, and B the resistance of the cell which produces a current Jj, through a resistance B^ in series with the ammeter; and let B^, /g, and ^j ^^ ^^^ corresponding quantities for a second cell. Representing the electromotive forces of the cells by E^ and E^ respectively, ^1 : ^2 = (5i + (? + i?i) Jj : (^2 + (? + B^ I^. If B-^ + JSj be made equal to B^ + iJg, then If B^ and B^ be so adjusted that ij equals Jj, then E.^: E^= G + B-^ + B.^: G + B^ + B^. Connect the two cells to be compared in series and let 7j be the current flowing through any convenient resistance; inter- change the poles of one cell so that the electromotive forces are opposed, and let /j be the current .flowing, the resistance remaining Unchanged ; then J^i- ^i = k'^ k'- k~ k- THERMO-ELECTROMOTIVE FORCE 347 CXLVI. THERMO-ELECTROMOTIVE FORCE BY DIRECT MEASURE (a) Determine the thermo-electiomotive force of lead-copper, lead-iron, and copper-iron thermo-elements at various temperatures between 0° and 100°. Plot the results. Make a thermo-electric diagram for copper and iron, and find their neutral temperature. (b) Calibrate a thermo-electric pyrometer. 259. Thermo-Electromotive Force. — If one junction of a thermo-couple is at a constant temperature, 0°, while the other junction is raised to different temperatures, since the contact difference of potential in general varies with the temperature, there will result an electric current the electromotive force of which is to be measured. To the ends of a wire of one of the metals to be studied, solder wires of the second material. Place the two junctions in narrow test tubes in which are thermometers, and place the tubes, one in an ice bath and the other in a water or oil bath. Gu -^l Hi 1 9 >f Fig. 167. Thekmo-Electeomotive roRCE For better heat conduction the tubes may be partially filled with petroleum. Connect the two ends of the thermo-couples, through a resistance, to a galvanometer, as indicated.in Fig. 167. By varying the temperature of one junction as much as is convenient, the varying electromotive force is measured with the galvanometer. This electromotive force may be taken as 348 ELECTRICITY proportional to- the deflection. The resistance is included in the circuit, to regulate the current so that the deflection may be readable. It is preferable that this should not be altered during the measures, in which case, if the total resistance in the circuit, including the galvanometer resistance, is over fifty ohms, the value of the resistance need not be considered. If the circuit resistance is low, the variation of resistance of the thermo-couple with temperature must be taken into account. In the several experiments the direction of the electromotive forces must be noted. Instead of measuring the deflection only, it is better to meas- ure the actual electromotive force by the compensation method of Art. 250. Or if the galvanometer constant is known (Art. 246) the electromotive force may be computed from the resistance of the circuit, and the deflection. 260. Thermo-Electric Power and Thermo-Electric Diagram. — The ratio of the electromotive force of a thermo-element to the difference in temperature of the junctions is the thermo-electric power of the couple at the mean temperature. A thermo-electric diagram is one showing these relations. Such diagrams are usually constructed with reference to lead as the standard, since hot lead and cold lead in contact show no thermo-electromotive force, while with other metals there is a difference of potential between the metal hot and the same metal cold. The neutral point for two metals may be found from the diagram; it is the temperature corresponding to the point of intersection of their thermo-electric power lines. CXLVII. ERRORS OF A VOLTMETER BY COMPENSATION Calibrate a voltmeter at ten or more equidistant points of its scale. 261. Calibration of Voltmeter. — The compensation method of Art. 250 may be adapted to the calibration of a voltmeter, as follows. A storage or other battery of such size as to give the various voltages corresponding to the points at which it is desired to calibrate the voltmeter must be provided. Pass the CALIBRATION OP VOLTMETER 349 current from this battery through a standard resistance, R-^, of large value, 100000 ohms for example, and through a standard of variable resistance, B^, connected in series. Connect the voltmeter V (Fig. 168), to indicate the total difference of poten- tial; and to the terminals ^ R, I ^^^ iB \-J^\-\i-\[-\\- of ^2 connect one or more standard cells, S, a gal- vanometer, G, and a key, X, in series, so that the electromotive force of the cells shall oppose that of the battery 5. It will now be possible so to adjust the resistance ^2 that the difference of potential be- tween its terminals shall be exactly equal to that of the standard cells. That this condition has been secured will be indicated by there being no deflection of the galvanometer when the key K is closed. Since the fall of potential is proportional to the resistance, the total potential, a, measured by the voltmeter, is to that of the n standard cells, ne, as Bj^ + B^is to B^ ; Fig. 168. Voltmeter Calibration E=ne —^ B-i -f- -B, i?2 The difference between this computed value of -E" and the voltmeter reading is the correction to the scale at this point. Alter the battery potential and repeat the process for each point to be calibrated. CHAPTER XXIII CAPACITY CXLVm. RELATIVE CAPACITY WITH A BALLISTIC GALVANOMETER Compare the capacities of the various parts of a divided condenser. Deter- mine the capacity of a condenser by comparison with a standard condenser. 262. Standard International Coulomb and Farad; Standard Condensers. — The coulomb is that quantity of electricity which is transferred by one ampere (Art. 244) in one second. The farad is the capacity of a conductor such that its potential is increased by one volt (Art. 249) when it receives a charge of one coulomb. The farad is too large a capacity for laboratory uses, and the one millionth part of the farad, called the micro- farad, is the working unit. Standard condensers are usually constructed of tin-foil sheets with mica insulation, and have capacities of ^ or 1 microfarad. They are sometimes subdivided into five parts of 0.5, 0.2, 0.2, Fig. 169. Plan of Divided Condenser 0.05, and 0.05 microfarads, which by means of the blocks and plugs shown in Fig. 169, can be connected to give a great variety of capacities. The first section of the condenser has one terminal 350 CONDENSER KEYS 351 connected to the first block and the other to the second block ; the second section of the condenser is connected between the second and third blocks, etc. The charging current is to be connected to the posts Pj and P^, which connect respectively to the bars B^ and B^. If any two consecutive blocks are con- nected to opposite bai's, it makes no difference which, that portion of the condenser between the blocks will receive a charge. In Fig. 169 the portion of the condenser connected is 0.45. The method of connection described is that in which the several parts are in parallel. They might be connected in series, in which case the capacity of the series is the reciprocal of the sum of the reciprocals of the several parts. Care must be taken not to insert plugs at the two ends of one block, for this would short circuit the charging battery. 263. Condenser Keys. — For facilitating the charg- ing and discharging of condensers, keys are made in many forms, the essential features of which may be explained with the aid of Fig. 170. One terminal of the galvanometer is to be connected to G, one pole of the battery to B, and one side of the condenser to C, the other connections being as shown in Fig. 171. A spiral spring draws the lever L downward in the position shown. By pressing the knob K, the front of the lever is brought downward till it catches under the two triggers, T-^ and T^. This brings the end of L into contact with B, which is the charge position. By pressing Tj the spring will pull the lever downward, but the trigger T^ will catch it and hold it horizon- tal so that L does not touch either B or G; this is the insulate position. By pressing T^ the lever takes the position shown, which is the discharge position. Fig. 170. Condenser Key 352 ELECTRICITY In another form of condenser key, a flexible lever is normally in'contact with the upper point (the charge position), while it- may be pressed away from this point into contact with the lower one (the discharge position). 264. Comparison of Condenser Capacities If different con- densers, or different parts of one condenser, are charged to the same potential, the quantities of electricity in the charges will be proportional to the capacities of the condensers. These quantities may be compared by discharging the condensers through a ballistic galvanometer (Art. 253). Connect a ballistic galvanometer, G, a condenser, C, a charge and discharge key, K, and a cell, B, as indicated in Fig. 171. I After charging the condenser, by Jl ^ changing the key to the galvanom- L 6ter contact, the condenser will be K^ discharged and the galvanometer needle will be deflected through an pj angle, 6^, such that sin i ^j is pro- portional to the charge and therefore Fig. 171. Compakison of _ j.- i j. ^i, -j. /-» tj proportional to the capacity C-. . By Capacities . , , » using a second condenser of capacity Cg, a deflection 6^ will be obtained. If the distance of the scale from the mirror is D, and the observed scale readings are c?j and d^, Ci'. C^ = sin ^ ^1 : sin ^ ^2 = ^^^ i tan~' -J : sin ^ tan~^ -^ . If the angular deflections of the needle do not exceed 6°, the sines and tangents may be considered proportional to the corresponding arcs; and then (Caution Do not allow the cell to be short-circuited, nor to be directly connected to the galvanometer.) The following numerical example illustrates the comparison of capacities. A part of these observations are used in the determination of the absolute capacity of one of the condensers, explained on page 358. COMPARISON OF CAPACITIES 353 Comparison of Capacities Octoher 18, 1897 S. & H. Standard Condenser No. 6829; nominal capacity, 1.003 micro- farad. Q Paper Condenser; nominal capacity, \ microfarad. Queen Bal- listic Galvanometer No. 92. The two condensers were charged successively from H. & B. Clark Cell No. 100, and the following deflections were obtained, as read in centi- meters on a scale distant 100 cm. CONDEXSEK No. S829 COKDENSEK 3 Zero Beading Second Reading Deflection Zero Reading Second Beading Deflection 39.55 cm 76.10 cm 36.55 cm 39.8 cm 48.9 cm 9.1cm .65 .25 .60 .7 8 ■ .70 .20 .50 .7 9 .75 .25 .40 .7 8 .80 .20 .50 .7 8 .80 .30 .50 .8 9 .85 .40 .55 .7 8 .85 .40 .55 .7 9 .85 .40 .55 .7 8 .8-3 .30 .47 .7 8 Mean dx = 36.52 cm Mean < is = 9.12 cm . 36..52 .9.12 (No. 6829) : (Q) = sin J tan-i '-j^ : sin J tan-i y^ = 1 : 0.260. Capacity of Condenser No. 6829 = 0.999 microfarad (p. 358). Capacity of Condenser Q = 0.259 microfarad. CXLK. RELATIVE CAPACITY BY BRIDGE METHODS Determine the capacities of the parts of a subdivided condenser by com- parison with a standard condenser. 265. Bridge Methods for Comparison of Capacities. — The fol- lowing zero methods for condenser comparisons are similar to the Wheatstone's bridge method for resistance comparisons. 354 ELECTRICITY De Sauty's Method. — Connect the two condensers, two resist- ances, a dead-beat galvanometer, a battery of from 10 to 15 volts, and a charge and discharge key, as shown in Fig. 172, the key being usually on the discharge point. Adjust the resist- ances until the galvanometer shows no deflec- tion when the condensers are charged and dis- charged. When this condition is fulfilled The resistances, B^ and JEj, should have values of from 1000 to 10000 ohms, and must be noninductive. Groifs Method. — Connect two condensers, two resistances, a dead-beat galvanometer, a battery of from 10 to 15 volts, and keys, as indicated in Fig. 173. As compared with the arrangement of the previous method, the battery and galva- nometer have changed places. It will now be possible so to adjust the resistances, E-^ and B^, that upon first closing the key K-^, which remains closed, and then closing the key K^, no deflection of the galvanometer is produced. When this condition is ful- filled, the following relation is true. After both keys have been closed as described, and the resistances have been altered, the condensers must be discharged by closing K^ only, before again charging through Ky As before, the resistances should be large, between 1000 and 10000 ohms. Fig. 172. De Satjty's Method Fig. 173. Gott's Method Reference. Vol. I, p. 440. - Gray, Absolute Measurements In Electricity and Magnetism, COMPAEISON OF CAPACITIES 355 CL. RELATIVE CAPACITY BY THE METHOD OF MIXTURES Determine the capacity of a condenser by comparison with a standard condenser. 266. Comparison of Capacities by the Method of Mixtures. — In this method two condensers are charged with opposite poten- tials of such values that their charges when mixed neutralize each other. Their capacities are inversely as these potentials. Connect apparatus as indicated in Fig. 174. A battery of from 10 to 15 volts is joined in series with two large resistances, B^ and B^; the condensers, Cj and Cg, are arranged to be connected to ^j and E^ re- spectively, by means of a special double key, K. A rocking commu- tator (Fig. 133) with the diagonal connections removed is suitable for this purpose. With the key in proper position the condensers will be charged to potentials which are proportional to ^j^ and B^. When the key is rocked to its second posi- tion the connections as shown are such that the two charges will be mixed, and the residual charge is only their difference. By closing the key k, this residual will be discharged through the galva- nometer G. The resistances are to be so adjusted that the galvanometer shows no deflection, when the condensers are charged and discharged as described; then ^1 ■ ^2 ^^ 1 ■ 2' The method is suitable for cable capacity measures, the con- ductor of the cable being joined to K, and the sheath of the cable or the water in which it is immersed being connected to Earth | Fig. 174. Capacity by Method OP MlXTUKES 356 ELECTEICITY the earth. The ground connection is necessary for cable testing, but may be omitted in other cases. Absorption by the condensers may cause an error, and often the time required for mixing the charges is appreciable ; hence high insulation is essential. CLI. ABSOLUTE CAPACITY OF A CONDENSER WITH A BALLISTIC GALVANOMETER Determine the absolute capacity of a condenser. 267. Absolute Capacity with a Ballistic Galvanometer When a ballistic galvanometer (Art. 253) is used for absolute measure- ment, it becomes necessary to consider the period of vibration of the needle as well as the deflection, and to make corrections for the effect of the amplitude upon the period and for the effect of damping on the deflection (Art. 93). The Period of the needle may be found from observations of transits, as explained in Art. 83, a set of ten transits being observed, and, after a lapse of fifty or more vibrations, a second set of ten. This observed period, T, is reduced to the period in an infi- nitely small arc, T^, by the approximate formula, « 256 Z)2' in which d is the observed scale reading (average) and D is the distance of the scale from the mirror. Complete formulae and tables to facilitate making this correction will be found in the references. The Logarithmic Decrement is the natural logarithm of the ratio of decrease in the arcs of successive vibrations of the needle. Let a^ be the arc of any swing of the needle, expressed in scale divisions, and let a^^^ be the arc of the wth following swing ; then the logarithmic decrement is , 2.3026 ,, . \ = -— — (log ai - log a^^ J. ABSOLUTE CAPACITY 357 Correction of the Tangent to the Arc. — If dis the observed number of scale divisions from the center of the scale to the turning point of the swing, expressed in centimeters, and the scale distance is D, the number which is proportional to the arc of swing is ^3 A = d 3i>2- The Absolute Capacity of a Condenser may be found, after the corrected period of the needle, Tq, and the logarithmic dec- rement, \ of the galvanometer have been determined from the results of the following deflection experiments. Charge the condenser with a given cell and discharge it through the galvanometer, as described in Art. 264. If c?j is the observed scale reading when the distance of the scale from the mirror is D, the corrected deflection is A, =2sini tan-'^. Then connect the same cell in series with the galvanometer and a very high resistance, R, and let d^ be the deflection pro- duced. Usually it will be necessary to shunt the galvanometer in order to secure a readable deflection. This deflection properly corrected will be t, A, = tan 1- tan""'-^. If the galvanometer resistance is G, the battery resistance B, and if the galvanometer is shunted with a resistance S, then the virtual value of the resistance through which the cell acted in producing the observed deflection d^ is Finally the absolute capacity of the condenser C is given by the following formula. j, /i + i x\ a References. — Stewart and Gee, Practical Physics, Vol. II, pp. 364-369, 407; KoMrausck, Physical Measurements, pp. 219-225, 347, 382; CarJiart and Patterson, pp. 207-213, 227. 358 ELECTRICITY A numerical example of the determination of absolute capacity- is given. Absolute Capacity op Siemens & Halsee Condenser No. 6829 nominal capacity, 1.003 miohofabad Queen D'Arsontal Ballistic Galvanometek No. 92 October 21, 1897 Two determinations of the period of the needle were made, the reduced average of which gives Tj, = 16.589 s. Obsekvations and Computation for the Logarithmic Decrement Scale distance, 100 cm. Center of scale, 40.00 TuBNiNG Point P d=p -40.00 3Z>2 Corrected Turning Point Arc 64.69 16.52 59.13 21.43 55.09 25.07 + 24.69 - 23.48 + 19.13 - 18.57 + 14.93 - 12.03 + 0.50 -0.43 + 0.23 -0.21 + 0.12 -0.11 64.19 16.95 58.90 21.64 54.97 25.18 47.24 = ax 41.95 = 02 37.26 = OS 33.33 = 04 29.79 = 05 J (log a, - log o ) = 0.05049 | ^^^^ ^ ^^^^^^ T (log «6 - log S) = 0.04955 J X = 2.3026 X 0.05002 = 0.11518. The observations for the deflection produced by the discharge of the condenser are given in the example on page 353. di = 36.52. Ai = 0.17485. The observations for the steady deflection are given in the example on page 328. d^ = 17.22. \ = 0.08257. iJ^= 11465000. The absolute capacity of the condenser is 16.598 X 1.05759 x 0.17485 C = •r- X 11 465000 X 0.08257 0.9991 microfarad. BALLISTIC CONSTANT 359 268. Ballistic Constant. — In the above method the electro- motive force of the cell is eliminated by using the same cell in both the condenser and deflection observations. If a standard cell of known electromotive force is used in the deflection experi- ment, the ballistic constant of the galvanometer may be deter- mined and then the instrument may be used to measure capacities or other quantities in absolute measure without the repetition of this part of the above method. This constant is the factor by which an observed ballistic deflection must be multiplied to give the absolute measure of the quantity of electricity that passed through the galvanometer. If E is the electromotive force of the cell, and T^, R^, and Aj have the values given in the preced- ing article, the ballistic constant of the galvanometer is 7rli^\ The absolute capacity C, of a condenser charged to a potential difference e, X and Aj having the values assigned in the preced- ing article, is C=K a + ix)A^ CHAPTER XXIV INDUCTION CLII. INDUCTANCE BY COMPARISON Determine the self-induction of several coils by comparison with a standard of self-induction. 269. Standard Henry ; Coefficient of Self-induction The unit of induction is the henry ; it is the induction due to a cur- rent whose strength is changing at the rate of one ampere per , second with a resulting induced electromotive force of one yolt. The coefficient of self-induction of a coil is the total induction through it per unit change of current producing the induction. The self-induction of two coils may be compared with a Wheatstone's bridge by Maxwell's method; if the self- induction of one coil is known, that of the other is determined. Let jBj and B^ (Fig. 175)be the resistances of two arms of a Wheatstone's bridge containing the coils whose coefficients of self-induction, L-^ and X^, are to be compared ; let ^3 and B^ be noninductive resistances. Connect these with a galvanometer, a battery, and a key, as indicated. If a steady current is flowing, then, as in Art. 207, no current will flow across the bridge from D to E when R^ and ^^ are so adjusted that Fig. 175. Self- Induotion B-^-.B^ — Bg B,. Also it can be proved that if the current varies so that the 360 MUTUAL INDUCTION 361 self-induction of the coils enters into the current relations, there- wiU be no current through the galvanometer when As it is not convenient to determine this latter condition alone, both conditions must be satisfied at the same time. The adjusir ments must be so made that no current flows through the galva- nometer while the circuit is closed, and also there must be no current when the battery circuit is made or broken. This means that the resistances in the arms of the bridge apparatus which contain the self-inductances must be made to have the same ratio as the self-induction coefficients. If a standard of self- induction is used for one coil, it is usually constructed so that its self-induction may be varied. This alone may permit the obtaining of a balance ; if not, noninductive resistance must be inserted in series with one of the inductive coils so as to change the value of ^j, for instance, without changing Ly By one or both of these operations it will be possible to secure the condi- tions for no deflection. Then References. — Carhart and Patterson, Electrical Measurements, p. 255 ; Stewart and Gee, Practical Physics, Vol. II, p. 394. CLm. COEFFICIENT OF MUTUAL INDUCTION BY COMPARISON "Verify the laws of mutual induction, and compare two mutual inductances. 270. Mutual Induction. — That the induced current in the secondary coil varies directly as the current in the primary coil and inversely as the resistance in the secondary circuit, and Fig. 176. Mutual Induction 362 ELECTRICITY the dependence of the induction upon the relation of the pri- mary and secondary, may be proved by comparing the currents produced under various conditions, by means of a ballistic gal- vanometer. If the constants of the current are known, the coeificient of mutual induction may be calculated. If the making of a current, /, in the primary (Fig. 176) induces a quantity of electricity Q in the secondary, and the entire resist- ance of the secondary circuit is B, the coefficient of mutual induction, M, is obtained from the following relation. Refebence. — Nichols, A Laboratory Manual of Physics, Vol. I, p. 240. 271. Comparison of Two Mutual Inductances. — Let it be required to compare the mutual induction of two coils, Cj and C„, with that of coils Cg and C4. Connect the two primary coils, one from each pair, Cj and C3. (Fig. 177), in series with a battery, the circuit containing a key, K. Connect the second- ary coil, C^, in series with a resistance, -Bj' ^^^ ^ sensitive galvanometer ; connect the coil C^, and a resistance, B^, to the same galvanometer so that the induced current in C^ shall oppose that in C^. By adjusting B^ and B^ so that the making and breaking of the primary circuit causes no deflection of the gal- vanometer, the coefficients of mutual induction, lfi_2 and M^_^, are in the same ratio as the resistances B^ and B^ ; that is, Fig. 177. Comparison of McTnAL Inductances 7lf,_2 : M^. .4 = -^2 ' B, Reference. — Carhart and Patterson, Electrical Measurements, p. 265. CHAPTER XXV MAGNETIC QUANTITIES CLIV. EARTH'S HORIZONTAL MAGNETIC INTENSITY WITH THE MAGNETOMETER Determine the horizontal intensity of the earth's magnetism, and the magnetic moment of a magnet. 272. The Earth's Magnetic Elements. — The vertical plane which contains the direction of the earth's magnetic force is the magnetic meridian; the angle between this plane and that of the geographic meridian is the magnetic declination. The direction of the force is inclined to the horizontal in the mag- netic meridian at an angle called the magnetic inclination or dip. The total intensity of the earth's magnetism is the number of dynes of force with which a unit magnet pole would be urged along in the direction of the force. The unit of inten- sity is called the gauss; the actual intensity varies from 0.28 to 0.78 of a gauss. This total intensity may be considered as consisting of two components, — the vertical intensity, V, and the horizontal intensity, H. The intensity and direction of this force are subject to changes which may be analyzed into daily, annual, secular, and irregular variations. It is important to know the values of the' horizontal intensity and its variations ; if the total intensity and its direction are required, they are most readily determined from the values of the horizontal and vertical components, or from the horizontal intensity and dip. 273. The Magnetometer. — If a magnet is suspended with its axis horizontal, it will come to rest in the magnetic meridian. After displacement from the meridian it will vibrate in the manner of a torsion pendulum, with a period which varies 363 364 ELECTEICITY inversely as the square root of the restoring force. This force is the product of the horizontal intensity of the earth's mag- netism and the magnetic moment of the magnet. A determi- nation of the period furnishes one equation of condition for determining these two unknown quantities. If the same magnet is placed at known distances from a com- pass needle, in a line through the center of the needle perpen- dicular to the plane of the magnetic meridian, the needle will be deflected to a position such that the tendency of the earth's field to restore the needle to the meridian is counterbalanced by the moment due to the magnet tending to set the needle east and west. The observed deflection furnishes a second relation between the horizontal intensity and the magnetic moment, permitting their values to be found. The instrument for making these measurements, the magnet- ometer, may be simple or elaborate, and while the formulae con- cerning the general principles are simple, as given here, many corrections may be made which greatly complicate both the observations and their reduction. Even in simple measurements care is required to avoid the effects of local magnetic disturbances and variations in the strength of the earth's field. Vibration Observations. — Suspend the magnet with its axis horizontal, by a fiber having as little torsion as possible. The torsion may be reduced to a minimum by first suspending in place of thie magnet a bar of nonmagnetic material having the same mass as the magnet, and adjusting the torsion head so that the bar would come to rest with its axis in the magnetic meridian. Displace the magnet from its position of equilib- rium so that it shall vibrate with an amplitude not exceeding 5°, and carefully determine the period, T, of a complete vibra- tion by the method of Art. 83. Then, if. 7 is the moment of inertia of the magnet, M its magnetic moment, and H the hori- zontal intensity of the earth's magnetism, The moment of inertia, I, may be found by observing the period of the needle when free and when a load of known THE MAGNETOMETER 365 moment of inertia is added to it, as explained in Art. 84 ; or it may be calculated from the mass and dimensions of the magnet, by the formula of Art. 85. The value of MH thus determined may be corrected for amplitude of swing, torsion of suspension, rate of clock, and for the effects of temperature and induction upon the magnet, as explained in the references. Deflection Observations. — Place the magnet used in the pre- vious experiment with its axis perpendicular to the plane of the magnetic meridian and passing through the center of a needle capable of horizontal deflections which can be measured. The latter may be a form of compass, or a needle carrying a mirror for telescope and scale observations. With the magnet at a known distance from the center of the needle, observe the deflection produced, reading both ends of the pointer if it is of the compass form; turn the magnet end for end, keeping it at the same distance, and observe the oppo- site deflection produced ; make observations with the magnet in two positions, at an equal distance on the opposite side of the needle. Let 6.^ be the average deflection obtained from the eight readings (or four readings if made with a telescope), and let T-j be the distance between the centers of the magnet and the needle, — that is, half the distance between the two positions of the magnet. Place the magnet at a different distance, r^, from the needle, and determine as before the average deflection, ^2- Then ^^^ r^Han 6^ - r^Han 6^ Corrections may be made for the effects of temperature and induction upon the magnets. Unless the deflections produced are too small for accurate reading, the shortest distance of the deflecting magnet from the needle should be not less than four times its length, and the greatest distance should be 1.4 times the lesser. M Remits. — Using the values of MH and -- thus determined, H M and H are found separately, which are the magnetic moment 366 ELECTKICITY of the magnet and the horizontal intensity of the earth's mag- netism respectively. 274. The Kew Magnetometer. — A form of magnetometer is sometimes used, for which the method of observing the deflec- tions differs slightly from that described above. The bar carry- ing the deflecting magnet, instead of remaining perpendicular to the plane of the magnetic meridian, is turned about the center of the needle, so that the magnet is always perpendic- ular to the axis of the needle. This requires the substitution of the sine function of the angle of deflection for the tangent in the formula given above; otberwise the method and formulae are not changed. ^ Repeeences. — Kohlrausch, Physical Measurements, pp. 240-260 ; Stewart and Gee, Practical Physics, Vol. II, pp. 285-308 ; Gray, Absolute Measurements in Electricity and Magnetism, Vol. II, p. 69 et seq. CLV. VARIATION OF THE EARTH'S HORIZONTAL MAGNETIC INTENSITY WITH THE VARIOMETER Determine the relative horizontal intensity and direction of the earth's magnetism at several assigned points about the laboratory, and plot the results. 275. The Magnetic Variometer. — A magnetic needle which is made to assume a position at right angles to the magnetic meridian by means of a deflecting magnet acting in opposition to the earth's magnetism is very sensitive to changes in the field strength, and it may be used to determine the variations occur- ring at one place ; or, by placing the instrument in several loca- tions, the relative intensities at these points may be compared. The deflecting magnet is supported below the needle so that it may be rotated in a horizontal plane about the same axis as that on which the needle swings. Its distance below the com- pass may also be varied. An outline of such a variometer is shown in Fig. 178. The instrument may have a mirror needle and a telescope and scale for observing the deflections, and the one deflecting magnet THE VARIOMETER 367 may be replaced by four small magnets placed around the needle and in the same horizontal plane. The adjustment and use of the variometer involve the following operations. (a) The Axis of Rotation of the instrument is to be made vertical, as may be indicated by the level. (b) Sensitiveness. — The magnet when in the meridian must exert a force on the needle slightly in excess of that of the earth. Turn the magnet to the zero of its divided circle and rotate the whole instrument until the iV" pole of the magnet is to the north and the n end of the needle is to the south. It should be possible to rotate the instrument until the reversed needle is parallel to the magnet ; that is, until its s end indicates 0° on the compass circle. If such a position cannot be found, the magnet must be set nearer to the compass. The greater the distance between magnet and needle at which this condition is fulfilled, the greater the sensitiveness. (c) To place the Variometer in the Mag- netic Meridian. — The operations described in the first part of the preceding paragraph place the instrument approximately in the meridian ; but if the position of the magnet is altered to secure proper sensitiveness, it is necessary to make again the meridian adjustment. Set the magnet to the zero of its divided circle. Turn the whole instru- ment until the iVend of the magnet is to the north and the s end of the needle indicates 0° on the compass circle. The needle is then in the meridian. Clamp the instrument to the base. (d) Angle of Rotation of the Magnet. — Turn the magnet to one side till the needle points east and west, and fix a stop to limit this position. Turn the magnet to the other side of the meridian until the needle again points east and west, and place the second stop to determine this position. Fig. 178. The Vakiometer 368 , ELECTEICITY It is not necessary for comparison that the deflection of the needle should be exactly 90°, though it simplifies the computa- tion if this exact deflection is produced when the instrument is set in the place where the horizontal intensity is known. Half of the angle of the rotation of the magnet between the stops is the quantity 6 of the formulae. The stops must remain unchanged in position during the entire set of comparisons. (e) To perfect the Meridian Adjustment. — If the circle read- ings for the positions of the two steps, determined as just described, are different, it indicates that the 0° line of the mag- net and compass circles are not in the same plane. To improve the meridian adjustment, set the large magnet midway between the two stops ; then, as in (c), turn the whole instrument until the s end of the reversed needle indicates 0° on the compass circle. The needle now indicates the magnetic meridian. The change in the position of the instrument required for this is usually so small that the adjustment is not disturbed. It may be repeated if required. In placing the instrument at a new station, the first setting is made with the magnet in the position required in this adjust- ment ; that is, in the position which corrects the zero error of its circle. This correction is not constant because of possible displacement of the circle when it is clamped in a new position on the upright support. 276. Magnetic Declination The variometer being set in the meridian as described, by means of sighting pieces on the com- pass box the angle between the direction of the needle and any given line, as the true north and south or the lines of a building, may be found. 277. Comparison of Horizontal Intensities. — The variometer having been adjusted as described above, in the first location, preferably a place for which the absolute value of the horizontal intensity is known, the magnet is turned against one stop, and the amount by which the needle deviates from the magnetic east and west (90° and 270°) is observed by reading both ends of the needle. The magnet is turned to the second stop, and the deviations of the two ends of the needle from east and west are THE VARIOMETER 369 again read. ■ The average of the four readings is 8 of the formulae, and it is positive if, when the N end of the magnet is turned toward the east, the n end of the needle is deflected more than 270° (that is, the n end is north of west, as shown in Fig. 179). If the magnet and needle have the relative position shown in Fig. 179, the forces acting on the s pole of the needle are the field of the magnet in the direction sF, and the earth's field in the direction sir. If the needle is at rest, the components of Fig. 179. Field op Variometer these two forces in the directions perpendicular to the needle must be equal and opposite. If F is the strength of the mag- net's field and -ff that of the earth, 6 and S having the meanings already explained, jy pos S = J- cos (6-8). The instrument is taken to the second station and adjustments (a) and (e) only are performed. The observations just described are then repeated. By adopting suitable subscripts the results of the measures in the two locations may be represented as follows : _Hj = ^^(cos + sin tan Sj), 11^ = F{cos 6 + sin 6 tan 8^). 370 ELECTRICITY Dividing one equation by the other, the unknown field strength of the magnet is eliminated, and by reducing, ITj _ 1 + tan 6 tan Sj H^ 1 + tan 6 tan Sj If the deflection of the needle at the first station is exactly 90°, 8i is and ^^ = JTj (1 + tan 6 tan 8,). In this manner any number of positions may be compared, and if the intensity at one place is known, the intensity for all the locations may be found. Refekence. — Koklrausch, Physical Measurements, pp. 252-258. 278. Oscillation and Deflection Methods for Comparison of Hori- zontal Intensities. — If a magnet is caused to vibrate as a torsion pendulum in a location where the horizontal intensity has the value JET^, and its period is Tj, determined as explained in Art. 83; and if the same magnet has a period T^ when oscillating in a field of horizontal intensity. JTj, then If a magnet placed in the magnetic east and west line through the center of a suspended needle which is in the location of hori- zontal intensity -Hj, deflects the needle d-^°; and if the deflection produced in the same apparatus when it is in a location of inten- sity H^, is 6^°; then H^: H^ = tan 6^ : tan 6^. CLVI. EARTH'S MAGNETIC INCLINATION AND INTENSITY WITH THE EARTH INDUCTOR Determine the magnetic inclination with the earth inductor by two methods; determine the component and total intensities. 279. The Earth Inductor. — A conductor which can be moved in a determined manner in the earth's magnetic field may have currents induced in it which are often useful for magnetic measurements and comparisons. The earth inductor consists of THE EARTH INDUCTOR 371 a coil of wire 20 cm or more in diameter, suspended so as to be turned about an axis in its own plane ; this axis is sup- ported by a frame which rotates on a second axis at right angles to the first, enabling the axis of the coil to be given any desired inclination from horizontal to vertical. The coil may be rotated continuously in this frame by means of a crank ; or stops may be provided limiting its rotation to 180°, which rotation may be produced by spiral springs. The terminals of the coil make contact through rings and brushes with an external circuit. (See Fig. 180.) If a circuit of wire be moved in a magnetic field so as to change the num- ber of lines of force inclosed by the coil, a current is in- duced in the circuit which is proportional to the change in the number of lines of force. If the coil consists of n turns of wire, each of area a, with its face perpendicular to the lines of a field whose strength is F, the number of lines inclosed is naF. If the plane of the coil is rotated 180°, the same number of lines passes through it in the opposite direction, and there has been a change of 2 naF lines. If the strength of the earth's magnetic field is F, and the direction of the lines of the force makes an angle of dip with the horizontal represented by 6, the horizontal component, H, of this force is F cos 0, and the vertical component, V, is F sin 6. If the plane of the coil of the earth inductor is rotated about an axis parallel to the horizontal component, from a position in which one face of the coil is vertically upward, and therefore in the position in which the maximum vertical component of the force passes through it; to a position 180° from this, the coil will cut Eakth Inductor 372 ELECTRICITY only the vertical component. If the entire resistance of the circuit of which the coil is a part is R ohms, the quantity of current induced by this rotation, in centimeter-gram-second ^"^ R.IO^ ■ If the plane of the coil rotates about an axis parallel to the vertical component, from a position of its face perpendicular to the horizontal component, to the position 180° from this, the coil will cut only the horizontal component of the force, and the induced current will be _ 2 naF cos 6 ^" ^.108 ■ The ratio of the first of these quantities to the second is the ratio of the vertical to the horizontal components, and this is the tangent of the angle of dip. The ratio of the two quantities can be determined without knowing any of the factors by which they are expressed above, by measuring the currents with a ballis- tic galvanometer. For determining the absolute value of the quantities these formulae or those of Art. 281 may be employed. 280. Magnetic Inclination. — Adjust the earth inductor so that the two rectangular axes of rotation shall be level, and so that the axis of the coil shall lie in the plane of the magnetic merid- ian and the plane of the coil shall be horizontal. These con- ditions may be secured by the aid of a compass and a level. Connect the coil in series with a ballistic galvanometer (Art. 253) and a resistance for controlling the current. Then, by means of the spiral springs, release and stop, cause the coil to be suddenly rotated 180°, and observe the galvanometer deflection produced. Make ten or more observations, and cor- rect the average of the readings as described in Art. 252 ; let di be the corrected average. Now place the axis of the coil vertical, as determined by a divided circle, by a plumb line or by other convenient method, and having the plane of the coil perpendicular to the plane of the magnetic meridian, cause the coil to be suddenly rotated 180°. Let d^ be the corrected MAGNETIC INTENSITY 373 average value of the observed galvanometer deflections, obtained with the coil in this position. Then the magnetic inclination, or the angle of dip, 6, is obtained from the following relation. tan0 = _^i d^ Second Method for Inclination. — If the coil of the earth inductor is rotated about an axis parallel to the lines of force of the field, there will be no variation in the number of lines of force inclosed by the coil and no current will be induced. By ti-ial such an inclination of the axis may be found, which gives at once the magnetic dip. 281. Magnetic Intensity. — The absolute value of either com- ponent of the earth's magnetic intensity may be determined from the observations of the preceding article if the constants of the earth inductor and the galvanometer are known. The dip having been determined, the total intensity may also be found. In accordance with the explanation of Arts. 267, 268, and 279, there follow the relations: 2naFs\n6 ^ ,^ , , ^. ■, and V — ^ oi" " — n = i^sin = — =^ i~ — * , Zna ^ K(1 + \X) djt 108 and similarly n=F cos 6 = — !^ 2—^^ ; •' Ana V H from which F = — — z. = ^ ■ sin u cos o The maker of an earth inductor usually supplies a certifi- cate giving the number of turns, w, of wire in the coil, and the diameters of the coils from which the average area, a, may be computed ; or the wires may be exposed to view for counting and measurement. The values of all the other quantities con- tained in these formulae are sufficiently explained in the articles to which reference is made. 374 ELECTKICITY CLVII. DISTRIBUTION OF MAGNETISM BY ROWLAND'S METHOD Determine the distribution and total flow of induction of a permanent magnet. 282. Flow of Induction from a Magnet. — If a circuit be moved from a- position in which it incloses all the lines of force of a magnet, to a position in which it incloses none of these lines, there will be induced in it a quantity of electricity which measures the total flow of induction. Provide a test coil of wire of a known number of turns, n, which will fit around the bar magnet, but with sufficient clear- ance to permit the coil to slide along the bar. Place the coil over the center of the bar magnet, and connect its terminals, through a resistance, B, to a ballistic galvanometer. Suddenly draw the coil off the bar and observe the galvanometer deflec- tion. Let this deflection, corrected as explained in Art. 252, be d, and let the constant of the galvanometer (Art. 268) be K, and its logarithmic decrement (Art. 267) be X; the number of unit tubes of induction emanating from the magnet is 283. Distribution of Magnetism. — When the test coil is on the bar magnet, stops may be clamped on each side of it to limit Fig. 181. Distribution or Magnetism its motion, and if the coil is suddenly moved from one stop to the other a current will be induced which is proportional to COMPARISON OF MAGNETIC FIELDS 375 the average normal component of magnetization between the two points. (See Fig. 181.) By placing the two stops so as to include between them the successive portions of the length of the magnet from one end to the other, and using the test coil in each position, the galvanometer deflections will be pro- portional to the flow of induction from the magnet at these points. If these deflections are plotted as ordinates, with the positions as abscissae, a curve representing the distribution of magnetism is obtained. References. — Stewart and Gee, Practical Physios, Vol. II, p. 388; Barker, Physics, pp. 674 and 812. CLVin. INTENSITY OF A MAGNETIC FIELD BY ROWLAND'S METHOD Find the number of unit tubes of induction per square centimeter in the field between the two poles of an electromagnet. 284. Comparison of Magnetic Fields with the Earth's Field. — Provide a test coil of wire of such size as to inclose that portion of the field which it is desired to measure. Connect the coil C Fio. 182. Intensity or Magnetic Field (Fig. 182) in series with a resistance, B, an earth inductor, /, and a ballistic galvanometer, G. Suddenly rotate the plane of the coil 180° from a position in which the lines of force are perpen- dicular to this plane ; let the galvanometer deflection produced be d^. The earth inductor, being in adjustment for measuring the horizontal component, H, of the earth's field (Art. 279), is 376 ELECTRICITY rotated 180° ; let the resulting galvanometer deflection be d^. If the number of turns of wire in the test coil is N, each of area A, and the number of turns in the earth inductor is n, each of area a, then the strength of the field is NAd^' If the test coil, instead of being rotated 180° in the field, is simply withdrawn from the field, the deflection d^ will be only- half as large as in the above case, and F-^2H nad-i NAd^' Eefeeence. — Stmuart and Gee, Practical Physics, Vol. II, pp. 382-387. CLIX. TEMPERATURE COEFFICIENT OF A MAGNET BY DEFLECTION METHODS Determine the temperature coefficient of a permanent magnet. 285. Temperature Coefficient of a Magnet. — The change in magnetism, per unit magnetism, per degree change of tem- perature, is the temperature coefficient of a magnet. It has a negative value for increasing temperatures. It may be determined by measuring the change in the effect of a magnet upon a suspended needle, when the temperature of the magnet changes. Two methods of manipulation by which the needle will be more sensitive to the control of the magnet are given. Zero Deflection Method. — Immerse the magnet to be experi- mented upon in an oil bath, the temperature of which can be conveniently changed. Place the bath magnetically east or west and at a convenient distance from a suspended magnetic needle, such for instance as the needle of a dead-beat galvanom- eter. Let the angle of deflection produced (not exceeding 20° or 30°) be 6. Now, by means of a compensating magnet, reduce the deflection of the needle nearly to zero. The magnet remaining unchanged in position, let its temperature be altered TEMPERATURE COEFFICIENT OF A MAGNET 377 t°. Let the resulting change in the deflection be d, as read with a telescope and scale distant D from the mirror on the needle. Then the temperature coefficient is M = 2 tan Dt Ninety-Degree Deflection Method. — Place the magnet whose coefficient is desired, in the oil bath, in the same horizontal plane with a short magnetometer needle, and with its center in the plane of the magnetic meridian through the center of the needle. The magnet is to be adjusted accurately to the mag- netic meridian by being turned so that the needle is unde- flected. Now turn the magnet out of the meridian till the needle is deflected about 90°, and let be the angle through which the magnet has been turned. Change the temperature of the magnet t° without altering its position, and, if the needle deflection changes 8 degrees, the temperature coefficient is 1 8 ^ ~ 2 tun 6' t' References. — Kohlrausch, Physical Measurements, p. 260 ; Stewart and Gee, Practical Physics, Vol. II, p. 486. Paet YII — Appbitdix chapter xxvi TABLES, CONSTANTS, AND EEFEEENCES 286. Explanation of Tables. — The data contained in the following tables have been selected and arranged from many sources. The results of recent investigations have been incor- porated as far as possible. The tables for the density and volume of water and of mercury are based upon the determina- tions of density made at the International Bureau of Weights and Measures and reported to the International Congress of Physics, held at Paris in 1900. The table of wave lengths of light is founded upon Michelson's determination of the wave length of cadmium light. The tables have been limited both as to subject-matter and range by the requirements of ordinary laboratory practice. The values of some of the quantities- tabulated, such as the elastic constants of solids, and electrical resistances, vary greatly with circumstances. Sometimes limiting values are given for these quantities, and at other times such single values as seem best to represent the quantities as ordinarily observed. It has not seemed convenient to indicate the sources of information in general. The tables which have been most frequently consulted are : Landolt und Bornstein, Physikalisch- Chemische Tabellen ; ICohlrausch, Praktische Physik ; Everett, The C. G. S. System of Units ; the Smithsonian Physical Tables and the Smithsonian Meteorological Tables. 378 TABLES 379 1. Reduction to Vacuum of Weighings made with Brass Weights in Air If a body of density s has in air the apparent weight of m grams, its weight reduced to vacuum is m + »«fc grams, k is computed for air of density 0.0012 and for brass weights of density 8.4. (See Art. 48.) ^ ^ 0.0012 0.0012 ~ s 8.4 ■ s k s k k s k 0.7 + 0.00157 1.3 + 0.00078 3.0 + 0.00026 10 - 0.00002 0.8 136 1.4 71 3.5 20 12 4 0.9 119 1.6 61 4.0 16 14 6 1.0 106 1.8 52 5.0 10 16 7 1.1 095 2.0 46 6.0 06 18 8 1.2 086 2.5 34 7.0 03 20 8 1.3 078 3.0 26 8.0 01 22 9 2. Density of Various Substances Solids Alnminum 2.7 Beeswax 0.96 Brass 8.1-8.7 Calcspar 2.7 CaoatchOQC 0.95 Copper 8.5-8.9 Glass, Common 2.4-2.6 Flint 3.0-5.9 Gold 19.3 Hard Eubber 1.15 Ice 0.9167 Iridium 21.8-22.4 Iron, Cast 7.1-7.7 Wrought 7.8 Steel 7.8 Ivory Lead 1.9 11.3 Nickel 8.8 Platinum 21.4 Quartz 2.65 Silver Tin Wood, Box Cork Ebony Lignum Vitse Mahogany Oak Pine Pitch Pine 10.5 7.3 0.95-1.16 0.2 1.2 1.2 0.56-0.85 0.60-0.90 0.35-O.50 0.84 LiQOIDS AT 20° Alcohol Amyl Acetate Bromoform Carbon Bisulphide Chloroform Ether 0.789 0.88 2.86 1.264 1.489 0.715 Glycerin Hydrochloric Acid, 40% Methyl Iodide Nitric Acid Olive Oil Petroleum 1.23 1.20 3.34 1.522 0.92 0.88 Sulphuric Acid Turpentine * Water, Pure Sea * Mercury *SeeTable3 1.832 0.87 0.998 1.024 13.546 Gases at 0° and 76 cm Air Carbon Dioxide 0.001 293 0.001 965 Chlorine Hydrogen 0,003091 0.00008987 Nitrogen Oxygen 0.001 251 0.001 429 380 APPENDIX 3. Density of Water and of Mercury at the Temperature t of the Hydrogen Thermometer (Thiesen, Guillaume, International Congress of Physics, Paris, 1900) t Water t Mercdrv o 0.999 823 o 18.5930 1 .999 882 1 .5925 2 .999 923 2 .5901 3 .999 947 3 .5876 4 0.999 955 4 .5851 5 0.999 947 5 13.5827 6 .999 923 6 .5802 7 .999 884 7 .5777 8 .999 831 8 .5753 9 .999 763 9 .5728 10 0.999 682 10 13.5703 11 .999 587 11 .5679 12 .999 480 12 .5654 13 .999 359 13 .5629 14 .999 226 14 .5605 15 0.999 081 15 13.5581 16 .998 925 16 .5556 17 .998 756 17 .5531 18 .998 577 18 .5507 19 .998 387 19 .5482 20 0.998 185 20 13.5457 21 .997 974 21 .5433 22 .997 752 22 .5408 23 .997 520 23 .5384 24 .997 278 24 .5359 25 0.997 026 25 13.5335 26 .996 765 26 .5310 27 .996 496 27 .5286 28 .996 214 28 .5261 29 .995 926 29 .5237 30 0.995 628 30 13.5212 4. Volume of a Glass Vessel at 20° If a glass vessel apparently contains 1 g of water (or of mercury) at the temper- ature t, being weighed with brass weights in air of density 0.00120, the volume of the vessel at 20° is as given in the table. The coefficient of cubical expansion of glass is assumed to be 0.000025. t Volume-Water t VOLUME-MERCnBY o com Q com 5 1.001 49 5 0.073 647 6 .00149 6 .073 658 7 .00150 7 .073 669 8 .00153 8 .073 681 9 .00157 9 .073 693 10 1.001 63 10 0.073 704 11 .00170 11 .073 716 12 .001 78 12 .073 727 13 .001 88 13 .073 739 14 .00199 14 .073 750 15 1.002 10 15 0.073 762 16 .002 23 16 .073 773 17 .002 38 17 .073 785 18 .002 53 18 .073 797 19 .002 70 19 .073 808 20 1.002 87 20 0.073 820 21 ■ .003 06 21 .073 831 22 .003 26 22 .073 843 23 .003 47 23 .073 854 24 .003 69 24 .073 866 25 1.003 92 25 0.073 877 26 .004 15 26 .073 889 27 .004 39 27 .073 900 28 .004 65 28 .073 912 29 .004 92 29 .073 923 30 1.005 19 30 0.073 935 5. Coefficient of Static Friction 6. Relative Viscosity at 19° Wood on Wood Metal on Oak, Dry Wet Metal on Metal,Dry Steel on Glass 0.20-0.50 0.50-0.60 0.24-0.26 0.15-0.20 0.10-0.20 Leather on Metal, Dry Oily Leather on Oak Smooth Surfaces,Oiled Rolling Friction 0.50 -O.60 0.15 -0.23 0.27 -0.38 0.03 -0.08 0.004-0.006 Cylinder Oil Machine Oil Wagon Oil Olive Oil Whale Oil TABLES 381 7. Elastic Constants of Solids SCBSTASOK Young's Modulus Rigidity Elastic Limit Velocity op SOUKD Aluminum Brass , Copper Glass Iron, Cast Iron, Wrought Steel Platinum Silver Wood dynes per scm 6.5 X 10" 7.7-9.3 8.5-11.6 4-^3 6.9-10.8 19.3-20.9 X 1011 20.1-21.6 15. 7. 0.7-1.5 dynes per scm 2.4^3.3 X 10" 3.1-3.6 3.2-4.5 1.7-2.4 2.0-4.2 7.7-8.5 X 10" 8.0-8.8 6.1-6.5 2.6 0.07-0.12 dynes per scm 4.5-11 X 108 3-7 2.3 7. 20 X 108 33-40 14-23 3-11 1.5-2.4 cm per s 5.10 X 105 3.66 3.74 4.42 4.32 5.06 X 106 5.22 2.69 2.61 3. Compressibility of Water, Mercury, and Glass 9. Surface Tension at 20° Substance COMPBESSIOX PEK MEGAEAKYE Elasticity OF Volume Water Mercury Glass 5.0 X 10-5 3.9 X 10-6 2.6 X 10-6 2.03 X 10i» 2.60 X 10" 3.90 X 1011 Water, Pure 73 Water, Saturated with Olive Oil 41 Water, Saturated with Oleate of Soda 25 Olive Oil 35 Turpentine 28 Alcohol 22 10. Absolute Value of Gravity Not reduced to sea level. By the United States Coast and Geodetic Survey, founded upon the provisional value for Potsdam, 1900-1903 Atlanta 979.523 Denver 979.608 San Francisco 979.964 Austin 979.282 Ithaca 980.299 St. Louis 980.000 Boston 980.395 Kansas City 979.989 Terra Haute 980.071 Cambridge 980.397 Little Rock 979.720 Washington 980.111 Charleston 979.545 Montreal 980.742 Worcester 980.323 Charlottesville 979.937 New Orleans 979.323 London 981.201 Chicago 980.277 New York 980.266 Paris 980.941 Cleveland 980.240 Philadelphia 980.195 Potsdam 981.274 Cincinnati 980.000 Princeton 980.177 Para 978.03 Colorado Springs 979.489 Salt Lake City 979.802 Spitzbergen 983.08 11. Local Geographical Data for Cleveland Case Observatory, Latitude, 41°30'14".53; Longitude, 6''26"25'.8; Main Building, Altitude, 21210 cm; Bearing, West of North, 41° 15' Reduction of Central Standard to Local Mean Time -I- 33" 34".l8 382 APPENDIX 12. Specific Gravity of Air At the temperature t, and under the pressure of Hem of mercury, the specific gravity of air referred to water at 4° is 0.001293 H 1 + 0.00367 ( 76 t Pbbssuke H in Centimeters Pbopoetional Pakts 72.0 73.0 74.0 75.0 76.0 77.0 o 10 0.001 182 0.001 198 0.001 215 0.001 231 0.001 247 0.001264 17 em 1 11 178 193 210 227 243 259 0.1 0.2 0.3 2 3 6 12 173 190 206 222 239 255 13 169 186 202 218 234 251 0.4 7 14 165 181 198 214 230 246 0.5 0.6 0.7 8 10 12 15 0.001 161 0.001 177 0.001 193 0.001 210 0.001 226 0.001 242 0.8 14 16 157 173 189 205 221 238 0.9 15 17 153 169 185 201 217 233 cm '' II 18 149 165 181 197 213 229 19 145 161 177 193 209 225 0.2 0.3 3 5 20 0.001 141 0.001 157 0.001 173 0.001 189 0.001 205 0.001 221 0.4 6 21 137 153 169 185 201 216 0.6 10 22 134 149 165 181 197 212 0.7 11 23 130 145 161 177 193 208 0.9 11 24 126 142 157 173 189 204 15 " 1 25 0.001 122 0.001 138 0.001 153 0.001 169 0.001 185 0.001200 cm 0.1 1 26 118 134 149 165 181 196 0.2 0.3 0.4 3 4 6 27 115 130 146 161 177 192 28 111 126 142 157 173 188 0.6 7 29 107 123 138 153 .169 184 0.6 0.7 0.8 9 10 12 30 0.001 104 0.001 119 0.001 134 0.001 150 0.001 165 0.001 180 0.9 13 13. Capillary Depression of Mercury in Glass Tubes DIAMETBK OF Tdbb Height of Meniscus in Centimeters 0.04 0.06 0.08 0.10 0.12 0.14 0.16 0.18 cm cm cm cm cm cm cm cm cm 0.4 0.083 0.122 0.154 0.198 0.237 0.5 .047 .065 .086 .119 .145 0.180 0.6 .027 .041 .056 .078 .098 .121 0.143 0.7 .018 .028 .040 .053 .067 .082 .097 .113 0.8 .020 .029 .038 .046 .056 .065 0.077 0.9 0.015 0.021 0.028 0.033 0.040 0.046 .052 1.0 .015 .020 .025 .029 .033 0.037 1.1 .010 .014 .018 .021 .024 .027 1.2 .007 .010 .013 .015 .018 .019 1.3 V .004 .007 .010 .012 .013 .014 TABLES 383 14. Reduction of Barometer Readings to 0° When the height of a mercury column has been measured with a brass scale, the length of which is correct at 0°, the mercury and scale being at the temperature t, the observed height will be reduced to 0° by subtracting the quantity corresponding to the temperature and height, taken from the following table. (See Art. 54.) t Observed Height in Centimeters 72.0 73.0 74.0 76.0 76.0 77.0 o cm cm cm cm 10 0.12 0.12 0.12 0.12 0.12 0.12 11 .13 .13 .13 .13 .14 .14 12 .14 .14 .14 .15 .15 ' .15 13 .15 .15 .16 .16 .16 .16 14 .16 .17 .17 .17 .17 .17 15 0.17 0.18 0.18 0.18 0.18 0.19 16 .19 .19 .19 .19 .20 .20 17 .20 .20 .20 .21 .21 .21 18 .21 .21 .22 .22 .22 .22 19 .22 .22 .23 .23 .23 .24 20 0.23 0.24 0.24 0.24 0.25 0.25 21 .25 .25 .25 .25 .26 .26 22 .26 .26 .26 .27 .27 .27 23 .27 .27 .28 .28 .28 .29 24 .28 .28 .29 .29 .29 .30 25 0.29 0.30 0.30 0.30 0.31 0.31 26 .30 .31 .31 .32 .32 .32 27 .31 .32 .32 .33 .33 .34 28 .33 .33 .34 .34 .34 .35 29 .34 .34 .35 .35 .36 .36 30 0.35 .0.35 0.36 0.36 0.37 0.37 15. Reduction of Mercury-in-Glass Thermometer Reading to the Normal Hydrogen Scale for Jena Normal Glass, 16'^ (See Art. 133) Reading 0° 10 20 30 40 50 COEBECTION 0°.000 -0.055 -0,090 -0.109 -0.115 -0.109 Reading 50° 60 70 80 90 100 CORBBCTION -0°.109 -0.096 -0.076 -0.053 -0.027 0.000 384 APPENDIX 16. Boiling Temperature of Water / at the Barometric Pressure B B t B t B t B t B t B t cm o cm o cm cm o cm o cm o 72.0 98.49 73.0 98.88 74.0 99.26 75.0 99.63 76.0 100.00 77.0 100.37 .1 .53 .1 .92 .1 .29 .1 .67 .1 .04 .1 .40 .2 .57 .2 .95 .2 .33 .2 .70 .2 .07 .2 .44 .3 .61 .3 98.99 .3 .37 .3 .74 .3 .11 .3 .48 A .65 .4 99.03 .4 .41 .4 .78 .4 .15 .4 .51 72.5 98.69 73.5 99.0T 74.5 99.44 75.5 99.82 76.5 100.18 77.5 100.55 .6 .72 .fi .10 .6 .48 .6 .85 .6 .22 .6 .58 ,7 .76 .7 .14 .7 .52 .7 .89 .7 .26 .7 .62 .8 .80 .8 .18 .8 .55 .8 .93 .8 .29 .8 .66 .9 .84 .9 .22 .9 .59 .9 .96 .9 .33 .9 .69 17. Fixed Points for High Temperatures (See Art. 138) SCBSTANCE BoiLiifG Point Substance MELTING POINT Alcohol o 78.26 Tin o 232 Water 100.0 Zinc 419 Naphthalene 218.0 Aluminum 657 Mercury- 356.7 Gold 1064 Sulphur 445.2 Copper. 1084 Zinc 930. Platinum 1775 18. Heat Constants of Liquids (See also Table 17) Cubical Specific Boiling Heat of Expansion Hkat Point Vapobization o cal Alcohol 0.001 10 0.58 78.3 210. Benzene 0.00124 0.40 80.3 94.4 Glycerin 0.000 50 0.58 290. Mercury 0.000 182 0.0332 356.7 62. Sulphur 0.000 21 0.2 445.2 362. Turpentine 0.000 94 0.42 159. 70. Water 0.00018 1. 100.0 539. TABLES 385 19. Heat Constants of Solids (See also Table 17) SOBSTANCE Linear Specific Melting Heat of Expansion Heat Point Fusion o oal Aluminum 0.0000 23 0.22 657 Brass 19 .093 900 Copper 17 .093 1084 Grerman Silver 18 .095 1000 Glass 0.0000 08 0.19 1100 Iron 12 .11 1300 30. Nickel 13 .11 1470 4.6 Platinum 09 .032 1775 27. Silver 0.000019 0.056 961 21. Steel 11 .12 1350 Tin 23 .054 232 13. Zinc 29 .094 419 28. 20. Reduction of Psychrometric Observations Values of 0.00660 B (t - «„,) [1 + 0.00115 (t - «„)], t being the temperature of the dry-bulb thermometer, („ that of the wet-bulb thermometer, and B the barometric pressure. (See Art. 151.) t-tw Babometeic Pressure B in Centimeters 70.0 71.0 72.0 73.0 74.0 75.0 76.0 77.0 cm cm cm cm cm cm cm cm 1 0.047 0.048 0.048 0.049 0.050 0.050 0.051 0.052 2 .093 .094 .096 .097 .098 .100 .101 .103 3 .139 .141 .143 .145 .147 .149 .152 .154 4 .186 .189 .191 .194 .197 .199 .202 .204 5 0.232 0.2.36 0.239 0.243 0.246 0.249 0.252 0.256 6 .279 .283 .287 .291 .295 .299 .303 .307 7 ..?2(i .331 .336 .340 .345 .350 .354 .359 8 .373 .379 .384 .389 .395 .400 .405 .411 9 .421 .427 .432 .438 .444 .450 .456 .462 10 0.468 0.474 0.481 0.488 0.494 0.601 0.508 0.515 11 .515 .522 .530 .537 .544 .551 .559 .566 12 .562 .570 .578 .586 .594 ,602 .611 .619 13 .610 .618 .627 .6.36 .645 .653 .662 .671 14 .658 .667 .676 .686 .695 .705 .714 .723 15 0.706 0.716 0.726 0.736 0.746 0.756 0.766 0.776 16 .754 .764 .775 .786 .796 .807 .818 .829 17 .802 .813 .824 .836 .847 .859 .870 .882 18 .850 .862 .874 .886 .898 .910 .922 .935 19 .898 .911 .923 .936 .949 .962 .975 ,987 20 0.946 0,960 0.973 0.987 1.000 1.014 1.027 1.041 386 APPENDIX 21. Relative Humidity The table gives the per cent, of satviration of air, t being the temperature of the air, d the dew-point, and t — d the depression of the dew-point. (See Art. 151.) Depression Dew-point, d OF Dew-Poikt t-d -5° 0° + 5° 10° 16° 20° 25° o 100 100 100 100 100 100 100 1 93 93 93 94 94 94 94 2 86 87 87 88 88 88 89 3 80 81 81 82 83 83 84 i 74 75 76 77 78 78 79 ■5 69 70 71 72 73 74 75 6 64 66 67 68 69 70 70 7 60 61 62 63 65 66 67 8 56 57 58 60 61 62 63 9 52 53 55 56 57 58 60 10 49 50 51 53 54 55 56 12 42 44 45 47 48 49 50 14 37 38 40 41 43 44 45 16 32 34 35 37 38 39 18 28 30 31 33 34 35 20 25 26 28 29 30 .32 25 18 19 21 22 23 30 13 14 16 17 22. Declination of the Sun, and Equation of Time Declina- DiFF. Equation DECLDfA- DlFF. Equation tion IDAY OF Time TION IDay oe Time o o m s o o m s Jan. -23.1 0.11 + 3 15 July 9 + 22.4 0.15 0.21 0.26 0.30 0.34 + 4 49 10 -22.0 0.18 + 7 42 19 + 20.9 + 5 58 20 -20.2 0.25 + 11 13 29 + 18.8 + 6 13 30 -17.7 0.30 + 13 32 Aug. 8 + 16.2 + 5 27 Feb. 9 -14.7 0.34 + 14 27 18 + 13.2 + 3 44 19 -11.3 0.37 + 14 5 28 + 9.8 0.36 0.39 0.39 0.38 0.38 + 1 11 March 1 - 7.6 0.38 + 12 36 Sept 7 + 6.2 - 1 59 11 - 3.8 0.40 + 10 15 17 + 2.3 - 5 26 21 -f 0.2 0.39 + 7 23 27 - 1.5 - 8 55 31 + 4.1 0.38 + 4 19 Oct. 7 - 5.4 -12 4 April 10 + 7.9 0.35 + 1 23 17 - 9.2 0.35 0.32 0.26 0.22 0.16 -14 31 20 4-11.4 0.33 - 1 5 27 -12.7 -16 30 -M4.7 0.29 - 2 62 Nov. 6 -15.9 - 16 .16 May- 10 -M7.6 0.23 - 3 48 16 -18.7 -15 7 20 + 19.9 0.18 - 3 45 26 -20.9 -12 36 .SO -1-21.7 0.12 - 2 49 Dec. 6 -22.5 0.08 0.01 0.08 - 8 54 June 9 + 22.9 0.05 - 1 11 16 -23.3 - 4 17 19 + 23.4 0.01 + 55 26 -23.4 + 41 29 + 23.3 0.09 + 32 Jan. 5 -22.6 + 5 34 TABLES 387 23. Tension and Mass of Aqueous Vapor in Saturated Air The table gives the tension e, and the mass / per cubic meter, of water vapor in air saturated at the temperature t. (See Art. 151.) t c f t e / i e / o cm g o cm g o cm g 0.46 4.9 10 0.92 9.4 20 1.75 17.3 1 0.49 5.2 11 0.98 10.0 21 1.86 18.3 2 0.33 5.6 12 1.05 10.7 22 1.98 19.4 3 0.57 6.0 13 1.12 11.4 23 2.11 20.6 4 0.61 6.4 14 1.20 12.1 24 2.24 21.8 5 0.65 6.8 15 1.28 12.8 25 2.38 23.1 6 0.70 7.3 16 1.36 13.7 26 2.53 24.5 7 0.75 7.8 17 1.45 14.5 27 2.68 26.8 8 0.80 8.2 18 1.55 15.4 28 2.84 27.3 9 0.86 8.8 19 1.65 16.3 29 3.01 28.8 10 0.92 9.4 20 1.75 17.3 30 3.18 30.4 24. Index of Refraction of Various Substances for Sodium Light, D Line, X = 0.5893 /i Air, Dry, 0° 1.0002945 20° 1.0002773 Ice 1.31 Water, 15° 1.33361 20° 1.33319 Alcohol 1.3616 Benzene 1.5005 Canada Balsam 1.54 Glass, Light crown Heavy crown Light flint Heavy flint Heaviest flint Carbon Bisul- phide, 15° 20° Phosphorus in CS, 1.5153 1.6152 1.6085 1.7515 1.9 1.6317 1.6277 1.97 a-Bromonaphtha- lene, 15° 20° Methyl Iodide, 15° 20° Calcite, Ordinary Eay Extraordinary Quartz, Ordinary Eay Extraordinary 1.6518 1.6495 1.7429 1.7419 1.6585 1.4864 1.5442 1.5533 25. Wave Length of Lines of Solar Spectrum in Air at 20°, Pressure 76 cm ; Unit, Micron = 0.001 mm (See Art. 196) Line Element Wave Length Line Element Wave Length Line Element Wave Length A a B C a O H O Na 0.7628 0.7185 0.68701 0.65629 0.62781 0.58960 6. c F d Na Fe, Ca Mg Fe H Fe 0.58900 0.,52703 0.51837 0.49576 0.48614 0.46682 e i h H K Fe H Fe, Ca H H, Ca Ca 0.43836 0.43405 0.43079 0.41018 0.39685 0.39337 388 APPENDIX 26. Specific Resistance of Various Substances p is the resistance at 0° of a conductor 1 cm long and 1 scm in section, a is the rate of increase in resistance per degree increase in tempera- ture. The resistance of a conductor of length / and section s at the temperature t is (see Art. 235) Rt = p-(l +at). SUBSTAKOE p a SUBSTAHOB P a ohms ohms Silver 0.16 X 10-6 0.0037 Iron 1.04 X 10-5 0.0060 Copper 0.17 43 Steel 5. 60 Gold 0.20 36 Lead 2.00 39 Aluminum 0.30 39 Manganin 4.20 003 Zinc 0.57 X 10-5 0.0036 German Silver 2.09 X 10-5 0.0003 Nickel 0.70 60 Brass 0.8 40 Platinum, Pure 1.08 32 Mercury 9.41 09 Commercial 1.40 32 Gas Carbon 500. - .0005 27. Electromotive Force and Internal Resistance of Cells Cell E. M. F. Besistakce Cell E. M. F. Eesistanoe volts ohms volts ohms Edison-Lalaude 0.7 0.03 Grove 1.9 0.1-0.2 Daniel 1.08 0.85 Bunsen 1.9 0.1-0.2 Gravity 1.1 1-5 Bicliromate 2.0 0.08-0.40 Silver Chloride 1.1 4. Storage 2.0 0.004-0.02 Dry Cell 1.3 0.2-1.0 * Clark Standard 1.4267 20-50 Leclanchg 1.4-1.7 0.4-0.2 * Weston Standard 1.0190 20-50 28. Vibration Frequency of Tones of the Musical Scale Higher or lower octaves are obtained by multiplying by some power of 2. SoiENTiPic Diatonic Scale Musical Equal-Tempered Chkomatio Scale Ca=256 A3=435 0« 2S6. Cs 258.65 Gs 387.54 Ds 288. C»3 274.03 GSs 410.58 Es 320. Da 290.33 As 43S. Fs Gs As 341.33 384. 426.66 D^ 307.59 A#s 460.87 Es 325.88 Bs 488.27 Bs 480. Fs 345.26 C4 517.30 Ci 512. F«s 365.79 REFERENCES 389 29. Reference Books The following list specifies those books and papers to which reference has been made in the text Barker, George F. Physics. New York, 1892. Barus, Cari.. Les Progres de la PyronxHrie. Rapports au Congrfes Interna- tional de Physique. Paris, 1900. Benton, J. R. Internal Resistance of Cells. Physical Review, 16, 1903. Carhart, Henry S., and Patterson, George W. Electrical Measurements. Boston, 1895. , Chappuis, p. L'Echelle Themiom^trigue Normale, Rapports au Gongrfes Inter- national de Physique ; Pyromitrie, Travaux et Memoires du Bureau Interna- tional des Poids et Mesures, Tome XII, Part 3. Paris, 1900. Chauvenet, William. Spherical and Practical Astronomy, 2 vols. Philadel- phia, 1863. Daniell, Alfred. Principles of Physics, 3d ed. New York, 1894. Drude, Paul. TOeorj/ o/ Opiics, trans, by Mann and MiUikan. New York, 1902. Everett, J. D. The C. G. S. System of Units, 5th ed. London, 1902. Gdazebrook, R. T. Physical Optics. London, 1882. Glazebrook, R. T., and Shaw, W. N. Practical Physics. London, 1884. Gray, Andrew. Absolute Measureinents in Electricity and Magnetism, 3 vols. London, 1888. Gray, Thomas. Smithsonian Physical Tables. Washington, 1896. GuiLLAUME, Ch. Ed. Thermometrie de Precision. Paris, 1889. GuYOT, LiBBEY, aud others. Smithsonian Meteorological Tables. Washington, 1893. Hastings, Charles S., and Beach, Frederick E. General Physics. Boston, 1899. HoLM.iN, Silas W. Precision of Measurements. New York, 1892. Johnson, 3. B. Theory and Practice of Surveying, 3d ed. New York, 1887. Koenig, Rudolph. Quelques Experiences d' Acoustique. Paris, 1882. Kohlrausch, F. Physical Measurements, 3d English from 7th German ed. New York, 1894. 9th German ed., Leipzig, 1901. Landauer, John. Spectrum Analysis, trans, by J. B. Tingle. New York, 1898. Landolt, H. Optical Rotating Power, trans, by J. H. Long. Easton, 1902. Landolt und Bornstein. Physikalisch^Chemische Tabellen, 2d ed. Berlin, 1893. Le Chatelier, H. High-Temperature Measurevnents, trans, by G. K. Burgess. New York, 1901. Leiss, C. Die optischen Instrumente der Firma R. Fuess. Leipzig, 1899. LuPTON, Sidney. Notes on Observations. London, 1898. Magie, William Francis. The Specific Heat of Solutions. Physical Review, 9, 1899; 14,1902. Merriman, Mansfield. Method of Least Squares, 7th ed. New York, 1897. Michelson, Albert A. Interference Phenomena in a New Form, of Inter- ferometer, Philosophical Magazine, 13, 1882; Valuer du Metre en Longueurs d'Ondes Lumineuses, Travaux et Memoires du Bureau International du Poids et Mesures, Tome XI. Paris, 1894. Light Waves and their Uses. Chicago, 1903. MORLEY, Edward W. Optical Principles of the Interferometer. Physical Review, 4, 1897. Nichols, Edward L. Laboratory Manual of Physics and Applied Electricity, 2 vols. New York, 1894. OSTWALD, WiLHELM. Physico-Chcmical Measurements, trans, by James Walker. London, 1893. 2d German ed. Leipzig, 1902. Palaz, H. Indujitrial Photometry, trans, by G. W. Patterson. New York, 1896. Preston, Thomas. Theory of Light, 2d ed. London, 1895 ; Theory of Heat, London, 1894. Price, B. Treatise on Infinitesimal Calculus, 2d ed., 4 vols. Oxford, 1868. PULFRICH, C. ANewFormofRefractometer. Astrophysical Journal, S, 1896. 390 APPENDIX Rebd, J. O. Method of Eating Tuning Forks. Physical Review, 12, 1901. EoUTH, E. J. Dynamics of a System of Rigid Bodies, 2 vols., 5tli ed. New York, 1890. ScHEiNER, J. Astronomical Spectroscopy, trans, by E. B. Frost. Boston, 1894. Schuster, Arthur, and Lees, C. H. Practical Pnysics. Cambridge, 1901. Shedd, J. C. Forms of Curves presented by the Michelson Interferometer. Physical Review, 11, 1900. Staley, Cady. Gillespie's Surveying, 2 vols., revised ed. New York, 1897. Stewart, Balfour, and Gee, W. W. Haldane. Practical Physics, 3 vols. London, 1885. Stine, Wilbur M. Photometrical Measurements. New York, 1900. Wadsworth, F. L. O. Applications of the Interferometer. Physical Review, 4, 1897. Whitman, F. P. On the Photometry of Different Colored Lights. Physical Review, 3, 1896; Science, 9, 1899. Zahm, J. H. Sound and Music. Chicago, 1892. 30. Miscellaneous Constants and Numbers T = 3.14159265 ir^ = 9.869604 log ir = 0.49714987 4 5r = 12.566 Jtt =0.079577 log 4 tt = 1.09921 1 Radian = 57°.2958 = 3437'.75 = 206265" Logarithms 1.758123 3.536274 5.314425 Base of natural logarithms, e = 2.7182818 ; log e = 0.434294. Mean radius of the earth, 6.37106 X IQS cm. Mechanical equivalent of heat, 4.184 X 10^ ergs. (See Art. 139.) Candle power: 1 English candle = 0.95 German candle = 1.14 Hefner units. (See Art. 155.) Velocity of sound in dry air at 0°, 33136 cm per s ; in illuminating gas at 0°, 49000 cm per s. (See Table 7, and Art. 114.) Velocity of light in vacuum, 2.9989 X 10i» cm per s. Specific rotation of sugar, [a]2»° = 6°.65 per cm. (See Art. 203.) Electro-chemical equivalents: silver, 0.001118; copper, 0.0003279; g per s per ampere. (See Arts. 243, 244.) Temperature coefficient of magnetism, from 0.0003 to 0.001. 31. Metric and English Equivalents and Abbreviations 1 inch = 2.539998 cm 1 micron = 0.001 mm m meter 1 foot = 30.47997 cm 1 meter = 39.37011 inches dm decimeter lyard =91.43992 cm 1 kilometer = 0.621371 miles cm centimeter 1 mile = 160934.3 cm 1 gram = 15.43236 grains mm millimeter Avoirdupois 1 milligram = 0.01543 grains km kilometer 1 grain = 64.79892 mg 1 kilogram = 2.204622 pounds fi, 0.001 millimeter 1 ounce = 28.34953 g 1 liter =1.75980 pints HH 0.000001 millimeter 1 pound = 453.5924 g Approximate Equivalents tenth-meter = lO-" m Troy 1 millimeter =A inch g gram 1 grain = 64.79892 mg 1 meter = 3 ft, 3 in, J in mg milligram 1 ounce = 31.10348 g 1 kilometer = 8 mile kg kilogram Apothecary 1 gram = 158 grains scm square centimeter 1 ounce = 31.10348 g 1 quart = 1.13649 1 1 kilogram = 2J pounds ccm cubic centimeter 1 liter = li pints 1 liter TABLES 32. Natural Trigonometrical Functions 391 Sine 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 0.0000 .0175 .0349 .0523 0.0872 .1045 .1219 .1392 .1564 0.1736 .1908 .2079 .2250 .2419 0.2588 .2756 .2924 .3090 .3256 0.3420 .3584 .3746 ..3907 .4067 0.4226 .4.384 .4540 .4695 .4848 0.5000 .5150 .5299 .5446 .5592 0.57.36 ..5878 .6018 .61.57 .6293 0.6428 .6.561 .6947 0.7071 175 174 174 175 174 173 174 173 172 172 172 171 171 169 169 168 168 166 166 164 im 162 161 160 159 168 156 155 153 152 150 149 147 146 144 142 140 139 136 135 133 130 129 127 124 Cosine Tangent 0.0000 .0175 .0349 .0524 .0699 0.0875 .1051 .1228 .1405 .1584 0.1763 .1944 .2126 .2309 .2493 0.2679 .2867 .3057 .3249 .3443 0.3640 .3839 .4040 .4245 .4452 0.4663 .4877 .5095 .5317 .5543 0.5774 .6009 .6249 .6494 .6745 0.7002 .7265 .7536 .7813 0.8391 .8693 .9004 .9325 .9657 1.0000' Cotangent COTANOENT oo 57.29 28.64 19.08 14.30 11.43 9.514 8.144 7.115 6.314 5.671 5.145 4.705 4.,331 4.011 3.732 3.487 3.271 3.078 2.904 2.747 2.605 2.475 2.356 2.246 2.145 2.0.50 1.963 1.881 1.804 1.732 1.664 1.600 1.S40 1.483 1.428 1.376 1.327 1.280 1.235 1.192 1.150 1.111 1.072 1.036 1.000 801 643 526 440 374 320 279 216 193 174 157 142 130 119 110 101 95 87 82 77 72 TANGENT Cosine Degree 1.0000 0.9998 .9994 .9986 .9976 0.9962 .9943 ■ .9925 .9903 .9877 0.9848 .9816 .9781 .9744 .9703 0.9659 .9613 .9563 .9511 .9455 0.9397 .9336 .9272 .9205 .9135 0.9063 .8988 .8910 .8829 .8746 0.8660 .8572 .8480 .8387 .8290 0.8192 .8090 .7986 .7880 .7771 0.7660 .7547 .7431 .7314 .7193 0.7071 02 04 08 10 14 17 20 22 26 29 32 35 37 41 44 46 50 62 56 58 61 64 67 70 72 75 78 81 88 92 93 97 102 104 106 109 111 113 116 117 121 122 90 87 86 84 83 82 81 79 78 77 76 75 74 73 72 71 70 69 68 67 66 65 64 63 62 61 60 59 58 57 56 55 54 53 52 51 50 49 48 47 46 45 Degree 392 APPENDIX 33. Logarithms Propoktional Parts , N 12 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 10 0000 0043 0086 0128 0170 0212 0253 0294 0334 0374 4 8 12 17 21 25 29 33 37 11 0414 0453 0492 0531 0569 0607 0645 0682 0719 0755 4 8 11 15 19 23 26 30 34 12 0792 0828 0864 0899 0934 0969 1004 1038 1072 1106 3 7 10 14 17 21 24 28 31 13 1139 1173 1206 1239 1271 1303 1335 1367 1399 1430 3 6 10 13 16 19 23 26 29 14 15 1461 1492 1523 1553 1584 1614 1644 1673 1703 1732 3 6 9 12 15 18 21 24 27 1761 1790 1818 1847 1875 1903 1931 1959 1987 2014 3 6 8 11 14 17 20 22 25 16 2041 2068 209S 2122 2148 2175 2201 2227 2253 2279 35 8 11 13 16 18 21 24 17 2304 2330 2353 2380 2405 243a 2455 2480 2504 2529 2 5 7 10 12 15 17 20 22 18 2553 2577 2601 2625 2648 2672 2695 2718 2742 2765 2 5 7 9 12 14 16 19 21 19 20 2788 2810 2833 2856 2878 2900 2923 2945 2967 2989 24 7 9 11 13 16 IS 20 3010 3032 3054 3075 3096 3118 3139 3160 3181 3201 2 4 6 8 11 13 15 17 19 21 3222 3243 3263 3284 3304 3324 3345 3365 3385 3404 2 4 6 8 10 12 14 16 18 22 3424 3444 3464 3483 3502 3522 3541 3560 3579 3598 24 6 8 10 12 14 15 17 23- 3617 3636 3655 3674 3692 3711 3729 3747 3766 3784 24 6 7 9 11 13 15 17 24 2R 3802 3820 3838 3856 3874 3892 3909 3927 3945 3962 24 5 7 9 11 12 14 16 3979 3997 4014 4031 4048 4065 4082 4099 4116 4133 2 3 5 7 9 10 12 14 15 26 4150 4166 4183 4200 4216 4232 4249 4265 4281 4298 2 3 5 7 8 10 11 13 15 27 4314 4330 4346 4362 4378 4393 4409 4425 4440 4456 2 3 S 6 8 9 11 13 14 28 4472 4487 4502 4518 4533 4548 4564 4579 4594 4609 23 5 6 8 9 11 12 14 29 30 4624 4639 4654 4669 4683 4698 4713 4728 4742 4757 1 3 4 6 7 9 10 12 13 4771 4786 4800 4814 4829 4843 4857 4871 4886 4900 1 3 4 6 7 9 10 11 13 31 4914 4928 4942 4955 4969 4983 4997 5011 5024 5038 1 3 4 6 7 8 10 11 12 32 5051 5065 5079 5092 5105 5119 6132 5145 6169 6172 1 3 4 5 7 8 9 11 12 33 5185 5198 5211 5224 5237 5250 5263 5276 5289 5302 1 3 4 6 6 8 9 10 12 34 5315 5328 5340 5353 5366 5378 5391 5403 5416 5428 1 3 4 5 6 8 9 10 11 5441 5453 6465 5478 5490 5502 5614 5527 5539 6661 1 2 4 5 6 7 9 10 11 36 5563 5575 5587 5599 5611 5623 5636 5647 5658 5670 1 2 4 6 6 7 8 10 11 37 5682 5694 5705 5717 5729 5740 6752 5763 5775 5786 1 2 3 5 6 7 8 9 10 38 5798 5809 5821 5832 5843 5855 5866 6877 5888 6899 1 2 3 5 6 7 8 9 10 39 40 5911 5922 5933 5944 5955 5966 5977 5988 5999 6010 1 2 3 4 5 7 8 9 10 6021 6031 6042 6053 6064 6076 6086 6096 6107 6117 1 2 3 4 5 6 8 9 10 41 6128 6138 6149 6160 6170 6180 6191 6201 6212 6222 1 2 3 4 5 6 7 8 9 42 6232 6243 6253 6263 6274 6284 6294 6304 6314 6326 1 2 3 4 5 6 7 8 9 43 6335 6345 6355 6365 6375 6385 6395 6405 6415 6425 1 2 3 4 5 G 7 8 9 44 4R 6435 6444 6454 6464 6474 6484 6493 6503 6513 6522 1 2 3 4 5 6 7 8 9 6532 6542 6551 6561 6571 6580 6590 6599 6609 6618 1 2 3 4 5 6 7 8 9 46 6628 6637 6646 6656 6665 6676 6684 6693 6702 6712 1 2 3 4 5 6 7 7 8 47 6721 6730 6739 6749 6758 6767 6776 6785 6794 6803 1 2 3 4 5 5 6 7 8 48 6812 6821 6830 6839 6848 6857 6866 6875 6884 6893 1 2 3 4 4 5 6 7 8 49 fiO 6902 6911 6920 6928 6937 6946 6955 6964 6972 6981 1 2 3 4 4 5 6 7 8 6990 6998 7007 7016 7024 7033 7042 7050 7059 7067 1 2 3 3 4 5 6 7 8 fil 7076 7084 7093 7101 7110 7118 7126 7136 7143 7152 1 2 3 3 4 5 6 7 8 fi2 7160 7168 7177 7185 7193 7202 7210 7218 7226 7235 1 2 2 3 4 5 6 7 7 m 7243 7251 7259 7267 7275 7284 7292 7300 7308 7316 1 2 2 3 4 5 6 6 7 54 7324 7332 7340 7348 7356 7364 7372 7380 7388 7396 1 2 2 3 4 5 6 6 7 N 12 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 TABLES 33. Logarithms 393 N 12 3 4 5 6 7 8 9 Proportional Parts 12 3 4 5 6 7 8 9 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 N 7404 7412 7419 7427 7435 7482 7490 7497 7505 7513 7559 7566 7374 7582 7589 7634 7642 7649 7657 7664 7709 7716 7723 7731 7738 7443 7451 7459 7466 7474 7520 7528 7536 7543 7551 7597 7604 7612 7619 7627 7672 7679 7686 7694 7701 7745 7752 7760 7767 7774 12 2 3 12 2 3 12 2 3 112 3 112 3 4 4 4 4 4 5 5 6 4 4 5 6 7 5 6 7 5 6 7 5 6 7 5 6 7 7782 7789 7796 7803 7810 7853 7860 7868 7875 7882 7924 7931 7938 7945 7952 7993 8000 8007 8014 8021 8062 8069 8075 8082 8089 7818 7825 7832 7839 7846 7889 7896 7903 7910 7917 7959 7966 7973 7980 7987 8028 8035 8041 8048 8055 8096 8102 8109 8116 8122 112 3 112 3 112 3 112 3 112 3 4 4 3 3 3 4 4 4 4 4 5 6 6 6 6 6 5 6 6 6 5 6 5 5 6 8129 8136 8142 8149 8156 8195 8202 8209 8215 8222 8261 8267 8274 8280 8287 8325 8331 8338 8344 8351 8388 8393 8401 8407 8414 8162 8169 8176 8182 8189 8228 8235 8241 8248 8234 8293 8299 8306 8312 8319 8357 8363 8370 8376 8382 8420 8426 8432 8439 8445 112 3 112 3 112 3 112 3 112 3 3 3 3 3 3 4 4 4 4 4 5 5 6 5 5 6 6 6 6 4 5 6 4 5 6 8451 8457 8463 8470 8476 8513 8519 8525 8531 8537 8573 8579 8385 8591 8597 8633 8639 8645 8651 8657 8692 8698 8704 8710 8716 8482 8488 8494 8500 8606 8543 8549 8653 8561 8567 8603 8609 8615 8621 8627 8663 8669 8675 8681 8686 8722 8727 8733 8739 8745 112 2 112 2 112 2 112 2 112 2 3 3 3 3 3 4 4 4 4 4 4 5 6 4 5 5 4 5 5 4 5 5 4 6 5 8751 8756 8762 8768 8774 8808 8814 8820 8825 8831 8865 8871 8876 8882 8887 8921 8927 8932 8938 8943 8976 8982 8987 8993 8998 8779 8785 8791 8797 8802 8837 8842 8848 8854 8869 8893 8899 8904 8910 8915 8949 8954 8960 8965 8971 9004 9009 9015 9020 9025 112 2 112 2 112 2 112 2 112 2 3 3 3 3 3 3 3 3 3 3 4 6 5 4 6 6 4 4 5 4 4 5 4 4 5 9031 9036 9042 9047 9053 9085 9090 9096 9101 9106 9138 9143 9149 9154 9159 9191 9196 9201 9206 9212 9243 9348 9253 9258 9263 9058 9063 9069 9074 9079 9112 9117 9122 9128 9133 9165 9170 9175 9180 9186 9217 9222 9227 9232 9238 9269 9274 9279 9284 9289 112 2 112 2 112 2 112 2 112 2 3 3 3 3 3 3 3 3 3 3 4 4 5 4 4 5 4 4 6 4 4 6 4 4 6 9294 9299 9304 9309 9315 9345 9350 9355 9360 9365 9395 9400 9405 9410 9415 9445 9450 9455 9460 9465 9494 9499 9504 9509 9513 9320 9325 9330 9335 9340 9370 9375 9380 9385 9390 9420 9425 9430 9435 9440 9469 9474 9479 9484 9489 9518 9323 9528 9533 9538 112 2 112 2 112 112 112 3 3 2 2 2 3 3 3 3 3 4 4 6 4 4 5 3 4 4 3 4 4 3 4 4 9542 9547 9552 9557 9562 9590 9595 9600 9605 9609 9638 9643 9647 9652 9657 9685 9689 9694 9699 9703 9731 9736 9741 9745 9750 9566 9371 9576 9581 9586 9614 9619 9624 9628 9633 9661 9666 9671 9675 9680 9708 9713 9717 9722 9727 9754 9759 9763 9768 9773 112 112 112 112 112 2 2 2 2 2 3 3 3 3 3 3 4 4 3 4 4 3 4 4 3 4 4 3 4 4 9777 9782 9786 9791 9795 9823 9827 9832 9836 9841 9868 9872 9877 9881 9886 9912 9917 9921 9926 9930 9956 9961 9965 9969 9974 9800 9805 9809 9814 9818 9845 9850 9854 9859 9863 9890 9894 9899 9903 9908 9934 9939 9943 9948 9962 9978 9983 9987 9991 9996 112 112 112 112 112 2 2 2 2 2 3 3 3 3 3 3 4 4 3 4 4 3 4 4 3 4 4 3 3 4 12 3 4 5 6 7 8 9 12 3 4 6 6 7 8 9 INDEX [The numbers refer to pages] Abbe, orystal-refractometer, 244 Abbreviations, Table 31. Absolute, capacity, 356 ; humidity, 197 ; index of refraction, 234, 235 ; mass, 64; units, 12. Accelerated motion, with Atwood's machine, 77 ; with falling tuning fork, 74. Acceleration with variable time unit, 76. Accidental errors, 7. Adjusting, ballistic galvanometer, 387 ; cathetometer, 97 ; difierential gal- vanometer, 300 ; galvanometers in general, 288 ; heliostat, 274 ; inter- ferometer, 258 ; reading microscope, 22 ; reading telescope and scale, 38, 290, 338 ; sextant, 47; spectrometer, 226 ; tangent galvanometer, 296 ; variometer, 367 ; weights, 68. Air, columns, vibrating, 151 ; density of. Table 12 ; method for determin- ing density of, 126 ; index of refrac- tion of, 235 ; thermometer, 166. Alternating currents, for resistance measures, 309 ; method of measur- ing, 330, 341. Altitudes with the barometer, 72. Ammeter, 302, 303, 345. Ampere, the, 323. Amyl acetate lamp, 207. Analysis, sound, 152 ; spectrum, 271 ; sugar, 280. Aneroid, testing, 110. Angle, of crystal, 223 ; of prism, 230 j of minimum deviation, 235 ; from scale readings, 337. Arc, lamp, photometry of, 210; mer- cury, 264 ; spectrum of, 273. Archimedes, Principle of, 119. Areas, measured with planimeter, 42 ; formulae for, 46. Assignment of exercises, 4. Astatic galvanometer, 288. Atmospheric pressure, barometer, 69. Atwood, machine of, 77. Auguste, psychrometer, 200. B Balance, the, 55, 64 ; hints on use of, 62 ; hydrostatic, 120 ; Jolly's spring, 129 ; ratio of arms of, 59 ; rider for, 55, 61 ; sensibility of, 62. Ballistic, constant, 359 ; galvanometer, 337 ; pendulum, 51. Bands, see fringes. Barometer, the, 69; aneroid, 110; Fortin, 70 ; pressure, 72 ; readings, reduction of, 70, Table 14 ; siphon, 70. Barus, method of calibrating bridge wire, 319. Barye, the, 72. Battery, electromotive force of. Table 27; resistance of. Table 27; meas- urement of resistance of : by Beetz's method, 307; Benton's method, 308; Kohlrausch's method, 309 ; by method of fall of potential, with voltmeter, ammeter, or condenser, 302 ; Mance's method, 306. Beats, frequency of sound by, 134. Beetz, method for battery resistance, 307. Benton, method for battery resistance, 308. Bi-prism for interference, 246. Black, ice calorimeter, 178. Boiling point, of various substances, 171, Tables 17, 18 ; of water, Table 16; of thermometer, 163. 394 INDEX 395 Books, for notes, 5 ; reference. Table 29. Boyle, Law of, 108, 197. Brashear, method of silvering and cleaning glass, 266, 270. Bridge, the box, 293 ; calibrating of wire of, 319 ; for measuring low re- sistances, 315 ; method for capacities, 353 ; Wheatstone's, 283. Bulk elasticity, modulus of, 93, 106, Table 8. Bunsen, ice calorimeter, 180 ; photom- eter, 206, 210. Buoyancy of air in weighing, 64, 121, Table 1. Cadmium, light, 264 ; cell, 333. Calibration, of aneroid, 110 ; of bridge wire, 319 ; with comparator, 30 ; of graduated scales, 28, 32 ; of level, 39; by precise methods, 32; of thermom- eter, 160 ; of voltmeter, 348 ; of weights, 66 ; with dividing engine, 28. Calipers, micrometer, 18 ; vernier, 17. CaMendar, platinum thermometer, 169. Calorie, the, 13, 173. Calorimeter, Black'sice, 178 ; Bunsen's ice, 180 ; cooling, 186 ; described, 173; electro-, 188, 324; heat capacity of, 174; Magie's, 188; Pfaundler's, 188 ; Eegnault's, 182, 184. Calorimetry, 173. Candle, British, 207; German, 207; power, 13, 204, 208. Capacity, absolute, 356 ; comparison of, with ballistic galvanometer, 352 ; with bridge, 353 ; by method of mixtures, 355 ; thermal, of calorim- eter, 174. Capillarity, 113. Capillary, correction for barometer, 71; depression. Table 13; electrom- eter, 342. Carbon rheostat, 292. Card system of assignment of exer- cises, 4. Carey Foster, method of resistance measurement, 316. Carhart, standard cell, 332. Cathetometer, the, 97; for determin- ing Young's modulus, 96. Cells, Carhart-Clark, 332; concentra- tion, 344 ; electromotive force and internal resistance of, Table 27; measurement of resistance of, see battery ; standard, 332 ; Weston, 333. Centimeter, the, 13. Charge, electrical, see capacity. Chronograph, cylinder, 86 ; tuning fork, 91, 136. Circles, divided, to read, 17, 229 ; dividing-engine for, 27. Clark, standard cell, 332. Cleaning glass for silvering, 270 ; glassware, 115. Cleveland, g and barometric pressure, 72 ; geographical data for, Table 11 . Coefficient, of elasticity, 93 ; of expan- sion, cubical, 155; of expansion, linear, 153 ; of expansion, linear and cubical. Tables 18, 19 ; of friction, 112, Table 5; of a gas, 168; of mutual induction, 361 ; of restitu- tion, 51 ; of rigidity, 99 ; of self-in- duction, 360 ; temperature, of mag- netism, 376, Table 30; temperature, of resistance, 292, 316, Table 26 temperature, of tuning forks, 133 of viscosity, 117. See modulus. Coincidences, method of, 82 ; optical method of, 88. Collimating eyepiece, 226. Collimator, 225, 228. Collision, 51. Commutator, 298. Comparator, 23 ; dividing-engine, 26 ; Lissajous's optical, 137 ; micrometer microscope, 30. Compensation, apparatus, 335; method for electromotive force, 333, 344. Compressibility, with piezometer, 106, Table 8. Concave, grating spectroscope, 251 ; lenses, 217 ; mirrors, 214. Concentration cell, 344. Condenser, capacity of, see capacity ; for determining electromotive force, 336 ; key, 351 ; standard, 350. Conductivity of electrolytes, 310. Conjugate foci, 213. Conservation of momentum, 51. Constant, ballistic, 359 ; errors, 7 ; of micrometer microscope, 20 ; of tan- gent galvanometer, 322. Constants, of a level, 39 ; elastic, of solids. Table 7 ; heat, for liquids. Tables 17, 18 ; heat, for solids. Tables 17, 19; miscellaneous, Table 30. 396 INDEX Contact difference of potential, 344, 347. Control magnet, 289, 328. Convex, lenses, 216 ; mirrors, 215. Cooling calorimeter, 186. Copper voltameter, 322. Corrections, in genei'al, 7 ; see calibra- tion, index, radiation, scale. Coulomb, the, 3oU; Crystal, angle of, 223 ; refraction of, 242 ; refractometer, 244. Cubical expansion, 155, 157, Table 18. Current strength, with electrocalorim- eter, 824 ; vfith electrodynamom- eter, 330 ; with voltameter, 322. Curvature, of a lens, 218 ; of a level, 41 ; radius of, with spherometer, 19. Cycle, stroboscopic, 141. Damped vibrations, 117, 356. JDaniell, cell, 327 ; hygrometer, 198. B^Arsonval, galvanometer, 170, 286, 303, 338. Datum circle of planimeter, 43 ; area of, 45. Dead-beat galvanometer, 287. Declination, magnetic, 363, 368 ; of ■ the sun. Table 22. Decrement, logarithmic, 117, 356. Degree, centigrade, 13, 160. Density, defined, 119 ; of air, Table 12; of mercury. Table 3 ; of various solids, liquids, and gases. Table 2 ; of water, 119, Table 3. Density, measurement of, of air, 126 ; of a gas, 127 ; by Hare's method, 129 ; with hydrometer, 131 ; by hydro- static weighing, 120; with the Jolly balance, 129 ; with the pyknometer, 124 ; with a U-tube, 128. Depression, capillary, in barometer, 71, Table 13. De Sauty, method for condenser capa- city, 354. Deviation, angle of minimum, 235. Deviations of measures, 9. Dew-point, 197 ; hygrometer, 198, Table 23. Difference of potential, contact, 344. See electromotive force. Differential galvanometer, 299. Diffraction, concave grating, 251 ; plane grating, 249 ; spectrum, 253. Dilatometer, the, 157. Dip, magnetic, 363, 372. Divided, circles, to read, 17, 229; scales, to read, 13. Dividing engine, comparator, 26 ; for circles, 27 ; for straight scales, 25. Double weighing, method of, 59, 64. Dust figures, velocity of sound by, 145. Dynameterfor power of telescope, 221. Dynamometer, electro-, 330. Earth inductor, 370, 375. Earth, magnetic elements of, 363; radius of. Table 30. Elastic, bodies, 52 ; constants of liq- uids. Table 8 ; constants of solids, Table 7. Elasticity, 51, 52; limit of, 93, Table 7 ; modulus of, 93, 98, 147 ; of vol- ume, 106, Table 8. Electrical measurements, 282. Electrocalorimeter, 188, 324. Electrochemical equivalent, of copper, 323 ; of silver, 323. Electrodynamometer, 330. Electrolyte resistance, 309. SeebaUery. Electrometer, capillary, 342; quad- rant, 339. Electromotive force, 332 et seq.; of standard cells, 332; of thermo-couple, 170 ; of various cells, Table 27 ; for methods of measurement of, see Contents. Elongation, middle, 103. English, candle, 207 ; and metric equivalents, Table 31. Equation of time. Table 22. Equilibrium, of forces, 49; of mo- ments, 54. Equivalent, electrochemical, 323; of fusion, 173, 191, Table 19 ; Joule's, 324 ; mechanical, of heat, 173, 194, 324 ; of vaporization, 192, Table 18. Equivalents, English and metric. Table 31. Errors, 7 ; of barometer, 71 ; Index, of calipers, 18 ; index, of sextant, 48 ; probable, 8 ; of weights, 66. Everett, Physical Constants, 378. Excursions, sum of, 57. Exercises, assignment of, 4; descrip- tions of, 4. Expansion, cubical, coefBcient of, 155, 157, Tables 8, 18; of a gas, 168; linear, coefficient of, 153, Table 19. Eyepiece, Gauss's coUimatlng, 226. INDEX 397 Fabry, wave length of light, 264. Fall, free, gravity by, 90 ; of potential, method of, 302. Falling tuning fork, for gravity, 74. Farad, the, 850. Figure of merit, 826, 329. Figures, significant, 11. Flashing apparatus for time obser- vations, Mendenhall's, 88; Reed's, 139. Flexure, modulus of elasticity by, 98. Flicker photometer, 212. Foci, of lenses, 216, 219 ; of mirrors, 213. , Forces, equilibrium of, 49; triangle of, 49. Fortin, barometer, 70. Foucavlt, photometer, 205. Fraunhofer, lines in spectrum, 272. Freezing point, of thermometer, 163. See fusion, melting point. Frequency of sound, by beats, 133 ; by graphic methods, 136; by Lis- sajous's figures, 137; by optical methods, 139; of musical scale. Table 28 ; with the siren, 134. See period. Fresnel, bi-prism, 246 ; mirrors, 249. Friction, coefiicients of, 112, Table 6 ; mechanical equivalent by, 194 ; roll- ing, 113 ; of viscosity, 117. Fringes, interference, with bi-prism, 246; with interferometer, 258, 261; with plane surfaces, 265 ; with polar- imeter, 278. Fundamental interval of thermometer, 162, 167, 170. Fusion, of ice, heat equivalent of, 173, 191 ; of solids. Table 19. See melt- ing point. G Galvanometer, the, general, 285 ; ad- justing, 288; aperiodic, 287; astatic, 288: ballistic, 287, 337 ; constant of, 322; D'Arsonval, 286, -303, 338; dead-beat, 287; differential, 299; figure of merit of, 325 ; needle of, to bring to rest, 339 ; resistance of, 305 ; sensitiveness of, 328 ; shunt for, 328 ; tangent, 295. Gas, density of, to measure, 127, Table 2 ; coeflScient of expansion of, 168 ; meter, 209 ; thermometer, 166 ; velocity of sound in, 144, 148, Table 30. Gauss, eyepiece, 226, 240. Gauss, the, 363. Gay-Lussac, method of calibration, 28, 32, 319. Gerhardt, thermometer calibration, 29, 164. German, Candle, 207; silver for resist- ance, 290. Glass, chemical, to clean, 115; opti- cal, to clean, 270 ; to silver, 266 ; to smoke, 91. Goniometer, 223. Gott, method for comparison of capa- city, 354. Gram, the, defined, 13. Graphical methods, general, 12; for frequency of sound, 136. Gravity, with Atwood's machine, 78 ; vrith falling fork, 76 ; by free fall, 90 ; with simple pendulum, 81 ; with reversible pendulum, 84 ; Table 10. Griffiths, platinum thermometer, 169. Hair hygrometer, 202. Half-shade polarimeter, 277. Half-silvered glass, 255, 269. Hansen, method of calibration, 32. Hare, method for density determina- tion, 129. Heat, capacity of calorimeter, 174 ; constants for liquids, Tables 17, 18 ; constants for solids. Tables 17, 19 ; equivalent of fusion, 173, 191, Table 19; equivalent of vaporization, 192, Table 18 ; mechanical equivalent of, 194 ; unit of, 173. Heatingj method of, for specific heat, 188. Hefner-Alteneck, standard lamp, 207.. Heliostat, 274. Henry, the, 360. Hints on use of balance, 62. Horizon, artificial, 48. Horizontal, candle power, 204 ; inten- sity, 363, 368, 373. Humidity, absolute, 197; relative, 197, Table 21. Hydrogen thermometer, 166 ; scale, reduction to, 166, Table 16. Hydrometers, 131. 398 INDEX Hydrostatic weighing, 120 ; other methods of, 123. Hygrometer, absorption, 198 ; Au- guste's, 200; Daniell's, 198; dew- point, 198 ; hair, 202 ; wet- and dry- bulb, 200. Hygrometry, 197, Tables 20, 21, 23. Ice, calorimeter, Black's, 178 ; calorim- eter, Bunsen's, 180; heat equiva- lent of fusion of, 173, 191; volume change in melting, 180. Impact, laws of, 51. Incandescent lamp, photometry of, 209. Inclination, magnetic, 363, 372. Inclined plane, friction on, 113. Index error, of barometer, 71 ; of cali- per, 18 ; of sextant, 48. Index of refraction, of air, 235 ; of carbon bisulphide, 241 ; by displace- ment, 238 ; of a liquid, 235 ; with a microscope, 236 ; of a prism, 234 ; by total reflection, 239; of water, 243, Table 24. Induction, coefBoient of mutual, 361; coefficient of self-, 360; flow of, 374. Inductor, earth, 370, 375. Inertia, moment of, 104 ; formulse for, 105; of pendulum, correction for, 82 ; of pulley of Atwood's machine, 78. Infinitely small arc, reduction to, 82, 356. Insulation, resistance of, 311. Intensity, of light, 203 ; magnetic, 363, 373. Interference, of light, 246, 255, 265; of sound, 147 ; polarimeter, 278. Interferometer, 255; circular bands, 261; counting fringes, 261; finding the bands, 258 ; lights for, 263 ; sil- vering mirrors, 266; standard of length, 261. J Jena Normal Glass thermometer, 160, 164, 166 ; to reduce to hydrogen scale. Table 15. Jolly, balance, 129. Joule, mechanical equivalent of heat, 173, 194, 324. Joule, the, 13, 324. K Kater, reversible pendulum, 84. Kelvin, reversing key, 341. See Thompson. Kew, magnetometer, 366. Key, condenser, 351 ; double succes- sive, 292 ; reversing, 298. Kilogram, the, 13. Koenig, tuning fork, 143. Kohlrausch, refractometer, 240, 245; electrolyte conductivity, 309 ; vari- ometer, 366. Kundt, velocity of sound, 145. Laboratory practice, objects of, 1. Lamp, and scale, 290; for monochro- matic light, 263. Landolt, Tables of Constants, 378. Latent heat, see heat equivalent. Laurent, polarimeter, 277. Laws, of friction, 112; of motion, 51 ; of vibrating strings, 149; Ohm's, 282. Least Squares, 10. Le Chatelier, pyrometer, 169, 171. Length, measurement of, 15. See Contents. Lenses, 20, 216, 219. Level, 39 ; of cathetometer, 97; trier, 39. Light, cadmium, 264; intensity of, see photometry; interference of, 246,256,265; mercury, 263; sodium, 263 ; velocity of. Table 30 ; wave length of, 246, 249, 251, Table 25. Limit, elastic, 93, Table 7. Linear expansion, coefficient of, 153, Table 19. Lippmann, capillary electrometer, 342. Liquids, compressibility of, 106, Table 8 ; density of, see density. Table 2 ; expansion coefficient of, 157 ; heat constants of, Tables 17, 18 ; specific heat of, 184, 186, 188. Lissajous, figures, frequency by, 137 ; projection of, 139. Logarithmic, calculation, 6, 11; 13; decrement, 117, 356. Logarithms, Tables 30, 33. Low-resistance bridge, 315. Lummer, photometer, 206, 210. INDEX 399 M Machine, Atwood's, 77. Magie, calorimeter, 188, 190. Magnet, control, 289, 328 ; tempera- ture coefficient of, 376, Table 30. Magnetic, fields, comparison of, 375 ; shield for galvanometer, 328; dec- lination, 363, 868 ; distribution, 374; dip, 363, 372; elements of earth, 363 ; inclination, 363, 372 ; intensity, 363, 373; meridian, 363; moment, 365 ; variometer, 366. Magnetometer, 363 ; Kew, 366. Magnifying povrer, 221. ilance, method for resistance, 306. Manganin alloy for resistance, 290 Manometric flames, 148, 151, 152. Mass, unit of, 13 ; determination of, 54, 55, 64, 120. Maxwell, method of, 360 ; rule for Wheatstone's bridge, 294. Mechanical equivalent of heat, 173, 194, 324. Megabarye, the, 72. Melde, experiments with vibrating strings, 151. Melting point, 171, Tables 17, 19. See fusion. Mendenhall, optical method for period, 88 ; pendulum, 89. Mercury, capillary depression of, 71, Table 13 ; correction for exposed column of, in thermometer, 165; density of, Table 3 ; light, 263 ; ther- mometer for high temperatures, 168 ; thermometer, reduction to hydrogen scale, 166, Table 15 ; volume of, 69, Table 4. Meridian, of Cleveland, Table 11 ; magnetic, 363, 367. Merit, figure of, 325, 329. Meter, the, 13; calibration of, 31, 33; gas, 209 ; slide-wire bridge, 284. Method, of coincidences, 82, 85, 88 ; of cooling, 186 ; graphical, 12 ; of heat- ing, 188; Mendenhall's, 88; of mix- tures, see mixtures ; of transits, 102. Metric equivalents for English meas- ures. Table 31 . Michelson, interferometer, 255; wave length of light, 264, 378. Microfarad, the, 350. Micrometer, caliper, 18; microscope, 20; microscope comparator, 30; optical, 36, 38 ; screw, 18. Microscope, index of refraction with, 236 ; micrometer, 20 ; power of, 221. Milliammeter for resistance measures, 346. Minimum deviation, 235. Mirror, concave, 214 ; convex, 215 ; foci of, 213 ; Fresnel's, 249 ; and scale, see scale. Mixtures, method of, for capacity, 355 ; radiation correction for, 176 ; for specific heat of liquids, 184 ; for specific heat of solids, 182. . Modulus, of bulk elasticity, 93, 106, Table 8 ; of rigidity, 93, 99 ; of tor- sion, 101 ; Young's, 93, 98 ; Young's, by velocity of sound, 147 ; Young's, Table 7. See coefficient. Molecular rotation, 276. Moment, of inertia, formulse for, 105 ; of inertia by torsion pendulum, 104 ; magnetic, 365. Moments, equilibrium of, 54. Momentum, and impact, 51 ; conser- vation of, 51. Monochromatic light, 263. Motion, accelerated, 74, 77 ; Laws of, 51. Musical scales, frequency. Table 28. Mutual induction, 361, 362. N Natural trigonometric functions. Table 32. Neumann, method for calibration, 32. Neutral point, of thermo-couple, 348. Newton, Laws of Cooling, 176; Laws of Motion, 51. Nicol, prism, 277. Nitrogen thermometer, 166. Nodes in organ pipes, 151. Noninductive winding, 290. Normal, pressure, 72 ; scale of temper- ature, 166, Table 16 ; spectrum, 253, 272. Notes and records of experimental work, 5. Null methods, 287. Numbers, miscellaneous. Table 30. Numerical example of, Boyle's Law, 110 ; calibration of aneroid. 111 ; calibration of bridge wire, 321 ; cal- ibration of meter (simple) , 31 ; calibra- tion of meter (complete), 34; cali- bration of micrometer microscope, 23; calibration of thermometer 400 INDEX scale, 29; calibration of thermom- eter, complete, 164; calibration of weights, 67 ; capacity comparison, 353; capacity (absolute) determina- tion, 358 ; density of aluminum, 123 ; divided-circle reading, 229 ; equilib- rium of forces, 50 ; figure of merit, 327 ; frequency of forlt. Reed's method, 143; gravity with simple pendulum, 84; mechanical equiva- lent of heat, 196 ; period by coinci- dences, 84 ; period by Mendenhall's method, 90; period by method of transits, 104; radiation correction, 177 ; significant figures, 12 ; speci- fic heat of iron, 177; specific heat by method of heating, 190 ; vernier reading, 17; weighing, single, 58; weighing, double, 60; weighing by reversal, 65 ; Young's modulus of iron, 95. Observations, making, 7; weighted, 10. Oersted, Law of, 285. Ohm, Law of, 282; method of, 296, 345. Ohm, the, 290. Oil bath for resistances, 291. Optical, activity, 275 ; axis of cathe- tometer, 97 ; axis of spectrometer, 227 ; method for frequency, 137, 139 ; method for period, 88 ; microm- eter, 36, 38; standard of length, 261 ; surfaces, to clean, 270. Organ pipes, vibration in, 151. Oscillation, see frequency, period. Ostwald, capillary electrometer, 342, 344. Overtones, 151, 152. T, values and logarithms. Table 30. Paper, to smoke, 91. Paraffin-diffusion photometer, 205. Parallax, of cathetometer, 97; method of, for mirrors and lenses, 214, 217 ; of reading microscope, 22 ; of spec- trometer, 227. Parallelogram of forces, 49. Pendulum, compound, 86; flashing, 140 ; Mendenhall's, 89 ; reversible, 84 ; simple, 81 ; torsion, 101, 104, 117. Percentage deviation, 9. Period, by coincidences, 82, 89; of a galvanometer, 356 ; by transits, 102. See frequency. Perot, wave length of light, 264. PfauncUer, calorimeter, 188. Photographic lens, focus of, 219. Photometer, Bunsen, 206 ; flicker, 212 ; Foucault, 205 ; Lummer-Brodhun, 210 ; Paraffiii-diffusion, 205 ; Ritchie, 205; Rood-Whitman, 212; Rum- ford, 205. Photometry, 203; of intense lights, 209; by precision methods, 210, 212 ; of colored lights, 206, 212. Piezometer, 106. Pipes, vibration in organ, 151. Pitch, of fork, to alter, 134. See fre- quency, screw. Plane, inclined, 113; optical surfaces, 264. Plane-parallel surfaces, 264. Flanimeter, 42. Platinum thermometer, 169. Plug, commutator, 298 ; for resistance boxes, 291. Polarimeter, 276. Polaristrobometer, 278. Polarization, rotatory, 275 ; of cell, 307, 309, 333. Post-office bridge, 293. Potential, contact difference of, 344 ; method of comparison of, 314 ; method of fall of, 302; large, to measure with quadrant electrom- eter, 341 ; small, to measure with capillary electrometer, 342. See electromotive force. Potentiometer, 335. Power, candle, 204 ; magnifying, 221 ; thermo-electric, 348. Precision, measures of, 9. Pressure, barometric, 69; standard, 72; by Boyle's Law, 108. Prism, angle of, 230 ; index of refrac- tion of, 234. Probable error, 8. Projectile, path of, 79. Psychrometer, 200, Table 20. Pulfrich, refractometer, 242. Pulley, inertia of, 78. Puluj, mechanical equivalent of heat, 194. Pyknometer, 124. Pyrometer, platinum, 168; thermo- electric, 170. INDEX 401 Quadrant electrometer, 339. Quantity, electrical, see capacity, current strength. Quartz wedge, polarimeter, 279. K Radian, the, 41, 100, Table 30. Radiation correction in calorimetry, 175, 176, 178. Radius of curvature, of level, 41; of lenses, 216, 218; of mirrors, 213; with the spherometer, 20. Reading, barometric, to reduce, 70, Table 14 ; divided circles and scales, 13, 17, 229 ; telescope, 38. Records of experimental work, 5, 12. Reduction, of barometric readings, 70, Table 14 ; of mercury thermometer to hydrogen scale, 166, Table 15 ; of psychrometer observations. Table 20 ; of weighings to vacuum, 64, 121, Table 1 ; to small arc, 82, 356. Beed, method for frequency of fork, 139 ; flashing pendulum, 140. Reference books. Table 29. Reflection, total, 239. Reflectrometer, total, 240. Refractive index, see index of refrac- tion. Refractometer, 242. Regnault, calorimeter, 182, 184 ; hy- grometer, 198. Relative, humidity, 197, Table 21 ; in- dex of refraction, 234 ; viscosity, 117, Table 6. Reports of laboratory exercises, 7. Residuals, 9. Resistance, boxes, 291; of cells. Table 27; methods for measurement of, see Contents ; oil bath for, 291 ; of plug, 291 ; of slide wire, 318; spe- cific, 313, Table 26 ; temperature coefficient of, 316, Table 26 ; ther- mometer, 169. Resonance, wave length by, 144. Resonators for analysis of sound, 152. Restitution, coefficient of, 51. Reversal, weighing by, 64. Reversible pendulum, 84. Reversing keys, 298, 341. Rheostats, 290, 292. Rider, for balance, 55, 61 ; weighing with, 61. Rigidity, 93, 99, Table 7. Ritchie, photometer, 205. Rochelle salts, method of silvering, 269. Rood, photometer, 212. Rotation, molecular, 276 ; specifio, 276. Rotatory polarization, 275. Rowland, wave length of light, 263 ; induction, 374, 375. Bueprecht, weights, 67. Rumford, photometer, 205. Saccharimeter, 277, 279, 280. Saturated water vapor. Table 23. Scale, calibration of, 28, 32 ; divided, to read, 13; musical, Table 28; with telescope or lamp, 37, 38, 41, 290, 338 ; with telescope, to correct read- ings of, 837, 357. Screw, micrometer, 18 ; pitch of, 26, 41. Second, the, 13. Self-induction, coefficient of, 360. Sensibility of balance, 62. Sensitive tint, polarimeter, 278. Sensitiveness, of balance, 56, 62 ; of galvanometer, 328 ; of electrometer, 343 ; of level, 40. Sextant, 46. Significant figures, 11. Silver voltameter, 323. Silvering glass, 266, 269. Simple, pendulum, 81 ; photometers, 204 ; torsion apparatus, 100. Siphon barometer, 70. Siren, 134. Slide-wire bridge, 284 ; resistance of, 318. Smithsonian Tables, 201, 378. Smoked paper and glass, 91. SocOti Genevoise, meter, 31, 32, 34. Sodium, chloride, conductivity of, 311 ; lamp and wave length of light, 263. Solar spectrum, wave lengths of. Table 25. Soleil, polarimeter, 278. Solids, density of. Table 2 ; elastic constants of. Table 7 ; heat con- stants of. Table 19. Sonometer, 149. Sound, analysis of, 152. See frequency, velocity, wave length. 402 INDEX Specific, gravity, 119 ; gravity, see den- sity ; gravity bottle, 124 ; gravity of air, Table 12 ; heat of iron, example of, 177; heat of liquids. Table 18; heat of solids. Table 19 ; heat, see calarimetry ; resistance, 313, Table 26 ; resistance of an electrolyte, 310 ; resistance. Table 26 ; rotation, 276 ; viscosity, 117. Spectrometer, 225. Spectroscope, 271 ; grating, 251. Spectrum, analysis, 271 ; lines in solar, Table 25; normal, 253, 272. Spherical candle power, 208. Spherometer, 19. Spring balance. Jolly, 129. Standard, cell, 332 ; interference, of length, 261 ; lights, 207 ; pitch. Table 28. Steam, see boiling point, vaporization. Strings, laws of vibrating, 149. Stroboscopio method, 141. Sugar analysis, 280. Sun, declination of, Table 22. Surface tension, 113, 110, Table 9; with an electrolyte, 342. Surfaces, plane and plane-parallel, 264. System of lenses, foci of, 219. .Tables, explanation of, 378. See Con- tents or Appendix. Tangent galvanometer, 295, 296 ; con- stant of, 322. Telephone bridge, 309. Telescope, focusing for infinity, 226 ; power of, 221; reading, 22, 38 ; with scale, 290, 337, 338. Temperature, coefficient of magnetism, 376, Table 30; coefficient of resist- ance, 292, 316, Table 26; correc- tion to barometer, 71, Table 14 ; fixed points for high, 171, Table 17; measurement of high, 168. See thermometer, pyrometer. Tension, surface, 113, 116, Table 9 ; of water vapor, 197, Table 23. Tenths, estimation of, 13. . Testing, aneroid, 110 ; half-silvered surfaces, 269 ; plane and plane-par- allel surfaces, 264 ; set, 294. Thermal capacity of calorimeter, 174. Thermo-electric, diagram, 348; pyrom- eter, 170. Thermo-electromotive, force, 170, 347, 348 ; power, 348. Thermometer, air, 166 ; calibration of, 29, 160, 162 ; for calorimetry, 174 ; exposed column of mercury, 165; fundamental interval of, 162 ; heat capacity of, 175 ; for high tempera- tures, 168 ; platinum, 169 ; reduc- tion to hydrogen scale, 166 ; thermo- electric, 170 ; weight, 155. Thiesen, method of calibration, 32. Thompson, method for resistance, 305. Time, equation of, Table 22 ; meas- urement of, 74 ; variable unit, 76. See chronograph, frequency, period. Torsion, lathe, 99 ; modulus of, 101 ; pendulum, 101, 104, 117 ; simple apparatus for, 100. Total reflection, 239. Total-reflectometer, 240. Trajectory, 79. Transits, periodic time by, 102. Triangle of forces, 49. Trigonometric functions. Table 32. Tubes, capillary, 113 ; volume and radius of, 69. Tuning fork, 133, 134; falling, 74; chronograph, 91. U Units, 12. See names of units. U-tube, for Boyle's Law, 108; for den- sity, 128. V Vacuum, reduction to, 64, 121, Table 1. Vapor, mass of water. Table 23 ; ten- sion of water. Table 23. Vaporization, heat equivalent of, 192, Table 18. Variometer, magnetic, 366. Velocity of sound, in air, 144 ; by dust figures, 145; in gas, 145, 147, Table 30 ; by interference, 147 ; by reso- nance, 144; in solids. Table 7. Vernier, 15 ; caliper, 17. Verniers, circle with two or more, 229. Vibrating, air columns, 151 ; strings, 149. Vibration, damped, 117, 356 ; fre- quency of musical scale, Table 28 ; in organ pipes, 151 ; weighing by, 57. See frequency, period. INDEX 403 Virtual, focus, 213, 216 ; resistance, 327, 357. Viscosity, 117, Table 6. Volt, the, 332. Voltameter, copper, 322; silver, 323. Voltmeter, 302 ; calibration of, 348. Volume, elasticity, 93, 106, Table 8; of a glass vessel, 69, Table 4; of mercury, 69, Table 4 ■ of a tube, 69 ; of water, 69, Table 4 ; by vfeighing, 68, Table 4. Volumetric expansion of liquids. Table 18. W Water, boiling point of, 163, Table 16; density of, 119, Table 3; equiv- alent of calorimeter, 174; mass of vapor of. Table 23; trough for organ pipe, 151 ; vapor tension of, Table 23; volume of, in glass vessel, 69, Table 4. Watt, the, 324. Wave length, of light with bi-prism, 246 ; by diffraction, 249, 251 ; of monochromatic lights, 363 ; of solar- spectrum lines. Table 85 ; of sound by interference, 147 ; of sound Tiy resonance, 144. Weighing, with constant load, 120 ; double, 59 ; hydrostatic, 120 ; by reversal, 64 ; with rider, 61 ; reduc- tion to vacuum, 65, Table 1 ; by vibration, 57 ; for volume, 68. Weight in vacuo, 64. Weight thermometer, 155. Weighted observations, 10. Weights, adjustment of, 68; calibra- tion of, 66 ; counting, 63 ; of obser- vations, 11. Weston, standard cell, 333. Wet- and dry-bulb hygrometer, 200. Wheatstone, bridge, 169, 283. White light, interference in, 259. Whitman, flicker photometer, 212. Wild, polarimeter, 278. Wollaston, goniometer, 223. Toung\i modulus, 93 ; by stretching, 93 ; by flexure, 98 ; by velocity of sound, 147 ; values of, Table 7. Zero point, of balance, 57, 64 ; of thermometer, 159, 163. /